WorldWideScience

Sample records for crude oil spills

  1. Bacterial consortia for crude oil spill remediation

    International Nuclear Information System (INIS)

    Chhatre, S.; Purohit, H.; Shanker, R.; Khanna, P.

    1996-01-01

    Oil spills generate enormous public concern and highlight the need for cost effective ad environmentally acceptable mitigation technologies. Physico-chemical methods are not completely effective after a spill. Hence, there is a need for improved and alternative technologies. Bioremediation is the most environmentally sound technology for clean up. This report intends to determine the potential of a bacterial consortium for degradation of Gulf and Bombay High crude oil. A four membered consortium was designed that could degrade 70% of the crude oil. A member of consortium produced a biosurfactant, rhamnolipid, that emulsified crude oil efficiently for effective degradation by the other members of consortium. The wide range of hydrocarbonoclastic capabilities of the selected members of bacterial consortium leads to the degradation of both aromatic and aliphatic fractions of crude oil in 72 hours. (Author)

  2. Tanker spills Norwegian crude oil off Shetlands

    International Nuclear Information System (INIS)

    Anon.

    1993-01-01

    This paper reports that crude oil was spilling last week from the U.S. owned Braer tanker after the 89,000 dwt vessel ran aground on the south end of Scotland's Shetland Islands. Workers were trying to assess the extent of damage to the tanker, shoreline, and wildlife after the January 5 accident. Braer's cargo amounted to 607,000 bbl of Norwegian oil bound for Canada. Braer loaded its cargo and sailed January 3 from Den norske stats oljeselskap AS's Mongstad, Norway, terminal with crude from Gullfaks field in the Norwegian North Sea. The $11 million shipment was destined for Ultramar Canada Inc.'s 125,000 b/d refinery at St. Romuald, Que

  3. Bioremediation of crude oil spills in marine and terrestrial environments

    International Nuclear Information System (INIS)

    Prince, R.C.

    1995-01-01

    Bioremediation can be a safe and effective tool for dealing with crude oil spills, as demonstrated during the cleanup following the Exxon Valdez spill in Alaska. Crude oil has also been spilled on land, and bioremediation is a promising option for land spills too. Nevertheless, there are still areas where understanding of the phenomenon is rather incomplete. Research groups around the world are addressing these problems, and this symposium provides an excellent overview of some of this work

  4. Bioremediation potential of crude oil spilled on soil

    International Nuclear Information System (INIS)

    McMillen, S.J.; Young, G.N.; Davis, P.S.; Cook, P.D.; Kerr, J.M.; Gray, N.R.; Requejo, A.G.

    1995-01-01

    Spills sometimes occur during routine operations associated with exploration and production (E and P) of crude oil. These spills at E and P sites typically are small, less than 1 acre (0.4 ha), and the spill may be in remote locations. As a result, bioremediation often represents a cost-effective alternative to other cleanup technologies. The goal of this study was to determine the potential for biodegrading a range of crude oil types and determining the effect of process variables such as soil texture and soil salinity. Crude oils evaluated ranged in American Petroleum institute (API) gravity from 14 degree to 45 degree. The extent of biodegradation was calculated from oxygen uptake data and the total extractable material (TEM) concentration. Based on the data collected, a simple model was developed for predicting the bioremediation potential of a range of crude oil types. Biodegradation rates were significantly lower in sandy soils. Soil salinities greater than approximately 40 mmhos/cm adversely impacted soil microbial activity and biodegradation rate

  5. Environmental considerations in a high desert, crude oil pipeline spill

    International Nuclear Information System (INIS)

    Lowe, M.A.; Mancini, E.R.; Chamberlain, D.W.; Albright, G.R.

    1993-01-01

    A road grader punctured a high-pressure crude oil pipeline in the California high desert resulting in the release of approximately 4,200 barrels of Alaska North Slope crude oil. Oil sprayed over a steeply sloped hillside and flowed into an adjacent, densely vegetated ephemeral stream channel which carried secondary treatment sewage discharge. Three underflow dams were constructed in the channel within 2.8 km of the site. To ensure containment at the first dam, the sewage discharge was diverted from the channel, eventually to an upland impulse sprinkler irrigation system. Channel water and phase-separated ANS crude oil, impounded behind the first dam, percolated through alluvial sands/gravels to a depth of about five meters. The oil percolated through the soils on the receding surface of the water, affecting soils to an equivalent depth and saturating a horizontally narrow band of stream-bank soils as much as two to four meters into the bank. Stream channel undergrowth and a small number of mature trees were cleared to provide access for cleanup and/or to remove oiled plants. A large number of trees experienced partial leaf-drop within 25 days of the spill while two heavily oiled trees died. New vegetative growth was evident within five weeks of the spill. Site restoration included planting cuttings of five riparian tree species and hydroseeding exposed banks. Total petroleum hydrocarbon concentrations ranged from not detectable to 203,000 parts per million and averaged approximately 25,000 ppm in affected soils as sampled in place and in stockpiles. Approximately 30,000 tons of hydrocarbon-contaminated soil was excavated from the length of the stream channel (3,600 tons) as well as the area behind the first dam and spill site (26,400 tons). All soils were staged on site for waste profiling and final disposition. After treatment, the contaminated soil was beneficially reused as daily cover at a southern California landfill at a turnkey cost of approximately $57/ton

  6. Natural resource injury assessment of a crude oil spill

    International Nuclear Information System (INIS)

    Fischel, M.; Mancini, E.R.

    1995-01-01

    In January 1994, a 6.7 magnitude earthquake in southern California ruptured a pipeline releasing approximately 4,200 barrels of blended San Joaquin Valley crude oil. A smaller volume entered the Santa Clara River and flowed 25 km downstream to an emergency containment dam. Ruptured water mains and chlorinated discharges from a damaged sewage treatment plant also affected water quality in the river. Quantitative injury assessment studies were initiated within days of the spill and included water/sediment chemistry, benthic macroinvertebrate community analyses and aquatic toxicity tests. Water quality values for TPH, BTEX, and chlorine ranged from nondetectable to 78 mg/l (TPH), nondetectable to 5.4 microg/l (total BTEX constituents) and nondetectable to 600 microg/l (residual chlorine) within 72 hours of the spill. Ammonia concentrations ranged from nondetectable to 12.1 mg/l within 10 days of the spill. Hydrocarbon concentrations in sediments ranged from nondetectable to 3,900 mg/kg within 8 to 12 weeks post-spill. Both the density and diversity of benthic macroinvertebrates were reduced immediately after the spill but were not significantly different from reference areas four months later. River water collected from numerous locations within 72 hrs of the earthquake was transferred to the laboratory for static renewal acute toxicity tests using rainbow trout (Oncorhynchus mykiss) and threespine stickleback (Gasterosteus aculeatus). TPH concentrations in test containers ranged from nondetectable to 23 mg/l, BTEX constituents were nondetectable, and chlorine, measured at 600 microg/l in one sample, was titrated with sodium thiosulfate prior to testing. No acute toxicity was observed in either species

  7. Soil water repellency at old crude oil spill sites

    International Nuclear Information System (INIS)

    Roy, J.L.

    1999-08-01

    This thesis presents the current state of knowledge regarding the cause of soil water repellency and characterizes disaggregated nonwettable surface soils found at old crude oil spill sites. Pollution-induced water repellency generally develops following prolonged exposures of soil to liquid- or vapour-phase petroleum hydrocarbons. The condition varies significantly in terms of severity and persistence. Soil water repellency retards plant growth and disturbs the hydrological balance of ecosystems. Disaggregated water-repellent soils are also very susceptible to dispersal by erosion, posing a threat to the productivity of surrounding soils. The author described the probable causes of soil water repellency under the following three main themes: (1) accumulation of hydrophobic organic material in soil, (2) redistribution and re-organisation of this material in soil, and (3) stabilisation of the hydrophobic organic material. This final process is necessary to ensure persistence of induced water repellency symptoms. Petroleum residues as water-repellent substances in weathered nonwettable oil-contaminated soils were also discussed and a hypothesis about soil water repellency was presented which deals with flexible conformation in organic matter coatings. Processes leading to the development of soil water repellency following crude oil contamination were also described. It was determined that soil water repellency is a function of the packing density and the chain conformation of amphiphilic organic molecules in the outermost layer of soil organic matter coatings. This research suggests that the fractional coverage of alkyl chains on soil particle surfaces determines the degree of water repellency that is displayed by soil. It was shown that prompt remediation of some oil-contaminated plots can effectively prevent the development of soil water repellency. 4 refs., 32 tabs., 22 figs., 5 appendices

  8. Analysis of inland crude oil spill threats, vulnerabilities, and emergency response in the midwest United States.

    Science.gov (United States)

    Brody, Thomas M; Di Bianca, Paisly; Krysa, Jan

    2012-10-01

    Although coastal oil spills tend to be highly publicized, crude oil spills in the United States affect inland areas relatively often. Spills to inland areas often affect sensitive environments and can have greater impacts to health and welfare than spills to coastal areas. For these reasons, the authors investigated inland crude oil spill threats, vulnerabilities, and emergency response in the midwestern U.S. states of Illinois, Indiana, Michigan, Minnesota, Ohio, and Wisconsin. These states work with the Region 5 Offices of the U.S. Environmental Protection Agency. Region 5's geospatial data in the Inland Sensitivity Atlas were turned into metrics indicating inland crude oil spill threats and vulnerabilities among the Region's sub-watersheds. These threats and vulnerabilities were weighted using data from the National Response Center and the Department of Energy's Environmental Restoration Priority System. The locations of the Region's emergency responders were geocoded in GIS. The GIS calculated the emergency response times to the Region's sub-watersheds. The resulting scatter plots are connected to the sub-watersheds in the map so stakeholders can (1) see the outlying sub-watersheds of concern and (2) better understand how reducing threats and better response time can reduce the risk of inland crude oil spills. Published 2012. This article is a U.S. Government work and is in the public domain in the U.S.A.

  9. Potentially beneficial spill-related effects of chemicals routinely added to crude oils

    International Nuclear Information System (INIS)

    Ross, S.; Maharaj, S.

    1993-01-01

    Amoco Trinidad Oil Company produces 60,000 bbl/d of oil from the Trinidadian offshore. The oil is pipelined ashore where it is processed and returned offshore to a buoy mooring for transport up Trinidad's east coast. Amoco Trinidad has developed comprehensive oil spill contingency plans, starting from computer models of spill scenarios. The models used initially assumed that the oils would emulsify quickly and the spills would become highly viscous and persistent, reaching the shoreline in 15-24 h. Such behavior would render ineffective the use of dispersants as a spill countermeasure. Studies showed a poor potential capability of physical recovery systems for spills off the Trinidad east coast due to high sea states, strong winds, and other factors. These results led to questioning of the spill model's assumptions, and laboratory tests were conducted to study the actual behavior of the crude oils. It was found that the oil was difficult to emulsify and highly prone to breakup and dispersion. These surprising results were explained by the presence of surfactants added during processing. A revised modelling exercise showed that if the surfactants stay with the oil, spills up to 100,000 bbl will dissipate in 15 h or less at average wind conditions. To guard against the possibility that the surfactants may not stay with the spilled oil, and to help accelerate dispersion of oil spills, Amoco Trinidad has developed a dispersant-use capacity for its spill contingency plan. It is suggested that additives normally added to crude oils during production and processing in other areas may also be providing spill cleanup benefits similar to those found in the Trinidad case. 9 refs., 1 fig., 4 tabs

  10. Crude oil metabolites in groundwater at two spill sites

    Science.gov (United States)

    Bekins, Barbara A.; Cozzarelli, Isabelle M.; Erickson, Melinda L.; Steenson, Ross; Thorn, Kevin A.

    2016-01-01

    Two groundwater plumes in north central Minnesota with residual crude oil sources have 20 to 50 mg/L of nonvolatile dissolved organic carbon (NVDOC). These values are over 10 times higher than benzene and two to three times higher than Diesel Range Organics in the same wells. On the basis of previous work, most of the NVDOC consists of partial transformation products from the crude oil. Monitoring data from 1988 to 2015 at one of the sites located near Bemidji, MN show that the plume of metabolites is expanding toward a lakeshore located 335 m from the source zone. Other mass balance studies of the site have demonstrated that the plume expansion is driven by the combined effect of continued presence of the residual crude oil source and depletion of the electron accepting capacity of solid phase iron oxide and hydroxides on the aquifer sediments. These plumes of metabolites are not covered by regulatory monitoring and reporting requirements in Minnesota and other states. Yet, a review of toxicology studies indicates that polar metabolites of crude oil may pose a risk to aquatic and mammalian species. Together the results suggest that at sites where residual sources are present, monitoring of NVDOC may be warranted to evaluate the fates of plumes of hydrocarbon transformation products.

  11. Salt marsh recovery from a crude oil spill: Vegetation, oil weathering, and response

    International Nuclear Information System (INIS)

    Hoff, R.Z.; Shigenaka, G.; Henry, C.B. Jr.

    1993-01-01

    When a spill of Prudhoe Bay crude oil covered a fringing Salicornia virginica marsh in Fidalgo Bay, Washington (northern Puget Sound) in February 1991, response personnel used several low-impact techniques to remove oil from the marsh, and minimized access by cleanup workers. Following the response, a monitoring program was established to track marsh recovery, and to document the effectiveness of the response techniques used and their impacts on the marsh. Through monthly sampling over a 16-month period, vegetative growth was monitored and chemical degradation of remaining oil was tracked. Sampling was conducted along transects located in four areas affected in different ways by the spill, including an oiled, trampled section; an oiled, vacuumed section; and an oiled, washed, and vacuumed section. In addition, a control transect was established in an unoiled adjacent marsh. The study included both biological and chemical components. Biological measurements included percent cover of live vegetation (sampled monthly) and below-ground plant biomass (sampled at the beginning of each growing season in April 1991 and April 1992). Sediment samples included surface sediment (monthly) and core samples collected at the beginning and end of the growing seasons. Sediment samples were analyzed using gas chromatography/mass spectroscopy, and indicator compounds were tracked to determine rates of oil degradation. Results from 16 months of post-spill monitoring show that foot trampling was most detrimental to marsh plants, while washing with vacuuming removed the most oil and minimized adverse impacts to vegetation. Dense clay substrate helped prevent oil from penetrating the sediment, thus minimizing acute toxic effects from oil exposure to marsh plant rootstock. By the second growing season post-spill, Salicornia and other marsh plants were growing in all areas except one heavily oiled patch

  12. Low level exposure to crude oil impacts avian flight performance: The Deepwater Horizon oil spill effect on migratory birds.

    Science.gov (United States)

    Perez, Cristina R; Moye, John K; Cacela, Dave; Dean, Karen M; Pritsos, Chris A

    2017-12-01

    In 2010, the Deepwater Horizon oil spill released 134 million gallons of crude oil into the Gulf of Mexico making it the largest oil spill in US history. The three month oil spill left tens of thousands of birds dead; however, the fate of tens of thousands of other migratory birds that were affected but did not immediately die is unknown. We used the homing pigeon as a surrogate species for migratory birds to investigate the effects of a single external oiling event on the flight performance of birds. Data from GPS data loggers revealed that lightly oiled pigeons took significantly longer to return home and spent more time stopped en route than unoiled birds. This suggests that migratory birds affected by the oil spill could have experienced long term flight impairment and delayed arrival to breeding, wintering, or crucial stopover sites and subsequently suffered reductions in survival and reproductive success. Copyright © 2017 Elsevier Inc. All rights reserved.

  13. Oil spills

    International Nuclear Information System (INIS)

    Katsouros, M.H.

    1992-01-01

    The world annually transports 1.7 billion tons of oil by sea, and oil spills, often highly concentrated discharges, are increasing from a variety of sources. The author discusses sources of oils spills: natural; marine transportation; offshore oil production; atmospheric sources; municipal industrial wastes and runoff. Other topics include: the fate of the spilled oil; the effects of the oil; the response to oil spills; and prevention of oil spills. 30 refs., 1 fig., 4 tabs

  14. Physical aspects of crude oil spills on northern terrain. Task Force on Northern Oil Development, Report No. 74-25

    Energy Technology Data Exchange (ETDEWEB)

    Mackay, D; Charles, M E; Phillips, C R

    1974-01-01

    The physical aspects of crude oil spills on the terrain of the Mackenzie Valley were investigated. The aqueous solubility of Norman Wells crude oil has been determined and it has been established that about half of the dissolved hydrocarbon is aromatic. The distribution of hydrocarbons between the oil and aqueous phases is in good agreement with predicted values. The permeability of the surface terrain to oil at Norman Wells was found to decrease very rapidly with depth below the surface. A simple, in-situ method for determination of the profile was developed. The implication of the results is that flow will occur more readily near the surface than near the basement. The spreading rates of two crude oils on water were studied on two lakes near Inuvik. Pembina crude oil showed only one spreading front, whereas Norman Wells crude oil showed a bulk front preceded by a surface-slick. Once the initial separation occurred, wind drove both fronts across the water at about 6 percent of the wind speed. The area of surface-active contamination was several times the area of the bulk oil film. The isothermal spreading of five crude oils on ice under gravity-viscous conditions was examined. The radius of the slick was found to increase linearly with the ratio (time/viscosity)/sup /sup 1///sub 5//. Surface roughness effects were negligible. An attempt has been made to predict the behavior of a 50,000 barrel oil spill in the taiga region of the Mackenzie Valley, under both summer and winter conditions. The areas affected and the amounts of hydrocarbon evaporated were predicted. These predictions are valuable in providing a scenario of an oil spill incident which will assist in assessing the environmental impact of oil spills in the Mackenzie Valley and in preparing for clean-up measures. Burning as a clean-up procedure considered in some detail. Other methods specifically designed for Arctic conditions will probably prove more satisfactory.

  15. Analysis of soil chemical parameters of an uncleaned crude oil spill ...

    African Journals Online (AJOL)

    Analysis of soil chemical parameters of an uncleaned crude oil spill site at Biara was carried out. Soil samples were collected at 0 -15 cm and 15 – 30 cm soil depths from both polluted and unpolluted sites for analysis. Significant increase in high total hydrocarbon content (1015±80.5 – 1150±90.1 mg/kg) in polluted site was ...

  16. Oil Spills

    Science.gov (United States)

    Oil spills often happen because of accidents, when people make mistakes or equipment breaks down. Other causes include natural disasters or deliberate acts. Oil spills have major environmental and economic effects. Oil ...

  17. Evaporation of Arabian light crude oil spilled on sea and on beach sands : influence of solar radiation and wind velocity

    International Nuclear Information System (INIS)

    Bergueiro, J.R.; Marti, A.; Fuertes, A.; Moreno, S.; Guijarro, S.

    1998-01-01

    The evaporation of crude oil resulting from a spill on sea water was studied to develop a simulation model. Evaporation takes place within a complex process of mass and energy transfer. The effects of physical and chemical variables (such as wind velocity and direct and diffused solar radiation) and the environmental conditions of the spillage were also considered. Arabian crude oil was used in the simulation model for crude oil spillage on sea water. An equation for the evaporation process was used to correlate the evaporated fraction of oil as a function of time. The area of spreading was determined as a function of the dominant stage at each moment of spreading. The evaporation of spilled crude oil on beach sand consisting of three different particle sizes was also studied and used for a simulation model for crude oil spillage on a polluted beach. 7 refs., 6 tabs., 10 figs

  18. Oil Spills

    Science.gov (United States)

    ... up. How Oil Harms Animals and Plants in Marine Environments In general, oil spills can affect animals and plants in two ways: from the oil ... up. How Oil Harms Animals and Plants in Marine Environments In general, oil spills can affect animals and plants in two ways: from the oil ...

  19. Accidental pollution in the ocean: besides crude oil, chemicals and other spills

    International Nuclear Information System (INIS)

    Marchand, M.

    2003-01-01

    Accidental pollution of the seas is usually illustrated by the shipwreck of tankers carrying crude oil. We must look beyond this image since such accidents spill substances other than petrochemicals. We need but mention the Levoli Sun's accident near the Cotentin peninsula, France, one year after the Erika went down. And what about spills of agricultural and food products? An accidental spill as apparently harmless as wheat might have serious effects on not just the environment but also human health. In all cases, two major series of questions crop up: 1) Is it necessary to intervene? If so, are we able to? And if we can, how to fight against spills? 2) What are the short- and long-term effects on the environment and on all human activities related to the sea (fishing, fish-farming, salt production, tourism, salt-water cures, etc.)? These two questions have a common denominator: the need to know how spilled products react. This knowledge conditions both the operational response for fighting against pollution and the assessment of the impact on the maritime environment. (author)

  20. Studies on the dissolution and long term weathering of spilled crude oils

    Energy Technology Data Exchange (ETDEWEB)

    Mackay, D; Charles, M E; Sumchi, Lee; Lun, R; Ooijen, H van; Romocki, K; Harner, T; Ralfs, M

    1993-04-01

    The development of a laboratory system for the study of the long term behavior of crude oil on a water surface is described. The apparatus consists of a cylindrical glass vessel containing water which is rotated at 33 rpm, thus creating a concave surface in which oil tends to accumulate at the center. Turbulence is induced by a stationary stirrer. Results are described of tests conducted with a number of crude oils and it is concluded that the system is able to create reproducible conditions of controlled evaporation, dissolution, turbulence, photolysis, and oil in water emulsion formation. A major advantage of the system is its simplicity and robustness which permits prolonged exposure of the oil to simulate weathering, over periods of weeks and months. A second system is described which can be used to determine the concentrations of dissolved hydrocarbons under oil slicks by in-situ headspace analysis. A prototype submersible sparger sampling system was devised and tested, and results are presented. It is concluded that the system is a promising and practical method of determining the extent to which dissolved hydrocarbons are present in water at various depths under an oil slick. In both cases it is concluded that the concepts have sufficient merit that further work is justified. Recommendations are made for further research and development which will, it is hoped, enable these systems to be used to investigate aspects of the fate and effects of oil spills at sea. 6 refs., 14 figs., 4 tabs.

  1. Response, remediation and risk management of a crude oil pipeline spill

    International Nuclear Information System (INIS)

    Rose, P.A.; Livingstone, W.R.

    1997-01-01

    A light crude oil spill occurred along a section of pipeline near the bank of a major river of a southern Alberta community in December of 1995. Crude oil was observed at ground surface over an area of 2,000 sq m at the top of the river slope. It had also migrated down slope through the subgrade soils and along the groundwater table toward the river. The initial emergency response measures included removing and disposing of oil-stained vegetation and snow, and the containment and recovery of free oil pooled on the ground surface. Other measures included the drilling of test holes and boreholes and the installation of groundwater monitoring and recovery wells. It was determined that phase-separated crude oil had accumulated at the water table within the flood plain sediments near the river. The water was remediated on-site to Canadian drinking water quality standards. The zone of impacted water was effectively captured, and ground water quality steadily improved

  2. Assessing field-scale biogeophysical signatures of bioremediation over a mature crude oil spill

    Science.gov (United States)

    Slater, Lee; Ntarlagiannis, Dimitrios; Atekwana, Estella; Mewafy, Farag; Revil, Andre; Skold, Magnus; Gorby, Yuri; Day-Lewis, Frederick D.; Lane, John W.; Trost, Jared J.; Werkema, Dale D.; Delin, Geoffrey N.; Herkelrath, William N.; Rectanus, H.V.; Sirabian, R.

    2011-01-01

    We conducted electrical geophysical measurements at the National Crude Oil Spill Fate and Natural Attenuation Research Site (Bemidji, MN). Borehole and surface self-potential measurements do not show evidence for the existence of a biogeobattery mechanism in response to the redox gradient resulting from biodegradation of oil. The relatively small self potentials recorded are instead consistent with an electrodiffusion mechanism driven by differences in the mobility of charge carriers associated with biodegradation byproducts. Complex resistivity measurements reveal elevated electrical conductivity and interfacial polarization at the water table where oil contamination is present, extending into the unsaturated zone. This finding implies that the effect of microbial cell growth/attachment, biofilm formation, and mineral weathering accompanying hydrocarbon biodegradation on complex interfacial conductivity imparts a sufficiently large electrical signal to be measured using field-scale geophysical techniques.

  3. Recovery of Arctic and Sub-Arctic vegetation nine summers after crude and diesel oil spills

    National Research Council Canada - National Science Library

    Hutchinson, T. C

    1984-01-01

    In August 1980 experimental oil spill sites set up in spruce taiga at Norman Wells and on tundra at Tuktoyaktuk from 1972-75 were monitored to determine degree of recovery of vegeta tion from summer & winter spills...

  4. Research on a dispersing solution for burnt crude oils: Aegean Sea oil spill

    International Nuclear Information System (INIS)

    Bergueiro, J.R.; Morales, N.; Dominguez, F.

    1993-01-01

    The oil tanker Aegean Sea spilled oil when it grounded during severe storm conditions near La Coruna, Spain. Much of the oil burned after an explosion was caused by the hull breaking apart. Oil which contaminated several beaches was affected by both combustion and weathering. Experiments were conducted on oil sampled from the beaches to investigate dispersion of the oil using Beep Enersperse 1990 at different shaking speeds. Biodegradation experiments were also conducted in the presence of Beep Enersperse 1990 but with seawater absent. Although emulsification of the burnt and weathered oil was very difficult, good dispersion and biodegradation were obtained. After 42 d in a stirred reactor, biodegradation of the oil reached at least 80%. 3 refs., 3 figs., 4 tabs

  5. Multiphase flow modeling of a crude-oil spill site with a bimodal permeability distribution

    Science.gov (United States)

    Dillard, Leslie A.; Essaid, Hedeff I.; Herkelrath, William N.

    1997-01-01

    Fluid saturation, particle-size distribution, and porosity measurements were obtained from 269 core samples collected from six boreholes along a 90-m transect at a subregion of a crude-oil spill site, the north pool, near Bemidji, Minnesota. The oil saturation data, collected 11 years after the spill, showed an irregularly shaped oil body that appeared to be affected by sediment spatial variability. The particle-size distribution data were used to estimate the permeability (k) and retention curves for each sample. An additional 344 k estimates were obtained from samples previously collected at the north pool. The 613 k estimates were distributed bimodal lognormally with the two population distributions corresponding to the two predominant lithologies: a coarse glacial outwash deposit and fine-grained interbedded lenses. A two-step geostatistical approach was used to generate a conditioned realization of k representing the bimodal heterogeneity. A cross-sectional multiphase flow model was used to simulate the flow of oil and water in the presence of air along the north pool transect for an 11-year period. The inclusion of a representation of the bimodal aquifer heterogeneity was crucial for reproduction of general features of the observed oil body. If the bimodal heterogeneity was characterized, hysteresis did not have to be incorporated into the model because a hysteretic effect was produced by the sediment spatial variability. By revising the relative permeability functional relation, an improved reproduction of the observed oil saturation distribution was achieved. The inclusion of water table fluctuations in the model did not significantly affect the simulated oil saturation distribution.

  6. Oil spills

    International Nuclear Information System (INIS)

    Spaulding, M.L.; Reed, M.

    1990-01-01

    Public awareness and concern for the potential short and long term impacts of oil spills on the marine environment has generally been high, particularly for regions of special ecological importance or where significant numbers of marine mammals and birds are present. This awareness was further heightened by the extraordinary number of recent large spills in coastal U.S. water: Exxon Valdez, Alaska; World Prodigy, Rhode Island; Presidente Rivera, Delaware; Rachel-B, Texas and American Trader, California. The occurrence of so many spills in a one year period is unprecedented in U.S. spill history. The legislative response to these spills has been immediate. New legislative initiative are rapidly being developed. Improved ways to organize spill response efforts are being devised and implemented. Funds are being allocated to further develop and improve spill response equipment and damage assessment methodologies. These spill events will have a significant impact in both the short and long term on oil exploration, development and transport in marine waters. They will result in major changes in management and operation of oil exploration and development. The purpose of this conference was to provide a forum for discussion of the changes which are currently taking place in oil spill legislation, management, and response strategies

  7. A population genetic analysis of the potential for a crude oil spill to induce heritable mutations and impact natural populations

    Energy Technology Data Exchange (ETDEWEB)

    Cronin, M.A. [LGL Alaska Research Associates Inc., Anchorage, AK (United States); Bickham, J.W. [Texas A and M University, College Station, TX (United States). Dept. of Wildlife and Fisheries Sciences; LGL Ecological Genetics Inc., Bryan, TX (United States)

    1998-07-01

    The primary environmental impact following an oil spill typically is acute toxicity to fish and wildlife. However, multigenerational effects through toxicant-induced heritable mutations might also occur. Some polycyclic aromatic hydrocarbon (PAH) components of crude oil are potentially mutagenic, although specific components and doses that induce mutations are poorly known. We applied population genetics concepts to assess the extent of mortality and the persistence of deleterious heritable mutations resulting from exposure to potential mutagens, such as crude oil. If lethal mutations are induced, the population will experience some mortality, but the mutations are quickly removed or reduced to low frequency by natural selection. This occurs within one or a few generations when mutations are dominant or partially recessive. Totally recessive alleles persist in low frequency for many generations, but result in relatively little impact on the population, depending on the number of mutated loci. We also applied population genetics concepts to assess the potential for heritable mutations induced by the Exxon Valdez oil spill in Prince William Sound, Alaska, to affect pink salmon populations. We stress that breeding units (e.g., streams with distinct spawning populations of salmon) must be considered individually to assess heritable genetic effects. For several streams impacted by the oil spill, there is inconsistency between observed egg mortality and that expected if lethal heritable mutations had been induced by exposure to crude oil. Observed mortality was either higher or lower than expected depending on the spawning population, year, and cohort considered. Any potential subtle effect of lethal mutations induced by the Exxon Valdez oil spill is overridden by natural environmental variation among spawning areas. We discuss the need to focus on population-level effects in toxicological assessments because fish and wildlife management focuses on populations, not

  8. When oil spills emulsify

    International Nuclear Information System (INIS)

    Bobra, M.; Fingas, M.; Tennyson, E.

    1992-01-01

    Cleanup operations of oil spills must take into account the numerous detrimental effects attributable to the emulsification of spilled oil into a stable water-in-oil mousse. The incorporation of water greatly increases the volume of the polluted material. The viscous nature of mousse impedes the efficient operation of most mechanical recovery equipment and results in a cohesive slick that resists dispersion, both natural and artificial. The rate at which spilled oil emulsifies determines the effective window of opportunity for specific countermeasures. Much has been learned from previous studies on petroleum emulsification, but is still remain a poorly understood phenomenon. Although most crude oils can be emulsified, not all spills result in the formation of stable mousse. The formation of mousse results from a complex series of processes. Whether an oil will form mousse or not, and if so, at what rate, depends on an array of different factors including the properties of the oil and the prevailing environmental conditions. We need a greater understanding of the emulsification process to better predict the emulsification behavior of oil spills and utilize the most appropriate countermeasures available. In this paper, the authors report on work to elucidate the role that physicochemical factors play in determining an oil's tendency to emulsify. The authors studied the emulsification behavior of oils of known composition to examine the importance of oil chemistry in the emulsification process

  9. Comparing ignitability for in situ burning of oil spills for an asphaltenic, a waxy and a light crude oil as a function of weathering conditions under arctic conditions

    DEFF Research Database (Denmark)

    Fritt-Rasmussen, Janne; Brandvik, Per Johan; Villumsen, Arne

    2012-01-01

    (asphalthenic), Kobbe (light oil) and Norne (waxy), for ignitability as a function of ice conditions and weathering degree. The crude oils (9 L) were weathered in a laboratory basin (4.8 m3) under simulated arctic conditions (0, 50 and 90% ice cover). The laboratory burning tests show that the ignitability...... is dependent on oil composition, ice conditions and weathering degree. In open water, oil spills rapidly become “not ignitable” due to the weathering e.g. high water content and low content of residual volatile components. The slower weathering of oil spills in ice (50 and 90% ice cover) results in longer time......-windows for the oil to be ignitable. The composition of the oils is important for the window of opportunity. The asphalthenic Grane crude oil had a limited timewindow for in situ burning (9 h or less), while the light Kobbe crude oil and the waxy Norne crude oil had the longest time-windows for in situ burning (from...

  10. Successful social environmental management model, implemented in Ecuador to overcome impacts from a heavy crude oil spill

    Energy Technology Data Exchange (ETDEWEB)

    Aleman, Miguel Angel; Bermeo, Ramiro; Mendizabal, Andres; Loon, Wong [ENTRIX Inc. Branch, Quito (Ecuador)

    2010-07-01

    An oil spill of 11,700 barrels of heavy crude oil occurred at an OCP Ecuador S.A. pipeline in a high biodiversity area in eastern Ecuador on February 25, 2009. The pipeline breakage was due to stress caused by an earth movement. The aim of this paper is to present the methodology used by the company for the emergency response. First of all, medical assistance was provided to the inhabitants of the area as a safety precaution and water was distributed to them while other workers contained the spill and cleaned the area. Residents were then offered temporary jobs participating in the cleaning efforts. Throughout the cleanup process, the media and the population were kept informed of how the process was progressing in an open and transparent manner. This methodology ensured the success of the cleanup and restoration work in a timely manner and this methodology can now be used and further developed for handling future events.

  11. Successful social environmental management model, implemented in Ecuador to overcome impacts from a heavy crude oil spill

    International Nuclear Information System (INIS)

    Aleman, Miguel Angel; Bermeo, Ramiro; Mendizabal, Andres; Loon, Wong

    2010-01-01

    An oil spill of 11,700 barrels of heavy crude oil occurred at an OCP Ecuador S.A. pipeline in a high biodiversity area in eastern Ecuador on February 25, 2009. The pipeline breakage was due to stress caused by an earth movement. The aim of this paper is to present the methodology used by the company for the emergency response. First of all, medical assistance was provided to the inhabitants of the area as a safety precaution and water was distributed to them while other workers contained the spill and cleaned the area. Residents were then offered temporary jobs participating in the cleaning efforts. Throughout the cleanup process, the media and the population were kept informed of how the process was progressing in an open and transparent manner. This methodology ensured the success of the cleanup and restoration work in a timely manner and this methodology can now be used and further developed for handling future events.

  12. Physical and biological effects of experimental crude oil spills on Low Artic tundra in the vicinity of Tuktoyaktuk, N. W. T. , Canada

    Energy Technology Data Exchange (ETDEWEB)

    Freedman, W.; Hutchinson, T.C.

    1976-10-01

    Data are presented on the effects of simulated crude oil spills on two Low Arctic terrestrial tundra plant communities near Tuktoyaktuk, Northwest Territories. Spills of fresh, unweathered crude oil had a general herbicidal effect, resulting in rapid damage to, and subsequent death of, all aboveground actively growing foliage coming in contact with the oil. Most species were defoliated. Mosses and lichens were especially susceptible and killed. However, within several weeks of the summer oil spillages, a limited number of relatively tolerant vascular plant species began to develop regrowth shoots. Summer spills were markedly more damaging than were equivalent spills made in winter. No increases were seen in active layer depth from spills made in summer. However, winter spills on one of the two sites did show consistent and statistically significant (P > 0.01) increases in depth of thaw. Examination of several key energy budget parameters at these field sites indicated consistently lower albedos and evapotranspiration and consistently higher soil surface temperatures and soil heat flux at all oil spill sites, relative to their controls. However, except for a winter spill on one site, the recorded differences were not sufficiently large in magnitude to produce significant increases in active layer thaw depths.

  13. Ecologically friendly ways to clean up oil spills in harbor water areas: crude oil and diesel sorption behavior of natural sorbents.

    Science.gov (United States)

    Paulauskiene, Tatjana

    2018-04-01

    This work aimed to evaluate the sorption capacity of natural sorbents (wool, moss, straw, peat) and their composites during the sorption of crude oil and of diesel overspread on the water surface. The work presents the research results of the maximum sorption capacity of the sorbents/their composites using crude oil/diesel; the sorption capacity of the sorbents/their composites when crude oil/diesel is spilled on the water surface; and the research results of the unrealized part of the crude oil/diesel in the sorbents. The results of the analysis showed that all the sorbents and their composites have their selectivity to crude oil less than 50%. Also the results showed that the distribution of diesel and water in the sorbents and their composites is very different compared with the distribution of crude oil during the sorption analyses. In total, the diesel in the liquid mass absorbed by the straw and the peat amounted to 17 and 20%, respectively. This shows that these sorbents are much more selective for water but not for diesel. A larger part of the diesel was in the liquid amount absorbed by the composites-up to 33%. Accordingly, the use of these composites in watery environments is much more effective than the use of individual sorbents. The composition of sorbents in the composite enhanced both the hydrophobic and the oleophilic properties; as a result, a more effective removal of the diesel and oil from the water surface was achieved.

  14. Effect of duration of exposure to polluted air environment on lung function in subjects exposed to crude oil spill into sea water.

    Science.gov (United States)

    Meo, Sultan Ayoub; Al-Drees, Abdul Majeed; Rasheed, Shahzad; Meo, Imran Mu; Khan, Muhammad Mujahid; Al-Saadi, Muslim M; Alkandari, Jasem Ramadan

    2009-01-01

    Oil spill in sea water represents a huge environmental disaster for marine life and humans in the vicinity. The aim was to investigate the effect of duration of exposure to polluted air environment on lung function in subjects exposed to crude oil spill into sea water. The present study was conducted under the supervision of Department of Physiology, College of Medicine, King Khalid University Hospital, King Saud University, Riyadh, Saudi Arabia, during the period July 2003 - December 2004. This was a comparative study of spirometry in 31 apparently healthy, non smoking, male workers, exposed to crude oil spill environment during the oil cleaning operation. The exposed group was matched with similar number of male, non smoking control subjects. Pulmonary function test was performed by using an electronic spirometer. Subjects exposed to polluted air for periods longer than 15 days showed a significant reduction in Forced Vital Capacity (FVC), Forced Expiratory Volume in First Second (FEV1), Forced Expiratory Flow in 25-25% (FEF25-75%) and Maximal Voluntary Ventilation (MVV). Air environment polluted due to crude oil spill into sea water caused impaired lung function and this impairment was associated with dose response effect of duration of exposure to air polluted by crude oil spill into sea water.

  15. Field-scale evidence for biogeophysical signatures resulting from natural attenuation of a well characterized crude oil spill

    Science.gov (United States)

    Slater, L. D.; Revil, A.; Atekwana, E. A.; Mewafy, F.; Bekins, B. A.; Cozzarelli, I.; Herkelrath, W. N.; Skold, M.; Ntarlagiannis, D.; Trost, J.; Erickson, M.; Heenan, J. W.; Lane, J. W.; Werkema, D. D.

    2012-12-01

    Recent biogeophysical research has indicated that unique geophysical signatures are associated with the long-term biodegradation of organic contaminants. However, field-scale demonstrations of the presence of these signatures at sites of organic contamination are lacking. For the last three years, we have performed geophysical measurements at the National Crude Oil Spill Fate and Natural Attenuation Research Site, a unique field laboratory situated just outside of Bemidji, MN. At this site, a ruptured pipeline spilled 1,700,000 L of crude oil into an uninhabited area in 1979. Natural attenuation of the spill has been extensively documented and a geochemical database extending back over 20 years is available to constrain interpretation of the geophysical signatures. We report compelling evidence of a transient geobattery associated with biodegradation of this mature hydrocarbon spill. Using an array of boreholes, self-potential measurements acquired from land surface, passing through the smear zone, capture a diagnostic dipole (peak to peak voltages up to 64 mV) indicating a current source centered on the smear zone, with anodic and cathodic reactions below and above the smear zone respectively. Down borehole measurements reveal that the smear zone is characterized by high magnetic susceptibility (MS); laboratory measurements show that this MS enhancement results from precipitation of iron mineral byproducts of biodegradation. These iron minerals presumably facilitate the electron transport between anode and cathode required to support a geobattery. Furthermore, laboratory and field-scale complex resistivity measurements reveal an enhancement in the complex surface conductivity within the smear zone most likely due to these biodegradation byproducts. The geobattery is not permanent, but instead periodically shuts down, presumably due to changes in the gradient of the redox species driving anodic and cathodic reactions. Gas samples show that conditions are anaerobic

  16. Oil spill clean up

    International Nuclear Information System (INIS)

    Claxton, L.D.; Houk, V.S.; Williams, R.; Kremer, F.

    1991-01-01

    Due to the consideration of bioremediation for oil spills, it is important to understand the ecological and human health implications of bioremediation efforts. During biodegradation, the toxicity of the polluting material may actually increase upon the conversion of non-toxic constituents to toxic species. Also, toxic compounds refractory to biological degradation may compromise the effectiveness of the treatment technique. In the study, the Salmonella mutagenicity assay showed that both the Prudhoe Bay crude oil and its weathered counterpart collected from oil-impacted water were weakly mutagenic. Results also showed that the mutagenic components were depleted at a faster rate than the overall content of organic material

  17. Evaluation of the Safety Issue Concerning the Potential for Loss of Decay Heat Removal Function due to Crude Oil Spill in the Ultimate Heat Sink of Nuclear Reactors

    International Nuclear Information System (INIS)

    Jo, Jong Chull; Roh, Kyung Wan; Yune, Young Gill; Kang, Dong Gu; Kim, Hho Jhung

    2008-01-01

    A barge crashed into a moored oil tanker at about 7:15 a.m., Dec. 12, 2007, dumping around 10,500 tons of crude oil into the sea in Korea. The incident took place about 15 kilometers northwest of Manripo beach in South Chungcheong where is Korea's west coast in the Yellow Sea. In a few days, the oil slicks spread to the northern and southern tips of the Taean Peninsula by strong winds and tides. As time went the spilled oil floating on the surface of sea water was volatilized to become tar-balls and lumps and drifted far away in the southern direction. 13 days after the incident, some of oil slicks and tar lumps were observed to flow in the service water intake at the Younggwang nuclear power plants (NPPs) operating 6 reactors, which are over 150 km away from the incident spot in the southeastern direction. According to the report by the Younggwang NPPs, a total weight 83 kg of tar lumps was removed for about 3 days. Oil spills in the sea can happen in any country or anytime due to human errors or mistakes, wars, terrors, intentional dumping of waste oils, and natural disasters like typhoon and tsunami. In fact, there have been 7 major oil spills over 10,000 tons that have occurred around the world since 1983. As such serious oil spill incidents may happen near the operating power plants using the sea water as ultimate heat sink. To ensure the safe operation of nuclear reactors it is required to evaluate the potential for loss of decay heat removal function of nuclear reactors due to the spilled oils flowing in the service water intake, from which the service water is pumped. Thus, Korea Institute of Nuclear Safety identified this problem as one of the important safety. When an incident of crude oil spill from an oil carrier occurs in the sea near the nuclear power plants, the spilled oil can be transported to the intake pit, where all service water pumps locate, by sea current and wind drift (induced) current. The essential service water pumps take the service

  18. Evaluation of the Safety Issue Concerning the Potential for Loss of Decay Heat Removal Function due to Crude Oil Spill in the Ultimate Heat Sink of Nuclear Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Jo, Jong Chull; Roh, Kyung Wan; Yune, Young Gill; Kang, Dong Gu; Kim, Hho Jhung [Korea Institute of Nuclear Safety, Daejeon (Korea, Republic of)

    2008-05-15

    A barge crashed into a moored oil tanker at about 7:15 a.m., Dec. 12, 2007, dumping around 10,500 tons of crude oil into the sea in Korea. The incident took place about 15 kilometers northwest of Manripo beach in South Chungcheong where is Korea's west coast in the Yellow Sea. In a few days, the oil slicks spread to the northern and southern tips of the Taean Peninsula by strong winds and tides. As time went the spilled oil floating on the surface of sea water was volatilized to become tar-balls and lumps and drifted far away in the southern direction. 13 days after the incident, some of oil slicks and tar lumps were observed to flow in the service water intake at the Younggwang nuclear power plants (NPPs) operating 6 reactors, which are over 150 km away from the incident spot in the southeastern direction. According to the report by the Younggwang NPPs, a total weight 83 kg of tar lumps was removed for about 3 days. Oil spills in the sea can happen in any country or anytime due to human errors or mistakes, wars, terrors, intentional dumping of waste oils, and natural disasters like typhoon and tsunami. In fact, there have been 7 major oil spills over 10,000 tons that have occurred around the world since 1983. As such serious oil spill incidents may happen near the operating power plants using the sea water as ultimate heat sink. To ensure the safe operation of nuclear reactors it is required to evaluate the potential for loss of decay heat removal function of nuclear reactors due to the spilled oils flowing in the service water intake, from which the service water is pumped. Thus, Korea Institute of Nuclear Safety identified this problem as one of the important safety. When an incident of crude oil spill from an oil carrier occurs in the sea near the nuclear power plants, the spilled oil can be transported to the intake pit, where all service water pumps locate, by sea current and wind drift (induced) current. The essential service water pumps take the

  19. Histopathologic lesions associated with crude oil exposure in sea otters. Marine mammal study 6-10. Exxon Valdez oil spill state/federal natural resources damage assessment final report

    Energy Technology Data Exchange (ETDEWEB)

    Lipscomb, T.P.; Harris, R.K.; Moeller, R.B.; Pletcher, J.M.; Haebler, R.J.

    1996-06-01

    Following the Exxon Valdez oil spill in Prince William Sound, Alaska, sea otters (Enhydra lutris) that appeared oiled, were in danger of becoming oiled, or were behaving abnormally were captured and taken to rehabilitation centers. Oil exposure was assessed by visual examination on arrival at the centers. Tissues from 51 oiled sea otters and from 6 unoiled sea otters that died in rehabilitation centers were examined histologically. Histologic examinations were performed on tissues from 5 sea otters found dead with external oil present shortly after the spill. Necropsies were performed on 214 sea otters that had been collected and frozen in the period following the oil spill. Tissues from 6 apparently normal sea otters collected from an area not affected by the oil spill were examined histologically, and none of these lesions were found. We conclude that pulmonary interstitial emphysema, gastric erosion and hemorrhage, centrilobular hepatic necrosis, and hepatic and renal lipidosis were associated with exposure to crude oil in sea otters.

  20. Consensus Ecological Risk Assessment of Potential Transportation-related Bakken and Dilbit Crude Oil Spills in the Delaware Bay Watershed, USA

    Directory of Open Access Journals (Sweden)

    Ann Hayward Walker

    2016-03-01

    Full Text Available Unconventionally-produced crude oils, i.e., Bakken oil and bitumen diluted for transport and known as dilbit, have become prominent components of the North American petroleum industry. Spills of these oils have occurred during transport from production areas to refineries via pipeline, rail, and barge. Some of their physical and chemical properties are distinct and present new challenges in mitigating spill impacts on people and the environment. This paper describes the adaptation of a qualitative risk assessment process to improve spill preparedness and response decisions for these oils when transported in an estuarine area. The application of this collaborative, interdisciplinary process drew upon a literature review, the local knowledge and experience of a broad set of decision makers, practitioners, and technical experts who developed consensus-based recommendations aimed at improving response to spills of these oils. Two emphasized components of this consensus ecological risk assessment (CERA concerned risks: (1 to human health and safety and (2 from spilled oil and the associated response actions on endangered species. Participants in the process defined levels of concern associated with Bakken and dilbit oils relative to a set of response actions in freshwater, brackish and saltwater habitats and on resources at risk.

  1. Bioremediation of oil spills

    International Nuclear Information System (INIS)

    Foght, J.M.; Westlake, D.W.S.

    1992-01-01

    In-situ bioremediation of crude oil spills relies on either the indigenous microbes at the polluted site, whose degradative abilities are accelerated by adding such agents as fertilizers or dispersants, or on introducing pollutant-degrading microbes into the site (possibly accompanied by stimulatory chemicals). The bioremediation method to be used at a specific site must be selected to be suitable for that site and its environmental conditions. The basic components of bioremediation are outlined and the background information needed to understand the chemical and biological limitations of the technique are presented. Specifically, the microbial community, the crude oil substrate composition, and biological limiting factors are discussed. Generalized examples of bioremediation applications are illustrated. 10 refs

  2. Oil spills - effects and response

    International Nuclear Information System (INIS)

    Dicks, B.M.; White, I.C.

    1992-01-01

    The incidence of oil spills from offshore industry operates on the United Kingdom continental shelf is reported for the period 1979 to 1988. The properties of North Sea crude oils which determine their fate and effects when spilled onto the surface of the sea are summarized. Examples of oil impacts on specific North Sea habitats and communities are used to illustrate the effect of oil spills and the economic impact on human activities such as recreation, industry and fishing are considered. Since most oil spills will dissipate through natural processes if they remain at sea long enough, the most appropriate response to a spill from a platform in the middle of the sea is often aerial surveillance to monitor the movement and dissipation of the oil. However, if an active response is required, containment and collection of the oil or chemical dispersion are the two main options. In coastal waters, it will be necessary to focus protection efforts on selected sensitive areas of coastline. Once the oil is ashore there are still occasions when the best course of actions is to do nothing as clean-up operations may do more harm than good. If oil removal is feasible and necessary, the methods which are most effective are usually straightforward and require no sophisticated technology. Contingency planning is an essential preparation for all operations to deal with oil spills. (UK)

  3. Bioremediation of oil spills

    International Nuclear Information System (INIS)

    Lynn, J.

    2001-01-01

    The conversion of oil to environmentally benign chemicals such as water and carbon dioxide by 'hydrocarbon-eating' bacteria is described. The emphasis is on a new process to selectively increase the population of 'oil eating' bacteria, a development that became the foundation for the second-generation bioremediation accelerator, Inipol EAP-22. Second-generation bioremediation products focus on providing nitrogen and phosphorus, chemicals that are not present in crude oil in readily available form, but are essential for the synthesis of proteins, nucleic acids, phospholipids and the energy metabolism of the bacteria. Providing these chemicals in the proper amounts encourages the preferential growth of oil-degrading microbes already present in the local biomass, thus overcoming the major limiting factor for biodegradation. These second-generation bioremediation products also have strong oleophilic properties engineered into them, to assure that the nutrients essential for the bacteria are in contact with the oil. The first major test for second-generation bioremediation accelerators came with the clean-up of the oil spill from the Exxon Valdez, a disaster that contaminated more than 120 kilometres of Alaskan beaches along the shores of Prince William Sound. The Inipol EAP-22 successfully held the nutrients in contact with the oil for the duration of the treatment period, despite constant exposure to the washing action of the surf and occasional heavy rainstorms. Today, the accelerator is routinely used in cleaning up all types of ordinary spills including diesel fuel spills along railway right-of-ways, truck yards and refinery sludge. Conditions under which the application of the accelerator is likely to be most successful are described

  4. Canada's crude oil resources : crude oil in our daily lives

    International Nuclear Information System (INIS)

    Bott, R.

    2001-10-01

    Created in 1975, the Petroleum Communication Foundation is a not-for-profit organization. The objective of the Foundation is to inform Canadians about the petroleum industry in Canada. It produces educational, fact-based publications and programs, employing a multi-stakeholder review process. The first section of this publication is devoted to crude oil and the benefits that are derived from it. It begins by providing a brief definition of crude oil, then moves to the many uses in our daily lives and the environmental impacts like air pollution, spills, and footprint on the land from exploration and production activities. Section 2 details the many uses of crude oil and identifies the major oil producing regions of Canada. A quick mention is made of non-conventional sources of crude oil. The search for crude oil is the topic of section 3 of the document, providing an overview of the exploration activities, the access rights that must be obtained before gaining access to the resource. The drilling of oil is discussed in section 4. Section 5 deals with issues pertaining to reservoirs within rocks, while section 6 covers the feeding of the refineries, discussing topics from the movement of oil to market to the refining of the crude oil, and the pricing issues. In section 7, the uncertain future is examined with a view of balancing the supply and demand, as crude oil is a non-renewable resource. Supplementary information is provided concerning additional publications published by various organizations and agencies. figs

  5. Oil Spill Cleanup

    Science.gov (United States)

    Kauble, Christena Ann

    2011-01-01

    Several classroom activities using a model of a seashore and an oil spill demonstrate the basic properties of oil spills in oceans. Students brainstorm about how to best clean up the mess. They work in teams, and after agreeing on how they will proceed, their method is tested by measuring the amount of oil removed and by rating the cleanliness of…

  6. Oil Spill Response Manual

    NARCIS (Netherlands)

    Marieke Zeinstra; Sandra Heins; Wierd Koops

    2014-01-01

    A two year programme has been carried out by the NHL University of Applied Sciences together with private companies in the field of oil and chemical spill response to finalize these manuals on oil and chemical spill response. These manuals give a good overview of all aspects of oil and chemical

  7. The Fate and Effects of Crude Oil Spilled on Subarctic Permafrost Terrain in Interior Alaska,

    Science.gov (United States)

    1980-12-01

    on microorganisms are more important than ab - the filamentous fungal population was greater in solute numbers. the winter plot than in the summer...nalkanes by McCown, B.H., F.J. Deneke, W.E. Rickard and L.L. Tieszen Cladosporium resinae Applied Microbiology, vol 25, p (197 t) The response of...alkanes.on Impact of Oil Resource Deselopment on Northern Plant Com- Cladosporium resinae Canadian Journal of Microbiology. vol munities University of

  8. Oil spill statistics and oil spill monitoring

    Energy Technology Data Exchange (ETDEWEB)

    Viebahn, C. von [Greifswald Univ. (Germany). Dept. of Geography

    2001-09-01

    The main parts of the report describe the analysis and it's results of German and international oil spill data (North Sea and Baltic Sea). In order to improve the current oil spill monitoring of the Baltic Sea regarding oil spill data, the report proposes the establishment of a combined monitoring system; its suitability is shown on selected examples. This contains today's pollution control aircraft plus in-service aircraft and satellites. (orig.) [German] Der Schwerpunkt der Arbeit liegt in der Analyse von Daten ueber marine Oelschadensfaelle in deutschen und internationalen Gewaessern (Nord- und Ostsee). Um die heutige Ueberwachung der Ostsee im Hinblick auf Oelschadensfaelle zu verbessern, wird die Einrichtung eines kombinierten Ueberwachungssystems vorgeschlagen und dessen Eignung an ausgewaehlten Beispielen dargestellt. Dieses umfasst sowohl die heute eingesetzten Ueberwachungsflugzeuge sowie zusaetzlich Linienflugzeuge und Satelliten. (orig.)

  9. The Galeta oil spill: Pt. 2

    International Nuclear Information System (INIS)

    Burns, K.A.; Jorissen, D.; MacPherson, J.; Stoelting, M.; Tierney, J.; Yelle-Simmons, L.; Garrity, S.D.

    1994-01-01

    Sediment chemistry studies, undertaken as part of the long-term assessment of the Bahia las Minas (Panama) oil spill, showed the unexpected persistence of the full range of aromatic hydrocarbon residues of the spilled crude oil in anoxic muds of coastal mangroves. Mangrove muds served as long-term reservoirs for chronic contamination of contiguous coastal communities for over 5 years. One result of the repeated history of oil pollution incidents along this coast was an increased proportion of dead mangrove (Rhizophora mangle) roots in sediment cores which was related to contaminant loading and was detectable for at least 20 years after major oil spills. We suggest that this is the minimum time-scale that is to be expected for the loss of toxicity of oil trapped in muddy coastal habitats impacted by catastrophic oil spills. (author)

  10. Oil spill response plan

    International Nuclear Information System (INIS)

    1999-08-01

    The plan outlined in this document specifies the actions that the Canadian Wildlife Service Atlantic Region is mandated to take in the event of an oil spill, or on discovering oiled migratory birds in terrestrial, fresh water, marine and inter-tidal habitats. In addition to describing the role and responsibilities of the Canadian Wildlife Service, the document also describes response plans of other agencies for dealing with all wildlife species affected by oil spills. Reporting paths, the lead agency concept, shared responsibilities with other Canadian Wildlife Service regional offices, provincial agencies, Heritage Canada, non-government wildlife response agencies, oil spill response organizations, and international organizations are outlined. An overview of the reporting and communications process is also provided

  11. Oil spill recovery technology

    International Nuclear Information System (INIS)

    Nash, J.; Cooper, W.; Nee, V.; Nigim, H.

    1992-01-01

    Current deficiencies in oil spill cleanup processes have resulted in research and development of new cleanup technologies at the University of Notre Dame. Emphasis on reducing, reusing and recycling equipment and waste at a cleanup site has prompted advances in oil recovery technology as well as improvement in sorbent materials. (author)

  12. Crude oil burning mechanisms

    DEFF Research Database (Denmark)

    van Gelderen, Laurens; Malmquist, L.M.V.; Jomaas, Grunde

    2015-01-01

    In order to improve predictions for the burning efficiency and the residue composition of in-situ burning of crude oil, the burning mechanism of crude oil was studied in relation to the composition of its hydrocarbon mixture, before, during and after the burning. The surface temperature, flame...... height, mass loss rate and residues of three hydrocarbon liquids (n-octane, dodecane and hexadecane), two crude oils (DUC and REBCO) and one hydrocarbon liquid mixture of the aforementioned hydrocarbon liquids were studied using the Crude Oil Flammability Apparatus. The experimental results were compared...... on the highest achievable oil slick temperature. Based on this mechanism, predictions can then be made depending on the hydrocarbon composition of the fuel and the measured surface temperature....

  13. Crude oil market report

    Energy Technology Data Exchange (ETDEWEB)

    1985-01-01

    Falling demand for refined products and an excess of production capacity are driving world oil prices down further. Competitive price cutting, notably by Mexico, Britain, and the Soviet Union, has left Saudi Arabia the only guardian of a costly pricing discipline in terms of crude oil sales. The current crisis is limited to the producers of crude oil. Refineries are now deciding what, where, and how to buy crude in order to meet the requirements of a slack market place. Saudi Arabia could precipitate a price collapse below $20 per barrel by increasing production volume, but that seems unlikely. 1 figure, 2 tables.

  14. Biodegradability of northern crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Cook, F D; Westlake, D W.S.

    1976-01-01

    Field studies on the microbiological degradation of crude oils encompassed the placing of oil-soaked plots in two areas in the Northwest Territories and Alberta. Replicate plots received amendments of fertilizer, oil-utilizing bacteria, fertilizer plus bacteria or were untreated except for the oil. Changes in microbial numbers and chemical composition of recovered oil were determined periodically. The initial stimulatory effect on bacterial numbers brought about by the addition of fertilizers to oil-soaked plots diminished two years after the application to a point where the differences were no longer significant. Experiments carried out in the Norman Wells area to determine the effect of the amount of fertilizer applied on oil degradation have yielded inconclusive results. The data suggest that at least 2.7 kg of urea-phosphate fertilizer per kl of oil is required to maintain a reasonable oil degradation rate. Preliminary studies on the use of fertilizer coated with chemicals to increase its hydrophobic character indicate that they could be useful in treating wet-land oil spills. Soils from the McKenzie River drainage basin indicate that bacteria are present which can use oil under mesophilic conditions. However, the ability to use the same oil under psychrophilic conditions is more restricted. At least one bacterial species from each mixed population studied was capable of bringing about chemical changes in oil similar to those observed for the original mixed culture. The potential hazards and uses of the seeding of oil spills is discussed relative to the environmental conditions found in the northern part of Canada. 35 refs., 2 figs., 15 tabs.

  15. Effect-directed analysis and mixture effects of AhR-active PAHs in crude oil and coastal sediments contaminated by the Hebei Spirit oil spill

    International Nuclear Information System (INIS)

    Hong, Seongjin; Lee, Sangwoo; Choi, Kyungho; Kim, Gi Beum; Ha, Sung Yong; Kwon, Bong-Oh; Ryu, Jongseong; Yim, Un Hyuk; Shim, Won Joon; Jung, Jinho; Giesy, John P.; Khim, Jong Seong

    2015-01-01

    The major AhR-active PAHs were identified in crude oil and oil-contaminated sediments by use of effect-directed analysis. As part of the study, an enhanced potency balance analysis was conducted by establishing the novel relative potency values of (alkyl)-PAHs from the H4IIE-luc bioassay. Silica gel column fractionation of crude oil resulted in greater AhR-mediated potencies in fractions of aromatics (F2) and resins (F3), and such trend was also observed for field collected sediment samples. AhR-mediated potencies of six F2 sub-fractions from HPLC indicated that the majority of F2 responses were attributable to 3–4 ring aromatics. Target PAHs including C4-phenanthrene, C1-chrysene, and C3-chrysene in sediments explained ∼18% of the bioassay-derived TCDD-EQs, however, the unknown AhR agonists and potential mixture effects remain in question. Overall, the AhR-potency and antagonistic potential of residual oil in sediment tended to decrease over time, thus monitoring of weathering process would be key for the post management of oil-contaminated sites. - Highlights: • AhR-active PAHs in crude oil and sediments were newly determined using EDA. • Novel relative potency values of (alkyl)-PAHs for AhR activity were established. • Three to four ring PAHs were identified to be major AhR agonists in crude oil. • Parent and alkyl-PAHs explained ∼18% of the total AhR-mediated potencies of crude oil. • AhR-mediated potencies apparently decreased by the timely weathering processes. - “Major AhR agonists were identified three to four ring PAHs in crude oil and sediments determined by use of effect-directed analysis.”

  16. Characterization of Petroleum Hydrocarbons in Post-Burn Crude Oil ...

    African Journals Online (AJOL)

    In the Niger delta, crude oil spilled soils are burned as a means of decontaminating the impacted soils. Gas chromatography - flame ionization detector (GCFID) analyses were performed on oil residues extracted from burnt spilled oil soil samples to facilitate detailed chemical composition and characterization of petroleum ...

  17. Worldwide analysis of marine oil spill cleanup cost factors

    International Nuclear Information System (INIS)

    Etkin, D.S.

    2000-01-01

    The many factors that influence oil spill response costs were discussed with particular emphasis on how spill responses differ around the world because of differing cultural values, socio-economic factors and labor costs. This paper presented an analysis of marine oil spill cleanup costs based on the country, proximity to shoreline, spill size, oil type, degree of shoreline oiling and cleanup methodology. The objective was to determine how each factor impacts per-unit cleanup costs. Near-shore spills and in-port spills were found to be 4-5 times more expensive to clean than offshore spills. Responses to spills of heavy fuels also cost 10 times more than for lighter crudes and diesel. Spill responses for spills under 30 tonnes are 10 times more costly than on a per-unit basis, for spills of 300 tonnes. A newly developed modelling technique that can be used on different types of marine spills was described. It is based on updated cost data acquired from case studies of more than 300 spills in 40 countries. The model determines a per-unit cleanup cost estimation by taking into consideration oil type, location, spill size, cleanup methodology, and shoreline oiling. It was concluded that the actual spill costs are totally dependent on the actual circumstances of the spill. 13 refs., 10 tabs., 3 figs

  18. 1999 Crude oil market outlook

    International Nuclear Information System (INIS)

    Cochener, J.

    1998-01-01

    Baseline projection handling of crude oil prices was discussed, based on actual crude oil price trends from 1992 to 1998. Attention was drawn to the lack of correlation between crude oil and natural gas prices. Predictions for crude oil production were extended to the year 2015. As far as the immediate future is concerned the crude oil price for 1999 was predicted to continue to be sluggish due to competitive pressure from refined products at burner tip. tabs., figs

  19. GC and GC-MS characterization of crude oil transformation in sediments and microbial mat samples after the 1991 oil spill in the Saudi Arabian Gulf coast

    International Nuclear Information System (INIS)

    Garcia de Oteyza, T.; Grimalt, J.O.

    2006-01-01

    The massive oil discharge in the Saudi Arabian coast at the end of the 1991 Gulf War is used here as a natural experiment to study the ability of microbial mats to transform oil residues after major spills. The degree of oil transformation has been evaluated from the analysis of the aliphatic and aromatic hydrocarbons by gas chromatography (GC) and GC coupled to mass spectrometry (GC-MS). The oil-polluted microbial mat samples from coastal environments exhibited an intermediate degree of transformation between that observed in superficial and deep sediments. Evaporation, photo-oxidation and water-washing seemed to lead to more effective and rapid elimination of hydrocarbons than cyanobacteria and its associated microorganisms. Furthermore, comparison of some compounds (e.g. regular isoprenoid hydrocarbons or alkylnaphthalenes) in the oil collected in the area after the spill or in the mixtures retained by cyanobacterial growth gave rise to an apparent effect of hydrocarbon preservation in the microbial mat ecosystems. - Cyanobacterial mats inhibit degradation of oil by reducing exposure to the atmosphere and seawater

  20. Bioremediation of oil spills

    International Nuclear Information System (INIS)

    Webb, M.

    1992-01-01

    For some years now UK and European oil spill response agencies, together with oil companies having an exploration or production interest in the European area, have been developing interest in the possible use of bioremediation techniques in combatting oil spills. The interest has accelerated in the aftermath of Exxon Valdez but there is significant scepticism over the actual value of the technique. The promise of increased rates of oil degradation, using bacteria or nutrients, does not yet appear to have been properly validated and there is concern over possible knock-on environmental effects. In consequence the response agencies are reluctant to bring the technique into their current combat armory. Some of the questions raised are: What efficacious techniques are available and how were they proven? On what type of oils can they be used? What is the scope for their use (at sea, type of coastline, temperature limitations, etc.)? What are the short and long term effects? Does bioremediation really work and offer a potential tool for oil spill clean-up? How do cleaning rates compare with natural recovery? There are many others. The view of the European Commission is that there should be a coordinated effort to answer these questions, but that effort should be properly targeted. I concur strongly with this view. The tasks are too large and varied for piecemeal attention. The European Commission wishes to initiate appropriate coordinated work, directed at the needs of European nations but which will subsequently inform the international response community through the International Maritime Organization and its Oil Pollution Preparedness and Response Cooperation initiative

  1. Oil well spill trough

    International Nuclear Information System (INIS)

    Wigington, J.R. Sr.

