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Sample records for crystal grain size

  1. Enhanced crystal grain size by bromine doping in electrodeposited Cu{sub 2}O

    Energy Technology Data Exchange (ETDEWEB)

    Han Kunhee; Kang Feng [Department of Electrical Engineering, University of Texas at Arlington, Arlington, TX 76019 (United States); Han Xiaofei [Department of Material Science and Engineering, University of Texas at Arlington, Arlington, TX 76019 (United States); Tao Meng, E-mail: meng.tao@asu.edu [Department of Electrical Engineering, University of Texas at Arlington, Arlington, TX 76019 (United States)

    2012-06-01

    Extremely large crystal grains are obtained by bromine doping in electrodeposited Cu{sub 2}O on indium tin oxide (ITO) substrate through an acetate bath. The grains are as large as 10,000 {mu}m{sup 2} in area, or {approx} 100 {mu}m in linear dimension, while the film is only 1-5 {mu}m thick. The enhanced grain size is explained by the effect of over-potential for the Cu{sup 2+}/Cu{sup +} redox couple on nucleation density of Cu{sub 2}O on ITO substrate. The over-potential is a function of several deposition conditions including solution pH, deposition potential, deposition temperature, bromine precursor concentration, and copper precursor concentration. In addition, undoped Cu{sub 2}O displays a high resistivity of 100 M{Omega}cm. Bromine doping in Cu{sub 2}O significantly reduces the resistivity to as low as 42 {Omega}cm after vacuum annealing. Br-doped Cu{sub 2}O shows n-type behavior. - Highlights: Black-Right-Pointing-Pointer Extremely large crystal grains ({approx} 100 {mu}m) achieved in electrodeposited Br-doped Cu{sub 2}O. Black-Right-Pointing-Pointer Large grains reduce carrier recombination and carrier scattering at grain boundaries. Black-Right-Pointing-Pointer N-type behavior demonstrated in naturally p-type Cu{sub 2}O by Br doping.

  2. The Influence of Grain Size and Crystal Content on Rheology and Deformation of Pyroclastic Material

    Science.gov (United States)

    Paquereau-Lebti, P.; Robert, G.; Grunder, A. L.; Russell, K. J.

    2007-12-01

    Pyroclastic deposits undergo variable degrees of sintering, viscous deformation of particles and loss of pore space, which combine to produce the dramatic textural variations that define welded facies. We here investigate the effects of grain size and crystal content on the rheology and welding of pyroclastic material.Uniaxial deformation experiments were conducted using sintered cores of natural rhyolite ash under conditions consistent with welding. Experiments were done in the University of British Columbia Volcanology Deformation Rig (VDR). This apparatus is designed to run experiments relevant to volcanology, by supporting low-load, high temperature, deformation experiments (Quane et al., 2004). We ran experiments at constant displacement rate (2.5.10-6 m.s-1), under ambient water pressure ("Dry"), at temperatures of 850 and 900°C and to maximal strain of 50%. Grain-size effect was investigated using sintered cores from three different sieving fractions of Rattlesnake Tuff (RST, Eastern Oregon, USA) ash: fine ash (grain size 15% crystal content inhibited sintering in a sample that welded under the same experimental conditions when phenocryst depleted (phenocryst content around 1% in whole Rattlesnake Tuff ash). Reference: Quane, S.L., Russell, J.K., and Kennedy, L.A. (2004). A low-load, high-temperature deformation apparatus for volcanological studies. American mineralogist, 89, 873-877.

  3. Crystal growth and the steady-state grain size during high-energy ball-milling

    DEFF Research Database (Denmark)

    Mørup, Steen; Jiang, Jianzhong; Bødker, Franz

    2001-01-01

    The change in crystal size during high-energy ball-milling of hematite and zinc sulphide powders with initial average crystal size of 8 nm and 4 nm, respectively, has been investigated by X-ray powder diffraction and transmission electron microscopy. It is found that the crystal size increases wi...

  4. A strain gradient crystal plasticity analysis of grain size effects in polycrystals

    DEFF Research Database (Denmark)

    Borg, Ulrik

    2007-01-01

    individually oriented grains, in a unit cell, each having three planar slip systems. An energy potential that penalizes crystallographic slip at grain boundaries is included in the analyzes. The polycrystal is subjected to plane strain tension for various grain sizes and higher order boundary conditions...

  5. On the effect of the amorphous silicon microstructure on the grain size of solid phase crystallized polycrystalline silicon

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Kashish; Branca, Annalisa; Illiberi, Andrea; Creatore, Mariadriana; Sanden, Mauritius C.M. van de [Department of Applied Physics, Eindhoven University of Technology (Netherlands); Tichelaar, Frans D. [Kavli Institute of Nanoscience, Delft University of Technology (Netherlands)

    2011-05-15

    In this paper the effect of the microstructure of remote plasma-deposited amorphous silicon films on the grain size development in polycrystalline silicon upon solid-phase crystallization is reported. The hydrogenated amorphous silicon films are deposited at different microstructure parameter values R* (which represents the distribution of SiH{sub x} bonds in amorphous silicon), at constant hydrogen content. Amorphous silicon films undergo a phase transformation during solid-phase crystallization and the process results in fully (poly-)crystallized films. An increase in amorphous film structural disorder (i.e., an increase in R*), leads to the development of larger grain sizes (in the range of 700-1100 nm). When the microstructure parameter is reduced, the grain size ranges between 100 and 450 nm. These results point to the microstructure parameter having a key role in controlling the grain size of the polycrystalline silicon films and thus the performance of polycrystalline silicon solar cells. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  6. Crystal preferred orientation in peridotite ultramylonites deformed by grain size sensitive creep, étang de Lers, Pyrenees, France

    NARCIS (Netherlands)

    Drury, M.R.; Avé Lallemant, H.G.; Pennock, G.M.; Palasse, L.N.

    2011-01-01

    In naturally deformed upper mantle rocks a strong olivine crystallographic preferred orientation (CPO) occurs in rocks with grain sizes larger than about 15 mm. Finer grained peridotites tend to have weak to random olivine CPO. The different types of olivine CPO are usually interpreted in relation t

  7. Apatite (U-Th-Sm)/He age dispersion arising from analysis of variable grain sizes and broken crystals - examples from the Scottish Southern Uplands

    Science.gov (United States)

    Łuszczak, Katarzyna; Persano, Cristina; Stuart, Finlay; Brown, Roderick

    2016-04-01

    Apatite (U-Th-Sm)/He (AHe) thermochronometry is a powerful technique for deciphering denudation of the uppermost crust. However, the age dispersion of single grains from the same rock is typical, and this hampers establishing accurate thermal histories when low grain numbers are analysed. Dispersion arising from the analysis of broken crystal fragments[1] has been proposed as an important cause of age dispersion, along with grain size and radiation damage. A new tool, Helfrag[2], allows constraints to be placed on the low temperature history derived from the analysis of apatite crystal fragments. However, the age dispersion model has not been fully tested on natural samples yet. We have performed AHe analysis of multiple (n = 20-25) grains from four rock samples from the Scottish Southern Uplands, which were subjected to the same exhumation episodes, although, the amount of exhumation varied between the localities. This is evident from the range of AFT ages (˜60 to ˜200 Ma) and variable thermal histories showing either strong, moderate and no support for a rapid cooling event at ˜60 Ma. Different apatite size and fragment geometry were analysed in order to maximise age dispersion. In general, the age dispersion increases with increasing AFT age (from 47% to 127%), consistent with the prediction from the fragmentation model. Thermal histories obtained using Helfrag were compared with those obtained by standard codes based on the spherical approximation. In one case, the Helfrag model was capable of resolving the higher complexity of the thermal history of the rock, constraining several heating/cooling events that are not predicted by the standard models, but are in good agreement with the regional geology. In other cases, the thermal histories are similar for both Helfrag and standard models and the age predictions for the Helfrag are only slightly better than for standard model, implying that the grain size has the dominant role in generating the age dispersion

  8. Size effects in crystal plasticity

    DEFF Research Database (Denmark)

    Borg, Ulrik

    2007-01-01

    Numerical analyses of plasticity size effects have been carried out for different problems using a developed strain gradient crystal plasticiy theory. The theory employs higher order stresses as work conjugates to slip gradients and uses higher order boundary conditions. Problems on localization...... of plastic flow in a single crystal, grain boundary effects in a bicrystal, and grain size effects in a polycrystal are studied. Single crystals containing micro-scale voids have also been analyzed at different loading conditions with focus on the stress and deformation fields around the voids, on void...... growth and interaction between neighboring voids, and on a comparison between the developed strain gradient crystal plasticity theory and a discrete dislocation plasticity theory. Furthermore, voids and rigid inclusions in isotropic materials have been studied using a strain gradient plasticity theory...

  9. Complete grain boundaries from incomplete EBSD maps: the influence of segmentation on grain size determinations

    Science.gov (United States)

    Heilbronner, Renée; Kilian, Ruediger

    2017-04-01

    Grain size analyses are carried out for a number of reasons, for example, the dynamically recrystallized grain size of quartz is used to assess the flow stresses during deformation. Typically a thin section or polished surface is used. If the expected grain size is large enough (10 µm or larger), the images can be obtained on a light microscope, if the grain size is smaller, the SEM is used. The grain boundaries are traced (the process is called segmentation and can be done manually or via image processing) and the size of the cross sectional areas (segments) is determined. From the resulting size distributions, 'the grain size' or 'average grain size', usually a mean diameter or similar, is derived. When carrying out such grain size analyses, a number of aspects are critical for the reproducibility of the result: the resolution of the imaging equipment (light microscope or SEM), the type of images that are used for segmentation (cross polarized, partial or full orientation images, CIP versus EBSD), the segmentation procedure (algorithm) itself, the quality of the segmentation and the mathematical definition and calculation of 'the average grain size'. The quality of the segmentation depends very strongly on the criteria that are used for identifying grain boundaries (for example, angles of misorientation versus shape considerations), on pre- and post-processing (filtering) and on the quality of the recorded images (most notably on the indexing ratio). In this contribution, we consider experimentally deformed Black Hills quartzite with dynamically re-crystallized grain sizes in the range of 2 - 15 µm. We compare two basic methods of segmentations of EBSD maps (orientation based versus shape based) and explore how the choice of methods influences the result of the grain size analysis. We also compare different measures for grain size (mean versus mode versus RMS, and 2D versus 3D) in order to determine which of the definitions of 'average grain size yields the

  10. The NGDC Seafloor Sediment Grain Size Database

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The NGDC (now NCEI) Seafloor Sediment Grain Size Database contains particle size data for over 17,000 seafloor samples worldwide. The file was begun by NGDC in 1976...

  11. Synthesis and characterisation of nanostructured neodymium titanium oxides by sol-gel process: Controlling the phase composition, crystal structure and grain size

    Energy Technology Data Exchange (ETDEWEB)

    Mohammadi, M.R., E-mail: mrm41@cam.ac.uk [Department of Materials Science and Engineering, Sharif University of Technology, Azadi Street, Tehran (Iran, Islamic Republic of); Department of Materials Science and Metallurgy, University of Cambridge, Pembroke Street, Cambridge CB2 3QZ (United Kingdom); Fray, D.J., E-mail: djf25@cam.ac.uk [Department of Materials Science and Metallurgy, University of Cambridge, Pembroke Street, Cambridge CB2 3QZ (United Kingdom)

    2010-08-01

    Nanocrystalline neodymium titanium oxide thin films and powders with different phase compositions with mesoporous structure were produced by a straightforward particulate sol-gel route. The sols were prepared in various Nd:Ti molar ratios and they showed a narrow particle size distribution in the range 20-26 nm. X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) revealed that the powders contained mixtures of Nd{sub 4}Ti{sub 9}O{sub 24}, Nd{sub 2}Ti{sub 4}O{sub 11}, Nd{sub 3}Ti{sub 4}O{sub 12} for titanium dominant powders (Nd:Ti {<=} 45:60), mixtures of Nd{sub 2}TiO{sub 5} and Nd{sub 2}O{sub 3} for neodymium dominant powders (Nd:Ti {>=} 75:25) and pure Nd{sub 3}Ti{sub 4}O{sub 12} phase for equal molar ratio of Nd:Ti, depending on the annealing temperature and Nd:Ti molar ratio. Moreover, it was found that Nd:Ti molar ratio influences the preferable orientation growth of the neodymium titanium oxide compounds. Transmission electron microscope (TEM) images confirmed that the average crystallite size of the powders annealed at 400 {sup o}C was in the range 1.0-2.8 nm and a gradual increase was occurred up to 6.7 nm by heat treatment at 1000 {sup o}C. The activation energy of crystal growth reduced with a decrease of Nd:Ti molar ratio, calculated in the range 6.90-18.12 kJ mol{sup -1}. Low activation energies indicating that the grain size will not change much with increase in temperature. Field emission scanning electron microscope (FE-SEM) analysis revealed that the deposited thin films had uniform, mesoporous and nanocrystalline structure. Moreover, atomic force microscope (AFM) images presented that the thin films had a columnar like morphology with average grain size in the range 17-30 nm at 600 {sup o}C and 47-60 nm at 800 {sup o}C, depending upon the Nd:Ti molar ratio. Based on Brunauer-Emmett-Taylor (BET) analysis, the synthesized powders showed mesoporous structure containing pores with sphere like shapes. The surface area of the

  12. Grain dissection as a grain size reducing mechanism during ice microdynamics

    Science.gov (United States)

    Steinbach, Florian; Kuiper, Ernst N.; Eichler, Jan; Bons, Paul D.; Drury, Martin R.; Griera, Albert; Pennock, Gill M.; Weikusat, Ilka

    2017-04-01

    Ice sheets are valuable paleo-climate archives, but can lose their integrity by ice flow. An understanding of the microdynamic mechanisms controlling the flow of ice is essential when assessing climatic and environmental developments related to ice sheets and glaciers. For instance, the development of a consistent mechanistic grain size law would support larger scale ice flow models. Recent research made significant progress in numerically modelling deformation and recrystallisation mechanisms in the polycrystalline ice and ice-air aggregate (Llorens et al., 2016a,b; Steinbach et al., 2016). The numerical setup assumed grain size reduction is achieved by the progressive transformation of subgrain boundaries into new high angle grain boundaries splitting an existing grain. This mechanism is usually termed polygonisation. Analogue experiments suggested, that strain induced grain boundary migration can cause bulges to migrate through the whole of a grain separating one region of the grain from another (Jessell, 1986; Urai, 1987). This mechanism of grain dissection could provide an alternative grain size reducing mechanism, but has not yet been observed during ice microdynamics. In this contribution, we present results using an updated numerical approach allowing for grain dissection. The approach is based on coupling the full field theory crystal visco-plasticity code (VPFFT) of Lebensohn (2001) to the multi-process modelling platform Elle (Bons et al., 2008). VPFFT predicts the mechanical fields resulting from short strain increments, dynamic recrystallisation process are implemented in Elle. The novel approach includes improvements to allow for grain dissection, which was topologically impossible during earlier simulations. The simulations are supported by microstructural observations from NEEM (North Greenland Eemian Ice Drilling) ice core. Mappings of c-axis orientations using the automatic fabric analyser and full crystallographic orientations using electron

  13. SEGMENTATION AND GRAIN SIZE OF CERAMICS

    Directory of Open Access Journals (Sweden)

    Xavier Arnould

    2011-05-01

    Full Text Available This paper presents some methods to automatically extract the grain boundaries of materials in order to develop an automatic method to determine the grain size and morphological parameters of ceramic materials. Results are presented in the case of sintered cerine (CeO2 materials.

  14. Ce2O3微粒对低碳钢夹杂和晶粒度的影响%Effect of Ce2O3 Particle on Crystal Grain Size and Inclusion of Low Carbon Steel

    Institute of Scientific and Technical Information of China (English)

    彭军; 王键; 李样兵; 郭瑞华; 安胜利

    2012-01-01

    The effect of Ce2O3 particle on inclusion and crystal grain size of steel product was studied by adding Ce2O3 particle into steel. The result shows the content of inclusion in steel will not increase when the particle size of Ce2O3 is lower than 1.13 |xm, but the content of inclusion will obviously increase when the size is higher than 2.34 μm. The Ce2O3 particle can combine with sulfide inclusion and deoxided product, which has the same function as adding rare earth alloy into steel partially. The Ce2O3 particle can reduce the size of crystal grain of cast structure. The average size of crystal grain is reduced from 180 μm to 90~75 μm. And it can also reduce the size of crystal grain of rolled structure. The degree is reduced from level 6.5 to level 11. The best economic and technical norms can be got when the size of Ce2O3 particle is 1.13 μm and the adding content is 0.5% of the content of metal.%通过在钢中外加Ce2O3微粒的方法,研究Ce2O3微粒对钢材夹杂物和晶粒度的影响.结果表明,Ce2O3粒度不大于1.13 μm时,钢中夹杂物含量不会增加,粒度大于2.34 μm时夹杂物含量会明显增加.外加Ce2O3微粒可以和钢中硫化物夹杂和脱氧产物结合,起到加稀土合金的部分作用.Ce2O3微粒可以细化铸态晶粒的粒度,晶粒平均尺寸由180 μm降低到90~75 μm;也可显著降低轧态组织的晶粒度,使晶粒度由6.5级降低到11级.当添加Ce2O3微粒粒度为1.13 μm,加入量为金属量的0.5%时,可以取得最好的经济技术指标.

  15. Function of magnesium aluminate hydrate and magnesium nitrate as MgO addition in crystal structure and grain size control of -Al2O3 during sintering

    Indian Academy of Sciences (India)

    Soumen Pal; A K Bandyopadhyay; S Mukherjee; B N Samaddar; P G Pal

    2010-02-01

    Chemically pure reactive alumina (-Al2O3) which is commercially available was used for densification study in presence of widely accepted dopant MgO as additive. MgO was added both as spinel (MgAl2O4) forming precursor i.e. magnesium aluminate hydrate, and magnesium nitrate. Sintering investigations were conducted in the temperature range 1500–1600°C with 2 h soaking. Structural study of sintered pellets was carried out by extensive XRD analysis. Scanning electron mode SEM images of the specimens were considered to understand the effect of both types of additions. Addition of MgO within and beyond optimum amount had some effect on development of microstructure of sintered bodies. Densification, around 99% ρth, with fine grain microstructure was achieved. These different types of additions caused two distinct changes in crystal structure of alumina-one small contraction and the other expansion of unit cell parameters.

  16. Ice crystal c-axis orientation and mean grain size measurements from the Dome Summit South ice core, Law Dome, East Antarctica

    Science.gov (United States)

    Treverrow, Adam; Jun, Li; Jacka, Tim H.

    2016-06-01

    We present measurements of crystal c-axis orientations and mean grain area from the Dome Summit South (DSS) ice core drilled on Law Dome, East Antarctica. All measurements were made on location at the borehole site during drilling operations. The data are from 185 individual thin sections obtained between a depth of 117 m below the surface and the bottom of the DSS core at a depth of 1196 m. The median number of c-axis orientations recorded in each thin section was 100, with values ranging from 5 through to 111 orientations. The data from all 185 thin sections are provided in a single comma-separated value (csv) formatted file which contains the c-axis orientations in polar coordinates, depth information for each core section from which the data were obtained, the mean grain area calculated for each thin section and other data related to the drilling site. The data set is also available as a MATLAB™ structure array. Additionally, the c-axis orientation data from each of the 185 thin sections are summarized graphically in figures containing a Schmidt diagram, histogram of c-axis colatitudes and rose plot of c-axis azimuths. All these data are referenced by doi:10.4225/15/5669050CC1B3B and are available free of charge at https://data.antarctica.gov.au" target="_blank">https://data.antarctica.gov.au.<

  17. Study of Surface Cell Madelung Constant and Surface Free Energy of Nanosized Crystal Grain

    Institute of Scientific and Technical Information of China (English)

    ZHANG Wei-Jia; WANG Tian-Min; CUI Min

    2005-01-01

    Surface cell Madelung constant is firstly defined in calculating surface free energy of nanosized crystal grains, which explains the physical performance of small crystals and may be great benefit to make surface analysis and study dynamics of crystal nucleus growth. A new ap- proximative expression of surface energy and relevant thermodynamic data was used in this cal- culation. A new formula and computing method for calculating the Madelung constant α of any complex crystals is proposed, and surface free energies and surface electrostatic energies of nano- sized crystal grains as well as Madelung constant of some complex crystals are theoretically cal- culated in this paper. The surface free energy of nanosized crystal grain TiO2 and surface elec- trostatic energy(absolute value) of nanosized crystal grain α-Al2O3 are found to be the biggest among other crystal grains.

  18. The spatial distribution of grains and crystals in rocks

    Science.gov (United States)

    Jerram, D. A.; Cheadle, Michael J.; Hunter, Robert H.; Elliott, Michael T.

    1996-09-01

    Characterisation and analysis of the spatial distribution pattern (SDP) of grains or crystals in rocks is potentially a powerful technique which can be used to constrain the processes which operate in the formation of rocks. A method to quantify the SDP of grains in thin section is presented. The distance betwen the centre of a grain and the centre of its nearest neighbour is calculated for all the grains in the sample area to produce a distribution of distances that characterises the spatial pattern of grains in the rock. This distribution is then normalised to a random distribution of points with the same population density to give a descriptive value, R. Values of R for rock samples are plotted against porosity (modal abundance of other phases in igneous and metamorphic rocks) to characterise the SDP. The SDP of randomly packed distributions of equal size spheres varies systematically with porosity, producing a line on a porosity versus R plot, termed the random sphere distribution line (RSDL). Rocks which plot above the RSDL have an ordered SDP and those that plot below, a clustered SDP. The effects of variation in grain packing order, grain sorting, compaction and random crystallisation (overgrowth) on determined R values were investigated using a combination of 3-D sphere models and 2-D texture models. The maximum possible value of R is 2.148, corresponding to a perfect section through hexagonal/cubic close packing of grains. The minimum value of R is dependent on the proportion of grains in the sample volume and may be as low as 1.2, for a sample volume with 30% grains which are clustered. Variations in size sorting can cause R to vary by approximately 0.25. Mechanical compaction of a loose framework of grains results in a higher packing order and an increase in R. Continued compaction creates a fabric in the texture and R decreases as cluster patterns are developed perpendicular to the principal stress. The overgrowth of grains in a touching framework

  19. Location control of crystal grains in excimer laser crystallization of silicon thin films

    Science.gov (United States)

    Kumomi, Hideya

    2003-07-01

    Location of crystal grains in polycrystalline Si thin films formed by excimer-laser crystallization is controlled by manipulating the superlateral-growth phenomenon. The superlateral growth of a single grain occurs preferentially at an artificial site where nanometer-sized crystallites are embedded in the precursory amorphous thin films. Only a part of the crystallites embedded in the site could survive the melting and grow to serve as the seed crystal in the subsequent recrystallization. Such grain-location control provides a basis for two-dimensional control of the grain-boundary location in low-temperature polycrystalline Si thin films, which is essential to the device-to-device uniformity of high-performance thin-film transistors.

  20. Relative importance of grain boundaries and size effects in thermal conductivity of nanocrystalline materials.

    Science.gov (United States)

    Dong, Huicong; Wen, Bin; Melnik, Roderick

    2014-11-13

    A theoretical model for describing effective thermal conductivity (ETC) of nanocrystalline materials has been proposed, so that the ETC can be easily obtained from its grain size, single crystal thermal conductivity, single crystal phonon mean free path (PMFP), and the Kaptiza thermal resistance. In addition, the relative importance between grain boundaries (GBs) and size effects on the ETC of nanocrystalline diamond at 300 K has been studied. It has been demonstrated that with increasing grain size, both GBs and size effects become weaker, while size effects become stronger on thermal conductivity than GBs effects.

  1. Hierarchical thermoelectrics: crystal grain boundaries as scalable phonon scatterers

    Science.gov (United States)

    Selli, Daniele; Boulfelfel, Salah Eddine; Schapotschnikow, Philipp; Donadio, Davide; Leoni, Stefano

    2016-02-01

    Thermoelectric materials are strategically valuable for sustainable development, as they allow for the generation of electrical energy from wasted heat. In recent years several strategies have demonstrated some efficiency in improving thermoelectric properties. Dopants affect carrier concentration, while thermal conductivity can be influenced by alloying and nanostructuring. Features at the nanoscale positively contribute to scattering phonons, however those with long mean free paths remain difficult to alter. Here we use the concept of hierarchical nano-grains to demonstrate thermal conductivity reduction in rocksalt lead chalcogenides. We demonstrate that grains can be obtained by taking advantage of the reconstructions along the phase transition path that connects the rocksalt structure to its high-pressure form. Since grain features naturally change as a function of size, they impact thermal conductivity over different length scales. To understand this effect we use a combination of advanced molecular dynamics techniques to engineer grains and to evaluate thermal conductivity in PbSe. By affecting grain morphologies only, i.e. at constant chemistry, two distinct effects emerge: the lattice thermal conductivity is significantly lowered with respect to the perfect crystal, and its temperature dependence is markedly suppressed. This is due to an increased scattering of low-frequency phonons by grain boundaries over different size scales. Along this line we propose a viable process to produce hierarchical thermoelectric materials by applying pressure via a mechanical load or a shockwave as a novel paradigm for material design.

  2. Grain size dependent mechanical properties in nanophase materials

    Energy Technology Data Exchange (ETDEWEB)

    Siegel, R.W. [Argonne National Lab., IL (United States); Fougere, G.E. [Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering

    1995-02-01

    It has become possible in recent years to synthesize metals and ceramics under well controlled conditions with constituent grain structures on a manometer size scale (below 100 nm). These new materials have mechanical properties that are strongly grain-size dependent and often significantly different than those of their coarser grained counterparts. Nanophase metals tend to become stronger and ceramics are more easily deformed as grain size is reduced. The observed mechanical property changes appear to be related primarily to grain size limitations and the large percentage of atoms in grain boundary environments. A brief overview of our present knowledge about the grain-size dependent mechanical properties of nanophase materials is presented.

  3. The role of grain size in He bubble formation: Implications for swelling resistance

    Science.gov (United States)

    El-Atwani, O.; Nathaniel, J. E.; Leff, A. C.; Muntifering, B. R.; Baldwin, J. K.; Hattar, K.; Taheri, M. L.

    2017-02-01

    Nanocrystalline metals are postulated as radiation resistant materials due to their high defect and particle (e.g. Helium) sink density. Here, the performance of nanocrystalline iron films is investigated in-situ in a transmission electron microscope (TEM) using He irradiation at 700 K. Automated crystal orientation mapping is used in concert with in-situ TEM to explore the role of grain orientation and grain boundary character on bubble density trends. Bubble density as a function of three key grain size regimes is demonstrated. While the overall trend revealed an increase in bubble density up to a saturation value, grains with areas ranging from 3000 to 7500 nm2 show a scattered distribution. An extrapolated swelling resistance based on bubble size and areal density indicated that grains with sizes less than 2000 nm2 possess the greatest apparent resistance. Moreover, denuded zones are found to be independent of grain size, grain orientation, and grain boundary misorientation angle.

  4. Universal scaling of grain size distributions during dislocation creep

    Science.gov (United States)

    Aupart, Claire; Dunkel, Kristina G.; Angheluta, Luiza; Austrheim, Håkon; Ildefonse, Benoît; Malthe-Sørenssen, Anders; Jamtveit, Bjørn

    2017-04-01

    Grain size distributions are major sources of information about the mechanisms involved in ductile deformation processes and are often used as paleopiezometers (stress gauges). Several factors have been claimed to influence the stress vs grain size relation, including the water content (Jung & Karato 2001), the temperature (De Bresser et al., 2001), the crystal orientation (Linckens et al., 2016), the presence of second phase particles (Doherty et al. 1997; Cross et al., 2015), and heterogeneous stress distributions (Platt & Behr 2011). However, most of the studies of paleopiezometers have been done in the laboratory under conditions different from those in natural systems. It is therefore essential to complement these studies with observations of naturally deformed rocks. We have measured olivine grain sizes in ultramafic rocks from the Leka ophiolite in Norway and from Alpine Corsica using electron backscatter diffraction (EBSD) data, and calculated the corresponding probability density functions. We compared our results with samples from other studies and localities that have formed under a wide range of stress and strain rate conditions. All distributions collapse onto one universal curve in a log-log diagram where grain sizes are normalized by the mean grain size of each sample. The curve is composed of two straight segments with distinct slopes for grains above and below the mean grain size. These observations indicate that a surprisingly simple and universal power-law scaling describes the grain size distribution in ultramafic rocks during dislocation creep irrespective of stress levels and strain rates. Cross, Andrew J., Susan Ellis, and David J. Prior. 2015. « A Phenomenological Numerical Approach for Investigating Grain Size Evolution in Ductiley Deforming Rocks ». Journal of Structural Geology 76 (juillet): 22-34. doi:10.1016/j.jsg.2015.04.001. De Bresser, J. H. P., J. H. Ter Heege, and C. J. Spiers. 2001. « Grain Size Reduction by Dynamic

  5. [Methods for grain size analysis of nanomedicines].

    Science.gov (United States)

    Geng, Zhi-Wang; He, Lan; Zhang, Qi-Ming; Yang, Yong-Jian

    2012-07-01

    As nanomedicines are developing fast in both academic and market areas, building up suitable methods for nanomedicine analysis with proper techniques is an important subject, requiring further research. The techniques, which could be employed for grain size analysis of nanomedicines, were reviewed. Several key techniques were discussed with their principles, scope of applications, advantages and defects. Their applications to nanomedine analysis were discussed according to the properties of different nanomedicines, with the purpose of providing some suggestions for the control and administration of nanomedicines.

  6. Paleowattmeters: A scaling relation for dynamically recrystallized grain size

    Science.gov (United States)

    Austin, Nicholas J.; Evans, Brian

    2007-04-01

    During dislocation creep, mineral grains often evolve to a stable size, dictated by the deformation conditions. We suggest that grain-size evolution during deformation is determined by the rate of mechanical work. Provided that other elements of microstructure have achieved steady state and that the dissipation rate is roughly constant, then changes in internal energy will be proportional to changes in grain-boundary area. If normal grain-growth and dynamic grain-size reduction occur simultaneously, then the steady-state grain size is determined by the balance of those rates. A scaling model using these assumptions and published grain-growth and mechanical relations matches stress grain-size relations for quartz and olivine rocks with no fitting. For marbles, the model also explains scatter not rationalized by assuming that recrystallized grain size is a function of stress alone. When extrapolated to conditions typical for natural mylonites, the model is consistent with field constraints on stresses and strain rates.

  7. Grain-size sorting and slope failure in experimental subaqueous grain flows

    NARCIS (Netherlands)

    Kleinhans, M.G.; Asch, Th.W.J. van

    2005-01-01

    Grain-size sorting in subaqueous grain flows of a continuous range of grain sizes is studied experimentally with three mixtures. The observed pattern is a combination of stratification and gradual segregation. The stratification is caused by kinematic sieving in the grain flow. The segregation is

  8. Grain-size sorting and slope failure in experimental subaqueous grain flows

    NARCIS (Netherlands)

    Kleinhans, M.G.; Asch, Th.W.J. van

    2005-01-01

    Grain-size sorting in subaqueous grain flows of a continuous range of grain sizes is studied experimentally with three mixtures. The observed pattern is a combination of stratification and gradual segregation. The stratification is caused by kinematic sieving in the grain flow. The segregation is ca

  9. Atomistic and Coarse-grained Simulations of Hexabenzocoronene Crystals

    Science.gov (United States)

    Ziogos, G.; Megariotis, G.; Theodorou, D. N.

    2016-08-01

    This study concerns atomistic and coarse-grained Molecular Dynamics simulations of pristine hexabenzocoronene (HBC) molecular crystals. HBC is a symmetric graphene flake of nanometric size that falls in the category of polyaromatic hydrocarbons, finding numerous applications in the field of organic electronics. The HBC molecule is simulated in its crystalline phase initially by means of an all-atom representation, where the molecules self- organize into well aligned molecular stacks, which in turn create a perfect monoclinic molecular crystal. The atomistic model reproduces fairly well the structural experimental properties and thus can be used as a reliable starting point for the development of a coarsegrained model following a bottom-up approach. The coarse-grained model is developed by applying Iterative Boltzmann Inversion, a systematic coarse-graining method which reproduces a set of target atomistic radial distribution functions and intramolecular distributions at the coarser level of description. This model allows the simulation of HBC crystals over longer time and length scales. The crystalline phase is analyzed in terms of the Saupe tensor and thermomechanical properties are probed at the atomistic level.

  10. Grain Constraint and Size Effects in Shape Memory Alloy Microwires

    Science.gov (United States)

    Ueland, Stian Melhus

    Shape memory alloys exhibit interesting and useful properties, such as the shape memory effect and superelasticity. Among the many alloy families that have been shown to exhibit shape memory properties the ones based on copper are interesting because they are relatively inexpensive and show excellent properties when made as single crystals. However, the performance ofthese alloys is severely compromised by the introduction of grain boundaries, to the point where they are too poor for commercial applications. This thesis studies the mechanical properties of fine Cobased wires with a bamboo microstructure, i.e., where triple junctions are absent and grain boundaries run perpendicular to the wire axis. These microwires are not single crystals, but their microstructure is not as complex as that of polycrystals either: we call this new class of shape memory alloys oligocrystals. This thesis seeks to better understand the relationship between microstructure and properties in these alloys through a combination of mechanical testing, in situ experiments and modeling. First, in situ scanning electron microscopy, together with finite element modeling, is used to understand the role of grain constraint on the martensitic transformation. Grain constraints are observed to be much less severe in oligocrystalline wires as compared to polycrystals. Oligocrystalline microwires are then thermomechanically tested and shown to exhibit excellent properties that approach those of single crystals. Next, property evolution during cycling is investigated, revealing training effects as well as fatigue life and fracture. Finally, size effects in damping and transformation morphology are studied and it is shown that a transition from a many-domain to a single domain martensite morphology takes place when the wire diameter is decreased. (Copies available exclusively from MIT Libraries, libraries.mit.edu/docs - docs@mit.edu)

  11. Simulation of grain size effects in nanocrystalline shape memory alloys

    Science.gov (United States)

    Ahluwalia, Rajeev; Quek, Siu Sin; Wu, David T.

    2015-06-01

    Recently, it has been demonstrated that martensitic transformation in nanocrystalline shape memory alloys can be suppressed for small grain sizes. Motivated by these results, we study the grain size dependence of martensitic transformations and stress-strain response of nanocrystalline shape memory alloys within the framework of the Ginzburg-Landau (GL) theory. A GL model for a square to rectangle transformation in polycrystals is extended to account for grain boundary effects. We propose that an inhibition of the transformation in grain boundary regions can occur, if the grain boundary energy of the martensite is higher than that of the austenite phase. We show that this inhibition of transformation in grain boundary regions has a strong influence on domain patterns inside grains. Although the transformation is inhibited only at the grain boundaries, it leads to a suppression of the transformation even inside the grains as grain size is decreased. In fact, below a critical grain size, the transformation can be completely suppressed. We explain these results in terms of the extra strain gradient cost associated with grain boundaries, when the transformation is inhibited at grain boundaries. On the other hand, no significant size effects are observed when transformation is not inhibited at grain boundaries. We also study the grain size dependence of the stress strain curve. It is found that when the transformation is inhibited at grain boundaries, a significant reduction in the hysteresis associated with stress-strain curves during the loading-unloading cycles is observed. The hysteresis for this situation reduces even further as the grain size is reduced, which is consistent with recent experiments. The simulations also demonstrate that the mechanical behavior is influenced by inter-granular interactions and the local microstructural neighbourhood of a grain has a stronger influence than the orientation of the grain itself.

  12. Electrospray crystallization for high-quality submicron-sized crystals

    NARCIS (Netherlands)

    Radacsi, N.; Stankiewicz, A.I.; Creyghton, Y.L.M.; Heijden, A.E.D.M. van der; Horst, J.H. ter

    2011-01-01

    Nano- and submicron-sized crystals are too small to contain inclusions and are, therefore, expected to have a higher internal quality compared to conventionally sized particles (several tens to hundreds of microns). Using electrospray crystallization, nano- and submicron-sized crystals can be easily

  13. Effect of CuO on Crystal Grain Size and Crystal Structure of C3S%CuO对C3S亚晶尺寸及晶型的影响

    Institute of Scientific and Technical Information of China (English)

    石立安; 柯凯

    2012-01-01

    Polymorphism of tricalcium silicate were prepared using Ca( OH)2 and SiO2 as crude materials and CuO as doping agent by calcination method. The influences of CuO agent on tricalcium silicate phase polymorphism transformation proeess and grains growth were studied wilh phase diagram analysis, XRD, IR and MDI jade 5. 0 sofeware. The results showed that; according to phase analysis of CaO-CuO and CuO-SiO2, CuO accelerated solid reaction of CaO-SiO2; when added CuO addition, the crystal form and partieles growth were both effected. When CuO addition was below 1. 5% , the reducing tendency of C3S grain growth was prominent; if the addtion exceed 1.5%, the reducing tendency become slow, and crystal form changed from T to R when adding,but when the addition exceed 2.0% , R form change hack to M1. From IR analysis, the symmetrical eharateristic of C3S crystal increased through observation of the spectral at 818 cm-1 and 999 cm-1 fade and appear, and the advection increment and decrease of dilation-libration at 497 cm-1 .%以Ca(OH)2、SiO2化学纯为原料,分别掺人不同质量分数的CuO制备不同晶型组成的C3S,运用相图分析、XRD、IR测试方法及MDI jade5.0软件对C3S亚晶生长、晶型转变过程进行研究.结果表明:由CaO-CuO、CuO-SiO2二元相图分析,CuO促进CaO-SiO2固相反应效应明显;C3S经CuO掺杂后,其晶型转变和亚晶成长均受到影响.当CuO掺量小于1.5%时,C3S亚晶尺寸减小趋势明显,大于1.5%时,减小趋势减缓.且C3S晶型随掺量变化先由T型向R型转换,但掺量大于2.0%时,R型又逐步转换为M1型.同时IR分析表明,818cm-1、999cm-1谱带处的先减弱后增强及497 cm-1伸缩振动平移先增大后减小,均说明C3S晶体对称性先增大后减小的变化趋势.

  14. Prediction of HAZ grain size in welding of ultra fine grained steel with different parameters

    Institute of Scientific and Technical Information of China (English)

    Zhao Hongyun; Zhang Hongtao; Li Dongqing; Wang Guodong

    2010-01-01

    The temperature field and thermal cycling curve in the heat-affected zone during welding 400 MPa ultra fine grained steel by plasma arc were simulated using finite element method.The principle of grain growth kinetics was used to predict the grain size in the heat-affected zone under different welding parameters.The simulation results show that the growing tendency of HAZ grain could be controlled by adjusting the welding parameters,but the growth of HAZ grain could not be eliminated at all.The HAZ grain size became small with increasing of the cooling rate and added with increasing of welding current,arc voltage and welding speed.

  15. Size modification of recent pollen grains under different treatments

    NARCIS (Netherlands)

    Reitsma, Tj.

    1969-01-01

    The effect of various chemicals on the size of recent pollen grains of Corylus avellana L. and Quercus robur L. was studied. The size of acetolysed grains was affected by the treatment prior to acetolysis and moreover by the duration of acetolysis. Preparation methods, which produce comparable sizes

  16. Size modification of recent pollen grains under different treatments

    NARCIS (Netherlands)

    Reitsma, Tj.

    1969-01-01

    The effect of various chemicals on the size of recent pollen grains of Corylus avellana L. and Quercus robur L. was studied. The size of acetolysed grains was affected by the treatment prior to acetolysis and moreover by the duration of acetolysis. Preparation methods, which produce comparable sizes

  17. Analysis of EBSD Grain Size Measurements Using Microstructure Simulations and a Customizable Pattern Matching Library for Grain PerimeterEstimation (Postprint)

    Science.gov (United States)

    2017-03-08

    member of grain #1. The crystal misorientation between the seed point and its neighbors is checked, and it is assumed that the adjacent pixel is a member...than circles, and whether the performance is a function of grain size dispersion . The EBSD technique-specific ASTM standard, E2627,[17] generally builds...of realistic looking microstructures with varied grain size dispersions and the ability to apply different pixel sampling resolutions to instances of

  18. Grain Size Dependence of Uniform Elongation in Single-Phase FCC/BCC Metals

    Science.gov (United States)

    Liu, Haiting; Shen, Yao; Ma, Jiawei; Zheng, Pengfei; Zhang, Lei

    2016-09-01

    We studied the dependence of uniform elongation on grain size in the range of submicron to millimeter for single-phase FCC/BCC metals by reviewing recent experimental results and applying crystal plasticity finite element method simulation. In the order of increasing grain size, uniform elongation can be divided into three stages, namely low elongation stage, nearly constant elongation stage, and decreased elongation with large scatters stage. Low elongation stage features a dramatic increase near the critical grain size at the end of the stage, which is primarily attributed to the emergence of dislocation cell size transition from ultrafine to mid-size grain. Other factors can be neglected due to their negligible influence on overall variation trend. In nearly constant elongation stage, uniform elongation remains unchanged at a high level in general. As grain size keeps growing, uniform elongation starts decreasing and becomes scattered upon a certain grain size, indicating the initiation of decreased elongation with large scatters stage. It is shown that the increase is not linear or smooth but rather sharp at the end of low elongation stage, leading to a wider range in nearly constant elongation stage. The grain size dependence of uniform elongation can serve as a guiding principle for designing small uniaxial tensile specimens for mechanical testing, where size effect matters in most cases.

  19. Effect of Grain Size on the Threshold Voltage for Double-Gate Polycrystaline Silicon MOSFET

    Directory of Open Access Journals (Sweden)

    Alka Panwar

    2011-01-01

    Full Text Available The effect of grain size (D on the threshold voltage (Vth for double gate polycrystalline silicon MOSFET is investigated theoretically in terms of grain boundary trap states (NT. It is found that the threshold voltage (Vth increases non-linearly with increasing silicon-oxide thickness (tox for all values of grain size (D. However the threshold voltage is seen to have smaller values for same tox for the larger grains. This may be attributed to the reduction in the number of trap states in the depletion regions on either side of a grain boundary. Finally the dependence of threshold voltage (Vth on various parameters such as the doping concentration, interface trap state density and field penetration from drain to source are explored out. The results of these findings are in good agreement with those available in the literature. For large grain poly silicon MOSFET the threshold voltage is seen to approach the single crystal value.

  20. Austenite and ferrite grain size evolution in plain carbon steel

    Energy Technology Data Exchange (ETDEWEB)

    Militzer, M.; Giumelli, A.; Hawbolt, E.B.; Meadowcroft, T.R. [British Columbia Univ., Vancouver, BC (Canada)

    1995-01-01

    Grain size evolution in a 0.17%C, 0.74%Mn plain carbon steel is investigated using a Gleeble 1500 thermomechanical simulator. Austenite grain growth measurements in the temperature range from 900 to 1150{degrees}C have been used to validate the Abbruzzese and Luecke model, which is recommended for simulating grain growth during reheating. For run-out table conditions, the ferrite grain size decreases from 1l{mu}m to 4{mu}m when the cooling rate from the austenite is increased from 1 to 80{degrees}C/s.

  1. Crystal plasticity and grain crushing in high-porosity rocks

    Science.gov (United States)

    Rahmani, H.; Tjioe, M.; Borja, R. I.

    2012-12-01

    Previous studies show the significance of considering microstructure of individual crystals in modeling the inelastic behavior of high-porosity rocks. Plastic deformation of high-porosity crystalline rocks, exemplified by limestone, is mainly attributed to crystal plasticity and cataclastic flow. Crystal plasticity is defined as the plastic deformation along potential slip systems within the crystal lattice. In the context of continuum mechanics this micro-mechanism is modeled by a nonlinear relationship between stresses and strains. Two types of nonlinearity characterize the inelastic behavior of the crystal grains: material nonlinearity and geometric nonlinearity. Material nonlinearity defines the changes in stiffness matrix due to plastic slip along slip systems. Geometric nonlinearity contributes to the changes in stiffness matrix due to changes in the geometry of the crystal grains. Geometric nonlinearity is modeled using theory of finite deformation, which assumes the geometry of slip systems to be a function of crystal deformation. This type of nonlinearity is very important in modeling crystal deformation mainly because of plastic spin induced by anisotropy in the crystal structure. However, considering the geometry of slip systems as a function of crystal slip makes the equations highly nonlinear. As a result, many studies either ignore geometric nonlinearity or make other assumptions to simplify the equations. Cataclastic flow, on the other hand, is characterized by pervasive grain crushing in which larger grains are converted into smaller ones. We model cataclastic flow as strong discontinuity in the grain scale via an assumed enhanced strain method formulated within the context of nonlinear finite elements. The method allows the individual finite elements, identified to be in critical condition, to break into two pieces along a plane identified by theory of bifurcation. We show that modeling cataclastic flow combined with finite deformation crystal

  2. Nano-Sized Grain Refinement Using Friction Stir Processing

    Science.gov (United States)

    2013-03-01

    friction stir weld is a very fine grain microstructure produced as a result of dynamic recrystallization. The friction stir ... Friction Stir Processing, Magnesium, Nano-size grains Abstract A key characteristic of a friction stir weld is a very fine grain microstructure...state process developed on the basis of the friction stir welding (FSW) technique invented by The Welding Institute (TWI) in 1991 [2]. During

  3. Inhibition effect of phosphate on the crystal grain growth of nanosized titania

    Institute of Scientific and Technical Information of China (English)

    FENG Xiaohui; LIE Jingze; LI Ping; ZHANG Yanfeng; WEI Yu

    2009-01-01

    The inhibitory effect of phosphate on the crystal grain growth of nanosized titania during high temperature calcination was investigated. Nanosized titanium dioxide powders prepared by hydrolysis of titanium tetrachloride were soaked in phosphate solutions with different con-centrations. The obtained powders calcined at various temperatures were characterized by X-ray diffraction (XRD), Fourier transform infra-red spectroscopy (FTIR), and X-ray photoelectronic spectroscopy (XPS). The grain size of the samples without phosphate treatment in-creased quickly when calcined at high temperatures, while the grain size of the samples with phosphate modification increased slowly when calcined at the same temperature. This phenomenon implies that phosphate treatment plays an important role in inhibiting the crystal grain growth of titania. The possible mechanism of the inhibition effect of phosphate on titania is discussed.

  4. GRAIN SIZE CONSTRAINTS ON HL TAU WITH POLARIZATION SIGNATURE

    Energy Technology Data Exchange (ETDEWEB)

    Kataoka, Akimasa; Dullemond, Cornelis P [Zentrum für Astronomie der Universität Heidelberg, Institut für Theoretische Astrophysik, Albert-Ueberle-Str. 2, D-69120 Heidelberg (Germany); Muto, Takayuki [Division of Liberal Arts, Kogakuin University, 1-24-2 Nishi-Shinjuku, Shinjuku-ku, Tokyo 163-8677 (Japan); Momose, Munetake; Tsukagoshi, Takashi, E-mail: kataoka@uni-heidelberg.de [College of Science, Ibaraki University, 2-1-1 Bunkyo, Mito, Ibaraki 310-8512 (Japan)

    2016-03-20

    The millimeter-wave polarization of the protoplanetary disk around HL Tau has been interpreted as the emission from elongated dust grains aligned with the magnetic field in the disk. However, the self-scattering of thermal dust emission may also explain the observed millimeter-wave polarization. In this paper, we report a modeling of the millimeter-wave polarization of the HL Tau disk with the self-polarization. Dust grains are assumed to be spherical and to have a power-law size distribution. We change the maximum grain size with a fixed dust composition in a fixed disk model to find the grain size to reproduce the observed signature. We find that the direction of the polarization vectors and the polarization degree can be explained with the self-scattering. Moreover, the polarization degree can be explained only if the maximum grain size is ∼150 μm. The obtained grain size from the polarization is different from that which has been previously expected from the spectral index of the dust opacity coefficient (a millimeter or larger) if the emission is optically thin. We discuss that porous dust aggregates may solve the inconsistency of the maximum grain size between the two constraints.

  5. Hard-core thinnings of germ-grain models with power-law grain sizes

    CERN Document Server

    Kuronen, Mikko

    2012-01-01

    Random sets with long-range dependence can be generated using a Boolean model with power-law grain sizes. We study thinnings of such Boolean models which have the hard-core property that no grains overlap in the resulting germ-grain model. A fundamental question is whether long-range dependence is preserved under such thinnings. To answer this question we study four natural thinnings of a Poisson germ-grain model where the grains are spheres with a regularly varying size distribution. We show that a thinning which favors large grains preserves the slow correlation decay of the original model, whereas a thinning which favors small grains does not. Our most interesting finding concerns the case where only disjoint grains are retained, which corresponds to the well-known Mat\\'ern type I thinning. In the resulting germ-grain model, typical grains have exponentially small sizes, but rather surprisingly, the long-range dependence property is still present. As a byproduct, we obtain new mechanisms for generating hom...

  6. Grain size effects on He bubbles distribution and evolution

    Energy Technology Data Exchange (ETDEWEB)

    Wang, J. [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); School of Physical Science and Technology, Lanzhou University, Lanzhou 730000 (China); Gao, X.; Gao, N. [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); Wang, Z.G., E-mail: zhgwang@impcas.ac.cn [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); Cui, M.H.; Wei, K.F.; Yao, C.F.; Sun, J.R.; Li, B.S.; Zhu, Y.B.; Pang, L.L. [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); Li, Y.F. [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); School of Physical Science and Technology, Lanzhou University, Lanzhou 730000 (China); Wang, D. [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Xie, E.Q. [School of Physical Science and Technology, Lanzhou University, Lanzhou 730000 (China)

    2015-02-15

    Highlights: • SMAT treated T91 and conventional T91 were implanted by 200 keV He{sup 2+} to 1 × 10{sup 21} He m{sup −2} at room temperature and annealed at 450 °C for 3.5 h. • He bubbles in nanometer-size-grained T91 are smaller in as-implanted case. • The bubbles in the matrix of nanograins were hard to detect and those along the nanograin boundaries coalesced and filled with the grain boundaries after annealing. • Brownian motion and coalescence and Ostwald ripening process might lead to bubbles morphology presented in the nanometer-size-grained T91 after annealing. - Abstract: Grain boundary and grain size effects on He bubble distribution and evolution were investigated by He implantation into nanometer-size-grained T91 obtained by Surface Mechanical Attrition Treatment (SMAT) and the conventional coarse-grained T91. It was found that bubbles in the nanometer-size-grained T91 were smaller than those in the conventional coarse-grained T91 in as-implanted case, and bubbles in the matrix of nanograins were undetectable while those at nanograin boundaries (GBs) coalesced and filled in GBs after heat treatment. These results suggested that the grain size of structural material should be larger than the mean free path of bubble’s Brownian motion and/or denuded zone around GBs in order to prevent bubbles accumulation at GBs, and multiple instead of one type of defects should be introduced into structural materials to effectively reduce the susceptibility of materials to He embrittlement and improve the irradiation tolerance of structural materials.

  7. A new look at grain size and load effects in the hardness of ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Krell, A. [Fraunhofer-Institut fuer Keramische Technologien und Sinterwerkstoffe (IKTS), Dresden (Germany)

    1998-05-01

    A simple model describes the load effect (size effect) in the hardness, assuming an increasing microplastic deformability, when the further extension of the plastic zone growth and multiplication of pre-existing elements of plasticity are more effective than the generation of new dislocations or twins in the virgin material around the indentation site. The model explains experiments with sintered alumina which indicate a reduced load effect in increasingly fine-grained microstructures due to a grain size effect that is more pronounced at higher testing loads (larger indents) than in the microhardness range. A large difference between the hardness of plastically deformed volumes in single crystals and in polycrystalline microstructures consisting of grains with the same size, respectively, reveals a substantial contribution of the grain boundaries to plastic deformation at the indentation site even at room temperature and even for coarser microstructures. (orig.) 18 refs.

  8. The MAFLA (Mississippi, Alabama, Florida) Study, Grain Size Analyses

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The MAFLA (Mississippi, Alabama, Florida) Study was funded by NOAA as part of the Outer Continental Shelf Program. Dr. L.J. Doyle produced grain size analyses in the...

  9. Skaergaard vs Sudbury: Solidification Times and Crystal Sizes

    Science.gov (United States)

    Marsh, B. D.; Mittal, T.; Currier, R. M.; Jordon, E.

    2010-12-01

    The overall cooling time of a batch of magma is intimately reflected in the nature of the crystal sizes. The thinner are dikes and sills the finer grained are the crystals they display. And the spatial variations in crystal size and abundance record the spatial progression of solidification. Chilled margins are fine grained because of rapid solidification, and a progressive inward increase in crystal size is perfectly predictable by coupling a law of crystal growth with a suitable solidification front-based cooling model. When observed crystal sizes are much larger than predicted, as in finding phenocrysts near or in chilled margins, this is a clear indication of crystals grown and entrained prior to final emplacement and solidification. This is exactly the process exhibited by volcanics carrying swarms of large crystals. But in plutonic rocks there is frequent confusion over what crystal sizes to expect, especially when the pluton size and shape is poorly known, and there is often an unexpressed feeling that fine grained (i.e., non-phenocryst bearing) bodies almost regardless of size somehow cool fundamentally different than large bodies, especially layered intrusions. An invaluable standard state body to which to compare the crystal sizes of other large bodies is the Sudbury impact melt sheet. Formed in a few minutes, the 3km thick 200 km wide superheated melt sheet cooled and crystallized to produce a systematic and predictable internal variation in crystal size and abundance (Zieg & Marsh, 2002, JPet). Buried by 3km of fallback debris, the sheet took about 100,000 to solidify. The Skaergaard intrusion is of a similar thickness (3.4-4 km), but is much less extensive, being more like a thin-edged elliptical laccolith (Norton et. al., 1984, JGR) or a fault-bounded loaf of bread (7.75 x 10.55 x 3.7 km; Nielsen, 2004, JPet). In spite of its limited extent, the extent is large enough for solidification of the thickest parts time to approach that of an infinite sheet

  10. The optimum grain size for minimizing energy losses in iron

    Energy Technology Data Exchange (ETDEWEB)

    Campos, M.F. de [Escola de Engenharia Industrial Metalurgica de Volta Redonda/Universidade Federal Fluminense Av. dos Trabalhadores 420, Vila Santa Cecilia, 27255-125, Volta Redonda, RJ (Brazil)]. E-mail: mcampos@metal.eeimvr.uff.br; Teixeira, J.C. [Instituto de Pesquisas Tecnologicas do Estado de Sao Paulo, Av. Prof. Almeida Prado 532, 05508-901, Sao Paulo, SP (Brazil); Landgraf, F.J.G. [Instituto de Pesquisas Tecnologicas do Estado de Sao Paulo, Av. Prof. Almeida Prado 532, 05508-901, Sao Paulo, SP (Brazil)]. E-mail: landgraf@ipt.br

    2006-06-15

    A model able to predict the optimum grain size for textured electrical steels used in motors or transformers is presented. The model is based on the Pry and Bean model for the anomalous losses. The validity of the model is restricted to the frequency range of 1-1000 Hz. The model predicts that the optimum grain size decreases as: resistivity decreases or frequency increases or thickness of steel sheet increases. The predictions of the model are compared with experimental results.

  11. Activation of Big Grain1 significantly improves grain size by regulating auxin transport in rice.

    Science.gov (United States)

    Liu, Linchuan; Tong, Hongning; Xiao, Yunhua; Che, Ronghui; Xu, Fan; Hu, Bin; Liang, Chengzhen; Chu, Jinfang; Li, Jiayang; Chu, Chengcai

    2015-09-01

    Grain size is one of the key factors determining grain yield. However, it remains largely unknown how grain size is regulated by developmental signals. Here, we report the identification and characterization of a dominant mutant big grain1 (Bg1-D) that shows an extra-large grain phenotype from our rice T-DNA insertion population. Overexpression of BG1 leads to significantly increased grain size, and the severe lines exhibit obviously perturbed gravitropism. In addition, the mutant has increased sensitivities to both auxin and N-1-naphthylphthalamic acid, an auxin transport inhibitor, whereas knockdown of BG1 results in decreased sensitivities and smaller grains. Moreover, BG1 is specifically induced by auxin treatment, preferentially expresses in the vascular tissue of culms and young panicles, and encodes a novel membrane-localized protein, strongly suggesting its role in regulating auxin transport. Consistent with this finding, the mutant has increased auxin basipetal transport and altered auxin distribution, whereas the knockdown plants have decreased auxin transport. Manipulation of BG1 in both rice and Arabidopsis can enhance plant biomass, seed weight, and yield. Taking these data together, we identify a novel positive regulator of auxin response and transport in a crop plant and demonstrate its role in regulating grain size, thus illuminating a new strategy to improve plant productivity.

  12. On the maximum grain size entrained by photoevaporative winds

    CERN Document Server

    Hutchison, Mark A; Maddison, Sarah T

    2016-01-01

    We model the behaviour of dust grains entrained by photoevaporation-driven winds from protoplanetary discs assuming a non-rotating, plane-parallel disc. We obtain an analytic expression for the maximum entrainable grain size in extreme-UV radiation-driven winds, which we demonstrate to be proportional to the mass loss rate of the disc. When compared with our hydrodynamic simulations, the model reproduces almost all of the wind properties for the gas and dust. In typical turbulent discs, the entrained grain sizes in the wind are smaller than the theoretical maximum everywhere but the inner disc due to dust settling.

  13. Size Effect in Tension Perpendicular to Grain

    DEFF Research Database (Denmark)

    Astrup, Thomas; Clorius, Christian Odin; Hoffmeyer, Preben;

    2004-01-01

    The strength of wood is reduced when the stressed volume is increased. The phenomenon is termed size effect and is often explained as being stochastic in the sense that the probability of weak locations occurring in the wood increases with increased volume. This paper presents a hypothesis where ...

  14. Effect of grain size of polycrystalline diamond on its heat spreading properties

    Science.gov (United States)

    Simon, Roland B.; Anaya, Julian; Faili, Firooz; Balmer, Richard; Williams, Gruffudd T.; Twitchen, Daniel J.; Kuball, Martin

    2016-06-01

    The exceptionally high thermal conductivity of polycrystalline diamond (>2000 W m-1 K-1) makes it a very attractive material for optimizing the thermal management of high-power devices. In this paper, the thermal conductivity of a diamond sample capturing grain size evolution from nucleation towards the growth surface is studied using an optimized 3ω technique. The thermal conductivity is found to decrease with decreasing grain size, which is in good agreement with theory. These results clearly reveal the minimum film thickness and polishing thickness from nucleation needed to achieve single-crystal diamond performance, and thus enable production of an optimal polycrystalline diamond for heat-spreading applications.

  15. A coarse-grained model for PETN crystals

    Energy Technology Data Exchange (ETDEWEB)

    Gee, R; Wu, C; Maiti, A

    2006-02-10

    Using the energetic material Pentaerythritol Tetranitrate (PETN) as a specific example of molecular crystal, we describe the development of a simple coarse-graining procedure by grouping several atoms or whole functional groups into single charge-neutral beads. As compared to fully atomistic calculations the coarse-grained model speeds up simulations by more than two orders of magnitude. Yet, by adjusting only two parameters in the coarse-grained interaction, the model accurately predicts the lattice constants, sublimation energy, pressure-volume curve up to P=10 GPa, and energetically the most stable facets. Computed surface and desorption energies, bulk modulus, and equilibrium morphology are reported as well.

  16. Radiation pressure on fluffy submicron-sized grains

    CERN Document Server

    Silsbee, Kedron

    2015-01-01

    We investigate the claim that the ratio {\\beta} of radiation pressure force to gravitational force on a dust grain in our solar system can substantially exceed unity for some grain sizes, provided that grain porosity is high enough. For model grains consisting of random aggregates of silicate spherules, we find that the maximum value of {\\beta} is almost independent of grain porosity, but for small (<0.3 {\\mu}m) grains, {\\beta} actually decreases with increasing porosity. These results affect the interpretation of the grain trajectories estimated from the Stardust mission, which were modeled assuming {\\beta} values exceeding one. We find that radiation pressure effects are not large enough for particles Orion and Hylabrook captured by Stardust to be of interstellar origin given their reported impact velocities. We also investigate the effect of metallic iron inclusions in the dust grains, and find that metallic iron will increase {\\beta}, but at least half the grain (by mass) must be iron in order to raise...

  17. Novel ultrafine grain size processing of soft magnetic materials.

    Energy Technology Data Exchange (ETDEWEB)

    Michael, Joseph Richard; Robino, Charles Victor

    2009-01-01

    High performance soft magnetic alloys are used in solenoids in a wide variety of applications. These designs are currently being driven to provide more margin, reliability, and functionality through component size reductions; thereby providing greater power to drive ratio margins as well as decreases in volume and power requirements. In an effort to produce soft magnetic materials with improved properties, we have conducted an initial examination of one potential route for producing ultrafine grain sizes in the 49Fe-49Co-2V alloy. The approach was based on a known method for the production of very fine grain sizes in steels, and consisted of repeated, rapid phase transformation cycling through the ferrite to austenite transformation temperature range. The results of this initial attempt to produce highly refined grain sizes in 49Fe-49Co-2V were successful in that appreciable reductions in grain size were realized. The as-received grain size was 15 {micro}m with a standard deviation of 9.5 {micro}m. For the temperature cycling conditions examined, grain refinement appears to saturate after approximately ten cycles at a grain size of 6 {micro}m with standard deviation of 4 {micro}m. The process also reduces the range of grain sizes present in these samples as the largest grain noted in the as received and treated conditions were 64 and 26 {micro}m, respectively. The results were, however, complicated by the formation of an unexpected secondary ferritic constituent and considerable effort was directed at characterizing this phase. The analysis indicates that the phase is a V-rich ferrite, known as {alpha}{sub 2}, that forms due to an imbalance in the partitioning of vanadium during the heating and cooling portions of the thermal cycle. Considerable but unsuccessful effort was also directed at understanding the conditions under which this phase forms, since it is conceivable that this phase restricts the degree to which the grains can be refined. Due to this difficulty

  18. Strong crystal size effect on deformation twinning

    DEFF Research Database (Denmark)

    Yu, Qian; Shan, Zhi-Wei; Li, Ju

    2010-01-01

    find that the stress required for deformation twinning increases drastically with decreasing sample size of a titanium alloy single crystal7, 8, until the sample size is reduced to one micrometre, below which the deformation twinning is entirely replaced by less correlated, ordinary dislocation....... The sample size in transition is relatively large and easily accessible in experiments, making our understanding of size dependence11, 12, 13, 14, 15, 16, 17 relevant for applications....

  19. A Model for Evaluation of Grain Sizes of Aluminum Alloys with Grain Refinement Additions

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Based on the assumption that the nucleation substrates are activated by constitutional undercooling generated by an adjacent grain growth and solute distribution during the initial solidification, a model for calculation of the grain size of aluminum alloys with the grain refinement is developed, where the nucleation is dominated by two parameters, I.e. Growth restriction factor Q and the undercooling parameter P. The growth restriction factor Q is proportional to the initial rate of constitutional undercooling development and can be used directly as a criterion of the grain refinement in the alloys with strong potential nucleation particles. The undercooling parameter P can be regarded as the maximum of constitutional undercooling △TC. For weak potential nucleation particles, the use of RGS would be more accurate. The experimental data of the grain refinement of pure aluminum and AISi7 alloys are coincident predicted results with the model.

  20. Effects of grain size evolution on mantle dynamics

    Science.gov (United States)

    Schulz, Falko; Tosi, Nicola; Plesa, Ana-Catalina; Breuer, Doris

    2016-04-01

    The rheology of planetary mantle materials is strongly dependent on temperature, pressure, strain-rate, and grain size. In particular, the rheology of olivine, the most abundant mineral of the Earth's upper mantle, has been extensively studied in the laboratory (e.g., Karato and Wu, 1993; Hirth and Kohlstedt, 2003). Two main mechanisms control olivine's deformation: dislocation and diffusion creep. While the former implies a power-law dependence of the viscosity on the strain-rate that leads to a non-Newtonian behaviour, the latter is sensitively dependent on the grain size. The dynamics of planetary interiors is locally controlled by the deformation mechanism that delivers the lowest viscosity. Models of the dynamics and evolution of planetary mantles should thus be capable to self-consistently distinguish which of the two mechanisms dominates at given conditions of temperature, pressure, strain-rate and grain size. As the grain size can affect the viscosity associated with diffusion creep by several orders of magnitude, it can strongly influence the dominant deformation mechanism. The vast majority of numerical, global-scale models of mantle convection, however, are based on the use of a linear diffusion-creep rheology with constant grain-size. Nevertheless, in recent studies, a new equation has been proposed to properly model the time-dependent evolution of the grain size (Austin and Evens, 2007; Rozel et al., 2010). We implemented this equation in our mantle convection code Gaia (Hüttig et al., 2013). In the framework of simple models of stagnant lid convection, we compared simulations based on the fully time-dependent equation of grain-size evolution with simulations based on its steady-state version. In addition, we tested a number of different parameters in order to identify those that affects the grain size to the first order and, in turn, control the conditions at which mantle deformation is dominated by diffusion or dislocation creep. References Austin

  1. Solidification of Suspended Sediments with Two Characteristic Grain Sizes

    Science.gov (United States)

    Zarski, G.; Borja, R. I.

    2010-12-01

    We use mixture theory to formulate the problem of solidification of sediments with two characteristic grain sizes in a suspension. The formulation involves a mixture of larger grains in a thick fluid, where the thick fluid is a mixture of smaller particles in a host fluid. This mixture within a mixture description resembles a double porosity representation in unsaturated soil mechanics. Two independent variables of interest include the volume fraction of the larger grains relative to the total volume of the mixture, and the volume fraction of the smaller grains relative to the volume of the thick fluid. The two volume fractions are coupled by a constitutive law based on the Richardson-Zaki equation. The governing partial differential equations describing the settling velocities of the two solid groups are solved simultaneously in space and time using the finite element method.

  2. Consolidation of nanometer-sized aluminum single crystals: Microstructure and defects evolutions

    KAUST Repository

    Afify, N. D.

    2014-04-01

    Deriving bulk materials with ultra-high mechanical strength from nanometer-sized single metalic crystals depends on the consolidation procedure. We present an accurate molecular dynamics study to quantify microstructure responses to consolidation. Aluminum single crystals with an average size up to 10.7 nm were hydrostatically compressed at temperatures up to 900 K and pressures up to 5 GPa. The consolidated material developed an average grain size that grew exponentially with the consolidation temperature, with a growth rate dependent on the starting average grain size and the consolidation pressure. The evolution of the microstructure was accompanied by a significant reduction in the concentration of defects. The ratio of vacancies to dislocation cores decreased with the average grain size and then increased after reaching a critical average grain size. The deformation mechanisms of poly-crystalline metals can be better understood in the light of the current findings. © 2013 Elsevier B.V. All rights reserved.

  3. Grain size effect on the thermal-induced martensitic transformation in polycrystalline Cu-based shape memory alloys

    OpenAIRE

    la Roca, Paulo Matías; Isola, Lucio Manuel; Sobrero, Cesar Enrique; Vermaut, P.; Malarria, Jorge Alberto

    2016-01-01

    In Cu-based SMA alloys, the grain size (d) effect on the martensitic transformation temperature was investigated for a wide range of d. Specimens were prepared by different heat treatments in order to create a range of grain sizes, from about 500 nm (ribbons and tapes obtained by rapid solidification techniques) up to 6 mm diameter single-crystals (grown by the Bridgman method). Information obtained from the literature was also included in the set of analyzed experimental data. The reduction ...

  4. Colour characteristics of winter wheat grits of different grain size

    Directory of Open Access Journals (Sweden)

    Horváth Zs. H.

    2015-01-01

    Full Text Available Nowadays, wheat has spread all over the world due to its extensive usability. The colour of wheat grits is very important for the milling and baking industry because it determines the colour of the products made from it. The instrumental colour measuring is used, first of all, for durum wheat. We investigated the relationship between colour characteristics and grain size in the case of different hard aestivum wheats. We determined the colour using the CIE (Commission Internationale de l’Eclairage 1976 L*, a*, b* colour system measured by MINOLTA CR-300 tristimulus colorimeter. After screening the colour of the wheat fractions of different grain size, grits was measured wet and dry. We determined the L*, a*, b* colour co-ordinates and the whiteness index, too. To evaluate the values we had obtained, we used analysis of variance and regression analysis. We pointed out that the colour of wheat grits of different grain size is dependent on the hardness index of wheat. The lightness co-ordinate (L* of grits of the harder wheat is smaller, while a* and b* co-ordinates are higher. We also found that while grain size rises, the L* co-ordinate decreases and a*, b* values increase in the case of every type of wheat. The colour of grits is determined by the colour of fractions of 250-400 μm in size, independently from the average grain size. The whiteness index and the L* colour co-ordinate have a linear relation (R2 = 0.9151; so, the determination of whiteness index is not necessary. The L* value right characterizes the whiteness of grits.

