Sample records for coupled dispersed two-phase

  1. Strongly coupled dispersed two-phase flows; Ecoulements diphasiques disperses fortement couples

    Energy Technology Data Exchange (ETDEWEB)

    Zun, I.; Lance, M.; Ekiel-Jezewska, M.L.; Petrosyan, A.; Lecoq, N.; Anthore, R.; Bostel, F.; Feuillebois, F.; Nott, P.; Zenit, R.; Hunt, M.L.; Brennen, C.E.; Campbell, C.S.; Tong, P.; Lei, X.; Ackerson, B.J.; Asmolov, E.S.; Abade, G.; da Cunha, F.R.; Lhuillier, D.; Cartellier, A.; Ruzicka, M.C.; Drahos, J.; Thomas, N.H.; Talini, L.; Leblond, J.; Leshansky, A.M.; Lavrenteva, O.M.; Nir, A.; Teshukov, V.; Risso, F.; Ellinsen, K.; Crispel, S.; Dahlkild, A.; Vynnycky, M.; Davila, J.; Matas, J.P.; Guazelli, L.; Morris, J.; Ooms, G.; Poelma, C.; van Wijngaarden, L.; de Vries, A.; Elghobashi, S.; Huilier, D.; Peirano, E.; Minier, J.P.; Gavrilyuk, S.; Saurel, R.; Kashinsky, O.; Randin, V.; Colin, C.; Larue de Tournemine, A.; Roig, V.; Suzanne, C.; Bounhoure, C.; Brunet, Y.; Tanaka, A.T.; Noma, K.; Tsuji, Y.; Pascal-Ribot, S.; Le Gall, F.; Aliseda, A.; Hainaux, F.; Lasheras, J.; Didwania, A.; Costa, A.; Vallerin, W.; Mudde, R.F.; Van Den Akker, H.E.A.; Jaumouillie, P.; Larrarte, F.; Burgisser, A.; Bergantz, G.; Necker, F.; Hartel, C.; Kleiser, L.; Meiburg, E.; Michallet, H.; Mory, M.; Hutter, M.; Markov, A.A.; Dumoulin, F.X.; Suard, S.; Borghi, R.; Hong, M.; Hopfinger, E.; Laforgia, A.; Lawrence, C.J.; Hewitt, G.F.; Osiptsov, A.N.; Tsirkunov, Yu. M.; Volkov, A.N.


    This document gathers the abstracts of the Euromech 421 colloquium about strongly coupled dispersed two-phase flows. Behaviors specifically due to the two-phase character of the flow have been categorized as: suspensions, particle-induced agitation, microstructure and screening mechanisms; hydrodynamic interactions, dispersion and phase distribution; turbulence modulation by particles, droplets or bubbles in dense systems; collective effects in dispersed two-phase flows, clustering and phase distribution; large-scale instabilities and gravity driven dispersed flows; strongly coupled two-phase flows involving reacting flows or phase change. Topic l: suspensions particle-induced agitation microstructure and screening mechanisms hydrodynamic interactions between two very close spheres; normal stresses in sheared suspensions; a critical look at the rheological experiments of R.A. Bagnold; non-equilibrium particle configuration in sedimentation; unsteady screening of the long-range hydrodynamic interactions of settling particles; computer simulations of hydrodynamic interactions among a large collection of sedimenting poly-disperse particles; velocity fluctuations in a dilute suspension of rigid spheres sedimenting between vertical plates: the role of boundaries; screening and induced-agitation in dilute uniform bubbly flows at small and moderate particle Reynolds numbers: some experimental results. Topic 2: hydrodynamic interactions, dispersion and phase distribution: hydrodynamic interactions in a bubble array; A 'NMR scattering technique' for the determination of the structure in a dispersion of non-brownian settling particles; segregation and clustering during thermo-capillary migration of bubbles; kinetic modelling of bubbly flows; velocity fluctuations in a homogeneous dilute dispersion of high-Reynolds-number rising bubbles; an attempt to simulate screening effects at moderate particle Reynolds numbers using an hybrid formulation; modelling the two-phase

  2. Separation of curcuminoids using ionic liquid based aqueous two-phase system coupled with in situ dispersive liquid-liquid microextraction. (United States)

    Shu, Yang; Gao, Mingcen; Wang, Xueying; Song, Rusheng; Lu, Jun; Chen, Xuwei


    An aqueous two-phase extraction system (ATPS) combined with an in situ dispersive liquid-liquid microextraction (DLLME) method using imidazolium ionic liquids (ILs) for the separation of curcuminoids is developed. The influence of structure of IL, the type of metathesis reagents, and the back extraction agents on the extraction efficiency is investigated. 2.0mg of curcuminoids are extracted by an IL ATPS composed of 0.4g 1,3-diethylimidazolium iodine (EeimI), 0.6g potassium hydrogen phosphate, 1.0g water. Then the bis[(trifluoromethyl)sulfonyl]imide lithium (LiNTf2) aqueous solution is added to the EeimI-rich phase of the ATPS. The water-immiscible ionic liquids, 1,3-diethylimidazole bis[(trifluoromethyl)sulfonyl]imide (EeimNTf2), forms by the metathesis reaction. The in situ DLLME is triggered simultaneously and further purifies the curcuminoids. 92% of EeimI transforms into EeimNTf2 and thus the Eeim(+) cation is used for twice in this method. Finally, 0.1mol/L NaOH aqueous solution is used as the back extraction reagent. The curcuminoids precipitate is achieved with 93% of recovery when the aqueous solution is adjusted to pH 3.0. This ATPS-DLLME method is successfully applied to the separation of curcuminoids from Curcuma Longa (0.96±0.02% of extraction yield, a purity of >51% with respect to the total dry mass of the product). Copyright © 2015 Elsevier B.V. All rights reserved.

  3. Mathematical modeling of disperse two-phase flows

    CERN Document Server

    Morel, Christophe


    This book develops the theoretical foundations of disperse two-phase flows, which are characterized by the existence of bubbles, droplets or solid particles finely dispersed in a carrier fluid, which can be a liquid or a gas. Chapters clarify many difficult subjects, including modeling of the interfacial area concentration. Basic knowledge of the subjects treated in this book is essential to practitioners of Computational Fluid Dynamics for two-phase flows in a variety of industrial and environmental settings. The author provides a complete derivation of the basic equations, followed by more advanced subjects like turbulence equations for the two phases (continuous and disperse) and multi-size particulate flow modeling. As well as theoretical material, readers will discover chapters concerned with closure relations and numerical issues. Many physical models are presented, covering key subjects including heat and mass transfers between phases, interfacial forces and fluid particles coalescence and breakup, a...

  4. Coupling two-phase fluid flow with two-phase darcy flow in anisotropic porous media

    KAUST Repository

    Chen, J.


    This paper reports a numerical study of coupling two-phase fluid flow in a free fluid region with two-phase Darcy flow in a homogeneous and anisotropic porous medium region. The model consists of coupled Cahn-Hilliard and Navier-Stokes equations in the free fluid region and the two-phase Darcy law in the anisotropic porous medium region. A Robin-Robin domain decomposition method is used for the coupled Navier-Stokes and Darcy system with the generalized Beavers-Joseph-Saffman condition on the interface between the free flow and the porous media regions. Obtained results have shown the anisotropic properties effect on the velocity and pressure of the two-phase flow. 2014 Jie Chen et al.

  5. Coupling Two-Phase Fluid Flow with Two-Phase Darcy Flow in Anisotropic Porous Media

    Directory of Open Access Journals (Sweden)

    Jie Chen


    Full Text Available This paper reports a numerical study of coupling two-phase fluid flow in a free fluid region with two-phase Darcy flow in a homogeneous and anisotropic porous medium region. The model consists of coupled Cahn-Hilliard and Navier-Stokes equations in the free fluid region and the two-phase Darcy law in the anisotropic porous medium region. A Robin-Robin domain decomposition method is used for the coupled Navier-Stokes and Darcy system with the generalized Beavers-Joseph-Saffman condition on the interface between the free flow and the porous media regions. Obtained results have shown the anisotropic properties effect on the velocity and pressure of the two-phase flow.

  6. Turbulent transition modification in dispersed two-phase pipe flow (United States)

    Winters, Kyle; Longmire, Ellen


    In a pipe flow, transition to turbulence occurs at some critical Reynolds number, Rec , and transition is associated with intermittent swirling structures extending over the pipe cross section. Depending on the magnitude of Rec , these structures are known either as puffs or slugs. When a dispersed second liquid phase is added to a liquid pipe flow, Rec can be modified. To explore the mechanism for this modification, an experiment was designed to track and measure these transitional structures. The facility is a pump-driven circuit with a 9m development and test section of diameter 44mm. Static mixers are placed upstream to generate an even dispersion of silicone oil in a water-glycerine flow. Pressure signals were used to identify transitional structures and trigger a high repetition rate stereo-PIV system downstream. Stereo-PIV measurements were obtained in planes normal to the flow, and Taylor's Hypothesis was employed to infer details of the volumetric flow structure. The presentation will describe the sensing and imaging methods along with preliminary results for the single and two-phase flows. Supported by Nanodispersions Technology.

  7. Disperse Two-Phase Flows, with Applications to Geophysical Problems (United States)

    Berselli, Luigi C.; Cerminara, Matteo; Iliescu, Traian


    In this paper, we study the motion of a fluid with several dispersed particles whose concentration is very small (smaller than ), with possible applications to problems coming from geophysics, meteorology, and oceanography. We consider a very dilute suspension of heavy particles in a quasi-incompressible fluid (low Mach number). In our case, the Stokes number is small and—as pointed out in the theory of multiphase turbulence—we can use an Eulerian model instead of a Lagrangian one. The assumption of low concentration allows us to disregard particle-particle interactions, but we take into account the effect of particles on the fluid (two-way coupling). In this way, we can study the physical effect of particles' inertia (and not only passive tracers), with a model similar to the Boussinesq equations. The resulting model is used in both direct numerical simulations and large eddy simulations of a dam-break (lock-exchange) problem, which is a well-known academic test case.

  8. Disperse two-phase flows, with applications to geophysical problems


    Berselli, Luigi Carlo; Cerminara, Matteo; Iliescu, Traian


    In this paper we study the motion of a fluid with several dispersed particles whose concentration is very small (smaller than $10^{-3}$), with possible applications to problems coming from geophysics, meteorology, and oceanography. We consider a very dilute suspension of heavy particles in a quasi-incompressible fluid (low Mach number). In our case the Stokes number is small and --as pointed out in the theory of multiphase turbulence-- we can use an Eulerian model instead of a Lagrangian one....

  9. Numerical flow analyses of a two-phase hydraulic coupling

    Energy Technology Data Exchange (ETDEWEB)

    Hur, N.; Kwak, M.; Moshfeghi, M. [Sogang University, Seoul (Korea, Republic of); Chang, C.-S.; Kang, N.-W. [VS Engineering, Seoul (Korea, Republic of)


    We investigated flow characteristics in a hydraulic coupling at different charged water conditions and speed ratios. Hence, simulations were performed for three-dimensional two-phase flow by using the VOF method. The realizable k-ε turbulence model was adopted. To resolve the interaction of passing blades of the primary and secondary wheels, simulations were conducted in the unsteady framework using a sliding grid technique. The results show that the water-air distribution inside the wheel is strongly dependent upon both amount of charged water and speed ratio. Generally, air is accumulated in the center of the wheel, forming a toroidal shape wrapped by the circulating water. The results also show that at high speed ratios, the solid-body-like rotation causes dry areas on the periphery of the wheels and, hence, considerably decreases the circulating flow rate and the transmitted torque. Furthermore, the momentum transfer was investigated through the concept of a mass flux triangle based on the local velocity multiplied by the local mixture density instead of the velocity triangle commonly used in a single-phase turbomachine analysis. Also, the mass fluxes along the radius of the coupling in the partially charged and fully charged cases were found to be completely different. It is shown that the flow rate at the interfacial plane and also the transmitted torque are closely related and are strongly dependent upon both the amount of charged water and speed ratio. Finally, a conceptual categorization together with two comprehensive maps was provided for the torque transmission and also circulating flow rates. These two maps in turn exhibit valuable engineering information and can serve as bases for an optimal design of a hydraulic coupling.

  10. Analysis of coupled mass transfer and sol-gel reaction in a two-phase system

    NARCIS (Netherlands)

    Castelijns, H.J.; Huinink, H.P.; Pel, L.; Zitha, P.L.J.


    The coupled mass transfer and chemical reactions of a gel-forming compound in a two-phase system were studied in detail. Tetra-methyl-ortho-silicate (TMOS) is often used as a precursor in sol-gel chemistry to produce silica gels in aqueous systems. TMOS can also be mixed with many hydrocarbons

  11. Coupling of two-phase flow in fractured-vuggy reservoir with filling medium

    Directory of Open Access Journals (Sweden)

    Xie Haojun


    Full Text Available Caves in fractured-vuggy reservoir usually contain lots of filling medium, so the two-phase flow in formations is the coupling of free flow and porous flow, and that usually leads to low oil recovery. Considering geological interpretation results, the physical filled cave models with different filling mediums are designed. Through physical experiment, the displacement mechanism between un-filled areas and the filling medium was studied. Based on the experiment model, we built a mathematical model of laminar two-phase coupling flow considering wettability of the porous media. The free fluid region was modeled using the Navier-Stokes and Cahn-Hilliard equations, and the two-phase flow in porous media used Darcy's theory. Extended BJS conditions were also applied at the coupling interface. The numerical simulation matched the experiment very well, so this numerical model can be used for two-phase flow in fracture-vuggy reservoir. In the simulations, fluid flow between inlet and outlet is free flow, so the pressure difference was relatively low compared with capillary pressure. In the process of water injection, the capillary resistance on the surface of oil-wet filling medium may hinder the oil-water gravity differentiation, leading to no fluid exchange on coupling interface and remaining oil in the filling medium. But for the water-wet filling medium, capillary force on the surface will coordinate with gravity. So it will lead to water imbibition and fluid exchange on the interface, high oil recovery will finally be reached at last.

  12. Dynamic simulation of dispersed gas-liquid two-phase flow using a discrete bubble model.

    NARCIS (Netherlands)

    Delnoij, E.; Lammers, F.A.; Kuipers, J.A.M.; van Swaaij, Willibrordus Petrus Maria


    In this paper a detailed hydrodynamic model for gas-liquid two-phase flow will be presented. The model is based on a mixed Eulerian-Lagrangian approach and describes the time-dependent two-dimensional motion of small, spherical gas bubbles in a bubble column operating in the homogeneous regime. The

  13. Coupling constant in dispersive model

    Indian Academy of Sciences (India)

    Abstract. The average of the moments for event shapes in e+e− → hadrons within the con- text of next-to-leading order (NLO) perturbative QCD prediction in dispersive model is studied. Moments used in this article are 〈1 − T〉, 〈ρ〉, 〈BT〉 and 〈BW〉. We extract αs, the coupling con- stant in perturbative theory and α0 in the ...

  14. A numerical method for a model of two-phase flow in a coupled free flow and porous media system

    KAUST Repository

    Chen, Jie


    In this article, we study two-phase fluid flow in coupled free flow and porous media regions. The model consists of coupled Cahn-Hilliard and Navier-Stokes equations in the free fluid region and the two-phase Darcy law in the porous medium region. We propose a Robin-Robin domain decomposition method for the coupled Navier-Stokes and Darcy system with the generalized Beavers-Joseph-Saffman condition on the interface between the free flow and the porous media regions. Numerical examples are presented to illustrate the effectiveness of this method. © 2014 Elsevier Inc.

  15. Kinetic and dynamic probability-density-function descriptions of disperse turbulent two-phase flows (United States)

    Minier, Jean-Pierre; Profeta, Christophe


    This article analyzes the status of two classical one-particle probability density function (PDF) descriptions of the dynamics of discrete particles dispersed in turbulent flows. The first PDF formulation considers only the process made up by particle position and velocity Zp=(xp,Up) and is represented by its PDF p (t ;yp,Vp) which is the solution of a kinetic PDF equation obtained through a flux closure based on the Furutsu-Novikov theorem. The second PDF formulation includes fluid variables into the particle state vector, for example, the fluid velocity seen by particles Zp=(xp,Up,Us) , and, consequently, handles an extended PDF p (t ;yp,Vp,Vs) which is the solution of a dynamic PDF equation. For high-Reynolds-number fluid flows, a typical formulation of the latter category relies on a Langevin model for the trajectories of the fluid seen or, conversely, on a Fokker-Planck equation for the extended PDF. In the present work, a new derivation of the kinetic PDF equation is worked out and new physical expressions of the dispersion tensors entering the kinetic PDF equation are obtained by starting from the extended PDF and integrating over the fluid seen. This demonstrates that, under the same assumption of a Gaussian colored noise and irrespective of the specific stochastic model chosen for the fluid seen, the kinetic PDF description is the marginal of a dynamic PDF one. However, a detailed analysis reveals that kinetic PDF models of particle dynamics in turbulent flows described by statistical correlations constitute incomplete stand-alone PDF descriptions and, moreover, that present kinetic-PDF equations are mathematically ill posed. This is shown to be the consequence of the non-Markovian characteristic of the stochastic process retained to describe the system and the use of an external colored noise. Furthermore, developments bring out that well-posed PDF descriptions are essentially due to a proper choice of the variables selected to describe physical systems

  16. Measurement and simulation of the turbulent dispersion of a radioactive tracer in a two-phase flow system

    Energy Technology Data Exchange (ETDEWEB)

    Hensel, F.; Rohde, U.


    The turbulent dispersion of a radiotracer in an experimental setup with a natural convection liquid-gaseous flow was investigated. A liquid-gaseous bubbly flow was generated in a narrow tank by injection of pressurized air into water or by catalytic disintegration of H{sub 2}O{sub 2}. Turbulent Prandtl numbers for gas and tracer dispersion were varied. In the case of higher gas superficial velocities (J{sub gas}{approx}5-15 mm/s), a reasonable agreement was achieved between calculated and measured tracer transport velocity and dispersion coefficient values. A nearly linear correlation between j{sub gas} and D was found in agreement with other authors. The calculation results contribute to a better understanding of the phenomena and interpretation of the measurement results as well as to the validation of the CFD code for turbulent two-phase flow applications. Further investigations are necessary to improve the agreement in the cases of H{sub 2}O{sub 2} disintegration and low gas superficial velocities. (orig.)

  17. A stochastic asymptotic-preserving scheme for a kinetic-fluid model for disperse two-phase flows with uncertainty

    Energy Technology Data Exchange (ETDEWEB)

    Jin, Shi, E-mail: [Department of Mathematics, University of Wisconsin–Madison, Madison, WI 53706 (United States); Institute of Natural Sciences, School of Mathematical Science, MOELSEC and SHL-MAC, Shanghai Jiao Tong University, Shanghai 200240 (China); Shu, Ruiwen, E-mail: [Department of Mathematics, University of Wisconsin–Madison, Madison, WI 53706 (United States)


    In this paper we consider a kinetic-fluid model for disperse two-phase flows with uncertainty. We propose a stochastic asymptotic-preserving (s-AP) scheme in the generalized polynomial chaos stochastic Galerkin (gPC-sG) framework, which allows the efficient computation of the problem in both kinetic and hydrodynamic regimes. The s-AP property is proved by deriving the equilibrium of the gPC version of the Fokker–Planck operator. The coefficient matrices that arise in a Helmholtz equation and a Poisson equation, essential ingredients of the algorithms, are proved to be positive definite under reasonable and mild assumptions. The computation of the gPC version of a translation operator that arises in the inversion of the Fokker–Planck operator is accelerated by a spectrally accurate splitting method. Numerical examples illustrate the s-AP property and the efficiency of the gPC-sG method in various asymptotic regimes.

  18. Modeling two-phase flow of immiscible fluids in porous media: Buckley-Leverett theory with explicit coupling terms (United States)

    Pasquier, Sylvain; Quintard, Michel; Davit, Yohan


    Continuum models that describe two-phase flow of immiscible fluids in porous media often treat momentum exchange between the two phases by simply generalizing the single-phase Darcy law and introducing saturation-dependent permeabilities. Here we study models of creeping flows that include an explicit coupling between both phases via the addition of cross terms in the generalized Darcy law. Using an extension of the Buckley-Leverett theory, we analyze the impact of these cross terms on saturation profiles and pressure drops for different couples of fluids and closure relations of the effective parameters. We show that these cross terms in the macroscale models may significantly impact the flow compared to results obtained with the generalized Darcy laws without cross terms. Analytical solutions, validated against experimental data, suggest that the effect of this coupling on the dynamics of saturation fronts and the steady-state profiles is very sensitive to gravitational effects, the ratio of viscosity between the two phases, and the permeability. Our results indicate that the effects of momentum exchange on two-phase flow may increase with the permeability of the porous medium when the influence of the fluid-fluid interfaces become similar to that of the solid-fluid interfaces.

  19. Impact of the initialisation on population balance CFD models coupled with two-phase flow (United States)

    Hliwa, Ghizlane Zineb; Bannari, Rachid; Belghiti, Mly Taib


    Several studies have been made about Computational Fluid Dynamics simulations of bubble columns and compared to experimental data. In the present work, a rectangular bubble column is simulated using a model of two-phase flows. The inter-phase forces are used. A population balance equation is introduced by comparing two different models to account the effects of bubble size distribution. The turbulence model k-ɛ is used with mixture transport properties. In this work, the impact of boundary conditions at the inlet is studied. The numerical predictions are validated with experimental data available in the literature.

  20. An interfacial shear term evaluation study for adiabatic dispersed air–water two-phase flow with the two-fluid model using CFD

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, S.L., E-mail: [School of Nuclear Engineering, Purdue University, West Lafayette, IN (United States); Hibiki, T.; Ishii, M. [School of Nuclear Engineering, Purdue University, West Lafayette, IN (United States); Schlegel, J.P. [Department of Mining and Nuclear Engineering, Missouri University of Science and Technology, Rolla, MO (United States); Buchanan, J.R.; Hogan, K.J. [Bettis Laboratory, Naval Nuclear Laboratory, West Mifflin, PA (United States); Guilbert, P.W. [ANSYS UK Ltd, Oxfordshire (United Kingdom)


    Highlights: • Closure form of the interfacial shear term in three-dimensional form is investigated. • Assessment against adiabatic upward bubbly air–water flow data using CFD. • Effect of addition of the interfacial shear term on the phase distribution. - Abstract: In commercially available Computational Fluid Dynamics (CFD) codes such as ANSYS CFX and Fluent, the interfacial shear term is missing in the field momentum equations. The derivation of the two-fluid model (Ishii and Hibiki, 2011) indicates the presence of this term as a momentum source in the right hand side of the field momentum equation. The inclusion of this term is considered important for proper modeling of the interfacial momentum coupling between phases. For separated flows, such as annular flow, the importance of the shear term is understood in the one-dimensional (1-D) form as the major mechanism by which the wall shear is transferred to the gas phase (Ishii and Mishima, 1984). For gas dispersed two-phase flow CFD simulations, it is important to assess the significance of this term in the prediction of phase distributions. In the first part of this work, the closure of this term in three-dimensional (3-D) form in a CFD code is investigated. For dispersed gas–liquid flow, such as bubbly or churn-turbulent flow, bubbles are dispersed in the shear layer of the continuous phase. The continuous phase shear stress is mainly due to the presence of the wall and the modeling of turbulence through the Boussinesq hypothesis. In a 3-D simulation, the continuous phase shear stress can be calculated from the continuous fluid velocity gradient, so that the interfacial shear term can be closed using the local values of the volume fraction and the total stress of liquid phase. This form also assures that the term acts as an action-reaction force for multiple phases. In the second part of this work, the effect of this term on the volume fraction distribution is investigated. For testing the model two-phase

  1. Coupled Hydromechanical Model of Two-Phase Fluid Flow in Deformable Porous Media

    Directory of Open Access Journals (Sweden)

    You-Seong Kim


    Full Text Available A model of solid-water-air coupling in triphasic mixtures is compared with solid-water coupling in biphasic mixtures with an application to partially saturated porous media. Based on thermodynamics, the mathematical framework governing the behavior of a partially saturated soil is derived using balance equations, and the numerical implementation and drainage tests of a soil column are carried out to validate the obtained formulations. The role of the air phase in the hydro-mechanical behavior of triphasic mixtures can be analyzed from the interactions among multiple phases for the constitutive behavior of a solid skeleton, and the triphasic mixture model can be applied in geotechnical engineering problems, such as CO2 sequestration and air storage in aquifers.

  2. Coupling constant in dispersive model

    Indian Academy of Sciences (India)

    perturbative theory using the dispersive model. By fitting the experimental data, the values of ( M Z ° ) = 0.1171 ± 0.00229 and 0 ( I = 2 GeV ) = 0.5068 ± 0.0440 are found. Our results are consistent with the above model. Our results are also ...

  3. A coupled CFD and two-phase substrate kinetic model for enzymatic hydrolysis of lignocellulose (United States)

    Danes, Nicholas; Sitaraman, Hariswaran; Stickel, Jonathan; Sprague, Michael


    Cost-effective production of fuels from lignocellulosic biomass is an important subject of research in order to meet the world's current and future energy demands. Enzymatic hydrolysis is one of the several steps in the biochemical conversion of biomass into fuels. This process involves the interplay of non-Newtonian fluid dynamics that happen over tens of seconds coupled with chemical reactions that happen over several hours. In this work, we present a coupled CFD-reaction model for conversion of cellulose to sugars in a benchtop mixer reactor. A subcycling approach is used to circumvent the large time scale disparity between fluid dynamics and reactions. We will present a validation study of our simulations with experiments for well-mixed and stratified reactor scenarios along with predictions for conversion rates and product concentrations at varying impeller speeds and in scaled-up reactors. This work is funded by the Bioenergy Technology Office of DOE and the NSF's Enriched Doctoral Training program (DMS-1551229).

  4. A framework for efficient irregular wave simulations using Higher Order Spectral method coupled with viscous two phase model

    Directory of Open Access Journals (Sweden)

    Inno Gatin


    Full Text Available In this paper a framework for efficient irregular wave simulations using Higher Order Spectral method coupled with fully nonlinear viscous, two-phase Computational Fluid Dynamics (CFD model is presented. CFD model is based on solution decomposition via Spectral Wave Explicit Navier–Stokes Equation method, allowing efficient coupling with arbitrary potential flow solutions. Higher Order Spectrum is a pseudo-spectral, potential flow method for solving nonlinear free surface boundary conditions up to an arbitrary order of nonlinearity. It is capable of efficient long time nonlinear propagation of arbitrary input wave spectra, which can be used to obtain realistic extreme waves. To facilitate the coupling strategy, Higher Order Spectrum method is implemented in foam-extend alongside the CFD model. Validation of the Higher Order Spectrum method is performed on three test cases including monochromatic and irregular wave fields. Additionally, the coupling between Higher Order Spectrum and CFD is validated on three hour irregular wave propagation. Finally, a simulation of a 3D extreme wave encountering a full scale container ship is shown.

  5. Effect of Mo Dispersion Size and Water Vapor on Oxidation of Two-Phase Directionally Solidified NiAl-9Mo In-Situ Composites

    Energy Technology Data Exchange (ETDEWEB)

    Brady, Michael P [ORNL; Bei, Hongbin [ORNL; Meisner, Roberta Ann [ORNL; Lance, Michael J [ORNL; Tortorelli, Peter F [ORNL


    Oxidation of two-phase NiAl-9Mo eutectics with 3 different growth rates/2nd phase Mo dispersion sizes were investigated at 900 C in air and air with 10% water vapor. Good oxidation resistance via alumina formation was observed in dry air, with Mo volatilization loss minimized by fine submicron Mo dispersions. However, extensive Mo volatilization and in-place internal oxidation of prior Mo phase regions was observed in wet air oxidation. Ramifications of this phenomenon for the development of multi-phase high-temperature alloys are discussed

  6. Flashing liquid jets and two-phase droplet dispersion I. Experiments for derivation of droplet atomisation correlations. (United States)

    Cleary, Vincent; Bowen, Phil; Witlox, Henk


    The large-scale release of a liquid contained at upstream conditions above its local atmospheric boiling point is a scenario often given consideration in process industry risk analysis. Current-hazard quantification software often employs simplistic equilibrium two-phase approaches. Scaled water experiments have been carried out measuring droplet velocity and droplet size distributions for a range of exit orifice aspect ratios (L/d) and conditions representing low to high superheat. 2D Phase-Doppler Anemometry has been utilised to characterise droplet kinematics and spray quality. Droplet size correlations have been developed for non-flashing, the transition between non-flashing and flashing, and fully flashing jets. Using high-speed shadowography, transition between regimes is defined in terms of criteria identified in the external flow structure. An overview companion paper provides a wider overview of the problem and reports implementation of these correlations into consequence models and subsequent validation. The fluid utilised throughout is water, hence droplet correlations are developed in non-dimensional form to allow extrapolation to other fluids through similarity scaling, although verification of model performance for other fluids is required in future studies. Data is reduced via non-dimensionalisation in terms of the Weber number and Jakob number, essentially representing the fluid mechanics and thermodynamics of the system, respectively. A droplet-size distribution correlation has also been developed, conveniently presented as a volume undersize distribution based on the Rosin-Rammler distribution. Separate correlations are provided for sub-cooled mechanical break-up and fully flashing jets. This form of correlation facilitates rapid estimates of likely mass rainout quantities, as well as full distribution information for more rigorous two-phase thermodynamic modelling in the future.

  7. A fully-coupled discontinuous Galerkin spectral element method for two-phase flow in petroleum reservoirs (United States)

    Taneja, Ankur; Higdon, Jonathan


    A high-order spectral element discontinuous Galerkin method is presented for simulating immiscible two-phase flow in petroleum reservoirs. The governing equations involve a coupled system of strongly nonlinear partial differential equations for the pressure and fluid saturation in the reservoir. A fully implicit method is used with a high-order accurate time integration using an implicit Rosenbrock method. Numerical tests give the first demonstration of high order hp spatial convergence results for multiphase flow in petroleum reservoirs with industry standard relative permeability models. High order convergence is shown formally for spectral elements with up to 8th order polynomials for both homogeneous and heterogeneous permeability fields. Numerical results are presented for multiphase fluid flow in heterogeneous reservoirs with complex geometric or geologic features using up to 11th order polynomials. Robust, stable simulations are presented for heterogeneous geologic features, including globally heterogeneous permeability fields, anisotropic permeability tensors, broad regions of low-permeability, high-permeability channels, thin shale barriers and thin high-permeability fractures. A major result of this paper is the demonstration that the resolution of the high order spectral element method may be exploited to achieve accurate results utilizing a simple cartesian mesh for non-conforming geological features. Eliminating the need to mesh to the boundaries of geological features greatly simplifies the workflow for petroleum engineers testing multiple scenarios in the face of uncertainty in the subsurface geology.

  8. Closure of the Averaged Equations for Disperse Two-Phase Flow by Direct Numerical Simulation: Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Andrea Prosperetti


    The report briefly describes the activities carried out in the course of the project. A first line of research was the development of systematic closure relations for averaged equations for disperse multiphase flow. A second line was the development of efficient numerical methods for the simulation of Navier-Stokes flows with many suspended particles. The report also lists the 21 journal articles in which this work is more fully decsribed.

  9. A generalized volumetric dispersion model for a class of two-phase separation/reaction: finite difference solutions (United States)

    Siripatana, Chairat; Thongpan, Hathaikarn; Promraksa, Arwut


    This article explores a volumetric approach in formulating differential equations for a class of engineering flow problems involving component transfer within or between two phases. In contrast to conventional formulation which is based on linear velocities, this work proposed a slightly different approach based on volumetric flow-rate which is essentially constant in many industrial processes. In effect, many multi-dimensional flow problems found industrially can be simplified into multi-component or multi-phase but one-dimensional flow problems. The formulation is largely generic, covering counter-current, concurrent or batch, fixed and fluidized bed arrangement. It was also intended to use for start-up, shut-down, control and steady state simulation. Since many realistic and industrial operation are dynamic with variable velocity and porosity in relation to position, analytical solutions are rare and limited to only very simple cases. Thus we also provide a numerical solution using Crank-Nicolson finite difference scheme. This solution is inherently stable as tested against a few cases published in the literature. However, it is anticipated that, for unconfined flow or non-constant flow-rate, traditional formulation should be applied.

  10. Improvements in Neutronics/Thermal-Hydraulics Coupling in Two-Phase Flow Systems Using Stochastic-Mixture Transport Models

    CERN Document Server

    Palmer, T S


    In this NEER project, researchers from Oregon State University have investigated the limitations of the treatment of two-phase coolants as a homogeneous mixture in neutron transport calculations. Improved methods of calculating the neutron distribution in binary stochastic mixtures have been developed over the past 10-15 years and are readily available in the transport literature. These methods are computationally more expensive than the homogeneous (or atomic mix) models, but can give much more accurate estimates of ensemble average fluxes and reaction rates provided statistical descriptions of the distributions of the two materials are know. A thorough review of the two-phase flow literature has been completed and the relevant mixture distributions have been identified. Using these distributions, we have performed Monte Carlo criticality calculations of fuel assemblies to assess the accuracy of the atomic mix approximation when compared to a resolved treatment of the two-phase coolant. To understand the ben...

  11. Effects of coupling a UF membrane with a mesh screen and elevating temperature in the methanogenic digester of a two-phased anaerobic system. (United States)

    Kim, Min Ho; Park, Chul-Hwi; Han, Gee-Bong


    This study was conducted to investigate coupling of UF with a mesh screen under thermophilic temperatures and compare the effectiveness of membrane filtration and temperature change in the methanogenic digester. A two-phased anaerobic digester coupled with an ultrafiltration (UF) membrane system was used for anaerobic sludge digestion. The overall average chemical oxygen demand (COD) removal efficiency achieved in the two-phased anaerobic digester coupled with the UF membrane system was 97.9 ± 0.8%. In the methanogenic digester, 10.5% improvement of methane production rate was obtained by the increased microbial population and metabolic activity due to coupling with a UF membrane and a mesh screen and elevating the temperature from mesophilic to thermophilic conditions. The average methane production per VS loading and unit volume (m3) was 477.14 ± 31.5 and 567.15 ± 43.3 mL CH4g-1 VS before and after elevating the temperature, respectively. The optimal operating pressure for the UF membrane system was less than 3 kgf cm-2, and the mesh screen saved 19.0% of the operating cost and 17.3% of energy consumption. As a result, the UF membrane system enhanced the digestion of sewage sludge, where the elevation of temperature improved the methane production rate in the thermophilic methanogenic digester.

  12. Coupled Enzyme Reactions Performed in Heterogeneous Reaction Media: Experiments and Modeling for Glucose Oxidase and Horseradish Peroxidase in a PEG/Citrate Aqueous Two-Phase System (United States)


    The intracellular environment in which biological reactions occur is crowded with macromolecules and subdivided into microenvironments that differ in both physical properties and chemical composition. The work described here combines experimental and computational model systems to help understand the consequences of this heterogeneous reaction media on the outcome of coupled enzyme reactions. Our experimental model system for solution heterogeneity is a biphasic polyethylene glycol (PEG)/sodium citrate aqueous mixture that provides coexisting PEG-rich and citrate-rich phases. Reaction kinetics for the coupled enzyme reaction between glucose oxidase (GOX) and horseradish peroxidase (HRP) were measured in the PEG/citrate aqueous two-phase system (ATPS). Enzyme kinetics differed between the two phases, particularly for the HRP. Both enzymes, as well as the substrates glucose and H2O2, partitioned to the citrate-rich phase; however, the Amplex Red substrate necessary to complete the sequential reaction partitioned strongly to the PEG-rich phase. Reactions in ATPS were quantitatively described by a mathematical model that incorporated measured partitioning and kinetic parameters. The model was then extended to new reaction conditions, i.e., higher enzyme concentration. Both experimental and computational results suggest mass transfer across the interface is vital to maintain the observed rate of product formation, which may be a means of metabolic regulation in vivo. Although outcomes for a specific system will depend on the particulars of the enzyme reactions and the microenvironments, this work demonstrates how coupled enzymatic reactions in complex, heterogeneous media can be understood in terms of a mathematical model. PMID:24517887

  13. Solutal configuration during coupled two-phase [α (Al) + θ-Al2Cu] planar univariant eutetic growth in Al-Cu-(Ag, Si) ternary eutetic alloys (United States)

    De Wilde, J.; Froyen, L.


