WorldWideScience

Sample records for cyclotron resonance deposition

  1. Preparation of Bismuth Titanate Films by Electron Cyclotron Resonance Plasma Sputtering-Chemical Vapor Deposition

    OpenAIRE

    Masumoto, H.; Hirai, T.

    1995-01-01

    Bismuth titanate (Bi4Ti3O12 : BIT) thin films were prepared on the Pt courted MgO(100) substrate by electron cyclotron resonance plasma sputtering-chemical vapor deposition (ECR plasma sputtering-CVD). Bi2O3 was used as a sputtering target and tetra-isopropoxy-titanium [Ti(i-C3H7O)4] as a CVD source. The composition of films was controlled by changing RF power (PRF) of Bi2O3 target and Ti source temperature (TTi). The stoichiometric BIT film was prepared under the condition of PRF=500W, TTi=6...

  2. Enhancement of octacalcium phosphate deposition on a titanium surface activated by electron cyclotron resonance plasma oxidation.

    Science.gov (United States)

    Orii, Yusuke; Masumoto, Hiroshi; Honda, Yoshitomo; Anada, Takahisa; Goto, Takashi; Sasaki, Keiichi; Suzuki, Osamu

    2010-05-01

    The present study was designed to investigate whether the formation of octacalcium phosphate (OCP) is accelerated on titanium (Ti) surface by an electron cyclotron resonance (ECR) plasma oxidation at various pressures and temperatures. X-ray diffraction (XRD) of Ti-oxidized substrates showed that the rutile TiO(2) phase on its surfaces appeared at 300 degrees C and was crystallized when the oxidation temperature increased up to 600 degrees C. The thickness of TiO(2) film on the substrates increased progressively as the temperature increased. The oxidized Ti surfaces were soaked in calcium and phosphate solutions supersaturated with respect to both hydroxyapatite (HA) and OCP but slightly supersaturated with dicalcium phosphate dihydrate (DCPD). OCP crystals with a blade-like morphology were deposited as the primary crystalline phase on Ti substrates, while DCPD was included as a minor constituent. The amount of OCP deposition was maximized under 0.015 Pa in 300 degrees C. On the other hand, the oxidation temperature did not show a significant effect on the deposit in the range examined. The phase conversion from OCP to HA, determined by XRD, was demonstrated to occur even at 1 day and to advance until 7 days by immersing the Ti substrate with the deposit in simulated body fluid at 37 degrees C. The present results suggest that ECR plasma oxidation could be used to improve a Ti surface regarding its bioactivity due to the enhancement of osteoconductive OCP deposition. (c) 2010 Wiley Periodicals, Inc.

  3. Ion cyclotron resonance cell

    Science.gov (United States)

    Weller, R.R.

    1995-02-14

    An ion cyclotron resonance cell is disclosed having two adjacent sections separated by a center trapping plate. The first section is defined by the center trapping plate, a first end trapping plate, and excitation and detector electrodes. The second section includes a second end trapping plate spaced apart from the center plate, a mirror, and an analyzer. The analyzer includes a wavelength-selective light detector, such as a detector incorporating an acousto-optical device (AOD) and a photodetector. One or more ion guides, grounded plates with holes for the ion beam, are positioned within the vacuum chamber of the mass spectrometer between the ion source and the cell. After ions are trapped and analyzed by ion cyclotron resonance techniques in the first section, the ions of interest are selected according to their mass and passed into the second section for optical spectroscopic studies. The trapped ions are excited by light from a laser and caused thereby to fluoresce. The fluorescent light emitted by the excited ions is reflected by the mirror and directed onto the detector. The AOD is scanned, and the photodetector output is recorded and analyzed. The ions remain in the second section for an extended period, enabling multiple studies to be carried out on the same ensemble of ions. 5 figs.

  4. Ion Cyclotron Resonance Facility (ICR)

    Data.gov (United States)

    Federal Laboratory Consortium — his facility is charged with developing and exploiting the unique capabilities of Fourier Transform Ion Cyclotron Resonance (FT-ICR) mass spectrometry, and leads the...

  5. Evidence of local power deposition and electron heating by a standing electromagnetic wave in electron-cyclotron-resonance plasma.

    Science.gov (United States)

    Durocher-Jean, A; Stafford, L; Dap, S; Makasheva, K; Clergereaux, R

    2014-09-01

    Microwave plasmas excited at electron-cyclotron resonance were studied in the 0.5-15 mTorr pressure range. In contrast with low-limit pressure conditions where the plasma emission highlights a fairly homogeneous spatial structure, a periodic spatial modulation (period ∼6.2 cm) appeared as pressure increased. This feature is ascribed to a local power deposition (related to the electron density) due to the presence of a standing electromagnetic wave created by the feed electromagnetic field (2.45 GHz) in the cavity formed by the reactor walls. Analysis of the electron energy probability function by Langmuir probe and optical emission spectroscopy further revealed the presence of a high-energy tail that showed strong periodic spatial modulation at higher pressure. The spatial evolution of the electron density and of the characteristic temperature of these high-energy electrons coincides with the nodes (maximum) and antinodes (minimum) of the standing wave. These spatially-modulated power deposition and electron heating mechanisms are then discussed.

  6. Zn-vapor diffused Er:Yb:LiNbO 3 channel waveguides fabricated by means of SiO 2 electron cyclotron resonance plasma deposition

    Science.gov (United States)

    Pernas, P. L.; Hernández, M. J.; Ruíz, E.; Cantelar, E.; Nevado, R.; Morant, C.; Lifante, G.; Cussó, F.

    2000-07-01

    We report here the fabrication method and operation of Zinc-vapor diffused channel waveguides on Erbium/Ytterbium (Er/Yb)-doped Lithium Niobate (LiNbO 3). electron cyclotron resonance (ECR) plasma deposition technique, UV photolithography and Reactive Ion Etching (RIE) are used to define an SiO 2 mask for pattern transfer. The whole process is performed at low temperatures eliminating typical LiO 2 out-diffusion problems and achieving low surface damage. The flexibility of the fabrication technology has been shown to be potentially applicable to integrated optics. EDAX measurements reveal good confinement and homogeneity of the diffused regions. Atomic Force Microscopy (AFM) surface characterization shows the swelling of the diffused areas, consistent with the topoepitaxial growth of a Zn xLi yNb zO w layer.

  7. Microwave power coupling with electron cyclotron resonance ...

    Indian Academy of Sciences (India)

    Electron cyclotron resonance (ECR) plasma was produced at 2.45 GHz using 200 – 750 W microwave power. The plasma was produced from argon gas at a pressure of 2 × 10−4 mbar. Three water-cooled solenoid coils were used to satisfy the ECR resonant conditions inside the plasma chamber. The basic parameters of ...

  8. Electron cyclotron resonance heating on TEXTOR

    NARCIS (Netherlands)

    Westerhof, E.; Hoekzema, J. A.; Hogeweij, G. M. D.; Jaspers, R. J. E.; Schüller, F. C.; Barth, C. J.; Bongers, W. A.; Donne, A. J. H.; Dumortier, P.; van der Grift, A. F.; van Gorkom, J. C.; Kalupin, D.; Koslowski, H. R.; Kramer-Flecken, A.; Kruijt, O. G.; Cardozo, N. J. L.; Mantica, P.; van der Meiden, H. J.; Merkulov, A.; Messiaen, A.; Oosterbeek, J. W.; Oyevaar, T.; Poelman, A. J.; Polman, R. W.; Prins, P. R.; Scholten, J.; Sterk, A. B.; Tito, C. J.; Udintsev, V.S.; Unterberg, B.; Vervier, M.; van Wassenhove, G.

    2003-01-01

    The 110 GHz and the new 140 GHz gyrotron systems for electron cyclotron resonance heating (ECRH) and ECCD on TEXTOR are described and results of ECRH experiments with the 110 GHz system are reported. Central ECRH on Ohmic plasmas shows the presence of an internal electron transport barrier near q =

  9. Resonant cyclotron scattering in magnetars' emission

    NARCIS (Netherlands)

    Rea, N.; Zane, S.; Turolla, R.; Lyutikov, M.; Götz, D.

    2008-01-01

    We present a systematic fit of a model of resonant cyclotron scattering (RCS) to the X-ray data of 10 magnetars, including canonical and transient anomalous X-ray pulsars (AXPs) and soft gamma repeaters (SGRs). In this scenario, nonthermal magnetar spectra in the soft X-rays (i.e., below ~10 keV)

  10. Fabrication of Ta2O5/GeNx gate insulator stack for Ge metal-insulator-semiconductor structures by electron-cyclotron-resonance plasma nitridation and sputtering deposition techniques

    Science.gov (United States)

    Otani, Yohei; Itayama, Yasuhiro; Tanaka, Takuo; Fukuda, Yukio; Toyota, Hiroshi; Ono, Toshiro; Mitsui, Minoru; Nakagawa, Kiyokazu

    2007-04-01

    The authors have fabricated germanium (Ge) metal-insulator-semiconductor (MIS) structures with a 7-nm-thick tantalum pentaoxide (Ta2O5)/2-nm-thick germanium nitride (GeNx) gate insulator stack by electron-cyclotron-resonance plasma nitridation and sputtering deposition. They found that pure GeNx ultrathin layers can be formed by the direct plasma nitridation of the Ge surface without substrate heating. X-ray photoelectron spectroscopy revealed no oxidation of the GeNx layer after the Ta2O5 sputtering deposition. The fabricated MIS capacitor with a capacitance equivalent thickness of 4.3nm showed excellent leakage current characteristics. The interface trap density obtained by the modified conductance method was 4×1011cm-2eV-1 at the midgap.

  11. Simulation of cyclotron resonant scattering features

    Directory of Open Access Journals (Sweden)

    Schwarm Fritz-Walter

    2014-01-01

    Full Text Available X-ray binary systems consisting of a mass donating optical star and a highly magnetized neutron star, under the right circumstances, show quantum mechanical absorption features in the observed spectra called cyclotron resonant scattering features (CRSFs. We have developed a simulation to model CRSFs using Monte Carlo methods. We calculate Green’s tables which can be used to imprint CRSFs to arbitrary X-ray continua. Our simulation keeps track of scattering parameters of individual photons, extends the number of variable parameters of previous works, and allows for more flexible geometries. Here we focus on the influence of bulk velocity of the accreted matter on the CRSF line shapes and positions.

  12. Ion–Cyclotron Resonance Frequency Interval Dependence on the O ...

    Indian Academy of Sciences (India)

    Solar corona—ion–cyclotron waves—coronal heating—. Vlasov equation. 1. Introduction. Heating of solar corona is still an active research area. It has recently been suggested that the ion–cyclotron resonance could play a key role in the problem of coronal heating. It is generally argued that various electromagnetic plasma ...

  13. Electron Cyclotron Resonance Heating of a High-Density Plasma

    DEFF Research Database (Denmark)

    Hansen, F. Ramskov

    1986-01-01

    Various schemes for electron cyclotron resonance heating of tokamak plasmas with the ratio of electron plasma frequency to electron cyclotron frequency, "»pe/^ce* larger than 1 on axis, are investigated. In particular, a mode conversion scheme is investigated using ordinary waves at the fundamental...

  14. Fourier Transform Ion Cyclotron Resonance Mass Spectrometry at the Cyclotron Frequency.

    Science.gov (United States)

    Nagornov, Konstantin O; Kozhinov, Anton N; Tsybin, Yury O

    2017-04-01

    The phenomenon of ion cyclotron resonance allows for determining mass-to-charge ratio, m/z, of an ensemble of ions by means of measurements of their cyclotron frequency, ω c . In Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS), the ω c quantity is usually unavailable for direct measurements: the resonant state is located close to the reduced cyclotron frequency (ω+), whereas the ω c and the corresponding m/z values may be calculated via theoretical derivation from an experimental estimate of the ω+ quantity. Here, we describe an experimental observation of a new resonant state, which is located close to the ω c frequency and is established because of azimuthally-dependent trapping electric fields of the recently developed ICR cells with narrow aperture detection electrodes. We show that in mass spectra, peaks close to ω+ frequencies can be reduced to negligible levels relative to peaks close to ω c frequencies. Due to reduced errors with which the ω c quantity is obtained, the new resonance provides a means of cyclotron frequency measurements with precision greater than that achieved when ω+ frequency peaks are employed. The described phenomenon may be considered for a development into an FT-ICR MS technology with increased mass accuracy for applications in basic research, life, and environmental sciences. Graphical Abstract ᅟ.

  15. A line-of-sight electron cyclotron emission receiver for electron cyclotron resonance heating feedback control of tearing modes

    DEFF Research Database (Denmark)

    Oosterbeek, J.W.; Bürger, A.; Westerhof, E.

    2008-01-01

    An electron cyclotron emission (ECE) receiver inside the electron cyclotron resonance heating (ECRH) transmission line has been brought into operation. The ECE is extracted by placing a quartz plate acting as a Fabry-Perot interferometer under an angle inside the electron cyclotron wave (ECW) beam...

  16. Wave propagation through an electron cyclotron resonance layer

    NARCIS (Netherlands)

    Westerhof, E.

    1997-01-01

    The propagation of a wave beam through an electron cyclotron resonance layer is analysed in two-dimensional slab geometry in order to assess the deviation from cold plasma propagation due to resonant, warm plasma changes in wave dispersion. For quasi-perpendicular propagation, N-parallel to x

  17. Electron-cyclotron-resonance ion sources (review)

    Energy Technology Data Exchange (ETDEWEB)

    Golovanivskii, K.S.; Dougar-Jabon, V.D. [People`s Friendship Univ., Moscow (Russian Federation)

    1992-01-01

    The physical principles are described and a brief survey of the present state is given of ion sources based on electron-cyclotron heating of plasma in a mirror trap. The characteristics of ECR sources of positive and negative ions used chiefly in accelerator technology are presented. 20 refs., 10 figs., 3 tabs.

  18. Ion cyclotron resonance heating system on Aditya

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    1Institute for Plasma Research, Bhat, Gandhinagar 382 428, India. 2Variable Electron Cyclotron .... Requirements for RF generators for fusion research include high power, long pulse duration and reliability. ... Output of pre-driver (triode 3CX5000A7) grounded grid amplifier is made tunable within. 20 to 47 MHz by using a ...

  19. Relativistic Cyclotron Resonance Shape in Magnetic Bottle Geonium

    Science.gov (United States)

    Dehmelt, Hans; Mittleman, Richard; Liu, Yuan

    1988-10-01

    The thermally excited axial oscillation of the electron through the weak magnetic bottle needed for the continuous Stern-Gerlach effect modulates the cyclotron frequency and produces a characteristic ≈ 12-kHz-wide vertical rise-exponential decline line shape of the cyclotron resonance. At the same time the relativistic mass shift decreases the frequency by ≈ 200 Hz per cyclotron motion quantum level n. Nevertheless, our analysis of the complex line shape shows that it should be possible to produce an abrupt rise in the cyclotron quantum number n from 0 to ≈ 20 over a small fraction of 200 Hz, when the 160-GHz microwave drive approaches the n = 0 → 1 transition, and a jump of 14 levels over a frequency increment of 200 Hz has already been observed in preliminary work. This realizes an earlier proposal to generate a very sharp cyclotron resonance feature by quasithermal excitation with a square noise band and should provide a way to detect spin flips when a weak bottle is used to reduce the broadening of the g - 2 resonance by a factor of 20.

  20. Study of microwave components for an electron cyclotron resonance ...

    Indian Academy of Sciences (India)

    Keywords. Microwave system; microwave studio software; network analyser; electron cyclotron resonance ion source. ... of ∼13 eV was obtained. This article describes various aspects of the microwave system including design, fabrication, characterization and performance studies of the microwave components.

  1. Electron cyclotron resonance heating in a short cylindrical plasma ...

    Indian Academy of Sciences (India)

    Electron cyclotron resonance (ECR) plasma is produced and studied in a small cylindrical system. Microwave power is delivered by a CW magnetron at 2.45 GHz in TE10 mode and launched radially to have extraordinary (X) wave in plasma. The axial magnetic field required for ECR in the system is such that the first two ...

  2. Cyclotron Resonance of Electrons Trapped in a Microwave Cavity

    Science.gov (United States)

    Elmore, W. C.

    1975-01-01

    Describes an experiment in which the free-electron cyclotron resonance of electrons trapped in a microwave cavity by a Penning trap is observed. The experiment constitutes an attractive alternative to one of the Gardner-Purcell variety. (Author/GS)

  3. Electron cyclotron resonance breakdown studies in a linear plasma ...

    Indian Academy of Sciences (India)

    Abstract. Electron cyclotron resonance (ECR) plasma breakdown is studied in a small linear cylindrical system with four different gases – hydrogen, helium, argon and nitrogen. Microwave power in the experimental system is delivered by a magnetron at 2.45 ± 0.02. GHz in TE10 mode and launched radially to have ...

  4. Study of microwave components for an electron cyclotron resonance ...

    Indian Academy of Sciences (India)

    rious aspects of the microwave system including design, fabrication, characterization and performance studies of the microwave components. Keywords. Microwave system; microwave studio software; network analyser; electron cyclotron resonance ion source. 1. Introduction. Microwave systems at 2.45 GHz have been ...

  5. Second-harmonic ion cyclotron resonance heating scenarios of ...

    Indian Academy of Sciences (India)

    ... Refresher Courses · Symposia · Live Streaming. Home; Journals; Pramana – Journal of Physics; Volume 85; Issue 4. Second-harmonic ion cyclotron resonance heating scenarios of Aditya tokamak plasma. Asim Kumar Chattopadhyay S V Kulkarni R Srinivasan Aditya Team. Volume 85 Issue 4 October 2015 pp 713-721 ...

  6. Application of compact electron cyclotron resonance ion source

    NARCIS (Netherlands)

    Muramatsu, M.; Kitagawa, A.; Iwata, Y.; Ogawa, H.; Hojo, S.; Kubo, T.; Kato, Y.; Biri, S.; Fekete, E.; Yoshida, Y.; Drentje, A. G.

    The compact electron cyclotron resonance (ECR) ion source with a permanent magnet configuration (Kei2 source) has been developed at National Institute of Radiological Sciences for a new carbon therapy facility. The Kei2 source was designed for production of C(4+) ions; its performance such as beam

  7. Ion–Cyclotron Resonance Frequency Interval Dependence on the O ...

    Indian Academy of Sciences (India)

    The frequency intervals in which O VI ions get in resonance with ion–cyclotron waves are calculated using the kinetic model, for the latest six values found in literature on O VI ion number densities in the 1.5–3 region of the NPCH. It is found that the common resonance interval is 1.5 kHz to 3 kHz. The -variations of wave ...

  8. Cyclotron Auto-Resonance Accelerator for environmental applications

    Science.gov (United States)

    Jiang, Yong; Shchelkunov, Sergey V.; Hirshfield, Jay L.

    2017-03-01

    A MW-level CW electron beam source for environmental remediation based on extensions of the scientifically-proven Cyclotron Auto-Resonance Accelerator, dubbed CARA, is described here. CARA is distinguished by its exceptionally high RF-to-beam efficiency, by its production of a self-scanning beam, and by its proportionately lower specific power loading on a beam output window. Its environmental applications include sterilization, flue gas and waste water treatment.

  9. Microwave power coupling with electron cyclotron resonance ...

    Indian Academy of Sciences (India)

    The effect of microwave power coupling to the plasma was studied by varying the microwave power. ... plasma is produced by the interaction of microwave radiation, in the presence of appro- priate magnetic field ... microwaves are used in resonant mode to couple the electromagnetic energy to the plasma for generating ...

  10. Monte Carlo simulation of cyclotron resonant scattering features

    Science.gov (United States)

    Schwarm, Fritz-Walter; Schönherr, Gabriele; Wilms, Joern

    In the regime of very high magnetic fields on the order of 10(12} mathrm{G) the electron momenta perpendicular to the field are quantized due to the discrete Landau levels populated by the electrons. Parallel to the magnetic field the electrons form a continuous momentum distribution. The seed photon continuum is generated for example by bremsstrahlung or blackbody radiation. Resonant scattering of a seed photon by an electron may excite the electron to a higher Landau level. The subsequent de-excitation of the excited electron produces additional photons close to the resonance energy. This way complex cyclotron resonant scattering features (CRSFs) are imprinted on the continuum radiation. Due to the continuous electron momentum distribution parallel to the magnetic field the scattering photon's energy and angle are mixed by Lorentz transformation to the electron rest frame in which the resonant scattering process is being carried out. Therefore synthetic spectra of cyclotron lines can not be accurately calculated analytically. CRSFs have been observed in more than a dozen accreting X-ray binaries. They provide much information about the accretion structure in the observed systems since the exact line shape is sensitive to many parameters in the column. Typical parameters are for example the geometry and the spectral properties of seed photon sources, the geometry of the column, or the magnetic field and temperature within the column. We present an overview over the Monte-Carlo approach to cyclotron line simulation and show results from our texttt{cyclosim} code. Furthermore we investigate the influence of the accretion geometry on the cyclotron line shape. Our code enables us to perform fully relativistic simulations including the correct cyclotron scattering cross sections and the possibility to cope with parameter gradients such as magnetic field, temperature, or velocity gradients within the accretion column. Using a Green's function approach these simulations

  11. Glow plasma trigger for electron cyclotron resonance ion sources.

    Science.gov (United States)

    Vodopianov, A V; Golubev, S V; Izotov, I V; Nikolaev, A G; Oks, E M; Savkin, K P; Yushkov, G Yu

    2010-02-01

    Electron cyclotron resonance ion sources (ECRISs) are particularly useful for nuclear, atomic, and high energy physics, as unique high current generators of multicharged ion beams. Plasmas of gas discharges in an open magnetic trap heated by pulsed (100 micros and longer) high power (100 kW and higher) high-frequency (greater than 37.5 GHz) microwaves of gyrotrons is promising in the field of research in the development of electron cyclotron resonance sources for high charge state ion beams. Reaching high ion charge states requires a decrease in gas pressure in the magnetic trap, but this method leads to increases in time, in which the microwave discharge develops. The gas breakdown and microwave discharge duration becomes greater than or equal to the microwave pulse duration when the pressure is decreased. This makes reaching the critical plasma density initiate an electron cyclotron resonance (ECR) discharge during pulse of microwave gyrotron radiation with gas pressure lower than a certain threshold. In order to reduce losses of microwave power, it is necessary to shorten the time of development of the ECR discharge. For fast triggering of ECR discharge under low pressure in an ECRIS, we initially propose to fill the magnetic trap with the plasmas of auxiliary pulsed discharges in crossed ExB fields. The glow plasma trigger of ECR based on a Penning or magnetron discharge has made it possible not only to fill the trap with plasma with density of 10(12) cm(-3), required for a rapid increase in plasma density and finally for ECR discharge ignition, but also to initially heat the plasma electrons to T(e) approximately = 20 eV.

  12. Static harmonization of dynamically harmonized Fourier transform ion cyclotron resonance cell.

    Science.gov (United States)

    Zhdanova, Ekaterina; Kostyukevich, Yury; Nikolaev, Eugene

    2017-08-01

    Static harmonization in the Fourier transform ion cyclotron resonance cell improves the resolving power of the cell and prevents dephasing of the ion cloud in the case of any trajectory of the charged particle, not necessarily axisymmetric cyclotron (as opposed to dynamic harmonization). We reveal that the Fourier transform ion cyclotron resonance cell with dynamic harmonization (paracell) is proved to be statically harmonized. The volume of the statically harmonized potential distribution increases with an increase in the number of trap segments.

  13. Optically detected cyclotron resonance in a single GaAs/AlGaAs heterojunction

    Energy Technology Data Exchange (ETDEWEB)

    Bartsch, Gregor

    2011-09-23

    Optically detected far-infrared cyclotron resonance (FIR-ODCR) in GaAs/AlGaAs HJs is interpreted in the frame of an exciton-dissociation mechanism. It is possible to explain the ODR mechanism by an exciton drag, mediated by ballistically propagating phonons. Furthermore, very narrow resonances are presented and realistic electron mobility values can be calculated. The exceptionally narrow ODCRs allow to measure conduction-band nonparabolicity effects and resolve satellite resonances, close to the main cyclotron resonance line.

  14. Effect of ion clouds micromotion on measured signal in Fourier transform ion cyclotron resonance: Computer simulation.

    Science.gov (United States)

    Vladimirov, Gleb; Kostyukevich, Yury; Kharybin, Oleg; Nikolaev, Eugene

    2017-08-01

    Particle-in-cell-based realistic simulation of Fourier transform ion cyclotron resonance experiments could be used to generate ion trajectories and a signal induced on the detection electrodes. It has been shown recently that there is a modulation of "reduced" cyclotron frequencies in ion cyclotron resonance signal caused by Coulomb interaction of ion clouds. In this work it was proposed to use this modulation in order to determine frequency difference between an ion of known m/z and all other ions generating signal in ion cyclotron resonance cell. It is shown that with an increase of number of ions in ion cyclotron resonance trap, the modulation index increases, which lead to a decrease in the accuracy of determination of peak intensities by super Fourier transform resolution methods such as filter diagonalization method.

  15. Numerical model of electron cyclotron resonance ion source

    Directory of Open Access Journals (Sweden)

    V. Mironov

    2015-12-01

    Full Text Available Important features of the electron cyclotron resonance ion source (ECRIS operation are accurately reproduced with a numerical code. The code uses the particle-in-cell technique to model the dynamics of ions in ECRIS plasma. It is shown that a gas dynamical ion confinement mechanism is sufficient to provide the ion production rates in ECRIS close to the experimentally observed values. Extracted ion currents are calculated and compared to the experiment for a few sources. Changes in the simulated extracted ion currents are obtained with varying the gas flow into the source chamber and the microwave power. Empirical scaling laws for ECRIS design are studied and the underlying physical effects are discussed.

  16. The Electron Cyclotron Resonance Light Source Assembly of PTB - ELISA

    CERN Document Server

    Gruebling, P; Ulm, G

    1999-01-01

    In the radiometry laboratory of the Physikalisch-Technische,Bundesanstalt at the Berlin electron storage ring BESSY I, radiation sources for radiometric applications in industry and basic research in the vacuum ultraviolet (VUV) spectral range are developed, characterized and calibrated. Established sources such as deuterium lamps, Penning and hollow cathode discharge sources have limited spectral ranges and in particular their stability and life time suffers from the erosion of the cathode material. To overcome these limitations we have developed a radiation source based on the principle of the electron cyclotron resonance ion source. ELISA is a 10 GHz monomode source with a compact design featuring a tunable cavity and axially positionable permanent magnets. The radiation emission of the source can be detected simultaneously in the VUV and X-ray spectral range via a toroidal grating monochromator and a Si(Li)-detector. The special design of the source allows spectroscopic investigations of the plasma in dep...

  17. Data processing in Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Qi, Yulin; O'Connor, Peter B

    2014-01-01

    The Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer intricately couples advanced physics, instrumentation, and electronics with chemical and particularly biochemical research. However, general understanding of the data processing methodologies used lags instrumentation, and most data processing algorithms we are familiar with in FT-ICR are not well studied; thus, professional skill and training in FT-ICR operation and data analysis is still the key to achieve high performance in FT-ICR. This review article is focused on FT-ICR data processing, and explains the procedures step-by-step for users with the goal of maximizing spectral features, such as mass accuracy, resolving power, dynamic range, and detection limits. © 2014 Wiley Periodicals, Inc.

  18. Cyclotron Resonance Gain for FIR and THz Radiation in Graphene

    CERN Document Server

    Cole, Nightvid

    2016-01-01

    A cyclotron resonance maser source using low-effective-mass conduction electrons in graphene, if successful, would allow for generation of Far Infrared (FIR) and Terahertz (THz) radiation without requiring magnetic fields running into the tens of Tesla. In order to investigate this possibility, we consider a device in which electrons are effectively injected via pumping from the valence band to the conduction band using an infrared (IR) laser source, subsequently gyrate in a magnetic field applied perpendicular to the plane of the graphene, and give rise to gain for a FIR/THz wave crossing the plane of the graphene. A set of integral expressions is derived by assuming that the non-radiative energy loss processes of the electrons can be adequately represented by a damping force proportional and antiparallel to their momentum. Minimal gain may occur at very short electron damping times of hundreds of femtoseconds.

  19. Ion cyclotron resonance heating system in the RT-1 magnetospheric plasma

    Science.gov (United States)

    Nishiura, M.; Kawazura, Y.; Yoshida, Z.; Kenmochi, N.; Yano, Y.; Saitoh, H.; Yamasaki, M.; Mushiake, T.; Kashyap, A.; Takahashi, N.; Nakatsuka, M.; Fukuyama, A.

    2017-08-01

    We have developed an ion cyclotron resonance frequency (ICRF) heating system for the Ring Trap 1 (RT-1) magnetospheric device. We excite slow waves from the polar region of the dipole magnetic field. The target helium plasma is produced by electron cyclotron heating. The electrons comprise high-temperature (>10 keV) and low-temperature (wave electric field in the plasma.

  20. Second-harmonic ion cyclotron resonance heating scenarios of ...

    Indian Academy of Sciences (India)

    at high field side. Direct electron heating experiment on the Aditya tokamak using fast waves (FW) in the IC frequency range has already been carried out in [3] and ... 1Spec (solid line) shows the power deposition profile of ions due to ... The vertical line indicates the second-harmonic resonance layer for hydrogen ions. 716.

  1. Real-time beam tracing for control of the deposition location of electron cyclotron waves

    Energy Technology Data Exchange (ETDEWEB)

    Reich, M., E-mail: matthias.reich@ipp.mpg.de; Bilato, R.; Mszanowski, U.; Poli, E.; Rapson, C.; Stober, J.; Volpe, F.; Zille, R.

    2015-11-15

    Highlights: • We successfully integrated a real-time EC beam tracing code at ASDEX Upgrade. • The calculation of EC beam deposition location is fast enough for control purposes. • The accuracy of the deposition location calculation exceeds equivalent measurements. • The implementation method is by design portable to larger fusion devices. - Abstract: Plasma control techniques that use electron cyclotron (EC) resonance heating and current drive such as control of neoclassical tearing modes require accurate control of the deposition location of EC beams. ASDEX Upgrade has successfully implemented a real-time version of the beam-tracing code TORBEAM into its real-time diagnostic system to act as a globally available module that calculates current deposition location and its sensitivity from other real-time diagnostic measurements for all its moveable EC wave launchers. Based on a highly (100×) accelerated version of TORBEAM, the software implementation as a diagnostic process uses parallelization and achieves cycle times of 15–20 ms for determining the radial deposition location of 12 beams in the plasma. This cycle time includes data input–output overhead arising from the use of available real-time signals. The system is by design portable to other machines such as ITER.

  2. Comparison of characteristics of fluorine doped zinc and gallium tin oxide composite thin films deposited on stainless steel 316 bipolar plate by electron cyclotron resonance-metal organic chemical vapor deposition for proton exchange membrane fuel cells.

    Science.gov (United States)

    Park, Jihun; Hudaya, Chairul; Lee, Joong Kee

    2011-09-01

    In order to replace the brittle graphite bipolar plates currently used for the PEMFC stack, coated SUS 316 was employed. As a metallic bipolar plate, coated SUS 316 can provide higher mechanical strength, better durability to shocks and vibration, less permeability, improved thermal and bulk electrical conductivity, as well as being thinner and lighter. To enhance the interfacial contact resistance and corrosion resistance of SUS 316, the deposition of GTO:F and ZTO:F composite films was carried out by ECR-MOCVD. The surface morphology of the films consisted of tiny elliptically shaped grains with a thickness of 1 microm. The corrosion current for GTO:F was 0.13 Acm(-2) which was much lower than that of bare SUS 316 (50.16 Acm(-2)). The GTO:F coated film had the smallest corrosion current due to the formation of a tight surface morphology with very few pin-holes. The GTO:F coated film exhibited the highest cell voltage and power density due to its lower ICR values.

  3. Parallel Spectral Acquisition with an Ion Cyclotron Resonance Cell Array.

    Science.gov (United States)

    Park, Sung-Gun; Anderson, Gordon A; Navare, Arti T; Bruce, James E

    2016-01-19

    Mass measurement accuracy is a critical analytical figure-of-merit in most areas of mass spectrometry application. However, the time required for acquisition of high-resolution, high mass accuracy data limits many applications and is an aspect under continual pressure for development. Current efforts target implementation of higher electrostatic and magnetic fields because ion oscillatory frequencies increase linearly with field strength. As such, the time required for spectral acquisition of a given resolving power and mass accuracy decreases linearly with increasing fields. Mass spectrometer developments to include multiple high-resolution detectors that can be operated in parallel could further decrease the acquisition time by a factor of n, the number of detectors. Efforts described here resulted in development of an instrument with a set of Fourier transform ion cyclotron resonance (ICR) cells as detectors that constitute the first MS array capable of parallel high-resolution spectral acquisition. ICR cell array systems consisting of three or five cells were constructed with printed circuit boards and installed within a single superconducting magnet and vacuum system. Independent ion populations were injected and trapped within each cell in the array. Upon filling the array, all ions in all cells were simultaneously excited and ICR signals from each cell were independently amplified and recorded in parallel. Presented here are the initial results of successful parallel spectral acquisition, parallel mass spectrometry (MS) and MS/MS measurements, and parallel high-resolution acquisition with the MS array system.

  4. Two-chamber configuration of Bio-Nano electron cyclotron resonance ion source for fullerene modification

    Energy Technology Data Exchange (ETDEWEB)

    Uchida, T., E-mail: uchida-t@toyo.jp [Bio-Nano Electronics Research Centre, Toyo University, Kawagoe 350-8585 (Japan); Graduate School of Interdisciplinary New Science, Toyo University, Kawagoe 350-8585 (Japan); Rácz, R.; Biri, S. [Institute for Nuclear Research (Atomki), Hungarian Academy of Sciences, Bem tér 18/C, H-4026 Debrecen (Hungary); Muramatsu, M.; Kitagawa, A. [National Institute of Radiological Sciences (NIRS), Chiba 263-8555 (Japan); Kato, Y. [Graduate School of Engineering, Osaka University, Suita 565-0871 (Japan); Yoshida, Y. [Bio-Nano Electronics Research Centre, Toyo University, Kawagoe 350-8585 (Japan); Faculty of Science and Engineering, Toyo University, Kawagoe 350-8585 (Japan)

    2016-02-15

    We report on the modification of fullerenes with iron and chlorine using two individually controllable plasmas in the Bio-Nano electron cyclotron resonance ion source (ECRIS). One of the plasmas is composed of fullerene and the other one is composed of iron and chlorine. The online ion beam analysis allows one to investigate the rate of the vapor-phase collisional modification process in the ECRIS, while the offline analyses (e.g., liquid chromatography-mass spectrometry) of the materials deposited on the plasma chamber can give information on the surface-type process. Both analytical methods show the presence of modified fullerenes such as fullerene-chlorine, fullerene-iron, and fullerene-chlorine-iron.

  5. Two-chamber configuration of Bio-Nano electron cyclotron resonance ion source for fullerene modification.

    Science.gov (United States)

    Uchida, T; Rácz, R; Muramatsu, M; Kato, Y; Kitagawa, A; Biri, S; Yoshida, Y

    2016-02-01

    We report on the modification of fullerenes with iron and chlorine using two individually controllable plasmas in the Bio-Nano electron cyclotron resonance ion source (ECRIS). One of the plasmas is composed of fullerene and the other one is composed of iron and chlorine. The online ion beam analysis allows one to investigate the rate of the vapor-phase collisional modification process in the ECRIS, while the offline analyses (e.g., liquid chromatography-mass spectrometry) of the materials deposited on the plasma chamber can give information on the surface-type process. Both analytical methods show the presence of modified fullerenes such as fullerene-chlorine, fullerene-iron, and fullerene-chlorine-iron.

  6. Stabilization of ion fishbone activities by electron cyclotron resonance heating in a toroidal plasma

    Science.gov (United States)

    Chen, W.; Yu, L. M.; Shi, P. W.; Ma, R.; Ji, X. Q.; Jiang, M.; Zhu, X. L.; Shi, Z. B.; Yu, D. L.; Yuan, B. S.; Li, Y. G.; Yang, Z. C.; Cao, J. Y.; Song, S. D.; Zhong, W. L.; He, H. D.; Dong, J. Q.; Ding, X. T.; Yan, L. W.; Liu, Yi.; Yang, Q. W.; Xu, M.; Duan, X. R.

    2018-01-01

    We report an experimental result on the stabilization of the energetic–ion driven internal kink mode (ion fishbone) by electron cyclotron resonance heating (ECRH), observed for the first time in a toroidal plasma. The mode asserts itself a resistive branch close to the marginal stability point. The resulting fishbone mode depends not only on the injected power but also on the radial deposition location of ECRH, and the instability can be completely suppressed when the injected ECRH power exceeds certain threshold. Analysis by the fishbone dispersion relation, including the resistive effect, suggests that the magnetic Reynolds number plays a key role in the mode stabilization—it weakens the mode growth-rate and enhances the critical energetic–ion beta without changing the energetic–ion population. This ion fishbone stabilization mechanism can be important for future devices such as ITER, which has significant ECRH capability.

  7. Summary of EC-17: the 17th Joint Workshop on Electron Cyclotron Emission and Electron Cyclotron Resonance Heating (Deurne, The Netherlands, 7-10 May 2012)

    NARCIS (Netherlands)

    Westerhof, E.; Austin, M. E.; Kubo, S.; Lin-Liu, Y. R.; Plaum, B.

    2013-01-01

    An overview is given of the papers presented at the 17th Joint Workshop on Electron Cyclotron Emission (ECE) and Electron Cyclotron Resonance Heating (ECRH). The meeting covered all aspects of the research field ranging from theory to enabling technologies. From the workshop, advanced control by

  8. Relativistic Cyclotron Resonance Shape in Magnetic Bottle Geonium

    National Research Council Canada - National Science Library

    Hans Dehmelt; Richard Mittleman; Yuan Liu

    1988-01-01

    The thermally excited axial oscillation of the electron through the weak magnetic bottle needed for the continuous Stern-Gerlach effect modulates the cyclotron frequency and produces a characteristic...

  9. Electron cyclotron resonance heating in the microwave tokamak experiment

    Energy Technology Data Exchange (ETDEWEB)

    Allen, S.L.; Casper, T.A.; Fenstermacher, M.E. [and others

    1992-09-01

    This paper presents the results from a series of Electron Cyclotron Resonance Heating (ECRH) experiments on the Microwave Tokamak Experiment (MTX). On-axis heating at B{sub T} = 5T (f{sub ce} = 140 GHz) has been performed at electron densities up to cutoff. We have used both a long-pulse gryotron ({approximately}200 kW, {approximately}0.1s) and a pulsed Free Electron Laser (FEL) as microwave sources. Gyrotron experiments with power densities corresponding to 4 MW m{sup {minus}3}. A far infrared (FIR) polarimeter measured peaking of plasma current profiles in some discharges during the ECRH pulse. During high-power single-pulse FEL experiments, single-pass microwave !transmission measurements show nonlinear effects; i.e., higher transmission than predicted by linear theory. A corrugated-wall duct was used in the tokamak port to increase the gradient of the parallel refractive index n{sub parallel} of the incident wave, and increased absorption was observed. Evidence of electron tail heating during FEL pulses was observed on soft x-ray and ECE diagnostics. These results are in agreement with predictions of nonlinear theory; extrapolation of this theory to reactor-like conditions indicates efficient absorption and heating. A Laser Assisted Particle Probe Spectroscopy (LAPPS) diagnostic provided estimates of the vacuum electric field of the FEL which were consistent with the measured power. Multiple pulse operation of the ETA-II accelerator for the FEL has also been demonstrated, indicating the feasibility of high-average power FEL operation.

  10. Status of a compact electron cyclotron resonance ion source for National Institute of Radiological Sciences-930 cyclotron.

    Science.gov (United States)

    Hojo, S; Katagiri, K; Nakao, M; Sugiura, A; Muramatsu, M; Noda, A; Okada, T; Takahashi, Y; Komiyama, A; Honma, T; Noda, K

    2014-02-01

    The Kei-source is a compact electron cyclotron resonance ion source using only permanent magnets and a frequency of 10 GHz. It was developed at the National Institute of Radiological Sciences (NIRS) for producing C(4+) ions oriented for high-energy carbon therapy. It has also been used as an ion source for the NIRS-930 cyclotron. Its microwave band region for the traveling-wave-tube amplifier and maximum output power are 8-10 GHz and 350 W, respectively. Since 2006, it has provided various ion beams such as proton, deuteron, carbon, oxygen, and neon with sufficient intensity (200 μA for proton and deuteron, 50 μA for C(4+), for example) and good stability for radioisotope production, tests of radiation damage, and basic research experiments. Its horizontal and vertical emittances were measured using a screen monitor and waist-scan. The present paper reports the current status of the Kei-source.

  11. Status of a compact electron cyclotron resonance ion source for National Institute of Radiological Sciences-930 cyclotron

    Science.gov (United States)

    Hojo, S.; Katagiri, K.; Nakao, M.; Sugiura, A.; Muramatsu, M.; Noda, A.; Okada, T.; Takahashi, Y.; Komiyama, A.; Honma, T.; Noda, K.

    2014-02-01

    The Kei-source is a compact electron cyclotron resonance ion source using only permanent magnets and a frequency of 10 GHz. It was developed at the National Institute of Radiological Sciences (NIRS) for producing C4+ ions oriented for high-energy carbon therapy. It has also been used as an ion source for the NIRS-930 cyclotron. Its microwave band region for the traveling-wave-tube amplifier and maximum output power are 8-10 GHz and 350 W, respectively. Since 2006, it has provided various ion beams such as proton, deuteron, carbon, oxygen, and neon with sufficient intensity (200 μA for proton and deuteron, 50 μA for C4+, for example) and good stability for radioisotope production, tests of radiation damage, and basic research experiments. Its horizontal and vertical emittances were measured using a screen monitor and waist-scan. The present paper reports the current status of the Kei-source.

  12. Discrete-Spectrum Waves in the Vicinity of Cyclotron Resonance in Silver

    DEFF Research Database (Denmark)

    Henningsen, J. O.

    1970-01-01

    Cyclotron-resonance studies of silver have revealed two additional series of oscillations, one between the fundamental and the second harmonic, the other above the fundamental resonance. These series are caused by the excitation of weakly damped discrete-spectrum waves propagating perpendicular...

  13. Differentiating Fragmentation Pathways of Cholesterol by Two-Dimensional Fourier Transform Ion Cyclotron Resonance Mass Spectrometry.

    Science.gov (United States)

    van Agthoven, Maria A; Barrow, Mark P; Chiron, Lionel; Coutouly, Marie-Aude; Kilgour, David; Wootton, Christopher A; Wei, Juan; Soulby, Andrew; Delsuc, Marc-André; Rolando, Christian; O'Connor, Peter B

    2015-12-01

    Two-dimensional Fourier transform ion cyclotron resonance mass spectrometry is a data-independent analytical method that records the fragmentation patterns of all the compounds in a sample. This study shows the implementation of atmospheric pressure photoionization with two-dimensional (2D) Fourier transform ion cyclotron resonance mass spectrometry. In the resulting 2D mass spectrum, the fragmentation patterns of the radical and protonated species from cholesterol are differentiated. This study shows the use of fragment ion lines, precursor ion lines, and neutral loss lines in the 2D mass spectrum to determine fragmentation mechanisms of known compounds and to gain information on unknown ion species in the spectrum. In concert with high resolution mass spectrometry, 2D Fourier transform ion cyclotron resonance mass spectrometry can be a useful tool for the structural analysis of small molecules. Graphical Abstract ᅟ.

  14. A Tuning Method for Electrically Compensated Ion Cyclotron Resonance Mass Spectrometer Traps

    Science.gov (United States)

    Brustkern, Adam M.; Rempel, Don L.; Gross, Michael L.

    2010-01-01

    We describe a method for tuning electrically compensated ion cyclotron resonance (ICR) traps by tracking the observed cyclotron frequency of an ion cloud at different oscillation mode amplitudes. Although we have used this method to tune the compensation voltages of a custom-built electrically compensated trap, the approach is applicable to other designs that incorporate electrical compensation. To evaluate the effectiveness of tuning, we examined the frequency shift as a function of cyclotron orbit size at different z-mode oscillation amplitudes. The cyclotron frequencies varied by ~ 12 ppm for ions with low z-mode oscillation amplitudes compared to those with high z-mode amplitudes. This frequency difference decreased to ~1 ppm by one iteration of trap tuning. PMID:20060743

  15. Cyclotron resonance in InAs/GaSb heterostructure in inclined magnetic field

    CERN Document Server

    Greshnov, A A; Vasilev, Yu B; Suchalkin, S D; Meltser, B Y; Ivanov, S V; Kopev, P S

    2002-01-01

    The mechanism of splitting the cyclotron resonance line in the InAs/GaSb heterostructure in the inclined magnetic field is experimentally and theoretically studied. It is shown that the electrons and holes mixing in leads to the anticrossing Landau levels and consequently to the cyclotron resonance line splitting. Splitting in the case of the inclined magnetic field was not observed which is explained by damping the electrons and holes states mixing in on the account of originating the additional barrier for the electrons and holes by availability of the magnetic field longitudinal constituent

  16. Status report of the multipurpose superconducting electron cyclotron resonance ion source

    NARCIS (Netherlands)

    Ciavola, G.; Gammino, S.; Barbarino, S.; Celona, L.; Consoli, F.; Gallo, G.; Maimone, F.; Mascali, D.; Passarello, S.; Galata, A.; Tinschert, K.; Spaedtke, P.; Lang, R.; Maeder, J.; Rossbach, J.; Koivisto, H.; Savonen, M.; Koponen, T.; Suominen, P.; Ropponen, T.; Barue, C.; Lechartier, M.; Beijers, J. P. M.; Brandenburg, S.; Kremers, H. R.; Vanrooyen, D.; Kuchler, D.; Scrivens, R.; Schachter, L.; Dobrescu, S.; Stiebing, K.

    Intense heavy ion beam production with electron cyclotron resonance (ECR) ion sources is a common requirement for many of the accelerators under construction in Europe and elsewhere. An average increase of about one order of magnitude per decade in the performance of ECR ion sources was obtained up

  17. Analysis of Chaperone Complexes by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry

    NARCIS (Netherlands)

    Geels, R.B.J.

    2008-01-01

    Investigation of methodologies for analyses of noncovalently bound protein assemblies using Fourier transformation ion cyclotron resonance mass spectrometry (FT-ICR-MS) and quadrupole Time-of-Flight (qToF) mass spectrometry. Specifically, the co-chaperonins GroEL and gp31 are used to perform

  18. Three-wave interaction during electron cyclotron resonance heating and current drive

    DEFF Research Database (Denmark)

    Nielsen, Stefan Kragh; Jacobsen, Asger Schou; Hansen, Søren Kjer

    2016-01-01

    Non-linear wave-wave interactions in fusion plasmas, such as the parametric decay instability (PDI) of gyrotron radiation, can potentially hamper the use of microwave diagnostics. Here we report on anomalous scattering in the ASDEX Upgrade tokamak during electron cyclotron resonance heating...

  19. On-line microseparations with Fourier transform ion cyclotron resonance mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Wahl, J.H.; Hofstadler, S.A.; Zhao, Zhongxi; Gale, D.C.; Smith, R.D. [Pacific Northwest Lab., Richland, WA (United States)

    1994-12-31

    The combination of capillary electrophoresis (CE) with electrospray ionization mass spectrometry (ESI/MS) is a powerful bioanalytical tool. Accurate charge states are readily obtained through high resolution MS techniques such as Fourier transform ion cyclotron resonance (FTICR) mass spectrometry. In this study, the authors examine the practical considerations that were necessary for successful on-line CE-ESI/FTICR MS.

  20. Techniques and mechanisms applied in electron cyclotron resonance sources for highly charged ions

    NARCIS (Netherlands)

    Drentje, AG

    Electron cyclotron resonance ion sources are delivering beams of highly charged ions for a wide range of applications in many laboratories. For more than two decades, the development of these ion sources has been to a large extent an intuitive and experimental enterprise. Much effort has been spent

  1. Three-dimensional simulations of ion dynamics in an Electron Cyclotron Resonance Ion Source

    NARCIS (Netherlands)

    Beijers, J. P. M.; Mironov, V.

    We present a three-dimensional simulation of the ion dynamics in an electron cyclotron resonance ion source. Ion trajectories in the min-B field of the source are calculated taking ion-ion and electron-ion collisions into account. The electrons are not tracked but considered as a neutralizing

  2. Abrupt variation in ion current with biased disk voltage in the electron cyclotron resonance ion source

    NARCIS (Netherlands)

    Taki, GS; Sarma, PR; Chakraborty, DK; Lhandari, RK; Ray, PK; Drentje, AG; Bhandari, R.K.

    The performance of the biased disk in the 6.4 GHz electron cyclotron resonance ion source at VECC, Kolkata was studied at a pressure of similar to 1 X 10(-7) Torr. We observed an abrupt variation of beam current with bias voltage. For low negative bias voltages (from 0 to -5 V) the beam current

  3. Experiments with biased cylinder in electron cyclotron resonance ion source (plenary)

    NARCIS (Netherlands)

    Drentje, AG; Kitagawa, A; Muramatsu, M; Ogawa, H; Sakamoto, Y

    The shape of the magnetic field of an electron cyclotron resonance ion source (ECRIS) gives rise to different particle fluxes (losses) from the plasma to the end plates (mainly diffusion of electrons), and to the side walls (mainly ions). The electron fluxes to the injection end plate can be reduced

  4. Selective minority-ion heating in the afterglow of an electron cyclotron resonance ion source

    NARCIS (Netherlands)

    Nadzeyka, A; Meyer, D; Barzangy, F; Drentje, AG; Wiesemann, K

    We report first experimental results on selective minority-ion heating in the afterglow mode of electron cyclotron resonance ion sources in Bochum and at the KVI (Groningen) in mixtures of Ar/O/He and in pure nitrogen. In addition we measured time resolved vacuum ultraviolet-line intensities of

  5. Isotopic anomaly for carbon ions in an electron cyclotron resonance ion source

    NARCIS (Netherlands)

    Drentje, A. G.; Kitagawa, A.; Muramatsu, M.

    In many experiments methods were applied to increase the highly charged ion output from an electron cyclotron resonance ion source; the gas-mixing method is still generally being applied. The dominant role of the masses of the ions in the gas-mixture was apparent. Two basically differing mechanisms

  6. Bounce Resonance Scattering of Radiation Belt Electrons by Low-Frequency Hiss: Comparison With Cyclotron and Landau Resonances

    Science.gov (United States)

    Cao, Xing; Ni, Binbin; Summers, Danny; Zou, Zhengyang; Fu, Song; Zhang, Wenxun

    2017-10-01

    Bounce resonant interactions with magnetospheric waves have been proposed as an important contributing mechanism for scattering near-equatorially mirroring electrons by violating the second adiabatic invariant associated with the electron bounce motion along a geomagnetic field line. This study demonstrates that low-frequency plasmaspheric hiss with significant wave power below 100 Hz can bounce resonate efficiently with radiation belt electrons. By performing quantitative calculations of pitch angle scattering rates, we show that low-frequency hiss-induced bounce resonant scattering of electrons has a strong dependence on equatorial pitch angle αeq. For electrons with αeq close to 90°, the timescale associated with bounce resonance scattering can be comparable to or even less than 1 h. Cyclotron and Landau resonant interactions between low-frequency hiss and electrons are also investigated for comparisons. It is found that while the bounce and Landau resonances are responsible for the diffusive transport of near-equatorially mirroring electrons to lower αeq, pitch angle scattering by cyclotron resonance could take over to further diffuse electrons into the atmosphere. Bounce resonance provides a more efficient pitch angle scattering mechanism of relativistic (≥1 MeV) electrons than Landau resonance due to the stronger scattering rates and broader resonance coverage of αeq, thereby demonstrating that bounce resonance scattering by low-frequency hiss can contribute importantly to the evolution of the electron pitch angle distribution and the loss of radiation belt electrons.

  7. Development of an 18 GHz superconducting electron cyclotron resonance ion source at RCNP.

    Science.gov (United States)

    Yorita, Tetsuhiko; Hatanaka, Kichiji; Fukuda, Mitsuhiro; Kibayashi, Mitsuru; Morinobu, Shunpei; Okamura, Hiroyuki; Tamii, Atsushi

    2008-02-01

    An 18 GHz superconducting electron cyclotron resonance ion source has recently been developed and installed in order to extend the variety and the intensity of ions at the RCNP coupled cyclotron facility. Production of several ions such as O, N, Ar, Kr, etc., is now under development and some of them have already been used for user experiments. For example, highly charged heavy ion beams like (86)Kr(21+,23+) and intense (16)O(5+,6+) and (15)N(6+) ion beams have been provided for experiments. The metal ion from volatile compounds method for boron ions has been developed as well.

  8. Lorentz force in water: evidence that hydronium cyclotron resonance enhances polymorphism.

    Science.gov (United States)

    D'Emilia, E; Giuliani, L; Lisi, A; Ledda, M; Grimaldi, S; Montagnier, L; Liboff, A R

    2015-01-01

    There is an ongoing question regarding the structure forming capabilities of water at ambient temperatures. To probe for different structures, we studied effects in pure water following magnetic field exposures corresponding to the ion cyclotron resonance of H3O(+). Included were measurements of conductivity and pH. We find that under ion cyclotron resonance (ICR) stimulation, water undergoes a transition to a form that is hydroxonium-like, with the subsequent emission of a transient 48.5 Hz magnetic signal, in the absence of any other measurable field. Our results indicate that hydronium resonance stimulation alters the structure of water, enhancing the concentration of EZ-water. These results are not only consistent with Del Giudice's model of electromagnetically coherent domains, but they can also be interpreted to show that these domains exist in quantized spin states.

  9. Results of RIKEN superconducting electron cyclotron resonance ion source with 28 GHz.

    Science.gov (United States)

    Higurashi, Y; Ohnishi, J; Nakagawa, T; Haba, H; Tamura, M; Aihara, T; Fujimaki, M; Komiyama, M; Uchiyama, A; Kamigaito, O

    2012-02-01

    We measured the beam intensity of highly charged heavy ions and x-ray heat load for RIKEN superconducting electron cyclotron resonance ion source with 28 GHz microwaves under the various conditions. The beam intensity of Xe(20+) became maximum at B(min) ∼ 0.65 T, which was ∼65% of the magnetic field strength of electron cyclotron resonance (B(ECR)) for 28 GHz microwaves. We observed that the heat load of x-ray increased with decreasing gas pressure and field gradient at resonance zone. It seems that the beam intensity of highly charged heavy ions with 28 GHz is higher than that with 18 GHz at same RF power.

  10. Studies on a Q/A selector for the SECRAL electron cyclotron resonance ion source.

    Science.gov (United States)

    Yang, Y; Sun, L T; Feng, Y C; Fang, X; Lu, W; Zhang, W H; Cao, Y; Zhang, X Z; Zhao, H W

    2014-08-01

    Electron cyclotron resonance ion sources are widely used in heavy ion accelerators in the world because they are capable of producing high current beams of highly charged ions. However, the design of the Q/A selector system for these devices is challenging, because it must have a sufficient ion resolution while controlling the beam emittance growth. Moreover, this system has to be matched for a wide range of ion beam species with different intensities. In this paper, research on the Q/A selector system at the SECRAL (Superconducting Electron Cyclotron Resonance ion source with Advanced design in Lanzhou) platform both in experiment and simulation is presented. Based on this study, a new Q/A selector system has been designed for SECRAL II. The features of the new design including beam simulations are also presented.

  11. Spin-orbit splitting of the cyclotron resonance in GaAs

    Science.gov (United States)

    Tonello, P.; Lipparini, E.

    2004-08-01

    We have studied the relevance of spin-orbit coupling to the splitting of the cyclotron resonance of electron space-charge layers in GaAs recently observed by Manger [Phys. Rev. B 63, 121203R (2001)]. We show that the spin-orbit interaction couples density and spin-density excitations in the long-wavelength limit and is able to explain all the features observed in the experiment.

  12. Cyclotron resonance in InAs/AlSb quantum wells in magnetic fields up to 45 T

    Energy Technology Data Exchange (ETDEWEB)

    Spirin, K. E., E-mail: spirink@ipmras.ru; Krishtopenko, S. S. [Russian Academy of Sciences, Institute for Physics of Microstructures (Russian Federation); Sadofyev, Yu. G. [Russian Academy of Sciences, Lebedev Physical Institute (Russian Federation); Drachenko, O. [Laboratoire National des Champs Magn’etiques Intenses (France); Helm, M. [Forschungszentrum Dresden–Rossendorf, Dresden High-Magnetic-Field Laboratory and Institute of Ion-Beam Physics and Materials Research (Germany); Teppe, F.; Knap, W. [GIS-TERALAB Universite Montpellier II, Laboratoire Charles Coulomb UMR CNRS 5221 (L2C) (France); Gavrilenko, V. I. [Russian Academy of Sciences, Institute for Physics of Microstructures (Russian Federation)

    2015-12-15

    Electron cyclotron resonance in InAs/AlSb heterostructures with quantum wells of various widths in pulsed magnetic fields up to 45 T are investigated. Our experimental cyclotron energies are in satisfactory agreement with the results of theoretical calculations performed using the eight-band kp Hamiltonian. The shift of the cyclotron resonance (CR) line, which corresponds to the transition from the lowest Landau level to the low magnetic-field region, is found upon varying the electron concentration due to the negative persistent photoconductivity effect. It is shown that the observed shift of the CR lines is associated with the finite width of the density of states at the Landau levels.

  13. Electron Cloud Cyclotron Resonances in the Presence of a Short-bunch-length Relativistic Beam

    Energy Technology Data Exchange (ETDEWEB)

    Celata, C.M.; Furman, Miguel A.; Vay, J.-L.; Yu, Jennifer W.

    2008-09-02

    Computer simulations using the 2D code"POSINST" were used to study the formation of the electron cloud in the wiggler section of the positron damping ring of the International Linear Collider. In order to simulate an x-y slice of the wiggler (i.e., a slice perpendicular to the beam velocity), each simulation assumed a constant vertical magnetic field. At values of the magnetic field where the cyclotron frequency was an integral multiple of the bunch frequency, and where the field strength was less than approximately 0.6 T, equilibrium average electron densities were up to three times the density found at other neighboring field values. Effects of this resonance between the bunch and cyclotron frequency are expected to be non-negligible when the beam bunch length is much less than the product of the electron cyclotron period and the beam velocity, for a beam moving at v~;;c. Details of the dynamics of the resonance are described.

  14. Sensitive test for ion-cyclotron resonant heating in the solar wind.

    Science.gov (United States)

    Kasper, Justin C; Maruca, Bennett A; Stevens, Michael L; Zaslavsky, Arnaud

    2013-03-01

    Plasma carrying a spectrum of counterpropagating field-aligned ion-cyclotron waves can strongly and preferentially heat ions through a stochastic Fermi mechanism. Such a process has been proposed to explain the extreme temperatures, temperature anisotropies, and speeds of ions in the solar corona and solar wind. We quantify how differential flow between ion species results in a Doppler shift in the wave spectrum that can prevent this strong heating. Two critical values of differential flow are derived for strong heating of the core and tail of a given ion distribution function. Our comparison of these predictions to observations from the Wind spacecraft reveals excellent agreement. Solar wind helium that meets the condition for strong core heating is nearly 7 times hotter than hydrogen on average. Ion-cyclotron resonance contributes to heating in the solar wind, and there is a close link between heating, differential flow, and temperature anisotropy.

  15. Development and experimental evaluation of theoretical models for ion cyclotron resonance frequency heating of tokamak plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Mantsinen, M. [Helsinki Univ. of Technology, Espoo (Finland). Dept. of Technical Physics

    1999-06-01

    Heating with electromagnetic waves in the ion cyclotron range of frequencies (ICRF) is a well-established method for auxiliary heating of present-day tokamak plasmas and is envisaged as one of the main heating techniques for the International Thermonuclear Experimental Reactor (ITER) and future reactor plasmas. In order to predict the performance of ICRF heating in future machines, it is important to benchmark present theoretical modelling with experimental results on present tokamaks. This thesis reports on development and experimental evaluation of theoretical models for ICRF heating at the Joint European Torus (JET). Several ICRF physics effects and scenarios have been studied. Direct importance to the ITER is the theoretical analysis of ICRF heating experiments with deuterium-tritium (D-T) plasmas. These experiments clearly demonstrate the potential of ICRF heating for auxiliary heating of reactor plasmas. In particular, scenarios with potential for good bulk ion heating and enhanced D-T fusion reactivity have been identified. Good bulk ion heating is essential for reactor plasmas in order to obtain a high ion temperature and a high fusion reactivity. In JET good bulk ion heating with ICRF waves has been achieved in high-performance discharges by adding ICRF heating to neutral beam injection. In these experiments, as in other JET discharges where damping at higher harmonics of the ion cyclotron frequency takes place, so-called finite Larmor radius (FLR) effects play an important role. Due to FLR effects, the resonating ion velocity distribution function can have a strong influence on the power deposition. Evidence for this effect has been obtained from the third harmonic deuterium heating experiments. Because of FLR effects, the wave-particle interaction can also become weak at certain ion energies, which prevents resonating ions from reaching higher energies. When interacting with the wave, an ion receives not only a change in energy but also a change in

  16. Electron cyclotron resonance near the axis of the gas-dynamic trap

    Science.gov (United States)

    Bagulov, D. S.; Kotelnikov, I. A.

    2012-08-01

    Propagation of an extraordinary electromagnetic wave in the vicinity of electron cyclotron resonance surface in an open linear trap is studied analytically, taking into account inhomogeneity of the magnetic field in paraxial approximation. Ray trajectories are derived from a reduced dispersion equation that makes it possible to avoid the difficulty associated with a transition from large propagation angles to the case of strictly longitudinal propagation. Our approach is based on the theory, originally developed by Zvonkov and Timofeev [Sov. J. Plasma Phys. 14, 743 (1988)], who used the paraxial approximation for the magnetic field strength, but did not consider the slope of the magnetic field lines, which led to considerable error, as has been recently noted by Gospodchikov and Smolyakova [Plasma Phys. Rep. 37, 768-774 (2011)]. We have found ray trajectories in analytic form and demonstrated that the inhomogeneity of both the magnetic field strength and the field direction can qualitatively change the picture of wave propagation and significantly affect the efficiency of electron cyclotron heating of a plasma in a linear magnetic trap. Analysis of the ray trajectories has revealed a criterion for the resonance point on the axis of the trap to be an attractor for the ray trajectories. It is also shown that a family of ray trajectories can still reach the resonance point on the axis if the latter generally repels the ray trajectories. As an example, results of general theory are applied to the electron cyclotron resonance heating experiment which is under preparation on the gas dynamic trap in the Budker Institute of Nuclear Physics [Shalashov et al., Phys. Plasmas 19, 052503 (2012)].

  17. Accessibility condition of wave propagation and multicharged ion production in electron cyclotron resonance ion source plasma.

    Science.gov (United States)

    Kato, Yushi; Yano, Keisuke; Nishiokada, Takuya; Nagaya, Tomoki; Kimura, Daiju; Kumakura, Sho; Imai, Youta; Hagino, Shogo; Otsuka, Takuro; Sato, Fuminobu

    2016-02-01

    A new tandem type source of electron cyclotron resonance (ECR) plasmas has been constructing for producing synthesized ion beams in Osaka University. Magnetic mirror field configuration with octupole magnets can be controlled to various shape of ECR zones, namely, in the 2nd stage plasma to be available by a pair mirror and a supplemental coil. Noteworthy correlations between these magnetic configurations and production of multicharged ions are investigated in detail, as well as their optimum conditions. We have been considering accessibility condition of electromagnetic and electrostatic waves propagating in ECR ion source plasma, and then investigated their correspondence relationships with production of multicharged ions. It has been clarified that there exits efficient configuration of ECR zones for producing multicharged ion beams experimentally, and then has been suggested from detail accessibility conditions on the ECR plasma that new resonance, i.e., upper hybrid resonance, must have occurred.

  18. Electron acceleration at Jupiter: input from cyclotron-resonant interaction with whistler-mode chorus waves

    Directory of Open Access Journals (Sweden)

    E. E. Woodfield

    2013-10-01

    Full Text Available Jupiter has the most intense radiation belts of all the outer planets. It is not yet known how electrons can be accelerated to energies of 10 MeV or more. It has been suggested that cyclotron-resonant wave-particle interactions by chorus waves could accelerate electrons to a few MeV near the orbit of Io. Here we use the chorus wave intensities observed by the Galileo spacecraft to calculate the changes in electron flux as a result of pitch angle and energy diffusion. We show that, when the bandwidth of the waves and its variation with L are taken into account, pitch angle and energy diffusion due to chorus waves is a factor of 8 larger at L-shells greater than 10 than previously shown. We have used the latitudinal wave intensity profile from Galileo data to model the time evolution of the electron flux using the British Antarctic Survey Radiation Belt (BAS model. This profile confines intense chorus waves near the magnetic equator with a peak intensity at ∼5° latitude. Electron fluxes in the BAS model increase by an order of magnitude for energies around 3 MeV. Extending our results to L = 14 shows that cyclotron-resonant interactions with chorus waves are equally important for electron acceleration beyond L = 10. These results suggest that there is significant electron acceleration by cyclotron-resonant interactions at Jupiter contributing to the creation of Jupiter's radiation belts and also increasing the range of L-shells over which this mechanism should be considered.

  19. Status of the Bio-Nano electron cyclotron resonance ion source at Toyo University

    Energy Technology Data Exchange (ETDEWEB)

    Uchida, T., E-mail: uchida-t@toyo.jp [Bio-Nano Electronics Research Centre, Toyo University, Kawagoe 350-8585 (Japan); Minezaki, H.; Ishihara, S. [Graduate School of Engineering, Toyo University, Kawagoe 350-8585 (Japan); Muramatsu, M.; Kitagawa, A.; Drentje, A. G. [National Institute of Radiological Sciences (NIRS), Chiba 263-8555 (Japan); Rácz, R.; Biri, S. [Institute for Nuclear Research (ATOMKI), H-4026 Debrecen (Hungary); Asaji, T. [Oshima National College of Maritime Technology, Yamaguchi 742-2193 (Japan); Kato, Y. [Graduate School of Engineering, Osaka University, Suita 565-0871 (Japan); Yoshida, Y. [Bio-Nano Electronics Research Centre, Toyo University, Kawagoe 350-8585 (Japan); Graduate School of Engineering, Toyo University, Kawagoe 350-8585 (Japan)

    2014-02-15

    In the paper, the material science experiments, carried out recently using the Bio-Nano electron cyclotron resonance ion source (ECRIS) at Toyo University, are reported. We have investigated several methods to synthesize endohedral C{sub 60} using ion-ion and ion-molecule collision reaction in the ECRIS. Because of the simplicity of the configuration, we can install a large choice of additional equipment in the ECRIS. The Bio-Nano ECRIS is suitable not only to test the materials production but also to test technical developments to improve or understand the performance of an ECRIS.

  20. Fullerene-rare gas mixed plasmas in an electron cyclotron resonance ion source

    Energy Technology Data Exchange (ETDEWEB)

    Asaji, T., E-mail: asaji@oshima-k.ac.jp; Ohba, T. [Oshima National College of Maritime Technology, 1091-1 Komatsu, Suo-oshima, Oshima, Yamaguchi 742-2193 (Japan); Uchida, T.; Yoshida, Y. [Bio-Nano Electronics Research Centre, Toyo University, 2100 Kujirai, Kawagoe, Saitama 350-8585 (Japan); Minezaki, H.; Ishihara, S. [Graduate School of Engineering, Toyo University, 2100 Kujirai, Kawagoe, Saitama 350-8585 (Japan); Racz, R.; Biri, S. [Institute of Nuclear Research (ATOMKI), H-4026 Debrecen, Bem Tér 18/c (Hungary); Muramatsu, M.; Kitagawa, A. [National Institute of Radiological Sciences (NIRS), 4-9-1 Anagawa, Inage-ku, Chiba 263-8555 (Japan); Kato, Y. [Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871 (Japan)

    2014-02-15

    A synthesis technology of endohedral fullerenes such as Fe@C{sub 60} has developed with an electron cyclotron resonance (ECR) ion source. The production of N@C{sub 60} was reported. However, the yield was quite low, since most fullerene molecules were broken in the ECR plasma. We have adopted gas-mixing techniques in order to cool the plasma and then reduce fullerene dissociation. Mass spectra of ion beams extracted from fullerene-He, Ar or Xe mixed plasmas were observed with a Faraday cup. From the results, the He gas mixing technique is effective against fullerene destruction.

  1. Nonlocal weakly relativistic permittivity tensor of magnetized plasma near electron cyclotron resonances

    Science.gov (United States)

    Sakharov, A. S.

    2017-11-01

    Compact expressions are derived for the nonlocal permittivity tensor of weakly relativistic plasma in a 2D nonuniform magnetic field near the resonances at the second harmonic of the electron cyclotron frequency for an extraordinary wave and at the first harmonic for an ordinary wave. It is shown that the wave equation with allowance for the obtained thermal correction to the permittivity tensor in the form of a differential operator in transverse (with respect to the external magnetic field) coordinates possesses an integral in the form of the energy conservation law.

  2. The Spontaneous Loss of Coherence Catastrophe in Fourier Transform Ion Cyclotron Resonance Mass Spectrometry

    Science.gov (United States)

    Aizikov, Konstantin; Mathur, Raman; O’Connor, Peter B.

    2009-01-01

    The spontaneous loss of coherence catastrophe (SLCC) is a frequently observed, yet poorly studied, space-charge related effect in Fourier-transform ion cyclotron resonance mass spectrometry (FTICR-MS). This manuscript presents an application of the filter diagonalization method (FDM) in the analysis of this phenomenon. The temporal frequency behavior reproduced by frequency shift analysis using the FDM shows the complex nature of the SLCC, which can be explained by a combination of factors occurring concurrently, governed by electrostatics and ion packet trajectories inside the ICR cell. PMID:19013078

  3. Multiply charged ion dissociation in Fourier transform ion cyclotron resonance mass spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Qinyuan; Bakhtair, R.; Sherman, M.G.; Hofstadler, S.A.; Smith, R.D. [Pacific Northwest Laboratory, Richland, WA (United States)

    1994-12-31

    Bimolecular ions of up to MDa size with thousands of charges have recently been trapped and studied in this laboratory using electrospray ionization (ESI) and Fourier transform ion cyclotron resonance mass spectrometer (FTICRMS). For structural analysis, multiply charged ions generated by ESI can be dissociated at the interface, by collision induced dissociation (CID) or Surface induced dissociation (SID). However, charge exchange with the surface and charge partition among the fragments significantly complicate the SID and CID spectra of multiply charged large ions. High resolution FTICR is an ideal solution to this problem.