  5. Mean grain size mapping with single-beam echo sounders

    NARCIS (Netherlands)

    Van Walree, P.A.; Ainslie, M.A.; Simons, D.G.

    2006-01-01

    Echo energies of single-beam echo sounders are inverted for the sediment mean grain size via a combination of theoretical and empirical relationships. In situ measurements of the seafloor mass density have revealed the presence of a thin transition layer between the water and the sediment. Within th

  6. Grain boundary migration and Zener pinning in particle-containing copper crystals

    Energy Technology Data Exchange (ETDEWEB)

    Humphreys, F.J.; Ardakani, M.G. [Univ. of Manchester (United Kingdom)

    1996-07-01

    Cu-Al single crystals have been partially internally oxidized to produce a microstructure which contains a dispersion of small Al{sub 2}O{sub 3} particles in part of a crystal, leaving the rest of the crystal single phase. After deformation and annealing, the single phase region recrystallizes readily, but in general the recrystallization front is halted at the single/two-phase interface. However, it is found that, at intermediate strains, grains with misorientations of {approximately}40{degree} about axes close to <111> with respect to the deformed matrix, may penetrate the two-phase region. The results are interpreted in terms of an orientation dependence of the particle pinning pressure (Zener drag), and the implications of this on the grain size and texture of heat treatable alloys are discussed.

  7. Grain Boundary Relaxation in Bi-Crystals: Mechanical Spectroscopy and Molecular Dynamics Simulations

    Directory of Open Access Journals (Sweden)

    Maier A.-K.

    2015-04-01

    Full Text Available Different Au-Ag-Cu samples have been studied by mechanical spectroscopy. Both polycrystals and bi-crystals show a relaxation peak at 800 K, accompanied by an elastic modulus change. Since this peak is absent in single crystals it is related to the presence of grain boundaries. Molecular dynamics simulations reveal two microscopic mechanisms, when a shear stress is applied onto a Σ5 grain boundary: at 700 K, the boundary migrates perpendicularly to the boundary plane under an external stress. At 1000 K, only sliding at the boundary is observed. These two mechanisms acting in different temperature intervals are used to model the mechanic response of a polycrystal under an applied stress. The models yield expressions for the relaxation strength Δ and for the relaxation time τ as a function of the grain size. A comparison with the mechanical spectroscopy measurements of polycrystals and the bi-crystals show that the grain boundary sliding model reproduces correctly the characteristics of the grain boundary peak.

  8. Grain Size Dependence of Exchange-Coupling Interaction between Magnetically Soft-Hard Grains and Effective Anisotropy

    Institute of Scientific and Technical Information of China (English)

    韩广兵; 高汝伟; 傅爽; 刘汉强; 冯维存; 陈伟

    2004-01-01

    Taking α-Fe and Nd2Fe14B grains as example, the grain size dependence of the exchange-coupling interaction and effective anisotropy and also their variations depending on the ratio of magnetically soft and hard grain sizes, Ds∶ Dh, were investigated. When grain size D>Lex, the grain's anisotropy is the statistic value of the coupled and uncoupled part. The anisotropy constant of uncoupled part is the common value K1 and that of coupled part varies with the distance to the grain surface. The effective anisotropy constant between magnetically soft and hard grains, Keff, can be expressed as the sum of the products of volume fractions for soft and hard grains, respectively, and the corresponding mean anisotropy constants. The calculation results indicate that the exchange-coupling interaction is enhanced with the reduction of grain size, and the effective anisotropy decreases with reducing grain size and increasing ratio of Ds∶ Dh. In order to get high effective anisotropy constant, Keff, in composite magnetically soft-hard grains, the hard grain size should be larger than 30 nm and the soft grain size should be about 10 nm.

  9. Influence of Substrate on Crystal Orientation of Large-Grained Si Thin Films Formed by Metal-Induced Crystallization

    Directory of Open Access Journals (Sweden)

    Kaoru Toko

    2015-01-01

    Full Text Available Producing large-grained polycrystalline Si (poly-Si film on glass substrates coated with conducting layers is essential for fabricating Si thin-film solar cells with high efficiency and low cost. We investigated how the choice of conducting underlayer affected the poly-Si layer formed on it by low-temperature (500°C Al-induced crystallization (AIC. The crystal orientation of the resulting poly-Si layer strongly depended on the underlayer material: (100 was preferred for Al-doped-ZnO (AZO and indium-tin-oxide (ITO; (111 was preferred for TiN. This result suggests Si heterogeneously nucleated on the underlayer. The average grain size of the poly-Si layer reached nearly 20 µm for the AZO and ITO samples and no less than 60 µm for the TiN sample. Thus, properly electing the underlayer material is essential in AIC and allows large-grained Si films to be formed at low temperatures with a set crystal orientation. These highly oriented Si layers with large grains appear promising for use as seed layers for Si light-absorption layers as well as for advanced functional materials.

  10. Size effect in tension perpendicular to the grain

    DEFF Research Database (Denmark)

    Pedersen, Martin Bo Uhre; Clorius, Christian Odin; Damkilde, Lars;

    1999-01-01

    The strength in tension perpendicular to the grain is known to decrease with an increase in the stressed volume. Usually this size effect is explained on a stochastic basis, that is an explanation relying on an increased probability of encountering a strength reducing flaw when the volume of the ...... that the size effect can be explained on a deterministic basis. Arguments for such a simple deterministic explanation of size effect is found in finite element modelling using the orthotropic stiffness characteristics in the transverse plane of wood....

  11. Quantifying the relative importance of flow regulation and grain size regulation of suspended sediment transport α and tracking changes in grain size of bed sediment β

    Science.gov (United States)

    Rubin, David M.; Topping, David J.

    2001-01-01

    To predict changes in sediment transport, it is essential to know whether transport is regulated mainly by changes in flow or by changes in grain size of sediment on the bed. In flows where changes in suspended sediment transport are regulated purely by changes in flow (grain size of bed sediment is constant), increases in flow strength cause increases in both concentration and grain size of sediment in suspension (because stronger flows are able to suspend more sediment and coarser grains). Under this constraint of constant grain size of bed sediment concentration and median diameter of suspended sediment are positively correlated. In contrast, where transport is regulated purely by changes in grain size of sediment on the bed, concentration and median diameter of suspended sediment are negatively correlated (because increasing the median diameter of the bed sediment causes the concentration to decrease while causing the median grain size in suspension to increase). Where both flow strength and grain size on the bed are free to vary, the relation between concentration and grain size in suspension can be used to quantify the importance of grain size regulation relative to flow regulation of sediment transport, a measure defined as α. To predict sediment transport in systems that are regulated dominantly by changes in grain size on the bed, it is more useful to measure sediment input events or changes in grain size on the bed than to measure changes in flow. More commonly, grain size of bed sediment may be secondary to flow in regulating transport but may, nevertheless, be important. The relative coarseness of bed sediment (β) can be measured directly or, like α, can be calculated from measurements of concentration and grain size of suspended sediment.

  12. Quantifying the relative importance of flow regulation and grain size regulation of suspended sediment transport a and tracking changes in grain size of bed sediment B

    Science.gov (United States)

    Rubin, David M.; Topping, David J.

    2001-01-01

    To predict changes in sediment transport, it is essential to know whether transport is regulated mainly by changes in flow or by changes in grain size of sediment on the bed. In flows where changes in suspended sediment transport are regulated purely by changes in flow (grain size of bed sediment is constant), increases in flow strength cause increases in both concentration and grain size of sediment in suspension (because stronger flows are able to suspend more sediment and coarser grains). Under this constraint of constant grain size of bed sediment concentration and median diameter of suspended sediment are positively correlated. In contrast, where transport is regulated purely by changes in grain size of sediment on the bed, concentration and median diameter of suspended sediment are negatively correlated (because increasing the median diameter of the bed sediment causes the concentration to decrease while causing the median grain size in suspension to increase). Where both flow strength and grain size on the bed are free to vary, the relation between concentration and grain size in suspension can be used to quantify the importance of grain size regulation relative to flow regulation of sediment transport, a measure defined as α. To predict sediment transport in systems that are regulated dominantly by changes in grain size on the bed, it is more useful to measure sediment input events or changes in grain size on the bed than to measure changes in flow. More commonly, grain size of bed sediment may be secondary to flow in regulating transport but may, nevertheless, be important. The relative coarseness of bed sediment (β) can be measured directly or, like α, can be calculated from measurements of concentration and grain size of suspended sediment.

  13. Study of surface cell Madelung constant and surface free energy of nanosized crystal grain

    Institute of Scientific and Technical Information of China (English)

    Zhang Wei-Jia; Wang Tian-Min; Rong Ai-Lun; Cui Min

    2006-01-01

    Surface cell Madelung constant is firstly defined for calculating the surface free energy of nanosized crystal grains,which explains the physical performance of small crystals and may be greatly beneficial to the analysis of surface states and the study of the dynamics of crystal nucleation and growth.A new approximative expression of the surface energy and relevant thermodynamic data are used in this calculation.New formula and computing method for calculating the Madelung constant α of any complex crystals are proposed,and the surface free energies and surface electrostatic energies of nanosized crystal grains and the Madelung constant of some complex crystals are theoretically calculated in this paper.The surface free energy of nanosized-crystal-grain TiO2 and the surface electrostatic energy (absolute value) of nanosized-crystal-grain α-A12O3 are found to be the biggest among all the crystal grains including those of other species.

  14. The dust grain size - stellar luminosity trend in debris discs

    CERN Document Server

    Pawellek, Nicole

    2015-01-01

    The cross section of material in debris discs is thought to be dominated by the smallest grains that can still stay in bound orbits despite the repelling action of stellar radiation pressure. Thus the minimum (and typical) grain size $s_\\text{min}$ is expected to be close to the radiation pressure blowout size $s_\\text{blow}$. Yet a recent analysis of a sample of Herschel-resolved debris discs showed the ratio $s_\\text{min}/s_\\text{blow}$ to systematically decrease with the stellar luminosity from about ten for solar-type stars to nearly unity in the discs around the most luminous A-type stars. Here we explore this trend in more detail, checking how significant it is and seeking to find possible explanations. We show that the trend is robust to variation of the composition and porosity of dust particles. For any assumed grain properties and stellar parameters, we suggest a recipe of how to estimate the "true" radius of a spatially unresolved debris disc, based solely on its spectral energy distribution. The r...

  15. Absorption Efficiencies of Forsterite. I: DDA Explorations in Grain Shape and Size

    Science.gov (United States)

    Lindsay, Sean S.; Wooden, Diane; Harker, David E.; Kelley, Michael S.; Woodward, Charles E.; Murphy, Jim R.

    2013-01-01

    We compute the absorption efficiency (Q(sub abs)) of forsterite using the discrete dipole approximation (DDA) in order to identify and describe what characteristics of crystal grain shape and size are important to the shape, peak location, and relative strength of spectral features in the 8 - 40 micron wavelength range. Using the DDSCAT code, we compute Q(sub abs) for non-spherical polyhedral grain shapes with a(sub eff) = 0.1 micron. The shape characteristics identified are: 1) elongation/reduction along one of three crystallographic axes; 2) asymmetry, such that all three crystallographic axes are of different lengths; and 3) the presence of crystalline faces that are not parallel to a specific crystallographic axis, e.g., non-rectangular prisms and (di)pyramids. Elongation/reduction dominates the locations and shapes of spectral features near 10, 11, 16, 23.5, 27, and 33.5 micron, while asymmetry and tips are secondary shape effects. Increasing grain sizes (0.1 - 1.0 micron) shifts the 10, 11 micron features systematically towards longer wavelengths and relative to the 11 micron feature increases the strengths and slightly broadens the longer wavelength features. Seven spectral shape classes are established for crystallographic a-, b-, and c-axes and include columnar and platelet shapes plus non-elongated or equant grain shapes. The spectral shape classes and the effects of grain size have practical application in identifying or excluding columnar, platelet or equant forsterite grain shapes in astrophysical environs. Identification of the shape characteristics of forsterite from 8 - 40 micron spectra provides a potential means to probe the temperatures at which forsterite formed.

  16. ABSORPTION EFFICIENCIES OF FORSTERITE. I. DISCRETE DIPOLE APPROXIMATION EXPLORATIONS IN GRAIN SHAPE AND SIZE

    Energy Technology Data Exchange (ETDEWEB)

    Lindsay, Sean S. [Department of Earth and Planetary Sciences, University of Tennessee, 1421 Circle Drive, Knoxville, TN 37996-2366 (United States); Wooden, Diane H. [Space Science Division, NASA Ames Research Center, MS 245-3, Moffett Field, CA 94035-0001 (United States); Harker, David E. [Center for Astrophysics and Space Sciences, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093-0424 (United States); Kelley, Michael S. [Department of Astronomy, University of Maryland, College Park, MD 20742 (United States); Woodward, Charles E. [Minnesota Institute of Astrophysics, 116 Church Street S. E., University of Minnesota, Minneapolis, MN 55455 (United States); Murphy, Jim R., E-mail: slindsay@utk.edu, E-mail: diane.h.wooden@nasa.gov, E-mail: dharker@uscd.edu, E-mail: msk@astro.umd.edu, E-mail: chelsea@astro.umn.edu, E-mail: murphy@nmsu.edu [Department of Astronomy, New Mexico State University, P.O. Box 30001, MSC 4500, Las Cruces, NM 88003-8001 (United States)

    2013-03-20

    We compute the absorption efficiency (Q{sub abs}) of forsterite using the discrete dipole approximation in order to identify and describe what characteristics of crystal grain shape and size are important to the shape, peak location, and relative strength of spectral features in the 8-40 {mu}m wavelength range. Using the DDSCAT code, we compute Q{sub abs} for non-spherical polyhedral grain shapes with a{sub eff} = 0.1 {mu}m. The shape characteristics identified are (1) elongation/reduction along one of three crystallographic axes; (2) asymmetry, such that all three crystallographic axes are of different lengths; and (3) the presence of crystalline faces that are not parallel to a specific crystallographic axis, e.g., non-rectangular prisms and (di)pyramids. Elongation/reduction dominates the locations and shapes of spectral features near 10, 11, 16, 23.5, 27, and 33.5 {mu}m, while asymmetry and tips are secondary shape effects. Increasing grain sizes (0.1-1.0 {mu}m) shifts the 10 and 11 {mu}m features systematically toward longer wavelengths and relative to the 11 {mu}m feature increases the strengths and slightly broadens the longer wavelength features. Seven spectral shape classes are established for crystallographic a-, b-, and c-axes and include columnar and platelet shapes plus non-elongated or equant grain shapes. The spectral shape classes and the effects of grain size have practical application in identifying or excluding columnar, platelet, or equant forsterite grain shapes in astrophysical environs. Identification of the shape characteristics of forsterite from 8 to 40 {mu}m spectra provides a potential means to probe the temperatures at which forsterite formed.

  17. Grain size control and superplasticity in 6013-type aluminum alloys

    Science.gov (United States)

    Troeger, Lillianne Plaster Whitelock

    Aluminum alloys have been the material of choice for aircraft construction since the 1930's. Currently, the automotive industry is also showing an increasing interest in aluminum alloys as structural materials. 6xxx aluminum alloys possess a combination of strength and formability which makes them attractive to both industries. In addition, 6xxx alloys are highly weldable, corrosion resistant, and low in cost as compared with the 2xxx and 7xxx aluminum alloys. Superplastic forming (SPF) is a manufacturing process which exploits the phenomenon of superplasticity in which gas pressure is used to form complex-shaped parts in a single forming operation. This reduces part counts and the need for fasteners and connectors, resulting in reduced product weight. Reduced product/vehicle weight improves fuel economy. Most alloys must be specially processed for superplasticity. Much research effort has been directed at the development of thermomechanical processes for the grain refinement of aluminum alloys by static or dynamic recrystallization. to induce superplasticity. While large numbers of studies have been conducted on 2xxx, 5xxx, 7xxx, and 8xxx aluminum alloys, very few studies have been focused on the grain refinement of 6xxx aluminum alloys for superplasticity. The current research describes a new thermomechanical process for application to 6xxx aluminum alloys for grain refinement and superplasticity. The process is shown to successfully refine and induce superplasticity in an Al-Mg-Si-Cu alloy which falls within the compositional limits of both 6013 and 6111. The grain refinement is by particle-stimulated nucleation of recrystallization. The microstructural evolution during the thermomechanical processing is characterized in terms of precipitate size, shape, distribution and composition; texture; recrystallization; and grain size, shape, and thermal stability. The new process produces a statically-stable, weakly-textured, equiaxed grain structure with an average

  18. Grain-to-Grain Variations in NbC Particle Size Distributions in an Austenitic Stainless Steel

    DEFF Research Database (Denmark)

    Barlow, Claire; Ralph, B.; Silverman, B.

    1979-01-01

    Quantitative information has been obtained concerning the size distributions of NbC precipitate particles in different grains in a deformed and aged austenitic stainless steel specimen. The precipitate size distributions obtained differ from one grain to another. The average disparity measured...... between the mean precipitate sizes was a function of the distance betwen the grains compared. The results obtained are considered in terms of differences in precipitation behaviour due to variations in the levels of plastic strain in constituent grains of the deformed specimen....

  19. Grain growth of cast-multicrystalline silicon grown from small randomly oriented seed crystal

    Science.gov (United States)

    Prakash, Ronit R.; Sekiguchi, Takashi; Jiptner, Karolin; Miyamura, Yoshiji; Chen, Jun; Harada, Hirofumi; Kakimoto, Koichi

    2014-09-01

    Multicrystalline silicon was grown from seeds with small grains of random orientation and the growth mechanism was studied with respect to grain size, shape, boundary character and orientation. The average grain size perpendicular to growth direction increased steadily initially, became constant and then increased steadily again. Grain size parallel to growth direction increased rapidly with growth due to grain elongation in the growth direction. Grain shape with respect to growth direction changed from spherical to columnar with growth. Initially non-CSL grain boundary fraction was very high but decreased with growth as the Σ3 grain boundary fraction increased. A simple model was proposed to explain the results.

  20. Calculated Grain Size-Dependent Vacancy Supersaturation and its Effect on Void Formation

    DEFF Research Database (Denmark)

    Singh, Bachu Narain; Foreman, A. J. E.

    1974-01-01

    In order to study the effect of grain size on void formation during high-energy electron irradiations, the steady-state point defect concentration and vacancy supersaturation profiles have been calculated for three-dimensional spherical grains up to three microns in size. In the calculations...... of vacancy supersaturation as a function of grain size, the effects of internal sink density and the dislocation preference for interstitial attraction have been included. The computations show that the level of vacancy supersaturation achieved in a grain decreases with decreasing grain size. The grain size...... dependence of the maximum vacancy supersaturation in the centre of the grains is found to be very similar to the grain size dependence of the maximum void number density and void volume swelling measured in the central regions of austenitic stainless steel grains. This agreement reinforces the interpretation...

  1. Mapping Snow Grain Size over Greenland from MODIS

    Science.gov (United States)

    Lyapustin, Alexei; Tedesco, Marco; Wang, Yujie; Kokhanovsky, Alexander

    2008-01-01

    This paper presents a new automatic algorithm to derive optical snow grain size (SGS) at 1 km resolution using Moderate Resolution Imaging Spectroradiometer (MODIS) measurements. Differently from previous approaches, snow grains are not assumed to be spherical but a fractal approach is used to account for their irregular shape. The retrieval is conceptually based on an analytical asymptotic radiative transfer model which predicts spectral bidirectional snow reflectance as a function of the grain size and ice absorption. The analytical form of solution leads to an explicit and fast retrieval algorithm. The time series analysis of derived SGS shows a good sensitivity to snow metamorphism, including melting and snow precipitation events. Preprocessing is performed by a Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm, which includes gridding MODIS data to 1 km resolution, water vapor retrieval, cloud masking and an atmospheric correction. MAIAC cloud mask (CM) is a new algorithm based on a time series of gridded MODIS measurements and an image-based rather than pixel-based processing. Extensive processing of MODIS TERRA data over Greenland shows a robust performance of CM algorithm in discrimination of clouds over bright snow and ice. As part of the validation analysis, SGS derived from MODIS over selected sites in 2004 was compared to the microwave brightness temperature measurements of SSM\\I radiometer, which is sensitive to the amount of liquid water in the snowpack. The comparison showed a good qualitative agreement, with both datasets detecting two main periods of snowmelt. Additionally, MODIS SGS was compared with predictions of the snow model CROCUS driven by measurements of the automatic whether stations of the Greenland Climate Network. We found that CROCUS grain size is on average a factor of two larger than MODIS-derived SGS. Overall, the agreement between CROCUS and MODIS results was satisfactory, in particular before and during the

  2. Grain Size of Recall Practice for Lengthy Text Material: Fragile and Mysterious Effects on Memory

    Science.gov (United States)

    Wissman, Kathryn T.; Rawson, Katherine A.

    2015-01-01

    The current research evaluated the extent to which the grain size of recall practice for lengthy text material affects recall during practice and subsequent memory. The "grain size hypothesis" states that a smaller vs. larger grain size will increase retrieval success during practice that in turn will enhance subsequent memory for…

  3. A grain size distribution model for non-catalytic gas-solid reactions

    NARCIS (Netherlands)

    Heesink, Albertus B.M.; Prins, W.; van Swaaij, Willibrordus Petrus Maria

    1993-01-01

    A new model to describe the non-catalytic conversion of a solid by a reactant gas is proposed. This so-called grain size distribution (GSD) model presumes the porous particle to be a collection of grains of various sizes. The size distribution of the grains is derived from mercury porosimetry measur

  4. Control of grain size in sublimation-grown CdTe, and the improvement in performance of devices with systematically increased grain size

    Energy Technology Data Exchange (ETDEWEB)

    Major, J.D.; Proskuryakov, Y.Y.; Durose, K. [Department of Physics, Science Laboratories, Durham University, South Road, Durham, DH1 3LE (United Kingdom); Zoppi, G.; Forbes, I. [Northumbria University, Northumbria Photovoltaics Applications Centre, Newcastle upon Tyne NE1 8ST (United Kingdom)

    2010-06-15

    A method to control the grain size of CdTe thin films deposited by close space sublimation using chamber pressure is demonstrated. Grain diameter is shown to increase in the pressure range 2-200 Torr, following the linear relationship D ({mu}m)=0.027 x P (Torr)+0.90. A mechanism is proposed to explain the dominance of the 111 preferred orientation in the small-grained, but not the large-grained films. For a series of CdTe/CdS solar cells in which the only variable was grain size, the performance parameters were seen to increase from 0.54% (0.94 {mu}m grains) up to a plateau of 11.3% ({>=}3.6 {mu}m grains). This corresponds to the point at which the series resistance is no longer dominated by grain boundaries, but by the contacts. (author)

  5. Control of grain size in sublimation-grown CdTe, and the improvement in performance of devices with systematically increased grain size

    OpenAIRE

    Major, Jonathan; Proskuryakov, Yuri; Durose, Ken; Zoppi, Guillaume; Forbes, Ian

    2010-01-01

    A method to control the grain size of CdTe thin films deposited by close space sublimation using chamber pressure is demonstrated. Grain diameter is shown to increase in the pressure range 2–200 Torr, following the linear relationship D (?m)=0.027×P (Torr)+0.90. A mechanism is proposed to explain the dominance of the 111 preferred orientation in the small-grained, but not the large-grained films. For a series of CdTe/CdS solar cells in which the only variable was grain size, the performance p...

  6. Effect of grain size on the behavior of hydrogen/helium retention in tungsten: a cluster dynamics modeling

    Science.gov (United States)

    Zhao, Zhe; Li, Yonggang; Zhang, Chuanguo; Pan, Guyue; Tang, Panfei; Zeng, Zhi

    2017-08-01

    Reducing ion retention in materials is a key factor in the management of tritium inventory, the selection of compatible plasma-facing materials (PFMs), and thus the future development of fusion reactors. In this work, by introducing the cellular sink strength of grain boundaries (GBs) into the cluster dynamics model, the behavior of hydrogen (H) and helium (He) retention in W with different grain sizes is studied under various irradiation conditions systematically. It is found that the H/He retention increases dramatically with decreasing grain size at typical service temperatures, due to the enhancement of H/He capture ratio by GBs. Generally, He retention exists in three forms: He in GBs, in dislocations and in clusters (He m V n , He n and He n I). Our further study shows that, under the irradiation of low energy and low fluence ions, the contribution of He in clusters is negligible. The total He retention is thus dominated by the competing absorption of GBs and dislocations, that is, changing from the dislocation-based to grain boundary-based retention with decreasing grain size. H retention also presents the same behavior. In view of these grain size-related behaviors of H/He retention in W, it is suggested that coarse-grained crystals should be selected for W-based PFMs in practice.

  7. Effect of grain size on the domain structures and electromechanical responses of ferroelectric polycrystal

    Science.gov (United States)

    Li, Xinkai; Wang, Jie

    2017-01-01

    The effect of grain size on the domain structures and electromechanical responses of ferroelectric polycrystals is investigated by a phase field model. The phase field simulations show that the different types of domains in different size of grains play an important role in the size-dependent properties of ferroelectric polycrystals. It is found that the remnant polarization, coercive field and dielectric coefficient increase monotonously with the increase of grain size. However, the piezoelectric coefficient increases first and then decreases as the grain size increases. The decrease of vortex domains is responsible for the increase of piezoelectric coefficient in the range of small grain size, the decrease of 90° domain walls results in the decrease of piezoelectric coefficient in the range of large grain size. In addition, different domain structures in different size of grains have also great influence on the mechanical depolarization of the ferroelectric polycrystals subjected to a compressive stress.

  8. SPEED DEPENDENCE OF ACOUSTIC VIBRATION PROPAGATION FROM THE FERRITIC GRAIN SIZE IN LOW-CARBON STEEL

    Directory of Open Access Journals (Sweden)

    I. A. Vakulenko

    2015-08-01

    Full Text Available Purpose. It is determining the nature of the ferrite grain size influence of low-carbon alloy steel on the speed propagation of acoustic vibrations. Methodology. The material for the research served a steel sheet of thickness 1.4 mm. Steel type H18T1 had a content of chemical elements within grade composition: 0, 12 % C, 17, 5 % Cr, 1 % Mn, 1, 1 % Ni, 0, 85 % Si, 0, 9 % Ti. The specified steel belongs to the semiferritic class of the accepted classification. The structural state of the metal for the study was obtained by cold plastic deformation by rolling at a reduction in the size range of 20-30 % and subsequent recrystallization annealing at 740 – 750 ° C. Different degrees of cold plastic deformation was obtained by pre-selection of the initial strip thickness so that after a desired amount of rolling reduction receives the same final thickness. The microstructure was observed under a light microscope, the ferrite grain size was determined using a quantitative metallographic technique. The using of X-ray structural analysis techniques allowed determining the level of second-order distortion of the crystal latitude of the ferrite. The speed propagation of acoustic vibrations was measured using a special device such as an ISP-12 with a working frequency of pulses 1.024 kHz. As the characteristic of strength used the hardness was evaluated by the Brinell’s method. Findings. With increasing of ferrite grain size the hardness of the steel is reduced. In the case of constant structural state of metal, reducing the size of the ferrite grains is accompanied by a natural increasing of the phase distortion. The dependence of the speed propagation of acoustic vibrations up and down the rolling direction of the ferrite grain size remained unchanged and reports directly proportional correlation. Originality. On the basis of studies to determine the direct impact of the proportional nature of the ferrite grain size on the rate of propagation of sound

  9. Surface finish effects and the strength-grain size relation in SiC

    Science.gov (United States)

    Cranmer, D. C.; Tressler, R. E.; Bradt, R. C.

    1977-01-01

    The effect of surface finish on the strength-grain size relation was investigated for dense hot-pressed SiC. Failure initiated predominantly via the propagation of extrinsic machining-induced flaws for the range of grain sizes and machining grit sizes studied. These results are consistent with the region of large-grain-size flaw control as delineated by Prochazka and Charles. The severity of machining-induced flaws, relative to the machining grit size, decreased with increasing machining grit size and decreasing SiC grain size.

  10. Deltaic processes on Titan - the role of grain size

    Science.gov (United States)

    Witek, Piotr; Czechowski, Leszek

    2015-04-01

    In Titan's polar regions the Cassini spacecraft observed numerous hydrocarbon lakes surrounded by river valley systems. The rivers transport sediments to the lakes which serve as local sedimentary basins. The shape and evolution of the sedimentary deposits depends, among other parameters, on grain size. This is a result of dependence of settling velocity and drag force on diameter of the sediment particle. In consequence the deltas and alluvial cones take different shapes depending on the source of sediments and the distance from the source, due to natural sorting of rocky material. We used numerical models to simulate development of river deltas in Titanian and terrestrial conditions. Despite differences in gravity and composition, affecting effectiveness of sediment transport, we found many similarities in evolution of sedimentary landforms on both bodies. This gives us another tool for understanding the evolution of the surface of this unique moon.

  11. Image - Rice Grain Scanner: a three-dimensional fully automated assessment of grain size and quality traits

    Directory of Open Access Journals (Sweden)

    Rubens Marschalek

    2016-12-01

    Full Text Available The Image is a scanner developed as a grain classifier for quality control at the rice industry based on Brazilian official norms. It orders the dehulled grains ensuring that each grain would pass individually, in free fall, while the grain is analysed from different sides, covering its whole surface. It ensures a precise three-dimensional measurement of grain size, chalkiness, defects of the grain, milling quality, given out a total of 39 traits/classes/defects/values, which are sent to a excel Microsoft spreadsheet. This is managed through a digital platform which analysis routine and layout were developed and designed by Selgron and Epagri to fit the needs of research. The scanner and its software reach outputs that enhance rice breeding efficiency for grain quality, performing it faster, precisely and with a high-throughput phenotyping than ever before, especially interesting in very early breeding generations.

  12. Nanoscale size effects in crystallization of metallic glass nanorods.

    Science.gov (United States)

    Sohn, Sungwoo; Jung, Yeonwoong; Xie, Yujun; Osuji, Chinedum; Schroers, Jan; Cha, Judy J

    2015-09-01

    Atomistic understanding of crystallization in solids is incomplete due to the lack of appropriate materials and direct experimental tools. Metallic glasses possess simple metallic bonds and slow crystallization kinetics, making them suitable to study crystallization. Here, we investigate crystallization of metallic glass-forming liquids by in-situ heating metallic glass nanorods inside a transmission electron microscope. We unveil that the crystallization kinetics is affected by the nanorod diameter. With decreasing diameters, crystallization temperature decreases initially, exhibiting a minimum at a certain diameter, and then rapidly increases below that. This unusual crystallization kinetics is a consequence of multiple competing factors: increase in apparent viscosity, reduced nucleation probability and enhanced heterogeneous nucleation. The first two are verified by slowed grain growth and scatter in crystallization temperature with decreasing diameters. Our findings provide insight into relevant length scales in crystallization of supercooled metallic glasses, thus offering accurate processing conditions for predictable metallic glass nanomolding.

  13. Grain size reduction due to fracturing and subsequent grain-size-sensitive creep in a lower crustal shear zone in the presence of a CO2-bearing fluid

    Science.gov (United States)

    Okudaira, Takamoto; Shigematsu, Norio; Harigane, Yumiko; Yoshida, Kenta

    2017-02-01

    To understand rheological weakening in the lower continental crust, we studied mylonites in the Paleoproterozoic Eidsfjord anorthosite, northern Norway. The zones of anorthositic mylonites range from a few millimeters to several meters thick, and include ultramylonites and protomylonites. They contain syn-kinematic metamorphic minerals, including Cl-bearing amphibole and scapolite. Thermodynamic analysis reveals that syn-deformational hydration reactions occurred at ∼600 °C and ∼700 MPa under CO2-bearing conditions. The protomylonites contain many fragmented plagioclase porphyroclasts. The fractures in porphyroclasts are filled with fine-grained plagioclase, suggesting that fracturing is a common mechanism of grain size reduction. The anorthite contents of fine-grained polygonal matrix plagioclase are different from those of porphyroclastic plagioclase, suggesting that the matrix grains nucleated and grew during syn-kinematic metamorphism. Plagioclase aggregates in the matrices of mylonites do not exhibit a distinct crystallographic preferred orientation, which implies that the dominant deformation mechanism was grain-size-sensitive creep. Consequently, in the lower crustal anorthositic mylonites, grain size reduction occurred via fracturing, rather than through dynamic recrystallization, leading to grain-size-sensitive creep. The syn-kinematic recrystallization of minor phases at plagioclase grain boundaries may suppress the growth of plagioclase and contribute to the development of grain-size-sensitive creep.

  14. Analysis of EBSD Grain Size Measurements Using Microstructure Simulations and a Customizable Pattern Matching Library for Grain Perimeter Estimation

    Science.gov (United States)

    Coutinho, Y. A.; Rooney, S. C. K.; Payton, E. J.

    2017-03-01

    Grain size data from electron backscatter diffraction (EBSD) maps are often reported as the mean of the circle equivalent diameters of the measured grain areas. Circle equivalent diameters are not directly comparable to the lineal intercept measurements more historically common for grain size characterization in analog optical microscopy. While the value of mean lineal intercept is the same in 2D and 3D for a given probe direction, the mean 2D circle equivalent section diameter is not directly related to any 3D property. Estimation of mean lineal intercept from circle equivalent diameter is usually carried out by again assuming feature circularity, despite the obvious corners that are inherent to grains from the requirements of space filling. A direct conversion between section areas and lineal intercepts can be performed if the grain perimeters are known. In the present work, a novel pattern matching library approach is investigated for measurement of grain perimeters using simulated 2D EBSD maps. The results are compared to alternative approaches for perimeter measurement and assessed with respect to spatial resolution, grain size distribution parameters, and relevant ASTM and ISO measurement standards. The benefits and drawbacks of each approach are discussed. Empirical estimators for conversion between lineal intercept, circle equivalent diameter, and ASTM grain size number are presented.

  15. Two-size approximation: a simple way of treating the evolution of grain size distribution in galaxies

    CERN Document Server

    Hirashita, Hiroyuki

    2014-01-01

    Full calculations of the evolution of grain size distribution in galaxies are in general computationally heavy. In this paper, we propose a simple model of dust enrichment in a galaxy with a simplified treatment of grain size distribution by imposing a `two-size approximation'; that is, all the grain population is represented by small (grain radius a 0.03 micron) grains. We include in the model dust supply from stellar ejecta, destruction in supernova shocks, dust growth by accretion, grain growth by coagulation and grain disruption by shattering, considering how these processes work on the small and large grains. We show that this simple framework reproduces the main features found in full calculations of grain size distributions as follows. The dust enrichment starts with the supply of large grains from stars. At a metallicity level referred to as the critical metallicity of accretion, the abundance of the small grains formed by shattering becomes large enough to rapidly increase the grain abundance by acc...

  16. Effects of grain size and grain boundary on critical current density of high T(sub c) superconducting oxides

    Science.gov (United States)

    Zhao, Y.; Zhang, Q. R.; Zhang, H.

    1990-01-01

    By means of adding impurity elements in high T sub c oxides, the effects were studied of grain size and grain boundary on the critical current density of the following systems: YBa2Cu3O(7-y) and Bi-Pr-Sr-Ca-Cu-O. In order to only change the microstructure instead of the superconductivity of the grains in the samples, the impurity elements were added into the systems in terms of the methods like this: (1) substituting Y with the lanthanide except Pr, Ce, and Tb in YBa2Cu3O(7-y) system to finning down grains in the samples, therefore, the effect can be investigated of the grain size on the critical current density of 1:2:3 compounds; (2) mixing the high T sub c oxides with the metal elements, such as Ag, according to the composition of (high T sub c oxide)1-xAgx to metallize the grain boundaries in the samples, studying the effect of the electric conductivity of the grain boundaries on the critical current density; (3) adding SiO2, PbO2, and SnO2 into the high T sub c oxide to form impurity phases in the grain boundaries, trying to find out the effects of the impurity phases or metalloid grain boundaries on the critical current density of the high T sub c superconductors. The experimental results indicate that in the case of of the presence of the metalloid grain boundaries finning down grains fails to enhance the j sub c, but restrains it strongly, the granular high T sub c superconductors with the small size grains coupled weakly is always the low j sub c system.

  17. Numerical modelling of riverbed grain size stratigraphic evolution

    Institute of Scientific and Technical Information of China (English)

    Peng HU; Zhi-xian CAO; Gareth PENDER; Huai-han LIU

    2014-01-01

    For several decades, quantification of riverbed grain size stratigraphic evolution has been based upon the active layer formulation (ALF), which unfortunately involves considerable uncertainty. While it is the sediment exchange across the bed surface that directly affects the riverbed stratigraphy, it has been assumed in the ALF that the sediment fraction at the lower interface of the active layer is a linear function of the sediment fraction in the flow. Here it is proposed that the sediment fraction of the sediment exchange flux is used directly in estimating the sediment fraction at the lower surface of the active layer. Together with the size-specific mass conservation for riverbed sediment, the modified approach is referred to as the surface-based formulation (SBF). When incorporated into a coupled non-capacity modelling framework for fluvial processes, the SBF leads to results that agree as well or better than those using ALF with laboratory and field observations. This is illustrated for typical cases featuring bed aggradation and degradation due to graded bed-load sediment transport. Systematic experiments on graded sediment transport by unsteady flows are warranted for further testing the modified formulation.

  18. Modeling the dependence of strength on grain sizes in nanocrystalline materials.

    Science.gov (United States)

    He, Wei; Bhole, Sanjeev D; Chen, DaoLun

    2008-01-01

    A model was developed to describe the grain size dependence of hardness (or strength) in nanocrystalline materials by combining the Hall-Petch relationship for larger grains with a coherent polycrystal model for nanoscale grains and introducing a log-normal distribution of grain sizes. The transition from the Hall-Petch relationship to the coherent polycrystal mechanism was shown to be a gradual process. The hardness in the nanoscale regime was observed to increase with decreasing grain boundary affected zone (or effective grain boundary thickness, Δ) in the form of Δ(-1/2). The critical grain size increased linearly with increasing Δ. The variation of the calculated hardness value with the grain size was observed to be in agreement with the experimental data reported in the literature.

  19. Holocene marine transgression as interpreted from bathymetry and sand grain size parameters off Gopalpur

    Digital Repository Service at National Institute of Oceanography (India)

    Rao, K.M.; Rajamanickam, G.V.; Rao, T.C.S.

    Grain size statistical parameters of the surface sediment samples collected from the innershelf off Gopalpur were calculated using graphic and moment methods. Fine-grained sand present up to 15 m water depth shows symmetrical skewness and good...

  20. Grain size effect of monolayer MoS2 transistors characterized by second harmonic generation mapping

    KAUST Repository

    Lin, Chih-Pin

    2015-08-27

    We investigated different CVD-synthesized MoS2 films, aiming to correlate the device characteristics with the grain size. The grain size of MoS2 can be precisely characterized through nondestructive second harmonic generation mapping based on the degree of inversion symmetry. The devices with larger grains at the channel region show improved on/off current ratio, which can be explained by the less carrier scattering caused by the grain boundaries.

  1. SMALL GRAIN 1, which encodes a mitogen-activated protein kinase kinase 4, influences grain size in rice.

    Science.gov (United States)

    Duan, Penggen; Rao, Yuchun; Zeng, Dali; Yang, Yaolong; Xu, Ran; Zhang, Baolan; Dong, Guojun; Qian, Qian; Li, Yunhai

    2014-02-01

    Although grain size is one of the most important components of grain yield, little information is known about the mechanisms that determine final grain size in crops. Here we characterize rice small grain1 (smg1) mutants, which exhibit small and light grains, dense and erect panicles and comparatively slightly shorter plants. The short grain and panicle phenotypes of smg1 mutants are caused by a defect in cell proliferation. The smg1 mutations were identified, using a map-based cloning approach, in mitogen-activated protein kinase kinase 4 (OsMKK4). Relatively higher expression of OsMKK4/SMG1 was detected in younger organs than in older ones, consistent with its role in cell proliferation. Green fluorescent protein (GFP)-OsMKK4/SMG1 fusion proteins appear to be distributed ubiquitously in plant cells. Further results revealed that OsMKK4 influenced brassinosteroid (BR) responses and the expression of BR-related genes. Thus, our findings have identified OsMKK4 as a factor for grain size, and suggest a possible link between the MAPK pathways and BRs in grain growth. © 2013 The Authors The Plant Journal © 2013 John Wiley & Sons Ltd.

  2. Effect of grain size on optical transmittance of birefringent polycrystalline ceramics

    Science.gov (United States)

    Wen, Tzu-Chien

    Polycrystalline ceramics are increasingly used for fabricating windows and domes for the mid infra-red regime (3-5 mum) due to their superior durability as compared to glass and the lower cost of their fabrication and finishing relative to single crystals without significant compromise in optical properties. Due to the noncubic structure, MgF2 and Al2O3 are birefringent ceramics. Birefringence causes scatter of light at the grain boundaries and diminishes in-line transmittance and optical performance. This dissertation presents experimental results and analyses of the grain-size and wavelength dependence of the in-line transmittance of polycrystalline MgF2 and Al2O3. Chapter 2 presents experimental results and analyses of light transmission in polycrystalline MgF2 as a function of the mean grain size at different wavelengths. The scattering coefficient of polycrystalline MgF 2 increased linearly with the mean grain size and inversely with the square of the wavelength of light. These trends are consistent with theoretical models based on both a limiting form of the Raleigh-Gans-Debye theory of particle scattering and light retardation theories that take refractive-index variations along the light path. Chapter 3 investigates the applicability of particle light scattering theories to light attenuation in birefringent polycrystalline ceramics by measuring light transmittance in a model two-phase system. The system consisted of microspheres of silica dispersed in a solution of glycerol in water. It was found that RGD theory showed the systematic deviation for higher particle volume fraction (φ > 0.2) and larger particle size (d p > 1 mum). This result suggested that light scattering models based on single particle scattering are unlikely to provide viable physical explanation for the effect of grain size on light transmittance in birefringent polycrystalline ceramics due to the high volume fraction in dense polycrystalline ceramics. Chapter 4 analyses light

  3. Grain growth of ε-iron: Implications to grain size and its evolution in the Earth's inner core

    Science.gov (United States)

    Yamazaki, Daisuke; Tsujino, Noriyoshi; Yoneda, Akira; Ito, Eiji; Yoshino, Takashi; Tange, Yoshinori; Higo, Yuji

    2017-02-01

    Knowledge of grain growth rate of ε-iron can put constraint on estimation of the grain size in the inner core. We determined grain growth rate of ε-iron at ∼55 GPa and 1200-1500 K by means of in-situ X-ray diffraction observation to be Gn - G0n = kt, where G (m) is the grain size at time t (s), G0 (m) is the initial grain size, n is growth exponent (fixed to 2) and k is the growth constant expressed as k =k0 exp ⁡ (-H* / RT) with log k0 (mn /s) = - 5.8 (± 2.4) and activation enthalpy H* = 221 (± 61) kJ /mol, and R is the gas constant and T is the absolute temperature. Extrapolation of the grain growth law of ε-iron to the inner core conditions suggests that the grain size in the inner core is in a range from several hundred meters to several kilometers, which is intermediate among the previous estimations, and hence the dominant deformation mechanism is considered to be Harper-Dorn creep rather than diffusion creep as pointed out by the previous work. This indicates the relatively uniform viscosity in the entire inner core.

  4. Time-of-Flight Three Dimensional Neutron Diffraction in Transmission Mode for Mapping Crystal Grain Structures.

    Science.gov (United States)

    Cereser, Alberto; Strobl, Markus; Hall, Stephen A; Steuwer, Axel; Kiyanagi, Ryoji; Tremsin, Anton S; Knudsen, Erik B; Shinohara, Takenao; Willendrup, Peter K; da Silva Fanta, Alice Bastos; Iyengar, Srinivasan; Larsen, Peter M; Hanashima, Takayasu; Moyoshi, Taketo; Kadletz, Peter M; Krooß, Philipp; Niendorf, Thomas; Sales, Morten; Schmahl, Wolfgang W; Schmidt, Søren

    2017-08-25

    The physical properties of polycrystalline materials depend on their microstructure, which is the nano- to centimeter scale arrangement of phases and defects in their interior. Such microstructure depends on the shape, crystallographic phase and orientation, and interfacing of the grains constituting the material. This article presents a new non-destructive 3D technique to study centimeter-sized bulk samples with a spatial resolution of hundred micrometers: time-of-flight three-dimensional neutron diffraction (ToF 3DND). Compared to existing analogous X-ray diffraction techniques, ToF 3DND enables studies of samples that can be both larger in size and made of heavier elements. Moreover, ToF 3DND facilitates the use of complicated sample environments. The basic ToF 3DND setup, utilizing an imaging detector with high spatial and temporal resolution, can easily be implemented at a time-of-flight neutron beamline. The technique was developed and tested with data collected at the Materials and Life Science Experimental Facility of the Japan Proton Accelerator Complex (J-PARC) for an iron sample. We successfully reconstructed the shape of 108 grains and developed an indexing procedure. The reconstruction algorithms have been validated by reconstructing two stacked Co-Ni-Ga single crystals, and by comparison with a grain map obtained by post-mortem electron backscatter diffraction (EBSD).

  5. Couette-Taylor crystallizer: Effective control of crystal size distribution and recovery of L-lysine in cooling crystallization

    Science.gov (United States)

    Nguyen, Anh-Tuan; Yu, Taekyung; Kim, Woo-Sik

    2017-07-01

    A Couette-Taylor crystallizer is developed to enhance the L-Lysine crystal size distribution and recovery in the case of continuous cooling crystallization. When using the proposed Couette-Taylor (CT) crystallizer, the size distribution and crystal product recovery were much narrower and higher, respectively, than those from a conventional stirred tank (ST) crystallizer. Here, the coefficient of the size distribution for the crystal product from the CT crystallizer was only 0.45, while it was 0.78 in the case of the conventional ST crystallizer at an agitation speed of 700 rpm, mean residence time of 20 min, and feed concentration of 900 (g/L). Furthermore, when using the CT crystallizer, the crystal product recovery was remarkably enhanced up to 100%wt with a mean residence time of only 20 min, while it required a mean residence time of at least 60 min when using the conventional ST crystallizer. This result indicates that the CT crystallizer was much more effective than the conventional ST crystallizer in terms of controlling a narrower size distribution and achieving a 100%wt L-lysine crystal product recovery from continuous cooling crystallization. The advantage of the CT crystallizer over the conventional ST crystallizer was explained based on the higher energy dissipation of the Taylor vortex flow and larger surface area for heat transfer of the CT crystallizer. Here, the energy dissipation of the Taylor vortex flow in the CT crystallizer was 13.6 times higher than that of the random fluid motion in the conventional ST crystallizer, while the surface area per unit volume for heat transfer of the CT crystallizer was 8.0 times higher than that of the conventional ST crystallizer. As a result, the mixing condition and heat transfer of the CT crystallizer were much more effective than those of the conventional ST crystallizer for the cooling crystallization of L-lysine, thereby enhancing the L-lysine crystal size distribution and product recovery.

  6. Grain size influences the corrosion and cavitation of Ni3Al intermetallic alloys

    Directory of Open Access Journals (Sweden)

    D. Zasada

    2015-01-01

    Full Text Available Influence of grain size on corrosion and cavitation of the Ni3Al - based intermetallic alloy was studied in recent paper. The research was conducted on Ni3Al - based intermetallic alloy doped with boron and zirconium. The initial grain size of 6, 20 and 45 μm the investigated samples was obtained through cold rolling followed by recrystallization annealing. It was found that initial grain size does not influence the breakthrough potential neither repassivation potential. On the other hand, various types of pits were found for alloys with different grain size during corrosion tests in sodium chloride solutions. It was found that increase of grain size results with reducing the depth of cavitational pits. However, surface area of the pits increases with increasing grain size.

  7. Determination of grain-size characteristics from electromagnetic seabed mapping data: A NW Iberian shelf study

    Science.gov (United States)

    Baasch, Benjamin; Müller, Hendrik; von Dobeneck, Tilo; Oberle, Ferdinand K. J.

    2017-05-01

    The electric conductivity and magnetic susceptibility of sediments are fundamental parameters in environmental geophysics. Both can be derived from marine electromagnetic profiling, a novel, fast and non-invasive seafloor mapping technique. Here we present statistical evidence that electric conductivity and magnetic susceptibility can help to determine physical grain-size characteristics (size, sorting and mud content) of marine surficial sediments. Electromagnetic data acquired with the bottom-towed electromagnetic profiler MARUM NERIDIS III were analysed and compared with grain size data from 33 samples across the NW Iberian continental shelf. A negative correlation between mean grain size and conductivity (R=-0.79) as well as mean grain size and susceptibility (R=-0.78) was found. Simple and multiple linear regression analyses were carried out to predict mean grain size, mud content and the standard deviation of the grain-size distribution from conductivity and susceptibility. The comparison of both methods showed that multiple linear regression models predict the grain-size distribution characteristics better than the simple models. This exemplary study demonstrates that electromagnetic benthic profiling is capable to estimate mean grain size, sorting and mud content of marine surficial sediments at a very high significance level. Transfer functions can be calibrated using grains-size data from a few reference samples and extrapolated along shelf-wide survey lines. This study suggests that electromagnetic benthic profiling should play a larger role for coastal zone management, seafloor contamination and sediment provenance studies in worldwide continental shelf systems.

  8. Effect of grain size on the elastic properties of nanocrystalline {alpha}-iron

    Energy Technology Data Exchange (ETDEWEB)

    Latapie, A.; Farkas, D

    2003-03-03

    The effect of grain size on the elastic properties of nanocrystalline {alpha}-iron is reported using atomistic simulations. A softening of the elastic properties is observed for grain sizes ranging from 12 nm down to 6 nm. The decrease in the Young's and shear moduli with decreasing grain size is in agreement with experimental data and matches an analytical model based on the rule of mixtures for composite materials.

  9. Synthesis of SAPO-56 with controlled crystal size

    Science.gov (United States)

    Wu, Ting; Feng, Xuhui; Carreon, Maria L.; Carreon, Moises A.

    2017-03-01

    Herein, we present the hydrothermal synthesis of SAPO-56 crystals with relatively controlled crystal/particle size. The effects of water content, aluminum source, gel composition, stirring, crystallization temperature and time, as well as the incorporation of crystal growth inhibitors during synthesis were systematically investigated. The synthesized SAPO-56 crystals displayed BET surface areas as high as ˜630 m2 g-1 with relative narrow size distribution in the ˜5-60 μm range. Nitrogen BET surface areas in the 451 to 631 m2 g-1 range were observed. Decreasing the crystallization temperature from 220 to 210 °C helped to decrease the average SAPO-56 crystal size. Diluted gel compositions promoted the formation of smaller crystals. Crystal growth inhibitors were found to be helpful in reducing crystal size and narrow the size distribution. Specifically, ˜5 μm SAPO-56 crystals displaying narrow size distribution were synthesized employing aluminum-tri-sec-butoxide as Al source, high water content, and high stirring rates.

  10. Recrystallization Behavior Design for Controlling Grain Size in Strip Rolling Process

    Institute of Scientific and Technical Information of China (English)

    ZHU Guo-hui; S V Subramanian

    2008-01-01

    To promote effectively dynamic recrystallization and obtain a homogeneous distribution of ultrafine grain size in strip finish rolling process, the behavior of static and dynamic recrystallization must be appropriately designed to provide an ultrafine austenite microstructure without mixed grain size. The design of rolling schedule was analyzed based on the control of the recrystallization behavior to achieve ultrafine grain size in the strip rolling process of niobium microalloyed steel. The experimental simulations were presented to validate the twice dynamic recrystallization design to achieve ultrafine grain size control.

  11. Material grain size characterization method based on energy attenuation coefficient spectrum and support vector regression.

    Science.gov (United States)

    Li, Min; Zhou, Tong; Song, Yanan

    2016-07-01

    A grain size characterization method based on energy attenuation coefficient spectrum and support vector regression (SVR) is proposed. First, the spectra of the first and second back-wall echoes are cut into several frequency bands to calculate the energy attenuation coefficient spectrum. Second, the frequency band that is sensitive to grain size variation is determined. Finally, a statistical model between the energy attenuation coefficient in the sensitive frequency band and average grain size is established through SVR. Experimental verification is conducted on austenitic stainless steel. The average relative error of the predicted grain size is 5.65%, which is better than that of conventional methods.

  12. Time-of-Flight Three Dimensional Neutron Diffraction in Transmission Mode for Mapping Crystal Grain Structures

    DEFF Research Database (Denmark)

    Cereser, Alberto; Strobl, Markus; Hall, Stephen A.

    2017-01-01

    constituting the material. This article presents a new non-destructive 3D technique to study centimeter-sized bulk samples with a spatial resolution of hundred micrometers: time-of-flight three-dimensional neutron diffraction (ToF 3DND). Compared to existing analogous X-ray diffraction techniques, ToF 3DND...... enables studies of samples that can be both larger in size and made of heavier elements. Moreover, ToF 3DND facilitates the use of complicated sample environments. The basic ToF 3DND setup, utilizing an imaging detector with high spatial and temporal resolution, can easily be implemented at a time....... The reconstruction algorithms have been validated by reconstructing two stacked Co-Ni-Ga single crystals, and by comparison with a grain map obtained by post-mortem electron backscatter diffraction (EBSD)....

  13. The Effects of Grain Size and Temperature Distributions on the Formation of Interstellar Ice Mantles

    CERN Document Server

    Pauly, Tyler

    2015-01-01

    Computational models of interstellar gas-grain chemistry have historically adopted a single dust-grain size of 0.1 micron, assumed to be representative of the size distribution present in the interstellar medium. Here, we investigate the effects of a broad grain-size distribution on the chemistry on dust-grain surfaces and the subsequent build-up of molecular ices on the grains, using a three-phase gas-grain chemical model of a quiescent dark cloud. We include an explicit treatment of the grain temperatures, governed both by the visual extinction of the cloud and the size of each individual grain-size population. We find that the temperature difference plays a significant role in determining the total bulk ice composition across the grain-size distribution, while the effects of geometrical differences between size populations appear marginal. We also consider collapse from a diffuse to a dark cloud, allowing dust temperatures to fall. Under the initial diffuse conditions, small grains are too warm to promote ...

  14. Martensitic transformations in nanostructured nitinol: Finite element modeling of grain size and distribution effects

    DEFF Research Database (Denmark)

    Liu, Hong-Sheng; Mishnaevsky, Leon

    2013-01-01

    A computational model of martensitic phase transformation in nanostructured nitinol is developed which takes into account the grain size effect. On the basis of the theoretical analysis of the thermodynamic transformation criterion and the energy barrier for phase transformation, it was demonstra...... between the coarse and fine grained regions, and expand inside the region with small grains along the shear band direction....

  15. Analytical Investigation of Prior Austenite Grain Size Dependence of Low Temperature Toughness in Steel Weld Metal

    Institute of Scientific and Technical Information of China (English)

    X.F. Zhang; P. Hall; H. Terasak; M. Sato; Y. Komizo

    2012-01-01

    Prior austenite grain size dependence of the low temperature impact toughness has been addressed in the bainitic weld metals by in situ observations.Usually,decreasing the grain size is the only approach by which both the strength and the toughness of a steel are increased.However,low carbon bainitic steel with small grain size shows a weakening of the low temperature impact toughness in this study.By direct tracking of the morphological evolution during phase transformation,it is found that large austenite grain size dominates the nucleation of intragranular acicular ferrite,whereas small austenite grain size leads to grain boundary nucleation of bainite.This kinetics information will contribute to meet the increasing low temperature toughness requirement of weld metals for the storage tanks and offshore structures.

  16. High-temperature grain size stabilization of nanocrystalline Fe–Cr alloys with Hf additions

    Energy Technology Data Exchange (ETDEWEB)

    Li, Lulu, E-mail: lli18@ncsu.edu; Saber, Mostafa; Xu, Weizong; Zhu, Yuntian; Koch, Carl C.; Scattergood, Ronald O.

    2014-09-08

    The influence of 1–4 at% Hf additions on the thermal stability of mechanically alloyed nanocrystalline Fe–14Cr alloys was studied in this work. XRD-calculated grain size and microhardness results were reported versus isochronal annealing treatments up to 1100 °C. Microstructural evolution was investigated using channeling contrast FIB imaging and TEM. Grain size of samples with 4 at% Hf was found to be maintained in the nanoscale range at temperatures up to 1000 °C. Zener pinning was considered as a major source of high temperature grain size stabilization. By comparing the Orowan strengthening contribution to the total hardness, the deviation of grain size predictions from the actual grain size in Fe–14Cr–4Hf suggests the presence of thermodynamic stabilization by the solute segregation to grain boundaries (GBs). A predictive thermodynamic model indicates that the thermodynamic stabilization can be expected.

  17. Grain Size Effect on Fracture Behavior of the Axis-Tensile Test of Inconel 718 Sheet

    Science.gov (United States)

    Liu, B. B.; Han, J. Q.; Zhao, R.; Liu, W.; Wan, M.

    2016-11-01

    Change in mechanical parts from macro-size to micro-size has become a trend in the metal- and alloy-forming process, with an increasing demand on micro-parts in the last decades. The material mechanical behaviors of micro-size parts are quite different from the conventional ones of macro-size parts due to size effect. It is necessary to further investigate the effects of grain size on material mechanisms in micro-scales, especially fracture behaviors. The fracture behaviors of Inconel 718 sheet with the thickness of 300 μm are studied by uniaxial tensile tests in different grain sizes ranging from 18 to 130 μm. The results show that fracture stress and strain decrease with the increase of grain size. A critical value in the specimen thickness (t) to grain size (d) ratio divides the strength levels into separate stages on the basis of an increase of the inverse of grain size. In addition, the grain size-dependent fracture morphology is changed in the number of dimples and micro-voids decreasing on the fracture surfaces and the sizes of micro-voids changing larger with the increase of grain size.

  18. Grain-size effect on the electrical properties of nanocrystalline indium tin oxide thin films

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jong Hoon [Korea Research Institute of Standards and Science, 267 Gajeong-Ro, Yuseong-Gu, Daejeon 305-340 (Korea, Republic of); Kim, Young Heon, E-mail: young.h.kim@kriss.re.kr [Korea Research Institute of Standards and Science, 267 Gajeong-Ro, Yuseong-Gu, Daejeon 305-340 (Korea, Republic of); University of Science & Technology, 217 Gajeong-Ro, Yuseong-Gu, Daejeon 305-350 (Korea, Republic of); Ahn, Sang Jung [Korea Research Institute of Standards and Science, 267 Gajeong-Ro, Yuseong-Gu, Daejeon 305-340 (Korea, Republic of); University of Science & Technology, 217 Gajeong-Ro, Yuseong-Gu, Daejeon 305-350 (Korea, Republic of); Ha, Tae Hwan [University of Science & Technology, 217 Gajeong-Ro, Yuseong-Gu, Daejeon 305-350 (Korea, Republic of); Future Biotechnology Research Division, Korea Research Institute of Bioscience and Biotechnology (KRIBB), 125 Gwahak-ro, Yuseong-Gu, Daejeon 305-806 (Korea, Republic of); Kim, Hong Seung [Department of Nano Semiconductor Engineering, Korea Maritime and Ocean University, 727 Taejong-Ro, Busan 606-791 (Korea, Republic of)

    2015-09-15

    Highlights: • Nanometer-sized small grains were observed in the ITO thin films. • The grain size increased as the post-thermal annealing temperature increased. • The mobility of ITO thin films increased with increasing grain size. • The ITO film annealed at 300 °C was an amorphous phase, while the others were polycrystalline structure. - Abstract: In this paper, we demonstrate the electrical properties, depending on grain size, of nanocrystalline indium tin oxide (ITO) thin films prepared with a solution process. The size distributions of nanometer-sized ITO film grains increased as the post-annealing temperature increased after deposition; the grain sizes were comparable with the calculated electron mean free path. The mobility of ITO thin films increased with increasing grain size; this phenomenon was explained by adopting the charge-trapping model for grain boundary scattering. These findings suggest that it is possible to improve mobility by reducing the number of trapping sites at the grain boundary.

  19. Size-dependent mechanical behavior of nanoscale polymer particles through coarse-grained molecular dynamics simulation.

    Science.gov (United States)

    Zhao, Junhua; Nagao, Shijo; Odegard, Gregory M; Zhang, Zhiliang; Kristiansen, Helge; He, Jianying

    2013-12-21

    Anisotropic conductive adhesives (ACAs) are promising materials used for producing ultra-thin liquid-crystal displays. Because the mechanical response of polymer particles can have a significant impact in the performance of ACAs, understanding of this apparent size effect is of fundamental importance in the electronics industry. The objective of this research is to use a coarse-grained molecular dynamics model to verify and gain physical insight into the observed size dependence effect in polymer particles. In agreement with experimental studies, the results of this study clearly indicate that there is a strong size effect in spherical polymer particles with diameters approaching the nanometer length scale. The results of the simulations also clearly indicate that the source for the increases in modulus is the increase in relative surface energy for decreasing particle sizes. Finally, the actual contact conditions at the surface of the polymer nanoparticles are shown to be similar to those predicted using Hertz and perfectly plastic contact theory. As ACA thicknesses are reduced in response to reductions in polymer particle size, it is expected that the overall compressive stiffness of the ACA will increase, thus influencing the manufacturing process.

  20. WIDE AND THICK GRAIN 1, which encodes an otubain-like protease with deubiquitination activity, influences grain size and shape in rice.

    Science.gov (United States)

    Huang, Ke; Wang, Dekai; Duan, Penggen; Zhang, Baolan; Xu, Ran; Li, Na; Li, Yunhai

    2017-09-01

    Grain size and shape are two crucial traits that influence grain yield and grain appearance in rice. Although several factors that affect grain size have been described in rice, the molecular mechanisms underlying the determination of grain size and shape are still elusive. In this study we report that WIDE AND THICK GRAIN 1 (WTG1) functions as an important factor determining grain size and shape in rice. The wtg1-1 mutant exhibits wide, thick, short and heavy grains and also shows an increased number of grains per panicle. WTG1 determines grain size and shape mainly by influencing cell expansion. WTG1 encodes an otubain-like protease, which shares similarity with human OTUB1. Biochemical analyses indicate that WTG1 is a functional deubiquitinating enzyme, and the mutant protein (wtg1-1) loses this deubiquitinating activity. WTG1 is expressed in developing grains and panicles, and the GFP-WTG1 fusion protein is present in the nucleus and cytoplasm. Overexpression of WTG1 results in narrow, thin, long grains due to narrow and long cells, further supporting the role of WTG1 in determining grain size and shape. Thus, our findings identify the otubain-like protease WTG1 to be an important factor that determines grain size and shape, suggesting that WTG1 has the potential to improve grain size and shape in rice. © 2017 The Authors The Plant Journal © 2017 John Wiley & Sons Ltd.

  1. GS6, A Member of the GRAS Gene Family, Negatively Regulates Grain Size in Rice

    Institute of Scientific and Technical Information of China (English)

    Lianjun Sun; Xiaojiao Li; Yongcai Fu; Zuofeng Zhu; Lubin Tan; Fengxia Liu; Xianyou Sun; Xuewen Sun; Chuanqing Sun

    2013-01-01

    Grain size is an important yield-related trait in rice. Intensive artificial selection for grain size during domestication is evidenced by the larger grains of most of today’s cultivars compared with their wild relatives. However, the molecular genetic control of rice grain size is still not well characterized. Here, we report the identification and cloning of Grain Size 6 (GS6), which plays an important role in reducing grain size in rice. A premature stop at the þ348 position in the coding sequence (CDS) of GS6 increased grain width and weight significantly. Alignment of the CDS regions of GS6 in 90 rice materials revealed three GS6 alleles. Most japonica varieties (95%) harbor the Type I haplotype, and 62.9%of indica varieties harbor the Type II haplotype. Association analysis revealed that the Type I haplotype tends to increase the width and weight of grains more than either of the Type II or Type III haplotypes. Further investigation of genetic diversity and the evolutionary mechanisms of GS6 showed that the GS6 gene was strongly selected in japonica cultivars. In addition, a “ggc” repeat region identified in the region that encodes the GRAS domain of GS6 played an important historic role in the domestication of grain size in rice. Knowledge of the function of GS6 might aid efforts to elucidate the molecular mechanisms that control grain development and evolution in rice plants, and could facilitate the genetic improvement of rice yield.

  2. Grain Refinement and Mechanical Properties of Cu–Cr–Zr Alloys with Different Nano-Sized TiCp Addition

    Science.gov (United States)

    Zhang, Dongdong; Bai, Fang; Wang, Yong; Wang, Jinguo; Wang, Wenquan

    2017-01-01

    The TiCp/Cu master alloy was prepared via thermal explosion reaction. Afterwards, the nano-sized TiCp/Cu master alloy was dispersed by electromagnetic stirring casting into the melting Cu–Cr–Zr alloys to fabricate the nano-sized TiCp-reinforced Cu–Cr–Zr composites. Results show that nano-sized TiCp can effectively refine the grain size of Cu–Cr–Zr alloys. The morphologies of grain in Cu–Cr–Zr composites changed from dendritic grain to equiaxed crystal because of the addition and dispersion of nano-sized TiCp. The grain size decreased from 82 to 28 μm with the nano-sized TiCp content. Compared with Cu–Cr–Zr alloys, the ultimate compressive strength (σUCS) and yield strength (σ0.2) of 4 wt% TiCp-reinforced Cu–Cr–Zr composites increased by 6.7% and 9.4%, respectively. The wear resistance of the nano-sized TiCp-reinforced Cu–Cr–Zr composites increased with the increasing nano-sized TiCp content. The wear loss of the nano-sized TiCp-reinforced Cu–Cr–Zr composites decreased with the increasing TiCp content under abrasive particles. The eletrical conductivity of Cu–Cr–Zr alloys, 2% and 4% nano-sized TiCp-reinforced Cu–Cr–Zr composites are 64.71% IACS, 56.77% IACS and 52.93% IACS, respectively. PMID:28786937

  3. Synthesis and characterization of large-grain solid-phase crystallized polycrystalline silicon thin films

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, Avishek, E-mail: avishek.kumar@nus.edu.sg, E-mail: dalapatig@imre.a-star.edu.sg [Solar Energy Research Institute of Singapore, National University of Singapore, 7 Engineering Drive 1, Block E3A, #06-01, Singapore 117574 (Singapore); Department of Electrical and Computer Engineering, National University of Singapore, Singapore 117583 (Singapore); Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore); Law, Felix; Widenborg, Per I. [Solar Energy Research Institute of Singapore, National University of Singapore, 7 Engineering Drive 1, Block E3A, #06-01, Singapore 117574 (Singapore); Dalapati, Goutam K., E-mail: avishek.kumar@nus.edu.sg, E-mail: dalapatig@imre.a-star.edu.sg; Subramanian, Gomathy S.; Tan, Hui R. [Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore); Aberle, Armin G. [Solar Energy Research Institute of Singapore, National University of Singapore, 7 Engineering Drive 1, Block E3A, #06-01, Singapore 117574 and Department of Electrical and Computer Engineering, National University of Singapore, Singapore 117583 (Singapore)

    2014-11-01

    n-type polycrystalline silicon (poly-Si) films with very large grains, exceeding 30 μm in width, and with high Hall mobility of about 71.5 cm{sup 2}/V s are successfully prepared by the solid-phase crystallization technique on glass through the control of the PH{sub 3} (2% in H{sub 2})/SiH{sub 4} gas flow ratio. The effect of this gas flow ratio on the electronic and structural quality of the n-type poly-Si thin film is systematically investigated using Hall effect measurements, Raman microscopy, and electron backscatter diffraction (EBSD), respectively. The poly-Si grains are found to be randomly oriented, whereby the average area weighted grain size is found to increase from 4.3 to 18 μm with increase of the PH{sub 3} (2% in H{sub 2})/SiH{sub 4} gas flow ratio. The stress in the poly-Si thin films is found to increase above 900 MPa when the PH{sub 3} (2% in H{sub 2})/SiH{sub 4} gas flow ratio is increased from 0.025 to 0.45. Finally, high-resolution transmission electron microscopy, high angle annular dark field-scanning tunneling microscopy, and EBSD are used to identify the defects and dislocations caused by the stress in the fabricated poly-Si films.