    The solutal configuration, both in the solid as in the liquid, during coupled two-phase planar growth as it can be obtained during unidirectional solidification of ternary Al-Cu-Ag and Al-Cu-Si alloys with a composition close to the univariant eutectic reaction L → α (Al) + θ-Al2Cu has been investigated during preparatory ground experiments. During solidification, both Al and Cu can be redistributed in the liquid by cross-diffusion parallel to the planar solid/liquid interface. However the third element, i.e. Ag and Si, must be segregated over a much longer distance. In the case of Ag, a diffusive stable solute boundary layer has been observed. Si however is found to be solutal unstable and gravity driven solutal convection breaks up the boundary layer. In both cases, however, the interface is prone to a Mullins-Sekerka instability giving rise to two-phase cellular growth at a critical value of the growth velocity. In the solid, the α(Al) composition, determined by the solidus line, changes with changing growth velocity.

  14. Practical dispersion relations for strongly coupled plasma fluids

    Directory of Open Access Journals (Sweden)

    Sergey A. Khrapak


    Full Text Available Very simple explicit analytical expressions are discussed, which are able to describe the dispersion relations of longitudinal waves in strongly coupled plasma systems such as one-component plasma and weakly screened Yukawa fluids with a very good accuracy. Applications to other systems with soft pairwise interactions are briefly discussed.

  15. Practical dispersion relations for strongly coupled plasma fluids (United States)

    Khrapak, Sergey A.


    Very simple explicit analytical expressions are discussed, which are able to describe the dispersion relations of longitudinal waves in strongly coupled plasma systems such as one-component plasma and weakly screened Yukawa fluids with a very good accuracy. Applications to other systems with soft pairwise interactions are briefly discussed.

  16. The effect of pH on coupled mass transfer and sol-gel reaction in a two-phase system. (United States)

    Castelijns, H J; Huinink, H P; Pel, L; Zitha, P L J


    The coupled mass transfer and chemical reactions of a gel-forming compound in a two-phase system were recently analyzed in detail [Castelijns et al. J. Appl. Phys. 2006, 100, 024916]. In this successive work, the gel-forming chemical tetramethylorthosilicate (TMOS) was dissolved in a mineral oil and placed together with heavy water (D2O) in small cylinders. The transfer of TMOS from the oleic phase to the aqueous phase was monitored through nuclear magnetic resonance (NMR) relaxation time measurements of hydrogen in the oleic phase. The rate of gelation was measured through NMR relaxation time measurements of deuterium in the aqueous phase. The temperature, the initial concentration of TMOS, and the type of buffer in the aqueous phase were varied in the experiments. The mass transfer is driven by the rate of hydrolysis, which increases with temperature. The hydrolysis rate is the lowest at a neutral pH and is the highest at a low pH. In the aqueous phase, a sharp decrease in the transverse relaxation time (T2) of 2H is observed, which is attributed to the gel reaction. The plateau in T2 indicates the gel transition point. The gel rates increase with increasing temperature and increasing concentration, and are the highest at a neutral pH.

  17. A mixture theory approach to model co- and counter-current two-phase flow in porous media accounting for viscous coupling (United States)

    Qiao, Y.; Andersen, P. Ø.; Evje, S.; Standnes, D. C.


    It is well known that relative permeabilities can depend on the flow configuration and they are commonly lower during counter-current flow as compared to co-current flow. Conventional models must deal with this by manually changing the relative permeability curves depending on the observed flow regime. In this paper we use a novel two-phase momentum-equation-approach based on general mixture theory to generate effective relative permeabilities where this dependence (and others) is automatically captured. In particular, this formulation includes two viscous coupling effects: (i) Viscous drag between the flowing phases and the stagnant porous rock; (ii) viscous drag caused by momentum transfer between the flowing phases. The resulting generalized model will predict that during co-current flow the faster moving fluid accelerates the slow fluid, but is itself decelerated, while for counter-current flow they are both decelerated. The implications of these mechanisms are demonstrated by investigating recovery of oil from a matrix block surrounded by water due to a combination of gravity drainage and spontaneous imbibition, a situation highly relevant for naturally fractured reservoirs. We implement relative permeability data obtained experimentally through co-current flooding experiments and then explore the model behavior for different flow cases ranging from counter-current dominated to co-current dominated. In particular, it is demonstrated how the proposed model seems to offer some possible interesting improvements over conventional modeling by providing generalized mobility functions that automatically are able to capture more correctly different flow regimes for one and the same parameter set.

  18. Magnetic ionic liquid aqueous two-phase system coupled with high performance liquid chromatography: A rapid approach for determination of chloramphenicol in water environment. (United States)

    Yao, Tian; Yao, Shun


    A novel organic magnetic ionic liquid based on guanidinium cation was synthesized and characterized. A new method of magnetic ionic liquid aqueous two-phase system (MILATPs) coupled with high-performance liquid chromatography (HPLC) was established to preconcentrate and determine trace amount of chloramphenicol (CAP) in water environment for the first time. In the absence of volatile organic solvents, MILATPs not only has the excellent properties of rapid extraction, but also exhibits a response to an external magnetic field which can be applied to assist phase separation. The phase behavior of MILATPs was investigated and phase equilibrium data were correlated by Merchuk equation. Various influencing factors on CAP recovery were systematically investigated and optimized. Under the optimal conditions, the preconcentration factor was 147.2 with the precision values (RSD%) of 2.42% and 4.45% for intra-day (n=6) and inter-day (n=6), respectively. The limit of detection (LOD) and limit of quantitation (LOQ) were 0.14ngmL(-1) and 0.42ngmL(-1), respectively. Fine linear range of 12.25ngmL(-1)-2200ngmL(-1) was obtained. Finally, the validated method was successfully applied for the analysis of CAP in some environmental waters with the recoveries for the spiked samples in the acceptable range of 94.6%-99.72%. Hopefully, MILATPs is showing great potential to promote new development in the field of extraction, separation and pretreatment of various biochemical samples. Copyright © 2016 Elsevier B.V. All rights reserved.

  19. Two phase sampling

    CERN Document Server

    Ahmad, Zahoor; Hanif, Muhammad


    The development of estimators of population parameters based on two-phase sampling schemes has seen a dramatic increase in the past decade. Various authors have developed estimators of population using either one or two auxiliary variables. The present volume is a comprehensive collection of estimators available in single and two phase sampling. The book covers estimators which utilize information on single, two and multiple auxiliary variables of both quantitative and qualitative nature. Th...

  20. Coupling and Vertical Dispersion Correction in the SPS

    CERN Document Server

    Aiba, M; Franchi, A; Tomas, R; Vanbavinckhove, G


    Consolidation of the coupling correction scheme in the LHC is challenged by a missing skew quadrupole family in Sector 3-4 at the start-up in 2009-2010. Simultaneous coupling and vertical dispersion correction using vertical orbit bumps at the sextupoles, was studied by analyzing turn-byturn data. This scheme was tested in the CERN SPS where the optical structure of arc cells is quite similar to the LHC. In the SPS, horizontal and vertical beam positions are measured separately with single plane BPMs, thus a technique to construct ”pseudo double plane BPM” is also discussed.

  1. A terahertz study of taurine: Dispersion correction and mode couplings (United States)

    Dai, Zelin; Xu, Xiangdong; Gu, Yu; Li, Xinrong; Wang, Fu; Lian, Yuxiang; Fan, Kai; Cheng, Xiaomeng; Chen, Zhegeng; Sun, Minghui; Jiang, Yadong; Yang, Chun; Xu, Jimmy


    The low-frequency characteristics of polycrystalline taurine were studied experimentally by terahertz (THz) absorption spectroscopy and theoretically by ab initio density-functional simulations. Full optimizations with semi-empirical dispersion correction were performed in spectral computations and vibrational mode assignments. For comparison, partial optimizations with pure density functional theory were conducted in parallel. Results indicate that adding long-range dispersion correction to the standard DFT better reproduces the measured THz spectra than the popular partial optimizations. The main origins of the observed absorption features were also identified. Moreover, a coupled-oscillators model was proposed to explain the experimental observation of the unusual spectral blue-shift with the increase of temperature. Such coupled-oscillators model not only provides insights into the temperature dynamics of non-bonded interactions but also offers an opportunity to better understand the physical mechanisms behind the unusual THz spectral behaviors in taurine. Particularly, the simulation approach and novel coupled-oscillators model presented in this work are applicable to analyze the THz spectra of other molecular systems.

  2. A level set-based topology optimization method for simultaneous design of elastic structure and coupled acoustic cavity using a two-phase material model (United States)

    Noguchi, Yuki; Yamamoto, Takashi; Yamada, Takayuki; Izui, Kazuhiro; Nishiwaki, Shinji


    This papers proposes a level set-based topology optimization method for the simultaneous design of acoustic and structural material distributions. In this study, we develop a two-phase material model that is a mixture of an elastic material and acoustic medium, to represent an elastic structure and an acoustic cavity by controlling a volume fraction parameter. In the proposed model, boundary conditions at the two-phase material boundaries are satisfied naturally, avoiding the need to express these boundaries explicitly. We formulate a topology optimization problem to minimize the sound pressure level using this two-phase material model and a level set-based method that obtains topologies free from grayscales. The topological derivative of the objective functional is approximately derived using a variational approach and the adjoint variable method and is utilized to update the level set function via a time evolutionary reaction-diffusion equation. Several numerical examples present optimal acoustic and structural topologies that minimize the sound pressure generated from a vibrating elastic structure.

  3. Two-Phase Accumulator (United States)

    Kalb, Charles E.; Kosson, Robert L.; Alario, Joseph P.; Brown, Richard F.; Edlestein, Fred


    Two-phase accumulator maintains pressure and temperature in thermal-bus system within predetermined range during variations in heat load on system. Stores liquid and vapor ammonia. Exchanges liquid ammonia with condenser to adjust level of liquid in condenser. Prototype has capacity of 13 gallons (49 liters). Simple and highly reliable. Responds quickly, restoring pressure and temperature to proper values within minutes. Low in cost and requires little further development. Used to dispose of waste heat, such as that from electronic equipment or power-plant.

  4. Determination of Sudan I-IV in candy using ionic liquid/anionic surfactant aqueous two-phase extraction coupled with high-performance liquid chromatography. (United States)

    Yu, Wei; Liu, Zhongling; Li, Qiang; Zhang, Hanqi; Yu, Yong


    Ionic liquid/anionic surfactant aqueous two-phase system was developed and applied for the extraction of Sudan I-IV. High-performance liquid chromatography was applied to the determination of the analytes. The aqueous two-phase system (ATPS) was formed in the present of C4[MIM]BF4, sodium dodecyl benzene sulphonate and (NH4)2SO4. The parameters affecting the extraction efficiency, such as volume of ionic liquid, amount of sodium dodecyl benzene sulphonate, ionic strength, pH value of system, extraction time and temperature were investigated. The limits of detection for Sudan I, II, III and IV were 5.45, 4.66, 3.68, 4.20 μg kg(-1), respectively. When the present method was applied to the analysis of candy samples, the recoveries of the analytes ranged from 82.3% to 112.1% and relative standard deviations were lower than 7.41%. Copyright © 2014 Elsevier Ltd. All rights reserved.

  5. A two-phase debris-flow model that includes coupled evolution of volume fractions, granular dilatancy, and pore-fluid pressure (United States)

    George, David L.; Iverson, Richard M.


    Pore-fluid pressure plays a crucial role in debris flows because it counteracts normal stresses at grain contacts and thereby reduces intergranular friction. Pore-pressure feedback accompanying debris deformation is particularly important during the onset of debrisflow motion, when it can dramatically influence the balance of forces governing downslope acceleration. We consider further effects of this feedback by formulating a new, depth-averaged mathematical model that simulates coupled evolution of granular dilatancy, solid and fluid volume fractions, pore-fluid pressure, and flow depth and velocity during all stages of debris-flow motion. To illustrate implications of the model, we use a finite-volume method to compute one-dimensional motion of a debris flow descending a rigid, uniformly inclined slope, and we compare model predictions with data obtained in large-scale experiments at the USGS debris-flow flume. Predictions for the first 1 s of motion show that increasing pore pressures (due to debris contraction) cause liquefaction that enhances flow acceleration. As acceleration continues, however, debris dilation causes dissipation of pore pressures, and this dissipation helps stabilize debris-flow motion. Our numerical predictions of this process match experimental data reasonably well, but predictions might be improved by accounting for the effects of grain-size segregation.

  6. Coupled particle dispersion by three-dimensional vortex structures

    Energy Technology Data Exchange (ETDEWEB)

    Troutt, T.R.; Chung, J.N.; Crowe, C.T.


    The primary objective of this research program is to obtain understanding concerning the role of three-dimensional vortex structures in the dispersion of particles and droplets in free shear flows. This research program builds on previous studies which focused on the nature of particle dispersion in large scale quasi two-dimensional vortex structures. This investigation employs time dependent experimental and numerical techniques to provide information concerning the particulate dispersion produced by three dimensional vortex structures in free shear layers. The free shear flows investigated include modified plane mixing layers, and modified plane wakes. The modifications to these flows involve slight perturbations to the initiation boundary conditions such that three-dimensional vortex structures are rapidly generated by the experimental and numerical flow fields. Recent results support the importance of these vortex structures in the particle dispersion process.

  7. Ionic liquid and aqueous two-phase extraction based on salting-out coupled with high-performance liquid chromatography for the determination of seven rare ginsenosides in Xue-Sai-Tong injection. (United States)

    Li, Lan-Jie; Jin, Yong-Ri; Wang, Xiao-Zhong; Liu, Ying; Wu, Qian; Shi, Xiao-Lei; Li, Xu-Wen


    A method of ionic liquid salt aqueous two-phase extraction coupled with high-performance liquid chromatography has been developed for the analysis of seven rare ginsenosides including Rg6 , F4 , 20(S)-Rg3 , 20(R)-Rg3 , Rk3 , Rk1 , and Rg5 in Xue-Sai-Tong injection. The injection was mixed with ionic liquid 1-butyl-3-methylimidazolium bromide aqueous solution, and a mixture was obtained. With the addition of sodium dodecyl sulfate and dipotassium phosphate into the mixture, the aqueous two-phase mixture was formed after ultrasonic treatment and centrifuged. Rare ginsenosides were extracted into the upper phase. To obtain a high extraction factors, various influences were considered systematically, such as the volume of ionic liquid, the category and amount of salts, the amount of sodium dodecyl sulfate, the pH value of system, and the time of ultrasonic treatment. Under the optimal condition, rare ginsenosides in Xue-Sai-Tong injection were enriched and detected, the recoveries of seven rare ginsenosides ranged from 90.05 to 112.55%, while relative standard deviations were lower than 2.50%. The developed method was reliable, rapid and sensitive for the determination of seven rare ginsenosides in the injections. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. A New Appraoch to Modeling Immiscible Two-phase Flow in Porous Media

    DEFF Research Database (Denmark)

    Yuan, Hao; Shapiro, Alexander; Stenby, Erling Halfdan

    based on Rapoport-Leas Equation and Film Model, a systematic literature review of the LBM CFD methods including the particle-based LBM and porous-medium-based LBM for multiphase flow, and the sample calculation of particle-based LBM in a random porous medium. Finally we come to present a new approach......In this work we present a systematic literature review regarding the macroscopic approaches to modeling immiscible two-phase flow in porous media, the formulation process of the incorporate PDE based on Film Model(viscous coupling), the calculation of saturation profile around the transition zone...... to modeling immiscible two-phase flow in porous media. The suggested approach to immiscible two-phase flow in porous media describes the dispersed mesoscopic fluids’ interfaces which are highly influenced by the injected interfacial energy and the local interfacial energy capacity. It reveals a new...

  9. Stochastic analysis of transverse dispersion in density-coupled transport in aquifers (United States)

    Welty, C.; Kane, A. C.; Kauffman, L.J.


    Spectral perturbation techniques have been used previously to derive integral expressions for dispersive mixing in concentration-dependent transport in three-dimensional, heterogeneous porous media, where fluid density and viscosity are functions of solute concentration. Whereas earlier work focused on evaluating longitudinal dispersivity in isotropic media and incorporating the result in a mean one-dimensional transport model, the emphasis of this paper is on evaluation of the complete dispersion tensor, including the more general case of anisotropic media. Approximate analytic expressions for all components of the macroscopic dispersivity tensor are derived, and the tensor is shown to be asymmetric. The tensor is separated into its symmetric and antisymmetric parts, where the symmetric part is used to calculate the principal components and principal directions of dispersivity, and the antisymmetric part of the tensor is shown to modify the velocity of the solute body compared to that of the background fluid. An example set of numerical simulations incorporating the tensor illustrates the effect of density-coupled dispersivity on a sinking plume in an aquifer. The simulations show that the effective transverse vertical spreading in a sinking plume to be significantly greater than would be predicted by a standard density-coupled transport model that does not incorporate the coupling in the dispersivity tensor.

  10. Ionic liquid-salt aqueous two-phase extraction based on salting-out coupled with high-performance liquid chromatography for the determination of sulfonamides in water and food. (United States)

    Han, Juan; Wang, Yun; Liu, Yan; Li, Yanfang; Lu, Yang; Yan, Yongsheng; Ni, Liang


    Ionic liquid-salt aqueous two-phase extraction coupled with high-performance liquid chromatography with ultraviolet detection was developed for the determination of sulfonamides in water and food samples. In the procedure, the analytes were extracted from the aqueous samples into the ionic liquid top phase in one step. Three sulfonamides, sulfamerazine, sulfamethoxazole, and sulfamethizole were selected here as model compounds for developing and evaluating the method. The effects of various experimental parameters in extraction step were studied using two optimization methods, one variable at a time and Box-Behnken design. The results showed that the amount of sulfonamides did not have effect on the extraction efficiency. Therefore, a three-level Box-Behnken experimental design with three factors, which combined the response surface modeling, was used to optimize sulfonamides extraction. Under the most favorable extraction parameters, the detection limits (S/N = 3) and quantification limits (S/N = 10) of the proposed method for the target compounds were achieved within the range of 0.15-0.3 ng/mL and 0.5-1.0 ng/mL from spiked samples, respectively, which are lower than or comparable with other reported approaches applied to the determination of the same compounds. Finally, the proposed method was successfully applied to the determination of sulfonamide compounds in different water and food samples and satisfactory recoveries of spiked target compounds in real samples were obtained.

  11. Separation, concentration and determination of trace chloramphenicol in shrimp from different waters by using polyoxyethylene lauryl ether-salt aqueous two-phase system coupled with high-performance liquid chromatography. (United States)

    Lu, Yang; Yao, Hui; Li, Chuang; Han, Juan; Tan, Zhenjiang; Yan, Yongsheng


    Polyoxyethylene lauryl ether (POELE10)-NaH2PO4 aqueous two-phase extraction system (ATPES) is coupled with HPLC to analyze chloramphenicol (CAP) in aquatic product. Response surface methodology (RSM) was adopted in the multi-factor experiment to determine the optimized conditions. The extraction efficiency of CAP (E%) is up to 99.42% under the optimal conditions, namely, the concentration of NaH2PO4, the concentration of POELE10, pH and temperature were 0.186 g · mL(-1), 0.033 g · mL(-1), 3.8 and 25 °C respectively. The optimal value of enrichment factor of CAP (F) was 22.56 when the concentration of NaH2PO4 was 0.192 g · mL(-1), the concentration of POELE10 was 0.024 g/ml, pH was 4.2 and temperature was 30 °C. The limit of detection (LOD) and limit of quantification (LOQ) of this method are 0.8 μg · kg(-1) and 1 μg · kg(-1), which meet the needs of determining trace or ultratrace CAP in food. The E% and F of this technique are much better than other extraction methods. Copyright © 2015 Elsevier Ltd. All rights reserved.

  12. Experimental observation of strong coupling effects on the dispersion of dust acoustic waves in a plasma

    CERN Document Server

    Bandyopadhyay, P; Sen, A; Kaw, P K


    The dispersion properties of low frequency dust acoustic waves in the strong coupling regime are investigated experimentally in an argon plasma embedded with a mixture of kaolin and $MnO_2$ dust particles. The neutral pressure is varied over a wide range to change the collisional properties of the dusty plasma. In the low collisional regime the turnover of the dispersion curve at higher wave numbers and the resultant region of $\\partial\\omega/\\partial k < 0$ are identified as signatures of dust-dust correlations. In the high collisional regime dust neutral collisions produce a similar effect and prevent an unambiguous identification of strong coupling effects.

  13. Solitary waves for a coupled nonlinear Schrodinger system with dispersion management

    Directory of Open Access Journals (Sweden)

    Panayotis Panayotaros


    Full Text Available We consider a system of coupled nonlinear Schrodinger equations with periodically varying dispersion coefficient that arises in the context of fiber-optics communication. We use Lions's Concentration Compactness principle to show the existence of standing waves with prescribed L^2 norm in an averaged equation that approximates the coupled system. We also use the Mountain Pass Lemma to prove the existence of standing waves with prescribed frequencies.

  14. Synchronized separation, concentration and determination of trace sulfadiazine and sulfamethazine in food and environment by using polyoxyethylene lauryl ether-salt aqueous two-phase system coupled to high-performance liquid chromatography. (United States)

    Lu, Yang; Cong, Biao; Tan, Zhenjiang; Yan, Yongsheng


    Polyoxyethylene lauryl ether (POELE10)-Na2C4H4O6 aqueous two-phase extraction system (ATPES) is a novel and green pretreatment technique to trace samples. ATPES coupled with high-performance liquid chromatography (HPLC) is used to analyze synchronously sulfadiazine (SDZ) and sulfamethazine (SMT) in animal by-products (i.e., egg and milk) and environmental water sample. It was found that the extraction efficiency (E%) and the enrichment factor (F) of SDZ and SMT were influenced by the types of salts, the concentration of salt, the concentration of POELE10 and the temperature. The orthogonal experimental design (OED) was adopted in the multi-factor experiment to determine the optimized conditions. The final optimal condition was as following: the concentration of POELE10 is 0.027gmL(-1), the concentration of Na2C4H4O6 is 0.180gmL(-1) and the temperature is 35°C. This POELE10-Na2C4H4O6 ATPS was applied to separate and enrich SDZ and SMT in real samples (i.e., water, egg and milk) under the optimal conditions, and it was found that the recovery of SDZ and SMT was 96.20-99.52% with RSD of 0.35-3.41%. The limit of detection (LOD) of this method for the SDZ and SMT in spiked samples was 2.52-3.64pgmL(-1), and the limit of quantitation (LOQ) of this method for the SDZ and SMT in spiked samples was 8.41-12.15pgmL(-1). Copyright © 2016 Elsevier Inc. All rights reserved.

  15. Spatiotemporal coupled-mode theory in dispersive media under a dynamic modulation

    CERN Document Server

    Dana, Brenda; Bahabad, Alon


    A simple and general formalism for mode coupling by a spatial, temporal or spatiotemporal perturbation in dispersive materials is developed. This formalism can be used for studying various linear and non-linear optical interactions involving a dynamic modulation of the interaction parameters such as non-reciprocal phenomena, time reversal of signals and spatiotemporal quasi phase matching

  16. Dispersion and functionalization of nonaqueous synthesized zirconia nanocrystals via attachment of silane coupling agents. (United States)

    Luo, Kaiqing; Zhou, Shuxue; Wu, Limin; Gu, Guangxin


    Zirconia (ZrO 2) nanocrystals, synthesized from zirconium(IV) isopropoxide isopropanol complex and benzyl alcohol, were dispersed and functionalized in organic solvents using three kinds of bifunctional silane coupling agents (SCAs), 3-glycidoxypropyltrimethoxysilane (GPTMS), 3-aminopropyltriethoxysilane (APTES), and 3-isocyanatopropyltriethoxysilane (IPTES). Completely transparent ZrO 2 dispersions were achieved in tetrahydrofuran (THF) with all three SCAs, in pyridine and toluene with APTES and IPTES, and in N, N-dimethylformamide with IPTES. Dynamic laser scattering (DLS) measurements and high-resolution transmission electron microscopical (HRTEM) observation indicated that the ZrO 2 nanocrystals are dispersed on a primary particle size level. Fourier transform infrared spectroscopy, solid-state (13)C- and (29)Si NMR spectroscopy, and thermogravimetric analysis demonstrated that all three SCAs are chemically attached to the surface of the ZrO 2 nanoparticles, however, in different bonding modes. Except for GPTMS/ZrO 2/THF dispersion and IPTES/ZrO 2/pyridine dispersion, all other transparent dispersions have poor long-term stability. The increasing polarity, due to high amount of APTES attached and high hydrolysis and condensation degree of the bonded APTES, and the aggregation, due to interparticle coupling via the bonded triethoxysilyl group, are the causes of the poor long-term stability for the ZrO 2 dispersions with APTES and IPTES, respectively. Nevertheless, the APTES-functionalized ZrO 2 precipitates can be deagglomerated in water to get a stable and transparent aqueous ZrO 2 dispersion via addition of a little hydrochloric acid.

  17. Dispersion and optical gradient force from high-order mode coupling between two hyperbolic metamaterial waveguides

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Guanghui, E-mail:; Zhang, Weifeng; Lu, Jiahui; Zhao, Huijun


    We analytically study dispersion properties and optical gradient forces of different-order transverse magnetic (TM) modes in two coupled hyperbolic metamaterial waveguides (HMMWs). According to Maxwell's equations, we obtain the dispersion relation of symmetric and antisymmetric modes, and calculate optical gradient forces of different-order modes by using Maxwell stress tensor. Numerical results show that the dispersion properties are dependent on the filling ratio, and the optical gradient forces of high-order TM modes are larger than the fundamental mode when the gap between two HMMWs is very narrow, but they weaken much faster than the case of low-order TM modes with the gap width increasing. In addition, the effects of the dielectric surrounding of waveguides on the coupling effect and optical gradient force are clarified. These properties offer an avenue for various optomechanical applications in optical sensors and actuators. - Highlights: • The dependence of dispersion properties in hyperbolic metamaterials on the filling ratio is analyzed. • It is possible that the optical gradient forces of high-order modes are larger than the fundamental mode. • Optical gradient forces of high-order modes weaken much faster than the case of low-order modes. • The influence of the dielectric surrounding on the coupling effect and optical gradient force are clarified.

  18. Two phase titanium aluminide alloy

    Energy Technology Data Exchange (ETDEWEB)

    Deevi, Seetharama C. (Midlothian, VA); Liu, C. T. (Oak Ridge, TN)


    A two-phase titanic aluminide alloy having a lamellar microstructure with little intercolony structures. The alloy can include fine particles such as boride particles at colony boundaries and/or grain boundary equiaxed structures. The alloy can include alloying additions such as .ltoreq.10 at % W, Nb and/or Mo. The alloy can be free of Cr, V, Mn, Cu and/or Ni and can include, in atomic %, 45 to 55% Ti, 40 to 50% Al, 1 to 5% Nb, 0.3 to 2% W, up to 1% Mo and 0.1 to 0.3% B. In weight %, the alloy can include 57 to 60% Ti, 30 to 32% Al, 4 to 9% Nb, up to 2% Mo, 2 to 8% W and 0.02 to 0.08% B.

  19. Multi-camera PIV of two-phase oscillating sheet flow (United States)

    Liu, Chang; Kiger, Ken


    We present a multi-camera thin light sheet imaging method to accurately measure dispersed phase concentration and velocity up to optical densities of close to O [1]. The work is an extension of prior single camera methods that utilize particle image characteristics to identify the dispersed phase and infer the effective measurement volume thickness. By introducing multiple camera perspectives, stereo photogrammetry can be combined with the redundancy of information available in the images to provide 1) increased accuracy in determining individual particle locations, and 2) increased reliability in identifying all of the dispersed phase objects. As a byproduct, the velocity of all three components is also available. As an example, this new method is directly applied to oscillating sheet flow conditions. From a single image pair, individual particles are identified and tracked, giving the instantaneous volume concentration and dispersed phase velocity. A median filter method is used to isolate an image composed only of the much smaller tracer particles, and processed to generate a 3-component continuous phase velocity field. Given the concentration and velocities of the two phases, two-phase flow properties such as the sedimentation rate and momentum coupling will be reported.

  20. Correction of vertical dispersion and betatron coupling for the CLIC damping ring

    CERN Document Server

    Korostelev, M S


    The sensitivity of the CLIC damping ring to various kinds of alignment errors has been studied. Without any correction, fairly small vertical misalignments of the quadrupoles and, in particular, the sextupoles, introduce unacceptable distortions of the closed orbit as well as intolerable spurious vertical dispersion and coupling due to the strong focusing optics of the damping ring. A sophisticated beam-based correction scheme has been developed to bring the design target emittances and the dynamic aperture back to the ideal value. The correction using dipolar correctors and several skew quadrupole correctors allows a minimization of the closed-orbit distortion, the cross-talk between vertical and horizontal closed orbits, the residual vertical dispersion and the betatron coupling.

  1. Polymer-grafted gold nanorods in polymer thin films: Dispersion and plasmonic coupling (United States)

    Hore, Michael-Jon Ainsley

    This dissertation describes complementary experimental and theoretical studies to deter- mine the thermodynamic factors that affect the dispersion of polymer-grafted Au nanorods within polymer thin films. Au nanorods exhibit a uniform dispersion with a regular spacing for favorable brush / matrix interactions, such as poly(ethylene glycol) (PEG)-Au / poly(methyl methacrylate) (PMMA) and polystyrene (PS)-Au / poly(2,6-dimethyl-p-phenylene oxide) (PPO). For PEG-Au / PMMA, the nanorods are locally oriented and their dispersion is independent of the ratio of the degree of polymerization of the matrix (P) to that of the brush (N), α = P/N, whereas for chemically similar brush / matrix combinations, such as PS-Au / PS and PEG-Au / poly(ethylene oxide) (PEO), nanorods are randomly dispersed for α 2. For aggregated systems (α > 2), nanorods are found primarily within aggregates containing side-by-side aligned nanorods with a spacing that scales with N. UV-visible spectroscopy and discrete dipole approximation (DDA) calculations demonstrate that coupling between surface plasmons within the aggregates leads to a blue shift in the optical absorption as α increases, indicating the sensitivity of spectroscopy for determining nanorod dispersion in polymer nanocomposite films. Self-consistent field theory (SCFT) calculations and Monte Carlo (MC) simulations show that the aggregation of nanorods for α > 2 can be attributed to depletion-attraction forces caused by autophobic dewetting of the brush and matrix. Finally, miscible blends of PS and PPO are investigated as a route to control depletion-attraction interactions between PS-Au nanorods. Initially, nanorods aggregate in matrices having 50 vol. % PPO and then gradually disperse as PPO becomes the majority component. The brush and matrix density profiles, determined by SCFT, show that PPO segregates into the PS brush, and acts as a compatibilizer, which improves dispersion. As dispersion improves, coupling between surface

  2. CFD modeling of particle dispersion and deposition coupled with particle dynamical models in a ventilated room (United States)

    Xu, Guangping; Wang, Jiasong


    Two dynamical models, the traditional method of moments coupled model (MCM) and Taylor-series expansion method of moments coupled model (TECM) for particle dispersion distribution and gravitation deposition are developed in three-dimensional ventilated environments. The turbulent airflow field is modeled with the renormalization group (RNG) k-ε turbulence model. The particle number concentration distribution in a ventilated room is obtained by solving the population balance equation coupled with the airflow field. The coupled dynamical models are validated using experimental data. A good agreement between the numerical and experimental results can be achieved. Both models have a similar characteristic for the spatial distribution of particle concentration. Relative to the MCM model, the TECM model presents a more close result to the experimental data. The vortex structure existed in the air flow makes a relative large concentration difference at the center region and results in a spatial non-uniformity of concentration field. With larger inlet velocity, the mixing level of particles in the room is more uniform. In general, the new dynamical models coupled with computational fluid dynamics (CFD) in the current study provide a reasonable and accurate method for the temporal and spatial evolution of particles effected by the deposition and dispersion behaviors. In addition, two ventilation modes with different inlet velocities are proceeded to study the effect on the particle evolution. The results show that with the ceiling ventilation mode (CVM), the particles can be better mixed and the concentration level is also higher. On the contrast, with the side ceiling ventilation mode (SVM), the particle concentration has an obvious stratified distribution with a relative lower level and it makes a much better environment condition to the human exposure.

  3. A carbon-free lithium-ion solid dispersion redox couple with low viscosity for redox flow batteries (United States)

    Qi, Zhaoxiang; Koenig, Gary M.


    A new type of non-aqueous redox couple without carbon additives for flow batteries is proposed and the target anolyte chemistry is demonstrated. The so-called ;Solid Dispersion Redox Couple; incorporates solid electroactive materials dispersed in organic lithium-ion battery electrolyte as its flowing suspension. In this work, a unique and systematic characterization approach has been used to study the flow battery redox couple in half cell demonstrations relative to a lithium electrode. An electrolyte laden with Li4Ti5O12 (LTO) has been characterized in multiple specially designed lithium half cell configurations. The flow battery redox couple described in this report has relatively low viscosity, especially in comparison to other flow batteries with solid active materials. The lack of carbon additive allows characterization of the electrochemical properties of the electroactive material in flow without the complication of conductive additives and unambiguous observation of the electrorheological coupling in these dispersed particle systems.

  4. Dispersive liquid-liquid microextraction coupled with magnetic nanoparticles for extraction of zearalenone in wheat samples

    Directory of Open Access Journals (Sweden)

    Mitra Amoli-Diva


    Full Text Available A new, sensitive and fast dispersive liquid-liquid microextraction (DLLME coupled with micro-solid phase extraction (μ-SPE was developed for determination of zearalenone (ZEN in wheat samples. The DLLME was performed using acetonitrile/water (80:20 v/v as the disperser solvent and 1-octanol as the extracting solvent.  The acetonitrile/water (80:20 v/v solvent was also used to extract ZEN from solid wheat matrix, and was directly applied as the disperser solvent for DLLME process. Additionally, hydrophobic oleic-acid-modified magnetic nanoparticles were used in μ-SPE approach to retrieve the analyte from the DLLME step. So, the method uses high surface area and strong magnetism properties of these nanoparticles to avoid time-consuming column-passing processes in traditional SPE. Main parameters affecting the extraction efficiency and signal enhancement were investigated and optimized. Under the optimum conditions, the calibration curve showed a good linearity in the range of 0.1-500 μg kg−1 (R2=0.9996 with low detection limit of 83 ng g−1. The intra-day and inter-day precisions (as RSD % in the range of 2.6-4.3 % and high recoveries ranging from 91.6 to 99.1 % were obtained. The pre-concentration factor was 3. The method is simple, inexpensive, accurate and remarkably free from interference effects.