    1992-01-01

    This patent describes a process involving an oil well and rig having a casing, a platform on the rig extending around the casing. This patent describes improvement in pulling the tubing from the casing; disconnecting joints of tubing thereby; and spilling liquids from the casing, catching spilled liquids from the casing in a basin below the platform, draining the basin substantially simultaneously; connecting the drain hole to a tank, and reducing the pressure in the tank to less than atmospheric pressure. This paper also describes an oil well and rig having a casing; the rig having a platform extending around the casing. This patent describes improvement in a basin surrounding the casing and connected thereto, the basin below the platform, a drain connection in the lower part of the basin, a conduit connected to the drain, and means for applying a suction to the conduit

  2. Classification of weathered crude oils

    International Nuclear Information System (INIS)

    Vogt, N.B.; Sjoegren, C.E.; Lichtenthaler, G.

    1987-01-01

    The NORDTEST procedure (1) for oil spill identification has been applied successfully at several occasions. The NORDTEST procedure includes analyses of sulfur (XRF), vanadium and nickel (ICP/AAS), GC, HPLC and UV-fluorescence. The NORDTEST procedure does not include GC-MS as an analytical method. As part of a joint Nordic to evaluate the NORDTEST procedure for oil identification, with participants from Denmark, Sweden, Finland and Norway, thirty artificially weathered crude oils from four geographical regions have been analyzed (2). The analytical methods evaluated include sulfur analysis, vanadium and nickel analysis, infrared analysis, UV-fluorescence, gas chromatography, high pressure liquid chromatography and high resolution GC-mass spectrometry. Figure 1 shows the distribution of variables analyzed in each analytical method. The 190 variables from GC-MS were split into 7 groups according to chemical considerations. These were steranes (25 var.), triterpanes (16 var.), di(+)aromatics (63 var.), sulf. aromatics (30 var.), monoaromatics (19 var.), cycloalkanes (15 var.) and n-alkanes (22) variables. The data from these chemical analyses have been evaluated for use in oil spill identification purposes

  3. The latest oil spills in the Mediterranean Sea

    International Nuclear Information System (INIS)

    Bergueiro Lopez, J.R.; Morales Correas, N.; Dominguez Laseca, F.

    1992-01-01

    The oil spills from the Agip Abruzzo and the Haven in April 1991 are described. The Agip Abruzzo collided with a ferry near Livorno, Italy and spilled 3,000 tonnes of Iranian crude oil. Another 12,000 tonnes burned and 140 people were killed in the incident. The spill had little effect on the sea environment as most of the spilled oil was removed. The Haven oil tanker exploded just after unloading crude oil at Arenzano, Italy, spilling 3,000 tonnes of oil along the Ligurian coast. A series of nine explosions occurred over the next few days and the ship finally sank in 60 m of water. Spill cleanup procedures used at sea and along the affected coast are reviewed. Crude oil residues drifting along the coast of the Balearic Islands were sampled and analyzed in May and July 1991 to determine whether they came from the Haven tanker. Experiments were also conducted to determine the evaporated fraction of heavy Iranian crude oil as a function of time when spilled on sea water or different sizes of beach sand. The analyzed samples were concluded not to have come from the Haven spill. 9 refs., 9 figs., 1 tab

  4. Oil spill response: Countdown to readiness

    International Nuclear Information System (INIS)

    Costello, J.D.

    1993-01-01

    In the wake of the Exxon Valdez oil spill, a task force representing America's oil industry set about studying the existing resources across the nation for responding to catastrophic oil spills. In June 1989 the task force reported that the capability did not exist in either government or industry to respond to a spill the magnitude of the one in Alaska. As a result of task force recommendations, 20 companies began the process that led to the creation of both the Marine Preservation Association (MPA) and the Marine Spill Response Corp. (MS-RC). The latter is headquartered in Washington, D.C., with 5 regional response centers around the US. Under the direction of the US Coast Guard, each of MSRC's five regions will provide a best-effort response to cleaning up spill of persistent (crude) oils that are beyond the capabilities of local spill response organizations. MSRC will work closely with both cooperatives and independent, commercial responders to maximize spill response effectiveness. The MPA and its member companies have committed more than $400 million for the acquisition of capital equipment for MSRC, an unprecedented record in American business history. MSRC is also involved in research programs concerning remote sensing, in-situ burning, dispersants, handling of recovered material, and shoreline countermeasures

  5. Responding to the Sea Empress oil spill

    International Nuclear Information System (INIS)

    Leonard, D.R.P.; Law, R.J.; Kelly, C.A.

    1999-01-01

    The Ministry of Agriculture, Fisheries and Food (MAFF) is a government department which has responsibility in England and in Wales (acting on behalf of the Secretary of State for Wales) for controlling deposits in the sea, including approving the use of dispersants in oil spill response. MAFF also has responsibility in relation to the management of sustainable commercial fish and shellfish fisheries. Following the grounding of the tanker Sea Empress on 15 February 1996, over 72,000 tonnes of crude oil and bunker fuel was lost. This paper summarises the involvement of MAFF staff in the response phase, and in the subsequent assessment of the environmental impact of the oil spill and the associated clean up operations on commercial fisheries. After two and a half years of environmental monitoring and complementary research, it is concluded that the oil spill has had an insignificant impact on these fisheries beyond their closure during the incident response phase. Suggestions for further work are discussed. (author)

  6. Marine oil spill response organizations

    International Nuclear Information System (INIS)

    Hendry, C.

    1997-01-01

    The obligations under the law relative to the prevention of marine oil spills and the type of emergency plans needed to mitigate any adverse effects caused by a marine oil spill were discussed. The organizational structure, spill response resources and operational management capabilities of Canada's newly created Response Organizations (ROs) were described. The overall range of oil spill response services that the RO provides to the domestic oil handling, oil transportation and the international shipping industries were reviewed. Amendments to the Canada Shipping Act which require that certain ships and oil handling facilities take oil spill preparedness and response measures, including having an arrangement with an RO certified by the Canadian Coast Guard, were outlined. Canadians now benefit from five ROs established to provide coast-to-coast oil spill response coverage. These include the Western Canada Marine Response Corporation, the Canadian Marine Response Management Corporation, the Great Lakes Response Corporation, the Eastern Canada Response Corporation and the Atlantic Emergency Response Team Ltd. ROs have the expertise necessary to organize and manage marine oil spill response services. They can provide equipment, personnel and operational management for the containment, recovery and cleanup of oil spilled on water

  7. A mass balance approach to investigating geochemical controls on secondary water quality impacts at a crude oil spill site near Bemidji, MN

    Science.gov (United States)

    Ng, Gene-Hua Crystal; Bekins, Barbara A.; Cozzarelli, Isabelle M.; Baedecker, Mary Jo; Bennett, Philip C.; Amos, Richard T.

    2014-01-01

    Secondary water quality impacts can result from a broad range of coupled reactions triggered by primary groundwater contaminants. Data from a crude-oil spill research site near Bemidji, MN provide an ideal test case for investigating the complex interactions controlling secondary impacts, including depleted dissolved oxygen and elevated organic carbon, inorganic carbon, CH4, Mn, Fe, and other dissolved ions. To better understand these secondary impacts, this study began with an extensive data compilation of various data types, comprising aqueous, sediment, gas, and oil phases, covering a 260 m cross-sectional domain over 30 years. Mass balance calculations are used to quantify pathways that control secondary components, by using the data to constrain the sources and sinks for the important redox processes. The results show that oil constituents other than BTEX (benzene, toluene, ethylbenzene, o-, m- and p-xylenes), including n-alkanes and other aromatic compounds, play significant roles in plume evolution and secondary water quality impacts. The analysis underscores previous results on the importance of non-aqueous phases. Over 99.9% of the Fe2+ plume is attenuated by immobilization on sediments as Fe(II) and 85–95% of the carbon biodegradation products are outgassed. Gaps identified in carbon and Fe mass balances and in pH buffering mechanisms are used to formulate a new conceptual model. This new model includes direct out-gassing of CH4 and CO2 from organic carbon biodegradation, dissolution of directly produced CO2, and sorption with H+ exchange to improve pH buffering. The identification of these mechanisms extends understanding of natural attenuation of potential secondary impacts at enhanced reductive dechlorination sites, particularly for reduced Fe plumes, produced CH4, and pH perturbations.

  8. A mass balance approach to investigating geochemical controls on secondary water quality impacts at a crude oil spill site near Bemidji, MN

    Science.gov (United States)

    Ng, G.-H. Crystal; Bekins, Barbara A.; Cozzarelli, Isabelle M.; Baedecker, Mary Jo; Bennett, Philip C.; Amos, Richard T.

    2014-08-01

    Secondary water quality impacts can result from a broad range of coupled reactions triggered by primary groundwater contaminants. Data from a crude-oil spill research site near Bemidji, MN provide an ideal test case for investigating the complex interactions controlling secondary impacts, including depleted dissolved oxygen and elevated organic carbon, inorganic carbon, CH4, Mn, Fe, and other dissolved ions. To better understand these secondary impacts, this study began with an extensive data compilation of various data types, comprising aqueous, sediment, gas, and oil phases, covering a 260 m cross-sectional domain over 30 years. Mass balance calculations are used to quantify pathways that control secondary components, by using the data to constrain the sources and sinks for the important redox processes. The results show that oil constituents other than BTEX (benzene, toluene, ethylbenzene, o-, m- and p-xylenes), including n-alkanes and other aromatic compounds, play significant roles in plume evolution and secondary water quality impacts. The analysis underscores previous results on the importance of non-aqueous phases. Over 99.9% of the Fe2 + plume is attenuated by immobilization on sediments as Fe(II) and 85-95% of the carbon biodegradation products are outgassed. Gaps identified in carbon and Fe mass balances and in pH buffering mechanisms are used to formulate a new conceptual model. This new model includes direct out-gassing of CH4 and CO2 from organic carbon biodegradation, dissolution of directly produced CO2, and sorption with H+ exchange to improve pH buffering. The identification of these mechanisms extends understanding of natural attenuation of potential secondary impacts at enhanced reductive dechlorination sites, particularly for reduced Fe plumes, produced CH4, and pH perturbations.

  9. Mitigating oil spills in the water column

    International Nuclear Information System (INIS)

    Barry, Edward; Libera, Joseph A.; Mane, Anil University; Avila, Jason R.; DeVitis, David

    2017-01-01

    The scale and scope of uncontrolled oil spills can be devastating. Diverse marine environments and fragile ecologies are some of the most susceptible to the many ill effects, while the economic costs can be crippling. A notoriously difficult challenge with no known technological solution is the successful removal of oil dispersed in the water column. Here, we address this problem through cheap and reusable oil sorbents based on the chemical modification of polymer foams. Interfacial chemistry was optimized and subsequently tested in a simulated marine environment at the National Oil Spill Response Research & Renewable Energy Test Facility, Ohmsett. We find favorable performance for surface oil mitigation and, for the first time, demonstrate the advanced sorbent's efficiency and efficacy at pilot scale in extraction of crude oil and refined petroleum products dispersed in the water column. As a result, this is a potentially disruptive technology, opening a new field of environmental science focused on sub-surface pollutant sequestration.

  10. Pigouvian penalty for oil spills

    International Nuclear Information System (INIS)

    Kohn, R.E.

    1993-01-01

    The imposition of ex ante taxes on expected spilled oil, in addition to ex post payments for damages under tort liability, would foster economic efficiency. This paper begins the analysis of the joint approach with the case in which Pigouvian taxes are used exclusively. A model is developed in which the volume of spilled oil causing environmental damage is reduced, first by spill prevention expenditures by shippers and then by clean-up expenditures by the government. The efficient Pigouvian tax on expected spilled oil equals marginal environmental damage which equals the net marginal cost of prevention which equals marginal clean-up cost. (Author)

  11. Methods of analyzing crude oil

    Science.gov (United States)

    Cooks, Robert Graham; Jjunju, Fred Paul Mark; Li, Anyin; Rogan, Iman S.

    2017-08-15

    The invention generally relates to methods of analyzing crude oil. In certain embodiments, methods of the invention involve obtaining a crude oil sample, and subjecting the crude oil sample to mass spectrometry analysis. In certain embodiments, the method is performed without any sample pre-purification steps.

  12. Oil spill preparedness in the Mediterranean Sea

    International Nuclear Information System (INIS)

    Jorigne, E.M.; Wong, K.V.

    1993-01-01

    Over 15% of the world's consumption of crude oil and refined products is shipped through the Mediterranean Sea each year. The sea is one of the most polluted areas in the world and has areas of high risk for oil spills, notably those places where there is a very narrow passage between coasts or islands. The region also needs to modernize its ports by developing more deballasting facilities, since a large percentage of spill accidents happens during terminal operations. Release of oily wastes from ships is also significant. The World Bank Global Environment Facility trust fund is working on a project to help the southwest Mediterranean countries modernize reception facilities for ballast water, bilge water, and oily waste water. The Regional Marine Pollution Emergency Response Center (REMPEC) in Malta acts as the coordinating center for regional contingency planning for oil spill response. The cost of the port facilities modernization program and oil spill contingency plan implementation for the Mediterranean is estimated at US$444 million. An allocation of costs is suggested which will help those countries needing more financial aid to implement the proposed programs. In the long run, the cost of these programs will be much lower than that of a massive oil spill cleanup. 7 refs., 2 figs., 4 tabs

  13. The Galeta oil spill: Pt. 1

    International Nuclear Information System (INIS)

    Garrity, S.D.; Levings, S.C.; Burns, K.A.

    1994-01-01

    In April 1986, more than 75 000 barrels (1.5 x 10 7 l) of medium-weight crude oil spilled into Bahia las Minas on the central Caribbean coast of Panama. Changes in the physical structure of the mangrove fringe after oiling were documented over time. These included defoliation, limb loss and eventual collapse of dead trees. By 5 years after the spill, the length of shore fringed by mangroves was reduced at oiled sites relative to unoiled sites. Surviving trees at oiled sites had fewer and shorter submerged prop roots and a higher proportion of dead roots than trees at unoiled sites. These changes reduced the surface area of submerged prop roots by 33% on oiled open coast, 38% in channels and 74% in streams. (author)

  14. Bohai and Yellow Sea Oil Spill Prediction System and Its Application to Huangdao ‘11.22’ Oil Spill Incident

    Science.gov (United States)

    Li, Huan; Li, Yan; Li, Cheng; Li, Wenshan; Wang, Guosong; Zhang, Song

    2017-08-01

    Marine oil spill has deep negative effect on both marine ecosystem and human activities. In recent years, due to China’s high-speed economic development, the demand for crude oil is increasing year by year in China, and leading to the high risk of marine oil spill. Therefore, it is necessary that promoting emergency response on marine oil spill in China and improving oil spill prediction techniques. In this study, based on oil spill model and GIS platform, we have developed the Bohai and Yellow sea oil spill prediction system. Combining with high-resolution meteorological and oceanographic forecast results, the system was applied to predict the drift and diffusion process of Huangdao ‘11.22’ oil spill incident. Although the prediction can’t be validated by some SAR images due to the lack of satellite observations, it still provided effective and referable oil spill behavior information to Maritime Safety Administration.

  15. Mega borg oil spill: Fate and effect studies

    International Nuclear Information System (INIS)

    1992-01-01

    The Mega Borg, a Norwegian tanker, released an estimated 5.1 million gallons (gal) of Palanca Angola crude oil into the Gulf of Mexico during a lightering accident and subsequent fire. The collection of reports was designed to provide a comprehensive overview of the spill chronology, the fate of the oil released, and subsequent studies that were conducted to assess the impacts of the oil spill on the environment and its biota

  16. Record prices [crude oil

    International Nuclear Information System (INIS)

    Anon

    2006-01-01

    Crude oil prices climbed to new record levels on fears of a future loss of supplies from Iran as Washington stepped up its efforts to persuade Tehran to abandon its programme to produce nuclear fuel. IPE's December Brent contract set a new record for the exchange by trading at $75.80/bbl on 21st April. On the same day October WTI reached an all-time high of $77.30/bbl on Nymex. US product prices gained as refiners struggled to produce sufficient middle distillate. Alarmed by the rising retail price of gasoline, the US Senate debated a reduction in the already low US tax rate on motor spirit. The House of Representatives passed a measure to prohibit overcharging for petrol, diesel and heating oil, but Democrats rejected a Republican proposal to speed-up the process for approving new refineries. President George W Bush announced a temporary easing of new gasoline and diesel specifications (see 'Focus', March 2006) to allow more fuel to be produced. He also agreed to delay the repayment of some 2.1 mn bbl of crude oil lent to companies after last year's hurricanes from the Strategic Petroleum Reserve. California announced an inquiry into alleged overcharging for fuel by oil companies operating in the state. (author)

  17. Fate and Effects of Crude Oil Spilled on Subarctic Permafrost Terrain in Interior Alaska: Fifteen Years Later

    Science.gov (United States)

    1993-08-01

    areas. The soil is cold and wet, a Histic downslope movement of the oil past the last Pergelic Cryaquept (Rieger 1983), typical of the Sau- mapped...histic pergelic cryaquept soil. mosses, lichens and shrubs were killed soon after have even flourished (Fig. 11). Most of the associat- the original

  18. A local oil spill revisited

    International Nuclear Information System (INIS)

    Teal, J.M.

    1993-01-01

    In October 1969 George Hampson and Howard Sanders (Woods Hole Oceanographic Institution) described a 'Local Oil Spill' in Oceanus. The spill had occurred a month before when the barge Florida, loaded with no. 2 fuel oil, ran into some rocks in Buzzards Bay off West Falmouth, Massachusetts. In the summer of 1989, almost 20 years later, They visited the Wild Harbor marsh area that had suffered the greatest impact from the spill to see if any traces of the event in the marsh ecosystem could be found. During those 20 years, the site has been visited by graduate students in marine ecology, by reporters seeking information about current oil spills but also interested in seeing the effects of the Wild Harbor spill, and by visiting scientists curious about one of the world's best-studied oil spills. For more than a decade after the spill, an oil sheen appeared on the surface of the water when mud from the most heavily oiled parts of the marsh was disturbed. During the second decade, the marsh's appearance returned to normal

  19. The Newfoundland oil spill burn experiment

    International Nuclear Information System (INIS)

    Fingas, M.

    1992-01-01

    A major offshore oil-spill combustion experiment is being planned for waters off Newfoundland. The experiment is designed to answer outstanding questions on the acceptability of in-situ oil spill burning. In the experiment, variables will be controlled to allow quantitative measurement of the scientific and operational parameters that will enhance understanding of in-situ combustion as an operational oil-spill response technique. The proposed full-scale tests follow six years of testing in laboratory tanks. Analyses have shown that the high temperatures reached during efficient in-situ combustion result in relatively complete destruction of the oil. Tests have shown that the most important factor in this regard is that the oil must be thickened sufficiently before effective burning will occur. Such thickening is potentially possible in the offshore, under suitable wind and sea conditions, using fireproof containment booms. The experiment will involve measurement of emissions to the air, levels of oil in water, and operational parameters of in-situ burning. Time and location of the experiment are chosen to minimize ecological damage and for operational reasons. When suitable conditions are present in early August 1993, two 45-m 3 batches of crude oil will be released into a containment boom and ignited. The burn residue will be recovered mechanically, and a secondary containment and recovery system will be towed behind the fireproof boom to pick up any fugitive oil or residue. 3 figs., 6 tabs

  20. Geotechnical properties of crude oil contaminated sand

    International Nuclear Information System (INIS)

    Puri, V.K.; Das, B.M.; Cook, E.E.; Shin, E.C.

    1994-01-01

    Contamination of soil due to an oil spill influences its subsequent engineering behavior. An investigation was conducted to study the effect of crude oil contamination on compaction characteristics, shear strength, one-dimensional compression, and coefficient of permeability. Water permeability was also determined by using commercial grade motor oils as contaminants. The test results indicate that the compaction characteristics are influenced by oil contamination. The angle of internal friction of sand (based on total stress condition) decreases due to presence of oil within the pore spaces in sand. One dimensional compression characteristics of sand are significantly influenced by oil contamination resulting in a decrease in the value of constrained modulus with increase in the degree of oil contamination compared to the case of dry sand. Water permeability was observed to be a function of the initial viscosity and the degree of saturation due to the contaminating oil

  1. Cost accounting and oil spills

    International Nuclear Information System (INIS)

    Peck, J.B.; Dufour, B.; Peck, V.P.

    1996-01-01

    Financial costs of an oil spill were considered. The control measures taken by Maritime Bureau Inc., in the San Juan oil spill were used as an example of how chaotic influences were minimized, how stability to the management team, structured under the Incident Command System (ICS) model, was provided, and how as a result of these actions, effective cost control was established. The importance of precise knowledge of operating costs was stressed as a basis for taking policy measures and for the evaluation of the short-term success of an oil spill clean-up operation. Staff responsibilities and management needs were described. Performance evaluation, as an important part of crisis cost accounting, was highlighted. Incident costs and response effectiveness comparisons were given for 13 oil spill incidents, including the EXXON VALDEZ affair. 4 tabs., 2 figs

  2. Vegetable oil spills : oil properties and behaviour

    International Nuclear Information System (INIS)

    Fingas, M.; Fieldhouse, B.; Jokuty, P.

    2001-01-01

    In 1997, the United States Environmental Protection Agency conducted a thorough review of the issue regarding vegetable oil spills. Recent attention has refocused on this issue as a result of an incident where 20 tons of canola oil was spilled in the Vancouver Harbour in 2000. In the past, vegetable oils were suggested to be a useful test material because they were thought to be innocuous. It was even suggested they be used to remove petroleum oil residues from beaches. However, recent studies have shown that spills of vegetable oils can have major environmental consequences, equivalent to those of petroleum oil spills. The spills have devastating effects on birds and intertidal organisms. This paper presented a summary of historical vegetable spills from around the world. In this study, specific behaviour tests were examined for several oils including canola, soy bean, olive, castor and corn oils. Evaporation, water-in-oil emulsification and chemical dispersion were measured and were found to be nearly zero, suggesting that vegetable oil spills are not very soluble in water. The aquatic toxicity of vegetable oil is low, but their fate is quite different from petroleum. Vegetable oils do not evaporate to a significant degree, they do not form water-in-oil emulsions, nor do they disperse in water. The physical properties of vegetable oils were also measured, including density and viscosity. This paper presented the aquatic toxicity of several vegetable oils along with other environmental data including the degradation rates noted in the literature. Most environmental damage reported in the literature is by contact with birds feathers resulting in hypothermia and secondly by smothering of intertidal organisms. The effect of vegetable oil on fish has not been well studied, but it is expected that there will be little destructive effect except where smothering can occur. 35 refs., 3 tabs

  3. Vegetable oil spills : oil properties and behaviour

    Energy Technology Data Exchange (ETDEWEB)

    Fingas, M.; Fieldhouse, B.; Jokuty, P. [Environment Canada, Ottawa, ON (Canada). Emergencies Science Div

    2001-07-01

    In 1997, the United States Environmental Protection Agency conducted a thorough review of the issue regarding vegetable oil spills. Recent attention has refocused on this issue as a result of an incident where 20 tons of canola oil was spilled in the Vancouver Harbour in 2000. In the past, vegetable oils were suggested to be a useful test material because they were thought to be innocuous. It was even suggested they be used to remove petroleum oil residues from beaches. However, recent studies have shown that spills of vegetable oils can have major environmental consequences, equivalent to those of petroleum oil spills. The spills have devastating effects on birds and intertidal organisms. This paper presented a summary of historical vegetable spills from around the world. In this study, specific behaviour tests were examined for several oils including canola, soy bean, olive, castor and corn oils. Evaporation, water-in-oil emulsification and chemical dispersion were measured and were found to be nearly zero, suggesting that vegetable oil spills are not very soluble in water. The aquatic toxicity of vegetable oil is low, but their fate is quite different from petroleum. Vegetable oils do not evaporate to a significant degree, they do not form water-in-oil emulsions, nor do they disperse in water. The physical properties of vegetable oils were also measured, including density and viscosity. This paper presented the aquatic toxicity of several vegetable oils along with other environmental data including the degradation rates noted in the literature. Most environmental damage reported in the literature is by contact with birds feathers resulting in hypothermia and secondly by smothering of intertidal organisms. The effect of vegetable oil on fish has not been well studied, but it is expected that there will be little destructive effect except where smothering can occur. 35 refs., 3 tabs.

  4. Assessing the recovery of coastal wetlands from oil spills

    International Nuclear Information System (INIS)

    Mendelssohn, I.A.; Hester, M.W.; Hill, J.M.

    1993-01-01

    The impact of oil spills on coastal environments and the ability of these systems to exhibit long-term recovery has received increased attention in recent years. Although oil spills can have significant short-term impacts on coastal marshes, the long-term effects and eventual recovery are not well documented. Estuarine marshes have sometimes been reported to exhibit slow recovery after oil spills, whereas in other instances they appear to have great resiliency, with complete recovery after one or two years. To document and understand this phenomenon better, we have investigated the long-term recovery of a south Louisiana estuarine marsh exposed to an accidental spill of crude oil. Although a pipeline rupture releasing Louisiana crude oil caused the near complete mortality of a brackish marsh dominated by Spartina patens and S. alterniflora, this marsh completely recovered four years after the spill with no differences in plant species cover between oiled and reference marshes. Remotely sensed imagery of the study site confirmed the relatively rapid recovery demonstrated by the ground truth data. Louisiana's coastal marshes are naturally experiencing rapid rates of deterioration. Land loss rates, determined from aerial imagery, at the spill site and adjacent reference areas before and after the spill demonstrated that the long-term loss rates were not affected by the spill event

  5. Trends in oil spills from tanker ships 1995-2004

    International Nuclear Information System (INIS)

    Huijer, K.

    2005-01-01

    The trends in oil spills around the world over from 1995 to 2004 were examined and analyzed for possible influences on spill volumes and frequencies for incidents of 3 spill size classes. The International Tanker Owners Pollution Federation (ITOPF) has maintained a database since 1974 of all oil spills from tankers, combined carriers and barges. The number of oil spills has decreased significantly in the last 30 years despite a steady increase in maritime oil trade since the 1980s. The recent trends were identified by causes, locations, oil type, and shipping legislation. The causes include ship loading/discharging, bunkering, collisions, groundings, hull failures and fires. The types of oil spilt include bunker, crude, cargo fuel, white product and some unknowns. It was concluded that the decline in oil spills is due to a range of initiatives taken by governments and the shipping industry rather than any one factor. Some notable influences towards reduced number of spills include: the international convention for the prevention of pollution from ships of 1972, as modified by the Protocol of 1978; the international convention for the safety of life at sea of 1974; and the Oil Pollution Act of 1990. Results of investigations into the causes of spills serve the purpose of informing the international process to further prevent and reduce marine oil pollution due to tankers. 7 refs., 5 tabs., 12 figs

  6. Laboratory tests, experimental oil spills, models, and reality: The Braer oil spill

    International Nuclear Information System (INIS)

    Reed, M.; Daling, P.S.; Brandvik, P.J.; Singsaas, I.

    1993-01-01

    The IKU Petroleum Research organization in Norway has accumulated data on the weathering behavior of spilled oils and petroleum products, mainly pertaining to North Sea crudes. Recent weathering research at IKU has been carried out in an elliptical mesoscale flume and in field tests consisting of experimental releases of crude oil. Results of these tests provided information on oil spill dispersion, evaporation, and emulsification. When the tanker Braer grounded in the Shetland Islands in January 1993 in extreme environmental conditions, the imminent release of a load of 84,000 tonnes of North Sea oil confronted response personnel with a variety of issues including the use of dispersants as a response action. Relevant information on the expected behavior of the crude was obtained within a day of the grounding as a result of close relations between IKU and Warren Spring Laboratory. The question is raised whether such information, which could have been spread between several organizations around the world, will be rapidly accessible in the event of another major spill. It is proposed to establish an electronically accessible database on the behavior and fate of specific oils and petroleum products to address this problem. 9 refs., 4 figs

  7. Maglev crude oil pipeline

    Science.gov (United States)

    Knolle, Ernst G.

    1994-01-01

    This maglev crude oil pipeline consists of two conduits guiding an endless stream of long containers. One conduit carries loaded containers and the other empty returns. The containers are levitated by permanent magnets in repulsion and propelled by stationary linear induction motors. The containers are linked to each other in a manner that allows them, while in continuous motion, to be folded into side by side position at loading and unloading points. This folding causes a speed reduction in proportion to the ratio of container diameter to container length. While in side by side position, containers are opened at their ends to be filled or emptied. Container size and speed are elected to produce a desired carrying capacity.

  8. Lack of physiological responses to hydrocarbon accumulation by Mytilus trossulus after 3-4 years chronic exposure to spilled Exxon Valdez crude oil in Prince William Sound

    International Nuclear Information System (INIS)

    Thomas, R.E.; Brodersen, C.; Carls, M.G.; Babcock, M.; Rice, S.D.

    1999-01-01

    Mussels, Mytilus trossulus, were sampled in 1992 and 1993 from beaches in Prince William Sound that had been oiled by the Exxon Valdez spill of March, 1989. At some of the oiled beaches, mussels were collected from beds overlying oiled sediments, and from bedrock adjacent to these beds. Mussels were also collected from beaches within the Sound that had not been impacted by the spill. Polynuclear aromatic hydrocarbon (PAH) concentrations in mussel tissue, physiological responses (byssal thread production, condition index, clearance rate, and glycogen content), were determined for each group of mussels. Total PAH concentrations in mussel tissue ranged from 0 to 6 μg g -1 , and were significantly greater in mussels from oiled beds than those from reference beds. No significant differences were noted in byssal thread production, condition index, clearance rate, or glycogen content between oiled sample sites and reference sites. The lack of physiological response was surprising because mussels in this study were chronically exposed to PAH for 3-4 years, and none of the physiological responses measured appeared to be affected by that exposure. The lack of a physiological response suggests that chronically exposed mussels may develop a physiological tolerance to PAH, but we recognize that these measures may not have been sensitive enough to discriminate response from background noise. (Copyright (c) 1999 Elsevier Science B.V., Amsterdam. All rights reserved.)

  9. Crude Oil Spills and Health

    Science.gov (United States)

    ... NIH Disaster Research Response (DR2) Research on the medical and public health aspects of disasters and public health emergencies. More about DR2 Technology & Innovation Virtual Reality Disaster Health Preparedness Training Resilient Email Communications System ...

  10. Managing an oil spill response

    International Nuclear Information System (INIS)

    Merlin, W.F.; Gorell, F.R.

    1994-01-01

    In the oil spill response business everything starts with a plan. When planning is set at only middle and top management levels before being chiseled into corporate marble, the result is all too often a plan for failure. For any chance at success, the plan must make sense to, and solve the problems of, the people at the ''business'' end of the business. In the case of Marine Spill Response Corporation (MSRC), that means highly trained responders are put at sea or along coastlines to remove oil from the water, or to deflect oil away from environmentally sensitive areas. They are fortunate in MSRC, and especially in the Gulf Coast Region, to have on their staff, some of the most knowledgeable and experienced oil spill responders in the world. The company relies on them to help build their plans, and to poke holes wherever their plans are inconsistent with getting the job done right

  11. The Exxon-Valdez oil spill

    International Nuclear Information System (INIS)

    Dean, K.G.; Stringer, W.J.; Grove, J.E.; Ahlnas, K.; Royer, T.C.

    1990-01-01

    This paper reports that satellite images were used to investigate the Exxon Valdez oil spill after the tanker ran aground on Bligh Reef, Alaska 24 March 1989. Since that time, over 11 million gallons of crude oil have circulated through the western Prince William Sound region of Alaska, oiling many of its beaches. A good deal of this oil subsequently entered the Gulf of Alaska with some transported beyond Kodiak Island, 500 km to the southwest. Satellite imagery of the spill was recorded by the NOAA Advanced Very High Resolution Radiometer, the Landsat Thematic Mapper, the SPOT Panchromatic Scanner and the SPOT Multispectral Scanner. Images from all four of these sources have been analyzed to help ascertain the extent of the spill and monitor its trajectory along the Alaskan coast. Digital image processing techniques have been utilized to emphasize spectral responses related to oil on the water surface and on teaches. Turbidity and sea surface temperature data have been enhanced to provide information on the circulation and distribution of surface water bodies. In addition to the satellite imagery, airborne visual observations with aerial photography, Side-Looking Airborne Radar, and other airborne sensors as well as shipboard sightings and samples were acquired

  12. Contained controlled burning of spilled oil during the Exxon Valdez oil spill

    International Nuclear Information System (INIS)

    Allen, A.A.

    1990-01-01

    During the evening of the second day following the Exxon Valdez oil spill, an estimated 57,000-114,000 liters of North Slope crude oil were eliminated using in-situ combustion. The oil was collected with 3M's Fire Boom towed in a U-shaped configuration behind two fishing boats. Working with 152 m long tow lines, a 137 m boom was moved at ca 0.26-5.2 m/s through slightly emulsified oil patches in the downwind region of the spill. A gelled fuel ignitor was used to ignite the captured oil, and the size and intensity of the blaze was controlled by adjusting the speed of the vessels. Total burn time was ca 1.25 h, however the intense part of the burn lasted for ca 45 minutes. Using several methods to estimate the total volume of oil collected, the volume resulted in ca 1136 liters of stiff, taffy-like burn residue that could be picked up easily on completion of the burn. The controlled burn thus resulted in an estimated 98% or better elimination of crude oil. It had been planned to use a helitorch to ignite the captured oil, however darkness required the use of the gelled ignitor. Had the helitorch been used, numerous ignition points could have been spread througout the contained oil, providing a much more efficient heating and ultimate ignition of the oil. 5 figs

  13. Lecithins - promising oil spill cleaner?

    International Nuclear Information System (INIS)

    Anon.

    1993-01-01

    A new, non-polluting method of cleaning up oil spills at sea as well as on land has been developed by researchers at the Hebrew University of Jerusalem. Their technique is based on the use of lecithins, a byproduct of producing edible oils from plants. Lecithin molecules are hydrophyllic at one end and lipophilic at their tail ends. When they come into contact with water, they organize themselves into bilayers whose heads all face the water and whose tails are all directed towards each other. These bilayers form particles called liposomes that, when spread on water fouled by oil spills, change the properties of the oil thereby stopping the spreading and breaking it down into sticky droplets that continue to float on the surface and can be easily collected. The treatment is said to be effective in both fresh and salt water and is almost temperature and pH independent. Another beneficial effect is that the physical change generated by liposomes in the spilled oil improves the ability of oil-eating bacteria in the water to remove some of the spill by bioremediation

  14. . Estimating soil contamination from oil spill using neutron backscattering technique

    International Nuclear Information System (INIS)

    Okunade, I.O.; Jonah, S.A.; Abdulsalam, M.O.

    2009-01-01

    An analytical facility which is based on neutron backscattering technique has been adapted for monitoring oil spill. The facility which consists of 1 Ci Am-Be isotopic source and 3 He neutron detector is based on the principle of slowing down of neutrons in a given medium which is dominated by the elastic process with the hydrogen nucleus. Based on this principle, the neutron reflection parameter in the presence of hydrogenous materials such as coal, crude oil and other hydrocarbon materials depends strongly on the number of hydrogen nuclei present. Consequently, the facility has been adapted for quantification of crude oil in soil contaminated in this work. The description of the facility and analytical procedures for quantification of oil spill in soil contaminated with different amount of crude oil are provided

  15. Oil spills and their cleanup

    International Nuclear Information System (INIS)

    Fingas, M.

    1995-01-01

    Oil spills are an unfortunately common occurrence in the world's seas and can have extensive damaging environmental consequences. This article examines various methods of cleaning up oil spills, evaluates their effectiveness in various situations, and identifies areas where, current methods being inadequate, further research is needed. Containment, mechanical removal, shoreline cleanup, chemical treating agents, in situ burning, natural recovery and enhanced bioremediation are all assessed. The cleanup method must be selected to match environmental conditions. Results are good in quiet, sheltered waters, but need extensive development in open waters and high seas. (UK)

  16. Use of bioremediation and treatment of wetland for remediation of the accidental crude-oil spill of July 16, 2000 at the Petrobras Refinery Refinaria Presidente Getulio Vargas (REPAR), Araucaria, PR, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Millette, D. [Hydrogeo Plus Inc., Montreal, PQ (Canada); Falkiewicz, F.; Zamberlan, E. [Petrobras-REPAR, Araucaria (Brazil); Campos Carvalho, F.J.P. de [Universidade Federal do Parana, Curifiba (Brazil). Dept. de Solos; Neto, A.C.B.; Caicedo, N.O.L.; Motta Marques, D. [Universidad Federal do Rio Grande do Sul, Porto Alegre (Brazil). Instituto de pesquisas hidraulicas; Linhares, M. [Petrobras, Rio de Janeiro (Brazil)

    2003-07-01

    On July 16, 2000, a pipeline supplying oil to the PETROBRAS refinery Refinaria Presidente Getulio Vargas-REPAR, located in Araucaria, Brazil, ruptured. The resulting oil spill involved approximately 4 million litres of crude oil. Workers managed to retain a vast quantity of oil within a two-kilometre area called Ponto O. The banks and floodplain of a small stream, the Arroio Saldanha, were contaminated, as well as the soil of four small wetlands. The authors presented an overview of the remediation program implemented. They focused on the soil bioremediation and treatment of wetland programs. Some of the remediation technologies used were: in situ bioremediation, injection and recovery trenches, and treatment of wetland in the vicinity of the discharge. Most of the free product from the sector adjacent to the spill site seems to have been removed by the recovery trenches. The preliminary data obtained from soil monitoring points to the efficiency of in situ bioremediation. Wetland vegetation was successfully restored and hydrocarbons appear to have been removed from the groundwater. 2 figs.

  17. Types of Crude Oil

    Science.gov (United States)

    The petroleum industry often classifies these types by geographical source, but the classification scheme here is more useful in a spill cleanup scenario. It indicates general toxicity, physical state, and changes caused by time and weathering.

  18. Oil spill response in the marine environment

    International Nuclear Information System (INIS)

    Doerffer, J.W.

    1992-01-01

    The rapid economic development of many countries since World War II has caused a considerable increase in marine transportation of raw materials, especially of crude oils and in offshore activities. However, a significant amount of oil comes into the sea from operational discharges of ships (ballast and bilge water) as well as from incidents such as collisions, groundings and contacts, and offshore exploration and exploitation of oil and gas. These incidents have been the pivotal points in the approach of maritime nations to the protection of the marine environment through international legislation and implementation of rigorous requirements concerning the construction and exploitation of ships and offshore platforms, limiting the possibility and extent of oil spills. A new danger for marine environments has ensued recently though the increasing maritime transport of chemicals. The aim of this book is to introduce these problems, and reflect the level and trends of development in this field. (Author)

  19. Mechanical cleaning of oil spills in seawater using circular conduits

    Energy Technology Data Exchange (ETDEWEB)

    Shedid, S.; Abou Kassem, J.; Zekri, A. [United Arab Emirates Univ., Al Ain City (United Arab Emirates). Dept. of Chemical and Petroleum Engineering

    2005-10-15

    Treatment of the crude oil pollution in seawater has attracted global attention during the last two decades. This study was undertaken using circular conduits as a mechanical means to clean oil spills in seawater under different conditions of temperature, oil gravity, shaking frequency, conduit diameter, and initial thickness of oil layer. An experimental model was designed and built to achieve the study. It consists of shaking water bath (to represent sea waves) fitted with temperature controller and glass tubes of different inside diameters of 0.3 cm, 0.5 cm, and 0.7 cm. Three crude oils of different oil gravity of 35{sup o}API, 38{sup o}API, and 47{sup o}API were investigated under different shaking frequencies of 20, 40, and 60 stroke/minute with different tube diameters. The results proved that application of mechanical cleaning of oil spills using circular conduits is a practical technique. The cleaning of black oil spills is more efficient than one of volatile oil. Furthermore, the results indicated that the increase of shaking frequency and/or water temperature provide(s) faster cleaning of oil spills while temperature increase recovers the maximum oil. (Author)

  20. Identification of oil spill's sources

    International Nuclear Information System (INIS)

    Boniforti, R.

    1992-10-01

    Identifying the source of a marine oil spill is complicated because of the rapid modifications (weathering) undergone by oil as soon as it reaches the sea. Deciding if differences occurring between an oil sample collected after the spill and the original oil can be attributed to weathering involves not only adoption of sophisticated analytical methods but also correct sampling techniques and strict adherence to a chain-of-custody procedure. The method described in this paper, largely based on those adopted by some northern European countries, establishes the identity or non-identity of two samples by exploiting differences rather than similarities between them. It increases the efficiency of the method because it is sufficient to establish that there exists only one difference for deciding that two samples are different

  1. Effective operational oil spill response planning

    International Nuclear Information System (INIS)

    Meyers, R.J.

    1991-01-01

    An operational Contingency Plan is one of the single most important aspects of effective oil spill response operations. It is a spill control game plan. A thorough contingency plan provides a set of guidelines that can be used to help direct all phases of spill response activities. More than simple a compilation of lists and rosters, the contingency plan reflects strategic and philosophical elements of spill response that help to ensure a viable response to any spill incident. Facilities and oil carrying vessels should have well maintained contingency plans with these features. This paper describes the requirement for effective oil spill response pans and the training required to exercise them

  2. Oil spill response, prevention and impact: lesson from Tasman spirit

    International Nuclear Information System (INIS)

    Raja, I.A.; Doggar, M.G.

    2005-01-01

    Nearly half of the world oil is transported is transported by sea. Due to high shipping density coastal water is at high risk. Oil spills in the coastal areas endanger public health, devastate natural resources, and disrupt local economy. The Pakistani coast was hit by the worst ever ecological disaster on 27th July 03, when The Greek vessel 'Tasman Spirit', carrying 67,000 tonnes of crude oil grounded at Karachi port. High concentration of oil vapours along the affected shoreline caused discomfort. The contamination and losses could further be limited by taking appropriate actions. There is a need bring in significant improvements in oil spill prevention and response planning. This paper described the risks associated with oils spill and contingency planning to meet this situation. (author)

  3. Leaking tankers: how much oil was spilled?

    International Nuclear Information System (INIS)

    Simecek-Beatty, D. A.; Lehr, W. J.; Lankford, J. F.

    1997-01-01

    A model to estimate leak rates from tankers has been developed for use in emergency situations when more direct oil-loss estimation methods are not available. The model includes algorithms for gravity outflow and air and water ingestion. Three laboratory tests were conducted using fresh water and canola oil to evaluate the model output. Comparison with results from the laboratory experiments indicate good correlation of model results with measured data. However, it is not yet possible in the case of very large crude carriers to answer the question 'how much oil was spilled?' Sensitivity analysis and further laboratory testing were suggested to determine the effect of factors such as: pressure vacuum relief valves that prevent cavitation in the event of tank puncture; changing outside water levels due to wave and tidal action; tank and hole dimensions; and the amount and density of the product.10 refs., 4 figs

  4. Exports of crude oil, 1988

    International Nuclear Information System (INIS)

    1989-06-01

    Effective June 1, 1985, licensing and charging of oil exports ended. The Board now issues export orders specifying neither volumes nor prices and covering an exportation period of up to 1 year for light crude oil and up to 2 years for heavy crude oil, available on request to both Canadian and foreign companies. The Board has assumed a monitoring role, and export prices and volumes are reported monthly by exporters. This annual report provides a review of the volumes and prices associated with the supply and disposition of Canadian crude oil during 1988. Highlights are given with detailed information on prices, both internationally, in Canada, and the Chicago posted price by light or heavy crude, and on volumes including capacity and disposition in both domestic and export markets. A short description of the import market is included. Comparisons are made with the previous year. Export volumes of light crude oil in 1988 increased by 13% to average 50,200 m 3 /d. Export volumes of heavy crude also increased by ca 13% to 62,600 m 3 /d. 15 figs., 2 tabs

  5. Application of biosurfactant in oil spill management

    International Nuclear Information System (INIS)

    Juwarkar, A.; Babu, P.S.; Mishra, K.; Deshpande, M.

    1993-01-01

    Surfactants are surface active agents which reduce surface tension and interfacial tension between two immiscible phases and help in emulsification. Toxicity, nonbiodegradability, and limited structural types of chemical surfactants have initiated the need for effective substitutes. Biosurfactants, which are synthesized by specific microbial cultures, have surface active properties comparable to chemical surfactants. They are compounds that can help in oil spill cleanup operations without presenting the problem posed by chemical surfactants. Two bacterial cultures were isolated from oil-contaminated soil and were used for biosurfactant production. The biosurfactants produced by Bacillus licheniformis, BS1, and Pseudomonas aeruginosa, BS2, in mineral media containing glucose as the carbon source belong to the class of lipoprotein and glycolipid, respectively. They were found to reduce the surface and interfacial tension of water and water-hexadecane system from 72 dynes/cm and 40 dynes/cm to 28 to 30 dynes/cm and 1 to 3 dynes/cm, respectively. These results were comparable with chemical surfactants with respect to surface tension reduction (Slic Gone 34 dynes/ cm and Castrol 30 dynes/cm). The low interfacial tension allows the formation of stable emulsion. The two cultures were grown on different substrates, namely, glucose, mannitol, glycerol, hexadecane, oily sludge, and crude oil. Emulsion formation of hexadecane in water was tested with the cell-free broth containing biosurfactant from the respective substrate broths. Emulsions of 56% stability to 100% stability were obtained from these biosurfactant-containing broths. Both biosurfactants were able to emulsify crude oil. A surfactant's ability to form a stable emulsion is the first step in oil spill cleanup. The emulsified oil can then be acted upon very easily by the microorganism under study

  6. How much crude oil can zooplankton ingest? Estimating the quantity of dispersed crude oil defecated by planktonic copepods

    International Nuclear Information System (INIS)

    Almeda, Rodrigo; Connelly, Tara L.; Buskey, Edward J.

    2016-01-01

    We investigated and quantified defecation rates of crude oil by 3 species of marine planktonic copepods (Temora turbinata, Acartia tonsa, and Parvocalanus crassirostris) and a natural copepod assemblage after exposure to mechanically or chemically dispersed crude oil. Between 88 and 100% of the analyzed fecal pellets from three species of copepods and a natural copepod assemblage exposed for 48 h to physically or chemically dispersed light crude oil contained crude oil droplets. Crude oil droplets inside fecal pellets were smaller (median diameter: 2.4–3.5 μm) than droplets in the physically and chemically dispersed oil emulsions (median diameter: 6.6 and 8.0 μm, respectively). This suggests that copepods can reject large crude oil droplets or that crude oil droplets are broken into smaller oil droplets before or during ingestion. Depending on the species and experimental treatments, crude oil defecation rates ranged from 5.3 to 245 ng-oil copepod"−"1 d"−"1, which represent a mean weight-specific defecation rate of 0.026 μg-oil μg-C_c_o_p_e_p_o_d"1 d"−"1. Considering a dispersed crude oil concentration commonly found in the water column after oil spills (1 μl L"−"1) and copepod abundances in high productive coastal areas, copepods may defecate ∼1.3–2.6 mg-oil m"−"3 d"−"1, which would represent ∼0.15%–0.30% of the total dispersed oil per day. Our results indicate that ingestion and subsequent defecation of crude oil by planktonic copepods has a small influence on the overall mass of oil spills in the short term, but may be quantitatively important in the flux of oil from surface water to sediments and in the transfer of low-solubility, toxic petroleum hydrocarbons into food webs after crude oil spills in the sea. - Highlights: • Copepods exposed to dispersed crude oil produced fecal pellets contained numerous small oil droplets (2.4 to 3.5 µm). • Copepods could reject large oil droplets or oil droplets are broken into

  7. Effect of temperature on biodegradation of crude oil

    International Nuclear Information System (INIS)

    Zekri, A.; Chaalal, O.

    2005-01-01

    An active strain of anaerobic thermophilic bacteria was isolated from the environment of the United Arab Emirates. This project studied the effect of temperature, salinity and oil concentration on biodegradation of crude oil. Oil weight loss, microbial growth and the changes of the crude oil asphaltene concentration are used to evaluate the oil degradation by this strain. A series of batch experiments was performed to study the effects of bacteria on the degradation of crude oil. The effects of oil concentration, bacteria concentration, temperature and salinity on the biodegradation were investigated. The temperatures of the studied systems were varied between 35 and 75 o C and the salt concentrations were varied between 0 and 10%. Oil concentrations were ranged from 5 to 50% by volume. Experimental work showed the bacteria employed in this project were capable of surviving the harsh environment and degrading the crude oil at various conditions. Increasing the temperature increases the rate of oil degradation by bacteria. Increasing the oil concentration in general decreases the rate of bacteria oil degradation. Salinity plays a major role on the acceleration of biodegradation process of crude oil. An optimum salinity should be determined for every studied system. The finding of this project could be used in either the treatment of oil spill or in-situ stimulation of heavy oil wells. (author)

  8. Oil spill cleanup in severe weather and open ocean conditions

    International Nuclear Information System (INIS)

    Kowalski, T.

    1993-01-01

    Most serious oil spills occur in open water under severe weather conditions. At first the oil stays on the surface, where it is spread by winds and water currents. The action of the waves then mixes the oil into the water column. With time the light elements of crude oil evaporate. The remaining residue is of very low commercial value, but of significant environmental impact. The oil spill can move either out to sea or inshore, where it ends up on the beaches. Normal procedures are to let outbound oil disperse by evaporation and mixing into the water column, and to let the inbound oil collect on the beaches, where the cleanup operations are concentrated. The reason for this is that there is no capability to clean the surface of the water in wave conditions-present-day oil skimmers are ineffective in waves approaching 4 ft in height. It would be simpler, more effective and environmentally more beneficial to skim the oil right at the spill location. This paper describes a method to do this. In the case of an oil spill in open water and high wave conditions, it is proposed to reduce the height of the ocean waves by the use of floating breakwaters to provide a relatively calm area. In such protected areas existing oil skimmers can be used to recover valuable oil and clean up the spill long before it hits the beaches. A floating breakwater developed at the University of Rhode Island by the author can be of great benefit in oil spill cleanup for open ocean conditions. This breakwater is constructed from scrap automobile tires. It is built in units of 20 tires each, which are easily transportable and can be connected together at the spill site to form any desired configuration

  9. Oil Spill Incident Tracking [ds394

    Data.gov (United States)

    California Natural Resource Agency — The Office of Spill Prevention and Response (OSPR) Incident Tracking Database is a statewide oil spill tracking information system. The data are collected by OSPR...

  10. Bioremediation of offshore oil spills

    International Nuclear Information System (INIS)

    Goldman, E.; Tedaldi, D.J.

    1994-01-01

    This research program was directed towards the enhancement of insitu biorestoration of open sea oil spills. Bacteria possessing petroleum degrading enzymes are capable of splitting even thick, viscous oils and tars into lighter fractions. This process will occur at the oil/bacterial interface and depends upon viscosity of the oil, bacterial species, availability of ancillary nutrients, residence times and extent of mixing/oxygenation. Through the enzymatic metabolism of bacteria, a wide range of petroleum oils can be converted almost completely into CO 2 , water, cell mass and harmless biological waste products, usually within 60 to 90 days under favorable conditions. Specifically, this research work focused on the selection and examination of a floating medium which enhances the biodegradation process through improvement of conditions necessary for the process to occur. An additional effort was made to update previous citations of the order of magnitude of oil biodegradation rates and to compare laboratory measurements of biodegradation rates with field or mesocosm measurements

  11. Do oil dispersants make spilled oil more toxic to fish?

    International Nuclear Information System (INIS)

    Hodson, P.

    2010-01-01

    The Deepwater Horizon blowout in the Gulf of Mexico was the world's largest oil spill in terms of duration and volume spilled. Clean-up operations, which involved the continuous and wide-spread use of oil dispersant at the surface and at the seabed discharge point at 1500 metres depth, gave rise to public concern about dispersant toxicity. Reports from the United States Environmental Protection Agency (EPA) claimed little difference in acute toxicity to marine fish and invertebrate species among commonly available dispersants and between dispersed and non-dispersed Louisiana Sweet Crude. Technically, the toxicity of waterborne hydrocarbons does not vary with chemical dispersion. However, the EPA omitted any consideration of loading, and misled the public about the risks of dispersant use in oil clean-up. This study examined the chronic toxicity of dispersed oil to fish embryos. The study revealed that toxicity expressed as oil loading increases by a factor of 10 to 1000 times with dispersion, largely because 10 to 1000 times more oil enters the water column. Since the action of dispersant is on the exposure component of the risk equation, not on the potency of the toxic components of oil, then the risk of oil toxicity to fish increases an equivalent amount.

  12. Oil spill risk assessment : relative impact indices by oil type and location

    International Nuclear Information System (INIS)

    French-McCay, D.; Beegle-Krause, C.J.; Rowe, J.; Rodriguez, W.; Schmidt Etkin, D.

    2009-01-01

    The aim of the study was to inform policies related to resource allocation for oil spill prevention, preparedness and response activities in Washington State. Oil spill reports and impact modelling studies were evaluated in order to determine major risk consequence factors including spill volume, location, timing, toxicity, persistence, and expected frequency of spills by sector. The Washington Compensation Schedule pre-assessment screening and oil spill compensation schedule regulations (WCS) designed to consider the sensitivity of oiled areas as well as the relative density and seasonal distributions of sensitive biota. Spill incidents were assigned per-gallon impact scores based on geographic location, oil type, and season. The WCS qualitative rating system was used to assess the potential impacts of spills in different geographic systems. Geographic zones were based on geography, circulation of currents, climate, and the WCS sub-regions in estuarine and marine areas on the Pacific coast of Washington State. Oil types included crude, heavy, and light oils; gasoline; jet fuel; and non-petroleum oils. A habitat index was calculated to represent existing stream conditions. It was concluded that the relative impact risk model is a reliable method for characterizing impacts based on spill volume, oil effects, and vulnerability rankings. 25 refs., 20 tabs., 3 figs

  13. Evaluation of soil microbial communities as influenced by crude oil ...

    African Journals Online (AJOL)

    Impact of petroleum pollution in a vulnerable Niger Delta ecosystem was investigated to assess interactions in a first-generation phytoremediation site of a crude oil freshly-spilled agricultural soil. Community-level approach for assessing patterns of sole carbon-source utilization by mixed microbial samples was employed to ...

  14. Louisiana's oil spill program : new developments

    International Nuclear Information System (INIS)

    Debusschere, K.; Tedford, R.; Brolin, J.; Lorentz, W.

    2000-01-01

    The Louisiana Oil Spill Coordinator's Office (LOSCO) was established to improve oil spill response, spill prevention and coordination. Louisiana is challenged with having the highest exposure of oil spills because a large portion of its economy is based on oil and gas exploration and production. LOSCO will find ways to minimize the risk of unauthorized oil spills and will address damage assessment and restoration efforts. The aging oil and gas infrastructure in Louisiana has also been recognized as a potential major source for oil spills. LOSCO locates potential spill locations and assesses the risks associated with the sites, some of which are 100 years old. LOSCO also initiated the following two programs: (1) the Abandoned Barge Program initiated in 1993 to remove abandoned barges that pose a high risk for oil discharge, and (2) the Abandoned Non-Hazardous Oil Waste (NOW) Pit and Facility Program initiated in 1992 to locate and remove structures, pits and wells that pose a risk for oil spills. About 25,000 facilities, pits, sumps and reservoirs have been inventoried and evaluated to determine if they pose a risk to human health or the environment. The Louisiana Oil Spill Prevention and Response Act (OSPRA) of 1991 allocates up to $2 million per year for the abatement of oil spills from abandoned facilities in Louisiana. The state legislature has also created the Applied and Educational Oil Spill Research and Development Program (OSRADP) to fund oil spill research. Since 1993, OSRADP has granted 68 awards in support of 42 projects, many of which focused on recovery and cleanup methods including in-situ burning, fate and effect of oil in Louisiana environments, bioremediation, phytoremediation, composting, chemical cleaners, dispersants, sorbents, and solidifiers. 3 refs., 1 tab

  15. 15 CFR 754.2 - Crude oil.

    Science.gov (United States)

    2010-01-01

    ... processed through a crude oil distillation tower. Included are reconstituted crude petroleum, and lease... 15 Commerce and Foreign Trade 2 2010-01-01 2010-01-01 false Crude oil. 754.2 Section 754.2....2 Crude oil. (a) License requirement. As indicated by the SS notation in the “License Requirements...

  16. Oil spill response issues in Washington State

    International Nuclear Information System (INIS)

    Lempriere, P.R.

    1997-01-01

    Washington State statutes and regulations applicable to oil transport and oil spills were described. Specific provisions of the statutes and regulations and other relevant matters were also discussed. Among these were: (1) Washington State oil spill prevention plans, (2) Washington State oil spill contingency plans, (3) best achievable protection, (4) Intertanko's lawsuit against Washington State, (5) oil spill removal organizations, (6) certificates of financial responsibility in Washington State, (7) extent of potential liability under Washington Law, (8) disposal of cleanup materials, and (9) definition of 'qualified individuals' on marine vessels having the authority to implement removal actions

  17. Mercury in Canadian crude oil

    International Nuclear Information System (INIS)

    Hollebone, B.P.

    2005-01-01

    Estimates for average mercury concentrations in crude oil range widely from 10 ng/g of oil to 3,500 ng/g of oil. With such a broad range of estimates, it is difficult to determine the contributions of the petroleum sector to the total budget of mercury emissions. In response to concerns that the combustion of petroleum products may be a major source of air-borne mercury pollution, Environment Canada and the Canadian Petroleum Products Institute has undertaken a survey of the average total mercury concentration in crude oil processed in Canadian refineries. In order to calculate the potential upper limit of total mercury in all refined products, samples of more than 30 different types of crude oil collected from refineries were measured for their concentration of mercury as it enters into a refinery before processing. High temperature combustion, cold vapour atomic absorption and cold vapour atomic fluorescence were the techniques used to quantify mercury in the samples. The results of the study provide information on the total mass of mercury present in crude oil processed in Canada each year. Results can be used to determine the impact of vehicle exhaust emissions to the overall Canadian mercury emission budget. 17 refs., 2 tabs., 2 figs

  18. Occupational-health aspects of marine oil-spill response

    International Nuclear Information System (INIS)

    Park, J.M.; Holliday, M.G.

    1999-01-01

    This paper with 108 references examines the effect on oil spill cleanup workers of exposure to the crude oil via inhalation and dermal contact, and discusses exposure and the nature of crude oil, routes and magnitudes of exposure, and special cases such as the formation of aerosols, and the effect of in-situ burning of the oil on the chemical hazards associated with cleanup. The acute and chronic health effects of inhalation exposure, and the effect of exposure to oil mists and aerosols are considered. The acute and chronic health effects of dermal exposure are addressed, and some epidemiologic studies on petroleum refinery and petrochemical workers are listed with details of the methodology used and the study findings given. The chemical and physical properties of two crude oils are tabulated. (UK)

  19. OPEC's optimal crude oil price

    International Nuclear Information System (INIS)

    Horn, Manfred

    2004-01-01

    OPEC decided to stabilise oil prices within a range of 22-28 US Dollar/barrel of crude oil. Such an oil-price-level is far beyond the short and long run marginal costs of oil production, beyond even that in regions with particularly high costs. Nevertheless, OPEC may achieve its goal if world demand for oil increases substantially in the future and oil resources outside the OPEC are not big enough to accordingly increase production. In this case OPEC, which controls about 78% of world oil reserves, has to supply a large share of that demand increase. If we assume OPEC will behave as a partial monopolist on the oil market, which takes into consideration the reaction of the other producers to its own sales strategy, it can reach its price target. Lower prices before 2020 are probable only if the OPEC cartel breaks up. Higher prices are possible if production outside OPEC is inelastic as assumed by some geologists, but they would probably stimulate the production of unconventional oil based on oil sand or coal. Crude oil prices above 30 US Dollar/barrel are therefore probably not sustainable for a long period. (Author)

  20. The Congressional response to oil spills

    International Nuclear Information System (INIS)

    Grumbles, B.H.

    1990-01-01

    March 24, 1989, ushered in a new era for oil spill reform legislation. Once the Exxon Valdez ran aground Bligh Reef and gusher over 11 million gallons of crude oil into pristine waters of Prince William Sound, Alaska, Congressional debate on comprehensive federal legislation would never be the same. Stalemate and frustration marked much of the B.V. (Before Valdez) period. Oil spill bills typically died quiet deaths at the end of each Congress. A flurry of legislation and debate has marked the new A.V. (After Valdez) era, however. Spurred by public outrage, members championed far-reaching proposals. For the first time in almost twenty years, both houses passed similar comprehensive reform bills. Some bills even reached the President's desk to become public law. This paper describes previous Congressional responses as well as the 101st Congress's ongoing efforts and highlights specific provisions, issues and recurring themes in proposed comprehensive legislation (S.686 and H.R. 1465). The paper concludes with general observations on the legislation's prospects and impacts

  1. The Galeta Oil Spill. II. Unexpected Persistence of Oil Trapped in Mangrove Sediments

    Science.gov (United States)

    Burns, K. A.; Garrity, S. D.; Jorissen, D.; MacPherson, J.; Stoelting, M.; Tierney, J.; Yelle-Simmons, L.

    1994-04-01

    Sediment chemistry studies, undertaken as part of the long-term assessment of the Bahía las Minas (Panamá) oil spill, showed the unexpected persistence of the full range of aromatic hydrocarbon residues of the spilled crude oil in anoxic muds of coastal mangroves. Mangrove muds served as long-term reservoirs for chronic contamination of contiguous coastal communities for over 5 years. One result of the repeated history of oil pollution incidents along this coast was an increased proportion of dead mangrove ( Rhizophora mangle) roots in sediment cores which was related to contaminant loading and was detectable for at least 20 years after major oil spills. We suggest that this is the minimum time-scale that is to be expected for the loss of toxicity of oil trapped in muddy coastal habitats impacted by catastrophic oil spills.

  2. The Galeta oil spill: Pt. 2; Unexpected persistence of oil trapped in mangrove sediments

    Energy Technology Data Exchange (ETDEWEB)

    Burns, K.A.; Jorissen, D.; MacPherson, J.; Stoelting, M.; Tierney, J.; Yelle-Simmons, L. (Bermuda Biological Station, Ferry Reach (Bermuda)); Garrity, S.D. (Coastal Zone Analysis, Sopchoppy, FL (United States))

    1994-04-01

    Sediment chemistry studies, undertaken as part of the long-term assessment of the Bahia las Minas (Panama) oil spill, showed the unexpected persistence of the full range of aromatic hydrocarbon residues of the spilled crude oil in anoxic muds of coastal mangroves. Mangrove muds served as long-term reservoirs for chronic contamination of contiguous coastal communities for over 5 years. One result of the repeated history of oil pollution incidents along this coast was an increased proportion of dead mangrove (Rhizophora mangle) roots in sediment cores which was related to contaminant loading and was detectable for at least 20 years after major oil spills. We suggest that this is the minimum time-scale that is to be expected for the loss of toxicity of oil trapped in muddy coastal habitats impacted by catastrophic oil spills. (author)

  3. Selecting protective gloves for oil spill response and cleanup

    International Nuclear Information System (INIS)

    McDermott, H.J.

    1993-01-01

    Oil spill responders and cleanup workers must be provided with gloves that prevent skin contact while permitting them to do their job safely and efficiently. Glove selection is largely based on professional judgment, considering permeation, resistance to puncture and abrasion, and whether the material gets slick when coated with oil. This paper consolidates the most useful information from various studies and presents a selection rationale. In general, we found neoprene, polyvinyl chloride (PVC), and nitrile to be the glove materials of choice for protection in oil spills. The skin toxicity potential for most petroleum materials encountered in a spill is low. Some fresh crudes may contain hydrocarbon molecules that may penetrate the skin and cause some systemic toxicity with high enough exposure. However, as crude weathers, the more volatile hydrocarbons evaporate rapidly, leaving behind the heavier fraction, which often contains polynuclear aromatic (PNA) compounds. Some PNAs have caused skin cancer in animals after prolonged and repeated contact. As a reference, most weathered crude is similar to used motor oil in skin toxicity; prolonged and repeated skin contact should be avoided, but there is no cause for concern if some gets on the skin. The typical skin problems from excessive skin contact are drying and cracking from the defatting action of the oil itself or from the soap or hand cleaners used to remove the oil, and pustules (similar to boils) if the oil plugs the sweat glands in the skin

  4. Bioavailability of chemically-dispersed crude oil

    International Nuclear Information System (INIS)

    Harris, B.C.; Bonner, J.S.; McDonald, T.J.; Fuller, C.B.; Page, C.A.; Dimitriou-Christidis, P.; Sterling, M.C.; Autenrieth, R.L.

