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Sample records for datsu hetero hanno

  1. Hanno Veldi pisiunistus kasvas suurfirmaks / Indrek Kald

    Index Scriptorium Estoniae

    Kald, Indrek, 1974-

    2008-01-01

    Hanno Veldile ja Helgo Äkkele kuuluv firma OÜ Hanhel Tehnika tegeleb väiketraktorite ja mootorrataste müügiga ning ettevõtte motokeskus Velt Motocenter on laienenud mitmesse linna üle Eesti. Hanno Veldist kui motosportlasest. Kommenteerib Helgo Äkke. Vt. samas: Hanno Velt: klienti võlub teenindus; Velt kukub ka arvutimängus

  2. Tarvo Hanno Varres, Mari-Leen Kiipli / Merilin Talumaa, Hanno Soans, Tatjana Kozlova-Johannes

    Index Scriptorium Estoniae

    Talumaa, Merilin, 1986-

    2015-01-01

    Vaatluse alla on võetud Tarvo Hanno Varrese heli- ja videoinstallatsioon "Lindistav põrand" (2015) ja heli- ja videoteos "Betweenland" (2014) ning Mari-Leen Kiipli fotoseeria "The school of dreams" (2012-2015)

  3. Sekkumine Kadriorus / Hanno Soans

    Index Scriptorium Estoniae

    Soans, Hanno, 1974-

    2003-01-01

    31. VIII Mikkeli muuseumis Briti kunstirühmituse Virus ja Chris Evansi presentatsioonid. Projekt "Sekkumine - kaasaegne kunst inglise pargis" toimub Väliskunsti muuseumis, Mikkeli muuseumis ja selle ümbruses. Inspiratsiooniks on Kadrioru park ja näitused "Kaduv maailm. Inglise park Eestis" Mikkeli ning "Looduse ja kunsti austajatele. Wörlitzi park" Väliskunsti muuseumis. Virus sekkub Kadrioru parki kohaspetsiifilise installatsiooniga. Projekti kuraator Hanno Soans

  4. Excuse me, are you the last here? / Hanno Soans

    Index Scriptorium Estoniae

    Soans, Hanno, 1974-

    2003-01-01

    Rotermanni soolalaos 2003 a. sügisel toimunud rahvusvahelisest näitusest "Viimane kangelane", kus oma nägemust kangelasest tutvustab 23 kunstnikku Ida-Euroopast. Kuraatorid Hanno Soans ja Eha Komissarov

  5. Radioimmunoassay with heterologous antibody (hetero-antibody RIA)

    International Nuclear Information System (INIS)

    Iwasawa, Atsushi; Hayashi, Hiroaki; Itoh, Zen; Wakabayashi, Katsumi

    1991-01-01

    To develop a homologous radioimmunoassay (RIA) for a hormone of a small or rare animal often meets difficulty in collecting a large amount of purified antigen required for antibody production. On the other hand, to employ a heterologous RIA to estimate the hormone often gives poor sensitivity. To overcome this difficulty, a 'hetero-antibody' RIA was studied. In a hetero-antibody RIA system, a purified preparation of a hormone is used for radioiodination and standardization and a heterologous antibody to the hormone is used for the first antibody. Canine motilin and rat LH were selected as examples, and anti-porcine motilin and anti-hCG, anti-hCGβ or anti-ovine LHβ was used as the heterologous antibody. The sensitivities of the hetero-antibody RIAs were much higher than those of heterologous RIAs in any case, showing that these hetero-antibody RIA systems were suitable for practical use. To clarify the principle of hetero-antibody RIA, antiserum to porcine motilin was fractionated on an affinity column where canine motilin was immobilized. The fraction bound had greater constants of affinity with both porcine and canine motilins than the rest of the antibody fractions. This fraction also reacted with a synthetic peptide corresponding to the C-terminal sequence common to porcine and canine motilins in a competitive binding test with labeled canine motilin. These results suggest that an antibody population having high affinity and cross-reactivity is present in polyclonal antiserum and indicate that the population can be used in hetero-antibody RIA at an appropriate concentration. (author)

  6. Kuraator, kunst, ühiskond / Anders Kreuger, Catrin Lundqvist, Hanno Soans ; interv. Reet Varblane

    Index Scriptorium Estoniae

    Kreuger, Anders

    2005-01-01

    Kuraatori rollist ja missioonist kõnelesid Anders Kreuger, kes praegu vabakutselisena kuraatorlusest doktoritööd kirjutab ja õppejõuna tegutseb, Stockholmi Moderna Museeti kuraator Catrin Lundqvist ja Hanno Soans Eesti Kunstimuuseumist

  7. Hydrogenation of heteroaromatics by high pressure DTA techniques. 3; Koatsu DTA ho ni yoru hokozoku kagobutsu no suisoka (rutenium tanji shokubai ni yoru kakusuisoka datsu hetero hanno)

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, M.; Yoshida, T. [Hokkaido National Industrial Research Institute, Sapporo (Japan); Kotanigawa, T. [Japan International Cooperation Agency, Tokyo (Japan)

    1996-10-28

    Ring-opening of heteroaromatics and heteroatom-removal reaction were studied experimentally using the acidic catalyst containing phosphoric acid for improvement of an upgrading method of coal derived oils. In experiment, some Ru-carrying metal oxide catalysts such as RMZ, RML and RMN catalyst, and MNP catalyst containing phosphoric acid were used as specimens. Nuclear hydrogenation reaction and hydro-denitrogenation reaction of dibenzothiophene and carbazole were compared with each other. The experimental results are as follows. Both RMN and RMNP catalysts offer a superior selectivity in nuclear hydrogenation reaction and hydro-denitrogenation reaction of carbazole. Although both catalysts offer an extremely high nuclear hydrogenation activity at 360{degree}C, these offer the high selectivity of denitrogenation products at 430{degree}C. In comparison of the activities of MN and MNP catalysts with the same Mn2O3:NiO ratio, MNP catalyst offers the higher denitrogenation activity than MN catalyst at 430{degree}C. 1 ref., 3 tabs.

  8. One-Dimensional Hetero-Nanostructures for Rechargeable Batteries.

    Science.gov (United States)

    Mai, Liqiang; Sheng, Jinzhi; Xu, Lin; Tan, Shuangshuang; Meng, Jiashen

    2018-04-17

    Rechargeable batteries are regarded as one of the most practical electrochemical energy storage devices that are able to convert and store the electrical energy generated from renewable resources, and they function as the key power sources for electric vehicles and portable electronics. The ultimate goals for electrochemical energy storage devices are high power and energy density, long lifetime, and high safety. To achieve the above goals, researchers have tried to apply various morphologies of nanomaterials as the electrodes to enhance the electrochemical performance. Among them, one-dimensional (1D) materials show unique superiorities, such as cross-linked structures for external stress buffering and large draw ratios for internal stress dispersion. However, a homogeneous single-component electrode material can hardly have the characteristics of high electronic/ionic conductivity and high stability in the electrochemical environment simultaneously. Therefore, designing well-defined functional 1D hetero-nanostructures that combine the advantages and overcome the limitations of different electrochemically active materials is of great significance. This Account summarizes fabrication strategies for 1D hetero-nanostructures, including nucleation and growth, deposition, and melt-casting and electrospinning. Besides, the chemical principles for each strategy are discussed. The nucleation and growth strategy is suitable for growing and constructing 1D hetero-nanostructures of partial transition metal compounds, and the experimental conditions for this strategy are relatively accessible. Deposition is a reliable strategy to synthesize 1D hetero-nanostructures by decorating functional layers on 1D substrate materials, on the condition that the preobtained substrate materials must be stable in the following deposition process. The melt-casting strategy, in which 1D hetero-nanostructures are synthesizes via a melting and molding process, is also widely used. Additionally

  9. Synthesis of hetero ionic compounds using dialkylcarbonate quaternization

    Energy Technology Data Exchange (ETDEWEB)

    Friesen, Cody A.; Wolfe, Derek; Johnson, Paul Bryan

    2018-04-03

    Methods of preparing hetero ionic complexes, and ionic liquids from bisulfate salts of heteroatomic compounds using dialkylcarbonates as a primary quaternizing reactant are disclosed. Also disclosed are methods of making electrochemical cells comprising the ionic liquids, and an electrochemical cell comprising an alkaline electrolyte and a hetero ionic complex additive.

  10. Unidirectional oxide hetero-interface thin-film diode

    International Nuclear Information System (INIS)

    Park, Youngmin; Lee, Eungkyu; Lee, Jinwon; Lim, Keon-Hee; Kim, Youn Sang

    2015-01-01

    The unidirectional thin-film diode based on oxide hetero-interface, which is well compatible with conventional thin-film fabrication process, is presented. With the metal anode/electron-transporting oxide (ETO)/electron-injecting oxide (EIO)/metal cathode structure, it exhibits that electrical currents ohmically flow at the ETO/EIO hetero-interfaces for only positive voltages showing current density (J)-rectifying ratio of ∼10 5 at 5 V. The electrical properties (ex, current levels, and working device yields) of the thin-film diode (TFD) are systematically controlled by changing oxide layer thickness. Moreover, we show that the oxide hetero-interface TFD clearly rectifies an AC input within frequency (f) range of 10 2  Hz < f < 10 6  Hz, providing a high feasibility for practical applications

  11. Unidirectional oxide hetero-interface thin-film diode

    Energy Technology Data Exchange (ETDEWEB)

    Park, Youngmin; Lee, Eungkyu; Lee, Jinwon; Lim, Keon-Hee [Program in Nano Science and Technology, Graduate School of Convergence Science and Technology, Seoul National University, Seoul 151-742 (Korea, Republic of); Kim, Youn Sang, E-mail: younskim@snu.ac.kr [Program in Nano Science and Technology, Graduate School of Convergence Science and Technology, Seoul National University, Seoul 151-742 (Korea, Republic of); Advanced Institute of Convergence Technology, Gyeonggi-do 443-270 (Korea, Republic of)

    2015-10-05

    The unidirectional thin-film diode based on oxide hetero-interface, which is well compatible with conventional thin-film fabrication process, is presented. With the metal anode/electron-transporting oxide (ETO)/electron-injecting oxide (EIO)/metal cathode structure, it exhibits that electrical currents ohmically flow at the ETO/EIO hetero-interfaces for only positive voltages showing current density (J)-rectifying ratio of ∼10{sup 5} at 5 V. The electrical properties (ex, current levels, and working device yields) of the thin-film diode (TFD) are systematically controlled by changing oxide layer thickness. Moreover, we show that the oxide hetero-interface TFD clearly rectifies an AC input within frequency (f) range of 10{sup 2} Hz < f < 10{sup 6} Hz, providing a high feasibility for practical applications.

  12. Rotermanni vana jahuladu ja uus jahuladu = Rotermann old and new flour storage / Hanno Grossschmidt, Tomomi Hayashi

    Index Scriptorium Estoniae

    Grossschmidt, Hanno, 1973-

    2009-01-01

    Tallinna endise Rotermanni tööstuskvartali arhitektuuri kaasajastamine. Arhitektid Yoko Azukawa, Hanno Grossschmidt ja Tomoni Hayashi, projekteerija HG Arthitektuur, konstruktor Neoprojekt. Projekt ja ehitus 2006-2008

  13. InAs/Si Hetero-Junction Nanotube Tunnel Transistors

    KAUST Repository

    Hanna, Amir; Fahad, Hossain M.; Hussain, Muhammad Mustafa

    2015-01-01

    Hetero-structure tunnel junctions in non-planar gate-all-around nanowire (GAA NW) tunnel FETs (TFETs) have shown significant enhancement in ‘ON’ state tunnel current over their all-silicon counterpart. Here we show the unique concept of nanotube TFET in a hetero-structure configuration that is capable of much higher drive current as opposed to that of GAA NW TFETs.Through the use of inner/outer core-shell gates, a single III-V hetero-structured nanotube TFET leverages physically larger tunneling area while achieving higher driver current (ION) and saving real estates by eliminating arraying requirement. Numerical simulations has shown that a 10 nm thin nanotube TFET with a 100 nm core gate has a 5×normalized output current compared to a 10 nm diameter GAA NW TFET.

  14. InAs/Si Hetero-Junction Nanotube Tunnel Transistors

    KAUST Repository

    Hanna, Amir

    2015-04-29

    Hetero-structure tunnel junctions in non-planar gate-all-around nanowire (GAA NW) tunnel FETs (TFETs) have shown significant enhancement in ‘ON’ state tunnel current over their all-silicon counterpart. Here we show the unique concept of nanotube TFET in a hetero-structure configuration that is capable of much higher drive current as opposed to that of GAA NW TFETs.Through the use of inner/outer core-shell gates, a single III-V hetero-structured nanotube TFET leverages physically larger tunneling area while achieving higher driver current (ION) and saving real estates by eliminating arraying requirement. Numerical simulations has shown that a 10 nm thin nanotube TFET with a 100 nm core gate has a 5×normalized output current compared to a 10 nm diameter GAA NW TFET.

  15. Solvent Effects in Asymmetric Hetero Diels-Alder and Ene Reactions

    DEFF Research Database (Denmark)

    Johannsen, Mogens; Jørgensen, Karl Anker

    1996-01-01

    The use of polar solvents such as nitromethane or 2-nitropropane leads to a significant improvement of the catalytic properties of a cationic copper-Lewis acid in the hetero Diels-Alder reaction of alkyl glyoxylates with dienes; The scope of a newly developed copper(II)-bisoxazoline catalyst...... for the hetero Diels-Alder reaction is demonstrated by the reaction of different dienes with alkyl glyoxylates in nitroalkane solvents with the formation of the hetero Diels-Alder adduct in high enantiomeric excess as the major product. The synthetic application of the reaction is exemplified by an improved...

  16. Light-Induced C-H Arylation of (Hetero)arenes by In Situ Generated Diazo Anhydrides.

    Science.gov (United States)

    Cantillo, David; Mateos, Carlos; Rincon, Juan A; de Frutos, Oscar; Kappe, C Oliver

    2015-09-07

    Diazo anhydrides (Ar-N=N-O-N=N-Ar) have been known since 1896 but have rarely been used in synthesis. This communication describes the development of a photochemical catalyst-free C-H arylation methodology for the preparation of bi(hetero)aryls by the one-pot reaction of anilines with tert-butyl nitrite and (hetero)arenes under neutral conditions. The key step in this procedure is the in situ formation and subsequent photochemical (>300 nm) homolytic cleavage of a transient diazo anhydride intermediate. The generated aryl radical then efficiently reacts with a (hetero)arene to form the desired bi(hetero)aryls producing only nitrogen, water, and tert-butanol as byproducts. The scope of the reaction for several substituted anilines and (hetero)arenes was investigated. A continuous-flow protocol increasing selectivity and safety has been developed enabling the experimentally straightforward preparation of a variety of substituted bi(hetero)aryls within 45 min of reaction time. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. High-efficiency super capacitors based on hetero-structured α-MnO2 nanorods

    International Nuclear Information System (INIS)

    Ghouri, Zafar Khan; Shaheer Akhtar, M.; Zahoor, Awan; Barakat, Nasser A.M.; Han, Weidong; Park, Mira; Pant, Bishweshwar; Saud, Prem Singh; Lee, Cho Hye; Kim, Hak Yong

    2015-01-01

    Highlights: • Hetero-structured α-MnO 2 nanorods are prepared by a facile hydrothermal route. • It is applied as active electrode materials for supercapacitor. • A high specific capacitance of 298 Fg −1 with a superior long term cyclic stability is achieved. • Supercapacitor shows high specific capacitance retention 94% after 1000 cycles. - Abstract: Hetero-structured manganese dioxide nanorods with α phase (α-MnO 2 ) were prepared by a facile hydrothermal route at low temperature. X-ray diffraction, scanning electron microscopy, transmission electron microscopy and nitrogen adsorption–desorption measurements were used to characterize the prepared hetero-structured α-MnO 2 nanorods. Supercapacitive performance of the hetero-structured α-MnO 2 nanomaterials as active electrode material was evaluated by cyclic voltammetry (CV) in alkaline medium. The MnO 2 hetero-structure with 2 × 2 tunnels constructed from double chains of octahedral [MnO 6 ] structure yield a significantly high specific capacitance of 298 Fg −1 at 5 mV s −1 and demonstrated a superior long term cyclic stability, with specific capacitance retention about 94% after 1000 cycles. The superior supercapacitive performance of the hetero-structured α-MnO 2 electrode is due to its high specific surface area and unique hierarchy architecture which facilitate fast electron and ion transport

  18. Distinguish self- and hetero-perceived stress through behavioral imaging and physiological features.

    Science.gov (United States)

    Spodenkiewicz, Michel; Aigrain, Jonathan; Bourvis, Nadège; Dubuisson, Séverine; Chetouani, Mohamed; Cohen, David

    2018-03-02

    Stress reactivity is a complex phenomenon associated to multiple and multimodal expressions. Response to stressors has an obvious survival function and may be seen as an internal regulation to adapt to threat or danger. The intensity of this internal response can be assessed as the self-perception of the stress response. In species with social organization, this response also serves a communicative function, so-called hetero-perception. Our study presents multimodal stress detection assessment - a new methodology combining behavioral imaging and physiological monitoring for analyzing stress from these two perspectives. The system is based on automatic extraction of 39 behavioral (2D+3D video recording) and 62 physiological (Nexus-10 recording) features during a socially evaluated mental arithmetic test. The analysis with machine learning techniques for automatic classification using Support Vector Machine (SVM) show that self-perception and hetero-perception of social stress are both close but different phenomena: self-perception was significantly correlated with hetero-perception but significantly differed from it. Also, assessing stress with SVM through multimodality gave excellent classification results (F1 score values: 0.9±0.012 for hetero-perception and 0.87±0.021 for self-perception). In the best selected feature subsets, we found some common behavioral and physiological features that allow classification of both self- and hetero-perceived stress. However, we also found the contributing features for automatic classifications had opposite distributions: self-perception classification was mainly based on physiological features and hetero-perception was mainly based on behavioral features. Copyright © 2017. Published by Elsevier Inc.

  19. Effect of doping on electronic properties of double-walled carbon and boron nitride hetero-nanotubes

    International Nuclear Information System (INIS)

    Majidi, R.; Ghafoori Tabrizi, K.; Jalili, S.

    2009-01-01

    The effect of boron nitride (BN) doping on electronic properties of armchair double-walled carbon and hetero-nanotubes is studied using ab initio molecular dynamics method. The armchair double-walled hetero-nanotubes are predicted to be semiconductor and their electronic structures depend strongly on the electronic properties of the single-walled carbon nanotube. It is found that electronic structures of BN-doped double-walled hetero-nanotubes are intermediate between those of double-walled boron nitride nanotubes and double-walled carbon and boron nitride hetero-nanotubes. Increasing the amount of doping leads to a stronger intertube interaction and also increases the energy gap.

  20. Effect of doping on electronic properties of double-walled carbon and boron nitride hetero-nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Majidi, R. [Department of Physics, Shahid Beheshti University, Evin, Tehran 19839-63113 (Iran, Islamic Republic of); Ghafoori Tabrizi, K., E-mail: K-TABRIZI@sbu.ac.i [Department of Physics, Shahid Beheshti University, Evin, Tehran 19839-63113 (Iran, Islamic Republic of); Jalili, S. [Department of Chemistry, K.N. Toosi University of Technology, Tehran 16315-1618 (Iran, Islamic Republic of)

    2009-11-01

    The effect of boron nitride (BN) doping on electronic properties of armchair double-walled carbon and hetero-nanotubes is studied using ab initio molecular dynamics method. The armchair double-walled hetero-nanotubes are predicted to be semiconductor and their electronic structures depend strongly on the electronic properties of the single-walled carbon nanotube. It is found that electronic structures of BN-doped double-walled hetero-nanotubes are intermediate between those of double-walled boron nitride nanotubes and double-walled carbon and boron nitride hetero-nanotubes. Increasing the amount of doping leads to a stronger intertube interaction and also increases the energy gap.

  1. High-efficiency super capacitors based on hetero-structured α-MnO{sub 2} nanorods

    Energy Technology Data Exchange (ETDEWEB)

    Ghouri, Zafar Khan [Department of BIN Fusion Technology, Chonbuk National University, Jeonju 561-756 (Korea, Republic of); Department of Organic materials and Fiber Engineering, Chonbuk National University, Jeonju 561-756 (Korea, Republic of); Shaheer Akhtar, M. [New & Renewable Energy Material Development Center (NewREC), Chonbuk National University, Jeonbuk (Korea, Republic of); Zahoor, Awan [Department of Chemical Engineering, NED University of Engineering & Technology, University Road, Karachi 75270 (Pakistan); Barakat, Nasser A.M., E-mail: nasser@jbnu.ac.kr [Department of Organic materials and Fiber Engineering, Chonbuk National University, Jeonju 561-756 (Korea, Republic of); Department of Chemical Engineering, Faculty of Engineering, El-Minia University, El-Minia (Egypt); Han, Weidong [Department of BIN Fusion Technology, Chonbuk National University, Jeonju 561-756 (Korea, Republic of); Park, Mira [Department of Organic materials and Fiber Engineering, Chonbuk National University, Jeonju 561-756 (Korea, Republic of); Pant, Bishweshwar; Saud, Prem Singh; Lee, Cho Hye [Department of BIN Fusion Technology, Chonbuk National University, Jeonju 561-756 (Korea, Republic of); Kim, Hak Yong, E-mail: khy@jbnu.ac.kr [Department of BIN Fusion Technology, Chonbuk National University, Jeonju 561-756 (Korea, Republic of)

    2015-09-05

    Highlights: • Hetero-structured α-MnO{sub 2} nanorods are prepared by a facile hydrothermal route. • It is applied as active electrode materials for supercapacitor. • A high specific capacitance of 298 Fg{sup −1} with a superior long term cyclic stability is achieved. • Supercapacitor shows high specific capacitance retention 94% after 1000 cycles. - Abstract: Hetero-structured manganese dioxide nanorods with α phase (α-MnO{sub 2}) were prepared by a facile hydrothermal route at low temperature. X-ray diffraction, scanning electron microscopy, transmission electron microscopy and nitrogen adsorption–desorption measurements were used to characterize the prepared hetero-structured α-MnO{sub 2} nanorods. Supercapacitive performance of the hetero-structured α-MnO{sub 2} nanomaterials as active electrode material was evaluated by cyclic voltammetry (CV) in alkaline medium. The MnO{sub 2} hetero-structure with 2 × 2 tunnels constructed from double chains of octahedral [MnO{sub 6}] structure yield a significantly high specific capacitance of 298 Fg{sup −1} at 5 mV s{sup −1} and demonstrated a superior long term cyclic stability, with specific capacitance retention about 94% after 1000 cycles. The superior supercapacitive performance of the hetero-structured α-MnO{sub 2} electrode is due to its high specific surface area and unique hierarchy architecture which facilitate fast electron and ion transport.

  2. New faces of porous Prussian blue: interfacial assembly of integrated hetero-structures for sensing applications.

    Science.gov (United States)

    Kong, Biao; Selomulya, Cordelia; Zheng, Gengfeng; Zhao, Dongyuan

    2015-11-21

    Prussian blue (PB), the oldest synthetic coordination compound, is a classic and fascinating transition metal coordination material. Prussian blue is based on a three-dimensional (3-D) cubic polymeric porous network consisting of alternating ferric and ferrous ions, which provides facile assembly as well as precise interaction with active sites at functional interfaces. A fundamental understanding of the assembly mechanism of PB hetero-interfaces is essential to enable the full potential applications of PB crystals, including chemical sensing, catalysis, gas storage, drug delivery and electronic displays. Developing controlled assembly methods towards functionally integrated hetero-interfaces with adjustable sizes and morphology of PB crystals is necessary. A key point in the functional interface and device integration of PB nanocrystals is the fabrication of hetero-interfaces in a well-defined and oriented fashion on given substrates. This review will bring together these key aspects of the hetero-interfaces of PB nanocrystals, ranging from structure and properties, interfacial assembly strategies, to integrated hetero-structures for diverse sensing.

  3. Spectrophotometric investigation of the hetero-association of Caffeine and thiazine dye in aqueous solution

    Science.gov (United States)

    Bolotin, P. A.; Baranovsky, S. F.; Evstigneev, M. P.

    2006-06-01

    The self-association of thiazine dye, Methylene Blue (MB), and its hetero-association with Caffeine (CAF), were studied in aqueous solution by means of spectrophotometry in the visible range of spectrum. Concentration and temperature dependences of molar absorption of the interacting molecules were used to analyse dynamic equilibrium in solution in terms of two-component model of molecular hetero-association. The magnitudes of equilibrium dimerization and hetero-association constants as well as thermodynamic parameters, enthalpy and entropy, were determined. The calculation of the fraction of different types of associates in the mixed solution, containing Methylene Blue and Caffeine, was done. It was concluded that the hetero-association of Methylene Blue and Caffeine molecules results in lower effective concentration of the dye in solution, which may account for the alteration of its biological activity.

  4. An Au/Si hetero-nanorod-based biosensor for Salmonella detection

    Energy Technology Data Exchange (ETDEWEB)

    Fu Junxue; Zhao Yiping [Physics and Astronomy Department, University of Georgia, Athens, GA 30602 (United States); Park, Bosoon; Siragusa, Greg [USDA, ARS, Russell Research Center, Athens, GA 30605 (United States); Jones, Les; Tripp, Ralph [Department of Infectious Diseases, College of Veterinary Medicine, University of Georgia, Athens, GA 30602 (United States); Cho, Yong-Jin [Korea Food Research Institute, Songnam (Korea, Republic of)], E-mail: zhaoy@physast.uga.edu

    2008-04-16

    We present a novel and effective food-borne bacteria detection method. A hetero-structured silicon/gold nanorod array fabricated by the glancing angle deposition method is functionalized with anti-Salmonella antibodies and organic dye molecules. Due to the high aspect ratio nature of the Si nanorods, dye molecules attached to the Si nanorods produce an enhanced fluorescence upon capture and detection of Salmonella. This bio-functional hetero-nanorod detection method has great potential in the food safety industry as well as in biomedical diagnostics.

  5. The first organocatalytic, ortho-regioselective inverse-electron-demand hetero-Diels-Alder reaction.

    Science.gov (United States)

    Hejmanowska, Joanna; Jasiński, Marcin; Wojciechowski, Jakub; Mlostoń, Grzegorz; Albrecht, Łukasz

    2017-10-17

    The development of the unprecedented ortho-regioselective inverse-electron-demand hetero-Diels-Alder (IEDHDA) reaction is described. It has been demonstrated that by proper choice of reactants and reaction conditions the inverse-electron-demand hetero-Diels-Alder cycloaddition can be realized with unprecedented regioselectivity arising from the reaction between the terminal carbon atom of the dienophile and the heteroatom of the heterodiene.

  6. Tundeid saab testida, kuid mitte hierarhiasse seada... / Hanno Soans, Raoul Kurvitz, Toomas Mikk...[jt.] ; interv. Reet Varblane

    Index Scriptorium Estoniae

    1998-01-01

    3.-12. juulini Moskvas Malõi Manezhi galeriis olnud rahvusvahelisest näitusest "Meelte testimise jaam" ("Senses Test Station"). Kuraator Georgi Nikitsh. Eesti kunstiprojektist "Hüljatud lahinguväljad". Kuraator Hanno Soans, osalejad Raoul Kurvitz, Toomas Mikk, Urmo Raus, Sven Saag, Jaan Toomik. Pikemalt R. Kurvitza ja T. Miku projektist.

  7. HETERO code, heterogeneous procedure for reactor calculation; Program Hetero, heterogeni postupak proracuna reaktora

    Energy Technology Data Exchange (ETDEWEB)

    Jovanovic, S M; Raisic, N M [Boris Kidric Institute of Nuclear Sciences Vinca, Beograd (Yugoslavia)

    1966-11-15

    This report describes the procedure for calculating the parameters of heterogeneous reactor system taking into account the interaction between fuel elements related to established geometry. First part contains the analysis of single fuel element in a diffusion medium, and criticality condition of the reactor system described by superposition of elements interactions. the possibility of performing such analysis by determination of heterogeneous system lattice is described in the second part. Computer code HETERO with the code KETAP (calculation of criticality factor {eta}{sub n} and flux distribution) is part of this report together with the example of RB reactor square lattice.

  8. Amplified emission and modified spectral features in an opal hetero-structure mediated by passive defect mode localization

    Science.gov (United States)

    Rout, Dipak; Kumar, Govind; Vijaya, R.

    2018-01-01

    A photonic crystal hetero-structure consisting of a passive planar defect of SiO2 thin film sandwiched between two identical opals grown by inward growing self-assembly method using Rhodamine-B dye-doped polystyrene microspheres is studied for the characteristics of dye emission. The optical properties and the defect mode characteristics of the hetero-structure are studied from the reflection and transmission measurements. Laser-induced fluorescence from the hetero-structure showed amplified and spectrally narrowed emission compared to the photonic crystal emphasizing the role of the defect mode and distributed feedback. The enhanced emission is also complemented by the reduction in fluorescence decay time in the case of the hetero-structure in comparison to the 3D photonic crystals.

  9. High toughness alumina/aluminate: The role of hetero-interfaces

    International Nuclear Information System (INIS)

    Brito, M.E.; Yasuoka, M.; Kanzaki, S.

    1996-01-01

    Silica doped alumina/aluminate materials present a combination of high strength and high toughness not achieved before in other alumina systems, except for transformation toughened alumina. The authors have associated the increase in toughness to crack bridging by anisotropically grown alumina grains with concurrent interfacial debonding of these grains. A HREM study of grain boundaries and hetero-interface structures in this material shows the absence of amorphous phases at grain boundaries. Local Auger electron analysis of fractured surfaces revealed the coexistence of Si and La at the grain facets exposed by the noticeable intergranular fracture mode of this material. It is concluded that a certain and important degree of boundaries weakness is related to both presence of Si at the interfaces and existence of alumina/aluminate hetero-interfaces

  10. The asymmetric hetero-Diels-Alder reaction in the syntheses of biologically relevant compounds.

    Science.gov (United States)

    Eschenbrenner-Lux, Vincent; Kumar, Kamal; Waldmann, Herbert

    2014-10-13

    The hetero-Diels-Alder reaction is one of the most powerful transformations in the chemistry toolbox for the synthesis of aza- and oxa-heterocycles embodying multiple stereogenic centers. However, as compared to other cycloadditions, in particular the dipolar cycloadditions and the Diels-Alder reaction, the hetero-Diels-Alder reaction has been much less explored and exploited in organic synthesis. Nevertheless, this powerful transformation has opened up efficient and creative routes to biologically relevant small molecules and different natural products which contain six-membered oxygen or nitrogen ring systems. Recent developments in this field, in particular in the establishment of enantioselectively catalyzed hetero-Diels-Alder cycloadditions steered by a plethora of different catalysts and the application of the resulting small molecules in chemical biology and medicinal chemistry research, are highlighted in this Minireview. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. DFT study on the interfacial properties of vertical and in-plane BiOI/BiOIO3 hetero-structures.

    Science.gov (United States)

    Dai, Wen-Wu; Zhao, Zong-Yan

    2017-04-12

    Composite photocatalysts with hetero-structures usually favor the effective separation of photo-generated carriers. In this study, BiOIO 3 was chosen to form a hetero-structure with BiOI, due to its internal polar field and good lattice matching with BiOI. The interfacial properties and band offsets were focused on and analyzed in detail by DFT calculations. The results show that the charge depletion and accumulation mainly occur in the region near the interface. This effect leads to an interfacial electric field and thus, the photo-generated electron-hole pairs can be easily separated and transferred along opposite directions at the interface, which is significant for the enhancement of the photocatalytic activity. Moreover, according to the analysis of band offsets, the vertical BiOI/BiOIO 3 belongs to the type-II hetero-structure, while the in-plane BiOI/BiOIO 3 belongs to the type-I hetero-structure. The former type of hetero-structure has more favorable effects to enhance the photocatalytic activity of BiOI than that of the latter type of hetero-structure. In the case of the vertical BiOI/BiOIO 3 hetero-structure, photo-generated electrons can move from the conduction band of BiOI to that of BiOIO 3 , while holes can move from the valence band of BiOIO 3 to that of BiOI under solar radiation. In addition, the introduced internal electric field functions as a selector that can promote the separation of photo-generated carriers, resulting in the higher photocatalytic quantum efficiency. These findings illustrate the underlying mechanism for the reported experiments, and can be used as a basis for the design of novel highly efficient composite photocatalysts with hetero-structures.

  12. Auto e hetero-avaliação no diagnóstico de necessidades de treinamento Self and hetero assessment in training needs diagnostic

    Directory of Open Access Journals (Sweden)

    Mônica Lemes Magalhães

    2001-06-01

    Full Text Available O presente estudo teve como objetivos: desenvolver uma metodologia de avaliação de necessidades de treinamento que incluísse atitudes; estudar a relação entre auto e hetero-avaliação, buscando avaliar conhecimentos, habilidades e atitudes; e avaliar a relação entre a auto-avaliação e algumas variáveis preditoras (tempo de trabalho na organização e na função, emprego anterior, gênero, estado civil, escolaridade e idade. Foram desenvolvidos questionários, de acordo com o método de análise de papel ocupacional. Esses questionários foram aplicados em 898 bancários e seus supervisores imediatos. Os resultados sugeriram que a metodologia parece ser adequada para analisar necessidades de treinamento. Mostraram também que existe relação significativa entre auto e hetero-avaliação de necessidades de treinamento, embora supervisores tendam a apontar maiores necessidades de treinamento, em seus subordinados, do que as auto-avaliações destes mesmos.The objectives of the present study were: to develop a training needs assessment methodology that included attitudes; to study the relationship between self and hetero assessment, by assessing knowledge, skills and attitudes; and to evaluate the relationship between self-assessment and some predicting variables (work experience at the organizational and occupational levels, prior job experience, gender, marital status, schooling and age. Questionnaires were developed, following the method of occupational role analysis. These questionnaires were applied in 898 bank employees and their immediate supervisors. Results have suggested that the methodology seems to be appropriate for analyzing training needs. They have also shown that there is a significant relationship between self and hetero assessments of training needs. However, supervisors tend to point higher training needs, in their subordinates, than the self-assessments made by the latter.

  13. Red light emission from ZnO:Eu"3"+|CuSCN hetero-junction under cathodic polarization

    International Nuclear Information System (INIS)

    Sirimanne, P.M.; Minoura, H.

    2015-01-01

    Eu"3"+ ions were bonded to ZnO ceramic via organic ligand. Surface bonded Eu"3"+ ions were exhibited specific luminescence bands due to electron transitions between f–f intra-configurationally transitions. Further enhancement of luminescence bands was observed by attaching selected oligomers to Eu"3"+ ions. A hetero-junction was prepared by depositing copper-thiocyanate on Eu"3"+ ions bonded ZnO ceramic. Red light emission was observed from surface bonded Eu"3"+ ions in ZnO:Eu"3"+|CuSCN hetero-junction under reverse bias. - Highlights: • Europium doped ZnO ceramic exhibits photo-luminescence. • Semiconductor hetro-junction was prepared. • ZnO:Eu"3"+|CuSCN hetero-junction emits red light under reverse bias.

  14. Neighboring Hetero-Atom Assistance of Sacrificial Amines to Hydrogen Evolution Using Pt-Loaded TiO2-Photocatalyst

    Directory of Open Access Journals (Sweden)

    Masahide Yasuda

    2014-05-01

    Full Text Available Photocatalytic H2 evolution was examined using Pt-loaded TiO2-photocatalyst in the presence of amines as sacrificial agents. In the case of amines with all of the carbon attached to the hetero-atom such as 2-aminoethanol, 1,2-diamonoethane, 2-amino-1,3-propanediol, and 3-amino-1,2-propanediol, they were completely decomposed into CO2 and water to quantitatively evolve H2. On the other hand, the amines with both hetero-atoms and one methyl group at the β-positions (neighboring carbons of amino group such as 2-amino-1-propanol and 1,2-diaminopropane were partially decomposed. Also, the photocatalytic H2 evolution using amines without the hetero-atoms at the β-positions such as ethylamine, propylamine, 1-butylamine, 1,3-diaminopropane, 2-propylamine, and 2-butylamine was inefficient. Thus, it was found that the neighboring hetero-atom strongly assisted the degradation of sacrificial amines. Moreover, rate constants for H2 evolution were compared among amines. In conclusion, the neighboring hetero-atom did not affect the rate constants but enhanced the yield of hydrogen evolution.

  15. HeteroGenius: A Framework for Hybrid Analysis of Heterogeneous Software Specifications

    Directory of Open Access Journals (Sweden)

    Manuel Giménez

    2014-01-01

    Full Text Available Nowadays, software artifacts are ubiquitous in our lives being an essential part of home appliances, cars, cell phones, and even in more critical activities like aeronautics and health sciences. In this context software failures may produce enormous losses, either economical or, in the worst case, in human lives. Software analysis is an area in software engineering concerned with the application of diverse techniques in order to prove the absence of errors in software pieces. In many cases different analysis techniques are applied by following specific methodological combinations that ensure better results. These interactions between tools are usually carried out at the user level and it is not supported by the tools. In this work we present HeteroGenius, a framework conceived to develop tools that allow users to perform hybrid analysis of heterogeneous software specifications. HeteroGenius was designed prioritising the possibility of adding new specification languages and analysis tools and enabling a synergic relation of the techniques under a graphical interface satisfying several well-known usability enhancement criteria. As a case-study we implemented the functionality of Dynamite on top of HeteroGenius.

  16. Respiration and body movement analysis during sleep in bed using hetero-core fiber optic pressure sensors without constraint to human activity.

    Science.gov (United States)

    Nishyama, Michiko; Miyamoto, Mitsuo; Watanabe, Kazuhiro

    2011-01-01

    We describe respiration monitoring in sleep using hetero-core fiber optic pressure sensors. The proposed hetero-core fiber optic sensor is highly sensitive to macrobending as a result of the core diameter difference due to stable single-mode transmission. Pressure sensors based on hetero-core fiber optics were fabricated to have a high sensitivity to small pressure changes resulting from minute body motions, such as respiration, during sleep and large pressure changes, such as those caused by a rollover. The sensors are installed in a conventional bed. The pressure characteristic performance of all the fabricated hetero-core fiber optic pressure sensors is found to show a monotonic response with weight changes. A respiration monitoring test in seven subjects efficiently demonstrates the effective use of eight hetero-core pressure sensors installed in a bed. Additionally, even in the case of different body postures, such as lying on one's side, a slight body movement due to respiration is detected by the hetero-core pressure sensors.

  17. Catalytic Asymmetric Total Synthesis of (+)- and (-)-Paeoveitol via a Hetero-Diels-Alder Reaction.

    Science.gov (United States)

    Li, Tian-Ze; Geng, Chang-An; Yin, Xiu-Juan; Yang, Tong-Hua; Chen, Xing-Long; Huang, Xiao-Yan; Ma, Yun-Bao; Zhang, Xue-Mei; Chen, Ji-Jun

    2017-02-03

    The first catalytic asymmetric total synthesis of (+)- and (-)-paeoveitol has been accomplished in 42% overall yield via a biomimetic hetero-Diels-Alder reaction. The chiral phosphoric acid catalyzed hetero-Diels-Alder reaction showed excellent diastereo- and enantioselectivity (>99:1 dr and 90% ee); two rings and three stereocenters were constructed in a single step to produce (-)-paeoveitol on a scale of 452 mg. This strategy enabled us to selectively synthesize both paeoveitol enantiomers from the same substrates by simply changing the enantiomer of the catalyst.

  18. The step-wise pathway of septin hetero-octamer assembly in budding yeast.

    Science.gov (United States)

    Weems, Andrew; McMurray, Michael

    2017-05-25

    Septin proteins bind guanine nucleotides and form rod-shaped hetero-oligomers. Cells choose from a variety of available septins to assemble distinct hetero-oligomers, but the underlying mechanism was unknown. Using a new in vivo assay, we find that a stepwise assembly pathway produces the two species of budding yeast septin hetero-octamers: Cdc11/Shs1-Cdc12-Cdc3-Cdc10-Cdc10-Cdc3-Cdc12-Cdc11/Shs1. Rapid GTP hydrolysis by monomeric Cdc10 drives assembly of the core Cdc10 homodimer. The extended Cdc3 N terminus autoinhibits Cdc3 association with Cdc10 homodimers until prior Cdc3-Cdc12 interaction. Slow hydrolysis by monomeric Cdc12 and specific affinity of Cdc11 for transient Cdc12•GTP drive assembly of distinct trimers, Cdc11-Cdc12-Cdc3 or Shs1-Cdc12-Cdc3. Decreasing the cytosolic GTP:GDP ratio increases the incorporation of Shs1 vs Cdc11, which alters the curvature of filamentous septin rings. Our findings explain how GTP hydrolysis controls septin assembly, and uncover mechanisms by which cells construct defined septin complexes.

  19. The polar 2e/12c bond in phenalenyl-azaphenalenyl hetero-dimers: Stronger stacking interaction and fascinating interlayer charge transfer

    Energy Technology Data Exchange (ETDEWEB)

    Zhong, Rong-Lin; Li, Zhi-Ru, E-mail: hlxu@nenu.edu.cn, E-mail: lzr@jlu.edu.cn [Institute of Theoretical Chemistry, Jilin University, Changchun 130023 (China); Xu, Hong-Liang, E-mail: hlxu@nenu.edu.cn, E-mail: lzr@jlu.edu.cn [Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (China)

    2016-08-07

    An increasing number of chemists have focused on the two-electron/multicenter bond (2e/mc) that was first introduced to interpret the bonding mechanism of radical dimers. Herein, we report the polar two-electron/twelve center (2e/12c) bonding character in a series of phenalenyl-azaphenalenyl radical hetero-dimers. Interestingly, the bonding energy of weaker polar hetero-dimer (P-TAP) is dominated by the overlap of the two different singly occupied molecular orbital of radicals, while that of stronger polar hetero-dimer (P-HAP) is dominated by the electrostatic attraction. Results show that the difference between the electronegativity of the monomers plays a prominent role in the essential attribution of the polar 2e/12c bond. Correspondingly, a stronger stacking interaction in the hetero-dimer could be effectively achieved by increasing the difference of nitrogen atoms number between the monomers. It is worthy of note that an interesting interlayer charge transfer character is induced in the polar hetero-dimers, which is dependent on the difference between the electronegativity of the monomers. It is our expectation that the new knowledge about the bonding nature of radical hetero-dimers might provide important information for designing radical based functional materials with various applications.

  20. Tööturg võttis majanduslanguse löögi enda peale / Hanno Pevkur, Raul Eamets, Ivi Proos, Sten Anspal ; intervjueerinud Helle Ruusing

    Index Scriptorium Estoniae

    2010-01-01

    Sotsiaaalminister Hanno Pevkur, Tartu Ülikooli makroökonoomika õppetooli juhataja Raul Eamets, Avatud Ühiskonna Instituudi juhataja Ivi Proos ja Eesti Rakendusuuringute Keskuse CENTAR vanemanalüütik Sten Anspal arutlevad Eesti tööturu olukorra ja tulevikuperspektiivide üle

  1. Analytical model of surface potential profiles and transfer characteristics for hetero stacked tunnel field-effect transistors

    Science.gov (United States)

    Xu, Hui Fang; Sun, Wen; Han, Xin Feng

    2018-06-01

    An analytical model of surface potential profiles and transfer characteristics for hetero stacked tunnel field-effect transistors (HS-TFETs) is presented for the first time, where hetero stacked materials are composed of two different bandgaps. The bandgap of the underlying layer is smaller than that of the upper layer. Under different device parameters (upper layer thickness, underlying layer thickness, and hetero stacked materials) and temperature, the validity of the model is demonstrated by the agreement of its results with the simulation results. Moreover, the results show that the HS-TFETs can obtain predominant performance with relatively slow changes of subthreshold swing (SS) over a wide drain current range, steep average subthreshold swing, high on-state current, and large on–off state current ratio.

  2. Electrochemical synthesis of p-Cu_2O/n-ZnO nanorods hetero-junction for photovoltaic application

    International Nuclear Information System (INIS)

    Rokade, A. V.; Rondiya, S. R.; Jadhavar, A. A.; Pandharkar, S. M.; Karpe, S. D.; Diwate, K. D.; Jadkar, S. R.

    2016-01-01

    Development of high performance visible light responsive solar cell materials has attracted wide interest due to their potential applications in the energy industries. In this work, ZnO nanorods films were successfully prepared on the ITO coated glass substrates via simple three electrode electrochemical deposition route. The Cu_2O nanoparticles were then electrodeposited on the surface of ZnO nanorods to form p-Cu_2O/n-ZnO core-shell hetero-structure. The synthesized ZnO, Cu_2O films and p-Cu_2O/n-ZnO hetero-structure were characterized by low angle x-ray diffraction, scanning electron microscopy, and UV-Visible spectrophotometer. Due to the hierarchical morphologies and core-shell structure, p-Cu_2O/n-ZnO hetero-structure shows a prominent visible-light-driven photocatalytic performance under the low intensity light irradiation. The obtained results suggest that it is possible to synthesize ZnO nanorods, Cu_2O films and p-Cu_2O/n-ZnO core-shell hetero-structure by a simple, cost effective and environment friendly electrodeposition process which can be useful for water splitting and solar cell device fabrication.

  3. Total Synthesis of (+)-Cytosporolide A via a Biomimetic Hetero-Diels-Alder Reaction.

    Science.gov (United States)

    Takao, Ken-Ichi; Noguchi, Shuji; Sakamoto, Shu; Kimura, Mizuki; Yoshida, Keisuke; Tadano, Kin-Ichi

    2015-12-23

    The first total synthesis of (+)-cytosporolide A was achieved by a biomimetic hetero-Diels-Alder reaction of (-)-fuscoatrol A with o-quinone methide generated from (+)-CJ-12,373. The dienophile, highly oxygenated caryophyllene sesquiterpenoid (-)-fuscoatrol A, was synthesized from the synthetic intermediate in our previous total synthesis of (+)-pestalotiopsin A. The o-quinone methide precursor, isochroman carboxylic acid (+)-CJ-12,373, was synthesized through a Kolbe-Schmitt reaction and an oxa-Pictet-Spengler reaction. The hetero-Diels-Alder reaction of these two compounds proceeded with complete chemo-, regio-, and stereoselectivity to produce the complicated pentacyclic ring system of the cytosporolide skeleton. This total synthesis unambiguously demonstrates that natural cytosporolide A has the structure previously suggested.

  4. Normal and hetero-yellow endosperm grain sorghum as substitute ...

    African Journals Online (AJOL)

    housed in flat deck-type cages, 1,6 x 1 m, fitted with a self- feeder and an automatic water nipple. Temperatures in the ... adiabatic bomb calorimeter. Amino acid analyses, following acid hydrolysis in a .... the hetero-yellow endosperm type sorghum had the highest avarage daily gains (ADGs), whereas pigs fed the maize-.

  5. Injustice to transsexual women in a hetero-normatie healthcare system

    Directory of Open Access Journals (Sweden)

    Douglas Newman-Valentine

    2014-11-01

    Conclusion: A hetero-normative healthcare system has a negative impact on the health of transsexual women and will cause them to be marginalised. This could contribute to both homoand trans-phobia that will in turn strengthen the belief that transsexual women are un-African.

  6. Stochastic models (cooperative and non-cooperative) for NMR analysis of the hetero-association of aromatic molecules in aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Evstigneev, Maxim P. [Department of Physics, Sevastopol National Technical University, Sevastopol 99053, Crimea (Ukraine)], E-mail: max_evstigneev@mail.ru; Davies, David B. [School of Biological and Chemical Sciences, Birkbeck College, University of London, Malet Street, London WC1E 7HX (United Kingdom); Veselkov, Alexei N. [Department of Physics, Sevastopol National Technical University, Sevastopol 99053, Crimea (Ukraine)

    2006-01-25

    Stochastic cooperative (STOCH-C) and non-cooperative (STOCH-NC) models have been developed for NMR analysis of the hetero-association of aromatic compounds in solution, in order to take into account all physically meaningful association reactions of molecules in which there are no limitations on the lengths of the aggregates and complexes. These algorithmical approaches are compared with previously published basic (BASE) and generalized (GEN) analytical statistical thermodynamical models of hetero-association of biologically active aromatic molecules using the same sets of published NMR data measured under the same solution conditions (0.1 M phosphate buffer, pD = 7.1, T = 298 K). It is shown that, within experimental errors, the BASE analytical model may be used to describe molecular systems characterized by relatively small contributions of hetero-association reactions, whereas the GEN model may be applied to hetero-association reactions of any aromatic compound with different self-association properties. The STOCH-C computational algorithm enabled the effect on hetero-association of the interactions of molecules with different cooperativity parameters of self-association to be estimated for the first time and it is proposed that the algorithm for the stochastic models has great potential for detailed investigation and understanding of the interactions of aromatic molecules in solution.

  7. Stochastic models (cooperative and non-cooperative) for NMR analysis of the hetero-association of aromatic molecules in aqueous solution

    International Nuclear Information System (INIS)

    Evstigneev, Maxim P.; Davies, David B.; Veselkov, Alexei N.

    2006-01-01

    Stochastic cooperative (STOCH-C) and non-cooperative (STOCH-NC) models have been developed for NMR analysis of the hetero-association of aromatic compounds in solution, in order to take into account all physically meaningful association reactions of molecules in which there are no limitations on the lengths of the aggregates and complexes. These algorithmical approaches are compared with previously published basic (BASE) and generalized (GEN) analytical statistical thermodynamical models of hetero-association of biologically active aromatic molecules using the same sets of published NMR data measured under the same solution conditions (0.1 M phosphate buffer, pD = 7.1, T = 298 K). It is shown that, within experimental errors, the BASE analytical model may be used to describe molecular systems characterized by relatively small contributions of hetero-association reactions, whereas the GEN model may be applied to hetero-association reactions of any aromatic compound with different self-association properties. The STOCH-C computational algorithm enabled the effect on hetero-association of the interactions of molecules with different cooperativity parameters of self-association to be estimated for the first time and it is proposed that the algorithm for the stochastic models has great potential for detailed investigation and understanding of the interactions of aromatic molecules in solution

  8. Analytical Modeling of Triple-Metal Hetero-Dielectric DG SON TFET

    Science.gov (United States)

    Mahajan, Aman; Dash, Dinesh Kumar; Banerjee, Pritha; Sarkar, Subir Kumar

    2018-02-01

    In this paper, a 2-D analytical model of triple-metal hetero-dielectric DG TFET is presented by combining the concepts of triple material gate engineering and hetero-dielectric engineering. Three metals with different work functions are used as both front- and back gate electrodes to modulate the barrier at source/channel and channel/drain interface. In addition to this, front gate dielectric consists of high-K HfO2 at source end and low-K SiO2 at drain side, whereas back gate dielectric is replaced by air to further improve the ON current of the device. Surface potential and electric field of the proposed device are formulated solving 2-D Poisson's equation and Young's approximation. Based on this electric field expression, tunneling current is obtained by using Kane's model. Several device parameters are varied to examine the behavior of the proposed device. The analytical model is validated with TCAD simulation results for proving the accuracy of our proposed model.

  9. Advanced Optoelectronic Devices based on Si Quantum Dots/Si Nanowires Hetero-structures

    International Nuclear Information System (INIS)

    Xu, J; Zhai, Y Y; Cao, Y Q; Chen, K J

    2017-01-01

    Si quantum dots are currently extensively studied since they can be used to develop many kinds of optoelectronic devices. In this report, we review the fabrication of Si quantum dots (Si QD) /Si nanowires (Si NWs) hetero-structures by deposition of Si QDs/SiO 2 or Si QDs/SiC multilayers on Si NWs arrays. The electroluminescence and photovoltaic devices based on the formed hetero-structures have been prepared and the improved performance is confirmed. It is also found that the surface recombination via the surface defects states on the Si NWs, especially the ones obtained by the long-time etching, may deteriorate the device properties though they exhibit the better anti-reflection characteristics. The possible surface passivation approaches are briefly discussed. (paper)

  10. Optical and mode-locking properties of InGaN/GaN based hetero-structures

    International Nuclear Information System (INIS)

    Irshad, A.

    2011-01-01

    Short wavelength pulsed lasers are indispensable for high density and high speed optical data acquisition, storage and transfer applications. Passively mode-locked blue lasers are an attractive alternative for blue laser sources achieved by non-linear frequency conversion techniques. Although over the recent years it has been shown that InGaN/GaN based hetero-structures can be used as potential material for the fabrication of saturable absorbers, passive mode-locking in the blue spectral range has not been realized yet. The main reason for that is the complicated microscopic nature of InGaN/GaN materials and the difficulty to control the dynamics of photo-induced carriers which determine mode-locking properties of the material. In this work, we have characterized different InGaN based hetero-structures as potential saturable absorbers. Three different groups of the samples have been investigated: i) quantum well samples with different numbers of quantum wells grown under optimal conditions; ii)quantum well samples with modified optical properties due to different buffer layer thickness and postgrowth treatment; iii) a multilayered quantum dot sample. The characterized quantum well samples exhibit relatively high optical quality and sufficiently high saturable losses (which can be controlled by alternating a number of the quantum wells). Nevertheless, they have two major disadvantages as saturable absorbers, namely, a very long absorption recovery time (in the order of a few nanoseconds) and a rather high saturation fluence. The long recovery times are not desirable for achieving a stable and self-starting mode-locking without Q-switching. In order to understand the relaxation processes of photo-induced carriers that determine the absorption recovery times of the saturable absorbers, optical properties of the hetero-structures have been extensively studied by using the frequency and time resolved photo-luminescence technique. The obtained data reveal that, directly

  11. Hetero-interaction between Gouy-Stern double layers : charge and potential regulation

    NARCIS (Netherlands)

    Lyklema, J.; Duval, J.F.L.

    2005-01-01

    This issue of Advances is devoted to the memory of Hans-Joachim Schulze who, before his untimely death, made substantial contributions in the domains of flotation, wetting and particle interaction, often under adverse working conditions. Many of his publications involve hetero-interaction between

  12. Dscam1 web server: online prediction of Dscam1 self- and hetero-affinity.

    Science.gov (United States)

    Marini, Simone; Nazzicari, Nelson; Biscarini, Filippo; Wang, Guang-Zhong

    2017-06-15

    Formation of homodimers by identical Dscam1 protein isomers on cell surface is the key factor for the self-avoidance of growing neurites. Dscam1 immense diversity has a critical role in the formation of arthropod neuronal circuit, showing unique evolutionary properties when compared to other cell surface proteins. Experimental measures are available for 89 self-binding and 1722 hetero-binding protein samples, out of more than 19 thousands (self-binding) and 350 millions (hetero-binding) possible isomer combinations. We developed Dscam1 Web Server to quickly predict Dscam1 self- and hetero- binding affinity for batches of Dscam1 isomers. The server can help the study of Dscam1 affinity and help researchers navigate through the tens of millions of possible isomer combinations to isolate the strong-binding ones. Dscam1 Web Server is freely available at: http://bioinformatics.tecnoparco.org/Dscam1-webserver . Web server code is available at https://gitlab.com/ne1s0n/Dscam1-binding . simone.marini@unipv.it or guangzhong.wang@picb.ac.cn. Supplementary data are available at Bioinformatics online. © The Author 2017. Published by Oxford University Press. All rights reserved. For Permissions, please e-mail: journals.permissions@oup.com

  13. Experimental and numerical investigation of hetero-/homogeneous combustion-based HCCI of methane–air mixtures in free-piston micro-engines

    International Nuclear Information System (INIS)

    Chen, Junjie; Liu, Baofang; Gao, Xuhui; Xu, Deguang

    2016-01-01

    Highlights: • Single-shot experiments and a transient model of micro-engine were presented. • Coupled combustion can significantly improve in-cylinder temperatures. • Coupled combustion can reduce mass losses and compression ratios. • Heterogeneous reactions cause earlier ignition. • Heat losses result in higher mass losses. - Abstract: The hetero-/homogenous combustion-based HCCI (homogeneous charge compression ignition) of fuel–lean methane–air mixtures over alumina-supported platinum catalysts was investigated experimentally and numerically in free-piston micro-engines without ignition sources. Single-shot experiments were carried out in the purely homogeneous and coupled hetero-/homogeneous combustion modes, involved temperature measurements, capturing the visible combustion image sequences, exhaust gas analysis, and the physicochemical characterization of catalysts. Simulations were performed with a two-dimensional transient model that includes detailed hetero-/homogeneous chemistry and transport, leakage, and free-piston motion to gain physical insight and to explore the hetero-/homogeneous combustion characteristics. The micro-engine performance concerning combustion efficiency, mass loss, energy density, and free-piston dynamics was investigated. The results reveal that both purely homogeneous and coupled hetero-/homogeneous combustion of methane–air mixtures in a narrow cylinder with a diameter of 3 mm and a height of approximately 0.3 mm are possible. The coupled hetero-/homogeneous mode can not only significantly improve the combustion efficiency, in-cylinder temperature and pressure, output power and energy density, but also reduce the mass loss because of its lower compression ratio and less time spent around TDC (top dead center) and during the expansion stroke, indicating that this coupled mode is a promising combustion scheme for micro-engine. Heat losses result in higher mass losses. Heterogeneous reactions cause earlier ignition

  14. Biomedical Applications of Gold Nanoparticles Functionalized Using Hetero-Bifunctional Poly(ethylene glycol) Spacer

    National Research Council Canada - National Science Library

    Fu, Wei; Shenoy, Dinesh; Li, Jane; Crasto, Curtis; Jones, Graham; Dimarzio, Charles; Sridhar, Srinivas; Amiji, Mansoor

    2005-01-01

    To increase the targeting potential, circulation time, and the flexibility of surface-attached biomedically-relevant ligands on gold nanoparticles, hetero-bifunctional poly(ethylene glycol) (PEG, MW 1,500...

  15. Band alignment studies of Al2O3/CuGaO2 and ZnO/CuGaO2 hetero-structures grown by pulsed laser deposition

    International Nuclear Information System (INIS)

    Ajimsha, R.S.; Das, Amit K.; Joshi, M.P.; Kukreja, L.M.

    2014-01-01

    Highlights: • Band offset studies at the interface of Al 2 O 3 /CuGaO 2 and ZnO/CuGaO 2 hetero-structures were performed using X-ray photoelectron spectroscopy. • Valance band offsets (VBO) of these hetero-structures were obtained from respective XPS peak positions and VB spectra using Kraut's equation. • Al 2 O 3 /CuGaO 2 interface exhibited a type I band alignment with valance band offset (VBO) of 4.05 eV whereas type II band alignment was observed in ZnO/CuGaO 2 hetero-structure with a VBO of 2.32 eV. • Schematic band alignment diagram for the interface of these hetero-structures has been constructed. • Band offset and alignment studies of these heterojunctions are important for gaining insight to the design of various optoelectronic devices based on such hetero-structures. - Abstract: We have studied the band offset and alignment of pulsed laser deposited Al 2 O 3 /CuGaO 2 and ZnO/CuGaO 2 hetero-structures using photoelectron spectroscopy. Al 2 O 3 /CuGaO 2 interface exhibited a type I band alignment with valance band offset (VBO) of 4.05 eV whereas type II band alignment was observed in ZnO/CuGaO 2 hetero-structure with a VBO of 2.32 eV. Schematic band alignment diagram for the interface of these hetero-structures has been constructed. Band offset and alignment studies of these heterojunctions are important for gaining insight to the design of various optoelectronic devices based on such hetero-structures

  16. Injustice to transsexual women in a hetero-normative healthcare system.

    Science.gov (United States)

    Newman-Valentine, Douglas; Duma, Sinegugu

    2014-11-21

    Transsexual women who are on the journey of sexual re-alignment will experience various health problems. These problems are related directly to the treatment regime that they are following in order to attain and maintain their physical embodiment as a woman. They are forced to negotiate a hetero-normative healthcare system in order to receive assistance and care for their health problems related to their sexual re-alignment process. The questions posed were: What are the unique health problems that transsexual women experience whilst on the journey of sexual re-alignment? What is the current context of the South African healthcare system in which transsexual women should negotiate healthcare? These questions were asked in order to explore the health problems with which transsexual women are faced and to describe the hetero-normative healthcare system in South Africa. An electronic literature search was executed via the EBSCO host with specific inclusion and exclusion criteria. The search words that were used were: Transsexual/s and Health/Healthcare. All studies had to be peer reviewed and published in the English language, from January 1972 up until February 2013. Literature on transsexual children was excluded. Transsexual women have the potential to suffer significant side-effects from their sexual re-alignment treatment, including cardio-vascular problems, endocrine problems and mental ill-health. They are also vulnerable to HIV infection. They have poor access to quality holistic healthcare and this may lead an increase in the mortality and morbidity figures of women. A hetero-normative healthcare system has a negative impact on the health of transsexual women and will cause them to be marginalised. This could contribute to both homo- and trans-phobia that will in turn strengthen the belief that transsexual women are un-African.

  17. A flexible tactile sensitive sheet using a hetero-core fiber optic sensor

    Science.gov (United States)

    Fujino, S.; Yamazaki, H.; Hosoki, A.; Watanabe, K.

    2014-05-01

    In this report, we have designed a tactile sensitive sheet based on a hetero-core fiber-optic sensor, which realize an areal sensing by using single sensor potion in one optical fiber line. Recently, flexible and wide-area tactile sensing technology is expected to applied to acquired biological information in living space and robot achieve long-term care services such as welfare and nursing-care and humanoid technology. A hetero-core fiber-optic sensor has several advantages such as thin and flexible transmission line, immunity to EMI. Additionally this sensor is sensitive to moderate bending actions with optical loss changes and is independent of temperature fluctuation. Thus, the hetero-core fiber-optic sensor can be suitable for areal tactile sensing. We measure pressure characteristic of the proposed sensitive sheet by changing the pressure position and pinching characteristic on the surface. The proposed tactile sensitive sheet shows monotonic responses on the whole sensitive sheet surface although different sensitivity by the position is observed at the sensitive sheet surface. Moreover, the tactile sensitive sheet could sufficiently detect the pinching motion. In addition, in order to realize the discrimination between pressure and pinch, we fabricated a doubled-over sensor using a set of tactile sensitive sheets, which has different kinds of silicon robbers as a sensitive sheet surface. In conclusion, the flexible material could be given to the tactile sensation which is attached under proposed sensitive sheet.

  18. Metal-catalyzed Asymmetric Hetero-Diels-Alder Reactions of Unactivated Dienes with Glyoxylates

    DEFF Research Database (Denmark)

    Johannsen, Mogens; Yao, Sulan; Graven, Anette

    1998-01-01

    The development of a catalytic asymmetric hetero-Diels-Alder methodology for the reaction of unactivated dienes with glyoxylates is presented. Several different asymmetric catalysts can be used, but copper-bisoxazolines and aluminium-BINOL give the highest yield, and the best chemo...

  19. HETERO code, heterogeneous procedure for reactor calculation

    International Nuclear Information System (INIS)

    Jovanovic, S.M.; Raisic, N.M.