  5. Experimental and CFD-PBM approach coupled with a simplified dynamic analysis of mass transfer in phenol biodegradation in a three phase system of an aerated two-phase partitioning bioreactor for environmental applications (United States)

    Moradkhani, Hamed; Anarjan Kouchehbagh, Navideh; Izadkhah, Mir-Shahabeddin


    A three-dimensional transient modeling of a two-phase partitioning bioreactor, combining system hydrodynamics, two simultaneous mass transfer and microorganism growth is modeled using computational fluid dynamics code FLUENT 6.2. The simulation is based on standard "k-ɛ" Reynolds-averaged Navier-Stokes model. Population balance model is implemented in order to describe gas bubble coalescence, breakage and species transport in the reaction medium and to predict oxygen volumetric mass transfer coefficient (kLa). Model results are verified against experimental data and show good agreement as 13 classes of bubble size is taking into account. Flow behavior in different operational conditions is studied. Almost at all impeller speeds and aeration intensities there were acceptable distributions of species caused by proper mixing. The magnitude of dissolved oxygen percentage in aqueous phase has a direct correlation with impeller speed and any increasing of the aeration magnitude leads to faster saturation in shorter periods of time.

  6. Tailoring alphabetical metamaterials in optical frequency: plasmonic coupling, dispersion, and sensing. (United States)

    Zhang, Jun; Cao, Cuong; Xu, Xinlong; Liow, Chihao; Li, Shuzhou; Tan, Pingheng; Xiong, Qihua


    Tailoring optical properties of artificial metamaterials, whose optical properties go beyond the limitations of conventional and naturally occurring materials, is of importance in fundamental research and has led to many important applications such as security imaging, invisible cloak, negative refraction, ultrasensitive sensing, and transformable and switchable optics. Herein, by precisely controlling the size, symmetry, and topology of alphabetical metamaterials with U, S, Y, H, U-bar, and V shapes, we have obtained highly tunable optical response covering visible-to-infrared (vis-NIR) optical frequency. In addition, we show a detailed study on the physical origin of resonance modes, plasmonic coupling, the dispersion of resonance modes, and the possibility of negative refraction. We have found that all the electronic and magnetic modes follow the dispersion of surface plasmon polaritons; thus, essentially they are electronic- and magnetic-surface-plasmon-polaritons-like (ESPP-like and MSPP-like) modes resulted from diffraction coupling between localized surface plasmon and freely propagating light. On the basis of the fill factor and formula of magnetism permeability, we predict that the alphabetical metamaterials should show the negative refraction capability in visible optical frequency. Furthermore, we have demonstrated the specific ultrasensitive surface enhanced Raman spectroscopy (SERS) sensing of monolayer molecules and femtomolar food contaminants by tuning their resonance to match the laser wavelength, or by tuning the laser wavelength to match the plasmon resonance of metamaterials. Our tunable alphabetical metamaterials provide a generic platform to study the electromagnetic properties of metamaterials and explore the novel applications in optical frequency.

  7. Tunable low dispersion optical delay line using three coupled micro-resonators (United States)

    Kalantarov, Dmitriy; Search, Christopher P.


    There is a large demand for integrated photonic devices capable of producing controllable pulse delays of optical signals. Normally, the achievable delay is proportional to the length of the optical path making it difficult to achieve significant delays in chip based devices. We propose a tunable optical delay line consisting of a waveguide coupled in an all pass geometry to a serial array of three micro-ring resonators. The coupling between the whispering gallery modes of the rings leads to a triplet of absorption resonances in between which the group delay is very large while pulse dispersion and attenuation is very small. Moreover, the delay and bandwidth are widely tunable by the coupling between the resonators with delays and bandwidths up to several hundred picoseconds and several tens of GHz, respectively. Although attenuation between the resonances is small, we show that including a modest amount of gain in the second and third resonators eliminates the attenuation regardless of how large the losses are in the first resonator.

  8. Thermal vibrational convection in a two-phase stratified liquid (United States)

    Chang, Qingming; Alexander, J. Iwan D.


    The response of a two-phase stratified liquid system subject to a vibration parallel to an imposed temperature gradient is analyzed using a hybrid thermal lattice Boltzmann method (HTLB). The vibrations considered correspond to sinusoidal translations of a rigid cavity at a fixed frequency. The layers are thermally and mechanically coupled. Interaction between gravity-induced and vibration-induced thermal convection is studied. The ability of the applied vibration to enhance the flow, heat transfer and interface distortion is investigated. For the range of conditions investigated, the results reveal that the effect of the vibrational Rayleigh number and vibrational frequency on a two-phase stratified fluid system is much different from that for a single-phase fluid system. Comparisons of the response of a two-phase stratified fluid system with a single-phase fluid system are discussed. To cite this article: Q. Chang, J.I.D. Alexander, C. R. Mecanique 335 (2007).

  9. Implicit coupling of turbulent diffusion with chemical reaction mechanisms for prognostic atmospheric dispersion models

    Energy Technology Data Exchange (ETDEWEB)

    Berlowitz, D.R.


    In the last few decades the negative impact by humans on the thin atmospheric layer enveloping the earth, the basis for life on this planet, has increased steadily. In order to halt, or at least slow down this development, the knowledge and study of these anthropogenic influence has to be increased and possible remedies have to be suggested. An important tool for these studies are computer models. With their help the atmospheric system can be approximated and the various processes, which have led to the current situation can be quantified. They also serve as an instrument to assess short or medium term strategies to reduce this human impact. However, to assure efficiency as well as accuracy, a careful analysis of the numerous processes involved in the dispersion of pollutants in the atmosphere is called for. This should help to concentrate on the essentials and also prevent excessive usage of sometimes scarce computing resources. The basis of the presented work is the EUMAC Zooming Model (ETM), and particularly the component calculating the dispersion of pollutants in the atmosphere, the model MARS. The model has two main parts: an explicit solver, where the advection and the horizontal diffusion of pollutants are calculated, and an implicit solution mechanism, allowing the joint computation of the change of concentration due to chemical reactions, coupled with the respective influence of the vertical diffusion of the species. The aim of this thesis is to determine particularly the influence of the horizontal components of the turbulent diffusion on the existing implicit solver of the model. Suggestions for a more comprehensive inclusion of the full three dimensional diffusion operator in the implicit solver are made. This is achieved by an appropriate operator splitting. A selection of numerical approaches to tighten the coupling of the diffusion processes with the calculation of the applied chemical reaction mechanisms are examined. (author) figs., tabs., refs.

  10. Two-phase flow in refrigeration systems

    CERN Document Server

    Gu, Junjie; Gan, Zhongxue


    Two-Phase Flow in Refrigeration Systems presents recent developments from the authors' extensive research programs on two-phase flow in refrigeration systems. This book covers advanced mass and heat transfer and vapor compression refrigeration systems and shows how the performance of an automotive air-conditioning system is affected through results obtained experimentally and theoretically, specifically with consideration of two-phase flow and oil concentration. The book is ideal for university postgraduate students as a textbook, researchers and professors as an academic reference book, and b

  11. Dispersive optomechanical coupling between a SiN nanomechanical oscillator and evanescent fields of a silica optical resonator (United States)

    Dong, Chunhua; Htay Oo, Thein; Fiore, Victor; Wang, Hailin


    Tensile stressed SiN nanostrings can feature a picogram effective mass and a mechanical Q-factor exceeding a million. These remarkable nanomechanical oscillators can be dispersively-coupled to an ultra-high finesse optical microresonator via its evanescent field. This composite optomechanical system can potentially lead to a cooperativity that far exceeds that of monolithic optomechanical resonators. Here, we report an experimental study coupling a SiN nanostring to evanescent fields of a whispering gallery mode (WGM) in a silica microsphere. The slight deformation of the microsphere enables us to use free-space optical excitation to probe the optomechanical coupling. The dispersive coupling between a nanostring and the evanescent field of a WGM is generally expected to lead to a red shift in the resonance frequency of the WGM. Our experiments, however, reveal a blue frequency shift of the WGM. Detailed experimental studies and possible physical mechanisms for the blue shift will be presented.

  12. Preparation of cationic polyacrylamide by aqueous two-phase polymerization

    Directory of Open Access Journals (Sweden)


    Full Text Available Cationic polyacrylamide (CPAM was synthesized by aqueous two-phase polymerization technique using acrylamide (AM and dimethylaminoethyl methacrylate methyl chloride (DMC as raw materials, aqueous polyethylene glycol 20000 (PEG 20000 solution as dispersant, 2,2′-azobis(2-amidinopropane dihydrochloride (V-50 as initiator and poly(dimethylaminoethyl methacrylate methyl chloride (PDMC as stabilizer. The polymer was characterized by infrared (IR spectroscopy, 1H-NMR spectrum and transmission electron microscopy (TEM. The copolymer composition was analyzed. The effect of monomers concentration, PEG 20000 concentration and stabilizer concentration on copolymer were investigated, respectively. The optimum reaction conditions for obtaining a stable CPAM aqueous two-phase system were monomers concentration 8~15%, PEG 20000 concentration 15~25%, and PDMC concentration 0.5~1.5%. Finally, the formation process of copolymer particles was investigated by optical microscope.

  13. Evaluation of a coupled dispersion and aerosol process model against measurements near a major road (United States)

    Pohjola, M. A.; Pirjola, L.; Karppinen, A.; Härkönen, J.; Ketzel, M.; Kukkonen, J.


    A field measurement campaign was conducted near a major road "Itäväylä" in an urban area in Helsinki in 17-20 February 2003. Aerosol measurements were conducted using a mobile laboratory "Sniffer" at various distances from the road, and at an urban background location. Measurements included particle size distribution in the size range of 7 nm-10 μm (aerodynamic diameter) by the Electrical Low Pressure Impactor (ELPI) and in the size range of 3-50 nm (mobility diameter) by Scanning Mobility Particle Sizer (SMPS), total number concentration of particles larger than 3 nm detected by an ultrafine condensation particle counter (UCPC), temperature, relative humidity, wind speed and direction, driving route of the mobile laboratory, and traffic density on the studied road. In this study, we have compared measured concentration data with the predictions of the road network dispersion model CAR-FMI used in combination with an aerosol process model MONO32. The vehicular exhaust emissions, and atmospheric dispersion and transformation of fine and ultrafine particles was evaluated within the distance scale of 200 m (corresponding to a time scale of a couple of minutes). We computed the temporal evolution of the number concentrations, size distributions and chemical compositions of various particle size classes. The atmospheric dilution rate of particles is obtained from the roadside dispersion model CAR-FMI. Considering the evolution of total number concentration, dilution was shown to be the most important process. The influence of coagulation and condensation on the number concentrations of particle size modes was found to be negligible at this distance scale. Condensation was found to affect the evolution of particle diameter in the two smallest particle modes. The assumed value of the concentration of condensable organic vapour of 1012 molecules cm-3 was shown to be in a disagreement with the measured particle size evolution, while the modelling runs with the


    Energy Technology Data Exchange (ETDEWEB)

    Scott A. Socolofsky; Brian C. Crounse; E. Eric Adams


    Two-phase plumes play an important role in the more practical scenarios for ocean sequestration of CO{sub 2}--i.e. dispersing CO{sub 2} as a buoyant liquid from either a bottom-mounted or ship-towed pipeline. Despite much research on related applications, such as for reservoir destratification using bubble plumes, our understanding of these flows is incomplete, especially concerning the phenomenon of plume peeling in a stratified ambient. To address this deficiency, we have built a laboratory facility in which we can make fundamental measurements of plume behavior. Although we are using air, oil and sediments as our sources of buoyancy (rather than CO{sub 2}), by using models, our results can be directly applied to field scale CO{sub 2} releases to help us design better CO{sub 2} injection systems, as well as plan and interpret the results of our up-coming international field experiment. The experimental facility designed to study two-phase plume behavior similar to that of an ocean CO{sub 2} release includes the following components: 1.22 x 1.22 x 2.44 m tall glass walled tank; Tanks and piping for the two-tank stratification method for producing step- and linearly-stratified ambient conditions; Density profiling system using a conductivity and temperature probe mounted to an automated depth profiler; Lighting systems, including a virtual point source light for shadowgraphs and a 6 W argon-ion laser for laser induced fluorescence (LIF) imaging; Imaging system, including a digital, progressive scanning CCD camera, computerized framegrabber, and image acquisition and analysis software; Buoyancy source diffusers having four different air diffusers, two oil diffusers, and a planned sediment diffuser; Dye injection method using a Mariotte bottle and a collar diffuser; and Systems integration software using the Labview graphical programming language and Windows NT. In comparison with previously reported experiments, this system allows us to extend the parameter range of

  15. Review of two-phase instabilities

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Han Ok; Seo, Han Ok; Kang, Hyung Suk; Cho, Bong Hyun; Lee, Doo Jeong


    KAERI is carrying out a development of the design for a new type of integral reactors. The once-through helical steam generator is important design features. The study on designs and operating conditions which prevent flow instability should precede the introduction of one-through steam generator. Experiments are currently scheduled to understand two-phase instability, evaluate the effect of each design parameter on the critical point, and determine proper inlet throttling for the prevention of instability. This report covers general two-phase instability with review of existing studies on this topics. The general classification of two phase flow instability and the characteristics of each type of instability are first described. Special attention is paid to BWR core flow instability and once-through steam generator instability. The reactivity feedback and the effect of system parameters are treated mainly for BWR. With relation to once-through steam generators, the characteristics of convective heating and dryout point oscillation are first investigated and then the existing experimental studies are summarized. Finally chapter summarized the proposed correlations for instability boundary conditions. (author). 231 refs., 5 tabs., 47 figs

  16. Dispersion spectrum of acoustoelectric waves in 1D piezoelectric crystal coupled with 2D infinite network of capacitors (United States)

    Kutsenko, A. A.; Shuvalov, A. L.; Poncelet, O.


    A one-dimensional piezoelectric crystal coupled through periodically embedded electrodes with a two-dimensional semi-infinite periodic network of capacitors is considered. The unit cell of the network contains two capacitors with capacitances C1 and C2 which are in parallel and in series, respectively, with the electrodes. The dispersion spectrum of the longitudinal acoustoelectric wave in the piezoelectric crystal coupled with the electric wave of potentials and charges in the network of capacitors is investigated. It is shown that when C1 and C2 are of the same sign, the dispersion spectrum consists of a discrete set of curves, for which the electric wave exponentially decays into the depth of the network of capacitors. In contrast, if C1 and C2 are of the opposite sign and |C1/C2|<1 , then the spectrum simultaneously includes the discrete set of dispersion curves, corresponding to the localized waves, and the continuous band, which admits a finite but not localized (not decaying into the depth) wave field at any frequency and wavenumber within the band. Finally, when C1 and C2 are of the opposite sign and |C1/C2|≥1 , the whole dispersion spectrum is a continuous band. The width of the continuous band and the equation describing the dispersion curves are found explicitly; the equation for the wave field is also obtained. Another interesting spectral feature is the unusual non-monotonic shape of the dispersion curves for a certain range of C1(<0), C2. This shape is due to the hybridization of the individual spectra of the crystal and of the network of capacitors.

  17. Modelling and simulation of temperature and concentration dispersion in a couple stress nanofluid flow through stenotic tapered arteries (United States)

    Ramana Reddy, J. V.; Srikanth, D.; Das, Samir K.


    A couple stress fluid model with the suspension of silver nanoparticles is proposed in order to investigate theoretically the natural convection of temperature and concentration. In particular, the flow is considered in an artery with an obstruction wherein the rheology of blood is taken as a couple stress fluid. The effects of the permeability of the stenosis and the treatment procedure involving a catheter are also considered in the model. The obtained non-linear momentum, temperature and concentration equations are solved using the homotopy perturbation method. Nanoparticles and the two viscosities of the couple stress fluid seem to play a significant role in the flow regime. The pressure drop, flow rate, resistance to the fluid flow and shear stress are computed and their effects are analyzed with respect to various fluids and geometric parameters. Convergence of the temperature and its dependency on the degree of deformation is effectively depicted. It is observed that the Nusselt number increases as the volume fraction increases. Hence magnification of molecular thermal dispersion can be achieved by increasing the nanoparticle concentration. It is also observed that concentration dispersion is greater for severe stenosis and it is maximum at the first extrema. The secondary flow of the axial velocity in the stenotic region is observed and is asymmetric in the tapered artery. The obtained results can be utilized in understanding the increase in heat transfer and enhancement of mass dispersion, which could be used for drug delivery in the treatment of stenotic conditions.

  18. Separation of aqueous two-phase polymer systems in microgravity (United States)

    Vanalstine, J. M.; Harris, J. M.; Synder, S.; Curreri, P. A.; Bamberger, S. B.; Brooks, D. E.


    Phase separation of polymer systems in microgravity is studied in aircraft flights to prepare shuttle experiments. Short duration (20 sec) experiments demonstrate that phase separation proceeds rapidly in low gravity despite appreciable phase viscosities and low liquid interfacial tensions (i.e., 50 cP, 10 micro N/m). Ostwald ripening does not appear to be a satisfactory model for the phase separation mechanism. Polymer coated surfaces are evaluated as a means to localize phases separated in low gravity. Contact angle measurements demonstrate that covalently coupling dextran or PEG to glass drastically alters the 1-g wall wetting behavior of the phases in dextran-PEG two phase systems.

  19. Dynamical dispersion engineering in coupled vertical cavities employing a high-contrast grating

    DEFF Research Database (Denmark)

    Taghizadeh, Alireza; Chung, Il-Sug


    strength. This can be implemented by employing a high-contrast grating (HCG) as the coupling reflector in a system of two coupled vertical cavities, and engineering both the HCG reflection phase and amplitude response. Several examples of HCG-based coupled cavities with novel features are discussed...

  20. Two-phase flow and calcite deposition

    Energy Technology Data Exchange (ETDEWEB)

    Gudmudsson, J.S.; Granadso-G, E.; Ortiz-R, J.


    The literature on two-phase flow in geothermal wells shows that the Orkiszewski method has found wide application in state-of-the-art wellbore simulators. Such a simulator was developed and then used for the problem of wellbore deposition of calcite in the Miravalles geothermal field in Costa Rica. The output of wells suffering calcite deposition decreases slowly at early time but rapidly at late time. The simulator was also used to estimate the deliverability curve for a large diameter well in the Svartsengi geothemal field in Iceland. The view is presented that more accurate wellbore simulators will make new reservoir engineering studies possible in geothermal fields.

  1. Mathematical Modeling of Two-Phase Flow. (United States)


    interactions between the fluids. In spite of much progress (Lahey & Moody 1977), two phase flow studies in nuclear reactors are still a concern. -7- The...Vi)] VX k> , (37) and the interfacial pressure on the kth phase by Pk,iIVak12 , <pk VXR>7 k ( 38) -21- Equation (38) is the dot product of Vak of...functions of a a k /at, Vak , Vk, VVk, 3Vk/at ... where ... represents the material -24- properties, such as the viscosities and densities of the two

  2. Study of the influence of particles on turbulence with the help of direct and large eddy simulations of gas-solid two-phase flows

    Energy Technology Data Exchange (ETDEWEB)

    Boivin, M.


    An investigation of dilute dispersed turbulent two-way coupling two-phase flows has been undertaken with the hemp of Direct Numerical Simulations (DNS) on stationary-forced homogeneous isotropic turbulence. The particle relaxation times range from the Kolmogorov to the Eulerian time scales and the load goes up to 1. The analyses is made within the Eulerian-model framework, enhanced by the National Hydraulics Laboratory Lagrangian approach, which is extended here to include inverse coupling and Reynolds effects. Particles are found to dissipate on average turbulence energy. The spectra of the fluid-particle exchange energy rate show that small particles drag the fluid at high wavenumbers, which explains the observed relative increase of small scale energy. A spectral analysis points as responsible mechanism the transfer of fluid-particle covariance by fluid turbulence. Regarding the modeling, he Reynolds dependency and the load contribution are found crucial for good predictions of the dispersed phase moments. A study for practical applications with Large Eddy Simulations (LES) has yielded: LES can be used two-way coupling two-phase flows provided that a dynamic mixed sub-grid scale model is adopted and the particle relaxation time is larger than the cutoff filter one; the inverse coupling should depend more on the position of this relaxation time with respect to the Eulerian one than to the Kolmogorov one. (author) 67 refs.

  3. Dispersive solvent-free ultrasound-assisted ionic liquid dispersive liquid-liquid microextraction coupled with HPLC for determination of ulipristal acetate. (United States)

    Gong, Aiqin; Zhu, Xiashi


    In this paper, a simple and efficient ultrasound-assisted ionic liquid dispersive liquid-liquid microextraction (UA IL-DLLME) coupled with high-performance liquid chromatography for the analysis of ulipristal acetate (UPA) was developed. UPA could be easily migrated into 1-octyl-3-methylimidazolium hexafluorophosphate [C8mimPF6] IL phase without dispersive solvent. The research of extraction mechanism showed that hydrophobic interaction force played a key role in the IL-DLLME. Several important parameters affecting the extraction recovery were optimized. Under the optimized conditions, 25-fold enrichment factor was obtained and the limit of detection (LOD) was 6.8 ng mL(-1) (tablet) or 9.3 ng mL(-1) (serum) at a signal-to-noise ratio of 3. The calibration curve was linear over the range of 0.03-6.0 µg mL(-1). The proposed method was successfully applied to the UPA tablets and the real mice serum samples. Copyright © 2014 Elsevier B.V. All rights reserved.

  4. Response of two-phase droplets to intense electromagnetic radiation (United States)

    Spann, James F.; Maloney, Daniel J.; Lawson, William F.; Casleton, Kent H.


    The response of two-phase droplets to intense radiant heating is studied to determine the incident power that is required for causing explosive boiling in the liquid phase. The droplets studied consist of strongly absorbing coal particles dispersed in a weakly absorbing water medium. Experiments are performed by confining droplets (radii of 37, 55, and 80 microns) electrodynamically and irradiating them from two sides with pulsed laser beams. Emphasis is placed on the transition region from accelerated droplet vaporization to droplet superheating and explosive boiling. The time scale observed for explosive boiling is more than 2 orders of magnitude longer than published values for pure liquids. The delayed response is the result of energy transfer limitations between the absorbing solid phase and the surrounding liquid.

  5. Mathematical model of two-phase flow in accelerator channel

    Directory of Open Access Journals (Sweden)

    О.Ф. Нікулін


    Full Text Available  The problem of  two-phase flow composed of energy-carrier phase (Newtonian liquid and solid fine-dispersed phase (particles in counter jet mill accelerator channel is considered. The mathematical model bases goes on the supposition that the phases interact with each other like independent substances by means of aerodynamics’ forces in conditions of adiabatic flow. The mathematical model in the form of system of differential equations of order 11 is represented. Derivations of equations by base physical principles for cross-section-averaged quantity are produced. The mathematical model can be used for estimation of any kinematic and thermodynamic flow characteristics for purposely parameters optimization problem solving and transfer functions determination, that take place in  counter jet mill accelerator channel design.

  6. Statistical descriptions of polydisperse turbulent two-phase flows (United States)

    Minier, Jean-Pierre


    Disperse two-phase flows are flows containing two non-miscible phases where one phase is present as a set of discrete elements dispersed in the second one. These discrete elements, or 'particles', can be droplets, bubbles or solid particles having different sizes. This situation encompasses a wide range of phenomena, from nano-particles and colloids sensitive to the molecular fluctuations of the carrier fluid to inertia particles transported by the large-scale motions of turbulent flows and, depending on the phenomenon studied, a broad spectrum of approaches have been developed. The aim of the present article is to analyze statistical models of particles in turbulent flows by addressing this issue as the extension of the classical formulations operating at a molecular or meso-molecular level of description. It has a three-fold purpose: (1) to bring out the thread of continuity between models for discrete particles in turbulent flows (above the hydrodynamical level of description) and classical mesoscopic formulations of statistical physics (below the hydrodynamical level); (2) to reveal the specific challenges met by statistical models in turbulence; (3) to establish a methodology for modeling particle dynamics in random media with non-zero space and time correlations. The presentation is therefore centered on organizing the different approaches, establishing links and clarifying physical foundations. The analysis of disperse two-phase flow models is developed by discussing: first, approaches of classical statistical physics; then, by considering models for single-phase turbulent flows; and, finally, by addressing current formulations for discrete particles in turbulent flows. This brings out that particle-based models do not cease to exist above the hydrodynamical level and offer great interest when combined with proper stochastic formulations to account for the lack of equilibrium distributions and scale separation. In the course of this study, general results

  7. Compressor Properties in Sucking Two Phase Refrigerant (United States)

    Inoue, Seiji; Nakayama, Masahiro; Matsuoka, Fumio

    A simulation model is proposed to analyze refrigerant properties in suction,compression and discharge process in rotary compressors,and compressor performance is analyzed by the calculations and the experiments in this paper. Heat transfer coefficients between the cylinder and refrigerant both in sucking two phase and superheated gas refrigerant have been evaluated by the calculations performed under the condition of the experiments since the validity of the simulation model has been proved by the agreement of the calculation results with the experimental ones. Linear relationship of discharge and cylinder temperature to compressor frequency and suction quality has been clarified by the experimental results. Mechanisms of the compressor performance have also analyzed by the refrigerant properties in the compression mechanism calculated every angle of the rolling piston in detail.

  8. Droplet Manipulations in Two Phase Flow Microfluidics

    Directory of Open Access Journals (Sweden)

    Arjen M. Pit


    Full Text Available Even though droplet microfluidics has been developed since the early 1980s, the number of applications that have resulted in commercial products is still relatively small. This is partly due to an ongoing maturation and integration of existing methods, but possibly also because of the emergence of new techniques, whose potential has not been fully realized. This review summarizes the currently existing techniques for manipulating droplets in two-phase flow microfluidics. Specifically, very recent developments like the use of acoustic waves, magnetic fields, surface energy wells, and electrostatic traps and rails are discussed. The physical principles are explained, and (potential advantages and drawbacks of different methods in the sense of versatility, flexibility, tunability and durability are discussed, where possible, per technique and per droplet operation: generation, transport, sorting, coalescence and splitting.

  9. Lamb wave dispersion and anisotropy profiling of composite plates via non-contact air-coupled and laser ultrasound (United States)

    Harb, M. S.; Yuan, F. G.


    Conventional ultrasound inspection has been a standard non-destructive testing method for providing an in-service evaluation and noninvasive means of probing the interior of a structure. In particular, measurement of the propagation characteristics of Lamb waves allows inspection of plates that are typical components in aerospace industry. A rapid, complete non-contact hybrid approach for excitation and detection of Lamb waves is presented and applied for non-destructive evaluation of composites. An air-coupled transducer (ACT) excites ultrasonic waves on the surface of a composite plate, generating different propagating Lamb wave modes and a laser Doppler vibrometer (LDV) is used to measure the out-of-plane velocity of the plate. This technology, based on direct waveform imaging, focuses on measuring dispersive curves for A0 mode in a composite laminate and its anisotropy. A two-dimensional fast Fourier transform (2D-FFT) is applied to out-of-plane velocity data captured experimentally using LDV to go from the time-spatial domain to frequency-wavenumber domain. The result is a 2D array of amplitudes at discrete frequencies and wavenumbers for A0 mode in a given propagation direction along the composite. The peak values of the curve are then used to construct frequency wavenumber and phase velocity dispersion curves, which are also obtained directly using Snell's law and the incident angle of the excited ultrasonic waves. A high resolution and strong correlation between numerical and experimental results are observed for dispersive curves with Snell's law method in comparison to 2D-FFT method. Dispersion curves as well as velocity curves for the composite plate along different directions of wave propagation are measured. The visual read-out of the dispersion curves at different propagation directions as well as the phase velocity curves provide profiling and measurements of the composite anisotropy. The results proved a high sensitivity of the air-coupled and laser

  10. The surface modification of TiN nano-particles using macromolecular coupling agents, and their resulting dispersibility

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, Guojun, E-mail: [School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039 (China); School of Materials Science and Engineering, Anhui University of Science and Technology, Huainan 232001 (China); Qian, Jiasheng, E-mail: [School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039 (China); Miao, Jibin; Yang, Bin; Xia, Ru; Chen, Peng [School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039 (China)


    Graphical abstract: The hydroxyl groups on the surface of nano-TiN particles interacted with the silanol groups [-Si-OCH{sub 3}] of a F-MCA to form an organic coating layer that hindered the aggregation of the nano-TiN. The obvious agglomeration and homogeneous dispersion can be seen in TEM images. - Highlights: • The dispersible TiN nano-particles were prepared to increase its surface activity. • Surface hydrophobicity increased due to being modified by F-MCA. • TiN nano-particles modified with F-MCA shows good dispersion in anhydrous ethanol. • The coupling agents are tightly absorbed on the surface of particles by chemisorption. • Modified TiN nano-particles can be widely used in polymers with great compatibility. - Abstract: Titanium nitride (TiN) nano-particles were modified by the grafting of a random copolymerization functionalized macromolecular coupling agent (F-MCA) via a direct blending method. The hydroxyl groups on the surface of the nano-TiN particles interact with the silanol groups [-Si-OCH{sub 3}] of the F-MCA to form an organic coating layer. The formation of covalent bonds [Ti-O-Si] was verified using Fourier transform infrared spectroscopy. An X-ray diffraction analysis suggests that the presence of the F-MCA inhibited the growth of the crystal plane but did not change the crystal structure of the TiN. Thermogravimetric analysis and contact angle measurement indicated that the F-MCA molecules were adsorbed or anchored to the surface of the nano-TiN particles, which hindered their aggregation. Pristine nano-TiN particles are poorly dispersed in ethyl acetate. Compared with the pristine TiN particles, the modified TiN particles show good dispersibility and form a stable colloidal dispersion in ethyl acetate. The surface hydrophobicity of the modified TiN increases, and the F-MCA molecules are anchored on the surface of the TiN particles. TiN particles modified by a F-MCA can be used in polymer blends, thermoplastic elastomers and polymer

  11. Hybrid Multiphase CFD Solver for Coupled Dispersed/Segregated Flows in Liquid-Liquid Extraction

    Directory of Open Access Journals (Sweden)

    Kent E. Wardle


    Full Text Available The flows in stage-wise liquid-liquid extraction devices include both phase segregated and dispersed flow regimes. As a additional layer of complexity, for extraction equipment such as the annular centrifugal contactor, free-surface flows also play a critical role in both the mixing and separation regions of the device and cannot be neglected. Traditionally, computional fluid dynamics (CFD of multiphase systems is regime dependent—different methods are used for segregated and dispersed flows. A hybrid multiphase method based on the combination of an Eulerian multifluid solution framework (per-phase momentum equations and sharp interface capturing using Volume of Fluid (VOF on selected phase pairs has been developed using the open-source CFD toolkit OpenFOAM. Demonstration of the solver capability is presented through various examples relevant to liquid-liquid extraction device flows including three-phase, liquid-liquid-air simulations in which a sharp interface is maintained between each liquid and air, but dispersed phase modeling is used for the liquid-liquid interactions.

  12. A Two-phase mixture model of platelet aggregation. (United States)

    Du, Jian; Fogelson, Aaron L


    We present a two-phase model of platelet aggregation in coronary-artery-sized blood vessels. The model tracks the number densities of three platelet populations as well as the concentration of a platelet activating chemical. Through the formation of elastic bonds, activated platelets can cohere with one another to form a platelet thrombus. Bound platelets in a thrombus move in a velocity field different from that of the bulk fluid. Stresses produced by the elastic bonds act on the bound platelet material. Movement of the bound platelet material and that of the background fluid are coupled through an interphase drag and an incompressibility constraint. The relative motion between bound platelets and the background fluid permits intraclot transport of individual platelets and activating chemical, allows the bound platelet density to reach levels much higher than the platelet density in the bulk blood, and allows thrombus formation to occur on a physiological timescale, all of which were precluded by our earlier single phase model. Computational results from the two-phase model indicate that through complicated fluid-structure interactions, the platelet thrombus can develop significant spatial inhomogeneities and that the amount of intraclot flow may greatly affect the growth, density, and stability of a thrombus. © The authors 2017. Published by Oxford University Press on behalf of the Institute of Mathematics and its Applications. All rights reserved.

  13. Development of a Two-Phase Flow Analysis Code based on a Unstructured-Mesh SIMPLE Algorithm

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jong Tae; Park, Ik Kyu; Cho, Heong Kyu; Yoon, Han Young; Kim, Kyung Doo; Jeong, Jae Jun


    For analyses of multi-phase flows in a water-cooled nuclear power plant, a three-dimensional SIMPLE-algorithm based hydrodynamic solver CUPID-S has been developed. As governing equations, it adopts a two-fluid three-field model for the two-phase flows. The three fields represent a continuous liquid, a dispersed droplets, and a vapour field. The governing equations are discretized by a finite volume method on an unstructured grid to handle the geometrical complexity of the nuclear reactors. The phasic momentum equations are coupled and solved with a sparse block Gauss-Seidel matrix solver to increase a numerical stability. The pressure correction equation derived by summing the phasic volume fraction equations is applied on the unstructured mesh in the context of a cell-centered co-located scheme. This paper presents the numerical method and the preliminary results of the calculations.

  14. The surface modification of TiN nano-particles using macromolecular coupling agents, and their resulting dispersibility (United States)

    Cheng, Guojun; Qian, Jiasheng; Miao, Jibin; Yang, Bin; Xia, Ru; Chen, Peng


    Titanium nitride (TiN) nano-particles were modified by the grafting of a random copolymerization functionalized macromolecular coupling agent (F-MCA) via a direct blending method. The hydroxyl groups on the surface of the nano-TiN particles interact with the silanol groups [SiOCH3] of the F-MCA to form an organic coating layer. The formation of covalent bonds [TiOSi] was verified using Fourier transform infrared spectroscopy. An X-ray diffraction analysis suggests that the presence of the F-MCA inhibited the growth of the crystal plane but did not change the crystal structure of the TiN. Thermogravimetric analysis and contact angle measurement indicated that the F-MCA molecules were adsorbed or anchored to the surface of the nano-TiN particles, which hindered their aggregation. Pristine nano-TiN particles are poorly dispersed in ethyl acetate. Compared with the pristine TiN particles, the modified TiN particles show good dispersibility and form a stable colloidal dispersion in ethyl acetate. The surface hydrophobicity of the modified TiN increases, and the F-MCA molecules are anchored on the surface of the TiN particles. TiN particles modified by a F-MCA can be used in polymer blends, thermoplastic elastomers and polymer nanocomposites that have a better performance and longer life cycle.

  15. A new coupling of spectrophotometric determination with ultrasound-assisted emulsification dispersive liquid-liquid microextraction of trace silver (United States)

    Wen, Xiaodong; Kong, Lamei; Chen, Meihui; Deng, Qingwen; Zhao, Xia; Guo, Jie


    In this work, a new coupling of spectrophotometric determination with preconcentration method named as ultrasound-assisted emulsification dispersive liquid-liquid microextraction (UAE-DLLME) for trace silver was firstly established. Disperser solvent in traditional DLLME was substituted by ultrasound-assisted emulsification, which could afford more effective emulsification and make the extraction method greener. The extraction was accomplished efficiently in only 3 min during ultrasound-assisted emulsification. Compared to traditional DLLME, the established pretreatment was simpler, greener and more effective. The UAE-DLLME technique was effectively coupled with ordinary spectrophotometer to improve the analytical performance and expand the application of spectrophotometric determination. The factors influencing UAE-DLLME, such as concentration of chelating agent, kind and volume of extractant, pH, conditions of phase separation, ultrasound extraction time and instrumental conditions, were studied in detail. Under the optimal conditions, the limit of detection (LOD) for silver was 0.45 μg L-1, with sensitivity enhancement factor (EF) of 35. The established method was applied to the determination of trace silver in real and certified reference samples with satisfactory analytical results.