    2002-01-01

    Oil spills can be treated with surfactant compounds to disperse them. This method enables the hydrophobic compounds to overcome their repulsion for water, enter the water phase and be diluted. Once in the water, the biodegradation fraction of the oil biodegrades over time and the residual fraction is deposited over a large area. One major issue which is not fully understood is whether oil compounds pass through the water phase to free floating cells or directly enter oil-attached microbial cells from the oil particle. In this study, crude oil was placed in a swirling flask with Corpus Christi Bay water and was then chemically dispersed with Corexit 9500. The biodegradation was then monitored and assessed. First order rate coefficients were determined based on the disappearance of specific compounds. The rate coefficients for total target PAHs were consistent for all tests. Napthalene, phenanthrene, dibenzothiophene and their alkylated homologs were among the target compounds. The trend was also observed for total target analytes and for total target saturates. The results indicate that the biodegradation rate coefficient was not dependent on the bulk concentration of oil in the water column. It was concluded that biodegradation rates was controlled by partitioning of the compounds between the two phases, and other factors such as particle size distribution and the capability of the microbial culture, temperature and nutrients. 13 refs., 1 tab., 6 figs

  5. The price of crude oil

    International Nuclear Information System (INIS)

    Bakhtiari, A.M.S.

    1999-01-01

    The price of crude oil is among the most important prices quoted daily across the world - which is not surprising, since crude oil is the most widely used source of energy worldwide, as well as being a unique commodity. When petroleum burst onto the world stage in 1859, its price first went through some initial gyrations (1860-70), before settling in the $1.00 - 2.00 per barrel range (barring a few exceptions) for a full century. Then, the price underwent two 'shocks' (1973 and 1980), followed by the 'counter-shock' of 1986. Thereafter, the price entered the relative stability of the $15 - 20 /b consensus, where it lingered until recently. Some day, there is bound to be a fresh paradigm of 'insufficient oil reserves', thus ushering in a new era for oil prices. Taking into consideration available data on reserves and expert analysis, it would seem that that day may be years rather than decades away

  6. Market potential for Canadian crude oil

    International Nuclear Information System (INIS)

    Heath, M.; Fisher, L.; Golosinski, D.; Luthin, A.; Gill, L.; Raggett, C.

    1997-01-01

    Future key markets for Canadian crude were evaluated, and probable flow volumes and prices were identified. Key concerns of market participants such as pricing, alternative crude sources, pipeline tariffs and crude quality, were examined. An overview of the competition faced by Canadian crude supply in global markets was presented. World crude oil supply and demand was discussed. US and Canadian crude oil supply (2000 to 2010), refinery demand for light and heavy crudes, existing future crude oil and refined product pipeline infrastructure, and pricing implications of changing crude oil flows were analyzed. The general conclusion was that the US market will continue to provide growing markets for Canadian crude oil, and that the Canadian supply to fulfill increased export requirements will be available due to the combined effects of increasing heavy crude supply, growing production from the east coast offshore, and recent and ongoing pipeline expansions and additions. 20 refs., 64 tabs., 42 figs

  7. Amoco Cadiz oil spill

    Energy Technology Data Exchange (ETDEWEB)

    O' Sullivan, A J

    1978-05-01

    This report gives a preliminary account of the events surrounding the wreck of the Amoco Cadiz on the Brittany coast in March, which caused the most massive oil pollution on record. The sequence of events is outlined. Also reported are details of clean-up of beaches as well as appearance and biological effects of oil. Further studies which will continue for years include: population dynamics (species of Littorina); feeding, reproduction, settlement of Spirorbis sp; surveillance of echinoderm and crustacean populations; changes in growth and development of species of red algae; changes in concentrations of bacteria, meiofauna, chlorophyll and organic material. There are indications of problems likely to arise in: sheltered areas (sediments, salt marsh vegetation); sandy shores; upper shore vegetation (higher plants, lichens); algae (temporary loss of algal cover); intertidal macrofauna; seabirds (mortality); economy (fishing, tourism, seaweed used for fertilizer).

  8. Method for estimating boiling temperatures of crude oils

    International Nuclear Information System (INIS)

    Jones, R.K.

    1996-01-01

    Evaporation is often the dominant mechanism for mass loss during the first few days following an oil spill. The initial boiling point of the oil and the rate at which the boiling point changes as the oil evaporates are needed to initialize some computer models used in spill response. The lack of available boiling point data often limits the usefulness of these models in actual emergency situations. A new computational method was developed to estimate the temperature at which a crude oil boils as a function of the fraction evaporated using only standard distillation data, which are commonly available. This method employs established thermodynamic rules and approximations, and was designed to be used with automated spill-response models. Comparisons with measurements show a strong correlation between results obtained with this method and measured values

  9. Crude oil pipeline expansion summary

    International Nuclear Information System (INIS)

    2005-02-01

    The Canadian Association of Petroleum Producers has been working with producers to address issues associated with the development of new pipeline capacity from western Canada. This document presents an assessment of the need for additional oil pipeline capacity given the changing mix of crude oil types and forecasted supply growth. It is of particular interest to crude oil producers and contributes to current available information for market participants. While detailed, the underlying analysis does not account for all the factors that may come into play when individual market participants make choices about which expansions they may support. The key focus is on the importance of timely expansion. It was emphasized that if pipeline expansions lags the crude supply growth, then the consequences would be both significant and unacceptable. Obstacles to timely expansion are also discussed. The report reviews the production and supply forecasts, the existing crude oil pipeline infrastructure, opportunities for new market development, requirements for new pipeline capacity and tolling options for pipeline development. tabs., figs., 1 appendix

  10. Chemometric techniques in oil classification from oil spill fingerprinting.

    Science.gov (United States)

    Ismail, Azimah; Toriman, Mohd Ekhwan; Juahir, Hafizan; Kassim, Azlina Md; Zain, Sharifuddin Md; Ahmad, Wan Kamaruzaman Wan; Wong, Kok Fah; Retnam, Ananthy; Zali, Munirah Abdul; Mokhtar, Mazlin; Yusri, Mohd Ayub

    2016-10-15

    Extended use of GC-FID and GC-MS in oil spill fingerprinting and matching is significantly important for oil classification from the oil spill sources collected from various areas of Peninsular Malaysia and Sabah (East Malaysia). Oil spill fingerprinting from GC-FID and GC-MS coupled with chemometric techniques (discriminant analysis and principal component analysis) is used as a diagnostic tool to classify the types of oil polluting the water. Clustering and discrimination of oil spill compounds in the water from the actual site of oil spill events are divided into four groups viz. diesel, Heavy Fuel Oil (HFO), Mixture Oil containing Light Fuel Oil (MOLFO) and Waste Oil (WO) according to the similarity of their intrinsic chemical properties. Principal component analysis (PCA) demonstrates that diesel, HFO, MOLFO and WO are types of oil or oil products from complex oil mixtures with a total variance of 85.34% and are identified with various anthropogenic activities related to either intentional releasing of oil or accidental discharge of oil into the environment. Our results show that the use of chemometric techniques is significant in providing independent validation for classifying the types of spilled oil in the investigation of oil spill pollution in Malaysia. This, in consequence would result in cost and time saving in identification of the oil spill sources. Copyright © 2016. Published by Elsevier Ltd.

  11. Kuwait oil spill studied

    Science.gov (United States)

    Bush, Susan

    1992-02-01

    More than a year after the Persian Gulf War, scientists are still trying to assess the environmental impact of the estimated 6-8 million barrels of oil that were dumped into the gulf and to understand the environmental processes that take place in such a disturbance. Many atmospheric studies were done in the months immediately following the war, but oceanographic studies have been slower in getting started.The National Oceanic and Atmospheric Administration is currently spearheading a major oceanographic study being undertaken in the Persian Gulf by the research vessel Mt. Mitchell. The ship left its home port of Norfolk, Va., in mid-January and arrived in Muscat, Oman, on February 16 to begin a 100-day oceanographic and environmental survey. The six-leg cruise will feature physical oceanography, near-shore, and marine life studies.

  12. A 50 to 70-year-old-oil-spill : Bluefish Creek, Northwest Territories, Canada

    Energy Technology Data Exchange (ETDEWEB)

    Sikstrom, C.B. [Imperial Oil Resources, Cold Lake, AB (Canada); Jensen, P.K. [Imperial Oil Resources, Calgary, AB (Canada)

    1998-09-01

    In 1991, an oil spill was discovered in Bluefish Creek near Fort Norman, Northwest Territories. It was estimated that the spill was between 50 to 70 years old. The spill was discovered in an excavated area that appeared to be a drilling sump. The old spill exhibited an unusual occurrence of patterned partitioning of translucent wax-like material. Gas chromatography found the substance to be consistent with a paraffin based crude oil similar to Norman Wells crude oil. It is possible that Norman Wells crude was used for drilling purposes at the site. It is not likely that the Bluefish wells were the source of the oil because they were both dry holes and there were no records of hydrocarbons being encountered during drilling. Imperial Oil Resources (NWT) Ltd., and Fort Norman Band have made joint efforts in removing 118 barrels of oily debris and have successfully restored the site. 12 refs., 4 figs.

  13. AUTOMATIC CALCULATION OF OIL SLICK AREA FROM MULTIPLE SAR ACQUISITIONS FOR DEEPWATER HORIZON OIL SPILL

    Directory of Open Access Journals (Sweden)

    B. Osmanoğlu

    2012-07-01

    Full Text Available The Deepwater Horizon oil spill occurred in the Gulf of Mexico in April 2010 and became the largest accidental marine oil spill in history. Oil leaked continuously between April 20th and July 15th of 2010, releasing about 780, 000m3 of crude oil into the Gulf of Mexico. The oil spill caused extensive economical and ecological damage to the areas it reached, affecting the marine and wildlife habitats along with fishing and tourism industries. For oil spill mitigation efforts, it is important to determine the areal extent, and most recent position of the contaminated area. Satellitebased oil pollution monitoring systems are being used for monitoring and in hazard response efforts. Due to their high accuracy, frequent acquisitions, large area coverage and day-and-night operation Synthetic Aperture Radar (SAR satellites are a major contributer of monitoring marine environments for oil spill detection. We developed a new algorithm for determining the extent of the oil spill from multiple SAR images, that are acquired with short temporal intervals using different sensors. Combining the multi-polarization data from Radarsat-2 (C-band, Envisat ASAR (C-band and Alos-PALSAR (L-band sensors, we calculate the extent of the oil spill with higher accuracy than what is possible from only one image. Short temporal interval between acquisitions (hours to days allow us to eliminate artifacts and increase accuracy. Our algorithm works automatically without any human intervention to deliver products in a timely manner in time critical operations. Acquisitions using different SAR sensors are radiometrically calibrated and processed individually to obtain oil spill area extent. Furthermore the algorithm provides probability maps of the areas that are classified as oil slick. This probability information is then combined with other acquisitions to estimate the combined probability map for the spill.

  14. AMOP (Arctic Marine Oil Spill Program) studies reviewed

    Energy Technology Data Exchange (ETDEWEB)

    1978-06-05

    A discussion of the Arctic Marine Oil Spill Program organized in 1976 by the Canadian Federal Government includes: an Arctic Atlas compiled by Fenco Consultants Ltd. to give background information necessary for developing marine oil spill countermeasures for the Arctic north of 60/sup 0/ including the west Greenland coast and the Labrador shelf (geology, meteorology and oceanography, ice conditions, biology, and social factors); program in emergency transport of spill-combatting equipment; and the factors which influence the choice of conveyance, i.e., accessibility of the site, urgency for response, and quantity of material required; laboratory studies involving the release of oil under artificial sea ice in simulated ice formation and decay purposes to determine the interaction of crude oil and first-year sea ice; inability of companies and government to control a major spill in the Labrador Sea because of poor and inadequate transport facilities, communications, and navigational aids, severe environmental conditions, and logistics problems; and studies on the effects of oil-well blowouts in deep water, including formation of oil and gas hydrates, design of oil skimmers, the use of hovercraft, and specifications for an airborne multisensor system for oil detection in ice-infested waters.

  15. The response of Scirpus pungens to crude oil contaminated sediments

    International Nuclear Information System (INIS)

    Longpre, D.; Jaouich, A.; Jarry, V.; Venosa, A.D.; Lee, K.; Suidan, M.T.

    1999-01-01

    An exposure study was conducted to determine the impacts of an oil spill on the plant Scirpus pungens and to determine potential recovery rates of the species in the event of an accidental spill within the St. Lawrence River. Scirpus pungens is an important wetland plant which is essential for control of coastal erosion and which provides a unique habitat for a variety of biota. Sediments contaminated with medium-light crude oil were used in this study. Transplants in oiled and unoiled sediments were maintained in greenhouses to monitor changes in plant height, growth and mortality over a 63 day period. Results showed that plants exposed to high concentrations of oiled sediment were much smaller than those exposed to lightly contaminated sediments. Elevated oil concentrations greatly decreased plant biomass. Mortality was highly correlated with oil concentration. Transplants were able to survive, grow and produce new shoots in sediments contaminated with crude oil in a range of concentrations comparable to those associated with oil spills

  16. The response of Scirpus pungens to crude oil contaminated sediments

    Energy Technology Data Exchange (ETDEWEB)

    Longpre, D; Jaouich, A [Quebec Univ., Montreal, PQ (Canada); Jarry, V [Environment Canada, Montreal, PQ (Canada); Venosa, A D [US Environmental Protection Agency, Cincinnati, OH (United States). National Risk Management Research Lab.; Lee, K [Fisheries and Oceans Canada, Mont Joli, PQ (Canada). Inst. Maurice Lamontagne; Suidan, M T [Cincinnati Univ., Cincinnati, OH (United States). Dept. of Civil and Environmental Engineering

    1999-01-01

    An exposure study was conducted to determine the impacts of an oil spill on the plant Scirpus pungens and to determine potential recovery rates of the species in the event of an accidental spill within the St. Lawrence River. Scirpus pungens is an important wetland plant which is essential for control of coastal erosion and which provides a unique habitat for a variety of biota. Sediments contaminated with medium-light crude oil were used in this study. Transplants in oiled and unoiled sediments were maintained in greenhouses to monitor changes in plant height, growth and mortality over a 63 day period. Results showed that plants exposed to high concentrations of oiled sediment were much smaller than those exposed to lightly contaminated sediments. Elevated oil concentrations greatly decreased plant biomass. Mortality was highly correlated with oil concentration. Transplants were able to survive, grow and produce new shoots in sediments contaminated with crude oil in a range of concentrations comparable to those associated with oil spills.

  17. Oil Spill Related Heavy Metal: A Review

    International Nuclear Information System (INIS)

    Ahmad Dasuki Mustafa; Hafizan Juahir; Kamaruzzaman Yunus; Mohammad Azizi Amran; Che Noraini Che Hasnam; Fazureen Azaman; Ismail Zainal Abidin; Syahril Hirman Azmee; Nur Hishaam Sulaiman

    2015-01-01

    Oil spill occurs every day worldwide and oil contamination is a significant contributor for the higher levels of heavy metals in the environment. This study is purposely to summarize the heavy metals which significant to major oil spill incidents around the world and effects of toxic metals to human health. The study performed a comprehensive review of relevant scientific journal articles and government documents concerning heavy metals contamination and oil spills. Overall, the heavy metals most frequently been detected in oil spill related study where Pb>Ni>V>Zn>Cd and caused many effects to human health especially cancer. In conclusion, the comparison of heavy metal level between the post - spill and baseline levels must be done, and implementation of continuous monitoring of heavy metal. In addition, the result based on the strategies must be transparent to public in order to maintaining human health. (author)

  18. effect of crude oil extracts on early stages of african catfish

    African Journals Online (AJOL)

    Admin

    Nigerian Bonny light crude oil and Exxon Mobil Oso off-shore condensate during a ... of Oso condensate extract when larval integument was damaged. It is ... Spills of oil condensate from Oso Exxon Mobil Oil rig readily enter the .... compounds are extracted from oil films in natural .... Resources and Fishing Rome, 9-13 Dec.

  19. A catalogue of crude oil and oil product properties, 1990

    International Nuclear Information System (INIS)

    Bobra, M.A.; Callaghan, S.

    1990-09-01

    This catalogue is a compilation of available data on crude oils and petroleum products. The emphasis of the catalogue is upon oils which could potentially impact Canada's environment. Other oils which are unlikely to be of direct Canadian concern are also included because they have been well characterized and used in relevant studies. The properties listed for each oil are those which will provide an indication of a spilled oil's environmental behaviour and effects. The properties on which data is provided include API gravity, density, viscosity, interfacial tension, pour point, flash point, vapor pressure, volatility and component distribution, emulsion formation tendency and stability, weathering, dispersability, major hydrocarbon groups, aqueous solubility, toxicity, sulfur content, fire point, and wax content. Most of the chemical-physical properties listed in this catalogue were measured using standard tests. For certain properties, data are given at different temperatures and for different degrees of oil weathering. An oil's degree of weathering is expresed as the volume or weight percent evaporated from the fresh oil. Weathered oils used for testing were artificially weathered by gas stripping following the method of Mackay and Stiver. 109 refs

  20. A catalogue of crude oil and oil product properties, 1992

    International Nuclear Information System (INIS)

    Whiticar, S.; Bobra, M.; Liuzzo, P.; Callaghan, S.; Fingas, M.; Jokuty, P.; Ackerman, F.; Cao, J.

    1993-02-01

    This catalogue is a compilation of available data on crude oils and petroleum products. The emphasis of the catalogue is upon oils which could potentially impact Canada's environment. Other oils which are unlikely to be of direct Canadian concern are also included because they have been well characterized and used in relevant studies. The properties listed for each oil are those which will provide an indication of a spilled oil's environmental behaviour and effects. The properties on which data is provided include API gravity, density, viscosity, interfacial tension, pour point, flash point, vapor pressure, volatility and component distribution, emulsion formation tendency and stability, weathering, dispersability, major hydrocarbon groups, aqueous solubility, toxicity, sulfur content, fire point, and wax content. Most of the chemical-physical properties listed in this catalogue were measured using standard tests. For certain properties, data are given at different temperatures and for different degrees of oil weathering. An oil's degree of weathering is expresed as the volume or weight percent evaporated from the fresh oil. Weathered oils used for testing were artificially weathered by gas stripping following the method of Mackay and Stiver. 140 refs

  1. The Worldwide Oil Spill Model (WOSM)

    International Nuclear Information System (INIS)

    Anderson, E.L.; Howlett, E.; Jayko, K.; Reed, M.; Spaulding, M.; Kolluru, V.

    1993-01-01

    The Worldwide Oil Spill Model (WOSM) is a standalone microcomputer-based state-of-the-art oil spill model system for use in oil spill response decision support, planning, research, training, and contingency planning. WOSM was developed under support provided by a consortium of oil companies and government agencies. WOSM represents the next generation of oil spill model beyond the OILMAP modelling system (Spaulding et al, 1992). WOSM is designed in a shell architecture in which the only parameters that change are those that describe the area in which the spill model is to be applied. A limited function geographic information system (GIS) is integrated within the model system, and the spill modelling shell has been extended to include interfaces to other GIS systems and digital data. WOSM contains all the databases, data manipulation and graphical display tools, and models to simulate any type of oil spill. The user has control over which weathering processes are to be modelled, and WOSM data input tools enable continual refinement of model predictions as more refined data is imported. Use of WOSM is described and illustrated, showing sample screens and applications. WOSM algorithms and file structure are also outlined. An example test case of a spill in the Juan de Fuca strait is included. 29 refs., 7 figs., 1 tab

  2. Evaluation of bird impacts on historical oil spill cases using the SIMAP oil spill model

    International Nuclear Information System (INIS)

    French McCay, D.; Rowe, J.J.

    2004-01-01

    The impact of an oil spill on bird and other wildlife species can be estimated using the Spill Impact Model Application Package (SIMAP). SIMAP estimates exposure and impact on bird species and their habitat based on physical fate and biological effects models under a broad range of environmental conditions. This paper presented the evaluations of 14 spill case studies which compared model predictions of biological impacts with field observations after a spill. Most of the observational data on the biological impacts of spills was for oiled birds and other wildlife. The impact of an oil spill on fish and invertebrates was examined in one case study. Error analysis was not performed on the field-base estimates of impact. Biological abundances and impacts are highly variable in time and space and very difficult to measure and quantify. Model-predicted and field-based estimates of oiled wildlife were compared. Uncertainty in the model-predicted number of oil wildlife was most related to mapping of biological distributions, behaviour of individuals, and local population density at the time of spill. The greatest uncertainty was the pre-spill abundance. The number of animals oils was found to be directly proportional to the pre-spill abundance assumed in the model inputs. Relative impact can be inferred from the percentage of population oiled. The total number oiled by a spill can be extrapolated using trajectories of oiled birds and counts of oiled animals collected in the field. 54 refs., 16 tabs., 12 figs

  3. Heavy crude oil and synthetic crude market outlook

    International Nuclear Information System (INIS)

    Crandall, G.R.

    1997-01-01

    This presentation included an outline of the international heavy crude supply and demand versus Canadian heavy crude supply and disposition, and pricing outlook for synthetic crudes. Differences among crude oils such as light sweet, light sour, heavy and bitumen were described and illustrated with respect to their gravity, API, percentage of sulphur, metals and nitrogen. Internationally, heavy and sour crude supplies are forecast to increase significantly over the next four years. Discoveries of light sour crude in offshore Gulf of Mexico will provide a major new source of sour crude to U.S. Gulf Coast refineries. Venezuela's supplies of heavy and sour crude are also expected to increase over the next few years. Mexico and Canada have plans to increase their heavy crude production. All of the crudes will be aimed at the U.S. Gulf Coast and Midwest markets. Pentanes and condensates are also expected to increase based on the growing Canadian natural gas production. Diluent demand will also grow to match Canadian heavy crude/bitumen production. U.S. midwest refiners are proposing expansions to allow them to process more Canadian heavy crude oil. At present, only a few refineries are equipped to process significant amounts of synthetic crude. It was suggested that to absorb available heavy and synthetic production, increased penetration into both Canadian and U.S. markets will be required. Some refineries may have to be modified to process heavy and synthetic oil supplies. Heavy oil and synthetic producers may need to develop relationships with refiners such as joint ventures and term supply agreements to secure markets. 2 tabs., 12 figs

  4. First crude oil from Chukotka

    Energy Technology Data Exchange (ETDEWEB)

    Arenbrister, L.P.; Demidenko, K.A.; Zhmykhova, N.M.

    1986-01-01

    The physicochemical properties of the crude taken from Neogene deposits at a depth of 1486-1443 m are analyzed. The oil is distinguished by low contents of sulfur and resinous-asphaltenic substances, a high content of wax, and a high yield of light cuts distilling below 350 degrees C. The naptha cuts have high contents of naphthenes, and the diesel fuel cuts have high cetane numbers, low sulfur contents, and high contents of straight chain paraffins. The vacuum gasoil has a low density, a low viscosity, a low carbon residue and low contents of sulfur and nitrogen. This gasoil is a good feedstock for catalytic cracking and hydrocracking. The Verkhne-Echin crude is classified as light, low-sulfur, lowresin and high-wax. It can be used to produce jet fuels and summer-grade diesel fuels with low sulfur contents, as well as high-V.I. lube base stocks and liquid and solid paraffins.

  5. In-Situ Burning of Crude Oil on Water

    DEFF Research Database (Denmark)

    van Gelderen, Laurens

    in the small scale water basin. Boilovers were also observed during the burning of a heavy crude oil with a substantial light fraction without a water layer, however, which suggests that water is not essential for boilover occurrence. Further studies are required to determine the conditions under which......The fire dynamics and fire chemistry of in-situ burning of crude oil on water was studied in order to improve predictions on the suitability of this oil spill response method. For this purpose, several operational parameters were studied to determine the factors that control the burning efficiency...... of in-situ burning, i.e. the amount of oil (in wt%) removed from the water surface by the burning process. The burning efficiency is the main parameter for expressing the oil removal effectiveness of in-situ burning as response method and is thus relevant for suitability predictions of in-situ burning...

  6. Oil Spill Public Information Center: Its role in the flow of information on the Exxon Valdez oil spill

    International Nuclear Information System (INIS)

    Holba, C.; McGee, M.; Thompson, P.

    1993-01-01

    On March 24, 1989, the supertanker Exxon Valdez struck a sub- merged rock pinnacle at Bligh Reef, puncturing eight of its storage tanks. Within hours, 11 million gallons of crude oil were dumped into the waters of Prince William Sound. The cleanup, damage assessment, and restoration activities undertaken for this environmentally complex area presented multifaceted challenges to public and private organizations and various professional disciplines. One of these challenges was obtaining and disseminating prespill, spill, and postspill information for both the private and public sector. The Oil Spill Public Information Center (OSPIC) was created for this purpose by the US Department of Justice on behalf of the federal trustees. Its management has since been assumed by the restoration team, an arm of the state-federal Exxon Valdez Oil Spill Trustee Council. On October 8, 1991, a settlement agreement was approved in United States District Court, which required Exxon to pay $1 billion in criminal restitution and civil damages to the United States and the state of Alaska. The settlement terms specify that the Trustee Council shall establish procedures providing for meaningful public participation in the injury assessment and restoration process. Consistent with that mandate, the OSPIC is responsible for providing a repository for all material related to the Exxon Valdez oil spill, The OSPIC is a specialized library open to the public. Its function is to collect, organize, and make accessible materials generated by state and federal agencies and the private sector as a result of the cleanup, damage assessment, and restoration activities of the spill. The OSPIC staff is also identifying and collecting baseline studies in the Prince William Sound and Gulf of Alaska areas, as well as materials on cold water marine spills. The OSPIC serves a variety of patrons, including industry, the oil spill response community, state and federal agencies, scientists, etc

  7. Laboratory studies of oil spill bioremediation; toward understanding field behavior

    International Nuclear Information System (INIS)

    Prince, R.C.; Hinton, S.M.; Elmendorf, D.L.; Lute, J.R.; Grossman, M.J.; Robbins, W.K.; Hsu, Chang S.; Richard, B.E.; Haith, C.E.; Senius, J.D.; Minak-Bernero, V.; Chianelli, R.R.; Bragg, J.R.; Douglas, G.S.

    1993-01-01

    Oil spill remediation aims to enhance the natural process of microbial hydrocarbon biodegradation. The microbial foundations have been studied throughout this century, but the focus of most of this work has been on the degradation of well defined compounds by well defined microbial species. This paper addresses laboratory studies on crude oil biodegradation by microbial consortia obtained from oiled beaches in Prince William Sound, Alaska following the spill from the Exxon Valdez. It demonstrates that oil degradation is indeed likely to be nitrogen-limited in Prince William Sound, the different molecular classes in crude oil that are subjected to biodegradation, the identification of conserved species in the oil that can be used for assessing biodegradation and bioremediation in the field, the effectiveness of fertilizers in stimulating sub-surface biodegradation, the role of the olephilic fertilizer Inipol EAP22, and the identification of the oil-degrading microorganisms in Prince William Sound. Together, these laboratory studies provided guidance and important insights into the microbial phenomena underlying the successful bioremediation of the oiled shorelines

  8. Oil spill trajectory analysis for the Calcasieu Estuary

    International Nuclear Information System (INIS)

    Meselhe, E.A.; Barker, C.H.; Hodges, M.

    2001-01-01

    A three-dimensional hydrodynamic model (H3D) was used to determine how oil spills might travel and spread within the Calcasieu River Estuary which has heavy oil traffic. The Calcasieu River is located in the southwest corner of the State of Louisiana and houses valuable wetlands that provide both commercial and recreational fishing and wildlife value to the area. These wetlands also filter water and protect Louisiana's coast areas from hurricane storm surges. An oil spill would damage areas of marshes that would have devastating effects on the entire ecological system within the estuary. A Trajectory Analysis Planner (TAP) H3D computer model is under development by the Hazardous Materials Response Division of the National Oceanic and Atmospheric Administration (NOAA). TAP is a statistical planning tool that randomly samples historical hydrodynamic, hydrology and climatological data, to build up a database with biological and cleanup resource information. TAP can be used to predict which sites within the estuarine system will be most susceptible to oil spills of varying magnitudes, materials and locations. TAP can also estimate the time available for mitigation and remedial actions before the spill can impact the site. Hydrodynamics in the Calcasieu estuary is a combination of processes such as saltwater intrusion and response to water level fluctuations at an open boundary, as well as lake dynamics. H3D provides the three components of velocity, plus scalar quantities such as water levels, temperature and salinity distribution on a Cartesian three-dimensional grid. TAP was tested for spills of kerosene, non-weathering oil, crude oil, and gasoline and was able to perform reliable spill trajectory analysis. 12 refs., 9 figs

  9. In-situ burning of spilled oil

    International Nuclear Information System (INIS)

    Tennyson, E.J.

    1992-01-01

    This presentation provided an overview of results from the Minerals Management Service's (MMS) funded research on in situ burning of spilled oil. The program began in 1983 to determine the limitations of this innovative response strategies. Specific physical variables evaluated were slick thickness, degree of weathering (sparging), sea state, wind velocities, air and water temperatures, degrees of emulsification and degree of ice-coverage. All of the oils tested burned with 50 to 95 percent removal ratios as long as emulsification had not occurred. Slick thickness of 3mm or thicker were required to sustain ignition and extinguishment occurred when the slick reached approximately 1mm thick. The next phase of the research involved quantitative analysis of the pollutants created by in situ burning including chemical composition of the parent oil, burn residue, and airborne constituents. These studies were conducted at the National Institute of Standards and Technology (NIST) with emphasis on particulate, and gaseous components created by the burning process. Research efforts over several years, and a variety of crude oils, yielded data which indicated that aldehydes ketones, dioxans, furans, and polyaromatic compounds (PAHS) were not formed in the burning process. The airborne pollutants reflected similar concentrations of these compounds that were present in the parent oil. Lighter molecular weight PAHs tended to be converted to higher molecular weight compounds. Heavier molecular weight compounds are considered less acutely toxic than lighter molecular weight PAHS. Predominant burn products released into the air were by weight: 75% carbon dioxide, 12% water vapor, 10% soot, 3% carbon monoxide and 0.2% other products including those listed above

  10. Computer based training for oil spill management

    International Nuclear Information System (INIS)

    Goodman, R.

    1993-01-01

    Large oil spills are infrequent occurrences, which poses a particular problem for training oil spill response staff and for maintaining a high level of response readiness. Conventional training methods involve table-top simulations to develop tactical and strategic response skills and boom-deployment exercises to maintain operational readiness. Both forms of training are quite effective, but they are very time-consuming to organize, are expensive to conduct, and tend to become repetitious. To provide a variety of response experiences, a computer-based system of oil spill response training has been developed which can supplement a table-top training program. Using a graphic interface, a realistic and challenging computerized oil spill response simulation has been produced. Integral to the system is a program editing tool which allows the teacher to develop a custom training exercise for the area of interest to the student. 1 ref

  11. Microbial population changes during bioremediation of an experimental oil spill

    International Nuclear Information System (INIS)

    Venosa, A.D.; Stephen, J.R.; Macnaughton, S.J.; Chang, Y.; White, D.C.

    2000-01-01

    Three crude oil bioremediation techniques were tested in a field experiment in Delaware, United States to determine the progress of natural and accelerated attenuation during a controlled oil spill. The four treatments studied were: no oil control, oil alone, oil plus nutrients, and oil plus nutrients plus an indigenous inoculum. During the first 14 weeks, microbial numbers were high but were steadily declining with no major differences among treatments. However, after the 14 week period, phospholipid fatty acid (PLFA) results showed that the communities shifted from being composed mostly of eukaryotes to gram-negative bacteria. The dominant species diversity changed and increased significantly over 14 weeks. Nutrient addition and the addition of the indigenous inoculum altered the nature of this change. Gas chromatography/mass spectrometry analyses of the oil analytes detected major differences in rates of biodegradation between the amended and unamended natural attenuation plots, but not between the nutrient and inoculum plots. 11 refs., 3 figs

  12. Synopsis of an oil spill modeling workshop

    International Nuclear Information System (INIS)

    Finnigan, T.D.

    1996-01-01

    The performance quality of various PC-based numerical spill models available on the market, were evaluated in a special spill modeling workshop. The models examined included OSSM/ADIOS, WOSM, OILMAP, SPILLSIM, and COZOIL. It was found that most oil spill trajectory models are based on the same basic trajectory and fates algorithms, but often provide different results. This anomaly was attributed to variations in how the algorithms are programmed and implemented. The lack of uniformity of predictions has contributed to a lack of faith in model results by local authorities, spill response operators and logistics groups. Some of the criticism levelled against the merits of the different spill models was considered unjustified by workshop participants. A list of 'best practices' for modeling/response strategies was compiled, and steps to be taken to minimize the variations in spill trajectory and weathering forecasts that would likely improve the usefulness of the models were identified. 15 refs., 4 figs

  13. Oil spill problems and sustainable response strategies through new technologies.

    Science.gov (United States)

    Ivshina, Irena B; Kuyukina, Maria S; Krivoruchko, Anastasiya V; Elkin, Andrey A; Makarov, Sergey O; Cunningham, Colin J; Peshkur, Tatyana A; Atlas, Ronald M; Philp, James C

    2015-07-01

    Crude oil and petroleum products are widespread water and soil pollutants resulting from marine and terrestrial spillages. International statistics of oil spill sizes for all incidents indicate that the majority of oil spills are small (less than 7 tonnes). The major accidents that happen in the oil industry contribute only a small fraction of the total oil which enters the environment. However, the nature of accidental releases is that they highly pollute small areas and have the potential to devastate the biota locally. There are several routes by which oil can get back to humans from accidental spills, e.g. through accumulation in fish and shellfish, through consumption of contaminated groundwater. Although advances have been made in the prevention of accidents, this does not apply in all countries, and by the random nature of oil spill events, total prevention is not feasible. Therefore, considerable world-wide effort has gone into strategies for minimising accidental spills and the design of new remedial technologies. This paper summarizes new knowledge as well as research and technology gaps essential for developing appropriate decision-making tools in actual spill scenarios. Since oil exploration is being driven into deeper waters and more remote, fragile environments, the risk of future accidents becomes much higher. The innovative safety and accident prevention approaches summarized in this paper are currently important for a range of stakeholders, including the oil industry, the scientific community and the public. Ultimately an integrated approach to prevention and remediation that accelerates an early warning protocol in the event of a spill would get the most appropriate technology selected and implemented as early as possible - the first few hours after a spill are crucial to the outcome of the remedial effort. A particular focus is made on bioremediation as environmentally harmless, cost-effective and relatively inexpensive technology. Greater

  14. Airborne detection and mapping of oil spills, Grand Bahamas, February 1973

    Energy Technology Data Exchange (ETDEWEB)

    Devilliers, J N

    1973-09-01

    An airborne exercise is described employing various sensors to investigate their ability to detect and map Louisiana crude and naphtha oil spills, both by day and by night. It is shown that photographic, infrared scanning, and low light level television all have some ability to detect Louisiana crude, but only infrared scanning detected naphtha. None of these sensors could identify the anomalies as oil. A laser fluorosensor showed promise in detecting oil at night. (Author) (GRA)

  15. San Jacinto River oil spill: wetland bioremediation project

    International Nuclear Information System (INIS)

    Mills, M.A.; Bonner, J.S.

    1996-01-01

    Gasoline, diesel and unrefined Arabian light crude oil were accidentally released into the San Jacinto River after a series of pipelines ruptured. Natural removal processes (volatilization, dissolution, weathering), fire, and the spill clean-up effort, removed approximately 95% of the petroleum. The area where residual oil was found was an estuarine wetland on the lower San Jacinto River. Samples were collected from 21 study areas and an evaluation of the varying levels of bioremediation was conducted. Phase one has been completed and involved the evaluation of the natural recovery of oil from the spill. Phase two was still in progress and involved the addition of inorganic nutrients and the alternate electron acceptor to enhance the biodegradation of the petroleum. Results showed that biodegradation was responsible for much of the reduction of certain components in petroleum within the first 150 days. 12 refs., 8 figs

  16. Comparison of crude oil interfacial behavior

    Energy Technology Data Exchange (ETDEWEB)

    Beetge, J.H.; Panchev, N. [Champion Technologies Inc., Fresno, TX (United States)

    2008-07-01

    The bulk properties of crude oil are used to predict its behaviour with regards to treatment, transport and processing. Surface active components, such as asphaltenes, are often used to study or explain critical interfacial behaviour of crude oil. This study investigated the differences and similarities in the interfacial behaviour of the collective surface active component in various crude oils from different sources. The properties of interfaces between crude oil and water were compared using a Teclis drop shape tensiometer. A portion of a crude oil sample was diluted in toluene and contacted with water in a rising drop configuration. Dynamic surface tension and interfacial rheology was examined as a function of time from the early stages of interface formation. Sinusoidal oscillation of the drop volume allowed for the evaluation of visco-elastic behaviour of the crude oil/water interface as it developed with time. The Gibbs elastic modulus, as well as its elastic and viscose components were calculated from the drop shape. The interfacial behaviour was expressed in terms of concentration, oscillation frequency and interface age. It was concluded that knowledge of crude oil interfacial character could be of value in the treatment, transport and processing of crude oils because the its behaviour may play a significant role in crude oil production and processing.

  17. Histopathologic lesions in sea otters exposed to crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Lipscomb, T.P.; Harris, R.K.; Moeller, R.B.; Pletcher, J.M.; Haebler, R.J.; Ballachey, B.E. (Armed Forces Institute of Pathology, Washington, DC (United States))

    1993-01-01

    Following the Exxon Valdez oil spill in Prince William Sound, Alaska, sea otters (Enhydra lutris) that appeared to be contaminated with oil, that were in danger of becoming contaminated, or that were behaving abnormally were captured and taken to rehabilitation centers. Exposure to oil was assessed by visual examination when otters arrived at the centers. Degree of oil exposure was graded according to the following criteria: oil covering greater than 60% of the body--heavily contaminated; oil covering 30-60% of the body--moderately contaminated; oil covering less than 30% of the body or light sheen on fur--lightly contaminated. If there was no oil visible, otters were considered uncontaminated. Tissues from 51 oil-contaminated sea otters (14 males, 37 females) and from six uncontaminated sea otters (three males, three females) that died in rehabilitation centers were examined histologically. Among oil-contaminated sea otters, 19/46 had interstitial pulmonary emphysema, 13/40 had gastric erosion and hemorrhage, 11/47 had centrilobular hepatic necrosis, 14/47 had periportal to diffuse hepatic lipidosis, and 10/42 had renal tubular lipidosis. Of the uncontaminated sea otters, 1/6 had gastric erosion and hemorrhage and 1/6 had diffuse hepatic lipidosis. Histologic examinations were performed on tissues from five sea otters found dead with external oil present 15 to 16 days after the spill. Periportal hepatic lipidosis and renal tubular lipidosis were found in 3/5, and interstitial pulmonary emphysema was found in 1/5. Tissues from six apparently normal sea otters collected from an area not affected by an oil spill were examined histologically, and none of these lesions were found. We conclude that interstitial pulmonary emphysema, centrilobular hepatic necrosis, and hepatic and renal lipidosis of sea otters were associated with exposure to crude oil. Gastric erosion and hemorrhage may have been associated with stress of captivity and/or oil exposure.

  18. Histopathologic lesions in sea otters exposed to crude oil

    Science.gov (United States)

    Lipscomb, T.P.; Harris, R.K.; Moeller, R.B.; Pletcher, J.M.; Haebler, R.J.; Ballachey, Brenda E.

    1993-01-01

    Following the Exxon Valdez oil spill in Prince William Sound, Alaska, sea otters (Enhydra lutris) that appeared to be contaminated with oil, that were in danger of becoming contaminated, or that were behaving abnormally were captured and taken to rehabilitation centers. Exposure to oil was assessed by visual examination when otters arrived at the centers. Degree of oil exposure was graded according to the following criteria: oil covering greater than 60% of the body - heavily contaminated; oil covering 30–60% of the body - moderately contaminated; oil covering less than 30% of the body or light sheen on fur - lightly contaminated. If there was no oil visible, otters were considered uncontaminated. Tissues from 51 oil-contaminated sea otters (14 males, 37 females) and from six uncontaminated sea otters (three males, three females) that died in rehabilitation centers were examined histologically. Among oil-contaminated sea otters, 19/46 had interstitial pulmonary emphysema, 13/40 had gastric erosion and hemorrhage, 11/47 had centrilobular hepatic necrosis, 14/47 had periportal to diffuse hepatic lipidosis, and 10/42 had renal tubular lipidosis. Of the uncontaminated sea otters, 1/6 had gastric erosion and hemorrhage and 1/6 had diffuse hepatic lipidosis. Histologic examinations were performed on tissues from five sea otters (three males, two females) found dead with external oil present 15 to 16 days after the spill. Periportal hepatic lipidosis and renal tubular lipidosis were found in 3/5, and interstitial pulmonary emphysema was found in 1/5. Tissues from six apparently normal sea otters (four males, two females) collected from an area not affected by an oil spill were examined histologically, and none of these lesions were found. We conclude that interstitial pulmonary emphysema, centrilobular hepatic necrosis, and hepatic and renal lipidosis of sea otters were associated with exposure to crude oil. Gastric erosion and hemorrhage may have been associated with

  19. Characteristics of bicyclic sesquiterpanes in crude oils and petroleum products.

    Science.gov (United States)

    Yang, Chun; Wang, Zhendi; Hollebone, Bruce P; Brown, Carl E; Landriault, Mike

    2009-05-15

    This study presents a quantitative gas chromatography-mass spectrometry analysis of bicyclic sesquiterpanes (BSs) in numerous crude oils and refined petroleum products including light and mid-range distillate fuels, residual fuels, and lubricating oils collected from various sources. Ten commonly recognized bicyclic sesquiterpanes were determined in all the studied crude oils and diesel range fuels with principal dominance of BS3 (C(15)H(28)), BS5 (C(15)H(28)) and BS10 (C(16)H(30)), while they were generally not detected or in trace in light fuel oils like gasoline and kerosene and most lubricating oils. Laboratory distillation of crude oils demonstrated that sesquiterpanes were highly enriched in the medium distillation fractions of approximately 180 to 481 degrees C and were generally absent or very low in the light distillation fraction (boiling point to approximately 180 degrees C) and the heavy residual fraction (>481 degrees C). The effect of evaporative weathering on a series of diagnostic ratios of sesquiterpanes, n-alkanes, and biomarkers was evaluated with two suites of weathered oil samples. The change of abundance of sesquiterpanes was used to determine the extent of weathering of artificially evaporated crude oils and diesel. In addition to the pentacyclic biomarker C(29) and C(30) alphabeta-hopane, C(15) and C(16) sesquiterpanes might be alternative internal marker compounds to provide a direct way to estimate the depletion of oils, particularly diesels, in oil spill investigations. These findings may offer potential applications for both oil identification and oil-source correlation in cases where the tri- to pentacyclic biomarkers are absent due to refining or environmental weathering of oils.

  20. Degradation of crude oil by marine cyanobacteria

    Digital Repository Service at National Institute of Oceanography (India)

    Raghukumar, C.; Vipparty, V.; David, J.J.; Chandramohan, D.

    The marine cyanobacteria Oscillatoria salina Biswas, Plectonema terebrans Bornet et Flanhault and Aphanocapsa sp. degraded Bombay High crude oil when grown in artificial seawater nutrients as well as in plain natural seawater. Oil removals...

  1. Novel insight into the role of heterotrophic dinoflagellates in the fate of crude oil in the sea

    DEFF Research Database (Denmark)

    Almeda, Rodrigo; Connelly, Tara L.; Buskey, Edward J.

    2014-01-01

    Although planktonic protozoans are likely to interact with dispersed crude oil after a spill, protozoan-mediated processes affecting crude oil pollution in the sea are still not well known. Here, we present the first evidence of ingestion and defecation of physically or chemically dispersed crude...... to 0.37 mu g-oil mg-C-dino (-1) d(-1), which could represent similar to 17% to 100% of dispersed oil in surface waters when heterotrophic dinoflagellates are abundant or bloom. Egestion of faecal pellets containing crude oil by heterotrophic dinoflagellates could contribute to the sinking and flux...... of toxic petroleum hydrocarbons in coastal waters. Our study indicates that crude oil ingestion by heterotrophic dinoflagellates is a noteworthy route by which petroleum enters marine food webs and a previously overlooked biological process influencing the fate of crude oil in the sea after spills....

  2. [Scientific basis of environmental health contingency planning for a coastal oil spill].

    Science.gov (United States)

    Kim, Young Min; Cheong, Hae Kwan; Kim, Jong Ho; Kim, Jong Hun; Ko, Kumsook; Ha, Mina

    2009-03-01

    This study presents a scientific basis for the establishment of an environmental health contingency plan for dealing with accidental coastal oil spills and suggests some strategies for use in an environmental health emergency. We reviewed the existing literature, and analyzed the various fundamental factors involved in response strategies for oil spill. Our analysis included data derived from Hebei Spirit oil spill and used air dispersion modeling. Spill amounts of more than 1,000 kl can affect the health of residents along the coast, especially those who belong to vulnerable groups. Almost 30% of South Korean population lives in the vicinity of the coast. The area that is at the highest risk for a spill and that has the greatest number of people at risk is the stretch of coastline from Busan to Tongyeong. The most prevalent types of oil spilt in Korean waters have been crude oil and bunker-C oil, both of which have relatively high specific gravity and contain volatile organic compounds, polycyclic aromatic hydrocarbons, and metals. In the case of a spill of more than 1,000 kl, it may be necessary to evacuate vulnerable and sensitive groups. The government should establish environmental health planning that considers the spill amount, the types of oil, and the distance between the spot of the accident and the coast, and should assemble a response team that includes environmental health specialists to prepare for the future oil spill.

  3. Monitoring of pipeline oil spill fire events using Geographical Information System and Remote Sensing

    Science.gov (United States)

    Ogungbuyi, M. G.; Eckardt, F. D.; Martinez, P.

    2016-12-01

    Nigeria, the largest producer of crude oil in Africa occupies sixth position in the world. Despite such huge oil revenue potentials, its pipeline network system is consistently susceptible to leaks causing oil spills. We investigate ground based spill events which are caused by operational error, equipment failure and most importantly by deliberate attacks along the major pipeline transport system. Sometimes, these spills are accompanied with fire explosion caused by accidental discharge, natural or illegal refineries in the creeds, etc. MODIS satellites fires data corresponding to the times and spill events (i.e. ground based data) of the Area of Interest (AOI) show significant correlation. The open source Quantum Geographical Information System (QGIS) was used to validate the dataset and the spatiotemporal analyses of the oil spill fires were expressed. We demonstrate that through QGIS and Google Earth (using the time sliders), we can identify and monitor oil spills when they are attended with fire events along the pipeline transport system accordingly. This is shown through the spatiotemporal images of the fires. Evidence of such fire cases resulting from bunt vegetation as different from industrial and domestic fire is also presented. Detecting oil spill fires in the study location may not require an enormous terabyte of image processing: we can however rely on a near-real-time (NRT) MODIS data that is readily available twice daily to detect oil spill fire as early warning signal for those hotspots areas where cases of oil seepage is significant in Nigeria.

  4. Oil spill models for emergency response

    International Nuclear Information System (INIS)

    Hodgins, D.O.

    1997-01-01

    The need for, and the nature of an oil spill model, were discussed. Modern oil spill models were shown to provide rapid and accurate input of information about a marine spill, as well as to provide powerful visualization methods for displaying output data. Marine oil spill models are designed to answer five questions: (1) where will the oil go in 2, 3, 6, 12, and 24 hours, (2) how fast will it move, (3) how big will the slick get, (4) how much will end up on shore and where, and (5) how do the oil properties change. The models are able to provide timely and accurate results by using reasonably complete algorithms for the physics and chemistry governing oil slick evolution that take advantage of computer visualization methods for displaying output data. These models have been made possible through new technologies which have increased access to environmental data on winds, currents and satellite imaging of slicks. Spill modelling is also evolving by taking advantage of the Internet for both acquisition of input data and dissemination of results. 5 figs

  5. Crude oil growth impact on pipelines

    International Nuclear Information System (INIS)

    Devries, O.

    2005-01-01

    This paper provided an outline of crude oil production and supply in Canada. Details of oil sands projects in Athabasca, Cold Lake and Peace River were presented. A chart of oil sands growth by major project was provided. A list of new emerging oil sands crude types was also presented along with details of a synthetic bitumen blending synergy. Maps of Western Canadian crude oil markets were provided, along with details of refinery and market demand by crude type. Various pipeline alternatives to new markets were examined, with reference to Enbridge Pipeline's supply and capacity. Details of the Hardisty to U.S Gulf Coast Pipeline and the Edmonton to Prince Rupert Pipeline and its terminal and dock facilities were presented. It was concluded that pipeline capacity and seasonal factors will influence market demand, while linefill, crude types and the quality of the product will influence operational strategies. tabs., figs

  6. GOM Deepwater Horizon Oil Spill: A Time Series Analysis of Variations in Spilled Hydrocarbons

    Science.gov (United States)

    Palomo, C. M.; Yan, B.

    2013-12-01

    An estimated amount of 210 million gallons of crude oil was released into the Gulf of Mexico (GOM) from April 20th to July 15th 2010 during the Deepwater Horizon oil rig explosion. The spill caused a tremendous financial, ecological, environmental and health impact and continues to affect the GOM today. Variations in hydrocarbons including alkanes, hopanes and poly-cyclic aromatic hydrocarbons (PAHs) can be analyzed to better understand the oil spill and assist in oil source identification. Twenty-one sediment samples*, two tar ball samples and one surface water oil sample were obtained from distinct locations in the GOM and within varying time frames from May to December 2010. Each sample was extracted through the ASE 200 solvent extractor, concentrated down under nitrogen gas, purified through an alumina column, concentrated down again with nitrogen gas and analyzed via GC X GC-TOF MS. Forty-one different hydrocarbons were quantified in each sample. Various hydrocarbon 'fingerprints,' such as parental :alkylate PAH ratios, high molecular weight PAHs: low molecular weight alkane ratios, and carbon preference index were calculated. The initial objective of this project was to identify the relative hydrocarbon contributions of petrogenic sources and combustion sources. Based on the calculated ratios, it is evident that the sediment core taken in October of 2010 was greatly affected by combustion sources. Following the first month of the spill, oil in the gulf was burned in attempts to contain the spill. Combustion related sources have quicker sedimentation rates, and hydrocarbons from a combustion source essentially move into deeper depths quicker than those from a petrogenic source, as was observed in analyses of the October 2010 sediment. *Of the twenty-one sediment samples prepared, nine were quantified for this project.

  7. Management and legislative implications of recent oil spills

    International Nuclear Information System (INIS)

    Ehler, C.N.

    1990-01-01

    This paper presents information on the National Oceanic and Atmospheric Administration's role in actions following oil spills. Topics include: NDAA's scientific support coordination during oil spill responses, NDAA's involvement in the Exxon Valdez spill; measures that may be taken for improved spill response; NOAA's environmental damage assessment and restoration planning activities

  8. Risk analysis in oil spill response planning

    International Nuclear Information System (INIS)

    Chernoplekov, A.N.; Alexandrov, A.A.

    2005-01-01

    Tiered response is a basic approach to emergency plans, including oil spill response (OSR). This paper delineates a huge set of accidental scenarios within a certain tier of response generated by a computer during risk assessment. Parameters such as the amount of oil spilled, duration of discharge and types of losses should be provided in OSR scenarios. Examples of applications include offshore installations, sub sea or onshore pipelines, and localized onshore facilities. The paper demonstrates how to use risk analysis results for delineating all likely spills into groups that need a specific tier response. The best world practices and Russian regulatory approaches were outlined and compared. Corresponding algorithms were developed and their application in pipelines was presented. The algorithm combines expert's skills and spill trajectory modeling with the net environmental benefit analysis principle into the incident specific emergency response planning. 9 refs., 13 tabs., 2 figs

  9. TESTING THE GENERALIZATION EFFICIENCY OF OIL SLICK CLASSIFICATION ALGORITHM USING MULTIPLE SAR DATA FOR DEEPWATER HORIZON OIL SPILL

    Directory of Open Access Journals (Sweden)

    C. Ozkan

    2012-07-01

    Full Text Available Marine oil spills due to releases of crude oil from tankers, offshore platforms, drilling rigs and wells, etc. are seriously affecting the fragile marine and coastal ecosystem and cause political and environmental concern. A catastrophic explosion and subsequent fire in the Deepwater Horizon oil platform caused the platform to burn and sink, and oil leaked continuously between April 20th and July 15th of 2010, releasing about 780,000 m3 of crude oil into the Gulf of Mexico. Today, space-borne SAR sensors are extensively used for the detection of oil spills in the marine environment, as they are independent from sun light, not affected by cloudiness, and more cost-effective than air patrolling due to covering large areas. In this study, generalization extent of an object based classification algorithm was tested for oil spill detection using multiple SAR imagery data. Among many geometrical, physical and textural features, some more distinctive ones were selected to distinguish oil and look alike objects from each others. The tested classifier was constructed from a Multilayer Perception Artificial Neural Network trained by ABC, LM and BP optimization algorithms. The training data to train the classifier were constituted from SAR data consisting of oil spill originated from Lebanon in 2007. The classifier was then applied to the Deepwater Horizon oil spill data in the Gulf of Mexico on RADARSAT-2 and ALOS PALSAR images to demonstrate the generalization efficiency of oil slick classification algorithm.

  10. Seahorse (Hippocampus reidi) as a bioindicator of crude oil exposure.

    Science.gov (United States)

    Delunardo, Frederico Augusto Cariello; de Carvalho, Luciano Rodrigues; da Silva, Bruno Ferreira; Galão, Michel; Val, Adalberto Luís; Chippari-Gomes, Adriana R

    2015-07-01

    This study explored the suitability of the seahorse Hippocampus reidi (Ginsburg, 1933) for assessing biomarkers of genotoxic effects and its use as a sentinel organism to detect the effects of acute exposure to petroleum hydrocarbons. Fish were exposed to three concentrations of crude oil (10, 20 and 30 g/kg) for 96 h, and the activity of phase II biotransformation enzyme glutathione S-transferase (GST) was measured. In addition, we performed genotoxicity assays, such as comet assay, micronucleus (MN) test and nuclear abnormalities (NA) induction, on the erythrocytes of the fish species. Our results revealed that the inhibition of hepatic GST activity in H. reidi was dependent on increasing crude oil concentrations. In contrast, an increase in the damage index (DI) and MN frequency were observed with increased crude oil concentrations. These results indicate that the alkaline comet assay and micronucleus test were suitable and useful in the evaluation of the genotoxicity of crude oil, which could improve determinations of the impact of oil spills on fish populations. In addition, H. reidi is a promising "sentinel organism" to detect the genotoxic impact of petroleum hydrocarbons. Copyright © 2015 Elsevier Inc. All rights reserved.

  11. A Review of Oil Spill Remote Sensing.

    Science.gov (United States)

    Fingas, Merv; Brown, Carl E

    2017-12-30

    The technical aspects of oil spill remote sensing are examined and the practical uses and drawbacks of each technology are given with a focus on unfolding technology. The use of visible techniques is ubiquitous, but limited to certain observational conditions and simple applications. Infrared cameras offer some potential as oil spill sensors but have several limitations. Both techniques, although limited in capability, are widely used because of their increasing economy. The laser fluorosensor uniquely detects oil on substrates that include shoreline, water, soil, plants, ice, and snow. New commercial units have come out in the last few years. Radar detects calm areas on water and thus oil on water, because oil will reduce capillary waves on a water surface given moderate winds. Radar provides a unique option for wide area surveillance, all day or night and rainy/cloudy weather. Satellite-carried radars with their frequent overpass and high spatial resolution make these day-night and all-weather sensors essential for delineating both large spills and monitoring ship and platform oil discharges. Most strategic oil spill mapping is now being carried out using radar. Slick thickness measurements have been sought for many years. The operative technique at this time is the passive microwave. New techniques for calibration and verification have made these instruments more reliable.

  12. The dynamics of crude oil price differentials

    International Nuclear Information System (INIS)

    Fattouh, Bassam

    2010-01-01

    Crude oil price differentials are modelled as a two-regime threshold autoregressive (TAR) process using the method proposed by Caner and Hansen [Caner, M., Hansen, B.E. Threshold autoregression with a unit root. Econometrica 2001; 69; 1555-1596.]. While standard unit root tests suggest that the prices of crude oil of different varieties move closely together such that their price differential is stationary, the TAR results indicate strong evidence of threshold effects in the adjustment process to the long-run equilibrium. These findings suggest that crude oil prices are linked and thus at the very general level, the oil market is 'one great pool' (Adelman, M.A. International oil agreements. The Energy Journal 1984; 5; 1-9.). However, differences in the dynamics of adjustment suggest that within this one pool, oil markets are not necessarily integrated in every time period and hence the dynamics of crude oil price differentials may not follow a stationary process at all times. Although the development of a liquid futures market around the crude oil benchmarks has helped make some distant markets more unified, arbitrage is not costless or risk-free and temporary breakdowns in the benchmarks can lead to decoupling of crude oil prices. (author)

  13. A remote oil spill detection system for early warning of spills at waterfront or land-based facilities

    International Nuclear Information System (INIS)

    Parsons, M.J.; Stocky, W.D.; Westerlind, J.; Gram, H.R.; Jadamec, M.P.; Johnson, J.R.

    1992-01-01

    Early detection of spills during loading/unloading of crude oil or products at terminals or plants is essential for quickly stopping the spill and minimizing its impact. Such detection is particularly difficult at night or in remote areas. In order to provide a reliable and inexpensive spill detection system for such an application, a joint development process was undertaken to redesign an oil spill detection buoy system which had been successfully tested in the 1970s. The sensor's operation is based on the stimulated fluorescence of oil and selective wavelength detection of this fluorescence. The prototype system consists of a flotation buoy for remote deployment of the sensor, rechargeable battery supply, a land-based computer base station, and radio signal transmitter. The oil spill detection buoy was modified in 1991 and tested in the laboratory. Field trials are under way and tests to date have confirmed the unit's ability to detect oil and to differentiate between various types of oil and/or products, particularly if the software is alerted to the type of product being transferred. 2 figs

  14. A novel apparatus for long term weathering of crude oils

    International Nuclear Information System (INIS)

    Berger, D.; Lun, R.; Skogen, E.; Ooijen, H. Van; Mackay, D.

    1993-01-01

    A novel apparatus is under development for exposing oil in the laboratory to prolonged weathering. The apparatus is mechanically simple and robust and involves contacting oil with water and air, and possibly with solar radiation, under controlled conditions of salinity and turbulence. The principle of operation is that the oil rests on the concave surface of water, which is held in a cylindrical glass vessel and rotated at 33 rpm. The oil is agitated by a fixed stirrer which has a variable pitch. Three oils were studied: Canadian Environmenal Protection Service standard, Kuwait crude, and Prudhoe Bay crude. Gas chromatographic analysis of the oil revealed the expected changes in composition due to evaporation, and purge and trap analysis of the water in contact with the oil determined the nature and concentration of the dissolved hydrocarbons. The apparatus also proved successful for testing the formation of water-in-oil emulsions. It is hoped that the system will contribute to an improved understanding of the mechanisms involved in the long term weathering processes which occur when oil is spilled at sea. 11 refs., 10 figs., 1 tab

  15. Influence of UVB radiation on the lethal and sublethal toxicity of dispersed crude oil to planktonic copepod nauplii.

    Science.gov (United States)

    Almeda, Rodrigo; Harvey, Tracy E; Connelly, Tara L; Baca, Sarah; Buskey, Edward J

    2016-06-01

    Toxic effects of petroleum to marine zooplankton have been generally investigated using dissolved petroleum hydrocarbons and in the absence of sunlight. In this study, we determined the influence of natural ultraviolet B (UVB) radiation on the lethal and sublethal toxicity of dispersed crude oil to naupliar stages of the planktonic copepods Acartia tonsa, Temora turbinata and Pseudodiaptomus pelagicus. Low concentrations of dispersed crude oil (1 μL L(-1)) caused a significant reduction in survival, growth and swimming activity of copepod nauplii after 48 h of exposure. UVB radiation increased toxicity of dispersed crude oil by 1.3-3.8 times, depending on the experiment and measured variables. Ingestion of crude oil droplets may increase photoenhanced toxicity of crude oil to copepod nauplii by enhancing photosensitization. Photoenhanced sublethal toxicity was significantly higher when T. turbinata nauplii were exposed to dispersant-treated oil than crude oil alone, suggesting that chemical dispersion of crude oil may promote photoenhanced toxicity to marine zooplankton. Our results demonstrate that acute exposure to concentrations of dispersed crude oil and dispersant (Corexit 9500) commonly found in the sea after oil spills are highly toxic to copepod nauplii and that natural levels of UVB radiation substantially increase the toxicity of crude oil to these planktonic organisms. Overall, this study emphasizes the importance of considering sunlight in petroleum toxicological studies and models to better estimate the impact of crude oil spills on marine zooplankton. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

  16. Guide to oil spill exercise planning

    International Nuclear Information System (INIS)

    1996-01-01

    The International Convention on Oil Pollution Preparedness, Response and Cooperation (OPRC Convention) foresees a future in which all at risk states have national oil spill preparedness and response plans. The Convention also encourages the idea that national plans be developed in cooperation with oil and shipping industries. The ultimate test of any contingency plan is measured by performance in a real emergency. It is vital, therefore, that any programme for developing a national contingency plan must include an ongoing programme to test the plan through realistic exercises. An exercise programme must progressively prepare the Oil Spill Energy Response Team to perform effectively in realistic representations of the risks that the contingency plan has been designed to meet. This report has been designed to guide all those in government or industry who are faced with the responsibility of developing and managing oil spill response exercises at all levels. It carries with it the authority that derives from peer review by many centres of oil spill response excellence around the world. It is well-illustrated with brief case histories of exercises that have been carried out by many IPIECA member companies. Each of those companies has indicated its preparedness to share more information by providing contact name and address details within this report. (author)

  17. Oil spills into freshwater environments-literature review of fate and effects

    International Nuclear Information System (INIS)

    Taylor, E.; Owens, E.; Craig, A.; Steen, A.; Fritz, D.

    1993-01-01

    A literature search (1984--1992) was performed to summarize the environmental and human health effects of inlands spills. Over 100 major spills that affected freshwater environments were reported through the Emergency Response Notification System (ERNS) in 1991--1992 alone. Spills from pipelines outnumber all other sources combined. The oil types involved are about equally distributed between non-persistent oils and crude. Small rivers, streams, and creeks are the habitats into which most freshwater spills occur. Cleanup of stranded oil, rather than protection or recovery of floating oil, is the norm in most situations because stranding on river and lake banks often occurs before response is possible. The prediction of spill movement commonly is simpler for freshwater spills because freshwater bodies are relatively small and commonly have strong uni-directional flow; however, fast flow in rivers and streams and turnover in cooling lakes serve to distribute oil throughout the water column. Impacts to the environment, through food web structures or groundwater, may persist for months following a spill but seldom persist for years, unlike marine coastal impacts. Chronic impacts of oil spills into freshwater are rarely documented and these impacts are difficult to separate from effects of other hydrocarbons in the environment

  18. The effectiveness testing of oil spill-treating agents

    International Nuclear Information System (INIS)

    Fingas, M.F.; Kyle, D.A.; Laroche, N.; Fieldhouse, B.; Sergy, G.; Stoodley, G.

    1995-01-01

    Laboratory effectiveness tests have been developed for four classes of oil spill treating agents: solidifiers, demulsifying agents, surface-washing agents and dispersants. Several treating agent products in these four categories have been tested for effectiveness. The aquatic toxicity of these agents is an important factor and has been measured for many products. These results are presented. Solidifiers or gelling agents solidify oil. Test results show that solidifiers require between 16% and 200% of agent by weight compared to the oil. De-emulsifying agents or emulsion breakers prevent the formation of or break water-in-oil emulsions. Surfactant-containing materials are of two types, surface-washing agents and dispersants. Testing has shown that effectiveness is orthogonal for these two types of treating agents. Tests of surface washing agents show that only a few agents have effectiveness of 25 to 55%, where this is defined as the percentage of oil removed from a test surface. Dispersant effectiveness results using the swirling flask test are reported. Heavy oils show effectiveness values of about 1%, medium crudes of about 10%, light crude oils of about 30% and very light oils of about 90%

  19. Interactions between zooplankton and crude oil: toxic effects and bioaccumulation of polycyclic aromatic hydrocarbons.