    1966-11-01

    This report describes the procedure for calculating the parameters of heterogeneous reactor system taking into account the interaction between fuel elements related to established geometry. First part contains the analysis of single fuel element in a diffusion medium, and criticality condition of the reactor system described by superposition of elements interactions. the possibility of performing such analysis by determination of heterogeneous system lattice is described in the second part. Computer code HETERO with the code KETAP (calculation of criticality factor η n and flux distribution) is part of this report together with the example of RB reactor square lattice

  20. The effect of Bi{sub In} hetero-antisite defects in In{sub 1–x}PBi{sub x} alloy

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Liyuan [State Key Laboratory of Information Photonics and Optical Communications, Ministry of Education, Beijing University of Posts and Telecommunications, P.O. Box 72, Beijing 100876 (China); Lu, Pengfei, E-mail: photon.bupt@gmail.com [State Key Laboratory of Information Photonics and Optical Communications, Ministry of Education, Beijing University of Posts and Telecommunications, P.O. Box 72, Beijing 100876 (China); State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China); Yang, Chuanghua [School of Physics and Telecommunication Engineering, Shanxi University of Technology (SNUT), Hanzhong 723001, Shaanxi (China); Liang, Dan [State Key Laboratory of Information Photonics and Optical Communications, Ministry of Education, Beijing University of Posts and Telecommunications, P.O. Box 72, Beijing 100876 (China); Zhang, Chunfang [Beijing Computational Science Research Center, Beijing 100094 (China); Wang, Shumin [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China); Photonics Laboratory, Department of Microtechnology and Nanoscience, Chalmers University of Technology, 41296 Gothenburg (Sweden)

    2016-07-25

    Bi{sub In} hetero-antisite defects in InP:Bi alloy is performed by using first-principle calculations. It is found that the hetero-antisite defect Bi{sub In} is energetically easier than Bi{sub P}. This Bi{sub In} defect is a deep level donor, and the related defect band is introduced by the sp-hybridization mainly between the 6s state of Bi{sub In} and 3p states of the nearest P atoms. The band gap of InP:Bi alloy increases slightly with the increase of Bi compositions, and the relative position of the defect level remains almost unchanged. These results represent that hetero-antisite defect Bi{sub In} does not contribute to the reduction of the band gap of InP:Bi alloy. The calculations of optical properties show that hetero-antisite defect Bi{sub In} can contribute to the red shift phenomena observed in experiment as the Bi composition increases. In addition, the interaction of two Bi{sub In} atoms can result in the split of the impurity band and cause a strong absorption in near-infrared region, indicating it can be a potential candidate for optoelectronics application. - Highlights: • The effects of Bi{sub In} hetero-antisite defects in InP:Bi alloy are studied. • The appearance and origin of Bi{sub In} related impurity band are discovered. • Bi{sub In} defects can contribute to the red shift phenomena observed in experiment. • A strong absorption in near-infrared region caused by two Bi{sub In} atoms is found.

  1. A novel hetero-material gate-underlap electrically doped TFET for improving DC/RF and ambipolar behaviour

    Science.gov (United States)

    Yadav, Shivendra; Sharma, Dheeraj; Chandan, Bandi Venkata; Aslam, Mohd; Soni, Deepak; Sharma, Neeraj

    2018-05-01

    In this article, the impact of gate-underlap with hetero material (low band gap) has been investigated in terms of DC and Analog/RF parameters by proposed device named as hetero material gate-underlap electrically doped TFET (HM-GUL-ED-TFET). Gate-underlap resolves the problem of ambipolarity, gate leakage current (Ig) and slightly improves the gate to drain capacitance, but DC performance is almost unaffected. Further, the use of low band gap material (Si0.5 Ge) in proposed device causes a drastic improvement in the DC as well as RF figures of merit. We have investigated the Si0.5 Ge as a suitable candidate among different low band gap materials. In addition, the sensitivity of gate-underlap in terms of gate to drain inversion and parasitic capacitances has been studied for HM-GUL-ED-TFET. Further, relatively it is observed that gate-underlap is a better way than drain-underlap in the proposed structure to improve Analog/RF performances without degrading the DC parameters of device. Additionally, hetero-junction alignment analysis has been done for fabrication feasibility.

  2. Auto and hetero-associative memory using a 2-D optical logic gate

    Science.gov (United States)

    Chao, Tien-Hsin (Inventor)

    1992-01-01

    An optical system for auto-associative and hetero-associative recall utilizing Hamming distance as the similarity measure between a binary input image vector V(sup k) and a binary image vector V(sup m) in a first memory array using an optical Exclusive-OR gate for multiplication of each of a plurality of different binary image vectors in memory by the input image vector. After integrating the light of each product V(sup k) x V(sup m), a shortest Hamming distance detection electronics module determines which product has the lowest light intensity and emits a signal that activates a light emitting diode to illuminate a corresponding image vector in a second memory array for display. That corresponding image vector is identical to the memory image vector V(sup m) in the first memory array for auto-associative recall or related to it, such as by name, for hetero-associative recall.

  3. Synthesis and thermal properties of hetero-bifunctional PLA oligomers and their stereocomplexes

    NARCIS (Netherlands)

    ten Breteler, M.R.; Feijen, Jan; Dijkstra, Pieter J.; Signori, F.; Signori, F.

    2013-01-01

    Abstract Hetero-telechelic, low-molecular-weight polylactides (PLAs) were prepared by the zinc-catalyzed ring-opening polymerization of l-lactide or d-lactide using functional initiators and subsequent reaction with termination reagents, yielding –OH, –COOH, –NH2 and –SH as functional chain ends.

  4. Effects of radiation on hetero-atom-containing polyacetylenes

    International Nuclear Information System (INIS)

    Yamaoka, H.; Matsuyama, T.; Masuda, T.; Higashimura, T.

    1991-01-01

    The effects of radiation on several substituted polyacetylenes containing hetero-atoms such as silicon and chlorine were studied. All the polymers containing silicon atoms degraded in the presence of air, whereas no degradation proceeded in vacuo. In the case of polymers containing chlorine atoms, degradation and crosslinking occurred simultaneously, both in air and in vacuo. The reaction mode of these polymers was found to be strongly dependent on the nature of the substituents. The relationship between the radiation sensitivity and thermal stability of substituted polyacetylenes is discussed on the basis of the obtained results. (author)

  5. DOE Energy Frontiers Research Center for Heterogeneous Functional Materials; the “HeteroFoaM Center”

    Energy Technology Data Exchange (ETDEWEB)

    Reifsnider, Kenneth Leonard [Univ. of South Carolina, Columbia, SC (United States)

    2016-11-03

    Synopsis of five year accomplishments: Devices that convert and store energy are generally made from heterogeneous constituent materials that act and interact to selectively conduct, transport, and separate mass, heat, and charge. Controlling these actions and interactions enables the technical breakthroughs that have made fuel cells, batteries, and solid state membranes, for example, essential parts of our society. In the biological sense, these materials are ‘vascular’ rather than primitive ‘cellular’ materials, in which the arrangements and configurations of the constituents (including their void phases) play essential and definitive roles in their functional capabilities. In 2009 a group of investigators, with lifetime investments of effort in the understanding of heterogeneous materials, recognized that the design of such material systems is not an optimization problem as such. Local interactions of the constituents create “emergent” properties and responses that are not part of the formal set of constituent characteristics, in much the same sense that society and culture is created by the group interactions of the people involved. The design of emergent properties is an open question in all formal science, but for energy materials the lack of this foundation science relegates development tasks to Edisonian trial and error, with anecdotal success and frequent costly failures. That group defined, for the first time, multi-scale heterogeneous functional materials with functional disordered and void phase regions as “HeteroFoaM,” and formed the first multidisciplinary research team to define and codify the foundation science of that material class. The primary goal of the HeteroFoaM Center was, and is, to create and establish the multi-scale fundamental knowledge and related methodology required for the rational and systematic multiphysics design of heterogeneous functional materials and their interfaces and surfaces for applications in energy

  6. Hydrogen doping of Indium Tin Oxide due to thermal treatment of hetero-junction solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Ritzau, Kurt-Ulrich, E-mail: kurt-ulrich.ritzau@ise.fraunhofer.de [Fraunhofer Institute for Solar Energy Systems (ISE), Heidenhofstrasse 2, 79110 Freiburg (Germany); Behrendt, Torge [Infineon Technologies, Max-Planck-Straße 5, 59581 Warstein (Germany); Palaferri, Daniele [Laboratoire Matériaux et Phénomènes Quantiques, Université Paris Diderot, Sorbonne Paris Cité, CNRS—UMR 7162, 75013 Paris (France); Bivour, Martin; Hermle, Martin [Fraunhofer Institute for Solar Energy Systems (ISE), Heidenhofstrasse 2, 79110 Freiburg (Germany)

    2016-01-29

    Indium Tin Oxide (ITO) layers in silicon hetero junction solar cells change their electrical and optical properties when exposed to temperature treatments. Hydrogen which effuses from underlying amorphous silicon layers is identified to dope the ITO layer. This leads to an additional increase in conductivity. In this way an almost isolating ITO can become degenerately doped through temperature treatments. The resulting carrier density in the range of 10{sup 20} cm{sup −3} leads to a substantial increase in free carrier absorption, which in turn leads to an increased parasitic absorption in the cell device. Thus hydrogen effusion in silicon hetero-junction (SHJ) solar cells does not only affect the degradation of amorphous silicon (a-Si:H) passivation of crystalline silicon (c-Si), but also the electrical and optical properties of both front and back ITO layers. This leads to the further design rule for SHJ solar cells, meaning that ITO properties have to be optimized in the state after modification during temperature treatment. - Highlights: • ITO is additionally doped by heat treatment of silicon hetero-junction solar cells. • The discovered effect turns an almost isolating ITO into a degenerately doped TCO. • TCO properties have to be considered as measured in the final cell.

  7. Theoretical evaluation of two dimensional electron gas characteristics of quaternary AlxInyGa1-x-yN/GaN hetero-junctions

    Science.gov (United States)

    Rahbardar Mojaver, Hassan; Manouchehri, Farzin; Valizadeh, Pouya

    2016-04-01

    The two dimensional electron gas (2DEG) characteristics of gated metal-face wurtzite AlInGaN/GaN hetero-junctions including positions of subband energy levels, fermi energy level, and the 2DEG concentration as functions of physical and compositional properties of the hetero-junction (i.e., barrier thickness and metal mole-fractions) are theoretically evaluated using the variational method. The calculated values of the 2DEG concentration are in good agreement with the sparsely available experimental data reported in the literature. According to our simulation results, a considerable shift in the positive direction of threshold voltage of AlInGaN/GaN hetero-junction field-effect transistors can be achieved by engineering both the spontaneous and the piezoelectric polarizations using a quaternary AlInGaN barrier-layer of appropriate mole-fractions.

  8. Tandem Reaction of Cationic Copolymerization and Concertedly Induced Hetero-Diels-Alder Reaction Preparing Sequence-Regulated Polymers.

    Science.gov (United States)

    Matsumoto, Suzuka; Kanazawa, Arihiro; Kanaoka, Shokyoku; Aoshima, Sadahito

    2017-06-14

    A unique tandem reaction of sequence-controlled cationic copolymerization and site-specific hetero-Diels-Alder (DA) reaction is demonstrated. In the controlled cationic copolymerization of furfural and 2-acetoxyethyl vinyl ether (AcOVE), only the furan ring adjacent to the propagating carbocation underwent the hetero-DA reaction with the aldehyde moiety of another furfural molecule. A further and equally important feature of the copolymerization is that the obtained copolymers had unprecedented 2:(1 + 1)-type alternating structures of repeating sequences of two VE and one furfural units in the main chain and one furfural unit in the side chain. The specific DA reaction is attributed to the delocalization of the positive charge to the side furan ring.

  9. Synthesis of Polyfunctional Diorganomagnesium and Diorganozinc Reagents through In Situ Trapping Halogen-Lithium Exchange of Highly Functionalized (Hetero)aryl Halides in Continuous Flow.

    Science.gov (United States)

    Ketels, Marthe; Ganiek, Maximilian A; Weidmann, Niels; Knochel, Paul

    2017-10-02

    We report a halogen-lithium exchange performed in the presence of various metal salts (ZnCl 2 , MgCl 2 ⋅LiCl) on a broad range of sensitive bromo- or iodo(hetero)arenes using BuLi or PhLi as the exchange reagent and a commercially available continuous-flow setup. The resulting diarylmagnesium or diarylzinc species were trapped with various electrophiles, resulting in the formation of polyfunctional (hetero)arenes in high yields. This method enables the functionalization of (hetero)arenes containing highly sensitive groups such as an isothiocyanate, nitro, azide, or ester. A straightforward scale-up was possible without further optimization. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Efficient Pd@MIL-101(Cr) hetero-catalysts for 2-butyne-1,4-diol hydrogenation exhibiting high selectivity

    KAUST Repository

    Yin, Dongdong

    2017-01-05

    Pd@MIL-101(Cr) hetero-catalysts have been successfully prepared using the metal-organic chemical vapour deposition (MOCVD) approach, by choosing [Pd(η-CH)(η-CH)] as a volatile precursor, and the hydrothermally stable metal-organic framework, MIL-101(Cr) as a support. The prepared Pd@MIL-101(Cr) hetero-catalysts characterized with various analytical techniques, exhibited highly monodispersed immobilized Pd nanoparticles in the MIL-101(Cr) cavities, while retaining the pristine crystallinity and porosity. The intact hybrid Pd@MIL-101(Cr) has been demonstrated to be an efficient catalyst for 2-butyne-1,4-diol hydrogenation with excellent activity, stability and selectivity (2-butene-1,4-diol (>94%)).

  11. NADP+ binding to the regulatory subunit of methionine adenosyltransferase II increases intersubunit binding affinity in the hetero-trimer.

    Directory of Open Access Journals (Sweden)

    Beatriz González

    Full Text Available Mammalian methionine adenosyltransferase II (MAT II is the only hetero-oligomer in this family of enzymes that synthesize S-adenosylmethionine using methionine and ATP as substrates. Binding of regulatory β subunits and catalytic α2 dimers is known to increase the affinity for methionine, although scarce additional information about this interaction is available. This work reports the use of recombinant α2 and β subunits to produce oligomers showing kinetic parameters comparable to MAT II purified from several tissues. According to isothermal titration calorimetry data and densitometric scanning of the stained hetero-oligomer bands on denatured gels, the composition of these oligomers is that of a hetero-trimer with α2 dimers associated to single β subunits. Additionally, the regulatory subunit is able to bind NADP(+ with a 1:1 stoichiometry, the cofactor enhancing β to α2-dimer binding affinity. Mutants lacking residues involved in NADP(+ binding and N-terminal truncations of the β subunit were able to oligomerize with α2-dimers, although the kinetic properties appeared altered. These data together suggest a role for both parts of the sequence in the regulatory role exerted by the β subunit on catalysis. Moreover, preparation of a structural model for the hetero-oligomer, using the available crystal data, allowed prediction of the regions involved in β to α2-dimer interaction. Finally, the implications that the presence of different N-terminals in the β subunit could have on MAT II behavior are discussed in light of the recent identification of several splicing forms of this subunit in hepatoma cells.

  12. Interactions between polystyrene microplastics and marine phytoplankton lead to species-specific hetero-aggregation.

    Science.gov (United States)

    Long, Marc; Paul-Pont, Ika; Hégaret, Hélène; Moriceau, Brivaela; Lambert, Christophe; Huvet, Arnaud; Soudant, Philippe

    2017-09-01

    To understand the fate and impacts of microplastics (MP) in the marine ecosystems, it is essential to investigate their interactions with phytoplankton as these may affect MP bioavailability to marine organisms as well as their fate in the water column. However, the behaviour of MP with marine phytoplanktonic cells remains little studied and thus unpredictable. The present study assessed the potential for phytoplankton cells to form hetero-aggregates with small micro-polystyrene (micro-PS) particles depending on microalgal species and physiological status. A prymnesiophycea, Tisochrysis lutea, a dinoflagellate, Heterocapsa triquetra, and a diatom, Chaetoceros neogracile, were exposed to micro-PS (2 μm diameter; 3.96 μg L -1 ) during their growth culture cycles. Micro-PS were quantified using an innovative flow-cytometry approach, which allowed the monitoring of the micro-PS repartition in microalgal cultures and the distinction between free suspended micro-PS and hetero-aggregates of micro-PS and microalgae. Hetero-aggregation was observed for C. neogracile during the stationary growth phase. The highest levels of micro-PS were "lost" from solution, sticking to flasks, with T. lutea and H. triquetra cultures. This loss of micro-PS sticking to the flask walls increased with the age of the culture for both species. No effects of micro-PS were observed on microalgal physiology in terms of growth and chlorophyll fluorescence. Overall, these results highlight the potential for single phytoplankton cells and residual organic matter to interact with microplastics, and thus potentially influence their distribution and bioavailability in experimental systems and the water column. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. Synthesis and optical spectroscopy of (hetero)-nanocrystals: An exciting interplay between Chemistry and Physics

    NARCIS (Netherlands)

    Groeneveld, E.

    2012-01-01

    This thesis describes the synthesis and study of the optical properties of various colloidal semiconductor (hetero)nanocrystals ((H)NCs). Before the experimental results are discussed in detail, the essential theoretical background on the chemical and physical aspects of this work is provided in

  14. Emission switching in carbon dots coated CdTe quantum dots driving by pH dependent hetero-interactions

    Energy Technology Data Exchange (ETDEWEB)

    Dai, Xiao; Wang, Hao; Yi, Qinghua; Wang, Yun; Cong, Shan; Zhao, Jie; Sun, Yinghui; Zou, Guifu, E-mail: zouguifu@suda.edu.cn, E-mail: jiexiong@uestc.edu.cn [College of Physics, Optoelectronics and Energy and Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215006 (China); Qian, Zhicheng [School of Electronic and Information Engineering, Xi' an Jiaotong University, Xi' an 710049 (China); Huang, Jianwen; Xiong, Jie, E-mail: zouguifu@suda.edu.cn, E-mail: jiexiong@uestc.edu.cn [State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054 (China); Luo, Hongmei [Department of Chemical and Materials Engineering, New Mexico State University, Las Cruces, New Mexico 88003 (United States)

    2015-11-16

    Due to the different emission mechanism between fluorescent carbon dots and semiconductor quantum dots (QDs), it is of interest to explore the potential emission in hetero-structured carbon dots/semiconducting QDs. Herein, we design carbon dots coated CdTe QDs (CDQDs) and investigate their inherent emission. We demonstrate switchable emission for the hetero-interactions of the CDQDs. Optical analyses indicate electron transfer between the carbon dots and the CdTe QDs. A heterojunction electron process is proposed as the driving mechanism based on N atom protonation of the carbon dots. This work advances our understanding of the interaction mechanism of the heterostructured CDQDs and benefits the future development of optoelectronic nanodevices with new functionalities.

  15. Elemental and Microscopic Analysis of Naturally Occurring C-O-Si Hetero-Fullerene-Like Structures.

    Science.gov (United States)

    Hullavarad, Nilima V; Hullavarad, Shiva S; Fochesatto, Javier

    2015-03-01

    Carbon exhibits an ability to form a wide range of structures in nature. Under favorable conditions, carbon condenses to form hollow, spheroid fullerenes in an inert atmosphere. Using high resolution FESEM, we have concealed the existence of giant hetero-fullerene like structures in the natural form. Clear, distinct features of connected hexagons and pentagons were observed. Energy dispersive X-ray analysis depth-profile of natural fullerene structures indicates that Russian-doll-like configurations composed of C, 0, and Si rings exist in nature. The analysis is based on an outstanding molecular feature found in the size fraction of aerosols having diameters 150 nm to 1.0 µm. The fullerene like structures, which are ~ 150 nm in diameter, are observed in large numbers. To the best of our knowledge, this is the first direct detailed observation of natural fullerene-like structures. This article reports inadvertent observation of naturally occurring hetero-fullerene-like structures in the Arctic.

  16. Self-sacrifice Template Formation of Hollow Hetero-Ni7S6/Co3S4 Nanoboxes with Intriguing Pseudo-capacitance for High-performance Electrochemical Capacitors

    Science.gov (United States)

    Hua, Hui; Liu, Sijia; Chen, Zhiyi; Bao, Ruiqi; Shi, Yaoyao; Hou, Linrui; Pang, Gang; Hui, Kwun Nam; Zhang, Xiaogang; Yuan, Changzhou

    2016-02-01

    Herein, we report a simple yet efficient self-sacrifice template protocol to smartly fabricate hollow hetero-Ni7S6/Co3S4 nanoboxes (Ni-Co-S NBs). Uniform nickel cobalt carbonate nanocubes are first synthesized as the precursor via solvothermal strategy, and subsequently chemically sulfidized into hollow heter-Ni-Co-S NBs through anion-exchange process. When evaluated as electrode for electrochemical capacitors (ECs), the resultant hetero-Ni-Co-S NBs visually exhibit attractive pesudo-capacitance in KOH just after continuously cyclic voltammetry (CV) scanning for 100 cycles. New insights into the underlying energy-storage mechanism of the hollow hetero-Ni-Co-S electrode, based on physicochemical characterizations and electrochemical evaluation, are first put forward that the electrochemically induced phase transformation gradually occurrs during CV sweep from the hetero-Ni-Co-S to bi-component-active NiOOH and CoOOH, which are the intrinsic charge-storage phases for the appealing Faradaic capacitance (~677 F g-1 at 4 A g-1) of hollow Ni-Co-S NBs at high rates after cycling. When further coupled with negative activated carbon (AC), the AC//hetero-Ni-Co-S asymmetric device with extended electrochemical window of 1.5 V demonstrates high specific energy density of ~31 Wh kg-1. Of significance, we strongly envision that hollow design concept and new findings here hold great promise for enriching synthetic methodologies, and electrochemistry of complex metal sulfides for next-generation ECs.

  17. Experimental evidence for the involvement of PDLIM5 in mood disorders in hetero knockout mice.

    Directory of Open Access Journals (Sweden)

    Yasue Horiuchi

    Full Text Available BACKGROUND: Reports indicate that PDLIM5 is involved in mood disorders. The PDLIM5 (PDZ and LIM domain 5 gene has been genetically associated with mood disorders; it's expression is upregulated in the postmortem brains of patients with bipolar disorder and downregulated in the peripheral lymphocytes of patients with major depression. Acute and chronic methamphetamine (METH administration may model mania and the evolution of mania into psychotic mania or schizophrenia-like behavioral changes, respectively. METHODS: To address whether the downregulation of PDLIM5 protects against manic symptoms and cause susceptibility to depressive symptoms, we evaluated the effects of reduced Pdlim5 levels on acute and chronic METH-induced locomotor hyperactivity, prepulse inhibition, and forced swimming by using Pdlim5 hetero knockout (KO mice. RESULTS: The homozygous KO of Pdlim5 is embryonic lethal. The effects of METH administration on locomotor hyperactivity and the impairment of prepulse inhibition were lower in Pdlim5 hetero KO mice than in wild-type mice. The transient inhibition of PDLIM5 (achieved by blocking the translocation of protein kinase C epsilon before the METH challenge had a similar effect on behavior. Pdlim5 hetero KO mice showed increased immobility time in the forced swimming test, which was diminished after the chronic administration of imipramine. Chronic METH treatment increased, whereas chronic haloperidol treatment decreased, Pdlim5 mRNA levels in the prefrontal cortex. Imipramine increased Pdlim5 mRNA levels in the hippocampus. CONCLUSION: These findings are partially compatible with reported observations in humans, indicating that PDLIM5 is involved in psychiatric disorders, including mood disorders.

  18. Catalytic Enantioselective Synthesis of Naturally Occurring Butenolides via Hetero-Allylic Alkylation and Ring Closing Metathesis

    NARCIS (Netherlands)

    Mao, Bin; Geurts, Koen; Fañanás-Mastral, Martín; Zijl, Anthoni W. van; Fletcher, Stephen P.; Minnaard, Adriaan J.; Feringa, Bernard

    2011-01-01

    An efficient catalytic asymmetric synthesis of chiral γ-butenolides was developed based on the hetero-allylic asymmetric alkylation (h-AAA) in combination with ring closing metathesis (RCM). The synthetic potential of the h-AAA-RCM protocol was illustrated with the facile synthesis of (-)-whiskey

  19. heteroHarvest: Harvesting Information from Heterogeneous Sources

    DEFF Research Database (Denmark)

    Qureshi, Pir Abdul Rasool; Memon, Nasrullah; Wiil, Uffe Kock

    2011-01-01

    The abundance of information regarding any topic makes the Internet a very good resource. Even though searching the Internet is very easy, what remains difficult is to automate the process of information extraction from the available online information due to the lack of structure and the diversity...... in the sharing methods. Most of the times, information is stored in different proprietary formats, complying with different standards and protocols which makes tasks like data mining and information harvesting very difficult. In this paper, an information harvesting tool (heteroHarvest) is presented...... with objectives to address these problems by filtering the useful information and then normalizing the information in a singular non hypertext format. Finally we describe the results of experimental evaluation. The results are found promising with an overall error rate equal to 6.5% across heterogeneous formats....

  20. Influence of Ti–O–Si hetero-linkages in the photocatalytic degradation of Rhodamine B

    NARCIS (Netherlands)

    Rasalingam, S; Kibombo, H.S.; Wu, C.M.; Budhi, S.; Peng, R.; Baltrusaitis, Jonas; Koodali, R.T.

    2013-01-01

    The influence of Ti–O–Si hetero-linkages in the degradation of Rhodamine B (RhB) dye over TiO2–SiO2 xerogels is exemplified by XPS analysis. We demonstrate a relationship between the percentage surface content of Ti–O–Si and the rate of photocatalytic degradation of RhB. Our detailed surface

  1. Si/Ge hetero-structure nanotube tunnel field effect transistor

    KAUST Repository

    Hanna, A. N.

    2015-01-07

    We discuss the physics of conventional channel material (silicon/germanium hetero-structure) based transistor topology mainly core/shell (inner/outer) gated nanotube vs. gate-all-around nanowire architecture for tunnel field effect transistor application. We show that nanotube topology can result in higher performance through higher normalized current when compared to nanowire architecture at Vdd-=-1-V due to the availability of larger tunneling cross section and lower Shockley-Reed-Hall recombination. Both architectures are able to achieve sub 60-mV/dec performance for more than five orders of magnitude of drain current. This enables the nanotube configuration achieving performance same as the nanowire architecture even when Vdd is scaled down to 0.5-V.

  2. Si/Ge hetero-structure nanotube tunnel field effect transistor

    KAUST Repository

    Hanna, A. N.; Hussain, Muhammad Mustafa

    2015-01-01

    We discuss the physics of conventional channel material (silicon/germanium hetero-structure) based transistor topology mainly core/shell (inner/outer) gated nanotube vs. gate-all-around nanowire architecture for tunnel field effect transistor application. We show that nanotube topology can result in higher performance through higher normalized current when compared to nanowire architecture at Vdd-=-1-V due to the availability of larger tunneling cross section and lower Shockley-Reed-Hall recombination. Both architectures are able to achieve sub 60-mV/dec performance for more than five orders of magnitude of drain current. This enables the nanotube configuration achieving performance same as the nanowire architecture even when Vdd is scaled down to 0.5-V.

  3. Efficient Pd@MIL-101(Cr) hetero-catalysts for 2-butyne-1,4-diol hydrogenation exhibiting high selectivity

    KAUST Repository

    Yin, Dongdong; Li, Chuang; Ren, Hangxing; Shekhah, Osama; Liu, Jinxuan; Liang, Changhai

    2017-01-01

    Pd@MIL-101(Cr) hetero-catalysts have been successfully prepared using the metal-organic chemical vapour deposition (MOCVD) approach, by choosing [Pd(η-CH)(η-CH)] as a volatile precursor, and the hydrothermally stable metal-organic framework, MIL-101

  4. Study of application properties of novel trisazo hetero bi-functional reactive dyes based on j-acid derivatives for cotton

    International Nuclear Information System (INIS)

    Mokhtari, Javad; Akbarzadeh, A; Phillips, D A S; Taylor, J A

    2009-01-01

    Three novel trisazo hetero bi-functional reactive dyes based on J-acid derivatives were prepared using the diazonium salt of [4-(4-sulphophenylazo-)-2,5-dimethylazobenzene-2-sulphonic acid] and a hetero bi-functional coupling component, derived from 1-hydroxy-6-aminonapthalene-3-sulphonic acid (J-acid), 1-hydroxy-6- methylaminonapthalene-3-sulphonic acid (methyl J-acid), and 1-hydroxy-6-aminonaphthalene-3,5-disulphonic acid (sulpho J-acid). On balance, the dye derived from sulpho J-acid displayed the most attractive set of technical properties, building up and fixing more efficiently than those derived from J-acid and methyl J-acid. In addition, the sulpho J-acid based dye offered better migration and, therefore, level dyeing and ease of wash off. (author)

  5. Hetero-Diels–Alder reactions of hetaryl and aryl thioketones with acetylenic dienophiles

    Directory of Open Access Journals (Sweden)

    Grzegorz Mlostoń

    2015-04-01

    Full Text Available Selected hetaryl and aryl thioketones react with acetylenecarboxylates under thermal conditions in the presence of LiClO4 or, alternatively, under high-pressure conditions (5 kbar at room temperature yielding thiopyran derivatives. The hetero-Diels–Alder reaction occurs in a chemo- and regioselective manner. The initially formed [4 + 2] cycloadducts rearrange via a 1,3-hydrogen shift sequence to give the final products. The latter were smoothly oxidized by treatment with mCPBA to the corresponding sulfones.

  6. Near Infrared Characterization of Hetero-Core Optical Fiber SPR Sensors Coated with Ta2O5 Film and Their Applications

    Directory of Open Access Journals (Sweden)

    Kazuhiro Watanabe

    2012-02-01

    Full Text Available This paper describes the characteristics of optical fiber sensors with surface plasmon resonance (SPR at 1,310 nm in which the scattering loss of silica optical fiber is low. SPR operation in the infrared wavelength range is achieved by coating a thin tantalum pentaoxide (Ta2O5 film. The novelty of this paper lies in the verification of how the hetero-core scheme could be operated as a commercial base candidate in the sense of easy fabrication, sufficient mechanical strength, and significant sensitivity as a liquid detector under the basis of a low loss transmission network in the near infrared wavelength region. The effect of Ta2O5 layer thickness has been experimentally revealed in the wavelength region extending to 1,800 nm by using the hetero-core structured optical fiber. SPR characterizations have been made in the wavelength region 1,000–1,300 nm, showing the feasible operation at the near infrared wavelength and the possible practical applications. In addition, the technique developed in this work has been interestingly applied to a multi-point water-detection and a water-level gauge in which tandem-connected SPR sensors system using hetero-core structured fibers were incorporated. The detailed performance characteristics are also shown on these applications.

  7. Design and realization of one-dimensional double hetero-structure photonic crystals for infrared-radar stealth-compatible materials applications

    International Nuclear Information System (INIS)

    Wang, Zhixun; Cheng, Yongzhi; Nie, Yan; Wang, Xian; Gong, Rongzhou

    2014-01-01

    In this paper, a new type one-dimensional (1D) double hetero-structure composite photonic crystal (CPC) for infrared-radar stealth-compatible materials applications was proposed and studied numerically and experimentally. First, based on transfer matrix method of thin-film optical theory, the propagation characteristics of the proposed structure comprising a stack of different alternating micrometer-thick layers of germanium and zinc sulfide were investigated numerically. Calculation results exhibit that this 1D single hetero-structure PC could achieve a flat high reflectivity gradually with increasing the number of the alternating media layers in a single broadband range. Then, based on principles of distributed Bragg reflector micro-cavity, a 1D double hetero-structure CPC comprising four PCs with thickness of 0.797 μm, 0.592 μm, 1.480 μm, and 2.114 μm, respectively, was proposed. Calculation results exhibit that this CPC could achieve a high reflectance of greater than 0.99 in the wavelength ranges of 3–5 μm and 8–14 μm and agreed well with experiment. Further experiments exhibit that the infrared emissivity of the proposed CPC is as low as 0.073 and 0.042 in the wavelength ranges of 3–5 μm and 8–12 μm, respectively. In addition, the proposed CPC can be used to construct infrared-radar stealth-compatible materials due to its high transmittance in radar wave band

  8. Design and realization of one-dimensional double hetero-structure photonic crystals for infrared-radar stealth-compatible materials applications

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Zhixun; Cheng, Yongzhi, E-mail: cyz0715@126.com; Nie, Yan; Wang, Xian; Gong, Rongzhou, E-mail: rzhgong@mail.hust.edu.cn [School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074 (China)

    2014-08-07

    In this paper, a new type one-dimensional (1D) double hetero-structure composite photonic crystal (CPC) for infrared-radar stealth-compatible materials applications was proposed and studied numerically and experimentally. First, based on transfer matrix method of thin-film optical theory, the propagation characteristics of the proposed structure comprising a stack of different alternating micrometer-thick layers of germanium and zinc sulfide were investigated numerically. Calculation results exhibit that this 1D single hetero-structure PC could achieve a flat high reflectivity gradually with increasing the number of the alternating media layers in a single broadband range. Then, based on principles of distributed Bragg reflector micro-cavity, a 1D double hetero-structure CPC comprising four PCs with thickness of 0.797 μm, 0.592 μm, 1.480 μm, and 2.114 μm, respectively, was proposed. Calculation results exhibit that this CPC could achieve a high reflectance of greater than 0.99 in the wavelength ranges of 3–5 μm and 8–14 μm and agreed well with experiment. Further experiments exhibit that the infrared emissivity of the proposed CPC is as low as 0.073 and 0.042 in the wavelength ranges of 3–5 μm and 8–12 μm, respectively. In addition, the proposed CPC can be used to construct infrared-radar stealth-compatible materials due to its high transmittance in radar wave band.

  9. HKUST-1 Membranes Anchored on Porous Substrate by Hetero MIL-110 Nanorod Array Seeds.

    Science.gov (United States)

    Mao, Yiyin; Cao, Wei; Li, Junwei; Sun, Luwei; Peng, Xinsheng

    2013-09-02

    Great anchors and seeds: Hetero-seeding growth processes and anchored nanorod arrays were successfully utilized in the synthesis of HKUST-1 membranes. These arrays were firmly anchored on porous substrates by using a MIL-110 nanorod array as both the anchor and seed. The resulting HKUST-1 membranes demonstrated good separation factors for binary gases exceeding the Knudson selectivity. Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Ab initio study of 3C-SiC/M (M = Ti or Al) nano-hetero interfaces

    International Nuclear Information System (INIS)

    Tanaka, Shingo; Kohyama, Masanori

    2003-01-01

    Ab initio pseudopotential calculation of 3C-SiC(1 1 1)/Al nano-hetero interfaces have been performed and interface atom species dependence (IASD) and interface orientation dependence (IOD) of nano-hetero interfaces between 3C-SiC ((1 1 1) or (0 0 1) orientation) and metal (Ti or Al) have been studied systematically. Stable atomic configurations of the 3C-SiC(1 1 1)/Al interfaces are quite different from those of the 3C-SiC(1 1 1)/Ti interfaces. Two terminated, Si-terminated (Si-TERM) and C-terminated (C-TERM), 3C-SiC(1 1 1)/Al interfaces have covalent bonding nature. In 3C-SiC/M (M = Ti or Al) nano-hetero interfaces, the C-terminated interface has relative strong, covalent and ionic C-Ti or C-Al bonds as TiC or SiC while the Si-terminated interface has various type of bonding nature, relative weak Si-Ti or Si-Al bonds from metallic character at the (0 0 1) interface to covalent character at the (1 1 1) interface. Adhesive energy (AE) shows strong IASD and IOD. The AE of the C-terminated interface is larger than that of the Si-terminated one. In the C-terminated interface, the AE of the (1 1 1) interface is smaller than that of the (0 0 1) one while in the Si-terminated interface there exists opposite interrelation. Schottky barrier height (SBH) also shows strong IASD and IOD. The SBH of the C-terminated interface is smaller than that of the Si-terminated one. The C-terminated SiC/Al interfaces have extremely small SBHs. In comparison with some experimental SBH, the present result is reliable as the difference of SBH between the two terminated interfaces and qualitative properties

  11. An Electron-Transporting Thiazole-Based Polymer Synthesized Through Direct (Hetero)Arylation Polymerization.

    Science.gov (United States)

    Chávez, Patricia; Bulut, Ibrahim; Fall, Sadiara; Ibraikulov, Olzhas A; Chochos, Christos L; Bartringer, Jérémy; Heiser, Thomas; Lévêque, Patrick; Leclerc, Nicolas

    2018-05-25

    In this work, a new n -type polymer based on a thiazole-diketopyrrolopyrrole unit has been synthesized through direct (hetero)arylation polycondensation. The molar mass has been optimized by systematic variation of the the monomer concentration. Optical and electrochemical properties have been studied. They clearly suggested that this polymer possess a high electron affinity together with a very interesting absorption band, making it a good non-fullerene acceptor candidate. As a consequence, its charge transport and photovoltaic properties in a blend with the usual P3HT electron-donating polymer have been investigated.

  12. Fundamental understanding of oxygen reduction and reaction behavior and developing high performance and stable hetero-structured cathodes

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Xingbo [West Virginia Univ., Morgantown, WV (United States)

    2016-11-14

    New unique hetero-structured cathode has been developed in this project. La2NiO4+δ (LNO) as a surface catalyst with interstitial oxygen defects was introduced onto the state-of-the-art (La0.6Sr0.4)0.95Co0.2Fe0.8O3-δ (LSCF) cathode to enhance the surface-limited ORR kinetics on SOFC cathode. Furthermore, the hetero-structured cathode surface maintains high activity under electrode polarization with much less negative effects from surface cation segregation of Sr, which is known to cause degradation issues for conventional LSCF and LSC cathodes, thus improving the cathode long-term stability. The interface chemistry distribution and oxygen transport properties have been studied to prove the enhancement of power out and stability of LNO-infiltrated LSCF cathode. The further investigation demonstrates that CeO2 & La2-xNiO4+δ (x=0-0.2) co-infiltration is a simple and cost-effective method to improve both performance and stability of LSCF cathode by limiting nano-particles growth/delamination and further improve the surface stability. For the first time, a physical model is proposed to illustrate how unique interstitial species on hetero-structured cathode surface work to regulate the exchange rate of the incorporation reaction. Meanwhile, fundamental investigation of the surface oxygen exchange and bulk oxygen transport properties under over-potential conditions across cathode materials have been carried out in this project, which were discussed and compared to the Nernst equation that is generally applied to treat any oxide electrodes under equilibrium.

  13. Interlayer couplings, Moiré patterns, and 2D electronic superlattices in MoS 2 /WSe 2 hetero-bilayers

    KAUST Repository

    Zhang, Chendong

    2017-01-07

    By using direct growth, we create a rotationally aligned MoS2/WSe2 hetero-bilayer as a designer van der Waals heterostructure. With rotational alignment, the lattice mismatch leads to a periodic variation of atomic registry between individual van der Waals layers, exhibiting a Moiré pattern with a well-defined periodicity. By combining scanning tunneling microscopy/spectroscopy, transmission electron microscopy, and first-principles calculations, we investigate interlayer coupling as a function of atomic registry. We quantitatively determine the influence of interlayer coupling on the electronic structure of the hetero-bilayer at different critical points. We show that the direct gap semiconductor concept is retained in the bilayer although the valence and conduction band edges are located at different layers. We further show that the local bandgap is periodically modulated in the X-Y direction with an amplitude of ~0.15 eV, leading to the formation of a two-dimensional electronic superlattice.

  14. S3 HMBC hetero: Spin-State-Selective HMBC for accurate measurement of long-range heteronuclear coupling constants

    DEFF Research Database (Denmark)

    Hoeck, Casper; Gotfredsen, Charlotte Held; Sørensen, Ole W.

    2017-01-01

    A novel method, Spin-State-Selective (S3) HMBC hetero, for accurate measurement of heteronuclear coupling constants is introduced. The method extends the S3 HMBC technique for measurement of homonuclear coupling constants by appending a pulse sequence element that interchanges the polarization...

  15. Synthesis of 2,5-Disubstituted Octahydroquinolin-4-ones via anIntramolecular Hetero Diels-Alder Reaction

    Directory of Open Access Journals (Sweden)

    J. Antonio Palenzuela

    2007-02-01

    Full Text Available A route for the preparation of 2,5-disubstituted octahydroquinolin-4-ones, synthetic precursors of the decahydroquinoline-type toxins, is presented. The key steps are an asymmetric epoxidation and an intramolecular hetero Diels-Alder reaction between an activated diene and an imine. The presence of an allylic stereogenic center induces some selectivity and thus only two cycloadducts are obtained in 70:30 ratio and good yield.

  16. Auto- and hetero-associative memory using a 2-D optical logic gate

    Science.gov (United States)

    Chao, Tien-Hsin

    1989-06-01

    An optical associative memory system suitable for both auto- and hetero-associative recall is demonstrated. This system utilizes Hamming distance as the similarity measure between a binary input and a memory image with the aid of a two-dimensional optical EXCLUSIVE OR (XOR) gate and a parallel electronics comparator module. Based on the Hamming distance measurement, this optical associative memory performs a nearest neighbor search and the result is displayed in the output plane in real-time. This optical associative memory is fast and noniterative and produces no output spurious states as compared with that of the Hopfield neural network model.

  17. Unconstrained pulse pressure monitoring for health management using hetero-core fiber optic sensor.

    Science.gov (United States)

    Nishiyama, Michiko; Sonobe, Masako; Watanabe, Kazuhiro

    2016-09-01

    In this paper, we present a pulse pressure waveform sensor that does not constrain a wearer's daily activity; the sensor uses hetero-core fiber optics. Hetero-core fiber sensors have been found to be sensitive to moderate bending. To detect minute pulse pressure changes from the radial artery at the wrist, we devised a fiber sensor arrangement using three-point bending supports. We analyzed and evaluated the measurement validity using wavelet transformation, which is well-suited for biological signal processing. It was confirmed that the detected pulse waveform had a fundamental mode frequency of around 1.25 Hz over the time-varying waveform. A band-pass filter with a range of frequencies from 0.85 to 1.7 Hz was used to pick up the fundamental mode. In addition, a high-pass filter with 0.85 Hz frequency eliminated arm motion artifacts; consequently, we achieved high signal-to-noise ratio. For unrestricted daily health management, it is desirable that pulse pressure monitoring can be achieved by simply placing a device on the hand without the sensor being noticed. Two types of arrangements were developed and demonstrated in which the pulse sensors were either embedded in a base, such as an armrest, or in a wearable device. A wearable device without cuff pressure using a sensitivity-enhanced fiber sensor was successfully achieved with a sensitivity of 0.07-0.3 dB with a noise floor lower than 0.01 dB for multiple subjects.

  18. The Nitrosocarbonyl Hetero-Diels–Alder Reaction as a Useful Tool for Organic Syntheses

    Science.gov (United States)

    Bodnar, Brian S.

    2014-01-01

    Organic transformations that result in the formation of multiple covalent bonds within the same reaction are some of the most powerful tools in synthetic organic chemistry. Nitrosocarbonyl hetero-Diels–Alder (HDA) reactions allow for the simultaneous stereospecific introduction of carbon–nitrogen and carbon–oxygen bonds in one synthetic step, and provide direct access to 3,6-dihydro-1,2-oxazines. This Review describes the development of the nitrosocarbonyl HDA reaction and the utility of the resulting oxazine ring in the synthesis of a variety of important, biologically active molecules. PMID:21520360

  19. Unified approach to catechin hetero-oligomers: first total synthesis of trimer EZ-EG-CA isolated from Ziziphus jujuba.

    Science.gov (United States)

    Yano, Takahisa; Ohmori, Ken; Takahashi, Haruko; Kusumi, Takenori; Suzuki, Keisuke

    2012-10-14

    A catechin hetero-trimer isolated from Ziziphus jujuba has been synthesized. Among three constituent monomers, (-)-epiafzelechin and (-)-epigallocatechin were prepared by de novo synthesis. Trimer formation relied on the unified approach to oligomers based on the bromo-capping and the orthogonal activation, reaching the reported structure of the natural product.

  20. Orgasm is gendered. A feminist exploration into the (hetero) sexual lives of young women

    OpenAIRE

    Mazzoni, Lorenza

    2011-01-01

    Italian society is still facing an enormous ???orgasm gap??? in (hetero) sexual relations: according to a very recent survey (Barbagli and co., 2010) only a minority of women reach an orgasm in every sexual intercourse, in contrast with the vast majority of men; this is true even in the younger generations. I take the lack of orgasm as a starting point for studying how sexual behaviours are still under the reign of patriarchy, imposing male standards that privilege male pleasure at the expens...

  1. Tuning Electronic Structures of BN and C Double-Wall Hetero-Nanotubes

    Directory of Open Access Journals (Sweden)

    Xueran Liu

    2015-01-01

    Full Text Available First principle calculations based on density functional theory with the generalized gradient approximation were carried out to investigate the energetic and electronic properties of carbon and boron nitride double-wall hetero-nanotubes (C/BN-DWHNTs with different chirality and size, including an armchair (n, n carbon nanotube (CNT enclosed in (m, m boron nitride nanotube (BNNT and a zigzag (n, 0 CNT enclosed in (m, 0 BNNT. The electronic structure of these DWHNTs under a transverse electric field was also investigated. The ability to tune the band gap with changing the intertube distance (di and imposing an external electric field (F of zigzag DWHNTs provides the possibility for future electronic and electrooptic nanodevice applications.

  2. Heterologous expression of an algal hydrogenase in a hetero-cystous cyanobacterium

    Energy Technology Data Exchange (ETDEWEB)

    Thorsten Heidorn; Peter Lindblad [Dept. of Physiological Botany, Uppsala University, V illavagen 6, SE-752 36 Uppsala, (Sweden)

    2006-07-01

    For the expression of an active algal [FeFe] hydrogenase in the hetero-cystous cyanobacterium Nostoc punctiforme A TCC 29133 the Chlamydomonas reinhardtii hydrogenase gene hydA1 and the accessory genes hydEF and hydG are to be introduced into the cyano-bacterial cells. The genes were amplified by PCR from EST clones, cloned into the cloning vector pBluescript SK+ and sequenced. An expression vector for multi-cistronic cloning, based on pSCR202, was constructed and for a functional test GFP was inserted as a reporter gene. The GFP construct was transformed into Nostoc punctiforme A TCC 29133 by electroporation and expression of GFP was visualized by fluorescence microscopy. (authors)

  3. Heterologous expression of an algal hydrogenase in a hetero-cystous cyanobacterium

    International Nuclear Information System (INIS)

    Thorsten Heidorn; Peter Lindblad

    2006-01-01

    For the expression of an active algal [FeFe] hydrogenase in the hetero-cystous cyanobacterium Nostoc punctiforme A TCC 29133 the Chlamydomonas reinhardtii hydrogenase gene hydA1 and the accessory genes hydEF and hydG are to be introduced into the cyano-bacterial cells. The genes were amplified by PCR from EST clones, cloned into the cloning vector pBluescript SK+ and sequenced. An expression vector for multi-cistronic cloning, based on pSCR202, was constructed and for a functional test GFP was inserted as a reporter gene. The GFP construct was transformed into Nostoc punctiforme A TCC 29133 by electroporation and expression of GFP was visualized by fluorescence microscopy. (authors)

  4. Synthesis of α- and β-lapachone derivatives from hetero diels-alder trapping of alkyl and aryl o-quinone methides

    International Nuclear Information System (INIS)

    Silva, Fernando de C. da; Ferreira, Sabrina B.; Ferreira, Vitor F.; Kaiser, Carlos R.; Pinto, Angelo C.

    2009-01-01

    Methylene and aryl o-quinone methides (o-QMs) generated by Knoevenagel condensation of 2-hydroxy-1,4-naphthoquinone with formaldehyde and arylaldehydes, undergo facile hetero Diels-Alder reaction with some substituted styrenes (as dienophiles) in aqueous ethanol media providing derivatives of α- and β-lapachone (author)

  5. Basic aspects for improving the energy conversion efficiency of hetero-junction organic photovoltaic cells.

    Science.gov (United States)

    Ryuzaki, Sou; Onoe, Jun

    2013-01-01

    Hetero-junction organic photovoltaic (OPV) cells consisting of donor (D) and acceptor (A) layers have been regarded as next-generation PV cells, because of their fascinating advantages, such as lightweight, low fabrication cost, resource free, and flexibility, when compared to those of conventional PV cells based on silicon and semiconductor compounds. However, the power conversion efficiency (η) of the OPV cells has been still around 8%, though more than 10% efficiency has been required for their practical use. To fully optimize these OPV cells, it is necessary that the low mobility of carriers/excitons in the OPV cells and the open circuit voltage (V OC), of which origin has not been understood well, should be improved. In this review, we address an improvement of the mobility of carriers/excitons by controlling the crystal structure of a donor layer and address how to increase the V OC for zinc octaethylporphyrin [Zn(OEP)]/C60 hetero-junction OPV cells [ITO/Zn(OEP)/C60/Al]. It was found that crystallization of Zn(OEP) films increases the number of inter-molecular charge transfer (IMCT) excitons and enlarges the mobility of carriers and IMCT excitons, thus significantly improving the external quantum efficiency (EQE) under illumination of the photoabsorption band due to the IMCT excitons. Conversely, charge accumulation of photo-generated carriers in the vicinity of the donor/acceptor (D/A) interface was found to play a key role in determining the V OC for the OPV cells.

  6. A Tunable and Enantioselective Hetero-Diels-Alder Reaction Provides Access to Distinct Piperidinoyl Spirooxindoles.

    Science.gov (United States)

    Jayakumar, Samydurai; Louven, Kathrin; Strohmann, Carsten; Kumar, Kamal

    2017-12-11

    The active complexes of chiral N,N'-dioxide ligands with dysprosium and magnesium salts catalyze the hetero-Diels-Alder reaction between 2-aza-3-silyloxy-butadienes and alkylidene oxindoles to selectively form 3,3'- and 3,4'-piperidinoyl spirooxindoles, respectively, in very high yields and with excellent enantioselectivities. The exo-selective asymmetric cycloaddition successfully regaled the construction of sp 3 -rich and highly substituted natural-product-based spirooxindoles supporting many chiral centers, including contiguous all-carbon quaternary centers. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Alcohol sensor based on u-bent hetero-structured fiber optic

    Science.gov (United States)

    Patrialova, Sefi N.; Hatta, Agus M.; Sekartedjo, Sekartedjo

    2016-11-01

    A sensor based on a fiber optic hetero-structure to determine the concentration of alcohol has been proposed. The structure of the sensing probe in this research is a singlemode-multimode-singlemode (SMS) which bent into Ushaped and soon called as SMS u-bent. The SMS structure was chosen to get a higher sensitivity. This research utilizes the principle of multimode interference and evanescent field by modifying the cladding with various alcohol concentration. Testing of the sensor's performance has been done by measuring the sensor's power output response to the length of the SMS fiber optic, bending diameter, and alcohol concentration. Based on the experiment result, the ubent SMS fiber optic with 50 mm bending diameter and 63 mm MMF lenght has the highest sensitivity, 3.87 dB/% and the minimum resolution, 0.26 x 10-3 %.

  8. High-speed Si/GeSi hetero-structure Electro Absorption Modulator.

    Science.gov (United States)

    Mastronardi, L; Banakar, M; Khokhar, A Z; Hattasan, N; Rutirawut, T; Bucio, T Domínguez; Grabska, K M; Littlejohns, C; Bazin, A; Mashanovich, G; Gardes, F Y

    2018-03-19

    The ever-increasing demand for integrated, low power interconnect systems is pushing the bandwidth density of CMOS photonic devices. Taking advantage of the strong Franz-Keldysh effect in the C and L communication bands, electro-absorption modulators in Ge and GeSi are setting a new standard in terms of device footprint and power consumption for next generation photonics interconnect arrays. In this paper, we present a compact, low power electro-absorption modulator (EAM) Si/GeSi hetero-structure based on an 800 nm SOI overlayer with a modulation bandwidth of 56 GHz. The device design and fabrication tolerant process are presented, followed by the measurement analysis. Eye diagram measurements show a dynamic ER of 5.2 dB at a data rate of 56 Gb/s at 1566 nm, and calculated modulator power is 44 fJ/bit.

  9. Microstructures and growth mechanisms of GaN films epitaxially grown on AlN/Si hetero-structures by pulsed laser deposition at different temperatures.

    Science.gov (United States)

    Wang, Wenliang; Yang, Weijia; Lin, Yunhao; Zhou, Shizhong; Li, Guoqiang

    2015-11-13

    2 inch-diameter GaN films with homogeneous thickness distribution have been grown on AlN/Si(111) hetero-structures by pulsed laser deposition (PLD) with laser rastering technique. The surface morphology, crystalline quality, and interfacial property of as-grown GaN films are characterized in detail. By optimizing the laser rastering program, the ~300 nm-thick GaN films grown at 750 °C show a root-mean-square (RMS) thickness inhomogeneity of 3.0%, very smooth surface with a RMS surface roughness of 3.0 nm, full-width at half-maximums (FWHMs) for GaN(0002) and GaN(102) X-ray rocking curves of 0.7° and 0.8°, respectively, and sharp and abrupt AlN/GaN hetero-interfaces. With the increase in the growth temperature from 550 to 850 °C, the surface morphology, crystalline quality, and interfacial property of as-grown ~300 nm-thick GaN films are gradually improved at first and then decreased. Based on the characterizations, the corresponding growth mechanisms of GaN films grown on AlN/Si hetero-structures by PLD with various growth temperatures are hence proposed. This work would be beneficial to understanding the further insight of the GaN films grown on Si(111) substrates by PLD for the application of GaN-based devices.

  10. A potential role of substrate as a base for deprotonation pathway in Rh-catalysed C-H amination of heteroArenes: DFT insights

    KAUST Repository

    Ajitha, Manjaly John; Huang, Kuo-Wei; Kwak, Jaesung; Kim, Hyun Jin; Chang, Sukbok; Jung, Yousung

    2016-01-01

    The possibility of direct introduction of a new functionality through C–H bond activation is an attractive strategy in covalent synthesis. Here, we investigated the mechanism of Rh-catalysed C-H amination of the hetero-aryl substrate (2

  11. Hetero-cellular prototyping by synchronized multi-material bioprinting for rotary cell culture system.

    Science.gov (United States)

    Snyder, Jessica; Son, Ae Rin; Hamid, Qudus; Wu, Honglu; Sun, Wei

    2016-01-13

    Bottom-up tissue engineering requires methodological progress of biofabrication to capture key design facets of anatomical arrangements across micro, meso and macro-scales. The diffusive mass transfer properties necessary to elicit stability and functionality require hetero-typic contact, cell-to-cell signaling and uniform nutrient diffusion. Bioprinting techniques successfully build mathematically defined porous architecture to diminish resistance to mass transfer. Current limitations of bioprinted cell assemblies include poor micro-scale formability of cell-laden soft gels and asymmetrical macro-scale diffusion through 3D volumes. The objective of this work is to engineer a synchronized multi-material bioprinter (SMMB) system which improves the resolution and expands the capability of existing bioprinting systems by packaging multiple cell types in heterotypic arrays prior to deposition. This unit cell approach to arranging multiple cell-laden solutions is integrated with a motion system to print heterogeneous filaments as tissue engineered scaffolds and nanoliter droplets. The set of SMMB process parameters control the geometric arrangement of the combined flow's internal features and constituent material's volume fractions. SMMB printed hepatocyte-endothelial laden 200 nl droplets are cultured in a rotary cell culture system (RCCS) to study the effect of microgravity on an in vitro model of the human hepatic lobule. RCCS conditioning for 48 h increased hepatocyte cytoplasm diameter 2 μm, increased metabolic rate, and decreased drug half-life. SMMB hetero-cellular models present a 10-fold increase in metabolic rate, compared to SMMB mono-culture models. Improved bioprinting resolution due to process control of cell-laden matrix packaging as well as nanoliter droplet printing capability identify SMMB as a viable technique to improve in vitro model efficacy.

  12. Hetero-cellular prototyping by synchronized multi-material bioprinting for rotary cell culture system

    International Nuclear Information System (INIS)

    Snyder, Jessica; Son, Ae Rin; Hamid, Qudus; Sun, Wei; Wu, Honglu

    2016-01-01

    Bottom-up tissue engineering requires methodological progress of biofabrication to capture key design facets of anatomical arrangements across micro, meso and macro-scales. The diffusive mass transfer properties necessary to elicit stability and functionality require hetero-typic contact, cell-to-cell signaling and uniform nutrient diffusion. Bioprinting techniques successfully build mathematically defined porous architecture to diminish resistance to mass transfer. Current limitations of bioprinted cell assemblies include poor micro-scale formability of cell-laden soft gels and asymmetrical macro-scale diffusion through 3D volumes. The objective of this work is to engineer a synchronized multi-material bioprinter (SMMB) system which improves the resolution and expands the capability of existing bioprinting systems by packaging multiple cell types in heterotypic arrays prior to deposition. This unit cell approach to arranging multiple cell-laden solutions is integrated with a motion system to print heterogeneous filaments as tissue engineered scaffolds and nanoliter droplets. The set of SMMB process parameters control the geometric arrangement of the combined flow’s internal features and constituent material’s volume fractions. SMMB printed hepatocyte-endothelial laden 200 nl droplets are cultured in a rotary cell culture system (RCCS) to study the effect of microgravity on an in vitro model of the human hepatic lobule. RCCS conditioning for 48 h increased hepatocyte cytoplasm diameter 2 μm, increased metabolic rate, and decreased drug half-life. SMMB hetero-cellular models present a 10-fold increase in metabolic rate, compared to SMMB mono-culture models. Improved bioprinting resolution due to process control of cell-laden matrix packaging as well as nanoliter droplet printing capability identify SMMB as a viable technique to improve in vitro model efficacy. (paper)

  13. Stereo- and regioselectivity of the hetero-Diels-Alder reaction of nitroso derivatives with conjugated dienes.

    Science.gov (United States)

    Brulíková, Lucie; Harrison, Aidan; Miller, Marvin J; Hlaváč, Jan

    2016-01-01

    The hetero-Diels-Alder reaction between a nitroso dienophile and a conjugated diene to give the 3,6-dihydro-2 H -1,2-oxazine scaffold is useful for the synthesis of many biologically interesting molecules due to the diverse opportunities created by subsequent transformations of the resulting 1,2-oxazine ring. This review discusses the rationale for the observed regio- and stereoselectivity and the methods developed in recent years used to control and improve the stereo- and regioselectivity for the synthesis of 1,2-oxazine scaffolds.

  14. Fast Hetero-Diels-Alder Reactions Using 4-Phenyl-1,2,4-Triazoline-3,5-Dione (PTAD) as the Dienophile

    Science.gov (United States)

    Celius, Tevye C.

    2010-01-01

    A hetero-Diels-Alder reaction that proceeds rapidly and only requires a simple filtration to purify the product is presented. The dienophile, 4-phenyl-1,2,4-triazoline-3,5-dione (PTAD), is prepared by the heterogeneous oxidation of 4-phenylurazole by the bromenium ion, Br[superscript +], generated in situ by the oxidation of potassium bromide by…

  15. Crystal Structure of the VapBC Toxin–Antitoxin Complex from Shigella flexneri Reveals a Hetero-Octameric DNA-Binding Assembly

    DEFF Research Database (Denmark)

    Dienemann, Christian; Bøggild, Andreas; Winther, Kristoffer S.

    2011-01-01

    the crystal structure of the intact Shigella flexneri VapBC TA complex, determined to 2.7 Å resolution. Both in solution and in the crystal structure, four molecules of each protein combine to form a large and globular hetero-octameric assembly with SpoVT/AbrB-type DNA-binding domains at each end and a total...

  16. 2-(Hetero(aryl)methylene)hydrazine-1-carbothioamides as potent urease inhibitors.

    Science.gov (United States)

    Saeed, Aamer; Imran, Aqeel; Channar, Pervaiz A; Shahid, Mohammad; Mahmood, Wajahat; Iqbal, Jamshed

    2015-02-01

    A small series of 2-(hetero(aryl)methylene) hydrazine-1-carbothioamides including two aryl derivatives was synthesized and tested for their inhibitory activity against urease. Compound (E)-2-(Furan-2-ylmethylene) hydrazine-1-carbothioamide (3f), having a furan ring, was the most potent inhibitor of urease with an IC50 value of 0.58 μM. Molecular modeling was carried out through docking the designed compounds into the urease binding site to predict whether these derivatives have analogous binding mode to the urease inhibitors. The study revealed that all of the tested compounds bind with both metal atoms at the active site of the enzyme. The aromatic ring of the compounds forms ionic interactions with the residues, Ala(440), Asp(494), Ala(636), and Met(637). © 2014 John Wiley & Sons A/S.

  17. High performance vertical tunneling diodes using graphene/hexagonal boron nitride/graphene hetero-structure

    Energy Technology Data Exchange (ETDEWEB)

    Hwan Lee, Seung; Lee, Jia; Ho Ra, Chang; Liu, Xiaochi; Hwang, Euyheon [Samsung-SKKU Graphene Center (SSGC), Sungkyunkwan University, 2066, Seobu-ro, Jangan-gu, Suwon, Gyeonggi-do 440-746 (Korea, Republic of); Department of Nano Science and Technology, SKKU Advanced Institute of Nano-Technology (SAINT), Sungkyunkwan University, 2066, Seobu-ro, Jangan-gu, Suwon, Gyeonggi-do 440-746 (Korea, Republic of); Sup Choi, Min [Department of Nano Science and Technology, SKKU Advanced Institute of Nano-Technology (SAINT), Sungkyunkwan University, 2066, Seobu-ro, Jangan-gu, Suwon, Gyeonggi-do 440-746 (Korea, Republic of); Center for Human Interface Nano Technology (HINT), Sungkyunkwan University, 2066, Seobu-ro, Jangan-gu, Suwon, Gyeonggi-do 440-746 (Korea, Republic of); Hee Choi, Jun [Frontier Research Laboratory, Samsung Advanced Institute of Technology, Samsung Electronics Co., Ltd., Yongin, Gyeonggi-do 446-711 (Korea, Republic of); Zhong, Jianqiang; Chen, Wei [Department of Physics, National University of Singapore, 2 Science Drive 3, Singapore 117542 (Singapore); Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543 (Singapore); Jong Yoo, Won, E-mail: yoowj@skku.edu [Samsung-SKKU Graphene Center (SSGC), Sungkyunkwan University, 2066, Seobu-ro, Jangan-gu, Suwon, Gyeonggi-do 440-746 (Korea, Republic of); Department of Nano Science and Technology, SKKU Advanced Institute of Nano-Technology (SAINT), Sungkyunkwan University, 2066, Seobu-ro, Jangan-gu, Suwon, Gyeonggi-do 440-746 (Korea, Republic of); Center for Human Interface Nano Technology (HINT), Sungkyunkwan University, 2066, Seobu-ro, Jangan-gu, Suwon, Gyeonggi-do 440-746 (Korea, Republic of)

    2014-02-03

    A tunneling rectifier prepared from vertically stacked two-dimensional (2D) materials composed of chemically doped graphene electrodes and hexagonal boron nitride (h-BN) tunneling barrier was demonstrated. The asymmetric chemical doping to graphene with linear dispersion property induces rectifying behavior effectively, by facilitating Fowler-Nordheim tunneling at high forward biases. It results in excellent diode performances of a hetero-structured graphene/h-BN/graphene tunneling diode, with an asymmetric factor exceeding 1000, a nonlinearity of ∼40, and a peak sensitivity of ∼12 V{sup −1}, which are superior to contending metal-insulator-metal diodes, showing great potential for future flexible and transparent electronic devices.

  18. One pot synthesis of CdS/TiO{sub 2} hetero-nanostructures for enhanced H{sub 2} production from water and removal of pollutants from aqueous streams

    Energy Technology Data Exchange (ETDEWEB)

    Mani, A. Daya; Subrahmanyam, Ch., E-mail: csubbu@iith.ac.in

    2016-01-15

    Highlights: • Novel one pot synthesis of CdS/TiO{sub 2} hetero nanostructures by combustion synthesis. • Excellent visible light photocatalytic activity for H{sub 2} production from water. • Enhanced activity for the removal of Cr(VI) from aqueous streams. - Abstract: To achieve more effective coupling of cadmium sulfide (CdS) to the TiO{sub 2}, single step synthesis of CdS/TiO{sub 2} composites is advantageous. In the present study a novel one pot synthesis of several CdS/TiO{sub 2} hetero-nanostructures was explored through combustion technique. As the process involves the simultaneous nucleation of CdS and TiO{sub 2} it leads to the proper connectivity between the constituent materials. All the catalysts were characterized by using several techniques and the excellent visible light activity of the composites has been asserted by the H{sub 2} production from water containing sacrificial reagents, removal of methylene blue and Cr(VI) from aqueous streams. Therefore the present synthetic strategy which is devoid of using molecular linker at interface is more suitable for solar applications, which require faster rates of electron transfer at the hetero junctions.

  19. Dual material gate doping-less tunnel FET with hetero gate dielectric for enhancement of analog/RF performance

    Science.gov (United States)

    Anand, Sunny; Sarin, R. K.