  16. Stability of stratified two-phase flows in horizontal channels

    CERN Document Server

    Barmak, Ilya; Ullmann, Amos; Brauner, Neima; Vitoshkin, Helen


    Linear stability of stratified two-phase flows in horizontal channels to arbitrary wavenumber disturbances is studied. The problem is reduced to Orr-Sommerfeld equations for the stream function disturbances, defined in each sublayer and coupled via boundary conditions that account also for possible interface deformation and capillary forces. Applying the Chebyshev collocation method, the equations and interface boundary conditions are reduced to the generalized eigenvalue problems solved by standard means of numerical linear algebra for the entire spectrum of eigenvalues and the associated eigenvectors. Some additional conclusions concerning the instability nature are derived from the most unstable perturbation patterns. The results are summarized in the form of stability maps showing the operational conditions at which a stratified-smooth flow pattern is stable. It is found that for gas-liquid and liquid-liquid systems the stratified flow with smooth interface is stable only in confined zone of relatively lo...

  17. Modelling compressible dense and dilute two-phase flows (United States)

    Saurel, Richard; Chinnayya, Ashwin; Carmouze, Quentin


    Many two-phase flow situations, from engineering science to astrophysics, deal with transition from dense (high concentration of the condensed phase) to dilute concentration (low concentration of the same phase), covering the entire range of volume fractions. Some models are now well accepted at the two limits, but none are able to cover accurately the entire range, in particular regarding waves propagation. In the present work, an alternative to the Baer and Nunziato (BN) model [Baer, M. R. and Nunziato, J. W., "A two-phase mixture theory for the deflagration-to-detonation transition (DDT) in reactive granular materials," Int. J. Multiphase Flow 12(6), 861 (1986)], initially designed for dense flows, is built. The corresponding model is hyperbolic and thermodynamically consistent. Contrarily to the BN model that involves 6 wave speeds, the new formulation involves 4 waves only, in agreement with the Marble model [Marble, F. E., "Dynamics of a gas containing small solid particles," Combustion and Propulsion (5th AGARD Colloquium) (Pergamon Press, 1963), Vol. 175] based on pressureless Euler equations for the dispersed phase, a well-accepted model for low particle volume concentrations. In the new model, the presence of pressure in the momentum equation of the particles and consideration of volume fractions in the two phases render the model valid for large particle concentrations. A symmetric version of the new model is derived as well for liquids containing gas bubbles. This model version involves 4 characteristic wave speeds as well, but with different velocities. Last, the two sub-models with 4 waves are combined in a unique formulation, valid for the full range of volume fractions. It involves the same 6 wave speeds as the BN model, but at a given point of space, 4 waves only emerge, depending on the local volume fractions. The non-linear pressure waves propagate only in the phase with dominant volume fraction. The new model is tested numerically on various

  18. Vapor Compressor Driven Hybrid Two-Phase Loop Project (United States)

    National Aeronautics and Space Administration — This Small Business Innovation Research Phase I project will demonstrate a vapor compressor driven hybrid two-phase loop technology. The hybrid two-phase loop...

  19. Enzyme mass-transfer coefficient in aqueous two-phase systems using static mixer extraction column. (United States)

    Rostami, K; Alamshahi, M


    Recent technical advances in aqueous two-phase systems (ATPS) have made this a sound technique for the extraction of biomacromolecules. The extraction of alpha-amylase was investigated using aqueous two-phase systems formed by sodium sulphate-polyethylene glycol (PEG) in water in a 47-mm inner diameter spray column packed with three types of static mixers. The effects of dispersed-phase flow rate, phase composition, column height and diameter were studied. The extraction column was operated in a semi-batch manner. It was found that the hold-up and volumetric mass transfer coefficients increased with an increase in dispersed (PEG-rich) phase velocity and decreased with increasing phase composition. Empirical correlations were developed for fractional dispersed-phase hold-up and volumetric mass transfer coefficients.

  20. Thermo-fluid dynamics of two-phase flow

    CERN Document Server

    Ishii, Mamoru; Ishii, Mamoru; Ishii, M


    Provides a very systematic treatment of two phase flow problems from a theoretical perspectiveProvides an easy to follow treatment of modeling and code devlopemnt of two phase flow related phenomenaCovers new results of two phase flow research such as coverage of fuel cells technology.

  1. Solitons of the coupled Schrödinger-Korteweg-de Vries system with arbitrary strengths of the nonlinearity and dispersion (United States)

    Gromov, Evgeny; Malomed, Boris


    New two-component soliton solutions of the coupled high-frequency (HF)—low-frequency (LF) system, based on Schrödinger-Korteweg-de Vries (KdV) system with the Zakharov's coupling, are obtained for arbitrary relative strengths of the nonlinearity and dispersion in the LF component. The complex HF field is governed by the linear Schrödinger equation with a potential generated by the real LF component, which, in turn, is governed by the KdV equation including the ponderomotive coupling term, representing the feedback of the HF field onto the LF component. First, we study the evolution of pulse-shaped pulses by means of direct simulations. In the case when the dispersion of the LF component is weak in comparison to its nonlinearity, the input gives rise to several solitons in which the HF component is much broader than its LF counterpart. In the opposite case, the system creates a single soliton with approximately equal widths of both components. Collisions between stable solitons are studied too, with a conclusion that the collisions are inelastic, with a greater soliton getting still stronger, and the smaller one suffering further attenuation. Robust intrinsic modes are excited in the colliding solitons. A new family of approximate analytical two-component soliton solutions with two free parameters is found for an arbitrary relative strength of the nonlinearity and dispersion of the LF component, assuming weak feedback of the HF field onto the LF component. Further, a one-parameter (non-generic) family of exact bright-soliton solutions, with mutually proportional HF and LF components, is produced too. Intrinsic dynamics of the two-component solitons, induced by a shift of their HF component against the LF one, is also studied, by means of numerical simulations, demonstrating excitation of a robust intrinsic mode. In addition to the above-mentioned results for LF-dominated two-component solitons, which always run in one (positive) velocities, we produce HF

  2. Drag reduction in numerical two-phase Taylor–Couette turbulence using an Euler–Lagrange approach

    NARCIS (Netherlands)

    Arza, Vamsi Spandan; Ostilla-Monico, Rodolfo; Verzicco, Roberto; Lohse, Detlef


    Two-phase turbulent Taylor–Couette (TC) flow is simulated using an Euler–Lagrange approach to study the effects of a secondary phase dispersed into a turbulent carrier phase (here bubbles dispersed into water). The dynamics of the carrier phase is computed using direct numerical simulations (DNS) in

  3. Considerations on data acquisition in laser ablation-inductively coupled plasma-mass spectrometry with low-dispersion interfaces (United States)

    Van Malderen, Stijn J. M.; van Elteren, Johannes T.; Šelih, Vid S.; Vanhaecke, Frank


    This work describes the aliasing effects induced by undersampling the high-frequency signal patterns generated by a laser ablation-inductively coupled plasma-mass spectrometer equipped with a low-dispersion ablation cell and sequential mass analyzer. By characterizing the width of the signal peak generated from a single shot on the sample, critical experimental parameters, such as the laser repetition rate and detector cycle timings for the individual nuclides can be matched so as to avoid these imaging artifacts (spectral skew) induced by an insufficient sampling rate. By increasing the laser repetition rate by a factor 2-3, masses at the end of the mass scan can be sampled at higher sensitivity. Furthermore, the dwell times can be redistributed over the nuclides of interest based on the signal-to-noise ratio to increase the image contrast.

  4. Design of Dispersive Delay Structures (DDSs) Formed by Coupled C-Sections Using Predistortion with Space Mapping

    CERN Document Server

    Zhang, Qingfeng; Caloz, Christophe


    The concept of space mapping is applied, for the first time, to the design of microwave dispersive delay structures (DDSs). DDSs are components providing specified group delay versus frequency responses for real-time radio systems. The DDSs considered in this paper are formed by cascaded coupled C-sections. It is first shown that aggressive space mapping suffers from accuracy issue in the synthesis of DDSs. To address this issue, we propose a predistortion space mapping technique. Compared to aggressive space mapping, this technique provides enhanced accuracy, while compared to output space mapping, it provides greater implementation simplicity. Two full-wave and one experimental examples are provided to illustrate the proposed predistortion space mapping technique.

  5. Analysis of four toxic metals in a single rice seed by matrix solid phase dispersion -inductively coupled plasma mass spectrometry (United States)

    He, Xiufen; Chen, Lixia; Chen, Xin; Yu, Huamei; Peng, Lixu; Han, Bingjun


    Toxic metals in rice pose great risks to human health. Metal bioaccumulation in rice grains is a criterion of breeding. Rice breeding requires a sensitive method to determine metal content in single rice grains to assist the variety selection. In the present study, four toxic metals of arsenic (As), cadmium (Cd), chromium (Cr) and lead (Pb) in a single rice grain were determined by a simple and rapid method. The developed method is based on matrix solid phase dispersion using multi-wall carbon nanotubes (MWCNTs) as dispersing agent and analyzed by inductively coupled plasma mass spectrometry. The experimental parameters were systematically investigated. The limits of detection (LOD) were 5.0, 0.6, 10 and 2.1 ng g-1 for As, Cd, Cr, and Pb, respectively, with relative standard deviations (n = 6) of rice samples analyzed by this method agreed well with those obtained by the standard microwave digestion. The amount of sample required was reduced approximately 100 fold in comparison with the microwave digestion. The method has a high application potential for other sample matrices and elements with high sensitivity and sample throughput.

  6. Enhanced air dispersion modelling at a typical Chinese nuclear power plant site: Coupling RIMPUFF with two advanced diagnostic wind models. (United States)

    Liu, Yun; Li, Hong; Sun, Sida; Fang, Sheng


    An enhanced air dispersion modelling scheme is proposed to cope with the building layout and complex terrain of a typical Chinese nuclear power plant (NPP) site. In this modelling, the California Meteorological Model (CALMET) and the Stationary Wind Fit and Turbulence (SWIFT) are coupled with the Risø Mesoscale PUFF model (RIMPUFF) for refined wind field calculation. The near-field diffusion coefficient correction scheme of the Atmospheric Relative Concentrations in the Building Wakes Computer Code (ARCON96) is adopted to characterize dispersion in building arrays. The proposed method is evaluated by a wind tunnel experiment that replicates the typical Chinese NPP site. For both wind speed/direction and air concentration, the enhanced modelling predictions agree well with the observations. The fraction of the predictions within a factor of 2 and 5 of observations exceeds 55% and 82% respectively in the building area and the complex terrain area. This demonstrates the feasibility of the new enhanced modelling for typical Chinese NPP sites. Copyright © 2017 Elsevier Ltd. All rights reserved.

  7. A sharp interface method for incompressible two-phase flows (United States)

    Sussman, M.; Smith, K. M.; Hussaini, M. Y.; Ohta, M.; Zhi-Wei, R.


    We present a sharp interface method for computing incompressible immiscible two-phase flows. It couples the level-set and volume-of-fluid techniques and retains their advantages while overcoming their weaknesses. It is stable and robust even for large density and viscosity ratios on the order of 1000 to 1. The numerical method is an extension of the second-order method presented by Sussman [M. Sussman, A second order coupled levelset and volume of fluid method for computing growth and collapse of vapor bubbles, Journal of Computational Physics 187 (2003) 110-136] in which the previous method treated the gas pressure as spatially constant and the present method treats the gas as a second incompressible fluid. The new method yields solutions in the zero gas density limit which are comparable in accuracy to the method in which the gas pressure was treated as spatially constant. This improvement in accuracy allows one to compute accurate solutions on relatively coarse grids, thereby providing a speed-up over continuum or "ghost-fluid" methods.

  8. Tsunami Generated by a Two-Phase Submarine Debris Flow (United States)

    Pudasaini, S. P.


    The general two-phase debris flow model proposed by Pudasaini (2011) is employed to study subaerial and submarine debris flows, and the tsunami generated by the debris impact at lakes and oceans. The model includes several essential physical aspects, including Mohr-Coulomb plasticity for the solid stress, while the fluid stress is modelled as a solid volume fraction gradient enhanced non-Newtonian viscous stress. The generalized interfacial momentum transfer includes the viscous drag, buoyancy, and the virtual mass. The generalized drag covers both the solid-like and fluid-like contributions, and can be applied to linear to quadratic drags. Strong couplings exist between the solid and the fluid momentum transfer. The advantage of the real two-phase debris flow model over classical single-phase or quasi-two-phase models is that by considering the solid (and/or the fluid) volume fraction appropriately, the initial mass can be divided into several (even mutually disjoint) parts; a dry (landslide or rock slide), a fluid (water or muddy water; e.g., dams, rivers), and a general debris mixture material as needed in real flow simulations. This offers a unique and innovative opportunity within a single framework to simultaneously simulate (a) the sliding debris (or landslide), (b) the water lake or ocean, (c) the debris impact at the lake or ocean, (d) tsunami generation and propagation, (e) mixing and separation between the solid and the fluid phases, and (f) sediment transport and deposition process in the bathymetric surface. The new model is applied to two-phase subaerial and submarine debris flows. Benchmark numerical simulations reveal that the dynamics of the debris impact induced tsunamis are fundamentally different than the tsunami generated by pure rock avalanche and landslides. Special attention is paid to study the basic features of the debris impact to the mountain lakes or oceans. This includes the generation, amplification and propagation of the multiple

  9. A bi-directional two-phase/two-phase heat exchanger (United States)

    Ku, Jentung; Ottenstein, Laura


    This paper describes the design and test of a heat exchanger that transfers heat from one two-phase thermal loop to another with very small drops in temperature and pressure. The heat exchanger condenses the vapor in one loop while evaporating the liquid in the other without mixing of the condensing and evaporating fluids. The heat exchanger is bidirectional in that it can transfer heat in reverse, condensing on the normally evaporating side and vice versa. It is fully compatible with capillary pumped loops and mechanically pumped loops. Test results verified that performance of the heat exchanger met the design requirements. It demonstrated a heat transfer rate of 6800 watts in the normal mode of operation and 1000 watts in the reverse mode with temperature drops of less than 5 C between two thermal loops.

  10. Gasdynamic Aspects of Two-Phase Flow Hyperbolicity, Wave Propagation Phenomena, and Related Numerical Methods

    CERN Document Server

    Staedtke, Herbert


    Here, the author, a researcher of outstanding experience in this field, summarizes and combines the recent results and findings on advanced two-phase flow modeling and numerical methods otherwise dispersed in various journals, while also providing explanations for numerical and modeling techniques previously not covered by other books. The resulting systematic and comprehensive monograph is unrivalled in its kind, serving as a reference for both researchers and engineers working in engineering as well as in environmental science.

  11. Experimental and CFD-PBM Study of Oxygen Mass Transfer Coefficient in Different Impeller Configurations and Operational Conditions of a Two-Phase Partitioning Bioreactor. (United States)

    Moradkhani, Hamed; Izadkhah, Mir-Shahabeddin; Anarjan, Navideh


    In this work, gas dispersion in a two-phase partitioning bioreactor is analyzed by calculating volumetric oxygen mass transfer coefficient which is modeled using a commercial computational fluid dynamics (CFD), code FLUENT 6.2. Dispersed oxygen bubbles dynamics is based on standard "k-ε" Reynolds-averaged Navier-Stokes (RANS) model. This paper describes a three-dimensional CFD model coupled with population balance equations (PBE) in order to get more confirming results of experimental measurements. Values of k L a are obtained using dynamic gassing-out method. Using the CFD simulation, the volumetric mass transfer coefficient is calculated based on Higbie's penetration theory. Characteristics of mass transfer coefficient are investigated for five configurations of impeller and three different aeration flow rates. The pitched six blade type, due to the creation of downward flow direction, leads to higher dissolved oxygen (DO) concentrations, thereby, higher values of k L a compared with other impeller compositions. The magnitude of dissolved oxygen percentage in the aqueous phase has direct correlation with impeller speed and any increase of the aeration magnitude leads to faster saturation in shorter periods of time. Agitation speeds of 300 to 800 rpm are found to be the most effective rotational speeds for the mass transfer of oxygen in two-phase partitioning bioreactors (TPPB).

  12. Advances in isoflavone profile characterisation using matrix solid-phase dispersion coupled to HPLC/DAD in Medicago species. (United States)

    Visnevschi-Necrasov, Tatiana; Barreira, João C M; Cunha, Sara C; Pereira, Graça; Nunes, Eugénia; Oliveira, M Beatriz P P


    Analytical methods used in phytochemistry analysis are limited by the sample preparation step, which should ideally be fast, accurate, ecofriendly and achievable using low quantities of the sample. Matrix solid-phase dispersion (MSPD) may be a good alternative for combining extraction and purification procedures, thereby reducing the indicated limitations. Applying an MSPD extraction procedure coupled to high-performance liquid chromatography diode-array detection (HPLC/DAD) as an alternative methodology to evaluate isoflavone profiles. Isoflavone profiles were determined for the leaves of nine species of Medicago in the late flower phenological stage (one or more nodes with 50% open flowers, no seed pods). Extraction was performed following MSPD, and isoflavone profiles were characterised using HPLC/DAD. The quantified amounts were compared with previous results in different species commonly recognised as good sources of isoflavones. Formononetin was the major isoflavone in most species, except M. polymorpha and M. truncatula. The isoflavone amounts were significantly different among the assayed species, with M. orbicularis and M. arabica as the major isoflavone sources, while M. rigidula presented the lowest contents. Furthermore, the detected differences allow electing the best species as a primary source of a specific isoflavone. The MSPD allowed good extraction efficiency, reproducibility and recovery. Some of the species showed relevant isoflavone contents, even when compared with acknowledged plant sources such as soy or red clover. To the best of our knowledge the results presented are reported for the first time in these species. Copyright © 2014 John Wiley & Sons, Ltd.

  13. Matrix solid-phase dispersion coupled with magnetic ionic liquid dispersive liquid-liquid microextraction for the determination of triazine herbicides in oilseeds. (United States)

    Wang, Yuanpeng; Sun, Ying; Xu, Bo; Li, Xinpei; Wang, Xinghua; Zhang, Hanqi; Song, Daqian


    A novel method was developed for the determination of six triazine herbicides from oilseeds by matrix solid-phase dispersion combined with magnetic ionic liquid dispersive liquid-liquid microextraction (MSPD-MIL-DLLME), followed by ultrafast liquid chromatography with ultraviolet detection (UFLC-UV). The MIL, 1-butyl-3-methylimidazolium tetrachloroferrate ([C4mim][FeCl4]), was used as the microextraction solvent to simplify the extraction procedure by magnetic separation. The effects of several important experimental parameters, including type of dispersant, ratio of sample to dispersant, type and volume of collected elution solvent, type and volume of MIL, were investigated. Using the present method, UFLC-UV gave the limits of detection (LODs) of 1.20-2.72 ng g(-1) and the limits of quantification (LOQs) of 3.99-9.06 ng g(-1) for triazine herbicides. The recoveries were ranged from 82.9 to 113.7% and the relative standard deviations (RSDs) were equal or lower than 7.7%. The present method is easy-to-use and effective for extraction of triazine herbicides from oilseeds and shows the potentials of practical applications in the treatment of the fatty solid samples. Copyright © 2015 Elsevier B.V. All rights reserved.

  14. Two-phase flow in geopressured geothermal wells

    Energy Technology Data Exchange (ETDEWEB)

    Grag, S.K.; Pritchett, J.W.; Meriwether, J.


    The production characteristics of two-phase (free methane and liquid water with dissolved methane) geopressured geothermal wells are analyzed. The fluid flow in the aquifer is treated as single-phase (liquid water with dissolved methane) unsteady radial Darcian flow; two-phase flow is assumed to occur only in the cased part of the production hole. The mathematical model allows for different gas and liquid velocities in the two-phase regime. Sample calculations illustrate the effects on production of aquifer permeability and compressibility, the depth of the geopressured aquifer, the reservoir temperature, and the dissolved methane content of the aquifer fluids.

  15. Gravity Independence of Microchannel Two-Phase Flow Project (United States)

    National Aeronautics and Space Administration — Most of the amassed two-phase flow and heat transfer knowledge comes from experiments conducted in Earth’s gravity. Space missions span varying gravity levels,...

  16. Vapor Compressor Driven Hybrid Two-Phase Loop Project (United States)

    National Aeronautics and Space Administration — The Phase I project successfully demonstrated the feasibility of the vapor compression hybrid two-phase loop (VCHTPL). The test results showed the high...

  17. [Extract berberine hydrochloride by aqueous two-phase system]. (United States)

    Wen, Chi-Fu; Xiang, Xiao-Qi; Zeng, Wei-Xiang; Wu, Ting; Tian, Chun-Lian


    To study the aqueous two-phase system which could be used for extraction of berberine hydrochloride. Three aqueous two-phase systems were used for extraction experiment firstly, the best one was chosen from that, and then the single factor experiment and orthogonal experiment were carried out. 10 mL 95% ethanol with 10 mL 2.2 mol/L ammonium sulfate could make a aqueous two-phase system, added 600 mg berberine hydrochloride whose purity was 53.22% into it, regulated its pH to 4, then the system was put into water-bath heater (70 degrees C) for 30 min, the extraction rate could reach 99.29%; Collected the extraction liquid, dried it under 40 degrees C, the purity of berberine hydrochloride was 88.43%. This system is a suitable aqueous two-phase system for extraction of berberine hydrochloride.

  18. Aqueous Two Phase System Assisted Self-Assembled PLGA Microparticles

    National Research Council Canada - National Science Library

    Yeredla, Nitish; Kojima, Taisuke; Yang, Yi; Takayama, Shuichi; Kanapathipillai, Mathumai


    Here, we produce poly(lactide-co-glycolide) (PLGA) based microparticles with varying morphologies, and temperature responsive properties utilizing a Pluronic F127/dextran aqueous two-phase system (ATPS...

  19. Scaling of Two-Phase Systems Across Gravity Levels Project (United States)

    National Aeronautics and Space Administration — There is a defined need for long term earth based testing for the development and deployment of two-phase flow systems in reduced-gravity, including lunar gravity,...

  20. Digital image processing for two-phase flow

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jae Young; Lim, Jae Yun [Cheju National University, Cheju (Korea, Republic of); No, Hee Cheon [Korea Advanced Institute of Science and Technology, Taejon (Korea, Republic of)


    A photographic method to measure the key parameters of two-phase flow is realized by using a digital image processing technique. The 8 bit gray level and 256 x 256 pixels are used to generates the image data which is treated to get the parameters of two-phase flow. It is observed that the key parameters could be identified by treating data obtained by the digital image processing technique.

  1. Two-phase cooling fluids; Les fluides frigoporteurs diphasiques

    Energy Technology Data Exchange (ETDEWEB)

    Lallemand, A. [Institut National des Sciences Appliquees (INSA), 69 - Lyon (France)


    In the framework of the diminution of heat transfer fluid consumption, the concept of indirect refrigerating circuits, using cooling intermediate fluids, is reviewed and the fluids that are currently used in these systems are described. Two-phase cooling fluids advantages over single-phase fluids are presented with their thermophysical characteristics: solid fraction, two-phase mixture enthalpy, thermal and rheological properties, determination of heat and mass transfer characteristics, and cold storage through ice slurry

  2. Numerical Investigations of Two-phase Flows through Enhanced Microchannels


    Chandra, A.K.; Kishor, K.; Mishra, P. K.; Alam, M.S.


    Microfluidic devices are quite important for process industries, as these devices can intensify heat and mass transfer in two-phase reaction systems. Two-phase reaction systems, such as gas-liquid and liquid-liquid reactions with certain limitations have already been carried out in microfluidic systems by a few authors. However, these concepts are still under development and a detailed understanding of the hydrodynamics involve is required. Hydrodynamics studies are inherently crucial to p...

  3. Refrigeration. Two-Phase Flow. Flow Regimes and Pressure Drop

    DEFF Research Database (Denmark)

    Knudsen, Hans-Jørgen Høgaard


    The note gives the basic definitions used in two-phase flow. Flow regimes and flow regimes map are introduced. The different contributions to the pressure drop are stated together with an imperical correlation from the litterature.......The note gives the basic definitions used in two-phase flow. Flow regimes and flow regimes map are introduced. The different contributions to the pressure drop are stated together with an imperical correlation from the litterature....

  4. Advanced in numerical modelling of two-phase flow

    Energy Technology Data Exchange (ETDEWEB)

    Paillere, H.; Kumbaro, A.; Toumi, I. [CEA Saclay, Dept. de Mecanique et de Technologie, 91 - Gif-sur-Yvette (France)


    Numerical modelling of two-phase flow using Godunov-type solvers is making progress. Schemes such as the Roe scheme, or the less sophisticated AUSM+scheme, have the ability to resolve propagating waves such as void or shock waves with no oscillations. Transition from two-phase to single phase flow can also be modelled, and interfaces captured in a satisfactory way. Extension to 3D and validation on more complex flow fields are also presently being performed. (authors)

  5. Convergence of Discontinuous Galerkin Methods for Incompressible Two-Phase Flow in Heterogeneous Media

    KAUST Repository

    Kou, Jisheng


    A class of discontinuous Galerkin methods with interior penalties is presented for incompressible two-phase flow in heterogeneous porous media with capillary pressures. The semidiscrete approximate schemes for fully coupled system of two-phase flow are formulated. In highly heterogeneous permeable media, the saturation is discontinuous due to different capillary pressures, and therefore, the proposed methods incorporate the capillary pressures in the pressure equation instead of saturation equation. By introducing a coupling approach for stability and error estimates instead of the conventional separate analysis for pressure and saturation, the stability of the schemes in space and time and a priori hp error estimates are presented in the L2(H 1) for pressure and in the L∞(L2) and L2(H1) for saturation. Two time discretization schemes are introduced for effectively computing the discrete solutions. © 2013 Societ y for Industrial and Applied Mathematics.

  6. Numerical simulation and analysis of solid-liquid two-phase flow in centrifugal pump (United States)

    Zhang, Yuliang; Li, Yi; Cui, Baoling; Zhu, Zuchao; Dou, Huashu


    The flow with solid-liquid two-phase media inside centrifugal pumps is very complicated and the relevant method for the hydraulic design is still immature so far. There exist two main problems in the operation of the two-phase flow pumps, i.e., low overall efficiency and severe abrasion. In this study, the three-dimensional, steady, incompressible, and turbulent solid-liquid two-phase flows in a low-specific-speed centrifugal pump are numerically simulated and analyzed by using a computational fluid dynamics (CFD) code based on the mixture model of the two-phase flow and the RNG k- ɛ two-equation turbulence model, in which the influences of rotation and curvature are fully taken into account. The coupling between impeller and volute is implemented by means of the frozen rotor method. The simulation results predicted indicate that the solid phase properties in two-phase flow, especially the concentration, the particle diameter and the density, have strong effects on the hydraulic performance of the pump. Both the pump head and the efficiency are reduced with increasing particle diameter or concentration. However, the effect of particle density on the performance is relatively minor. An obvious jet-wake flow structure is presented near the volute tongue and becomes more remarkable with increasing solid phase concentration. The suction side of the blade is subject to much more severe abrasion than the pressure side. The obtained results preliminarily reveal the characteristics of solid-liquid two-phase flow in the centrifugal pump, and are helpful for improvement and empirical correction in the hydraulic design of centrifugal pumps.

  7. Numerical methods for two-phase flow with contact lines

    Energy Technology Data Exchange (ETDEWEB)

    Walker, Clauido


    This thesis focuses on numerical methods for two-phase flows, and especially flows with a moving contact line. Moving contact lines occur where the interface between two fluids is in contact with a solid wall. At the location where both fluids and the wall meet, the common continuum descriptions for fluids are not longer valid, since the dynamics around such a contact line are governed by interactions at the molecular level. Therefore the standard numerical continuum models have to be adjusted to handle moving contact lines. In the main part of the thesis a method to manipulate the position and the velocity of a contact line in a two-phase solver, is described. The Navier-Stokes equations are discretized using an explicit finite difference method on a staggered grid. The position of the interface is tracked with the level set method and the discontinuities at the interface are treated in a sharp manner with the ghost fluid method. The contact line is tracked explicitly and its dynamics can be described by an arbitrary function. The key part of the procedure is to enforce a coupling between the contact line and the Navier-Stokes equations as well as the level set method. Results for different contact line models are presented and it is demonstrated that they are in agreement with analytical solutions or results reported in the literature.The presented Navier-Stokes solver is applied as a part in a multiscale method to simulate capillary driven flows. A relation between the contact angle and the contact line velocity is computed by a phase field model resolving the micro scale dynamics in the region around the contact line. The relation of the microscale model is then used to prescribe the dynamics of the contact line in the macro scale solver. This approach allows to exploit the scale separation between the contact line dynamics and the bulk flow. Therefore coarser meshes can be applied for the macro scale flow solver compared to global phase field simulations

  8. Matrix solid-phase dispersion coupled with homogeneous ionic liquid microextraction for the determination of sulfonamides in animal tissues using high-performance liquid chromatography. (United States)

    Wang, Zhibing; He, Mengyu; Jiang, Chunzhu; Zhang, Fengqing; Du, Shanshan; Feng, Wennan; Zhang, Hanqi


    Matrix solid-phase dispersion coupled with homogeneous ionic liquid microextraction was developed and applied to the extraction of some sulfonamides, including sulfamerazine, sulfamethazine, sulfathiazole, sulfachloropyridazine, sulfadoxine, sulfisoxazole, and sulfaphenazole, in animal tissues. High-performance liquid chromatography was applied to the separation and determination of the target analytes. The solid sample was directly treated by matrix solid-phase dispersion and the eluate obtained was treated by homogeneous ionic liquid microextraction. The ionic liquid was used as the extraction solvent in this method, which may result in the improvement of the recoveries of the target analytes. To avoid using organic solvent and reduce environmental pollution, water was used as the elution solvent of matrix solid-phase dispersion. The effects of the experimental parameters on recoveries, including the type and volume of ionic liquid, type of dispersant, ratio of sample to dispersant, pH value of elution solvent, volume of elution solvent, amount of salt in eluate, amount of ion-pairing agent (NH4 PF6 ), and centrifuging time, were evaluated. When the present method was applied to the analysis of animal tissues, the recoveries of the analytes ranged from 85.4 to 118.0%, and the relative standard deviations were lower than 9.30%. The detection limits for the analytes were 4.3-13.4 μg/kg. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Matrix Solid-Phase Dispersion Coupled with High-Performance Liquid Chromatography Diode Array Detection for Simultaneous Determination of Four Lipophilic Constituents from Salvia miltiorrhiza Bunge. (United States)

    Wang, Zhibing; Ma, Siyu; Zhang, Qian; He, Shuang; Li, Qing; Hu, Jianxue; Zhang, Hanqi


    A simple, rapid and efficient method based on matrix solid-phase dispersion coupled with high-performance liquid chromatography was developed for determination of lipophilic constituents, including dihydrotanshinone, tanshinone I, cryptotanshinone and tanshinone II A in Salvia miltiorrhiza Bunge Box-Behnken design was employed for optimization of the extraction conditions of matrix solid-phase dispersion, including mass ratio of dispersant to sample, volume of elution solvent, and amount of cleanup reagent. The optimal experimental results were obtained using 0.27 g of acid alumina as dispersant, 13 mL of acetonitrile as elution solvent and 0.36 g of acid alumina as cleanup reagent. The target analytes was determined by high-performance liquid chromatography. The recoveries of tanshinones obtained by analyzing the spiked samples were from 83.81% to 93.74% and relative standard deviations from 2.87% to 6.83%. Matrix solid-phase dispersion integrated the extraction and cleanup into a single step, which provides the advantages of being simple, fast and convenient. Compared with other conventional methods, the present method consumed less time and less organic solvent. The results demonstrate that this method has potential for the determination of active constituents and the quality control of traditional Chinese medicine. © The Author 2016. Published by Oxford University Press. All rights reserved. For Permissions, please email:

  10. Two-Phase Immiscible Flows in Porous Media: The Mesocopic Maxwell–Stefan Approach

    DEFF Research Database (Denmark)

    Shapiro, Alexander


    We develop an approach to coupling between viscous flows of the two phases in porous media, based on the Maxwell–Stefan formalism. Two versions of the formalism are presented: the general form, and the form based on the interaction of the flowing phases with the interface between them. The last...... approach is supported by the description of the flow on the mesoscopic level, as coupled boundary problems for the Brinkmann or Stokes equations. It becomes possible, in some simplifying geometric assumptions, to derive exact expressions for the phenomenological coefficients in the Maxwell–Stefan transport...

  11. Dispersion of overdamped diffusing particles in channel flows coupled to transverse acoustophoretic potentials: transport regimes and scaling anomalies. (United States)

    Giona, Massimiliano; Garofalo, Fabio


    We address the dispersion properties of overdamped Brownian particles migrating in a two-dimensional acoustophoretic microchannel, where a pressure-driven axial Stokes flow coexists with a transverse acoustophoretic potential. Depending on the number and symmetries of the stable nodal points of the acoustophoretic force with respect to the axial velocity profile, different convection-enhanced dispersion regimes can be observed. Among these regimes, an anomalous scaling, for which the axial dispersion increases exponentially with the particle Peclét number, is observed whenever two or more stable acoustophoretic nodes are associated with different axial velocities. A theoretical explanation of this regime is derived, based on exact moment homogenization. Attention is also focused on transient dispersion, which can exhibit superballistic behavior 〈(x-〈x〉)^{2}〉∼t^{3},x being the axial coordinate.

  12. Two-phase flow with mass transfer in bubble columns

    Energy Technology Data Exchange (ETDEWEB)

    Mewes, D.; Wiemann, D. [Institute of Process Engineering, University of Hannover, D-30167 Hannover (Germany)


    Bubble columns are widely used in the chemical and biochemical industries. In these reactors a gaseous phase is dispersed into a continuous liquid phase thus the rising bubble swarm induces a circulating flow field. For the dimension of these reactors the local interfacial area and the residence time of the liquid and the gaseous phase are key parameters. In this paper an Euler-Euler approach is used to calculate the flow field in bubble columns numerically. Therefore a transport equation for the mean bubble volume based on a population balance equation approach is coupled with the balance equations for mass and momentum. The calculations are performed for three-dimensional, instationary flow fields in cylindrical bubble columns considering the homogeneous and the heterogeneous flow regime. For the interphase mass transfer the physical absorption of the gaseous phase into the liquid is assumed. The back mixing in the gaseous and liquid phase is calculated from the local and time dependent concentration of a tracer. (Abstract Copyright [2003], Wiley Periodicals, Inc.)

  13. A mechanical erosion model for two-phase mass flows

    CERN Document Server

    Pudasaini, Shiva P


    Erosion, entrainment and deposition are complex and dominant, but yet poorly understood, mechanical processes in geophysical mass flows. Here, we propose a novel, process-based, two-phase, erosion-deposition model capable of adequately describing these complex phenomena commonly observed in landslides, avalanches, debris flows and bedload transport. The model is based on the jump in the momentum flux including changes of material and flow properties along the flow-bed interface and enhances an existing general two-phase mass flow model (Pudasaini, 2012). A two-phase variably saturated erodible basal morphology is introduced and allows for the evolution of erosion-deposition-depths, incorporating the inherent physical process including momentum and rheological changes of the flowing mixture. By rigorous derivation, we show that appropriate incorporation of the mass and momentum productions or losses in conservative model formulation is essential for the physically correct and mathematically consistent descript...