  4. Characterizing the Large (cm-size) Grains Around Comet 103P/Hartley 2

    Science.gov (United States)

    Sunshine, Jessica M.; Feaga, Lori M.; Farnham, Tony; Protopapa, Silvia; Kelley, Michael S.; Engle, Anna

    2016-10-01

    During the flyby of comet 103P/Hartley 2, two populations of bright grains were identified in the coma. Small, 1 µm-sized, water ice-rich grains were observed near the small end of the nucleus that were dragged from the interior by CO2 gas emissions. At closest approach a population of larger grains was clearly seen in visible images off the large lobe. The estimated brightness of the isolated grains suggests that they are likely cm-sized particles and likely water ice-rich. Both sets of grains were simultaneously observed in visible images, at two different resolutions, and by Deep Impact infrared spectrometer. However, because of the difficulty in finding isolated grains in the infrared slit, the population of larger grains has not previously been characterized. Doing so allows us to determine both the reflected and thermal properties of the grains, which when compared to visible images can be used to constrain the size of the grains. Their spectral properties can also be used to definitively detect water ice as has been assumed from visible albedos. In addition, the infrared spectra can be used estimate the relative abundance and particle sizes of ice and non-ice components. The velocity and dynamics of these larger grains can also be characterized. These data will be compared with those of the population of smaller grains emanated directly from the nucleus.Funding from NASA'S Discovery Data Analysis Program (NNX16AJ93G) is greatfully acknowledged.

  5. Micrometer size grains of hot isostatically pressed alumina and its characterization

    Indian Academy of Sciences (India)

    A K Mallik; S Gangadharan; S Dutta; D Basu

    2010-08-01

    Alumina samples were prepared from two different particle size powders. Finer particle compacts when heated along with coarser particle compacts at same processing temperatures produce bigger grain microstructures due to higher grain growth. An unconventional method of etching by molten V2O5 was adopted to look at the microstructure for accuracy in reported data. On an average starting with finer particles give microstructure with a grain size of 5.5 m and starting with coarser particles, give microstructure with 2.2 m average grain size. The flexural strength is around 400 MPa for alumina samples prepared from finer powder in comparison with about 550 MPa for alumina samples prepared from coarser powder. The Vickers hardness in 5.5 m grain microstructure is around 20 GPa in comparison to about 18 GPa in microstructure with smaller grains of 2.2 m size.

  6. Derivation of Hillert-type 3D grain growth rate model with topological considerations and discussion on its grain size parameter

    Institute of Scientific and Technical Information of China (English)

    Guoquan Liu; Haibo Yu; Xiaoyan Song; Xiangge Qin; Chao Wang

    2004-01-01

    A Hillert-type three-dimensional grain growth rate model was derived through the grain topology-size correlation model,combined with a topology-dependent grain growth rate equation in three dimensions. It shows clearly that the Hillert-type 3D grain growth rate model may also be described with topology considerations of microstructure. The size parameter bearing in the model is further discussed both according to the derived model and in another approach with the aid of quantitative relationship between the grain size and the integral mean curvature over grain surface. Both approaches successfully demonstrate that, if the concerned grains can be well approximated by a space-filling convex polyhedra in shape, the grain size parameter bearing in the Hillert-type 3D grain growth model should be a parameter proportional to the mean grain tangent radius.

  7. Misorientation related microstructure at the grain boundary in a nickel-based single crystal superalloy

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Ming; Zhuo, Longchao [National Center for Electron Microscopy in Beijing, School of Materials Science and Engineering, The State Key Laboratory of New Ceramics and Fine Processing, Laboratory of Advanced Materials (MOE), Tsinghua University, Beijing 100084 (China); Liu, Zhanli [Applied Mechanics Lab, School of Aerospace, Tsinghua University, Beijing 100084 (China); Lu, Xiaogang [School of Materials Science and Engineering, Shanghai University, Shanghai (China); Shi, Zhenxue; Li, Jiarong [Science and Technology on Advanced High Temperature Structural Materials Laboratory, Beijing Institute of Aeronautical Materials, Beijing 100095 (China); Zhu, Jing, E-mail: jzhu@mail.tsinghua.edu.cn [National Center for Electron Microscopy in Beijing, School of Materials Science and Engineering, The State Key Laboratory of New Ceramics and Fine Processing, Laboratory of Advanced Materials (MOE), Tsinghua University, Beijing 100084 (China)

    2015-07-29

    The mechanical properties of nickel-based single crystal superalloys deteriorate with increasing misorientation, thus the finished product rate of the casting of single crystal turbine airfoils may be reduced due to the formation of grain boundaries especially when the misorientation angle exceeds to some extent. To this day, evolution of the microstructures at the grain boundaries with misorientation and the relationship between the microstructures and the mechanical properties are still unclear. In this work a detailed characterization of the misorientation related microstructure at the grain boundary in DD6 single crystal superalloy has been carried out using scanning electron microscopy (SEM) and transmission electron microscopy (TEM) techniques; the elemental distribution at the grain boundaries has been analyzed by energy dispersive (EDS) X-ray mapping; and the effect of precipitation of μ phases at the grain boundary on the mechanical property has been evaluated by finite element calculation. It is shown that the proportion of γ phase at the grain boundaries decreases, while the proportion of γ′ phase at the grain boundaries increases with increasing misorientation; the μ phase is precipitated at the grain boundaries when the misorientation angle exceeds about 10° and thus it could lead to a dramatic deterioration of the mechanical properties, as well as that the enrichment of Re and W gradually disappears as the misorientation angle increases. All these factors may result in the degradation of the mechanical properties at the grain boundaries as the misorientation increases. Furthermore, the finite element calculation confirms that precipitation of μ phases at the grain boundary is responsible for the significant deterioration of the mechanical properties when the misorientation exceeds about 10°. This work provides a physical imaging of the microstructure for understanding the relationship between the mechanical properties and the misorientation

  8. Grain size in lithospheric-scale shear zones: Chicken or Egg?

    Science.gov (United States)

    Thielmann, M.; Rozel, A.; Kaus, B. J. P.; Ricard, Y.

    2012-04-01

    Lithospheric-scale shear zones are commonly defined as regions inhomogeneous and localized deformation. Strain softening has been demonstrated to be necessary for localization in those shear zones, but there is still debate about the physical cause of this softening. As natural shear zones typically have a significantly reduced grain size, it has been proposed that grain size reduction provides the necessary strain softening to localize deformation. As grain size reduces, the dominant deformation mechanism switches from dislocation to diffusion creep, thus requiring less stress to deform the rock. Until recently, the equilibrium grain size has been thought to follow a piezometric relationship, thus indicating the stress under which a shear zone deformed. More recent work (Austin and Evans (2007), Rozel et. al. (2011)) suggests that the equilibrium grain size is not dependent on stress, but rather on the deformational work. Using this relationship, we use numerical models to investigate the effect of grain size evolution on lithospheric deformation. We focus on the question if grain size provides sufficient weakening to effectively localize deformation under lithospheric conditions or if it's effect is rather passive and as such a marker for the deformational work done in a shear zone. We then compare the localization potential of grain size reduction to shear heating and investigate the interplay between the two weakening mechanisms.

  9. Grain-size dependence of superconductivity in dc sputtered Nb films

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The superconducting transition temperature and grain size of dc sputtered Nb films are systematically investigated. The results show that the superconductivity is closely related to the grain size, rather than to the scattering strength of electrons or the surface layer proximity effect of the films.

  10. Eyewitness Recall: Regulation of Grain Size and the Role of Confidence

    Science.gov (United States)

    Weber, Nathan; Brewer, Neil

    2008-01-01

    Eyewitness testimony plays a critical role in Western legal systems. Three experiments extended M. Goldsmith, A. Koriat, and A. Weinberg-Eliezer's (2002) framework of the regulation of grain size (precision vs. coarseness) of memory reports to eyewitness memory. In 2 experiments, the grain size of responses had a large impact on memory accuracy.…

  11. A Method of Stray Grain Suppression for Single-Crystal Superalloy During Seed Melt-Back

    Science.gov (United States)

    Xuan, Weidong; Lan, Jian; Liu, Huan; Li, Chuanjun; Zhong, Yunbo; Ren, Xingfu; Li, Xi; Cao, Guanghui; Ren, Zhongming

    2016-12-01

    The suppression of stray grains during seed melt-back of single-crystal superalloy through thermal resistance technique has been investigated based on both experimental observations and numerical simulation. The results indicate that the introduction of thermal resistance layer significantly suppresses the stray grain formation of single-crystal superalloy. Based on both theoretical analysis and numerical simulation, above results should be attributed to the decrease of radial heat transfer of sample in the thermal resistance layer.

  12. Plasticity size effects in voided crystals

    DEFF Research Database (Denmark)

    Hussein, M. I.; Borg, Ulrik; Niordson, Christian Frithiof;

    The shear and equi-biaxial straining responses of periodic voided single crystals are analysed using discrete dislocation plasticity and a continuum strain gradient crystal plasticity theory. In the discrete dislocation formulation the dislocations are all of edge character and are modelled as line...... predictions of the two formulations for all crystal types and void volume fractions considered when the material length scale in the non-local plasticity model chosen to be $0.325\\mu m$ (around ten times the slip plane spacing in the discrete dislocation models)....

  13. Reduction of glycine particle size by impinging jet crystallization.

    Science.gov (United States)

    Tari, Tímea; Fekete, Zoltán; Szabó-Révész, Piroska; Aigner, Zoltán

    2015-01-15

    The parameters of crystallization processes determine the habit and particle size distribution of the products. A narrow particle size distribution and a small average particle size are crucial for the bioavailability of poorly water-soluble pharmacons. Thus, particle size reduction is often required during crystallization processes. Impinging jet crystallization is a method that results in a product with a reduced particle size due to the homogeneous and high degree of supersaturation at the impingement point. In this work, the applicability of the impinging jet technique as a new approach in crystallization was investigated for the antisolvent crystallization of glycine. A factorial design was applied to choose the relevant crystallization factors. The results were analysed by means of a statistical program. The particle size distribution of the crystallized products was investigated with a laser diffraction particle size analyser. The roundness and morphology were determined with the use of a light microscopic image analysis system and a scanning electron microscope. Polymorphism was characterized by differential scanning calorimetry and powder X-ray diffraction. Headspace gas chromatography was utilized to determine the residual solvent content. Impinging jet crystallization proved to reduce the particle size of glycine. The particle size distribution was appropriate, and the average particle size was an order of magnitude smaller (d(0.5)=8-35 μm) than that achieved with conventional crystallization (d(0.5)=82-680 μm). The polymorphic forms of the products were influenced by the solvent ratio. The quantity of residual solvent in the crystallized products was in compliance with the requirements of the International Conference on Harmonization.

  14. METHODS OF RECEIVING OF FINE-GRAINED STRUCTURE OF CASTINGS AT CRYSTALLIZATION

    Directory of Open Access Journals (Sweden)

    N. K. Tolochko

    2012-01-01

    Full Text Available The article deals with methods for fine-grained structure of ingots during crystallization depending on the used foundry technologies. It is shown that by using modern scientific and technological advances may improve the traditional and the development of new casting processes, providing production of cast parts with over fine-grained structure and enhanced properties.

  15. Grain-size effects on thermal properties of BaTiO3 ceramics

    Indian Academy of Sciences (India)

    C J Xiao; Z X Li; X R Deng

    2011-07-01

    Dense nanocrystalline BaTiO3 ceramics are successfully prepared by the high pressure assisted sintering. Microstructures are observed by scanning electronic microscopes. The grain sizes are estimated to be about 30 and 150 nm. In comparison, BaTiO3 ceramics with the grain size of 600 nm and 1.5 m are fabricated by conventional pressure-less sintering. The thermal properties of BaTiO3 ceramics with different grain sizes are investigated by differential scanning calorimetry and thermal expansion. The results suggest that the enthalpy values for the tetragonal-cubic transition decreased and the thermal expansion values increased with decreasing grain size. Furthermore, the Curie temperature shifts to lower temperature with decreasing grain size.

  16. Effect of Grain Size on Mechanical Properties of Nickel-Free High Nitrogen Austenitic Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    LI Hua-bing; JIANG Zhou-hua; ZHANG Zu-rui; YANG Yan

    2009-01-01

    The fine grained structures of nickel-free high nitrogen austenitic stainless steels had been obtained by means of cold rolling and subsequent annealing.The relationship between microstructure and mechanical properties and gain size of nickel-free high nitrogen austenitic stainless steels was examined.High strength and good ductility of the steel were found.In the grain size range,the Hall-Petch dependency for yield stress,tensile strength,and hardness was valid for grain size ranges for the nickel-free high nitrogen austenitic stainless steel.In the present study,the ductility of cold rolled nickel-free high nitrogen austenitic stainless steel decreased with annealing time when the grain size was refined.The fracture surfaces of the tensile specimens in the grain size range were covered with dimples as usually seen in a ductile fracture mode.

  17. A new method to determine the grain size of planetary regolith

    CERN Document Server

    Gundlach, Bastian

    2012-01-01

    Airless planetary bodies are covered by a dusty layer called regolith. The grain size of the regolith determines the temperature and the mechanical strength of the surface layers. Thus, knowledge of the grain size of planetary regolith helps to prepare future landing and/or sample-return missions. In this work, we present a method to determine the grain size of planetary regolith by using remote measurements of the thermal inertia. We found that small bodies in the Solar System (diameter less than ~100 km) are covered by relatively coarse regolith grains with typical particle sizes in the millimeter to centimeter regime, whereas large objects possess very fine regolith with grain sizes between 10 and 100 micrometer.

  18. Grain size, stress and creep in polycrystalline solids

    CSIR Research Space (South Africa)

    Nabarro, FRN

    2000-08-01

    Full Text Available ?Herring sources within the grain and the annihilation of dislocation pairs under their mutual attraction. This process occurs and Harper?Dorn creep is possible if inequality (4) is satisfied. If the inequality is not satisfied, dislocations climb into the grain... by glide. If, in addition, inequality (5) is satisfied, disloca- tions will multiply by glide within the cell much more rapidly than they can annihilate by climb. Harper?Dorn creep gives way to power-law creep [9]. If the product L 1/2 s is less...

  19. Genetic dissection of grain size and grain number trade-offs in CIMMYT wheat germplasm.

    Directory of Open Access Journals (Sweden)

    Simon Griffiths

    Full Text Available Grain weight (GW and number per unit area of land (GN are the primary components of grain yield in wheat. In segregating populations both yield components often show a negative correlation among themselves. Here we use a recombinant doubled haploid population of 105 individuals developed from the CIMMYT varieties Weebill and Bacanora to understand the relative contribution of these components to grain yield and their interaction with each other. Weebill was chosen for its high GW and Bacanora for high GN. The population was phenotyped in Mexico, Argentina, Chile and the UK. Two loci influencing grain yield were indicated on 1B and 7B after QTL analysis. Weebill contributed the increasing alleles. The 1B effect, which is probably caused by to the 1BL.1RS rye introgression in Bacanora, was a result of increased GN, whereas, the 7B QTL controls GW. We concluded that increased in GW from Weebill 7B allele is not accompanied by a significant reduction in grain number. The extent of the GW and GN trade-off is reduced. This makes this locus an attractive target for marker assisted selection to develop high yielding bold grain varieties like Weebill. AMMI analysis was used to show that the 7B Weebill allele appears to contribute to yield stability.

  20. Genetic dissection of grain size and grain number trade-offs in CIMMYT wheat germplasm.

    Science.gov (United States)

    Griffiths, Simon; Wingen, Luzie; Pietragalla, Julian; Garcia, Guillermo; Hasan, Ahmed; Miralles, Daniel; Calderini, Daniel F; Ankleshwaria, Jignaben Bipinchandra; Waite, Michelle Leverington; Simmonds, James; Snape, John; Reynolds, Matthew

    2015-01-01

    Grain weight (GW) and number per unit area of land (GN) are the primary components of grain yield in wheat. In segregating populations both yield components often show a negative correlation among themselves. Here we use a recombinant doubled haploid population of 105 individuals developed from the CIMMYT varieties Weebill and Bacanora to understand the relative contribution of these components to grain yield and their interaction with each other. Weebill was chosen for its high GW and Bacanora for high GN. The population was phenotyped in Mexico, Argentina, Chile and the UK. Two loci influencing grain yield were indicated on 1B and 7B after QTL analysis. Weebill contributed the increasing alleles. The 1B effect, which is probably caused by to the 1BL.1RS rye introgression in Bacanora, was a result of increased GN, whereas, the 7B QTL controls GW. We concluded that increased in GW from Weebill 7B allele is not accompanied by a significant reduction in grain number. The extent of the GW and GN trade-off is reduced. This makes this locus an attractive target for marker assisted selection to develop high yielding bold grain varieties like Weebill. AMMI analysis was used to show that the 7B Weebill allele appears to contribute to yield stability.

  1. Metal-assisted chemical etching of CIGS thin films for grain size analysis

    Energy Technology Data Exchange (ETDEWEB)

    Xue, Chaowei [Research and Development Centre, Hanergy Thin Film Power Group Limited, Chengdu (China); Loi, Huu-Ha; Duong, Anh; Parker, Magdalena [Failure Analysis Department, MiaSole Hi-Tech Corp., Santa Clara, CA (United States)

    2016-09-15

    Grain size of the CIGS absorber is an important monitoring factor in the CIGS solar cell manufacturing. Electron backscatter diffraction (EBSD) analysis is commonly used to perform CIGS grain size analysis in the scanning electron microscope (SEM). Although direct quantification on SEM image using the average grain intercept (AGI) method is faster and simpler than EBSD, it is hardly applicable on CIGS thin films. The challenge is that, not like polycrystalline silicon, to define grain boundaries by selective chemical etching is not easily realizable for the multi-component CIGS alloy. In this Letter, we present direct quantification of CIGS thin film grain size using the AGI method by developing metal-assisted wet chemical etching process to define CIGS grain boundaries. The calculated value is similar to EBSD result. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  2. Grain size distribution of quartz isolated from Chinese loess/paleosol

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Grain size distribution of bulk loess-paleosol and quartz chemically extracted from the loess/paleosol shows that mean size of the bulk samples is always finer than that of the quartz. The original aeolian depositions have been modified to various degrees by post-depositional weathering and pedogenic processes. The grain size distribution of the isolated quartz should be close to that of the primary aeolian sediment because the chemical pretreatment excludes secondary produced minerals. Therefore, the grain size of the quartz may be considered to more clearly reflect the variations of winter monsoon intensity.

  3. Grain Size Effect on Electrical Conductivity and Giant Magnetoresistance of Bulk Magnetic Polycrystals

    Institute of Scientific and Technical Information of China (English)

    LUO Wei; ZHU Lin-Li; ZHENG Xiao-Jing

    2009-01-01

    By solving the Boltzmann transport equation and considering the spin-dependent grain boundary scattering, the distribution of electrons in grains and the electrical transport properties in the applied magnetic field are studied. With regard to the dominant influence of grain boundary scattering which is taken as a boundary condi-tion for the electrical transport, the grain size-dependent electrical conductivity is investigated. In addition, the reorientation of the relative magnetization between grains brings the change of the electron spin when the magne-tonanocrystalline material is subjected to the magnetic field, resulting in the remarkable giant magnetoresistance effect.

  4. A statistical mixture model for estimating the proportion of unreduced pollen grains in perennial ryegrass (Lolium perenne L.) via the size of pollen grains

    NARCIS (Netherlands)

    Jansen, R.C.; Nijs, A.P.M. den

    1993-01-01

    The size of pollen grains is commonly used to indicate the ploidy level of pollen grains. In this paper observations of the diameter of pollen grains are evaluated from one diploid accession of perennial ryegrass (Lolium perenne L.), which was expected to produce diploid (unreduced) pollen grains in

  5. Investigating feedback mechanisms between stress and grain-size: preliminary findings from finite-element modelling

    Science.gov (United States)

    Cross, A. J.; Prior, D. J.; Ellis, S. M.

    2012-12-01

    It is widely accepted that changes in stress and grain size can induce a switch between grain-size insensitive (GSI) and sensitive (GSS) creep mechanisms. Under steady-state conditions, grains evolve to an equilibrium size in the boundary region between GSS and GSI, described by the paleopiezometer for a given material. Under these conditions, significant rheological weakening is not expected, as grain size reduction processes are balanced by grain growth processes. However, it has been shown that the stress field surrounding faults varies through the seismic cycle, with both rapid loading and unloading of stress possible in the co- and post-seismic stages. We propose that these changes in stress in the region of the brittle-ductile transition zone may be sufficient to force a deviation from the GSI-GSS boundary and thereby cause a change in grain size and creep mechanism prior to system re-equilibration. Here we present preliminary findings from numerical modelling of stress and grain size changes in response to loading of mechanical inhomogeneities. Our results are attained using a grain-size evolution (GSE) subroutine incorporated into the SULEC finite-element code developed by Susan Ellis and Susanne Buiter, which utilises an iterative approach of solving for spatial and temporal changes in differential stress, grain size and active creep mechanism. Preliminary models demonstrate that stress changes in response to the opening of a fracture in a flowing medium can be significant enough to cause a switch from GSI to GSS creep. These results are significant in the context of understanding spatial variations and feedback between stress, grain size and deformation mechanisms through the seismic cycle.

  6. Size Matters: FTIR Spectral Analysis of Apollo Regolith Samples Exhibits Grain Size Dependence.

    Science.gov (United States)

    Martin, Dayl; Joy, Katherine; Pernet-Fisher, John; Wogelius, Roy; Morlok, Andreas; Hiesinger, Harald

    2017-04-01

    The Mercury Thermal Infrared Spectrometer (MERTIS) on the upcoming BepiColombo mission is designed to analyse the surface of Mercury in thermal infrared wavelengths (7-14 μm) to investigate the physical properties of the surface materials [1]. Laboratory analyses of analogue materials are useful for investigating how various sample properties alter the resulting infrared spectrum. Laboratory FTIR analysis of Apollo fine (60%) causes a 'flattening' of the spectrum, with reduced reflectance in the Reststrahlen Band region (RB) as much as 30% in comparison to samples that are dominated by a high proportion of crystalline material. Apollo 15401,147 is an immature regolith with a high proportion of volcanic glass pyroclastic beads [2]. The high mafic mineral content results in a systematic shift in the Christiansen Feature (CF - the point of lowest reflectance) to longer wavelength: 8.6 μm. The glass beads dominate the spectrum, displaying a broad peak around the main Si-O stretch band (at 10.8 μm). As such, individual mineral components of this sample cannot be resolved from the average spectrum alone. Apollo 67481,96 is a sub-mature regolith composed dominantly of anorthite plagioclase [2]. The CF position of the average spectrum is shifted to shorter wavelengths (8.2 μm) due to the higher proportion of felsic minerals. Its average spectrum is dominated by anorthite reflectance bands at 8.7, 9.1, 9.8, and 10.8 μm. The average reflectance is greater than the other samples due to a lower proportion of glassy material. In each soil, the smallest fractions (0-25 and 25-63 μm) have CF positions 0.1-0.4 μm higher than the larger grain sizes. Also, the bulk-sample spectra mostly closely resemble the 0-25 μm sieved size fraction spectrum, indicating that this size fraction of each sample dominates the bulk spectrum regardless of other physical properties. This has implications for surface analyses of other Solar System bodies where some mineral phases or components

  7. ON ESTIMATION AND HYPOTHESIS TESTING OF THE GRAIN SIZE DISTRIBUTION BY THE SALTYKOV METHOD

    Directory of Open Access Journals (Sweden)

    Yuri Gulbin

    2011-05-01

    Full Text Available The paper considers the problem of validity of unfolding the grain size distribution with the back-substitution method. Due to the ill-conditioned nature of unfolding matrices, it is necessary to evaluate the accuracy and precision of parameter estimation and to verify the possibility of expected grain size distribution testing on the basis of intersection size histogram data. In order to review these questions, the computer modeling was used to compare size distributions obtained stereologically with those possessed by three-dimensional model aggregates of grains with a specified shape and random size. Results of simulations are reported and ways of improving the conventional stereological techniques are suggested. It is shown that new improvements in estimating and testing procedures enable grain size distributions to be unfolded more efficiently.

  8. Effects of grain size on the quasi-static mechanical properties of ultrafine-grained and nanocrystalline tantalum

    Science.gov (United States)

    Ligda, Jonathan Paul

    The increase in strength due to the Hall-Petch effect, reduced strain hardening capacity, a reduced ductility, and changes in deformation mechanisms are all effects of reducing grain size (d) into the ultrafine-grained (UFG, 100 replacement for depleted uranium in kinetic energy penetrators. However, an ideal replacement material must also plastically deform in tension under quasi-static rates to survive initial launch conditions. This raises the question: if the material forms ASBs at dynamic rates, will it also form shear bands at quasi-static isothermal rates? As well as, is there a specific grain size for a material that will plastically deform in tension at quasi-static rates but form adiabatic shear bands at dynamic rates? Using high pressure torsion, a polycrystalline bulk tantalum disk was refined into the UFG/NC regime. Using microscale mechanical testing techniques, such as nanoindentation, microcompression, and microtension, it is possible to isolate locations with a homogeneous grain size within the disk. Pillars are compressed using a nanoindenter with a flat punch tip, while "dog-bone" specimens were pulled in tension using a custom built in-situ tension stage within a scanning electron microscope (SEM). The observed mechanical behavior is related to the microstructure by using transmission electron microscopy (TEM) on the as-processed material and tested specimens. Synchrotron X-ray based texture analysis was also conducted on the disk to determine if any changes in the deformation texture occur during HPT processing. Nanoindentation data shows a trend of increasing hardness with radial position that saturates at 4.5 GPa near the edge, and decreasing strain rate sensitivity. The micromechanical tests show two distinct regions on a processed circular disk, a non-shearing region and a shearing region. Microcompression/tension tests in the region of 1.0 5.3 mm show a drastic switch to localized plastic deformation in the form of shear bands, with

  9. Analysis of submicron-sized niflumic acid crystals prepared by electrospray crystallization.

    Science.gov (United States)

    Ambrus, Rita; Radacsi, Norbert; Szunyogh, Tímea; van der Heijden, Antoine E D M; Ter Horst, Joop H; Szabó-Révész, Piroska

    2013-03-25

    Interest in submicron-sized drug particles has emerged from both laboratory and industrial perspectives in the last decade. Production of crystals in the nano size scale offers a novel way to particles for drug formulation solving formulation problems of drugs with low solubility in class II of the Biopharmaceutical Classification System. In this work niflumic acid nanoparticles with a size range of 200-800nm were produced by the novel crystallization method, electrospray crystallization. Their properties were compared to those from evaporative and anti-solvent crystallizations, using the same organic solvent, acetone. There is a remarkable difference in the product crystal size depending on the applied methods. The size and morphology were analyzed by scanning electron microscopy and laser diffraction. The structure of the samples was investigated using differential scanning calorimetry, Fourier-transformed infrared spectroscopy and X-ray powder diffraction. The particles produced using electrospray crystallization process were probably changing from amorphous to crystalline state after the procedure.

  10. The effect of grain size on dynamic tensile extrusion behaviour

    Directory of Open Access Journals (Sweden)

    Park Leeju

    2015-01-01

    Full Text Available Dynamic tensile extrusion (DTE tests were conducted on coarse grained and ultrafine grained (UFG OFHC Cu, Interstitial free (IF Steel, and pure Ta. Equal channel angular pressing (ECAP of 16passes with Bc for Cu, IF Steel and 4 passes for Ta was employed to fabricated UFG materials. DTE tests were carried out by launching the sphere samples (Dia. 7.62 mm to the conical extrusion die at a speed of ∼500 m/sec. The fragmentation behavior of the soft-recovered fragments were examined and compared with each other. The DTE fragmentation behavior of CG and UFG was numerically simulated by the LS-DYNA FEM code.

  11. Geochemical indicator of original eolian grain size and implications on winter monsoon evolution

    Institute of Scientific and Technical Information of China (English)

    彭淑贞; 郭正堂

    2001-01-01

    Grain size of eolian deposits from the Loess Plateau in China has been widely used to reconstruct the history of the East Asian winter monsoon. However, the grain size of bulk samples is only partially indicative to the strength of the winter monsoon because post-depositional weathering processes have significantly changed the grain size of original eolian particles. Here, non-weathered loess samples were separated into eight different particle fractions, and major chemical elements were determined in order to establish a geochemical indicator of original eolian grain size. The results show that SiO2and AI2O3contents and the SiO2/AI203 ratio in different fractions vary regularly with grain size, and that a good linear relation exists between the SiO2/AI2O3 ratio and grain size for the fractions<50μm. Because Al and Si are among the most stable elements and pedogenic processes in the Loess Plateau cannot affect the SiO2/AI2O3 ratio, this index can be used to reflect the grain size of original eolian part

  12. Study on pore characteristics and microstructure of sandstones with different grain sizes

    Science.gov (United States)

    Li, Huigui; Li, Huamin; Gao, Baobin; Wang, Wen; Liu, Chuang

    2017-01-01

    The grain sizes have a pronounced influence on the pore characteristics and microstructure of sandstone. This work examined the pore structure and characteristics of three kinds of sandstones with different grain sizes using the scanning electron microscopy (SEM) and nuclear magnetic resonance (NMR) methods and analyzed their grain size distributions, pore size distributions, T2-distributions, and porosity variations. The experimental results showed that sandstones with different grain sizes have significant differences in the microstructures grain size distribution, pore size distribution, T2-distribution, and porosity variation. The results show that coarse, medium and fine sandstones have two peaks in T2-distributions, mean grain size of 398.5, 145.1 and 25.1 μm, respectively, mean pore size of 46.3, 25.9, and 8.4 μm, respectively, porosity of 7.52%, 5.88% and 1.55%, respectively, indicating that both coarse and medium sandstones contain big pores, while fine sandstone contains small pores. This study is of significance for understanding of water migration characteristics in aquifers and gas in coal seams after the working face exploitation.

  13. Grain size evolution in the mantle and its effect on geodynamics, seismic velocities and attenuation

    Science.gov (United States)

    Dannberg, Juliane; Eilon, Zach; Gassmoeller, Rene; Moulik, Pritwiraj; Myhill, Robert; Faul, Ulrich; Asimow, Paul

    2015-04-01

    Dynamic models of Earth's convecting mantle usually implement flow laws with constant grain size, stress-independent viscosity and a limited treatment of variations associated with changes in mineral assemblage. These simplifications greatly reduce computational requirements but preclude effects such as shear localisation and transient changes in rheology associated with phase transitions, which have the potential to fundamentally change flow patterns in the mantle. Here we use the finite-element code ASPECT (Bangerth et al., 2013) to model grain size evolution and the interplay between grain size, stress and strain rate in the convecting mantle. We include the simultaneous and competing effects of dynamic recrystallisation resulting from work done by dislocation creep, grain growth in multiphase assemblages and recrystallisation at phase transitions. Grain size variations also affect seismic properties of mantle materials. We use several published formulations to relate intrinsic variables (P, T, and grain size) from our numerical models to seismic velocity (Vs) and attenuation (Q). Our calculations use thermodynamically self-consistent anharmonic elastic moduli determined for the mineral assemblages in the mantle using HeFESTo (Stixrude and Lithgow-Bertelloni, 2013). We investigate the effect of realistically heterogeneous grain sizes by computing body wave travel times, ray paths, and attenuation (t*) at different frequencies. We highlight the frequency-dependent sensitivity of seismic waves to grain size, which is important when interpreting Vs and Q observations in terms of mineral assemblage and temperature. Our models show that rapid metamorphic reactions in mantle upwellings and downwellings lead to high lateral viscosity contrasts, as a result of gradual grain size evolution. Positive feedback between grain size reduction and viscosity reduction results in shear localisation. As a result, the edges of thermal plumes have smaller grain sizes and lower

  14. Growth of centimeter-sized C60 single crystals

    Institute of Scientific and Technical Information of China (English)

    李宏年; 徐亚伯; 张建华; 何丕模; 李海洋; 吴太权; 鲍世宁

    2001-01-01

    C60 single crystals larger than one centimeter in size are grown with vapor method by nucleation control and by a proper time-dependent temperature process which allows only one nucleus growing larger and larger. X-ray diffraction patterns exhibit the high quality of the sample. As an example of the applications of large single C60 crystals,svnchrotron radiation photoemission spectra are measured to investigate the fine structure of valence bands of C60 crystals.

  15. The Role of Grain Size and Shape on the Electrical Conductivity of Volcanic Ash

    Science.gov (United States)

    Woods, T.; Genareau, K. D.; Cloer, S.

    2016-12-01

    Volcanic lightning is a common, yet understudied, phenomenon. The exact mechanisms of electric charge generation and transmission in explosive eruption plumes are poorly understood. Ash is a probable charge carrier, and thus, the physical properties of ash may factor into charge generation and transmission. Specifically, the shape and size of ash grains, volatiles bound within the grains, and the efficiency of grains to act as ice nuclei may be contributing factors. To examine the relationship between conductivity and grain size/shape, this research compares conductivity measurements to grain size distribution and shape from five minimally processed ash samples collected from explosive eruptions in Alaska, U.S.A. (Katmai, 1912; Crater Peak, 1992; Augustine, 2006; Okmok, 2008; Redoubt, 2009) that produced volcanic lightning and a set of homogenized (with respect to grain size and shape) ash samples from Lathrop Wells (Nevada, U.S.A.), Taupo (New Zealand), and the Valles Caldera (New Mexico, U.S.A.). Grain size distribution was measured using a laser diffractometer particle size analyzer and grain shapes (aspect ratios, concavity indices) were characterized using backscattered electron images that were processed with ImageJ freeware. The resistance of minimally compressed samples was measured using a current amplifier and converted to conductivity. A general effective media (GEM) equation was then applied using the assumption that the grains are oblate ellipsoids under the influence of minimal compaction. Preliminary analyses suggest that compaction, and therefore shape and contact points, controls ash conductivity and not bulk composition, as homogenized samples provide variable resistance measurements from 1.6 x 10-3 to 9.9 x 10-1 S/m. Non-homogenized Alaskan samples are hypothesized to have higher concavity indices and conductivities when compared to the homogenized samples, due to wider variations in grain size and shape, and these data will be presented.

  16. Measurement and Simulation of Grain Size in Strong Textured and Coarse-Grained Metal Sheets

    Institute of Scientific and Technical Information of China (English)

    Leng CHEN; Weimin MAO; Yongning YU; Huiping FENG

    2003-01-01

    An X-ray diffractometer that equipped with a two-dimensional detector is used for developing the technique of grainsize measurement for strong textured and coarse-grained Si steel sheet. The method is based on the concept thatthe position of diffraction s

  17. Systematic Modelling and Crystal Size Distribution Control for Batch Crystallization Processes

    DEFF Research Database (Denmark)

    Abdul Samad, Noor Asma Fazli; Singh, Ravendra; Sin, Gürkan

    Crystallization processes form an important class of separation methods that are frequently used in the chemical, the pharmaceutical and the food industry. The specifications of the crystal product are usually given in terms of crystal size, shape and purity. In order to predict the desired cryst...

  18. Influence of Grain Size on Electrical and Optical Properties of InP Films

    Institute of Scientific and Technical Information of China (English)

    Mustafa (O)ztas

    2008-01-01

    InP film samples were prepared by spray pyrolysis technique using aqueous solutions of lnCl3 and Na2HPO4,which were atomized with compressed air as carrier gas onto glass substrates at 500℃ with different thicknesses of the films. It is found that the resistivity of the polycrystalline films strongly depends on the grain size. It is observed that the grain size of the films increase with the decrease of the energy band gap and strain of the film.The changes observed in the energy band gap and strain related to the film grain size of the films are discussed in detail.

  19. Grain-Size-Limited Mobility in Methylammonium Lead Iodide Perovskite Thin Films

    Energy Technology Data Exchange (ETDEWEB)

    Reid, Obadiah G.; Yang, Mengjin; Kopidakis, Nikos; Zhu, Kai; Rumbles, Garry

    2016-09-09

    We report a systematic study of the gigahertz-frequency charge carrier mobility found in methylammonium lead iodide perovskite films as a function of average grain size using time-resolved microwave conductivity and a single processing chemistry. Our measurements are in good agreement with the Kubo formula for the AC mobility of charges confined within finite grains, suggesting (1) that the surface grains imaged via scanning electron microscopy are representative of the true electronic domain size and not substantially subdivided by twinning or other defects not visible by microscopy and (2) that the time scale of diffusive transport across grain boundaries is much slower than the period of the microwave field in this measurement (-100 ps). The intrinsic (infinite grain size) minimum mobility extracted form the model is 29 +/- 6 cm2 V-1 s-1 at the probe frequency (8.9 GHz).

  20. Intensity and degree of segregation in bimodal and multimodal grain size distributions

    Science.gov (United States)

    Katra, Itzhak; Yizhaq, Hezi

    2017-08-01

    The commonly used grain size analysis technique which applies moments (sorting, skewness and kurtosis) is less useful in the case of sediments with bimodal size distributions. Herein we suggest a new simple method for analyzing the degree of grain size segregation in sand-sized sediment that has clear bimodal size distributions. Two main features are used to characterize the bimodal distribution: grain diameter segregation, which is the normalized difference between coarse and fine grain diameters, and the frequency segregation which is the normalized difference in frequencies between two modes. The new defined indices can be calculated from frequency plot curves and can be graphically represented on a two dimensional coordinate system showing the dynamical aspects of the size distribution. The results enable comparison between granular samples from different locations and/or times to shed new light on the dynamic processes involved in grain size segregation of sediments. We demonstrate here the use of this method to analyze bimodal distributions of aeolian granular samples mostly from aeolian megaripples. Six different aeolian cases were analyzed to highlight the method's applicability, which is relevant to wide research themes in the Earth and environmental sciences, and can furthermore be easily adapted to analyze polymodal grain size distributions.

  1. Relationship between ferromagnetic properties and grain size of Inconel alloy 600

    Energy Technology Data Exchange (ETDEWEB)

    Kikuchi, H., E-mail: hkiku@iwate-u.ac.jp; Takahashi, H.; Yanagiwara, H.; Murakami, T.

    2015-05-01

    Inconel alloy 600 is widely used in steam generator tubings where sensitization due to chromium depletion occurs at grain boundaries and the sensitization induces tubing failures. Though the alloy usually exhibits paramagnetic properties, it shows ferromagnetic properties along grain boundaries when chromium depletion occurs. This means that magnetic nondestructive evaluation of sensitization is possible. Therefore, as a fundamental study to develop magnetic nondestructive evaluation technique for sensitization, the relationship between ferromagnetic properties and grain size in Inconel 600 was investigated using isothermal heat treatment. The grain was controlled using solution annealing, and then, specimens were heat treated at 873, 923, and 973 K within 400 h. The saturation magnetization increases as heat treatment time increases and eventually peaks. The peak time depends on the heat treatment temperature. The coercivity increases during the initial heat treatment stage, and decreases as the duration of heat treatment increases. The maximum saturation magnetization decreases as the grain diameter increases and is inversely proportional to the grain diameter squared, which is consistent with the fact that the ferromagnetic phase only formed along grain boundaries. - Highlights: • Relationship between ferromagnetism and grain size in Inconel 600 was clarified. • The saturation magnetization increases and eventually peaks during heat treatment. • The coercivity increases during the initial heat treatment stage, and then decreases. • The saturation magnetization is inversely proportional to the grain diameter squared. • The magnetic property changes are explained by the Cr depletion at grain boundaries.

  2. AUTOMATED DETERMINATION OF THE CRYSTALS SIZE IN ELECTRODEPOSITED METAL MATERIALS

    Directory of Open Access Journals (Sweden)

    E. V. Kolesnik

    2014-01-01

    Full Text Available Methods of automated determination of the crystals size in the electrodeposited metal materials including digital processing of the electronicand microscopic image of the structure with sequential use of the low-and-high-leaky filter based on fast transformation of Fourier, Watershed-algorithm and decomposing of Voronoj with further measurement of thr crystal size with one of the traditional methods is offered.

  3. The role of grain-size ratio in the mobility of mixed granular beds

    Science.gov (United States)

    Staudt, Franziska; Mullarney, Julia C.; Pilditch, Conrad A.; Huhn, Katrin

    2017-02-01

    The main goal of the study was to understand the effects of grain-size distribution on the stability of beds in the sand-silt range, which is a critical subject for the understanding of geomorphological processes in aquatic environments. Although theoretical models can explain the mobilization of a mixed bed, there is a clear lack in knowledge regarding the stabilizing effect of non-cohesive fine material. To connect existing findings, we analysed bed stability in relation to grain-size distribution in laboratory experiments. Erosion experiments in an annular flume were conducted using beds of different size compositions of spherical glass beads, i.e. a) the grain-size ratio RD = D50,coarse/D50,fine (the relative size of coarse and fine grains; D50 = 39-367 μm) and b) the amount of fines. Several glass-bead combinations with unimodal and bimodal grain-size distributions (RD = 3.9, 5.8, and 9.4) and varying fine fractions (10-40% dry weight) were subjected to increasing flow speeds (0.01-0.19 m s-1). Using acoustic Doppler velocimetry (ADV) and optical backscatter, the flow profile in the vicinity of the bed surface, the changes in bed morphology, and the suspended sediment concentration (SSC) were measured. A new method was developed to evaluate the bed-level changes detected by the ADV as a proxy for the bed mobility. We found different modes of bed mobility depending on the grain-size ratio. For low grain-size ratios, an increase in the fine fraction (to 40%) led to increased bed-level changes during the experiment and the mobilization of the mixed bed at the highest flow speed. For high ratios an increase in fine fraction (to 40%) led to a decrease of bed-level changes and the beds remained stable, i.e. no bed forms developed even at the highest flow speed. Therefore, increasing the amount of fine particles can lead to different modes of behaviour depending on the grain-size ratio. For a bimodal sediment bed with spherical grains under unidirectional flow

  4. Location and sizes of forsterite grains in protoplanetary disks: Interpretation from the Herschel DIGIT programme

    NARCIS (Netherlands)

    K.M. Maaskant; B.L. de Vries; M. Min; L.B.F.M. Waters; C. Dominik; F. Molster; A.G.G.M. Tielens

    2015-01-01

    Context. The spectra of protoplanetary disks contain mid- and far- infrared emission features produced by forsterite dust grains. The spectral features contain information about the forsterite temperature, chemical composition and grain size. Aims. We aim to characterize how the 23 and 69 μm feature

  5. Millimeter-sized grains in the protostellar envelopes: Where do they come from?

    Science.gov (United States)

    Wong, Yi Hang Valerie; Hirashita, Hiroyuki; Li, Zhi-Yun

    2016-08-01

    Grain growth during star formation affects the physical and chemical processes in the evolution of star-forming clouds. We investigate the origin of the millimeter (mm)-sized grains recently observed in Class I protostellar envelopes. We use the coagulation model developed in our previous paper and find that a hydrogen number density of as high as 1010 cm-3, instead of the typical density 105 cm-3, is necessary for the formation of mm-sized grains. Thus, we test a hypothesis that such large grains are transported to the envelope from the inner, denser parts, finding that gas drag by outflow efficiently "launches" the large grains as long as the central object has not grown to ≳0.1 M⊙. By investigating the shattering effect on the mm-sized grains, we ensure that the large grains are not significantly fragmented after being injected in the envelope. We conclude that the mm-sized grains observed in the protostellar envelopes are not formed in the envelopes but formed in the inner parts of the star-forming regions and transported to the envelopes before a significant mass growth of the central object, and that they survive in the envelopes.

  6. Millimeter-sized grains in the protostellar envelopes: where do they come from?

    CERN Document Server

    Wong, Yi Hang Valerie; Li, Zhi-Yun

    2016-01-01

    Grain growth during star formation affects the physical and chemical processes in the evolution of star-forming clouds. We investigate the origin of the millimeter (mm)-sized grains recently observed in Class I protostellar envelopes. We use the coagulation model developed in our previous paper and find that a hydrogen number density of as high as $10^{10}~{\\rm cm^{-3}}$, instead of the typical density $10^5~{\\rm cm^{-3}}$, is necessary for the formation of mm-sized grains. Thus, we test a hypothesis that such large grains are transported to the envelope from the inner, denser parts, finding that gas drag by outflow efficiently "launches" the large grains as long as the central object has not grown to $\\gtrsim 0.1$ M$_{\\odot}$. By investigating the shattering effect on the mm-sized grains, we ensure that the large grains are not significantly fragmented after being injected in the envelope. We conclude that the mm-sized grains observed in the protostellar envelopes are not formed in the envelopes but formed i...

  7. Size Distribution and Rate of Dust Generated During Grain Elevator Handling

    Science.gov (United States)

    Dust generated during grain handling is an air pollutant that produces safety and health hazards. This study was conducted to characterize the particle size distribution (PSD) of dust generated during handling of wheat and shelled corn in the research elevator of the USDA Grain Marketing and Product...

  8. Optical dating of single sand-sized grains of quartz: Sources of variability

    DEFF Research Database (Denmark)

    Duller, G.A.T.; Bøtter-Jensen, L.; Murray, A.S.

    2000-01-01

    Optically stimulated luminescence (OSL) measurements have been made of over 3000 sand-sized grains of quartz. Analysis at this scale highlights the variability in the luminescence sensitivity and the dose saturation characteristics of individual quartz grains. Using a new instrument capable of me...... intensity, dose saturation characteristics and instrument uncertainty in equivalent dose calculation. (C) 2000 Elsevier Science Ltd. All rights reserved....

  9. Transport, retention, and size perturbation of graphene oxide in saturated porous media: Effects of input concentration and grain size

    Science.gov (United States)

    Accurately predicting the fate and transport of graphene oxide (GO) in porous media is critical to assess its environmental impact. In this work, sand column experiments were conducted to determine the effect of input concentration and grain size on transport, retention, and size perturbation of GO ...

  10. On-line monitoring of the crystallization process: relationship between crystal size and electrical impedance spectra

    Science.gov (United States)

    Zhao, Yanlin; Yao, Jun; Wang, Mi

    2016-07-01

    On-line monitoring of crystal size in the crystallization process is crucial to many pharmaceutical and fine-chemical industrial applications. In this paper, a novel method is proposed for the on-line monitoring of the cooling crystallization process of L-glutamic acid (LGA) using electrical impedance spectroscopy (EIS). The EIS method can be used to monitor the growth of crystal particles relying on the presence of an electrical double layer on the charged particle surface and the polarization of double layer under the excitation of alternating electrical field. The electrical impedance spectra and crystal size were measured on-line simultaneously by an impedance analyzer and focused beam reflectance measurement (FBRM), respectively. The impedance spectra were analyzed using the equivalent circuit model and the equivalent circuit elements in the model can be obtained by fitting the experimental data. Two equivalent circuit elements, including capacitance (C 2) and resistance (R 2) from the dielectric polarization of the LGA solution and crystal particle/solution interface, are in relation with the crystal size. The mathematical relationship between the crystal size and the equivalent circuit elements can be obtained by a non-linear fitting method. The function can be used to predict the change of crystal size during the crystallization process.

  11. Modeling grain size variations of aeolian gypsum deposits at White Sands, New Mexico, using AVIRIS imagery

    Science.gov (United States)

    Ghrefat, H.A.; Goodell, P.C.; Hubbard, B.E.; Langford, R.P.; Aldouri, R.E.

    2007-01-01

    Visible and Near-Infrared (VNIR) through Short Wavelength Infrared (SWIR) (0.4-2.5????m) AVIRIS data, along with laboratory spectral measurements and analyses of field samples, were used to characterize grain size variations in aeolian gypsum deposits across barchan-transverse, parabolic, and barchan dunes at White Sands, New Mexico, USA. All field samples contained a mineralogy of ?????100% gypsum. In order to document grain size variations at White Sands, surficial gypsum samples were collected along three Transects parallel to the prevailing downwind direction. Grain size analyses were carried out on the samples by sieving them into seven size fractions ranging from 45 to 621????m, which were subjected to spectral measurements. Absorption band depths of the size fractions were determined after applying an automated continuum-removal procedure to each spectrum. Then, the relationship between absorption band depth and gypsum size fraction was established using a linear regression. Three software processing steps were carried out to measure the grain size variations of gypsum in the Dune Area using AVIRIS data. AVIRIS mapping results, field work and laboratory analysis all show that the interdune areas have lower absorption band depth values and consist of finer grained gypsum deposits. In contrast, the dune crest areas have higher absorption band depth values and consist of coarser grained gypsum deposits. Based on laboratory estimates, a representative barchan-transverse dune (Transect 1) has a mean grain size of 1.16 ??{symbol} (449????m). The error bar results show that the error ranges from - 50 to + 50????m. Mean grain size for a representative parabolic dune (Transect 2) is 1.51 ??{symbol} (352????m), and 1.52 ??{symbol} (347????m) for a representative barchan dune (Transect 3). T-test results confirm that there are differences in the grain size distributions between barchan and parabolic dunes and between interdune and dune crest areas. The t-test results

  12. Plasticity size effects in voided crystals

    DEFF Research Database (Denmark)

    Hussein, M. I.; Borg, Ulrik; Niordson, Christian Frithiof

    singularities in an elastic material. The lattice resistance to dislocation motion, dislocation nucleation, dislocation interaction with obstacles and annihilation are incorporated through a set of constitutive rules. Over the range of length scales investigated, both the discrete dislocation and strain...... predictions of the two formulations for all crystal types and void volume fractions considered when the material length scale in the non-local plasticity model chosen to be $0.325\\mu m$ (around ten times the slip plane spacing in the discrete dislocation models)....

  13. Plasticity size effects in voided crystals

    DEFF Research Database (Denmark)

    Hussein, M.I.; Borg, Ulrik; Niordson, Christian Frithiof

    2008-01-01

    as line singularities in an elastic material. The lattice resistance to dislocation motion, dislocation nucleation, dislocation interaction with obstacles and annihilation are incorporated through a set of constitutive rules. Over the range of length scales investigated, both the discrete dislocation...... between predictions of the two formulations for all crystal types and void volume fractions considered when the material length scale in the non-local plasticity model is chosen to be 0.325 mu m (about 10 times the slip plane spacing in the discrete dislocation models)....

  14. Grain size stabilization of tetragonal phase of zirconia in sputtered Zr- O cermet films

    Directory of Open Access Journals (Sweden)

    M. S. Hadavi

    2005-06-01

    Full Text Available  In this research, thin films of Zr/ZrO2 composites were deposited by reactive magnetron sputtering technique on Si and fused Silica substrates, and their structures were investigated by XRD method. During the deposition of the cermet layers, a Zr metallic target was sputtered in a gas mixture of Ar and O2. By controlling of O2 flow rate, the different metal volume fractions in the cermet layers were achieved. The optical response of the samples was studied using spectroscopy methods. Also the effect of vacuum annealing on the structures and the optical properties were studied. XRD results indicated that the prepared samples were amorphous and vacuum annealing induced crystallization in the cermet films. This research also showed that without doping, the tetragonal phase of zirconia can be stabilized at a temperature lower than the normal transition temperature. This is “grain size stabilization” and relates to the small size of the crystallites. In order to study the electron diffraction in the selected area patterns (SAD, the samples were analyzed by a high-resolution transmission microscope. The SAD results showed that all of the as prepared samples were amorphous showing evidence of very small Zr crystallites immersed in a dielectric medium.The SAD results are in close agreement with those obtained by XRD analysis.

  15. Diffusion of Oxygen Isotopes in Thermally Evolving Planetesimals and Size Ranges of Presolar Silicate Grains

    Science.gov (United States)

    Wakita, Shigeru; Nozawa, Takaya; Hasegawa, Yasuhiro

    2017-02-01

    Presolar grains are small particles found in meteorites through their isotopic compositions, which are considerably different from those of materials in the solar system. If some isotopes in presolar grains diffused out beyond their grain sizes when they were embedded in parent bodies of meteorites, their isotopic compositions could be washed out, and hence the grains could no longer be identified as presolar grains. We explore this possibility for the first time by self-consistently simulating the thermal evolution of planetesimals and the diffusion length of 18O in presolar silicate grains. Our results show that presolar silicate grains smaller than ˜0.03 μm cannot keep their original isotopic compositions even if the host planetesimals experienced a maximum temperature as low as 600 °C. Since this temperature corresponds to that experienced by petrologic type 3 chondrites, isotopic diffusion can constrain the size of presolar silicate grains discovered in such chondrites to be larger than ˜0.03 μm. We also find that the diffusion length of 18O reaches ˜0.3-2 μm in planetesimals that were heated up to 700-800°C. This indicates that, if the original size of presolar grains spans a range from ˜0.001 μm to ˜0.3 μm like that in the interstellar medium, then the isotopic records of the presolar grains may be almost completely lost in such highly thermalized parent bodies. We propose that isotopic diffusion could be a key process to control the size distribution and abundance of presolar grains in some types of chondrites.

  16. Condition for the formation of micron-sized dust grains in dense molecular cloud cores

    CERN Document Server

    Hirashita, Hiroyuki

    2013-01-01

    We investigate the condition for the formation of micron-sized grains in dense cores of molecular clouds. This is motivated by the detection of the mid-infrared emission from deep inside a number of dense cores, the so-called `coreshine,' which is thought to come from scattering by micron-sized grains. Based on numerical calculations of coagulation starting from the typical grain size distribution in the diffuse interstellar medium, we obtain a conservative lower limit to the time $t$ to form micron-sized grains: $t/t_\\mathrm{ff}>3 (5/S) (n_\\mathrm{H}/10^5 \\mathrm{cm}^{-3})^{-1/4}$ (where $t_\\mathrm{ff}$ is the free-fall time at hydrogen number density $n_\\mathrm{H}$ in the core, and $S$ the enhancement factor to the grain-grain collision cross-section to account for non-compact aggregates). At the typical core density $n_\\mathrm{H}=10^5 \\mathrm{cm}^{-3}$, it takes at least a few free-fall times to form the micron-sized grains responsible for coreshine. The implication is that those dense cores observed in co...

  17. Grain-size dynamics beneath mid-ocean ridges: Implications for permeability and melt extraction

    CERN Document Server

    Turner, Andrew J; Behn, Mark D

    2014-01-01

    Grain size is an important control on mantle viscosity and permeability, but is difficult or impossible to measure in situ. We construct a two-dimensional, single phase model for the steady-state mean grain size beneath a mid-ocean ridge. The mantle rheology is modelled as a composite of diffusion creep, dislocation creep, dislocation accommodated grain boundary sliding, and a plastic stress limiter. The mean grain size is calculated by the piezometric relationship of Austin and Evans [2007]. We investigate the sensitivity of our model to global variations in grain growth exponent, potential temperature, spreading-rate, and mantle hydration. We interpret the mean mean grain-size field in the context of permeability. The permeability structure due to mean grain size may be approximated as a high permeability region beneath a low permeability region. The transition between high and low permeability regions forms a boundary that is steeply sloped toward the ridge axis. We hypothesise that such a permeability str...

  18. Grain-size analysis of sediment cores collected in 2009 offshore from Palos Verdes, California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This part of the data release includes grain-size analysis of sediment cores collected in 2009 offshore of Palos Verdes, California. It is one of seven files...

  19. National Marine Fisheries Service Grain Size Data from the Baltimore Canyon Trough

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Grain size analyses produced by Robert Reid of the NOAA National Marine Fisheries Service for the NOAA/BLM Outer Continental Shelf Mid-Atlantic Project, Baltimore...

  20. Evaluating grain size in polycrystals with rough surfaces by corrected ultrasonic attenuation.

    Science.gov (United States)

    Li, Xiongbing; Han, Xiaoqin; Arguelles, Andrea P; Song, Yongfeng; Hu, Hongwei

    2017-02-27

    Surface roughness of a sample has a great effect on the calculated grain size when measurements are based on ultrasonic attenuation. Combining modified transmission and reflection coefficients at the rough interface with a Multi-Gaussian beam model of the transducer, a comprehensive correction scheme for the attenuation coefficient is developed. An approximate inverse model of the calculated attenuation, based on Weaver's diffuse scattering theory, is established to evaluate grain size in polycrystals. The experimental results showed that for samples with varying surface roughness and matching microstructures, the fluctuation of evaluated average grain size was ±1.17μm. For polished samples with different microstructures, the relative errors to optical microscopy were no more than ±3.61%. The presented method provides an effective nondestructive tool for evaluating the grain size in metals with rough surfaces.

  1. Grain size effect on magnetic and electric properties of LuMnO3 nanocrystalline materials

    Science.gov (United States)

    Han, Tai-Chun; Chen, Jia-Wern; Liu, Yuan-Hsun; Hu, Yu-Min

    2013-05-01

    Magnetic and electric properties are investigated for the nanosized LuMnO3 samples with different grain sizes (30 nm to 500 nm) synthesized by a modified Pechini method. It shows that magnetic and electric properties are strongly dependent on the grain size. The magnetic characterization indicates that with increasing grain size, the antiferromagnetic (AFM) transition temperature increases from 72 to 89 K. The temperature-dependent dielectric measurements show an anomaly in the dielectric constant at temperatures close to the AFM ordering temperature for all samples. A corresponding shift of the peak-positions of dielectric anomaly and magnetic ordering indicates a strong correlation between the magnetic ordering and the electric polarization. Further analysis suggests that the rising of AFM transition temperature with increasing grain size should be from the structural origin, in which the strength of AFM interaction as well as the electrical polarization is dependent on the in-plane lattice parameters.

  2. Laboratory Liquefaction Test of Sand Based on Grain Size and Relative Density

    Directory of Open Access Journals (Sweden)

    Abdul Hakam

    2016-08-01

    Full Text Available Liquefaction due to strong earthquakes often occurs in sandy soil under low water table conditions with certain physical properties. The physical properties of sandy soil that give effect to liquefaction resistance include grain size and relative density. This paper presents the physical properties of sand soils related to their resistance to vibration. Vibration tests were conducted by using a shaking table. The acceleration and settlement of the samples were recorded during shaking. The tests were conducted with variation of soil density and mean grain size. The test results showed that average grain size and relative density of sand have a unique effect on liquefaction resistance. It can be concluded that there is a density limit with respect to the mean grain size of the sand particles associated with the liquefaction resistance for a certain acceleration.

  3. Surface-sediment grain-size distributions from the Elwha River delta, Washington, July 2015

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This portion of the data release presents sediment grain-size data from samples collected on the Elwha River delta, Washington, between July and August 2015 (USGS...

  4. Surface-sediment grain-size distributions from the Elwha River delta, Washington, May 2014

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This portion of the data release presents sediment grain-size data from samples collected on the Elwha River delta, Washington, in May 2014 (USGS Field Activity...

  5. Surface-sediment grain-size distributions from the Elwha River delta, Washington, March 2013

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This portion of the data release presents sediment grain-size data from samples collected on the Elwha River delta, Washington, in March 2013 (USGS Field Activity...

  6. Surface-sediment grain-size distributions of the Elwha River delta, Washington, July 2016

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This portion of the data release presents sediment grain-size data from samples collected on the Elwha River delta, Washington, in July 2016 (USGS Field Activity...

  7. Surface-sediment grain-size distributions of the Elwha River delta, Washington, January 2015

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This portion of the data release presents sediment grain-size data from samples collected on the Elwha River delta, Washington, in January 2015 (USGS Field Activity...

  8. Surface-sediment grain-size distributions from the Elwha River delta, Washington, September 2013

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This portion of the data release presents sediment grain-size data from samples collected on the Elwha River delta, Washington, in September 2013 (USGS Field...

  9. Sediment grain size in the Elwha River estuary, Washington, from 2013 and 2014.

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This portion of the data release presents sediment grain-size data from samples collected in the Elwha River estuary, Washington, in July 2013 and June 2014 (USGS...

  10. Surface-sediment grain-size distributions from the Elwha River delta, Washington, September 2014

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This portion of the data release presents sediment grain-size data from samples collected on the Elwha River delta, Washington, in September 2014 (USGS Field...

  11. Surface-sediment grain-size distributions from the Elwha River delta, Washington, August 2012

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This portion of the data release presents sediment grain-size data from samples collected on the Elwha River delta, Washington, in August 2012 (USGS Field Activity...

  12. Geostatistical modeling of regionalized grain-size distributions using Min/Max Autocorrelation Factors

    National Research Council Canada - National Science Library

    Desbarats, A J

    2001-01-01

    .... Since the number of classes may be large and abundances in adjacent classes may be highly cross-correlated, practical simulation of regionalized grain-size distributions requires an efficient method...

  13. Measuring spatiotemporal variation in snow optical grain size under a subalpine forest canopy using contact spectroscopy

    National Research Council Canada - National Science Library

    Molotch, Noah P; Barnard, David M; Burns, Sean P; Painter, Thomas H

    2016-01-01

    .... In this study, we address one of many measurement gaps by using contact spectroscopy to measure snow optical grain size at high spatial resolution in trenches dug between tree boles in a subalpine forest...

  14. Grain Size Data from the NOAA Outer Continental Shelf Environmental Assessment Program (OCSEAP)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This data set contains grain size data from samples acquired under the NOAA Outer Continental Shelf Environmental Assessment Program (OCSEAP) from the Outer...

  15. Influence of austenite grain size on recrystallisation-precipitation interaction in a V-microalloyed steel

    Energy Technology Data Exchange (ETDEWEB)

    Quispe, A. [National University ' Jorge Basadre' , Av. Miraflores s/n, University City, Tacna (Peru)]. E-mail: abqc@unjbg.edu.pe; Medina, S.F. [National Center for Metallurgical Research (CENIM), Av. Gregorio del Amo 8, 28040-Madrid (Spain)]. E-mail: smedina@cenim.csic.es; Gomez, M. [National Center for Metallurgical Research (CENIM), Av. Gregorio del Amo 8, 28040-Madrid (Spain); Chaves, J.I. [National Center for Metallurgical Research (CENIM), Av. Gregorio del Amo 8, 28040-Madrid (Spain)

    2007-02-25

    By means of torsion tests using small specimens, the influence of austenite grain size on strain induced precipitation kinetics has been determined in a vanadium microalloyed steel. Determination of recrystallisation-precipitation-time-temperature (RPTT) diagrams for two austenite grain sizes allows values of the aforementioned magnitudes to be determined. An ample discussion is made of the quantitative influence found and its relation with nucleation and growth mechanisms of precipitates. The results are compared with the quantitative influence exerted by the other variables, reaching the conclusion that the austenite grain size has a notable influence on strain induced precipitation kinetics which should not be underestimated. Finally, the influence of austenite grain size is included in a strain induced precipitation model constructed by the authors of this work and which also takes into account the other aforementioned variables.

  16. Laboratory Application of Laser Grain-Size Analyzer in Determining Suspended Sediment Concentration

    Institute of Scientific and Technical Information of China (English)

    LIU Xiao; FENG Xiuli; LIU Jie; LIN Lin

    2014-01-01

    Suspended sediment concentration (SSC) is an important parameter in marine sedimentology. With the development of technology, many acoustic and optical devices, such as the Laser In-Situ Scattering and Transmissometry, have been designed to meas-ure in situ SSC and grain size distribution. But due to fund or other restrictions, many experiments were only conducted in laboratory, using an indoor laser grain-size analyzer and gravimetric method to measure grain size distribution and concentration, respectively. In this study the laboratory experiment is simplified by omitting the tiring step of gravimetric method. The connections between SSC and other parameters (obscuration, D50 and sorting index) were investigated based on 124 surface sediment samples collected from different offshore areas. A new method is developed for determining SSC in laboratory using a laser grain-size analyzer.

  17. How to form asteroids from mm-sized grains

    CERN Document Server

    Carrera, Daniel; Davies, Melvyn B

    2016-01-01

    The size distribution of asteroids in the solar system suggests that they formed top-down, with 100-1000 km bodies forming from the gravitational collapse of dense clumps of small solid particles. We investigate the conditions under which solid particles can form dense clumps in a protoplanetary disc. We used a hydrodynamic code to model the solid-gas interaction in disc. We found that particles down to millimeter size can form dense clumps, but only in regions where solids make $\\sim$ 8% of the local surface density. More generally, we mapped the range of particle sizes and concentrations that is consistent with the formation of particle clumps.

  18. Standard practice for determining average grain size using electron backscatter diffraction (EBSD) in fully recrystallized polycrystalline materials

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2010-01-01

    1.1 This practice is used to determine grain size from measurements of grain areas from automated electron backscatter diffraction (EBSD) scans of polycrystalline materials. 1.2 The intent of this practice is to standardize operation of an automated EBSD instrument to measure ASTM G directly from crystal orientation. The guidelines and caveats of E112 apply here, but the focus of this standard is on EBSD practice. 1.3 This practice is only applicable to fully recrystallized materials. 1.4 This practice is applicable to any crystalline material which produces EBSD patterns of sufficient quality that a high percentage of the patterns can be reliably indexed using automated indexing software. 1.5 The practice is applicable to any type of grain structure or grain size distribution. 1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.7 The values stated in inch-pound units are to be regarded as standard. The values given in parenthe...

  19. The influence of grain size, grain color, and suspended-sediment concentration on light attenuation: why fine-grained terrestrial sediment is bad for coral reef ecosystems

    Science.gov (United States)

    Storlazzi, Curt; Norris, Benjamin; Rosenberger, Kurt

    2015-01-01

    Sediment has been shown to be a major stressor to coral reefs globally. Although many researchers have tested the impact of sedimentation on coral reef ecosystems in both the laboratory and the field and some have measured the impact of suspended sediment on the photosynthetic response of corals, there has yet to be a detailed investigation on how properties of the sediment itself can affect light availability for photosynthesis. We show that finer-grained and darker-colored sediment at higher suspended-sediment concentrations attenuates photosynthetically active radiation (PAR) significantly more than coarser, lighter-colored sediment at lower concentrations and provide PAR attenuation coefficients for various grain sizes, colors, and suspended-sediment concentrations that are needed for biophysical modeling. Because finer-grained sediment particles settle more slowly and are more susceptible to resuspension, they remain in the water column longer, thus causing greater net impact by reducing light essential for photosynthesis over a greater duration. This indicates that coral reef monitoring studies investigating sediment impacts should concentrate on measuring fine-grained lateritic and volcanic soils, as opposed to coarser-grained siliceous and carbonate sediment. Similarly, coastal restoration efforts and engineering solutions addressing long-term coral reef ecosystem health should focus on preferentially retaining those fine-grained soils rather than coarse silt and sand particles.

  20. Grain size record of microparticles in the Muztagata ice core

    Institute of Scientific and Technical Information of China (English)

    WU; Guangjian; YAO; Tandong; XU; Baiqin; LI; Zheng; TIAN; Lide; DUAN; Keqin; WEN; Linke

    2006-01-01

    The dust transport and sediment characteristics are discussed based on analysis of microparticle size and size distribution in the Muztagata ice core at 6350 m a.s.l. The finer particles with diameter of 1―5μm are the dominant fraction in number, while middle and coarse particles mainly contribute to the total volume. The lognormal distribution characteristics can be seen for some high concentration samples, showing that model size and standard variation are greater than that in the Greenland ice cores. However, size-volume distribution of some low concentration samples is abnormal. Those distributions reflect the dust deposit process in high mountain glaciers at mid-low latitudes and show differences from those in polar ice sheet.

  1. Nano-scale machining of polycrystalline coppers - effects of grain size and machining parameters.

    Science.gov (United States)

    Shi, Jing; Wang, Yachao; Yang, Xiaoping

    2013-11-22

    In this study, a comprehensive investigation on nano-scale machining of polycrystalline copper structures is carried out by molecular dynamics (MD) simulation. Simulation cases are constructed to study the impacts of grain size, as well as various machining parameters. Six polycrystalline copper structures are produced, which have the corresponding equivalent grain sizes of 5.32, 6.70, 8.44, 13.40, 14.75, and 16.88 nm, respectively. Three levels of depth of cut, machining speed, and tool rake angle are also considered. The results show that greater cutting forces are required in nano-scale polycrystalline machining with the increase of depth of cut, machining speed, and the use of the negative tool rake angles. The distributions of equivalent stress are consistent with the cutting force trends. Moreover, it is discovered that in the grain size range of 5.32 to 14.75 nm, the cutting forces and equivalent stress increase with the increase of grain size for the nano-structured copper, while the trends reserve after the grain size becomes even higher. This discovery confirms the existence of both the regular Hall-Petch relation and the inverse Hall-Petch relation in polycrystalline machining, and the existence of a threshold grain size allows one of the two relations to become dominant. The dislocation-grain boundary interaction shows that the resistance of the grain boundary to dislocation movement is the fundamental mechanism of the Hall-Petch relation, while grain boundary diffusion and movement is the reason of the inverse Hall-Petch relation.