  4. Calculating method for confinement time and charge distribution of ions in electron cyclotron resonance sources

    Energy Technology Data Exchange (ETDEWEB)

    Dougar-Jabon, V.D. [Escuela de Fisica, Universidad Industrial de Santander, A.A. 678, Bucaramanga (Colombia); Umnov, A.M. [Russian Friendship University, 117198 Moscow (Russia); Kutner, V.B. [Joint Institute for Nuclear Research, Dubna (Russia)

    1996-03-01

    It is common knowledge that the electrostatic pit in a core plasma of electron cyclotron resonance sources exerts strict control over generation of ions in high charge states. This work is aimed at finding a dependence of the lifetime of ions on their charge states in the core region and to elaborate a numerical model of ion charge dispersion not only for the core plasmas but for extracted beams as well. The calculated data are in good agreement with the experimental results on charge distributions and magnitudes for currents of beams extracted from the 14 GHz DECRIS source. {copyright} {ital 1996 American Institute of Physics.}

  5. Photovoltaic infrared photoresponse of the high-mobility graphene quantum Hall system due to cyclotron resonance

    Science.gov (United States)

    Masubuchi, Satoru; Onuki, Masahiro; Arai, Miho; Yamaguchi, Takehiro; Watanabe, Kenji; Taniguchi, Takashi; Machida, Tomoki

    2013-09-01

    We report on the infrared photoresponse of high-mobility graphene in high magnetic fields. Two types of photoresponse signals were observed that were due to photovoltaic and bolometric effects. The photovoltaic signal was observed in the quantum Hall regime, whereas the bolometric signal was dominant in the quantum Hall transition regime. The photovoltaic effect, which was induced by cyclotron resonance, was observable up to 180 K. The polarity of the photovoltaic photoresponse was shown to be systematically reversed on reversal of the applied magnetic field direction and measurement geometry, suggesting that the photovoltage signals were generated along the quantum Hall edge channel.

  6. Development of DRAGON electron cyclotron resonance ion source at Institute of Modern Physics.

    Science.gov (United States)

    Lu, W; Xie, D Z; Zhang, X Z; Xiong, B; Ruan, L; Sha, S; Zhang, W H; Cao, Y; Lin, S H; Guo, J W; Fang, X; Guo, X H; Li, X X; Ma, H Y; Yang, Y; Wu, Q; Zhao, H Y; Ma, B H; Wang, H; Zhu, Y H; Feng, Y C; Li, J Y; Li, J Q; Sun, L T; Zhao, H W

    2012-02-01

    A new room temperature electron cyclotron resonance (ECR) ion source, DRAGON, is under construction at IMP. DRAGON is designed to operate at microwaves of frequencies of 14.5-18 GHz. Its axial solenoid coils are cooled with evaporative medium to provide an axial magnetic mirror field of 2.5 T at the injection and 1.4 T at the extraction, respectively. In comparison to other conventional room temperature ECR ion sources, DRAGON has so far the largest bore plasma chamber of inner diameter of 126 mm with maximum radial fields of 1.4-1.5 T produced by a non-Halbach permanent sextupole magnet.

  7. Effect of pulse-modulated microwaves on fullerene ion production with electron cyclotron resonance ion source.

    Science.gov (United States)

    Asaji, T; Uchida, T; Minezaki, H; Oshima, K; Racz, R; Muramatsu, M; Biri, S; Kitagawa, A; Kato, Y; Yoshida, Y

    2012-02-01

    Fullerene plasmas generated by pulse-modulated microwaves have been investigated under typical conditions at the Bio-Nano electron cyclotron resonance ion source. The effect of the pulse modulation is distinct from that of simply structured gases, and then the density of the fullerene plasmas increased as decreasing the duty ratio. The density for a pulse width of 10 μs at the period of 100 μs is 1.34 times higher than that for CW mode. We have studied the responses of fullerene and argon plasmas to pulsed microwaves. After the turnoff of microwave power, fullerene plasmas lasted ∼30 times longer than argon plasmas.

  8. Phase-resolved optical emission spectroscopy for an electron cyclotron resonance etcher

    Energy Technology Data Exchange (ETDEWEB)

    Milosavljevic, Vladimir [BioPlasma Research Group, Dublin Institute of Technology, Sackville Place, Dublin 1 (Ireland); Biosystems Engineering, University College Dublin, Dublin 4, Ireland and Faculty of Physics, University of Belgrade, Belgrade (Serbia); MacGearailt, Niall; Daniels, Stephen; Turner, Miles M. [NCPST, Dublin City University, Dublin (Ireland); Cullen, P. J. [BioPlasma Research Group, Dublin Institute of Technology, Sackville Place, Dublin 1 (Ireland)

    2013-04-28

    Phase-resolved optical emission spectroscopy (PROES) is used for the measurement of plasma products in a typical industrial electron cyclotron resonance (ECR) plasma etcher. In this paper, the PROES of oxygen and argon atoms spectral lines are investigated over a wide range of process parameters. The PROES shows a discrimination between the plasma species from gas phase and those which come from the solid phase due to surface etching. The relationship between the micro-wave and radio-frequency generators for plasma creation in the ECR can be better understood by the use of PROES.

  9. The third generation superconducting 28 GHz electron cyclotron resonance ion source VENUS (invited)

    Energy Technology Data Exchange (ETDEWEB)

    Lyneis, C.; Leitner, D.; Leitner, M.; Taylor, C.; Abbott, S. [Lawrence Berkeley National Laboratory, One Cyclotron Road, Berkeley, California 94720 (United States)

    2010-02-15

    VENUS is a third generation electron cyclotron resonance (ECR) ion source, which incorporates a high field superconducting NbTi magnet structure, a 28 GHz gryotron microwave source and a state of the art closed cycle cryosystem. During the decade from initial concept to regular operation, it has demonstrated both the feasibility and the performance levels of this new generation of ECR ion sources and required innovation on magnet construction, plasma chamber design, and beam transport. In this paper, the development, performance, and major innovations are described as well as a look to the potential to construct a fourth generation ECR ion source.

  10. Collision cross section measurements for biomolecules within a high-resolution Fourier transform ion cyclotron resonance cell.

    Science.gov (United States)

    Mao, Lu; Chen, Yu; Xin, Yi; Chen, Yu; Zheng, Li; Kaiser, Nathan K; Marshall, Alan G; Xu, Wei

    2015-04-21

    To understand the role and function of a biomolecule in a biosystem, it is important to know both its composition and structure. Here, a mass spectrometric based approach has been proposed and applied to demonstrate that collision cross sections and high-resolution mass spectra of biomolecule ions may be obtained simultaneously by Fourier transform ion cyclotron resonance mass spectrometry. With this method, the unfolding phenomena for ubiquitin ions that possess different number of charges have been investigated, and results agree well with ion mobility measurements. In the present approach, we extend ion collision cross-section measurements to lower pressures than in prior ion cyclotron resonance (ICR)-based experiments, thereby maintaining the potentially high resolution of Fourier transform ion cyclotron resonance mass spectrometry (FTICR MS), and enabling collision cross section (CCS) measurements for high-mass biomolecules.

  11. Development of a miniature microwave electron cyclotron resonance plasma ion thruster for exospheric micro-propulsion.

    Science.gov (United States)

    Dey, Indranuj; Toyoda, Yuji; Yamamoto, Naoji; Nakashima, Hideki

    2015-12-01

    A miniature microwave electron cyclotron resonance plasma source [(discharge diameter)/(microwave cutoff diameter) micro-propulsion applications in the exosphere. The discharge source uses both radial and axial magnetostatic field confinement to facilitate electron cyclotron resonance and increase the electron dwell time in the volume, thereby enhancing plasma production efficiency. Performance of the ion thruster is studied at 3 microwave frequencies (1.2 GHz, 1.6 GHz, and 2.45 GHz), for low input powers (<15 W) and small xenon mass flow rates (<40 μg/s), by experimentally measuring the extracted ion beam current through a potential difference of ≅1200 V. The discharge geometry is found to operate most efficiently at an input microwave frequency of 1.6 GHz. At this frequency, for an input power of 8 W, and propellant (xenon) mass flow rate of 21 μg/s, 13.7 mA of ion beam current is obtained, equivalent to an calculated thrust of 0.74 mN.

  12. Precision mass measurements using the Phase-Imaging Ion-Cyclotron-Resonance detection technique

    CERN Document Server

    Karthein, Jonas

    This thesis presents the implementation and improvement of the Phase-Imaging Ion-Cyclotron-Resonance (PI-ICR) detection technique at the ISOLTRAP experiment, located at the ISOLDE / CERN, with the purpose of on-line high-precision and high-resolution mass spectrometry. Extensive simulation studies were performed with the aim of improving the phase-imaging resolution and finding the optimal position for detector placement. Following the outcome of these simulations, the detector was moved out of a region of electric-field distortion and closer to the center of the Penning trap, showing a dramatic improvement in the quality and reproducibility of the phase-imaging measurements. A new image reconstitution and analysis software for the MCP-PS detector was written in Python and ROOT and introduced in the framework of PI-ICR mass measurements. The state of the art in the field of time-of-flight ion-cyclotron-resonance measurements is illustrated through an analysis of on-line measurements of the mirror nuclei $...

  13. Enhanced Physicochemical and Biological Properties of Ion-Implanted Titanium Using Electron Cyclotron Resonance Ion Sources

    Directory of Open Access Journals (Sweden)

    Csaba Hegedűs

    2016-01-01

    Full Text Available The surface properties of metallic implants play an important role in their clinical success. Improving upon the inherent shortcomings of Ti implants, such as poor bioactivity, is imperative for achieving clinical use. In this study, we have developed a Ti implant modified with Ca or dual Ca + Si ions on the surface using an electron cyclotron resonance ion source (ECRIS. The physicochemical and biological properties of ion-implanted Ti surfaces were analyzed using various analytical techniques, such as surface analyses, potentiodynamic polarization and cell culture. Experimental results indicated that a rough morphology was observed on the Ti substrate surface modified by ECRIS plasma ions. The in vitro electrochemical measurement results also indicated that the Ca + Si ion-implanted surface had a more beneficial and desired behavior than the pristine Ti substrate. Compared to the pristine Ti substrate, all ion-implanted samples had a lower hemolysis ratio. MG63 cells cultured on the high Ca and dual Ca + Si ion-implanted surfaces revealed significantly greater cell viability in comparison to the pristine Ti substrate. In conclusion, surface modification by electron cyclotron resonance Ca and Si ion sources could be an effective method for Ti implants.

  14. Study of ion beam transport from the SECRAL electron cyclotron resonance ion source at the Institute of Modern Physics.

    Science.gov (United States)

    Cao, Y; Lu, W; Zhang, W H; Sha, S; Yang, Y; Ma, B H; Wang, H; Zhu, Y H; Guo, J W; Fang, X; Lin, S H; Li, X X; Feng, Y C; Li, J Y; Zhao, H Y; Ma, H Y; Zhang, X Z; Guo, X H; Wu, Q; Sun, L T; Zhao, H W; Xie, D Z

    2012-02-01

    Ion beam transport from the Superconducting Electron Cyclotron Resonance ion source with Advanced design in Lanzhou (SECRAL) electron cyclotron resonance ion source was studied at the Institute of Modern Physics during 2010. Particle-in-cell simulations and experimental results have shown that both space charge and magnetic aberrations lead to a larger beam envelope and emittance growth. In the existing SECRAL extraction beam line, it has been shown that raising the solenoid lens magnetic field reduces aberrations in the subsequent dipole and results in lower emittance. Detailed beam emittance measurements are presented in this paper.

  15. Electron cyclotron resonance plasma reactor for production of carbon stripper foil

    Science.gov (United States)

    Faith Romero, Camille; Kanamori, Keita; Kinsho, Michikazu; Yoshimoto, Masahiro; Wada, Motoi

    2018-01-01

    A graphite antenna for the production of carbon-containing hydrogen plasmas is being developed to prepare impurity-free charge exchange foils for high-energy synchrotrons. Microwave power at 2.45 GHz frequency drives a coaxial structure antenna with a 12-mm-diameter central graphite cylinder and a tapered surrounding cylinder serving as the ground electrode. The antenna was placed in a linear magnetic field to investigate how it performs under an electron cyclotron resonance (ECR) condition. A clear resonance phenomenon was observed in plasma luminosity, microwave power absorption, and microwave power reflection when the induction current used to produce a linear magnetic field was changed. The antenna realized the best microwave coupling to the plasma with the ECR zone formed 5 mm from the end of the center electrode. The antenna realized stable operation for more than 5 h with 100 W input microwave power and with operating hydrogen pressure from 0.5 to 50 Pa.

  16. Weak-field H3O+ ion cyclotron resonance alters water refractive index.

    Science.gov (United States)

    D'Emilia, E; Ledda, M; Foletti, A; Lisi, A; Giuliani, L; Grimaldi, S; Liboff, A R

    2017-01-01

    Heretofore only observed in living systems, we report that weak-field ion cyclotron resonance (ICR) also occurs in inanimate matter. Weak magnetic field (50 nT) hydronium ICR at the field combination (7.84 Hz, 7.5 µT) markedly changes water structure, as evidenced by finding an altered index of refraction exactly at this combined field. This observation utilizes a novel technique which measures the scattering of a He-Ne laser beam as the sample is exposed to a ramped magnetic field frequency. In addition to the hydronium resonance, we find evidence of ICR coupling to a more massive structure, possibly a tetrahedral combination of three waters and a single hydronium ion. To check our observations, we extended this technique to D2O, successfully predicting the specific ICR charge-to-mass ratio for D3O+ that alters the index of refraction.

  17. Cyclotron resonant scattering feature simulations. II. Description of the CRSF simulation process

    Science.gov (United States)

    Schwarm, F.-W.; Ballhausen, R.; Falkner, S.; Schönherr, G.; Pottschmidt, K.; Wolff, M. T.; Becker, P. A.; Fürst, F.; Marcu-Cheatham, D. M.; Hemphill, P. B.; Sokolova-Lapa, E.; Dauser, T.; Klochkov, D.; Ferrigno, C.; Wilms, J.

    2017-05-01

    Context. Cyclotron resonant scattering features (CRSFs) are formed by scattering of X-ray photons off quantized plasma electrons in the strong magnetic field (of the order 1012 G) close to the surface of an accreting X-ray pulsar. Due to the complex scattering cross-sections, the line profiles of CRSFs cannot be described by an analytic expression. Numerical methods, such as Monte Carlo (MC) simulations of the scattering processes, are required in order to predict precise line shapes for a given physical setup, which can be compared to observations to gain information about the underlying physics in these systems. Aims: A versatile simulation code is needed for the generation of synthetic cyclotron lines. Sophisticated geometries should be investigatable by making their simulation possible for the first time. Methods: The simulation utilizes the mean free path tables described in the first paper of this series for the fast interpolation of propagation lengths. The code is parallelized to make the very time-consuming simulations possible on convenient time scales. Furthermore, it can generate responses to monoenergetic photon injections, producing Green's functions, which can be used later to generate spectra for arbitrary continua. Results: We develop a new simulation code to generate synthetic cyclotron lines for complex scenarios, allowing for unprecedented physical interpretation of the observed data. An associated XSPEC model implementation is used to fit synthetic line profiles to NuSTAR data of Cep X-4. The code has been developed with the main goal of overcoming previous geometrical constraints in MC simulations of CRSFs. By applying this code also to more simple, classic geometries used in previous works, we furthermore address issues of code verification and cross-comparison of various models. The XSPEC model and the Green's function tables are available online (see link in footnote, page 1).

  18. Production of hydrogen and deuterium negative ions in an electron cyclotron resonance driven plasma

    Energy Technology Data Exchange (ETDEWEB)

    Dougar-Jabon, V.D. [Industrial Univ. of Santander, Bucaramanga (Colombia)

    2001-04-01

    An electron cyclotron resonance source with driven plasma rings for hydrogen isotope ion production is studied. Extracted currents of positive and negative ions depending on gas pressure, microwave power value and extraction voltage are obtained. The study shows that the negative ion yield is an order of magnitude higher than the yield of positive particles when a driven ring is in contact with the surface of the plasma electrode. The production of negative ions of deuterium, D{sup -}, is close to the production of negative ions of light hydrogen isotope, H{sup -}. The comparison of the experimental data with the calculated ones shows that the most probable process of the H{sup -} and D{sup -} ion formation in the electron cyclotron driven plasma is dissociative attachment of electrons to molecules in high Rydberg states. For hydrogen ions and ions of deuterium, the negative current at a microwave power of 200 W through a 3-mm aperture and 8 kV extraction voltage are 4.7 mA and 3.1 mA respectively. (orig.)

  19. Magnetic field and dimensionality-induced population effects in HgSe : Fe quantum wells: the cyclotron resonance

    Science.gov (United States)

    Portugall, O.; Barczewski, M.; von Ortenberg, M.; Schikora, D.; Widmer, T.; Lischka, H.

    1998-02-01

    Line shapes of the high-field cyclotron resonance are investigated both experimentally and theoretically for thin layers of the Fermi-level pinned system HgSe : Fe. Characteristic features are related to a subband population representing the two- and three-dimensional limits as well as intermediate steps.

  20. Three-dimensional simulations of ion dynamics in the plasma of an electron cyclotron resonance ion source

    NARCIS (Netherlands)

    Mironov, V.; Beijers, J.P.M.

    The ion production in an electron cyclotron resonance ion source (ECRIS) is modeled using a particle-in-cell Monte-Carlo-collision code in a three-dimensional geometry. Only the heavy particles (ions and atoms) are tracked, while the electrons are represented using a Maxwell-Boltzmann energy

  1. Fourier transform ion cyclotron resonance versus time of flight for precision mass measurements

    Energy Technology Data Exchange (ETDEWEB)

    Kouzes, R.T.

    1993-02-01

    Both Fourier Transform Ion Cyclotron Resonance and ICR Time-of-Flight mass spectroscopy (FTICR-MS and ICR-TOF-MS, respectively) have been applied to precision atomic mass measurements. This paper reviews the status of these approaches and compares their limitations. Comparisons are made of FTICR-MS and ICR-TOF-MS for application to precision atomic mass measurements of stable and unstable nuclei, where the relevant scale is an accuracy of 1 keV and where halflives are longer than 10 milliseconds (optimistically). The atomic mass table is built up from mass chains, and ICR-MS brings a method of producing new types of mass chains to the mass measurement arena.

  2. First results of the 2.45 GHz Oshima electron cyclotron resonance ion source

    Energy Technology Data Exchange (ETDEWEB)

    Asaji, T., E-mail: asaji@nc-toyama.ac.jp [National Institute of Technology, Toyama College, 13 Hongo, Toyama 939-8630 (Japan); Nakamura, T.; Furuse, M. [National Institute of Technology, Oshima College, 1091-1 Komatsu, Suouoshima, Oshima, Yamaguchi 742-2193 (Japan); Hitobo, T. [Tateyama Machine Co., Ltd., 30 Shimonoban, Toyama 930-1305 (Japan); Uchida, T. [Graduate School of Engineering, Toyo University, 2100 Kujirai, Kawagoe, Saitama 350-8585 (Japan); Muramatsu, M. [National Institute of Radiological Sciences (NIRS), 4-9-1 Anagawa, Inage-ku, Chiba 263-8555 (Japan); Kato, Y. [Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871 (Japan)

    2016-02-15

    A new electron cyclotron resonance ion source has been constructed at Oshima College with a 2.45 GHz magnetron microwave source and permanent magnets employed as the main components. In addition, a solid-state power amplifier with a frequency range of 2.5–6.0 GHz was installed to study two-frequency plasma heating. Three solenoid coils were set up for adjusting the axial magnetic fields. Argon plasma generation and ion beam production have been conducted during the first year of operation. Ion current densities in the ECR plasma were measured using a biased disk. For 2.45 and 4.65 GHz two-frequency plasma heating, the ion density was approximately 1.5 times higher than that of 2.45 GHz single-frequency heating.

  3. Status of charge breeding with electron cyclotron resonance ion sources (invited)

    CERN Document Server

    Lamy, T; Sortais, P; Thuillier, T; 10.1063/1.2149300

    2006-01-01

    Due to the production methods of exotic nuclei, an efficient acceleration of radioactive ion beams needs charge breeding of weakly charged ions. The upgrade of existing isotope separator on-line facilities (TRIUMF-isotope separation and acceleration, CERN-isotope separation on-line detector, etc.) or the development of projects for the acceleration of radioactive ion beams (GANIL-SPIRAL2, MAFF, EURISOL, etc.) requires charge breeders with high efficiency, fast charge breeding time, low background levels, and high intensity acceptance either in continuous or in pulsed mode. The optimization of these parameters is a challenge for the electron cyclotron resonance (ECR) community and is useful to get a better understanding of plasma physics in ECR ion sources (ECRISs). The ECR charge breeding technique has been developed for more than ten years at LPSC (former ISN) Grenoble, typical 1+rightward arrown+ efficiencies are in the 3%-10% range depending on the nature of the incoming beam (metallic, alkaline, and gaseo...

  4. On-line capillary electrophoresis with Fourier transform ion cyclotron resonance mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Hofstadler, S.A.; Wahl, J.H.; Bruce, J.E.; Smith, R.D. (Pacific Northwest Lab., Richland, WA (United States))

    1993-07-28

    The role of capillary electrophoresis (CE) in chemical and biochemical characterization is growing rapidly due to its speed, resolution, and flexibility for the manipulation of extremely small samples. CE was first combined with mass spectrometry (MS) at our laboratory. In this communication we report results for the first on-line combination of CE with Fourier transform ion cyclotron resonance (FTICR) mass spectrometry, an approach that is capable of providing both high CE and MS resolution and high sensitivity. The advantages of FTICR include the ability to simultaneously realize ultrahigh MS resolution/mass measurement accuracy and high sensitivity, as well as the capability for higher order tandem MS methods (i.e., MS[sup n], where n [ge] 2) for structural studies because of its nondestructive detection method. 20 refs., 3 figs.

  5. Poloidal rotation driven by electron cyclotron resonance wave in tokamak plasmas

    Directory of Open Access Journals (Sweden)

    Qing Zhou

    2017-10-01

    Full Text Available The poloidal electric filed, which is the drive field of poloidal rotation, has been observed and increases obviously after the injection of electron cyclotron resonance wave in HL-2A experiment, and the amplitude of the poloidal electric field is in the order of 103 V/m. Through theoretical analysis using Stringer rotation model, the observed poloidal electric field is of the same order as the theoretical calculation value. In addition, the magnetic pump damping which would damp the poloidal rotation is calculated numerically and the calculation results show that the closer to the core plasmas, the stronger the magnetic pump damping will be. Meanwhile, according to the value of the calculated magnetic pump damping, the threshold of the poloidal electric field which could overcome magnetic pump damping and drive poloidal rotation in tokamak plasmas is given out. Finally, the poloidal rotation velocity over time at different minor radius is studied theoretically.

  6. Ultrathin oxide grown on polysilicon by using an electron cyclotron resonance N sub 2 O plasma

    CERN Document Server

    Han, S Y

    2000-01-01

    We have developed a process for growing ultrathin oxide on a polysilicon layer by using an electron cyclotron resonance (ECR) N sub 2 O plasma. Sub-4-nm thick polyoxides were grown on n sup + and p sup + polysilicon layers and were characterized. These oxides had larger breakdown fields, smaller electron trapping characteristics, and larger Q sub B sub D values than those of thermal polyoxides. The electron trapping characteristics of ECR N sub 2 O plasma polyoxides, which were smaller than those of thermal polyoxides at positive bias, resulted from the smaller roughness of the polysilicon surface after the oxidation process. Under a negative constant-current stress of 20 mA/cm sup 2 for polyoxide on p sup + polysilicon were obtained. These ultrathin plasma polyoxides would be good candidates for future inter-poly dielectrics and gate oxides for thin film transistors.

  7. Status report on electron cyclotron resonance ion sources at the Heavy Ion Medical Accelerator in Chiba

    CERN Document Server

    Kitagawa, A; Sekiguchi, M; Yamada, S; Jincho, K; Okada, T; Yamamoto, M; Hattori, T G; Biri, S; Baskaran, R; Sakata, T; Sawada, K; Uno, K

    2000-01-01

    The Heavy Ion Medical Accelerator in Chiba at the National Institute of Radiological Sciences (NIRS) is not only dedicated to cancer therapy, it is also utilized with various ion species for basic experiments of biomedical science, physics, chemistry, etc. Two electron cyclotron resonance (ECR) ion sources are installed for production of gaseous ions. One of them, the NIRS-ECR, is a 10 GHz ECR ion source, and is mainly operated to produce C/sup 4+/ ions for daily clinical treatment. This source realizes good reproducibility and reliability and it is easily operated. The other source, the NIRS-HEC, is an 18 GHz ECR ion source that is expected to produce heavier ion species. The output ion currents of the NIRS-ECR and the NIRS-HEC are 430e mu A for C/sup 4+/ and 1.1e mA for Ar/sup 8+/, respectively. (14 refs).

  8. On ion-cyclotron-resonance heating of the corona and solar wind

    Directory of Open Access Journals (Sweden)

    E. Marsch

    2003-01-01

    Full Text Available This paper concisely summarizes and critically reviews recent work by the authors on models of the heating of the solar corona by resonance of ions with high-frequency waves (up to the proton cyclotron frequency. The quasi-linear theory of pitch angle diffusion is presented in connection with relevant solar wind proton observations. Hybrid fluid-kinetic model equations, which include wave-particle interactions and collisions, are derived. Numerical solutions are discussed, representative of the inner corona and near-Sun solar wind. A semi-kinetic model for reduced velocity distributions is presented, yielding kinetic results for heavy ions in the solar corona. It is concluded that a self-consistent treatment of particle distributions and wave spectra is required, in order to adequately describe coronal physics and to obtain agreement with observations.

  9. Production and decay of chlorine ion excited species in an electron cyclotron resonance ion source plasma

    Energy Technology Data Exchange (ETDEWEB)

    Santos, J P; Martins, M C; Parente, F [Centro de Fisica Atomica, CFA, Departamento de Fisica, Faculdade de Ciencias e Tecnologia, FCT, Universidade Nova de Lisboa, 2829-516 Caparica (Portugal); Costa, A M; Marques, J P [Centro de Fisica Atomica, CFA, Departamento de Fisica, Faculdade de Ciencias, FCUL, Universidade de Lisboa, Campo Grande, 1749-016 Lisboa (Portugal); Indelicato, P, E-mail: jps@fct.unl.pt [Laboratoire Kastler Brossel, Ecole Normale Superieure, CNRS, Universite P et M Curie-Paris 6, Case 74, 4 place Jussieu, 75252 Paris Cedex 05 (France)

    2011-06-15

    The most important processes for the creation of chlorine ion excited states from the ground configurations of Cl{sup 10+} to Cl{sup 15+} ions in an electron cyclotron resonance ion source, leading to the emission of K x-ray lines, were studied. Theoretical values for inner-shell excitation and ionization cross-sections, including double KL and triple KLL ionization, transition probabilities and energies for the de-excitation processes, were calculated in the framework of the multi-configuration Dirac-Fock method. With reasonable assumptions about the electron energy distribution, a theoretical K{alpha} x-ray spectrum was obtained, which was then compared with recent experimental data.

  10. Development of Electron Cyclotron Resonance Ion Source for Synthesis of Endohedral Metallofullerenes

    Science.gov (United States)

    Tanaka, K.; Muramatsu, M.; Uchida, T.; Biri, S.; Asaji, T.; Shima, K.; Hanajiri, T.; Kitagawa, A.; Kato, Y.; Yoshida, Y.

    2008-11-01

    A new electron cyclotron resonance ion source (ECRIS) has been constructed for synthesis of endohedral metallofullerenes. The main purpose of the ion source is to produce new biological and medical materials. The design is based on ECRIS for production of multicharged ion beams with a traditional minimum-B magnetic field. An 8-10 GHz traveling wave tube (TWT) amplifier and a 2.45 GHz magnetron have been applied as microwave sources. Fullerene and metal vapor are introduced with a filament heating micro-oven and an induction heating oven, respectively. In preliminary ion-extraction test, Ar+ is 54 μA. Many broken fullerenes such as C58 and C56 are observed in fullerene ion beams.

  11. Time evolution of bremsstrahlung and ion production of an electron cyclotron resonance ion source

    Energy Technology Data Exchange (ETDEWEB)

    Tarvainen, Ollie [Los Alamos National Laboratory; Ropponen, Tommi [UNIV OF JYVASKYLA; Jones, Peter [UNIV OF JYVASKYLA; Peura, Pauli [UNIV OF JYVASKYLA

    2008-01-01

    Bremsstrahlung radiation measurement is one of the most commonly used plasma diagnostics methods. Most of the bremsstrahlung measurements with electron cyclotron resonance (ECR) ion sources have been performed in continuous operation mode yielding information only on the steady state bremsstrahlung emission. This article describes the results of bremsstrahlung and ion current measurement with the JYFL 14 GHz ECRIS operated in pulsed mode. The experiments reveal information about the bremsstrahlung radiation in plasma conditions before reaching the equilibrium. The time scale of bremsstrahlung production is compared to ion production time scale for different charge states. The bremsstrahlung data is presented with 2 millisecond time intervals as a function of neutral gas pressure and microwave power. Data from hundreds of microwave pulses is combined in order to have a sufficient amount of events at each time step. The relevant plasma physics phenomena during both, the leading and the trailing edge of the RF pulse, are discussed.

  12. Cyclotron-resonance-induced photovoltaic effect in high-mobility graphene in the quantum Hall regime

    Science.gov (United States)

    Masubuchi, Satoru; Onuki, Masahiro; Arai, Miho; Watanabe, Kenji; Taniguchi, Takashi; Machida, Tomoki

    2013-03-01

    We have investigated the infrared photoinduced voltage ΔV in high-mobility graphene on hexagonal boron nitride in the quantum Hall regime. We observed ΔV of up to several μV at ν = +/- 2 quantum Hall states under the cyclotron resonance conditions. The dependence of ΔV on the bias current indicates that ΔV signals derive from the photovoltaic effect rather than the bolometric effect. The dependence of ΔV on magnetic field direction and measurement geometry suggest the edge channel transport as an origin of photovoltaic effect. ΔV signals were robust up to T = 180 K, indicating that ΔV signals can be used for developing novel terahertz photodetectors operating at high temperatures.

  13. Electron cyclotron resonance ion source plasma characterization by energy dispersive x-ray imaging

    Science.gov (United States)

    Rácz, R.; Mascali, D.; Biri, S.; Caliri, C.; Castro, G.; Galatà, A.; Gammino, S.; Neri, L.; Pálinkás, J.; Romano, F. P.; Torrisi, G.

    2017-07-01

    Pinhole and CCD based quasi-optical x-ray imaging technique was applied to investigate the plasma of an electron cyclotron resonance ion source (ECRIS). Spectrally integrated and energy resolved images were taken from an axial perspective. The comparison of integrated images taken of argon plasma highlights the structural changes affected by some ECRIS setting parameters, like strength of the axial magnetic confinement, RF frequency and microwave power. Photon counting analysis gives precise intensity distribution of the x-ray emitted by the argon plasma and by the plasma chamber walls. This advanced technique points out that the spatial positions of the electron losses are strongly determined by the kinetic energy of the electrons themselves to be lost and also shows evidences how strongly the plasma distribution is affected by slight changes in the RF frequency.

  14. Prospects for advanced electron cyclotron resonance and electron beam ion source charge breeding methods for EURISOL.

    Science.gov (United States)

    Delahaye, P; Galata, A; Angot, J; Ban, G; Celona, L; Choinski, J; Gmaj, P; Jakubowski, A; Jardin, P; Kalvas, T; Koivisto, H; Kolhinen, V; Lamy, T; Lunney, D; Maunoury, L; Porcellato, A M; Prete, G F; Steckiewicz, O; Sortais, P; Thuillier, T; Tarvainen, O; Traykov, E; Varenne, F; Wenander, F

    2012-02-01

    As the most ambitious concept of isotope separation on line (ISOL) facility, EURISOL aims at producing unprecedented intensities of post-accelerated radioactive isotopes. Charge breeding, which transforms the charge state of radioactive beams from 1+ to an n+ charge state prior to post-acceleration, is a key technology which has to overcome the following challenges: high charge states for high energies, efficiency, rapidity and purity. On the roadmap to EURISOL, a dedicated R&D is being undertaken to push forward the frontiers of the present state-of-the-art techniques which use either electron cyclotron resonance or electron beam ion sources. We describe here the guidelines of this R&D.

  15. Trap density of GeNx/Ge interface fabricated by electron-cyclotron-resonance plasma nitridation

    Science.gov (United States)

    Fukuda, Yukio; Otani, Yohei; Toyota, Hiroshi; Ono, Toshiro

    2011-07-01

    We have investigated GeNx/Ge interface properties using Si3N4(7 nm)/GeNx(2 nm)/Ge metal-insulator-semiconductor structures fabricated by the plasma nitridation of Ge substrates using an electron-cyclotron-resonance-generated nitrogen plasma. The interface trap density (Dit) measured by the conductance method is found to be distributed symmetrically in the Ge band gap with a minimum Dit value lower than 3 × 1011 cm-2eV-1 near the midgap. This result may lead to the development of processes for the fabrication of p- and n-Ge Schottky-barrier (SB) source/drain metal-insulator-semiconductor field-effect transistors using chemically and thermally robust GeNx dielectrics as interlayers for SB source/drain contacts and high-κ gate dielectrics.

  16. Developing laser ablation in an electron cyclotron resonance ion source for actinide detection with AMS

    Energy Technology Data Exchange (ETDEWEB)

    Bauder, W. [Argonne National Laboratory, Physics Division, 9600 S. Cass Ave, Lemont, IL 60439 (United States); University of Notre Dame, Nuclear Science Laboratory, 124 Nieuwland Science Hall, Notre Dame, IN 46556 (United States); Pardo, R.C.; Kondev, F.G.; Kondrashev, S.; Nair, C.; Nusair, O. [Argonne National Laboratory, Physics Division, 9600 S. Cass Ave, Lemont, IL 60439 (United States); Palchan, T. [Hebrew University, Racah Institute of Physics, Jerusalem 91904 (Israel); Scott, R.; Seweryniak, D.; Vondrasek, R. [Argonne National Laboratory, Physics Division, 9600 S. Cass Ave, Lemont, IL 60439 (United States); Collon, P. [University of Notre Dame, Nuclear Science Laboratory, 124 Nieuwland Science Hall, Notre Dame, IN 46556 (United States); Paul, M. [Hebrew University, Racah Institute of Physics, Jerusalem 91904 (Israel)

    2015-10-15

    A laser ablation material injection system has been developed at the ATLAS electron cyclotron resonance (ECR) ion source for use in accelerator mass spectrometry experiments. Beam production with laser ablation initially suffered from instabilities due to fluctuations in laser energy and cratering on the sample surface by the laser. However, these instabilities were rectified by applying feedback correction for the laser energy and rastering the laser across the sample surface. An initial experiment successfully produced and accelerated low intensity actinide beams with up to 1000 counts per second. With continued development, laser ablation shows promise as an alternative material injection scheme for ECR ion sources and may help substantially reduce cross talk in the source.

  17. Intense highly charged ion beam production and operation with a superconducting electron cyclotron resonance ion source

    Directory of Open Access Journals (Sweden)

    H. W. Zhao

    2017-09-01

    Full Text Available The superconducting electron cyclotron resonance ion source with advanced design in Lanzhou (SECRAL is a superconducting-magnet-based electron cyclotron resonance ion source (ECRIS for the production of intense highly charged heavy ion beams. It is one of the best performing ECRISs worldwide and the first superconducting ECRIS built with an innovative magnet to generate a high strength minimum-B field for operation with heating microwaves up to 24–28 GHz. Since its commissioning in 2005, SECRAL has so far produced a good number of continuous wave intensity records of highly charged ion beams, in which recently the beam intensities of ^{40}Ar^{12+} and ^{129}Xe^{26+} have, for the first time, exceeded 1 emA produced by an ion source. Routine operations commenced in 2007 with the Heavy Ion accelerator Research Facility in Lanzhou (HIRFL, China. Up to June 2017, SECRAL has been providing more than 28,000 hours of highly charged heavy ion beams to the accelerator demonstrating its great capability and reliability. The great achievement of SECRAL is accumulation of numerous technical advancements, such as an innovative magnetic system and an efficient double-frequency (24+18  GHz heating with improved plasma stability. This article reviews the development of SECRAL and production of intense highly charged ion beams by SECRAL focusing on its unique magnet design, source commissioning, performance studies and enhancements, beam quality and long-term operation. SECRAL development and its performance studies representatively reflect the achievements and status of the present ECR ion source, as well as the ECRIS impacts on HIRFL.

  18. Intense highly charged ion beam production and operation with a superconducting electron cyclotron resonance ion source

    Science.gov (United States)

    Zhao, H. W.; Sun, L. T.; Guo, J. W.; Lu, W.; Xie, D. Z.; Hitz, D.; Zhang, X. Z.; Yang, Y.

    2017-09-01

    The superconducting electron cyclotron resonance ion source with advanced design in Lanzhou (SECRAL) is a superconducting-magnet-based electron cyclotron resonance ion source (ECRIS) for the production of intense highly charged heavy ion beams. It is one of the best performing ECRISs worldwide and the first superconducting ECRIS built with an innovative magnet to generate a high strength minimum-B field for operation with heating microwaves up to 24-28 GHz. Since its commissioning in 2005, SECRAL has so far produced a good number of continuous wave intensity records of highly charged ion beams, in which recently the beam intensities of 40Ar+ and 129Xe26+ have, for the first time, exceeded 1 emA produced by an ion source. Routine operations commenced in 2007 with the Heavy Ion accelerator Research Facility in Lanzhou (HIRFL), China. Up to June 2017, SECRAL has been providing more than 28,000 hours of highly charged heavy ion beams to the accelerator demonstrating its great capability and reliability. The great achievement of SECRAL is accumulation of numerous technical advancements, such as an innovative magnetic system and an efficient double-frequency (24 +18 GHz ) heating with improved plasma stability. This article reviews the development of SECRAL and production of intense highly charged ion beams by SECRAL focusing on its unique magnet design, source commissioning, performance studies and enhancements, beam quality and long-term operation. SECRAL development and its performance studies representatively reflect the achievements and status of the present ECR ion source, as well as the ECRIS impacts on HIRFL.

  19. The accuracy of heavy-ion mass measurements using time of flight-ion cyclotron resonance in a Penning trap

    Science.gov (United States)

    Bollen, G.; Moore, R. B.; Savard, G.; Stolzenberg, H.

    1990-11-01

    Ion motion in a Penning trap and the electrical signals it can produce have been analyzed for the purpose of identifying the important causes of uncertainty in high-accuracy mass measurements of heavy ions. The role of the azimuthal quadrupole electric field in signal pickup, and its effects on ion motion at the sum frequency of the cyclotron and magnetron motions, have been identified. A useful scheme for calculating the signal strength and strength of the interaction between an applied field and the ion motion has been developed. The important sources of uncertainty in using the sum frequency of the cyclotron and magnetron motions for determining the ion mass are discussed. Particular application is made to the case of cyclotron resonance detection by observation of the time of flight of ejected ions.

  20. Effects of initial layers on surface roughness and crystallinity of microcrystalline silicon thin films formed by remote electron cyclotron resonance silane plasma

    CERN Document Server

    Murata, K; Hori, Masaki; Goto, T; Ito, M

    2002-01-01

    We have observed mu c-Si:H films grown in the glass substrate in electron cyclotron resonance plasma-enhanced chemical vapor deposition employing two-step growth (TSG) method, where the seed layer was formed without charged species firstly, and subsequently, the film with charged species. The mu c-Si:H films with smooth surface and high crystallinity were synthesized with a relatively high deposition rate at a low substrate temperature by TSG. By Fourier transform infrared attenuated-total reflection, it was found that the surface roughness and crystallinity of seed layer were related to the ratio of SiH bonds over SiH sub 2 ones in the film. Consequently, the control of chemical bonds at the initial layer is of importance and TSG method is effective for the formation of mu c-Si:H film with high quality.

  1. Cyclotron resonance on galliumnitride in fields up to 700 T generated by explosive driven flux compression

    Science.gov (United States)

    Puhlmann, N.; Tatsenko, O. M.; Stolpe, I.; Markevtsev, I. M.; von Ortenberg, M.; Platonov, V. V.; Selemir, V. D.; Bykov, A. I.; Moiseenko, A. N.; Schikora, D.

    2001-01-01

    We report on the first successful cyclotron resonance experiment on a semiconductor in ultrahigh magnetic fields generated by explosive-driven flux compression. The sample under investigation was a p-type cubic GaN layer grown by plasma-assisted MBE on a (0 0 1)-GaAs substrate. We have used the magnetocumulative generator MC-1 for generating a magnetic field exceeding 700 T. A CO 2 laser with a fixed wavelength of λ=10.6 μm was used as radiation source. The transmitted radiation intensity was detected by use of a fast HgCdTe-detector. The experiment was performed at 270 K in Faraday geometry with the magnetic field oriented parallel to the [0 0 1]-direction of the epitaxial layer. Three distinct transmission minima at about 90 T, 270 T and 400-425 T with a resonance depth of a few percent only, are clearly resolved. The data in the lower field region correspond excellently to results derived previously from experiments in fields up to 275 T generated by use of the single-turn coil technique. The data are compared directly with the Landau level scheme of cubic GaN in the Luttinger model.

  2. Boosting Sensitivity in Liquid Chromatography-Fourier Transform Ion Cyclotron Resonance-Tandem Mass Spectrometry for Product Ion Analysis of Monoterpene Indole Alkaloids

    National Research Council Canada - National Science Library

    Nakabayashi, Ryo; Tsugawa, Hiroshi; Kitajima, Mariko; Takayama, Hiromitsu; Saito, Kazuki

    2015-01-01

    .... However, the development of relevant analytical methods are less advanced. Here, we developed a method to boost sensitivity in liquid chromatography-Fourier transform ion cyclotron resonance-tandem mass spectrometry analysis...

  3. New development of advanced superconducting electron cyclotron resonance ion source SECRAL (invited).

    Science.gov (United States)

    Zhao, H W; Sun, L T; Lu, W; Zhang, X Z; Guo, X H; Cao, Y; Zhao, H Y; Feng, Y C; Li, J Y; Ma, H Y; Shang, Y; Ma, B H; Wang, H; Li, X X; Xie, D Z

    2010-02-01

    Superconducting electron cyclotron resonance ion source with advance design in Lanzhou (SECRAL) is an 18-28 GHz fully superconducting electron cyclotron resonance (ECR) ion source dedicated for highly charged heavy ion beam production. SECRAL, with an innovative superconducting magnet structure of solenoid-inside-sextupole and at lower frequency and lower rf power operation, may open a new way for developing compact and reliable high performance superconducting ECR ion source. One of the recent highlights achieved at SECRAL is that some new record beam currents for very high charge states were produced by 18 GHz or 18+14.5 GHz double frequency heating, such as 1 e microA of (129)Xe(43+), 22 e microA of (209)Bi(41+), and 1.5 e microA of (209)Bi(50+). To further enhance the performance of SECRAL, a 24 GHz/7 kW gyrotron microwave generator was installed and SECRAL was tested at 24 GHz. Some promising and exciting results at 24 GHz with new record highly charged ion beam intensities were produced, such as 455 e microA of (129)Xe(27+) and 152 e microA of (129)Xe(30+), although the commissioning time was limited within 3-4 weeks and rf power only 3-4 kW. Bremsstrahlung measurements at 24 GHz show that x-ray is much stronger with higher rf frequency, higher rf power. and higher minimum mirror magnetic field (minimum B). Preliminary emittance measurements indicate that SECRAL emittance at 24 GHz is slightly higher that at 18 GHz. SECRAL has been put into routine operation at 18 GHz for heavy ion research facility in Lanzhou (HIRFL) accelerator complex since May 2007. The total operation beam time from SECRAL for HIRFL accelerator has been more than 2000 h, and (129)Xe(27+), (78)Kr(19+), (209)Bi(31+), and (58)Ni(19+) beams were delivered. All of these new developments, the latest results, and long-term operation for the accelerator have again demonstrated that SECRAL is one of the best in the performance of ECR ion source for highly charged heavy ion beam production

  4. A proposal for a novel H ion source based on electron cyclotron resonance heating and surface ionization

    Energy Technology Data Exchange (ETDEWEB)

    Tarvainen, Ollie A [Los Alamos National Laboratory; Kurennoy, Sergey [Los Alamos National Laboratory

    2008-01-01

    A design for a novel H{sup -} ion source based on electron cyclotron resonance plasma heating and surface ionization is presented. The plasma chamber of the source is an rf-cavity designed for TE{sub 111} eigenmode at 2.45 GHz. The desired mode is excited with a loop antenna. The ionization process takes place on a cesiated surface of a biased converter electrode. The H{sup -} ion beam is further 'self-extracted' through the plasma region. The magnetic field of the source is optimized for plasma generation by electron cyclotron resonance heating, and beam extraction. The design features of the source are discussed in detail and the attainable H{sup -} ion current, beam emittance and duty factor of the novel source are estimated.

  5. Stochastic heating in the cyclotron resonance of electrons; Calentamiento estocastico en la resonancia ciclotronica de los electrones

    Energy Technology Data Exchange (ETDEWEB)

    Gutierrez T, C.; Hernandez A, O. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    1999-07-01

    The study of the different schemes of plasma heating by radiofrequency waves is a very actual problem related with the plasma heating in different machines and the particle acceleration mechanisms. In this work, it is obtained the expression for the temporal evolution of the energy absorbed in the cyclotron resonance of electrons where it is showed the stochastic character of the energy absorption. It is obtained the stochastic criteria in a magnetic configuration of an Ecr type plasma source. (Author)

  6. Growth of etiolated barley plants in weak static and 50 Hz electromagnetic fields tuned to calcium ion cyclotron resonance

    OpenAIRE

    Pazur, Alexander; Rassadina, Valentina; Dandler, Jörg; Zoller, Jutta

    2006-01-01

    Background The effects of weak magnetic and electromagnetic fields in biology have been intensively studied on animals, microorganisms and humans, but comparably less on plants. Perception mechanisms were attributed originally to ferrimagnetism, but later discoveries required additional explanations like the "radical pair mechanism" and the "Ion cyclotron resonance" (ICR), primarily considered by Liboff. The latter predicts effects by small ions involved in biological processes, that occur in...

  7. 21 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometer Greatly Expands Mass Spectrometry Toolbox

    Energy Technology Data Exchange (ETDEWEB)

    Shaw, Jared B.; Lin, Tzu-Yung; Leach, Franklin E.; Tolmachev, Aleksey V.; Tolić, Nikola; Robinson, Errol W.; Koppenaal, David W.; Paša-Tolić, Ljiljana

    2016-10-12

    We provide the initial performance evaluation of a 21 Tesla Fourier transform ion cyclotron resonance mass spectrometer operating at the Environmental Molecular Sciences Laboratory at Pacific Northwest National Laboratory. The spectrometer constructed for the 21T system employs a commercial dual linear ion trap mass spectrometer coupled to a FTICR spectrometer designed and built in-house. Performance gains from moving to higher magnetic field strength are exemplified by the measurement of peptide isotopic fine structure, complex natural organic matter mixtures, and large proteins. Accurate determination of isotopic fine structure was demonstrated for doubly charged substance P with minimal spectral averaging, and 8,158 molecular formulas assigned to Suwannee River Fulvic Acid standard with RMS error of 10 ppb. We also demonstrated superior performance for intact proteins; namely, broadband isotopic resolution of the entire charge state distribution of apotransferrin (78 kDa) and facile isotopic resolution of monoclonal antibody under a variety of acquisition parameters (e.g. 6 s time-domains with absorption mode processing yielded resolution of approximately 1M at m/z =2,700).

  8. C60 Secondary Ion Fourier Transform Ion Cyclotron Resonance Mass Spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Donald F.; Robinson, Errol W.; Tolmachev, Aleksey V.; Heeren, Ronald M.; Pasa-Tolic, Ljiljana

    2011-12-15

    Secondary ion mass spectrometry (SIMS) has seen increased application for high spatial chemical imaging of complex biological surfaces. The advent and commercial availability of cluster and polyatomic primary ion sources (e.g. Au and Bi cluster and buckminsterfullerene (C60)) provide improved secondary ion yield and decreased fragmentation of surface species, thus accessibility to intact molecular ions. Despite developments in primary ion sources, development of mass spectrometers to fully exploit their advantages has been limited. Tandem mass spectrometry for identification of secondary ions is highly desirable, but implementation has proven to be difficult. Similarly, high mass resolution and high mass measurement accuracy would greatly improve the chemical specificity of SIMS. Here we combine, for the first time, the advantages of a C60 primary ion source with the ultra-high mass resolving power and high mass measurement accuracy of Fourier transform ion cyclotron resonance mass spectrometry. Mass resolving power in excess of 100,000 (m/Δm50%) is demonstrated, with mass measurement accuracies below 3 parts-per-million. Imaging of mouse brain tissue at 40 μm pixel size is shown. Tandem mass spectrometry of ions from biological tissue is demonstrated and molecular formulae can be assigned to fragment ions.

  9. Design of coupled cavity with energy modulated electron cyclotron resonance ion source for materials irradiation research

    Directory of Open Access Journals (Sweden)

    Z. Wang (王智

    2012-05-01

    Full Text Available The surface topography of samples after irradiation with heavy ions, protons, and helium ions based on accelerators is an important issue in the study of materials irradiation. We have coupled the separated function radio frequency quadrupole (SFRFQ electrodes and the traditional RFQ electrodes into a single cavity that can provide a 0.8 MeV helium beam for our materials irradiation project. The higher accelerating efficiency has been verified by the successful commissioning of the prototype SFRFQ cavity. An energy modulated electron cyclotron resonance (ECR ion source can achieve a well-bunched beam by loading a sine wave voltage onto the extracted electrodes. Bunching is achieved without the need for an external bunch cavity, which can substantially reduce the cost of the system and the length of the beam line. The coupled RFQ-SFRFQ with an energy modulated ECR ion source will lead to a more compact accelerator system. The conceptual design of this novel structure is presented in this paper.

  10. Increase of the performances of electron cyclotron resonance ion sources by using cold electron emission

    CERN Document Server

    Schaechter, I; Badescu-Singureanu, A I; Stiebing, K E; Runkel, S; Hohn, O; Schmidt, L; Schmidt-Böcking, H; Drentje, A; Rodríguez, G

    2003-01-01

    The possibility of a significant increase of the high charge state ion beams delivered by electron cyclotron resonance (ECR) ion sources was approached in IFIN-HH, Bucharest, Romania by a new method. It consists in the introduction in the plasma chamber of the ECR ion source of a metal-dielectric (MD) structure characterized by very high secondary electron emission properties. The intensities of argon ion beams extracted from the 14 GHz ECR ion sources of IKF, Frankfurt/Main, Germany and KVI, Groningen, Netherlands were measured both in the standard mode of operation of the sources and in the presence of a MD structure. Similar results were obtained in both experiments when the MD structure was used showing a net shift of the beam intensity towards higher charge states as compared with the usual standard plasma chamber of the ECR ion sources. Ion current enhancement factors of up to two orders of magnitude were obtained for Ar sup 1 sup 6 sup + ions. (authors)

  11. High-Throughput Metabolic Profiling of Soybean Leaves by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry.

    Science.gov (United States)

    Yilmaz, Ali; Rudolph, Heather L; Hurst, Jerod J; Wood, Troy D

    2016-01-19

    As a relatively recent research field, plant metabolomics has gained increasing interest in the past few years and has been applied to answer biological questions through large-scale qualitative and quantitative analyses of the plant metabolome. The combination of sensitivity and selectivity offered by mass spectrometry (MS) for measurement of many metabolites in a single shot makes it an indispensable platform in metabolomics. In this regard, Fourier-transform ion cyclotron resonance (FTICR) has the unique advantage of delivering high mass resolving power and mass accuracy simultaneously, making it ideal for the study of complex mixtures such as plant extracts. Here we optimize soybean leaf extraction methods compatible with high-throughput reproducible MS-based metabolomics. In addition, matrix-assisted laser desorption ionization (MALDI) and direct LDI of soybean leaves are compared for metabolite profiling. The extraction method combined with electrospray (ESI)-FTICR is supported by the significant reduction of chlorophyll and its related metabolites as the growing season moves from midsummer to the autumn harvest day. To our knowledge for the first time, the use of ESI-FTICR MS and MALDI-FTICR MS is described in a complementary manner with the aim of metabolic profiling of plant leaves that have been collected at different time points during the growing season.

  12. A gain and bandwidth enhanced transimpedance preamplifier for Fourier-transform ion cyclotron resonance mass spectrometry

    Science.gov (United States)

    Lin, Tzu-Yung; Green, Roger J.; O'Connor, Peter B.

    2011-01-01

    The nature of the ion signal from a 12-T Fourier-transform ion cyclotron resonance mass spectrometer and the electronic noise were studied to further understand the electronic detection limit. At minimal cost, a new transimpedance preamplifier was designed, computer simulated, built, and tested. The preamplifier design pushes the electronic signal-to-noise performance at room temperature to the limit, because of its enhanced tolerance of the capacitance of the detection device, lower intrinsic noise, and larger flat mid-band gain (input current noise spectral density of around 1 pA/\\documentclass[12pt]{minimal}\\begin{document}$\\sqrt{\\mbox{Hz}}$\\end{document}Hz when the transimpedance is about 85 dBΩ). The designed preamplifier has a bandwidth of ∼3 kHz to 10 MHz, which corresponds to the mass-to-charge ratio, m/z, of approximately 18 to 61 k at 12 T. The transimpedance and the bandwidth can be easily adjusted by changing the value of passive components. The feedback limitation of the circuit is discussed. With the maximum possible transimpedance of 5.3 MΩ when using an 0402 surface mount resistor, the preamplifier was estimated to be able to detect ∼110 charges in a single scan. PMID:22225232

  13. First Signal on the Cryogenic Fourier-Transform Ion Cyclotron Resonance Mass Spectrometer

    Science.gov (United States)

    Lin, Cheng; Mathur, Raman; Aizikov, Kostantin; O'Connor, Peter B.

    2009-01-01

    The construction and achievement of the first signal on a cryogenic Fourier-transform ion cyclotron resonance mass spectrometer (FT-ICR-MS) are reported here, demonstrating proof-of-concept of this new instrument design. Building the FTICR cell into the cold bore of a superconducting magnet provided advantages over conventional warm bore design. At 4.2 K, the vacuum system cryopumps itself, thus removing the requirement for a large bore to achieve the desired pumping speed for maintaining base pressure. Furthermore, because the bore diameter has been reduced, the amount of magnet wire needed to achieve high field and homogeneity was also reduced, greatly decreasing the cost/Tesla of the magnet. The current instrument implements an actively shielded 14-Tesla magnet of vertical design with an external matrix assisted laser desorption/ionization (MALDI) source. The first signal was obtained by detecting the laser desorbed/ionized (LDI) C60+• ions, with the magnet at 7 Tesla, unshimmed, and the preamplifier mounted outside of the vacuum chamber at room temperature. A subsequent experiment done with the magnet at 14 Tesla and properly shimmed produced a C60 spectrum showing ∼350,000 resolving power at m/z ∼720. Increased magnetic field strength improves many FTMS performance parameters simultaneously, particularly mass resolving power and accuracy. PMID:17931882

  14. 21 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometer Greatly Expands Mass Spectrometry Toolbox

    Science.gov (United States)

    Shaw, Jared B.; Lin, Tzu-Yung; Leach, Franklin E.; Tolmachev, Aleksey V.; Tolić, Nikola; Robinson, Errol W.; Koppenaal, David W.; Paša-Tolić, Ljiljana

    2016-12-01

    We provide the initial performance evaluation of a 21 Tesla Fourier transform ion cyclotron resonance mass spectrometer operating at the Environmental Molecular Sciences Laboratory at the Pacific Northwest National Laboratory. The spectrometer constructed for the 21T system employs a commercial dual linear ion trap mass spectrometer coupled to a FTICR spectrometer designed and built in-house. Performance gains from moving to higher magnetic field strength are exemplified by the measurement of peptide isotopic fine structure, complex natural organic matter mixtures, and large proteins. Accurate determination of isotopic fine structure was demonstrated for doubly charged Substance P with minimal spectral averaging, and 8158 molecular formulas assigned to Suwannee River Fulvic Acid standard with root-mean-square (RMS) error of 10 ppb. We also demonstrated superior performance for intact proteins; namely, broadband isotopic resolution of the entire charge state distribution of apo-transferrin (78 kDa) and facile isotopic resolution of monoclonal antibody under a variety of acquisition parameters (e.g., 6 s time-domains with absorption mode processing yielded resolution of approximately 1 M at m/z = 2700).

  15. Electron cyclotron resonance heating by magnetic filter field in a negative hydrogen ion source

    Energy Technology Data Exchange (ETDEWEB)

    Kim, June Young, E-mail: beacoolguy@snu.ac.kr; Cho, Won-Hwi; Dang, Jeong-Jeung; Chung, Kyoung-Jae, E-mail: jkjlsh1@snu.ac.kr; Hwang, Y. S. [Department of Nuclear Engineering, Seoul National University, Seoul 151-742 (Korea, Republic of)

    2016-02-15

    The influence of magnetic filter field on plasma properties in the heating region has been investigated in a planar-type inductively coupled radio-frequency (RF) H{sup −} ion source. Besides filtering high energy electrons near the extraction region, the magnetic filter field is clearly observed to increase the electron temperature in the heating region at low pressure discharge. With increasing the operating pressure, enhancement of electron temperature in the heating region is reduced. The possibility of electron cyclotron resonance (ECR) heating in the heating region due to stray magnetic field generated by a filter magnet located at the extraction region is examined. It is found that ECR heating by RF wave field in the discharge region, where the strength of an axial magnetic field is approximately ∼4.8 G, can effectively heat low energy electrons. Depletion of low energy electrons in the electron energy distribution function measured at the heating region supports the occurrence of ECR heating. The present study suggests that addition of axial magnetic field as small as several G by an external electromagnet or permanent magnets can greatly increase the generation of highly ro-vibrationally excited hydrogen molecules in the heating region, thus improving the performance of H{sup −} ion generation in volume-produced negative hydrogen ion sources.

  16. Electron cyclotron resonance discharge as a source for hydrogen and deuterium ions production

    Energy Technology Data Exchange (ETDEWEB)

    Chacon Velasco, A.J. [Universidad de Pamplona, Pamplona (Colombia); Dougar-Jabon, V.D. [Universidad Industrial de Santander, Bucaramanga (Colombia)

    2004-07-01

    In this report, we describe characteristics of a ring-structure hydrogen plasma heated in electron cyclotron resonance conditions and confined in a mirror magnetic trap and discuss the relative efficiency of secondary electrons and thermo-electrons in negative hydrogen and deuterium ion production. The obtained data and calculations of the balance equations for possible reactions demonstrate that the negative ion production is realized in two stages. First, the hydrogen and deuterium molecules are excited in collisions with the plasma electrons to high-laying Rydberg or vibrational levels in the plasma volume. The second stage leads to the negative ion production through the process of dissociative attachment of low energy electrons. The low energy electrons are originated due to a bombardment of the plasma electrode by ions of one of the driven rings and thermo-emission from heated tungsten filaments. Experiments seem to indicate that the negative ion generation occurs predominantly in the limited volume filled with thermo-electrons. Estimation of the negative ion generation rate shows that the main channel of H{sup -} and D{sup -} ion production involves the process of high Rydberg state excitation. (authors)

  17. Atmospheric pressure chemical ionization Fourier transform ion cyclotron resonance mass spectrometry for complex thiophenic mixture analysis

    KAUST Repository

    Hourani, Nadim

    2013-10-01

    Rationale Polycyclic aromatic sulfur heterocycles (PASHs) are detrimental species for refining processes in petroleum industry. Current mass spectrometric Methods that determine their composition are often preceded by derivatization and dopant addition approaches. Different ionization Methods have different impact on the molecular assignment of complex PASHs. The analysis of such species under atmospheric pressure chemical ionization (APCI) is still considered limited due to uncontrolled ion generation with low- and high-mass PASHs. Methods The ionization behavior of a model mixture of five selected PASH standards was investigated using an APCI source with nitrogen as the reagent gas. A complex thiophenic fraction was separated from a vacuum gas oil (VGO) and injected using the same method. The samples were analyzed using Fourier transform ion cyclotron resonance mass spectrometry (FTICR MS). RESULTS PASH model analytes were successfully ionized and mainly [M + H]+ ions were produced. The same ionization pattern was observed for the real thiophenic sample. It was found that S1 class species were the major sulfur-containing species found in the VGO sample. These species indicated the presence of alkylated benzothiophenic (BT), dibenzothiophenic (DBT) and benzonaphthothiophenic (BNT) series that were detected by APCI-FTICR MS. CONCLUSIONS This study provides an established APCI-FTICR MS method for the analysis of complex PASHs. PASHs were detected without using any derivatization and without fragmentation. The method can be used for the analysis of S-containing crude oil samples. © 2013 John Wiley & Sons, Ltd.

  18. First results from the new RIKEN superconducting electron cyclotron resonance ion source (invited).

    Science.gov (United States)

    Nakagawa, T; Higurashi, Y; Ohnishi, J; Aihara, T; Tamura, M; Uchiyama, A; Okuno, H; Kusaka, K; Kidera, M; Ikezawa, E; Fujimaki, M; Sato, Y; Watanabe, Y; Komiyama, M; Kase, M; Goto, A; Kamigaito, O; Yano, Y

    2010-02-01

    The next generation heavy ion accelerator facility, such as the RIKEN radio isotope (RI) beam factory, requires an intense beam of high charged heavy ions. In the past decade, performance of the electron cyclotron resonance (ECR) ion sources has been dramatically improved with increasing the magnetic field and rf frequency to enhance the density and confinement time of plasma. Furthermore, the effects of the key parameters (magnetic field configuration, gas pressure, etc.) on the ECR plasma have been revealed. Such basic studies give us how to optimize the ion source structure. Based on these studies and modern superconducting (SC) technology, we successfully constructed the new 28 GHz SC-ECRIS, which has a flexible magnetic field configuration to enlarge the ECR zone and to optimize the field gradient at ECR point. Using it, we investigated the effect of ECR zone size, magnetic field configuration, and biased disk on the beam intensity of the highly charged heavy ions with 18 GHz microwaves. In this article, we present the structure of the ion source and first experimental results with 18 GHz microwave in detail.

  19. Ion trap with narrow aperture detection electrodes for Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Nagornov, Konstantin O; Kozhinov, Anton N; Tsybin, Oleg Y; Tsybin, Yury O

    2015-05-01

    The current paradigm in ion trap (cell) design for Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) is the ion detection with wide aperture detection electrodes. Specifically, excitation and detection electrodes are typically 90° wide and positioned radially at a similar distance from the ICR cell axis. Here, we demonstrate that ion detection with narrow aperture detection electrodes (NADEL) positioned radially inward of the cell's axis is feasible and advantageous for FT-ICR MS. We describe design details and performance characteristics of a 10 T FT-ICR MS equipped with a NADEL ICR cell having a pair of narrow aperture (flat) detection electrodes and a pair of standard 90° excitation electrodes. Despite a smaller surface area of the detection electrodes, the sensitivity of the NADEL ICR cell is not reduced attributable to improved excite field distribution, reduced capacitance of the detection electrodes, and their closer positioning to the orbits of excited ions. The performance characteristics of the NADEL ICR cell are comparable with the state-of-the-art FT-ICR MS implementations for small molecule, peptide, protein, and petroleomics analyses. In addition, the NADEL ICR cell's design improves the flexibility of ICR cells and facilitates implementation of advanced capabilities (e.g., quadrupolar ion detection for improved mainstream applications). It also creates an intriguing opportunity for addressing the major bottleneck in FTMS-increasing its throughput via simultaneous acquisition of multiple transients or via generation of periodic non-sinusoidal transient signals.

  20. Electric polarization and the viability of living systems: ion cyclotron resonance-like interactions.

    Science.gov (United States)

    Liboff, A R

    2009-01-01

    Wellness can be described in physical terms as a state that is a function of the organism's electric polarization vector P(r, t). One can alter P by invasive application of electric fields or by non invasive external pulsed magnetic fields (PMF) or ion cyclotron resonance (ICR)-like combinations of static and sinusoidal magnetic fields. Changes in human (total) body bioimpedance are significantly altered during exposure to ICR magnetic field combinations. The conductivities of polar amino acids in solution exhibit sharp discontinuities at ICR magnetic fields tuned to the specific charge to mass ratio of the amino acid. It has been reported that protein peptide bonds are broken by such amino acid ICR fields. Remarkably, some of these effects are only found at ultra-low AC magnetic intensities, on the order of .05 muT. This is approximately 10(3) below accepted levels determined by engineering estimates. Such strikingly low magnetic intensities imply the existence of physically equivalent endogenous weak electric field oscillations. These observations not only make claims related to electromagnetic pollution more credible but also provide a basis for future electromagnetic applications in medicine. They also reinforce the notion that physical factors acting to influence the electric polarization in living organisms play a key role in biology.

  1. Effects of Electron-Cyclotron-Resonance Oxygen Plasma Irradiation on Properties of Insulator/Ge-Semiconductor Interfaces Prior to Germanium Nitride Formation

    Science.gov (United States)

    Otani, Yohei; Fukuda, Yukio; Sato, Tetsuya; Nakagawa, Kiyokazu; Toyota, Hiroshi; Ono, Toshiro

    2008-09-01

    Electron-cyclotron-resonance (ECR) oxygen (O2) plasma was irradiated onto the surface of germanium (Ge) substrates prior to germanium nitride (GeNx) formation. Germanium metal-insulator-semiconductor (Ge-MIS) structures with a 5-nm-thick silicon nitride/2-nm-thick GeNx gate insulator stack fabricated by ECR plasma nitridation and sputtering deposition without substrate heating were electrically and physically characterized. Although ECR O2 plasma irradiation onto the surface of Ge substrates caused no significant difference in the chemical state of GeNx/Ge interfaces in X-ray photoemission spectroscopic measurement, irradiation for an appropriate period improved the state of GeNx/Ge interfaces and the electrical properties of Ge-MIS.

  2. Bayesian fuzzy logic-based estimation of electron cyclotron heating (ECH) power deposition in MHD control systems

    Energy Technology Data Exchange (ETDEWEB)

    Davoudi, Mehdi, E-mail: mehdi.davoudi@polimi.it [Department of Electrical and Computer Engineering, Buein Zahra Technical University, Buein Zahra, Qazvin (Iran, Islamic Republic of); Davoudi, Mohsen, E-mail: davoudi@eng.ikiu.ac.ir [Department of Electrical Engineering, Imam Khomeini International University, Qazvin, 34148-96818 (Iran, Islamic Republic of)

    2017-06-15

    Highlights: • A couple of algorithms to diagnose if Electron Cyclotron Heating (ECH) power is deposited properly on the expected deposition minor radius are proposed. • The algorithms are based on Bayesian theory and Fuzzy logic. • The algorithms are tested on the off-line experimental data acquired from Frascati Tokamak Upgrade (FTU), Frascati, Italy. • Uncertainties and evidences derived from the combination of online information formed by the measured diagnostic data and the prior information are also estimated. - Abstract: In the thermonuclear fusion systems, the new plasma control systems use some measured on-line information acquired from different sensors and prior information obtained by predictive plasma models in order to stabilize magnetic hydro dynamics (MHD) activity in a tokamak. Suppression of plasma instabilities is a key issue to improve the confinement time of controlled thermonuclear fusion with tokamaks. This paper proposes a couple of algorithms based on Bayesian theory and Fuzzy logic to diagnose if Electron Cyclotron Heating (ECH) power is deposited properly on the expected deposition minor radius (r{sub DEP}). Both algorithms also estimate uncertainties and evidences derived from the combination of the online information formed by the measured diagnostic data and the prior information. The algorithms have been employed on a set of off-line ECE channels data which have been acquired from the experimental shot number 21364 at Frascati Tokamak Upgrade (FTU), Frascati, Italy.

  3. R&D activities on RF contacts for the ITER ion cyclotron resonance heating launcher

    Energy Technology Data Exchange (ETDEWEB)

    Hillairet, Julien, E-mail: julien.hillairet@cea.fr [CEA, IRFM, F-13108 Saint-Paul-lez-Durance (France); Argouarch, Arnaud [CEA, IRFM, F-13108 Saint-Paul-lez-Durance (France); Bamber, Rob [CCFE, Culham Science Centre, Abingdon OX14 3DB (United Kingdom); Beaumont, Bertrand [ITER Organization, Route de Vinon-sur-Verdon, CS 90 046, 13067 St. Paul Lez Durance Cedex (France); Bernard, Jean-Michel; Delaplanche, Jean-Marc [CEA, IRFM, F-13108 Saint-Paul-lez-Durance (France); Durodié, Frédéric [Laboratory for Plasmas Physics, 1000 Brussels (Belgium); Lamalle, Philippe [ITER Organization, Route de Vinon-sur-Verdon, CS 90 046, 13067 St. Paul Lez Durance Cedex (France); Lombard, Gilles [CEA, IRFM, F-13108 Saint-Paul-lez-Durance (France); Nicholls, Keith; Shannon, Mark [CCFE, Culham Science Centre, Abingdon OX14 3DB (United Kingdom); Vulliez, Karl [Maestral Laboratory, Technetics Group, Pierrelatte (France); Cantone, Vincent; Hatchressian, Jean-Claude; Larroque, Sébastien; Lebourg, Philippe; Martinez, André; Mollard, Patrick; Mouyon, David; Pagano, Marco [CEA, IRFM, F-13108 Saint-Paul-lez-Durance (France); and others

    2015-10-15

    Highlights: • CEA have developed a dedicated test-bed for testing RF contact in ITER relevant conditions (vacuum, temperature, RF current). • A prototype of RF contacts have been designed and manufactured, with copper lamellas brazed on a titanium holder. • This RF contact prototype failed at RF current larger than 1.8 kA. • Extensive R&D is foreseen with new RF contact designs. - Abstract: Embedded RF contacts are integrated within the ITER ICRH launcher to allow assembling, sliding and to lower the thermo-mechanical stress. They have to withstand a peak RF current up to 2.5 kA at 55 MHz in steady-state conditions, in the vacuum environment of the machine. The contacts have to sustain a temperature up to 250 °C during several days in baking operations and have to be reliable during the whole life of the launcher without degradation. The RF contacts are critical components for the launcher performance and intensive R&D is therefore required, since no RF contacts have so far been qualified at these specifications. In order to test and validate the anticipated RF contacts in operational conditions, CEA has prepared a test platform consisting of a steady-state vacuum pumped RF resonator. In collaboration with ITER Organization and the CYCLE consortium (CYclotron CLuster for Europe), an R&D program has been conducted to develop RF contacts that meet the ITER ICRH launcher specifications. A design proposed by CYCLE consortium, using brazed lamellas supported by a spring to improve thermal exchange efficiency while guaranteeing high contact force, was tested successfully in the T-resonator up to 1.7 kA during 1200 s, but failed for larger current values due to a degradation of the contacts. Details concerning the manufacturing of the brazed contacts on its titanium holder, the RF tests results performed on the resonator and the non-destructive tests analysis of the contacts are given in this paper.

