Highly integrated CO2 capture and conversion: Direct synthesis of cyclic carbonates from industrial flue gas

KAUST Repository

Barthel, Alexander

2016-02-08

Robust and selective catalytic systems based on early transition metal halides (Y, Sc, Zr) and organic nucleophiles were found able to quantitatively capture CO2 from diluted streams via formation of hemicarbonate species and to convert it to cyclic organic carbonates under ambient conditions. This observation was exploited in the direct and selective chemical fixation of flue gas CO2 collected from an industrial exhaust, affording high degrees of CO2 capture and conversion.

Enhanced oil recovery (EOR) by miscible CO{sub 2} and water flooding of asphaltenic and non-asphaltenic oils

Energy Technology Data Exchange (ETDEWEB)

Chukwudeme, E. A.; Hamouda, A. A. [Department of Petroleum Engineering, University of Stavanger, 4036 Stavanger (Norway)

2009-07-01

An EOR study has been performed applying miscible CO{sub 2} flooding and compared with that for water flooding. Three different oils are used, reference oil (n-decane), model oil (n-C10, SA, toluene and 0.35 wt % asphaltene) and crude oil (10 wt % asphaltene) obtained from the Middle East. Stearic acid (SA) is added representing a natural surfactant in oil. For the non-asphaltenic oil, miscible CO{sub 2} flooding is shown to be more favourable than that by water. However, it is interesting to see that for first years after the start of the injection (< 3 years) it is shown that there is almost no difference between the recovered oils by water and CO{sub 2}, after which (> 3 years) oil recovery by gas injection showed a significant increase. This may be due to the enhanced performance at the increased reservoir pressure during the first period. Maximum oil recovery is shown by miscible CO{sub 2} flooding of asphaltenic oil at combined temperatures and pressures of 50 {sup o}C/90 bar and 70 {sup o}C/120 bar (no significant difference between the two cases, about 1%) compared to 80 {sup o}C/140 bar. This may support the positive influence of the high combined temperatures and pressures for the miscible CO{sub 2} flooding; however beyond a certain limit the oil recovery declined due to increased asphaltene deposition. Another interesting finding in this work is that for single phase oil, an almost linear relationship is observed between the pressure drop and the asphaltene deposition regardless of the flowing fluid pressure. (author)

Numerical Simulation of CO2 Flooding of Coalbed Methane Considering the Fluid-Solid Coupling Effect.

Directory of Open Access Journals (Sweden)

Jianjun Liu

Full Text Available CO2 flooding of coalbed methane (CO2-ECBM not only stores CO2 underground and reduces greenhouse gas emissions but also enhances the gas production ratio. This coupled process involves multi-phase fluid flow and coal-rock deformation, as well as processes such as competitive gas adsorption and diffusion from the coal matrix into fractures. A dual-porosity medium that consists of a matrix and fractures was built to simulate the flooding process, and a mathematical model was used to consider the competitive adsorption, diffusion and seepage processes and the interaction between flow and deformation. Due to the effects of the initial pressure and the differences in pressure variation during the production process, permeability changes caused by matrix shrinkage were spatially variable in the reservoir. The maximum value of permeability appeared near the production well, and the degree of rebound decreased with increasing distance from the production well.

Development of ε-insensitive smooth support vector regression for predicting minimum miscibility pressure in CO2 flooding

Directory of Open Access Journals (Sweden)

Shahram Mollaiy-Berneti

2018-02-01

Full Text Available Successful design of a carbon dioxide (CO2 flooding in enhanced oil recovery projects mostly depends on accurate determination of CO2-crude oil minimum miscibility pressure (MMP. Due to the high expensive and time-consuming of experimental determination of MMP, developing a fast and robust method to predict MMP is necessary. In this study, a new method based on ε-insensitive smooth support vector regression (ε-SSVR is introduced to predict MMP for both pure and impure CO2 gas injection cases. The proposed ε-SSVR is developed using dataset of reservoir temperature, crude oil composition and composition of injected CO2. To serve better understanding of the proposed, feed-forward neural network and radial basis function network applied to denoted dataset. The results show that the suggested ε-SSVR has acceptable reliability and robustness in comparison with two other models. Thus, the proposed method can be considered as an alternative way to monitor the MMP in miscible flooding process.

Experimental research on microscopic displacement mechanism of CO2-water alternative flooding in low permeability reservoir

Science.gov (United States)

Han, Hongyan; Zhu, Weiyao; Long, Yunqian; Song, Hongqing; Huang, Kun

2018-02-01

This paper provides an experimental method to deal with the problems of low oil recovery ratio faced with water flooding utilizing the CO2/water alternate displacement technology. A series of CO2/water alternate flooding experiments were carried out under 60°C and 18.4MPa using high temperature / pressure microscopic visualization simulation system. Then, we used the image processing technique and software to analyze the proportion of remaining oil in the displacement process. The results show that CO2 can extract the lighter chemical components in the crude oil and make it easier to form miscible phase, which can reduce the viscosity and favorable mobility ratio of oil. What’s more, the displacement reduces the impact of gas channeling, which can achieve an enlarged sweeping efficiency to improve filtration ability. In addition, the CO2 dissolved in oil and water can greatly reduce the interfacial tension, which can increase the oil displacement efficiency in a large extent. Generally speaking, the recovery rate of residual oil in the micro - model can be elevated up to 15.89% ∼ 16.48% under formation condition by alternate displacement.

CO2 Huff-n-Puff Process in a Light Oil Shallow Shelf Carbonate Reservoir

Energy Technology Data Exchange (ETDEWEB)

Boomer, R.J.; Cole, R.; Kovar, M.; Prieditis, J.; Vogt, J.; Wehner, S.

1999-02-24

The application cyclic CO2, often referred to as the CO2 Huff-n-Puff process, may find its niche in the maturing waterfloods of the Permian Basin. Coupling the CO2 Huff-n-Puff process to miscible flooding applications could provide the needed revenue to sufficiently mitigate near-term negative cash flow concerns in capital-intensive miscible projects. Texaco Exploration and Production Inc. and the US Department of Energy have teamed up in a attempt to develop the CO2 Huff-n-Puff process in the Grayburg and San Andres formations which are light oil, shallow shelf carbonate reservoirs that exist throughout the Permian Basin. This cost-shared effort is intended to demonstrate the viability of this underutilized technology in a specific class of domestic reservoir.

Going beyond the flood insurance rate map: insights from flood hazard map co-production

Science.gov (United States)

Luke, Adam; Sanders, Brett F.; Goodrich, Kristen A.; Feldman, David L.; Boudreau, Danielle; Eguiarte, Ana; Serrano, Kimberly; Reyes, Abigail; Schubert, Jochen E.; AghaKouchak, Amir; Basolo, Victoria; Matthew, Richard A.

2018-04-01

Flood hazard mapping in the United States (US) is deeply tied to the National Flood Insurance Program (NFIP). Consequently, publicly available flood maps provide essential information for insurance purposes, but they do not necessarily provide relevant information for non-insurance aspects of flood risk management (FRM) such as public education and emergency planning. Recent calls for flood hazard maps that support a wider variety of FRM tasks highlight the need to deepen our understanding about the factors that make flood maps useful and understandable for local end users. In this study, social scientists and engineers explore opportunities for improving the utility and relevance of flood hazard maps through the co-production of maps responsive to end users' FRM needs. Specifically, two-dimensional flood modeling produced a set of baseline hazard maps for stakeholders of the Tijuana River valley, US, and Los Laureles Canyon in Tijuana, Mexico. Focus groups with natural resource managers, city planners, emergency managers, academia, non-profit, and community leaders refined the baseline hazard maps by triggering additional modeling scenarios and map revisions. Several important end user preferences emerged, such as (1) legends that frame flood intensity both qualitatively and quantitatively, and (2) flood scenario descriptions that report flood magnitude in terms of rainfall, streamflow, and its relation to an historic event. Regarding desired hazard map content, end users' requests revealed general consistency with mapping needs reported in European studies and guidelines published in Australia. However, requested map content that is not commonly produced included (1) standing water depths following the flood, (2) the erosive potential of flowing water, and (3) pluvial flood hazards, or flooding caused directly by rainfall. We conclude that the relevance and utility of commonly produced flood hazard maps can be most improved by illustrating pluvial flood hazards

The new management policy: Indonesian PSC-Gross split applied on CO2 flooding project

Science.gov (United States)

Irham, S.; Sibuea, S. N.; Danu, A.

2018-01-01

“SIAD” oil field will be developed by CO2 flooding. CO2, a famous pollutant gas, is injected into the oil reservoir to optimize the oil recovery. This technique should be conducted economically according to the energy management policy in Indonesia. In general, Indonesia has two policy contracts on oil and gas: the old one is PSC-Cost-Recovery, and the new one is PSC-Gross-Split (introduced in 2017 as the new energy management plan). The contractor must choose between PSC-Cost-Recovery and PSC-Gross-Split which makes more profit. The aim of this paper is to show the best oil and gas contract policy for the contractor. The methods are calculating and comparing the economic indicators. The result of this study are (1) NPV for the PSC-Cost-Recovery is -46 MUS, while for the PSC-Gross-Split is 73 MUS, and (2) IRR for the PSC-Cost-Recovery is 9%, whereas for the PSC-Gross-Split is 11%. The conclusion is that the NPV and IRR for PSC-Gross-Split are greater than the NPV and IRR of PSC-Cost-Recovery, but POT in PSC-Gross-split is longer than POT in PSC-Cost-Recovery. Thus, in this case, the new energy policy contract can be applied for CO2 flooding technology since it yields higher economic indicators than its antecendent.

Attributing Increased River Flooding in the Future: Hydrodynamic Downscaling Reveals Role of Plant Physiological Responses to Increased CO2 is First Order

Science.gov (United States)

Fowler, M. D.; Kooperman, G. J.; Pritchard, M. S.; Randerson, J. T.

2017-12-01

River flooding events, which are the most frequently occurring natural disaster today, are expected to become more frequent and intense in response to climate change. However, the magnitude of these changes remains debated, in part due to uncertainty in our understanding of the physical processes that contribute to these events and their representation in global climate models. While the intensification of precipitation has been shown to be a primary driver of increased flooding, plant physiological responses to increasing CO2 may also play an important role. As the atmospheric concentration of CO2 increases, plants may respond by reducing the width of their stomata (i.e. stomatal conductance), which can decrease water lost through transpiration and in turn maintain higher soil moisture levels. On long timescales, reduced transpiration has been shown to increase average runoff, but on short timescales elevated soil moisture can also increase instantaneous runoff by limiting the rate at which water is able to infiltrate the soil surface. Here, through hydrodynamic downscaling, we isolate the portion of flooding amplification that can be attributed to the physiological response to increasing CO2. This builds on a new analysis that has revealed such physiological effects can rival changes caused by the atmospheric response alone in the tails of the runoff distribution. We use a set of four simulations run with the Community Earth System Model: one pre-industrial control simulation and three others that are forced with four times CO2. In the three climate change simulations, the increased CO2 is applied only to the land-surface, only to the atmosphere, and to both, respectively. Thirty years of daily runoff from these experiments are used as input for the hydrodynamic CaMa-Flood model. Our results reveal that both the radiative and physiological responses to climate change contribute significantly to future changes in flood return period and inundated area. This

Ascorbic acid as a bifunctional hydrogen bond donor for the synthesis of cyclic carbonates from CO2 under ambient conditions

KAUST Repository

Arayachukiat, Sunatda; Kongtes, Chutima; Barthel, Alexander; Vummaleti, Sai V. C.; Poater, Albert; Wannakao, Sippakorn; Cavallo, Luigi; D'Elia, Valerio

2017-01-01

Readily available ascorbic acid was discovered as an environmentally benign hydrogen bond donor (HBD) for the synthe-sis of cyclic organic carbonates from CO2 and epoxides in the presence of nucleophilic co-catalysts. The ascorbic acid/TBAI (TBAI: tetrabutylammonium iodide) binary system could be applied for the cycloaddition of CO2 to various epoxides under ambient or mild conditions. DFT calculations and catalysis experiments revealed an intriguing bifunctional mechanism in the step of CO2 insertion involving different hydroxyl moieties (enediol, ethyldiol) of the ascorbic acid scaffold.

Ascorbic acid as a bifunctional hydrogen bond donor for the synthesis of cyclic carbonates from CO2 under ambient conditions

KAUST Repository

Arayachukiat, Sunatda

2017-07-14

Readily available ascorbic acid was discovered as an environmentally benign hydrogen bond donor (HBD) for the synthe-sis of cyclic organic carbonates from CO2 and epoxides in the presence of nucleophilic co-catalysts. The ascorbic acid/TBAI (TBAI: tetrabutylammonium iodide) binary system could be applied for the cycloaddition of CO2 to various epoxides under ambient or mild conditions. DFT calculations and catalysis experiments revealed an intriguing bifunctional mechanism in the step of CO2 insertion involving different hydroxyl moieties (enediol, ethyldiol) of the ascorbic acid scaffold.

Investigation of water and CO2 (carbon dioxide) flooding using micro-CT (micro-computed tomography) images of Berea sandstone core using finite element simulations

International Nuclear Information System (INIS)

Gunde, Akshay C.; Bera, Bijoyendra; Mitra, Sushanta K.

2010-01-01

The present study reports a numerical investigation of water and CO 2 (carbon dioxide) flooding at the pore scale of a porous medium. We use high resolution micro-computed tomography (micro-CT) images of Berea sandstone core to obtain the pore geometry. The numerical solution used for the simulation was carried out by a finite element based software package. Level Set method is used to determine the position of the interface between two immiscible fluids when oil is displaced by water and CO 2 , respectively. The present formulation is validated against single-phase flow through the porous structure. It is found that, fluid flow inside the pore space takes place through preferential inlet and outlet pores. For two-phase flow, it is observed that continuous displacement of oil occurs during water flooding but CO 2 is able to displace oil at certain locations in the pores. Also, the separation of flow front is observed in the case of CO 2 flooding. A quantitative comparison of the results obtained in two types of flooding simulations suggests that water displaces a higher volume of oil than CO 2 in the time period for which the simulations are performed.

Going beyond the flood insurance rate map: insights from flood hazard map co-production

Directory of Open Access Journals (Sweden)

A. Luke

2018-04-01

Full Text Available Flood hazard mapping in the United States (US is deeply tied to the National Flood Insurance Program (NFIP. Consequently, publicly available flood maps provide essential information for insurance purposes, but they do not necessarily provide relevant information for non-insurance aspects of flood risk management (FRM such as public education and emergency planning. Recent calls for flood hazard maps that support a wider variety of FRM tasks highlight the need to deepen our understanding about the factors that make flood maps useful and understandable for local end users. In this study, social scientists and engineers explore opportunities for improving the utility and relevance of flood hazard maps through the co-production of maps responsive to end users' FRM needs. Specifically, two-dimensional flood modeling produced a set of baseline hazard maps for stakeholders of the Tijuana River valley, US, and Los Laureles Canyon in Tijuana, Mexico. Focus groups with natural resource managers, city planners, emergency managers, academia, non-profit, and community leaders refined the baseline hazard maps by triggering additional modeling scenarios and map revisions. Several important end user preferences emerged, such as (1 legends that frame flood intensity both qualitatively and quantitatively, and (2 flood scenario descriptions that report flood magnitude in terms of rainfall, streamflow, and its relation to an historic event. Regarding desired hazard map content, end users' requests revealed general consistency with mapping needs reported in European studies and guidelines published in Australia. However, requested map content that is not commonly produced included (1 standing water depths following the flood, (2 the erosive potential of flowing water, and (3 pluvial flood hazards, or flooding caused directly by rainfall. We conclude that the relevance and utility of commonly produced flood hazard maps can be most improved by illustrating

Water, energy and CO2 exchange over a seasonally flooded forest in the Sahel.

Science.gov (United States)

Kergoat, L.; Le Dantec, V.; Timouk, F.; Hiernaux, P.; Mougin, E.; Manuela, G.; Diawara, M.

2014-12-01

In semi-arid areas like the Sahel, perennial water bodies and temporary-flooded lowlands are critical for a number of activities. In some cases, their existence is simply a necessary condition for human societies to establish. They also play an important role in the water and carbon cycle and have strong ecological values. As a result of the strong multi-decadal drought that impacted the Sahel in the 70' to 90', a paradoxical increase of ponds and surface runoff has been observed ("Less rain, more water in the ponds", Gardelle 2010). In spite of this, there are excessively few data documenting the consequence of such a paradox on the water and carbon cycle. Here we present 2 years of eddy covariance data collected over the Kelma flooded Acacia forest in the Sahel (15.50 °N), in the frame of the AMMA project. The flooded forest is compared to the other major component of this Sahelian landscape: a grassland and a rocky outcrop sites. All sites are involved in the ALMIP2 data/LSM model comparison. The seasonal cycle of the flooded forest strongly departs from the surroundings grassland and bare soil sites. Before the rain season, the forest displays the strongest net radiation and sensible heat flux. Air temperature within the canopy reaches extremely high values. During the flood, it turns to the lowest sensible heat flux. In fact, due to an oasis effect, this flux is negative during the late flood. Water fluxes turn from almost zero in the dry season to strong evaporation during the flood, since it uses additional energy provided by negative sensible heat flux. The eddy covariance fluxes are consistent with sap flow data, showing that the flood greatly increases the length of the growing season. CO2 fluxes over the forest were twice as large as over the grassland, and the growing season was also longer, giving a much larger annual photosynthesis. In view of these data and data over surroundings grasslands and bare soil, as well as data from a long-term ecological

Calcium looping technology using improved stability nanostructured sorbent for cyclic CO{sub 2} capture

Energy Technology Data Exchange (ETDEWEB)

Luo, Cong; Zheng, Ying; Ding, Ning; Zheng, Chu-guang [Huazhong Univ. of Science and Technology, Wuhan (China). State Key Lab. of Coal Combustion

2013-07-01

One of the post-combustion CO{sub 2} capture technologies that have sufficiently been proved to be the best candidates for practical large scale post-combustion application is the calcium looping cycle. However, the CO{sub 2} capture capacity of a calcium-based sorbent derived from natural limestone decays through long-term cyclic utilization; thus, the development of novel sorbents to achieve a high CO{sub 2} capture capacity is an critical challenge for the calcium looping cycle technology. In this paper, we report the preparation and character of a new calcium-based sorbent produced via the combustion of a dry gel. The results show that the novel calcium-based sorbent has a much higher residual carbonation conversion as well as a better performance of anti-sintering when compared with the calcium-based sorbent derived from commercial micrometer grade CaCO{sub 3} and nanometer grade CaCO{sub 3}. It is reasonable to propose that the different final carbonation performances are induced by their different pore structures and BET surface areas rather than by different particle sizes. Compared with the commercial nano CaO, the morphology of the new sorbent shows a more rough porous appearance with hollow nanostructure. During carbonation, CO{sub 2} diffused more easily through the hollow structure than through a solid structure to reach the unreacted CaO. Besides, there is less chance for the hollow nanostructured particles to be merged together during the high temperature reactions.

A New Role for CO2: Controlling Agent of the Anionic Ring-Opening Polymerization of Cyclic Esters

KAUST Repository

Varghese, Jobi K.

2017-08-15

Conventional anionic ring-opening of polymerization (AROP) of cyclic esters suffers from the nonselective and concomitant attack of the monomer and of the polymer chains by the growing active species, which results in polyester samples with uncontrolled molar masses and broad polydispersity due to the competition between propagation and transesterification reactions. In this report, we describe a new AROP system mediated by a controlled amount of CO2 which prevents transesterification reactions from occurring. Using lithium monomethyl diethylene glycoxide (MEEOLi) as initiator and 1.5 equiv of CO2, ε-caprolactone could be polymerized under truly “living” conditions in dichloromethane (DCM) at 70 °C, as evidenced by the control of molar masses, the narrow polydispersity indexes (Mn up to ∼40 kg/mol, Đ < 1.16), and also successful chain extension experiments. Lithium carbonate used as initiator in the presence of 0.5 equiv of CO2 afforded similar polymerization results. Experiments carried out with other alkoxide salts and solvents demonstrate that CO2 is indispensable as well as lithium and noncoordinating solvents for the suppression of transesterifications. A similar strategy was applied for the AROP of l-lactide (LLA). At −20 °C, LLA could be polymerized under living conditions with undetectable level of transesterification as demonstrated by MALDI-ToF analysis. To account for the polymerization mechanism occurring in the presence of a slight excess of CO2, we resorted to computational studies. It appears that a fast equilibrium takes place between two tetrameric aggregates, one dormant comprising four carbonates (RCO3Li)4, and an active one involving three carbonates and one alkoxide (RCO3Li)3(ROLi). The latter is shown to selectively ring-open cyclic ester without indulging in transesterifications like (ROLi)4 precursors.

A New Role for CO2: Controlling Agent of the Anionic Ring-Opening Polymerization of Cyclic Esters

KAUST Repository

Varghese, Jobi K.; Goncalves, Theo; Huang, Kuo-Wei; Hadjichristidis, Nikolaos; Gnanou, Yves; Feng, Xiaoshuang

2017-01-01

Conventional anionic ring-opening of polymerization (AROP) of cyclic esters suffers from the nonselective and concomitant attack of the monomer and of the polymer chains by the growing active species, which results in polyester samples with uncontrolled molar masses and broad polydispersity due to the competition between propagation and transesterification reactions. In this report, we describe a new AROP system mediated by a controlled amount of CO2 which prevents transesterification reactions from occurring. Using lithium monomethyl diethylene glycoxide (MEEOLi) as initiator and 1.5 equiv of CO2, ε-caprolactone could be polymerized under truly “living” conditions in dichloromethane (DCM) at 70 °C, as evidenced by the control of molar masses, the narrow polydispersity indexes (Mn up to ∼40 kg/mol, Đ < 1.16), and also successful chain extension experiments. Lithium carbonate used as initiator in the presence of 0.5 equiv of CO2 afforded similar polymerization results. Experiments carried out with other alkoxide salts and solvents demonstrate that CO2 is indispensable as well as lithium and noncoordinating solvents for the suppression of transesterifications. A similar strategy was applied for the AROP of l-lactide (LLA). At −20 °C, LLA could be polymerized under living conditions with undetectable level of transesterification as demonstrated by MALDI-ToF analysis. To account for the polymerization mechanism occurring in the presence of a slight excess of CO2, we resorted to computational studies. It appears that a fast equilibrium takes place between two tetrameric aggregates, one dormant comprising four carbonates (RCO3Li)4, and an active one involving three carbonates and one alkoxide (RCO3Li)3(ROLi). The latter is shown to selectively ring-open cyclic ester without indulging in transesterifications like (ROLi)4 precursors.

Metal–organic framework-based catalysts: Chemical fixation of CO2 with epoxides leading to cyclic organic carbonates

Directory of Open Access Journals (Sweden)

M. Hassan eBeyzavi

2015-01-01

Full Text Available As a C1 feedstock, CO2 has the potential to be uniquely highly economical in both a chemical and a financial sense. In particular, the highly atom-economical acid-catalyzed cycloaddition of CO2 to epoxides to yield cyclic organic carbonates (OCs, a functionality having many important industrial applications, is an attractive reaction for the utilization of CO2 as a chemical feedstock. Metal–organic frameworks (MOFs are promising candidates in catalysis as they are a class of crystalline, porous and functional materials with remarkable properties including great surface area, high stability, open channels and permanent porosity. MOFs structure tunability and their affinity for CO2, makes them great catalysts for the formation of OCs using CO2 and epoxides. In this review, we examine MOF-based catalytic materials for the cycloaddition of carbon dioxide to epoxides. Catalysts are grouped based on the location of catalytic sites, i.e., at the struts, nodes, defect sites, or some combination thereof. Additionally, important features of each catalyst system are critically discussed.

Design and Implementation of a CO2 Flood Utilizing Advanced Reservoir Characterization and Horizontal Injection Wells In a Shallow Shelf Carbonate Approaching Waterflood Depletion, Class II; ANNUAL

International Nuclear Information System (INIS)

Czirr, K.L.; Gaddis, M.P.; Moshell, M.K.

2002-01-01

The principle objective of this project is to demonstrate the economic viability and widespread applicability of an innovative reservoir management and carbon dioxide (CO2) flood project development approach for improving CO2 flood project economics in shallow shelf carbonate (SSC) reservoirs

Future flood risk in the tropics as measured by changes in extreme runoff intensity is strongly influenced by plant-physiological responses to rising CO2

Science.gov (United States)

Kooperman, G. J.; Hoffman, F. M.; Koven, C.; Lindsay, K. T.; Swann, A. L. S.; Randerson, J. T.

2017-12-01

Climate change is expected to increase the frequency of intense flooding events, and thus the risk of flood-related mortality, infrastructure damage, and economic loss. Assessments of future flooding from global climate models based only on precipitation intensity and temperature neglect important processes that occur within the land-surface, particularly the impacts of plant-physiological responses to rising CO2. Higher CO2 reduces stomatal conductance, leading to less water loss through transpiration and higher soil moisture. For a given precipitation rate, higher soil moisture decreases the amount of rainwater that infiltrates the surface and increases runoff. Here we assess the relative impacts of plant-physiological and radiative-greenhouse effects on changes in extreme runoff intensity over tropical continents using the Community Earth System Model. We find that extreme percentile rates increase significantly more than mean runoff in response to higher CO2. Plant-physiological effects contribute to only a small increase in precipitation intensity, but are a dominant driver of runoff intensification, contributing to one-half of the 99th percentile runoff intensity change and one-third of the 99.9th percentile change. Comprehensive assessments of future flooding risk need to account for the physiological as well as radiative impacts of CO2 in order to better inform flood prediction and mitigation practices.

Determining CO2 storage potential during miscible CO2 enhanced oil recovery: Noble gas and stable isotope tracers

Science.gov (United States)

Shelton, Jenna L.; McIntosh, Jennifer C.; Hunt, Andrew; Beebe, Thomas L; Parker, Andrew D; Warwick, Peter D.; Drake, Ronald; McCray, John E.

2016-01-01

Rising atmospheric carbon dioxide (CO2) concentrations are fueling anthropogenic climate change. Geologic sequestration of anthropogenic CO2 in depleted oil reservoirs is one option for reducing CO2 emissions to the atmosphere while enhancing oil recovery. In order to evaluate the feasibility of using enhanced oil recovery (EOR) sites in the United States for permanent CO2 storage, an active multi-stage miscible CO2flooding project in the Permian Basin (North Ward Estes Field, near Wickett, Texas) was investigated. In addition, two major natural CO2 reservoirs in the southeastern Paradox Basin (McElmo Dome and Doe Canyon) were also investigated as they provide CO2 for EOR operations in the Permian Basin. Produced gas and water were collected from three different CO2 flooding phases (with different start dates) within the North Ward Estes Field to evaluate possible CO2 storage mechanisms and amounts of total CO2retention. McElmo Dome and Doe Canyon were sampled for produced gas to determine the noble gas and stable isotope signature of the original injected EOR gas and to confirm the source of this naturally-occurring CO2. As expected, the natural CO2produced from McElmo Dome and Doe Canyon is a mix of mantle and crustal sources. When comparing CO2 injection and production rates for the CO2 floods in the North Ward Estes Field, it appears that CO2 retention in the reservoir decreased over the course of the three injections, retaining 39%, 49% and 61% of the injected CO2 for the 2008, 2010, and 2013 projects, respectively, characteristic of maturing CO2 miscible flood projects. Noble gas isotopic composition of the injected and produced gas for the flood projects suggest no active fractionation, while δ13CCO2 values suggest no active CO2dissolution into formation water, or mineralization. CO2 volumes capable of dissolving in residual formation fluids were also estimated along with the potential to store pure-phase supercritical CO2. Using a combination

Evaluating the purity of a (57)Co flood source by PET.

Science.gov (United States)

DiFilippo, Frank P

2014-11-01

Flood sources of (57)Co are commonly used for quality control of gamma cameras. Flood uniformity may be affected by the contaminants (56)Co and (58)Co, which emit higher energy photons. Although vendors specify a maximum combined (56)Co and (58)Co activity, a convenient test for flood source purity that is feasible in a clinical environment would be desirable. Both (56)Co and (58)Co emit positrons with branching 19.6% and 14.9%, respectively. As is known from (90)Y imaging, a positron emission tomography (PET) scanner is capable of quantitatively imaging very weak positron emission in a high single-photon background. To evaluate this approach, two (57)Co flood sources were scanned with a clinical PET/CT multiple times over a period of months. The (56)Co and (58)Co activity was clearly visible in the reconstructed PET images. Total impurity activity was quantified from the PET images after background subtraction of prompt gamma coincidences. Time-of-flight PET reconstruction was highly beneficial for accurate image quantification. Repeated measurements of the positron-emitting impurities showed excellent agreement with an exponential decay model. For both flood sources studied, the fit parameters indicated a zero intercept and a decay half-life consistent with a mixture of (56)Co and (58)Co. The total impurity activity at the reference date was estimated to be 0.06% and 0.07% for the two sources, which was consistent with the vendor's specification of <0.12%. The robustness of the repeated measurements and a thorough analysis of the detector corrections and physics suggest that the accuracy is acceptable and that the technique is feasible. Further work is needed to validate the accuracy of this technique with a calibrated high resolution gamma spectrometer as a gold standard, which was not available for this study, and for other PET detector models.

Large CO2 and CH4 release from a flooded formerly drained fen

Science.gov (United States)

Sachs, T.; Franz, D.; Koebsch, F.; Larmanou, E.; Augustin, J.

2016-12-01

Drained peatlands are usually strong carbon dioxide (CO2) sources. In Germany, up to 4.5 % of the national CO2 emissions are estimated to be released from agriculturally used peatlands and for some peatland-rich northern states, such as Mecklenburg-Western Pomerania, this share increases to about 20%. Reducing this CO2 source and restoring the peatlands' natural carbon sink is one objective of large-scale nature protection and restoration measures, in which 37.000 ha of drained and degraded peatlands in Mecklenburg-Western Pomerania are slated for rewetting. It is well known, however, that in the initial phase of rewetting, a reduction of the CO2 source strength is usually accompanied by an increase in CH4 emissions. Thus, whether and when the intended effects of rewetting with regard to greenhouse gases are achieved, depends on the balance of CO2 and CH4 fluxes and on the duration of the initial CH4 emission phase. In 2013, a new Fluxnet site went online at a flooded formerly drained river valley fen site near Zarnekow, NE Germany (DE-Zrk), to investigate the combined CO2 and CH4 dynamics at such a heavily degraded and rewetted peatland. The site is dominated by open water with submerged and floating vegetation and surrounding Typha latifolia.Nine year after rewetting, we found large CH4 emissions of 53 g CH4 m-2 a-1 from the open water area, which are 4-fold higher than from the surrounding vegetation zone (13 g CH4 m-2 a-1). Surprisingly, both the open water and the vegetated area were net CO2 sources of 158 and 750 g CO2 m-2 a-1, respectively. Unusual meteorological conditions with a warm and dry summer and a mild winter might have facilitated high respiration rates, particularly from temporally non-inundated organic mud in the vegetation zone.

Potential Mississippi oil recovery and economic impact from CO2 miscible flooding

International Nuclear Information System (INIS)

Moring, J.A.; Rogers, R.E.

1991-01-01

Maturing of Mississippi oil reservoirs has resulted in a steady decline in crude oil production in the state. This paper reports that, to evaluate the potential of enhanced recovery processes, particularly in the use of the state's large CO 2 reserves, for arresting this trend, the subject study was performed. A computer data base of over 1315 Mississippi reservoirs was established. All reservoirs were screened for applicability of the carbon dioxide miscible process. With models developed by the National Petroleum Council and DOE, incremental oil that could be produced from the carbon dioxide miscible process was calculated. Under selected economic conditions, carbon dioxide miscible flooding with utilization of carbon dioxide from the state's Norphlet formation (3-7 tcf reserves of high-purity CO 2 ) could produce 120 million barrels of incremental oil in Mississippi. Incremental state revenues as a consequence of this production were calculated to be $45 million of severance taxes, $50 million of corporate income taxes, and $60 million of royalty payments, expressed as present values

CO 2 as versatile carbonation agent of glycosides: Synthesis of 5- and 6-membered cyclic glycocarbonates and investigation of their ring-opening

KAUST Repository

Pati, Debasis

2018-03-15

This study demonstrates the successful use of CO as versatile carbonation agent for the synthesis of 5-membered and 6-membered bicyclic glycocarbonates from methyl α-d-mannopyranoside (MDM) and methyl α-d-galactopyranoside (MDG). On the one hand, these two sugars were cyclized into 5-membered glycocarbonates by mere reaction of CO with their hydroxyls either at cis-2,3 or cis-3,4 positions and without resorting to phosgene or its derivatives. The reactivity of the obtained 5-membered cyclic glycocarbonates were further tested with hexyl- and dodecyl amine. The self-assembling behavior of the formed alkyl glycosides in water was investigated and characterized by transmission electron microscope (TEM). On the other hand, secondary hydroxyls at 2- and 3- positions in MDM and MDG were first protected by a ketal group and by two ether, respectively before subjecting their respective 6-position hydroxyl to bromination. Their respective 6-bromo and 4-hydroxyl functions were subsequently reacted in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) and CO. The resulting 6-membered cyclic glycocarbonates were then polymerized using 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) or DBU as organocatalyst. All the synthesized 5- and 6-membered cyclic glycocarbonates and polyglycocarbonates were thoroughly characterized by FT-IR, H, C NMR and MALDI-ToF and Gel Permeation Chromatography (GPC).

The U.S. Gas Flooding Experience: CO2 Injection Strategies and Impact on Ultimate Recovery

Energy Technology Data Exchange (ETDEWEB)

Nunez-Lopez, Vanessa [The University of Texas at Austin; Hosseini, Seyyed; Gil-Egui, Ramon

2017-09-29

The Permian Basin in West Texas and southwestern New Mexico has seen 45 years of oil reserve growth through CO2 enhanced oil recovery (CO2 EOR). More than 60 CO2 EOR projects are currently active in the region’s limestone, sandstone and dolomite reservoirs. Water alternating gas (WAG) has been the development strategy of choice in the Permian for several technical and economic reasons. More recently, the technology started to get implemented in the much more porous and permeable clastic depositional systems of the onshore U.S. Gulf Coast. Continued CO2 injection (CGI), as opposed to WAG, was selected as the injection strategy to develop Gulf Coast oil fields, where CO2 injection volumes are significantly larger (up to 6 times larger) than those of the Permian. We conducted a compositional simulation based study with the objective of comparing the CO2 utilization ratios (volume of CO2 injected to produce a barrel of oil) of 4 conventional and novel CO2 injection strategies: (1) continuous gas injection (CGI), (2) water alternating gas (WAG), (3) water curtain injection (WCI), and (4) WAG and WCI combination. These injection scenarios were simulated using the GEM module from the Computer Modeling Group (CMG). GEM is an advanced general equation-of-state compositional simulator, which includes equation of state, CO2 miscible flood, CO2/brine interactions, and complex phase behavior. The simulator is set up to model three fluid phases including water, oil, and gas. Our study demonstrates how the selected field development strategy has a significant impact on the ultimate recovery of CO2-EOR projects, with GCI injection providing maximum oil recovery in absolute volume terms, but with WAG offering a more balanced technical-economical approach.

Inexpensive CO2 Thickening Agents for Improved Mobility Control of CO2 Floods

Energy Technology Data Exchange (ETDEWEB)

Robert Enick; Eric Beckman; Andrew Hamilton

2005-08-31

The objective of this research was the design, synthesis and evaluation of inexpensive, non-fluorous carbon dioxide thickening agents. We followed the same strategy employed in the design of fluorinated CO{sub 2} polymeric thickeners. First, a highly CO{sub 2}-philic, hydrocarbon-based monomer was to be identified. Polymers or oligomers of this monomer were then synthesized. The second step was to design a CO{sub 2}-thickener based on these CO{sub 2}-philic polymers. Two types of thickeners were considered. The first was a copolymer in which the CO{sub 2}-philic monomer was combined with a small proportion of CO{sub 2}-phobic associating groups that could cause viscosity-enhancing intermolecular interactions to occur. The second was a small hydrogen-bonding compound with urea groups in the core to promote intermolecular interactions that would cause the molecules to 'stack' in solution while the arms were composed of the CO{sub 2}-philic oligomers. Although we were not able to develop a viable thickener that exhibited high enough CO{sub 2} solubility at EOR MMP conditions to induce a viscosity increase, we made significant progress in our understanding of CO{sub 2}-soluble compounds that can be used in subsequent studies to design CO{sub 2}-soluble thickeners or CO{sub 2}-soluble surfactant-based foaming agents. These findings are detailed in this final report. In summary, we assessed many polymers and verified that the most CO{sub 2}-soluble oxygenated hydrocarbon polymer is poly(vinyl acetate), PVAc. This is primarily due to the presence of both ether and carbonyl oxygens associated with acetate-rich compounds. In addition to polymers, we also made small acetate-rich molecules that were also capable of associating in solution via the inclusion of hydrogen-bonding groups in hopes of forming viscosity-enhancing macromolecules. Despite the presence of multiple acetate groups in these compounds, which can impart incredible CO{sub 2}-solubility to many

Has the magnitude of floods across the USA changed with global CO2 levels?

Science.gov (United States)

Hirsch, Robert M.; Ryberg, Karen R.

2012-01-01

Statistical relationships between annual floods at 200 long-term (85–127 years of record) streamgauges in the coterminous United States and the global mean carbon dioxide concentration (GMCO2) record are explored. The streamgauge locations are limited to those with little or no regulation or urban development. The coterminous US is divided into four large regions and stationary bootstrapping is used to evaluate if the patterns of these statistical associations are significantly different from what would be expected under the null hypothesis that flood magnitudes are independent of GMCO2. In none of the four regions defined in this study is there strong statistical evidence for flood magnitudes increasing with increasing GMCO2. One region, the southwest, showed a statistically significant negative relationship between GMCO2 and flood magnitudes. The statistical methods applied compensate both for the inter-site correlation of flood magnitudes and the shorter-term (up to a few decades) serial correlation of floods.

Oxidation of cyclic amines by molybdenum(II and tungsten(II halocarbonyls, [M(CO4X2]2 (M = Mo, W; X = Cl, Br

Directory of Open Access Journals (Sweden)

H.M. Mbuvi

2013-05-01

Full Text Available The molybdenum(II and tungsten(II halocarbonyls, [M(CO4X2]2 (M = Mo, W; X = Cl, Br react with a large excess of the nitrogen bases, 1-methylpyrrolidine, 1-methylpiperidine, 1-ethylpiperidine and 2-ethylpiperidine to give aminecarbonyl complexes of the type M(CO3L3 (L= alkylamine. Excess piperidine reacts with the tungsten halocarbonyls, [W(CO4X2]2 (X = Cl, Br, to give the trans isomer of the complex, W(CO3(C5H11N3. The halogens were recovered as the amminium salts, amine, HX. The oxidized amine dimerized to form a yellow product which was recovered as an oily liquid but in very small amounts. However, in the reaction between Mo(CO4Br2 and 1-ethylpiperidine, a yellow crystalline solid, with a melting point of 224 oC was recovered in sufficient amounts for elemental analysis, melting point and spectral data. Its mass spectrum showed a molecular ion peak at m+/z = 222, a clear evidence that the oxidized amine dimerizes. The cyclic dibasic amine piperazine, C4H10N2 is not, however, oxidized by these halocarbonyls but rather it reacts by substituting some CO groups to form products of the type, M(CO3(C4H10N22X2 (M = Mo, W; X = Cl, Br. Products were characterized by elemental analysis, IR, UV, 1H NMR and mass spectrometry.

Optimization of CO2 adsorption capacity and cyclical adsorption/desorption on tetraethylenepentamine-supported surface-modified hydrotalcite.

Science.gov (United States)

Thouchprasitchai, Nutthavich; Pintuyothin, Nuthapol; Pongstabodee, Sangobtip

2018-03-01

The objective of this research was to investigate CO 2 adsorption capacity of tetraethylenepentamine-functionalized basic-modified calcined hydrotalcite (TEPA/b-cHT) sorbents at atmospheric pressure formed under varying TEPA loading levels, temperatures, sorbent weight to total gaseous flow rate (W/F) ratios and CO 2 concentrations in the influent gas. The TEPA/b-cHT sorbents were characterized by means of X-ray diffraction (XRD), Fourier transform infrared spectrometry (FT-IR), thermal gravimetric analysis (TGA), Brunauer-Emmet-Teller (BET) analysis of nitrogen (N 2 ) adsorption/desorption and carbon-hydrogen-nitrogen (CHN) elemental analysis. Moreover, a full 2 4 factorial design with three central points at a 95% confidence interval was used to screen important factor(s) on the CO 2 adsorption capacity. It revealed that 85.0% variation in the capacity came from the influence of four main factors and the 15.0% one was from their interactions. A face-centered central composite design response surface method (FCCCD-RSM) was then employed to optimize the condition, the maximal capacity of 5.5-6.1mmol/g was achieved when operating with a TEPA loading level of 39%-49% (W/W), temperature of 76-90°C, W/F ratio of 1.7-2.60(g·sec)/cm 3 and CO 2 concentration of 27%-41% (V/V). The model fitted sufficiently the experimental data with an error range of ±1.5%. From cyclical adsorption/desorption and selectivity at the optimal condition, the 40%TEPA/b-cHT still expressed its effective performance after eight cycles. Copyright © 2017. Published by Elsevier B.V.

How much CO2 is trapped in carbonate minerals of a natural CO2 occurrence?

Science.gov (United States)

Király, Csilla; Szabó, Zsuzsanna; Szamosfalvi, Ágnes; Cseresznyés, Dóra; Király, Edit; Szabó, Csaba; Falus, György

2017-04-01

Carbon Capture and Storage (CCS) is a transitional technology to decrease CO2 emissions from human fossil fuel usage and, therefore, to mitigate climate change. The most important criteria of a CO2 geological storage reservoir is that it must hold the injected CO2 for geological time scales without its significant seepage. The injected CO2 undergoes physical and chemical reactions in the reservoir rocks such as structural-stratigraphic, residual, dissolution or mineral trapping mechanisms. Among these, the safest is the mineral trapping, when carbonate minerals such as calcite, ankerite, siderite, dolomite and dawsonite build the CO2 into their crystal structures. The study of natural CO2 occurrences may help to understand the processes in CO2 reservoirs on geological time scales. This is the reason why the selected, the Mihályi-Répcelak natural CO2 occurrence as our research area, which is able to provide particular and highly significant information for the future of CO2 storage. The area is one of the best known CO2 fields in Central Europe. The main aim of this study is to estimate the amount of CO2 trapped in the mineral phase at Mihályi-Répcelak CO2 reservoirs. For gaining the suitable data, we apply petrographic, major and trace element (microprobe and LA-ICP-MS) and stable isotope analysis (mass spectrometry) and thermodynamic and kinetic geochemical models coded in PHREEQC. Rock and pore water compositions of the same formation, representing the pre-CO2 flooding stages of the Mihályi-Répcelak natural CO2 reservoirs are used in the models. Kinetic rate parameters are derived from the USGS report of Palandri and Kharaka (2004). The results of petrographic analysis show that a significant amount of dawsonite (NaAlCO3(OH)2, max. 16 m/m%) precipitated in the rock due to its reactions with CO2 which flooded the reservoir. This carbonate mineral alone traps about 10-30 kg/m3 of the reservoir rock from the CO2 at Mihályi-Répcelak area, which is an

Post Waterflood CO2 Miscible Flood in Light Oil, Fluvial-Dominated Deltaic Reservoir (Pre-Work and Project Proposal - Appendix)

Energy Technology Data Exchange (ETDEWEB)

Bou-Mikael, Sami

2002-02-05

The main objective of the Port Neches Project was to determine the feasibility and producibility of CO2 miscible flooding techniques enhanced with horizontal drilling applied to a Fluvial Dominated Deltaic reservoir. The second was to disseminate the knowledge gained through established Technology Transfer mechanisms to support DOE's programmatic objectives of increasing domestic oil production and reducing abandonment of oil fields.

Post Waterflood CO2 Miscible Flood in Light Oil, Fluvial-Dominated Deltaic Reservoir (Pre-Work and Project Proposal), Class I

Energy Technology Data Exchange (ETDEWEB)

Bou-Mikael, Sami

2002-02-05

This project outlines a proposal to improve the recovery of light oil from waterflooded fluvial dominated deltaic (FDD) reservoir through a miscible carbon dioxide (CO2) flood. The site is the Port Neches Field in Orange County, Texas. The field is well explored and well exploited. The project area is 270 acres within the Port Neches Field.

pCO2 and enzymatic activity in a river floodplain system of the Danube under different hydrological settings.

Science.gov (United States)

Sieczko, Anna; Demeter, Katalin; Mayr, Magdalena; Meisterl, Karin; Peduzzi, Peter

2014-05-01

Surface waters may serve as either sinks or sources of CO2. In contrast to rivers, which are typically sources of CO2 to the atmosphere, the role of fringing floodplains in CO2 flux is largely understudied. This study was conducted in a river-floodplain system near Vienna (Austria). The sampling focused on changing hydrological situations, particularly on two distinct flood events: a typical 1-year flood in 2012 and an extraordinary 100-year flood in 2013. One objective was to determine partial pressure of CO2 (pCO2) in floodplain lakes with different degree of connectivity to the main channel, and compare the impact of these two types of floods. Another aim was to decipher which fraction of the dissolved organic matter (DOM) pool contributed to pCO2 by linking pCO2 with optical properties of DOM and extracellular enzymatic activity (EEA) of microbes. The EEA is a valuable tool, especially for assessing the non-chromophoric but rapidly utilized DOM-fraction during floods. In 2012 and 2013, the floodplain lakes were dominated by supersaturated pCO2 conditions, which indicates that they served as CO2 sources. Surprisingly, there were no significant differences in pCO2 between the two types of flood. Our findings imply that the extent of the flood had minor impact on pCO2, but the general occurrence of a flood appears to be important. During the flood in 2013 significantly more dissolved organic carbon (DOC) (pcarbohydrates.

Residual CO2 trapping in Indiana limestone.

Science.gov (United States)

El-Maghraby, Rehab M; Blunt, Martin J

2013-01-02

We performed core flooding experiments on Indiana limestone using the porous plate method to measure the amount of trapped CO(2) at a temperature of 50 °C and two pressures: 4.2 and 9 MPa. Brine was mixed with CO(2) for equilibration, then the mixture was circulated through a sacrificial core. Porosity and permeability tests conducted before and after 884 h of continuous core flooding confirmed negligible dissolution. A trapping curve for supercritical (sc)CO(2) in Indiana showing the relationship between the initial and residual CO(2) saturations was measured and compared with that of gaseous CO(2). The results were also compared with scCO(2) trapping in Berea sandstone at the same conditions. A scCO(2) residual trapping end point of 23.7% was observed, indicating slightly less trapping of scCO(2) in Indiana carbonates than in Berea sandstone. There is less trapping for gaseous CO(2) (end point of 18.8%). The system appears to be more water-wet under scCO(2) conditions, which is different from the trend observed in Berea; we hypothesize that this is due to the greater concentration of Ca(2+) in brine at higher pressure. Our work indicates that capillary trapping could contribute to the immobilization of CO(2) in carbonate aquifers.