    2017-02-01

    In this paper, charge-plasma-based tunnel FET is proposed by employing dual material gate with hetero gate dielectric technique and it is named hetero-dielectric dual material gate doping-less TFET (HD_DMG_DLTFET). It is compared with conventional doping-less TFET (DLTFET) and dual material gate doping-less TFET (DMG_DLTFET) on the basis of analog and RF performance. The HD_DMG_DLTFET provides better ON state current ({I}\\text{ON}=94 μ \\text{A}/μ \\text{m}), {I}\\text{ON}/{I}\\text{OFF}(≈ 1.36× {10}13), \\text{point} (≈ 3\\text{mV}/\\text{dec}) and average subthreshold slope (\\text{AV}-\\text{SS}=40.40 \\text{mV}/\\text{dec}). The proposed device offers low total gate capacitance (C gg) along with higher drive current. However, with a better transconductance (g m) and cut-off frequency (f T), the HD_DMG_DLTFET can be a good candidate for RF circuitry. The early voltage (V EA) and output conductance (g d) are also moderate for the proposed device with comparison to other devices and therefore can be a candidate for analog devices. From all these simulation results and their study, it is observed that HD_DMG_DLTFET has improved analog/RF performance compared to DLTFET and DMG_DLTFET.

  20. Low temperature route synthesis of SiC–Al2O3 hetero-structural nanofibers

    International Nuclear Information System (INIS)

    Dai, Xiao; Wang, Hao; Cao, Fengfeng; Yi, Qinghua; Cong, Shan; Wang, Yun; Song, Pingyuan; Zhai, Pengfei; Zou, Guifu; Dong, Chao

    2014-01-01

    SiC–Al 2 O 3 hetero-structural nanofibers have been synthesized by the chemical solution approach at 200 ° C. The diameters of nanofibers are in the range of 60–100 nm while the lengths are from tens of micrometers to hundreds of micrometers. The microstructural analysis shows that the fibers possess a like-epitaxial relationship between (104) of hexagonal Al 2 O 3 and (111) of cubic SiC. Additionally, the optical investigation of the nanofibers suggests there are some defects in the low annealing temperature synthesized SiC–Al 2 O 3 nanofibers. (paper)

  1. Revealing the compact structure of lactic acid bacterial hetero-exopolysaccharides by SAXS and DLS

    DEFF Research Database (Denmark)

    Khan, Sanaullah; Birch, Johnny; Harris, Pernille

    2017-01-01

    solution structures of three lactic acid bacterial hetero-exopolysaccharides (HePS-1, HePS-2 and HePS-3). Values of radius of gyration RG, cross-sectional radius of gyration RXS, approximate length L and hydrodynamic diameter were not directly proportional to the molar mass and indicated the HePSs adopted...... Galf residues significantly influence the conformation. Ab initio scattering modeling of HePS-2 and HePS-3 gave excellent curve fittings with χ2 of 0.43 and 0.34 for best-fit models, respectively, compatible with coil-like conformation. The findings disclose solution behaviour of HePS relevant...

  2. Stereo- and regioselectivity of the hetero-Diels–Alder reaction of nitroso derivatives with conjugated dienes

    Directory of Open Access Journals (Sweden)

    Lucie Brulíková

    2016-09-01

    Full Text Available The hetero-Diels–Alder reaction between a nitroso dienophile and a conjugated diene to give the 3,6-dihydro-2H-1,2-oxazine scaffold is useful for the synthesis of many biologically interesting molecules due to the diverse opportunities created by subsequent transformations of the resulting 1,2-oxazine ring. This review discusses the rationale for the observed regio- and stereoselectivity and the methods developed in recent years used to control and improve the stereo- and regioselectivity for the synthesis of 1,2-oxazine scaffolds.

  3. The compositional, structural, and magnetic properties of a Fe{sub 3}O{sub 4}/Ga{sub 2}O{sub 3}/GaN spin injecting hetero-structure grown by metal-organic chemical vapor deposition

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Zhonghua; Huang, Shimin [Nanjing National Laboratory of Microstructures and School of Electronic Science and Engineering, Nanjing University, Nanjing 210023 (China); Tang, Kun, E-mail: ktang@nju.edu.cn [Nanjing National Laboratory of Microstructures and School of Electronic Science and Engineering, Nanjing University, Nanjing 210023 (China); Gu, Shulin, E-mail: slgu@nju.edu.cn [Nanjing National Laboratory of Microstructures and School of Electronic Science and Engineering, Nanjing University, Nanjing 210023 (China); Zhu, Shunming [Nanjing National Laboratory of Microstructures and School of Electronic Science and Engineering, Nanjing University, Nanjing 210023 (China); Ye, Jiandong [Nanjing National Laboratory of Microstructures and School of Electronic Science and Engineering, Nanjing University, Nanjing 210023 (China); Nanjing University Institute of Optoelectronics at Yangzhou, Yangzhou 225009 (China); Xu, Mingxiang [Department of Physics, Southeast University, Nanjing 210096 (China); Wang, Wei; Zheng, Youdou [Nanjing National Laboratory of Microstructures and School of Electronic Science and Engineering, Nanjing University, Nanjing 210023 (China)

    2016-12-01

    Highlights: • The Fe{sub 3}O{sub 4}/Ga{sub 2}O{sub 3}/GaN hetero-structure has been fabricated by MOCVD successfully. • The formation mechanism of different layers in sample was revealed in details. • The properties of the hetero-structure have been presented and discussed extensively. • The effect of Ga diffusion on the magnetic properties of Fe{sub 3}O{sub 4} film has been shown. - Abstract: In this article, the authors have designed and fabricated a Fe{sub 3}O{sub 4}/Ga{sub 2}O{sub 3}/GaN spin injecting hetero-structure by metal-organic chemical vapor deposition. The compositional, structural, and magnetic properties of the hetero-structure have been characterized and discussed. From the characterizations, the hetero-structure has been successfully grown generally. However, due to the unintentional diffusion of Ga ions from Ga{sub 2}O{sub 3}/GaN layers, the most part of the nominal Fe{sub 3}O{sub 4} layer is actually in the form of Ga{sub x}Fe{sub 3−x}O{sub 4} with gradually decreased x values from the Fe{sub 3}O{sub 4}/Ga{sub 2}O{sub 3} interface to the Fe{sub 3}O{sub 4} surface. Post-annealing process can further aggravate the diffusion. Due to the similar ionic radius of Ga and Fe, the structural configuration of the Ga{sub x}Fe{sub 3−x}O{sub 4} does not differ from that of pure Fe{sub 3}O{sub 4}. However, the ferromagnetism has been reduced with the incorporation of Ga into Fe{sub 3}O{sub 4}, which has been explained by the increased Yafet-Kittel angles in presence of considerable amount of Ga incorporation. A different behavior of the magnetoresistance has been found on the as-grown and annealed samples, which could be modelled and explained by the competition between the spin-dependent and spin-independent conduction channels. This work has provided detailed information on the interfacial properties of the Fe{sub 3}O{sub 4}/Ga{sub 2}O{sub 3}/GaN spin injecting hetero-structure, which is the solid basis for further improvement and application of

  4. Polarization and angle independent magneto-electric Fano resonance in multilayer hetero-nanoshells

    Science.gov (United States)

    Wang, Wudeng; Xiong, Li; Zheng, Li; Li, Wei; Shi, Ying; Qi, Jianguang

    2018-05-01

    In this work, we have demonstrated that the Si-SiO2 -Au multilayer hetero-nanoshells can support the polarization and angle independent magneto-electric Fano resonance. Such Fano resonance arises from the direct destructive interference between the orthogonal electric dipole mode of Au core and magnetic dipole mode of the Si shell and is independent of the angle due to the high structural symmetry. In contrast to metal particle arrays, here is a possibility to generate controllable interaction between the electric and magnetic dipole resonances of individual nanoshell with the structural features. The discrete magnetic responses provided directly by the Si shell pave the groundwork for designing the magnetic responses at optical frequencies and enable many fascinating applications in nanophotonics.

  5. Hetero-oligonucleotide Nanoscale Tiles Capable of Two-Dimensional Lattice Formation as Testbeds for a Rapid, Affordable Purification Methodology

    Science.gov (United States)

    2013-01-01

    devices; however, DNA is not the only polymer that can take advantage of the specicity of the Watson – Crick base-pair to achieve these goals. Central to...14. ABSTRACT 16. SECURITY CLASSIFICATION OF: New nanoscale hetero-oligonucleotide tiles are assembled from DNA , RNA and morpholino oligos and...purified using size exclusion filtration. Homo-oligonucleotide tiles assembled from RP-cartridge processed DNA oligos are purified by nondenaturing gel

  6. The Synthesis of "N"-Benzyl-2-Azanorbornene via Aqueous Hetero Diels-Alder Reaction: An Undergraduate Project in Organic Synthesis and Structural Analysis

    Science.gov (United States)

    Sauvage, Xavier; Delaude, Lionel

    2008-01-01

    The synthesis of "N"-benzyl-2-azanorbornene via aqueous hetero Diels-Alder reaction of cyclopentadiene and benzyliminium chloride formed in situ from benzylamine hydrochloride and formaldehyde is described. Characterization of the product was achieved by IR and NMR spectroscopies. The spectral data acquired are thoroughly discussed. Numerous…

  7. Frequency selectivity in pulse responses of Pt/poly(3-hexylthiophene-2,5-diyl/polyethylene oxide +Li+/Pt hetero-junction.

    Directory of Open Access Journals (Sweden)

    Fei Zeng

    Full Text Available Pt/poly(3-hexylthiophene-2,5-diyl/polyethylene oxide + Li+/Pt hetero junctions were fabricated, and their pulse responses were studied. The direct current characteristics were not symmetric in the sweeping range of ±2 V. Negative differential resistance appeared in the input range of 0 to 2 V because of de-doping (or reduction in the side with the semiconductor layer. The device responded stably to a train of pulses with a fixed frequency. The inverse current after a pulse was related to the back-migrated ions. Importantly, the weight calculated based on the inverse current strength, was depressed during low-frequency stimulations but was potentiated during high-frequency stimulations when pulses were positive. Therefore, frequency selectivity was first observed in a semiconducting polymer/electrolyte hetero junction. Detailed analysis of the pulse response showed that the input frequency could modulate the timing of ion doping, de-doping, and re-doping at the semiconducting polymer/electrolyte interface, which then resulted in the frequency selectivity. Our study suggests that the simple redox process in semiconducting polymers can be modulated and used in signal handling or the simulation of bio-learning.

  8. Structure, chemical bonding states, and optical properties of the hetero-structured ZnO/CuO prepared by using the hydrothermal and the electrospinning methods

    Energy Technology Data Exchange (ETDEWEB)

    Hong, Kyong-Soo; Kim, Jong Wook; Bae, Jong-Seong; Hong, Tae Eun; Jeong, Euh Duck; Jin, Jong Sung; Ha, Myoung Gyu; Kim, Jong-Pil, E-mail: jpkim@kbsi.re.kr

    2017-01-01

    ZnO-branched nanostructures have recently attracted considerable attention due to their rich architectures and promising applications in the field of optoelectronics. Contrary to n-type semiconducting metal oxides, cupric oxide is a p-type semiconductor which can be applied to high-critical-temperature superconductors, photovoltaic materials, field emission, and catalysis. We report the synthesis of the ZnO nanorods on the CuO nanofibers prepared by using the electrospinning method along with the hydrothermal method. As the growing time increases, emission spectra of the hetero-structured ZnO/CuO show that the observed band in the UV region is slightly increased, while the intensity of the green emission is highly enhanced. The hetero-structured ZnO/CuO is found to be a promising candidate for developing renewable devices with photoluminescent behavior and the increased surface to volume ratio.

  9. Fiscal 1998 New Sunshine Project research report. Development of separation technology of hetero-compounds from coal-derived oil, and use methods of them; 1998 nendo sekitan ekikayuchu no tetero kagobutsu nado no bunri gijutsu to yoto no kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This project develops the efficient separation technology of compounds including hetero-atoms such as O and N from coal- derived oil, and researches effective use methods of them. Study is made on the concrete applications and problems of the following separation technologies of hetero-compounds: Distillation/refrigeration, extraction, supercritical gas extraction, pressurized crystallization, crystallization, adsorption, and membrane separation technologies. Based on the study result, the applicability of such various separation technologies of hetero-compounds from coal-derived oil fractions is confirmed experimentally. By using the newly developed bench-scale test equipment of an optimum separation process, the process performance is confirmed, and various engineering data are collected. Study is also made on the effective use method of the hetero-compounds separated by the above equipment. In fiscal 1998, as the electric membrane dialysis experiment result on phenolates derived from phenols in Kashima pilot naphtha and atmospheric light oil, the existence of substances (Ca, Fe, SO{sub 4}) deteriorating membranes was confirmed. Preventive measures against contamination of these bivalent cations and anions are one of future issues. (NEDO)

  10. Visible light CrO{sub 4}{sup 2-} reduction using the new CuAlO{sub 2}/CdS hetero-system

    Energy Technology Data Exchange (ETDEWEB)

    Brahimi, R. [Centre of Research in Physical and Chemical Analysis (CRAPC), BP 248, RP 16004 Algiers (Algeria); Laboratory of Storage and Valorization of Renewable Energies, Faculty of Chemistry (USTHB), BP 32 16111 Algiers (Algeria); Bessekhouad, Y. [Laboratory of Storage and Valorization of Renewable Energies, Faculty of Chemistry (USTHB), BP 32 16111 Algiers (Algeria); National Veterinary High School, BP 16111 Algiers (Algeria); Nasrallah, N. [Laboratory of Storage and Valorization of Renewable Energies, Faculty of Chemistry (USTHB), BP 32 16111 Algiers (Algeria); Trari, M., E-mail: solarchemistry@gmail.com [Laboratory of Storage and Valorization of Renewable Energies, Faculty of Chemistry (USTHB), BP 32 16111 Algiers (Algeria)

    2012-06-15

    Graphical abstract: Pseudo-first order kinetic for CrO{sub 4}{sup 2-} photoreduction for various concentrations. Highlights: Black-Right-Pointing-Pointer The work deals with the chromium reduction over CuAlO{sub 2}/CdS hetero-system. Black-Right-Pointing-Pointer The conduction band of CdS (-1.08 V) is more negative than the CrO{sub 4}{sup 2-}/Cr{sup 3+} level. Black-Right-Pointing-Pointer The sensitizer CuAlO{sub 2} has been synthesized by sol-gel. Black-Right-Pointing-Pointer The Cr(VI) reduction follows a pseudo first order kinetic with of salicylic acid. - Abstract: In this study, 64% of hexavalent chromium Cr(VI) reduction from the initial concentration (10{sup -4} M) is reported under visible light using the (CuAlO{sub 2}/CdS) hetero-system. In this new hetero-system, low doped CuAlO{sub 2} delafossite, synthesized by sol-gel works as an electrons reservoir with a wide space charge region (440 nm). In this case, the electron transfer to chromate is mediated via the hexagonal CdS variety, whose conduction band level is at -1.08 V with respect to the saturated calomel electrode which is more negative than the CrO{sub 4}{sup 2-}/Cr{sup 3+} level. This high reduction rate is achieved under optimized pH and CuAlO{sub 2} percentage. Moreover, salicylic acid gives the best performance among hole scavengers and CuAlO{sub 2} approaches 100% photostability at pH 7.5. The photo-catalytic process follows a pseudo first order kinetic with a half life of 2 h. The reaction products are identified by UV-visible spectrophotometry and linear voltametry at a platinum rotating electrode. The results reveal the presence of Cr{sup 3+} after irradiation.

  11. Classical and quantum analysis of a hetero-triatomic molecular Bose-Einstein condensate model

    International Nuclear Information System (INIS)

    Tonel, A.P.; Kuhn, C.C.N.; Foerster, A.; Santos, G.; Roditi, I.; Santos, Z.V.T.

    2014-11-01

    We investigate an integrable Hamiltonian modelling a hetero-triatomic-molecular Bose-Einstein condensate. This model describes a mixture of two species of atoms in different proportions, which can combine to form a triatomic molecule. Beginning with a classical analysis, we determine the fixed points of the system. Bifurcations of these points separate the parameter space into different regions. Three distinct scenarios are found, varying with the atomic population imbalance. This result suggests the ground state properties of the quantum model exhibits a sensitivity on the atomic population imbalance, which is confirmed by a quantum analysis using different approaches, such as the ground-state expectation values, the behaviour of the quantum dynamics, the energy gap and the ground state fidelity. (author)

  12. Molecular Design of a Chiral Brønsted Acid with Two Different Acidic Sites: Regio-, Diastereo-, and Enantioselective Hetero-Diels-Alder Reaction of Azopyridinecarboxylate with Amidodienes Catalyzed by Chiral Carboxylic Acid-Monophosphoric Acid.

    Science.gov (United States)

    Momiyama, Norie; Tabuse, Hideaki; Noda, Hirofumi; Yamanaka, Masahiro; Fujinami, Takeshi; Yamanishi, Katsunori; Izumiseki, Atsuto; Funayama, Kosuke; Egawa, Fuyuki; Okada, Shino; Adachi, Hiroaki; Terada, Masahiro

    2016-09-07

    A chiral Brønsted acid containing two different acidic sites, chiral carboxylic acid-monophosphoric acid 1a, was designed to be a new and effective concept in catalytic asymmetric hetero-Diels-Alder reactions of azopyridinecarboxylate with amidodienes. The multipoint hydrogen-bonding interactions among the carboxylic acid, monophosphoric acid, azopyridinecarboxylate, and amidodiene achieved high catalytic and chiral efficiency, producing substituted 1,2,3,6-tetrahydropyridazines with excellent stereocontrol in a single step. This constitutes the first example of regio-, diastereo-, and enantioselective azo-hetero-Diels-Alder reactions by chiral Brønsted acid catalysis.

  13. Increasing conversion efficiency of two-step photon up-conversion solar cell with a voltage booster hetero-interface.

    Science.gov (United States)

    Asahi, Shigeo; Kusaki, Kazuki; Harada, Yukihiro; Kita, Takashi

    2018-01-17

    Development of high-efficiency solar cells is one of the attractive challenges in renewable energy technologies. Photon up-conversion can reduce the transmission loss and is one of the promising concepts which improve conversion efficiency. Here we present an analysis of the conversion efficiency, which can be increased by up-conversion in a single-junction solar cell with a hetero-interface that boosts the output voltage. We confirm that an increase in the quasi-Fermi gap and substantial photocurrent generation result in a high conversion efficiency.

  14. Comparative investigation of novel hetero gate dielectric and drain engineered charge plasma TFET for improved DC and RF performance

    Science.gov (United States)

    Yadav, Dharmendra Singh; Verma, Abhishek; Sharma, Dheeraj; Tirkey, Sukeshni; Raad, Bhagwan Ram

    2017-11-01

    Tunnel-field-effect-transistor (TFET) has emerged as one of the most prominent devices to replace conventional MOSFET due to its ability to provide sub-threshold slope below 60 mV/decade (SS ≤ 60 mV/decade) and low leakage current. Despite this, TFETs suffer from ambipolar behavior, lower ON-state current, and poor RF performance. To address these issues, we have introduced drain and gate work function engineering with hetero gate dielectric for the first time in charge plasma based doping-less TFET (DL TFET). In this, the usage of dual work functionality over the drain region significantly reduces the ambipolar behavior of the device by varying the energy barrier at drain/channel interface. Whereas, the presence of dual work function at the gate terminal increases the ON-state current (ION). The combined effect of dual work function at the gate and drain electrode results in the increment of ON-state current (ION) and decrement of ambipolar conduction (Iambi) respectively. Furthermore, the incorporation of hetero gate dielectric along with dual work functionality at the drain and gate electrode provides an overall improvement in the performance of the device in terms of reduction in ambipolarity, threshold voltage and sub-threshold slope along with improved ON-state current and high frequency figures of merit.

  15. Sexuality, gendered identities and exclusion: the deployment of proper (hetero)sexuality within an HIV-prevention text from South Africa.

    Science.gov (United States)

    Gacoin, Andrée

    2010-05-01

    HIV prevention discourses concern lives, the protection of bodily rights and people's active involvement in the policies and programmes that affect them. HIV prevention discourses also create lives, relying upon the deployment of normative sexual identities at the same time as they invite complex and fluid youth identities to embody the norms of prevention. This paper examines a particular HIV prevention text that is available to teachers in the Western Cape province of South Africa to support the implementation of the national Life Orientation programme. Rather than considering this text as a neutral 'scaffold' upon which teachers and students add cultural meanings, it is important to interrogate the ways in which texts rely upon and reiterate particular discursive constructions of the youth sexual subject. This paper argues that the text deploys a particular discursive framework in order to construct a 'normal' (and hetero) sexuality that validates, rather than questions, social constructions of masculine privilege within heterosexuality. This is achieved through the deployment of a scientific expertise of sexuality; the mobilisation of a valued hetero/homosexual binary to create a 'safe' heterosexuality; the normalisation of bourgeois sexuality through the ideology of marriage; and the naturalisation of heterosexual masculine and feminine identities.

  16. In situ observation of modulated light emission of fiber fuse synchronized with void train over hetero-core splice point.

    Directory of Open Access Journals (Sweden)

    Shin-ichi Todoroki

    Full Text Available BACKGROUND: Fiber fuse is a process of optical fiber destruction under the action of laser radiation, found 20 years ago. Once initiated, opical discharge runs along the fiber core region to the light source and leaves periodic voids whose shape looks like a bullet pointing the direction of laser beam. The relation between damage pattern and propagation mode of optical discharge is still unclear even after the first in situ observation three years ago. METHODOLOGY/PRINCIPAL FINDINGS: Fiber fuse propagation over hetero-core splice point (Corning SMF-28e and HI 1060 was observed in situ. Sequential photographs obtained at intervals of 2.78 micros recorded a periodic emission at the tail of an optical discharge pumped by 1070 nm and 9 W light. The signal stopped when the discharge ran over the splice point. The corresponding damage pattern left in the fiber core region included a segment free of periodicity. CONCLUSIONS: The spatial modulation pattern of the light emission agreed with the void train formed over the hetero-core splice point. Some segments included a bullet-shaped void pointing in the opposite direction to the laser beam propagation although the sequential photographs did not reveal any directional change in the optical discharge propagation.

  17. Median Hetero-Associative Memories Applied to the Categorization of True-Color Patterns

    Science.gov (United States)

    Vázquez, Roberto A.; Sossa, Humberto

    Median associative memories (MED-AMs) are a special type of associative memory based on the median operator. This type of associative model has been applied to the restoration of gray scale images and provides better performance than other models, such as morphological associative memories, when the patterns are altered with mixed noise. Despite of his power, MED-AMs have not been applied in problems involving true-color patterns. In this paper we describe how a median hetero-associative memory (MED-HAM) could be applied in problems that involve true-color patterns. A complete study of the behavior of this associative model in the restoration of true-color images is performed using a benchmark of 14400 images altered by different type of noises. Furthermore, we describe how this model can be applied to an image categorization problem.

  18. The effect of halogen hetero-atoms on the vapor pressures and thermodynamics of polycyclic aromatic compounds measured via the Knudsen effusion technique

    International Nuclear Information System (INIS)

    Goldfarb, Jillian L.; Suuberg, Eric M.

    2008-01-01

    Knowledge of vapor pressures of high molar mass organics is essential to predicting their behavior in combustion systems as well as their fate and transport within the environment. This study involved polycyclic aromatic compounds (PACs) containing halogen hetero-atoms, including bromine and chlorine. The vapor pressures of eight PACs, ranging in molar mass from (212 to 336) g . mol -1 , were measured using the isothermal Knudsen effusion technique over the temperature range of (296 to 408) K. These compounds included those with few or no data available in the literature, namely: 1,4-dibromonaphthalene, 5-bromoacenaphthene, 9-bromoanthracene, 1,5-dibromoanthracene, 9,10-dibromoanthracene, 2-chloroanthracene, 9,10-dichloroanthracene, and 1-bromopyrene. Enthalpies of sublimation of these compounds were determined via application of the Clausius-Clapeyron equation. An analysis is presented on the effects of the addition of halogen hetero-atoms to pure polycyclic aromatic hydrocarbons using these data as well as available literature data. As expected, the addition of halogens onto these PACs increases their enthalpies of sublimation and decreases their vapor pressures as compared to the parent compounds

  19. The hetero-hexameric nature of a chloroplast AAA+ FtsH protease contributes to its thermodynamic stability.

    Directory of Open Access Journals (Sweden)

    Ofer Moldavski

    Full Text Available FtsH is an evolutionary conserved membrane-bound metalloprotease complex. While in most prokaryotes FtsH is encoded by a single gene, multiple FtsH genes are found in eukaryotes. Genetic and biochemical data suggest that the Arabidopsis chloroplast FtsH is a hetero-hexamer. This raises the question why photosynthetic organisms require a heteromeric complex, whereas in most bacteria a homomeric one is sufficient. To gain structural information of the possible complexes, the Arabidopsis FtsH2 (type B and FtsH5 (type A were modeled. An in silico study with mixed models of FtsH2/5 suggests that heteromeric hexamer structure with ratio of 4:2 is more likely to exists. Specifically, calculation of the buried surface area at the interfaces between neighboring subunits revealed that a hetero-complex should be thermodynamically more stable than a homo-hexamer, due to the presence of additional hydrophobic and hydrophilic interactions. To biochemically assess this model, we generated Arabidopsis transgenic plants, expressing epitope-tagged FtsH2 and immuno-purified the protein. Mass-spectrometry analysis showed that FtsH2 is associated with FtsH1, FtsH5 and FtsH8. Interestingly, we found that 'type B' subunits (FtsH2 and FtsH8 were 2-3 fold more abundant than 'type A' (FtsH1 and FtsH5. The biochemical data corroborate the in silico model and suggest that the thylakoid FtsH hexamer is composed of two 'type A' and four 'type B' subunits.

  20. Palladium(II)-Catalyzed meta-C-H Olefination: Constructing Multisubstituted Arenes through Homo-Diolefination and Sequential Hetero-Diolefination.

    Science.gov (United States)

    Bera, Milan; Maji, Arun; Sahoo, Santosh K; Maiti, Debabrata

    2015-07-13

    Divinylbenzene derivatives represent an important class of molecular building blocks in organic chemistry and materials science. Reported herein is the palladium-catalyzed synthesis of divinylbenzenes by meta-C-H olefination of sulfone-based arenes. Successful sequential olefinations in a position-selective manner provided a novel route for the synthesis of hetero-dialkenylated products, which are difficult to access using conventional methods. Additionally, 1,3,5-trialkenylated compounds can be generated upon successful removal of the directing group. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Thermal replacement reaction: a novel route for synthesizing eco-friendly ZnO@γ-In2Se3 hetero-nanostructures by replacing cadmium with indium and their photoelectrochemical and photocatalytic performances.

    Science.gov (United States)

    Zhang, Zhuo; Choi, Mingi; Baek, Minki; Yong, Kijung

    2015-05-21

    A novel route called thermal replacement reaction was demonstrated for synthesizing eco-friendly ZnO@γ-In2Se3 hetero-structural nanowires on FTO glass by replacing the element cadmium with indium for the first time. The indium layer was coated on the surface of the ZnO nanowires beforehand, then CdSe quantum dots were deposited onto the coated indium layer, and finally the CdSe quantum dots were converted to γ-In2Se3 quantum dots by annealing under vacuum at 350 °C for one hour. The prepared ZnO@γ-In2Se3 hetero-nanostructures exhibit stable photoelectrochemical properties that can be ascribed to the protection of the In2O3 layer between the ZnO nanowire and γ-In2Se3 quantum dots and better photocatalytic performance in the wide wavelength region from 400 nm to nearly 750 nm. This strategy for preparing the ZnO@γ-In2Se3 hetero-nanostructures not only enriches our understanding of the single replacement reaction where the active element cadmium can be replaced with indium, but also opens a new way for the in situ conversion of cadmium-based to eco-friendly indium-based nano-devices.

  2. Performance evaluation of ZnO–CuO hetero junction solid state room temperature ethanol sensor

    International Nuclear Information System (INIS)

    Yu, Ming-Ru; Suyambrakasam, Gobalakrishnan; Wu, Ren-Jang; Chavali, Murthy

    2012-01-01

    Graphical abstract: Sensor response (resistance) curves of time were changed from 150 ppm to 250 ppm alcohol concentration of ZnO–CuO 1:1. The response and recovery times were measured to be 62 and 83 s, respectively. The sensing material ZnO–CuO is a high potential alcohol sensor which provides a simple, rapid and highly sensitive alcohol gas sensor operating at room temperature. Highlights: ► The main advantages of the ethanol sensor are as followings. ► Novel materials ZnO–CuO ethanol sensor. ► The optimized ZnO–CuO hetero contact system. ► A good sensor response and room working temperature (save energy). -- Abstract: A semiconductor ethanol sensor was developed using ZnO–CuO and its performance was evaluated at room temperature. Hetero-junction sensor was made of ZnO–CuO nanoparticles for sensing alcohol at room temperature. Nanoparticles were prepared by hydrothermal method and optimized with different weight ratios. Sensor characteristics were linear for the concentration range of 150–250 ppm. Composite materials of ZnO–CuO were characterized using X-ray diffraction (XRD), temperature-programmed reduction (TPR) and high-resolution transmission electron microscopy (HR-TEM). ZnO–CuO (1:1) material showed maximum sensor response (S = R air /R alcohol ) of 3.32 ± 0.1 toward 200 ppm of alcohol vapor at room temperature. The response and recovery times were measured to be 62 and 83 s, respectively. The linearity R 2 of the sensor response was 0.9026. The sensing materials ZnO–CuO (1:1) provide a simple, rapid and highly sensitive alcohol gas sensor operating at room temperature.

  3. Hetero-azeotropic distillation: combining fungal dehydration and lipid extraction.

    Science.gov (United States)

    Tough, A J; Isabella, B L; Beattie, J E; Herbert, R A

    2000-01-01

    A low-cost single-stage laboratory process combining fungal dehydration and lipid extraction was compared with a traditional two-stage method employing freeze-drying and subsequent mechanical disruption in the presence of solvent. The ability of a number of organic solvents to form hetero-azeotropes with water was exploited. Chloroform, cyclohexane and hexane were assessed in their abilities to both dry and extract lipid from the oleaginous phycomycete Mortierella alpina (ATCC 32222). Drying rate and lipid extraction were maximised under conditions that prevented fungal agglomeration. The total processing time was limited by the rate of dehydration rather than by the rate of lipid extraction. In all cases azeotropic distillation facilitated a greater rate of dehydration than was possible with freeze-drying. A consequent reduction in overall processing time was observed. Uniquely, both the solvent used and the mode of mixing employed controlled the morphology of the aggregates formed during distillation. In combination with mild mixing chloroform discouraged agglomeration whereas cyclohexane and hexane promoted aggregation. Successful lipid extraction was dependent on the use of dry biomass rather than on the application of heat to effect distillation. Neither the application of heat nor the solvent employed had any significant effect on the lipid composition of the extracted oil.

  4. Optimum Design of ARC-less InGaP/GaAs DJ Solar Cell with Hetero Tunnel Junction

    Science.gov (United States)

    Abbasian, Sobhan; Sabbaghi-Nadooshan, Reza

    2018-03-01

    The operation of hetero In0.49Ga0.51P-Al0.7Ga0.3As tunnel diodes has been evaluated, and an approach for optimizing the back surface field (BSF) layer of a InGaP/GaAs dual-junction (DJ) solar cell developed. The results show that the hetero In0.49Ga0.51P-Al0.7Ga0.3As tunnel diode transferred more electrons and holes and showed less recombination between the top and bottom cells with increased efficiency (η) in the InGaP/GaAs DJ solar cell. To achieve higher open-circuit voltage (V oc), GaAs semiconductor was investigated to match with Al0.52In0.48P with bandgap of 2.4 eV, and replacement of the bottom cell in the InGaP/GaAs DJ solar cell with such an Al0.52In0.48P-GaAs heterojunction increased the photogeneration in this region. In the next step, addition of a BSF layer to the top cell required two BSF layers in the bottom cell to optimize the short-circuit current (J sc) and η. The thickness and doping of the BSF layers were increased to obtain the highest η for the cell. The proposed structure was then compared with previous works. The proposed structure yielded V oc = 2.46 V, J sc = 30 mA/cm2, fill factor (FF) = 88.61%, and η = 65.51% under AM1.5 (1 sun) illumination.

  5. Enhancement-mode two-channel triple quantum dot from an undoped Si/Si0.8Ge0.2 quantum well hetero-structure.

    Energy Technology Data Exchange (ETDEWEB)

    Studenikin, S. A.; Gaudreau, L.; Kataoka, K.; Austing, D. G.; Lu, Tzu-Ming; Luhman, Dwight; Bethke, Donald Thomas; Wanke, Michael; Lilly, Michael; Carroll, Malcolm S.; Sachrajda, A. S.

    2017-12-01

    We demonstrate coupled triple dot operation and charge sensing capability for the recently introduced quantum dot technology employing undoped Si/Si0.8Ge0.2 hetero-structures which also incorporate a single metal-gate layer to simplify fabrication [T. M. Lu et al., Appl. Phys. Lett. 109, 093102 (2016)]. Si/SiGe hetero-structures with a Ge concentration of 20% rather than the more usual 30% typically encountered offer higher electron mobility. The devices consist of two in-plane parallel electron channels that host a double dot in one channel and a single dot in the other channel. In a device where the channels are sufficiently close a triple dot in a triangular configuration is induced leading to regions in the charge stability diagram where three addition lines of different slope approach each other and anti-cross. In a device where the channels are further apart the single dot charge-senses the double dot with relative change of ~2% in the sensor current. We also highlight temporal drifting and metastability of the Coulomb oscillations. These effects are induced if the temperature environment of the device is not kept constant and arise from non-equilibrium charge redistribution and subsequent slow recovery.

  6. Antifungal activity of synthetic di(hetero)arylamines based on the benzo[b]thiophene moiety.

    Science.gov (United States)

    Pinto, Eugénia; Queiroz, Maria-João R P; Vale-Silva, Luís A; Oliveira, João F; Begouin, Agathe; Begouin, Jeanne-Marie; Kirsch, Gilbert

    2008-09-01

    The antifungal activity of several di(hetero)arylamine derivatives of the benzo[b]thiophene system was evaluated against clinically relevant Candida, Aspergillus, and dermatophyte species by a broth macrodilution test based on CLSI (formerly NCCLS) guidelines. The most active compound showed a broad spectrum of activity (against all tested fungal strains, including fluconazole-resistant fungi), with particularly low MICs for dermatophytes. Results from the inhibition of the dimorphic transition in Candida albicans and flow cytometry studies further confirmed their biological activity. With this study it was possible to establish some structure-activity relationships (SARs). The hydroxy groups proved to be essential for the activity in the aryl derivatives. Furthermore, the spectrum of activity in the pyridine derivatives was broadened by the absence of the ester group on position 2 of the benzo[b]thiophene system.

  7. Improved electron density through hetero-junction binary sensitized TiO2/ CdTe / D719 system as photoanode for dye sensitized solar cell

    Science.gov (United States)

    Pandey, A. K.; Ahmad, Muhammad Shakeel; Alizadeh, Mahdi; Rahim, Nasrudin Abd

    2018-07-01

    The combined effect of dual sensitization and hetero-junction symmetry has been investigated on the performance of TiO2 based dye sensitized solar cell. CdTe nanoparticles have been introduced in TiO2 matrix to function as sensitizer as well as act as hetero-junction between D719 dye and TiO2 nanoarchitecture. Four concentrations of CdTe i.e. 0.5 wt%, 2 wt%, 5 wt% and 8 wt% have been investigated. Morphological and compositional studies have been conducted using scanning electron microscope (SEM) and X-ray diffraction (XRD) respectively. Light absorption characteristics have been investigated by employing Uv-vis spectroscopy and the overall performance has been studied using solar simulator and electrochemical impedance spectroscopy (EIS). Performance has been found to be increased with the addition of CdTe due to high electron density and reduction in recombination reactions. An increase of 41.73% in incident photo conversion efficiency (IPCE) and 75.57% in short circuit current density (Jsc) have been recorded for the specimens containing 5 wt% CdTe compared to bare TiO2 based DSSCs. Further addition of CdTe leads to reduction in overall performance of DSSCs.

  8. Light-driven self-assembly of hetero-shaped gold nanorods

    Science.gov (United States)

    Liaw, Jiunn-Woei; Chao, Hsueh-Yu; Huang, Cheng-Wei; Kuo, Mao-Kuen

    2018-01-01

    Light-driven self-assembly and coalescence of two nearby hetero-shaped gold nanorods (GNRs) with different lengths are studied theoretically. The optical forces and torques, in terms of Maxwell's stress tensor, upon these GNRs provided by a linearly polarized (LP) plane wave are analyzed using the multiple multipole (MMP) method. Numerical results show that the optical torque dominates their alignments and the optical force their attraction. The most likely outcome of the plasmon-mediated light-matter interaction is wavelength dependent. Three different coalescences of the two GNRs could be induced by a LP light in three different wavelength regimes, respectively. For example, the side-by-side coalescence of two GNRs with radius of 15 nm and different lengths (120 and 240 nm) is induced in water as irradiated by a LP light at 633 nm, the T-shaped one at 1064 nm, and the end-to-end one at 1700 nm. The plasmonic attractive force and heating power densities inside GNRs with different gaps are also studied; the smaller the gap, the larger the attractive force and heating power. The results imply that the plasmonic coalescence and heating of two discrete GNRs may cause the local fusion at the junction of the assembly and the subsequent annealing (even recrystallization). Because the heating makes the two discrete GNRs fused to become a new nanostructure, the plasmonic coalescence of optical manipulation is irreversible.

  9. Novel topotactically transformed carbon-CoO-NiO-NiCo₂O₄ nanosheet hybrid hetero-structured arrays as ultrahigh performance supercapacitors.

    Science.gov (United States)

    Wang, Hai; Guo, Junling; Qing, Chen; Sun, Daming; Wang, Bixiao; Tang, Yiwen

    2014-08-14

    A novel carbon-CoO-NiO-NiCo2O4 integrated electrode has been designed by reducing the hetero-structured NiCo2O4 nanosheet array with C2H2 on the nickel foam at a low temperature of 350 °C. The topotactical transformation from NiCo2O4 to the integrated electrode has been first conceived and investigated. Such unique nanoarchitectures exhibit excellent electrochemical performance with ultrahigh capacitance and desirable cycle life at high rates.

  10. Stereo-controlled synthesis of polyheterocycles via the diene-transmissive hetero-Diels-Alder reaction of β,γ-unsaturated α-keto esters.

    Science.gov (United States)

    Otani, Takashi; Tamai, Yumiko; Seki, Kazunori; Kikuchi, Tomohiro; Miyazawa, Taiichiro; Saito, Takao

    2015-06-07

    We describe the stereoselective synthesis of polyring-fused heterocyclic compounds based on diene-transmissive hetero-Diels-Alder reactions utilizing β,γ-unsaturated α-keto esters. This protocol involves the initial endo- or exo-selective Diels-Alder (DA) reactions with electron-rich dienophiles, methylenation of the ester carbonyl groups with the Tebbe reagent, and a stereoselective second DA reaction with electron-deficient dienophiles. The use of enantioselective DA reactions in the initial reaction enables access to chiral polyring-fused heterocyclic compounds with multiple chiral centres.

  11. Hetero-epitaxial growth of TiC films on MgO(001) at 100 °C by DC reactive magnetron sputtering

    International Nuclear Information System (INIS)

    Braic, M.; Zoita, N.C.; Danila, M.; Grigorescu, C.E.A.; Logofatu, C.

    2015-01-01

    Hetero-epitaxial TiC thin films were deposited at 100 °C on MgO(001) by DC reactive magnetron sputtering in a mixture of Ar and CH 4 . The 62 nm thick films were analyzed for elemental composition and chemical bonding by Auger electron spectroscopy, X-ray photoelectron spectroscopy and micro-Raman spectroscopy. The crystallographic structure investigation by high resolution X-ray diffraction revealed that the films consist of two layers: an interface partially strained epilayer with high crystalline quality, and a relaxed layer, formed by columnar grains, maintaining the epitaxial relationship with the substrate. The films presented smooth surfaces (RMS roughness ~ 0.55 nm), with circular equi-sized grains/crystallites, as observed by atomic force microscopy. The Hall measurements in Van der Pauw geometry revealed relatively high resistivity value ~ 620 μΩ cm, ascribed to electron scattering on interfaces, on grain boundaries and on different defects/dislocations. - Highlights: • Hetero-epitaxial TiC 0.84 thin films were grown on MgO(001) at 100 °C by magnetron sputtering. • 62 nm thick films were synthesized by magnetron sputtering, using Ti, Ar and CH 4 . • The film comprises a partially strained interface epilayer and a relaxed top layer. • Both layers preserve the epitaxial relationship with the substrate. • Low RMS surface roughness ~ 0.55 nm and grains with mean lateral size of ~ 38.5 nm were observed

  12. Hetero-epitaxial growth of TiC films on MgO(001) at 100 °C by DC reactive magnetron sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Braic, M. [National Institute for Optoelectronics, 409 Atomistilor St., 077125 Magurele (Romania); Zoita, N.C., E-mail: cnzoita@inoe.ro [National Institute for Optoelectronics, 409 Atomistilor St., 077125 Magurele (Romania); Danila, M. [National Institute for Research and Development in Microtechnology, 126A Erou Iancu Nicolae Blvd., 077190 Bucharest (Romania); Grigorescu, C.E.A. [National Institute for Optoelectronics, 409 Atomistilor St., 077125 Magurele (Romania); Logofatu, C. [National Institute of Materials Physics, 105 bis Atomistilor St., 077125 Magurele (Romania)

    2015-08-31

    Hetero-epitaxial TiC thin films were deposited at 100 °C on MgO(001) by DC reactive magnetron sputtering in a mixture of Ar and CH{sub 4}. The 62 nm thick films were analyzed for elemental composition and chemical bonding by Auger electron spectroscopy, X-ray photoelectron spectroscopy and micro-Raman spectroscopy. The crystallographic structure investigation by high resolution X-ray diffraction revealed that the films consist of two layers: an interface partially strained epilayer with high crystalline quality, and a relaxed layer, formed by columnar grains, maintaining the epitaxial relationship with the substrate. The films presented smooth surfaces (RMS roughness ~ 0.55 nm), with circular equi-sized grains/crystallites, as observed by atomic force microscopy. The Hall measurements in Van der Pauw geometry revealed relatively high resistivity value ~ 620 μΩ cm, ascribed to electron scattering on interfaces, on grain boundaries and on different defects/dislocations. - Highlights: • Hetero-epitaxial TiC{sub 0.84} thin films were grown on MgO(001) at 100 °C by magnetron sputtering. • 62 nm thick films were synthesized by magnetron sputtering, using Ti, Ar and CH{sub 4}. • The film comprises a partially strained interface epilayer and a relaxed top layer. • Both layers preserve the epitaxial relationship with the substrate. • Low RMS surface roughness ~ 0.55 nm and grains with mean lateral size of ~ 38.5 nm were observed.

  13. Mononuclear, trinuclear, and hetero-trinuclear supramolecular complexes containing a new tri-sulfonate ligand and cobalt(II)/copper(II)-(1, 10-phenanthroline)(2) building blocks

    NARCIS (Netherlands)

    Yu, Yunfang; Wei, Yongqin; Broer, Ria; Sa, Rongjian; Wu, Kechen

    Novel mononuclear, trinuclear, and hetero-trinuclear supermolecular complexes, [Co(phen)(2)(H2O)(HTST)] center dot 2H(2)O (1), [CO3(phen)(6) (H2O)(2)(TST)(2)]center dot 7H(2)O (2), and [CO2Cu(phen)(6)(H2O)(2)(TST)(2)]center dot 10H(2)O (3), have been synthesized by the reactions of a new

  14. Mononuclear, trinuclear, and hetero-trinuclear supramolecular complexes containing a new tri-sulfonate ligand and cobalt(II)/copper(II)-(1,10-phenanthroline)2 building blocks

    International Nuclear Information System (INIS)

    Yu Yunfang; Wei Yongqin; Broer, Ria; Sa Rongjian; Wu Kechen

    2008-01-01

    Novel mononuclear, trinuclear, and hetero-trinuclear supermolecular complexes, [Co(phen) 2 (H 2 O)(HTST)].2H 2 O (1), [Co 3 (phen) 6 (H 2 O) 2 (TST) 2 ].7H 2 O (2), and [Co 2 Cu(phen) 6 (H 2 O) 2 (TST) 2 ].10H 2 O (3), have been synthesized by the reactions of a new tri-sulfonate ligand (2,4,6-tris(4-sulfophenylamino)-1,3,5-triazine, H 3 TST) with the M 2+ (M=Co, Cu) and the second ligand 1,10-phenanthroline (phen). Complex 1 contains a cis-Co(II)(phen) 2 building block and an HTST as monodentate ligand; complex 2 consists of two TST as bidentate ligands connecting one trans- and two cis-Co(II)(phen) 2 building blocks; complex 3 is formed by replacing the trans-Co(II)(phen) 2 in 2 with a trans-Cu(II)(phen) 2 , which is the first reported hetero-trinuclear supramolecular complex containing both the Co(II)(phen) 2 and Cu(II)(phen) 2 as building blocks. The study shows the flexible multifunctional self-assembly capability of the H 3 TST ligands presenting in these supramolecular complexes through coordinative, H-bonding and even π-π stacking interactions. The photoluminescent optical properties of these complexes are also investigated and discussed as well as the second-order nonlinear optical properties of 1. - Graphical abstract: Novel mononuclear, trinuclear, and hetero-trinuclear supermolecular complexes, [Co(phen) 2 (H 2 O)(HTST)].2H 2 O (1), [Co 3 (phen) 6 (H 2 O) 2 (TST) 2 ].7H 2 O (2), and [Co 2 Cu(phen) 6 (H 2 O) 2 (TST) 2 ].10H 2 O (3), have been synthesized by the reactions of a new tri-sulfonate ligand (2,4,6-tris(4-sulfophenylamino)-1,3,5-triazine, H 3 TST) with the M 2+ (M=Co, Cu) and the second ligand 1,10-phenanthroline (phen). The study shows the flexible multifunctional self-assembly capability of H 3 TST ligand presenting in these supramolecular complexes

  15. Tunnel field-effect transistors with germanium/strained-silicon hetero-junctions for low power applications

    International Nuclear Information System (INIS)

    Kim, Minsoo; Kim, Younghyun; Yokoyama, Masafumi; Nakane, Ryosho; Kim, SangHyeon; Takenaka, Mitsuru; Takagi, Shinichi

    2014-01-01

    We have studied a simple structure n-channel tunnel field-effect transistor with a pure-Ge/strained-Si hetero-junction. The device operation was demonstrated for the devices fabricated by combining epitaxially-grown Ge on strained-silicon-on-insulator substrates. Atomic-layer-deposition-Al 2 O 3 -based gate stacks were formed with electron cyclotron resonance plasma post oxidation to ensure the high quality metal–oxide–semiconductor interface between the high-k insulator and Ge. While the gate leakage current and drain current saturation are well controlled, relatively higher minimum subthreshold swing of 125 mV/dec and lower I ON /I OFF ratio of 10 3 –10 4 were obtained. It is expected that these device characteristics can be improved by further process optimization. - Highlights: • Layer by layer growth of Ge • Uniform interface between Ge and the insulator • Gate leakage current and drain current saturation seem to be well controlled. • The output characteristics show good saturation

  16. Charge movement in a GaN-based hetero-structure field effect transistor structure with carbon doped buffer under applied substrate bias

    International Nuclear Information System (INIS)

    Pooth, Alexander; Uren, Michael J.; Cäsar, Markus; Kuball, Martin; Martin, Trevor

    2015-01-01

    Charge trapping and transport in the carbon doped GaN buffer of a GaN-based hetero-structure field effect transistor (HFET) has been investigated under both positive and negative substrate bias. Clear evidence of redistribution of charges in the carbon doped region by thermally generated holes is seen, with electron injection and capture observed during positive bias. Excellent agreement is found with simulations. It is shown that these effects are intrinsic to the carbon doped GaN and need to be controlled to provide reliable and efficient GaN-based power HFETs

  17. Demonstration of hetero-gate-dielectric tunneling field-effect transistors (HG TFETs).

    Science.gov (United States)

    Choi, Woo Young; Lee, Hyun Kook

    2016-01-01

    The steady scaling-down of semiconductor device for improving performance has been the most important issue among researchers. Recently, as low-power consumption becomes one of the most important requirements, there have been many researches about novel devices for low-power consumption. Though scaling supply voltage is the most effective way for low-power consumption, performance degradation is occurred for metal-oxide-semiconductor field-effect transistors (MOSFETs) when supply voltage is reduced because subthreshold swing (SS) of MOSFETs cannot be lower than 60 mV/dec. Thus, in this thesis, hetero-gate-dielectric tunneling field-effect transistors (HG TFETs) are investigated as one of the most promising alternatives to MOSFETs. By replacing source-side gate insulator with a high- k material, HG TFETs show higher on-current, suppressed ambipolar current and lower SS than conventional TFETs. Device design optimization through simulation was performed and fabrication based on simulation demonstrated that performance of HG TFETs were better than that of conventional TFETs. Especially, enlargement of gate insulator thickness while etching gate insulator at the source side was improved by introducing HF vapor etch process. In addition, the proposed HG TFETs showed higher performance than our previous results by changing structure of sidewall spacer by high- k etching process.

  18. Si/SiC-based DD hetero-structure IMPATTs as MM-wave power-source: a generalized large-signal analysis

    International Nuclear Information System (INIS)

    Mukherjee, Moumita; Tripathy, P. R.; Pati, S. P.

    2015-01-01

    A full-scale, self-consistent, non-linear, large-signal model of double-drift hetero-structure IMPATT diode with general doping profile is derived. This newly developed model, for the first time, has been used to analyze the large-signal characteristics of hexagonal SiC-based double-drift IMPATT diode. Considering the fabrication feasibility, the authors have studied the large-signal characteristics of Si/SiC-based hetero-structure devices. Under small-voltage modulation (∼ 2%, i.e. small-signal conditions) results are in good agreement with calculations done using a linearised small-signal model. The large-signal values of the diode's negative conductance (5 × 10 6 S/m 2 ), susceptance (10.4 × 10 7 S/m 2 ), average breakdown voltage (207.6 V), and power generating efficiency (15%, RF power: 25.0 W at 94 GHz) are obtained as a function of oscillation amplitude (50% of DC breakdown voltage) for a fixed average current density. The large-signal calculations exhibit power and efficiency saturation for large-signal (> 50%) voltage modulation and thereafter decrease gradually with further increasing voltage-modulation. This generalized large-signal formulation is applicable for all types of IMPATT structures with distributed and narrow avalanche zones. The simulator is made more realistic by incorporating the space-charge effects, realistic field and temperature dependent material parameters in Si and SiC. The electric field snap-shots and the large-signal impedance and admittance of the diode with current excitation are expressed in closed loop form. This study will act as a guide for researchers to fabricate a high-power Si/SiC-based IMPATT for possible application in high-power MM-wave communication systems. (paper)

  19. Synthesis of a pH-Sensitive Hetero[4]Rotaxane Molecular Machine that Combines [c2]Daisy and [2]Rotaxane Arrangements.

    Science.gov (United States)

    Waelès, Philip; Riss-Yaw, Benjamin; Coutrot, Frédéric

    2016-05-10

    The synthesis of a novel pH-sensitive hetero[4]rotaxane molecular machine through a self-sorting strategy is reported. The original tetra-interlocked molecular architecture combines a [c2]daisy chain scaffold linked to two [2]rotaxane units. Actuation of the system through pH variation is possible thanks to the specific interactions of the dibenzo-24-crown-8 (DB24C8) macrocycles for ammonium, anilinium, and triazolium molecular stations. Selective deprotonation of the anilinium moieties triggers shuttling of the unsubstituted DB24C8 along the [2]rotaxane units. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Tunneling Photocurrent Assisted by Interlayer Excitons in Staggered van der Waals Hetero-Bilayers.

    Science.gov (United States)

    Luong, Dinh Hoa; Lee, Hyun Seok; Neupane, Guru Prakash; Roy, Shrawan; Ghimire, Ganesh; Lee, Jin Hee; Vu, Quoc An; Lee, Young Hee

    2017-09-01

    Vertically stacked van der Waals (vdW) heterostructures have been suggested as a robust platform for studying interfacial phenomena and related electric/optoelectronic devices. While the interlayer Coulomb interaction mediated by the vdW coupling has been extensively studied for carrier recombination processes in a diode transport, its correlation with the interlayer tunneling transport has not been elucidated. Here, a contrast is reported between tunneling and drift photocurrents tailored by the interlayer coupling strength in MoSe 2 /MoS 2 hetero-bilayers (HBs). The interfacial coupling modulated by thermal annealing is identified by the interlayer phonon coupling in Raman spectra and the emerging interlayer exciton peak in photoluminescence spectra. In strongly coupled HBs, positive photocurrents are observed owing to the inelastic band-to-band tunneling assisted by interlayer excitons that prevail over exciton recombinations. By contrast, weakly coupled HBs exhibit a negative photovoltaic diode behavior, manifested as a drift current without interlayer excitonic emissions. This study sheds light on tailoring the tunneling transport for numerous optoelectronic HB devices. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. A step-by-step experiment of 3C-SiC hetero-epitaxial growth on 4H-SiC by CVD

    Energy Technology Data Exchange (ETDEWEB)

    Xin, Bin [School of Microelectronics, Xidian University, Key Laboratory of Wide Band-Gap Semiconductor Materials and Devices, Xi’an 710071 (China); Jia, Ren-Xu, E-mail: rxjia@mail.xidian.edu.cn [School of Microelectronics, Xidian University, Key Laboratory of Wide Band-Gap Semiconductor Materials and Devices, Xi’an 710071 (China); Hu, Ji-Chao [School of Microelectronics, Xidian University, Key Laboratory of Wide Band-Gap Semiconductor Materials and Devices, Xi’an 710071 (China); Tsai, Cheng-Ying [Graduate Institute of Electronics Engineering, National Taiwan University, 10617 Taipei, Taiwan (China); Lin, Hao-Hsiung, E-mail: hhlin@ntu.edu.tw [Graduate Institute of Electronics Engineering, National Taiwan University, 10617 Taipei, Taiwan (China); Graduate Institute of Photonics and Optoelectronics, National Taiwan University, 10617 Taipei, Taiwan (China); Zhang, Yu-Ming [School of Microelectronics, Xidian University, Key Laboratory of Wide Band-Gap Semiconductor Materials and Devices, Xi’an 710071 (China)

    2015-12-01

    Highlights: • A step-by-step experiment to investigate the growth mechanism of SiC hetero-epitaxial is proposed. • It has shown protrusive regular “hill” morphology with much lower density of DPB defect in our experiment, which normally were in high density with shallow groove. Based on the defect morphology, an anisotropy migration rate phenomenon of adatoms has been regarded as forming the morphology of DPB defects and a new “DPB defects assist epitaxy” growth mode has been proposed based on Frank-van der Merwe growth mode. - Abstract: To investigate the growth mechanism of hetero-epitaxial SiC, a step-by-step experiment of 3C-SiC epitaxial layers grown on 4H-SiC on-axis substrates by the CVD method are reported in this paper. Four step experiments with four one-quarter 4H-SiC wafers were performed. Optical microscopy and atomic force microscopy (AFM) were used to characterize the morphology of the epitaxial layers. It was previously found that the main factor affecting the epilayer morphology was double-positioning boundary (DPB) defects, which normally were in high density with shallow grooves. However, a protrusive regular “hill” morphology with a much lower density was shown in our experiment in high-temperature growth conditions. The anisotropic migration of adatoms is regarded as forming the morphology of DPB defects, and a new “DPB defects assist epitaxy” growth mode has been proposed based on the Frank-van der Merwe growth mode. Raman spectroscopy and X-ray diffraction were used to examine the polytypes and the quality of the epitaxial layers.

  2. Mononuclear, trinuclear, and hetero-trinuclear supramolecular complexes containing a new tri-sulfonate ligand and cobalt(II)/copper(II)-(1,10-phenanthroline) 2 building blocks

    Science.gov (United States)

    Yu, Yunfang; Wei, Yongqin; Broer, Ria; Sa, Rongjian; Wu, Kechen

    2008-03-01

    Novel mononuclear, trinuclear, and hetero-trinuclear supermolecular complexes, [Co(phen) 2(H 2O)(HTST)]·2H 2O ( 1), [Co 3(phen) 6(H 2O) 2(TST) 2]·7H 2O ( 2), and [Co 2Cu(phen) 6(H 2O) 2(TST) 2]·10H 2O ( 3), have been synthesized by the reactions of a new tri-sulfonate ligand (2,4,6-tris(4-sulfophenylamino)-1,3,5-triazine, H 3TST) with the M2+ ( M=Co, Cu) and the second ligand 1,10-phenanthroline (phen). Complex 1 contains a cis-Co(II)(phen) 2 building block and an HTST as monodentate ligand; complex 2 consists of two TST as bidentate ligands connecting one trans- and two cis-Co(II)(phen) 2 building blocks; complex 3 is formed by replacing the trans-Co(II)(phen) 2 in 2 with a trans-Cu(II)(phen) 2, which is the first reported hetero-trinuclear supramolecular complex containing both the Co(II)(phen) 2 and Cu(II)(phen) 2 as building blocks. The study shows the flexible multifunctional self-assembly capability of the H 3TST ligands presenting in these supramolecular complexes through coordinative, H-bonding and even π- π stacking interactions. The photoluminescent optical properties of these complexes are also investigated and discussed as well as the second-order nonlinear optical properties of 1.

  3. Photovoltaic properties of pentacene/[6,6]-phenyl C61 butyric acid methyl ester based bilayer hetero-junction solar cells

    International Nuclear Information System (INIS)

    Reddy, V S; Karak, S; Ray, S K; Dhar, A

    2009-01-01

    The photovoltaic properties of devices based on a new combination, pentacene/[6,6]-phenyl C 61 butyric acid methyl ester (PCBM) bilayer hetero-junctions, were investigated. The crystallinity of pentacene was found to be improved by depositing a PEDOT : PSS layer on an indium tin oxide substrate, which in turn doubled the power conversion efficiency of the device. The PCBM layer showed a significant contribution to the device photocurrent, which originated mainly due to the dissociation of excitons at the pentacene/PCBM interface. By optimizing the thickness of the pentacene and PCBM layers, a broader photo-response was obtained in the external quantum efficiency spectra indicating efficient light harvesting throughout the visible region of the solar spectrum.

  4. Hetero-Colloidal Metal Particle Multilayer Films Grown Using Electrostatic Interactions at the Air-water Interface

    International Nuclear Information System (INIS)

    Sastry, Murali; Mayya, K.S.

    2000-01-01

    The formation of nanoparticle multilayer films by electrostatic immobilization of surface-modified colloidal particles at the air-water interface has been recently demonstrated by us. In this paper, we extend our study to show that multilayer assemblies consisting of metal particles of different chemical nature (hetero-colloidal particle superlattices) and size can be deposited by the versatile Langmuir-Blodgett technique. Multilayer films consisting of a different number of bilayers of gold and silver colloidal particles have been deposited and characterized using quartz crystal microgravimetry and UV-visible spectroscopy measurements. It is observed that while layer-by-layer deposition of the different colloidal particle assemblies is possible by this technique without a detectable variation in the cluster density in the different layers, a degree of post-deposition reorganization of the clusters occurs in the film. In addition to this aging behavior, the effect of different organic solvents on the reorganization process has also been studied

  5. [The professional self and hetero image among public health nurses: a study of social representations].

    Science.gov (United States)

    Gomes, Antonio Marcos Tosoli; Oliveira, Denize Cristina de

    2005-01-01

    The object of this study is the professional image constructed by public health nurses and the objective is to describe and analyze the professional images present in the representations of nurses who deliver direct care to this clientele. The theoretical-methodological reference framework adopted was Social Representations Theory. A qualitative study was developed in Petrópolis-Rio de Janeiro/Brazil, through in-depth interviews with 30 nurses. Alceste 4.5 software was used for the lexical analysis. The results reveal the existence of a professional self-image with three groups of meanings: being a reference for the team, the non-specific image and the image of plaster; and a professional hetero-image with four groups of meanings: administrator, invisible, positive image and superposition. The study of the professional image reflects the construction of the nurse's identity in itself and emphasizes Social Representations Theory as a useful tool for nursing research development.

  6. Amorphous Oxide Thin Film Transistors with Nitrogen-Doped Hetero-Structure Channel Layers

    Directory of Open Access Journals (Sweden)

    Haiting Xie

    2017-10-01

    Full Text Available The nitrogen-doped amorphous oxide semiconductor (AOS thinfilm transistors (TFTs with double-stacked channel layers (DSCL were prepared and characterized. The DSCL structure was composed of nitrogen-doped amorphous InGaZnO and InZnO films (a-IGZO:N/a-IZO:N or a-IZO:N/a-IGZO:N and gave the corresponding TFT devices large field-effect mobility due to the presence of double conduction channels. The a-IZO:N/a-IGZO:N TFTs, in particular, showed even better electrical performance (µFE = 15.0 cm2・V−1・s−1, SS = 0.5 V/dec, VTH = 1.5 V, ION/IOFF = 1.1 × 108 and stability (VTH shift of 1.5, −0.5 and −2.5 V for positive bias-stress, negative bias-stress, and thermal stress tests, respectively than the a-IGZO:N/a-IZO:N TFTs. Based on the X-ray photoemission spectroscopy measurements and energy band analysis, we assumed that the optimized interface trap states, the less ambient gas adsorption, and the better suppression of oxygen vacancies in the a-IZO:N/a-IGZO:N hetero-structures might explain the better behavior of the corresponding TFTs.

  7. Tunnel field-effect transistors with germanium/strained-silicon hetero-junctions for low power applications

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Minsoo, E-mail: minsoo@mosfet.t.u-tokyo.ac.jp; Kim, Younghyun; Yokoyama, Masafumi; Nakane, Ryosho; Kim, SangHyeon; Takenaka, Mitsuru; Takagi, Shinichi

    2014-04-30

    We have studied a simple structure n-channel tunnel field-effect transistor with a pure-Ge/strained-Si hetero-junction. The device operation was demonstrated for the devices fabricated by combining epitaxially-grown Ge on strained-silicon-on-insulator substrates. Atomic-layer-deposition-Al{sub 2}O{sub 3}-based gate stacks were formed with electron cyclotron resonance plasma post oxidation to ensure the high quality metal–oxide–semiconductor interface between the high-k insulator and Ge. While the gate leakage current and drain current saturation are well controlled, relatively higher minimum subthreshold swing of 125 mV/dec and lower I{sub ON}/I{sub OFF} ratio of 10{sup 3}–10{sup 4} were obtained. It is expected that these device characteristics can be improved by further process optimization. - Highlights: • Layer by layer growth of Ge • Uniform interface between Ge and the insulator • Gate leakage current and drain current saturation seem to be well controlled. • The output characteristics show good saturation.

  8. Uncovering homo-and hetero-interactions on the cell membrane using single particle tracking approaches

    International Nuclear Information System (INIS)

    Torreno-Pina, Juan A; Manzo, Carlo; Garcia-Parajo, Maria F

    2016-01-01

    The plasma membrane of eukaryotic cells is responsible for a myriad of functions that regulate cell physiology and plays a crucial role in a multitude of processes that include adhesion, migration, signaling recognition and cell–cell communication. This is accomplished by specific interactions between different membrane components such as lipids and proteins on the lipid bilayer but also through interactions with the underlying cortical actin cytoskeleton on the intracellular side and the glycocalyx matrix in close proximity to the extracellular side. Advanced biophysical techniques, including single particle tracking (SPT) have revealed that the lateral diffusion of molecular components on the plasma membrane represents a landmark manifestation of such interactions. Indeed, by studying changes in the diffusivity of individual membrane molecules, including sub-diffusion, confined diffusion and/or transient arrest of molecules in membrane compartments, it has been possible to gain insight on the nature of molecular interactions and to infer on its functional role for cell response. In this review, we will revise some exciting results where SPT has been crucial to reveal homo- and hetero-interactions on the cell membrane. (paper)

  9. Facile fabrication and electrical investigations of nanostructured p-Si/n-TiO2 hetero-junction diode

    Science.gov (United States)

    Kumar, Arvind; Mondal, Sandip; Rao, K. S. R. Koteswara

    2018-05-01

    In this work, we have fabricated the nanostructured p-Si/n-TiO2 hetero-junction diode by using a facile spin-coating method. The XRD analysis suggests the presence of well crystalline anatase TiO2 film on Si with small grain size (˜16 nm). We have drawn the band alignment using Anderson model to understand the electrical transport across the junction. The current-voltage (J-V) characteristics analysis reveals the good rectification ratio (103 at ± 3 V) and slightly higher ideality factor (4.7) of our device. The interface states are responsible for the large ideality factor as Si/TiO2 form a dissimilar interface and possess a large number of dangling bonds. The study reveals the promises to be used Si/TiO2 diode as an alternative to the traditional p-n homo-junction diode, which typically require high budget.