  14. Dynamic Modeling of Phase Crossings in Two-Phase Flow

    DEFF Research Database (Denmark)

    Madsen, Søren; Veje, Christian; Willatzen, Morten


    Two-phase flow and heat transfer, such as boiling and condensing flows, are complicated physical phenomena that generally prohibit an exact solution and even pose severe challenges for numerical approaches. If numerical solution time is also an issue the challenge increases even further. We present...... of the variables and are usually very slow to evaluate. To overcome these challenges, we use an interpolation scheme with local refinement. The simulations show that the method handles crossing of the saturation lines for both liquid to two-phase and two-phase to gas regions. Furthermore, a novel result obtained...... in this work, the method is stable towards dynamic transitions of the inlet/outlet boundaries across the saturation lines. Results for these cases are presented along with a numerical demonstration of conservation of mass under dynamically varying boundary conditions. Finally we present results...

  15. Coupled-mode theory for electromagnetic pulse propagation in dispersive media undergoing a spatiotemporal perturbation: Exact derivation, numerical validation, and peculiar wave mixing (United States)

    Sivan, Y.; Rozenberg, S.; Halstuch, A.


    We present an extension of the canonical coupled-mode theory of electromagnetic waves to the case of pulses and spatiotemporal perturbations in complex media. Unlike previous attempts to derive such a model, our approach involves no approximation, and it does not impose any restriction on the spatiotemporal profile. Moreover, the effect of modal dispersion on mode evolution and on the coupling to other modes is fully taken into account. Thus, our approach can yield any required accuracy by retaining as many terms in the expansion as needed. It also avoids various artifacts of previous derivations by introducing the correct form of the solution. We then validate the coupled-mode equations with exact numerical simulations, and we demonstrate the wide range of possibilities enabled by spatiotemporal perturbations of pulses, including pulse shortening or broadening or more complex shaping. Our formulation is valid across the electromagnetic spectrum, and it can be applied directly also to other wave systems.

  16. Experimental study of precessing vortex core in two-phase flow

    Directory of Open Access Journals (Sweden)

    Vinokurov Alexey


    Full Text Available The work is devoted to the study of a precessing vortex core (PVC in a swirling gas-liquid flow in an axisymmetric hydrodynamic chamber. The influence of the dispersed gas phase on the frequency of PVC precession and on the pressure in the hydrodynamic chamber is considered, and a correlation of the changes in these characteristics depending on gas content variation is demonstrated. The effect of flow swirling on the precession of the vortex core is shown. Experimental data for the two-phase flow are compared with the case of single-phase system.

  17. Experimental Study about Two-phase Damping Ratio on a Tube Bundle Subjected to Homogeneous Two-phase Flow

    Energy Technology Data Exchange (ETDEWEB)

    Sim, Woo Gun; Dagdan, Banzragch [Hannam Univ., Daejeon (Korea, Republic of)


    Two-phase cross flow exists in many shell-and-tube heat exchangers such as condensers, evaporators, and nuclear steam generators. The drag force acting on a tube bundle subjected to air/water flow is evaluated experimentally. The cylinders subjected to two-phase flow are arranged in a normal square array. The ratio of pitch to diameter is 1.35, and the diameter of the cylinder is 18 mm. The drag force along the flow direction on the tube bundles is measured to calculate the drag coefficient and the two-phase damping ratio. The two-phase damping ratios, given by the analytical model for a homogeneous two-phase flow, are compared with experimental results. The correlation factor between the frictional pressure drop and the hydraulic drag coefficient is determined from the experimental results. The factor is used to calculate the drag force analytically. It is found that with an increase in the mass flux, the drag force, and the drag coefficients are close to the results given by the homogeneous model. The result shows that the damping ratio can be calculated using the homogeneous model for bubbly flow of sufficiently large mass flux.

  18. Application of laser ablation inductivly coupled plasma mass spectrometry for characterization of U-7Mo/Al-55i dispersion fuels

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jeong Mook; Park, Jai Il; Youn, Young Sang; Ha, Yeong Keong; Kim, Jong Yun [Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)


    This technical note demonstrates the feasibility of using laser ablation inductively coupled plasma mass spectrometry for the characterization of U–7Mo/Al–5Si dispersion fuel. Our measurements show 5.0% Relative Standard Deviation (RSD) for the reproducibility of measured {sup 98}Mo/{sup 238}U ratios in fuel particles from spot analysis, and 3.4% RSD for {sup 98}Mo/{sup 238}U ratios in a NIST-SRM 612 glass standard. Line scanning allows for the distinction of U–7Mo fuel particles from the Al–5Si matrix. Each mass spectrum peak indicates the presence of U–7Mo fuel particles, and the time width of each peak corresponds to the size of that fuel particle. The size of the fuel particles is estimated from the time width of the mass spectrum peak for {sup 98}Mo by considering the scan rate used during the line scan. This preliminary application clearly demonstrates that laser ablation inductively coupled plasma mass spectrometry can directly identify isotope ratios and sizes of the fuel particles in U–Mo/Al dispersion fuel. Once optimized further, this instrument will be a powerful tool for investigating irradiated dispersion fuels in terms of fission product distributions in fuel matrices, and the changes in fuel particle size or shape after irradiation.

  19. Application of Laser Ablation Inductively Coupled Plasma Mass Spectrometry for Characterization of U-7Mo/Al-5Si Dispersion Fuels

    Directory of Open Access Journals (Sweden)

    Jeongmook Lee


    Full Text Available This technical note demonstrates the feasibility of using laser ablation inductively coupled plasma mass spectrometry for the characterization of U–7Mo/Al–5Si dispersion fuel. Our measurements show 5.0% Relative Standard Deviation (RSD for the reproducibility of measured 98Mo/238U ratios in fuel particles from spot analysis, and 3.4% RSD for 98Mo/238U ratios in a NIST-SRM 612 glass standard. Line scanning allows for the distinction of U–7Mo fuel particles from the Al–5Si matrix. Each mass spectrum peak indicates the presence of U–7Mo fuel particles, and the time width of each peak corresponds to the size of that fuel particle. The size of the fuel particles is estimated from the time width of the mass spectrum peak for 98Mo by considering the scan rate used during the line scan. This preliminary application clearly demonstrates that laser ablation inductively coupled plasma mass spectrometry can directly identify isotope ratios and sizes of the fuel particles in U–Mo/Al dispersion fuel. Once optimized further, this instrument will be a powerful tool for investigating irradiated dispersion fuels in terms of fission product distributions in fuel matrices, and the changes in fuel particle size or shape after irradiation.

  20. Dispersive suspended microextraction. (United States)

    Yang, Zhong-Hua; Liu, Yu; Lu, Yue-Le; Wu, Tong; Zhou, Zhi-Qiang; Liu, Dong-Hui


    A novel sample pre-treatment technique termed dispersive suspended microextraction (DSME) coupled with gas chromatography-flame photometric detection (GC-FPD) has been developed for the determination of eight organophosphorus pesticides (ethoprophos, malathion, chlorpyrifos, isocarbophos, methidathion, fenamiphos, profenofos, triazophos) in aqueous samples. In this method, both extraction and two phases' separation process were performed by the assistance of magnetic stirring. After separating the two phases, 1 μL of the suspended phase was injected into GC for further instrument analysis. Varieties of experiment factors which could affect the experiment results were optimized and the following were selected: 12.0 μL p-xylene was selected as extraction solvent, extraction speed was 1200 rpm, extraction time was 30 s, the restoration speed was 800 rpm, the restoration time was 8 min, and no salt was added. Under the optimum conditions, limits of detections (LODs) varied between 0.01 and 0.05 μg L(-1). The relative standard deviation (RSDs, n=6) ranged from 4.6% to 12.1%. The linearity was obtained by five points in the concentration range of 0.1-100.0 μg L(-1). Correlation coefficients (r) varied from 0.9964 to 0.9995. The enrichment factors (EFs) were between 206 and 243. In the final experiment, the developed method has been successfully applied to the determination of organophosphorus pesticides in wine and tap water samples and the obtained recoveries were between 83.8% and 101.3%. Compared with other pre-treatment methods, DSME has its own features and could achieve satisfied results for the analysis of trace components in complicated matrices. Copyright © 2011 Elsevier B.V. All rights reserved.

  1. Determination of aminophenols and phenol in hair colorants by ultrasound-assisted solid-phase dispersion extraction coupled with ion chromatography. (United States)

    Zhong, Zhixiong; Li, Gongke; Wu, Rong; Zhu, Binghui; Luo, Zhibin


    A simple and reliable ultrasound-assisted solid-phase dispersion extraction coupled with ion chromatography was developed for the determination of aminophenols and phenol. The highly viscous hair colorant was dispersed in solvents using anhydrous sodium sulfite having dual functions of dispersant and antioxidant. The use of anhydrous sodium sulfite did not change the sample volume because it could completely dissolve in solution after matrix dispersion. The extraction and cleanup were combined in one single step for simplifying operation. The extraction process could be rapidly accomplished within 9 min with high sample throughput under the synergistic effects of vibration, ultrasound, and heating. Satisfactory linearity was observed with correlation coefficients higher than 0.9992, and the limits of detection varied from 0.02 to 0.09 mg/L. The applicability of the proposed method was demonstrated by measuring the concentrations of aminophenols and phenol in 32 different commercial hair color products. The recoveries ranged from 86.4-101.2% with the relative standard deviations in the range of 0.52-4.3%. The method offers an attractive alternative for the analysis of trace phenols in complex matrices. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Micro-matrix solid-phase dispersion coupled with MEEKC for quantitative analysis of lignans in Schisandrae Chinensis Fructus using molecular sieve TS-1 as a sorbent. (United States)

    Chu, Chu; Wei, Mengmeng; Wang, Shan; Zheng, Liqiong; He, Zheng; Cao, Jun; Yan, Jizhong


    A simple and effective method was developed for determining lignans in Schisandrae Chinensis Fructus by using a micro-matrix solid phase dispersion (MSPD) technique coupled with microemulsion electrokinetic chromatography (MEEKC). Molecular sieve, TS-1, was applied as a solid supporting material in micro MSPD extraction for the first time. Parameters that affect extraction efficiency, such as type of dispersant, mass ratio of the sample to the dispersant, grinding time, elution solvent and volume were optimized. The optimal extraction conditions involve dispersing 25mg of powdered Schisandrae samples with 50mg of TS-1 by a mortar and pestle. A grinding time of 150s was adopted. The blend was then transferred to a solid-phase extraction cartridge and the target analytes were eluted with 500μL of methanol. Moreover, several parameters affecting MEEKC separation were studied, including the type of oil, SDS concentration, type and concentration of cosurfactant, and concentration of organic modifier. A satisfactory linearity (R>0.9998) was obtained, and the calculated limits of quantitation were less than 2.77μg/mL. Finally, the micro MSPD-MEEKC method was successfully applied to the analysis of lignans in complex Schisandrae fructus samples. Copyright © 2017 Elsevier B.V. All rights reserved.

  3. experimental validation of a dual loop control of two phases

    African Journals Online (AJOL)

    Kraa O, Ghodbane H, Saadi R, Ayad M.Y, Becherif M, Bahri M and Aboubou A


    May 1, 2016 ... boost topology used usually for FC applications [11] and IBC two phases converter. 3. MODELING OF THE FC AND IBC SYSTEM. The studied system here is considered as a power train system for electric vehicle application. (Fuel cell vehicle). It constituted by a FC (energy source) connected with a load ...

  4. Controlling two-phase flow in microfluidic systems using electrowetting

    NARCIS (Netherlands)

    Gu, H.


    Electrowetting (EW)-based digital microfluidic systems (DMF) and droplet-based two-phase flow microfluidic systems (TPF) with closed channels are the most widely used microfluidic platforms. In general, these two approaches have been considered independently. However, integrating the two

  5. A form of two-phase sampling utilizing regression analysis (United States)

    Michael A. Fiery; John R. Brooks


    A two-phase sampling technique was introduced and tested on several horizontal point sampling inventories of hardwood tracts located in northern West Virginia and western Maryland. In this sampling procedure species and dbh are recorded for all “in-trees” on all sample points. Sawlog merchantable height was recorded on a subsample of intensively measured (second phase...

  6. Modelling two-phase transport of 3H/3He

    NARCIS (Netherlands)

    Visser, A.; Schaap, J.D.; Leijnse, T.; Broers, H.P.; Bierkens, M.F.P.


    Degassing of groundwater by excess denitrification of agricultural pollution complicates the interpretation of 3H/3He data and hinders the estimation of travel times in nitrate pollution studies. In this study we used a two-phase flow and transport model (STOMP) to evaluate the method presented by

  7. Electrophoretic Partitioning of Proteins in Two-Phase Microflows

    DEFF Research Database (Denmark)

    Münchow, G.; Hardt, S.; Kutter, Jörg Peter


    This work reports on protein transport phenomena discovered in partitioning experiments with a novel setup for continuous-flow two-phase electrophoresis consisting of a microchannel in which a phase boundary is formed in flow direction. Proteins can be partitioned exploiting their affinity to dif...

  8. Tunable two-phase coexistence in half-doped manganites

    Indian Academy of Sciences (India)

    Abstract. We discuss our very interesting experimental observation that the low- temperature two-phase coexistence in half-doped manganites is multi-valued (at any field) in that we can tune the coexisting antiferromagnetic-insulating (AF-I) and the ferromagnetic-metallic (FM-M) phase fractions by following different paths in ...

  9. Tunable two-phase coexistence in half-doped manganites

    Indian Academy of Sciences (India)

    temperature two-phase coexistence in half-doped manganites is multi-valued (at any field) in that we can tune the coexisting antiferromagnetic-insulating (AF-I) and the ferromagnetic-metallic (FM-M) phase fractions by following different paths in (; ...

  10. Rubisco separation using biocompatible aqueous two-phase systems

    NARCIS (Netherlands)

    Suarez Ruiz, C.A.; Berg, van den C.; Wijffels, R.H.; Eppink, M.H.M.


    Mild and efficient separation processes have to be developed to convert microalgal biomass into high valuable products. Aqueous two-phase system (ATPS) was adopted as a new approach in microalgae to separate hydrophilic from hydrophobic components. In this work, three biocompatible ATPSs


    African Journals Online (AJOL)

    Ifeanyichukwu Onwuka

    transients, up to ten parallel flow paths, simple and complicated geometries, including the boilers of fossil steam generators and nuclear power plants. A test calculation has been made with a simplified three- channel system subjected to a two-phase flow transient, and the results have been very encouraging. NOTATION.

  12. Two Phase Flow Split Model for Parallel Channels | Iloeje | Nigerian ...

    African Journals Online (AJOL)

    The model and code are capable of handling single and two phase flows, steady states and transients, up to ten parallel flow paths, simple and complicated geometries, including the boilers of fossil steam generators and nuclear power plants. A test calculation has been made with a simplified three-channel system ...


    Directory of Open Access Journals (Sweden)

    Sit B.M.


    Full Text Available It is presented the calculus of the two-phase ejector for carbon dioxide heat pump. The method of calculus is based on the method elaborated by S.M. Kandil, W.E. Lear, S.A. Sherif, and is modified taking into account entrainment ratio as the input for the calculus.

  14. Numerical simulation of two-phase flow in offshore environments

    NARCIS (Netherlands)

    Wemmenhove, Rik


    Numerical Simulation of Two-Phase Flow in Offshore Environments Rik Wemmenhove Weather conditions on full sea are often violent, leading to breaking waves and lots of spray and air bubbles. As high and steep waves may lead to severe damage on ships and offshore structures, there is a great need for

  15. Detection and characterization of elongated bubbles and drops in two-phase flow using magnetic fields (United States)

    Wiederhold, A.; Boeck, T.; Resagk, C.


    We report a method to detect and to measure the size and velocity of elongated bubbles or drops in a dispersed two-phase flow. The difference of the magnetic susceptibilities between two phases causes a force on the interface between both phases when it is exposed to an external magnetic field. The force is measured with a state-of-the-art electromagnetic compensation balance. While the front and the back of the bubble pass the magnetic field, two peaks in the force signal appear, which can be used to calculate the velocity and geometry parameters of the bubble. We achieve a substantial advantage over other bubble detection techniques because this technique is contactless, non-invasive, independent of the electrical conductivity and can be applied to opaque or aggressive fluids. The measurements are performed in an inclined channel with air bubbles and paraffin oil drops in water. The bubble length is in the range of 0.1-0.25 m and the bubble velocity lies between 0.02-0.22 m s-1. Furthermore we show that it is possible to apply this measurement principle for nondestructive testing (NDT) of diamagnetic and paramagnetic materials like metal, plastics or glass, provided that defects are in the range of 10‒2 m. This technique opens up new possibilities in industrial applications to measure two-phase flow parameters and in material testing.

  16. A theory of electrophoresis of emulsion drops in aqueous two-phase polymer systems (United States)

    Levine, S.


    An electrophoresis study has been carried out in an emulsion formed from an electrically neutral aqueous mixture of dextran and polyethylene glycol equilibrated at sufficient concentrations in the presence of electrolytes. Electrophoresis of a drop of one phase suspended in the other is observed, and the direction of the drop's motion is reversed when the disperse phase and the continuous phase are interchanged. In the presence of sulfate, phosphate, or citrate ions, an electrostatic potential difference of the order of a few mV exists between the two phases. The potential implied by the direction of the electrophoretic motion is opposite to the Donnan potential observed between the two phases. The mobility of an emulsion drop increases with the drop radius and depends on ion concentration. These results are explained in terms of a model postulating an electric dipole layer associated with a mixture of oriented polymer molecules at the surface of a drop, with a potential difference between the interiors of the two phases resulting from the unequal ion distribution.

  17. Thermal and dynamical regimes of single- and two-phase magmatic flow in dikes (United States)

    Carrigan, Charles R.; Schubert, Gerald; Eichelberger, John C.


    The coupling between thermal and dynamical regimes of single- and two-phase magmatic flow in dikes, due to temperature-dependent viscosity and dissipation, was investigated using finite element calculations of magma flow in dikelike channels with length-to-width ratios of 1000:1 or more. Solutions of the steady state equations governing magma flow are obtained for a variety of conditions ranging from idealized plane-parallel models to cases involving nonparallel geometry and two-phase flows. The implications of the numerical simulations for the dynamics of flow in a dike-reservoir system and the consequences of dike entrance conditions on magmatic storage are discussed. Consideration is also given to an unmixing/self-lubrication mechanism which may be important for the lubrication of silicic magmas rising to the earth's surface in mixed magma ascent scenarios, which naturally segregates magma mixtures of two components with differing viscosities to minimize the driving pressure gradient.

  18. Dispersion of the intrinsic neuronal periods affects the relationship of the entrainment range to the coupling strength in the suprachiasmatic nucleus (United States)

    Gu, Changgui; Yang, Huijie; Wang, Man


    Living beings on the Earth are subjected to and entrained (synchronized) to the natural 24-h light-dark cycle. Interestingly, they can also be entrained to an external artificial cycle of non-24-h periods. The range of these periods is called the entrainment range and it differs among species. In mammals, the entrainment range is regulated by a main clock located in the suprachiasmatic nucleus (SCN) which is composed of 10 000 neurons in the brain. Previous works have found that the entrainment range depends on the cellular coupling strength in the SCN. In particular, the entrainment range decreases with the increase of the cellular coupling strength, provided that all the neuronal oscillators are identical. However, the SCN neurons differ in the intrinsic periods that follow a normal distribution in a range from 22 to 28 h. In the present study, taking the dispersion of the intrinsic neuronal periods into account, we examined the relationship between the entrainment range and the coupling strength. Results from numerical simulations and theoretical analyses both show that the relationship is altered to be paraboliclike if the intrinsic neuronal periods are nonidentical, and the maximal entrainment range is obtained with a suitable coupling strength. Our results shed light on the role of the cellular coupling in the entrainment ability of the SCN network.

  19. Numerical Investigation of Two-Phase Flows With Charged Droplets in Electrostatic Field (United States)

    Kim, Sang-Wook


    A numerical method to solve two-phase turbulent flows with charged droplets in an electrostatic field is presented. The ensemble-averaged Navier-Stokes equations and the electrostatic potential equation are solved using a finite volume method. The transitional turbulence field is described using multiple-time-scale turbulence equations. The equations of motion of droplets are solved using a Lagrangian particle tracking scheme, and the inter-phase momentum exchange is described by the Particle-In-Cell scheme. The electrostatic force caused by an applied electrical potential is calculated using the electrostatic field obtained by solving a Laplacian equation and the force exerted by charged droplets is calculated using the Coulombic force equation. The method is applied to solve electro-hydrodynamic sprays. The calculated droplet velocity distributions for droplet dispersions occurring in a stagnant surrounding are in good agreement with the measured data. For droplet dispersions occurring in a two-phase flow, the droplet trajectories are influenced by aerodynamic forces, the Coulombic force, and the applied electrostatic potential field.

  20. Instrumentation development for multi-dimensional two-phase flow modeling

    Energy Technology Data Exchange (ETDEWEB)

    Kirouac, G.J.; Trabold, T.A.; Vassallo, P.F.; Moore, W.E.; Kumar, R. [Lockheed Martin Corp., Schenectady, NY (United States)


    A multi-faceted instrumentation approach is described which has played a significant role in obtaining fundamental data for two-phase flow model development. This experimental work supports the development of a three-dimensional, two-fluid, four field computational analysis capability. The goal of this development is to utilize mechanistic models and fundamental understanding rather than rely on empirical correlations to describe the interactions in two-phase flows. The four fields (two dispersed and two continuous) provide a means for predicting the flow topology and the local variables over the full range of flow regimes. The fidelity of the model development can be verified by comparisons of the three-dimensional predictions with local measurements of the flow variables. Both invasive and non-invasive instrumentation techniques and their strengths and limitations are discussed. A critical aspect of this instrumentation development has been the use of a low pressure/temperature modeling fluid (R-134a) in a vertical duct which permits full optical access to visualize the flow fields in all two-phase flow regimes. The modeling fluid accurately simulates boiling steam-water systems. Particular attention is focused on the use of a gamma densitometer to obtain line-averaged and cross-sectional averaged void fractions. Hot-film anemometer probes provide data on local void fraction, interfacial frequency, bubble and droplet size, as well as information on the behavior of the liquid-vapor interface in annular flows. A laser Doppler velocimeter is used to measure the velocity of liquid-vapor interfaces in bubbly, slug and annular flows. Flow visualization techniques are also used to obtain a qualitative understanding of the two-phase flow structure, and to obtain supporting quantitative data on bubble size. Examples of data obtained with these various measurement methods are shown.

  1. Dispersed Two-Phase Flow Modelling for Nuclear Safety in the NEPTUNE_CFD Code


    Mimouni, Stephane; Benguigui, William; Fleau, Solène; Foissac, Arnaud; Guingo , Mathieu; Hassanaly, Mickael; Lavieville, Jérôme; Malet, Jeanne; Méchitoua, Namane; Mérigoux, Nicolas; Vincent, Stéphane


    The objective of this paper is to give an overview of the capabilities of Eulerian bifluid approach to meet the needs of studies for nuclear safety regarding hydrogen risk, boiling crisis, and pipes and valves maintenance. The Eulerian bifluid approach has been implemented in a CFD code named NEPTUNE_CFD. NEPTUNE_CFD is a three-dimensional multifluid code developed especially for nuclear reactor applications by EDF, CEA, AREVA, and IRSN. The first set of models is dedicated to wall vapor cond...

  2. Computational fluid dynamics study on two-phase CO2 dispersion in a neutral atmosphere

    NARCIS (Netherlands)

    Trijssenaar, I.J.M.; Spruijt, M.P.N.; Hulsbosch, C.E.C.


    Abstract: A large release of Carbon Dioxide (CO2) is modelled with Computational Fluid Dynamics (CFD), (Fluent v12.1). Special attention is given to the modelling of a neutral atmospheric boundary layer (ABL) with gravity. Both the presence of non-vapour CO2 and the high density of CO2 require that

  3. Dispersed Two-Phase Flow Modelling for Nuclear Safety in the NEPTUNE_CFD Code

    Directory of Open Access Journals (Sweden)

    Stephane Mimouni


    Full Text Available The objective of this paper is to give an overview of the capabilities of Eulerian bifluid approach to meet the needs of studies for nuclear safety regarding hydrogen risk, boiling crisis, and pipes and valves maintenance. The Eulerian bifluid approach has been implemented in a CFD code named NEPTUNE_CFD. NEPTUNE_CFD is a three-dimensional multifluid code developed especially for nuclear reactor applications by EDF, CEA, AREVA, and IRSN. The first set of models is dedicated to wall vapor condensation and spray modelling. Moreover, boiling crisis remains a major limiting phenomenon for the analysis of operation and safety of both nuclear reactors and conventional thermal power systems. The paper aims at presenting the generalization of the previous DNB model and its validation against 1500 validation cases. The modelling and the numerical simulation of cavitation phenomena are of relevant interest in many industrial applications, especially regarding pipes and valves maintenance where cavitating flows are responsible for harmful acoustics effects. In the last section, models are validated against experimental data of pressure profiles and void fraction visualisations obtained downstream of an orifice with the EPOCA facility (EDF R&D. Finally, a multifield approach is presented as an efficient tool to run all models together.

  4. Water transport in two-phase fuel cell microchannels (United States)

    Lee, Eon Soo

    Many fuel cells contain small rectangular channels in which three of the channel walls are smooth, impermeable metal and the fourth wall is a porous gas-diffusion layer. The main function of the channels is to supply reactant gases through the porous layer to the reaction surface, but also to remove water formed by the electro-chemical reactions. Analysis of the two-phase flow through these channels is complicated by the fact that both gas and liquid can move through either the channel or the porous layer. This study presents the flow regime maps for the two-phase flow and a 1-D two-phase flow model for the frictional characteristics of the porous wall bounded channel flow. Experiments were performed on a straight 200 by 500 micron by 150 mm long rectangular channel. Three walls of the channel were machined into a solid piece of acrylic. One of the 500 micron wide walls was a commercial Toray carbon paper gas-diffusion layer (GDL) material held in place by a flat sheet of acrylic. Water was forced through the GDL layer from four evenly spaced holes in the flat acrylic piece. Two-phase flow regime maps were constructed from flow visualization in terms of a superficial gas velocity, JG and the superficial liquid velocity, JL at the channel exit between 0 < JG < 20 m/s and 0 < JL < 10 mm/s. Flow regimes were observed to change from plug flow to stratified flow through an intermediate flow regime as superficial gas velocities increased. The transition from plug flow generally occurs at a constant superficial gas velocity and a two-phase Weber number is proposed as an appropriate dimensionless parameter to characterize this transition. A one-dimensional, two-phase flow model was developed which included the effect of air and water flows in both the channel and GDL. The analysis from experimental measurements showed that the product of the friction factor and the gas flow Reynolds number was very nearly a constant, indicating that the model captures the critical physical

  5. Up scaling two-phase flow in heterogeneous porous media; Mise a l'echelle des ecoulements diphasiques dans les milieux poreux heterogenes

    Energy Technology Data Exchange (ETDEWEB)

    Artus, V.


    For two-phase flow in heterogeneous media, the emergence of different flow regimes at large-scale is driven by local interactions between the viscous coupling and the heterogeneity. In particular, when the viscosity ratio is favorable, viscous effects induce a transverse flow that stabilizes the front while flooding. However, most of recent stochastic models neglect the influence of the viscous coupling. We developed a stochastic model for the dynamics of the front, taking the viscous coupling into account. For stable cases, this model relates the statistical properties of the front to the statistical properties of the permeability field. For stable flow in stratified media, we show that the front is stationary by parts in the reservoir. These parts can be identified as large-scale hydrodynamic layers and separately coarsened in the large-scale simulation model. For flows with favorable viscosity ratios in isotropic reservoirs, we show that a stationary front occurs, in a statistical sense. For unfavorable viscosity ratios, the flow is driven by the development of viscous fingering. These different regimes lead to different large-scale saturation profiles that can be matched with a macro-dispersion equation, if the effective convective flux is modified to take into account stabilizing or destabilizing viscous effects. (author)

  6. Two-phase computer codes for zero-gravity applications

    Energy Technology Data Exchange (ETDEWEB)

    Krotiuk, W.J.


    This paper discusses the problems existing in the development of computer codes which can analyze the thermal-hydraulic behavior of two-phase fluids especially in low gravity nuclear reactors. The important phenomenon affecting fluid flow and heat transfer in reduced gravity is discussed. The applicability of using existing computer codes for space applications is assessed. Recommendations regarding the use of existing earth based fluid flow and heat transfer correlations are made and deficiencies in these correlations are identified.

  7. Two phase flow instabilities in horizontal straight tube evaporator



    Abstract It is essential to ensure the stability of a refrigeration system if the oscillation in evaporation process is the primary cause for the whole system instability. This paper is concerned with an experimental investigation of two phase flow instabilities in a horizontal straight tube evaporator of a refrigeration system. The relationship between pressure drop and mass flow with constant heat flux and evaporation pressure is measured and determined. It is found that there is...

  8. Comparison of Predictions of Three Two-Phase Flow Codes (United States)


    Q for Q in Equation (1) yields an estimate L Llg T, -T = 3.30K . b o That the two estimates are close to each other is satisfying enough to...two-phase interior ballistics of solid propellant guns. The debate on the correct- ness of the governing equations should seek the practical effects...published. Of note are the diffusion terms in the momentum and energy equations , the use of a solid phase energy equation , the bulk temperature ignition

  9. Computational methods for two-phase flow and particle transport

    CERN Document Server

    Lee, Wen Ho


    This book describes mathematical formulations and computational methods for solving two-phase flow problems with a computer code that calculates thermal hydraulic problems related to light water and fast breeder reactors. The physical model also handles the particle and gas flow problems that arise from coal gasification and fluidized beds. The second part of this book deals with the computational methods for particle transport.

  10. Testing and modeling of a two-phase ejector


    Harrell, Greg S.


    The ejector expansion refrigeration cycle is a modified vapor compression cycle in which a two phase ejector is used to recover a portion of the work otherwise lost in the expansion valve. The ejector improves cycle performance by increasing compressor inlet pressure and by lowering the quality of the fluid entering the evaporator. Theoretically, a cooling COP improvement of approximately 21 % is achievable for a typical refrigerating cycle and an ideal ejector. If the ejector ...

  11. Recent advances in two-phase flow numerics

    Energy Technology Data Exchange (ETDEWEB)

    Mahaffy, J.H.; Macian, R. [Pennsylvania State Univ., University Park, PA (United States)


    The authors review three topics in the broad field of numerical methods that may be of interest to individuals modeling two-phase flow in nuclear power plants. The first topic is iterative solution of linear equations created during the solution of finite volume equations. The second is numerical tracking of macroscopic liquid interfaces. The final area surveyed is the use of higher spatial difference techniques.

  12. Simulation of the depletion of two-phase geothermal reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Pruess, K.; Bodvarsson, G.; Schroeder, R.C.; Witherspoon, P.A.; Marconcini, R.; Neri, G.; Ruffilli, C.


    The simulator SHAFT79 has been used to study the depletion of different types of geothermal reservoirs. Investigations of idealized systems include effects of gravity and fluid injection. Pressure decline is analyzed as a function of cumulative production. The main conclusions are as follows: (1) the well-known p/Z-method for estimating fluid reserves is not applicable to two-phase geothermal reservoirs; (2) there is a strong tendency towards spatially uniform boiling. This causes a pressure decline which allows in many cases estimates of the total reservoir volume and of the total heat content of the reservoir rock; (3) propagation of a boiling front through a deep water table, as a consequence of fluid production, gives rise to a peculiar pattern of pressure decline. This may allow prediction of the distance of the water table from the producing wells and of the vertical thickness of the water zone, thereby giving important clues to estimating fluid reserves; (4) the pressure effects of injection of colder fluid depend strongly on (one- or two-) phase conditions in the reservoir, upon injection rate, and upon absolute permeability. Average pressure may actually decline in two-phase reservoirs rather than increase due to injection. Preliminary results of a case-history investigation of the Serrazzano zone at Larderello, Italy, are presented. SHAFT79 has been used for a fully three-dimensional simulation of a geologically accurate model of the Serrazzano reservoir. Comparison of computed results with field data allows improved estimates of reservoir conditions and parameters.

  13. Characterization of horizontal air–water two-phase flow

    Energy Technology Data Exchange (ETDEWEB)

    Kong, Ran; Kim, Seungjin, E-mail:


    Highlights: • A visualization study is performed to develop flow regime map in horizontal flow. • Database in horizontal bubbly flow is extended using a local conductivity probe. • Frictional pressure drop analysis is performed in horizontal bubbly flow. • Drift flux analysis is performed in horizontal bubbly flow. - Abstract: This paper presents experimental studies performed to characterize horizontal air–water two-phase flow in a round pipe with an inner diameter of 3.81 cm. A detailed flow visualization study is performed using a high-speed video camera in a wide range of two-phase flow conditions to verify previous flow regime maps. Two-phase flows are classified into bubbly, plug, slug, stratified, stratified-wavy, and annular flow regimes. While the transition boundaries identified in the present study compare well with the existing ones (Mandhane et al., 1974) in general, some discrepancies are observed for bubbly-to-plug/slug, and plug-to-slug transition boundaries. Based on the new transition boundaries, three additional test conditions are determined in horizontal bubbly flow to extend the database by Talley et al. (2015a). Various local two-phase flow parameters including void fraction, interfacial area concentration, bubble velocity, and bubble Sauter mean diameter are obtained. The effects of increasing gas flow rate on void fraction, bubble Sauter mean diameter, and bubble velocity are discussed. Bubbles begin to coalesce near the gas–liquid layer instead of in the highly packed region when gas flow rate increases. Using all the current experimental data, two-phase frictional pressure loss analysis is performed using the Lockhart–Martinelli method. It is found that the coefficient C = 24 yields the best agreement with the data with the minimum average difference. Moreover, drift flux analysis is performed to predict void-weighted area-averaged bubble velocity and area-averaged void fraction. Based on the current database, functional

  14. Simultaneous Pre-Concentration of Cadmium and Lead in Environmental Water Samples with Dispersive Liquid-Liquid Microextraction and Determination by Inductively Coupled Plasma-Atomic Emission Spectrometry

    Directory of Open Access Journals (Sweden)

    M. Salahinejad


    Full Text Available The dispersive liquid–liquid microextraction (DLLME method for determination of Pb+2 and Cd+2 ions in the environmental water samples was combined with inductively coupled plasma-atomic emission spectrometry (ICP-AES. Ammonium pyrrolidine dithiocarbamate (APDC, chloroform and ethanol were used as chelating agent, extraction solvent and disperser solvent, respectively. Some effective parameters on the microextraction and the complex formation were selected and optimized. These parameters included extraction and disperser solvent type as well as their volume, extraction time, salt effect, pH, sample volume and amount of the chelating agent.   Under the optimum conditions, the enrichment factor of 75 and 105 for Cd+2 and Pb+2 ions respectively was obtained from only 5.00mL of water sample. The detection limit (S/N=3 was 12 and 0.8ngmL−1 for Pb and Cd respectively. The relative standard deviation (RSDs for five replicate measurements of 0.50 mgL−1 of lead and cadmium was 6.5 and 4.4 % respectively. Mineral, tap, river, sea, dam and spiked water samples were analyzed for Cd and Pb amount.

  15. A Mass Conservative Numerical Solution for Two-Phase Flow in Porous Media With Application to Unsaturated Flow

    DEFF Research Database (Denmark)

    Celia, Michael A.; Binning, Philip John


    A numerical algorithm for simulation of two-phase flow in porous media is presented. The algorithm is based on a modified Picard linearization of the governing equations of flow, coupled with a lumped finite element approximation in space and dynamic time step control. Numerical results indicate...... that the algorithm produces solutions that are essentially mass conservative and oscillation free, even in the presence of steep infiltrating fronts. When the algorithm is applied to the case of air and water flow in unsaturated soils, numerical results confirm the conditions under which Richards's equation is valid...... that describe two-phase flow in porous media....