  4. Observations of compound sawteeth in ion cyclotron resonant heating plasma using ECE imaging on experimental advanced superconducting tokamak

    Science.gov (United States)

    Hussain, Azam; Zhao, Zhenling; Xie, Jinlin; Zhu, Ping; Liu, Wandong; Ti, Ang

    2016-04-01

    The spatial and temporal evolutions of compound sawteeth were directly observed using 2D electron cyclotron emission imaging on experimental advanced superconducting tokamak. The compound sawtooth consists of partial and full collapses. After partial collapse, the hot core survives as only a small amount of heat disperses outwards, whereas in the following full collapse a large amount of heat is released and the hot core dissipates. The presence of two q = 1 surfaces was not observed. Instead, the compound sawtooth occurs mainly at the beginning of an ion cyclotron resonant frequency heating pulse and during the L-H transition phase, which may be related to heat transport suppression caused by a decrease in electron heat diffusivity.

  5. Towards analytically useful two-dimensional Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    van Agthoven, Maria A; Delsuc, Marc-André; Bodenhausen, Geoffrey; Rolando, Christian

    2013-01-01

    Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry (MS) achieves high resolution and mass accuracy, allowing the identification of the raw chemical formulae of ions in complex samples. Using ion isolation and fragmentation (MS/MS), we can obtain more structural information, but MS/MS is time- and sample-consuming because each ion must be isolated before fragmentation. In 1987, Pfändler et al. proposed an experiment for 2D FT-ICR MS in order to fragment ions without isolating them and to visualize the fragmentations of complex samples in a single 2D mass spectrum, like 2D NMR spectroscopy. Because of limitations of electronics and computers, few studies have been conducted with this technique. The improvement of modern computers and the use of digital electronics for FT-ICR hardware now make it possible to acquire 2D mass spectra over a broad mass range. The original experiments used in-cell collision-induced dissociation, which caused a loss of resolution. Gas-free fragmentation modes such as infrared multiphoton dissociation and electron capture dissociation allow one to measure high-resolution 2D mass spectra. Consequently, there is renewed interest to develop 2D FT-ICR MS into an efficient analytical method. Improvements introduced in 2D NMR spectroscopy can also be transposed to 2D FT-ICR MS. We describe the history of 2D FT-ICR MS, introduce recent improvements, and present analytical applications to map the fragmentation of peptides. Finally, we provide a glossary which defines a few keywords for the 2D FT-ICR MS field.

  6. Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry of large biomolecules in complex buffer systems

    Energy Technology Data Exchange (ETDEWEB)

    Hofstadler, S.A.; Bruce, J.E.; Cheng, X.; Anderson, G.A.; Smith, R.D. [Pacific Northwest Lab., Richland, WA (United States); Wang, K. [Univ.of Texas, Austin, TX (United States); Swanek, F.; Ewing, A.G. [Penn State Univ., University Park, PA (United States)

    1994-12-31

    Recent advances in electrospray ionization (ESI) Fourier transform ion cyclotron resonance (FTICR) mass spectrometry allow ultra-high resolution, precision mass measurements of a wide range of biochemically relevant species including proteins, glycoproteins, DNA, and non-covalent complexes. One of the most common difficulties encountered when analyzing biological samples derived from multi-step extraction procedures is obtaining an {open_quotes}electrosprayable{close_quotes} analyte solution which keeps the protein(s) of interest in solution and which does not create numerous background ions which overwhelm the analyte signal or adversely affect the electrospray ionization process. In addition to loss of sensitivity, ionized buffer ions introduce undesirable space charge to the trapped ion cell which limits dynamic range and adversely affects mass measurement precision. Thus, it is highly desirable to minimize the number of background ions in the trapped ion cell. In this poster the authors will present two distinct, and potentially complimentary, techniques which allow high performance mass analysis of biomolecules from complex buffer systems. The first technique, which is particularly well suited for larger analytes, discriminates against low mass matrix ions by the combination of kinetic energy dependent ion accumulation and mass dependent ion loss due to collisionally enhanced magnetron radii. An alternative technique, which is particularly applicable to smaller analytes, is based on electrophoretic separations using on-line capillary zone electrophoresis prior to mass analysis. Preliminary results are presented in which two classes of biomolecules were analyzed from complex buffer systems. These examples include large muscle proteins electrosprayed directly from a 5 M urea buffer and mass analysis from whole human erthrocytes extracted from a buffer which mimics physiological conditions.

  7. Numerical simulations of gas mixing effect in electron cyclotron resonance ion sources

    Directory of Open Access Journals (Sweden)

    V. Mironov

    2017-01-01

    Full Text Available The particle-in-cell Monte Carlo collisions code nam-ecris is used to simulate the electron cyclotron resonance ion source (ECRIS plasma sustained in a mixture of Kr with O_{2}, N_{2}, Ar, Ne, and He. The model assumes that ions are electrostatically confined in the ECR zone by a dip in the plasma potential. A gain in the extracted krypton ion currents is seen for the highest charge states; the gain is maximized when oxygen is used as a mixing gas. The special feature of oxygen is that most of the singly charged oxygen ions are produced after the dissociative ionization of oxygen molecules with a large kinetic energy release of around 5 eV per ion. The increased loss rate of energetic lowly charged ions of the mixing element requires a building up of the retarding potential barrier close to the ECR surface to equilibrate electron and ion losses out of the plasma. In the mixed plasmas, the barrier value is large (∼1  V compared to pure Kr plasma (∼0.01  V, with longer confinement times of krypton ions and with much higher ion temperatures. The temperature of the krypton ions is increased because of extra heating by the energetic oxygen ions and a longer time of ion confinement. In calculations, a drop of the highly charged ion currents of lighter elements is observed when adding small fluxes of krypton into the source. This drop is caused by the accumulation of the krypton ions inside plasma, which decreases the electron and ion confinement times.

  8. Modeling of ion-cyclotron resonant heating in Wendelstein 7-X equilibrium

    Science.gov (United States)

    Faustin, J. M.; Cooper, W. A.; Graves, J. P.; Pfefferlé, D.

    2014-11-01

    W7X stellarator 3D equilibrium has been computed with the equilibrium code ANIMEC (Anisotropic Neumann Inverse Moments Equilibrium Code). This equilibrium was used to model ICRH minority heating in 4He(H) plasma with the 3D full-wave code LEMan (Low frequency ElectroMagnetic wave propagation). The coupled power spatial distribution is shown for different resonance positions within the range of frequencies foreseen for the ICRH antenna. It is found that for the high mirror equilibrium examined, the antenna frequency can be chosen to optimise the power deposition in the plasma core while limiting the absorption at the edge.

  9. Production of highly charged heavy ions by 18 GHz superconducting electron cyclotron resonance at Research Center for Nuclear Physics.

    Science.gov (United States)

    Yorita, Tetsuhiko; Hatanaka, Kichiji; Fukuda, Mitsuhiro; Kibayashi, Mitsuru; Morinobu, Shunpei; Okamura, Hiroyuki; Tamii, Atsushi

    2010-02-01

    An 18 GHz superconducting electron cyclotron resonance ion source has been installed as a subject of the azimuthally varying field cyclotron upgrade project (K. Hatanaka et al., in Proceedings of the 17th International Conference on Cyclotrons and Their Applications, Tokyo, Japan, 18-22 October 2004, pp. 115-117), in order to increase beam currents and to extend the variety of ions. The production development of several ions has been performed since 2006 and some of them have already been used for user experiments [T. Yorita et al., Rev. Sci. Instrum. 79, 02A311 (2008)]. Further optimizations for each component such as the material of plasma electrode, material, and shape of bias probe and mirror field have been continued and more intense ion beams have been obtained for O, N, and Ar. For the purpose of obtaining highly charged Xe with several microamperes, the optimization of position and shape of plasma electrode and bias disk has also been done and highly charged Xe(32+) beam has been obtained successfully.

  10. Design and Research of Electron Cyclotron Resonance Heating and Current Dive System on HL-2M Tokamak

    Science.gov (United States)

    Huang, Mei; Rao, Jao; Song, Shaodong; Wang, He; Chen, Gangyu; Kang, Zhihua; Zhang, Feng; Wang, Jieqiong; Ye, Jiruo; Feng, Kun; Lu, Bo; Huang, Bo; Wang, Chao; Wang, Mingwei; Xuan, Weimin; Rao, Lieying; Li, Qing; Mao, Xiaohui; Duan, Xuru; Liu, Yong

    2017-07-01

    A research has been conducted to develop an 8MW electron cyclotron resonance heating and current drive (ECRH/ECCD) system on HL-2M tokamak. The ECRH system compromise eight 1MW gyrotrons, eight evacuated transmission lines and three launchers. The main purpose of the ECRH system was to suppress the neo-classical tearing modes and control the plasma profile. This paper presents an overview of the design and studies performed in this framework. Some primary test results of the critical components have been released in this paper, e.g. polarizers, power monitor and fast steering launchers.

  11. Pitch-angle diffusion coefficients from resonant interactions with electrostatic electron cyclotron harmonic waves in planetary magnetospheres

    Directory of Open Access Journals (Sweden)

    A. K. Tripathi

    2011-02-01

    Full Text Available Pitch-angle diffusion coefficients have been calculated for resonant interaction with electrostatic electron cyclotron harmonic (ECH waves in the magnetospheres of Earth, Jupiter, Saturn, Uranus and Neptune. Calculations have been performed at two radial distances of each planet. It is found that observed wave electric field amplitudes in the magnetospheres of Earth and Jupiter are sufficient to put electrons on strong diffusion in the energy range of less than 100 eV. However, for Saturn, Uranus and Neptune, the observed ECH wave amplitude are insufficient to put electrons on strong diffusion at any radial distance.

  12. Emittance study of a 28 GHz electron cyclotron resonance ion source for the Rare Isotope Science Project superconducting linear accelerator.

    Science.gov (United States)

    Park, Bum-Sik; Hong, In-Seok; Jang, Ji-Ho; Jin, Hyunchang; Choi, Sukjin; Kim, Yonghwan

    2016-02-01

    A 28 GHz electron cyclotron resonance (ECR) ion source is being developed for use as an injector for the superconducting linear accelerator of the Rare Isotope Science Project. Beam extraction from the ECR ion source has been simulated using the KOBRA3-INP software. The simulation software can calculate charged particle trajectories in three dimensional complex magnetic field structures, which in this case are formed by the arrangement of five superconducting magnets. In this study, the beam emittance is simulated to understand the effects of plasma potential, mass-to-charge ratio, and spatial distribution. The results of these simulations and their comparison to experimental results are presented in this paper.

  13. Influence of electron injection on electron cyclotron resonance plasma properties and reflected mode electrons (abstract)

    Science.gov (United States)

    Ovsyannikov, V. P.; Ullmann, F.; Zschornack, G.

    2000-02-01

    The injection of an additional strong focused electron beam from a special designed electron gun into a magnetic electron cyclotron resonance (ECR) confinement field is studied. The electron gun uses a cathode with a long lifetime and resistiveness providing high emission current densities with electron currents up to 50 mA and voltages up to 4 keV. A sequence of aluminum foils is used to investigate the trajectories of the electrons in the magnetic field without plasma. The high density electron beam passes through the foils, welds them, and prints its image into the foils. Details of this technique are described in Ref. 1. Using this technique we see that before the electrons enter the sextupole region the beam moves along the magnetic straight lines preserving its structure. Only a central beam passes through the sextupole region, thereby changing its form due to the interaction with radial components of the magnetic field. A new operation method at our 14.5 GHz ECR ion source is based on so-called reflection mode electrons (RMEs) analogous to a known electron beam ion source operation regime.2 The basic idea is that electrons, which traveling from the cathode in a strong axial field, meet an anticathode potential, are reflected from it, move back to the cathode, and will be reflected again and so on. It can be supposed that the electrons will make reflections up to the moment when the anode aperture of the gun is fulfilled and the electrons will be collected on the anode electrode. Investigations are performed extracting nitrogen ions using the RME beam. As a result we got a clear increase in the beam current of the extracted ions (e.g., at 10 mA electron injection an increase of the current of N5+ ions up to 400%) and a shift of the measured ion charge state distribution to higher mean ionization stages. Measured x-ray spectra from a neon loaded plasma show for the case of RME operation increasing energy shifts to the high energy side of the spectra, i.e., the

  14. Nb3Sn superconducting magnets for electron cyclotron resonance ion sources.

    Science.gov (United States)

    Ferracin, P; Caspi, S; Felice, H; Leitner, D; Lyneis, C M; Prestemon, S; Sabbi, G L; Todd, D S

    2010-02-01

    Electron cyclotron resonance (ECR) ion sources are an essential component of heavy-ion accelerators. Over the past few decades advances in magnet technology and an improved understanding of the ECR ion source plasma physics have led to remarkable performance improvements of ECR ion sources. Currently third generation high field superconducting ECR ion sources operating at frequencies around 28 GHz are the state of the art ion injectors and several devices are either under commissioning or under design around the world. At the same time, the demand for increased intensities of highly charged heavy ions continues to grow, which makes the development of even higher performance ECR ion sources a necessity. To extend ECR ion sources to frequencies well above 28 GHz, new magnet technology will be needed in order to operate at higher field and force levels. The superconducting magnet program at LBNL has been developing high field superconducting magnets for particle accelerators based on Nb(3)Sn superconducting technology for several years. At the moment, Nb(3)Sn is the only practical conductor capable of operating at the 15 T field level in the relevant configurations. Recent design studies have been focused on the possibility of using Nb(3)Sn in the next generation of ECR ion sources. In the past, LBNL has worked on the VENUS ECR, a 28 GHz source with solenoids and a sextupole made with NbTi operating at fields of 6-7 T. VENUS has now been operating since 2004. We present in this paper the design of a Nb(3)Sn ECR ion source optimized to operate at an rf frequency of 56 GHz with conductor peak fields of 13-15 T. Because of the brittleness and strain sensitivity of Nb(3)Sn, particular care is required in the design of the magnet support structure, which must be capable of providing support to the coils without overstressing the conductor. In this paper, we present the main features of the support structure, featuring an external aluminum shell pretensioned with water

  15. Stochasticity of the energy absorption in the electron cyclotron resonance; Estocasticidad de la absorcion de energia en la resonancia electron-ciclotronica

    Energy Technology Data Exchange (ETDEWEB)

    Gutierrez T, C. [Departamento de Fisica, ININ, A.P. 18-1027, 11801 Mexico D.F. (Mexico); Hernandez A, O

    1998-07-01

    The energy absorption mechanism in cyclotron resonance of the electrons is a present problem, since it could be considered from the stochastic point of view or this related with a non-homogeneous but periodical of plasma spatial structure. In this work using the Bogoliubov average method for a multi periodical system in presence of resonances, the drift equations were obtained in presence of a RF field for the case of electron cyclotron resonance until first order terms with respect to inverse of its cyclotron frequency. The absorbed energy equation is obtained on part of electrons in a simple model and by drift method. It is showed the stochastic character of the energy absorption. (Author)

  16. Spatial distribution of charged particles along the ion-optical axis in electron cyclotron resonance ion sources. Experimental results

    Energy Technology Data Exchange (ETDEWEB)

    Panitzsch, Lauri

    2013-02-08

    The experimental determination of the spatial distribution of charged particles along the ion-optical axis in electron cyclotron resonance ion sources (ECRIS) defines the focus of this thesis. The spatial distributions of different ion species were obtained in the object plane of the bending magnet ({approx}45 cm downstream from the plasma electrode) and in the plane of the plasma electrode itself, both in high spatial resolution. The results show that each of the different ion species forms a bloated, triangular structure in the aperture of the plasma electrode. The geometry and the orientation of these structures are defined by the superposition of the radial and axial magnetic fields. The radial extent of each structure is defined by the charge of the ion. Higher charge states occupy smaller, more concentrated structures. The total current density increases towards the center of the plasma electrode. The circular and star-like structures that can be observed in the beam profiles of strongly focused, extracted ion beams are each dominated by ions of a single charge state. In addition, the spatially resolved current density distribution of charged particles in the plasma chamber that impinge on the plasma electrode was determined, differentiating between ions and electrons. The experimental results of this work show that the electrons of the plasma are strongly connected to the magnetic field lines in the source and thus spatially well confined in a triangular-like structure. The intensity of the electrons increases towards the center of the plasma electrode and the plasma chamber, as well. These electrons are surrounded by a spatially far less confined and less intense ion population. All the findings mentioned above were already predicted in parts by simulations of different groups. However, the results presented within this thesis represent the first (and by now only) direct experimental verification of those predictions and are qualitatively transferable to

  17. Electron cyclotron resonance ion source plasma characterization by X-ray spectroscopy and X-ray imaging

    Energy Technology Data Exchange (ETDEWEB)

    Mascali, David, E-mail: davidmascali@lns.infn.it; Castro, Giuseppe; Celona, Luigi; Neri, Lorenzo; Gammino, Santo [INFN–Laboratori Nazionali del Sud, Via S. Sofia 62, 95125 Catania (Italy); Biri, Sándor; Rácz, Richárd; Pálinkás, József [Institute for Nuclear Research (Atomki), Hungarian Academy of Sciences, Bem tér 18/c, H-4026 Debrecen (Hungary); Caliri, Claudia [INFN–Laboratori Nazionali del Sud, Via S. Sofia 62, 95125 Catania (Italy); Università degli Studi di Catania, Dip.to di Fisica e Astronomia, via Santa Sofia 64, 95123 Catania (Italy); Romano, Francesco Paolo [INFN–Laboratori Nazionali del Sud, Via S. Sofia 62, 95125 Catania (Italy); CNR, Istituto per i Beni Archeologici e Monumentali, Via Biblioteca 4, 95124 Catania (Italy); Torrisi, Giuseppe [INFN–Laboratori Nazionali del Sud, Via S. Sofia 62, 95125 Catania (Italy); Università Mediterranea di Reggio Calabria, DIIES, Via Graziella, I-89100 Reggio Calabria (Italy)

    2016-02-15

    An experimental campaign aiming to investigate electron cyclotron resonance (ECR) plasma X-ray emission has been recently carried out at the ECRISs—Electron Cyclotron Resonance Ion Sources laboratory of Atomki based on a collaboration between the Debrecen and Catania ECR teams. In a first series, the X-ray spectroscopy was performed through silicon drift detectors and high purity germanium detectors, characterizing the volumetric plasma emission. The on-purpose developed collimation system was suitable for direct plasma density evaluation, performed “on-line” during beam extraction and charge state distribution characterization. A campaign for correlating the plasma density and temperature with the output charge states and the beam intensity for different pumping wave frequencies, different magnetic field profiles, and single-gas/gas-mixing configurations was carried out. The results reveal a surprisingly very good agreement between warm-electron density fluctuations, output beam currents, and the calculated electromagnetic modal density of the plasma chamber. A charge-coupled device camera coupled to a small pin-hole allowing X-ray imaging was installed and numerous X-ray photos were taken in order to study the peculiarities of the ECRIS plasma structure.

  18. Observation of free electron cyclotron resonance in NaAlSi3O8 feldspar: Direct determination of the effective electron mass

    DEFF Research Database (Denmark)

    Poolton, N.R.J.; Nicholis, J.E.; Bøtter-Jensen, L.

    2001-01-01

    We report the first observation of cyclotron resonances in alkali feldspars, using highly sensitive optical detection methods. In Na-feldspar (NaAlSi3O8). a near isotropic effective electron mass value of m(c)(*) = 0.79m, has been determined. The significance of this measurement in terms of the o......We report the first observation of cyclotron resonances in alkali feldspars, using highly sensitive optical detection methods. In Na-feldspar (NaAlSi3O8). a near isotropic effective electron mass value of m(c)(*) = 0.79m, has been determined. The significance of this measurement in terms...

  19. The investigation of the bio-oil produced by hydrothermal liquefaction of Spirulina platensis using ultrahigh resolution Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Kostyukevich, Yury; Vlaskin, Mikhail; Vladimirov, Gleb; Zherebker, Alexander; Kononikhin, Alexey; Popov, Igor; Nikolaev, Eugene

    2017-04-01

    We report the investigation of the hydrothermal liquefaction products of the Spirulina platensis microalgae by using the Fourier transform ion cyclotron resonance mass spectrometry. The hydrothermal liquefaction produced two fractions: one with boiling temperature below 300℃ and the dense residue that remained in the reactor. It was observed that N 2 and N classes of compounds that dominate in the positive ESI Fourier transform ion cyclotron resonance spectra for both fractions, and that the light fraction is considerably more saturated then the heavy one. The performed hydrogen/deuterium exchange reaction indicated the presence of the onium compounds in the bio-oil.

  20. Probing regA/RNA interactions using electrospray ionization-Fourier transform ion cyclotron resonance-mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Liu, C.; Tolic, L.P.; Hofstadler, S.A.; Harms, A.C.; Smith, R.D. [Pacific Northwest National Lab., Richland, WA (United States). Environmental Molecular Sciences Lab.; Kang, C.H. [Washington State Univ., Pullman, WA (United States). Dept. of Biochemistry and Biophysics; Sinha, N. [Boston Biosystems, Inc., Bedford, MA (United States)

    1998-08-15

    The interactions of bacteriophage T4 regA protein, a unique translational regulator, with RNAs of various size and sequence were studied using electrospray ionization-Fourier transform ion cyclotron resonance-mass spectrometry. Using very gentle interface conditions, regA/RNA complexes with a 1:1 binding stoichiometry were observed for all four target RNAs studied, consistent with solution binding studies. Competitive binding of target RNAs and their degradation products with regA demonstrated that the loss of a single nucleotide resulted in a dramatic change in binding affinity in some cases. Competitive binding of regA with four target RNAs revealed similar relative binding affinity order to that suggested by previous in vitro repression experiments. The use of sustained off-resonance irradiation for collisionally induced dissociation of a regA/RNA complex suggested the potential for directly obtaining information regarding the regA binding domain.

  1. Twelve million resolving power on 4.7 T Fourier transform ion cyclotron resonance instrument with dynamically harmonized cell--observation of fine structure in peptide mass spectra.

    Science.gov (United States)

    Popov, Igor A; Nagornov, Konstantin; Vladimirov, Gleb N; Kostyukevich, Yury I; Nikolaev, Eugene N

    2014-05-01

    Resolving power of about 12,000 000 at m/z 675 has been achieved on low field homogeneity 4.7 T magnet using a dynamically harmonized Fourier transform ion cyclotron resonance (FT ICR) cell. Mass spectra of the fine structure of the isotopic distribution of a peptide were obtained and strong discrimination of small intensity peaks was observed in case of resonance excitation of the ions of the whole isotopic cluster to the same cyclotron radius. The absence of some peaks from the mass spectra of the fine structure was explained basing on results of computer simulations showing strong ion cloud interactions, which cause the coalescence of peaks with m/z close to that of the highest magnitude peak. The way to prevent peak discrimination is to excite ion clouds of different m/z to different cyclotron radii, which was demonstrated and investigated both experimentally and by computer simulations.

  2. Trapping, detection, and mass measurement of individual ions in a Fourier transform ion cyclotron resonance mass spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    Bruce, J.E.; Cheng, X.; Bakhtiar, R.; Wu, Q.; Hofstadler, S.A.; Anderson, G.A.; Smith, R.D. [Pacific Northwest Lab., Richland, WA (United States)

    1994-08-24

    A fourier transform ion cyclotron resonance (FTICR) mass spectrometer has been used to trap individual multiply charged ions of several high molecular weight polymers, including poly(ethylene oxide), sodium poly(styrene sulfonate), and the protein bovine serum albumin. Detection of these ions is performed with the nondestructive method distinctive of FTICR, which also allows remeasurement of the same ion or ion population over several hours. For the determination of the charge states (and hence the masses) of individual ions, a new scheme was developed on the basis of the observation of the stepwise m/z shifts that results from charge exchange reactions or adduction of a substance of known mass. A novel technique for mass determination of individual ions has been made possible with the observation of cyclotron frequency shifts during the time-domain acquisition period. This time-resolved ion correlation (TRIC) technique allows reactant and product ions to be correlated with confidence and provides the basis for simultaneously studying a moderate number of ions. In this work, a range of observations related to the detection and measurement of individual ions is presented, as are examples of mass determinations of individual ions performed by utilizing the TRIC technique. 47 refs., 9 figs., 2 tabs.

  3. Screening and confirmation criteria for hormone residue analysis using liquid chromatography accurate mass time-of-flight, Fourier transform ion cyclotron resonance and orbitrap mass spectrometry techniques

    NARCIS (Netherlands)

    Nielen, M.W.F.; Engelen, M.C. van; Zuiderent, R.; Ramaker, R.

    2007-01-01

    An emerging trend is recognised in hormone and veterinary drug residue analysis from liquid chromatography tandem mass spectrometry (LC/MS/MS) based screening and confirmation towards accurate mass alternatives such as LC coupled with time-of-flight (TOF), Fourier transform ion cyclotron resonance

  4. Optimizing C4+ and C5+ beams of the Kei2 electron cyclotron resonance ion source using a special gas-mixing technique

    NARCIS (Netherlands)

    Drentje, A. G.; Muramatsu, M.; Kitagawa, A.

    With the prototype electron cyclotron resonance ion source for the next carbon therapy facility in Japan a series of measurements has been performed in order (a) to find the best condition for producing high beam currents of C4+ ions, and (b) to study the effect of "special" gas mixing by using a

  5. An ICR study of ion-molecule reactions of PH(n)+ ions. [of importance to interstellar chemistry, using ion cyclotron resonance techniques

    Science.gov (United States)

    Thorne, L. R.; Anicich, V. G.; Huntress, W. T.

    1983-01-01

    The reactions of PH(n)+ ions (n = 0-3) were examined with a number of neutrals using ion-cyclotron-resonance techniques. The reactions examined have significance for the distribution of phosphorus in interstellar molecules. The results indicate that interstellar molecules containing the P-O bond are likely to be more abundant than those containing the P-H bond.

  6. Synthesis of carboxylated styrene polymer for internal calibration of Fourier transform ion cyclotron resonance mass-spectrometry of humic substances.

    Science.gov (United States)

    Zherebker, Alexander; Turkova, Alexandra V; Kostyukevich, Yury; Kononikhin, Alexey; Zaitsev, Kirill V; Popov, Igor A; Nikolaev, Eugene; Perminova, Irina V

    2017-08-01

    We report synthesis and application of the novel carboxylated styrene for internal calibration of Fourier transform ion cyclotron resonance mass-spectra of humic substances. The calibrant was synthesized in five steps from acetylsalicylic acid (aspirin) followed by spontaneous polymerization of vinyl salicylic acid. Aromatic nature of the prepared polymer enabled its simultaneous analysis in the presence of the Suwannee River fulvic acid without using dual-spray approach. The major advantage of the calibrant proposed in this study is a lack of suppression of humic substances signals and maintenance of peak intensity distribution. The appropriate calibration resulted in an increased number of unambiguous identification in Suwannee River fulvic acid. Thanks to the higher mass accuracy, it was also possible to refine attribution of the CHOS species to hydrolysable tannins as opposed to the erroneous previous assignment to the condensed tannins.

  7. Investigation of the ozonation products of natural complex mixtures using Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Kostyukevich, Yury; Stavitskaya, Anna; Zherebker, Alexander; Konstantinova, Marina; Vlaskin, Mikhail; Borisova, Ludmila; Kononikhin, Alexey; Popov, Igor; Nikolaev, Eugene

    2017-08-01

    Natural complex mixtures such as oil and dissolved organic matter play an important role in the economy and in the global carbon cycle. One of the most promising approaches for the investigation of the chemical structure of such substances is the combination of the high-resolution mass spectrometry and selective chemical reactions. Here, we report the investigation of the ozonation products of natural complex mixtures using Fourier transform ion cyclotron resonance mass spectrometry. Ozonation of crude oil results in the appearance of the new compounds with high content (up to 9 atom) of oxygen. Isotopic exchange reaction showed that those oxygen stem from the carbonyl groups. Ozonation of the dissolved organic matter leads to the destruction of the substance and shift towards the region of the saturated compounds.

  8. Three-dimensional simulations of ion dynamics in the plasma of an electron cyclotron resonance ion source

    Directory of Open Access Journals (Sweden)

    V. Mironov

    2009-07-01

    Full Text Available The ion production in an electron cyclotron resonance ion source (ECRIS is modeled using a particle-in-cell Monte-Carlo-collision code in a three-dimensional geometry. Only the heavy particles (ions and atoms are tracked, while the electrons are represented using a Maxwell-Boltzmann energy distribution with the electron density determined from the requirement of quasineutrality, and the electron temperature considered as a free parameter. It is found that experimentally observed features of ECRIS plasma are closely reproduced by the code, including the charge-state distributions of extracted ion beams and sputtering patterns inside the source. The isotope anomaly is observed for the mixture of ^{20}Ne+^{22}Ne isotopes, and a possible explanation is proposed. Finally, the wall-coating effect is treated by modeling the neutralization of ions impinging on the walls of the plasma chamber.

  9. Edge characteristics and global confinement of electron cyclotron resonance heated plasmas in the TJ-II Stellarator

    Energy Technology Data Exchange (ETDEWEB)

    Tabares, F.L.; Branas, B.; Garcia-Cortes, I.; Tafalla, D.; Estrada, T.; Tribaldos, V. [Laboratorio Nacional de Fusion por Confinamiento Magnetico, Asociacion EURATOM/CIEMAT, Madrid (Spain)

    2001-08-01

    The edge parameters of electron cyclotron resonance heated plasmas in the TJ-II stellarator are reported. Data from atomic beam diagnostics and electrical probes have been used for edge and scrape-off layer characterization. Scans in heating power and plasma density for H and He plasmas have been performed, for a given magnetic configuration. A linear increase of the diffusion coefficient at the last-closed magnetic surface with the ratio of injected power to plasma density and a similar value of that parameter for the two atomic species investigated were obtained. Global particle confinement times between 3 and 15 ms have been deduced, and transition to an enhanced confinement mode in H plasmas has been observed under some conditions. The role of high-energy particle losses, due to trapping into the relatively high magnetic ripple, in the global energy balance of TJ-II plasmas is addressed. (author)

  10. Studies of the beam extraction system of the GTS-LHC electron cyclotron resonance ion source at CERN.

    Science.gov (United States)

    Toivanen, V; Küchler, D

    2016-02-01

    The 14.5 GHz GTS-LHC Electron Cyclotron Resonance Ion Source (ECRIS) provides multiply charged heavy ion beams for the CERN experimental program. The GTS-LHC beam formation has been studied extensively with lead, argon, and xenon beams with varied beam extraction conditions using the ion optical code IBSimu. The simulation model predicts self-consistently the formation of triangular and hollow beam structures which are often associated with ECRIS ion beams, as well as beam loss patterns which match the observed beam induced markings in the extraction region. These studies provide a better understanding of the properties of the extracted beams and a way to diagnose the extraction system performance and limitations, which is otherwise challenging due to the lack of direct diagnostics in this region and the limited availability of the ion source for development work.

  11. A multi-sample changer coupled to an electron cyclotron resonance source for accelerator mass spectrometry experiments.

    Science.gov (United States)

    Vondrasek, R; Palchan, T; Pardo, R; Peters, C; Power, M; Scott, R

    2014-02-01

    A new multi-sample changer has been constructed allowing rapid changes between samples. The sample changer has 20 positions and is capable of moving between samples in 1 min. The sample changer is part of a project using Accelerator Mass Spectrometry (AMS) at the Argonne Tandem Linac Accelerator System (ATLAS) facility to measure neutron capture rates on a wide range of actinides in a reactor environment. This project will require the measurement of a large number of samples previously irradiated in the Advanced Test Reactor at Idaho National Laboratory. The AMS technique at ATLAS is based on production of highly charged positive ions in an electron cyclotron resonance ion source followed by acceleration in the ATLAS linac. The sample material is introduced into the plasma via laser ablation chosen to limit the dependency of material feed rates upon the source material composition as well as minimize cross-talk between samples.

  12. The effect of gas mixing and biased disc voltage on the preglow transient of electron cyclotron resonance ion source.

    Science.gov (United States)

    Tarvainen, O; Toivanen, V; Komppula, J; Kalvas, T; Koivisto, H

    2012-02-01

    The effect of gas mixing and biased disc voltage on the preglow of electron cyclotron resonance ion source plasma has been studied with the AECR-U type 14 GHz ion source. It was found that gas mixing has a significant effect on the preglow. The extracted transient beam currents and efficiency of the heavier species increase, while the currents and efficiency of the lighter species decrease when gas mixing is applied. The effect of the biased disc was found to be pronounced in continuous operation mode in comparison to preglow. The data provide information on the time scales of the plasma processes explaining the effects of gas mixing and biased disc. The results also have implications on production of radioactive ion beams in preglow mode for the proposed Beta Beam neutrino factory.

  13. Superconducting magnet performance for 28 GHz electron cyclotron resonance ion source developed at the Korea Basic Science Institute.

    Science.gov (United States)

    Park, Jin Yong; Choi, Seyong; Lee, Byoung-Seob; Yoon, Jang-Hee; Ok, Jung-Woo; Kim, Byoung Chul; Shin, Chang Seouk; Ahn, Jung Keun; Won, Mi-Sook

    2014-02-01

    A superconducting magnet for use in an electron cyclotron resonance ion source was developed at the Korea Basic Science Institute. The superconducting magnet is comprised of three solenoids and a hexapole magnet. According to the design value, the solenoid magnets can generate a mirror field, resulting in axial magnetic fields of 3.6 T at the injection area and 2.2 T at the extraction region. A radial field strength of 2.1 T can also be achieved by hexapole magnet on the plasma chamber wall. NbTi superconducting wire was used in the winding process following appropriate techniques for magnet structure. The final assembly of the each magnet involved it being vertically inserted into the cryostat to cool down the temperature using liquid helium. The performance of each solenoid and hexapole magnet was separately verified experimentally. The construction of the superconducting coil, the entire magnet assembly for performance testing and experimental results are reported herein.

  14. Fabrication of an optimized hexapole magnet for a 14.5 GHz electron cyclotron resonance ion source.

    Science.gov (United States)

    Oh, Byung-Hoon; Seo, Chang Seog; In, Sang-Ryul; Kim, Tae-Seong

    2010-02-01

    A hexapole magnet for a 14.5 GHz electron cyclotron resonance (ECR) ion source, where the maximum radial field on the wall of the plasma chamber is higher than 1.1 T, has been designed and fabricated. The size of the outer diameter and the number of the sector of the hexapole are optimized for a 14.5 GHz ECR ion source with the help of a three-dimensional field calculation code. Moreover, to make a strong and long-life magnet against the demagnetic field on the hexapole multilayered structure in radial and axial directions is considered in the design. The distributions of the demagnetic fields are estimated by the calculation of the radial field in a hexapole magnet and the axial field from the solenoid coils. Proper grades of magnetic materials depending on the strength of the demagnetic field are applied for the different layers. The magnetic fields of the measured and calculated ones have been compared.

  15. Resonant infrared pulsed laser deposition of thin biodegradable polymer films

    DEFF Research Database (Denmark)

    Bubb, D.M.; Toftmann, B.; Haglund Jr., R.F.

    2002-01-01

    Thin films of the biodegradable polymer poly(DL-lactide-co-glycolide) (PLGA) were deposited using resonant infrared pulsed laser deposition (RIR-PLD). The output of a free-electron laser was focused onto a solid target of the polymer, and the films were deposited using 2.90 (resonant with O...... absorbance spectrum of the films is nearly identical with that of the native polymer, the average molecular weight of the films is a little less than half that of the starting material. Potential strategies for defeating this mass change are discussed....

  16. Performance evaluation of a dual linear ion trap-Fourier transform ion cyclotron resonance mass spectrometer for proteomics research.

    Science.gov (United States)

    Weisbrod, Chad R; Hoopmann, Michael R; Senko, Michael W; Bruce, James E

    2013-08-02

    A novel dual cell linear ion trap Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS) and its performance characteristics are reported. A linear ion trap-Fourier transform ion cyclotron resonance mass spectrometer has been modified to incorporate a LTQ-Velos mass spectrometer. This modified instrument features efficient ion accumulation and fast MS/MS acquisition capabilities of dual cell linear RF ion trap instruments coupled to the high mass accuracy, resolution, and dynamic range of a FT-ICR for improved proteomic coverage. The ion accumulation efficiency is demonstrated to be an order of magnitude greater than that observed with LTQ-FT Ultra instrumentation. The proteome coverage with yeast was shown to increase over the previous instrument generation by 50% (100% increase on the peptide level). In addition, many lower abundance level yeast proteins were only detected with this modified instrument. This novel configuration also enables beam type CID fragmentation using a dual cell RF ion trap mass spectrometer. This technique involves accelerating ions between traps while applying an elevated DC offset to one of the traps to accelerate ions and induce fragmentation. This instrument design may serve as a useful option for labs currently considering purchasing new instrumentation or upgrading existing instruments. A novel hybrid mass spectrometer that allows increased MS/MS acquisition rates with high mass measurement accuracy and new ion fragmentation methods greatly improves the number of proteins, posttranslational modifications and protein-protein interactions that can be identified from cells. Copyright © 2013 Elsevier B.V. All rights reserved.

  17. Possible Detection of an Emission Cyclotron Resonance Scattering Feature from the Accretion-Powered Pulsar 4U 1626-67

    Science.gov (United States)

    Iwakiri, W. B.; Terada, Y.; Tashiro, M. S.; Mihara, T.; Angelini, L.; Yamada, S.; Enoto, T.; Makishima, K.; Nakajima, M.; Yoshida, A.

    2012-01-01

    We present analysis of 4U 1626-67, a 7.7 s pulsar in a low-mass X-ray binary system, observed with the hard X-ray detector of the Japanese X-ray satellite Suzaku in 2006 March for a net exposure of 88 ks. The source was detected at an average 10-60 keY flux of approx 4 x 10-10 erg / sq cm/ s. The phase-averaged spectrum is reproduced well by combining a negative and positive power-law times exponential cutoff (NPEX) model modified at approx 37 keY by a cyclotron resonance scattering feature (CRSF). The phase-resolved analysis shows that the spectra at the bright phases are well fit by the NPEX with CRSF model. On the other hand. the spectrum in the dim phase lacks the NPEX high-energy cutoff component, and the CRSF can be reproduced by either an emission or an absorption profile. When fitting the dim phase spectrum with the NPEX plus Gaussian model. we find that the feature is better described in terms of an emission rather than an absorption profile. The statistical significance of this result, evaluated by means of an F test, is between 2.91 x 10(exp -3) and 1.53 x 10(exp -5), taking into account the systematic errors in the background evaluation of HXD-PIN. We find that the emission profile is more feasible than the absorption one for comparing the physical parameters in other phases. Therefore, we have possibly detected an emission line at the cyclotron resonance energy in the dim phase.

  18. Note: Optimized circuit for excitation and detection with one pair of electrodes for improved Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Chen, T; Beu, S C; Kaiser, N K; Hendrickson, C L

    2014-06-01

    A conventional Fourier transform-Ion Cyclotron Resonance (ICR) detection cell is azimuthally divided into four equal sections. One pair of opposed electrodes is used for ion cyclotron excitation, and the other pair for ion image charge detection. In this work, we demonstrate that an appropriate electrical circuit facilitates excitation and detection on one pair of opposed electrodes. The new scheme can be used to minimize the number of electrically independent ICR cell electrodes and/or improve the electrode geometry for simultaneously increased ICR signal magnitude and optimal post-excitation radius, which results in higher signal-to-noise ratio and decreased space-charge effects.

  19. Low magnetic field cooling of lepton plasmas via cyclotron-cavity resonance

    Science.gov (United States)

    Hunter, E. D.; Evetts, N.; Fajans, J.; Hardy, W. N.; Landsberger, H.; Mcpeters, R.; Wurtele, J. S.

    2018-01-01

    Pure electron or pure positron plasmas held in magnetic fields B radiate energy because of the cyclotron motion of the plasma particles; nominally, the plasmas should cool to the often cryogenic temperatures of the trap in which they are confined. However, the cyclotron cooling rate for leptons is (1/4 s)(B/1 T)2, and significant cooling is not normally observed unless B ≳ 1 T . Cooling to the trap temperatures of ˜10 K is particularly difficult to attain. Here, we show that dramatically higher cooling rates (×100) and lower temperatures (÷1000) can be obtained if the plasmas are held in electromagnetic cavities rather than in effectively free space conditions. We find that plasmas with up to 107 particles can be cooled in fields close to 0.15 T, much lower than 1 T commonly thought to be necessary to obtain plasma cooling. Appropriate cavities can be constructed with only minor modifications to the standard Penning-Malmberg trap structures.

  20. Beyond Naphthenic Acids: Environmental Screening of Water from Natural Sources and the Athabasca Oil Sands Industry Using Atmospheric Pressure Photoionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry.

    Science.gov (United States)

    Barrow, Mark P; Peru, Kerry M; Fahlman, Brian; Hewitt, L Mark; Frank, Richard A; Headley, John V

    2015-09-01

    There is a growing need for environmental screening of natural waters in the Athabasca region of Alberta, Canada, particularly in the differentiation between anthropogenic and naturally-derived organic compounds associated with weathered bitumen deposits. Previous research has focused primarily upon characterization of naphthenic acids in water samples by negative-ion electrospray ionization methods. Atmospheric pressure photoionization is a much less widely used ionization method, but one that affords the possibility of observing low polarity compounds that cannot be readily observed by electrospray ionization. This study describes the first usage of atmospheric pressure photoionization Fourier transform ion cyclotron resonance mass spectrometry (in both positive-ion and negative-ion modes) to characterize and compare extracts of oil sands process water, river water, and groundwater samples from areas associated with oil sands mining activities. When comparing mass spectra previously obtained by electrospray ionization and data acquired by atmospheric pressure photoionization, there can be a doubling of the number of components detected. In addition to polar compounds that have previously been observed, low-polarity, sulfur-containing compounds and hydrocarbons that do not incorporate a heteroatom were detected. These latter components, which are not amenable to electrospray ionization, have potential for screening efforts within monitoring programs of the oil sands.

  1. Surface treatment of a-axis EuBa2Cu3O7 - y thin films by an electron cyclotron resonance ion beam

    Science.gov (United States)

    Asano, H.; Asahi, M.; Kimachi, Y.

    1993-07-01

    An electron cyclotron resonance (ECR) ion beam has been utilized for a developing surface cleaning process of high-Tc superconducting thin films. By means of silver-contact resistivity measurements, and ex situ surface analysis using x-ray photoelectron spectroscopy (XPS) and reflection high-energy electron diffraction (RHEED), the effects of ECR treatment on an air-exposed surface of a-axis EuBa2Cu3O7-y (EBCO) films are examined. Ag/EBCO contacts are made with exposure of the EBCO surface to an ECR oxygen ion beam with ion current densities of 100 μA/cm2 at room temperature for about 30 min and the in situ deposition of silver. The contacts, which are not annealed in oxygen, exhibit low contact resistivity in the 10-8-10-7 Ω cm2 range. These values are about five orders of magnitude lower than those of samples fabricated without ECR treatment. Based on XPS and RHEED data, change in the EBCO surface caused by ECR treatment is surmised.

  2. UV laser ablation of GdCa4O(BO3)3 (GdCOB) investigated by Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Chéty-Gimondo, Rachel; Aubriet, Frédéric; Millon, Eric; Muller, J-F

    2004-01-01

    The ions generated by laser ablation (LA) of calcium and gadolinium oxoborate GdCa4O(BO3)3 (GdCOB) were investigated by Fourier transform ion cyclotron resonance mass spectrometry (FTICRMS), a powerful tool for the characterization of ionic species produced by laser interaction with solid material. In order to better understand the matter transfer and the mechanism of thin film growth by pulsed-laser deposition (PLD), cationic and anionic clusters generated by UV laser ablation of GdCOB bulk material were studied. Laser ablation of GdCOB leads to the formation of various cluster ions which result from association of CaO, BO and B2O3 building blocks (BB) with different charge carriers (CC): H+, BO+, GdO+ in positive ion mode, and BO2-, OK-, OH-, Cl-, WO3- in negative ion mode. LA-FTICRMS investigations allow us to assign a valence state to each metallic atom included in each BB. A +II chemical state may be associated with calcium and +II and +III ones to boron. UV laser ablation of GdCOB therefore induces reduction processes of boron species in the gas phase. The oxygen reactive atmosphere used during PLD experiments allows the growth of stoichiometric thin films by fixation of oxygen on the ablated species. 2004 John Wiley & Sons, Ltd.

  3. Beam experiments with the Grenoble test electron cyclotron resonance ion source at iThemba LABS.

    Science.gov (United States)

    Thomae, R; Conradie, J; Fourie, D; Mira, J; Nemulodi, F; Kuechler, D; Toivanen, V

    2016-02-01

    At iThemba Laboratory for Accelerator Based Sciences (iThemba LABS) an electron cyclotron ion source was installed and commissioned. This source is a copy of the Grenoble Test Source (GTS) for the production of highly charged ions. The source is similar to the GTS-LHC at CERN and named GTS2. A collaboration between the Accelerators and Beam Physics Group of CERN and the Accelerator and Engineering Department of iThemba LABS was proposed in which the development of high intensity argon and xenon beams is envisaged. In this paper, we present beam experiments with the GTS2 at iThemba LABS, in which the results of continuous wave and afterglow operation of xenon ion beams with oxygen as supporting gases are presented.

  4. Modeling of electron cyclotron resonance acceleration in a stationary inhomogeneous magnetic field

    Directory of Open Access Journals (Sweden)

    Valeri D. Dougar-Jabon

    2008-04-01

    Full Text Available In this paper, the cyclotron autoresonance acceleration of electrons in a stationary inhomogeneous magnetic field is studied. The trajectory and energy of electrons are found through a numerical solution of the relativistic Newton-Lorentz equation by a finite difference method. The electrons move along a TE_{112} cylinder cavity in a steady-state magnetic field whose axis coincides with the cavity axis. The magnetic field profile is such that it keeps the phase difference between the electric microwave field and the electron velocity vector within the acceleration phase band. The microwaves amplitude of 6  kV/cm is used for numerical calculations. It is shown that an electron with an initial longitudinal energy of 8 keV can be accelerated up to 260 keV by 2.45 GHz microwaves at a distance of 17 cm.

  5. The preliminary tests of the superconducting electron cyclotron resonance ion source DECRIS-SC2.

    Science.gov (United States)

    Efremov, A; Bekhterev, V; Bogomolov, S; Drobin, V; Loginov, V; Lebedev, A; Yazvitsky, N; Yakovlev, B

    2012-02-01

    A new compact version of the "liquid He-free" superconducting ECR ion source, to be used as an injector of highly charged heavy ions for the MC-400 cyclotron, is designed and built at the Flerov Laboratory of Nuclear Reactions in collaboration with the Laboratory of High Energy Physics of JINR. The axial magnetic field of the source is created by the superconducting magnet and the NdFeB hexapole is used for the radial plasma confinement. The microwave frequency of 14 GHz is used for ECR plasma heating. During the first tests, the source shows a good enough performance for the production of medium charge state ions. In this paper, we will present the design parameters and the preliminary results with gaseous ions.

  6. Beam experiments with the Grenoble test electron cyclotron resonance ion source at iThemba LABS

    Energy Technology Data Exchange (ETDEWEB)

    Thomae, R., E-mail: rthomae@tlabs.ac.za; Conradie, J.; Fourie, D.; Mira, J.; Nemulodi, F. [iThemba LABS, P.O. Box 722, Somerset West 7130 (South Africa); Kuechler, D.; Toivanen, V. [CERN, BE/ABP/HSL, 1211 Geneva 23 (Switzerland)

    2016-02-15

    At iThemba Laboratory for Accelerator Based Sciences (iThemba LABS) an electron cyclotron ion source was installed and commissioned. This source is a copy of the Grenoble Test Source (GTS) for the production of highly charged ions. The source is similar to the GTS-LHC at CERN and named GTS2. A collaboration between the Accelerators and Beam Physics Group of CERN and the Accelerator and Engineering Department of iThemba LABS was proposed in which the development of high intensity argon and xenon beams is envisaged. In this paper, we present beam experiments with the GTS2 at iThemba LABS, in which the results of continuous wave and afterglow operation of xenon ion beams with oxygen as supporting gases are presented.

  7. Recent advances in physics and technology of ion cyclotron resonance heating in view of future fusion reactors

    Science.gov (United States)

    Ongena, J.; Messiaen, A.; Kazakov, Ye O.; Koch, R.; Ragona, R.; Bobkov, V.; Crombé, K.; Durodié, F.; Goniche, M.; Krivska, A.; Lerche, E.; Louche, F.; Lyssoivan, A.; Vervier, M.; Van Eester, D.; Van Schoor, M.; Wauters, T.; Wright, J.; Wukitch, S.

    2017-05-01

    Ion temperatures of over 100 million degrees need to be reached in future fusion reactors for the deuterium-tritium fusion reaction to work. Ion cyclotron resonance heating (ICRH) is a method that has the capability to directly heat ions to such high temperatures, via a resonant interaction between the plasma ions and radiofrequency waves launched in the plasma. This paper gives an overview of recent developments in this field. In particular a novel and recently developed three-ion heating scenario will be highlighted. It is a flexible scheme with the potential to accelerate heavy ions to high energies in high density plasmas as expected for future fusion reactors. New antenna designs will be needed for next step large future devices like DEMO, to deliver steady-state high power levels, cope with fast variations in coupling due to fast changes in the edge density and to reduce the possibility for impurity production. Such a new design is the traveling wave antenna (TWA) consisting of an array of straps distributed around the circumference of the machine, which is intrinsically resilient to edge density variations and has an optimized power coupling to the plasma. The structure of the paper is as follows: to provide the general reader with a basis for a good understanding of the later sections, an overview is given of wave propagation, coupling and RF power absorption in the ion cyclotron range of frequencies, including a brief summary of the traditionally used heating scenarios. A special highlight is the newly developed three-ion scenario together with its promising applications. A next section discusses recent developments to study edge-wave interaction and reduce impurity influx from ICRH: the dedicated devices IShTAR and Aline, field aligned and three-strap antenna concepts. The principles behind and the use of ICRH as an important option for first wall conditioning in devices with a permanent magnetic field is discussed next. The final section presents ongoing

  8. Metabolic profile of Kudiezi injection in rats by UHPLC coupled with Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Zhang, Jingdan; Zhang, Xiaoxue; Zhao, Yangyang; Song, Aihua; Sun, Wei; Yin, Ran

    2017-11-13

    In this study, a reliable and sensitive ultra-high performance liquid chromatography coupled with fourier transform ion cyclotron resonance mass spectrometry method was developed for the systematic study of the metabolic profile of Kudiezi injection in rat plasma, bile, urine, and feces after intravenous administration of a single dose. The chromatographic separation was performed on an Agilent Eclipse Plus C18 column (4.6 mm × 50 mm, 1.8 μm) and the identification of prototype components and metabolites was achieved on a Bruker Solarix 7.0 T ultra-high resolution spectrometer in negative ion mode. Results indicated that a total of 76 constituents including 29 prototype compounds and 47 metabolites (10 phase I metabolites and 37 phase II metabolites) were tentatively identified. And the metabolic pathways of these prototype compounds including hydroxylation, dehydrogenation, glucuronidation, and sulfate conjugation. In conclusion, the developed method with high resolution and sensitivity was effective for screening and identification of prototypes and metabolites of Kudiezi injection in vivo. Moreover, these results would provide significant information for further pharmacokinetic and pharmacological research of Kudiezi injection in vivo. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. A mode converter to generate a Gaussian-like mode for injection into the VENUS electron cyclotron resonance ion source

    Energy Technology Data Exchange (ETDEWEB)

    Lyneis, C., E-mail: CMLyneis@lbl.gov; Benitez, J.; Hodgkinson, A.; Strohmeier, M.; Todd, D. [Nuclear Science Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Plaum, B. [Institut für Grenzflächenverfahrenstechnik und Plasmatechnologie (IGVP), Stuttgart (Germany); Thuillier, T. [Laboratoire de Physique Subatomique et de Cosmologie, Université Joseph Fourier Grenoble 1, CNRS/IN2P3, Institut Polytechnique de Grenoble, 53 rue des martyrs 38026 Grenoble cedex (France)

    2014-02-15

    A number of superconducting electron cyclotron resonance (ECR) ion sources use gyrotrons at either 24 or 28 GHz for ECR heating. In these systems, the microwave power is launched into the plasma using the TE{sub 01} circular waveguide mode. This is fundamentally different and may be less efficient than the typical rectangular, linearly polarized TE{sub 10} mode used for launching waves at lower frequencies. To improve the 28 GHz microwave coupling in VENUS, a TE{sub 01}-HE{sub 11} mode conversion system has been built to test launching HE{sub 11} microwave power into the plasma chamber. The HE{sub 11} mode is a quasi-Gaussian, linearly polarized mode, which should couple strongly to the plasma electrons. The mode conversion is done in two steps. First, a 0.66 m long “snake” converts the TE{sub 01} mode to the TE{sub 11} mode. Second, a corrugated circular waveguide excites the HE{sub 11} mode, which is launched directly into the plasma chamber. The design concept draws on the development of similar devices used in tokamaks and stellerators. The first tests of the new coupling system are described below.

  10. Matrix-free mass spectrometric imaging using laser desorption ionisation Fourier transform ion cyclotron resonance mass spectrometry

    Science.gov (United States)

    Goodwin, Richard J A; Pitt, Andrew R; Harrison, David; Weidt, Stefan K; Langridge-Smith, Pat R R; Barrett, Michael P; Logan Mackay, C

    2011-01-01

    Mass spectrometry imaging (MSI) is a powerful tool in metabolomics and proteomics for the spatial localization and identification of pharmaceuticals, metabolites, lipids, peptides and proteins in biological tissues. However, sample preparation remains a crucial variable in obtaining the most accurate distributions. Common washing steps used to remove salts, and solvent-based matrix application, allow analyte spreading to occur. Solvent-free matrix applications can reduce this risk, but increase the possibility of ionisation bias due to matrix adhesion to tissue sections. We report here the use of matrix-free MSI using laser desorption ionisation performed on a 12 T Fourier transform ion cyclotron resonance (FTICR) mass spectrometer. We used unprocessed tissue with no post-processing following thaw-mounting on matrix-assisted laser desorption ionisation (MALDI) indium-tin oxide (ITO) target plates. The identification and distribution of a range of phospholipids in mouse brain and kidney sections are presented and compared with previously published MALDI time-of-flight (TOF) MSI distributions. Copyright © 2011 John Wiley & Sons, Ltd. PMID:21416534

  11. Generation of high charge state metal ion beams by electron cyclotron resonance heating of vacuum arc plasma in cusp trap.

    Science.gov (United States)

    Nikolaev, A G; Savkin, K P; Oks, E M; Vizir, A V; Yushkov, G Yu; Vodopyanov, A V; Izotov, I V; Mansfeld, D A

    2012-02-01

    A method for generating high charge state heavy metal ion beams based on high power microwave heating of vacuum arc plasma confined in a magnetic trap under electron cyclotron resonance conditions has been developed. A feature of the work described here is the use of a cusp magnetic field with inherent "minimum-B" structure as the confinement geometry, as opposed to a simple mirror device as we have reported on previously. The cusp configuration has been successfully used for microwave heating of gas discharge plasma and extraction from the plasma of highly charged, high current, gaseous ion beams. Now we use the trap for heavy metal ion beam generation. Two different approaches were used for injecting the vacuum arc metal plasma into the trap--axial injection from a miniature arc source located on-axis near the microwave window, and radial injection from sources mounted radially at the midplane of the trap. Here, we describe preliminary results of heating vacuum arc plasma in a cusp magnetic trap by pulsed (400 μs) high power (up to 100 kW) microwave radiation at 37.5 GHz for the generation of highly charged heavy metal ion beams.

  12. Collision Cross Sections for 20 Protonated Amino Acids: Fourier Transform Ion Cyclotron Resonance and Ion Mobility Results

    Science.gov (United States)

    Anupriya; Jones, Chad A.; Dearden, David V.

    2016-08-01

    We report relative dephasing cross sections for the 20 biogenic protonated amino acids measured using the cross sectional areas by Fourier transform ion cyclotron resonance (CRAFTI) technique at 1.9 keV in the laboratory reference frame, as well as momentum transfer cross sections for the same ions computed from Boltzmann-weighted structures determined using molecular mechanics. Cross sections generally increase with increasing molecular weight. Cross sections for aliphatic and aromatic protonated amino acids are larger than the average trend, suggesting these side chains do not fold efficiently. Sulfur-containing protonated amino acids have smaller than average cross sections, reflecting the mass of the S atom. Protonated amino acids that can internally hydrogen-bond have smaller than average cross sections, reflecting more extensive folding. The CRAFTI measurements correlate well with results from drift ion mobility (IMS) and traveling wave ion mobility (TWIMS) spectrometric measurements; CRAFTI results correlate with IMS values approximately as well as IMS and TWIMS values from independent measurements correlate with each other. Both CRAFTI and IMS results correlate well with the computed momentum transfer cross sections, suggesting both techniques provide accurate molecular structural information. Absolute values obtained using the various methods differ significantly; in the case of CRAFTI, this may be due to errors in measurements of collision gas pressure, measurement of excitation voltage, and/or dependence of cross sections on kinetic energy.

  13. Unambiguous identification and discovery of bacterial siderophores by direct injection 21 Tesla Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Walker, Lawrence R; Tfaily, Malak M; Shaw, Jared B; Hess, Nancy J; Paša-Tolić, Ljiljana; Koppenaal, David W

    2017-01-25

    Under iron-limiting conditions, bacteria produce low molecular mass Fe(iii) binding molecules known as siderophores to sequester the Fe(iii), along with other elements, increasing their bioavailability. Siderophores are thought to influence iron cycling and biogeochemistry in both marine and terrestrial ecosystems and hence the need for rapid, confident characterization of these compounds has increased. In this study, the type of siderophores produced by two marine bacterial species, Synechococcus sp. PCC 7002 and Vibrio cyclitrophicus 1F53, were characterized by use of a newly developed 21 T Fourier Transform Ion Cyclotron Resonance Mass Spectrometer (FTICR MS) with direct injection electrospray ionization. This technique allowed for the rapid detection of synechobactins from Synechococcus sp. PCC 7002 as well as amphibactins from Vibrio cyclitrophicus 1F53 based on high mass accuracy and resolution allowing for observation of specific Fe isotopes and isotopic fine structure enabling highly confident identification of these siderophores. When combined with molecular network analysis two new amphibactins were discovered and verified by tandem MS. These results show that high-field FTICR MS is a powerful technique that will greatly improve the ability to rapidly identify and discover metal binding species in the environment.

  14. A comprehensive method for lipid profiling by liquid chromatography-ion cyclotron resonance mass spectrometry[S

    Science.gov (United States)

    Fauland, Alexander; Köfeler, Harald; Trötzmüller, Martin; Knopf, Astrid; Hartler, Jürgen; Eberl, Anita; Chitraju, Chandramohan; Lankmayr, Ernst; Spener, Friedrich

    2011-01-01

    This work aims to combine chromatographic retention, high mass resolution and accuracy, MS/MS spectra, and a package for automated identification and quantitation of lipid species in one platform for lipidomic analysis. The instrumental setup elaborated comprises reversed-phase HPLC coupled to a Fourier transform ion cyclotron resonance mass spectrometer (LTQ-FT), and Lipid Data Analyzer (LDA) software. Data analysis for lipid species quantification in this platform is based on retention time, mass resolution of 200,000, and mass accuracy below 2 ppm. In addition, automatically generated MS/MS spectra provide structural information at molecular level. This LC/MS technology allows analyzing complex biological samples in a quantitative manner as shown here paradigmatically for murine lipid droplets having a huge surplus of triacylglycerol species. Chromatographic preseparation of the bulk lipid class alleviates the problem of ion suppression of lipid species from other classes. Extension of 1D to 2D chromatography is possible, yet time consuming. The platform affords unambiguous detection of lipid species as low as 0.1‰ within major lipid classes. Taken together, a novel lipidomic LC/MS platform based on chromatographic retention, high mass resolution and accuracy, MS/MS analysis, and quantitation software enables analysis of complex samples as demonstrated for lipid droplets. PMID:21960706

  15. Capillary electrophoresis-electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry for direct analysis of cellular proteins

    Energy Technology Data Exchange (ETDEWEB)

    Hofstadler, S.A.; Gale, D.C.; Smith, R.D. [Pacific Northwest Lab., Richland, WA (United States); Swanek, F.D.; Ewing, A.G. [Pennsylvania State Univ., University Park, PA (United States)

    1995-04-15

    The combination of capillary electrophoresis (CE) with electrospray ionization (ESI) mass spectrometry has proven to be broadly applicable to a wide range of biologically important compounds. When combined with Fourier transform ion cyclotron resonance (FTICR) mass spectrometry, the combined method, in addition to high-resolution separations, affords high-resolution precision mass measurements for analytes separated from complex mixtures. Direct chemical analysis of single cells has received considerable attention in recent years; the single cell approach provides a major step toward answering important questions in the field of cellular biochemistry. In this work we present preliminary results which demonstrate the feasibility of using the CE-ESI-FTICR combination as a high-performance detection scheme for the analysis of cellular proteins acquired directly from small populations (i.e., 5-10) of intact living cells. The human erythrocyte was chosen as a model system owing to its availability, relatively homogeneous composition, and thorough documentation of contents by previous researchers. In this work we demonstrate the on-line acquisition of high-resolution mass spectra (average resolution >45 000 fwhm) of both the {alpha} and the {beta} chains of hemoglobin acquired from the injection of 10 human erythrocytes. 33 refs., 3 figs.

  16. Unambiguous identification and discovery of bacterial siderophores by direct injection 21 Tesla Fourier transform ion cyclotron resonance mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Walker, Lawrence R.; Tfaily, Malak M.; Shaw, Jared B.; Hess, Nancy J.; Pasa Tolic, Ljiljana; Koppenaal, David W.

    2017-01-01

    Under iron-limiting conditions, bacteria produce low molecular mass Fe(III) binding molecules known as siderophores to sequester the Fe(III), along with other elements, increasing their bioavailibility. Siderophores are thought to influence iron cycling and biogeochemistry in both marine and terrestrial ecosystems and hence the need for rapid, confident characterization of these compounds has increased. In this study, the type of siderophores produced by two marine bacterial species, Synechococcus sp. PCC 7002 and Vibrio cyclitrophicus 1F53, were characterized using a newly developed 21T Fourier Transform Ion Cyclotron Resonance Mass Spectrometer (FTICR MS) with direct injection electrospray ionization. This technique allowed for the rapid detection of synechobactins from Synechococcus sp. PCC 7002 as well as amphibactins from Vibrio cyclitrophicus 1F53 based on high mass accuracy and resolution allowing for observation of specific Fe isotopic peaks and fine isotopic structure enables highly confident identification of these sideropohores. When combined with molecular network analysis two new amphibactins were discovered and verified by tandem MS. These results show that high-field FTICR MS is a powerful technique that will greatly improve the ability to rapidly identify and discover metal binding species in the environment.

  17. Diagnostics of a charge breeder electron cyclotron resonance ion source helium plasma with the injection of ^{23}Na^{1+} ions

    Directory of Open Access Journals (Sweden)

    O. Tarvainen

    2016-05-01

    Full Text Available This work describes the utilization of an injected ^{23}Na^{1+} ion beam as a diagnostics of the helium plasma of a charge breeder electron cyclotron resonance ion source. The obtained data allows estimating the upper limit for the ion-ion collision mean-free path of the incident sodium ions, the lower limit of ion-ion collision frequencies for all charge states of the sodium ions and the lower limit of the helium plasma density. The ion-ion collision frequencies of high charge state ions are shown to be at least on the order of 1–10 MHz and the plasma density is estimated to be on the order of 10^{11}  cm^{-3} or higher. The experimental results are compared to simulations of the ^{23}Na^{1+} capture into the helium plasma. The results indicate that the lower breeding efficiency of light ions in comparison to heavier elements is probably due to different capture efficiencies in which the in-flight ionization of the incident 1+ ions plays a vital role.

  18. Effect of electron-electron interaction on cyclotron resonance in high-mobility InAs/AlSb quantum wells

    Energy Technology Data Exchange (ETDEWEB)

    Krishtopenko, S. S., E-mail: sergey.krishtopenko@mail.ru; Gavrilenko, V. I. [Institute for Physics of Microstructures, Russian Academy of Sciences, 603950 Nizhny Novgorod, GSP-105 (Russian Federation); Lobachevsky State University, 23 Prospekt Gagarina, 603950 Nizhny Novgorod (Russian Federation); Ikonnikov, A. V. [Institute for Physics of Microstructures, Russian Academy of Sciences, 603950 Nizhny Novgorod, GSP-105 (Russian Federation); Orlita, M. [Laboratoire National des Champs Magnétiques Intenses (LNCMI-G), CNRS, 25 rue des Martyrs, B.P. 166, 38042 Grenoble (France); Sadofyev, Yu. G. [P.N. Lebedev Physical Institute, Russian Academy of Sciences, Moscow 119991, GSP-1, 53 Leninskiy Prospect (Russian Federation); Goiran, M. [Laboratoire National des Champs Magnétiques Intenses (LNCMI-T), CNRS, 143 Avenue de Rangueil, 31400 Toulouse (France); Teppe, F.; Knap, W. [Laboratoire Charles Coulomb (L2C), UMR CNRS 5221, GIS-TERALAB, Universite Montpellier II, 34095 Montpellier (France)

    2015-03-21

    We report observation of electron-electron (e-e) interaction effect on cyclotron resonance (CR) in InAs/AlSb quantum well heterostructures. High mobility values allow us to observe strongly pronounced triple splitting of CR line at noninteger filling factors of Landau levels ν. At magnetic fields, corresponding to ν > 4, experimental values of CR energies are in good agreement with single-electron calculations on the basis of eight-band k ⋅ p Hamiltonian. In the range of filling factors 3 < ν < 4 pronounced, splitting of CR line, exceeding significantly the difference in single-electron CR energies, is discovered. The strength of the splitting increases when occupation of the partially filled Landau level tends to a half, being in qualitative agreement with previous prediction by MacDonald and Kallin [Phys. Rev. B 40, 5795 (1989)]. We demonstrate that such behaviour of CR modes can be quantitatively described if one takes into account both electron correlations and the mixing between conduction and valence bands in the calculations of matrix elements of e-e interaction.

  19. Upgrade of the beam extraction system of the GTS-LHC electron cyclotron resonance ion source at CERN.

    Science.gov (United States)

    Toivanen, V; Bellodi, G; Dimov, V; Küchler, D; Lombardi, A M; Maintrot, M

    2016-02-01

    Linac3 is the first accelerator in the heavy ion injector chain of the Large Hadron Collider (LHC), providing multiply charged heavy ion beams for the CERN experimental program. The ion beams are produced with GTS-LHC, a 14.5 GHz electron cyclotron resonance ion source, operated in afterglow mode. Improvement of the GTS-LHC beam formation and beam transport along Linac3 is part of the upgrade program of the injector chain in preparation for the future high luminosity LHC. A mismatch between the ion beam properties in the ion source extraction region and the acceptance of the following Low Energy Beam Transport (LEBT) section has been identified as one of the factors limiting the Linac3 performance. The installation of a new focusing element, an einzel lens, into the GTS-LHC extraction region is foreseen as a part of the Linac3 upgrade, as well as a redesign of the first section of the LEBT. Details of the upgrade and results of a beam dynamics study of the extraction region and LEBT modifications will be presented.

  20. Surface-Induced Dissociation of Protein Complexes in a Hybrid Fourier Transform Ion Cyclotron Resonance Mass Spectrometer

    Energy Technology Data Exchange (ETDEWEB)

    Yan, Jing; Zhou, Mowei; Gilbert, Joshua D.; Wolff, Jeremy J.; Somogyi, Árpád; Pedder, Randall E.; Quintyn, Royston S.; Morrison, Lindsay J.; Easterling, Michael L.; Paša-Tolić, Ljiljana; Wysocki, Vicki H.

    2017-01-03

    Mass spectrometry continues to develop as a valuable tool in the analysis of proteins and protein complexes. In protein complex mass spectrometry studies, surface-induced dissociation (SID) has been successfully applied in quadrupole time-of-flight (Q-TOF) instruments. SID provides structural information on non-covalent protein complexes that is complementary to other techniques. However, the mass resolution of Q-TOF instruments can limit the information that can be obtained for protein complexes by SID. Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) provides ultrahigh resolution and ultrahigh mass accuracy measurements. In this study, an SID device was designed and successfully installed in a hybrid FT-ICR instrument in place of the standard gas collision cell. The SID-FT-ICR platform has been tested with several protein complex systems (homooligomers, a heterooligomer, and a protein-ligand complex, ranging from 53 kDa to 85 kDa), and the results are consistent with data previously acquired on Q-TOF platforms, matching predictions from known protein interface information. SID fragments with the same m/z but different charge states are well-resolved based on distinct spacing between adjacent isotope peaks, and the addition of metal cations and ligands can also be isotopically resolved with the ultrahigh mass resolution available in FT-ICR.

  1. Effect of double frequency heating on the lead afterglow beam currents of an electron cyclotron resonance ion source

    Science.gov (United States)

    Toivanen, V.; Bellodi, G.; Küchler, D.; Wenander, F.; Tarvainen, O.

    2017-10-01

    The effect of double frequency heating on the performance of the CERN GTS-LHC 14.5 GHz Electron Cyclotron Resonance (ECR) ion source in afterglow mode is reported. The source of the secondary microwave frequency was operated both in pulsed and continuous wave (CW) modes within the range of 12-18 GHz. The results demonstrate that the addition of the secondary frequency can significantly impact the extracted beam currents and the temporal stability of the beam during the afterglow discharge. For example, up to a factor of 2.6 increase was achieved for 208Pb 35 and a factor of 3.1 for 208Pb 37+ compared to single frequency afterglow currents. It is shown that these effects are dependent on the choice of the secondary frequency with respect to the primary one and on the temporal synchronization between the two microwave sources. Overall, the results provide new insight into the afterglow discharge supporting the prevailing understanding of the physical processes behind the phenomenon.