  10. High Temperature and High Sensitive NOx Gas Sensor with Hetero-Junction Structure using Laser Ablation Method

    Science.gov (United States)

    Gao, Wei; Shi, Liqin; Hasegawa, Yuki; Katsube, Teruaki

    In order to develop a high temperature (200°C˜400°C) and high sensitive NOx gas sensor, we developed a new structure of SiC-based hetero-junction device Pt/SnO2/SiC/Ni, Pt/In2O3/SiC/Ni and Pt/WO3/SiC/Ni using a laser ablation method for the preparation of both metal (Pt) electrode and metal-oxide film. It was found that Pt/In2O3/SiC/Ni sensor shows higher sensitivity to NO2 gas compared with the Pt/SnO2/SiC/Ni and Pt/WO3/SiC/Ni sensor, whereas the Pt/WO3/SiC/Ni sensor had better sensitivity to NO gas. These results suggest that selective detection of NO and NO2 gases may be obtained by choosing different metal oxide films.

  11. The crystal orientation relation and macroscopic surface roughness in hetero-epitaxial graphene grown on Cu/mica

    International Nuclear Information System (INIS)

    Qi, J L; Nagashio, K; Nishimura, T; Toriumi, A

    2014-01-01

    Clean, flat and orientation-identified graphene on a substrate is in high demand for graphene electronics. In this study, the hetero-epitaxial graphene growth on Cu(111)/mica(001) by chemical vapor deposition is investigated to check the applicability for top-gate insulator research on graphene, as well as graphene channel research, by transferring graphene on to SiO 2 /Si substrates. After adjusting the graphene growth conditions, the surface roughness of the graphene/Cu/mica substrate and the average smoothed areas are ∼0.34 nm and ∼100 μm 2 , respectively. The orientation of graphene in the graphene/Cu/mica substrate can be identified by the hexagonal void morphology of Cu. Moreover, we demonstrate a relatively high mobility of ∼4500 cm 2 V −1 s −1 in graphene transferred on the SiO 2 /Si substrate. These results suggest that the present graphene/Cu/mica substrate can be used for top-gate insulator research on graphene. (papers)

  12. Versatile nature of hetero-chitosan based derivatives as biodegradable adsorbent for heavy metal ions; a review.

    Science.gov (United States)

    Ahmad, Mudasir; Manzoor, Kaiser; Ikram, Saiqa

    2017-12-01

    The polyfunctional chitosan can act as the biological macromolecule ligand not only for the adsorption and the recovery of metal ions from an aqueous media, but also for the fabrication of novel adsorbents which shows selectivity and better adsorption properties. The unmodified chitosan itself, a single cationic polysaccharide, has hydroxyl and amine groups carrying complex properties with the metal ions. In addition, the selectivity of metal ions, the adsorption efficiency and adsorption capacity of the adsorbent can be modified chemically. This review covers the synthetic strategies of chitosan towards the synthesis of hetero-chitosan based adsorbents via chemical modifications in past two decades. It also includes how chemical modification influences the metal adsorption with N, O, S and P containing chitosan derivatives. Hope this review article provides an opportunity for researchers in the future to explore the potential of chitosan as an adsorbent for removal of metal ions from wastewater. Copyright © 2017 Elsevier B.V. All rights reserved.

  13. Effects of Different Solvents on the Planar Hetero-junction Perovskite Solar Cells

    Directory of Open Access Journals (Sweden)

    Lin Shunquan

    2015-01-01

    Full Text Available The perovskite (CH3NH3PbI3 films on the planar hetero-junction perovskite solar cells (PHJ-PSCs are fabricated by “two-steps” process with the wet spin-coating method. The precursor (PbI2 solutions are compounded with 4 types of solvents: N-Methyl Pyrrolidone (NMP, γ-butyrolactone (GBL, Dimethyl Sulfoxide (DMSO and N, N-dimethylformamide (DMF. All the solutions have the same concentration. The influences of different precursor solvents to the micro-structures of CH3NH3PbI3 films and device performance are studied. Atomic force microscopy (AFM and scanning electron microscope (SEM are used to characterize the CH3NH3PbI3 films. The results indicate that the CH3NH3PbI3 film using DMF solvent possesses more rough morphology and thickest thickness. The monolithic PHJ-PSCs devices based on DMF solvent are tested under a standard one sun of simulated solar irradiation (AM1.5. The results show that the open-circuit voltage (Voc reaches 872mV, the short-circuit current (Jsc reaches 9.35mA/cm2, the filling factor(FF is 0.62 and the photo-current conversion efficiency (PCE is 5.05%. DMF is the best one among these 4 types of solvents for PHJ-PSCs.

  14. Hetero- and homogeneous three-dimensional hierarchical tungsten oxide nanostructures by hot-wire chemical vapor deposition

    Energy Technology Data Exchange (ETDEWEB)

    Houweling, Z.S., E-mail: Silvester.Houweling@asml.com [Utrecht University, Debye Institute for Nanomaterials Science, Nanophotonics—Physics of Devices, Princetonlaan 4, 3584 CB Utrecht (Netherlands); Harks, P.-P.R.M.L.; Kuang, Y.; Werf, C.H.M. van der [Utrecht University, Debye Institute for Nanomaterials Science, Nanophotonics—Physics of Devices, Princetonlaan 4, 3584 CB Utrecht (Netherlands); Geus, J.W. [Utrecht University, Inorganic Chemistry and Catalysis, Padualaan 8, 3584 CH Utrecht (Netherlands); Schropp, R.E.I. [Utrecht University, Debye Institute for Nanomaterials Science, Nanophotonics—Physics of Devices, Princetonlaan 4, 3584 CB Utrecht (Netherlands)

    2015-01-30

    We present the synthesis of three-dimensional tungsten oxide (WO{sub 3−x}) nanostructures, called nanocacti, using hot-wire chemical vapor deposition. The growth of the nanocacti is controlled through a succession of oxidation, reduction and re-oxidation processes. By using only a resistively heated W filament, a flow of ambient air and hydrogen at subatmospheric pressure, and a substrate heated to about 700 °C, branched nanostructures are deposited. We report three varieties of simple synthesis approaches to obtain hierarchical homo- and heterogeneous nanocacti. Furthermore, by using catalyst nanoparticles site-selection for the growth is demonstrated. The atomic, morphological and crystallographic compositions of the nanocacti are determined using a combination of electron microscopy techniques, energy-dispersive X-ray spectroscopy and electron diffraction. - Highlights: • Continuous upscalable hot-wire CVD of 3D hierarchical nanocacti • Controllable deposition of homo- and heterogeneous WO{sub 3−x}/WO{sub 3−y} nanocacti • Introduction of three synthesis routes comprising oxidation, reduction and re-oxidation processes • Growth of periodic arrays of hetero- and homogeneous hierarchical 3D nanocacti.

  15. Growth and characterization of tin oxide thin films and fabrication of transparent p-SnO/n-ZnO p–n hetero junction

    Energy Technology Data Exchange (ETDEWEB)

    Sanal, K.C., E-mail: sanalcusat@gmail.com [Nanophotonic and Optoelectronic Devices Laboratory, Department of Physics, Cochin University of Science and Technology, Kerala 682 022 (India); Inter University Center for Nanomaterials and Devices (IUCND), Cochin University of Science and Technology (India); Jayaraj, M.K. [Nanophotonic and Optoelectronic Devices Laboratory, Department of Physics, Cochin University of Science and Technology, Kerala 682 022 (India)

    2013-07-01

    Highlights: • Growth of p-type semiconducting SnO thin films by rf sputtering. • Varying the type of charge carriers with oxygen partial pressure. • Atomic percentage of SnO{sub x} thin films from the XPS analysis. • Demonstration of transparent p–n hetero junctions fabricated in the structure glass/ITO/n-ZnO/p-SnO. -- Abstract: p-Type and n-type tin oxide thin films were deposited by rf-magnetron sputtering of metal tin target by varying the oxygen pressure. Chemical composition of SnO thin film according to the intensity of the XPS peak is about 48.85% and 51.15% for tin and oxygen respectively. Nearest neighbor distance of the atoms calculated from SAED patterns is 2.9 Åand 2.7 Åfor SnO and SnO{sub 2} respectively. The Raman scattering spectrum obtained from SnO thin films showed two peaks, one at 113 cm{sup −1} and the other at 211 cm{sup −1}. Band gap of as-deposited SnO{sub x} thin films vary from 1.6 eV to 3.2 eV on varying the oxygen partial pressure from 3% to 30% which indicates the oxidization of metallic phase Sn to SnO and SnO{sub 2}. p-Type conductivity of SnO thin films and n-type conductivity of SnO{sub 2} thin films were confirmed through Hall coefficient measurement. Transparent p–n hetero junction fabricated in the structure glass/ITO/n-ZnO/p-SnO shows rectification with forward to reverse current ratio as 12 at 4.5 V.

  16. Acousto-optical interaction of surface acoustic and optical waves in a two-dimensional phoxonic crystal hetero-structure cavity.

    Science.gov (United States)

    Ma, Tian-Xue; Zou, Kui; Wang, Yue-Sheng; Zhang, Chuanzeng; Su, Xiao-Xing

    2014-11-17

    Phoxonic crystal is a promising material for manipulating sound and light simultaneously. In this paper, we theoretically demonstrate the propagation of acoustic and optical waves along the truncated surface of a two-dimensional square-latticed phoxonic crystal. Further, a phoxonic crystal hetero-structure cavity is proposed, which can simultaneously confine surface acoustic and optical waves. The interface motion and photoelastic effects are taken into account in the acousto-optical coupling. The results show obvious shifts in eigenfrequencies of the photonic cavity modes induced by different phononic cavity modes. The symmetry of the phononic cavity modes plays a more important role in the single-phonon exchange process than in the case of the multi-phonon exchange. Under the same deformation, the frequency shift of the photonic transverse electric mode is larger than that of the transverse magnetic mode.

  17. A novel approach for the improvement of electrostatic behaviour of physically doped TFET using plasma formation and shortening of gate electrode with hetero-gate dielectric

    Science.gov (United States)

    Soni, Deepak; Sharma, Dheeraj; Aslam, Mohd.; Yadav, Shivendra

    2018-04-01

    This article presents a new device configuration to enhance current drivability and suppress negative conduction (ambipolar conduction) with improved RF characteristics of physically doped TFET. Here, we used a new approach to get excellent electrical characteristics of hetero-dielectric short gate source electrode TFET (HD-SG SE-TFET) by depositing a metal electrode of 5.93 eV work function over the heavily doped source (P+) region. Deposition of metal electrode induces the plasma (thin layer) of holes under the Si/HfO2 interface due to work function difference of metal and semiconductor. Plasma layer of holes is advantageous to increase abruptness as well as decrease the tunneling barrier at source/channel junction for attaining higher tunneling rate of charge carriers (i.e., electrons), which turns into 86.66 times higher ON-state current compared with the conventional physically doped TFET (C-TFET). Along with metal electrode deposition, gate electrode is under-lapped for inducing asymmetrical concentration of charge carriers in the channel region, which is helpful for widening the tunneling barrier width at the drain/channel interface. Consequently, HD-SG SE-TFET shows suppression of ambipolar behavior with reduction in gate-to-drain capacitance which is beneficial for improvement in RF performance. Furthermore, the effectiveness of hetero-gate dielectric concept has been used for improving the RF performance. Furthermore, reliability of C-TFET and proposed structures has been confirmed in term of linearity.

  18. Mild and modular surface modification of cellulose via hetero Diels-Alder (HDA) cycloaddition.

    Science.gov (United States)

    Goldmann, Anja S; Tischer, Thomas; Barner, Leonie; Bruns, Michael; Barner-Kowollik, Christopher

    2011-04-11

    A combination of reversible addition-fragmentation chain transfer (RAFT) polymerization and hetero Diels-Alder (HDA) cycloaddition was used to effect, under mild (T ≈ 20 °C), fast, and modular conditions, the grafting of poly(isobornyl acrylate) (M(n) = 9800 g mol(-1), PDI = 1.19) onto a solid cellulose substrate. The active hydroxyl groups expressed on the cellulose fibers were converted to tosylate leaving groups, which were subsequently substituted by a highly reactive cyclopentadienyl functionality (Cp). By employing the reactive Cp-functionality as a diene, thiocarbonyl thio-capped poly(isobornyl acrylate) synthesized via RAFT polymerization (mediated by benzyl pyridine-2-yldithioformiate (BPDF)) was attached to the surface under ambient conditions by an HDA cycloaddition (reaction time: 15 h). The surface-modified cellulose samples were analyzed in-depth by X-ray photoelectron spectroscopy, scanning electron microscopy, elemental analysis, Fourier transform infrared (FT-IR) spectroscopy as well as Fourier transform infrared microscopy employing a focal plane array detector for imaging purposes. The analytical results provide strong evidence that the reaction of suitable dienophiles with Cp-functional cellulose proceeds under mild reaction conditions (T ≈ 20 °C) in an efficient fashion. In particular, the visualization of individual modified cellulose fibers via high-resolution FT-IR microscopy corroborates the homogeneous distribution of the polymer film on the cellulose fibers.

  19. Palladium Gate All Around - Hetero Dielectric -Tunnel FET based highly sensitive Hydrogen Gas Sensor

    Science.gov (United States)

    Madan, Jaya; Chaujar, Rishu

    2016-12-01

    The paper presents a novel highly sensitive Hetero-Dielectric-Gate All Around Tunneling FET (HD-GAA-TFET) based Hydrogen Gas Sensor, incorporating the advantages of band to band tunneling (BTBT) mechanism. Here, the Palladium supported silicon dioxide is used as a sensing media and sensing relies on the interaction of hydrogen with Palladium-SiO2-Si. The high surface to volume ratio in the case of cylindrical GAA structure enhances the fortuities for surface reactions between H2 gas and Pd, and thus improves the sensitivity and stability of the sensor. Behaviour of the sensor in presence of hydrogen and at elevated temperatures is discussed. The conduction path of the sensor which is dependent on sensors radius has also been varied for the optimized sensitivity and static performance analysis of the sensor where the proposed design exhibits a superior performance in terms of threshold voltage, subthreshold swing, and band to band tunneling rate. Stability of the sensor with respect to temperature affectability has also been studied, and it is found that the device is reasonably stable and highly sensitive over the bearable temperature range. The successful utilization of HD-GAA-TFET in gas sensors may open a new door for the development of novel nanostructure gas sensing devices.

  20. Homo- or Hetero- Triplet-Triplet Annihilation? A Case Study with Perylene-Bodipy Dyads/Triads

    KAUST Repository

    Cui, Xiaoneng

    2017-07-06

    The photophysical processes of intramolecular ‘ping-pong’ energy transfers in the iodinated reference dyad BDP-I2-Py, as well as the uniodinated dyad BDP-Py and triad BDP-2Py, were studied. For BDP-I2-Py, a forward Förster resonance energy transfer (FRET) from the perylene (Py) unit to the diiodoBDP unit (7 ps) and a backward triplet energy transfer (TTET, 3 ns) from the diiodoBDP unit to the Py unit were observed. For the BDP-Py and BDP-2Py systems, a FRET (5 ~ 8 ps) and a photo-induced electron transfer (PET) (1-1.5 ns) were observed in acetonitrile. The uniodinated dyad and triad were used as the triplet energy acceptor and emitter for a TTA upconversion with palladium tetraphenyltetrabenzoporphyrin as the triplet photosensitizer. A maximum upconversion quantum yield of 12.6 % was measured. Given that the dyad (BDP-Py) contains one BDP unit and one Py unit, while the triad (BDP-2Py) contains two Py units and one BDP unit, and based on the results from steady-state femtosecond and nanosecond transient optical spectroscopies, it is concluded that neither intramolecular homo- triplet-triplet annihilation (TTA) nor intramolecular hetero-TTA is possible during a TTA upconversion for those upconversion systems.

  1. Single Site Mutations in the Hetero-oligomeric Mrp Antiporter from Alkaliphilic Bacillus pseudofirmus OF4 That Affect Na+/H+ Antiport Activity, Sodium Exclusion, Individual Mrp Protein Levels, or Mrp Complex Formation*

    OpenAIRE

    Morino, Masato; Natsui, Shinsuke; Ono, Tomohiro; Swartz, Talia H.; Krulwich, Terry A.; Ito, Masahiro

    2010-01-01

    Mrp systems are widely distributed and structurally complex cation/proton antiporters. Antiport activity requires hetero-oligomeric complexes of all six or seven hydrophobic Mrp proteins (MrpA–MrpG). Here, a panel of site-directed mutants in conserved or proposed motif residues was made in the Mrp Na+(Li+)/H+ antiporter from an alkaliphilic Bacillus. The mutant operons were expressed in antiporter-deficient Escherichia coli KNabc and assessed for antiport properties, support of sodium resista...

  2. Flavan hetero-dimers in the Cymbopogon citratus infusion tannin fraction and their contribution to the antioxidant activity.

    Science.gov (United States)

    Costa, Gustavo; González-Manzano, Susana; González-Paramás, Ana; Figueiredo, Isabel Vitória; Santos-Buelga, Celestino; Batista, Maria Teresa

    2015-03-01

    Cymbopogon citratus (lemongrass) leaf infusion, a commonly used ingredient in Asian, African and Latin American cuisines, is also used in traditional medicine for the treatment of several pathological conditions; however, little is known about their bioactive compounds. Recent studies revealed the crucial role of the phenolic compounds namely flavonoids and tannins on the infusion bioactivity. Flavonoids have already been characterized; however the tannin fraction of lemongrass infusion is still uncharted. The aim of the present work is to characterize this fraction, and to evaluate its contribution to the antioxidant potential of this plant. Chemical characterization was achieved by HPLC-DAD-ESI/tandem MS and the antioxidant activity was evaluated using DPPH, ABTS and FRAP assays. Hetero-dimeric flavan structures have been described for the first time in lemongrass consisting of apigeniflavan or luteoliflavan units linked to a flavanone, either naringenin or eriodictyol, which may occur as aglycone or glycosylated forms. The antioxidant capacity of the fraction containing these compounds was significantly higher than the infusion, indicating its potential as a source of natural antioxidants.

  3. The Longitudinal Force Measurement of CWR Tracks with Hetero-Cladding FBG Sensors: A Proof of Concept

    Directory of Open Access Journals (Sweden)

    Li-Yang Shao

    2016-12-01

    Full Text Available A new method has been proposed to accurately determine longitudinal additional force in continuous welded rail (CWR on bridges via hetero-cladding fiber Bragg grating (HC-FBG sensors. The HC-FBG sensor consists of two FBGs written in the same type of fiber but with different cladding diameters. The HC-FBGs have the same temperature sensitivity but different strain sensitivity because of the different areas of the cross section. The differential strain coefficient is defined as the relative wavelength differences of two FBGs with the change of applied longitudinal force. In the verification experiment in the lab, the HC-FBGs were attached on a section of rail model of which the material property is the same as that of rail on line. The temperature and differential strain sensitivity were calibrated using a universal testing machine. As shown by the test results, the linearity between the relative wavelength difference and the longitudinal additional force is greater than 0.9999. The differential strain sensitivity is 4.85 × 10−6/N. Moreover, the relative wavelength difference is not affected by the temperature change. Compared to the theoretical results, the accumulated error is controlled within 5.0%.

  4. An ARC less InGaP/GaAs DJ solar cell with hetero tunnel junction

    Science.gov (United States)

    Sahoo, G. S.; Nayak, P. P.; Mishra, G. P.

    2016-07-01

    Multi junction solar cell has not achieved an optimum performance yet. To acquire more conversion efficiency research on multi junction solar cell are in progress. In this work we have proposed a dual junction solar cell with conversion efficiency of 43.603%. Mainly the focus is given on the tunnel diode, window layer and back surface field (BSF) layer of the cell, as all of them plays important role on the cell performance. Here we have designed a hetero InGaP/GaAs tunnel diode which makes tunnel diode more transparent to the bottom cell as well as reduces the recombination at the interfaces. The thickness of the window and BSF layer are optimized to achieve higher conversion efficiency. The simulation is carried out using Silvaco ATLAS TCAD under 1000 sun of AM1.5G spectrum. Different performance parameters of the cell like short circuit current density (Jsc), open circuit voltage (Voc), external quantum efficiency (EQE), fill factor (FF), conversion efficiency (η), spectral response and photogeneration rate of the cell are examined and compared with previously reported literatures. For the proposed model a Voc of 2.7043 V, Jsc of 1898.52 mA/cm2, FF of 88.88% and η of 43.6% are obtained.

  5. Superhalogen properties of hetero-binuclear anions MM‧F4- and MM″F5- (M = Li, Na, M‧ = Be, Mg, Ca; M″ = B, Al, Ga)

    Science.gov (United States)

    Yang, Hui; Li, Ying; He, Hui-Min; Tong, Jing; Wu, Di; Li, Zhi-Ru

    2017-09-01

    Hetero-binuclear superhalogen anions, namely MM‧F4- and MM″F5- (M = Li, Na; M‧ = Be, Mg, Ca; M″ = B, Al, Ga), have been theoretically characterized at the MP2(FULL)/6-311+G(3df) level. It is found that two central atoms can be linked by at most three fluorine ligands. The large vertical electron detachment energies (VDEs, 7.449-8.978 eV) verify the superhalogen identity of these anions. The VDEs of both MM‧F4- and MM″F5- decrease when the atomic size of M increases whereas increase with the size of M‧ and M″. Besides, the extra electron distribution also has effect on the VDEs of such superhalogen anions.

  6. Effect of repeat unit structure and molecular mass of lactic acid bacteria hetero-exopolysaccharides on binding to milk proteins

    DEFF Research Database (Denmark)

    Birch, Johnny; HarÐarson, HörÐur Kári; Khan, Sanaullah

    2017-01-01

    -exopolysaccharides (HePSs) of 0.14–4.9 MDa from lactic acid bacteria to different milk proteins (β-casein, κ-casein, native and heat-treated β-lactoglobulin) at pH 4.0–5.0. Maximum binding capacity (RUmax) and apparent affinity (KA,app) were HePS- and protein-dependent and varied for example 10- and 600-fold......, respectively, in the complexation with native β-lactoglobulin at pH 4.0. Highest RUmax and KA,app were obtained with heat-treated β-lactoglobulin and β-casein, respectively. Overall, RUmax and KA,app decreased 6- and 20-fold, respectively, with increasing pH from 4.0 to 5.0. KA,app was influenced by ionic......Interactions of exopolysaccharides and proteins are of great importance in food science, but complicated to analyze and quantify at the molecular level. A surface plasmon resonance procedure was established to characterize binding of seven structure-determined, branched hetero...

  7. Influence of Pt Gate Electrode Thickness on the Hydrogen Gas Sensing Characteristics of Pt/In2O3/SiC Hetero-Junction Devices

    Directory of Open Access Journals (Sweden)

    S. Kandasamy

    2007-09-01

    Full Text Available Hetero-junction Pt/In2O3/SiC devices with different Pt thickness (30, 50 and 90nm were fabricated and their hydrogen gas sensing characteristics have been studied. Pt and In2O3 thin films were deposited by laser ablation. The hydrogen sensitivity was found to increase with decreasing Pt electrode thickness. For devices with Pt thickness of 30 nm, the sensitivity gradually increased with increasing temperature and reached a maximum of 390 mV for 1% hydrogen in air at 530°C. Atomic force microscopy (AFM analysis revealed a decrease in Pt grain size and surface roughness for increasing Pt thickness. The relationship between the gas sensing performance and the Pt film thickness and surface morphology is discussed.

  8. Photoelectrochemical enhancement of ZnO/BiVO4/ZnFe2O4/rare earth oxide hetero-nanostructures

    Science.gov (United States)

    She, Xuefeng; Zhang, Zhuo; Baek, Minki; Yong, Kijung

    2018-01-01

    Over the decades, researchers have made great efforts to turn the world into a cleaner place through efficient recycling of industrial waste and developing of green energy. Here we demonstrate a prototype heterostructure photoelectrochemical (PEC) cell fabricated using recycled industrial waste. ZnFe2O4 (ZFO) nanorod (NR) clusters were synthesized on the BiVO4@ZnO hetero-nanostructures using recycled rare earth oxide (REO) slags as Fe source. The NR-based PEC cell exhibited a significantly enhanced photon to hydrogen conversion efficiency over the entire UV and visible spectrum. Further study demonstrates that the photo-carrier separation and migration processes can be facilitated by the cascade band alignment of the heterostructure and the clustered nanostructure network. In addition, the life-time of the photo-carriers can be enhanced by the REO passivation layer, leading to a further increased PEC performance. Our results present a novel approach for high efficiency PEC cells, and offer great promises to the efficient recycling of industrial waste for clean renewable energy applications.

  9. Electrical charging characteristics of the hetero layer film for reducing water-borne paint contamination in electrostatic rotary atomizers

    Energy Technology Data Exchange (ETDEWEB)

    Yamada, Y.; Imanishi, T.; Yoshida, O.; Mizuno, A. [ABB Japan, Tokyo (Japan)

    2010-07-01

    The electrostatic rotary atomizer is the most efficient of all liquid spray painting methods. Its use minimizes the waste of paint and reduces emissions of volatile organic compounds (VOCs). Water-borne painting processes which use water-soluble paint also reduce VOC emissions, but the atomizer body is easily contaminated by the paint mists. The Institute of Electrical and Electronics Engineers (IEEE) considered the causes of water-borne paint contamination and presented the experimental results of a contamination proof system in which the atomizer is surrounded by the repelling film that is charged and repels the incoming paint droplets. Among the key factors for repelling film were electrical properties, such as low capacitance and high insulation to keep high surface potential. Charging uniformity was found to be among the most important characteristic to avoid contamination. The pulse electro-acoustic (PEA) method was used to check these features using space charge measurements inside the repelling film. It was concluded that hetero layer films have more uniform charging characteristics than single layer films.

  10. sp-d Exchange Interactions in Wave Function Engineered Colloidal CdSe/Mn:CdS Hetero-Nanoplatelets.

    Science.gov (United States)

    Muckel, Franziska; Delikanli, Savas; Hernández-Martínez, Pedro Ludwig; Priesner, Tamara; Lorenz, Severin; Ackermann, Julia; Sharma, Manoj; Demir, Hilmi Volkan; Bacher, Gerd

    2018-03-14

    In two-dimensional (2D) colloidal semiconductor nanoplatelets, which are atomically flat nanocrystals, the precise control of thickness and composition on the atomic scale allows for the synthesis of heterostructures with well-defined electron and hole wave function distributions. Introducing transition metal dopants with a monolayer precision enables tailored magnetic exchange interactions between dopants and band states. Here, we use the absorption based technique of magnetic circular dichroism (MCD) to directly prove the exchange coupling of magnetic dopants with the band charge carriers in hetero-nanoplatelets with CdSe core and manganese-doped CdS shell (CdSe/Mn:CdS). We show that the strength of both the electron as well as the hole exchange interactions with the dopants can be tuned by varying the nanoplatelets architecture with monolayer accuracy. As MCD is highly sensitive for excitonic resonances, excited level spectroscopy allows us to resolve and identify, in combination with wave function calculations, several excited state transitions including spin-orbit split-off excitonic contributions. Thus, our study not only demonstrates the possibility to expand the extraordinary physical properties of colloidal nanoplatelets toward magneto-optical functionality by transition metal doping but also provides an insight into the excited state electronic structure in this novel two-dimensional material.

  11. Mineralization of hetero bi-functional reactive dye in aqueous solution by Fenton and photo-Fenton reactions.

    Science.gov (United States)

    Torrades, Francesc; García-Hortal, José Antonio; García-Montaño, Julia

    2015-01-01

    This study focused on the advanced oxidation of the hetero bi-functional reactive dye Sumifix Supra Yellow 3RF (CI Reactive Yellow 145) using dark Fenton and photo-Fenton conditions in a lab-scale experiment. A 2(3) factorial design was used to evaluate the effects of the three key factors: temperature, Fe(II) and H2O2 concentrations, for a dye concentration of 250 mg L(-1) with chemical oxygen demand (COD) of 172 mg L(-1) O2 at pH=3. The response function was the COD reduction. This methodology lets us find the effects and interactions of the studied variables and their roles in the efficiency of the treatment process. In the optimization, the correlation coefficients for the model (R2) were 0.948 and 0.965 for Fenton and photo-Fenton treatments, respectively. Under optimized reaction conditions: pH=3, temperature=298 K, [H2O2]=11.765 mM and [Fe(II)]=1.075 mM; 60 min of treatment resulted in a 79% and 92.2% decrease in COD, for the dye taken as the model organic compound, after Fenton and photo-Fenton treatments, respectively.

  12. N,N'-dioxide/nickel(II)-catalyzed asymmetric inverse-electron-demand hetero-diels-alder reaction of β,γ-unsaturated α-ketoesters with enecarbamates.

    Science.gov (United States)

    Zhou, Yuhang; Zhu, Yin; Lin, Lili; Zhang, Yulong; Zheng, Jianfeng; Liu, Xiaohua; Feng, Xiaoming

    2014-12-08

    N,N'-Dioxide/nickel(II) complexes have been developed to catalyze the inverse-electron-demand hetero-Diels-Alder reaction of β,γ-unsaturated α-ketoesters with acyclic enecarbamates. After detailed screening of the reaction parameters, mild optimized reaction conditions were established, affording 3,4-dihydro-2H-pyranamines in up to 99 % yield, 99 % ee and more than 95:5 d.r. The catalytic system was also efficient for β-substituted acyclic enecarbamates, affording more challenging 2,3,4-trisubstituted 3,4-dihydro-2H-pyranamine with three contiguous stereogenic centers in excellent yields, diastereoselectivities, and enantioselectivities. The reaction could be scaled up to a gram scale with no deterioration of either enantioselectivity or yield. Based on these experiments and on previous reports, a possible transition state was proposed. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. Effect of thermal strain on structure and polarization fatigue of CSD-derived PbZr0.53Ti0.47O3/LaNiO3 hetero-structures

    International Nuclear Information System (INIS)

    Wang, G.S.; Remiens, D.; Dogheche, E.; Dong, X.L.

    2007-01-01

    PbZr 0.53 Ti 0.47 O 3 /LaNiO 3 (PZT/LNO) hetero-structures have been successfully deposited on MgO, SrTiO 3 , Al 2 O 3 and Si substrate by chemical solution routes, respectively. The X-ray diffraction measurements show that out-of-plane lattice parameters of PZT increase as increase of thermal expansion coefficient of substrate. Polarization fatigues of Pt/PZT/LNO capacitors are strongly affected by the thermal strain caused by difference of thermal expansion coefficient between PZT and substrate materials. High fatigue resistance of Pt/PZT/LNO can be obtained by using substrate with similar thermal expansion coefficient as PZT. (orig.)

  14. Gender relations, prostate cancer and diet: re-inscribing hetero-normative food practices.

    Science.gov (United States)

    Mróz, Lawrence William; Chapman, Gwen E; Oliffe, John L; Bottorff, Joan L

    2011-05-01

    Although diet might be a valuable adjunct to prostate cancer care, men typically have poorer diets than women and are less likely to change the way they eat after a cancer diagnosis. Gender theory suggests that dominant ideals of masculinity shape men's health and food practices; however, the role of female partners in men's diets is poorly understood. Through qualitative analysis of in-depth interviews, this article explores accounts of 14 Canadian couples' food practices guided by a gender relations framework to expose how tacit performances of masculinity and femininity interact to shape the diets of men with prostate cancer. Findings show that many men became more interested and involved in their diets after a prostate cancer diagnosis, practices that might be theorized as a counter hegemonic project or 'feminization', adding to other prostate cancer induced emasculations (i.e., treatment induced incontinence and impotence). At the same time, however, couples mutually limited men's engagement with diet while concurrently reinforcing women's traditional femininities in nurturing the men in their lives through food provision. Also embedded here were women's attempts to mitigate subordinate productions of masculinity by catering to their partner's tastes as well as monitoring their diets. Most couples mutually maintained traditional gender food 'roles' by positioning women as proficient leaders in domestic food provision and men as unskilled 'try-hard' and sometimes uninterested assistants. Findings also revealed complex gender power dynamics that predominated as complicit in sustaining hegemonic masculinity through women's deference to men's preferences and careful negotiation of instrumental support for men's diet changes. Overall men and women jointly worked to re-inscribe hetero-normative family food practices that shaped men's diets and nutritional health. Crown Copyright © 2011. Published by Elsevier Ltd. All rights reserved.

  15. Nieuwsgierig naar de wereld : opleiden en opvoeden in verbondenheid

    NARCIS (Netherlands)

    Hanno van Keulen

    2014-01-01

    Curious about the world. Education in harmony with the surrounding context’. On December 11, 2014, dr. Hanno van Keulen was installed as professor on the chair for Educational Leadership at Windesheim Flevoland University of Applied Science in Almere, the Netherlands. In his lecture, Hanno van

  16. Il Raffrescamento per Ventilazione

    DEFF Research Database (Denmark)

    Perino, Marco; Heiselberg, Per Kvols

    2016-01-01

    termicamente e sempre più a tenuta d'aria. Tali misure hanno consentito indubbiamente di ridurre la domanda energetica per il riscaldamento invernale, ma hanno determinato delle crescenti problematiche di surriscaldamento dell'ambiente interno. Molti degli edifici ad alta efficienza energeti-ca di nuova...

  17. Development of p-type amorphous Cu{sub 1−x}B{sub x}O{sub 2−δ} thin films and fabrication of pn hetero junction

    Energy Technology Data Exchange (ETDEWEB)

    Sanal, K.C., E-mail: sanalcusat@gmail.com [Nanophotonic and Optoelectronic Devices Laboratory, Department of Physics, Cochin University of Science and Technology, Kerala 682022 (India); Inter University Center for Nanomaterials and Devices (IUCND), Cochin University of Science and Technology, Kerala 682022 (India); Center for Advanced Materials, Cochin University of Science and Technology, Kerala 682022 (India); Jayaraj, M.K., E-mail: mkj@cusat.ac.in [Nanophotonic and Optoelectronic Devices Laboratory, Department of Physics, Cochin University of Science and Technology, Kerala 682022 (India); Center for Advanced Materials, Cochin University of Science and Technology, Kerala 682022 (India)

    2014-07-01

    Highlights: • Growth of p-type semiconducting amorphous Cu{sub 1−x}B{sub x}O{sub 2−δ} thin films by co-sputtering. • Atomic percentage of Cu{sub 1−x}B{sub x}O{sub 2−δ} thin films from the XPS analysis. • Variation of bandgap with boron concentration in Cu{sub 1−x}B{sub x}O{sub 2−δ} thin films. • Demonstration of p–n hetero junctions fabricated in the structure n-Si/p-Cu{sub 1−x}B{sub x}O{sub 2−δ}/Au. - Abstract: Transparent conducting amorphous p type Cu{sub 1−x}B{sub x}O{sub 2−δ} thin films were grown by RF magnetron co-sputtering at room temperature, using copper and boron targets in oxygen atmosphere. The structural, electrical as well as optical properties were studied. Composition of the films was analyzed by XPS. Amorphous structure of as deposited films was confirmed by GXRD. Surface morphology of the films was analyzed by AFM studies. p-Type nature and concentration of carriers were investigated by Hall effect measurement. Band gap of the films was found to increase with the atomic content of boron in the film. A p–n hetero junction using p-type Cu{sub 1−x}B{sub x}O{sub 2−δ} and n-type silicon was fabricated in the structure n-Si/p-Cu{sub 1−x}B{sub x}O{sub 2−δ}/Au which showed rectifying behavior. As deposited amorphous Cu{sub 1−x}B{sub x}O{sub 2−δ} thin films with lower carrier concentration can be used as a channel layer for thin film transistors.

  18. Heterosídeos alcaloídicos de Solanum lycocarpum A. St.-Hil.: avaliação das atividades contra fungos dermatófitos e câncer de pele

    OpenAIRE

    Juliana de Carvalho da Costa

    2012-01-01

    de pele é o tipo mais frequente, correspondendo a cerca de 25% de todos os tumores malignos registrados no Brasil. Há que se destacar que uma formulação de uso tópico foi desenvolvida pelo grupo para uso contra câncer de pele e o estudo da estabilidade acelerada desta formulação foi avaliado nesse trabalho. Os frutos da espécie S. lycocarpum foram coletados, secos, triturados, submetidos à extração ácido-base e o precipitado foi suspenso em etanol e filtrado. Os heterosídeos alcaloídicos, SS ...

  19. The [2 + 2] Cycloaddition-Retroelectrocyclization and [4 + 2] Hetero-Diels-Alder Reactions of 2-(Dicyanomethylene)indan-1,3-dione with Electron-Rich Alkynes: Influence of Lewis Acids on Reactivity.

    Science.gov (United States)

    Donckele, Etienne J; Finke, Aaron D; Ruhlmann, Laurent; Boudon, Corinne; Trapp, Nils; Diederich, François

    2015-07-17

    The reaction of electrophilic 2-(dicyanomethylene)indan-1,3-dione (DCID) with substituted, electron-rich alkynes provides two classes of push-pull chromophores with interesting optoelectronic properties. The formal [2 + 2] cycloaddition-retroelectrocyclization reaction at the exocyclic double bond of DCID gives cyanobuta-1,3-dienes, and the formal [4 + 2] hetero-Diels-Alder (HDA) reaction at an enone moiety of DCID generates fused 4H-pyran heterocycles. Both products can be obtained in good yield and excellent selectivity by carefully tuning the reaction conditions; in particular, the use of Lewis acids dramatically enhances formation of the HDA adduct.

  20. Coming to power: women's fake orgasms and best orgasm experiences illuminate the failures of (hetero)sex and the pleasures of connection.

    Science.gov (United States)

    Fahs, Breanne

    2014-01-01

    While some literature has explored women's sexual satisfaction and, to a lesser degree, women's faking orgasm experiences, little research has examined the context and conditions around women's best and most memorable orgasms. This paper utilised thematic analysis of qualitative data from a community sample of 20 women in the USA (mean age = 34 years, SD = 13.35 years) from a wide range of racial, socioeconomic, and sexual identity backgrounds to illuminate their experiences with fake or pretend orgasms, and with their best orgasms. While faking orgasm narratives reflected themes of wanting to reinforce a partner's sexual skills, strategically ending sexual interactions, and suppressing feelings of abnormality and shame, best orgasm experiences showcased the power of interpersonal connection, the joys of masturbation and other non-penile-vaginal intercourse behaviours, and the significance of 'transformative embodiment'. Implications for the relative failures of (hetero)sex, particularly in the context of gendered power imbalances, along with the importance of deconstructing the sexually 'functional' or 'dysfunctional' woman are explored.

  1. A theoretical investigation on the regioselectivity of the intramolecular hetero Diels-Alder and 1,3-dipolar cycloaddition of 2-vinyloxybenzaldehyde derivatives

    Directory of Open Access Journals (Sweden)

    Hamzehloueian Mahshid

    2014-01-01

    Full Text Available The present study reports a systematic computational analysis of the two possible pathways, fused and bridged, for an intramolecular hetero Diels-Alder (IMHDA and an intramolecular 1,3-dipolar cycloaddition (IMDCA of 2-vinyloxybenzaldehyde derivatives. The potential energy surface analysis for both reactions is in agreement with experimental observations. The activation energies associated with the two regioisomeric channels in IMHDA reaction show that the bridged product is favored, although in IMDCA, the most stable TS results the fused product. The global electronic properties of fragments within each molecule were studied to discuss the reactivity patterns and charge transfer direction in the intramolecular processes. The asynchronicity of the bond formation and aromaticity of the optimized TSs in the Diels-Alder reaction as well as cycloaddition reaction were evaluated. Finally, 1H NMR chemical shifts of the possible regioisomers have been calculated using the GIAO method which of the most stable products are in agreement with the experimental data in the both reaction.

  2. Hetero-gate-dielectric double gate junctionless transistor (HGJLT) with reduced band-to-band tunnelling effects in subthreshold regime

    International Nuclear Information System (INIS)

    Ghosh, Bahniman; Mondal, Partha; Akram, M. W.; Bal, Punyasloka; Salimath, Akshay Kumar

    2014-01-01

    We propose a hetero-gate-dielectric double gate junctionless transistor (HGJLT), taking high-k gate insulator at source side and low-k gate insulator at drain side, which reduces the effects of band-to-band tunnelling (BTBT) in the sub-threshold region. A junctionless transistor (JLT) is turned off by the depletion of carriers in the highly doped thin channel (device layer) which results in a significant band overlap between the valence band of the channel region and the conduction band of the drain region, due to off-state drain bias, that triggers electrons to tunnel from the valence band of the channel region to the conduction band of the drain region leaving behind holes in the channel. These effects of band-to-band tunnelling increase the sub-threshold leakage current, and the accumulation of holes in the channel forms a parasitic bipolar junction transistor (n–p–n BJT for channel JLT) in the lateral direction by the source (emitter), channel (base) and drain (collector) regions in JLT structure in off-state. The proposed HGJLT reduces the subthreshold leakage current and suppresses the parasitic BJT action in off-state by reducing the band-to-band tunnelling probability. (semiconductor devices)

  3. Synthesis and in vitro anti-proliferative effects of 3-(hetero)aryl substituted 3-[(prop-2-ynyloxy)(thiophen-2-yl)methyl]pyridine derivatives on various cancer cell lines.

    Science.gov (United States)

    Reddy Chamakura, Upendar; Sailaja, E; Dulla, Balakrishna; Kalle, Arunasree M; Bhavani, S; Rambabu, D; Kapavarapu, Ravikumar; Rao, M V Basaveswara; Pal, Manojit

    2014-03-01

    A series of 3-(hetero)aryl substituted 3-[(prop-2-ynyloxy)(thiophen-2-yl)methyl]pyridine derivatives were designed as potential anticancer agents. These compounds were conveniently prepared by using Pd/C-Cu mediated Sonogashira type coupling as a key step. Many of these compounds were found to be promising when tested for their in vitro anti-proliferative properties against six cancer cell lines. All these compounds were found to be selective towards the growth inhibition of cancer cells with IC50 values in the range of 0.9-1.7 μM (against MDA-MB 231 and MCF7 cells), comparable to the known anticancer drug doxorubicin. Copyright © 2014 Elsevier Ltd. All rights reserved.

  4. What place has an emigration past in an immigration present? Italy ...

    African Journals Online (AJOL)

    Ironicamente, questa distinzione è diventata percettibile nei dibattiti contemporanei sull'immigrazione. In Irlanda, nei primi dibattiti che hanno avuto luogo tra la metà e la fine degli anni '90, gli attori pro-immigrazione hanno evocato in maniera costante la memoria della passata emigrazione irlandese, per indurre nei nativi ...

  5. Structural variability in uranyl-lanthanide hetero-metallic complexes with DOTA and oxalato ligands

    International Nuclear Information System (INIS)

    Thuery, P.

    2009-01-01

    Four novel 4f-5f hetero-metallic complexes could be obtained from the reaction of uranyl and lanthanide nitrates with DOTA (H 4 L) under hydrothermal conditions. In all cases, as in the previous examples reported, additional oxalato ligands are formed in situ. Variations in the stoichiometry of the final products and the presence of hydroxo ions in some cases appear to result in a large structural variability. In the two isomorphous complexes [(UO 2 ) 2 Ln 2 (L) 2 (C 2 O 4 )] with Ln = Sm(1) or Eu(2), the lanthanide ion is located in the N 4 O 4 site and is also bound to a carboxylate oxygen atom from a neighbouring unit, to give zigzag chains which are further linked to one another by [(UO 2 ) 2 (C 2 O 4 )] 2+ di-cations, resulting in the formation of a 3D framework. In [(UO 2 ) 4 Gd 2 (L) 2 (C 2 O 4 ) 3 (H 2 O) 6 ].2H 2 O (3), 2D bilayer subunits of the 'double floor' type with uranyl oxalate pillars are assembled into a 3D framework by other, disordered uranyl ions. [(UO 2 ) 2 Gd(L)(C 2 O 4 )(OH)].H 2 O (4) is a 2D assembly in which cationic {[(UO 2 ) 2 (C 2 O 4 )(OH)] + } n chains are linked to one another by the [Gd(L)] - groups. The most notable feature of this compound is the environment of the 4f ion, which is eight-coordinate and twisted square anti-prismatic (TSA'), instead of nine-coordinate mono-capped square anti-prismatic (SA), as generally observed in DOTA complexes of gadolinium(III) and similarly-sized ions. (author)

  6. Growth and characterization of para-hexaphenyl based organic hetero-structures

    International Nuclear Information System (INIS)

    Schwabegger, G.

    2013-01-01

    hetero-structures is studied and optimized by scanning force microscopy and X-ray diffraction. Optical properties are examined by means of photo and electro-luminescence measurements as well as by time resolved spectroscopy. It could be assured, that the preparation of multilayer systems allows the manipulation of optical properties of nano-needles without altering their highly anisotropic structure. Importantly, it could be shown that this approach allows to shift the emission wavelengths of organic nano-fiber lasers from the blue to the green and orange spectral regime of the visible light. (author) [de

  7. Hetero-junctions of Boron Nitride and Carbon Nanotubes: Synthesis and Characterization

    Energy Technology Data Exchange (ETDEWEB)

    Yap, Yoke Khin

    2013-03-14

    Hetero-junctions of boron nitride nanotubes (BNNTs) and carbon nanotubes (CNTs) are expected to have appealing new properties that are not available from pure BNNTs and CNTs. Theoretical studies indicate that BNNT/CNT junctions could be multifunctional and applicable as memory, spintronic, electronic, and photonics devices with tunable band structures. This will lead to energy and material efficient multifunctional devices that will be beneficial to the society. However, experimental realization of BNNT/CNT junctions was hindered by the absent of a common growth technique for BNNTs and CNTs. In fact, the synthesis of BNNTs was very challenging and may involve high temperatures (up to 3000 degree Celsius by laser ablation) and explosive chemicals. During the award period, we have successfully developed a simple chemical vapor deposition (CVD) technique to grow BNNTs at 1100-1200 degree Celsius without using dangerous chemicals. A series of common catalyst have then been identified for the synthesis of BNNTs and CNTs. Both of these breakthroughs have led to our preliminary success in growing two types of BNNT/CNT junctions and two additional new nanostructures: 1) branching BNNT/CNT junctions and 2) co-axial BNNT/CNT junctions, 3) quantum dots functionalized BNNTs (QDs-BNNTs), 4) BNNT/graphene junctions. We have started to understand their structural, compositional, and electronic properties. Latest results indicate that the branching BNNT/CNT junctions and QDs-BNNTs are functional as room-temperature tunneling devices. We have submitted the application of a renewal grant to continue the study of these new energy efficient materials. Finally, this project has also strengthened our collaborations with multiple Department of Energy's Nanoscale Science Research Centers (NSRCs), including the Center for Nanophase Materials Sciences (CNMS) at Oak Ridge National Laboratory, and the Center for Integrated Nanotechnologies (CINTs) at Sandia National Laboratories and Los

  8. Creato un nuovo stato della materia

    CERN Document Server

    Valsecchi, M C

    2004-01-01

    "Nei laboratori di tutto il mondo nascono continuamente nuovi materiali plastici, leghe di metallo, molecole progettate e assemblate atomo per atomo. I ricercatori dell'Istituto nazionale di fisica nucleare hanno fatto un passo in piu': manipolando i costituenti fondamentali dei nuclei atomici, hanno creato una nuova forma di materia, radicalmente diversa da quella che noi conosciamo" (1 page)

  9. Sn-PILC: A novel Efficient and Recyclable Catalyst for One-pot Three Component Povarov’s Inverse-electron-demand Hetero Diels-Alder Reaction for a Facile Synthesis of Tetrahydropyranoquinoline Derivatives under Neat Conditions

    Directory of Open Access Journals (Sweden)

    Megha Rai

    2016-07-01

    Full Text Available The Povarov’s inverse-electron-demand hetero Diels–Alder one-pot three components reaction of aromatic aldehyde, aromatic amine with DHF has been developed using Sn-PILC as a catalyst under a neat condition which may helpful to society to get pharmacologically more active compounds. In the present study a novel series of tetrahydroquinoline 4(a-f were synthesized and characterized by IR, 1HNMR, 13CNMR, Mass spectral analysis and elemental analysis. The synthetic details and characterization results are discussed. DOI: http://dx.doi.org/10.17807/orbital.v8i3.801

  10. Effect of dopants and thermal treatment on properties of Ga-Al-ZnO thin films fabricated by hetero targets sputtering system

    International Nuclear Information System (INIS)

    Hong, JeongSoo; Matsushita, Nobuhiro; Kim, KyungHwan

    2013-01-01

    In this study, we fabricated Ga and Al doped ZnO (Ga-Al-ZnO; GAZO) thin films by using the facing targets sputtering system under various conditions such as input current and thermal treatment temperature. The properties of the as-deposited GAZO thin films were examined by four-point, UV/Vis spectrometry, X-ray diffraction, atomic force microscopy and field-emission scanning electron microscopy. The result showed that the lowest sheet resistance of the films was 59.3 ohm/sq and transmittance was about 85%. After thermal treatment, the properties of GAZO thin films were improved. The lowest sheet resistance (47.3 ohm/sq) of the GAZO thin films were obtained at thermal treatment temperature of 300 °C, considered to be the result of continuous substitutions by dopants and improved crystallinity by the thermal treatment. - Highlights: ► Ga and Al doped ZnO thin films were prepared by hetero targets sputtering system. ► Free electrons were increased due to the continuous substitutions of Ga and Al. ► Crystallinity was improved by recombination of particles with increasing of temperature

  11. APTES Functionalized Iron Oxide-Silver Magnetic Hetero-Nanocomposites for Selective Capture and Rapid Removal of Salmonella enteritidis from Aqueous Solution

    Science.gov (United States)

    Trang, Vu Thi; Dinh, Ngo Xuan; Lan, Hoang; Tam, Le Thi; Huy, Tran Quang; Tuan, Pham Anh; Phan, Vu Ngoc; Le, Anh-Tuan

    2018-02-01

    Magnetic nanomaterials, as a promising platform for the fast and sensitive detection of bacterial pathogens, have attracted increasing interest from researchers in recent years. In this work, by utilizing a two-step synthetic technique consisting of co-precipitation and subsequent hydrothermal reaction, followed by functionalization steps with (3-aminopropyl)triethoxysilane (APTES) and the antibody against Salmonella enteritidis, antibody-conjugated Fe3O4-Ag@APTES hetero-nanocomposites were successfully prepared. Due to the specific antibody, the developed Fe3O4-Ag@APTES@SE-Ab conjugates are capable of selectively capturing S. enteritidis at a low concentration of about 101 CFU/mL. Moreover, the prepared magnetic conjugates also revealed that the S. enteritidis could be rapidly removed from water solution in 20 min by using an external magnetic field with a removal efficiency obtained of ˜ 91.36%. These results indicated that the Fe3O4-Ag@APTES@SE-Ab conjugates are promising for the rapid selective capture and removal of bacterial pathogens from aqueous environments, and can be used for improving the detection quality of pathogens in water samples using immunosensor-based diagnostic tests.

  12. “Il Risorgimento in scena. Le donne in mostra”

    Directory of Open Access Journals (Sweden)

    Francesco Muollo

    2013-01-01

    Full Text Available Questo paper nasce in seguito alla raccolta dei lavori del convegno “IL RISORGIMENTO IN SCENA. LE DONNE IN MOSTRA”. Ciascuna delle tre giornate che hannoarticolato il convegno, sono dedicate al protagonismo femminile nel Risorgimento, rappresentate dal cinema, dalla danza e dall’ arte. Le arti figurative e sceniche hanno saputo, forse meglio dei libri, preservare la memoria delle donne che hanno fatto l’Italia.

  13. Single site mutations in the hetero-oligomeric Mrp antiporter from alkaliphilic Bacillus pseudofirmus OF4 that affect Na+/H+ antiport activity, sodium exclusion, individual Mrp protein levels, or Mrp complex formation.

    Science.gov (United States)

    Morino, Masato; Natsui, Shinsuke; Ono, Tomohiro; Swartz, Talia H; Krulwich, Terry A; Ito, Masahiro

    2010-10-01

    Mrp systems are widely distributed and structurally complex cation/proton antiporters. Antiport activity requires hetero-oligomeric complexes of all six or seven hydrophobic Mrp proteins (MrpA-MrpG). Here, a panel of site-directed mutants in conserved or proposed motif residues was made in the Mrp Na(+)(Li(+))/H(+) antiporter from an alkaliphilic Bacillus. The mutant operons were expressed in antiporter-deficient Escherichia coli KNabc and assessed for antiport properties, support of sodium resistance, membrane levels of each Mrp protein, and presence of monomeric and dimeric Mrp complexes. Antiport did not depend on a VFF motif or a conserved tyrosine pair, but a role for a conserved histidine in a potential quinone binding site of MrpA was supported. The importance of several acidic residues for antiport was confirmed, and the importance of additional residues was demonstrated (e.g. three lysine residues conserved across MrpA, MrpD, and membrane-bound respiratory Complex I subunits (NuoL/M/N)). The results extended indications that MrpE is required for normal membrane levels of other Mrp proteins and for complex formation. Moreover, mutations in several other Mrp proteins lead to greatly reduced membrane levels of MrpE. Thus, changes in either of the two Mrp modules, MrpA-MrpD and MrpE-MrpG, influence the other. Two mutants, MrpB-P37G and MrpC-Q70A, showed a normal phenotype but lacked the MrpA-MrpG monomeric complex while retaining the dimeric hetero-oligomeric complex. Finally, MrpG-P81A and MrpG-P81G mutants exhibited no antiport activity but supported sodium resistance and a low [Na(+)](in). Such mutants could be used to screen hypothesized but uncharacterized sodium efflux functions of Mrp apart from Na(+) (Li(+))/H(+) antiport.

  14. Ag(I)-mediated homo and hetero pairs of guanosine and cytidine: monitoring by circular dichroism spectroscopy.

    Science.gov (United States)

    Goncharova, Iryna

    2014-01-24

    Ag(I)-containing compounds are attractive as antibacterial and antifungal agents. The renewed interest in the application of silver(I) compounds has led to the need for detailed knowledge of the mechanism of their action. One of the possible ways is the coordination of Ag(I) to G-C pairs of DNA, where Ag(+) ions form Ag(I)-mediated base pairs and inhibit the transcription. Herein, a systematic chiroptical study on silver(I)-mediated homo and mixed pairs of the C-G complementary-base derivatives cytidine(C) and 5'-guanosine monophosphate(G) in water is presented. Ag(I)-mediated homo and hetero pairs of G and C and their self-assembled species were studied under two pH levels (7.0 and 10.0) by vibrational (VCD) and electronic circular dichroism(ECD). VCD was used for the first time in this field and showed itself to be a powerful method for obtaining specific structural information in solution. Based on results of the VCD experiments, the different geometries of the homo pairs were proposed under pH 7.0 and 10.0. ECD was used as a diagnostic tool to characterize the studied systems and as a contact point between the previously defined structures of the metal or proton mediated pairs of nucleobases and the systems studied here. On the basis of the obtained data, the formation of the self-assembled species of cytidine with a structure similar to the i-motif structure in DNA was proposed at pH 10.0. Copyright © 2013 Elsevier B.V. All rights reserved.

  15. Synthesis of cyclopentadienyl capped polyethylene and subsequent block copolymer formation via hetero Diels-Alder (HDA) chemistry.

    Science.gov (United States)

    Espinosa, Edgar; Glassner, Mathias; Boisson, Christophe; Barner-Kowollik, Christopher; D'Agosto, Franck

    2011-09-15

    In the current contribution it is demonstrated - for the first time - that poly(ethylene) (M(n) = 1,400 as well as 2,800 g  ·  mol(-1) , PDI = 1.2) can be readily equipped with highly reactive cyclopentadienyl (Cp) end groups. The Cp terminal poly(ethylene) can subsequently be reacted in an efficient hetero Diels-Alder (HDA) reaction with macromolecules (poly(isobornyl acrylate) (M(n) = 4,600 g  ·  mol(-1) , PDI = 1.10) and poly(styrene) (M(n) = 6,300 g  ·  mol(-1) , PDI = 1.13) featuring strongly electron withdrawing thiocarbonyl thio end groups, prepared via reversible addition fragmentation chain transfer (RAFT) polymerization employing benzylpyridin-2-yldithioformate (BPDF) as transfer agent. The resulting block copolymers have been analyzed via high-temperature size exclusion chromatography (SEC) as well as nuclear magnetic resonance (NMR) spectroscopy. The current system allows for the removal of the excess of the non-poly(ethylene) containing segment via filtration of the poly(ethylene)-containing block copolymer. However, the reaction temperatures need to be judiciously selected. Characterization of the generated block copolymers at elevated temperatures can lead - depending on the block copolymer type - to the occurrence of retro Diels-Alder processes. The present study thus demonstrates that RAFT-HDA ligation can be effectively employed for the generation of block copolymers containing poly(ethylene) segments. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. Spatial arrangement and functional role of α subunits of proteasome activator PA28 in hetero-oligomeric form

    Energy Technology Data Exchange (ETDEWEB)

    Sugiyama, Masaaki, E-mail: sugiyama@rri.kyoto-u.ac.jp [Research Reactor Institute, Kyoto University, Osaka 590-0494 (Japan); Sahashi, Hiroki [Graduate School of Pharmaceutical Sciences, Nagoya City University, Nagoya 467-8603 (Japan); Kurimoto, Eiji [Graduate School of Pharmaceutical Sciences, Nagoya City University, Nagoya 467-8603 (Japan); Faculty of Pharmacy, Meijo University, Nagoya 468-8503 (Japan); Takata, Shin-ichi [J-PARC Center, Japan Atomic Energy Agency, Ibaraki 319-1195 (Japan); Yagi, Hirokazu; Kanai, Keita; Sakata, Eri [Graduate School of Pharmaceutical Sciences, Nagoya City University, Nagoya 467-8603 (Japan); Minami, Yasufumi [Department of Biotechnology, Maebashi Institute of Technology, Gunma 371-0816 (Japan); Tanaka, Keiji [Tokyo Metropolitan Institute of Medical Science, Tokyo 156-8506 (Japan); Kato, Koichi, E-mail: kkatonmr@ims.ac.jp [Graduate School of Pharmaceutical Sciences, Nagoya City University, Nagoya 467-8603 (Japan); Okazaki Institute for Integrative Bioscience, National Institutes of Natural Sciences, Okazaki, Aichi 444-8787 (Japan); Institute for Molecular Science, National Institutes of Natural Sciences, Okazaki, Aichi 444-8787 (Japan)

    2013-03-01

    Highlights: ► Homologous α and β subunits are alternatively arranged in the PA28 heptameric ring. ► The flexible loops of the three α subunits surround the site of substrate entry. ► The loops serve as gatekeepers that selectively hinder passage of longer peptides. - Abstract: A major form of proteasome activator PA28 is a heteroheptamer composed of interferon-γ-inducible α and β subunits, which share approximately 50% amino acid identity and possess distinct insert loops. This activator forms a complex with the 20S proteasome and thereby stimulates proteasomal degradation of peptides in an ATP-independent manner, giving rise to smaller antigenic peptides presented by major histocompatibility complex class I molecules. In this study, we performed biophysical and biochemical characterization of the structure and function of the PA28 hetero-oligomer. Deuteration-assisted small-angle neutron scattering demonstrated three α and four β subunits are alternately arranged in the heptameric ring. In this arrangement, PA28 loops surround the central pore of the heptameric ring (site for peptide entry). Activating the 20S proteasome with a PA28 mutant that lacked the α subunit loops cleaved model substrates longer than a nonapeptide with better efficiency when compared to wild-type PA28. Based on these data, we hypothesize that the flexible PA28 loops act as gatekeepers, which function to select the length of peptide substrates to be transported between the proteolytic chamber and the extra-proteasomal medium.

  17. Effect of doping and chemical ordering on the optoelectronic properties of complex oxides: Fe 2 O 3 –V 2 O 3 solid solutions and hetero-structures

    Energy Technology Data Exchange (ETDEWEB)

    Nayyar, Iffat H.; Chamberlin, Sara E.; Kaspar, Tiffany C.; Govind, Niranjan; Chambers, Scott A.; Sushko, Petr

    2017-01-01

    The electronic and optical properties of a-(Fe1xVx)2O3 at low (x = 0.04) and high (x = 0.5) doping levels are investigated using a combination of periodic and embedded cluster approaches, and time dependent density functional theory. At low V concentrations the onset of the optical absorption is B0.5 eV (i.e., nearly 1.6 eV lower than that in pure a-Fe2O3) and corresponds to the electron transitions from V 3d to Fe 3d* orbitals. At high V concentrations, optical absorption energies and intensities are sensitive to specific arrangements of Fe and V atoms and their spin configuration that determine Fe–V hybridization. The onset of the lowest inter-vanadium absorption band in the case of Fe2O3/V2O3 hetero-structures is as low as B0.3 eV and the corresponding peak is at B0.7 eV. In contrast, in the case of solid solutions this peak has lower intensity and is shifted to higher energy (B1.2 eV). Analysis of the orbital character of electronic excitation suggests that Fe2O3/V2O3 hetero-structures absorb light much more effectively than random alloys, thus promoting efficient photo-induced carrier generation. These predictions can be tested in a-(Fe1xVx)2O3 thin films synthesized with well-controlled spatial distribution of Fe and V species.

  18. Self-Assembly of Chip-Size Components with Cavity Structures: High-Precision Alignment and Direct Bonding without Thermal Compression for Hetero Integration

    Directory of Open Access Journals (Sweden)

    Mitsumasa Koyanagi

    2011-02-01

    Full Text Available New surface mounting and packaging technologies, using self-assembly with chips having cavity structures, were investigated for three-dimensional (3D and hetero integration of complementary metal-oxide semiconductors (CMOS and microelectromechanical systems (MEMS. By the surface tension of small droplets of 0.5 wt% hydrogen fluoride (HF aqueous solution, the cavity chips, with a side length of 3 mm, were precisely aligned to hydrophilic bonding regions on the surface of plateaus formed on Si substrates. The plateaus have micro-channels to readily evaporate and fully remove the liquid from the cavities. The average alignment accuracy of the chips with a 1 mm square cavity was found to be 0.4 mm. The alignment accuracy depends, not only on the area of the bonding regions on the substrates and the length of chip periphery without the widths of channels in the plateaus, but also the area wetted by the liquid on the bonding regions. The precisely aligned chips were then directly bonded to the substrates at room temperature without thermal compression, resulting in a high shear bonding strength of more than 10 MPa.

  19. Manganite based hetero-junction structure of La_0_._7Sr_0_._7_−_xCa_xMnO_3 and CaMnO_3_−_δ for cross-point arrays

    International Nuclear Information System (INIS)

    Lee, Hong-Sub; Park, Hyung-Ho

    2015-01-01

    Resistive random access memory and the corresponding cross-point array (CPA) structure have received a great deal of attention for high-density next generation non-volatile memory. However, the cross-talk issue of CPA structure by sneak current should be overcome to realize the highest density integration. To accomplish this, the sneak current can be minimized by high, nonlinear characteristic behaviors of resistive switching (RS). Therefore this study fabricated pnp bipolar hetero-junction structure using the perovskite manganite family, such as La_0_._7Sr_0_._3_−_xCa_xMnO_3 (LSCMO) and CaMnO_3_−_δ (CMO), to obtain nonlinear RS behavior. The pnp structure not only shows nonlinear characteristics, but also a tunable characteristic with Ca substitution. (paper)

  20. A Phytophthora sojae effector PsCRN63 forms homo-/hetero-dimers to suppress plant immunity via an inverted association manner.