  16. Simulating Flow and Dispersion by Using WRF-CFD Coupled Model in a Built-Up Area of Shenyang, China

    Directory of Open Access Journals (Sweden)

    Yijia Zheng


    Full Text Available Results are presented from a series of numerical studies designed to investigate the atmospheric boundary layer structure, ambient wind, and pollutant source location and their impacts on the wind field and pollutant distribution within the built-up areas of Shenyang, China. Two models, namely, Open Source Field Operation and Manipulation (OpenFOAM software package and Weather Research and Forecasting (WRF model, are used in the present study. Then the high resolution computational fluid dynamics (CFD numerical experiments were performed under the typical simulated atmospheric boundary conditions. It was found that the atmospheric boundary structure played a crucial role in the pollution within the building cluster, which determined the potential turbulent diffusion ability of the atmospheric surface layer; the change of the ambient wind direction can significantly affect the dispersion pattern of pollutants, which was a more sensitive factor than the ambient wind speed; under a given atmospheric state, the location of the pollution sources would dramatically determine the pollution patterns within built-up areas. The WRF-CFD numerical evaluation is a reliable method to understand the complicated flow and dispersion within built-up areas.

  17. Performance testing of a two-phase interface heat exchanger (United States)

    Mccabe, M. E., Jr.; Swanson, T. D.


    This paper describes the design and performance testing of a heat exchanger which interfaces separate two-phase ammonia thermal loops. The basic design involves a tube-in-tube concept, with boiling occurring in the inner tube and condensation in the outer tube. Eight such tubes are arranged in parallel. Testing has demonstrated that up to 8.2 kW of heat may be transferred across the heat exchanger when the saturation temperature difference between the systems is 5 C. Performance of the heat exchanger is affected primarily by the mass flow rate of ammonia in the liquid supply loop.

  18. Experimental and numerical investigation on two-phase flow instabilities

    Energy Technology Data Exchange (ETDEWEB)

    Ruspini, Leonardo Carlos


    Two-phase flow instabilities are experimentally and numerically studied within this thesis. In particular, the phenomena called Ledinegg instability, density wave oscillations and pressure drop oscillations are investigated. The most important investigations regarding the occurrence of two-phase flow instabilities are reviewed. An extensive description of the main contributions in the experimental and analytical research is presented. In addition, a critical discussion and recommendations for future investigations are presented. A numerical framework using a hp-adaptive method is developed in order to solve the conservation equations modelling general thermo-hydraulic systems. A natural convection problem is analysed numerically in order to test the numerical solver. Moreover, the description of an adaptive strategy to solve thermo-hydraulic problems is presented. In the second part of this dissertation, a homogeneous model is used to study Ledinegg, density wave and pressure drop oscillations phenomena numerically. The dynamic characteristics of the Ledinegg (flow excursion) phenomenon are analysed through the simulation of several transient examples. In addition, density wave instabilities in boiling and condensing systems are investigated. The effects of several parameters, such as the fluid inertia and compressibility volumes, on the stability limits of Ledinegg and density wave instabilities are studied, showing a strong influence of these parameters. Moreover, the phenomenon called pressure drop oscillations is numerically investigated. A discussion of the physical representation of several models is presented with reference to the obtained numerical results. Finally, the influence of different parameters on these phenomena is analysed. In the last part, an experimental investigation of these phenomena is presented. The designing methodology used for the construction of the experimental facility is described. Several simulations and a non

  19. Two-phase materials for high-temperature service

    CSIR Research Space (South Africa)

    Nabarro, FRN


    Full Text Available viewed on the scale of the precipitate particles The structure consists of cubes of the g0 phase, an ordered L12 structure based on Ni3Al, stacked in a simple cubic array in a matrix of g, a disordered face- centred cubic lattice, also nickel-based. The g... phases show lattice coherence after standard heat treatments. 2.2. Current superalloys viewed on the atomic scale The great strength of the two-phase structure is com- parison with either of its components is explained as follows. In both phases, glide...

  20. Two-Phase Flow Regime Identification by Ultrasonic Computerized Tomography

    Directory of Open Access Journals (Sweden)



    Full Text Available This paper describes the development of ultrasonic computerized tomography for identifying the liquid and gas flow regimes. The work reported in this paper demonstrates image reconstruction techniques applied to an experimental vessel using non-invasive technique. The investigations were based on the transmission and the reception of ultrasonic sensors that were mounted circularly on the surface of an experimental vessel. The algorithms used to reconstruct the concentration profile for two-phase flow using fan-shaped beam scanning geometry were also presented.

  1. Role of Nucleation and Growth in Two-Phase Microstructure Formation

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Jong Ho [Iowa State Univ., Ames, IA (United States)


    oscillatory microstructures that depend on the imposed velocity and the size of the sample. At low thermal gradient to velocity ratio, a steady-state composite microstructure is observed. Two mechanisms of composite microstructure formation were examined: (1) the formation of the peritectic phase in the intercellular region of the primary phase where the solute rejected by the primary phase is absorbed by the peritectic phase. The peritectic phase forms a small distance behind the growing primary phase front. (2) The second mechanism is the coupled growth of the two phases with a macroscopically planar interface, as in the case of eutectic growth. Detailed studies showed that this composite microstructure, although it appears as a eutectic microstructure, did not grow in the coupled manner at the advancing interface in the Sn-cd system. However, a new observation was made when experiments were carried out in thin ampoule of Ta. The peritectic phase nucleated at the wall-interface triple junction and grew along the wall, while the primary phase continued to grow at the center, giving rise to a steady-state couple growth at some specific velocity. The mechanism of coupled growth in this case was shown to be operative due to the presence of a finite contact angle at the wall, and this was demonstrated by including the contact angle effect at the wall in the rod eutectic growth model. The experimental results were summarized to map out the conditions of thermal gradient and velocity on the regimes of composite and oscillatory microstructure formation. The formation of complex time-dependent microstructures was then discussed in terms of the time-dependent dynamics of planar interface growth.

  2. Hydrodynamic dispersion within porous biofilms

    KAUST Repository

    Davit, Y.


    Many microorganisms live within surface-associated consortia, termed biofilms, that can form intricate porous structures interspersed with a network of fluid channels. In such systems, transport phenomena, including flow and advection, regulate various aspects of cell behavior by controlling nutrient supply, evacuation of waste products, and permeation of antimicrobial agents. This study presents multiscale analysis of solute transport in these porous biofilms. We start our analysis with a channel-scale description of mass transport and use the method of volume averaging to derive a set of homogenized equations at the biofilm-scale in the case where the width of the channels is significantly smaller than the thickness of the biofilm. We show that solute transport may be described via two coupled partial differential equations or telegrapher\\'s equations for the averaged concentrations. These models are particularly relevant for chemicals, such as some antimicrobial agents, that penetrate cell clusters very slowly. In most cases, especially for nutrients, solute penetration is faster, and transport can be described via an advection-dispersion equation. In this simpler case, the effective diffusion is characterized by a second-order tensor whose components depend on (1) the topology of the channels\\' network; (2) the solute\\'s diffusion coefficients in the fluid and the cell clusters; (3) hydrodynamic dispersion effects; and (4) an additional dispersion term intrinsic to the two-phase configuration. Although solute transport in biofilms is commonly thought to be diffusion dominated, this analysis shows that hydrodynamic dispersion effects may significantly contribute to transport. © 2013 American Physical Society.

  3. A component architecture for the two-phase flows simulation system Neptune

    Energy Technology Data Exchange (ETDEWEB)

    Bechaud, C.; Boucker, M.; Douce, A. [Electricite de France (EDF-RD/MFTT), 78 - Chatou (France); Grandotto, M. [CEA Cadarache (DEN/DTP/STH), 13 - Saint-Paul-lez-Durance (France); Tajchman, M. [CEA Saclay (DEN/DM2S/SFME), 91 - Gif-sur-Yvette (France)


    Electricite de France (EdF) and the French atomic energy commission (Cea) have planed a large project to build a new set of software in nuclear reactors analysis. One of the main idea is to allow coupled calculations in which several scientific domains are involved. This paper presents the software architecture of the two-phase flows simulation Neptune project. Neptune should allow computations of two-phase flows in 3 dimensions under normal operating conditions as well as safety conditions. Three scales are identified: the local scale where there is only homogenization between the two phases, an intermediate scale where solid internal structures are homogenized with the fluid and the system scale where some parts of the geometry under study are considered point-wise or subject to one dimensional simplifications. The main properties of this architecture are as follow: -) coupling with scientific domains, and between different scales, -) re-using of quite all or parts of existing validated codes, -) components usable by the different scales, -) easy introducing of new physical modeling as well as new numerical methods, -) local, distributed and parallel computing. The Neptune architecture is based on the component concept with stable and well suited interface. In the case of a distributed application the components are managed through a Corba bus. The building of the components is organized in shell: a programming shell (Fortran or C++ routines), a managing shell (C++ language), an interpreted shell (Python language), a Corba shell and a global driving shell (C++ or Python). Neptune will use the facilities offered by the Salome project: pre and post processors and controls. A data model has been built to have a common access to the information exchanged between the components (meshes, fields, physical and technical information). This architecture has first been setup and tested on some simple but significant cases and is now currently in use to build the Neptune

  4. Cell-laden microgel prepared using a biocompatible aqueous two-phase strategy. (United States)

    Liu, Yang; Nambu, Natalia Oshima; Taya, Masahito


    Microfluidic methods are frequently used to produce cell-laden microgels for various biomedical purposes. Such microfluidic methods generally employ oil-water systems. The poor distribution of crosslinking reagents in the oil phase limits the available gelation strategies. Extracting the microgel from the oil-phase also reduces its production efficiency. In this study, an aqueous two-phase system (ATPS) involving dextran (DEX) and polyethylene glycol (PEG) was used to prepare cell-laden microgel. This avoided the problems associated with an oil phase. The microgel precursor polymers and crosslinking reagents were dispersed in the DEX and PEG phases, respectively. The ultra-low interfacial tension of the ATPS hindered droplet formation. A co-flow microfluidic device was fabricated to overcome this problem. The device incorporated a square-wave-changing injection force, to improve the efficiency of droplet formation. The microgel precursor (including alginate and carboxymethyl cellulose derivatives possessing phenolic hydroxyl moieties) could be dispersed in the DEX solution at various concentrations. Uniform droplets were formed with controllable diameters, and were sequentially converted to microgel by horseradish peroxidase-catalyzed crosslinking. Cells were dispersed in the DEX phase with the microgel precursor polymer, and retained their high viability and proliferation in the resulting microgel. The solubility of gelatin derivatives in the DEX phase was low, but was sufficient to impart cell adhesion properties on the microgel.

  5. Droplets formation and merging in two-phase flow microfluidics. (United States)

    Gu, Hao; Duits, Michel H G; Mugele, Frieder


    Two-phase flow microfluidics is emerging as a popular technology for a wide range of applications involving high throughput such as encapsulation, chemical synthesis and biochemical assays. Within this platform, the formation and merging of droplets inside an immiscible carrier fluid are two key procedures: (i) the emulsification step should lead to a very well controlled drop size (distribution); and (ii) the use of droplet as micro-reactors requires a reliable merging. A novel trend within this field is the use of additional active means of control besides the commonly used hydrodynamic manipulation. Electric fields are especially suitable for this, due to quantitative control over the amplitude and time dependence of the signals, and the flexibility in designing micro-electrode geometries. With this, the formation and merging of droplets can be achieved on-demand and with high precision. In this review on two-phase flow microfluidics, particular emphasis is given on these aspects. Also recent innovations in microfabrication technologies used for this purpose will be discussed.

  6. Diffusion analysis for two-phase metal-matrix composite (United States)

    Tenney, D. R.


    Diffusion controlled filament matrix interaction in a metal matrix composite, where the filaments and matrix comprise a two phase binary alloy system, was mathematically modeled. The problem of a diffusion controlled, two phase moving interface by means of a one dimensional, variable grid, finite difference technique was analyzed. Concentration dependent diffusion coefficients and equilibrium solubility limits were used, and the change in filament diameter and compositional changes in the matrix were calculated as a function of exposure time at elevated temperatures. With the tungsten nickel (W-Ni) system as a model composite system, unidirectional composites containing from 0.06 to 0.44 initial filament volume fraction were modeled. Compositional changes in the matrix were calculated by superposition of the contributions from neighboring filaments. Alternate methods for determining compositional changes between first and second nearest neighbor filaments were also considered. The results show the relative importance of filament volume fraction, filament diameter, exposure temperature, and exposure time as they affect the rate and extent of filament matrix interaction.

  7. Experimental study of two-phase natural circulation circuit

    Energy Technology Data Exchange (ETDEWEB)

    Lemos, Wanderley Freitas; Su, Jian, E-mail:, E-mail: [Coordenacao dos Programas de Pos-Graduacao em Engenharia (COPPE/UFRJ), Rio de Janeiro, RJ (Brazil). Programa de Engenharia Nuclear; Faccini, Jose Luiz Horacio, E-mail: [Instituto de Engenharia Nuclear (IEN/CNEN-RJ), RIo de Janeiro, RJ (Brazil). Lab. de Termo-Hidraulica Experimental


    This paper reports an experimental study on the behavior of fluid flow in natural circulation under single-and two-phase flow conditions. The natural circulation circuit was designed based on concepts of similarity and scale in proportion to the actual operating conditions of a nuclear reactor. This test equipment has similar performance to the passive system for removal of residual heat presents in Advanced Pressurized Water Reactors (A PWR). The experiment was carried out by supplying water to primary and secondary circuits, as well as electrical power resistors installed inside the heater. Power controller has available to adjust the values for supply of electrical power resistors, in order to simulate conditions of decay of power from the nuclear reactor in steady state. Data acquisition system allows the measurement and control of the temperature at different points by means of thermocouples installed at several points along the circuit. The behavior of the phenomenon of natural circulation was monitored by a software with graphical interface, showing the evolution of temperature measurement points and the results stored in digital format spreadsheets. Besides, the natural circulation flow rate was measured by a flowmeter installed on the hot leg. A flow visualization technique was used the for identifying vertical flow regimes of two-phase natural circulation. Finally, the Reynolds Number was calculated for the establishment of a friction factor correlation dependent on the scale geometrical length, height and diameter of the pipe. (author)

  8. Two-phase deformation of lower mantle mineral analogs (United States)

    Kaercher, P.; Miyagi, L.; Kanitpanyacharoen, W.; Zepeda-Alarcon, E.; Wang, Y.; Parkinson, D.; Lebensohn, R. A.; De Carlo, F.; Wenk, H. R.


    The lower mantle is estimated to be composed of mostly bridgmanite and a smaller percentage of ferropericlase, yet very little information exists for two-phase deformation of these minerals. To better understand the rheology and active deformation mechanisms of these lower mantle minerals, especially dislocation slip and the development of crystallographic preferred orientation (CPO), we deformed mineral analogs neighborite (NaMgF3, iso-structural with bridgmanite) and halite (NaCl, iso-structural with ferropericlase) together in the deformation-DIA at the Advanced Photon Source up to 51% axial shortening. Development of CPO was recorded in situ with X-ray diffraction, and information on microstructural evolution was collected using X-ray microtomography. Results show that when present in as little as 15% volume, the weak phase (NaCl) controls the deformation. Compared to single phase NaMgF3 samples, samples with just 15% volume NaCl show a reduction of CPO in NaMgF3 and weakening of the aggregate. Microtomography shows both NaMgF3 and NaCl form highly interconnected networks of grains. Polycrystal plasticity simulations were carried out to gain insight into slip activity, CPO evolution, and strain and stress partitioning between phases for different synthetic two-phase microstructures. The results suggest that ferropericlase may control deformation in the lower mantle and reduce CPO in bridgmanite, which implies a less viscous lower mantle and helps to explain why the lower mantle is fairly isotropic.

  9. Droplets Formation and Merging in Two-Phase Flow Microfluidics

    Directory of Open Access Journals (Sweden)

    Hao Gu


    Full Text Available Two-phase flow microfluidics is emerging as a popular technology for a wide range of applications involving high throughput such as encapsulation, chemical synthesis and biochemical assays. Within this platform, the formation and merging of droplets inside an immiscible carrier fluid are two key procedures: (i the emulsification step should lead to a very well controlled drop size (distribution; and (ii the use of droplet as micro-reactors requires a reliable merging. A novel trend within this field is the use of additional active means of control besides the commonly used hydrodynamic manipulation. Electric fields are especially suitable for this, due to quantitative control over the amplitude and time dependence of the signals, and the flexibility in designing micro-electrode geometries. With this, the formation and merging of droplets can be achieved on-demand and with high precision. In this review on two-phase flow microfluidics, particular emphasis is given on these aspects. Also recent innovations in microfabrication technologies used for this purpose will be discussed.

  10. Novel method for determination of anthracene by coupling dispersive liquid-liquid extraction to first-derivative synchronous spectrofluorimetry. (United States)

    Abdel-Aziz, Omar; El Kosasy, A M; El-Sayed Okeil, Sherif Mahmoud


    A novel method could be adopted successfully for determination of anthracene in environmental samples, utilizing dispersive liquid-liquid extraction followed by first-derivative synchronous fluorimetry at a constant wavelength difference Δλ = 165 nm, where a linear calibration curve was obtained in a concentration range of 0.5-100 ng mL(-1) at 244 nm. The detection limit was 0.1 ng mL(-1). The method can be easily adopted for determination of anthracene in aqueous media including tap water and river water. The recoveries obtained were 85.40-108.02%. The proposed method was validated according to International Conference of Harmonization (ICH) guide lines and successfully applied to determine anthracene in pure form and in water samples including real life water samples from different sources. All the results obtained were compared with those of published method, where no a significant difference was observed.

  11. Speciation analysis of mercury in water samples by dispersive liquid-liquid microextraction coupled to capillary electrophoresis. (United States)

    Yang, Fangfang; Li, Jinhua; Lu, Wenhui; Wen, Yingying; Cai, Xiaoqiang; You, Jinmao; Ma, Jiping; Ding, Yangjun; Chen, Lingxin


    In this study, a method of pretreatment and speciation analysis of mercury by dispersive liquid-liquid microextraction along with CE was developed. The method was based on the fact that mercury species including methylmercury (MeHg), ethylmercury (EtHg), phenylmercury (PhHg), and Hg(II) were complexed with 1-(2-pyridylazo)-2-naphthol to form hydrophobic chelates and l-cysteine could displace 1-(2-pyridylazo)-2-naphthol to form hydrophilic chelates with the four mercury species. Factors affecting complex formation and extraction efficiency, such as pH value, type, and volume of extractive solvent and disperser solvent, concentration of the chelating agent, ultrasonic time, and buffer solution were investigated. Under the optimal conditions, the enrichment factors were 102, 118, 547, and 46, and the LODs were 1.79, 1.62, 0.23, and 1.50 μg/L for MeHg, EtHg, PhHg, and Hg(II), respectively. Method precisions (RSD, n = 5) were in the range of 0.29-0.54% for migration time, and 3.08-7.80% for peak area. Satisfactory recoveries ranging from 82.38 to 98.76% were obtained with seawater, lake, and tap water samples spiked at three concentration levels, respectively, with RSD (n = 5) of 1.98-7.18%. This method was demonstrated to be simple, convenient, rapid, cost-effective, and environmentally benign, and could be used as an ideal alternative to existing methods for analyzing trace residues of mercury species in water samples. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. A Diffuse Interface Model for Incompressible Two-Phase Flow with Large Density Ratios

    KAUST Repository

    Xie, Yu


    In this chapter, we explore numerical simulations of incompressible and immiscible two-phase flows. The description of the fluid–fluid interface is introduced via a diffuse interface approach. The two-phase fluid system is represented by a coupled Cahn–Hilliard Navier–Stokes set of equations. We discuss challenges and approaches to solving this coupled set of equations using a stabilized finite element formulation, especially in the case of a large density ratio between the two fluids. Specific features that enabled efficient solution of the equations include: (i) a conservative form of the convective term in the Cahn–Hilliard equation which ensures mass conservation of both fluid components; (ii) a continuous formula to compute the interfacial surface tension which results in lower requirement on the spatial resolution of the interface; and (iii) a four-step fractional scheme to decouple pressure from velocity in the Navier–Stokes equation. These are integrated with standard streamline-upwind Petrov–Galerkin stabilization to avoid spurious oscillations. We perform numerical tests to determine the minimal resolution of spatial discretization. Finally, we illustrate the accuracy of the framework using the analytical results of Prosperetti for a damped oscillating interface between two fluids with a density contrast.

  13. Validation of NEPTUNE-CFD Two-Phase Flow Models Using Experimental Data

    Directory of Open Access Journals (Sweden)

    Jorge Pérez Mañes


    Full Text Available This paper deals with the validation of the two-phase flow models of the CFD code NEPTUNEC-CFD using experimental data provided by the OECD BWR BFBT and PSBT Benchmark. Since the two-phase models of CFD codes are extensively being improved, the validation is a key step for the acceptability of such codes. The validation work is performed in the frame of the European NURISP Project and it was focused on the steady state and transient void fraction tests. The influence of different NEPTUNE-CFD model parameters on the void fraction prediction is investigated and discussed in detail. Due to the coupling of heat conduction solver SYRTHES with NEPTUNE-CFD, the description of the coupled fluid dynamics and heat transfer between the fuel rod and the fluid is improved significantly. The averaged void fraction predicted by NEPTUNE-CFD for selected PSBT and BFBT tests is in good agreement with the experimental data. Finally, areas for future improvements of the NEPTUNE-CFD code were identified, too.

  14. Numerical simulation of two-phase flow behavior in Venturi scrubber by interface tracking method

    Energy Technology Data Exchange (ETDEWEB)

    Horiguchi, Naoki, E-mail: [Japan Atomic Energy Agency, 2-4, Shirakata, Tokai-mura, Naka-gun, Ibaraki 319-1195 (Japan); University of Tsukuba, 1-1-1, Tennodai, Tsukuba, Ibaraki, 305-8577 (Japan); Yoshida, Hiroyuki [Japan Atomic Energy Agency, 2-4, Shirakata, Tokai-mura, Naka-gun, Ibaraki 319-1195 (Japan); Abe, Yutaka [University of Tsukuba, 1-1-1, Tennodai, Tsukuba, Ibaraki, 305-8577 (Japan)


    Highlights: • Self-priming occur because of pressure balance between inside and outside of throat is confirmed. • VS has similar flow with a Venturi tube except of disturbance and burble flow is considered. • Some of atomization simulated are validated qualitatively by comparison with previous studies. - Abstract: From the viewpoint of protecting a containment vessel of light water reactor and suppressing the diffusion of radioactive materials from a light water reactor, it is important to develop the device which allows a filtered venting of contaminated high pressure gas. In the filtered venting system that used in European reactors, so called Multi Venturi scrubbers System is used to realize filtered venting without any power supply. This system is able to define to be composed of Venturi scrubbers (VS) and a bubble column. In the VS, scrubbing of contaminated gas is promoted by both gas releases through the submerged VS and gas-liquid contact with splay flow formed by liquid suctioned through a hole provided by the pressure difference between inner and outer regions of a throat part of the VS. However, the scrubbing mechanism of the self-priming VS including effects of gas mass flow rate and shape of the VS are understood insufficiently in the previous studies. Therefore, we started numerical and experimental study to understand the detailed two-phase flow behavior in the VS. In this paper, to understand the VS operation characteristics for the filtered venting, we performed numerical simulations of two-phase flow behavior in the VS. In the first step of this study, we perform numerical simulations of supersonic flow by the TPFIT to validate the applicability of the TPFIT for high velocity flow like flow in the VS. In the second step, numerical simulation of two-phase flow behavior in the VS including self-priming phenomena. As the results, dispersed flow in the VS was reproduced in the numerical simulation, as same as the visualization experiments.

  15. Investigation of Power Losses of Two-Stage Two-Phase Converter with Two-Phase Motor

    Directory of Open Access Journals (Sweden)

    Michal Prazenica


    Full Text Available The paper deals with determination of losses of two-stage power electronic system with two-phase variable orthogonal output. The simulation is focused on the investigation of losses in the converter during one period in steady-state operation. Modeling and simulation of two matrix converters with R-L load is shown in the paper. The simulation results confirm a very good time-waveform of the phase current and the system seems to be suitable for low-cost application in automotive/aerospace industries and in application with high frequency voltage sources.

  16. Performance of a two-phase gas/liquid flow model in vertical wells

    Energy Technology Data Exchange (ETDEWEB)

    Kabir, C.S.; Hasan, A.R. (Chevron Oil Field Research Co., La Habra, CA (USA))


    Application of a recently developed method for predicting two-phase gas/oil pressure-drop in vertical oil wells is presented. The new method, which is flow-pattern based, is capable of handling flow in both circular and annular channels. Five principal flow regimes, bubbly, dispersed bubbly, slug, churn and annular, are recognized while developing appropriate correlations for predicting void fraction and pressure-drop in each flow regime. Standard oilfield correlations are used for estimating PVT properties of oil and gas: Standing's correlation for solution gas-oil ratio; Katz's correlation for oil formation volume factor; Standing's, and Chew and Connally's correlations for dead and live oil viscosities, respectively; and Lee et al.'s correlation for gas viscosity. A finite-difference algorithm is developed to compute pressure gradient in a wellbore. Computations performed on 115 field tests, involving all the two-phase flow regimes, suggest that the new method performs better than the Aziz et al. correlation. Further comparison of the new method's performance with other standard methods, such as, Orkiszewski, Duns and Ros, Beggs and Brill, Hagedorn and Brown, and Chierci et al., reveals its consistency and improved performance. The test data bank used in this study is that previously used by other authors; thus, validation of the new method is demonstrated with an independent data set. 4 figs., 42 refs., 7 tabs.

  17. Digital image plane holography (DIPH) for two-phase flow diagnostics in multiple planes (United States)

    Palero, V.; Lobera, J.; Arroyo, M. P.


    A technique for measuring the size and displacement of the disperse phase in two planes of a two-phase flow is presented. Digital image plane holography (DIPH) is used for the simultaneous recording and independent reconstruction of both planes. Each fluid plane is illuminated with two laser sheets propagating in opposite directions. The defocused image fields are holographically recorded at 90°, and can be reconstructed either in a defocused or in the best-focused plane. The analysis of the images in a defocused plane provides the sizes, while the cross-correlation of the focused images provides the velocity field, as in a regular particle image velocimetry (PIV) experiment. For air bubbles freely drifting in glycerine, diameters from 50 μm to 400 μm and displacements of up to 300 μm have been measured.

  18. Computational dynamics of two-phase flows. Final report on Phase 1

    Energy Technology Data Exchange (ETDEWEB)

    Goldhirsch, I.


    Phase I of the investigation concentrated on the study of a prototypical example of a dispersed two-phase system, i.e., that of a monodisperse suspension of spheres. Using exact mathematical analysis, researchers obtained local instant equations for the momentum field, the density fields and the suspension angular momentum field, which together comprise a closed set of equations. Exact expressions for the pressure field inside the fluid phase in terms of the velocity field and for the force acting on any particle in the suspension were found. Coarse graining procedures of the equations were performed at various levels. The coarse grained equations contain new coupings which are nonexistent in presently used engineering models. A program for further generalization of these results up to an applied level has been formulated and integration of the new models into the complex geometry flow code NEKTON has been planned.

  19. Comparison of ultrasound-assisted cloud point extraction and ultrasound-assisted dispersive liquid liquid microextraction for copper coupled with spectrophotometric determination (United States)

    Yang, Shengchun; Fang, Xiang; Duan, Liju; Yang, Shu; Lei, Zirong; Wen, Xiaodong


    In this work, ultrasound-assisted cloud point extraction (UA-CPE) and ultrasound-assisted dispersive liquid liquid microextraction (UA-DLLME) were investigated and compared firstly as ultrasound-assisted liquid phase microextraction methods, which were coupled with spectrophotometer for copper preconcentration and detection. Compared to conventional CPE and DLLME, the extraction patterns were changed and improved by the effect of ultrasound. As novel methods, their applications were expanded and the analytical performance of spectrophotometric determination for copper was considerably improved. The influence factors of UA-CPE and UA-DLLME were studied in detail. Under the optimal conditions, the limits of detection (LODs) for copper were 0.7 μg L-1 of UA-CPE and 0.8 μg L-1 of UA-DLLME with sensitivity enhancement factors (EFs) of 17 and 16. The developed methods were applied to the determination of trace copper in real water samples with satisfactory analytical results.

  20. Synthesis of Disperse Dyes from Pyridone and Resorcinol Coupled to Diazotized 2-Amino-4-chloro-5-formylthiazole and Application to Polyester

    Directory of Open Access Journals (Sweden)

    Yusuf Y. Lams


    Full Text Available The aim of this study was to synthesize disperse dyes in the derivative of 2-amino-4-chloro-5-formylthiazole by conventional diazotization and couplings with pyridone and resorcinol. The dyes were characterized by visible absorption spectroscopy, IR spectral studies, and 1H and 13C NMR. The pyridone and resorcinol substituted dyes exhausted well with good depth on 100% polyester fabrics with a shade of brown and purple colours, respectively. The heteroatom and the intrinsic conjugation in the thiazole structure results in high bathochromic shifts and lead to brightness of shades. The dyed fabrics showed very good to excellent wash fastness and moderate to good light and perspiration fastness properties.

  1. A coupled SAFE-2.5D BEM approach for the dispersion analysis of damped leaky guided waves in embedded waveguides of arbitrary cross-section. (United States)

    Mazzotti, M; Bartoli, I; Marzani, A; Viola, E


    The paper presents a Semi-Analytical Finite Element (SAFE) formulation coupled with a 2.5D Boundary Element Method (BEM) for the computation of the dispersion properties of viscoelastic waveguides with arbitrary cross-section and embedded in unbounded isotropic viscoelastic media. Attenuation of guided modes is described through the imaginary component of the axial wavenumber, which accounts for material damping, introduced via linear viscoelastic constitutive relations, as well as energy loss due to radiation of bulk waves in the surrounding media. Energy radiation is accounted in the SAFE model by introducing an equivalent dynamic stiffness matrix for the surrounding medium, which is derived from a regularized 2.5D boundary element formulation. The resulting dispersive wave equation is configured as a nonlinear eigenvalue problem in the complex axial wavenumber. The eigenvalue problem is reduced to a linear one inside a chosen contour in the complex plane of the axial wavenumber by using a contour integral method. Poles of leaky and evanescent modes are obtained by choosing appropriately the phase of the wavenumbers normal to the interface in compliance with the nature of the waves in the surrounding medium. Finally, the obtained eigensolutions are post-processed to compute the energy velocity and the radiated wavefield in the surrounding domain. The reliability of the method is first validated on existing results for waveguides of circular cross sections embedded in elastic and viscoelastic media. Next, the potential of the proposed numerical framework is shown by computing the dispersion properties for a square steel bar embedded in grout and for an H-shaped steel pile embedded in soil. Copyright © 2013 Elsevier B.V. All rights reserved.

  2. Suzuki Coupling Reactions Catalyzed by PdO Dispersed on Dealuminated Y Zeolite in Air under Ambient Conditions. (United States)

    Okumura, Kazu; Mushiake, Takumi; Matsui, Yu; Ishii, Akira


    Suzuki coupling reactions are performed using PdO loaded on dealuminated Y (USY) zeolite. The reaction between bromobenzene and phenylboronic acid is complete in 15 min at room temperature in air, with a turnover number of 1300. The reaction can be repeated at least five times by using 1 wt % Pd. Inductively coupled plasma analysis does not reveal the dissolution of Pd from products, even if the reaction is repeated up to four times. Pd K-edge extended X-ray absorption fine structure analysis reveals the presence of molecular-like PdO and a mixture of Pd(0) -PdO before and after the reaction, respectively. This is probably because Pd stabilized by Al sites is present at the II sites of the Y-type zeolite, as estimated using first-principles calculations. Conversely, Pd species change to PdO clusters after repeated reactions in air using the thermally treated sample. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. Dispersive liquid-liquid microextraction coupled with digital image colorimetric analysis for detection of total iron in water and food samples. (United States)

    Peng, Bo; Chen, Guorong; Li, Kai; Zhou, Min; Zhang, Ji; Zhao, Shengguo


    A simple and low cost assay for total iron in various samples based on dispersive liquid-liquid microextraction (DLLME) coupled with digital scanning image analysis was proposed. Orthogonal experiment design was utilized to optimize the amount of extraction solvent and disperser solvent, O-phenanthroline concentration and buffer pH. Under the optimum conditions, the calibration curve was linear over the range of 0.047-1.0μgmL(-1) (R(2)>0.99) of iron. The limit of detection (LOD) for iron was 14.1μgL(-1) and limit of quantification (LOQ) was 46.5μgL(-1). The relative standard deviations for seven replicate determinations of 0.5μgmL(-1) of iron was 3.75%. The method was successfully applied for analysis of total iron in water and food samples without using any spectral instrument and it could have a potential industrial impact in developing fast and portable devices to analyze the iron content in water and certain foods. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. Up-and-down-shaker-assisted dispersive liquid-liquid microextraction coupled with gas chromatography-mass spectrometry for the determination of fungicides in wine. (United States)

    Chu, Shang-Ping; Tseng, Wan-Chi; Kong, Po-Hsin; Huang, Chun-Kai; Chen, Jung-Hsuan; Chen, Pai-Shan; Huang, Shang-Da


    An up-and-down-shaker-assisted dispersive liquid-liquid microextraction (UDSA-DLLME) method coupled with gas chromatography-mass spectrometry was developed for the determination of fungicides (cyprodinil, procymidone, fludioxonil, flusilazole, benalaxyl, and tebuconazole) in wine. The developed method requires 11 μL of 1-octanol without the need for dispersive solvents. The total extraction time was approximately 3 min. Under optimum conditions, the linear range of the method was 0.05-100 μg L(-1) for all fungicides and the limit of detection was 0.007-0.025 μg L(-1). The absolute and relative recoveries were 31-83% and 83-107% for white wine, respectively, and 32-85% and 83-108% for red wine, respectively. The intra-day and inter-day precision were 0.5-7.5% and 0.7-6.1%, respectively. Our developed method had good sensitivity and high extraction efficiency. UDSA-DLLME is a desirable method in terms of performance and speed. Copyright © 2015 Elsevier Ltd. All rights reserved.

  5. One-baryon spectrum and analytical properties of one-baryon dispersion curves in 3 + 1 dimensional strongly coupled lattice QCD with three flavors

    Energy Technology Data Exchange (ETDEWEB)

    Faria da Veiga, Paulo A., E-mail:; O’Carroll, Michael, E-mail:; Valencia Alvites, José C., E-mail: [Departamento de Matemática Aplicada e Estatística, ICMC, USP-São Carlos, C.P. 668, São Carlos, SP 13560-970 (Brazil)


    Considering a 3 + 1 dimensional lattice quantum chromodynamics (QCD) model defined with the improved Wilson action, three flavors, and 4 × 4 Dirac spin matrices, in the strong coupling regime, we reanalyze the question of the existence of the eightfold way baryons and complete our previous work where the existence of isospin octet baryons was rigorously solved. Here, we show the existence of isospin decuplet baryons which are associated with isolated dispersion curves in the subspace of the underlying quantum mechanical Hilbert space with vectors constructed with an odd number of fermion and antifermion basic quark and antiquark fields. Moreover, smoothness properties for these curves are obtained. The present work deals with a case for which the traditional method to solve the implicit equation for the dispersion curves, based on the use of the analytic implicit function theorem, cannot be applied. We do not have only one but two solutions for each one-baryon decuplet sector with fixed spin third component. Instead, we apply the Weierstrass preparation theorem, which also provides a general method for the general degenerate case. This work is completed by analyzing a spectral representation for the two-baryon correlations and providing the leading behaviors of the field strength normalization and the mass of the spectral contributions with more than one-particle. These are needed results for a rigorous analysis of the two-baryon and meson-baryon particle spectra.