Post Waterflood CO2 Miscible Flood in Light Oil, Fluvial-Dominated Deltaic Reservoir (Pre-Work and Project Proposal - Appendix); FINAL

International Nuclear Information System (INIS)

Bou-Mikael, Sami

2002-01-01

The main objective of the Port Neches Project was to determine the feasibility and producibility of CO2 miscible flooding techniques enhanced with horizontal drilling applied to a Fluvial Dominated Deltaic reservoir. The second was to disseminate the knowledge gained through established Technology Transfer mechanisms to support DOE's programmatic objectives of increasing domestic oil production and reducing abandonment of oil fields

Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

Energy Technology Data Exchange (ETDEWEB)

Fauth, D.J.; Filburn, T.P. (University of Hartford, West Hartford, CT); Gray, M.L.; Hedges, S.W.; Hoffman, J.; Pennline, H.W.; Filburn, T.

2007-06-01

Capturing CO2 emissions generated from fossil fuel-based power plants has received widespread attention and is considered a vital course of action for CO2 emission abatement. Efforts are underway at the Department of Energy’s National Energy Technology Laboratory to develop viable energy technologies enabling the CO2 capture from large stationary point sources. Solid, immobilized amine sorbents (IAS) formulated by impregnation of liquid amines within porous substrates are reactive towards CO2 and offer an alternative means for cyclic capture of CO2 eliminating, to some degree, inadequacies related to chemical absorption by aqueous alkanolamine solutions. This paper describes synthesis, characterization, and CO2 adsorption properties for IAS materials previously tested to bind and release CO2 and water vapor in a closed loop life support system. Tetraethylenepentamine (TEPA), acrylonitrile-modified tetraethylenepentamine (TEPAN), and a single formulation consisting of TEPAN and N, N’-bis(2-hydroxyethyl)ethylenediamine (BED) were individually supported on a poly (methyl methacrylate) (PMMA) substrate and examined. CO2 adsorption profiles leading to reversible CO2 adsorption capacities were obtained using thermogravimetry. Under 10% CO2 in nitrogen at 25°C and 1 atm, TEPA supported on PMMA over 60 minutes adsorbed ~3.2 mmol/g{sorbent} whereas, TEPAN supported on PMMA along with TEPAN and BED supported on PMMA adsorbed ~1.7 mmol/g{sorbent} and ~2.3 mmol/g{sorbent} respectively. Cyclic experiments with a 1:1 weight ratio of TEPAN and BED supported on poly (methyl methacrylate) beads utilizing a fixed-bed flow system with 9% CO2, 3.5% O2, nitrogen balance with trace gas constituents were studied. CO2 adsorption capacity was ~ 3 mmols CO2/g{sorbent} at 40°C and 1.4 atm. No beneficial effect on IAS performance was found using a moisture-laden flue gas mixture. Tests with 750 ppmv NO in a humidified gas stream revealed negligible NO sorption onto the IAS. A high SO2

A Review of CO2-Enhanced Oil Recovery with a Simulated Sensitivity Analysis

Directory of Open Access Journals (Sweden)

Mandadige Samintha Anne Perera

2016-06-01

Full Text Available This paper reports on a comprehensive study of the CO2-EOR (Enhanced oil recovery process, a detailed literature review and a numerical modelling study. According to past studies, CO2 injection can recover additional oil from reservoirs by reservoir pressure increment, oil swelling, the reduction of oil viscosity and density and the vaporization of oil hydrocarbons. Therefore, CO2-EOR can be used to enhance the two major oil recovery mechanisms in the field: miscible and immiscible oil recovery, which can be further increased by increasing the amount of CO2 injected, applying innovative flood design and well placement, improving the mobility ratio, extending miscibility, and controlling reservoir depth and temperature. A 3-D numerical model was developed using the CO2-Prophet simulator to examine the effective factors in the CO2-EOR process. According to that, in pure CO2 injection, oil production generally exhibits increasing trends with increasing CO2 injection rate and volume (in HCPV (Hydrocarbon pore volume and reservoir temperature. In the WAG (Water alternating gas process, oil production generally increases with increasing CO2 and water injection rates, the total amount of flood injected in HCPV and the distance between the injection wells, and reduces with WAG flood ratio and initial reservoir pressure. Compared to other factors, the water injection rate creates the minimum influence on oil production, and the CO2 injection rate, flood volume and distance between the flood wells have almost equally important influence on oil production.

INEXPENSIVE CO{sub 2} THICKENING AGENTS FOR IMPROVED MOBILITY CONTROL OF CO{sub 2} FLOODS

Energy Technology Data Exchange (ETDEWEB)

Robert M. Enick; Eric J. Beckman; Andrew Hamilton

2004-10-01

The objective of this research was the design, synthesis and evaluation of inexpensive, nonfluorous carbon dioxide thickening agents. We followed the same strategy employed in the design of fluorinated CO{sub 2} polymeric thickeners. First, a highly CO{sub 2}-philic, hydrocarbon-based monomer was to be identified. Polymers or oligomers of this monomer were then synthesized. The second step was to be completed only when a CO{sub 2}-soluble polymer that was soluble in CO{sub 2} at pressures comparable to the MMP was identified. In the second step, viscosity-enhancing associating groups were to be incorporated into the polymer to make it a viable thickener that exhibited high CO{sub 2} solubility at EOR MMP conditions. This final report documents the CO{sub 2} solubility of a series of commercial and novel polymers composed of carbon, hydrogen, oxygen and, in some cases, nitrogen.

Soil CO2 venting as one of the mechanisms for tolerance of Zn deficiency by rice in flooded soils.

Science.gov (United States)

Affholder, Marie-Cecile; Weiss, Dominik J; Wissuwa, Matthias; Johnson-Beebout, Sarah E; Kirk, Guy J D

2017-12-01

We sought to explain rice (Oryza sativa) genotype differences in tolerance of zinc (Zn) deficiency in flooded paddy soils and the counter-intuitive observation, made in earlier field experiments, that Zn uptake per plant increases with increasing planting density. We grew tolerant and intolerant genotypes in a Zn-deficient flooded soil at high and low planting densities and found (a) plant Zn concentrations and growth increased with planting density and more so in the tolerant genotype, whereas the concentrations of other nutrients decreased, indicating a specific effect on Zn uptake; (b) the effects of planting density and genotype on Zn uptake could only be explained if the plants induced changes in the soil to make Zn more soluble; and (c) the genotype and planting density effects were both associated with decreases in dissolved CO 2 in the rhizosphere soil solution and resulting increases in pH. We suggest that the increases in pH caused solubilization of soil Zn by dissolution of alkali-soluble, Zn-complexing organic ligands from soil organic matter. We conclude that differences in venting of soil CO 2 through root aerenchyma were responsible for the genotype and planting density effects. © 2017 John Wiley & Sons Ltd.

Straw enhanced CO2 and CH4 but decreased N2O emissions from flooded paddy soils: Changes in microbial community compositions

Science.gov (United States)

Wang, Ning; Yu, Jian-Guang; Zhao, Ya-Hui; Chang, Zhi-Zhou; Shi, Xiao-Xia; Ma, Lena Q.; Li, Hong-Bo

2018-02-01

To explore microbial mechanisms of straw-induced changes in CO2, CH4, and N2O emissions from paddy field, wheat straw was amended to two paddy soils from Taizhou (TZ) and Yixing (YX), China for 60 d under flooded condition. Illumia sequencing was used to characterize shift in bacterial community compositions. Compared to control, 1-5% straw amendment significantly elevated CO2 and CH4 emissions with higher increase at higher application rates, mainly due to increased soil DOC concentrations. In contrast, straw amendment decreased N2O emission. Considering CO2, CH4, and N2O emissions as a whole, an overall increase in global warming potential was observed with straw amendment. Total CO2 and CH4 emissions from straw-amended soils were significantly higher for YX than TZ soil, suggesting that straw-induced greenhouse gas emissions depended on soil characteristics. The abundance of C-turnover bacteria Firmicutes increased from 28-41% to 54-77% with straw amendment, thereby increasing CO2 and CH4 emissions. However, straw amendment reduced the abundance of denitrifying bacteria Proteobacteria from 18% to 7.2-13% or increased the abundance of N2O reducing bacteria Clostridium from 7.6-11% to 13-30%, thereby decreasing N2O emission. The results suggested straw amendment strongly influenced greenhouse gas emissions via alerting soil properties and bacterial community compositions. Future field application is needed to ascertain the effects of straw return on greenhouse gas emissions.

Post Waterflood CO2 Miscible Flood in Light Oil, Fluvial-Dominated Deltaic Reservoir (Pre-Work and Project Proposal), Class I; FINAL

International Nuclear Information System (INIS)

Bou-Mikael, Sami

2002-01-01

This project outlines a proposal to improve the recovery of light oil from waterflooded fluvial dominated deltaic (FDD) reservoir through a miscible carbon dioxide (CO2) flood. The site is the Port Neches Field in Orange County, Texas. The field is well explored and well exploited. The project area is 270 acres within the Port Neches Field

Combining Co-Benefits and Stakeholders Perceptions into Green Infrastructure Selection for Flood Risk Reduction

Directory of Open Access Journals (Sweden)

Alida Alves

2018-02-01

Full Text Available An important increase in flood risk levels is expected in future decades in many areas around the globe. In addition, the traditional approaches for flood management offer options with low sustainability. As a response, the use of non-traditional drainage measures, also called green infrastructures, has been increasingly suggested in the last years. One important reason for their increasing popularity has been the co-benefits that they offer to the environment. The development of an efficient planning for sustainable urban drainage systems is a complex process that needs the involvement of multiple stakeholders. Moreover, the measures to be adopted should be evaluated considering their potential to achieve multiple benefits related to human well-being, rather than just to flood risk management. In this work, we propose a framework for the selection of green infrastructures on the basis of a co-benefits analysis. The aim is to include the achievement of co-benefits and human well-being into decision-making for flood management, considering the stakeholders’ perceptions to define the most important benefits to be enhanced. The application of the framework presented here to a case study in Ayutthaya, Thailand, shows the importance of including different stakeholder’s opinions. In addition, it shows that decision makers should consider locally defined co-benefits as well as flood risk reduction when defining which green infrastructures to apply.

Application of eosin-modified reconstituted Co(II)-myoglobin as semisynthetic photoenzyme for cyclic photosynthesis

Energy Technology Data Exchange (ETDEWEB)

Zahavy, E.; Willner, I. [Hebrew Univ. of Jerusalem (Israel)

1995-10-25

During the last two decades, extensive research efforts were directed to the development of artificial photosynthetic systems. Here we report on the cyclic coupling of the reductive semisynthetic photoenzyme, Eo{sup 2-}-Mb-Co(II), to the oxidative enzyme lactate dehydrogenase, LDH, using a reversible ferrocene electron mediator as electron shuttle between the oxidative and reductive sites. We demonstrated that the Eo{sup 2-}-Mb-Co(II) photoenzyme and a reversible ferrocene electron donor provided an assembly for the effective stabilization of the photogenerated redox products against recombination. This facilitated the subsequent oxidation and reduction of lactate and acetylene, respectively. 18 refs., 4 refs.

Carbon dioxide (CO2) capture and storage : Canadian market development

International Nuclear Information System (INIS)

Hendriks, A.

2006-01-01

Carbon dioxide (CO 2 ) enhanced oil recovery (EOR) is used to extend the life of light oil reservoirs in Canada. An additional 13 per cent of original oil in place is typically recovered using CO 2 flooding processes. However, a carbon capture and storage (CCS) market is needed in order to commercialize CO 2 flooding technologies. CO 2 can be obtained from naturally-occurring accumulations in underground reservoirs, electrical and coal-fired generation plants, petrochemical facilities, and upstream oil and gas processing facilities. CO 2 is sequestered in EOR processes, in sour gas disposal processes, solvent recovery processes, and in coalbed methane (CBM) extraction. It is also disposed in depleted fields and aquifers. While CCS technologies are mature, project economics remain marginal. However, CCS in EOR is commercially feasible at current high oil prices. No transportation infrastructure is in place to transport sources of CO 2 in the high volumes needed to establish a market. While governments have created a favourable public policy environment for CCS, governments will need to address issues related to infrastructure, public perception of CCS, and stakeholder engagement with CCS projects. It was concluded that CCS and CO 2 flooding techniques have the capacity to reduce greenhouse gas (GHG) emissions while helping to sustain light oil production. tabs., figs

CO{sub 2} huff-n-puff process in a light oil shallow carbonate reservoir. Annual report, January 1, 1996--December 31, 1996

Energy Technology Data Exchange (ETDEWEB)

Prieditis, J.; Wehner, S.

1998-01-01

The application of cyclic CO{sub 2}, often referred to as the CO{sub 2} Huff-n-Puff process, may find its niche in the maturing waterfloods of the Permian Basin. Coupling the CO{sub 2} H-n-P process to miscible flooding applications could provide the needed revenue to sufficiently mitigate near-term negative cash flow concerns in the capital intensive miscible projects. Texaco Exploration & Production Inc. and the U.S. Department of Energy have teamed up in an attempt to develop the CO{sub 2} Huff-n-Puff process in the Grayburg and San Andres formations; a light oil, shallow shelf carbonate reservoir that exists throughout the Permian Basin. A significant amount of oil reserves are located in carbonate reservoirs. Specifically, the carbonates deposited in shallow shelf (SSC) environments make up the largest percentage of known reservoirs within the Permian Basin of North America. Many of these known resources have been under waterflooding operations for decades and are at risk of abandonment if crude oil recoveries cannot be economically enhanced. The selected site for this demonstration project is the Central Vacuum Unit waterflood in Lea County, New Mexico. Miscible CO{sub 2} flooding is the process of choice for enhancing recovery of light oils and already accounts for over 12% of the Permian Basin`s daily production. There are significant probable reserves associated with future miscible CO{sub 2} projects. However, many are marginally economic at current market conditions due to large up-front capital commitments for a peak response which may be several years in the future. The resulting negative cash-flow is sometimes too much for an operator to absorb. The CO{sub 2} H-n-P process is being investigated as a near-term option to mitigate the negative cash-flow situation--allowing acceleration of inventoried miscible CO{sub 2} projects when coupled together.

Reactivation properties of carbide slag as a CO{sub 2} sorbent during calcination/carbonation cycles

Energy Technology Data Exchange (ETDEWEB)

Li, Yingjie; Sun, Rongyue; Liu, Hongling; Lu, Chunmei [Shandong Univ., Jinan (China). School of Energy and Power Engineering

2013-07-01

The carbide slag from polyvinyl chloride production as industry hazardous wastes was proposed as CO{sub 2} sorbent at high temperature in calcium looping cycle. The cyclic CO{sub 2} capture behavior and the microstructure characteristics of the carbide slag as one of the typical calcium-based industrial wastes during the multiple calcination/carbonation cycles. Also, the comparisons between the carbide slag and the natural limestone in cyclic CO{sub 2} capture behavior were made. XRD analysis demonstrates that the predominating constituent of the carbide slag is Ca(OH){sub 2}. The carbonation temperature ranging from 650 to 700 C is favourable to cyclic carbonation of the carbide slag. The cyclic carbonation conversions of the carbide slag is lower than that of the limestone before a certain time, but the situation is converse after that time in a thermogravimetric analyzer. The carbide slag has better cyclic CO{sub 2} capture capacity. The carbonation conversion of the carbide slag retains 0.28 after 100 calcination/carbonation cycles, while the two limestones achieve 0.08 and 0.14 respectively at the same reaction conditions in a dual fixed-bed reactor. The microstructure of the carbide slag by SEM reveals the reason why it possesses better CO{sub 2} capture capacity.

Design and Implementation of a CO2 Flood Utilizing Advanced Reservoir Characterization and Horizontal Injection Wells In a Shallow Shelf Carbonate Approaching Waterflood Depletion, Class II

Energy Technology Data Exchange (ETDEWEB)

Wier, Don R. Chimanhusky, John S.; Czirr, Kirk L.; Hallenbeck, Larry; Gerard, Matthew G.; Dollens, Kim B.; Owen, Rex; Gaddis, Maurice; Moshell, M.K.

2002-11-18

The purpose of this project was to economically design an optimum carbon dioxide (CO2) flood for a mature waterflood nearing its economic abandonment. The original project utilized advanced reservoir characterization and CO2 horizontal injection wells as the primary methods to redevelop the South Cowden Unit (SCU). The development plans; project implementation and reservoir management techniques were to be transferred to the public domain to assist in preventing premature abandonment of similar fields.

Spatial variability of greenhouse gases emissions (CO2, CH4, N2O) in a tropical hydroelectric reservoir flooding primary forest (Petit Saut Reservoir, French Guiana)

Science.gov (United States)

Cailleaud, Emilie; Guérin, Frédéric; Bouillon, Steven; Sarrazin, Max; Serça, Dominique

2014-05-01

At the Petit Saut Reservoir (PSR, French Guiana, South America), vertical profiles were performed at 5 stations in the open waters (OW) and 6 stations in two shallow flooded forest (FF) areas between April 2012 and September 2013. Measurements included physico-chemical parameters, ammonium, nitrate and dissolved greenhouse gas (CO2, CH4, N2O) concentrations, dissolved and particulate organic carbon (DOC, POC) and nitrogen (PN), δ13C-POC and δ15N-PN . The diffusive fluxes were calculated from surface concentrations. The aim of this study was to estimate the spatial variations of greenhouse gas emissions at a dentrical hydroelectric reservoir located in the tropics and flooding primary forest. Twenty years after impoundment, the water column of the PSR is permanently and tightly stratified thermally in the FF whereas in the OW, the thermal gradients are not as stable. The different hydrodynamical behaviours between the two different zones have significant consequences on the biogeochemistry: oxygen barely diffuses down to the hypolimnion in the FF whereas destratification occurs sporadically during the rainy season in the OW. Although we found the same range of POC in the FF and the OW (2.5-29 μmol L-1) and 20% more DOC at the bottom of OW than in the FF (229-878 μmol L-1), CO2 and CH4 concentrations were always significantly higher in the FF (CO2: 11-1412 μmol L-1, CH4: 0.001-1015 μmol L-1) than in the OW. On average, the CO2 concentrations were 30-40% higher in the FF than in the OW and the CH4 concentrations were three times higher in the FF than in the OW. The δ13C-POC and C:N values did not suggest substantial differences in the sources of OM between the FF and OW. At all stations, POC at the bottom has an isotopic signature slightly lighter than the terrestrial OM in the surrounding forest whereas the isotopic signature of surface POM would result from phytoplankton and methanotrophs. The vertical profiles of nitrogen compounds reveal that the main

Water mobility key to improved floods

Energy Technology Data Exchange (ETDEWEB)

Pamenter, C B

1967-03-01

The use of polymer floods in the U.S. and Canada is discussed. A 2-yr laboratory study conducted by Dow Chemical Co. early in the life of polymer flooding showed that polymers improved the mobility ratio without damage to porosity or permeability of reservoir rock. A pilot test was made in the Niagara Field, Ky., and the results of this pilot compared to the performance of a waterflood that had been operating in this field for about 4 yr. The results showed that polymer flooding was superior to conventional waterflooding and had a distinct behavior. Another pilot flood conducted by Dow in the Albrecht Field, Starr County, Tex., showed similar results. Union Oil Co. of California also conducted pilot tests in 4 of their California reservoirs. Additional recoverable reserves resulting from polymer flooding for 2 of these reservoirs were estimated at 95,000 and 70,000 bbl. The other 2 tests were not as satisfactory, but this behavior is thought to be the result of not using enough polymer. Two other projects discussed are the NE. Hallsville Field unit in East Texas and the Squirrel sand reservoir in Woodson County, Kans., which were conducted by Hunt Oil Co. and Brazos Oil and Gas Co., respectively.

Pore-scale imaging of capillary trapped supercritical CO2 as controlled by water-wet vs. CO2-wet media and grain shapes

Science.gov (United States)

Chaudhary, K.; Cardenas, M.; Wolfe, W. W.; Maisano, J. A.; Ketcham, R. A.; Bennett, P.

2013-12-01

The capillary trapping of supercritical CO2 (s-CO2) is postulated to comprise up to 90% of permanently trapped CO2 injected during geologic sequestration. Successive s-CO2/brine flooding experiments under reservoir conditions showed that water-wet rounded beads trapped 15% of injected s-CO2 both as clusters and as individual ganglia, whereas CO2¬-wet beads trapped only 2% of the injected s-CO2 as minute pockets in pore constrictions. Angular water-wet grains trapped 20% of the CO2 but flow was affected by preferential flow. Thus, capillary trapping is a viable mechanism for the permanent CO2 storage, but its success is constrained by the media wettability.

Water supply and tree growth. Part II. Flooding

Energy Technology Data Exchange (ETDEWEB)

Kozlowski, T.T.

1982-02-01

Continuous or periodic flooding of soil with fresh or salt water is a common occurrence. Although flooding rapidly depletes soil oxygen the problem of poor soil aeration also exists in extensive areas of unflooded, fine-textured soils. Compounds that may be phytotoxic and accumulate in flooded soils include ethanol, acetaldehyde, cyanogenic compounds, sulphides, CO/sub 2/, iron, manganese, ethane, propylene, fatty acids, hydroxy and dicarboxylic acids, unsaturated acids, aldehydes, ketones, mercaptans, and ethylene. Flooding affects seed germination, stomatal aperture, photosynthesis, permeability of roots, mineral relations, and growth and survival of trees. Although growth of most trees is reduced by flooding it is sometimes increased in a few flood-tolerant species. Flood tolerance of trees varies widely with species, age of trees, and periodicity, duration, and season of occurrence of flooding. Standing water is much more harmful than moving water. Physiological dysfunctions associated with flooding are complex and variously involve the influence of oxygen deficiency, excess CO/sub 2/, a variety of toxic compounds, and altered hormone metabolism. Flood tolerance involves both morphological and physiological adaptations. Important morphological adaptations include formation of lenticels and root regeneration. Physiological adaptations may reflect avoidance of accumulation of ethanol as well as capacity to oxidize the rhizosphere and to tolerate high CO/sub 2/ concentrations in the soil. Adaptations to flooding by salt water include mechanisms for both salt tolerance and avoidance.

Biosynthesis of cyclic 2,3-diphosphoglycerate. Isolation and characterization of 2-phosphoglycerate kinase and cyclic 2,3-diphosphoglycerate synthetase from Methanothermus fervidus.

Science.gov (United States)

Lehmacher, A; Vogt, A B; Hensel, R

1990-10-15

Starting from 2-phosphoglycerate the biosynthesis of cDPG comprises two steps: (i) the phosphorylation of 2-phosphoglycerate to 2,3-diphosphoglycerate and (ii) the intramolecular cyclization to cyclic 2,3-diphosphoglycerate. The involved enzymes, 2-phosphoglycerate kinase and cyclic 2,3-diphosphoglycerate synthetase, were purified form Methanothermus fervidus. Their molecular and catalytic properties were characterized.

Integrated Electrochemical Processes for CO₂ Capture and Conversion to Commodity Chemicals

Energy Technology Data Exchange (ETDEWEB)

Hatton, T. Alan [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Jamison, Timothy [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

2013-09-30

The Massachusetts Institute of Technology (MIT) and Siemens Corporations (SCR) are developing new chemical synthesis processes for commodity chemicals from CO₂. The process is assessed as a novel chemical sequestration technology that utilizes CO₂ from dilute gas streams generated at industrial carbon emitters as a raw material to produce useful commodity chemicals. Work at Massachusetts Institute of Technology (MIT) commenced on October 1st, 2010, and finished on September 30th, 2013. During this period, we have investigated and accomplished five objectives that mainly focused on converting CO₂ into high-value chemicals: 1) Electrochemical assessment of catalytic transformation of CO₂ and epoxides to cyclic carbonates; 2) Investigation of organocatalytic routes to convert CO₂ and epoxide to cyclic carbonates; 3) Investigation of CO₂ Capture and conversion using simple olefins under continuous flow; 4) Microwave assisted synthesis of cyclic carbonates from olefins using sodium bicarbonates in a green pathway; 5) Life cycle analyses of integrated chemical sequestration process. In this final report, we will describe the detailed study performed during the three year period and findings and conclusions drawn from our research.

Conditions Leading to High CO2 (>5 kPa) in Waterlogged–Flooded Soils and Possible Effects on Root Growth and Metabolism

Science.gov (United States)

GREENWAY, HANK; ARMSTRONG, WILLIAM; COLMER, TIMOTHY D.

2006-01-01

• Aims Soil waterlogging impedes gas exchange with the atmosphere, resulting in low PO2 and often high PCO2. Conditions conducive to development of high PCO2 (5–70 kPa) during soil waterlogging and flooding are discussed. The scant information on responses of roots to high PCO2 in terms of growth and metabolism is reviewed. • Scope PCO2 at 15–70 kPa has been reported for flooded paddy-field soils; however, even 15 kPa PCO2 may not always be reached, e.g. when soil pH is above 7. Increases of PCO2 in soils following waterlogging will develop much more slowly than decreases in PO2; in soil from rice paddies in pots without plants, maxima in PCO2 were reached after 2–3 weeks. There are no reliable data on PCO2 in roots when in waterlogged or flooded soils. In rhizomes and internodes, PCO2 sometimes reached 10 kPa, inferring even higher partial pressures in the roots, as a CO2 diffusion gradient will exist from the roots to the rhizomes and shoots. Preliminary modelling predicts that when PCO2 is higher in a soil than in roots, PCO2 in the roots would remain well below the PCO2 in the soil, particularly when there is ventilation via a well-developed gas-space continuum from the roots to the atmosphere. The few available results on the effects of PCO2 at > 5 kPa on growth have nearly all involved sudden increases to 10–100 kPa PCO2; consequently, the results cannot be extrapolated with certainty to the much more gradual increases of PCO2 in waterlogged soils. Nevertheless, rice in an anaerobic nutrient solution was tolerant to 50 kPa CO2 being suddenly imposed. By contrast, PCO2 at 25 kPa retarded germination of some maize genotypes by 50 %. With regard to metabolism, assuming that the usual pH of the cytoplasm of 7·5 was maintained, every increase of 10 kPa CO2 would result in an increase of 75–90 mm HCO3− in the cytoplasm. pH maintenance would depend on the biochemical and biophysical pH stats (i.e. regulatory systems

Health Co-Benefits of Green Building Design Strategies and Community Resilience to Urban Flooding: A Systematic Review of the Evidence.

Science.gov (United States)

Houghton, Adele; Castillo-Salgado, Carlos

2017-12-06

Climate change is increasingly exacerbating existing population health hazards, as well as resulting in new negative health effects. Flooding is one particularly deadly example of its amplifying and expanding effect on public health. This systematic review considered evidence linking green building strategies in the Leadership in Energy and Environmental Design ® (LEED) Rating System with the potential to reduce negative health outcomes following exposure to urban flooding events. Queries evaluated links between LEED credit requirements and risk of exposure to urban flooding, environmental determinants of health, co-benefits to public health outcomes, and co-benefits to built environment outcomes. Public health co-benefits to leveraging green building design to enhance flooding resilience included: improving the interface between humans and wildlife and reducing the risk of waterborne disease, flood-related morbidity and mortality, and psychological harm. We conclude that collaborations among the public health, climate change, civil society, and green building sectors to enhance community resilience to urban flooding could benefit population health.

Synthesis of Co 2SnO 4@C core-shell nanostructures with reversible lithium storage

Science.gov (United States)

Qi, Yue; Du, Ning; Zhang, Hui; Wu, Ping; Yang, Deren

This paper reports the synthesis of Co 2SnO 4@C core-shell nanostructures through a simple glucose hydrothermal and subsequent carbonization approach. The as-synthesized Co 2SnO 4@C core-shell nanostructures have been applied as anode materials for lithium-ion batteries, which exhibit improved cyclic performance compared to pure Co 2SnO 4 nanocrystals. The carbon matrix has good volume buffering effect and high electronic conductivity, which may be responsible for the improved cyclic performance.

Effect of stratification on segregation in carbon dioxide miscible flooding in a water-flooded oil reservoir

International Nuclear Information System (INIS)

Bhatti, A.A.; Mahmood, S.M.; Amjad, B.

2013-01-01

Oil reservoirs are subjected to tertiary recovery by deploying any enhanced oil recovery (EOR) technique for the recovery of left over oil. Amongst many EOR methods one of the widely applied worldwide is CO/sub 2/ flooding through miscible, near miscible or immiscible displacement processes. CO/sub 2/ flooding process responds to a number of reservoir and fluid characteristics. These characteristics have strong effect on overall efficiency of the displacement process. Better understanding of the effect of different characteristics on displacement process is important to plan an efficient displacement process. In this work, the effect of stratification resulting in gravity segregation of the injected fluid is studied in an oil reservoir which is water-flooded during secondary phase of recovery. Sensitivity analysis is performed through successive simulation on Eclipse 300 (compositional) reservoir simulator. Process involves the continuous CO/sub 2/ injection in an oil reservoir with more than 1/3rd of original oil in place left after water flooding. Reservoir model with four different permeability layers is studied. Four patterns by changing the arrangement of the permeabilities of the layers are analysed. The effect of different arrangement or stratification on segregation of CO/sub 2/ and ultimately on the incremental oil recovery, is investigated. It has been observed that out of four arrangements, upward fining pattern relatively overcame the issue of the segregation of CO/sub 2/ and consequently 33% more oil with half injection volume is recovered when compared with the downward fining pattern. (author)

CaO-Based CO2 Sorbents Effectively Stabilized by Metal Oxides.

Science.gov (United States)

Naeem, Muhammad Awais; Armutlulu, Andac; Imtiaz, Qasim; Müller, Christoph R

2017-11-17

Calcium looping (i.e., CO 2 capture by CaO) is a promising second-generation CO 2 capture technology. CaO, derived from naturally occurring limestone, offers an inexpensive solution, but due to the harsh operating conditions of the process, limestone-derived sorbents undergo a rapid capacity decay induced by the sintering of CaCO 3 . Here, we report a Pechini method to synthesize cyclically stable, CaO-based CO 2 sorbents with a high CO 2 uptake capacity. The sorbents synthesized feature compositional homogeneity in combination with a nanostructured and highly porous morphology. The presence of a single (Al 2 O 3 or Y 2 O 3 ) or bimetal oxide (Al 2 O 3 -Y 2 O 3 ) provides cyclic stability, except for MgO which undergoes a significant increase in its particle size with the cycle number. We also demonstrate a direct relationship between the CO 2 uptake and the morphology of the synthesized sorbents. After 30 cycles of calcination and carbonation, the best performing sorbent, containing an equimolar mixture of Al 2 O 3 and Y 2 O 3 , exhibits a CO 2 uptake capacity of 8.7 mmol CO 2  g -1 sorbent, which is approximately 360 % higher than that of the reference limestone. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Soil CO2 concentrations and efflux dynamics of a tree island in the Pantanal wetland

Science.gov (United States)

Lathuillière, Michael J.; Pinto, Osvaldo B.; Johnson, Mark S.; Jassal, Rachhpal S.; Dalmagro, Higo J.; Leite, Nei K.; Speratti, Alicia B.; Krampe, Daniela; Couto, Eduardo G.

2017-08-01

The Pantanal is the largest tropical wetland on the planet, and yet little information is available on the biome's carbon cycle. We used an automatic station to measure soil CO2 concentrations and oxidation-reduction potential over the 2014 and 2015 flood cycles of a tree island in the Pantanal that is immune to inundation during the wetland's annual flooding. The soil CO2 concentration profile was then used to estimate soil CO2 efflux over the two periods. In 2014, subsurface soil saturation at 0.30 m depth created conditions in that layer that led to CO2 buildup close to 200,000 ppm and soil oxidation-reduction potential below -300 mV, conditions that were not repeated in 2015 due to annual variability in soil saturation at the site. Mean CO2 efflux over the 2015 flood cycle was 0.023 ± 0.103 mg CO2-C m-2 s-1 representing a total annual efflux of 593 ± 2690 mg CO2-C m-2 y-1. Unlike a nearby tree island site that experiences full inundation during the wet season, here the soil dried quickly following repeated rain events throughout the year, which led to the release of CO2 pulses from the soil. This study highlights not only the complexity and heterogeneity in the Pantanal's carbon balance based on differences in topography, flood cycles, and vegetation but also the challenges of applying the gradient method in the Pantanal due to deviations from steady state conditions.

A Co-Opted Hormonal Cascade Activates Dormant Adventitious Root Primordia upon Flooding in Solanum dulcamara.

Science.gov (United States)

Dawood, Thikra; Yang, Xinping; Visser, Eric J W; Te Beek, Tim A H; Kensche, Philip R; Cristescu, Simona M; Lee, Sangseok; Floková, Kristýna; Nguyen, Duy; Mariani, Celestina; Rieu, Ivo

2016-04-01

Soil flooding is a common stress factor affecting plants. To sustain root function in the hypoxic environment, flooding-tolerant plants may form new, aerenchymatous adventitious roots (ARs), originating from preformed, dormant primordia on the stem. We investigated the signaling pathway behind AR primordium reactivation in the dicot species Solanum dulcamara Transcriptome analysis indicated that flooding imposes a state of quiescence on the stem tissue, while increasing cellular activity in the AR primordia. Flooding led to ethylene accumulation in the lower stem region and subsequently to a drop in abscisic acid (ABA) level in both stem and AR primordia tissue. Whereas ABA treatment prevented activation of AR primordia by flooding, inhibition of ABA synthesis was sufficient to activate them in absence of flooding. Together, this reveals that there is a highly tissue-specific response to reduced ABA levels. The central role for ABA in the response differentiates the pathway identified here from the AR emergence pathway known from rice (Oryza sativa). Flooding and ethylene treatment also induced expression of the polar auxin transporter PIN2, and silencing of this gene or chemical inhibition of auxin transport inhibited primordium activation, even though ABA levels were reduced. Auxin treatment, however, was not sufficient for AR emergence, indicating that the auxin pathway acts in parallel with the requirement for ABA reduction. In conclusion, adaptation of S. dulcamara to wet habitats involved co-option of a hormonal signaling cascade well known to regulate shoot growth responses, to direct a root developmental program upon soil flooding. © 2016 American Society of Plant Biologists. All Rights Reserved.

Cyclic oxidation behavior of plasma sprayed NiCrAlY/WC-Co/cenosphere coating

Science.gov (United States)

Mathapati, Mahantayya; Ramesh M., R.; Doddamani, Mrityunjay

2018-04-01

Components working at elevated temperature like boiler tubes of coal and gas fired power generation plants, blades of gas and steam turbines etc. experience degradation owing to oxidation. Oxidation resistance of such components can be increased by developing protective coatings. In the present investigation NiCrAlY-WC-Co/Cenosphere coating is deposited on MDN 321 steel substrate using plasma spray coating. Thermo cyclic oxidation behavior of coating and substrate is studied in static air at 600 °C for 20 cycles. The thermo gravimetric technique is used to approximate the kinetics of oxidation. X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM), Energy Dispersive Spectroscopy (EDS) and X-ray mapping techniques are used to characterize the oxidized samples. NiCrAlY-WC-Co/Cenosphere coating exhibited lower oxidation rate in comparison to MDN 321 steel substrate. The lower oxidation rate of coating is attributed to formation of Al2O3, Cr2O3, NiO and CoWO4 oxides on the outermost surface.

Different sorbents in calcium looping cycle for CO{sub 2} capture

Energy Technology Data Exchange (ETDEWEB)

Luo, Cong; Zheng, Ying; Ding, Ning [Huazhong Univ. of Science and Technology, Wuhan (China). State Key Lab. of Coal Combustion

2013-07-01

Cyclic CO{sub 2} capture using commercial pure micro CaCO{sub 3} and nano CaCO{sub 3} is investigated in this paper which focuses on the different characteristics two different sorbents during high temperature reactions. The results indicate that the nano CaCO{sub 3} sorbent has higher carbonation conversions and carbonation rates than the micro CaCO{sub 3} sorbent in the cyclic reactions. Furthermore, nano sorbent can retain its fast carbonation rates at the beginning dozens of seconds during each cycle. In contrast, the carbonation rates of micro sorbent diminish with the increase of cycle number. But, unfortunately, CaO derived from nano CaCO3 sorbent sinter much easily. Its grains, which are composed of numerous spherical nanocrystallites, experience dramatic morphological changes during high temperature reactions.

On the potential for CO2 mineral storage in continental flood basalts – PHREEQC batch- and 1D diffusion–reaction simulations

Directory of Open Access Journals (Sweden)

Van Pham Thi

2012-06-01

Full Text Available Abstract Continental flood basalts (CFB are considered as potential CO2 storage sites because of their high reactivity and abundant divalent metal ions that can potentially trap carbon for geological timescales. Moreover, laterally extensive CFB are found in many place in the world within reasonable distances from major CO2 point emission sources. Based on the mineral and glass composition of the Columbia River Basalt (CRB we estimated the potential of CFB to store CO2 in secondary carbonates. We simulated the system using kinetic dependent dissolution of primary basalt-minerals (pyroxene, feldspar and glass and the local equilibrium assumption for secondary phases (weathering products. The simulations were divided into closed-system batch simulations at a constant CO2 pressure of 100 bar with sensitivity studies of temperature and reactive surface area, an evaluation of the reactivity of H2O in scCO2, and finally 1D reactive diffusion simulations giving reactivity at CO2 pressures varying from 0 to 100 bar. Although the uncertainty in reactive surface area and corresponding reaction rates are large, we have estimated the potential for CO2 mineral storage and identified factors that control the maximum extent of carbonation. The simulations showed that formation of carbonates from basalt at 40 C may be limited to the formation of siderite and possibly FeMg carbonates. Calcium was largely consumed by zeolite and oxide instead of forming carbonates. At higher temperatures (60 – 100 C, magnesite is suggested to form together with siderite and ankerite. The maximum potential of CO2 stored as solid carbonates, if CO2 is supplied to the reactions unlimited, is shown to depend on the availability of pore space as the hydration and carbonation reactions increase the solid volume and clog the pore space. For systems such as in the scCO2 phase with limited amount of water, the total carbonation potential is limited by the amount of water present

An econometric time-series analysis of global CO2 concentrations and emissions

International Nuclear Information System (INIS)

Cohen, B.C.; Labys, W.C.; Eliste, P.

2001-01-01

This paper extends previous work on the econometric modelling of CO 2 concentrations and emissions. The importance of such work rests in the fact that models of the Cohen-Labys variety represent the only alternative to scientific or physical models of CO 2 accumulations whose parameters are inferred rather than estimated. The stimulation for this study derives from the recent discovery of oscillations and cycles in the net biospheric flux of CO 2 . A variety of time series tests is thus used to search for the presence of normality, stationarity, cyclicality and stochastic processes in global CO 2 emissions and concentrations series. Given the evidence for cyclicality of a short-run nature in the spectra of these series, both structural time series and error correction model are applied to confirm the frequency and amplitude of these cycles. Our results suggest new possibilities for determining equilibrium levels of CO 2 concentrations and subsequently revising stabilization policies. (Author)

An Atmospheric CO2 Record Across the End-Cretaceous Extinction

Science.gov (United States)

Royer, D. L.; Milligan, J. N.; Kowalczyk, J.

2017-12-01

A bolide impact and flood-basalt emissions likely caused large changes to the end-Cretaceous carbon cycle. Presently, there is only one proxy record for atmospheric CO2 that captures these changes (Beerling et al., 2002, PNAS 99: 7836-7840). These authors estimated CO2 from the calibrated stomatal indices of Ginkgo dated to within 105 yrs before and after the extinction ( 300-500 ppm) in addition to that of Stenochlaena, a fern disaster taxa present in the Raton Basin, New Mexico, 2300 ppm). We revisited these fossil collections and applied a newer and more robust CO2 proxy that is based on leaf gas-exchange principles and does not require calibrations with present-day species (Franks et al., 2014, Geophys Res Lett 41: 4685-4694). We reconstruct pre- and post-extinction CO2 concentrations of 650 ppm from Ginkgo, compared to 850 ppm directly after the extinction from Stenochlaena. This change in CO2 of 200 ppm can be readily explained with carbon cycle models as a consequence of either the bolide impact or flood-basalt emissions. Placing these CO2 estimates into the broader context of other leaf gas-exchange CO2 estimates for the Cenozoic, the Earth system sensitivity was 3 K per CO2 doubling during the early Paleogene, before steepening to >6 K several million years before the Eocene-Oligocene boundary.

Towards CO2 sequestration and applications of CO2 hydrates: the effects of tetrahydrofuran on the phase equilibria of CO2 hydrates

International Nuclear Information System (INIS)

Khalik, M.S.; Peters, C.J.

2006-01-01

The increasing quantity of carbon dioxide (CO 2 ) in the atmosphere has caused widespread global concerns. Capturing CO 2 from its sources and stored it in the form of gas hydrates and application of CO 2 hydrates are among the proposed methods to overcome this problem. In order to make hydrate-based process more attractive, the use of cyclic ethers as promoters is suggested to reduce the required hydrate formation pressure and enhancing the corresponding kinetic rate. In the present work, tetrahydrofuran (THF) is chosen as a hydrate promoter, participating in forming hydrates and produces mixed hydrate together with CO 2 . The pressure and temperature ranges of hydrate stability region are carefully determined through phase equilibrium measurement of the ternary CO 2 , tetrahydrofuran (THF) and water systems. From the experimental results, it is confirmed that the presence of THF in CO 2 + water systems will extend the hydrate formation region to higher temperature at a constant pressure. The extension of the hydrate stability region is depended on the overall concentration of the ternary system. Moreover, four-phase equilibrium of H-Lw-Lv-V is observed in the system, which may be due to a liquid phase split. In the region where the four-phase equilibrium exists, the ternary system loses its concentration dependency of the hydrate equilibrium conditions. (Author)

Multishelled CaO Microspheres Stabilized by Atomic Layer Deposition of Al2 O3 for Enhanced CO2 Capture Performance.

Science.gov (United States)

Armutlulu, Andac; Naeem, Muhammad Awais; Liu, Hsueh-Ju; Kim, Sung Min; Kierzkowska, Agnieszka; Fedorov, Alexey; Müller, Christoph R

2017-11-01

CO 2 capture and storage is a promising concept to reduce anthropogenic CO 2 emissions. The most established technology for capturing CO 2 relies on amine scrubbing that is, however, associated with high costs. Technoeconomic studies show that using CaO as a high-temperature CO 2 sorbent can significantly reduce the costs of CO 2 capture. A serious disadvantage of CaO derived from earth-abundant precursors, e.g., limestone, is the rapid, sintering-induced decay of its cyclic CO 2 uptake. Here, a template-assisted hydrothermal approach to develop CaO-based sorbents exhibiting a very high and cyclically stable CO 2 uptake is exploited. The morphological characteristics of these sorbents, i.e., a porous shell comprised of CaO nanoparticles coated by a thin layer of Al 2 O 3 (<3 nm) containing a central void, ensure (i) minimal diffusion limitations, (ii) space to accompany the substantial volumetric changes during CO 2 capture and release, and (iii) a minimal quantity of Al 2 O 3 for structural stabilization, thus maximizing the fraction of CO 2 -capture-active CaO. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

CO2 Absorption by Biphasic Solvents: Comparison with Lower Phase Alone

International Nuclear Information System (INIS)

Xu, Zhicheng; Wang, Shujuan; Qi, Guojie; Liu, Jinzhao; Zhao, Bo; Chen, Changhe

2014-01-01

The mixtures of 2 M 1,4-butanediamine (BDA) and 4 M 2-(diethylamino)-ethanol (DEEA) have been found to be promising biphasic solvents. This work identifies the composition of the lower phase using a DX-120 Ion Chromatograph (IC) and a Metrohm 809 Titrando auto titrator. The cyclic capacities, cyclic loadings and reaction products of the biphasic solvent are compared with those of the aqueous solution with the same amine concentration as the lower phase of the biphasic solvent at the rich loading ((2B4D) L ) using a fast screening facility and a JNM ECA-600 Nuclear Magnetic Resonance spectrometer (NMR). Their absorption rates at different loadings are also investigated using a Wetted Wall Column (WWC). The results show that the cyclic capacity and cyclic loading of (2B4D) L are almost the same as those of 2B4D. The absorption rate of (2B4D) L is higher than 2B4D at all the 3 tested loadings, except for the fresh solutions at CO 2 pressure lower than 10 kPa. NMR results show that the reaction products of (2B4D) L had more BDA bi-carbamate, less BDA and less BDA carbamate than 2B4D. The CO 2 reaction products of (2B4D) L had twice as much carbonate/bicarbonate as with 2B4D and less BDA carbamate. (authors)

CO2 Huff-n-Puff process in a light oil shallow shelf carbonate reservoir. Annual report, January 1, 1995--December 31, 1995

Energy Technology Data Exchange (ETDEWEB)

Wehner, S.C.; Boomer, R.J.; Cole, R.; Preiditus, J.; Vogt, J.

1996-09-01

The application of cyclic CO{sub 2}, often referred to as the CO{sub 2} Huff-n-Puff process, may find its niche in the maturing waterfloods of the Permian Basin. Coupling the CO{sub 2} H-n-P process to miscible flooding applications could provide the needed revenue to sufficiently mitigate near-term negative cash flow concerns in the capital intensive miscible projects. Texaco Exploration & Production Inc. and the U.S. Department of Energy have teamed up in an attempt to develop the CO{sub 2} Huff-n-Puff process in the Grayburg/San Andres formation; a light oil, shallow shelf carbonate reservoir within the Permian Basin. This cost-shared effort is intended to demonstrate the viability of this underutilized technology in a specific class of domestic reservoir. A significant amount of oil reserves are located in carbonate reservoirs. Specifically, the carbonates deposited in shallow shelf (SSC) environments make up the largest percentage of known reservoirs within the Permian Basin of North America. Many of these known resources have been under waterflooding operations for decades and are at risk of abandonment if crude oil recoveries cannot be economically enhanced. The selected site for this demonstration project is the Central Vacuum Unit waterflood in Lea County, New Mexico.