  2. Fatigue Resistance of the Grain Size Transition Zone in a Dual Microstructure Superalloy Disk

    Science.gov (United States)

    Gabb, T. P.; Kantzos, P. T.; Telesman, J.; Gayda, J.; Sudbrack, C. K.; Palsa, B. S.

    2010-01-01

    Mechanical property requirements vary with location in nickel-based superalloy disks. To maximize the associated mechanical properties, heat treatment methods have been developed for producing tailored microstructures. In this study, a specialized heat treatment method was applied to produce varying grain microstructures from the bore to the rim portions of a powder metallurgy processed nickel-based superalloy disk. The bore of the contoured disk consisted of fine grains to maximize strength and fatigue resistance at lower temperatures. The rim microstructure of the disk consisted of coarse grains for maximum resistance to creep and dwell crack growth at high temperatures up to 704 C. However, the fatigue resistance of the grain size transition zone was unclear, and needed to be evaluated. This zone was located as a band in the disk web between the bore and rim. Specimens were extracted parallel and transverse to the transition zone, and multiple fatigue tests were performed at 427 and 704 C. Mean fatigue lives were lower at 427 C than for 704 C. Specimen failures often initiated at relatively large grains, which failed on crystallographic facets. Grain size distributions were characterized in the specimens, and related to the grains initiating failures as well as location within the transition zone. Fatigue life decreased with increasing maximum grain size. Correspondingly, mean fatigue resistance of the transition zone was slightly higher than that of the rim, but lower than that of the bore. The scatter in limited tests of replicates was comparable for all transition zone locations examined.

  3. Dependence of corrosion properties of AISI 304L stainless steel on the austenite grain size

    Energy Technology Data Exchange (ETDEWEB)

    Sabooni, Soheil; Rashtchi, Hamed; Eslami, Abdoulmajid; Karimzadeh, Fathallah; Enayati, Mohammad Hossein; Raeissi, Keyvan; Imani, Reihane Faghih [Isfahan Univ. of Technology, Isfahan (Iran, Islamic Republic of). Dept. of Materials Engineering; Ngan, Alfonso Hing Wan [The Univ. of Hong Kong (China). Dept. of Mechanical Engineering

    2017-07-15

    The corrosion resistance of austenitic stainless steels is known to be hampered by the loss of chromium available for passive surface layer formation as a result of chromium carbide precipitation at austenite grain boundaries during annealing treatments. Although high-temperature annealing can promote carbide dissolution leading to better corrosion resistance, grain coarsening also results, which would lead to poorer mechanical properties. Processing methods to achieve both good corrosion resistance and mechanical properties are thus highly desirable for austenitic stainless steels. In the present study, we show that the corrosion resistance of AISI 304L stainless steel can be improved by grain refinement into the ultrafine-grained regime. Specifically, samples with different austenite grain sizes in the range of 0.65-12 μm were studied by potentiodynamic polarization and electrochemical impedance spectroscopy tests in a 3.5 wt.% NaCl solution. All samples showed a typical passive behavior with similar corrosion potential, but the corrosion current density decreased significantly with decreasing grain size. The results show that the sample with the finest grain size had the best corrosion resistance due to a higher resistance of the passive layer to pitting attacks. This study indicates that grain refinement which improves mechanical properties can also significantly improve the corrosion resistance of AISI 304L stainless steel.

  4. The Importance of Grain Size to Mantle Dynamics and Seismological Observations: A Multidisciplinary Approach

    Science.gov (United States)

    Gassmöller, Rene; Dannberg, Juliane; Eilon, Zach; Moulik, Pritwiraj; Myhill, Robert; Faul, Ulrich

    2016-04-01

    Dynamic models of Earth's convecting mantle usually implement flow laws with constant grain size, stress-independent viscosity and a limited treatment of variations associated with changes in mineral assemblage. These simplifications greatly reduce computational requirements but preclude effects such as shear localisation and transient changes in rheology associated with phase transitions, which have the potential to fundamentally change flow patterns in the mantle. Here we use the finite-element code ASPECT [Bangerth et al., 2013] to model grain size evolution and the interplay between grain size, stress and strain rate in the convecting mantle. We include the simultaneous and competing effects of dynamic recrystallisation resulting from work done by dislocation creep, grain growth in multiphase assemblages and recrystallisation at phase transitions. Grain size variations also affect seismic properties of mantle materials. We apply published formalisms [Jackson & Faul, 2010; McCarthy et al., 2011; Takei et al., 2014] to relate intrinsic variables (P, T, and grain size) from our numerical models to seismic velocity (Vs) and attenuation (Q). We investigate these formalisms for consistency with seismic observations at conditions beyond the range of the experiments upon which they are based; this requires constraining the range of pre-factors and activation volumes relevant for the lower mantle. Our calculations use thermodynamically self-consistent anharmonic elastic moduli determined for the mineral assemblages in the mantle using HeFESTo [Stixrude and Lithgow-Bertelloni, 2013]. We investigate the effect of realistically heterogeneous grain sizes by computing synthetic seismological data; these highlight the frequency-dependent sensitivity of seismic waves to grain size, which is important when interpreting Vs and Q observations in terms of mineral assemblage and temperature. Our models show that grain size evolution can lead to lateral viscosity variations of six

  5. Multiscale architectured materials with composition and grain size gradients manufactured using high-pressure torsion.

    Science.gov (United States)

    Kang, Ji Yun; Kim, Jung Gi; Park, Hyo Wook; Kim, Hyoung Seop

    2016-05-27

    The concept of multiscale architectured materials is established using composition and grain size gradients. Composition-gradient nanostructured materials are produced from coarse grained interstitial free steels via carburization and high-pressure torsion. Quantitative analyses of the dislocation density using X-ray diffraction and microstructural studies clearly demonstrate the gradients of the dislocation density and grain size. The mechanical properties of the gradient materials are compared with homogeneous nanostructured carbon steel without a composition gradient in an effort to investigate the gradient effect. Based on the above observations, the potential of multiscale architecturing to open a new material property is discussed.

  6. Grain size of loess and paleosol samples: what are we measuring?

    Science.gov (United States)

    Varga, György; Kovács, János; Szalai, Zoltán; Újvári, Gábor

    2017-04-01

    Particle size falling into a particularly narrow range is among the most important properties of windblown mineral dust deposits. Therefore, various aspects of aeolian sedimentation and post-depositional alterations can be reconstructed only from precise grain size data. Present study is aimed at (1) reviewing grain size data obtained from different measurements, (2) discussing the major reasons for disagreements between data obtained by frequently applied particle sizing techniques, and (3) assesses the importance of particle shape in particle sizing. Grain size data of terrestrial aeolian dust deposits (loess and paleosoil) were determined by laser scattering instruments (Fritsch Analysette 22 Microtec Plus, Horiba Partica La-950 v2 and Malvern Mastersizer 3000 with a Hydro Lv unit), while particles size and shape distributions were acquired by Malvern Morphologi G3-ID. Laser scattering results reveal that the optical parameter settings of the measurements have significant effects on the grain size distributions, especially for the fine-grained fractions (Innovation Office (Hungary) under contract NKFI 120620 is gratefully acknowledged. It was additionally supported (for G. Varga) by the Bolyai János Research Scholarship of the Hungarian Academy of Sciences.

  7. EFFECT OF INITIAL GRAIN SIZE ON STATIC RECRYSTALLIZA-TION SOFTENING IN Cr STEEL USING STRESS RELAXATION TECHNIQUE

    Institute of Scientific and Technical Information of China (English)

    A.R. Morgridge

    2002-01-01

    Effect of initial grain size (I.G.S.) on static recrystallization softening in Cr steel(0.77wt.% CR) has been investigated through the use of interrupted hot compressiontests and stress relaxation curves from Gleeble 1500. Initial grain sizes were variedbetween 20 and 93 microns. Stress strains curves for Cr steel for different initialgrain sizes and recrystallization times have been highlighted. Similar observation wasmade for metadynamic recrystallization with shorter retardation times. Staticallyrecrystallized grain size also increased as initial grain size increases. It is found thatthe values of initial grain size have significant effects on the mean flow stress andstatic recrystallization kinetics as well as the peak strain values to initiate dynamicrecrystallization.

  8. Grain-Size Analysis of Debris Flow Alluvial Fans in Panxi Area along Jinsha River, China

    Directory of Open Access Journals (Sweden)

    Wen Zhang

    2015-11-01

    Full Text Available The basic geometric parameters of 236 debris flow catchments were determined by interpreting SPOT5 remote sensing images with a resolution of 2.5 m in a 209 km section along the Jinsha River in the Panxi area, China. A total of 27 large-scale debris flow catchments were selected for detailed in situ investigation. Samples were taken from two profiles in the deposition zone for each debris flow catchment. The φ value gradation method of the grain size was used to obtain 54 histograms with abscissa in a logarithmic scale. Five types of debris flows were summarized from the outline of the histogram. Four grain size parameters were calculated: mean grain size, standard deviation, coefficient of skewness, and coefficient of kurtosis. These four values were used to evaluate the features of the histogram. The grain index that reflects the transport (kinetic energy information of debris flows was defined to describe the characteristics of the debris-flow materials. Furthermore, a normalized grain index based on the catchment area was proposed to allow evaluation of the debris flow mobility. The characteristics of the debris-flow materials were well-described by the histogram of grain-size distribution and the normalized grain index.

  9. Role of grain size and particle velocity distribution in secondary electron emission in space plasmas

    Science.gov (United States)

    Chow, V. W.; Mendis, D. A.; Rosenberg, M.

    1993-01-01

    By virtue of being generally immersed in a plasma environment, cosmic dust is necessarily electrically charged. The fact that secondary emission plays an important role in determining the equilibrium grain potential has long been recognized, but the fact that the grain size plays a crucial role in this equilibrium potential, when secondary emission is important, has not been widely appreciated. Using both conducting and insulating spherical grains of various sizes and also both Maxwellian and generalized Lorentzian plasmas (which are believed to represent certain space plasmas), we have made a detailed study of this problem. In general, we find that the secondary emission yield delta increases with decreasing size and becomes very large for grains whose dimensions are comparable to the primary electron penetration depth, such as in the case of the very small grains observed at comet Halley and inferred in the interstellar medium. Moreover, we observed that delta is larger for insulators and equilibrium potentials are generally more positive when the plasma has a broad non-Maxwellian tail. Interestingly, we find that for thermal energies that are expected in several cosmic regions, grains of different sizes can have opposite charge, the smaller ones being positive while the larger ones are negative. This may have important consequences for grain accretion in polydisperse dusty space plasmas.

  10. The Influence of Grain Size on Decomposition Reaction of Limestone in Dispersing State

    Institute of Scientific and Technical Information of China (English)

    XU De-long; WEI Hon-gen; LUO Yong-qin

    2004-01-01

    The thermal behavior and kinetic parameters of decomposition reaction of limestone in a temperature-programmed mode were investigated by means of TG. The experimental results show that the kinetic model functions in different forms for the thermal decomposition reactions of different limestone grain sizes in dispersing state under the atmosphere of static air are 4(1-α)3/4 for small size limestone and (1-α) for large size limestone. Information was obtained on the relationship among the decomposition temperature, decomposition time, decomposition fraction, decomposition reaction rate constant and grain size of limestone.

  11. Large-grained copper indium diselenide crystal growth by computer-controlled high-pressure liquid-encapsulated directional solidification

    Science.gov (United States)

    Schwerdtfeger, C. R.; Ciszek, T. F.

    1992-12-01

    Large-grained copper indium diselenide crystal growth by computer-controlled high-pressure liquid-encapsulated directional solidification is presented. A supply of good quality angle crystals is essential to characterization of the fundamental material properties. [AIP

  12. Effect of grain size on superelasticity in Fe-Mn-Al-Ni shape memory alloy wire

    Directory of Open Access Journals (Sweden)

    T. Omori

    2013-09-01

    Full Text Available Effects of grain size on superelastic properties in Fe-34Mn-15Al-7.5Ni alloy wires with a ⟨110⟩ fiber-texture were investigated by cyclic tensile tests. It was confirmed that the critical stress for induced martensitic transformation and the superelastic strain are functions of relative grain size d/D (d: mean grain diameter, D: wire diameter, and that the critical stress is proportional to (1–d/D2 as well as in Cu-based shape memory alloys. A large superelastic strain of about 5% was obtained in the specimen with a large relative grain size over d/D = 1.

  13. Characterization of grain sizes and roughness of HfOsub>2sub> single layers.

    Science.gov (United States)

    Zhang, Lei; Cheng, Xinbin; Zhang, Jinlong; Jiao, Hongfei; Bao, Ganghua; Ding, Tao; Wang, Zhanshan

    2017-02-01

    The grain sizes and their influence on the roughness of an HfOsub>2sub> single layer prepared with ion-assisted deposition were investigated. Three methods, x ray diffractometry, atomic force microscopy, and the k-correlated power spectral density function model, were used to obtain the grain sizes in two HfOsub>2sub> single layers with 16 and 20 nm thicknesses. X ray diffractometry showed that the grain sizes were about 7 and 9 nm, respectively, whereas the other two methods demonstrated that the grain sizes were about 14 and 16 nm. It was thought that x ray diffractometry underestimated the grain size due to micro strain or a shallow penetration depth. The grains in an HfOsub>2sub> single layer lead to a rough surface, which had a significant bulge at the middle-high frequency range in a power spectral density function curve. The coating intrinsic roughness of the HfOsub>2sub> single layer was separated from the substrate roughness.

  14. Dynamics of a Dust Crystal with Two Different Size Dust Species

    CERN Document Server

    Matthews, L S; Hyde, T W

    2005-01-01

    A self-consistent three-dimensional model for a complex (dusty) plasma is used to study the effects of multiple-sized dust grains in a dust crystal. In addition to the interparticle forces, which interact through a Yukawa potential, the model includes the effects of gravity, the variation of the sheath potential above the powered electrode, and a radial confining potential. Simulations studied various ratios of a mix of 6.5- and 8.9-micron monodisperse particles and compared their correlation functions, electric potential energy of the crystal formations, and the dispersion relations for in-plane and out-of-plane dust lattice wave (DLW) modes for two different sheath thicknesses. In the 7 mm sheath, the particles formed two layers in the vertical direction by size, and acted as a two-layer crystal with weak correlation between the layers. In the 3 mm sheath, the particles formed an essentially monolayer crystal; however the crystal dynamics showed some characteristics of a bilayer crystal.

  15. Investigations of grain size dependent sediment transport phenomena on multiple scales

    Science.gov (United States)

    Thaxton, Christopher S.

    Sediment transport processes in coastal and fluvial environments resulting from disturbances such as urbanization, mining, agriculture, military operations, and climatic change have significant impact on local, regional, and global environments. Primarily, these impacts include the erosion and deposition of sediment, channel network modification, reduction in downstream water quality, and the delivery of chemical contaminants. The scale and spatial distribution of these effects are largely attributable to the size distribution of the sediment grains that become eligible for transport. An improved understanding of advective and diffusive grain-size dependent sediment transport phenomena will lead to the development of more accurate predictive models and more effective control measures. To this end, three studies were performed that investigated grain-size dependent sediment transport on three different scales. Discrete particle computer simulations of sheet flow bedload transport on the scale of 0.1--100 millimeters were performed on a heterogeneous population of grains of various grain sizes. The relative transport rates and diffusivities of grains under both oscillatory and uniform, steady flow conditions were quantified. These findings suggest that boundary layer formalisms should describe surface roughness through a representative grain size that is functionally dependent on the applied flow parameters. On the scale of 1--10m, experiments were performed to quantify the hydrodynamics and sediment capture efficiency of various baffles installed in a sediment retention pond, a commonly used sedimentation control measure in watershed applications. Analysis indicates that an optimum sediment capture effectiveness may be achieved based on baffle permeability, pond geometry and flow rate. Finally, on the scale of 10--1,000m, a distributed, bivariate watershed terain evolution module was developed within GRASS GIS. Simulation results for variable grain sizes and for

  16. Can high resolution 3D topographic surveys provide reliable grain size estimates in gravel bed rivers?

    Science.gov (United States)

    Pearson, E.; Smith, M. W.; Klaar, M. J.; Brown, L. E.

    2017-09-01

    High resolution topographic surveys such as those provided by Structure-from-Motion (SfM) contain a wealth of information that is not always exploited in the generation of Digital Elevation Models (DEMs). In particular, several authors have related sub-metre scale topographic variability (or 'surface roughness') to sediment grain size by deriving empirical relationships between the two. In fluvial applications, such relationships permit rapid analysis of the spatial distribution of grain size over entire river reaches, providing improved data to drive three-dimensional hydraulic models, allowing rapid geomorphic monitoring of sub-reach river restoration projects, and enabling more robust characterisation of riverbed habitats. However, comparison of previously published roughness-grain-size relationships shows substantial variability between field sites. Using a combination of over 300 laboratory and field-based SfM surveys, we demonstrate the influence of inherent survey error, irregularity of natural gravels, particle shape, grain packing structure, sorting, and form roughness on roughness-grain-size relationships. Roughness analysis from SfM datasets can accurately predict the diameter of smooth hemispheres, though natural, irregular gravels result in a higher roughness value for a given diameter and different grain shapes yield different relationships. A suite of empirical relationships is presented as a decision tree which improves predictions of grain size. By accounting for differences in patch facies, large improvements in D50 prediction are possible. SfM is capable of providing accurate grain size estimates, although further refinement is needed for poorly sorted gravel patches, for which c-axis percentiles are better predicted than b-axis percentiles.

  17. Relationship between Spectral Induced Polarization Measurements and Grain Size of Sandstones

    Science.gov (United States)

    Seleznev, N. V.; Hou, C. Y.; Freed, D.; Fellah, K.; Feng, L.; Xu, G.; Slater, L. D.

    2016-12-01

    Frequency dependence of the complex conductivity of ion-conductive soils and sediments in the range from millihertz to kilohertz can exhibit what is called the spectral induced polarization (SIP) effect, in which the impedance phase shows a near-resonance peak at a characteristic frequency as a result of a strong polarization response. Because the conventional Maxwell-Wagner interfacial polarization related to rock texture cannot provide an adequate explanation, the electrochemical polarization related to the electrical double layer formed in the presence of grains with surface charge is often invoked as a main mechanism for the SIP effect. Several studies demonstrating the link between SIP effect and the dominant grain size have previously been conducted on loose sands. Although loose sands provide good control of the grain size, they are not entirely representative of the consolidated sedimentary rocks common in the subsurface. In the present study we investigate the relationship between SIP effect and dominant grain size of well-characterized quarried consolidated sandstones. The choice of samples minimizes the influence of other factors, such as the presence of clays, on the SIP effect. Dominant grain size was determined using digital image analysis of scanning electron microscope (SEM) images obtained on thin sections. SIP spectra were measured on a collection of quarried clay-free sandstones saturated with brines. All rocks displayed a distinct peak in the imaginary conductivity dispersion curve. Also, we establish a rock model based on differential effective medium approach that accounts for both the interfacial polarization and electrochemical polarization due to the presence of charged grains. Experimental data is inverted with the model to obtain the dominant grain size. The model is shown to be capable of reproducing experimental data, and the inverted dominant grain size compares favorably with values determined from image analysis.

  18. Grain size effect on yield strength of titanium alloy implanted with aluminum ions

    Energy Technology Data Exchange (ETDEWEB)

    Popova, Natalya, E-mail: natalya-popova-44@mail.ru [Tomsk State University of Architecture and Building, 2, Solyanaya Sq., 634003, Tomsk (Russian Federation); Institute of Strength Physics and Materials Science, SB RAS, 2/4, Akademicheskii Ave., 634021, Tomsk (Russian Federation); Nikonenko, Elena, E-mail: vilatomsk@mail.ru [Tomsk State University of Architecture and Building, 2, Solyanaya Sq., 634003, Tomsk (Russian Federation); National Research Tomsk Polytechnic University, 30, Lenin Str., 634050, Tomsk (Russian Federation); Yurev, Ivan, E-mail: yiywork@mail.ru [Tomsk State University of Architecture and Building, 2, Solyanaya Sq., 634003, Tomsk (Russian Federation); Kalashnikov, Mark, E-mail: kmp1980@mail.ru [Institute of Strength Physics and Materials Science, SB RAS, 2/4, Akademicheskii Ave., 634021, Tomsk (Russian Federation); Kurzina, Irina, E-mail: kurzina99@mail.ru [National Research Tomsk State University, 36, Lenin Str., 634050, Tomsk (Russian Federation)

    2016-01-15

    The paper presents a transmission electron microscopy (TEM) study of the microstructure and phase state of commercially pure titanium VT1-0 implanted by aluminum ions. This study has been carried out before and after the ion implantation for different grain size, i.e. 0.3 µm (ultra-fine grain condition), 1.5 µm (fine grain condition), and 17 µm (polycrystalline condition). This paper presents details of calculations and analysis of strength components of the yield stress. It is shown that the ion implantation results in a considerable hardening of the entire thickness of the implanted layer in the both grain types. The grain size has, however, a different effect on the yield stress. So, both before and after the ion implantation, the increase of the grain size leads to the decrease of the alloy hardening. Thus, hardening in ultra-fine and fine grain alloys increased by four times, while in polycrystalline alloy it increased by over six times.

  19. Specimen- and grain-size dependence of compression deformation behavior in nanocrystalline copper

    OpenAIRE

    Okamoto, Norihiko L.; Kashioka, Daisuke; Hirato, Tetsuji; Inui, Haruyuki

    2014-01-01

    The compression deformation behavior of electrodeposited nanocrystalline copper pillars with average grain sizes (d) of 360, 100, and 34 nm has been investigated as a function of specimen size (D). The yield stress for nanocrystalline pillars with d = 360 and 100 nm does not depend on specimen size, exhibiting essentially the bulk yield stress until the specimen size is reduced down to the critical values ((D/d)∗ = 35 and 85), below which the yield stress decreases with the decrease in specim...

  20. Effects of Strain Energy and Grain Size on Corrosion Resistance of Ultrafine Grained Fe-20%Cr Steels with Extremely low C and N Fabricated by ECAP

    Directory of Open Access Journals (Sweden)

    Muhammad Rifai

    2015-01-01

    Full Text Available Effect of strain energy and grain size on corrosion resistance of ultrafine grained (UFG Fe-20%Cr steels with extremely low C and N fabricated by equal channel angular pressing (ECAP was investigated. UFG structures of initial grain size of 144 nm exhibited the typical three-stage softening comprising recovery, recrystallization, and grain growth. Potentiodynamic polarization measurements were carried out with a conventional three-electrode cell to evaluate pitting potential. Pitting potential in 1000 mol·m−3 NaCl solution was nobler in UFG state, but pitting potential started to decrease monotonously at lower temperature compared to hardness. The degradation of corrosion resistance in the early stage of annealing is attributed to stability change of passivation by recovery of dislocation structures inside grains and in nonequilibrium grain boundaries. We therefore conclude that nobler potentials of UFG states were realized by not only grain size reduction but also defective deformation-induced UFG.

  1. GRAIN SIZE DISTRIBUTION OF SEDIMENT IN THE NORTHERN EAST CHINA SEA AND THE RELATIONSHIP WITH THE SEA CURRENTS

    Institute of Scientific and Technical Information of China (English)

    LEI Kun; YANG Zuosheng; GUO Zhigang

    2002-01-01

    This paper discusses the relationship between the grain size distribution of sediment and currents in the northern East China Sea on the basis of the grain size analysis. The results show that grain size distribution of suspended sediment is controlled by the currents. Suspended sediment in the littoral water is finer than those in the open sea currents. Grain size distribution of surface sediment is affected by the sea currents to some extent. And the grain size of suspended sediment and surface sediment do not agree with each other in positions.

  2. Crystal size growth in the liquid phase methanol synthesis catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Sawant, A.; Lee, S.; Foos, A.

    1988-01-01

    The phenomenon of crystal growth in the methanol synthesis catalyst has been studied. Crystallite size distributions in the CuO/ZnO/Al/sub 2/O/sub 3/ methanol synthesis catalyst have been determined. The effects of temperature, reaction environment and time under reaction conditions have been studied. It is observed that water in the reaction mixture promotes crystal growth. 26 refs., 10 figs., 1 tab.

  3. Species sensitivity distributions for suspended clays, sediment burial, and grain size change in the marine environment.

    Science.gov (United States)

    Smit, Mathijs G D; Holthaus, Karlijn I E; Trannum, Hilde C; Neff, Jerry M; Kjeilen-Eilertsen, Grete; Jak, Robbert G; Singsaas, Ivar; Huijbregts, Mark A J; Hendriks, A Jan

    2008-04-01

    Assessment of the environmental risk of discharges, containing both chemicals and suspended solids (e.g., drilling discharges to the marine environment), requires an evaluation of the effects of both toxic and nontoxic pollutants. To date, a structured evaluation scheme that can be used for prognostic risk assessments for nontoxic stress is lacking. In the present study we challenge this lack of information by the development of marine species sensitivity distributions (SSDs) for three nontoxic stressors: suspended clays, burial by sediment, and change in sediment grain size. Through a literature study, effect levels were obtained for suspended clays, as well as for burial of biota. Information on the species preference range for median grain size was used to assess the sensitivity of marine species to changes in grain size. The 50% hazardous concentrations (HC50) for suspended barite and bentonite based on 50% effect concentrations (EC50s) were 3,010 and 1,830 mg/L, respectively. For burial the 50% hazardous level (HL50) was 5.4 cm. For change in median grain size, two SSDs were constructed; one for reducing and one for increasing the median grain size. The HL50 for reducing the median grain size was 17.8 mum. For increasing the median grain size this value was 305 mum. The SSDs have been constructed by using information related to offshore oil- and gas-related activities. Nevertheless, the results of the present study may have broader implications. The hypothesis of the present study is that the SSD methodology developed for the evaluation of toxic stress can also be applied to evaluate nontoxic stressors, facilitating the incorporation of nontoxic stressors in prognostic risk assessment tools.

  4. Effects of grain size distribution on remanence and coercivity of Pr2Fe14B nanocrystalline magnet

    Institute of Scientific and Technical Information of China (English)

    He Shu-Li; Zhang Hong-Wei; Rong Chuan-Bing; Chen Ren-Jie; Shen Bao-Gen

    2005-01-01

    The demagnetization curves of Pr2Fe14B nanocrystalline magnets are calculated using micromagnetic finiteelement method. Samples with three different distributions of grain size are simulated. We find that the remanence enhancement does not depend on grain size distribution but on the mean diameter of grains, and the influence of grain size distribution on coercivity is affected by the strength of intergrain exchange coupling.

  5. Size Effect Of Glulam Beams In Tension Perpendicular To Grain

    DEFF Research Database (Denmark)

    Astrup, Thomas; Odin Clorius, Christian; Damkilde, Lars;

    2007-01-01

    The strength of wood is reduced when the stressed volume is increased. The phenomenon is termed size effect and is often explained as being stochastic in the sense that the probability of weak locations occurring in the wood increases with increased volume. This paper presents the hypothesis...... that the lower strength is caused by stress concentrations. The stress concentrations arise from the anisotropic structure of wood, and are therefore deterministic. The hypothesis is substantiated through extensive FEM-calculations and experiments. A reasonable agreement between ultimate stresses determined...

  6. Size effect of glulam beams in tension perpendicular to grain

    DEFF Research Database (Denmark)

    Astrup, Thomas; Clorius, Christian Odin; Damkilde, Lars;

    2007-01-01

    that the lower strength is caused by stress concentrations. The stress concentrations arise from the anisotropic structure of wood, and are therefore deterministic. The hypothesis is substantiated through extensive FEM-calculations and experiments. A reasonable agreement between ultimate stresses determined......The strength of wood is reduced when the stressed volume is increased. The phenomenon is termed size effect and is often explained as being stochastic in the sense that the probability of weak locations occurring in the wood increases with increased volume. This paper presents the hypothesis...

  7. Preliminary analysis of grain-size populations with environmentally sensitive terrigenous components in marginal sea setting

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    Terrigenous components were separated from the bulk sediment of Core A7 from the Okinawa Trough and Core A37 from the Ryukru Trench and grain-size distributions of these sub-samples were analyzed. Based upon an analysis of the grain-size data of the two sedimentary sequences, grain-size populations are identified to be sensitive to sedimentary environmental changes. The modal values and size ranges of the two main grain-size populations in Core A7 are evidently different from those of Core A37, indicating the spatial variability of sediment sources and transport processes between the two places. The downcore variations in the content of the environmentally sensitive grain-size populations reveal that during the accumulation of sedimentary material the environment remained relatively stable at the site where Core A7 was collected, except for the apparent events for the formation of two turbidite layers and a volcanic ash layer. However, the sedimentary sequence of Core A37 shows six sedimentary cycles, indicating a highly variable sedimentary environment at this location.

  8. Dislocation Analysis for Large-sized Sapphire Single Crystal Grown by SAPMAC Method

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    In this paper, large-sized sapphire (Φ230×210 mm, 27.5 kg) was grown by SAPMAC method (sapphire growth technique with micro-pulling and shoulder-expanding at the cooled center). Dislocation peculiarity in large sapphire boule (0001) basal plane was investigated by chemical etching, scanning electron microscopy and X-ray topography method. The triangular dislocation etch pit measured is 7.6×101~8.0×102 cm-2, in which relative high-density dislocations were generated at both initial and final stages of crystal growth. The analysis of single-crystal X-ray topography shows that there are no apparent sub-grain boundaries; the dislocation lines are isolated and straight. Finally, the origins of low-density dislocation in sapphire crystal are discussed by numerical analysis method.

  9. Fatigue Failure Modes of the Grain Size Transition Zone in a Dual Microstructure Disk

    Science.gov (United States)

    Gabb, Timothy P.; Kantzos, Pete T.; Palsa, Bonnie; Telesman, Jack; Gayda, John; Sudbrack, Chantal K.

    2012-01-01

    Mechanical property requirements vary with location in nickel-based superalloy disks. In order to maximize the associated mechanical properties, heat treatment methods have been developed for producing tailored grain microstructures. In this study, fatigue failure modes of a grain size transition zone in a dual microstructure disk were evaluated. A specialized heat treatment method was applied to produce varying grain microstructure in the bore to rim portions of a powder metallurgy processed nickel-based superalloy disk. The transition in grain size was concentrated in a zone of the disk web, between the bore and rim. Specimens were extracted parallel and transversely across this transition zone, and multiple fatigue tests were performed at 427 C and 704 C. Grain size distributions were characterized in the specimens, and related to operative failure initiation modes. Mean fatigue life decreased with increasing maximum grain size, going out through the transition zone. The scatter in limited tests of replicates was comparable for failures of uniform gage specimens in all transition zone locations examined.

  10. The influence of grain size ratio upon the relative mobility in bimodal sediment mixtures

    Science.gov (United States)

    Dudill, Ashley; Frey, Philippe

    2014-05-01

    The behaviour of grain mixtures varies from that of uniform grain, which has implications for bedload sediment transport in gravel-bed rivers. In particular, sediment mixtures act to modify the level of mobility within the bed, leading to aggradation or degradation, which has significant implications for river stability. Previous work has reported upon this change in mobility within bimodal mixtures; however we do not know how far grain size ratio influences these results. We hypothesise that there is a link between the change in levels of mobility and the grain size ratio due to varying amounts of infiltration, which controls the hiding/exposure function. This poster will present experimental results from an investigation designed to isolate the influence of grain size ratio upon the change in levels of mobility in bimodal sediment mixtures. This experimental investigation was undertaken using various sizes of spherical particles in a relatively narrow flume. Using this arrangement, we are able to observe effects at the particle scale in order to understand the individual and bulk grain behaviour.

  11. Model for evolution of grain size in the rim region of high burnup UO2 fuel

    Science.gov (United States)

    Xiao, Hongxing; Long, Chongsheng; Chen, Hongsheng

    2016-04-01

    The restructuring process of the high burnup structure (HBS) formation in UO2 fuel results in sub-micron size grains that accelerate the fission gas swelling, which will raise some concern over the safety of extended the nuclear fuel operation life in the reactor. A mechanistic and engineering model for evolution of grain size in the rim region of high burnup UO2 fuel based on the experimental observations of the HBS in the literature is presented. The model takes into account dislocations evolution under irradiation and the grain subdivision occur successively at increasing local burnup. It is assumed that the original driving force for subdivision of grain in the HBS of UO2 fuel is the production and accumulation of dislocation loops during irradiation. The dislocation loops can also be annealed through thermal diffusion when the temperature is high enough. The capability of this model is validated by the comparison with the experimental data of temperature threshold of subdivision, dislocation density and sub-grain size as a function of local burnup. It is shown that the calculated results of the dislocation density and subdivided grain size as a function of local burnup are in good agreement with the experimental results.

  12. Film Grain-Size Related Long-Term Stability of Inverted Perovskite Solar Cells.

    Science.gov (United States)

    Chiang, Chien-Hung; Wu, Chun-Guey

    2016-09-22

    The power conversion efficiency (PCE) of the perovskite solar cell is high enough to be commercially viable. The next important issue is the stability of the device. This article discusses the effect of the perovskite grain-size on the long-term stability of inverted perovskite solar cells. Perovskite films composed of various sizes of grains were prepared by controlling the solvent annealing time. The grain-size related stability of the inverted cells was investigated both in ambient atmosphere at relative humidity of approximately 30-40 % and in a nitrogen filled glove box (H2 Osolar cell based on a perovskite film having the grain size larger than 1 μm (D-10) decreases less than 10 % with storage in a glove box and less than 15 % when it was stored under an ambient atmosphere for 30 days. However, the cell using the perovskite film composed of small (∼100 nm) perovskite grains (D-0) exhibits complete loss of PCE after storage under the ambient atmosphere for only 15 days and a PCE loss of up to 70 % with storage in the glove box for 30 days. These results suggest that, even under H2 O-free conditions, the chemical- and thermal-induced production of pin holes at the grain boundaries of the perovskite film could be the reason for long-term instability of inverted perovskite solar cells.

  13. Collective resonances in plasmonic crystals: Size matters

    CERN Document Server

    Rodriguez, S R K; Berrier, A; Rivas, J Gomez

    2013-01-01

    Periodic arrays of metallic nanoparticles may sustain Surface Lattice Resonances (SLRs), which are collective resonances associated with the diffractive coupling of Localized Surface Plasmon Resonances (LSPRs). By investigating a series of arrays with varying number of particles, we traced the evolution of SLRs to its origins. Polarization resolved extinction spectra of arrays formed by a few nanoparticles were measured, and found to be in very good agreement with calculations based on a coupled dipole model. Finite size effects on the optical properties of the arrays are observed, and our results provide insight into the characteristic length scales for collective plasmonic effects: for arrays smaller than 5 x 5 particles, the Q-factors of SLRs are lower than those of LSPRs; for arrays larger than 20 x 20 particles, the Q-factors of SLRs saturate at a much larger value than those of LSPRs; in between, the Q-factors of SLRs are an increasing function of the number of particles in the array.

  14. Effect of time and temperature on grain size of V and V-Cr-Ti alloys

    Energy Technology Data Exchange (ETDEWEB)

    Natesan, K.; Rink, D.L. [Argonne National Lab., IL (United States)

    1996-10-01

    Grain growth studies were conducted to evaluate the effect of time and temperature on the grain size of pure V, V-4 wt.%Cr-4 wt.%Ti, and V-5 wt.%Cr-5 wt.%Ti alloys. The temperatures used in the study were 500, 650, 800, and 1000{degrees}C, and exposure times ranged between 100 and {approx}5000 h. All three materials exhibited negligible grain growth at 500, 650, and 800{degrees}C, even after {approx}5000 h. At 1000{degrees}C, pure V showed substantial grain growth after only 100 h, and V-4Cr-4Ti showed growth after 2000 h, while V-5Cr-5Ti showed no grain growth after exposure for up to 2000 h.

  15. Lost in Jupiter's Shadow: Can Resonant Charge Variations Explain Dust Grain Sizes in the Main Ring?

    Science.gov (United States)

    Jontof-Hutter, Daniel; Hamilton, D. P.

    2012-10-01

    Interplanetary impacts onto the tiny moons Metis and Adrastea replenish Jupiter's main ring with dusty ejecta of all sizes. The equilibrium size distribution present in the rings at a given time is a function of production and loss mechanisms, both of which may be vary with particle size. Loss mechanisms include collisions and dynamical processes. Here we explore some of the latter. Grains tend to pick up negative electric charges due to motion through Jupiter's plasma environment, and positive charges from the photoelectric effect of sunlight. The periodic interruption of sunlight in Jupiter's shadow causes the equilibrium electric charge, and hence the Lorentz force, to resonate with the Kepler orbital frequency. The eccentricity increases for grains moving radially inwards during the shadow transit, and decreases when grains move outward in the shadow, hence the azimuthal location of pericenter is important. For smaller grains, the eccentricity increases monotonically until they collide with Jupiter. For much larger grains, precession due to both the Lorentz force and planetary oblateness causes the eccentricity to oscillate periodically. We explore the shadow instability in the main ring for a variety of uniform plasma density models, comparing numerical data with a semi-analytic approximation. We find that the effect of the shadow dwindles in importance for plasma that is either too sparse or too dense. In sparse plasma, the charging timescale slows, limiting the change in electric potential from sunlight to shadow. In dense plasma, charging currents from the plasma overwhelm the photoelectric effect in sunlight, also resulting in a small change in electric potential. Between these two regimes, the shadow resonance efficiently removes grains up to a particular size threshold in the main ring. This size-dependent loss mechanism may contribute to the observed flattening in the size distribution index for smaller grains.

  16. Dependence of coercivity on phase distribution and grain size in nanocomposite Nd2Fe14B/α-Fe magnets

    Institute of Scientific and Technical Information of China (English)

    Feng Wei-Cun; Gao Ru-Wei; Li Wei; Han Guang-Bing; Sun Yan

    2005-01-01

    The dependence of coercivity on the grain size in nanocomposite Nd2Fe14B/α-Fe magnets with different distributions of magnetically soft and hard phases is investigated by means of statistical mean. The calculations show that when there exists no soft phase, the coercivity of magnets decreases monotonically with hard grain size reducing. For a given volume fraction of hard phase, the coercivity of nanocomposite Nd2Fe14B/α-Fe magnets with a random distribution of soft and hard grains shows a peak value as a function of hard grain size. When the hard grain size is larger than an optimum value of soft grain size (15nm), the nanocomposite Nd2Fe14B/α-Fe magnets with the multilayer structure of soft and hard grains can possess a higher coercivity than that with the random distribution of soft and hard grains.

  17. Grain size and texture changes of magnesium alloy AZ31 during multi-directional forging

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Grain size and texture changes of magnesium alloy AZ31 were studied in multidirectional forging(MDF) under decreasing temperature conditions. MDF was carried out up to large cumulative strains of 4.8 with changing the loading direction during decrease in temperature from pass to pass. MDF can accelerate the uniform development of fine-grained structures and increase the plastic workability at low temperatures. As a result, the MDFed alloy shows excellent higher strength as well as moderate ductility at room temperature even at the grain size below 1 μm. Superplastic flow takes place at 423 K and depends on the anisotropy of MDFed samples. The mechanisms of strain-induced free-grained structure development and of the plastic deformation were discussed in detail.

  18. Effect of texture and grain size on the residual stress of nanocrystalline thin films

    Science.gov (United States)

    Cao, Lei; Sengupta, Arkaprabha; Pantuso, Daniel; Koslowski, Marisol

    2017-10-01

    Residual stresses develop in thin film interconnects mainly as a result of deposition conditions and multiple thermal loading cycles during the manufacturing flow. Understanding the relation between the distribution of residual stress and the interconnect microstructure is of key importance to manage the nucleation and growth of defects that can lead to failure under reliability testing and use conditions. Dislocation dynamics simulations are performed in nanocrystalline copper subjected to cyclic loading to quantify the distribution of residual stresses as a function of grain misorientation and grain size distribution. The outcomes of this work help to evaluate the effect of microstructure in thin films failure by identifying potential voiding sites. Furthermore, the simulations show how dislocation structures are influenced by texture and grain size distribution that affect the residual stress. For example, when dislocation loops reach the opposite grain boundary during loading, these dislocations remain locked during unloading.

  19. Trend analysis of sediment grain size and sedimentary process in the central South Yellow Sea

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    With the method of trend analysis of sediment grain size, the sediment transport trend of the fine-grained sediments area in the central South Yellow Sea was studied. The results demonstrated that there is a sedimentation center around the point of 123.4°E, 35.1°N, and the sediments outside the center are transported to it. The patterns of sediment transportation and deposition in the Yellow Sea should be controlled by cyclonic circulation (including the Yellow Sea Cold Water Mass) and cold water gyre. The study also showed that the method of trend analysis of sediment grain size has prospective utilization in the fine-grained sediment deposited area on large-scale continental shelf.

  20. [The measurement and retrieval of the spectral reflectance of different snow grain size on Northern Xinjiang, China].

    Science.gov (United States)

    Hao, Xiao-Hua; Wang, Jie; Wang, Jian; Zhang, Pu; Huang, Chun-Lin

    2013-01-01

    The retrieval of snow grain size is one of the important research directions for cryosphere snow remote sensing. In the present study, we designed the measurement plan of different snow grain size by different snow layer. A SVC HR-1024 ground-based spectral radiometer was used for measuring the spectral property of different snow grain size in northern Xinjiang, China. At the same time, the snow grain size and shape were measured by a hand-loupe with scale. Then the DSPP method was used to calculate the equivalent snow grain size. Finally, the asymptotic radiative transfer (ART) theory was applied to retrieve the snow grain size from measured snow spectral reflectance of different snow layer by optimizing the inversion band and the snow grain size factor "b". The retrieved snow grain size was validated by the measured snow grain size from DSPP method. The results showed that the DSPP method is an effective means of measuring the equivalent snow grain size. However, there is a large deviation of the snow grain size sample in the same snow layer. It is necessary to improve the measurement method of the single snow grain size sample; The study showed that the near-infrared bands are the most effective selection for retrieval of snow grain size. The retrieval algorithm from ART is feasible. When the snow is dry, the authors optimize the inversion band and the snow grain size factor b in the Northern Xinjiang, China. The optimal band wavelength is 1.20 microm and b is 3.62.

  1. Grain size control and phase transformations in nanocrystalline ZrO(2)-Al(2)O(3)

    Science.gov (United States)

    Smyser, Bridget Maureen

    1998-12-01

    An effort has been made to develop nanocrystalline ZrOsb2-Alsb2Osb3 powders that exhibit grain size and phase stability during one thermal cycle from room temperature to 1100-1200sp°C for potential use as thermal barrier coating materials. For this use, the tetragonal phase of ZrOsb2 must be maintained. Tetragonal ZrOsb2 can be prevented from transforming to the monoclinic form by maintaining the grain size below a critical value. Alsb2Osb3 was intended to provide this grain size control due to its immiscibility with ZrOsb2. Several sol-gel and precipitation methods of producing the powders were compared, along with two different forms of high energy mixing. The powders were subsequently calcined and heat treated in order to assess their ability to maintain the desired phase distribution during thermal cycling. The powders were characterized by x-ray diffraction and transmission electron microscopy. The method producing the greatest fraction of tetragonal ZrOsb2 with the least amount of added Alsb2Osb3 was that in which a commercial colloidal solution of ZrOsb2 was mixed with an aluminum nitrate solution. The critical grain size of ZrOsb2 in this system was 30 nm. The grain size was controlled not by a pinning mechanism as is often seen in conventional, high Alsb2Osb3,\\ Alsb2Osb3-ZrOsb2 ceramics, but instead by mutual constraint of surrounding grains aided by sluggish grain boundary diffusion. The grain growth kinetics in all the phases tended to be slower than in micron sized materials, and a range of grain growth exponents from n = 1 to n = 30 were determined for the various phases. Transformation kinetics in ZrOsb2 followed classic Avrami behavior. Alsb2Osb3 phase transformation kinetics were not specifically determined, however, gamma-Alsb2Osb3 was identified at temperatures well beyond its usual stability, which is possibly a grain size effect.

  2. Estimate the influence of snow grain size and black carbon on albedo

    Institute of Scientific and Technical Information of China (English)

    ZhongMing Guo; NingLian Wang; XiaoBo Wu; HongBo Wu; YuWei Wu

    2015-01-01

    Estimation of the influence of snow grain size and black carbon on albedo is essential in obtaining the accurate albedo. In this paper, field measurement data, including snow grain size, snow depth and density was obtained. Black carbon samples were collected from the snow surface. A simultaneous observation using Analytical Spectral Devices was employed in the Qiyi Glacier located in the Qilian Mountain. Analytical Spectral Devices spectrum data were used to analyze spectral re-flectance of snow for different grain size and black carbon content. The measurements were compared with the results obtained from the Snow, Ice, and Aerosol Radiation model, and the simulation was found to correlate well with the ob-served data. However, the simulated albedo was near to 0.98 times of the measured albedo, so the other factors were as-sumed to be constant using the corrected Snow, Ice, and Aerosol Radiation model to estimate the influence of measured snow grain size and black carbon on albedo. Field measurements were controlled to fit the relationship between the snow grain size and black carbon in order to estimate the influence of these factors on the snow albedo.

  3. Grain-size-independent plastic flow at ultrahigh pressures and strain rates.

    Science.gov (United States)

    Park, H-S; Rudd, R E; Cavallo, R M; Barton, N R; Arsenlis, A; Belof, J L; Blobaum, K J M; El-dasher, B S; Florando, J N; Huntington, C M; Maddox, B R; May, M J; Plechaty, C; Prisbrey, S T; Remington, B A; Wallace, R J; Wehrenberg, C E; Wilson, M J; Comley, A J; Giraldez, E; Nikroo, A; Farrell, M; Randall, G; Gray, G T

    2015-02-13

    A basic tenet of material science is that the flow stress of a metal increases as its grain size decreases, an effect described by the Hall-Petch relation. This relation is used extensively in material design to optimize the hardness, durability, survivability, and ductility of structural metals. This Letter reports experimental results in a new regime of high pressures and strain rates that challenge this basic tenet of mechanical metallurgy. We report measurements of the plastic flow of the model body-centered-cubic metal tantalum made under conditions of high pressure (>100  GPa) and strain rate (∼10(7)  s(-1)) achieved by using the Omega laser. Under these unique plastic deformation ("flow") conditions, the effect of grain size is found to be negligible for grain sizes >0.25  μm sizes. A multiscale model of the plastic flow suggests that pressure and strain rate hardening dominate over the grain-size effects. Theoretical estimates, based on grain compatibility and geometrically necessary dislocations, corroborate this conclusion.

  4. Grain-size distribution in suspension over a sand-gravel bed in open channel flow

    Institute of Scientific and Technical Information of China (English)

    Koeli GHOSHAL; Debasish PAL

    2014-01-01

    Grain-size distributions of suspended load over a sand-gravel bed at two different flow velocities were studied in a laboratory flume. The experiments had been performed to study the influence of flow velocity and suspension height on grain-size distribution in suspension over a sand-gravel bed. The experimental findings show that with an increase of flow velocity, the grain-size distribution of suspended load changed from a skewed form to a bimodal one at higher suspension heights. This study focuses on the determination of the parameter βn which is the ratio of the sediment diffusion coefficient to the momentum diffusion coefficient of n th grain-size. A new relationship has been proposed involvingβn , the normalizing settling velocity of sediment particles and suspension height, which is applicable for widest range of normalizing settling velocity available in literature so far. A similar parameter β for calculating total suspension concentration is also developed. The classical Rouse equation is modified with βn and β and used to compute grain-size distribution and total concentration in suspension, respectively. The computed values have shown good agreement with the measured values of experimental data.

  5. EXAFS study of structural characteristics of nanocrystalline selenium with different grain sizes

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    Extended x-ray-absorption fine-structure measurements(EXAFS) were performed on nanocrystalline (nc) elemental Se samples with grain sizes ranging from 13 to 60 nm.Accompanied with the previous study,we concluded that,with the refinement in nc.Se.the intrachain structure (the bond length,the coordination number)is unchanged while the interchain spacing is enlarged.The grain boundary in the nc Se is found to be in a low-energy configuration that is different from the disordered gaslike grain boundary structure.

  6. Variance in Dominant Grain Size Across the Mississippi River Delta

    Science.gov (United States)

    Miller, K. L.; Chamberlain, E. L.; Esposito, C. R.; Wagner, R. W.; Mohrig, D. C.

    2016-02-01

    Proposals to restore coastal Louisiana often center on Mississippi River diversion projects wherein water and sediment are routed into wetlands and shallow waters in an effort to build land. Successful design and implementation of diversions will include consideration of behavior and characteristics of sediment, both in the river and in the receiving basin. The Mississippi River sediment load is primarily mud (roughly 75%), with the remainder being very-fine to medium sand or organic detritus. The dominance of muds leads many to suggest that diversions should focus on capturing the mud fraction despite the smaller size and longer settling times required for these particles compared to sand; others believe that sand should be the focus. We present a systemic analysis of the texture of land-building sediment in the Mississippi Delta using borehole data from various depositional environments representing a range of spatial scales, system ages, and fluvial and basin characteristics. We include subdelta-scale data from the incipient Wax Lake Delta and from the distal plain of the abandoned Lafourche subdelta, as well as crevasse-scale data from modern Cubit's Gap and the Attakapas splay, an inland Lafourche crevasse. Comparison of these sites demonstrates a large variance in the volumetric mud to sand ratios across the system. We consider the differences to be emblematic of the various forcings on each lobe as it formed and suggest that the most efficient building block for a diversion is a function of the receiving basin and is not uniform across the entire delta.

  7. [Theory and practice of electrospray crystallization in particle size reduction].

    Science.gov (United States)

    Szunyogh, Tímea; Ambrus, Rita; Szabóné Révész, Piroska

    2015-01-01

    Nowdays, one of the most challenges for the researchers is the formulation of poorly water soluble drugs. Reduction of particle size of active agents to submicron range could result in a faster dissolution rate and higher bioavailability. Integration as crystallization process is an often used particle size decreasing technique. The aim of this study was to show the theoretical background and practical application of the electros pray crystallization as an innovative particle size decreasing technique. Our model drug was the niflumic acid (NIF), which belongs to the BCS Class II. After the optimization of the process parameters, the physico-chemical properties of the samples were characterized. Particle size and shape were visualized by scanning electron microscopy (SEM). Crystalline state of NIF and the samples were investigated using differential scanning calorimetry (DSC) and X-ray powder diffraction. Physico-chemical properties were determined using dissolution test from simulated media. The electrospray crytallization resulted in particle size reduction but the aggregation of nanonized NIF crystals (NIF-nano) could not avoid without excipient. Aggregates with poor secondary forces are suitable for production of the interactive physical mixture. It was found that NIF-nano could be well distributed on the surface of the mannitol as carrier and the Poloxamer R protected the NIF-nano crystals (320 nm)from aggregation. Consequently, the physical mixture resulted in product with higher polarity, better wettability and faster dissolution rate of NIF as raw NIF or NIF-nano.

  8. Effect of composition and grain size on electrical discharge machining of BN--TiB sub 2 composites

    Energy Technology Data Exchange (ETDEWEB)

    Gadalla, A.M.; Bedi, H.S. (Chemical Engineering Department, Texas A M University, College Station, Texas (USA))

    1991-11-01

    TiB{sub 2} conducts the current and forms a liquid phase at the interface with BN. Neighboring crystals of BN and some TiB{sub 2} spall due to thermal shock. During pause periods parts of the liquid and fragments are flushed out by the dielectric. Composites rich in TiB{sub 2} or with fine TiB{sub 2} grains gave high material removal rates. Increasing the amount of conducting phase by 10% is as effective as decreasing the grain size from 11 to 7 {mu}m. Coarse TiB{sub 2} could withstand high pulse durations before wire breaks. Material removal rate increases with pulse duration, frequency, and current. For the same composition and grain size, increasing the pulse duration or current increased the crater depth (the roughness) up to a certain value, beyond which increasing these parameters yielded a smoother surface. The conductivity of the dielectric was effective only for compositions rich in TiB{sub 2} content. In such cases, higher water conductivity lowered the energy required for material removal.

  9. Effect of Grain Size Distribution on Processing Maps for Isothermal Compression of Inconel 718 Superalloy

    Science.gov (United States)

    Wang, Jianguo; Liu, Dong; Hu, Yang; Yang, Yanhui; Zhu, Xinglin

    2016-02-01

    Cylindrical specimens of Inconel 718 alloys with three types of grain size distribution were used in the compression tests and processing maps were developed in 940-1040 °C and 0.001-10 s-1. The equiaxed fine grain is more effective on the dynamic softening behavior. For partial recrystallized microstructure, the peak efficiency of power dissipation occurs at the strain rate of 0.001 s-1, and the temperature range of 1000-1020 °C. In order to obtain homogeneous microstructure with fine grains, the partial recrystallized microstructure should be deformed at the low temperature and slow strain rates. The area fraction of instability domains decreases with strain increasing. The peak efficiency of power dissipation increases with average grain size decreasing. The efficiency of power dissipation will be stimulated by the precipitation of δ phase at slow strain rate of 0.001-0.01 s-1, and the initial deformed substructure at the strain rate of 0.1-1 s-1. Equiaxed fine grain is the optimum state for forging process and dynamic recrystallization. The grain size distribution has slight influence on the microstructure evolution at high temperatures.

  10. Correlation vs. Causation: The Effects of Ultrasonic Melt Treatment on Cast Metal Grain Size

    Directory of Open Access Journals (Sweden)

    J. B. Ferguson

    2014-10-01

    Full Text Available Interest in ultrasonic treatment of liquid metal has waxed and waned for nearly 80 years. A review of several experiments representative of ultrasonic cavitation treatment of Al and Mg alloys shows that the theoretical mechanisms thought to be responsible for grain refinement are (1 cavitation-induced increase in melting temperature predicted by the Clausius-Clapeyron equation and (2 cavitation-induced wetting of otherwise unwetted insoluble particles. Neither of these theoretical mechanisms can be directly confirmed by experiment, and though they remain speculative, the available literature generally assumes that one or the other or both mechanisms are active. However, grain size is known to depend on temperature of the liquid, temperature of the mold, and cooling rate of the entire system. From the reviewed experiments, it is difficult to isolate temperature and cooling rate effects on grain size from the theoretical effects. Ultrasonic treatments of Al-A356 were carried out to isolate such effects, and though it was found that ultrasound produced significant grain refinement, the treatments also significantly chilled the liquid and thereby reduced the pouring temperature. The grain sizes attained closely correlated with pouring temperature suggesting that ultrasonic grain refinement is predominantly a result of heat removal by the horn and ultrasonic stirring.

  11. The Effect of Grain Size and Strain on the Tensile Flow Stress of Aluminium at Room Temperature

    DEFF Research Database (Denmark)

    Hansen, Niels

    1977-01-01

    Tensile-stress-strain data over a strain range from 0.2 to 30% were obtained at room temperature for 99.999 and 99.5% aluminium as a function of grain size. The yield stress-grain size relationship can be expressed by a Petch-Hall relation with approximately the same slope for the two materials. ...... stress-grain size relationship was analyzed in terms of matrix strengthening and grain boundary strengthening according to the dislocation concept of Ashby. At intermediate strains this approach gives a good description of the effect of strain, grain size and purity on the flow stress....

  12. The prediction of the evolution of grain size of land-gear forging during the die-forging process

    Directory of Open Access Journals (Sweden)

    Lin Gao

    2015-01-01

    Full Text Available The land-gear forgings are the most important structure parts, made of high strength steel 300M. Because of the bad service environment, the microstructure and performance of the part are very strict requirements. In this article the evolution of grain size during the die-forging process is predicted, the volume fraction of dynamic recrystallization, grain refinement and development of grain size in-homogeneity, and the affection of billet shape on the grain size distribution are analyzed. The simulated results show that the grain size differences on the different billet positions are very large at the deformation beginning. But in final forging stage, the difference of the average grain size is smaller. At some center zones of the part the maximum difference of grain size is bigger than 100 μm.

  13. A new database sub-system for grain-size analysis

    Science.gov (United States)

    Suckow, Axel

    2013-04-01

    Detailed grain-size analyses of large depth profiles for palaeoclimate studies create large amounts of data. For instance (Novothny et al., 2011) presented a depth profile of grain-size analyses with 2 cm resolution and a total depth of more than 15 m, where each sample was measured with 5 repetitions on a Beckman Coulter LS13320 with 116 channels. This adds up to a total of more than four million numbers. Such amounts of data are not easily post-processed by spreadsheets or standard software; also MS Access databases would face serious performance problems. The poster describes a database sub-system dedicated to grain-size analyses. It expands the LabData database and laboratory management system published by Suckow and Dumke (2001). This compatibility with a very flexible database system provides ease to import the grain-size data, as well as the overall infrastructure of also storing geographic context and the ability to organize content like comprising several samples into one set or project. It also allows easy export and direct plot generation of final data in MS Excel. The sub-system allows automated import of raw data from the Beckman Coulter LS13320 Laser Diffraction Particle Size Analyzer. During post processing MS Excel is used as a data display, but no number crunching is implemented in Excel. Raw grain size spectra can be exported and controlled as Number- Surface- and Volume-fractions, while single spectra can be locked for further post-processing. From the spectra the usual statistical values (i.e. mean, median) can be computed as well as fractions larger than a grain size, smaller than a grain size, fractions between any two grain sizes or any ratio of such values. These deduced values can be easily exported into Excel for one or more depth profiles. However, such a reprocessing for large amounts of data also allows new display possibilities: normally depth profiles of grain-size data are displayed only with summarized parameters like the clay

  14. Crystal-Size-Dependent Structural Transitions in Nanoporous Crystals: Adsorption-Induced Transitions in ZIF-8

    KAUST Repository

    Zhang, Chen

    2014-09-04

    © 2014 American Chemical Society. Understanding the crystal-size dependence of both guest adsorption and structural transitions of nanoporous solids is crucial to the development of these materials. We find that nano-sized metal-organic framework (MOF) crystals have significantly different guest adsorption properties compared to the bulk material. A new methodology is developed to simulate the adsorption and transition behavior of entire MOF nanoparticles. Our simulations predict that the transition pressure significantly increases with decreasing particle size, in agreement with crystal-size-dependent experimental measurements of the N2-ZIF-8 system. We also propose a simple core-shell model to examine this effect on length scales that are inaccessible to simulations and again find good agreement with experiments. This study is the first to examine particle size effects on structural transitions in ZIFs and provides a thermodynamic framework for understanding the underlying mechanism.

  15. Effects of grain size on high temperature creep of fine grained, solution and dispersion hardened V-1.6Y-8W-0.8TiC

    Energy Technology Data Exchange (ETDEWEB)

    Furuno, T. [Ehime Univerisity, 3 Bunkyo-cho, Matsuyama 790-8577 (Japan); Kurishita, H., E-mail: kurishi@imr.tohoku.ac.jp [International Research Center for Nuclear Materials Science, Institute for Materials Research (IMR), Tohoku University, Oarai, Ibaraki 311-1313 (Japan); Nagasaka, T.; Nishimura, A.; Muroga, T. [Fusion Engineering Research Center, National Institute for Fusion Science (NIFS), Oroshi-cho 322-6, Tok, Gifu 292 (Japan); Sakamoto, T.; Kobayashi, S.; Nakai, K. [Department of Materials Science and Biotechnology, Ehime Univerisity, 3 Bunkyo-cho, Matsuyama 790-8577 (Japan); Matsuo, S.; Arakawa, H. [International Research Center for Nuclear Materials Science, Institute for Materials Research (IMR), Tohoku University, Oarai, Ibaraki 311-1313 (Japan)

    2011-10-01

    Creep resistance is the major concern of vanadium and its alloys for fusion reactor structural applications. In order to elucidate the effects of grain size on the creep behavior of solution and dispersion strengthened vanadium alloys, V-1.6Y-8W-0.8TiC specimens with fine grain sizes from 0.58 to 1.45 {mu}m were prepared by mechanical alloying and HIP without any plastic working and tested at 1073 K and 250 MPa in vacuum. It is shown that the creep resistance of V-1.6Y-8W-0.8TiC depends strongly on grain size and increases with increasing grain size: The creep life for the grain size of 1.45 {mu}m is almost one order longer than that of 0.58 {mu}m, and about two orders longer than that of V-4Cr-4Ti (NIFS-Heat 2) although the grain size of V-4Cr-4Ti is as large as 17.8 {mu}m. The observed creep behavior is discussed in terms of grain size effects on dislocation glide and grain boundary sliding.

  16. Growth of large size lithium niobate single crystals of high quality by tilting-mirror-type floating zone method

    Energy Technology Data Exchange (ETDEWEB)

    Sarker, Abdur Razzaque, E-mail: razzaque_ru2000@yahoo.com [Department of Physics, University of Rajshahi (Bangladesh)

    2016-05-15

    Large size high quality LiNbO{sub 3} single crystals were grown successfully by tilting-mirror-type floating zone (TMFZ) technique. The grown crystals were characterized by X-ray diffraction, etch pits density measurement, Impedance analysis, Vibrating sample magnetometry (VSM) and UV-Visible spectrometry. The effect of mirror tilting during growth on the structural, electrical, optical properties and defect density of the LiNbO{sub 3} crystals were investigated. It was found that the defect density in the crystals reduced for tilting the mirror in the TMFZ method. The chemical analysis revealed that the grown crystals were of high quality with uniform composition. The single crystals grown by TMFZ method contains no low-angle grain boundaries, indicating that they can be used for high efficiency optoelectronic devices. (author)

  17. The Effect Of Grain Size On The Mechanical Properties Of Aluminum

    Directory of Open Access Journals (Sweden)

    Jeong G.

    2015-06-01

    Full Text Available Although many studies have focused on the unique plastic deformation behavior of nanocrystalline aluminum (e.g., the positive deviation from Hall-Petch relation, the unusual yield-drop phenomenon in tensile mode, etc., the data reported by different research groups are inconsistent with each other, possibly because of different fabrication processes. In this study, aluminum samples with a wide grain-size spectrum – from a few micrometers down to 100 nanometers – are manufactured by powder metallurgy. The grain size was measured by X-ray diffraction analysis and transmission electron microscope observation. Furthermore, the tensile behavior, which varied according to a grain size, is discussed with a comparison of the theoretical models.

  18. Scattering and Absorption Properties of Polydisperse Wavelength-sized Particles Covered with Much Smaller Grains

    Science.gov (United States)

    Dlugach, Jana M.; Mishchenko, Michael I.; Mackowski, Daniel W.

    2012-01-01

    Using the results of direct, numerically exact computer solutions of the Maxwell equations, we analyze scattering and absorption characteristics of polydisperse compound particles in the form of wavelength-sized spheres covered with a large number of much smaller spherical grains.The results pertain to the complex refractive indices1.55 + i0.0003,1.55 + i0.3, and 3 + i0.1. We show that the optical effects of dusting wavelength-sized hosts by microscopic grains can vary depending on the number and size of the grains as well as on the complex refractive index. Our computations also demonstrate the high efficiency of the new superposition T-matrix code developed for use on distributed memory computer clusters.

  19. Grain-size related nitrogen distribution in southern Yellow Sea surface sediments

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    Forty-eight surface sediments of the southern Yellow Sea are separated into three grain-size fractions. Four forms of extractable nitrogen (nitrogen in ion-exchangeable form (Nie), nitrogen in weak-acid extractable form (Nwa), nitrogen in strong-alkali extractable form (Nsa) and nitrogen in strong-oxidant form (Nso)) are obtained by the sequential extraction. The results show that the contents and the distributions of the extractable nitrogen in the southern Yellow Sea surface sediments are closely related to sediment grain size. The distributions of Nie, Nso and total nitrogen (TN) present positive correlations with fine particles content, while Nwa and Nsa does not have such correlation. The net contents of all the forms of nitrogen increase with sediment grain size finer.

  20. NANOCRYSTALLINE GROWTH AND GRAIN-SIZE EFFECTS IN AU-CU ELECTRODEPOSITS

    Energy Technology Data Exchange (ETDEWEB)

    Jankowski, A F; Saw, C K; Harper, J F; Vallier, R F; Ferreira, J L; Hayes, J P

    2005-02-25

    The processing-structure-property relationship is investigated for electrodeposited foils of the gold-copper alloy system. A model is presented that relates the deposition process parameters to the nanocrystalline grain size. An activation energy of 1.52 eV {center_dot} atom{sup -1} for growth is determined for a long pulse (>10 msec) mode, and is 0.16 eV {center_dot} atom{sup -1} for short pulses (<5 msec). The affect of nanocrystalline grain size on the mechanical properties is assessed using indentation measurements. A Hall-Petch type variation of the Vickers microhardness with nanocrystalline grain size (>6 nm) is observed for Au-Cu samples with 1-12 wt.% Cu as tested in cross-section. The hardness increases three-fold from a rule-of-mixtures value <1 GPa to a maximum of 2.9 GPa.

  1. Effects of grain size and porosity on strength of Li2TiO3 tritium breeding pebbles and its grain growth behavior

    Science.gov (United States)

    Xiang, Maoqiao; Zhang, Yingchun; Zhang, Yun; Wang, Chaofu; Liu, Wei; Yu, Yonghong

    2016-12-01

    Tons of Li2TiO3 tritium breeding pebbles will be filled in the blanket for obtaining tritium fuel. In this work, isothermal sintering was carried out to study the grain growth behavior of the Li2TiO3 pebbles fabricated by agarose method. The grain growth exponent (n) and the activation energy (Q) calculated by the phenomenological kinetic equation were 2 and 435.65 kJ/mol, respectively. The grain growth was controlled by vapor transport (p = 2S/r). In addition, effects of porosity and grain-size on the strength of Li2TiO3 pebbles were investigated. The strength was affected by the grain size and the porosity of Li2TiO3 pebbles, and high strength (about 72 MPa) depended partly on achieving the optimum balance between the porosity (about 10%) and grain size (about 2 μm).

  2. Attempt to detect diamagnetic anisotropy of dust-sized crystal orientated to investigate the origin of interstellar dust alignment

    Science.gov (United States)

    Takeuchi, T.; Hisayoshi, K.; Uyeda, C.

    2013-03-01

    Diamagnetic anisotropy Δ χ dia was detected on a submillimeter-sized calcite crystal by observing the rotational oscillation of its magnetically stable axis with respect to the magnetic field direction. The crystal was released in an area of microgravity generated by a 1.5-m-long drop shaft. When the oscillations are observable, the present method can measure Δ χ dia of crystal grains irrespective of how small they are without measuring the sample mass. In conventional Δ χ measurements, the background signal from the sample holder and the difficulty in measuring the sample mass prevent measurement of Δ χ dia for small samples. The present technique of observing Δ χ dia of a submillimeter-sized single crystal is a step toward realizing Δ χ dia measurements of micron-sized grains. The Δ χ dia values of single micron-sized grains can be used to assess the validity of a dust alignment model based on magnetic torque that originates from the Δ χ dia of individual dust particles.

  3. Tailoring the thermal and electrical transport properties of graphene films by grain size engineering

    Science.gov (United States)

    Ma, Teng; Liu, Zhibo; Wen, Jinxiu; Gao, Yang; Ren, Xibiao; Chen, Huanjun; Jin, Chuanhong; Ma, Xiu-Liang; Xu, Ningsheng; Cheng, Hui-Ming; Ren, Wencai

    2017-02-01

    Understanding the influence of grain boundaries (GBs) on the electrical and thermal transport properties of graphene films is essentially important for electronic, optoelectronic and thermoelectric applications. Here we report a segregation-adsorption chemical vapour deposition method to grow well-stitched high-quality monolayer graphene films with a tunable uniform grain size from ~200 nm to ~1 μm, by using a Pt substrate with medium carbon solubility, which enables the determination of the scaling laws of thermal and electrical conductivities as a function of grain size. We found that the thermal conductivity of graphene films dramatically decreases with decreasing grain size by a small thermal boundary conductance of ~3.8 × 109 W m-2 K-1, while the electrical conductivity slowly decreases with an extraordinarily small GB transport gap of ~0.01 eV and resistivity of ~0.3 kΩ μm. Moreover, the changes in both the thermal and electrical conductivities with grain size change are greater than those of typical semiconducting thermoelectric materials.