  6. Determination of total iron in water and foods by dispersive liquid-liquid microextraction coupled with microvolume UV-vis spectrophotometry. (United States)

    Peng, Bo; Shen, Yingping; Gao, Zhuantao; Zhou, Min; Ma, Yongjun; Zhao, Shengguo


    A novel microvolume UV-vis spectrophotometry method was proposed for the rapid determination of total iron coupling with an efficient pretreatment method known as dispersive liquid-liquid microextraction (DLLME). The basis of the method is a quantitative colorimetric reaction between ferrous iron and 2-(5-bromo-2-pyridylazo)-5-(diethyl amino) phenol (5-Br-PADAP) after the reduction of Fe(III) to Fe(II) by using ascorbic acid as reducing agent. Parameters related to the efficiency of microextraction, such as pH, complexant concentration, the volume ratio of disperser solvent and extraction solvent were discussed and optimized in detail. Under the optimized conditions, the absorbance was in proportion to iron concentration in the range of 5-400μgL(-1) with a correlation coefficient (R) of 0.9993. The limit of detection (LOD) and limit of quantitation (LOQ) were 1.5μgL(-1) and 5.2μgL(-1), respectively. The relative standard deviation (RSD) for samples were 1.37- 4.42% (n=3). Good recoveries of iron were obtained in the range of 95.4-103.2% in food samples, 96.9-103.6% in water samples and 98.8-102.3% in Certified Reference Material. The proposed method was rapid, reliable and high-selective for the determination of total iron in food and water samples. Copyright © 2014 Elsevier Ltd. All rights reserved.

  7. Automated dispersive liquid-liquid microextraction coupled to high performance liquid chromatography - cold vapour atomic fluorescence spectroscopy for the determination of mercury species in natural water samples. (United States)

    Liu, Yao-Min; Zhang, Feng-Ping; Jiao, Bao-Yu; Rao, Jin-Yu; Leng, Geng


    An automated, home-constructed, and low cost dispersive liquid-liquid microextraction (DLLME) device that directly coupled to a high performance liquid chromatography (HPLC) - cold vapour atomic fluorescence spectroscopy (CVAFS) system was designed and developed for the determination of trace concentrations of methylmercury (MeHg(+)), ethylmercury (EtHg(+)) and inorganic mercury (Hg(2+)) in natural waters. With a simple, miniaturized and efficient automated DLLME system, nanogram amounts of these mercury species were extracted from natural water samples and injected into a hyphenated HPLC-CVAFS for quantification. The complete analytical procedure, including chelation, extraction, phase separation, collection and injection of the extracts, as well as HPLC-CVAFS quantification, was automated. Key parameters, such as the type and volume of the chelation, extraction and dispersive solvent, aspiration speed, sample pH, salt effect and matrix effect, were thoroughly investigated. Under the optimum conditions, linear range was 10-1200ngL(-1) for EtHg(+) and 5-450ngL(-1) for MeHg(+) and Hg(2+). Limits of detection were 3.0ngL(-1) for EtHg(+) and 1.5ngL(-1) for MeHg(+) and Hg(2+). Reproducibility and recoveries were assessed by spiking three natural water samples with different Hg concentrations, giving recoveries from 88.4-96.1%, and relative standard deviations <5.1%. Copyright © 2017 Elsevier B.V. All rights reserved.

  8. One-step displacement dispersive liquid-liquid microextraction coupled with graphite furnace atomic absorption spectrometry for the selective determination of methylmercury in environmental samples. (United States)

    Liang, Pei; Kang, Caiyan; Mo, Yajun


    A novel method for the selective determination of methylmercury (MeHg) was developed by one-step displacement dispersive liquid-liquid microextraction (D-DLLME) coupled with graphite furnace atomic absorption spectrometry. In the proposed method, Cu(II) reacted with diethyldithiocarbamate (DDTC) to form Cu-DDTC complex, which was used as the chelating agent instead of DDTC for the dispersive liquid-liquid microextraction (DLLME) of MeHg. Because the stability of MeHg-DDTC is higher than that of Cu-DDTC, MeHg can displace Cu from the Cu-DDTC complex and be preconcentrated in a single DLLME procedure. MeHg could be extracted into the extraction solvent phase at pH 6 while Hg(II) remained in the sample solution. Potential interference from co-existing metal ions with lower DDTC complex stability was largely eliminated without the need of any masking reagent. Under the optimal conditions, the limit of detection of this method was 13.6ngL(-1) (as Hg), and an enhancement factor of 81 was achieved with a sample volume of 5.0mL. The proposed method was successfully applied for the determination of trace MeHg in some environmental samples with satisfactory results. Copyright © 2015 Elsevier B.V. All rights reserved.

  9. Tractability gains in symmetry-adapted perturbation theory including coupled double excitations: CCD+ST(CCD) dispersion with natural orbital truncations (United States)

    Parrish, Robert M.; Hohenstein, Edward G.; Sherrill, C. David


    This work focuses on efficient and accurate treatment of the intermolecular dispersion interaction using the CCD+ST(CCD) dispersion approach formulated by Williams et al. [J. Chem. Phys. 103, 4586 (1995)]. We apply natural orbital truncation techniques to the solution of the monomer coupled-cluster double (CCD) equations, yielding substantial accelerations in this computationally demanding portion of the SAPT2+(CCD), SAPT2+(3)(CCD), and SAPT2+3(CCD) analyses. It is shown that the wholly rate-limiting dimer-basis particle-particle ladder term can be computed in a reduced natural virtual space which is essentially the same size as the monomer-basis virtual space, with an error on the order of a few thousandths of 1 kcal mol-1. Coupled with our existing natural orbital techniques for the perturbative triple excitation contributions [E. G. Hohenstein and C. D. Sherrill, J. Chem. Phys. 133, 104107 (2010)], this technique provides speedups of greater than an order of magnitude for the evaluation of the complete SAPT2+3(CCD) decomposition, with a total error of a few hundredths of 1 kcal mol-1. The combined approach yields tractability gains of almost 2× in the system size, allowing for SAPT2+3(CCD)/aug-cc-pVTZ analysis to be performed for systems such as adenine-thymine for the first time. Natural orbital based SAPT2+3(CCD)/aug-cc-pVTZ results are presented for stacked and hydrogen-bonded configurations of uracil dimer and the adenine-thymine dimer.

  10. Phase Detection aided Thermometry for Two-Phase Flow (United States)

    Takeyama, Mao; Kunugi, Tomoaki; Kawara, Zensaku; Yokomine, Takehiko


    Since temperature and void fraction (or phase fraction) are important parameters to characterize and grasp multiphase flow behaviors, various methods have been developed and applied to. However, these multi-phase flow parameters cannot be measured at the same time and position because they need the individual sensor. A new thermometry to detect the phase for two-phase flow and simultaneously measure the liquid/gas temperature with a miniature thermocouple with high temporal-spatial resolutions is developed; this method was named as a phase detection aided thermometry (PDaT). The principle of PDaT is that a miniature (φ25 μm) thermocouple with 10 kHz of the sampling rate is used not only as a thermometer with the high temporal-spatial resolution, but also as an electrical conductance probe as a phase detector. The results of the proof of principle experiments will be presented.

  11. Two phase fermentation of whole leaf biomass to biogas

    Energy Technology Data Exchange (ETDEWEB)

    Chanakya, H.N.; Borgaonkar, S.; Rajan, M.G.C.; Wahi, M. (Indian Inst. of Science, Bangalore (India))


    Two phase (diphasic) fermentation of untreated whole leaf biomass involving a solid phase acidogenic system and an upflow anaerobic packed bed digester for methanogenesis has been studied. The solid phase acidogenic system consisted of a bed of biomass (22% solids) sprinkled daily with an aqueous suspension of biodegrading bacteria. Accumulation of volatile fatty acids (VFA) in the liquid lowered its pH to about 5 and suppressed methanogenesis in the biomass bed. A part of the leachate from the acidogenic digester was fed to the methanogenic digesters. Clear phase separation was obtained with fresh or dried leaf biomass when the total VFA levels exceeded 6 g L[sup -1] (pH 5). At low VFA concentrations in the first stage significant levels of gas production occurred from the decomposing biomass bed indicating a possibility of solid phase fermentation without phase separation if VFA and pH levels are maintained within these critical limits. (author)

  12. Solutal Marangoni instability in layered two-phase flows

    CERN Document Server

    Picardo, Jason R; Pushpavanam, S


    In this paper, the instability of layered two-phase flows caused by the presence of a soluble surfactant (or a surface active solute) is studied. The fluids have different viscosities, but are density matched to focus on Marangoni effects. The fluids flow between two flat plates, which are maintained at different solute concentrations. This establishes a constant flux of solute from one fluid to the other in the base state. A linear stability analysis is performed, using a combination of asymptotic and numerical methods. In the creeping flow regime, Marangoni stresses destabilize the flow, provided a concentration gradient is maintained across the fluids. One long wave and two short wave Marangoni instability modes arise, in different regions of parameter space. A well-defined condition for the long wave instability is determined in terms of the viscosity and thickness ratios of the fluids, and the direction of mass transfer. Energy budget calculations show that the Marangoni stresses that drive long and shor...

  13. Numerical modeling of two-phase transonic flow

    Czech Academy of Sciences Publication Activity Database

    Halama, Jan; Benkhaldoun, F.; Fořt, Jaroslav


    Roč. 80, č. 88 (2010), s. 1624-1635 ISSN 0378-4754 Grant - others:GA ČR(CZ) GA201/08/0012 Program:GA Institutional research plan: CEZ:AV0Z20760514 Keywords : two-phase flow * condensation * fractional step method Subject RIV: BK - Fluid Dynamics Impact factor: 0.812, year: 2010

  14. Emerging Two-Phase Cooling Technologies for Power Electronic Inverters

    Energy Technology Data Exchange (ETDEWEB)

    Hsu, J.S.


    In order to meet the Department of Energy's (DOE's) FreedomCAR and Vehicle Technologies (FVCT) goals for volume, weight, efficiency, reliability, and cost, the cooling of the power electronic devices, traction motors, and generators is critical. Currently the power electronic devices, traction motors, and generators in a hybrid electric vehicle (HEV) are primarily cooled by water-ethylene glycol (WEG) mixture. The cooling fluid operates as a single-phase coolant as the liquid phase of the WEG does not change to its vapor phase during the cooling process. In these single-phase systems, two cooling loops of WEG produce a low temperature (around 70 C) cooling loop for the power electronics and motor/generator, and higher temperature loop (around 105 C) for the internal combustion engine. There is another coolant option currently available in automobiles. It is possible to use the transmission oil as a coolant. The oil temperature exists at approximately 85 C which can be utilized to cool the power electronic and electrical devices. Because heat flux is proportional to the temperature difference between the device's hot surface and the coolant, a device that can tolerate higher temperatures enables the device to be smaller while dissipating the same amount of heat. Presently, new silicon carbide (SiC) devices and high temperature direct current (dc)-link capacitors, such as Teflon capacitors, are available but at significantly higher costs. Higher junction temperature (175 C) silicon (Si) dies are gradually emerging in the market, which will eventually help to lower hardware costs for cooling. The development of high-temperature devices is not the only way to reduce device size. Two-phase cooling that utilizes the vaporization of the liquid to dissipate heat is expected to be a very effective cooling method. Among two-phase cooling methods, different technologies such as spray, jet impingement, pool boiling and submersion, etc. are being developed. The

  15. Two phase flow models in DxUNSp code platform

    Directory of Open Access Journals (Sweden)

    Catalin NAE


    Full Text Available The aim of this work is to find an efficient implementation for a two phase flow model in an existing URANS CFD code platform (DxUNSp, initially based on unsteady URANS equations with a k- turbulence model and various other extensions, ranging from a broad selection of wall laws up to a very efficient LES model. This code has the capability for development for nonreacting/reacting multifluid flows for research applications and is under continuous progress. It is intend to present mainly three aspects of this implementation for unstructured mesh based solvers, for high Reynolds compressible flows: the importance of the 5/7 equation model, performance with respect to a basic test cases and implementation details of the proposed schemes. From a numerical point of view, we propose a new approximation schemes of this system based on the VFRoe-ncv.

  16. Characteristics of two-phase flows in large diameter channels

    Energy Technology Data Exchange (ETDEWEB)

    Schlegel, J.P., E-mail: [Department of Mining and Nuclear Engineering, Missouri University of Science and Technology, 301 W 14th St., Rolla, MO 65401 (United States); Hibiki, T.; Ishii, M. [School of Nuclear Engineering, Purdue University, 400 Central Dr., West Lafayette, IN 47907 (United States)


    Two-phase flows in large diameter channels have a great deal of importance in a wide variety of industrial applications. Nuclear systems, petroleum refineries, and chemical processes make extensive use of larger systems. Flows in such channels have very different properties from flows in smaller channels which are typically used in experimental research. In this paper, the various differences between flows in large and small channels are highlighted using the results of previous experimental and analytical research. This review is followed by a review of recent experiments in and model development for flows in large diameter channels performed by the authors. The topics of these research efforts range from void fraction and interfacial area concentration measurement to flow regime identification and modeling, drift-flux modeling for high void fraction conditions, and evaluation of interfacial area transport models for large diameter channels.

  17. Investigations of a Two-Phase Fluid Model

    CERN Document Server

    Nadiga, B T


    We study an interface-capturing two-phase fluid model in which the interfacial tension is modelled as a volumetric stress. Since these stresses are obtainable from a Van der Waals-Cahn-Hilliard free energy, the model is, to a certain degree, thermodynamically realistic. Thermal fluctuations are not considered presently for reasons of simplicity. The utility of the model lies in its momentum-conservative representation of surface tension and the simplicity of its numerical implementation resulting from the volumetric modelling of the interfacial dynamics. After validation of the model in two spatial dimensions, two prototypical applications---instability of an initially high-Reynolds-number liquid jet in the gaseous phase and spinodal decomposition in a liquid-gas system--- are presented.

  18. A Two Phase Treatment of an Infected Hip Endoprosthesis. (United States)

    Ciriviri, Jasmin; Talevski, Darko; Nestorovski, Zoran; Vraniskoski, Tode; Mishevska-Perchinkova, Snežana


    The revision of the two phase treatment represents a golden standard in the treatment of infected endoprosthesis. Throughout this study, the results of 21 patients with an infected hip endoprosthesis treated in two phases have been processed, with the use of an antibiotic spacer, within the period of 2009 and 2012. Thereby, a unique protocol for diagnosis and treatment of infections has been applied to all the patients, which entails a preoperational x-ray image, laboratory findings (Se, CRP), as well as a puncture aspiration with a microbiological and biochemical examination of the aspirated fragments. The operational treatment consists of: taking a sample for microbiological and histopathological diagnosis, removal of the implanted endoprosthesis, excision of the avascular and necrotic tissue and installing an antibiotic spacer. Postoperatively, the patients are treated with a parenteral application of an antibiotics based on an antibiogram, throughout a period of two weeks, and later on an oral treatment, a combination of two antibiotics, depending on the antibiogram, within the following four to six weeks. After the appeasement of the local findings and the laboratory results, a revision with a removal of the antibiotic spacer and reimplantation of an endoprosthesis - revisional or primary has been conducted on the patients, depending on the bone deficit. The functionality of the joint is graded based on the Haris Hip Score. The patients are being observed postoperatively for a period of 12 to 36 months. A definite reimplantation has been applied to 20 patients, while one patient has been treated with a resection method. The Haris Hip Score was 45 preoperatively, and 80 postoperatively. The applied protocol of the treatment of infected endoprosthesis is effective in the eradication of the infection and the final reimplantation.

  19. Supporting Universal Prevention Programs: A Two-Phased Coaching Model (United States)

    Becker, Kimberly D.; Darney, Dana; Domitrovich, Celene; Keperling, Jennifer Pitchford; Ialongo, Nicholas S.


    Schools are adopting evidence-based programs designed to enhance students’ emotional and behavioral competencies at increasing rates (Hemmeter, Snyder, & Artman, 2011). At the same time, teachers express the need for increased support surrounding implementation of these evidence-based programs (Carter & Van Norman, 2010). Ongoing professional development in the form of coaching may enhance teacher skills and implementation (Noell et al., 2005; Stormont, Reinke, Newcomer, Darney, & Lewis, 2012). There exists a need for a coaching model that can be applied to a variety of teacher skill levels and one that guides coach decision-making about how best to support teachers. This article provides a detailed account of a two-phased coaching model with empirical support developed and tested with coaches and teachers in urban schools (Becker, Bradshaw, Domitrovich, & Ialongo, 2013). In the initial universal coaching phase, all teachers receive the same coaching elements regardless of their skill level. Then, in the tailored coaching phase, coaching varies according to the strengths and needs of each teacher. Specifically, more intensive coaching strategies are used only with teachers who need additional coaching supports whereas other teachers receive just enough support to consolidate and maintain their strong implementation. Examples of how coaches used the two-phased coaching model when working with teachers who were implementing two universal prevention programs (i.e., the PATHS® curriculum and PAX Good Behavior Game [PAX GBG]) provide illustrations of the application of this model. The potential reach of this coaching model extends to other school-based programs as well as other settings in which coaches partner with interventionists to implement evidence-based programs. PMID:23660973

  20. Spatial structure and dispersion of drift mirror waves coupled with Alfvén waves in a 1-D inhomogeneous plasma

    Directory of Open Access Journals (Sweden)

    D. Yu. Klimushkin


    Full Text Available The paper employs the frame of a 1-D inhomogeneous model of space plasma,to examine the spatial structure and growth rate of drift mirror modes, often suggested for interpreting some oscillation types in space plasma. Owing to its coupling with the Alfvén mode, the drift mirror mode attains dispersion across magnetic shells (dependence of the frequency on the wave-vector's radial component, kr. The spatial structure of a mode confined across magnetic shells is studied. The scale of spatial localization of the wave is shown to be determined by the plasma inhomogeneity scale and by the azimuthal component of the wave vector. The wave propagates across magnetic shells, its amplitude modulated along the radial coordinate by the Gauss function. Coupling with the Alfvén mode strongly influences the growth rate of the drift mirror instability. The mirror mode can only exist in a narrow range of parameters. In the general case, the mode represents an Alfvén wave modified by plasma inhomogeneity.

  1. Creep of Two-Phase Microstructures for Microelectronic Applications

    Energy Technology Data Exchange (ETDEWEB)

    Reynolds, Heidi Linch [Univ. of California, Berkeley, CA (United States)


    The mechanical properties of low-melting temperature alloys are highly influenced by their creep behavior. This study investigates the dominant mechanisms that control creep behavior of two-phase, low-melting temperature alloys as a function of microstructure. The alloy systems selected for study were In-Ag and Sn-Bi because their eutectic compositions represent distinctly different microstructure.” The In-Ag eutectic contains a discontinuous phase while the Sn-Bi eutectic consists of two continuous phases. In addition, this work generates useful engineering data on Pb-free alloys with a joint specimen geometry that simulates microstructure found in microelectronic applications. The use of joint test specimens allows for observations regarding the practical attainability of superplastic microstructure in real solder joints by varying the cooling rate. Steady-state creep properties of In-Ag eutectic, Sn-Bi eutectic, Sn-xBi solid-solution and pure Bi joints have been measured using constant load tests at temperatures ranging from O°C to 90°C. Constitutive equations are derived to describe the steady-state creep behavior for In-Ageutectic solder joints and Sn-xBi solid-solution joints. The data are well represented by an equation of the form proposed by Dom: a power-law equation applies to each independent creep mechanism. Rate-controlling creep mechanisms, as a function of applied shear stress, test temperature, and joint microstructure, are discussed. Literature data on the steady-state creep properties of Sn-Bi eutectic are reviewed and compared with the Sn-xBi solid-solution and pure Bi joint data measured in the current study. The role of constituent phases in controlling eutectic creep behavior is discussed for both alloy systems. In general, for continuous, two-phase microstructure, where each phase exhibits significantly different creep behavior, the harder or more creep resistant phase will dominate the creep behavior in a lamellar microstructure. If a

  2. [Two-phase Interfaces in Weak External Fields (United States)

    Percus, J. K.


    Our aim has been that of understanding from first principles the behavior of two-phase interfaces in the absence of gravitational constraints. This is fundamental to our ability to deal with the fluid structures that abound in the real biological, chemical, and physical world. A substantial effort was mounted to determine how familiar hydrodynamic concepts have to be modified and interpreted to make them appropriate to the multi-level structure alluded to above. This was primarily in the context of the microscopic symmetric pressure tensor, which was, for the first time, expressed in the invaluable density functional format, and the used to follow the predictions of popular microscopic models of the energetics of interfacial systems. In the course of these investigations, the previous murky relation between pressure tensor and thermodynamics was completely clarified. The process of extending thermodynamic information to interfacial dynamics was initiated along two paths. One was from the viewpoint of an inertialess lattice gas, resulting in the surprising conclusion that at this level, all transport is governed by precisely the thermodynamic free energy, albeit with a non-trivial effective particle mobility. The other aimed at understanding the fashion in which slow macroscopic motions, accounted for by a time-varying microscopic energy, generate effective hydrodynamic parameters. By examining a solvable model system, it was found that all current procedures for doing so are deficient, and suitable alleviation suggested. The major effect of this project was to set the stage for the analysis of the substantial dynamical regimes in which extensive equilibrium information provides the dominant background. This produces a smooth junction to the models of Araki and Munakata, Giacomin and Lebowitz, and Oxtoby. It is also crucial to our understanding of the complex interfacial equilibrium configurations required for intermediate stages of two-phase separation, for which

  3. Multiphysics modeling of two-phase film boiling within porous corrosion deposits (United States)

    Jin, Miaomiao; Short, Michael


    Porous corrosion deposits on nuclear fuel cladding, known as CRUD, can cause multiple operational problems in light water reactors (LWRs). CRUD can cause accelerated corrosion of the fuel cladding, increase radiation fields and hence greater exposure risk to plant workers once activated, and induce a downward axial power shift causing an imbalance in core power distribution. In order to facilitate a better understanding of CRUD's effects, such as localized high cladding surface temperatures related to accelerated corrosion rates, we describe an improved, fully-coupled, multiphysics model to simulate heat transfer, chemical reactions and transport, and two-phase fluid flow within these deposits. Our new model features a reformed assumption of 2D, two-phase film boiling within the CRUD, correcting earlier models' assumptions of single-phase coolant flow with wick boiling under high heat fluxes. This model helps to better explain observed experimental values of the effective CRUD thermal conductivity. Finally, we propose a more complete set of boiling regimes, or a more detailed mechanism, to explain recent CRUD deposition experiments by suggesting the new concept of double dryout specifically in thick porous media with boiling chimneys.

  4. Two-phase behavior and compression effects in the PEFC gas diffusion medium

    Energy Technology Data Exchange (ETDEWEB)

    Mukherjee, Partha P [Los Alamos National Laboratory; Kang, Qinjun [Los Alamos National Laboratory; Schulz, Volker P [APL-LANDAU GMBH; Wang, Chao - Yang [PENN STATE UNIV; Becker, Jurgen [NON LANL; Wiegmann, Andreas [NON LANL


    A key performance limitation in the polymer electrolyte fuel cell (PEFC), manifested in terms of mass transport loss, originates from liquid water transport and resulting flooding phenomena in the constituent components. A key contributor to the mass transport loss is the cathode gas diffusion layer (GDL) due to the blockage of available pore space by liquid water thus rendering hindered oxygen transport to the active reaction sites in the electrode. The GDL, therefore, plays an important role in the overall water management in the PEFC. The underlying pore-morphology and the wetting characteristics have significant influence on the flooding dynamics in the GDL. Another important factor is the role of cell compression on the GDL microstructural change and hence the underlying two-phase behavior. In this article, we present the development of a pore-scale modeling formalism coupled With realistic microstructural delineation and reduced order compression model to study the structure-wettability influence and the effect of compression on two-phase behavior in the PEFC GDL.

  5. A Lagrangian-Lagrangian Model for Two-Phase Bubbly Flow around Circular Cylinder

    Directory of Open Access Journals (Sweden)

    M. Shademan


    Full Text Available A Lagrangian-Lagrangian model is developed using an in-house code to simulate bubble trajectory in two-phase bubbly flow around circular cylinder. Random Vortex Method (RVM which is a Lagrangian approach is used for solving the liquid phase. The significance of RVM relative to other RANS/LES methods is its capability in directly modelling the turbulence. In RVM, turbulence is modeled by solving the vorticity transport equation and there is no need to use turbulence closure models. Another advantage of RVM relative to other CFD approaches is its independence from mesh generation. For the bubbles trajectory, equation of motion of bubbles which takes into account effect of different forces are coupled with the RVM. Comparison of the results obtained from current model with the experimental data confirms the validity of the model. Effect of different parameters including flow Reynolds number, bubble diameter and injection point on the bubbles' trajectory are investigated. Results show that increase in the Reynolds number reduces the rising velocity of the bubbles. Similar behavior is observed for the bubbles when their diameter was decreased. According to the analysis carried out, present Lagrangian-Lagrangian model solves the issues of mesh generation and turbulence modelling which exist in common two phase flow modelling schemes.

  6. Gradient Augmented Level Set Method for Two Phase Flow Simulations with Phase Change (United States)

    Anumolu, C. R. Lakshman; Trujillo, Mario F.


    A sharp interface capturing approach is presented for two-phase flow simulations with phase change. The Gradient Augmented Levelset method is coupled with the two-phase momentum and energy equations to advect the liquid-gas interface and predict heat transfer with phase change. The Ghost Fluid Method (GFM) is adopted for velocity to discretize the advection and diffusion terms in the interfacial region. Furthermore, the GFM is employed to treat the discontinuity in the stress tensor, velocity, and temperature gradient yielding an accurate treatment in handling jump conditions. Thermal convection and diffusion terms are approximated by explicitly identifying the interface location, resulting in a sharp treatment for the energy solution. This sharp treatment is extended to estimate the interfacial mass transfer rate. At the computational cell, a d-cubic Hermite interpolating polynomial is employed to describe the interface location, which is locally fourth-order accurate. This extent of subgrid level description provides an accurate methodology for treating various interfacial processes with a high degree of sharpness. The ability to predict the interface and temperature evolutions accurately is illustrated by comparing numerical results with existing 1D to 3D analytical solutions.

  7. Analysis of a combined mixed finite element and discontinuous Galerkin method for incompressible two-phase flow in porous media

    KAUST Repository

    Kou, Jisheng


    We analyze a combined method consisting of the mixed finite element method for pressure equation and the discontinuous Galerkin method for saturation equation for the coupled system of incompressible two-phase flow in porous media. The existence and uniqueness of numerical solutions are established under proper conditions by using a constructive approach. Optimal error estimates in L2(H1) for saturation and in L∞(H(div)) for velocity are derived. Copyright © 2013 John Wiley & Sons, Ltd.

  8. The continuum modelling of two-phase flow systems

    Energy Technology Data Exchange (ETDEWEB)

    Lahey, R.T. Jr.; Drew, D.A.


    This research program is concerned with the development of self-consistent multidimensional two-fluid models which predict a wide variety of data and satisfy all relevant physical laws and constraints. If successful, these models can revolutionize the way in which two-phase lows are analyzed, since mechanistic, rather than empirical-based predictions should be possible. During this report period the research has focused on understanding the relationships between the interfacial closure laws and the onset of ill-posedness. In particular, it is now known that only the void wave eigenvalues can become complex, thus leading to ill-posedness. As a consequence, a detailed set of void wave data were taken and these data were compared with the two-fluid model we have developed. The kinematic void wave data was well predicted, and, in addition, a much faster void wave was also measured. The faster void wave was associated with bubble clusters which were observed to form due to hydrodynamic effects. Significantly, these clusters were found to be the precursors of Taylor bubble formation (i.e., the bubbly-to-slug flow regime transition). Moreover, it was found that for certain conditions, these void waves were amplified, thus triggering flow regime transition. 2 refs.

  9. Passive Two-Phase Cooling of Automotive Power Electronics: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Moreno, G.; Jeffers, J. R.; Narumanchi, S.; Bennion, K.


    Experiments were conducted to evaluate the use of a passive two-phase cooling strategy as a means of cooling automotive power electronics. The proposed cooling approach utilizes an indirect cooling configuration to alleviate some reliability concerns and to allow the use of conventional power modules. An inverter-scale proof-of-concept cooling system was fabricated, and tests were conducted using the refrigerants hydrofluoroolefin HFO-1234yf and hydrofluorocarbon HFC-245fa. Results demonstrated that the system can dissipate at least 3.5 kW of heat with 250 cm3 of HFC-245fa. An advanced evaporator design that incorporates features to improve performance and reduce size was conceived. Simulation results indicate its thermal resistance can be 37% to 48% lower than automotive dual side cooled power modules. Tests were also conducted to measure the thermal performance of two air-cooled condensers--plain and rifled finned tube designs. The results combined with some analysis were then used to estimate the required condenser size per operating conditions and maximum allowable system (i.e., vapor and liquid) temperatures.

  10. Dielectric barrier discharge in a two-phase mixture

    Energy Technology Data Exchange (ETDEWEB)

    Ye Qizheng; Zhang Ting; Lu Fei; Li Jin; He Zhenghao; Lin Fuchang [College of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China)


    This paper reports the experimental investigation of the dielectric barrier discharge in which the gap area is filled with a two-phase mixture (TPM), air and solid particles. We found that there are two kinds of discharges in the TPM. One is the surface discharge generated on the surface of the solid particles and the other is the filament discharge generated in the air void. For the case of low volume fraction of solid particles, the surface discharge starts to occur when the applied voltage is higher than the onset voltage. At a further voltage increase, the filament discharge takes place at the same time. For the case of high volume fraction, such as the packed-bed reactor, only the surface discharge exists. Under the condition of the same volume fraction, the larger the diameter of the solid particles, the lower the surface discharge onset voltage. As a conclusion, we think that the plasma reactor using the form of low volume fraction of solid particles may be a better choice for waste-gas treatment enhanced by catalysts.


    Directory of Open Access Journals (Sweden)



    Full Text Available The CUPID code has been developed at KAERI for a transient, three-dimensional analysis of a two-phase flow in light water nuclear reactor components. It can provide both a component-scale and a CFD-scale simulation by using a porous media or an open media model for a two-phase flow. In this paper, recent advances in the CUPID code are presented in three sections. First, the domain decomposition parallel method implemented in the CUPID code is described with the parallel efficiency test for multiple processors. Then, the coupling of CUPID-MARS via heat structure is introduced, where CUPID has been coupled with a system-scale thermal-hydraulics code, MARS, through the heat structure. The coupled code has been applied to a multi-scale thermal-hydraulic analysis of a pool mixing test. Finally, CUPID-SG is developed for analyzing two-phase flows in PWR steam generators. Physical models and validation results of CUPID-SG are discussed.

  12. An evaluation of cis- and trans-retinol contents in juices using dispersive liquid-liquid microextraction coupled to liquid chromatography with fluorimetric detection. (United States)

    Viñas, Pilar; Bravo-Bravo, María; López-García, Ignacio; Hernández-Córdoba, Manuel


    This study describes a method for coupling dispersive liquid-liquid microextraction (DLLME) and normal-phase liquid chromatography (NP-LC) with fluorescence detection for vitamin A determination with the view to developing a new green sample preparation technique. Parameters affecting DLLME, including the nature and volume of both extractant and disperser solvents, salt addition and time and speed of the centrifugation step, were optimized. The sample was saponified according to European Standards to convert all forms of vitamin A to retinol. For microextraction, 8 mL water were placed in a glass tube with conical bottom and the saponified sample consisting of 2 mL of the methanolic extract containing 100 μL tetrachloroethane was rapidly injected by syringe, thereby forming a cloudy solution. Phase separation was performed by centrifugation, and a volume of 20 μL of the sedimented phase was analyzed by NP-LC. The enrichment factor, calculated as the ratio between the slopes of DLLME-LC and direct LC, was 50 ± 3. The matrix effect was evaluated for different juice samples, and it was concluded that sample quantification can be carried out by aqueous calibration when the standards are also submitted to saponification. The proposed method was applied for determining both cis- and trans-retinol isomers in commercial juices of different types. The intraday and interday precisions were lower than 6% in terms of relative standard deviation. The method was validated using two certified reference materials. Copyright © 2012 Elsevier B.V. All rights reserved.

  13. Time dependent two phase flows in Magnetohydrodynamics: A ...

    African Journals Online (AJOL)

    The two regions are coupled by equating the velocity and shear stress at the interface. Using the Green\\'s function approach, expressions for velocity in both phases were obtained for general class of time dependent movement of boundary or sudden change in pressure gradient or both. As a special case, expressions for ...

  14. Rapid RNA Exchange in Aqueous Two-Phase System and Coacervate Droplets (United States)

    Jia, Tony Z.; Hentrich, Christian; Szostak, Jack W.


    Compartmentalization in a prebiotic setting is an important aspect of early cell formation and is crucial for the development of an artificial protocell system that effectively couples genotype and phenotype. Aqueous two-phase systems (ATPSs) and complex coacervates are phase separation phenomena that lead to the selective partitioning of biomolecules and have recently been proposed as membrane-free protocell models. We show in this study through fluorescence recovery after photobleaching (FRAP) microscopy that despite the ability of such systems to effectively concentrate RNA, there is a high rate of RNA exchange between phases in dextran/polyethylene glycol ATPS and ATP/poly-L-lysine coacervate droplets. In contrast to fatty acid vesicles, these systems would not allow effective segregation and consequent evolution of RNA, thus rendering these systems ineffective as model protocells.

  15. Degassing and two-phase flow pilot hole test report

    Energy Technology Data Exchange (ETDEWEB)

    Geller, J.T. [Lawrence Berkeley Lab., CA (United States); Jarsjoe, J. [Royal Institute of Technology, Stockholm (Sweden). Water Resource Engineering


    A pilot hole test was conducted to support the design of the Degassing of Groundwater and Two-Phase Flow experiments planned for the Hard Rock Laboratory, Aespoe, Sweden. The test consisted of a sequence of constant pressure borehole inflow tests (CPTs) and pressure recovery tests (PRTs) in borehole KA2512A. The test sequence was designed to detect degassing effects from the change in transmissivity, or hydraulic conductivity, and storativity when the borehole pressure is lowered below the groundwater bubble pressure. The entire 37.3m of the borehole section was tested without packers. Flow response to pressure changes in CPTs occurred rapidly. Flowrates fluctuated before attaining a steady trend, probably due to effective stress changes when borehole pressure was reduced for the first time. These factors decreased the sensitivity of type-curve fits to values of specific storage. The relationship between borehole pressure and steady-state flowrates was linear over borehole pressures of 1500 kPa (abs) down to 120 kPa (abs) during testing in December 1994, indicating that processes that may change hydraulic conductivity at low borehole pressures, such as degassing, calcite precipitation or turbulence, did not occur to a measurable degree. Test results during January and February of 1995 suggest that degassing may have occurred. The hydraulic conductivity measured at a borehole pressure equal to 120 kPa (abs) was 20% lower than the hydraulic conductivity measured at a borehole pressure of 1500 kPa (abs); the latter value was 10% lower than the hydraulic conductivity measured in December, 1994. The volumetric gas content measured during this time was 1% v/v. Pressures in monitoring well KA2511A responded to the testing in KA2512A. Step-changes in flowrates coincided with blasting at 3300-3400 m tunnel length. The magnitude of these changes was greater at the lower borehole pressures. Step increases in pressures in KA2511A also coincided with the blasts.