Recycling CO 2 ? Computational Considerations of the Activation of CO 2 with Homogeneous Transition Metal Catalysts

KAUST Repository

Drees, Markus

2012-08-10

Faced with depleting fossil carbon sources, the search for alternative energy carriers and energy storage possibilities has become an important issue. Nature utilizes carbon dioxide as starting material for storing sun energy in plant hydrocarbons. A similar approach, storing energy from renewable sources in chemical bonds with CO 2 as starting material, may lead to partial recycling of CO 2 created by human industrial activities. Unfortunately, currently available routes for the transformation of CO 2 involve high temperatures and are often not selective. With the development of more sophisticated methods and better software, theoretical studies have become both increasingly widespread and useful. This concept article summarizes theoretical investigations of the current state of the feasibility of CO 2 activation with molecular transition metal catalysts, highlighting the most promising reactions of CO 2 with olefins to industrially relevant acrylic acid/acrylates, and the insertion of CO 2 into metal-element bonds, particularly for the synthesis of cyclic carbonates and polymers. Rapidly improving computational power and methods help to increase the importance and accuracy of calculations continuously and make computational chemistry a useful tool helping to solve some of the most important questions for the future. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

CO2 Capture by Cement Raw Meal

DEFF Research Database (Denmark)

Pathi, Sharat Kumar; Lin, Weigang; Illerup, Jytte Boll

2013-01-01

The cement industry is one of the major sources of CO2 emissions and is likely to contribute to further increases in the near future. The carbonate looping process has the potential to capture CO2 emissions from the cement industry, in which raw meal for cement production could be used...... as the sorbent. Cyclic experiments were carried out in a TGA apparatus using industrial cement raw meal and synthetic raw meal as sorbents, with limestone as the reference. The results show that the CO2 capture capacities of the cement raw meal and the synthetic raw meal are comparable to those of pure limestone...... that raw meal could be used as a sorbent for the easy integration of the carbonate looping process into the cement pyro process for reducing CO2 emissions from the cement production process....

Flexible and High Performance Supercapacitors Based on NiCo2O4for Wide Temperature Range Applications

Science.gov (United States)

Gupta, Ram K.; Candler, John; Palchoudhury, Soubantika; Ramasamy, Karthik; Gupta, Bipin Kumar

2015-10-01

Binder free nanostructured NiCo2O4 were grown using a facile hydrothermal technique. X-ray diffraction patterns confirmed the phase purity of NiCo2O4. The surface morphology and microstructure of the NiCo2O4 analyzed by scanning electron microscopy (SEM) showed flower-like morphology composed of needle-like structures. The potential application of binder free NiCo2O4 as an electrode for supercapacitor devices was investigated using electrochemical methods. The cyclic voltammograms of NiCo2O4 electrode using alkaline aqueous electrolytes showed the presence of redox peaks suggesting pseudocapacitance behavior. Quasi-solid state supercapacitor device fabricated by sandwiching two NiCo2O4 electrodes and separating them by ion transporting layer. The performance of the device was tested using cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy. The device showed excellent flexibility and cyclic stability. The temperature dependent charge storage capacity was measured for their variable temperature applications. Specific capacitance of the device was enhanced by ~150% on raising the temperature from 20 to 60 °C. Hence, the results suggest that NiCo2O4 grown under these conditions could be a suitable material for high performance supercapacitor devices that can be operated at variable temperatures.

Improving Gas Flooding Efficiency

Energy Technology Data Exchange (ETDEWEB)

Reid Grigg; Robert Svec; Zheng Zeng; Alexander Mikhalin; Yi Lin; Guoqiang Yin; Solomon Ampir; Rashid Kassim

2008-03-31

This study focuses on laboratory studies with related analytical and numerical models, as well as work with operators for field tests to enhance our understanding of and capabilities for more efficient enhanced oil recovery (EOR). Much of the work has been performed at reservoir conditions. This includes a bubble chamber and several core flood apparatus developed or modified to measure interfacial tension (IFT), critical micelle concentration (CMC), foam durability, surfactant sorption at reservoir conditions, and pressure and temperature effects on foam systems.Carbon dioxide and N{sub 2} systems have been considered, under both miscible and immiscible conditions. The injection of CO2 into brine-saturated sandstone and carbonate core results in brine saturation reduction in the range of 62 to 82% brine in the tests presented in this paper. In each test, over 90% of the reduction occurred with less than 0.5 PV of CO{sub 2} injected, with very little additional brine production after 0.5 PV of CO{sub 2} injected. Adsorption of all considered surfactant is a significant problem. Most of the effect is reversible, but the amount required for foaming is large in terms of volume and cost for all considered surfactants. Some foams increase resistance to the value beyond what is practical in the reservoir. Sandstone, limestone, and dolomite core samples were tested. Dissolution of reservoir rock and/or cement, especially carbonates, under acid conditions of CO2 injection is a potential problem in CO2 injection into geological formations. Another potential change in reservoir injectivity and productivity will be the precipitation of dissolved carbonates as the brine flows and pressure decreases. The results of this report provide methods for determining surfactant sorption and can be used to aid in the determination of surfactant requirements for reservoir use in a CO{sub 2}-foam flood for mobility control. It also provides data to be used to determine rock permeability

Loss of CO2 sensing by the olfactory system of CNGA3 knockout mice

Directory of Open Access Journals (Sweden)

Jinlong HAN, Minmin LUO

2010-12-01

Full Text Available Atmospheric CO2 can signal the presence of food, predators or environmental stress and trigger stereotypical behaviors in both vertebrates and invertebrates. Recent studies have shown that the necklace olfactory system in mice sensitively detects CO2 in the air. Olfactory CO2 neurons are believed to rely on cyclic guanosine monophosphate (cGMP as the key second messenger; however, the specific ion channel underlying CO­2 responses remains unclear. Here we show that CO2-evoked neuronal and behavioral responses require cyclic nucleotide-gated (CNG channels consisting of the CNGA3 subunit. Through Ca2+-imaging, we found that CO2-triggered Ca2+ influx was abolished in necklace olfactory sensory neurons (OSNs of CNGA3-knockout mice. Olfactory detection tests using a Go/No-go paradigm showed that these knockout mice failed to detect 0.5% CO2. Thus, sensitive detection of atmospheric CO2 depends on the function of CNG channels consisting of the CNGA3 subunit in necklace OSNs. These data support the important role of the necklace olfactory system in CO2 sensing and extend our understanding of the signal transduction pathway mediating CO2 detection in mammals [Current Zoology 56 (6: 793–799, 2010].

Quantum Codes From Cyclic Codes Over The Ring R 2

International Nuclear Information System (INIS)

Altinel, Alev; Güzeltepe, Murat

2016-01-01

Let R 2 denotes the ring F 2 + μF 2 + υ 2 + μυ F 2 + wF 2 + μwF 2 + υwF 2 + μυwF 2 . In this study, we construct quantum codes from cyclic codes over the ring R 2 , for arbitrary length n, with the restrictions μ 2 = 0, υ 2 = 0, w 2 = 0, μυ = υμ, μw = wμ, υw = wυ and μ (υw) = (μυ) w. Also, we give a necessary and sufficient condition for cyclic codes over R 2 that contains its dual. As a final point, we obtain the parameters of quantum error-correcting codes from cyclic codes over R 2 and we give an example of quantum error-correcting codes form cyclic codes over R 2 . (paper)

A Co-Opted Hormonal Cascade Activates Dormant Adventitious Root Primordia upon Flooding in Solanum dulcamara1[OPEN

Science.gov (United States)

Dawood, Thikra; Kensche, Philip R.; Cristescu, Simona M.; Mariani, Celestina

2016-01-01

Soil flooding is a common stress factor affecting plants. To sustain root function in the hypoxic environment, flooding-tolerant plants may form new, aerenchymatous adventitious roots (ARs), originating from preformed, dormant primordia on the stem. We investigated the signaling pathway behind AR primordium reactivation in the dicot species Solanum dulcamara. Transcriptome analysis indicated that flooding imposes a state of quiescence on the stem tissue, while increasing cellular activity in the AR primordia. Flooding led to ethylene accumulation in the lower stem region and subsequently to a drop in abscisic acid (ABA) level in both stem and AR primordia tissue. Whereas ABA treatment prevented activation of AR primordia by flooding, inhibition of ABA synthesis was sufficient to activate them in absence of flooding. Together, this reveals that there is a highly tissue-specific response to reduced ABA levels. The central role for ABA in the response differentiates the pathway identified here from the AR emergence pathway known from rice (Oryza sativa). Flooding and ethylene treatment also induced expression of the polar auxin transporter PIN2, and silencing of this gene or chemical inhibition of auxin transport inhibited primordium activation, even though ABA levels were reduced. Auxin treatment, however, was not sufficient for AR emergence, indicating that the auxin pathway acts in parallel with the requirement for ABA reduction. In conclusion, adaptation of S. dulcamara to wet habitats involved co-option of a hormonal signaling cascade well known to regulate shoot growth responses, to direct a root developmental program upon soil flooding. PMID:26850278

Geologic CO2 Sequestration: Predicting and Confirming Performance in Oil Reservoirs and Saline Aquifers

Science.gov (United States)

Johnson, J. W.; Nitao, J. J.; Newmark, R. L.; Kirkendall, B. A.; Nimz, G. J.; Knauss, K. G.; Ziagos, J. P.

2002-05-01

Reducing anthropogenic CO2 emissions ranks high among the grand scientific challenges of this century. In the near-term, significant reductions can only be achieved through innovative sequestration strategies that prevent atmospheric release of large-scale CO2 waste streams. Among such strategies, injection into confined geologic formations represents arguably the most promising alternative; and among potential geologic storage sites, oil reservoirs and saline aquifers represent the most attractive targets. Oil reservoirs offer a unique "win-win" approach because CO2 flooding is an effective technique of enhanced oil recovery (EOR), while saline aquifers offer immense storage capacity and widespread distribution. Although CO2-flood EOR has been widely used in the Permian Basin and elsewhere since the 1980s, the oil industry has just recently become concerned with the significant fraction of injected CO2 that eludes recycling and is therefore sequestered. This "lost" CO2 now has potential economic value in the growing emissions credit market; hence, the industry's emerging interest in recasting CO2 floods as co-optimized EOR/sequestration projects. The world's first saline aquifer storage project was also catalyzed in part by economics: Norway's newly imposed atmospheric emissions tax, which spurred development of Statoil's unique North Sea Sleipner facility in 1996. Successful implementation of geologic sequestration projects hinges on development of advanced predictive models and a diverse set of remote sensing, in situ sampling, and experimental techniques. The models are needed to design and forecast long-term sequestration performance; the monitoring techniques are required to confirm and refine model predictions and to ensure compliance with environmental regulations. We have developed a unique reactive transport modeling capability for predicting sequestration performance in saline aquifers, and used it to simulate CO2 injection at Sleipner; we are now

Nitration Study of Cyclic Ladder Polyphenylsilsesquioxane

Directory of Open Access Journals (Sweden)

LIANG Jia-xiang

2017-05-01

Full Text Available Several nitration reagents including fuming nitric acid, HNO3-H2SO4, KNO3-H2SO4, HNO3-KNO3, CH3COOH-KNO3, (CH3CO2O-HNO3 were used to nitrate cyclic ladder polyphenylsilsesquioxane (CL-PPSQ in different conditions in order to enhance the compatibility of the CL-PPSQ in polymers, the NO2-PPSQ was obtained. FTIR, element analysis, GPC, TGA and 1H NMR were used to characterize the structures of the nitrated products. The results show that the nitrating abilities of the fuming nitric acid, HNO3-H2SO4 and KNO3-H2SO4 are very strong. Many nitro groups can be linked with phenyl groups in CL-PPSQ, but with low molecular mass, fracture occurs in siloxane segment. However, the Mn of the product NO2-PPSQ sharply drops by 50% compared with that of CL-PPSQ, so the nitration reagents can break the cyclic structure of CL-PPSQ. The nitrating reagents of HNO3-KNO3 and CH3COOH-KNO3 have no nitration effects on CL-PPSQ. At last, NO2-CL-PPSQ was prepared using (CH3CO2O-HNO3 because of the moderate nitration process and ability. The cyclic structure of PPSQ is remained, although the number of —NO2 group is not too much. At the same time, the nitration mechanism using different nitration reagents was analyzed. A certain amount of NO2+, which is a kind of activator owning strong nitration ability, can be found in the fuming nitric acid and H2SO4-HNO3(KNO3 systems. As to the (CH3CO2O-HNO3 system, the main activator is CH3COONO2.

Development of an Advanced Simulator to Model Mobility Control and Geomechanics during CO{sub 2} Floods

Energy Technology Data Exchange (ETDEWEB)

Delshad, Mojdeh; Wheeler, Mary; Sepehrnoori, Kamy; Pope, Gary

2013-12-31

The simulator is an isothermal, three-dimensional, four-phase, compositional, equation-of– state (EOS) simulator. We have named the simulator UTDOE-CO2 capable of simulating various recovery processes (i.e., primary, secondary waterflooding, and miscible and immiscible gas flooding). We include both the Peng-Robinson EOS and the Redlich-Kwong EOS models. A Gibbs stability test is also included in the model to perform a phase identification test to consistently label each phase for subsequent property calculations such as relative permeability, viscosity, density, interfacial tension, and capillary pressure. Our time step strategy is based on an IMPEC-type method (implicit pressure and explicit concentration). The gridblock pressure is solved first using the explicit dating of saturation-dependent terms. Subsequently, the material balance equations are solved explicitly for the total concentration of each component. The physical dispersion term is also included in the governing equations. The simulator includes (1) several foam model(s) for gas mobility control, (2) compositional relative permeability models with the hysteresis option, (3) corner point grid and several efficient solvers, (4) geomechanics module to compute stress field as the result of CO{sub 2} injection/production, (5) the format of commercial visualization software, S3graf from Science-soft Ltd., was implemented for user friendly visualization of the simulation results. All tasks are completed and the simulator was fully tested and delivered to the DOE office including a user’s guide and several input files and the executable for Windows Pcs. We have published several SPE papers, presented several posters, and one MS thesis is completed (V. Pudugramam, 2013) resulting from this DOE funded project.

The arabidopsis cyclic nucleotide interactome

KAUST Repository

Donaldson, Lara Elizabeth

2016-05-11

Background Cyclic nucleotides have been shown to play important signaling roles in many physiological processes in plants including photosynthesis and defence. Despite this, little is known about cyclic nucleotide-dependent signaling mechanisms in plants since the downstream target proteins remain unknown. This is largely due to the fact that bioinformatics searches fail to identify plant homologs of protein kinases and phosphodiesterases that are the main targets of cyclic nucleotides in animals. Methods An affinity purification technique was used to identify cyclic nucleotide binding proteins in Arabidopsis thaliana. The identified proteins were subjected to a computational analysis that included a sequence, transcriptional co-expression and functional annotation analysis in order to assess their potential role in plant cyclic nucleotide signaling. Results A total of twelve cyclic nucleotide binding proteins were identified experimentally including key enzymes in the Calvin cycle and photorespiration pathway. Importantly, eight of the twelve proteins were shown to contain putative cyclic nucleotide binding domains. Moreover, the identified proteins are post-translationally modified by nitric oxide, transcriptionally co-expressed and annotated to function in hydrogen peroxide signaling and the defence response. The activity of one of these proteins, GLYGOLATE OXIDASE 1, a photorespiratory enzyme that produces hydrogen peroxide in response to Pseudomonas, was shown to be repressed by a combination of cGMP and nitric oxide treatment. Conclusions We propose that the identified proteins function together as points of cross-talk between cyclic nucleotide, nitric oxide and reactive oxygen species signaling during the defence response.

The Wolff rearrangement of cyclic 2-diazo-1,3-diketones in electron impact - mass spectrometry - controlling the molecular fragmentation by means of low-energy electrons 18 to 70 eV

International Nuclear Information System (INIS)

Kuruc, J.; Kardosova, E.; Nikolaev, V. A.

2016-01-01

The electron-impact-induced fragmentations (the mass spectra, 17 - 70 eV) of cyclic 2-diazo-1,3-diketones were studied. As the suitable compounds were selected the following cyclic 2-diazo-1,3-diketones: 2-diazo-1,3-cyclohexanedione, Ia; 2-diazo-4,4-dimethyl-1,3-cyclohexanedione, Ib; 2-diazo-5,5-dimethyl-1,3-cyclohexanedione, Ic; 2-diazo-4,6-dioxa-5,5-dimethyl-1,3-cyclohexanedione, Id; and 2-diazo-5-phenyl-1,3-cyclohexanedione, Ie). The mass spectra were measured with Varian MAT 111 instrument with direct introduction of samples, with a source temperature of 120 grad C, energy of ionising electrons was in the range (17 - 70) eV. The elimination of the diazo group is the typical reaction of the fragmentation of the cyclic diazo-1,3-diketones after ionization of molecules by electron impact. All our studied cyclic diazo-1,3-diketones have a molecular ion with a relative intensity from 0.7 to 86.4%. Typical ions are [M]"+·, [M-N"_2]"+"·, [M-N_2-CO]"+"·, [M-N_2-CO-CH_2]"+"·, [M-N_2-CO-CH_3]"+"·. For all treatment cyclic diazo-1,3-diketones have been registered 3D mass spectra, for each cyclic diazo-1,3-diketone was proposed fragmentation scheme, including the general fragmentation scheme. The Wolff rearrangement is observed in all studied cyclic diazo-1,3-diketones after cleavage of nitrogen molecules. The energy of ionizing electrons ∼20 eV in the case of compounds Ib, Id - Ie dominating ions are fragments of the [M-N_2]"+"·, in the compound Ia at 18 and 20 eV is dominant fragment [M-N_2-CO-C_2H_2-H]"+"· and for the Ic at 30 eV becomes a dominant fragment [M-N_2-CH_3]"+"· (m/z = 123) but at (25 - 18) eV the most intensive ion is [M-N_2]"+"· (m/z = 138). (authors)

Adenosine 3':5'-cyclic monophosphate in higher plants: Isolation and characterization of adenosine 3':5'-cyclic monophosphate from Kalanchoe and Agave.

Science.gov (United States)

Ashton, A R; Polya, G M

1977-01-01

1.3':5'-Cyclic AMP was extensively purified from Kalanchoe daigremontiana and Agave americana by neutral alumina and anion- and cation-exchange column chromatography. Inclusion of 3':5'-cyclic [8-3H]AMP from the point of tissue extraction permitted calculation of yields. The purification procedure removed contaminating material that was shown to interfere with the 3':5'-cyclic AMP estimation and characterization procedures. 2. The partially purified 3':5'-cyclic AMP was quantified by means of a radiochemical saturation assay using an ox heart 3':5'-cyclic AMP-binding protein and by an assay involving activation of a mammalian protein kinase. 3. The plant 3':5'-cyclic AMP co-migrated with 3':5'-cyclic [8-3H]AMP on cellulose chromatography, poly(ethyleneimine)-cellulose chromatography and silica-gel t.l.c. developed with several solvent systems. 4. The plant 3':5'-cyclic AMP was degraded by ox heart 3':5'-cyclic nucleotide phosphodiesterase at the same rates as authentic 3':5'-cyclic AMP. 1-Methyl-3-isobutylxanthine (1 mM), a specific inhibitor of the 3':5'-cyclic nucleotide phosphodieterase, completely inhibited such degradation. 5. The concentrations of 3':5'-cyclic AMP satisfying the above criteria in Kalanchoe and Agave were 2-6 and 1 pmol/g fresh wt. respectively. Possible bacterial contribution to these analyses was estimated to be less than 0.002pmol/g fresh wt. Evidence for the occurrence of 3':5'-cyclic AMP in plants is discussed. PMID:196595

Protection of neuroblastoma Neuro2A cells from hypoxia-induced apoptosis by cyclic phosphatidic acid (cPA.

Directory of Open Access Journals (Sweden)

Mari Gotoh

Full Text Available Cyclic phosphatidic acid (cPA is a naturally occurring phospholipid mediator with a unique cyclic phosphate ring at the sn-2 and sn-3 positions of its glycerol backbone. We have previously shown that cPA significantly suppresses ischemia-induced delayed neuronal death and the accumulation of glial fibrillary acidic protein in the CA1 region of the rat hippocampus. These results indicated that the systemic administration of cPA can protect hippocampal neurons against ischemia-induced delayed neuronal cell death. In the current study, we investigated the effects of cPA on neuronal cell death caused by hypoxia in vitro and the molecular mechanisms underlying these effects. We used cobalt chloride (CoCl(2 to expose cells to hypoxic conditions in vitro. Treating mouse neuroblastoma (Neuro2A cells with CoCl(2 induced nuclear DNA condensation and phosphatidylserine exposure. However, adding cPA led to the suppression of CoCl(2-induced apoptosis in a cPA dose-dependent manner and attenuated the increase in the Bax/Bcl-2 ratio caused by CoCl(2. Quantitative PCR analysis showed that Neuro2A cells strongly express the LPA(1, LPA(2, and LPA(6, which are G-protein coupled receptors that can be activated by cPA. To date, LPA(1 and LPA(2 have been reported to exhibit antiapoptotic activity. Therefore, to assess the roles of LPA(1 and LPA(2 on cPA-induced neuroprotective functions, Ki16425, a selective LPA(1 and LPA(3 antagonist, was adopted to know the LPA(1 function and siRNA was used to knockdown the expression of LPA(2. On the basis of our results, we propose that cPA-induced protection of Neuro2A cells from CoCl(2-induced hypoxia damage is mediated via LPA(2.

2 Dimensional Hydrodynamic Flood Routing Analysis on Flood Forecasting Modelling for Kelantan River Basin

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Azad Wan Hazdy

2017-01-01

Full Text Available Flood disaster occurs quite frequently in Malaysia and has been categorized as the most threatening natural disaster compared to landslides, hurricanes, tsunami, haze and others. A study by Department of Irrigation and Drainage (DID show that 9% of land areas in Malaysia are prone to flood which may affect approximately 4.9 million of the population. 2 Dimensional floods routing modelling demonstrate is turning out to be broadly utilized for flood plain display and is an extremely viable device for evaluating flood. Flood propagations can be better understood by simulating the flow and water level by using hydrodynamic modelling. The hydrodynamic flood routing can be recognized by the spatial complexity of the schematization such as 1D model and 2D model. It was found that most of available hydrological models for flood forecasting are more focus on short duration as compared to long duration hydrological model using the Probabilistic Distribution Moisture Model (PDM. The aim of this paper is to discuss preliminary findings on development of flood forecasting model using Probabilistic Distribution Moisture Model (PDM for Kelantan river basin. Among the findings discuss in this paper includes preliminary calibrated PDM model, which performed reasonably for the Dec 2014, but underestimated the peak flows. Apart from that, this paper also discusses findings on Soil Moisture Deficit (SMD and flood plain analysis. Flood forecasting is the complex process that begins with an understanding of the geographical makeup of the catchment and knowledge of the preferential regions of heavy rainfall and flood behaviour for the area of responsibility. Therefore, to decreases the uncertainty in the model output, so it is important to increase the complexity of the model.

Preparation of Cyclic Urethanes from Amino Alcohols and Carbon Dioxide Using Ionic Liquid Catalysts with Alkali Metal Promoters

OpenAIRE

Masahiko Arai; Hisanori Senboku; Hiroshi Kanamaru; Shin-ichiro Fujita

2006-01-01

Several ionic liquids were applied as catalysts for the synthesis of cyclic urethanes from amino alcohols and pressurized CO2 in the presence of alkali metal compounds as promoters. A comparative study was made for the catalytic performance using different ionic liquids, substrates, promoters, and pressures. The optimum catalytic system was BMIM-Br promoted by K2CO3, which, for 1-amino-2-propanol, produced cyclic urethane in 40% yield with a smaller yield of substituted cyclic ...

Cyclic Oxidation of High Mo, Reduced Density Superalloys

Directory of Open Access Journals (Sweden)

James L. Smialek

2015-11-01

Full Text Available Cyclic oxidation was characterized as part of a statistically designed, 12-alloy compositional study of 2nd generation single crystal superalloys as part of a broader study to co-optimize density, creep strength, and cyclic oxidation. The primary modification was a replacement of 5 wt. % W by 7% or 12% Mo for density reductions of 2%–7%. Compositions at two levels of Mo, Cr, Co, and Re were produced, along with a midpoint composition. Initially, polycrystalline vacuum induction samples were screened in 1100 °C cyclic furnace tests using 1 h cycles for 200 h. The behavior was primarily delimited by Cr content, producing final weight changes of −40 mg/cm2 to −10 mg/cm2 for 0% Cr alloys and −2 mg/cm2 to +1 mg/cm2 for 5% Cr alloys. Accordingly, a multiple linear regression fit yielded an equation showing a strong positive Cr effect and lesser negative effects of Co and Mo. The results for 5% Cr alloys compare well to −1 mg/cm2, and +0.5 mg/cm2 for Rene′ N4 and Rene′ N5 (or Rene′ N6, respectively. Scale phases commonly identified were Al2O3, NiAl2O4, NiTa2O6, and NiO, with (Ni,CoMoO4 found only on the least resistant alloys having 0% Cr and 12% Mo. Scale microstructures were complex and reflected variations in the regional spallation history. Large faceted NiO grains and fine NiTa2O6 particles distributed along NiAl2O4 grain boundaries were typical distinctive features. NiMoO4 formation, decomposition, and volatility occurred for a few high Mo compositions. A creep, density, phase stability, and oxidation balanced 5% Cr, 10% Co, 7% Mo, and 3% Re alloy was selected to be taken forward for more extensive evaluations in single crystal form.

The real governance of disaster risk management in peri-urban Senegal: Delivering flood response services through co-production

DEFF Research Database (Denmark)

Schaer, Caroline; Hahonou, Eric Komlavi

2017-01-01

Disastrous and recurring floods have impacted West African urban centres over the last decade, accentuating already existing vulnerabilities in poor neighbourhoods. Climate change-induced changing weather patterns and more extreme weather events are only part of the explanation for this situation......, as large segments of the urban population in West Africa are not offered the public services, infrastructure and protective regulations needed in order to respond to floods. Through an empirically grounded approach, the article shows that the ability to respond to floods is formed largely outside the realm....... The article concludes that weak state capacity is not equivalent to non-existent of ungoverned collective services linked to floods. While flood response service delivery through co-production, may constitute the best available options in a context of poor resources, because of the negotiated character...

Chemisorption of H2O and CO2 on hydrotalcites for sorptionenhanced water-gas-shift processes

NARCIS (Netherlands)

Coenen, K.T.; Gallucci, F.; Cobden, P.; van Dijk, E; Hensen, E.J.M.; van Sint Annaland, M.

2017-01-01

Thermogravimetric analysis and breakthrough experiments in a packed bed reactor were used to validate a developed adsorption model to describe the cyclic working capacity of CO2 and H2O on a potassium-promoted hydrotalcite, a very promising adsorbent for sorption-enhanced water-gas-shift

CaO-based CO2 sorbents: from fundamentals to the development of new, highly effective materials.

Science.gov (United States)

Kierzkowska, Agnieszka M; Pacciani, Roberta; Müller, Christoph R

2013-07-01

The enormous anthropogenic emission of the greenhouse gas CO2 is most likely the main reason for climate change. Considering the continuing and indeed growing utilisation of fossil fuels for electricity generation and transportation purposes, development and implementation of processes that avoid the associated emissions of CO2 are urgently needed. CO2 capture and storage, commonly termed CCS, would be a possible mid-term solution to reduce the emissions of CO2 into the atmosphere. However, the costs associated with the currently available CO2 capture technology, that is, amine scrubbing, are prohibitively high, thus making the development of new CO2 sorbents a highly important research challenge. Indeed, CaO, readily obtained through the calcination of naturally occurring limestone, has been proposed as an alternative CO2 sorbent that could substantially reduce the costs of CO2 capture. However, one of the major drawbacks of using CaO derived from natural sources is its rapidly decreasing CO2 uptake capacity with repeated carbonation-calcination reactions. Here, we review the current understanding of fundamental aspects of the cyclic carbonation-calcination reactions of CaO such as its reversibility and kinetics. Subsequently, recent attempts to develop synthetic, CaO-based sorbents that possess high and cyclically stable CO2 uptakes are presented. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Cyclic Polymers: From Scientific Curiosity to Advanced Materials for Gene Delivery and Surface Modification.

Science.gov (United States)

Verbraeken, Bart; Hoogenboom, Richard

2017-06-12

Cyclic versus linear: The superiority of cyclic polymers over their linear counterparts is highlighted. Cyclic poly(2-oxazoline)s have been shown to provide excellent shielding properties when grafted to TiO 2 surfaces and Fe 3 O 4 nanoparticles owing to their ultrahigh grafting densities leading to low friction surfaces, superior antifouling properties, and extreme nanoparticle stabilization. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Cyclic oxidation behaviour of different treated CoNiCrAlY coatings

Energy Technology Data Exchange (ETDEWEB)

Marginean, G. [University of Applied Sciences Gelsenkirchen, Neidenburger Str. 43, 45877 Gelsenkirchen (Germany); Utu, D., E-mail: dutu@eng.upt.ro [University ' Politehnica' Timisoara, Faculty of Mechanical Engineering, Blv. Mihai Viteazu 1, 300222 Timisoara (Romania)

2012-08-01

High velocity oxygen fuel (HVOF) spraying method was used in order to obtain very dense and good adhesive CoNiCrAlY-coatings deposited onto nickel-based alloy. The coatings were differently treated (preoxidized, vacuum treated or electron beam irradiated) before their exposure to cyclic oxidation tests in air at 1000 Degree-Sign C for periods up to 5 h. Changes of the coatings morphology and structure were analysed by scanning electron microscopy (SEM) and X-ray diffraction technique (XRD). The surface temperature of the samples was measured during cooling, between the oxidation cycles, and finally was associated with the thickness of the grown protective oxide scale on the CoNiCrAlY-surface. The experimental results demonstrated that depending on the thickness respectively on the different structures of the grown oxide scale, the cooling rate of the sample surface will be different as well.

Impact of elevated CO2 and temperature on soil C and N dynamics in relation to CH4 and N2O emissions from tropical flooded rice (Oryza sativa L.).

Science.gov (United States)

Bhattacharyya, P; Roy, K S; Neogi, S; Dash, P K; Nayak, A K; Mohanty, S; Baig, M J; Sarkar, R K; Rao, K S

2013-09-01

A field experiment was carried out to investigate the impact of elevated carbon dioxide (CO2) (CEC, 550 μmol mol(-1)) and elevated CO2+elevated air temperature (CECT, 550 μmol mol(-1) and 2°C more than control chamber (CC)) on soil labile carbon (C) and nitrogen (N) pools, microbial populations and enzymatic activities in relation to emissions of methane (CH4) and nitrous oxide (N2O) in a flooded alluvial soil planted with rice cv. Naveen in open top chambers (OTCs). The labile soil C pools, namely microbial biomass C, readily mineralizable C, water soluble carbohydrate C and potassium permanganate oxidizable C were increased by 27, 23, 38 and 37% respectively under CEC than CC (ambient CO2, 394 μmol mol(-1)). The total organic carbon (TOC) in root exudates was 28.9% higher under CEC than CC. The labile N fractions were also increased significantly (29%) in CEC than CC. Methanogens and denitrifier populations in rhizosphere were higher under CEC and CECT. As a result, CH4 and N2O-N emissions were enhanced by 26 and 24.6% respectively, under CEC in comparison to open field (UC, ambient CO2, 394 μmol mol(-1)) on seasonal basis. The global warming potential (GWP) was increased by 25% under CEC than CC. However, emissions per unit of grain yield under elevated CO2 and temperature were similar to those observed at ambient CO2. The stimulatory effect on CH4 and N2O emissions under CEC was linked with the increased amount of soil labile C, C rich root exudates, lowered Eh, higher Fe(+2) concentration and increased activities of methanogens and extracellular enzymes. Copyright © 2013 Elsevier B.V. All rights reserved.

CHARACTERIZATION OF P2-PURINOCEPTOR MEDIATED CYCLIC-AMP FORMATION IN MOUSE C2C12 MYOTUBES

NARCIS (Netherlands)

HENNING, RH; DUIN, M; DENHERTOG, A; NELEMANS, A

1 The formation of adenosine 3':5'-cyclic monophosphate (cyclic AMP) and inositol(1,4,5)trisphosphate (Ins(1,4,5)P3), induced by ATP and other nucleotides was investigated in mouse C2Cl2 myotubes. 2 ATP (100 muM) and ATPgammaS (100 muM) caused a sustained increase in cyclic AMP content of the cells,

Ultrahigh volumetric capacitance and cyclic stability of fluorine and nitrogen co-doped carbon microspheres

Science.gov (United States)

Zhou, Junshuang; Lian, Jie; Hou, Li; Zhang, Junchuan; Gou, Huiyang; Xia, Meirong; Zhao, Yufeng; Strobel, Timothy A.; Tao, Lu; Gao, Faming

2015-09-01

Highly porous nanostructures with large surface areas are typically employed for electrical double-layer capacitors to improve gravimetric energy storage capacity; however, high surface area carbon-based electrodes result in poor volumetric capacitance because of the low packing density of porous materials. Here, we demonstrate ultrahigh volumetric capacitance of 521 F cm-3 in aqueous electrolytes for non-porous carbon microsphere electrodes co-doped with fluorine and nitrogen synthesized by low-temperature solvothermal route, rivaling expensive RuO2 or MnO2 pseudo-capacitors. The new electrodes also exhibit excellent cyclic stability without capacitance loss after 10,000 cycles in both acidic and basic electrolytes at a high charge current of 5 A g-1. This work provides a new approach for designing high-performance electrodes with exceptional volumetric capacitance with high mass loadings and charge rates for long-lived electrochemical energy storage systems.

Increased spring flooding of agricultural fields will exhibit altered production of greenhouse gases

Science.gov (United States)

Paul, R. F.; Smith, C. M.; Smyth, E. M.; Kantola, I. B.; DeLucia, E. H.

2013-12-01

The U.S. Corn Belt currently is a net source of carbon dioxide and nitrous oxide to the atmosphere, but is also a sink of methane. Among the proposed effects of climate change in the North American Midwest region is an increase in the frequency and duration of spring flooding events. This would cause ponding in fields which may change the greenhouse gas balance of the region, especially by providing a suitable anoxic environment for the proliferation of methanogens, increasing methane emissions. To determine whether methanogenesis occurs in flooded agricultural soils of the Midwest and how other gas fluxes are affected, we installed collars into the ground of a research field located in central Illinois. The control group was maintained at the same conditions as the surrounding field. Two groups of collars were sustained with water flooding the headspaces via a drip irrigation system; one treatment was analyzed for gas fluxes of CH4, N2O, and CO2 evolving from the collars, and a separate treatment of flooded collars was used for soil sampling. Comparing flooded soils versus control we measured reduced N2O fluxes (-3.12 x 10-6 × 6.8 x 10-7 g N m-2 min-1), reduced CO2 fluxes (-6.13 x 10-3 × 9.3 x 10-4 g CO2 m-2 min-1), and increased methane fluxes (+2.72 x 10-6 × 5.8 x 10-7 g CH4 m-2 min-1). After only one week of treatment the flooded soils switched from being sinks to sources of methane, which continued across the duration of the experiment. These preliminary results indicate that methanogenesis occurs in flooded agricultural fields, and suggest including regional modeling into further study. Although the global warming potential of methane is 25 times greater than CO2, our measured rates of methane production were compensated by reductions in nitrous oxide and CO2 fluxes, reducing the total 100-year horizon global warming potential of the flooded soils we studied by 64.8%. This indicates that accounting for more frequent seasonal ponding would significantly

Cyclic electron flow is redox-controlled but independent of state transition.

Science.gov (United States)

Takahashi, Hiroko; Clowez, Sophie; Wollman, Francis-André; Vallon, Olivier; Rappaport, Fabrice

2013-01-01

Photosynthesis is the biological process that feeds the biosphere with reduced carbon. The assimilation of CO2 requires the fine tuning of two co-existing functional modes: linear electron flow, which provides NADPH and ATP, and cyclic electron flow, which only sustains ATP synthesis. Although the importance of this fine tuning is appreciated, its mechanism remains equivocal. Here we show that cyclic electron flow as well as formation of supercomplexes, thought to contribute to the enhancement of cyclic electron flow, are promoted in reducing conditions with no correlation with the reorganization of the thylakoid membranes associated with the migration of antenna proteins towards Photosystems I or II, a process known as state transition. We show that cyclic electron flow is tuned by the redox power and this provides a mechanistic model applying to the entire green lineage including the vast majority of the cases in which state transition only involves a moderate fraction of the antenna.

Levels of cyclic-2,3-diphosphoglycerate in Methanobacterium thermoautotrophicum during phosphate limitation.

Science.gov (United States)

Seely, R J; Fahrney, D E

1984-10-01

Batch-grown Methanobacterium thermoautotrophicum cells grew nonexponentially in the absence of exogenous Pi until intracellular cyclic-2,3-diphosphoglycerate (cyclic DPG) had fallen below 2 mumol/g (dry weight), the limit of detection. Growth resumed immediately upon transfer to medium containing Pi Cyclic DPG levels were also below detection in Pi-limited chemostat cultures operating at a dilution rate of 0.173 h-1 (4-h doubling time), with reservoir Pi concentrations below 200 microM. At this dilution rate, the Pi concentration in the culture was 4 microM. An H2-limited steady state was achieved with 400 microM Pi in the inflowing medium (67 microM in the culture). The cyclic DPG content of these cells was 72 to 74 mumol/g, about one-third the amount in batch-grown cells. The specific growth rate accelerated immediately to 0.36 h-1 (1.9-h doubling time) under washout conditions at high dilution rate. The cellular content of cyclic DPG declined over a 2-h period, and then increased rapidly as the Pi level in the medium approached 200 microM. Expansion of the cyclic DPG pool coincided with a marked increase in Pi assimilation. These results indicated that M. thermoautotrophicum accumulated cyclic DPG only when Pi and H2 were readily available.

Levels of cyclic-2,3-diphosphoglycerate in Methanobacterium thermoautotrophicum during phosphate limitation.

Science.gov (United States)

Seely, R J; Fahrney, D E

1984-01-01

Batch-grown Methanobacterium thermoautotrophicum cells grew nonexponentially in the absence of exogenous Pi until intracellular cyclic-2,3-diphosphoglycerate (cyclic DPG) had fallen below 2 mumol/g (dry weight), the limit of detection. Growth resumed immediately upon transfer to medium containing Pi Cyclic DPG levels were also below detection in Pi-limited chemostat cultures operating at a dilution rate of 0.173 h-1 (4-h doubling time), with reservoir Pi concentrations below 200 microM. At this dilution rate, the Pi concentration in the culture was 4 microM. An H2-limited steady state was achieved with 400 microM Pi in the inflowing medium (67 microM in the culture). The cyclic DPG content of these cells was 72 to 74 mumol/g, about one-third the amount in batch-grown cells. The specific growth rate accelerated immediately to 0.36 h-1 (1.9-h doubling time) under washout conditions at high dilution rate. The cellular content of cyclic DPG declined over a 2-h period, and then increased rapidly as the Pi level in the medium approached 200 microM. Expansion of the cyclic DPG pool coincided with a marked increase in Pi assimilation. These results indicated that M. thermoautotrophicum accumulated cyclic DPG only when Pi and H2 were readily available. PMID:6480564

Camp Marmal Flood Study

Science.gov (United States)

2012-03-01

was simulated by means of a broad - crested weir built into the topography of the mesh. There is 0.5 m of freeboard and the width of the weir is 30 m...ER D C/ CH L TR -1 2- 5 Camp Marmal Flood Study Co as ta l a nd H yd ra ul ic s La bo ra to ry Jeremy A. Sharp , Steve H. Scott...Camp Marmal Flood Study Jeremy A. Sharp , Steve H. Scott, Mark R. Jourdan, and Gaurav Savant Coastal and Hydraulics Laboratory U.S. Army Engineer

RAPID Assessment of Extreme Reservoir Sedimentation Resulting from the September 2013 Flood, North St. Vrain Creek, CO

Science.gov (United States)

Rathburn, S. L.; McElroy, B. J.; Wohl, E.; Sutfin, N. A.; Huson, K.

2014-12-01

During mid-September 2013, approximately 360 mm of precipitation fell in the headwaters of the North St. Vrain drainage basin, Front Range, CO. Debris flows on steep hillslopes and extensive flooding along North St. Vrain Creek resulted in extreme sedimentation within Ralph Price Reservoir, municipal water supply for the City of Longmont. The event allows comparison of historical sedimentation with that of an unusually large flood because 1) no reservoir flushing has been conducted since dam construction, 2) reservoir stratigraphy chronicles uninterrupted delta deposition, and 3) this is the only on-channel reservoir with unimpeded, natural sediment flux from the Continental Divide to the mountain front in a basin with no significant historic flow modifications and land use impacts. Assessing the flood-related sedimentation prior to any dredging activities included coring the reservoir delta, a bathymetric survey of the delta, resistivity and ground penetrating radar surveys of the subaerial inlet deposit, and surveying tributary deposits. Over the 44-year life of the reservoir, two-thirds of the delta sedimentation is attributed to extreme discharges from the September 2013 storm. Total storm-derived reservoir sedimentation is approximately 275,000 m3, with 81% of that within the gravel-dominated inlet and 17% in the delta. Volumes of deposition within reservoir tributary inlets is negatively correlated with contributing area, possibly due to a lack of storage in these small basins (1-5 km2). Flood-related reservoir sedimentation will be compared to other research quantifying volumes from slope failures evident on post-storm lidar. Analysis of delta core samples will quantify organic carbon flux associated with the extreme discharge and develop a chronology of flood and fire disturbances for North St. Vrain basin. Applications of similar techniques are planned for two older Front Range reservoirs affected by the September flooding to fill knowledge gaps about

An in-situ IR study on the adsorption of CO2 and H2O on hydrotalcites

NARCIS (Netherlands)

Coenen, K.T.; Gallucci, F.; Mezari, B.; Hensen, E.J.M.; van Sint Annaland, M.

2018-01-01

In-situ IR technique was used to study the reversible adsorption of CO2 and H2O at elevated temperatures on a potassium-promoted hydrotalcite for its use in sorption-enhanced water-gas shift (SEWGS). It was found that mainly bidentate carbonate species are responsible for the reversible (cyclic)

Modelling CO2 emissions from water surface of a boreal hydroelectric reservoir.

Science.gov (United States)

Wang, Weifeng; Roulet, Nigel T; Kim, Youngil; Strachan, Ian B; Del Giorgio, Paul; Prairie, Yves T; Tremblay, Alain

2018-01-15

To quantify CO 2 emissions from water surface of a reservoir that was shaped by flooding the boreal landscape, we developed a daily time-step reservoir biogeochemistry model. We calibrated the model using the measured concentrations of dissolved organic and inorganic carbon (C) in a young boreal hydroelectric reservoir, Eastmain-1 (EM-1), in northern Quebec, Canada. We validated the model against observed CO 2 fluxes from an eddy covariance tower in the middle of EM-1. The model predicted the variability of CO 2 emissions reasonably well compared to the observations (root mean square error: 0.4-1.3gCm -2 day -1 , revised Willmott index: 0.16-0.55). In particular, we demonstrated that the annual reservoir surface effluxes were initially high, steeply declined in the first three years, and then steadily decreased to ~115gCm -2 yr -1 with increasing reservoir age over the estimated "engineering" reservoir lifetime (i.e., 100years). Sensitivity analyses revealed that increasing air temperature stimulated CO 2 emissions by enhancing CO 2 production in the water column and sediment, and extending the duration of open water period over which emissions occur. Increasing the amount of terrestrial organic C flooded can enhance benthic CO 2 fluxes and CO 2 emissions from the reservoir water surface, but the effects were not significant over the simulation period. The model is useful for the understanding of the mechanism of C dynamics in reservoirs and could be used to assist the hydro-power industry and others interested in the role of boreal hydroelectric reservoirs as sources of greenhouse gas emissions. Copyright © 2017 Elsevier B.V. All rights reserved.

Récupération assistée des hydrocarbures par injection de CO2. Aspects techniques et économiques Enhanced Hydrocarbon Recovery by CO2 Flooding. Technical and Economic Aspects

Directory of Open Access Journals (Sweden)

Simandoux P.

2006-11-01

encountered. This review brings out the principal characteristics of the process and the main difficulties encountered. A brief survey is made of ongoing research projects aimed at resolving these difficulties and at improving the process. The last part concentrates on the outlook for the application of CO2 flooding, and for this process are discussed, i. e. the performances and the field of application, the avaibility and cost of different potential CO2 sources, and an economic evaluation of the process.

Conversion of a moderately rewetted fen to a shallow lake - implications for net CO2 exchange

Science.gov (United States)

Koebsch, Franziska; Glatzel, Stephan; Hofmann, Joachim; Forbrich, Inke; Jurasinski, Gerald

2013-04-01

Extensive rewetting projects to re-establish the natural carbon (C) sequestration function of degraded peatlands are currently taking place in Europe and North-America. Year-round flooding provides a robust measure to prevent periods of drought that are associated with ongoing peat mineralization and to initiate the accumulation of new organic matter. Here, we present measurements of net carbon dioxide (CO2) exchange during the gradual conversion of a moderately rewetted fen to a shallow lake. When we started our measurements in 2009, mean growing season water level (MWGL) was 0 cm. In 2010 the site was flooded throughout the year with MWGL of 36 cm. Extraordinary strong rainfalls in July 2011 resulted in a further increase of MWGL to 56 cm. Measurements of net ecosystem exchange (NEE) were conducted during growing seasons (May-October) using the Eddy Covariance method. Information about vegetation vitality was deduced from the enhanced vegetation index (EVI) based on MODIS data. Ecosystem respiration (Reco) and gross ecosystem production (GEP) were high during vegetation period 2009 (1273.4 and -1572.1 g CO2-C m-2), but decreased by 61 and 46% respectively when the fen was flooded throughout 2010. Under water-logged conditions, heterotrophic respiration declines and gas exchange is limited. Moreover, flooding is a severe stress factor for plants and decreases autotrophic respiration and photosynthesis. However, in comparison to 2010, rates of Reco and GEP doubled during the beginning of growing season 2011, indicating plastic response strategies of wetland plants to flooding. Presumably, plants were not able to cope with the further increase of water levels to up to 120 cm in June/July 2011, resulting in another drop of GEP and Reco. The effects of plant vitality on GEP were confirmed by the remote sensed vegetation index. Throughout all three growing seasons, the fen was a distinct net CO2 sink (2009: -333.3±12.3, 2010: -294.1±8.4, -352.4±5.1 g CO2-C m-2

Soil CO2 Dynamics in a Tree Island Soil of the Pantanal: The Role of Soil Water Potential

Science.gov (United States)

Johnson, Mark S.; Couto, Eduardo Guimarães; Pinto Jr, Osvaldo B.; Milesi, Juliana; Santos Amorim, Ricardo S.; Messias, Indira A. M.; Biudes, Marcelo Sacardi

2013-01-01

The Pantanal is a biodiversity hotspot comprised of a mosaic of landforms that differ in vegetative assemblages and flooding dynamics. Tree islands provide refuge for terrestrial fauna during the flooding period and are particularly important to the regional ecosystem structure. Little soil CO2 research has been conducted in this region. We evaluated soil CO2 dynamics in relation to primary controlling environmental parameters (soil temperature and soil water). Soil respiration was computed using the gradient method using in situ infrared gas analyzers to directly measure CO2 concentration within the soil profile. Due to the cost of the sensors and associated equipment, this study was unreplicated. Rather, we focus on the temporal relationships between soil CO2 efflux and related environmental parameters. Soil CO2 efflux during the study averaged 3.53 µmol CO2 m−2 s−1, and was equivalent to an annual soil respiration of 1220 g C m−2 y−1. This efflux value, integrated over a year, is comparable to soil C stocks for 0–20 cm. Soil water potential was the measured parameter most strongly associated with soil CO2 concentrations, with high CO2 values observed only once soil water potential at the 10 cm depth approached zero. This relationship was exhibited across a spectrum of timescales and was found to be significant at a daily timescale across all seasons using conditional nonparametric spectral Granger causality analysis. Hydrology plays a significant role in controlling CO2 efflux from the tree island soil, with soil CO2 dynamics differing by wetting mechanism. During the wet-up period, direct precipitation infiltrates soil from above and results in pulses of CO2 efflux from soil. The annual flood arrives later, and saturates soil from below. While CO2 concentrations in soil grew very high under both wetting mechanisms, the change in soil CO2 efflux was only significant when soils were wet from above. PMID:23762259

Enzymatic degradation of cyclic 2,3-diphosphoglycerate to 2,3-diphosphoglycerate in Methanobacterium thermoautotrophicum

International Nuclear Information System (INIS)

Krishna Sastry, M.V.; Robertson, D.E.; Moynihan, J.A.; Roberts, M.F.