    Science.gov (United States)

    Li, Qi; Zhang, Meixiang; Shen, Danyu; Liu, Tingli; Chen, Yanyu; Zhou, Jian-Min; Dou, Daolong

    2016-05-31

    Oomycete pathogens produce a large number of effectors to promote infection. Their mode of action are largely unknown. Here we show that a Phytophthora sojae effector, PsCRN63, suppresses flg22-induced expression of FRK1 gene, a molecular marker in pathogen-associated molecular patterns (PAMP)-triggered immunity (PTI). However, PsCRN63 does not suppress upstream signaling events including flg22-induced MAPK activation and BIK1 phosphorylation, indicating that it acts downstream of MAPK cascades. The PsCRN63-transgenic Arabidopsis plants showed increased susceptibility to bacterial pathogen Pseudomonas syringae pathovar tomato (Pst) DC3000 and oomycete pathogen Phytophthora capsici. The callose deposition were suppressed in PsCRN63-transgenic plants compared with the wild-type control plants. Genes involved in PTI were also down-regulated in PsCRN63-transgenic plants. Interestingly, we found that PsCRN63 forms an dimer that is mediated by inter-molecular interactions between N-terminal and C-terminal domains in an inverted association manner. Furthermore, the N-terminal and C-terminal domains required for the dimerization are widely conserved among CRN effectors, suggesting that homo-/hetero-dimerization of Phytophthora CRN effectors is required to exert biological functions. Indeed, the dimerization was required for PTI suppression and cell death-induction activities of PsCRN63.

  1. Afterword: A view from African cities

    Directory of Open Access Journals (Sweden)

    Pino Schirripa

    2016-08-01

    Full Text Available La diffusione del pentecostalismo e la crescita degli aderenti ha assunto negli ultimi decenni dimensioni considerevoli che ne hanno fatto il movimento cristiano a più altro tasso di crescita a livello mondiale. Sebbene conosca una sua diffusione anche nelle aree rurali, è in quelle urbani che conosce uno sviluppo maggiore. Tra i fattori che ne hanno favorito la diffusione vi è certamente la flessibilità dell'idioma pentecostale che permette di adattarsi ai vari contesti locali. Diversi studiosi hanno evidenziato come versioni oggi più in crescita del pentecostalismo presentino nella dottrina, nelle predicazioni e nelle pratiche elementi coerenti con la prospettiva neoliberista oggi egemonica in larga parte del pianeta. Partendo dagli articoli presenti in questa sezione, il contributo intende riflettere su queste questioni, concentrandosi principalmente sul fenomeno per come si presenta nelle aree urbane.

  2. Presentazione

    OpenAIRE

    Ceccatelli Gurrieri, Giovanna

    2017-01-01

    Gli ultimi tre decenni hanno visto introdurre, nel dibattito sulle scienze sociali e sulla sociologia in particolare, alcuni radicali mutamenti di prospettiva, legati come è noto, in estrema sintesi, a tre principali riferimenti: la teoria dei sistemi, la fenomenologia, l’approccio ermeneutico. Si sono così andati imponendo, insieme al riconoscimento della sostanziale precarietà di ogni tentativo di conoscenza della realtà sociale, alcuni paradigmi che hanno trasformato irreversibilmente i fo...

  3. La Banca Centrale Europea : profili giuridici e istituzionali, un confronto con il modello americano della Federal Reserve

    OpenAIRE

    BARONCELLI, Stefania

    2000-01-01

    Il libro analizza il processo di creazione e l'evoluzione istituzionale della Banca Centrale Europea facendo una comparazione con l'esperienza storica del Federal Reserve System americano. Vengono così confrontate le ragioni che hanno portato alla creazione delle due banche centrali, le politiche economiche che ne hanno ispirato l'azione ed i problemi istituzionali legati alla gestione della politica monetaria in un'area politicamente non uniforme quale appunto l'attuale Unione Europea. Pu...

  4. Tunability of Open-Shell Character, Charge Asymmetry, and Third-Order Nonlinear Optical Properties of Covalently Linked (Hetero)Phenalenyl Dimers.

    Science.gov (United States)

    Minamida, Yuka; Kishi, Ryohei; Fukuda, Kotaro; Matsui, Hiroshi; Takamuku, Shota; Yamane, Masaki; Tonami, Takayoshi; Nakano, Masayoshi

    2018-02-06

    Tunability of the open-shell character, charge asymmetry, and third-order nonlinear optical (NLO) properties of covalently linked (hetero)phenalenyl dimers are investigated by using the density functional theory method. By changing the molecular species X and substitution position (i, j) for the linker part, a variety of intermonomer distances R and relative alignments between the phenalenyl dimers can be realized from the geometry optimizations, resulting in a wide-range tuning of diradical character y and charge asymmetry. It is found that the static second hyperpolarizabilities along the stacking direction, γ yyyy , are one-order enhanced for phenalenyl dimer systems exhibiting intermediate y, a feature that is in good agreement with the "y-γ correlation". By replacing the central carbon atoms of the phenalenyl rings with a boron or a nitrogen, we have also designed covalently linked heterophenalenyl dimers. The introduction of such a charge asymmetry to the open-shell systems, which leads to closed-shell ionic ground states, is found to further enhance the γ yyyy values of the systems having longer intermonomer distance R with intermediate ionic character, that is, charge asymmetry. The present results demonstrate a promising potential of covalently linked NLO dimers with intermediate open-shell/ionic characters as a new building block of highly efficient NLO systems. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Thickness measurement of a thin hetero-oxide film with an interfacial oxide layer by X-ray photoelectron spectroscopy

    Science.gov (United States)

    Kim, Kyung Joong; Lee, Seung Mi; Jang, Jong Shik; Moret, Mona

    2012-02-01

    The general equation Tove = L cos θ ln(Rexp/R0 + 1) for the thickness measurement of thin oxide films by X-ray photoelectron spectroscopy (XPS) was applied to a HfO2/SiO2/Si(1 0 0) as a thin hetero-oxide film system with an interfacial oxide layer. The contribution of the thick interfacial SiO2 layer to the thickness of the HfO2 overlayer was counterbalanced by multiplying the ratio between the intensity of Si4+ from a thick SiO2 film and that of Si0 from a Si(1 0 0) substrate to the intensity of Si4+ from the HfO2/SiO2/Si(1 0 0) film. With this approximation, the thickness levels of the HfO2 overlayers showed a small standard deviation of 0.03 nm in a series of HfO2 (2 nm)/SiO2 (2-6 nm)/Si(1 0 0) films. Mutual calibration with XPS and transmission electron microscopy (TEM) was used to verify the thickness of HfO2 overlayers in a series of HfO2 (1-4 nm)/SiO2 (3 nm)/Si(1 0 0) films. From the linear relation between the thickness values derived from XPS and TEM, the effective attenuation length of the photoelectrons and the thickness of the HfO2 overlayer could be determined.

  6. Solution-processed efficient CdTe nanocrystal/CBD-CdS hetero-junction solar cells with ZnO interlayer

    International Nuclear Information System (INIS)

    Tian, Yiyao; Zhang, Yijie; Lin, Yizhao; Gao, Kuo; Zhang, Yunpeng; Liu, Kaiyi; Yang, Qianqian; Zhou, Xiao; Qin, Donghuan; Wu, Hongbin; Xia, Yuxin; Hou, Lintao; Lan, Linfeng; Chen, Junwu; Wang, Dan; Yao, Rihui

    2013-01-01

    CdTe nanocrystal (NC)/CdS p–n hetero-junction solar cells with an ITO/ZnO-In/CdS/CdTe/MoO x /Ag-inverted structure were prepared by using a layer-by-layer solution process. The CdS thin films were prepared by chemical bath deposition on top of ITO/ZnO-In and were found to be very compact and pin-hole free in a large area, which insured high quality CdTe NCs thin-film formation upon it. The device performance was strongly related to the CdCl 2 annealing temperature and annealing time. Devices exhibited power conversion efficiency (PCE) of 3.08 % following 400 °C CdCl 2 annealing for 5 min, which was a good efficiency for solution processed CdTe/CdS NC-inverted solar cells. By carefully designing and optimizing the CdCl 2 -annealing conditions (370 °C CdCl 2 annealing for about 15 min), the PCE of such devices showed a 21 % increase, in comparison to 400 °C CdCl 2 -annealing conditions, and reached a better PCE of 3.73 % while keeping a relatively high V OC of 0.49 V. This PCE value, to the best of our knowledge, is the highest PCE reported for solution processed CdTe–CdS NC solar cells. Moreover, the inverted solar cell device was very stable when kept under ambient conditions, less than 4 % degradation was observed in PCE after 40 days storage

  7. A potential role of substrate as a base for deprotonation pathway in Rh-catalysed C-H amination of heteroArenes: DFT insights

    KAUST Repository

    Ajitha, Manjaly John

    2016-03-29

    The possibility of direct introduction of a new functionality through C–H bond activation is an attractive strategy in covalent synthesis. Here, we investigated the mechanism of Rh-catalysed C-H amination of the hetero-aryl substrate (2-phenylpyridine) using phenyl azide as nitrogen source by density functional theory (DFT). For the deprotocyclometallation and protodecyclometallation processes of the title reaction, we propose a stepwise base-assisted mechanism (pathway I) instead of previously reported concerted mechanism (pathway II). In the new mechanism proposed here, 2-phenylpyridine acts as a base in the initial deprotonation step (C-H bond cleavage) and transports the proton towards the final protonation step. In fact, the N-H bond of the strong conjugate acid (formed during initial C-H bond cleavage) considered in pathway I (via TS4) is more acidic than the C-H bond of the neutral substrate considered in pathway II (via TS5). The higher activation barrier of TS5 mainly originates from the ring strain of the four membered cyclic transition state. The vital role of base, as disclosed here, can potentially have broader mechanistic implications for the development of reaction conditions of transition metal catalysed reactions.

  8. Ultralow threading dislocation density in GaN epilayer on near-strain-free GaN compliant buffer layer and its applications in hetero-epitaxial LEDs.

    Science.gov (United States)

    Shih, Huan-Yu; Shiojiri, Makoto; Chen, Ching-Hsiang; Yu, Sheng-Fu; Ko, Chung-Ting; Yang, Jer-Ren; Lin, Ray-Ming; Chen, Miin-Jang

    2015-09-02

    High threading dislocation (TD) density in GaN-based devices is a long unresolved problem because of the large lattice mismatch between GaN and the substrate, which causes a major obstacle for the further improvement of next-generation high-efficiency solid-state lighting and high-power electronics. Here, we report InGaN/GaN LEDs with ultralow TD density and improved efficiency on a sapphire substrate, on which a near strain-free GaN compliant buffer layer was grown by remote plasma atomic layer deposition. This "compliant" buffer layer is capable of relaxing strain due to the absorption of misfit dislocations in a region within ~10 nm from the interface, leading to a high-quality overlying GaN epilayer with an unusual TD density as low as 2.2 × 10(5) cm(-2). In addition, this GaN compliant buffer layer exhibits excellent uniformity up to a 6" wafer, revealing a promising means to realize large-area GaN hetero-epitaxy for efficient LEDs and high-power transistors.

  9. Optimisation of electronic interface properties of a-Si:H/c-Si hetero-junction solar cells by wet-chemical surface pre-treatment

    Energy Technology Data Exchange (ETDEWEB)

    Angermann, H. [Hahn-Meitner-Institut, Abt. Siliziumphotovoltaik, Kekulestrasse 5, D-12489 Berlin (Germany)], E-mail: angermann@hmi.de; Korte, L.; Rappich, J.; Conrad, E.; Sieber, I.; Schmidt, M. [Hahn-Meitner-Institut, Abt. Siliziumphotovoltaik, Kekulestrasse 5, D-12489 Berlin (Germany); Huebener, K.; Hauschild, J. [Freie Universitaet Berlin, FB Physik, Arnimallee 14, 14195 Berlin (Germany)

    2008-08-30

    The relation between structural imperfections at structured silicon surfaces, energetic distribution of interface state densities, recombination loss at a-Si:H/c-Si interfaces and solar cell characteristics have been intensively investigated using non-destructive, surface sensitive techniques, surface photovoltage (SPV) and photoluminescence (PL) measurements, atomic force microscopy (AFM) and electron microscopy (SEM). Sequences of wet-chemical oxidation and etching steps were optimised with respect to the etching behaviour of Si(111) pyramids. Special wet-chemical smoothing and oxide removal procedures for structured substrates were developed, in order to reduce the preparation-induced surface micro-roughness and density of electronically active defects. H-termination and passivation by wet-chemical oxides were used to inhibit surface contamination and native oxidation during the technological process. We achieved significantly lower micro-roughness, densities of surface states D{sub it}(E) and recombination loss at a-Si:H/c-Si interfaces on wafers with randomly distributed pyramids, compared to conventional pre-treatments. For amorphous-crystalline hetero-junction solar cells (ZnO/a-Si:H/c-Si/BSF/Al), the c-Si surface becomes part of the a-Si:H/c-Si interface, whose recombination activity determines cell performance. With textured substrates, the smoothening procedure results in a significant increase of short circuit current, fill factor and efficiency.

  10. Optimisation of electronic interface properties of a-Si:H/c-Si hetero-junction solar cells by wet-chemical surface pre-treatment

    International Nuclear Information System (INIS)

    Angermann, H.; Korte, L.; Rappich, J.; Conrad, E.; Sieber, I.; Schmidt, M.; Huebener, K.; Hauschild, J.

    2008-01-01

    The relation between structural imperfections at structured silicon surfaces, energetic distribution of interface state densities, recombination loss at a-Si:H/c-Si interfaces and solar cell characteristics have been intensively investigated using non-destructive, surface sensitive techniques, surface photovoltage (SPV) and photoluminescence (PL) measurements, atomic force microscopy (AFM) and electron microscopy (SEM). Sequences of wet-chemical oxidation and etching steps were optimised with respect to the etching behaviour of Si(111) pyramids. Special wet-chemical smoothing and oxide removal procedures for structured substrates were developed, in order to reduce the preparation-induced surface micro-roughness and density of electronically active defects. H-termination and passivation by wet-chemical oxides were used to inhibit surface contamination and native oxidation during the technological process. We achieved significantly lower micro-roughness, densities of surface states D it (E) and recombination loss at a-Si:H/c-Si interfaces on wafers with randomly distributed pyramids, compared to conventional pre-treatments. For amorphous-crystalline hetero-junction solar cells (ZnO/a-Si:H/c-Si/BSF/Al), the c-Si surface becomes part of the a-Si:H/c-Si interface, whose recombination activity determines cell performance. With textured substrates, the smoothening procedure results in a significant increase of short circuit current, fill factor and efficiency

  11. Characterization, non-isothermal decomposition kinetics and photocatalytic water splitting of green chemically synthesized polyoxoanions of molybdenum containing phosphorus as hetero atom

    International Nuclear Information System (INIS)

    D’Cruz, Bessy; Samuel, Jadu; George, Leena

    2014-01-01

    Highlights: • CPM nanorods were synthesized by applying the principles of green chemistry. • The isoconversional method was used to analyze the effective activation energy. • The appropriate reaction models of the two decomposition stages were determined. • Photocatalytic water splitting was investigated in the presence of platinum co-catalyst. - Abstract: In here, the green synthesis and thermal characterization of a novel polyoxoanions of molybdenum containing phosphorus as hetero atom are reported. The composition and morphology of the nanorods were established by fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA) and inductively coupled plasma atomic emission spectroscopic (ICP-AES) techniques. Thermal properties of the nanoparticles were investigated by non-isothermal analysis under nitrogen atmosphere. The values activation energy of each stage of thermal decomposition for all heating rates was calculated by Flynn–Wall–Ozawa (FWO) and Kissinger–Akahira–Sunnose (KAS) methods. Invariant kinetic parameter (IKP) method and master plot method were also used to evaluate the kinetic parameters and mechanism for the thermal decomposition of cetylpyridinium phosphomolybdate (CPM). Photocatalytic water oxidation mechanism using CPM catalyst in the presence of platinum (Pt) co-catalyst enhances the H 2 evolution and was found to be 1.514 mmol/g/h

  12. Characterization, non-isothermal decomposition kinetics and photocatalytic water splitting of green chemically synthesized polyoxoanions of molybdenum containing phosphorus as hetero atom

    Energy Technology Data Exchange (ETDEWEB)

    D’Cruz, Bessy [Department of Chemistry, Mar Ivanios College, Thiruvananthapuram 695015 (India); Samuel, Jadu, E-mail: jadu_samuel@yahoo.co.in [Department of Chemistry, Mar Ivanios College, Thiruvananthapuram 695015 (India); George, Leena [Catalysis and Inorganic Chemistry Division, National Chemical Laboratory, Pune 411008 (India)

    2014-11-20

    Highlights: • CPM nanorods were synthesized by applying the principles of green chemistry. • The isoconversional method was used to analyze the effective activation energy. • The appropriate reaction models of the two decomposition stages were determined. • Photocatalytic water splitting was investigated in the presence of platinum co-catalyst. - Abstract: In here, the green synthesis and thermal characterization of a novel polyoxoanions of molybdenum containing phosphorus as hetero atom are reported. The composition and morphology of the nanorods were established by fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA) and inductively coupled plasma atomic emission spectroscopic (ICP-AES) techniques. Thermal properties of the nanoparticles were investigated by non-isothermal analysis under nitrogen atmosphere. The values activation energy of each stage of thermal decomposition for all heating rates was calculated by Flynn–Wall–Ozawa (FWO) and Kissinger–Akahira–Sunnose (KAS) methods. Invariant kinetic parameter (IKP) method and master plot method were also used to evaluate the kinetic parameters and mechanism for the thermal decomposition of cetylpyridinium phosphomolybdate (CPM). Photocatalytic water oxidation mechanism using CPM catalyst in the presence of platinum (Pt) co-catalyst enhances the H{sub 2} evolution and was found to be 1.514 mmol/g/h.

  13. Solution-processed efficient CdTe nanocrystal/CBD-CdS hetero-junction solar cells with ZnO interlayer

    Energy Technology Data Exchange (ETDEWEB)

    Tian, Yiyao; Zhang, Yijie; Lin, Yizhao; Gao, Kuo; Zhang, Yunpeng; Liu, Kaiyi; Yang, Qianqian [South China University of Technology, School of Materials Science and Engineering (China); Zhou, Xiao; Qin, Donghuan, E-mail: qindh@scut.edu.cn; Wu, Hongbin [South China University of Technology, Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices (China); Xia, Yuxin; Hou, Lintao [Jinan University, College of Science and Engineering (China); Lan, Linfeng; Chen, Junwu; Wang, Dan; Yao, Rihui [South China University of Technology, Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices (China)

    2013-11-15

    CdTe nanocrystal (NC)/CdS p–n hetero-junction solar cells with an ITO/ZnO-In/CdS/CdTe/MoO{sub x}/Ag-inverted structure were prepared by using a layer-by-layer solution process. The CdS thin films were prepared by chemical bath deposition on top of ITO/ZnO-In and were found to be very compact and pin-hole free in a large area, which insured high quality CdTe NCs thin-film formation upon it. The device performance was strongly related to the CdCl{sub 2} annealing temperature and annealing time. Devices exhibited power conversion efficiency (PCE) of 3.08 % following 400 °C CdCl{sub 2} annealing for 5 min, which was a good efficiency for solution processed CdTe/CdS NC-inverted solar cells. By carefully designing and optimizing the CdCl{sub 2}-annealing conditions (370 °C CdCl{sub 2} annealing for about 15 min), the PCE of such devices showed a 21 % increase, in comparison to 400 °C CdCl{sub 2}-annealing conditions, and reached a better PCE of 3.73 % while keeping a relatively high V{sub OC} of 0.49 V. This PCE value, to the best of our knowledge, is the highest PCE reported for solution processed CdTe–CdS NC solar cells. Moreover, the inverted solar cell device was very stable when kept under ambient conditions, less than 4 % degradation was observed in PCE after 40 days storage.

  14. Mechanisms of the Knoevenagel hetero Diels-Alder sequence in multicomponent reactions to dihydropyrans: experimental and theoretical investigations into the role of water.

    Science.gov (United States)

    Frapper, Gilles; Bachmann, Christian; Gu, Yanlong; Coval De Sousa, Rodolphe; Jérôme, François

    2011-01-14

    The role of water in a multicomponent domino reaction (MCR) involving styrene, 2,4-pentanedione, and formaldehyde was studied. Whereas anhydrous conditions produced no reaction, the MCR successfully proceeded in the presence of water, affording the targeted dihydropyran derivatives with good yield. The mechanism of this MCR (Knoevenagel hetero Diels-Alder sequence) was studied with and without explicit water molecules using the SMD continuum solvation model in combination with the B3LYP density functional and the 6-311++G** basis set to compute the water and acetone (aprotic organic solvent) solution Gibbs free energies. In the Knoevenagel step, we found that water acted as a proton relay to favor the formation of more flexible six-membered ring transition state structures both in concerted (direct H(2)O elimination) and stepwise (keto-enol tautomerization and dehydration) pathways. The inclusion of a water molecule in our model resulted in a significant decrease (-8.5 kcal mol(-1)ΔG(water)(‡)) of the direct water elimination activation barrier. Owing to the presence of water, all chemical steps involved in the MCR mechanism had activation free energies barriers lower than 39 kcal mol(-1) at 25 °C in aqueous solvent (ZPE corrected electronic energies barriers). Consequently, the MCR proceeded without the assistance of any catalyst.

  15. Characterization of nano-powder grown ultra-thin film p-CuO/n-Si hetero-junctions by employing vapour-liquid-solid method for photovoltaic applications

    Energy Technology Data Exchange (ETDEWEB)

    Sultana, Jenifar; Das, Anindita [Centre for Research in Nanoscience and Nanotechnology (CRNN), Kolkata 700098 (India); Das, Avishek [Department of Electronic Science, University of Calcutta, Kolkata 700009 (India); Saha, Nayan Ranjan [Department of Polymer Science and Technology, University of Calcutta, Kolkata 700009 (India); Karmakar, Anupam [Department of Electronic Science, University of Calcutta, Kolkata 700009 (India); Chattopadhyay, Sanatan, E-mail: scelc@caluniv.ac.in [Department of Electronic Science, University of Calcutta, Kolkata 700009 (India)

    2016-08-01

    In this work, the CuO nano-powder has been synthesized by employing chemical bath deposition technique for its subsequent use to grow ultrathin film (20 nm) of p-CuO on n-Si substrate for the fabrication of p-CuO/n-Si hetero-junction diodes. The thin CuO film has been grown by employing vapour-liquid-solid method. The crystalline structure and chemical phase of the film are characterized by employing field-emission scanning electron microscopy and X-ray diffraction studies. Chemical stoichiometry of the film has been confirmed by using energy dispersive X-ray spectroscopy. The potential for photovoltaic applications of such films is investigated by measuring the junction current-voltage characteristics and by extracting the relevant parameters such as open circuit photo-generated voltage, short circuit current density, fill-factor and energy conversion efficiency. - Highlights: • Synthesis of CuO nano-powder by CBD method • Growth of ultra-thin film of CuO by employing VLS method for the first time • Physical and electrical characterization of such films for photovoltaic applications • Estimation of energy conversion efficiency of the p-CuO/n-Si p-n junction solar cell.

  16. Enhanced electrical properties of AZO thin films grown on different substrates by using a facing-target sputtering system with hetero targets

    Science.gov (United States)

    Lee, ChangHyun; Bae, Kang; Jin, IkHyeon; Kim, HwaMin; Sohn, SunYoung

    2015-09-01

    Al-doped ZnO (AZO) films were deposited on glass, polyethylene naphthalate (PEN) and polyethylene terephthalate (PET) at room temperature by using conventional rf-magneton sputtering (CMS) and a facing-target sputtering (FTS) with hetero targets of Al2O3 and ZnO. Their structural, surface morphology, electrical and optical properties were characterized by using X-ray diffractometry (XRD), atomic force microscopy (AFM), Hall-effect measurement and ultravioletvisible spectrophotometry, respectively. The films exhibit highly c-axis preferred orientation and a closely packed nanocrystalline. Structure the FTS-films deposited on plastic substrate are found to receive much less stress due to bombardment of high-energy particles compress to the CMS-films deposited on plastic substrates, during the sputtering process, which can enhance the electrical properties and crystalline quality of the FTS-films compared with those of the CMS-films. The resistivities of the FTS-films are 6.50 × 10-4 Ω·cm on glass, 7.0 × 10-4 Ω·cm on PEN and 7.4 × 10-4 Ω·cm on PET while the values for the CMS-films are 7.6 × 10-4 Ω·cm on glass, 1.20 × 10-3 Ω·cm on PEN and 1.58 × 10-3 Ω·cm on PET.

  17. A computational study of the effects of linear doping profile on the high-frequency and switching performances of hetero-material-gate CNTFETs

    International Nuclear Information System (INIS)

    Wang Wei; Li Na; Ren Yuzhou; Li Hao; Zheng Lifen; Li Jin; Jiang Junjie; Chen Xiaoping; Wang Kai; Xia Chunping

    2013-01-01

    The effects of linear doping profile near the source and drain contacts on the switching and high-frequency characteristics for conventional single-material-gate CNTFET (C-CNTFET) and hetero-material-gate CNTFET (HMG-CNTFET) have been theoretically investigated by using a quantum kinetic model. This model is based on two-dimensional non-equilibrium Green's functions (NEGF) solved self-consistently with Poisson's equations. The simulation results show that at a CNT channel length of 20 nm with chirality (7, 0), the intrinsic cutoff frequency of C-CNTFETs reaches up to a few THz. In addition, a comparison study has been performed between C-and HMG-CNTFETs. For the C-CNTFET, results reveal that a longer linear doping length can improve the cutoff frequency and switching speed. However, it has the reverse effect on on/off current ratios. To improve the on/off current ratios performance of CNTFETs and overcome short-channel effects (SCEs) in high-performance device applications, a novel CNTFET structure with a combination of an HMG and linear doping profile has been proposed. It is demonstrated that the HMG structure design with an optimized linear doping length has improved high-frequency and switching performances as compared to C-CNTFETs. The simulation study may be useful for understanding and optimizing high-performance of CNTFETs and assessing the reliability of CNTFETs for prospective applications. (semiconductor devices)

  18. Photocatalytic reduction of Cr(VI) on the new hetero-system CuAl{sub 2}O{sub 4}/TiO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Gherbi, R. [Laboratory of Reaction Engineering, Faculty of Mechanic and Engineering Processes, USTHB, BP 32, 16111 Algiers (Algeria); Nasrallah, N. [Laboratory of Reaction Engineering, Faculty of Mechanic and Engineering Processes, USTHB, BP 32, 16111 Algiers (Algeria); Equipe chimie et Ingenierie des procedes, UMR CNRS 6226, E.N.S.C.R., Avenue du General Leclerc, CS 50837, 35708 Rennes Cedex 7 (France); Amrane, A. [Equipe chimie et Ingenierie des procedes, UMR CNRS 6226, E.N.S.C.R., Avenue du General Leclerc, CS 50837, 35708 Rennes Cedex 7 (France); Maachi, R. [Laboratory of Reaction Engineering, Faculty of Mechanic and Engineering Processes, USTHB, BP 32, 16111 Algiers (Algeria); Trari, M., E-mail: solarchemistry@gmail.com [Laboratory of Storage and Valorization of Renewable Energies, Faculty of Chemistry, USTHB, BP 32, 16111 Algiers (Algeria)

    2011-02-28

    Visible light driven HCrO{sub 4}{sup -} reduction was successfully achieved over the new hetero-system CuAl{sub 2}O{sub 4}/TiO{sub 2}. The spinel, elaborated by nitrate route, was characterized photo electrochemically. The optical gap was found to be 1.70 eV and the transition is directly allowed. The conduction band (-1.05 V{sub SCE}) is located below that of TiO{sub 2}, more negative than the HCrO{sub 4}{sup -}/Cr{sup 3+} level (+0.58 V{sub SCE}) yielding a thermodynamically feasible chromate reduction upon visible illumination. CuAl{sub 2}O{sub 4} is stable against photo corrosion by holes consumption reaction involving salicylic acid which favors the charges separation. There is a direct correlation between the dark adsorption and the photo activity. A reduction of more than 95% of chromate was achieved after 3 h irradiation at pH 2 with an optimal mass ratio (CuAl{sub 2}O{sub 4}/TiO{sub 2}) equal to 1/3. The reduction follows a first order kinetic with a half life of {approx}1 h and a quantum yield of 0.11% under polychromatic light. Prolonged illumination was accompanied by a deceleration of the Cr(VI) reduction thanks to the competitive water discharge. The hydrogen evolution, an issue of energetic concern, took place with a rate of 3.75 cm{sup 3} (g catalyst){sup -1} h{sup -1}.

  19. Surface Reconstruction for Preparation of Plasmonic Au/TiO₂ Nanoparticle with Perfect Hetero Interface and Improved Photocatalytic Capacity.

    Science.gov (United States)

    Yuan, Guoqiu; Ping, Chen; Zhao, Qin; Cao, Min; Jin, Yonglong; Ge, Cunwang

    2018-07-01

    The photocatalytic activity of plasmonic Au/TiO2 nanoparticles (NPs) is dependent on distances between Au and TiO2. The preparation of plasmonic NPs is still a challenge because of an inherent lattice mismatch on heterogeneous interfaces. The combination between Au and TiO2 NPs often exhibits physical adsorption, which affect block the electron transferring process by photo-induction from TiO2 to Au NPs and weaken the photocatalytic activity. In this work an approach for preparing plasmonic Au/TiO2 NPs with perfect hetero-interface was proposed based on reconstruction of anatase TiO2 with (101) surface and in-situ reduction of Au NPs. Under UV-irradiation, anatase TiO2 NPs with a high percentage of (001) facets in formaldehyde solution undergo photochemical reactions to reconstruct the (101) surface of TiO2 and simultaneously allow polyformaldehyde to absorb on the same surface. Thus, Au(OH)-4 ions could be adsorbed on the (101) surfaces of TiO2 through electrostatic adsorption and reduced to form nano-Au in situ after recrystallization at 180 °C. The high-resolution transmission electron microscopy (HRTEM) images showed clear nanoscale lattice transition on heterogeneous interfaces of Au/TiO2 NPs. The surface structure of TiO2 NPs and the growth mechanism of Au/TiO2 NPs were evaluated with HRTEM, X-ray photoelectron spectra (XPS) and Fourier transform infrared spectroscopy (FTIR). It was demonstrated that the as-prepared plasmonic Au/TiO2 NPs had higher photocatalytic activity and corrosion resistance in comparison with primary TiO2 NPs by photo-electrochemical measurements. The reinforcing mechanism could be interpreted with Mott-Schottky analysis in terms of quantum mechanics. Our study implied that the reconstruction based synthesis may open up more opportunities to obtain lattice-mismatch nanomaterials for photocatalysis.

  20. "Videvik" - hiiglaslik videotuba / Hanno Soans

    Index Scriptorium Estoniae

    Soans, Hanno, 1974-

    1998-01-01

    Sorosi Kaasaegse Kunsti Leedu Keskuse V aastanäitus "Videvik" Vilniuse keskuses 20. jaan. - 22. veebr. Korraldajad leedu noorema põlvkonna kriitikud-kuraatorid K. Kuizinas, D. Narkevicius, E. Stankevicius, briti osa kordinaator R. Wall.

  1. Young British Art / Hanno Soans

    Index Scriptorium Estoniae

    Soans, Hanno, 1974-

    2001-01-01

    1990ndate kunsti muutumisest. Inglise kunstniku Peter Daviese maalist "Kuum esimene sada" (1996), Gavin Turki vahakujuna valminud autoportreest "Pop". "Young British Art'i" uuskunstist ja Jasper Zoova installatsioonist "F1". Eri analüüsivõimalusi pakkuvatest töödest (Marko Laimre & Ene-Liis Semperi 2000. a. novembri ühisnäituse osa töid).

  2. Bonds broken and formed during the mixed-linkage glucan : xyloglucan endotransglucosylase reaction catalysed by Equisetum hetero-trans-β-glucanase.

    Science.gov (United States)

    Simmons, Thomas J; Fry, Stephen C

    2017-03-08

    Mixed-linkage glucan∶xyloglucan endotransglucosylase (MXE) is one of the three activities of the recently characterised hetero-trans-β-glucanase (HTG), which among land plants is known only from Equisetum species. The biochemical details of the MXE reaction were incompletely understood - details that would promote understanding of MXE's role in vivo and enable its full technological exploitation. We investigated HTG's site of attack on one of its donor substrates, mixed-linkage (1→3),(1→4)-β-d-glucan (MLG), with radioactive oligosaccharides of xyloglucan as the acceptor substrate. Comparing three different MLG preparations, we showed that the enzyme favours those with a high content of cellotetraose blocks. The reaction products were analysed by enzymic digestion, thin-layer chromatography (TLC), high-pressure liquid chromatography (HPLC) and gel-permeation chromatography (GPC). Equisetum HTG consistently cleaved the MLG at the third consecutive β-(1→4)-bond following (towards the reducing terminus) a β-(1→3)-bond. It then formed a β-(1→4)-bond between the MLG and the non-reducing terminal glucose residue of the xyloglucan oligosaccharide, consistent with its xyloglucan endotransglucosylase/hydrolase subfamily membership. Using size-homogeneous barley MLG as the donor substrate, we showed that HTG does not favour any particular region of the MLG chain relative to the polysaccharide's reducing and non-reducing termini; rather, it selects its target cellotetraosyl unit stochastically along the MLG molecule. This work improves our understanding of how enzymes can exhibit promiscuous substrate specificities and provides the foundations to explore strategies for engineering novel substrate specificities into transglycanases. © 2017 The Author(s).

  3. Photocatalytic reduction of Cr(VI) on the novel hetero-system CuFe{sub 2}O{sub 4}/CdS

    Energy Technology Data Exchange (ETDEWEB)

    Nasrallah, N.; Kebir, M. [Laboratory of Engineering Reaction, Faculty of Engineering Mechanic and Engineering Processus (USTHB), BP 32, Algiers (Algeria); Koudri, Z. [Laboratory of Storage and Valorization of Renewable Energies, Faculty of Chemistry (USTHB), BP 32, Algiers (Algeria); Trari, M., E-mail: solarchemistry@gmail.com [Laboratory of Storage and Valorization of Renewable Energies, Faculty of Chemistry (USTHB), BP 32, Algiers (Algeria)

    2011-01-30

    The photocatalytic HCrO{sub 4}{sup -} reduction was investigated in air equilibrated solution using the spinel CuFe{sub 2}O{sub 4} nanoparticles as sensitizers. The oxide is p-type semi conductor, prepared from nitrates decomposition. The catalytic performance increases with decreasing pH and the concomitant oxidation of salicylic acid contributes significantly to the photoactivity through the charges separation of electron/hole pairs (C{sub 7}H{sub 6}O{sub 3} + 6 O{sub 2} + 4 h{sup +} + 3 H{sub 2}O {yields} 7 CO{sub 2} + 4 H{sub 3}O{sup +}). Evidence has been given to show the advantages of the hetero-system CuFe{sub 2}O{sub 4}/CdS in the chromate reduction. CuFe{sub 2}O{sub 4} acts as electrons pump and the electron transfer to chromate is mediated via CdS hexagonal variety (greenockite). A reduction of 60% occurs and the process is well described by a pseudo first order kinetic with a half life of {approx}2.8 h and a quantum yield of {approx}0.12% for an initial HCrO{sub 4}{sup -} concentration of 3 x 10{sup -4} M. An improvement up to 72% is obtained when the reaction occurs in a stirred reactor and no cadmium was detected after 6 h illumination. The results indicate a competitive effect with the water reduction. The hydrogen evolutions are found to be 0.236 and 0.960 cm{sup 3} mn{sup -1} g{sup -1} in presence and in absence of HCrO{sub 4}{sup -}, respectively.

  4. Attrattività delle città di celluloide. A Venezia tra cinema "avventura" e turismo / Attractiveness of the celluloid cities. In Venice between “adventure” cinema and tourism

    Directory of Open Access Journals (Sweden)

    Donatella Privitera

    2016-05-01

    Full Text Available Molte destinazioni hanno basato la loro strategia di promozione affidandosi ai prodotti multimediali, considerando i vantaggi legati alla potenza incisiva del cinema. Il cinema conserva un ruolo privilegiato grazie alla sua capacità di suggestione. Lo scopo dello studio è di migliorare la comprensione del cineturismo in location in film noti e di avventura. Quali sono le immagini che i turisti hanno di Venezia visionando i film di James Bond? Le interviste sono state condotte con un gruppo di studenti che hanno visto la pellicola Casino Royale. I risultati mostrano che Venezia nel mondo di Bond contiene elementi attrattivi ma rimane piuttosto in secondo piano.   Film and Tourism share a close relationship. The aim of the study is to improve understanding of film induced tourism on locations featured in popular films. The present research used the case of James Bond film to explore this issue about Venice. Interviews were conducted with students who have seen Casino Royale movie. These interviews indicate that Venice, into the world of Bond contains elements attractive but it remains of little importance compared to Bond.

  5. Diavolo di una particella perchè il bosone di Higgs cambierà la nostra vita

    CERN Document Server

    Menasce, Dario

    2013-01-01

    Lo scienziato del Cern Dario Menasce ha partecipato direttamente agli esperimenti che hanno condotto alla scoperta del Bosone di Higgs, ma , prima di condurre il lettore all'interno dell'LHC e dei suoi misteri, con coinvolgimento e grande serietà guida il lettore attraverso i momenti più importanti delle ricerche della fisica tramite l'intervento dei grandi scienziati del passato e del presente, che hanno infine permesso di arrivare a definire il Modello Standard delle particelle, il primo passo verso l'ipotetica Teoria del Tutto. Un testo molto utile per chi vuole sondare il mondo dell'ultrasottile, che riprendo in più occasioni anche come manuale di consultazione e approfondimento.

  6. Koolidirektor muretseb / Age Viil ; vahendas Sirje Tohver

    Index Scriptorium Estoniae

    Viil, Age

    1997-01-01

    Tallinna Humanitaarkeskkooli direktor Age Viil õpetaja palgaprobleemidest, riigieksamitest, kooli õppekavast, kommenteerivad Anneli Kommer, Ants Eglon, Hanno Isok, Toivo Sikk ja Kersti Kaldma Haridusministeeriumist

  7. Mõtteid "Pegasusest" = Thoughts about Pegasus / Edina Dufala-Pärn

    Index Scriptorium Estoniae

    Dufala-Pärn, Edina

    2000-01-01

    Kohvik-restorani kujundusest. Projekteerija: Front Arhitektid. Sisekujundajad Gert Sarv, Margus Tammik, Tarvo Hanno Varres. Projekt 1999, valmis 2000. "Pegasuse" endise vaimsuse kadumisest. 11 illustratsiooni

  8. Synthesis of novel chromeno-annulated cis-fused pyrano[3,4-c]benzopyran and naphtho pyran derivatives via domino aldol-type/hetero Diels-Alder reaction and their cytotoxicity evaluation.

    Science.gov (United States)

    Madda, Jyothi; Venkatesham, Akkaladevi; Naveen Kumar, Bejjanki; Nagaiah, Kommu; Sujitha, Pombala; Ganesh Kumar, C; Rao, Tadikamalla Prabhakar; Jagadeesh Babu, Nanubolu

    2014-09-15

    New chromeno-annulated cis-fused pyrano[3,4-c]benzopyran and naphtho pyran derivatives have been synthesized by domino aldol-type reaction/hetero Diels-Alder reaction generated from o-quinone methide in situ from 7-O-prenyl derivatives of 8-formyl-2,3-disubstituted chromenones with resorcinols/naphthols in the presence of 20 mol% ethylenediamine diacetate (EDDA), triethylamine (2 mL) as co-catalyst in CH3CN under reflux conditions in good yields. The structures were established based on spectroscopic data, and further confirmed by X-ray diffraction analysis. The results showed that compounds 4h and 4j exhibited very potent cytotoxicity against human cervical cancer cell line (HeLa). Compound 4h displayed good inhibitory activity against both breast cancer cell lines, MDA-MB-231 and MCF-7. Further, the compound 4i exhibited good cytotoxicity against only MDA-MB-231, and compound 4j showed promising activity against human lung cancer cell line, A549 with IC50 value of 2.53±0.07 μM, which was comparable to the standard doxorubicin (IC50=1.21±0.1 μM). Copyright © 2014 Elsevier Ltd. All rights reserved.

  9. Theoretical calculation of performance enhancement in lattice-matched SiGeSn/GeSn p-channel tunneling field-effect transistor with type-II staggered tunneling junction

    Science.gov (United States)

    Wang, Hongjuan; Han, Genquan; Wang, Yibo; Peng, Yue; Liu, Yan; Zhang, Chunfu; Zhang, Jincheng; Hu, Shengdong; Hao, Yue

    2016-04-01

    In this work, a lattice-matched SiGeSn/GeSn heterostructure p-channel tunneling field-effect transistor (hetero-PTFET) with a type-II staggered tunneling junction (TJ) is investigated theoretically. Lattice matching and type-II band alignment at the Γ-point is obtained at the SiGeSn/GeSn interface by tuning Sn and Si compositions. A steeper subthreshold swing (SS) and a higher on state current (I ON) are demonstrated in SiGeSn/GeSn hetero-PTFET than in GeSn homo-PTFET. Si0.31Ge0.49Sn0.20/Ge0.88Sn0.12 hetero-PTFET achieves a 2.3-fold higher I ON than Ge0.88Sn0.12 homo-PTFET at V DD of 0.3 V. Hetero-PTFET achieves a more abrupt hole profile and a higher carrier density near TJ than the homo-PTFET, which contributes to the significantly enhanced band-to-band tunneling (BTBT) rate and tunneling current in hetero-PTFET.

  10. Hetero-oligomeric Complex between the G Protein-coupled Estrogen Receptor 1 and the Plasma Membrane Ca2+-ATPase 4b.

    Science.gov (United States)

    Tran, Quang-Kim; VerMeer, Mark; Burgard, Michelle A; Hassan, Ali B; Giles, Jennifer

    2015-05-22

    The new G protein-coupled estrogen receptor 1 (GPER/GPR30) plays important roles in many organ systems. The plasma membrane Ca(2+)-ATPase (PMCA) is essential for removal of cytoplasmic Ca(2+) and for shaping the time courses of Ca(2+)-dependent activities. Here, we show that PMCA and GPER/GPR30 physically interact and functionally influence each other. In primary endothelial cells, GPER/GPR30 agonist G-1 decreases PMCA-mediated Ca(2+) extrusion by promoting PMCA tyrosine phosphorylation. GPER/GPR30 overexpression decreases PMCA activity, and G-1 further potentiates this effect. GPER/GPR30 knockdown increases PMCA activity, whereas PMCA knockdown substantially reduces GPER/GPR30-mediated phosphorylation of the extracellular signal-related kinase (ERK1/2). GPER/GPR30 co-immunoprecipitates with PMCA with or without treatment with 17β-estradiol, thapsigargin, or G-1. Heterologously expressed GPER/GPR30 in HEK 293 cells co-localizes with PMCA4b, the main endothelial PMCA isoform. Endothelial cells robustly express the PDZ post-synaptic density protein (PSD)-95, whose knockdown reduces the association between GPER/GPR30 and PMCA. Additionally, the association between PMCA4b and GPER/GPR30 is substantially reduced by truncation of either or both of their C-terminal PDZ-binding motifs. Functionally, inhibition of PMCA activity is significantly reduced by truncation of GPER/GPR30's C-terminal PDZ-binding motif. These data strongly indicate that GPER/GPR30 and PMCA4b form a hetero-oligomeric complex in part via the anchoring action of PSD-95, in which they constitutively affect each other's function. Activation of GPER/GPR30 further inhibits PMCA activity through tyrosine phosphorylation of the pump. These interactions represent cross-talk between Ca(2+) signaling and GPER/GPR30-mediated activities. © 2015 by The American Society for Biochemistry and Molecular Biology, Inc.

  11. Aristotele, Einstein e gli altri i grandi scienziati tra pensiero e vita quotidiana

    CERN Document Server

    Fischer, Ernst Peter

    1997-01-01

    Abbiamo spesso un'idea confusa di quelle che sono state le vite degli uomini che hanno consacrato all'impresa scientifica le loro migliori energie. Eppure, non solo nell'arte e nella filosofia, ma anche nella scienza "lo stile è l'uomo" e la psicologia del singolo scienziato può rivelarsi il miglior aiuto per capire la logica della scoperta scientifica. Questa è una "storia della scienza raccontata agli amici davanti al caminetto", come l'autore stesso definisce la propria opera. Che non è soltanto una ricostruzione puntuale delle svolte principali che hanno portato alla scienza contemporanea, ma un racconto delle vicende personali di tutti quegli scienziati che sono stati divorati dalla passione del conoscere.

  12. Report on the surveys in fiscal 1984. Surveys on the possibility of using coal liquefied oil as a raw material, and technological development thereon; 1984 nendo sekitan ekikayu no genryoka no kanosei oyobi sono gijutsu kaihatsu ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1985-03-01

    With an objective to establish an optimal method for utilizing coal liquefied oil, surveys were performed on the current status of applicable separation technologies for effective utilization of the hetero compounds of O and N contained in liquefied oil, the possibility of hetero compound utilization and issues in technological development for the utilization thereof. Since coal liquefied oil reflects greatly the coal composition and its structure, it contains generally a greater amount of hetero compounds, such as nitrogen and sulfur, as well as aromatic compounds than petroleum. If the hetero compounds could be removed from the liquefied oil more effectively before reforming as a result of progress in separation technologies, hydrogen consumption may be reduced. In addition, economic performance of the coal liquefaction business can be relatively improved by establishing a technology to utilize more effectively these by-products. The current fiscal year has performed surveys on the current status of technologies to separate oxygen and nitrogen in liquefied oil, the possibility of utilizing these hetero compounds, and issues in technological development for the utilization thereof. At the same time, surveys were carried out on the compositions, contents, and separation and analysis methods of hetero compounds in oil obtained by using the coal liquefaction systems being practically used. (NEDO)

  13. Täna avab kesklinnas uksed uus kaubatänav / Oliver Õunmaa

    Index Scriptorium Estoniae

    Õunmaa, Oliver

    2007-01-01

    Jõukamale ja eneseteadlikule ostjale mõeldud kaubanduskeskusest Foorum Tallinnas Narva mnt. Sisearhitekt Hannes Praks. Foorumi projekti autorid Hanno Grossschmidt ja Tomomi Hayashi arhitektuuribüroost HG Arhitektuur

  14. WiFiabe: un’esperienza di storytelling dal territorio al web 2.0

    Directory of Open Access Journals (Sweden)

    Marco Carnesecchi

    2013-03-01

    Full Text Available L’impatto iniziale di WiRoni sulla popolazione di Monteroni d’Arbia (Siena è stato limitato alla fruizione dei contenuti caricati dal team di design, in particolare le storie per i bambini. Mancavano infatti brani audio prodotti dalla comunità locale. In realtà, però, la competenza tecnica necessaria a trasmettere i contenuti nel parco e in rete è minima (upload da CMS wordpress e anche le tecnologie per registrare e arricchire l’audio con effetti sonori sono alla portata di tutti, se opportunamente guidati da esperti. Da queste osservazioni è nato il progetto WiFiabe. Nel corso dell’anno scolastico 2010/2011 20 bambini tra 6 e 13 anni, coordinati da un’educatrice durante l’attività di doposcuola del Comune, hanno lavorato in gruppi e creato storie di fantasia. In seguito, alcuni studenti dell’Università di Siena, con l’aiuto di un musicista per la parte degli effetti sonori, hanno assistito i ragazzi nel diventare autori digitali e apprendere in prima persona come trasformare le loro storie in contenuti audio. In questo modo i partecipanti hanno interagito con il web non in quanto fruitori ma come autori, e messo in moto un processo per rendere WiRoni uno strumento per dare voce alle varie anime della comunità.

  15. I parchi eolici: la complessa interazione tra natura, uomo e tecnologia - The wind farms: the complex interaction among nature, man and technology

    Directory of Open Access Journals (Sweden)

    Massimiliano Masullo

    2015-10-01

    Full Text Available Sin dai tempi antichi l’uomo ha costruito macchine che, sfruttando l’energia del vento, lo hanno aiutato a nutrire se stesso, la terra e a svolgere lavorazioni complesse. Con la scoperta dell’elettricità la funzione di queste macchine è cambiata radicalmente. Negli ultimi venti anni, politiche d'incentivazione hanno portato allo sviluppo di impianti eolici ed alla loro diffusione sul territorio, determinando una interazione sempre più intensa fra turbine eoliche, ambiente circostante ed uomo. Questo articolo presentata una rassegna dei principali fattori che determinano o modificano la percezione dell’impatto che queste macchine hanno sull’uomo e sull’ambiente circostante. ------ Since ancient times the man has built machines which exploiting the energy of the wind have helped to feed himself, the land and carry out complex operations. With the discovery of electricity the function of these machines is changed radically. In the last twenty years, incentive policies have led to the development of wind farms and their diffusion over the territory, resulting in a more intense interaction between wind turbines, environment and man. This article presents a review of the main factors that determine or affect the perception of the impact that these machines have on humans and the surrounding environment.

  16. Homo-Hetero

    African Journals Online (AJOL)

    Administrator

    distance inter-connectedness, at least across national boundaries, preferably between ... individuals would be increasingly free from the ascribed particularistic identities ... religious nationalism is seen as a part of the conflicting process of ...

  17. Investigation of energy band alignments and interfacial properties of rutile NMO2/TiO2 (NM = Ru, Rh, Os, and Ir) by first-principles calculations.

    Science.gov (United States)

    Yang, Chen; Zhao, Zong-Yan

    2017-11-08

    In the field of photocatalysis, constructing hetero-structures is an efficient strategy to improve quantum efficiency. However, a lattice mismatch often induces unfavorable interfacial states that can act as recombination centers for photo-generated electron-hole pairs. If the hetero-structure's components have the same crystal structure, this disadvantage can be easily avoided. Conversely, in the process of loading a noble metal co-catalyst onto the TiO 2 surface, a transition layer of noble metal oxides is often formed between the TiO 2 layer and the noble metal layer. In this article, interfacial properties of hetero-structures composed of a noble metal dioxide and TiO 2 with a rutile crystal structure have been systematically investigated using first-principles calculations. In particular, the Schottky barrier height, band bending, and energy band alignments are studied to provide evidence for practical applications. In all cases, no interfacial states exist in the forbidden band of TiO 2 , and the interfacial formation energy is very small. A strong internal electric field generated by interfacial electron transfer leads to an efficient separation of photo-generated carriers and band bending. Because of the differences in the atomic properties of the components, RuO 2 /TiO 2 and OsO 2 /TiO 2 hetero-structures demonstrate band dividing, while RhO 2 /TiO 2 and IrO 2 /TiO 2 hetero-structures have a pseudo-gap near the Fermi energy level. Furthermore, NMO 2 /TiO 2 hetero-structures show upward band bending. Conversely, RuO 2 /TiO 2 and OsO 2 /TiO 2 hetero-structures present a relatively strong infrared light absorption, while RhO 2 /TiO 2 and IrO 2 /TiO 2 hetero-structures show an obvious absorption edge in the visible light region. Overall, considering all aspects of their properties, RuO 2 /TiO 2 and OsO 2 /TiO 2 hetero-structures are more suitable than others for improving the photocatalytic performance of TiO 2 . These findings will provide useful information

  18. The 3,7-diazabicyclo[3.3.1]nonane scaffold for subtype selective nicotinic acetylcholine receptor (nAChR) ligands. Part 1: the influence of different hydrogen bond acceptor systems on alkyl and (hetero)aryl substituents.

    Science.gov (United States)

    Eibl, Christoph; Tomassoli, Isabelle; Munoz, Lenka; Stokes, Clare; Papke, Roger L; Gündisch, Daniela

    2013-12-01

    3,7-Diazabicyclo[3.3.1]nonane is a naturally occurring scaffold interacting with nicotinic acetylcholine receptors (nAChRs). When one nitrogen of the 3,7-diazabicyclo[3.3.1]nonane scaffold was implemented in a carboxamide motif displaying a hydrogen bond acceptor (HBA) functionality, compounds with higher affinities and subtype selectivity for α4β2(∗) were obtained. The nature of the HBA system (carboxamide, sulfonamide, urea) had a strong impact on nAChR interaction. High affinity ligands for α4β2(∗) possessed small alkyl chains, small un-substituted hetero-aryl groups or para-substituted phenyl ring systems along with a carboxamide group. Electrophysiological responses of selected 3,7-diazabicyclo[3.3.1]nonane derivatives to Xenopus oocytes expressing various nAChR subtypes showed diverse activation profiles. Compounds with strongest agonistic profiles were obtained with small alkyl groups whereas a shift to partial agonism/antagonism was observed for aryl substituents. Copyright © 2013 Elsevier Ltd. All rights reserved.

  19. OECD sarjab II samba peatamist / Erik Müürsepp

    Index Scriptorium Estoniae

    Müürsepp, Erik

    2009-01-01

    OECD peab II pensionisamba maksete peatamist taunitavaks. OECD dokumendist, milles vaadeldakse praegu kriisiolukorda sattunud riikide käitumist pensionisüsteemi kujundamisel. Sotsiaalminister Hanno Pevkuri arvamus OECD soovituste kohta

  20. Mis mulje jättis esimene "Portfolio Cafe"? / Anneli Porri ; interv. R[eet] V[arblane

    Index Scriptorium Estoniae

    Porri, Anneli, 1980-

    2007-01-01

    Oktoobris 2007 Tallinnas toimuva noorte kunstnike biennaali esimesest "Portfolio Cafe'st" Eesti Kunstiakadeemia aulas. Töid kommenteerisid Ahto Külvet, Annie Fletcher, Marita Muukkonen, Hanno Soans ja Ave Randviir

  1. Into a flowering garden / Hanno Soans

    Index Scriptorium Estoniae

    Soans, Hanno, 1974-

    2001-01-01

    Viimane projekt seeriast "Reformatsioon" oli tekstiinstallatsioon avalikus paigas seoses propagandaportselani näitusega Väliskunsti Muuseumis Tallinnas. Loosung "Me muudame kogu maailma õitsvaks aiaks" Kadrioru pargis. Kadrioru lossist kunstimuuseumina

  2. Korrast ja selle kaitsest / Hanno Pevkur

    Index Scriptorium Estoniae

    Pevkur, Hanno, 1977-

    2007-01-01

    Korrakaitseseaduse eelnõust. Ilmunud ka Hiiu Leht 20. aprill 2007, lk. 2 ; Vali Uudised 20. aprill 2007, lk. 2 ; Põhjarannik 20. aprill 2007, lk. 2 ; Sakala 20. aprill 2007, lk. 2 ; Elva Postipoiss 21. aprill 2007, lk. 4 ; Koit 24. aprill 2007, lk. 2 ; Nädaline 24. aprill 2007, lk. 4 ; Oma Saar 26. aprill 2007, lk. 5 ; Valgamaalane 26. aprill 2007, lk. 2 ; Pärnu Postimees 9. mai 2007, lk. 19

  3. Glucocorticoid Receptor Hetero-Complex Gene STIP1 Is Associated with Improved Lung Function in Asthmatics Treated with Inhaled Corticosteroids

    Science.gov (United States)

    Hawkins, Gregory A.; Lazarus, Ross; Smith, Richard S.; Tantisira, Kelan G.; Meyers, Deborah A.; Peters, Stephen P.; Weiss, Scott T.; Bleecker, Eugene R.

    2015-01-01

    Background Corticosteroids exert their anti-inflammatory action by binding and activating the intracellular the glucocorticoid receptor (GR) hetero-complex. Objective Evaluate the genes HSPCB, HSPCA, STIP1, HSPA8, DNAJB1, PTGES3, FKBP5, and FKBP4 on corticosteroid response. Methods Caucasian asthmatics (382) randomized to once daily flunisolide or conventional inhaled corticosteroid therapy were genotyped. Outcome measures were baseline FEV1, % predicted FEV1, and % change in FEV1 after corticosteroid treatment. Multivariable analyses adjusted for age, gender, and height, were performed fitting the most appropriate genetic model based on quantitative mean derived from ANOVA models to determine if there was an independent effect of polymorphisms on change in FEV1 independent of baseline level. Results Positive recessive model correlations for STIP1 SNPs were observed for baseline FEV1 [rs4980524, p=0.009; rs6591838, p=0.0045; rs2236647, p=0.002; and rs2236648; p=0.013], baseline % predicted FEV1 [rs4980524, p=0.002; rs6591838, p=0.017; rs2236647, p=0.003; and rs2236648; p=0.008] ; % change in FEV1 at 4 weeks [rs4980524, p=0.044; rs6591838, p=0.016; rs2236647; p=0.01] and 8 weeks therapy [rs4980524, p=0.044; rs6591838, p=0.016; rs2236647; p=0.01]. Haplotypic associations were observed for baseline FEV1 and % change in FEV1 at 4 weeks therapy [p=0.05 and p=0.01, respectively]. Significant trends towards association were observed for baseline % predicted FEV1 and % change in FEV1 at 8 weeks therapy. Positive correlations between haplotypes and % change in FEV1 were also observed. Conclusions STIP1 genetic variations may play a role in regulating corticosteroid response in asthmatics with reduced lung function. Replication in a second asthma population is required to confirm these observations. Clinical Implications Identifying genes that regulate corticosteroid responses could allow a priori determination of individual responses to corticosteroid therapy, leading to

  4. Kamina valik : disain ja funktsionaalsus

    Index Scriptorium Estoniae

    2007-01-01

    Kaminasalongi Tulering juht Hanno Tammvere salongis pakutavatest Belgia firmas Stuv ja Poola firmas Hadjuk kaminatest. Salong teeb koostööd eesti sisearhitektidega (14 nime), tellida saab kamina projekteerimisest paigaldamiseni

  5. 15 aastat ehitamist Eestis / Ado Eigi

    Index Scriptorium Estoniae

    Eigi, Ado, 1938-2008

    2006-01-01

    Eesti arhitektuur viimase 15 aasta jooksul. Loetletud parimad arhitektuuriteosed: Mardi talu Saaremaal (Jüri Okas, 2002); Transgroup Investi büroohoone Tallinnas (Urmas Lõoke, 2005); Ferrumi kaubanduskeskuse hoone Kuressaares (Andres Alver, Tiit Trummal, Tarmo Laht, Indrek Rünkla, Ulla Mets, 2002); KUMU kunstimuuseum (Pekka Vapaavuori, 2005); Lootsi 3a korterelamu Tallinnas (Hanno Grossschmidt, 2005); City Plaza Tallinnas (Andres Alver, Tiit Trummal, Martin Melioranski, Indrek Rünkla, 2005); Okupatsioonide muuseum (Indrek Peil, Siiri Vallner, 2003); Pärnu kesklinna koolide võimla (Katrin Koov, Kaire Nõmm, Heidi Urb, Siiri Vallner, 2005); De la Gardie kaubamaja Tallinnas (Andres Alver, Tiit Trummal, Tarmo Laht, 2000); Lasnamäe spordihoone Tallinnas (Siiri Vallner, Hanno Grossschmidt, Tomomi Hayashi, 2003); TTP büroohoone Tallinnas (Meelis Press, 2005)

  6. Mis kasu sellest kõigest on?

    Index Scriptorium Estoniae

    2004-01-01

    Väljavõtteid mõttevahetusest 19. novembril 2004 toimunud rahvusvahelisel konverentsil "Kohtumine ristteel. Muuseum kui ühiskonna sõlmpunkt". Vestlusringis osalesid Barry Lord Torontost, Tomislav Shola Zagrebist ja Hanno Soans Eestist

  7. Raidpere Veneetsia biennaalile

    Index Scriptorium Estoniae

    2005-01-01

    2005. aastal esindab 51. Veneetsia kunstibiennaalil Eestit fotograaf Mark Raidpere oma väljapanekuga "Varjupaik", mille koostab kunstikriitik Hanno Soans. Kuraatorid Maria Corral (Kunsti kogemus) ja Rosa Martinez (Alati pisut eespool)

  8. Radikaalsus muuseumi kaitsva teki all / Mari Sobolev

    Index Scriptorium Estoniae

    Sobolev, Mari, 1968-

    2004-01-01

    Rotermanni soolalaos avatud Marco (Marko) Laimre isiknäituse "Küsimused ja vastused" puhul 13. IV toimunud konverentsist. Johannes Saare, Eha Komissarovi, Hanno Soansi, Anders Härmi ja Mari Sobolevi ettekannetest

  9. Korpusepoistest / Toomas Hiio

    Index Scriptorium Estoniae

    Hiio, Toomas, 1965-

    2008-01-01

    Rets. rmt.: Tiit Noormets, Toe Nõmm, Hanno Ojalo, Olev Raidla, Eigo Rosenthal, Tõnis Taavet, Mati Õun. Korpusepoisid. Tallinn : Eesti Akadeemiline Sõjaajaloo Selts : Sentinel, 2007. Punaarmee eesti üksustest aastatel 1940-1956.

  10. High efficient photocatalytic activity from nanostructuralized photonic crystal-like p-n coaxial hetero-junction film photocatalyst of Cu3SnS4/TiO2 nanotube arrays

    Science.gov (United States)

    Li, Yan; Liu, Fang-Ting; Chang, Yin; Wang, Jian; Wang, Cheng-Wei

    2017-12-01

    Structuring the materials in the form of photonic crystals is a new strategy for photocatalytic applications. Herein, a new concept of photonic crystal-induced p-n coaxial heterojunction film photocatalyst of Cu3SnS4/TiO2 (CTS/PhC-TNAs) was well-designed and successfully fabricated by combining periodic pulse anodic oxidation and in-situ self-assembling methods Such nanostructured CTS/PhC-TNAs exhibited significantly improved photocatalytic degradation activity under simulated sunlight irradiation with methyl orange (MO) as the target pollutants. Within 120 min, 82% of the MO (10 mg/L) was photodegraded and its kinetic constant per specific surface area reached 0.05332 μmol/m2h, which is 1.6 and 12.8 times more quickly than that of PhC-TNAs and CTS, respectively. Its significantly enhanced photocatalytic activity could be mainly attributed to a joint effect of the unique photonic crystal property of PhC-TNAs and the nanostructured hollow p-n coaxial hetero-junction, which result in an increased efficiency of charge separation and transfer and also an improved spectral response capability. This photonic crystal film photocatalyst has the potential for enhancing the photocatalytic activity via further optimizing the photonic stop band of PhC-TNAs. The study presents a new means to design the kind of photonic crystal structural-induced novel photocatalysts with high photocatalytic activities in pollution treatment.

  11. UV and visible photoluminescence emission intensity of undoped and In-doped ZnO thin film and photoresponsivity of ZnO:In/Si hetero-junction

    International Nuclear Information System (INIS)

    Zebbar, N.; Chabane, L.; Gabouze, N.; Kechouane, M.; Trari, M.; Aida, M.S.; Belhousse, S.; Hadj Larbi, F.