  4. Inhomogeneity of the grain size of aircraft engine turbine polycrystalline blades

    Directory of Open Access Journals (Sweden)

    J. Chmiela

    2011-10-01

    Full Text Available The determination of the behaviour of inhomogeneous materials with a complex microstructure requires taking into account the inhomogeneity of the grain size, as it is the basis for the process of designing and modelling effective behaviours. Therefore, the functional description of the inhomogeneity is becoming an important issue. The paper presents an analytical approach to the grain size inhomogeneity, based on the derivative of a logarithmic-logistic function. The solution applied enabled an effective evaluation of the inhomogeneity of two macrostructures of aircraft engine turbine blades, characterized by a high degree of diversity in the grain size. For the investigated single-modal and bimodal grain size distributions on a perpendicular projection and for grains with a non-planar surface, we identified the parameters that describe the degree of inhomogeneity of the constituents of weight distributions and we also derived a formula describing the overall degree of inhomogeneity of bimodal distributions. The solution presented in the paper is of a general nature and it can be used to describe the degree of inhomogeneity of multi-modal distributions. All the calculations were performed using the Mathematica® package.

  5. Grain size evaluation of structural materials in nuclear power plant using a thickness independent ultrasonic method

    Energy Technology Data Exchange (ETDEWEB)

    Li, Xiongbing, E-mail: lixb_ex@163.com [CAD/CAM Institute, Central South University, Changsha 410075 (China); State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083 (China); Song, Yongfeng [CAD/CAM Institute, Central South University, Changsha 410075 (China); Ni, Peijun [The Ningbo Branch of Ordnance Science Institute of China, Ningbo 315103 (China); Wang, Zi; Liu, Feng [State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083 (China); Du, Hualong [Mechanical and Aerospace Engineering Department, North Carolina State University, Raleigh, NC 27606 (United States)

    2015-05-15

    Highlights: •We derive a coefficient of ultrasonic attenuation rate related to the grain size. •The mean grain size of the pipe can be evaluated without measuring its thickness. •Experiments show this method is better suited to square pipe than other methods. -- Abstract: It is important to accurately and nondestructively evaluate the grain size of structural materials used in nuclear power plants. The current ultrasonic non-destructive methods are so dependent on the thickness measurement of a square pipe that it reduces their practicality and reliability. In this paper, a novel method using the coefficient of ultrasonic attenuation rate is developed by using the transmission and reflection coefficients. As a result, the mean grain size of the pipe can be nondestructively evaluated without measuring its thickness. Moreover, the signal preprocessing is studied to improve the stability and accuracy of evaluation results. The experimental results show that the dependence of the attenuation rate on grain sizes is much higher than that of the ultrasonic velocity. The relative error of the attenuation rate method is lower than that of the backscatter method if the thickness of the sample is less than 5 mm. When evaluating a TP304 stainless steel square pipe whose thickness is not convenient to measure, the mean grain sizes are measured 103.5 ± 2.6 μm, 96.9 ± 3.5 μm and 94.0 ± 1.7 μm by the attenuation method, the attenuation rate method and the electron backscattering diffraction method, respectively. The result verifies that the presented method works better than the attenuation method due to the fact that the error of the thickness measurement has no effect on the ultrasonic attenuation rate.

  6. A universal approximation to grain size from images of non-cohesive sediment

    Science.gov (United States)

    Buscombe, D.; Rubin, D.M.; Warrick, J.A.

    2010-01-01

    The two-dimensional spectral decomposition of an image of sediment provides a direct statistical estimate, grid-by-number style, of the mean of all intermediate axes of all single particles within the image. We develop and test this new method which, unlike existing techniques, requires neither image processing algorithms for detection and measurement of individual grains, nor calibration. The only information required of the operator is the spatial resolution of the image. The method is tested with images of bed sediment from nine different sedimentary environments (five beaches, three rivers, and one continental shelf), across the range 0.1 mm to 150 mm, taken in air and underwater. Each population was photographed using a different camera and lighting conditions. We term it a “universal approximation” because it has produced accurate estimates for all populations we have tested it with, without calibration. We use three approaches (theory, computational experiments, and physical experiments) to both understand and explore the sensitivities and limits of this new method. Based on 443 samples, the root-mean-squared (RMS) error between size estimates from the new method and known mean grain size (obtained from point counts on the image) was found to be ±≈16%, with a 95% probability of estimates within ±31% of the true mean grain size (measured in a linear scale). The RMS error reduces to ≈11%, with a 95% probability of estimates within ±20% of the true mean grain size if point counts from a few images are used to correct bias for a specific population of sediment images. It thus appears it is transferable between sedimentary populations with different grain size, but factors such as particle shape and packing may introduce bias which may need to be calibrated for. For the first time, an attempt has been made to mathematically relate the spatial distribution of pixel intensity within the image of sediment to the grain size.

  7. The effect of grain size on the mechanical response of a metastable austenitic stainless steel

    Directory of Open Access Journals (Sweden)

    Sinclair C.W.

    2013-11-01

    Full Text Available The combination of high environmental resistance and excellent strength, elongation and energy absorption make austenitic stainless steels potentially attractive for transportation applications. In the case of metastable grades that undergo a strain induced martensitic transformation it is possible to significantly change the mechanical properties simply by changing the austenite grain size. Predicting such behaviour using physically based models is, however, extremely challenging. Here, some recent work on the coupling between grain size and mechanical response will be presented for a metastable AISI 301 LN stainless steel. Successes and continuing challenges will be highlighted.

  8. Grain size and film thickness effect on the thermal expansion coefficient of FCC metallic thin films.

    Science.gov (United States)

    Hwang, Seulgi; Kim, Youngman

    2011-08-01

    Thin films are used in wide range of applications in industry, such as solar cells and LEDs. When thin films are deposited on substrates, various stresses are generated due to the mechanical difference between the film and substrate. These stresses can cause defects, such as cracking and buckling. Therefore, knowledge of the mechanical properties is important for improving their reliability and stability. In this study, the thermal expansion coefficient of FCC metallic thin films, such as Ag and Cu, which have different grain sizes and thicknesses, were calculated using the thermal cycling method. As a result, thermal expansion coefficient increased with increasing grain size. However, the film thickness had no remarkable effect.

  9. Effect the Grain Size on the Polymer Matrix Composites Reinforced by Reenia Particles

    Directory of Open Access Journals (Sweden)

    Kdhim khaion kahlol

    2013-01-01

    Full Text Available Synthetic polymers such as polyurethane are used widely in the field of biomedical applications such as implants or part of implant systems.This paper focuses on the preparation of base polymer matrix composite materials by (Hand Lay-Up method, and studying the effect of selected grain size (32, 53, 63, 75, and 90 µm of (Reenia particles on some properties of the prepared composite.Mechanical tests were used to evaluate the prepared system (Tensile, Compression, Impact, and Hardness tests, and a physical test of (Water absorption %, and all tests were accomplished at room temperature.Where results showed tensile test (maximum tensile strength and modulus of elasticity high at small grain size while the percentage of elongation decreased with increasing size. As the compressive strength increased with small grain size. And also the values of hardness and fracture energy affected by particle size where the hardness and fracture energy increased at small particles size of compared to larger particles size. While the percentage of water absorption increased at large particle size.In general the results showed clear improvement in properties and maximum values which get it of tensile strength, Modulus of elasticity, elongation percentage, compression strength, fracture energy, hardness and water absorption were as follows ((34.8 MPa, (10%, (268 N/mm2, ( 54.2 MPa,( o.408 J, (78.9 Shor (D, (0.2668 % at using (32µm except water absorption was at (90µm .

  10. Analysis of submicron-sized niflumic acid crystals prepared by electrospray crystallization

    NARCIS (Netherlands)

    Ambrus, R.; Radacsi, N.; Szunyogh, T.; Heijden, A.E.D.M. van der; Horst, J.H. ter; Szabó-Révész, P.

    2013-01-01

    Interest in submicron-sized drug particles has emerged from both laboratory and industrial perspectives in the last decade. Production of crystals in the nano size scale offers a novel way to particles for drug formulation solving formulation problems of drugs with low solubility in class II of the

  11. Linking differential domain functions of the GS3 protein to natural variation of grain size in rice

    OpenAIRE

    Mao, Hailiang; Sun, Shengyuan; Yao, Jialing; Wang, Chongrong; Yu, Sibin; Xu, Caiguo; Li, Xianghua; Zhang, Qifa

    2010-01-01

    Grain yield in many cereal crops is largely determined by grain size. Here we report the genetic and molecular characterization of GS3, a major quantitative trait locus for grain size. It functions as a negative regulator of grain size and organ size. The wild-type isoform is composed of four putative domains: a plant-specific organ size regulation (OSR) domain in the N terminus, a transmembrane domain, a tumor necrosis factor receptor/nerve growth factor receptor (TNFR/NGFR) family cysteine-...

  12. Preferential {100} grain orientation in 10 micrometer-thick laser crystallized multicrystalline silicon on glass

    Energy Technology Data Exchange (ETDEWEB)

    Kühnapfel, S., E-mail: sven.kuehnapfel@helmholtz-berlin.de [Helmholtz-Zentrum Berlin für Materialien und Energie, Institut für Silizium-Photovoltaik, Kekuléstr. 5, 12489 Berlin (Germany); Nickel, N.H.; Gall, S. [Helmholtz-Zentrum Berlin für Materialien und Energie, Institut für Silizium-Photovoltaik, Kekuléstr. 5, 12489 Berlin (Germany); Klaus, M.; Genzel, C. [Helmholtz-Zentrum Berlin für Material und Energie, Abteilung Mikrostruktur- und Eigenspannungsanalyse, Albert-Einstein-Str. 15, 12489 Berlin (Germany); Rech, B.; Amkreutz, D. [Helmholtz-Zentrum Berlin für Materialien und Energie, Institut für Silizium-Photovoltaik, Kekuléstr. 5, 12489 Berlin (Germany)

    2015-02-02

    Liquid phase crystallization of 10 μm thin silicon layers on glass substrates was performed with a line-shaped continuous wave laser beam. The process window was investigated in terms of the scanning velocity of the laser, the pre-heating of the specimens and the applied laser intensity. We have identified the entire process window, in which large-scale crystallization without deformation or destruction of the substrate and cracking of the silicon layer can be obtained. The grain orientations of the resulting Si layers were analyzed using both electron backscatter diffraction (EBSD) and X-ray diffraction (XRD). The influence of the critical crystallization parameters on the grain orientation of the silicon film was examined. EBSD and XRD measurements show that a preferential {100} surface texture and {100} and {101} orientations in scanning direction of the laser can be achieved if appropriate crystallization parameters are used. This texture formation is accompanied with a substantial decrease of high angle grain boundaries. - Highlights: • Zone melting of thin silicon films (10 μm) directly on glass substrates. • The process window was examined in dependence of all process parameters. • A preferential {100} orientation was obtained within a specific parameter range. • A reduction of high angle boundaries is accompanied with the texture formation.

  13. The grain-size distribution of pyroclasts: Primary fragmentation, conduit sorting or abrasion?

    Science.gov (United States)

    Kueppers, U.; Schauroth, J.; Taddeucci, J.

    2013-12-01

    Explosive volcanic eruptions expel a mixture of pyroclasts and lithics. Pyroclasts, fragments of the juvenile magma, record the state of the magma at fragmentation in terms of porosity and crystallinity. The grain size distribution of pyroclasts is generally considered to be a direct consequence of the conditions at magma fragmentation that is mainly driven by gas overpressure in bubbles, high shear rates, contact with external water or a combination of these factors. Stress exerted by any of these processes will lead to brittle fragmentation by overcoming the magma's relaxation timescale. As a consequence, most pyroclasts exhibit angular shapes. Upon magma fragmentation, the gas pyroclast mixture is accelerated upwards and eventually ejected from the vent. The total grain size distribution deposited is a function of fragmentation conditions and transport related sorting. Porous pyroclasts are very susceptible to abrasion by particle-particle or particle-conduit wall interaction. Accordingly, pyroclastic fall deposits with angular clasts should proof a low particle abrasion upon contact to other surfaces. In an attempt to constrain the degree of particle interaction during conduit flow, monomodal batches of washed pyroclasts have been accelerated upwards by rapid decompression and subsequently investigated for their grain size distribution. In our set-up, we used a vertical cylindrical tube without surface roughness as conduit. We varied grain size (0.125-0.25; 0.5-1; 1-2 mm), porosity (0; 10; 30 %), gas-particle ratio (10 and 40%), conduit length (10 and 28 cm) and conduit diameter (2.5 and 6 cm). All ejected particles were collected after settling at the base of a 3.3 m high tank and sieved at one sieve size below starting size (half-Φ). Grain size reduction showed a positive correlation with starting grain size, porosity and overpressure at the vent. Although milling in a volcanic conduit may take place, porous pyroclasts are very likely to be a primary product

  14. Regolith grain sizes of Saturn's rings inferred from Cassini-CIRS far-infrared spectra

    CERN Document Server

    Morishima, Ryuji; Spilker, Linda

    2012-01-01

    We analyze far-infrared (10-650 cm$^{-1}$) emissivity spectra of Saturn's main rings obtained by the Cassini Composite Infrared Spectrometer (CIRS). In modeling of the spectra, the single scattering albedos of regolith grains are calculated using the Mie theory, diffraction is removed with the delta-Eddington approximation, and the hemispherical emissivities of macroscopic free-floating ring particles are calculated using the Hapke's isotropic scattering model. Only pure crystalline water ice is considered and the size distribution of regolith grains is estimated. We find that good fits are obtained if the size distribution is broad ranging from 1 $\\mu$m to 1-10 cm with a power law index of $ \\sim 3$. This means that the largest regolith grains are comparable to the smallest free-floating particles in size and that the power law indices for both free-floating particles and regolith grains are similar to each other. The apparent relative abundance of small grains increases with decreasing solar phase angle (or...

  15. Numerical modelling of intergranular fracture in polycrystalline materials and grain size effects

    Directory of Open Access Journals (Sweden)

    P. Wriggers

    2011-07-01

    Full Text Available In this paper, the phenomenon of intergranular fracture in polycrystalline materials is investigated using a nonlinear fracture mechanics approach. The nonlocal cohesive zone model (CZM for finite thickness interfaces recently proposed by the present authors is used to describe the phenomenon of grain boundary separation. From the modelling point of view, considering the dependency of the grain boundary thickness on the grain size observed in polycrystals, a distribution of interface thicknesses is obtained. Since the shape and the parameters of the nonlocal CZM depend on the interface thickness, a distribution of interface fracture energies is obtained as a consequence of the randomness of the material microstructure. Using these data, fracture mechanics simulations are performed and the homogenized stress-strain curves of 2D representative volume elements (RVEs are computed. Failure is the result of a diffuse microcrack pattern leading to a main macroscopic crack after coalescence, in good agreement with the experimental observation. Finally, testing microstructures characterized by different average grain sizes, the computed peak stresses are found to be dependent on the grain size, in agreement with the trend expected according to the Hall-Petch law.

  16. SSZ-13 Crystallization by Particle Attachment and Deterministic Pathways to Crystal Size Control.

    Science.gov (United States)

    Kumar, Manjesh; Luo, Helen; Román-Leshkov, Yuriy; Rimer, Jeffrey D

    2015-10-14

    Many synthetic and natural crystalline materials are either known or postulated to grow via nonclassical pathways involving the initial self-assembly of precursors that serve as putative growth units for crystallization. Elucidating the pathway(s) by which precursors attach to crystal surfaces and structurally rearrange (postattachment) to incorporate into the underlying crystalline lattice is an active and expanding area of research comprising many unanswered fundamental questions. Here, we examine the crystallization of SSZ-13, which is an aluminosilicate zeolite that possesses exceptional physicochemical properties for applications in separations and catalysis (e.g., methanol upgrading to chemicals and the environmental remediation of NO(x)). We show that SSZ-13 grows by two concerted mechanisms: nonclassical growth involving the attachment of amorphous aluminosilicate particles to crystal surfaces and classical layer-by-layer growth via the incorporation of molecules to advancing steps on the crystal surface. A facile, commercially viable method of tailoring SSZ-13 crystal size and morphology is introduced wherein growth modifiers are used to mediate precursor aggregation and attachment to crystal surfaces. We demonstrate that small quantities of polymers can be used to tune crystal size over 3 orders of magnitude (0.1-20 μm), alter crystal shape, and introduce mesoporosity. Given the ubiquitous presence of amorphous precursors in a wide variety of microporous crystals, insight of the SSZ-13 growth mechanism may prove to be broadly applicable to other materials. Moreover, the ability to selectively tailor the physical properties of SSZ-13 crystals through molecular design offers new routes to optimize their performance in a wide range of commercial applications.

  17. Investigation on grain size effect in high strain rate ductility of 1100 pure aluminum

    Science.gov (United States)

    Bonora, N.; Bourne, N.; Ruggiero, A.; Iannitti, G.; Testa, G.

    2017-01-01

    The effect of the initial grain size on the material ductility at high strain rates in 1100 pure aluminum was investigated. Dynamic tensile extrusion (DTE) tests, at different impact velocities, were performed. Samples have been annealed at 350°C for different exposure times to induce grain growth. Extruded fragments were soft-recovered and the overall length of the extruded jets was used as a measure of material ductility at high strain rates. Numerical simulation of DTE test at different velocity was performed using the modified Rusinek-Klepaczko constitutive model. Results indicates that, as reported for pure copper, the overall ductility of the aluminum increases when grain size decreases. Numerical simulation results were in quite good agreement with experimental data.

  18. Influence of Processing Parameters on Grain Size Evolution of a Forged Superalloy

    Science.gov (United States)

    Reyes, L. A.; Páramo, P.; Salas Zamarripa, A.; de la Garza, M.; Guerrero-Mata, M. P.

    2016-01-01

    The microstructure evolution of nickel-based superalloys has a great influence on the mechanical behavior during service conditions. Microstructure modification and the effect of process variables such as forging temperature, die-speed, and tool heating were evaluated after hot die forging of a heat-resistant nickel-based alloy. Forging sequences in a temperature range from 1253 to 1323 K were considered through experimental trials. An Avrami model was applied using finite element data to evaluate the average grain size and recrystallization at different evolution zones. It was observed that sequential forging at final temperatures below 1273 K provided greater grain refinement through time-dependent recrystallization phenomena. This investigation was aim to explore the influence of forging parameters on grain size evolution in order to design a fully homogenous and refined microstructure after hot die forging.

  19. Low-Angle Grain Boundaries in Sublimation Grown 6H-SiC Crystals

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    High-resolution X-ray diffractometry (HRXRD) was used to assess the quality of 6H-SiC crystals grown by sublimation method. The results show the occurrence of low-angle grain boundaries (LB) is close relative to the inclination of the crystal interface. At the central faceted region with 0° inclination the crystal is of high structural perfection. However, at the region close to the facet with less than 5° inclination LB occurs slightly and at the region close to the peripheral polytype ring with more than 5° inclination LB defect occurs heavily. The density of LB can be drastically reduced by decreasing radial temperature gradient that determines the shape of the crystal growth interface.

  20. Effect of process parameters on crystal size and morphology of lactose in ultrasound-assisted crystallization

    Energy Technology Data Exchange (ETDEWEB)

    Patel, S.R.; Murthy, Z.V.P. [Chemical Engineering Department, S.V. National Institute of Technology, Surat - 395 007, Gujarat (India)

    2011-03-15

    {alpha}-lactose monohydrate is widely used as a pharmaceutical excipient. Drug delivery system requires the excipient to be of narrow particle size distribution with regular particle shape. Application of ultrasound is known to increase or decrease the growth rate of certain crystal faces and controls the crystal size distribution. In the present paper, effect of process parameters such as sonication time, anti-solvent concentration, initial lactose concentration and initial pH of sample on lactose crystal size, shape and thermal transition temperature was studied. The parameters were set according to the L{sub 9}-orthogonal array method at three levels and recovered lactose from whey by sonocrystallization. The recovered lactose was analyzed by particle size analyzer, scanning electron microscopy and differential scanning calorimeter. It was found that the morphology of lactose crystal was rod/needle like shape. Crystal size distribution of lactose was observed to be influenced by different process parameters. From the results of analysis of variance, the sonication time interval was found to be the most significant parameter affecting the volume median diameter of lactose with the highest percentage contribution (74.28%) among other parameters. (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  1. Response of grain size of Quaternary gravels to climate and tectonics in the northern Tibetan Plateau

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The widely distributed thick gravel deposits along the rim of the Tibetan Plateau have been long thought to be the product of rapid tectonic uplift of the plateau. However, this has been challenged by recent works that suggest these thick gravels may be the result of climate change. In this paper we carried out a detailed field measurement of gravel grain sizes from the Jiuquan and Gobi Gravel Beds in the top of the Laojunmiao section in the Jiuxi Basin in the northern margin of Qilian Mts. (northern Tibetan Plateau). The results suggest that the grain sizes of the Jiuquan and Gobi Gravel Beds over the last 0.8 Ma are characterized by nine coarse-fine cycles having strong 100-ka and 41-ka periodicities that correlate well with the loess-paleosol monsoon record and isotopic global climatic record from deep sea sediments as well as by a long trend of coarsening in gravel grain size. The coarse gravel layers were formed during the warm-humid interglaciations while the fine layers correspond to the cold-dry glaciations. Because the paleoclimate in NW China began to get dramatically drier after the mid-Pleistocene, we think the persistent coarsening of gravel grain size was most probably caused by the rapid uplift of the northern Tibetan Plateau, and that the orbital scale cyclic variations in gravel grain size were driven by orbital forcing factors that were superimposed on the tectonically-forced long-term coarsening trend in gravel size. These findings also shed new light on the interaction results of climate and tectonics in relation to the uplift of the Tibetan Plateau.

  2. The grain-size characteristics of Quaternary deposits at Xingshan near Siping in Jilin province, China

    Institute of Scientific and Technical Information of China (English)

    Maxwell A Boateng; Xikui Wang

    2006-01-01

    This research paper analyses the grain-size characteristics of the Quaternary deposits at Xingshan near Siping, Jilin province in China by employing graphic measures to study the grain size distribution and its mode of transport and deposition. The Quaternary deposits at Xingshan lie unconformable on Cretaceous rocks made of siltstone, mudstone and sandstone. The average grain size is between 8.06 to 8.55Φ (0.002 6 ~0.003 7 mm). The Quaternary deposits at Xingshan mainly compose of very fine silt to clay. The compositions of the grade are clay 63% and silt 37%. The clay size components are weathered debris transported and deposited by flowing water from the SE highlands or hills to the low lying NW Xingshan plains whereas the silty components accumulated by aoelian process. The Quaternary deposits at Xingshan accumulated in the middle and late Pleistocene interglacial periods from (459.12~39.03) ka to (88.92~7.56) ka. The standard deviation ranged from 0.96 to 1.36Φ, indicating that the sediments are moderately to poorly sorted, Coefficient of skewness ranged from 0.16~0.31 with an average skewness of 0.218, (Positively skewed towards fine). Kurtosis values (0.84~1.05) from the grain size distribution and visual inspection of the frequency curves indicate platykurtic to mesokurtic curves and unimodal to bimodal grain-size distribution. The type of deposit formation is sand dune and the source is at a distal from its provenance.

  3. THE INFLUENCE OF GRAIN SIZE AND TEMPERATURE ON THE MECHANICAL DEFORMATION OF NANOCRYSTALLINE MATERIALS:MOLECULAR DYNAMICS SIMULATION

    Institute of Scientific and Technical Information of China (English)

    WEN YU-HUA; ZHOU FU-XIN; LIU YUE-WU

    2001-01-01

    Nanocrystalline (nc) materials are characterized by a typical grain size of 1-100nm. The uniaxial tensile deformation of computer-generated nc samples, with several average grain sizes ranging from 5.38 to 1.79nm, is simulated by using molecular dynamics with the Finnis-Sinclair potential. The influence of grain size and temperature on the mechanical deformation is studied in this paper. The simulated nc samples show a reverse Hall-Petch effect. Grain boundary sliding and motion, as well as grain rotation are mainly responsible for the plastic deformation. At low temperatures, partial dislocation activities play a minor role during the deformation. This role begins to occur at the strain of 5%, and is progressively remarkable with increasing average grain size. However, at elevated temperatures no dislocation activity is detected, and the diffusion of grain boundaries may come into play.

  4. Microstructure and mechanical strength of near- and sub-micrometre grain size copper prepared by spark plasma sintering

    DEFF Research Database (Denmark)

    Zhu, K. N.; Godfrey, A.; Hansen, Niels

    2017-01-01

    Spark plasma sintering (SPS) has been used to prepare fully dense samples of copper in a fully recrystallized condition with grain sizes in the near- and sub-micrometre regime. Two synthesis routes have been investigated to achieve grain size control: (i) SPS at different temperatures from 800 to...... been probed using hardness measurements and tensile testing, revealing an enhanced strength for samples with grain sizes less than ≈ 1 μm....

  5. Influence of temperature, grain size and cobalt content on the hardness of WC-Co alloys

    CSIR Research Space (South Africa)

    Milman, YV

    1999-01-01

    Full Text Available The Vickers hardness of WC-Co alloys has been measured at temperatures ranging from -196 to 900 degrees C. The cobalt content of the alloys ranged from 10 to 24 vol% and the grain size from 0.5 to 2.3 um. It was found that, at all cobalt contents...

  6. Discrimination of sediment provenance in the Yellow Sea: Secondary grain-size effect and REE proxy

    Science.gov (United States)

    Jung, Hoi-Soo; Lim, Dhongil; Jeong, Do-Hyun; Xu, Zhaokai; Li, Tiegang

    2016-06-01

    This study analyzed grain size and elemental concentrations (Al, Mg, Fe, and rare earth elements (REEs)) in 91 surface sediments to elucidate sediment provenance in the Yellow Sea. Elemental concentrations were normalized by Al concentration (Celement/CAl) to minimize the sediment grain-size effect (GSE). However, noticeable linear relationships between Al concentration (or mean grain size) and the ratio (e.g., Mg/Al or Fe/Al) appeared unexpectedly in pair diagrams. The spatial distribution patterns of Fe/Al and Mg/Al ratios were also similar to the pattern of mean grain size. This implies that the GSE was not removed completely, even after the normalization process. Thus, great care must be taken when applying the ratios of Celement/CAl as a proxy of sediment provenance. To improve provenance discrimination of the sediments in the Yellow Sea, the difference between the REE distribution patterns of Chinese and Korean river sediments, expressed as δ (δ = REE∗(La) - REE∗(Lu)), was calculated, and the spatial distribution patterns of the δ values were mapped. The δ values gradually increased from the western to the eastern part of the Yellow Sea, except for low δ values in the southeastern part of the Yellow Sea. This result indicates that the majority of Chinese and Korean river sediments are accumulating near to their respective coasts, except for a deposit along the southwestern coast of Korea in which a considerable amount of sediment from Chinese rivers has been accumulating.

  7. Using LiDAR derivatives to estimate sediment grain size on beaches in False Bay

    CSIR Research Space (South Africa)

    Burns, J

    2017-05-01

    Full Text Available to global and climate change in particular, continues to have a big impact on coastal environments. The vulnerability of the sandy coast is dependent on the physical characteristics such as orientation/exposure, beach slope, and sand grain size...

  8. Agriproteomics of Bread Wheat: Comparative Proteomics and Network Analyses of Grain Size Variation.

    Science.gov (United States)

    Dawkar, Vishal V; Dholakia, Bhushan B; Gupta, Vidya S

    2015-07-01

    Agriproteomics signifies the merging of agriculture research and proteomics systems science and is impacting plant research and societal development. Wheat is a frequently consumed foodstuff, has highly variable grain size that in effect contributes to wheat grain yield and the end-product quality. Very limited information is available on molecular basis of grain size due to complex multifactorial nature of this trait. Here, using liquid chromatography-mass spectrometry, we investigated the proteomics profiles from grains of wheat genotypes, Rye selection 111 (RS111) and Chinese spring (CS), which differ in their size. Significant differences in protein expression were found, including 33 proteins uniquely present in RS111 and 32 only in CS, while 54 proteins were expressed from both genotypes. Among differentially expressed proteins, 22 were upregulated, while 21 proteins were downregulated in RS111 compared to CS. Functional classification revealed their role in energy metabolism, seed storage, stress tolerance and transcription. Further, protein interactive network analysis was performed to predict the targets of identified proteins. Significantly different interactions patterns were observed between these genotypes with detection of proteins such as Cyp450, Sus2, and WRKY that could potentially affect seed size. The present study illustrates the potentials of agriproteomics as a veritable new frontier of plant omics research.

  9. Optimal foraging in the thalassinidean shrimp Callianassa subterranea - Improving food quality by grain size selection

    NARCIS (Netherlands)

    Stamhuis, EJ; Videler, JJ; de Wilde, PAWJ

    1998-01-01

    The grain size distributions and organic content of habitat sediment, stomach content and faecal pellets of the endobenthic shrimp C. subterranea were analyzed to study food selection and its nutritional yield. Sub-samples of sediment from the shrimps' habitat and the stomach content were fractioned

  10. Effects of grain size distribution on the packing fraction and shear strength of frictionless disk packings

    Science.gov (United States)

    Estrada, Nicolas

    2016-12-01

    Using discrete element methods, the effects of the grain size distribution on the density and the shear strength of frictionless disk packings are analyzed. Specifically, two recent findings on the relationship between the system's grain size distribution and its rheology are revisited, and their validity is tested across a broader range of distributions than what has been used in previous studies. First, the effects of the distribution on the solid fraction are explored. It is found that the distribution that produces the densest packing is not the uniform distribution by volume fractions as suggested in a recent publication. In fact, the maximal packing fraction is obtained when the grading curve follows a power law with an exponent close to 0.5 as suggested by Fuller and Thompson in 1907 and 1919 [Trans Am. Soc. Civ. Eng. 59, 1 (1907) and A Treatise on Concrete, Plain and Reinforced (1919), respectively] while studying mixtures of cement and stone aggregates. Second, the effects of the distribution on the shear strength are analyzed. It is confirmed that these systems exhibit a small shear strength, even if composed of frictionless particles as has been shown recently in several works. It is also found that this shear strength is independent of the grain size distribution. This counterintuitive result has previously been shown for the uniform distribution by volume fractions. In this paper, it is shown that this observation keeps true for different shapes of the grain size distribution.

  11. Comparison of geostatistical kriging algorithms for intertidal surface sediment facies mapping with grain size data.

    Science.gov (United States)

    Park, No-Wook; Jang, Dong-Ho

    2014-01-01

    This paper compares the predictive performance of different geostatistical kriging algorithms for intertidal surface sediment facies mapping using grain size data. Indicator kriging, which maps facies types from conditional probabilities of predefined facies types, is first considered. In the second approach, grain size fractions are first predicted using cokriging and the facies types are then mapped. As grain size fractions are compositional data, their characteristics should be considered during spatial prediction. For efficient prediction of compositional data, additive log-ratio transformation is applied before cokriging analysis. The predictive performance of cokriging of the transformed variables is compared with that of cokriging of raw fractions in terms of both prediction errors of fractions and facies mapping accuracy. From a case study of the Baramarae tidal flat, Korea, the mapping method based on cokriging of log-ratio transformation of fractions outperformed the one based on cokriging of untransformed fractions in the prediction of fractions and produced the best facies mapping accuracy. Indicator kriging that could not account for the variation of fractions within each facies type showed the worst mapping accuracy. These case study results indicate that the proper processing of grain size fractions as compositional data is important for reliable facies mapping.

  12. Comparison of Geostatistical Kriging Algorithms for Intertidal Surface Sediment Facies Mapping with Grain Size Data

    Directory of Open Access Journals (Sweden)

    No-Wook Park

    2014-01-01

    Full Text Available This paper compares the predictive performance of different geostatistical kriging algorithms for intertidal surface sediment facies mapping using grain size data. Indicator kriging, which maps facies types from conditional probabilities of predefined facies types, is first considered. In the second approach, grain size fractions are first predicted using cokriging and the facies types are then mapped. As grain size fractions are compositional data, their characteristics should be considered during spatial prediction. For efficient prediction of compositional data, additive log-ratio transformation is applied before cokriging analysis. The predictive performance of cokriging of the transformed variables is compared with that of cokriging of raw fractions in terms of both prediction errors of fractions and facies mapping accuracy. From a case study of the Baramarae tidal flat, Korea, the mapping method based on cokriging of log-ratio transformation of fractions outperformed the one based on cokriging of untransformed fractions in the prediction of fractions and produced the best facies mapping accuracy. Indicator kriging that could not account for the variation of fractions within each facies type showed the worst mapping accuracy. These case study results indicate that the proper processing of grain size fractions as compositional data is important for reliable facies mapping.

  13. Retrieval of snow albedo and grain size using reflectance measurements in Himalayan basin

    Directory of Open Access Journals (Sweden)

    H. S. Negi

    2011-03-01

    Full Text Available In the present paper, spectral reflectance measurements of Himalayan seasonal snow were carried out and analysed to retrieve the snow albedo and effective grain size. The asymptotic radiative transfer (ART theory was applied to retrieve the plane and spherical albedo. The retrieved plane albedo was compared with the measured spectral albedo and a good agreement was observed with ±10% differences. Retrieved integrated albedo was found within ±6% difference with ground observed broadband albedo. The retrieved snow grain sizes using different models based on the ART theory were compared for various snow types and it was observed that the grain size model using two channel method (one in visible and another in NIR region can work well for the Himalayan seasonal snow and it was found consistent with temporal changes in grain size. This method can work very well for clean, dry snow as in the upper Himalaya, but sometimes, due to the low reflectances (<20% using wavelength 1.24 μm, the ART theory cannot be applied, which is common in lower and middle Himalayan old snow. This study is important for monitoring the Himalayan cryosphere using air-borne or space-borne sensors.

  14. Modeling grain-size dependent bias in estimating forest area: a regional application

    Science.gov (United States)

    Daolan Zheng; Linda S. Heath; Mark J. Ducey

    2008-01-01

    A better understanding of scaling-up effects on estimating important landscape characteristics (e.g. forest percentage) is critical for improving ecological applications over large areas. This study illustrated effects of changing grain sizes on regional forest estimates in Minnesota, Wisconsin, and Michigan of the USA using 30-m land-cover maps (1992 and 2001)...

  15. Retrieval of snow albedo and grain size using reflectance measurements in Himalayan basin

    Directory of Open Access Journals (Sweden)

    H. S. Negi

    2010-11-01

    Full Text Available In the present paper spectral reflectance measurements of Himalayan seasonal snow were carried out and analysed to retrieve the snow albedo and effective grain size. The asymptotic radiative transfer (ART theory was applied to retrieve the plane and spherical albedo. The retrieved plane albedo was compared with the measured spectral albedo and a good agreement was observed with ±10% measured error accuracy. Retrieved integrated albedo was found within ±6% difference with ground observed broadband albedo. The snow grain sizes retrieved using different models based on ART theory are compared for different snow types and it was observed that presently grain size model using two channel method (one in visible and another in NIR region can work well for Himalayan seasonal snow and it was found consistence with temporal increased grain size. This method can work very well for clean dry snow like in upper Himalaya but sometime due to low reflectances (<0.2 using wavelength 1.24 μm ART theory can not be applied, which is common in lower and middle Himalayan old snow. This study is of importance for monitoring the Himalayan cryosphere using air-borne or space-borne sensors.

  16. Ceramography and segmentation of polycristalline ceramics: application to grain size analysis by automatic methods

    Energy Technology Data Exchange (ETDEWEB)

    Arnould, X.; Coster, M.; Chermant, J.L.; Chermant, L. [LERMAT, ISMRA, Caen (France); Chartier, T. [SPCTS, ENSCI, Limoges (France)

    2002-07-01

    The knowledge of the mean grain size of ceramics is a very important problem to solve in the ceramic industry. Some specific methods of segmentation are presented to analyse, by an automatic way, the granulometry and morphological parameters of ceramic materials. Example presented concerns cerine materials. Such investigations lead to important information on the sintering process. (orig.)

  17. Distribution of grain size and clay minerals in sediments from the INDEX area, central Indian Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Valsangkar, A.B.; Ambre, N.V.

    ,R.,H. L. Howa,and D. Michel. 1996. Application of grain size trend analysis for the determination of sediment transport pathways in intertidal areas. Marine Geology135:35–49.Pettijohn,F. G.,P. D. Potter,and R. Siever. 1972. Sand and Sandstone.New York...

  18. Power law olivine crystal size distributions in lithospheric mantle xenoliths

    Science.gov (United States)

    Armienti, P.; Tarquini, S.

    2002-12-01

    Olivine crystal size distributions (CSDs) have been measured in three suites of spinel- and garnet-bearing harzburgites and lherzolites found as xenoliths in alkaline basalts from Canary Islands, Africa; Victoria Land, Antarctica; and Pali Aike, South America. The xenoliths derive from lithospheric mantle, from depths ranging from 80 to 20 km. Their textures vary from coarse to porphyroclastic and mosaic-porphyroclastic up to cataclastic. Data have been collected by processing digital images acquired optically from standard petrographic thin sections. The acquisition method is based on a high-resolution colour scanner that allows image capturing of a whole thin section. Image processing was performed using the VISILOG 5.2 package, resolving crystals larger than about 150 μm and applying stereological corrections based on the Schwartz-Saltykov algorithm. Taking account of truncation effects due to resolution limits and thin section size, all samples show scale invariance of crystal size distributions over almost three orders of magnitude (0.2-25 mm). Power law relations show fractal dimensions varying between 2.4 and 3.8, a range of values observed for distributions of fragment sizes in a variety of other geological contexts. A fragmentation model can reproduce the fractal dimensions around 2.6, which correspond to well-equilibrated granoblastic textures. Fractal dimensions >3 are typical of porphyroclastic and cataclastic samples. Slight bends in some linear arrays suggest selective tectonic crushing of crystals with size larger than 1 mm. The scale invariance shown by lithospheric mantle xenoliths in a variety of tectonic settings forms distant geographic regions, which indicate that this is a common characteristic of the upper mantle and should be taken into account in rheological models and evaluation of metasomatic models.

  19. Determination of crystal grain orientations by optical microscopy at textured surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Lausch, D.; Gläser, M.; Hagendorf, C. [Team Mikrostrukturdiagnostik und Analytik, Fraunhofer-Center für Silizium-Photovoltaik CSP, Walter-Hülse-Straße 1 Halle (Saale), Sachsen-Anhalt D-06120 (Germany)

    2013-11-21

    In this contribution, a new method to determine the crystal orientation with the example of chemical treated silicon wafers by means of optical microscopy has been demonstrated. The introduced procedure represents an easy method to obtain all relevant parameters to describe the crystal structure of the investigated material, i.e., the crystal grain orientation and the grain boundary character. The chemical treatment is a standard mono-texture for solar cells, well known in the solar industry. In general, this concept can also be applied to other crystalline materials, i.e., GaAs, SiC, etc., the only thing that needs to be adjusted is the texturing method to reveal specific crystal planes and the calculation model. In conclusion, an application of this method is shown with the example of the defect classification of recombination active defects in mc-Si solar cell. The introduced method demonstrates a simple and quick opportunity to improve the crystallization process and the quality of electronic devices by means of an optical microscope and a chemical treatment of the material.

  20. Dolomite microstructures between 390° and 700 °C: Indications for deformation mechanisms and grain size evolution

    Science.gov (United States)

    Berger, Alfons; Ebert, Andreas; Ramseyer, Karl; Gnos, Edwin; Decrouez, Danielle

    2016-08-01

    Dolomitic marble on the island of Naxos was deformed at variable temperatures ranging from 390 °C to >700 °C. Microstructural investigations indicate two end-member of deformation mechanisms: (1) Diffusion creep processes associated with small grain sizes and weak or no CPO (crystallographic preferred orientation), whereas (2) dislocation creep processes are related with larger grain sizes and strong CPO. The change between these mechanisms depends on grain size and temperature. Therefore, sample with dislocation and diffusion creep microstructures and CPO occur at intermediate temperatures in relative pure dolomite samples. The measured dolomite grain size ranges from 3 to 940 μm. Grain sizes at Tmax >450 °C show an Arrhenius type evolution reflecting the stabilized grain size in deformed and relative pure dolomite. The stabilized grain size is five times smaller than that of calcite at the same temperature and shows the same Arrhenius-type evolution. In addition, the effect of second phase particle influences the grain size evolution, comparable with calcite. Calcite/dolomite mixtures are also characterized by the same difference in grain size, but recrystallization mechanism including chemical recrystallization induced by deformation may contribute to apparent non-temperature equilibrated Mg-content in calcite.

  1. Enhanced Sucrose Loading Improves Rice Yield by Increasing Grain Size1[OPEN

    Science.gov (United States)

    Wang, Liang; Lu, Qingtao

    2015-01-01

    Yield in cereals is a function of grain number and size. Sucrose (Suc), the main carbohydrate product of photosynthesis in higher plants, is transported long distances from source leaves to sink organs such as seeds and roots. Here, we report that transgenic rice plants (Oryza sativa) expressing the Arabidopsis (Arabidopsis thaliana) phloem-specific Suc transporter (AtSUC2), which loads Suc into the phloem under control of the phloem protein2 promoter (pPP2), showed an increase in grain yield of up to 16% relative to wild-type plants in field trials. Compared with wild-type plants, pPP2::AtSUC2 plants had larger spikelet hulls and larger and heavier grains. Grain filling was accelerated in the transgenic plants, and more photoassimilate was transported from the leaves to the grain. In addition, microarray analyses revealed that carbohydrate, amino acid, and lipid metabolism was enhanced in the leaves and grain of pPP2::AtSUC2 plants. Thus, enhancing Suc loading represents a promising strategy to improve rice yield to feed the global population. PMID:26504138

  2. Grain size stabilization of nanocrystalline copper at high temperatures by alloying with tantalum

    Energy Technology Data Exchange (ETDEWEB)

    Darling, K.A., E-mail: kristopher.darling.civ@mail.mil [U.S. Army Research Laboratory, Weapons and Materials Research Directorate, Aberdeen Proving Ground, MD 21005-5069 (United States); Roberts, A.J. [ORISE Program, U.S. Army Research Laboratory, Aberdeen Proving Ground, MD 21005-5069 (United States); Mishin, Y. [George Mason University, Dept of Physics and Astronomy, Fairfax, VA 22030 (United States); Mathaudhu, S.N. [U.S. Army Research Laboratory, Army Research Office, Research Triangle Park, NC 27709-2211 (United States); Kecskes, L.J. [U.S. Army Research Laboratory, Weapons and Materials Research Directorate, Aberdeen Proving Ground, MD 21005-5069 (United States)

    2013-10-05

    Highlights: •A mean grain size of 167 nm is retained after annealing at 97% of the melting point. •Hardness surpasses conventional pure nanocrystalline Cu by 2.5 GPa. •Extreme stability is attributed to both thermodynamic and kinetic stabilization. -- Abstract: Nanocrystalline Cu–Ta alloys belong to an emerging class of immiscible materials with potential for high-temperature applications. Differential scanning calorimetry (DSC), Vickers microhardness, transmission and scanning electron microscopy (TEM/SEM), and atomistic simulations have been applied to study the structural evolution in high-energy cryogenically alloyed nanocrystalline Cu–10 at.%Ta. The thermally induced coarsening of the as-milled microstructure was investigated and it was found that the onset of grain growth occurs at temperatures higher than that for pure nanocrystalline Cu. The total heat release associated with grain growth was 0.553 kJ/mol. Interestingly, nanocrystalline Cu–10 at.%Ta maintains a mean grain size (GS) of 167 nm after annealing at 97% of its melting point. The increased microstructural stability is attributed to a combination of thermodynamic and kinetic stabilization effects which, in turn, appear to be controlled by segregation and diffusion of Ta solute atoms along grain boundaries (GBs). The as-milled nanocrystalline Cu–10 at.%Ta exhibits Vickers microhardness values near 5 GPa surpassing the microhardness of conventional pure nanocrystalline Cu by ∼2.5 GPa.

  3. Hardening by ion implantation of VT1-0 alloy having different grain size

    Energy Technology Data Exchange (ETDEWEB)

    Nikonenko, Alisa, E-mail: aliska-nik@mail.ru; Kurzina, Irina, E-mail: kurzina99@mail.ru [National Research Tomsk State University, 36, Lenin Str., 634050, Tomsk (Russian Federation); Popova, Natalya, E-mail: natalya-popova-44@mail.ru [Tomsk State University of Architecture and Building, 2, Solyanaya Sq., 634003, Tomsk (Russian Federation); Institute of Strength Physics and Materials Science, SB RAS, 2/4, Akademicheskii Ave., 634021, Tomsk Russia (Russian Federation); Nikonenko, Elena, E-mail: vilatomsk@mail.ru [Tomsk State University of Architecture and Building, 2, Solyanaya Sq., 634003, Tomsk (Russian Federation); National Research Tomsk Polytechnic University, 30, Lenin Str., 634050, Tomsk (Russian Federation); Kalashnikov, Mark, E-mail: kmp1980@mail.ru [Institute of Strength Physics and Materials Science, SB RAS, 2/4, Akademicheskii Ave., 634021, Tomsk Russia (Russian Federation)

    2016-01-15

    The paper presents a transmission electron microscopy (TEM) study of the structural and phase state of commercially pure titanium implanted by aluminum ions. TEM study has been carried out for two types of grains, namely coarse (0.4 µm) and small (0.5 µm). This paper presents details of the yield stress calculations and the analysis of strength components for the both grain types in two areas of the modified layer: at a distance of 0-150 nm (surface area I) and ∼300 nm (central area II) from the irradiated surface. It is shown that the ion implantation results in a considerable hardening of the entire thickness of the implanted layer in the both grain types. The grain size has, however, a different effect on the yield stress in areas I and II. Thus, near the ion-alloyed layer, the yield stress decreases with the increase of the grain size, whilst area II demonstrates its increase. Moreover, the contribution to the general hardening of the alloy made by certain hardening mechanisms differs from contributions made by each of these mechanisms in each certain case.

  4. Magnetic properties in an ash flow tuff with continuous grain size variation: a natural reference for magnetic particle granulometry

    Science.gov (United States)

    Till, J.L.; Jackson, M.J.; Rosenbaum, J.G.; Solheid, P.

    2011-01-01

    The Tiva Canyon Tuff contains dispersed nanoscale Fe-Ti-oxide grains with a narrow magnetic grain size distribution, making it an ideal material in which to identify and study grain-size-sensitive magnetic behavior in rocks. A detailed magnetic characterization was performed on samples from the basal 5 m of the tuff. The magnetic materials in this basal section consist primarily of (low-impurity) magnetite in the form of elongated submicron grains exsolved from volcanic glass. Magnetic properties studied include bulk magnetic susceptibility, frequency-dependent and temperature-dependent magnetic susceptibility, anhysteretic remanence acquisition, and hysteresis properties. The combined data constitute a distinct magnetic signature at each stratigraphic level in the section corresponding to different grain size distributions. The inferred magnetic domain state changes progressively upward from superparamagnetic grains near the base to particles with pseudo-single-domain or metastable single-domain characteristics near the top of the sampled section. Direct observations of magnetic grain size confirm that distinct transitions in room temperature magnetic susceptibility and remanence probably denote the limits of stable single-domain behavior in the section. These results provide a unique example of grain-size-dependent magnetic properties in noninteracting particle assemblages over three decades of grain size, including close approximations of ideal Stoner-Wohlfarth assemblages, and may be considered a useful reference for future rock magnetic studies involving grain-size-sensitive properties.

  5. Coarse-grained molecular dynamics studies of cluster-bombarded benzene crystals

    Energy Technology Data Exchange (ETDEWEB)

    Smiley, Edward J. [Department of Chemistry, Penn State University, 104 Chemistry Building, University Park, PA 16802 (United States)]. E-mail: ejs236@psu.edu; Postawa, Zbigniew [Smoluchowski Institute of Physics, Jagiellonian University, Cracow (Poland); Wojciechowski, Igor A. [Department of Chemistry, Penn State University, 104 Chemistry Building, University Park, PA 16802 (United States); Winograd, Nicholas [Department of Chemistry, Penn State University, 104 Chemistry Building, University Park, PA 16802 (United States); Garrison, Barbara J. [Department of Chemistry, Penn State University, 104 Chemistry Building, University Park, PA 16802 (United States)

    2006-07-30

    As high-energy cluster projectile beams become standard analysis probes for SIMS, simulating larger crystals is now a requirement for the modeling community due to the large sputtering yields. As crystals get larger, computer resources become a limitation. Even though computer technology has evolved to include large memory systems and fast processors, there are still issues with having sufficient resources to run a calculation. This manuscript reports a method of studying a full crystal of benzene after impact with a 500 eV C{sub 60} projectile using a coarse-grained model. The potentials developed for this model incorporate the C-H bond of benzene into a single coarse-grained bead. This coarse-grained method has several advantages over atomistic models-the amount of time to perform these calculations has been drastically reduced and the potentials for this sample are pair-wise additive potentials. A discussion is made as to how these results compare to those obtained with fully atomistic calculations using the AIREBO potential.

  6. Sparsity-based image monitoring of crystal size distribution during crystallization

    Science.gov (United States)

    Liu, Tao; Huo, Yan; Ma, Cai Y.; Wang, Xue Z.

    2017-07-01

    To facilitate monitoring crystal size distribution (CSD) during a crystallization process by using an in-situ imaging system, a sparsity-based image analysis method is proposed for real-time implementation. To cope with image degradation arising from in-situ measurement subject to particle motion, solution turbulence, and uneven illumination background in the crystallizer, sparse representation of a real-time captured crystal image is developed based on using an in-situ image dictionary established in advance, such that the noise components in the captured image can be efficiently removed. Subsequently, the edges of a crystal shape in a captured image are determined in terms of the salience information defined from the denoised crystal images. These edges are used to derive a blur kernel for reconstruction of a denoised image. A non-blind deconvolution algorithm is given for the real-time reconstruction. Consequently, image segmentation can be easily performed for evaluation of CSD. The crystal image dictionary and blur kernels are timely updated in terms of the imaging conditions to improve the restoration efficiency. An experimental study on the cooling crystallization of α-type L-glutamic acid (LGA) is shown to demonstrate the effectiveness and merit of the proposed method.

  7. Strain Amount Dependent Grain Size and Orientation Developments during Hot Compression of a Polycrystalline Nickel Based Superalloy

    Directory of Open Access Journals (Sweden)

    Guoai He

    2017-02-01

    Full Text Available Controlling grain size in polycrystalline nickel base superalloy is vital for obtaining required mechanical properties. Typically, a uniform and fine grain size is required throughout forging process to realize the superplastic deformation. Strain amount occupied a dominant position in manipulating the dynamic recrystallization (DRX process and regulating the grain size of the alloy during hot forging. In this article, the high-throughput double cone specimen was introduced to yield wide-range strain in a single sample. Continuous variations of effective strain ranging from 0.23 to 1.65 across the whole sample were achieved after reaching a height reduction of 70%. Grain size is measured to be decreased from the edge to the center of specimen with increase of effective strain. Small misorientation tended to generate near the grain boundaries, which was manifested as piled-up dislocation in micromechanics. After the dislocation density reached a critical value, DRX progress would be initiated at higher deformation region, leading to the refinement of grain size. During this process, the transformations from low angle grain boundaries (LAGBs to high angle grain boundaries (HAGBs and from subgrains to DRX grains are found to occur. After the accomplishment of DRX progress, the neonatal grains are presented as having similar orientation inside the grain boundary.

  8. Grain size distribution and annual variation along the beaches from Poompuhar to Nagoor, Tamilnadu, India

    Digital Repository Service at National Institute of Oceanography (India)

    Chandrasekaran, R.; Angusamy, N.; Manickaraj, D.S.; Loveson, V.J.; Gujar, A.R.; Chandrasekar, N.; Rajamanickam, G.V.

    samples, peaks are represented in the order of dominance by 1.86, 2.35, 2.87 Ø, whereas it is found to be the reverse in the post-tsunami sample. In Kuttiyandiur, polymodal distribution of LT and HT samples of pre and post- tsunami displays similar... (Tab.2). In the present study region, graphic mean size of the LT, HT samples of Poompuhar show that sediments are of medium grained in pre and post-tsunami whereas the berm samples display a change in characteristics from medium grained...

  9. Grain size dependent optical band gap of CdI2 films

    Indian Academy of Sciences (India)

    Pankaj Tyagi; A G Vedeshwar

    2001-06-01

    The thermally evaporated stoichiometric CdI2 films show good -axis alignment normal to substrate plane for film thickness up to 200 nm. The optical absorption data indicate an allowed direct interband transition across a gap of 3.6 eV in confirmation with earlier band structure calculations. However, part of the absorption data near band edge can be fitted to an indirect band gap of 3 eV. The dependence of band gap on film thickness (> 200 nm) can be explained qualitatively in terms of decreasing grain boundary barrier height with grain size.

  10. On Techniques to Characterize and Correlate Grain Size, Grain Boundary Orientation and the Strength of the SiC Layer of TRISO Coated Particles: A Preliminary Study

    Energy Technology Data Exchange (ETDEWEB)

    I.J.van Rooyen; J.L. Dunzik Gougar; T. Trowbridge; Philip M van Rooyen

    2012-10-01

    The mechanical properties of the silicon carbide (SiC) layer of the TRi-ISOtropic (TRISO) coated particle (CP) for high temperature gas reactors (HTGR) are performance parameters that have not yet been standardized by the international HTR community. Presented in this paper are the results of characterizing coated particles to reveal the effect of annealing temperature (1000 to 2100°C) on the strength and grain size of unirradiated coated particles. This work was further expanded to include possible relationships between the grain size and strength values. The comparative results of two strength measurement techniques and grain size measured by the Lineal intercept method are included. Preliminary grain boundary characterization results determined by electron backscatter diffraction (EBSD) are included. These results are also important for future fission product transport studies, as grain boundary diffusion is identified as a possible mechanism by which 110mAg, one of the fission activation products, might be released through intact SiC layers. Temperature is a parameter known to influence the grain size of SiC and therefore it is important to investigate the effect of high temperature annealing on the SiC grain size. Recommendations and future work will also be briefly discussed.

  11. Conditions necessary for capillary hysteresis in porous media: Tests of grain size and surface tension influences

    Science.gov (United States)

    Tokunaga, Tetsu K.; Olson, Keith R.; Wan, Jiamin

    2004-05-01

    Hysteresis in the relation between water saturation and matric potential is generally regarded as a basic aspect of unsaturated porous media. However, the nature of an upper length scale limit for saturation hysteresis has not been previously addressed. Since hysteresis depends on whether or not capillary rise occurs at the grain scale, this criterion was used to predict required combinations of grain size, surface tension, fluid-fluid density differences, and acceleration in monodisperse systems. The Haines number (Ha), composed of the aforementioned variables, is proposed as a dimensionless number useful for separating hysteretic (Ha 15) behavior. Vanishing of hysteresis was predicted to occur for grain sizes greater than 10.4 ± 0.5 mm, for water-air systems under the acceleration of ordinary gravity, based on Miller-Miller scaling and Haines' original model for hysteresis. Disappearance of hysteresis was tested through measurements of drainage and wetting curves of sands and gravels and occurs between grain sizes of 10 and 14 mm (standard conditions). The influence of surface tension was tested through measurements of moisture retention in 7 mm gravel, without and with a surfactant (sodium dodecylbenzenesulfonate (SDBS)). The ordinary water system (Ha = 7) exhibited hysteresis, while the SDBS system (Ha = 18) did not. The experiments completed in this study indicate that hysteresis in moisture retention relations has an upper limit at Ha = 16 ± 2 and show that hysteresis is not a fundamental feature of unsaturated porous media.

  12. Grain size effects on stability of nonlinear vibration with nanocrystalline NiTi shape memory alloy

    Science.gov (United States)

    Xia, Minglu; Sun, Qingping

    2017-10-01

    Grain size effects on stability of thermomechanical responses for a nonlinear torsional vibration system with nanocrystalline superelastic NiTi bar are investigated in the frequency and amplitude domains. NiTi bars with average grain size from 10 nm to 100 nm are fabricated through cold-rolling and subsequent annealing. Thermomechanical responses of the NiTi bar as a softening nonlinear damping spring in the torsional vibration system are obtained by synchronised acquisition of rotational angle and temperature under external sinusoidal excitation. It is shown that nonlinearity and damping capacity of the NiTi bar decrease as average grain size of the material is reduced below 100 nm. Therefore jump phenomena of thermomechanical responses become less significant or even vanish and the vibration system becomes more stable. The work in this paper provides a solid experimental base for manipulating the undesired jump phenomena of thermomechanical responses and stabilising the mechanical vibration system through grain refinement of NiTi SMA.

  13. An assessment of calcite crystal growth mechanisms based on crystal size distributions

    Science.gov (United States)

    Kile, D.E.; Eberl, D.D.; Hoch, A.R.; Reddy, M.M.

    2000-01-01

    Calcite crystal growth experiments were undertaken to test a recently proposed model that relates crystal growth mechanisms to the shapes of crystal size distributions (CSDs). According to this approach, CSDs for minerals have three basic shapes: (1) asymptotic, which is related to a crystal growth mechanism having constant-rate nucleation accompanied by surface-controlled growth; (2) lognormal, which results from decaying-rate nucleation accompanied by surface-controlled growth; and (3) a theoretical, universal, steady-state curve attributed to Ostwald ripening. In addition, there is a fourth crystal growth mechanism that does not have a specific CSD shape, but which preserves the relative shapes of previously formed CSDs. This mechanism is attributed to supply-controlled growth. All three shapes were produced experimentally in the calcite growth experiments by modifying nucleation conditions and solution concentrations. The asymptotic CSD formed when additional reactants were added stepwise to the surface of solutions that were supersaturated with respect to calcite (initial Ω = 20, where Ω = 1 represents saturation), thereby leading to the continuous nucleation and growth of calcite crystals. Lognormal CSDs resulted when reactants were added continuously below the solution surface, via a submerged tube, to similarly supersaturated solutions (initial Ω = 22 to 41), thereby leading to a single nucleation event followed by surface-controlled growth. The Ostwald CSD resulted when concentrated reactants were rapidly mixed, leading initially to high levels of supersaturation (Ω >100), and to the formation and subsequent dissolution of very small nuclei, thereby yielding CSDs having small crystal size variances. The three CSD shapes likely were produced early in the crystallization process, in the nanometer crystal size range, and preserved during subsequent growth. Preservation of the relative shapes of the CSDs indicates that a supply-controlled growth mechanism

  14. Porous media grain size distribution and hydrodynamic forces effects on transport and deposition of suspended particles.

    Science.gov (United States)

    Ahfir, Nasre-Dine; Hammadi, Ahmed; Alem, Abdellah; Wang, HuaQing; Le Bras, Gilbert; Ouahbi, Tariq

    2017-03-01

    The effects of porous media grain size distribution on the transport and deposition of polydisperse suspended particles under different flow velocities were investigated. Selected Kaolinite particles (2-30μm) and Fluorescein (dissolved tracer) were injected in the porous media by step input injection technique. Three sands filled columns were used: Fine sand, Coarse sand, and a third sand (Mixture) obtained by mixing the two last sands in equal weight proportion. The porous media performance on the particle removal was evaluated by analysing particles breakthrough curves, hydro-dispersive parameters determined using the analytical solution of convection-dispersion equation with a first order deposition kinetics, particles deposition profiles, and particle-size distribution of the recovered and the deposited particles. The deposition kinetics and the longitudinal hydrodynamic dispersion coefficients are controlled by the porous media grain size distribution. Mixture sand is more dispersive than Fine and Coarse sands. More the uniformity coefficient of the porous medium is large, higher is the filtration efficiency. At low velocities, porous media capture all sizes of suspended particles injected with larger ones mainly captured at the entrance. A high flow velocity carries the particles deeper into the porous media, producing more gradual changes in the deposition profile. The median diameter of the deposited particles at different depth increases with flow velocity. The large grain size distribution leads to build narrow pores enhancing the deposition of the particles by straining. Copyright © 2016. Published by Elsevier B.V.

  15. Grain size fraction of heavy metals in soil and their relationship with land use

    Directory of Open Access Journals (Sweden)

    M. H. Sayadi

    2017-03-01

    Full Text Available The aim of the present study was to investigate the distribution of heavy metals (Pb, Ni, Cr and Cd in different grain-size fractions of the surface soils. The soil samples of different land uses were taken from 20 cm depth at 12 stations where is located at Amir Abad of Birjand city, Iran. The air-dried samples were passed through sieves of different sizes to collect the fractions lesser than 63 μm, 63-125 μm, 125-250 μm, 250-500 μm, 500-1000 μm and 1000-2000 μm. The samples were digested by perchloric acid and nitric acid; and the concentrations of heavy metals were determined using Atomic Absorption Spectrophotometer (model AAcontr700. The highest concentrations for Pb, Cr, Ni and Cd (139.5, 195.4, 98.4 and 3.15 mg/kg respectively were obtained in the fractions less than 63 μm from the road-side soils. The contamination factor values for the fractions less than 63 μm were higher than other fractions. The comparison of different toxic metals concentration from various grain-size fractions demonstrated higher Cr levels, especially in the 63-125 μm size fractions from the road-side lands. Thus, the comparison of grain size factors from different soils revealed that Cr exhibited highest values in relation to the other toxic elements studied.

  16. Effect of grain size reduction on high temperature oxidation ofbinary two-phase alloys

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The effect of grain size reduction on the high temperature oxidation of binary two-phase alloys was discussed based on the recent research progress. The results show that for those two-phase alloys with coarse grain prepared by the conventional methods, complex oxide scales are easily formed after oxidation under high oxygen pressure or under oxygen pressure below the stability limit of the less reactive component oxides. On the contrary, for the nano-sized alloys, an exclusive external oxidation of the most reactive component usually occurs during oxidation in air or pure oxygen even for much lower content of the most reactive component. So the gain size reduction is not always beneficial to improve the oxidation resistance of the materials, but exhibits different effects depending mainly on the protective feature of the scales. The transition mechanisms between the different oxidation modes are discussed with respect to the thermodynamic and dynamic aspects.

  17. Synthesis of few layer single crystal graphene grains on platinum by chemical vapour deposition

    Institute of Scientific and Technical Information of China (English)

    S. Karamat; S. Sonuşen; Ü. Çelik; Y. Uysallı; E. Özgönül; A. Oral

    2015-01-01

    The present competition of graphene electronics demands an efficient route which produces high quality and large area graphene. Chemical vapour deposition technique, where hydrocarbons dissociate in to active carbon species and form graphene layer on the desired metal catalyst via nucleation is considered as the most suitable method. In this study, single layer graphene with the presence of few layer single crystal graphene grains were grown on Pt foil via chemical vapour deposition. The higher growth temperature changes the surface morphology of the Pt foil so a delicate process of hydrogen bubbling was used to peel off graphene from Pt foil samples with the mechanical support of photoresist and further transferred to SiO2/Si substrates for analysis. Optical microscopy of the graphene transferred samples showed the regions of single layer along with different oriented graphene domains. Two type of interlayer stacking sequences, Bernal and twisted, were observed in the graphene grains. The presence of different stacking sequences in the graphene layers influence the electronic and optical properties;in Bernal stacking the band gap can be tunable and in twisted stacking the overall sheet resistance can be reduced. Grain boundaries of Pt provides low energy sites to the carbon species, therefore the nucleation of grains are more at the boundaries. The stacking order and the number of layers in grains were seen more clearly with scanning electron microscopy. Raman spectroscopy showed high quality graphene samples due to very small D peak. 2D Raman peak for single layer graphene showed full width half maximum (FWHM) value of 30 cm ? 1. At points A, B and C, Bernal stacked grain showed FWHM values of 51.22, 58.45 and 64.72 cm ? 1, while twisted stacked grain showed the FWHM values of 27.26, 28.83 and 20.99 cm ? 1, respectively. FWHM values of 2D peak of Bernal stacked grain showed an increase of 20–30 cm ? 1 as compare to single layer graphene which showed its

  18. Synthesis of few layer single crystal graphene grains on platinum by chemical vapour deposition

    Directory of Open Access Journals (Sweden)

    S. Karamat

    2015-08-01

    Full Text Available The present competition of graphene electronics demands an efficient route which produces high quality and large area graphene. Chemical vapour deposition technique, where hydrocarbons dissociate in to active carbon species and form graphene layer on the desired metal catalyst via nucleation is considered as the most suitable method. In this study, single layer graphene with the presence of few layer single crystal graphene grains were grown on Pt foil via chemical vapour deposition. The higher growth temperature changes the surface morphology of the Pt foil so a delicate process of hydrogen bubbling was used to peel off graphene from Pt foil samples with the mechanical support of photoresist and further transferred to SiO2/Si substrates for analysis. Optical microscopy of the graphene transferred samples showed the regions of single layer along with different oriented graphene domains. Two type of interlayer stacking sequences, Bernal and twisted, were observed in the graphene grains. The presence of different stacking sequences in the graphene layers influence the electronic and optical properties; in Bernal stacking the band gap can be tunable and in twisted stacking the overall sheet resistance can be reduced. Grain boundaries of Pt provides low energy sites to the carbon species, therefore the nucleation of grains are more at the boundaries. The stacking order and the number of layers in grains were seen more clearly with scanning electron microscopy. Raman spectroscopy showed high quality graphene samples due to very small D peak. 2D Raman peak for single layer graphene showed full width half maximum (FWHM value of 30 cm−1. At points A, B and C, Bernal stacked grain showed FWHM values of 51.22, 58.45 and 64.72 cm−1, while twisted stacked grain showed the FWHM values of 27.26, 28.83 and 20.99 cm−1, respectively. FWHM values of 2D peak of Bernal stacked grain showed an increase of 20–30 cm−1 as compare to single layer graphene

  19. Relationship among grain size, annealing twins and shape memory effect in Fe-Mn-Si based shape memory alloys

    Science.gov (United States)

    Wang, Gaixia; Peng, Huabei; Zhang, Chengyan; Wang, Shanling; Wen, Yuhua

    2016-07-01

    In order to clarify the relationship among grain size, annealing twins and the shape memory effect in Fe-Mn-Si based shape memory alloys, the Fe-21.63Mn-5.60Si-9.32Cr-5.38Ni (weight %) alloy with a grain size ranging from 48.9 μm-253.6 μm was obtained by adjusting the heating temperature or heating time after 20% cold-rolling. The densities of grain boundaries and annealing twins increase with a decrease in grain size, whereas the volume fraction and width of stress-induced ɛ martensite after 9% deformation at Ms + 10 K decrease. This result indicates that grain refinement raises the constraint effects of grain boundaries and annealing twins upon martensitic transformation. In this case, the ability to suppress the plastic deformation and facilitate the stress-induced ɛ martensite transformation deteriorates after grain refinement owing to the enhancement of the constraint effects. It is demonstrated by the result that the difference at Ms + 10 K between the critical stress for plastic yielding and that for inducing martensitic transformation is smaller for the specimen with a grain size of 48.9 μm than for the specimen with a grain size of 253.6 μm. Therefore, the shape memory effect declined by decreasing the grain size.

  20. Effect of alloy grain size on the high-temperature oxidation behavior of the austenitic steel TP 347

    Directory of Open Access Journals (Sweden)

    Vicente Braz Trindade

    2005-12-01

    Full Text Available Generally, oxide scales formed on high Cr steels are multi-layered and the kinetics are strongly influenced by the alloy grain boundaries. In the present study, the oxidation behaviour of an austenite steel TP347 with different grain sizes was studied to identify the role of grain-boundaries in the oxidation process. Heat treatment in an inert gas atmosphere at 1050 °C was applied to modify the grain size of the steel TP347. The mass gain during subsequent oxidation was measured using a microbalance with a resolution of 10-5 g. The scale morphology was examined using SEM in combination with energy-dispersive X-ray spectroscopy (EDS. Oxidation of TP347 with a grain size of 4 µm at 750 °C in air follows a parabolic rate law. For a larger grain size (65 µm, complex kinetics is observed with a fast initial oxidation followed by several different parabolic oxidation stages. SEM examinations indicated that the scale formed on specimens with smaller grain size was predominantly Cr2O3, with some FeCr2O4 at localized sites. For specimens with larger grain size the main oxide is iron oxide. It can be concluded that protective Cr2O3 formation is promoted by a high density of fast grain-boundary diffusion paths which is the case for fine-grained materials.

  1. On the origin of size-dependent and size-independent crystal growth: Influence of advection and diffusion

    Science.gov (United States)

    Kile, D.E.; Eberl, D.D.