1992-01-01

2,3-Diphosphoglycerate (2,3-DPG) has been found to be the product of the enzymatic degradation of cyclic 2,3-diphosphoglycerate (cDPG) in the archaebacterium Methanobacterium thermoautotrophicum ΔH. Although 2,3-DPG has not previously been detected as a major soluble component of M. thermoautotrophicum, large pools accumulated at an incubation temperature of 50C. Under these conditions, cellular activity was significantly decreased; a return of the culture to the optimum growth temperature restored the 2,3-DPG pool back to original low levels and caused steady-state cDPG levels to increase again. While 13 CO 2 -pulse/ 12 CO 2 -chase experiments at 50C showed that the cDPG turned over, the appearance of 2,3-DPG at NMR-visible concentrations required at least 10 h. Production of 2,3-DPG in vivo was prevented by exposure of the cells to O 2 . the enzyme responsible for this hydrolysis of cDPG was purified by affinity chromatography and appears to be a 33-kDa protein. Activity was detected in the presence of oxygen and was enhanced by a solution of 1 M KCl, 25 mM MgCl 2 , and dithiothreitol. Both K m and V max have been determined at 37C; kinetics also indicate that in vitro the product, 2,3-DPG, is an inhibitor of cDPG hydrolysis. These findings are discussed in view of a proposed role for cDPG in methanogens

Study of Adsorbents for the Capture of CO2 in Post-combustion. Contribution of CIEMAT to Module 4 of the CENITCO2 Project

International Nuclear Information System (INIS)

Ruiz, E.; Marono, M.; Sanchez-Hervas, J. M.

2010-01-01

The main goal of CIEMAT within the CENIT-CO 2 project has been the development of a process for CO 2 capture from combustion flue gases by physical adsorption. In the first stage, screening studies to select promising adsorbents were carried out at laboratory scale, using simplified gas compositions. After that, pilot plant studies were performed using appropriate configurations of promising adsorbents under realistic conditions. CO 2 adsorption cyclic capacity of different adsorbents has been studied. Lastly, for the adsorbent selected as most promising, its cyclic efficiency and selectivity for CO 2 adsorption in the presence of other gaseous components (SO 2 , H 2 O, NO) of the combustion gas has been determined, as well as its performance along multiple sorption-desorption cycles in the presence of simulated combustion gas. None of the studied adsorbents, though being promising since they all have a capture efficiency of about 90%, seem to be susceptible of direct application to CO 2 capture by physical adsorption under conditions representative of gases exiting the desulphurization tower of conventional pulverized coal combustion plants. As an alternative, the development of hybrid and regenerable solid sorbents (physical-chemical adsorption) is proposed or the application of new technologies under development such as the electrochemical promotion in capturing CO 2 . (Author) 33 refs.

Hierarchical CuCo2O4 nanobelts as a supercapacitor electrode with high areal and specific capacitance

International Nuclear Information System (INIS)

Vijayakumar, Subbukalai; Lee, Seong-Hun; Ryu, Kwang-Sun

2015-01-01

Highlights: • First time we report the synthesis of CuCo 2 O 4 nanobelts using hydrothermal method. • The spinel CuCo 2 O 4 nanobelts exhibit maximum areal capacitance of 2.42 F cm −2 . • After 1800 cycles, 127% of the initial specific capacitance was retained. - Abstract: One dimensional hierarchical CuCo 2 O 4 nanobelt like architecture was synthesized via hydrothermal method. The synthesized nanomaterial was characterized using X-ray diffraction (XRD) analysis, field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM). The TEM image clearly shows the nanobelt like architecture of CuCo 2 O 4 . The supercapacitor properties of CuCo 2 O 4 nanobelts electrode were tested using cyclic voltammetry, charge-discharge and electrochemical impedance spectroscopy. The spinel CuCo 2 O 4 nanobelts exhibit maximum areal and specific capacitance of 2.42 F cm −2 (809 F g −1 ). After 1800 continuous charge-discharge cycles, 127% of the initial capacitance was retained. This superior electrochemical supercapacitor property is mainly due to increased surface area and ion transport of nanobelt like architecture. The charge transfer resistance (R ct ) value of CuCo 2 O 4 nanobelt electrode is 3.85 Ω. This high capacitance and cyclic stability demonstrate that the prepared CuCo 2 O 4 nanobelts are a promising candidate for supercapacitors.

Hurricane Harvey Riverine Flooding: Part 1 - Reconstruction of Hurricane Harvey Flooding for Harris County, TX using a GPU-accelerated 2D flood model for post-flood hazard analysis

Science.gov (United States)

Kalyanapu, A. J.; Dullo, T. T.; Gangrade, S.; Kao, S. C.; Marshall, R.; Islam, S. R.; Ghafoor, S. K.

2017-12-01

Hurricane Harvey that made landfall in the southern Texas this August is one of the most destructive hurricanes during the 2017 hurricane season. During its active period, many areas in coastal Texas region received more than 40 inches of rain. This downpour caused significant flooding resulting in about 77 casualties, displacing more than 30,000 people, inundating hundreds of thousands homes and is currently estimated to have caused more than $70 billion in direct damage. One of the significantly affected areas is Harris County where the city of Houston, TX is located. Covering over two HUC-8 drainage basins ( 2702 mi2), this county experienced more than 80% of its annual average rainfall during this event. This study presents an effort to reconstruct flooding caused by extreme rainfall due to Hurricane Harvey in Harris County, Texas. This computationally intensive task was performed at a 30-m spatial resolution using a rapid flood model called Flood2D-GPU, a graphics processing unit (GPU) accelerated model, on Oak Ridge National Laboratory's (ORNL) Titan Supercomputer. For this task, the hourly rainfall estimates from the National Center for Environmental Prediction Stage IV Quantitative Precipitation Estimate were fed into the Variable Infiltration Capacity (VIC) hydrologic model and Routing Application for Parallel computation of Discharge (RAPID) routing model to estimate flow hydrographs at 69 locations for Flood2D-GPU simulation. Preliminary results of the simulation including flood inundation extents, maps of flood depths and inundation duration will be presented. Future efforts will focus on calibrating and validating the simulation results and assessing the flood damage for better understanding the impacts made by Hurricane Harvey.

Study of Adsorbents for the Capture of CO{sub 2} in Post-combustion. Contribution of CIEMAT to Module 4 of the CENITCO{sub 2} Project; Estudio de Adsorbentes para la Captura de CO{sub 2} en Postcombustion. Contribucion del CIEMAT al Modulo 4 del Proyecto CENITCO{sub 2}

Energy Technology Data Exchange (ETDEWEB)

Ruiz, E; Marono, M; Sanchez-Hervas, J M

2010-07-01

The main goal of CIEMAT within the CENIT-CO{sub 2} project has been the development of a process for CO{sub 2} capture from combustion flue gases by physical adsorption. In the first stage, screening studies to select promising adsorbents were carried out at laboratory scale, using simplified gas compositions. After that, pilot plant studies were performed using appropriate configurations of promising adsorbents under realistic conditions. CO{sub 2} adsorption cyclic capacity of different adsorbents has been studied. Lastly, for the adsorbent selected as most promising, its cyclic efficiency and selectivity for CO{sub 2} adsorption in the presence of other gaseous components (SO{sub 2}, H{sub 2}O, NO) of the combustion gas has been determined, as well as its performance along multiple sorption-desorption cycles in the presence of simulated combustion gas. None of the studied adsorbents, though being promising since they all have a capture efficiency of about 90%, seem to be susceptible of direct application to CO{sub 2} capture by physical adsorption under conditions representative of gases exiting the desulphurization tower of conventional pulverized coal combustion plants. As an alternative, the development of hybrid and regenerable solid sorbents (physical-chemical adsorption) is proposed or the application of new technologies under development such as the electrochemical promotion in capturing CO{sub 2}. (Author) 33 refs.

Agricultural peatland restoration: effects of land-use change on greenhouse gas (CO2 and CH4) fluxes in the Sacramento-San Joaquin Delta.

Science.gov (United States)

Knox, Sara Helen; Sturtevant, Cove; Matthes, Jaclyn Hatala; Koteen, Laurie; Verfaillie, Joseph; Baldocchi, Dennis

2015-02-01

Agricultural drainage of organic soils has resulted in vast soil subsidence and contributed to increased atmospheric carbon dioxide (CO2) concentrations. The Sacramento-San Joaquin Delta in California was drained over a century ago for agriculture and human settlement and has since experienced subsidence rates that are among the highest in the world. It is recognized that drained agriculture in the Delta is unsustainable in the long-term, and to help reverse subsidence and capture carbon (C) there is an interest in restoring drained agricultural land-use types to flooded conditions. However, flooding may increase methane (CH4) emissions. We conducted a full year of simultaneous eddy covariance measurements at two conventional drained agricultural peatlands (a pasture and a corn field) and three flooded land-use types (a rice paddy and two restored wetlands) to assess the impact of drained to flooded land-use change on CO2 and CH4 fluxes in the Delta. We found that the drained sites were net C and greenhouse gas (GHG) sources, releasing up to 341 g C m(-2) yr(-1) as CO2 and 11.4 g C m(-2) yr(-1) as CH4. Conversely, the restored wetlands were net sinks of atmospheric CO2, sequestering up to 397 g C m(-2) yr(-1). However, they were large sources of CH4, with emissions ranging from 39 to 53 g C m(-2) yr(-1). In terms of the full GHG budget, the restored wetlands could be either GHG sources or sinks. Although the rice paddy was a small atmospheric CO2 sink, when considering harvest and CH4 emissions, it acted as both a C and GHG source. Annual photosynthesis was similar between sites, but flooding at the restored sites inhibited ecosystem respiration, making them net CO2 sinks. This study suggests that converting drained agricultural peat soils to flooded land-use types can help reduce or reverse soil subsidence and reduce GHG emissions. © 2014 John Wiley & Sons Ltd.

Cloning, Sequencing, and Expression of the Gene Encoding Cyclic 2,3-Diphosphoglycerate Synthetase, the Key Enzyme of Cyclic 2,3-Diphosphoglycerate Metabolism in Methanothermus fervidus

OpenAIRE

Matussek, Karl; Moritz, Patrick; Brunner, Nina; Eckerskorn, Christoph; Hensel, Reinhard

1998-01-01

Cyclic 2,3-diphosphoglycerate synthetase (cDPGS) catalyzes the synthesis of cyclic 2,3-diphosphoglycerate (cDPG) by formation of an intramolecular phosphoanhydride bond in 2,3-diphosphoglycerate. cDPG is known to be accumulated to high intracellular concentrations (>300 mM) as a putative thermoadapter in some hyperthermophilic methanogens. For the first time, we have purified active cDPGS from a methanogen, the hyperthermophilic archaeon Methanothermus fervidus, sequenced the coding gene, and...

CO2 in Alberta - a vision of the future

International Nuclear Information System (INIS)

Edwards, K.

1999-01-01

The potential to develop a province-wide infrastructure for carbon dioxide (CO 2 ) collection and transmission was discussed. The petroleum industry's original interest in CO 2 was its potential for enhanced oil recovery (EOR) for Alberta's depleted oil fields. However, new interest has stemmed from its perceived role in global climate change and the potentially negative business and economic implications of emitting CO 2 into the atmosphere. It was suggested that the development of a province wide infrastructure to collect CO 2 would address both interests. A simple screening of the reservoirs was carried out to determine if Alberta has the right oil reservoirs and sufficient CO 2 supplies to support a large-scale CO 2 infrastructure. The proposed infrastructure would consist of CO 2 supplies from electrical power generation plants, CO 2 trunklines, feeder pipelines to deliver CO 2 from the trunklines to the field and the oil reservoirs where the CO 2 would be injected. Such infrastructures already exist in Texas and Mexico where more than 1 billion scf per day of CO 2 is used for EOR. This study compared the factors leading to a large-scale CO 2 industry with factors in place during the 1970s and 1980s, when most of the hydrocarbon miscible floods were initiated in Alberta. It was concluded that the preliminary economics suggest that the concept has merit. 12 refs., 3 tabs., 9 figs

A new refillable Cobalt-57 flood phantom to measure camera uniformity

International Nuclear Information System (INIS)

Dias-Neto, A.; Silva, C.P.G. da; Osso, J.

1997-01-01

Full text: The system uniformity of a scintillation camera is assessed using an extended Tc-99m source: a well constructed flood phantom, filled with a solution of Tc-99m pertechnetate, that does not bulge and is well mixed. A convenient substitute is a commercial solid Co-57 sheet source, which is expensive (5k-10k USS), has a relative short life-span (1,5 - 2 years), and, may not be quite uniform. As an alternative, an inexpensive fillable Co-57 flood source is presented. For pilot testing, a plastic flood phantom was filled with a solution of Co-57 chloride produced by IPEN's cyclotron. Special filling plugs with O-rings were used to avoid any leakage. High count uniformity images, using a low-energy high-resolution collimator and 15% energy windows, were obtained with the fillable Co-57 source, a commercial Co-57 sheet source, and a Tc-99 source. The data were compared visually and quantified with the NEMA uniformity parameters. The fillable Co-57 source compared favourably with the other sources. A shock-proof flood phantom is at present under development. This phantom is intended to be refilled annually with Co-57, at a fraction of the cost of a commercial sheet source. (authors)

IMPROVING CO2 EFFICIENCY FOR RECOVERING OIL IN HETEROGENEOUS RESERVOIRS

International Nuclear Information System (INIS)

Reid B. Grigg; Robert K. Svec; Zheng-Wen Zeng; Liu Yi; Baojun Bai

2004-01-01

A three-year contract for the project, DOE Contract No. DE-FG26-01BC15364, ''Improving CO 2 Efficiency for Recovering Oil in Heterogeneous Reservoirs'', was started on September 28, 2001. This project examines three major areas in which CO 2 flooding can be improved: fluid and matrix interactions, conformance control/sweep efficiency, and reservoir simulation for improved oil recovery. The project has received a one-year, no-cost extension to September 27, 2005. During this extra time additional deliverables will be (1) the version of MASTER that has been debugged and a foam option added for CO 2 mobility control and (2) adsorption/desorption data on pure component minerals common in reservoir rock that will be used to improve predictions of chemical loss to adsorption in reservoirs. This report discusses the activity during the six-month period covering October 1, 2003 through March 31, 2004 that comprises the first and second fiscal quarters of the project's third year. During this period of the project several areas have advanced: reservoir fluid/rock interactions and their relationships to changing injectivity, and surfactant adsorption on quarried core and pure component granules, foam stability, and high flow rate effects. Presentations and papers included: a papers covered in a previous report was presented at the fall SPE ATCE in Denver in October 2003, a presentation at the Southwest ACS meeting in Oklahoma City, presentation on CO 2 flood basic behavior at the Midland Annual CO 2 Conference December 2003; two papers prepared for the biannual SPE/DOE Symposium on IOR, Tulsa, April 2004; one paper accepted for the fall 2004 SPE ATCE in Houston; and a paper submitted to an international journal Journal of Colloid and Interface Science which is being revised after peer review

Levels of cyclic-2,3-diphosphoglycerate in Methanobacterium thermoautotrophicum during phosphate limitation.

OpenAIRE

Seely, R J; Fahrney, D E

1984-01-01

Batch-grown Methanobacterium thermoautotrophicum cells grew nonexponentially in the absence of exogenous Pi until intracellular cyclic-2,3-diphosphoglycerate (cyclic DPG) had fallen below 2 mumol/g (dry weight), the limit of detection. Growth resumed immediately upon transfer to medium containing Pi Cyclic DPG levels were also below detection in Pi-limited chemostat cultures operating at a dilution rate of 0.173 h-1 (4-h doubling time), with reservoir Pi concentrations below 200 microM. At th...

Supplementary Material for: The arabidopsis cyclic nucleotide interactome

KAUST Repository

Donaldson, Lara; Meier, Stuart; Gehring, Christoph A

2016-01-01

Abstract Background Cyclic nucleotides have been shown to play important signaling roles in many physiological processes in plants including photosynthesis and defence. Despite this, little is known about cyclic nucleotide-dependent signaling mechanisms in plants since the downstream target proteins remain unknown. This is largely due to the fact that bioinformatics searches fail to identify plant homologs of protein kinases and phosphodiesterases that are the main targets of cyclic nucleotides in animals. Methods An affinity purification technique was used to identify cyclic nucleotide binding proteins in Arabidopsis thaliana. The identified proteins were subjected to a computational analysis that included a sequence, transcriptional co-expression and functional annotation analysis in order to assess their potential role in plant cyclic nucleotide signaling. Results A total of twelve cyclic nucleotide binding proteins were identified experimentally including key enzymes in the Calvin cycle and photorespiration pathway. Importantly, eight of the twelve proteins were shown to contain putative cyclic nucleotide binding domains. Moreover, the identified proteins are post-translationally modified by nitric oxide, transcriptionally co-expressed and annotated to function in hydrogen peroxide signaling and the defence response. The activity of one of these proteins, GLYGOLATE OXIDASE 1, a photorespiratory enzyme that produces hydrogen peroxide in response to Pseudomonas, was shown to be repressed by a combination of cGMP and nitric oxide treatment. Conclusions We propose that the identified proteins function together as points of cross-talk between cyclic nucleotide, nitric oxide and reactive oxygen species signaling during the defence response.

Enzymatic degradation of cyclic 2,3-diphosphoglycerate to 2,3-diphosphoglycerate in Methanobacterium thermoautotrophicum.

Science.gov (United States)

Sastry, M V; Robertson, D E; Moynihan, J A; Roberts, M F

1992-03-24

2,3-Diphosphoglycerate (2,3-DPG) has been found to be the product of the enzymatic degradation of cyclic 2,3-diphosphoglycerate (cDPG) in the archaebacterium Methanobacterium thermoautotrophicum delta H. Although 2,3-DPG has not previously been detected as a major soluble component of M. thermoautotrophicum, large pools accumulated at an incubation temperature of 50 degrees C (below the optimum growth temperature of 62 degrees C). Under these conditions, cellular activity was significantly decreased; a return of the culture to the optimum growth temperature restored the 2,3-DPG pool back to original low levels and caused steady-state cDPG levels to increase again. While 13CO2-pulse/12CO2-chase experiments at 50 degrees C showed that the cDPG turned over, the appearance of 2,3-DPG at NMR-visible concentrations required at least 10 h. Production of 2,3-DPG in vivo was prevented by exposure of the cells to O2. The enzyme responsible for this hydrolysis of cDPG was purified by affinity chromatography and appears to be a 33-kDa protein. Activity was detected in the presence of oxygen and was enhanced by a solution of 1 M KCl, 25 mM MgCl2, and dithiothreitol. Both Km and Vmax have been determined at 37 degrees C; kinetics also indicate that in vitro the product, 2,3-DPG, is an inhibitor of cDPG hydrolysis. These findings are discussed in view of a proposed role for cDPG in methanogens.

Numerical modelling of the impact of flood wave cyclicality on the stability of levees

Directory of Open Access Journals (Sweden)

Franczyk Anna

2016-01-01

Full Text Available Sensitivity analysis applied to the flooding process is discussed in the paper. The analysis was done as part of the ISMOP project devoted to elaborating and designing a complex system for embankment monitoring and threat forecasting. The analysis was performed using selected geotechnical parameters that describe embankment state. It was shown that the sensitivity analysis method is very practical for detecting places where the largest vertical displacement and pore pressure distribution are observed. The sensitivity analysis was carried out for a single flood wave numerical experiment as well as for a double successive flood wave experiment. Comparison of the results allowed us to detect the places where the biggest differences in total relative sensitivity values are observed. Plots of these differences can help to indicate the particular places within the embankment that are the most influenced by successive flood waves and should be especially examined during field experiments as part of the ISMOP project.

The preparation and role of Li_2ZrO_3 surface coating LiNi_0_._5Co_0_._2Mn_0_._3O_2 as cathode for lithium-ion batteries

International Nuclear Information System (INIS)

Xu, Yue; Liu, Yang; Lu, Zhongpei; Wang, Haiying; Sun, Deqin; Yang, Gang

2016-01-01

Graphical abstract: LiNi_0_._5Co_0_._2Mn_0_._3O_2 is coated by Li_2ZrO_3 layer with the thickness about 20 nm. Li_2ZrO_3 coating effectively improves cycling performance and rate capability. LZO-LMO delivers 194 mAh g"−"1 at 0.2 C and presents improved cyclic performance at 55 °C. - Highlights: • LiNi_0_._5Co_0_._2Mn_0_._3O_2 is coated by Li_2ZrO_3 layer with the thickness about 20 nm. • Li_2ZrO_3 coating effectively improves cycling performance and rate capability. • LZO-LMO delivers 194 mAh g"−"1 at 0.2 C and presents improved cyclic performance at 55 °C. • Li_2ZrO_3 coating suppresses cation dissolution and enhances the structural stability. - Abstract: Li_2ZrO_3-coated LiNi_0_._5Co_0_._2Mn_0_._3O_2 (LZO-LMO) is successful synthesized by using a wet chemical method. Li_2ZrO_3 coating formed a uniform layer on LiNi_0_._5Co_0_._2Mn_0_._3O_2 particles (LMO) without changing the crystal structure. Cyclic voltammetry (CV) and charge–discharge tests show that the Li_2ZrO_3-modified layer can improve the cyclic and rate performance. In the cut-off voltage of 2.7–4.6 V, LZO-LMO maintains 86% of the initial capacity at the 50th cycle, which is much higher than LMO with the retention of 66% of the initial capacity. The coating layer of LZO plays the positive role in conductivity of lithium diffusion and improves rate performance of LMO. At 10 C rates, LZO-LMO delivers the initial capacity of 95 mAh g"−"1 which is much higher than 40 mAh g"−"1 delivered by LMO. At the environmental temperature of 55 °C, LZO-LMO delivers the initial capacity of 194 mAh g"−"1 at 0.2 C rate and presents an improved cyclic performance in comparison with LMO. The elemental analysis of electrodes carried out after 50 charge/discharge cycles shows minor Ni content deviation in LMO, but LZO-LMO still remains the stoichiometric ratio, because the Li_2ZrO_3 coating efficiently hinders the metal dissolution during charge/discharge.

Forecasting approach of electrochemical valorisation of CO2 in alkali molten carbonates

International Nuclear Information System (INIS)

Chery, Deborah

2015-01-01

Carbon Dioxide is a greenhouse which can be valorised by means of electrochemical valorisation into carbon monoxide. The main goals of the thesis consist in the theoretical determination of the conductive conditions leading to this electrochemical valorisation in alkali molten carbonates along with the study of the feasibility of this electrochemical reduction in binary and ternary eutectics under experimental condition. CO 2 solubility has been determined by manometric measure and increase along with the temperature. CO 2 electrochemical experimental feasibility into CO in eutectics on gold plate electrode and graphite carbon has been proved by cyclic volt-amperometry for temperatures exceeding 550 C, without gold plate electrode pretreatment and with gold plate pretreatment by an pre-electrolysis at potential slightly negative as the CO 2 reduction potential. A global approach of reactional mechanisms implied in CO 2 reduction is proposed. (author)

Reactivity of Fe3(CO)12 with Alkynes R-C≡-C-R':Syntheses and Crystal Structures of Substituted Cyclic Ketones and Carbonyl Iron Complexes

Institute of Scientific and Technical Information of China (English)

SUO Quan-Ling; WU Le; SU Qian; ZHU Ning; GAO Yuan-Yuan; HONG Hai-Long; XIE Rui-Jun; HAN Li-Min

2017-01-01

The reactivity of carbonyl iron cluster with alkynes has been studied by the thermal reaction of Fe3(CO)12 with R-C≡C-R'(R =Fc (Ferrocenyl);R'=Ph (Phenyl),Fc,H).The hexacarbonyldiiron cluster with ferracyclopentadiene ring (μ2,η4-C4Ph4)Fe2(CO)6 (1) and one tetraphenyl substituted cyclopentadienone (Ph4C4CO) (2) were simultaneously obtained by the reaction of Fe3(CO)12 with alkyne (Ph-C≡C-Ph).Only one ferrole cluster (μ2,η4-C4Fc2H2)Fe2(CO)6 (3) was separated by using Fc-C≡C-H as alkyne.One tri-carbonyl iron complex (η4-C4Fc4CO)Fe(CO)3 (4) and an unexpected new cyclic ketone compound 2,2,4,5-tetraferrocenylcyclopenta-4-en-l,3-di-one [Fc4C3(CO)2] (5) were obtained by using Fc-C≡C-Fc as alkyne.A new complex (η4-2,4-diphenyl-3,5-diferrocenylcyclopenta-2,4-dien-l-one)-tricarbonyl iron (η4-C4Ph2Fc2CO)Fe(CO)3 (6)was synthesized by the reaction of Fe3(CO)12 with Fc-C≡C-Ph.The structures of compounds 1～6 were determined by X-ray single-crystal diffraction and spectroscopic characterization.The crystal structures of two new compounds 5 and 6 were analyzed.Our experimental results reveal the structural models of the reaction products are affected by the kinds of substituents from alkynes R-C≡C-R'.

Efficient MgO-based mesoporous CO2 trapper and its performance at high temperature.

Science.gov (United States)

Han, Kun Kun; Zhou, Yu; Chun, Yuan; Zhu, Jian Hua

2012-02-15

A novel MgO-based porous adsorbent has been synthesized in a facile co-precipitation method for the first time, in order to provide a candidate for trapping CO(2) in flue gas at high temperature. The resulting composite exhibits a mesoporous structure with a wide pore size distribution, due to the even dispersion and distribution of microcrystalline MgO in the framework of alumina to form a concrete-like structure. These sorbents can capture CO(2) at high temperature (150-400°C), possessing high reactivity and stability in cyclic adsorption-desorption processes, providing competitive candidates to control CO(2) emission. Copyright © 2011 Elsevier B.V. All rights reserved.

Nested 1D-2D approach for urban surface flood modeling

Science.gov (United States)

Murla, Damian; Willems, Patrick

2015-04-01

Floods in urban areas as a consequence of sewer capacity exceedance receive increased attention because of trends in urbanization (increased population density and impermeability of the surface) and climate change. Despite the strong recent developments in numerical modeling of water systems, urban surface flood modeling is still a major challenge. Whereas very advanced and accurate flood modeling systems are in place and operation by many river authorities in support of flood management along rivers, this is not yet the case in urban water management. Reasons include the small scale of the urban inundation processes, the need to have very high resolution topographical information available, and the huge computational demands. Urban drainage related inundation modeling requires a 1D full hydrodynamic model of the sewer network to be coupled with a 2D surface flood model. To reduce the computational times, 0D (flood cones), 1D/quasi-2D surface flood modeling approaches have been developed and applied in some case studies. In this research, a nested 1D/2D hydraulic model has been developed for an urban catchment at the city of Gent (Belgium), linking the underground sewer (minor system) with the overland surface (major system). For the overland surface flood modelling, comparison was made of 0D, 1D/quasi-2D and full 2D approaches. The approaches are advanced by considering nested 1D-2D approaches, including infiltration in the green city areas, and allowing the effects of surface storm water storage to be simulated. An optimal nested combination of three different mesh resolutions was identified; based on a compromise between precision and simulation time for further real-time flood forecasting, warning and control applications. Main streets as mesh zones together with buildings as void regions constitute one of these mesh resolution (3.75m2 - 15m2); they have been included since they channel most of the flood water from the manholes and they improve the accuracy of

CO₂ Problems and waste recycling. Research at the Institute of ferrous metallurgy

OpenAIRE

Gudenau, H. W.; Senk, D.; Babich, A.; Fröhling, C.; Kueon, O. S.; Wang, S.; Wieting, X.

2005-01-01

In a short introduction tests and calculations about CO₂-ice-blocs in the deep sea, use of CO₂ for underground-coal-gasification and tertiary processes to increase oil-production by C02-flooding are shown. New activities are presented e.g. CO₂-injection into EAF combined with injection of coal, coke or directreduction-fines. After research of injection of coals, fine ores or dust into blast furnaces and other shaft furnaces ...

Effect of rice husk ash addition on CO2 capture behavior of calcium-based sorbent during calcium looping cycle

International Nuclear Information System (INIS)

Li, Yingjie; Zhao, Changsui; Ren, Qiangqiang; Duan, Lunbo; Chen, Huichao; Chen, Xiaoping

2009-01-01

Rice husk ash/CaO was proposed as a CO 2 sorbent which was prepared by rice husk ash and CaO hydration together. The CO 2 capture behavior of rice husk ash/CaO sorbent was investigated in a twin fixed bed reactor system, and its apparent morphology, pore structure characteristics and phase variation during cyclic carbonation/calcination reactions were examined by SEM-EDX, N 2 adsorption and XRD, respectively. The optimum preparation conditions for rice husk ash/CaO sorbent are hydration temperature of 75 C, hydration time of 8 h, and mole ratio of SiO 2 in rice husk ash to CaO of 1.0. The cyclic carbonation performances of rice husk ash/CaO at these preparation conditions were compared with those of hydrated CaO and original CaO. The temperature at 660 C-710 C is beneficial to CO 2 absorption of rice husk ash/CaO, and it exhibits higher carbonation conversions than hydrated CaO and original CaO during multiple cycles at the same reaction conditions. Rice husk ash/CaO possesses better anti-sintering behavior than the other sorbents. Rice husk ash exhibits better effect on improving cyclic carbonation conversion of CaO than pure SiO 2 and diatomite. Rice husk ash/CaO maintains higher surface area and more abundant pores after calcination during the multiple cycles; however, the other sorbents show a sharp decay at the same reaction conditions. Ca 2 SiO 4 found by XRD detection after calcination of rice husk ash/CaO is possibly a key factor in determining the cyclic CO 2 capture behavior of rice husk ash/CaO. (author)

Cyclic-2,3-diphosphoglycerate cycle in methanogenic bacteria

International Nuclear Information System (INIS)

Fahrney, D.E.; Harper, S.H.; Krueger, R.D.

1987-01-01

A new and unprecedented model for P/sub i/ translocation into Methanobacterium thermoautotrophicum is proposed. It is based on an analysis of the rates of P/sub i/ uptake and concomitant flux through the cyclic-2,3-diphosphoglycerate (cDPG) pool in the presence of cyanide. CN - completely blocks flow of carbon into cellular constituents, but methanogenesis continues at about 70%, indicating considerable energy flow. P/sub i/ uptake continued at 20% of control for 30 min or longer, resulting in an expansion of the intracellular P/sub i/ pool. During this period the flux of phosphate through the cDPG pool remained equal to the rate of P/sub i/ entry. The distribution of 32 P in cDPG showed that the C-2 phosphoryl group was labeled preferentially, indicating that this phosphoryl group has a half-life under 10 min in the presence of CN - . Since CN - completely blocks CO 2 fixation but does not interfere with cDPG turnover, cDPG is neither a biosynthetic intermediate nor a phosphate storage compound. Earlier they had demonstrated that this methanogen can transport P/sub i/ against a million-fold concentration gradient via a H 2 -driven transport system having a K/sub m/ of 25 nM. The evidence that cDPG may play a role in this transport mechanism seems compelling, but further studies are needed

Electroreduction of CO{sub 2} using copper-deposited on boron-doped diamond (BDD)

Energy Technology Data Exchange (ETDEWEB)

Panglipur, Hanum Sekar; Ivandini, Tribidasari A., E-mail: ivandini.tri@sci.ui.ac.id [Department of Chemistry, FMIPA, Universitas Indonesia, Kampus UI Depok (Indonesia); Einaga, Yasuaki [Department of Chemistry, Keio University (Japan); Wibowo, Rahmat

2016-04-19

Electroreduction of CO{sub 2} was studied at copper-modified boron-doped diamond (Cu-BDD) electrodes as the working electrode. The Cu-BDD electrodes were prepared by electrochemical reduction with various concentrations of CuSO{sub 4} solutions. FE-SEM was utilized to characterize the electrodes. At Cu-BDD electrodes, a reduction peak at around -1.2 V (vs Ag/AgCl) attributtable to CO{sub 2} reductions could be observed by cyclic voltammetry technique of CO{sub 2} bubbled in water containing 0.1M NaCl. Accordingly, electroreduction of CO{sub 2} was conducted at -1.2 V (vs Ag/AgCl) using amperometry technique. The chemical products of the electroreduction analyzed by using HPLC showed the formation of formaldehyde, formic acid, and acetic acid at Cu-BDD electrodes.

DIGITAL FLOOD INSURANCE RATE MAP DATABASE, HUNTERDON CO., NJ

Data.gov (United States)

Federal Emergency Management Agency, Department of Homeland Security — The Digital Flood Insurance Rate Map (DFIRM) Database depicts flood risk information and supporting data used to develop the risk data. The primary risk...

[Dynamic observation, simulation and application of soil CO2 concentration: a review].

Science.gov (United States)

Sheng, Hao; Luo, Sha; Zhou, Ping; Li, Teng-Yi; Wang, Juan; Li, Jie

2012-10-01

Soil CO2 concentration is the consequences of biological activities in above- and below-ground, and its fluctuation may significantly affect the future atmospheric CO2 concentration and the projected climate change. This paper reviewed the methodologies for measuring the soil CO2 concentration in situ as well as their advantages and disadvantages, analyzed the variation patterns and controlling factors of soil CO2 concentration across the temporal (diurnal, several days, seasonal and inter-annual) and spatial (soil profile, site and landscape) scales, introduced the primary empirical and mechanical models for estimating and predicting soil CO2 concentration, and summarized the applications and constraints of soil CO2 concentration gradient in determining soil respiration. Four research priorities were proposed, i. e., to develop new techniques for collecting and determining the soil CO2 in severe soil conditions (e. g., flooding, lithoso and others), to approach the responses of soil CO2 concentration to weather change and related regulation mechanisms, to strengthen the researches on the spatial heterogeneity of soil CO2 concentration, and to expand the applications of soil CO2 concentration gradient in the measurement of tropical-subtropical soil respiration.

DESIGN AND IMPLEMENTATION OF A CO2 FLOOD UTILIZING ADVANCED RESERVOIR CHARACTERIZATION AND HORIZONTAL INJECTION WELLS IN A SHALLOW SHELF CARBONATE APPROACHING WATERFLOOD DEPLETION

Energy Technology Data Exchange (ETDEWEB)

K.J. Harpole; Ed G. Durrett; Susan Snow; J.S. Bles; Carlon Robertson; C.D. Caldwell; D.J. Harms; R.L. King; B.A. Baldwin; D. Wegener; M. Navarrette

2002-09-01

The purpose of this project was to economically design an optimum carbon dioxide (CO{sub 2}) flood for a mature waterflood nearing its economic abandonment. The original project utilized advanced reservoir characterization and CO{sub 2} horizontal injection wells as the primary methods to redevelop the South Cowden Unit (SCU). The development plans; project implementation and reservoir management techniques were to be transferred to the public domain to assist in preventing premature abandonment of similar fields. The Unit was a mature waterflood with water cut exceeding 95%. Oil must be mobilized through the use of a miscible or near-miscible fluid to recover significant additional reserves. Also, because the unit was relatively small, it did not have the benefit of economies of scale inherent in normal larger scale projects. Thus, new and innovative methods were required to reduce investment and operating costs. Two primary methods used to accomplish improved economics were use of reservoir characterization to restrict the flood to the higher quality rock in the unit and use of horizontal injection wells to cut investment and operating costs. The project consisted of two budget phases. Budget Phase I started in June 1994 and ended late June 1996. In this phase Reservoir Analysis, Characterization Tasks and Advanced Technology Definition Tasks were completed. Completion enabled the project to be designed, evaluated, and an Authority for Expenditure (AFE) for project implementation submitted to working interest owners for approval. Budget Phase II consisted of the implementation and execution of the project in the field. Phase II was completed in July 2001. Performance monitoring, during Phase II, by mid 1998 identified the majority of producing wells which under performed their anticipated withdrawal rates. Newly drilled and re-activated wells had lower offtake rates than originally forecasted. As a result of poor offtake, higher reservoir pressure was a concern

Impacts of soil incorporation of pre-incubated silica-rich rice residue on soil biogeochemistry and greenhouse gas fluxes under flooding and drying.

Science.gov (United States)

Gutekunst, Madison Y; Vargas, Rodrigo; Seyfferth, Angelia L

2017-09-01

Incorporation of silica-rich rice husk residue into flooded paddy soil decreases arsenic uptake by rice. However, the impact of this practice on soil greenhouse gas (GHG) emissions and elemental cycling is unresolved particularly as amended soils experience recurrent flooding and drying cycles. We evaluated the impact of pre-incubated silica-rich rice residue incorporation to soils on pore water chemistry and soil GHG fluxes (i.e., CO 2 , CH 4 , N 2 O) over a flooding and drying cycle typical of flooded rice cultivation. Soils pre-incubated with rice husk had 4-fold higher pore water Si than control and 2-fold higher than soils pre-incubated with rice straw, whereas the pore water As and Fe concentrations in soils amended with pre-incubated straw and husk were unexpectedly similar (maximum ~0.85μM and ~450μM levels, respectively). Pre-incubation of residues did not affect Si but did affect the pore water levels of As and Fe compared to previous studies using fresh residues where straw amended soils had higher As and Fe in pore water. The global warming potential (GWP) of soil GHG emissions decreased in the order straw (612±76g CO 2 -eqm -2 )>husk (367±42gCO 2 -eqm -2 )>ashed husk=ashed straw (251±26 and 278±28gCO 2 -eqm -2 )>control (186±23gCO 2 -eqm -2 ). The GWP increase due to pre-incubated straw amendment was due to: a) larger N 2 O fluxes during re-flooding; b) smaller contributions from larger CH 4 fluxes during flooded periods; and c) higher CH 4 and CO 2 fluxes at the onset of drainage. In contrast, the GWP of the husk amendment was dominated by CO 2 and CH 4 emissions during flooded and drainage periods, while ashed amendments increased CO 2 emissions particularly during drainage. This experiment shows that ashed residues and husk addition minimizes GWP of flooded soils and enhances pore water Si compared to straw addition even after pre-incubation. Copyright © 2017 Elsevier B.V. All rights reserved.

Z₂-double cyclic codes

OpenAIRE

Borges, J.

2014-01-01

A binary linear code C is a Z2-double cyclic code if the set of coordinates can be partitioned into two subsets such that any cyclic shift of the coordinates of both subsets leaves invariant the code. These codes can be identified as submodules of the Z2[x]-module Z2[x]/(x^r − 1) × Z2[x]/(x^s − 1). We determine the structure of Z2-double cyclic codes giving the generator polynomials of these codes. The related polynomial representation of Z2-double cyclic codes and its duals, and the relation...

Flood Inundation Modelling in the Kuantan River Basin using 1D-2D Flood Modeller coupled with ASTER-GDEM

Science.gov (United States)

Ng, Z. F.; Gisen, J. I.; Akbari, A.

2018-03-01

Topography dataset is an important input in performing flood inundation modelling. However, it is always difficult to obtain high resolution topography that provide accurate elevation information. Fortunately, there are some open source topography datasets available with reasonable resolution such as SRTM and ASTER-GDEM. In Malaysia particularly in Kuantan, the modelling research on the floodplain area is still lacking. This research aims to: a) to investigate the suitability of ASTER-GDEM to be applied in the 1D-2D flood inundation modelling for the Kuantan River Basin; b) to generate flood inundation map for Kuantan river basin. The topography dataset used in this study is ASTER-GDEM to generate physical characteristics of watershed in the basin. It is used to perform rainfall runoff modelling for hydrological studies and to delineate flood inundation area in the Flood Modeller. The results obtained have shown that a 30m resolution ASTER-GDEM is applicable as an input for the 1D-2D flood modelling. The simulated water level in 2013 has NSE of 0.644 and RSME of 1.259. As a conclusion, ASTER-GDEM can be used as one alternative topography datasets for flood inundation modelling. However, the flood level obtained from the hydraulic modelling shows low accuracy at flat urban areas.

An Improved CO2-Crude Oil Minimum Miscibility Pressure Correlation

Directory of Open Access Journals (Sweden)

Hao Zhang

2015-01-01

Full Text Available Minimum miscibility pressure (MMP, which plays an important role in miscible flooding, is a key parameter in determining whether crude oil and gas are completely miscible. On the basis of 210 groups of CO2-crude oil system minimum miscibility pressure data, an improved CO2-crude oil system minimum miscibility pressure correlation was built by modified conjugate gradient method and global optimizing method. The new correlation is a uniform empirical correlation to calculate the MMP for both thin oil and heavy oil and is expressed as a function of reservoir temperature, C7+ molecular weight of crude oil, and mole fractions of volatile components (CH4 and N2 and intermediate components (CO2, H2S, and C2~C6 of crude oil. Compared to the eleven most popular and relatively high-accuracy CO2-oil system MMP correlations in the previous literature by other nine groups of CO2-oil MMP experimental data, which have not been used to develop the new correlation, it is found that the new empirical correlation provides the best reproduction of the nine groups of CO2-oil MMP experimental data with a percentage average absolute relative error (%AARE of 8% and a percentage maximum absolute relative error (%MARE of 21%, respectively.

Evaluation of miscible and immiscible CO2 injection in one of the Iranian oil fields

Directory of Open Access Journals (Sweden)

Aref Hashemi Fath

2014-09-01

Full Text Available Carbon dioxide (CO2 flooding is one of the most important methods for enhanced oil recovery (EOR because it not only increases oil recovery efficiency but also causes a reduction of greenhouse gas emissions. It is a very complex system, involving phase behavior that could increase the recovery of oil by means of swelling, evaporation and decreasing viscosity of the oil. In this study, a reservoir modeling approach was used to evaluate immiscible and miscible CO2 flooding in a fractured oil field. To reduce simulation time, we grouped fluid components into 10 pseudo-components. The 3-parameter, Peng–Robinson Equation of State (EOS was used to match PVT experimental data by using the PVTi software. A one-dimensional slim-tube model was defined using ECLIPSE 300 software to determine the minimum miscibility pressure (MMP for injection of CO2. We used FloGrid software for making a reservoir static model and the reservoir model was calibrated using manual and assisted history matching methods. Then various scenarios of natural depletion, immiscible and miscible CO2 injection have been simulated by ECLIPSE 300 software and then the simulation results of scenarios have been compared. Investigation of simulation results shows that the oil recovery factor in miscible CO2 injection scenario is more than other methods.

Modeling and simulation of an activated carbon–CO2 four bed based adsorption cooling system

International Nuclear Information System (INIS)

Jribi, Skander; Saha, Bidyut Baran; Koyama, Shigeru; Bentaher, Hatem

2014-01-01

Highlights: • A transient mathematical model of a 4-bed adsorption chiller is proposed. • The performances of the cyclic-steady-state system are presented for different heating and cooling water inlet temperatures. • The desorption pressure has a big influence in the performances. • With 80 kg of Maxsorb III, the CO 2 based adsorption chiller produces 2 kW of cooling power and presents a COP of 0.1. - Abstract: In this study, a transient mathematical model of a 4-bed adsorption chiller using Maxsorb III as the adsorbent and CO 2 as the refrigerant has been analyzed. The performances of the cyclic-steady-state system are presented for different heating and cooling water inlet temperatures. It is found that the desorption pressure has a big influence in the performances due to the low critical point of CO 2 (T c = 31 °C). With 80 kg of Maxsorb III, the CO 2 based adsorption chiller produces 2 kW of cooling power and presents a COP of 0.1, at driving heat source temperature of 95 °C along with a cooling temperature of 27 °C and at optimum desorption pressure of 79 bar. The present thermal compression air-conditioning system could be driven with solar energy or waste heat from internal combustion engines and therefore is suitable for both residential and mobile air-conditioning applications

CuCo_2O_4 flowers/Ni-foam architecture as a battery type positive electrode for high performance hybrid supercapacitor applications

International Nuclear Information System (INIS)

Vijayakumar, Subbukalai; Nagamuthu, Sadayappan; Ryu, Kwang-Sun

2017-01-01

Graphical abstract: The Ni- foam supported CuCo_2O_4 flowers exhibits a high specific capacity with superior long term cyclic stability. - Highlights: • This paper reports the hydrothermal preparation of CuCo_2O_4 flowers on Ni-foam. • The CuCo_2O_4 flowers exhibits maximum specific capacity of 645.1C g"−"1. • After 2000 cycles, 109% of the initial specific capacity was retained. - Abstract: The battery type CuCo_2O_4 electrode was evaluated as a positive electrode material for its hybrid supercapacitor applications. CuCo_2O_4 flowers were prepared on Ni-foam through a simple hydrothermal process and post calcination treatment. The structure and morphology of the CuCo_2O_4 flowers/Ni-foam was characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and high resolution transmission electron microscopy. FESEM clearly revealed the flower-like morphology, which was composed of large number of petals. The length and width of the petals ranged from approximately 5–8 μm and approximately 50–150 nm, respectively. The CuCo_2O_4 flowers/Ni-foam electrode was employed for electrochemical characterization for hybrid supercapacitor applications. The specific capacity of the CuCo_2O_4 flower-like electrode was 692.4C g"−"1 (192.3 mA h g"−"1) at a scan rate of 5 mV s"−"1. The flower-like CuCo_2O_4 electrode exhibited a maximum specific capacity of 645.1C g"−"1 (179.2 mA h g"−"1) at a specific current of 1 A g"−"1 and good long term cyclic stability. The high specific capacity, good cyclic stability, and low internal and charge transfer resistance of the CuCo_2O_4 flowers/Ni-foam electrode confirmed the suitability of the prepared material as a positive electrode for hybrid supercapacitor applications.

Experimental studies on the krypton absorption in liquid CO2 (KALC) process

International Nuclear Information System (INIS)

Glass, R.W.; Beaujean, H.W.R.; Fowler, V.L.; Gilliam, T.M.; Inman, D.J.; Levins, D.M.