    2016-01-01

    Undoped zinc oxide (ZnO) and indium-doped (ZnO:In) thin films were grown at different temperatures (250–400 °C) on alkali-free borosilicate glass and n-Si (100) substrates by Ultrasonic Spray Pyrolysis method. The structural, compositional, optical and electrical properties of ZnO films were investigated by X-ray diffraction, Scanning Electron Microscopy, Rutherford Back Scattering Spectroscopy, Fourier Transform Infrared spectroscopy, photoluminescence (PL) and the four-point probe technique. The predominance of ultraviolet (UV) and blue emission intensities was found to be closely dependent on the resistivity of the film. The visible emission band (peaking at 432 nm) prevails for low film resistivity, ranging from 10 −2 to 1 Ω·cm. By contrast, for higher resistivity (> 1 Ω·cm), there is a predominance of the UV band (382 nm). The PL and photoresponsivity results of fabricated ZnO:In/n-Si(100) heterojunctions prepared at different temperatures are discussed. The maximum spectral response of the ZnO:8%In/Si heterojunction diode fabricated at 250 °C was about 80 mA/W at zero bias. The highlighted results are attractive for the optoelectronic applications. - Highlights: • Properties of ZnO thin films grown by Ultrasonic Spray Pyrolysis at 350 °C. • Photoluminescence emission intensity in undoped ZnO film: effect of the resistivity • Photoluminescence emission intensity of In-doped ZnO film is resistivity dependent. • The spectral response of ZnO:In/Si hetero-junction deposited in the range (250–400 °C)

  12. UV and visible photoluminescence emission intensity of undoped and In-doped ZnO thin film and photoresponsivity of ZnO:In/Si hetero-junction

    Energy Technology Data Exchange (ETDEWEB)

    Zebbar, N., E-mail: nacbar2003@yahoo.fr [LCMS, Faculty of Physics, University of Sciences and Technology (USTHB), BP 32, El-Alia, Algiers (Algeria); Chabane, L. [LCMS, Faculty of Physics, University of Sciences and Technology (USTHB), BP 32, El-Alia, Algiers (Algeria); Gabouze, N. [CRTSE, 02 Bd. Frantz Fanon, BP 140, Algiers (Algeria); Kechouane, M. [LCMS, Faculty of Physics, University of Sciences and Technology (USTHB), BP 32, El-Alia, Algiers (Algeria); Trari, M. [Laboratory of Storage and Valorization of Renewable Energies, Faculty of Chemistry (USTHB), BP 32, El-Alia, Algiers (Algeria); Aida, M.S. [LCM et Interface, Faculty of Sciences, University of Constantine, 25000 (Algeria); Belhousse, S. [CRTSE, 02 Bd. Frantz Fanon, BP 140, Algiers (Algeria); Hadj Larbi, F. [MEMS & Sensors, Division Microélectronique et Nanotechnologie, Centre de Développement des Technologies Avancées (CDTA), BP 17, Baba Hassen, Algiers (Algeria)

    2016-04-30

    Undoped zinc oxide (ZnO) and indium-doped (ZnO:In) thin films were grown at different temperatures (250–400 °C) on alkali-free borosilicate glass and n-Si (100) substrates by Ultrasonic Spray Pyrolysis method. The structural, compositional, optical and electrical properties of ZnO films were investigated by X-ray diffraction, Scanning Electron Microscopy, Rutherford Back Scattering Spectroscopy, Fourier Transform Infrared spectroscopy, photoluminescence (PL) and the four-point probe technique. The predominance of ultraviolet (UV) and blue emission intensities was found to be closely dependent on the resistivity of the film. The visible emission band (peaking at 432 nm) prevails for low film resistivity, ranging from 10{sup −2} to 1 Ω·cm. By contrast, for higher resistivity (> 1 Ω·cm), there is a predominance of the UV band (382 nm). The PL and photoresponsivity results of fabricated ZnO:In/n-Si(100) heterojunctions prepared at different temperatures are discussed. The maximum spectral response of the ZnO:8%In/Si heterojunction diode fabricated at 250 °C was about 80 mA/W at zero bias. The highlighted results are attractive for the optoelectronic applications. - Highlights: • Properties of ZnO thin films grown by Ultrasonic Spray Pyrolysis at 350 °C. • Photoluminescence emission intensity in undoped ZnO film: effect of the resistivity • Photoluminescence emission intensity of In-doped ZnO film is resistivity dependent. • The spectral response of ZnO:In/Si hetero-junction deposited in the range (250–400 °C)

  13. Effects Of Spontaneous And Piezoelectric Polarization On The Electronic Properties Of AlGaN/GaN Heterostructures

    International Nuclear Information System (INIS)

    Demir, M.

    2010-01-01

    Nitride containing semiconductors and their alloys are used to produce hetero structures where materials with different energy gaps are grown on top of each other so that quantum wells capable of holding free electrons in two dimensions are formed. The carriers in the wells are free to move along the hetero interface but their motion in the direction of growth is restricted. While the density of electron gas depends on the doping concentration and the dimensions of the hetero structure among others, another important parameter that determines the electron density is the spontaneous polarization in the material and piezoelectric polarization near the hetero interface. Polarization is so effective that in some cases it is possible to get electron concentrations as high as 10 1 2-10 1 3 cm - 2 even in the absence of any intentional doping. In this study the electronic properties of an AlGaN/GaN structure is investigated by solving the Poisson/Schroedinger equation self-consistently in the modulation doped hetero structure. The effect of spacer, doping concentration, dimensions of the structure and temperature and especially the spontaneous and piezoelectric polarizations on the electronic properties are investigated.

  14. Theoretical investigation of GaAsBi/GaAsN tunneling field-effect transistors with type-II staggered tunneling junction

    Science.gov (United States)

    Wang, Yibo; Liu, Yan; Han, Genquan; Wang, Hongjuan; Zhang, Chunfu; Zhang, Jincheng; Hao, Yue

    2017-06-01

    We investigate GaAsBi/GaAsN system for the design of type-II staggered hetero tunneling field-effect transistor (hetero-TFET). Strain-symmetrized GaAsBi/GaAsN with effective lattice match to GaAs exhibits a type-II band lineup, and the effective bandgap EG,eff at interface is significantly reduced with the incorporation of Bi and N elements. The band-to-band tunneling (BTBT) rate and drive current of GaAsBi/GaAsN hetero-TFETs are boosted due to the utilizing of the type-II staggered tunneling junction with the reduced EG,eff. Numerical simulation shows that the drive current and subthreshold swing (SS) characteristics of GaAsBi/GaAsN hetero-TFETs are remarkably improved by increasing Bi and N compositions. The dilute content GaAs0.85Bi0.15/GaAs0.92N0.08 staggered hetero-nTFET achieves 7.8 and 550 times higher ION compared to InAs and In0.53Ga0.47As homo-TFETs, respectively, at the supply voltage of 0.3 V. GaAsBi/GaAsN heterostructure is a potential candidate for high performance TFET.

  15. Kes joonistab uue kunstilaine kaardi? / Katrin Kivimaa

    Index Scriptorium Estoniae

    Kivimaa, Katrin, 1969-

    2008-01-01

    Anders Härmi ja Hanno Soansi kureeritud näitusest "Uus laine. 21. sajandi eesti kunstnikud" Tallinna Kunstihoones ja Kunstihoone galeriis ning Non Grata kollektiivnäitusest "Uus laine. 20. sajandi kunst" Kultuuritehases Polymer

  16. Mitte ainult jätistele : fassaadid kodututele / Karin Paulus

    Index Scriptorium Estoniae

    Paulus, Karin, 1975-

    1999-01-01

    Festival 'Backdoor media'99' koondnimetusega 'Fassaadid kodututele' Tallinnas. Andres Kure heliinstallatsioon, performance Tammsaare monumendi juures (kuraator Hanno Soans), Peterburi kunstnike Natalja Jegorova ja Olga Jakimanskaja videod, Silja Saarepuu kerjamiskarbid, Raoul Kurvitza video, samizdat-ajakiri.

  17. "Central Station" Londonis

    Index Scriptorium Estoniae

    2000-01-01

    Londoni galeriis Milch seitsme läti, leedu ja eesti kunstniku projekt "Central Station". Kuraatorid Lisa Panting, Sally Tallant. Eestist osalevad Hanno Soans (Catarina Campinoga koostöös valminud video), Kiwa, Kai Kaljo

  18. Ooperimärkmeid padja kõrvalt, esmajoones Brittenist ja Tulvest / Kristel Pappel

    Index Scriptorium Estoniae

    Pappel, Kristel, 1961-

    2004-01-01

    Helena Tulve kammerooperi "Läheb nii pimedaks" ("It is Getting so Dark") (lavastaja Anu Lamp, videokujundus Tarvo Hanno Varres) ja Benjamin Britteni lühiooperi "Koovitaja jõgi" ("Curlew River") lavastustest Tallinna Linnateatri Taevalaval

  19. Tallinna Rahvaülikool kutsub kõiki uuele algavale kursusele "Kunstikriitikute lemmikud"

    Index Scriptorium Estoniae

    2005-01-01

    Loengusari: 9. II - Eha Komissarov "Popkunstnik Andy Warhol"; 16. III - Anders Härm "Saksa performance'i-kunstnik Joseph Beuys"; 23. III - Hanno Soans "Inglise maali- ja installatsioonikunstnik Martin Creed (sünd. 1968, Wakefield)"

  20. Le nuove frontiere dell'astronomia cosmologia e teoria della relatività generale

    CERN Document Server

    Kaufmann, Willian J

    1980-01-01

    Questa opera costituisce un'introduzione non specialistica, ma aggiornata e chiara all'incredibile numero di recenti scoperte e teorie che hanno riformato - e sconvolto - il nostro modo di pensare sulle stelle e sull'Universo.

  1. Comporre conoscenza: il collage come strategia meta-riflessiva

    Directory of Open Access Journals (Sweden)

    Elisabetta Biffi

    2015-09-01

    Full Text Available Il presente contributo intende riflettere sull’utilizzo di una tecnica artistica, il collage, all’interno della formazione degli insegnanti e degli educatori. Si tratta di una differente modalità di azione da parte dei formatori che è inserita nell’ambito dell’art-based research (McNiff, 2008, e dell’arts-informed research (Cole & Knowles, 2008. Per comprendere in modo approfondito questa scelta è necessario conoscere la nascita di questa tecnica e l’utilizzo che di questa hanno fatto vari artisti. Questo consente di delineare alcuni processi cognitivi riflessivi connessi alla pratica del collage che lo rendono strumento efficace in contesti formativi, soprattutto quando rivolti a insegnanti ed educatori. In chiusura, pertanto, si andranno presentando alcuni esempi di esperienze formative che hanno visto il ricorso al collage come strategia riflessiva.

  2. Camões e Tasso: l’Oriente nel poema eroico

    Directory of Open Access Journals (Sweden)

    Anna Cerbo

    2011-11-01

    Full Text Available Questo contributo si è proposto lo studio della presenza dell’Oriente nel poema epico europeo del Cinquecento. La struttura e l’elaborazione del discorso si sono basate soprattutto sul confronto di due opere: la Gerusalemme liberata di T. Tasso e I Lusiadi di L. de Camões . L’analisi testuale e la metodologia comparatistica hanno portato alla conoscenza storico-ideologica, culturale-letteraria e linguistica dei due poemi, e hanno consentito di rilevare le affinità e le differenze nel rapporto con l’’altro’ e nella rappresentazione dell’‘altro’ da parte dei due Poeti, entrambi attenti allo sguardo incrociato dell’Occidente e dell’Oriente. Tra i risultati conseguiti aggiungiamo che  è stato possibile individuare una comune retorica dell’‘alterità’ nella letteratura europea del Rinascimento.

  3. Primo Levi and Ivan Denisovič: The Literary Act between Representation and Expressive Capacity

    Directory of Open Access Journals (Sweden)

    Pietro Tosco

    2011-11-01

    Full Text Available Se questo è un uomo di Primo Levi e Una giornata di Ivan Denisovič di Aleksandr Solženicyn sono due “atti letterari” che hanno contribuito in modo significativo alla conoscenza storica del XX secolo: il primo nell’Occidente dei campi di concentramento nazisti, il secondo nell’Oriente del Gulag. Perché sono così famosi? C’è qualcosa che li accomuna? Questo saggio si propone di analizzare la forza della letteratura come luogo di conoscenza e autocoscienza. Se le opere di Levi e Solženicyn hanno un grande valore come testimonianze, in esse la forza della testimonianza è data dal “gesto letterario” che le ha create, un gesto che produce una conoscenza sintetica in cui gli universali esistono solo nel particolare.

  4. Cyanide bridged hetero-metallic polymeric complexes: Syntheses, vibrational spectra, thermal analyses and crystal structures of complexes [M(1,2-dmi)2Ni(μ-CN)4]n (M = Zn(II) and Cd(II))

    Science.gov (United States)

    Kürkçüoğlu, Güneş Süheyla; Sayın, Elvan; Şahin, Onur

    2015-12-01

    Two cyanide bridged hetero-metallic complexes of general formula, [M(1,2-dmi)2Ni(μ-CN)4]n (1,2-dmi = 1,2-dimethylimidazole and M = Zn(II) or Cd(II)) have been synthesized and characterized by vibrational (FT-IR and Raman) spectroscopy, single crystal X-ray diffraction, thermal analyses and elemental analyses. The crystallographic analyses reveal that the complexes, [Zn(1,2-dmi)2Ni(μ-CN)4] (1) and [Cd(1,2-dmi)2Ni(μ-CN)4] (2), have polymeric 2D networks. In the complexes, four cyanide groups of [Ni(CN)4]2- coordinated to the adjacent M(II) ions and distorted octahedral geometries of complexes are completed by two nitrogen atoms of trans 1,2-dmi ligands. The structures of 1 and 2 are similar and linked via intermolecular hydrogen bonding, C-H⋯Ni interactions to give rise to 3D networks. Vibration assignments are given for all the observed bands and the spectral features also supported to the crystal structures of heteronuclear complexes. The FT-IR and Raman spectra of the complexes are very much consistent with the structural data presented.

  5. Pärnu Kontserdimaja : Pärnu, Aida tn. 4 / Katrin Koov

    Index Scriptorium Estoniae

    Koov, Katrin, 1973-

    2003-01-01

    Projekteerija: COO Arhitektid. Arhitektid-sisekujundajad Hanno Grossschmidt, Kaire Nõmm, Katrin Koov. Konstruktor: Inseneribüroo Pike OÜ. Projekt: jaanuar 2002, valmis: november 2002. I ja II korruse plaan, 2 välis- ja 3 sisevaadet

  6. 51. Veneetsia kunstibiennaalil esindab Eestit kunstnik Mark Raidpere...

    Index Scriptorium Estoniae

    2005-01-01

    Mark Raidpere ekspositsiooni "Varjupaik" on koostanud Hanno Soans. 12. VI-6. XI avatud biennaalil on kaks peakuraatorit ja kaks teemanäitust: Maria de Corrali kureeritud "Kunsti kogemus" ja Rosa Martinezi kureeritud "Alati pisut eespool"

  7. 24. IV avati Tartu Kunstimajas...

    Index Scriptorium Estoniae

    2003-01-01

    Vallo Kalamehe ja Peeter Linnapi kureeritud fotonäitus "XXL. Eesti fotoklassika". Osalevad Herkki-Erich Merila, Tarvo Hanno Varres, Peeter Laurits, Toomas Kalve, P. Linnap, V. Kalamees, Malev Toom, Madis Palm, Tõnu Tamm, Meelis Lokk

  8. Lasnamäe uus spordihoone on teistmoodi kast / Triin Ojari

    Index Scriptorium Estoniae

    Ojari, Triin, 1974-

    2004-01-01

    Siiri Vallneri ja Hanno Grossschmidti (kaasautoriks Tomomi Hayashi) Punasele tänavale projekteeritud kergejõustikuhalli arhitektuurist, ruumilahendusest, sobivusest ümbritsevasse miljöösse. Detailplaneeringu tegi ja peatöövõttu korraldas Rein Murula

  9. Kes joonistab uue kunstilaine kaardi? / Katrin Kivimaa

    Index Scriptorium Estoniae

    Kivimaa, Katrin, 1969-

    2007-01-01

    Eesti noorema kunsti näitus "Uus laine. 21. sajandi eesti kunstnikud" (kuraatorid Anders Härm, Hanno Soans) Tallinna Kunstihoones ja Kunstihoone galeriis. Non Grata kollektiivnäitus "Uus laine. 20. sajandi kunst" Kultuuritehases Polymer

  10. Molecular dynamics simulation of effects of twin interfaces on Cu/Ni multilayers

    International Nuclear Information System (INIS)

    Fu, Tao; Peng, Xianghe; Weng, Shayuan; Zhao, Yinbo; Gao, Fengshan; Deng, Lijun; Wang, Zhongchang

    2016-01-01

    We perform molecular dynamics simulation of the indentation on pure Cu and Ni films and Cu/Ni multilayered films with a cylindrical indenter, aimed to investigate the effects of the cubic-on-cubic interface and hetero-twin interface on their mechanical properties. We also investigate systematically the formation of twin boundary in the pure metals and the effects of the cubic-on-cubic and hetero-twin interface on mechanical properties of the multilayers. We find that the slip of the horizontal stacking fault can release the internal stress, resulting in insignificant strengthening. The change in the crystal orientation by horizontal movement of the atoms in a layer-by-layer manner is found to initiate the movement of twin boundary, and the hetero-twin interface is beneficial to the hardening of multilayers. Moreover, we also find that increasing number of hetero-twin interfaces can harden the Cu/Ni multilayers.

  11. 'Kunstniku nutt' Portugalis

    Index Scriptorium Estoniae

    1999-01-01

    5. juunil Portugalis Museu de Ceramica das Caldas da Rainhas avataval grupinäitusel 'Artist's Cry' eksponeerib Hanno Soans oma videot 'Private Dancer', mis on tehtud koos Catarina Campinoga Portugalist. Näituse kuraator Kestutis Kuizinas Leedust

  12. Vaimne dotatsioon meediaikaldusele / Mari Sobolev

    Index Scriptorium Estoniae

    Sobolev, Mari, 1968-

    1998-01-01

    Seoses Eesti Kunstimuuseumis toimunud näitusega "Medialization" 22.-23. nov. Eesti Kunstiakadeemias korraldatud meediakonverentsist 'Action ئ Reflection'. Korraldaja Ando Keskküla. Eric Kluitenbergi (Holland), Tapio Mäkela (Soome) ja Hanno Soansi ettekannetest. Avatud kanalist.

  13. Eesti foto Londonis teeb meist "kuuma" riigi / Maris Lillak, Ann Alari

    Index Scriptorium Estoniae

    Lillak, Maris, 1970-

    2004-01-01

    Westminsteri parlamendihoones eesti fotonäitus "Similar Spaces" (Sarnased kohad - värsked fotod Eestist). Eksponeeritud Ly Lestbergi, Tarvo Hanno Varrese, Mare Tralla, Mark Raidpere, Raoul Kurvitza, Liina Siibi tööd. Kuraator Liina Siib

  14. Pärnu Kontserdimaja arhitektuurikonkurss = Architectural Competition of Pärnu Concert Hall / Martti Preem

    Index Scriptorium Estoniae

    Preem, Martti, 1949-

    2001-01-01

    Asukohavalikust, premeeritud ja äramärgitud töödest. Konkursi tulemused: I preemia - Hanno Grossschmidt, Katrin Koov, Kaire Nõmm, Üla Koppel; II - Indrek Erm, Emil Urbel; III - Kalle Komissarov, Andres Ojari. 21 ill.

  15. Prospettive della reazione di idroformilazione nella sintesi di composti biologicamente attivi

    OpenAIRE

    Marchetti, Mauro

    2000-01-01

    Il nostro gruppo sta conducendo uno studio su complessi di rodio con una nuova classe di leganti idrosolubili di origine proteica, tali complessi impiegati nell’idroformilazione bifasica in solvente acquoso di diversi substrati hanno fornito buoni risultati.

  16. Disturbi mentali come complex network : Un’ introduzione e una panoramica all’ approccio network in psicopatologia

    NARCIS (Netherlands)

    Nuijten, M.B.; Deserno, Marie K.; Cramer, A.O.J.; Costantini, Giulio; Borsboom, Denny

    2016-01-01

    I disturbi mentali sono stati tradizionalmente concepiti come variabili latenti, che hanno un impatto sulla sintomatologia osservabile. Approcci alternativi proposti più recentemente invece concepiscono i disturbi mentali come sistemi di sintomi che si rinforzano vicendevolmente. Tali approcci

  17. Mis on looming.org? : elektrooniline heli / Andres Lõo

    Index Scriptorium Estoniae

    Lõo, Andres

    2004-01-01

    Võrguajakirjast www.looming.org, kuhu kogutakse infot põhiliselt kahe jaotuse põhjal: muusika ja helieksperimentalism ning kaasaegne kunst, kunsti ja meediaga seonduv. Idee autorid: Hanno Soans ja Andres Lõo. Ilmunud on looming.orgi esimene muusikakogumik "Lilled algebrale"

  18. Swiss Property kontor = Offices of Swiss Property / kommenteerinud Tõnis Sõõrumaa

    Index Scriptorium Estoniae

    2015-01-01

    Swiss Property kontoriruumid Tallinnas Rotermanni 8. Sisekujunduse autorid Kätlin Ölluk, Tiina Kesküla, Katy Seppel, Aet Kiivet, Liina Rohtlaan, Marita Mätas, Lilian Esing, Kristin Boginski (Swiss Property); arhitektid Yoko Azukawa, Hanno Grossschmidt, Tomomi Hayashi

  19. Attivita sismica in italia dal 1953 al 1957

    Directory of Open Access Journals (Sweden)

    M. De Panfilis

    1959-06-01

    Full Text Available molto notevole. In tale periodo, le scosse sismiche di cui abbiamo potutoavere sicura notizia, comprese quelle di leggera e leggerissima intensitàe le repliche dei sismi più importanti, hanno superato di poco il numerodi 400. Invece tale attività si deve considerare piuttosto elevata neiriguardi dell'intensità, poiché 160 delle scosse predette hanno superatoil IV grado della Scala Mercalli. Due di esse, anzi, l'una avvenuta nelGargano nel febbraio 1955 e l'altra nei Monti Volsini, a nord del Lago diBolsena, nel dicembre 1957, raggiunsero nella zona epicentrale un'intensitàquasi rovinosa, fortunatamente senza vittime, ma con danniingenti ai fabbricati.Assai diversamente, poi, si è distribuita l'attività sismica nei singolianni del quinquennio. La minima si è avuta nel 1954 con un totale di52 scosse e la massima

  20. La tracciabilità della filiera vitivinicola: dal sistema di cantina alla gestione completa dell’azienda vitivinicola con strumenti GIS-Oriented

    Directory of Open Access Journals (Sweden)

    Luigi Rosadini

    2013-03-01

    Full Text Available Nell’ultimo decennio le aziende Agrarie e Vitivinicole in particolare hanno visto aumentare in maniera considerevole le difficoltà di mercato ed al contempo hanno registrato una maturità e sensibilità da parte del consumatore. Questo nuovo contesto ha fatto sì che le esigenze di automazione, informatizzazione e relativa tracciabilità di prodotto sifacessero più pressanti e dettagliate, tanto da richiedere lo sviluppo di veri e propri Sistemi Informativi di Cantina eGIS agrario-vitivinicoli anche partendo da una analisi e un relativo approccio geospaziale delle problematiche presenti.AbstractThe new context of agricultural and wine-devoted farm duringlast decades has brought to the needs of automation, computerizationand traceability of its product, requiring the developmentof real Information Systems as a GIS agrarian wine cellar,starting from an analysis and the approach to the geospatialissues. 

  1. he ‘Fabulous Dragon’s Teeth’: Censorship and Self-Censorship in the Italian Translation of Paradise Lost

    Directory of Open Access Journals (Sweden)

    Daniele Borgogni

    2015-05-01

    Full Text Available Il presente contributo discute le molteplici prassi che, sotto forma di espurgazioni religiose, adattamenti neoclassici, mutilazioni stilistiche, hanno caratterizzato le traduzioni italiane del Paradise Lost di John Milton. La difficoltà nell’accettare  l’eterodossia stilistica e religiosa del grande poeta inglese ha tradizionalmente favorito una serie di versioni infarcite di “migliorie” che hanno  offuscato o travisato il testo miltoniano anche in tempi recenti. Il contributo discute in dettaglio l’atteggiamento idiosincratico nei confronti di Milton e del suo capolavoro, nonché i pregiudizi, le pratiche di autocensura e le strategie più o meno vincenti adottate dai traduttori. La traduzione viene dunque utilizzata  come indice culturale ampio, strumento di indagine privilegiato in quanto fisiologicamente legata a pratiche di censura, ri-creazione e ri-mediazione dell’oggetto letterario nel suo passaggio tra sistemi culturali diversi.

  2. Kas alternatiivid mainstreamil või alternatiivne mainstream? / Reet Varblane

    Index Scriptorium Estoniae

    Varblane, Reet, 1952-

    1998-01-01

    Missugune on praeguste eesti noorte sub- ja kontrakultuur? Samasuguseid laineid on enne olnud, näiteks Lapin-Okas-Keskküla, Eve ja Peeter Linnap & jüngrid. Hanno Soansi kutse väljuda galeriidest ja mõjutama olmet.

  3. Camillo Faverzani (éditeur), Part[h]enope. Naples et les arts / Napoli ...

    African Journals Online (AJOL)

    User

    arte e della storia hanno il loro teatro di elezione, è facile pronosticare al mito di Partenope, affascinante e ingombrante, attraente e irritante, un lungo futuro. Franco Arato. (Università di Torino). Paolo Sortino, Elisabeth, Torino, Einaudi, 2011, ...

  4. Paolo Sortino, Elisabeth, Torino, Einaudi, 2011, pp. 216.

    African Journals Online (AJOL)

    User

    arte e della storia hanno il loro teatro di elezione, è facile pronosticare al mito di Partenope, affascinante e ingombrante, attraente e irritante, un lungo futuro. Franco Arato. (Università di Torino). Paolo Sortino, Elisabeth, Torino, Einaudi, 2011, ...

  5. Analogovoje TV na digitalnoi osnove. Barokko i gotika kak obraztsõ roskoshi / Ilja Sundelevitsh

    Index Scriptorium Estoniae

    Sundelevitsh, Ilja

    2003-01-01

    Anders Härmi ja Hanno Soansi kuraatoriprojektist "Skriinseiver" Tallinna Kunstihoones. Peale Härmi ja Soansi tööde on vaatluse all ka Marko Laimre installatsioon. G-galeriis on Kaie Partsi ehted ja Hille Palmi skulptuurid ühisnäitusel "Luksus"

  6. "Backdoor" kunstnikku testimas / Rael Artel

    Index Scriptorium Estoniae

    Artel, Rael, 1980-

    1999-01-01

    Festival "Backdoor media'99" alapealkirjaga 'Fassaadid kodututele' Tallinnas. Performance Tammsaare monumendi juures (kuraator Hanno Soans), Silja Saarepuu video kerjamiskarpidest, Andrus Kõresaare ja Jouni Partaneni videod kerjustest, Marko Raadi dokumentaalfilm 'Esteetilistel põhjustel' (peaosas Andres Kurg), tekstikogumik ehk samizdat (toimetaja Katrin Kivimaa).

  7. Dal caos... alla coscienza

    CERN Document Server

    Prattico, Franco

    1989-01-01

    Attraverso i domini della fisica, della genetica e della biologia, fino alle neuroscienze, alla ricerca dei percorsi che hanno portato alla nascita del cervello umano : frutto di una singolare serie casuale o di una necessità inscritta nelle leggi del Cosmo?

  8. Baltic Landscapes : Festival of Images from Baltics

    Index Scriptorium Estoniae

    2000-01-01

    Hanno Soans eesti projektist "Analogue TV" N.E.W.S. (north-east-west-süd) seminaril. Eesti videoprogramm näitusel "Baltic Landscapes" (kunstnikud A. Maimik, K. Kaljo, E-L. Semper, M. Raat, M. Laanemets, K. Sukmit, J. Zoova) Bornholmis

  9. Towards a national system of teaching qualifications in higher education in The Netherlands

    NARCIS (Netherlands)

    van Keulen, H.; van Alst, J.; de Jong, R.; Halma, A.

    2006-01-01

    2005 6th Conference of the International Consortium for Educational Development Enhancing Academic Development Practice: International Perspectives 1. Contact Name: Hanno van Keulen 2. Title: Dr 3. Institution(s): Utrecht University 4. Department: IVLOS Institute of Education 5. Address for

  10. Avenüüle tõi edu kindla nishi hoidmine / Merike Reino ; interv. Eda-Liis Kann

    Index Scriptorium Estoniae

    Reino, Merike

    2005-01-01

    Ajakirja Avenüü tegevjuht ajakirja käibe kasvust, laienemisest Lätisse, konkurentsist Eestis ja Lätis, allahindlustest reklaamiklientidele. Kommenteerib Media House'i juht Hanno Kindel. Tabel: Ajakirjade reklaamikäibe TOP 10. Vt. samas: Kroonika on ajakirjade lipulaev

  11. WHO: haigekassa vajab lisaraha / Kadri Ibrus

    Index Scriptorium Estoniae

    Ibrus, Kadri

    2010-01-01

    Haigekassa, sotsiaalministeeriumi ja WHO koostöös valminud aruande "Võimalused Eesti tervisesüsteemi rahastamise jätkusuutlikkuse tagamiseks" kohaselt ei ole Eesti tervishoiu rahastamise süsteem kaugemas perspektiivis elujõuline. WHO soovitustest Eestile. Sotsiaalminister Hanno Pevkuri seisukoht

  12. Festival, mis kodustas linnakeskkonna / Heie Treier

    Index Scriptorium Estoniae

    Treier, Heie, 1963-

    1998-01-01

    7.-8. nov. toimunud Tallinna linnakultuuri festivalist 'Backdoor Media'. Kunstiakadeemias toimunud ürituste kuraator Hanno Soans. Seal linastunud Mari Sobolevi ja tema 'kogukonna' road-movie'st. Peeter Linnapi videoloeng kunstnikust kui kriitilisest institutsioonist. Raoul Kurvitza etteaste alternatiivsest raharinglusest (loeng, video).

  13. Tselluloidi aura ja kaasaegne kunst / Hanno Soans

    Index Scriptorium Estoniae

    Soans, Hanno, 1974-

    2004-01-01

    Muutustest filmitegemises ja filmiesteetikas. Filmi sarnanemisest tehniliselt üha enam videoga. Kunstnike tegelemisest filmiga. 26. XI näeb kinos "Sõprus" "1+1=1" raames kaasaegsete kunstnike teoseid laiekraanil: Eija-Liisa Ahtila "If 6 was 9" (1995), "Today" (1996-97), "Consolation Service" (1999); Sara Lunden ja Henry Moore Selder (sünd. 1973, Stockholm) "Deadly Boring" (2001), "She is Dead" (2003)

  14. Efficiency of a new strategy involving a new class of natural hetero-ligand iron(III) chelates (Fe(III)-NHL) to improve fruit tree growth in alkaline/calcareous soils.

    Science.gov (United States)

    Fuentes, Marta; Ortuño, María F; Pérez-Sarmiento, Francisco; Bacaicoa, Eva; Baigorri, Roberto; Conejero, Wenceslao; Torrecillas, Arturo; García-Mina, José M

    2012-12-01

    Iron (Fe) chlorosis is a serious problem affecting the yield and quality of numerous crops and fruit trees cultivated in alkaline/calcareous soils. This paper describes the efficiency of a new class of natural hetero-ligand Fe(III) chelates (Fe-NHL) to provide available Fe for chlorotic lemon trees grown in alkaline/calcareous soils. These chelates involve the participation in the reaction system of a partially humified lignin-based natural polymer and citric acid. First results showed that Fe-NHL was adsorbed on the soil matrix while maintaining available Fe for plants in alkaline/calcareous solution. The effects of using three different sources as Fe fertilisers were also compared: two Fe-NHL formulations (NHL1, containing 100% of Fe as Fe-NHL, and NHL2, containing 80% of Fe as Fe-NHL and 20% of Fe as Fe-ethylenediamine-N,N'-bis-(o-hydroxyphenylacetic) acid (Fe-EDDHA)) and Fe-EDDHA. Both Fe-NHL formulations increased fruit yield without negative effects on fruit quality in comparison with Fe-EDDHA. In the absence of the Fe-starter fraction (NHL1), trees seemed to optimise Fe assimilation and translocation from Fe-NHL, directing it to those parts of the plant more involved in development. The field assays confirmed that Fe-NHL-based fertilisers are able to provide Fe to chlorotic trees, with results comparable to Fe-EDDHA. Besides, this would imply a more sustainable and less expensive remediation than synthetic chelates. Copyright © 2012 Society of Chemical Industry.

  15. Journal of Chemical Sciences | Indian Academy of Sciences

    Indian Academy of Sciences (India)

    An intramolecular charge transfer (ICT) molecule with an extra hetero atom in its donor moiety has been synthesized in order to investigate how ICT reaction is affected by hetero atom replacement. Photo-physical and photo-dynamical properties of this molecule, 4-(morpholenyl)benzonitrile (M6C), have been studied in 20 ...

  16. Report on the research achievements in the Sunshine Project in fiscal 1990. Studies on coal liquefying reaction, and reforming and utilization of the products; 1990 nendo sekitan no ekika hanno to seiseibutsu no kaishitsu riyo no kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-03-01

    This paper describes the achievements in the Sunshine Project in fiscal 1990 on research of coal liquefying reaction. The research contributes to developing a coal liquefaction technology as one of the methods for manufacturing clean energy and chemical raw materials from coal. In the fundamental study on the liquefaction, primarily liquefied heavy constituents in different types of coals were divided into such constituents as HI, TI, and THFI to discuss the performance and coking behavior of each constituent as solvent. Furthermore, effects of hydrogenation treatment were also elucidated. Decomposing reaction was performed on different heavy products to discuss effects of the reaction conditions. In the liquefying reaction using petroleum-based heavy oil as solvent, different shale oils were used in experiments for comparison with the case of using tar sand bitumen. In the study of reforming the product, comparison was carried out on reactions in hydrogenation treatment and contact decomposition of medium to heavy fractions of liquefied oil. A separation experiment was made on hetero compounds by means of solvent extraction and pressure crystallization of liquefied oil naphtha and light oil fraction. Effects of additive were investigated in an engine test on the stabilized and balanced light oil fraction. Discussions were given on high level utilization of heat treated oil recovered from residues in liquefaction distillation. (NEDO)

  17. Tundlikkuse test Moskvas / Mari Laanemets

    Index Scriptorium Estoniae

    Laanemets, Mari, 1975-

    1998-01-01

    Näitus "Meeled : testimise jaam" Moskvas. Üldkontseptsiooni autor- Georgi Nikitsh. Eesti kuraator Hanno Soans. Eesti väljapanekust (J. Toomiku, U. Rausi, S. Saagi maalid, R. Kurvitza installatsioon nõgestega, T. Miku "Stick Off One Eye, Black Uhuru ja teised hobused").

  18. Tallinna Kunstihoones on skriinseiver

    Index Scriptorium Estoniae

    2003-01-01

    21. II-16. III eesti-läti-leedu-inglise ühisprojekt "Skriinseiver". Projekti eesotsas on kuraatorid Anders Härm, Hanno Soans ja troubleproduction. Esinevad Eriks Bozhis (Läti), Darius Mikshys (Leedu), John Frankland (Inglismaa), troubleproductions, ESTO TV ja 11 osalejat Eestist

  19. Immigrazione Senegalese in Italia: stato dell¿arte

    NARCIS (Netherlands)

    G. Sinatti (Giulia)

    2007-01-01

    textabstractÈ trascorso ormai circa un trentennio da quando i primi immigrati senegalesi giungevano in Italia nella seconda metà degli anni Ottanta. Nel corso di questi tre decenni, essi hanno stabilmente rappresentato la presenza straniera più significativa in provenienza dall’Africa

  20. Dal laboratorio all’impresa: l’economia sperimentale

    NARCIS (Netherlands)

    Bucciol, A.; Maggian, V.; Montinari, N.; Piovesan, M.

    2010-01-01

    I recenti contributi della psicologia cognitiva e della neurobiologia hanno permesso di scrivere modelli economici più aderenti alla realtà disegnando regole e istituzioni più efficaci. Grazie ai contributi dell’economia comportamentale e sperimentale, concetti come tentazioni e problemi di

  1. Indagine su un primo cittadino al di sopra di ogni sospetto. Renato Accorinti performer

    Directory of Open Access Journals (Sweden)

    Katia Trifiro'

    2014-05-01

    Lo studio, condotto all’insegna dei Performance Studies di impostazione schechneriana, si propone di interpretare, attraverso l’analisi dei comportamenti di Accorinti performer, alcuni dispositivi tipici delle forze antagoniste nel momento in cui, in tempi recenti, hanno assunto o assumono posizioni di potere.

  2. Karm tegelikkus: kuu sissetulek 1000 krooni / Dannar Leitmaa

    Index Scriptorium Estoniae

    Leitmaa, Dannar, 1982-

    2010-01-01

    Tallinna tervishoiu- ja sotsiaalameti hoolekandeosakonna peaspetsialisti Ljudmilla Leiuse hinnangul on toimetuleku piir ajale jalgu jäänud. Tallinnas on toimetulekutoetust saavate perede hulk kasvanud aastaga mitu korda. Sotsiaalminister Hanno Pevkuri sõnul on toimetulekupiiri tõstmise eelduseks eelarveliste vahendite olemasolu. Graafik, diagramm

  3. Arhitektuurikonkurss õnnestus / Tiia-Helle Schmitte

    Index Scriptorium Estoniae

    Schmitte, Tiia-Helle

    2005-01-01

    Arhitektuurivõistlusest, mille eesmärgiks oli saada parim lahendus Mahtra talurahvamuuseumi kaasajastamiseks ja laiendamiseks. Žürii (osalejad loetletud) tunnistas parimaks Tomomi Hayashi ja Hanno Grossschmidti (HG Arhitektuur) võistlustöö. Näitus konkursitöödest oli vaadata muuseumis

  4. Stekljannaja litshina Narvskogo shosse / Viktoria Panova

    Index Scriptorium Estoniae

    Panova, Viktoria

    2005-01-01

    Tallinna Hobujaama tänavale ehitatavast hoonetekompleksist Forum. Arhitekt Hanno Grossschmidt (HG Arhitektuur) ja Narva mnt. 7 büroohoone renoveerimisest arhitektuuribüroo Künnapu ja Padrik poolt. Hoonele, mis saab nimeks Triumpf Plaza, ehitatakse kolm torni ja kolm korrust muudetakse korteriteks

  5. Kui ma oleksin rahvas... / Jürgen Rooste

    Index Scriptorium Estoniae

    Rooste, Jürgen, 1979-

    2007-01-01

    Anders Härmi kuraatorinäitus "Poliitiline/Poeetiline" Tallinna IV graafikatriennaali raames Tallinna Kunstihoones kuni 25. XI. Abel Abidini, Michael Baersi, Johansoni ja Johansoni, Jakob Koldingu, Teemu Mäki, Dan Perjovschi, Hanno Soansi ning Aleksandr Breneri & Barbara Schurzi töödest

  6. L’e-tutor in Italia: una rassegna della letteratura scientifica

    Directory of Open Access Journals (Sweden)

    Veronica Mattana

    2014-04-01

    Full Text Available Il lavoro propone una rassegna della letteratura scientifica italiana, condotta analizzando i contributi apparsi su riviste specializzate o su atti di convegni/congressi nel campo dell’apprendimento con le ICT. Sono stati selezionati dieci lavori, pubblicati tra il 2006 e il 2013, che hanno trattato la figura dell’e-tutor nei diversi contesti formativi italiani (università, scuola, Pubblica Amministrazione, e che hanno fornito evidenze empiriche su ruoli, funzioni e competenze, nonché sulle modalità di selezione, formazione e valutazione. Le analisi condotte sono state sia di tipo quantitativo (mediante questionari e successive elaborazioni statistiche sia qualitative (analisi del contenuto dei messaggi su forum di discussione. Risultano ancora pochi i contributi scientifici sull’e-tutor, a causa, come sottolineato da diversi autori, della difficoltà di realizzazione di ricerche empiriche o sperimentali. Vengono discussi limiti e alcuni spunti per le future ricerche.

  7. Feeling Ashamed of Myself Because of You

    DEFF Research Database (Denmark)

    Montes Sanchez, Alba; Salice, Alessandro

    2017-01-01

    the phenomenological credentials of what might be called ‘hetero-induced shame’ and to resist possible attempts to reduce its specificity. The second goal is to show how the standard account of shame as self-directed can be made hospitable to cases of hetero-induced shame. We argue that a promising way to do...

  8. Intrinsic Rashba-like splitting in asymmetric Bi{sub 2}Te{sub 3}/Sb{sub 2}Te{sub 3} heterogeneous topological insulator films

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Xiaofei; Guo, Wanlin, E-mail: wlguo@nuaa.edu.cn [State Key Laboratory of Mechanics and Control for Mechanical Structures and Key Laboratory for Intelligent Nano Materials and Devices (MOE), Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China)

    2014-08-25

    We show by density functional theory calculations that asymmetric hetero-stacking of Bi{sub 2}Te{sub 3}/Sb{sub 2}Te{sub 3} films can modulate the topological surface states. Due to the structure inversion asymmetry, an intrinsic Rashba-like splitting of the conical surface bands is aroused. While such splitting in homogeneous Bi{sub 2}Te{sub 3}-class topological insulators can be realized in films with more than three quintuple layers under external electric fields, the hetero-stacking breaks the limit of thickness for preserving the topological nature into the thinnest two quintuple layers. These results indicate that the hetero-stacking can serve as an efficient strategy for spin-resolved band engineering of topological insulators.

  9. ‘The political deadlock is life’: Boris and the satire of contemporary Italian media and cultural industries

    Directory of Open Access Journals (Sweden)

    Giacomo Boitani

    2014-12-01

    Full Text Available ‘Il pareggio elettorale è la vita’: Boris e la satira dei mass media italiani e dell’industria culturale odierni  Nel 2007 il network satellitare Fox Italia ha cominciato la produzione di Boris, una serie comica del genere mockumentary messa in onda sui canali Sky Italia dal 2007 al 2010. La trama di Boris narra le peripezie di una troupe televisiva alle prese con la produzione di una soap-opera per la RAI. In Italia la serie è presto diventata un prodotto ‘cult’. Nella serie Boris i pigri e opportunisti membri della troupe televisiva fittizia sono rappresentati come succubi delle ripercussioni che gli sviluppi politici nel Paese hanno sul servile network per il quale lavorano. Gli attori nella soap-opera fittizia vengono rimpiazzati e la trama stessa della soap-opera viene riscritta a seconda delle nuove coalizioni che vengono formate in Parlamento e i membri della troupe sono costantemente alla ricerca di raccomandazioni e protezione politica. Per quanto satirizza lo stato del Paese, Boris mette anche in discussione il fatto stesso che l’industria culturale Italiana corrente possa produrre un discorso significativo. Con riferimento alla teorizzazione della ‘parodia’ da parte di Linda Hutcheon, questo articolo discute la rappresentazione che Boris ha tratteggiato dell’industria culturale, analizza il rapporto esistente tra la serie e tradizioni comiche Italiane che l’hanno preceduta (la ‘commedia all’italiana’ e il modo in cui l’ironia implementata dalla serie ricalca e/o diverge da quella tipica delle serie mockumentary estere che l’hanno ispirata (Arrested Development e The Larry Sanders Show.

  10. Digital Games as Tools for Stimulating and Assessing Reasoning Skills

    Directory of Open Access Journals (Sweden)

    Rosa Maria Bottino

    2016-04-01

    Full Text Available This paper offers some thoughts on the use of educational digital logic games. Specifically refers to a number of research experiments conducted by ITD-CNR, which have highlighted the significant potential of digital games to help develop and/or consolidation of logical thinking and reasoning skills in students of primary and secondary school level. It offers a brief overview of four research experiences carried out by multidisciplinary teams coordinated by ITD-CNR since the early 2000s These experiences have highlighted the high potential of digital games to develop and strengthen logical thinking skills and have shown the positive impact of their use even on school performance. Verificare e stimolare le abilità di ragionamento con i giochi digitaliQuesto contributo propone alcune riflessioni sull’uso educativo dei giochi logici digitali. In particolare fa riferimento ad alcune esperienze di ricerca condotte dall’Istituto di Tecnologie Didattiche - Consiglio Nazionale delle Ricerche (ITD-CNR che hanno evidenziato le interessanti potenzialità dei giochi digitali per contribuire allo sviluppo e/o al consolidamento del pensiero logico e delle abilità di ragionamento in studenti di scuola primaria e secondaria di primo grado. Si propone un breve excursus su quattro esperienze di ricerca svolte da equipe multidisciplinari coordinate da ITD-CNR a partire dai primi anni Duemila. Tali esperienze hanno messo in luce l’alto potenziale dei giochi digitali per sviluppare e potenziare abilità di pensiero logico ed hanno evidenziato il positivo impatto del loro uso anche sul rendimento scolastico.

  11. Programmable gaming environments for four year olds

    OpenAIRE

    Edith K. Ackermann

    2002-01-01

    Apprendere a programmare alla scuola dell'infanzia? Perche'? Che cosa ci puo' essere di interessante in questo per un bambino? Che cosa si puo' imparare? Questo articolo e' rivolto ai ricercatori, ai progettisti, agli educatori e ai genitori; tutti questi hanno buone ragioni per interrogarsi.

  12. Omas mahlas / Raineras Vilumaa

    Index Scriptorium Estoniae

    Vilumaa, Raineras

    2004-01-01

    Leedu kaasaegse kunsti näitus "Omas mahlas" Tallinna Kunstihoones kuni 11. VII ja Rotermanni soolalaos kuni 8. VIII. Kuraatorid Anders Härm, Eha Komissarov ja Hanno Soans. 26. VI esitlesid kunstnikud Arturas Bumshteinas, Laura Garbshtiene (G-Lab) ja helilooja Antanas Jasenka oma heliinstallatsioone

  13. Riigikontrolli audit paljastab Natura-alade segaduse / Ulvar Käärt

    Index Scriptorium Estoniae

    Käärt, Ulvar, 1982-

    2008-01-01

    Riigikontrolli audit näitab, et Natura 2000 kaitsealade hulka on arvatud ka väheväärtuslikke metsaalasid, samas on välja jäetud kaitset väärivaid elupaiku. Keskkonnaministeeriumi nõuniku Hanno Zingeli selgitusi. Lisa: Paljud taluvad asjata piiranguid

  14. Momenti nella vita di uno scienziato

    CERN Document Server

    Rossi, Bruno

    1987-01-01

    Nel giro di pochi decenni, la nostra visione del mondo fisico, dal mond subatomico al mondo del cosmo, ha subito una profonda evoluzione. In questo libro, uno degli scienziati che hanno contribuito a tale sviluppo narra la storia della sua vita e del suo lavoro.

  15. Elektrokardiogramm : tekstivabriku töötulemused / Mari Laanemets

    Index Scriptorium Estoniae

    Laanemets, Mari, 1975-

    1998-01-01

    "Elektrokardiogramm" Eesti Kunstimuuseumi filiaalis Rotermanni soolalaos 3. ja 4. märtsil. EKG seadis keskmesse protsessi : tegevusmaali ja performance'id, arvutite taga töötasid tekstitöölised, kes pidid looma kunstitegevusele analoogi omamoodi actionkirjutamisega. Osalejatest. Kodanlikust maitsest, kodanlikust kunstist. Kuraator Hanno Soans.

  16. Raoul Kurvitz soovitab: Stalkeri monumendi etendused

    Index Scriptorium Estoniae

    2011-01-01

    Rotermanni kvartalisse kohta, kus filmiti Andrei Tarkovski "Stalker", on kavas rajada Stalkerile pühendatud monument, mille autor on Raoul Kurvitz. Monumendi rajamise idee pärineb projekti kaasautorilt Tarvo Hanno Varreselt. 10., 11., 17., 18., 23. ja 24. septembril toimuvad monumenti tutvustavad performance'id

  17. apprendere una lingua straniera: tempo e spazio nella cultura italiana

    African Journals Online (AJOL)

    User

    partecipazione al programma Erasmus/Socrates, 1 che prevede programmi integrati di insegnamento tra le Università partecipanti e un sistema di riconoscimento reciproco delle attività svolte attraverso l'assegnazione di crediti. Dall'altra, hanno il compito di coordinare maggiormente la formazione universitaria in relazione ...

  18. La crisi energetica nel mondo e in Italia da Enrico Fermi ed Edoardo Amaldi a oggi

    CERN Document Server

    Salvini, Giorgio

    2007-01-01

    Enrico Fermi e il suo allievo Edoardo Amaldi, grandi padri della Scuola di fisica nucleare italiana, hanno promosso l'impiego pacifico dell'energia nucleare: Fermi con il primo reattore a Chicago nel 1942, Arnaldi con i suoi contributi a tutti gli usi pacifici, dalla medicina alla produzione di energia. L'Italia, però, ha fatto eccessivo ricorso al petrolio, di cui non è produttrice. La ricerca è rimasta molto indietro rispetto a quella degli altri paesi e la politica sta dedicando pochissimi sforzi a questa gravissima situazione. Ragioni economiche, nonché ambientali, esigono ora una revisione e una ricontestualizzazione del problema. Durante un importante Convegno, tenutosi a Roma il 15 e 16 maggio 2007, alcuni tra i più noti ed esperti fisici italiani e stranieri hanno discusso proprio di questo problema. L'intento del volume, che raccoglie gli interventi del Convegno romano, è quello di fornire dati e informazioni che mettano il lettore in condizione di farsi un'idea propria, libera da pregiudizi, s...

  19. Fisica e filosofia come la scienza contemporanea ha modificato il pensiero dell'uomo

    CERN Document Server

    Heisenberg, Werner

    2003-01-01

    Nel corso del Novecento le scoperte della fisica – dalla meccanica quantistica alla teoria della relatività, dalle ricerche sul cosmo all’energia nucleare – hanno travolto le precedenti nozioni di spazio e tempo e rivoluzionato la percezione che l’uomo aveva di sé, investendolo inoltre della responsabilità di una possibile autodistruzione. Figura geniale e controversa, Werner Heisenberg è stato un protagonista assoluto dell’epopea scientifica del secolo scorso, insieme a Bohr e Fermi, Einstein e Planck. Fisica e filosofia esplora la complessità di quello snodo offrendo risposte chiare a domande che non hanno mai perso la loro centralità. Cosa affermano le teorie della fisica contemporanea? In che modo investono la concezione che l’uomo ha di sé? Quali sono i limiti etici delle loro applicazioni tecnologiche? E quale sarà l’influenza politica della scienza su scala planetaria? Affrontando quesiti di portata universale, Heisenberg si dimostra consapevole della necessità di ristabilire la ...

  20. BetOnMath azzardo e matematica a scuola

    CERN Document Server

    Andrà, Chiara; Verani, Marco

    2016-01-01

    Il libro ha origine dall'attività svolta durante il progetto "BetOnMath", un'esperienza di Matematica Civile finalizzata alla prevenzione dell'abuso di gioco d'azzardo tra gli studenti della scuola secondaria di secondo grado attraverso un insegnamento innovativo della matematica. In particolare, durante il progetto gli autori del libro hanno sviluppato un percorso didattico modulare sulla matematica del gioco d'azzardo che gli insegnanti di matematica delle scuole secondarie possono utilizzare sia per introdurre gli strumenti di base del calcolo delle probabilità sia per sensibilizzare sui rischi legati al gioco d'azzardo. Il libro descrive i pilastri metodologici e concettuali che hanno guidato la concezione e dato forma al percorso didattico, ovvero la centralità del ruolo dell'insegnante, l'uso dei simulatori di gioco, l'importanza delle attività di gruppo e il ruolo delle emozioni nell'affrontare e comprendere nuovi concetti matematici. Nel libro, ciascuno di questi pilastri è trattato sia mediante ...

  1. “Mne govorjat, kakaja bednost’ slovarja...” Il protosamizdat del periodo staliniano alla ricerca di un’espressività

    Directory of Open Access Journals (Sweden)

    Massimo Maurizio

    2015-07-01

    Full Text Available L’estetica della letteratura afferente al circuito samizdat dopo il XX congresso del PCUS (1956 è strettamente legata alla produzione non ufficiale del periodo staliniano, a sua volta definitasi secondo una relazione antitetica alla poesia proletaria degli anni Venti. Molte delle figure di rife- rimento di questo periodo hanno attinto il proprio linguaggio e gli strumenti poetici dall'arsenale espressivo e formale del Secolo d’Argento, sebbene differenziadosene notevolmente e adattan- dolo all'estetica che essi perseguivano, intimamente alternativa a quella realsocialista. La com- plessa poetica di autori quali E. Kropivnickij, Jan Satunovskj (come anche, in un periodo succes- sivo, il “discepolo” del primo G Sapgir e molti altri hanno attinto i tratti distintivi della propria produzione dalla rielaborazione dell’arte proletaria della prima metà degli anni Venti alla luce di una visione dissacrante e grottesca della contemporaneità, che emerge in primo luogo dall'aspetto delle loro opere poetiche.

  2. La «Cortegiania» e la «Cortesana Filosofia»: B. Castiglione e B. Gracián

    Directory of Open Access Journals (Sweden)

    Maria Teresa Ricci

    2013-06-01

    Full Text Available L’articolo stabilisce un confronto fra la cortigiania, ovvero la filosofia del comportamento raffinato dell’uomo cortese proposta dal testo Il cortigiano di Baldassare Castiglione, e la cortesana filosofia presente in tutta l’opera di Gracián. Questi due autori, che hanno vissuto in paesi e luoghi differenti, hanno dei principi filosofici, antropologici e religiosi molto diversi. Si distinguono dunque sia dal punto di vista letterario sia per il loro approccio teorico. Il primo offre un nuovo modello sociale di comportamento legato alla struttura particolare della corte all’inizio dell’epoca moderna; il secondo si propone esplicitamente di creare un «prodigio», un uomo «artificiale» che sappia far fronte alla realtà ingannevole, che sappia sopravvivere in un mondo ostile. Egli annuncia in un certo senso il passaggio dalla tradizionale società d’ordini, in cui ognuno ha sin dalla nascita il suo posto assicurato nella società, al mondo dell’«individualità astratta»

  3. Rulaga muuseumis : Maria Soomre ja Hanno Soans räägivad rulakultuurist ja kunstist : subkultuur / Maria-Kristiina Soomre, Hanno Soans

    Index Scriptorium Estoniae

    Soomre, Maria-Kristiina, 1978-

    2004-01-01

    Ka rulasõitjate kunstist (USA rulasõitja Ed Templeton, tema näitus "The Essencial Disturbance" Pariisi Palais de Tokyos), soome rulafotograaf Tuukka Kailast, kelle tööd on Kiasmas näitusel "Faster than History"

  4. Programmable gaming environments for four year olds

    Directory of Open Access Journals (Sweden)

    Edith K. Ackermann

    2002-01-01

    Full Text Available Apprendere a programmare alla scuola dell'infanzia? Perche'? Che cosa ci puo' essere di interessante in questo per un bambino? Che cosa si puo' imparare? Questo articolo e' rivolto ai ricercatori, ai progettisti, agli educatori e ai genitori; tutti questi hanno buone ragioni per interrogarsi.

  5. Serre fotovoltaiche Attenti alle perdite; Stanghellini: il calo produttivo non è da poco

    NARCIS (Netherlands)

    Contri, L.; Stanghellini, C.

    2010-01-01

    Gli installatori di pannelli fotovoltaici hanno nel mirino gli ortoflorovivaisti che gestiscono serre. Costoro, per contro, sono alla ricerca di sistemi atti a far loro recuperare la marginalità perduta in questi anni di crisi. Un matrimonio che s'ha da fare? Meglio di no. A sconsigliarlo è Cecilia

  6. Adamson-Eric 100 : XX sajandi kunsti- ja kultuurilugu ühe inimsaatuse kaudu / Ülle Kruus

    Index Scriptorium Estoniae

    Kruus, Ülle

    2002-01-01

    Näitus "Adamson-Eric 100" Eesti Kunstimuuseumi Rüütelkonna hoones ja Adamson-Ericu muuseumis. Koostajad Ülle Kruus, Kersti Koll, Hanno Soans, kujundajad Leonhard Lapin (EKM), Jaak Soans (Adamson-Ericu muuseum). Adamson-Ericu teosed väljaspool Eestit ja Eestisse tagasi jõudnud tööd

  7. Spatial separation of electrons and holes for enhancing the gas-sensing property of a semiconductor: ZnO/ZnSnO3 nanorod arrays prepared by a hetero-epitaxial growth

    Science.gov (United States)

    Wang, Ying; Gao, Peng; Sha, Linna; Chi, Qianqian; Yang, Lei; Zhang, Jianjiao; Chen, Yujin; Zhang, Milin

    2018-04-01

    The construction of semiconductor composites is known as a powerful method used to realize the spatial separation of electrons and the holes in them, which can result in more electrons or holes and increase the dispersion of oxygen ions ({{{{O}}}2}- and O - ) (one of the most critical factors for their gas-sensing properties) on the surface of the semiconductor gas sensor. In this work, using 1D ZnO/ZnSnO3 nanoarrays as an example, which are prepared through a hetero-epitaxial growing process to construct a chemically bonded interface, the above strategy to attain a better semiconductor gas-sensing property has been realized. Compared with single ZnSnO3 nanotubes and no-matching ZnO/ZnSnO3 nanoarrays gas sensors, it has been proven by x-ray photoelectron spectroscopy and photoluminescence spectrum examination that the as-obtained ZnO/ZnSnO3 sensor showed a greatly increased quantity of active surface electrons with exceptional responses to trace target gases and much lower optimum working temperatures (less than about 170 °C). For example, the as-obtained ZnO/ZnSnO3 sensor exhibited an obvious response and short response/recovery time (less than 10 s) towards trace H2S gas (a detection limit down to 700 ppb). The high responses and dynamic repeatability observed in these sensors reveal that the strategy based on the as-presented electron and hole separation is reliable for improving the gas-sensing properties of semiconductors.

  8. Drinking water pollution. DNA effects reproductive disorders; Inquinamento delle acque potabili. Effetti sul DNA e sulla riproduzione umana

    Energy Technology Data Exchange (ETDEWEB)

    Monarca, S.; Zani, C. [Brescia Univ., Brescia (Italy). Dipt. di Medicina Sperimentale ed Applicata, Sez. Igiene; Mantovani, A. [Istituto Superiore di Sanita' , Rome (Italy); Righi, E.; Aggazzotti, G. [Modena Univ., Modena (Italy). Dipt. di Scienze Igienistiche, Microbiologiche e Biostatiche

    2001-06-01

    Experimental studies have revealed in drinking water the presence of mutagenic/carcinogenic compounds, such as pesticides, organic solvents, heavy metals and disinfection by-products and epidemiological studies have found cancer risk for populations exposed to these contaminants. Moreover, researches have shown reproductive and developmental hazards for people who consume drinking water containing endocrine disrupting chemicals. The aim of this review is to describe and evaluate the health hazards arisen from the human exposure to these drinking water pollutants potentially able to damage DNA and produce adverse reproductive effects. [Italian] Il monitoraggio delle sostanze genotossiche nelle acque potabili e' ormai una tecnica matura, applicata in numerosi laboratori in tutto il mondo che analizzano di routine le acque potabili. Gli stessi Standard Methods for Examination of Water and Wastewater statunitensi nel 1995 hanno introdotto per la prima volta l'indicazione del test di Ames come test di riferimento per condurre indagini di mutagenesi nelle acque. Negli ultimi anni ricerche sperimentali ed epidemiologiche hanno messo in luce un nuovo problema legato all'inquinamento idrico: la presenza di composti che producono effetti dannosi sulla salute riproduttiva umana. Grazie anche all'incremento degli studi sperimentali di tossicologia della riproduzione, un numero crescente di composti sono stati identificati come possibili fattori di rischio per la fertilita' e lo sviluppo. Inoltre alcune indagini epidemiologiche hanno rilevato possibili effetti dannosi sulla salute riproduttiva in gruppi di donne esposte a contaminanti idrici. Metodiche biologiche sempre piu' sofisticate sono in fase di sperimentazione e si spera che in futuro possano essere applicate anche per il monitoraggio degli inquinanti idrici tossici per la riproduzione umana.

  9. La città sotterranea e il suo ruolo nella mobilità urbana

    Directory of Open Access Journals (Sweden)

    Giuseppe Mazzeo

    2008-12-01

    Full Text Available La città sotterranea è un elemento fondamentale nella struttura urbana. Soprattutto nelle grandi città essa assume connotazioni rilevanti nella pianificazione urbana in considerazione del fatto che rappresenta una risorsa e il suo impiego può incidere significativamente sull’efficienza del sistema urbano. Alcune città, a causa soprattutto della rigidità del clima, hanno progettato città sotterranee di grande complessità funzionale; esempi significativi sono Montreal, Toronto e altre città del Nord America. In Europa occidentale le realizzazioni associabili al concetto di città sotterranea sono più limitate e sono relative soprattutto alla realizzazione di infrastrutture per la mobilità urbana, come le reti metropolitane, i passanti ferroviari, i tunnel stradali e i parcheggi sotterranei. La funzione primaria di questi spazi è la riduzione e lo spostamento dalla superficie di quote di traffico e la trasformazione di ampie parti della città in aree verdi o in aree a maggiore qualità ambientale. In ogni modo è possibile sostenere che l’uso degli spazi sotterranei è ormai entrato a far parte della vita delle città moderne. L’articolo analizza alcuni dei fattori principali nella costruzione di questi spazi urbani; i costi e i benefici dell’uso di spazi sotterranei sono messi in relazione con gli aspetti psicologici e con la costruzione di modelli per la previsione dei percorsi degli utenti. La seconda parte dell’articolo mostra alcuni casi studio evidenziando le diverse necessità che hanno spinto e hanno guidato verso la scelta degli spazi sotterranei; una analisi più dettagliata è svolta sul caso di Montreal, che può essere considerato archetipo della citta sotterranea.

  10. Comparison of band-to-band tunneling models in Si and Si—Ge junctions

    International Nuclear Information System (INIS)

    Jiao Yipeng; Wang Taihuan; Wei Kangliang; Du Gang; Liu Xiaoyan

    2013-01-01

    We compared several different band-to-band tunneling (BTBT) models with both Sentaurus and the two-dimensional full-band Monte Carlo simulator in Si homo-junctions and Si—Ge hetero-junctions. It was shown that in Si homo-junctions, different models could achieve similar results. However, in the Si—Ge hetero-junctions, there were significant differences among these models at high reverse biases (over 2 V). Compared to the nonlocal model, the local models in Sentaurus underrated the BTBT rate distinctly, and the Monte Carlo method was shown to give a better approximation. Additionally, it was found that in the Si region near the interface of the Si—Ge hetero-junctions, the direct tunneling rates increased largely due to the interaction of the band structures of Si and Ge. (semiconductor physics)

  11. I RACCONTI DEL SECONDO MILLENNIO DI GIULIO ANGIONI

    African Journals Online (AJOL)

    User

    diversa da libro a libro. Questi mitemi di varia ampiezza e complessità hanno anche differenti origini: si passa infatti dall'ampio patrimonio di conoscenze sul folclore e sugli usi e costumi delle popolazioni contadine della Sardegna, chiaramente sempre disponibili al Giulio. Angioni antropologo,8 a fatti, eventi e personaggi ...

  12. Agreements for energy and environment; Patto per l'energia e l'ambiente

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-07-01

    In this paper are reported in ambit of italian national conference of energy and environment, an agreement undersigned by deputy of political and social forces. [Italian] In questo documento e' illustrato il patto per l'energia e l'ambiente cui hanno aderito forze sociali e politiche del paese.