  2. Improved optimization of the Fourier transform ion cyclotron resonance mass spectrometry phase correction function using a genetic algorithm.

    Science.gov (United States)

    Kilgour, David P A; Neal, Mark J; Soulby, Andrew J; O'Connor, Peter B

    2013-09-15

    Fourier Transform Ion Cyclotron Resonance mass spectra exhibit improved resolving power, mass accuracy and signal-to-noise ratio when presented in absorption mode; a process which requires calculation of a phase correction function. Mass spectrometric images can contain many thousands of pixels; hence methods of decreasing the time required to solve for a phase correction function will result in significant improvements in this application. A genetic algorithm approach for optimizing the phase correction function has been developed and compared with a previously described convergent iteration technique. The genetic algorithm method has been shown to offer a five-fold improvement in processing speed compared with the previous iterative approach used in the Autophaser algorithm, while maintaining the levels of accuracy. This translates to an 11 hour improvement in processing for a 20 000 pixel mass spectrometric image. The genetic algorithm method described in this manuscript offers significant processing speed advantages over the previously described convergent iteration technique. This improvement is key to allowing the future routine use of absorption mode mass spectrometric images. Copyright © 2013 John Wiley & Sons, Ltd.

  3. Carbon beam extraction with 14.5 GHz electron cyclotron resonance ion source at Korea Atomic Energy Research Institute.

    Science.gov (United States)

    Lee, Cheol Ho; Oh, Byung-Hoon; Chang, Dae-Sik; Jeong, Sun-Chan

    2014-02-01

    A 14.5 GHz Electron Cyclotron Resonance ion source (ECRIS) has been made to produce C(4+) beam for using a carbon therapy facility and recently tested at KAERI. Highly charged carbon ions have been successfully extracted. When using only CO2 gas, the beam current of C(4+) was almost 14 μA at 15 kV extraction voltage. To get higher current of the C(4+) beam, while optimizing confinement magnetic field configuration (e.g., axial strengths at minimum and extraction side), gas-mixing (CO2/He), and biased disk were introduced. When the gas mixing ratio of the CO2/He gas is 1:8 at an operational pressure of 5 × 10(-7) mbar and the disk was biased to -150 V relative to the ion source body, the highest current of the C(4+) beam was achieved to be 50 μA, more than three times higher than previously observed only with CO2 gas. Some details on the operating conditions of the ECRIS were discussed.

  4. Time evolution of endpoint energy of Bremsstrahlung spectra and ion production from an electron cyclotron resonance ion source

    Energy Technology Data Exchange (ETDEWEB)

    Tarvainen, Ollie [Los Alamos National Laboratory; Ropponen, Tommi [JYFL; Jones, Peter [JYFL; Kalvas, Taneli [JYFL

    2008-01-01

    Electron cyclotron resonance ion sources (ECRIS) are used to produce high charge state heavy ion beams for the use of nuclear and materials science, for instance. The most powerful ECR ion sources today are superconducting. One of the problems with superconducting ECR ion sources is the use of high radio frequency (RF) power which results in bremsstrahlung radiation adding an extra heat load to the cryostat. In order to understand the electron heating process and timescales in the ECR plasma, time evolution measurement of ECR bremsstrahlung was carried out. In the measurements JYFL 14 GHz ECRIS was operated in a pulsed mode and bremsstrahlung data from several hundred RF pulses was recorded. Time evolution of ion production was also studied and compared to one of the electron heating theories. To analyze the measurement data at C++ program was developed. Endpoint energies of the bremsstrahlung spectra as a function of axial magnetic field strength, pressure and RF power are presented and ion production timescales obtained from the measurements are compared to bremsstrahlung emission timescales and one of the stochastic heating theories.

  5. A mode converter to generate a Gaussian-like mode for injection into the VENUS electron cyclotron resonance ion source.

    Science.gov (United States)

    Lyneis, C; Benitez, J; Hodgkinson, A; Plaum, B; Strohmeier, M; Thuillier, T; Todd, D

    2014-02-01

    A number of superconducting electron cyclotron resonance (ECR) ion sources use gyrotrons at either 24 or 28 GHz for ECR heating. In these systems, the microwave power is launched into the plasma using the TE01 circular waveguide mode. This is fundamentally different and may be less efficient than the typical rectangular, linearly polarized TE10 mode used for launching waves at lower frequencies. To improve the 28 GHz microwave coupling in VENUS, a TE01-HE11 mode conversion system has been built to test launching HE11 microwave power into the plasma chamber. The HE11 mode is a quasi-Gaussian, linearly polarized mode, which should couple strongly to the plasma electrons. The mode conversion is done in two steps. First, a 0.66 m long "snake" converts the TE01 mode to the TE11 mode. Second, a corrugated circular waveguide excites the HE11 mode, which is launched directly into the plasma chamber. The design concept draws on the development of similar devices used in tokamaks and stellerators. The first tests of the new coupling system are described below.

  6. Pitch angle scattering of relativistic electrons near electromagnetic ion cyclotron resonances in diverging magnetic fields

    Science.gov (United States)

    Eliasson, B.; Papadopoulos, K.

    2017-10-01

    A theoretical study of the propagation of left-hand polarized shear Alfvén waves in spatially decreasing magnetic field geometries near the EMIC resonance, including the spectrum and amplitude of the mode converted EMIC waves and the pitch angle scattering of relativistic electrons transiting the resonant region, is presented. The objective of the paper is to motivate an experimental study of the subject using the UCLA LAPD chamber. The results are relevant in exploring the possibility that shear Alfvén waves strategically injected into the radiation belts using either ionospheric heating from ground based RF transmitters or injected by transmitters based on space platforms can enhance the precipitation rate of trapped relativistic electrons. Effects of multi-ionic composition are also investigated.

  7. Radioanalytical prediction of radiative capture in 99Mo production via transmutation adiabatic resonance crossing by cyclotron

    CERN Document Server

    Khorshidi, Abdollah; Pazirandeh, Ali; Tenreiro, Claudio; Kadi, Yacine

    2014-01-01

    In this study, the transmutation adiabatic resonance crossing (TARC) concept was estimated in Mo-99 radioisotope production via radiative capture reaction in two designs. The TARC method was composed of moderating neutrons in lead or a composition of lead and water. Additionally, the target was surrounded by a moderator assembly and a graphite reflector district. Produced neutrons were investigated by (p,xn) interactions with 30 MeV and 300 mu A proton beam on tungsten, beryllium, and tantalum targets. The Mo-99 production yield was related to the moderator property, cross section, and sample positioning inside the distinct region of neutron storage as must be proper to achieve gains. Gathered thermal flux of neutrons can contribute to molybdenum isotope production. Moreover, the sample positioning to gain higher production yield was dependent on a greater flux in the length of thermal neutrons and region materials inside the moderator or reflector. When the sample radial distance from Be was 38 cm inside the...

  8. Resonant infrared pulsed laser deposition of a polyimide precursor

    Energy Technology Data Exchange (ETDEWEB)

    Dygert, N L; Schriver, K E; Jr, R F Haglund [Department of Physics and Astronomy and W M Keck Foundation Free-Electron Laser Centre, Vanderbilt University, Nashville TN 37235 (United States)

    2007-04-15

    Poly(amic acid) (PAA), a precursor to polyimide, was successfully deposited on substrates without reaching curing temperature, by resonant infrared pulsed laser ablation. The PAA was prepared by dissolving pyromellitic dianhydride and 4, 4' oxidianiline in the polar solvent Nmethyl pyrrolidinone (NMP). The PAA was deposited in droplet-like morphologies when ablation occurred in air, and in string-like moieties in the case of ablation in vacuum. In the as-deposited condition, the PAA was easily removed by washing with NMP; however, once cured thermally for thirty minutes, the PAA hardened, indicating the expected thermosetting property. Plume shadowgraphy showed very clear contrasts in the ablation mechanism between ablation of the solvent alone and the ablation of the PAA, even at low concentrations. A Wavelength dependence in plume velocity was also observed.

  9. Potential of dynamically harmonized Fourier transform ion cyclotron resonance cell for high-throughput metabolomics fingerprinting: control of data quality.

    Science.gov (United States)

    Habchi, Baninia; Alves, Sandra; Jouan-Rimbaud Bouveresse, Delphine; Appenzeller, Brice; Paris, Alain; Rutledge, Douglas N; Rathahao-Paris, Estelle

    2018-01-01

    Due to the presence of pollutants in the environment and food, the assessment of human exposure is required. This necessitates high-throughput approaches enabling large-scale analysis and, as a consequence, the use of high-performance analytical instruments to obtain highly informative metabolomic profiles. In this study, direct introduction mass spectrometry (DIMS) was performed using a Fourier transform ion cyclotron resonance (FT-ICR) instrument equipped with a dynamically harmonized cell. Data quality was evaluated based on mass resolving power (RP), mass measurement accuracy, and ion intensity drifts from the repeated injections of quality control sample (QC) along the analytical process. The large DIMS data size entails the use of bioinformatic tools for the automatic selection of common ions found in all QC injections and for robustness assessment and correction of eventual technical drifts. RP values greater than 106 and mass measurement accuracy of lower than 1 ppm were obtained using broadband mode resulting in the detection of isotopic fine structure. Hence, a very accurate relative isotopic mass defect (RΔm) value was calculated. This reduces significantly the number of elemental composition (EC) candidates and greatly improves compound annotation. A very satisfactory estimate of repeatability of both peak intensity and mass measurement was demonstrated. Although, a non negligible ion intensity drift was observed for negative ion mode data, a normalization procedure was easily applied to correct this phenomenon. This study illustrates the performance and robustness of the dynamically harmonized FT-ICR cell to perform large-scale high-throughput metabolomic analyses in routine conditions. Graphical abstract Analytical performance of FT-ICR instrument equipped with a dynamically harmonized cell.

  10. Development of portable mass spectrometer with electron cyclotron resonance ion source for detection of chemical warfare agents in air.

    Science.gov (United States)

    Urabe, Tatsuya; Takahashi, Kazuya; Kitagawa, Michiko; Sato, Takafumi; Kondo, Tomohide; Enomoto, Shuichi; Kidera, Masanori; Seto, Yasuo

    2014-01-01

    A portable mass spectrometer with an electron cyclotron resonance ion source (miniECRIS-MS) was developed. It was used for in situ monitoring of trace amounts of chemical warfare agents (CWAs) in atmospheric air. Instrumental construction and parameters were optimized to realize a fast response, high sensitivity, and a small body size. Three types of CWAs, i.e., phosgene, mustard gas, and hydrogen cyanide were examined to check if the mass spectrometer was able to detect characteristic elements and atomic groups. From the results, it was found that CWAs were effectively ionized in the miniECRIS-MS, and their specific signals could be discerned over the background signals of air. In phosgene, the signals of the 35Cl+ and 37Cl+ ions were clearly observed with high dose-response relationships in the parts-per-billion level, which could lead to the quantitative on-site analysis of CWAs. A parts-per-million level of mustard gas, which was far lower than its lethal dosage (LCt50), was successfully detected with a high signal-stability of the plasma ion source. It was also found that the chemical forms of CWAs ionized in the plasma, i.e., monoatomic ions, fragment ions, and molecular ions, could be detected, thereby enabling the effective identification of the target CWAs. Despite the disadvantages associated with miniaturization, the overall performance (sensitivity and response time) of the miniECRIS-MS in detecting CWAs exceeded those of sector-type ECRIS-MS, showing its potential for on-site detection in the future. Copyright © 2013 Elsevier B.V. All rights reserved.

  11. Intense beam production of highly charged heavy ions by the superconducting electron cyclotron resonance ion source SECRAL.

    Science.gov (United States)

    Zhao, H W; Sun, L T; Zhang, X Z; Guo, X H; Cao, Y; Lu, W; Zhang, Z M; Yuan, P; Song, M T; Zhao, H Y; Jin, T; Shang, Y; Zhan, W L; Wei, B W; Xie, D Z

    2008-02-01

    There has been increasing demand to provide higher beam intensity and high enough beam energy for heavy ion accelerator and some other applications, which has driven electron cyclotron resonance (ECR) ion source to produce higher charge state ions with higher beam intensity. One of development trends for highly charged ECR ion source is to build new generation ECR sources by utilization of superconducting magnet technology. SECRAL (superconducting ECR ion source with advanced design in Lanzhou) was successfully built to produce intense beams of highly charged ion for Heavy Ion Research Facility in Lanzhou (HIRFL). The ion source has been optimized to be operated at 28 GHz for its maximum performance. The superconducting magnet confinement configuration of the ion source consists of three axial solenoid coils and six sextupole coils with a cold iron structure as field booster and clamping. An innovative design of SECRAL is that the three axial solenoid coils are located inside of the sextupole bore in order to reduce the interaction forces between the sextupole coils and the solenoid coils. For 28 GHz operation, the magnet assembly can produce peak mirror fields on axis of 3.6 T at injection, 2.2 T at extraction, and a radial sextupole field of 2.0 T at plasma chamber wall. During the commissioning phase at 18 GHz with a stainless steel chamber, tests with various gases and some metals have been conducted with microwave power less than 3.5 kW by two 18 GHz rf generators. It demonstrates the performance is very promising. Some record ion beam intensities have been produced, for instance, 810 e microA of O(7+), 505 e microA of Xe(20+), 306 e microA of Xe(27+), and so on. The effect of the magnetic field configuration on the ion source performance has been studied experimentally. SECRAL has been put into operation to provide highly charged ion beams for HIRFL facility since May 2007.

  12. Progress of superconducting electron cyclotron resonance ion sources at Institute of Modern Physics (IMP).

    Science.gov (United States)

    Sun, L; Lu, W; Feng, Y C; Zhang, W H; Zhang, X Z; Cao, Y; Zhao, Y Y; Wu, W; Yang, T J; Zhao, B; Zhao, H W; Ma, L Z; Xia, J W; Xie, D

    2014-02-01

    Superconducting ECR ion sources can produce intense highly charged ion beams for the application in heavy ion accelerators. Superconducting Electron Resonance ion source with Advanced Design (SECRAL) is one of the few fully superconducting ECR ion sources that has been successfully built and put into routine operation for years. With enormous efforts and R&D work, promising results have been achieved with the ion source. Heated by the microwave power from a 7 kW/24 GHz gyrotron microwave generator, very intense highly charged gaseous ion beams have been produced, such as 455 eμA Xe(27+), 236 eμA Xe(30+), and 64 eμA Xe(35+). Since heavy metallic ion beams are being more and more attractive and important for many accelerator projects globally, intensive studies have been made to produce highly charged heavy metal ion beams, such as those from bismuth and uranium. Recently, 420 eμA Bi(30+) and 202 eμA U(33+) have been produced with SECRAL source. This paper will present the latest results with SECRAL, and the operation status will be discussed as well. An introduction of recently started SECRAL II project will also be given in the presentation.

  13. Studies of extraction and transport system for highly charged ion beam of 18 GHz superconducting electron cyclotron resonance ion source at Research Center for Nuclear Physics.

    Science.gov (United States)

    Yorita, T; Hatanaka, K; Fukuda, M; Ueda, H; Yasuda, Y; Morinobu, S; Tamii, A; Kamakura, K

    2014-02-01

    An 18 GHz superconducting electron cyclotron resonance ion source is installed to increase beam currents and to extend the variety of ions especially for highly charged heavy ions which can be accelerated by cyclotrons of Research Center for Nuclear Physics (RCNP), Osaka University. The beam production developments of several ions from B to Xe have been already done [T. Yorita, K. Hatanaka, M. Fukuda, M. Kibayashi, S. Morinobu, H.Okamura, and A. Tamii, Rev. Sci. Instrum. 79, 02A311 (2008) and T. Yorita, K. Hatanaka, M. Fukuda, M. Kibayashi, S. Morinobu, H.Okamura, and A. Tamii, Rev. Sci. Instrum. 81, 02A332 (2010)] and the further studies for those beam extraction and its transport have been done in order to increase the beam current more. The plasma electrode, extraction electrode, and einzel lens are modified. Especially extraction electrode can be applied minus voltage for the beam extraction and it works well to improve the extracted beam current. The extraction voltage dependences of transmission and emittance also have been studied for beam current improvement which is injected into azimuthally varying field cyclotron at RCNP.

  14. Laser ablation of aluminosilicates: Comparison between allophane and mixed alumina/silicas by Fourier Transform-Ion Cyclotron Resonance-Mass Spectrometry

    Science.gov (United States)

    Castello, J.; Gaumet, J. J.; Muller, J. F.; Derousseaux, S.; Guilment, J.; Poncelet, O.

    2007-07-01

    Laser ablation coupled to Fourier Transform-Ion Cyclotron Resonance-Mass Spectrometry [FT-ICR-MS] was used for analysing allophane aluminosilicates and mixtures of Al 2O 3/SiO 2. We show that both positive and negative ionization modes in FT-ICR-MS allows direct analysis of the various Al/Si ratios in allophanes and mixed alumina/silica samples. FT-ICR-MS technique provides a routine analytical methodology providing insight into the Al/Si molar composition and the origin of any aluminosilicate materials.

  15. Two-slope soft X-ray spectra observed in experiments on electron cyclotron resonance plasma heating in the L-2M stellarator

    Science.gov (United States)

    Meshcheryakov, A. I.; Vafin, I. Yu.; Grishina, I. A.; Letunov, A. A.; Tereshchenko, M. A.

    2017-06-01

    In experiments on the generation and electron cyclotron resonance heating (ECRH) of plasma in the L-2M stellarator, non-Maxwellian two-slope soft X-ray (SXR) spectra were observed. The temperatures of the thermal and epithermal components of the spectra were measured as functions of the heating power and plasma density. A hypothesis based on the experimental results is suggested to explain the formation mechanism of two-slope SXR spectra in the ECRH experiments at the L-2M stellarator. The measured SXR spectra are compared with the results of numerical simulations.

  16. Novel molecular-level evidence of iodine binding to natural organic matter from Fourier transform ion cyclotron resonance mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Chen, E-mail: xuchen66@tamu.edu [Laboratory for Environmental and Oceanographic Research, Department of Marine Sciences, Texas A and M University, Building 3029, Galveston, TX 77551 (United States); Chen, Hongmei [Department of Chemistry and Biochemistry, Old Dominion University, Norfolk, VA 23529 (United States); Sugiyama, Yuko [Department of Chemistry and Biochemistry, Old Dominion University, Norfolk, VA 23529 (United States); University of Hyogo, 1-1-12, Shinzaike-honcho, Himeji, Hyogo 670-0092 (Japan); Zhang, Saijin; Li, Hsiu-Ping; Ho, Yi-Fang; Chuang, Chia-ying; Schwehr, Kathleen A. [Laboratory for Environmental and Oceanographic Research, Department of Marine Sciences, Texas A and M University, Building 3029, Galveston, TX 77551 (United States); Kaplan, Daniel I. [Savannah River National Laboratory, Aiken, SC 29808 (United States); Yeager, Chris [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Roberts, Kimberly A. [Savannah River National Laboratory, Aiken, SC 29808 (United States); Hatcher, Patrick G. [Department of Chemistry and Biochemistry, Old Dominion University, Norfolk, VA 23529 (United States); Santschi, Peter H. [Laboratory for Environmental and Oceanographic Research, Department of Marine Sciences, Texas A and M University, Building 3029, Galveston, TX 77551 (United States)

    2013-04-01

    Major fractions of radioiodine ({sup 129}I) are associated with natural organic matter (NOM) in the groundwater and surface soils of the Savannah River Site (SRS). Electrospray ionization coupled to Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS) was applied to elucidate the interactions between inorganic iodine species (iodide and iodate) and a fulvic acid (FA) extracted from a SRS surface soil. Iodate is likely reduced to reactive iodine species by the lignin- and tannin-like compounds or the carboxylic-rich alicyclic molecules (CRAM), during which condensed aromatics and lignin-like compounds were generated. Iodide is catalytically oxidized into reactive iodine species by peroxides, while FA is oxidized by peroxides into more aliphatic and less aromatic compounds. Only 9% of the total identified organo-iodine compounds derived from molecules originally present in the FA, whereas most were iodine binding to newly-produced compounds. The resulting iodinated molecules were distributed in three regions in the van Krevelen diagrams, denoting unsaturated hydrocarbons, lignin and protein. Moreover, characteristics of these organo-iodine compounds, such as their relatively low O/C ratios (< 0.2 or < 0.4) and yet some degree of un-saturation close to that of lignin, have multiple important environmental implications concerning possibly less sterically-hindered aromatic ring system for iodine to get access to and a lower hydrophilicity of the molecules thus to retard their migration in the natural aquatic systems. Lastly, ∼ 69% of the identified organo-iodine species contains nitrogen, which is presumably present as -NH{sub 2} or -HNCOR groups and a ring-activating functionality to favor the electrophilic substitution. The ESI-FTICR-MS technique provides novel evidence to better understand the reactivity and scavenging properties of NOM towards radioiodine and possible influence of NOM on {sup 129}I migration. Highlights: ► IO{sub 3}{sup

  17. Comprehensive characterization of natural organic matter by MALDI- and ESI-Fourier transform ion cyclotron resonance mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Dong [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Science, Chinese Academy of Sciences, P.O. Box 2871, 18 Shuangqing Road, Haidian District, Beijing 100085 (China); Huang, Huogao [Department of Endocrinology and Rheumatology, Navy General Hospital, PLA, 6 Fucheng Road, Haidian District, Beijing 100048 (China); Hu, Ming [Central Lab Navy General Hospital, PLA, 6 Fucheng Road, Haidian District, Beijing 100048 (China); Cui, Lin; Geng, Fanglan; Rao, Ziyu; Niu, Hongyun; Cai, Yaqi [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Science, Chinese Academy of Sciences, P.O. Box 2871, 18 Shuangqing Road, Haidian District, Beijing 100085 (China); Kang, Yuehui, E-mail: yhkang@rcees.ac.cn [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Science, Chinese Academy of Sciences, P.O. Box 2871, 18 Shuangqing Road, Haidian District, Beijing 100085 (China)

    2015-03-25

    Highlights: • MALDI-FT-ICR-MS was firstly employed for molecular characterization of NOM. • 1,8-Bis(dimethyl-amino)-naphthalene (DMAN) was used as matrix. • Mass spectra of NOM generated by MALDI and ESI methods were compared. • Complementary molecular information of NOM was provided by MALDI. - Abstract: Natural organic matter (NOM) is a complex and non-uniform mixture of organic compounds which plays an important role in environmental processes. Due to the complexity, it is challenging to obtain fully detailed structural information about NOM. Although Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) has been demonstrated to be a powerful tool for providing molecular information about NOM, multiple ionization methods are needed for comprehensive characterization of NOM at the molecular level considering the ionizing selectivity of different ionization methods. This paper reports the first use of matrix assisted laser desorption/ionization (MALDI) method coupled with FT-ICR-MS for molecular characterization of NOM within a mass range of 200–800 Da. The mass spectral data obtained by MALDI were systematically compared with data generated by electrospray ionization (ESI). It showed that complementary molecular information about NOM which could not be detected by ESI, were provided by MALDI. More unsaturated and aromatic constituents of NOM with lower O/C ratio (O/C ratio < 0.5) were preferentially ionized in MALDI negative mode, whereas more polar constituents of NOM with higher O/C ratio were preferentially ionized in ESI negative mode. Molecular anions of NOM appearing at even m/z in MALDI negative ion mode were detected. The results show that NOM molecules with aromatic structures, moderate O/C ratio (0.7 > O/C ratio > 0.25) and lower H/C ratio were liable to form molecular anions at even m/z, whereas those with higher H/C ratio are more likely to form deprotonated ions at odd m/z. It is speculated that almost half of the NOM

  18. Growth of etiolated barley plants in weak static and 50 Hz electromagnetic fields tuned to calcium ion cyclotron resonance

    Science.gov (United States)

    Pazur, Alexander; Rassadina, Valentina; Dandler, Jörg; Zoller, Jutta

    2006-01-01

    Background The effects of weak magnetic and electromagnetic fields in biology have been intensively studied on animals, microorganisms and humans, but comparably less on plants. Perception mechanisms were attributed originally to ferrimagnetism, but later discoveries required additional explanations like the "radical pair mechanism" and the "Ion cyclotron resonance" (ICR), primarily considered by Liboff. The latter predicts effects by small ions involved in biological processes, that occur in definite frequency- and intensity ranges ("windows") of simultaneously impacting magnetic and electromagnetic fields related by a linear equation, which meanwhile is proven by a number of in vivo and in vitro experiments. Methods Barley seedlings (Hordeum vulgare, L. var. Steffi) were grown in the dark for 5 and 6 days under static magnetic and 50 Hz electromagnetic fields matching the ICR conditions of Ca2+. Control cultures were grown under normal geomagnetic conditions, not matching this ICR. Morphology, pigmentation and long-term development of the adult plants were subsequently investigated. Results The shoots of plants exposed to Ca2+-ICR exposed grew 15–20% shorter compared to the controls, the plant weight was 10–12% lower, and they had longer coleoptiles that were adhering stronger to the primary leaf tissue. The total pigment contents of protochlorophyllide (PChlide) and carotenoids were significantly decreased. The rate of PChlide regeneration after light irradiation was reduced for the Ca2+-ICR exposed plants, also the Shibata shift was slightly delayed. Even a longer subsequent natural growing phase without any additional fields could only partially eliminate these effects: the plants initially exposed to Ca2+-ICR were still significantly shorter and had a lower chlorophyll (a+b) content compared to the controls. A continued cultivation and observation of the adult plants under natural conditions without any artificial electromagnetic fields showed a

  19. Enhanced sensitivity of surface plasmon resonance phase-interrogation biosensor by using oblique deposited silver nanorods

    OpenAIRE

    Chung, Hung-Yi; Chen, Chih-Chia; Wu, Pin Chieh; Tseng, Ming Lun; Lin, Wen-Chi; Chen, Chih-Wei; Chiang, Hai-Pang

    2014-01-01

    Sensitivity of surface plasmon resonance phase-interrogation biosensor is demonstrated to be enhanced by oblique deposited silver nanorods. Silver nanorods are thermally deposited on silver nanothin film by oblique angle deposition (OAD). The length of the nanorods can be tuned by controlling the deposition parameters of thermal deposition. By measuring the phase difference between the p and s waves of surface plasmon resonance heterodyne interferometer with different wavelength of incident l...

  20. Resonant infrared pulsed-laser deposition of a sorbent chemoselective polymer

    DEFF Research Database (Denmark)

    Bubb, D.M.; Horwitz, J.S.; McGill, R.A.

    2001-01-01

    Fluoropolyol, a sorbent chemoselective polymer, has been deposited as a thin film by resonant infrared pulsed laser deposition using a free electron laser operating at 2.90 mum, a wavelength resonant with the hydroxl stretch. A comparison of the infrared absorbance of the deposited film...

  1. Terahertz cyclotron resonance spectroscopy of an AlGaN/GaN heterostructure using a high-field pulsed magnet and an asynchronous optical sampling technique

    Energy Technology Data Exchange (ETDEWEB)

    Spencer, B. F., E-mail: Ben.Spencer@manchester.ac.uk; Smith, W. F.; Hibberd, M. T.; Dawson, P.; Graham, D. M. [School of Physics and Astronomy and the Photon Science Institute, The University of Manchester, Manchester M13 9PL (United Kingdom); Beck, M.; Bartels, A. [Laser Quantum GmbH, Max-Stromeyer-Str. 116, 78467 Konstanz (Germany); Guiney, I.; Humphreys, C. J. [Department of Materials Science and Metallurgy, 27 Charles Babbage Road, University of Cambridge, Cambridge CB3 0FS (United Kingdom)

    2016-05-23

    The effective mass, sheet carrier concentration, and mobility of electrons within a two-dimensional electron gas in an AlGaN/GaN heterostructure were determined using a laboratory-based terahertz cyclotron resonance spectrometer. The ability to perform terahertz cyclotron resonance spectroscopy with magnetic fields of up to 31 T was enabled by combining a high-field pulsed magnet with a modified asynchronous optical sampling terahertz detection scheme. This scheme allowed around 100 transmitted terahertz waveforms to be recorded over the 14 ms magnetic field pulse duration. The sheet density and mobility were measured to be 8.0 × 10{sup 12 }cm{sup −2} and 9000 cm{sup 2} V{sup −1} s{sup −1} at 77 K. The in-plane electron effective mass at the band edge was determined to be 0.228 ± 0.002m{sub 0}.

  2. Application of the laser induced fluorescence to the investigation of highly magnetized plasmas, heated by ion cyclotron resonance; Fluorescence induite par laser sur des plasmas fortement magnetises, chauffes par resonnance cyclotron ionique

    Energy Technology Data Exchange (ETDEWEB)

    Pailloux, A. [CEA Centre d`Etudes de Saclay, 91 - Gif-sur-Yvette (France). Dept. des Procedes d`Enrichissement]|[Universite Louis Pasteur, 67 - Strasbourg (France)

    1997-12-31

    This work has been achieved in the frame of isotopic separation studies by in cyclotron resonance. For this purpose, in a highly magnetized (2 to 3 Tesla) and non-collisional (10{sup 12} ions/cm{sup 3}) plasma, composed of metallic ions, a wave near the ion cyclotron frequency is thrown in order to heat selectively a given species. A laser induced fluorescence (LIP) has been developed on barium and gadolinium plasmas. The Larmor gyration of ions greatly modifies the interaction, which has been modelled through the time-dependent Schroedinger equation. The obtained excitation probably has been integrated over all the ions excited in the measurement volume in order to check that the LIF still leads to the distribution function of ion velocities. The influence of the Larmor motion of ions on the spectral distribution of LIF has been derived both theoretically and experimentally. The LIF diagnostics has been achieved with a dye O`ring laser. The barium ion has been excited on the transition 6142 angstrom, using rhodamine 6G dye, and the gadolinium ion on the pseudo-triplet 3861 angstrom, using exalite dye. Data treatment has been developed taking into account the Zeeman effect and the different heating of isotopes. The ionic temperature (from 1 eV to some hundreds eV) has been measured as a function of radiofrequency heating. Our experimental results are in good agreement with the selective heating theory. Also, the ion velocity distribution function has been found locally Maxwellian. And the behaviour of the plasma has been studied as a function of control parameters of the plasma source. (author) 62 refs.

  3. Amyloid Hydrogen Bonding Polymorphism Evaluated by (15)N{(17)O}REAPDOR Solid-State NMR and Ultra-High Resolution Fourier Transform Ion Cyclotron Resonance Mass Spectrometry.

    Science.gov (United States)

    Wei, Juan; Antzutkin, Oleg N; Filippov, Andrei V; Iuga, Dinu; Lam, Pui Yiu; Barrow, Mark P; Dupree, Ray; Brown, Steven P; O'Connor, Peter B

    2016-04-12

    A combined approach, using Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) and solid-state NMR (Nuclear Magnetic Resonance), shows a high degree of polymorphism exhibited by Aβ species in forming hydrogen-bonded networks. Two Alzheimer's Aβ peptides, Ac-Aβ(16-22)-NH2 and Aβ(11-25), selectively labeled with (17)O and (15)N at specific amino acid residues were investigated. The total amount of peptides labeled with (17)O as measured by FTICR-MS enabled the interpretation of dephasing observed in (15)N{(17)O}REAPDOR solid-state NMR experiments. Specifically, about one-third of the Aβ peptides were found to be involved in the formation of a specific >C═(17)O···H-(15)N hydrogen bond with their neighbor peptide molecules, and we hypothesize that the rest of the molecules undergo ± n off-registry shifts in their hydrogen bonding networks.

  4. A gas-jet transport and catcher technique for on-line production of radioactive ion beams using an electron cyclotron resonance ion-source

    Energy Technology Data Exchange (ETDEWEB)

    Naik, V.; Chakrabarti, A.; Bhattacharjee, M.; Karmakar, P.; Bandyopadhyay, A.; Dechoudhury, S.; Mondal, M.; Pandey, H. K.; Lavanyakumar, D.; Mandi, T. K.; Dutta, D. P.; Kundu Roy, T.; Bhowmick, D.; Sanyal, D.; Srivastava, S. C. L.; Ray, A.; Ali, Md. S. [Variable Energy Cyclotron Centre (VECC), Sector-1, Block-AF, Bidhan Nagar, Kolkata 700064 (India); Bhattacharjee, S. [UGC-DAE CSR, Kolkata Centre, III/LB-8, Bidhan Nagar, Kolkata 700098 (India)

    2013-03-15

    Radioactive ion beams (RIB) have been produced on-line, using a gas-jet recoil transport coupled Electron Cyclotron Resonance (ECR) ion-source at the VECC-RIB facility. Radioactive atoms/molecules carried through the gas-jet were stopped in a catcher placed inside the ECR plasma chamber. A skimmer has been used to remove bulk of the carrier gas at the ECR entrance. The diffusion of atoms/molecules through the catcher has been verified off-line using stable isotopes and on-line through transmission of radioactive reaction products. Beams of {sup 14}O (71 s), {sup 42}K (12.4 h), {sup 43}K (22.2 h), and {sup 41}Ar (1.8 h) have been produced by bombarding nitrogen and argon gas targets with proton and alpha particle beams from the K130 cyclotron at VECC. Typical measured intensity of RIB at the separator focal plane is found to be a few times 10{sup 3} particles per second (pps). About 3.2 Multiplication-Sign 10{sup 3} pps of 1.4 MeV {sup 14}O RIB has been measured after acceleration through a radiofrequency quadrupole linac. The details of the gas-jet coupled ECR ion-source and RIB production experiments are presented along with the plans for the future.

  5. Bioconversion of red ginseng saponins in the gastro-intestinal tract in vitro model studied by high-performance liquid chromatography-high resolution Fourier transform ion cyclotron resonance mass spectrometry

    NARCIS (Netherlands)

    Kong, H.; Wang, M.; Venema, K.; Maathuis, A.; Heijden, R. van der; Greef, J. van der; Xu, G.; Hankemeier, T.

    2009-01-01

    A high-performance liquid chromatography-high resolution Fourier transform ion cyclotron resonance mass spectrometry (HPLC-FTICR-MS) method was developed to investigate the metabolism of ginsenosides in in vitro models of the gastro-intestinal tract. The metabolites were identified by

  6. Enhanced sensitivity of surface plasmon resonance phase-interrogation biosensor by using oblique deposited silver nanorods

    Science.gov (United States)

    Chung, Hung-Yi; Chen, Chih-Chia; Wu, Pin Chieh; Tseng, Ming Lun; Lin, Wen-Chi; Chen, Chih-Wei; Chiang, Hai-Pang

    2014-09-01

    Sensitivity of surface plasmon resonance phase-interrogation biosensor is demonstrated to be enhanced by oblique deposited silver nanorods. Silver nanorods are thermally deposited on silver nanothin film by oblique angle deposition (OAD). The length of the nanorods can be tuned by controlling the deposition parameters of thermal deposition. By measuring the phase difference between the p and s waves of surface plasmon resonance heterodyne interferometer with different wavelength of incident light, we have demonstrated that maximum sensitivity of glucose detection down to 7.1 × 10-8 refractive index units could be achieved with optimal deposition parameters of silver nanorods.

  7. Combination of statistical methods and Fourier transform ion cyclotron resonance mass spectrometry for more comprehensive, molecular-level interpretations of petroleum samples.

    Science.gov (United States)

    Hur, Manhoi; Yeo, Injoon; Park, Eunsuk; Kim, Young Hwan; Yoo, Jongshin; Kim, Eunkyoung; No, Myoung-han; Koh, Jaesuk; Kim, Sunghwan

    2010-01-01

    Complex petroleum mass spectra obtained by Fourier-transform ion cyclotron resonance mass spectrometry (FTICR MS) were successfully interpreted at the molecular level by applying principle component analysis (PCA) and hierarchical clustering analysis (HCA). A total of 40 mass spectra were obtained from 20 crude oil samples using both positive and negative atmospheric pressure photoionization (APPI). Approximately 400,000 peaks were identified at the molecular level. Conventional data analyses would have been impractical with so much data. However, PCA grouped samples into score plots based on their molecular composition. In this way, the overall compositional difference between samples could be easily displayed and identified by comparing score and loading plots. HCA was also performed to group and compare samples based on selected peaks that had been grouped by PCA. Subsequent heat map analyses revealed detailed compositional differences among grouped samples. This study demonstrates a promising new approach for studying multiple, complex petroleum samples at the molecular level.

  8. Development of a compact thermal lithium atom beam source for measurements of electron velocity distribution function anisotropy in electron cyclotron resonance plasmas.

    Science.gov (United States)

    Nishioka, T; Shikama, T; Nagamizo, S; Fujii, K; Zushi, H; Uchida, M; Iwamae, A; Tanaka, H; Maekawa, T; Hasuo, M

    2013-07-01

    The anisotropy of the electron velocity distribution function (EVDF) in plasmas can be deduced from the polarization of emissions induced by anisotropic electron-impact excitation. In this paper, we develop a compact thermal lithium atom beam source for spatially resolved measurements of the EVDF anisotropy in electron cyclotron resonance (ECR) plasmas. The beam system is designed such that the ejected beam has a slab shape, and the beam direction is variable. The divergence and flux of the beam are evaluated by experiments and calculations. The developed beam system is installed in an ECR plasma device with a cusp magnetic field, and the LiI 2s-2p emission (670.8 nm) is observed in low-pressure helium plasma. The two-dimensional distributions of the degree and direction of the polarization in the LiI emission are measured by a polarization imaging system. The evaluated polarization distribution suggests the spatial variation of the EVDF anisotropy.

  9. A liquid-helium-free superconducting coil system forming a flat minimum-magnetic-field distribution of an electron cyclotron resonance ion source.

    Science.gov (United States)

    Yoshida, Ken-ichi; Nara, Takayuki; Saitoh, Yuichi; Yokota, Watalu

    2014-02-01

    A flat distribution of the minimum magnetic field (flat-Bmin) of an electron cyclotron resonance ion source (ECRIS) is expected to perform better in highly charged ion production than classical Bmin. To form a flat-Bmin structure with a liquid helium-free superconducting device, a coil system of seven coils with four current leads has been designed. The lead number was reduced by connecting the plural coils in series to maintain the flat-Bmin structure even when the coil currents are changed for adjustment. This coil system can be operated with a helium-free cryostat, since the estimation of heat from the leads to the coils is nearly equivalent to the existing superconducting ECRIS of a similar type.

  10. A liquid-helium-free superconducting coil system forming a flat minimum-magnetic-field distribution of an electron cyclotron resonance ion source

    Energy Technology Data Exchange (ETDEWEB)

    Yoshida, Ken-ichi, E-mail: yoshida.kennichi71@jaea.go.jp; Nara, Takayuki; Saitoh, Yuichi; Yokota, Watalu [Takasaki Advanced Radiation Research Institute, Japan Atomic Energy Agency, 1233 Watanuki, Takasaki, Gunma 370-1292 (Japan)

    2014-02-15

    A flat distribution of the minimum magnetic field (flat-B{sub min}) of an electron cyclotron resonance ion source (ECRIS) is expected to perform better in highly charged ion production than classical B{sub min}. To form a flat-B{sub min} structure with a liquid helium-free superconducting device, a coil system of seven coils with four current leads has been designed. The lead number was reduced by connecting the plural coils in series to maintain the flat-B{sub min} structure even when the coil currents are changed for adjustment. This coil system can be operated with a helium-free cryostat, since the estimation of heat from the leads to the coils is nearly equivalent to the existing superconducting ECRIS of a similar type.

  11. Direct Analysis in Real Time (DART of an Organothiophosphate at Ultrahigh Resolution by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry and Tandem Mass Spectrometry

    Directory of Open Access Journals (Sweden)

    Laszlo Prokai

    2016-01-01

    Full Text Available Direct analysis in real time (DART is a recently developed ambient ionization technique for mass spectrometry to enable rapid and sensitive analyses with little or no sample preparation. After swab-based field sampling, the organothiophosphate malathion was analyzed using DART-Fourier transform ion cyclotron resonance (FT-ICR mass spectrometry (MS and tandem mass spectrometry (MS/MS. Mass resolution was documented to be over 800,000 in full-scan MS mode and over 1,000,000 for an MS/MS product ion produced by collision-induced dissociation of the protonated analyte. Mass measurement accuracy below 1 ppm was obtained for all DART-generated ions that belonged to the test compound in the mass spectra acquired using only external mass calibration. This high mass measurement accuracy, achievable at present only through FTMS, was required for unequivocal identification of the corresponding molecular formulae.

  12. Low-noise AlGaAs/InGaAs/GaAs pseudomorphic high electron mobility transistor recessed by electron cyclotron resonance plasma etching

    CERN Document Server

    Lee, J H; Lee, C W; Yoon, H S; Park, B S; Park, C S

    1999-01-01

    GaAs pseudomorphic high electron mobility transistor recessed by electron cyclotron resonance (ECR) plasma etching have been investigated. We used a BCl sub 3 /SF sub 6 gas mixture to implement the gate recess process. We obtained a uniformity of the threshold voltage to within 50 mV in 3-inch wafers. The GaAs PHEMTs with a 0.2-mu m gate length recessed by the ECR plasma exhibited a minimum noise figure (NF sub m sub i sub n) as low as 0.26 dB with an associated gain (G sub a) of 13 dB at 12 GHz. At 18 GHz, the NF sub m sub i sub n was 0.47 dB with a Ga of 11.66 dB. These results suggest that the ECR plasma etching process reported here is suitable as a manufacturing process for gate recess of a GaAs PHEMT.

  13. Gas Chromatography/Atmospheric Pressure Chemical Ionization-Fourier Transform Ion Cyclotron Resonance Mass Spectrometry of Pyrolysis Oil from German Brown Coal

    Science.gov (United States)

    Zuber, Jan; Kroll, Marius M.; Rathsack, Philipp; Otto, Matthias

    2016-01-01

    Pyrolysis oil from the slow pyrolysis of German brown coal from Schöningen, obtained at a temperature of 500°C, was separated and analyzed using hyphenation of gas chromatography with an atmospheric pressure chemical ionization source operated in negative ion mode and Fourier transform ion cyclotron resonance mass spectrometry (GC-APCI-FT-ICR-MS). Development of this ultrahigh-resolving analysis method is described, that is, optimization of specific GC and APCI parameters and performed data processing. The advantages of GC-APCI-FT-ICR-MS hyphenation, for example, soft ionization, ultrahigh-resolving detection, and most important isomer separation, were demonstrated for the sample liquid. For instance, it was possible to separate and identify nine different propylphenol, ethylmethylphenol, and trimethylphenol isomers. Furthermore, homologous series of different acids, for example, alkyl and alkylene carboxylic acids, were verified, as well as homologous series of alkyl phenols, alkyl dihydroxy benzenes, and alkoxy alkyl phenols. PMID:27066076

  14. A liquid-helium-free superconducting coil system forming a flat minimum-magnetic-field distribution of an electron cyclotron resonance ion source

    Science.gov (United States)

    Yoshida, Ken-ichi; Nara, Takayuki; Saitoh, Yuichi; Yokota, Watalu

    2014-02-01

    A flat distribution of the minimum magnetic field (flat-Bmin) of an electron cyclotron resonance ion source (ECRIS) is expected to perform better in highly charged ion production than classical Bmin. To form a flat-Bmin structure with a liquid helium-free superconducting device, a coil system of seven coils with four current leads has been designed. The lead number was reduced by connecting the plural coils in series to maintain the flat-Bmin structure even when the coil currents are changed for adjustment. This coil system can be operated with a helium-free cryostat, since the estimation of heat from the leads to the coils is nearly equivalent to the existing superconducting ECRIS of a similar type.

  15. Gas Chromatography/Atmospheric Pressure Chemical Ionization-Fourier Transform Ion Cyclotron Resonance Mass Spectrometry of Pyrolysis Oil from German Brown Coal

    Directory of Open Access Journals (Sweden)

    Jan Zuber

    2016-01-01

    Full Text Available Pyrolysis oil from the slow pyrolysis of German brown coal from Schöningen, obtained at a temperature of 500°C, was separated and analyzed using hyphenation of gas chromatography with an atmospheric pressure chemical ionization source operated in negative ion mode and Fourier transform ion cyclotron resonance mass spectrometry (GC-APCI-FT-ICR-MS. Development of this ultrahigh-resolving analysis method is described, that is, optimization of specific GC and APCI parameters and performed data processing. The advantages of GC-APCI-FT-ICR-MS hyphenation, for example, soft ionization, ultrahigh-resolving detection, and most important isomer separation, were demonstrated for the sample liquid. For instance, it was possible to separate and identify nine different propylphenol, ethylmethylphenol, and trimethylphenol isomers. Furthermore, homologous series of different acids, for example, alkyl and alkylene carboxylic acids, were verified, as well as homologous series of alkyl phenols, alkyl dihydroxy benzenes, and alkoxy alkyl phenols.

  16. Gas Chromatography/Atmospheric Pressure Chemical Ionization-Fourier Transform Ion Cyclotron Resonance Mass Spectrometry of Pyrolysis Oil from German Brown Coal.

    Science.gov (United States)

    Zuber, Jan; Kroll, Marius M; Rathsack, Philipp; Otto, Matthias

    2016-01-01

    Pyrolysis oil from the slow pyrolysis of German brown coal from Schöningen, obtained at a temperature of 500°C, was separated and analyzed using hyphenation of gas chromatography with an atmospheric pressure chemical ionization source operated in negative ion mode and Fourier transform ion cyclotron resonance mass spectrometry (GC-APCI-FT-ICR-MS). Development of this ultrahigh-resolving analysis method is described, that is, optimization of specific GC and APCI parameters and performed data processing. The advantages of GC-APCI-FT-ICR-MS hyphenation, for example, soft ionization, ultrahigh-resolving detection, and most important isomer separation, were demonstrated for the sample liquid. For instance, it was possible to separate and identify nine different propylphenol, ethylmethylphenol, and trimethylphenol isomers. Furthermore, homologous series of different acids, for example, alkyl and alkylene carboxylic acids, were verified, as well as homologous series of alkyl phenols, alkyl dihydroxy benzenes, and alkoxy alkyl phenols.

  17. Surface passivation of p-type Ge substrate with high-quality GeNx layer formed by electron-cyclotron-resonance plasma nitridation at low temperature

    Science.gov (United States)

    Fukuda, Yukio; Okamoto, Hiroshi; Iwasaki, Takuro; Otani, Yohei; Ono, Toshiro

    2011-09-01

    We have investigated the effects of the formation temperature and postmetallization annealing (PMA) on the interface properties of GeNx/p-Ge fabricated by the plasma nitridation of Ge substrates using an electron-cyclotron-resonance-generated nitrogen plasma. The nitridation temperature is found to be a critical parameter in improving the finally obtained GeNx/Ge interface properties. The GeNx/Ge formed at room temperature and treated by PMA at 400 °C exhibits the best interface properties with an interface trap density of 1 × 1011 cm-2 eV-1. The GeNx/Ge interface is unpinned and the Fermi level at the Ge surface can move from the valence band edge to the conduction band edge.

  18. submitter Beam experiments with the Grenoble test electron cyclotron resonance ion source at iThemba LABS

    CERN Document Server

    Thomae, R; Fourie, D; Mira, J; Nemulodi, F; Kuechler, D; Toivanen, V

    2016-01-01

    ABSTRACT At iThemba Laboratory for Accelerator Based Sciences (iThemba LABS) an electron cyclotron ion source was installed and commissioned. This source is a copy of the Grenoble Test Source (GTS) for the production of highly charged ions. The source is similar to the GTS-LHC at CERN and named GTS2. A collaboration between the Accelerators and Beam Physics Group of CERN and the Accelerator and Engineering Department of iThemba LABS was proposed in which the development of high intensity argon and xenon beams is envisaged. In this paper, we present beam experiments with the GTS2 at iThemba LABS, in which the results of continuous wave and afterglow operation of xenon ion beams with oxygen as supporting gases are presented.

  19. First commissioning results with the Grenoble test electron cyclotron resonance ion source at iThemba LABS

    Energy Technology Data Exchange (ETDEWEB)

    Thomae, R.; Conradie, J.; Delsink, H.; Du Plessis, H.; Fourie, D.; Klopp, M.; Kohler, I.; Lussi, C.; McAlister, R.; Ntshangase, S.; Sakildien, M. [iThemba LABS, P.O Box 722, Somerset West 7130 (South Africa); Hitz, D. [CEA/DRFMC, 17 Av. Des Martyrs, 38054, Grenoble Cedex 9 (France); Kuechler, D. [CERN, BE/ABP/HSL, 1211 Geneva 23 (Switzerland)

    2012-02-15

    iThemba Laboratory for Accelerator Based Science (iThemba LABS) is a multi-disciplinary accelerator facility. One of its main activities is the operation of a separated-sector cyclotron with a K-value of 200, which provides beams of various ion species. These beams are used for fundamental nuclear physics research in the intermediate energy region, radioisotope production, and medical physics applications. Due to the requirements of nuclear physics for new ion species and higher energies, the decision was made to install a copy of the so-called Grenoble test source (GTS) at iThemba LABS. In this paper, we will report on the experimental setup and the first results obtained with the GTS2 at iThemba LABS.

  20. Detection of heterogeneous deposits on the surface of metal structures using nonlinear acoustic resonance technology

    Science.gov (United States)

    Jiao, Jingpin; Chang, Yu; Wu, Chao; Wu, Bin; He, Cunfu

    2017-12-01

    Failures caused by carbon deposits have always been a challenge in hydrocarbon processes. In this paper, a nonlinear acoustic resonance technique was investigated to characterize heterogeneous deposits on the surface of metal structures. The amplitude-frequency curves of the fundamental and second-harmonic responses were measured at various excitation levels. Experimental results indicated that the dependence of the resonant spectrum of the second harmonic response on the excitation level is based on the status of the deposit. Moreover, two hysteretic nonlinear parameters related to the second harmonic, the hysteretic elastic nonlinearity and the hysteretic dissipative nonlinearity, were proposed for the quantitative characterization of the deposited layers. The developed nonlinear acoustic resonance method in the megahertz region was used for quantitative evaluation of carbon deposits in a pipe, and the feasibility of the method for assessing carbon deposits was demonstrated.

  1. Identification of black carbon derived structures in a volcanic ash soil humic acid by Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Kramer, Robert W; Kujawinski, Elizabeth B; Hatcher, Patrick G

    2004-06-15

    Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS), coupled with cross-polarization magic angle spinning 13C nuclear magnetic resonance (NMR) spectroscopy and Kendrick mass defect analysis, was used to study the molecular composition of an aromatic carbon-rich humic acid extracted from a dark black soil from Iwata, Japan. Black carbon, produced by the incomplete combustion of fossil fuels and organic matter, has been suggested as a major component of humic acids having intense peaks in the aromatic and carboxyl regions of the 13C NMR spectrum. Taking advantage of the high resolving power of FT-ICR MS to make precise formula assignments, three different types of highly carboxylated polycyclic aromatic compounds were identified in the sample: linearly fused aromatic structures, aromatic structures linked by carbon-carbon single bonds, and highly condensed aromatic structures. These carboxylated aromatic structures have a low mass defect in their mass spectra due to their abundance of oxygen and deficiency of hydrogen. This mass defect is observed in the vast majority of peaks present in the entire mass spectrum, differentiating them from structures that are hydrogen-rich (e.g., fatty acids, proteins, carbohydrates). Thus, we conclude that the bulk of the sample analyzed is comprised of these heavily carboxylated, hydrogen-deficient, condensed aromatic structures, features believed to be characteristic of black carbon-like material.

  2. Analysis of cancer cell lipids using matrix-assisted laser desorption/ionization 15-T Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Yang, Hyo-Jik; Park, Kyu Hwan; Lim, Dong Wan; Kim, Hyun Sik; Kim, Jeongkwon

    2012-03-30

    A combination of methodologies using the extremely high mass accuracy and resolution of 15-T Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry (MS) was introduced for the identification of intact cancer cell phospholipids. Lipids from a malignant glioma cell line were initially analyzed at a resolution of >200,000 and identified by setting the mass tolerance to ±1 mDa using matrix-assisted laser desorption/ionization (MALDI) 15-T FT-ICR MS in positive ion mode. In most cases, a database search of potential lipid candidates using the exact masses of the lipids yielded only one possible chemical composition. Extremely high mass accuracy (800,000), yielded well-resolved isotopic fine structures allowing for the identification of lipids by MALDI 15-T FT-ICR MS without using tandem mass spectrometric (MS/MS) analysis. Using this method, a total of 38 unique lipids were successfully identified. Copyright © 2012 John Wiley & Sons, Ltd.

  3. Observation of hydrogen-deuterium exchange of ubiquitin by direct analysis of electrospray capillary-skimmer dissociation with Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Akashi, S; Naito, Y; Takio, K

    1999-11-01

    The structure of ubiquitin, a small cytoplasmic protein with an extended beta-sheet and an alpha-helix surrounding a hydrophobic core, has been characterized by hydrogen-deuterium (H/D) exchange labeling in conjunction with successive analysis by capillary-skimmer dissociation with electrospray ionization-Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR MS). The deuterium content of each fragment ion was investigated at different times, and the results indicate that the deuterium incorporation rate into the backbone amides of ubiquitin varied depending on the environment of the amide hydrogens. Amide hydrogens of the N-terminal beta-strand showed quite slow exchange while those of the 35-39 loop were exchanged within a short exposure time to deuterium oxide. It was also possible to evaluate the difference in hydrogen-bond stability. The present data are consistent with the structural features obtained by X-Ray and NMR analyses. Although some of the labeling information might be lost by the scrambling of amide protons during capillary-skimmer dissociation, the results demonstrate that the present method provides useful higher-order structural information for proteins.

  4. Online quench-flow electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry for elucidating kinetic and chemical enzymatic reaction mechanisms.

    Science.gov (United States)

    Clarke, David J; Stokes, Adam A; Langridge-Smith, Pat; Mackay, C Logan

    2010-03-01

    We have developed an automated quench-flow microreactor which interfaces directly to an electrospray ionization (ESI) mass spectrometer. We have used this device in conjunction with ESI Fourier transform ion cyclotron resonance mass spectrometry (FTICR MS) to demonstrate the potential of this approach for studying the mechanistic details of enzyme reactions. For the model system chosen to test this device, namely, the pre-steady-state hydrolysis of p-nitrophenyl acetate by the enzyme chymotrypsin, the kinetic parameters obtained are in good agreement with those in the literature. To our knowledge, this is the first reported use of online quench-flow coupled with FTICR MS. Furthermore, we have exploited the power of FTICR MS to interrogate the quenched covalently bound enzyme intermediate using top-down fragmentation. The accurate mass capabilities of FTICR MS permitted the nature of the intermediate to be assigned with high confidence. Electron capture dissociation (ECD) fragmentation allowed us to locate the intermediate to a five amino acid section of the protein--which includes the known catalytic residue, Ser(195). This experimental approach, which uniquely can provide both kinetic and chemical details of enzyme mechanisms, is a potentially powerful tool for studies of enzyme catalysis.

  5. Molecular Characterization of Thiols in Fossil Fuels by Michael Addition Reaction Derivatization and Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry.

    Science.gov (United States)

    Wang, Meng; Zhao, Suoqi; Liu, Xuxia; Shi, Quan

    2016-10-04

    Thiols widely occur in sediments and fossil fuels. However, the molecular composition of these compounds is unclear due to the lack of appropriate analytical methods. In this work, a characterization method for thiols in fossil fuels was developed on the basis of Michael addition reaction derivatization followed by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS). Model thiol compound studies showed that thiols were selectively reacted with phenylvinylsulfone and transformed to sulfones with greater than 98% conversions. This method was applied to a coker naphtha, light and heavy gas oils, and crude oils from various geological sources. The results showed that long alkyl chain thiols are readily present in petroleum, which have up to 30 carbon atoms. Large DBE dispersity of thiols indicates that naphthenic and aromatic thiols are also present in the petroleum. This method is capable of detecting thiol compounds in the part per million range by weight. This method allows characterization of thiols in a complex hydrocarbon matrix, which is complementary to the comprehensive analysis of sulfur compounds in fossil fuels.

  6. Metabolic profile of salidroside in rats using high-performance liquid chromatography combined with Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Han, Fei; Li, Yan-ting; Mao, Xin-juan; Zhang, Xiao-shu; Guan, Jiao; Song, Ai-hua; Yin, Ran

    2016-03-01

    A high-performance liquid chromatography coupled to Fourier transform ion cyclotron resonance mass spectrometry (HPLC-FT-ICR MS) method was developed to study the in vivo metabolism of salidroside for the first time. Plasma, urine, bile, and feces samples were collected from male rats after a single intragastric gavage of salidroside at a dose of 50 mg/kg. Besides the parent drug, a total of seven metabolites (three phase I and four phase II metabolites) were detected and tentatively identified by comparing their mass spectrometry profiles with those of salidroside. Results indicated that metabolic pathways of salidroside in male rats included hydroxylation, dehydrogenation, glucuronidation, and sulfate conjugation. Among them, glucuronidation and sulfate conjugation were the major metabolic reactions. And most important, the detection of the sulfation metabolite of p-tyrosol provides a clue for whether the deglycosylation of salidroside occurs in vivo after intragastric gavage. In summary, results obtained in this study may contribute to the better understanding of the safety and mechanism of action of salidroside.

  7. Native Top-Down ESI-MS of 158 kDa Protein Complex by High Resolution Fourier Transform Ion Cyclotron Resonance Mass Spectrometry

    Science.gov (United States)

    Li, Huilin; Wolff, Jeremy J.; Van Orden, Steve L.; Loo, Joseph A.

    2014-01-01

    Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) delivers high resolving power, mass measurement accuracy, and the capabilities for unambiguously sequencing by a top-down MS approach. Here, we report isotopic resolution of a 158 kDa protein complex - tetrameric aldolase with an average absolute deviation of 0.36 ppm and an average resolving power of ~520,000 at m/z 6033 for the 26+ charge state in magnitude mode. Phase correction further improves the resolving power and average absolute deviation by 1.3 fold. Furthermore, native top-down electron capture dissociation (ECD) enables the sequencing of 149 C-terminal amino acid (AA) residues out of 463 total AAs. Combining the data from top-down MS of native and denatured aldolase complexes, a total of 58% of the backbone cleavages efficiency is achieved. The observation of complementary product ion pairs confirms the correctness of the sequence and also the accuracy of the mass fitting of the isotopic distribution of the aldolase tetramer. Top-down MS of the native protein provides complementary sequence information to top-down ECD and CAD MS of the denatured protein. Moreover, native top-down ECD of aldolase tetramer reveals that ECD fragmentation is not limited only to the flexible regions of protein complexes and that regions located on the surface topology are prone to ECD cleavage. PMID:24313806

  8. Structural characterization of arginine-vasopressin and lysine-vasopressin by Fourier- transform ion cyclotron resonance mass spectrometry and infrared multiphoton dissociation.

    Science.gov (United States)

    Bianco, Giuliana; Battista, Fabio; Buchicchio, Alessandro; Amarena, Concetta G; Schmitt-Kopplin, Philippe; Guerrieri, Antonio

    2015-01-01

    Arginine-vasopressin (AVP) and lysine-vasopressin (LVP) were analyzed by reversed-phase liquid chromatography/mass spectrometry (LC-MS) using Fourier-transform ion cyclotron resonance (FT-ICR) mass spectrometry (MS) electrospray ionization (ESI) in the positive ion mode. LVP and AVP exhibited the protonated adduct [M+H](+) as the predominant ion at m/z 1056.43965 and at m/z 1084.44561, respectively. Infrared multiphoton dissociation (IRMPD), using a CO(2) laser source at a wavelength of 10.6 μm, was applied to protonated vasopressin molecules. The IRMPD mass spectra presented abundant mass fragments essential for a complete structural information. Several fragment ions, shared between two target molecules, are discussed in detail. Some previously unpublished fragments were identified unambiguously utilizing the high resolution and accurate mass information provided by the FT-ICR mass spectrometer. The opening of the disulfide loop and the cleavage of the peptide bonds within the ring were observed even under low-energy fragmentation conditions. Coupling the high-performance FT-ICR mass spectrometer with IRMPD as a contemporary fragmentation technique proved to be very promising for the structural characterization of vasopressin.

  9. Molecular evidence of heavy-oil weathering following the M/V Cosco Busan spill: insights from Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Lemkau, Karin L; McKenna, Amy M; Podgorski, David C; Rodgers, Ryan P; Reddy, Christopher M

    2014-04-01

    Recent studies have highlighted a critical need to investigate oil weathering beyond the analytical window afforded by conventional gas chromatography (GC). In particular, techniques capable of detecting polar and higher molecular weight (HMW; > 400 Da) components abundant in crude and heavy fuel oils (HFOs) as well as transformation products. Here, we used atmospheric pressure photoionization Fourier transform ion cyclotron resonance mass spectrometry (APPI FT-ICR MS) to identify molecular transformations in oil-residue samples from the 2007 M/V Cosco Busan HFO spill (San Francisco, CA). Over 617 days, the abundance and diversity of oxygen-containing compounds increased relative to the parent HFO, likely from bio- and photodegradation. HMW, highly aromatic, alkylated compounds decreased in relative abundance concurrent with increased relative abundance of less alkylated stable aromatic structures. Combining these results with GC-based data yielded a more comprehensive understanding of oil spill weathering. For example, dealkylation trends and the overall loss of HMW species observed by FT-ICR MS has not previously been documented and is counterintuitive given losses of lower molecular weight species observed by GC. These results suggest a region of relative stability at the interface of these techniques, which provides new indicators for studying long-term weathering and identifying sources.

  10. Chemical Assignment of Structural Isomers of Sulfur-Containing Metabolites in Garlic by Liquid Chromatography-Fourier Transform Ion Cyclotron Resonance-Mass Spectrometry.

    Science.gov (United States)

    Nakabayashi, Ryo; Sawada, Yuji; Aoyagi, Morihiro; Yamada, Yutaka; Hirai, Masami Yokota; Sakurai, Tetsuya; Kamoi, Takahiro; Rowan, Daryl D; Saito, Kazuki

    2016-02-01

    The chemical assignment of metabolites is crucial to understanding the relation between food composition and biological activity. This study was designed to detect and chemically assign sulfur-containing metabolites by using LC-Fourier transform ion cyclotron resonance-mass spectrometry (FTICR-MS) in Allium plants. Ultrahigh resolution (>250,000 full width at half-maximum) and mass accuracy (<1 mDa) by FTICR-MS allowed us to distinguish ions containing sulfur isotopes ((32)S and (34)S). Putative 69 S-containing monoisotopic ions (S-ions) were extracted from the metabolome data of onion (Allium cepa), green onion (Allium fistulosum), and garlic (Allium sativum) on the basis of theoretical mass differences between (32)S-ions and their (34)S-substituted counterparts and on the natural abundance of (34)S. Eight S-ions were chemically assigned by using the reference data according to the guidelines of the Metabolomics Standards Initiative. Three ions detected in garlic were assigned as derived from the isomers γ-glutamyl-S-1-propenylcysteine and γ-glutamyl-S-2-propenylcysteine and as S-2-propenylmercaptoglutathione on the basis of differences in key product ions identified in reference tandem MS spectra. The ability to discriminate between such geometric isomers will be extremely useful for the chemical assignment of unknown metabolites in MS-based metabolomics. © 2016 American Society for Nutrition.

  11. Trapping, detection, and mass determination of coliphage T4 DNA ions of 10{sup 8} Da by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Chen, R.; Cheng, X.; Mitchell, D.W.; Hofstadler, S.A.; Wu, Q.; Rockwood, A.L.; Sherman, M.G.; Smith, R.D. [Pacific Northwest Lab., Richland, WA (United States)

    1995-04-01

    The trapping, detection, and mass measurement of individual T4 DNA ions (nominal molecular weight, M{sub r} = 1.1 x 10{sup 8} Da) have been performed with a 7 T electrospray ionization Fourier transform ion cyclotron resonance (ESI-FTICR) mass spectrometer. The ionic mass was obtained by direct measurement of the number of charges carried by individual T4 DNA ions. The ions detected are a factor of approximately 20 larger than any molecule previously studied by mass spectrometry. These gas-phase macroions demonstrate a high degree of stability, which allows the acquisition of long transients (>476 s) from individual ions and the study of relatively slow reactions or dissociation processes. These results show the potential utility of ESI-FTICR mass spectrometry for the analysis of very large biomolecules and microparticles and indicate that it is possible to transfer ions of 110 MDa size to the gas phase substantially intact. The potential applications of the FTICR analysis of such highly charged ions are briefly discussed. 33 refs., 3 figs., 1 tab.

  12. Direct charge number and molecular weight determination of large individual ions by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Chen, R.; Wu, Q.; Mitchell, D.W.; Hofstadler, S.A.; Rockwood, A.L.; Smith, R.D. (Pacific Northwest Lab., Richland, WA (United States))

    1994-11-15

    The coupling of electrospray ionization (ESI) techniques with Fourier transform ion cyclotron resonance (FTICR) mass spectrometry allows the analysis of individual (i.e., single) multiply charged ions. In this paper, we demonstrate that individual large ions can be directly characterized through their excitation and ejection behavior in the FTICR cell. We also report the direct measurement of the charge carried by an individual poly(ethylene glycol) ion (5 [times] 10[sup 6] nominal molecular weight) and thus obtain the molecular weight of an individual ion ([approximately] 4.1 [times] 10[sup 6]) directly from the m/z measurement. These results confirm that the observed ions are indeed large individual molecular ions produced by ESI, as opposed to small fragments, and that an approximate molecular weight can be directly measured on the basis of charge determination and measured m/z. This capability augments the ability for more precise mass determination based upon the observation of a known reaction process (e.g., proton transfer) for individual ions. 39 refs., 5 figs., 1 tab.

  13. Pathway confirmation and flux analysis of central metabolicpathways in Desulfovibrio vulgaris Hildenborough using GasChromatography-Mass Spectrometry and Fourier Transform-Ion CyclotronResonance Mass Spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Tang, Yinjie; Pingitore, Francesco; Mukhopadhyay, Aindrila; Phan,Richard; Hazen, Terry C.; Keasling, Jay D.

    2007-03-15

    Flux distribution in central metabolic pathways ofDesulfovibrio vulgaris Hildenborough was examined using 13C tracerexperiments. Consistent with the current genome annotation andindependent evidence from enzyme activity assays, the isotopomer resultsfrom both GC-MS and Fourier Transform-Ion Cyclotron Resonance massspectrometry (FT-ICR MS) indicate the lack of oxidatively functional TCAcycle and an incomplete pentose phosphate pathway. Results from thisstudy suggest that fluxes through both pathways are limited tobiosynthesis. The data also indicate that>80 percent of the lactatewas converted to acetate and the reactions involved are the primary routeof energy production (NAD(P)H and ATP production). Independent of the TCAcycle, direct cleavage of acetyl-CoA to CO and 5,10-methyl-THF also leadsto production of NADH and ATP. Although the genome annotation implicatesa ferredoxin-dependentoxoglutarate synthase, isotopic evidence does notsupport flux through this reaction in either the oxidative or reductivemode; therefore, the TCA cycle is incomplete. FT-ICR MS was used tolocate the labeled carbon distribution in aspartate and glutamate andconfirmed the presence of an atypical enzyme for citrate formationsuggested in previous reports (the citrate synthesized by this enzyme isthe isotopic antipode of the citrate synthesized by the (S)-citratesynthase). These findings enable a better understanding of the relationbetween genome annotation and actual metabolic pathways in D. vulgaris,and also demonstrate FT-ICR MS as a powerful tool for isotopomeranalysis, overcoming problems in both GC-MS and NMRspectroscopy.

  14. Calibration laws based on multiple linear regression applied to matrix-assisted laser desorption/ionization Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Williams, D Keith; Chadwick, M Ashley; Williams, Taufika Islam; Muddiman, David C

    2008-12-01

    Operation of any mass spectrometer requires implementation of mass calibration laws to translate experimentally measured physical quantities into a m/z range. While internal calibration in Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) offers several attractive features, including exposure of calibrant and analyte ions to identical experimental conditions (e.g. space charge), external calibration affords simpler pulse sequences and higher throughput. The automatic gain control method used in hybrid linear trap quadrupole (LTQ) FT-ICR-MS to consistently obtain the same ion population is not readily amenable to matrix-assisted laser desorption/ionization (MALDI) FT-ICR-MS, due to the heterogeneous nature and poor spot-to-spot reproducibility of MALDI. This can be compensated for by taking external calibration laws into account that consider magnetic and electric fields, as well as relative and total ion abundances. Herein, an evaluation of external mass calibration laws applied to MALDI-FT-ICR-MS is performed to achieve higher mass measurement accuracy (MMA). Copyright (c) 2008 John Wiley & Sons, Ltd.

  15. Photoelectron Spectroscopy of EuBa2Cu3O7-y Thin Film Surfaces Treated by an Electron Cyclotron Resonance Oxygen Ion Beam

    Science.gov (United States)

    Asano, Hidefumi; Suzuki, Minoru; Kiyokura, Takanori; Maeda, Fumihiko; Menz, Andreas; Watanabe, Yoshio; Oshima, Masaharu

    1995-04-01

    Surface modification of EuBa2Cu3O7- y (EBCO) thin films induced by an electron cyclotron resonance (ECR) oxygen ion beam treatment has been studied using X-ray and synchrotron-radiation photoelectron spectroscopy (XPS and SRPES). The in situ characterization has been performed during the course of 50 eV ECR oxygen treatment for 30 min. Time-dependent analysis shows that the contaminant carbon layer on the surface region can be removed at the initial stage of the treatment (<2 min), and that the copper valence of the surfaces can be recovered to Cu2+ after 30 min treatment. It is found that room-temperature treatment using ECR oxygen can alter the contaminated, oxygen-depleted surface to a clean, well-oxygenated surface. The present results suggest that ECR treatment which can modify the surfaces in a well-defined manner would be a feasible technique for surface cleaning of high-temperature superconductors.

  16. Chemical Composition of Microbe-derived Dissolved Organic Matter in Cryoconite in Tibetan Plateau Glaciers: Insights from Fourier Transform Ion Cyclotron Resonance Mass Spectrometry Analysis

    Science.gov (United States)

    Lin, F.; Zhong, X. J.; Shichang, K.; Xiaofei, L.; Yang, L.; Quan, S.; Bin, J.