    2003-01-01

    Crystal growth experiments were conducted using potassium alum and calcite crystals in aqueous solution under both non-stirred and stirred conditions to elucidate the mechanism for size-dependent (proportionate) and size-independent (constant) crystal growth. Growth by these two laws can be distinguished from each other because the relative size difference among crystals is maintained during proportionate growth, leading to a constant crystal size variance (??2) for a crystal size distribution (CSD) as the mean size increases. The absolute size difference among crystals is maintained during constant growth, resulting in a decrease in size variance. Results of these experiments show that for centimeter-sized alum crystals, proportionate growth occurs in stirred systems, whereas constant growth occurs in non-stirred systems. Accordingly, the mechanism for proportionate growth is hypothesized to be related to the supply of reactants to the crystal surface by advection, whereas constant growth is related to supply by diffusion. Paradoxically, micrometer-sized calcite crystals showed proportionate growth both in stirred and in non-stirred systems. Such growth presumably results from the effects of convection and Brownian motion, which promote an advective environment and hence proportionate growth for minute crystals in non-stirred systems, thereby indicating the importance of solution velocity relative to crystal size. Calcite crystals grown in gels, where fluid motion was minimized, showed evidence for constant, diffusion-controlled growth. Additional investigations of CSDs of naturally occurring crystals indicate that proportionate growth is by far the most common growth law, thereby suggesting that advection, rather than diffusion, is the dominant process for supplying reactants to crystal surfaces.

  2. Effects of Moisture and Grain Sizes on Rainsplash Transport with Implications for Desert Plant-Soil Interactions

    Science.gov (United States)

    Taube, S. R.; Furbish, D. J.; Roberts, A. S.

    2009-12-01

    Soil mounds beneath desert shrubs can develop from sediment transport associated with rainsplash of soil grains around the plants. As the canopy of a plant protects the underlying soil from the raindrop impacts, sediment accumulates beneath the shrub canopy due to differential rainsplash of grains. Previous work has clarified how rainsplash transport varies with raindrop momentum and with different sizes of dry sediment, focusing on the transfer of momentum of the drops to grains during drop impacts. Details of this transfer of momentum and grain mobilization for moist sediment conditions are not well known, which is important for understanding sediment transport by rainsplash during the progression of storms. Moreover, related work suggests that relatively immobile coarse soil grains are less likely to be splashed beneath shrub canopies than are small grains, so that smaller grains are more likely to accumulate within shrub mounds. However, systematic measurements of sediment grain sizes around and beneath desert shrubs in the Cibola National Forest, New Mexico, suggest that, aside from the coarsest lag material, larger grain sizes (0.5 - 1.5 mm) are preferentially concentrated within the mound surfaces close to the shrubs. This pattern of grain-size sorting is likely associated with effects of moisture, wherein small grains tend to be ejected during drop impacts as grain clumps rather than individually due to surface tension, and thereby behave as relative coarse grains with shorter splash distances. High-speed imaging of drop impacts on sediment reveals this clumping behavior. These results may be useful in determining the dispersal of nutrients and contaminants that preferentially adhere to the smaller grain sizes. This information also extends our understanding of rainsplash transport beyond dry conditions, that is, to storm conditions where soil moisture and grain detachment rates are changing.

  3. Systematic Procedure for Generating Operational Policies to Achieve Target Crystal Size Distribution (CSD) in Batch Cooling Crystallization

    DEFF Research Database (Denmark)

    Abdul Samad, Noor Asma Fazli; Singh, Ravendra; Sin, Gürkan

    Batch cooling crystallization is one of the important unit operations involving separation of solid-liquid phases. Usually the most common crystal product qualities are directly related to the crystal size distribution (CSD). However the main difficulty in batch crystallization is to obtain a uni...

  4. Grain size distributions of chalk from image analysis of electron micrographs

    DEFF Research Database (Denmark)

    Røgen, Birte; Gommesen, Lars; Fabricius, Ida Lykke

    2001-01-01

    In the chalk of the Ekofisk formation in the Chalk Group of the North Sea, substantial depth-related variations in porosityare observed. With the aim of obtaining a textural interpretation of these porositydata, we have developed a method to assess the grain size distribution of the chalk from...... image analysis. The chalk is composed of a fine-grained matrix of nannofossils and predominantlycalcitic fossil debris with larger microfossil grains, but the chalk may also contain significant amounts of silica and siliciclastic clay. For image analysis, we used backscatter electron images of epoxy......-impregnated, polished samples from the Ekofisk Formation, Tyra field, Danish North Sea. On backscatter images the calcite phase will appear light as opposed to the dark pore space. The procedure involves the combination of data acquired at two magnifications and bythis method analysis of only four images per sample...

  5. Linking differential domain functions of the GS3 protein to natural variation of grain size in rice.

    Science.gov (United States)

    Mao, Hailiang; Sun, Shengyuan; Yao, Jialing; Wang, Chongrong; Yu, Sibin; Xu, Caiguo; Li, Xianghua; Zhang, Qifa

    2010-11-09

    Grain yield in many cereal crops is largely determined by grain size. Here we report the genetic and molecular characterization of GS3, a major quantitative trait locus for grain size. It functions as a negative regulator of grain size and organ size. The wild-type isoform is composed of four putative domains: a plant-specific organ size regulation (OSR) domain in the N terminus, a transmembrane domain, a tumor necrosis factor receptor/nerve growth factor receptor (TNFR/NGFR) family cysteine-rich domain, and a von Willebrand factor type C (VWFC) in the C terminus. These domains function differentially in grain size regulation. The OSR domain is both necessary and sufficient for functioning as a negative regulator. The wild-type allele corresponds to medium grain. Loss of function of OSR results in long grain. The C-terminal TNFR/NGFR and VWFC domains show an inhibitory effect on the OSR function; loss-of-function mutations of these domains produced very short grain. This study linked the functional domains of the GS3 protein to natural variation of grain size in rice.

  6. Defect formation energy in pyrochlore: the effect of crystal size

    Science.gov (United States)

    Wang, Jianwei; Ewing, Rodney C.; Becker, Udo

    2014-09-01

    Defect formation energies of point defects of two pyrochlores Gd2Ti2O7 and Gd2Zr2O7 as a function of crystal size were calculated. Density functional theory with plane-wave basis sets and the projector-augmented wave method were used in the calculations. The results show that the defect formation energies of the two pyrochlores diverge as the size decreases to the nanometer range. For Gd2Ti2O7 pyrochlore, the defect formation energy is higher at nanometers with respect to that of the bulk, while it is lower for Gd2Zr2O7. The lowest defect formation energy for Gd2Zr2O7 is found at 15-20 Å. The different behaviors of the defect formation energies as a function of crystal size are caused by different structural adjustments around the defects as the size decreases. For both pyrochlore compositions at large sizes, the defect structures are similar to those of the bulk. As the size decreases, for Gd2Ti2O7, additional structure distortions appear at the surfaces, which cause the defect formation energy to increase. For Gd2Zr2O7, additional oxygen Frenkel pair defects are introduced, which reduce the defect formation energy. As the size further decreases, increased structure distortions occur at the surfaces, which cause the defect formation energy to increase. Based on a hypothesis that correlates the energetics of defect formation and radiation response for complex oxides, the calculated results suggest that at nanometer range Gd2Ti2O7 pyrochlore is expected to have a lower radiation tolerance, and those of Gd2Zr2O7 pyrochlore to have a higher radiation tolerance. The highest radiation tolerance for Gd2Zr2O7 pyrochlore is expected to be found at ˜2 nanometers.

  7. Grain Size Distribution in Mudstones: A Question of Nature vs. Nurture

    Science.gov (United States)

    Schieber, J.

    2011-12-01

    Grain size distribution in mudstones is affected by the composition of the source material, the processes of transport and deposition, and post-depositional diagenetic modification. With regard to source, it does make a difference whether for example a slate belt is eroded vs a stable craton. The former setting tends to provide a broad range of detrital quartz in the sub 62 micron size range in addition to clays and greenschist grade rock fragments, whereas the latter may be biased towards coarser quartz silt (30-60 microns), in addition to clays and mica flakes. In flume experiments, when fine grained materials are transported in turbulent flows at velocities that allow floccules to transfer to bedload, a systematic shift of grain size distribution towards an increasingly finer grained suspended load is observed as velocity is lowered. This implies that the bedload floccules are initially constructed of only the coarsest clay particles at high velocities, and that finer clay particles become incorporated into floccules as velocity is lowered. Implications for the rock record are that clay beds deposited from decelerating flows should show subtle internal grading of coarser clay particles; and that clay beds deposited from continuous fast flows should show a uniform distribution of coarse clays. Still water settled clays should show a well developed lower (coarser) and upper (finer) subdivision. A final complication arises when diagenetic processes, such as the dissolution of biogenic silica, give rise to diagenetic quartz grains in the silt to sand size range. This diagenetic silica precipitates in fossil cavities and pore spaces of uncompacted muds, and on casual inspection can be mistaken for detrital quartz. In distal mudstone successions close to 100 % of "apparent" quartz silt can be of that origin, and reworking by bottom currents can further enhance a detrital perception by producing rippled and laminated silt beds. Although understanding how size

  8. Grain-size evidence for multiple origins of the reticulate red clay in southern China

    Institute of Scientific and Technical Information of China (English)

    HU Xuefeng; ZHU Yu; SHEN Mingneng

    2005-01-01

    Grain-size distributions of the reticulate red clay in Xuancheng, Anhui Province, and Jiujiang, Taihe and Ganzhou, Jiangxi Province, are analyzed. The results are as follows: (1) Generally fine and uniform, grain-size characteristics of the reticulate red clay in Xuancheng and Jiujiang are much similar, with no >2 mm gravels, 0.30% and 1.14% of >63 μm fraction on average, respectively, and 34.65% and 37.20% of 10―50 μm fraction, which is apparently accumulated. The patterns of the grain-size distribution curves of the uppermost yellow-brown earth of the profiles in the two areas much resemble those of the loess in northern China and the Xiashu loess in southeastern China, while the patterns of the other layers also apparently show some attributes inherited from the above. The grain-size distribution patterns of the quartz separated from the whole profiles in the areas are almost identical, which could also be compared with those of the loess and the Xiashu loess. All the features above reveal aeolian characteristics of the reticulated red clay in these two areas. (2) The reticulate red clay in Taihe and Ganzhou is much coarser than that in Xuancheng and Jiujiang, with high content of >63 μm fraction and relatively low content of 10―50 μm fraction. The variations in grain-size distributions of the profiles are also observed. The grain-size distribution patterns of both the original samples and the quartz of the red clay could hardly be compared with those of the loess and the Xiashu loess. All the features above reveal their alluvial or diluvial origins. (3) The multiple origins of the reticulate red clay in the areas reflect the diversity and complexity of the Quaternary environment in southern China. The existence of the reticulate red clay with aeolian characteristics brings forth objective evidence for the occurrence of large-scale dust deposition in southern China during the Quaternary glacial periods. Further investigation and study on the regional

  9. MinSORTING: an Excel macro for modelling sediment composition and grain-size distribution

    Science.gov (United States)

    Resentini, Alberto; Malusà, Marco G.; Garzanti, Eduardo

    2013-04-01

    Detrital mineral analyses are gaining increasing attention in the geosciences as new single-grain analytical techniques are constantly improving their resolution, and consequently widening their range of application, including sedimentary petrology, tectonic geomorphology and archaeology (Mange and Wright, 2007; von Eynatten and Dunkl, 2012). We present here MinSORTING, a new tool to quickly predict the size distribution of various minerals and rock fragments in detrital sediments, based on the physical laws that control sedimentation by tractive wind or water currents (Garzanti et al., 2008). The input values requested by the software are the sediment mean size, sorting, fluid type (seawater, freshwater, air) and standard sediment composition chosen from a given array including nine diverse tectonic settings. MinSORTING calculates the bulk sediment density and the settling velocity. The mean size of each single detrital component, assumed as lognormally-distributed, is calculated from its characteristic size-shift with respect to bulk sediment mean size, dependent in turn on its density and shape. The final output of MinSORTING is the distribution of each single detrital mineral in each size classes (at the chosen 0.25, 0.5 or 1 phi intervals). This allows geochronolgists to select the most suitable grain size of sediment to be sampled in the field, as well as the most representative size-window for analysis. Also, MinSORTING provides an estimate of the volume/weight of the fractions not considered in both sizes finer and coarser than the selected size-window. A beta version of the software is available upon request from: alberto.resentini@unimib.it Mange, M., and Wright, D. (eds), 2007. Heavy minerals in use. Developments in Sedimentology Series, 58. Elsevier, Amsterdam. Garzanti, E., Andò, S., Vezzoli, G., 2008. Settling-equivalence of detrital minerals and grain-size dependence of sediment composition. Earth and Planetary Science Letters 273, 138-151. von

  10. Variations in CYP78A13 coding region influence grain size and yield in rice.

    Science.gov (United States)

    Xu, Fan; Fang, Jun; Ou, Shujun; Gao, Shaopei; Zhang, Fengxia; Du, Lin; Xiao, Yunhua; Wang, Hongru; Sun, Xiaohong; Chu, Jinfang; Wang, Guodong; Chu, Chengcai

    2015-04-01

    Grain size is one of the most important determinants of crop yield in cereals. Here, we identified a dominant mutant, big grain2 (bg2-D) from our enhancer-trapping population. Genetic analysis and SiteFinding PCR (polymerase chain reaction) revealed that BG2 encodes a cytochrome P450, OsCYP78A13. Sequence search revealed that CYP78A13 has a paralogue Grain Length 3.2 (GL3.2, LOC_Os03g30420) in rice with distinct expression patterns, analysis of transgenic plants harbouring either CYP78A13 or GL3.2 showed that both can promote grain growth. Sequence polymorphism analysis with 1529 rice varieties showed that the nucleotide diversity at CYP78A13 gene body and the 20 kb flanking region in the indica varieties were markedly higher than those in japonica varieties. Further, comparison of the genomic sequence of CYP78A13 in the japonica cultivar Nipponbare and the indica cultivar 9311 showed that there were three InDels in the promoter region and eight SNPs (single nucleotide polymorphism) in its coding sequence. Detailed examination of the transgenic plants with chimaeric constructs suggested that variation in CYP78A13 coding region is responsible for the variation of grain yield. Taken together, our results suggest that the variations in CYP78A13 in the indica varieties hold potential in rice breeding for application of grain yield improvement.

  11. Influence of charging process and size distribution of dust grain on the electric conductivity of dusty plasma

    Energy Technology Data Exchange (ETDEWEB)

    Duan Jizheng; Wang Canglong; Zhang Jianrong; Ma Shengqian; Hong Xueren; Sun Jianan [College of Physics and Electronic Engineering and Joint Laboratory of Atomic and Molecular Physics of NWNU and IMP CAS, Northwest Normal University, Lanzhou 730070 (China) and Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); Duan Wenshan [College of Physics and Electronic Engineering and Joint Laboratory of Atomic and Molecular Physics of NWNU and IMP CAS, Northwest Normal University, Lanzhou 730070 (China) and Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); Key Laboratory of Atomic and Molecular Physics and Functional Materials of Gansu Province, College of Physics and Electronic Engineering, Northwest Normal University, Lanzhou 730070 (China); Yang Lei [College of Physics and Electronic Engineering and Joint Laboratory of Atomic and Molecular Physics of NWNU and IMP CAS, Northwest Normal University, Lanzhou 730070 (China) and Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); Department of Physics, Lanzhou University, Lanzhou 730000 (China)

    2012-08-15

    The effects of dust size distribution and charging process of dust grains on the complex electric conductivity of dusty plasmas have been investigated in the present paper. Comparisons are made between real dusty plasma in which there are many different dust grain species and the mono-sized dusty plasma (MDP) in which there is only one kind of dust grain whose size is the average dust size. In some cases the complex electric conductivity of real dusty plasma is larger than that of MDP, while in other cases it is smaller than that of MDP, it depends on the dust size distribution function.

  12. Estimating the settling velocity of bioclastic sediment using common grain-size analysis techniques

    Science.gov (United States)

    Cuttler, Michael V. W.; Lowe, Ryan J.; Falter, James L.; Buscombe, Daniel D.

    2017-01-01

    Most techniques for estimating settling velocities of natural particles have been developed for siliciclastic sediments. Therefore, to understand how these techniques apply to bioclastic environments, measured settling velocities of bioclastic sedimentary deposits sampled from a nearshore fringing reef in Western Australia were compared with settling velocities calculated using results from several common grain-size analysis techniques (sieve, laser diffraction and image analysis) and established models. The effects of sediment density and shape were also examined using a range of density values and three different models of settling velocity. Sediment density was found to have a significant effect on calculated settling velocity, causing a range in normalized root-mean-square error of up to 28%, depending upon settling velocity model and grain-size method. Accounting for particle shape reduced errors in predicted settling velocity by 3% to 6% and removed any velocity-dependent bias, which is particularly important for the fastest settling fractions. When shape was accounted for and measured density was used, normalized root-mean-square errors were 4%, 10% and 18% for laser diffraction, sieve and image analysis, respectively. The results of this study show that established models of settling velocity that account for particle shape can be used to estimate settling velocity of irregularly shaped, sand-sized bioclastic sediments from sieve, laser diffraction, or image analysis-derived measures of grain size with a limited amount of error. Collectively, these findings will allow for grain-size data measured with different methods to be accurately converted to settling velocity for comparison. This will facilitate greater understanding of the hydraulic properties of bioclastic sediment which can help to increase our general knowledge of sediment dynamics in these environments.

  13. Physical conditions in three high-z H2-bearing DLAs: implications for grain size

    CERN Document Server

    Rawlins, Katherine; Srianand, Raghunathan

    2016-01-01

    We present results of our numerical simulation of three H2-bearing damped Lyman alpha absorbers (DLAs) in the redshift interval ~ 2-3. The systems we have modelled are the DLAs at zabs = 2.3377 towards the quasar LBQS 1232+0815, at zabs = 2.41837 towards SDSS J143912.04+111740.5 and at zabs = 2.6265 towards FBQS J081240.6+320808. We have used the spectral synthesis code CLOUDY to simulate the physical environment of these DLAs, and constrain the density, radiation field, geometry and dust-grain properties of the DLAs self-consistently based on the observed column densities of various atomic and molecular species such as H I, fine structure lines of C I and the rotational level population of H2. In our models, we explore the effect of grain size distribution on the predicted column densities of different species. Within the allowed uncertainties in the inferred dust-to-gas ratio, both models with standard ISM grains and smaller-sized grains reproduce the observations equally well. Improved constraints on dust-...

  14. Determination of grain-size distribution function using two-dimensional Fourier transforms of tone-pulse-encoded images

    Science.gov (United States)

    Generazio, E. R.

    1988-01-01

    Microstructural images may be tone pulse encoded and subsequently Fourier transformed to determine the two-dimensional density of frequency components. A theory is developed relating the density of frequency components to the density of length components. The density of length components corresponds directly to the actual grain-size distribution function from which the mean grain shape, size, and orientation can be obtained.

  15. Determination of grain size distribution function using two-dimensional Fourier transforms of tone pulse encoded images

    Science.gov (United States)

    Generazio, E. R.

    1986-01-01

    Microstructural images may be tone pulse encoded and subsequently Fourier transformed to determine the two-dimensional density of frequency components. A theory is developed relating the density of frequency components to the density of length components. The density of length components corresponds directly to the actual grain size distribution function from which the mean grain shape, size, and orientation can be obtained.

  16. Grain-size distribution patterns of suspended sediment in response to hydrodynamics on the Dafeng intertidal flat, Jiangsu, China

    Institute of Scientific and Technical Information of China (English)

    LI Zhanhai; GAO Shu; CHEN Shenliang; WANG Yaping

    2006-01-01

    Patterns of grain-size distributions of suspended sediment in relation to resuspension, settling, and tidal processes are investigated, based on in situ measurements over the Dafeng intertidal flat, on the Jiangsu coast, in the summer of 2002 and 2003. The suspended sediment here is dominated by fine and very fine silt, with a mean grain-size of 7~13 μm. The patterns of the grain-size distributions of suspended sediment during a tidal cycle are characterized by two types: one stable type representing insignificant spatial and temporal variations; and the other bimodal type with significant variations. The main factors influencing the grain-size distributions include resuspension, settling, suspended sediment imported into intertidal flats during the flood phase, and the grain-size distribution of seabed sediment. Resuspension increases the coarse particle content, enhances the mean grain-size of suspended sediment, and results in grain-size distributions for the suspended sediment similar to those of seabed sediment; the settling process has opposite effects on the suspended sediment. When resuspension occurs, the gain-size distributions of suspended sediment in the lower part of water column respond significantly to the current velocity. Where the influence of resuspension and settling processes is weak, the grain-size distributions of suspended sediment appear to be stable and almost identical for the various parts of intertidal flats during different measurement periods. Such distributions are referred to the background grain-size distribution, for which the mean grain-size over the Dafeng intertidal flat is around 7 μm.

  17. Reading acquisition, developmental dyslexia, and skilled reading across languages: a psycholinguistic grain size theory.

    Science.gov (United States)

    Ziegler, Johannes C; Goswami, Usha

    2005-01-01

    The development of reading depends on phonological awareness across all languages so far studied. Languages vary in the consistency with which phonology is represented in orthography. This results in developmental differences in the grain size of lexical representations and accompanying differences in developmental reading strategies and the manifestation of dyslexia across orthographies. Differences in lexical representations and reading across languages leave developmental "footprints" in the adult lexicon. The lexical organization and processing strategies that are characteristic of skilled reading in different orthographies are affected by different developmental constraints in different writing systems. The authors develop a novel theoretical framework to explain these cross-language data, which they label a psycholinguistic grain size theory of reading and its development.

  18. Grain-size cycles in Salawusu River valley since 150 ka BP

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The palaeo-mobile dune sands and fluvio-lacustrine facies with palaeosols in Milanggouwan stratigraphic section of the Salawusu River valley situated at the southeast of the Mu Us Desert experienced abundant remarkable alternative changes of coarse and fine rhythms in grainsize since 150 ka BP, and the grain-size parameters - Mz, σ, Sk, Kg and SC/I also respond to the situation of multi-fluctuational alternations between peak and valley values. Simultaneity the grainsize eigenvalues - Ф5, Ф16, P25, Ф50, Ф75, Ф84 and Ф95 are respondingly manifested as greatly cadent jumpiness. Hereby, the Milanggouwan section can be divided into 27 grain-size coarse and fine sedimentary cycles, which can be regarded as a real and integreted record of climate-geological process of desert vicissitude resulted from the alternative evolvement of the ancient winter and summer monsoons of East Asia since 150 ka BP.

  19. Influence of the Matrix Grain Size on the Apparent Density and Bending Strength of Sand Cores

    Directory of Open Access Journals (Sweden)

    Dańko R.

    2017-03-01

    Full Text Available The results of investigations of the influence of the matrix grain sizes on properties of cores made by the blowing method are presented in the hereby paper. Five kinds of matrices, differing in grain size compositions, determined by the laser diffraction method in the Analysette 22NanoTec device, were applied in investigations. Individual kinds of matrices were used for making core sands in the Cordis technology. From these sands the shaped elements, for determining the apparent density of compacted sands and their bending strength, were made by the blowing method. The shaped elements (cores were made at shooting pressures being 3, 4 and 5 atn. The bending strength of samples were determined directly after their preparation and after the storing time of 1 hour.

  20. Grain size analysis and depositional environment of shallow marine to basin floor, Kelantan River Delta

    Science.gov (United States)

    Afifah, M. R. Nurul; Aziz, A. Che; Roslan, M. Kamal

    2015-09-01

    Sediment samples were collected from the shallow marine from Kuala Besar, Kelantan outwards to the basin floor of South China Sea which consisted of quaternary bottom sediments. Sixty five samples were analysed for their grain size distribution and statistical relationships. Basic statistical analysis like mean, standard deviation, skewness and kurtosis were calculated and used to differentiate the depositional environment of the sediments and to derive the uniformity of depositional environment either from the beach or river environment. The sediments of all areas were varied in their sorting ranging from very well sorted to poorly sorted, strongly negative skewed to strongly positive skewed, and extremely leptokurtic to very platykurtic in nature. Bivariate plots between the grain-size parameters were then interpreted and the Coarsest-Median (CM) pattern showed the trend suggesting relationships between sediments influenced by three ongoing hydrodynamic factors namely turbidity current, littoral drift and waves dynamic, which functioned to control the sediments distribution pattern in various ways.

  1. Disk Radii and Grain Sizes in Herschel-resolved Debris Disks

    Science.gov (United States)

    Pawellek, Nicole; Krivov, Alexander V.; Marshall, Jonathan P.; Montesinos, Benjamin; Ábrahám, Péter; Moór, Attila; Bryden, Geoffrey; Eiroa, Carlos

    2014-09-01

    The radii of debris disks and the sizes of their dust grains are important tracers of the planetesimal formation mechanisms and physical processes operating in these systems. Here we use a representative sample of 34 debris disks resolved in various Herschel Space Observatory (Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA) programs to constrain the disk radii and the size distribution of their dust. While we modeled disks with both warm and cold components, and identified warm inner disks around about two-thirds of the stars, we focus our analysis only on the cold outer disks, i.e., Kuiper-belt analogs. We derive the disk radii from the resolved images and find a large dispersion for host stars of any spectral class, but no significant trend with the stellar luminosity. This argues against ice lines as a dominant player in setting the debris disk sizes, since the ice line location varies with the luminosity of the central star. Fixing the disk radii to those inferred from the resolved images, we model the spectral energy distribution to determine the dust temperature and the grain size distribution for each target. While the dust temperature systematically increases toward earlier spectral types, the ratio of the dust temperature to the blackbody temperature at the disk radius decreases with the stellar luminosity. This is explained by a clear trend of typical sizes increasing toward more luminous stars. The typical grain sizes are compared to the radiation pressure blowout limit s blow that is proportional to the stellar luminosity-to-mass ratio and thus also increases toward earlier spectral classes. The grain sizes in the disks of G- to A-stars are inferred to be several times s blow at all stellar luminosities, in agreement with collisional models of debris disks. The sizes, measured in the units of s blow, appear to decrease with the luminosity

  2. Disk radii and grain sizes in Herschel-resolved debris disks

    Energy Technology Data Exchange (ETDEWEB)

    Pawellek, Nicole; Krivov, Alexander V. [Astrophysikalisches Institut und Universitätssternwarte, Friedrich-Schiller-Universität Jena, Schillergäßchen 2-3, 07745 Jena (Germany); Marshall, Jonathan P. [School of Physics, University of New South Wales, Sydney NSW 2052 (Australia); Montesinos, Benjamin [Departmento de Astrofísica, Centro de Astrobiología (CAB, CSIC-INTA), ESAC Campus, P.O. Box 78, E-28691 Villanueva de la Cañada, Madrid (Spain); Ábrahám, Péter; Moór, Attila [Konkoly Observatory, Research Centre for Astronomy and Earth Sciences, Hungarian Academy of Sciences, P.O. Box 67, H-1525 Budapest (Hungary); Bryden, Geoffrey [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109 (United States); Eiroa, Carlos [Departamento de Física Teórica, Facultad de Ciencias, Universidad Autónoma de Madrid, Cantoblanco, E-28049 Madrid (Spain)

    2014-09-01

    The radii of debris disks and the sizes of their dust grains are important tracers of the planetesimal formation mechanisms and physical processes operating in these systems. Here we use a representative sample of 34 debris disks resolved in various Herschel Space Observatory (Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA) programs to constrain the disk radii and the size distribution of their dust. While we modeled disks with both warm and cold components, and identified warm inner disks around about two-thirds of the stars, we focus our analysis only on the cold outer disks, i.e., Kuiper-belt analogs. We derive the disk radii from the resolved images and find a large dispersion for host stars of any spectral class, but no significant trend with the stellar luminosity. This argues against ice lines as a dominant player in setting the debris disk sizes, since the ice line location varies with the luminosity of the central star. Fixing the disk radii to those inferred from the resolved images, we model the spectral energy distribution to determine the dust temperature and the grain size distribution for each target. While the dust temperature systematically increases toward earlier spectral types, the ratio of the dust temperature to the blackbody temperature at the disk radius decreases with the stellar luminosity. This is explained by a clear trend of typical sizes increasing toward more luminous stars. The typical grain sizes are compared to the radiation pressure blowout limit s {sub blow} that is proportional to the stellar luminosity-to-mass ratio and thus also increases toward earlier spectral classes. The grain sizes in the disks of G- to A-stars are inferred to be several times s {sub blow} at all stellar luminosities, in agreement with collisional models of debris disks. The sizes, measured in the units of s {sub blow}, appear to decrease

  3. Identifying grain-size dependent errors on global forest area estimates and carbon studies

    Science.gov (United States)

    Daolan Zheng; Linda S. Heath; Mark J. Ducey

    2008-01-01

    Satellite-derived coarse-resolution data are typically used for conducting global analyses. But the forest areas estimated from coarse-resolution maps (e.g., 1 km) inevitably differ from a corresponding fine-resolution map (such as a 30-m map) that would be closer to ground truth. A better understanding of changes in grain size on area estimation will improve our...

  4. Test of magnetic susceptibility and grain-size age models of loess

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Ages of the stratigraphic boundary MIS1/2 and MIS3/4 of the Yuanbu loess section in Linxia are used as the basis of the nodal control age. The age of MIS1/2 and MIS3/4 are obtained from the latest international research result-the climatic events recorded in the stalagmite in the Hulu Cave in Nanjing, that MIS1/2 is 11.5 kaB. P. and MIS3/4 is 59.8 kaB.P.. The ages of the two climatic events contain three nodal age control models (Model 1: 0 kaB. P. -59.8 kaB. P.; Model 2: 0 kaB. P. -11.5 kaB. P. and 11.5kaB. P. -59.8 kaB. P.; Model 3: 11.5 kaB. P. -59.8 kaB. P. ), which are used as the nodal control age separately. The deposition times of various stratigraphic horizons are calculated by using the magnetic susceptibility age model and grain-size age model, and then compared with each other. In addition, the AMS14C age, OSL age and the ages of YD and H events are compared with the ages of the corresponding horizons calculated by the three models of nodal control ages. From the analyses of lithologic characters and climatic stages it has been found that both the magnetic susceptibility age model and the grain-size age model have some defects. Because the accurate control ages are selected as the nodal points of the glacial period or interglacial period, the stratigraphic deposition times determined by the high resolution of magnetic susceptibility age model and grain-size age model approximate to the actual ages. As for the relative accuracy of the two age models, the magnetic susceptibility age model is more accurate than the grain-size age model.

  5. The detection of QTLs in barley associated with endosperm hardness, grain density, grain size and malting quality using rapid phenotyping tools.

    Science.gov (United States)

    Walker, Cassandra K; Ford, Rebecca; Muñoz-Amatriaín, María; Panozzo, Joe F

    2013-10-01

    Using a barley mapping population, 'Vlamingh' × 'Buloke' (V × B), whole grain analyses were undertaken for physical seed traits and malting quality. Grain density and size were predicted by digital image analysis (DIA), while malt extract and protein content were predicted using near infrared (NIR) analysis. Validation of DIA and NIR algorithms confirmed that data for QTL analysis was highly correlated (R (2) > 0.82), with high RPD values (the ratio of the standard error of prediction to the standard deviation, 2.31-9.06). Endosperm hardness was measured on this mapping population using the single kernel characterisation system. Grain density and endosperm hardness were significantly inter-correlated in all three environments (r > 0.22, P hardness QTLs were found on 1H, 5H, and 7H. In this study, the majority of the genomic regions associated with grain texture were also coincident with QTLs for grain size, yield, flowering date and/or plant development genes. This study highlights the complexity of genomic regions associated with the variation of endosperm hardness and grain density, and their relationships with grain size traits, agronomic-related traits, and plant development loci.

  6. Determination of hydraulic conductivity from grain-size distribution for different depositional environments.

    Science.gov (United States)

    Rosas, Jorge; Lopez, Oliver; Missimer, Thomas M; Coulibaly, Kapo M; Dehwah, Abdullah H A; Sesler, Kathryn; Lujan, Luis R; Mantilla, David

    2014-01-01

    Over 400 unlithified sediment samples were collected from four different depositional environments in global locations and the grain-size distribution, porosity, and hydraulic conductivity were measured using standard methods. The measured hydraulic conductivity values were then compared to values calculated using 20 different empirical equations (e.g., Hazen, Carman-Kozeny) commonly used to estimate hydraulic conductivity from grain-size distribution. It was found that most of the hydraulic conductivity values estimated from the empirical equations correlated very poorly to the measured hydraulic conductivity values with errors ranging to over 500%. To improve the empirical estimation methodology, the samples were grouped by depositional environment and subdivided into subgroups based on lithology and mud percentage. The empirical methods were then analyzed to assess which methods best estimated the measured values. Modifications of the empirical equations, including changes to special coefficients and addition of offsets, were made to produce modified equations that considerably improve the hydraulic conductivity estimates from grain size data for beach, dune, offshore marine, and river sediments. Estimated hydraulic conductivity errors were reduced to 6 to 7.1 m/day for the beach subgroups, 3.4 to 7.1 m/day for dune subgroups, and 2.2 to 11 m/day for offshore sediments subgroups. Improvements were made for river environments, but still produced high errors between 13 and 23 m/day.

  7. Determination of hydraulic conductivity from grain-size distribution for different depositional environments

    KAUST Repository

    Rosas, Jorge

    2013-06-06

    Over 400 unlithified sediment samples were collected from four different depositional environments in global locations and the grain-size distribution, porosity, and hydraulic conductivity were measured using standard methods. The measured hydraulic conductivity values were then compared to values calculated using 20 different empirical equations (e.g., Hazen, Carman-Kozeny) commonly used to estimate hydraulic conductivity from grain-size distribution. It was found that most of the hydraulic conductivity values estimated from the empirical equations correlated very poorly to the measured hydraulic conductivity values with errors ranging to over 500%. To improve the empirical estimation methodology, the samples were grouped by depositional environment and subdivided into subgroups based on lithology and mud percentage. The empirical methods were then analyzed to assess which methods best estimated the measured values. Modifications of the empirical equations, including changes to special coefficients and addition of offsets, were made to produce modified equations that considerably improve the hydraulic conductivity estimates from grain size data for beach, dune, offshore marine, and river sediments. Estimated hydraulic conductivity errors were reduced to 6 to 7.1m/day for the beach subgroups, 3.4 to 7.1m/day for dune subgroups, and 2.2 to 11m/day for offshore sediments subgroups. Improvements were made for river environments, but still produced high errors between 13 and 23m/day. © 2013, National Ground Water Association.

  8. The origin of bimodal grain-size distribution for aeolian deposits

    Science.gov (United States)

    Lin, Yongchong; Mu, Guijin; Xu, Lishuai; Zhao, Xue

    2016-03-01

    Atmospheric dust deposition is a common phenomenon in arid and semi-arid regions. Bimodal grain size distribution (BGSD) (including the fine component and coarse component) of aeolian deposits has been widely reported. But the origin of this pattern is still debated. Here, we focused on the sedimentary process of modern dust deposition, and analyzed the grain size distribution of modern dust deposition, foliar dust, and aggregation of the aeolian dust collected in Cele Oasis, southern margin of Tarim Basin. The results show that BGSD also appear in a dust deposition. The content of fine components (dust storm is significant less than that from subsequent floating dust. Fine component also varies with altitude. These indicate that modern dust deposition have experienced changing aerodynamic environment and be reworked during transportation and deposition, which is likely the main cause for BGSD. The dusts from different sources once being well-mixed in airflow are hard to form multiple peaks respectively corresponding with different sources. In addition, the dust deposition would appear BGSD whether aggregation or not. Modern dust deposition is the continuation of ancient dust deposition. They both may have the same cause of formation. Therefore, the origin of BGSD should provide a theoretical thinking for reconstructing the palaeo-environmental changes with the indicator of grain size.

  9. New empirical relationship between grain size distribution and hydraulic conductivity for ephemeral streambed sediments

    KAUST Repository

    Rosas, Jorge

    2014-07-19

    Grain size distribution, porosity, and hydraulic conductivity were determined for 39 sediment samples collected from ephemeral streams (wadis) in western Saudi Arabia. The measured hydraulic conductivity values were then compared to values calculated using 20 different empirical equations commonly used to estimate hydraulic conductivity from grain size analyses. It was found that most of the hydraulic conductivity values estimated from the empirical equations correlated very poorly with the measured hydraulic conductivity values. Modifications of the empirical equations, including changes to special coefficients and statistical offsets, were made to produce modified equations that considerably improved the hydraulic conductivity estimates from grain size data for wadi sediments. The Chapuis, Hazen, Kozeny, Slichter, Terzaghi, and Barr equations produced the best correlations, but still had relatively high predictive errors. The Chapius equation was modified for wadi sediments by incorporating mud percentage and the standard deviation (in phi units) into a new equation that reduced the predicted hydraulic conductivity error to ±14.1 m/day. The equation is best applied to ephemeral stream samples that have hydraulic conductive values greater than 2 m/day.

  10. Energy saving cement production by grain size optimisation of the raw meal

    Directory of Open Access Journals (Sweden)

    B. Simons

    Full Text Available The production of cement clinker is an energy consuming process. At about 50% of the energy is associated with grinding and milling of the raw meal, that normally is in the range 100% <200 μm with 90% <90 μm. Question: is it possible to use coarser components of the raw meal without reducing the clinker quality. With synthetic raw meals of various grain sizes the clinker formation was studied at static (1100 - 1450°C and dynamic conditions (heating microscope. A routine to adjust the grain size of the components for industrial raw meals is developed. The fine fraction <90 μm should mainly contain the siliceous and argileous components, whereas the calcitic component can be milled separately to a grain size between 200-500 μm, resulting in lower energy consumption for milling. Considering the technical and economical realizability the relation fine/coarse should be roughly 1:1. The energy for milling can be reduced significantly, that in addition leads to the preservation of natural energy resources.

  11. Computer program for the calculation of grain size statistics by the method of moments

    Science.gov (United States)

    Sawyer, Michael B.

    1977-01-01

    A computer program is presented for a Hewlett-Packard Model 9830A desk-top calculator (1) which calculates statistics using weight or point count data from a grain-size analysis. The program uses the method of moments in contrast to the more commonly used but less inclusive graphic method of Folk and Ward (1957). The merits of the program are: (1) it is rapid; (2) it can accept data in either grouped or ungrouped format; (3) it allows direct comparison with grain-size data in the literature that have been calculated by the method of moments; (4) it utilizes all of the original data rather than percentiles from the cumulative curve as in the approximation technique used by the graphic method; (5) it is written in the computer language BASIC, which is easily modified and adapted to a wide variety of computers; and (6) when used in the HP-9830A, it does not require punching of data cards. The method of moments should be used only if the entire sample has been measured and the worker defines the measured grain-size range. (1) Use of brand names in this paper does not imply endorsement of these products by the U.S. Geological Survey.

  12. Effect of grain size on high-temperature oxidation behavior of Cu-80Ni alloy

    Institute of Scientific and Technical Information of China (English)

    曹中秋; 牛焱; 曹丽杰; 吴维(山又)

    2003-01-01

    The thermogravimetric analysis of binary Cu-80Ni alloys prepared respectively by conventional casting(CA) and mechanical alloying(MA) techniques and presenting widely different grain sizes was performed at 800 ℃ in air in order to study the effect of grain size change on the oxidation behavior of a solid solution alloy. The results show that the kinetic curves for the oxidation of the two alloys are complex and deviate from the parabolic rate law and usually are not composed of a single stage. Mixed scales were produced on the CACu-80Ni alloy surface, which consists of a mixture of copper and nickel oxides. However, oxide scale for MACu-80Ni alloy is mainly composed of a thick compact and continuous inner layer of nickel oxide. The reduction in the alloy grain size speeds up the diffusion of the more reactive component nickel from the alloy to alloy/oxide scale interface and completes the transition from a mixed scale to continuous scale of nickel oxide.

  13. How well does end-member modelling analysis of grain size data work?

    Science.gov (United States)

    Schulte, Philipp; Dietze, Michael; Dietze, Elisabeth

    2014-05-01

    End-member modelling analysis (EMMA) is a powerful and flexible statistic approach to identify and quantify generic sediment transport processes from multimodal grain-size distributions. EMMA has been introduced over 15 years ago and is now available in different approaches as encapsulated FORTRAN code (Weltje, 1997), Matlab-script (Dietze et al., 2012) and the R-package EMMAgeo (Dietze and Dietze, 2013). EMMA was mainly used to reconstruct past sedimentation processes in a variety of sedimentary environments (marine, aeolian, lacustrine). Typically, it is rather difficult to assess how meaningful and well the model performs in a certain environment, since neither the actual process end-members (generic grain-size distributions sorted by a certain sediment transport) nor their individual contributions to each sample are known a priori. To allow a comprehensive performance test, we sampled a set of four known process end-members: alluvial sand (main mode: 0.70±0.55 φ), dune sand (main mode: 1.35±0.60 φ), loess (main mode: 4.71±0.65 φ) and overbank deposit (main mode: 5.81±1.62 φ). High resolution grain-size information is based on laser-diffraction analysis (116 classes). The four process end-members were artificially mixed with random, but known proportions to yield 100 samples. This mixed data set was measured again with the laser particle size analyser and served as input for EMMA within the R-package EMMAgeo. This contribution discusses the ability of EMMA to identify and characterise the four distinct process end-members and quantify their contributions to each sample. Different ways to estimate uncertainties are presented. Further evaluations focus on the influence of numbers of included samples, numbers of grain-size classes, vertical mixing of samples (simulating turbation) and self-similarity of process end-members. Dietze E, et al. 2012. An end-member algorithm for deciphering modern detrital processes from lake sediments of Lake Donggi Cona, NE

  14. Can we use only Grain Size Data for Paleo-Flow Reconstructions?

    Science.gov (United States)

    Perillo, M. M.; Pohl, F.; Eggenhuisen, J. T.; Fedele, J.; Hoyal, D. C. J. D.; Mohrig, D. C.

    2015-12-01

    Paleo-flow and paleo-environmental reconstruction from ancient deposits is a critical task for earth surface scientists interested in the sedimentary record. Forming processes are commonly interpreted from the architectural characteristics of sedimentary deposits using quantitative relationships derived from experiments or geomorphic studies. However, very little attention has been paid to the equivalent problem at the scale of micro-facies: can we interpret the conditions at the time of sediment accumulation from grain size information in a small sample? Here we investigate the use of grain size distributions alone to reconstruct the flow conditions based on a set of experiments conducted in a 2D flume tank in the Eurotank facilities at Utrecht University. The experiments are designed for the examination of grain size distributions within sediments which were deposited by flows with known conditions (e.g. velocity, turbulence, shear velocity, concentration). By changing the slope of the flume tank we were able to create a range of flows from strongly depositional (depletive) to bypassing. Inspired by Eastwood et al (2012), we propose a working methodology to link the grain size distribution of the deposit to flow conditions. Our method utilizes the following empiric relations: i) the finer fraction of the deposit was deposited while most of that range surpass the Bagnold (1966)'s suspension threshold (shear velocity υ* approx. 3 times the settling velocity ωs); ii) the mean fraction was at incipient suspension stage (υ* ~ ωs); iii) the finer portion of the coarser grains were at bedload/saltation stage, where u* is approx. υ*c (critical shear velocity for initiation of motion); and iv) the coarser portion of the coarser grains were at creep-bedload stage, where υ* is approx. 0.7υ*c . We test whether this set of rules can be applied to the probability distribution function of deposit grainsize in an inversion that converges on a single value for the shear

  15. Preparation, characterization and combustion properties of Zr/ZrH2 particles coated with α-FeOOH crystal grains

    Institute of Scientific and Technical Information of China (English)

    Baoliang Lv; Yao Xu; Bo Hou; Dong Wu; Yuhan Sun

    2009-01-01

    Zr/ZrH2 particles with irregular morphologies and broad size distribution were uniformly coated with aci-cular α-FeOOH crystal grains via a facile route without using polymers or surfactants. The as-synthesized material was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), UV-vis diffusion reflection (UV-vis) and Raman spectrometry. Based on these char-acterizations, the synthesis mechanism was explained in terms of combined heterogeneous nucleation and solid state transformation reaction. The presence of α-FeOOH coating greatly changed the combustion behavior of Zr/ZrH2 particles: the combustion lasting time decreased from 32 s for un-coated Zr/ZrH2 par-ticles to 0.2 s for coated particles while the maximum temperature in the combustion process increased from 1510℃ to 2036℃.

  16. Only pick the right grains: Modelling the bias due to subjective grain-size interval selection for chronometric and fingerprinting approaches.

    Science.gov (United States)

    Dietze, Michael; Fuchs, Margret; Kreutzer, Sebastian

    2016-04-01

    Many modern approaches of radiometric dating or geochemical fingerprinting rely on sampling sedimentary deposits. A key assumption of most concepts is that the extracted grain-size fraction of the sampled sediment adequately represents the actual process to be dated or the source area to be fingerprinted. However, these assumptions are not always well constrained. Rather, they have to align with arbitrary, method-determined size intervals, such as "coarse grain" or "fine grain" with partly even different definitions. Such arbitrary intervals violate principal process-based concepts of sediment transport and can thus introduce significant bias to the analysis outcome (i.e., a deviation of the measured from the true value). We present a flexible numerical framework (numOlum) for the statistical programming language R that allows quantifying the bias due to any given analysis size interval for different types of sediment deposits. This framework is applied to synthetic samples from the realms of luminescence dating and geochemical fingerprinting, i.e. a virtual reworked loess section. We show independent validation data from artificially dosed and subsequently mixed grain-size proportions and we present a statistical approach (end-member modelling analysis, EMMA) that allows accounting for the effect of measuring the compound dosimetric history or geochemical composition of a sample. EMMA separates polymodal grain-size distributions into the underlying transport process-related distributions and their contribution to each sample. These underlying distributions can then be used to adjust grain-size preparation intervals to minimise the incorporation of "undesired" grain-size fractions.

  17. DUST DYNAMICS IN PROTOPLANETARY DISK WINDS DRIVEN BY MAGNETOROTATIONAL TURBULENCE: A MECHANISM FOR FLOATING DUST GRAINS WITH CHARACTERISTIC SIZES

    Energy Technology Data Exchange (ETDEWEB)

    Miyake, Tomoya; Suzuki, Takeru K.; Inutsuka, Shu-ichiro, E-mail: miyake.tomoya@e.mbox.nagoya-u.ac.jp, E-mail: stakeru@nagoya-u.jp [Department of Physics, Nagoya University, Nagoya, Aichi 464-8602 (Japan)

    2016-04-10

    We investigate the dynamics of dust grains of various sizes in protoplanetary disk winds driven by magnetorotational turbulence, by simulating the time evolution of the dust grain distribution in the vertical direction. Small dust grains, which are well-coupled to the gas, are dragged upward with the upflowing gas, while large grains remain near the midplane of a disk. Intermediate-size grains float near the sonic point of the disk wind located at several scale heights from the midplane, where the grains are loosely coupled to the background gas. For the minimum mass solar nebula at 1 au, dust grains with size of 25–45 μm float around 4 scale heights from the midplane. Considering the dependence on the distance from the central star, smaller-size grains remain only in an outer region of the disk, while larger-size grains are distributed in a broader region. We also discuss the implications of our result for observations of dusty material around young stellar objects.

  18. Initial Tests on First Full-size Endcap Crystals

    CERN Document Server

    Davies, Gavin; Lecoq, Paul; Marcos, Roger; Schneegans, Marc; Sempere-Roldan, P

    1999-01-01

    At the end of last year the first full size ECAL endcap crystals were delivered to CERN.Thirty in number, they were produced to the final geometrical specifications; 220mm long with a rear square face of 30mm and a front square face of 28.6mm. All were de livered polished. The visual inspection, dimension, transmission, light yield and light yield uniformity tests carried out since are discussed, with particular emphasis on the light yield uniformity. The results are very encouraging.

  19. Grain size effect on the Neel temperature and magnetic properties of nanocrystalline $NiFe{_2}O{_4}$ spinel

    OpenAIRE

    Chinnasamy, CN; Narayanasamy, A.; Ponpandian, N; Joseyphus, RJ; Jeyadevan, B.; Tohji, K.; Chattopadhyay, K.

    2002-01-01

    Nanocrystalline NiFe2O4 spinel ferrites with various grain sizes have been synthesized by ball milling the bulk NiFe2O4. The average grain sizes were estimated from the X-ray line broadening of the (3 1 1) reflection. The Neel temperatures of NiFe2O4 for various grain sizes were determined by magneto thermogravimetric method. The magnetic behaviour has been explained by combining the effects of changes in cation distribution on milling and finite size scaling. The shift in B-H loops has been ...

  20. Enhanced proton conductivity of niobium phosphates by interfacing crystal grains with an amorphous functional phase

    DEFF Research Database (Denmark)

    Huang, Yunjie; Yu, Lele; Li, Haiyan

    2016-01-01

    Niobium phosphate is an interesting proton conductor operational in the intermediate temperature range. In the present work two forms of phosphates were prepared: an amorphous one with high specific area and a crystalline one with low specific surface area. Both phosphates exhibited very low proton...... conductivities. An activation process was developed to convert the phosphates into crystal grains with a phosphorus rich amorphous phase along the grain boundaries. As a result, the obtained niobium phosphates showed considerably enhanced and stable proton conductivities. The activation effect was prominent when...... the high surface area amorphous phosphate was used as the precursor. At 250 °C thus obtained niobium phosphate showed a high and stable conductivity of 0.03 S cm−1 under dry atmosphere and of 0.06 S cm−1 at a water partial pressure of 0.12 atm....

  1. Effects of particle optical properties on grain size measurements of aeolian dust deposits

    Science.gov (United States)

    Varga, György; Újvári, Gábor; Kovács, János; Szalai, Zoltán

    2015-04-01

    Particle size data are holding crucial information on the sedimentary environment at the time the aeolian dust deposits were accumulated. Various aspects of aeolian sedimentation (wind strength, distance to source(s), possible secondary source regions and modes of sedimentation and transport) can be reconstructed from proper grain size distribution data. Laser diffraction methods provide much more accurate and reliable information on the major granulometric properties of wind-blown sediments compared to the sieve and pipette methods. The Fraunhofer and Mie scattering theories are generally used for laser diffraction grain size measurements. () The two different approaches need different 'background' information on the medium measured. During measurements following the Fraunhofer theory, the basic assumption is that parcticles are relatively large (over 25-30 µm) and opaque. The Mie theory could offer more accurate data on smaller fractions (clay and fine silt), assuming that a proper, a'priori knowledge on refraction and absorption indices exists, which is rarely the case for polymineral samples. This study is aimed at determining the effects of different optical parameters on grain size distributions (e.g. clay-content, median, mode). Multiple samples collected from Hungarian red clay and loess-paleosol records have been analysed using a Malvern Mastersizer 3000 laser diffraction particle sizer (with a Hydro LV unit). Additional grain size measurements have been made on a Fritsch Analysette 22 Microtec and a Horiba Partica La-950 v2 instrument to investigate possible effects of the used laser sources with different wavelengths. XRF and XRD measurements have also been undertaken to gain insight into the geochemical/mineralogical compositions of the samples studied. Major findings include that measurements using the Mie theory provide more accurate data on the grain size distribution of aeolian dust deposits, when we use a proper optical setting. Significant

  2. Investigation of the size effect for photonic crystals

    Science.gov (United States)

    Liu, M.; Xu, W.; Bai, J.; Chua, C. K.; Wei, J.; Li, Z.; Gao, Y.; Kim, D. H.; Zhou, K.

    2016-10-01

    Three types of photonic crystal (PC) thin films have been prepared for the investigation of their deformation behaviors by nanoindentation tests at the microscale and nanoscale. Each type of PC thin film was composed of poly(methyl methacrylate) (PMMA) nanoparticles with a uniform size. Another type of thin film was prepared by assembling nanoparticles with three different sizes. It was exciting to observe that the hardness and Young’s modulus were significantly improved (more than 15 times) in well-ordered PC thin films than disordered ones. Furthermore, size-dependent mechanical properties were observed for the three types of PCs. Such a size effect phenomenon can be attributed to the special polycrystalline material having a periodical face-centered cubic structure of PC thin films. Furthermore, the indentation size effect that shows that the indentation hardness decreases with an increasing indentation depth has also been observed for all four types of thin films. It is conjectured that the application of the PC structure to other functional materials may enhance their mechanical properties.

  3. Debris flow grain size scales with sea surface temperature over glacial-interglacial timescales

    Science.gov (United States)

    D'Arcy, Mitch; Roda Boluda, Duna C.; Whittaker, Alexander C.; Araújo, João Paulo C.

    2015-04-01

    Debris flows are common erosional processes responsible for a large volume of sediment transfer across a range of landscapes from arid settings to the tropics. They are also significant natural hazards in populated areas. However, we lack a clear set of debris flow transport laws, meaning that: (i) debris flows remain largely neglected by landscape evolution models; (ii) we do not understand the sensitivity of debris flow systems to past or future climate changes; and (iii) it remains unclear how to interpret debris flow stratigraphy and sedimentology, for example whether their deposits record information about past tectonics or palaeoclimate. Here, we take a grain size approach to characterising debris flow deposits from 35 well-dated alluvial fan surfaces in Owens Valley, California. We show that the average grain sizes of these granitic debris flow sediments precisely scales with sea surface temperature throughout the entire last glacial-interglacial cycle, increasing by ~ 7 % per 1 ° C of climate warming. We compare these data with similar debris flow systems in the Mediterranean (southern Italy) and the tropics (Rio de Janeiro, Brazil), and find equivalent signals over a total temperature range of ~ 14 ° C. In each area, debris flows are largely governed by rainfall intensity during triggering storms, which is known to increase exponentially with temperature. Therefore, we suggest that these debris flow systems are transporting predictably coarser-grained sediment in warmer, stormier conditions. This implies that debris flow sedimentology is governed by discharge thresholds and may be a sensitive proxy for past changes in rainfall intensity. Our findings show that debris flows are sensitive to climate changes over short timescales (≤ 104 years) and therefore highlight the importance of integrating hillslope processes into landscape evolution models, as well as providing new observational constraints to guide this. Finally, we comment on what grain size

  4. Determination of the total grain size distribution in a vulcanian eruption column, and its implications to stratospheric aerosol perturbation

    Science.gov (United States)

    Murrow, P. J.; Rose, W. I., Jr.; Self, S.

    1980-11-01

    The total grain distribution of tephra from the eruption by the Fuego volcano in Guatemala on Oct. 14, 1974 was determined by grain size analysis. The region within each isopach has a grain distribution which was weighted proportionally to its percentage volume; the total distribution had a median grain size of 0.6 mm and a sorting coefficient of 2.3. The ash composed of fine particles did not fall in the volcano area as part of the recognizable tephra blanket; the eruption column reached well into the stratosphere to the height of 10-12 km above sea level, with mass flux rate estimated altitudes of 18-23 km

  5. The effect of oxide particles on the strength and ductility of bulk iron with a bimodal grain size distribution

    Energy Technology Data Exchange (ETDEWEB)

    Casas, C.; Tejedor, R. [Department of Materials Science and Metallurgical Engineering, ETSEIB, Universitat Politècnica de Catalunya, Av. Diagonal 647, 08028 Barcelona (Spain); Rodríguez-baracaldo, R. [Department of Mechanical Engineering, Universidad Nacional de Colombia, Bogotá. Colombia (Colombia); Benito, J.A., E-mail: Josep.a.benito@upc.edu [Department of Materials Science and Metallurgical Engineering, EUETIB, Universitat Politècnica de Catalunya, Comte d' Urgell 187, 08036 Barcelona (Spain); Fundació CTM Centre Tecnològic de Manresa, Plaça de la Ciencia, 2, 08243 Manresa (Spain); Cabrera, J.M. [Department of Materials Science and Metallurgical Engineering, ETSEIB, Universitat Politècnica de Catalunya, Av. Diagonal 647, 08028 Barcelona (Spain); Fundació CTM Centre Tecnològic de Manresa, Plaça de la Ciencia, 2, 08243 Manresa (Spain)

    2015-03-11

    The strength and ductility of bulk nanostructured and ultrafine-grained iron containing 0.39% oxygen by weight was determined by tensile tests. Samples were obtained by consolidation of milled iron powder at 500 °C. Heat treatments were designed to cover a wide range of grain sizes spanning from 100 to 2000 nm with different percentages of coarse and nanostructured grain areas, which was defined as a bimodal grain size distribution. Transmission electron microscopy was used to determine the diameter, volume fraction and location of oxides in the microstructure. The strength was analysed following two approaches. The first one was based on the strong effect of oxides and involved the use of a mixed particle-grain boundary strengthening model, and the second one was based on simple grain boundary strengthening. The mixed model underestimated the strength of nanostructured samples, whereas the simple grain boundary model worked better. However, for specimens with a bimodal grain size, the fitting of the mixed model was better. In this case, the more effective particle strengthening was related to the dispersion of oxides inside the large ferrite grains. In addition, the bimodal samples showed an acceptable combination of strength and ductility. Again, the ferrite grains containing oxides promoted strain hardening due to the increase in dislocation activity.

  6. Superlocalization and Formation of Grain Structure in Ni3ge Single Crystals with Different Orientations of Deformation Axes

    Science.gov (United States)

    Solov'eva, Yu. V.; Lipatnikova, Ya. D.; Starenchenko, S. V.; Solov'ev, A. N.; Starenchenko, V. A.

    2017-09-01

    The paper describes the influence of orientation of Ni3Ge single crystal deformation axes on the high-temperature superlocalization of plastic deformation. Mechanical properties of single crystals with different orientations are studied in this paper as well as the slip traces and the evolution of the dislocation structure. Based on these investigations, the observing conditions are described for the superlocalization bands and the formation of the grain structure in local areas of the original single crystal.

  7. Microplastics in the Mediterranean Sea: Deposition in coastal shallow sediments, spatial variation and preferential grain size.

    Science.gov (United States)

    Alomar, Carme; Estarellas, Fernando; Deudero, Salud

    2016-04-01

    Marine litter loads in sea compartments are an emergent issue due to their ecological and biological consequences. This study addresses microplastic quantification and morphological description to test spatial differences along an anthropogenic gradient of coastal shallow sediments and further on to evaluate the preferential deposition of microplastics in a given sediment grain fraction. Sediments from Marine Protected Areas (MPAs) contained the highest concentrations of microplastics (MPs): up to 0.90 ± 0.10 MPs/g suggesting the transfer of microplastics from source areas to endpoint areas. In addition, a high proportion of microplastic filaments were found close to populated areas whereas fragment type microplastics were more common in MPAs. There was no clear trend between sediment grain size and microplastic deposition in sediments, although microplastics were always present in two grain size fractions: 2 mm > x > 1 mm and 1 mm > x 0.5 mm.

  8. Influence of grain size and exchange interaction on the LLB modeling procedure

    Science.gov (United States)

    Vogler, Christoph; Abert, Claas; Bruckner, Florian; Suess, Dieter; Praetorius, Dirk

    2016-12-01

    Reliably predicting bit-error rates in realistic heat-assisted magnetic recording simulations is a challenging task. Integrating the Landau-Lifshitz-Bloch (LLB) equation, within a coarse graining approach, can reduce the computational effort to determine the magnetization dynamics in the vicinity of the Curie temperature, compared to solving the atomistic Landau-Lifshitz-Gilbert equation. If the aim is that the dynamics of both approaches coincide, temperature dependent material functions, such as the zero-field equilibrium magnetization as well as the parallel and normal susceptibilities, must be modeled carefully in order to use them as input in the LLB equation. We present an extensive study on how these functions depend on grain size and exchange interactions. We show that, if the size or the exchange constant of a reference grain is modified, the material functions can be scaled, according to the changed Curie temperature, yielding negligible errors. This is shown to be valid for volume changes of up to ±40% and variations of the exchange constant of up to ±10%. Besides the temperature dependent material curves, computed switching probabilities also agree well with probabilities separately determined for each system. Our study suggests that there is no need to recalculate the required LLB input functions for each particle. Within the presented limits, it is sufficient to scale them to the Curie temperature of the altered system.

  9. DEPENDENCE OF GRAIN SIZE OF AUSTENITE STEEL OF RAILWAY WHEEL FROM PARAMETERS OF HOT DEFORMATION

    Directory of Open Access Journals (Sweden)

    L. I. Vakulenko

    2015-03-01

    Full Text Available Purpose. The estimation of heat temperature influence and degree of hot reduction of carbon steel on the size of grain аustenite at making of railway wheels. Methodology. The material for research was carbon steel, mark 60 with carbon content of 0,55 and 0,65 %, selected from the fragments of railway wheels. The size of grain аustenite depending on a temperature (from 800 to 1 150 ºC and degrees of hot deformation (10−50 % was determined. The size of grain was determined under a light microscope with the use of quantitative metallography methods. Findings. The use of cooling in the process of hot reduction of the railway wheel will allow dispergating the structure of аustenite on large distances from the surface of the rim. The reason for this is that the volumes of metal after cooling have an increased strength and will be exposed in less degree to the plastic deformation. To compare the cooling layers near-by with the surface of rim, they are more warmed-up in internal volumes of metal. In the conditions of continuity of plastic deformation distribution, having a high temperature, they will be exposed to the reduction on the large total degree of deformation. In consequence of the resulted decisions more even austenitic structure must be formed on the section of rim of railway wheel. To obtain the effect of disperse grain of аustenite at making of the whole-rolled railway wheels it is necessary to decrease the heat temperature of billet under rolling or increase the degree of reduction on the lasts stages of shape-generating deformation. The pause by duration of 1,5 min. after reduction of 20 % at a temperature 950 ºC is sufficiently for processes completion of dynamic and static recrystalization of аustenite carbon steel of the railway wheel. Originality. Increase of plastic deformation degree, especially in the central volumes of rim is accompanied by the decrease of heterogeneity of austenitic structure on his section. The

  10. Experimental investigation of dynamic effects in capillary pressure: Grain size dependency and upscaling

    Science.gov (United States)

    Camps-Roach, Geremy; O'Carroll, Denis M.; Newson, Timothy A.; Sakaki, Toshihiro; Illangasekare, Tissa H.

    2010-08-01

    The macroscopic flow equations used to predict two-phase flow typically utilizes a capillary pressure-saturation relationship determined under equilibrium conditions. Theoretical reasoning, experimental evidence, and numerical modeling results have indicated that when one fluid phase replaces another fluid, this relationship may not be unique but may depend on the rate at which the phase saturations change in response to changes in phase pressures. This nonuniqueness likely depends on a variety of factors including soil-fluid properties and possibly physical scale. To quantify this dependency experimentally, direct measurements of equilibrium and dynamic capillary pressure-saturation relationships were developed for two Ottawa sands with different grain sizes using a 20 cm long column. A number of replicate air-water experiments were conducted to facilitate statistical comparison of capillary pressure-saturation relationships. Water and air pressures and phase saturations were measured at three different vertical locations in the sand column under different desaturation rates (1) to measure local capillary pressure-saturation relationships (static and dynamic); (2) to quantify the dynamic coefficient τ, a measure of the magnitude of observed dynamic effects, as a function of water saturation for different grain sizes and desaturation rates; (3) to investigate the importance of grain size on measured dynamic effects; and (4) to assess the importance of sample scale on the magnitude of dynamic effects in capillary pressure. A comparison of the static and dynamic Pc-Sw relationships showed that at a given water saturation, capillary pressure measured under transient water drainage conditions is statistically larger than capillary pressure measured under equilibrium or static conditions, consistent with thermodynamic theory. The dynamic coefficient τ, used in the expression relating the static and dynamic capillary pressures to the desaturation rate was dependant on

  11. The effect of grain size and phosphorous-doping of polycrystalline 3C-SiC on infrared reflectance spectra

    Energy Technology Data Exchange (ETDEWEB)

    Rooyen, I.J. van, E-mail: Isabella.vanRooyen@inl.gov [Fuel Performance and Design Department, Idaho National Laboratory, Idaho Falls, ID 83415-6188 (United States); Department of Physics, Nelson Mandela Metropolitan University, Port Elizabeth (South Africa); Engelbrecht, J.A.A. [Department of Physics, Nelson Mandela Metropolitan University, Port Elizabeth (South Africa); Henry, A.; Janzen, E. [Department of Physics, Chemistry and Biology, Semiconductor Materials, Linkoeping University, Linkoeping 58183 (Sweden); Neethling, J.H. [Department of Physics, Nelson Mandela Metropolitan University, Port Elizabeth (South Africa); Rooyen, P.M. van [Philip M van Rooyen Network Consultants, Midlands Estates (South Africa)

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer IR is investigated as a technique to measure grain size and P-doping of polycrystalline SiC. Black-Right-Pointing-Pointer Infrared plasma minima can be used to determine doping levels in 3C-SiC for doping levels greater than 5 Multiplication-Sign 10{sup 17} cm{sup -3}. Black-Right-Pointing-Pointer A linear relationship is found between FWHM and the inverse of grain size of 3C-SiC irrespective of P-doping level. Black-Right-Pointing-Pointer It is further found that {omega}{sub p} is not influenced by the grain size. Black-Right-Pointing-Pointer P-doping level has no significant effect on the linear relationship between grain size and surface roughness. - Abstract: The effect of P-doping and grain size of polycrystalline 3C-SiC on the infrared reflectance spectra is reported. The relationship between grain size and full width at half maximum (FWHM) suggest that the behavior of the 3C-SiC with the highest phosphorous doping level (of 1.2 Multiplication-Sign 10{sup 19} at. cm{sup -3}) is different from those with lower doping levels (<6.6 Multiplication-Sign 10{sup 18} at. cm{sup -3}). It is also further demonstrated that the plasma resonance frequency ({omega}{sub p}) is not influenced by the grain size.

  12. Effect of grain size on the mechanical properties of dual phase Fe/Si/C steels

    Energy Technology Data Exchange (ETDEWEB)

    Ahn, J.H.

    1983-08-01

    For an Fe/2Si/0.1C steel with an intermediate quenching heat treatment, it was found that as the prior austenite grain size is refined, significant improvements in total elongation, reduction in area and impact toughness can be achieved, while uniform elongation, yield and tensile strengths are not affected. These improvements are analyzed in terms of microstructure and fracture characteristics. The cleavage cracks propagate nearly straight without deviation at the ferrite/martensite interfaces within the sub-units of the DFM structure, but change their path at high angle sub-unit boundaries. The crack is less likely to be deflected at the ferrite/martensite interface because the interface is coherent. Comparison of optical micrographs and SEM fractographs has shown that there is close agreement between the sub-unit size and cleavage facet size. The observations lead to the conclusion that the sub-unit size is the basic microstructure unit controlling the fracture behavior of DFM steels produced by the intermediate quenching heat treatment. A controlled rolling process was undertaken to obtain grain refined DFM steels. Results showed that this produces micro-duplex structures with attractive mechanical properties in an economicl way.

  13. The potential for adaptive evolution of pollen grain size in Mimulus guttatus.

    Science.gov (United States)

    Lamborn, Ellen; Cresswell, James E; Macnair, Mark R

    2005-07-01

    We tested whether pollen grain size (PGS) shows heritable variation in three independent populations of Mimulus guttatus by imposing artificial selection for this character. In addition, we looked for correlated responses to selection in a range of 15 other floral characters. Heritable variation in PGS was found in all three populations, with heritabilities of between 19 and 40% (average 30%). After three generations, upward and downward lines differed on average by 30% in pollen volume. No consistent patterns of correlated response were found in other characters, indicating that PGS can respond to selective forces acting on PGS alone. Possible selection mechanisms on PGS in this species could include intermale selection, if large pollen grains produce more competitive gametophytes; or optimization of patterns of resource allocation, if local mate competition varies.

  14. Influence of grain size, shape and compaction on georadar waves: example of an Aeolian dune

    CERN Document Server

    Guillemoteau, Julien; Dujardin, Jean-Rémi; 10.1111/j.1365-246X.2012.05577.x

    2012-01-01

    Many Ground Penetrating Radar (GPR) profiles acquired in dry aeolian environment have shown good reflectivity inside present-day dunes. We show that the origin of this reflectivity is related to changes in grain size distribution, packing and/or grain shape in a sandy material. We integrate these three parameters into analytical models for bulk permittivity in order to predict the reflections and the velocity of GPR waves. We consider two GPR cross-sections acquired over Aeolian dunes in the Chadian desert. The 2D migration of GPR data suggests that dunes contain different kinds of bounding surfaces. We discuss and model three kinds of reflections using reasonable geological hypothesis about Aeolian sedimentation processes. The propagation and the reflection of radar waves are calculated using the 1D wavelet modelling method in spectral domain. The results of the forward modelling are in good accordance with real observed data.

  15. Location, Identification, and Size Distribution of Depleted Uranium Grains in Reservoir Sediments

    Science.gov (United States)

    Lo, D.; Fleischer, R. L.; Albert, E. A.; Arnason, J. G.