    Directory of Open Access Journals (Sweden)

    Rodrigo Almeda

    Full Text Available We conducted ship-, shore- and laboratory-based crude oil exposure experiments to investigate (1 the effects of crude oil (Louisiana light sweet oil on survival and bioaccumulation of polycyclic aromatic hydrocarbons (PAHs in mesozooplankton communities, (2 the lethal effects of dispersant (Corexit 9500A and dispersant-treated oil on mesozooplankton, (3 the influence of UVB radiation/sunlight exposure on the toxicity of dispersed crude oil to mesozooplankton, and (4 the role of marine protozoans on the sublethal effects of crude oil and in the bioaccumulation of PAHs in the copepod Acartia tonsa. Mortality of mesozooplankton increased with increasing oil concentration following a sigmoid model with a median lethal concentration of 32.4 µl L(-1 in 16 h. At the ratio of dispersant to oil commonly used in the treatment of oil spills (i.e. 1∶20, dispersant (0.25 µl L(-1 and dispersant-treated oil were 2.3 and 3.4 times more toxic, respectively, than crude oil alone (5 µl L(-1 to mesozooplankton. UVB radiation increased the lethal effects of dispersed crude oil in mesozooplankton communities by 35%. We observed selective bioaccumulation of five PAHs, fluoranthene, phenanthrene, pyrene, chrysene and benzo[b]fluoranthene in both mesozooplankton communities and in the copepod A. tonsa. The presence of the protozoan Oxyrrhis marina reduced sublethal effects of oil on A. tonsa and was related to lower accumulations of PAHs in tissues and fecal pellets, suggesting that protozoa may be important in mitigating the harmful effects of crude oil exposure in copepods and the transfer of PAHs to higher trophic levels. Overall, our results indicate that the negative impact of oil spills on mesozooplankton may be increased by the use of chemical dispersant and UV radiation, but attenuated by crude oil-microbial food webs interactions, and that both mesozooplankton and protozoans may play an important role in fate of PAHs in marine environments.

  20. Interactions between Zooplankton and Crude Oil: Toxic Effects and Bioaccumulation of Polycyclic Aromatic Hydrocarbons

    Science.gov (United States)

    Almeda, Rodrigo; Wambaugh, Zoe; Wang, Zucheng; Hyatt, Cammie; Liu, Zhanfei; Buskey, Edward J.

    2013-01-01

    We conducted ship-, shore- and laboratory-based crude oil exposure experiments to investigate (1) the effects of crude oil (Louisiana light sweet oil) on survival and bioaccumulation of polycyclic aromatic hydrocarbons (PAHs) in mesozooplankton communities, (2) the lethal effects of dispersant (Corexit 9500A) and dispersant-treated oil on mesozooplankton, (3) the influence of UVB radiation/sunlight exposure on the toxicity of dispersed crude oil to mesozooplankton, and (4) the role of marine protozoans on the sublethal effects of crude oil and in the bioaccumulation of PAHs in the copepod Acartia tonsa. Mortality of mesozooplankton increased with increasing oil concentration following a sigmoid model with a median lethal concentration of 32.4 µl L−1 in 16 h. At the ratio of dispersant to oil commonly used in the treatment of oil spills (i.e. 1∶20), dispersant (0.25 µl L−1) and dispersant- treated oil were 2.3 and 3.4 times more toxic, respectively, than crude oil alone (5 µl L−1) to mesozooplankton. UVB radiation increased the lethal effects of dispersed crude oil in mesozooplankton communities by 35%. We observed selective bioaccumulation of five PAHs, fluoranthene, phenanthrene, pyrene, chrysene and benzo[b]fluoranthene in both mesozooplankton communities and in the copepod A. tonsa. The presence of the protozoan Oxyrrhis marina reduced sublethal effects of oil on A. tonsa and was related to lower accumulations of PAHs in tissues and fecal pellets, suggesting that protozoa may be important in mitigating the harmful effects of crude oil exposure in copepods and the transfer of PAHs to higher trophic levels. Overall, our results indicate that the negative impact of oil spills on mesozooplankton may be increased by the use of chemical dispersant and UV radiation, but attenuated by crude oil-microbial food webs interactions, and that both mesozooplankton and protozoans may play an important role in fate of PAHs in marine environments. PMID:23840628

  1. Petroleum biodegradation and oil spill bioremediation

    International Nuclear Information System (INIS)

    Atlas, R.M.

    1995-01-01

    Hydrocarbon-utilizing microorganisms are ubiquitously distributed in the marine environment following oil spills. These microorganisms naturally biodegrade numerous contaminating petroleum hydrocarbons, thereby cleansing the oceans of oil pullutants. Bioremediation, which is accomplished by adding exogenous microbial populations or stimulating indigenous ones, attempts to raise the rates of degradation found naturally to significantly higher rates. Seeding with oil degraders has not been demonstrated to be effective, but addition of nitrogenous fertilizers has been shown to increase rates of petroleum biodegradation. In the case of the Exxon Valdez spill, the largest and most thoroughly studied application of bioremediation, the application of fertilizer (slow release or oleophilic) increased rates of biodegradation 3-5 times. Because of the patchiness of oil, an internally conserved compound, hopane, was critical for demonstrating the efficacy of bioremediation. Multiple regression models showed that the effectiveness of bioremediation depended upon the amount of nitrogen delivered, the concentration of oil, and time. (author)

  2. Cotton for removal of aquatic oil spills

    International Nuclear Information System (INIS)

    Parker, H.W.; Fedler, C.B.; Heintz, C.E.; Nash, P.T.; Carr, D.L.; Lu, M.

    1992-01-01

    Raw cotton has considerable potential for selective removal of spilled oil and oil products from surface waters, since the natural waxes on the raw cotton make it preferentially oil wet. This potential was recognized in the early seventies at Texas Tech University. More recently other research workers have considered cotton as an adsorbent for spilled oil. The adsorbent market is now dominated by synthetic materials, such as air-blown polypropylene fiber, inorganic clays, and recycled paper and paper products. This paper further examines the potential of cotton in relation to these other adsorbents. Emphasis is placed on the potential for complete biodegradation of oil-soaked cotton adsorbents as a means avoiding the expense for incineration and/or the long-term environmental risk associated with placing the used adsorbents in landfills

  3. Microbial hydrocarbon degradation - bioremediation of oil spills

    Energy Technology Data Exchange (ETDEWEB)

    Atlas, R M [Louisville Univ., KY (United States). Dept. of Biology

    1991-01-01

    Bioremediation has become a major method employed in restoration of oil-polluted environments that makes use of natural microbial biodegradative activities. Bioremediation of petroleum pollutants overcomes the factors limiting rates of microbial hydrocarbon biodegradation. Often this involves using the enzymatic capabilities of the indigenous hydrocarbon-degrading microbial populations and modifying environmental factors, particularly concentrations of molecular oxygen, fixed forms of nitrogen and phosphate to achieve enhanced rates of hydrocarbon biodegradation. Biodegradation of oily sludges and bioremediation of oil-contaminated sites has been achieved by oxygen addition-e.g. by tilling soils in landfarming and by adding hydrogen peroxide or pumping oxygen into oiled aquifers along with addition of nitrogen- and phosphorous-containing fertilizers. The success of seeding oil spills with microbial preparations is ambiguous. Successful bioremediation of a major marine oil spill has been achieved based upon addition of nitrogen and phosphorus fertilizers. (author).

  4. Combating oil spill problem using plastic waste

    Energy Technology Data Exchange (ETDEWEB)

    Saleem, Junaid, E-mail: junaidupm@gmail.com [Department of Chemical Engineering, University of Karachi (Pakistan); Ning, Chao; Barford, John [Department of Chemical and Biomolecular Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong); McKay, Gordon [Department of Chemical and Biomolecular Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong); Division of Sustainable Development, College of Science, Engineering and Technology, Hamad Bin Khalifa University, Qatar Foundation, Doha (Qatar)

    2015-10-15

    Highlights: • Up-cycling one type of pollution i.e. plastic waste and successfully using it to combat the other type of pollution i.e. oil spill. • Synthesized oil sorbent that has extremely high oil uptake of 90 g/g after prolonged dripping of 1 h. • Synthesized porous oil sorbent film which not only facilitates in oil sorption but also increases the affinity between sorbent and oil by means of adhesion. - Abstract: Thermoplastic polymers (such as polypropylene, polyethylene, polyethylene terephthalate (PET) and high density polyethylene (HDPE)) constitute 5–15% of municipal solid waste produced across the world. A huge quantity of plastic waste is disposed of each year and is mostly either discarded in landfills or incinerated. On the other hand, the usage of synthetic polymers as oil sorbents, in particular, polyolefins, including polypropylene (PP), and polyethylene (PE) are the most commonly used oil sorbent materials mainly due to their low cost. However, they possess relatively low oil absorption capacities. In this work, we provide an innovative way to produce a value-added product such as oil-sorbent film with high practical oil uptake values in terms of g/g from waste HDPE bottles for rapid oil spill remedy.

  5. Combating oil spill problem using plastic waste

    International Nuclear Information System (INIS)

    Saleem, Junaid; Ning, Chao; Barford, John; McKay, Gordon

    2015-01-01

    Highlights: • Up-cycling one type of pollution i.e. plastic waste and successfully using it to combat the other type of pollution i.e. oil spill. • Synthesized oil sorbent that has extremely high oil uptake of 90 g/g after prolonged dripping of 1 h. • Synthesized porous oil sorbent film which not only facilitates in oil sorption but also increases the affinity between sorbent and oil by means of adhesion. - Abstract: Thermoplastic polymers (such as polypropylene, polyethylene, polyethylene terephthalate (PET) and high density polyethylene (HDPE)) constitute 5–15% of municipal solid waste produced across the world. A huge quantity of plastic waste is disposed of each year and is mostly either discarded in landfills or incinerated. On the other hand, the usage of synthetic polymers as oil sorbents, in particular, polyolefins, including polypropylene (PP), and polyethylene (PE) are the most commonly used oil sorbent materials mainly due to their low cost. However, they possess relatively low oil absorption capacities. In this work, we provide an innovative way to produce a value-added product such as oil-sorbent film with high practical oil uptake values in terms of g/g from waste HDPE bottles for rapid oil spill remedy

  6. Potential impacts of the Deepwater Horizon oil spill on large pelagic fishes

    Science.gov (United States)

    Frias-Torres, Sarrah; Bostater, Charles R., Jr.

    2011-11-01

    Biogeographical analyses provide insights on how the Deepwater Horizon oil spill impacted large pelagic fishes. We georeferenced historical ichthyoplankton surveys and published literature to map the spawning and larval areas of bluefin tuna, swordfish, blue marlin and whale shark sightings in the Gulf of Mexico with daily satellite-derived images detecting surface oil. The oil spill covered critical areas used by large pelagic fishes. Surface oil was detected in 100% of the northernmost whale shark sightings, in 32.8 % of the bluefin tuna spawning area and 38 % of the blue marlin larval area. No surface oil was detected in the swordfish spawning and larval area. Our study likely underestimates the extend of the oil spill due to satellite sensors detecting only the upper euphotic zone and the use of dispersants altering crude oil density, but provides a previously unknown spatio-temporal analysis.

  7. Oil spill modeling input to the offshore environmental cost model (OECM) for US-BOEMRE's spill risk and costs evaluations

    International Nuclear Information System (INIS)

    French McCay, Deborah; Reich, Danielle; Rowe, Jill; Schroeder, Melanie; Graham, Eileen

    2011-01-01

    This paper simulates the consequences of oil spills using a planning model known as the Offshore Environmental Cost Model (OECM). This study aims at creating various predictive models for possible oil spill scenarios in marine waters. A crucial part of this investigation was the SIMAP model. It analyzes the distance and the direction covered by the spill under certain test conditions, generating a regression equation that simulates the impact of the spill. Tests were run in two different regions; the Mid-Atlantic region and the Chukchi Sea. Results showed that the higher wind speeds and higher water temperature of the Mid-Atlantic region had greater impact on wildlife and the water column respectively. However, short-line impact was higher in the Chukchi area due to the multi-directional wind. It was also shown that, because of their higher diffusivity in water, lighter crude oils had more impact than heavier oils. It was suggested that this model could ultimately be applied to other oil spill scenarios happening under similar conditions.

  8. Biodegradation of marine oil spill residues using aboriginal bacterial consortium based on Penglai 19-3 oil spill accident, China.

    Science.gov (United States)

    Wang, Chuanyuan; Liu, Xing; Guo, Jie; Lv, Yingchun; Li, Yuanwei

    2018-09-15

    Bioremediation, mainly by indigenous bacteria, has been regarded as an effective way to deal with the petroleum pollution after an oil spill accident. The biodegradation of crude oil by microorganisms co-incubated from sediments collected from the Penglai 19-3 oil platform, Bohai Sea, China, was examined. The relative susceptibility of the isomers of alkylnaphthalenes, alkylphenanthrenes and alkyldibenzothiophene to biodegradation was also discussed. The results showed that the relative degradation values of total petroleum hydrocarbon (TPH) are 43.56% and 51.29% for sediments with untreated microcosms (S-BR1) and surfactant-treated microcosms (S-BR2), respectively. TPH biodegradation results showed an obvious decrease in saturates (biodegradation rate: 67.85-77.29%) and a slight decrease in aromatics (biodegradation rate: 47.13-57.21%), while no significant difference of resins and asphaltenes was detected. The biodegradation efficiency of alkylnaphthalenes, alkylphenanthrenes and alkyldibenzothiophene for S-BR1 and S-BR2 samples reaches 1.28-84.43% and 42.56-86.67%, respectively. The efficiency of crude oil degradation in sediment with surfactant-treated microcosms cultures added Tween 20, was higher than that in sediment with untreated microcosms. The biodegradation and selective depletion is not only controlled by thermodynamics but also related to the stereochemical structure of individual isomer compounds. Information on the biodegradation of oil spill residues by the bacterial community revealed in this study will be useful in developing strategies for bioremediation of crude oil dispersed in the marine ecosystem. Copyright © 2018 Elsevier Inc. All rights reserved.

  9. Oil spill R ampersand D efforts in Sweden

    International Nuclear Information System (INIS)

    Thorell, D.; Jansson, B.

    1992-01-01

    Let me at first mention some significant facts of the Baltic Sea and of Sweden. It has an average depth of only 60 to 70 meters.The waters are low in temperature as well as low in oxygen and salt content (salinity). The air-temperature is in the winter often lower than minus 20 degrees C. The entrance to the Baltic is very narrow and shallow, which means that it takes thirty years before the water in the Baltic is completely renewed. This makes the Baltic Sea to the world's largest brackish water area where the organisms are very vulnerable and sensitive to all kinds of pollution. Oil spills pose a special threat. Every year, approximately 45 million tons of oil of all types crude, bunker, diesel - to name some - are transported through Swedish waters. The shipping of oil in other parts of the Baltic Sea exceeds this figure; a shipping not subject to our legislation but from time to time, with its spills polluting our environment. Sweden has an extremely long coastline to protect: 14,000 kilometers (nearly 9,000 miles) along the mainland plus the shores of more than 100,000 islands. Some oil spills have contaminated more than 12,000 islands which have large bird and seal populations and are public recreation areas for 1 million people and pleasure boats. Sweden started a comprehensive oil spill R ampersand D programme in 1982. This programme, introduced in this document, is now ended and strategies for the twenty-first century are now being drawn up

  10. REVIEW OF PVT CORRELATIONS FOR CRUDE OILS

    African Journals Online (AJOL)

    win

    approaches that of the fluids used. During the last 50 years, ... applied to crude oils from other regions (Sutton and Farshad,. 1990). ... S. S. Ikiensikimama, Department of Chemistry Engineering, University of Lagos, Lagos, Nigeria. O. Ogboja ...

  11. Combustion: an oil spill mitigation tool

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-11-01

    The technical feasibility of using combustion as an oil spill mitigation tool was studied. Part I of the two-part report is a practical guide oriented toward the needs of potential users, while Part II is the research or resource document from which the practical guidance was drawn. The study included theoretical evaluations of combustion of petroleum pool fires under the effects of weathering and an oil classification system related to combustion potential. The theoretical analysis of combustion is balanced by practical experience of oil burning and case history information. Decision elements are provided which can be used as a guide for technical evaluations of a particular oil spill situation. The rationale for assessing technical feasibility is given in the context of other alternatives available for response to an oil spill. A series of research and technology development concepts are included for future research. The ethics of using oil burning are discussed as issues, concerns, and tradeoffs. A detailed annotated bibliography is appended along with a capsule review of a decade of oil burning studies and other support information.

  12. Modeling of response, socioeconomic, and natural resource damage costs for hypothetical oil spill scenarios in San Francisco Bay

    International Nuclear Information System (INIS)

    Etkin, D.S.; French McCay, D.; Whittier, N.; Sankaranarayanan, S.; Jennings, J.

    2002-01-01

    A study was conducted to determine the influence of oil type, spill size, response strategy and location factors on oil spill response costs, with particular reference to the cost benefits of the use of dispersants. Modeling has been conducted for a hypothetical oil spill in San Francisco Bay to determine biological impacts, damages to natural resources and response costs. The SIMAP modeling software by the Applied Science Associates was used to model 3 spill sizes (20, 50 and 95 percentile by volume) and 4 types of oil (gasoline, diesel, heavy fuel oil, and crude oil). Response costs, natural resource damages and socioeconomic impact were determined based on spill trajectory and fate. Mechanical recovery-based operations carry higher response costs than dispersant-based operations. Response costs for diesel and gasoline spills make up 20 per cent of the total costs, compared to 43 per cent for crude and heavy fuel oil spills. Damages to natural resources are higher for spills of toxic lighter fuels such as gasoline and diesel because gasoline has a greater impact on the water column with less shoreline oiling, resulting in more damages to natural resources. Heavier oils have a greater impact on shorelines and higher response and socioeconomic costs. Although socioeconomic costs varied by location, they tend to be greater than response costs and natural resource damage costs. Proportions of the different costs were described with reference to various spill factors. Socioeconomic costs are 61, 76, 45 and 53 per cent respectively for gasoline, diesel, crude oil, and heavy fuel oil spills. 27 refs., 23 tabs., 5 figs

  13. Deepwater Horizon Oil Spill PSA (:24)

    Centers for Disease Control (CDC) Podcasts

    This 24 second PSA from Dr. Regina Benjamin, U.S. Surgeon General, encourages people to get help if they are feeling sad, angry, depressed, or stressed as a result of the Gulf oil spill. It was recorded so that localities can add their own "For more information" at the end, as appropriate.

  14. Cyber Physical Intelligence for Oil Spills (CPI)

    Science.gov (United States)

    Lary, D. J.

    2015-12-01

    The National Academy of Sciences estimate 1.7 to 8.8 million tons of oil are released into global waters every year. The effects of these spills include dead wildlife, oil covered marshlands and contaminated water. Deepwater horizon cost approximately $50 billion and severely challenged response capabilities. In such large spills optimizing a coordinated response is a particular challenge. This challenge can be met in a revolutionary new way by using an objectively optimized Cyber Physical Decision Making System (CPS) for rapid response products and a framework for objectively optimized decision-making in an uncertain environment. The CPS utilizes machine learning for the processing of the massive real-time streams of Big Data from comprehensive hyperspectral remote sensing acquired by a team of low-cost robotic aerial vehicles, providing a real-time aerial view and stream of hyperspectral imagery from the near UV to the thermal infrared, and a characterization of oil thickness, oil type and oil weathering. The objective decision making paradigm is modeled on the human brain and provides the optimal course trajectory for response vessels to achieve the most expeditious cleanup of oil spills using the available resources. In addition, oil spill cleanups often involve surface oil burns that can lead to air quality issues. The aerial vehicles comprehensively characterize air quality in real-time, streaming location, temperature, pressure, humidity, the abundance of 6 criterion pollutants (O3, CO, NO, NO2, SO2, and H2S) and the full size distribution of airborne particulates. This CPS can be readily applied to other systems in agriculture, water conversation, monitoring of stream quality, air quality, diagnosing risk of wild fires, etc..

  15. Oil pipeline valve automation for spill reduction

    Energy Technology Data Exchange (ETDEWEB)

    Mohitpour, Mo; Trefanenko, Bill [Enbridge Technology Inc, Calgary (Canada); Tolmasquim, Sueli Tiomno; Kossatz, Helmut [TRANSPETRO - PETROBRAS Transporte S.A., Rio de Janeiro, RJ (Brazil)

    2003-07-01

    Liquid pipeline codes generally stipulate placement of block valves along liquid transmission pipelines such as on each side of major river crossings where environmental hazards could cause or are foreseen to potentially cause serious consequences. Codes, however, do not stipulate any requirement for block valve spacing for low vapour pressure petroleum transportation, nor for remote pipeline valve operations to reduce spills. A review of pipeline codes for valve requirement and spill limitation in high consequence areas is thus presented along with a criteria for an acceptable spill volume that could be caused by pipeline leak/full rupture. A technique for deciding economically and technically effective pipeline block valve automation for remote operation to reduce oil spilled and control of hazards is also provided. In this review, industry practice is highlighted and application of the criteria for maximum permissible oil spill and the technique for deciding valve automation thus developed, as applied to ORSUB pipeline is presented. ORSUB is one of the three initially selected pipelines that have been studied. These pipelines represent about 14% of the total length of petroleum transmission lines operated by PETROBRAS Transporte S.A. (TRANSPETRO) in Brazil. Based on the implementation of valve motorization on these three pipeline, motorization of block valves for remote operation on the remaining pipelines is intended, depending on the success of these implementations, on historical records of failure and appropriate ranking. (author)

  16. Impact of oil spill from ship on air quality around coastal regions of Korea

    Science.gov (United States)

    Shon, Zang-Ho; Song, Sang-Keun

    2010-05-01

    Regional air quality around coastal regions, where regular maritime traffic emissions from cargo, other commercial, fishing and military vessels are significantly active, can be affected by their direct emission of primary air pollutants (NOx, SO2, particulate matter (PM), etc.). For instance, harbor traffic exerted an important impact on NO2, SO2, O3, and PM levels. In addition, regional air quality around coastal regions is also affected by oil spill caused by ship accident in the coast. On 7 Dec., 2007, a barge carrying a crane hit the oil tanker MT Hebei Sprit off the west coast of the Republic of Korea, Yellow Sea (approximately 10 km off the coast), at 0700 local time, causing the spill of total estimated 12,547 tons of Iranian heavy (IH) and Kuwait Export (KE) crude oils. Since then, oil began coming on shore late in the night on 7 Dec. More than 150 km of coastline had been identified as being impacted by 17 Dec. Much of the affected area is part of the Taean-gun National Park and the nearest coastal city to spilled area is Taean. On 8 Dec., the flow of oil from the tanker was stopped when the holes were patched. The accident is the worst oil spill in Korea and the spill area is about one-third of the size of the Exxon Valdez oil spill. The short- and long-term effects of oil spill on marine environment have been numerously studied, not on atmospheric environment. In this study, the air quality impact near spilled area by the evaporation of hydrocarbons from the oil spill is studied in detail. The evaporation rates of the volatile fractions of the crude oils released by oil spill were estimated based on their mole fractions of crude oils and mass transfer coefficients. Based on a molecular diffusion process, the flux of spilled oil component (Fivap, mol m-2 s-1) can be expressed as follows: Fivap = Kivap(Civap - C∞vap) (1) where Civap is concentration (mol m-3) of a component i of crude oil vapor in the air at the oil-air interface; C∞vap is the

  17. Rate of biodegradation of crude oil by microorganisms isolated from ...

    African Journals Online (AJOL)

    The rate of biodegradation of crude oil by micro-organisms isolated from crude oil sludge environment in Eket, Akwa Ibom State of Nigeria was studied. Mineral salt medium supplemented with crude oil was used and three most abundant species isolated from a crude oil sludged soil - Micrococcus varians, Bacillus subtilis ...

  18. Transporting US oil imports: The impact of oil spill legislation on the tanker market

    International Nuclear Information System (INIS)

    Rowland, P.J.

    1992-05-01

    The Oil Pollution Act of 1990 (''OPA'') and an even more problematic array of State pollution laws have raised the cost, and risk, of carrying oil into and out of the US. This report, prepared under contract to the US Department of energy's Office of Domestic and International Policy, examines the impact of Federal and State oil spill legislation on the tanker market. It reviews the role of marine transportation in US oil supply, explores the OPA and State oil spill laws, studies reactions to OPA in the tanker and tank barge industries and in related industries such as insurance and ship finance, and finally, discusses the likely developments in the years ahead. US waterborne oil imports amounted to 6.5 million B/D in 1991, three-quarters of which was crude oil. Imports will rise by almost 3 million B/D by 2000 according to US Department of energy forecasts, with most of the crude oil growth after 1995. Tanker demand will grow even faster: most of the US imports and the increased traffic to other world consuming regions will be on long-haul trades. Both the number of US port calls by tankers and the volume of offshore lightering will grow. Every aspect of the tanker industry's behavior is affected by OPA and a variety of State pollution laws

  19. Transporting US oil imports: The impact of oil spill legislation on the tanker market

    Energy Technology Data Exchange (ETDEWEB)

    Rowland, P.J. (Rowland (P.) Associates (United States))

    1992-05-01

    The Oil Pollution Act of 1990 ( OPA'') and an even more problematic array of State pollution laws have raised the cost, and risk, of carrying oil into and out of the US. This report, prepared under contract to the US Department of energy's Office of Domestic and International Policy, examines the impact of Federal and State oil spill legislation on the tanker market. It reviews the role of marine transportation in US oil supply, explores the OPA and State oil spill laws, studies reactions to OPA in the tanker and tank barge industries and in related industries such as insurance and ship finance, and finally, discusses the likely developments in the years ahead. US waterborne oil imports amounted to 6.5 million B/D in 1991, three-quarters of which was crude oil. Imports will rise by almost 3 million B/D by 2000 according to US Department of energy forecasts, with most of the crude oil growth after 1995. Tanker demand will grow even faster: most of the US imports and the increased traffic to other world consuming regions will be on long-haul trades. Both the number of US port calls by tankers and the volume of offshore lightering will grow. Every aspect of the tanker industry's behavior is affected by OPA and a variety of State pollution laws.

  20. Cost-effectiveness criteria for marine oil spill preventive measures

    International Nuclear Information System (INIS)

    Vanem, Erik; Endresen, Oyvind; Skjong, Rolf

    2008-01-01

    Oil tanker accidents resulting in large quantities of oil spills and severe pollution have occurred in the past, leading to major public attention and an international focus on finding solutions for minimising the risks related to such events. This paper proposes a novel approach for evaluating measures for prevention and control of marine oil spills, based on considerations of oil spill risk and cost effectiveness. A cost model that incorporates all costs of a shipping accident has been established and oil tanker spill accidents have been further elaborated as a special case of such accidents. Utilising this model, novel implementation criteria, in terms of the Cost of Averting a Tonne of oil Spilt (CATS), for risk control options aiming at mitigating the environmental risk of accidental oil spills, are proposed. The paper presents a review of previous studies on the costs associated with oil spills from shipping, which is a function of many factors such as location of spill, spill amount, type of oil, etc. However, ships are designed for global trade, transporting different oil qualities. Therefore, globally applicable criteria must average over most of these factors, and the spill amount is the remaining factor that will be used to measure cost effectiveness against. A weighted, global average cleanup cost of USD 16,000/tonne of oil spilt has been calculated, considering the distribution of oil tanker traffic densities. Finally, the criteria are compared with some existing regulations for oil spill prevention, response and compensation (OPA 90)

  1. [Identification of spill oil species based on low concentration synchronous fluorescence spectra and RBF neural network].

    Science.gov (United States)

    Liu, Qian-qian; Wang, Chun-yan; Shi, Xiao-feng; Li, Wen-dong; Luan, Xiao-ning; Hou, Shi-lin; Zhang, Jin-liang; Zheng, Rong-er

    2012-04-01

    In this paper, a new method was developed to differentiate the spill oil samples. The synchronous fluorescence spectra in the lower nonlinear concentration range of 10(-2) - 10(-1) g x L(-1) were collected to get training data base. Radial basis function artificial neural network (RBF-ANN) was used to identify the samples sets, along with principal component analysis (PCA) as the feature extraction method. The recognition rate of the closely-related oil source samples is 92%. All the results demonstrated that the proposed method could identify the crude oil samples effectively by just one synchronous spectrum of the spill oil sample. The method was supposed to be very suitable to the real-time spill oil identification, and can also be easily applied to the oil logging and the analysis of other multi-PAHs or multi-fluorescent mixtures.

  2. Assessment of raw luffa as a natural hollow oleophilic fibrous sorbent for oil spill cleanup

    Directory of Open Access Journals (Sweden)

    Ola Abdelwahab

    2014-03-01

    Full Text Available Oil spills have a global concern due to its environmental and economical impact. Various commercial systems have been developed to control these spills, including the use of fibers as sorbents. However, plant biomass is renewable resource that can be converted into useful materials and energy. Luffa, an agricultural waste, was used as a sorbent material. The present study examines the adsorption capacity of raw luffa fibers for different types of oil and water pickup. The investigation revealed that the efficiency of fibers to remove crude oil from sea water was related to the surface properties of the fibers, concentration of the oil, amount of the fibers, as well as the temperature of the crude oil. The results show high sorption efficiency of luffa fibers for different kinds of oil. This sorbent also exhibited a good reusability since the decrease in sorption efficiency did not exceed 50% of the initial value after three sorption cycles.

  3. When Will Occur the Crude Oil Bubbles?

    International Nuclear Information System (INIS)

    Su, Chi-Wei; Li, Zheng-Zheng; Chang, Hsu-Ling; Lobonţ, Oana-Ramona

    2017-01-01

    In this paper, we apply a recursive unit root test to investigate whether there exist multiple bubbles in crude oil price. The method is best suited for a practical implementation of a time series and delivers a consistent date-stamping strategy for the origination and termination of multiple bubbles. The empirical result indicates that there exist six bubbles during 1986–2016 when the oil price deviate from its intrinsic value based on market fundamentals. Specifically, oil price contains the fundamentals and bubble components. The dates of the bubbles correspond to specific events in the politics and financial markets. The authorities should actively fight speculative bubbles or just observe their evolutions and speculation activities may decrease, which is favour of the stabilisation of the staple commodities including crude oil price. These findings have important economic and policy implications to recognise the cause of bubbles and take corresponding measures to reduce the impact on the real economy cause of the fluctuation of crude oil price. - Highlights: • Investigate multiple bubbles in crude oil price. • Indicate six bubbles deviate from its intrinsic value based on market fundamentals. • The bubbles correspond to specific events in the politics and financial markets. • Reduce the impact on the real economy cause of the fluctuation of crude oil price.

  4. Novel insight into the role of heterotrophic dinoflagellates in the fate of crude oil in the sea

    Science.gov (United States)

    Almeda, Rodrigo; Connelly, Tara L.; Buskey, Edward J.

    2014-12-01

    Although planktonic protozoans are likely to interact with dispersed crude oil after a spill, protozoan-mediated processes affecting crude oil pollution in the sea are still not well known. Here, we present the first evidence of ingestion and defecation of physically or chemically dispersed crude oil droplets (1-86 μm in diameter) by heterotrophic dinoflagellates, major components of marine planktonic food webs. At a crude oil concentration commonly found after an oil spill (1 μL L-1), the heterotrophic dinoflagellates Noctiluca scintillans and Gyrodinium spirale grew and ingested ~0.37 μg-oil μg-Cdino-1 d-1, which could represent ~17% to 100% of dispersed oil in surface waters when heterotrophic dinoflagellates are abundant or bloom. Egestion of faecal pellets containing crude oil by heterotrophic dinoflagellates could contribute to the sinking and flux of toxic petroleum hydrocarbons in coastal waters. Our study indicates that crude oil ingestion by heterotrophic dinoflagellates is a noteworthy route by which petroleum enters marine food webs and a previously overlooked biological process influencing the fate of crude oil in the sea after spills.

  5. Decalcification of benthic foraminifera due to "Hebei Spirit" oil spill, Korea.

    Science.gov (United States)

    Lee, Yeon Gyu; Kim, Shin; Jeong, Da Un; Lee, Jung Sick; Woo, Han Jun; Park, Min Woo; Kim, Byeong Hak; Son, Maeng Hyun; Choi, Yang Ho

    2014-10-15

    In order to determine the effects on foraminifera due to spilled crude oil in the "Herbei Spirit" incident, a study of benthic foraminiferal assemblages was carried out on sediment samples collected from the Sogeunri tidal flat, Taean Peninsula, Korea. Breakages of the chambers in the Ammonia beccarii and Elphidium subincertum species of the Sogeunri tidal flat with a low pH (6.98 on average) were marked. These chamber breakages occurred in 71.6% of A. beccarii and are thought to be caused by decalcification due to the fall in pH resulting from the "Hebei Spirit" oil spill. The factors that affect breakage of the chamber in benthic foraminifera under low pH condition may be not only deto decalcification but also to exposure duration of substrata in the tidal flat spilled crude oil. Copyright © 2014 Elsevier Ltd. All rights reserved.

  6. Oil spill remote sensing sensors and aircraft

    International Nuclear Information System (INIS)

    Fingas, M.; Fruhwirth, M.; Gamble, L.

    1992-01-01

    The most common form of remote sensing as applied to oil spills is aerial remote sensing. The technology of aerial remote sensing, mainly from aircraft, is reviewed along with aircraft-mounted remote sensors and aircraft modifications. The characteristics, advantages, and limitations of optical techniques, infrared and ultraviolet sensors, fluorosensors, microwave and radar sensors, and slick thickness sensors are discussed. Special attention is paid to remote sensing of oil under difficult circumstances, such as oil in water or oil on ice. An infrared camera is the first sensor recommended for oil spill work, as it is the cheapest and most applicable device, and is the only type of equipment that can be bought off-the-shelf. The second sensor recommended is an ultraviolet and visible-spectrum device. The laser fluorosensor offers the only potential for discriminating between oiled and un-oiled weeds or shoreline, and for positively identifying oil pollution on ice and in a variety of other situations. However, such an instrument is large and expensive. Radar, although low in priority for purchase, offers the only potential for large-area searches and foul-weather remote sensing. Most other sensors are experimental or do not offer good potential for oil detection or mapping. 48 refs., 8 tabs

  7. Review of oil spill remote sensing.

    Science.gov (United States)

    Fingas, Merv; Brown, Carl

    2014-06-15

    Remote-sensing for oil spills is reviewed. The use of visible techniques is ubiquitous, however it gives only the same results as visual monitoring. Oil has no particular spectral features that would allow for identification among the many possible background interferences. Cameras are only useful to provide documentation. In daytime oil absorbs light and remits this as thermal energy at temperatures 3-8K above ambient, this is detectable by infrared (IR) cameras. Laser fluorosensors are useful instruments because of their unique capability to identify oil on backgrounds that include water, soil, weeds, ice and snow. They are the only sensor that can positively discriminate oil on most backgrounds. Radar detects oil on water by the fact that oil will dampen water-surface capillary waves under low to moderate wave/wind conditions. Radar offers the only potential for large area searches, day/night and foul weather remote sensing. Copyright © 2014 Elsevier Ltd. All rights reserved.

  8. European Atlantic: the hottest oil spill hotspot worldwide

    NARCIS (Netherlands)

    Rodriguez Vieites, D.; Nieto-Roman, S.; Palanca, A.; Ferrer, X.; Vences, M.

    2004-01-01

    Oil spills caused by maritime transport of petroleum products are still an important source of ocean pollution, especially in main production areas and along major transport routes. We here provide a historical and geographic analysis of the major oil spills (>700 tonnes) since 1960. Spills were

  9. Microcosm evaluation of autochthonous bioaugmentation to combat marine oil spills.

    Science.gov (United States)

    Nikolopoulou, Maria; Eickenbusch, P; Pasadakis, Nikos; Venieri, Danae; Kalogerakis, Nicolas

    2013-09-25

    Oil spills can be disastrous to any ecosystem. Bioremediation through bioaugmentation (addition of oil-degrading bacteria) and biostimulation (addition of nutrients N&P) options can be a promising strategy for combating oil spills following first response actions. However, bioaugmentation is one of the most controversial issues of bioremediation since nutrient addition alone has a greater effect on oil biodegradation than the addition of microbial products that are highly dependent on environmental conditions. There is increasing evidence that the best way to overcome the above barriers is to use microorganisms from the polluted area, an approach proposed as autochthonous bioaugmentation (ABA) and defined as the bioaugmentation technology that uses exclusively microorganisms indigenous to the sites (soil, sand, and water) to be decontaminated. In this study, we examined the effectiveness of an ABA strategy for the successful remediation of polluted marine environments. A consortium was enriched from seawater samples taken from Elefsina Gulf near the Hellenic Petroleum Refinery, a site exposed to chronic crude oil pollution. Pre-adapted consortium was tested alone or in combination with inorganic nutrients in the presence (or not) of biosurfactants (rhamnolipids) in 30-day experiments. Treatment with fertilizers in the presence of biosurfactants exhibited the highest alkane and PAH degradation and showed highest growth over a period of almost 15 days. Considering the above, the use of biostimulation additives in combination with naturally pre-adapted hydrocarbon degrading consortia has proved to be a very effective treatment and it is a promising strategy in the future especially when combined with lipophilic fertilizers instead of inorganic nutrients. Such an approach becomes more pertinent when the oil spill approaches near the shoreline and immediate hydrocarbon degradation is needed. Copyright © 2013 Elsevier B.V. All rights reserved.

  10. The North Cape oil spill assessment: PAHs in oil

    International Nuclear Information System (INIS)

    Brown, J.; Boehm, P. D.; Hardestine, J. H.; Douglas, G. S.

    1997-01-01

    The North Cape oil spill in January 1996 resulted in the release of an estimated 827,000 gallons of No. 2 home heating oil into the nearshore turbulent waters of coastal Rhode Island. The oil was mixed into the water column and was transported on the surface as well as below the surface. Some of the spilled oil entered the coastal ponds behind the beaches. Sampling and chemical analysis for detailed suites of petroleum saturated and polycyclic aromatic hydrocarbons (PAHs) was undertaken as part of the assessment of the fate of the oil spill and of the exposure to the marine environment. The ponds were found to contain significant quantities of background petroleum hydrocarbons, including petrogenic PAHs and combustion PAHs. Initial assessment pointed (incorrectly as it turned out) to widespread contamination due only to the North Cape spill. Application of advanced chemical fingerprinting approaches, and geochemical biomarker data illustrated that many of the PAHs consisted of combustion-related 4- and 5-ringed PAHs, attributable to diesel fuel used routinely by boats in the area. The analysis demonstrated that the use of non-specific total PAH data and insufficient fingerprinting and allocation of petrogenic residues has the potential to overestimate contamination and hence injury to the environment in similar oil spill situations

  11. Histopathologic and biochemical responses in Arctic marine bivalve molluscs exposed to experimentally spilled oil

    Energy Technology Data Exchange (ETDEWEB)

    Neff, J.M.; Hillman, R.E.; Carr, R.S.; Buhl, R.L.; Lahey, J.I.

    1987-01-01

    Following two experimental spills of chemically dispersed and undispersed crude oil in shallow bays on the northwest coast of Baffin Island bivalve molluscs accumulated significant amounts of petroleum hydrocarbons in bay receiving dispersed oil and in those receiving crude oil alone. Specimens of Mya truncata and Macoma calcarea for histopathologic examination were collected immediately before, immediately after and one year after the experimental oil spills. Immediately after there was increased gill and digestive tract necrosis in Mya from the chemically dispersed oil. After one year a few clams had granulocytomas throughout the tissues. Three clams receiving oil alone collected one year after the spill had invasive neoplasias. There were few lesions in Macoma immediatelly after or one year after the spill; animals had a high incidence of vacuolization of the digestive tubule epithelium. The incidence of parasitism and hemocytic infiltration also was higher in Maccoma. Clams Mya truncata were collected for biochemical analysis before, after and two weeks after the simulated oil spills. Concentations in the clam tissues of glucose, glycogen, trehalose, total lipid, and free amino acids were measured; free amino acids in adductor muscles were the most useful indices of pollutant stress. The results of the biochemical analyses indicate that Mya were not severely stressed by either dispersed oil or oil alone. After two weeks, clams from the dispersed oil bays were nearly normal, while those from the bay receiving oil alone appeared stressed. These results seem to corroborate results that the acute effects of dispersed oil are greater than those of undispersed oil, but effects of undispersed oil on infaunal molluscs develop more slowly and persist longer than those from dispersed oil. 43 refs., 2 figs., 6 tabs.

  12. Pengaruh Penambahan Kosubstrat pada Biodegradasi Crude Oil

    Directory of Open Access Journals (Sweden)

    Any Juliani

    2016-06-01

    Full Text Available Kegiatan penambangan minyak bumi tidak hanya dilakukan oleh perusahaan-perusahaan besar, tetapi juga oleh masyarakat secara tradisional. Potensi pencemaran lingkungan yang ditimbulkan oleh kegiatan penambangan rakyat ini menjadi lebih tinggi karena pengelolaannya yang tradisional. Salah satu jenis pencemaran yang ditimbulkannya misalnya adalah tanah atau perairan yang tercemar oleh minyak bumi (crude oil pada saat berlangsungnya kegiatan penambangan. Salah satu upaya untuk dapat mengatasinya adalah dengan bioremediasi. Bioremediasi merupakan teknologi pengolahan pencemar dengan memanfaatkan aktivitas mikroba, terutama dari golongan bakteri. Bioremediasi tersebut harus melibatkan bakteri yang memiliki kapasitas metabolic untuk melakukan biodegradasi terhadap crude oil tersebut. Crude oil sendiri pada dasarnya merupakan senyawa hidrokarbon yang merupakan sumber karbon yang kaya bagi mikroba. Namun demikian, biodegradasi crude oil relative lebih sulit dilakukan karena karakteristiknya yang merupakan senyawa dengan berat molekul dan ukuran yang besar. Oleh karena itu penambahan kosubstrat yang lebih sederhana dapat dilakukan untuk membantu biodegradasi terutama pada tahap awal proses. Penelitian ini dilakukan untuk mengetahui pengaruh penambahan kosubstrat dalam hal ini glukosa terhadap biodegradasi crude oil. Penelitian dilakukan dalam media cair dengan bioaugmentasi melalui penambahan inoculum bakteri yang diisolasi dari tanah yang dikondisikan terhadap crude oil dalam beberapa variasi reactor. Indikasi terjadinya biodegradasi diperiksa melalui pengukuran terhadap parameter Total Petroleum Hydrocarbon (TPH dan Total Plate Count (TPC. Hasil penelitian menunjukkan bahwa penambahan kosubstrat glukosa memberikan pengaruh positif terhadap penurunan TPH. Penurunan TPH tertinggi setelah 28 hari adalah sebesar 25,3 % yang diberikan oleh reactor dengan penambahan kosubstrat serta konsentrasi crude oil awal sebesar 8.1 %. Sementara itu reactor tanpa

  13. Comparative toxicology of four crude oils

    Energy Technology Data Exchange (ETDEWEB)

    Clarke, L.M.; Hodson, P.V. [Queen' s Univ., Kingston, ON (Canada). Dept. of Biology; Brown, R.S. [Queen' s Univ., Kingston, ON (Canada). Dept. of Chemistry

    2003-07-01

    Fish that are chronically exposed to polycyclic aromatic hydrocarbons (PAHs) exhibit dioxin-like toxicity characterized by blue sac disease and the induction of cytochrome P4501A (CYP1A). This study compared the relative toxicity of four crude oils (Scotian Shelf, MESA, the synthetic Alberta Sweet Mixed Blend, and Alaskan North Slope Crude Oil), in causing the disease in rainbow trout embryos living in simulated spawning beds with hydrocarbon-contaminated gravel. Each oil had different chemical characteristics and PAH concentrations. The study confirmed the assumption that the Alberta Sweet Mixed Blend would be the most toxic due to its high PAH concentration. The results suggest that the main cause of toxicity in crude oil is due to the presence, concentration, and conformation of specific PAHs.

  14. Physical, chemical and biological observations and modeling of oil spills in the Mediterranean Sea

    Science.gov (United States)

    Ribotti, A.; De Dominicis, M.

    2016-11-01

    According to a definition of GESAMP, United Nations advisory body on scientific aspects of marine protection, a marine pollution is: "direct or indirect introduction by man of substances or energy into the marine environment … which results in such deleterious effects as harm to living resources, hazard to human health, hindrance to marine activities including fishing, impairment of water quality and reduction of marine attractions". The works presented in this Special Issue stem from the need to manage the problem of marine pollution. The categories of pollutants associated with the maritime traffic are mainly hydrocarbons and chemicals. Hydrocarbon is the oil in all its forms, including the crude oil, the fuel oil, the sludges, debris and other refined products (as defined by MARPOL 73/78 Annex I (MARPOL, 1978)). An oil spill is a release of a liquid petroleum hydrocarbon into the environment due to human activity, and is a form of pollution. The term often refers to marine oil spills, where oil is released into the open ocean or coastal waters. Oil spills include releases of crude oil from tankers, offshore platforms, drilling rigs and wells, as well as spills of refined petroleum products (such as gasoline, diesel) and their by-products, and heavier fuels used by large ships such as bunker fuel, or the spill of any oily refuse or waste oil. Oil spills can have devastating effects on the marine environment and can jeopardize the functional integrity of the marine ecosystem (seabirds populations, fish communities, and marine mammals), as reported in Jackson et al. (1989), Piatt and Anderson (1996), Peterson et al. (2003). While being toxic to marine life, the hydrocarbons are very difficult to clean up, and last for years in the sediment and marine environment. Discharge of cargo residues from bulk carries can pollute ports, waterways and oceans. In many instances vessels intentionally discharge illegal wastes despite foreign and domestic regulation prohibiting

  15. A program approach for site safety at oil spills

    International Nuclear Information System (INIS)

    Whipple, F.L.; Glenn, S.P.; Ocken, J.J.; Ott, G.L.

    1993-01-01

    When OSHA developed the hazardous waste operations (Hazwoper) regulations (29 CFR 1910.120) members of the response community envisioned a separation of oil and open-quotes hazmatclose quotes response operations. Organizations that deal with oil spills have had difficulty applying Hazwoper regulations to oil spill operations. This hinders meaningful implementation of the standard for their personnel. We should approach oil spills with the same degree of caution that is applied to hazmat response. Training frequently does not address the safety of oil spill response operations. Site-specific safety and health plans often are neglected or omitted. Certain oils expose workers to carcinogens, as well as chronic and acute hazards. Significant physical hazards are most important. In responding to oil spills, the hazards must be addressed. It is the authors' contention that a need exists for safety program at oil spill sites. Gone are the days of labor pool hires cleaning up spills in jeans and sneakers. The key to meaningful programs for oil spills requires application of controls focused on relevant safety risks rather than minimal chemical exposure hazards. Working with concerned reviewers from other agencies and organizations, the authors have developed a general safety and health program for oil spill response. It is intended to serve as the basis for organizations to customize their own written safety and health program (required by OSHA). It also provides a separate generic site safety plan for emergency phase oil spill operations (check-list) and long term post-emergency phase operations

  16. Assessment of the use of dispersants on oil spills in California marine waters

    International Nuclear Information System (INIS)

    Trudel, K.; Ross, S.; Belore, R.; Buffington, S.; Ogawa, C.; Panzer, D.

    2002-01-01

    The technical issues regarding the use of dispersants to clean up oil spills from offshore production sources and transportation sources in California were assessed in this study which examined both operational and environmental issues. The operational issues included the dispersibility of produced and imported oils, along with the capabilities of California response resources to deal with typical spills and limiting environmental impacts to offshore environments. The environmental issues include the risks associated with typical spills and potential net environmental benefit of chemically dispersing oil spills. Most crude oils produced offshore California are heavy and border on the undispersable range, but the imported crudes are somewhat lighter. Modeling has shown that most produced oils and some imported oils emulsify quickly and weather more quickly to the point where they are no longer dispersible. There is a very narrow window of time for chemical dispersions to be used effectively. The net environmental benefit analysis demonstrates that the use of dispersants lessens the total environmental impact of spill scenarios. It was emphasized that it is necessary to act quickly if chemical dispersion is to be effective. Rapid response strategies are needed, including locally based vessel and helicopter spraying systems. 19 refs., 8 tabs., 1 fig

  17. Crude oil spot market pricing: Pearsonian analysis of crude oil spot market prices

    International Nuclear Information System (INIS)

    Akinnusi, Ayo

    1994-01-01

    This paper presents a brief overview of crude oil pricing before describing a study of sets of 1991 spot market prices, and examining Pearson's model. Empirical distribution characteristics for 14 crude oils are tabulated, and skewness-kurtosis relationship and implication are considered. (UK)

  18. Computer simulation of the Shetland oil spill

    International Nuclear Information System (INIS)

    Elliott, A.; Proctor, R.

    1994-01-01

    Model predictions of the movement of oil released during the Shetland oil spill in January 1993 commenced immediately following the grounding of the Braer. The initial forecast, made with a 5 nautical mile grid model, predicted oil along the west coast of the island but were too coarse to resolve the coastal bathymetry and circulation. This forced the development of a fine grid (924m) hydrodynamic model of the region which was interfaced to surface wind forecasts and meshed to a shelf-wide storm surge model. (author)

  19. Bioremediation Potential of Native Hydrocarbons Degrading Bacteria in Crude Oil Polluted Soil

    Directory of Open Access Journals (Sweden)

    Mariana MARINESCU

    2017-05-01

    Full Text Available Bioremediation of crude oil contaminated soil is an effective process to clean petroleum pollutants from the environment. Crude oil bioremediation of soils is limited by the bacteria activity in degrading the spills hydrocarbons. Native crude oil degrading bacteria were isolated from different crude oil polluted soils. The isolated bacteria belong to the genera Pseudomonas, Mycobacterium, Arthrobacter and Bacillus. A natural biodegradable product and bacterial inoculum were used for total petroleum hydrocarbon (TPH removal from an artificial polluted soil. For soil polluted with 5% crude oil, the bacterial top, including those placed in the soil by inoculation was 30 days after impact, respectively 7 days after inoculum application, while in soil polluted with 10% crude oil,  multiplication top of bacteria was observed in the determination made at 45 days after impact and 21 days after inoculum application, showing once again how necessary is for microorganisms habituation and adaptation to environment being a function of pollutant concentration. The microorganisms inoculated showed a slight adaptability in soil polluted with 5% crude oil, but complete inhibition in the first 30 days of experiment at 10% crude oil.

  20. The Other Major 2010 Oil Spill: Oil weathering after the Kalamazoo River Dilbit Spill

    Science.gov (United States)

    Swarthout, B.; Reddy, C. M.; Nelson, R. K.; Hamilton, S. K.; Aeppli, C.; Valentine, D. L.; Fundaun, S. E.; Oliveira, A. H.

    2016-02-01

    Diluted bitumen (dilbit) from the oil sands (tar sands) of western Canada is increasingly being transported to US markets. North America's largest inland oil spill and the first major oil sands spill in a freshwater environment occurred in 2010, when at least 843,000 gallons leaked from a pipeline into the Kalamazoo River of southwest Michigan. Cleanup of this oil was unusually difficult and protracted, lasting through 2014 and costing over a billion dollars, largely because a substantial fraction of the oil became submersed and deposited in slack water areas over 60 km of river channel, reservoirs, and floodplain backwaters. To investigate the fate of the spilled dilbit from the 2010 Kalamazoo River release, black rings, presumably oil residues, on the bark of dead trees were collected in 2015. These residues were deposited on the trees during high flood levels that have not been observed since the spill and represent an opportunity to constrain weathering processes excluding dissolution. This material contained a major non-GC amenable fraction of 90-95%, presumably oxygenated hydrocarbons. The GC amenable portion was consistent with laboratory weathered dilbit. We used a variety of analytical tools to characterize the dilbit residues, as well as to identify dilbit weathering processes that occurred since the spill.

  1. Combating oil spill problem using plastic waste.

    Science.gov (United States)

    Saleem, Junaid; Ning, Chao; Barford, John; McKay, Gordon

    2015-10-01

    Thermoplastic polymers (such as polypropylene, polyethylene, polyethylene terephthalate (PET) and high density polyethylene (HDPE)) constitute 5-15% of municipal solid waste produced across the world. A huge quantity of plastic waste is disposed of each year and is mostly either discarded in landfills or incinerated. On the other hand, the usage of synthetic polymers as oil sorbents, in particular, polyolefins, including polypropylene (PP), and polyethylene (PE) are the most commonly used oil sorbent materials mainly due to their low cost. However, they possess relatively low oil absorption capacities. In this work, we provide an innovative way to produce a value-added product such as oil-sorbent film with high practical oil uptake values in terms of g/g from waste HDPE bottles for rapid oil spill remedy. Copyright © 2015 Elsevier Ltd. All rights reserved.

  2. Experimental investigation of various vegetable fibers as sorbent materials for oil spills

    Energy Technology Data Exchange (ETDEWEB)

    Annunciado, T.R.; Sydenstricker, T.H.D.; Amico, S.C. [Federal University of Parana, Curitiba, (Brazil). Department of Mechanical Engineering

    2005-11-15

    Oil spills are a global concern due to their environmental and economical impact. various commercial systems have been developed to control these spills, including the use of fibers as sorbents. This research investigates the use of various vegetable fibers, namely mixed leaves residues, mixed sawdust, sisal (Agave sisalana), coir fiber (Cocos nucifera), sponge-gourd (Luffa cylindrica) and silk-floss as sorbent materials of crude oil. Sorption tests with crude oil were conducted in deionized and marine water media, with and without agitation. Water uptake by the fibers was investigated by tests in dry conditions and distillation of the impregnated sorbent. The silk-floss fiber showed a very high degree of hydrophobicity and oil sorption capacity of approximately 85 g oil/g sorbent (in 24 hours). Specific gravity measurements and buoyancy tests were also used to evaluate the suitability of these fibers for the intended application. (author)

  3. Evaluating technologies of oil spill surveillance

    International Nuclear Information System (INIS)

    Hover, G.L.

    1993-01-01

    Surveillance and monitoring of oil in the marine environment imposes a broad spectrum of remote sensing requirements. At the US Coast Guard Research ampersand Development Center, the environmental safety branch is sponsoring oil spill remote sensing research in four areas of technology: Synthetic aperture radar (SAR), Frequency-scanning microwave radiometry (FSR), Laser fluorosensing (LFS), and Forward-looking infrared (FLIR) imagers. SAR technology uses sophisticated signal processing to overcome prior limitations, providing images of higher and more uniform spatial acuity which may enable interpreters to more-readily distinguish petroleum slicks from others. The ability to determine the distribution of oil thickness within a slick is necessary when an estimate of oil volume is desired. Scientists at MIT have formulated a new approach to radiometric oil thickness measurement that takes advantage of recent advances in electronic component technology. The initial data collected with a prototype FSR instrument have validated the FSR concept and more work is ongoing. The Coast Guard is co-funding a program to demonstrate and evaluate the capabilities of an airborne laser fluorosensor to support oil spill response operations. During a controlled test, the instrument successfully demonstrated an ability to detect oil on water, ice, and various beach surfaces. Additional testing included different oil types and allowed for weathering. Data analysis is ongoing. Recent developments in infrared imager technology have produced a wide variety of off-the-shelf, portable cameras that could potentially provide a rapid-response spill assessment capability. The R ampersand D Center has been involved in the testing of many of these sensors

  4. Assessment of Antioxidant Indices after incorporating Crude Oil ...

    African Journals Online (AJOL)

    ADOWIE PERE

    Exposure to crude oil pollution leads to the formation ... vitamin/mineral mixture (5 %). The food ..... hepatic antioxidant enzymes against cadmium induced liver ... Interaction of crude oil with alpha-tocopherol: ... Essential oil from Monodora.

  5. Effects of dispersants on microbial growth and biodegradation of crude oils

    Digital Repository Service at National Institute of Oceanography (India)

    Bhosle, N.B.; Mavinkurve, S.

    Four oil spill dispersants when used along (0.1% V/V) or in combination with Saudi Arabian Crude (0.5% V/V) were non-toxic to Arthrobacter simplex and Candida tropicalis. At a higher concentration of 0.6% (V/V) only D2 was found to be toxic to both...

  6. The 1990 Arthur Kill oil spills

    International Nuclear Information System (INIS)

    Astor, P.H.

    1990-01-01

    On January 1-2, 1990, Exxon discharged 567,000 gallons of No. 2 heating oil in the Arthur Kill, the strait separating Staten Island, New York from New Jersey. Lawsuits against Exxon were filed by the State of New Jersey, New York City, and the City of Elizabeth. They seek to force Exxon to reimburse the municipalities and the state for cleanup costs and to restore damaged wetlands and other natural resources. The three plaintiffs, joined by New York State and the federal government, initiated a three-tiered natural resource damage assessment study (Tier II), currently underway, includes sampling and chemical analysis of sediments and benthic invertebrates, mapping of impacted wetlands and measurement of direct impacts on water birds and their prey. The purposes of the study are to quantify the damages and determine the presence of Exxon's oil in the sediments. Since the Exxon spill, there have been two major spills and an intermediate-size spill. During the first size months of 1990, over one million gallons of petroleum products have been discharged into the Arthur Kill and nearby waters. This paper reports that a review of these incidents provides lessons for the prevention, investigation, and cleanup of spills in urban estuaries

  7. New guidelines for oil spill identification of waterborne petroleum and petroleum products

    Energy Technology Data Exchange (ETDEWEB)

    Faksness, L.G.; Daling, P.S. [SINTEF Energy Research, Trondheim (Norway); Hansen, A.B. [National Environmental Research Inst., Roskilde (Denmark); Kienhuis, P. [RIZA, (Netherlands); Duus, R. [Norwegian Standard Association (Norway)

    2005-07-01

    Advances in interpretive and analytical methods have opened the possibility to improve the existing Nordtest methodology for oil spill identification which was developed in 1991 under the Nordic Council of Ministers. In 2002, the European Committee for Standardization (CEN) established 2 working groups to revise the Nordtest Methodology into the following 2 CEN guidelines: (1) oil spill identification which includes waterborne and petroleum products, and (2) oil spill identification which in addition to including waterborne petroleum and petroleum products, includes analytical methodology and interpretation of results. The revised methodology includes a protocol/decision chart that has 3 tiered levels of analyses and data treatment. The methodology relies on the characterization of diagnostic ratios. The CEN working group intends to use the guidelines as a basis for a national oil spill identification protocol in each European country and for further international use. The methodology can be applied to oil samples of petrogenic origin with boiling points above 200 degrees C, such as crude oils, diesel fuel oils, residual bunker oils, lubricants, and mixtures of oily bilge and sludge samples. It is not intended for automotive gasolines or other light petroleum products. The method has been implemented in most forensic laboratories in Europe and has successfully differentiated between oils from a spill and possible pollution sources. 19 refs., 4 tabs., 10 figs.

  8. New guidelines for oil spill identification of waterborne petroleum and petroleum products

    International Nuclear Information System (INIS)

    Faksness, L.G.; Daling, P.S.; Hansen, A.B.; Kienhuis, P.; Duus, R.

    2005-01-01

    Advances in interpretive and analytical methods have opened the possibility to improve the existing Nordtest methodology for oil spill identification which was developed in 1991 under the Nordic Council of Ministers. In 2002, the European Committee for Standardization (CEN) established 2 working groups to revise the Nordtest Methodology into the following 2 CEN guidelines: (1) oil spill identification which includes waterborne and petroleum products, and (2) oil spill identification which in addition to including waterborne petroleum and petroleum products, includes analytical methodology and interpretation of results. The revised methodology includes a protocol/decision chart that has 3 tiered levels of analyses and data treatment. The methodology relies on the characterization of diagnostic ratios. The CEN working group intends to use the guidelines as a basis for a national oil spill identification protocol in each European country and for further international use. The methodology can be applied to oil samples of petrogenic origin with boiling points above 200 degrees C, such as crude oils, diesel fuel oils, residual bunker oils, lubricants, and mixtures of oily bilge and sludge samples. It is not intended for automotive gasolines or other light petroleum products. The method has been implemented in most forensic laboratories in Europe and has successfully differentiated between oils from a spill and possible pollution sources. 19 refs., 4 tabs., 10 figs

  9. Tourism and its hypersensitivity to oil spills.

    Science.gov (United States)

    Cirer-Costa, Joan Carles

    2015-02-15

    The sinking of the Don Pedro merchant ship in 2007 near the island of Ibiza is a good example of the extreme sensitivity of the tourism sector to oil spills. Despite the limited scale of the spill (only some 20 tonnes), its minimal ecological impact, and the rapid deployment of personnel and equipment to contain it, the accident nonetheless caused significant economic damage to the island's tourism sector. This particular case demonstrates the importance of the beach as a factor of production in the holiday tourism sector, and the capacity of even small amounts of oil to render it unusable and cause heavy losses to holiday firms. Copyright © 2014 Elsevier Ltd. All rights reserved.

  10. Introducing COSS: A new and unique oil spill research facility

    International Nuclear Information System (INIS)

    Kitchen, R. B.; Bonner, J. S.; Autenrieth, R. L.; Donnelly, K. C.; Ernest, A. N. S.

    1997-01-01

    A new oil spill research facility in Corpus Christi, Texas began operation in April 1997 to address the appropriate use, application and effectiveness of chemical, physical and biological oil spill response agents. The Coastal Oil Spill Simulation (COSS) facility consists of nine meso scale wave tanks and will offer to science and industry a unique opportunity to spill oil in a controlled environment and to study fate, transport and remediation of oil releases in simulated coastal, intertidal, lagunal, channel and porous media. 1 ref

  11. Biogeochemistry of anaerobic crude oil biodegradation

    Science.gov (United States)

    Head, Ian; Gray, Neil; Aitken, Caroline; Sherry, Angela; Jones, Martin; Larter, Stephen

    2010-05-01

    Anaerobic degradation of crude oil and petroleum hydrocarbons is widely recognized as a globally significant process both in the formation of the world's vast heavy oil deposits and for the dissipation of hydrocarbon pollution in anoxic contaminated environments. Comparative analysis of crude oil biodegradation under methanogenic and sulfate-reducing conditions has revealed differences not only in the patterns of compound class removal but also in the microbial communities responsible. Under methanogenic conditions syntrophic associations dominated by bacteria from the Syntropheaceae are prevalent and these are likely key players in the initial anaerobic degradation of crude oil alkanes to intermediates such as hydrogen and acetate. Syntrophic acetate oxidation plays an important role in these systems and often results in methanogenesis dominated by CO2 reduction by members of the Methanomicrobiales. By contrast the bacterial communities from sulfate-reducing crude oil-degrading systems were more diverse and no single taxon dominated the oil-degrading sulfate-reducing systems. All five proteobacterial subdivisions were represented with Delta- and Gammaproteobacteria being detected most consistently. In sediments which were pasteurized hydrocarbon degradation continued at a relatively low rate. Nevertheless, alkylsuccinates characteristic of anaerobic hydrocarbon degradation accumulated to high concentrations. This suggested that the sediments harbour heat resistant, possibly spore-forming alkane degrading sulfate-reducers. This is particularly interesting since it has been proposed recently, that spore-forming sulfate-reducing bacteria found in cold arctic sediments may have originated from seepage of geofluids from deep subsurface hydrocarbon reservoirs.

  12. Waxy crude oil flow restart ability

    Energy Technology Data Exchange (ETDEWEB)

    Sierra, Andre Gaona; Varges, Priscilla Ribeiro; Mendes, Paulo Roberto de Souza [Dept. of Mechanical Engineering. Pontificia Universidade Catolica do Rio de Janeiro, RJ (Brazil)], e-mails: prvarges@puc-rio.br, pmendes@puc-rio.br; Ziglio, Claudio [PETROBRAS S.A, R.J., Rio de Janeiro, RJ (Brazil)], e-mail: ziglio@petrobras.com.br

    2010-07-01

    Under the hot reservoir conditions, waxy crudes behave like Newtonian fluids but once they experience very cold temperatures on the sea floor, the heavy paraffin's begin to precipitate from the solution impacting non- Newtonian flow behavior to the crude (Chang 2000, Lee 2009, Davidson 2004) and begin to deposit on the pipe wall leave blocked of pipeline. This gel cannot be broken with the original steady state flow operating pressure applied before gelation (Chang 1998). Restarting waxy crude oil flows in pipelines is a difficult issue because of the complex rheological behavior of the gelled oil. Indeed, below the WAT, the gelled oil exhibits viscoplastic, thixotropic, temperature-dependent, and compressible properties due to the interlocking gel-like structure formed by the crystallized paraffin compounds and the thermal shrinkage of the oil. The main objective of this work is to determine the minimal pressure to restart the flow, and the relationship between the fluid rheology , pipe geometry and the restart pressure of the flow. Experiments will be performed to investigate the displacement of carbopol aqueous solutions (viscoplastic fluid without thixotropic effects) by Newtonian oil flowing through a strait pipe to validate the experimental apparatus. Therefore, tests will be made with different fluids, like Laponite and waxy crude oils. (author)

  13. Use of three generations of oil spill models during the Gulf War oil spills

    International Nuclear Information System (INIS)

    Cerkirge, H.M.; Al-Rabeh, A.H.; Gunay, N.