    2016-12-01

    ryoconite in mountain glaciers plays important roles in glacial ablation and biogeochemical cycles. The compositions and sources of dissolved organic matter (DOM) in cryoconite from the ablation regions of two Tibetan Plateau glaciers were determined using ultrahigh-resolution electrospray-ionization Fourier-transform ion cyclotron resonance mass spectrometry and fluorescence spectrometry. A marked absorbance between 300 and 350 nm in the DOM absorption spectra was consistent with microbe-derived mycosporine-like amino acids. The high-resolution mass spectra showed cryoconite DOM from both glaciers contained diverse lignins, lipids, proteins, and unsaturated hydrocarbons. The lipids and proteins were consistent with material from microbial sources, and the lignins and unsaturated hydrocarbons were probably from vascular plant material supplied in atmospheric aerosols and debris from around the glaciers. Almost one third of the identified DOM molecules had low C/N ratios (≤20), indicating their bioavailability. Using a conservative cryoconite distribution on Chinese mountain glacier surfaces and an average debris mass per square meter of cryoconite, we found that cryoconite in Chinese glaciers could produce as much as 0.5 Gg of dissolved organic carbon per year. This dissolved organic carbon may absorb solar radiation, accelerating glacial melting, and could be an important source of bioavailable DOM to proglacier and downstream ecosystems. Key words:cryoconite, DOM, FT-ICR-MS

  17. Characterization of chemical constituents in Rhodiola Crenulate by high-performance liquid chromatography coupled with Fourier-transform ion cyclotron resonance mass spectrometer (HPLC-FT-ICR MS).

    Science.gov (United States)

    Han, Fei; Li, Yanting; Mao, Xinjuan; Xu, Rui; Yin, Ran

    2016-05-01

    In this work, an approach using high-performance liquid chromatography coupled with diode-array detection and Fourier-transform ion cyclotron resonance mass spectrometer (HPLC-FT-ICR MS) for the identification and profiling of chemical constituents in Rhodiola crenulata was developed for the first time. The chromatographic separation was achieved on an Inertsil ODS-3 column (150 mm × 4.6 mm,3 µm) using a gradient elution program, and the detection was performed on a Bruker Solarix 7.0 T mass spectrometer equipped with electrospray ionization source in both positive and negative modes. Under the optimized conditions, a total of 48 chemical compounds, including 26 alcohols and their glycosides, 12 flavonoids and their glycosides, 5 flavanols and gallic acid derivatives, 4 organic acids and 1 cyanogenic glycoside were identified or tentatively characterized. The results indicated that the developed HPLC-FT-ICR MS method with ultra-high sensitivity and resolution is suitable for identifying and characterizing the chemical constituents in R. crenulata. And it provides a helpful chemical basis for further research on R. crenulata. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.

  18. Comparing Laser Desorption Ionization and Atmospheric Pressure Photoionization Coupled to Fourier Transform Ion Cyclotron Resonance Mass Spectrometry To Characterize Shale Oils at the Molecular Level

    Science.gov (United States)

    Cho, Yunjo; Jin, Jang Mi; Witt, Matthias; Birdwell, Justin E.; Na, Jeong-Geol; Roh, Nam-Sun; Kim, Sunghwan

    2013-01-01

    Laser desorption ionization (LDI) coupled to Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) was used to analyze shale oils. Previous work showed that LDI is a sensitive ionization technique for assessing aromatic nitrogen compounds, and oils generated from Green River Formation oil shales are well-documented as being rich in nitrogen. The data presented here demonstrate that LDI is effective in ionizing high-double-bond-equivalent (DBE) compounds and, therefore, is a suitable method for characterizing compounds with condensed structures. Additionally, LDI generates radical cations and protonated ions concurrently, the distribution of which depends upon the molecular structures and elemental compositions, and the basicity of compounds is closely related to the generation of protonated ions. This study demonstrates that LDI FT-ICR MS is an effective ionization technique for use in the study of shale oils at the molecular level. To the best of our knowledge, this is the first time that LDI FT-ICR MS has been applied to shale oils.

  19. Subsequent radical fragmentation reactions of N, N-diethylamino-substituted azobenzene derivatives in a Fourier transform ion cyclotron resonance mass spectrometer using collision-induced dissociation and photodissociation.

    Science.gov (United States)

    Clemen, Martin; Grotemeyer, Jürgen

    2017-12-01

    The fragmentation behavior of N, N-diethylamino-substituted azobenzene derivatives is investigated by high-resolving mass spectrometry using a Fourier transform ion cyclotron resonance mass spectrometer. Former investigations by photodissociation as well as collision-induced dissociation experiments used to induce a loss of C 3 H 8 from the diethylamino group. The position of the additional proton in [M + H] + ions is important due to the sequences of radical fragmentation reactions. Two possibilities arise. First, a charge is located at the azo group leading to a methyl radical loss. The second possibility is that the charge has been located on the aniline nitrogen of the molecule resulting in an ethyl radical loss. Only o-ethyl red has shown the overall loss of C 3 H 8 in a two-step radical reaction mechanism. Nevertheless, p-ethyl red and ethyl yellow have shown systematic fragmentation reactions as well. Loss of C 3 H 8 has not been likely regarding both these molecules. All experimental findings together with quantum chemical calculations as well as kinetic calculations support the proposed fragmentation mechanisms of the three azo dyes.

  20. Investigation of bio-oil produced by hydrothermal liquefaction of food waste using ultrahigh resolution Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Kostyukevich, Yury; Vlaskin, Mikhail; Borisova, Ludmila; Zherebker, Alexander; Perminova, Irina; Kononikhin, Alexey; Popov, Igor; Nikolaev, Eugene

    2018-02-01

    Recent research has revealed that more than 1.3 billion tons of food is wasted globally every year. The disposal of such huge biomass has become a challenge. In the present paper, we report the production of the bio-oil by hydrothermal liquefaction of three classes of food waste: meat, cheese and fruits. The highest yield of the bio-oil was observed for meat (∼60%) and cheese (∼75%), while for fruits, it was considerably low (∼10%). The molecular composition of the obtained bio-oil was investigated using ultrahigh resolution Fourier Transform Ion Cyclotron Resonance mass spectrometry and was found to be similar to that obtained from algae. Several thousand heteroatom compounds (N, N2, ON2, etc. classes) were reliably identified from each sample. It was found that bio-oils produced from meat and cheese have many compounds (∼90%) with common molecular formulas, while bio-oil produced from fruits differs considerably (∼30% of compounds are unique).

  1. Preparative free-flow electrophoretic offline ESI-Fourier transform ion cyclotron resonance/MS analysis of Suwannee River fulvic acid.

    Science.gov (United States)

    Gaspar, Andras; Harir, Mourad; Hertkorn, Norbert; Schmitt-Kopplin, Philippe

    2010-06-01

    Free-flow electrophoresis (FFE), a preparative free zone electrophoretic method, was used offline in conjunction with ultrahigh-resolution FT/ion cyclotron resonance -MS to resolve the complexity of Suwannee River fulvic acid (SRFA). Before MS, the FFE separation conditions and the compatibility with ESI were optimized. The constituents in SRFA were effectively separated based on their charge states and sizes. The obtained mass spectra were compared by means of van Krevelen diagrams and the calculated aromaticity indices of the individual constituents were used to describe the distribution of aromatic/unsaturated structures across the FFE-fractionated samples. The consolidated number of ions observed within the individual SRFA fractions were much higher than those of the bulk samples alone, demonstrating extensive ion suppression effects in bulk SRFA likely also operating in the analysis of complex biogeochemical mixtures in flow injection mode. The FFE approach allows for producing sizable amounts of sample from dilute solutions, which can be easily fractionated into dozens of individual samples with the possibility of further in-depth characterization.

  2. Operation of Lanzhou all permanent electron cyclotron resonance ion source No. 2 on 320 kV platform with highly charged ions.

    Science.gov (United States)

    Lu, W; Li, J Y; Kang, L; Liu, H P; Li, H; Li, J D; Sun, L T; Ma, X W

    2014-02-01

    The 320 kV platform for multi-discipline research with highly charged ions is a heavy ion beam acceleration instrument developed by Institute of Modern Physics, which is dedicated to basic scientific researches such as plasma, atom, material physics, and astrophysics, etc. The platform has delivered ion beams of 400 species for 36,000 h. The average operation time is around 5000 h/year. With the beams provided by the platform, lots of outstanding progresses were made in various research fields. The ion source of the platform is an all-permanent magnet electron cyclotron resonance ion source, LAPECR2 (Lanzhou All Permanent ECR ion source No. 2). The maximum axial magnetic fields are 1.28 T at injection and 1.07 T at extraction, and the radial magnetic field is up to 1.21 T at the inner wall of the plasma chamber. The ion source is capable to produce low, medium, and high charge state gaseous and metallic ion beams, such as H(+), (40)Ar(8+), (129)Xe(30+), (209)Bi(33+), etc. This paper will present the latest result of LAPECR2 and the routine operation status for the high voltage platform.

  3. Boosting Sensitivity in Liquid Chromatography-Fourier Transform Ion Cyclotron Resonance-Tandem Mass Spectrometry for Product Ion Analysis of Monoterpene Indole Alkaloids.

    Science.gov (United States)

    Nakabayashi, Ryo; Tsugawa, Hiroshi; Kitajima, Mariko; Takayama, Hiromitsu; Saito, Kazuki

    2015-01-01

    In metabolomics, the analysis of product ions in tandem mass spectrometry (MS/MS) is noteworthy to chemically assign structural information. However, the development of relevant analytical methods are less advanced. Here, we developed a method to boost sensitivity in liquid chromatography-Fourier transform ion cyclotron resonance-tandem mass spectrometry analysis (MS/MS boost analysis). To verify the MS/MS boost analysis, both quercetin and uniformly labeled (13)C quercetin were analyzed, revealing that the origin of the product ions is not the instrument, but the analyzed compounds resulting in sensitive product ions. Next, we applied this method to the analysis of monoterpene indole alkaloids (MIAs). The comparative analyses of MIAs having indole basic skeleton (ajmalicine, catharanthine, hirsuteine, and hirsutine) and oxindole skeleton (formosanine, isoformosanine, pteropodine, isopteropodine, rhynchophylline, isorhynchophylline, and mitraphylline) identified 86 and 73 common monoisotopic ions, respectively. The comparative analyses of the three pairs of stereoisomers showed more than 170 common monoisotopic ions in each pair. This method was also applied to the targeted analysis of MIAs in Catharanthus roseus and Uncaria rhynchophylla to profile indole and oxindole compounds using the product ions. This analysis is suitable for chemically assigning features of the metabolite groups, which contributes to targeted metabolome analysis.

  4. Analysis of O-glycan heterogeneity in IgA1 myeloma proteins by Fourier transform ion cyclotron resonance mass spectrometry: implications for IgA nephropathy

    DEFF Research Database (Denmark)

    Renfrow, MB; Mackay, CL; Chalmers, MJ

    2007-01-01

    IgA nephropathy (IgAN) is the most common form of primary glomerulonephritis. In IgAN, IgA1 molecules with incompletely galactosylated O-linked glycans in the hinge region (HR) are present in mesangial immunodeposits and in circulating immune complexes. It is not known whether the galactose...... deficiency in IgA1 proteins occurs randomly or preferentially at specific sites. We have previously demonstrated the first direct localization of multiple O-glycosylation sites on a single IgA1 myeloma protein by use of activated ion-electron capture dissociation (AI-ECD) Fourier transform ion cyclotron...... resonance (FT-ICR) tandem mass spectrometry. Here, we report the analysis of IgA1 O-glycan heterogeneity by use of FT-ICR MS and liquid chromatography FT-ICR MS to obtain unbiased accurate mass profiles of IgA1 HR glycopeptides from three different IgA1 myeloma proteins. Additionally, we report the first AI...

  5. A near infra-red video system as a protective diagnostic for electron cyclotron resonance heating operation in the Wendelstein 7-X stellarator.

    Science.gov (United States)

    Preynas, M; Laqua, H P; Marsen, S; Reintrog, A; Corre, Y; Moncada, V; Travere, J-M

    2015-11-01

    The Wendelstein 7-X stellarator is a large nuclear fusion device based at Max-Planck-Institut für Plasmaphysik in Greifswald in Germany. The main plasma heating system for steady state operation in W7-X is electron cyclotron resonance heating (ECRH). During operation, part of plama facing components will be directly heated by the non-absorbed power of 1 MW rf beams of ECRH. In order to avoid damages of such components made of graphite tiles during the first operational phase, a near infra-red video system has been developed as a protective diagnostic for safe and secure ECRH operation. Both the mechanical design housing the camera and the optical system are very flexible and respect the requirements of steady state operation. The full system including data acquisition and control system has been successfully tested in the vacuum vessel, including on-line visualization and data storage of the four cameras equipping the ECRH equatorial launchers of W7-X.

  6. A near infra-red video system as a protective diagnostic for electron cyclotron resonance heating operation in the Wendelstein 7-X stellarator

    Energy Technology Data Exchange (ETDEWEB)

    Preynas, M.; Laqua, H. P.; Marsen, S.; Reintrog, A. [Max-Planck-Institut für Plasmaphysik (IPP), D-17491 Greifswald (Germany); Corre, Y.; Moncada, V.; Travere, J.-M. [IRFM, CEA-Cadarache, 13108 Saint Paul lez Durance Cedex (France)

    2015-11-15

    The Wendelstein 7-X stellarator is a large nuclear fusion device based at Max-Planck-Institut für Plasmaphysik in Greifswald in Germany. The main plasma heating system for steady state operation in W7-X is electron cyclotron resonance heating (ECRH). During operation, part of plama facing components will be directly heated by the non-absorbed power of 1 MW rf beams of ECRH. In order to avoid damages of such components made of graphite tiles during the first operational phase, a near infra-red video system has been developed as a protective diagnostic for safe and secure ECRH operation. Both the mechanical design housing the camera and the optical system are very flexible and respect the requirements of steady state operation. The full system including data acquisition and control system has been successfully tested in the vacuum vessel, including on-line visualization and data storage of the four cameras equipping the ECRH equatorial launchers of W7-X.

  7. Superconducting Titanium Nitride Coplanar Resonators: Relationships between performance and deposition parameters

    Science.gov (United States)

    Chiaro, B.; Ohya, S.; Megrant, A.; Neill, C.; Barends, R.; Campbell, B.; Chen, Y.; Kelly, J.; Mariantoni, M.; Mutus, J.; O'Malley, P.; Roushan, P.; Sank, D.; Vainsencher, A.; Wenner, J.; White, T.; Palmstrom, C. J.; Mazin, B. A.; Cleland, A. N.; Martinis, J. M.

    2013-03-01

    Superconducting coplanar waveguide (CPW) resonators are widely used structures in the fields of photon detection and quantum information processing. Recently, there has been a growing interest in titanium nitride (TiN) thin films due to their widely tunable critical temperature, large surface inductance, and ability to produce high intrinsic quality factor (Qi) resonators. We have deposited nearly stoichiometric TiN films on Si substrates by reactive magnetron sputtering. By increasing the deposition pressure and adjusting the N2 flow rate to maintain stoichiometry, the film stress was changed from ~ 100 MPa to > 3000 MPa and the Qi of CPW resonators made from these films increased from ~104 to ~106 for single photon excitations measured at ~ 100 mK. In this talk, we discuss relationships between deposition parameters, film properties, and microwave electrodynamic responses in these resonators. S. O. acknowledges the Japan Society for the Promotion of Sciences (JSPS) for a Postdoctoral Fellowship for Research Abroad.

  8. Laser-induced breakdown spectroscopy to monitor ion cyclotron range of frequency wall cleaning Li/D co-deposition in EAST tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Liu, P.; Wu, D.; Sun, L.Y.; Zhao, D.Y.; Hai, R.; Li, C. [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Chinese Ministry of Education, School of Physics and Optical Electronic Technology, Dalian University of Technology, Dalian, 116024 (China); Ding, H., E-mail: hding@dlut.edu.cn [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Chinese Ministry of Education, School of Physics and Optical Electronic Technology, Dalian University of Technology, Dalian, 116024 (China); Hu, Z.H.; Wang, L.; Hu, J.S.; Chen, J.L.; Luo, G.N. [Institute of Plasma Physics, Chinese Academy of Sciences, P.O. Box 1126, Hefei, Anhui 230031 (China)

    2017-05-15

    Highlights: • LIBS was applied to EAST for monitoring the cleaning performance of the first wall using He-ICRF cleaning. • The cleaning performance is effective under helium ambient gas and some measurements have been obtained. • The results also indicate that the influence of magnetic field on LIBS signal is much stronger in helium ambient gas. • The effect of delay time and laser fluence on the LIBS signal has been investigated. - Abstract: In this paper, laser-induced breakdown spectroscopy (LIBS) under magnetic field condition has been studied in laboratory and EAST tokamak. The experimental results reveal that in helium ambient gas, the magnetic field significantly enhances the LIBS signal intensity (∼3 times). The effect of time delay and laser fluence on the intensity of LIBS has been investigated for optimizing the signal to background ratio (S/B). The developed LIBS approach has been applied to monitor the cleaning performance of the first wall in the fusion device of EAST using the ion cyclotron range of frequency (ICRF). The experimental results demonstrate that the cleaning performance for Li/D co-deposition layer is effective under helium ambient gas. The removing rate of Li on the surface of W tile is faster than that on Mo tile in He-ICRF cleaning and the D/(D + H) ratio on Mo tile is higher by ∼1.2 times than that on W tile. This work would indicate the feasibility of using LIBS to monitor the wall cleaning processes in EAST tokamak.

  9. Spectroscopy of collective cyclotron and intersubband resonances of Quantum Hall systems in GaAs; Spektroskopie kollektiver Zyklotron- und Intersubband-Resonanzen von Quanten-Hall-Systemen in GaAs

    Energy Technology Data Exchange (ETDEWEB)

    Manger, Matthias

    2008-07-01

    This thesis is dedicated to the long wavelength collective excitations of quasi two-dimensional electron systems (Q2DEG) in GaAs under the influence of high magnetic fields. These excitations, which are classified into cyclotron resonances and magneto intersubband resonances, were experimentally investigated by means of far infrared Fourier spectroscopy. Cyclotron resonances were studied in a magnetic field range 0cyclotron resonance in the presence of polaron coupling, bands nonparabolicity, and disorder under the combined influence of electronic screening and electron-electron coupling. The magneto intersubband resonances were investigated in the regime of the Integral Quantum Hall Effect. The grating coupler technique was used in order to couple the electromagnetic field to these collective excitations. Self consistent calculations of the subband structure and the collective modes were performed in the framework of the Hartree-Fock approximation scheme. These calculations were used for an interpretation of the experimental observations. (orig.)

  10. CLOVERLEAF CYCLOTRON

    Science.gov (United States)

    McMillan, E.M.; Judd, D.L.

    1959-02-01

    A cyclotron is presented embodying a unique magnetic field configuration, which configuration increases in intensity with radius and therefore compensates for the reltivistic mass effect, the field having further convolutions productive of axial stability in the particle beam. By reconciling the seemingly opposed requirements of mass increase compensation on one hand and anial stability on the other, the production of extremely high current particle beams in the relativistie energy range is made feasible. Certain further advantages inhere in the invention, notably an increase in the usable magnet gap, simplified and more efficient extraction of the beam from the accelerator, and ready adaptation to the use of multiply phased excitation as contrasted with the single phased systems herstofore utilized. General

  11. Wafer-Scale Aluminum Nanoplasmonic Resonators with Optimized Metal Deposition

    Science.gov (United States)

    2016-01-04

    Tittl, A.; Michel , A.-K. U.; Schaferling, M.; Yin, X.; Gholipour, B.; Cui, L.; Wuttig, M.; Taubner, T.; Neubrech, F.; Giessen, H. A Switchable Mid...surface plasmon resonances in aluminum nanodisks. Nano Letters 2008, 8, 1461-1471. 41. Chu, Y.; Crozier , K. B. Experimental study of the interaction

  12. Reflection and backscattering of microwaves under doubling of the plasma density and displacement of the gyroresonance region during electron cyclotron resonance heating of plasma in the l-2M stellarator

    Energy Technology Data Exchange (ETDEWEB)

    Batanov, G. M.; Borzosekov, V. D.; Vasilkov, D. G.; Kolik, L. V.; Konchekov, E. M., E-mail: konchekov@fpl.gpi.ru; Malakhov, D. V.; Vafin, I. Yu.; Petrov, A. E.; Sarksyan, K. A.; Sakharov, A. S.; Stepakhin, V. D.; Kharchev, N. K. [Russian Academy of Sciences, Prokhorov General Physics Institute (Russian Federation)

    2016-08-15

    Reflection and backscattering of high-power (400 kW) gyrotron radiation creating and heating plasma at the second harmonic of the electronic cyclotron frequency in the L-2M stellarator have been investigated experimentally. The effect of the displacement of the gyroresonance region from the axis of the plasma column under doubling of the plasma density on the processes of reflection and backscattering of microwave radiation has been examined. A near doubling of short-wavelength (k{sub ⊥} ≈ 30 cm{sup –1}) turbulent density fluctuations squared is observed. The change in the energy confinement time under variations of plasma parameters and characteristics of short-wavelength turbulence is discussed. A discrepancy between the measured values of the reflection coefficient from the electron cyclotron resonance heating region and predictions of the one-dimensional model is revealed.

  13. Dimer ion formation and intermolecular fragmentation of 1,2-diacylglycerols revealed by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry for more comprehensive lipid analysis.

    Science.gov (United States)

    Müller, Constanze; Kanawati, Basem; Rock, Theresa M; Forcisi, Sara; Moritz, Franco; Schmitt-Kopplin, Philippe

    2014-08-15

    The ionization of neutral diacylglycerols (DAGs) by electrospray ionization mass spectrometry (ESI-MS) is challenging compared with other lipid classes which possess ionic head group conjugations. Although ESI-MS is the method of choice in lipidomic analysis, it is questionable whether all lipid classes can be efficiently ionized by this method. Actually, various lipids were not efficiently detected (due to poor ionization) in many studies which claimed to comprehensively describe lipid profiles. Since neutral lipids are precursors for the biosynthesis of most other lipid classes, the necessity for improved or alternative ionization and identification schemes becomes obvious. We identified the 1,2-diacylglycerol (DAG) dimer ion formation in the gas phase by ultra-high-resolution Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) in negative electrospray ionization ((-)ESI) mode. The geometry of the dimer ion was investigated by accurate density functional theory (DFT) calculations at the B3LYP/6-311+G(d)//B3LYP/LANL2DZ level of theory. Fragmentation of the dimer ions of many investigated DAGs has been achieved via collision-induced dissociation (CID) experiments with several elevated collision energies (0-12 eV). We revealed the possibility to ionize neutral DAGs as dimer ions in the negative ESI mode. Quantum mechanical calculations revealed a polar head-to-head intermolecular interaction between one charged DAG and one DAG neutral. This represents an energy minimum structure for the DAG dimer ions. We could furthermore detect CID fragmentation product ions that can only result from intermolecular reactions in this head-to-head conformation (SN2 nucleophilic substitution reactions inside the dimer DAG ion). Here, we present for the first time the opportunity to ionize and identify DAGs as dimer ions. This new finding provides a new alternative for investigations of important diacylglycerol lipids and provides the opportunity to obtain

  14. Chemical Composition of Microbe-Derived Dissolved Organic Matter in Cryoconite in Tibetan Plateau Glaciers: Insights from Fourier Transform Ion Cyclotron Resonance Mass Spectrometry Analysis.

    Science.gov (United States)

    Feng, Lin; Xu, Jianzhong; Kang, Shichang; Li, Xiaofei; Li, Yang; Jiang, Bin; Shi, Quan

    2016-12-20

    Cryoconite in mountain glaciers plays important roles in glacial ablation and biogeochemical cycles. In this study, the composition and sources of dissolved organic matter (DOM) in cryoconite from the ablation regions of two Tibetan Plateau glaciers were determined using electrospray ionization (ESI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) and fluorescence spectrometry. A marked absorbance between 300 and 350 nm in the DOM absorption spectra was observed which was consistent with microbe-derived mycosporine-like amino acids. Fluorescence excitation-emission matrices showed that DOM had intense signals at protein-like substance peaks and weak signals at humic-like substance peaks. The high-resolution mass spectra of FT-ICR-MS showed cryoconite DOM from both glaciers contained diverse lignins, lipids, proteins, and unsaturated hydrocarbons. The lipids and proteins were consistent with material from microbial sources, and the lignins and unsaturated hydrocarbons were probably from vascular plant material supplied in atmospheric aerosols and debris from around the glaciers. Almost one-third of the identified DOM molecules had low C/N ratios (≤20), indicating their high bioavailability. Using a conservative cryoconite distribution on Chinese mountain glacier surfaces (6%) and an average debris mass per square meter of cryoconite (292 ± 196 g m-2), we found that the amount of DOC produced in cryoconite on Chinese glaciers as much as 0.23 ± 0.1 Gg per cryoconite formation process. This dissolved organic carbon may absorb solar radiation, accelerate glacial melting, and be an important source of bioavailable DOM to proglacial and downstream aquatic ecosystems.

  15. Synthesis of model humic substances: a mechanistic study using controllable H/D exchange and Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Zherebker, Alexander Ya; Airapetyan, David; Konstantinov, Andrey I; Kostyukevich, Yury I; Kononikhin, Alexey S; Popov, Igor A; Zaitsev, Kirill V; Nikolaev, Eugene N; Perminova, Irina V

    2015-07-07

    The products of the oxidative coupling of phenols are frequently used as synthetic analogues to natural humic substances (HS) for biomedical research. However, their molecular compositions and exact structures remain largely unknown. The objective of this study was to develop a novel approach for the molecular-level analysis of phenolic polymerisates that is capable of inventorying molecular constituents and resolving their distinct structural formulas. For this purpose, we have synthesized the model HS using the oxidative coupling of a specifically designed phenylpropanoic monomer, 3-(4-hydroxy-3-methoxyphenyl)-3-oxopropionic acid, to hydroquinone. We have characterized the synthesized model HS using high resolution Fourier transform ion cyclotron resonance mass spectrometry (FTICR MS), (1)H NMR spectroscopy, and controllable hydrogen/deuterium (H/D) exchange. We succeeded in the molecular inventory of the model HS. The assigned molecular formulas occupied the substantial space of CHO compositions in the Van Krevelen diagram with a maximum density found in the regions of tannins and lignins, resembling those of natural HS. To identify the exact structural formulas of the individual constituents in the model HS, we have applied selective H/D exchange of non-labile backbone protons by a choice of basic or acidic catalytic conditions followed by FTICR MS. The determined formulas allowed us to verify the proposed pathways of hydroxylation and carboxylation in the course of the phenolic coupling and to identify the acetylation of aromatic rings as an important side reaction. We conclude that the proposed analytical approach may be used to identify the molecular carriers of biological activity within the phenolic polymerisates and eventually within natural HS.

  16. Closure of multi-fluid and kinetic equations for cyclotron-resonant interactions of solar wind ions with Alfvén waves

    Directory of Open Access Journals (Sweden)

    E. Marsch

    1998-01-01

    Full Text Available Based on quasilinear theory, a closure scheme for anisotropic multi-component fluid equations is developed for the wave-particle interactions of ions with electromagnetic Alfvén and ion-cyclotron waves propagating along the mean magnetic field. Acceleration and heating rates are calculated. They may be used in the multi-fluid momentum and energy equations as anomalous transport terms. The corresponding evolution equation for the average wave spectrum is established, and the effective growth/damping rate for the spectrum is calculated. Given a simple power-law spectrum, an anomalous collision frequency can be derived which depends on the slope and average intensity of the spectrum, and on the gyrofrequency and the differential motion (with respect to the wave frame of the actual ion species considered. The wave-particle interaction terms attain simple forms resembling the ones for collisional friction and temperature anisotropy relaxation (due to pitch angle scattering with collision rates that are proportional to the gyrofrequency but diminished substantially by the relative wave energy or the fluctuation level with respect the background field. In addition, a set of quasilinear diffusion equations is derived for the reduced (with respect to the perpendicular velocity component velocity distribution functions (VDFs, as they occur in the wave dispersion equation and the related dielectric function for parallel propagation. These reduced VDFs allow one to describe adequately the most prominent observed features, such as an ion beam and temperature anisotropy, in association with the resonant interactions of the particles with the waves on a kinetic level, yet have the advantage of being only dependent upon the parallel velocity component.

  17. Observation of CO2 and solvent adduct ions during negative mode electrospray ionization Fourier transform ion cyclotron resonance mass spectrometric analysis of monohydric alcohols.

    Science.gov (United States)

    Zhou, Xibin; Zhang, Yahe; Zhao, Suoqi; Hsu, Chang Samuel; Shi, Quan

    2013-12-15

    Monohydric alcohols are common in natural products, bio-oils, and medicine. We have found that monohydric alcohols can form O3 (ions containing three oxygen atoms) and O4 adduct ions in negative electrospray ionization (ESI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS), which would significantly affect the composition analysis of alcohols, especially in a complex mixture. It is necessary to study the reaction pathways and the method to eliminate or reduce the 'artifact' adducts. Octadecanol, cholesterol, squalanol and two complex monohydric alcohol mixtures were selected as model compounds. These samples were subjected to negative ion ESI FT-ICR MS analysis. The composition and formation mechanism of adducts were studied by the ultrahigh-resolution accurate mass measurement for elemental composition, along with the MS(2) isolation and collision-induced dissociation (CID) experiments for structural determination. The reaction pathway of O3 adduct formation is the coupling of a monohydric alcohol ion with a CO2 to form a stable O3 ionic species by likely a covalent bond (source of CO2 is not clear). The O4 species are formed by O3 ionic species adducted with an alcohol molecule of the solvent, such as methanol or ethanol, by likely a hydrogen bond. These adduct ions could be eliminated or reduced by increasing collision energy. However, excessive collision energy would fragment monohydric alcohol ions. The formation mechanisms of O3 and O4 adducts from monohydric alcohols in negative ion ESI FT-ICR MS were proposed. The solvent adduction effects can be eliminated or reduced by optimizing the collision energy of CID in FT-ICR MS. Copyright © 2013 John Wiley & Sons, Ltd.

  18. The effect of cavity tuning on oxygen beam currents of an A-ECR type 14 GHz electron cyclotron resonance ion source

    Energy Technology Data Exchange (ETDEWEB)

    Tarvainen, O., E-mail: olli.tarvainen@jyu.fi; Orpana, J.; Kronholm, R.; Kalvas, T.; Laulainen, J.; Koivisto, H. [Department of Physics (JYFL), University of Jyväskylä, 40500 Jyväskylä (Finland); Izotov, I.; Skalyga, V. [Institute of Applied Physics, RAS, 46 Ul’yanova St., 603950 Nizhny Novgorod (Russian Federation); Lobachevsky State University of Nizhny Novgorod (UNN), 23 Gagarina St., 603950 Nizhny Novgorod (Russian Federation); Toivanen, V. [European Organization for Nuclear Research (CERN), 1211 Geneva 23 (Switzerland)

    2016-09-15

    The efficiency of the microwave-plasma coupling plays a significant role in the production of highly charged ion beams with electron cyclotron resonance ion sources (ECRISs). The coupling properties are affected by the mechanical design of the ion source plasma chamber and microwave launching system, as well as damping of the microwave electric field by the plasma. Several experiments attempting to optimize the microwave-plasma coupling characteristics by fine-tuning the frequency of the injected microwaves have been conducted with varying degrees of success. The inherent difficulty in interpretation of the frequency tuning results is that the effects of microwave coupling system and the cavity behavior of the plasma chamber cannot be separated. A preferable approach to study the effect of the cavity properties of the plasma chamber on extracted beam currents is to adjust the cavity dimensions. The results of such cavity tuning experiments conducted with the JYFL 14 GHz ECRIS are reported here. The cavity properties were adjusted by inserting a conducting tuner rod axially into the plasma chamber. The extracted beam currents of oxygen charge states O{sup 3+}–O{sup 7+} were recorded at various tuner positions and frequencies in the range of 14.00–14.15 GHz. It was observed that the tuner position affects the beam currents of high charge state ions up to several tens of percent. In particular, it was found that at some tuner position / frequency combinations the plasma exhibited “mode-hopping” between two operating regimes. The results improve the understanding of the role of plasma chamber cavity properties on ECRIS performances.

  19. Coumarins as new matrices for matrix-assisted laser-desorption/ionization Fourier transform ion cyclotron resonance mass spectrometric analysis of hydrophobic compounds

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Hang, E-mail: hangwang@sjtu.edu.cn [Instrumental Analysis Center, Shanghai Jiao Tong University, Dongchuan Road 800, Shanghai 200240 (China); Dai, Bona [Instrumental Analysis Center, Shanghai Jiao Tong University, Dongchuan Road 800, Shanghai 200240 (China); Liu, Bin [Key Laboratory of Kidney Disease Pathogenesis and Intervention of Hubei Province, College of Medicine, Hubei Polytechnic University, Huangshi, Hubei 435003 (China); Lu, Han [Department of Anesthesiology, Ruijin Hospital, Shanghai Jiao Tong University School of Medicine (SJTU-SM), 197, Rui Jin Er Road, Shanghai 200025 (China)

    2015-07-02

    Highlights: • Coumarins were used as new MALDI matrices. • Coumarins were used for MALDI-FT ICR MS detection of hydrophobic compounds. • DCA had improvement in detection sensitivity, stability, selectivity and reproducibility. • DCA was applied to sterols detection in yeast cells. - Abstract: Hydrophobic compounds with hydroxyl, aldehyde or ketone groups are generally difficult to detect using matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS), because these compounds have low proton affinity and are poorly ionized by MALDI. Herein, coumarins have been used as new matrices for MALDI-MS analysis of a variety of hydrophobic compounds with low ionization efficiency, including steroids, coenzyme Q10, a cyclic lipopeptide and cholesterol oleate. Five coumarins, including coumarin, umbelliferone, esculetin, 7-hydroxycoumarin-3-carboxylic acid (HCA) and 6,7-dihydroxycoumarin-3-carboxylic acid (DCA), were compared with the conventional matrices of 2,5-dihydroxybenzoic acid (DHB) and α-cyano-4-hydroxycinnamic acid (CHCA). Coumarins with hydroxyl or carboxylic acid groups enabled detection. Taking DCA as an example, this matrix proved to be superior to DHB or CHCA in detection sensitivity, stability, spot-to-spot and sample-to-sample reproducibility, and accuracy. DCA increased the stability of the target compounds and decreased the loss of water. The [M + Na]{sup +} peaks were observed for all target compounds by adding NaCl as an additive, and the [M − H{sub 2}O + H]{sup +} and [M + H]{sup +} peaks decreased. DCA was selected for the identification of sterols in yeast cells, and thirteen sterols were detected by Fourier transform ion cyclotron resonance (FT ICR) mass spectrometry. This work demonstrates the potential of DCA as a new matrix for detection of hydrophobic molecules by MALDI-MS and provides an alternative tool for screening sterols in antifungal research.

  20. Technical Note: Molecular characterization of aerosol-derived water soluble organic carbon using ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry

    Directory of Open Access Journals (Sweden)

    R. M. Dickhut

    2008-09-01

    Full Text Available Despite the acknowledged relevance of aerosol-derived water-soluble organic carbon (WSOC to climate and biogeochemical cycling, characterization of aerosol WSOC has been limited. Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS was utilized in this study to provide detailed molecular level characterization of the high molecular weight (HMW; m/z>223 component of aerosol-derived WSOC collected from rural sites in Virginia and New York, USA. More than 3000 peaks were detected by ESI FT-ICR MS within a m/z range of 223–600 for each sample. Approximately 86% (Virginia and 78% (New York of these peaks were assigned molecular formulas using only carbon (C, hydrogen (H, oxygen (O, nitrogen (N, and sulfur (S as elemental constituents. H/C and O/C molar ratios were plotted on van Krevelen diagrams and indicated a strong contribution of lignin-like and lipid-like compounds to the aerosol-derived WSOC samples. Approximately 1–4% of the peaks in the aerosol-derived WSOC mass spectra were classified as black carbon (BC on the basis of double bond equivalents calculated from the assigned molecular formulas. In addition, several high-magnitude peaks in the mass spectra of samples from both sites corresponded to molecular formulas proposed in previous secondary organic aerosol (SOA laboratory investigations indicating that SOAs are important constituents of the WSOC. Overall, ESI FT-ICR MS provides a level of resolution adequate for detailed compositional and source information of the HMW constituents of aerosol-derived WSOC.

  1. Rapid Profiling of Bovine and Human Milk Gangliosides by Matrix-Assisted Laser Desorption/Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry.

    Science.gov (United States)

    Lee, Hyeyoung; An, Hyun Joo; Lerno, Larry A; German, J Bruce; Lebrilla, Carlito B

    2011-08-15

    Gangliosides are anionic glycosphingolipids widely distributed in vertebrate tissues and fluids. Their structural and quantitative expression patterns depend on phylogeny and are distinct down to the species level. In milk, gangliosides are exclusively associated with the milk fat globule membrane. They may participate in diverse biological processes but more specifically to host-pathogen interactions. However, due to the molecular complexities, the analysis needs extensive sample preparation, chromatographic separation, and even chemical reaction, which makes the process very complex and time-consuming. Here, we describe a rapid profiling method for bovine and human milk gangliosides employing matrix-assisted desorption/ionization (MALDI) Fourier transform ion cyclotron resonance (FTICR) mass spectrometry (MS). Prior to the analyses of biological samples, milk ganglioside standards GM3 and GD3 fractions were first analyzed in order to validate this method. High mass accuracy and high resolution obtained from MALDI FTICR MS allow for the confident assignment of chain length and degree of unsaturation of the ceramide. For the structural elucidation, tandem mass spectrometry (MS/MS), specifically as collision-induced dissociation (CID) and infrared multiphoton dissociation (IRMPD) were employed. Complex ganglioside mixtures from bovine and human milk were further analyzed with this method. The samples were prepared by two consecutive chloroform/methanol extraction and solid phase extraction. We observed a number of differences between bovine milk and human milk. The common gangliosides in bovine and human milk are NeuAc-NeuAc-Hex-Hex-Cer (GD3) and NeuAc-Hex-Hex-Cer (GM3); whereas, the ion intensities of ganglioside species are different between two milk samples. Kendrick mass defect plot yields grouping of ganglioside peaks according to their structural similarities. Gangliosides were further probed by tandem MS to confirm the compositional and structural assignments

  2. Characterization of organic aerosol in Beijing by laser desorption ionization coupled with Fourier Transform Ion Cyclotron Resonance Mass spectrometry

    Science.gov (United States)

    Xue, Jinjuan; Li, Yafeng; Xie, Xiaobo; Xiong, Caiqiao; Liu, Huihui; Chen, Suming; Nie, Zongxiu; Chen, Chuncheng; Zhao, Jincai

    2017-06-01

    In order to resolve the organic compositions in the atmospheric aerosol which is significant for understanding the formation mechanism of particulate matter and their harm for human health, a direct laser desorption ionization (LDI) coupled with Fourier Transform Resonance Mass (FT-ICR MS) was utilized for characterizing the aerosol particles collected in Beijing during winter. A lot of organic compounds can be detected by direct laser desorption ionization of the aerosol particular with different size collected on aluminum foil without complicated sample pretreatment process. In addition, semi quantification of the organic compounds can be achieved with solvent extraction procedure. It was found that the ubiquitous polycyclic aromatic hydrocarbons (PAHs) contaminants in the aerosol could serve as matrix, which helps the detection of many kinds of compounds including highly saturated amphiphilic long alkyl chain compounds (carbon number>16), like aliphatic amines in positive ion mode and organosulfates in negative ion mode. Based on the accurate mass measurement results, elemental compositions of over 1500 peaks in the mass spectrum were derived, and we categorized them into five groups according to their elemental compositions in order to provide helpful information for tracing the pollution source. It is demonstrated that abundant information about the organic components in the atmospheric aerosol can be provided by direct LDI FT-ICR MS method, and these information will largely facilitate further studies on origin and formation process of the aerosol.

  3. Advanced light ion source extraction system for a new electron cyclotron resonance ion source geometry at Saclay

    Energy Technology Data Exchange (ETDEWEB)

    Delferriere, O.; Gobin, R.; Harrault, F.; Nyckees, S.; Sauce, Y.; Tuske, O. [Commissariat a l' Energie Atomique, CEA/Saclay, DSM/IRFU, 91191 Gif/Yvette (France)

    2012-02-15

    One of the main goal of intense light ion injector projects such as IPHI, IFMIF, or SPIRAL2, is to produce high current beams while keeping transverse emittance as low as possible. To prevent emittance growth induced in a dual solenoid low energy transfer line, its length has to be minimized. This can be performed with the advanced light ion source extraction system concept that we are developing: a new ECR 2.45 GHz type ion source based on the use of an additional low energy beam transport (LEBT) short length solenoid close to the extraction aperture to create the resonance in the plasma chamber. The geometry of the source has been considerably modified to allow easy maintenance of each component and to save space in front of the extraction. The source aims to be very flexible and to be able to extract high current ion beams at energy up to 100 kV. A specific experimental setup for this source is under installation on the BETSI test bench, to compare its performances with sources developed up to now in the laboratory, such as SILHI, IFMIF, or SPIRAL2 ECR sources. This original extraction source concept is presented, as well as electromagnetic simulations with OPERA-2D code. Ion beam extraction in space charge compensation regime with AXCEL, and beam dynamics simulation with SOLMAXP codes show the beam quality improvement at the end of the LEBT.

  4. Advanced light ion source extraction system for a new electron cyclotron resonance ion source geometry at Saclay.

    Science.gov (United States)

    Delferrière, O; Gobin, R; Harrault, F; Nyckees, S; Sauce, Y; Tuske, O

    2012-02-01

    One of the main goal of intense light ion injector projects such as IPHI, IFMIF, or SPIRAL2, is to produce high current beams while keeping transverse emittance as low as possible. To prevent emittance growth induced in a dual solenoid low energy transfer line, its length has to be minimized. This can be performed with the advanced light ion source extraction system concept that we are developing: a new ECR 2.45 GHz type ion source based on the use of an additional low energy beam transport (LEBT) short length solenoid close to the extraction aperture to create the resonance in the plasma chamber. The geometry of the source has been considerably modified to allow easy maintenance of each component and to save space in front of the extraction. The source aims to be very flexible and to be able to extract high current ion beams at energy up to 100 kV. A specific experimental setup for this source is under installation on the BETSI test bench, to compare its performances with sources developed up to now in the laboratory, such as SILHI, IFMIF, or SPIRAL2 ECR sources. This original extraction source concept is presented, as well as electromagnetic simulations with OPERA-2D code. Ion beam extraction in space charge compensation regime with AXCEL, and beam dynamics simulation with SOLMAXP codes show the beam quality improvement at the end of the LEBT.

  5. Dispersion engineered high-Q silicon Nitride Ring-Resonators via Atomic Layer Deposition

    CERN Document Server

    Riemensberger, Johann; Herr, Tobias; Brasch, Victor; Holzwarth, Ronald; Kippenberg, Tobias J

    2012-01-01

    We demonstrate dispersion engineering of integrated silicon nitride based ring resonators through conformal coating with hafnium dioxide deposited on top of the structures via atomic layer deposition (ALD). Both, magnitude and bandwidth of anomalous dispersion can be significantly increased. All results are confirmed by high resolution frequency-comb-assisted-diode-laser spectroscopy and are in very good agreement with the simulated modification of the mode spectrum.

  6. V.U.V. plasma spectroscopy diagnostic of electron cyclotron resonance multicharged ion sources; Diagnostic de plasmas crees dans des sources d'ions multicharges a resonance cyclotronique electronique par spectroscopie V.U.V

    Energy Technology Data Exchange (ETDEWEB)

    Berreby, R

    1997-12-15

    To characterize the multicharged ions within the plasma of an E.C.R. ion source, the V.U.V. spectroscopy is used as a non invasive diagnostic of excited matter. In E.C.R.I. S. (electron cyclotron resonance ion source) electrons are heated and magnetically confined within the mirror machine to overcome the successive ionization potentials of the desired elements. As the electrons bounce inside the magnetic configuration in their gyration movement, they interact with the microwaves injected into the source at the resonance frequency. To enhance the performances in high charge states and extracted currents delivered by E.C.R.I.S., the fundamental parameters of the plasma created in these machines must be known. The goal of spectroscopic diagnostics in the V.U.V. range installed on the sources is to determine electron density and temperature on one hand, and the ionic densities and confinement time on the other hand. We used microchannel plates as detector on a 3 meter grazing incidence spectrometer equipped with a 600 lines/mm holographic grating. The calibration of the whole grating with detector was performed by two different methods. These are the branching ratio and charge exchange methods. Identification of lines emitted by a plasma, which gather the whole charge states of ions is necessary to make an exhaustive study of the plasma state. And finally, the determination of plasma parameters like electron density and temperature and ion densities and confinement times that uses theoretical models were the aim of this work. (author)

  7. Numerical solution of the Maxwell-Vlasov equations in the periodic regime. Application to the study of isotope separation by ion cyclotron resonance; Resolution numerique des equations de Maxwell-Vlasov en regime periodique. Application a l'etude de la separation isotopique par resonance cyclotron ionique

    Energy Technology Data Exchange (ETDEWEB)

    Omnes, P

    1999-01-25

    This work is dedicated to the study of the behaviour of a magnetic confined plasma that is excited by a purely sinusoidal electric current delivered by an antenna. The response of the electrons to the electromagnetic field is considered as linear,whereas the ions of the plasma are represented by a non-relativistic Vlasov equation. In order to avoid transients, the coupled Maxwell-Vlasov equations are solved in a periodic mode and in a bounded domain. An equivalent electric conductivity tensor has been defined, this tensor is a linear operator that links the electric current generated by the movement of the particles to the electromagnetic field. Theoretical considerations can assure the existence and uniqueness of a periodical solution to Vlasov equations and of a solution to Maxwell equations in harmonic mode. The system of equations is periodical and has been solved by using an iterative method. The application of this method to the simulation of a isotopic separation device based on ionic cyclotron resonance has shown that the convergence is reached in a few iterations and that the solution is valid. Furthermore a method based on a finite-volume formulation of Maxwell equations in the time domain is presented. 2 new variables are defined in order to better take into account the Gauss' law and the conservation of the magnetic flux, the new system is still hyperbolic. The parallelization of the process has been successfully realized. (A.C.)

  8. Simultaneous molecular formula determinations of natural compounds in a plant extract using 15 T Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Park, Kyu Hwan; Kim, Min Sun; Baek, Sun Jong; Bae, Ik Hyun; Seo, Sang-Wan; Kim, Jongjin; Shin, Yong Kook; Lee, Yong-Moon; Kim, Hyun Sik

    2013-01-01

    Plant extracts are a reservoir of pharmacologically active substances; however, conventional analytical methods can analyze only a small portion of an extract. Here, we report a high-throughput analytical method capable of determining most phytochemicals in a plant extract and of providing their molecular formulae from a single experiment using ultra-high-resolution electrospray ionization mass spectrometry (UHR ESI MS). UHR mass profiling was used to analyze natural compounds in a 70% ethanol ginseng extract, which was directly infused into a 15 T Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer for less than 10 min without a separation process. The UHR FT-ICR MS yielded a mass accuracy of 0.5 ppm and a mass resolving power (m/Δm) of 1,000,000-270,000 for the range m/z 290-1,100. The mass resolution was sufficient to resolve the isotopic fine structure (IFS) of many compounds in the extract. After noise removal from 1,552 peaks, 405 compounds were detected. The molecular formulae of 123 compounds, including 33 ginsenosides, were determined using the observed IFS, exact monoisotopic mass, and exact mass difference. Liquid chromatography (LC)/FT-ICR MS of the extract was performed to compare the high-throughput performance of UHR ESI FT-ICR MS. The LC/FT-ICR MS detected only 129 compounds, including 19 ginsenosides. The result showed that UHR ESI FT-ICR MS identified three times more compounds than LC/FT-ICR MS and in a relatively shorter time. The molecular formula determination by UHR FT-ICR MS was validated by LC and tandem MS analyses of three known ginsenosides. UHR mass profiling of a plant extract by 15 T FT-ICR MS showed that multiple compounds were simultaneously detected and their molecular formulae were decisively determined by a single experiment with ultra-high mass resolution and mass accuracy. Simultaneous molecular determination of multiple natural products by UHR ESI FT-ICR MS would be a powerful method to profile a wide

  9. Correlation of III/V semiconductor etch results with physical parameters of high-density reactive plasmas excited by electron cyclotron resonance

    Science.gov (United States)

    Gerhard, FRANZ; Ralf, MEYER; Markus-Christian, AMANN

    2017-12-01

    Reactive ion etching is the interaction of reactive plasmas with surfaces. To obtain a detailed understanding of this process, significant properties of reactive composite low-pressure plasmas driven by electron cyclotron resonance (ECR) were investigated and compared with the radial uniformity of the etch rate. The determination of the electronic properties of chlorine- and hydrogen-containing plasmas enabled the understanding of the pressure-dependent behavior of the plasma density and provided better insights into the electronic parameters of reactive etch gases. From the electrical evaluation of I(V) characteristics obtained using a Langmuir probe, plasmas of different compositions were investigated. The standard method of Druyvesteyn to derive the electron energy distribution functions by the second derivative of the I(V) characteristics was replaced by a mathematical model which has been evolved to be more robust against noise, mainly, because the first derivative of the I(V) characteristics is used. Special attention was given to the power of the energy dependence in the exponent. In particular, for plasmas that are generated by ECR with EM modes, the existence of Maxwellian distribution functions is not to be taken as a self-evident fact, but the bi-Maxwellian distribution was proven for Ar- and Kr-stabilized plasmas. In addition to the electron temperature, the global uniform discharge model has been shown to be useful for calculating the neutral gas temperature. To what extent the invasive method of using a Langmuir probe could be replaced with the non-invasive optical method of emission spectroscopy, particularly actinometry, was investigated, and the resulting data exhibited the same relative behavior as the Langmuir data. The correlation with etchrate data reveals the large chemical part of the removal process—most striking when the data is compared with etching in pure argon. Although the relative amount of the radial variation of plasma density and

  10. A hybrid electron cyclotron resonance metal ion source with integrated sputter magnetron for the production of an intense Al{sup +} ion beam

    Energy Technology Data Exchange (ETDEWEB)

    Weichsel, T., E-mail: tim.weichsel@fep.fraunhofer.de; Hartung, U.; Kopte, T. [Fraunhofer Institute for Organic Electronics, Electron Beam and Plasma Technology FEP, 01277 Dresden (Germany); Zschornack, G. [Institute of Solid State Physics, Dresden University of Technology, 01062 Dresden, Germany and Helmholtz-Zentrum Dresden-Rossendorf e.V., Institute of Ion Beam Physics and Materials Research, Dresden (Germany); Kreller, M.; Philipp, A. [DREEBIT GmbH, 01900 Grossroehrsdorf (Germany)

    2015-09-15

    A metal ion source prototype has been developed: a combination of magnetron sputter technology with 2.45 GHz electron cyclotron resonance (ECR) ion source technology—a so called magnetron ECR ion source (MECRIS). An integrated ring-shaped sputter magnetron with an Al target is acting as a powerful metal atom supply in order to produce an intense current of singly charged metal ions. Preliminary experiments show that an Al{sup +} ion current with a density of 167 μA/cm{sup 2} is extracted from the source at an acceleration voltage of 27 kV. Spatially resolved double Langmuir probe measurements and optical emission spectroscopy were used to study the plasma states of the ion source: sputter magnetron, ECR, and MECRIS plasma. Electron density and temperature as well as Al atom density were determined as a function of microwave and sputter magnetron power. The effect of ECR heating is strongly pronounced in the center of the source. There the electron density is increased by one order of magnitude from 6 × 10{sup 9} cm{sup −3} to 6 × 10{sup 10} cm{sup −3} and the electron temperature is enhanced from about 5 eV to 12 eV, when the ECR plasma is ignited to the magnetron plasma. Operating the magnetron at constant power, it was observed that its discharge current is raised from 1.8 A to 4.8 A, when the ECR discharge was superimposed with a microwave power of 2 kW. At the same time, the discharge voltage decreased from about 560 V to 210 V, clearly indicating a higher plasma density of the MECRIS mode. The optical emission spectrum of the MECRIS plasma is dominated by lines of excited Al atoms and shows a significant contribution of lines arising from singly ionized Al. Plasma emission photography with a CCD camera was used to prove probe measurements and to identify separated plasma emission zones originating from the ECR and magnetron discharge.

  11. Multicavity proton cyclotron accelerator

    Directory of Open Access Journals (Sweden)

    J. L. Hirshfield

    2002-08-01

    Full Text Available A mechanism for acceleration of protons is described, in which energy gain occurs near cyclotron resonance as protons drift through a sequence of rotating-mode TE_{111} cylindrical cavities in a strong nearly uniform axial magnetic field. Cavity resonance frequencies decrease in sequence from one another with a fixed frequency interval Δf between cavities, so that synchronism can be maintained between the rf fields and proton bunches injected at intervals of 1/Δf. An example is presented in which a 122 mA, 1 MeV proton beam is accelerated to 961 MeV using a cascade of eight cavities in an 8.1 T magnetic field, with the first cavity resonant at 120 MHz and with Δf=8 MHz. Average acceleration gradient exceeds 40 MV/m, average effective shunt impedance is 223 MΩ/m, but maximum surface field in the cavities does not exceed 7.2 MV/m. These features occur because protons make many orbital turns in each cavity and thus experience acceleration from each cavity field many times. Longitudinal and transverse stability appear to be intrinsic properties of the acceleration mechanism, and an example to illustrate this is presented. This acceleration concept could be developed into a proton accelerator for a high-power neutron spallation source, such as that required for transmutation of nuclear waste or driving a subcritical fission burner, provided a number of significant practical issues can be addressed.

  12. Advanced characterisation of organic matter in oil sands and tailings sands used for land reclamation by Fourier transform-ion cyclotron resonance-mass spectrometry (FT-ICR-MS)

    Science.gov (United States)

    Noah, M.; Vieth-Hillebrand, A.; Wilkes, H.

    2012-04-01

    subsequent separation into asphaltenes, aliphatic hydrocarbons, aromatic hydrocarbons, neutral nitrogen, sulphur, oxygen (NSO) compounds and carboxylic acids. The asphaltene fractions are analysed using pyrolysis-GC, all other fractions are analysed by GC-MS. Additionally Fourier transform-ion cyclotron resonance-mass spectrometry (FT-ICR-MS) is used to study the chemical composition of the samples on the molecular level using different ionisation methods.

  13. Cyclotron waves in plasma

    CERN Document Server

    Lominadze, D G

    2013-01-01

    Cyclotron Waves in Plasma is a four-chapter text that covers the basic physical concepts of the theory of cyclotron waves and cyclotron instabilities, brought about by the existence of steady or alternating plasma currents flowing perpendicular to the magnetic field.This book considers first a wide range of questions associated with the linear theory of cyclotron oscillations in equilibrium plasmas and in electron plasmas in metals and semiconductors. The next chapter deals with the parametric excitation of electron cyclotron oscillations in plasma in an alternating electric field. A chapter f

  14. Proposal and verification numerical simulation for a microwave forward scattering technique at upper hybrid resonance for the measurement of electron gyroscale density fluctuations in the electron cyclotron frequency range in magnetized plasmas

    Science.gov (United States)

    Kawamori, E.; Igami, H.

    2017-11-01

    A diagnostic technique for detecting the wave numbers of electron density fluctuations at electron gyro-scales in an electron cyclotron frequency range is proposed, and the validity of the idea is checked by means of a particle-in-cell (PIC) numerical simulation. The technique is a modified version of the scattering technique invented by Novik et al. [Plasma Phys. Controlled Fusion 36, 357-381 (1994)] and Gusakov et al., [Plasma Phys. Controlled Fusion 41, 899-912 (1999)]. The novel method adopts forward scattering of injected extraordinary probe waves at the upper hybrid resonance layer instead of the backward-scattering adopted by the original method, enabling the measurement of the wave-numbers of the fine scale density fluctuations in the electron-cyclotron frequency band by means of phase measurement of the scattered waves. The verification numerical simulation with the PIC method shows that the technique has a potential to be applicable to the detection of electron gyro-scale fluctuations in laboratory plasmas if the upper-hybrid resonance layer is accessible to the probe wave. The technique is a suitable means to detect electron Bernstein waves excited via linear mode conversion from electromagnetic waves in torus plasma experiments. Through the numerical simulations, some problems that remain to be resolved are revealed, which include the influence of nonlinear processes such as the parametric decay instability of the probe wave in the scattering process, and so on.

  15. Identification of chemical components in Baidianling Capsule based on gas chromatography-mass spectrometry and high-performance liquid chromatography combined with Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Wu, Wenying; Chen, Yu; Wang, Binjie; Sun, Xiaoyang; Guo, Ping; Chen, Xiaohui

    2017-08-01

    Baidianling Capsule, which is made from 16 Chinese herbs, has been widely used for treating vitiligo clinically. In this study, the sensitive and rapid method has been developed for the analysis of chemical components in Baidianling Capsule by gas chromatography-mass spectrometry in combination with retention indices and high-performance liquid chromatography combined with Fourier transform ion cyclotron resonance mass spectrometry. Firstly, a total of 110 potential volatile compounds obtained from different extraction procedures including alkanes, alkenes, alkynes, ketones, ethers, aldehydes, alcohols, phenols, organic acids, esters, furans, pyrrole, acid amides, heterocycles, and oxides were detected from Baidianling Capsule by gas chromatography-mass spectrometry, of which 75 were identified by mass spectrometry in combination with the retention index. Then, a total of 124 components were tentatively identified by high-performance liquid chromatography combined with Fourier transform ion cyclotron resonance mass spectrometry. Fifteen constituents from Baidianling Capsule were accurately identified by comparing the retention times with those of reference compounds, others were identified by comparing the retention times and mass spectrometry data, as well as retrieving the reference literature. This study provides a practical strategy for rapidly screening and identifying the multiple constituents of a complex traditional Chinese medicine. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. Unstable plasma characteristics in mirror field electron cyclotron ...

    Indian Academy of Sciences (India)

    Electron cyclotron plasma reactor are prone to instabilities in specific input power [3–. 7] region (150–450 watts). ... Electron cyclotron resonance (ECR) plasma technology has become very important for fabrication of very large scale ... left hand polarized (LHP) wave. Shufflbotham and Thomson [4] observed several distinct.

  17. Deposition of Methylammonium Lead Triiodide by Resonant Infrared Matrix-Assisted Pulsed Laser Evaporation

    Science.gov (United States)

    Barraza, E. Tomas; Dunlap-Shohl, Wiley A.; Mitzi, David B.; Stiff-Roberts, Adrienne D.

    2017-09-01

    Resonant infrared matrix-assisted pulsed laser evaporation (RIR-MAPLE) was used to deposit the metal-halide perovskite (MHP) CH3NH3PbI3 (methylammonium lead triiodide, or MAPbI), creating phase-pure films. Given the moisture sensitivity of these crystalline, multi-component organic-inorganic hybrid materials, deposition of MAPbI by RIR-MAPLE required a departure from the use of water-based emulsions as deposition targets. Different chemistries were explored to create targets that properly dissolved MAPbI components, were stable under vacuum conditions, and enabled resonant laser energy absorption. Secondary phases and solvent contamination in the resulting films were studied through Fourier transform infrared (FTIR) absorbance and x-ray diffraction (XRD) measurements, suggesting that lingering excess methylammonium iodide (MAI) and low-vapor pressure solvents can distort the microstructure, creating crystalline and amorphous non-perovskite phases. Thermal annealing of films deposited by RIR-MAPLE allowed for excess solvent to be evaporated from films without degrading the MAPbI structure. Further, it was demonstrated that RIR-MAPLE does not require excess MAI to create stoichiometric films with optoelectronic properties, crystal structure, and film morphology comparable to films created using more established spin-coating methods for processing MHPs. This work marks the first time a MAPLE-related technique was used to deposit MHPs.

  18. Deposition of Methylammonium Lead Triiodide by Resonant Infrared Matrix-Assisted Pulsed Laser Evaporation

    Science.gov (United States)

    Barraza, E. Tomas; Dunlap-Shohl, Wiley A.; Mitzi, David B.; Stiff-Roberts, Adrienne D.

    2018-02-01

    Resonant infrared matrix-assisted pulsed laser evaporation (RIR-MAPLE) was used to deposit the metal-halide perovskite (MHP) CH3NH3PbI3 (methylammonium lead triiodide, or MAPbI), creating phase-pure films. Given the moisture sensitivity of these crystalline, multi-component organic-inorganic hybrid materials, deposition of MAPbI by RIR-MAPLE required a departure from the use of water-based emulsions as deposition targets. Different chemistries were explored to create targets that properly dissolved MAPbI components, were stable under vacuum conditions, and enabled resonant laser energy absorption. Secondary phases and solvent contamination in the resulting films were studied through Fourier transform infrared (FTIR) absorbance and x-ray diffraction (XRD) measurements, suggesting that lingering excess methylammonium iodide (MAI) and low-vapor pressure solvents can distort the microstructure, creating crystalline and amorphous non-perovskite phases. Thermal annealing of films deposited by RIR-MAPLE allowed for excess solvent to be evaporated from films without degrading the MAPbI structure. Further, it was demonstrated that RIR-MAPLE does not require excess MAI to create stoichiometric films with optoelectronic properties, crystal structure, and film morphology comparable to films created using more established spin-coating methods for processing MHPs. This work marks the first time a MAPLE-related technique was used to deposit MHPs.

  19. Influence of resonant magnetic perturbations on transient heat load deposition and fast ion losses

    Energy Technology Data Exchange (ETDEWEB)

    Rack, Michael Thomas

    2014-07-11

    Thermonuclear fusion is the energy conversion process which keeps the sun shining. For the last six decades, researchers have been investigating the physics involved in order to enable the usage of this energy supply on Earth. The most promising candidates for fusion power plants are based on magnetic confinement of plasma to provide the ideal conditions for efficient thermonuclear fusion in well controlled surroundings. One important aspect is the control of instabilities that occur in the edge region of the plasma and lead to an ejection of huge amounts of energy. Magnetic perturbation fields which are resonant in the plasma edge are found to modify the plasma favourably and reduce the impact of these instabilities. This dissertation focuses on the effects of resonant magnetic perturbation fields on the ejected energy as well as on the drawbacks of these perturbation fields. The transient energy ejection which is triggered by the instabilities causes extreme heat loads on the wall components in fusion devices. Therefore, it is crucial to understand how resonant magnetic perturbation fields affect the heat load deposition. Furthermore, the impact of resonant magnetic perturbation fields on the confinement of fast ions is an important aspect as fast ions are still required to be well confined in order to avoid additional wall loads and increase the fusion efficiency. Recent upgrades on the Joint European Torus allow for a detailed study of the heat load deposition profiles caused by transient events. Throughout this work, the new features are used for the study of the modifications of the transient heat load depositions that occur if resonant magnetic perturbation fields are applied. This leads to a further understanding of the processes involved during the plasma edge instabilities. Additionally, an alternative method using lower hybrid waves for applying resonant magnetic perturbations is investigated. Furthermore, a new diagnostic, capable of detecting fast ion

  20. Tokamak startup with electron cyclotron heating

    Energy Technology Data Exchange (ETDEWEB)

    Holly, D J; Prager, S C; Shepard, D A; Sprott, J C

    1980-04-01

    Experiments are described in which the startup voltage in a tokamak is reduced by approx. 60% by the use of a modest amount of electron cyclotron resonance heating power for preionization. A 50% reduction in volt-second requirement and impurity reflux are also observed.

  1. Low hydrogen content silicon nitride films deposited at room temperature with a multipolar ECR plasma source

    NARCIS (Netherlands)

    Isai, I.G.; Holleman, J.; Wallinga, Hans; Woerlee, P.H.

    2004-01-01

    Silicon nitride layers with very low hydrogen content (less than 1 atomic percent) were deposited at near room temperature, from N2 and SiH4, with a multipolar electron cyclotron resonance plasma. The influences of pressure and nitrogen flow rate on physical and electrical properties were studied in

  2. The method of controlling the thickness of the deposited film on the basis of the surface plasmon resonance effect

    Science.gov (United States)

    Komlev, A. E.; Dyukin, R. V.; Shutova, E. S.

    2017-07-01

    New method, based on surface plasmon resonance, for thickness control of thin films deposition in vacuum is offered by authors. This method allows to determine with high accuracy thickness of nanoscale optical coatings. Numerical simulation of surface plasmon resonance conditions in Kretchman geometry and it’s frequency changes during deposition of different thickness Ta2O5 films are presented. Modeling was given in WinSpall program.

  3. Cyclotron resonance and De Haas-Van Alphen effect in (BEDT-TTF) sub 8 Hg sub 4 Cl sub 1 sub 2 (C sub 6 H sub 5 Cl) sub 2 organic conductor

    CERN Document Server

    Voskobojnikov, I B; Samarin, N A; Cluchanko, N E; Lyubovskaya, R N; Moshchalkov, V V

    2002-01-01

    Within 0.33-1.44 K temperature range at B <= 50 T magnetic field values one measured the De Haas-Van Alphen effect for (BEDT-TTF) sub 8 Hg sub 4 Cl sub 1 sub 2 (C sub 6 H sub 5 Cl) sub 2 organic quasi-two-dimensional conductor. Analysis of quantum oscillations with regard to data on cyclotron resonance derived for 40-120 GHz frequency interval enabled to determine that a complex spectrum of quantum oscillations was formed by alpha approx 256 T and beta approx 670-610 T fundamental frequencies as well as, by combination and multiple frequencies. It is shown that nature of temperature rearrangement of oscillation spectrum may be interpreted in terms of model taking account of occurrence of magnetic phase transition at T sub c approx 0.9 K and proximity of a fundamental frequency with m* = 1.48m sub 0 efficient mass to the spin dumping condition

  4. Thermal Improvement and Stability of Si3N4/GeNx/p- and n-Ge Structures Prepared by Electron-Cyclotron-Resonance Plasma Nitridation and Sputtering at Room Temperature

    Science.gov (United States)

    Fukuda, Yukio; Okamoto, Hiroshi; Iwasaki, Takuro; Izumi, Kohei; Otani, Yohei; Ishizaki, Hiroki; Ono, Toshiro

    2012-09-01

    This paper reports on the thermal improvement of Si3N4/GeNx/Ge structures. After the Si3N4 (5 nm)/GeNx (2 nm) stacks were prepared on Ge substrates by electron-cyclotron-resonance plasma nitridation and sputtering at room temperature, they were thermally annealed in atmospheric N2 + 10% H2 ambient at temperatures from 400 to 600 °C. It was demonstrated that the electronic properties of the GeNx/Ge interfaces were thermally improved at temperatures of up to 500 °C with a minimum interface trap density (Dit) of ˜1×1011 cm-2 eV-1 near the Ge midgap, whereas the interface properties were slightly degraded after annealing at 600 °C with a minimum Dit value of ˜4×1011 cm-2 eV-1.

  5. ELECTRON CYCLOTRON WAVES

    NARCIS (Netherlands)

    Westerhof, E.

    2010-01-01

    This lecture gives an overview of heating and current drive with electron cyclotron waves. We present the main theoretical aspects of wave propagation, wave absorption, and non-inductive current drive, as well as important technical aspects for the application of high power electron cyclotron waves,

  6. Electron cyclotron waves

    NARCIS (Netherlands)

    Westerhof, E.

    2012-01-01

    This lecture gives an overview of heating and current drive with electron cyclotron waves. We present the main theoretical aspects of wave propagation, wave absorption, and non-inductive current drive, as well as important technical aspects for the application of high power electron cyclotron waves,

  7. Electron cyclotron waves

    NARCIS (Netherlands)

    Westerhof, E.

    2008-01-01

    This lecture gives an overview of heating and current drive with electron cyclotron waves. We present the main theoretical aspects of wave propagation, wave absorption, and non-inductive current drive, as well as important technical aspects for the application of high power electron cyclotron waves,

  8. High-Power Performance of a Resonant Diplexer for Advanced ECRH

    NARCIS (Netherlands)

    Kasparek, W.; Van den Braber, R.; Doelman, N.; Fritz, E.; Erckmann, V.; Hollmann, F.; Michel, G.; Noke, F.; Purps, F.; Bongers, W.; Krijger, B.; Petelin, M.; Lubyako, L.; Bruschi, A.

    2011-01-01

    Electron cyclotron resonance heating (ECRH) systems for next-step large fusion devices operate in continuous wave power in the multimegawatt range. The unique feature of narrow and well-localized power deposition assigns a key role to ECRH for different tasks, such as plasma start-up, electron

  9. High-power performance of a resonant diplexer for advanced ECRH

    NARCIS (Netherlands)

    Kasparek, W.; Braber, R. van den; Doelman, N.J.; Fritz, E.; Erckmann, V.; Hollmann, F.; Michel, G.; Noke, F.; Purps, F.; Bongers, W.; Krijger, B.; Petelin, M.; Lubyako, L.; Bruschi, A.

    2011-01-01

    Electron cyclotron resonance heating (ECRH) systems for next-step large fusion devices operate in continuous wave power in the multimegawatt range. The unique feature of narrow and well-localized power deposition assigns a key role to ECRHfor different tasks, such as plasma start-up, electron

  10. New analytical technique for establishing the quality of Soil Organic Matter affected by a wildfire. A first approach using Fourier transform ion cyclotron resonance mass spectrometry

    Science.gov (United States)

    Jiménez-Morillo, Nicasio T.; González-Pérez, José A.; Waggoner, Derek C.; Almendros, Gonzalo; González-Vila, Francisco J.; Hatcher, Patrick G.