1976-01-01

Results are presented for a series of experiments to quantify krypton removal from simulated High-Temperature Gas-Cooled Reactor reprocessing off-gas by the KALC process. The Experimental Engineering Section Off-Gas Decontamination Facility used in the campaign provides engineering-scale experiments with nominal gas and liquid flows of 5 scfm and 0.5 gpm respectively. Equilibrium and nonequilibrium mass transfer experiments for the CO 2 --O 2 --Kr system are described. Data analysis indicates values of HTU for krypton on the order of 0.5 ft for decontamination factors from 100 to 10,000. Recent flooding information for the packed columns is combined with previous data and is shown to be well represented by an empirical flooding equation

Flood hazard mapping of Palembang City by using 2D model

Science.gov (United States)

Farid, Mohammad; Marlina, Ayu; Kusuma, Muhammad Syahril Badri

2017-11-01

Palembang as the capital city of South Sumatera Province is one of the metropolitan cities in Indonesia that flooded almost every year. Flood in the city is highly related to Musi River Basin. Based on Indonesia National Agency of Disaster Management (BNPB), the level of flood hazard is high. Many natural factors caused flood in the city such as high intensity of rainfall, inadequate drainage capacity, and also backwater flow due to spring tide. Furthermore, anthropogenic factors such as population increase, land cover/use change, and garbage problem make flood problem become worse. The objective of this study is to develop flood hazard map of Palembang City by using two dimensional model. HEC-RAS 5.0 is used as modelling tool which is verified with field observation data. There are 21 sub catchments of Musi River Basin in the flood simulation. The level of flood hazard refers to Head Regulation of BNPB number 2 in 2012 regarding general guideline of disaster risk assessment. The result for 25 year return per iod of flood shows that with 112.47 km2 area of inundation, 14 sub catchments are categorized in high hazard level. It is expected that the hazard map can be used for risk assessment.

Inverse strain rate effect on cyclic stress response in annealed Zircaloy-2

Energy Technology Data Exchange (ETDEWEB)

Sudhakar Rao, G.; Verma, Preeti [Center of Advanced Study, Department of Metallurgical Engineering, Indian Institute of Technology (Banaras Hindu University), Varanasi 221005 (India); Chakravartty, J.K. [Mechanical Metallurgy Group, Bhabha Atomic Research Center, Trombay 400 085, Mumbai (India); Nudurupati, Saibaba [Nuclear Fuel Complex, Hyderabad 500 062 (India); Mahobia, G.S.; Santhi Srinivas, N.C. [Center of Advanced Study, Department of Metallurgical Engineering, Indian Institute of Technology (Banaras Hindu University), Varanasi 221005 (India); Singh, Vakil, E-mail: vsingh.met@itbhu.ac.in [Center of Advanced Study, Department of Metallurgical Engineering, Indian Institute of Technology (Banaras Hindu University), Varanasi 221005 (India)

2015-02-15

Low cycle fatigue behavior of annealed Zircaloy-2 was investigated at 300 and 400 °C at different strain amplitudes and strain rates of 10{sup −2}, 10{sup −3}, and 10{sup −4} s{sup −1}. Cyclic stress response showed initial hardening with decreasing rate of hardening, followed by linear cyclic hardening and finally secondary hardening with increasing rate of hardening for low strain amplitudes at both the temperatures. The rate as well the degree of linear hardening and secondary hardening decreased with decrease in strain rate at 300 °C, however, there was inverse effect of strain rate on cyclic stress response at 400 °C and cyclic stress was increased with decrease in strain rate. The fatigue life decreased with decrease in strain rate at both the temperatures. The occurrence of linear cyclic hardening, inverse effect of strain rate on cyclic stress response and deterioration in fatigue life with decrease in strain rate may be attributed to dynamic strain aging phenomena resulting from enhanced interaction of dislocations with solutes. Fracture surfaces revealed distinct striations, secondary cracking, and oxidation with decrease in strain rate. Deformation substructure showed parallel dislocation lines and dislocation band structure at 300 °C. Persistent slip band wall structure and development of fine Corduroy structure was observed at 400 °C.

Inverse strain rate effect on cyclic stress response in annealed Zircaloy-2

International Nuclear Information System (INIS)

Sudhakar Rao, G.; Verma, Preeti; Chakravartty, J.K.; Nudurupati, Saibaba; Mahobia, G.S.; Santhi Srinivas, N.C.; Singh, Vakil

2015-01-01

Low cycle fatigue behavior of annealed Zircaloy-2 was investigated at 300 and 400 °C at different strain amplitudes and strain rates of 10 −2 , 10 −3 , and 10 −4 s −1 . Cyclic stress response showed initial hardening with decreasing rate of hardening, followed by linear cyclic hardening and finally secondary hardening with increasing rate of hardening for low strain amplitudes at both the temperatures. The rate as well the degree of linear hardening and secondary hardening decreased with decrease in strain rate at 300 °C, however, there was inverse effect of strain rate on cyclic stress response at 400 °C and cyclic stress was increased with decrease in strain rate. The fatigue life decreased with decrease in strain rate at both the temperatures. The occurrence of linear cyclic hardening, inverse effect of strain rate on cyclic stress response and deterioration in fatigue life with decrease in strain rate may be attributed to dynamic strain aging phenomena resulting from enhanced interaction of dislocations with solutes. Fracture surfaces revealed distinct striations, secondary cracking, and oxidation with decrease in strain rate. Deformation substructure showed parallel dislocation lines and dislocation band structure at 300 °C. Persistent slip band wall structure and development of fine Corduroy structure was observed at 400 °C

CO{sub 2} capture behavior of shell during calcination/carbonation cycles

Energy Technology Data Exchange (ETDEWEB)

Li, Y.J.; Zhao, C.S.; Chen, H.C.; Duan, L.B.; Chen, X.P. [School of Energy and Environment, Southeast University, Nanjing (China)

2009-08-15

The cyclic carbonation performances of shells as CO{sub 2} sorbents were investigated during multiple calcination/carbonation cycles. The carbonation kinetics of the shell and limestone are similar since they both exhibit a fast kinetically controlled reaction regime and a diffusion controlled reaction regime, but their carbonation rates differ between these two regions. Shell achieves the maximum carbonation conversion for carbonation at 680-700 C. The mactra veneriformis shell and mussel shell exhibit higher carbonation conversions than limestone after several cycles at the same reaction conditions. The carbonation conversion of scallop shell is slightly higher than that of limestone after a series of cycles. The calcined shell appears more porous than calcined limestone, and possesses more pores >230 nm, which allow large CO{sub 2} diffusion-carbonation reaction rates and higher conversion due to the increased surface area of the shell. The pores of the shell that are greater than 230 nm do not sinter significantly. The shell has more sodium ions than limestone, which probably leads to an improvement in the cyclic carbonation performance during the multiple calcination/carbonation cycles. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

High efficiency nanocomposite sorbents for CO2 capture based on amine-functionalized mesoporous capsules

KAUST Repository

Qi, Genggeng; Wang, Yanbing; Estevez, Luis; Duan, Xiaonan; Anako, Nkechi; Park, Ah-Hyung Alissa; Li, Wen; Jones, Christopher W.; Giannelis, Emmanuel P.

2011-01-01

A novel high efficiency nanocomposite sorbent for CO2 capture has been developed based on oligomeric amine (polyethylenimine, PEI, and tetraethylenepentamine, TEPA) functionalized mesoporous silica capsules. The newly synthesized sorbents exhibit extraordinary capture capacity up to 7.9 mmol g-1 under simulated flue gas conditions (pre-humidified 10% CO 2). The CO2 capture kinetics were found to be fast and reached 90% of the total capacities within the first few minutes. The effects of the mesoporous capsule features such as particle size and shell thickness on CO2 capture capacity were investigated. Larger particle size, higher interior void volume and thinner mesoporous shell thickness all improved the CO2 capacity of the sorbents. PEI impregnated sorbents showed good reversibility and stability during cyclic adsorption-regeneration tests (50 cycles). © 2011 The Royal Society of Chemistry.

Use of co2 for the synthesis of cyclic glycocarbonates and linear polyglycocarbonates by polycondensation from glycans

KAUST Repository

Gnanou, Yves

2016-10-20

Provided herein are methods for synthesizing cyclic carbonates, glycocarbonates, and polyglycocarbonates by reacting polyol glycans with carbon dioxide. Synthesis can include selective polycondensation of polyol glycan hydroxyl moieties.

Use of co2 for the synthesis of cyclic glycocarbonates and linear polyglycocarbonates by polycondensation from glycans

KAUST Repository

Gnanou, Yves; Pati, Debasis; Feng, Xiaoshuang; Hadjichristidis, Nikolaos

2016-01-01

Provided herein are methods for synthesizing cyclic carbonates, glycocarbonates, and polyglycocarbonates by reacting polyol glycans with carbon dioxide. Synthesis can include selective polycondensation of polyol glycan hydroxyl moieties.

Comparative study of CO2 and H2O activation in the synthesis of carbon electrode for supercapacitors

Science.gov (United States)

Taer, E.; Apriwandi, Yusriwandi, Mustika, W. S.; Zulkifli, Taslim, R.; Sugianto, Kurniasih, B.; Agustino, Dewi, P.

2018-02-01

The physical activation for the comparative study of carbon electrode synthesized for supercapacitor applications made from rubber wood sawdust has been performed successfully. Comparison of physical activation used in this research is based on the different gas activation such as CO2 and H2O. The CO2 and H2O activation are made by using an integrated carbonization and activation system. The carbonization process is performed in N2 atmosphere followed by CO2 and H2O activation process. The carbonization process at temperature of 600°C, the CO2 and H2O activation process at a temperature of 900°C and maintained at this condition for 2 h and 3 h. The electrochemical properties were analyzed using cyclic voltammetric (CV) method. The CV results show that the carbon electrode with CO2 activation has better capacitive properties than H2O, the highest specific capacitance obtained is 93.22 F/g for 3 h of activation time. In addition, the analysis of physical properties such as surface morphology and degree of crystallinity was also performed.

Numerical Simulation and Optimization of Enhanced Oil Recovery by the In Situ Generated CO2 Huff-n-Puff Process with Compound Surfactant

Directory of Open Access Journals (Sweden)

Yong Tang

2016-01-01

Full Text Available This paper presents the numerical investigation and optimization of the operating parameters of the in situ generated CO2 Huff-n-Puff method with compound surfactant on the performance of enhanced oil recovery. First, we conducted experiments of in situ generated CO2 and surfactant flooding. Next, we constructed a single-well radial 3D numerical model using a thermal recovery chemical flooding simulator to simulate the process of CO2 Huff-n-Puff. The activation energy and reaction enthalpy were calculated based on the reaction kinetics and thermodynamic models. The interpolation parameters were determined through history matching a series of surfactant core flooding results with the simulation model. The effect of compound surfactant on the Huff-n-Puff CO2 process was demonstrated via a series of sensitivity studies to quantify the effects of a number of operation parameters including the injection volume and mole concentration of the reagent, the injection rate, the well shut-in time, and the oil withdrawal rate. Based on the daily production rate during the period of Huff-n-Puff, a desirable agreement was shown between the field applications and simulated results.

Cyclic compressive creep-elastoplastic behaviors of in situ TiB_2/Al-reinforced composite

International Nuclear Information System (INIS)

Zhang, Qing; Zhang, Weizheng; Liu, Youyi; Guo, BingBin

2016-01-01

This paper presents a study on the cyclic compressive creep-elastoplastic behaviors of a TiB_2-reinforced aluminum matrix composite (ZL109) at 350 °C and 200 °C. According to the experimental results, under cyclic elastoplasticity and cyclic coupled compressive creep-elastoplasticity, the coupled creep will cause changes in isotropic stress and kinematic stress. Isotropic stress decreases with coupled creep, leading to cyclic softening. Positive kinematic stress, however, increases with coupled creep, leading to cyclic hardening. Transmission electron microscopy (TEM) observations of samples under cyclic compressive creep-elastoplasticity with different temperatures and strain amplitudes indicate that more coupled creep contributes to more subgrain boundaries but fewer intracrystalline dislocations. Based on the macro tests and micro observations, the micro mechanism of compressive creep's influence on cyclic elastoplasticity is elucidated. Dislocations recovering with coupled creep leads to isotropic softening, whereas subgrain structures created by coupled creep lead to kinematic hardening during cyclic deformation.

NiCo2S4 nanorod embedded rGO sheets as electrodes for supercapacitor

Science.gov (United States)

Sarkar, Aatreyee; Bera, Supriya; Chakraborty, Amit Kumar

2018-04-01

We report the synthesis of a hybrid nanostructure based on NiCo2S4 and reduced graphene oxide (rGO) following a facile hydrothermal method. X-ray diffraction (XRD), and electron microscopy (FESEM and HRTEM) analyses showed rod-like NiCo2S4 nanostructures embedded in rGO sheets. The electrochemical analysis of the synthesized nanohybrid using cyclic voltammetry (CV) and galvanostatic charge discharge (GCD) revealed specific capacitance of 410 F/gm indicating its suitability as a good electrode material for supercapacitor.

Adaptive cyclically dominating game on co-evolving networks: numerical and analytic results

Science.gov (United States)

Choi, Chi Wun; Xu, Chen; Hui, Pak Ming

2017-10-01

A co-evolving and adaptive Rock (R)-Paper (P)-Scissors (S) game (ARPS) in which an agent uses one of three cyclically dominating strategies is proposed and studied numerically and analytically. An agent takes adaptive actions to achieve a neighborhood to his advantage by rewiring a dissatisfying link with a probability p or switching strategy with a probability 1 - p. Numerical results revealed two phases in the steady state. An active phase for p pc has three separate clusters of agents using only R, P, and S, respectively with terminated adaptive actions. A mean-field theory based on the link densities in co-evolving network is formulated and the trinomial closure scheme is applied to obtain analytical solutions. The analytic results agree with simulation results on ARPS well. In addition, the different probabilities of winning, losing, and drawing a game among the agents are identified as the origin of the small discrepancy between analytic and simulation results. As a result of the adaptive actions, agents of higher degrees are often those being taken advantage of. Agents with a smaller (larger) degree than the mean degree have a higher (smaller) probability of winning than losing. The results are informative for future attempts on formulating more accurate theories.

Improved CO_2 adsorption capacity and cyclic stability of CaO sorbents incorporated with MgO

International Nuclear Information System (INIS)

Farah Diana Mohd Daud; Kumaravel Vignesh; Srimala Sreekantan; Abdul Rahman Mohamed

2016-01-01

Calcium oxide (CaO) sorbents incorporated with magnesium oxide (MgO) were synthesized using a co-precipitation route. The sorbents were prepared with different MgO concentrations (from 5 wt% to 30 wt%). The as-prepared sorbents were characterized using X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDX) and BET surface area analysis techniques. The sintering effect of CaO sorbents was decreased after the incorporation of MgO. The sorbents with 5 wt% and 10 wt% of MgO retained their CO_2 adsorption capacity over multiple cycles. Most importantly, CaO with 10 wt% MgO showed constant CO_2 adsorption capacity over 30 carbonation cycles. The results revealed that CaO with 10 wt% MgO is sufficient to produce sorbents with high surface area, good structural stability and enhanced CO_2 adsorption capacity. (authors)

CO₂ Storage and Enhanced Oil Recovery: Bald Unit Test Site, Mumford Hills Oil Field, Posey County, Indiana

Energy Technology Data Exchange (ETDEWEB)

Frailey, Scott M. [Illinois State Geological Survey, Champaign, IL (United States); Krapac, Ivan G. [Illinois State Geological Survey, Champaign, IL (United States); Damico, James R. [Illinois State Geological Survey, Champaign, IL (United States); Okwen, Roland T. [Illinois State Geological Survey, Champaign, IL (United States); McKaskle, Ray W. [Illinois State Geological Survey, Champaign, IL (United States)

2012-03-30

The Midwest Geological Sequestration Consortium (MGSC) carried out a small-scale carbon dioxide (CO₂) injection test in a sandstone within the Clore Formation (Mississippian System, Chesterian Series) in order to gauge the large-scale CO₂ storage that might be realized from enhanced oil recovery (EOR) of mature Illinois Basin oil fields via miscible liquid CO₂ flooding.

Metabolism of acyclic and cyclic N-nitroamines by cultured human colon

DEFF Research Database (Denmark)

Autrup, Herman; Harris, Curtis C.; Trump, Benjamin F.

1978-01-01

Cultured human colon mucosa was found to metabolize both acyclic and cyclic N-nitrosamines as measured by 14C-CO2 formation and reaction of the activated moieties with cellular macromolecules. Dimethylnitrosamine and N-nitrosopyrrolidine were metabolized by explants from all patients studied. A p...

Electron transfer reactions in some complexes of V+2, Co+3 and Eu+3

International Nuclear Information System (INIS)

Lellis, F.T.P.

1983-01-01

The stability constants β 1 , β 2 , β 3 for the mono-,bis-and tris-substituted complexes from vanadium (III) ions with the pyridine-2-carboxilate liquid are determined potentiometrically. The tris-substituted complex in aqueous solutions by electronic spectra and reversible cyclic voltammetry using gold electrodes is extensively characterized. In the investigation of electron tranfer kinetics involving mild oxidizing complexes, such as Co(NH 3 ) 3+ 6 , Co(en) 3+ 3 , Co(en) 2 gly 2+ , Co (histidinate) + 2 , Ru(NH 3 ) 3+ 6 and Eu 3+ ions, the tris (picolinate) vanadate (III) complex is used. Electron transfer kinetics for the Eu 3+ / 2+ couple in terms of a pseudo-first order process is analysed. The results, in terms of a tunneling mechanism, involving a set of similar, nuclear coordinates for the reactants and products, are explained. (M.J.C.) [pt

Impacts of repetitive floods and satisfaction with flood relief efforts: A case study of the flood-prone districts in Thailand’s Ayutthaya province

Directory of Open Access Journals (Sweden)

Nawhath Thanvisitthpon

2017-01-01

Full Text Available This research investigates the impacts of the repetitive flooding on the inhabitants of the four flood-prone districts in Thailand’s central province of Ayutthaya: Pranakorn Si Ayutthaya, Sena, Bang Ban, and Pak Hai. In addition, the residents’ satisfaction levels with the flood relief efforts and operations of the local authorities were examined and analyzed. The research revealed that most local residents have adapted to co-exist with the repetitive floods, an example of which is the elevation of the houses a few meters above the ground where the living quarter is on the upper level. The findings also indicated that the repetitive flooding incurred substantial post-flood repair costs, in light of the low income-earning capabilities of the locals. However, the flood-recovery financial aids was incommensurate with the actual expenditures, contributing to the lowest average satisfaction score among the inhabitants with regard to the adequacy of the post-flood repair and restoration financial aid. Furthermore, the research identified the differences between districts on the satisfaction with the flood relief efforts. The disparity could be attributed to the extent of coordination and participation of the local residents and their local leaders in the flood-related measures.

DIGITAL FLOOD INSURANCE RATE MAP DATABASE, MARIPOSA_CO_CA, CALIFORNIA

Data.gov (United States)

Federal Emergency Management Agency, Department of Homeland Security — The Digital Flood Insurance Rate Map (DFIRM) Database depicts flood risk information and supporting data used to develop the risk data. The primary risk...

Spontaneous passivation observations during scale formation on mild steel in CO{sub 2} brines

Energy Technology Data Exchange (ETDEWEB)

Han Jiabin, E-mail: jhan@lanl.gov [Institute for Corrosion and Multiphase Technology, Department of Chemical and Biomolecular Engineering, Ohio University, 342 West State Street, Athens, OH 45701 (United States); Nesic, Srdjan, E-mail: nesic@ohio.edu [Institute for Corrosion and Multiphase Technology, Department of Chemical and Biomolecular Engineering, Ohio University, 342 West State Street, Athens, OH 45701 (United States); Yang Yang; Brown, Bruce N. [Institute for Corrosion and Multiphase Technology, Department of Chemical and Biomolecular Engineering, Ohio University, 342 West State Street, Athens, OH 45701 (United States)

2011-06-01

Highlights: > We observed spontaneous passivation was at pH > 7. A higher open circuit potential was achieved comparing to bare surface or FeCO{sub 3} scaled surface. > Effects of pH, temperature, CO{sub 2}/FeCO{sub 3} on spontaneous passivation were systematically investigated. > TEM analysis determined the structure and chemistry of the passive film is Fe{sub 3}O{sub 4} instead of FeCO{sub 3}. > Root cause of the galvanic mechanism of localized CO{sub 2} corrosion is clarified. - Abstract: Previous study revealed localized corrosion in CO{sub 2} environments was driven by a galvanic cell established between pit surfaces and scaled surrounding area. In order to underpin the understanding of the galvanic mechanism of localized corrosion, the root cause of potential differences between these two surfaces, passivation of mild steel, in CO{sub 2} environments was investigated using transmission electron microscopy technique and electrochemical techniques including potentiodynamic polarization, cyclic polarization and open circuit potential techniques. Potentiodynamic polarization experiments showed that the passivation of the carbon steel surface favorably occurred at pH > 7 and facilitated with the presence of FeCO{sub 3} scale. Cyclic polarization tests showed that polarization rate had an important influence on passivation behavior. At a slower polarization rate, lower passivation potential and current density were observed. Spontaneous passivation was evidenced by a significant increase of corrosion resistance and an open circuit potential without any externally applied current or potential during electrode immersion. This process is affected by pH, temperature, presence of CO{sub 2} and iron carbonate. Nevertheless, iron carbonate film is not the only one responsible for passivation, as demonstrated from depassivation tests where passivity was lost without losing the existing iron carbonate film. Transmission electron microscopy technique was used to determine

Effect of Mineral Dissolution/Precipitation and CO2 Exsolution on CO2 transport in Geological Carbon Storage.

Science.gov (United States)

Xu, Ruina; Li, Rong; Ma, Jin; He, Di; Jiang, Peixue

2017-09-19

continuously injected through the core. The MRI results indicate dissolution of the carbonates during the experiments since the porosity has been increased after the core-flooding experiments. The mineral dissolution changes the pore structure by enlarging the throat diameters and decreasing the pore specific surface areas, resulting in lower CO 2 /water capillary pressures and changes in the relative permeability. When the reservoir pressure decreases, the CO 2 exsolution occurs due to the reduction of solubility. The CO 2 bubbles preferentially grow toward the larger pores instead of toward the throats or the finer pores during the depressurization. After exsolution, the exsolved CO 2 phase shows low mobility due to the highly dispersed pore-scale morphology, and the well dispersed small bubbles tend to merge without interface contact driven by the Ostwald ripening mechanism. During depressurization, the dissolved carbonate could also precipitate as a result of increasing pH. There is increasing formation water flow resistance and low mobility of the CO 2 in the presence of CO 2 exsolution and carbonate precipitation. These effects produce a self-sealing mechanism that may reduce unfavorable CO 2 migration even in the presence of sudden reservoir depressurization.

Li3V2(PO4)3-coated Li1.17Ni0.2Co0.05Mn0.58O2 as the cathode materials with high rate capability for Lithium ion batteries

International Nuclear Information System (INIS)

Liu, Yi; Huang, Xiao; Qiao, Qiqi; Wang, Yonglong; Ye, Shihai; Gao, Xueping

2014-01-01

In this work, Lithium rich layered oxide Li 1.17 Ni 0.2 Co 0.05 Mn 0.58 O 2 (LNCMO) is prepared and coated with Li 3 V 2 (PO 4 ) 3 (LVP) by a chemical deposition method. The surface modification with LVP is introduced into Li-rich layered oxides LNCMO for the first time. After 100 cycles of charging and discharging at various rates, the Li 3 V 2 (PO 4 ) 3 -coated Li 1.17 Ni 0.2 Co 0.05 Mn 0.58 O 2 (LVP-coated LNCMO) (5 wt%) still provides a large capacity of 261.4 mAh g -1 , much higher than the pristine LNCMO (211.5 mAh g -1 ). At 5 C rate, the LVP-coated LNCMO exhibits a stable cyclic capacity of 153.4 mAh g -1 , higher than 114.1 mAh g -1 of the pristine LNCMO. The electrochemical impedance spectroscopy (EIS) analysis demonstrates the LVP coating layer can suppress interaction between the cathode surface and the electrolyte and enhance the kinetics of lithium-ion diffusion, contributing to the stable cyclic performance with more cyclic capacity as well as at the high current density

IMPROVING CO2 EFFICIENCY FOR RECOVERING OIL IN HETEROGENEOUS RESERVOIRS

Energy Technology Data Exchange (ETDEWEB)

Reid B. Grigg

2003-10-31

The second annual report of ''Improving CO{sub 2} Efficiency for Recovery Oil in Heterogeneous Reservoirs'' presents results of laboratory studies with related analytical models for improved oil recovery. All studies have been undertaken with the intention to optimize utilization and extend the practice of CO{sub 2} flooding to a wider range of reservoirs. Many items presented in this report are applicable to other interest areas: e.g. gas injection and production, greenhouse gas sequestration, chemical flooding, reservoir damage, etc. Major areas of studies include reduction of CO{sub 2} mobility to improve conformance, determining and understanding injectivity changes in particular injectivity loses, and modeling process mechanisms determined in the first two areas. Interfacial tension (IFT) between a high-pressure, high-temperature CO{sub 2} and brine/surfactant and foam stability are used to assess and screen surfactant systems. In this work the effects of salinity, pressure, temperature, surfactant concentration, and the presence of oil on IFT and CO{sub 2} foam stability were determined on the surfactant (CD1045{trademark}). Temperature, pressure, and surfactant concentration effected both IFT and foam stability while oil destabilized the foam, but did not destroy it. Calcium lignosulfonate (CLS) can be used as a sacrificial and an enhancing agent. This work indicates that on Berea sandstone CLS concentration, brine salinity, and temperature are dominant affects on both adsorption and desorption and that adsorption is not totally reversible. Additionally, CLS adsorption was tested on five minerals common to oil reservoirs; it was found that CLS concentration, salinity, temperature, and mineral type had significant effects on adsorption. The adsorption density from most to least was: bentonite > kaolinite > dolomite > calcite > silica. This work demonstrates the extent of dissolution and precipitation from co-injection of CO{sub 2} and

Turnover of cyclic 2,3-diphosphoglycerate in Methanobacterium thermoautotrophicum. Phosphate flux in P1- and H2-limited chemostat cultures.

Science.gov (United States)

Krueger, R D; Campbell, J W; Fahrney, D E

1986-09-15

The archaebacterium Methanobacterium thermoautotrophicum was grown at 65 degrees C in H2- and Pi-limited chemostat cultures at dilution rates corresponding to 3- and 4-h doubling times, respectively. Under these conditions the steady state concentration of cyclic 2,3-diphosphoglycerate was 44 mM in the H2-limited cells and 13 mM in the cells grown under Pi limitation. Flux of Pi into the cyclic pyrophosphate pool was estimated by two 32P-labeling procedures: approach to isotopic equilibrium and replacement of prelabeled cyclic diphosphoglycerate with unlabeled compound. The results unequivocally demonstrate turnover of the phosphoryl groups; either both phosphoryl groups of the cyclic pyrophosphate leave together or the second leaves at a faster rate. The half-life of the rate-determining step for loss of the phosphoryl groups was approximately equal to the culture doubling time. The Pi flowing into the cyclic diphosphoglycerate pool accounted for 19% of the total Pi flux into Pi-limited cells and 43% of the total for H2-limited cells. The high phosphate flux through the large cyclic diphosphoglycerate pool suggests that this molecule plays an important role in the phosphorus metabolism of this methanogen.

Elevated CO2 stimulates marsh elevation gain, counterbalancing sea-level rise.

Science.gov (United States)

Langley, J Adam; McKee, Karen L; Cahoon, Donald R; Cherry, Julia A; Megonigal, J Patrick

2009-04-14

Tidal wetlands experiencing increased rates of sea-level rise (SLR) must increase rates of soil elevation gain to avoid permanent conversion to open water. The maximal rate of SLR that these ecosystems can tolerate depends partly on mineral sediment deposition, but the accumulation of organic matter is equally important for many wetlands. Plant productivity drives organic matter dynamics and is sensitive to global change factors, such as rising atmospheric CO(2) concentration. It remains unknown how global change will influence organic mechanisms that determine future tidal wetland viability. Here, we present experimental evidence that plant response to elevated atmospheric [CO(2)] stimulates biogenic mechanisms of elevation gain in a brackish marsh. Elevated CO(2) (ambient + 340 ppm) accelerated soil elevation gain by 3.9 mm yr(-1) in this 2-year field study, an effect mediated by stimulation of below-ground plant productivity. Further, a companion greenhouse experiment revealed that the CO(2) effect was enhanced under salinity and flooding conditions likely to accompany future SLR. Our results indicate that by stimulating biogenic contributions to marsh elevation, increases in the greenhouse gas, CO(2), may paradoxically aid some coastal wetlands in counterbalancing rising seas.

Elevated CO2 stimulates marsh elevation gain, counterbalancing sea-level rise

Science.gov (United States)

Langley, J. Adam; McKee, Karen L.; Cahoon, Donald R.; Cherry, Julia A.; Megonigal, J. Patrick

2009-01-01

Tidal wetlands experiencing increased rates of sea-level rise (SLR) must increase rates of soil elevation gain to avoid permanent conversion to open water. The maximal rate of SLR that these ecosystems can tolerate depends partly on mineral sediment deposition, but the accumulation of organic matter is equally important for many wetlands. Plant productivity drives organic matter dynamics and is sensitive to global change factors, such as rising atmospheric CO2 concentration. It remains unknown how global change will influence organic mechanisms that determine future tidal wetland viability. Here, we present experimental evidence that plant response to elevated atmospheric [CO2] stimulates biogenic mechanisms of elevation gain in a brackish marsh. Elevated CO2 (ambient + 340 ppm) accelerated soil elevation gain by 3.9 mm yr−1 in this 2-year field study, an effect mediated by stimulation of below-ground plant productivity. Further, a companion greenhouse experiment revealed that the CO2 effect was enhanced under salinity and flooding conditions likely to accompany future SLR. Our results indicate that by stimulating biogenic contributions to marsh elevation, increases in the greenhouse gas, CO2, may paradoxically aid some coastal wetlands in counterbalancing rising seas. PMID:19325121

IMPROVING CO2 EFFICIENCY FOR RECOVERING OIL IN HETEROGENEOUS RESERVOIRS

International Nuclear Information System (INIS)

Grigg, Reid B.

2002-01-01

A three-year contract, DOE Contract No. DE-FG26-01BC15364 ''Improving CO 2 Efficiency for Recovering Oil in Heterogeneous Reservoirs,'' was started on September 28, 2001. This project examines three major areas in which CO 2 flooding can be improved: fluid and matrix interactions, conformance control/sweep efficiency, and reservoir simulation for improved oil recovery. This report discusses the activity during the six-month period covering January 1, 2002 through June 30, 2002 that covers the second and third fiscal quarters of the project's first year. Paper SPE 75178, ''Cost Reduction and Injectivity Improvements for CO 2 Foams for Mobility Control,'' has been presented and included in the proceedings of the SPE/DOE Thirteenth Symposium on Improved Oil Recovery, Tulsa, OK, April 13-17, 2002. During these two quarters of the project we have been working in several areas: reservoir fluid/rock interactions and their relationships to changing injectivity, producer survey on injectivity, and surfactant adsorption on quarried and reservoir core

Characterization of cyclical phases in the manufacturing industry in Spain

OpenAIRE

Sala, Mercè; Torres, Teresa; Farré, Mariona

2014-01-01

Purpose: The purpose of this paper is to characterize the cyclical phases of the manufacturing industry in Spain and detect which industries have more influence on the Spanish business cycle. We assume that economic growth is a priority; we are going to determine which industries have a more/less appropriate cyclical behavior according this priority. We analyze if the industries with better cyclical behavior are the ones that achieve greater co-movement with the business cycle of the Spanish...

Using eddy covariance of CO2, 13CO2 and CH4, continuous soil respiration measurements, and PhenoCams to constrain a process-based biogeochemical model for carbon market-funded wetland restoration

Science.gov (United States)

Oikawa, P. Y.; Baldocchi, D. D.; Knox, S. H.; Sturtevant, C. S.; Verfaillie, J. G.; Dronova, I.; Jenerette, D.; Poindexter, C.; Huang, Y. W.

2015-12-01

We use multiple data streams in a model-data fusion approach to reduce uncertainty in predicting CO2 and CH4 exchange in drained and flooded peatlands. Drained peatlands in the Sacramento-San Joaquin River Delta, California are a strong source of CO2 to the atmosphere and flooded peatlands or wetlands are a strong CO2 sink. However, wetlands are also large sources of CH4 that can offset the greenhouse gas mitigation potential of wetland restoration. Reducing uncertainty in model predictions of annual CO2 and CH4 budgets is critical for including wetland restoration in Cap-and-Trade programs. We have developed and parameterized the Peatland Ecosystem Photosynthesis, Respiration, and Methane Transport model (PEPRMT) in a drained agricultural peatland and a restored wetland. Both ecosystem respiration (Reco) and CH4 production are a function of 2 soil carbon (C) pools (i.e. recently-fixed C and soil organic C), temperature, and water table height. Photosynthesis is predicted using a light use efficiency model. To estimate parameters we use a Markov Chain Monte Carlo approach with an adaptive Metropolis-Hastings algorithm. Multiple data streams are used to constrain model parameters including eddy covariance of CO2, 13CO2 and CH4, continuous soil respiration measurements and digital photography. Digital photography is used to estimate leaf area index, an important input variable for the photosynthesis model. Soil respiration and 13CO2 fluxes allow partitioning of eddy covariance data between Reco and photosynthesis. Partitioned fluxes of CO2 with associated uncertainty are used to parametrize the Reco and photosynthesis models within PEPRMT. Overall, PEPRMT model performance is high. For example, we observe high data-model agreement between modeled and observed partitioned Reco (r2 = 0.68; slope = 1; RMSE = 0.59 g C-CO2 m-2 d-1). Model validation demonstrated the model's ability to accurately predict annual budgets of CO2 and CH4 in a wetland system (within 14% and 1

Cyclic phosphopeptides for interference with Grb2 SH2 domain signal transduction prepared by ring-closing metathesis and phosphorylation

NARCIS (Netherlands)

Dekker, Frank J; de Mol, Nico J; Fischer, Marcel J E; Kemmink, Johan; Liskamp, Rob M J; Dekker, Frank

2003-01-01

Cyclic phosphopeptides were prepared using ring-closing metathesis followed by phosphorylation. These cyclic phosphopeptides were designed to interact with the SH2 domain of Grb2, which is a signal transduction protein of importance as a target for antiproliferative drug development. Binding of

Treatment of cyclic vomiting syndrome with co-enzyme Q10 and amitriptyline, a retrospective study

Directory of Open Access Journals (Sweden)

Preston Amy

2010-01-01

Full Text Available Abstract Background Cyclic vomiting syndrome (CVS, which is defined by recurrent stereotypical episodes of nausea and vomiting, is a relatively-common disabling condition that is associated with migraine headache and mitochondrial dysfunction. Co-enzyme Q10 (Co-Q is a nutritional supplement that has demonstrated efficacy in pediatric and adult migraine. It is increasingly used in CVS despite the complete lack of studies to demonstrate its value in treatment Methods Using an Internet-based survey filled out by subjects with CVS or their parents, the efficacy, tolerability and subject satisfaction in CVS prophylaxis were queried. Subjects taking Co-Q (22 subjects were compared against those taking amitriptyline (162 subjects, which is the general standard-of-care. Results Subjects/parents reported similar levels of efficacy for a variety of episode parameters (frequency, duration, number of emesis, nausea severity. There was a 50% reduction in at least one of those four parameters in 72% of subjects treated with amitriptyline and 68% of subjects treated Co-Q. However, while no side effects were reported on Co-Q, 50% of subjects on amitriptyline reported side effects (P = 5 × 10-7, resulting in 21% discontinuing treatment (P = 0.007. Subjects/parents considered the benefits to outweigh the risks of treatment in 47% of cases on amitriptyline and 77% of cases on Co-Q (P = 0.008. Conclusion Our data suggest that the natural food supplement Co-Q is potentially efficacious and tolerable in the treatment of CVS, and should be considered as an option in CVS prophylaxis. Our data would likely be helpful in the design of a double-blind clinical trial.

A benchmark of co-flow and cyclic deposition/etch approaches for the selective epitaxial growth of tensile-strained Si:P

Science.gov (United States)

Hartmann, J. M.; Veillerot, M.; Prévitali, B.

2017-10-01

We have compared co-flow and cyclic deposition/etch processes for the selective epitaxial growth of Si:P layers. High growth rates, relatively low resistivities and significant amounts of tensile strain (up to 10 nm min-1, 0.55 mOhm cm and a strain equivalent to 1.06% of substitutional C in Si:C layers) were obtained at 700 °C, 760 Torr with a co-flow approach and a SiH2Cl2 + PH3 + HCl chemistry. This approach was successfully used to thicken the sources and drains regions of n-type fin-shaped Field Effect Transistors. Meanwhile, the (Si2H6 + PH3/HCl + GeH4) CDE process evaluated yielded at 600 °C, 80 Torr even lower resistivities (0.4 mOhm cm, typically), at the cost however of the tensile strain which was lost due to (i) the incorporation of Ge atoms (1.5%, typically) into the lattice during the selective etch steps and (ii) a reduction by a factor of two of the P atomic concentration in CDE layers compared to that in layers grown in a single step (5 × 1020 cm-3 compared to 1021 cm-3).

Photoinduced electron transfer from organic semiconductors onto redox mediators for CO2

International Nuclear Information System (INIS)

Portenkirchner, E.

2014-01-01

In this work the photoinduced electron transfer from organic semiconductors onto redox mediator catalysts for CO 2 reduction has been investigated. In the beginning, the work focuses on the identication, characterization and test of suitable catalyst materials. For this purpose, rhenium compounds with 2,2'-bipyridine bis(arylimino) acenaphthene ligands and pyridinium were tested for molecular homogenous catalysis. Infrared, ultraviolet-visible (UV-Vis) and nuclear magnetic resonance (NMR) spectroscopy were used for initial characterization of the catalyst substances. Since the interpretation of infrared spectra was difficult for large molecules based on measured data only, additionally infrared absorption spectra obtained by quantum mechanical density functional theory(DFT) calculations were successfully used to correlate characteristic features in the measured spectra to their molecular origin. It was found that experimentally observed data and quantum chemical predictions for the infrared spectra of the novel compounds are in good agreement. Additionally, quantum mechanical calculations were carried out for the determination of molecular orbital frontier energy levels and correlated to UV-Vis absorption and cyclic voltammetry measurements. Extensive cyclic voltammetry measurements and bulk controlled-potential electrolysis experiments were performed using a N 2 - and CO 2 -saturated electrolyte solution. Together with a detailed product analysis via infrared spectroscopy, gas and ion chromatography the results allowed electrochemical characterizations of the novel catalysts regarding their suitability for electrochemical CO 2 reduction. Once suitable catalysts were identied, the materials were immobilized on the electrode surface by electro-polymerization of the catalyst (5,5'bisphenylethynyl-2,2'-bipyridyl)Re(CO) 3 Cl itself or by incorporation of (2,2'-bipyridyl)Re(CO) 3 Cl into a polypyrrole matrix, thereby changing from homogeneous to

Cyclic α-Alkoxyphosphonium Salts from (2-(Diphenylphosphino)phenyl)methanol and Aldehydes and Their Application in Synthesis of Vinyl Ethers and Ketones via Wittig Olefination.

Science.gov (United States)

Huang, Wenhua; Rong, Hong-Ying; Xu, Jie

2015-07-02

Cyclic α-alkoxyphosphonium salts have been synthesized from (2-(diphenylphosphino)phenyl)methanol and aldehydes in 36-89% yields. These phosphonium salts are bench-stable solids and undergo Wittig olefination with aldehydes under basic conditions (K2CO3 or t-BuOK) to form benzylic vinyl ethers, which are readily hydrolyzed to 1,2-disubstituted ethanones under acidic conditions. The formation mechanism of these phosphonium salts via hemiacetal is also proposed.

Multi-dimensional perspectives of flood risk - using a participatory framework to develop new approaches to flood risk communication

Science.gov (United States)

Rollason, Edward; Bracken, Louise; Hardy, Richard; Large, Andy

2017-04-01

Flooding is a major hazard across Europe which, since, 1998 has caused over €52 million in damages and displaced over half a million people. Climate change is predicted to increase the risks posed by flooding in the future. The 2007 EU Flood Directive cemented the use of flood risk maps as a central tool in understanding and communicating flood risk. Following recent flooding in England, an urgent need to integrate people living at risk from flooding into flood management approaches, encouraging flood resilience and the up-take of resilient activities has been acknowledged. The effective communication of flood risk information plays a major role in allowing those at risk to make effective decisions about flood risk and increase their resilience, however, there are emerging concerns over the effectiveness of current approaches. The research presented explores current approaches to flood risk communication in England and the effectiveness of these methods in encouraging resilient actions before and during flooding events. The research also investigates how flood risk communications could be undertaken more effectively, using a novel participatory framework to integrate the perspectives of those living at risk. The research uses co-production between local communities and researchers in the environmental sciences, using a participatory framework to bring together local knowledge of flood risk and flood communications. Using a local competency group, the research explores what those living at risk from flooding want from flood communications in order to develop new approaches to help those at risk understand and respond to floods. Suggestions for practice are refined by the communities to co-produce recommendations. The research finds that current approaches to real-time flood risk communication fail to forecast the significance of predicted floods, whilst flood maps lack detailed information about how floods occur, or use scientific terminology which people at risk

Flooding and Flood Management

Science.gov (United States)

Brooks, K.N.; Fallon, J.D.; Lorenz, D.L.; Stark, J.R.; Menard, Jason; Easter, K.W.; Perry, Jim

2011-01-01

Floods result in great human disasters globally and nationally, causing an average of $4 billion of damages each year in the United States. Minnesota has its share of floods and flood damages, and the state has awarded nearly $278 million to local units of government for flood mitigation projects through its Flood Hazard Mitigation Grant Program. Since 1995, flood mitigation in the Red River Valley has exceeded $146 million. Considerable local and state funding has been provided to manage and mitigate problems of excess stormwater in urban areas, flooding of farmlands, and flood damages at road crossings. The cumulative costs involved with floods and flood mitigation in Minnesota are not known precisely, but it is safe to conclude that flood mitigation is a costly business. This chapter begins with a description of floods in Minneosta to provide examples and contrasts across the state. Background material is presented to provide a basic understanding of floods and flood processes, predication, and management and mitigation. Methods of analyzing and characterizing floods are presented because they affect how we respond to flooding and can influence relevant practices. The understanding and perceptions of floods and flooding commonly differ among those who work in flood forecasting, flood protection, or water resource mamnagement and citizens and businesses affected by floods. These differences can become magnified following a major flood, pointing to the need for better understanding of flooding as well as common language to describe flood risks and the uncertainty associated with determining such risks. Expectations of accurate and timely flood forecasts and our ability to control floods do not always match reality. Striving for clarity is important in formulating policies that can help avoid recurring flood damages and costs.

CO2 as a C1-organic building block: Enantioselective electrocarboxylation of aromatic ketones with CO2catalyzed by cinchona alkaloids under mild conditions

International Nuclear Information System (INIS)

Chen, Bao-Li; Tu, Zhuo-Ying; Zhu, Hong-Wei; Sun, Wen-Wen; Wang, Huan; Lu, Jia-Xing

2014-01-01

Highlights: •Cinchona alkaloids catalysis achieve enantioselective electrocarboxylation of racemic aromatic ketones. •The applications of CO 2 enantioselective electrochemical fixation into optically active hydroxyl carboxylic acids have been expanded. •The applications of alkaloids have been expanded. •The applications of asymmetric synthesis by electrochemical methodology have been expanded. -- Abstract: The enantioselective electrocarboxylation of pro-chiral aromatic ketones (2-acetonaphthone, 1-(6-methoxy-2-naphthyl)ethanone, 1-(4-methoxy-1-naphthyl)ethanone) with atmospheric pressure of CO 2 catalyzed by cinchona alkaloids in the presence of phenol was investigated in an undivided cell for the first time to give optically active 2-hydroxy-2-arylpropionic acid. For the model compound 2-acetonaphthone, the influence of various reaction conditions, such as cathode material, current density, catalyst type, ratio of proton to catalyst and catalyst quantity, on the enantiomeric excesses (ee) and yield has been investigated. Under the optimized conditions of 2-acetonaphthone, all the aromatic ketones examined are converted into corresponding optically active 2-hydroxy-2-arylpropionic acids in moderate yield (32.2% - 41.3%) and ee (48.1% - 48.6%). In addition, the electrochemical behavior of 2-acetonaphthone has been studied by cyclic voltammetry (CV) in the absence and presence of CO 2 . Moreover, the probable reaction pathway was proposed accordingly

New Insights into CO2 Adsorption on Layered Double Hydroxide (LDH)-Based Nanomaterials

Science.gov (United States)

Tang, Nian; He, Tingyu; Liu, Jie; Li, Li; Shi, Han; Cen, Wanglai; Ye, Zhixiang

2018-02-01

The interlamellar spacing of layered double hydroxides (LDHs) was enlarged by dodecyl sulfonate ions firstly, and then, (3-aminopropyl)triethoxysilane (APS) was chemically grafted (APS/LDHs). The structural characteristics and thermal stability of these prepared samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), reflectance Fourier transform infrared spectrometer (FTIR), thermogravimetric analysis (TG), and elemental analysis (EA) respectively. The CO2 adsorption performance was investigated adopting TG and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). The results presented that the CO2 adsorption capacity on APS/LDHs was as high as 90 mg/g and showed no obvious reduction during a five cyclic adsorption-desorption test, indicating its superior performance stability. The DRIFTS results showed that both carbamates and weakly bounded CO2 species were generated on APS/LDHs. The weakly adsorbed species was due to the different local chemical environment for CO2 capture provided by the surface moieties of LDHs like free silanol and hydrogen bonds.

Escherichia coli pathotypes in Pakistan from consecutive floods in 2010 and 2011.

Science.gov (United States)

Bokhari, Habib; Shah, Muhammad Ali; Asad, Saba; Akhtar, Sania; Akram, Muhammad; Wren, Brendan W

2013-03-01

This study compares Escherichia coli pathotypes circulating among children in Pakistan during the floods of 2010 and 2011 and from sporadic cases outside flood affected areas. Using multiplex polymerase chain reaction 115 of 205 stool samples (56.29%) were positive for diarrheagenic E. coli from specimens taken during the floods compared with 50 of 400 (12.5%) stool samples being positive for sporadic cases. The E. coli pathotypes were categorized as Enteropathogenic E. coli 33 (28.69%) and 13 (26%), Enterotoxigenic E. coli 29 (25.21%) and 15 (30%), Enteroaggregative E. coli 21 (18.2%) and 18 (36%), Enterohemorrhagic E. coli 5 (4.34%) and 1 (2%) from flood and sporadic cases, respectively. Furthermore, patients co-infected with more than one pathotype were 26 (22.60%) and 3 (6%) from flood and sporadic cases, respectively. The study shows an unexpectedly high rate of isolation of E. coli pathotypes suggesting Pakistan as an endemic region that requires active surveillance particularly during flood periods.