    1992-01-01

    During the January-May 1991 Gulf War, an estimated 6 million bbl of oil was spilled into the Arabian Gulf, mostly around Mina Al-Ahmadi in southern Kuwait. Three models were used to analyze the fate and transport of the spills originating at Al-Ahmadi. The first generation model, GULFSLIK I, was developed in the late 1970s and predicts the movements of a spill by considering that the center of the slick advects with a velocity equal to 3% of the wind speed. This model is best for the initial forecasting of oil spill movement. The second generation GULFSLIK II Model predicts the trajectory of spills at 24 h intervals, requiring as input the average daily wind velocity. Surface currents are obtained for the model from a reliable 3-dimensional hydrodynamic model of the Gulf coupled with an appropriate interpolation scheme. Comparisons between predicted spill trajectories and actual sightings show GULFSLIK II to be reasonably accurate. The third generation model, called OILPOL, consists of a set of algorithms describing the processes of advection, turbulent diffusion, surface spreading, vertical mechanical dispersion, emulsification, and evaporation. After 80 days, results show under 8% of the initial oil volume remains on the sea surface while 15% is suspended in the water column or sedimented on the sea bed. Comparisons of simulation results and actual sightings show excellent agreement. 4 refs., 7 figs., 2 tabs

  14. Forecasting volatility of crude oil markets

    International Nuclear Information System (INIS)

    Kang, Sang Hoon; Kang, Sang-Mok; Yoon, Seong-Min

    2009-01-01

    This article investigates the efficacy of a volatility model for three crude oil markets - Brent, Dubai, and West Texas Intermediate (WTI) - with regard to its ability to forecast and identify volatility stylized facts, in particular volatility persistence or long memory. In this context, we assess persistence in the volatility of the three crude oil prices using conditional volatility models. The CGARCH and FIGARCH models are better equipped to capture persistence than are the GARCH and IGARCH models. The CGARCH and FIGARCH models also provide superior performance in out-of-sample volatility forecasts. We conclude that the CGARCH and FIGARCH models are useful for modeling and forecasting persistence in the volatility of crude oil prices. (author)

  15. Forecasting volatility of crude oil markets

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Sang Hoon [Department of Business Administration, Gyeongsang National University, Jinju, 660-701 (Korea); Kang, Sang-Mok; Yoon, Seong-Min [Department of Economics, Pusan National University, Busan, 609-735 (Korea)

    2009-01-15

    This article investigates the efficacy of a volatility model for three crude oil markets - Brent, Dubai, and West Texas Intermediate (WTI) - with regard to its ability to forecast and identify volatility stylized facts, in particular volatility persistence or long memory. In this context, we assess persistence in the volatility of the three crude oil prices using conditional volatility models. The CGARCH and FIGARCH models are better equipped to capture persistence than are the GARCH and IGARCH models. The CGARCH and FIGARCH models also provide superior performance in out-of-sample volatility forecasts. We conclude that the CGARCH and FIGARCH models are useful for modeling and forecasting persistence in the volatility of crude oil prices. (author)

  16. Designing an oil spill information management system

    International Nuclear Information System (INIS)

    Douligeris, C.; Collins, J.; Iakovou, E.; Sun, P.; Riggs, K.R.

    1995-01-01

    This paper presents the architectural design of OSIMS, an Oil Spill Information Management System, which is an integrated information management tool that consists of an object-relational database management system, an adaptive decision support system, an advanced visualization system (AVS) and a geographic information system (GIS). OSIMS will handle large and diverse databases of environmental, ecological, geographical, engineering, and regulatory information and will be used for risk analysis and contingency planning

  17. Designing an oil spill information management system

    Energy Technology Data Exchange (ETDEWEB)

    Douligeris, C.; Collins, J.; Iakovou, E.; Sun, P.; Riggs, K.R. [Univ. of Miami, Coral Gables, FL (United States)

    1995-12-31

    This paper presents the architectural design of OSIMS, an Oil Spill Information Management System, which is an integrated information management tool that consists of an object-relational database management system, an adaptive decision support system, an advanced visualization system (AVS) and a geographic information system (GIS). OSIMS will handle large and diverse databases of environmental, ecological, geographical, engineering, and regulatory information and will be used for risk analysis and contingency planning.

  18. Acetylation of oil palm empty fruit bunch fiber as an adsorbent for removal of crude oil.

    Science.gov (United States)

    Asadpour, Robabeh; Sapari, Nasiman B; Isa, Mohamed Hasnain; Kakooei, Saeid

    2016-06-01

    Removal of oil spillage from the environment is a global concern. Various methods, including the use of fibers as sorbents, have been developed for oil spill control. Oil palm empty fruit bunch (OPEFB) fiber is a plant biomass that may be acetylated by acetic anhydride using N-bromosuccinimide (NBS) as a catalyst; here, the extent of acetylation may be calculated in terms of weight percent gain (WPG). The modified fiber was used to remove Tapis and Arabian crude oils. The optimum time, temperature, and catalyst concentration were 4 h, 120 °C, and 3 %, respectively, and these parameters could achieve an 11.49 % increase in WPG. The optimized parameters improved the adsorption capacity of OPEFB fibers for crude oil removal. The acetylated OPEFB fibers were characterized by using Fourier transform infrared spectroscopy and field emission scanning electron microscopy to observe the functional groups available and morphology. Kinetic and isotherm studies were conducted using different contact times and oil/water ratios. The rate of oil sorption onto the OPEFB fibers can be adequately described by the pseudo-second-order equation. Adsorption studies revealed that adsorption of crude oil on treated OPEFB fiber could be best described by the Langmuir isotherm model.

  19. Crude oil hedging: benchmarking price protection strategies

    International Nuclear Information System (INIS)

    Krapels, Edward N.; Pratt, Michael

    1998-01-01

    This report presents a review of hedging (protection against a loss) strategies in the crude oil futures and options markets. The introductory section of the report gives details of hedging instruments, and the purposes of hedging crude oil. Hedging strategies including pure futures strategies, pure options strategies, options combination strategies, exotic (Asian) options strategies, and insurance instruments are described. The West Texas intermediate (WTI) market depth, liquidity and hedging effectiveness are examined, and winners and losers, and energy consumers are considered. The appendix gives tables and charts summarising the outcomes of futures and options strategies under different market conditions and expectations. (UK)

  20. Seaweeds and the Exxon Valdez oil spill

    International Nuclear Information System (INIS)

    Stekoll, M.S.; Deysher, L.; Dean, T.A.

    1993-01-01

    A three-year study, initiated in 1989, has evaluated the response of subtidal and intertidal seaweed communities to the Exxon Valdez oil spill and subsequent cleanup activities. The project was part of the coastal habitat injury assessment research sanctioned under the natural resource damage assessment program. A stratified random design was used to select oiled sites for the study. Paired control (unoiled) sites were then matched to the oiled sites. The most consistent effect found in subtidal populations in Prince William Sound was the higher relative abundance of small-size classes of kelps at the oiled sites, indicating the prior disappearance of larger plants. This disappearance was possibly caused by activities associated with the cleanup operations. Intertidal populations of algae were affected by the spill and cleanup in all three major areas studied: Prince William Sound, Cook Inlet-Kenai, and Kodiak-Alaskan Peninsula. The most obvious effect was a significant removal of the dominant intertidal plant Fucus gardneri from the mid and upper intertidal zones. The limited dispersal of this plant combined with the relatively harsh conditions of the upper intertidal will cause a slow recovery of the upper intertidal zone in the affected areas. Effects of the spill extended to other algal species. Species such as Cladophora, Myelophycus, Odonthalia, Palmaria, and Polysiphonia showed decreases in their percent cover at oiled sites. Only Gloiopeltis populations appeared to increase in percent cover in oiled areas. In both the Cook Inlet-Kenai and the Kodiak-Alaskan Peninsula areas Fucus populations appeared to be enhanced in the lower intertidal zone - between 2 and 3 meters below the high-tide mark - in 1991

  1. Superoleophillic electrospun polystrene/exofoliated graphite fibre for selective removal of crude oil from water

    Science.gov (United States)

    Alayande, S. Oluwagbemiga; Dare, Enock O.; Olorundare, F. O. Grace; Nkosi, D.; Msagati, Titus A. M.; Mamba, B. B.

    2016-04-01

    During oil spills, the aquatic environment is greatly endangered because oil floats on water making the penetration of sunlight difficult therefore primary productivity is compromised, birds and aquatic organisms are totally eliminated within a short period. It is therefore essential to remove the oil from the water bodies after the spillage. This work reports on the fabrication of oil loving electrospun polystyrene-exofoliated graphite fibre with hydrophobic and oleophillic surface properties. The fibre was applied for the selective adsorption of crude oil from simulated crude oil spillage on water. The maximum oil adsorption capacity of the EPS/EG was 1.15 kg/g in 20 min while the lowest oil adsorption capacity was 0.81 kg/g in 10 min. Cheap oil adsorbent was developed with superoleophillic and superhydrophobic properties.

  2. Chemical composition of Pechora Sea crude oil

    Directory of Open Access Journals (Sweden)

    Derkach S. R.

    2017-03-01

    Full Text Available The physicochemical properties of the Pechora Sea shelf oil and its chemical composition have been studied using the methods of refractometry, titrimetry, viscometry, rheometry and standard methods for the analysis of oil and petroleum products. The fractionation of oil is held at atmospheric pressure, some fractions boiling at the temperature below and above 211 °C have been received. Chemical structural-group composition of oil and its components has been investigated using a Fourier infrared (IR spectroscopy method. The density of oil has been obtained, it is equal to 24.2 API. The chemical composition analysis shows that water content in the investigated oil sample is about 0.03 % (by weight. The oil sample contains hydrocarbons (including alkanes, naphthenes, arenes and asphaltenes with resins; their content is equal to 89 and 10 % (by weight respectively. Alkane content is about 66 %, including alkanes of normal structure – about 37 %. The solidification temperature of oil sample is equal to –43 °C. This low temperature testifies obliquely low content of solid alkanes (paraffin. Bearing in mind the content of asphaltenes with resins we can refer the investigated oil sample to resinous oils. On the other hand spectral coefficient values (aromaticity quotient and aliphaticity quotient show that oil sample belongs to naphthenic oils. According to the data of Fourier IR spectroscopy contents of naphthenes and arenes are 5.9 and 17.8 % respectively. Thus, the obtained data of chemical structural-group composition of crude oil and its fractions indicate that this oil belongs to the heavy resinous naphthenic oils. The rheological parameters obtained at the shear deformation conditions characterize the crude oil as a visco-plastic medium.

  3. Bacteria Provide Cleanup of Oil Spills, Wastewater

    Science.gov (United States)

    2010-01-01

    Through Small Business Innovation Research (SBIR) contracts with Marshall Space Flight Center, Micro-Bac International Inc., of Round Rock, Texas, developed a phototrophic cell for water purification in space. Inside the cell: millions of photosynthetic bacteria. Micro-Bac proceeded to commercialize the bacterial formulation it developed for the SBIR project. The formulation is now used for the remediation of wastewater systems and waste from livestock farms and food manufacturers. Strains of the SBIR-derived bacteria also feature in microbial solutions that treat environmentally damaging oil spills, such as that resulting from the catastrophic 2010 Deepwater Horizon oil rig explosion in the Gulf of Mexico.

  4. Compound-specific stable carbon isotopic composition of petroleum hydrocarbons as a tool for tracing the source of oil spills

    International Nuclear Information System (INIS)

    Li Yun; Xiong Yongqiang; Yang Wanying; Xie Yueliang; Li Siyuan; Sun Yongge

    2009-01-01

    With the increasing demand for and consumption of crude oils, oil spill accidents happen frequently during the transportation of crude oils and oil products, and the environmental hazard they pose has become increasingly serious in China. The exact identification of the source of spilled oil can act as forensic evidence in the investigation and handling of oil spill accidents. In this study, a weathering simulation experiment demonstrates that the mass loss of crude oils caused by short-term weathering mainly occurs within the first 24 h after a spill, and is dominated by the depletion of low-molecular weight hydrocarbons ( 18 n-alkanes). Short-term weathering has no significant effect on δ 13 C values of individual n-alkanes (C 12 -C 33 ), suggesting that a stable carbon isotope profile of n-alkanes can be a useful tool for tracing the source of an oil spill, particularly for weathered oils or those with a relatively low concentration or absence of sterane and terpane biomarkers

  5. Spilled oil and infaunal activity - Modification of burrowing behavior and redistribution of oil

    Science.gov (United States)

    Clifton, H.E.; Kvenvolden, K.A.; Rapp, J.B.

    1984-01-01

    A series of experiments in Willapa Bay, Washington, indicates the degree to which the presence of spilled oil modifies the burrowing behavior of infauna and the extent to which the animals redistribute oil into intertidal sediment. Small amounts of North Slope crude oil introduced at low tide directly into burrow openings (mostly made by the crustacean Callianassa) resulted in a limited and temporary reduction in the number of burrow openings. In contrast, a layer of oil-saturated sand 1 cm thick buried about 5 cm below the sediment surface sharply reduced the number of burrow openings. After a year, the few new burrows penetrated only the margins of the experimental plot, and bioturbation below the buried oil-saturated sand layer declined dramatically. The experiments suggest that small amounts of oil temporarily stranded by tides in themselves have no long-range effect on burrowing behavior. The fauna, however, are capable of introducing measurable amounts of oil into the subsurface, where it is retained long after the rest of the stranded oil had washed away. A buried layer of oil-saturated sand greatly reduces infaunal activity; the oil presents an effective barrier that can persist for years. The oil incorporated into the sediment from burrow openings showed evidence of degradation after 7 months. In contrast the layer of buried oil remained essentially undergraded after a period of two years, even though oil in lower concentrations above the layer was degraded after a period of one year. This variation in degree of degradation of the buried oil, as well as the heterogeneity of oil distribution wherever the oil has been incorporated from the surface, emphasises the importance of careful sampling in any attempt to locate or monitor the presence of spilled oil in the substrate.In a series of experiments in Willapa Bay, Washington, small amounts of North Slope crude oil introduced at low tide directly into burrow openings resulted in a limited and temporary

  6. Japan FRI research activities on oil tank/spilled oil fire

    International Nuclear Information System (INIS)

    Koseki, Hiroshi

    1992-01-01

    Introduction of research activities on oil tank/spilled oil fire at FRI, Japan is done. FRI has a long history of studying oil tank and spilled oil fires. Many large oil fire tests were done. The purpose of these studies is different with research of response of oil spill, but the accumulation of this knowledge is useful for conducting elimination of spilled oil on the sea with burning. Therefore to do collaboration with fire science research groups, such as FRI is useful for future activities for response to oil spills

  7. Economic impacts of oil spills: Spill unit costs for tankers, pipelines, refineries, and offshore facilities

    International Nuclear Information System (INIS)

    1993-01-01

    The impacts of oil spills -- ranging from the large, widely publicized Exxon Valdez tanker incident to smaller pipeline and refinery spills -- have been costly to both the oil industry and the public. For example, the estimated costs to Exxon of the Valdez tanker spill are on the order of $4 billion, including $2.8 billion (in 1993 dollars) for direct cleanup costs and $1.125 billion (in 1992 dollars) for settlement of damages claims caused by the spill. Application of contingent valuation costs and civil lawsuits pending in the State of Alaska could raise these costs appreciably. Even the costs of the much smaller 1991 oil spill at Texaco's refinery near Anacortes, Washington led to costs of $8 to 9 million. As a result, inexpensive waming, response and remediation technologies could lower oil spin costs, helping both the oil industry, the associated marine industries, and the environment. One means for reducing the impact and costs of oil spills is to undertake research and development on key aspects of the oil spill prevention, warming, and response and remediation systems. To target these funds to their best use, it is important to have sound data on the nature and size of spills, their likely occurrence and their unit costs. This information could then allow scarce R ampersand D dollars to be spent on areas and activities having the largest impact. This report is intended to provide the ''unit cost'' portion of this crucial information. The report examines the three key components of the US oil supply system, namely, tankers and barges; pipelines and refineries; and offshore production facilities. The specific purpose of the study was to establish the unit costs of oil spills. By manipulating this key information into a larger matrix that includes the size and frequency of occurrence of oil spills, it will be possible' to estimate the likely future impacts, costs, and sources of oil spills

  8. The future for heavy crude oil

    International Nuclear Information System (INIS)

    Horsnell, P.

    1995-01-01

    The expectation, still held in 1993, that the light oil-heavy crude oil differential would go on increasing in favour of light oil has not been fulfilled. Current perceptions are that heavy oil will continue to be relatively strong and there is no inevitable upward trend in light-heavy crude differentials. Non-OPEC production has grown significantly lighter overall in recent years and is likely to continue so for several more years. This is due to expanded light oil production in the North Sea, Latin America and the Far East, and contractions in heavy oil production in Russia and the USA. OPEC production has also become lighter with, in particular, an expansion in light oil and contraction in heavy grades from Saudi Arabia. At the same time, the nature of the demand from refineries has changed with the introduction of new units designed to process the residium from heavy oil distillation. Thus the supply of light oil has expanded while demand for it has contracted with the reverse being true for heavy oil. (2 figures, 1 table) (UK)

  9. Experimental investigation of various vegetable fibers as sorbent materials for oil spills.

    Science.gov (United States)

    Annunciado, T R; Sydenstricker, T H D; Amico, S C

    2005-11-01

    Oil spills are a global concern due to their environmental and economical impact. Various commercial systems have been developed to control these spills, including the use of fibers as sorbents. This research investigates the use of various vegetable fibers, namely mixed leaves residues, mixed sawdust, sisal (Agave sisalana), coir fiber (Cocos nucifera), sponge-gourd (Luffa cylindrica) and silk-floss as sorbent materials of crude oil. Sorption tests with crude oil were conducted in deionized and marine water media, with and without agitation. Water uptake by the fibers was investigated by tests in dry conditions and distillation of the impregnated sorbent. The silk-floss fiber showed a very high degree of hydrophobicity and oil sorption capacity of approximately 85goil/g sorbent (in 24hours). Specific gravity measurements and buoyancy tests were also used to evaluate the suitability of these fibers for the intended application.

  10. Simple suggestions for including vertical physics in oil spill models

    International Nuclear Information System (INIS)

    D'Asaro, Eric; University of Washington, Seatle, WA

    2001-01-01

    Current models of oil spills include no vertical physics. They neglect the effect of vertical water motions on the transport and concentration of floating oil. Some simple ways to introduce vertical physics are suggested here. The major suggestion is to routinely measure the density stratification of the upper ocean during oil spills in order to develop a database on the effect of stratification. (Author)

  11. 10 CFR 212.78 - Tertiary incentive crude oil.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 3 2010-01-01 2010-01-01 false Tertiary incentive crude oil. 212.78 Section 212.78 Energy DEPARTMENT OF ENERGY OIL MANDATORY PETROLEUM PRICE REGULATIONS Producers of Crude Oil § 212.78 Tertiary incentive crude oil. Annual prepaid expenses report. By January 31 of each year after 1980, the project...

  12. Oil spill dispersants. Risk assessment for Swedish waters

    International Nuclear Information System (INIS)

    Lindgren, C.; Lager, H.; Fejes, J.

    2001-12-01

    IVL has compiled a list of the international usage of oil spill dispersants and presents the technical limitations with the use of such agents as well as the biological effects of these chemical products. IVL, has also conducted an analysis of the pros and cons to using dispersants against oil spills in waters and has applied this with a risk assessment of chemical methods to combat oil spills in the Kattegat and Skagerrak and the Baltic Sea

  13. Evaluating environmental effects of oil spills by simulating the behaviour and spreading of oil on the sea surface

    International Nuclear Information System (INIS)

    Goncharov, V.K.; Ivanov, I.V.; Sokolov, A.N.

    2005-01-01

    The area of polluted surface of the sea and the volume of crude oil carried to the coastline are the main parameters that determine ecological damage. This paper considered some of the problems surrounding the assessment of environmental impacts caused by oil spills in the marine environment. Assessment of potential damage involves the analysis of many possible scenarios and the conditions that accompany them, including varying weather conditions. Computer simulations of the behaviour of spilled oil on the sea surface along with other criteria allow for the evaluation of the predicted scenario. Computer simulations provide knowledge of the spreading and drift of oil, as well as its volume and thickness. Knowledge of the following factors, combined with a knowledge of weather conditions is important in emergency response planning: vulnerability of oil pollution areas on shore; calculation of impact factors; detection of vulnerability to oil pollution; the possibility of incidents of the inadmissible oil pollution forecast; and results of a simulation of 48 hour drift of oil slick formed due to a spill in Devkin Zavod Bay. Adequate meteorological information is crucial for the development of valid data. Further progress is currently being developed for specific water areas around oil fields, tanker routes, seabed crude oil pipeline, wind currents, heaving, hydrological and environmental characteristics of sea water. 5 refs., 3 figs

  14. Natural resource damage assessments for oil spills: Status of rules and application to recent oil spills

    International Nuclear Information System (INIS)

    Robilliard, G.A.; Winfield, T.P.; Lebednik, P.A.; Markarian, R.K.

    1992-01-01

    The natural resource damage assessment (NRDA) process is based on the concept that all natural resources managed by government agencies or Indian tribes (trustees) are available to the public for its use and enjoyment. These resources have an economic value that can be affected by a spill of oil or other chemicals. The spiller or potentially responsible party (PRP) is responsible to the public, through the trustees, for paying damages and for restoration of the resource. The NRDA process should also determine the appropriate means of restoration, provide a cost for doing so and for conducting the NRDA, and should implement the appropriate restoration activities. The legal and regulatory authority behind NRDA in the USA is explained and reasons why PRPs should be concerned about NRDAs in the context of oil spills are presented. US Department of the Interior regulations describe two procedures for implementing a NRDA. A simplified procedure intended for small spills uses a computer model to generate a damage value. A more thorough and complicated procedure involves a number of phases and steps within the phases, and may include field sampling, data collection and analysis, and detailed evaluation of restoration alternatives. The NRDA experience in oil spills to date is reviewed and the future of NRDA is assessed. Examples cited include the 1988 Shell Oil spill from the Martinez Refinery, the Exxon Bayway pipeline leak of 1990, the Mega Borg spill in the Texas offshore, and the Exxon Valdez spill. It is speculated that trustees will focus on the NRDA process as a cooperative one that includes the trustees and PRPs, with the ultimate goal being restoration of the foregone services provided by natural resources. 5 refs., 1 fig

  15. Phototoxic potential of undispersed and dispersed fresh and weathered Macondo crude oils to Gulf of Mexico Marine Organisms.

    Science.gov (United States)

    Finch, Bryson E; Marzooghi, Solmaz; Di Toro, Dominic M; Stubblefield, William A

    2017-10-01

    Crude oils contain a mixture of hydrocarbons, including phototoxic polycyclic aromatic hydrocarbons (PAHs) that have the ability to absorb ultraviolet (UV) light. Absorption of UV light by PAHs can substantially increase their toxicity to marine organisms. The objective of the present study was to examine the potential for phototoxicity of fresh and naturally weathered Macondo crude oils alone and in combination with the dispersant Corexit 9500 to mysid shrimp (Americamysis bahia), inland silverside (Menidia beryllina), sheepshead minnow (Cyprinodon variegatus), and Gulf killifish (Fundulus grandis). Acute toxicity tests were conducted using combinations of natural or artificial sunlight and low-energy water-accommodated fractions (WAFs) of fresh and weathered Macondo crude oils collected from the Gulf of Mexico. Studies were also conducted to compare the phototoxicity resulting from natural and artificial sunlight. Fresh Macondo crude oil was more phototoxic than weathered crude oils, both in the presence and in the absence of UV light. Differences in toxicity between fresh and weathered crude oils were likely attributed to lighter-ringed PAHs in fresh crude oils. Phototoxic PAHs were relatively resistant to weathering compared with lighter-ringed PAHs. The addition of Corexit 9500 to crude oil increased toxicity compared with tests with crude oil alone, by increasing phototoxic PAH concentrations in WAFs. Macondo crude oils had the potential to be phototoxic to Gulf of Mexico marine organisms if specific light conditions and PAH concentrations were present during the Deepwater Horizon oil spill. Environ Toxicol Chem 2017;36:2640-2650. © 2017 SETAC. © 2017 SETAC.

  16. Cold weather oil spill response training

    International Nuclear Information System (INIS)

    Solsberg, L.B.; Owens, E.H.

    2001-01-01

    In April 2000, a three-day oil spill response training program was conducted on Alaska's North Slope. The unique hands-on program was specifically developed for Chevron Corporation's world-wide response team. It featured a combination of classroom and outdoor sessions that helped participants to learn and apply emergency measures in a series of field exercises performed in very cold weather conditions. Temperatures remained below minus 20 degrees C and sometimes reached minus 40 degrees C throughout the training. The classroom instructions introduced participants to the Emergency Prevention Preparedness and Response (EPPR) Working Group's Field Guide for Spill Response in Arctic Waters. This guide provides response strategies specific to the Arctic, including open water, ice and snow conditions. The sessions also reviewed the Alaska Clean Seas Tactics Manual which addresses spill containment and recovery, storage, tracking, burning and disposal. The issues that were emphasized throughout the training program were cold weather safety and survival. During the training sessions, participants were required to set up weather ports and drive snowmobiles and all terrain vehicles. Their mission was to detect oil with infra-red and hand-held devices. They were required to contain the oil by piling snow into snow banks, and by augering, trenching and slotting ice. Oil was removed by trimming operations on solid ice, snow melting, snow blowing, skimming and pumping. In-situ burning was also performed. Other sessions were also conducted develop skills in site characterization and treating oiled shorelines. The successfully conducted field sessions spanned all phases of a cleanup operation in cold weather. 5 refs., 7 figs

  17. Automated oil spill detection with multispectral imagery

    Science.gov (United States)

    Bradford, Brian N.; Sanchez-Reyes, Pedro J.

    2011-06-01

    In this publication we present an automated detection method for ocean surface oil, like that which existed in the Gulf of Mexico as a result of the April 20, 2010 Deepwater Horizon drilling rig explosion. Regions of surface oil in airborne imagery are isolated using red, green, and blue bands from multispectral data sets. The oil shape isolation procedure involves a series of image processing functions to draw out the visual phenomenological features of the surface oil. These functions include selective color band combinations, contrast enhancement and histogram warping. An image segmentation process then separates out contiguous regions of oil to provide a raster mask to an analyst. We automate the detection algorithm to allow large volumes of data to be processed in a short time period, which can provide timely oil coverage statistics to response crews. Geo-referenced and mosaicked data sets enable the largest identified oil regions to be mapped to exact geographic coordinates. In our simulation, multispectral imagery came from multiple sources including first-hand data collected from the Gulf. Results of the simulation show the oil spill coverage area as a raster mask, along with histogram statistics of the oil pixels. A rough square footage estimate of the coverage is reported if the image ground sample distance is available.

  18. Treatment of Liquid Oil Spill by Untreated and Treated Aswanly Clay ...

    African Journals Online (AJOL)

    The aim of this work is to use cheap, available and recyclable sorbents for oil spill clean – up. α -SiO2-Quartz, Na2Si2O5(OH)4, CaCO3, MgCO3, BaCO3, CaO, MgO, ... Characteristics of crude oil and Aswanly clay were investigated by FTIR, X – Ray Fluorescence, X – Ray Diffraction, pour point and centrifuge instruments.

  19. Hebei Spirit Oil Spill Exposure and Subjective Symptoms in Residents Participating in Clean-Up Activities

    OpenAIRE

    Cheong, Hae-Kwan; Ha, Mina; Lee, Jong Seong; Kwon, Hojang; Ha, Eun-Hee; Hong, Yun-Chul; Choi, Yeyong; Jeong, Woo-Chul; Hur, Jongil; Lee, Seung-Min; Kim, Eun-Jung; Im, Hosub

    2011-01-01

    Objectives This study was conducted to examine the relationship between crude oil exposure and physical symptoms among residents participating in clean-up work associated with the Hebei Spirit oil spill, 2007 in Korea. Methods A total of 288 residents responded to a questionnaire regarding subjective physical symptoms, sociodemographic characteristics and clean-up activities that occurred between two and eight weeks after the accident. Additionally, the urine of 154 of the respondents was ana...

  20. PRP: The Proven Solution for Cleaning Up Oil Spills

    Science.gov (United States)

    2006-01-01

    The basic technology behind PRP is thousands of microcapsules, tiny balls of beeswax with hollow centers. Water cannot penetrate the microcapsule s cell, but oil is absorbed right into the beeswax spheres as they float on the water s surface. This way, the contaminants, chemical compounds that originally come from crude oil such as fuels, motor oils, or petroleum hydrocarbons, are caught before they settle. PRP works well as a loose powder for cleaning up contaminants in lakes and other ecologically fragile areas. The powder can be spread over a contaminated body of water or soil, and it will absorb contaminants, contain them in isolation, and dispose of them safely. In water, it is important that PRP floats and keeps the oil on the surface, because, even if oil exposure is not immediately lethal, it can cause long-term harm if allowed to settle. Bottom-dwelling fish exposed to compounds released after oil spills may develop liver disease, in addition to reproductive and growth problems. This use of PRP is especially effective for environmental cleanup in sensitive areas like coral reefs and mangroves.

  1. DOE/DOE Tight Oil Flammability & Transportation Spill Safety

    Energy Technology Data Exchange (ETDEWEB)

    Lord, David L. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2014-12-01

    This presentation describes crude oils, their phase behavior, the SPR vapor pressure program, and presents data comparisons from various analytical techniques. The overall objective is to describe physical properties of crude oil relevant to flammability and transport safety

  2. Microbial population changes during bioremediation of an experimental oil spill

    International Nuclear Information System (INIS)

    MacNaughton, S.J.; Stephen, J.R.; Chang, Y.J.; Davis, G.A.; White, D.C.; Oak Ridge National Lab., TN

    1999-01-01

    Three crude oil bioremediation techniques were applied in a randomized block field experiment simulating a coastal oil spill. Four treatments (no oil control, oil alone, oil plus nutrients, and oil plus nutrients plus an indigenous inoculum) were applied. In situ microbial community structures were monitored by phospholipid fatty acid (PLFA) analysis and 16S rDNA PCR-denaturing gradient gel electrophoresis (DGGE) to (i) identify the bacterial community members responsible for the decontamination of the site and (ii) define an end point for the removal of the hydrocarbon substrate. The results of PLFA analysis demonstrated a community shift in all plots from primarily eukaryotic biomass to gram-negative bacterial biomass with time. PLFA profiles from the oiled plots suggested increased gram-negative biomass and adaptation to metabolic stress compared to unoiled controls. DGGE analysis of untreated control plots revealed a simple, dynamic dominant population structure throughout the experiment. This banding pattern disappeared in all oiled plots, indicating that the structure and diversity of the dominant bacterial community changed substantially. No consistent differences were detected between nutrient-amended and indigenous inoculum-treated plots, but both differed from the oil-only plots. Prominent bands were excised for sequence analysis and indicated that oil treatment encouraged the growth of gram-negative microorganisms within the α-proteobacteria and Flexibacter-Cytophaga-Bacteroides phylum. α-Proteobacteria were never detected in unoiled controls. PLFA analysis indicated that by week 14 the microbial community structures of the oiled plots were becoming similar to those of the unoiled controls from the same time point, but DGGE analysis suggested that major differences in the bacterial communities remained

  3. Characterization of dioxygenases and biosurfactants produced by crude oil degrading soil bacteria

    Directory of Open Access Journals (Sweden)

    Santhakumar Muthukamalam

    Full Text Available ABSTRACT Role of microbes in bioremediation of oil spills has become inevitable owing to their eco friendly nature. This study focused on the isolation and characterization of bacterial strains with superior oil degrading potential from crude-oil contaminated soil. Three such bacterial strains were selected and subsequently identified by 16S rRNA gene sequence analysis as Corynebacterium aurimucosum, Acinetobacter baumannii and Microbacterium hydrocarbonoxydans respectively. The specific activity of catechol 1,2 dioxygenase (C12O and catechol 2,3 dioxygenase (C23O was determined in these three strains wherein the activity of C12O was more than that of C23O. Among the three strains, Microbacterium hydrocarbonoxydans exhibited superior crude oil degrading ability as evidenced by its superior growth rate in crude oil enriched medium and enhanced activity of dioxygenases. Also degradation of total petroleum hydrocarbon (TPH in crude oil was higher with Microbacterium hydrocarbonoxydans. The three strains also produced biosurfactants of glycolipid nature as indicated d by biochemical, FTIR and GCMS analysis. These findings emphasize that such bacterial strains with superior oil degrading capacity may find their potential application in bioremediation of oil spills and conservation of marine and soil ecosystem.

  4. Refining crude oils and gasolines, etc

    Energy Technology Data Exchange (ETDEWEB)

    1931-11-23

    A process of refining crude oils and gasolines distilled from shale and the like is described, consisting of submitting them to a prewash with soda, an oxidation preferably with hypochlorite solution, a hydrogenation with nascent hydrogen, and finally rectification and neutralization.

  5. Floating Oil-Spill Containment Device

    Science.gov (United States)

    Jones, Jack A.

    2012-01-01

    Previous oil containment booms have an open top that allows natural gas to escape, and have significant oil leakage due to wave action. Also, a subsea pyramid oil trap exists, but cannot move relative to moving oil plumes from deepsea oil leaks. The solution is to have large, moveable oil traps. One version floats on the sea surface and has a flexible tarp cover and a lower weighted skirt to completely entrap the floating oil and natural gas. The device must have at least three sides with boats pulling at each apex, and sonar or other system to track the slowly moving oil plume, so that the boats can properly locate the booms. The oil trap device must also have a means for removal of the oil and the natural gas. A second design version has a flexible pyramid cover that is attached by lines to ballast on the ocean floor. This is similar to fixed, metal pyramid oil capture devices in the Santa Barbara Channel off the coast of California. The ballast lines for the improved design, however, would have winches that can move the pyramid to always be located above the oil and gas plume. A third design is a combination of the first two. It uses a submerged pyramid to trap oil, but has no anchor and uses boats to locate the trap. It has ballast weights located along the bottom of the tarp and/or at the corners of the trap. The improved floating oil-spill containment device has a large floating boom and weighted skirt surrounding the oil and gas entrapment area. The device is triangular (or more than three sides) and has a flexible tarp cover with a raised gas vent area. Boats pull on the apex of the triangles to maintain tension and to allow the device to move to optimum locations to trap oil and gas. The gas is retrieved from a higher buoyant part of the tarp, and oil is retrieved from the floating oil layer contained in the device. These devices can be operated in relatively severe weather, since waves will break over the devices without causing oil leaking. Also, natural

  6. Ecological effects research related to oil spills and oil spill countermeasures

    International Nuclear Information System (INIS)

    Aurand, D.

    1992-01-01

    The Marine Spill Response Corporation (MSRC) was created specifically to provide an improved response option for large marine oil spills in U.S. waters. As part of that capability, MSRC is committed to an extensive research and development program designed to improve the state-of-the-art for oil spill response. Within the mission, the goals of the Environmental Health Program are to ensure that ecological and human health effects of both oil and oil cleanup counter measures are well understood and that this information is made widely available for appropriate consideration in planning and implementing oil spill response efforts. This an applied program, and is intended to directly support the MSRC response mission. It does not include studies directly related to damage assessment, which is outside of the mission of MSRC. This paper focuses on the issues MSRC sees as critical in the area of ecological effects research, and addresses four topics: Why do we need to do more? What is it we hope to accomplish? What needs to be done? What is being planned or implemented?

  7. State of the Art Satellite and Airborne Marine Oil Spill Remote Sensing: Application to the BP Deepwater Horizon Oil Spill

    Science.gov (United States)

    2012-01-01

    development and operationalization of new spill response remote sensing tools must precede the next major oil spill. © 2012 Elsevier Inc. All rights reserved...Environment 124 (2012) 185–209 sensing oil spill impacts, and 5) a final discussion. Each section presents background, available remote sensing tools , and...cialized DaVinci command-line software (Clark et al., 2003) then mapped oil slick volume (Clark et al., 2010) in each AVIRIS pixel by identifying the

  8. Comparative study on adsorption of crude oil and spent engine oil from seawater and freshwater using algal biomass.

    Science.gov (United States)

    Boleydei, Hamid; Mirghaffari, Nourollah; Farhadian, Omidvar

    2018-05-15

    Efficiency of a biosorbent prepared from the green macroalga Enteromorpha intestinalis biomass for decontamination of seawater and freshwater polluted by crude oil and engine spent oil was compared. The effect of different experimental conditions including contact time, pH, particle size, initial oil concentration, and biosorbent dose on the oil biosorption was studied in the batch method. The biosorbent was characterized by CHNOS, FTIR, and SEM analysis. The experimental data were well fitted to the pseudo-second-order kinetic model and the Langmuir adsorption isotherm model. Based on the obtained results, the adsorption of spent oil with higher viscosity was better than crude oil. The biosorption of oil hydrocarbons from seawater was more efficient than freshwater. The algal biomasses which are abundantly available could be effectively used as a low-cost and environmentally friendly adsorbent for remediation of oil spill in the marine environments or in the water and wastewater treatment.

  9. Information to help reduce environmental impacts from freshwater oil spills

    International Nuclear Information System (INIS)

    Fritz, D.E.; Steen, A.E.

    1995-01-01

    The American Petroleum Institute (API) has been working since 1990 to provide information to help the response community minimize the impact of spills to pared jointly with the US inland freshwater. Projects have included a manual, pre National Oceanic and Atmospheric Administration (NOAA), to give guidance on the cleanup techniques that will minimize environmental impacts on spills in freshwater habitats. Nearing completion are a literature review and annotated bibliography of the environmental and human health effects of oil spilled in freshwater habitats. The use of chemical treating agents for freshwater spill applications is being studied with input from other industry and government groups. A project has begun, with funding from API, the Louisiana Applied Oil Spill Research and Development Program, NOAA, the Marine Spill Response Corporation (MSRC), and the US Department of Energy, to evaluate in situ burning of oil spilled in marshes

  10. Compositional modification of crude oil during oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Yangming; Weng, Huanxin [Department of Earth Sciences, Zhejiang University, Hangzhou 310027 (China); Chen, Zulin; Chen, Qi [Petroleum Geochemistry Research Center, Jianghan Petroleum University, Jingzhou, Hubei (China)

    2003-05-01

    Ten crude oils from two recovery stages spanning 5-10-year interval of five productive wells in the Tarim Basin, northwest China were analyzed for their compositional modification during production process. Significant compositional changes in polar and nonpolar fractions between the previous oil samples and the latter ones were noted at both bulk and molecular level. The latter oil samples appear to contain more aromatic fraction and less asphaltenes and resin, and their gas chromatography (GC) data for whole oil show reduced alkanes with low molecular weight and enhanced high homologue relative to the previous oil samples. Compared with the oils collected from the previous recovery stage, the concentration of basic type of nitrogen-containing compounds and organic acids in oils from the latter recovery stage have a reducing trend, suggesting the occurrence of interaction between crude oil and reservoir rock.

  11. Diverse wettability of superoleophilicity and superoleophobicity for oil spill cleanup and recycling

    Science.gov (United States)

    Xu, Mengya; Wang, Gang; Zeng, Zhixiang; Chen, Junjun; Zhang, Xingyuan; Wang, Longsheng; Song, Weiguang; Xue, Qunji

    2017-12-01

    The frequent marine oil spill accidents in nowadays has aroused great attention all over the world. Lots of superwetting absorption materials with 2D or 3D structures are fabricated to efficiently remove oil spill, but the desorption of the absorbed oil is more difficult. Oil contaminants adhere on the surface will decline the performance and reusability of the absorption materials. Discarding or burning them will bring secondary pollution. Faced with these problems, we prepared an oil extractor integrated by a superhydrophobic-superoleophilic stainless steels wire mesh and a 3D porous cellulose sponge with superhydrophilicity-superoleophilicity in air and superoleophobicity in water. The oil extractor can in situ collect oil spill no matter on the water or under the water. More importantly, it is good at underwater oil desorption, which ensure the recovery and reuse of oil, and meanwhile avoid the materials being fouled by oils. More than 85.5% of crude oil could be successfully discharged only in 2 min when the oil-contaminated sponge was placed in water. The findings in this work not only put forward a new strategy for collection and reuse of various "oils", but also offer a facile method to achieve a combination of two kinds of materials with diverse wettability.

  12. GC/MS determination of bicyclic sesquiterpanes in crude oils and petroleum products

    International Nuclear Information System (INIS)

    Yang, C.; Wang, Z.; Hollebone, B.; Brown, C.E.; Landriault, M.

    2008-01-01

    A study was conducted in which sesquiterpanes, a component of crude oils and petroleum products, were identified and characterized in an effort to determine the feasibility of using them as biomarkers for fingerprinting and identifying unknown lighter petroleum product spills. The study compared the distributions of sesquiterpanes in different oils, oil distillation fractions and refined products, including light and mid-range distillate fuels, residual fuels and lubricating oils. Evaporative weathering effects on sesquiterpane distribution and concentration were quantitatively studied and several diagnostic indices of sesquiterpane were developed for oil correlation and differentiation. Bicyclic sesquiterpanes in crude oils and oil products have much different abundances and distributions. Therefore, the relevant sesquiterpane ratios are different. Bicyclic sesquiterpanes are mostly partitioned into the medium distillation fractions. The study showed that concentrations of sesquiterpanes in crude oil and diesel fuel increase in proportion with the increase of weathering percentages. Relevant diagnostic ratios therefore remained stable. It was concluded that C 15 and C 16 sesquiterpanes may be alternative internal tracers to provide a direct way to estimate the depletion of oils, particularly diesels, in oil spill investigations. 13 refs., 6 tabs., 4 figs

  13. Application of Markov Model in Crude Oil Price Forecasting

    Directory of Open Access Journals (Sweden)

    Nuhu Isah

    2017-08-01

    Full Text Available Crude oil is an important energy commodity to mankind. Several causes have made crude oil prices to be volatile. The fluctuation of crude oil prices has affected many related sectors and stock market indices. Hence, forecasting the crude oil prices is essential to avoid the future prices of the non-renewable natural resources to rise. In this study, daily crude oil prices data was obtained from WTI dated 2 January to 29 May 2015. We used Markov Model (MM approach in forecasting the crude oil prices. In this study, the analyses were done using EViews and Maple software where the potential of this software in forecasting daily crude oil prices time series data was explored. Based on the study, we concluded that MM model is able to produce accurate forecast based on a description of history patterns in crude oil prices.

  14. A MODEL FOR DIFFUSION CONTROLLED BIOAVAILABILITY OF CRUDE OIL COMPONENTS

    Science.gov (United States)

    Crude oil is a complex mixture of several different structural classes of compounds including alkanes, aromatics, heterocyclic polar compounds, and asphaltenes. The rate and extent of microbial degradation of crude oil depends on the interaction between the physical and biochemi...

  15. Characterization of CRUDE OILS and petroleum products: (i) elution ...

    African Journals Online (AJOL)

    Characterization of CRUDE OILS and petroleum products: (i) elution liquid chromatographic separation and gas chromatographic analysis of crude oils and petroleum products. E.O. Odebunmi, E.A. Ogunsakin, P.E.P. Ilukhor ...

  16. Efficient way of importing crude oil from oil producing countries - A review on diversification policy of crude oil import

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Dal Sok [Korea Energy Economics Institute, Euiwang (Korea)

    1999-03-01

    Since the second oil crisis, the government has operated the import diversification support program to reduce the risk of crude oil import from Middle-East region and to raise the ability of dealing with the risk. This study tried to seek policy trends in future through reviewing the market environment related to the crude oil import diversification policy and the goal, instrument and effect of the policy. The supply and demand of crude oil and the price are influenced by market system in the world oil market and there are various types of crude oil trading available to both sellers and buyers. There is a probability that the suspension of supply in a certain area could be led to the price issue rather than the physical use of crude oil. In addition, the advantage of price with long-term contract of crude oil was abolished since the price of crude oil imported by term contract has been linked to spot prices. As a result, it is shown that the potential benefit from crude oil import diversification policy is reduced although political and social insecurity still exists in Middle-East region. Therefore, it is desirable to maintain the existing support program until the amount of stored oil reaches the optimum level and to help private enterprises determine the import considering economical efficiency and risk. (author). 36 refs., 5 figs., 23 tabs.

  17. Oil spill risk assessment in maritime transportation networks

    International Nuclear Information System (INIS)

    Yudhbir, L.; Iakovou, E.

    2005-01-01

    Commercial shippers and regulatory agencies face the challenge of evaluating the merits of various alternative policies for the transportation of crude oil and petroleum products. This paper presented a new risk estimation and assignment methodology that assesses the risk costs for the bodies of water where shipping lanes exist. The methodology is based on historical spills and uses causal data to estimate risk cost between 2 points of reference for numerous products transported by a variety of vessels. In response to public concerns regarding the environmental impacts of accidental spills from tanker ships, laws have been imposed on companies for all costs relating to environmental damage. This measure has prompted the oil industry to take greater responsibility, but a better understanding of tanker re-routing on environmental sensitive areas is needed in order to implement detailed emergency response plans and greater safety precautions. This methodology addressed the need for an efficient maritime transportation system that provides routing for various vessels carrying different petroleum products. The risk estimation methodology successfully modeled a multi-objective, multi-commodity routing problem. 23 refs., 3 figs

  18. Literature Survey of Crude Oil Properties Relevant to Handling and Fire Safety in Transport.

    Energy Technology Data Exchange (ETDEWEB)

    Lord, David [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Luketa, Anay [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Wocken, Chad [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Schlasner, Steve [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Aulich, Ted [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Allen, Ray [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Rudeen, David Keith [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-03-01

    Several fiery rail accidents in 2013-2015 in the U.S. and Canada carrying crude oil produced from the Bakken region of North Dakota have raised questions at many levels on the safety of transporting this, and other types of crude oil, by rail. Sandia National Laboratories was commissioned by the U.S. Department of Energy to investigate the material properties of crude oils, and in particular the so-called "tight oils" like Bakken that comprise the majority of crude oil rail shipments in the U.S. at the current time. The current report is a literature survey of public sources of information on crude oil properties that have some bearing on the likelihood or severity of combustion events that may occur around spills associated with rail transport. The report also contains background information including a review of the notional "tight oil" field operating environment, as well a basic description of crude oils and potential combustion events in rail transport. This page intentionally blank

  19. The Galeta oil spill: Pt. 4

    International Nuclear Information System (INIS)

    Burns, K.A.; Yelle-Simmons, L.

    1994-01-01

    This paper gives the detailed compositions of oil residues in sediments and encrusting bivalves, and the changes over time. Initial weathering processes removed most of the volatile hydrocarbons and all market alkanes in oil adsorbed to surface sediments within 6 months after the spill. This initially fast rate of biodegradation was not maintained in the rate of disappearance of the aromatic hydrocarbons over time. Oil leaching out of heavily contaminated sediments was bioaccumulated in bivalves for at least 5 years. The organisms accumulated the whole range of alkylated polynuclear aromatic hydrocarbons (PAHs) in the naphthalene through the benzoperylene elution range, seemingly in proportion to what was leached from sediments. A change in the composition of the aromatics bioaccumulated at most sites in year 5 indicated depletion of the most soluble and most acutely toxic hydrocarbons in the readily leachable reservoirs. (author)

  20. A laboratory study of particulate and gaseous emissions from crude oil and crude oil-dispersant contaminated seawater due to breaking waves

    Science.gov (United States)

    Afshar-Mohajer, Nima; Li, Cheng; Rule, Ana M.; Katz, Joseph; Koehler, Kirsten

    2018-04-01

    Crude oil spill incidents occur frequently causing a verity of occupational, ecological and environmental problems. Dispersants are applied to enhance the dispersion rate of crude oil slicks into the water column. In this study, the aerosol size distribution from 10 nm to 20 μm, total particle-bound aromatic hydrocarbons (pPAH) and volatile organic compounds (VOCs) are measured in a 6 x 0.3 x 0.6 m tank as plunging breaking waves entrain oil slicks. The experiments are performed for seawater with slicks of crude oil, crude oil-dispersant mixture and dispersant only. The measurements investigate the effects of wave energy and slick properties on the temporal evolution of the emissions. The total number concentrations of particles originating from the oil-dispersant mixture are 1-2 orders of magnitude higher than those of crude oil across the entire nano-scale range, reaching 100x for 20 nm particles. Conversely, the differences in concentration are small in the micron range. The average concentrations of pPAH are variable but similar (150-270 ng/m3). The VOC concentrations for crude oil-dispersant mixtures are 2-3 times lower than those of crude oil, presumably due to the surfactant effect on mass diffusion. The drastic increase in ultrafine particle concentrations may raise concerns about effects of inhalation by cleanup workers and downstream communities though VOC emissions reduce. Findings through this study provide insight into how the spray of dispersant may change the ratio of airborne particulate matter and VOC emissions from seawater due to natural processes.

  1. Kinetic modeling and half life study on bioremediation of crude oil dispersed by Corexit 9500

    International Nuclear Information System (INIS)

    Zahed, Mohammad Ali; Aziz, Hamidi Abdul; Isa, Mohamed Hasnain; Mohajeri, Leila; Mohajeri, Soraya; Kutty, Shamsul Rahman Mohamed

    2011-01-01

    Hydrocarbon pollution in marine ecosystems occurs mainly by accidental oil spills, deliberate discharge of ballast waters from oil tankers and bilge waste discharges; causing site pollution and serious adverse effects on aquatic environments as well as human health. A large number of petroleum hydrocarbons are biodegradable, thus bioremediation has become an important method for the restoration of oil polluted areas. In this research, a series of natural attenuation, crude oil (CO) and dispersed crude oil (DCO) bioremediation experiments of artificially crude oil contaminated seawater was carried out. Bacterial consortiums were identified as Acinetobacter, Alcaligenes, Bacillus, Pseudomonas and Vibrio. First order kinetics described the biodegradation of crude oil. Under abiotic conditions, oil removal was 19.9% while a maximum of 31.8% total petroleum hydrocarbons (TPH) removal was obtained in natural attenuation experiment. All DCO bioreactors demonstrated higher and faster removal than CO bioreactors. Half life times were 28, 32, 38 and 58 days for DCO and 31, 40, 50 and 75 days for CO with oil concentrations of 100, 500, 1000 and 2000 mg/L, respectively. The effectiveness of Corexit 9500 dispersant was monitored in the 45 day study; the results indicated that it improved the crude oil biodegradation rate.

  2. Heavy oils processing materials requirements crude processing

    Energy Technology Data Exchange (ETDEWEB)

    Sloley, Andrew W. [CH2M Hill, Englewood, CO (United States)

    2012-07-01

    Over time, recommended best practices for crude unit materials selection have evolved to accommodate new operating requirements, feed qualities, and product qualities. The shift to heavier oil processing is one of the major changes in crude feed quality occurring over the last 20 years. The three major types of crude unit corrosion include sulfidation attack, naphthenic acid attack, and corrosion resulting from hydrolyzable chlorides. Heavy oils processing makes all three areas worse. Heavy oils have higher sulfur content; higher naphthenic acid content; and are more difficult to desalt, leading to higher chloride corrosion rates. Materials selection involves two major criteria, meeting required safety standards, and optimizing economics of the overall plant. Proper materials selection is only one component of a plant integrity approach. Materials selection cannot eliminate all corrosion. Proper materials selection requires appropriate support from other elements of an integrity protection program. The elements of integrity preservation include: materials selection (type and corrosion allowance); management limits on operating conditions allowed; feed quality control; chemical additives for corrosion reduction; and preventive maintenance and inspection (PMI). The following discussion must be taken in the context of the application of required supporting work in all the other areas. Within that context, specific materials recommendations are made to minimize corrosion due to the most common causes in the crude unit. (author)

  3. Evaluation of the toxic properties of naturally weathered Exxon Valdez crude oil to surrogate wildlife species

    International Nuclear Information System (INIS)

    Stubblefield, W.A.; Hancock, G.A.; Ford, W.H.; Prince, H.H.; Ringer, R.K.

    1995-01-01

    The toxic properties of naturally weathered Exxon Valdez crude oil (WEVC) to avian and mammalian wildlife species were evaluated using the surrogate species, mallard duck, Anas platyrhynchos, and European ferret, Mustela putorius. This study was conducted to evaluate the potential for toxic (rather than physical) injury to wildlife species that may have been exposed to WEVC, either through external contact or through dietary uptake. Previous studies have assessed the toxicity of unweathered crude oils, including Alaska North Slope Crude, but little information exists regarding the toxicity of a naturally weathered crude oil, typical of that encountered following a spill. A battery of laboratory toxicity tests was conducted, in compliance with standard and published test procedures, to evaluate acute and subchronic toxicity of WEVC. These included tests of food avoidance, reproductive effects, and direct eggshell application toxicity. Naturally weathered EVC, recovered postspill from Prince William Sound, was used as the test material. 36 refs., 7 figs., 4 tabs

  4. Volatility persistence in crude oil markets

    International Nuclear Information System (INIS)

    Charles, Amélie; Darné, Olivier

    2014-01-01

    Financial market participants and policy-makers can benefit from a better understanding of how shocks can affect volatility over time. This study assesses the impact of structural changes and outliers on volatility persistence of three crude oil markets – Brent, West Texas Intermediate (WTI) and Organization of Petroleum Exporting Countries (OPEC) – between January 2, 1985 and June 17, 2011. We identify outliers using a new semi-parametric test based on conditional heteroscedasticity models. These large shocks can be associated with particular event patterns, such as the invasion of Kuwait by Iraq, the Operation Desert Storm, the Operation Desert Fox, and the Global Financial Crisis as well as OPEC announcements on production reduction or US announcements on crude inventories. We show that outliers can bias (i) the estimates of the parameters of the equation governing volatility dynamics; (ii) the regularity and non-negativity conditions of GARCH-type models (GARCH, IGARCH, FIGARCH and HYGARCH); and (iii) the detection of structural breaks in volatility, and thus the estimation of the persistence of the volatility. Therefore, taking into account the outliers on the volatility modelling process may improve the understanding of volatility in crude oil markets. - Highlights: • We study the impact of outliers on volatility persistence of crude oil markets. • We identify outliers and patches of outliers due to specific events. • We show that outliers can bias (i) the estimates of the parameters of GARCH models, (ii) the regularity and non-negativity conditions of GARCH-type models, (iii) the detection of structural breaks in volatility of crude oil markets

  5. Bioremediation of crude oil contaminated tea plantation soil using ...

    African Journals Online (AJOL)

    Crude oil contamination of soil is a major concern for tea industry in Assam, India. Crude oil is a persistent organic contaminant which alters soil physical and biochemical characteristics and makes tea plants more susceptible against crude oil contamination. Therefore, two native bacterial strains designated as AS 03 and ...

  6. Modeling fates and impacts for bio-economic analysis of hypothetical oil spill scenarios in San Francisco Bay

    International Nuclear Information System (INIS)

    French McCay, D.; Whittier, N.; Sankaranarayanan, S.; Jennings, J.; Etkin, D.S.

    2002-01-01

    The oil spill risks associated with four submerged rock pinnacles near Alcatraz Island in San Francisco Bay are being evaluated by the United States Army Corps of Engineers. Oil spill modeling has been conducted for a hypothetical oil spill to determine biological impacts, damages to natural resources and response costs. The scenarios are hypothetical vessel grounding on the pinnacles. The SIMAP modeling software by the Applied Science Associates was used to model 3 spill sizes (20, 50 and 95 percentile by volume) and 4 types of oil (gasoline, diesel, heavy fuel oil, and crude oil). The frequency distribution of oil fates and impacts was determined by first running each scenario in stochastic mode. The oil fates and biological effects of the spills were the focus of this paper. It was shown that diesel and crude oil spills would have greater impacts in the water column than heavy fuel or gasoline because gasoline is more volatile and less toxic and because heavy oil spills would be small in volume. It was determined that the major impacts and damage to birds would be low due to the high dilution potential of the bay. It was also noted that dispersants would be very effective in reducing impacts on wildlife and the shoreline. These results are being used to evaluate the cost-benefit analysis of removing the rocks versus the risk of an oil spill. The work demonstrates a statistically quantifiable method to estimate potential impacts that could be used in ecological risk assessment and cost-benefit analysis. 15 refs., 13 tabs., 11 figs

  7. Generation of shrimp waste-based dispersant for oil spill response.

    Science.gov (United States)

    Zhang, Kedong; Zhang, Baiyu; Song, Xing; Liu, Bo; Jing, Liang; Chen, Bing

    2018-04-01

    In this study, shrimp waste was enzymatically hydrolyzed to generate a green dispersant and the product was tested for crude oil dispersion in seawater. The hydrolysis process was first optimized based on the dispersant effectiveness (DE) of the product. The functional properties of the product were identified including stability, critical micelle concentration, and emulsification activity. Water was confirmed as a good solvent for dispersant generation when compared with three chemical solvents. The effects of salinity, mixing energy, and temperature on the dispersion of the Alaska North Slope (ANS) crude oil were examined. Microtox acute toxicity test was also conducted to evaluate the toxicity of the produced dispersant. In addition, DE of the product on three different types of crude oil, including ANS crude oil, Prudhoe Bay crude oil (PBC), and Arabian Light crude oil (ALC) was compared with that of the Corexit 9500, respectively. The research output could lead to a promising green solution to the oil spill problem and might result in many other environmental applications.

  8. Natural gas and crude oil

    International Nuclear Information System (INIS)

    Valais, M.R.

    1991-01-01

    Two main development could gradually modify these traditional features of natural gas markets and prices. First, environmental pressures and the tightening of emission standards and of the quality specifications for fuels should work in favor of natural gas. Second the increasing distance of resources in relation to the major consuming zones should bring about a considerable development of international natural gas trade. International expansion should mark the development of the gas industry in the coming decades. This evolution will give natural gas an importance and a role appreciably closer to those of oil on the world energy scene. But it is obvious that such a development can come about only at the cost of considerable investments for which the economic viability is and will remain dependent on the level of the prices of natural gas as the inlet to its consuming markets. This paper attempts to answer the questions: Will these markets accept a new scale of value for gas in relation to other fossil fuels, including oil, which will take into account new environmental constraints and which will be able to fulfill the formidable financial needs of the gas industry in the coming decades?

  9. Regional economic impact of oil spills

    International Nuclear Information System (INIS)

    Heen, K.; Andersen, M.

    1994-01-01

    An approach is demonstrated of coupling an environmental model to input-output analysis which aims to quantify the regional economic impact of an environmental accident. The model is implemented with the data of a potential oil spill interacting with the salmon aquaculture industry in Northern Norway. The production loss in salmon aquaculture and the regional income impact is computed and discussed. The approach used in this article could be a model for estimating the regional socio-economic impact of environmental factors like water and air pollution. 1 fig., 4 tabs., 19 refs

  10. Study of the sediment contamination levels in a mangrove swamp polluted by a marine oil spill

    International Nuclear Information System (INIS)

    Wong, T.W.Y.; Ke, L.; Wong, Y.S.; Tam, N.F.Y.

    2002-01-01

    The pattern of oil retention in mangrove sediments was studied in an effort to determine the temporal changes of petroleum hydrocarbon concentrations and composition several months after oil spills occur. Mangroves are inter-tidal wetlands in tropical and subtropical coastlines. Due to the anoxic and water logging characteristics of mangrove sediments, oil residues linger much longer in these wetlands compared to other coastal habitats. In November 2000, an accidental oil spill occurred in the Pearl River Estuary in which approximately 230,000 litres of crude oil was leaked from an oil tanker. The spilled oil migrated to the YiO, a typical mangrove swamp in Hong Kong Special Administrative Region. The degree of oil contamination in the sediments depended on the sediment texture and topography of the mangrove. The total petroleum hydrocarbon (TPH) concentration of the sediments in the most affected area near a freshwater creek flowing into the sea was 130 times higher than normal, one month after the accident. The mean TPH concentration was 2862 ug/g of dry sediment while the mean carbon preference index was 1.22 compared to the background value of 3.97. The temporal changes of the petroleum hydrocarbon level in 5 defined areas were examined for 7 months after the spill. The most polluted area next to the creek was determined to have very high TPH levels in the muddy sediments even 7 months after the spill. Oil residues infiltrated as deep as 20 cm into the sediments, making it more difficult to degrade than surface pollution and posing long-term adverse effects on trees in the area. It was determined that with growing industrialization and increasing demands for fuel and energy supply, mangroves in South China should be ranked as top priority for protection from oil spills. 19 refs., 6 tabs., 6 figs

  11. Study of the sediment contamination levels in a mangrove swamp polluted by a marine oil spill

    Energy Technology Data Exchange (ETDEWEB)

    Wong, T.W.Y.; Ke, L.; Wong, Y.S.; Tam, N.F.Y. [City University of Hong Kong, Hong Kong SAR (China)

    2002-07-01

    The pattern of oil retention in mangrove sediments was studied in an effort to determine the temporal changes of petroleum hydrocarbon concentrations and composition several months after oil spills occur. Mangroves are inter-tidal wetlands in tropical and subtropical coastlines. Due to the anoxic and water logging characteristics of mangrove sediments, oil residues linger much longer in these wetlands compared to other coastal habitats. In November 2000, an accidental oil spill occurred in the Pearl River Estuary in which approximately 230,000 litres of crude oil was leaked from an oil tanker. The spilled oil migrated to the YiO, a typical mangrove swamp in Hong Kong Special Administrative Region. The degree of oil contamination in the sediments depended on the sediment texture and topography of the mangrove. The total petroleum hydrocarbon (TPH) concentration of the sediments in the most affected area near a freshwater creek flowing into the sea was 130 times higher than normal, one month after the accident. The mean TPH concentration was 2862 ug/g of dry sediment while the mean carbon preference index was 1.22 compared to the background value of 3.97. The temporal changes of the petroleum hydrocarbon level in 5 defined areas were examined for 7 months after the spill. The most polluted area next to the creek was determined to have very high TPH levels in the muddy sediments even 7 months after the spill. Oil residues infiltrated as deep as 20 cm into the sediments, making it more difficult to degrade than surface pollution and posing long-term adverse effects on trees in the area. It was determined that with growing industrialization and increasing demands for fuel and energy supply, mangroves in South China should be ranked as top priority for protection from oil spills. 19 refs., 6 tabs., 6 figs.

  12. Combustive management of oil spills

    International Nuclear Information System (INIS)

    1992-01-01

    Extensive experiments with in situ incineration were performed on a desert site at the University of Arizona with very striking results. The largest incinerator, 6 feet in diameter with a 30 foot chimney, developed combustion temperatures of 3000, F, and attendant soot production approximately 1000 times less than that produced by conventional in situ burning. This soot production, in fact, is approximately 30 times less than current allowable EPA standards for incinerators and internal combustion engines. Furthermore, as a consequence of the high temperature combustion, the bum rate was established at a very high 3400 gallons per hour for this particular 6 foot diameter structure. The rudimentary design studies we have carried out relative to a seagoing 8 foot diameter incinerator have predicted that a continuous burn rate of 7000 gallons per hour is realistic. This structure was taken as a basis for operational design because it is compatible with C130 flyability, and will be inexpensive enough ($120,000 per copy) to be stored at those seaside depots throughout the US coast line in which the requisite ancillary equipments (booms, service tugs, etc.) are already deployed. The LOX experiments verified our expectations with respect to combustion of debris and various highly weathered or emulsified oils. We have concluded, however, that the use of liquid oxygen in actual beach clean up is not promising because the very high temperatures associated with this combustion are almost certain to produce environmentally deleterious effects on the beach surface and its immediately sublying structures. However, the use of liquid oxygen augmentation for shore based and flyable incinerators may still play an important role in handing the problem of accumulated debris

  13. Wax deposition in crude oil pipelines

    Energy Technology Data Exchange (ETDEWEB)

    Assuncao, Pablo Morelato; Rodrigues, Lorennzo Marrochi Nolding [Universidade Federal do Espirito Santo, Sao Mateus, ES (Brazil). Centro Universitario Norte do Espirito Santo. Engenharia de Petroleo; Romero, Mao Ilich [University of Wyoming, Laramie, WY (United States). Enhanced Oil Recovery Institute], e-mail: mromerov@uwyo.edu

    2010-07-01

    Crude oil is a complex mixture of hydrocarbons which consists of aromatics, paraffins, naphthenics, resins asphaltenes, etc. When the temperature of crude oil is reduced, the heavy components, like paraffin, will precipitate and deposit on the pipe internal wall in the form of a wax-oil gel. The gel deposit consists of wax crystals that trap some amount of oil. As the temperature gets cooler, more wax will precipitate and the thickness of the wax gel will increase, causing gradual solidification of the crude and eventually the oil stop moving inside the offshore pipeline. Crude oil may not be able to be re-mobilized during re-startup. The effective diameter will be reduced with wax deposition, resulting in several problems, for example, higher pressure drop which means additional pumping energy costs, poor oil quality, use of chemical components like precipitation inhibitors or flowing facilitators, equipment failure, risk of leakage, clogging of the ducts and process equipment. Wax deposition problems can become so sever that the whole pipeline can be completely blocked. It would cost millions of dollars to remediate an offshore pipeline that is blocked by wax. Wax solubility decreases drastically with decreasing temperature. At low temperatures, as encountered in deep water production, is easy to wax precipitate. The highest temperature below which the paraffins begins to precipitate as wax crystals is defined as wax appearance temperature (WAT). Deposition process is a complex free surface problem involving thermodynamics, fluid dynamics, mass and heat transfer. In this work, a numerical analysis of wax deposition by molecular diffusion and shear dispersion mechanisms in crude oil pipeline is studied. Diffusion flux of wax toward the wall is estimated by Fick's law of diffusion, in similar way the shear dispersion; wax concentration gradient at the solid-liquid interface is obtained by the volume fraction conservation equation; and since the wax deposition

  14. Unconventional oil and gas spills: Materials, volumes, and risks to surface waters in four states of the U.S.

    Science.gov (United States)

    Maloney, Kelly O; Baruch-Mordo, Sharon; Patterson, Lauren A; Nicot, Jean-Philippe; Entrekin, Sally A; Fargione, Joseph E; Kiesecker, Joseph M; Konschnik, Kate E; Ryan, Joseph N; Trainor, Anne M; Saiers, James E; Wiseman, Hannah J

    2017-03-01

    Extraction of oil and gas from unconventional sources, such as shale, has dramatically increased over the past ten years, raising the potential for spills or releases of chemicals, waste materials, and oil and gas. We analyzed spill data associated with unconventional wells from Colorado, New Mexico, North Dakota and Pennsylvania from 2005 to 2014, where we defined unconventional wells as horizontally drilled into an unconventional formation. We identified materials spilled by state and for each material we summarized frequency, volumes and spill rates. We evaluated the environmental risk of spills by calculating distance to the nearest stream and compared these distances to existing setback regulations. Finally, we summarized relative importance to drinking water in watersheds where spills occurred. Across all four states, we identified 21,300 unconventional wells and 6622 reported spills. The number of horizontal well bores increased sharply beginning in the late 2000s; spill rates also increased for all states except PA where the rate initially increased, reached a maximum in 2009 and then decreased. Wastewater, crude oil, drilling waste, and hydraulic fracturing fluid were the materials most often spilled; spilled volumes of these materials largely ranged from 100 to 10,000L. Across all states, the average distance of spills to a stream was highest in New Mexico (1379m), followed by Colorado (747m), North Dakota (598m) and then Pennsylvania (268m), and 7.0, 13.3, and 20.4% of spills occurred within existing surface water setback regulations of 30.5, 61.0, and 91.4m, respectively. Pennsylvania spills occurred in watersheds with a higher relative importance to drinking water than the other three states. Results from this study can inform risk assessments by providing improved input parameters on volume and rates of materials spilled, and guide regulations and the management policy of spills. Published by Elsevier B.V.