    2016-04-01

    Introduction: Fire is one of the most important modulator factors of the environment and the forest. It is able to induce chemical and biological shifts and these, in turn, can alter the physical properties of soil. Generally, fire affects the most reactive fraction, soil organic matter (SOM) (González-Pérez et al., 2004) resulting in changes to several soil properties and functions. To study changes in SOM following a wildfire, researchers can count on several traditional as well as new analytical techniques. One of the most recently employed techniques is Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS). This new powerful ultra-high resolution mass spectral technique, together with graphic interpretation tools such as van Krevelen diagrams (Kim et al, 2003), may be used to shed light on alterations caused by the burning of SOM. The objective of this research is to study fire impacts on SOM, using a sandy soil collected under a Cork oak (Quercus suber) in Doñana National Park, Southwest Spain. that was affected by a wildfire in August 2012. Methods: The impact of fire on SOM was studied in various different sieve fractions (coarse, 1-2 mm, and fine, tannins, lignin, lipids, protein and carbohydrate derived. The unburnt SOM in the coarse fraction was mainly composed of compounds with a high intensity in the tannin-like, lignin-like and carbohydrate-like regions of the van Krevelen diagram, whereas the SOM in the fine fraction showed a high intensity in the lipid-like and protein-like regions. These results suggest that the SOM in the coarse fraction was less altered than that of the fine fraction; the latter believed to be subjected to higher microbial activity. We suggest that the observed changes occurs via a methylation process, producing a SOM that is highly humified (Jiménez-Morillo et al., 2014). The SOM in the coarse fraction affected by fire, showed a high relative intensity of chemical compounds in the carbohydrate-like and

  11. Material deposition and migration processes with resonant magnetic perturbation fields at TEXTOR

    Science.gov (United States)

    Laengner, Ruth; Schmitz, O.; Brezinsek, S.; Coenen, J. W.; Eich, T.; Freisinger, M.; Kirschner, A.; Kreter, A.; Möller, S.; Laengner, M.; Philipps, V.; Pospieszczyk, A.; Reimer, H.; Samm, U.; Wienhold, P.; Textor Team

    2013-07-01

    Resonant Magnetic Perturbations (RMPs) are applied with the Dynamic Ergodic Divertor (DED) at TEXTOR to control the plasma edge transport and the plasma surface interaction. This leads to the formation of a three-dimensional (3D) topology of the scrape-off layer (SOL). To quantify the erosion/deposition balance and the material migration in this 3D boundary, spherical test limiters were exposed to plasmas with and without RMP fields applied. Methane doped with 13C as tracer element was injected through a gas inlet in the test limiter. The local gas source was monitored by spatially resolving spectroscopy and the resulting deposition patterns on the limiters were analysed with colourimetry and nuclear reaction analysis. These measurements were compared to simulations of the magnetic field topology simulations. The data provide evidence of a particle migration dominated by an ExB drift within stochastic zones of the 3D plasma boundary.

  12. Calibration and use cases of the electron cyclotron emission diagnostic at Wendelstein 7-X

    Energy Technology Data Exchange (ETDEWEB)

    Hoefel, Udo; Hirsch, Matthias; Ewert, Karsten; Hartfuss, Hans-Juergen; Laqua, Heinrich Peter; Stange, Torsten; Wolf, Robert [Max-Planck-Institut fuer Plasmaphysik, Greifswald (Germany); Collaboration: the W7-X Team

    2016-07-01

    The world's largest stellarator, Wendelstein 7-X (W7-X), is equipped with a 140 GHz electron cyclotron resonance heating (ECRH) system providing up to 5 MW absorbed power in the first operation phase OP1.1. The foreseen X2-heating scenario uses the high absorption of the second harmonic extraordinary electron cyclotron waves, which leads on the other hand to a black body electron cyclotron emission (ECE) being proportional to the local electron temperature. ECE is one of the fundamental operating diagnostics and is planned to yield the electron temperature profile from the very first discharges onwards. Unlike most other ECE diagnostics, the 32 channel ECE radiometer diagnostic (with additional 16 channels with higher radial resolution) at W7-X is absolutely calibrated. It is planned to use this diagnostic for intensive studies on electron heat transport in the upcoming operational phases of W7-X. Simple switch-off experiments for the determination of the energy confinement time should already be possible within the first plasma shots. Due to the high temporal and radial resolution the ECE will be used also to determine the power deposition by modulation of the heating gyrotron. or the localization of a power modulated ECRH to optimize the power deposition. If reasonably equilibrated plasma conditions could be generated in the first operational phase (OP 1.1), first studies on electron thermal diffusivity could also be possible.

  13. Cyclotron Line Measurements with INTEGRAL

    Science.gov (United States)

    Pottschmidt, K.; Kreykenbohm, I.; Caballero, I.; Fritz, S.; Schoenherr, G.; Kretschmar, P.; Wilms, J.; McBride, V. A.; Suchy, S.; Rothschild, R. E.

    2008-01-01

    Due to its broadband energy coverage, INTEGRAL has made important contributions to observing and interpreting cyclotron lines, which are present in the 10-100 keV range of a sample of accreting pulsars. In these systems photons with energies fulfilling the resonance condition inelastically Compton scatter off electrons quantized in the accretion column above the neutron star's magnetic pole(s). This process gives rise to the broad, absorption-like lines or 'cyclotron resonant scattering features' (CRSF). The observed lines allow to directly measure the B-fields of these sources, resulting in values of a few times 1E12G. In this overview I will present recent highlights regarding CRSF observations as well as discuss current ideas and models for the physical conditions in the accretion column. Among the former are the stability of the spectrum of Vela X-1 during giant flares in 2003, the observation of three cyclotron lines during the 2004 outburst of V0332+53, the confirmation of the fundamental line at approximately 45 keV during a 2005 normal outburst of A0535-26, and the simultaneous detection of the two lines in the dipping source 4U 1907+09 (for which also a torque reversal was detected for the first time). Through these and other observations it has become increasingly apparent that two types of observations can potentially be used to constrain the accretion column geometry: the determination of energy ratios for multiple harmonic lines (only two sources with greater than 2 lines are known), was well as the evolution of the fundamental line centroid, which, for different sources, may or may not be correlated with flux. Furthermore, first steps have been taken away from the usual phenomenological description of the lines, towards a physical approach based on self-consistent CRSF modeling. Initial applications are presented.

  14. Quantum oscillation of the cyclotron mass in two-dimensional electron systems in silicon

    NARCIS (Netherlands)

    Kaesen, K.F.; Huber, A; Lorenz, H.; Kotthaus, J.P.; Bakker, S.; Klapwijk, T.M

    1996-01-01

    The cyclotron resonance of two-dimensional electron systems in silicon metal-oxide-semiconductor devices is investigated for high electron densities in high magnetic fields. The cyclotron mass, extracted from the resonance frequency, shows an oscillatory behavior. The periodicity of this oscillation

  15. Use of surface plasmon resonance to investigate lateral wall deposition kinetics and properties of polydopamine films.

    Science.gov (United States)

    Li, Hui; Cui, Dafu; Cai, Haoyuan; Zhang, Lulu; Chen, Xing; Sun, Jianhai; Chao, Yapeng

    2013-03-15

    Dopamine (DA) is a particularly important neurotransmitter. Polydopamine (pDA) films have been demonstrated to be important materials for the immobilization of biomolecules onto almost any type of solid substrate. In this study, a surface plasmon resonance (SPR)-based sensor system with the sensor chip surface parallel to the direction of gravity was used to investigate the lateral wall deposition kinetics and properties of pDA films. The deposition kinetics of pDA Films are limited by the oxidation process. The pDA film could not be removed from the sensor chip completely by a strongly alkaline solution, indicating that the pDA film was heterogeneous in the direction of deposition. The pDA film formed near the interior of the solution was less stable than the film formed near the gold-solution interface. Adsorption of proteins on pDA film was studied compared with that on bare gold and dextran sensor chip. The reduction of Au(111) cations by the pDA film, forming a layer of gold particles, was monitored using SPR. Copyright © 2012 Elsevier B.V. All rights reserved.

  16. Synchro-cyclotron

    CERN Multimedia

    CERN PhotoLab

    1972-01-01

    The electromagnetic coil which forms the first section of the proton extraction channel in the improved synchro-cyclotron. The photograph shows the positioning gear and the current septum. An extraction efficiency above 50% is expected.

  17. Highly Sensitive Local Surface Plasmon Resonance in Anisotropic Au Nanoparticles Deposited on Nanofibers

    Directory of Open Access Journals (Sweden)

    Masanari Saigusa

    2015-01-01

    Full Text Available This paper reports the facile and high-throughput fabrication method of anisotropic Au nanoparticles with a highly sensitive local surface plasmon resonance (LPR using cylindrical nanofibers as substrates. The substrates consisting of nanofibers were prepared by the electrospinning of poly(vinylidene fluoride (PVDF. The Au nanoparticles were deposited on the surface of electrospun nanofibers by vacuum evaporation. Scanning electron microscopy revealed the formation of a curved Au island structure on the surface of cylindrical nanofibers. Polarized UV-visible extinction spectroscopy showed anisotropy in their LPR arising from the high surface curvature of the nanofiber. The LPR of the Au nanoparticles on the thinnest nanofiber with a diameter of ~100 nm showed maximum refractive index (RI sensitivity over 500 nm/RI unit (RIU. The close correlation between the fiber diameter dependence of the RI sensitivity and polarization dependence of the LPR suggests that anisotropic Au nanoparticles improve RI sensitivity.

  18. Fundamental processes of fuel removal by cyclotron frequency range plasmas and integral scenario for fusion application studied with carbon co-deposits

    Energy Technology Data Exchange (ETDEWEB)

    Möller, S., E-mail: s.moeller@fz-juelich.de [Forschungszentrum Jülich GmbH, Institut für Energie- und Klimaforschung – Plasmaphysik, Partner of the Trilateral Euregio Cluster (TEC), 52425 Jülich (Germany); Wauters, T. [Laboratory for Plasma Physics, ERM/KMS, TEC Partner, 1000 Brussels (Belgium); Kreter, A. [Forschungszentrum Jülich GmbH, Institut für Energie- und Klimaforschung – Plasmaphysik, Partner of the Trilateral Euregio Cluster (TEC), 52425 Jülich (Germany); Petersson, P.; Carrasco, A.G. [Fusion Plasma Physics, KTH Royal Institute of Technology, Teknikringen 31, 10044 Stockholm (Sweden)

    2015-08-15

    Plasma impact removal using radio frequency heated plasmas is a candidate method to control the co-deposit related tritium inventory in fusion devices. Plasma parameters evolve according to the balance of input power to losses (transport, radiation, collisions). Material is sputtered by the ion fluxes with impact energies defined by the plasma sheath. H{sub 2}, D{sub 2} and {sup 18}O{sub 2} plasmas are produced in the carbon limiter tokamak TEXTOR. Pre-characterised a-C:D layers are exposed to study local removal rates. The D{sub 2} plasma exhibits the highest surface release rate of 5.7 ± 0.9 ∗ 10{sup 19} D/m{sup 2}s. Compared to this the rate of the O{sub 2} plasma is 3-fold smaller due to its 11-fold lower ion flux density. Re-deposition of removed carbon is observed, indicating that pumping and ionisation are limiting the removal in TEXTOR. Presented models can explain the observations and allow tailoring removal discharges. An integral application scenario using ICWC and thermo-chemical removal is presented, allowing to remove 700 g T from a-C:DT co-deposits in 20 h with fusion compatible wall conditions using technical specifications similar to ITER.

  19. Operation of a quasioptical electron cyclotron maser

    Energy Technology Data Exchange (ETDEWEB)

    Morse, E.C.; Pyle, R.V.

    1984-12-01

    The electron cyclotron maser or gyrotron concept has been developed to produce sources producing 200 kW at 28 GHz continuously, and higher power outputs and frequencies in pulsed mode. These sources have been useful in electron cyclotron resonance heating (ECRH) in magnetically confined fusion devices. However, higher frequencies and higher power levels will be required in reactor-grade fusion plasmas, with likely requirements of 1.0 MW or more per source at 140 GHz. Conventional gyrotrons follow a trend of decreasing power for increasing frequency. In order to circumvent this problem, the quasioptical electron cyclotron maser was proposed. In this device, the closed resonator of the conventional gyrotron is replaced with an open, Fabry-Perot type resonator. The cavity modes are then the TEM-type modes of an optical laser. The advantage of this configuration is that the cavity size is not a function of frequency, since the length can be any half-integer number of wavelengths. Furthermore, the beam traverses across the cavity transverse to the direction of radiation output, and thus the rf window design is less complicated than in conventional tubes. The rf output, if obtained by diffraction coupling around one of the mirrors, could be in a TEM mode, which would allow for quasioptical transmission of the microwaves into the plasma in fusion devices. 4 references, 1 figure.

  20. The Effects of Magnetic Exposure on the Nervous System: A study on the effects of low-strength low-frequency magnetic fields on neurotransmitter exocytosis and cell viability through ionic cyclotron resonance frequency

    Science.gov (United States)

    Saveriades, George

    This PhD dissertation focuses on the study of the effects of magnetic exposure on biological systems using amperometry techniques and viability assays. In our prior work based on the cyclotron resonance model, chromaffin cells in physiological saline and Ca2+-free media were exposed for 5 minutes to a 2.7 muT magnetic field, with frequency sweeps going from 30-60 Hz (targeting several ions involved in exocytosis) and 44-48 Hz (targeting specifically Ca2+ ions), with noticeable effects on exocytosis. The present study extended the work on chromaffin cells by covering frequency sweeps for different ions, manipulating the time of exposure and the strength of the magnetic field. Furthermore, amperometry was conducted on acute coronal brain slices, to demonstrate that the recorded effects could be measured on neuronal tissue. The viability of chromaffin cells and primary neuronal cultures exposed to magnetic fields was also addressed. The results demonstrate that cellular exocytosis is sensitive to the frequency of the magnetic field it is exposed to, the strength of the magnetic field and the duration of exposure. No significant effects were established with regards to the viability of the cells exposed to magnetic fields.

  1. Design of the 1.5 MW, 30-96 MHz ultra-wideband 3 dB high power hybrid coupler for Ion Cyclotron Resonance Frequency (ICRF) heating in fusion grade reactor

    Energy Technology Data Exchange (ETDEWEB)

    Yadav, Rana Pratap, E-mail: ranayadav97@gmail.com; Kumar, Sunil; Kulkarni, S. V. [Thapar University, Patiala, Punjab 147004, India and Institute for Plasma Research, Gandhinagar 382428 (India)

    2016-01-15

    Design and developmental procedure of strip-line based 1.5 MW, 30-96 MHz, ultra-wideband high power 3 dB hybrid coupler has been presented and its applicability in ion cyclotron resonance heating (ICRH) in tokamak is discussed. For the high power handling capability, spacing between conductors and ground need to very high. Hence other structural parameters like strip-width, strip thickness coupling gap, and junction also become large which can be gone upto optimum limit where various constrains like fabrication tolerance, discontinuities, and excitation of higher TE and TM modes become prominent and significantly deteriorates the desired parameters of the coupled lines system. In designed hybrid coupler, two 8.34 dB coupled lines are connected in tandem to get desired coupling of 3 dB and air is used as dielectric. The spacing between ground and conductors are taken as 0.164 m for 1.5 MW power handling capability. To have the desired spacing, each of 8.34 dB segments are designed with inner dimension of 3.6 × 1.0 × 40 cm where constraints have been significantly realized, compensated, and applied in designing of 1.5 MW hybrid coupler and presented in paper.

  2. Enumeration of non-labile oxygen atoms in dissolved organic matter by use of ¹⁶O/ ¹⁸O exchange and Fourier transform ion-cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Kostyukevich, Yury; Kononikhin, Alexey; Zherebker, Alexander; Popov, Igor; Perminova, Irina; Nikolaev, Eugene

    2014-10-01

    We report a simple approach for enumeration of non-labile oxygen atoms in individual molecules of dissolved organic matter (DOM), using acid-catalyzed (16)O/(18)O exchange and ultrahigh-resolution Fourier-transform ion-cyclotron-resonance mass spectrometry (FTICR-MS). We found that by dissolving DOM in H2 (18)O at 95 °C for 20 days it is possible to replace all oxygen atoms of DOM molecules (excluding oxygen from ether groups) with (18)O. The number of exchanges in each molecule can be determined using high-resolution FTICR. Using the proposed method we identified the number of non-labile oxygen atoms in 231 molecules composing DOM. Also, using a previously developed hydrogen-deuterium (H/D)-exchange approach we identified the number of labile hydrogen atoms in 450 individual molecular formulas. In addition, we observed that several backbone hydrogen atoms can be exchanged for deuterium under acidic conditions. The method can be used for structural and chemical characterization of individual DOM molecules, comparing different DOM samples, and investigation of biological pathways of DOM in the environment.

  3. Polycyclic aromatic hydrocarbons (PAHs) in ambient aerosols from Beijing: characterization of low volatile PAHs by positive-ion atmospheric pressure photoionization (APPI) coupled with Fourier transform ion cyclotron resonance.

    Science.gov (United States)

    Jiang, Bin; Liang, Yongmei; Xu, Chunming; Zhang, Jingyi; Hu, Miao; Shi, Quan

    2014-05-06

    Aromatic fractions derived from aerosol samples were characterized by gas chromatography and mass spectrometry (GC-MS), high temperature simulated distillation (SIMDIS), and positive-ion atmospheric pressure photoionization (APPI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS), respectively. It was found that about 27 wt % compounds in aromatic fractions could not be eluted from a GC column and some large molecule PAHs were neglected in GC-MS analysis. APPI FT-ICR MS was proven to be a powerful approach for characterizing the molecular composition of aromatics, especially for the large molecular species. An aromatic sample from Beijing urban aerosol was successfully characterized by APPI FT-ICR MS. Results showed that most abundant aromatic compounds in PM2.5 (particles with aerodynamic diameter ≤ 2.5 μm) were highly condensed hydrocarbons with 4-8 aromatic rings and their homologues with very short alkyl chains. Furthermore, heteroatom-containing hydrocarbons were found as the significant components of the aromatic fractions: O1, O2, N1, and S1 class species with 10-28 DBEs (double bond equivalents) and 14-38 carbon numbers were identified by APPI FT-ICR MS. The heteroatom PAHs had similar DBEs and carbon number distribution as regular PAHs.

  4. Periodic Beam Current Oscillations Driven by Electron Cyclotron Instabilities in ECRIS Plasmas

    OpenAIRE

    Tarvainen, Olli; Kalvas, Taneli; Koivisto, Hannu; Komppula, Jani; Kronholm, Risto; Laulainen, Janne; Izotov, I.; Mansfeld, D.; Skalyga, V.; Toivanen, V.

    2014-01-01

    Experimental observation of cyclotron instabilities in electron cyclotron resonance ion source plasma operated in cwmode is reported. The instabilities are associated with strong microwave emission and a burst of energetic electrons escaping the plasma, and explain the periodic oscillations of the extracted beam currents. The instabilities are shown to restrict the parameter space available for the optimization of high charge state ion currents.

  5. Demonstration of the deposition of hemosiderin in the kidneys of patients with paroxysmal nocturnal hemoglobinuria by megnetic resonance imaging

    Energy Technology Data Exchange (ETDEWEB)

    Suzukawa, Kazumi; Ninomiya, Haruhiko; Mitsuhashi, Shoichi; Anno, Izumi; Nagasawa, Toshiro; Abe, Tsukasa (Tsukuba Univ., Ibaraki (Japan). Inst. of Clinical Medicine)

    1993-09-01

    Hemosiderinuria caused by intravascular hemolysis is a characteristic clinical feature of an acquired hemolytic disorder, paroxysmal nocturnal hemoglobinuria (PNH). We examined the deposition of hemosiderin (iron) in the kidneys of 6 patients with PNH using magnetic resonance imaging (MRI). Three patients with autoimmune hemolytic anemia (AIHA), a hemolytic disorder showing extravascular hemolysis, served as controls. In five of the six patients with PNH, a characteristic T2-weighted MRI of the kidneys, suggesting the deposition of iron (hemosiderin) predominantly in the renal cortex, was obtained. Hemosiderin-deposition was not revealed in the kidneys of any of the patients with AIHA. We conclude that MRI is a sensitive means of detecting hemosiderin deposited in the renal cortex of patients with PNH and that this feature is considerably specific for diseases showing intravascular hemolysis, as represented by PNH. (author).

  6. Identification of glucosinolates in capers by LC-ESI-hybrid linear ion trap with Fourier transform ion cyclotron resonance mass spectrometry (LC-ESI-LTQ-FTICR MS) and infrared multiphoton dissociation.

    Science.gov (United States)

    Bianco, Giuliana; Lelario, Filomena; Battista, Fabio Giuseppe; Bufo, Sabino A; Cataldi, Tommaso R I

    2012-09-01

    An liquid chromatography-mass spectrometry method using electrospray ionization in negative ion mode coupled with a hybrid quadrupole linear ion trap and Fourier transform ion cyclotron resonance (FTICR) mass spectrometer was applied to characterize of intact glucosinolates (GLSs) in crude sample extracts of wild bud flowers of Capparis spinosa (Capparis species, family Capparaceae). Structural information of GLSs was obtained upon precursor ions' isolation within the FTICR trapping cell and subsequent fragmentation induced by infrared multiphoton dissociation (IRMPD). Such a fragmentation was found very useful in terms of chemical identification of all precursor ions [M-H](-) including sulfur-rich GLSs reported here for the first time. Along with most common GLSs already found in capers such as glucocapparin, isopropyl/n-propyl-GLS, mercapto-glucocapparin, and two indolic GLS, i.e., 4-hydroxyglucobrassicin and glucobrassicin, the occurrence of the uncommon glycinyl-glucocapparin as well as two sulfur-rich GLSs is reported. IRMPD showed an increased selectivity towards disulfide bond cleavages with thiol migration, suggesting the side chain structure of non-targeted compounds, i.e., disulfanyl-glucocapparin and trisulfanyl-glucocapparin. Glucocapparin [2.05 ± 0.25 mg/g, dry weight (dw)] was the most abundant GLS, followed by glucobrassicin (232 ± 18 µg/g, dw) and 4-hydroxyglucobrassicin (89 ± 12 µg/g, dw). All other compounds were present at very low content ranging from 0.5 to 1.5 µg/g dw. Copyright © 2012 John Wiley & Sons, Ltd.

  7. Observation of cyclotron resonance and electron-phonon coupling in surface states of the bulk-insulating topological insulator Cu0.02Bi2Se3

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Liang [Johns Hopkins Univ., Baltimore, MD (United States). The Inst. of Quantum Matter; Tse, Wang-Kong [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Morris, C. M. [Johns Hopkins Univ., Baltimore, MD (United States). The Inst. of Quantum Matter; Brahlek, M. [Rutgers Univ., Piscataway, NJ (United States). Dept. of Physics and Astronomy; Koirala, N. [Rutgers Univ., Piscataway, NJ (United States). Dept. of Physics and Astronomy; Oh, S. [Rutgers Univ., Piscataway, NJ (United States). Dept. of Physics and Astronomy; Armitage, N. P. [Johns Hopkins Univ., Baltimore, MD (United States). The Inst. of Quantum Matter

    2015-02-05

    We have utilized magneto-optical time-domain spectroscopy to investigate the low frequency optical response of topological insulator Cu0.02Bi2Se3 and Bi2Se3 films. With both field and frequency depedence, such experiments give sufficient information to measure the mobility and carrier density of multiple conduction channels simultaneously. We observe sharp cyclotron resonances (CRs) in both samples. The small amount of Cu substitution into the Cu0.02Bi2Se3 induces a true bulk insulator with only a single conduction channel with total sheet carrier density 4.9 x 1012/cm2 and mobility as large as 4000 cm2/V s. This is consistent with pure topological surface state (TSSs) conduction with a chemical potential 150 meV above the Dirac point. Hence, a true topological insulator with an insulating bulk is realized. The CR broadens at high fields, an e ect that we attribute to an electron-phonon interaction. This assignment is supported by an extended Drude model analysis on the zero field data. In contrast to Cu0.02Bi2Se3, two charge channels were observed in normal Bi2Se3 films. We demonstrate a method to distinguish between the dominant TSSs and trivial bulk/2DEG states. The dominant channel exhibits a CR with a carrier density of ~2.0 x 1013/cm2 and mobility ~3200 cm2/V s, consistent with TSSs with a chemical potential ~350meV above the Dirac point.

  8. Metabolomic profiling of prostate cancer by matrix assisted laser desorption/ionization-Fourier transform ion cyclotron resonance mass spectrometry imaging using Matrix Coating Assisted by an Electric Field (MCAEF).

    Science.gov (United States)

    Wang, Xiaodong; Han, Jun; Hardie, Darryl B; Yang, Juncong; Pan, Jingxi; Borchers, Christoph H

    2017-07-01

    In this work, we combined the use of two MALDI matrices (quercetin and 9-aminoacridine), a recently developed new matrix coating technique - matrix coating assisted by an electric field (MCAEF), and matrix-assisted laser desorption/ionization - Fourier transform ion cyclotron resonance mass spectrometry (MALDI-FTICRMS) to detect and image endogenous compounds in the cancerous and non-cancerous regions of three human prostate cancer (stage II) tissue specimens. After three rounds of imaging data acquisitions (i.e., quercetin for positive and negative ion detection and 9-aminoacridine for negative ion detection), and metabolite identification, a total of 1091 metabolites including 1032 lipids and 59 other metabolites were routinely detected and successfully localized. Of these compounds, 250 and 217 were only detected in either the cancerous or the non-cancerous regions respectively, although we cannot rule out the presence of these metabolites at concentrations below the detection limit. In addition, 152 of the other 624 metabolites showed differential distributions (p<0.05, t-test) between the two regions of the tissues. Further studies on a larger number of clinical specimens will need to be carried out to confirm this large number of apparently cancer-related metabolites. The successful determination of the spatial locations and abundances of these endogenous biomolecules indicated significant metabolism abnormalities - e.g., increased energy charge and under-expression of neutral acyl glycerides, in the prostate cancer samples. To our knowledge, this work has resulted in MALDI-MS imaging of the largest group of metabolites in prostate cancer thus far and demonstrated the importance of using complementary matrices for comprehensive metabolomic imaging by MALDI-MS. This article is part of a Special Issue entitled: MALDI Imaging, edited by Dr. Corinna Henkel and Prof. Peter Hoffmann. Copyright © 2017 Elsevier B.V. All rights reserved.

  9. Combination of electrospray ionization, atmospheric pressure photoionization and laser desorption ionization Fourier transform ion cyclotronic resonance mass spectrometry for the investigation of complex mixtures – Application to the petroleomic analysis of bio-oils

    Energy Technology Data Exchange (ETDEWEB)

    Hertzog, Jasmine [LCP-A2MC, FR 2843 Institut Jean Barriol de Chimie et Physique Moléculaires et Biomoléculaires, FR 3624 Réseau National de Spectrométrie de Masse FT-ICR à très haut champ, Université de Lorraine, ICPM, 1 boulevard Arago, 57078 Metz Cedex 03 (France); Carré, Vincent, E-mail: vincent.carre@univ-lorraine.fr [LCP-A2MC, FR 2843 Institut Jean Barriol de Chimie et Physique Moléculaires et Biomoléculaires, FR 3624 Réseau National de Spectrométrie de Masse FT-ICR à très haut champ, Université de Lorraine, ICPM, 1 boulevard Arago, 57078 Metz Cedex 03 (France); Le Brech, Yann [LRGP, CNRS, Université de Lorraine, ENSIC, 1, Rue Grandville, 54000 Nancy (France); Mackay, Colin Logan [SIRCAMS, School of Chemistry, University of Edinburgh, Edinburgh, EH9 3FJ, Scotland (United Kingdom); Dufour, Anthony [LRGP, CNRS, Université de Lorraine, ENSIC, 1, Rue Grandville, 54000 Nancy (France); Mašek, Ondřej [UK Biochar Research Center, School of Geosciences, University of Edinburgh, Kings Buildings, Edinburgh, EH9 3JN (United Kingdom); and others

    2017-05-29

    The comprehensive description of complex mixtures such as bio-oils is required to understand and improve the different processes involved during biological, environmental or industrial operation. In this context, we have to consider how different ionization sources can improve a non-targeted approach. Thus, the Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) has been coupled to electrospray ionization (ESI), laser desorption ionization (LDI) and atmospheric pressure photoionization (APPI) to characterize an oak pyrolysis bio-oil. Close to 90% of the all 4500 compound formulae has been attributed to C{sub x}H{sub y}O{sub z} with similar oxygen class compound distribution. Nevertheless, their relative abundance in respect with their double bound equivalent (DBE) value has evidenced significant differences depending on the ion source used. ESI has allowed compounds with low DBE but more oxygen atoms to be ionized. APPI has demonstrated the efficient ionization of less polar compounds (high DBE values and less oxygen atoms). The LDI behavior of bio-oils has been considered intermediate in terms of DBE and oxygen amounts but it has also been demonstrated that a significant part of the features are specifically detected by this ionization method. Thus, the complementarity of three different ionization sources has been successfully demonstrated for the exhaustive characterization by petroleomic approach of a complex mixture. - Highlights: • Non-targeted mass spectrometry by combining electrospray ionization, atmospheric pressure photoionization and laser/desorption ionization. • Exhaustive description of pyrolytic bio-oil components. • Distinction of sugaric derivatives, lignin derivatives and lipids contained in a woody-based pyrolytic bio-oil.

  10. Identification of unsaturated N-acylhomoserine lactones in bacterial isolates of Rhodobacter sphaeroides by liquid chromatography coupled to electrospray ionization-hybrid linear ion trap-Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Cataldi, Tommaso R I; Bianco, Giuliana; Abate, Salvatore; Losito, Ilario

    2011-07-15

    The identification of two unsaturated N-acylhomoserine lactones (AHLs) produced by Rhodobacter sphaeroides bacteria, based on liquid chromatography (LC) coupled to a hybrid quadrupole linear ion trap (LTQ)-Fourier transform ion cyclotron resonance (FTICR) mass spectrometer upon electrospray ionization (ESI), is presented. Besides the confirmation of the signaling molecule already described in the literature, i.e. (Z)-N-tetradec-7-enoyl-homoserine lactone (C(14:1)-HSL), we have discovered the occurrence, at low, yet significant levels, of another monounsaturated compound, C(12:1) -HSL, which may extend the number of small diffusible chemical signals known for R. sphaeroides. Both unsaturated AHLs were identified by high-resolution FTICR mass spectrometry in extracts of bacterial culture media and the occurrence of a C=C bond was assessed upon their conversion into bromohydrins. Collision-induced dissociation (CID) spectra were then collected on the LTQ mass analyzer. A careful comparison of tandem MS spectra of monounsaturated (i.e., C(12:1)-HSL and C(14:1)-HSL) and saturated AHLs (i.e. C(12)-HSL and C(14)-HSL) led to the emphasis of two series of product ions, exhibiting 14 Da spaced m/z ratios. Both series were referred to progressive fragmentations at the aliphatic end of the AHL acyl chains, followed by neutral losses of terminal alkenes (i.e. CH(2)=CH(CH(2))(n)H). In particular, the series located at the higher end of the explored m/z range (>200 Da), observed only for monounsaturated species, enabled the location of the C=C bond between carbons 7 and 8 of the acyl chain. Copyright © 2011 John Wiley & Sons, Ltd.

  11. Ammonia-treated N-(1-naphthyl) ethylenediamine dihydrochloride as a novel matrix for rapid quantitative and qualitative determination of serum free fatty acids by matrix-assisted laser desorption/ionization-Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Zhang, Yaping; Wang, Yanmin; Guo, Shuai; Guo, Yumei; Liu, Hui; Li, Zhili

    2013-09-10

    The blood free fatty acids (FFAs), which provide energy to the cell and act as substrates in the synthesis of fats, lipoproteins, liposaccharides, and eicosanoids, involve in a number of important physiological processes. In the present study, matrix-assisted laser desorption/ionization-Fourier transform ion cyclotron resonance mass spectrometry (MALDI-FTICR MS) with ammonia-treated N-(1-naphthyl) ethylenediamine dihydrochloride (ATNEDC) as a novel MALDI matrix in a negative ion mode was employed to directly quantify serum FFAs. Multiple point internal standard calibration curves between the concentration ratios of individual fatty acids to internal standard (IS, C17:0) versus their corresponding intensity ratios were constructed for C14:0, C16:1, C16:0, C18:0, C18:1, C18:2, C18:3, C20:4, and C22:6, respectively, in their mixture, with correlation coefficients between 0.991 and 0.999 and limits of detection (LODs) between 0.2 and 5.4μM, along with the linear dynamic range of more than two orders of magnitude. The results indicate that the multiple point internal standard calibration could reduce the impact of ion suppression and improve quantification accuracy in the MALDI mode. The quantitative results of nine FFAs from 339 serum samples, including 161 healthy controls, 118 patients with hyperglycemia and 60 patients without hyperglycemia show that FFAs levels in hyperglycemic patient sera are significantly higher than those in healthy controls and patients without hyperglycemia, and elevated FFA levels are also associated with increased levels of fasting blood glucose (FBG) in hyperglycemic patient sera. Serum FFAs were identified on the basis of the observed accurate molecular masses and reliable isotope distributions obtained by MALDI-FTICR MS. Copyright © 2013 Elsevier B.V. All rights reserved.

  12. Production of cyclotron radionuclides

    Energy Technology Data Exchange (ETDEWEB)

    Suh, Yong Sup; Lim, Sang Moo; Yang, Seung Dae; Chun, Kwon Soo; Ahn, Soon Hyuk; Yun, Yong Kee; Park, Hyun; Lee, Ji Sup; Lee, Jong Doo; Chai, Jong Seo; Kim, Yoo Seok; Hong, Sung Suk; Lee, Min Yong; Beak, Seung Ki [Korea Cancer Center Hospital, Seoul (Korea)

    1999-12-01

    In the project, 11,492mCi of {sup 201}Tl, 4,384mCi of {sup 67}Ga, 1,245mCi of {sup 123}l, 523mCi of [{sup 123}I]mlBG and 1,283mCi of {sup 18}FDG were supplied, and the revenue were 304,723,000won. In the production of RI, 13 deg for {sup 201}Tl and {sup 67}Ga, 45 deg for {sup 123}l angle solid target have been used, and liquid target system has been used for {sup 18}F production. For the efficient use of the cyclotron, the MC-50 cyclotron was opened to outside user and basic research project was carried out. The technical supports and radionuclides analysis were done during the execution of the research. Then the facilities of safety supervision and handling techniques of radioisotope production were improved. 7 refs., 9 figs., 8 tabs. (Author)

  13. Production of cyclotron radionuclides

    Energy Technology Data Exchange (ETDEWEB)

    Chun, Kwon Soo; Lim, Sang Moo; Yang, Seung Dae; Suh, Yong Sup; Ahn, Soon Hyuk; Yun, Yong Kee; Park, Hyun; Lee, Ji Sup; Chai, Jong Seo; Kim, Yoo Seok; Hong, Sung Suk; Lee, Min Yong; Beak, Seung Ki; Kim, Jang Hye; Kim, Gi Sup [Korea Cancer Center Hospital, Seoul (Korea)

    2000-12-01

    In the project, 12,077mCi of {sup 201}Tl, 5,717mCi of {sup 67}Ga, 2,096mCi of {sup 123}l, 482mCi of [{sup 123}I]mlBG and 2,738mCi of {sup 18}FDG were supplied, and the revenue were 387,253,000won. In the production of RI, 13 deg for {sup 201}Tl and {sup 67}Ga, 45 deg for {sup 123}l angle solid target have been used, and liquid target system has been used for {sup 18}F production. For the efficient use of the cyclotron, the MC-50 cyclotron was opened to outside user and basic research project was carried out. The technical supports and radionuclides analysis were done during the execution of the research. Then the facilities of safety supervision and handling techniques of radioisotope production were improved. 7 refs., 8 figs., 9 tabs. (Author)

  14. Experiments on ion cyclotron damping at the deuterium fourth harmonic in DIII-D

    Energy Technology Data Exchange (ETDEWEB)

    Pinsker, R.I.; Petty, C.C. [General Atomics, San Diego, CA (United States); Baity, F.W. [Oak Ridge National Lab., TN (United States); Bernabei, S.; Greenough, N. [Princeton Plasma Physics Lab., NJ (United States); Heidbrink, W.W. [Univ. of California, Irvine, CA (United States); Mau, T.K. [Univ. of California, San Diego, CA (United States); Porkolab, M. [Massachusetts Inst. of Tech., Cambridge, MA (United States)

    1999-05-01

    Absorption of fast Alfven waves by the energetic ions of an injected beam is evaluated in the DIII-D tokamak. Ion cyclotron resonance absorption at the fourth harmonic of the deuteron cyclotron frequency is observed with deuterium neutral beam injection (f = 60 MHz, B{sub T} = 1.9 T). Enhanced D-D neutron rates are evidence of absorption at the Doppler-shifted cyclotron resonance. Characteristics of global energy confinement provide further proof of substantial beam acceleration by the rf. In many cases, the accelerated deuterons cause temporary stabilization of the sawtooth (monster sawteeth), at relatively low rf power levels of {approximately}1 MW.

  15. Numerical investigation of the electric field distribution and the power deposition in the resonant cavity of a microwave electrothermal thruster

    Directory of Open Access Journals (Sweden)

    Mehmet Serhan Yildiz

    2017-04-01

    Full Text Available Microwave electrothermal thruster (MET, an in-space propulsion concept, uses an electromagnetic resonant cavity as a heating chamber. In a MET system, electromagnetic energy is converted to thermal energy via a free floating plasma inside a resonant cavity. To optimize the power deposition inside the cavity, the factors that affect the electric field distribution and the resonance conditions must be accounted for. For MET thrusters, the length of the cavity, the dielectric plate that separates the plasma zone from the antenna, the antenna length and the formation of a free floating plasma have direct effects on the electromagnetic wave transmission and thus the power deposition. MET systems can be tuned by adjusting the lengths of the cavity or the antenna. This study presents the results of a 2-D axis symmetric model for the investigation of the effects of cavity length, antenna length, separation plate thickness, as well as the presence of free floating plasma on the power absorption. Specifically, electric field distribution inside the resonant cavity is calculated for a prototype MET system developed at the Bogazici University Space Technologies Laboratory. Simulations are conducted for a cavity fed with a constant power input of 1 kW at 2.45 GHz using COMSOL Multiphysics commercial software. Calculations are performed for maximum plasma electron densities ranging from 1019 to 1021 #/m3. It is determined that the optimum antenna length changes with changing plasma density. The calculations show that over 95% of the delivered power can be deposited to the plasma when the system is tuned by adjusting the cavity length.

  16. Cyclotrons and positron emitting radiopharmaceuticals

    Energy Technology Data Exchange (ETDEWEB)

    Wolf, A.P.; Fowler, J.S.

    1984-01-01

    The state of the art of Positron Emission Tomography (PET) technology as related to cyclotron use and radiopharmaceutical production is reviewed. The paper discusses available small cyclotrons, the positron emitters which can be produced and the yields possible, target design, and radiopharmaceutical development and application. 97 refs., 12 tabs. (ACR)

  17. Cyclotron Phase-Coherent Ion Spatial Dispersion in a Non-Quadratic Trapping Potential is Responsible for FT-ICR MS at the Cyclotron Frequency

    Science.gov (United States)

    Nagornov, Konstantin O.; Kozhinov, Anton N.; Tsybin, Yury O.

    2017-11-01

    Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) at the cyclotron frequency instead of the reduced cyclotron frequency has been experimentally demonstrated using narrow aperture detection electrode (NADEL) ICR cells. Here, based on the results of SIMION simulations, we provide the initial mechanistic insights into the cyclotron frequency regime generation in FT-ICR MS. The reason for cyclotron frequency regime is found to be a new type of a collective motion of ions with a certain dispersion in the initial characteristics, such as pre-excitation ion velocities, in a highly non-quadratic trapping potential as realized in NADEL ICR cells. During ion detection, ions of the same m/z move in phase for cyclotron ion motion but out of phase for magnetron (drift) ion motion destroying signals at the fundamental and high order harmonics that comprise reduced cyclotron frequency components. After an initial magnetron motion period, ion clouds distribute into a novel type of structures - ion slabs, elliptical cylinders, or star-like structures. These structures rotate at the Larmor (half-cyclotron) frequency on a plane orthogonal to the magnetic field, inducing signals at the true cyclotron frequency on each of the narrow aperture detection electrodes. To eliminate the reduced cyclotron frequency peak upon dipolar ion detection, a number of slabs or elliptical cylinders organizing a star-like configuration are formed. In a NADEL ICR cell with quadrupolar ion detection, a single slab or an elliptical cylinder is sufficient to minimize the intensity of the reduced cyclotron frequency components, particularly the second harmonic. [Figure not available: see fulltext.

  18. Ammonia-treated N-(1-naphthyl) ethylenediamine dihydrochloride as a novel matrix for rapid quantitative and qualitative determination of serum free fatty acids by matrix-assisted laser desorption/ionization-Fourier transform ion cyclotron resonance mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Yaping [Department of Biophysics and Structural Biology, Institute of Basic Medical Sciences, Chinese Academy of Medical Sciences and School of Basic Medicine, Peking Union Medical College, 5 Dongdan San Tiao, Beijing 100005 (China); Wang, Yanmin [Department of Clinical Laboratory, Heze Municipal Hospital, Shandong (China); Guo, Shuai; Guo, Yumei; Liu, Hui [Department of Biophysics and Structural Biology, Institute of Basic Medical Sciences, Chinese Academy of Medical Sciences and School of Basic Medicine, Peking Union Medical College, 5 Dongdan San Tiao, Beijing 100005 (China); Li, Zhili, E-mail: lizhili@ibms.pumc.edu.cn [Department of Biophysics and Structural Biology, Institute of Basic Medical Sciences, Chinese Academy of Medical Sciences and School of Basic Medicine, Peking Union Medical College, 5 Dongdan San Tiao, Beijing 100005 (China)

    2013-09-10

    Graphical abstract: -- Highlights: •A novel MALDI matrix for the detection of serum free fatty acids is ammonia-treated N-(1-naphthyl) ethylenediamine dihydrochloride. •Multiple point internal standard calibration curves were constructed for nine FFAs, respectively, with excellent correlation coefficients between 0.991 and 0.999. •The MALDI-MS approach was used to rapidly differentiate the patients with and without hyperglycemia and healthy controls. -- Abstract: The blood free fatty acids (FFAs), which provide energy to the cell and act as substrates in the synthesis of fats, lipoproteins, liposaccharides, and eicosanoids, involve in a number of important physiological processes. In the present study, matrix-assisted laser desorption/ionization-Fourier transform ion cyclotron resonance mass spectrometry (MALDI-FTICR MS) with ammonia-treated N-(1-naphthyl) ethylenediamine dihydrochloride (ATNEDC) as a novel MALDI matrix in a negative ion mode was employed to directly quantify serum FFAs. Multiple point internal standard calibration curves between the concentration ratios of individual fatty acids to internal standard (IS, C{sub 17:0}) versus their corresponding intensity ratios were constructed for C{sub 14:0}, C{sub 16:1}, C{sub 16:0}, C{sub 18:0}, C{sub 18:1}, C{sub 18:2}, C{sub 18:3}, C{sub 20:4}, and C{sub 22:6}, respectively, in their mixture, with correlation coefficients between 0.991 and 0.999 and limits of detection (LODs) between 0.2 and 5.4 μM, along with the linear dynamic range of more than two orders of magnitude. The results indicate that the multiple point internal standard calibration could reduce the impact of ion suppression and improve quantification accuracy in the MALDI mode. The quantitative results of nine FFAs from 339 serum samples, including 161 healthy controls, 118 patients with hyperglycemia and 60 patients without hyperglycemia show that FFAs levels in hyperglycemic patient sera are significantly higher than those in healthy

  19. A gold-deposited surface plasmon resonance-based optical fiber sensor system using various light-emitting diodes.

    Science.gov (United States)

    Mitsushio, Masaru; Higo, Morihide

    2011-01-01

    The performance of a simple gold (Au)-deposited optical fiber sensor system based on surface plasmon resonance (SPR) is presented. Our sensor system comprises a light-emitting diode (LED) and a photodiode (PD) as the light source and the detector, respectively. The response curves and sensor properties of the Au-deposited optical fiber with a Au film thickness of 45 nm obtained by using three LEDs with 563, 660, and 940 nm emissions were investigated. The sensor properties depend strongly on the wavelength of the incident light and can be controlled by changing the LED emission wavelength. The response curves of the sensor obtained at the three wavelengths and calculated using SPR theoretical equations were compared with those obtained by experimentation. Our sensor system represents a new SPR-based refractometer with performance almost equal to that of an Abbe refractometer. To demonstrate its usefulness, ethanol concentrations in various spirits were measured and the results compared with those as labeled.

  20. Ion cyclotron resonance heating system on Aditya

    Indian Academy of Sciences (India)

    Duration of 500 ms is sufficient for operation on Aditya, however, the same system feeds the final stage of the 1·5 MW ICRH system being prepared for the steady-state superconducting tokamak (SST-1) for a duration of 1000 s. Radio frequency (RF) power (225 kW) has been generated and successfully tested on a dummy ...

  1. Organic Thin Films Deposited by Emulsion-Based, Resonant Infrared, Matrix-Assisted Pulsed Laser Evaporation: Fundamentals and Applications

    Science.gov (United States)

    Ge, Wangyao

    Thin film deposition techniques are indispensable to the development of modern technologies as thin film based optical coatings, optoelectronic devices, sensors, and biological implants are the building blocks of many complicated technologies, and their performance heavily depends on the applied deposition technique. Particularly, the emergence of novel solution-processed materials, such as soft organic molecules, inorganic compounds and colloidal nanoparticles, facilitates the development of flexible and printed electronics that are inexpensive, light weight, green and smart, and these thin film devices represent future trends for new technologies. One appealing feature of solution-processed materials is that they can be deposited into thin films using solution-processed deposition techniques that are straightforward, inexpensive, high throughput and advantageous to industrialize thin film based devices. However, solution-processed techniques rely on wet deposition, which has limitations in certain applications, such as multi-layered film deposition of similar materials and blended film deposition of dissimilar materials. These limitations cannot be addressed by traditional, vacuum-based deposition techniques because these dry approaches are often too energetic and can degrade soft materials, such as polymers, such that the performance of resulting thin film based devices is compromised. The work presented in this dissertation explores a novel thin film deposition technique, namely emulsion-based, resonant infrared, matrix-assisted pulsed laser evaporation (RIR-MAPLE), which combines characteristics of wet and dry deposition techniques for solution-processed materials. Previous studies have demonstrated the feasibility of emulsion-based RIR-MAPLE to deposit uniform and continuous organic, nanoparticle and blended films, as well as hetero-structures that otherwise are difficult to achieve. However, fundamental understanding of the growth mechanisms that govern

  2. Laser-induced resonant excitation of ethylene molecules in C2H4/C2H2/O2 reactions to enhance diamond deposition

    Science.gov (United States)

    Ling, H.; Sun, J.; Han, Y. X.; Gebre, T.; Xie, Z. Q.; Zhao, M.; Lu, Y. F.

    2009-01-01

    Vibrational resonant excitation of ethylene (C2H4) molecules using a carbon dioxide laser was employed to promote reactions in precursors of ethylene, acetylene (C2H2), and oxygen to enhance diamond deposition. One of the vibrational modes (CH2 wag mode, v7) of the C2H4 molecules was selected to achieve the resonant excitation in the reactions. Optical emission spectroscopy was used to study the effects of laser resonant excitation on the reactions for diamond deposition. The optical emissions of CH and C2 species were enhanced with the laser excitation, indicating that there are more active species generated in the reactions. Thicknesses and grain sizes of the deposited films were increased correspondingly. Temperature calculations from the line set in the R-branch of CH emission spectra indicated that a nonthermal process is involved in the enhanced diamond deposition.

  3. Design of RF system for CYCIAE-230 superconducting cyclotron

    Energy Technology Data Exchange (ETDEWEB)

    Yin, Zhiguo, E-mail: bitbearAT@hotmail.com; Ji, Bin; Fu, Xiaoliang; Cao, Xuelong; Zhao, Zhenlu; Zhang, Tinajue

    2017-05-11

    The CYCIAE230 is a low-current, compact superconducting cyclotron designed for proton therapy. The Radio Frequency system consists of four RF cavities and applies second harmonic to accelerate beams. The driving power for the cavity system is estimated to be approximately 150 kW. The LLRF controller is a self-made device developed and tested at low power using a small-scale cavity model. In this paper, the resonator systems of an S.C. cyclotron in history are reviewed. Contrary to those RF systems, the cavities of the CYCIAE230 cyclotron connect two opposite dees. Two high-power RF windows are included in the system. Each window carries approximately 75 kW RF power from the driver to the cavities. Thus, the RF system for the CY-CIAE230 cyclotron is operated in driven push–pull mode. The two-way amplifier-coupler-cavity systems are operated with approximately the same amount of RF power but 180° out of phase compared with each other. The design, as well as the technical advantage and limitations of this operating mode, of the CYCIAE230 cyclotron RF system is analyzed.

  4. Design of RF system for CYCIAE-230 superconducting cyclotron

    Science.gov (United States)

    Yin, Zhiguo; Ji, Bin; Fu, Xiaoliang; Cao, Xuelong; Zhao, Zhenlu; Zhang, Tinajue

    2017-05-01

    The CYCIAE230 is a low-current, compact superconducting cyclotron designed for proton therapy. The Radio Frequency system consists of four RF cavities and applies second harmonic to accelerate beams. The driving power for the cavity system is estimated to be approximately 150 kW. The LLRF controller is a self-made device developed and tested at low power using a small-scale cavity model. In this paper, the resonator systems of an S.C. cyclotron in history are reviewed. Contrary to those RF systems, the cavities of the CYCIAE230 cyclotron connect two opposite dees. Two high-power RF windows are included in the system. Each window carries approximately 75 kW RF power from the driver to the cavities. Thus, the RF system for the CY-CIAE230 cyclotron is operated in driven push-pull mode. The two-way amplifier-coupler-cavity systems are operated with approximately the same amount of RF power but 180° out of phase compared with each other. The design, as well as the technical advantage and limitations of this operating mode, of the CYCIAE230 cyclotron RF system is analyzed.

  5. Surface chemistry of group 11 atomic layer deposition precursors on silica using solid-state nuclear magnetic resonance spectroscopy

    Science.gov (United States)

    Pallister, Peter J.; Barry, Seán T.

    2017-02-01

    The use of chemical vapour deposition (CVD) and atomic layer deposition (ALD) as thin film deposition techniques has had a major impact on a number of fields. The deposition of pure, uniform, conformal thin films requires very specific vapour-solid reactivity that is largely unknown for the majority of ALD and CVD precursors. This work examines the initial chemisorption of several thin film vapour deposition precursors on high surface area silica (HSAS) using 13C, 31P, and quantitative 29Si nuclear magnetic resonance spectroscopy (NMR). Two copper metal precursors, 1,3-diisopropyl-imidazolin-2-ylidene copper (I) hexamethyldisilazide (1) and 1,3-diethyl-imidazolin-2-ylidene copper(I) hexamethyldisilazide (2), and one gold metal precursor, trimethylphosphine gold(III) trimethyl (3), are examined. Compounds 1 and 2 were found to chemisorb at the hydroxyl surface-reactive sites to form a ||-O-Cu-NHC surface species and fully methylated silicon (||-SiMe3, due to reactivity of the hexamethyldisilazane (HMDS) ligand on the precursor) at 150 °C and 250 °C. From quantitative 29Si solid-state NMR (SS-NMR) spectroscopy measurements, it was found that HMDS preferentially reacts at geminal disilanol surface sites while the copper surface species preferentially chemisorbed to lone silanol surface species. Additionally, the overall coverage was strongly dependent on temperature, with higher overall coverage of 1 at higher temperature but lower overall coverage of 2 at higher temperature. The chemisorption of 3 was found to produce a number of interesting surface species on HSAS. Gold(III) trimethylphosphine, reduced gold phosphine, methylated phosphoxides, and graphitic carbon were all observed as surface species. The overall coverage of 3 on HSAS was only about 10% at 100 °C and, like the copper compounds, had a preference for lone silanol surface reactive sites. The overall coverage and chemisorbed surface species have implications to the overall growth rate and purity of

  6. EC-5 fifth international workshop on electron cyclotron emission and electron cyclotron heating

    Energy Technology Data Exchange (ETDEWEB)

    Prater, R.; Lohr, J. [eds.

    1985-12-31

    This report contains papers on the following topics: electron cyclotron emission measurements; electron cyclotron emission theory; electron cyclotron heating; gyrotron development; and ECH systems and waveguide development. These paper have been indexed separately elsewhere. (LSP).

  7. Reduction of axial kinetic energy induced perturbations on observed cyclotron frequency.

    Science.gov (United States)

    Kaiser, Nathan K; Weisbrod, Chad R; Webb, Brian N; Bruce, James E

    2008-04-01

    With Fourier transform ion cyclotron resonance (FTICR) mass spectrometry one determines the mass-to-charge ratio of an ion by measuring its cyclotron frequency. However, the need to confine ions to the trapping region of the ion cyclotron resonance (ICR) cell with electric fields induces deviations from the unperturbed cyclotron frequency. Additional perturbations to the observed cyclotron frequency are often attributed to changes in space charge conditions. This study presents a detailed investigation of the observed ion cyclotron frequency as a function of ion z-axis kinetic energy. In a perfect three-dimensional quadrupolar field, cyclotron frequency is independent of position within the trap. However, in most ICR cell designs, this ideality is approximated only near the trap center and deviations arise from this ideal quadrupolar field as the ion moves both radially and axially from the center of the trap. To allow differentiation between deviations in observed cyclotron frequency caused from changes in space charge conditions or differences in oscillation amplitude, ions with identical molecular weights but different axial kinetic energy, and thus amplitude of z-axis motion, were simultaneously trapped within the ICR cell. This allows one to attribute deviations in observed cyclotron frequency to differences in the average force from the radial electric field experienced by ions of different axial amplitude. Experimentally derived magnetron frequency is compared with the magnetron frequency calculated using SIMION 7.0 for ions of different axial amplitude. Electron promoted ion coherence, or EPIC, is used to reduce the differences in radial electric fields at different axial positions. Thus with the application of EPIC, the differences in observed cyclotron frequencies are minimized for ions of different axial oscillation amplitudes.

  8. BEST medical radioisotope production cyclotrons

    Energy Technology Data Exchange (ETDEWEB)

    Sabaiduc, Vasile; Milton, Bruce; Suthanthiran, Krishnan; Johnson, Richard R. [Best Cyclotron Systems Inc., 7-8765 Ash Street, Vancouver, British Columbia, V6P 6T3 (Canada); Gelbart, W. Z. [Advanced System Designs Inc., 5295 Bear Bay Road, Garden Bay, BC, V0N 1S1 (Canada)

    2013-04-19

    Best Cyclotron Systems Inc (BCSI) is currently developing 14 MeV, 25 MeV, 35MeV and 70MeV cyclotrons for radioisotope production and research applications as well as the entire spectrum of targets and nuclear synthesis modules for the production of Positron Emission Tomography (PET), Single Photon Emission Computed Tomography (SPECT) and radiation therapy isotopes. The company is a subsidiary of Best Medical International, renowned in the field of medical instrumentation and radiation therapy. All cyclotrons have external negative hydrogen ion sources, four radial sectors with two dees in opposite valleys, cryogenic vacuum system and simultaneous beam extraction on opposite lines. The beam intensity ranges from 400 {mu}A to 1000 {mu}A, depending on the cyclotron energy and application.

  9. Resonance

    DEFF Research Database (Denmark)

    Petersen, Nils Holger

    2014-01-01

    A chapter in a book about terminology within the field of medievalism: the chapter discusses the resonance of medieval music and ritual in modern (classical) music culture and liturgical practice.......A chapter in a book about terminology within the field of medievalism: the chapter discusses the resonance of medieval music and ritual in modern (classical) music culture and liturgical practice....

  10. Cyclotron for Beam Therapy Application

    CERN Document Server

    Alenitsky, Yu G; Karamysheva, G A; Kostromin, S A; Mitsyn, G V; Molokanov, A G; Onishchenko, L M; Samsonov, E V; Vorozhtsov, S B; Zaplatin, N L

    2005-01-01

    The basic parameters of the proton isochronous cyclotron on the fixed energy are considered. The energy of protons is $E_{p}\\sim $ 220~MeV, intensity of the extracted beam is $I_{p}\\sim $ 0.1~$\\mu$A. The cyclotron is projected on the basis of compact magnet with four sectors and the diameter of poles 300 cm. Two dees of the accelerating system are located in valleys.

  11. High-throughput and high-sensitivity quantitative analysis of serum unsaturated fatty acids by chip-based nanoelectrospray ionization-Fourier transform ion cyclotron resonance mass spectrometry: early stage diagnostic biomarkers of pancreatic cancer.

    Science.gov (United States)

    Zhang, Yaping; Qiu, Ling; Wang, Yanmin; Qin, Xuzhen; Li, Zhili

    2014-04-07

    In this study, Fourier transform ion cyclotron resonance mass spectrometry (FTICR MS) coupled with chip-based direct-infusion nanoelectrospray ionization source (CBDInanoESI) in a negative ion mode is first employed to evaluate the effect of serum and its corresponding supernatant matrixes on the recoveries of serum free fatty acids (FFAs) based on spike-and-recovery experimental strategy by adding analytes along with analog internal standard (IS). The recoveries between serum (69.8-115.6%) and the supernatant (73.6-99.0%) matrixes are almost identical. Multiple point internal standard calibration curves between the concentration ratios of individual fatty acids to ISs, (C(17:1) as IS of C(16:1), C(18:3), C(18:2), or C(18:1) or C(21:0) as IS of C(20:4) or C(22:6)) versus their corresponding intensity ratios were constructed for C(16:1), C(18:3), C(18:2), C(18:1), C(20:4) and C(22:6), respectively, with correlation coefficients of greater than 0.99, lower limits of detection between 0.3 and 1.8 nM, and intra- and inter-day precision (relative standard deviations <18%), along with the linear dynamic range of three orders of magnitude. Sequentially, this advanced analytical platform was applied to perform simultaneous quantitative and qualitative analysis of multiple targets, e.g., serum supernatant unsaturated FFAs from 361 participants including 95 patients with pancreatic cancer (PC), 61 patients with pancreatitis and 205 healthy controls. Experimental results indicate that the levels of C(18:1), C(18:2), C(18:3), C(20:4) and C(22:6), as well as the level ratios of C(18:2)/C(18:1) and C(18:3)/C(18:1) of the PC patients were significantly decreased compared with those of healthy controls and the patients with pancreatitis (p < 0.01). It is worth noting that the ratio of C(18:2)/C(18:1), polyunsaturated fatty acids (PUFAs) (C(18:2), C(18:3), C(20:4), and C(22:6)), panel a (C(16:1), C(18:3), C(18:2), C(20:4) and C(22:6)) and panel b (C(18:2)/C(18:1) and C(18:3)/C(18

  12. Resonances

    DEFF Research Database (Denmark)

    an impetus or drive to that account: change, innovation, rupture, or discontinuity. Resonances: Historical Essays on Continuity and Change explores the historiographical question of the modes of interrelation between these motifs in historical narratives. The essays in the collection attempt to realize...... theoretical consciousness through historical narrative ‘in practice’, by discussing selected historical topics from Western cultural history, within the disciplines of history, literature, visual arts, musicology, archaeology, philosophy, and theology. The title Resonances indicates the overall perspective...... of the book: how connotations of past meanings may resonate through time, in new contexts, assuming new meanings without surrendering the old....

  13. Combined time-lapse magnetic resonance imaging and modeling to investigate colloid deposition and transport in porous media.

    Science.gov (United States)

    Lehoux, Alizée P; Faure, Pamela; Lafolie, François; Rodts, Stéphane; Courtier-Murias, Denis; Coussot, Philippe; Michel, Eric

    2017-10-15

    Colloidal particles can act as vectors of adsorbed pollutants in the subsurface, or be themselves pollutants. They can reach the aquifer and impair groundwater quality. The mechanisms of colloid transport and deposition are often studied in columns filled with saturated porous media. Time-lapse profiles of colloid concentration inside the columns have occasionally been derived from magnetic resonance imaging (MRI) data recorded in transport experiments. These profiles are valuable, in addition to particle breakthrough curves (BTCs), for testing and improving colloid transport models. We show that concentrations could not be simply computed from MRI data when both deposited and suspended colloids contributed to the signal. We propose a generic method whereby these data can still be used to quantitatively appraise colloid transport models. It uses the modeled suspended and deposited particle concentrations to compute modeled MRI data that are compared to the experimental data. We tested this method by performing transport experiments with sorbing colloids in sand, and assessed for the first time the capacity of the model calibrated from BTCs to reproduce the MRI data. Interestingly, the dispersion coefficient and deposition rate calibrated from the BTC were respectively overestimated and underestimated compared with those calibrated from the MRI data, suggesting that these quantities, when determined from BTCs, need to be interpreted with care. In a broader perspective, we consider that combining MRI and modeling offers great potential for the quantitative analysis of complex MRI data recorded during transport experiments in complex environmentally relevant porous media, and can help improve our understanding of the fate of colloids and solutes, first in these media, and later in soils. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. Multifocal hemosiderin depositions on T2*-weighted magnetic resonance imaging in a patient with pathology-proven systemic diffuse large B-cell lymphoma.

    Science.gov (United States)

    Yang, Xun-zhe; Ni, Jun; Cui, Li-ying

    2014-09-25

    Intracranial hemorrhage in central nervous system lymphoma is extremely rare. T2*-weighted gradient-echo magnetic resonance imaging is of particularly use in detecting silent hemorrhage as hypointense signals due to the deposition of paramagnetic hemosiderin or mineralization. Multifocal hemosiderin depositions caused by chronic silent hemorrhage have not yet been identified in patients with central nervous system involvement of systemic lymphoma. We present an unexpected radiographic feature on T2*-weighted gradient-echo magnetic resonance imaging in a patient with central nervous system involvement of pathologically confirmed systemic diffuse large B-cell lymphoma. A 56-year-old woman presented with lower extremities weakness and progressive cognitive decline for four months. Conventional brain magnetic resonance imaging demonstrated multiple lesions with hypointensities on T1-weighted images and hyperintensities on T2-weighted images and fluid attenuated inversion recovery in both hemispheres. She was then transferred to our hospital. This is the first report of pathologically confirmed case of CNS involvement of systemic diffuse large B-cell lymphoma with multifocal silent hemosiderin depositions detected by T2*-weighted gradient-echo magnetic resonance imaging. Even though uncommon, our report offers an insight that CNS lymphoma could present with multifocal silent hemosiderin depositions on T2*-weighted gradient-echo magnetic resonance imaging. Further studies were expected for exploring the association between this radiologic feature and systemic lymphoma and their underlying mechanisms.

  15. High-Resolution Ion Cyclotron Mobility Spectrometry

    Science.gov (United States)

    Merenbloom, Samuel I.; Glaskin, Rebecca S.; Henson, Zachary B.; Clemmer, David E.

    2009-01-01

    A novel ion mobility spectrometry instrument incorporating a cyclotron geometry drift tube is presented. The drift tube consists of eight regions, four curved drift tubes and four ion funnels. Packets of ions are propagated around the drift tube by changing the drift field at a frequency that is resonant with the ion’s drift time through each region. The approach trims each packet of ions as it leaves and enters each new region. An electrostatic gate allows ions to be kept in the drift tube for numerous cycles, increasing the ability to resolve specified ions. We demonstrate the approach by isolating the [M+2H]2+ or [M+3H]3+ charge state of substance P as well as individual trisaccharide isomers from a mixture of melezitose and raffinose. Resolving powers in excess of 300 are obtainable with this approach. PMID:19143495

  16. RESONANCE

    Indian Academy of Sciences (India)

    Nuclear magnetic resonance (NMR) is a mani- festation of an intrinsic property of the nucleus, i.e. nuclear spin angular momen- tum. Spin angular momentum gives rise to magnetic moments. Thus, nuclei that pos- sess net magnetic moments behave like very small bar magnets. NMR spectroscopy in- volves the study of the ...

  17. The development of technology for the improvement of cyclotron performance

    Energy Technology Data Exchange (ETDEWEB)

    Chai, Jong Seo; Kim, Y. S.; Ha, J. H.; Lee, M. Y.; Lee, H. S

    1999-05-01

    We show the first-order beam optics theory which is a simplified theory that can be used to carry out the initial design of a cyclotron. Based on this, a computer program has been developed to determine main cyclotron parameters such as number of magnet sectors, sector angle, hill and valley fields, and overall size of the cyclotron etc. We then show the result of two-dimensional magnetic field calculation using POISSON program. By using this program, one can determine magnet yoke geometry and the average magnetic fields etc. Finally, the three-dimensional computer program OPERA-3D had been invoked to determine magnet pole tips (i.e. sector). Validity of the design can be seen by investigating magnetic fields, radial and vertical focusing frequencies as a function of the beam energy. In this report, we show the results of cyclotron magnet design. And we designed 72 MHz RF system and ion source system. We tested RF resonance each coupling methods. We show the result of RF design and prototype operation. Our developed ion source is PIG type. We described our design methods and implementation. We report the result of getting negative hydrogen ion.

  18. MC-50 AVF cyclotron operation

    Energy Technology Data Exchange (ETDEWEB)

    Chae, Jong Seo; Lee, Dong Hoon; Kim, You Seok; Park, Chan Won; Lee, Yong Min; Hong, Sung Seok; Lee, Min Yong

    1995-12-01

    The first cyclotron in Korea, MC-59 cyclotron is used for neutron irradiation, radionuclide development, production and material and biomedical research. 50.5MeV and 35MeV proton beam have been extracted with 20-70 .mu.A. A total of beam extraction time are 1095.7 hours. 206.5 hours are used for the developments and 663.8 hours are for radionuclide production and development and 225.4 hours for application researches. The shutdown days are 23days. Fundamental data for failure decrement and efficient beam extraction were composed and maintenance technologies were developed. (author). 8 tabs., 17 figs., 10 refs.

  19. MC-50 AVF cyclotron operation

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Yu Seok; Chai, Jong Seo; Bak, Seong Ki; Park, Chan Won; Jo, Young Ho; Hong, Seong Seok; Lee, Min Yong; Jang Ho Ha

    2000-01-01

    The first cyclotron in Korea, MC-50 cyclotron is used for neutron irradiation, radionuclide development, production and material and biomedical research. 50.5MeV and 35MeV proton beam have been extracted with 20-60{mu}A. A total of beam extraction time are 1095.7 hours. 206.5 hours are used for the developments and 663.8 hours are for radionuclide production and development and 225.4 hours for application researches. The shutdown days are 23 days. Fundamental data for failure decrement and efficient beam extraction were composed and maintenance technologies were developed.

  20. Research of the Electron Cyclotron Emission with Vortex Property excited by high power high frequency Gyrotron

    Science.gov (United States)

    Goto, Yuki; Kubo, Shin; Tsujimura, Tohru; Takubo, Hidenori

    2017-10-01

    Recently, it has been shown that the radiation from a single electron in cyclotron motion has vortex property. Although the cyclotron emission exists universally in nature, the vortex property has not been featured because this property is normally cancelled out due to the randomness in gyro-phase of electrons and the development of detection of the vortex property has not been well motivated. In this research, we are developing a method to generate the vortex radiation from electrons in cyclotron motion with controlled gyro-phase. Electron that rotates around the uniform static magnetic field is accelerated by right-hand circular polarized (RHCP) radiation resonantly when the cyclotron frequency coincides with the applied RHCP radiation frequency. A large number of electrons can be coherently accelerated in gyro-phase by a RHCP high power radiation so that these electrons can radiate coherent emission with vortex feature. We will show that vortex radiation created by purely rotating electrons for the first time.

  1. Cyclotron transitions of bound ions

    Science.gov (United States)

    Bezchastnov, Victor G.; Pavlov, George G.

    2017-06-01

    A charged particle in a magnetic field possesses discrete energy levels associated with particle rotation around the field lines. The radiative transitions between these levels are the well-known cyclotron transitions. We show that a bound complex of particles with a nonzero net charge displays analogous transitions between the states of confined motion of the entire complex in the field. The latter bound-ion cyclotron transitions are affected by a coupling between the collective and internal motions of the complex and, as a result, differ from the transitions of a "reference" bare ion with the same mass and charge. We analyze the cyclotron transitions for complex ions by including the coupling within a rigorous quantum approach. Particular attention is paid to comparison of the transition energies and oscillator strengths to those of the bare ion. Selection rules based on integrals of collective motion are derived for the bound-ion cyclotron transitions analytically, and the perturbation and coupled-channel approaches are developed to study the transitions quantitatively. Representative examples are considered and discussed for positive and negative atomic and cluster ions.

  2. Lymphedema Leads to Fat Deposition in Muscle and Decreased Muscle/Water Volume After Liposuction: A Magnetic Resonance Imaging Study.

    Science.gov (United States)

    Hoffner, Mattias; Peterson, Pernilla; Månsson, Sven; Brorson, Håkan

    2017-09-28

    Lymphedema leads to adipose tissue deposition. Water-fat magnetic resonance imaging (MRI) can quantify and localize fat and water. The presence of excess fat and excess water/muscle in the subfascial compartment of the lymphedematous limb has not been investigated before. The aim of this study was to investigate epifascial and subfascial fat and water contents in patients with chronic lymphedema before and after liposuction. Seven patients with arm lymphedema and six with leg lymphedema were operated on. The limbs were examined with water-fat MRI before liposuction (baseline) and at five time points. Complete reduction of the excess limb volumes was achieved. The excess epifascial fat was evident in the edematous limbs and a drop was seen following surgery. There were differences in excess water at all time points. At 1 year there was a decrease in excess water. Excess subfascial fat was seen in the edematous limbs at all time points. Subfascial excess water/muscle did not show any differences after surgery. However, starting from 3 months there was less subfascial water/muscle compared with baseline. Subfascial fat in the lymphedematous limbs did not change. In contrast, the water in the subfascial compartment was reduced over time, which may represent a decrease of muscle volume after treatment due to less mechanical load after liposuction. Using water-fat MRI-based fat quantification, the fat and water contents may be quantified and localized in the various compartments in lymphedema.

  3. Orbit-averaged quasilinear diffusion operator in the ion-cyclotron range of frequencies

    Science.gov (United States)

    Belmondo, V.; Bilato, R.; Brambilla, M.; Maj, O.

    2010-11-01

    The absorption of radio-frequency waves in the ion-cyclotron range of frequencies (ICRF) in fusion plasmas is adequately described in the frame of the quasilinear theory. A peculiarity of ICRF heating is to increase the fraction of trapped particles, whose the guiding-center trajectories are typically banana orbits with finite width. One possible way to properly account for the effects due to the finite-width orbits is provided by the orbit-averaged quasilinear theory. Here, we propose a routine for the evaluation of the orbit-averaged quasilinear diffusion tensor, given the the wave fields from the full wave code TORIC. Particular care is taken in the evaluation of the contribution of each wave-particle resonance as well as for the transition between the two regimes of correlated and uncorrelated resonances along the orbit. We discuss the quasilinear diffusion coefficient thus obtained and validate the result by comparing the power deposition profile computed from the orbit-averaged quasilinear operator with the one determined by TORIC. For future applications, a novel algorithm for the calculation of the corresponding Monte Carlo operators is also presented.