Cycle development and design for CO2 capture from flue gas by vacuum swing adsorption.

Science.gov (United States)

Zhang, Jun; Webley, Paul A

2008-01-15

CO2 capture and storage is an important component in the development of clean power generation processes. One CO2 capture technology is gas-phase adsorption, specifically pressure (or vacuum) swing adsorption. The complexity of these processes makes evaluation and assessment of new adsorbents difficult and time-consuming. In this study, we have developed a simple model specifically targeted at CO2 capture by pressure swing adsorption and validated our model by comparison with data from a fully instrumented pilot-scale pressure swing adsorption process. The model captures nonisothermal effects as well as nonlinear adsorption and nitrogen coadsorption. Using the model and our apparatus, we have designed and studied a large number of cycles for CO2 capture. We demonstrate that by careful management of adsorption fronts and assembly of cycles based on understanding of the roles of individual steps, we are able to quickly assess the effect of adsorbents and process parameters on capture performance and identify optimal operating regimes and cycles. We recommend this approach in contrast to exhaustive parametric studies which tend to depend on specifics of the chosen cycle and adsorbent. We show that appropriate combinations of process steps can yield excellent process performance and demonstrate how the pressure drop, and heat loss, etc. affect process performance through their effect on adsorption fronts and profiles. Finally, cyclic temperature profiles along the adsorption column can be readily used to infer concentration profiles-this has proved to be a very useful tool in cyclic function definition. Our research reveals excellent promise for the application of pressure/vacuum swing adsorption technology in the arena of CO2 capture from flue gases.

Hopf Algebroids and Their Cyclic Theory

NARCIS (Netherlands)

Kowalzig, N.

2009-01-01

The main objective of this thesis is to clarify concepts of generalised symmetries in noncommutative geometry (i.e., the noncommutative analogue of groupoids and Lie algebroids) and their associated (co)homologies. These ideas are incorporated by the notion of Hopf algebroids and Hopf-cyclic

CO2 Problems and waste recycling. Research at the Institute of ferrous metallurgy

International Nuclear Information System (INIS)

Gudenau, H. W.; Senk, D.; Babich, A.; Frohling, C.; Kweon, O. S.; Wang, S.; Wieting, T.

2005-01-01

In a short introduction tests and calculations about CO 2 -ice-blocs in the deep sea,use of CO 2 for underground-coal-gasifications and tertiary processes to increase oil-production by CO 2 -flooding are shown. New activities are presented e. g. CO 2 -injection into EAF combined with injection of coal, coke or direct reduction-fines. After research of injection of coals, fine ores or dust into blast furnaces and other shaft furnaces activities are compared with injection of hot reducing gas generated by coal or waste gasification or top gas recycling combined with injection of fine solid fuels. Results of injection of prepared plastics (Duales System Deutschland), shredder-light-fraction from car-recycling and unburned carbon of power-station-ashes are discussed. Beside production of direct-reduced-iron by H 2 fluidized reactor results of the reduction behaviour ore/coal or dust/coal pellets or briquettes for the use in rotary hearth or modern shaft furnaces are shown. (Author) 76 refs

Concurrent separation of CO2 and H2O from air by a temperature-vacuum swing adsorption/desorption cycle.

Science.gov (United States)

Wurzbacher, Jan Andre; Gebald, Christoph; Piatkowski, Nicolas; Steinfeld, Aldo

2012-08-21

A temperature-vacuum swing (TVS) cyclic process is applied to an amine-functionalized nanofibrilated cellulose sorbent to concurrently extract CO(2) and water vapor from ambient air. The promoting effect of the relative humidity on the CO(2) capture capacity and on the amount of coadsorbed water is quantified. The measured specific CO(2) capacities range from 0.32 to 0.65 mmol/g, and the corresponding specific H(2)O capacities range from 0.87 to 4.76 mmol/g for adsorption temperatures varying between 10 and 30 °C and relative humidities varying between 20 and 80%. Desorption of CO(2) is achieved at 95 °C and 50 mbar(abs) without dilution by a purge gas, yielding a purity exceeding 94.4%. Sorbent stability and a closed mass balance for both H(2)O and CO(2) are demonstrated for ten consecutive adsorption-desorption cycles. The specific energy requirements of the TVS process based on the measured H(2)O and CO(2) capacities are estimated to be 12.5 kJ/mol(CO2) of mechanical (pumping) work and between 493 and 640 kJ/mol(CO2) of heat at below 100 °C, depending on the air relative humidity. For a targeted CO(2) capacity of 2 mmol/g, the heat requirement would be reduced to between 272 and 530 kJ/mol(CO2), depending strongly on the amount of coadsorbed water.

On the equivalence of cyclic and quasi-cyclic codes over finite fields

Directory of Open Access Journals (Sweden)

Kenza Guenda

2017-07-01

Full Text Available This paper studies the equivalence problem for cyclic codes of length $p^r$ and quasi-cyclic codes of length $p^rl$. In particular, we generalize the results of Huffman, Job, and Pless (J. Combin. Theory. A, 62, 183--215, 1993, who considered the special case $p^2$. This is achieved by explicitly giving the permutations by which two cyclic codes of prime power length are equivalent. This allows us to obtain an algorithm which solves the problem of equivalency for cyclic codes of length $p^r$ in polynomial time. Further, we characterize the set by which two quasi-cyclic codes of length $p^rl$ can be equivalent, and prove that the affine group is one of its subsets.

The electrolytic deposition of carbon from molten Li2CO3

International Nuclear Information System (INIS)

Dimitrov, A.T.

2003-01-01

Electrodeposition of carbon on an nickel electrode in molten salt has been investigated with the aid of scanning electron microscopy (SEM) and cyclic voltammetry, using molten LiCl, as a base electrolyte with adding of 1 and 5 % of Li 2 CO 3 . Commercial nickel wire was used as a cathode and graphite crucible as the anode electrode. A cyclic voltammograms for an nickel electrode indicates that the deposition or discharge of carbon at the cathode occurs at potential range of - 0.8 to -1.7 V. Further, SEM observations showed that morphology of the carbon at the cathode is in the form of a fairly hard black deposit. It was found that the quality of the deposit depends by the cathode surface, applied overpotential, content of lithium carbonate and the thickness of the carbon film. (Original)

Cyclic [G(2',5')pA(3',5')p] is the metazoan second messenger produced by DNA-activated cyclic GMP-AMP synthase.

Science.gov (United States)

Gao, Pu; Ascano, Manuel; Wu, Yang; Barchet, Winfried; Gaffney, Barbara L; Zillinger, Thomas; Serganov, Artem A; Liu, Yizhou; Jones, Roger A; Hartmann, Gunther; Tuschl, Thomas; Patel, Dinshaw J

2013-05-23

Recent studies identified cyclic GMP-AMP (cGAMP) as a metazoan second messenger triggering an interferon response. cGAMP is generated from GTP and ATP by cytoplasmic dsDNA sensor cGAMP synthase (cGAS). We combined structural, chemical, biochemical, and cellular assays to demonstrate that this second messenger contains G(2',5')pA and A(3',5')pG phosphodiester linkages, designated c[G(2',5')pA(3',5')p]. We show that, upon dsDNA binding, cGAS is activated through conformational transitions, resulting in formation of a catalytically competent and accessible nucleotide-binding pocket for generation of c[G(2',5')pA(3',5')p]. We demonstrate that cyclization occurs in a stepwise manner through initial generation of 5'-pppG(2',5')pA prior to cyclization to c[G(2',5')pA(3',5')p], with the latter positioned precisely in the catalytic pocket. Mutants of cGAS dsDNA-binding or catalytic pocket residues exhibit reduced or abrogated activity. Our studies have identified c[G(2',5')pA(3',5')p] as a founding member of a family of metazoan 2',5'-containing cyclic heterodinucleotide second messengers distinct from bacterial 3',5' cyclic dinucleotides. Copyright © 2013 Elsevier Inc. All rights reserved.

Novel biodegradable aliphatic poly(butylene succinate-co-cyclic carbonate)s bearing functionalizable carbonate building blocks: II. Enzymatic biodegradation and in vitro biocompatibility assay.

Science.gov (United States)

Yang, Jing; Tian, Weisheng; Li, Qiaobo; Li, Yang; Cao, Amin

2004-01-01

In a previous study, we have reported chemical synthesis of novel aliphatic poly(butylene succinate-co-cyclic carbonate) P(BS-co-CC)s bearing various functionalizable carbonate building blocks, and this work will continue to present our new studies on their enzymatic degradation and in vitro cell biocompatibility assay. First, enzymatic degradation of the novel P(BS-co-CC) film samples was investigated with two enzymes of lipase B Candida Antartic (Novozyme 435) and lipase Porcine Pancreas PPL, and it was revealed that copolymerizing linear poly(butylene succinate) PBS with a functionalizable carbonate building block could remarkably accelerate the enzymatic degradation of a synthesized product P(BS-co-CC), and its biodegradation behavior was found to strongly depend on the overall impacts of several important factors as the cyclic carbonate (CC) comonomer structure and molar content, molar mass, thermal characteristics, morphology, the enzyme-substrate specificity, and so forth. Further, the biodegraded residual film samples and water-soluble enzymatic degradation products were allowed to be analyzed by means of proton nuclear magnetic resonance (1H NMR), gel permeation chromatograph (GPC), differential scanning calorimeter (DSC), attenuated total reflection FTIR (ATR-FTIR), scanning electron microscope (SEM), and liquid chromatograph-mass spectrometry (LC-MS). On the experimental evidences, an exo-type mechanism of enzymatic chain hydrolysis preferentially occurring in the noncrystalline domains was suggested for the synthesized new P(BS-co-CC) film samples. With regard to their cell biocompatibilities, an assay with NIH 3T3 mouse fibroblast cell was conducted using the novel synthesized P(BS-co-CC) films as substrates with respect to the cell adhesion and proliferation, and these new biodegradable P(BS-co-CC) samples were found to exhibit as low cell toxicity as the PLLA control, particularly the two samples of poly(butylene succinate-co-18.7 mol % dimethyl

Exploring the co-production of digital storytelling for lay knowledge exchange within and between flood risk communities: the case of the River Severn, UK

Directory of Open Access Journals (Sweden)

Holmes Andrew

2016-01-01

Full Text Available This paper evaluates the potential role of co-produced digital storytelling as a medium of linking flood memories and lay knowledge exchange around flood preparedness for resilience within flood risk communities. The objectives of the described action focus on both process andd output - to capture memory of flood events, and to share critical reflection on, and adaptive learning from, flood experiences within and between communities. Very specific pieces of resilience stories on preparedness were co-produced into digital stories (audio and images working with individuals and small clusters of people. In the development process, stories were shared within the communities who created them, and within new communities. At all community events, the experience of sharing the stories was observed and evaluated using participant and facilitator questionnaires and independent observation. When shared in community events, the value of the digital media, nature of the story construction, the local or transferable nature of messages, and emotional weight given to the story were all appraised. The stories stimulated new discussions within different community groups and in multi-stakeholder meetings; conversations generated by the same digital story were found to differ depending on the setting. Listeners had high degrees of empathy with the stories gaining insights around “mobilising community#x201D; and “developing emotional resilience”. The paper explores issues of engagement in order to produce a participatory media -demonstrating the process and tensions of exchanging knowledge, and how the cultural practice of digital storytelling can jump the divide to policymaking and function as a successful way of engaging a wider public at flood risk.

Fate of injected CO2 in the Wilcox Group, Louisiana, Gulf Coast Basin: Chemical and isotopic tracers of microbial–brine–rock–CO2 interactions

Science.gov (United States)

Shelton, Jenna L.; McIntosh, Jennifer C.; Warwick, Peter D.; Lee Zhi Yi, Amelia

2014-01-01

The “2800’ sandstone” of the Olla oil field is an oil and gas-producing reservoir in a coal-bearing interval of the Paleocene–Eocene Wilcox Group in north-central Louisiana, USA. In the 1980s, this producing unit was flooded with CO2 in an enhanced oil recovery (EOR) project, leaving ∼30% of the injected CO2 in the 2800’ sandstone post-injection. This study utilizes isotopic and geochemical tracers from co-produced natural gas, oil and brine to determine the fate of the injected CO2, including the possibility of enhanced microbial conversion of CO2 to CH4 via methanogenesis. Stable carbon isotopes of CO2, CH4 and DIC, together with mol% CO2 show that 4 out of 17 wells sampled in the 2800’ sandstone are still producing injected CO2. The dominant fate of the injected CO2appears to be dissolution in formation fluids and gas-phase trapping. There is some isotopic and geochemical evidence for enhanced microbial methanogenesis in 2 samples; however, the CO2 spread unevenly throughout the reservoir, and thus cannot explain the elevated indicators for methanogenesis observed across the entire field. Vertical migration out of the target 2800’ sandstone reservoir is also apparent in 3 samples located stratigraphically above the target sand. Reservoirs comparable to the 2800’ sandstone, located along a 90-km transect, were also sampled to investigate regional trends in gas composition, brine chemistry and microbial activity. Microbial methane, likely sourced from biodegradation of organic substrates within the formation, was found in all oil fields sampled, while indicators of methanogenesis (e.g. high alkalinity, δ13C-CO2 and δ13C-DIC values) and oxidation of propane were greatest in the Olla Field, likely due to its more ideal environmental conditions (i.e. suitable range of pH, temperature, salinity, sulfate and iron concentrations).

Automatic domain updating technique for improving computational efficiency of 2-D flood-inundation simulation

Science.gov (United States)

Tanaka, T.; Tachikawa, Y.; Ichikawa, Y.; Yorozu, K.

2017-12-01

Flood is one of the most hazardous disasters and causes serious damage to people and property around the world. To prevent/mitigate flood damage through early warning system and/or river management planning, numerical modelling of flood-inundation processes is essential. In a literature, flood-inundation models have been extensively developed and improved to achieve flood flow simulation with complex topography at high resolution. With increasing demands on flood-inundation modelling, its computational burden is now one of the key issues. Improvements of computational efficiency of full shallow water equations are made from various perspectives such as approximations of the momentum equations, parallelization technique, and coarsening approaches. To support these techniques and more improve the computational efficiency of flood-inundation simulations, this study proposes an Automatic Domain Updating (ADU) method of 2-D flood-inundation simulation. The ADU method traces the wet and dry interface and automatically updates the simulation domain in response to the progress and recession of flood propagation. The updating algorithm is as follow: first, to register the simulation cells potentially flooded at initial stage (such as floodplains nearby river channels), and then if a registered cell is flooded, to register its surrounding cells. The time for this additional process is saved by checking only cells at wet and dry interface. The computation time is reduced by skipping the processing time of non-flooded area. This algorithm is easily applied to any types of 2-D flood inundation models. The proposed ADU method is implemented to 2-D local inertial equations for the Yodo River basin, Japan. Case studies for two flood events show that the simulation is finished within two to 10 times smaller time showing the same result as that without the ADU method.

Reduced Graphene Oxide: Is it a promising catalyst for the electrochemistry of [UO2(CO3)3]4−/[UO2(CO3)3]5−?

International Nuclear Information System (INIS)

Guin, Saurav K.; Ambolikar, Arvind S.; Kamat, J.V.

2015-01-01

Highlights: • First report on aqueous electrochemistry of uranium on graphene materials. • Graphene(Nafion)/GC did not show applicability for the anionic analytes. • Electrochemically Reduced Graphene Oxide (ERGNO) was synthesised by cyclic voltammetry. • ERGNO catalysed the electrochemistry of [U VI O 2 (CO 3 ) 3 ] 4- /[U V O 2 (CO 3 ) 3 ] 5- . • Both the cathodic and anodic overpotentials of U(VI)/U(V) reaction decreased on ERGNO. - Abstract: The graphene has been emerging in the electrocatalysis and electroanalysis as the potent surface modifying agents for the working electrodes. However, the aqueous electrochemistry of the actinides on graphene (or graphene type materials) is yet unexplored. In this paper, the aqueous electrochemistry of [U VI O 2 (CO 3 ) 3 ] 4− /[U V O 2 (CO 3 ) 3 ] 5− redox couple was systematically investigated on electrochemically reduced graphene oxide (ERGNO) modified glassy carbon (GC) electrode in saturated Na 2 CO 3 solution (pH ∼12.3). This is the first report on aqueous actinide electrochemistry on graphene materials. The results showed that ERGNO could catalyse the redox chemistry of [U VI O 2 (CO 3 ) 3 ] 4− /[U V O 2 (CO 3 ) 3 ] 5− by reducing both the cathodic and anodic overpotentials compared to bare GC electrode. However, no enhancement in the peak current was observed on ERGNO electrode for the same reaction. Therefore, the present study introduces an appeal for a systematic investigation on the electrochemistry of the actinides at graphene materials to gear up their applications in nuclear technology

Integrated Reservoir Modeling of CO2-EOR Performance and Storage Potential in the Farnsworth Field Unit, Texas.

Science.gov (United States)

Ampomah, W.; Balch, R. S.; Cather, M.; Dai, Z.

2017-12-01

We present a performance assessment methodology and storage potential for CO2 enhanced oil recovery (EOR) in partially depleted reservoirs. A three dimensional heterogeneous reservoir model was developed based on geological, geophysics and engineering data from Farnsworth field Unit (FWU). The model aided in improved characterization of prominent rock properties within the Pennsylvanian aged Morrow sandstone reservoir. Seismic attributes illuminated previously unknown faults and structural elements within the field. A laboratory fluid analysis was tuned to an equation of state and subsequently used to predict the thermodynamic minimum miscible pressure (MMP). Datasets including net-to-gross ratio, volume of shale, permeability, and burial history were used to model initial fault transmissibility based on Sperivick model. An improved history match of primary and secondary recovery was performed to set the basis for a CO2 flood study. The performance of the current CO2 miscible flood patterns was subsequently calibrated to historical production and injection data. Several prediction models were constructed to study the effect of recycling, addition of wells and /or new patterns, water alternating gas (WAG) cycles and optimum amount of CO2 purchase on incremental oil production and CO2 storage in the FWU. The history matching study successfully validated the presence of the previously undetected faults within FWU that were seen in the seismic survey. The analysis of the various prediction scenarios showed that recycling a high percentage of produced gas, addition of new wells and a gradual reduction in CO2 purchase after several years of operation would be the best approach to ensure a high percentage of recoverable incremental oil and sequestration of anthropogenic CO2 within the Morrow reservoir. Larger percentage of stored CO2 were dissolved in residual oil and less amount existed as supercritical free CO2. The geomechanical analysis on the caprock proved to an

OIL RESERVOIR CHARACTERIZATION AND CO2 INJECTION MONITORING IN THE PERMIAN BASIN WITH CROSSWELL ELECTROMAGNETIC IMAGING

Energy Technology Data Exchange (ETDEWEB)

Michael Wilt

2004-02-01

Substantial petroleum reserves exist in US oil fields that cannot be produced economically, at current prices, unless improvements in technology are forthcoming. Recovery of these reserves is vital to US economic and security interests as it lessens our dependence on foreign sources and keeps our domestic petroleum industry vital. Several new technologies have emerged that may improve the situation. The first is a series of new flooding techniques to re-pressurize reservoirs and improve the recovery. Of these the most promising is miscible CO{sub 2} flooding, which has been used in several US petroleum basins. The second is the emergence of new monitoring technologies to track and help manage this injection. One of the major players in here is crosswell electromagnetics, which has a proven sensitivity to reservoir fluids. In this project, we are applying the crosswell EM technology to a CO{sub 2} flood in the Permian Basin oil fields of New Mexico. With our partner ChevronTexaco, we are testing the suitability of using EM for tracking the flow of injected CO{sub 2} through the San Andreas reservoir in the Vacuum field in New Mexico. The project consisted of three phases, the first of which was a preliminary field test at Vacuum, where a prototype system was tested in oil field conditions including widely spaced wells with steel casing. The results, although useful, demonstrated that the older technology was not suitable for practical deployment. In the second phase of the project, we developed a much more powerful and robust field system capable of collecting and interpreting field data through steel-cased wells. The final phase of the project involved applying this system in field tests in the US and overseas. Results for tests in steam and water floods showed remarkable capability to image between steel wells and provided images that helped understand the geology and ongoing flood and helped better manage the field. The future of this technology is indeed bright

Flooding in counter-current two-phase flow

International Nuclear Information System (INIS)

Ragland, W.A.; Ganic, E.N.

1982-01-01

Flooding is a phenomenon which is best described as the transition from counter-current to co-current flow. Early notice was taken of this phenomenon in the chemical engineering industry. Flooding also plays an important role in the field of two-phase heat transfer since it is a limit for many systems involving counter-current flow. Practical applications of flooding limited processes include wickless thermosyphons and the emergency core cooling system (ECCS) of pressurized water nuclear reactors. The phenomenon of flooding also is involved in the behavior of nuclear reactor core materials during severe accident conditions where flooding is one of the mechanisms governing the motion of the molten fuel pin cladding

Flooding in counter-current two-phase flow

Energy Technology Data Exchange (ETDEWEB)

Ragland, W.A.; Ganic, E.N.

1982-01-01

Flooding is a phenomenon which is best described as the transition from counter-current to co-current flow. Early notice was taken of this phenomenon in the chemical engineering industry. Flooding also plays an important role in the field of two-phase heat transfer since it is a limit for many systems involving counter-current flow. Practical applications of flooding limited processes include wickless thermosyphons and the emergency core cooling system (ECCS) of pressurized water nuclear reactors. The phenomenon of flooding also is involved in the behavior of nuclear reactor core materials during severe accident conditions where flooding is one of the mechanisms governing the motion of the molten fuel pin cladding.

Regional-scale advective, diffusive, and eruptive dynamics of CO2 and brine leakage through faults and wellbores

Science.gov (United States)

Jung, Na-Hyun; Han, Weon Shik; Han, Kyungdoe; Park, Eungyu

2015-05-01

Regional-scale advective, diffusive, and eruptive transport dynamics of CO2 and brine within a natural analogue in the northern Paradox Basin, Utah, were explored by integrating numerical simulations with soil CO2 flux measurements. Deeply sourced CO2 migrates through steeply dipping fault zones to the shallow aquifers predominantly as an aqueous phase. Dense CO2-rich brine mixes with regional groundwater, enhancing CO2 dissolution. Linear stability analysis reveals that CO2 could be dissolved completely within only 500 years. Assigning lower permeability to the fault zones induces fault-parallel movement, feeds up-gradient aquifers with more CO2, and impedes down-gradient fluid flow, developing anticlinal CO2 traps at shallow depths (<300 m). The regional fault permeability that best reproduces field spatial CO2 flux variation is estimated 1 × 10-17 ≤ kh < 1 × 10-16 m2 and 5 × 10-16 ≤ kv < 1 × 10-15 m2. The anticlinal trap serves as an essential fluid source for eruption at Crystal Geyser. Geyser-like discharge sensitively responds to varying well permeability, radius, and CO2 recharge rate. The cyclic behavior of wellbore CO2 leakage decreases with time.

Layered Ni(OH)2-Co(OH)2 films prepared by electrodeposition as charge storage electrodes for hybrid supercapacitors.

Science.gov (United States)

Nguyen, Tuyen; Boudard, Michel; Carmezim, M João; Montemor, M Fátima

2017-01-04

Consecutive layers of Ni(OH) 2 and Co(OH) 2 were electrodeposited on stainless steel current collectors for preparing charge storage electrodes of high specific capacity with potential application in hybrid supercapacitors. Different electrodes were prepared consisting on films of Ni(OH) 2 , Co(OH) 2 , Ni 1/2 Co 1/2 (OH) 2 and layered films of Ni(OH) 2 on Co(OH) 2 and Co(OH) 2 on Ni(OH) 2 to highlight the advantages of the new architecture. The microscopy studies revealed the formation of nanosheets in the Co(OH) 2 films and of particles agglomerates in the Ni(OH) 2 films. Important morphological changes were observed in the double hydroxides films and layered films. Film growth by electrodeposition was governed by instantaneous nucleation mechanism. The new architecture composed of Ni(OH) 2 on Co(OH) 2 displayed a redox response characterized by the presence of two peaks in the cyclic voltammograms, arising from redox reactions of the metallic species present in the layered film. These electrodes revealed a specific capacity of 762 C g -1 at the specific current of 1 A g -1 . The hybrid cell using Ni(OH) 2 on Co(OH) 2 as positive electrode and carbon nanofoam paper as negative electrode display specific energies of 101.3 W h g -1 and 37.8 W h g -1 at specific powers of 0.2 W g -1 and 2.45 W g -1 , respectively.

Elevated CO2 causes changes in the photosynthetic apparatus of a toxic cyanobacterium, Cylindrospermopsis raciborskii.

Science.gov (United States)

Pierangelini, Mattia; Stojkovic, Slobodanka; Orr, Philip T; Beardall, John

2014-07-15

We studied the physiological acclimation of growth, photosynthesis and CO2-concentrating mechanism (CCM) in Cylindrospermopsis raciborskii exposed to low (present day; L-CO2) and high (1300ppm; H-CO2) pCO2. Results showed that under H-CO2 the cell specific division rate (μc) was higher and the CO2- and light-saturated photosynthetic rates (Vmax and Pmax) doubled. The cells' photosynthetic affinity for CO2 (K0.5CO2) was halved compared to L-CO2 cultures. However, no significant differences were found in dark respiration rates (Rd), pigment composition and light harvesting efficiency (α). In H-CO2 cells, non-photochemical quenching (NPQ), associated with state transitions of the electron transport chain (ETC), was negligible. Simultaneously, a reorganisation of PSII features including antenna connectivity (JconPSIIα), heterogeneity (PSIIα/β) and effective absorption cross sectional area (σPSIIα/β) was observed. In relation to different activities of the CCM, our findings suggest that for cells grown under H-CO2: (1) there is down-regulation of CCM activity; (2) the ability of cells to use the harvested light energy is altered; (3) the occurrence of state transitions is likely to be associated with changes of electron flow (cyclic vs linear) through the ETC; (4) changes in PSII characteristics are important in regulating state transitions. Copyright © 2014 Elsevier GmbH. All rights reserved.

One pot synthesized Li, Zr doped porous silica nanoparticle for low temperature CO2 adsorption

Directory of Open Access Journals (Sweden)

Mani Ganesh

2017-05-01

Full Text Available Li, Zr doped porous silica was synthesized in one pot and investigated for low temperature CO2 adsorption. The synthesized nanoparticle was characterized by X-ray diffraction (XRD, N2 adsorption–desorption measurement, thermogravimetric analysis (TGA and scanning electron microscopy (SEM. The specific surface area, average pore diameter and pore volume were determined to be 962 m2/g, 2.3 nm and 0.56 cm3/g respectively. ICP-AES analysis revealed a metal content of 4 wt.% (Zr and 3.42 wt.% (Li. Their CO2 adsorption capacity was tested at room temperature and atmospheric pressure. An uptake of about 5 wt.% was observed and regenerable at a low temperature of 200 °C. This adsorption and desorption temperature of the sorbent is lower than the reported lithium silicate. The CO2 adsorption–desorption cyclic performance studies illustrated that Li, Zr doped porous silica is a recyclable, selective and potential sorbent for CO2 adsorption.

A new approach for river flood extent delineation in rural and urban areas combining RADARSAT-2 imagery and flood recurrence interval data

Science.gov (United States)

Tanguy, Marion; Bernier, Monique; Chokmani, Karem

2015-04-01

When a flood hits an inhabited area, managers and services responsible for public safety need precise, reliable and up to date maps of the areas affected by the flood, in order to quickly roll out and to coordinate the adequate intervention and assistance plans required to limit the human and material damages caused by the disaster. Synthetic aperture radar (SAR) sensors are now considered as one of the most adapted tool for flood detection and mapping in a context of crisis management. Indeed, due to their capacity to acquire data night and day, in almost all meteorological conditions, SAR sensors allow the acquisition of synoptic but detailed views of the areas affected by the flood, even during the active phases of the event. Moreover, new generation sensors such as RADARSAT-2, TerraSAR-X, COSMO-SkyMed, are providing very high resolution images of the disaster (down to 1m ground resolution). Further, critical improvements have been made on the temporal repetitivity of acquisitions and on data availability, through the development of satellite constellations (i.e the four COSMO-Skymed or the Sentinel-1A and 1B satellites) and thanks to the implementation of the International Charter "Space and Major Disasters", which guarantees high priority images acquisition and delivery with 4 to 12 hours. If detection of open water flooded areas is relatively straightforward with SAR imagery, flood detection in built-up areas is often associated with important issues. Indeed, because of the side looking geometry of the SAR sensors, structures such as tall vegetation and structures parallel to the satellite direction of travel may produce shadow and layover effects, leading to important over and under-detections of flooded pixels. Besides, the numerous permanent water-surfaces like radar response areas present in built-up environments, such as parking lots, roads etc., may be mixed up with flooded areas, resulting in substantial inaccuracies in the final flood map. In spite of

An Experimental Study of Surfactant Alternating CO2 Injection for Enhanced Oil Recovery of Carbonated Reservoir

Directory of Open Access Journals (Sweden)

Asghar Gandomkar

2016-10-01

Full Text Available Core flooding experiments were conducted with the objective of evaluating near miscible surfactant alternating CO2 injection and the effect of surfactant concentrations on gas-oil and water displacements in porous media. The core samples were provided from a low permeability mixed wet oil reservoir at 156 °F and 1900 psia. In addition, very few studies of surfactant adsorption on carbonate minerals have been conducted. Hence, the surfactant adsorption on carbonate rock was determined by core flooding and crushed tests. It was found that for the crushed rock, the required equilibrium time is approximately five hours, while it is more than four days for the flow-through tests. Hysteresis effects demonstrated that the irreducible water saturations were 5 to 10% higher than the initial connate water saturation after drainage cycles during 5000 ppm surfactant solution. Furthermore, near-miscible surfactant alternating CO2 injection process led to a 4-17% increase in the recovery factor in comparison to water alternating gas process.

Large-scale boiling experiments of the flooded cavity concept for in-vessel core retention

International Nuclear Information System (INIS)

Chu, T.Y.; Slezak, S.E.; Bentz, J.H.; Pasedag, W.F.

1994-01-01

This paper presents results of ex-vessel boiling experiments performed in the CYBL (CYlindrical BoiLing) facility. CYBL is a reactor-scale facility for confirmatory research of the flooded cavity concept for accident management. CYBL has a tank-within-a-tank design; the inner tank simulates the reactor vessel and the outer tank simulates the reactor cavity. Experiments with uniform and edge-peaked heat flux distributions up to 20 W/cm 2 across the vessel bottom were performed. Boiling outside the reactor vessel was found to be subcooled nucleate boiling. The subcooling is mainly due to the gravity head which results from flooding the sides of the reactor vessel. The boiling process exhibits a cyclic pattern with four distinct phases: direct liquid/solid contact, bubble nucleation and growth, coalescence, and vapor mass dispersion (ejection). The results suggest that under prototypic heat load and heat flux distributions, the flooded cavity in a passive pressurized water reactor like the AP-600 should be capable of cooling the reactor pressure vessel in the central region of the lower head that is addressed by these tests

Cyclic biogeochemical processes and nitrogen fate beneath a subtropical stormwater infiltration basin.

Science.gov (United States)

O'Reilly, Andrew M; Chang, Ni-Bin; Wanielista, Martin P

2012-05-15

A stormwater infiltration basin in north-central Florida, USA, was monitored from 2007 through 2008 to identify subsurface biogeochemical processes, with emphasis on N cycling, under the highly variable hydrologic conditions common in humid, subtropical climates. Cyclic variations in biogeochemical processes generally coincided with wet and dry hydrologic conditions. Oxidizing conditions in the subsurface persisted for about one month or less at the beginning of wet periods with dissolved O(2) and NO(3)(-) showing similar temporal patterns. Reducing conditions in the subsurface evolved during prolonged flooding of the basin. At about the same time O(2) and NO(3)(-) reduction concluded, Mn, Fe and SO(4)(2-) reduction began, with the onset of methanogenesis one month later. Reducing conditions persisted up to six months, continuing into subsequent dry periods until the next major oxidizing infiltration event. Evidence of denitrification in shallow groundwater at the site is supported by median NO(3)(-)-N less than 0.016 mg L(-1), excess N(2) up to 3 mg L(-1) progressively enriched in δ(15)N during prolonged basin flooding, and isotopically heavy δ(15)N and δ(18)O of NO(3)(-) (up to 25‰ and 15‰, respectively). Isotopic enrichment of newly infiltrated stormwater suggests denitrification was partially completed within two days. Soil and water chemistry data suggest that a biogeochemically active zone exists in the upper 1.4m of soil, where organic carbon was the likely electron donor supplied by organic matter in soil solids or dissolved in infiltrating stormwater. The cyclic nature of reducing conditions effectively controlled the N cycle, switching N fate beneath the basin from NO(3)(-) leaching to reduction in the shallow saturated zone. Results can inform design of functionalized soil amendments that could replace the native soil in a stormwater infiltration basin and mitigate potential NO(3)(-) leaching to groundwater by replicating the biogeochemical

Synthesis of Mesoporous Single Crystal Co(OH)2 Nanoplate and Its Topotactic Conversion to Dual-Pore Mesoporous Single Crystal Co3O4.

Science.gov (United States)

Jia, Bao-Rui; Qin, Ming-Li; Li, Shu-Mei; Zhang, Zi-Li; Lu, Hui-Feng; Chen, Peng-Qi; Wu, Hao-Yang; Lu, Xin; Zhang, Lin; Qu, Xuan-Hui

2016-06-22

A new class of mesoporous single crystalline (MSC) material, Co(OH)2 nanoplates, is synthesized by a soft template method, and it is topotactically converted to dual-pore MSC Co3O4. Most mesoporous materials derived from the soft template method are reported to be amorphous or polycrystallined; however, in our synthesis, Co(OH)2 seeds grow to form single crystals, with amphiphilic block copolymer F127 colloids as the pore producer. The single-crystalline nature of material can be kept during the conversion from Co(OH)2 to Co3O4, and special dual-pore MSC Co3O4 nanoplates can be obtained. As the anode of lithium-ion batteries, such dual-pore MSC Co3O4 nanoplates possess exceedingly high capacity as well as long cyclic performance (730 mAh g(-1) at 1 A g(-1) after the 350th cycle). The superior performance is because of the unique hierarchical mesoporous structure, which could significantly improve Li(+) diffusion kinetics, and the exposed highly active (111) crystal planes are in favor of the conversion reaction in the charge/discharge cycles.

Effective Wettability Measurements of CO2-Brine-Sandstone System at Different Reservoir Conditions

Science.gov (United States)

Al-Menhali, Ali; Krevor, Samuel

2014-05-01

The wetting properties of CO2-brine-rock systems will have a major impact on the management of CO2 injection processes. The wettability of a system controls the flow and trapping efficiency during the storage of CO2 in geological formations as well as the efficiency of enhanced oil recovery operations. Despite its utility in EOR and the continued development of CCS, little is currently known about the wetting properties of the CO2-brine system on reservoir rocks, and no investigations have been performed assessing the impact of these properties on CO2 flooding for CO2 storage or EOR. The wetting properties of multiphase fluid systems in porous media have major impacts on the multiphase flow properties such as the capillary pressure and relative permeability. While recent studies have shown CO2 to generally act as a non-wetting phase in siliciclastic rocks, some observations report that the contact angle varies with pressure, temperature and water salinity. Additionally, there is a wide range of reported contact angles for this system, from strongly to weakly water-wet. In the case of some minerals, intermediate wet contact angles have been observed. Uncertainty with regard to the wetting properties of CO2-brine systems is currently one of the remaining major unresolved issues with regards to reservoir management of CO2 storage. In this study, we make semi-dynamic capillary pressure measurements of supercritical CO2 and brine at reservoir conditions to observe shifts in the wetting properties. We utilize a novel core analysis technique recently developed by Pini et al in 2012 to evaluate a core-scale effective contact angle. Carbon dioxide is injected at constant flow rate into a core that is initially fully saturated with water, while maintaining a constant outlet pressure. In this scenario, the pressure drop across the core corresponds to the capillary pressure at the inlet face of the core. When compared with mercury intrusion capillary pressure measurements

Recycling of cobalt from spent Li-ion batteries as β-Co(OH)2 and the application of Co3O4 as a pseudocapacitor

Science.gov (United States)

Barbieri, E. M. S.; Lima, E. P. C.; Lelis, M. F. F.; Freitas, M. B. J. G.

2014-12-01

This work has investigated recycling cobalt from the cathodes of spent Li-ion batteries as β-Co(OH)2, obtaining Co3O4. β-Co(OH)2 with a hexagonal structure by using chemical precipitation (CP) or electrochemical precipitation (EP). In addition, the study has investigated whether the charge density applied directly affects the β-Co(OH)2 morphology. Co3O4 is formed by heat-treating β-Co(OH)2 at 450 °C for 3 h (h) in an air atmosphere. After calcining, the Co3O4 shows a cubic structure and satisfactory purity grade, regardless of the route used for preparation via which it was obtained. Cyclic voltammetry (CV) is then used for electrochemical characterization of the Co3O4 composite electrodes. In the cathodic process, CoO2 undergoes reduction to CoOOH, which undergoes further reduction to Co3O4. In the anodic process, Co3O4 undergoes oxidation to CoOOH, which simultaneously undergoes further oxidation to CoO2. The composite electrodes containing Co3O4, carbon black, and epoxy resin show great reversibility, charge efficiency, and a specific capacitance of 13.0 F g-1 (1.0 mV s-1). The synthesis method of Co(OH)2 influences the charge efficiency of Co3O4 composite electrodes at a scan rate of 10.0 mV s-1. Therefore, in addition to presenting an alternative use for exhausted batteries, Co3O4 composites exhibit favorable characteristics for use as pseudocapacitors.

Plastic strain accumulation during asymmetric cyclic loading of Zircaloy-2 at room temperature

International Nuclear Information System (INIS)

Rajpurohit, R.S.; Santhi Srinivas, N.C.; Singh, Vakil

2016-01-01

Asymmetric cyclic loading leads to accumulation of cyclic plastic strain and reduces the fatigue life of components. This phenomenon is known as ratcheting fatigue. Zircaloy-2 is a important structural material in nuclear reactors and used as pressure tubes and fuel cladding in pressurized light and heavy water nuclear reactors. Due to power fluctuations, these components experience plastic strain cycles in the reactor and their life is reduced due to strain cycles. Power fluctuations also cause asymmetric straining of the material and leads to accumulation of plastic strain. The present investigation deals with the effect of the magnitude of mean stress, stress amplitude and stress rate on hardening/softening behavior of Zircaloy-2 under asymmetric cyclic loading, at room temperature. It was observed that plastic strain accumulation increased with mean stress and stress amplitude; however, it decreased with stress rate. (author)

New iron pyridylamino-bis(phenolate) catalyst for converting CO2 into cyclic carbonates and cross-linked polycarbonates

NARCIS (Netherlands)

Taherimehr, Masoumeh; Sertã, João Paulo C.ardoso Costa; Kleij, Arjan W.; Whiteoak, Christopher J.; Pescarmona, Paolo P.

2015-01-01

The atom-efficient reaction of CO2 with a variety of epoxides has been efficiently achieved employing iron pyridylamino-bis(phenolate) complexes as bifunctional catalysts. The addition of a Lewis base co-catalyst allowed significant reduction in the amount of iron complex needed to achieve high

Electroreduction of CO2 into Ethanol over an Active Catalyst: Copper Supported on Titania

OpenAIRE

Jing Yuan; Li Liu; Rong-Rong Guo; Sheng Zeng; Huan Wang; Jia-Xing Lu

2017-01-01

A simple, inexpensive, and novel method was used to prepare electrocatalysts from Cu supported on titanium dioxide (Cu/TiO2). XRD, SEM, and TEM characterizations confirmed different loadings of Cu nanoparticles (NPs) on TiO2. Cyclic voltammetry tests indicated that Cu/TiO2 exhibited lower overpotential for CO2 reduction than that of Cu NPs. Moreover, 40 wt % Cu/TiO2 exhibited the highest faradaic efficiency for ethanol (FEethanol) of 27.4%, which is approximately 10-fold higher than that for ...

Cyclic-2,3-diphosphoglycerate levels in Methanobacterium thermoautotrophicum reflect inorganic phosphate availability.

Science.gov (United States)

Seely, R J; Krueger, R D; Fahrney, D E

1983-11-15

Methanobacterium thermoautotrophicum was grown in phosphate-limited chemostat cultures at a dilution rate corresponding to a doubling time of 13.2 h. The cyclic-2,3-diphospho-D-glycerate content of these cells was 8 to 10-fold lower than that of cells grown in batch cultures having a doubling time of 11.5 h. This metabolite accounted for 5% of cell dry weight during batch growth on 2 mM phosphate. In the chemostat the steady-state concentration of phosphate was 4 microM, showing that this methanogen is adapted to highly efficient growth at low phosphate concentrations. Since growth rates were similar in both cultures, the growth rate clearly does not depend on intracellular levels of cyclic-2,3-diphosphoglycerate.

Corrosion characteristics of an aluminium alloy in the H3PO4 - CO2 mixture

International Nuclear Information System (INIS)

Aljinovic, Lj.; Smith, M.; Gotovac, V.

1998-01-01

The Al 6063 alloy examined in this work contains silicon and magnesium capable of forming Mg 2 Si and iron, which can form an intermetallic second phase (FeAl 3 ). In order to examine the influence of temperature on the corrosion behaviour of the Al 6063 alloy, examinations were carried out in aerated H 3 PO 4 and in H 3 PO 4 saturated with CO 2 at temperatures of 20, 30, 40, and 50 C. The following electrochemical methods were applied: determination of dependence of E OCP on time, recording of anodic and cathodic polarization curves, and cyclic voltammetry. It has been observed that corrosion parameters obtained are strongly temperature dependent. They also depend on CO 2 dissolved in H 3 PO 4 . CO 2 retards cathodic and anodic reactions at all temperatures, which can be attributed to formation of a kind of mechanical passivity as alloy components react with CO 2 . (orig.)

Development of a cost-effective CO2 adsorbent from petroleum coke via KOH activation

Science.gov (United States)

Jang, Eunji; Choi, Seung Wan; Hong, Seok-Min; Shin, Sangcheol; Lee, Ki Bong

2018-01-01

The capture of CO2 via adsorption is considered an effective technology for decreasing global warming issues; hence, adsorbents for CO2 capture have been actively developed. Taking into account cost-effectiveness and environmental concerns, the development of CO2 adsorbents from waste materials is attracting considerable attention. In this study, petroleum coke (PC), which is the carbon residue remaining after heavy oil upgrading, was used to produce high-value-added porous carbon for CO2 capture. Porous carbon materials were prepared by KOH activation using different weight ratios of KOH/PC (1:1, 2:1, 3:1, and 4:1) and activation temperatures (600, 700, and 800 °C). The specific surface area and total pore volume of resulting porous carbon materials increased with KOH amount, reaching up to 2433 m2/g and 1.11 cm3/g, respectively. The sample prepared under moderate conditions with a KOH/PC weight ratio of 2:1 and activation temperature of 700 °C exhibited the highest CO2 adsorption uptake of 3.68 mmol/g at 25 °C and 1 bar. Interestingly, CO2 adsorption uptake was linearly correlated with the volume of micropores less than 0.8 nm, indicating that narrow micropore volume is crucial for CO2 adsorption. The prepared porous carbon materials also exhibited good selectivity for CO2 over N2, rapid adsorption, facile regeneration, and stable adsorption-desorption cyclic performance, demonstrating potential as a candidate for CO2 capture.

Post Waterflood CO2 Miscible Flood in Light Oil, Fluvial-Dominated Deltaic Reservoir, Class I

Energy Technology Data Exchange (ETDEWEB)

Bou-Mikael, Sami

2002-02-05

This report demonstrates the effectiveness of the CO2 miscible process in Fluvial Dominated Deltaic reservoirs. It also evaluated the use of horizontal CO2 injection wells to improve the overall sweep efficiency. A database of FDD reservoirs for the gulf coast region was developed by LSU, using a screening model developed by Texaco Research Center in Houston. The results of the information gained in this project is disseminated throughout the oil industry via a series of SPE papers and industry open forums.

One-step engineered self-assembly Co3O4 nanoparticles to nanocubes for supercapacitors

Science.gov (United States)

Nagajyothi, P. C.; Pandurangan, M.; Sreekanth, T. V. M.; Shim, Jaesool

2018-02-01

Tricobalt tetraoxide or cobalt oxide (Co3O4) nanocubes (NCs) were synthesized from the self-assemblies of Co3O4 nanoparticles (NPs) via a simple one-step hydrothermal method. X-ray diffraction analysis confirmed the cubic crystal structure of Co3O4 NCs. The surface properties were investigated by x-ray photoelectron spectroscopy, which suggests the co-existence of Co in +2 and +3 states. The self-assemblies of aggregation of NPs to NCs were inspected using scanning electron microscopy, which is supported by transmission electron microscopy. The electrochemical properties of Co3O4 NCs were carried out by cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) curves and impedance analysis. The areal capacitance of 3.04 mF cm-2 was obtained at current density of 10 μA cm-2. The Co3O4 NCs electrode exhibits good long-cyclic stability with 92.1% capacitance retention over 3000 cycles. The CV, GCD and impedance curves of Co3O4 NCs were recorded after cyclic test, which are similar to the curves recorded before the test. Therefore, the Co3O4 NCs serves good candidate as positive electrode materials for asymmetric supercapacitors.

4-D High-Resolution Seismic Reflection Monitoring of Miscible CO2 Injected into a Carbonate Reservoir

Energy Technology Data Exchange (ETDEWEB)

Richard D. Miller; Abdelmoneam E. Raef; Alan P. Byrnes; William E. Harrison

2007-06-30

The objective of this research project was to acquire, process, and interpret multiple high-resolution 3-D compressional wave and 2-D, 2-C shear wave seismic data in the hopes of observing changes in fluid characteristics in an oil field before, during, and after the miscible carbon dioxide (CO{sub 2}) flood that began around December 1, 2003, as part of the DOE-sponsored Class Revisit Project (DOE No.DE-AC26-00BC15124). Unique and key to this imaging activity is the high-resolution nature of the seismic data, minimal deployment design, and the temporal sampling throughout the flood. The 900-m-deep test reservoir is located in central Kansas oomoldic limestones of the Lansing-Kansas City Group, deposited on a shallow marine shelf in Pennsylvanian time. After 30 months of seismic monitoring, one baseline and eight monitor surveys clearly detected changes that appear consistent with movement of CO{sub 2} as modeled with fluid simulators and observed in production data. Attribute analysis was a very useful tool in enhancing changes in seismic character present, but difficult to interpret on time amplitude slices. Lessons learned from and tools/techniques developed during this project will allow high-resolution seismic imaging to be routinely applied to many CO{sub 2} injection programs in a large percentage of shallow carbonate oil fields in the midcontinent.

Tidal marsh plant responses to elevated CO2 , nitrogen fertilization, and sea level rise.