    2006-05-01

    The location, isotopic composition, and size distribution of uranium-rich grains in sediment layers can be identified by analysis of etched particle tracks. Samples are pressed against track detectors, irradiated with thermal neutrons, and the detectors are chemically etched to reveal fission tracks. The total track abundance from the sample is a measure of the U-235 content; hence, if the bulk uranium (mostly U-238) has been measured, the two sets of results give the depletion or enrichment of the uranium. Each uranium-rich particle produces a sunburst of tracks where the number of tracks is proportional to the size of the particle. From 1958 to 1984, National Lead Industries processed depleted uranium (DU) at its plant in Colonie, NY (just west of Albany). Radioactive materials, principally DU, that were emitted from its exhaust stacks have been found 40 km away (Dietz, 1981). We have studied a sediment core taken by Arnason and Fletcher (2003, 2004) from a small body of water, the Patroon Reservoir, which is 1 km east-southeast of the National Lead plant. Examination of portions of that core demonstrates the usefulness of induced nuclear tracks (1) to locate microscopic high-uranium grains for further mineralogical study ; (2) to determine the size distribution of uranium grains; and (3) to help analyze the average isotopic depletion of the uranium when total U concentrations are known. We infer that the size of DU particles in the sediment was controlled by both atmospheric transport from stack to reservoir and fluvial transport within the reservoir.

  16. Beyond the threshold for motion: river channel geometry and grain size reflect sediment supply

    Science.gov (United States)

    Pfeiffer, A.; Finnegan, N. J.; Willenbring, J. K.

    2016-12-01

    In many gravel-bedded rivers, floods that fill the ch­­annel banks create just enough shear stress to move the median-sized gravel particles on the bed surface (D50). Because this observation is common and is supported by theory, the coincidence of bankfull flow and the incipient motion of D50 has become a­­ commonly employed assumption. However, not all natural gravel channels actually conform to this simple relationship; some channels maintain bankfull stresses far in excess of the critical stress required to initiate sediment transport. We use a database of >300 gravel-bedded rivers and >600 10Be-derived erosion rates from across North America to explore the hypothesis that sediment supply drives the magnitude of bankfull shear stress relative to the critical stress required to mobilize the median bed surface grain size. We find that the ratio of bankfull to critical stress is significantly higher in West Coast river reaches (2.47, n= 84) than in river reaches in the rest of the continent (1.03, n = 245). This pattern parallels trends in erosion rates (and hence sediment supplies). Supporting our hypothesis, we find a significant correlation between upstream erosion rate and local τ*bf/τ*c at sites where this comparison is possible. Our analysis reveals a decrease in bed surface armoring with increasing τ*bf/τ*c, suggesting that channels accommodate changes in sediment supply through adjustments in bed surface grain size, as predicted through numerical modeling. Our findings demonstrate that sediment supply is encoded in the bankfull hydraulic geometry of gravel-bedded channels through its control on bed surface grain size.

  17. Exploring the effects of temperature and grain size on plumes associated with PDCs through analogue experimentation

    Science.gov (United States)

    Mitchell, S. J.; Eychenne, J.; Rust, A.

    2015-12-01

    Pyroclastic density currents (PDCs) often loft upwards into convective, buoyant co-PDC plumes. Recent analogue experiments using a unimodal grain size of 22 ± 6 μm (Andrews & Manga, 2012) have established that plume generation is aided by PDC interaction with a topographic barrier. Here, we have simulated the onset of co-PDC plumes from the collapse of concentrated particle-gas mixtures comprised of unimodal or bimodal grain size distributions (GSD) of glass beads, using combinations of lognormal populations with modes of 35, 195 and 590 μm. The collapse of a mixture, with constant mass 2950 ± 150 g, induced the propagation of a gravity current channelized down a 13° sloping tank; a barrier in the tank caused the gravity current to produce a plume of particles. Experiments were recorded with high speed visible and thermal-infrared cameras. Initial GSD and temperature of the mixture were varied to assess the effects of the addition of a coarser component on plume generation. Analogue co-PDC plumes were only produced when a proportion of fine grains (35 μm) was present in the initial granular mixture. Sampling of the particles entrained in the co-PDC plumes revealed that fine grains (35 μm) are preferentially lofted, although a few coarser particles (195 or 590 μm) are also entrained in the co-PDC plumes and settle closer to the area of uplift. Increasing the initial temperature of the mixture increases plume height measured at 1 and 2s after onset; this is supported by repeat experiments at specific conditions. Bimodal mixtures containing both fine (35 μm) and coarser (195 or 590 μm) grains result in plume heights and initial flow velocities higher than observed in unimodal fine-grained experiments of the same total mass of particles. Repeat experiments identify the natural variability in plume generation under the same nominal conditions, which is likely due to the combined variations of momentum during flow propagation and heat-driven buoyancy, as well

  18. Comparison of Automated Image-Based Grain Sizing to Standard Pebble Count Methods

    Science.gov (United States)

    Strom, K. B.

    2009-12-01

    This study explores the use of an automated, image-based method for characterizing grain-size distributions (GSDs) of exposed, open-framework gravel beds. This was done by comparing the GSDs measured with an image-based method to distributions obtained with two pebble-count methods. Selection of grains for the two pebble-count methods was carried out using a gridded sampling frame and the heel-to-toe Wolman walk method at six field sites. At each site, 500-partcle pebble-count samples were collected with each of the two pebble-count methods and digital images were systematically collected over the same sampling area. For the methods used, the pebble counts collected with the gridded sampling frame were assumed to be the most accurate representations of the true grain-size population, and results from the image-based method were compared to the grid derived GSDs for accuracy estimates; comparisons between the grid and Wolman walk methods were conducted to give an indication of possible variation between commonly used methods for each particular field site. Comparison of grain sizes were made at two spatial scales. At the larger scale, results from the image-based method were integrated over the sampling area required to collect the 500-particle pebble-count samples. At the smaller sampling scale, the image derived GSDs were compared to those from 100-particle, pebble-count samples obtained with the gridded sampling frame. The comparisons show that the image-based method performed reasonably well on five of the six study sites. For those five sites, the image-based method slightly underestimate all grain-size percentiles relative to the pebble counts collected with the gridded sampling frame. The average bias for Ψ5, Ψ50, and Ψ95 between the image and grid count methods at the larger sampling scale was 0.07Ψ, 0.04Ψ, and 0.19Ψ respectively; at the smaller sampling scale the average bias was 0.004Ψ, 0.03Ψ, and 0.18Ψ respectively. The average bias between the

  19. Grain-size-induced weakening of H2O ices I and II and associated anisotropic recrystallization

    Science.gov (United States)

    Stern, L.A.; Durham, W.B.; Kirby, S.H.

    1997-01-01

    Grain-size-dependent flow mechanisms tend to be favored over dislocation creep at low differential stresses and can potentially influence the rheology of low-stress, low-strain rate environments such as those of planetary interiors. We experimentally investigated the effect of reduced grain size on the solid-state flow of water ice I, a principal component of the asthenospheres of many icy moons of the outer solar system, using techniques new to studies of this deformation regime. We fabricated fully dense ice samples of approximate grain size 2 ?? 1 ??m by transforming "standard" ice I samples of 250 ?? 50 ??m grain size to the higher-pressure phase ice II, deforming them in the ice II field, and then rapidly releasing the pressure deep into the ice I stability field. At T ??? 200 K, slow growth and rapid nucleation of ice I combine to produce a fine grain size. Constant-strain rate deformation tests conducted on these samples show that deformation rates are less stress sensitive than for standard ice and that the fine-grained material is markedly weaker than standard ice, particularly during the transient approach to steady state deformation. Scanning electron microscope examination of the deformed fine-grained ice samples revealed an unusual microstructure dominated by platelike grains that grew normal to the compression direction, with c axes preferentially oriented parallel to compression. In samples tested at T ??? 220 K the elongation of the grains is so pronounced that the samples appear finely banded, with aspect ratios of grains approaching 50:1. The anisotropic growth of these crystallographically oriented neoblasts likely contributes to progressive work hardening observed during the transient stage of deformation. We have also documented remarkably similar microstructural development and weak mechanical behavior in fine-grained ice samples partially transformed and deformed in the ice II field.

  20. Rainfall-runoff properties of tephra: Simulated effects of grain-size and antecedent rainfall

    Science.gov (United States)

    Jones, Robbie; Thomas, Robert E.; Peakall, Jeff; Manville, Vern

    2017-04-01

    Rain-triggered lahars (RTLs) are a significant and often persistent secondary volcanic hazard at many volcanoes around the world. Rainfall on unconsolidated volcaniclastic material is the primary initiation mechanism of RTLs: the resultant flows have the potential for large runout distances (> 100 km) and present a substantial hazard to downstream infrastructure and communities. RTLs are frequently anticipated in the aftermath of eruptions, but the pattern, timing and scale of lahars varies on an eruption-by-eruption and even catchment-by-catchment basis. This variability is driven by a set of local factors including the grain size distribution, thickness, stratigraphy and spatial distribution of source material in addition to topography, vegetation coverage and rainfall conditions. These factors are often qualitatively discussed in RTL studies based on post-eruption lahar observations or instrumental detections. Conversely, this study aims to move towards a quantitative assessment of RTL hazard in order to facilitate RTL predictions and forecasts based on constrained rainfall, grain size distribution and isopach data. Calibrated simulated rainfall and laboratory-constructed tephra beds are used within a repeatable experimental set-up to isolate the effects of individual parameters and to examine runoff and infiltration processes from analogous RTL source conditions. Laboratory experiments show that increased antecedent rainfall and finer-grained surface tephra individually increase runoff rates and decrease runoff lag times, while a combination of these factors produces a compound effect. These impacts are driven by increased residual moisture content and decreased permeability due to surface sealing, and have previously been inferred from downstream observations of lahars but not identified at source. Water and sediment transport mechanisms differ based on surface grain size distribution: a fine-grained surface layer displayed airborne remobilisation

  1. Grain size dependence of dynamic mechanical behavior of AZ31B magnesium alloy sheet under compressive shock loading

    Energy Technology Data Exchange (ETDEWEB)

    Asgari, H., E-mail: hamed.asgari@usask.ca [Department of Mechanical Engineering, University of Saskatchewan, Saskatoon (Canada); Odeshi, A.G.; Szpunar, J.A. [Department of Mechanical Engineering, University of Saskatchewan, Saskatoon (Canada); Zeng, L.J.; Olsson, E. [Department of Applied Physics, Chalmers University of Technology, Göteborg (Sweden)

    2015-08-15

    The effects of grain size on the dynamic deformation behavior of rolled AZ31B alloy at high strain rates were investigated. Rolled AZ31B alloy samples with grain sizes of 6, 18 and 37 μm, were subjected to shock loading tests using Split Hopkinson Pressure Bar at room temperature and at a strain rate of 1100 s{sup −} {sup 1}. It was found that a double-peak basal texture formed in the shock loaded samples. The strength and ductility of the alloy under the high strain-rate compressive loading increased with decreasing grain size. However, twinning fraction and strain hardening rate were found to decrease with decreasing grain size. In addition, orientation imaging microscopy showed a higher contribution of double and contraction twins in the deformation process of the coarse-grained samples. Using transmission electron microscopy, pyramidal dislocations were detected in the shock loaded sample, proving the activation of pyramidal slip system under dynamic impact loading. - Highlights: • A double-peak basal texture developed in all shock loaded samples. • Both strength and ductility increased with decreasing grain size. • Twinning fraction and strain hardening rate decreased with decreasing grain size. • ‘g.b’ analysis confirmed the presence of dislocations in shock loaded alloy.

  2. Quantifying Grain-Size Variability of Metal Pollutants in Road-Deposited Sediments Using the Coefficient of Variation.

    Science.gov (United States)

    Zhao, Hongtao; Wang, Xiaoxue; Li, Xuyong

    2017-07-28

    Particle grain size is an important indicator for the variability in physical characteristics and pollutants composition of road-deposited sediments (RDS). Quantitative assessment of the grain-size variability in RDS amount, metal concentration, metal load and GSFLoad is essential to elimination of the uncertainty it causes in estimation of RDS emission load and formulation of control strategies. In this study, grain-size variability was explored and quantified using the coefficient of variation (Cv) of the particle size compositions, metal concentrations, metal loads, and GSFLoad values in RDS. Several trends in grain-size variability of RDS were identified: (i) the medium class (105-450 µm) variability in terms of particle size composition, metal loads, and GSFLoad values in RDS was smaller than the fine (coefficient (Lc), the Cv was similarly effective at describing the grain-size variability, whereas it is simpler to calculate because it did not require the data to be pre-processed. The results of this study will facilitate identification of the uncertainty in modelling RDS caused by grain-size class variability.

  3. Effect of Grain Size on Selected Physico-Chemical Properties of Clay

    Directory of Open Access Journals (Sweden)

    Osumanu H. Ahmed

    2009-01-01

    Full Text Available Problem statement: Mixture of the right proportion of expanding and non-expanding clays to improve plasticity (moldability of clays used in the pot industry of Malaysia is yet to be well investigated. In addition, little is known about the choice of the right clay size to eliminate or reduce the content of undesirable compounds such as Fe2O3, Al2O3 to improve the strength of pots and roofing tiles in the country. The objective of this study was to investigate how selected physico-chemical properties of pottery clay relate to grain size of Nyalau series ((Typic Paleudults. Approach: Soil samples were refined into 25, 20 and 63 µm using size grading method. The mineralogical composition of the samples was determined using X-Ray Diffraction (XRD. The chemical composition of the samples was also determined using standard procedures. Firing was done at 800°C in a muffle furnace and the cracks of the samples recorded. Results: The clay particles with sizes 20 and 25 µm were higher in LOI and total C than that those of 63 µm regardless of grain size, the clay investigated had quartz (SiO2, illite-montmorillonite, Anatase ((TiO2 and kaolinite. Grading affected the concentrations of Fe, Al and Si as clays with particle sizes 20 and 25 µm had higher contents of the aforementioned elements compared with those of 63 µm. The clay with particles 63 µm had the best strength and this was so because the clay particles had the lowest amount of Fe, Al and Si. Conclusion: The strength of Malaysian pots could be improved upon proper grading of the clay particles.

  4. Crystal Size Distributions in Igneous rocks: Where are we now?

    Science.gov (United States)

    Higgins, M.

    2003-12-01

    Modern Crystal Size Distributions (CSD) studies started in 1988 and have expanded since then, albeit somewhat slowly. We have now measured CSDs in a variety of different compositions and for both plutonic and volcanic rocks. However, the subject still lags far behind chemical petrology and we need many more studies. CSD methodology has advanced considerably, both for 3D and 2D methods, but it is unfortunate that some 2D studies still do not use appropriate stereological conversions or publish their raw data. The nature of the lower size limit is very important, real or measurement artefact, but is not commonly stated. All this is especially important for comparing data with earlier studies. Individual CSDs of minerals are not always very informative. A much better approach is to look at suites of related CSDs. For instance, different minerals within a single sample, ensembles of related whole rock samples, comparison of late and early textures as preserved in oikocrysts, dykes or volcanic rocks. As more data become available it will be possible to compare usefully unrelated suites of rocks. Straight or nearly straight CSDs in volcanic rocks can be produced by steady-state crystallisation. If the growth rate is known then the residence time can be determined. In some rocks there is a good agreement with other chronometric techniques, but others show no such concordance. In the latter case another model may be more appropriate, such as textural coarsening. This model has been applied in some cases in inappropriate situations, which has cast doubt on the whole subject of CSDs. For plutonic rocks exponentially increasing undercooling can also produce straight CSDs. However, many CSDs are slightly curved and other models are possible, especially if no small crystals are present. Within ensembles of straight CSDs the slope and intercept are commonly correlated. This is mostly accounted for by closure and hence this correlation is not significant, although the variation

  5. The Effect of Grain Size on the Radiation Response of Silicon Carbide and its Dependence on Irradiation Species and Temperature

    Science.gov (United States)

    Jamison, Laura

    In recent years the push for green energy sources has intensified, and as part of that effort accident tolerant and more efficient nuclear reactors have been designed. These reactors demand exceptional material performance, as they call for higher temperatures and doses. Silicon carbide (SiC) is a strong candidate material for many of these designs due to its low neutron cross-section, chemical stability, and high temperature resistance. The possibility of improving the radiation resistance of SiC by reducing the grain size (thus increasing the sink density) is explored in this work. In-situ electron irradiation and Kr ion irradiation was utilized to explore the radiation resistance of nanocrystalline SiC (nc-SiC), SiC nanopowders, and microcrystalline SiC. Electron irradiation simplifies the experimental results, as only isolated Frenkel pairs are produced so any observed differences are simply due to point defect interactions with the original microstructure. Kr ion irradiation simulates neutron damage, as large radiation cascades with a high concentration of point defects are produced. Kr irradiation studies found that radiation resistance decreased with particle size reduction and grain refinement (comparing nc-SiC and microcrystalline SiC). This suggests that an interface-dependent amorphization mechanism is active in SiC, suggested to be interstitial starvation. However, under electron irradiation it was found that nc-SiC had improved radiation resistance compared to single crystal SiC. This was found to be due to several factors including increased sink density and strength and the presence of stacking faults. The stacking faults were found to improve radiation response by lowering critical energy barriers. The change in radiation response between the electron and Kr ion irradiations is hypothesized to be due to either the change in ion type (potential change in amorphization mechanism) or a change in temperature (at the higher temperatures of the Kr ion

  6. Optically stimulated luminescence dating as a tool for calculating sedimentation rates in Chinese loess: comparisons with grain-size records

    DEFF Research Database (Denmark)

    Stevens, Thomas; Lu, HY

    2009-01-01

    over the late Pleistocene and Holocene. The results demonstrate that sedimentation rates are site specific, extremely variable over millennial timescales and that this variation is often not reflected in grain-size changes. In the central part of the Loess Plateau, the relationship between grain...

  7. Disk Radii and Grain Sizes in Herschel-Resolved Debris Disks

    CERN Document Server

    Pawellek, Nicole; Marshall, Jonathan P; Montesinos, Benjamin; Ábrahám, Péter; Moór, Attila; Bryden, Geoffrey; Eiroa, Carlos

    2014-01-01

    (Abridged) The radii of debris disks and the sizes of their dust grains are tracers of the formation mechanisms and physical processes operating in these systems. We use a sample of 34 debris disks spatially resolved in various Herschel programs to constrain them. While we modeled disks with both warm and cold components, we focus our analysis only on the cold outer disks, i.e. Kuiper-belt analogs. The disk radii derived from the resolved images reveal a large dispersion, but no significant trend with the stellar luminosity, which argues against ice lines as a dominant player in setting the debris disk sizes. Fixing the disk radii to those inferred from the resolved images, we model the spectral energy distributions to determine the dust temperatures and the grain size distributions. While the dust temperature systematically increases towards earlier spectral types, its ratio to the blackbody temperature at the disk radius decreases with the stellar luminosity. This is explained by an increase of typical grai...

  8. Flow rate of polygonal grains through a bottleneck: Interplay between shape and size

    Directory of Open Access Journals (Sweden)

    Ezequiel Goldberg

    2015-11-01

    Full Text Available We report two-dimensional simulations of circular and polygonal grains passing through an aperture at the bottom of a silo. The mass flow rate for regular polygons is lower than for disks\\red{,} as observed by other authors. We show that both the exit velocity of the grains and the packing fraction are lower for polygons, which leads to the reduced flow rate. We point out the importance of the criteria used to define when two objects of different shape are considered to be of the same size. Depending on this criteria, the mass flow rate may vary significantly for some polygons. Moreover, the particle flow rate is non-trivially related to a combination of mass flow rate, particle shape and particle size. For some polygons, the particle flow rate may be lower or higher than that of the corresponding disks depending on the size comparison criteria. Received: 18 May 2015, Accepted: 30 October 2015; Edited by: F. Melo; Reviewed by: J.-N. Roux, Universite Parsi Est, Laboratoire Navier, Champs-sur-Marne, France; DOI: http://dx.doi.org/10.4279/PIP.070016 Cite as: E Goldberg, C M Carlevaro, L A Pugnaloni, Papers in Physics 7, 070016 (2015

  9. Grain size trends reveal alluvial fan sensitivity to late Pleistocene climate change

    Science.gov (United States)

    Whittaker, A. C.; D'Arcy, M. K.; Roda Boluda, D. C.

    2015-12-01

    The effects of climate change on eroding landscapes and the sedimentary record remain poorly understood. The measurement of grain size fining rates in stream-flow dominated deposits provides one way to address this issue because, in principle, these trends embed important information about the dynamics of sediment routing systems and their sensitivities to external forcing. At a fundamental level, downstream fining is often driven by selective deposition of sediment. The relative efficiency of this process is determined by the physical characteristics of the input sediment supply and the spatial distribution of subsidence rate, which generates the accommodation necessary for mass extraction. Here, we measure grain size fining rates from apex to toe on two alluvial fan systems in northern Death Valley, California, which have well-exposed modern and 70 ka surfaces, where the long-term tectonic boundary conditions are known and where climatic variation over this time period is well-constrained. We integrate a self-similar gravel fraction fining model, based on selective sediment extraction, with cosmogenically-derived catchment erosion rates and gravel fining data, to estimate the change in sediment flux that occurred between 70 ka and the present day. Our results show that a 30 % decrease in average precipitation rate led to a 20 % decrease in sediment flux and a clear increase in the down-fan rate of fining. This supports existing landscape evolution models that relate a decrease in precipitation rate to a decrease in sediment flux, but implies that this relationship may be sub-linear. This study offers a new approach to applying grain size fining models to mountain catchments and their alluvial fan systems, and shows fan stratigraphy can be highly sensitive to climate changes over sensitivity is lost when sediment is remobilised and recycled over a time period longer than the duration of the climatic perturbation.

  10. The referential grain size and effective porosity in the Kozeny-Carman model

    Science.gov (United States)

    Urumović, Kosta; Urumović, Kosta, Sr.

    2016-05-01

    In this paper, the results of permeability and specific surface area analyses as functions of granulometric composition of various sediments (from silty clays to very well graded gravels) are presented. The effective porosity and the referential grain size are presented as fundamental granulometric parameters expressing an effect of the forces operating on fluid movement through the saturated porous media. This paper suggests procedures for calculating referential grain size and determining effective (flow) porosity, which result in parameters that reliably determine the specific surface area and permeability. These procedures ensure the successful application of the Kozeny-Carman model up to the limits of validity of Darcy's law. The value of effective porosity in the referential mean grain size function was calibrated within the range of 1.5 µm to 6.0 mm. The reliability of the parameters applied in the KC model was confirmed by a very high correlation between the predicted and tested hydraulic conductivity values (R2 = 0.99 for sandy and gravelly materials; R2 = 0.70 for clayey-silty materials). The group representation of hydraulic conductivity (ranging from 10-12 m s-1 up to 10-2 m s-1) presents a coefficient of correlation of R2 = 0.97 for a total of 175 samples of various deposits. These results present new developments in the research of the effective porosity, the permeability and the specific surface area distributions of porous materials. This is important because these three parameters are critical conditions for successful groundwater flow modeling and contaminant transport. Additionally, from a practical viewpoint, it is very important to identify these parameters swiftly and very accurately.

  11. An investigation of the effect of grain size on some properties of intrinsic Josephson junction

    Energy Technology Data Exchange (ETDEWEB)

    Aslan Çataltepe, Özden, E-mail: ozdenaslan@yahoo.com [Gedik University, Faculty of Engineering, Yakacık/Kartal, 34876, İstanbul (Turkey); Güven Özdemir, Zeynep [Yıldız Technical University, Physics Department, Faculty of Science and Arts, Davutpaşa Campus, Esenler 34210, İstanbul (Turkey); Onbaşli, Ülker [University of Marmara, Physics Department, Faculty of Science and Arts, Rıdvanpaşa cad.3.sok., 85/12, 34730, Göztepe, İstanbul (Turkey)

    2013-08-15

    Highlights: ► Grain size, t, determined by SEM, has a key role for intrinsic Josephson Junctions. ► Supercurrent density and Josephson penetration depth are changed with variation of t. ► HgBa{sub 2}Ca{sub 2}Cu{sub 3}O{sub 8+x} (Hg-1223) consists of intrinsic Josephson junction array. ► The effect of t on electrodynamics parameters of Hg-1223 was investigated by SEM. -- Abstract: Some superconducting parameters of the high temperature superconductors, such as the plasma frequency and the critical transition temperature, depend on the oxygen content of the material. Since the oxygen content is effective on the grain size of the system, the under, optimally and over oxygen doped Hg-based copper oxide layered superconductors, which have the hole type superconductivity, have been investigated in this study. As is known that the concentration of hole type carriers is increased via optimally oxygen annealing. In other words, relatively higher values for the various critical parameters are achieved by the optimally oxygen doping procedure. In this work, the grain sizes of the oxygen annealed samples have been investigated by Scanning Electron Microscopy (SEM). Moreover, the magnetization data obtained via Superconducting Interference Quantum Device (SQUID) has been utilized for calculation of critical current density, which is essential parameter for determining Josephson penetration depth. The Josephson penetration depths of the systems have been calculated by Lawrence–Doniach Model for high temperature superconductors. Since plasma frequency of the system is inversely proportional to Josephson penetration depth, the plasma frequencies of the various doping profiles have also been calculated for the high temperature superconductor investigated.

  12. [Effectiveness of arsenite adsorption by ferric and alum water treatment residuals with different grain sizes].

    Science.gov (United States)

    Lin, Lu; Xu, Jia-Rui; Wu, Hao; Wang, Chang-Hui; Pei, Yuan-Sheng

    2013-07-01

    Effectiveness of arsenite adsorption by ferric and alum water treatment residuals (FARs) with different grain sizes was studied. The results indicated that the content of active Fe and Al, the specific surface area and pore volume in FARs with different grain sizes were in the range of 523.72-1 861.72 mmol x kg(-1), 28.15-265.59 m2 x g(-1) and 0.03-0.09 cm3 x g(-1), respectively. The contents of organic matter, fulvic acid, humic acid and humin were in the range of 46.97-91.58 mg x kg(-1), 0.02-32.27 mg x kg(-1), 22.27-34.09 mg x kg(-1) and 10.76-34.22 mg x kg(-1), respectively. Results of SEM and XRD analysis further demonstrated that FARs with different grain sizes were amorphousness. Batch experiments suggested that both the pseudo-first-order and pseudo-second-order equations could well describe the kinetics adsorption processes of arsenite by FARs. Moreover, the contents of arsenite absorbed by FARs increased with the increase of arsenite concentrations. The theoretical saturated adsorption capacities calculated from Langmuir isotherm model were in the range of 6.72-21.79 mg x g(-1). Interestingly, pH showed little effect on the arsenite adsorption capability of FARs. The capability of FARs had a close relationship with their physicochemical properties. Correlation analysis showed that the active Fe and Al contents and pore volume had major effects on the arsenite adsorption capability of FARs.

  13. Sediment transport modelling based on grain size trend analysis in Augusta Harbour (Sicily)

    Science.gov (United States)

    Barbera, Giuseppe; Feo, Roberto; Freni, Gabriele

    2015-12-01

    To support marine civil engineer in pollutant studies, sediment management or dredging operations, is useful to know how the sediments move in accumulation basin. This paper investigates the dynamic of the sediment path using a two-dimensional numeric model: the Grain Size Trend Analysis (GSTA). The GSTA was applied using GiSedTrend plugin, under GIS software. The case study is the Augusta Harbour, which is one of the most polluted Italian harbours. It is the marine part of the Site of National Interest (SNI) of Priolo Gargallo (Siracusa, Italy) and it can be hydrodynamically considered as a lagoon. Two scenarios were obtained by using different geostatistical criteria.

  14. Effects of grain size on landscape patterns in mineral resource zones:a case study of Wu’an, China

    Institute of Scientific and Technical Information of China (English)

    Jianjun Zhang; Yongheng Rao; Yang Xu; Meichen Fu

    2014-01-01

    A mineral resource zone, rich in resources and energy, is intensively developed and disturbed by human activities, which causes an obvious change of landscapes. Taking Wu’an of Hebei Province, China, as a case study, this paper extracts landscape information of mineral resource zones through overlapping mineral resources distribution map and landscape pattern map. And then, various landscape indices are selected for analyzing the effects of grain size (30, 60, 90, 120, 150, 180, 210, 240, 270 and 300 m) on landscape patterns. Due to different kinds of landscape information transmitted by indices, the changing trends vary with the increase of grain sizes. Accordingly the landscape indices are classified into three types of effects:disturbance, continuity and sustainability, and each type of effect has its own optimal range for grain sizes. Then the optimal range of grain size on landscape patterns in mineral resource zones is gained through a comparison of the effects in various grain sizes of landscape indices. The best first domain of scale covers 30–90 m, with a suitable grain size of 30–60 m before intensive mining and a suitable grain size of 60–90 m after intensive mining. Besides, the suitable grain sizes for reflecting disturbance, continuity and sustainability before intensive mining are 30–60, 30–60 and 30–90 m, respectively, however, the sizes are changed to 60–90, 60–90 and 30–90 m, respectively, after intensive mining. The results are helpful for rational land use and optimal landscape allocation.

  15. Size of Defect Clusters in Lithium Niobate Single Crystals

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    On the basis of the Li-site vacancy model, the non-stoichiometric defects in LN crystals, i.e., anti-site defects NbLi and corresponding lithium vacancy defects VLi, were investigated by the bond valence model. According to the valence sum rule, 4 VLi sites must emerge in the nearest lattices of NbLi, and thus form a neutral cluster with the center, NbLi(VLi)4Nb5O15. The bond graph of the defect cluster was given, which reveals the ideal chemical bonding characteristics of defect clusters. Combining the possible configuration of defect clusters and the ideal bond lengths in the bond graph, the size of defect clusters in the LN crystallographic frame is estimated as 0.9~1.2 nm in diameter.

  16. Photoevaporation and spatial variation of grain sizes in Orion 114-426

    CERN Document Server

    Miotello, Anna; Potenza, Marco A C; Ricci, Luca

    2012-01-01

    Deep HST broad-band images taken with ACS and WFPC2 of the giant ($\\sim 1000$ AU diameter) dark silhouette proplyd 114-426 in the Orion Nebula show that this system is tilted, asymmetric, warped and photoevaporated. The exquisite angular resolution of ACS allows us to map the distribution of dust grains at the northern translucent edge of the disk, dominated by the photoevaporative flow. Using the Mie theory for standard circumstellar disk grains, we find evidence for a spatial gradient in grain size. The typical dust radius, $\\simeq 0.2-0.7 \\mu$m (less than what reported by previous studies) becomes smaller as the distance from the disk center increases, consistent with the expectations for the dynamic of dust entrained in a gaseous photoevaporative wind. Our analysis of the disk morphology and location within the nebula indicates that this system is photoevaporated by the diffuse radiation field of the Orion Nebula, while being shielded from the radiation coming directly from the central Trapezium stars. We...

  17. Grain size refinement in nanocrystalline Hitperm-type glass-coated microwires

    Energy Technology Data Exchange (ETDEWEB)

    Talaat, A. [Departamento de Física de Materiales, UPV/EHU, 20018 San Sebastián (Spain); Departamento de Física Aplicada, EUPDS, UPV/EHU, 20018 San Sebastián (Spain); Val, J.J. del [Departamento de Física de Materiales, UPV/EHU, 20018 San Sebastián (Spain); Zhukova, V. [Departamento de Física de Materiales, UPV/EHU, 20018 San Sebastián (Spain); Departamento de Física Aplicada, EUPDS, UPV/EHU, 20018 San Sebastián (Spain); Ipatov, M. [Departamento de Física de Materiales, UPV/EHU, 20018 San Sebastián (Spain); Klein, P.; Varga, R. [Institute of Physics, Faculty of Science, University of Pavol Jozef Safarik, Park Angelinum 9, 04154 Kosice (Slovakia); González, J. [Departamento de Física de Materiales, UPV/EHU, 20018 San Sebastián (Spain); Churyukanova, M. [National University of Science and Technology “MISIS”, Moscow 119049 (Russian Federation); Zhukov, A., E-mail: arkadi.joukov@ehu.es [Departamento de Física de Materiales, UPV/EHU, 20018 San Sebastián (Spain); Departamento de Física Aplicada, EUPDS, UPV/EHU, 20018 San Sebastián (Spain); IKERBASQUE, Basque Foundation for Science, 48011 Bilbao (Spain)

    2016-05-15

    We present a new-Fe{sub 38.5}Co{sub 38.5}B{sub 18}Mo{sub 4}Cu{sub 1} Hitperm glass-coated microwires obtained by Taylor-Ulitovsky technique with nanocrystalline structure consisting of about 23 nm of BCC α-FeCo and an amorphous precursors in as-prepared samples. Annealing resulted in a considerable decrease of such nano-grains down to (11 nm). Obtained results are discussed in terms of the stress diffusion of limited crystalline growth and the chemical composition. Rectangular hysteresis loops have been observed on all annealed samples that are necessary conditions to obtain fast domain wall propagation. An enhancement of the domain wall velocity as well as mobility after annealing has been obtained due to the structural relaxation of such grains with positive magnetostriction. These structure benefits found in the nanocrystalline Hitperm glass-coated microwires are promising for developing optimal magnetic properties. - Highlights: • Grains size refinement upon annealing. • Enhancement of the domain wall velocity as well as mobility after annealing. • Nanocrystalline structure in as-prepared microwires.

  18. Grain Size Effect of Commercial Pure Titanium Foils on Mechanical Properties, Fracture Behaviors and Constitutive Models

    Science.gov (United States)

    Daming, Nie; Zhen, Lu; Kaifeng, Zhang

    2017-02-01

    The constitutive models based on grain size effect are crucial for analyzing the deformation of metal foils. Previous investigations on the constitutive models concentrate on the foils whose thickness/average grain diameter (T/D) ratios are more than 3. In this study, the commercial pure titanium foils with thickness of 0.1 and 0.2 mm were employed as the experimental materials. The mechanical properties of foils with dimensions of nine different T/D ratios categorized into three ranges (T/D mechanisms of the samples with different T/D ratios were compared and analyzed. Besides, three constitutive models incorporating the surface layer effect and grain boundary strengthening effect were established for the three T/D ratio ranges correspondingly. In these models, the thickness of the surface layers is set T for T/D 3, and increases with D linearly in 1 ≤ T/D < 3. The results calculated by the three models were compared. The experiments indicate that those models are all in good agreement.

  19. Relationship between grain size and fracture toughness in transition region of Mn-Mo-Ni low-alloy steels

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sang Ho; Lee, Sung Hak [Pohang Univ. of Science and Technology, Pohang (Korea, Republic of); Oh, Yong Jun [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2002-03-01

    The present study aims at interpreting the effect of grain size on fracture toughness in the transition region of Mn-Mo-Ni low-alloy steels. Three kinds of steels with different austenite grain sizes were fabricated, and their microstructures and mechanical properties were examined. Elastic-plastic cleavage fracture toughness, K{sub Jc}, was determined by 3-point bend tests of precracked Charpy V-notch (PCVN) specimens according to ASTM E1921 standard test method. When the austenite grain size decreased, the total number of carbides increased, while the size and the aspect ratio of carbides decreased. Local fracture stresses, estimated from a theoretical stress distribution in front of a crack tip, were found to be mainly determined by the 92%th size of carbides. Cross-sectional areas beneath fracture surfaces were observed to understand microstructural features to affect the cleavage crack propagation behavior. The results showed that measured cleavage fracture units were smaller than austenite grain sizes, indicating that packet boundaries as well as austenite grain boundaries played an important role in the cleavage crack propagation. Based on the electron back-scatter diffraction (EBSD) results, the cleavage fracture units could also be matched with the effective grain sizes determined by the misorientation tolerance angle of 25 degree.

  20. Multiple Hadean crystallization and reworking events preserved in individual Jack Hills zircon grains

    Science.gov (United States)

    Bellucci, Jeremy; Nemchin, Alexander; Whitehouse, Martin; Snape, Joshua

    2017-04-01

    Five Hadean (>3.9 Ga) aged zircon grains from the Jack Hills metasedimentary belt have been investigated by an improved secondary ion mass spectrometry scanning ion image technique. This technique has the ability to obtain accurate and precise full U-Pb systematics on a scale document the spatial distribution of U, Th and Pb. All five of the grains investigated here have complex cathodoluminescence patterns that correlate to different U, Th, and Pb concentration domains. The age determinations for these different chemical zones indicate multiple reworking events that are preserved in each grain and have affected the primary crystalized zircon on the scale of <10 μm, smaller than traditional ion microprobe spot analyses. These new scanning ion images and age determinations suggest that roughly half, if not all, previous analyses, including those of trace elements and various isotope systems, could have intersected several domains of unfractured zircon, thus making the interpretation of any trace element, Hf, or O isotopic data tenuous. Lastly, all of the grains analyzed here preserve at least two distinguishable 207Pb/206Pb ages. These ages are preserved in core-rim and/or complex internal textural relationships. These secondary events took place during at ca. 4.3, 4.2, 4.1, 4.0, and 3.7 Ga potentially indicating a sequence of magmatic and/or metamorphic events that recycled some volume of early crust during the Hadean and into Paleo- to Mesoarchean several times with an apparent periodicity of ca. 100 Ma.

  1. Grain Size Biasing of 230Th-derived Focusing Factors in the Panama Basin

    Science.gov (United States)

    Loveley, M. R.; Marcantonio, F.; Lyle, M. W.; Ibrahim, R.; Wang, J. K.; Hertzberg, J. E.

    2014-12-01

    In this study, we attempt to understand how differing grain size classes in Panama Basin sediments may create biasing of 230Th as a constant-flux proxy. Greater amounts of 230Th are contained in fine grained particles, which, if fractionated from coarser grained counterparts may lead to biasing of 230Th-derived mass accumulation rates (MARs) and sediment focusing factors. We examined sediments that span the past 25 kyr from four new sediment cores retrieved from two different localities close to the ridges that bound the Panama Basin. Each locality contained paired sites that were seismically interpreted to have undergone sediment redistribution, i.e., thick focused sites versus thin winnowed sites. Two sediment cores were retrieved from the northern part of the Panama basin, Cocos Ridge, (MV1014-01-"4JC", 5° 44.7'N 85° 45.5' W, 1730 m depth; MV1014-01-"8JC", 6° 14.0'N 86° 2.6' W, 1993 m depth), and two were retrieved from the southern part of the basin, Carnegie Ridge, (MV1014-02-"11JC", 0° 41.6'S 85° 20.0' W, 2452 m depth; MV1014-02-"17JC" 0° 10.8'S 85° 52.0' W, 2846 m depth). Cores 4JC and 11JC lie closer to the ridge tops of the Cocos and Carnegie Ridges, respectively, and have thin sediment drapes, while deeper cores, 8JC (Cocos) and 17JC (Carnegie), have thicker sediment drapes and lie downslope from the ridge top cores. Age-model-derived sand MARs, which likely represent the vertical rain of particles that cannot be transported by bottom currents, are similar at each of the paired sites in Holocene and glacial time slices. However, 230Th-normalized MARs are about 50% lower, on average at each of the paired sites during the same time slices. Both Holocene and glacial samples from "thin" cores (4,11JC) contain, surprisingly, significant amounts (up to 50%) of the 230Th within the coarse grained (>63 μm) fraction which makes up 40-70% of the bulk samples analyzed. On the contrary, Holocene and glacial samples from "thick" cores, (8,17JC), contain the

  2. Oxygen isotopic composition of micrometer-sized quartz grains in EPICA-Dome C ice core

    Science.gov (United States)

    Delmonte, B.; Hoppe, P.; Hellebrand, E.; Huth, J.; Petit, J.; Maggi, V.

    2006-12-01

    Depicting the geographic provenance of aeolian dust reaching the interior of the East Antarctic plateau is of primary importance for a thorough underst94anding of paleo-atmospheric circulation patterns. A geochemical approach based on the 87Sr/86Sr versus 143Nd/144Nd isotopic signature of mineral particles extracted from Antarctic ice cores and comparison with samples from the Potential Source Areas (PSA) of the Southern Hemisphere has been classically used. This allowed pointing out a dominant Southern South American provenance for dust in the EPICA-Dome C and Vostok ice cores during late Quaternary glacial stages. However, the Sr-Nd isotopic fields from other potential source regions did show a partial overlap with the South American and glacial dust fields, and complementary arguments had to be invoked to infer that their possible contribution is negligible. In this study, we propose a new approach for dust fingerprinting based on the 18O/16O ratios of micrometer- sized quartz grains (1 to 2 μm in size) entrapped in Antarctic ice. Micrometric quartz grains were first identified through SEM/EDX in a sample from the EPICA-Dome C ice core dating back the last glacial maximum. O-isotopic measurements on 25 single grains were performed with the NanoSIMS ion microprobe at the Max-Plank-Institute for Chemistry in Mainz. 18OSMOW values are between 2 and 43 per mil; however most 18OSMOW values fall within a gaussian distribution with a mean 18OSMOW of 25.5 per mil and standard deviation of 2.6 per mil (1^3). These results suggest that a significant contribution from Australian and New Zealand sources seems very unlikely during glacial stage 2, but unfortunately 18OSMOW values for small quartz grains from the Southern Hemisphere PSAs are very scarce. NanoSIMS O-isotopic measurements on Aeolian quartz grains entrapped in Antarctic ice by is a promising tool for investigating the geographic provenance of mineral dust in Quaternary times.

  3. Surface-sediment grain-size data from the mouth of the Columbia River, Oregon and Washington, 2013

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This portion of the USGS data release presents sediment grain-size data from samples collected from the mouth of the Columbia River, Oregon and Washington, in 2013....

  4. Effects of grain size and humidity on fretting wear in fine-grained alumina, Al{sub 2}O{sub 3}/TiC, and zirconia

    Energy Technology Data Exchange (ETDEWEB)

    Krell, A. [Fraunhofer Inst. for Ceramic Technologies and Sintered Materials, Dresden (Germany); Klaffke, D. [Federal Inst. for Materials Research and Testing, Berlin (Germany)

    1996-05-01

    Friction and wear of sintered alumina with grain sizes between 0.4 and 3 {micro}m were measured in comparison with Al{sub 2}O{sub 3}/TiC composites and with tetragonal ZrO{sub 2} (3 mol% Y{sub 2}O{sub 3}). The dependence on the grain boundary toughness and residual microstresses is investigated, and a hierarchical order of influencing parameters is observed. In air, reduced alumina grain sizes improve the micromechanical stability of the grain boundaries and the hardness, and reduced wear is governed by microplastic deformation, with few pullout events. Humidity and water slightly reduce the friction of all of the investigated ceramics. In water, this effect reduces the wear of coarser alumina microstructures. The wear of aluminas and of the Al{sub 2}O{sub 3}/TiC composite is similar; it is lower than observed in zirconia, where extended surface cracking occurs at grain sizes as small as 0.3 {micro}m.

  5. Probing the Physical Conditions of Supernova Ejecta with the Measured Sizes of Presolar Al2O3 Grains

    OpenAIRE

    2015-01-01

    A few particles of presolar Al2O3 grains with sizes above 0.5 mum are believed to have been produced in the ejecta of core-collapse supernovae (SNe). In order to clarify the formation condition of such large Al2O3 grains, we investigate the condensation of Al2O3 grains for wide ranges of the gas density and cooling rate. We first show that the average radius and condensation efficiency of newly formed Al2O3 grains are successfully described by a non-dimensional quantity "Lambda_on" defined as...

  6. Importance of suspended sediment (SPS) composition and grain size in the bioavailability of SPS-associated pyrene to Daphnia magna.

    Science.gov (United States)

    Xia, Xinghui; Zhang, Xiaotian; Zhou, Dong; Bao, Yimeng; Li, Husheng; Zhai, Yawei

    2016-07-01

    Hydrophobic organic compounds (HOCs) tend to associate with suspended sediment (SPS) in aquatic environments; the composition and grain size of SPS will affect the bioavailability of SPS-associated HOCs. However, the bioavailability of HOCs sorbed on SPS with different compositions and grain sizes is not well understood. In this work, passive dosing devices were made to control the freely dissolved concentration of pyrene, a typical HOC, in the exposure systems. The effect of pyrene associated with amorphous organic carbon (AOC), black carbon (BC), and minerals of SPS with grain sizes of 0-50 μm and 50-100 μm on the immobilization and enzymatic activities of Daphnia magna was investigated to quantify the bioavailability of pyrene sorbed on SPS with different grain sizes and compositions. The results showed that the contribution of AOC-, BC-, and mineral-associated pyrene to the total bioavailability of SPS-associated pyrene was approximately 50%-60%, 10%-29%, and 20%-30%, respectively. The bioavailable fraction of pyrene sorbed on the three components of SPS was ordered as AOC (22.4%-67.3%) > minerals (20.1%-46.0%) > BC (9.11%-16.8%), and the bioavailable fraction sorbed on SPS of 50-100 μm grain size was higher than those of 0-50 μm grain size. This is because the SPS grain size will affect the ingestion of SPS and the SPS composition will affect the desorption of SPS-associated pyrene in Daphnia magna. According to the results obtained in this study, a model has been developed to calculate the bioavailability of HOCs to aquatic organisms in natural waters considering both SPS grain size and composition.

  7. Characterizing 3D grain size distributions from 2D sections in mylonites using a modified version of the Saltykov method

    Science.gov (United States)

    Lopez-Sanchez, Marco; Llana-Fúnez, Sergio

    2016-04-01

    The understanding of creep behaviour in rocks requires knowledge of 3D grain size distributions (GSD) that result from dynamic recrystallization processes during deformation. The methods to estimate directly the 3D grain size distribution -serial sectioning, synchrotron or X-ray-based tomography- are expensive, time-consuming and, in most cases and at best, challenging. This means that in practice grain size distributions are mostly derived from 2D sections. Although there are a number of methods in the literature to derive the actual 3D grain size distributions from 2D sections, the most popular in highly deformed rocks is the so-called Saltykov method. It has though two major drawbacks: the method assumes no interaction between grains, which is not true in the case of recrystallised mylonites; and uses histograms to describe distributions, which limits the quantification of the GSD. The first aim of this contribution is to test whether the interaction between grains in mylonites, i.e. random grain packing, affects significantly the GSDs estimated by the Saltykov method. We test this using the random resampling technique in a large data set (n = 12298). The full data set is built from several parallel thin sections that cut a completely dynamically recrystallized quartz aggregate in a rock sample from a Variscan shear zone in NW Spain. The results proved that the Saltykov method is reliable as long as the number of grains is large (n > 1000). Assuming that a lognormal distribution is an optimal approximation for the GSD in a completely dynamically recrystallized rock, we introduce an additional step to the Saltykov method, which allows estimating a continuous probability distribution function of the 3D grain size population. The additional step takes the midpoints of the classes obtained by the Saltykov method and fits a lognormal distribution with a trust region using a non-linear least squares algorithm. The new protocol is named the two-step method. The

  8. Influence of grain size on mechanical properties of isostatically pressed beryllium materials

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Six kinds of beryllium powders with different particle sizes (4 ~ 15 μm) and low oxygen prepared by impactgrinding were compacted and consolidated by cold-hot isostatic pressing (CIP-HIP). The tensile strength, yield strength,elongation and micro-yield strength(MYS) of the materials were tested and it showed that the strength of the materials,especially the yield strength and micro yield strength(MYS) increase obviously with the refinement of grain size. From theXRD and TEM, the second phase is BeO which is finely dispersed in matrix. This is considered to be the main strength-ening mechanism for CIP-HIPed beryllium materials with higher purity

  9. Optimizing the crystal size and habit of beta-sitosterol in suspension

    DEFF Research Database (Denmark)

    von Bonsdorff-Nikander, Anna; Rantanen, Jukka; Christiansen, Leena

    2003-01-01

    The aim of this work was to survey how processing parameters affect the crystal growth of beta-sitosterol in suspension. The process variables studied were the cooling temperature, stirring time and stirring rate during recrystallization. In addition, we investigated the effect a commonly used...... surfactant, polysorbate 80, has on crystal size distribution and the polymorphic form. This study describes the optimization of the crystallization process, with the object of preparing crystals as small as possible. Particle size distribution and habit were analyzed using optical microscopy, and the crystal...... structure was analyzed using X-ray diffractometry. The cooling temperature had a remarkable influence on the crystal size. Crystals with a median crystal length of approximately 23 microm were achieved with a low cooling temperature (crystals over 50 microm...

  10. THE EFFECT OF GRAIN SIZE ANALYSIS FOR POSTFLOTATION SEDIMENTS ON ASSESSMENT OF THEIR APPLICABILITY IN EARTH STRUCTURE CONSTRUCTION

    Directory of Open Access Journals (Sweden)

    Magdalena Walczak

    2016-02-01

    Full Text Available This paper presents the comparison of the results of laboratory tests of postflotation sediments grain size distributions, originating from the copper ore flotation process. The paper also presents the results of statistical analysis conducted on grain size parameters. Statistically significant differences were shown in the assessment of grain size distribution, which result from the selection of the research procedure. A comparison of results recorded for wet and dry sieving methods was conducted within a group of the same samples of postflotation deposits. The selection of an appropriate research method and procedure should also be preceded by a thorough analysis and preliminary determination of the soil medium. A correctly determined grain size distribution is essential for its further classification and then, through grain size criteria, for the assessment of suitability of the analysed material in earth structure construction. This problem is of even greater importance in the case of anthropogenic soils, which are used to construct dams or seal hydroengineering structures. In practical terms knowledge on the limitations resulting from the application of a given method prevents erroneous conclusions on research results. This problem may be perfectly illustrated based on the selection of a method assessing parameters and soil grain size distributions.

  11. Experimental Investigation and Numerical Simulation of the Grain Size Evolution during Isothermal Forging of a TC6 Alloy

    Institute of Scientific and Technical Information of China (English)

    Miaoquan LI; Shankun XUE; Aiming XIONG; Shenghui CHEN

    2005-01-01

    Hot compression was conducted at a Thermecmaster-Z simulator, at deformation temperatures of 800~1040℃, with strain rates of 0.001~50 s-1 and height reduction of 50%. Grain size of the prior α phase was measured with a Leica LABOR-LUX12MFS/ST microscope to which QUANTIMET 500 software for image analysis for quantitative metallography was linked. According to the present experimental data, a constitutive relationship for a TC6 alloy and a model for grain size of the prior α phase were established based on the Arrhenius' equation and the Yada's equation,respectively. By finite element (FE) simulation, deformation distribution was determined for isothermal forging of a TC6 aerofoil blade at temperatures of 860~940℃ and hammer velocities of 9~3000.0 mm/min. Meanwhile, the grain size of the prior α phase is simulated during isothermal forging of the TC6 aerofoil blade, by combining FE outputs with the present grain size model. The present results illustrate the grain size and its distribution in the prior α phase during the isothermal forging of the TC6 aerofoil blade. The simulated results show that the height reduction, deformation temperature, and hammer velocity have significant effects on distribution of the equivalent strain and the grain size of the prior α phase.

  12. Grain-size features of a Miocene loess-soil sequence at Qinan: Implications on its origin

    Institute of Scientific and Technical Information of China (English)

    QIAO Yansong; GUO Zhengtang; HAO Qingzhen; YIN Qiuzhen; YUAN Baoyin; LIU Tungsheng

    2006-01-01

    In this study, grain-size of 507 bulk samples from the QA-I Miocene loess-soil sequenceat Qinan were analyzed, and the grain-size features are compared with those of typical Quaternary loess and soil samples, representative lacustrine and fluvial samples. The results indicate that the grain-size distribution pattern of the Miocene loess is essentially similar to that of Quaternary loess,but greatly differs from the lacustrine and fluvial sediments. Loess layers are regularly coarser than soil layers, indicating cyclical climate changes. Median grain-size along the 253.1 m sequence varies from 6 to 13 μm and the >63 μm fraction represents only 5.3% in maximum, 0.9% in average.Long-term grain-size variations are consistent with the loess accumulation rate at Qinan and with the eolian mass accumulation rate in the North Pacific. These features firmly indicate an eolian origin of the studied sequence, and also reveal a coeval changes between the long-term changes of eolian grain-size and continental aridity in the dust source regions.

  13. Downwind changes in grain size of aeolian dust; examples from marine and terrestrial archives

    Science.gov (United States)

    Stuut, Jan-Berend; Prins, Maarten

    2013-04-01

    Aeolian dust in the atmosphere may have a cooling effect when small particles in the high atmosphere block incoming solar energy (e.g., Claquin et al., 2003) but it may also act as a 'greenhouse gas' when larger particles in the lower atmosphere trap energy that was reflected from the Earth's surface (e.g., Otto et al., 2007). Therefore, it is of vital importance to have a good understanding of the particle-size distribution of aeolian dust in space and time. As wind is a very size-selective transport mechanism, the sediments it carries typically have a very-well sorted grain-size distribution, which gradually fines from proximal to distal deposition sites. This fact has been used in numerous paleo-environmental studies to both determine source-to-sink changes in the particle size of aeolian dust (e.g., Weltje and Prins, 2003; Holz et al., 2004; Prins and Vriend, 2007) and to quantify mass-accumulation rates of aeolian dust (e.g., Prins and Weltje 1999; Stuut et al., 2002; Prins et al., 2007; Prins and Vriend, 2007; Stuut et al., 2007; Tjallingii et al., 2008; Prins et al., 2009). Studies on modern wind-blown particles have demonstrated that particle size of dust not only is a function of lateral but also vertical transport distance (e.g., Torres-Padron et al., 2002; Stuut et al., 2005). Nonetheless, there are still many unresolved questions related to the physical properties of wind-blown particles like e.g., the case of "giant" quartz particles found on Hawaii (Betzer et al., 1988) that can only originate from Asia but have a too large size for the distance they travelled through the atmosphere. Here, we present examples of dust particle-size distributions from terrestrial (loess) as well as marine (deep-sea sediments) sedimentary archives and their spatial and temporal changes. With this contribution we hope to provide quantitative data for the modelling community in order to get a better grip on the role of wind-blown particles in the climate system. Cited

  14. A theoretical explanation of grain size distributions in explosive rock fragmentation

    Science.gov (United States)

    Fowler, A. C.; Scheu, Bettina

    2016-06-01

    We have measured grain size distributions of the results of laboratory decompression explosions of volcanic rock. The resulting distributions can be approximately represented by gamma distributions of weight per cent as a function of ϕ =-log2⁡d , where d is the grain size in millimetres measured by sieving, with a superimposed long tail associated with the production of fines. We provide a description of the observations based on sequential fragmentation theory, which we develop for the particular case of `self-similar' fragmentation kernels, and we show that the corresponding evolution equation for the distribution can be explicitly solved, yielding the long-time lognormal distribution associated with Kolmogorov's fragmentation theory. Particular features of the experimental data, notably time evolution, advection, truncation and fines production, are described and predicted within the constraints of a generalized, `reductive' fragmentation model, and it is shown that the gamma distribution of coarse particles is a natural consequence of an assumed uniform fragmentation kernel. We further show that an explicit model for fines production during fracturing can lead to a second gamma distribution, and that the sum of the two provides a good fit to the observed data.

  15. The Impact of Li Grain Size on Coulombic Efficiency in Li Batteries.

    Science.gov (United States)

    Mehdi, B Layla; Stevens, Andrew; Qian, Jiangfeng; Park, Chiwoo; Xu, Wu; Henderson, Wesley A; Zhang, Ji-Guang; Mueller, Karl T; Browning, Nigel D

    2016-10-05

    One of the most promising means to increase the energy density of state-of-the-art lithium Li-ion batteries is to replace the graphite anode with a Li metal anode. While the direct use of Li metal may be highly advantageous, at present its practical application is limited by issues related to dendrite growth and low Coulombic efficiency, CE. Here operando electrochemical scanning transmission electron microscopy (STEM) is used to directly image the deposition/stripping of Li at the anode-electrolyte interface in a Li-based battery. A non-aqueous electrolyte containing small amounts of H2O as an additive results in remarkably different deposition/stripping properties as compared to the "dry" electrolyte when operated under identical electrochemical conditions. The electrolyte with the additive deposits more Li during the first cycle, with the grain sizes of the Li deposits being significantly larger and more variable. The stripping of the Li upon discharge is also more complete, i.e., there is a higher cycling CE. This suggests that larger grain sizes are indicative of better performance by leading to more uniform Li deposition and an overall decrease in the formation of Li dendrites and side reactions with electrolyte components, thus potentially paving the way for the direct use of Li metal in battery technologies.

  16. Distribution Characteristics of Heavy Metals and Grain Size of Sediments from Hailing Bay, China

    Institute of Scientific and Technical Information of China (English)

    QIU Yaowen; ZHU Liangsheng; LI Manqiu

    2005-01-01

    The geochemical properties of sediment in the nearby seawater areas of Hailing Bay of the western Guangdong province were first time investigated in the dry period of 2001 and the flood period of 2002, respectively. The temporal and spatial characteristics of Cu, Pb, Zn, Cd and Hg concentrations, organic carbon and total sulfides contents, and granulometric distribution in the surface sediment from the Hailing Bay were analyzed. Results demonstrated that there were no remarkable changes in the composition of sediment between the dry period and the flood period;the average concentrations of Cu, Pb, Zn, Cd and Hg were 32.1 ± 17.5, 36.1 ± 10.0,respectively; surface sediments were dominated by clayey silt and sand, and their mean grain size was 4.62 ± 2.36 φ and in the range 0.52-7.55 φ; there existed obvious correlation between the concentrations of Cu, Pb, Zn and Hg, and among Cu, Pb, Zn and Hg concentrations, organic carbon contents and grain size of sediments.

  17. Exceptional high fatigue strength in Cu-15at.%Al alloy with moderate grain size

    Science.gov (United States)

    Liu, Rui; Tian, Yanzhong; Zhang, Zhenjun; An, Xianghai; Zhang, Peng; Zhang, Zhefeng

    2016-06-01

    It is commonly proposed that the fatigue strength can be enhanced by increasing the tensile strength, but this conclusion needs to be reconsidered according to our study. Here a recrystallized α-Cu-15at.%Al alloy with moderate grain size of 0.62 μm was fabricated by cold rolling and annealing, and this alloy achieved exceptional high fatigue strength of 280 MPa at 107 cycles. This value is much higher than the fatigue strength of 200 MPa for the nano-crystalline counterpart (0.04 μm in grain size) despite its higher tensile strength. The remarkable improvement of fatigue strength should be mainly attributed to the microstructure optimization, which helps achieve the reduction of initial damage and the dispersion of accumulated damage. A new strategy of “damage reduction” was then proposed for fatigue strength improvement, to supplement the former strengthening principle. The methods and strategies summarized in this work offer a general pathway for further improvement of fatigue strength, in order to ensure the long-term safety of structural materials.

  18. A CONCENTRATION OF CENTIMETER-SIZED GRAINS IN THE OPHIUCHUS IRS 48 DUST TRAP

    Energy Technology Data Exchange (ETDEWEB)

    Marel, N. van der; Pinilla, P.; Tobin, J.; Kempen, T. van [Leiden Observatory, P.O. Box 9513, 2300 RA Leiden (Netherlands); Andrews, S.; Ricci, L.; Birnstiel, T., E-mail: nmarel@strw.leidenuniv.nl [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States)

    2015-09-01

    Azimuthally asymmetric dust distributions observed with the Atacama Large Millimeter/submillimeter Array (ALMA) in transition disks have been interpreted as dust traps. We present Very Large Array Ka band (34 GHz or 0.9 cm) and ALMA Cycle 2 Band 9 (680 GHz or 0.45 mm) observations at a 0.″2 resolution of the Oph IRS 48 disk, which suggest that larger particles could be more azimuthally concentrated than smaller dust grains, assuming an axisymmetric temperature field or optically thin 680 GHz emission. Fitting an intensity model to both data demonstrates that the azimuthal extent of the millimeter emission is 2.3 ± 0.9 times as wide as the centimeter emission, marginally consistent with the particle trapping mechanism under the above assumptions. The 34 GHz continuum image also reveals evidence for ionized gas emission from the star. Both the morphology and the spectral index variations are consistent with an increase of large particles in the center of the trap, but uncertainties remain due to the continuum optical depth at 680 GHz. Particle trapping has been proposed in planet formation models to allow dust particles to grow beyond millimeter sizes in the outer regions of protoplanetary disks. The new observations in the Oph IRS 48 disk provide support for the dust trapping mechanism for centimeter-sized grains, although additional data are required for definitive confirmation.

  19. The Impact of Li Grain Size on Coulombic Efficiency in Li Batteries

    Science.gov (United States)

    Mehdi, B. Layla; Stevens, Andrew; Qian, Jiangfeng; Park, Chiwoo; Xu, Wu; Henderson, Wesley A.; Zhang, Ji-Guang; Mueller, Karl T.; Browning, Nigel D.

    2016-01-01

    One of the most promising means to increase the energy density of state-of-the-art lithium Li-ion batteries is to replace the graphite anode with a Li metal anode. While the direct use of Li metal may be highly advantageous, at present its practical application is limited by issues related to dendrite growth and low Coulombic efficiency, CE. Here operando electrochemical scanning transmission electron microscopy (STEM) is used to directly image the deposition/stripping of Li at the anode-electrolyte interface in a Li-based battery. A non-aqueous electrolyte containing small amounts of H2O as an additive results in remarkably different deposition/stripping properties as compared to the “dry” electrolyte when operated under identical electrochemical conditions. The electrolyte with the additive deposits more Li during the first cycle, with the grain sizes of the Li deposits being significantly larger and more variable. The stripping of the Li upon discharge is also more complete, i.e., there is a higher cycling CE. This suggests that larger grain sizes are indicative of better performance by leading to more uniform Li deposition and an overall decrease in the formation of Li dendrites and side reactions with electrolyte components, thus potentially paving the way for the direct use of Li metal in battery technologies.

  20. The Impact of Li Grain Size on Coulombic Efficiency in Li Batteries

    Energy Technology Data Exchange (ETDEWEB)

    Mehdi, B. Layla; Stevens, Andrew; Qian, Jiangfeng; Park, Chiwoo; Xu, Wu; Henderson, Wesley A.; Zhang, Ji-Guang; Mueller, Karl T.; Browning, Nigel D.

    2016-10-05

    One of the most promising means to increase the energy density of state-of-the-art lithium (Li)-ion batteries is to replace the graphite anode with a Li metal anode1, 2, 3. While the direct use of Li metal may be highly advantageous4,5, at present its practical application is limited by issues related to dendrite growth and low Coulombic efficiency (CE)6. Here operando electrochemical scanning transmission electron microscopy (STEM) is used to directly image the deposition/stripping of Li at the anode-electrolyte interface in a Li-based battery. A non-aqueous electrolyte containing small amounts of H2O as an additive results in remarkably different deposition/stripping properties as compared to the "dry" electrolyte when operated under identical electrochemical conditions. The electrolyte with the additive deposits more Li during the first cycle, with the grain sizes of the Li deposits being significantly larger and more variable. The stripping of the Li upon discharge is also more complete, i.e., there is a higher cycling CE. This suggests that larger grain sizes are indicative of better performance by leading to more uniform Li deposition and an overall decrease in the formation of Li dendrites and side reactions with electrolyte components, thus potentially paving the way for the direct use of Li metal in battery technologies.

  1. Dependence of Effective Anisotropy on Grain Size in Nanocrystalline Nd2Fe14B Hard Magnetic Material

    Institute of Scientific and Technical Information of China (English)

    Feng Weicun; Gao Ruwei; Han Guangbing; Zhu Minggang; Li Wei; Sun Guangfei

    2005-01-01

    Taking nanocrystalline Nd2Fe14B as a typical sample, based on Herzer′s random anisotropy theory and the cubic grain model, the partial exchange-coupling interaction model was established and the dependence of effective anisotropy constant Keff on grain size was investigated. Calculation results reveal that the exchange-coupling interaction enhances and the effective anisotropy of material Keff decreases with the reduction of grain size. The variation of Keff is basically the same as that of coercivity. The decrease of effective anisotropy is the main reason of the reduction of coercivity for nanocrystalline Nd2Fe14B permanent magnetic material.

  2. Measurement of grain size of polycrystalline materials with confocal energy dispersive micro-X-ray diffraction technology based on polycapillary X-ray optics

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Weiyuan; Liu, Zhiguo [The Key Laboratory of Beam Technology and Materials Modification of the Ministry of Education, Beijing Normal University, Beijing 100875 (China); College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China); Beijing Radiation Center, Beijing 100875 (China); Sun, Tianxi, E-mail: stx@bnu.edu.cn [The Key Laboratory of Beam Technology and Materials Modification of the Ministry of Education, Beijing Normal University, Beijing 100875 (China); College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China); Beijing Radiation Center, Beijing 100875 (China); Peng, Song [The Key Laboratory of Beam Technology and Materials Modification of the Ministry of Education, Beijing Normal University, Beijing 100875 (China); College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China); Beijing Radiation Center, Beijing 100875 (China); Ma, Yongzhong [Center for Disease Control and Prevention of Beijing, Beijing 100013 (China); Li, Fangzuo; Sun, Xuepeng; Ding, Xunliang [The Key Laboratory of Beam Technology and Materials Modification of the Ministry of Education, Beijing Normal University, Beijing 100875 (China); College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China); Beijing Radiation Center, Beijing 100875 (China)

    2014-11-11

    The confocal energy dispersive micro-X-ray diffraction (EDMXRD) based on polycapillary X-ray optics was used to determine the grain size of polycrystalline materials. The grain size of a metallographic specimen of nickel base alloy was measured by using the confocal EDMXRD. The experimental results demonstrated that the confocal EDMXRD had potential applications in measuring large grain size.

  3. Transient response in longitudinal grain size to reduced sediment supply in a large river

    Science.gov (United States)

    Singer, Michael

    2010-05-01

    Bed material grain size is an important degree of freedom in fluvial systems as they adjust to system-wide perturbations such as sediment supply changes. However, little is known about processes and patterns of such adjustment in longitudinal grain size sorting in large rivers. This research uses unprecedented datasets collected in a large fluvial system to investigate transient response to recent supply changes associated with anthropogenic activities. Separate fining trends for gravel and fines, a protracted gravel-sand (G-S) transition, and bed patchiness identified in Singer (2008) were interrogated using output from a hydraulic model with grain size distributions (GSDs) extracted from ~125 cross sections spanning ~400 river kilometers of the Sacramento River, California. The analysis suggests that interactions between hydraulics, bed material sorting, and sediment flux explain these previously identified anomalies. Highest values of sorting occur in the G-S transition and represent the overlap of separate fining trends for gravel and fines, where the long profile is jagged with evidence of progressive incision. Much of the sediment in this poorly sorted zone is organized into patches, where transport apparently occurs as bedload sheets. Patchiness occurs over short length scales leading to strong differences in entrainment and flux, regardless of hydraulic conditions. A modified Shields stress is proposed that is scaled by GSD sorting to improve characterization of entrainment/disentrainment. Sediment flux calculations based on an equation sensitive bed material conditions (Singer and Dunne, 2004) reveal a strong relationship between fine sediment flux and d90, suggesting that the efficiency of fine patch flux controls bed material bed surface roughness. Results are in part consistent with Paola and Seal (1995) suggesting that patches are a result of overlapping pdfs of shear stress and sorting and with Ferguson (2003) in that the final end of the protracted G

  4. Remote Analysis of Grain Size Characteristic in Submarine Pyroclastic Deposits from Kolumbo Volcano, Greece

    Science.gov (United States)

    Smart, C.; Whitesell, D. P.; Roman, C.; Carey, S.

    2011-12-01

    Grain size characteristics of pyroclastic deposits provide valuable information about source eruption energetics and depositional processes. Maximum size and sorting are often used to discriminate between fallout and sediment gravity flow processes during explosive eruptions. In the submarine environment the collection of such data in thick pyroclastic sequences is extremely challenging and potentially time consuming. A method has been developed to extract grain size information from stereo images collected by a remotely operated vehicle (ROV). In the summer of 2010 the ROV Hercules collected a suite of stereo images from a thick pumice sequence in the caldera walls of Kolumbo submarine volcano located about seven kilometers off the coast of Santorini, Greece. The highly stratified, pumice-rich deposit was likely created by the last explosive eruption of the volcano that took place in 1650 AD. Each image was taken from a distance of only a few meters from the outcrop in order to capture the outlines of individual clasts with relatively high resolution. Mosaics of individual images taken as the ROV transected approximately 150 meters of vertical outcrop were used to create large-scale vertical stratigraphic columns that proved useful for overall documentation of the eruption sequence and intracaldera correlations of distinct tephra units. Initial image processing techniques, including morphological operations, edge detection, shape and size estimation were implemented in MatLab and applied to a subset of individual images of the mosiacs. A large variety of algorithms were tested in order to best discriminate the outlines of individual pumices. This proved to be challenging owing to the close packing and overlapping of individual pumices. Preliminary success was achieved in discriminating the outlines of the large particles and measurements were carried out on the largest clasts present at different stratigraphic levels. In addition, semi-quantitative analysis of the

  5. Multiscale Crystal Plasticity Modeling Considering Nucleation of Dislocations Based on Thermal Activation Process on Ultrafine-grained Aluminum

    Science.gov (United States)

    Aoyagi, Y.