  15. The Effect of Oil Spills on Marine Microbes: The Importance of Where, When, and How

    Science.gov (United States)

    Brock, M. L.; Ederington-Hagy, M.; Richardson, R. L.; Snyder, R.; Jeffrey, W. H.

    2016-02-01

    While much recent attention has been paid to the Deepwater Horizon oil spill in the Gulf of Mexico and biodegradation by microbial communities, it is important to remember that numerous factors may determine the types of environmental effects that may result from oil spills. Not all oil spills (e.g., crude, refined, weathered, fuels, use of dispersants) are created equal, and it is likely that the characteristics of different environments will affect ecosystem response to oil. Temperature, salinity, and solar radiation are three potentially important factors related to location and seasonality. The effects of some of these environmental factors on the formation of Water Accommodated Fractions (WAFs) developed from Deepwater Horizon oils and the subsequent effects on microbial growth is being investigated. WAFs were generated under varying solar but controlled temperature conditions, various temperatures and salinities, as well as from burned and weathered oil. After all WAFs were collected, each was added to a coastal seawater sample and their effects on bacterial production or phytoplankton photosynthesis determined. Results from both assays demonstrated that WAFs produced in the dark had minimal effects on growth while inhibition was proportional to the amount of solar exposure. Burning oil prior to formation of WAFs increased inhibition of production independent of subsequent solar treatment. Preliminary data suggests that temperature plays a minimal role. The results imply that the ecological effects caused by oil spills are very light dependent and thus could vary by season, location, and may occur to significant depths in the ocean.

  16. Acute health effects of the Sea Empress oil spill.

    Science.gov (United States)

    Lyons, R A; Temple, J M; Evans, D; Fone, D L; Palmer, S R

    1999-05-01

    To investigate whether residents in the vicinity of the Sea Empress tanker spill suffered an increase in self reported physical and psychological symptoms, which might be attributable to exposure to crude oil. Retrospective cohort study; postal questionnaire including demographic details, a symptom checklist, beliefs about health effects of oil and the Hospital Anxiety and Depression and SF-36 mental health scales. Populations living in four coastal towns on the exposed south Pembrokeshire coast and two control towns on the unexposed north coast. 539 exposed and 550 unexposed people sampled at random from the family health services authority age-sex register who completed questionnaires. Adjusted odds ratios for self reported physical symptoms; scores on the Hospital Anxiety and Depression and SF-36 mental health scales, in 1089 people who responded out of a possible 1585 (69%). Living in areas exposed to the crude oil spillage was significantly associated with higher anxiety and depression scores, worse mental health; and self reported headache (odds ratio = 2.35, 95% CI 1.56, 3.55), sore eyes (odds ratio = 1.96, 95% CI 1.06, 3.62), and sore throat (odds ratio = 1.70, 95% CI 1.12, 2.60) after adjusting for age, sex, smoking status, anxiety, and the belief that oil had affected health. People living in exposed areas reported higher rates of physical and psychological symptoms than control areas. Symptoms significantly associated with exposure after adjustment for anxiety and health beliefs were those expected from the known toxicological effect of oil, suggesting a direct health effect on the exposed population.

  17. How much crude oil can zooplankton ingest? Estimating the quantity of dispersed crude oil defecated by planktonic copepods

    DEFF Research Database (Denmark)

    Almeda, Rodrigo; Connelly, Tara L.; Buskey, Edward J.

    2016-01-01

    % of the analyzed fecal pellets from three species of copepods and a natural copepod assemblage exposed for 48 h to physically or chemically dispersed light crude oil contained crude oil droplets. Crude oil droplets inside fecal pellets were smaller (median diameter: 2.4-3.5 mu m) than droplets in the physically...

  18. Australia's tyranny of distance in oil spill response

    International Nuclear Information System (INIS)

    Lipscombe, Ray

    2000-01-01

    In view of the quantity of oil spilled, smaller spills generally receive less attention than headline grabbing incidents such as the 'Amoco Cadiz', 'Exxon Valdez', 'Braer' and 'Sea Empress'. The latter incidents involve the loss of significant quantities of oil, the establishment of relatively complex spill response management structures and the involvement of significant numbers of personnel and equipment. As such, large spills from tankers have the potential to create problem areas, for example in establishing and maintaining effective communications, logistics and resource management systems. In general terms spill response personnel are well aware that large spills come complete with significant operational and administrative problems, however what may not be so well recognised is that smaller spills also have the potential to present response personnel with their own unique problems. One of the major problems to be overcome when responding to spills in Australia is the 'tyranny of distance'. In quite a few responses, Australian oil spill response managers have had to move personnel and equipment thousands of kilometres to provide an effective outcome. This paper outlines a range of problems that have been encountered by Australian personnel over the years. These include health and safety, communications, logistics and equipment issues. For the purpose of this paper a 'smaller' spill has been defined as one involving a discharge of less than 1000 tonnes of oil. (Author)

  19. Washington's marine oil spill compensation schedule - simplified resource damage assessment

    International Nuclear Information System (INIS)

    Geselbracht, L.; Logan, R.

    1993-01-01

    The Washington State Preassessment Screening and Oil Spill Compensation Schedule Rule (Chapter 173-183 Washington Administrative Code), which simplifies natural resource damage assessment for many oil spill cases, became effective in May 1992. The approach described in the rule incorporates a number of preconstructed rankings that rate environmental sensitivity and the propensity of spilled oil to cause environmental harm. The rule also provides guidance regarding how damages calculated under the schedule should be reduced to take into account actions taken by the responsible party that reduce environmental injury. To apply the compensation schedule to marine estuarine spills, the resource trustees need only collect a limited amount of information such as type of product spilled, number of gallons spilled, compensation schedule subregions the spill entered, season of greatest spill impact, percent coverage of habitats affected by the spill, and actions taken by the responsible party. The result of adding a simplified tool to the existing assortment of damage assessment approaches is that resource trustees will now be able to assess damages for most oil spill cases and shift more effort than was possible in the past to resource restoration

  20. Implication of Human Hair in Regaining Spilled Oil Further Creating A Production Rise in Oyster Mushrooms

    Science.gov (United States)

    Pandey, A.; Srivastava, P.; Singh, U.

    2016-12-01

    It is estimated that 4.9 million liters of petroleum are spilled into U.S. waters from vessels and pipelines in a typical year. Oil spill may be as huge as of 8 million barrels (The Persian Gulf oil spill of 1991). Oil-water separation processes using polymeric or inorganic membranes have been proposed as effective and cost competitive technologies but in present the commercial use of membrane in treatment of spilled oil is currently limited by their low efficiency as well as high capital and operating cost. Indian hair-market is a billion-dollar industry yearly exporting thousands of tones of thick and dark hairs. Hairs contain keratin, a family of fibrous structural proteins been proved to adsorb oils. Laboratory results conclude that one gram of human hair can selectively adsorb about 15.5301 grams of crude oil over water, following Frendlich's isotherm. We seek hair mats made up of hairs of size ≤5 inches, costing 37/ton from selected parts of Indian hair market. With a known adsorbing efficiency of 95% towards crude oil, an estimated desorption efficiency of 70% oil worth 0.8M per year can be regained in crude form from U.S. waters only. To ensure solid waste management of hairs, hair mats left with 30% of adsorbed oil can be utilized in the cultivation of oyster mushrooms, a 20-34/kg crop that grows best in 20-25°C ,80-90% relative humidity and oily conditions. This will reduce the growing period of crop ensuring yearly profit of $6.06M in U.S. only engaging variety of stakeholders over borders. Results thus obtained in this study present an economic, safer and sustainable technique to minimize oil loss due to oil spill in waters further ensuring a low labor-low cost technique of waste management that enhances the growth of an in-demand crop. Keywords: Oil Spill, Human Hair Mats, Adsorb, Oyster Mushrooms

  1. California Conservation Corps trains youth to safely clean up oil spills

    International Nuclear Information System (INIS)

    Penn, P.

    1993-01-01

    Initiated in response to environmentally destructive crude oil spills, the California Conservation Corps (CCC) is trained to respond anywhere in California, and beyond. Corpsmembers are provided 32 hours of training to exceed both State and Federal Occupational Health and Safety Administration (OSHA) requirements for worker safety. The CCC responded to the Huntington Beach spill in 1990 and impressed both the private sector and government agencies with the high quality of work performed, the organization and discipline of the responders and the safe manner in which they approached the sensitive environmental cleanup. The program was begun with a $75,000 grant from BP America (British Petroleum), the owner of the oil in the American Trader incident. Following the passage of comprehensive oil spill legislation in California, the California Department of Fish and Game Office of Oil Spill Prevention and Response (OSPR) contracted with the CCC to provide 200 trained oil spill workers for beach cleanup. Subsequently, the Corps has responded along the California coast to a pipeline break at Avila Beach in San Luis Obispo County and cleaned up tar balls in the Monterey area

  2. Where the oil from surface and subsurface plumes deposited during/after Deepwater Horizon oil spill?

    Science.gov (United States)

    Yan, B.

    2016-02-01

    The Deepwater Horizon (DwH) oil spill released an estimated 4.9 million barrels (about 200 million gallons) of crude oil into the Gulf of Mexico between April 20, 2010 and July 15, 2010. Though Valentine et al. has linked the elevated oil components in some sediments with the subsurface plume, the sites with fallout from the ocean surface plume has not been identified. This piece of information is critical not only for a comprehensive scientific understanding of the ecosystem response and fate of spill-related pollutants, but also for litigation purposes and future spill response and restoration planning. In this study we focus on testing the hypothesis that marine snow from the surface plume were deposited on the sea floor over a broad area. To do so, we use publicly available data generated as part of the ongoing Natural Resource Damage Assessment (NRDA) process to assess the spatial distribution of petroleum hydrocarbons in the water column and deep-ocean sediments of the Gulf of Mexico. Sensitive hydrocarbon markers are used to differentiate hydrocarbons from surface plume, deep subsurface plume, and in-situ burning. Preliminary results suggest the overlapping but different falling sites of these plumes and the sedimentation process was controlled by various biological, chemical, and physical factors.

  3. Oil Characterization and Distribution in Florida Estuary Sediments Following the Deepwater Horizon Spill

    Directory of Open Access Journals (Sweden)

    Mace G. Barron

    2015-09-01

    Full Text Available Barrier islands of Northwest Florida were heavily oiled during the Deepwater Horizon spill, but less is known about the impacts to the shorelines of the associated estuaries. Shoreline sediment oiling was investigated at 18 sites within the Pensacola Bay, Florida system prior to impact, during peak oiling, and post-wellhead capping. Only two locations closest to the Gulf of Mexico had elevated levels of total petroleum hydrocarbons (TPH and total polycyclic aromatic hydrocarbons (PAHs. These samples showed a clear weathered crude oil signature, pattern of depletion of C9 to C19 alkanes and C0 to C4 naphthalenes, and geochemical biomarker ratios in concordance with weathered Macondo crude oil. All other locations and sample times showed only trace petroleum contamination. The results of this study are consistent with available satellite imagery and visual shoreline survey data showing heavy shoreline oiling limited to sandy beaches near the entrance to Pensacola Bay and shorelines of Santa Rosa Island.

  4. Crude oil prices: Speculation versus fundamentals

    Science.gov (United States)

    Kolodziej, Marek Krzysztof

    Beginning in 2004, the price of crude oil fluctuates rapidly over a wide range. Large and rapid price increases have recessionary consequences and dampen long-term infrastructural investment. I investigate whether price changes are driven by market fundamentals or speculation. With regard to market fundamentals, I revisit econometric evidence for the importance of demand shocks, as proxied by dry maritime cargo rates, on oil prices. When I eliminate transportation costs from both sides of the equation, disaggregate OPEC and non-OPEC production, and allow for more than one cointegrating relation, I find that previous specifications are inconsistent with arguments that demand shocks play an important role. Instead, results confirm the importance of OPEC supply shocks. I investigate two channels by which speculation may affect oil prices; the direct effect of trader behavior and changes in oil from a commodity to a financial asset. With regard to trader behavior, I find evidence that trader positions are required to explain the spread between spot and futures prices of crude oil on the New York Mercantile Exchange. The inclusion of trader positions clarifies the process of equilibrium error correction, such that there is bidirectional causality between prices and trader positions. This creates the possibility of speculative bubbles. With regard to oil as a commodity and/or financial asset, I use a Kalman Filter model to estimate the time-varying partial correlation between returns to investments in equity and oil markets. This correlation changes from negative to positive at the onset of the 2008 financial crisis. The low interest rates used to rescue the economy depress convenience yields, which reduces the benefits of holding oil as a commodity. Instead, oil becomes a financial asset (on net) as the oil market changed from contango to backwardation. Contradicting simple political narratives, my research suggests that both market fundamentals and speculation drive

  5. Spill-of-opportunity testing of dispersant effectiveness at the Mega Borg oil spill

    International Nuclear Information System (INIS)

    Payne, J.R.; Martrano, R.J.; Reilly, T.J.; Lindblom, G.P.; Kennicutt, M.C. II; Brooks, J.M.

    1993-01-01

    The release of 3.9 million gallons of Angola Planca crude oil from the stricken tanker Mega Borg 57 miles offshore of Galveston, Texas in June 1990 provided a valuable opportunity to document dispersant effectiveness under field conditions. Aerial application of Corexit 9527 (968 gallons total in four adjacent passes) onto an identified test portion of the slick was evaluated by concurrent observations from a command-and-control aircraft and surface vessels (with videotape and 35-mm photographic documentation) and ground truth measurements, including continuous 4-meter-depth ultraviolet/fluorescence and a discrete water sampling program. Using the study plan outlined by Payne and colleagues, target and control areas were designated before dispersant application by deployment of smoke bombs and coded three-meter drogues. Postdispersant surface vessel placement and 30 liter water sampling activities from the Texas A ampersand M research vessel HOS Citation were aided by the smoke bombs, the free-drifting drogues, and directions from the command-and-control aircraft. Subsequent FID GC and GC/MS analyses of water sample extracts allowed quantitation of the dispersed oil concentrations under both treated and control areas. Although the spilled oil was extremely light (API gravity 39.0) and subject to significant natural dispersion, the field observations, filmed documentation, and water column data clearly demonstrated an increase in dispersed oil concentrations beneath the treated slick. The distribution of dispersed oil droplets was very heterogeneous and reflected the patchy distribution of oil on the water surface before dispersant application. Maximum concentrations of dispersed hydrocarbons in the center of the treated zone were 22,000 μg/L (22 ppm) for total aliphatic and 5.6 μg/L (5.6 ppb) for total aromatics 60 to 90 minutes after dispersant application. Elevated levels were generally limited to the upper 1 to 3 meters of the water column

  6. Long-term recovery of peat bogs oiled by pipeline spills in northern Alberta

    International Nuclear Information System (INIS)

    Blenkinsopp, S.; Sergy, G.

    1996-01-01

    Sites in northern Alberta, in which oil spills occurred more than 23 years ago, were revisited. The Nipisi spill occurred when a rupture in the underground oil pipeline leaked 60,000 barrels of crude into a 25 acre bog, with very little drainage. It was one of the largest spills in Canadian history. The Rainbow spill was into a fen that was draining by subsurface seepage. Treatments at the time included burning, tilling, and fertilizer addition. The sites were revisited in order to take samples and to evaluate both the natural and enhanced recovery and the effectiveness of the cleanup techniques. The long-term persistence of oil residues and changes in oil character resulting from weathering and biodegradation over time, were studied. Results showed that samples of oil residue and vegetation were still highly contaminated with oil which was heavily degraded. Subsurface samples were contaminated but the oil was only slightly degraded. The Nipisi site still had large areas devoid of vegetation. The unique drainage of peat bogs and the influence it has on rehabilitation was described. It was concluded that although the sites are recovering, they are doing so at a very slow pace and will require some more time to be complete. 12 refs., 4 tabs., 9 figs

  7. Computational model for the assessment of oil spill damages

    Energy Technology Data Exchange (ETDEWEB)

    Seip, K L; Heiberg, A B; Brekke, K A

    1985-06-01

    A description is given of the method and the required data of a model for calculating oil spill damages. Eleven damage attributes are defined: shorelength contaminated, shore restitution time, birds dead, restitution time for three groups of birds, open sea damages-two types, damages to recreation, economy and fisheries. The model has been applied in several cases of oil pollution assessments: in an examination of alternative models for the organization of oil spill combat in Norway, in the assessment of the damages coused by a blowout at Tromsoeflaket and in assessing a possible increase in oil spill preparedness for Svalbard. 56 references.

  8. The breakup of oil spills in the marine environment

    International Nuclear Information System (INIS)

    Zeidan, E.; Zahariev, K.; Li, M.; Garrett, C.

    1997-01-01

    Existing theories of oil slick disintegration under stormy conditions were examined. A novel empirical model suitable for use in oil spill models was developed in an effort to demonstrate the many difficulties encountered in modeling the emulsification process. Chief among the difficulties is the prediction of the onset and extent of oil spill emulsification. The empirical model was described in some detail using surface active constituents and energy available from wind and waves as the controlling parameters. The resulting chart, if used in the marine environment, can predict localized emulsification and a more realistic behaviour of oil spills. 43 refs., 6 figs

  9. Release of surfactant cargo from interfacially-active halloysite clay nanotubes for oil spill remediation.

    Science.gov (United States)

    Owoseni, Olasehinde; Nyankson, Emmanuel; Zhang, Yueheng; Adams, Samantha J; He, Jibao; McPherson, Gary L; Bose, Arijit; Gupta, Ram B; John, Vijay T

    2014-11-18

    Naturally occurring halloysite clay nanotubes are effective in stabilizing oil-in-water emulsions and can serve as interfacially-active vehicles for delivering oil spill treating agents. Halloysite nanotubes adsorb at the oil-water interface and stabilize oil-in-water emulsions that are stable for months. Cryo-scanning electron microscopy (Cryo-SEM) imaging of the oil-in-water emulsions shows that these nanotubes assemble in a side-on orientation at the oil-water interface and form networks on the interface through end-to-end linkages. For application in the treatment of marine oil spills, halloysite nanotubes were successfully loaded with surfactants and utilized as an interfacially-active vehicle for the delivery of surfactant cargo. The adsorption of surfactant molecules at the interface serves to lower the interfacial tension while the adsorption of particles provides a steric barrier to drop coalescence. Pendant drop tensiometry was used to characterize the dynamic reduction in interfacial tension resulting from the release of dioctyl sulfosuccinate sodium salt (DOSS) from halloysite nanotubes. At appropriate surfactant compositions and loadings in halloysite nanotubes, the crude oil-saline water interfacial tension is effectively lowered to levels appropriate for the dispersion of oil. This work indicates a novel concept of integrating particle stabilization of emulsions together with the release of chemical surfactants from the particles for the development of an alternative, cheaper, and environmentally-benign technology for oil spill remediation.

  10. Emissions of polycyclic aromatic hydrocarbons from the combustion of crude oil on water

    International Nuclear Information System (INIS)

    Benner, B.A. Jr.; Bryner, N. P.; Wise, S.A.; Mulholland, G.W.; Evans, D.D.; Fingas, M.F.; Li, K.

    1991-01-01

    A study was conducted to examine some of the factors necessary to assess the environmental impact of an in-situ burn of an oil spill on water. These factors include the fraction of an oil layer which can be burned, the quantity of smoke emitted, and the concentrations of 18 polycyclic aromatic hydrocarbons (PAHs) in the smoke, crude oil, and burn residue. Alberta sweet mixed blend crude in 1, 3, 5, 10, and 30 mm layers on water was burned in the laboratory and smoke samples were collected at elevated and ambient temperatures and analyzed by two independent laboratories. While burning the crude oil produced less total PAHs than was in the original crude, the concentrations of PAHs with 5 or more rings were 10-20 times greater in the smoke than in the oil. The organic carbon fraction of the smoke was in the 14-21% range. As the fuel layer thickness was increased from 2 to 10 mm, the smoke yield increased from 0.035 g smoke/g fuel and the percentage of oil residue decreased from 46% to 17%. By consuming much of the oil spill and reducing the amount of PAHs in the water, and by dispersing the combustion products over a larger area, in-situ burning can mitigate the local environmental impact of an oil spill. There appears to be a range of situations, such as in Arctic ice fields, where in-situ burning might be the most viable cleanup method. 25 refs., 6 figs., 6 tabs

  11. Developing effective environmental and oil spill management for remote locations

    International Nuclear Information System (INIS)

    Smith, J.P.; Wardrop, J.; Kilborn, A.

    1994-01-01

    Historically, Exploration and Production (E and P) operators' environmental philosophy was a consequence of environmental damages, actual and perceived, caused by hydrocarbon spills. Pertamina/Maxus Southeast Sumatra, Inc. (Maxus), the largest offshore E and P operator in Indonesia has adopted a proactive philosophy as they operate offshore production and shipping facilities immediately adjacent to the Pulau Seribu (Thousand Island) National Marine Park and approximately 30 kilometers from the Southeast Sumatra coast. These ecosystems are of great concern to Indonesia and Maxus as they comprise approximately 250 km of tropical, sparsely inhabited coastline, 106 coral and lagoon islands, and habitats for numerous endangered species. This paper describes the contract zone within which Maxus operates; the environmental risks associated with E and P in this region; and Maxus' response to management of those risks. A significant component of Maxus' overall response has been the ESACOC project (Environmental Sensitivity and Characterization of Crude) undertaken during 1993. ESACOC is described here in regard to the use and interrelation of remote sensing, in-depth laboratory studies, and development of new sensitivity rankings techniques into one computer program for effective environmental and oil spill management. ESACOC illustrates the synthesis of seemingly diverse and unrelated data to develop an effective environmental management plan

  12. Pilot scale refinning of crude soybean oil | Mensah | Journal of ...

    African Journals Online (AJOL)

    Pilot scale refinning of crude soybean oil. ... Abstract. A laboratory process for refining soybean has been scaled up to a 145 tonne per annum pilot plant to refine crude soybean oil. ... The quality of the refined oil was found to be within national and codex standard specifications for edible oil from vegetable sources.

  13. Oil mixing behavior after an oil spill: identification conflicts of different fingerprints.

    Science.gov (United States)

    He, Shijie; Yu, Hongjun; Luo, Yongming; Wang, Chuanyuan; Li, Xueshuang; Li, Zhongping

    2018-04-01

    Clearing up whether spilled oil is mixed or not can strengthen the accuracy of oil spill identification. In the present study, the biomarkers in spilled oil samples were detected. The weathering modes of different types of diagnostic ratio and carbon isotope values of individual n-alkanes were also analyzed. The results showed that the diagnostic ratios of steroids, terpenes and aromatics, and weathering characteristics of carbon isotope composition (δ 13 C) of individual n-alkanes supported the idea that Dalian oil spill emerged from a single oil source. Furthermore, commonly used diagnostic ratios of n-alkanes indicated that the Dalian oil spill had undergone the oil mixing process. The different identifying outcomes indicate that some kinds of n-alkane-rich substance (such as oil dispersants) were mixed in the Dalian spilled oil and interfered with the routine diagnosis ratios of n-alkanes.

  14. Oil spills: Is the perception worse than the reality?

    International Nuclear Information System (INIS)

    Mielke, J.E.

    1991-01-01

    Most people form their perceptions of oil spills from television pictures immediately after the spill occurs. But the real environmental impact of the spill will not be felt until later, long after the TV crews have left and public attention has focused elsewhere. And the good news, says Mielke, is that the long-term damages may be less than initially perceived. Nature operates a very effective cleaning service. The perceived impact of an oil spill may be only vaguely related to what ultimately happens to the oil or to the oils interaction with the affected area, Mielke says. This was the case with two large spills in the 1970s - the Arco Merchant spill off Massachusetts in 1976 and the Amoco Cadiz spill off Brittany, France, in 1978. And it may be the case with the Exxon Valdez spill in Prince William Sound in Alaska in the spring of 1989, he adds. Human efforts to clean up the spills are less effective than nature's own processes, he says, and, in some cases, can actually delay the natural ecological restoration. This raises the question of whether the cost to society of massive physical clean-up efforts is equal to the social and environmental benefit

  15. Satellite observations of oil spills in Bohai Sea

    International Nuclear Information System (INIS)

    Wei, Y L; Tang, Z Y; Li, X F

    2014-01-01

    Several oil spills occurred at two oil platforms in Bohai Sea, China on June 4 and 17, 2011. The oil spills were subsequently imaged by different types of satellite sensors including SAR (Synthetic Aperture Radar), Chinese HJ-1-B CCD and NOAA MODIS. In order to detect the oil spills more accurately, images of the former three sensors were used in this study. Oil spills were detected using the semi-supervised Texture-Classifying Neural Network Algorithm (TCNNA) in SAR images and gradient edge detection algorithm in HJ-1-B and MODIS images. The results show that, on June 11, the area of oil slicks is 31 km 2 and they are observed in the vicinity and to the north of the oilfield in SAR image. The coverage of the oil spill expands dramatically to 244 km 2 due to the newly released oil after June 11 in SAR image of June 14. The results on June 19 show that under a cloud-free condition, CCD and MODIS images capture the oil spills clearly while TCNNA cannot separate them from the background surface, which implies that the optical images play an important role in oil detection besides SAR images

  16. Studies on marine oil spills and their ecological damage

    Science.gov (United States)

    Mei, Hong; Yin, Yanjie

    2009-09-01

    The sources of marine oil spills are mainly from accidents of marine oil tankers or freighters, marine oil-drilling platforms, marine oil pipelines, marine oilfields, terrestrial pollution, oil-bearing atmosphere, and offshore oil production equipment. It is concluded upon analysis that there are two main reasons for marine oil spills: (I) The motive for huge economic benefits of oil industry owners and oil shipping agents far surpasses their sense of ecological risks. (II) Marine ecological safety has not become the main concern of national security. Oil spills are disasters because humans spare no efforts to get economic benefits from oil. The present paper draws another conclusion that marine ecological damage caused by oil spills can be roughly divided into two categories: damage to marine resource value (direct value) and damage to marine ecosystem service value (indirect value). Marine oil spills cause damage to marine biological, fishery, seawater, tourism and mineral resources to various extents, which contributes to the lower quality and value of marine resources.

  17. Electrical desalting - preparing of the crude oil for further processing

    International Nuclear Information System (INIS)

    Asadi, Nadija; Minovski, Mino; Sokolovski, Aleksandar

    1999-01-01

    Desalting as well as dewatering of the crude oil is important preparing process, which takes place in crude units on the refinery plants. One of the most efficient ways of desalting is use of high voltage electricity. In this work attention is paid on the principals of this process, illustrated with practically gained results from the OKTA Crude Oil Refinery in Macedonia. (Original)

  18. Use of geochemical biomarkers in bottom sediment to track oil from a spill, San Francisco Bay, California

    Science.gov (United States)

    Hostettler, F.D.; Rapp, J.B.; Kvenvolden, K.A.

    1992-01-01

    In April 1988, approximately 1500 m3 of a San Joaquin Valley crude oil were accidentally released from a Shell Oil Co. refinery near Martinez, Californa. The oil flowed into Carquinez Strait and Suisun Bay in northern San Francisco Bay Sediment and oil samples were collected within a week and analysed for geochemical marker compounds in order to track the molecular signature of the oil spill in the bottom sediment. Identification of the spilled oil in the sediment was complicated by the degraded nature of the oil and the similarity of the remaining, chromatographically resolvable constituents to those already present in the sediments from anthropogenic petroleum contamination, pyrogenic sources, and urban drainage. Ratios of hopane and sterane biomarkers, and of polycyclic aromatic hydrocarbons and their alkylated derivatives best identified the oil impingement. They showed the oil impact at this early stage to be surficial only, and to be patchy even within an area of heavy oil exposure.

  19. Comparison of Ecological Impacts of Postulated Oil Spills at Selected Alaskan Locations. Volume 2, Results

    Science.gov (United States)

    1975-06-01

    DISCUSSION TaMe 2-22 presents the results of the oil spill scenarios examined at St. Matthew Island without cleanup. 2-485 DIESEL-2 CRUDE BUNKER...include red fox, Arctic ground squirrel, lemmings, shrews , and voles. The Arctic fox, an inhabitant of both the terrestrial area and the pack ice, is... the time you ordered this report— which is only one of the hundreds of thou- sands in the NTIS information collection avail- able to you—and the

  20. Environmental Impacts and Recovery After the Hebei Spirit Oil Spill in Korea.

    Science.gov (United States)

    Yim, U H; Khim, J S; Kim, M; Jung, J-H; Shim, W J

    2017-07-01

    The Hebei Spirit oil spill (HSOS) on December 7, 2007 was the worst oil spill recorded in Korea, with the release of approximately 10,900 tons of crude oil and 375 km of coastline polluted along the west coast of Korea. Cleanup operation was conducted by official and contract responders as well as volunteers for massive oil containment and removal of heavy accumulations of stranded oil. Together with the oil cleanup, a long-term environmental impact assessment (EIA) of the HSOS was initiated based on the Marine Environmental Management Act, which covers oil contamination in a multimedia environment, toxic effects on organisms, and ecosystem injury. This review summarizes the long-term monitoring results of HSOS EIA focused on (1) pollution status of seawater, sediment, and bivalves, (2) ecotoxicological effects, and (3) ecosystem recovery. Overall, concentrations of petroleum hydrocarbons in the environment indicated that their concentrations were well down to at or near background or pre-spill contamination levels at most sites after 1 year. The potential toxic effects of residual oils in sediments have decreased to background levels in most coastal areas of Taean. The entire ecosystem in the most affected area of the Taean coasts appear to be considerably, but not fully, recovered at present, namely after 8 years of the HSOS. The presence of lingering oil and elevated contamination levels at several sites still require continuous long-term monitoring.

  1. Site Selection and Resource Allocation of Oil Spill Emergency Base for Offshore Oil Facilities

    Science.gov (United States)

    Li, Yunbin; Liu, Jingxian; Wei, Lei; Wu, Weihuang

    2018-02-01

    Based on the analysis of the historical data about oil spill accidents in the Bohai Sea, this paper discretizes oil spilled source into a limited number of spill points. According to the probability of oil spill risk, the demand for salvage forces at each oil spill point is evaluated. Aiming at the specific location of the rescue base around the Bohai Sea, a cost-benefit analysis is conducted to determine the total cost of disasters for each rescue base. Based on the relationship between the oil spill point and the rescue site, a multi-objective optimization location model for the oil spill rescue base in the Bohai Sea region is established. And the genetic algorithm is used to solve the optimization problem, and determine the emergency rescue base optimization program and emergency resources allocation ratio.

  2. Subordinated Levy Processes and Applications to Crude Oil Options

    OpenAIRE

    Noureddine Krichene

    2005-01-01

    One approach to oil markets is to treat oil as an asset, besides its role as a commodity. Speculative and nonspeculative activity by investors in the derivatives markets could be responsible for a sizable increase in oil prices. This paper recognizes both the consumption and investment aspects of crude oil and proposes Levy processes for modeling uncertainty and options pricing. Calibration to crude oil futures' options shows high volatility of oil futures prices, fat-tailed, and right-skewed...

  3. Managing public support during oil spills

    International Nuclear Information System (INIS)

    Zuidinga, K.; Boston, N.; Robertson, I.

    1990-01-01

    Too often oil spill contingency plans ignore and responders overlook the problem of managing auxiliary support, that is volunteers. These may consists of Native Bands, environmental organizations, community groups and the public in general. The consequences of not managing or poorly managing public support for the response effort is an increasingly frustrated public which begins to coordinate their own response efforts, proceeding without training or supervision. such a response can pose a threat to individuals as well as to the clean-up effort in general. Preparation and effective communication, particularly with the news media are key elements in successfully managing public support. In this paper the issues to be addressed are: coordination (mobilization, assignments), safety and insurance, equipment and clothing, fatigue and stress, food and shelter, training, public information including information about potential hazards, and public expectations of response efficiency

  4. Removing Spilled Oil With Liquid Nitrogen

    Science.gov (United States)

    Snow, Daniel B.

    1991-01-01

    Technique proposed to reduce more quickly, contain, clean up, and remove petroleum products and such other pollutants as raw sewage and chemicals without damage to humans, animals, plants, or the environment. Unique and primary aspect of new technique is use of cryogenic fluid to solidify spill so it can be carried away in solid chunks. Liquid nitrogen (LN2), with boiling point at -320 degrees F (-196 degrees C), offers probably best tradeoff among extreme cold, cost, availability, and lack of impact on environment among various cryogenic fluids available. Other applications include extinguishing fires at such locations as oil derricks or platforms and at tank farms containing such petroleum products as gasoline, diesel fuel, and kerosene.

  5. Oysters as biomonitors of the apex barge oil spill

    International Nuclear Information System (INIS)

    Wade, T.L.; Jackson, T.J.; McDonald, T.J.; Wilkinson, D.L.; Brooks, J.M.

    1993-01-01

    The collision of the Greek tanker ship Shinoussa resulted in a spill of an estimated 692,000 gallons of catalytic feed stock oil into Galveston Bay on July 28, 1990. Oysters were collected from Galveston Bay Todds Dump (GBTD) 235 days previous to the spill and 6, 37, 132, and 495 days after the spill. Oysters were also collected from Galveston Bay Redfish Island (GBRI), a site known to be impacted by the spill, 37 and 110 days after the spill. The concentration of the 24 polynuclear aromatic hydrocarbons (PAH) measured for the National Oceanic and Atmospheric Administration's national status and trends program (NS ampersand T) site showed a sharp increase from about 100 ng/g to over 600 ng/g one week after the spill compared to concentrations 235 days previous to the spill. The concentration of the 24 NS ampersand T PAH in oysters from GBRI ranges from 400 to over 1000 ng/g. Soon after the spill the concentration of the 24 NS ampersand T PAH at Todds Dump decreased to levels not statistically different from prespill samples. However, analyses of alkylated and sulfur containing aromatic compounds indicate the oysters were still contaminated with Apex barge oil at least 37 and 110 days after the spill at GBTD and GBRI, respectively. Data from NS ampersand T sampling at GBTD more than a year after the spill (495 days) indicates the presence of alkylated aromatic hydrocarbons that may be from Apex barge oil still in the area. It appears that a sink of Apex barge oil (i.e., in sediments) may periodically be released by storms or other events into the ecosystem near GBTD. Therefore, bioavailable Apex barge oil is still present and may adversely affect oysters 495 days after the spill

  6. Remote sensing for oil spill detection and response

    International Nuclear Information System (INIS)

    Engelhardt, F.R.

    1999-01-01

    This paper focuses on the use of remote sensing for marine oil spill detection and response. The surveillance and monitoring of discharges, and the main elements of effective surveillance are discussed. Tactical emergency response and the requirements for selecting a suitable remote sensing approach, airborne remote sensing systems, and the integration of satellite and airborne imaging are examined. Specifications of satellite surveillance systems potentially usable for oil spill detection, and specifications of airborne remote sensing systems suitable for oil spill detection, monitoring and supplemental actions are tabulated, and a schema of integrated satellite-airborne remote sensing (ISARS) is presented. (UK)

  7. Crude Oil Remote Sensing, Characterization and Cleaning with CW and Pulsed Lasers

    Science.gov (United States)

    Kukhtareva, Tatiana; Chirita, Arc; Gallegos, Sonia C.

    2014-01-01

    For detection, identification and characterization of crude oil we combine several optical methods of remote sensing of crude oil films and emulsions (coherent fringe projection illumination (CFP), holographic in-line interferometry (HILI), and laser induced fluorescence). These methods allow the three-dimensional characterization of oil spills, important for practical applications. Combined methods of CFP and HILI are described in the frame of coherent superposition of partial interference patterns. It is shown, that in addition to detection/identification laser illumination in the green-blue region can also degrade oil slicks. Different types of surfaces contaminated by oil spills are tested: oil on the water, oil on the flat solid surfaces and oil on the curved surfaces of pipes. For the detection and monitoring of the laser-induced oil degradation in pipes, coherent fiber bundles were used. Both continuous-wave (CW) and pulsed lasers are tested using pump-probe schemes. This finding suggests that properly structured laser clean-up can be an alternative environmentally-friendly method of decontamination, as compared to the currently used chemical methods that are dangerous to environment.

  8. OSIS: A PC-based oil spill information system

    International Nuclear Information System (INIS)

    Leech, M.V.; Tyler, A.; Wiltshire, M.

    1993-01-01

    Warren Spring Laboratory and BMT Ceemaid Ltd. are cooperating to produce an Oil Spill Information System (OSIS) that will have worldwide application. OSIS is based on EUROSPILL, a spill simulation model originally developed under programs sponsored by the European Commission and the Marine Pollution Control Unit of the United Kingdom government's Department of Transport. OSIS is implemented in the Microsoft Windows 3.x graphical environment on a personal computer. A variety of options enables the user to input information on continuous or instantaneous spills of different types of oil under variable environmental conditions, to simulate the fate of oil and the trajectory of a spill. Model results are presented in the forms of maps, charts, graphs, and tables, displayed in multiple windows on a color monitor. Color hard copy can be produced, and OSIS can be linked to other Windows software packages, providing the opportunity to create a suite of spill incident management tools

  9. The media politics of oil spills

    International Nuclear Information System (INIS)

    Anderson, A.G.

    2002-01-01

    This paper considers the ways in which news values shape the reporting of oil spills and the constraints under which media practitioners work. A series of oil spills since the late 1960s [including the Torrey Canyon (1967), the Exxon Valdez (1989), and the Sea Empress (1996)] have attracted considerable attention from the news media. The focus is upon the dynamics through which news sources, with their own particular vested interests, compete to secure representation of the issues. Media discourse on risk and the environment is, to a significant extent, a discourse dependent upon the voices of official ''experts''. Environmental organizations, industry, scientists and government offer their own particular competing accounts of the ''reality'' of the situation. Issues concerning differential access to the news media are crucial when considering who comes to define the event. Accordingly, the article examines the strategies adopted by the various news sources involved in influencing the symbolic representation of public issues. Media practitioners are faced with great problems in interpreting and explaining these competing claims. Relatively few journalists and broadcasters have a scientific training and perhaps one of the greatest problems is that by simplifying complex scientific information one inevitably distorts it. Frequently researchers make the assumption that it is possible to demonstrate a direct causal link between news media coverage and public attitudes. However, the paper calls for great caution in interpreting ''public opinion'' concerning environmental issues and concludes by arguing that news media representations may more usefully be viewed as the outcome of a battle among a selective range of news sources, each seeking to provide their own definition of the public representation of the issues. (author)

  10. The media politics of oil spills

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, A.G. [University of Plymouth (United Kingdom). Dept. of Sociology

    2002-06-01

    This paper considers the ways in which news values shape the reporting of oil spills and the constraints under which media practitioners work. A series of oil spills since the late 1960s [including the Torrey Canyon (1967), the Exxon Valdez (1989), and the Sea Empress (1996)] have attracted considerable attention from the news media. The focus is upon the dynamics through which news sources, with their own particular vested interests, compete to secure representation of the issues. Media discourse on risk and the environment is, to a significant extent, a discourse dependent upon the voices of official ''experts''. Environmental organizations, industry, scientists and government offer their own particular competing accounts of the ''reality'' of the situation. Issues concerning differential access to the news media are crucial when considering who comes to define the event. Accordingly, the article examines the strategies adopted by the various news sources involved in influencing the symbolic representation of public issues. Media practitioners are faced with great problems in interpreting and explaining these competing claims. Relatively few journalists and broadcasters have a scientific training and perhaps one of the greatest problems is that by simplifying complex scientific information one inevitably distorts it. Frequently researchers make the assumption that it is possible to demonstrate a direct causal link between news media coverage and public attitudes. However, the paper calls for great caution in interpreting ''public opinion'' concerning environmental issues and concludes by arguing that news media representations may more usefully be viewed as the outcome of a battle among a selective range of news sources, each seeking to provide their own definition of the public representation of the issues. (author)

  11. DOE/DOT Crude Oil Characterization Research Study, Task 2 Test Report on Evaluating Crude Oil Sampling and Analysis Methods

    Energy Technology Data Exchange (ETDEWEB)

    Lord, David [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Allen, Ray [Allen Energy Services, Inc., Longview, TX (United States); Rudeen, David [GRAM, Inc., Albuquerque, NM (United States)

    2017-11-01

    The Crude Oil Characterization Research Study is designed to evaluate whether crude oils currently transported in North America, including those produced from "tight" formations, exhibit physical or chemical properties that are distinct from conventional crudes, and how these properties associate with combustion hazards with may be realized during transportation and handling.

  12. Results from oil spill response research - an update

    International Nuclear Information System (INIS)

    Tennyson, E.J.

    1993-01-01

    Recent large oil spills from tankers have reaffirmed the need for continuing technology assessment and research to improve oil spill response capabilities. This paper discusses Minerals Management Service concerns, as reinforced by the acceleration of its research program in 1990. It briefly assesses current state-of-the-art technology for major aspects of spill response, including remote sensing, open-ocean containment and recovery, in-situ burning, use of chemical treating agents, beachline cleanup, and oil behavior. Specific research projects have begun to yield information that will improve detection and at-sea equipment performance; current projects include the development of an airborne laser-fluorosensor to determine whether apparent slicks contain oil. Additional projects involve the development of improved strategies for responding to oil in broken-ice conditions, for gaining an improved understanding of the fate and behavior of spilled oil as it affects response strategies, and for defining the capabilities of available dispersants and development of improved formulations. Recently, progress has been made on the development of safe and environmentally acceptable strategies to burn spilled oil in situ. The Ohmsett facility has been reopened and will be used to test prospective improvements in chemical treating agents and to develop standard procedures for testing and evaluating response equipment. Results of research published since the last Oil Spill Conference are discussed

  13. Improving oil biodegradability of aliphatic crude oil fraction by ...

    African Journals Online (AJOL)

    The percentage of biodegrading ability of B. subtilis and the mixture of these bacteria to n-alkanes and isoprenoids (pristine, phytane) were measured and compared with control. Crude oil is used as a sole source of energy and the incubation period was 24 days, the hydrocarbons loss are detected each 6 day interval using ...

  14. Transient leak detection in crude oil pipelines

    Energy Technology Data Exchange (ETDEWEB)

    Beushausen, R.; Tornow, S.; Borchers, H. [Nord-West Oelleitung, Wilhelmshaven (Germany); Murphy, K.; Zhang, J. [Atmos International Ltd., Manchester (United Kingdom)

    2004-07-01

    Nord-West Oelleitung (NWO) operates 2 crude oil pipelines from Wilhemshaven to Koln and Hamburg respectively. German regulations for transporting flammable substances stipulate that 2 independent continuously working procedures be used to detect leaks. Leak detection pigs are used routinely to complement the surveillance system. This paper described the specific issues of transient leak detection in crude oil pipelines. It was noted that traditional methods have failed to detect leaks that occur immediately after pumps are turned on or off because the pressure wave generated by the transient dominates the pressure wave that results from the leak. Frequent operational changes in a pipeline are often accompanied by an increased number of false alarms and failure to detect leaks due to unsteady operations. NWO therefore decided to have the Atmos statistical pipeline leak detection (SPLD) system installed on their pipelines. The key to the SPLD system is the sequential probability ratio test. Comprehensive data validation is performed following reception of pipeline data from the supervisory control and data acquisition (SCADA) system. The validated data is then used to calculate the corrected flow imbalance, which is fed into the SPRT to determine if there is an increase in the flow imbalance. Pattern recognition is then used to distinguish a leak from operational changes. The SPLD is unique because it uses 3 computational pipeline monitoring methods simultaneously, namely modified volume balance, statistical analysis, and pressure and flow monitoring. The successful installation and testing of the SPLD in 2 crude oil pipelines was described along with the main difficulties associated with transient leaks. Field results were presented for both steady-state and transient conditions. 5 refs., 2 tabs., 16 figs.

  15. In situ oil burning in the marshland environment : soil temperatures resulting from crude oil and diesel fuel burns

    International Nuclear Information System (INIS)

    Bryner, N.P.; Walton, W.D.; Twilley, W.H.; Roadarmel, G.; Mendelssohn, I.A.; Lin, Q.; Mullin, J.V.

    2001-01-01

    The unique challenge associated with oil spill cleanups in sensitive marsh environments was discussed. Mechanical recovery of crude or refined hydrocarbons in wetlands may cause more damage to the marsh than the oil itself. This study evaluated whether in situ burning of oiled marshlands would provide a less damaging alternative than mechanical recovery. This was done through a series of 6 crude oil and 5 diesel fuel burns conducted in a test tank to examine the impact of intentional burning of oil spilled in a wetlands environment. There are several factors which may influence how well such an environment would recover from an in situ oil burn, such as plant species, fuel type and load, water level, soil type, and burn duration. This paper focused on soil, air and water temperatures, as well as total heat fluxes that resulted when 3 plant species were exposed to full-scale in situ burns that were created by burning diesel fuel and crude oil. The soil temperatures were monitored during the test burn at three different soil/water elevations for 700 second burn exposures. A total of 184 plant sods were harvested from marshlands in southern Louisiana and were subjected to the burning fuel. They were instrumental in characterizing the thermal and chemical stress that occur during an in-situ burn. The plants were inserted into the test tanks at various water and soil depths. The results indicated that diesel fuel and crude oil burns produced similar soil temperature profiles at each of three plant sod elevations. Although in-situ burning did not appear to remediate oil that had penetrated into the soil, it did effectively remove floating oil from the water surface, thereby preventing it from potentially contaminating adjacent habitats and penetrating the soil when the water recedes. The regrowth and recovery of the plants will be described in a separate report. 25 refs., 7 tabs., 15 figs

  16. Vulnerability maps for Druzba crude oil pipeline

    International Nuclear Information System (INIS)

    Hladik, P.; Hosnedl, P.; Buresova, H.; Corbet, J.

    2012-01-01

    Maps of risk for individual environmental aspects within the protection zone of the Czech part of the Druzba crude oil pipeline (505.7 km) were developed based on a modified 'H and V index' method. Risk data were added into a GIS of the Druzba pipeline so that the system could be used as conceptual material in the field of environmental protection (a base for the new SCADA system). Considered environmental aspects were assessed in terms of their vulnerability. The criteria were defined as the vulnerability of the aquatic environment (surface waters and ground waters), the vulnerability of soil environment and the vulnerability of biotic components of the environment. (authors)

  17. Effects of an oil spill on American lobster (Homarus americanus) from Placentia Bay, Newfoundland

    Energy Technology Data Exchange (ETDEWEB)

    Wiliams, U P; Kiceniuk, J W; Ryder, J E; Botta, J R

    1988-10-01

    In March 1988 an accidental spill of ca 500 bbl of crude oil occurred during the unloading of a tanker at a Newfoundland oil refinery. Studies of selected parameters were undertaken to determine the possible short-and long-term effects on the local lobster fishery. Sensory analyses were carried out to ascertain the effects of the oil on the taste and odor of lobster. Lobster muscle and hepatopancreas were analyzed for PAH (polycyclic aromatic hydrocarbon) content and levels of gill browning were determined. Sediments were sampled at various locations in the bay where the spill occurred and levels of PAHs were determined in an attempt to delineate the extent of contamination. Results from the sensory analyses indicate that there was no tainting of lobster samples obtained from the area. There was also no evidence of gill browning or of elevated levels of PAHs in either tail muscle or hepatopancreas. Elevated levels of PAH were not detected in any of the sediments from the bay. The results indicate that lobsters were not contaminated as a result of the oil spill. Based on the results of analyses of sediments for PAHs, future contamination, as a result of the spill at the oil refinery wharf, is not anticipated. 18 refs., 6 tabs.

  18. New insights into microbial responses to oil spills from the Deepwater Horizon incident

    Energy Technology Data Exchange (ETDEWEB)

    Mason, O.U.; Hazen, T.C.

    2011-06-15

    On April 20, 2010, a catastrophic eruption of methane caused the Deepwater Horizon exploratory drill rig drilling the Macondo Well in Mississippi Canyon Block 252 (MC252) to explode. The Deepwater Horizon oil spill was unprecendeted for several reasons: the volume of oil released; the spill duration; the well depth; the distance from the shore-line (77 km or about 50 miles); the type of oil (light crude); and the injection of dispersant directly at the wellhead. This study clearly demonstrated that there was a profound and significant response by certain members of the in situ microbial community in the deep-sea in the Gulf of Mexico. In particular putative hydrocarbon degrading Bacteria appeared to bloom in response to the Deepwater Horizon oil spill, even though the temperature at these depths is never >5 C. As the plume aged the shifts in the microbial community on a temporal scale suggested that different, yet metabolically important members of the community were able to respond to a myriad of plume constituents, e.g. shifting from propane/ethane to alkanes and finally to methane. Thus, the biodegradation of hydrocarbons in the plume by Bacteria was a highly significant process in the natural attenuation of many compounds released during the Deepwater Horizon oil spill.

  19. Transporting US oil imports: The impact of oil spill legislation on the tanker market. Draft final report

    Energy Technology Data Exchange (ETDEWEB)

    Rowland, P.J. [Rowland (P.) Associates (United States)

    1992-05-01

    The Oil Pollution Act of 1990 (``OPA``) and an even more problematic array of State pollution laws have raised the cost, and risk, of carrying oil into and out of the US. This report, prepared under contract to the US Department of energy`s Office of Domestic and International Policy, examines the impact of Federal and State oil spill legislation on the tanker market. It reviews the role of marine transportation in US oil supply, explores the OPA and State oil spill laws, studies reactions to OPA in the tanker and tank barge industries and in related industries such as insurance and ship finance, and finally, discusses the likely developments in the years ahead. US waterborne oil imports amounted to 6.5 million B/D in 1991, three-quarters of which was crude oil. Imports will rise by almost 3 million B/D by 2000 according to US Department of energy forecasts, with most of the crude oil growth after 1995. Tanker demand will grow even faster: most of the US imports and the increased traffic to other world consuming regions will be on long-haul trades. Both the number of US port calls by tankers and the volume of offshore lightering will grow. Every aspect of the tanker industry`s behavior is affected by OPA and a variety of State pollution laws.

  20. Assessment of biological characteristics on coastal environment of Murud (Maharashtra) during the oil spill (17 May 1993)

    Digital Repository Service at National Institute of Oceanography (India)

    Gajbhiye, S.N.; Mustafa, S.; Mehta, P.; Nair, V.R.

    A rupture of a feeder riser pipeline resulted in spillage of crude oil estimated to be 3000-8000 tonnes in Bombay High Region on 17 May 1993. The treated spill broken down into several patches and drifted south and finally got deposited on the Murud...

  1. Comparative study of biodegradation of crude oil in soil amended ...

    African Journals Online (AJOL)

    Analysis of soil samples treated with 10% (v/w) Escravos light crude oil and amended with chicken droppings and NPK fertilizer revealed that the aerobic heterotrophic bacterial counts were depressed while the proliferation of crude oil degrading bacteria (CDB) in the soil was encouraged. The counts of CDB in oil free ...

  2. Design of a Low-cost Oil Spill Tracking Buoy

    Science.gov (United States)

    Zhao, Y.; Hu, X.; Yu, F.; Dong, S.; Chen, G.

    2017-12-01

    As the rapid development of oil exploitation and transportation, oil spill accidents, such as Prestige oil spill, Gulf of Mexico oil spill accident and so on, happened frequently in recent years which would result in long-term damage to the environment and human life. It would be helpful for rescue operation if we can locate the oil slick diffusion area in real time. Equipped with GNSS system, current tracking buoys(CTB), such as Lagrangian drifting buoy, Surface Velocity Program (SVP) drifter, iSLDMB (Iridium self locating datum marker buoy) and Argosphere buoy, have been used as oil tracking buoy in oil slick observation and as validation tools for oil spill simulation. However, surface wind could affect the movement of oil slick, which couldn't be reflected by CTB, thus the oil spill tracking performance is limited. Here, we proposed an novel oil spill tracking buoy (OSTB) which has a low cost of less than $140 and is equipped with Beidou positioning module and sails to track oil slick. Based on hydrodynamic equilibrium model and ocean dynamic analysis, the wind sails and water sails are designed to be adjustable according to different marine conditions to improve tracking efficiency. Quick release device is designed to assure easy deployment from air or ship. Sea experiment was carried out in Jiaozhou Bay, Northern China. OSTB, SVP, iSLDMB, Argosphere buoy and a piece of oil-simulated rubber sheet were deployed at the same time. Meanwhile, oil spill simulation model GNOME (general NOAA operational modeling environment) was configured with the wind and current field, which were collected by an unmanned surface vehicle (USV) mounted with acoustic Doppler current profilers (ADCP) and wind speed and direction sensors. Experimental results show that the OSTB has better relevance with rubber sheet and GNOME simulation results, which validate the oil tracking ability of OSTB. With low cost and easy deployment, OSTB provides an effective way for oil spill numerical

  3. Evaluation of behavioral parameters, hematological markers, liver and kidney functions in rodents exposed to Deepwater Horizon crude oil and Corexit.

    Science.gov (United States)

    Ramesh, Sindhu; Bhattacharya, Dwipayan; Majrashi, Mohammed; Morgan, Marlee; Prabhakar Clement, T; Dhanasekaran, Muralikrishnan

    2018-04-15

    The 2010 Deepwater Horizon (DWH) oil spill is the largest marine oil spill in US history. In the aftermath of the spill, the response efforts used a chemical dispersant, Corexit, to disperse the oil spill. The health impacts of crude oil and Corexit mixture to humans, mammals, fishes, and birds are mostly unknown. The purpose of this study is to investigate the in vivo effects of DWH oil, Corexit, and oil-Corexit mixture on the general behavior, hematological markers, and liver and kidney functions of rodents. C57 Bl6 mice were treated with DWH oil (80 mg/kg) and/or Corexit (95 mg/kg), and several hematological markers, lipid profile, liver and kidney functions were monitored. The results show that both DWH oil and Corexit altered the white blood cells and platelet counts. Moreover, they also impacted the lipid profile and induced toxic effects on the liver and kidney functions. The impacts were more pronounced when the mice were treated with a mixture of DWH-oil and Corexit. This study provides preliminary data to elucidate the potential toxicological effects of DWH oil, Corexit, and their mixtures on mammalian health. Residues from the DWH spill continue to remain trapped along various Gulf Coast beaches and therefore further studies are needed to fully understand their long-term impacts on coastal ecosystems. Copyright © 2018. Published by Elsevier Inc.

  4. Enhanced crude oil biodegradative potential of natural phytoplankton-associated hydrocarbonoclastic bacteria.

    Science.gov (United States)

    Thompson, Haydn; Angelova, Angelina; Bowler, Bernard; Jones, Martin; Gutierrez, Tony

    2017-07-01

    Phytoplankton have been shown to harbour a diversity of hydrocarbonoclastic bacteria (HCB), yet it is not understood how these phytoplankton-associated HCB would respond in the event of an oil spill at sea. Here, we assess the diversity and dynamics of the bacterial community associated with a natural population of marine phytoplankton under oil spill-simulated conditions, and compare it to that of the free-living (non phytoplankton-associated) bacterial community. While the crude oil severely impacted the phytoplankton population and was likely conducive to marine oil snow formation, analysis of the MiSeq-derived 16S rRNA data revealed dramatic and differential shifts in the oil-amended communities that included blooms of recognized HCB (e.g., Thalassospira, Cycloclasticus), including putative novel phyla, as well as other groups with previously unqualified oil-degrading potential (Olleya, Winogradskyella, and members of the inconspicuous BD7-3 phylum). Notably, the oil biodegradation potential of the phytoplankton-associated community exceeded that of the free-living community, and it showed a preference to degrade substituted and non-substituted polycyclic aromatic hydrocarbons. Our study provides evidence of compartmentalization of hydrocarbon-degrading capacity in the marine water column, wherein HCB associated with phytoplankton are better tuned to degrading crude oil hydrocarbons than that by the community of planktonic free-living bacteria. © 2017 Society for Applied Microbiology and John Wiley & Sons Ltd.

  5. Potential Environmental Impacts of Oil Spills in Greenland

    DEFF Research Database (Denmark)

    This report analyses information status and research needs in relation to potential environmental impacts of oil spills (offshore and onshore) in Greenland. The report assesses potential effects and potential mitigation and monitoring measures. Information gaps are identified and a number...

  6. OSIS: A Windows 3 Oil Spill Information System

    International Nuclear Information System (INIS)

    Leech, M.; Walker, M.; Wiltshire, M.; Tyler, A.

    1993-01-01

    An oil spill modelling and analysis system called the Oil Spill Information System (OSIS) has recently been developed. OSIS uses a model of oceanographic processes to predict three-dimensional spreading and transport of an oil slick under the influence of wind, waves, tide, turbulence, and shear diffusion. Oil weathering and fate processes of emulsification, evaporation, and dispersion are also simulated. The physical models have been tested against data obtained from sea trials and spill incidents. OSIS uses an object-oriented programming technique and presents model output as maps, graphs, and tables in multiple windows and can link to other Windows packages to create a suite of spill information management tools. 15 refs., 12 figs

  7. Crude oil prices: Are our oil markets too tight?

    International Nuclear Information System (INIS)

    Simmons, M.R.

    1997-01-01

    The answer to the question posed in the title is that tightness in the market will surely prevail through 1997. And as discussed herein, with worldwide demand expected to continue to grow, there will be a strong call on extra oil supply. Meeting those demands, however, will not be straightforward--as many observers wrongly believe--considering the industry's practice of maintaining crude stocks at ''Just in time'' inventory levels. Further, impact will be felt from the growing rig shortage, particularly for deepwater units, and down-stream capacity limits. While these factors indicate 1997 should be another good year for the service industry, it is difficult to get any kind of consensus view from the oil price market. With most observers' information dominated by the rarely optimistic futures price of crude, as reflected by the NYMEX, the important fact is that oil prices have remained stable for three years and increased steadily through 1996

  8. [Acute health effects of the Hebei oil spill on the residents of Taean, Korea].

    Science.gov (United States)

    Lee, Cheol-Heon; Kang, Young-A; Chang, Kyu-Jin; Kim, Chang-Hoon; Hur, Jong-Il; Kim, Jae-Youn; Lee, Jong-Koo

    2010-03-01

    On December 7, 2007, the Hebei Spirit oil tanker spilled out 12,547 kl of crude oil on the Yellow Sea 10 km away from the cost of Taean Province, Korea. As the coastline has been contaminated, local residents have been exposed to crude oil. Because the residents were showing many symptoms, we investigated the acute health effects of this oil spill on them. We conducted a cross-sectional study consisting of the heavy and moderately oil soaked area in Taean and the lightly oil soaked area in Seocheon. Ten seashore villages were selected from each area, and 10 male and female adults were selected from each village. We interviewed the subjects using a structured questionnaire on the characteristics of residents, the cleanup activities, the perception of oil hazard, depression and anxiety, and the physical symptoms. The odds ratios and 95% confidence intervals were analyzed using logistic regression analysis. The logistic regression model was adjusted for age, gender, education, smoking, the perception of oil hazard and anxiousness. The more highly contaminated the area, the more likely it was for residents to be engaged in cleanup activities and have a greater chance of exposure to oil. The indexes of anxiety and depression were higher in the heavy and moderately oil soaked areas. The increased risks of headache, nausea, dizziness, fatigue, tingling of limb, hot flushing, sore throat, cough, runny nose, shortness of breath, itchy skin, rash, and sore eyes were significant. The results suggest that exposure to crude oil is associated with various acute physical symptoms. Long-term investigation is required to monitor the residents' health.

  9. Oil spill cleanup for soft sediments

    International Nuclear Information System (INIS)

    Abbott, J.A.; Tookey, D.J.

    1993-01-01

    A series of experimental trials are in progress to investigate the effectiveness and consequences of oil spill cleanup methods for areas of mud flats and salt marsh. Trials have shown that wheeled and tracked vehicles have limited utility. Field measurements of the load bearing capacity of the mud can show where such vehicles may be used. Lightweight hover craft provide a useful means of transport. Shallow-draft boats can have a useful transport role: whether such craft can be used depends on the local topography and tidal regime. The trials showed that practical problems associated with implementing low-pressure flushing operations (lack of water for flushing, recovery of the flushed oil) can be overcome - although the environmental effects have yet to be assessed. The use of straw matting as a sorbent material was also demonstrated. The objective of the first two phases of the project, reported here, was to select workable methods with a view to subsequently employing them in larger-scale trials. The environmental consequences of using the selected methods will be examined in the later trials

  10. Environmental effects of acute oil spills. Marine environment

    International Nuclear Information System (INIS)

    Moe, K.A.; Lystad, E.; Nesse, S.; Selvik, J.R.

    1993-01-01

    Biological effects as result of acute oil spill pollution may be considered as a product of: the existing biophysical conditions; occurrence and appearance of organisms in time and space; the fate of the oil in time and space; the vulnerability of the various organisms for oil and oil derivatives in a three-dimensional perspective. In general, it seems as every individual oil spill has its own nature and dynamics, inter alia because the physical, chemical and biological conditions never are the same. This means that the properties of the recipients often are more important than the amount of oil that is spilled. This may be exemplified by two oil spills in recent time. Exxon Valdez (1989), where 35000 ton oil were released in a partly closed sea area, caused considerable effects. From Braer (1993) the double amount of oil was spilled, but in an open sea area and at a time where the presence of dense concentrations of environmental components was limited, and the physical conditions favorable with respect to evaporation and dilution. Preliminary results show that the environmental effects were very limited. 311 refs., 32 figs., 10 tabs

  11. Numerical modeling of oil spills in continental and estuarine waters

    International Nuclear Information System (INIS)

    Goeury, C.

    2012-10-01

    The application of the European Water Framework Directive on water quality for human consumption and industrial activities creates a need for water quality assessment and monitoring systems. The MIGR'HYCAR research project (http://www.migrhycar.com) was initiated to provide decisional tools for risks connected to oil spills in continental waters (rivers, lakes and estuaries), which represent more than 50% of accidental spills in France. Within the framework of this project, a new numerical oil spill model has been developed, as part of the TELEMAC hydro-informatics system (http://www.opentelemac.org), by combining Lagrangian and Eulerian methods. The Lagrangian model describes the transport of an oil spill near the free surface. The oil spill model enables to simulate the main processes driving oil plumes: advection, diffusion, oil beaching, oil re-floating, evaporation, dissolution, spreading and volatilization. Though generally considered as a minor process, dissolution is important from the point of view of toxicity. To model dissolved oil in water, an Eulerian advection-diffusion model is used. The fraction of dissolved oil is represented by a passive tracer. This approach is able to follow dissolved hydrocarbons in the water column. Laboratory experiments were conducted to characterise the numerous kinetics of the processes listed above. In addition, meso-scale dynamic experiments in artificial channels and test cases derived from the literature are used to validate the numerical model. (author)

  12. Operational problems related to the preparation of the seawater soluble fraction of crude oil.

    Science.gov (United States)

    Ziolli, Roberta L; Jardim, Wilson F

    2002-02-01

    Owing to the importance of dissolution and weathering processes following oil spills, this work focused on the operational (quantitative) aspects related to the dissolution of petroleum-derived products, as well as the influence of solar light on both dissolution and the photoproduction of hydrogen peroxide. Four Brazilian crude oil samples were used to study the transfer process of organic compounds from the crude oil film to the aqueous phase (natural seawater) over a period of up to 45 days. Dissolved organic carbon (DOC), measured by non-dispersive infrared spectroscopy followed by high temperature catalytic combustion, was used to follow the partitioning between the two phases. Aqueous DOC values increased as a function of time (up to 15 days) until equilibrium was reached at concentrations ranging from 5 to 45 mg C L(-1). The final DOC concentration as well as the rate of dissolution depends on the nature of the crude oil. When exposed to sunlight, the dissolution was enhanced by up to 67.3%, and inorganic peroxides were generated in the concentration range from 4.5 up to 8.0 micromol L(-1) after 7.3 h irradiation. These results indicate that there is a need for a standard procedure for the production of the WSF in order to generate a more reliable tool to assess the impact of oil spills on the marine environment.