  4. Physics of electron cyclotron current drive on DIII-D

    CERN Document Server

    Petty, C C; Harvey, R W; Kinsey, J E; Lao, L L; Lohr, J; Luce, T C; Makowski, M A; Prater, R

    2002-01-01

    OAK A271 PHYSICS OF ELECTRON CYCLOTRON CURRENT DRIVE ON DIII-D. Recent experiments on the DIII-D tokamak have focused on determining the effect of trapped particles on the electron cyclotron current drive (ECCD) efficiency. The measured ECCD efficiency increases as the deposition location is moved towards the inboard midplane or towards smaller minor radius for both co and counter injection. The measured ECCD efficiency also increases with increasing electron density and/or temperature. The experimental ECCD is compared to both the linear theory (Toray-GA) as well as a quasilinear Fokker-Planck model (CQL3D). The experimental ECCD is found to be in better agreement with the more complete Fokker-Planck calculation, especially for cases of high rf power density and/or loop voltage. The narrow width of the measured ECCD profile is consistent with only low levels of radial transport for the current carrying electrons.

  5. TRIUMF cyclotron vacuum system refurbishing

    Science.gov (United States)

    Sekachev, I.

    2008-03-01

    The cyclotron at TRIUMF was commissioned to full energy in 1974. The volume of the cyclotron vacuum tank is about 100 m3 and it operates at 5×10-8 Torr pressure during beam production. The pumping is mainly based on a Phillips B-20 cryogenerator (Stirling cycle 4-cylinder engine). The cryogenerator supplies helium gas at 16 K and 70 K to cryopanels in the tank. The decreasing reliability of the B-20 and demanding maintenance requirements triggered the decision to completely overhaul or replace the cryogenerator. Replacement with the LINDE-1630 helium refrigerator was found to be the most attractive (technically and economically) option. The details of the proposal with installation of the helium refrigerator and with a continuous flow liquid nitrogen shield cooling system are presented.

  6. The development of cyclotron radiopharmaceuticals

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Seung Dae; Chun, K. W.; Suh, Y. S.; Lee, J. D.; Ahn, S. H. and others

    1999-03-01

    The purpose of this project is to developthe radiopharmaceuticals and automatic synthetic unit for labelled compounds, and to establish mass production system of radiopharmaceuticals. These will contribute to the early diagnosis of the disease hard to cure. The contents of this project are as follows, the development of the radiopharmaceutical for imaging of cancer, the development of automatic synthesizer for the synthesis of radio-pharmaceuticals, the development of hormone derivatives labelled with {sup 12}'3I, the development of the radiopharmaceuticals for therapy of cancer labelled with cyclotron produced radionuclides, the development of radiopharmaceuticals for therapy of cancer labelled with cyclotron produced radionuclides, the development of radiopharmaceuticals for imaging of myocardial metabolism.

  7. Experiments on ion cyclotron damping at the deuterium fourth harmonic in DIII-D

    Energy Technology Data Exchange (ETDEWEB)

    Pinsker, R. I. [General Atomics, P.O. Box 85608, San Diego, California 92186-5608 (United States); Baity, F. W. [Oak Ridge National Laboratory, Oak Ridge, Tennessee (United States); Bernabei, S. [Princeton Plasma Physics Laboratory, Princeton, New Jersey (United States); Greenough, N. [Princeton Plasma Physics Laboratory, Princeton, New Jersey (United States); Heidbrink, W. W. [University of California, Irvine, California (United States); Mau, T. K. [University of California, San Diego, California (United States); Petty, C. C. [General Atomics, P.O. Box 85608, San Diego, California 92186-5608 (United States); Porkolab, M. [Massachusetts Institute of Technology, Cambridge, Massachusetts (United States)

    1999-09-20

    Absorption of fast Alfven waves by the energetic ions of an injected beam is evaluated in the DIII-D tokamak. Ion cyclotron resonance absorption at the fourth harmonic of the deuteron cyclotron frequency is observed with deuterium neutral beam injection (f=60 MHz, B{sub T}=1.9 T). Enhanced D-D neutron rates are evidence of absorption at the Doppler-shifted cyclotron resonance. Characteristics of global energy confinement provide further proof of substantial beam acceleration by the rf. In many cases, the accelerated deuterons cause temporary stabilization of the sawtooth (''monster sawteeth''), at relatively low rf power levels of {approx}1 MW. (c) 1999 American Institute of Physics.

  8. Method and apparatus for ion cyclotron spectrometry

    Science.gov (United States)

    Dahl, David A [Idaho Falls, ID; Scott, Jill R [Idaho Falls, ID; McJunkin, Timothy R [Idaho Falls, ID

    2010-08-17

    An ion cyclotron spectrometer may include a vacuum chamber that extends at least along a z-axis and means for producing a magnetic field within the vacuum chamber so that a magnetic field vector is generally parallel to the z-axis. The ion cyclotron spectrometer may also include means for producing a trapping electric field within the vacuum chamber that includes at least a first section that induces a first magnetron effect that increases a cyclotron frequency of an ion and at least a second section that induces a second magnetron effect that decreases the cyclotron frequency of an ion. The cyclotron frequency changes induced by the first and second magnetron effects substantially cancel one another so that an ion traversing the at least first and second sections will experience no net change in cyclotron frequency.

  9. Influence of injection beam emittance on beam transmission efficiency in a cyclotron.

    Science.gov (United States)

    Kurashima, Satoshi; Kashiwagi, Hirotsugu; Miyawaki, Nobumasa; Yoshida, Ken-Ichi; Okumura, Susumu

    2014-02-01

    The JAEA AVF cyclotron accelerates various kinds of high-energy ion beams for research in biotechnology and materials science. Beam intensities of an ion species of the order of 10(-9)-10(-6) ampere are often required for various experiments performed sequentially over a day. To provide ion beams with sufficient intensity and stability, an operator has to retune an ion source in a short time. However, the beam intensity downstream of the cyclotron rarely increases in proportion to the intensity at the ion source. To understand the cause of this beam behavior, transmission efficiencies of a (12)C(5+) beam from an electron cyclotron resonance ion source to the cyclotron were measured for various conditions of the ion source. Moreover, a feasible region for acceleration in the emittance of the injection beam was clarified using a transverse-acceptance measuring system. We confirmed that the beam emittance and profile were changed depending on the condition of the ion source and that matching between the beam emittance and the acceptance of the cyclotron was degraded. However, after fine-tuning to improve the matching, beam intensity downstream of the cyclotron increased.

  10. Observation of quasi-periodic frequency sweeping in electron cyclotron emission of nonequilibrium mirror-confined plasma

    CERN Document Server

    Viktorov, M E; Mansfeld, D A; Golubev, S V

    2016-01-01

    Chirping frequency patterns have been observed in the electron cyclotron emission from strongly nonequilibrium plasma confined in a table-top mirror magnetic trap. Such patterns are typical for the formation of nonlinear phase space structures in a proximity of the wave-particle resonances of a kinetically unstable plasma, also known as the "holes and clumps" mechanism. Our data provides the first experimental evidence for acting of this mechanism in the electron cyclotron frequency domain.

  11. Quantitative T2* magnetic resonance imaging for evaluation of iron deposition in the brain of β-thalassemia patients.

    Science.gov (United States)

    Akhlaghpoor, S; Ghahari, A; Morteza, A; Khalilzadeh, O; Shakourirad, A; Alinaghizadeh, M R

    2012-09-01

    Iron overload is a common clinical problem in patients with β-thalassemia major. The purpose of this study was to assess the presence of excess iron in certain areas of the brain (thalamus, midbrain, adenohypophysis and basal ganglia) in patients with β-thalassemia major and evaluate the association with serum ferritin and liver iron content. A cross-sectional study on 53 patients with β-thalassemia major and 40 healthy controls was carried out. All patients and healthy controls underwent magnetic resonance imaging (MRI) examinations of the brain and liver. Multiecho fast gradient echo sequence was used and T2* values were calculated based on the Brompton protocol. Correlations between T2* values in the brain with T2* values in the liver as well as serum ferritin levels were investigated. There were no significant differences between patients and healthy controls with respect to age and sex. Patients had significantly lower T2* values in basal ganglia (striatum), thalamus and adenohypophysis compared to controls while there were no differences in the midbrain (red nucleus). There were no significant correlations between liver T2* values or serum ferritin with T2* values of basal ganglia (striatum), thalamus and adenohypophysis in patients or healthy controls. There were no significant correlations between T2* values of adenohypophysis and thalamus or basal ganglia (striatum) while these variables were significantly correlated in healthy controls. Serum ferritin and liver iron content may not be good indicators of brain iron deposition in patients with β thalassemia major. Nevertheless, the quantitative T2* MRI technique is useful for evaluation of brain iron overload in β thalassemia major patients.

  12. Niobium thin film coating on a 500-MHz copper cavity by plasma deposition

    Energy Technology Data Exchange (ETDEWEB)

    Haipeng Wang; Genfa Wu; H. Phillips; Robert Rimmer; Anne-Marie Valente; Andy Wu

    2005-05-16

    A system using an Electron Cyclotron Resonance (ECR) plasma source for the deposition of a thin niobium film inside a copper cavity for superconducting accelerator applications has been designed and is being constructed. The system uses a 500-MHz copper cavity as both substrate and vacuum chamber. The ECR plasma will be created to produce direct niobium ion deposition. The central cylindrical grid is DC biased to control the deposition energy. This paper describes the design of several subcomponents including the vacuum chamber, RF supply, biasing grid and magnet coils. Operational parameters are compared between an operating sample deposition system and this system. Engineering work progress toward the first plasma creation will be reported here.

  13. Deposition of low stress, high transmittance SiC as an x-ray mask membrane using ECR plasma CVD

    CERN Document Server

    Lee, S Y; Lim, S T; Ahn, J H

    1998-01-01

    SiC for x-ray mask membrane is deposited by Electron Cyclotron Resonance plasma Chemical Vapor Deposition from SiH sub 4 /CH sub 4 Ar mixtures. Stoichiometric SiC is deposited at SiH sub 4 /CH sub 4 ratio of 0.4, deposition temperature of 600.deg.C and microwave power of 500 W with +- 5% thickness uniformity, As-deposited film has compressive residual stress, very smooth surface (31 A rms) and high optical transmittance of 90% at 633 nm wavelength. The microstructure of this film consists of the nanocrystalline particle (100 A approx 200A) embedded in amorphous matrix. Residual stress can be turned to tensile stress via Rapid Thermal Annealing in N sub 2 atmosphere, while suppressing structural change during annealing, As a result, smooth (37 A rms) SiC film with moderate tensile stress and high optical transmittance (85% at 633 nm wavelength) is obtained.

  14. Determination of Magnet Specification of 13 MeV Proton Cyclotron Based on Opera 3D

    Directory of Open Access Journals (Sweden)

    Taufik

    2014-08-01

    Full Text Available The magnet is one of the main components of a cyclotron, used to form a circular particle beam trajectories and to provide focusing of the beam. To support the mastery of 13-MeV proton cyclotron technologies, cyclotron magnet design must be done to satisfy cyclotron magnet requirements. This research was conducted by studying important parameters in designing the cyclotron magnet which is then used to determine the design requirements. The magnet design was based on the results of a 3D simulation using Opera 3D software. Opera 3D is a software developed by Cobham plc to solve physical problems in 3D such as magnetostatic using finite element methods. The simulation started by drawing a 3D model of the magnet using a modeler, followed by magnetic field calculations by Tosca module in the Opera 3D software. Simulation results were analyzed with the Genspeo software to determine whether the parameters of the cyclotron magnet have met design requirements. The results indicate that the magnet design satisfied the cyclotron magnet design requirement, that B in the median plane of the magnetic pole approached the isochronous curve, providing axial and radial focusing beam, crossing the resonance line at vr = 1 when the particle energy is low and the particle energy is more than 13 MeV, and lead to small enough phase shift of about 13°. The dimension of the cyclotron magnet is 1.96 m × 1.30 m × 1.21 m; its weight is 17.3 ton; its coil current is 88,024 ampere-turn; its center magnetic field is 1.27479 T; its maximum magnetic field is 1.942116 T; its minimum magnetic field is 0.7689 T; its valley gap is 120 mm; its hill gaps are 40 to 50.78 mm; and its hill angles are 35° to 44°.to 44°

  15. Annealing effects on the ferromagnetic resonance linewidths of sputter-deposited Fe{sub 100−x}Co{sub x}(001) thin films (x < 11)

    Energy Technology Data Exchange (ETDEWEB)

    Kusaoka, A.; Kimura, J.; Takahashi, Y., E-mail: takahasy@yz.yamagata-u.ac.jp; Inaba, N. [Graduate School of Science and Engineering, Yamagata University, Yonezawa, Yamagata 992-8510 (Japan); Kirino, F. [Graduate School of Fine Arts, Tokyo National University of Fine Arts and Music, Tokyo 110-8714 (Japan); Ohtake, M.; Futamoto, M. [Faculty of Science and Engineering, Chuo University, Tokyo 112-8551 (Japan)

    2015-05-07

    Effects of post-growth annealing on the magnetic damping of 3d transition alloy thin films were investigated. Fe{sub 100−x}Co{sub x} (x < 11 at. %) thin films were epitaxially deposited on GaAs(001) substrates by rf magnetron sputtering, and some of them were annealed without exposing to atmosphere. Electrical measurement showed that in-plane resistivity was smaller in the annealed films than in the as-deposited ones, indicating that the annealing mitigates crystalline imperfections and leads to reduced electron scattering rates. Magnetic damping was evaluated by the peak widths of ferromagnetic resonance (FMR) spectra obtained by a conventional Q-band spectrometer. Comparison of as-deposited and annealed specimens showed that the damping was decreased by annealing. Combined with the electrical and FMR measurements, these observations are consistent with the theoretical predictions that crystalline imperfections strongly influence the magnetic damping, both in intrinsic and extrinsic origins.

  16. The smooth cyclotron line in Her X-1 as seen with NuSTAR

    DEFF Research Database (Denmark)

    Fuerst, Felix; Grefenstette, Brian W.; Staubert, Ruediger

    2013-01-01

    Her X-1, one of the brightest and best studied X-ray binaries, shows a cyclotron resonant scattering feature (CRSF) near 37 keV. This makes it an ideal target for detailed study with the Nuclear Spectroscopic Telescope Array (NuSTAR), taking advantage of its excellent hard X-ray spectral resolution...

  17. The smooth cyclotron line in her x-1 as seen with nuclear spectroscopic telescope array

    DEFF Research Database (Denmark)

    Fuerst, Felix; Grefenstette, Brian W.; Staubert, Ruediger

    2013-01-01

    Her X-1, one of the brightest and best studied X-ray binaries, shows a cyclotron resonant scattering feature (CRSF) near 37 keV. This makes it an ideal target for detailed study with the Nuclear Spectroscopic Telescope Array (NuSTAR), taking advantage of its excellent hard X-ray spectral resolution...

  18. A remotely steered millimetre wave launcher for electron cyclotron heating and current drive on ITER

    NARCIS (Netherlands)

    Bongers, W. A.; M. F. Graswinckel,; Goede, A. P. H.; Kasparek, W.; Danilov, I.; Curto, A. F.; M.R. de Baar,; van den Berg, M. A.; Donne, A. J. H.; Elzendoorn, B. S. Q.; Heidinger, R.; Ivanov, P.; Kruijt, O. G.; Lamers, B.; Meier, A.; Piosczyk, B.; Plaum, B.; Ronden, D. M. S.; Thoen, D. J.; Schmid, M.; Verhoeven, A. G. A.

    2010-01-01

    High-power millimetre wave beams employed on ITER for heating and Current drive at the 170 GHz electron cyclotron resonance frequency require agile steering and tight focusing of the beams to suppress neoclassical tearing modes. This paper presents experimental validation of the remote steering (RS)

  19. A Suzaku View of Cyclotron Line Sources and Candidates

    Science.gov (United States)

    Pottschmidt, K.; Suchy, S.; Rivers, E.; Rothschild, R. E.; Marcu, D. M.; Barragan, L.; Kuehnel, M.; Fuerst, F.; Schwarm, F.; Kreykenbohm, I.; hide

    2012-01-01

    Seventeen accreting neutron star pulsars, mostly high mass X-ray binaries with half of them Be-type transients, are known to exhibit Cyclotron Resonance Scattering Features (CRSFs) in their X-ray spectra, with characteristic line energies from 10 to 60 keY. To date about two thirds of them, plus a few similar systems without known CRSFs, have been observed with Suzaku. We present an overview of results from these observations, including the discovery of a CRSF in the transient IA1118-61 and pulse phase resolved spectroscopy of OX 301-2. These observations allow for the determination of cyclotron line parameters to an unprecedented degree of accuracy within a moderate amount of observing time. This is important since these parameters vary - e.g., with orbital phase, pulse phase, or luminosity - depending on the geometry of the magnetic field of the pulsar and the properties of the accretion column at the magnetic poles. We briefly introduce a spectral model for CRSFs that is currently being developed and that for the first time is based on these physical properties. In addition to cyclotron line measurements, selected highlights from the Suzaku analyses include dip and flare studies, e.g., of 4U 1907+09 and Vela X-I, which show clumpy wind effects (like partial absorption and/or a decrease in the mass accretion rate supplied by the wind) and may also display magnetospheric gating effects.

  20. The cyclotron laboratory and the RFQ accelerator in Bern

    Science.gov (United States)

    Braccini, S.; Ereditato, A.; Kreslo, I.; Nirkko, M.; Scampoli, P.; von Bremen, K.; Weber, M.

    2013-07-01

    Two proton accelerators have been recently put in operation in Bern: an 18 MeV cyclotron and a 2 MeV RFQ linac. The commercial IBA 18/18 cyclotron, equipped with a specifically conceived 6 m long external beam line ending in a separate bunker, will provide beams for routine 18-F and other PET radioisotope production as well as for novel detector, radiation biophysics, radioprotection, radiochemistry and radiopharmacy developments. The accelerator is embedded into a complex building hosting two physics laboratories and four Good Manufacturing Practice (GMP) laboratories. This project is the result of a successful collaboration between the Inselspital, the University of Bern and private investors, aiming at the constitution of a combined medical and research centre able to provide the most cutting-edge technologies in medical imaging and cancer radiation therapy. The cyclotron is complemented by the RFQ with the primary goals of elemental analysis via Particle Induced Gamma Emission (PIGE), and the detection of potentially dangerous materials with high nitrogen content using the Gamma-Resonant Nuclear Absorption (GRNA) technique. In this context, beam instrumentation devices have been developed, in particular an innovative beam profile monitor based on doped silica fibres and a setup for emittance measurements using the pepper-pot technique. On this basis, the establishment of a proton therapy centre on the campus of the Inselspital is in the phase of advanced study.

  1. The cyclotron laboratory and the RFQ accelerator in Bern

    Energy Technology Data Exchange (ETDEWEB)

    Braccini, S.; Ereditato, A.; Kreslo, I.; Nirkko, M.; Weber, M. [Albert Einstein Center for Fundamental Physics, Laboratory for High Energy Physics (LHEP), University of Bern, Sidlerstrasse 5, CH-3012 Bern (Switzerland); Scampoli, P. [Albert Einstein Center for Fundamental Physics, Laboratory for High Energy Physics (LHEP), University of Bern, Sidlerstrasse 5, CH-3012 Bern, Switzerland and Department of Physical Sciences, University Federico II, Via Cintia, I-60126 Napoli (Italy); Bremen, K. von [SWAN Isotopen AG, Inselspital, CH-3010 Bern (Switzerland)

    2013-07-18

    Two proton accelerators have been recently put in operation in Bern: an 18 MeV cyclotron and a 2 MeV RFQ linac. The commercial IBA 18/18 cyclotron, equipped with a specifically conceived 6 m long external beam line ending in a separate bunker, will provide beams for routine 18-F and other PET radioisotope production as well as for novel detector, radiation biophysics, radioprotection, radiochemistry and radiopharmacy developments. The accelerator is embedded into a complex building hosting two physics laboratories and four Good Manufacturing Practice (GMP) laboratories. This project is the result of a successful collaboration between the Inselspital, the University of Bern and private investors, aiming at the constitution of a combined medical and research centre able to provide the most cutting-edge technologies in medical imaging and cancer radiation therapy. The cyclotron is complemented by the RFQ with the primary goals of elemental analysis via Particle Induced Gamma Emission (PIGE), and the detection of potentially dangerous materials with high nitrogen content using the Gamma-Resonant Nuclear Absorption (GRNA) technique. In this context, beam instrumentation devices have been developed, in particular an innovative beam profile monitor based on doped silica fibres and a setup for emittance measurements using the pepper-pot technique. On this basis, the establishment of a proton therapy centre on the campus of the Inselspital is in the phase of advanced study.

  2. 76 FR 80982 - International Cyclotron, Inc., Hato Rey, Puerto Rico; Order Suspending Licensed Activities

    Science.gov (United States)

    2011-12-27

    ...-0292] International Cyclotron, Inc., Hato Rey, Puerto Rico; Order Suspending Licensed Activities I International Cyclotron, Inc. (International Cyclotron; Licensee) is the holder of Byproduct Materials License... International Cyclotron submitted its NRC license application related to the cyclotron, it requested...

  3. Radiation surveillance in and around cyclotron facility

    Science.gov (United States)

    Kaur, Amandeep; Sharma, Sarika; Mittal, BR

    2012-01-01

    The cyclotron is the most widely used particle accelerator for producing medically important radio nuclides. Many medical centers in India have installed compact medical cyclotrons for on-site production of short-lived positron-emitting radio nuclides such as 18F, 13N, and 11C. A mandatory requirement for cyclotron installation is radiation control permit from Atomic Energy Regulatory Board. Cyclotron radiation survey is an integral part of the overall radiation safety in the cyclotron facility. Radiation surveillance in and around a newly installed cyclotron was performed using ionization chamber counter and Geiger Muller counter before, during and after operating the cyclotron. The readings were recorded at various locations where a high radiation field was expected. The results were recorded, tabulated and analyzed. The highest exposure level (0.93 μSv) was found at the back wall of the radiochemistry lab facing the cyclotron vault. Reason for the high exposure of 0.93 μSv/h: Synthesis of 18F-Fluoro-Deoxy-Glucose (18F-FDG) was going in the synthesis module and activity (18F) was present in the synthesis module when reading was taken. All other values were found to be below the recommended levels of exposure. PMID:24019654

  4. Determination of electromagnetic modes in oversized corrugated waveguides on the electron cyclotron resonance heating installation at the tokamak Tore Supra; Determination de modes electromagnetiques de guides d'ondes corrugues surdimensionnes sur l'installation de chauffage des electrons de tokamak Tore Supra

    Energy Technology Data Exchange (ETDEWEB)

    Courtois, L

    2001-03-09

    Electron cyclotron resonance heating (ECRH) in the Tore Supra tokamak constitutes an important step in the research aimed at obtaining thermonuclear fusion reactions. Electron heating is achieved by transmitting an electromagnetic wave from the oscillators (gyrotrons) to the plasma via the fundamental mode, propagating in oversized corrugated waveguides. Maximizing the proportion of the gyrotron power coupled to the fundamental waveguide mode is essential for the good functioning of the transmission line and for maximizing the effect on the plasma. This thesis gives all necessary tools for finding the proportion of the fundamental mode and all other modes present in passive components and at the output of the gyrotron as installed in the Tore Supra ECRH plant. This characterisation is based on obtaining amplitude and phase diagrams of the electric field on a plane transverse to the propagation axis. The most difficult part of obtaining these diagrams is measuring the phase which, despite the very short wavelength, is measured directly at low power levels. At high power levels the phase is numerically reconstructed from amplitude measurements for gyrotron characterisation. A complete theoretical study of the phase reconstruction code is given including its validation with theoretical diagrams. This study allows the realisation of a modal characterisation unit electromagnetic for measurement of radiated beams and usable in each part of the ECRH installation. At the end, the complete modal characterisation is given at low level for a mode converter and also at high level for the first series gyrotron installed at TORE SUPRA. (author)

  5. Developing the smallest possible medical cyclotron

    CERN Multimedia

    Katarina Anthony

    2011-01-01

    Imagine a portable medical cyclotron operated in a conventional radioactive facility at a hospital. Imagine a nurse or technician switching it on and producing isotopes at the patient’s bedside. Sounds like science fiction? Think again.   CERN has teamed up with Spain’s national scientific research centre (CIEMAT) to develop an avant-garde cyclotron to be used for Positron Emission Tomography (PET). “We plan to make a cyclotron that doesn't need an insulated building or ‘vault’: a cyclotron small enough to fit inside a hospital lift,” explains Jose Manuel Perez, who is leading the CIEMAT/CERN collaboration. “It will be the smallest possible medical cyclotron for single patient dose production and will dramatically reduce costs for hospitals.” While PET technology has transformed imaging techniques, many of its medical benefits have remained confined to highly specialised hospitals. “Studies have foun...

  6. First results of electron cyclotron emission measurements at the GDT magnetic mirror

    CERN Document Server

    Shalashov, A G; Gospodchikov, E D; Lubyako, L V; Yakovlev, D V; Bagryansky, P A

    2016-01-01

    This paper summarizes the results of experiments on electron cyclotron emission (ECE) measurements at the fundamental harmonic recently performed at the axially symmetric magnetic mirror device GDT (Budker Institute, Novosibirsk). New ECE diagnostics is installed to facilitate the successful electron cyclotron resonance heating experiment and operates in the vicinity of the heating frequency of 54.5 GHz. Besides expected emission of thermal electrons, a clearly resolved non-thermal ECE is observed indicating the presence of suprathermal electrons driven by high-power microwave heating. The particulars of plasma emission are studied experimentally in a broad range of discharge scenarios.

  7. Biomedical research with cyclotron produced radionuclides. Progress report, October 1, 1977--September 30, 1978

    Energy Technology Data Exchange (ETDEWEB)

    Laughlin, J.S.; Benua, R.S.; Tilbury, R.S.; Bigler, R.E.

    1978-09-30

    Progress is reported on biomedical studies using cyclotron-produced /sup 18/F, /sup 15/O, /sup 11/C, /sup 13/N, /sup 52/Fe, /sup 38/K, /sup 206/Bi, /sup 73/Se, /sup 53/Co, and /sup 43/K. The following research projects are described: tumor detection and diagnosis; neurological studies; radiopharmaceutical development; /sup 38/K as an indicator of blood flow to the myocardium; dosimetry for internally deposited isotopes in animals and man; cyclotron development; positron tomographic imaging with the TOKIM System; and review of positron emission transaxial tomograph instruments. (HLW)

  8. Dynamics of r.f. production of Stellarator plasmas in the ion cyclotron range of frequency

    Energy Technology Data Exchange (ETDEWEB)

    Moiseenko, V.E. [Kharkov Inst. of Phys. and Tech. (Ukraine). Nat. Center; Lysoivan, A.I. [Kharkov Inst. of Phys. and Tech. (Ukraine). Nat. Center; Kasilov, S.V. [Kharkov Inst. of Phys. and Tech. (Ukraine). Nat. Center; Plyusnin, V.V. [Kharkov Inst. of Phys. and Tech. (Ukraine). Nat. Center

    1995-01-01

    The present study investigated numerically the process of r.f. production of plasma in the URAGAN-3M torsatron in the frequency range below the ion cyclotron frequency ({omega}<{omega}{sub ci}). The dynamics of r.f. plasma build-up at the stages of neutral gas burnout and plasma heating were studied using a zero-dimensional transport code, in which the plasma confinement law was determined by large helical device scaling. Two models for input r.f. power were used. In the first case, the r.f. power absorbed by the electrons was computed by a one-dimensional r.f. code solving Maxwell`s boundary problem equations. The mechanisms of electron heating through direct excitation of the slow wave (SW) by antennae as well as the conversion of fast wave (FW) into SW in the vicinity of Alfven resonance (scenario of Alfven heating) were taken into account in the computations. In the second case, an `ideal` model of r.f. power deposition onto the electrons as a linear function of plasma density was employed. A noticeable difference in plasma production dynamics computed for these two cases was found. Better agreement with experimental data obtained from the URAGAN-3M torsatron was found for the first case resulting from combination of the one-dimensional r.f. and zero-dimensional transport codes. ((orig.)).

  9. Advanced electron cyclotron heating and current drive experiments on the stellarator Wendelstein 7-X

    Directory of Open Access Journals (Sweden)

    Stange Torsten

    2017-01-01

    Full Text Available During the first operational phase (OP 1.1 of Wendelstein 7-X (W7-X electron cyclotron resonance heating (ECRH was the exclusive heating method and provided plasma start-up, wall conditioning, heating and current drive. Six gyrotrons were commissioned for OP1.1 and used in parallel for plasma operation with a power of up to 4.3 MW. During standard X2-heating the spatially localized power deposition with high power density allowed controlling the radial profiles of the electron temperature and the rotational transform. Even though W7-X was not fully equipped with first wall tiles and operated with a graphite limiter instead of a divertor, electron densities of n e > 3·1019 m-3 could be achieved at electron temperatures of several keV and ion temperatures above 2 keV. These plasma parameters allowed the first demonstration of a multipath O2-heating scenario, which is envisaged for safe operation near the X-cutoff-density of 1.2·1020 m-3 after full commissioning of the ECRH system in the next operation phase OP1.2.

  10. Advanced electron cyclotron heating and current drive experiments on the stellarator Wendelstein 7-X

    Science.gov (United States)

    Stange, Torsten; Laqua, Heinrich Peter; Beurskens, Marc; Bosch, Hans-Stephan; Bozhenkov, Sergey; Brakel, Rudolf; Braune, Harald; Brunner, Kai Jakob; Cappa, Alvaro; Dinklage, Andreas; Erckmann, Volker; Fuchert, Golo; Gantenbein, Gerd; Gellert, Florian; Grulke, Olaf; Hartmann, Dirk; Hirsch, Matthias; Höfel, Udo; Kasparek, Walter; Knauer, Jens; Langenberg, Andreas; Marsen, Stefan; Marushchenko, Nikolai; Moseev, Dmitry; Pablant, Novomir; Pasch, Ekkehard; Rahbarnia, Kian; Mora, Humberto Trimino; Tsujimura, Toru; Turkin, Yuriy; Wauters, Tom; Wolf, Robert

    2017-10-01

    During the first operational phase (OP 1.1) of Wendelstein 7-X (W7-X) electron cyclotron resonance heating (ECRH) was the exclusive heating method and provided plasma start-up, wall conditioning, heating and current drive. Six gyrotrons were commissioned for OP1.1 and used in parallel for plasma operation with a power of up to 4.3 MW. During standard X2-heating the spatially localized power deposition with high power density allowed controlling the radial profiles of the electron temperature and the rotational transform. Even though W7-X was not fully equipped with first wall tiles and operated with a graphite limiter instead of a divertor, electron densities of n e > 3·1019 m-3 could be achieved at electron temperatures of several keV and ion temperatures above 2 keV. These plasma parameters allowed the first demonstration of a multipath O2-heating scenario, which is envisaged for safe operation near the X-cutoff-density of 1.2·1020 m-3 after full commissioning of the ECRH system in the next operation phase OP1.2.

  11. A Kinetic Model of Solar Wind Generation by Oblique Ion-cyclotron Waves

    Science.gov (United States)

    Isenberg, Philip A.; Vasquez, Bernard J.

    2011-04-01

    The fast solar wind is generated by extended perpendicular ion heating in coronal holes, but the kinetic mechanism responsible for this heating has not been determined. One long-standing possibility is the resonant-cyclotron dissipation of ion-cyclotron waves, replenished from a turbulent cascade of interacting counter-propagating Alfvén waves. We present results of a kinetic model for proton heating by the quasilinear resonant-cyclotron wave-particle interaction in a coronal hole. The resonant wave spectrum is taken as a power law in wavenumber, uniformly distributed in propagation direction between 0° and 60° with respect to the large-scale radial magnetic field. We obtain the steady-state solution of the kinetic guiding-center equation for the proton distribution in an expanding coronal hole, including the effects of large-scale forces of gravity, charge-separation electric field, Alfvén wave ponderomotive force, and mirror force, along with the small-scale scattering from the wave dissipation. We find that plausible wave intensities can yield reasonable flow speeds and temperatures in the heliocentric radial range between 2 and 6 solar radii. We address the claim in earlier work that dissipation of parallel-propagating ion-cyclotron waves cannot provide enough acceleration and show that claim to be incorrect. We find that the combined action of the large-scale forces and the resonant-cyclotron scattering produces proton distribution functions with a characteristic structure: compressed in the sunward half of velocity space with a high-density shell separate from the origin, and relatively expanded in the anti-sunward half of velocity space. We suggest that qualitatively similar proton distributions would result from the kinetic evolution of any sufficiently effective perpendicular heating mechanism operating in an expanding coronal hole.

  12. Cyclotrons: From Science to Human Health

    Science.gov (United States)

    Craddock, Michael

    2011-04-01

    Lawrence's invention of the cyclotron, whose 80th anniversary we have just celebrated, not only revolutionized nuclear physics, but proved the starting point for a whole variety of recirculating accelerators, from the smallest microtron to the largest synchrotron, that have had an enormous impact in almost every branch of science and in several areas of medicine and industry. Cyclotrons themselves have proved remarkably adaptable, incorporating a variety of new ideas and technologies over the years: frequency modulation, edge focusing, AG focusing, separate magnet sectors, axial and azimuthal injection, ring geometries, stripping extraction, superconducting magnets and rf...... Even FFAGs, those most complex members of the cyclotron (fixed-magnetic-field) family, are making a comeback. Currently there are more than 50 medium or large cyclotrons around the world devoted to research. These provide intense primary beams of protons or stable ions, and correspondingly intense secondary beams of neutrons, pions, muons and radioactive ions, for experiments in nuclear, particle and condensed-matter physics, and in the materials and life sciences. Far outnumbering these, however, are the 800 or so small and medium cyclotrons used to produce radioisotopes for medical and other purposes. In addition, a rapidly growing number of 230-MeV proton cyclotrons are being built for cancer therapy -12 brought into operation since 1998 and as many more in the works. Altogether, cyclotrons are flourishing!

  13. The nanostructure and microstructure of SiC surface layers deposited by MWCVD and ECRCVD

    Science.gov (United States)

    Dul, K.; Jonas, S.; Handke, B.

    2017-12-01

    Scanning electron microscopy (SEM) and Atomic force microscopy (AFM) have been used to investigate ex-situ the surface topography of SiC layers deposited on Si(100) by Microwave Chemical Vapour Deposition (MWCVD) -S1,S2 layers and Electron Cyclotron Resonance Chemical Vapor Deposition (ECRCVD) - layers S3,S4, using silane, methane, and hydrogen. The effects of sample temperature and gas flow on the nanostructure and microstructure have been investigated. The nanostructure was described by three-dimensional surface roughness analysis based on digital image processing, which gives a tool to quantify different aspects of surface features. A total of 13 different numerical parameters used to describe the surface topography were used. The scanning electron image (SEM) of the microstructure of layers S1, S2, and S4 was similar, however, layer S3 was completely different; appearing like grains. Nonetheless, it can be seen that no grain boundary structure is present in the AFM images.

  14. Low Temperature Metal Free Growth of Graphene on Insulating Substrates by Plasma Assisted Chemical Vapor Deposition.

    Science.gov (United States)

    Muñoz, R; Munuera, C; Martínez, J I; Azpeitia, J; Gómez-Aleixandre, C; García-Hernández, M

    2017-03-01

    Direct growth of graphene films on dielectric substrates (quartz and silica) is reported, by means of remote electron cyclotron resonance plasma assisted chemical vapor deposition r-(ECR-CVD) at low temperature (650°C). Using a two step deposition process- nucleation and growth- by changing the partial pressure of the gas precursors at constant temperature, mostly monolayer continuous films, with grain sizes up to 500 nm are grown, exhibiting transmittance larger than 92% and sheet resistance as low as 900 Ω·sq-1. The grain size and nucleation density of the resulting graphene sheets can be controlled varying the deposition time and pressure. In additon, first-principles DFT-based calculations have been carried out in order to rationalize the oxygen reduction in the quartz surface experimentally observed. This method is easily scalable and avoids damaging and expensive transfer steps of graphene films, improving compatibility with current fabrication technologies.

  15. Experimental observations of mode-converted ion cyclotron waves in a tokamak plasma by phase contrast imaging.

    Science.gov (United States)

    Nelson-Melby, E; Porkolab, M; Bonoli, P T; Lin, Y; Mazurenko, A; Wukitch, S J

    2003-04-18

    The process of mode conversion, whereby an externally launched electromagnetic wave converts into a shorter wavelength mode(s) in a thermal plasma near a resonance in the index of refraction, is particularly important in a multi-ion species plasma near the ion cyclotron frequency. Using phase contrast imaging techniques (PCI), mode-converted electromagnetic ion cyclotron waves have been detected for the first time in the Alcator C-Mod tokamak near the H-3He ion-ion hybrid resonance region during high power rf heating experiments. The results agree with theoretical predictions.

  16. On the origin of cyclotron lines in the spectra of X-ray pulsars

    Directory of Open Access Journals (Sweden)

    Mushtukov A. A.

    2014-01-01

    Full Text Available Cyclotron resonance scattering features are observed in the spectra of some X-ray pulsars and show significant changes in the line energy with the pulsar luminosity. In a case of bright sources, the line centroid energy is anti-correlated with the luminosity. Such a behaviour is often associated with the onset and growth of the accretion column, which is believed to be the origin of the observed emission and the cyclotron lines. However, this scenario inevitably implies large gradient of the magnetic field strength within the line-forming region, and it makes the formation of the observed line-like features problematic. Moreover, the observed variation of the cyclotron line energy is much smaller than could be anticipated for the corresponding luminosity changes. We argue that a more physically realistic situation is that the cyclotron line forms when the radiation emitted by the accretion column is reflected from the neutron star surface. The idea is based on the facts that a substantial part of column luminosity is intercepted by the neutron star surface and the reflected radiation should contain absorption features. The reflection model is developed and applied to explain the observed variations of the cyclotron line energy in a bright X-ray pulsar V 0332+53 over a wide range of luminosities.

  17. Theoretical and experimental study of cyclotronic waves in a fusion plasma; Etude theorique et experimentale des ondes cyclotroniques electroniques dans un plasma de fusion

    Energy Technology Data Exchange (ETDEWEB)

    Vezard, D.

    1994-12-20

    This thesis presents a study concerning cyclotronic waves in a plasma. It starts with an illustration of the elementary interaction between electromagnetic waves and matter.It shows that electrons from tokamak absorbs waves at cyclotronic frequency. Cyclotronic waves are studied by solving the dispersion relation in plasma; it concerns polarisation, absorption, dispersion, extinction. Then, classical theories are reminded in order to speak about decoupled electrons and their interactions. Absorption and emission properties of cyclotronic waves by electrons from a queue are described. After that, cyclotronic waves propagation is studied taking into account resonance. The last part of this thesis is dedicated to the electronic distribution function that is made by a wave spectra at a inferior hybrid frequency. (TEC). 129 refs., 75 figs.

  18. Method and apparatuses for ion cyclotron spectrometry

    Science.gov (United States)

    Dahl, David A [Idaho Falls, ID; Scott, Jill R [Idaho Falls, ID; McJunkin, Timothy R [Idaho Falls, ID

    2012-03-06

    An ion cyclotron spectrometer may include a vacuum chamber that extends at least along a z-axis and means for producing a magnetic field within the vacuum chamber so that a magnetic field vector is generally parallel to the z-axis. The ion cyclotron spectrometer may also include means for producing a trapping electric field within the vacuum chamber. The trapping electric field may comprise a field potential that, when taken in cross-section along the z-axis, includes at least one section that is concave down and at least one section that is concave up so that ions traversing the field potential experience a net magnetron effect on a cyclotron frequency of the ions that is substantially equal to zero. Other apparatuses and a method for performing ion cyclotron spectrometry are also disclosed herein.

  19. 10 GHz ECRIS for Warsaw Cyclotron

    CERN Document Server

    Sudlitz, K

    1999-01-01

    Cusp type, 10 GHz ECRIS has been built and tested earlier. For obtaining intensive beams, more relevant for cyclotron, cusp geometry has been replaced by hexapole. Discharge chamber (stainless steel, 50 mm diameter, 250 mm long) is an extension of a coaxial line, feeding RF (9,6 GHz, up to 200 W) to the plasma. The NdFeB hexapole (0,52 T on the surface) has been used. The axial magnetic field is created by water cooled coils. The axial injection line dedicated to K160 isochronous heavy ion cyclotron has been constructed. The line consists of Glaser lenses, double focusing magnet, solenoid and mirror type inflector. The system provides sufficient transmission of the beam from ECR ion source to the firsts orbits of the cyclotron for m/q ranging from 7 to 2. After successful initial tests which were done in July 1997 the ECRIS serves as an external source for Warsaw Cyclotron.

  20. Cyclotron axial ion-beam-buncher system

    Energy Technology Data Exchange (ETDEWEB)

    Hamm, R.W.; Swenson, D.A.; Wangler, T.P.

    1982-02-11

    Adiabatic ion bunching is achieved in a cyclotron axial ion injection system through the incorporation of a radio frequency quadrupole system, which receives ions from an external ion source via an accelerate-decelerate system and a focusing einzel lens system, and which adiabatically bunches and then injects the ions into the median plane of a cyclotron via an electrostatic quadrupole system and an inflection mirror.

  1. Building 211 cyclotron characterization survey report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-30

    The Building 211 Cyclotron Characterization Survey includes an assessment of the radioactive and chemical inventory of materials stored within the facility; an evaluation of the relative distribution of accelerator-produced activation products within various cyclotron components and adjacent structures; measurement of the radiation fields throughout the facility; measurement and assessment of internal and external radioactive surface contamination on various equipment, facility structures, and air-handling systems; and an assessment of lead (Pb) paint and asbestos hazards within the facility.

  2. New approach in design of efficient low level RF circuit for 10 MeV cyclotron

    Directory of Open Access Journals (Sweden)

    M S Sharifi Asadi Malafeh

    2015-09-01

    Full Text Available The electric field in cavity accelerates charged particles and magnetic field of magnets changes the direction of these particles in cyclotrons. In order to establish the electric field inside the cavity, a noiseless radio frequency (RF signal should be generated, amplified and sent to cavity. The resonant frequency of the cavity could be changed by temperature variation. Variation of resonant frequency will cause reflected power from the cavity. in this work the low level RF circuits with task of signal generation, phase and frequency Adjustment, cavity resonant frequency Adjustment, protection of the RF set from the reflected power and stability of RF system was designed

  3. Effective novel dissociation methods for intact protein: heat-assisted nozzle-skimmer collisionally induced dissociation and infrared multiphoton dissociation using a Fourier transform ion cyclotron resonance mass spectrometer equipped with a micrometal electrospray ionization emitter.

    Science.gov (United States)

    Yamada, Naoyuki; Suzuki, Ei-Ichiro; Hirayama, Kazuo

    2006-01-01

    Heating of a nano-electrospray ionization (nanoESI) source can improve the dissociation efficiency of collisionally induced dissociation (CID) methods, such as nozzle-skimmer CID (NS-CID) and infrared multiphoton dissociation (IRMPD), for large biomolecule fragmentation. A metal nanoESI emitter was used due to its resistance to heating above 250 degrees C. This novel method for the dissociation of large biomolecular ions is termed "heat-assisted NS-CID" (HANS-CID) or "heat-assisted IRMPD" (HA-IRMPD). Multiple charged nonreduced protein ions (8.6 Da ubiquitin, 14 kDa lysozyme, and 67 kDa bovine serum albumin) were directly dissociated by HANS-CID and HA-IRMPD to effectively yield fragment ions that could be assigned. The fragment ions of ubiquitin by HANS-CID can be analyzed by tandem mass spectrometry (MS/MS) using sustained off-resonance irradiation CID (SORI-CID) and IRMPD. In addition, a native large protein, immunoglobulin G (IgG, 150 kDa), was efficiently dissociated by HA-IRMPD. The product ions that were obtained reflected the domain structure of IgG. However, these product ions of IgG and lysozyme were not dissociated by MS/MS using the same heating energetic methods such as IRMPD and SORI-CID.

  4. The high-order cyclotron modes in Fermi liquid of Q2D layered conductors

    Directory of Open Access Journals (Sweden)

    O.V.Kirichenko

    2005-01-01

    Full Text Available The propagation of electromagnetic waves in layered conductors at the presence of an external magnetic field is investigated theoretically. At certain orientations of a magnetic field concerning the layers of the conductor the collisionless absorption is absent and weakly damping collective modes can propagate even under the strong spatial dispersion. In a short-wave limit the existence of electromagnetic waves with frequencies near the cyclotron resonances is possible at an arbitrary orientation of the wave vector with respect to an external magnetic field. We have obtained the spectrum of waves with the frequencies near the cyclotron resonances of high order with regard to the Fermi-liquid interaction of the electrons.

  5. Metal impurity transport control in JET H-mode plasmas with central ion cyclotron radiofrequency power injection

    DEFF Research Database (Denmark)

    Valisa, M.; Carraro, L.; Predebon, I.

    2011-01-01

    The scan of ion cyclotron resonant heating (ICRH) power has been used to systematically study the pump out effect of central electron heating on impurities such as Ni and Mo in H-mode low collisionality discharges in JET. The transport parameters of Ni and Mo have been measured by introducing a t...

  6. Main-ion temperature and plasma rotation measurements based on scattering of electron cyclotron heating waves in ASDEX Upgrade

    DEFF Research Database (Denmark)

    Pedersen, Morten Stejner; Rasmussen, Jesper; Nielsen, Stefan Kragh

    2017-01-01

    We demonstrate measurements of spectra of O-mode electron cyclotron resonance heating (ECRH) waves scattered collectively from microscopic plasma fluctuations in ASDEX Upgrade discharges with an ITER-like ECRH scenario. The measured spectra are shown to allow determination of the main ion...

  7. Parametric decay instability of an obliquely propagating ordinary wave in the electron cyclotron frequency range

    Science.gov (United States)

    Gusakov, E. Z.; Popov, A. Yu.

    2018-01-01

    The possibility of the low-power-threshold parametric decay of an obliquely propagating ordinary wave to an upper hybrid wave and a low-hybrid wave is analysed under conditions of nonmonotonic plasma density profile in a magnetic trap. The instability threshold and growth rate are derived explicitly. The analytical results are illustrated under the conditions typical of the ordinary mode fundamental electron cyclotron resonance heating harmonic experiments at the FTU tokamak.

  8. A real-time intercepting beam-profile monitor for a medical cyclotron

    Science.gov (United States)

    Hendriks, C.; Uittenbosch, T.; Cameron, D.; Kellogg, S.; Gray, D.; Buckley, K.; Schaffer, P.; Verzilov, V.; Hoehr, C.

    2013-11-01

    There is a lack of real-time continuous beam-diagnostic tools for medical cyclotrons due to high power deposition during proton irradiation. To overcome this limitation, we have developed a profile monitor that is capable of providing continuous feedback about beam shape and current in real time while it is inserted in the beam path. This enables users to optimize the beam profile and observe fluctuations in the beam over time with periodic insertion of the monitor.

  9. A real-time intercepting beam-profile monitor for a medical cyclotron.

    Science.gov (United States)

    Hendriks, C; Uittenbosch, T; Cameron, D; Kellogg, S; Gray, D; Buckley, K; Schaffer, P; Verzilov, V; Hoehr, C

    2013-11-01

    There is a lack of real-time continuous beam-diagnostic tools for medical cyclotrons due to high power deposition during proton irradiation. To overcome this limitation, we have developed a profile monitor that is capable of providing continuous feedback about beam shape and current in real time while it is inserted in the beam path. This enables users to optimize the beam profile and observe fluctuations in the beam over time with periodic insertion of the monitor.

  10. One-electron quantum cyclotron (and implications for cold antihydrogen)

    CERN Document Server

    Gabrielse, G; Odom, B; D'Urso, B

    2001-01-01

    Quantum jumps between Fock states of a one-electron oscillator reveal the quantum limit of a cyclotron accelerator. The states live for seconds when spontaneous emission is inhibited by a factor of 140 within a cylindrical Penning trap cavity. Averaged over hours the oscillator is in thermal equilibrium with black-body photons in the cavity. At 80 mK, quantum jumps occur only when resonant microwave photons are introduced into the cavity, opening a route to improved measurements of the magnetic moments of the electron and positron. The temperature demonstrated is about 60 times lower than the 4.2 K temperature at which charged elementary particles were previously stored. Implications for the production of cold antihydrogen are discussed. (21 refs).

  11. Mechanism for electron cyclotron heating of collisionless plasma

    Energy Technology Data Exchange (ETDEWEB)

    Golovanivskii, K.S.; Dugard-Jabon, V.D.; Milant' ev, V.P.

    1975-01-01

    The electron distribution with respect to transverse energy is derived for electron cyclotron resonance in a constant, homogeneous magnetic field; weak relativistic effects are taken into account. After the establishment of a steady-state distribution with groups of hot and cold electrons, no energy is pumped from the rf field to the plasma. The rf electrostatic perturbations are studied on the basis of the distribution function found; it is shown that waves of two types are unstable eigenmodes of the plasma at rest and drift waves. The growth rates for the corresponding instabilities are derived. A study is also made of the stability of right-handed circularly polarized electromagnetic wave propagating along the magnetic field. Instabilities occur at frequencies which depend on the degree of anisotropy, analogous to the case of a plasma with a temperature anisotropy.

  12. ROKCY-12 (KCCH PET-dedicated cyclotron): main features and improvements

    Energy Technology Data Exchange (ETDEWEB)

    Chai, J. S.; Kim, Y. S.; Yang, Y. T.; Jung, I. S.; Hong, S. S.; Lee, M. Y.; Jang, H. S.; Kim, J. H. [Korea Cancer Center Hospital, Seoul (Korea, Republic of)

    2002-07-01

    In this paper, we describe the development of 13 MeV cyclotron (ROKCY-12) that can be used for a Position Emission Tomography(PET) purpose. This cyclotron with a maximum beam energy of 13 MeV can produce radio isotopes especially {sup 18}F which has a relatively short half lifetime of 110 minutes. First, we show the beam characteristics can be used to carry out the operation of ROCKY-12. Based on this, a computer program has been developed to determine main cyclotron parameters such as cyclotron magnet, RF system, ion source, vacuum system and other cyclotron operation parameters. And then we show the result of design and manufacturing feature of ROKCY-12. By using this design program, one can determines magnet yoke geometry and the average magnetic fields etc. And then the three-dimensional computer program OPERA-3D has been invoked to determine magnet pole tips. Validity of the design can be seen by investigating magnetic fields, radial and vertical focusing frequencies as a function of the beam energy. In this paper, we show the results of cyclotron beam by ROCKY-12. We designed 77.3 MHz RF system and ion source system. We tested RF resonance each coupling methods. We show the result of RF design and prototype operation. Developed ion source is PIG type. We described our design methods and implementation. We report the result of getting negative hydrogen ion. Cyclotron controller asks inputs of every sensor and output of every instrument for notifying current condition to operator. It has independent controllers, for example DC power supply, vacuum system, beam profile system, beam extraction system, RF system, ion source, cooling unit and so on. Basically, each control system uses RS-485 for communication to main control computer. Consumers reward products and services that feature quality, originality, a distinct personality and charm. The International Standardization Organization (ISO) requires, as its mission, that we achieve competitive superiority by

  13. Electron spin resonance and radiocarbon dating of coral deposited by Holocene tsunami events on Curaçao, Bonaire and Aruba (Netherlands Antilles)

    Science.gov (United States)

    Radtke, Ulrich; Schellmann, Gerhard; Scheffers, Anja; Kelletat, Dieter; Kromer, Bernd; Uwe Kasper, Haino

    2003-05-01

    Electron spin resonance (ESR) dating of coral has become an efficient geochronological tool for studying the last 500,000 years. This study presents results of ESR dating of Holocene coral from Curaçao, Bonaire and Aruba, Leeward Netherlands Antilles. The coral accumulated in rubble ridges and ramparts onshore and the depositional process is attributed to a series of tsunami events. In addition to the calculation of equivalent dose ( DE) values, it is crucial for ESR dating to obtain the correct D0 value for each sample. The annual dose rate ( D0) estimation of the samples in this study is uncertain as the timing of the tsunami event and the residence time of a component of the dated sediment in different environments (marine versus terrestrial) is difficult to quantify. Assuming that the tsunami event deposited coral shortly after death, the ESR and 14C ages of 22 samples reaching from 3650 to 128 years correspond well with each other. This confirms the idea that the living coral reef was partly destroyed by tsunami events. The ESR dating uncertainties coincide with the variability of 14C ages caused by the marine reservoir effect. The local marine reservoir effect was estimated using four recent samples from 1920 and provided values between 375 and 595 yr BP.

  14. Residual radioactivity at the Milan AVF cyclotron

    Science.gov (United States)

    Birattari, C.; Cantone, M. C.; Ferrari, A.; Silari, M.

    1989-08-01

    γ-ray spectrometry measurements have been carried out at the Cyclotron Laboratory at the Department of Physics of the University of Milan, to evaluate the levels of residual radioactivity after about one year from shut down. Measurements were performed inside the cyclotron and at several points in the accelerator vault and target room, as well as on specific components removed from the beam transport system, on samples of the concrete shields and on residues taken from the cyclotron vacuum chamber. The radionuclides identified and the values of specific activity and dose rate are reported. The results indicate that no particular hazard and waste disposal problems should be encountered at the time of the decommissioning of the facility.

  15. Improving cancer treatment with cyclotron produced radionuclides

    Energy Technology Data Exchange (ETDEWEB)

    Larson, S.M. Finn, R.D.

    1992-08-04

    This report describes the author's continuing long term goal of promoting nuclear medicine applications by improving the scientific basis for tumor diagnosis treatment and treatment follow-up based on the use of cyclotron produced radiotracers in oncology. The program has 3 interactive components: Radiochemistry /Cyclotron; Pharmacology; and Immunology. An essential strategy is as follows: novel radionuclides and radiotracers developed in the Radiochemistry/Cyclotron section under the DOE grant during the 1989--1992 grant period, will be employed in the Pharmacology and Immunology sections of the DOE grant during the 1992--1995 grant period. The development of novel radionuclides and tracers is of course useful in and of itself, but their utility is greatly enhanced by the interaction with the immunology and pharmacology components of the program.

  16. Ion cyclotron range of frequencies heating of plasma with small impurity production

    Science.gov (United States)

    Ohkawa, Tihiro

    1987-01-01

    Plasma including plasma ions is magnetically confined by a magnetic field. The plasma has a defined outer surface and is intersected by resonance surfaces of respective common ion cyclotron frequency of a predetermined species of plasma ions moving in the magnetic field. A radio frequency source provides radio frequency power at a radio frequency corresponding to the ion cyclotron frequency of the predetermined species of plasma ions moving in the field at a respective said resonance surface. RF launchers coupled to the radio frequency source radiate radio frequency energy at the resonance frequency onto the respective resonance surface within the plasma from a plurality of locations located outside the plasma at such respective distances from the intersections of the respective resonance surface and the defined outer surface and at such relative phases that the resulting interference pattern provides substantially null net radio frequency energy over regions near and including substantial portions of the intersections relative to the radio frequency energy provided thereby at other portions of the respective resonance surface within the plasma.

  17. Dispersion equations for field-aligned cyclotron waves in axisymmetric magnetospheric plasmas

    Directory of Open Access Journals (Sweden)

    N. I. Grishanov

    2006-03-01

    Full Text Available In this paper, we derive the dispersion equations for field-aligned cyclotron waves in two-dimensional (2-D magnetospheric plasmas with anisotropic temperature. Two magnetic field configurations are considered with dipole and circular magnetic field lines. The main contribution of the trapped particles to the transverse dielectric permittivity is estimated by solving the linearized Vlasov equation for their perturbed distribution functions, accounting for the cyclotron and bounce resonances, neglecting the drift effects, and assuming the weak connection of the left-hand and right-hand polarized waves. Both the bi-Maxwellian and bi-Lorentzian distribution functions are considered to model the ring current ions and electrons in the dipole magnetosphere. A numerical code has been developed to analyze the dispersion characteristics of electromagnetic ion-cyclotron waves in an electron-proton magnetospheric plasma with circular magnetic field lines, assuming that the steady-state distribution function of the energetic protons is bi-Maxwellian. As in the uniform magnetic field case, the growth rate of the proton-cyclotron instability (PCI in the 2-D magnetospheric plasmas is defined by the contribution of the energetic ions/protons to the imaginary part of the transverse permittivity elements. We demonstrate that the PCI growth rate in the 2-D axisymmetric plasmasphere can be significantly smaller than that for the straight magnetic field case with the same macroscopic bulk parameters.

  18. Photocurrent enhancement by surface plasmon resonance of gold nanoparticles in spray deposited large area dye sensitized solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Chander, Nikhil; Singh, Puneet [Photovoltaic Laboratory, Centre for Energy Studies, Indian Institute of Technology Delhi, New Delhi 110016 (India); Khan, A.F. [Department of Electronics and Information Technology, Ministry of Communications and Information Technology, Government of India, New Delhi 110003 (India); Dutta, Viresh [Photovoltaic Laboratory, Centre for Energy Studies, Indian Institute of Technology Delhi, New Delhi 110016 (India); Komarala, Vamsi K., E-mail: vamsi@ces.iitd.ac.in [Photovoltaic Laboratory, Centre for Energy Studies, Indian Institute of Technology Delhi, New Delhi 110016 (India)

    2014-10-01

    A facile method for fabricating large area TiO{sub 2} and TiO{sub 2}–Au nanocomposite films for dye sensitized solar cells (DSSCs) is presented using a spray technique. Pre-synthesized gold nanoparticles (Au NPs) were sprayed together with the TiO{sub 2} NPs and composite films with brilliant coloration due to surface plasmon resonances of Au NPs were prepared. Composite films containing ∼ 15 nm sized Au NPs exhibited enhanced absorption in the visible region of the electromagnetic spectrum. DSSCs with a large area of ∼ 4.5 cm{sup 2} were fabricated and a photocurrent enhancement of ∼ 10% was obtained for plasmonic DSSC containing 0.3 wt.% of ∼ 15 nm Au NPs. Incident photon to current conversion efficiency data conclusively showed enhanced currents in the visible region of the polychromatic spectrum arising due to plasmon enhanced near-field effects of Au NPs around the absorbing dye molecules. - Highlights: • Preparation of TiO{sub 2} and TiO{sub 2}–Au films with a large area of ∼ 7.5 cm{sup 2} by a spray technique • An efficiency of ∼ 4.5% achieved by the large area plasmonic DSSC • Photocurrent enhancement due to SPR effects of gold NPs observed • Comparison of the spray and conventional doctor blade methods in DSSC performance • Demonstration of technological feasibility and versatility of a simple spray process.

  19. Photonic crystal fiber-based surface plasmon resonance sensor with selective analyte channels and graphene-silver deposited core.

    Science.gov (United States)

    Rifat, Ahmmed A; Mahdiraji, G Amouzad; Chow, Desmond M; Shee, Yu Gang; Ahmed, Rajib; Adikan, Faisal Rafiq Mahamd

    2015-05-19

    We propose a surface plasmon resonance (SPR) sensor based on photonic crystal fiber (PCF) with selectively filled analyte channels. Silver is used as the plasmonic material to accurately detect the analytes and is coated with a thin graphene layer to prevent oxidation. The liquid-filled cores are placed near to the metallic channel for easy excitation of free electrons to produce surface plasmon waves (SPWs). Surface plasmons along the metal surface are excited with a leaky Gaussian-like core guided mode. Numerical investigations of the fiber's properties and sensing performance are performed using the finite element method (FEM). The proposed sensor shows maximum amplitude sensitivity of 418 Refractive Index Units (RIU-1) with resolution as high as 2.4 × 10(-5) RIU. Using the wavelength interrogation method, a maximum refractive index (RI) sensitivity of 3000 nm/RIU in the sensing range of 1.46-1.49 is achieved. The proposed sensor is suitable for detecting various high RI chemicals, biochemical and organic chemical analytes. Additionally, the effects of fiber structural parameters on the properties of plasmonic excitation are investigated and optimized for sensing performance as well as reducing the sensor's footprint.

  20. Photonic Crystal Fiber-Based Surface Plasmon Resonance Sensor with Selective Analyte Channels and Graphene-Silver Deposited Core

    Directory of Open Access Journals (Sweden)

    Ahmmed A. Rifat

    2015-05-01

    Full Text Available We propose a surface plasmon resonance (SPR sensor based on photonic crystal fiber (PCF with selectively filled analyte channels. Silver is used as the plasmonic material to accurately detect the analytes and is coated with a thin graphene layer to prevent oxidation. The liquid-filled cores are placed near to the metallic channel for easy excitation of free electrons to produce surface plasmon waves (SPWs. Surface plasmons along the metal surface are excited with a leaky Gaussian-like core guided mode. Numerical investigations of the fiber’s properties and sensing performance are performed using the finite element method (FEM. The proposed sensor shows maximum amplitude sensitivity of 418 Refractive Index Units (RIU−1 with resolution as high as 2.4 × 10−5 RIU. Using the wavelength interrogation method, a maximum refractive index (RI sensitivity of 3000 nm/RIU in the sensing range of 1.46–1.49 is achieved. The proposed sensor is suitable for detecting various high RI chemicals, biochemical and organic chemical analytes. Additionally, the effects of fiber structural parameters on the properties of plasmonic excitation are investigated and optimized for sensing performance as well as reducing the sensor’s footprint.

  1. Ion cyclotron waves in the Earth’s magnetotail during CASSINI’s Earth swing-by

    Directory of Open Access Journals (Sweden)

    A. T. Bogdanov

    2003-10-01

    Full Text Available The properties of low frequency magnetotail waves observed during CASSINI’s Earth swing-by are examined. A maximum in the distribution of the waves about half the proton cyclotron frequency and a peak at linear polarisation are found and their implications are analysed in detail. Data on the fluid plasma velocity for the observation interval are not available and thus no unique conclusions about Doppler shift influence on the properties of the waves can be made. This determines the need to analyse different hypotheses in order to understand the origin of the waves. The plausibility of competing interpretations, such as off-resonance proton cyclotron waves and bi-ion cyclotron waves at the gyrofrequency of a heavy ion component of the magneto-tail plasma in the form of He ++ ions of solar wind origin is questioned.Key words. Space plasma physics (waves and instabilities – Magnetospheric physics (plasma waves and instabilities; magnetotail

  2. Electron cyclotron resonance heating in a short cylindrical plasma ...

    Indian Academy of Sciences (India)

    produced plasmas are still not well-investigated. To study these ECR-produced plasmas ... Section 4 contains the presentation and interpretation of the main experimental results. Section 5 contains the discussion and the final conclusion. 2.

  3. Characteristics of electron cyclotron resonance plasma formed by ...

    Indian Academy of Sciences (India)

    m3. When the ECR appears .... capacitor bank power supply assisted by ECR plasma, formed by LHCD system. The main parameters of the ..... voltage is gradually decreased from shot to shot, till the discharge ceases to form. We refer these ...

  4. Characteristics of electron cyclotron resonance plasma formed by ...

    Indian Academy of Sciences (India)

    2015-11-27

    Nov 27, 2015 ... The RF powe r, up to 10 kW (of which ∼ 50% is reflected back), with a typical pulse length of 50 ms, is injected into the vacuum chamber of the ADITYA tokamak by a LHCD grill antenna and is used for plasma formation. The average coupled RF power density (the RF power/a typical volume of the plasma) ...

  5. Characteristics of the KVI electron cyclotron resonance ion source

    NARCIS (Netherlands)

    Kremers, HR; Beijers, JPM; Brandenburg, S

    In this article, an update will be given of last year's activities to modify the CAPRICE-type ECR ion source into an AECR-type ECR ion source as developed in Berkely, Argonne and Jyvaskyla. Here we will present measurements on the radial and the axial magnetic field, the vacuum system, report on the

  6. Superconducting magnets for the RAON electron cyclotron resonance ion source.

    Science.gov (United States)

    Choi, S; Kim, Y; Hong, I S; Jeon, D

    2014-02-01

    The RAON linear accelerator of Rare Isotope Science Project has been developed since 2011, and the superconducting magnet for ECRIS was designed. The RAON ECR ion source was considered as a 3rd generation source. The fully superconducting magnet has been designed for operating using 28 GHz radio frequency. The RAON ECRIS operates in a minimum B field configuration which means that a magnetic sextupole field for radial confinement is superimposed with a magnetic mirror field for axial confinement. The highest field strength reaches 3.5 T on axis and 2 T at the plasma chamber wall for operating frequency up to 28 GHz. In this paper, the design results are presented of optimized superconducting magnet consisting of four solenoids and sextupole. The prototype magnet for ECRIS was fabricated and tested to verify the feasibility of the design. On the basis of test results, a fully superconducting magnet will be fabricated and tested.

  7. Experimental Study of an ion cyclon resonance accelerator presentation of his thesis

    CERN Document Server

    Ramsell, C T

    1999-01-01

    The Ion Cyclotron Resonance Accelerator (ICRA) uses the operating principles of cyclotrons and gyrotrons. The novel geometry of the ICRA allows an ion beam to drift axially while being accelerated in the azimuthal direction. Previous work on electron cyclotron resonance acceleration used waveguide modes to accelerate an electron beam [5]. This research extends cyclotron resonance acceleration to ions by using a high field superconducting magnet and an rf driven magnetron operating at a harmonic of the cyclotron frequency. The superconducting solenoid provides an axial magnetic field for radial confinement and an rf driven magnetron provides azimuthal electric fields for acceleration. The intent of the ICRA concept is to create an ion accelerator which is simple, compact, lightweight, and inexpensive. Furthermore, injection and extraction are inherently simple since the beam drifts through the acceleration region. However, use of this convenient geometry leads to an accelerated beam with a large energy spread....

  8. The Data Cyclotron query processing scheme

    NARCIS (Netherlands)

    Goncalves, R.; Kersten, M.

    2011-01-01

    A grand challenge of distributed query processing is to devise a self-organizing architecture which exploits all hardware resources optimally to manage the database hot set, minimize query response time, and maximize throughput without single point global coordination. The Data Cyclotron

  9. The Data Cyclotron query processing scheme.

    NARCIS (Netherlands)

    R.A. Goncalves (Romulo); M.L. Kersten (Martin)

    2011-01-01

    htmlabstractA grand challenge of distributed query processing is to devise a self-organizing architecture which exploits all hardware resources optimally to manage the database hot set, minimize query response time, and maximize throughput without single point global coordination. The Data Cyclotron

  10. <600> MeV synchro-cyclotron

    CERN Multimedia

    CERN PhotoLab

    1971-01-01

    One of the 14 pancakes of the new magnet coils for the 600 MeV synchro-cyclotron which were wound and coated with epoxy resin on the CERN site. These new coils will replace the present ones which have been in use for more than 14 years but are now showing signs of deteriorations.

  11. Development of the cyclotron radioisotope production technology

    Energy Technology Data Exchange (ETDEWEB)

    Suh, Yong Sup; Chun, K.S.; Yang, S.D.; Lee, J.D.; Ahn, S.H.; Yun, Y.K.; Park, H.; Lee, J.S.; Chai, J.S.; Kim, U.S.; Hong, S.S.; Lee, M.Y.; Park, C.W.; Baik, S. K.; Kim, E. H.; Kim, T. K.; Kim, K. S.; Kim, J. H

    1999-04-01

    The purpose of this study is to contribute the advance of nuclear medicine and to the improvement of human health through the development of various accelerator radionuclides and mass production with automization of production. The results obtained from this study are following: 1) In order to introduce 30 MeV high current cyclotron, the specification of cyclotron has been made, the building site was selected and we drew the draw-up of cyclotron. The cyclotron installation contract was postponed until the financial resources could be secured. 2) For a development high purity 1-123 producing system, a Xe-124 target system, a temperature measurement system of the inner part of the target and a target window were fabricated. A Xe-124 gas target recovery system and a full production system of 1-123 was drew up. 3) For a development of a therapeutic nuclide At-211, a target for the production of At-211 via {sup 209}Bi(alpha, 2n) reaction was fabricated. Produced At-211 was separated by distillation method. 4) For development of beta-emitting nuclides, Ti-45, C-11, F{sub 2}-18, beam irradiation system suitable for each target were fabricated. 5) For automatic production of Ga-67, automated module and PLC program was made 6) For the quality control of radiopharmaceuticals, analytical method of thallium and copper by polarography was investigated and established.

  12. Program Complex For Cyclotron Beam Dynamic Simulations

    CERN Document Server

    Glazov, A A; Karamysheva, G A; Lisenkova, O E

    2004-01-01

    The program complex in MATLAB intended for particle dynamic simulations is described. Programming in an easy-to-use environment permits creation of models in a short space of time. Advanced graphical tools of MATLAB give good visualization features to created models. The beam dynamic modelling results by the example of two different cyclotron designs are presented.

  13. SC Cyclotron and RIB Facilities in Kolkata

    CERN Document Server

    Sinha, Bikash; Chakrabarti, Alok

    2005-01-01

    The superconducting cyclotron under construction at this Centre has bending limit (K-bend) of 520 and focusing limit (K-foc) of 160. It is being constructed, primarily, for nuclear physics experiments with heavy ion beams at intermediate energies. The 100-ton main magnet is currently in the commissioning phase with the main coil already at 4.2K temperature. Magnetic field measurements will be carried out over the next several months. All other systems of the cyclotron are in an advanced stage of fabrication or development. We plan to start assembly of the complete cyclotron around the end of 2005. In the phase-I of the project one beam line has been provided. Construction of three more beam lines and various experimental facilities for nuclear physics as well as irradiation experiments has also been funded and the work is well on its way. An ISOL type Radioactive Ion Beam (RIB) facility is being built with the existing K=130 room temperature cyclotron, VEC, as the primary beam source. In-beam RIB production a...

  14. Cyclotron-based neutron source for BNCT

    Science.gov (United States)

    Mitsumoto, T.; Yajima, S.; Tsutsui, H.; Ogasawara, T.; Fujita, K.; Tanaka, H.; Sakurai, Y.; Maruhashi, A.

    2013-04-01

    Kyoto University Research Reactor Institute (KURRI) and Sumitomo Heavy Industries, Ltd. (SHI) have developed a cyclotron-based neutron source for Boron Neutron Capture Therapy (BNCT). It was installed at KURRI in Osaka prefecture. The neutron source consists of a proton cyclotron named HM-30, a beam transport system and an irradiation & treatment system. In the cyclotron, H- ions are accelerated and extracted as 30 MeV proton beams of 1 mA. The proton beams is transported to the neutron production target made by a beryllium plate. Emitted neutrons are moderated by lead, iron, aluminum and calcium fluoride. The aperture diameter of neutron collimator is in the range from 100 mm to 250 mm. The peak neutron flux in the water phantom is 1.8×109 neutrons/cm2/sec at 20 mm from the surface at 1 mA proton beam. The neutron source have been stably operated for 3 years with 30 kW proton beam. Various pre-clinical tests including animal tests have been done by using the cyclotron-based neutron source with 10B-p-Borono-phenylalanine. Clinical trials of malignant brain tumors will be started in this year.