Science.gov (United States)

Adam Langley, J; Mozdzer, Thomas J; Shepard, Katherine A; Hagerty, Shannon B; Patrick Megonigal, J

2013-05-01

Elevated CO2 and nitrogen (N) addition directly affect plant productivity and the mechanisms that allow tidal marshes to maintain a constant elevation relative to sea level, but it remains unknown how these global change drivers modify marsh plant response to sea level rise. Here we manipulated factorial combinations of CO2 concentration (two levels), N availability (two levels) and relative sea level (six levels) using in situ mesocosms containing a tidal marsh community composed of a sedge, Schoenoplectus americanus, and a grass, Spartina patens. Our objective is to determine, if elevated CO2 and N alter the growth and persistence of these plants in coastal ecosystems facing rising sea levels. After two growing seasons, we found that N addition enhanced plant growth particularly at sea levels where plants were most stressed by flooding (114% stimulation in the + 10 cm treatment), and N effects were generally larger in combination with elevated CO2 (288% stimulation). N fertilization shifted the optimal productivity of S. patens to a higher sea level, but did not confer S. patens an enhanced ability to tolerate sea level rise. S. americanus responded strongly to N only in the higher sea level treatments that excluded S. patens. Interestingly, addition of N, which has been suggested to accelerate marsh loss, may afford some marsh plants, such as the widespread sedge, S. americanus, the enhanced ability to tolerate inundation. However, if chronic N pollution reduces the availability of propagules of S. americanus or other flood-tolerant species on the landscape scale, this shift in species dominance could render tidal marshes more susceptible to marsh collapse. © 2013 Blackwell Publishing Ltd.

1D and 2D urban dam-break flood modelling in Istanbul, Turkey

Science.gov (United States)

Ozdemir, Hasan; Neal, Jeffrey; Bates, Paul; Döker, Fatih

2014-05-01

Urban flood events are increasing in frequency and severity as a consequence of several factors such as reduced infiltration capacities due to continued watershed development, increased construction in flood prone areas due to population growth, the possible amplification of rainfall intensity due to climate change, sea level rise which threatens coastal development, and poorly engineered flood control infrastructure (Gallegos et al., 2009). These factors will contribute to increased urban flood risk in the future, and as a result improved modelling of urban flooding according to different causative factor has been identified as a research priority (Gallegos et al., 2009; Ozdemir et al. 2013). The flooding disaster caused by dam failures is always a threat against lives and properties especially in urban environments. Therefore, the prediction of dynamics of dam-break flows plays a vital role in the forecast and evaluation of flooding disasters, and is of long-standing interest for researchers. Flooding occurred on the Ayamama River (Istanbul-Turkey) due to high intensity rainfall and dam-breaching of Ata Pond in 9th September 2009. The settlements, industrial areas and transportation system on the floodplain of the Ayamama River were inundated. Therefore, 32 people were dead and millions of Euros economic loses were occurred. The aim of this study is 1 and 2-Dimensional flood modelling of the Ata Pond breaching using HEC-RAS and LISFLOOD-Roe models and comparison of the model results using the real flood extent. The HEC-RAS model solves the full 1-D Saint Venant equations for unsteady open channel flow whereas LISFLOOD-Roe is the 2-D shallow water model which calculates the flow according to the complete Saint Venant formulation (Villanueva and Wright, 2006; Neal et al., 2011). The model consists a shock capturing Godunov-type scheme based on the Roe Riemann solver (Roe, 1981). 3 m high resolution Digital Surface Model (DSM), natural characteristics of the pond

Advanced Reservoir Characterization and Evaluation of CO{sub 2} Gravity Drainage in the Naturally Fractured Spraberry Trend Area

Energy Technology Data Exchange (ETDEWEB)

Schechter, D.S.

1999-02-03

The overall goal of this project is to assess the economic feasibility of CO{sub 2} flooding the naturally fractured Spraberry Trend Area in West Texas. This objective is being accomplished by conducting research in four areas: (1) extensive characterization of the reservoirs, (2) experimental studies of crude oil/brine/rock (COBR) interactions in the reservoirs, (3) reservoir performance analysis, and, (4) experimental investigations on CO2 gravity drainage in Spraberry whole cores. This report provides results of the third year of the five-year project for each of the four areas including a status report of field activities leading up to injection of CO2.

Hurricane Harvey Riverine Flooding: Part 2: Integration of Heterogeneous Earth Observation Data for Comparative Analysis with High-Resolution Inundation Boundaries Reconstructed from Flood2D-GPU Model

Science.gov (United States)

Jackson, C.; Sava, E.; Cervone, G.

2017-12-01

Hurricane Harvey has been noted as the wettest cyclone on record for the US as well as the most destructive (so far) for the 2017 hurricane season. An entire year worth of rainfall occurred over the course of a few days. The city of Houston was greatly impacted as the storm lingered over the city for five days, causing a record-breaking 50+ inches of rain as well as severe damage from flooding. Flood model simulations were performed to reconstruct the event in order to better understand, assess, and predict flooding dynamics for the future. Additionally, number of remote sensing platforms, and on ground instruments that provide near real-time data have also been used for flood identification, monitoring, and damage assessment. Although both flood models and remote sensing techniques are able to identify inundated areas, rapid and accurate flood prediction at a high spatio-temporal resolution remains a challenge. Thus a methodological approach which fuses the two techniques can help to better validate what is being modeled and observed. Recent advancements in data fusion techniques of remote sensing with near real time heterogeneous datasets have allowed emergency responders to more efficiently extract increasingly precise and relevant knowledge from the available information. In this work the use of multiple sources of contributed data, coupled with remotely sensed and open source geospatial datasets is demonstrated to generate an understanding of potential damage assessment for the floods after Hurricane Harvey in Harris County, Texas. The feasibility of integrating multiple sources at different temporal and spatial resolutions into hydrodynamic models for flood inundation simulations is assessed. Furthermore the contributed datasets are compared against a reconstructed flood extent generated from the Flood2D-GPU model.

Vehicle emissions of greenhouse gases and related tracers from a tunnel study: : CO: CO2, N2O: CO2, CH4: CO2, O2: CO2 ratios, and the stable isotopes 13C and 18O in CO2 and CO

NARCIS (Netherlands)

Popa, Maria Elena; Vollmer, M. K.; Jordan, A.; Brand, W. A.; Pathirana, S. L.; Rothe, M.; Röckmann, T.

2014-01-01

Measurements of CO2, CO, N2O and CH4 mole fractions, O2/N2 ratios and the stable isotopes 13C and 18O in CO2 and CO have been performed in air samples from the Islisberg highway tunnel (Switzerland). The molar CO : CO2 ratios, with an average of (4.15 ± 0.34) ppb:ppm, are lower than reported in

CO2 and humidity removal system for extended Shuttle missions - Equilibrium testing and performance analysis

Science.gov (United States)

Davis, S. H.; Kissinger, L. D.

1976-01-01

In Shuttle orbiter cabins, lithium hydroxide (LiOH) canisters are currently planned to be used for CO2 adsorption and condensing heat exchangers for humidity control. In this paper a more effective CO2 and humidity removal method is proposed by replacing the LiOH component with HS-C adsorbent (a polyethylenimine coated acrylic ester), thus eliminating the low temperature constraints on the active thermal control system. Since the adsorption of CO2 and H2O are reversible, a double bed configuration operating cyclicly is planned to provide continuous atmospheric control. Apparatus and the experimental procedure to test the adsorption equilibrium are described and some of the indicative results, tabulated by computers, are presented with the help of exponential expressions and differential equations. By using a computer model of the Shuttle HS-C system, performance predictions are made.

Flooding in imagination vs flooding in vivo: A comparison with agoraphobics

NARCIS (Netherlands)

Emmelkamp, Paul M.G.; Wessels, Hemmy

In this investigation of agoraphobic patients, 3 different flooding procedures were compared: (1) prolonged exposure in vivo, (2) flooding in the imagination by a ‘live’ therapist and (3) a combination of flooding in the imagination and flooding in vivo. After an intermediate-test all clients were

Electrochemical deposition of carbon films on titanium in molten LiCl–KCl–K2CO3

International Nuclear Information System (INIS)

Song, Qiushi; Xu, Qian; Wang, Yang; Shang, Xujing; Li, Zaiyuan

2012-01-01

Electrodeposition of carbon films on the oxide-scale-coated titanium has been performed in a LiCl–KCl–K 2 CO 3 melt, which are characterized by scanning electron microscopy, Raman spectroscopy and X-ray diffraction analysis. The electrochemical process of carbon deposition is investigated by cyclic voltammetry on the graphite, titanium and oxide-scale-coated titanium electrodes. The particle-size-gradient carbon films over the oxide-scale-coated titanium can be achieved by electrodeposition under the controlled potentials for avoiding codeposition of lithium carbide. The deposited carbon films are comprised of micron-sized ‘quasi-spherical’ carbon particles with graphitized and amorphous phases. The cyclic voltammetry behavior on the graphite, titanium and oxide-scale-coated titanium electrodes shows that CO 3 2− ions are reduced most favorably on the graphite for the three electrodes. Lithium ions can discharge under the less negative potential on the electrode containing carbon compared with titanium electrode because of the formation of lithium carbide from the reaction between lithium and carbon. - Highlights: ► Carbon films are prepared on oxide-scale-coated titanium in a LiCl–KCl–K 2 CO 3 melt. ► The films comprise micron-size ‘quasi-spherical’ carbon particles. ► The films present particle-size-gradient. ► The particles contain graphitized and amorphous phases. ► The prepared carbon films are more electrochemically active than graphite.

Understanding the geomorphology of macrochannel systems for flood risk management in Queensland, Australia

Science.gov (United States)

Thompson, Chris; Croke, Jacky

2016-04-01

The year 2010-2011 was the wettest on record for the state of Queensland, Australia producing catastrophic floods. A tropical low pressure system in 2013 delivered further extreme flood events across South East Queensland (SEQ) which prompted state and local governments to conduct studies into flood magnitude and frequency in the region and catchment factors contributing to flood hazards. The floods in the region are strongly influenced by El Nino-Southern Oscillation (ENSO) phenomenon, but also modulated by the Interdecadal Pacific Oscillation (IPO) which leads to flood and drought dominated regimes and high hydrological variability. One geomorphic feature in particular exerted a significant control on the transmission speed, the magnitude of flood inundation and resultant landscape resilience. This feature was referred to as a 'macrochannel', a term used to describe a 'large-channel' which has bankfull recurrence intervals generally greater than 10 years. The macrochannels display non-linear downstream hydraulic geometry which leads to zones of flood expansion (when hydraulic geometry decreases) and zones of flood contraction (when hydraulic geometry increases). The pattern of contraction and expansion zones determines flood hazard zones. The floods caused significant wet flow bank mass failures that mobilised over 1,000,000 m3 of sediment in one subcatchment. Results suggest that the wetflow bank mass failures are a stage in a cyclical evolution process which maintains the macrochannel morphology, hence channel resilience to floods. Chronological investigations further show the macrochannels are laterally stable and identify periods of heightened flood activity over the past millennium and upper limits on flood magnitude. This paper elaborates on the results of the geomorphic investigations on Lockyer Creek in SEQ and how the results have alerted managers and policy makers to the different flood responses of these systems and how flood risk management plans can

Cyclic biogeochemical processes and nitrogen fate beneath a subtropical stormwater infiltration basin

Science.gov (United States)

O'Reilly, Andrew M.; Chang, Ni-Bin; Wanielista, Martin P.

2012-01-01

A stormwater infiltration basin in north–central Florida, USA, was monitored from 2007 through 2008 to identify subsurface biogeochemical processes, with emphasis on N cycling, under the highly variable hydrologic conditions common in humid, subtropical climates. Cyclic variations in biogeochemical processes generally coincided with wet and dry hydrologic conditions. Oxidizing conditions in the subsurface persisted for about one month or less at the beginning of wet periods with dissolved O2 and NO3- showing similar temporal patterns. Reducing conditions in the subsurface evolved during prolonged flooding of the basin. At about the same time O2 and NO3- reduction concluded, Mn, Fe and SO42- reduction began, with the onset of methanogenesis one month later. Reducing conditions persisted up to six months, continuing into subsequent dry periods until the next major oxidizing infiltration event. Evidence of denitrification in shallow groundwater at the site is supported by median NO3-–N less than 0.016 mg L-1, excess N2 up to 3 mg L-1 progressively enriched in δ15N during prolonged basin flooding, and isotopically heavy δ15N and δ18O of NO3- (up to 25‰ and 15‰, respectively). Isotopic enrichment of newly infiltrated stormwater suggests denitrification was partially completed within two days. Soil and water chemistry data suggest that a biogeochemically active zone exists in the upper 1.4 m of soil, where organic carbon was the likely electron donor supplied by organic matter in soil solids or dissolved in infiltrating stormwater. The cyclic nature of reducing conditions effectively controlled the N cycle, switching N fate beneath the basin from NO3- leaching to reduction in the shallow saturated zone. Results can inform design of functionalized soil amendments that could replace the native soil in a stormwater infiltration basin and mitigate potential NO3- leaching to groundwater by replicating the biogeochemical conditions under the observed basin.

Using Combined X-ray Computed Tomography and Acoustic Resonance to Understand Supercritical CO2 Behavior in Fractured Sandstone

Science.gov (United States)

Kneafsey, T. J.; Nakagawa, S.

2015-12-01

Distribution of supercritical (sc) CO2 has a large impact on its flow behavior as well as on the properties of seismic waves used for monitoring. Simultaneous imaging of scCO2 distribution in a rock core using X-ray computed tomography (CT) and measurements of seismic waves in the laboratory can help understand how the distribution evolves as scCO2 invades through rock, and the resulting seismic signatures. To this end, we performed a series of laboratory scCO2 core-flood experiments in intact and fractured anisotropic Carbon Tan sandstone samples. In these experiments, we monitored changes in the CO2 saturation distribution and sonic-frequency acoustic resonances (yielding both seismic velocity and attenuation) over the course of the floods. A short-core resonant bar test system (Split-Hopkinson Resonant Bar Apparatus) custom fit into a long X-ray transparent pressure vessel was used for the seismic measurements, and a modified General Electric medical CT scanner was used to acquire X-ray CT data from which scCO2 saturation distributions were determined. The focus of the experiments was on the impact of single fractures on the scCO2 distribution and the seismic properties. For this reason, we examined several cases including 1. intact, 2. a closely mated fracture along the core axis, 3. a sheared fracture along the core axis (both vertical and horizontal for examining the buoyancy effect), and 4. a sheared fracture perpendicular to the core axis. For the intact and closely mated fractured cores, Young's modulus declined with increasing CO2 saturation, and attenuation increased up to about 15% CO2 saturation after which attenuation declined. For cores having wide axial fractures, the Young's modulus was lower than for the intact and closely mated cases, however did not change much with CO2 pore saturation. Much lower CO2 pore saturations were achieved in these cases. Attenuation increased more rapidly however than for the intact sample. For the core

On the τ(2)-model in the chiral Potts model and cyclic representation of the quantum group Uq(sl2)

International Nuclear Information System (INIS)

Roan Shishyr

2009-01-01

We identify the precise relationship between the five-parameter τ (2) -family in the N-state chiral Potts model and XXZ chains with U q (sl 2 )-cyclic representation. By studying the Yang-Baxter relation of the six-vertex model, we discover a one-parameter family of L-operators in terms of the quantum group U q (sl 2 ). When N is odd, the N-state τ (2) -model can be regarded as the XXZ chain of U q (sl 2 ) cyclic representations with q N =1. The symmetry algebra of the τ (2) -model is described by the quantum affine algebra U q (sl 2 -hat) via the canonical representation. In general, for an arbitrary N, we show that the XXZ chain with a U q (sl 2 )-cyclic representation for q 2N = 1 is equivalent to two copies of the same N-state τ (2) -model. (fast track communication)

The aerial fertilization effect of CO sub 2 and its implications for global carbon cycling and maximum greenhouse warming

Energy Technology Data Exchange (ETDEWEB)

Idso, S B [US Water Conservation Laboratory, Phoenix, AZ (USA)

1991-07-01

The author observes that the CO{sub 2} sequestering ability of the world's plant life should increase with the rising CO{sub 2} content of the atmosphere. The enhanced cyclic variation of atmospheric CO{sub 2} in the Northern Hemisphere is seen to be a result of the CO{sub 2} fertilization effect. Trees are responsible for about two-thirds of global photosynthesis. It is calculated that a 300 ppm increase in atmospheric CO{sub 2} produces a 182 per cent increase in the mean productivity of the world's forests. Global warming yet to be faced will not be much more than that which has already occurred. The rising CO{sub 2} content of the atmosphere provides a strong impetus for forest expansion, and a solution to any problems its continued upward trend might produce by intensifying the major mechanisms for its removal. 22 refs., 1 fig.

Recent advances in flood forecasting and flood risk assessment

Directory of Open Access Journals (Sweden)

G. Arduino

2005-01-01

Full Text Available Recent large floods in Europe have led to increased interest in research and development of flood forecasting systems. Some of these events have been provoked by some of the wettest rainfall periods on record which has led to speculation that such extremes are attributable in some measure to anthropogenic global warming and represent the beginning of a period of higher flood frequency. Whilst current trends in extreme event statistics will be difficult to discern, conclusively, there has been a substantial increase in the frequency of high floods in the 20th century for basins greater than 2x105 km2. There is also increasing that anthropogenic forcing of climate change may lead to an increased probability of extreme precipitation and, hence, of flooding. There is, therefore, major emphasis on the improvement of operational flood forecasting systems in Europe, with significant European Community spending on research and development on prototype forecasting systems and flood risk management projects. This Special Issue synthesises the most relevant scientific and technological results presented at the International Conference on Flood Forecasting in Europe held in Rotterdam from 3-5 March 2003. During that meeting 150 scientists, forecasters and stakeholders from four continents assembled to present their work and current operational best practice and to discuss future directions of scientific and technological efforts in flood prediction and prevention. The papers presented at the conference fall into seven themes, as follows.

Evaluation of various modelling approaches in flood routing simulation and flood area mapping

Science.gov (United States)

Papaioannou, George; Loukas, Athanasios; Vasiliades, Lampros; Aronica, Giuseppe

2016-04-01

An essential process of flood hazard analysis and mapping is the floodplain modelling. The selection of the modelling approach, especially, in complex riverine topographies such as urban and suburban areas, and ungauged watersheds may affect the accuracy of the outcomes in terms of flood depths and flood inundation area. In this study, a sensitivity analysis implemented using several hydraulic-hydrodynamic modelling approaches (1D, 2D, 1D/2D) and the effect of modelling approach on flood modelling and flood mapping was investigated. The digital terrain model (DTMs) used in this study was generated from Terrestrial Laser Scanning (TLS) point cloud data. The modelling approaches included 1-dimensional hydraulic-hydrodynamic models (1D), 2-dimensional hydraulic-hydrodynamic models (2D) and the coupled 1D/2D. The 1D hydraulic-hydrodynamic models used were: HECRAS, MIKE11, LISFLOOD, XPSTORM. The 2D hydraulic-hydrodynamic models used were: MIKE21, MIKE21FM, HECRAS (2D), XPSTORM, LISFLOOD and FLO2d. The coupled 1D/2D models employed were: HECRAS(1D/2D), MIKE11/MIKE21(MIKE FLOOD platform), MIKE11/MIKE21 FM(MIKE FLOOD platform), XPSTORM(1D/2D). The validation process of flood extent achieved with the use of 2x2 contingency tables between simulated and observed flooded area for an extreme historical flash flood event. The skill score Critical Success Index was used in the validation process. The modelling approaches have also been evaluated for simulation time and requested computing power. The methodology has been implemented in a suburban ungauged watershed of Xerias river at Volos-Greece. The results of the analysis indicate the necessity of sensitivity analysis application with the use of different hydraulic-hydrodynamic modelling approaches especially for areas with complex terrain.

Effect of Molybdenum on the Corrosion Behavior of High-Entropy Alloys CoCrFeNi2 and CoCrFeNi2Mo0.25 under Sodium Chloride Aqueous Conditions

Directory of Open Access Journals (Sweden)

Alvaro A. Rodriguez

2018-01-01

Full Text Available The corrosion behavior of high-entropy alloys (HEAs CoCrFeNi2 and CoCrFeNi2Mo0.25 was investigated in 3.5 wt. percent sodium chloride (NaCl at 25°C by electrochemical methods. Their corrosion parameters were compared to those of HASTELLOY® C-276 (UNS N10276 and stainless steel 316L (UNS 31600 to assess the suitability of HEAs for potential industrial applications in NaCl simulating seawater type environments. The corrosion rates were calculated using corrosion current determined from electrochemical experiments for each of the alloys. In addition, potentiodynamic polarization measurements can indicate active, passive, and transpassive behavior of the metal as well as potential susceptibility to pitting corrosion. Cyclic voltammetry (CV can confirm the alloy susceptibility to pitting corrosion. Electrochemical impedance spectroscopy (EIS elucidates the corrosion mechanism under studied conditions. The results of the electrochemical experiments and scanning electron microscopy (SEM analyses of the corroded surfaces revealed general corrosion on alloy CoCrFeNi2Mo0.25 and HASTELLOY C-276 and pitting corrosion on alloy CoCrFeNi2 and stainless steel 316L.

Effects of salinity and flooding on seedlings of cabbage palm (Sabal palmetto).

Science.gov (United States)

Perry, L; Williams, K

1996-03-01

Sabal palmetto (Walt.) Lodd. ex Schultes (cabbage palm) dominates the coastal limit of many forests in North Florida and Georgia, United States. Changes in saltwater flooding due to sea level rise have been credicted with pushing the coastal limit of cabbage palms inland, eliminating regeneration before causing death of mature trees. Localized freshwater discharge along the coast causes different forest stands to experience tidal flooding with waters that differ in salinity. To elucidate the effect of such variation on regeneration failure under tidal flooding, we examined relative effects of flooding and salinity on the performance of cabbage palm seedlings. We examined the relationship between seedling establishment and degree of tidal inundation in the field, compared the ability of seedlings to withstand tidal flooding at two coastal sites that differed in tidal water salinity, and investigated the physiological responses of cabbage palm seedlings to salinity and flooding in a factorial greenhouse experiment. Seedling survival was inversely correlated with depth and frequency of tidal flooding. Survival of seedlings at a coastal site flooded by waters low in salinity [c. 3 parts per thousand (ppt)] was greater than that at a site flooded by waters higher in salinity (up to 23 ppt). Greenhouse experiments revealed that leaves of seedlings in pots flushed twice daily with salt solutions of 0 ppt and 8 ppt exhibited little difference in midmorning net CO 2 assimilation rates; those flushed with solutions of 15 ppt and 22 ppt, in contrast, had such low rates that they could not be detected. Net CO 2 assimilation rates also declined with increasing salinity for seedlings in pots that were continuously inundated. Continuous root zone inundation appeared to ameliorate effects of salinity on photosynthesis, presumably due to increased salt concentrations and possibly water deficits in periodically flushed pots. Such problems associated with periodic flushing by salt

Floods and Flash Flooding

Science.gov (United States)

Floods and flash flooding Now is the time to determine your area’s flood risk. If you are not sure whether you ... If you are in a floodplain, consider buying flood insurance. Do not drive around barricades. If your ...

Cyclic mononucleotides modulate potassium and calcium flux responses to H2O2 in Arabidopsis roots

KAUST Repository

Ordoñez, Natalia Maria

2014-02-13

Cyclic mononucleotides are messengers in plant stress responses. Here we show that hydrogen peroxide (H2O2) induces rapid net K+-efflux and Ca2+-influx in Arabidopsis roots. Pre-treatment with either 10 μM cAMP or cGMP for 1 or 24 h does significantly reduce net K+-leakage and Ca2+-influx, and in the case of the K+-fluxes, the cell permeant cyclic mononucleotides are more effective. We also examined the effect of 10 μM of the cell permeant 8-Br-cGMP on the Arabidopsis microsomal proteome and noted a specific increase in proteins with a role in stress responses and ion transport, suggesting that cGMP is sufficient to directly and/or indirectly induce complex adaptive changes to cellular stresses induced by H2O2. © 2014 Federation of European Biochemical Societies. Published by Elsevier B.V. All rights reserved.

Enhanced transfer of terrestrially derived carbon to the atmosphere in a flooding event

Science.gov (United States)

Bianchi, Thomas S.; Garcia-Tigreros, Fenix; Yvon-Lewis, Shari A.; Shields, Michael; Mills, Heath J.; Butman, David; Osburn, Christopher; Raymond, Peter A.; Shank, G. Christopher; DiMarco, Steven F.; Walker, Nan; Kiel Reese, Brandi; Mullins-Perry, Ruth; Quigg, Antonietta; Aiken, George R.; Grossman, Ethan L.

2013-01-01

Rising CO2 concentration in the atmosphere, global climate change, and the sustainability of the Earth's biosphere are great societal concerns for the 21st century. Global climate change has, in part, resulted in a higher frequency of flooding events, which allow for greater exchange between soil/plant litter and aquatic carbon pools. Here we demonstrate that the summer 2011 flood in the Mississippi River basin, caused by extreme precipitation events, resulted in a “flushing” of terrestrially derived dissolved organic carbon (TDOC) to the northern Gulf of Mexico. Data from the lower Atchafalaya and Mississippi rivers showed that the DOC flux to the northern Gulf of Mexico during this flood was significantly higher than in previous years. We also show that consumption of radiocarbon-modern TDOC by bacteria in floodwaters in the lower Atchafalaya River and along the adjacent shelf contributed to northern Gulf shelf waters changing from a net sink to a net source of CO2 to the atmosphere in June and August 2011. This work shows that enhanced flooding, which may or may not be caused by climate change, can result in rapid losses of stored carbon in soils to the atmosphere via processes in aquatic ecosystems.

Wettability impact on supercritical CO2 capillary trapping: Pore-scale visualization and quantification

Science.gov (United States)

Hu, Ran; Wan, Jiamin; Kim, Yongman; Tokunaga, Tetsu K.

2017-08-01

How the wettability of pore surfaces affects supercritical (sc) CO2 capillary trapping in geologic carbon sequestration (GCS) is not well understood, and available evidence appears inconsistent. Using a high-pressure micromodel-microscopy system with image analysis, we studied the impact of wettability on scCO2 capillary trapping during short-term brine flooding (80 s, 8-667 pore volumes). Experiments on brine displacing scCO2 were conducted at 8.5 MPa and 45°C in water-wet (static contact angle θ = 20° ± 8°) and intermediate-wet (θ = 94° ± 13°) homogeneous micromodels under four different flow rates (capillary number Ca ranging from 9 × 10-6 to 8 × 10-4) with a total of eight conditions (four replicates for each). Brine invasion processes were recorded and statistical analysis was performed for over 2000 images of scCO2 saturations, and scCO2 cluster characteristics. The trapped scCO2 saturation under intermediate-wet conditions is 15% higher than under water-wet conditions under the slowest flow rate (Ca ˜ 9 × 10-6). Based on the visualization and scCO2 cluster analysis, we show that the scCO2 trapping process in our micromodels is governed by bypass trapping that is enhanced by the larger contact angle. Smaller contact angles enhance cooperative pore filling and widen brine fingers (or channels), leading to smaller volumes of scCO2 being bypassed. Increased flow rates suppress this wettability effect.

Azole-Anion-Based Aprotic Ionic Liquids: Functional Solvents for Atmospheric CO2 Transformation into Various Heterocyclic Compounds.

Science.gov (United States)

Zhao, Yanfei; Wu, Yunyan; Yuan, Guangfeng; Hao, Leiduan; Gao, Xiang; Yang, Zhenzhen; Yu, Bo; Zhang, Hongye; Liu, Zhimin

2016-10-06

The chemical transformation of atmospheric CO 2 is of great significance yet still poses a great challenge. Herein, azole-anion-based aprotic ionic liquids (ILs) were synthesized by the deprotonation of weak proton donors (e.g., 2-methylimidazole, 4-methylimidazole, and 2,4-dimethylimidazole) with tetrabutylphosphonium hydroxide, [Bu 4 P][OH]. We found that these ILs, such as [Bu 4 P][2-MIm], could activate atmospheric CO 2 through the formation of carbamates. The resultant carbamate intermediates could further react with various types of substrate, including propargylic alcohols, 2-aminobenzonitriles, ortho-phenylenediamines, and 2-aminothiophenol, thereby producing α-alkylidene cyclic carbonates, quinazoline-2,4(1 H,3 H)-diones, benzimidazolones, and benzothiazoline, respectively, in moderate-to-good yields. Thus, we have achieved the transformation of CO 2 at atmospheric pressure, and we expect this method to open up new routes for the synthesis of various oxygen-containing heterocyclic compounds under metal-free conditions. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Applications of Poly(indole-6-carboxylic acid-co-2,2′-bithiophene Films in High-Contrast Electrochromic Devices

Directory of Open Access Journals (Sweden)

Chung-Wen Kuo

2018-03-01

Full Text Available Two homopolymers (poly(indole-6-carboxylic acid (PInc and poly(2,2′-bithiophene (PbT and a copolymer (poly(indole-6-carboxylic acid-co-2,2′-bithiophene (P(Inc-co-bT are electrodeposited on ITO electrode surfaces via electrochemical method. Electrochemical and electrochromic properties of PInc, PbT, and P(Inc-co-bT films were characterized using cyclic voltammetry and in situ UV-Vis spectroscopy. The anodic P(Inc-co-bT film prepared using Inc./bT = 1/1 feed molar ratio shows high optical contrast (30% at 890 nm and coloring efficiency (112 cm2 C−1 at 890 nm. P(Inc-co-bT film revealed light yellow, yellowish green, and bluish grey in the neutral, intermediate, and oxidation states, respectively. Electrochromic devices (ECDs were constructed using PInc, PbT, or P(Inc-co-bT film as anodic layer and PEDOT-PSS as cathodic layer. P(Inc-co-bT/PMMA-PC-ACN-LiClO4/PEDOT-PSS ECD showed high ∆T (31% at 650 nm, and PInc/PMMA-PC-ACN-LiClO4/PEDOT-PSS ECD displayed high coloration efficiency (416.7 cm2 C−1 at 650 nm. The optical memory investigations of PInc/PMMA-PC-ACN-LiClO4/PEDOT-PSS, PbT/PMMA-PC-ACN-LiClO4/PEDOT-PSS, and P(Inc-co-bT/PMMA-PC-ACN-LiClO4/PEDOT-PSS ECDs exhibited that ECDs had adequate optical memory in bleaching and coloring states.

The influence of cyclic structure on the radiolysis of hydrocarbons

International Nuclear Information System (INIS)

Foeldiak, G.; Cserep, Gy.; Horvath, Zs.; Wojnarovits, L.

1975-01-01

Aliphatic and cyclic C 3 -C 12 alkanes and alkenes have been irradiated in liquid phase by a 60 Co-γ-source with the nominal activity of 80 000 Ci. The dose rate was 1-2 Mrad/hr, the doses were between 0 and 10 Mrad. The following conclusions can be drawn from the experiments: 1., While no significant difference can be observed between radiolytic decomposition of n-hydrocarbon homologues, that of cyclic hydrocarbons is the function of the size of the ring. 2., Reactivity of cyclic hydrocarbons is influenced not only by their surplus enthalpy of formation (strain energy) but also by the individual components of this surplus enthalpy, e.g. bond deformation or repulsion between hydrogen atoms. 3., The overall yield of decomposition of higher than C 4 straightchain and cyclic alkanes activated by radiation and reacting via either C-C or C-H fission is approximately constant, with a G value of 6.5+-0.5. The structure of the molecules affects mainly the ratio of C-C and C-H bond rupture, i.e. these two processes are in competition. 4., Hydrogen yields from alkenes are affected mainly by the order and number of allylic C-H bonds, and by the possibility of the formation of allyl-type radicals. This latter is facilitated by ''free'' rotation in the case of open-chain hydrocarbons whereas it is hindered in the case of small and medium size cycles. (K.A.)

Valorisation du CO2 et d'huiles végétales pour la synthèse de monomères biosourcés

OpenAIRE

Alves , Margot

2016-01-01

Although it is a thermodynamically and kinetically stable molecule, carbon dioxide can beconverted into five- and six-membered cyclic carbonates by coupling with epoxides or oxetanes, respectively, using appropriate catalysts. Cyclic carbonates are used as green solvents, electrolytes for Liion batteries or intermediates for the synthesis of polymers. However, the catalytic performance must be further enhanced in particular for the coupling of CO2 with epoxidized vegetable oils or oxetanes. I...

The investigation of photo-induced chemiluminescence on Co2+-doped TiO2 nanoparticles and its analytical application.

Science.gov (United States)

Li, Guixin; Nan, Hongyan; Zheng, Xingwang

2009-07-01

A novel space- and time-resolved photo-induced chemiluminescence (PICL) analytical method was developed based on the photocatalysis of the Co2+-doped TiO2 nanoparticles. The PICL reaction procedure under the photocatalysis of Co2+-doped TiO2 nanoparticles was investigated using cyclic voltammetry and potentiometry. Meanwhile, the effect of the electrical double layer outside the Co2+-doped TiO2 nanoparticles on the PICL was investigated by contrasting with the Co2+-doped TiO2-SiO2 core-shell nanoparticles. Significantly, the CL intensity increased apparently and the time of the CL was prolonged in the presence of procaterol hydrochloride because the mechanism of the enhanced PICL reaction may be modified. The route of the PICL was changed due to the participation of the procaterol hydrochloride enriched at the surface of the Co2+-doped TiO2-SiO2 in the PICL reaction, which prolonged the time of the CL reaction and resulted in the long-term PICL. The analytical characteristics of the proposed in-situ PICL method were investigated using the procaterol hydrochloride as the model analyte. The investigation results showed that this new PICL analytical method offered higher sensitivity to the analysis of the procaterol hydrochloride and the PICL intensity was linear with the concentration of the procaterol hydrochloride in the range from ca. 2.0 x 10(-10) to 1.0 x 10(-8) g mL(-1).

Hierarchical Core/Shell NiCo2O4@NiCo2O4 Nanocactus Arrays with Dual-functionalities for High Performance Supercapacitors and Li-ion Batteries

Science.gov (United States)

Cheng, Jinbing; Lu, Yang; Qiu, Kangwen; Yan, Hailong; Xu, Jinyou; Han, Lei; Liu, Xianming; Luo, Jingshan; Kim, Jang-Kyo; Luo, Yongsong

2015-07-01

We report the synthesis of three dimensional (3D) NiCo2O4@NiCo2O4 nanocactus arrays grown directly on a Ni current collector using a facile solution method followed by electrodeposition. They possess a unique 3D hierarchical core-shell structure with large surface area and dual-functionalities that can serve as electrodes for both supercapacitors (SCs) and lithium-ion batteries (LIBs). As the SC electrode, they deliver a remarkable specific capacitance of 1264 F g-1 at a current density of 2 A g-1 and ~93.4% of capacitance retention after 5000 cycles at 2 A g-1. When used as the anode for LIBs, a high reversible capacity of 925 mA h g-1 is achieved at a rate of 120 mA g-1 with excellent cyclic stability and rate capability. The ameliorating features of the NiCo2O4 core/shell structure grown directly on highly conductive Ni foam, such as hierarchical mesopores, numerous hairy needles and a large surface area, are responsible for the fast electron/ion transfer and large active sites which commonly contribute to the excellent electrochemical performance of both the SC and LIB electrodes.

Validating predictions of evolving porosity and permeability in carbonate reservoir rocks exposed to CO2-brine

Science.gov (United States)

Smith, M. M.; Hao, Y.; Carroll, S.

2017-12-01

Improving our ability to better forecast the extent and impact of changes in porosity and permeability due to CO2-brine-carbonate reservoir interactions should lower uncertainty in long-term geologic CO2 storage capacity estimates. We have developed a continuum-scale reactive transport model that simulates spatial and temporal changes to porosity, permeability, mineralogy, and fluid composition within carbonate rocks exposed to CO2 and brine at storage reservoir conditions. The model relies on two primary parameters to simulate brine-CO2-carbonate mineral reaction: kinetic rate constant(s), kmineral, for carbonate dissolution; and an exponential parameter, n, relating porosity change to resulting permeability. Experimental data collected from fifteen core-flooding experiments conducted on samples from the Weyburn (Saskatchewan, Canada) and Arbuckle (Kansas, USA) carbonate reservoirs were used to calibrate the reactive-transport model and constrain the useful range of k and n values. Here we present the results of our current efforts to validate this model and the use of these parameter values, by comparing predictions of extent and location of dissolution and the evolution of fluid permeability against our results from new core-flood experiments conducted on samples from the Duperow Formation (Montana, USA). Agreement between model predictions and experimental data increase our confidence that these parameter ranges need not be considered site-specific but may be applied (within reason) at various locations and reservoirs. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

Quantifying the Effects of Spatial Uncertainty in Fracture Permeability on CO2 Leakage through Columbia River Basalt Flow Interiors

Science.gov (United States)

Gierzynski, A.; Pollyea, R.

2016-12-01

Recent studies suggest that continental flood basalts may be suitable for geologic carbon sequestration, due to fluid-rock reactions that mineralize injected CO2 on relatively short time-scales. Flood basalts also possess a morphological structure conducive to injection, with alternating high-permeability (flow margin) and low-permeability (flow interior) layers. However, little information exists on the behavior of CO2 migration within field-scale fracture networks, particularly within flow interiors and at conditions near the critical point for CO2. In this study, numerical simulation is used to investigate the influence of fracture permeability uncertainty during gravity-driven CO2 migration within a jointed basalt flow interior as CO2 undergoes phase change from supercritical fluid to a subcritical phase. The model domain comprises a 2D fracture network mapped with terrestrial LiDAR scans of Columbia River Basalt acquired near Starbuck, WA. The model domain is 5 m × 5 m with bimodal heterogeneity (fracture and matrix), and initial conditions corresponding to a hydrostatic pressure gradient between 750 and 755 m depth. Under these conditions, the critical point for CO2 occurs 1.5 m above the bottom of the domain. For this model scenario, CO2 enters the base of the fracture network at 0.5 MPa overpressure, and matrix permeability is assumed constant. Fracture permeability follows a lognormal distribution on the basis of fracture aperture values from literature. In order to account for spatial uncertainty, the lognormal fracture permeability distribution is randomly located in the model domain and CO2 migration is simulated within the same fracture network for 50 equally probable realizations. Model results suggest that fracture connectivity, which is independent of permeability distribution, governs the path taken by buoyant CO2 as it rises through the flow interior; however, the permeability distribution strongly governs the CO2 flux magnitude. In particular

Pump Hydro Energy Storage systems (PHES) in groundwater flooded quarries

Science.gov (United States)

Poulain, Angélique; de Dreuzy, Jean-Raynald; Goderniaux, Pascal

2018-04-01

Pump storage hydroelectricity is an efficient way to temporarily store energy. This technique requires to store temporarily a large volume of water in an upper reservoir, and to release it through turbines to the lower reservoir, to produce electricity. Recently, the idea of using old flooded quarries as a lower reservoir has been evoked. However, these flooded quarries are generally connected to unconfined aquifers. Consequently, pumping or injecting large volumes of water, within short time intervals, will have an impact on the adjacent aquifers. Conversely, water exchanges between the quarry and the aquifer may also influence the water level fluctuations in the lower reservoir. Using numerical modelling, this study investigates the interactions between generic flooded open pit quarries and adjacent unconfined aquifers, during various pump-storage cyclic stresses. The propagation of sinusoidal stresses in the adjacent porous media and the amplitude of water level fluctuations in the quarry are studied. Homogeneous rock media and the presence of fractures in the vicinity of the quarry are considered. Results show that hydrological quarry - rock interactions must be considered with caution, when implementing pump - storage systems. For rock media characterized by high hydraulic conductivity and porosity values, water volumes exchanges during cycles may affect significantly the amplitude of the water level fluctuations in the quarry, and as a consequence, the instantaneous electricity production. Regarding the impact of the pump - storage cyclic stresses on the surrounding environment, the distance of influence is potentially high under specific conditions, and is enhanced with the occurrence of rock heterogeneities, such as fractures. The impact around the quarry used as a lower reservoir thus appears as an important constraining factor regarding the feasibility of pump - storage systems, to be assessed carefully if groundwater level fluctuations around the quarry

Homoleptic diphosphacyclobutadiene complexes [M(η(4)-P2C2R2)2]x- (M = Fe, Co; x = 0, 1).

Science.gov (United States)

Wolf, Robert; Ehlers, Andreas W; Khusniyarov, Marat M; Hartl, František; de Bruin, Bas; Long, Gary J; Grandjean, Fernande; Schappacher, Falko M; Pöttgen, Rainer; Slootweg, J Chris; Lutz, Martin; Spek, Anthony L; Lammertsma, Koop

2010-12-27

The preparation and comprehensive characterization of a series of homoleptic sandwich complexes containing diphosphacyclobutadiene ligands are reported. Compounds [K([18]crown-6)(thf)(2)][Fe(η(4)-P(2)C(2)tBu(2))(2)] (K1), [K([18]crown-6)(thf)(2)][Co(η(4)-P(2)C(2)tBu(2))(2)] (K2), and [K([18]crown-6)(thf)(2)][Co(η(4)-P(2)C(2)Ad(2))(2)] (K3, Ad = adamantyl) were obtained from reactions of [K([18]crown-6)(thf)(2)][M(η(4)-C(14)H(10))(2)] (M = Fe, Co) with tBuC[triple bond]P (1, 2), or with AdC[triple bond]P (3). Neutral sandwiches [M(η(4)-P(2)C(2)tBu(2))(2)] (4: M = Fe 5: M = Co) were obtained by oxidizing 1 and 2 with [Cp(2)Fe]PF(6). Cyclic voltammetry and spectro-electrochemistry indicate that the two [M(η(4)-P(2)C(2)tBu(2))(2)](-)/[M(η(4)-P(2)C(2)tBu(2))(2)] moieties can be reversibly interconverted by one electron oxidation and reduction, respectively. Complexes 1-5 were characterized by multinuclear NMR, EPR (1 and 5), UV/Vis, and Mössbauer spectroscopies (1 and 4), mass spectrometry (4 and 5), and microanalysis (1-3). The molecular structures of 1-5 were determined by using X-ray crystallography. Essentially D(2d)-symmetric structures were found for all five complexes, which show the two 1,3-diphosphacyclobutadiene rings in a staggered orientation. Density functional theory calculations revealed the importance of covalent metal-ligand π bonding in 1-5. Possible oxidation state assignments for the metal ions are discussed.

Detection of Cyclic Dinucleotides by STING.

Science.gov (United States)

Du, Xiao-Xia; Su, Xiao-Dong

2017-01-01

STING (stimulator of interferon genes) is an essential signaling adaptor protein mediating cytosolic DNA-induced innate immunity for both microbial invasion and self-DNA leakage. STING is also a direct receptor for cytosolic cyclic dinucleotides (CDNs), including the microbial secondary messengers c-di-GMP (3',3'-cyclic di-GMP), 3',3'cGAMP (3',3'-cyclic GMP-AMP), and mammalian endogenous 2',3'cGAMP (2',3'-cyclic GMP-AMP) synthesized by cGAS (cyclic GMP-AMP synthase). Upon CDN binding, STING undergoes a conformational change to enable signal transduction by phosphorylation and finally to active IRF3 (Interferon regulatory factor 3) for type I interferon production. Here, we describe some experimental procedures such as Isothermal Titration Calorimetry and luciferase reporter assays to study the CDNs binding and activity by STING proteins.

SO{sub 2} Retention by CaO-Based Sorbent Spent in CO{sub 2} Looping Cycles

Energy Technology Data Exchange (ETDEWEB)

Manovic, V.; Anthony, E.J.; Loncarevic, D.

2009-07-15

CaO-based looping cycles are promising processes for CO{sub 2} Capture from both syngas and flue gas. The technology is based on cyclical carbonation of CaO and regeneration of CaCO{sub 3} in a dual fluidized-bed reactor to produce a pure CO{sub 2} stream suitable for sequestration. Use of spent sorbent from CO{sub 2} looping cycles for SO{sub 2} capture is investigated. Three limestones were investigated: Kelly Rock (Canada), La Blanca (Spain), and Katowice (Poland, Upper Silesia). Carbonation/calcination cycles were performed in a tube furnace with both the original limestones and samples thermally pretreated for different times (i.e., sintered). The spent sorbent samples were sulfated in a thermogravimetric analyzer (TGA). The changes in the resulting sorbent pore structure were then investigated using mercury porosimetry. It has been shown that the sulfation rates of both thermally pretreated and spent sorbent samples are lower in comparison with those of the original samples. However, final conversions of both spent and pretreated sorbents after longer sulfation time were comparable or higher than those observed for the original sorbents under comparable conditions. Maximum sulfation levels strongly depend on sorbent porosity and pore surface area. The results showed that spent sorbent samples from CO{sub 2} looping cycles can be used as sorbents for SO{sub 2} retention in cases where significant porosity loss does not occur during CO{sub 2} reaction cycles. In the case of spent Kelly Rock and Katowice samples, sorbent particles are practically uniformly sulfated, achieving final conversions that are determined by the total pore volume available for the bulky CaSO{sub 4} product.

Advanced Reservoir Characterization and Evaluation of CO2 Gravity Drainage in the Naturally Fractured Spraberry Trend Area, Class III

Energy Technology Data Exchange (ETDEWEB)

Knight, Bill; Schechter, David S.

2002-07-26

The goal of this project was to assess the economic feasibility of CO2 flooding the naturally fractured Spraberry Trend Area in west Texas. This objective was accomplished through research in four areas: (1) extensive characterization of the reservoirs, (2) experimental studies of crude oil/brine/rock (COBR) interactions in the reservoirs, (3) reservoir performance analysis, and (4) experimental investigations on CO2 gravity drainage in Spraberry whole cores. This provides results of the final year of the six-year project for each of the four areas.

Adsorption of CO2 from flue gas streams by a highly efficient and stable aminosilica adsorbent.

Science.gov (United States)

Liu, Shou-Heng; Lin, Yuan-Chung; Chien, Yi-Chi; Hyu, Han-Ren

2011-02-01

Three ordered mesoporous silicas (OMSs) with different pore sizes and pore architectures were prepared and modified with amine functional groups by a postgrafting method. The carbon dioxide (CO2) adsorption on these amine-modified OMSs was measured by using microbalances at 348 K, and their adsorption capacities were found to be 0.2-1.4 mmol g(-1) under ambient pressure using dry 15% CO2. It was found experimentally that the CO2 adsorption capacity and adsorption rate were attributed to the density of amine groups and pore volume, respectively. A simple method is described for the production of densely anchored amine groups on a solid adsorbent invoking direct incorporation of tetraethylenepentamine onto the as-synthesized OMSs. Unlike conventional amine-modified OMSs, which typically show CO2 adsorption capacity less than 2 mmol g(-1), such organic template occluded amine-OMS composites possessed remarkably high CO2 uptake of approximately 4.6 mmol g(-1) at 348 K and 1 atm for a dry 15% CO2/nitrogen feed mixture. The enhancement of 8% in CO2 adsorption capacity was also observed in the presence of 10.6% water vapor. Durability tests done by cyclic adsorption-desorption revealed that these adsorbents also possess excellent stability.