  13. Alkane and crude oil degrading bacteria from the petroliferous soil of India

    International Nuclear Information System (INIS)

    Roy, I.; Mishra, A.K.; Ray, A.K.

    1991-01-01

    It has been estimated that approximately 0.5 percent of transported crude oil finds its way into seawater, largely through accidental spills and discharge of ballast and wash water from oil tankers. Some microorganisms are well known for their ability to degrade a variety of hydrocarbons present in crude oil. Oil spills at sea or on land have demonstrated the hydrocarbon-degrading potential of these organisms. Under laboratory conditions, nitrogen may be supplied in soluble form (inorganic salts of ammonia or nitrate of urea). Since most natural aquatic environments are deficient in utilizable forms of nitrogen, it is necessary to add the same exogeneously, but because of rapid dilution the added source of nitrogen does not remain effective. The need for nitrogen supplements may be overcome by appropriate choice of microbes with the genetic capacity to fix molecular nitrogen. In this paper the authors are reporting the isolation of a strain of Pseudomonas stutzeri from the petroliferous soil of India. This strain has the capacity to degrade alkane and crude oil and to fix nitrogen

  14. In Situ burning of Arctic marine oil spills

    DEFF Research Database (Denmark)

    Fritt-Rasmussen, Janne

    experiments where the ignitability of oil spill as a function of oil type and weathering conditions (time/ice) was tested. The results show that the composition of the oil and the ice cover is important for the in situ burning time-window. The results were used to develop an algorithm that was implemented...

  15. Crude oil pricing report, issue 89, December 1992

    International Nuclear Information System (INIS)

    1992-01-01

    This report is prepared by the Canadian Oil Markets and Emergency Planning Division (COMEP), Energy, Mines and Resources Canada. It provides a reference for domestic and imported crude oil prices in Canadian markets and illustrates the competitive position of Canadian crude in the U.S. market. The information in this report is in part based on the Crude Oil Pricing Survey (COPS), conducted by COMEP, of Canadian refiners' domestic crude oil purchases, refinery receipts, imports and data from trade publications as well as industry pricing bulletins. 8 tabs

  16. Modulations in cell-mediated immunity of Mytilus edulis following the 'Sea Empress' oil spill

    International Nuclear Information System (INIS)

    Dyrynda, E.A.; Dyrynda, P.E.J.; Ratcliffe, N.A.; Pipe, R.K.

    1997-01-01

    The 'Sea Empress' oil tanker grounded outside Milford Haven (Wales, UK) in February 1996, spilling ∼ 70,000 tonnes of crude oil and contaminating over 100 km of coastline, causing mass mortalities and strandings of at least 11 mollusc species. Intensive field monitoring commenced after the spill, examining immunity and hydrocarbon levels in the mussel, Mytilus edulis (Mollusca: Bivalvia), a commercially-harvested species which can accumulate contaminants. Comparisons of mussels from oiled and reference sites revealed significant modulations in cell-mediated immunity. Elevations in blood cell (haemocyte) numbers and decreases in superoxide generation and phagocytosis were identified in contaminated animals. The immune response of contaminated mussels gradually improved and generally showed no significant differences compared with clean mussels after 11 weeks. By then, total hydrocarbon content in contaminated mussels had declined by 70-90%, while polycyclic aromatic hydrocarbon content had decreased by over 90%. (author)

  17. Effect of Prudhoe Bay crude oil on the homing of coho salmon in marine waters

    International Nuclear Information System (INIS)

    Nakatani, R.E.; Nevissi, A.E.

    1991-01-01

    Resource managers and the fishing industry have expressed concern that a crude-oil spill occurring in the pathway of a salmon run may destroy the ability of the maturing salmon to reach the home stream. To address this concern, groups of mature 3-year-old and precocious 2-year-old coho salmon Oncorhynchus kisutch were tagged and exposed in seawater for 1 hr to sublethal concentration of Prudhoe Bay crude oil, dispersed oil, or seawater oil dispersant alone, and then were released in seawater about 5 km from their home stream. The results show that the coho salmon's homing success and speed of return to the home stream were not affected by any of the treatments. The longevity or holding tests, in which coho salmon were held in saltwater netpens after experimental treatments, showed that the larger 3-year-old coho salmon were more sensitive to the stress of confinement than the smaller 2-year-old fish

  18. Enrichment of Fusobacteria in Sea Surface Oil Slicks from the Deepwater Horizon Oil Spill

    OpenAIRE

    Gutierrez, Tony; Berry, David; Teske, Andreas; Aitken, Michael D.

    2016-01-01

    The Deepwater Horizon (DWH) oil spill led to rapid microbial community shifts in the Gulf of Mexico, including the formation of unprecedented quantities of marine oil snow (MOS) and of a massive subsurface oil plume. The major taxa that bloomed in sea surface oil slicks during the spill included Cycloclasticus, and to a lesser extent Halomonas, Alteromonas, and Pseudoalteromonas?organisms that grow and degrade oil hydrocarbons aerobically. Here, we show that sea surface oil slicks at DWH cont...

  19. ADIOS-automated data inquiry for oil spills

    International Nuclear Information System (INIS)

    Lehr, W.J.; Overstreet, R.; Jones, R.; Watabayashi, G.

    1992-01-01

    An intelligent computer database called ADIOS has been developed which stores properties of several hundred oils and oil products and which is combined with a model for oil weathering. Environmental data are input by the user through a menu-driven graphic interface. The format of the output is designed to provide immediate information for oil spill cleanup decisions. Typical output information includes changes in key physical parameters (density, viscosity, water content of emulsions) over time and an oil loss budget at any specific time. The model includes algorithms for spill spreading, evaporation, entrainment, droplet size distributions, rate of mousse formation, and changes in density and viscosity. ADIOS will eventually be part of a larger spill model which includes oil transport. ADIOS calculations are presented as either pie charts or graphs. 21 refs., 2 figs

  20. Systemic toxicity of dermally applied crude oils in rats

    Energy Technology Data Exchange (ETDEWEB)

    Feuston, M.H.; Mackerer, C.R.; Schreiner, C.A.; Hamilton, C.E. [Stonybrook Labs., Inc., Princeton, NJ (United States)

    1997-12-31

    Two crude oils, differing in viscosity (V) and nitrogen (N) and sulfur (S) content, were evaluated for systemic toxicity, In the Crude I (low V, low N, low S) study, the material was applied to the clipped backs of rats at dose levels of 0, 30, 125, and 500 mg/kg. In the Crude II (high V, high N, moderate S) study, the oil was applied similarly at the same dose levels. The crude oils were applied for 13 wk, 5 d/wk. Exposure sites were not occluded. Mean body weight gain (wk 1-14) was significantly reduced in male rats exposed to Crude II; body weight gain of all other animals was not adversely affected by treatment. An increase in absolute (A) and relative (R) liver weights and a decrease in A and R thymus weights were observed in male and female rats exposed to Crude II at 500 mg/kg; only liver weights (A and R) were adversely affected in male and female rats exposed to Crude I. In general, there was no consistent pattern of toxicity for serum chemistry endpoints; however, more parameters were adversely affected in Crude II-exposed female rats than in the other exposed groups. A consistent pattern of toxicity for hematology endpoints was observed among male rats exposed to Crude I and male and female rats exposed to Crude II. Parameters affected included: Crudes I and II, red blood cell count, hemoglobin, and hematocrit, Crude II, platelet count. Microscopic evaluation of tissues revealed the following treatment-related findings: Crude I, treated skin, thymus, and thyroid; Crude II, bone marrow, treated skin, thymus, and thyroid. The LOEL (lowest observable effect level) for skin irritation and systemic toxicity (based on marginal effects on the thyroid) for both crude oils was 30 mg/kg; effects were more numerous and more pronounced in animals exposed to Crude II. Systemic effects are probably related to concentrations of polycyclic aromatic compounds (PAC) found in crude oil.

  1. A MODIS-Based Robust Satellite Technique (RST for Timely Detection of Oil Spilled Areas

    Directory of Open Access Journals (Sweden)

    Teodosio Lacava

    2017-02-01

    Full Text Available Natural crude-oil seepages, together with the oil released into seawater as a consequence of oil exploration/production/transportation activities, and operational discharges from tankers (i.e., oil dumped during cleaning actions represent the main sources of sea oil pollution. Satellite remote sensing can be a useful tool for the management of such types of marine hazards, namely oil spills, mainly owing to the synoptic view and the good trade-off between spatial and temporal resolution, depending on the specific platform/sensor system used. In this paper, an innovative satellite-based technique for oil spill detection, based on the general robust satellite technique (RST approach, is presented. It exploits the multi-temporal analysis of data acquired in the visible channels of the Moderate Resolution Imaging Spectroradiometer (MODIS on board the Aqua satellite in order to automatically and quickly detect the presence of oil spills on the sea surface, with an attempt to minimize “false detections” caused by spurious effects associated with, for instance, cloud edges, sun/satellite geometries, sea currents, etc. The oil spill event that occurred in June 2007 off the south coast of Cyprus in the Mediterranean Sea has been considered as a test case. The resulting data, the reliability of which has been evaluated by both carrying out a confutation analysis and comparing them with those provided by the application of another independent MODIS-based method, showcase the potential of RST in identifying the presence of oil with a high level of accuracy.

  2. Effect of crude oil contamination on the chlorophyll content and morpho-anatomy of Cyperus brevifolius (Rottb.) Hassk.

    Science.gov (United States)

    Baruah, Plabita; Saikia, Rashmi Rekha; Baruah, Partha Pratim; Deka, Suresh

    2014-11-01

    Chlorophyll plays a pivotal role in the plant physiology and its productivity. Cultivation of plants in crude oil contaminated soil has a great impact on the synthesis of chlorophyll pigment. Morpho-anatomy of the experimental plant also shows structural deformation in higher concentrations. Keeping this in mind, a laboratory investigation has been carried out to study the effect of crude oil on chlorophyll content and morpho-anatomy of Cyperus brevifolius plant. Fifteen-day-old seedling of the plant was planted in different concentrations of the crude oil mixed soil (i.e., 10,000, 20,000, 30,000, 40,000, and 50,000 ppm). A control setup was also maintained without adding crude oil. Results were recorded after 6 months of plantation. Investigation revealed that there is a great impact of crude oil contamination on chlorophyll content of the leaves of the experimental plant. It also showed that chlorophyll a, chlorophyll b, and total chlorophyll content of leaves grown in different concentrations of crude oil were found to be lower than those of the control plant. Further, results also demonstrated that chlorophyll content was lowest in the treatment that received maximum dose of crude oil. It also showed that chlorophyll content was decreased with increased concentration of crude oil. Results also demonstrated that there was a reduction in plant shoot and root biomass with the increase of crude oil concentration. Results also revealed that the shoot biomass is higher than root biomass. Morphology and anatomy of the experimental plant also show structural deformation in higher concentrations. Accumulation of crude oil on the cuticle of the transverse section of the leaves and shoot forms a thick dark layer. Estimation of the level of pollution in an environment due to oil spill is possible by the in-depth study of the harmful effects of oil on the morphology and anatomy and chlorophyll content of the plants grown in that particular environment.

  3. 1993 International oil spill conference: Prevention, preparedness, response

    International Nuclear Information System (INIS)

    Anon.

    1993-01-01

    This book contains the proceedings of the 1993 International Oil Spill Conference which took place March 29 - April 1 in Tampa, Florida. It was jointly sponsored by the American Petroleum Institute, the US Coast Guard, and the US Environmental Protection Agency. Topics discussed included all aspects of spill prevention and preparedness, including planning, training, and research and development. Response issues, including fate and effects of spilled oil, cleanup, bioremediation, and in situ burning were also discussed. Legal and economic issues were also analyzed in the form of case studies

  4. Food Insecurity, Malnutrition and Crude Oil Spillage in a Rural ...

    African Journals Online (AJOL)

    , external control group study design, with a semi-structured questionnaire and anthropometry as the study tools. The study ... Keywords: Pipeline oil spill, household food security, malnutrition, rural community, Nigeria. Nigerian Journal of ...

  5. Allocation of multiple, widely spread oil spills associated with one polluter : GC-MS fingerprinting and diagnostic ratios of spilled oil and oiled seabirds

    International Nuclear Information System (INIS)

    Hansen, A.B.; Avnskjold, J.

    2005-01-01

    In January 2005, a Cypriot cargo ship leaked about 5 tons of heavy fuel bunker oil in Kerteminde Bay in the Great Belt, Denmark. The ship was stopped to inspect and collect oil samples from its 2 damaged tanks for forensic oil spill identification by gas chromatography and mass spectrometry. Two weeks following the accident, a series of waterborne and stranded oil spills showed up in the Great Belt area, north and south of the vessel's route. Thousands of oiled seabirds on small islands and coastlines were affected. The Danish Coast Guard suspected that the vessel might be responsible for the observed spills. More than 50 oil samples were collected and sent for forensic analysis at the National Environmental Research Institute. Both waterborne and stranded spill samples showed an almost perfect match of diagnostic ratios and chromatograph with the potential responsible party (PRP) bunker. The spill samples therefore matched the reference oil and were allocated to the spill associated with the Cypriot cargo ship. One sample deviated significantly from the other samples and was not allocated to the ship's accidental spill. Oil samples collected from oiled seabirds showed larger variations between diagnostic ratios and the reference bunker oils. The variations can be attributed to weathering and biodegradation, but also to contamination by non-petrogenic material. It was concluded that the oiled seabirds represented non-match samples that cannot be allocated to the oil spill associated with the Cypriot cargo ship. 14 refs., 3 tabs., 4 figs

  6. Integration of Web-GIS and oil spill simulation applications for environmental management of near-shore spill accidents

    International Nuclear Information System (INIS)

    Goto, S.; Miyata, D.; Varlamov, S.M.; Kim, S.-W.

    2001-01-01

    In the event of a near-shore oil spill, the use of a web-based Geographic Information System (GIS) can greatly improve emergency response management and oil recovery operations by providing real-time information support. This paper presented a Web-GIS that is used in combination with an oil spill simulation model. The structure and content of the system was defined after the Nakhodka vessel spilled oil in the Sea of Japan in January 1997, leaving serious environmental damage to the coastal area of the Ishikawa prefecture. The Web-GIS provides a wide range of environmental and oil spill related information, presented in a geographical form. The system also consolidates spill and environmental damage related information from different sources and provides links to the specialized environmental and socio-economical information of other GIS databases. The oil spill modeling subsystem is part of an application for protection planning and oil recovery operations. With this system, oil-drift simulation begins at the onset of any oil spill and then remote sensing data are used to estimate the position and state of the spilled oil. The spill information is then assimilated into the spill model and the observed simulated results are uploaded to the Web page for public information. The applicability of the Web-GIS is extended by support for information gathering from the public and the responsible agencies. The relative simplicity of the system interface is an added advantage. 9 refs., 4 figs

  7. What about oil reserve depletion and crude oil price evolution?

    International Nuclear Information System (INIS)

    2007-01-01

    The objective of this report is to give a synthesis of different points of view with respect to the 'Peak Oil' perspective and to the crude oil price evolution. In the first part, the authors examine the evolutions and assessments of oil reserves and productions, by discussing the different types of reserve, the optimistic and pessimistic points of views. Then, in the second part, they analyse the long term price formation, the various production technical costs (conventional oils, heavy oils and asphaltic sands, coal- and gas-based synthetic hydrocarbons, bio-fuels), the external costs (notably in relationship with greenhouse emissions), the relationship between geopolitical issues and short and middle term price formation. In the third and last part, they discuss the possible evolutions and scenarios in terms of demand, production, and prices

  8. Sacrificial amphiphiles: Eco-friendly chemical herders as oil spill mitigation chemicals.

    Science.gov (United States)

    Gupta, Deeksha; Sarker, Bivas; Thadikaran, Keith; John, Vijay; Maldarelli, Charles; John, George

    2015-06-01

    Crude oil spills are a major threat to marine biota and the environment. When light crude oil spills on water, it forms a thin layer that is difficult to clean by any methods of oil spill response. Under these circumstances, a special type of amphiphile termed as "chemical herder" is sprayed onto the water surrounding the spilled oil. The amphiphile forms a monomolecular layer on the water surface, reducing the air-sea surface tension and causing the oil slick to retract into a thick mass that can be burnt in situ. The current best-known chemical herders are chemically stable and nonbiodegradable, and hence remain in the marine ecosystem for years. We architect an eco-friendly, sacrificial, and effective green herder derived from the plant-based small-molecule phytol, which is abundant in the marine environment, as an alternative to the current chemical herders. Phytol consists of a regularly branched chain of isoprene units that form the hydrophobe of the amphiphile; the chain is esterified to cationic groups to form the polar group. The ester linkage is proximal to an allyl bond in phytol, which facilitates the hydrolysis of the amphiphile after adsorption to the sea surface into the phytol hydrophobic tail, which along with the unhydrolyzed herder, remains on the surface to maintain herding action, and the cationic group, which dissolves into the water column. Eventual degradation of the phytol tail and dilution of the cation make these sacrificial amphiphiles eco-friendly. The herding behavior of phytol-based amphiphiles is evaluated as a function of time, temperature, and water salinity to examine their versatility under different conditions, ranging from ice-cold water to hot water. The green chemical herder retracted oil slicks by up to ~500, 700, and 2500% at 5°, 20°, and 35°C, respectively, during the first 10 min of the experiment, which is on a par with the current best chemical herders in practice.

  9. Impact of Expanded North Slope of Alaska Crude Oil Production on Crude Oil Flows in the Contiguous United States

    Energy Technology Data Exchange (ETDEWEB)

    DeRosa, Sean E. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Flanagan, Tatiana Paz [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-05-01

    The National Transportation Fuels Model was used to simulate a hypothetical increase in North Slope of Alaska crude oil production. The results show that the magnitude of production utilized depends in part on the ability of crude oil and refined products infrastructure in the contiguous United States to absorb and adjust to the additional supply. Decisions about expanding North Slope production can use the National Transportation Fuels Model take into account the effects on crude oil flows in the contiguous United States.

  10. The effects of spilled oil on coastal ecosystems: Lessons from the Exxon Valdez spill: Chapter 11

    Science.gov (United States)

    Bodkin, James L.; Esler, Daniel N.; Rice, Stanley D.; Matkin, Craig O.; Ballachey, Brenda E.; Maslo, Brooke; Lockwood, Julie L.

    2014-01-01

    Oil spilled from ships or other sources into the marine environment often occurs in close proximity to coastlines, and oil frequently accumulates in coastal habitats. As a consequence, a rich, albeit occasionally controversial, body of literature describes a broad range of effects of spilled oil across several habitats, communities, and species in coastal environments. This statement is not to imply that spilled oil has less of an effect in pelagic marine ecosystems, but rather that marine spills occurring offshore may be less likely to be detected, and associated effects are more difficult to monitor, evaluate, and quantify (Peterson et al., 2012). As a result, we have a much greater awareness of coastal pollution, which speaks to our need to improve our capacities in understanding the ecology of the open oceans. Conservation of coastal ecosystems and assessment of risks associated with oil spills can be facilitated through a better understanding of processes leading to direct and indirect responses of species and systems to oil exposure.It is also important to recognize that oil spilled from ships represents only ~9% of the nearly 700 000 barrels of petroleum that enter waters of North America annually from anthropogenic sources (NRC, 2003). The immediate effects of large spills can be defined as acute, due to the obvious and dramatic effects that are observed. In contrast, the remaining 625 000 barrels that are released each year can be thought of as chronic non-point pollution, resulting from oil entering the coastal ocean as runoff in a more consistent but much less conspicuous rate. In this chapter, we primarily address the effects of large oil spills that occur near coastlines and consider their potential for both acute and chronic effects on coastal communities. As described below, in some instances, the effects from chronic exposure may meet or exceed the more evident acute effects from large spills. Consequently, although quantifying chronic effects

  11. Characterization and identification of Detroit River mystery oil spill (2002)

    International Nuclear Information System (INIS)

    Wang, Z.; Fingas, M.; Lambert, P.

    2003-01-01

    The authors described the mysterious oil spill which occurred in the Detroit River in 2002. Advanced chemical fingerprinting and data interpretation techniques were conducted on spill samples collected by Environment Canada, Ontario Region, to determine the chemical composition of the oil and find out where it came from. The objective was to gather information concerning the nature, type, and components of the spill samples. The authors checked if the samples were identical to determine if they originated from the same source. They used a tiered analytical approach which facilitates the detailed compositional analysis by gas chromatograph-mass spectrometer (GC-MS) and GC-flame ionization detection (FID). A wide range of diagnostic ratios of source-specific marker compounds for interpreting chemical data was determined and analyzed. The results proved that: (1) the spill samples were largely composed of lube oil mixed with a smaller portion of diesel fuel, (2) sample number 3 collected from N. Boblo Island was more weathered than samples 1 and 2, (3) the oil in three samples was the same and originated from the same source, as shown by fingerprinting results, (4) most PAH compounds were from the diesel portion in the spill samples, and the biomarker compounds were mostly from the lube oil, (5) the diesel in the samples had been weathered and degraded, and the lube oil in the spill samples was waste lube oil, and (6) input of pyrogenic PAHs to the spill samples was clearly proven. The spill likely came from a place where both combustion and motor lubrication processes occur. 46 refs., 4 tabs., 6 figs

  12. Results of laboratory tests on the potential for using in situ burning on seventeen crude oils

    International Nuclear Information System (INIS)

    McCourt, J.; Buist, I.; Buffington, S.

    2000-01-01

    The past five years at SL Ross (Ottawa) have been spent analysing seventeen crude oils to establish whether each oil could be cleaned up using an in situ burning technique in the event of a spill. The process involved a series of laboratory tests and controlled burns. The authors determined the emulsification characteristics, the limits to ignition imposed by evaporation and emulsion formation using a series of baseline burns, as well as the emulsion breaker burn test on emulsions that could not be ignited with gelled gas in the baseline burn test. They also determined the density, viscosity, and for some oils the interfacial tension, pour point, and flash point. The results obtained provided valuable information to be used in the case of a spill. They also indicated avenues to be followed in future research. 10 refs., 2 tabs

  13. Alkyl PAH in crude oil cause chronic toxicity to early life stages of fish. Volume 1

    Energy Technology Data Exchange (ETDEWEB)

    Hodson, P.V.; Khan, C.W.; Saravanabhavan, G.; Clarke, L.; Brown, R.S. [Queen' s Univ., Kingston, ON (Canada). School of Environmental Studies; Hollebone, B.; Wang, Z. [Environment Canada, Ottawa, ON (Canada). ; Short, J. [National Oceanic and Atmospheric Administration, Juneau, AK (United States). Auke Bay Lab; Lee, K.; King, T. [Fisheries and Oceans Canada, Dartmouth, NS (Canada). Centre for Offshore Oil and Gas Environmental Research

    2007-07-01

    In order to mitigate the risk to fisheries following an offshore oil spill, it is necessary to know the components of crude oil that are toxic. Chronic exposure of early life stages of fish to crude oil causes Blue Sac Disease, a syndrome characterized by induction of the cytochrome P450 (CYP1A) enzyme. In this study, effects-driven fractionation of Alaska North Slope Crude was used to identify the classes of compounds that cause CYP1A induction in juvenile rainbow trout and chronic toxicity to developing stages of Japanese medaka. Four fractions of compounds were created by low temperature vacuum distillation. This separated the constituents of oil according to their volatility within defined temperature ranges. The fractions were separated according to their boiling points. With a temperature range of 287-481 degrees C, fraction F3 was the only fraction as toxic as whole oil and induced CYPP1A enzymes of fish. Fractions containing specific classes of alkyl PAH were also collected. For all separations, the performance of the method was evaluated by the extent to which PAH were separated from aliphatics, resins and waxes, as well as by the quantitative recovery of mass in fractions and subfractions. The induction of CYP1A enzymes showed that PAH was present in all fractions that were highly toxic, but the toxicity tests indicated that not all fractions containing PAH were toxic. This research provided a scientific basis for comparing the risks of different crude oils based on chemical analyses that show the different proportions or amounts of PAH present. The results indicate which compounds of concern should be used to determine the extent and success of oil spill remediation, and provide a biological interpretation of chemical fingerprinting used to discriminate the sources of oil pollution. 15 refs., 1 tab.

  14. Alkyl PAH in crude oil cause chronic toxicity to early life stages of fish

    Energy Technology Data Exchange (ETDEWEB)

    Hodson, P.V.; Khan, C.W.; Saravanabhavan, G.; Clarke, L.; Brown, R.S. [Queen' s Univ., Kingston, ON (Canada). School of Environmental Studies; Hollebone, B.; Wang, Z. [Environment Canada, Ottawa, ON (Canada). ; Short, J. [National Oceanic and Atmospheric Administration, Juneau, AK (United States). Auke Bay Lab; Lee, K.; King, T. [Fisheries and Oceans Canada, Dartmouth, NS (Canada). Centre for Offshore Oil and Gas Environmental Research

    2007-07-01

    In order to mitigate the risk to fisheries following an offshore oil spill, it is necessary to know the components of crude oil that are toxic. Chronic exposure of early life stages of fish to crude oil causes Blue Sac Disease, a syndrome characterized by induction of the cytochrome P450 (CYP1A) enzyme. In this study, effects-driven fractionation of Alaska North Slope Crude was used to identify the classes of compounds that cause CYP1A induction in juvenile rainbow trout and chronic toxicity to developing stages of Japanese medaka. Four fractions of compounds were created by low temperature vacuum distillation. This separated the constituents of oil according to their volatility within defined temperature ranges. The fractions were separated according to their boiling points. With a temperature range of 287-481 degrees C, fraction F3 was the only fraction as toxic as whole oil and induced CYPP1A enzymes of fish. Fractions containing specific classes of alkyl PAH were also collected. For all separations, the performance of the method was evaluated by the extent to which PAH were separated from aliphatics, resins and waxes, as well as by the quantitative recovery of mass in fractions and subfractions. The induction of CYP1A enzymes showed that PAH was present in all fractions that were highly toxic, but the toxicity tests indicated that not all fractions containing PAH were toxic. This research provided a scientific basis for comparing the risks of different crude oils based on chemical analyses that show the different proportions or amounts of PAH present. The results indicate which compounds of concern should be used to determine the extent and success of oil spill remediation, and provide a biological interpretation of chemical fingerprinting used to discriminate the sources of oil pollution. 15 refs., 1 tab.

  15. Effects of a dual-pump crude-oil recovery system, Bemidji, Minnesota, USA

    Science.gov (United States)

    Delin, Geoffrey N.; Herkelrath, William N.

    2014-01-01

    A crude-oil spill occurred in 1979 when a pipeline burst near Bemidji, MN. In 1998, the pipeline company installed a dual-pump recovery system designed to remove crude oil remaining in the subsurface at the site. The remediation from 1999 to 2003 resulted in removal of about 115,000 L of crude oil, representing between 36% and 41% of the volume of oil (280,000 to 316,000 L) estimated to be present in 1998. Effects of the 1999 to 2003 remediation on the dissolved plume were evaluated using measurements of oil thicknesses in wells plus measurements of dissolved oxygen in groundwater. Although the recovery system decreased oil thicknesses in the immediate vicinity of the remediation wells, average oil thicknesses measured in wells were largely unaffected. Dissolved-oxygen measurements indicate that a secondary plume was caused by disposal of the pumped water in an upgradient infiltration gallery; this plume expanded rapidly immediately following the start of the remediation in 1999. The result was expansion of the anoxic zone of groundwater upgradient and beneath the existing natural attenuation plume. Oil-phase recovery at this site was shown to be challenging, and considerable volumes of mobile and entrapped oil remain in the subsurface despite remediation efforts.

  16. Oil spill research : salt water and fresh water

    International Nuclear Information System (INIS)

    Goodman, R.

    2006-01-01

    The difference in oil spill response activities between marine and freshwater environments were reviewed. Although containment, recovery and in-situ burning remain the same in both environments, the fate of oil is different due to water density and salinity considerations. The lower energy of lakes and the lack of major currents changes the advection of the oil. Rivers have high currents, and wind speed and direction are highly influenced by topographic effects. Tidal action is not a consideration for the inland situation, but water levels in rivers can change due to sudden rain events or the action of control devices upstream from the spill. Typically, the volume of oil released in freshwater environments is lower than in marine tanker situations, but spills from pipelines or a major train derailment can exceed 1000 m 3 . Since the use of water for human consumption and irrigation is another important factor in inland spills, it is important to have a means of obtaining information on the dynamics of spills and a system for archiving the response activities, such as the shoreline cleanup assessment technique (SCAT)and resulting cleanup. It was suggested that research studies must be undertaken to improve response strategies for freshwater spills. These include the dynamics of oil in freshwater environments such as rivers, lakes and sloughs; the role of oil-fine interactions in freshwater situations; the process involved in the formation of tar balls; and, the dynamics of oil in a freshwater situation. The response techniques that must be developed to improve the response to freshwater spills include techniques to remove oil from the bottom; techniques to filter and remove oil from the water column; and, development and testing of dispersants for freshwater environments

  17. Laboratory based degradation of light crude oil by aquatic ...

    African Journals Online (AJOL)

    STORAGESEVER

    2009-08-18

    Aug 18, 2009 ... This spilled oil produces destructive effect on the environment. For example, when ... growth was separated from the oil using gas chromatography. The hydrocarbon that dissolved in carbon tetrachloride ... Gasoline and gas oil were also degraded (Figure 1). ACKNOWLEDGEMENT. The authors wish to ...

  18. Major oil spills, St. Croix, U.S. Virgin Islands

    International Nuclear Information System (INIS)

    Bills, C.E.; Whiting, D.C.

    1990-01-01

    The destruction caused by Hurricane Hugo resulted in two major oil spills on the island of St. Croix, U.S. Virgin Islands. Roughly 10,000 barrels of oil were discharged from damaged storage tanks at the Hess Oil Virgin Island Corporation and 14,000 barrels of oil were discharged from the Virgin Islands Water and Power Authority facility in Christiansted. Pollution responders overcame the lack of power, water, food lodging, communications and transportation to perform an effective cleanup of these spills. This paper presents details of the pollution response effort as coordinated by the Federal On Scene Coordinator

  19. Nature preservation acceptance model applied to tanker oil spill simulations

    DEFF Research Database (Denmark)

    Friis-Hansen, Peter; Ditlevsen, Ove Dalager

    2003-01-01

    is exemplified by a study of oil spills due to simulated tanker collisions in the Danish straits. It is found that the distribution of the oil spill volume per spill is well represented by an exponential distribution both in Oeresund and in Great Belt. When applied in the Poisson model, a risk profile reasonably...... acceptance criterion for the pollution of the environment. This NPWI acceptance criterion is applied to the oil spill example....... be defined in a similar way as the so-called Life Quality Index defined by Nathwani et al [Nathwani JS, Lind NC, Padey MD. Affordable safety by choice: the life quality method. Institute for Risk Research, University of Waterloo; Waterloo (Ontario, Canada):1997], and can be used to quantify the risk...

  20. Impacts to Ecological Services: Buried Oil from the 2010 Deepwater Horizon Spill and Its Effect on Salt Marsh Denitrification

    Science.gov (United States)

    Levine, B. M.; White, J. R.; Delaune, R.

    2016-02-01

    In coastal Louisiana (LA), demands for ecosystem services are increasing while human activities continue to deteriorate coastal systems. On April 20, 2010, the largest offshore oil spill in United States history occurred in the Gulf of Mexico, known as the Deepwater Horizon (DWH) oil spill. Approximately 795 million L of crude oil were released, consequently oiling 1,773 km of Gulf Coast shoreline. Four years later, oil from the spill was found buried in the soil and seeping at the salt marsh surface in Bay Jimmy, LA. Previous studies found that immediately following oil exposure, wetland soils have suppressed microbial activity. This study seeks to understand effects of the long-term presence of oil on soil microbes and associated impacts to wetland soil denitrification. Bulk soil and intact soil cores were collected four years after the DWH spill from a heavily impacted salt marsh and a proximal site deemed unoiled in Barataria Bay, LA. Oil present in the soil subsurface increased dry weight bulk density, and decreased moisture content. Potential denitrification (acetylene block) in the top 10 cm of soil was 38% lower for oiled samples versus unoiled controls. Areal nitrate reduction rates were significantly lower in oiled samples in an intact core flux experiment under environmentally relevant nitrate conditions (2mg/L NO3-N), P-value ecosystem service of water quality improvement. Future studies should investigate impacts of oil being rebroadcasted onto marshes as land erodes in the study area.

  1. The Eurobulker oil spill: mid-term changes of some ecosystem indicators

    International Nuclear Information System (INIS)

    Zenetos, A.; Hatzianestis, J.; Lantzouni, M.; Simboura, M.; Sklivagou, E.; Arvanitakis, G.

    2004-01-01

    The sinking of the tanker Eurobulker in Southern Evoikos gulf (Aegean Sea, Greece) in September 2000 resulted in a spill of 700 tons of crude oil. The environmental impact of the spill was studied by the National Centre for Marine Research. The hydrocarbon concentrations in water, sediment and coastal benthic organisms were measured and the response of the benthic communities to the disturbance caused by the oil spill was studied along the direction to the coast and over three sampling seasons. The most severe and direct effects were evidenced on the muddy benthic communities of the accident site and the stations in the close vicinity sampled shortly after the spill. The effects included reduction of the species richness and community diversity, but the communities reached full recovery 8 months later. The impact of the spill was more indirect and delayed in the coastal stations, where as the hydrocarbon measurements indicated, the pollutants were transported later and induced their effects on the benthic communities 6 months after the accident. (author)

  2. New problems and opportunities of oil spill monitoring systems

    Directory of Open Access Journals (Sweden)

    G. M. Barenboim

    2015-04-01

    Full Text Available Emergency oil and oil products spills represent a great danger to the environment, including ecosystems, and to the population. New problems of such dangerous spills and methods of early detection are discussed in this paper. It is proposed to conduct assessment of biological hazards of such spills on the basis of data on the distribution of individual oil hydrocarbons within the column of the water body and computer predictions of their toxicity. Oil radioactivity, which is associated with uranium and thorium, is seen as the important aspect of the oil spill danger, especially in watercourses. The need for an automated monitoring system for the early detection of oil spills in water bodies is analysed. The proposed system consists of three subsystems. The first remote sensing subsystem is based on powerful fluorescent lidars; experimental results on lidar registration of oil pollution of water are reported. The second subsystem uses a network of automatic monitoring stations with contact detectors. The third subsystem is the combined sensor system based on remote and contact technologies.

  3. A comprehensive review of oil spill combustion studies

    International Nuclear Information System (INIS)

    Walavalkar, A.Y.; Kulkarni, A.K.

    1996-01-01

    The complex process of in-situ burning of oil or a water-in-oil emulsion floating on top of a water-base, such as the ocean, was discussed. The process was examined before, during and after actual combustion. In general, the success of oil spill combustion is measured in terms of the fraction of the spilled oil or emulsion that is burned away. However, the air and aquatic pollution caused by the combustion should also be considered. The physical conditions such as wind velocity, waves and the presence or absence of a containment device, such as a fire boom, could determine the continuation of the combustion process. An overview of the oil spill combustion techniques was provided. There still remains a need for fundamental studies, especially in mathematical modeling, to understand the basic mechanisms and predict the applicability of the in-situ combustion. 74 refs., 7 tabs., 3 figs

  4. Alberta oil sands crudes : upgrading and marketing

    International Nuclear Information System (INIS)

    Ashar, M.

    2008-01-01

    Open pit mining and in situ techniques, such as steam stimulation, are used to recover Alberta's bitumen and heavy oil resources, which have higher viscosities than conventional hydrocarbons. The bitumen is typically upgraded to synthetic crude oil (SCO). In the simplest processing scheme, the bitumen is blended with diluent for ease in pipeline transport and then processed at refineries with upgrading facilities. The bitumen is also upgraded to light SCO at world-scale upgraders in Alberta. The SCO is then processed at refineries in downstream markets. The 2 categories of upgrading, notably primary and secondary upgrading, were described in this article along with technology options for both categories. Slurry hydrocracking is regarded as the most interesting emerging residual fuel upgrading technology. It combines special catalyst mixes with the latest slurry reactor designs as well as innovative catalyst capture and recycle schemes to produce very high conversions and potentially superior upgrading economics. The increase in volume and rate of SCO from Alberta provides refiners in the oil sands marketing sector an unprecedented choice of opportunities to improve profitability. Key trends indicate that production will increase substantially from 2008 to 2030. 5 figs

  5. Alberta oil sands crudes : upgrading and marketing

    Energy Technology Data Exchange (ETDEWEB)

    Ashar, M. [Suncor Energy, Fort McMurray, AB (Canada)

    2008-05-15

    Open pit mining and in situ techniques, such as steam stimulation, are used to recover Alberta's bitumen and heavy oil resources, which have higher viscosities than conventional hydrocarbons. The bitumen is typically upgraded to synthetic crude oil (SCO). In the simplest processing scheme, the bitumen is blended with diluent for ease in pipeline transport and then processed at refineries with upgrading facilities. The bitumen is also upgraded to light SCO at world-scale upgraders in Alberta. The SCO is then processed at refineries in downstream markets. The 2 categories of upgrading, notably primary and secondary upgrading, were described in this article along with technology options for both categories. Slurry hydrocracking is regarded as the most interesting emerging residual fuel upgrading technology. It combines special catalyst mixes with the latest slurry reactor designs as well as innovative catalyst capture and recycle schemes to produce very high conversions and potentially superior upgrading economics. The increase in volume and rate of SCO from Alberta provides refiners in the oil sands marketing sector an unprecedented choice of opportunities to improve profitability. Key trends indicate that production will increase substantially from 2008 to 2030. 5 figs.

  6. Microbial activity in Alaskan taiga soils contaminated by crude oil in 1976

    International Nuclear Information System (INIS)

    Monroe, E.M.; Lindstrom, J.E.; Brown, E.J.; Raddock, J.F.

    1995-01-01

    Biodegradation, often measured via microbial activity, includes destruction of environmental pollutants by living microorganisms and is dependent upon many physical and chemical factors. Effects of mineral nutrients and organic matter on biodegradation of Prudhoe Bay crude oil were investigated at a nineteen-year-old oil spill site in Alaskan taiga. Microcosms of two different soil types from the spill site; one undeveloped soil with forest litter and detritus (O horizon) and one more developed with lower organic content (A horizon), were treated with various nitrogen and phosphorus amendments, and incubated for up to six weeks. Each microcosm was sampled periodically and assayed for hydrocarbon mineralization potential using radiorespirometry, for total carbon dioxide respired using gas chromatography, and for numbers of hydrocarbon-degrading bacteria and heterotrophic bacteria using most probable number counting techniques. Organic matter in the O horizon soil along with combinations of mineral nutrients were found to stimulate microbial activity. No combination of mineral nutrient additions to the A horizon soil stimulated any of the parameters above those measured in control microcosms. The results of this study indicate that adding mineral nutrients and tilling the O horizon into the A horizon of subarctic soils contaminated with crude oil, would stimulate microbial activity, and therefore the biodegradation potential, ultimately increasing the rate of destruction of crude oil in these soils

  7. Process for removing heavy metal compounds from heavy crude oil

    Science.gov (United States)

    Cha, Chang Y.; Boysen, John E.; Branthaver, Jan F.

    1991-01-01

    A process is provided for removing heavy metal compounds from heavy crude oil by mixing the heavy crude oil with tar sand; preheating the mixture to a temperature of about 650.degree. F.; heating said mixture to up to 800.degree. F.; and separating tar sand from the light oils formed during said heating. The heavy metals removed from the heavy oils can be recovered from the spent sand for other uses.

  8. The deepwater horizon oil spill coast guard cohort study: A cross-sectional study of acute respiratory health symptoms.

    Science.gov (United States)

    Alexander, Melannie; Engel, Lawrence S; Olaiya, Nathan; Wang, Li; Barrett, John; Weems, Laura; Schwartz, Erica G; Rusiecki, Jennifer A

    2018-04-01

    Over 8500 United States Coast Guard (USCG) personnel were deployed in response to the Deepwater Horizon (DWH) oil spill; however, human respiratory effects as a result of spill-related exposures are relatively unknown. USCG personnel who responded to the DWH oil spill were queried via survey on exposures to crude oil and oil dispersant, and acute respiratory symptoms experienced during deployment. Adjusted log binomial regressions were used to calculate prevalence ratios (PRs) and 95% confidence intervals (CI), investigating the associations between oil spill exposures and respiratory symptoms. 4855 USCG personnel completed the survey. More than half (54.6%) and almost one-fourth (22.0%) of responders were exposed to crude oil and oil dispersants, respectively. Coughing was the most prevalent symptom (19.4%), followed by shortness of breath (5.5%), and wheezing (3.6%). Adjusted analyses showed an exposure-response relationship between increasing deployment duration and likelihood of coughing, shortness of breath, and wheezing in the pre-capping period. A similar pattern was observed in the post-capping period for coughing and wheezing. Adjusted analyses revealed increased PRs for coughing (PR=1.92), shortness of breath (PR=2.60), and wheezing (PR=2.68) for any oil exposure. Increasing frequency of inhalation of oil was associated with increased likelihood of all three respiratory symptoms. A similar pattern was observed for contact with oil dispersants for coughing and shortness of breath. The combination of both oil and oil dispersants presented associations that were much greater in magnitude than oil alone for coughing (PR=2.72), shortness of breath (PR=4.65), and wheezing (PR=5.06). Results from the present study suggested strong relationships between oil and oil dispersant exposures and acute respiratory symptoms among disaster responders. Future prospective studies will be needed to confirm these findings. Copyright © 2017 Elsevier Inc. All rights reserved.

  9. British Columbia inland oil spill response plan

    International Nuclear Information System (INIS)

    2005-01-01

    This paper presents an outline of the organization, procedures and duties of the provincial government in response to inland oil spills stemming from pipeline or tank-farm rupture, train derailment and vehicle accidents in British Columbia. Provincial response strategies were reviewed, along with their relationships to various policies and standards. Public, infrastructure and environmental protection were identified as key factors. Incident notification procedures were detailed, including outlines of roles, event criteria and call for incident management teams. Agreements and cost recovery issues were examined. The characteristics of site response were reviewed, including details of communications, tactical planning, and unified command among local and federal governments. The role of First Nations and responsible parties was also addressed. Details of shore cleanup, wildlife rescue, decontamination, and waste handling strategies were presented. The organization, missions and duties for an incident management team were outlined, along with a summary of operational guidelines and information on team positions and the establishment of joint information centres. The involvement of cooperating agencies was examined. An incident command system was also presented, including details of planning, operations, logistics, and organization. A checklist of individual duties was provided, with details of responsibilities, safety issues and general instructions for all team members. tabs., figs

  10. Improving oil classification quality from oil spill fingerprint beyond six sigma approach.

    Science.gov (United States)

    Juahir, Hafizan; Ismail, Azimah; Mohamed, Saiful Bahri; Toriman, Mohd Ekhwan; Kassim, Azlina Md; Zain, Sharifuddin Md; Ahmad, Wan Kamaruzaman Wan; Wah, Wong Kok; Zali, Munirah Abdul; Retnam, Ananthy; Taib, Mohd Zaki Mohd; Mokhtar, Mazlin

    2017-07-15

    This study involves the use of quality engineering in oil spill classification based on oil spill fingerprinting from GC-FID and GC-MS employing the six-sigma approach. The oil spills are recovered from various water areas of Peninsular Malaysia and Sabah (East Malaysia). The study approach used six sigma methodologies that effectively serve as the problem solving in oil classification extracted from the complex mixtures of oil spilled dataset. The analysis of six sigma link with the quality engineering improved the organizational performance to achieve its objectivity of the environmental forensics. The study reveals that oil spills are discriminated into four groups' viz. diesel, hydrocarbon fuel oil (HFO), mixture oil lubricant and fuel oil (MOLFO) and waste oil (WO) according to the similarity of the intrinsic chemical properties. Through the validation, it confirmed that four discriminant component, diesel, hydrocarbon fuel oil (HFO), mixture oil lubricant and fuel oil (MOLFO) and waste oil (WO) dominate the oil types with a total variance of 99.51% with ANOVA giving F stat >F critical at 95% confidence level and a Chi Square goodness test of 74.87. Results obtained from this study reveals that by employing six-sigma approach in a data-driven problem such as in the case of oil spill classification, good decision making can be expedited. Copyright © 2017. Published by Elsevier Ltd.

  11. Biodispersant production by sea bacteria and its application to oil spills at sea

    International Nuclear Information System (INIS)

    Mayol, M.A.; Pita, A.; Bergueiro, J.R.; Rallo, M.; Somoza, S.

    1998-01-01

    The feasibility of developing natural dispersants (biodispersants) for use in response to a marine oil spill was discussed. In this study biochemical tests were conducted with Bacillus and Coccus Gram Positive bacteria in order to select the one marine microorganism which is capable of producing biodispersants to degrade crude oil. Different carbon sources and salt concentrations were used in the experiments. A second experiment was conducted in which the production of biodispersants by the pure microbial strain were studied by measuring interfacial tension, determined by using the Longman method. The surfactant efficacy and the dispersant stability of Arabian Light crude oil was also studied. The biological oxygen demand at five days, biological oxygen demand at the end of the biodegradation, the biodegradation constant and the biochemical stabilization constant were determined during the degradation process. 23 refs., 9 tabs.,4 figs

  12. Process of cleaning oil spills and the like

    International Nuclear Information System (INIS)

    Breisford, J.A.

    1993-01-01

    A process of cleaning spills of toxic or hazardous materials such as oil, antifreeze, gasoline, and the like from bodies of water, garage floors, roadways and the like, comprising spraying unbonded shredded fiberglass blowing wool composition particles onto the spill, absorbing the spill into the shredded fiberglass blowing wool composition particles, and removing the soaked shredded fiberglass blowing wool composition particles and the spill absorbed therein. An absorbent composition for absorbing spills of toxic or hazardous materials such as oil, antifreeze, gasoline, and like, comprising shredded fiberglass blowing wool particles, and means for absorbing the spill and for stiffening the co-position so that the composition fights against being compressed so that less of the absorbed spill escapes from the composition when it is being removed from the spill, said means including cork particles dispersed in with the fiberglass blowing wool particles. An absorbent sock for absorbing or containing a spill of toxic or hazardous materials such as oil, antifreeze, gasoline, and the like, comprising a hollow tube, said tube being permeable to the toxic or hazardous materials and being made of nylon or polypropylene, and unbonded, shredded fiberglass blowing wool composition particles enclosed in the tube. Apparatus for controlling an oil slick on the surface of water, comprising a craft for traversing the slick, a supply of fiberglass blowing wool composition particles stored on the craft in position for being dispersed, shredding means on the craft for shredding the fiberglass blowing wool particles to form unbonded, shredded fiberglass blowing wool particles, and dispensing means on the craft for dispensing the unbonded, shredded fiberglass blowing wool particles onto the slick

  13. Studies on crude oil removal from pebbles by the application of biodiesel.

    Science.gov (United States)

    Xia, Wen-xiang; Xia, Yan; Li, Jin-cheng; Zhang, Dan-feng; Zhou, Qing; Wang, Xin-ping

    2015-02-15

    Oil residues along shorelines are hard to remove after an oil spill. The effect of biodiesel to eliminate crude oil from pebbles alone and in combination with petroleum degrading bacteria was investigated in simulated systems. Adding biodiesel made oil detach from pebbles and formed oil-biodiesel mixtures, most of which remained on top of seawater. The total petroleum hydrocarbon (TPH) removal efficiency increased with biodiesel quantities but the magnitude of augment decreased gradually. When used with petroleum degrading bacteria, the addition of biodiesel (BD), nutrients (NUT) and BD+NUT increased the dehydrogenase activity and decreased the biodegradation half lives. When BD and NUT were replenished at the same time, the TPH removal efficiency was 7.4% higher compared to the total improvement of efficiency when BD and NUT was added separately, indicating an additive effect of biodiesel and nutrients on oil biodegradation. Copyright © 2014 Elsevier Ltd. All rights reserved.

  14. Crude oil degradation by Bacillus and Micrococcus species isolated ...

    African Journals Online (AJOL)

    Microorganisms capable of degrading crude oil were isolated from soil compost in Kano, northwestern Nigeria. The work was carried out with the aim of determining crude-oil biodegradation potentials of Bacillus and Micrococcus species isolated from the soil compost as well as the assessment of the applicability of ...

  15. Remediation trials of crude oil contaminated soil using different ...

    African Journals Online (AJOL)

    A 3 month remediation trial of the use of detergent and sawdust in different combination forms in the restoration of a crude oil contaminated tropical soil was investigated. 8 remediation treatments labeled A – H in addition to the control (I) were used in 10 kg soil artificially polluted with 300 ml crude oil each. Remediation ...

  16. Toxicity of crude oil products and detergent on serum alkaline ...

    African Journals Online (AJOL)

    The comparative effect of exposing Clarias gariepinus juveniles (100.20 + 0.8g) to diferent concentrations of crude oil products and detergent were studied. Bonny Light Crude oil (BLCO), Premium motor spirit (PMS), Dual purpose kerosene (DPK) and Ariel Enzymax Detergent (AED) were respectively applied at three ...

  17. Manihot esculenta crantz in crude oil contaminated soil amended ...

    African Journals Online (AJOL)

    Studies on the performance of Manihot esculenta, Crantz (TMS 30572) in a crude oil polluted soil was investigated in the Botanic Garden of University of Port Harcourt. The soil samples were polluted at four different levels (0%, 2%, 4% and 6%) with crude oil and amended with organic supplement (decomposed Centrosem ...

  18. On-site monitoring of Hebei Spirit oil spill by fluorometric detection of oil residues in coastal waters off Taean, Korea

    Energy Technology Data Exchange (ETDEWEB)

    Kim, M.; Yim, U.H.; Hong, S.H.; Jung, J.H.; Won, J.; An, J.; Choi, H.W.; Shim, W.J. [Korea Ocean Research and Development Inst., Geoje (Korea, Republic of)

    2009-07-01

    This paper discussed activities conducted to monitor a crude oil spill that contaminated over 70 km of the western Korean coastline. Contamination levels and temporal variations of dissolved and dispersed oils in sea and pore water at 40 beaches were monitored using a portable fluorimeter for 10 months after the spill. More than 980 samples from the heavily-impacted Mallipo Beach area were analyzed. The analysis showed that oil concentrations in the sea water were as high as 16,600 {mu}g/L directly after the spill, and decreased to below the Korean marine water quality standard of 10 {mu}g/L at most sites 10 months after the spill. However, the oil content in pore water remained high, with levels of up to 2,320 {mu}g/L for the first few months following the spill. Higher oil contamination levels were observed at some sites for up to 10 months after the spill. Results of the study suggested that oil in pore water persisted in confined areas along the coastline. Results from the fluorescence detection technique were then compared with traditional gas chromatography (GC) techniques of total petroleum hydrocarbon analysis. It was concluded that fluorescence detection was capable of generating accurate results more quickly and cost-effectively than traditional GC techniques. 22 refs., 7 figs.

  19. Crude oil options market found to be efficient

    International Nuclear Information System (INIS)

    Anon.

    1992-01-01

    This paper reports that the U.S. crude oil options market operates efficiently and does not overreact. The authors, with the JFK School of Government, studied the crude oil options market under a Department of Energy grant. The current market was created in November 1986 when the New York Mercantile Exchange introduced an options contract for delivery of West Texas intermediate crude futures. it has grown greatly since then

  20. European Atlantic: the hottest oil spill hotspot worldwide

    Science.gov (United States)

    Vieites, David R.; Nieto-Román, Sandra; Palanca, Antonio; Ferrer, Xavier; Vences, Miguel

    2004-11-01

    Oil spills caused by maritime transport of petroleum products are still an important source of ocean pollution, especially in main production areas and along major transport routes. We here provide a historical and geographic analysis of the major oil spills (>700 t) since 1960. Spills were recorded from several key marine ecosystems and marine biodiversity hotspots. The past four decades have been characterized by an overall decrease in the number of accidents and tonnes of oil spilled in the sea, but this trend was less distinct in the European Atlantic area. Recent black tides from the Erika and Prestige vessels provided new evidence for the high risk of accidents with serious ecological impact in this area, which according to our analysis is historically the most important oil spill hotspot worldwide. The English Channel and waters around Galicia in Spain were the areas with most accidents. Maritime transport in European Atlantic waters has been predicted to continue increasing. Together with our own results this suggests that, in addition to measures for increased traffic safety, deployment of emergency capacities in the spill hotspot areas may be crucial for a sustainable conservation of sea resources and ecosystems.

  1. Oil spill sorbents: Testing protocol and certification listing program

    International Nuclear Information System (INIS)

    Cooper, D.; Gausemel, I.

    1993-01-01

    Environment Canada's Emergencies Engineering Division is spearheading a program in conjunction with the Canadian General Standards Board that would see the development of a certification and listing program in addition to a national standard for the testing of sorbent materials. Funding for this program is provided by Environment Canada (EC), Canadian Coast Guard (CCG), Marine Spill Response Corporation (MSRC), US Coast Guard (USCG), and US Minerals Management Service (MMS). The test methods are based upon those defined by the American Society for Testing and Materials and previous test methods developed by Environment Canada for our series of reports entitled Selection Criteria and Laboratory Evaluation of Oil Spill Sorbents. This series, which was started in 1975, encompasses a number of commercially available oil spill sorbents tested with different petroleum products and hydrocarbon solvents. The testing program will categorize the sorbents according to their operating characteristics. The main categories are oil spills on water, oil spills on land, and industrial use. The characteristics to be evaluated with the new test protocols include initial and maximum sorption capacities, water pickup, buoyancy, reuse potential, retention profile, disintegration (material integrity), and ease of application and retrieval. In the near future are plans to incorporate changes to the test that would involve increasing the list of test liquids to encompass spills in an industrial setting, in addition to testing sorbent booms and addressing the disposal problem

  2. Oil spills and other issues in the aftermath of Hurricanes Katrina and Rita : an overview

    International Nuclear Information System (INIS)

    Davis, D.W.

    2006-01-01

    The aftermath of Hurricane Katrina revealed weaknesses in the command, control, communications, and information dissemination functions within a variety of emergency response systems. This paper gave an outline of clean-up procedures involving hazardous materials. To date, clean-up crews have disposed of 8.0 million tonnes of an estimated 22.0 million tonnes of debris. The clean-up involved more than 1.3 million containerized hazardous materials; more than 230,000 damaged white goods; and nearly 43,000 damaged electronic goods. More than 3,400 samples of water, soil and air have been collected. Nearly 75 chemistry laboratories in schools have been inspected, and an additional 1500 emergency assessments of potential chemical releases were investigated. The floodwaters carried nearly 4.1 million litres of oil from a Chalmette refinery. Between September and the end of 2005, the Louisiana Oil Spill Coordinator's Office logged in 81 spill events in southwest Louisiana involving 22,000 bbls of crude. Six major, 3 medium and 131 minor events have occurred in southeast Louisiana. More than 3000 offshore platforms were shut down or damaged during the 2005 hurricane season. At least 115 platforms were destroyed and 52 were damaged. Onshore spills of concern included incidents at Murphy Oil Refinery; Bass Enterprise Production Company; Chevron at Port Fourchon; Venice Energy Services Company; Shell Pipeline; and Sundown Energy. It was concluded work done by the spill community will result in the development of more effective response plans. 23 refs

  3. Development of a field testing protocol for identifying Deepwater Horizon oil spill residues trapped near Gulf of Mexico beaches

    Science.gov (United States)

    Han, Yuling

    2018-01-01

    The Deepwater Horizon (DWH) accident, one of the largest oil spills in U.S. history, contaminated several beaches located along the Gulf of Mexico (GOM) shoreline. The residues from the spill still continue to be deposited on some of these beaches. Methods to track and monitor the fate of these residues require approaches that can differentiate the DWH residues from other types of petroleum residues. This is because, historically, the crude oil released from sources such as natural seeps and anthropogenic discharges have also deposited other types of petroleum residues on GOM beaches. Therefore, identifying the origin of these residues is critical for developing effective management strategies for monitoring the long-term environmental impacts of the DWH oil spill. Advanced fingerprinting methods that are currently used for identifying the source of oil spill residues require detailed laboratory studies, which can be cost-prohibitive. Also, most agencies typically use untrained workers or volunteers to conduct shoreline monitoring surveys and these worker will not have access to advanced laboratory facilities. Furthermore, it is impractical to routinely fingerprint large volumes of samples that are collected after a major oil spill event, such as the DWH spill. In this study, we propose a simple field testing protocol that can identify DWH oil spill residues based on their unique physical characteristics. The robustness of the method is demonstrated by testing a variety of oil spill samples, and the results are verified by characterizing the samples using advanced chemical fingerprinting methods. The verification data show that the method yields results that are consistent with the results derived from advanced fingerprinting methods. The proposed protocol is a reliable, cost-effective, practical field approach for differentiating DWH residues from other types of petroleum residues. PMID:29329313

  4. Development of a field testing protocol for identifying Deepwater Horizon oil spill residues trapped near Gulf of Mexico beaches.

    Science.gov (United States)

    Han, Yuling; Clement, T Prabhakar

    2018-01-01

    The Deepwater Horizon (DWH) accident, one of the largest oil spills in U.S. history, contaminated several beaches located along the Gulf of Mexico (GOM) shoreline. The residues from the spill still continue to be deposited on some of these beaches. Methods to track and monitor the fate of these residues require approaches that can differentiate the DWH residues from other types of petroleum residues. This is because, historically, the crude oil released from sources such as natural seeps and anthropogenic discharges have also deposited other types of petroleum residues on GOM beaches. Therefore, identifying the origin of these residues is critical for developing effective management strategies for monitoring the long-term environmental impacts of the DWH oil spill. Advanced fingerprinting methods that are currently used for identifying the source of oil spill residues require detailed laboratory studies, which can be cost-prohibitive. Also, most agencies typically use untrained workers or volunteers to conduct shoreline monitoring surveys and these worker will not have access to advanced laboratory facilities. Furthermore, it is impractical to routinely fingerprint large volumes of samples that are collected after a major oil spill event, such as the DWH spill. In this study, we propose a simple field testing protocol that can identify DWH oil spill residues based on their unique physical characteristics. The robustness of the method is demonstrated by testing a variety of oil spill samples, and the results are verified by characterizing the samples using advanced chemical fingerprinting methods. The verification data show that the method yields results that are consistent with the results derived from advanced fingerprinting methods. The proposed protocol is a reliable, cost-effective, practical field approach for differentiating DWH residues from other types of petroleum residues.

  5. Significance of cytochrome P450 system responses and levels of bile fluorescent aromatic compounds in marine wildlife following oil spills

    International Nuclear Information System (INIS)

    Lee, R.F.; Anderson, J.W.

    2005-01-01

    The relationships among cytochrome P450 induction in marine wildlife species, levels of fluorescent aromatic compounds (FAC) in their bile, the chemical composition of the inducing compounds, the significance of the exposure pathway, and any resulting injury, as a consequence of exposure to crude oil following a spill, are reviewed. Fish collected after oil spills often show increases in cytochrome P450 system activity, cytochrome P4501A (CYP1A) and bile fluorescent aromatic compounds (FAC), that are correlated with exposure to polycyclic aromatic hydrocarbons (PAH) in the oil. There is also some evidence for increases in bile FAC and induction of cytochrome P450 in marine birds and mammals after oil spills. However, when observed, increases in these exposure indicators are transitory and generally decrease to background levels within one year after the exposure. Laboratory studies have shown induction of cytochrome P450 systems occurs after exposure of fish to crude oil in water, sediment or food. Most of the PAH found in crude oil (dominantly 2- and 3-ring PAH) are not strong inducers of cytochrome P450. Exposure to the 4-ring chrysenes or the photooxidized products of the PAH may account for the cytochrome P450 responses in fish collected from oil-spill sites. The contribution of non-spill background PAH, particularly combustion-derived (pyrogenic) PAH, to bile FAC and cytochrome P450 system responses can be confounding and needs to be considered when evaluating oil spill effects. The ubiquity of pyrogenic PAH makes it important to fully characterize all sources of PAH, including PAH from natural resources, e.g. retene, in oil spill studies. In addition, such parameters as species, sex, age, ambient temperature and season need to be taken into account. While increases in fish bile FAC and cytochrome P450 system responses, can together, be sensitive general indicators of PAH exposure after an oil spill, there is little unequivocal evidence to suggest a linkage to

  6. Analysis of potential effects of the Idoho-QIT oil spill on river-estuarine fisheries in Nigeria

    International Nuclear Information System (INIS)

    Inyang, L.E.D.; Essien, G.E.; Gundlach, E.R.; Moses, B.S.; Gilfillan, E.S.; Page, D.S.

    2002-01-01

    40,000 bbls of Nigerian crude oil were released into the offshore waters of Nigeria when a 24-inch pipeline ruptured offshore of the Mobil Qua Iboe Terminal on January 12, 1998. Most of the oil was dispersed by natural processes and by the application of 299 bbls of dispersants. There was very limited contact of the oil with shoreline and estuaries of Nigeria. Several short and long term studies into the health and socio-economic impacts of the spill were conducted to determine the impacts. In particular, this paper discusses the evaluation of river-mouth fisheries using pre-spill data, data obtained during the spill, and data obtain 9 to 12 months following the spill. Catch rates, fisheries composition, and fish tissue chemistry was reviewed. It was determined that catch rates in the spill zone and control areas were within the historical range expected in the rainy season. There was no major difference in species composition values within the study and those expected for the rainy season. A rich and diverse fish population was found to exist in the spill zone, suggesting that there was no detectable effects of the spill. Concentrations of copper, lead, cadmium, zinc, mercury, nickel and vanadium were below recommended limits. None of the metals are indicative of petroleum in fish tissues. Total lipids were also well below 25 ppm. 31 refs., 11 tabs., 1 fig

  7. E-beam radiolysis for oil spill clean up

    International Nuclear Information System (INIS)

    Patterson, E.L.; Jackson, N.B.; Thornberg, S.M.; Samlin, G.E.

    1992-12-01

    This paper describes preliminary experiments to investigate electron-beam radiolysis of model compounds appropriate for crude oil spills on water or soil. Since no previous work in this area is known to exist, the rate of destruction of such concentrated organic materials in aqueous media is not known. The experiments conducted here were designed to provide preliminary estimates of the destruction rate and the estimated costs. Samples of model compounds were irradiated to dose levels up to 700 Mrad (H 2 0) and the change in chemical composition was determined by mass spectrometry/gas chromatography and Fourier transform infrared spectroscopy. It was found that a dose of 700 Mrads reduced the liquid volume of the model compound by 60% and that the major effect of irradiation was the formation of long chain alkanes and dimethyl and ethyl benzenes. Under certain conditions a solid polymer was found to form. When alcohol was present in the model compound, additional products included small quantities of ethane diodic acid, butanol, butanediol, and various other alcohols. Further research is recommended to obtain a better analysis of the products, better values for the destruction rates, and better understanding of dose rate effects

  8. Securing the Safety of Nuclear Power Plants against Oil Spill Accidents at Sea

    International Nuclear Information System (INIS)

    Hyun, Seung Gyu; Choi, Ho Seon; Kim, Sang Yun

    2008-01-01

    As of 2008, 20 nuclear power plants are under operation and six plants are under construction in Korea. NPPs account for approximately 38% of Korea's electric power production; however, it is expected that the share of power produced by NPPs will be further increased to reduce the level of CO 2 emissions, taking into account the concern over global warming. All of NPPs in Korea are located on the coast to facilitate the supply of cooling water sources. Thus, tar and other floating matters from vessels following oil spill accidents at sea may affect intake systems, and consequently interrupt the supply of cooling water. This study will review cases of response measures taken by NPPs against large-scale crude oil spill accidents that had occurred off the coast of Korea, including such accidents as the Sea Prince (July 23, 1995) and the Hebei Sprit(December 7, 2007), and relevant regulatory requirements at home and abroad

  9. Natural resource injury at oil spills: A new approach

    International Nuclear Information System (INIS)

    Cecil, G.R.