    2017-05-01

    In this study, a crystal plasticity model expressing the behavior of the dislocation source and the mobile dislocations is proposed by considering a thermal activation process of dislocations. In order to predict the variation of critical resolved shear stress due to grain boundaries, mobile dislocations, or dislocation sources, information on these crystal defects is introduced into a hardening law of crystal plasticity. The crystal orientation and shape of ultrafine-grained (UFG) aluminum produced by accumulative roll bonding processes are measured by electron backscatter diffraction (EBSD). Mechanical properties of the UFG aluminum are estimated using tensile test and indentation test. Results obtained by EBSD are introduced into a computational model. Finite element simulation for polycrystal of aluminum investigates the effect of microstructure on mechanical properties of UFG aluminum.

  6. The effect of grain size on the biocompatibility, cell-materials interface, and mechanical properties of microwave-sintered bioceramics.

    Science.gov (United States)

    Veljović, Djordje; Colić, Miodrag; Kojić, Vesna; Bogdanović, Gordana; Kojić, Zvezdana; Banjac, Andrijana; Palcevskis, Eriks; Petrović, Rada; Janaćković, Djordje

    2012-11-01

    The effect of decreasing the grain size on the biocompatibility, cell-material interface, and mechanical properties of microwave-sintered monophase hydroxyapatite bioceramics was investigated in this study. A nanosized stoichiometric hydroxyapatite powder was isostatically pressed at high pressure and sintered in a microwave furnace in order to obtain fine grained dense bioceramics. The samples sintered at 1200°C, with a density near the theoretical one, were composed of micron-sized grains, while the grain size decreased to 130 nm on decreasing the sintering temperature to 900°C. This decrease in the grain size certainly led to increases in the fracture toughness by much as 54%. An in vitro investigation of biocompatibility with L929 and human MRC-5 fibroblast cells showed noncytotoxic effects for both types of bioceramics, while the relative cell proliferation rate, cell attachment and metabolic activity of the fibroblasts were improved with decreasing of grain size. An initial in vivo investigation of biocompatibility by the primary cutaneous irritation test showed that both materials exhibited no irritation properties.

  7. Grain-Size Based Additivity Models for Scaling Multi-rate Uranyl Surface Complexation in Subsurface Sediments

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Xiaoying; Liu, Chongxuan; Hu, Bill X.; Hu, Qinhong

    2016-07-01

    This study statistically analyzed a grain-size based additivity model that has been proposed to scale reaction rates and parameters from laboratory to field. The additivity model assumed that reaction properties in a sediment including surface area, reactive site concentration, reaction rate, and extent can be predicted from field-scale grain size distribution by linearly adding reaction properties for individual grain size fractions. This study focused on the statistical analysis of the additivity model with respect to reaction rate constants using multi-rate uranyl (U(VI)) surface complexation reactions in a contaminated sediment as an example. Experimental data of rate-limited U(VI) desorption in a stirred flow-cell reactor were used to estimate the statistical properties of multi-rate parameters for individual grain size fractions. The statistical properties of the rate constants for the individual grain size fractions were then used to analyze the statistical properties of the additivity model to predict rate-limited U(VI) desorption in the composite sediment, and to evaluate the relative importance of individual grain size fractions to the overall U(VI) desorption. The result indicated that the additivity model provided a good prediction of the U(VI) desorption in the composite sediment. However, the rate constants were not directly scalable using the additivity model, and U(VI) desorption in individual grain size fractions have to be simulated in order to apply the additivity model. An approximate additivity model for directly scaling rate constants was subsequently proposed and evaluated. The result found that the approximate model provided a good prediction of the experimental results within statistical uncertainty. This study also found that a gravel size fraction (2-8mm), which is often ignored in modeling U(VI) sorption and desorption, is statistically significant to the U(VI) desorption in the sediment.

  8. Probing the Physical Conditions of Supernova Ejecta with the Measured Sizes of Presolar Al2O3 Grains

    CERN Document Server

    Nozawa, Takaya; Hasegawa, Yasuhiro; Kozasa, Takashi

    2015-01-01

    A few particles of presolar Al2O3 grains with sizes above 0.5 mum are believed to have been produced in the ejecta of core-collapse supernovae (SNe). In order to clarify the formation condition of such large Al2O3 grains, we investigate the condensation of Al2O3 grains for wide ranges of the gas density and cooling rate. We first show that the average radius and condensation efficiency of newly formed Al2O3 grains are successfully described by a non-dimensional quantity "Lambda_on" defined as the ratio of the timescale with which the supersaturation ratio increases to the collision timescale of reactant gas species at dust formation. Then, we find that the formation of submicron-sized Al2O3 grains requires at least ten times higher gas densities than those presented by one-dimensional SN models. This indicates that presolar Al2O3 grains identified as a SN origin might be formed in dense gas clumps, allowing us to propose that the measured sizes of presolar grains can be a powerful tool to constrain the physic...

  9. A comparison of grain nucleation and grain growth during crystallization of HWCVD and PECVD a-Si:H films

    NARCIS (Netherlands)

    Mahan, A.H.; Ahrenkiel, S.P.; Schropp, R.E.I.; Li, H. B. T.; Ginley, D.S.

    2008-01-01

    From TEM, XRD and Raman measurements, we compare the crystallization kinetics when HWCVD and PECVD a-Si:H films, containing different initial film hydrogen contents (CH), are crystallized by annealing at 600 °C. For the HWCVD films, the nucleation rate increases, and the incubation time and the full

  10. Acoustic Measurements of Residual Stresses and Grain Sizes in Aluminum Alloys

    Science.gov (United States)

    Fisher, Martin John

    The theory of acoustoelasticity relates the velocity of an acoustic wave in a solid to the elastic stress state in that solid. This thesis presents new theories, measurement techniques, and methodologies related to the use of longitudinal wave acoustoelasticity in aluminum alloys. A one-dimensional model has been developed to provide a simple understanding of the acoustoelastic effect. A new acoustic device for accurately measuring relative thickness variations has been designed and built. This device is used--in conjunction with a pulse-echo phase measurement device and a computer controlled scanning system--to measure acoustic velocity variations in plastically deformed and non-flat-and-parallel samples. Acoustic velocity variations from point to point in an unstressed sample can sometimes be on the same order as velocity changes due to applied or residual stresses, and this can make stress measurements difficult. A statistical theory has been developed to relate these unstressed velocity variations to the average grain size in the sample and to the active area of the acoustic transducer used. Large transducers and small grain sizes will minimize these variations. This relationship has been verified by tests on a number of aluminum alloys and a new method for non-destructive grain size determination has been suggested. A systematic methodology has been developed and tested for studying the influence of uniaxial plastic deformation on the acoustoelastic response. Samples have been plastically deformed in four-point bending to produce elastic-plastic and residual stress states. Acoustic measurements of these stresses have then been compared directly to theoretical predictions based on the materials' stress-strain curves and simple beam theory. In the aluminum alloys tested (2024-T351 and 7075-T651), the acoustoelastic constants are shown to be virtually unchanged by uniaxial plastic strains of less than 2.5%. Thus, the acoustoelastic technique can be reliably

  11. Expading fluvial remote sensing to the riverscape: Mapping depth and grain size on the Merced River, California

    Science.gov (United States)

    Richardson, Ryan T.

    This study builds upon recent research in the field of fluvial remote sensing by applying techniques for mapping physical attributes of rivers. Depth, velocity, and grain size are primary controls on the types of habitat present in fluvial ecosystems. This thesis focuses on expanding fluvial remote sensing to larger spatial extents and sub-meter resolutions, which will increase our ability to capture the spatial heterogeneity of habitat at a resolution relevant to individual salmonids and an extent relevant to species. This thesis consists of two chapters, one focusing on expanding the spatial extent over which depth can be mapped using Optimal Band Ratio Analysis (OBRA) and the other developing general relations for mapping grain size from three-dimensional topographic point clouds. The two chapters are independent but connected by the overarching goal of providing scientists and managers more useful tools for quantifying the amount and quality of salmonid habitat via remote sensing. The OBRA chapter highlights the true power of remote sensing to map depths from hyperspectral images as a central component of watershed scale analysis, while also acknowledging the great challenges involved with increasing spatial extent. The grain size mapping chapter establishes the first general relations for mapping grain size from roughness using point clouds. These relations will significantly reduce the time needed in the field by eliminating the need for independent measurements of grain size for calibrating the roughness-grain size relationship and thus making grain size mapping with SFM more cost effective for river restoration and monitoring. More data from future studies are needed to refine these relations and establish their validity and generality. In conclusion, this study adds to the rapidly growing field of fluvial remote sensing and could facilitate river research and restoration.

  12. Dense molecular cloud cores as a source of micrometer-sized grains in galaxies

    CERN Document Server

    Hirashita, Hiroyuki; Nozawa, Takaya; Li, Zhi-Yun; Liu, Ming-Chang

    2014-01-01

    Coreshine in dense molecular cloud cores (dense cores) is interpreted as evidence for micrometer-sized grains (referred to as very large grains, VLGs). VLGs may have a significant influence on the total dust amount and the extinction curve. We estimate the total abundance of VLGs in the Galaxy, assuming that dense cores are the site of VLG formation. We find that the VLG abundance relative to the total dust mass is roughly $\\phi_\\mathrm{VLG}\\sim 0.01(1-\\epsilon )/\\epsilon (\\tau_\\mathrm{SF}/5\\times 10^9~\\mathrm{yr})^{-1} (f_\\mathrm{VLG}/0.5)(t_\\mathrm{shat}/10^8~\\mathrm{yr})$, where $\\epsilon$ is the star formation efficiency in dense cores, $\\tau_\\mathrm{SF}$ the timescale of gas consumption by star formation, $f_\\mathrm{VLG}$ the fraction of dust mass eventually coagulated into VLGs in dense cores, and $t_\\mathrm{shat}$ the lifetime of VLGs (determined by shattering). Adopting their typical values for the Galaxy, we obtain $\\phi_\\mathrm{VLG}\\sim 0.02$--0.09. This abundance is well below the value detected in...

  13. Effect of current and atomized grain size distribution on the solidification of Plasma Transferred Arc coatings

    Directory of Open Access Journals (Sweden)

    Danielle Bond

    2012-10-01

    Full Text Available Plasma Transferred Arc (PTA is the only thermal spray process that results in a metallurgical bond, being frequently described as a hardfacing process. The superior properties of coatings have been related to the fine microstructures obtained, which are finer than those processed under similar heat input with welding techniques using wire feedstock. This observation suggests that the atomized feedstock plays a role on the solidification of coatings. In this study a model for the role of the powders grains in the solidification of PTA coatings is put forward and discussed. An experiment was setup to discuss the model which involved the deposition of an atomized Co-based alloy with different grain size distributions and deposition currents. X ray diffraction showed that there were no phase changes due to the processing parameters. Microstructure analysis by Laser Confocal Microscopy, dilution with the substrate steel and Vickers microhardness were used the characterized coatings and enriched the discussion confirming the role of the powdered feedstock on the solidification of coatings.

  14. Experimental investigation of suspended particles transport through porous media: particle and grain size effect.

    Science.gov (United States)

    Liu, Quansheng; Cui, Xianze; Zhang, Chengyuan; Huang, Shibing

    2016-01-01

    Particle and grain size may influence the transportation and deposition characteristics of particles within pollutant transport and within granular filters that are typically used in wastewater treatment. We conducted two-dimensional sandbox experiments using quartz powder as the particles and quartz sand as the porous medium to study the response of transportation and deposition formation to changes in particle diameter (ds, with median diameter 18, 41, and 82 μm) and grain diameter (dp, with median diameter 0.36, 1.25, and 2.82 mm) considering a wide range of diameter ratios (ds/dp) from 0.0064 to 0.228. Particles were suspended in deionized water, and quartz sand was used as the porous medium, which was meticulously cleaned to minimize any physicochemical and impurities effects that could result in indeterminate results. After the experiments, the particle concentration of the effluent and particle mass per gram of dry sands were measured to explore changes in transportation and deposition characteristics under different conditions. In addition, a micro-analysis was conducted to better analyse the results on a mesoscopic scale. The experimental observation analyses indicate that different diameter ratios (ds/dp) may lead to different deposit formations. As ds/dp increased, the deposit formation changed from 'Random Deposition Type' to 'Gradient Deposition Type', and eventually became 'Inlet Deposition Type'.

  15. Time-of-Flight Three Dimensional Neutron Diffraction in Transmission Mode for Mapping Crystal Grain Structures

    DEFF Research Database (Denmark)

    Cereser, Alberto; Strobl, Markus; Hall, Stephen A.

    2017-01-01

    constituting the material. This article presents a new non-destructive 3D technique to study centimeter-sized bulk samples with a spatial resolution of hundred micrometers: time-of-flight three-dimensional neutron diffraction (ToF 3DND). Compared to existing analogous X-ray diffraction techniques, ToF 3DND......-of-flight neutron beamline. The technique was developed and tested with data collected at the Materials and Life Science Experimental Facility of the Japan Proton Accelerator Complex (J-PARC) for an iron sample. We successfully reconstructed the shape of 108 grains and developed an indexing procedure...... enables studies of samples that can be both larger in size and made of heavier elements. Moreover, ToF 3DND facilitates the use of complicated sample environments. The basic ToF 3DND setup, utilizing an imaging detector with high spatial and temporal resolution, can easily be implemented at a time...

  16. Extracting magnetic cluster size and its distributions in advanced perpendicular recording media with shrinking grain size using small angle x-ray scattering

    Energy Technology Data Exchange (ETDEWEB)

    Mehta, Virat; Ikeda, Yoshihiro; Takano, Ken; Terris, Bruce D.; Hellwig, Olav [San Jose Research Center, HGST a Western Digital company, 3403 Yerba Buena Rd., San Jose, California 95135 (United States); Wang, Tianhan [Department of Materials Science and Engineering, Stanford University, Stanford, California 94035 (United States); Stanford Institute for Materials and Energy Science (SIMES), SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025 (United States); Wu, Benny; Graves, Catherine [Stanford Institute for Materials and Energy Science (SIMES), SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025 (United States); Department of Applied Physics, Stanford University, Stanford, California 94035 (United States); Dürr, Hermann A.; Scherz, Andreas; Stöhr, Jo [Stanford Institute for Materials and Energy Science (SIMES), SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025 (United States)

    2015-05-18

    We analyze the magnetic cluster size (MCS) and magnetic cluster size distribution (MCSD) in a variety of perpendicular magnetic recording (PMR) media designs using resonant small angle x-ray scattering at the Co L{sub 3} absorption edge. The different PMR media flavors considered here vary in grain size between 7.5 and 9.5 nm as well as in lateral inter-granular exchange strength, which is controlled via the segregant amount. While for high inter-granular exchange, the MCS increases rapidly for grain sizes below 8.5 nm, we show that for increased amount of segregant with less exchange the MCS remains relatively small, even for grain sizes of 7.5 and 8 nm. However, the MCSD still increases sharply when shrinking grains from 8 to 7.5 nm. We show evidence that recording performance such as signal-to-noise-ratio on the spin stand correlates well with the product of magnetic cluster size and magnetic cluster size distribution.

  17. Variability of grain sizes in a beach nourishment programme for the Danish West Caost

    DEFF Research Database (Denmark)

    Frigaard, Peter; Wahl, Niels Arne

    2007-01-01

    The coastal landscape in Denmark is characterized by multiple areas of geologic, biologic and recreational interests both national and international. In the later years several guidelines have been set up for the coastal protection area. The aims for the future are to ensure the presence...... of naturally shaped beaches while at the same time the risk for erosion is reduced. For this reason beach nourishment is used widely along the Danish North Sea coast (called West Coast) and this method is preferred in preference to put up solid constructions. Beach nourishment is the primary method used...... by the Danish Coastal Authority. However problems have occurred in describing the spatial distribution of medium grain size d50 and the gradation U of the sediment used for beach nourishment. At the same time the sedimentary composition determines how fast the nourished beach is eroded and how the beach...

  18. Grain Size Control of Semisolid A356 Alloy Manufactured by Electromagnetic Stirring

    Institute of Scientific and Technical Information of China (English)

    Z Yang; P.K. Seo; C.G.Kang

    2005-01-01

    To investigate the possibility of substituting the mechanical stirring system with electromagnetic stirring (EMS)system for aluminum rheo die-casting, the EMS under the different stirring cooling conditions was carried out. It was found that in the early period of solidification, the dendrite breakages led to a fine primary phase. When dendrites grew coarsely, the effect of ripening on grain size overwhelmed that of dendrite breakage. It was also found that the high cooling rate favored large nucleation rate, and led to a fine primary phase. But high cooling rate also made the growth rate of the dendrite arm, which prevented the dendrite arm from being sheared off. Therefore there were a suitable stirring time and suitable cooling rate to obtain the best rheo die-casting structure. Qualified semisolid A356aluminum alloy was successfully manufactured with short time EMS.

  19. Stimulated Brillouin scattering of laser in semiconductor plasma embedded with nano-sized grains

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Giriraj, E-mail: grsharma@gmail.com [SRJ Government Girls’ College, Neemuch (M P) (India); Dad, R. C. [Government P G College, Mandsaur (M P) (India); Ghosh, S. [School of Studies in Physics, Vikram University, Ujjain, (M P) (India)

    2015-07-31

    A high power laser propagating through semiconductor plasma undergoes Stimulated Brillouin scattering (SBS) from the electrostrictively generated acoustic perturbations. We have considered that nano-sized grains (NSGs) ions are embedded in semiconductor plasma by means of ion implantation. The NSGs are bombarded by the surrounding plasma particles and collect electrons. By considering a negative charge on the NSGs, we present an analytically study on the effects of NSGs on threshold field for the onset of SBS and Brillouin gain of generated Brillouin scattered mode. It is found that as the charge on the NSGs builds up, the Brillouin gain is significantly raised and the threshold pump field for the onset of SBS process is lowered.

  20. Structure and strength of aluminum with sub-micrometer/micrometer grain size prepared by spark plasma sintering

    DEFF Research Database (Denmark)

    Le, G.M.; Godfrey, A.; Hansen, Niels

    2013-01-01

    A spark plasma sintering (SPS) technique has been applied to prepare fully dense Al samples from Al powder. By applying a sintering temperature of 600°C and a loading pressure of 50MPa, fully recrystallized samples of nearly 100% density with average grain sizes of 5.2μm, 1.3μm and 0.8μm have been...... the initial powder particle size. The SPS samples show higher strength than Al samples with an identical grain size prepared using thermo-mechanical processing, and a better strength-ductility combination, with the 1.3μm grain size sample showing a yield strength (σ0.2%) of 140MPa and a uniform elongation...

  1. Grain size effect on the electrical response of SnO2 thin and thick film gas sensors

    Directory of Open Access Journals (Sweden)

    Raluca Savu

    2009-03-01

    Full Text Available Porous nano and micro crystalline tin oxide films were deposited by RF Magnetron Sputtering and doctor blade techniques, respectively. Electrical resistance and impedance spectroscopy measurements, as a function of temperature and atmosphere, were performed in order to determine the influence of the microstructure and working conditions over the electrical response of the sensors. The conductivity of all samples increases with the temperature and decreases in oxygen, as expected for an n-type semiconducting material. The impedance plots indicated the existence of two time constants related to the grains and the grain boundaries. The Nyquist diagrams at low frequencies revealed the changes that took place in the grain boundary region, with the contribution of the grains being indicated by the formation of a second semicircle at high frequencies. The better sensing performance of the doctor bladed samples can be explained by their lower initial resistance values, bigger grain sizes and higher porosity.

  2. Attraction of likely charged nano-sized grains in dust-electron plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Vishnyakov, Vladimir I., E-mail: eksvar@ukr.net [Physical-Chemical Institute for Environmental and Human Protection, Odessa 65082 (Ukraine)

    2016-01-15

    Dust-electron plasma, which contains only the dust grains and electrons, emitted by them, is studied. Assumption of almost uniform spatial electrons distribution, which deviates from the uniformity only near the dust grains, leads to the grain charge division into two parts: first part is the individual for each grain “visible” charge and the second part is the common charge of the neutralized background. The visible grain charge can be both negative and positive, while the total grain charge is only positive. The attraction of likely charged grains is possible, because the grain interaction is determined by the visible charges. The equilibrium state between attraction and repulsion of grains is demonstrated.

  3. Flow Characteristics and Grain Size Distribution of Granular Gangue Mineral by Compaction Treatment

    Directory of Open Access Journals (Sweden)

    Ran Yuan

    2017-01-01

    Full Text Available A test system for water flow in granular gangue mineral was designed to study the flow characteristics by compaction treatment. With the increase of the compaction displacement, the porosity decreases and void in granular gangue becomes less. The main reason causing initial porosity decrease is that the void of larger size is filled with small particles. Permeability tends to decrease and non-Darcy flow factor increases under the compaction treatment. The change trend of flow characteristics shows twists and turns, which indicate that flow characteristics of granular gangue mineral are related to compaction level, grain size distribution, crushing, and fracture structure. During compaction, larger particles are crushed, which in turn causes the weight of smaller particles to increase, and water flow induces fine particles to migrate (weight loss; meanwhile, a sample with more weight of size (0–2.5 mm has a higher amount of weight loss. Water seepage will cause the decrease of some chemical components, where SiO2 decreased the highest in these components; the components decreased are more likely locked at fragments rather than the defect of the minerals. The variation of the chemical components has an opposite trend when compared with permeability.

  4. (100)-textured self-assembled square-shaped polycrystalline silicon grains by multiple shot excimer laser crystallization

    NARCIS (Netherlands)

    He, M.; Ishihara, R.; Metselaar, W.; Beenakker, K.

    2006-01-01

    Strong preference for (100) surface and in-plane orientations has been observed in polycrystalline silicon film on SiO2 after crystallization with multiple excimer laser pulses. Laser induced periodic surface structure (LIPSS) is developed in the film, constructing self-assembled square-shaped grain

  5. Double hexagonal close-packed structure revealed in a single colloidal crystal grain by Bragg rod analysis

    NARCIS (Netherlands)

    Meijer, J. M.; Shabalin, A.; Dronyak, R.; Yefanov, O. M.; Singer, A.; Kurta, R. P.; Lorenz, U.; Gorobstov, O.; Dzhigaev, D.; Gulden, J.; Byelov, D. V.; Zozulya, A. V.; Sprung, M.; Vartanyants, I. A.; Petukhov, Andrei V.

    2014-01-01

    A coherent X-ray diffraction study of a single colloidal crystal grain composed of silica spheres is reported. The diffraction data contain Bragg peaks and additional features in the form of Bragg rods, which are related to the stacking of the hexagonally close-packed layers. The profile of the Brag

  6. 3D granulometry: grain-scale shape and size distribution from point cloud dataset of river environments

    Science.gov (United States)

    Steer, Philippe; Lague, Dimitri; Gourdon, Aurélie; Croissant, Thomas; Crave, Alain

    2016-04-01

    The grain-scale morphology of river sediments and their size distribution are important factors controlling the efficiency of fluvial erosion and transport. In turn, constraining the spatial evolution of these two metrics offer deep insights on the dynamics of river erosion and sediment transport from hillslopes to the sea. However, the size distribution of river sediments is generally assessed using statistically-biased field measurements and determining the grain-scale shape of river sediments remains a real challenge in geomorphology. Here we determine, with new methodological approaches based on the segmentation and geomorphological fitting of 3D point cloud dataset, the size distribution and grain-scale shape of sediments located in river environments. Point cloud segmentation is performed using either machine-learning algorithms or geometrical criterion, such as local plan fitting or curvature analysis. Once the grains are individualized into several sub-clouds, each grain-scale morphology is determined using a 3D geometrical fitting algorithm applied on the sub-cloud. If different geometrical models can be conceived and tested, only ellipsoidal models were used in this study. A phase of results checking is then performed to remove grains showing a best-fitting model with a low level of confidence. The main benefits of this automatic method are that it provides 1) an un-biased estimate of grain-size distribution on a large range of scales, from centimeter to tens of meters; 2) access to a very large number of data, only limited by the number of grains in the point-cloud dataset; 3) access to the 3D morphology of grains, in turn allowing to develop new metrics characterizing the size and shape of grains. The main limit of this method is that it is only able to detect grains with a characteristic size greater than the resolution of the point cloud. This new 3D granulometric method is then applied to river terraces both in the Poerua catchment in New-Zealand and

  7. Regional Association Analysis of MetaQTLs Delineates Candidate Grain Size Genes in Rice

    Directory of Open Access Journals (Sweden)

    Anurag V. Daware

    2017-05-01

    Full Text Available Molecular mapping studies which aim to identify genetic basis of diverse agronomic traits are vital for marker-assisted crop improvement. Numerous Quantitative Trait Loci (QTLs mapped in rice span long genomic intervals with hundreds to thousands of genes, which limits their utilization for marker-assisted genetic enhancement of rice. Although potent, fine mapping of QTLs is challenging task as it requires screening of large number of segregants to identify suitable recombination events. Association mapping offers much higher resolution as compared to QTL mapping, but detects considerable number of spurious QTLs. Therefore, combined use of QTL and association mapping strategies can provide advantages associated with both these methods. In the current study, we utilized meta-analysis approach to identify metaQTLs associated with grain size/weight in diverse Indian indica and aromatic rice accessions. Subsequently, attempt has been made to narrow-down identified grain size/weight metaQTLs through individual SNP- as well as haplotype-based regional association analysis. The study identified six different metaQTL regions, three of which were successfully revalidated, and substantially scaled-down along with GS3 QTL interval (positive control by regional association analysis. Consequently, two potential candidate genes within two reduced metaQTLs were identified based on their differential expression profiles in different tissues/stages of rice accessions during seed development. The developed strategy has broader practical utility for rapid delineation of candidate genes and natural alleles underlying QTLs associated with complex agronomic traits in rice as well as major crop plants enriched with useful genetic and genomic information.

  8. Orthographic transparency modulates the grain size of orthographic processing: behavioral and ERP evidence from bilingualism.

    Science.gov (United States)

    Lallier, Marie; Carreiras, Manuel; Tainturier, Marie-Josèphe; Savill, Nicola; Thierry, Guillaume

    2013-04-10

    Grapheme-to-phoneme mapping regularity is thought to determine the grain size of orthographic information extracted whilst encoding letter strings. Here we tested whether learning to read in two languages differing in their orthographic transparency yields different strategies used for encoding letter-strings as compared to learning to read in one (opaque) language only. Sixteen English monolingual and 16 early Welsh-English bilingual readers undergoing event-related brain potentials (ERPs) recordings were asked to report whether or not a target letter displayed at fixation was present in either a nonword (consonant string) or an English word presented immediately before. Bilinguals and monolinguals showed similar behavioural performance on target detection presented in words and nonwords, suggesting similar orthographic encoding in the two groups. By contrast, the amplitude of ERPs locked to the target letters (P3b, 340-570 ms post target onset, and a late frontal positive component 600-1,000 ms post target onset) were differently modulated by the position of the target letter in words and nonwords between bilinguals and monolinguals. P3b results show that bilinguals who learnt to read simultaneously in an opaque and a transparent orthographies encoded orthographic information presented to the right of fixation more poorly than monolinguals. On the opposite, only monolinguals exhibited a position effect on the late positive component for both words and nonwords, interpreted as a sign of better re-evaluation of their responses. The present study shed light on how orthographic transparency constrains grain size and visual strategies underlying letter-string encoding, and how those constraints are influenced by bilingualism.

  9. Systematic procedure for generating operational policies to achieve target crystal size distribution (CSD) in batch cooling crystallization

    DEFF Research Database (Denmark)

    Abdul Samad, Noor Asma Fazli; Singh, Ravendra; Sin, Gürkan

    2011-01-01

    A systematic procedure to achieve a target crystal size distribution (CSD) under generated operational policies in batch cooling crystallization is presented. An analytical CSD estimator has been employed in the systematic procedure to generate the necessary operational policies to achieve the ta...

  10. Influence of retained austenite on the grain size of austenite after reaustenitization of steels for heavy forgings

    Energy Technology Data Exchange (ETDEWEB)

    Peters, H.J.; Tacke, G.; Hougardy, H.P.

    1989-01-01

    In this investigation the grain size of austenite reaustenitization of different microstructures containing different volume fractions of retained austenite was determined. The austenite grain size after austenitization of martensite and lower bainite was coarse for heating rates lower than a minimum value, which is dependent on the chemical composition. In this case, the austenite forms by rapid growth of retained austenite in the initial microstructure. At heating rates higher than the critical value, formation of austenite starts at the ferrite-carbide phase boundaries giving a fine austenite grain. The formation of austenite from microstructures free of retained austenite, such as pearlite, always occurred by nucleation on the ferrite-carbide interphase resulting in fine austenite grains. (orig.).

  11. Exploring the Role of Sub-micron Sized Dust Grains in the Atmospheres of Red L0 - L6 Dwarfs

    CERN Document Server

    Hiranaka, Kay; Douglas, Stephanie T; Marley, Mark S; Baldassare, Vivienne F

    2016-01-01

    We examine the hypothesis that the red near-infrared colors of some L dwarfs could be explained by a "dust haze" of small particles in their upper atmospheres. This dust haze would exist in conjunction with the clouds found in dwarfs with more typical colors. We developed a model which uses Mie theory and the Hansen particle size distributions to reproduce the extinction due to the proposed dust haze. We apply our method to 23 young L dwarfs and 23 red field L dwarfs. We constrain the properties of the dust haze including particle size distribution and column density using Markov-Chain Monte Carlo methods. We find that sub-micron range silicate grains reproduce the observed reddening. Current brown dwarf atmosphere models include large grain (1--100~$\\mu m$) dust clouds but not submicron dust grains. Our results provide a strong proof of concept and motivate a combination of large and small dust grains in brown dwarf atmosphere models.

  12. Seasonal changes of magnetic minerals and their grain sizes in the Hiroshima Bay sediments

    Science.gov (United States)

    Kawamura, N.; Ishikawa, N.

    2011-12-01

    Frequent outbreaks of red tide have been reported since 1970 in the Hiroshima bay, and the red tide is caused by a bloom of dinoflagellates. Iron is an essential element for dinoflagellates, and is supplied as bivalent or trivalent ions and iron compounds from lands to sea. For damage predictions of red tide, it is important to research the distribution of iron in the bay. The acidification of seawater during summer has been also observed in the Hiroshima Bay. Increase of CO2 concentration and decrease of dissolved oxygen (DO) content in seawater cause an anoxic condition in the bay. It is known that iron oxides are dissolved and sulfides are formed in an anoxic condition. For clarifying variations of the distribution and mode of iron in sediments and bottom water in the Hiroshima Bay, we investigated kinds of iron compounds in the sediments and the amount of dissolved iron in the bottom waters. Sediment cores of 5cm in depth were taken at three sites in the Hiroshima Bay by using a multiple corer and crab sampler. Data of oceanographic observations at these sites showed that the temperature of the bottom water increased, whereas DO and pH values decreased during the sampling period. The sediment samples were composed of clayey silt. We measured dissolved iron concentration in interstitial and bottom waters filtered above 0.45 um grains, and performed magnetic hysteresis measurements and high temperature magnetometry on the sediment samples. The presence of magnetite (Fe3O4) and hematite (Fe2O3) were recognized in all analyzed samples, whereas greigite (Fe3S4) appeared at these sites with an anoxic condition in the bottom water. Magnetic grain size increased from June to August, while iron concentration increased in the bottom waters. It is suggested that magnetite and hematite were dissolved and greigite was formed, associated with the proceeding of the anoxic condition, and that the grain-size of magnetic minerals and the iron concentration of the bottom water

  13. Size effects on void growth in single crystals with distributed voids

    DEFF Research Database (Denmark)

    Borg, Ulrik; Niordson, Christian Frithiof; Kysar, J.W.

    2008-01-01

    The effect of void size on void growth in single crystals with uniformly distributed cylindrical voids is studied numerically using a finite deformation strain gradient crystal plasticity theory with an intrinsic length parameter. A plane strain cell model is analyzed for a single crystal...

  14. Prediction of charge mobility in organic semiconductors with consideration of the grain-size effect

    Science.gov (United States)

    Park, Jin Woo; Lee, Kyu Il; Choi, Youn-Suk; Kim, Jung-Hwa; Jeong, Daun; Kwon, Young-Nam; Park, Jong-Bong; Ahn, Ho Young; Park, Jeong-Il; Lee, Hyo Sug; Shin, Jaikwang

    2016-09-01

    A new computational model to predict the hole mobility of poly-crystalline organic semiconductors in thin film was developed (refer to Phys. Chem. Chem. Phys., 2016, DOI: 10.1039/C6CP02993K). Site energy differences and transfer integrals in crystalline morphologies of organic molecules were obtained from quantum chemical calculation, in which the periodic boundary condition was efficiently applied to capture the interactions with the surrounding molecules in the crystalline organic layer. Then the parameters were employed in kinetic Monte Carlo (kMC) simulations to estimate the carrier mobility. Carrier transport in multiple directions has been considered in the kMC simulation to mimic polycrystalline characteristic in thin-film condition. Furthermore, the calculated mobility was corrected with a calibration equation based on the microscopic images of thin films to take the effect of grain boundary into account. As a result, good agreement was observed between the predicted and measured hole mobility values for 21 molecular species: the coefficient of determination (R2) was estimated to be 0.83 and the mean absolute error was 1.32 cm2 V-1 s-1. This numerical approach can be applied to any molecules for which crystal structures are available and will provide a rapid and precise way of predicting the device performance.

  15. [Effect of dragon's blood powder with different grain size on transdermal absorption and adhesion of ZJHX paste].

    Science.gov (United States)

    Hu, Qin; Sun, E; Zhang, Zhen-Hai; Zhu, Jing; Jia, Xiao-Bin

    2012-12-01

    To study the effect of dragon's blood powder with different grain size on the transdermal permeability and adhesion of ZJHX paste. Dragon's blood powder with grain sizes of 4, 19, 55 microm were got by ultrafine grinding technology, and then prepared into rubber pastes A, B, C and D, together with dragon's blood powder with grain size of 93 microm of original description. Franz diffusion cell method was adopted to compare the difference in transdermal permeability of dragon's blood powder with different grain sizes, with dracorhodin as the index, and compared their effect on the adhesion of pastes with initial adhesion, permanent adhesion and peel strength as the indexes. Q(s)-t equations of pastes A, B, C, D were as follows: Q(s)=1.369 6t + 3.985 5, Q(s) = 1.262 8t +3.738 1, Q(s) = 1.192 3t + 3.320 6, Q(s) = 1.152 2t + 2.366 1, respectively, which showed that the adhesion of A was the best good. With the decrease in the grain size of dragon's blood powder, accumulative penetration of dracorhodin increases, which facilitates transdermal permeability and adhesion.

  16. Conditions necessary for capillary hysteresis in porous media: Tests of grain-size and surface tension influences

    OpenAIRE

    Tokunaga, Tetsu K.; Olson, Keith R.; Wan, Jiamin

    2004-01-01

    Hysteresis in the relation between water saturation and matric potential is generally regarded as a basic aspect of unsaturated porous media. However, the nature of an upper length scale limit for saturation hysteresis has not been previously addressed. Since hysteresis depends on whether or not capillary rise occurs at the grain scale, this criterion was used to predict required combinations of grain size, surface tension, fluid-fluid density differences, and acceleration in monodisper...

  17. Producing laminated NiAl with bimodal distribution of grain size by solid–liquid reaction treatment

    DEFF Research Database (Denmark)

    Fan, G.H.; Wang, Q.W.; Du, Y.

    2014-01-01

    The prospect of combining laminated structure design and grain size tailoring to toughen brittle materials is examined. Laminated NiAl consisting of coarse-grained layers and fine-grained layers was fabricated by solid–liquid reaction treatment of stacking Ni and Al foils. The fracture toughness...... at ambient temperature has been improved 2–3 times. It is of great potential to extend this approach to other binary alloys, such as Ti–Al, Fe–Al, Nb–Al, etc., where solid–liquid reaction occurs readily at high temperature....

  18. Evolution of grain sizes and orientations during phase transitions in hydrous Mg2SiO4

    Science.gov (United States)

    Rosa, Angelika D.; Hilairet, Nadège; Ghosh, Sujoy; Perrillat, Jean-Philippe; Garbarino, Gaston; Merkel, Sébastien

    2016-10-01

    Transformation microstructures in mantle minerals, such as (Mg,Fe)2SiO4, are critical for predicting the rheological properties of rocks and the interpretation of seismic observations. We present in situ multigrain X-ray diffraction experiments on hydrous Mg2SiO4 at the P/T conditions relevant for deep cold subducting slabs (up to 40 GPa and 850°C) at a low experimental strain rate ( 4 * 10-6s-1). We monitor the orientations of hundreds of grains and grain size variations during the series of α-β-γ (forsterite-wadsleyite-ringwoodite) phase transformations. Microtextural results indicate that the β and an intermediate γ* phase grow incoherently relatively to the host α phase consistent with a nucleation and growth model. The β and γ phases exhibit orientation relationships which are in agreement with previous ex situ observations. The β and intermediate γ* show texturing due to moderate differential stress in the sample. Both the α-β and α-γ transformation induce significant reductions of the mean sample grain size of up to 90% that starts prior to the appearance of the daughter phase. Apart from the γ*, in the newly formed β and γ phases, the nucleation rate is faster than the growth rate, inhibiting the formation of large grains. These results on grain orientations and grain size reductions in relation to transformation kinetics should allow refining existing slab strength models.

  19. Size effects of nano-scale pinning centers on the superconducting properties of YBCO single grains

    Science.gov (United States)

    Moutalbi, Nahed; Noudem, Jacques G.; M'chirgui, Ali

    2014-08-01

    High pinning superconductors are the most promising materials for power engineering. Their superconducting properties are governed by the microstructure quality and the vortex pinning behavior. We report on a study of the vortex pinning in YBa2Cu3O7-x (YBCO) single grain with defects induced through the addition of insulating nano-particles. In order to improve the critical current density, YBCO textured bulk superconductors were elaborated using the Top Seeded Melt Texture and Growth process with different addition amounts of Al2O3 nano-particles. Serving as strong pinning centers, 0.05% excess of Al2O3 causes a significant enhancement of the critical current density Jc under self field and in magnetic fields at 77 K. The enhanced flux pinning achieved with the low level of alumina nano-particles endorses the effectiveness of insulating nano-inclusions to induce effectives pinning sites within the superconducting matrix. On the other side, we focused on the effect of the size of pinning centers on the critical current density. This work was carried out using two batches of alumina nano-particles characterized by two different particle size distributions with mean diameters PSD1 = 20 nm and PSD2 = 2.27 μm. The matching effects of the observed pinning force density have been compared. The obtained results have shown that the flux pinning is closely dependent on the size of the artificial pinning centers. Our results suggest that the optimization of the size of the artificial pinning centers is crucial to a much better understanding of the pinning mechanisms and therefore to insure high superconducting performance for the practical application of superconducting materials.

  20. Effect of flow discharge and median grain size on mean flow velocity under overland flow

    Science.gov (United States)

    Ali, M.; Sterk, G.; Seeger, M.; Stroosnijder, L.

    2012-07-01

    SummaryPrecise estimation of mean flow velocity (Umean) is imperative for accurate prediction of hydrographs and sediment yield. For overland flow, Umean is normally estimated by multiplying the dye or salt based velocity measurement with a correction factor (α). A wide range of correction factors is available in the literature, all of which were derived under different experimental conditions. The selection of a suitable α has become a main challenge for accurate mean flow calculations. This study aimed to assess the variability of α with grain size (D50) and slope (S), and to evaluate the dependency of Umean on flow rate (Q), D50 and S by regression analysis. Flume experiments were performed at Q varying from 33 to 1033 × 10-6 m3 s-1, S ranging from 3° to 10°, and D50 ranging from 0.233 to 1.022 mm. Flow velocities were measured directly with the dye tracing technique (Udye), and derived indirectly from flow depth measurements (Udepth). The Udepth measurements were considered as Umean. The derived α (Udepth/Udye) values did not remain constant with sediment size and increase significantly with the increase of D50. The mean α values for 0.230, 0.536, 0.719 and 1.022 mm sands were 0.44, 0.77, 0.82 and 0.82, respectively. Hence, due to the substantial variation of α with D50, no absolute α value is applicable to all hydraulic and sedimentary conditions. However, mean α values for 0.230, 0.536 and 0.719 mm sands were found comparable with α values available in the literature for similar grain sizes. The influence of Q, S, and D50 on Umean was studied by regression analysis. Regression analysis depicted the significant influence of Q and D50 on Umean, while the effect of slope was found to be non-significant. Comparison of the derived regression equation with five literature datasets showed that the model can predict mean flow velocities in overland flow at a reasonable accuracy as long as the mean velocity is below 0.4 m s-1. At higher velocities the

  1. Incorporating gold into nanocrystalline silver dressings reduces grain boundary size and maintains suitable antimicrobial properties.

    Science.gov (United States)

    Unrau, Kevin R; Cavanagh, Marion H; Cheng, On Kwan; Wang, Shiman; Burrell, Robert E

    2013-12-01

    Nanocrystalline silver dressings are widely known to be potent antimicrobial and anti-inflammatory agents and have long been used to treat topical wounds. Gold is known to be a strong anti-inflammatory agent and has been used in the treatment of rheumatoid arthritis for >70 years. The purpose of this work was to study the effect of incorporating gold into nanocrystalline silver dressings from antimicrobial and anti-inflammatory perspectives. Gold and silver dressing alloys were created by direct current magnetron sputtering and compared with pure silver nanocrystalline dressings using conventional biological (log reduction and corrected zone of inhibition) and physical (X-ray diffraction, X-ray photoelectron spectroscopy, energy-dispersive X-ray spectroscopy, atomic absorption spectroscopy, atomic force microscopy and scanning electron microscopy) characterisation techniques. While the gold/silver dressings were slightly weaker antimicrobials than the pure silver nanocrystalline structures, the addition of gold to the nanostructure reduces the minimum crystallite size from 17 to 4 nm. This difference increases the number of grain boundary atoms from 12% to 40% which could augment the anti-inflammatory properties of the dressings. The formation of gold oxide (Au2O3) was thought to be responsible for the observed decrease in crystallite size.

  2. A Conceptual Model for Spatial Grain Size Variability on the Surface of and within Beaches

    Directory of Open Access Journals (Sweden)

    Edith Gallagher

    2016-05-01

    Full Text Available Grain size on the surface of natural beaches has been observed to vary spatially and temporally with morphology and wave energy. The stratigraphy of the beach at Duck, North Carolina, USA was examined using 36 vibracores (~1–1.5 m long collected along a cross-shore beach profile. Cores show that beach sediments are finer (~0.3 mm and more uniform high up on the beach. Lower on the beach, with more swash and wave action, the sand is reworked, segregated by size, and deposited in layers and patches. At the deepest measurement sites in the swash (~−1.4 to −1.6 m NAVD88, which are constantly being reworked by the energetic shore break, there is a thick layer (60–80 cm of very coarse sediment (~2 mm. Examination of two large trenches showed that continuous layers of coarse and fine sands comprise beach stratigraphy. Thicker coarse layers in the trenches (above mean sea level are likely owing to storm erosion and storm surge elevating the shore break and swash, which act to sort the sediment. Those layers are buried as water level retreats, accretion occurs and the beach recovers from the storm. Thinner coarse layers likely represent similar processes acting on smaller temporal scales.

  3. Heavy metal speciation in various grain sizes of industrially contaminated street dust using multivariate statistical analysis.

    Science.gov (United States)

    Yıldırım, Gülşen; Tokalıoğlu, Şerife

    2016-02-01

    A total of 36 street dust samples were collected from the streets of the Organised Industrial District in Kayseri, Turkey. This region includes a total of 818 work places in various industrial areas. The modified BCR (the European Community Bureau of Reference) sequential extraction procedure was applied to evaluate the mobility and bioavailability of trace elements (Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn) in street dusts of the study area. The BCR was classified into three steps: water/acid soluble fraction, reducible and oxidisable fraction. The remaining residue was dissolved by using aqua regia. The concentrations of the metals in street dust samples were determined by flame atomic absorption spectrometry. Also the effect of the different grain sizes (Cu (48.9)>Pb (42.8)=Cr (42.1)>Ni (41.4)>Zn (40.9)>Co (36.6)=Mn (36.3)>Fe (3.1). No significant difference was observed among metal partitioning for the three particle sizes. Correlation, principal component and cluster analysis were applied to identify probable natural and anthropogenic sources in the region. The principal component analysis results showed that this industrial district was influenced by traffic, industrial activities, air-borne emissions and natural sources. The accuracy of the results was checked by analysis of both the BCR-701 certified reference material and by recovery studies in street dust samples.

  4. Prediction of as-cast grain size of inoculated aluminum alloys melt solidified under non-isothermal conditions

    Science.gov (United States)

    Du, Qiang; Li, Yanjun

    2015-06-01

    In this paper, a multi-scale as-cast grain size prediction model is proposed to predict as-cast grain size of inoculated aluminum alloys melt solidified under non-isothermal condition, i.e., the existence of temperature gradient. Given melt composition, inoculation and heat extraction boundary conditions, the model is able to predict maximum nucleation undercooling, cooling curve, primary phase solidification path and final as-cast grain size of binary alloys. The proposed model has been applied to two Al-Mg alloys, and comparison with laboratory and industrial solidification experimental results have been carried out. The preliminary conclusion is that the proposed model is a promising suitable microscopic model used within the multi-scale casting simulation modelling framework.

  5. Analysis of Grain Size Distribution and Hydraulic Conductivity for a Variety of Sediment Types with Application to Wadi Sediments

    KAUST Repository

    Rosas Aguilar, Jorge

    2013-05-01

    Grain size distribution, porosity, and hydraulic conductivity from over 400 unlithified sediment samples were analized. The measured hydraulic conductivity values were then compared to values calculated using 20 different empirical equations commonly used to estimate hydraulic conductivity from grain size analyses. It was found that most of the hydraulic conductivity values estimated from the empirical equations correlated very poorly to the measured hydraulic conductivity values. Modifications of the empirical equations, including changes to special coefficients and statistical off sets, were made to produce modified equations that considerably improve the hydraulic conductivity estimates from grain size data for beach, dune, off shore marine, and wadi sediments. Expected hydraulic conductivity estimation errors were reduced. Correction factors were proposed for wadi sediments, taking mud percentage and the standard deviation (in phi units) into account.

  6. Influence of grain size on distribution of temperature and thermal stress in ZnO varistor ceramics

    Institute of Scientific and Technical Information of China (English)

    陈青恒; 何金良; 谈克雄; 陈水明; 严民昱; 唐建新

    2002-01-01

    The nonuniformity of temperature distribution within ZnO varistor ceramics would decrease its energy absorption capability. In this paper, the distributions of current, temperature and thermal stress within the microstructures of ZnO varistor ceramics are simulated using Voronoi diagram models. The results show that the current concentrates through a few paths in ZnO varistor due to the nonuniformity of ZnO grain size and the variety of electrical characteristics of grain boundaries, which induces local high temperature and great thermal stress when injecting impulse current into ZnO varistor, and leads to melting puncture or cracking failure. The influence of the ZnO grain size on the distributions of temperature and thermal stress within ZnO varistor ceramics is analyzed in detail. The energy absorption capability of ZnO varistor ceramics can be greatly improved by increasing the uniformity of ZnO grain size or decreasing the average size of ZnO grains.

  7. HydrogeoSieveXL: an Excel-based tool to estimate hydraulic conductivity from grain-size analysis

    Science.gov (United States)

    Devlin, J. F.

    2015-06-01

    For over a century, hydrogeologists have estimated hydraulic conductivity ( K) from grain-size distribution curves. The benefits of the practice are simplicity, cost, and a means of identifying spatial variations in K. Many techniques have been developed over the years, but all suffer from similar shortcomings: no accounting of heterogeneity within samples (i.e., aquifer structure is lost), loss of grain packing characteristics, and failure to account for the effects of overburden pressure on K. In addition, K estimates can vary by an order of magnitude between the various methods, and it is not generally possible to identify the best method for a given sample. The drawbacks are serious, but the advantages have seen the use of grain-size distribution curves for K estimation continue, often using a single selected method to estimate K in a given project. In most cases, this restriction results from convenience. It is proposed here that extending the analysis to include several methods would be beneficial since it would provide a better indication of the range of K that might apply. To overcome the convenience limitation, an Excel-based spreadsheet program, HydrogeoSieveXL, is introduced here. HydrogeoSieveXL is a freely available program that calculates K from grain-size distribution curves using 15 different methods. HydrogeoSieveXL was found to calculate K values essentially identical to those reported in the literature, using the published grain-size distribution curves.

  8. Small grain size zirconium-based coatings deposited by magnetron sputtering at low temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Jimenez, O., E-mail: omar.jimenez.udg@gmail.com [Departamento de Ingeniería de Proyectos, CUCEI, Universidad de Guadalajara, AP 307, CP 45101 Zapopan, Jal (Mexico); Department of Materials Science and Engineering, The University of Sheffield, Sheffield S1 3JD (United Kingdom); Audronis, M.; Leyland, A. [Department of Materials Science and Engineering, The University of Sheffield, Sheffield S1 3JD (United Kingdom); Flores, M.; Rodriguez, E. [Departamento de Ingeniería de Proyectos, CUCEI, Universidad de Guadalajara, AP 307, CP 45101 Zapopan, Jal (Mexico); Kanakis, K.; Matthews, A. [Department of Materials Science and Engineering, The University of Sheffield, Sheffield S1 3JD (United Kingdom)

    2015-09-30

    Hard, partly amorphous, ZrTiB(N) coatings were deposited by Physical Vapour Deposition (PVD) onto (111) silicon wafers at low substrate temperatures of 85 and 110 °C using Closed Field Unbalanced Magnetron Sputtering. A segmented rectangular sputter target composed of three pieces (Zr/TiB{sub 2}/Zr) was used as the source of evaporation of coating components. Two different substrate biases (i.e. floating potential and − 50 V) and N{sub 2} reactive-gas flow rates of 2, 4 and 6 sccm were employed as the main deposition parameter variables. The chemical composition, structure, morphology and mechanical properties were investigated using a variety of analytical techniques such as Glow-Discharge Optical Emission Spectroscopy, cross-sectional Scanning Electron Microscopy (SEM), Glancing Angle X-ray Diffraction (GAXRD) and nanoindentation. With other parameters fixed, coating properties were found to be dependent on the substrate negative bias and nitrogen flow rate. Linear scan profiles and SEM imaging revealed that all coatings were smooth, dense and featureless (in fracture cross section) with no apparent columnar morphology or macro-defects. GAXRD structural analysis revealed that mostly metallic phases were formed for coatings containing no nitrogen, whereas a solid solution (Zr,Ti)N single phase nitride was found in most of the reactively deposited coatings — exhibiting a very small grain size due to nitrogen and boron grain refinement effects. Hardness values from as low as 8.6 GPa up to a maximum of 25.9 GPa are related mainly to solid solution strengthening effects. The measured elastic moduli correlated with the trends in hardness behaviour; values in the range of 120–200 GPa were observed depending on the selected deposition parameters. Also, high H/E values (> 0.1) were achieved with several of the coatings.

  9. Influence of grain size on radiation effects in a low carbon steel

    Energy Technology Data Exchange (ETDEWEB)

    Alsabbagh, Ahmad, E-mail: ahalsabb@ncsu.edu [Department of Nuclear Engineering, North Carolina State University (United States); Valiev, Ruslan Z. [Institute of Physics of Advanced Materials, Ufa State Aviation Technical University (Russian Federation); Murty, K.L. [Department of Nuclear Engineering, North Carolina State University (United States)

    2013-11-15

    Ultra-fine grain (UFG) metals with a relatively large volume of interfaces are expected to be more radiation resistant than conventional metals; grain boundaries act as unsaturable sinks for neutron irradiation induced defects. Effects of neutron irradiation on conventional and ultra-fine grain structured carbon steel are studied using the PULSTAR reactor at NC State University to relatively low fluence (∼1.15 × 10{sup −3} dpa). The low dose irradiation of ultrafine grained carbon steel revealed minute radiation effects in contrast to the observed radiation hardening and reduction of ductility in its conventional grained counterpart.

  10. Effect of suspended sediment grain size on channel sedimentation in the lower Yellow River and some implications

    Institute of Scientific and Technical Information of China (English)

    XU JiongXin; HU ChunHong; CHEN JianGuo

    2009-01-01

    Based on the data of suspended sediment transport and channel sedimentation in various grain size fractions in the period of 1962-1985,the relationship between channel sedimentation in the lower Yellow River and sediment input has been plotted with respect to each grain size fraction.Several fill-scour thresholds in sediment input have been identified from these graphs.It was found that the fill-scour threshold in sediment input decreases with the increase in fraction grain size.The correlation coefficient between channel sedimentation and sediment input becomes larger with the increasing fraction grain size,indicating that channel sedimentation depends more on coarser grain size fractions than on smaller ones.The fraction channel sedimentation induced by unit change of fraction sediment input increases with grain size.Of the input of sediment larger than 0.025 mm,43.73% was deposited on the channel,and for inputs of sediments larger than 0.05 mm and larger than 0.10 mm,76.61% and 97.68% were deposited on the channel,respectively.Thus,for reduction of each ton of sediment larger than 0.10 mm from the drainage basin,the resultant reduction in channel sedimentation in the lower Yellow River would be 1.275 times that for the sediment larger than 0.10 mm,and 2.234 times that for the sediment larger than 0.025 mm.Therefore,if the erosion and sediment control measures are enforced in the areas where >0.05 or >0.10 mm sediment is produced,then the best beneficial will be achieved in reducing sedimentation in the lower Yellow River.

  11. Effect of suspended sediment grain size on channel sedimentation in the lower Yellow River and some implications

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Based on the data of suspended sediment transport and channel sedimentation in various grain size fractions in the period of 1962―1985, the relationship between channel sedimentation in the lower Yellow River and sediment input has been plotted with respect to each grain size fraction. Several fill-scour thresholds in sediment input have been identified from these graphs. It was found that the fill-scour threshold in sediment input decreases with the increase in fraction grain size. The correlation coefficient between channel sedimentation and sediment input becomes larger with the increasing fraction grain size, indicating that channel sedimentation depends more on coarser grain size fractions than on smaller ones. The fraction channel sedimentation induced by unit change of fraction sediment input increases with grain size. Of the input of sediment larger than 0.025 mm, 43.73% was deposited on the channel, and for inputs of sediments larger than 0.05 mm and larger than 0.10 mm, 76.61% and 97.68% were deposited on the channel, respectively. Thus, for reduction of each ton of sediment larger than 0.10 mm from the drainage basin, the resultant reduction in channel sedimentation in the lower Yellow River would be 1.275 times that for the sediment larger than 0.10 mm, and 2.234 times that for the sediment larger than 0.025 mm. Therefore, if the erosion and sediment control measures are enforced in the areas where >0.05 or >0.10 mm sediment is produced, then the best beneficial will be achieved in reducing sedimentation in the lower Yellow River.

  12. Numerical simulation of temperature distribution using finite difference equations and estimation of the grain size during friction stir processing

    Energy Technology Data Exchange (ETDEWEB)

    Arora, H.S. [School of Mechanical, Material and Energy Engineering, Indian Institute of Technology Ropar, Rupnagar, Punjab 140001 (India); Singh, H., E-mail: harpreetsingh@iitrpr.ac.in [School of Mechanical, Material and Energy Engineering, Indian Institute of Technology Ropar, Rupnagar, Punjab 140001 (India); Dhindaw, B.K. [School of Materials and Mineral Resources, Universiti Sains Malaysia, Engineering Campus, Nibong Tebal, Pulau Penang 14300 (Malaysia)

    2012-05-01

    Highlights: Black-Right-Pointing-Pointer Magnesium alloy AE42 was friction stir processed under different cooling conditions. Black-Right-Pointing-Pointer Heat flow model was developed using finite difference heat equations. Black-Right-Pointing-Pointer Generalized MATLAB code was developed for solving heat flow model. Black-Right-Pointing-Pointer Regression equation for estimation of grain size was developed. - Abstract: The present investigation is aimed at developing a heat flow model to simulate temperature history during friction stir processing (FSP). A new approach of developing implicit form of finite difference heat equations solved using MATLAB code was used. A magnesium based alloy AE42 was friction stir processed (FSPed) at different FSP parameters and cooling conditions. Temperature history was continuously recorded in the nugget zone during FSP using data acquisition system and k type thermocouples. The developed code was validated at different FSP parameters and cooling conditions during FSP experimentation. The temperature history at different locations in the nugget zone at different instants of time was further utilized for the estimation of grain growth rate and final average grain size of the FSPed specimen. A regression equation relating the final grain size, maximum temperature during FSP and the cooling rate was developed. The metallurgical characterization was done using optical microscopy, SEM, and FIB-SIM analysis. The simulated temperature profiles and final average grain size were found to be in good agreement with the experimental results. The presence of fine precipitate particles generated in situ in the investigated magnesium alloy also contributed in the evolution of fine grain structure through Zener pining effect at the grain boundaries.

  13. Grain size effect on the structural parameters of the stress induced epsilonhcp: martensite in iron-based shape memory alloy

    Directory of Open Access Journals (Sweden)

    Fabiana Cristina Nascimento

    2008-03-01

    Full Text Available The aim of this work was to study the effect of austenitic grain size (GS reduction on the structural parameters of the epsilonhcp - martensite in stainless shape memory alloy (SMA. Rietveld refinement data showed an expansion in c-axis and a reduction in a and b-axis with thermo-mechanical cycles for all samples analyzed. Samples with 75 < GS (µm < 129 were analyzed. It was also observed an increase of the unit cell volume in this phase with GS reduction. The smallest grain size sample (GS = 75 µm presented a c/a ratio of 1.649, and approximately 90% of total shape memory recovery.

  14. Temperature dependent grain-size and microstrain of CdO thin films prepared by spray pyrolysis method

    Indian Academy of Sciences (India)

    B G Jeyaprakash; K Kesavan; R Ashok Kumar; S Mohan; A Amalarani

    2011-07-01

    CdO thin films on glass substrate were prepared by home built spray pyrolysis unit from aqueous solution of Cd(CH3COO)2.2H2O at different substrate temperatures. X-ray diffraction (XRD) studies indicate the formation of polycrystalline cubic CdO phase with preferential orientation along (111) plane. X-ray line broadening technique is adopted to study the effect of substrate temperature on microstructural parameters such as grain size and microstrain. Scanning electron microscopy (SEM) shows that the film prepared at 250°C consists of spherical shape grains with size in nanometer range and is comparable with the XRD studies.

  15. Grain Size and Photocatalytic Activity of Nanometer TiO2 Thin Films Prepared by the Sol-gel Method

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Transparent anatase TiO2 nanometer thin films with photocatalytic activity were prepared via the sol-gel method on soda-lime glass. The thickness, crystalline phase, grain size, surface hydroxyl amount and so on were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and UV-visible spectrophotometer (UV-VIS). The photocatalytic activity of TiO2 thin films was evaluated for the photocatalytic decolorization of aqueous methyl orange. The effects of film thickness on the crystalline phase, grain size, transmittance and photocatalytic activity of nanometer TiO2 thin films were discussed.

  16. The effect of grain size and film thickness on the thermal expansion coefficient of copper thin films.

    Science.gov (United States)

    Hwang, Seulgi; Kim, Youngman

    2011-02-01

    Cu thin films underwent thermal cycling to determine their coefficient of thermal expansion (CTE). The thermal stress of the Cu thin films with various microstructures (different grain size and film thickness) was measured using a curvature measurement system. The thermal expansion coefficients of the films were obtained from the slope of the stress-temperature curve with the knowledge of the Young's modulus and Poisson's ratio. The change in thermal stress with temperature of the Cu thin films tended to decrease with increasing grain size, resulting in an increase in the CTE. The thickness of Cu thin film had little effect on the thermal stress or the CTE.

  17. Bathymetry, topography, and sediment grain-size data from the Elwha River delta, Washington, February 2016

    Science.gov (United States)

    Stevens, Andrew; Gelfenbaum, Guy R.; Warrick, Jonathan; Miller, Ian M.; Weiner, Heather M.

    2016-01-01

    Two dams on the Elwha River, Washington State, USA trapped over 20 million m3 of sediment, reducing downstream sediment fluxes and contributing to erosion of the river's coastal delta. The removal of the Elwha and Glines Canyon dams between 2011 and 2014 induced massive increases in river sediment supply and provided an unprecedented opportunity to examine the response of a delta system to changes in sediment supply. The U.S. Geological Survey (USGS) developed an integrated research program aimed at understanding the ecosystem responses following dam removal. The research program included repeated surveys of beach topography, nearshore bathymetry, and surface sediment grain size to quantify changes in delta morphology and texture following the dam removals. For more information on the USGS role in the Elwha River Restoration Project, please visit http://walrus.wr.usgs.gov/elwha/. This USGS data release presents data collected during surveys of nearshore bathymetry, beach topography, and surface sediment grain size from the Elwha River delta, Washington. Survey operations were conducted between February 15 and February 19, 2016 (USGS Field Activity Number 2016-608-FA) by a team of scientists from the U.S. Geological Survey Pacific Coastal and Marine Science Center (PCMSC), Washington State Department of Ecology (WA DOE), Washington Sea Grant, and National Park Service (table 1). Nearshore bathymetry data were collected using two personal watercraft (PWCs) and a kayak, each equipped with single-beam echosounders and survey-grade global navigation satellite systems (GNSS). Topography data were collected on foot with GNSS mounted on backpacks. Positions of the survey platforms were referenced to a GNSS base station placed on a nearby benchmark with known horizontal and vertical coordinates. Depths from the echosounders were computed using sound velocity profiles measured with a conductivity-temperature-depth (CTD) sensor during the survey. A total of 126 km of

  18. Influence of Grain Growth Inhibitors and Powder Size on the Properties of Ultrafine and Nanostructured Cemented Carbides Sintered in Hydrogen

    Directory of Open Access Journals (Sweden)

    Tamara Aleksandrov Fabijanić

    2016-08-01

    Full Text Available The influence of grain growth inhibitors and powder size on the microstructure and mechanical properties of ultrafine and nanostructured cemented carbides was researched. Three different WC powders, with an addition of different type and content of grain growth inhibitors GGIs, VC and Cr3C2 and with dBET grain sizes in the range from 95 to 150 nm were selected as starting powders. Four different mixtures with 6 and 9 wt. % Co were prepared. The consolidated samples are characterized by different microstructural and mechanical properties with respect to the characteristics of starting powders. Increased sintering temperatures led to microstructural irregularities in the form of a discontinuous WC growth, carbide agglomerates and abnormal grain growth as a consequence of coalescence via grain boundary elimination. The addition of 0.45% Cr3C2 contributed to microstructure homogeneity, reduced discontinuous and continuous grain growth, and increased Vickers hardness by approximately 70 HV and fracture toughness by approximately 0.15 MN/m3/2. The reduction of the starting powder to a real nanosize of 95 nm resulted in lower densities, and significant hardness increase, with a simultaneously small increase in fracture toughness. The consolidation of real nanopowders (dBET < 100 nm solely by conventional sintering in hydrogen without isostatic pressing is not preferred.

  19. Size-dependent optical properties of 9,10-bis(phenylethynyl)anthracene crystals

    Energy Technology Data Exchange (ETDEWEB)

    Yagita, Yoshimi; Matsui, Kazunori, E-mail: matsui@kanto-gakuin.ac.jp

    2015-05-15

    The optical properties of 9,10-bis(phenylethynyl)anthracene (BPEA) were studied for various states: nanoparticles (~100 nm), microcrystals (~1 μm), bulk crystals (~1 mm), and vacuum-deposited film. The absorption spectra showed a red shift from ethanol solution to bulk crystals with an increase in crystal size. The vacuum-deposited film seemed to have mixed spectral characteristics of nanoparticles and bulk crystals. The fluorescence of BPEA showed two peaks for the various crystals. The fluorescence of the shorter wavelength peak was shifted toward the blue from 556 to 527 nm from the bulk to nanoparticles. On the other hand, the position of the longest wavelength peak changed little, staying around 596 nm. The relative intensity of the former and latter increased with a decrease in the crystal size. The time-resolved fluorescence spectra clearly confirmed the existence of two emissive sites in the bulk crystals. These sites are probably located at the peripheral and inner positions of the crystals. Change in the relative proportions of the two sites could be the main reason for the size-dependent fluorescence. - Highlights: ●The optical properties of 9,10-bis(phenylethynyl)anthracene crystals were studied. ●The absorption spectra showed a red-shift with an increase in crystal size. ●The fluorescence spectra showed size-dependent and size-independent peaks. ●A size-dependent peak with a shorter decay is attributed to the surface molecules. ●A size-independent peak with a longer decay is attributed to the bulk crystals.

  20. Collecting, shipping, storing, and imaging snow crystals and ice grains with low-temperature scanning electron microscopy

    Science.gov (United States)

    Erbe, E.F.; Rango, A.; Foster, J.; Josberger, E.G.; Pooley, C.; Wergin, W.P.

    2003-01-01

    Methods to collect, transport, and store samples of snow and ice have been developed that enable detailed observations of these samples with a technique known as low-temperature scanning electron microscopy (LTSEM). This technique increases the resolution and ease with which samples of snow and ice can be observed, studied, and photographed. Samples are easily collected in the field and have been shipped to the electron microscopy laboratory by common air carrier from distances as far as 5,000 miles. Delicate specimens of snow crystals and ice grains survive the shipment procedures and have been stored for as long as 3 years without undergoing any structural changes. The samples are not subjected to the melting or sublimation artifacts. LTSEM allows individual crystals to be observed for several hours with no detectable changes. Furthermore, the instrument permits recording of photographs containing the parallax information necessary for three-dimensional imaging of the true shapes of snowflakes, snow crystals, snow clusters, ice grains, and interspersed air spaces. This study presents detailed descriptions of the procedures that have been used successfully in the field and the laboratory to collect, ship, store, and image snow crystals and ice grains. Published 2003 Wiley-Liss, Inc.

  1. A Visual Basic Program to Generate Sediment Grain-Size Statistics and Extrapolate Particle Distributions

    Science.gov (United States)

    Poppe, L. J.; Eliason, A. E.; Hastings, M. E.

    2004-05-01

    Methods that describe and summarize grain-size distributions are important to geologists because of the large amount of information contained in textural data sets. Therefore, to facilitate reduction of sedimentologic data, we have written a computer program (GSSTAT) to generate grain-size statistics and extrapolate particle distributions. Our program is written in Microsoft Visual Basic 6.0, runs on Windows 95/98/ME/NT/2000/XP computers, provides a window to facilitate execution, and allows users to select options with mouse-click events or through interactive dialogue boxes. The program permits users to select output in either inclusive graphics or moment statistics, to extrapolate distributions to the colloidal-clay boundary by three methods, and to convert between frequency and cumulative frequency percentages. Detailed documentation is available within the program. Input files to the program must be comma-delimited ASCII text and have 20 fields that include: sample identifier, latitude, longitude, and the frequency or cumulative frequency percentages of the whole-phi fractions from 11 phi through -5 phi. Individual fields may be left blank, but the sum of the phi fractions must total 100% (+/- 0.2%). The program expects the first line of the input file to be a header showing attribute names; no embedded commas are allowed in any of the fields. Error messages warn the user of potential problems. The program generates an output file in the requested destination directory and allows the user to view results in a display window to determine the occurrence of errors. The output file has a header for its first line, but now has 34 fields; the original descriptor fields plus percentages of gravel, sand, silt and clay, statistics, classification, verbal descriptions, frequency or cumulative frequency percentages of the whole- phi fractions from 13 phi through -5 phi, and a field for error messages. If the user has selected extrapolation, the two additional phi

  2. INFLUENCE OF AUSTENITE GRAIN SIZE TO DEVELOPMENT OF DECARBONIZATION IN PRODUCTION OF ROLLED STEEL

    Directory of Open Access Journals (Sweden)

    PARUSOV E. V.

    2016-08-01

    ]. The paper [11] acknowledges the influence of micro-additives of boron on changes in the austenite grain size and accordingly the length of borders in high-carbon steels with austenitizing temperature increase within the range of 900…1 100ºС. The purpose of work is to research the effect of austenite grain size on the decarburization depth in carbon (base steel and boron micro-alloyed steel.

  3. Boundary effects in finite