  13. Veneetsia pärgab sotsiaalkriitikuid / Johannes Saar

    Index Scriptorium Estoniae

    Saar, Johannes, 1965-

    2005-01-01

    13. juunil avatud Veneetsia 51. kunstibiennaalist. Rahvuspaviljonidest, preemiasaajaid. Elutööpreemia sai Barbara Kruger, kuraatoripreemiad Rosa Martinez ja Maria de Corral. Eestit esindab Mark Raidpere, kuraator Hanno Soans. Kesk-Aasia paviljonist lisas "Tapetud vaikitakse maha". Usbeki, Kirgiisi ja Kasahstani kunstnike ühisnäituse kuraator on Viktor Misiano Moskvast

  14. Jabloko razdora / Andrei Babin

    Index Scriptorium Estoniae

    Babin, Andrei

    2002-01-01

    Hanno Soansi mitmeosalisest kunstiprojektist: jälgib inimeste reaktsioone lavastatud situatsioonides - 1998. a. seisis poolalasti Tõnismäe monumendi juures, samas jagas banaane; Kadriorus püstitas 20 m kõrguse plakati loosungiga "Mõ prevratim ves mir v tsvetushtshi sad !"; jagas roosa haakristiga õunu 9. mail 2002 Tallinnas Tammsaare monumendi juures

  15. Isehakanud klassikute näitus / Margus Kiis

    Index Scriptorium Estoniae

    Kiis, Margus

    2003-01-01

    Fotonäitusest XXL, mis hõlmab peamiselt 1990-2000 a. fotosid, Tartu Kunstnike Majas. Näituse koostajad Peeter Linnap ja Vello Kalamets. Kirjeldatud DeStudio, Peeter Lauritsa, Toomas Kalve, Tarvo Hanno Varrese, Peeter Linnapi, Meelis Lukki, Ain Protsini, Tõnu Tamme, Malev Toomi, Vello Kalametsa ja Madis Palmi töid

  16. Mahtra talurahvamuuseumi uue hoone arhitektuurse eskiisprojekti võistluse...

    Index Scriptorium Estoniae

    2005-01-01

    Hindamiskomisjon (osalejad loetletud) andis I preemia Tomomi Hayashi ja Hanno Grossschmidti (HG Arhitektuur) võistlustööle "Heinamaa", II - Andres Lemberi (Male Arhitektid) võistlustöö "Talgud", III - Liina Jaanuse võistlustöö "Pärand", ergutuspreemia - Indrek Järve (Schults ja Partnerid) võistlustöö "Part"

  17. Classi plurilingue in condizioni di super-diversita

    NARCIS (Netherlands)

    Spotti, Max

    2015-01-01

    Il plurilinguismo nelle classi è e rimane un punto di preoccupazione per gli insegnanti fin dall'inizio della scuola dell'obbligo. In Italia, cosi come in tutta l’Europa occidentale, da quando le scuole hanno aperto le loro porte ai bambini appartenenti a comunità immigrate, i docenti si sono dovuti

  18. Kunst, tapmine, surm / Aivo Lõhmus

    Index Scriptorium Estoniae

    Lõhmus, Aivo, 1950-2005

    1996-01-01

    Järg: 22. märts 1996. Vastukaja : Juske, Ants. Uusi õuduspilte 'moodsast' kunstist // Eesti Päevaleht (1996) 27. märts, lk.8 : ill.; Lõhmus, Aivo. Tänuavaldus [Ants Juskele] // Kultuurileht (1996) 29. märts, lk.19 ; Soans, Hanno. Tegelikkusest vaevatud kriitika // Kultuurileht (1996) 26. apr., lk. 6

  19. Hea tahte mängud Helsingis / Hanno Soans

    Index Scriptorium Estoniae

    Soans, Hanno, 1974-

    2003-01-01

    3. ja 4. XII Kiasmas toimunud seminarist "Institutsioonid ruudus", mis tutvustas kümmet kaasaegse kunstiga tegelevat institutsiooni Euroopas ja nende uusi töömudeleid seminari, workshopide ja näituse abil. Eestit esindas Silva Lutsu sketsh Tellervo Kalleineni videos "In the Middle of the Movie", seminaril olid H. Soans, Reiu Tüür, Eve Kiiler

  20. Teine nahk ehk Ornament ja meie / Hanno Soans

    Index Scriptorium Estoniae

    Soans, Hanno, 1974-

    2003-01-01

    Arhitekt Adolf Loosi suhtumine ornamenti ja nahakaunistustesse, tattoo tagasitulek käibesse läänes XX sajandi II poolel. EKA nahakunsti eriala diplomandi Kerstin Raidma lõputööst, mis sisaldas seeria levinumaid tätoveeringupiirkondi katvaid nahast ehteid, lühidalt sama eriala lõpetaja Agnetha Kurusoni lõputööst "Kest" ja lõputööde hinnetest

  1. Foorumi ärikeskus Tallinnas / Hanno Grossschmidt, Tomomi Hayashi

    Index Scriptorium Estoniae

    Grossschmidt, Hanno, 1973-

    2007-01-01

    asendiplaan, I korruse plaan, lõige, 4 värv. välis- ja 2 sisevaadet (restoran, äritänav); fotod: Kaido Haagen, Margus Tammik; projekteerija HG Arhitektuur; sisekujundajad: äritänav - Kohvi OÜ, Argentiina restoran - Ruumilabor OÜ

  2. Skaalanihe : kunstnikud räägivad / Hanno Soans

    Index Scriptorium Estoniae

    Soans, Hanno, 1974-

    2006-01-01

    Kunstnikud tutvustavad Kumus avanäitusel eksponeeritud kunstiteoseid: Anssi Kasitonni "Jah-monstrum", Chris Evans "Radikaalne lojaalsus", Neeme Külm "Betooni valatud lehm", Cevdet Erek "Teine sild", Heli Ryhänen "Ootus", Hans Hammert "Õhupallikabel", Veronica Brovall "Lahutus", Karsten Konrad "Supersuziseacat", Anders Krüger "Mis silma alt ära, see unustatud", Tommy Stockel "Tulevaste asjade kuju"

  3. Lasteaiad jäägu lastele / Hanno Pevkur

    Index Scriptorium Estoniae

    Pevkur, Hanno, 1977-

    2006-01-01

    Tallinna volikogu liige selgitab, miks temas tekitab küsitavusi linnavalitsuse kava rajada Tallinnasse 100 uut mänguväljakut. Autor leiab, et mänguväljakud saab rajada kavandatust neli korda odavamalt ning nad peaksid jääma ainult lasteaedade laste kasutada

  4. Globaalarhitekti uus manifest / Karin Hallas-Murula

    Index Scriptorium Estoniae

    Hallas-Murula, Karin, 1957-

    2004-01-01

    Hollandi arhitekt Rem Koolhaas'ist, kelle näitus "Content" Rotterdami Kunstihallis ning näitus "Start" Rotterdami Hollandi Arhitektuuriinstituudis on avatud 31. maini. Näituse "Content" kataloogist. 2000. a. sai R. Koolhaas Pritzkeri preemia, 2003. a. Praemium Imperiale, 2004. a. veebruaris RIBA kuldmedali. Kommenteerinud Andres Alver, Hanno Grossschmidt ja Inga Raukas

  5. Mesto vstretshi - Tallinn / Aleksandra Manukjan

    Index Scriptorium Estoniae

    Manukjan, Aleksandra

    2003-01-01

    22. juulil avatakse Rotermanni soolalaos rahvusvaheline Põhja- Euroopa kaasaegse kunsti näitus "Kohtumispaik". Eesti kuraator on Hanno Soans, nimetatud ka kuraatoreid teistest maadest. Osalejatest on esile toodud Laura Stasiulyte, Miklos Gaal ja Sandis Konrads, nimetatud veel 13 osaleja nimed. Projekti autor ja mänedžer on rootsi kunstnik Truls Olin

  6. Mereline Foorum kutsub kulla ja karraga / Urmas Oja

    Index Scriptorium Estoniae

    Oja, Urmas, 1981-2012

    2007-01-01

    Elu- ja ärihoonest Narva mnt. 5 / Hobujaama 10H Tallinnas. Arhitektid: Hanno Grossschmidt ja Tomomi Hayashi, HG Arhitektuur. Siselahendus: Hannes Praks ja Margus Tammik, OÜ Kohvi. Ehitaja: AS KMG Ehitus. Ehituse algus: detsember 2004, valmimisaeg: 01.07. 2006 - 01. 09. 2007. 5 värv. välis- ja 2 sisevaadet

  7. Narva maantee uus nägu on klaasist ja alumiiniumist / Askur Alas

    Index Scriptorium Estoniae

    Alas, Askur, 1973-

    2005-01-01

    Ehitustegevusest Tallinnas Narva maanteel. Hobujaama tänava nurgale kerkib Foorumi-nimeline majadekompleks - büroohoone ja kaks korteritega ärihoonet. Üheks arhitektiks on Hanno Grossschmidt (HG Arhitektuur). Narva mnt. 7 büroohoone ehitatakse Künnapu ja Padriku kavandi järgi ümber kolmekordseks modernseks kolme torniga elumajaks Triumph Plaza

  8. Multivariate curve resolution using a combination of mid-infrared and near-infrared spectra for the analysis of isothermal epoxy curing reaction

    Science.gov (United States)

    Yamasaki, Hideki; Morita, Shigeaki

    2018-05-01

    Multivariate curve resolution (MCR) was applied to a hetero-spectrally combined dataset consisting of mid-infrared (MIR) and near-infrared (NIR) spectra collected during the isothermal curing reaction of an epoxy resin. An epoxy monomer, bisphenol A diglycidyl ether (BADGE), and a hardening agent, 4,4‧-diaminodiphenyl methane (DDM), were used for the reaction. The fundamental modes of the Nsbnd H and Osbnd H stretches were highly overlapped in the MIR region, while their first overtones could be independently identified in the NIR region. The concentration profiles obtained by MCR using the hetero-spectral combination showed good agreement with the results of calculations based on the Beer-Lambert law and the mass balance. The band assignments and absorption sites estimated by the analysis also showed good agreement with the results using two-dimensional (2D) hetero-correlation spectroscopy.

  9. Attivitá fisica extra-scolastica negli adolescenti: il ruolo dello stato socio-economico delle famiglie

    Directory of Open Access Journals (Sweden)

    G. Capelli

    2003-05-01

    Full Text Available

    Obiettivi: l’associazione fra stato socio-economico (SES ed attività fisica è poco indagata. Obiettivo del presente studio è quello di valutare la relazione tra attività fisica extra-scolastica di adolescenti scolarizzati e lo SES della famiglia di provenienza.

    Metodi: l’indagine ha previsto la somministrazione nel corso dell’anno scolastico 2002-2003 di un apposito questionario anonimo autocompilato, già validato in uno studio pilota, ad un campione di studenti delle scuole medie inferiori del Lazio (province di Roma, Frosinone e Latina.

    Risultati: hanno partecipato allo studio 1486 studenti di cui 756 maschi (50.9% e 730 femmine (49.1%. L’età dei partecipanti varia fra gli 11 ed i 15 anni (età mediana 12 anni. Il 72.7% degli studenti dichiara di svolgere attività fisica al di fuori della scuola. Il livello di istruzione dei genitori e la loro attività lavorativa sembrano avere un peso notevole sui determinanti dell’attività fisica negli studenti. Infatti, svolgono prevalentemente attività fisica extra-scolastica i figli di genitori manager/libero professionisti (OR = 3.29 e con un elevato livello educativo (OR = 10.38 per i figli di genitori laureati.

    Conclusioni: i risultati confermano quanto la situazione socio-economica delle famiglie sia in netta relazione con l’attività fisico-sportiva dei giovani. Tali risultati potranno essere utili per gli operatori scolastici e gli amministratori nell’ispirare e realizzare azioni volte a diminuire il divario esistente fra i giovani che hanno le possibilità economiche e svolgono attività sportiva extra-scolastica e quelli che, invece, appartenendo a famiglie svantaggiate, hanno minore accesso a tali attività.

  10. Book review, Amati cani, José Jorge Letria

    Directory of Open Access Journals (Sweden)

    Manuel Graziani

    2008-03-01

    Full Text Available Con Amati cani ci discostiamo per una volta dalle pubblicazioni a carattere scientifico, per dare il giusto risalto ad un’interessante raccolta di narrativa che esplora il rapporto tra l'uomo e il suo miglior amico. José Jorge Latria, noto soprattutto per essere un esponente di spicco della canzone politica portoghese e per le sue opere poetiche, teatrali e di letteratura per ragazzi, nello scrivere questo libro compie un vero e proprio atto d’amore verso i cani, con il preciso intento di costringere i lettori ad eliminare dal proprio vocabolario il gratuito modo di dire ‘mondo cane’. L’Autore delinea brevi ritratti di cani che, da Argo in poi, hanno accompagnato da amici veri i loro celebri padroni nella buona e nella cattiva sorte: racconta cioè la storia di quei cani che non sono sprofondati nella voragine dell’oblio perchè i loro padroni hanno raggiunto la celebrità nel mondo della letteratura, della politica, del cinema, delle scienze o della musica. Con a fianco un amico fedele come un cane, la vita ha avuto un sapore diverso per Ernest Hemingway, Isaac Newton, Sigmund Freud, Buster Keaton, Marilyn Monroe, Pablo Picasso, John Steinbeck, Lord Byron, Tim Burton e altri ancora, tutti personaggi che sono presenti in questo libro grazie ai cani che hanno condiviso con loro la vita e le memorie. La lettura di Amati cani dà piacere poichè in ognuno di questi racconti batte, affettuoso e delicato, il cuore di un cane; ma dà anche un pò da pensare in quanto celebra in maniera molto tenera l’amore, la fedeltà e la solidarietà tra l’uomo e il suo speciale amico a quattro zampe.

  11. Näitus Mahtra talurahvamuuseumi arhitektuurikonkursile laekunud töödest

    Index Scriptorium Estoniae

    2005-01-01

    Võistlustööde hindamiskomisjoni liikmed. Parim töö "Heinamaa", arhitektid Tomomi Hayashi ja Hanno Grossschmidt arhitektuuribüroost HG Arhitektuur. Teine koht Andres Lemberi ja Tarmo Maiste tööle "Talgud", kolmas koht Liina Jaanuse tööle "Pärand", neljas koht Indrek Järve tööle "Part"

  12. Tallinna linn või aukude plombeerimine = City of Tallinn or filling of holes / Veljo Kaasik

    Index Scriptorium Estoniae

    Kaasik, Veljo

    1999-01-01

    "Eesti Päevalehes" ilmunud arhitektide viimase aja karakteersemate tööde hindamistabelist, selles olevast Nissani keskusest (Andres Siim, Hanno Kreis), Hansapanga hoonest ja Stockmanni kaubamajast (Peep Jänes). Tallinna arhitektuurist kui tervikust. Tallinnas on palju tühje krunte, rekonstrueerimist ootavaid linnaosi ja suuri üksikhooneid. Linn realiseerub läbi investorite majandusliku huvitatuse

  13. Aeg aias / Jaan Mettik

    Index Scriptorium Estoniae

    Mettik, Jaan

    2007-01-01

    Päikesekellade ajaloost, tüüpidest, Santiago Calatrava kavandatud jalakäijate sillast-päikesekellast Californias, Eesti päikesekelladest Kadrioru pargis, Haapsalu rannapromenaadil (Roman Haavamägi) ja Saue tammepargis (Hanno Grossschmidt, Tomoni Hayashi). Kuukelladest, Karl Linne lillekellast, libalillekelladest. Juhised päikesekella tegemiseks. Lk. 60-61 "Ajanäitajaid lillekellale"

  14. Wilfried Kürschner (Hg., Linguisten-Handbuch: Biographische und bibliographische Daten deutschsprachiger Sprachwissenschaftlerinnen und Sprachwissenschaftler der Gegenwart, I-II, Tübingen, Gunter Narr Verlag, 1994, XXX-1191 pp.

    Directory of Open Access Journals (Sweden)

    Žarko Muljačić

    1994-12-01

    Full Text Available Sebbene questo manuale fosse ideato nell'ormai lontano 1988 esso vede luce, a cura di W. Kurschner (1945-, professore di linguistica generale e germanica all'Universita di Osnabriick (sede di Vechta, appena ora. Una delle ragioni che hanno differito la sua pubblicazione è il fatto che fino al 1990 non esisteva un indirizzario dei linguisti attivi nella ex RDT. Le poche persone che già nel 1989 risposero all'appello dalla Germania Orientale appartenevano quasi esclusivamente all'Istituto Centrale di Linguistica dell'Accademia delle Scienze (ZISW di Berlino (Est e neanche essi erano liberi di rispondere all'intero Questionario (in base a ordini ricevuti hanno dovuto "saltare" ogni risposta alle domande Nr. 5, 6, 16, 18 e 31 (cf. W. Kurschner, "Notizen zur Entstehung des Linguisten-Handbuchs", vol. I, XII-XIV e il divertente e che queste domande si riferivano a cose del tutto "normali" (per es. ai numeri dei telefoni privato e d'ufficio e alle attività svolte fra la fine degli studi e l'ultimo incarico di lavoro.

  15. Neanche sbagliata il fallimento della teoria delle stringhe e la corsa all'unificazione delle leggi della fisica

    CERN Document Server

    Woit, Peter

    2007-01-01

    La teoria delle stringhe, "eterna promessa" della fisica teorica, sembra oggi giunta alla resa dei conti, e molti studiosi si stanno da tempo interrogando sulla sua reale validità. Un certo malcontento già serpeggiava nei corridoi delle università e in alcuni scritti quasi clandestini ma ora giunge dagli Stati Uniti la voce di Peter Woit, ferma e decisa nel lanciare un messaggio chiaro: questa presunta "teoria del tutto" che pretendeva di unificare le leggi della fisica, si è rivelata alla fine una "teoria del niente", incapace di dimostrare anche uno solo dei suoi enunciati. Dopo una dettagliata panoramica sugli sviluppi della fisica che hanno portato, nella metà degli anni Settanta, alla nascita e al successo del Modello standard, Woit giunge quindi al cuore del suo libro. L'accusa è pesante: non solo i teorici delle stringhe non fanno scienza, ma hanno goduto di un predominio eccessivo per vent'anni, monopolizzando il reperimento dei fondi economici pubblici e privati e impedendo di fatto un sano pro...

  16. Le narrazioni come metodo di indagine sociologica

    Directory of Open Access Journals (Sweden)

    Rita Bichi

    2012-04-01

    Full Text Available L'incontro trentino ha dimostrato l'interesse crescente dei giovani sociologi per lo sviluppo dei metodi narrativi e la capacità che questi hanno di essere efficaci nell'analisi di svariati temi, dai racconti di malattia alle narrazioni identitarie, dallo studio di lavoro e organizzazioni a quello delle migrazioni, di genere e memoria. Tuttavia, l'interesse della sociologia italiana va visto in un quadro di sviluppo più ampio a livello europeo e americano dove, a partire dagli anni '90, l'intervento di alcuni autori come Lyotard, Bruner e Macintyre, ha sancito quella che alcuni autori hanno definito svolta narrativa. La sociologia, infatti, tende sempre più a valorizzare la narrazione come processo di conoscenza peculiare che è attivato costantemente nella vita quotidiana; la "rivoluzione" risiede nel fatto che la narrazione diventa oggetto della sociologia e la disciplina stessa valorizza il suo uso sia come strumento di indagine scientifica, sia come modo di conoscere che come modo di comunicare, rivendicando la legittimità scientifica all'ascolto della parola diretta degli individui coinvolti all'interno delle ricerche di stampo sociologico.

  17. Political Turmoil and Lack of Rights in Nigerian Literature

    Directory of Open Access Journals (Sweden)

    Nicola Turi

    2012-05-01

    Full Text Available La letteratura nigeriana del Novecento è stata fortemente condizionata dagli eventi collettivi che hanno scandito la storia recente del paese – dalla colonizzazione inglese alla guerra del Biafra, fino agli scontri armati tra il governo centrale e le forze del Mosop sul Delta del Niger – e che hanno di volta in volta a che fare con la sostituzione e/o la sospensione dell’ordinamento giuridico vigente, con la controversa applicazione del diritto internazionale, con la repressione legalizzata del dissenso. Coprendo il cinquantennio che va da Things fall apart (1958 di Chinua Achebe (nel quale si racconta l’avvento dei primi missionari inglesi alle testimonianze (narrative e non di Wole Soyinka (1972, Ken Saro-Wiwa (1985 e Chimamanda Ngozi Adichie (2006 intorno alla guerra civile del 1967-1970, il presente studio intende offrire, mettendo tra loro in dialogo i testi citati, le declinazioni esemplari della dialettica tra letteratura e diritto all’interno di un panorama letterario pressoché condannato a figurare la legge come chimera, abuso, scontro tra codici (morali e poi legislativi tra loro incompatibili.

  18. Simple balloon dilation for drug-eluting in-stent restenosis: An optical coherent tomography analysis

    Energy Technology Data Exchange (ETDEWEB)

    Arikawa, Ryo [Division of Cardiology, Tenyoukai Central Hospital, Izumi-cho, Kagoshima City, Kagoshima (Japan); Yamaguchi, Hiroshi, E-mail: hyamaguchi@tsm.bbiq.jp [Division of Cardiology, Tenyoukai Central Hospital, Izumi-cho, Kagoshima City, Kagoshima (Japan); Takaoka, Junichiro; Miyamura, Akihiro; Atsuchi, Nobuhiko; Ninomiya, Toshiko; Atsuchi, Yoshihiko [Division of Cardiology, Tenyoukai Central Hospital, Izumi-cho, Kagoshima City, Kagoshima (Japan); Ohishi, Mitsuru [Department of Cardiovascular Medicine and Hypertension, Graduate School of Medical and Dental Science, Kagoshima University, Kagoshima (Japan); Terashima, Mitsuyasu [Department of Cardiology, Toyohashi Heart Center, Toyohashi (Japan); Kaneda, Hideaki [Okinaka Memorial Institute for Medical Research, Tokyo (Japan)

    2015-01-15

    Background: Although drug-eluting stent (DES) has significantly reduced restenosis, the treatment of DES-in-stent restenosis (ISR) remains a challenge with high restenosis rate. Methods: We examined whether morphologic appearance of restenosis tissue by optical coherent tomography (OCT) had an impact on outcomes after balloon angioplasty for DES-ISR. The morphologic appearance of restenosis tissue was qualitatively assessed for tissue structures such as homogeneous, layered, and heterogeneous patterns. Results: Using OCT, 50 patients with DES-ISR were divided into 2 groups: 25 lesions with homogeneous or layered patterns (homo/layered group) and 25 lesions with heterogeneous patterns (hetero group). Acute gain was larger in the hetero group (1.33 ± 0.41 mm vs. 1.06 ± 0.32 mm in the homo/layered group, P = 0.03). On intravascular ultrasound analysis, post-procedural percent neointimal area was smaller in the hetero group (27.4 ± 9.2% vs. 34.0 ± 11.2% in the homo/layered group, P = 0.05). Angiographic follow-up was performed in 37 lesions (74%). Follow-up minimal lumen diameter was larger in the hetero group (1.75 ± 0.89 mm vs. 1.01 ± 0.81 mm in the homo/layered group, P = 0.04). Target lesion revascularization rates tended to be lower in the hetero group (20% vs. 43% in the homo/layered group, P = 0.12). Conclusions: Balloon angioplasty was more effective for DES-ISR with heterogeneous tissue appearance than DES-ISR with homogeneous/layered tissue appearance. OCT assessment of DES-ISR morphology may be a useful adjunct in determining clinical strategies. Simple balloon dilatation is a possible treatment strategy for DES-ISR lesions with a heterogeneous appearance on OCT images.

  19. Marzo 1991: la residenza del gruppo Gorgona a Brunnenburg

    Directory of Open Access Journals (Sweden)

    Marco Scotti

    2013-12-01

    Full Text Available Questo articolo indaga l'affermazione di una ricezione critica di Gorgona in Italia attraverso uno specifico caso di studio, individuato nella residenza d'artista a cui hanno partecipato alcuni esponenti del gruppo presso il castello di Brunnenburg (Merano, organizzata dal collezionista ed editore veronese Francesco Conz in collaborazione con l’MSU di Zagabria nel 1991.

  20. Trent'anni che sconvolsero la fisica la storia della teoria dei quanti

    CERN Document Server

    Gamow, George

    1993-01-01

    Gli anni dal 1900 al 1930 hanno portato un profondo mutamento nella visione che l'uomo aveva dell'universo: tra la prima idea di Max Planck dei quanti di luce nel 1900, e la previsione dell'esistenza delle antiparticelle formulata da P. A. M. Dirac nel 1929, corre un periodo di emozionanti progressi nel campo della fisica teorica.

  1. Mahtra Talurahvamuuseum

    Index Scriptorium Estoniae

    2005-01-01

    Mahtra Talurahvamuuseumi eskiisprojekti võistluse eesmärgiks oli saada parim lahendus muuseumihoone kaasajastamiseks ja laiendamiseks. Žürii koosseis. Võidutööst. Preemiad: I - Tomomi Hayashi, Hanno Grossschmidt ((HG Arhitektuur), II - Andres Lember, Tarmo Maiste (Male Arhitektid), III - Liina Jaanus, ergutuspreemia - Indrek Järve (Schults ja Partnerid). Ill.: võidutöö asendiplaan, korruste plaanid, vaade

  2. Tõeline arhitektuur kolis linnast Juuru valda / Tiia Truu

    Index Scriptorium Estoniae

    Truu, Tiia, 1948-

    2005-01-01

    Arhitektuurivõistlusest, mille eesmärgiks oli saada parim lahendus Mahtra muuseumi laiendamiseks. Esimene preemia - märgusõna "Heinamaa", Tomomi Hayashi ja Hanno Grossschmidt arhitektuuribüroost HG Arhitektuur. Teine preemia - märgusõna "Talgud", Andres Lember ja Tarmo Maiste arhitektuuribüroost Male Arhitektid. Kolmas preemia - märgusõna "Pärand", arhitekt Liina Jaanus

  3. 14. II kell 14 esitletakse EKMi Rüütelkonna hoones...

    Index Scriptorium Estoniae

    2005-01-01

    Esitletakse raamatuid "Eesti kunst. 101 teost Eesti kunstimuuseumi kogudest" (autorid: Tiina Abel, Eha Komissarov, Hanno Soans, koostanud T. Abel, E. Komissarov, H. Soans ja Kädi Talvoja, kujundanud Anu Lemsalu), "Kunstnik ja tema kodu. C. T. von Neffi kunstikogu Piira ja Muuga mõisast" (koostanud Tiina Abel, kujundanud Andres Tali) ja Kiwa "Roboti tee on nihe. Salatühik"

  4. Rotermanni vana ja uus jahuladu = The Rotermann Old and New Flour Storage / Margit Mutso

    Index Scriptorium Estoniae

    Mutso, Margit, 1966-

    2010-01-01

    Tallinna Rotermanni 8 asuvast Rotermanni uuest ja vanast jahulaost, mis pälvis 2009. a. EK arhitektuuri sihtkapitali arhitektuuripreemia linnaruumi tunnetava, uut ja vana tervikuks siduva arhitektuuri eest. Arhitektid: Hanno Grossschmidt, Tomomi Hayashi, Yoko Azukawa (HG Arhitektuur). Büroode üldkujundus: Tarmo Piirmets, Raul Tiitus (OÜ Pink). Žürii liige Kalle Komissarov žürii hinnangust hoonele

  5. E-learning e Università. Riflessioni tratte dalle interviste a quattro esperti italiani: Antonio Calvani, Luigi Guerra, Roberto Maragliano, Pier Cesare Rivoltella.

    Directory of Open Access Journals (Sweden)

    Laura Corazza

    2006-01-01

    Full Text Available Quattro esperti italiani di e-learning in ambito universitario hanno accettato di rispondere ad alcune domande su vantaggi e svantaggi, caratteristiche attuali e prospettive future di una nuova forma di didattica, l’e-learning, che richiede un ripensamento complessivo del modo di intendere l’apprendimento, lo sviluppo del sapere e la formazione della conoscenza.

  6. Low-tech-video ehk naivistide, amatööride ja videokunstnike audiovisuaalne kunst / Raivo Kelomees

    Index Scriptorium Estoniae

    Kelomees, Raivo, 1960-

    2001-01-01

    Varajasest videokunstist ja videokunstist muutunud kontekstis. Vene kunstniku Oleg Mavromatti videotest "Võbljadki" ja "Roheline elevandike". Rael Arteli, Valdek Alberi, Kristin Kalamehe ja Allan Tõnissoo töödest. Trash-videost. Marko Siguse videotest-filmidest. Taave Tuutma, Mari Sobolevi, Hanno Soansi ja Katrin Kivimaa planeeritud aktsioonide dokumentatsioonidest. Ilmunud ka kogumikus "Ekraan kui membraan". Tartu, 2007, lk. 195-198

  7. Auto y heteroestereotipo étnico en estudiantes preuniversitarios de Lima Metropolitana

    Directory of Open Access Journals (Sweden)

    Carmen Zornoza

    1986-12-01

    Full Text Available La autora revisa algunas de las investigaciones hechas en el Perú acerca de la influencia de factores étnicos. Luego expone los resultados de una investigación acerca de auto y hetero estereotipos en grupos raciales diferentes.  Queda demostrado que el auto estereotipo de los blancos es más alto que el de los mestizos y que el hetero estereotipo de estos últimos es más alto que el de los primeros.

  8. Metal-doped graphene layers composed with boron nitride-graphene as an insulator: a nano-capacitor.

    Science.gov (United States)

    Monajjemi, Majid

    2014-11-01

    A model of a nanoscale dielectric capacitor composed of a few dopants has been investigated in this study. This capacitor includes metallic graphene layers which are separated by an insulating medium containing a few h-BN layers. It has been observed that the elements from group IIIA of the periodic table are more suitable as dopants for hetero-structures of the {metallic graphene/hBN/metallic graphene} capacitors compared to those from groups IA or IIA. In this study, we have specifically focused on the dielectric properties of different graphene/h-BN/graphene including their hetero-structure counterparts, i.e., Boron-graphene/h-BN/Boron-graphene, Al-graphene/h-BN/Al-graphene, Mg-graphene/h-BN/Mg-graphene, and Be-graphene/h-BN/Be-graphene stacks for monolayer form of dielectrics. Moreover, we studied the multi dielectric properties of different (h-BN)n/graphene hetero-structures of Boron-graphene/(h-BN)n/Boron-graphene.

  9. Women in nursing teams: organizational identification and experiences of pleasure and suffering

    Directory of Open Access Journals (Sweden)

    Adriane Vieira

    2013-09-01

    Full Text Available OBJECTIVE: to analyze the degree of influence of the organizational identification on the experiences of pleasure and suffering of women who are members of the nursing staff of two general hospitals in Belo Horizonte. METHOD: a quantitative study was conducted with 97 nurses and 414 nursing technicians chosen by convenience in their workplaces. We used a self-administered questionnaire containing four Likert-type scales: self and hetero-perceptions; identification with the organization; and experiences of pleasure and pain at work. RESULTS: the structural relations explained a small percentage of the variability of organizational identification, showing that the self and hetero-perception are presented as relevant factors in professional identification with the organization. When considering how much the self and the hetero-perception and organizational identification all together impact in the experiences of pleasure and pain, a higher explanatory power is observed for: professional exhaustion, lack of recognition, freedom of expression and professional achievement.

  10. Melanin from the nitrogen-fixing bacterium Azotobacter chroococcum: a spectroscopic characterization.

    Directory of Open Access Journals (Sweden)

    Aulie Banerjee

    Full Text Available Melanins, the ubiquitous hetero-polymer pigments found widely dispersed among various life forms, are usually dark brown/black in colour. Although melanins have variety of biological functions, including protection against ultraviolet radiation of sunlight and are used in medicine, cosmetics, extraction of melanin from the animal and plant kingdoms is not an easy task. Using complementary physicochemical techniques (i.e. MALDI-TOF, FTIR absorption and cross-polarization magic angle spinning solid-state (13C NMR, we report here the characterization of melanins extracted from the nitrogen-fixing non-virulent bacterium Azotobacter chroococcum, a safe viable source. Moreover, considering dihydroxyindole moiety as the main constituent, an effort is made to propose the putative molecular structure of the melanin hetero-polymer extracted from the bacterium. Characterization of the melanin obtained from Azotobacter chroococcum would provide an inspiration in extending research activities on these hetero-polymers and their use as protective agent against UV radiation.

  11. Ricerca e sperimentazione fra arte e medium. Intervista a Giuliano Giuman

    Directory of Open Access Journals (Sweden)

    Manuela Perria

    2016-07-01

    Full Text Available Sperimentazione e intermedialità: sono questi i principali fattori che, negli ultimi cinquant’anni, hanno segnato la complessa ricerca estetica di Giuliano Giuman. Partendo dagli esordi pittorici fino alle più recenti opere in vetro, il maestro perugino si racconta in un’intervista ricca di elementi che approfondiscono l’origine del suo personale linguaggio artistico destinato a una continua evoluzione.

  12. Kodu osa isiklikus ja ühiskondlikus elus

    Index Scriptorium Estoniae

    2008-01-01

    15. II avatakse Eesti Tarbekunsti-ja Disainimuuseumis Eesti Vabariigi 90. aastapäevale pühendatud näitus "Varamu. Esindusruum ja moodne kodu 1918-1940", mille on koostanud Merike Alber, kujundanud Margit Lillak ning graafiliselt kujundanud Denes Farkas. Eksponaadid on pärit riigikogust, presidendi kantseleist, Eesti muuseumidest ning erakogudest. Lõik Hanno Kompuse artiklist ajakirjas "Kaunis Kodu", 1935, nr. 3

  13. Kodu osa isiklikus ja ühiskondlikus elus

    Index Scriptorium Estoniae

    2008-01-01

    15. veebruaril 2008. a. avatakse Eesti Tarbekunsti-ja Disainimuuseumis Eesti Vabariigi 90. aastapäevale pühendatud näitus "Varamu. Esindusruum ja moodne kodu 1918-1940", mille on koostanud Merike Alber, kujundanud Margit Lillak ning graafiliselt kujundanud Denes Farkas. Eksponaadid on pärit riigikogust, presidendi kantseleist, Eesti muuseumidest ning erakogudest. Lõik Hanno Kompuse artiklist ajakirjas "Kaunis Kodu", 1935, nr. 3

  14. A “novel site”: Carmen Covito, writing, literature and technology ...

    African Journals Online (AJOL)

    L'Internet cambia l'idea del libro e pone allo scrittore nuovi orizzonti di lettori prima impensabili. Carmen Covito è fra i primi scrittori italiani ad avere un proprio sito web. Le sue varie iniziative in internet hanno destato l'attenzione sia di critici culturali e letterari sia del grande pubblico. Tramite l'analisi di alcuni scritti di Covito ...

  15. Antonio Costa, La mela di Cézanne e l’accendino di Hitchcock. Il senso delle cose nei film

    Directory of Open Access Journals (Sweden)

    Beatrice Seligardi

    2016-05-01

    Full Text Available «Sono diecimila persone, forse, che non hanno dimenticato la mela di Cézanne ma sono un miliardo gli spettatori che si ricorderanno dell’accendino di Delitto per delitto» (5. Così Godard recitava all’interno delle Histoire(s du cinéma, e così si apre il saggio di Antonio Costa, prendendone spunto anche per il titolo.

  16. Synthesis and characterization of titanium oxide/bismuth sulfide nanorods for solar cells applications

    International Nuclear Information System (INIS)

    Solis, M.; Rincon, M. E.

    2008-01-01

    In the present work is showed the synthesis and characterization of titanium oxide/bismuth sulfide nanowires hetero-junctions for solar cells applications. Conductive glass substrates (Corning 25 x 75 mm) were coated with a thin layer of sol-gel TiO2 and used as substrates for the subsequent deposition of bismuth sulfide nanorods (BN). TiO2 films (∼400 nm) were deposited with a semiautomatic immersion system with controlled immersion/withdraw velocity, using titanium isopropoxide as the titania precursor [1]. For BN synthesis and deposition, the solvo-thermal method was used, introducing air annealed TiO2-substrates in the autoclave. The typical bilayer TiO2/BN hetero-junction was 600 nm thick. The synthesized materials (powders and films) were characterized by X-Ray Diffraction, Scanning Electron Microscopy, and UV-Visible Spectroscopy. Anatase was the crystalline phase of TiO2, while bismuth sulfide nanotubes show a diffraction pattern characteristic of bismuthinite distorted by the preferential growth of some planes [2-4]. The optoelectronic characterization of TiO2/NB hetero-junctions was compared with hetero-junctions obtained by sensitizing TiO2 with chemically deposited bismuth sulfide films. Bismuth sulfide nanowires are 2µm long and 70nm wide (aspect ratio L/D = 43), while chemically deposited bismuth sulfide have L/D = 1, therefore the effect of particle size evaluation and geometry in the photosensitization phenomena will be discussed in the context of new materials for solar-cells applications. (Full text)

  17. Elucidation on protection mechanism of living body from cellular obstacle due to radiation and its functional obstacle in a highly carcinogenic family

    International Nuclear Information System (INIS)

    Mizutani, Shuki; Asada, Minoru; Takagi, Masatoshi; Yamada, Takayuki

    1999-01-01

    Development of a serologic diagnostic method for patients with ataxia telangiectasia (AT) and its carriers who have abnormalities in AT gene was attempted in this study. The expression of ATM protein was examined in 18 cell lines derived from AT patients of homo-mutant, complex hetero-mutant and asymptomatic hetero mutant. The results showed that the expression of ATM protein was very little in these mutant lines; homo and complex hetero mutants and the rate of its expression in complex-hetero patients presenting with some AT insufficiencies was less than 40% at most. Therefore, diagnosis of AT patients would be possible in future using ATM antibody with some exceptions. In the previous year, the authors reported that lymphocytes derived from AT carriers had some cytological abnormalities, such as p53-phosphorylating activity, apoptosis, etc. However, the expression level of ATM protein in the carrier cells from 9 patients was nearly 60% at most. These results suggest that the use of anti-ATM antibody would allow detection of the carriers of ATM abnormalities and such carriers might include AT patients that can not be assigned into cytologically normal group. Furthermore, it was shown that the expression of ATM protein was decreased and cytological abnormalities were present in normal somatic cells from patients with T cell typed, acute lymphocytic leukemia. Thus, the ATM antibody is thought available for detection of AT carriers, who are difficult to be discriminated from its normally appearing patients. (M.N.)

  18. Asjade seis, viimane vaatus... / Anders Härm, Hanno Soans

    Index Scriptorium Estoniae

    Härm, Anders, 1977-

    2008-01-01

    Muutustest ühiskonnas ja vastuoludest kunstielus pärast kolme üheaegselt toimunud noortenäitust - Härmi-Soansi kureeritud "Uus laine. 21. sajandi Eesti kunstnikud", Non Grata "Uus laine. 21. sajandi kunst" ja Andres Lõo kureeritud "Pomo Sapiens"i, ka näituse kuraatorikontseptsioonidest, Non Grata juhtfiguuridest ja kriitikast

  19. Kahe venna suured ärid / Peeter Raidla, Hanno Tomberg

    Index Scriptorium Estoniae

    Raidla, Peeter, 1955-

    1997-01-01

    Ärimeestest vendade tegevus ja nende osalusega firmad: AS BKE, AS Eferelt, AS Standard, AS Kodax, Eesti Näituste AS, Expodi-Saini AS. Ilmunud ka: Molodjozh Estonii : Kupetsheskaja Gavan 11. apr. lk. 8

  20. See kunst ei ela su korteri seinal! / Hanno Soans

    Index Scriptorium Estoniae

    Soans, Hanno, 1974-

    2009-01-01

    Kiasma näitus "Full House" (17.10.2008-18.01.2009) eksponeeris minimalistlikku kunsti. Näitus oli koostatud kunstikoguja Pentti Kouri kollektsiooni baasil, lisaks oli eksponaate Guggenheimi Muuseumist (New York)

  1. Vähemuste kaudu jõuab kunstnik valgustuseni / Hanno Soans

    Index Scriptorium Estoniae

    Soans, Hanno, 1974-

    2011-01-01

    Tallinna Kunstihoone galeriis 12. juunini 2011 avatud mustlasjuurtega prantsuse videokunstniku Jean-Charles Hue' näitusest "Tattoo Fight", kuraator Harry Liivrand. Kunstnik on tundnud huvi yéniche'i mustlaste ja Tijuana mehhiklaste elumudeli vastu

  2. Palgatöölise perspektiivid rahvusvahelises kunstis / Hanno Soans

    Index Scriptorium Estoniae

    Soans, Hanno, 1974-

    2010-01-01

    Töötemaatikat käsitlev rahvusvaheline näitus "Blue Collar Blues" Tallinna Kunstihoones 31. jaanuarini 2010, kuraator Anders Härm. Lähemalt Santiago Sierra (Hispaania), kunstnikeduo Kennedy Browne'i (Iirimaa) ja Francis Alÿs'e (Belgia, Mehhiko) töödest

  3. La rappresentazione del sogno, due modelli a confronto: la metapsicologia di Sigmund Freud e la teoria del Codice Multiplo di Wilma Bucci

    Directory of Open Access Journals (Sweden)

    Ilaria Bellavia

    2007-09-01

    Full Text Available Obiettivo di questo lavoro è quello di fornire le principali linee di orientamento teorico dell’approccio psicodinamico relative alla funzione del sogno. In tal senso ci si avvarrà della metapsicologia Freudiana, ma anche dei prestigiosi contributi sul carattere del sogno portati da Wilma Bucci. In particolare, si proporrà un parallelismo tra la metapsicologia e la teoria del Codice Multiplo. La teoria energetica di derivazione psicoanalitica mette in risalto alcuni punti cardine sul ruolo del sogno: 1 il sogno deriva dall’energia di un desiderio inconscio; 2 i sogni hanno la funzione di preservare il sonno; 3 la nozione di un censore che si attiva per distorcere e mascherare i contenuti latenti; 4 i contenuti manifesti hanno la funzione di nascondere il reale significato del sogno. Secondo la teoria del codice multiplo, il sogno ha un valore là dove fornisce l’accesso al significato emotivo che è stato dissociato, ma la funzione dell’elaborazione dell’informazione emotiva nel sogno è sovrapponibile a quella dell’elaborazione dell’informazione emotiva durante la veglia, in particolare per quanto riguarda il sonno REM.

  4. Rise and Growth of the Project

    Directory of Open Access Journals (Sweden)

    Monica Abbiati

    2015-06-01

    Full Text Available La presenza di un’importante stratificazione archeologica nella città di Milano è fatto noto da molto tempo e i cantieri che si sono succeduti, segnando la trasformazione urbanistica della città a partire dal secolo scorso, ne hanno dato ampia testimonianza, anche se spesso non accompagnata da adeguata valorizzazione. Le ricerche e gli studi hanno chiaramente individuato i capisaldi urbanistici di Mediolanum, sviluppatasi in vero e proprio centro urbano da un insediamento celtico, a partire dall’epoca augustea, quando furono eretti quegli edifici monumentali (il foro con i suoi annessi, il teatro, le mura, l’anfiteatro necessari allo svolgimento della vita politica, religiosa, economica e sociale dell’epoca. Il panorama monumentale della città si arricchì ulteriormente alla fine del III secolo d.C. quando Mediolanum fu scelta da Massimiano quale sede imperiale, ruolo svolto fino agli inizi del V secolo d.C.: l’ampliamento delle mura, la costruzione del complesso palazzo imperiale – circo e l’edificazione di un imponente complesso termale (Fig. 2 – resero Milano uno delle più importanti città dell’impero romano d’Occidente.

  5. Teatri della memoria: una ricerca sulle mediatiche domestiche

    Directory of Open Access Journals (Sweden)

    Olimpia Affuso

    2011-12-01

    Full Text Available Questo contributo ruota intorno ai risultati di una ricerca collettiva che riguarda i rapporti fra alcuni oggetti della casa e le memorie di chi li raccoglie. Il tema di sfondo della ricerca è molto ampio. Nelle case ci sono mobili e soprammobili, fotografie e manifesti, quadri, e infiniti altri oggetti. Possiamo dire che la casa intera è un deposito di “mnemoteche”, di teche della memoria, che è la stessa disposizione dello spazio domestico a fungere da dispositivo mnestico. Rispetto a tutto ciò, abbiamo scelto quelli che hanno a che fare con il mondo dei media. Ci siamo occupati cioè di come vengono raccolti, selezionati, conservati, usati e scartati oggetti come libri, dischi, videocassette, CD e DVD, e anche file sui computer, telefonini e lettori portatili (audio-video. Si tratta di un insieme di oggetti la cui analisi consente di comprendere sia diversi aspetti dei rapporti che le persone intrattengono con le proprie memorie, sia alcuni dei modi in cui spazi privati e pubblici si interconnettono. Poiché questi prodotti hanno a che fare con le industrie mediali, abbiamo chiamato l’insieme di questi oggetti mediateche domestiche.

  6. Il Conto di Sostituzione nel sistema monetario internazionale. (The substitution account: the problem, the techniques and the politics

    Directory of Open Access Journals (Sweden)

    S. MICOSSI

    2013-12-01

    Full Text Available Il presente articolo sostiene che in una prospettiva a lungo termine molti dei problemi e delle difficoltà che hanno causato il progetto conto di sostituzione ( SA da rottamare non sono così convincenti come in precedenza sembravano essere .  Le ragioni che hanno impedito un accordo dall'essere raggiunto ad Amburgo vengono quindi considerate . La potenziale utilità di un sistema di sostituzione è poi valutata contro la prospettiva di persistenti squilibri nei pagamenti dell'economia mondiale e di un sistema di riserva emergente multi-valuta .The present paper argues that in a longer-term perspective many of the problems and difficulties which caused the Substitution Account (SA project to be scrapped are not as compelling as they previously appeared to be. The authors first review the purposes of the SA before looking at its main technical features. The reasons which prevented an agreement from being reached in Hamburg are then considered. The potential usefulness of a substitution scheme is then assessed agains the prospect of persisting payments imbalances in the world economy and of an emerging multi-currency reserve system. JEL: F33

  7. L’uso delle tecnologie visive per documentare e rappresentare l’impatto di interventi futuri.

    Directory of Open Access Journals (Sweden)

    Laura Galloni

    2010-12-01

    Full Text Available Le tecnologie visuali, e il disegno in particolare, mirano spesso a documentare gli impatti di interventi futuri, essendo esse, per natura, dei mezzi di comunicazione equiparabili al linguaggio, e dunque preposti a descrivere e dimostrare ciò che sta accadendo. Il disegno è, da sempre, il linguaggio universalmente valido e conosciuto: questa sua peculiarità deve far riflettere sulle sue potenzialità. Se da un lato ha la valenza di strumento chiarificatore dall’altro può essere visto come supporto e mezzo preventivo a un miglioramento di interventi futuri, architettonici o ambientali. Come i pittori, da Cimabue a Giotto, da Mantegna a Leonardo, a Raffaello, hanno creato con le loro tele, elevando il livello artistico e culturale del tempo, o i grandi architetti, da Palladio a Bramante fino a Le Corbusier hanno costruito con i loro progetti, così il disegno, material prima di pittori, di architetti, o di chiunque si accinga a realizzare un’idea in fieri, deve assumersi la responsabilità e il compito di “essere un bel disegno”, per migliorare ciò che più riguarda l’uomo: l’ambiente in cui vive.

  8. Efficient Visible Photoluminescence from Self-Assembled Ge QDs Embedded in Silica Matrix

    Institute of Scientific and Technical Information of China (English)

    Alireza Samavati; Zahra Samavati; A.F.Ismail; M.H.D.Othman; M.A.Rahman; A.K.Zulhairun

    2017-01-01

    Measuring the growth parameters of Ge quantum dots (QDs) embedded in SiO2/Si hetero-structure is prerequisite for developing the optoelectronic devices such as photovoltaics and sensors.Their optical properties can be tuned by tailoring the growth morphology and structures,where the growth parameters' optimizations still need to be explored.We determine the effect of annealing temperature on surface morphology,structures and optical properties of Ge/SiO2/Si hetero-structure.Samples are grown via rf magnetron sputtering and subsequent characterizations are made using imaging and spectroscopic techniques.

  9. Dramatic Influence of Ionic Liquid and Ultrasound Irradiation on the Electrophilic Sulfinylation of Aromatic Compounds by Sulfinic Esters

    DEFF Research Database (Denmark)

    Nguyen, Ngoc-Lan Thi; Vo, Hong-Thom; Duus, Fritz

    2017-01-01

    The sulfinylation reaction of aromatic and hetero-aromatic compounds with sulfinic esters as electrophiles has been investigated in different ionic liquids and by means of different Lewis acid salts in order to get moderate to good yields of asymmetrical sulfoxides. Mixtures of 1-butyl-3-methylim......The sulfinylation reaction of aromatic and hetero-aromatic compounds with sulfinic esters as electrophiles has been investigated in different ionic liquids and by means of different Lewis acid salts in order to get moderate to good yields of asymmetrical sulfoxides. Mixtures of 1-butyl-3...

  10. Uus glamuur : Foorumi ärikeskus = Fresh Glamour : the Foorum Business Centre in Narva maantee / Inga Raukas

    Index Scriptorium Estoniae

    Raukas, Inga, 1967-

    2007-01-01

    Projekteerija: HG Arhitektuur OÜ. Autorid: Hanno Grossschmidt, Tomomi Hayashi. Konstruktor: Neoprojekt OÜ. Sisekujundajad: äritänav, Cafe Peterson - Kohvi OÜ, korterid - Kadri Tamme, Argentiina restoran - Ruumilabor OÜ, St.Patricks - SAB Link OÜ, hoone üldruumid - HG Arhitektuur OÜ. Kortereid 193. Projekt 2004-2006, valmis 2007. Asendiplaan, I korruse plaan, lõige, 4 värv. välis- ja 2 sisevaadet. Bibliograafia lk. 50

  11. Il teatro degli spiriti.

    Directory of Open Access Journals (Sweden)

    Chiara Pussetti

    2013-07-01

    Full Text Available Questo saggio è dedicato a un culto di possessione, in cui tutte ledonne, investite dagli spiriti degli uomini morti prima dell’iniziazione, compiono un percorso iniziatico parallelo a quello maschile, consentendo a queste anime, potenzialmente pericolose, di completare il cammino che non hanno potuto percorrere da vivi e quindi di raggiungere serenamente il mondo dei morti, come antenati protettori del villaggio

  12. Geografia elettorale dell’Emilia Romagna: una cartografia interattiva delle elezioni politiche dal 1976 al 1992

    Directory of Open Access Journals (Sweden)

    Marianna Pino

    2013-05-01

    Full Text Available La rappresentazione cartografica del comportamento elettorale dell’Emilia Romagna può essere un utile strumento di analisi delle traiettorie dei partiti nel cruciale passaggio tra la prima e la seconda Repubblica. La mappatura interattiva, infatti, permette di leggere e comparare su scala comunale i risultati dei maggiori partiti che hanno partecipato alle cinque elezioni politiche tenutesi tra il 1976 e il 1992.

  13. Scienze umane aperte

    Directory of Open Access Journals (Sweden)

    Maria Chiara Pievatolo

    2012-04-01

    Full Text Available L’espressione digital humanities  viene solitamente tradotta come “informatica umanistica”. Secondo Eric Johnson, bibliotecario, le definizioni recenti di questa disciplina in verità non così nuova sono accomunate da una caratteristica: non hanno nulla a che vedere con l’informatica. Intendono infatti se stesse secondo principi così ampi e programmatici da rischiare di apparire retorici: collaborazione, spirito inclusivo, [...

  14. Formaatidevaheline kunstisündmus

    Index Scriptorium Estoniae

    2003-01-01

    1. XI Kanuti gildis üritusteseeria "1+1=1" hooaja avaüritus. Esinevad kuraatorid Hanno Soans ja Andres Lõo (võrguväljaande www.looming.org tutvustus), Ieva Auzina (Läti, Haralds Elcerise film "Matti Miliuse hull manifest" (1988) jm.), Suzanne van de Ven (Kassel). A. Lõo, Kiwa, Joanne Richardson (Rumeenia), Enrico Glerean (Itaalia) esinevad heliloenguga, Ene- Liis Semper, Mark Raidpere, Jaan Toomik videoportreedega

  15. Fisica. I progressi nello studio delle particelle piu' abbondanti ma piu mistriose

    CERN Multimedia

    Bilenky, Samoil Mikhelevich

    2003-01-01

    "Caccia ai neutrino conferme all'inutizione di Pontecorvo: hanno una masa (sia pure minima) e i loro 3 tipi si mutano l'uno nell'altro fisica i progressi nello studio delle particelle piu' abbondanti ma piu' misteriose". [The hunt for the neutrinos. Pontecorvo's theory has been confirmed: the neutrino has a mass (though minimal). It switches from one of the 3 types into the others].

  16. In memory of Gaetano Fichera

    Directory of Open Access Journals (Sweden)

    Francesco Nicolosi

    2007-12-01

    Full Text Available Sono raccolte in questo Volume alcune delle conferenze svolte durante il 3^o Simposio Internazionale Problemi Attuali dell’Analisi e della Fisica Matematica, dedicato alla memoria di Gaetano Fichera, che si è svolto a Taormina dal 29 Giugno al 1 Luglio, 2006. Hanno partecipato al Simposio più di cinquanta studiosi italiani e stranieri (cfr. Elenco dei Partecipanti. Sono state svolte trentasette relazioni.

  17. Kohta määratledes : Lootsi maja, Lootsi tn. 3A, Tallinn = Redefining the Site : Lootsi House, Lootsi St. 3A, Tallinn / Tomomi Hayashi

    Index Scriptorium Estoniae

    Hayashi, Tomomi, 1971-

    2006-01-01

    Tallinna praeguse sadamaala ja kiire arengu probleemidest. Y-kujulise põhiplaaniga Lootsi majast, mis on mõeldud noortele ja kesklinnas elada eelistavatele pensionäridele. Projekteerija: HG Arhitektid OÜ. Autorid: Hanno Grossschmidt, Tomomi Hayashi. Konstruktor: OÜ Projektbüroo Teinos. Tellija: Lootsi kinnisvara OÜ. Ehitaja: KMG Ehitus. Projekt ja ehitus: 2003-2005. Ill.: tüüpkorruse plaan, 5 värv. välisvaadet

  18. Lasnamäe Kergejõustikuhall : Punane tn. 45, Tallinn = Lasnamäe Track and Field Centre / Tomomi Hayashi

    Index Scriptorium Estoniae

    Hayashi, Tomomi, 1971-

    2004-01-01

    Arhitektid, sisekujundus: Siiri Vallner, Hanno Grossschmidt, Tomomi Hayashi (COO Arhitektid / Head Arhitektid). Peatöövõtja: Arhitektuuribüroo Rein Murula. Peatöövõtja, ehitaja: Eesti Ehitus. Konstruktor: TA-Konsult. Projekt 2001-2002, valmis 2003. 4 välis- ja 3 sisevaadet, I ja II korruse plaan. Hoonet tunnustati Eesti Kultuurkapitali 2003. a. objektipreemia ja Eesti Betooniühingu 2003. a. eriauhinnaga

  19. Sintesi stereoselettiva di piridilammine

    OpenAIRE

    Chelucci, Giorgio Adolfo; Baldino, Salvatore; Pinna, Gérard Aimé; Soccolini, Francesco

    2006-01-01

    Ammino piridine chirali hanno dimostrato la loro validità come leganti per la formazione di complessi metallici utilizzati nella catalisi asimmetrica. Tra i possibili approcci alla sintesi di questi composti noi abbiamo investigato la riduzione diastereoselettiva di N-sostituite (p-totil e tert-butil) piridil chetimmine con una serie di agenti riducenti (NaBH4, L-Selectride, DIBAL, 9-BBN) in diverse condizioni di reazione.

  20. National security and the impact of cyber threats on the average citizen

    CSIR Research Space (South Africa)

    Jansen van Vuuren, JC

    2010-09-01

    Full Text Available LinkedIn account Work information Company name Intecon Occupation Programmer Colleagues Trevor Mohasoa ? Help desk Marista Conradie ? Receptionist and Personal Assistant Personal information Email address and username/alias einad5@gmail....com Contacts Stephen Swart Justin Booth Ivan Burke Francois Joubert Nicolaas Strecker Hanno Combrink Data gathered from Google profile and gmail email address ? Information gathered from Google Buzz account ? Operating System preference (complains...

  1. Valutazione degli elementi di struttura e monitoraggio microbiologico nel Comparto operatorio comune del Dipartimento ortopedico dell'Azienda ospedaliera di Parma

    Directory of Open Access Journals (Sweden)

    C. Pasquarella

    2003-05-01

    Full Text Available Obiettivi: scopo di questo studio, che si inserisce nell’ambito di un progetto multicentrico promosso dal Gruppo Italiano Studio Igiene Ospedaliera, è stato quello di valutare le condizioni ambientali e gestionali delle sale operatorie del comparto ortopedico dell’Azienda ospedaliera di Parma. Metodi: l’indagine, svolta nell’ottobre 2002, ha previsto la compilazione di un questionario, riguardante gli aspetti strutturali, impiantistici, organizzativi e gestionali, e l’effettuazione di un monitoraggio microbiologico ambientale nelle diverse aree del blocco operatorio. La carica microbica dell’aria è stata valutata utilizzando piastre di sedimentazione per la rilevazione dell’Indice Microbico Aria (IMA mentre per le superfici sono state impiegate membrane di nitrocellulosa. I campionamenti sono stati effettuati prima dell’inizio e durante l’attività chirurgica. Risultati: i dati ottenuti per mezzo del questionario hanno evidenziato condizioni generalmente buone, sia dal punto di vista strutturale che gestionale del comparto operatorio studiato. Per quanto riguarda il controllo microbiologico, nelle sale operatorie, in tutte le rilevazioni prima dell’attività si sono ottenuti valori di IMA uguali a 0; durante l’attività, si è registrato un valore massimo di IMA di 4 in quelle a flusso laminare e di 19 in quelle con flusso turbolento, al di sotto dei valori limite, rispettivamente di 5 e 25; i valori di contaminazione microbica delle superfici prima dell’attività hanno oscillato da un minimo di 0 ufc/cm2 a un massimo di 0,20 ufc/cm2; durante l’attività, solo in una rilevazione si è registrato un valore di 0,58 ufc/cm2, superiore al valore soglia stabilito. Anche negli altri ambienti del comparto operatorio la contaminazione microbica è risultata complessivamente al di sotto dei limiti di riferimento. Conclusioni: il questionario si è rivelato un valido strumento

  2. Monza nelle pellicole cinematografiche. Una risorsa da dilatare / Monza in films. An asset to promote

    Directory of Open Access Journals (Sweden)

    Marisa Malvasi

    2016-05-01

    Full Text Available Monza offrirebbe diverse location per far da sfondo a chi voglia girare un film. Eppure, la scelta dei produttori è caduta quasi esclusivamente sull’Autodromo e sulla Villa Reale ed ovviamente sulle numerose testimonianze esistenti in città circa la Monaca di Monza, nella quale la città si identifica tout court. C’è, comunque, da osservare che piuttosto scarso sembra, a tutt’oggi, l’interesse dei monzesi verso il cineturismo. Parecchi sono, infatti, i film che hanno come sfondo l’Autodromo, ma, fa notare qualcuno, potrebbero essere molti di più. E, forse, questo dipende da quel rapporto di amore-odio che i cittadini hanno da sempre con il famoso circuito del Gran Premio di Formula 1. Va bene che il cineturismo è ancora un fenomeno ai suoi esordi, ma è ugualmente vero che, e questo vale in particolare per l’Autodromo, non si fa altro che esaltare, una volta di più, proprio un aspetto del capoluogo brianzolo che già i mass-media hanno contribuito a diffondere nelle varie contrade del mondo.   Monza could offer different locations as background for one who wants to make a film. And yet producer's choice has been almost exclusively made in favour of Autodromo (Formula 1 Car Race Circuit and Villa Reale (Royal Castle such as, obviously, of the numerous still existing evidences about Monaca di Monza (Nun of Monza, character into which the town is tout courtidentified. However, we have to observe that up till now Monza townpeople care about tourism cinema remains poor. Numerous remain, as a matter of fact, films which have the Autodromo as background but, as somebody suggests, they could be much more. And, maybe, this depends on love - hate relationship that uninterrupedly Monza citizens demonstrate with regard to Formula ! Grand Prix Circuit. It is true that tourism cinema is for the time being a new phenomenon, but it is in the same way true that, particularly for Autodromo, the aspect already diffused by mass - media all over

  3. Polystyrene star-shaped polymers made by the new In-Inmethod

    International Nuclear Information System (INIS)

    Fazeli, N.; Afshar Toromi, F.

    2002-01-01

    Three main methods are usually used for the synthesis of star-shaped polymers, where each one has its own advantages and disadvantages. Among these techniques, i n-out m ethod is the best one to produce hetero arm star polymers with narrow molecular weight distribution and long arms with active sites at the end of the second-generation arms. This method, however, has some difficulties during the synthesis of hetero-arm star polymers with styrene or dienes as the second monomers. The reason is that in the o ut s tep, the carbanions of the growing chain attack the existing double bonds of the other cores and produce an irreversible gel. The new i n-in m ethod mentioned in this paper, is used to synthesize double-star polystyrene polymers with relatively narrow molecular weight distribution and without occurrence of any gelation during the process. With the monomers, which are able to attack the existing double bonds of the cores of the star polymers, it is also possible to produce-hetero-arm star polymers using this new method

  4. Studies on the hydroprocessing of deashed oil. 10. ; Comparison of the reaction performance between pilot plant and BSU. Deashed oil no suisoka bunkai hanno ni kansuru kenkyu. 10. ; Pilot to bench hanno sochi no hanno tokusei no hikaku

    Energy Technology Data Exchange (ETDEWEB)

    Hijiriyama, M.; Kaneko, T. (Mitsubishi Kasei Co., Tokyo (Japan)); Kageyama, Y. (Nippon Brown Coal Liquefaction Co. Ltd., Tokyo (Japan))

    1990-11-29

    The secondary hydroprocessing process in the two-stage hydrogenating liquefaction equipment under development at Nippon Brown Coal Liquefaction Company uses a fixed bed system. This paper describes operation of a bench reaction equipment using catalyst used in the pilot plant to compare it with fresh catalyst, and compare characteristics of the bench scale equipment with those of the pilot reactor. The catalyst is Ca-Ni-No/Al2O. The reaction was carried out in a gas-liquid downward parallel-flow fixed-bed reactor using deashed oil (DAO) with the same material as that used in the pilot plant and the same equilibrium solvent. The experiment result indicates that the used catalyst had its activity fallen below the fresh catalyst, but its temperature dependence was identical, and the selectivity on products of both catalysts was also identical. The result of reactions in the bench scale equipment clarified that the relationship between the DAO conversion rate and denitrogenation activity and the relationship between fa and H/C in the products are in good agreement, and that there is no difference in reaction selectivity. 5 refs., 6 figs., 1 tab.

  5. Desolvation of L-histidine and {alpha}-ketoisocaproic acid complex from ethanolate crystals under humidified conditions and influence of crystallinity on its desolvation; Histidine Ketoisocapron san ensan ethanol wamono kessho no koshitsudo jokenka deno datsu ethanol to datsu ethanol sei ni oyobosu kesshosei no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Kishimoto, S.; Tanabe, T.; Maruyama, S.; Kishishita, A.; Nagashima, N. [Ajinomoto Co. Inc., Tokyo (Japan)

    1996-07-10

    Desolvation of L-histidine and a-ketoisocaproic acid complex from ethanolate crystals was investigated. The ethanolate crystals were obtained from ethanol aqueous solutions of above 60 wt% of ethanol. It was difficult to remove ethanol molecules from the crystals lay vacuum drying. However, it was found that ethanol molecules in the crystal lattice could be released under humidified conditions, for example, 313 K and 60% relative humidity, accompanied by transformation to non-solvated crystals. When the peak of 2{theta}=9.0{degree}(CuK{alpha} radiation) in powder X-ray diffraction pattern of the ethanolate crystals was weak, ethanol molecules (about 1wt.%) remained in the crystals at the end of transformations and then the residual ethanol decreased slowly. A controlled moderate cooling process, where the supersaturation is released slowly, is the key point to obtain ethanolate crystals having high `crystallinity` (defined as peak height of 2{theta}=9.0{degree}) which shows quick desolation rather than adding ethanol for a rapid increase of supersaturation in crystallization. 6 refs., 7 figs.

  6. Kõrged maksud paisutavad mõttetult töötukasa reserve / Vahur Koorits

    Index Scriptorium Estoniae

    Koorits, Vahur, 1981-

    2010-01-01

    Sotsiaalministri ja Töötukassa nõukogu esimehe Hanno Pevkuri sõnul tuleks kaaluda töötuskindlustuse makse langetamist 2012. aastast, töötukassa nõukogus ametiühinguid esindava Harri Taliga arvates võiks töötuskindlustuse makseid vähendada juba 2011. aastal, tööandjaid esindava Tarmo Kriisi arvates võiks maksemäära alles paari aasta pärast arutama hakata. Graafik

  7. Mondi possibili

    CERN Document Server

    Dyson, Freeman

    1998-01-01

    Scienza, fantascienza, storia. Freeman Dyson percorre con sicurezza, acume e spirito critico i sentieri che conducono al futuro del nostro mondo ; ci fa scorgere i pericoli e le insidie del progresso scientifico e tecnologico, ci narra le vicende che hanno caratterizzato la scienza e la cultura del nostro secolo e si misura con le grandi questioni che gli scienziati e l'umanita dovranno affrontare agli inizi di un nuovo millenio.