Effects of soil flooding on photosynthesis and growth of Zea mays L ...

African Journals Online (AJOL)

user

2012-04-12

Apr 12, 2012 ... most important responses of plants to soil flooding which could be caused by ... by monitoring stomata morphometric, intercellular CO2 (Ci) and stomata ..... absorb water and nutrients, then decrease root growth rate and dry ...

NMR and magnetic studies of mechanically alloyed Co sub 7 sub 5 Ti sub 2 sub 5

CERN Document Server

Hiraoka, K; Tomiyoshi, S

2003-01-01

We have measured zero field sup 5 sup 9 Co NMR, X-ray diffraction (XRD) and magnetization in ferromagnetic mechanically alloyed Co sub 7 sub 5 Ti sub 2 sub 5 powder as a function of milling time at 4.2 K. The XRD patterns showed that the sample is primarily in an amorphous phase after a short milling time of 10 h, and no clear amorphous-crystalline phase transformation is detected with further milling. The NMR results revealed that successive phase transformations occur with milling, and the amorphous phase consists of small clusters of such ferromagnetic phases as fcc-Co sub 3 Ti, hexagonal-Co sub 2 Ti, bcc-Co sub 3 Ti, fcc-Co and fcc-Co-Ti solid solution depending on the milling time. The bcc-Co sub 3 Ti phase, being metastable, is a disordered one in contrast to the ordered fcc-Co sub 3 Ti phase and has a Co magnetic moment larger than that of fcc-Co sub 3 Ti. We suggest that the precipitation of Co plays an important role in the cyclic phase transformation, which was previously reported. (author)

Counting surface-kernel epimorphisms from a co-compact Fuchsian group to a cyclic group with motivations from string theory and QFT

Directory of Open Access Journals (Sweden)

Khodakhast Bibak

2016-09-01

Full Text Available Graphs embedded into surfaces have many important applications, in particular, in combinatorics, geometry, and physics. For example, ribbon graphs and their counting is of great interest in string theory and quantum field theory (QFT. Recently, Koch et al. (2013 [12] gave a refined formula for counting ribbon graphs and discussed its applications to several physics problems. An important factor in this formula is the number of surface-kernel epimorphisms from a co-compact Fuchsian group to a cyclic group. The aim of this paper is to give an explicit and practical formula for the number of such epimorphisms. As a consequence, we obtain an ‘equivalent’ form of Harvey's famous theorem on the cyclic groups of automorphisms of compact Riemann surfaces. Our main tool is an explicit formula for the number of solutions of restricted linear congruence recently proved by Bibak et al. using properties of Ramanujan sums and of the finite Fourier transform of arithmetic functions.

Counting surface-kernel epimorphisms from a co-compact Fuchsian group to a cyclic group with motivations from string theory and QFT

Energy Technology Data Exchange (ETDEWEB)

Bibak, Khodakhast, E-mail: kbibak@uvic.ca; Kapron, Bruce M., E-mail: bmkapron@uvic.ca; Srinivasan, Venkatesh, E-mail: srinivas@uvic.ca

2016-09-15

Graphs embedded into surfaces have many important applications, in particular, in combinatorics, geometry, and physics. For example, ribbon graphs and their counting is of great interest in string theory and quantum field theory (QFT). Recently, Koch et al. (2013) gave a refined formula for counting ribbon graphs and discussed its applications to several physics problems. An important factor in this formula is the number of surface-kernel epimorphisms from a co-compact Fuchsian group to a cyclic group. The aim of this paper is to give an explicit and practical formula for the number of such epimorphisms. As a consequence, we obtain an ‘equivalent’ form of Harvey's famous theorem on the cyclic groups of automorphisms of compact Riemann surfaces. Our main tool is an explicit formula for the number of solutions of restricted linear congruence recently proved by Bibak et al. using properties of Ramanujan sums and of the finite Fourier transform of arithmetic functions.

Performance evaluation of symmetric supercapacitor based on cobalt hydroxide [Co(OH)2] thin film electrodes

International Nuclear Information System (INIS)

Jagadale, A.D.; Kumbhar, V.S.; Dhawale, D.S.; Lokhande, C.D.

2013-01-01

In the present investigation, we have successfully assembled symmetric supercapacitor device based on cobalt hydroxide [Co(OH) 2 ] thin film electrodes using 1 M KOH as an electrolyte. Initially, potentiodynamic electrodeposition method is employed for the preparation of Co(OH) 2 thin films onto stainless steel substrate. These films are characterized for structural and morphological elucidations using X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The XRD reveals formation of β-Co(OH) 2 material with hexagonal crystal structure. The SEM images show formation of nanoflakes like microstructure with average flake width 100 nm. Electrochemical characterizations of Co(OH) 2 based symmetric supercapacitor cell are carried out using cyclic voltammetry, charge–discharge and electrochemical impedance spectroscopy (EIS) techniques. In the performance evaluation the maximum values of specific capacitance, specific energy and specific power are encountered as 44 F g −1 , 3.96 Wh kg −1 and 42 kW kg −1 . The value of equivalent series resistance (ESR) is estimated as 2.3 Ω using EIS

An order-by-disorder process in the cyclic phase of spin-2 condensate with a weak magnetic field

International Nuclear Information System (INIS)

Zheng, Gong-Ping; Xu, Lei-Kuan; Qin, Shuai-Feng; Jian, Wen-Tian; Liang, J.-Q.

2013-01-01

We present in this paper a model study on the “order-by-disorder” process in the cyclic phase of spin-2 condensate, which forms a family of incommensurable, spiral degenerate ground states. On the basis of the ordering mechanism of entropic splitting, it is demonstrated that the energy corrections resulting from quantum fluctuations of disorder lift the accidental degeneracy of the cyclic configurations and thus lead to an eventual spiral order called the cyclic order. The order-by-disorder phenomenon is then realized even if the magnetic field exists. Finally, we show that our theoretic observations can be verified experimentally by direct detection of the cyclic order in the 87 Rb condensate of a spin-2 manifold with a weak magnetic field. -- Highlights: •A model for the order-by-disorder process in the cyclic phase of spin-2 condensate is presented. •The second-order quantum fluctuations of the mean-field states are studied. •The energy corrections lift the accidental degeneracy of the cyclic configurations. •The order-by-disorder phenomenon is realized even if a magnetic field exists. •The theoretic observations can be verified experimentally for 87 Rb condensate

Cobalt hydroxide film on Pt as co-catalyst for oxidation of polyhydric alcohols in alkaline medium

International Nuclear Information System (INIS)

Das, Debasmita; Das, Kaushik

2010-01-01

Electrochemical behavior of chemically prepared Co(OH) 2 film on Pt has been studied in alkaline medium using cyclic voltammetry and chronoamperometry. Amount of Co(OH) 2 deposited increases linearly with the number of times of deposition. The deposit is of fibrous structure, as shown by scanning electron microphotograph. There is evidence of Co II /Co III and Co III /Co IV redox transitions during the cyclic potential scan. The former oxidation proceeds under diffusion control. The Co(OH) 2 deposit acts as an efficient co-catalyst for anodic oxidation of ethanediol, propanediol and glycerol on Pt in alkaline medium. This is demonstrated by appreciable enhancement of the alcohol oxidation currents upon deposition of Co(OH) 2 on Pt. Among the alcohols studied, the highest oxidation currents are obtained for ethanediol, both on Co(OH) 2 /Pt and bare Pt. Co(OH) 2 alone also acts as a redox mediator for alcohol oxidation at more positive potentials.

Cyclic mononucleotides modulate potassium and calcium flux responses to H2O2 in Arabidopsis roots

KAUST Repository

Ordoñ ez, Natalia Maria; Marondedze, Claudius; Thomas, Ludivine; Pasqualini, Stefania; Shabala, Lana; Shabala, Sergey; Gehring, Christoph A

2014-01-01

Cyclic mononucleotides are messengers in plant stress responses. Here we show that hydrogen peroxide (H2O2) induces rapid net K+-efflux and Ca2+-influx in Arabidopsis roots. Pre-treatment with either 10 μM cAMP or cGMP for 1 or 24 h does

Influence of the substrate texture on the structural and electrochemical properties of sputtered LiCoO2 thin films

International Nuclear Information System (INIS)

Jung, Ki-Taek; Cho, Gyu-Bong; Kim, Ki-Won; Nam, Tae-Hyun; Jeong, Hyo-Min; Huh, Sun-Chul; Chung, Han-Shik; Noh, Jung-Pil

2013-01-01

LiCoO 2 thin films were fabricated on textured and annealed STS304 substrates by direct current magnetron sputtering method. The effects of the substrate texture on the structural and electrochemical properties of the LiCoO 2 thin film deposited on both the substrates have been investigated. The crystal structures and surface morphologies of the deposited films were analyzed by X-ray diffractometry (XRD), Raman spectroscopy, and field emission scanning electron microscopy (FE-SEM). Based on the XRD analysis, the LiCoO 2 thin film deposited on the textured substrate was found to exhibit (003) preferred orientation, while the film deposited on annealed substrate exhibited (104) preferred orientation. In addition, SEM analysis revealed that the film deposited on the textured substrate showed a smooth morphology. On the other hand, the film deposited on the annealed substrate exhibited a very rough surface morphology, which resulted in a higher surface area. Consequently, the initial discharge capacity of the film deposited on the annealed substrate was higher than that of the film deposited on the textured substrate. The film deposited on the textured substrate exhibited a good cyclic performance compared to the film deposited on the annealed substrate. - Highlights: • The sputtered LiCoO 2 thin films were influenced by the substrate texture. • The film deposited on the annealed substrate exhibited (104) preferred orientation. • The film deposited on the textured substrate exhibited a good cyclic performance

Solid amine sorbents for CO2 capture by chemical adsorption: A review

Directory of Open Access Journals (Sweden)

Elif Erdal Ünveren

2017-03-01

Full Text Available Amines are well-known for their reversible reactions with CO2, which make them ideal for CO2 capture from several gas streams, including flue gas. In this respect, selective CO2 absorption by aqueous alkanolamines is the most mature technology but the process is energy intensive and has also corrosion problems. Both disadvantages can be diminished to a certain extent by chemical adsorption of CO2 selectively. The most important element of the chemical adsorption of CO2 involves the design and development of a suitable adsorbent which consist of a porous support onto which an amine is attached or immobilized. Such an adsorbent is often called as solid amine sorbent. This review covers solid amine-based studies which are developed and published in recent years. First, the review examines several different types of porous support materials, namely, three mesoporous silica (MCM-41, SBA-15 and KIT-6 and two polymeric supports (PMMA and PS for CO2 adsorption. Emphasis is given to the synthesis, modifications and characterizations -such as BET and PXRD data-of them. Amination of these supports to obtain a solid amine sorbent through impregnation or grafting is reviewed comparatively. Focus is given to the adsorption mechanisms, material characteristics, and synthesis methods which are discussed in detail. Significant amount of original data are also presented which makes this review unique. Finally, relevant CO2 adsorption (or equilibrium capacity data, and cyclic adsorption/desorption performance and stability of important classes of solid amine sorbents are critically reviewed. These include severa PEI or TEPA impregnated adsorbents and APTES-grafted systems.

The 2-3 November 2015 flood of the Sió River (NE Iberian Peninsula): a flash flood that turns into a mudflow downstream

Science.gov (United States)

Carles Balasch Solanes, Josep; Lluís Ruiz-Bellet, Josep; Rodríguez, Rafael; Tuset, Jordi; Castelltort, Xavier; Barriendos, Mariano; Pino, David; Mazón, Jordi

2016-04-01

Historical and recent evidence shows that many floods in the interior of Catalonia (NE Iberian Peninsula) usually have such a great sediment load that can even alter the hydraulic behaviour of the flow. This is especially true in catchments with a great proportion of agricultural soils, which are the main source of sediment. The night of 2-3 November 2015 torrential rains fell on the headwaters of the Sió River catchment (508 km2); the subsequent flood caused four deaths and many damages along the stream. The hydrological, hydraulic and sedimentary characteristics of this recent flood have been analysed in order to gain a better insight on the characteristics of the major historical floods in the same catchment. The rainfall height on the headwaters was between 139 and 146 mm in ten hours, with a maximum intensity of about 50 mm·h-1. In the rest of the catchment it rained much less (22-71 mm). The agricultural soils in the headwaters show evidence of intense erosion by laminar and concentrated Hortonian overland flow in their superficial layer (Ap1; 10 cm), which uncovered the more compact underlying layer (Ap2). The peak flow in the headwaters (Oluges) was 90 m3·s-1 (that is, a specific peak flow near 1 m3·s-1·km-2) and it diminished downstream: 40 m3·s-1 in the centre of the catchment (Oluges + 27 km) and 15 m3·s-1 in the outlet (Oluges + 54 km). The suspended sediment load was 10-15% in volume in the headwaters and, judging from recorded images and eyewitnesses, it increased as the flow moved downstream, turning the flash flood into a mudflow. This concentration gain was most probably caused by the flood wave's water loss due to the dryness of the riverbed and translated in an increased viscosity that ultimately altered the hydraulic behaviour of the flow, slowing it down. This process of water loss has been observed in flash floods in dry riverbeds in arid and semiarid areas such as Negev (Israel) and Atacama (Chile). Historical floods in neighbouring

Hydro-geophysical responses to the injection of CO2 in core plugs of Berea sandstone

Science.gov (United States)

Song, I.; Park, K. G.

2017-12-01

We have built a laboratory-scale core flooding system to measure the relative permeability of a core sample and the acoustic response to the CO2 saturation degree at in situ condition of pressure and temperature down to a few kilometer depths. The system consisted of an acoustic velocity core holder (AVC model from the Core Laboratories) between upstream where CO2 and H2O were injected separately and downstream where the mixed fluids came out of a core sample. Core samples with 4 cm in diameter and 5 cm in length of Berea sandstone were in turn placed in the core holder for confining and axial pressures. The flooding operations of the multiphase fluids were conducted through the sample at 40ºC in temperature and 8 MPa in backpressure. CO2 and H2O in the physical condition were injected separately into a sample at constant rate with various ratios. The two phases were mixed during flowing through the sample. The mixed fluids out of the sample were separated again by their different densities in a chamber equipped with a level gauge of the interface. From the level change of the water in the separator, we measured the volume of water coming out of the sample for each test with a constant ratio of the injection rates. Then it was possible to calculate the saturation degree of CO2 from the difference between input volume and output volume of water. The differential pressure between upstream and downstream was directly measured to calculate the relative permeability as a function of the CO2 saturation degree. We also conducted ultrasonic measurements using piezoelectric sensors on the end plugs. An electric pulse was given to a sensor on one end of sample, and then ultrasonic waves were recorded from the other end. The various ratios of injection rate of CO2 and H2O into Berea sandstone yielded a range of 0.1-0.7 in CO2 saturation degree. The relative permeability was obtained at the condition of steady-state flow for given stages from the velocity of each phase and

INVESTIGATION OF EFFICIENCY IMPROVEMENTS DURING CO2 INJECTION IN HYDRAULICALLY AND NATURALLY FRACTURED RESERVOIRS

Energy Technology Data Exchange (ETDEWEB)

David S. Schechter

2005-04-27

This report describes the work performed during the fourth year of the project, ''Investigating of Efficiency Improvements during CO{sub 2} Injection in Hydraulically and Naturally Fractured Reservoirs.'' The objective of this project is to perform unique laboratory experiments with artificially fractured cores (AFCs) and X-ray CT scanner to examine the physical mechanisms of bypassing in hydraulically fractured reservoirs (HFR) and naturally fractured reservoirs (NFR) that eventually result in more efficient CO{sub 2} flooding in heterogeneous or fracture-dominated reservoirs. In Chapter 1, we worked with DOE-RMOTC to investigate fracture properties in the Tensleep Formation at Teapot Dome Naval Reserve as part of their CO{sub 2} sequestration project. In Chapter 2, we continue our investigation to determine the primary oil recovery mechanism in a short vertically fractured core. Finally in Chapter 3, we report our numerical modeling efforts to develop compositional simulator with irregular grid blocks.

SUBTASK 2.19 – OPERATIONAL FLEXIBILITY OF CO2 TRANSPORT AND STORAGE

Energy Technology Data Exchange (ETDEWEB)

Jensen, Melanie; Schlasner, Steven; Sorensen, James; Hamling, John

2014-12-31

experts represented a range of disciplines and hailed from North America and Europe. Major findings of the study are that compression and transport of CO2 for enhanced oil recovery (EOR) purposes in the United States has shown that impurities are not likely to cause transport problems if CO2 stream composition standards are maintained and pressures are kept at 10.3 MPa or higher. Cyclic, or otherwise intermittent, CO2 supplies historically have not impacted in-field distribution pipeline networks, wellbore integrity, or reservoir conditions. The U.S. EOR industry has demonstrated that it is possible to adapt to variability and intermittency in CO2 supply through flexible operation of the pipeline and geologic storage facility. This CO2 transport and injection experience represents knowledge that can be applied in future CCS projects. A number of gaps in knowledge were identified that may benefit from future research and development, further enhancing the possibility for widespread application of CCS. This project was funded through the Energy & Environmental Research Center–U.S. Department of Energy Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding was provided by the IEA Greenhouse Gas R&D Programme.

Effect of Climate Extremes, Seasonal Change, and Agronomic Practices on Measured Evapotranspiration and CO2 Exchange in Sacramento-San Joaquin River Delta Alfalfa Fields

Science.gov (United States)

Clay, J.; Kent, E. R.; Leinfelder-Miles, M.; Paw U, K. T.; Little, C.; Lambert, J. J.

2017-12-01

Evapotranspiration and CO2 exchange was measured in five alfalfa fields in the Sacramento-San Joaquin River Delta region from 2016 to 2017 using eddy covariance and surface renewal methods. Seasonal changes of evapotranspiration and CO2 fluxes were compared between 2016, a drought year, and 2017, a high rainfall year. Additionally, changes in evapotranspiration and CO2 flux were investigated across various agronomic considerations, such as irrigation methods (border-check flood and sub-surface), stand life, and herbicide programs. Components of the energy balance, including net radiation, latent heat, ground heat flux, and sensible heat, were evaluated considering correlations to wind speed measured by three sonic anemometers, irrigation frequency, and crop cutting cycle. Comparisons between two different types of radiometers were also carried out. Under drought conditions, we observed higher amounts of evapotranspiration in a field having a stand life of less than two years of age compared to older stands, and in a sub-surface irrigated field compared to flood irrigated fields.

Effect of Urban Green Spaces and Flooded Area Type on Flooding Probability

Directory of Open Access Journals (Sweden)

Hyomin Kim

2016-01-01

Full Text Available Countermeasures to urban flooding should consider long-term perspectives, because climate change impacts are unpredictable and complex. Urban green spaces have emerged as a potential option to reduce urban flood risks, and their effectiveness has been highlighted in notable urban water management studies. In this study, flooded areas in Seoul, Korea, were divided into four flooded area types by cluster analysis based on topographic and physical characteristics and verified using discriminant analysis. After division by flooded area type, logistic regression analysis was performed to determine how the flooding probability changes with variations in green space area. Type 1 included regions where flooding occurred in a drainage basin that had a flood risk management infrastructure (FRMI. In Type 2, the slope was steep; the TWI (Topographic Wetness Index was relatively low; and soil drainage was favorable. Type 3 represented the gentlest sloping areas, and these were associated with the highest TWI values. In addition, these areas had the worst soil drainage. Type 4 had moderate slopes, imperfect soil drainage and lower than average TWI values. We found that green spaces exerted a considerable influence on urban flooding probabilities in Seoul, and flooding probabilities could be reduced by over 50% depending on the green space area and the locations where green spaces were introduced. Increasing the area of green spaces was the most effective method of decreasing flooding probability in Type 3 areas. In Type 2 areas, the maximum hourly precipitation affected the flooding probability significantly, and the flooding probability in these areas was high despite the extensive green space area. These findings can contribute towards establishing guidelines for urban spatial planning to respond to urban flooding.

Cyclic AMP is a key regulator of M1 to M2a phenotypic conversion of microglia in the presence of Th2 cytokines.

Science.gov (United States)

Ghosh, Mousumi; Xu, Yong; Pearse, Damien D

2016-01-13

Microglia and macrophages play a central role in neuroinflammation. Pro-inflammatory cytokines trigger their conversion to a classically activated (M1) phenotype, sustaining inflammation and producing a cytotoxic environment. Conversely, anti-inflammatory cytokines polarize the cells towards an alternatively activated (M2), tissue reparative phenotype. Elucidation of the signal transduction pathways involved in M1 to M2 phenotypic conversion may provide insight into how the innate immune response can be harnessed during distinct phases of disease or injury to mediate neuroprotection and neurorepair. Microglial cells (cell line and primary) were subjected to combined cyclic adenosine monophosphate (cyclic AMP) and IL-4, or either alone, in the presence of pro-inflammatory mediators, lipopolysaccharide (LPS), or tumor necrosis factor-α (TNF-α). Their effects on the expression of characteristic markers for M1 and M2 microglia were assessed. Similarly, the M1 and M2 phenotypes of microglia and macrophages within the lesion site were then evaluated following a contusive spinal cord injury (SCI) to the thoracic (T8) spinal cord of rats and mice when the agents were administered systemically. It was demonstrated that cyclic AMP functions synergistically with IL-4 to promote M1 to M2 conversion of microglia in culture. The combination of cyclic AMP and IL-4, but neither alone, induced an Arg-1(+)/iNOS(-)cell phenotype with concomitant expression of other M2-specific markers including TG2 and RELM-α. M2-converted microglia showed ameliorated production of pro-inflammatory cytokines (TNF-α and IP-10) and reactive oxygen species, with no alteration in phagocytic properties. M2a conversion required protein kinase A (PKA), but not the exchange protein directly activated by cyclic AMP (EPAC). Systemic delivery of cyclic AMP and IL-4 after experimental SCI also promoted a significant M1 to M2a phenotypic change in microglia and macrophage population dynamics in the lesion

Isoreticular rare earth fcu-MOFs for the selective removal of H 2 S from CO 2 containing gases

KAUST Repository

Bhatt, Prashant

2017-05-04

In this work, we present the implementation of reticular chemistry and the molecular building block approach to unveil the appropriateness of Rare Earth (RE) based Metal-Organic Frameworks (MOFs) with fcu topology for H2S removal applications. Markedly, RE-fcu-MOFs, having different pore apertures sizes in the range of 4.7-6.0 Å and different functionalities, showed excellent properties for the removal of H2S from CO2 and CH4 containing gases such as natural gas, biogas and landfill gas. A series of cyclic mixed gas breakthrough experiments were carried out on three isoreticular fcu-MOFs, containing linkers of different lengths (between 8.4 and 5 Å), by using simulated natural gas mixture containing CO2/H2S/CH4 (5%/5%/90%) under different adsorption and regeneration conditions. The fcu-MOF platform has good H2S removal capacity with a high H2S/CO2 selectivity, outperforming benchmark materials like activated carbon and Zeolites in many aspects. The comparison of H2S removal performance with the related structures of the RE-fcu-MOFs provides insightful information to shed light on the relationship between the structural features of the MOF and its associated H2S separation properties. The excellent H2S/CO2 and H2S/CH4 selectivity of these materials offer great prospective for the production of pure H2S, with acceptable levels of CO2for Claus process to produce elemental sulfur.

DEVELOPMENT OF MORE-EFFICIENT GAS FLOODING APPLICABLE TO SHALLOW RESERVOIRS

Energy Technology Data Exchange (ETDEWEB)

William R. Rossen; Russell T. Johns; Gary A. Pope

2003-08-21

The objective of this research is to widen the applicability of gas flooding to shallow oil reservoirs by reducing the pressure required for miscibility using gas enrichment and increasing sweep efficiency with foam. Task 1 examines the potential for improved oil recovery with enriched gases. Subtask 1.1 examines the effect of dispersion processes on oil recovery and the extent of enrichment needed in the presence of dispersion. Subtask 1.2 develops a fast, efficient method to predict the extent of enrichment needed for crude oils at a given pressure. Task 2 develops improved foam processes to increase sweep efficiency in gas flooding. Subtask 2.1 comprises mechanistic experimental studies of foams with N2 gas. Subtask 2.2 conducts experiments with CO{sub 2} foam. Subtask 2.3 develops and applies a simulator for foam processes in field application.

ELSA flood stack for MIS 2-3 from dry maar lakestructure Auel (Eifel/Germany)

Science.gov (United States)

Brunck, Heiko; Sirocko, Frank

2015-04-01

Lacustrine sediments are very sensitive to natural and anthropogenically enviromental changes. Thus, lake sediments are excellent climate archives and can be used for reconstructions of past precipitation and flood events. However, until now, there is no continous flood record for the entire last 60 000 years for Central Europe. The present study reconstructs paleo floods from event layers in the sediment, of dry maar lakestructure Auel (Eifel). This silted up basin has an inflow by a local stream. Accordingly the sedimentation rate is directly linked to runoff activity. The bioturbation was low so that event layers become visible, but varves are not preserved. The maar site is near to the town of Gerolstein in the Eifel; the core AU2 was drilled in the ELSA (Eifel Laminated Sediment archive) project and is 123m long. AU2 has the highest sedimentation rate of all ELSA cores, due to abundant fluvial input. The Eifel area is well suited to approximate Central European weather, because modern water level gauge data from Eifel rivers correlate with respective data from the Rhine (Wernli and Pfahl, 2009). Due to the high inflow into the maar, Auel has the highest number of botanical macro remains of all ELSA cores. These specific conditions explain why only in AU2 all 21 Greenland interstadials can be observed in the abundance of wood remains and the organic carbon concentration. In a final stratigraphic step the time series of Corg was tuned to the Greenland ice core chronology to link the central European landscape evolution directly to the Greenland climate curve (Svensson et al., 2008). Combined sedimentological, paleobotanical and geochemical data received from AU2 builds the foundation of the 14C based chronology. The synchronisation of the record with other cores is controlled by tephra time markers and pollen. Both are used to align the main cores of the ELSA project and construct an integrated age model for the last 220 000 years [b2k] (Förster and Sirocko

Biomass co-firing for Delta Electricity

International Nuclear Information System (INIS)

Anon

2014-01-01

Electricity generator Delta Electricity has implemented a biomass co-firing program at its Vales Point power station on the Central Coast to reduce its reliance on coal and emissions of CO 2 . The program comprises two parts: direct co-firing with coal of up to 5% biomass; and development of Continuous Biomass Converter (CBC) technology with the Crucible Group to remove technology constraints and enable much higher rates of biomass co-firing. It is talking industrial scale tests. Delta increased biomass co-firing in 2013/14 to 32,000 tonnes, up from just 3,000 tonnes the previous year, and conducted biochar co-firing trials at a rate equivalent to 400,000 tonnes per annum to demonstrate the potential of CBC technology. It reduced CO 2 emissions in 2013/14 by more than 32,000 tonnes. 'Legislation and regulations define biomass as renewable,' said Delta Electricity sustainability manager Justin Flood. 'By preferring biomass over coal, the carbon in the coal is not burnt and remains locked up.' One biomass source is wood waste that would normally go to landfill, but the primary driver of Delta's recent increase in co-firing is sawmill residues. 'Previously there was a higher value market for the residues for paper pulp. However, when that market evaporated the timber industry was left with a sizable problem in terms of what to do with its residues and the loss of revenue,' said Flood. The way greenhouse gas accounting is conducted in Australia, with carbon emissions based on site activities, makes it difficult to undertake a life cycle assessment of the program. 'However, some of the international studies looking at this issue have concluded that the net carbon emissions of the biomass system are significantly lower than the coal system because of the uptake of carbon during biomass growth,' said Flood. Delta identified two challenges, sourcing the feedstock and that biomass conversion to electricity is slightly less

Tacking Flood Risk from Watersheds using a Natural Flood Risk Management Toolkit

Science.gov (United States)

Reaney, S. M.; Pearson, C.; Barber, N.; Fraser, A.

2017-12-01

In the UK, flood risk management is moving beyond solely mitigating at the point of impact in towns and key infrastructure to tackle problem at source through a range of landscape based intervention measures. This natural flood risk management (NFM) approach has been trailed within a range of catchments in the UK and is moving towards being adopted as a key part of flood risk management. The approach offers advantages including lower cost and co-benefits for water quality and habitat creation. However, for an agency or group wishing to implement NFM within a catchment, there are two key questions that need to be addressed: Where in the catchment to place the measures? And how many measures are needed to be effective? With this toolkit, these questions are assessed with a two-stage workflow. First, SCIMAP-Flood gives a risk based mapping of likely locations that contribute to the flood peak. This tool uses information on land cover, hydrological connectivity, flood generating rainfall patterns and hydrological travel time distributions to impacted communities. The presented example applies the tool to the River Eden catchment, UK, with 5m grid resolution and hence provide sub-field scale information at the landscape extent. SCIMAP-Flood identifies sub-catchments where physically based catchment hydrological simulation models can be applied to test different NFM based mitigation measures. In this example, the CRUM3 catchment hydrological model has been applied within an uncertainty framework to consider the effectiveness of soil compaction reduction and large woody debris dams within a sub-catchment. It was found that large scale soil aeration to reduce soil compaction levels throughout the catchment is probably the most useful natural flood management measure for this catchment. NFM has potential for wide-spread application and these tools help to ensure that the measures are correctly designed and the scheme performance can be quantitatively assessed and predicted.

How useful are Swiss flood insurance data for flood vulnerability assessments?

Science.gov (United States)

Röthlisberger, Veronika; Bernet, Daniel; Zischg, Andreas; Keiler, Margreth

2015-04-01

The databases of Swiss flood insurance companies build a valuable but to date rarely used source of information on physical flood vulnerability. Detailed insights into the Swiss flood insurance system are crucial for using the full potential of the different databases for research on flood vulnerability. Insurance against floods in Switzerland is a federal system, the modalities are manly regulated on cantonal level. However there are some common principles that apply throughout Switzerland. First of all coverage against floods (and other particular natural hazards) is an integral part of every fire insurance policy for buildings or contents. This coupling of insurance as well as the statutory obligation to insure buildings in most of the cantons and movables in some of the cantons lead to a very high penetration. Second, in case of damage, the reinstatement costs (value as new) are compensated and third there are no (or little) deductible and co-pay. High penetration and the fact that the compensations represent a large share of the direct, tangible losses of the individual policy holders make the databases of the flood insurance companies a comprehensive and therefore valuable data source for flood vulnerability research. Insurance companies not only store electronically data about losses (typically date, amount of claims payment, cause of damage, identity of the insured object or policyholder) but also about insured objects. For insured objects the (insured) value and the details on the policy and its holder are the main feature to record. On buildings the insurance companies usually computerize additional information such as location, volume, year of construction or purpose of use. For the 19 (of total 26) cantons with a cantonal monopoly insurer the data of these insurance establishments have the additional value to represent (almost) the entire building stock of the respective canton. Spatial referenced insurance data can be used for many aspects of

A framework for probabilistic pluvial flood nowcasting for urban areas

Science.gov (United States)

Ntegeka, Victor; Murla, Damian; Wang, Lipen; Foresti, Loris; Reyniers, Maarten; Delobbe, Laurent; Van Herk, Kristine; Van Ootegem, Luc; Willems, Patrick

2016-04-01

Pluvial flood nowcasting is gaining ground not least because of the advancements in rainfall forecasting schemes. Short-term forecasts and applications have benefited from the availability of such forecasts with high resolution in space (~1km) and time (~5min). In this regard, it is vital to evaluate the potential of nowcasting products for urban inundation applications. One of the most advanced Quantitative Precipitation Forecasting (QPF) techniques is the Short-Term Ensemble Prediction System, which was originally co-developed by the UK Met Office and Australian Bureau of Meteorology. The scheme was further tuned to better estimate extreme and moderate events for the Belgian area (STEPS-BE). Against this backdrop, a probabilistic framework has been developed that consists of: (1) rainfall nowcasts; (2) sewer hydraulic model; (3) flood damage estimation; and (4) urban inundation risk mapping. STEPS-BE forecasts are provided at high resolution (1km/5min) with 20 ensemble members with a lead time of up to 2 hours using a 4 C-band radar composite as input. Forecasts' verification was performed over the cities of Leuven and Ghent and biases were found to be small. The hydraulic model consists of the 1D sewer network and an innovative 'nested' 2D surface model to model 2D urban surface inundations at high resolution. The surface components are categorized into three groups and each group is modelled using triangular meshes at different resolutions; these include streets (3.75 - 15 m2), high flood hazard areas (12.5 - 50 m2) and low flood hazard areas (75 - 300 m2). Functions describing urban flood damage and social consequences were empirically derived based on questionnaires to people in the region that were recently affected by sewer floods. Probabilistic urban flood risk maps were prepared based on spatial interpolation techniques of flood inundation. The method has been implemented and tested for the villages Oostakker and Sint-Amandsberg, which are part of the

Rising atmospheric CO{sub 2} and crops: Research methodology and direct effects

Energy Technology Data Exchange (ETDEWEB)

Rogers, H. [National Soil Dynamics Laboratory, Auburn, AL (United States); Acock, B. [Systems Research Laboratory, Beltsville, MD (United States)

1993-12-31

Carbon dioxide is the food of trees and grass. Our relentless pursuit of a better life has taken us down a traffic jammed road, past smoking factories and forests. This pursuit is forcing a rise in the atmospheric CO{sub 2} level, and no one know when and if flood stage will be reached. Some thinkers have suggested that this increase of CO{sub 2} in the atmosphere will cause warming. No matter whether this prediction is realized or not, more CO{sub 2} will directly affect plants. Data from controlled observations have usually, but not always, shown benefits. Our choices of scientific equipment for gathering CO{sub 2} response data are critical since we must see what is happening through the eye of the instrument. The signals derived from our sensors will ultimately determine the truth of our conclusions, conclusion which will profoundly influence our policy decisions. Experimental gear is selected on the basis of scale of interest and problem to be addressed. Our imaginations and our budgets interact to set bounds on our objectives and approaches. Techniques run the gamut from cellular microprobes through whole-plant controlled environment chambers to field-scale exposure systems. Trade-offs exist among the various CO{sub 2} exposure techniques, and many factors impinge on the choice of a method. All exposure chambers are derivatives of three primary types--batch, plug flow, and continuous stirred tank reactor. Systems for the generation of controlled test atmospheres of CO{sub 2} vary in two basic ways--size and degree of control. Among the newest is free-air CO{sub 2} enrichment which allows tens of square meters of cropland to be studied.

Unprecedented Carbonato Intermediates in Cyclic Carbonate Synthesis Catalysed by Bimetallic Aluminium(Salen) Complexes.

Science.gov (United States)

Castro-Osma, José A; North, Michael; Offermans, Willem K; Leitner, Walter; Müller, Thomas E

2016-04-21

The mechanism by which [Al(salen)]2 O complexes catalyse the synthesis of cyclic carbonates from epoxides and carbon dioxide in the absence of a halide cocatalyst has been investigated. Density functional theory (DFT) studies, mass spectrometry and (1) H NMR, (13) C NMR and infrared spectroscopies provide evidence for the formation of an unprecedented carbonato bridged bimetallic aluminium complex which is shown to be a key intermediate for the halide-free synthesis of cyclic carbonates from epoxides and carbon dioxide. Deuterated and enantiomerically-pure epoxides were used to study the reaction pathway. Based on the experimental and theoretical results, a catalytic cycle is proposed. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bifunctional bamboo-like CoSe2 arrays for high-performance asymmetric supercapacitor and electrocatalytic oxygen evolution

Science.gov (United States)

Chen, Tian; Li, Songzhan; Gui, Pengbin; Wen, Jian; Fu, Xuemei; Fang, Guojia

2018-05-01

Bifunctional bamboo-like CoSe2 arrays are synthesized by thermal annealing of Co(CO3)0.5OH grown on carbon cloth in Se atmosphere. The CoSe2 arrays obtained have excellent electrical conductivity, larger electrochemical active surface areas, and can directly serve as a binder-free electrode for supercapacitors and the oxygen evolution reaction (OER). When tested as a supercapacitor electrode, the CoSe2 delivers a higher specific capacitance (544.6 F g‑1 at current density of 1 mA cm‑2) compared with CoO (308.2 F g‑1) or Co3O4 (201.4 F g‑1). In addition, the CoSe2 electrode possesses excellent cycling stability. An asymmetric supercapacitor (ASC) is also assembled based on bamboo-like CoSe2 as a positive electrode and active carbon as a negative electrode in a 3.0 M KOH aqueous electrolyte. Owing to the unique stucture and good electrochemical performance of bamboo-like CoSe2, the as-assembled ACS can achieve a maximum operating voltage window of 1.7 V, a high energy density of 20.2 Wh kg‑1 at a power density of 144.1 W kg‑1, and an outstanding cyclic stability. As the catalyst for the OER, the CoSe2 exhibits a lower potential of 1.55 V (versus RHE) at current density of 10 mA cm‑2, a smaller Tafel slope of 62.5 mV dec‑1 and an also outstanding stability.

METHODOLOGICAL ASPECTS OF ECONOMIC EVENTS CYCLICITY METHOD CONSIDERATION

Directory of Open Access Journals (Sweden)

Yaskova Natalia Yur'ievna

2017-07-01

Full Text Available The cyclicity of economic phenomena is not only their immanent property but also the subject of economic analysis. The modern way of making managerial decisions requires analysis of a number of cycles that fill any kind of activity. Accounting and reconciliation of construction, design, investment, purchasing, reproduction, leasing and other cycles is important for the investment and construction sector, both from the point of view of the need for their synchronization and from the position of determining trends in sectoral development. The analysis has showed that three main types of development are characteristic for investment and construction activity. Increasing intensity is inherent in a high level of cyclic synchronization. The degradation trend arises as a result of mismatched cycles. The stabilization character is inherent in the regular modes of maintaining the established proportions and cyclical inter-conformity. The study of the cyclical nature of investment and building processes is impossible without understanding their co-ordination. The principles of synchronization and subordination of the cycles should be used not only for the construction of cost-effective systems but also for the development of management tools.

Volcanic CO2 Emissions and Glacial Cycles: Coupled Oscillations

Science.gov (United States)

Burley, J. M.; Huybers, P. J.; Katz, R. F.

2016-12-01

Following the mid-Pleistocene transition, the dominant period of glacial cycles changed from 40 ka to 100 ka. It is broadly accepted that the 40 ka glacial cycles were driven by cyclical changes in obliquity. However, this forcing does not explain the 100 ka glacial cycles. Mechanisms proposed for 100 ka cycles include isostatic bed depression and proglacial lakes destabilising the Laurentide ice sheet, non-linear responses to orbital eccentricity, and Antarctic ice sheets influencing deep-ocean stratification. None of these are universally accepted. Here we investigate the hypothesis that variations in volcanic CO2 emissions can cause 100 ka glacial cycles. Any proposed mechanism for 100 ka glacial cycles must give the Earth's climate system a memory of 10^4 - 10^5years. This timescale is difficult to achieve for surface processes, however it is possible for the solid Earth. Recent work suggests volcanic CO2 emissions change in response to glacial cycles [1] and that there could be a 50 ka delay in that response [2]. Such a lagged response could drive glacial cycles from 40 ka cycles to an integer multiple of the forcing period. Under what conditions could the climate system admit such a response? To address this, we use a simplified climate model modified from Huybers and Tziperman [3]. Our version comprises three component models for energy balance, ice sheet growth and atmospheric CO2 concentration. The model is driven by insolation alone with other components varying according to a system of coupled, differential equations. The model is run for 500 ka to produce several glacial cycles and the resulting changes in global ice volume and atmospheric CO2 concentration.We obtain a switch from 40 ka to 100 ka cycles as the volcanic CO2 response to glacial cycles is increased. These 100 ka cycles are phase-locked to obliquity, lasting 80 or 120 ka. Whilst the MOR response required (in this model) is larger than plausible estimates based on [2], it illustrates the

Internal flood analysis at Fermi 2 using a component-based frequency calculation approach

International Nuclear Information System (INIS)

Lin, J.C.; Hou, Y.M.; Ramirez, J.V.; Page, E.M.

2004-01-01

An analysis to identify potential accident sequences involving internal floods at Fermi Unit 2 was completed to fulfill the individual plant examination requirements. Floods can be significant core damage scenarios if they cause an initiating event and a common mode failure of critical systems. (author)

Attempts To Catalyze the Electrochemical CO2-to-Methanol Conversion by Biomimetic 2e(-) + 2H(+) Transferring Molecules.

Science.gov (United States)

Saveant, Jean-Michel; Tard, Cédric

2016-01-27

In the context of the electrochemical and photochemical conversion of CO2 to liquid fuels, one of the most important issues of contemporary energy and environmental issues, the possibility of pushing the reduction beyond the CO and formate level and catalytically generate products such as methanol is particularly attractive. Biomimetic 2e(-) + 2H(+) is often viewed as a potential hydride donor. This has been the object of a recent interesting attempt (J. Am. Chem. Soc. 2014, 136, 14007) in which 6,7-dimethyl-4-hydroxy-2-mercaptopteridine was reported as a catalyst of the electrochemical conversion of CO2 to methanol and formate, based on cyclic voltammetric, (13)C NMR, IR, and GC analyses. After checking electrolysis at the reported potential and at a more negative potential to speed up the reaction, it appears, on (1)H NMR and gas chromatographic grounds, that there is neither catalysis nor methanol and nor formate production. (1)H NMR (with H2O presaturation) brings about an unambiguous answer to the eventual production of methanol and formate, much more so than (13)C NMR, which can even be misleading when no internal standard is used as in the above-mentioned paper. IR analysis is even less conclusive. Use of a GC technique with sufficient sensitivity confirmed the lack of methanol formation. The direct or indirect hydride transfer electrochemical reduction of CO2 to formate and to methanol remains an open question. Original ideas and efforts such as those discussed here are certainly worth tempting. However, in view of the importance of the stakes, it appears necessary to carefully check reports in this area.

The climate and flood risk potential of northern areas of Pakistan

International Nuclear Information System (INIS)

Awan, S.A.

2002-01-01

The extreme floods in northern parts of Pakistan are caused by glacier lake outbursts and Dam-Breaks following landslides, which block river valleys. Geographically glacier dams in mountain rivers and valleys have occurred from the east-western and west-western Karakuram ranges and in the lesser Karakuram range floods which arise from Karakuram precipitation and temperature of various region pose greater problem, as these floods are neither homogeneous nor stationary. These floods arise from various generating mechanisms i. e. generated by melting of snow and glacier and those generated from the monsoon rainfall and dam-breaks following landslide into the river and out burst of glacier lake. The estimation of present and future risk of flooding at sites in northern Pakistan requires an understanding, of the climate, which provides, the generating mechanism of floods. Climates are extremely variable and depend op broad global circulation patterns and local topographic influences. The variables of the climate are studied using available data, with emphasis on temperature and precipitation Spatial Co-relation in northern area stations have been conducted to find Co-relation Co-efficient, using regression analysis. This is spread over intra seasonal and inter station comparison. The time series analysis of the climatic variables has been conducted to examine geographically and statistically the trend in their behaviour. This may be reflected in the hydrological regime of glaciers and rivers and it can cause non linear flood series through changes in any one of the flood generating mechanism. The climate feed-back mechanism has been discussed, which are practically important because they assist seasonal prediction of climate and flow in the Indus. Additionally if climate warming is causing an upward Trend in winter and spring temperature and reduction in snowfall, the effect might be felt more widely over the region. The non-linear changes with elevation and differences

Advanced Reservoir Characterization in the Antelope Shale to Establish the Viability of CO2 Enhanced Oil Recovery in California's Monterey Formation Siliceous Shales

International Nuclear Information System (INIS)

Morea, Michael F.

1999-01-01

The primary objective of this research is to conduct advanced reservoir characterization and modeling studies in the Antelope Shale reservoir. Characterization studies will be used to determine the technical feasibility of implementing a CO2 enhanced oil recovery project in the Antelope Shale in Buena Vista Hills Field. The Buena Vista Hills pilot CO2 project will demonstrate the economic viability and widespread applicability of CO2 flooding in fractured siliceous shale reservoirs of the San Joaquin Valley. The research consists of four primary work processes: (1) Reservoir Matrix and Fluid Characterization; (2) Fracture characterization; (3) reservoir Modeling and Simulation; and (4) CO2 Pilot Flood and Evaluation. Work done in these areas is subdivided into two phases or budget periods. The first phase of the project will focus on the application of a variety of advanced reservoir characterization techniques to determine the production characteristics of the Antelope Shale reservoir. Reservoir models based on the results of the characterization work will be used to evaluate how the reservoir will respond to secondary recovery and EOR processes. The second phase of the project will include the implementation and evaluation of an advanced enhanced oil recovery (EOR) pilot in the United Anticline (West Dome) of the Buena Vista Hills Field

Violet Grove CO{sub 2} injection project : monitoring with timelapse VSP surveys

Energy Technology Data Exchange (ETDEWEB)

Coueslan, M.; Lawton, D. [Calgary Univ., Calgary, AB (Canada); Jones, M. [Schlumberger Canada Ltd., Calgary, AB (Canada)

2006-07-01

Several oil and gas fields in western Canada have been depleted through primary production and secondary recovery methods. Injecting carbon dioxide (CO{sub 2}) into a reservoir can enhance oil recovery (EOR) and has the potential benefit of CO{sub 2} sequestration, which reduces greenhouse gas emissions into the atmosphere. It has been estimated that western Canada has a practical CO{sub 2} storage capacity of about 3.3 Gt in its oil and gas reservoirs. In order to claim a reduction in CO{sub 2} emissions, however, the injected CO{sub 2} must be monitored to prove that it is being trapped in these reservoirs. For that reason, the Violet Grove site, near Drayton Valley, Alberta was chosen as a pilot site to study CO{sub 2} injection into a reservoir for enhanced recovery and carbon sequestration purposes. The reservoir is located in the Cardium Formation in the Pembina Field. It was expected that the CO{sub 2} would flow preferentially in the reservoir's dominant fracture orientation, which is northeast-southwest. Simultaneously acquired time-lapse multicomponent surface and borehole seismic surveys were used to monitor changes in the reservoir. Prior to CO{sub 2} injection, a baseline survey was acquired in March 2005. A second survey was acquired 8 months after CO{sub 2} injection. The borehole seismic data displayed higher bandwidth and increased resolution compared to the surface seismic data. The PS-wave borehole seismic data in particular showed much better results. Together, these seismic surveys provide lateral coverage of the area as well as high resolution images near the observation well. Preliminary results from the time-lapse analysis show an increase of 30 to 60 per cent in the reservoir reflectivity amplitudes in the 8 months between the baseline and monitor surveys, suggesting that the CO{sub 2} flood has progressed southwest of the injector, most likely along the dominant fracture trend. 7 refs., 5 figs.