    1993-01-01

    1993 is a critical time to review the actions taken at past spills and to formulate a new approach to natural resource injury at oil spills. The Oil Pollution Act of 1990 has replaced the oil spill provisions of the Clean Water Act, and new regulations to govern natural resource damage assessments are due to be published by the National Oceanic and Atmospheric Administration (NOAA) this year. The new law and regulations provide impetus for new directions. The new approach advocates cooperative damage assessments utilizing the new NOAA procedures. Litigation must be regarded as a last resort because it does not foster the goals of either the trustees or the oil industry. There are significant advantages to both trustees and industry from this approach

  10. Oil spill contamination probability in the southeastern Levantine basin.

    Science.gov (United States)

    Goldman, Ron; Biton, Eli; Brokovich, Eran; Kark, Salit; Levin, Noam

    2015-02-15

    Recent gas discoveries in the eastern Mediterranean Sea led to multiple operations with substantial economic interest, and with them there is a risk of oil spills and their potential environmental impacts. To examine the potential spatial distribution of this threat, we created seasonal maps of the probability of oil spill pollution reaching an area in the Israeli coastal and exclusive economic zones, given knowledge of its initial sources. We performed simulations of virtual oil spills using realistic atmospheric and oceanic conditions. The resulting maps show dominance of the alongshore northerly current, which causes the high probability areas to be stretched parallel to the coast, increasing contamination probability downstream of source points. The seasonal westerly wind forcing determines how wide the high probability areas are, and may also restrict these to a small coastal region near source points. Seasonal variability in probability distribution, oil state, and pollution time is also discussed. Copyright © 2014 Elsevier Ltd. All rights reserved.

  11. Oil spill research program, U. S. Minerals Management Service

    International Nuclear Information System (INIS)

    LaBelle, R. P.; Mullin, J. V.; White, A. C.

    1997-01-01

    The oil spill prevention and response research program of the U.S. Minerals Management Service was described including its goals and objectives, some recently funded projects, and future research directions. As it is now the trend in most research organizations, a large part of the program is carried out in cooperation with other major research centers to leverage funds and to maximize study results. For example, joint research with Environment Canada focuses on the physical and chemical properties of dispersants, remote sensing and mapping oil slicks and shoreline cleanup strategies. Similarly, cooperative projects are underway with the National Institute of Standards and Technology in assessing the capabilities of in-situ burning as an oil spill response tool. Research capabilities of OHMSETT - The National Oil Spill Response Test Facility were also reviewed. A series of tables listed titles of research projects completed during 1995-1996. 5 tabs.,

  12. Hebei Spirit Oil Spill Exposure and Subjective Symptoms in Residents Participating in Clean-Up Activities

    Science.gov (United States)

    Cheong, Hae-Kwan; Lee, Jong Seong; Kwon, Hojang; Ha, Eun-Hee; Hong, Yun-Chul; Choi, Yeyong; Jeong, Woo-Chul; Hur, Jongil; Lee, Seung-Min; Kim, Eun-Jung; Im, Hosub

    2011-01-01

    Objectives This study was conducted to examine the relationship between crude oil exposure and physical symptoms among residents participating in clean-up work associated with the Hebei Spirit oil spill, 2007 in Korea. Methods A total of 288 residents responded to a questionnaire regarding subjective physical symptoms, sociodemographic characteristics and clean-up activities that occurred between two and eight weeks after the accident. Additionally, the urine of 154 of the respondents was analyzed for metabolites of volatile organic compounds (VOCs) and polycyclic aromatic hydrocarbons (PAHs) and heavy metals. To compare the urinary levels of exposure biomarkers, the urine of 39 inland residents who were not directly exposed to the oil spill were analyzed. Results Residents exposed to oil remnants through clean-up work showed associations between physical symptoms and the exposure levels defined in various ways, including days of work, degree of skin contamination, and levels of some urinary exposure biomarkers of VOCs, metabolites and metals, although no major abnormalities in urinary exposure biomarkers were observed. Conclusions This study provides evidence of a relationship between crude oil exposure and acute human health effects and suggests the need for follow-up to evaluate the exposure status and long-term health effects of clean-up participants. PMID:22125768

  13. 161 EVALUATION OF ON-SHORE OIL SPILL REMEDIATION ...

    African Journals Online (AJOL)

    EVALUATION OF ON-SHORE OIL SPILL REMEDIATION OPERATIONS IN. PORT HARCOURT ... study is an attempt to unravel the effectiveness of clean-up exercises undertaken by oil .... Research Design. The study ..... remediation as well as tilling and evacuation of affected soils would certainly be more productive.

  14. Impact of oil spill on intertidal organisms in Bahrain

    International Nuclear Information System (INIS)

    Mohamed, S.A.

    1991-01-01

    This paper reports on a study carried out after a major oil spill hit the coasts of Bahrain in 1988. A total of fifteen stations around the Island of Bahrain were monitored for a period of six months in order to measure the impact of the spill on marine organisms and in particular those living in the intertidal zone. Large quantities of heavy hydrocarbons accumulated on the shores and caused death or serious damage to many organisms, including birds and fishes. The spill first hit the northwest shores. The oil spill was also reported to be the main factor in damaging the traditional fishing traps in the coastal waters, which caused serious effects on the fish catch for seven months

  15. A case study of consensus modelling for tracking oil spills

    International Nuclear Information System (INIS)

    King, Brian; Brushett, Ben; Lemckert, Charles

    2010-01-01

    Metocean forecast datasets are essential for the timely response to marine incidents and pollutant spill mitigation at sea. To effectively model the likely drift pattern and the area of impact for a marine spill, both wind and ocean current forecast datasets are required. There are two ocean current forecast models and two wind forecast models currently used operationally in the Australia and Asia Pacific region. The availability of several different forecast models provides a unique opportunity to compare the outcome of a particular modelling exercise with the outcome of another using a different model and determining whether there is consensus in the results. Two recent modelling exercises, the oil spill resulting from the damaged Pacific Adventurer (in Queensland) and the oil spill from the Montara well blowout (in Western Australia) are presented as case studies to examine consensus modelling.

  16. Oil spill response engineering and planning. Technical completion report

    International Nuclear Information System (INIS)

    Swift, M.R.; Celikkol, B.; Goodwin, C.E.; Carrier, R.; McDonald, S.P.

    1991-12-01

    Tanker and barge traffic associated with the five petroleum product terminals along the NH side of the Piscataqua River represents a constant oil spill threat to the contiguous Great Bay System, NH, an estuarine reserve. Several serious accidents have in fact taken place in the 1970's and two small spills in 1990. A major factor is that the Piscataqua channel is subject to high velocity tidal currents. Should a spill occur, problems arise in knowing where the slick will move and how to control it using booms. In the project, these problems were addressed by developing procedures for using diversion booms in high speed current environments and in revising and implementing a previously developed Oil Spill Trajectory Model

  17. Crude oil treatment leads to shift of bacterial communities in soils from the deep active layer and upper permafrost along the China-Russia Crude Oil Pipeline route.

    Science.gov (United States)

    Yang, Sizhong; Wen, Xi; Zhao, Liang; Shi, Yulan; Jin, Huijun

    2014-01-01

    The buried China-Russia Crude Oil Pipeline (CRCOP) across the permafrost-associated cold ecosystem in northeastern China carries a risk of contamination to the deep active layers and upper permafrost in case of accidental rupture of the embedded pipeline or migration of oil spills. As many soil microbes are capable of degrading petroleum, knowledge about the intrinsic degraders and the microbial dynamics in the deep subsurface could extend our understanding of the application of in-situ bioremediation. In this study, an experiment was conducted to investigate the bacterial communities in response to simulated contamination to deep soil samples by using 454 pyrosequencing amplicons. The result showed that bacterial diversity was reduced after 8-weeks contamination. A shift in bacterial community composition was apparent in crude oil-amended soils with Proteobacteria (esp. α-subdivision) being the dominant phylum, together with Actinobacteria and Firmicutes. The contamination led to enrichment of indigenous bacterial taxa like Novosphingobium, Sphingobium, Caulobacter, Phenylobacterium, Alicylobacillus and Arthrobacter, which are generally capable of degrading polycyclic aromatic hydrocarbons (PAHs). The community shift highlighted the resilience of PAH degraders and their potential for in-situ degradation of crude oil under favorable conditions in the deep soils.

  18. Crude oil treatment leads to shift of bacterial communities in soils from the deep active layer and upper permafrost along the China-Russia Crude Oil Pipeline route.

    Directory of Open Access Journals (Sweden)

    Sizhong Yang

    Full Text Available The buried China-Russia Crude Oil Pipeline (CRCOP across the permafrost-associated cold ecosystem in northeastern China carries a risk of contamination to the deep active layers and upper permafrost in case of accidental rupture of the embedded pipeline or migration of oil spills. As many soil microbes are capable of degrading petroleum, knowledge about the intrinsic degraders and the microbial dynamics in the deep subsurface could extend our understanding of the application of in-situ bioremediation. In this study, an experiment was conducted to investigate the bacterial communities in response to simulated contamination to deep soil samples by using 454 pyrosequencing amplicons. The result showed that bacterial diversity was reduced after 8-weeks contamination. A shift in bacterial community composition was apparent in crude oil-amended soils with Proteobacteria (esp. α-subdivision being the dominant phylum, together with Actinobacteria and Firmicutes. The contamination led to enrichment of indigenous bacterial taxa like Novosphingobium, Sphingobium, Caulobacter, Phenylobacterium, Alicylobacillus and Arthrobacter, which are generally capable of degrading polycyclic aromatic hydrocarbons (PAHs. The community shift highlighted the resilience of PAH degraders and their potential for in-situ degradation of crude oil under favorable conditions in the deep soils.

  19. Crude Oil Treatment Leads to Shift of Bacterial Communities in Soils from the Deep Active Layer and Upper Permafrost along the China-Russia Crude Oil Pipeline Route

    Science.gov (United States)

    Yang, Sizhong; Wen, Xi; Zhao, Liang; Shi, Yulan; Jin, Huijun

    2014-01-01

    The buried China-Russia Crude Oil Pipeline (CRCOP) across the permafrost-associated cold ecosystem in northeastern China carries a risk of contamination to the deep active layers and upper permafrost in case of accidental rupture of the embedded pipeline or migration of oil spills. As many soil microbes are capable of degrading petroleum, knowledge about the intrinsic degraders and the microbial dynamics in the deep subsurface could extend our understanding of the application of in-situ bioremediation. In this study, an experiment was conducted to investigate the bacterial communities in response to simulated contamination to deep soil samples by using 454 pyrosequencing amplicons. The result showed that bacterial diversity was reduced after 8-weeks contamination. A shift in bacterial community composition was apparent in crude oil-amended soils with Proteobacteria (esp. α-subdivision) being the dominant phylum, together with Actinobacteria and Firmicutes. The contamination led to enrichment of indigenous bacterial taxa like Novosphingobium, Sphingobium, Caulobacter, Phenylobacterium, Alicylobacillus and Arthrobacter, which are generally capable of degrading polycyclic aromatic hydrocarbons (PAHs). The community shift highlighted the resilience of PAH degraders and their potential for in-situ degradation of crude oil under favorable conditions in the deep soils. PMID:24794099

  20. Procedures in field systems for collecting and demulsifying crude oils

    Energy Technology Data Exchange (ETDEWEB)

    Vakhitov, G G; Graifer, V I; Tronov, V P; Zakirov, I G

    1969-01-01

    This microscopic study of crude oil emulsification and demulsification showed that the sooner an emulsion is chemically treated, the less its stability. This finding led to the practice of adding demulsifiers to the crude oil in pipelines. This method of demulsification is now used in Romashkino, Bablinsk, and Elkhovs fields. By this early addition of a chemical, the tendency of the pipeline to form stable, highly viscous emulsions is reduced. This treatment also facilitates separation of water from oil in storage tanks. Repeated tests have shown that pipeline demulsification is a highly effective and economic process. This method reduces crude oil dewatering costs by several hundred percent.

  1. Tweens demulsification effects on heavy crude oil/water emulsion

    Directory of Open Access Journals (Sweden)

    Nastaran Hayati Roodbari

    2016-09-01

    Full Text Available The demulsification role of Tweens (nonionic polymers was determined in the separation of water from heavy crude oil emulsion. According to the previous researches, these nonionic polymers, having hydrophilic and lipophilic groups, are appropriate for making oil in water emulsion. In this research their effects in certain concentrations on demulsifying of water in crude oil emulsion were proved. High molecular weight, alkenes’ chains and groups of ketone and ester in these polymers can improve their performance for the demulsification of water in crude oil emulsion. Their efficiencies are improved with electronegative groups such as oxygen. They leave no corrosion effect because they are neutral and do not leave counter ions.

  2. Crude oil prices: It's not like '86

    International Nuclear Information System (INIS)

    Simmons, M.R.

    1994-01-01

    In 1981, daily crude oil productive capacity exceeded demand by more than 25%, leading to a 4-yr price decline from near $40 per barrel levels, and a sharp drop in 1986 to near $12. But, in 1994, the fundamentals are reversed, worldwide demand is growing, conservation movements are not active, and certain geographic areas, like Asia, are set to tax the system as they modernize. Meanwhile, US and Former Soviet Union production is off, without prospects for near-term turnaround. And there is reason to believe OPEC leaders may not feel compelled to cut their output, when combined small cuts of the magnitude of 5% by the rest of the world's producers could accomplish the same objective of raising oil prices. As with any forecast, only time and hindsight will tell the real story, but 1994 could end up being one of the periodic turning points for what has always been a long-term cyclical industry. This paper summarizes the predictions and causes of predicted price changes

  3. Some recommendations for testing oil spill computer models

    International Nuclear Information System (INIS)

    Garcia-Martinez, R.

    1998-01-01

    According to a recent state-of-the-art review of modelling transport and fate of spills, more than 50 oil spill models have been developed in the last 30 years. Even though some of these models are used for spill response actions during accidents, environmental impact assessment, contingency planning and response training, there are no standard methodologies to evaluate their quality. This article presents some ideas that may contribute to design a set of standard benchmarks that would allow users and developers to assess models on a rational basis. (author)

  4. In-situ production of biosurfactants: An alternative method for dispersing and bioremediating marine oil spills

    International Nuclear Information System (INIS)

    Josefsen, K.; Sveum, P.; Ramstad, S.; Markussen, S.; Folkvord, K.; Krigsvoll, S.; Aune, R.; Storroe, I.

    1995-01-01

    A study of surfactant producing bacteria for the dispersion of oil spills was conducted. Isolation procedures, shoreline experiments, flume basin experiments, and simulated open sea meso-scale experiments and results were described. Bacteria strains were obtained from several locations world-wide, though more success was experienced with strains from colder regions. Two strains were used in the meso-scale experiment. A rapid reduction in the aliphatic fraction of the dispersed oil was observed. Most strains were found to be capable of dispersing crude oils with differing compositions. Efforts to emulsify oil-in-water on an artificial shoreline with biosurfactants producing bacteria showed only limited success in mobilizing the oil. 8 figs., 2 tabs., 14 refs

  5. Methodology for environmental assessments of oil and hazardous substance spills

    Science.gov (United States)

    Davis, W. P.; Scott, G. I.; Getter, C. D.; Hayes, M. O.; Gundlach, E. R.

    1980-03-01

    Scientific assessment of the complex environmental consequences of large spills of oil or other hazardous substances has stimulated development of improved strategies for rapid and valid collection and processing of ecological data. The combination of coastal processes and geological measurements developed by Hayes & Gundlach (1978), together with selected field biological and chemical observations/measurements, provide an ecosystem impact assessment approach which is termed “integrated zonal method of ecological impact assessment.” Ecological assessment of oil and hazardous material spills has been divided into three distinct phases: (1) first-order response studies — conducted at the time of the initial spill event, which gather data to document acute impacts and assist decision-makers in prioritization of cleanup efforts and protection of ecologically sensitive habitats, (2) second-order response studies — conducted two months to one year post-spill, which document any delayed mortality and attempt to identify potential sublethal impacts in sensitive species, and (3) third-order response studies — conducted one to three years post-spill, to document chronic impacts (both lethal and sublethal) to specific indicator species. Data collected during first-order response studies are gathered in a quantitative manner so that the initial assessment may become a baseline for later, more detailed, post-spill scientific efforts. First- and second-order response studies of the “Peck Slip” oil spill in Puerto Rico illustrate the usefulness of this method. The need for contingency planning before a spill has been discussed along with the use of the Vulnerability Index, a method in which coastal environments are classified on a scale of 1 10, based upon their potential susceptibility to oiling. A study of the lower Cook Inlet section of the Alaskan coast illustrates the practical application of this method.

  6. Herring parasite and tissue alterations following the Exxon Valdez oil spill

    International Nuclear Information System (INIS)

    Moles, A.D.; Rice, S.D.; Okihiro, M.S.

    1993-01-01

    The authors examined the intensity and prevalence of larval nematodes (Anisakis simplex) and alterations in selected tissues of spawning Pacific herring (Clupea harengus pallasi) exposed to crude oil, in the laboratory under controlled conditions and in Prince William Sound 14 days after the Exxon Valdez oil spill. In the laboratory, intensity and prevalence of nematodes in the body cavities of herring exposed to the water-soluble fraction of oil declined when exposed to doses above 1.2 mg/L total aromatics. In Prince William Sound, nematodes were rare in spawning herring from oiled sites and abundant among herring from areas outside the spill. Oil exposure apparently induced the nematodes to migrate from the body cavity to the body wall with the lower intensity reflecting a change in parasite location. A coccidian, Eimeria clupearum, was found in greater numbers in oil-exposed herring. To verify exposure effects and to link parasite and tissue alteration with oil exposure, histological examination was used. Liver coagulative necrosis indicated hepatotoxic exposure. Necrosis was followed by macrophage aggregation in the resolution phase. The laboratory exposures allowed confirmation of oil exposure in Prince William Sound and permitted analysis of effects on two internal parasites

  7. Experimental study on yield behavior of Daqing crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Hou, Lei [China University of Petroleum, College of Mechanical and Transportation Engineering, Beijing (China)

    2012-07-15

    The yield behavior of Daqing crude oil was studied by means of multi-mode controlled-stress tests with a high-precision stress controlled rheometer. Two experiments of creep and constant stress loading rate were performed. The yield stress of gelled crude oil was dependent on the test conditions such as the stress loading time and the stress loading rate, but the yield strain did not change with test conditions. The yield strain did exist objectively and it can be used as the criterion for the yielding of the structure of gelled crude oil. The yield strain of gelled oil was studied through experiments of creep, constant stress loading rate, oscillatory shear stress increase, and constant shear rate. The yield strain of gelled crude oil decreased with the increasing gel strength. The experiment of constant speed increase of stress showed the strain softening phenomena for low gel strength oil. (orig.)

  8. Long term effects of crude oil on common murres (Uria aalge) following rehabilitation

    International Nuclear Information System (INIS)

    Khan, R.A.; Ryan, P.

    1991-01-01

    Oil spilled or discharged at sea is known to contaminate and cause mortality in seabirds and in some instances, these losses can be substantial as reported recently following an oil spill from the Exxon Valdez in Alaskan waters. Crude petroleum alters the arrangement of the feather barbules causing a loss of buoyancy and hypothermia. Attempts to rehabilitate birds with light to moderate amounts of oil exposure have met with modest success. Following cleaning and release, many of these birds never recovered and little is known of their survival rate in nature subsequently. A number of oiled sea birds, primarily common murres (Uria aalge), were retrieved recently by the Canadian Coast Guard and attempts to rehabilitate them were conducted. Since the majority of birds were retained longer than the usual 4 to 5 days recommended by the Bird Rescue International Centre after retrieval, it soon became apparent that many were suffering from problems other than diet or thermoregulation. Following autopsy/necropsy, extensive organ damage was observed in all of the birds. The purpose of this communication is to report the long term effects of crude oil on common murres

  9. Effect of non-aqueous phase liquid on biodegradation of PAHs in spilled oil on tidal flat

    International Nuclear Information System (INIS)

    Kose, T.; Miyagishi, A.; Mukai, T.; Takimoto, K.; Okada, M.

    2003-01-01

    Biodegradation rates of polycyclic aromatic hydrocarbons (PAHs) in spilled oil stranded on tidal flats were studied using model reactors to clarify the effects of NAPL on the biodegradation of PAHs in stranded oil on tidal flat with special emphasis on the relationship between dissolution rates of PAHs into water and viscosity of NAPL. Biodegradation of PAHs in NAPL was limited by the dissolution rates of PAHs into water. Biodegradation rate of chrysene was smaller than that for acenaphthene and phenanthrene due to the smaller dissolution rates. Dissolution rates of PAHs in fuel oil C were smaller than those in crude oil due to high viscosity of fuel oil C. Therefore, biodegradation rates of PAHs in fuel oil C were smaller than those in crude oil. Biodegradation rates of PAHs in NAPL with slow decrease rate like fuel oil C were slower than those in NAPL with rapid decrease like crude oil. The smaller decrease rate of fuel oil C than crude oil was due to higher viscosity of fuel oil C. Therefore, not only the dissolution rate of PAHs but also the decrease rates of NAPL were important factors for the biodegradation of PAHs. (author)

  10. In situ production of bio-surfactants: An alternative method for dispersing and bioremediating marine oil spills

    International Nuclear Information System (INIS)

    Josefsen, K.D.; Sveum, P.; Ramstad, P.; Markussen, S.; Folkvord, K.; Krigsvoll, K.; Aune, R.; Storroe, I.

    1995-01-01

    Some oil degrading bacteria are able to produce surfactants. These biosurfactants enhance dispersion of oil droplets into the water column. A large number of surfactant producing bacterial strains have been isolated from seawater samples collected at different sites around the world. Strains isolated from seawater samples collected in cold regions generally had better properties than strains isolated from warm seawater. Many of the isolated strains were able to disperse crude oils with a large variation of composition, as well as the water-in-emulsion (chocolate mousse) formed during weathering of crude oil in the sea. The results show that in situ application of surfactant producing bacteria can be a viable tool in future oil spill contingency, and that dispersion of oil may increase the biodegradation rate. Work is in progress to examine the use of such bacteria in the bioremediation of oil contaminated shorelines. 10 refs., 3 figs., 2 tabs

  11. Environmental guidance documents for exploration, development, Production, and transportation of crude oil and natural gas in texas: Quarterly technical report, January 1, 1997-March 31, 1997

    International Nuclear Information System (INIS)

    Savage, L.

    1997-01-01

    The following technical report provides a detailed status report of the DOE grant project entitled ''Environmental Guidance Documents for Exploration, Development, Production, and Transportation of Crude Oil and Natural Gas in Texas.'' The grant funding allocated is for the purpose of provided the Railroad Commission of Texas (Commission) with resources and capabilities to draft, publish and distribute documents that provide guidance to oil and gas operators on issues concerning oil and gas naturally occurring radioactive material (NORM) waste, oil and gas hazardous waste, remediation of crude oil spills, management of non-hazardous oil and gas wastes, and mechanical integrity testing of Class II injection and disposal wells

  12. Beyond the crude oil and gas reserves

    International Nuclear Information System (INIS)

    Sote, K.

    1993-01-01

    Petroleum remains the greatest jewel of inestimable value in both the local and international treasure hunts for cheap energy source and viable investment options the world over. The diverse business potentials and favourable government policies in Nigeria aimed specifically at stimulating investments in the up streams, midstream and downstream industries need to be tapped by both indigenous and foreign investors alike. Beyond the crude oil and gas reserves' is therefore our modest effort to support such policies, sensitise the Nigerian petroleum industry and promote more dynamic awareness for the varied business opportunities abound in this sector of the economy. The main objective or this publication is to bring to a wider audience within and outside the oil industry a spectrum of such salient opportunities therein. The publication further presents in a lucid and consize form the hidden potentials yet to be harnessed, captures the essence of such investments, identifies the inherent problems in Nigeria peculiar circumstance and thus provides a detailed guide to address such short-coming, viz. Inadequate and poor knowledge of petroleum industry, its operation, by products and their correct applications. - Lack of understanding of the intricacies, realities and technicalities of petroleum business in general. - Poor financial resources, management style, operational and marketing strategies man power and human resources development.- Dirge of information, lack of professional advice and technical service support on the varied business opportunities for diversification. Apathy on the part of the investors themselves to seek for professional support from competent oil consultants, technocrats, institutionalised authorities on petroleum and related matters, amongst others. In summary, the book is divided into ten chapters with illustrations, graphics, drawings, sketches and incorporating figures, statistics, business reports, marketing results, feasibility studies

  13. Oil spill contingency planning in the Ivory coast

    International Nuclear Information System (INIS)

    Bender, K.; Jensen, S.K.; Ostergaerd, J.; Nogbou, P.

    1993-01-01

    The administrative center in charge of handling oil spill pollution situations on the Ivory Coast, West Africa, is named Centre Ivoirien Antipollution (CIAPOL). Its organizational structure has been reshuffled recently. CIAPOL now has three divisions: a laboratory division, a division for cleaning up oil and chemical pollution at sea, and an administrative division. The risk for oil pollution is known: within the past ten years five spills have been reported. All of these have been connected to operations relating to the refinery in Abidjan. More than 2,000 ships call at the port of Abidjan every year. Minor oil slicks are found almost permanently in the harbor and the lagoons around the harbor. Lumps of tar are rather common on the beaches all along the country's coast. This paper focuses on the background investigation in sensitive areas and risk analysis that led to a revision of the oil spill contingency plan, Plan Pollumar, and the recent purchase of oil spill cleanup equipment. The creation of a regional oil pollution response center at CIAPOL for all of the countries in West Africa, is proposed

  14. Feasibility Process for Remediation of the Crude Oil Contaminated Soil

    Science.gov (United States)

    Keum, H.; Choi, H.; Heo, H.; Lee, S.; Kang, G.

    2015-12-01

    More than 600 oil wells were destroyed in Kuwait by Iraqi in 1991. During the war, over 300 oil lakes with depth of up to 2m at more than 500 different locations which has been over 49km2. Therefore, approximately 22 million m3was crude oil contaminated. As exposure of more than 20 years under atmospheric conditions of Kuwait, the crude oil has volatile hydrocarbons and covered heavy oily sludge under the crude oil lake. One of crude oil contaminated soil which located Burgan Oilfield area was collected by Kuwait Oil Company and got by H-plus Company. This contaminated soil has about 42% crude oil and could not biodegraded itself due to the extremely high toxicity. This contaminated soil was separated by 2mm sieve for removal oil sludge ball. Total petroleum hydrocarbons (TPH) was analysis by GC FID and initial TPH concentration was average 48,783 mg/kg. Ten grams of the contaminated soil replaced in two micro reactors with 20mL of bio surfactant produce microorganism. Reactor 1 was added 0.1g powder hemoglobin and other reactor was not added hemoglobin at time 0 day. Those reactors shake 120 rpm on the shaker for 7 days and CO2 produced about 150mg/L per day. After 7 days under the slurry systems, the rest days operated by hemoglobin as primary carbon source for enhanced biodegradation. The crude oil contaminated soil was degraded from 48,783mg/kg to 20,234mg/kg by slurry process and final TPH concentration degraded 11,324mg/kg for 21days. Therefore, highly contaminated soil by crude oil will be combined bio slurry process and biodegradation process with hemoglobin as bio catalytic source. Keywords: crude-oil contaminated soil, bio slurry, biodegradation, hemoglobin ACKOWLEDGEMENTS This project was supported by the Korea Ministry of Environment (MOE) GAIA Program

  15. New heavy crude oil flow improver increases delivery : application scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Pierce, J.; Johnston, R.; Lauzon, P. [ConocoPhillips Specialty Products Inc., Houston, TX (United States)

    2009-07-01

    Flow improvers or drag reducing agents have been used for over 25 years as a method to increase fluid flow in hydrocarbon pipelines. The technology is effective in refined projects, light and medium crude oils. This paper presented a new development in flow improver technology that allows treatment of heavy crude oil slates. It discussed case studies of flow improver treatment of heavy oils in various pipeline system as well as factors that affect commercial success. tabs., figs.

  16. Oil spill first principles. Prevention and best response

    International Nuclear Information System (INIS)

    Ornitz, B.; Champ, M.

    2002-01-01

    Different international conventions, U.S. laws, and policy considerations are reviewed, regulatory strategies are discussed, and the book helps promote the use of better science, engineering, technology and policy and law in oil spill prevention and response. 'Oil Spill Response' has greatly improved over the last 30 years. On a global basis, billions have been spent in R and D in planning and response. However, a paradigm shift is in the works that is needed to more effectively use what has been learned in the last 30 years in both prevention and in clean up. The key terms that describe this paradigm shift are Best Science, Engineering and Technology produce Best Response and the Safety Culture prevents oil spills. Oil spills are no longer considered unavoidable 'accidents' of environmental conditions or functions of catastrophic events. More than 80% of all spills are the result of human error. The focus of the current legal, regulatory and convention framework affecting the transportation of oil by ship reflects a recent change in public attitude, an insistence upon protection of the world's marine environments, particularly coastal ecosystems. This public concern seeks to address the root cause of oil spills, including human error. The outcome of such national and international attention is the creation of significant legal and political motivators for a cultural shift by the oil shipping industry, from an 'evasion' culture to a 'safety culture'. The new 'safety culture' connotes continuous improvement in ship operations and a willingness to adopt the evolving safety culture concepts of communication at all levels within the company, better trained and qualified personnel on board ship, emphasis on safety from top down, and proactive institution of safety management systems at all levels of operation. Evasion or mere compliance with international and national law is no longer sufficient for future sustainable shipping

  17. Oil spill first principles. Prevention and best response

    Energy Technology Data Exchange (ETDEWEB)

    Ornitz, B.; Champ, M. (eds.)

    2002-07-01

    Different international conventions, U.S. laws, and policy considerations are reviewed, regulatory strategies are discussed, and the book helps promote the use of better science, engineering, technology and policy and law in oil spill prevention and response. 'Oil Spill Response' has greatly improved over the last 30 years. On a global basis, billions have been spent in R and D in planning and response. However, a paradigm shift is in the works that is needed to more effectively use what has been learned in the last 30 years in both prevention and in clean up. The key terms that describe this paradigm shift are Best Science, Engineering and Technology produce Best Response and the Safety Culture prevents oil spills. Oil spills are no longer considered unavoidable 'accidents' of environmental conditions or functions of catastrophic events. More than 80% of all spills are the result of human error. The focus of the current legal, regulatory and convention framework affecting the transportation of oil by ship reflects a recent change in public attitude, an insistence upon protection of the world's marine environments, particularly coastal ecosystems. This public concern seeks to address the root cause of oil spills, including human error. The outcome of such national and international attention is the creation of significant legal and political motivators for a cultural shift by the oil shipping industry, from an 'evasion' culture to a 'safety culture'. The new 'safety culture' connotes continuous improvement in ship operations and a willingness to adopt the evolving safety culture concepts of communication at all levels within the company, better trained and qualified personnel on board ship, emphasis on safety from top down, and proactive institution of safety management systems at all levels of operation. Evasion or mere compliance with international and national law is no longer sufficient for future

  18. Enhanced Gravitational Drainage of Crude Oil Through Alabama Beach Sand Caused by the Dispersant Corexit 9500A

    Science.gov (United States)

    Steffy, D. A.; Nichols, A.; Hobbs, K.

    2017-12-01

    Oil spill material released by the 2010 Deepwater Horizon accident contaminated a majority of the 60 miles of Alabama coastline. In response to the oil spill, BP sprayed a dispersant, Corexit 9500A, as an initial remediation effort. An unforeseen impact of the saltwater-dispersant mixture includes the mobilization of oil-spilled material into the underlying beach sand. This study investigated the effect of the dispersant to promote gravitational drainage by measuring the physical characteristics of the sand, saltwater, crude oil, and the dispersant solution. The saltwater-dispersant mixture promoted the downward movement of oil mass 20 times greater extent than just saltwater. These tests are meant to simulate spill material on the beach being exposed to a low-energy, 1-meter mixed tide occurring along the Alabama coastline. A separate test simulated oilwet sand exposed to saltwater and a saltwater-dispersant mixture. The oil-wet sand impeded the vertical movement of saltwater, but allowed a saltwater-dispersant solution to mobilize the oil to migrate downward. The mobilization of oil in this three phase system of saltwater, oil, and air is controlled by: the pressure-saturation profile of the sand; interfacial tension with saltwater; and its surface tension with air.

  19. MICROWAVE HEATING AND SEPARATION OF WATER-IN-OIL EMULSION FROM MEXICAN CRUDE OIL

    OpenAIRE

    VAZQUEZ V., ADRIAN; LOPEZ M., ARTURO; ANDRADE C., LUIS J.; VAZQUEZ A., ARIANA M.

    2014-01-01

    Microwave heating and gravity sedimentation are alternatives for demulsification and layer separation into oil and water layers, this process was demonstrated in the laboratory and provides an option for reducing and oil recovering from water-in-oil Mexican oil emulsions. The combinatorial process was implemented in a test lab using Mexican crude oil samples. The Laboratory samples were 100% and 50-50%, crude and crude-water respectively, were heated. The results were encouraging show that mi...

  20. Proceedings of the nineteenth arctic and marine oil spill program (AMOP) technical seminar

    International Nuclear Information System (INIS)

    1996-01-01

    The technical seminar on arctic and marine oil spills introduced issues concerning oil spills at sea, in particular the critical first few hours of an oil spill. State-of-the-art technologies which assist the response team in tracking and predicting the behavior of oil spills, were described. The physical and chemical properties of spilled oil were studied, as well as those of oil spill treating agents, including testing their biological effects. New methods to contain and recover spilled oil were reviewed. Volume 2 presented results from field experiments in which in-situ burning was performed, and demonstrated modelling techniques for the detection, prediction and tracking of oil spills. refs., tabs., figs

  1. Maximum tech, minimum time. Response and cleanup of the Fidalgo Bay oil spill

    International Nuclear Information System (INIS)

    Pintler, L.R.

    1991-01-01

    A booster pump failure on a pipeline at Texaco's Anacortes refinery spilled more than 17,000 gallons of oil into Fidalgo Bay. A description is given of the spill control measures taken under Texaco's Spill Prevention and Control Countermeasures and facility contingency plans. The spill was addressed quickly, and containment booms were used to cordon off the spill. Vacuum trucks, rope mop machines and disk skimmers were used to collect the thickest concentrations of oil, and the oil and water collected was separated at the refinery's wastewater treatment centre. Nonwoven polypropylene sorbent pads, sweeps, booms and oil snares were used to clean up thinner concentrations of oil. Essential steps for a smooth spill response include the following: a comprehensive spill prevention and control countermeasures plan, training and regular drills and testing; immediate notification of appropriate regulatory agencies and company emergency response personnel; and the use of professional oil spill management contractors to assist in spill cleanup. 2 figs

  2. Economic impacts of oil spills: Spill unit costs for tankers, pipelines, refineries, and offshore facilities. [Task 1, Final report

    Energy Technology Data Exchange (ETDEWEB)

    1993-10-15

    The impacts of oil spills -- ranging from the large, widely publicized Exxon Valdez tanker incident to smaller pipeline and refinery spills -- have been costly to both the oil industry and the public. For example, the estimated costs to Exxon of the Valdez tanker spill are on the order of $4 billion, including $2.8 billion (in 1993 dollars) for direct cleanup costs and $1.125 billion (in 1992 dollars) for settlement of damages claims caused by the spill. Application of contingent valuation costs and civil lawsuits pending in the State of Alaska could raise these costs appreciably. Even the costs of the much smaller 1991 oil spill at Texaco`s refinery near Anacortes, Washington led to costs of $8 to 9 million. As a result, inexpensive waming, response and remediation technologies could lower oil spin costs, helping both the oil industry, the associated marine industries, and the environment. One means for reducing the impact and costs of oil spills is to undertake research and development on key aspects of the oil spill prevention, warming, and response and remediation systems. To target these funds to their best use, it is important to have sound data on the nature and size of spills, their likely occurrence and their unit costs. This information could then allow scarce R&D dollars to be spent on areas and activities having the largest impact. This report is intended to provide the ``unit cost`` portion of this crucial information. The report examines the three key components of the US oil supply system, namely, tankers and barges; pipelines and refineries; and offshore production facilities. The specific purpose of the study was to establish the unit costs of oil spills. By manipulating this key information into a larger matrix that includes the size and frequency of occurrence of oil spills, it will be possible` to estimate the likely future impacts, costs, and sources of oil spills.

  3. Remote oil spill detector for oil terminals and API separators

    International Nuclear Information System (INIS)

    Fitch, R.

    1993-01-01

    Oil leaks from moored tankers, ruptured pipes, and other sources often go unnoticed until significant quantities have polluted the waters. Technology is available to detect oil on water, and a number of methods have been tried with varying success. Floating detection/alarm devices, while potentially offering accurate analysis of samples, have drawbacks. These systems need to be tethered and serviced with new batteries, and they sample only the immediate areas where they are situated. One potential answer to these problems is a remote-sensing system that has one master base station and a number of slave detectors. An inexpensive remote-sensing device has been developed using mostly off-the-shelf hardware. The unit consists of low-light sensors mounted on a mast or rail, each having a 20-degree field of view. The sensors are contained in explosion-proof housings to Zone 1 standard and provide video data to the host computer station via land line or radio link. The computer, on recognizing the oil, calculates the area with respect to time and decides if the spill is significant enough to warrant an alarm. The system operates day or night; in the daytime using the sun's rays and at night using artificial light

  4. Efficiency of crude oil markets: Evidences from informational entropy analysis

    International Nuclear Information System (INIS)

    Ortiz-Cruz, Alejandro; Rodriguez, Eduardo; Ibarra-Valdez, Carlos; Alvarez-Ramirez, Jose

    2012-01-01

    The role of crude oil as the main energy source for the global economic activity has motivated the discussion about the dynamics and causes of crude oil price changes. An accurate understanding of the issue should provide important guidelines for the design of optimal policies and government budget planning. Using daily data for WTI over the period January 1986–March 2011, we analyze the evolution of the informational complexity and efficiency for the crude oil market through multiscale entropy analysis. The results indicated that the crude oil market is informationally efficient over the scrutinized period except for two periods that correspond to the early 1990s and late 2000s US recessions. Overall, the results showed that deregulation has improved the operation of the market in the sense of making returns less predictable. On the other hand, there is some evidence that the probability of having a severe US economic recession increases as the informational efficiency decreases, which indicates that returns from crude oil markets are less uncertain during economic downturns. - Highlights: ► Entropy concepts are used to characterize crude oil prices. ► An index of market efficiency is introduced. ► Except for periods of economic recession, the crude oil market is informationally efficient.

  5. An oil spill-food chain interaction model for coastal waters

    International Nuclear Information System (INIS)

    Yew Hoong Gin, K.; Huda, Md. K.; Tkalich, P.

    2001-01-01

    An oil spill-food chain interaction model, composed of a multiphase oil spill model (MOSM) and a food chain model, has been developed to assess the probable impacts of oil spills on several key marine organisms (phytoplankton, zooplankton, small fish, large fish and benthic invertebrates). The MOSM predicts oil slick thickness on the water surface; dissolved, emulsified and particulate oil concentrations in the water column; and dissolved and particulate oil concentrations in bed sediments. This model is used to predict the fate of oil spills and transport with respect to specific organic compounds, while the food chain model addresses the uptake of toxicant by marine organisms. The oil spill-food chain interaction model can be used to assess the environmental impacts of oil spills in marine ecosystems. The model is applied to the recent Evoikos-Orapin Global oil spill that occurred in the Singapore Strait. (author)

  6. Recovery of seabirds following the Exxon Valdez oil spill

    International Nuclear Information System (INIS)

    Wiens, J.A.

    1993-01-01

    Following the Exxon Valdez oil spill in 1989, over 35,000 dead birds were retrieved and overall mortality was estimated in the hundreds of thousands. These observations led to concerns about persistent impacts on seabirds, especially murres (Uria spp.). Surveys of attendance by murres at breeding colonies in the spill path in 1991, however, indicated no overall differences from prespill attendance levels. Investigations of habitat occupancy conducted shortly after the spill in 1989 showed that, of the 47 bird species examined, the majority were using areas of oil-affected habitats by late 1991, although a few species did not show clear signs of recovery at the end of the study. These species were primarily wintering and resident forms. Because habitat use by other ecologically similar species was not affected by the spill or they recovered rapidly, prospects for recovery of the species that continued to show evidence of oiling impacts on habitat use in late 1991 would seem to be good. Collectively, these studies indicate that concerns about long-term impacts of the Exxon Valdez oil spill on seabirds may not be justified, and that recovery in the use of habitats by many bird species and in colony attendance by murres appeared to be well advanced by late 1991

  7. Large Scale Behavior and Droplet Size Distributions in Crude Oil Jets and Plumes

    Science.gov (United States)

    Katz, Joseph; Murphy, David; Morra, David

    2013-11-01

    The 2010 Deepwater Horizon blowout introduced several million barrels of crude oil into the Gulf of Mexico. Injected initially as a turbulent jet containing crude oil and gas, the spill caused formation of a subsurface plume stretching for tens of miles. The behavior of such buoyant multiphase plumes depends on several factors, such as the oil droplet and bubble size distributions, current speed, and ambient stratification. While large droplets quickly rise to the surface, fine ones together with entrained seawater form intrusion layers. Many elements of the physics of droplet formation by an immiscible turbulent jet and their resulting size distribution have not been elucidated, but are known to be significantly influenced by the addition of dispersants, which vary the Weber Number by orders of magnitude. We present experimental high speed visualizations of turbulent jets of sweet petroleum crude oil (MC 252) premixed with Corexit 9500A dispersant at various dispersant to oil ratios. Observations were conducted in a 0.9 m × 0.9 m × 2.5 m towing tank, where large-scale behavior of the jet, both stationary and towed at various speeds to simulate cross-flow, have been recorded at high speed. Preliminary data on oil droplet size and spatial distributions were also measured using a videoscope and pulsed light sheet. Sponsored by Gulf of Mexico Research Initiative (GoMRI).

  8. Oil spill studies: A review of ecological effects

    Science.gov (United States)

    Teal, John M.; Howarth, Robert W.

    1984-01-01

    We reviewed seven particularly well known and/or studied oil spills that have occurred since the National Academy of Sciences 1975 report, “Petroleum in the Marine Environment” or that occurred prior to that report but about which significant new information has since been acquired. The spills studied were from the barge Florida, and tankers Arrow, Argo Merchant, Amoco Cadiz, and Tsesis and blowouts from the Bravo and Ixtoc I platforms. These “best” studies yield only limited insight into effects because they lack controls and have a high degree of natural variability. The Tsesis, Florida, and Amoco Cadiz cases are exceptional since they occurred in areas of ongoing research programs and had nearby areas suitable for controls. Oil spills have produced measurable effects on ecosystems that have not been readily predictable from laboratory studies on isolated organisms. However, ecosystemlevel interactions are poorly understood even without the complications resulting from effects of pollution. These generalizations emerge: oil regularly reaches sediments after a spill; oil in anoxic sediments is persistent; oil regularly contaminates Zooplankton and benthic invertebrates; fish are also contaminated, but to a lesser extent; oil contamination decreases the abundance and diversity of benthic communities.

  9. Colonial pipeline Enoree River oil spill: A case history

    International Nuclear Information System (INIS)

    Smith, A.B. Jr.

    1993-01-01

    In December 1991, a pipeline ruptured near Fountain Inn, South Carolina, resulting in the release of approximately 13,000 barrels of No. 2 fuel oil to the inland surface water system. Final estimates provided by CPC for the amount of oil discharged from the pipeline rupture indicate that up to 13,100 barrels (over 555,000 gallons) of No. 2 fuel oil were released into the environment - of which approximately 12,600 barrels (530,000 gallons) were recovered. The recovery rate of greater than 95% of spilled product is considered to be well above average for a major discharge of oil in the inland zone. The primary factors influencing this rate of recovery were the ability to provide containment at the leak site within 12 hours of the release and to establish containment downstream of the spill in advance of the leading edge of the oil plume. A total of 23,320 barrels (almost a million gallons) of an oil/water mixture were collected within a five day period. Although the water systems in Clinton and Whitmire were affected by the spill, adequate backup systems provided alternate drinking water to these residents until the primary intakes could be opened. However, this spill caused significant environmental impacts. The South Carolina Wildlife and Marine Resources Department reports that 2,123 fish, representing 24 different species were killed along nine miles of Durbin Creek. From an overall standpoint, the response to this incident was sufficient to protect human health and minimize environmental damage. Contingency planning had prepared CPC for a spill of this magnitude and resources committed to the cleanup were adequate to accomplish the removal of the spilled product. The RRT concept proved to be of valuable assistance to the OSC from a resource perspective; and implementing the organizational components of the RRT provided the necessary mechanism for input and decision making for various parties affected by this incident

  10. Additives in crude oil. A new attempt to prevent boilover; Additive im Rohoel. Ein neuer Ansatz zur Vermeidung eines Boilover

    Energy Technology Data Exchange (ETDEWEB)

    Gosewinkel, Martin; Dworschak, Rene [INBUREX Consulting GmbH, Hamm (Germany)

    2011-03-15

    Boilover of tanks is a rare cause of serious fires in crude oil storage. The greatest danger is the spill of burning material from the tank. In the research project presented here, a method to prevent boilover and/or reduce its effects was to be developed. One approach is the addition of additives that modify the hetero-azeotropic boiling characteristics of crude oil components in case of fire. Even minimum concentrations of the additive will delay the time until boilover and also reduce its intensity.

  11. Hydrocarbon degraders establish at the costs of microbial richness, abundance and keystone taxa after crude oil contamination in permafrost environments

    Science.gov (United States)

    Yang, Sizhong; Wen, Xi; Shi, Yulan; Liebner, Susanne; Jin, Huijun; Perfumo, Amedea

    2016-01-01

    Oil spills from pipeline ruptures are a major source of terrestrial petroleum pollution in cold regions. However, our knowledge of the bacterial response to crude oil contamination in cold regions remains to be further expanded, especially in terms of community shifts and potential development of hydrocarbon degraders. In this study we investigated changes of microbial diversity, population size and keystone taxa in permafrost soils at four different sites along the China-Russia crude oil pipeline prior to and after perturbation with crude oil. We found that crude oil caused a decrease of cell numbers together with a reduction of the species richness and shifts in the dominant phylotypes, while bacterial community diversity was highly site-specific after exposure to crude oil, reflecting different environmental conditions. Keystone taxa that strongly co-occurred were found to form networks based on trophic interactions, that is co-metabolism regarding degradation of hydrocarbons (in contaminated samples) or syntrophic carbon cycling (in uncontaminated samples). With this study we demonstrate that after severe crude oil contamination a rapid establishment of endemic hydrocarbon degrading communities takes place under favorable temperature conditions. Therefore, both endemism and trophic correlations of bacterial degraders need to be considered in order to develop effective cleanup strategies. PMID:27886221

  12. Expanding U.S. markets for Canadian crude oil

    International Nuclear Information System (INIS)

    Heath, M.; Angevine, G.; Chan, K.; Renne, G.; Stariha, J.; MacKay, E.

    1993-01-01

    The quantities and types of Canadian, U.S. and competing foreign crudes flowing into U.S. market regions and the potential to retain and/or expand Canadian crude oil sales in each of those markets, was studied. The various pipeline system expansion/construction proposals were reviewed. Findings of the study with respect to prospects for crude oil sales into each of the U.S. market regions were presented. Opportunities and constraints with regard to the potential for incremental crude oil sales into each of the U.S. market regions were detailed. The study concluded that there was a substantial market in the U.S. for incremental sales of Canadian crudes. Most of the refineries in the U.S. market regions were more flexible in terms of their crude diet than they were before the rationalization and restructuring of the industry began. The market for crude oil in the U.S. was shown to be one of the most competitive in the world and the most volatile. The study also revealed that there were risks associated with large additions to the capacity to ship crude oil by pipeline from Western Canada, given the uncertainties surrounding future supply. 4 refs., figs., tabs

  13. Mesoscale experiments help to evaluate in-situ burning of oil spills

    International Nuclear Information System (INIS)

    Evans, D.D.; Walton, W.D.; Baum, H.R.; Notarianni, K.A.; Tennyson, E.J.; Tebeau, P.A.

    1993-01-01

    Burning of spilled oil has distinct advantages over other cleanup countermeasures. It offers the potential to convert rapidly large quantities of oil into its primary combustion products, carbon dioxide and water, with a small percentage of other unburned and residue by-products. Disadvantages include the dispersal of the combustion products into the air. Mesoscale and laboratory experiments have been conducted to measure the burning characteristics of crude oil fires. Measurements on crude oil pool fires from 0.4 m to 17.2 m in effective diameter were made to obtain data on the rate of burning, heat release rate, composition of the combustion products, and downwind dispersion of the products. The smaller experiments were performed in laboratories at the National Institute of Standards and Technology and the Fire Research Institute in Japan; and the larger ones at the US Coast Guard Fire Safety and Test Detachment in Mobile, Alabama. From these experiments, the value for surface regression rate of a burning crude oil spill was found to be 0.055 mm/s. A major concern for public safety is the content and extent of the smoke plume from the fires. Smoke yield, the fraction of the oil mass burned that is emitted as particulate, was found to be 13 percent. A large-eddy simulation calculation method for smoke plume trajectory and smoke particulate deposition developed by NIST showed that the smoke particulate deposition from a 114 m 2 burn would occur in striations over a long, slender area 3.2 km wide and 258 km downwind of the burn

  14. An Improved CO2-Crude Oil Minimum Miscibility Pressure Correlation

    Directory of Open Access Journals (Sweden)

    Hao Zhang

    2015-01-01

    Full Text Available Minimum miscibility pressure (MMP, which plays an important role in miscible flooding, is a key parameter in determining whether crude oil and gas are completely miscible. On the basis of 210 groups of CO2-crude oil system minimum miscibility pressure data, an improved CO2-crude oil system minimum miscibility pressure correlation was built by modified conjugate gradient method and global optimizing method. The new correlation is a uniform empirical correlation to calculate the MMP for both thin oil and heavy oil and is expressed as a function of reservoir temperature, C7+ molecular weight of crude oil, and mole fractions of volatile components (CH4 and N2 and intermediate components (CO2, H2S, and C2~C6 of crude oil. Compared to the eleven most popular and relatively high-accuracy CO2-oil system MMP correlations in the previous literature by other nine groups of CO2-oil MMP experimental data, which have not been used to develop the new correlation, it is found that the new empirical correlation provides the best reproduction of the nine groups of CO2-oil MMP experimental data with a percentage average absolute relative error (%AARE of 8% and a percentage maximum absolute relative error (%MARE of 21%, respectively.

  15. Responding to oil spills in the open ocean environment

    International Nuclear Information System (INIS)

    Wood, A.E.

    1994-01-01

    The primary objectives in responding to any oil spill is to control the source of the spill, then, contain, collect, and recover the spilled product. Accomplishing those objectives is an immense challenge. It becomes much more difficult when attempted in the open ocean environment due to the more complex logistical and communications problems one encounters when operating miles from the nearest land. Often times, too, the response must be coordinated with either a salvage operation, a fire-fighting operation, a well control operation or a combination of any of these. There have been volumes of papers comparing the relative merits of mechanical recovery, in-situ burning, dispersant application, and bioremediation in responding to open ocean spills. Although each approach deserves special consideration in different circumstances, this presentation focuses on mechanical methods; the specialized equipment and operational tactics that are best utilized in responding to a major spill in the open ocean. This paper is divided into two sections. The first section, Equipment Used in Open Ocean Spills, addresses in general terms, the special equipment required in an offshore response operation. The second section, entitled Operational Tactics Used In Open Ocean Spills offers an overview of the tactics employed to achieve the general objectives of containment, collection, recovery, and temporary storage

  16. Perspective: Ecological recovery following the Exxon Valdez oil spill

    International Nuclear Information System (INIS)

    Maki, A.W.

    1993-01-01

    A series of field and laboratory studies were designed to characterize the initial effects and subsequent rate of ecosystem recovery following the Exxon Valdez oil spill. These studies were organized within an ecological risk assessment framework wherein measurements of residual spill hydrocarbons from specific environmental compartments were correlated with observed biological effects for resident species and communities. This allowed an assessment of the likelihood of spill-related effects vs. effects of natural ecosystem variability. Measurement of polycyclic automatic hydrocarbons (PAH) were made from throughout the spill-affected area for water column, intertidal shoreline sediments and deep subtidal sediments. Data document the expected high levels of PAH in 1989 with rapid PAH decreases in following years from all compartments reflecting natural assimilation and dissipation via chemical, physical and biological processes. Parallel investigations of risks to biological resources representing major trophic levels were conducted to quantify recovery rates of spill impacted habitats and resident species. Results are summarized documenting respective recovery rates for key trophic levels including intertidal flora and fauna, benthic invertebrates and infauna, herring and salmon, shorebirds and colonial seabirds and sea otters. Quantitative data developed for these species support the conclusion that the effects of oil spills are largely short-term acute events, and the Prince William Sound recovery was well advanced by 1991

  17. Abnormal development of Dentalium due to the Amoco Cadiz oil spill

    NARCIS (Netherlands)

    Koster, A.SJ.; Biggelaar, J.A.M. van den

    A comparison was made between the development of Dentalium eggs, spawned by animals, collected before and after the Amoco Cadiz oil spill. Development of eggs from animals collected before the oil spill was significantly better than development of eggs from animals collected after the oil spill. It

  18. 75 FR 29397 - National Commission on the BP Deepwater Horizon Oil Spill and Offshore Drilling

    Science.gov (United States)

    2010-05-26

    ... National Commission on the BP Deepwater Horizon Oil Spill and Offshore Drilling By the authority vested in... Deepwater Horizon Oil Spill and Offshore Drilling (the ``Commission''). Sec. 2. Membership. (a) The... impact of, oil spills associated with offshore drilling, taking into consideration the environmental...

  19. Effect of asphaltenes on crude oil wax crystallization

    DEFF Research Database (Denmark)

    Kriz, Pavel; Andersen, Simon Ivar

    2005-01-01

    The paper summarizes the experimental work done on asphaltene influenced wax crystallization. Three different asphaltenes (from stable oil, instable oil, and deposit) were mixed at several concentrations or dispersions into the waxy crude oil. These blends were evaluated by viscometry and yield s...

  20. Russian crude-oil production and export still increasing

    International Nuclear Information System (INIS)

    Purho, P.

    2001-01-01

    Russian crude-oil production is still increasing. In 2000 the annual production 6.48 mb/d was about 6% higher than a year before. In 2001 the production is expected to rise near the level 7 mb/d, so the increase in production volume is fast. However, the production is still far away from the maximum level of the former Soviet Union, 12 mb/d. At the moment Russia is the second largest oil producer right after Saudi Arabia. The increase in production is based on intensified use of old oil fields caused by improved technology. The oil export of Russia far abroad in 2000 was 2.5 mb/d and near abroad into FSU countries only about 180 000 b/d. The recent export of crude-oil has been near the maximum export capacity corresponding to 2.7 mb/d. About 61 million tons of oil products were exported in 2000, and even the export of oil products is increasing. Most of this was gas oil and heavy fuel oil, but also the export of gasoline was significant. The export of oil and oil products is mainly based on shipments, but also the share of train transport is high. Nearly all the crude oil is transported west either by ships or via pipelines. The share of railway transport is only few percents. Russia will continue its own oil pumping policy despite of the appeals of OPEC for reduction of oil production. Opinion in Russia is that if the increase of production and export serves the interests of Russia, it will also be carried out. The target value for crude oil for 2002 is 22 USD per barrel. The Russian crude oil production is estimated to grow up to 7.4 - 8.4 mb/d by the year 2010

  1. Influence of the type of crude oil to platforming effects

    International Nuclear Information System (INIS)

    Kafedzhiski, Branko; Crvenkova, Suzana; Zikovski, Toni

    1999-01-01

    Platforming in one of the most subtleties processing in refinery industry and it is permanent source for research and finding out the higher optimum degree. Optimum of the last effects of platforming directly depends on many parameters. One of more important parameters is the type of crude. The purpose of this work is presenting positive and negative effect to the platforming parameters caused by different types of crude in OCTA-Crude Oil Refinery -Skopje, Macedonia. (Original)

  2. Influence of the crude oil type to platforming effects

    International Nuclear Information System (INIS)

    Kafedzhiski, Branko; Crvenkova, Suzana; Zikovski, Toni

    1999-01-01

    Platforming is one of the most subtleties processing in refinery industry and it is permanent source for research and finding out the higher optimum degree. Optimum of the last effects of platforming directly depends on many parameters. One of the more important parameters is the type of the crude. The purpose of this work is presenting positive and negative effect to the platforming parameters caused by different types of crude in OCTA Crude Oil Refinery - Skopje (Macedonia). (Author)

  3. Modeling of well drilling heating on crude oil using microwave

    Energy Technology Data Exchange (ETDEWEB)

    Muntini, Melania Suweni, E-mail: melania@physics.its.ac.id; Pramono, Yono Hadi; Yustiana [Physics Department, Institut Teknologi Sepuluh Nopember, Surabaya Kampus ITS, Sukolilo, Surabaya 60111 (Indonesia)

    2016-03-11

    As the world’s oil reserves are dwindling, some researchers have been prompted to make a breakthrough to further improve the efficiency of exploration and production. One of the technologies used is heating the crude oil. This paper presents the modeling results of heat treatment on crude oil using microwave energy. Modeling is conducted by assuming that the diameter of the well is 11,16 cm, the heat source is applied on the surface of the well, and the cut-off frequency in the air and on crude oil are 1,56 GHz. and 0.91 GHz, respectively. The energy generated by the microwave radiation is converted into heat energy which is absorbed by the crude oil. Consequently, this energy increases the temperature of crude oil through a heat transfer mechanism. The results obtained showed that the temperature of crude oil is about 200°C at a depth of 62.5cm, and at a distance of 3 cm from the center of the well. Temperature along the well follows an exponential function, which is from the center of the well in the direction radially outward from the cylinder axis. It has been observed that the temperature decreases as measured from the well surface along the cylinder.

  4. Active avoidance from a crude oil soluble fraction by an Andean paramo copepod.

    Science.gov (United States)

    Araújo, Cristiano V M; Moreira-Santos, Matilde; Sousa, José P; Ochoa-Herrera, Valeria; Encalada, Andrea C; Ribeiro, Rui

    2014-09-01

    Several oil spills due to ruptures in the pipeline oil systems have occurred at the Andean paramo. A sample of this crude oil was mixed with water from a nearby Andean lagoon and the toxicity of the soluble fraction was assessed through lethal and avoidance assays with a locally occurring copepod (Boeckella occidentalis intermedia). The integration of mortality and avoidance aimed at predicting the immediate decline of copepod populations facing an oil leakage. The 24-h median lethal PAH concentration was 42.7 (26.4-91.6) µg L(-1). In the 12-h avoidance assay, 30% avoidance was recorded at the highest PAH concentration (19.4 µg L(-1)). The mortality at this PAH concentration would be of 25% and, thus, the population immediate decline would be of 55%. The inclusion of non-forced exposure testing with the quantification of the avoidance response in environmental risk assessments is, therefore, supported due to underestimation of the lethal assays.

  5. Weathering of hydrocarbons in mangrove sediments: testing the effects of using dispersants to treat oil spills

    International Nuclear Information System (INIS)

    Burns, K.A.; Codi, S.; Pratt, C.; Duke, N.C.

    1999-01-01

    This field study was a combined chemical and biological investigation of the relative effects of using dispersants to treat oil spills impacting mangrove habitats. The aim of the chemistry was to determine whether dispersant affected the short- or long-term composition of a medium range crude oil (Gippsland) stranded in a tropical mangrove environment in Queensland, Australia. Sediment cores from three replicate plots of each treatment (oil only and oil plus dispersant) were analyzed for total hydrocarbons and for individual molecular markers (alkanes, aromatics, triterpanes, and steranes). Sediments were collected at 2 days, then 1, 7, 13 and 22 months post-spill. Over this time, oil in the six treated plots decreased exponentially from 36.6 ± 16.5 to 1.2 ± 0.8 mg/g dry wt. There was no statistical difference in initial oil concentrations, penetration of oil to depth, or in the rates of oil dissipation between oiled or dispersed oil plots. At 13 months, alkanes were > 50% degraded, aromatics were ∼30% degraded based upon ratios of labile to resistant markers. However, there was no change in the triterpane or sterane biomarker signatures of the retained oil. This is of general forensic interest for pollution events. The predominant removal processes were evaporation (≤27%) and dissolution (≥56%), with a lag-phase of 1 month before the start of significant microbial degradation (≤17%). The most resistant fraction of the oil that remained after 7 months (the higher molecular weight hydrocarbons) correlated with the initial total organic carbon content of the soil. Removal rate in the Queensland mangroves was significantly faster than that observed in the Caribbean and was related to tidal flushing. (author)

  6. The relationship between SARA fractions and crude oil stability

    Directory of Open Access Journals (Sweden)

    Siavash Ashoori

    2017-03-01

    Full Text Available Asphaltene precipitation and deposition are drastic issues in the petroleum industry. Monitoring the asphaltene stability in crude oil is still a serious problem and has been subject of many studies. To investigate crude oil stability by saturate, aromatic, resin and asphaltene (SARA analysis seven types of crudes with different components were used. The applied methods for SARA quantification are IP-143 and ASTM D893-69 and the colloidal instability index (CII is computed from the SARA values as well. In comparison between CII results, the values of oil compositions demonstrated that the stability of asphaltenes in crude oils is a phenomenon that is related to all these components and it cannot be associated only with one of them, individually.

  7. Dynamic Relationship between Crude Oil Price, Exchange Rate and ...

    African Journals Online (AJOL)

    DrNneka

    Second, since Hamilton (1983) documented the impact of crude oil price volatility .... Hariri,2013) sourced from the U.S. Energy Information Administration (EIA). .... is explained by identifying the relative importance of a variable in generating.

  8. Evaluation of Crude Oil Biodegradation Efficiency and Peroxidase ...

    African Journals Online (AJOL)

    ADOWIE PERE

    Increase in biomass enhanced degradation efficiency above 80 % after 10 days for all concentration of crude oil studied. Peroxidase ... compounds by various bacteria and fungi (Gianfreda et al, 1999) ... into a clean plastic container. Microbial.

  9. Investigating Asphaltenes Composition in Crude Oil Samples using ...

    African Journals Online (AJOL)

    MBI

    2015-12-22

    Dec 22, 2015 ... composition of asphaltenes by Iatroscan TLC-FID method was compared with the weight% of asphaltenes precipitated. ... SARA in the crude oil samples were determined in this work ..... Fractionation and characterization of.

  10. Enhancement of Crude Oil Polluted Soil by Applying Single and ...

    African Journals Online (AJOL)

    ADOWIE PERE

    bioline.org.br/ja ... 5 kg of soil each was polluted with 200 ml of crude oil ... organic matter, phosphate, nitrate, total hydrocarbon content, potassium and microbial population were analyzed before ... arise mainly from the processing and distribution of.

  11. An isolated bacterial consortium for crude oil biodegradation

    African Journals Online (AJOL)

    GREGORY

    2011-12-16

    Dec 16, 2011 ... African Journal of Biotechnology Vol. 10(81), pp. ... The removal of crude oil by bioremediation was achieved in less time as compared to natural attenuation ... Environmental pollution, especially with hydrocarbons is a major ...

  12. Phytoremediation of some tropical soils contaminated with petroleum crude oil

    International Nuclear Information System (INIS)

    Oyibo, Charles

    2013-12-01

    This study was undertaken in three phases to identify (phase 1), screen (phase 11) and evaluate (phase 111) plants for their phytoremediation potential. In Phase 1, 15 plant species made up of grasses and legumes namely: Paspalum. vaginatum, Cynodon.dactylon, Pueraria. phaseoloides, Centrosema. pubescens, Panicum. maximum, Schrankia. leptocarpa, Eclipta. alba (Linn.), Cyperus. haspen (Linn.), Melastromastrum. capitatum, Acreceras. zizanoides Dandy, Pteridum aquilinum (Linn), Ludwigia.decurrens Walt,Setaria longiseta P.Beauv., Physalis angulata (Linn.), and Desmodium scorpiurus Desv.were identified on sites previously polluted by crude oil spills in the Niger Delta Area of Nigeria. The first 6 species were used in phase 11 while the first four species were earmarked (rolled over) for phase 111. Responses to Questionnaire indicated that majority of residents in the selected sites/communities had lived in these areas for 10 or more years had mainly JHS/SHS education; were self employed – mainly farmers and fishers although most were unemployed in the public sector. Adverse effects of the operations of oil companies particularly oil spillage on the environment and local residents include: loss of vegetation and farmlands, soil and water body contamination, weak social and cultural institutions (disrespect by youth for elders and institutions), militancy and hostage taking among youth from the area. In phase 11, seeds of legumes among the six selected species were collected from Accra, Aburi environs and Kusi in the Eastern region of Ghana; they were scarified, cultured in growth medium and the seedlings which emerged from them were transplanted into experimental pots, each containing 2000g of either Alajo or Toje soil series. One week after transplanting, each pot was simulated with a corresponding serial crude oil concentration of 0% (control) 1 % (24ml), 3% (83ml), 5.5% (130ml) and 8% (189ml) or 10% (237ml) in three replicates. These concentrations were arrived at