  15. Cyclotron-based neutron source for BNCT

    Energy Technology Data Exchange (ETDEWEB)

    Mitsumoto, T.; Yajima, S.; Tsutsui, H.; Ogasawara, T.; Fujita, K. [Sumitomo Heavy Industries, Ltd (Japan); Tanaka, H.; Sakurai, Y.; Maruhashi, A. [Kyoto University Research Reactor Institute (Japan)

    2013-04-19

    Kyoto University Research Reactor Institute (KURRI) and Sumitomo Heavy Industries, Ltd. (SHI) have developed a cyclotron-based neutron source for Boron Neutron Capture Therapy (BNCT). It was installed at KURRI in Osaka prefecture. The neutron source consists of a proton cyclotron named HM-30, a beam transport system and an irradiation and treatment system. In the cyclotron, H- ions are accelerated and extracted as 30 MeV proton beams of 1 mA. The proton beams is transported to the neutron production target made by a beryllium plate. Emitted neutrons are moderated by lead, iron, aluminum and calcium fluoride. The aperture diameter of neutron collimator is in the range from 100 mm to 250 mm. The peak neutron flux in the water phantom is 1.8 Multiplication-Sign 109 neutrons/cm{sup 2}/sec at 20 mm from the surface at 1 mA proton beam. The neutron source have been stably operated for 3 years with 30 kW proton beam. Various pre-clinical tests including animal tests have been done by using the cyclotron-based neutron source with {sup 10}B-p-Borono-phenylalanine. Clinical trials of malignant brain tumors will be started in this year.

  16. EBCO Technologies TR Cyclotrons, Dynamics, Equipment, and Applications

    Science.gov (United States)

    Johnson, R. R.; Erdman, K. L.; Gyles, Wm.; Burbee, J.; VanLier, E.; Kovacs, M.; Perron, F.

    2003-08-01

    The Ebco Technologies TR cyclotrons have a common parent in the 500 MeV negative ion cyclotron at TRIUMF in Vancouver. As such, the TR cyclotrons have features that can be adapted for specific application. The cyclotron design is modularized into ion source and injection system, central region and then extraction. The cyclotron ion source is configured for cyclotron beam currents ranging from 50 microAmps to 2 milliAmps. The injection line can be operated in either continuous (CW) or in pulsed mode. The center region of the cyclotron is configured to match the ion source configuration. The extracted beams are directed either to a local target station or to beam lines and thence to target stations. There has been development both in solid, liquid and gas targets. There has been development in radioisotope handling techniques, target material recovery and radiochemical synthesis.

  17. Ion cyclotron and spin-flip emissions from fusion products in tokamaks

    Energy Technology Data Exchange (ETDEWEB)

    Arunasalam, V.; Greene, G.J.; Young, K.M.

    1993-02-01

    Power emission by fusion products of tokamak plasmas in their ion cyclotron range of frequencies (ICRF) and at their spin-flip resonance frequency is calculated for some specific model fusion product velocity-space distribution functions. The background plasma of say deuterium (D) is assumed to be in equilibrium with a Maxwellian distribution both for the electrons and ions. The fusion product velocity distributions analyzed here are: (1) A monoenergetic velocity space ring distribution. (2) A monoenergetic velocity space spherical shell distribution. (3) An anisotropic Maxwellian distribution with T {perpendicular} {ne} T{parallel}and with appreciable drift velocity along the confining magnetic field. Single ``dressed`` test particle spontaneous emission calculations are presented first and the radiation temperature for ion cyclotron emission (ICE) is analyzed both for black-body emission and nonequilibrium conditions. Thresholds for instability and overstability conditions are then examined and quasilinear and nonlinear theories of the electromagnetic ion cyclotron modes are discussed. Distinctions between ``kinetic or causal instabilities`` and ``hydrodynamic instabilities`` are drawn and some numerical estimates are presented for typical tokamak parameters. Semiquantitative remarks are offered on wave accessibility, mode conversion, and parametric decay instabilities as possible for spatially localized ICE. Calculations are carried out both for k{parallel} = 0 for k{parallel} {ne} 0. The effects of the temperature anisotropy and large drift velocities in the parallel direction are also examined. Finally, proton spin-flip resonance emission and absorption calculations are also presented both for thermal equilibrium conditions and for an ``inverted`` population of states.

  18. Differential deposition of manganese in the rat brain following subchronic exposure to manganese: a T1-weighted magnetic resonance imaging study.

    Science.gov (United States)

    Finkelstein, Yoram; Zhang, Na; Fitsanakis, Vanessa A; Avison, Malcolm J; Gore, John C; Aschner, Michael

    2008-11-01

    Manganism is a central nervous system disorder caused by toxic exposure to manganese. Manganism has been related to occupational exposures, liver diseases, prolonged parenteral nutrition, and abuse of illicit drugs. Initially manifested by a reversible neuropsychiatric syndrome (locura manganica), the main symptoms and signs of manganism are emotional lability, compulsive behavior and visual hallucinations. Locura manganica is followed by an irreversible extrapyramidal syndrome, the onset of which occurs years after chronic exposure. To characterize the regional distribution of Mn in the rat brain after subchronic exposure to Mn. This animal model holds special clinical relevance, reflecting the earlier clinical stages of manganism before chronic exposure to Mn exerts its irreversible effects. Sprague-Dawley rats were intravenously injected with MnCl2 weekly, for a total of 14 weeks - approximately 1/10 of the lifetime of the rat. T1-weighted magnetic resonance imaging was used to detect the distribution of Mn deposition in brain tissues, as evidenced by areas of T1-weighted hyperintense signals. A consistent region-specific pattern of T1-weighted hyperintensities was observed in the brains of Mn-treated rats. Cortical hyperintensities were prominent in the hippocampus and dentate gyrus. Hyperintensities were also observed in the olfactory bulbs, pituitary gland, optic nerves and chiasma, pons, midbrain tegmentum, habenula, lentiform and caudate nuclei, thalamus, chorioid plexus and cerebellar hemispheres. Prominent Mn depositions, evidenced by T1-weighted hyperintensities in the hippocampus after subacute exposure to Mn, are compatible with the clinical picture of manganism during its early stages, and may explain its pathophysiology.

  19. Experimental observation of acoustic emissions generated by a pulsed proton beam from a hospital-based clinical cyclotron.

    Science.gov (United States)

    Jones, Kevin C; Vander Stappen, François; Bawiec, Christopher R; Janssens, Guillaume; Lewin, Peter A; Prieels, Damien; Solberg, Timothy D; Sehgal, Chandra M; Avery, Stephen

    2015-12-01

    To measure the acoustic signal generated by a pulsed proton spill from a hospital-based clinical cyclotron. An electronic function generator modulated the IBA C230 isochronous cyclotron to create a pulsed proton beam. The acoustic emissions generated by the proton beam were measured in water using a hydrophone. The acoustic measurements were repeated with increasing proton current and increasing distance between detector and beam. The cyclotron generated proton spills with rise times of 18 μs and a maximum measured instantaneous proton current of 790 nA. Acoustic emissions generated by the proton energy deposition were measured to be on the order of mPa. The origin of the acoustic wave was identified as the proton beam based on the correlation between acoustic emission arrival time and distance between the hydrophone and proton beam. The acoustic frequency spectrum peaked at 10 kHz, and the acoustic pressure amplitude increased monotonically with increasing proton current. The authors report the first observation of acoustic emissions generated by a proton beam from a hospital-based clinical cyclotron. When modulated by an electronic function generator, the cyclotron is capable of creating proton spills with fast rise times (18 μs) and high instantaneous currents (790 nA). Measurements of the proton-generated acoustic emissions in a clinical setting may provide a method for in vivo proton range verification and patient monitoring.

  20. Understanding the bursty electron cyclotron emission during a sawtooth crash in the HT-7 tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Li, Erzhong, E-mail: rzhonglee@ipp.ac.cn; Hu, Liqun; Chen, Kaiyun [Institute of Plasma Physics, Chinese Academy of Science, Hefei 230031 (China)

    2014-01-15

    Bursts in electron cyclotron emission (ECE) were observed during sawtooth crashes in HT-7 in discharges with ion cyclotron resonance heating injected near the q = 1 rational surface (q is the safety factor). The local ECE measurement indicated that the bursty radiation is only observed on channels near but a little away outward from the q = 1 magnetic surface. In conjunction with the soft x-ray tomography analysis, it was determined that, for the first time, only a compression process survives in the later stage of fast magnetic reconnection but before prompt heat transport. The compression enhanced the electron radiation temperature, the increased amplitude of which agreed well with the estimation according to a kinetic compression theory model [R. J. Hastie and T. C. Hender, Nucl. Fusion 28, 585 (1988)]. This paper presents the experimental evidence that there indeed exists a transient compression phase which results in the bursty ECE radiation during a sawtooth crash.

  1. Understanding the bursty electron cyclotron emission during a sawtooth crash in the HT-7 tokamak

    Science.gov (United States)

    Li, Erzhong; Hu, Liqun; Chen, Kaiyun

    2014-01-01

    Bursts in electron cyclotron emission (ECE) were observed during sawtooth crashes in HT-7 in discharges with ion cyclotron resonance heating injected near the q = 1 rational surface (q is the safety factor). The local ECE measurement indicated that the bursty radiation is only observed on channels near but a little away outward from the q = 1 magnetic surface. In conjunction with the soft x-ray tomography analysis, it was determined that, for the first time, only a compression process survives in the later stage of fast magnetic reconnection but before prompt heat transport. The compression enhanced the electron radiation temperature, the increased amplitude of which agreed well with the estimation according to a kinetic compression theory model [R. J. Hastie and T. C. Hender, Nucl. Fusion 28, 585 (1988)]. This paper presents the experimental evidence that there indeed exists a transient compression phase which results in the bursty ECE radiation during a sawtooth crash.

  2. Assessment of ablative margin after radiofrequency ablation for hepatocellular carcinoma; comparison between magnetic resonance imaging with ferucarbotran and enhanced CT with iodized oil deposition.

    Science.gov (United States)

    Koda, Masahiko; Tokunaga, Shiho; Fujise, Yuki; Kato, Jun; Matono, Tomomitsu; Sugihara, Takaaki; Nagahara, Takakazu; Ueki, Masaru; Murawaki, Yoshikazu; Kakite, Suguru; Yamashita, Eijiro

    2012-07-01

    Our aim was to investigate whether magnetic resonance imaging (MRI) with ferucarbotran administered prior to radiofrequency ablation could accurately assess ablative margin when compared with enhanced computed tomography (CT) with iodized oil marking. We enrolled 27 patients with 32 hepatocellular carcinomas in which iodized oil deposits were visible throughout the nodule after transcatheter arterial chemoembolization. For these nodules, radiofrequency ablation was performed after ferucarbotran administration. We then performed T2-weighted MRI after 1 week and enhanced CT after 1 month. T2-weighted MRI demonstrated the ablative margin as a low-intensity rim. We classified the margin into three grades; margin (+): high-intensity area with a continuous low-intensity rim; margin zero: high-intensity area with a discontinuous low-intensity rim; and margin (-): high-intensity area extending beyond the low-intensity rim. In 28 (86%) of 32 nodules, there was agreement between MRI and CT. The overall agreement between for the two modalities in the assessment of ablative margin was good (κ=0.759, 95% confidence interval: 0.480-1.000, pablative margins on MRI were underestimated by one grade compared with CT. MRI using ferucarbotran is less invasive and allows earlier assessment than CT. The MRI technique performed similarly to enhanced CT with iodized oil marking in evaluating the ablative margin after radiofrequency ablation. Copyright © 2011 Elsevier Ireland Ltd. All rights reserved.

  3. Assessment of single-turn extraction for a superconducting separated-sector cyclotron

    Directory of Open Access Journals (Sweden)

    J.-W. Kim

    1999-04-01

    Full Text Available We have studied the beam dynamics in a high field separated-sector cyclotron to establish conditions required to achieve single-turn extraction. Extraction efficiency above 99% is aimed to avoid beam-induced damages. A sufficient last-turn separation and a preservation of beam quality throughout the acceleration are the prerequisites. The last-turn separation can be enhanced with the orbital precession induced by an off-centering injection as in existent lower field separated-sector cyclotrons. The beam qualities, on the other hand, are affected by the resonances traversed or approached during the acceleration. Acceleration of light nuclei to the energies of 300–400 MeV/u was especially disturbing because of the broadening of radial beamwidth upon crossing the ν_{r}=3/2 resonance. Tolerance to the third harmonic gradient field, which causes the resonance in lowest order, is set to be 0.1 G/cm. The integer resonance ν_{z}=1 can be avoided with a proper design of the yoke. The longitudinal space charge forces were also investigated to estimate the intensity limits determined by the energy spreads of beam assuming simplified charge distributions. Moreover, beam preparations for injection matching are described in view of reducing the beam losses into the extraction elements.

  4. Beam stripping extraction from the VINCY cyclotron

    Directory of Open Access Journals (Sweden)

    Ristić-Đurović Jasna L.

    2006-01-01

    Full Text Available The extraction system of a cyclotron guides an ion beam from a spiral acceleration orbit, through an extraction trajectory, into a high energy transport line. The two methods commonly used to direct an ion into the extraction path are deflection, by the electric field of an electrostatic deflector, and ion stripping, by a thin carbon foil. Compared to the electrostatic deflector system, the stripping extraction provides a fast and easy change of the extracted ion energy and is easier to manufacture operate, and maintain. However, the extraction trajectory and dynamics of an ion beam after stripping are highly dependant on the ion energy and specific charge. Thus, when a multipurpose machine such as the VINCY Cyclotron is concerned, it is far from easy to deliver a variety of ion beams into the same high energy transport line and at the same time preserve a reasonable compactness of the extraction system. The front side stripping extraction system of the VINCY Cyclotron provides high (~70 MeV and mid (~30 MeV energy protons, as well as a number of heavy ions in broad energy ranges. The back side stripping extraction system extracts low energy protons (~18 MeV and enables their simultaneous use with high energy protons at the front side of the machine.

  5. Wave-particle resonance condition test for ion-kinetic waves in the solar wind

    Energy Technology Data Exchange (ETDEWEB)

    Narita, Y. [Austrian Academy of Sciences, Graz (Austria). Space Research Inst.; Technische Univ. Braunschweig (Germany). Inst. fuer Geophysik und extraterrestrische Physik; Marsch, E. [Kiel Univ. (Germany). Inst fuer Experimentelle und Angewandte Physik; Perschke, C. [Technische Univ. Braunschweig (Germany). Inst. fuer Geophysik und extraterrestrische Physik; Technische Univ. Braunschweig (Germany). Inst. fuer Theoretische Physik; Glassmeier, K.H. [Technische Univ. Braunschweig (Germany). Inst. fuer Geophysik und extraterrestrische Physik; Max-Planck-Institut fuer Sonnensystemforschung, Goettingen (Germany); Motschmann, U. [Technische Univ. Braunschweig (Germany). Inst. fuer Theoretische Physik; Deutsches Zentrum fuer Luft- und Raumfahrt, Berlin (Germany). Inst. fuer Planetenforschung; Comisel, H. [Technische Univ. Braunschweig (Germany). Inst. fuer Theoretische Physik; Institute for Space Sciences, Bucharest-Magurele (Romania)

    2016-08-01

    Conditions for the Landau and cyclotron resonances are tested for 543 waves (identified as local peaks in the energy spectra) in the magnetic field fluctuations of the solar wind measured by the Cluster spacecraft on a tetrahedral scale of 100 km. The resonance parameters are evaluated using the frequencies in the plasma rest frame, the parallel components of the wavevectors, the ion cyclotron frequency, and the ion thermal speed. The observed waves show a character of the sideband waves associated with the ion Bernstein mode, and are in a weak agreement with the fundamental electron cyclotron resonance in spite of the ionkinetic scales. The electron cyclotron resonance is likely taking place in solar wind turbulence near 1AU (astronomical unit).

  6. NuSTAR Discovery of a Cyclotron Line in the Be/X-ray Binary RX J0520.5-6932 During Outburst

    DEFF Research Database (Denmark)

    Tendulkar, Shriharsh P.; Fürst, Felix; Pottschmidt, Katja

    2014-01-01

    We present spectral and timing analysis of NuSTAR observations of RX J0520.5$-$6932 in the 3-79 keV band collected during its outburst in January 2014. The target was observed on two epochs and we report the detection of a cyclotron resonant scattering feature with central energies of $E_\\mathrm{...

  7. Geonium "K" experiment using spin dependency of cyclotron frequency supports g data of earlier geonium "S" work.

    OpenAIRE

    Mittleman, R; Palmer, F; Gabrielse, G.; Dehmelt, H.

    1991-01-01

    By substituting the relativistic spin state dependence of the cyclotron frequency for the continuous Stern-Gerlach effect and running the geonium atom as a microsynchrocyclotron accelerator we have detected spin flips of the individual trapped electron. In our initial efforts we have been able to obtain a simple symmetric spin resonance about 4-fold narrower instead of a complex asymmetric one and also to support but not as yet seriously test the result of the earlier geonium "S" work, g/2 = ...

  8. Low temperature plasma enhanced chemical vapor deposition of thin films combining mechanical stiffness, electrical insulation, and homogeneity in microcavities

    Science.gov (United States)

    Peter, S.; Günther, M.; Hauschild, D.; Richter, F.

    2010-08-01

    The deposition of hydrogenated amorphous carbon (a-C:H) as well as hydrogenated amorphous silicon carbonitride (SiCN:H) films was investigated in view of a simultaneous realization of a minimum Young's modulus (>70 GPa), a high electrical insulation (≥1 MV/cm), a low permittivity and the uniform coverage of microcavities with submillimeter dimensions. For the a-C:H deposition the precursors methane (CH4) and acetylene (C2H2) were used, while SiCN:H films were deposited from mixtures of trimethylsilane [SiH(CH3)3] with nitrogen and argon. To realize the deposition of micrometer thick films with the aforementioned complex requirements at substrate temperatures ≤200 °C, several plasma enhanced chemical vapor deposition methods were investigated: the capacitively coupled rf discharge and the microwave electron cyclotron resonance (ECR) plasma, combined with two types of pulsed substrate bias. SiCN:H films deposited at about 1 Pa from ECR plasmas with pulsed high-voltage bias best met the requirements. Pulsed biasing with pulse periods of about 1 μs and amplitudes of about -2 kV was found to be most advantageous for the conformal low temperature coating of the microtrenches, thereby ensuring the required mechanical and insulating film properties.

  9. Spectra of KeV Protons Related to Ion-Cyclotron Wave Packets

    Science.gov (United States)

    Khazanov, G. V.; Sibeck, D. G.; Tel'Nikhin, A. A.; Kronberg, T. K.

    2017-01-01

    We use the Fokker-Planck-Kolmogorov equation to study the statistical aspects of stochastic dynamics of the radiation belt (RB) protons driven by nonlinear electromagnetic ion-cyclotron (EMIC) wave packets. We obtain the spectra of keV protons scattered by these waves that showsteeping near the gyroresonance, the signature of resonant wave-particle interaction that cannot be described by a simple power law. The most likely mechanism for proton precipitation events in RBs is shown to be nonlinear wave-particle interaction, namely, the scattering of RB protons into the loss cone by EMIC waves.

  10. Theory of electromagnetic cyclotron wave growth in a time-varying magnetoplasma

    Science.gov (United States)

    Gail, William B.

    1990-01-01

    The effect of a time-dependent perturbation in the magnetoplasma on the wave and particle populations is investigated using the Kennel-Petchek (1966) approach. Perturbations in the cold plasma density, energetic particle distribution, and resonance condition are calculated on the basis of the ideal MHD assumption given an arbitrary compressional magnetic field perturbation. An equation is derived describing the time-dependent growth rate for parallel propagating electromagnetic cyclotron waves in a time-varying magnetoplasma with perturbations superimposed on an equilibrium configuration.

  11. Distorted cyclotron line profile in Cep X-4 as observed by NuSTAR

    DEFF Research Database (Denmark)

    Fürst, F.; Pottschmidt, K.; Miyasaka, H.

    2015-01-01

    deviations at the red side of the line. We characterize this asymmetry with a second absorption feature around 19 keV. The line energy of the CRSF, which is not influenced by the addition of this feature, shows a small but significant positive luminosity dependence. With luminosities between (1-6)e36 erg...... a powerlaw with a Fermi-Dirac cutoff at high energies. Cep X-4 has a very strong cyclotron resonant scattering feature (CRSF) around 30 keV. A simple absorption-like line with a Gaussian optical depth or a pseudo-Lorentzian profile both fail to describe the shape of the CRSF accurately, leaving significant...

  12. Remote-Steering Antennas for 140 GHz Electron Cyclotron Heating of the Stellarator W7-X

    Directory of Open Access Journals (Sweden)

    Lechte C.

    2017-01-01

    Full Text Available For electron cyclotron resonance heating of the stellarator W7-X at IPP Greifswald, a 140 GHz/10 MW cw millimeter wave system has been built. Two out of 12 launchers will employ a remote-steering design. This paper describes the overall design of the two launchers, and design issues like input coupling structures, manufacturing of corrugated waveguides, optimization of the steering range, integration of vacuum windows, mitrebends and vacuum valves into the launchers, as well as low power tests of the finished waveguides.

  13. Remote-Steering Antennas for 140 GHz Electron Cyclotron Heating of the Stellarator W7-X

    Science.gov (United States)

    Lechte, C.; Kasparek, W.; Plaum, B.; Zeitler, A.; Erckmann, V.; Laqua, H.; Schneider, N.; Weissgerber, M.; Bechtold, A.; Busch, M.; Szepaniak, B.

    2017-07-01

    For electron cyclotron resonance heating of the stellarator W7-X at IPP Greifswald, a 140 GHz/10 MW cw millimeter wave system has been built. Two out of 12 launchers will employ a remote-steering design. This paper describes the overall design of the two launchers, and design issues like input coupling structures, manufacturing of corrugated waveguides, optimization of the steering range, integration of vacuum windows, mitrebends and vacuum valves into the launchers, as well as low power tests of the finished waveguides.

  14. Benchmarking of codes for electron cyclotron heating and electron cyclotron current drive under ITER conditions

    NARCIS (Netherlands)

    Prater, R.; Farina, D.; Gribov, Y.; Harvey, R. W.; Ram, A. K.; Lin-Liu, Y. R.; Poli, E.; Smirnov, A. P.; Volpe, F.; Westerhof, E.; Zvonkovo, A.

    2008-01-01

    Optimal design and use of electron cyclotron heating requires that accurate and relatively quick computer codes be available for prediction of wave coupling, propagation, damping and current drive at realistic levels of EC power. To this end, a number of codes have been developed in laboratories

  15. Electron cyclotron emission diagnostics on KSTAR tokamak.

    Science.gov (United States)

    Jeong, S H; Lee, K D; Kogi, Y; Kawahata, K; Nagayama, Y; Mase, A; Kwon, M

    2010-10-01

    A new electron cyclotron emission (ECE) diagnostics system was installed for the Second Korea Superconducting Tokamak Advanced Research (KSTAR) campaign. The new ECE system consists of an ECE collecting optics system, an overmode circular corrugated waveguide system, and 48 channel heterodyne radiometer with the frequency range of 110-162 GHz. During the 2 T operation of the KSTAR tokamak, the electron temperatures as well as its radial profiles at the high field side were measured and sawtooth phenomena were also observed. We also discuss the effect of a window on in situ calibration.

  16. Electron cyclotron emission imaging diagnostic system for Rijnhuizen Tokamak Project

    NARCIS (Netherlands)

    Deng, B.H.; Hsia, R. P.; Domier, C.W.; Burns, S. R.; Hillyer, T. R.; N C Luhmann Jr.,; Oyevaar, T.; Donne, A. J. H.; R. T. P. Team,

    1999-01-01

    A 16-channel electron cyclotron emission (ECE) imaging diagnostic system has been developed and installed on the Rijnhuizen Tokamak Project for measuring plasma electron cyclotron emission with a temporal resolution of 2 mu s. The high spatial resolution of the system is achieved by utilizing a low

  17. Cyclotron Lines: From Magnetic Field Strength Estimators to ...

    Indian Academy of Sciences (India)

    Chandreyee Maitra

    2017-09-12

    Sep 12, 2017 ... With forty years since the discovery of the first cyclotron line in Her X-1, there have been remarkable ... the important results related to cyclotron lines since its discovery and reviews their significance. ... context can provide, to build a complete picture for the physics of accretion and hence X-ray emission in.

  18. Towards quantitative simulations of high power proton cyclotrons

    Directory of Open Access Journals (Sweden)

    Y. J. Bi

    2011-05-01

    Full Text Available We describe a large scale simulation effort using Object Oriented Parallel Accelerator Library, that leads to a better quantitative understanding of the existing Paul Scherrer Institut high power proton cyclotron facility. The 1.3 MW of beam power on target poses stringent constraints on the controlled and uncontrolled beam losses. We present initial conditions for the Ring simulation, obtained from the new time-structure measurement and the many profile monitors of the 72 MeV transfer line. A trim coil model is developed, including trim coil TC15, which is needed to avoid the dangerous ν_{r}=2ν_{z} resonance. By properly selecting the injection position and angle (eccentric injection, the flattop voltage, and phase, very good agreement between simulations and measurements at the radial probe RRE4 is obtained. We report on 3–4 orders of magnitude in dynamic range when comparing simulations with measurements. The relation between beam intensity, rms beam size, and accelerating voltage is studied and compared with measurement. The demonstrated capabilities are mandatory in the design and operation of the next generation high power proton drivers. In an outlook we discuss our future plans to include more physics into the model, which eventually leads to an even larger dynamic range in the simulation.

  19. Electron-cyclotron plasma startup in the GDT experiment

    CERN Document Server

    Yakovlev, D V; Gospodchikov, E D; Solomakhin, A L; Savkin, V Ya; Bagryansky, P A

    2016-01-01

    The paper reports on a new plasma startup scenario in the Gas Dynamic Trap (GDT) magnetic mirror device. The primary 5 MW neutral beam injection (NBI) plasma heating system fires into a sufficiently dense plasma target ("seed plasma"), which is commonly supplied by an arc plasma generator. In the reported experiments, a different approach to seed plasma generation is explored. One of the channels of the electron cyclotron resonance (ECR) heating system is used to ionize the neutral gas and build up the density of plasma to a level suitable for NBI capture. After a short transition (about 1 ms) the discharge becomes essentially similar to a standard one initiated by the plasma gun. The paper presents the discharge scenario and experimental data on the seed plasma evolution during ECR heating, along with the dependencies on incident microwave power, magnetic configuration and pressure of a neutral gas. The characteristics of consequent high-power NBI discharge are studied and differences to the conventional sce...

  20. Electron cyclotron plasma startup in the GDT experiment

    Science.gov (United States)

    Yakovlev, D. V.; Shalashov, A. G.; Gospodchikov, E. D.; Solomakhin, A. L.; Savkin, V. Ya.; Bagryansky, P. A.

    2017-01-01

    We report on a new plasma startup scenario in the gas dynamic trap (GDT) magnetic mirror device. The primary 5 MW neutral beam injection (NBI) plasma heating system fires into a sufficiently dense plasma target (‘seed plasma’), which is commonly supplied by an arc plasma generator. In the reported experiments, a different approach to seed plasma generation is explored. One of the channels of the electron cyclotron resonance (ECR) heating system is used to ionize the neutral gas and build up the density of plasma to a level suitable for NBI capture. After a short transition of approximately 1 ms the discharge becomes essentially similar to a standard one initiated by the plasma gun. This paper presents the discharge scenario and experimental data on the seed plasma evolution during ECRH, along with the dependencies on incident microwave power, magnetic configuration and pressure of a neutral gas. The characteristics of the consequent high-power NBI discharge are studied and differences from the conventional scenario are discussed. A theoretical model describing the ECR breakdown and the seed plasma accumulation in a large-scale mirror trap is developed on the basis of the GDT experiment.

  1. Ion cyclotron and spin-flip emissions from fusion products in tokamaks

    Energy Technology Data Exchange (ETDEWEB)

    Arunasalam, V.; Greene, G.J.; Young, K.M.

    1993-02-01

    Power emission by fusion products of tokamak plasmas in their ion cyclotron range of frequencies (ICRF) and at their spin-flip resonance frequency is calculated for some specific model fusion product velocity-space distribution functions. The background plasma of say deuterium (D) is assumed to be in equilibrium with a Maxwellian distribution both for the electrons and ions. The fusion product velocity distributions analyzed here are: (1) A monoenergetic velocity space ring distribution. (2) A monoenergetic velocity space spherical shell distribution. (3) An anisotropic Maxwellian distribution with T [perpendicular] [ne] T[parallel]and with appreciable drift velocity along the confining magnetic field. Single dressed'' test particle spontaneous emission calculations are presented first and the radiation temperature for ion cyclotron emission (ICE) is analyzed both for black-body emission and nonequilibrium conditions. Thresholds for instability and overstability conditions are then examined and quasilinear and nonlinear theories of the electromagnetic ion cyclotron modes are discussed. Distinctions between kinetic or causal instabilities'' and hydrodynamic instabilities'' are drawn and some numerical estimates are presented for typical tokamak parameters. Semiquantitative remarks are offered on wave accessibility, mode conversion, and parametric decay instabilities as possible for spatially localized ICE. Calculations are carried out both for k[parallel] = 0 for k[parallel] [ne] 0. The effects of the temperature anisotropy and large drift velocities in the parallel direction are also examined. Finally, proton spin-flip resonance emission and absorption calculations are also presented both for thermal equilibrium conditions and for an inverted'' population of states.

  2. Use of gadolinium-based magnetic resonance imaging contrast agents and awareness of brain gadolinium deposition among pediatric providers in North America

    Energy Technology Data Exchange (ETDEWEB)

    Mithal, Leena B. [Northwestern University, Feinberg School of Medicine, Ann and Robert H. Lurie Children' s Hospital of Chicago, Department of Pediatrics, Chicago, IL (United States); Patel, Payal S. [University of Arizona College of Medicine, Department of Pediatrics, Phoenix, AZ (United States); Mithal, Divakar [Northwestern University, Feinberg School of Medicine, Ann and Robert H. Lurie Children' s Hospital of Chicago, Department of Pediatric Neurology, Chicago, IL (United States); Palac, Hannah L. [Northwestern University, Biostatistics, Feinberg School of Medicine, Ann and Robert H. Lurie Children' s Hospital of Chicago, Chicago, IL (United States); Rozenfeld, Michael N. [University of Arizona College of Medicine, Department of Radiology, Phoenix, AZ (United States)

    2017-05-15

    Numerous recent articles have reported brain gadolinium deposition when using linear but not macrocyclic gadolinium-based contrast agents (GBCAs). To determine the current landscape of gadolinium use among pediatric institutions and the knowledge base of radiologists and referring providers with regard to GBCAs and brain gadolinium deposition. We e-mailed voluntary closed surveys to 5,390 physicians in various pediatric professional societies between January 2016 and March 2016. We used chi-square and Fisher exact tests to compare response distributions among specialties. We found that 80% of surveyed pediatric hospitals use macrocyclic contrast agents. In the last year, 58% switched their agent, most commonly to gadoterate meglumine, with the most common reason being brain gadolinium deposition. Furthermore, surveys indicated that 23% of hospitals are considering switching, and, of these, 83% would switch to gadoterate meglumine; the most common reasons were brain gadolinium deposition and safety. Radiologists were more aware of brain gadolinium deposition than non-radiologist physicians (87% vs. 26%; P<0.0001). Radiologists and referring providers expressed similar levels of concern (95% and 89%). Twelve percent of radiologists and 2% of referring providers reported patients asking about brain gadolinium deposition. Radiologists were significantly more comfortable addressing patient inquiries than referring pediatric physicians (48% vs. 6%; P<0.0001). The number of MRIs requested by referring pediatric physicians correlated with their knowledge of brain gadolinium deposition, contrast agent used by their hospital, and comfort discussing brain gadolinium deposition with patients (P<0.0001). Since the discovery of brain gadolinium deposition, many pediatric hospitals have switched to or plan to switch to a more stable macrocyclic MR contrast agent, most commonly gadoterate meglumine. Despite this, there is need for substantial further education of radiologists and

  3. Extension of electron cyclotron heating at ASDEX Upgrade with respect to high density operation

    Science.gov (United States)

    Schubert, Martin; Stober, Jörg; Herrmann, Albrecht; Kasparek, Walter; Leuterer, Fritz; Monaco, Francesco; Petzold, Bernhard; Plaum, Burkhard; Vorbrugg, Stefan; Wagner, Dietmar; Zohm, Hartmut

    2017-10-01

    The ASDEX Upgrade electron cyclotron resonance heating operates at 105 GHz and 140 GHz with flexible launching geometry and polarization. In 2016 four Gyrotrons with 10 sec pulse length and output power close to 1 MW per unit were available. The system is presently being extended to eight similar units in total. High heating power and high plasma density operation will be a part of the future ASDEX Upgrade experiment program. For the electron cyclotron resonance heating, an O-2 mode scheme is proposed, which is compatible with the expected high plasma densities. It may, however, suffer from incomplete single-pass absorption. The situation can be improved significantly by installing holographic mirrors on the inner column, which allow for a second pass of the unabsorbed fraction of the millimetre wave beam. Since the beam path in the plasma is subject to refraction, the beam position on the holographic mirror has to be controlled. Thermocouples built into the mirror surface are used for this purpose. As a protective measure, the tiles of the heat shield on the inner column were modified in order to increase the shielding against unabsorbed millimetre wave power.

  4. Development of a low-level RF control system for PET cyclotron CYCIAE-14

    Science.gov (United States)

    Li, Pengzhan; Yin, Zhiguo; Ji, Bin; Zhang, Tianjue; Zhao, Zhenlu

    2014-01-01

    The project of a 14 MeV PET cyclotron aiming at medical diagnosis and treatment was proposed and started at CIAE in 2010. The low-level RF system is designed to stabilize acceleration voltage and control the resonance of the cavity. Based on the experience of the existing CRM Cyclotron in CIAE, a new start-up sequence is developed and tested. The frequency sweeping is used to activate the RF system. Before the tuner is put into use, a new state called "DDS tuning" is applied to trace the resonance frequency to the designed value. This new option state helps to cover the tuning range, if a large frequency variation occurs because of a thermal cavity deformation. The logic control unit detects the spark, reflection, Pulse/CW state and the frequency of the RF source to perform all kinds of protection and state operations. The test bench and on-line test are carried out to verify the initial design.

  5. Extension of electron cyclotron heating at ASDEX Upgrade with respect to high density operation

    Directory of Open Access Journals (Sweden)

    Schubert Martin

    2017-01-01

    Full Text Available The ASDEX Upgrade electron cyclotron resonance heating operates at 105 GHz and 140 GHz with flexible launching geometry and polarization. In 2016 four Gyrotrons with 10 sec pulse length and output power close to 1 MW per unit were available. The system is presently being extended to eight similar units in total. High heating power and high plasma density operation will be a part of the future ASDEX Upgrade experiment program. For the electron cyclotron resonance heating, an O-2 mode scheme is proposed, which is compatible with the expected high plasma densities. It may, however, suffer from incomplete single-pass absorption. The situation can be improved significantly by installing holographic mirrors on the inner column, which allow for a second pass of the unabsorbed fraction of the millimetre wave beam. Since the beam path in the plasma is subject to refraction, the beam position on the holographic mirror has to be controlled. Thermocouples built into the mirror surface are used for this purpose. As a protective measure, the tiles of the heat shield on the inner column were modified in order to increase the shielding against unabsorbed millimetre wave power.

  6. High-current cyclotron to drive an electronuclear assembly

    CERN Document Server

    Alenitsky, Yu G

    2002-01-01

    The proposal on creation of a high-current cyclotron complex for driving an electronuclear assembly reported at the 17th Meeting on Accelerators of Charged Particles is discussed. Some changes in the basic design parameters of the accelerator are considered in view of new results obtained in the recent works. It is shown that the cyclotron complex is now the most real and cheapest accelerator for production of proton beams with a power of up to 10 MW. Projects on design of a high-current cyclotron complex for driving an electronuclear subcritical assembly are presented.

  7. Improving cancer treatment with cyclotron produced radionuclides. Progress report

    Energy Technology Data Exchange (ETDEWEB)

    Larson, S.M.; Finn, R.D.

    1993-11-01

    This report describes our continuing long term goal of promoting nuclear medicine applications by improving the scientific basis for tumor diagnosis, treatment and treatment follow-up based on the use of cyclotron produced radiotracers in oncology. The program includes 3 interactive components: Radiochemistry/Cyclotron; Pharmacology; and Immunology. An essential strategy is as follows: novel radionuclides and radiotracers developed in the Radiochemistry/Cyclotron section will be employed in the Pharmacology and Immunology sections during the next year. The development of novel radionuclides and tracers is of course useful in and of itself, but their utility is greatly enhanced by the interaction with the immunology and pharmacology components of the program.

  8. Shielding design of the Mayo Clinic Scottsdale cyclotron vault

    Directory of Open Access Journals (Sweden)

    Riper Kenneth A. Van

    2017-01-01

    Full Text Available Mayo Clinic Scottsdale (Scottsdale, Arizona is building a cyclotron vault containing a cyclotron with adjacent targets and a beam line leading to an external target. The targets are irradiated by high energy (15 to 16.5 MeV protons for the production of radioisotopes. We performed Monte Carlo radiation transport simulations to calculate the radiation dose outside of the vault during irradiation of the cyclotron and external targets. We present the Monte Carlo model including the geometry, sources, and variance reduction methods. Mesh tallies surrounding the vault show the external dose rate is within acceptable limits.

  9. Radiation Monitoring System of 30 MeV Cyclotron

    Directory of Open Access Journals (Sweden)

    Lee Jin-Woo

    2017-01-01

    Full Text Available A state-of-the-art radiation monitoring system was implemented at KAERI for a 30-MeV cyclotron. This system consists of several types of radiation measuring systems for ambient dose equivalent rate measurements of outside photon and neutron areas as well as inside the cyclotron, and monitors the alpha and beta particulates released from a stack, as well as the results of worker contamination at the portal of the cyclotron. In addition, an automatic alarm system is also mounted if there are alarms in the measuring systems.

  10. Ion cyclotron emission by spontaneous emission

    Energy Technology Data Exchange (ETDEWEB)

    Da Costa, O. [Commission of the European Communities, Abingdon (United Kingdom). JET Joint Undertaking; Gresillon, D. [Ecole Polytechnique, 91 - Palaiseau (France). Lab. de Physique des Milieux Ionises

    1994-07-01

    The goal of the study is to examine whether the spontaneous emission can account for ICE (ion cyclotron emission) experimental results, or part of them. A straightforward approach to plasma emission is chosen, investigating the near equilibrium wave radiation by gyrating ions, and thus building from the majority and fast fusion ions the plasma fluctuations and emission on the fast magnetoacoustic or compressional Alfven wave mode in the IC frequency range. Similarities with the ICE experiments are shown: the emission temperature in the presence of fast ions (even in a very small amount), the strong fast ion emission increase with the harmonic, the fine double-line splitting of each peak, the linear but not proportional increase of the peak width with the harmonic. 3 refs., 2 figs.

  11. Modeling of the influences of multiple modulated electron cyclotron current drive on NTMs in rotating plasma

    Science.gov (United States)

    Chen, Long; Liu, Jinyuan; Duan, Ping; Liu, Guangrui; Bian, Xingyu

    2017-02-01

    In this work, physical models of neoclassical tearing modes (NTMs) including bootstrap current and multiple modulated electron cyclotron current drive model are applied. Based on the specific physical problems during the suppression of NTMs by driven current, this work compares the efficiency of continuous and modulated driven currents, and simulates the physical processes of multiple modulated driven currents on suppressing rotating magnetic island. It is found that when island rotates along the poloidal direction, the suppression ability of continuous driven current can be massively reduced due to current deposition outside the island separatrix and reverse deposition direction at the X point, which can be avoided by current drive modulation. Multiple current drive has a better suppressing effect than single current drive. This work gives realistic numerical simulations by optimizing the model and parameters based on the experiments, which could provide references for successful suppression of NTMs in future advanced tokamak such as international thermonuclear experimental reactor.

  12. Single-electron detection and spectroscopy via relativistic cyclotron radiation

    Energy Technology Data Exchange (ETDEWEB)

    Asner, David M.; Bradley, Rich; De Viveiros Souza Filho, Luiz A.; Doe, Peter J.; Fernandes, Justin L.; Fertl, M.; Finn, Erin C.; Formaggio, Joseph; Furse, Daniel L.; Jones, Anthony M.; Kofron, Jared N.; LaRoque, Benjamin; Leber, Michelle; MCBride, Lisa; Miller, M. L.; Mohanmurthy, Prajwal T.; Monreal, Ben; Oblath, Noah S.; Robertson, R. G. H.; Rosenberg, Leslie; Rybka, Gray; Rysewyk, Devyn M.; Sternberg, Michael G.; Tedeschi, Jonathan R.; Thummler, Thomas; VanDevender, Brent A.; Woods, N. L.

    2015-04-01

    It has been understood since 1897 that accelerating charges should emit electromagnetic radiation. Cyclotron radiation, the particular form of radiation emitted by an electron orbiting in a magnetic field, was first derived in 1904. Despite the simplicity of this concept, and the enormous utility of electron spectroscopy in nuclear and particle physics, single-electron cyclotron radiation has never been observed directly. Here we demonstrate single-electron detection in a novel radiofrequency spectrometer. We observe the cyclotron radiation emitted by individual electrons that are produced with mildly-relativistic energies by a gaseous radioactive source and are magnetically trapped. The relativistic shift in the cyclotron frequency permits a precise electron energy measurement. Precise beta electron spectroscopy from gaseous radiation sources is a key technique in modern efforts to measure the neutrino mass via the tritium decay endpoint, and this work is a proof-of-concept for future neutrino mass experiments using this technique.

  13. Neutron field inside a PET Cyclotron vault room

    Energy Technology Data Exchange (ETDEWEB)

    Vega C, H.R. [UAZ, C. Cipres 10, 98068 Zacatecas (Mexico); Mendez, R. [CIEMAT, Ave. Complutense 22, 28040 Madrid (Spain); Iniguez, M.P. [Universidad de Valladolid, Po Prado de la Magdalena s/n, 47011 Valladolid (Spain); Climent, J.M.; Penuelas, I. [Servicio de Medicina Nuclear de la Clinica Universitaria de Navarra, Pamplona (Spain); Barquero, R. [Hospital Universitario Rio Hortega, Valladolid (Spain)]. e-mail: fermineutron@yahoo.com

    2006-07-01

    The neutron field around a Positron Emission Tomography cyclotron was investigated during {sup 18} F radioisotope production with an 18 MeV proton beam. In this study the Ion Beam Application cyclotron, model Cyclone 18/9, was utilized. Measurements were carried out with a Bonner sphere neutron spectrometer with pairs of thermoluminescent dosemeters (TLD600 and TLD700) as thermal neutron detector. The TLDs readouts were utilized to unfold the neutron spectra at three different positions inside the cyclotron's vault room. With the spectra the Ambient dose equivalent was calculated. Neutron spectra unfolding were performed with the BUNKIUT code and the UTA4 response matrix. Neutron spectra were also determined by Monte Carlo calculations using a detailed model of cyclotron and vault room. (Author)

  14. Vacuum Control Systems of the Cyclotrons in VECC, Kolkata

    Science.gov (United States)

    Roy, Anindya; Akhtar, Javed; Yadav, R. C.; Bhole, R. B.; Pal, Sarbajit; Sarkar, D.; Bhandari, R. K.

    2012-11-01

    VECC has undertaken the modernization of the K-130 Room Temperature Cyclotron (RTC) (operational since 1978) and commissioning of K-500 Superconducting Cyclotron (SCC) at present. The control system of RTC vacuum system has been upgraded to Programmable Logic Controller (PLC) based automated system from relay based manual system. A distributed PLC based system is under installation for SCC vacuum system. The requirement of high vacuum in both the cyclotrons (1×10-6 mbar for RTC and 5 × 10-8 mbar SCC) imposes the reliable local and remote operation of all vacuum components and instrumentation. The design and development of the vacuum control system of two cyclotrons using the Experimental Physics and Industrial Control System (EPICS) distributed real-time software tools are presented.

  15. Maryland University sectored isochronous cyclotron (MUSIC): Progress report No. 23

    Energy Technology Data Exchange (ETDEWEB)

    1967-10-09

    Progress is reported in the design, installation of various components of the cyclotron, including coils, magnets, rf system, and vacuum system. Also reported are measurements on magnets and rf components. (LEW)

  16. Maryland University sectored isochronous cyclotron (MUSIC): Progress report No. 20

    Energy Technology Data Exchange (ETDEWEB)

    1967-06-30

    Progress is reported in the fabrication and testing of cyclotron components, including magnet system and rf system components. Work on vacuum components and instrumentation and control equipment is also reported. (LEW)

  17. Maryland University sectored isochronous cyclotron (MUSIC): Progress report No. 32

    Energy Technology Data Exchange (ETDEWEB)

    1968-06-28

    Completion of magnet tests, followed by completion of installation of major cyclotron components, are reported. Intermediate level power tests of the rf system are also reported. Design and fabrication of the control system are reported to be under way. (LEW)

  18. Maryland University sectored isochronous cyclotron (MUSIC): Progress report No. 26

    Energy Technology Data Exchange (ETDEWEB)

    1968-01-17

    Progress is reported in the fabrication, installation, and testing of cyclotron components, including magnets and coils, rf components, vacuum and control equipment. Also reported are magnet and rf component measurements. (LEW)

  19. Cryogenic system for VECC K500 superconducting cyclotron

    CERN Document Server

    Pal, G; Bhattacharyya, T K; Bhandari, R K

    2009-01-01

    VEC Centre, Kolkata in India is at an advanced stage of commissioning a K500 superconducting cyclotron. The superconducting coil of the magnet for cyclotron is cooled by liquid helium. Three liquid helium cooled cryopanels, placed inside the Dees of the radiofrequency system, maintain the vacuum in the acceleration region of the superconducting cyclotron. The cryogenic system for magnet for cyclotron has been tested by cooling the coil and energizing the magnet. The cryogenic system for cryopanels has also been tested. Heater and temperature sensor were placed on the liquid helium cold head for cryopanel. The temperature of the cold head was observed to be below 20 K upto a heat load of 11.7 watt.

  20. Design of 10 MeV cyclotron accelerator

    Directory of Open Access Journals (Sweden)

    R Solhju

    2015-09-01

    Full Text Available Design and construction of 10MeV cyclotron has been started at Amirkabir University of Technology since 2012. So far, the conceptual and detail engineering design phases have been finalized. The main purpose of this baby cyclotron is to generate proton beam for the production of PET radioisotopes. The cyclotron consists of magnet, cavity, ion source, RF and LLRF system, vacuum system, cooling system, power amplifiers and power supplies system. In this paper, a brief of design principles for all the parts of cyclotron and their final simulation results is presented. It should be noted that these simulations have been performed and optimized by the most accurate softwares such as TOSCA, ANSYS, HFSS, SolidWorks and CST. Also, the manufacturing feasibility of all the parts is performed and their dimensions and parameters are synchronized with manufacturing standards

  1. A new way to measure the electron cyclotron frequency

    Science.gov (United States)

    Palmer, F. L.

    1993-03-01

    A method is described for using spin flips to measure the 0 to 1 cyclotron transition frequency of a single electron in a Penning trap. Detection can be accomplished with magnetic bottles of 10 T/m2 or less, thereby greatly reducing the thermal broadening of the cyclotron line. This method complements a recently published technique for measuring the anomaly frequency, making a more precise measurement of the electron anomaly ratio possible.

  2. Ion-Beam-Excited Electrostatic Ion Cyclotron Waves

    DEFF Research Database (Denmark)

    Michelsen, Poul; Pécseli, Hans; Juul Rasmussen, Jens

    1976-01-01

    Self-excited electrostatic ion cyclotron waves were observed in an ion-beam-plasma system produced in a DP-operated Q-machine. The frequency of the waves showed the theoretically predicted variation with the magnetic field.......Self-excited electrostatic ion cyclotron waves were observed in an ion-beam-plasma system produced in a DP-operated Q-machine. The frequency of the waves showed the theoretically predicted variation with the magnetic field....

  3. PET computer programs for use with the 88-inch cyclotron

    Energy Technology Data Exchange (ETDEWEB)

    Gough, R.A.; Chlosta, L.

    1981-06-01

    This report describes in detail several offline programs written for the PET computer which provide an efficient data management system to assist with the operation of the 88-Inch Cyclotron. This function includes the capability to predict settings for all cyclotron and beam line parameters for all beams within the present operating domain of the facility. The establishment of a data base for operational records is also described from which various aspects of the operating history can be projected.

  4. Electron-cyclotron heating in the Constance 2 mirror experiment

    Energy Technology Data Exchange (ETDEWEB)

    Mauel, Michael E.

    1982-09-01

    Electron cyclotron heating of a highly-ionized plasma in mirror geometry is investigated. The experimental diagnosis of the electron energy distribution and the comparison of the results of this diagnosis with a two dimensional, time-dependent Fokker-Planck simulation are accomplished in four steps. (1) First, the power balance of the heated and unheated Constance 2 plasma is analyzed experimentally. It is concluded that the heated electrons escape the mirror at a rate dominated by a combination of the influx of cool electrons from outside the mirror and the increased loss rate of the ions. (2) The microwave parameters at the resonance zones are then calculated by cold-plasma ray tracing. High N/sub parallel/ waves are launched and for these waves, strong first-pass absorption is predicted. The absorption strength is qualitatively checked in the experiment by surrounding the plasma with non-reflecting liners. (3) A simplified quasilinear theory including the effect of N/sub parallel/ is developed to model the electrons. An analytic expression is derived for the RF-induced pump-out of the magnetically-confined warm electrons. Results of the Fokker-Planck simulations show the development of the electron energy distribution for several plasma conditions and verify the scaling of the analytic expression for RF-induced diffusion into the loss cone. (4) Sample x-ray and endloss data are presented, and the overall comparison between the simulation and experiment is discussed. The x-ray signals indicate that, for greater RF power, the hot electrondensity increases more rapidly than its temperature. The time history of the endloss data, illustrating RF-enhancement, suggests the predicted scaling for warm-electron pump-out. Finally, a comparison between the measured and predicted energy distribution shows that the bulk, warm and hot components of the heated Constance 2 electrons are indeed reproduced by the simulation.

  5. Ion source and injection line for high intensity medical cyclotron.

    Science.gov (United States)

    Jia, XianLu; Guan, Fengping; Yao, Hongjuan; Zhang, TianJue; Yang, Jianjun; Song, Guofang; Ge, Tao; Qin, Jiuchang

    2014-02-01

    A 14 MeV high intensity compact cyclotron, CYCIAE-14, was built at China Institute of Atomic Energy (CIAE). An injection system based on the external H- ion source was used on CYCIAE-14 so as to provide high intensity beam, while most positron emission tomography cyclotrons adopt internal ion source. A beam intensity of 100 μA/14 MeV was extracted from the cyclotron with a small multi-cusp H- ion source (CIAE-CH-I type) and a short injection line, which the H- ion source of 3 mA/25 keV H- beam with emittance of 0.3π mm mrad and the injection line of with only 1.2 m from the extraction of ion source to the medial plane of the cyclotron. To increase the extracted beam intensity of the cyclotron, a new ion source (CIAE-CH-II type) of 9.1 mA was used, with maximum of 500 μA was achieved from the cyclotron. The design and test results of the ion source and injection line optimized for high intensity acceleration will be given in this paper.

  6. Electromagnetic cyclotron waves near the proton cyclotron frequency in the solar wind

    Science.gov (United States)

    Jian, Lan K.; Boardsen, Scott; Moya, Pablo; Stevens, Michael; Alexander, Robert; Vinas, Adolfo

    2015-04-01

    Strong narrow-band electromagnetic waves around the proton cyclotron frequency (fpc) have been found sporadically in the solar wind from 0.3 to 0.7 AU during MESSENGER spacecraft’s cruise phase. These waves are transverse and circularly polarized, and they propagate in directions quasi-parallel to the magnetic field. The wave power decreases quadratically with heliocentric distance, faster than the trend if assuming the conservation of Poynting flux for wave packets, suggesting there is energy dissipation from the waves, which could contribute to the heating and acceleration of solar wind plasma. Although the wave frequency is a few times of fpc in the spacecraft frame, it is a fraction of fpc in the solar wind plasma frame after removing the Doppler shift effect. In this frequency range, the waves can be left-hand (LH) polarized ion cyclotron waves or right-hand (RH) polarized magnetosonic waves. Because the waves are LH or RH polarized in the spacecraft frame with otherwise nearly identical characteristics, they could be due to Doppler shift of a same type of waves or a mixture of waves with intrinsically different polarizations. Through the assistance of audification, we have studied the long-lasting wave events in 2005 using high-cadence magnetic field data from the Wind mission. Statistically, in contrast with general solar wind, the protons at these waves are distributed closer to the proton instability thresholds, while the alpha particles at these waves are distributed further away from the alpha instability thresholds. For selected events of extensive waves, the ion distribution is analyzed in detail. A mixture of temperature anisotropies for core protons, beam protons, and alpha particles, as well as proton beam drift are often found in such events. We conduct linear wave dispersion analysis using these ion moments to examine whether these waves can be explained by the local generation of kinetic instabilities such as the LH ion cyclotron, the RH

  7. Correlation electron cyclotron emission diagnostic in TCV

    Science.gov (United States)

    Fontana, M.; Porte, L.; Molina Cabrera, P.

    2017-08-01

    The correlation electron cyclotron emission diagnostic of tokamak à configuration variable has recently been upgraded. It now has the choice of three lines of sight: two horizontal lines placed on the low field side of the vessel, perpendicular to the magnetic field, and a dual-axis steerable antenna. The polarization of the radiation collected by the latter can be rotated using a universal polarizer situated in the transmission line. This line is also shared with a reflectometry system, allowing simultaneous measurements of temperature and density fluctuations in the same plasma volumes. When using this line, it is possible to choose between two dedicated front ends characterized by different local oscillator frequencies, adding flexibility in the choice of the plasma region to be studied. The intermediate frequency section is now equipped with six frequency tunable YIG filters allowing the study of turbulence properties in a wide range of radial positions. When studying fluctuations over the whole video bandwidth, the minimum detectable fluctuation level is δ Te/Te˜0.5 % . The new system has been used to measure electron temperature fluctuations over a large fraction of the plasma profiles in a series of plasmas with triangularity varying from 0.6 to -0.6 but comparable collisionality profiles.

  8. Progress in research, April 1, 1992--March 31, 1993, Texas A and M University Cyclotron Institute

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-07-01

    This Institute annual report for the period 1 April 1992--31 March 1993 covers a period which has seen the initial runs of three new spectrometers which constitute a major portion of the new detection capabilities developed for this facility. These devices are the Proton Spectrometer (PSP), the Mass Achromat Recoil Mass Spectrometer (MARS), and the Multipole dipole Multipole (MDM) Particle Spectrometer. These devices are now available to pursue the studies of Gamow Teller states, reactions of astrophysical interest, and giant resonance studies for which they were constructed, as well as for other experiments. A beam analysis system which will deliver high resolution beams to the MDM spectrometer is currently under construction. With the completion of these spectrometer projects, the facility emphasis is now focused on the development of the full capabilities of the K500 cyclotron and on the research program. During the report period, the ECR-K500 cyclotron combination operated 5,849 hours. Theoretical work reported in this document ranges from nuclear structure calculations using the IBM-2 model to calculations of kaon production and the in-medium properties of the rho and phi mesons, the latter as a probe of the QCD phase transition. Nuclear dynamics and exotic shapes and fragmentation modes of hot nuclei are also addressed. In atomic physics, new measurements of x-ray emission from highly ionized ions, of molecular dissociation and of surface interactions are reported.

  9. NuSTAR Discovery of a Cyclotron Line in KS 1947+300

    Science.gov (United States)

    Furst, Felix; Pottschmidt, Katja; Wilms, Jorn; Kennea, Jamie; Bachetti, Matteo; Bellm, Eric; Boggs, Steven E.; Chakrabarty, Deepto; Christensen, Finn E.; Craig, William W.; hide

    2014-01-01

    We present a spectral analysis of three simultaneous Nuclear Spectroscopy Telescope Array and Swift/XRT observations of the transient Be-neutron star binary KS 1947+300 taken during its outburst in 2013/2014. These broadband observations were supported by Swift/XRTmonitoring snapshots every three days, which we use to study the evolution of the spectrum over the outburst.We find strong changes of the power-law photon index, which shows a weak trend of softening with increasing X-ray flux. The neutron star shows very strong pulsations with a period of P ˜ [almost equal to] 18.8 s. The 0.8-79 keV broadband spectrum can be described by a power law with an exponential cutoff and a blackbody component at low energies. During the second observation we detect a cyclotron resonant scattering feature at 12.5 keV, which is absent in the phase-averaged spectra of observations 1 and 3. Pulse phase-resolved spectroscopy reveals that the strength of the feature changes strongly with pulse phase and is most prominent during the broad minimum of the pulse profile. At the same phases the line also becomes visible in the first and third observation at the same energy. This discovery implies that KS 1947+300 has a magnetic field strength of B ˜ [almost equal to] 1.1 × 1012(1 + z) G, which is at the lower end of known cyclotron line sources.

  10. The electron-cyclotron maser instability as a source of plasma radiation. [Solar radio bursts

    Science.gov (United States)

    Winglee, R. M.; Dulk, G. A.

    1986-01-01

    The generation of continuum bursts from the sun at dm and m wavelengths (in particular, type IV bursts) via the electron-cyclotron-maser instability is examined. The maser instability can be driven by an electron distribution with either a loss-cone anisotropy or a peak at large pitch angles. For omega(p)/Omega(e) much greater than 1, the maser emission is produced by electrons interacting through a harmonic (cyclotron) resonance and is electrostatic, being in the upper hybrid mode at frequencies approximately equal to omega(p). Coalescence processes are required to convert the electrostatic waves into transverse radiation which can escape from the source region. Whether the resultant spectrum is nearly a smooth continuum or has a zebra-stripe pattern (both of which occur in type IV bursts) depends on the form of the electron distribution, inhomogeneities in the density and magnetic field, and whether the maser reaches saturation. For at least the case of some type IV dm bursts with fine structure, comparison with observations seems to indicate that the electrons producing the emission are more likely to have a loss-cone distribution, and that the maser instability is not at saturation.

  11. A quasi-optical electron cyclotron maser for fusion reactor heating

    Energy Technology Data Exchange (ETDEWEB)

    Morse, E.C.

    1990-01-01

    High power microwave and millimeter sources, such as the quasi-optical electron cyclotron maser (QOECM) are important in fusion research as well as in high-energy physics and in other applications. The interaction between the electromagnetic modes of a Fabry-Perot resonator and an electron beam gyrating through a magnetic field has been studied for both the cases of beams parallel and perpendicular to the resonator. The parallel case was theoretically first studied by Kurin for forward and backward wave interaction, and experimentally by Komlev and Kurin. Kreischer and Temkin reviewed the general case of the linear small signal interaction parallel and perpendicular to the resonator. Sprangle, et al discussed the perpendicular case in a self-consistent linear and nonlinear theoretical study using the Gaussian transverse profile of an open resonator with a single longitudinal mode. Experimental verification of the devices operation was first mentioned in work at the Naval Research Laboratory. Theoretical studies using a time-dependent analysis of a large number of longitudinal modes with similar transverse mode profiles have demonstrated that single longitudinal-mode operation can be achieved at equilibrium and that performance can be enhanced by prebunching the electron beam and tapering the magnetic field. The use of output coupling apertures in the mirrors has been studied theoretically in relation to the structure of the modes for both confocal and nonconfocal resonators by Permnoud; use of an open resonator with stepped mirrors has been studied in order to choose a particular longitudinal mode. Studies at the Naval Research Laboratory mirror used configurations that diffraction couple the energy from around the mirror edges, so that the transverse profile inside the resonator can be selective to the fundamental mode.

  12. A quasi-optical electron cyclotron maser for fusion reactor heating. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Morse, E.C.

    1990-12-31

    High power microwave and millimeter sources, such as the quasi-optical electron cyclotron maser (QOECM) are important in fusion research as well as in high-energy physics and in other applications. The interaction between the electromagnetic modes of a Fabry-Perot resonator and an electron beam gyrating through a magnetic field has been studied for both the cases of beams parallel and perpendicular to the resonator. The parallel case was theoretically first studied by Kurin for forward and backward wave interaction, and experimentally by Komlev and Kurin. Kreischer and Temkin reviewed the general case of the linear small signal interaction parallel and perpendicular to the resonator. Sprangle, et al discussed the perpendicular case in a self-consistent linear and nonlinear theoretical study using the Gaussian transverse profile of an open resonator with a single longitudinal mode. Experimental verification of the devices operation was first mentioned in work at the Naval Research Laboratory. Theoretical studies using a time-dependent analysis of a large number of longitudinal modes with similar transverse mode profiles have demonstrated that single longitudinal-mode operation can be achieved at equilibrium and that performance can be enhanced by prebunching the electron beam and tapering the magnetic field. The use of output coupling apertures in the mirrors has been studied theoretically in relation to the structure of the modes for both confocal and nonconfocal resonators by Permnoud; use of an open resonator with stepped mirrors has been studied in order to choose a particular longitudinal mode. Studies at the Naval Research Laboratory mirror used configurations that diffraction couple the energy from around the mirror edges, so that the transverse profile inside the resonator can be selective to the fundamental mode.

  13. Conceptual design studies of the Electron Cyclotron launcher for DEMO reactor

    Science.gov (United States)

    Moro, Alessandro; Bruschi, Alex; Franke, Thomas; Garavaglia, Saul; Granucci, Gustavo; Grossetti, Giovanni; Hizanidis, Kyriakos; Tigelis, Ioannis; Tran, Minh-Quang; Tsironis, Christos

    2017-10-01

    A demonstration fusion power plant (DEMO) producing electricity for the grid at the level of a few hundred megawatts is included in the European Roadmap [1]. The engineering design and R&D for the electron cyclotron (EC), ion cyclotron and neutral beam systems for the DEMO reactor is being performed by Work Package Heating and Current Drive (WPHCD) in the framework of EUROfusion Consortium activities. The EC target power to the plasma is about 50 MW, in which the required power for NTM control and burn control is included. EC launcher conceptual design studies are here presented, showing how the main design drivers of the system have been taken into account (physics requirements, reactor relevant operations, issues related to its integration as in-vessel components). Different options for the antenna are studied in a parameters space including a selection of frequencies, injection angles and launch points to get the best performances for the antenna configuration, using beam tracing calculations to evaluate plasma accessibility and deposited power. This conceptual design studies comes up with the identification of possible limits, constraints and critical issues, essential in the selection process of launcher setup solution.

  14. Conceptual design studies of the Electron Cyclotron launcher for DEMO reactor

    Directory of Open Access Journals (Sweden)

    Moro Alessandro

    2017-01-01

    Full Text Available A demonstration fusion power plant (DEMO producing electricity for the grid at the level of a few hundred megawatts is included in the European Roadmap [1]. The engineering design and R&D for the electron cyclotron (EC, ion cyclotron and neutral beam systems for the DEMO reactor is being performed by Work Package Heating and Current Drive (WPHCD in the framework of EUROfusion Consortium activities. The EC target power to the plasma is about 50 MW, in which the required power for NTM control and burn control is included. EC launcher conceptual design studies are here presented, showing how the main design drivers of the system have been taken into account (physics requirements, reactor relevant operations, issues related to its integration as in-vessel components. Different options for the antenna are studied in a parameters space including a selection of frequencies, injection angles and launch points to get the best performances for the antenna configuration, using beam tracing calculations to evaluate plasma accessibility and deposited power. This conceptual design studies comes up with the identification of possible limits, constraints and critical issues, essential in the selection process of launcher setup solution.

  15. Efficiency enhancement of slow-wave electron-cyclotron maser by a second-order shaping of the magnetic field in the low-gain limit

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Si-Jia; Zhang, Yu-Fei; Wang, Kang [School of Science, Beijing University of Chemical Technology, Beijing 100029 (China); Li, Yong-Ming [Information Science and Engineering College, XinJiang University, Urumqi XinJiang 830046 (China); Jing, Jian, E-mail: jingjian@mail.buct.edu.cn [School of Science, Beijing University of Chemical Technology, Beijing 100029 (China)

    2017-03-15

    Based on the anomalous Doppler effect, we put forward a proposal to enhance the conversion efficiency of the slow-wave electron cyclotron masers (ECM) under the resonance condition. Compared with previous studies, we add a second-order shaping term in the guild magnetic field. Theoretical analyses and numerical calculations show that it can enhance the conversion efficiency in the low-gain limit. The case of the initial velocity spread of electrons satisfying the Gaussian distribution is also analysed numerically.

  16. Inverse ion-cyclotron damping and excitation of multiharmonic ion-cyclotron waves in the northern magnetospheric cusp

    Science.gov (United States)

    Slapak, Rikard; Gunell, Herbert; Hamrin, Maria

    2017-04-01

    We have investigated a case of inverse ion-cyclotron damping taking place in the northern terrestrial magnetospheric cusp, exciting waves at the ion-cyclotron frequency and its harmonics. Magnetosheath influx in the cusps and the effect of convection and magnetic mirroring give rise to parallel velocity shears, dvallel/dx\\perp, often associated with instabilities in the plasma and corresponding ion-cyclotron waves, whose evolution is described by a damping factor. This damping factor depends on, for example, the wave numbers and the velocity shear itself and can under certain conditions be negative, hence describing inverse damping (or wave growth). However, an additional required condition for inverse ion-cyclotron damping is a velocity shear in the magnetic field-aligned ion-bulk flow, and this condition is only met for magnetosheath influx in the northern cusp, as oppose to the southern cusp. The ion-cyclotron waves are primarily seen as peaks in the magnetic-field spectral densities, as presented by Slapak et al., [GRL (2016), doi:10.1002/2016GL071680]. The corresponding peaks in the electric-field spectral densities are not as profound, suggesting a background electric field noise or other processes of wave generation causing the electric spectral densities to smoothen out more compared to the magnetic counterpart. We note that some ion-cyclotron wave activity is present in a few similar shear events in the southern cusp, which indicates that other mechanisms generating ion-cyclotron waves may also be present during such conditions.

  17. Risk assessment of 30 MeV cyclotron facilities

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Gyo Seong; Lee, Jin Woo [Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute, Jeongeup (Korea, Republic of); Kim, Chong Yeal [Dept. of Radiation Science and Technology, Chonbuk National University, Jeonju (Korea, Republic of)

    2017-03-15

    A cyclotron is a kind of particle accelerator that produces a beam of charged particles for the production of medical, industrial, and research radioisotopes. More than 30 cyclotrons are operated in Korea to produce 18F, an FDG synthesis at hospitals. A 30-MeV cyclotron was installed at ARTI (Advanced Radiation Technology Institute, KAERI) mainly for research regarding isotope production. In this study, we analyze and estimate the items of risk such as the problems in the main components of the cyclotron, the loss of radioactive materials, the leakage of coolant, and the malfunction of utilities, fres and earthquakes. To estimate the occurrence frequency in an accident risk assessment, five levels, i.e., Almost certain, Likely, Possible, Unlikely, and Rare, are applied. The accident consequence level is classified under four grades based on the annual permissible dose for radiation workers and the public in the nuclear safety law. The analysis of the accident effect is focused on the radioactive contamination caused by radioisotope leakage and radioactive material leakage of a ventilation filter due to a free. To analyze the risks, Occupation Safety and Health Acts is applied. In addition, action plans against an accident were prepared after a deep discussion among relevant researchers. In this acts, we will search for hazard and introduce the risk assessment for the research 30-MeV cyclotron facilities of ARTI.

  18. 75 FR 48939 - National Superconducting Cyclotron Laboratory of Michigan State University; Notice of Decision on...

    Science.gov (United States)

    2010-08-12

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF COMMERCE International Trade Administration National Superconducting Cyclotron Laboratory of Michigan State University...., NW., Washington, DC. Docket Number: 10-043. Applicant: National Superconducting Cyclotron Laboratory...

  19. Development of a fast scintillator based beam phase measurement system for compact superconducting cyclotrons

    Energy Technology Data Exchange (ETDEWEB)

    Bhattacharjee, Tanushyam; Kanti Dey, Malay; Dhara, Partha; Roy, Suvodeep; Debnath, Jayanta; Balakrishna Bhole, Rajendra; Dutta, Atanu; Pradhan, Jedidiah; Pal, Sarbajit; Pal, Gautam; Roy, Amitava; Chakrabarti, Alok [Variable Energy Cyclotron Centre, 1/AF Bidhannagar, Kolkata 700064 (India)

    2013-05-15

    In an isochronous cyclotron, measurements of central phase of the ion beam with respect to rf and the phase width provide a way to tune the cyclotron for maximum energy gain per turn and efficient extraction. We report here the development of a phase measurement system and the measurements carried out at the Variable Energy Cyclotron Centre's (VECC's) K= 500 superconducting cyclotron. The technique comprises detecting prompt {gamma}-rays resulting from the interaction of cyclotron ion beam with an aluminium target mounted on a radial probe in coincidence with cyclotron rf. An assembly comprising a fast scintillator and a liquid light-guide inserted inside the cyclotron was used to detect the {gamma}-rays and to transfer the light signal outside the cyclotron where a matching photo-multiplier tube was used for light to electrical signal conversion. The typical beam intensity for this measurement was a few times 10{sup 11} pps.

  20. Calibration of the simulation model of the VINCY cyclotron magnet

    Directory of Open Access Journals (Sweden)

    Ćirković Saša

    2002-01-01

    Full Text Available The MERMAID program will be used to isochronise the nominal magnetic field of the VINCY Cyclotron. This program simulates the response, i. e. calculates the magnetic field, of a previously defined model of a magnet. The accuracy of 3D field calculation depends on the density of the grid points in the simulation model grid. The size of the VINCY Cyclotron and the maximum number of grid points in the XY plane limited by MERMAID define the maximumobtainable accuracy of field calculations. Comparisons of the field simulated with maximum obtainable accuracy with the magnetic field measured in the first phase of the VINCY Cyclotron magnetic field measurements campaign has shown that the difference between these two fields is not as small as required. Further decrease of the difference between these fields is obtained by the simulation model calibration, i. e. by adjusting the current through the main coils in the simulation model.