  8. Aasta Betoonehitis 2003 - elamu mere kaldal / Enno Rebane

    Index Scriptorium Estoniae

    Rebane, Enno, 1964-

    2004-01-01

    2003. a. parim betoonehitis - arhitekt Emil Urbeli kavandatud eramu (projekteerija TA Konsult OÜ, betoonitööde teostaja Mapri Projekt OÜ). Eriauhinna arhitektuurse lahenduse eest sai Siiri Vallneri, Hanno Grossschmidti ja Tomomi Hayashi kavandatud Lasnamäe spordihoone (projekteerija TA Konsult OÜ, ehitasid Eesti Ehitus OÜ, AS E-Betoonelement - ka betoonisegu tarnija) ja betoonitehnoloogia eest AS E-Betoonelement Ekseko seafarmi sõnnikuhoidla eest Viljandimaal. IV betoonipäevast

  9. Osobnjak na beregu morja - lutshsheje betonnoje strojenije 2003 goda / Enno Rebane

    Index Scriptorium Estoniae

    Rebane, Enno, 1964-

    2004-01-01

    2003. a. parim betoonehitis - arhitekt Emil Urbeli kavandatud eramu (projekteerija TA Konsult OÜ, betoonitööde teostaja Mapri Projekt OÜ). Eriauhinna arhitektuurse lahenduse eest sai Siiri Vallneri, Hanno Grossschmidti ja Tomomi Hayashi kavandatud Lasnamäe spordihoone (projekteerija TA Konsult OÜ, ehitasid Eesti Ehitus OÜ, AS E-Betoonelement - ka betoonisegu tarnija) ja betoonitehnoloogia eest AS E-Betoonelement Ekseko seafarmi sõnnikuhoidla eest Viljandimaal. IV betoonipäevast

  10. Attività antimicrobica, antivirale ed immunomodulante di peptidi anticorpali

    OpenAIRE

    Ciociola, Tecla

    2011-01-01

    Il progetto complessivo si è proposto di studiare le potenzialità immunoterapeutiche ed immunomodulanti di peptidi sintetici di derivazione anticorpale. I peptidi correlati ai CDR e molti decapeptidi, rappresentanti la regione variabile di un Ab anti-idiotipico ricombinante immagine interna di una tossina killer di lievito, hanno esibito attività fungicida in vitro nei confronti di Candida albicans. Un derivato alaninico di un decapeptide candidacida ha mostrato una incrementata efficacia ter...

  11. Towards a national system of teaching qualifications in higher education in The Netherlands

    OpenAIRE

    van Keulen, H.; van Alst, J.; de Jong, R.; Halma, A.

    2006-01-01

    2005 6th Conference of the International Consortium for Educational Development Enhancing Academic Development Practice: International Perspectives 1. Contact Name: Hanno van Keulen 2. Title: Dr 3. Institution(s): Utrecht University 4. Department: IVLOS Institute of Education 5. Address for correspondence: PO Box 80127 6. Country: The Netherlands 7. Postcode/Zipcode: 3508 TC Utrecht 8. Telephone: +31 30 253 1718 (office) / +31 6 5213 8991 (GSM) 9. Email: 10. Title and ...

  12. Dai fuseaux ai leggings, dal crème caramel ai cupcakes: l’inglese alla conquista della moda e della cucina italiane

    OpenAIRE

    Università degli Studi di Trieste

    2017-01-01

    Video della lezione Cosa rappresenta il made in Italy più della moda o della cucina? Probabilmente nulla: l’immagine che gli stranieri hanno degli italiani è quella di un popolo maniaco dell’eleganza e del buon cibo. Eppure, quando parliamo di questi argomenti, usiamo sempre un gran numero di parole straniere, negli ultimi anni soprattutto inglesi. Vedremo alcuni esempi di questa invasione e cercheremo di spiegarne il perché.

  13. Il patrimonio scomodo del Novecento europeo nel progetto Atrium a Forlì

    Directory of Open Access Journals (Sweden)

    Elena Pirazzoli

    2013-09-01

    Full Text Available Il Novecento ha lasciato tracce difficili nelle città d'Europa. I regimi che si sono succeduti hanno trasformato urbanisticamente e architettonicamente l'intero territorio e oggi è complesso relazionarsi con questi segni. Il progetto europeo Atrium - Architecture of Totalitarian Regimes in Urban Managements si propone di valorizzare, con attenta cura e senza intenti mistificatori, proprio il “patrimonio scomodo” di 11 paesi dell'Europa del sud.

  14. [Trattamento della dipendenza da alcol. Alcol e persone senza fissa dimora: punto di vista sociale].

    Science.gov (United States)

    Alessandrini, Giovanni; Ciccarelli, Rosaria; Battagliese, Gemma; Cereatti, Federica; Gencarelli, Simona; Messina, Marisa Patrizia; Vitali, Mario; De Rosa, Francesca; Ledda, Roberta; Mancini, Serena; Attilia, Maria Luisa

    2018-01-01

    RIASSUNTO. Il fenomeno delle persone senza fissa dimora sta assumendo in questi anni una rilevanza sociale devastante, con una prevalenza stimata in USA e in Europa compresa tra il 5,6% e il 13,9%. Queste persone hanno una scarsa qualità di vita, una limitata o assente vita sociale, sono spesso disoccupate o lavorano solo saltuariamente. Sono a rischio di problemi con la legge, sono spesso affette da dipendenza da droghe, da patologie psichiatriche e internistiche. L'alcol spesso non rappresenta la causa della loro condizione sociale, ma solo la conseguenza, contribuendo in questo modo al loro degrado bio-psico-sociale. Nel 2009 lo US Department of Housing and Urban Development's Homelessness Assistance Programs e nel 2010 la European Consensus Conference on Homelessness hanno segnato un grande passo avanti nella riabilitazione sociale di queste persone, utilizzando il concetto del "case management". In particolare lo Standard Case Management si è dimostrato in grado di migliorare la stabilità abitativa, di ridurre l'uso di droghe e di rimuovere le barriere lavorative. L'Assertive Community Treatment si è dimostrato, invece, in grado di migliorare la stabilità abitativa e ha un rapporto costo/beneficio migliore per i pazienti affetti da doppia diagnosi.

  15. La “grande bellezza” del paesaggio italiano nel cinema contemporaneo: tra falsificazione e finanziamento locale / The “great beauty” of Italian landscape in contemporary movies: between falsification and local funding

    Directory of Open Access Journals (Sweden)

    Eleonora Mastropietro

    2016-05-01

    Full Text Available I film hanno rappresentato l’evoluzione del paesaggio italiano per gran parte del novecento. Negli ultimi due decenni i film italiani hanno però smesso di esplorare le trasformazioni del territorio. La debolezza dell’industria cinematografica spiega in parte l’assenza del contemporaneo dagli schermi. Inoltre il diffuso ricorso al supporto economico degli enti pubblici, che spesso vedono i film come strumenti di promozione turistica, sembra influenzare le modalità di rappresentazione del paesaggio. Il contributo presenta una ricerca condotta sui film di maggior successo tra il 1990 e il 2014 alla ricerca dell’immagine del paesaggio italiano in essi prevalente e evidenzia alcune cause alla base di questa rappresentazione omogenea. Films have portrayed the evolution of the Italian urban landscape in the last 100 years. Nevertheless, contemporary movies partially ignore the recent transformations and represent instead a stereotyped image of Italian landscapes. The structure of the local movie industry could provide a first explanation of this phenomenon. Moreover, the financial support of productions provided by local government influences the choice of including or excluding elements of the landscape in the movies screen. The paper explores the new representations of landscape in Italian movies, in order to show which features of the changing contemporary Italian landscapes are visible and which are hidden.

  16. Il commercio dei captivi nel Mediterraneo di età moderna (secc. XVI - XVIII. Orientamenti e prospettive attuali di ricerca

    Directory of Open Access Journals (Sweden)

    Bosco, Michele

    2014-02-01

    Full Text Available Da oltre un ventennio, il tema della guerra da corsa e quello del commercio dei captivi nel Mediterraneo di età moderna, ad esso strettamente connesso, sono oggetto di rinnovato interesse da parte della storiografia internazionale. Soprattutto in Italia, Spagna e Francia (ma anche altrove, ricerche sistematiche hanno permesso di ricostruire diversi aspetti della schiavitù nel Mediterraneo di età moderna: modalità della cattura, condizioni di vita dei prigionieri, riscatti, conversioni. Non solo storici, ma anche antropologi, economisti, storici delle religioni e del diritto hanno dato il loro contributo alla ricerca, tradottosi in raccolte di saggi o in volumi monografici; tale abbondante produzione ha innanzitutto mostrato chiaramente come la guerra da corsa e il commercio dei captivi abbiano rappresentato a lungo un elemento cruciale della storia dei paesi che si affacciano sul Mediterraneo, dal medioevo all’età moderna, giungendo fino ai primi decenni del secolo XIX. Nelle prossime pagine proveremo a ricostruire, a grandi linee, l’evoluzione del dibattito storiografico sull’argomento, in modo da far emergere le questioni ancora aperte e di individuare nuovi possibili percorsi di indagine, che sfruttino in particolare le serie documentarie ancora scarsamente utilizzate o meritevoli di ulteriori ricerche.

  17. “My big statement”: art, political experience and the quest for identity in Alex Kuo's Chinese Opera

    Directory of Open Access Journals (Sweden)

    Fulvia Sarnelli

    2015-11-01

    Full Text Available Il saggio considera l'esperienza politica degli intellettuali cinesi e americani in Chinese Opera (1998, romanzo breve dello scrittore americano di discendenza cinese Alex Kuo. Il suo protagonista, compiendo un viaggio dagli Stati Uniti alla Cina nei mesi immediatamente precedenti alle dimostrazioni di piazza Tiananmen, intraprende un cammino alla ricerca della sua storia familiare, e delle ragioni che hanno spinto il padre all'esilio. Intellettuale e musicista, a cavallo tra due realtà di attivismo politico che hanno esercitato il loro peso nel definire o nello smantellare, a seconda delle prospettive, proprio i concetti di appartenenza, il protagonista sceglie e fa proprio l'impegno sul piano transnazionale, ma a partire da una consolidata quanto rivendicata consapevolezza della propria individualità. La letteratura e l'arte sono il punto focale in grado di esprimere una tensione tra l'individuo e la collettività che ritorna con una declinazione diversa in entrambi i sistemi socio-politici. Il romanzo, dunque, propone un soggetto politicizzato ma non contenibile all'interno di alcuna coordinata discorsiva pre-scritta. A sua volta, il discorso politico nel testo letterario, costruito nel senso della double critique di Khatibi, intreccia la dimensione pubblica e privata dell'intellettuale con le significazioni etniche, nazionali e transnazionali.

  18. Long-term monitoring of Pyrenean chamois in a protected area reveals a fluctuating population

    Directory of Open Access Journals (Sweden)

    Pau Pañella

    2011-02-01

    Full Text Available Monitoraggio a lungo termine del camoscio dei Pirenei in una zona protetta: fluttuazione della popolazione.
    Tra il 1993 ed il 2009, la popolazione di camoscio pirenaico Rupicapra p. pyrenaica del Parco Nazionale d’Aigüestortes e Estany de Sant Maurici (14119 ha, Catalogna, Spagna è stata monitorata periodicamente. Nel periodo post-riproduttivo (luglio, i censimenti sono stati condotti lungo 20 percorsi supraforestali fissi, con l’obiettivo di stimare le variazioni nelle dimensioni, rapporto sessi, struttura e produttività della popolazione nell’area protetta. La densità media è risultata pari a 6,7 camosci km-2, il rapporto sessi circa 1:3 in favore delle femmine, mentre la produttività è stata pari a 0,6 juvenes per femmina adulta. La proporzione di animali indeterminati durante i conteggi è diminuita significativamente nel tempo, probabilmente in seguito al progressivo training degli operatori. Nel periodo di studio, le dimensioni della popolazione sono fluttuate significativamente. Sebbene le cause di tali variazioni siano ancora da approfondire, le successive epidemie di cheratocongiuntivite infettiva e Pestivirus che hanno colpito la popolazione hanno probabilmente svolto un ruolo determinante. Si raccomanda di sviluppare un piano di gestione dell’intero massiccio montuoso, che includa regolari monitoraggi sanitari e conteggi autunnali.

  19. 3D hierarchical assembly of ultrathin MnO2 nanoflakes on silicon nanowires for high performance micro-supercapacitors in Li- doped ionic liquid

    Science.gov (United States)

    Dubal, Deepak P.; Aradilla, David; Bidan, Gérard; Gentile, Pascal; Schubert, Thomas J.S.; Wimberg, Jan; Sadki, Saïd; Gomez-Romero, Pedro

    2015-01-01

    Building of hierarchical core-shell hetero-structures is currently the subject of intensive research in the electrochemical field owing to its potential for making improved electrodes for high-performance micro-supercapacitors. Here we report a novel architecture design of hierarchical MnO2@silicon nanowires (MnO2@SiNWs) hetero-structures directly supported onto silicon wafer coupled with Li-ion doped 1-Methyl-1-propylpyrrolidinium bis(trifluromethylsulfonyl)imide (PMPyrrBTA) ionic liquids as electrolyte for micro-supercapacitors. A unique 3D mesoporous MnO2@SiNWs in Li-ion doped IL electrolyte can be cycled reversibly across a voltage of 2.2 V and exhibits a high areal capacitance of 13 mFcm−2. The high conductivity of the SiNWs arrays combined with the large surface area of ultrathin MnO2 nanoflakes are responsible for the remarkable performance of these MnO2@SiNWs hetero-structures which exhibit high energy density and excellent cycling stability. This combination of hybrid electrode and hybrid electrolyte opens up a novel avenue to design electrode materials for high-performance micro-supercapacitors. PMID:25985388

  20. Editoriale / Editorial

    Directory of Open Access Journals (Sweden)

    Balloni Augusto

    2011-12-01

    Full Text Available Nel 1991 si è costituita la nostra Società Italiana di Vittimologia (S.I.V. e in questi vent’anni molte attività hanno attirato interesse da parte di diversi settori: si sono sviluppati rapporti con istituzioni del territorio e con organizzazioni nazionali e internazionali; inoltre la Rivista di Criminologia, Vittimologia e Sicurezza è diventata un importante strumento per il giusto riconoscimento e la necessaria visibilità delle vittime.

  1. The Magic Background of Pearl Harbor. Volume 4. Appendix

    Science.gov (United States)

    1977-01-01

    validita dei detti accorde ed hanno all nopo convenuto quanta segue. Articolo 1. II patto contra d’internazional communista, che resulta dall accordo...decoirere dal25 Novembre 1941. Articol 2. Gli stati che in seguito ad invito del Regio Governo Italiano, del Governo del Reich Germanico e de patto control...l’Internazional Comunista, si propongono di aderire a questo patto , transmetteranno per iscritto Ie lara dichiarazioni di adesione al Governo del Reich

  2. Genomica avanzata per lo studio dei geni di resistenza a patogeni in pianta

    OpenAIRE

    Sanseverino, Walter

    2009-01-01

    I geni di resistenza hanno grossa importanza nel settore della genetica vegetale e del miglioramento genetico. Le loro caratteristiche genetiche e strutturali li rendono interessanti sia da un punto di vista scientifico sia nell’ottica di un loro utilizzo pratico. Sono una famiglia affascinante da studiare e capire i loro meccanismi evolutivi e di interazione con altre proteine rappresenta una sfida per il chiarimento di molte caratteristiche molecolari e di funzionamento. Questo studio propo...

  3. Mõistuse hääl = Making Sense / Klaske Havik

    Index Scriptorium Estoniae

    Havik, Klaske, 1975-

    2004-01-01

    Naisarhitektide loomingust, kehalisest kogemusest arhitektuurses kujunduses, muutustest Tallinna linnaruumis ja uutest avalikest hoonetest. Okupatsioonide muuseumist (Siiri Vallner, Indrek Peil), selle vastavusest kaasaegse avaliku ruumi arusaamadele. Lasnamäe Spordihoonest (S. Vallner, Tomomi Hayashi, Hanno Grossschmidt). Sookesksest lähenemisest naistest koosneva büroo Kavakava, kus praegu töötab S. Vallner, loomingu puhul. Kavakava üks viimaseid projekte - Pärnu gümnaasiumi arhitektuurikonkursi võistlustöö. Bibliograafia lk. 15

  4. Digital Marketing

    OpenAIRE

    Stefano Pace; Margherita Pagani; Silvia Vianello

    2011-01-01

    Lo sviluppo di nuove modalità di commercio elettronico via web, le nuove piattaforme di Tv digitale interattiva (t-commerce) e le applicazioni mobili (m-commerce) hanno suscitato rilevante attenzione allo studio del comportamento del consumatore nei nuovi contesti digitali. Per le aziende è rilevante comprendere i fattori che influenzano l’intenzione di acquisto e adozione dei beni e servizi online da parte dei consumatori e il comportamento di fruizione delle singole piattaforme digitali...

  5. Alle origini della conservazione del paesaggio in Belgio: il contributo originale di Louis Van der Swaelmen

    OpenAIRE

    Rapalo, Maria Chiara

    2017-01-01

    La ricerca che si propone si inserisce nell’ambito di alcuni studi condotti nel quadro di una collaborazione Italia-Belgio sulle tematiche della conservazione e tutela dei beni architettonici e del paesaggio, collegate e talvolta intrecciate a quelle dell’urbanistica. Essa nasce dall’esigenza di comprendere gli interessanti e meno approfonditi contributi che, in ambito belga, hanno concorso al delinearsi delle attuali linee di orientamento internazionale nel campo della conservazione e della ...

  6. Tallinna Fotokuu 2015 / Karin Kahre

    Index Scriptorium Estoniae

    Kahre, Karin

    2015-01-01

    Tallinna Fotokuu 2015 programmist. Näitus "Prosu(u)mer" Eesti Kaasaegse Kunsti Muuseumis, kuraator David Raymond Conroy. Näitus "Aegvõte. Time Lapse" Tallinna Kunstihoones, kuraator Anna Laarits. Näitus "Võrdlev sissevaade 1990. aastate üleminekuaja Balti fotokunsti" Tallinna Kunstihoone galeriis, kuraator Tanja Muravskaja. Duo-näitus "Leegi vari" Tartu Kunstimajas, kunstnikud Tarvo Hanno Varres ja Kirke Kangro. Näitus "Plahvatusest tasandikule. Eesti kaasaegne foto 1991-2015" Taru Kunstimuuseumis, kuraator Anneli Porri

  7. Il diritto all’assistenza linguistica dell’imputato straniero nel procedimento penale. Indagine conoscitiva presso il tribunale di Trieste

    OpenAIRE

    Mometti, Francesca

    2014-01-01

    Interviste a magistrati in servizio presso il Tribunale di Trieste e a interpreti/traduttori attivi presso la stessa istituzione hanno consentito di far emergere in che misura e attraverso quali pratiche venga garantito il diritto all’assistenza linguistica in ambito penale. L’incrocio tra i dati derivanti dall’analisi di un campione di fascicoli di liquidazione e quelli relativi ad alcuni fascicoli dibattimentali ha rivelato come si concretizzi nella prassi quotidiana la garanzia del diritto...

  8. Reportaaž välitöödelt / Hanno Soans

    Index Scriptorium Estoniae

    Soans, Hanno, 1974-

    2011-01-01

    NU Performance Festival IV: Külalislahkusest / On Hospitality Tallinnas Viru hotellis 7.-10.11. 2011, kuraatorid Silke Bake ja Peter Stamer (Saksamaa). Lähemalt rühmituse deepblue (Heine Rødal Avdal, Yukiko Shinozaki) etendusest "Field Works - hotel", grupi toxic dreams (Yosi Wanunu, Michael Strohmann) õhtusöök-performance'ist, 10 kunstniku etendusest "The Love Piece", kanadalaste trupi PME-ART-i etendusest "Külalislahkus 3: individualism oli viga"

  9. Klubi "Spirit" = Club Spirit / Hanno Soans ; tõlk. Liisi Ojamaa

    Index Scriptorium Estoniae

    Soans, Hanno, 1974-

    2000-01-01

    Eesti klubikultuurist 1990-ndatel. Klubi "Spirit" kujundusest. Sisearhitektid Tarmo Piirmets, Martti Siimann. Arhitekt Jüri Irik Arhitektuuribüroost Ehala & Irik. Projekt ja klubi valmis 2000. Flaierid kujundas Aadam Kaarma. 10 ill. Vaated, korruste plaanid

  10. Kaasaegse kunsti muuseum suurendab panuseid - Köler Prize / Hanno Soans

    Index Scriptorium Estoniae

    Soans, Hanno, 1974-

    2011-01-01

    Eesti Kaasaegse Kunsti Muuseumi loodud kaasaegse kunsti preemiast. 6. juunini EKKM-is avatud Köler Prize 2011 nominentide - Dénes Kalev Farkas, Tõnis Saadoja, Timo Toots, Sigrid Viir, Jevgeni Zolotko - näitusest

  11. A two-storey structured photoanode of a 3D Cu2ZnSnS4/CdS/ZnO@steel composite nanostructure for efficient photoelectrochemical hydrogen generation

    Science.gov (United States)

    Choi, Youngwoo; Baek, Minki; Zhang, Zhuo; Dao, Van-Duong; Choi, Ho-Suk; Yong, Kijung

    2015-09-01

    A two-storey structured photoanode of a 3D Cu2ZnSnS4(CZTS)/CdS/ZnO@steel composite nanostructure has been fabricated by using the solution method and demonstrated highly efficient photoelectrochemical hydrogen generation due to its contraption in the structure for sufficient light absorption as well as the three step-down band alignments for efficient charge separation and transport. This composite structure is composed of two storeys: the upper storey is the CZTS/CdS/ZnO hetero-nanorods (NRs) covered on the stainless steel mesh; the bottom storey is the CZTS/CdS/ZnO hetero-NRs grown on the FTO glass. The CZTS/CdS/ZnO hetero-NRs have cascade band gaps decreasing from 3.15 to 1.82 eV, which gives them efficient charge transfer and broad photoresponse in the UV to near-IR region, resulting in 47% IPCE in a wide light region from 400 to 500 nm; and the stainless steel mesh serves not only as a conductor for charge transport, but also as a skeleton of the grid structure for absorbing more light. The related mechanism has been investigated, which demonstrates that the two-storey CZTS/CdS/ZnO@steel composite nanostructure would have great potential as a promising photoelectrode with high efficiency and low cost for PEC hydrogen generation.A two-storey structured photoanode of a 3D Cu2ZnSnS4(CZTS)/CdS/ZnO@steel composite nanostructure has been fabricated by using the solution method and demonstrated highly efficient photoelectrochemical hydrogen generation due to its contraption in the structure for sufficient light absorption as well as the three step-down band alignments for efficient charge separation and transport. This composite structure is composed of two storeys: the upper storey is the CZTS/CdS/ZnO hetero-nanorods (NRs) covered on the stainless steel mesh; the bottom storey is the CZTS/CdS/ZnO hetero-NRs grown on the FTO glass. The CZTS/CdS/ZnO hetero-NRs have cascade band gaps decreasing from 3.15 to 1.82 eV, which gives them efficient charge transfer and broad

  12. UNO STUDIO DI CASO SULL’ELABORAZIONE E L’UTILIZZO DEL FEEDBACK SCRITTO IN APPRENDENTI DI ITALIANO L2

    Directory of Open Access Journals (Sweden)

    Livia Alberti

    2015-02-01

    Full Text Available Attraverso uno studio di caso che coinvolge due studentesse di italiano L2 di livello elementare/intermedio, si prendono in esame alcuni dei fattori che possono influire sull’utilizzo del feedback scritto da parte degli apprendenti. La raccolta dei dati si è svolta in tre giornate: nella prima le partecipanti hanno scritto un testo collaborativo a partire da una storia per immagini; nella seconda i testi, corretti con un intervento di feedback implicito, sono stati riconsegnati e la coppia ha prima analizzato le segnalazioni ricevute e poi riscritto il testo; nella terza le apprendenti hanno prodotto testi individuali a partire dallo stesso stimolo visivo. Oltre a confrontare le diverse stesure del testo, si analizzano le interazioni avvenute tra le apprendenti durante il lavoro di coppia finalizzato a utilizzare il feedback per produrre il secondo testo collaborativo. I risultati mostrano da un lato che un elevato livello di coinvolgimento nell’elaborazione del feedback non ne garantisce un utilizzo efficace, dall’altro che hanno un peso non trascurabile anche fattori più “personali” come le convinzioni sulla lingua bersaglio e l’atteggiamento nei confronti del lavoro di coppia.  A case study on the development and use of written feedback in Italian L2 learners  Through a case study involving two female elementary/intermediate Italian L2 students, we examine some of the factors that may affect the use of written feedback by the learners. Data collection took place over three days: on the first day, the participants wrote a collaborative text from a picture story; on the second the texts, corrected using implicit feedback, were returned, and the students first analyzed the reports received and then rewrote the text; on the third day the learners produced individual texts from the same visual stimulus. In addition to comparing the various drafts of the text, we analyzed the interactions between the learners during pair work aimed

  13. Reflecting through the designing: a brief analysis of the teacher’s planning process

    Directory of Open Access Journals (Sweden)

    Francesca Anello

    2017-01-01

    Full Text Available The aim of this work is to study the conditions in which teachers plan and execute educational actions in the classroom and to find out which difficulties they encountered during the development of the planned teaching action. The “concrete operations” that 15 teachers in the Palermo area had accomplished, were highlighted before, during and after every structured activity to promote the pupils’ oral expression. Specifically, the research, which is collocated in the case study, had the function of verifying forty descriptors. These were grouped in the five cardinal points of the ADDIE model (Analysis, Design, Development, Implementation, Evaluation, with a motivated group of teachers that were formed during the action-research. To check intentions and behaviors of teachers, tools for self-analysis were built, individual notes and shared reports of the practice were used. The teachers found that the proposed projected device, initially, designed with 40 descriptors was not practical and chose only 20 of these. A simplified and flexible model is now available for the didactical preparation of the activities.Riflettere attraverso la progettazione: breve analisi del processo di programmazione didattica dell’insegnanteL’obiettivo del contributo è indagare le condizioni in cui gli insegnanti pianificano e realizzano un intervento in classe, e quali difficoltà incontrano nelle fasi di sviluppo dell’azione didattica programmata. Sono state evidenziate le “operazioni concrete” che 15 insegnanti del territorio di Palermo hanno compiuto prima, durante e dopo un’attività strutturata per promuovere negli alunni l’espressione orale. Nello specifico la ricerca, che si colloca nella tipologia dello studio di caso, si è occupata di verificare la funzionalità di 40 descrittori, raggruppati nei cinque punti cardine del modello ADDIE (Analysis, Design, Development, Implementation, Evaluation, con un gruppo motivato di insegnanti che si

  14. Behavioral Own-Body-Transformations in Children and Adolescents With Typical Development, Autism Spectrum Disorder, and Developmental Coordination Disorder

    Directory of Open Access Journals (Sweden)

    Soizic Gauthier

    2018-05-01

    Full Text Available Background: In motor imitation, taking a partner's perspective often involves a mental body transformation from an embodied, ego-centered viewpoint to a disembodied, hetero-centered viewpoint. Impairments of both own-body-transformation (OBT and abnormalities in visual-spatial processing have been reported in patients with neurodevelopmental disorders including autism spectrum disorder (ASD. In the context of a visual-motor interactive task, studying OBT impairments while disentangling the contribution of visual-spatial impairments associated with motor coordination problems has not been investigated.Methods: 85 children and adolescents (39 controls with typical development, TD; 29 patients with ASD; 17 patients with developmental coordination disorder, DCD, aged 6–19 years, participated in a behavioral paradigm in which participants interacted with a virtual tightrope walker (TW standing and moving with him. The protocol enables to distinguish ego-centered and hetero-centered perspectives.Results: We show that (1 OBT was possible but difficult for children with neurodevelopmental disorders, as well as for TD children, when the task required the participant to perform a mental rotation in order to adopt a hetero-centered perspective. (2 Using multivariate models, hetero-centered perspective score was significantly associated with age, TW orientation, latency, and diagnosis. ASD and TD groups' performances were close and significantly correlated with age. However, it was not the case for DCD, since this group was specifically handicapped by visual-spatial impairments. (3 ASD and DCD did not perform similarly: motor performance as shown by movement amplitude was better in DCD than ASD. ASD motor response was more ambiguous and hardly readable.Conclusion: Changing perspective in a spatial environment is possible for patients with ASD although delayed compared with TD children. In patients with DCD, their visual-spatial impairments negatively

  15. Un intreccio di iniziative scientifiche. Reti Medievali e il futuro della storiografia digitale

    Directory of Open Access Journals (Sweden)

    Roberto Delle Donne

    2014-12-01

    Full Text Available L’articolo muove dall'esperienza di Reti Medievali per analizzare il modo in cui, più in generale, gli storici hanno guardato e guardano alla rete delle reti. Affronta quindi un tema che si colloca al crocevia tra l’evoluzione delle tecnologie informatiche e telematiche, i percorsi della storiografia e le trasformazioni delle sue metodologie, i mutamenti del mercato della comunicazione scientifica, i cambiamenti nei criteri di valutazione della qualità delle pubblicazioni.

  16. Atleti adolescenti e comunità sportiva: il senso psicologico di comunità applicato allo sport

    OpenAIRE

    Scotto Di Luzio, Silvia

    2013-01-01

    Il Senso di Comunità costituisce un fattore importante per il benessere e lo sviluppo sociale positivo degli adolescenti (Pretty, 2002 ; Cicognani et al., 2006; 2012). Tuttavia, pochi studi hanno fornito informazioni significative sui meccanismi che possono condurre alla costruzione di una Comunità nello sport (Warner & Dixon, 2011). Finalità generale di questa tesi è di contribuire alla definizione di una Comunità Sportiva, esaminando i meccanismi alla base della formazione del Senso di Comu...

  17. New Materials for Sample Treatment, MS-Based Methods and Clinical Applications

    OpenAIRE

    Riboni, Nicolò

    2018-01-01

    Lo sviluppo e l’utilizzo di nuovi materiali per scopi analitici è un campo di grande interesse per la ricerca scientifica. I progressi ottenuti nell’ambito della chimica dei materiali hanno permesso lo sviluppo di nuovi metodi analitici e tecniche di estrazione caratterizzati da alte performance in termini di selettività e sensibilità. In particolare sono stati incrementati nuovi dispositivi in grado di operare in-situ e in tempo reale tramite controllo remoto, interfacciandosi con smartphone...

  18. Caratterizzazione della flora microbica orale in diverse categorie di pazienti sindromici in età evolutiva.

    OpenAIRE

    Vocale, Caterina

    2012-01-01

    La salute orale dei soggetti affetti da patologie sistemiche responsabili di disabilità fisiche e/o psichiche, in particolare in età evolutiva, è un obiettivo da perseguire di primaria importanza al fine di migliorare la qualità della vita del bambino e garantirgli un buon inserimento nel contesto sociale. Ricerche sperimentali e cliniche hanno individuato i momenti eziopatogenetici delle diverse problematiche che si riscontrano a carico del cavo orale, con una frequenza superiore nei paz...

  19. Kunsti estica Rootsis ja Lätis

    Index Scriptorium Estoniae

    1999-01-01

    Suvel hakkas Stockholmis ilmuma uus Põhjamaade kunstiajakiri "Nu", mis loodi Soome ajakirja "Siksi" ja Rootsi ajakirja "Index" ühendamisel. "NU" teises numbris "Nu" Eesti korrespondendi Harry Liivranna lühiartikkel Udo Siiast. Läti kunstiajakirjas Studija nr. 8 tutvustab Daiga Rudzate Veneetsia biennaaliga seoses Eesti ekspositsiooni, Irena Buzinska Tallinnas novembris avatavat inglise moefoto näitust. Läti kunstiajakirjas Acoustic.Space nr. 2 on Raivo Kelomehe informatsioon novembris Tallinnas toimuvast 2. meediakunsti festivalist ning Hanno Soansi videoprojekti tutvustus

  20. Sicurezza e crisi economica. Alcune considerazioni

    OpenAIRE

    Carlo Giannone

    2013-01-01

    Il saggio indaga gli eventuali legami tra l’attuale situazione di crisi economica, con l’incombente spettro della recessione, e il forte diffuso senso d’insicurezza che sembra accomunare i cittadini di diversi paesi del pianeta. Si passano in rassegna alcuni studi internazionali che hanno indagato sulle principali fonti di “felicità” reale e percepita (reddito, lavoro, vita familiare, rapporti con la propria comunità, la salute, ecc.) cercando di comprendere i caratteri strutturali e continge...

  1. Dalla parola all'immagine: il linguaggio della critica d'arte: Per la traduzione di una "traduzione"

    OpenAIRE

    De Martin, Maria Pia

    1994-01-01

    Negli ultimi decenni i musei e le gallerie d'arte di tutta Europa hanno visto crescere continuamente l'afflusso dei visitatori: basti pensare alle grandi mostre degli ultimi anni e alle interminabili code per accedervi (per esempio Kandinsky a Parigi e a Milano nel 1985). Laddove, in passato, la fruizione delle opere d'arte era limitata ad una stretta cerchia di persone, esse sembrano aver risvegliato oggi l'interesse del grande pubblico. Insieme all'interesse generale cres...

  2. Fistole retto-vaginali Crohn-relate trattate mediante trasposizione del muscolo gracile: risultati a lungo termine e qualità della vita

    OpenAIRE

    Tassone, Daniela

    2015-01-01

    OBIETTIVO: Le fistole retto-vaginali Crohn-relate hanno un impatto significativo sulla qualità della vita. Quando il canale anale è alterato da ulcerazioni e stenosi o in pazienti con difetti estesi del perineo, la chirurgia locale produce risultati insoddisfacenti. Lo scopo di questo studio è quello di valutare l'efficacia della trasposizione del muscolo gracile nelle fistole retto-vaginali Crohn-relate e determinare i suoi effetti sulla qualità della vita. MATERIALI E METODI: Da gennaio...

  3. On the electrophilic character of molecules through its relation with electronegativity and chemical hardness.

    Science.gov (United States)

    Islam, Nazmul; Ghosh, Dulal C

    2012-01-01

    Electrophilicity is an intrinsic property of atoms and molecules. It probably originates logistically with the involvement in the physical process of electrostatics of soaked charge in electronic shells and the screened nuclear charge of atoms. Motivated by the existing view of conceptual density functional theory that similar to electronegativity and hardness equalization, there should be a physical process of equalization of electrophilicity during the chemical process of formation of hetero nuclear molecules, we have developed a new theoretical scheme and formula for evaluating the electrophilicity of hetero nuclear molecules. A comparative study with available bench marking reveals that the hypothesis of electrophilicity and equalization, and the present method of evaluating equalized electrophilicity, are scientifically promising.

  4. What is the Essence of Hypnosis?

    Science.gov (United States)

    Dell, Paul F

    2017-01-01

    The author explores the nature of hypnosis, which he characterizes as a motivated mode of neural functioning that enables most humans to alter, to varying degrees, their experience of body, self, actions, and world. The essence of hypnosis is not to be found in hetero-hypnosis; instead, it lies in the spontaneous self-activation of that mode of neural functioning. The hypnosis field has substantially lost sight of spontaneous self-activation, because the word hypnosis is usually used to mean hetero-hypnosis. Self-activation of this mode of neural functioning is the necessary sine qua non of hypnotic psychopathology. Moreover, self-activation of trance is the characteristic hypnotic behavior of a distinct subset of highly hypnotizable individuals.

  5. Process for obtaining cobalt and lanthanum nickelate

    International Nuclear Information System (INIS)

    Tapcov, V.; Samusi, N.; Gulea, A.; Horosun, I.; Stasiuc, V.; Petrenco, P.

    1999-01-01

    The invention relates to the process for obtaining polycrystalline ceramics of cobalt and lanthanum nickelate with the perovskite structure from coordinative hetero metallic compounds. The obtained products can be utilized in the industry in the capacity of catalysts. Summary of the invention consists in obtaining polycrystalline ceramics LaCoO 3 and LaNiO 3 with the perovskite structure by pyrolysis of the parent compounds, namely, the coordinative hetero metallic compounds of the lanthanum cobalt or lanthanum nickel. The pyrolysis of the parent compound runs during one hour at 800 C. The technical result of the invention consists in lowering the temperature of the parent compound pyrolysis containing the precise ratio of metals necessary for ceramics obtaining

  6. On the Electrophilic Character of Molecules Through Its Relation with Electronegativity and Chemical Hardness

    Directory of Open Access Journals (Sweden)

    Dulal C. Ghosh

    2012-02-01

    Full Text Available Electrophilicity is an intrinsic property of atoms and molecules. It probably originates logistically with the involvement in the physical process of electrostatics of soaked charge in electronic shells and the screened nuclear charge of atoms. Motivated by the existing view of conceptual density functional theory that similar to electronegativity and hardness equalization, there should be a physical process of equalization of electrophilicity during the chemical process of formation of hetero nuclear molecules, we have developed a new theoretical scheme and formula for evaluating the electrophilicity of hetero nuclear molecules. A comparative study with available bench marking reveals that the hypothesis of electrophilicity and equalization, and the present method of evaluating equalized electrophilicity, are scientifically promising.

  7. Influence of the interface on growth rates in AlN/GaN short period superlattices via metal organic vapor phase epitaxy

    Science.gov (United States)

    Rodak, L. E.; Korakakis, D.

    2011-11-01

    AlN/GaN short period superlattices are well suited for a number of applications including, but not limited to, digital alloys, intersubband devices, and emitters. In this work, AlN/GaN superlattices with periodicities ranging from 10 to 20 Å have been grown via metal organic vapor phase epitaxy in order to investigate the influence of the interface on the binary alloy growth rates. The GaN growth rate at the interface was observed to decrease with increasing GaN thickness while the AlN growth rate remained constant. This has been attributed to a decrease in the decomposition rate of GaN at the hetero-interface as seen in other III-V hetero-structures.

  8. Achievement report for fiscal 1990 on research and development of electrically conductive polymeric materials; 1990 nendo dodensei kobunshi zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-03-01

    It is intended to realize new electrically conductive materials characterized by light weight, corrosion resistance and easy-to-process performance, and electrical and electronic materials having functions different from those of metallic conduction mechanism. Therefore, activities were performed to seek technologies for polymeric materials having conductivity greater than 10{sup 5} S/cm and being stable and easy to process. Activities were taken in the following six fields: (1) new hydrocarbon conjugate polymers, (2) excipient conjugate conductive materials, (3) technologies to form thin films of graphite synthesized at low temperatures, (4) conductive polymers of hetero aromatic system, (5) research and development of conductive materials of the hetero containing system and the {pi} conjugate system, and (6) comprehensive investigative research. In (1), thin films of polyacetylene and polyacene systems were formed, in (2), excipient hydrocarbon conjugate polymers and excipient graphite materials were developed, in (3), a high-accuracy process controlled graphite thin film forming technology was developed, in (4), the conductivity was enhanced by using high-order structural control and molecular design, and stability of the conductive polymers of complex annular conjugate system was enhanced, and in (5), conductive polymers of the hetero containing system and the {pi} conjugate system, and flexible graphite fibers were developed. (NEDO)

  9. Alcune note sugli effetti dell'inflazione sui bilanci aziendali, e sul problema della rivalutazione monetaria dei beni d'imprese. (Some notes on the effects of inflation on business balance sheets, and on the problem of the appreciation of business assets

    Directory of Open Access Journals (Sweden)

    V. VISCO

    2013-12-01

    Full Text Available Gli effetti dell'inflazione sui bilanci delle imprese negli ultimi anni sono stati oggetto di numerosi studi . Questi hanno evidenziato le distorsioni causate dagli aumenti dei prezzi e hanno suggerito modi per eliminare o mitigarne l'effetto, come l'uso di metodi di indicizzazione , sistemi modificati di contabilità e interventi legislativi specifici e periodici. Il presente lavoro si propone di chiarire la portata degli effetti dell'inflazione sulle voci più significative dei bilanci delle imprese . Inoltre , cerca di analizzare le logiche , le conseguenze e le limitazioni dei meccanismi apprezzamento per beni aziendali adottate in Italia in passato e recentemente proposto di nuovo .The effects of inflation on firms’ balance sheets in recent years have been the subject of numerous studies. These have highlighted the distortions caused by the rises in prices and have suggested ways to eliminate or mitigate them, such as the use of indexing methods, modified systems of accounting and specific and periodic legislative interventions. The present work aims to clarify the scope of the effects of inflation on the most significant items of firms’ balance sheets. Moreover, it seeks to analyse the logic, consequences and limitations of the appreciation mechanisms for business assets adopted in Italy in the past and recently proposed again.JEL: E31, M41

  10. Apartheid education legacies and new directions in post-apartheid South Africa

    Directory of Open Access Journals (Sweden)

    Linda Chisholm

    2012-12-01

    Full Text Available Questo saggio prende in considerazione i retaggi della educazione dell’apartheid e le nuove direttive entrate in vigore dal 1994, innanzitutto problematizzando il concetto di retaggio dell’apartheid e poi esaminandolo all’interno del più vasto contesto storico che vede l’emergere di un sistema di scolarizzazione di massa differenziato su base razziale, nelle particolari condizioni politiche ed economiche del Novecento. I principali retaggi che la nuova politica del periodo post-apartheid si proponeva di affrontare comprendevano: 1 i finanziamenti, l’organizzazione e le risorse diseguali riservati alle diverse razze; 2 la scarsa qualità dell’istruzione per la popolazione nera; 3 l’alto livello di disoccupazione giovanile; 4 i bassi livelli di partecipazione all’educazione degli adulti e all’istruzione tecnica e superiore. Il saggio mostra come le nuove iniziative per la riorganizzazione dell’istruzione, la politica sul personale docente, il curriculum, lo sviluppo delle compe- tenze e l’istruzione superiore siano state prese in condizioni economiche e politiche particolari e dimostra che non hanno modificato marcate diseguaglianze e non hanno segnato una discontinuità rispetto ai risultati dell’apprendimento. Contrariamente alle posizioni di chi nega l’apartheid, questa contraddizione è spiegata in rapporto alla forte presenza del passato nel presente, alla contraddizione fra intenti educativi e risultati, e al ruolo subordinato dell’istruzione in qualunque ordine sociale.

  11. Christine Angot: una hetero-homosexual incestuosa

    Directory of Open Access Journals (Sweden)

    María José Palma Borrego

    2008-01-01

    Full Text Available El proyecto literario de Christine Angot en L’inceste (1999 es el de desvelar no su historia incestuosa –ella misma afirma que su libro no es una autobiografía– sino el hacer visible lo más reprimido, lo más oculto y a la vez lo más originario de nuestra Cultura: el incesto con la madre. Un incesto que puede ser real o imaginario, y que el trabajo de escritura desvela y configura sus territorios que van desde la fusión con la madre, característica de toda situación preedípica, hasta una relación homosexual real con su doble narcisista, pasando por el deseo incestuoso por su hija. Mundo sin castración en donde todo puede ser posible, en ese juego de “ser” y “no-ser”, y en donde la temática del incesto está representada en el texto por una espacialidad vertical, de arriba abajo, generacional, madre/hija-Christine-Léonore, y horizontal, Christine-Marie Christine.

  12. Protein dimerization and oligomerization in biology

    National Research Council Canada - National Science Library

    Matthews, Jacqueline M

    2012-01-01

    .... However, protein function is so often linked to both homo- and hetero-oligomerization and many heterologous interactions likely evolved from homologous interaction, so this volume also covers many...

  13. Report compiled by Research Center for Carbonaceous Resources, Institute for Chemical Reaction Science, Tohoku University; Tohoku Daigaku Hanno Kagaku Kenkyusho tanso shigen hanno kenkyu center hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-04-01

    The Research Center for Carbonaceous Resources was established in April 1991 for the purpose of developing a comprehensive process for converting carbonaceous resources into clean fuels or into materials equipped with advanced functions. In this report, the track records etc. of the center are introduced. Under study in the conversion process research department is the organization of a comprehensive coal conversion process which will be a combination of solvent extraction, catalytic decomposition, and catalytic gasification, whose goal is to convert coal in a clean way at high efficiency. Under study in the conversion catalyst research department are the development of a coal denitrogenation method, development of a low-temperature gasification method by use of inexpensive catalysts, synthesis of C{sub 2} hydrocarbons in a methane/carbon dioxide reaction, etc. Other endeavors under way involve the designing and development of new organic materials such as new carbon materials and a study of the foundation on which such efforts stand, that is, the study of the control of reactions between solids. Furthermore, in the study of interfacial reaction control, the contact gasification of coal, brown coal ion exchange capacity and surface conditions, carbonization of cation exchanged brown coal, etc., are being developed. (NEDO)

  14. Editorial. To pay homage to Paris attack victims through the writings of Cardinals Poma and Biffi / Éditorial. En hommage aux victimes des massacres de Paris par les écrits des Cardinaux Poma et Biffi

    Directory of Open Access Journals (Sweden)

    Balloni Augusto

    2015-12-01

    Full Text Available Questo editoriale è dedicato alla memoria delle 129 vittime della strage di Parigi del 13 novembre 2015, ricordando brani di omelie, discorsi e dichiarazioni dei Cardinali Antonio Poma e Giacomo Biffi . Ritengo ora particolarmente importante una riflessione su questi eventi che hanno sconvolto la Francia, l'Europa e tutto il mondo. Infatti, in questi luttuosi avvenimenti si riscontrano odi razziali e religiosi, coinvolgimento di molte persone e soprattutto le numerose vittime in cui compaiono giovani e giovanissimi.

  15. Il Teatro Shakespeariano di Danzica. L'Alato / Gdansk Shakespearian Theatre. The Winged

    OpenAIRE

    Renato Rizzi

    2014-01-01

    Il 23 aprile, giorno della nascita e della morte di William Shakespeare, è stato inaugurato il tetto apribile del nuovo Teatro Elisabettiano, che sarà inaugurato il prossimo settembre a Danzica. L'evento diventa l'occasione per celebrare allo stesso tempo le potenze plastiche del simbolo, che, disseminate nella metafisica dei luoghi (e della memoria), guidano le forze alla 'forma' e i valori e gli ideali che hanno sostenuto il tormentato processo storico della città baltica e della nazione p...

  16. Il monastero di Bobbio in età altomedievale

    Directory of Open Access Journals (Sweden)

    Eleonora Destefanis

    2003-11-01

    Full Text Available Il monastero di Bobbio, sorto sull’Appennino piacentino per iniziativa di S. Colombano e con il sostegno del re longobardo Agilulfo, ha conosciuto una lunga storia di studi che ne hanno messo di volta in volta in luce l’importanza come centro scrittorio e di raccolta di testi, il ruolo di primo piano quale interlocutore delle monarchie avvicendatesi nel corso dell’altomedioevo, la posizione di spicco nell’esperienza del monachesimo insulare sul Continente, riflessa da una cospicua produzione ...

  17. I leave you a respect for the use of power". Mary McLeod Bethune: donne nere e processi di "decision making" negli Stati Uniti

    OpenAIRE

    Vezzosi, Elisabetta

    2004-01-01

    Gli studi degli anni Ottanta sulla leadership femminile nera, raramente di carattere storico, ne hanno evidenziato soprattutto i connotati simbolici, in cui spesso i confini tra vite personali e ruoli organizzativi sono assai sfumati. L'immagine di una leadership debole da essi proposta è stata tuttavia smentita dalla storiografia più recente, che peraltro appare ancora ad uno stadio embrionale. Tutto ciò spiega almeno in gran parte perché sia tanto a lungo stata trascurata la figura di Mary ...

  18. Principi di Marketing

    OpenAIRE

    P. Kotler; G. Armstrong; F. Ancarani; M. Costabile

    2015-01-01

    Principi di marketing propone un quadro dei processi di gestione del marketing relativamente innovativo, ispirato a un modello rigoroso e semplice al tempo stesso: il valore, dei clienti, per i clienti e delle relazioni con i clienti. È su questo modello che vengono declinati i princìpi del marketing e che se ne progettano le strategie – segmentazione, targeting e posizionamento – da cui hanno origine le scelte di differenziazione di prodotti, marche, modalità di distribuzione e comunicazione...

  19. Aurora Bosna, Scautismo femminile e Guidismo. Esperienze educative in prospettiva di Genere: i casi dell'Italia e della Spagna

    Directory of Open Access Journals (Sweden)

    Lucia Tortora

    2015-03-01

    pp. 291 La recensione presenta il volume Scautismo femminile e Guidismo. Esperienze educative in prospettiva di Genere: i casi dell'Italia e della Spagna di Aurora Bosna, che analizza i fenomeni dello Scautismo femminile e del Guidismo in una prospettiva comparatstica e in un'ottica pedagogica e di genere, evidenziando il valore che tali esperienze hanno avuto nel percorso di emancipazione femminile all'interno dei contesti socio-culturali dell'Italia e della Spagna tra il XIX e il XX secolo.

  20. President Ilves sarjas hoogtöö korras seaduste tegemist / Tuuli Koch

    Index Scriptorium Estoniae

    Koch, Tuuli

    2010-01-01

    President Toomas Hendrik Ilvese kõnest iseseisvuspäeval. Arvamust avaldavad justiitsminister Rein Lang, Riigikogu põhiseaduskomisjoni esimees Väino Linde ja komisjoni aseesimees Evelyn Sepp, sotsiaalminister Hanno Pevkur ning haridus- ja teadusminister Tõnis Lukas. Presidendi vastuvõtu kujundust ja kontserti hindavad lilleseadja Taivo Piller, muusikakriitik Margus Haav ja Rakvere teatri peanäitejuht Üllar Saaremäe. Küsimustele vastab presidendi vastuvõtu teleülekande produtsent Margus Saar. Juuresoleval fotol justiitsminister Rein Lang presidendi kätlemistseremoonial

  1. Concept City: Roma ri-vista e vissuta ne La dolce vita e La grande bellezza

    OpenAIRE

    Martini, Alessia

    2015-01-01

    A partire dagli anni del neorealismo, Roma è stata una location particolarmente amata dai registi italiani che hanno utilizzato con finalità simboliche diversi luoghi della città—dalle borgate ai monumenti del centro—al fine di raccontare un preciso momento storico e una precisa situazione sociale. In questo articolo prenderò in considerazione due film ambientati a Roma, La dolce vita di Federico Fellini (1960) e La grande bellezza di Paolo Sorrentino (2013), per analizzare le valenze che la ...

  2. FOOD SAFETY AND QUALITY IN DEVELOPING COUNTRIES: THE ROLE OF LACTIC ACID BACTERIA

    OpenAIRE

    ANGRI, MATTEO

    2016-01-01

    La sicurezza e la qualità degli alimenti sono tutt’ora un problema critico per i paesi in via di sviluppo. Le diete a basso contenuto di acido folico, per esempio, possono causare gravi problemi di salute, soprattutto nei bambini. Gravi disturbi legati al tubo neurale (DTN) nei neonati possono derivare infatti da madri che hanno insufficiente apporto di acido folico (400-600 g / giorno) durante il periodo di gravidanza. Inoltre, se non adeguatamente protetti o trattati, I prodotti alimentari ...

  3. Sognando Shadow Moses. Grafica, gameplay e reiterazione come strumenti narrativi metareferenziali

    OpenAIRE

    Luca Papale

    2013-01-01

    Un campo innevato, un eliporto, container metallici, telecamere di sorveglianza. Basta una rapida occhiata alla schermata e il giocatore di Metal Gear Solid 4: Guns of the Patriots fa un salto indietro nel tempo di dieci anni, tornando ancora una volta ad infiltrarsi nella base militare di Shadow Moses. La grafica è quella della prima PlayStation, una grafica che all’epoca era lo stato dell’arte, e che ora mostra tutte le sue grossolane imperfezioni. I dieci anni trascorsi hanno visto sussegu...

  4. Inviting queer ideas into the science classroom: studying sexuality education from a queer perspective

    Science.gov (United States)

    Lundin, Mattias

    2014-06-01

    Science education has been pointed out as fact-based and built on reliable knowledge. Nevertheless, there are areas that include other aspects. Sexual education is, according to the Swedish syllabus, such an example and it involves aspects as love, sexuality and relations. These aspects suggest a possible tension between the biological and well-established definition of sex and later non-dichotomized perspectives. Teachers need to take both of these aspects into account as they work. Equality work aiming at providing equality for people that are not part of the prevalent norms for doing gender and sexuality is another endeavour to teachers in science education. To be able to study prevalent norms a queer perspective has been used. The hetero norm is defined in this perspective and it is explained as the expectation that everybody is heterosexual and wishes to live in hetero pair-ship. This perspective also involves the normative construction of man and woman. The different ways to approach sex and sexuality is the research object of this study and the research question is formulated as follows: How can the construction of the hetero norm be visualized by queer theory to challenge the norm in sexuality education? A framework that visualizes the hetero norm and that could elicit attempts to question the norm was chosen for the analysis. The applied framework can be summarized using the following descriptions: repetition of desirability, dichotomization of sexes, differentiation of sexualities and hierarchy of positions. The data constituted of observations made in two classes with 14-year-old students during sexuality education lessons. The results illustrate how the hetero norm was reconstructed in all of the four parts of the applied framework. The analysis provides four examples of how the norm was challenged, first, by expressing the unexpected and uncommon, second, by an orientation towards uncommon positions, third, by eliciting the communalities of sexes and

  5. GPCR Interaction: 151 [GRIPDB[Archive

    Lifescience Database Archive (English)

    Full Text Available hey are close enough to form hetero-oligomers. ... Immunofluorescence Microscopy, De...tection of the Phosphorylated MAPK, MAPK Assay, Inositol Phosphate Assay, Immunogold Electron Microscopy NP_001516.2 ...

  6. GPCR Interaction: 150 [GRIPDB[Archive

    Lifescience Database Archive (English)

    Full Text Available ey are close enough to form hetero-oligomers. ... Immunofluorescence Microscopy, Det...ection of the Phosphorylated MAPK, MAPK Assay, Inositol Phosphate Assay, Immunogold Electron Microscopy NP_057167.2 ...

  7. Rapid trifluoromethylation and perfluoroalkylation of five-membered heterocycles by photoredox catalysis in continuous flow.

    Science.gov (United States)

    Straathof, Natan J W; Gemoets, Hannes P L; Wang, Xiao; Schouten, Jaap C; Hessel, Volker; Noël, Timothy

    2014-06-01

    Trifluoromethylated and perfluoroalkylated heterocycles are important building blocks for the synthesis of numerous pharmaceutical products, agrochemicals and are widely applied in material sciences. To date, trifluoromethylated and perfluoroalkylated hetero-aromatic systems can be prepared utilizing visible light photoredox catalysis methodologies in batch. While several limitations are associated with these batch protocols, the application of microflow technology could greatly enhance and intensify these reactions. A simple and straightforward photocatalytic trifluoromethylation and perfluoroalkylation method has been developed in continuous microflow, using commercially available photocatalysts and microflow components. A selection of five-membered hetero-aromatics were successfully trifluoromethylated (12 examples) and perfluoroalkylated (5 examples) within several minutes (8-20 min). © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Synthesis, characterization and toxicity of azanonaborane-containing imidazoles for boron neutron capture therapy

    International Nuclear Information System (INIS)

    El-Zaria, Mohamed E.; Genady, Afaf R.; Gabel, Detlef

    2006-01-01

    The exo-NH 2 R group of the azanonaborane of the type [(RH 2 N)B 8 H 11 NHR] can be exchanged by one hetero-nitrogen atom of the imidazole ring. In the case of histamine, the exchange takes place on the aliphatic amino group, the hetero-nitrogen atom of the imidazole ring or both of them. In vitro experiments using B16 melanoma cells showed that incorporation of B 8 N cluster unit into primary amino group of the histamine increases the compound's toxicity. In contrast, this specificity for cytotoxicity effect was not observed in the case of histamine containing two B 8 N clusters which was relatively nontoxic and did not inhibit colony formation up to 2 mM. (author)

  9. Aggregation of Heteropolyanions Implicates the Presence of Zundel Ions Near Air-Water Interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Bera, Mrinal K. [Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne Illinois 60439 United States; DUBBLE-CRG, ESRF-The European Synchrotron Radiation Facility CS40220, 38043 Grenoble Cedex 9 France; Antonio, Mark R. [Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne Illinois 60439 United States

    2016-07-01

    Protons play crucial roles in the interactions between hetero-polyanions (HPAs) in aqueous solutions and solid acid salts. We report the aggregation behaviours of Keggin HPAs near the surfaces of heteropolyacid solutions. The structure of the aggregated HPA layer near the solution-vapour phase boundary closely resembles the solid-state crystal structure of the hetero-polyacids in which the HPAs are connected by Zundel ions. The resemblance not only implicates the presence of protons in the form of planar Zundel ions near the air-water interface but, also, suggests that these align parallel to the interface. This study demonstrates an indirect means of assessing the impact of protons on HPA interactions near air-water interfaces and, in general, provides new insights about interfacial proton chemistry of heteropolyacids.

  10. Effect of Solvent Additives on the Solution Aggregation of Phenyl-C61-Butyl Acid Methyl Ester (PCBM)

    KAUST Repository

    Tummala, Naga Rajesh; Sutton, Christopher; Aziz, Saadullah G.; Toney, Michael F.; Risko, Chad; Bredas, Jean-Luc

    2015-01-01

    High-boiling-point solvent additives, employed during the solution processing of active-layer formulations, impact the efficiency of bulk hetero-junction (BHJ) organic solar cells by influencing the morphological / topological features

  11. Kunstnikud käivad katuseid mööda / Hanno Soans

    Index Scriptorium Estoniae

    Soans, Hanno, 1974-

    2010-01-01

    Näitus "Linna kohal" Tallinna Linnagaleriis 19. septembrini 2010. Osalevad Anu Vahtra, Johnson & Johnson, Timo Toots, Claudia Doms, Mikk Heinsoo, Urmo Mets, Marit Ilison. Kuraatorid Kadri Klementi ja Helis Teiter. Näituse teemaks on linnamajade kasutamata katusepinnad

  12. Le ultime tecnologie hanno aiutato i primi soccorsi alla Costa Concordia

    Directory of Open Access Journals (Sweden)

    Andrea Faccioli

    2012-04-01

    Thanks to the Geomatics, the Costa Concordia operations are conducted in conditions of extreme security to protect both the lives of rescue workers and the delicate environment.All technologies involved (Lidar, Multibeam, GNSS, INS, ecc…, while having a primary role in real life, have always worked quietly behind the scenes.

  13. Soluble Polymer-supported Synthesis of Indoles via Palladium-mediat -ed Heteroannulation of Terminal Alkynes with o-Iodoanilines

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    A soluble polymer-supported synthesis of indoles via palladium-mediated hetero- annulation of terminal alkynes with o-iodoanilines has been described. The protocol provides a useful tool for constructing combinatorial indole libraries.

  14. 3D Structure and Interaction of p24β and p24δ Golgi Dynamics Domains: Implication for p24 Complex Formation and Cargo Transport.

    Science.gov (United States)

    Nagae, Masamichi; Hirata, Tetsuya; Morita-Matsumoto, Kana; Theiler, Romina; Fujita, Morihisa; Kinoshita, Taroh; Yamaguchi, Yoshiki

    2016-10-09

    The p24 family consists of four subfamilies (p24α, p24β, p24γ, and p24δ), and the proteins are thought to form hetero-oligomeric complexes for efficient transport of cargo proteins from the endoplasmic reticulum to the Golgi apparatus. The proteins possess a conserved luminal Golgi dynamics (GOLD) domain, whose functions are largely unknown. Here, we present structural and biochemical studies of p24β1 and p24δ1 GOLD domains. Use of GOLD domain-deleted mutants revealed that the GOLD domain of p24δ1 is required for proper p24 hetero-oligomeric complex formation and efficient transport of GPI-anchored proteins. The p24β1 and p24δ1 GOLD domains share a common β-sandwich fold with a characteristic intrasheet disulfide bond. The GOLD domain of p24δ1 crystallized as dimers, allowing the analysis of a homophilic interaction site. Surface plasmon resonance and solution NMR analyses revealed that p24β1 and p24δ1 GOLD domains interact weakly (K d = ~10 -4 M). Bi-protein titration provided interaction site maps. We propose that the heterophilic interaction of p24 GOLD domains contributes to the formation of the p24 hetero-oligomeric complex and to efficient cargo transport. Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. Trasforiiazioni Termoelastiche Finite di Solidi Incomprimibili

    Science.gov (United States)

    Signorini, A.

    Queste lezlioni hanno come direttiva una sintesi di quanto si trova sistematicamente sviluppato in una mia Memoria sulle trasformazioni termoelastiche finite di solidi incomprimibili, in corso di stampa negli Annali di Matematica pura e applicata t. XXXIX ( 1955) pp. 147-201 , Verranno anche esposti, come necessaria premessa, alcuni d ei risultati di due precedenti Memorie degli stessi Annali. Invece, per motivo di brevità, non potrò dare neppure un cenno delle ulteriori ricerche svilup pate dal prof. T. Manacorda in tre recentissimi suoi lavori:

  16. Kultuurkapitali aastapreemiad 2009 / Liina Jänes

    Index Scriptorium Estoniae

    Jänes, Liina, 1977-

    2010-01-01

    Žürii liige kandidaatidest, preemia saanud objektidest, preemia määramise põhjendus. Peapreemia said Andres Alver, Veljo Kaasik ja Tiit Trummal Tallinna Vabaduse väljaku eest. Arhitektuuri objektipreemia võitis Uus- ja Vana Jahuladu Tallinnas (HG Arhitektuur, Hanno Grossschmidt, Tomomi Hayashi, Yoko Azukava), väikeobjekti preemia Lasva veetorn (põhiautor Veronika Valk), restaureerimise preemia Nõmme Saksa Lunastaja kirik (Fredi-Armand Tomps, Anne Koppel), sisearhitektuuri preemia AS Baltika büroo (Studio 3, Kolm Pluss Üks), tegevuspreemia Ilona Gurjanova

  17. Dal Conte di Montecristo ai Promessi Sposi (passando per Melissa): l’Italia all’ombra degli sceneggiati Rai

    OpenAIRE

    Campanile, Achille; Rodari, Gianni; Cipriani, Ivano

    2016-01-01

    Come Gianluigi Rossini spiega nel libro Le serie TV, e come questo numero illustra, le tante diverse forme di serialità narrativa hanno via via creato tante diverse forme di dipendenza. Ma una delle più memorabili resta quella innescata dai cosiddetti “sceneggiati” che la nostra Rai manda in onda tra gli anni Cinquanta e i Settanta, dipendenza vissuta pressoché da tutti con la stessa assolutezza, cerimonia laica, passione (e non di rado ossessione) condivisa negli stessi tempi e modi: non sol...

  18. Italian renewable energy sources improvement; Decollo su larga scala delle fonti rinnovabili

    Energy Technology Data Exchange (ETDEWEB)

    Silvestrini, G. [Ministero dell' Ambiente, Rome (Italy)

    1999-08-01

    The paper reports Italian and international guidelines for renewable energy sources improvement. [Italian] Si assiste ad una ripresa di attenzione a livello internazionale ed italiano nei confronti delle energie rinnovabili, il cui panoramam e' oggi cambiato. In Italia sono pero' inadeguate le realta' produttive in questo settore ed anche i grandi attori energetici hanno finora affrontato la tematica con eccessiva timidezza. Il Ministero dell'Ambiente sollecita un maggiore impegno da parte delle societa' energetiche nei confronti delle energie rinnovabili.

  19. Synthesis of 3-Alkenyl-1-azaanthraquinones via Diels-Alder and Electron Transfer Reactions

    Directory of Open Access Journals (Sweden)

    Patrice Vanelle

    2002-12-01

    Full Text Available A convenient route to 3-alkenyl-1-azaanthraquinones via a hetero Diels-Alder reaction between an azadiene and naphthoquinone, a free radical chlorination and an electron transfer reaction is reported.

  20. The association of XRCC3 Thr241Met genetic variant with risk of ...

    African Journals Online (AJOL)

    genetic variant could be potentially associated with the risk of prostate cancer. However ... Results: Overall, significant associations were detected in the heterozygote comparison genetic model. (CT versus (vs.) ..... Quantifying hetero- geneity in ...