  16. Nuclear magnetic relaxation induced by exchange-mediated orientational randomization: Longitudinal relaxation dispersion for a dipole-coupled spin-1/2 pair (United States)

    Chang, Zhiwei; Halle, Bertil


    In complex biological or colloidal samples, magnetic relaxation dispersion (MRD) experiments using the field-cycling technique can characterize molecular motions on time scales ranging from nanoseconds to microseconds, provided that a rigorous theory of nuclear spin relaxation is available. In gels, cross-linked proteins, and biological tissues, where an immobilized macromolecular component coexists with a mobile solvent phase, nuclear spins residing in solvent (or cosolvent) species relax predominantly via exchange-mediated orientational randomization (EMOR) of anisotropic nuclear (electric quadrupole or magnetic dipole) couplings. The physical or chemical exchange processes that dominate the MRD typically occur on a time scale of microseconds or longer, where the conventional perturbation theory of spin relaxation breaks down. There is thus a need for a more general relaxation theory. Such a theory, based on the stochastic Liouville equation (SLE) for the EMOR mechanism, is available for a single quadrupolar spin I = 1. Here, we present the corresponding theory for a dipole-coupled spin-1/2 pair. To our knowledge, this is the first treatment of dipolar MRD outside the motional-narrowing regime. Based on an analytical solution of the spatial part of the SLE, we show how the integral longitudinal relaxation rate can be computed efficiently. Both like and unlike spins, with selective or non-selective excitation, are treated. For the experimentally important dilute regime, where only a small fraction of the spin pairs are immobilized, we obtain simple analytical expressions for the auto-relaxation and cross-relaxation rates which generalize the well-known Solomon equations. These generalized results will be useful in biophysical studies, e.g., of intermittent protein dynamics. In addition, they represent a first step towards a rigorous theory of water 1H relaxation in biological tissues, which is a prerequisite for unravelling the molecular basis of soft

  17. Gas segregation and two-phase flow in basaltic explosive activity (United States)

    Pioli, L.; Cashman, K.; Wallace, P.


    instability during transitions and in churn flow. Sustained flow, in turn, occurs when the flow regime has a regular geometry, such as in annular and homogenous bubbly flow. Using theoretical and experimental models, we explore the possible two-phase flow patterns (bubbly, slug, churn, annular and dispersed) that can develop in vertical conduits for different liquid and gas fluxes (Taitel et al., 1980; McQuillan and Whalley 1986; Lucas et al., 2005). We then discuss their expected stability in magmatic systems and their potential effects on the explosive eruption dynamics. Finally, we compare the theoretical results with natural examples.

  18. Studies of efficiency in a perforated rotating disc contactor using a polymer-polymer aqueous two-phase systems

    Directory of Open Access Journals (Sweden)

    L. A. Sarubbo


    Full Text Available The mass transfer process in a perforated rotating disc contactor (PRDC using a polymer-polymer aqueous two-phase system was investigated. The results show that the efficiency did not show a regular trend with the increase of the dispersed phase velocity and increased with the rotation velocity. The separation efficiency was higher for three rotating discs than for four discs. The increase in tie-line length decreased the efficiency. The separation efficiency reached high values, about 96% under conditions studied in this work.

  19. Preconcentration of uranium in water samples using dispersive liquid-liquid micro- extraction coupled with solid-phase extraction and determination with inductively coupled plasma-optical emission spectrometry

    Directory of Open Access Journals (Sweden)

    M. Rezaee,


    Full Text Available A new liquid phase microextraction method based on the dispersion of an extraction solvent into aqueous phase coupled with solid-phase extraction was investigated for the extraction, preconcentration and determination of uranium in water samples. 1-(2-Pyridylazo-2-naphthol reagent (PAN at pH 6.0 was used as a chelating agent prior to extraction. After concentration and purification of the samples in SPE C18 sorbent, 1.5 mL elution sample containing 40.0 µL chlorobenzene was injected into the 5.0 mL pure water. After extraction and centrifuging, the sedimented phase was evaporated and the residue was dissolved in nitric acid (0.5 M and was injected by injection valve into the ICP-OES. Some important extraction parameters, such as sample solution flow rate, sample pH, type and volume of extraction and disperser solvents as well as the salt addition were studied and optimized. Under the optimum conditions, the calibration graph was linear in the range of 0.5-500 µg L-1. The detection limit was 0.1 µg L-1. The relative standard deviation (RSD at 5.0 µg L-1 concentration level was 6.6%. Finally, the developed method was successfully applied to the extraction and determination of uranium in the well, river, mineral, waste and tap water samples and satisfactory results were obtained.DOI:

  20. A new method for polychromatic X-ray μLaue diffraction on a Cu pillar using an energy-dispersive pn-junction charge-coupled device. (United States)

    Abboud, A; Kirchlechner, C; Send, S; Micha, J S; Ulrich, O; Pashniak, N; Strüder, L; Keckes, J; Pietsch, U


    μLaue diffraction with a polychromatic X-ray beam can be used to measure strain fields and crystal orientations of micro crystals. The hydrostatic strain tensor can be obtained once the energy profile of the reflections is measured. However, this remains a challenge both on the time scale and reproducibility of the beam position on the sample. In this review, we present a new approach to obtain the spatial and energy profiles of Laue spots by using a pn-junction charge-coupled device, an energy-dispersive area detector providing 3D resolution of incident X-rays. The morphology and energetic structure of various Bragg peaks from a single crystalline Cu micro-cantilever used as a test system were simultaneously acquired. The method facilitates the determination of the Laue spots' energy spectra without filtering the white X-ray beam. The synchrotron experiment was performed at the BM32 beamline of ESRF using polychromatic X-rays in the energy range between 5 and 25 keV and a beam size of 0.5 μm × 0.5 μm. The feasibility test on the well known system demonstrates the capabilities of the approach and introduces the "3D detector method" as a promising tool for material investigations to separate bending and strain for technical materials.

  1. Chemometric classification of gunshot residues based on energy dispersive X-ray microanalysis and inductively coupled plasma analysis with mass-spectrometric detection (United States)

    Steffen, S.; Otto, M.; Niewoehner, L.; Barth, M.; Bro¿żek-Mucha, Z.; Biegstraaten, J.; Horváth, R.


    A gunshot residue sample that was collected from an object or a suspected person is automatically searched for gunshot residue relevant particles. Particle data (such as size, morphology, position on the sample for manual relocation, etc.) as well as the corresponding X-ray spectra and images are stored. According to these data, particles are classified by the analysis-software into different groups: 'gunshot residue characteristic', 'consistent with gunshot residue' and environmental particles, respectively. Potential gunshot residue particles are manually checked and - if necessary - confirmed by the operating forensic scientist. As there are continuing developments on the ammunition market worldwide, it becomes more and more difficult to assign a detected particle to a particular ammunition brand. As well, the differentiation towards environmental particles similar to gunshot residue is getting more complex. To keep external conditions unchanged, gunshot residue particles were collected using a specially designed shooting device for the test shots revealing defined shooting distances between the weapon's muzzle and the target. The data obtained as X-ray spectra of a number of particles (3000 per ammunition brand) were reduced by Fast Fourier Transformation and subjected to a chemometric evaluation by means of regularized discriminant analysis. In addition to the scanning electron microscopy in combination with energy dispersive X-ray microanalysis results, isotope ratio measurements based on inductively coupled plasma analysis with mass-spectrometric detection were carried out to provide a supplementary feature for an even lower risk of misclassification.

  2. Chemometric classification of gunshot residues based on energy dispersive X-ray microanalysis and inductively coupled plasma analysis with mass-spectrometric detection

    Energy Technology Data Exchange (ETDEWEB)

    Steffen, S. [Bundeskriminalamt (BKA), Forensic Science Institute KT23, Thaerstr. 11, D - 65193 Wiesbaden (Germany); Otto, M. [TU Bergakademie Freiberg (TU BAF), Institute for Analytical Chemistry, Leipziger Str. 29, D - 09599 Freiberg (Germany)], E-mail:; Niewoehner, L.; Barth, M. [Bundeskriminalamt (BKA), Forensic Science Institute KT23, Thaerstr. 11, D - 65193 Wiesbaden (Germany); Brozek-Mucha, Z. [Instytut Ekspertyz Sadowych (IES), Westerplatte St. 9, PL - 31-033 Krakow (Poland); Biegstraaten, J. [Nederlands Forensisch Instituut (NFI), Fysische Technologie, Laan van Ypenburg 6, NL-2497 GB Den Haag (Netherlands); Horvath, R. [Kriminalisticky a Expertizny Ustav (KEU PZ), Institute of Forensic Science, Sklabinska 1, SK - 812 72 Bratislava (Slovakia)


    A gunshot residue sample that was collected from an object or a suspected person is automatically searched for gunshot residue relevant particles. Particle data (such as size, morphology, position on the sample for manual relocation, etc.) as well as the corresponding X-ray spectra and images are stored. According to these data, particles are classified by the analysis-software into different groups: 'gunshot residue characteristic', 'consistent with gunshot residue' and environmental particles, respectively. Potential gunshot residue particles are manually checked and - if necessary - confirmed by the operating forensic scientist. As there are continuing developments on the ammunition market worldwide, it becomes more and more difficult to assign a detected particle to a particular ammunition brand. As well, the differentiation towards environmental particles similar to gunshot residue is getting more complex. To keep external conditions unchanged, gunshot residue particles were collected using a specially designed shooting device for the test shots revealing defined shooting distances between the weapon's muzzle and the target. The data obtained as X-ray spectra of a number of particles (3000 per ammunition brand) were reduced by Fast Fourier Transformation and subjected to a chemometric evaluation by means of regularized discriminant analysis. In addition to the scanning electron microscopy in combination with energy dispersive X-ray microanalysis results, isotope ratio measurements based on inductively coupled plasma analysis with mass-spectrometric detection were carried out to provide a supplementary feature for an even lower risk of misclassification.

  3. A new method for polychromatic X-ray μLaue diffraction on a Cu pillar using an energy-dispersive pn-junction charge-coupled device (United States)

    Abboud, A.; Kirchlechner, C.; Send, S.; Micha, J. S.; Ulrich, O.; Pashniak, N.; Strüder, L.; Keckes, J.; Pietsch, U.


    μLaue diffraction with a polychromatic X-ray beam can be used to measure strain fields and crystal orientations of micro crystals. The hydrostatic strain tensor can be obtained once the energy profile of the reflections is measured. However, this remains a challenge both on the time scale and reproducibility of the beam position on the sample. In this review, we present a new approach to obtain the spatial and energy profiles of Laue spots by using a pn-junction charge-coupled device, an energy-dispersive area detector providing 3D resolution of incident X-rays. The morphology and energetic structure of various Bragg peaks from a single crystalline Cu micro-cantilever used as a test system were simultaneously acquired. The method facilitates the determination of the Laue spots' energy spectra without filtering the white X-ray beam. The synchrotron experiment was performed at the BM32 beamline of ESRF using polychromatic X-rays in the energy range between 5 and 25 keV and a beam size of 0.5 μm × 0.5 μm. The feasibility test on the well known system demonstrates the capabilities of the approach and introduces the "3D detector method" as a promising tool for material investigations to separate bending and strain for technical materials.

  4. 48 CFR 570.305 - Two-phase design-build selection procedures. (United States)


    ... 48 Federal Acquisition Regulations System 4 2010-10-01 2010-10-01 false Two-phase design-build... for Leasehold Interests in Real Property 570.305 Two-phase design-build selection procedures. (a) These procedures apply to acquisitions of leasehold interests if you use the two-phase design-build...

  5. Characterization of two-phase flow regimes in horizontal tubes using {sup 81m}Kr tracer experiments

    Energy Technology Data Exchange (ETDEWEB)

    Oriol, Jean [LPAC, CEA Grenoble, 17, rue des Martyrs, 38054 Grenoble Cedex 9 (France); Leclerc, Jean Pierre [Laboratoire des Sciences du Genie Chimique (LSGC), Nancy-Universite, CNRS, BP 20451, F-54001 Nancy (France)], E-mail:; Berne, Philippe; Gousseau, Georges [L2T, CEA Grenoble, 17, rue des Martyrs, 38054 Grenoble Cedex 9 (France); Jallut, Christian [Universite de Lyon, Universite Lyon 1, LAGEP, UMR CNRS 5007, ESCPE, 43 Bd du 11 novembre 1918, 69622 Villeurbanne Cedex (France); Tochon, Patrice; Clement, Patrice [GRETh, CEA Grenoble, 17, rue des Martyrs, 38054 Grenoble Cedex 9 (France)


    The diagnosis of heat exchangers on duty with respect to flow mal-distributions needs the development of non-intrusive inlet-outlet experimental techniques in order to perform an online fault diagnosis. Tracer experiments are an example of such techniques. They can be applied to mono-phase heat exchangers but also to multi-phase ones. In this case, the tracer experiments are more difficult to perform. In order to check for the capabilities of tracer experiments to be used for the flow mal-distribution diagnosis in the case of multi-phase heat exchangers, we present here a preliminary study on the simplest possible system: two-phase flows in a horizontal tube. {sup 81m}Kr is used as gas tracer and properly collimated NaI (TI) crystal scintillators as detectors. The specific shape of the tracer response allows two-phase flow regimes to be characterized. Signal analysis allows the estimation of the gas phase real average velocity and consequently of the liquid phase real average velocity as well as of the volumetric void fraction. These results are compared successfully to those obtained with liquid phase tracer experiments previously presented by Oriol et al. 2007. Characterization of the two-phase flow regimes and liquid dispersion in horizontal and vertical tubes using coloured tracer and no intrusive optical detector. Chem. Eng. Sci. 63(1), 24-34, as well as to those given by correlations from literature.

  6. Characterization of two-phase flow regimes in horizontal tubes using 81mKr tracer experiments. (United States)

    Oriol, Jean; Leclerc, Jean Pierre; Berne, Philippe; Gousseau, Georges; Jallut, Christian; Tochon, Patrice; Clement, Patrice


    The diagnosis of heat exchangers on duty with respect to flow mal-distributions needs the development of non-intrusive inlet-outlet experimental techniques in order to perform an online fault diagnosis. Tracer experiments are an example of such techniques. They can be applied to mono-phase heat exchangers but also to multi-phase ones. In this case, the tracer experiments are more difficult to perform. In order to check for the capabilities of tracer experiments to be used for the flow mal-distribution diagnosis in the case of multi-phase heat exchangers, we present here a preliminary study on the simplest possible system: two-phase flows in a horizontal tube. (81m)Kr is used as gas tracer and properly collimated NaI (TI) crystal scintillators as detectors. The specific shape of the tracer response allows two-phase flow regimes to be characterized. Signal analysis allows the estimation of the gas phase real average velocity and consequently of the liquid phase real average velocity as well as of the volumetric void fraction. These results are compared successfully to those obtained with liquid phase tracer experiments previously presented by Oriol et al. 2007. Characterization of the two-phase flow regimes and liquid dispersion in horizontal and vertical tubes using coloured tracer and no intrusive optical detector. Chem. Eng. Sci. 63(1), 24-34, as well as to those given by correlations from literature.

  7. Numerical simulation of evaporating two-phase flow: application to concentrated solar plants with direct steam generation

    Directory of Open Access Journals (Sweden)

    Dinsenmeyer Rémi


    Full Text Available Numerical simulations using CFD are conducted on a boiling two-phase flow in order to study the changes in flow patterns during evaporation. A model for heat and mass transfer at the tube inner wall and at the liquid-gas interface is presented. Transport of two custom scalars is solved: one stands for the enthalpy fields in the flow, the other represents a new dispersed vapor phase in the liquid. A correlation is used to model heat and mass transfer at the tube inner wall. The dispersed phase is created at the surface in the liquid and flows up to the liquid-vapor interface. There, it is transformed into actual vapor phase. The multiphase VOF model is validated for the creation of slugs in an horizontal tube for an adiabatic flow. Results are presented for a subcooled boiling flow in a bend.

  8. Study of sustainable production in two-phase liquid dominated with steam cap underlying brine reservoir by numerical simulation (United States)

    Pratama, Heru Berian; Miryani Saptadji, Nenny


    The main issue in the management of the two-phase liquid-dominated geothermal field is rapid decline pressure in the reservoir so that the supply of steam to the power plant cannot be fulfilled. To understanding that, modelling and numerical simulation used reservoir simulators. The model is developed on liquid-dominated geothermal fields are assessed in various scenarios of production strategies (focusing only steam cap, brine reservoir and a combination) and injection strategies (deep and shallow injection, centered and dispersed injection), with the calculation using separated steam cycle method. The simulation results of the model for sustainable production are production 25% from steam cap + 75% from brine reservoir, dispersed and deep reinjection with make-up wells from steam cap results 9 make-up well number. The implementation of production-injection strategy needs to be planned right from the beginning of exploitation so that the strategy can adapt to changes in reservoir characteristics.

  9. Simultaneous speciation of inorganic arsenic, selenium and tellurium in environmental water samples by dispersive liquid liquid microextraction combined with electrothermal vaporization inductively coupled plasma mass spectrometry. (United States)

    Liu, Ying; He, Man; Chen, Beibei; Hu, Bin


    A new method based on dispersive liquid liquid microextraction (DLLME) combined with electrothermal vaporization inductively coupled plasma mass spectrometry (ETV-ICP-MS) was developed for the simultaneous speciation of inorganic arsenic (As), selenium (Se) and tellurium (Te) with sodium diethyldithiocarbamate (DDTC) as both chelating reagent and chemical modifier. As(III), Se(IV) and Te(IV) were transformed into DDTC-chelates at pH 7 and extracted into the fine droplets formed by injecting the binary solution of bromobenzene (extraction solvent) and methanol (dispersive solvent) into the sample solution. After phase separation by centrifugation, As(III), Se(IV) and Te(IV) preconcentrated in the organic phase were determined by ETV-ICP-MS. Total inorganic As, Se and Te were obtained by reducing As(V), Se(VI) and Te(VI) to As(III), Se(IV) and Te(IV) with L-cysteine, which were then subjected to the same DLLME-ETV-ICP-MS process. The concentration of As(V), Se(VI), Te(VI) were calculated by subtracting the concentration of As(III), Se(IV) and Te(IV) from the total inorganic As, Se and Te, respectively. The main factors affecting the microextraction efficiency and the vaporization behavior of target species were investigated in detail. Under the optimal conditions, the limits of detection were 2.5, 8.6 and 0.56 ng L(-1) for As(III), Se(IV) and Te(IV), respectively, with the relative standard deviations (n=7) of 8.5-9.7%. The developed method was applied to the speciation of inorganic As, Se and Te in Certified Reference Materials of GSBZ50004-88, GBW(E)080395 and GBW(E)080548 environmental waters, and the determined values are in good agreement with the certified values. The method was also successfully applied to the simultaneous speciation of inorganic As, Se and Te in different environmental water samples with the recoveries in the range of 86.3-107% for the spiked samples. Copyright © 2015 Elsevier B.V. All rights reserved.

  10. Optimization and modeling of preconcentration and determination of dyes based on ultrasound assisted-dispersive liquid-liquid microextraction coupled with derivative spectrophotometry. (United States)

    Alipanahpour Dil, Ebrahim; Ghaedi, Mehrorang; Asfaram, Arash


    Present study is based on describing an ultrasound-assisted dispersive liquid-liquid microextraction coupled with derivative spectrophotometry (UAS-DLLME-UV-vis) as useful technique for selective determination of crystal violet (CV) and azure b (Az-B). The significant factors like pH, extractor volume, disperser value and extraction time contribution and their numerical coefficient in quadratic model were calculated according to central composite design (CCD). According to desirability function (DF) as good criterion the best experimental conditions was adjusted and selected at pH of 7.0, 170μL of chloroform, 800μL of ethanol that strongly mixed with the aqueous phase via 4min sonication. Additionally, under study system was modeled by trained artificial neural networks (ANNs) as fitness function with acceptable error of MSE 2.97×10 -06 and 1.15×10 -05 with R 2 : 0.9999 and 0.9997 for CV and Az-B, respectively. The optimum conditions by using genetic algorithm (GA) method was pH of 6.3, 160μL of chloroform, 740μL of ethanol and 4.5min sonication. Under above specified and optimize conditions, the predicted extraction percentage were 99.80 and 102.20% for CV and Az-B, respectively. The present UAS-DLLME-UV-vis procedure has minimum interference from other substances assign to the matrix, which candidate this method as good alternative to quantify under study dyes content with recoveries in the range of 86-100% for dyes. The detection limits were 2.043ngmL -1 and 1.72ngmL -1 , and limits of quantitation were 6.81ngmL -1 and 5.727ngmL -1 for CV and Az-B, respectively. The proposed methodology was successfully applied for quantification of under study analytes at different media. Copyright © 2016 Elsevier B.V. All rights reserved.

  11. Continued development of a semianalytical solution for two-phase fluid and heat flow in a porous medium

    Energy Technology Data Exchange (ETDEWEB)

    Doughty, C.; Pruess, K. [Lawrence Berkeley Lab., CA (United States)


    Over the past few years the authors have developed a semianalytical solution for transient two-phase water, air, and heat flow in a porous medium surrounding a constant-strength linear heat source, using a similarity variable {eta} = r/{radical}t. Although the similarity transformation approach requires a simplified geometry, all the complex physical mechanisms involved in coupled two-phase fluid and heat flow can be taken into account in a rigorous way, so that the solution may be applied to a variety of problems of current interest. The work was motivated by adverse to predict the thermohydrological response to the proposed geologic repository for heat-generating high-level nuclear wastes at Yucca Mountain, Nevada, in a partially saturated, highly fractured volcanic formation. The paper describes thermal and hydrologic conditions near the heat source; new features of the model; vapor pressure lowering; and the effective-continuum representation of a fractured/porous medium.

  12. Turbulence-induced bubble collision force modeling and validation in adiabatic two-phase flow using CFD

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Subash L., E-mail: [School of Nuclear Engineering, Purdue University, West Lafayette, IN 47907-1290 (United States); Hibiki, Takashi; Ishii, Mamoru [School of Nuclear Engineering, Purdue University, West Lafayette, IN 47907-1290 (United States); Brooks, Caleb S. [Department of Nuclear, Plasma, and Radiological Engineering, University of Illinois, Urbana, IL 61801 (United States); Schlegel, Joshua P. [Nuclear Engineering Program, Missouri University of Science and Technology, Rolla, MO 65409 (United States); Liu, Yang [Nuclear Engineering Program, Department of Mechanical Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061 (United States); Buchanan, John R. [Bechtel Marine Propulsion Corporation, Bettis Laboratory, West Mifflin, PA 15122 (United States)


    Highlights: • Void distribution in narrow rectangular channel with various non-uniform inlet conditions. • Modeling of void diffusion due to bubble collision force. • Validation of new modeling in adiabatic air–water two-phase flow in a narrow channel. - Abstract: The prediction capability of the two-fluid model for gas–liquid dispersed two-phase flow depends on the accuracy of the closure relations for the interfacial forces. In previous studies of two-phase flow Computational Fluid Dynamics (CFD), interfacial force models for a single isolated bubble has been extended to disperse two-phase flow assuming the effect in a swarm of bubbles is similar. Limited studies have been performed investigating the effect of the bubble concentration on the lateral phase distribution. Bubbles, while moving through the liquid phase, may undergo turbulence-driven random collision with neighboring bubbles without significant coalescence. The rate of these collisions depends upon the bubble approach velocity and bubble spacing. The bubble collision frequency is expected to be higher in locations with higher bubble concentrations, i.e., volume fraction. This turbulence-driven random collision causes the diffusion of the bubbles from high concentration to low concentration. Based on experimental observations, a phenomenological model has been developed for a “turbulence-induced bubble collision force” for use in the two-fluid model. For testing the validity of the model, two-phase flow data measured at Purdue University are utilized. The geometry is a 10 mm × 200 mm cross section channel. Experimentally, non-uniform inlet boundary conditions are applied with different sparger combinations to vary the volume fraction distribution across the wider dimension. Examining uniform and non-uniform inlet data allows for the influence of the volume fraction to be studied as a separate effect. The turbulence-induced bubble collision force has been implemented in ANSYS CFX. The

  13. Ultrasound-Assisted Aqueous Two-Phase System for Extraction and Enrichment of Zanthoxylum armatum Lignans

    Directory of Open Access Journals (Sweden)

    Tao Guo


    Full Text Available In the study, an aqueous two phase system (ATPS coupled with ultrasound was employed to extract lignans from Zanthoxylum armatum. Three standard lignans, namely (−-fargesin, sesamin and L-asarinin, were used as marker compounds, and extraction was optimized and projected by response surface methodology (RSM and artificial neural network (ANN. The optimal condition for ATPS with 20% n-propanol and 24% (NH42SO4 coupled with ultrasonic-assisted extraction including a solvent to solid ratio of 15:1, a temperature of 40 °C, and a treatment time of 55 min was obtained. Under the condition, the yield of (−-fargesin increased 15.12%, and the purities of (−-fargesin, sesamin and L-asarinin reached 2.222%, 1.066%, and 1.583%, with an increase of 44.38%, 25.70%, and 26.34% compared to those extracted with 95% ethanol, respectively. Coefficient of the determined (0.9855 and mean squared error (0.0018 of ANN model suggested good fitness and generalization of the ANN. Taken together, the results showed that ultrasonic-assisted ATPS can be a suitable method for extraction and enrichment of lignans from Z. armatum.

  14. Ultrasound-Assisted Aqueous Two-Phase System for Extraction and Enrichment of Zanthoxylum armatum Lignans. (United States)

    Guo, Tao; Su, Dan; Huang, Yan; Wang, Ya; Li, Yong-Hui


    In the study, an aqueous two phase system (ATPS) coupled with ultrasound was employed to extract lignans from Zanthoxylum armatum. Three standard lignans, namely (-)-fargesin, sesamin and L-asarinin, were used as marker compounds, and extraction was optimized and projected by response surface methodology (RSM) and artificial neural network (ANN). The optimal condition for ATPS with 20% n-propanol and 24% (NH4)2SO4 coupled with ultrasonic-assisted extraction including a solvent to solid ratio of 15:1, a temperature of 40 °C, and a treatment time of 55 min was obtained. Under the condition, the yield of (-)-fargesin increased 15.12%, and the purities of (-)-fargesin, sesamin and L-asarinin reached 2.222%, 1.066%, and 1.583%, with an increase of 44.38%, 25.70%, and 26.34% compared to those extracted with 95% ethanol, respectively. Coefficient of the determined (0.9855) and mean squared error (0.0018) of ANN model suggested good fitness and generalization of the ANN. Taken together, the results showed that ultrasonic-assisted ATPS can be a suitable method for extraction and enrichment of lignans from Z. armatum.

  15. Dynamics of explosive degassing of magma: Observations of fragmenting two-phase flows (United States)

    Mader, H. M.; Phillips, J. C.; Sparks, R. S. J.; Sturtevant, B.


    Liquid explosions, generated by rapid degassing of strongly supersaturated liquids, have been investigated in the laboratory with a view to understanding the basic physical processes operating during bubble nucleation and growth and the subsequent behavior of the expanding two-phase flow. Experiments are carried out in a shock tube and are monitored by high-speed photography and pressure transducers. Theoretical CO2 supersaturations up to 455 times the ambient saturation concentration are generated by a chemical reaction; K2CO3 solution is suddenly injected into an excess of HCl solution in such a way as to mix the two solutions rapidly. Immediately after the injection event, a bubble nucleation delay of a few milliseconds is followed by rapid nucleation and explosive expansion of CO2 bubbles forming a highly heterogeneous foam. Enhanced diffusion due to advection in the flow coupled with continuous mixing of the reactants, and hence on-going bubble nucleation after injection, generates an increasingly accelerating flow until the reactants become depleted at peak accelerations of around 150 g and velocities of about 15 ms-1. Stretching of the accelerating two-phase mixture enhances the mixing. Liberation of CO2 vapor is spatially inhomogeneous leading to ductile fragmentation occurring throughout the flow in regions of greatest gas release as the consequence of the collision and stretching of fluid streams. The violence of the eruptions is controlled by using different concentrations of the HCl and K2CO3 solutions, which alters the CO2 supersaturation and yield and also the efficiency of the mixing process. Peak acceleration is proportional to theoretical supersaturation. Pressure measurements at the base of the shock tube show an initial nucleation delay and a pressure pulse related to the onset of explosive bubble formation. These chemically induced explosions differ from liquid explosions created in other experiments. In explosions caused by sudden

  16. Meso-Scale Modeling of Spall in a Heterogeneous Two-Phase Material

    Energy Technology Data Exchange (ETDEWEB)

    Springer, Harry Keo [Univ. of California, Davis, CA (United States)


    The influence of the heterogeneous second-phase particle structure and applied loading conditions on the ductile spall response of a model two-phase material was investigated. Quantitative metallography, three-dimensional (3D) meso-scale simulations (MSS), and small-scale spall experiments provided the foundation for this study. Nodular ductile iron (NDI) was selected as the model two-phase material for this study because it contains a large and readily identifiable second- phase particle population. Second-phase particles serve as the primary void nucleation sites in NDI and are, therefore, central to its ductile spall response. A mathematical model was developed for the NDI second-phase volume fraction that accounted for the non-uniform particle size and spacing distributions within the framework of a length-scale dependent Gaussian probability distribution function (PDF). This model was based on novel multiscale sampling measurements. A methodology was also developed for the computer generation of representative particle structures based on their mathematical description, enabling 3D MSS. MSS were used to investigate the effects of second-phase particle volume fraction and particle size, loading conditions, and physical domain size of simulation on the ductile spall response of a model two-phase material. MSS results reinforce existing model predictions, where the spall strength metric (SSM) logarithmically decreases with increasing particle volume fraction. While SSM predictions are nearly independent of applied load conditions at lower loading rates, which is consistent with previous studies, loading dependencies are observed at higher loading rates. There is also a logarithmic decrease in SSM for increasing (initial) void size, as well. A model was developed to account for the effects of loading rate, particle size, matrix sound-speed, and, in the NDI-specific case, the probabilistic particle volume fraction model. Small-scale spall experiments were designed

  17. Sub-grid combustion modeling for compressible two-phase reacting flows (United States)

    Sankaran, Vaidyanathan


    A generic formulation for modeling the turbulent combustion in compressible, high Reynolds number, two-phase; reacting flows has been developed and validated. A sub-grid mixing/combustion model called Linear Eddy Mixing (LEM) model has been extended to compressible flows and used inside the framework of Large Eddy Simulation (LES) in this LES-LEM approach. The LES-LEM approach is based on the proposition that the basic mechanistic distinction between the convective and the molecular effects should be preserved for accurate prediction of complex flow-fields such as those encountered in many combustion systems. Liquid droplets (represented by computational parcels) are tracked using the Lagrangian approach wherein the Newton's equation of motion for the discrete particles are integrated explicitly in the Eulerian gas field. The gas phase LES velocity fields are used to estimate the instantaneous gas velocity at the droplet location. Drag effects due to the droplets on the gas phase and the heat transfer between the gas and the liquid phase are explicitly included. Thus, full coupling is achieved between the two phases in the simulation. Validation of the compressible LES-LEM approach is conducted by simulating the flow-field in an operational General Electric Aircraft Engines combustor (LM6000). The results predicted using the proposed approach compares well with the experiments and a conventional (G-equation) thin-flame model. Particle tracking algorithms used in the present study are validated by simulating droplet laden temporal mixing layers. Quantitative and qualitative comparison with the results of spectral DNS exhibits good agreement. Simulations using the current LES-LEM for freely propagating partially premixed flame in a droplet-laden isotropic turbulent field correctly captures the flame structure in the partially premixed flames. Due to the strong spatial variation of equivalence ratio a broad flame similar to a premixed flame is realized. The current

  18. Time Delay Estimation in Two-Phase Flow Investigation Using the γ-Ray Attenuation Technique

    Directory of Open Access Journals (Sweden)

    Robert Hanus


    Full Text Available Time delay estimation is an important research question having many applications in a range of technologies. Measurement of a two-phase flow in a pipeline or an open channel using radioisotopes is an example of such application. For instance, the determination of velocity of dispersed phase in that case is based on estimation of the time delay between two stochastic signals provided by scintillation probes. The proper analysis of such signals, usually in presence of noise, requires the use of advanced statistical signal processing. In this paper, the simulation studies of time delay estimation were carried out with the use of the following differential methods: average magnitude difference function, and average square difference function and proposed combined methods comprising the above-mentioned differential and cross-correlation functions are presented. Attached simulations have been carried out for models of stochastic signals corresponding to the signals obtained in gamma-ray absorption measurements of gas-liquid flow in a horizontal pipeline. The standard uncertainties of time delay estimations have been determined for each of the methods. Improved metrological properties have been stated in the combined methods in comparison with the classical cross-correlation procedure.

  19. Treatment of phenol in synthetic saline wastewater by solvent extraction and two-phase membrane biodegradation. (United States)

    Juang, Ruey-Shin; Huang, Wen-Ching; Hsu, Ya-Han


    Phenol in synthetic saline (100gL(-1) NaCl) and acidic (pH 3) wastewater was treated by a hybrid solvent extraction and two-phase membrane biodegradation process at 30 degrees C. Kerosene was adopted to be the organic solvent because it was biocompatible and had a suitable partition coefficient for phenol. Phenol in water was first extracted by kerosene in a batch stirred vessel and the loaded solvent was passed through the lumen of a polyvinylidene fluoride (PVDF) hollow-fiber membrane contactor; in the meantime, Pseudomonas putida BCRC 14365 in mineral salt medium was flowed across the shell, to which tetrasodium phyophosphate (1gL(-1)) was added as a dispersing agent. The effect of the initial phenol level in wastewater (110-2400mgL(-1)) on phenol removal and cell growth was experimentally studied. At a cell concentration of 0.023gL(-1), it was shown that the removal of phenol from saline wastewater was more efficient at a level of 2000mgL(-1) when 0.02-m(2) membrane module was used. The effects of bigger membrane module size (0.19m(2) area) and higher initial cell concentration (0.092-0.23gL(-1)) on the performance of such a hybrid process for the treatment of higher-level phenol in saline wastewater was also evaluated and discussed.

  20. Numerical and dimensional analysis of nanoparticles transport with two-phase flow in porous media

    KAUST Repository

    El-Amin, Mohamed


    In this paper, a mathematical model and numerical simulation are developed to describe the imbibition of nanoparticles-water suspension into two-phase flow in a porous medium. The flow system may be changed from oil-wet to water-wet due to nanoparticles (which are also water-wet) deposition on surface of the pores. So, the model is extended to include the negative capillary pressure and mixed-wet relative permeability correlations to fit with the mixed-wet system. Moreover, buoyancy and capillary forces as well as Brownian diffusion and mechanical dispersion are considered in the mathematical model. An example of countercurrent imbibition in a core of small scale is considered. A dimensional analysis of the governing equations is introduced to examine contributions of each term of the model. Several important dimensionless numbers appear in the dimensionless equations, such as Darcy number Da, capillary number Ca, and Bond number Bo. Throughout this investigation, we monitor the changing of the fluids and solid properties due to addition of the nanoparticles using numerical experiments.

  1. Purification and In Situ Immobilization of Papain with Aqueous Two-Phase System (United States)

    Li, Mingliang; Su, Erzheng; You, Pengyong; Gong, Xiangyu; Sun, Ming; Xu, Diansheng; Wei, Dongzhi


    Papain was purified from spray-dried Carica papaya latex using aqueous two-phase system (ATPS). Then it was recovered from PEG phase by in situ immobilization or preparing cross-linked enzyme aggregates (CLEAs). The Plackett-Burman design and the central composite design (CCD) together with the response surface methodology (RSM) were used to optimize the APTS processes. The highly purified papain (96–100%) was achieved under the optimized conditions: 40% (w/w) 15 mg/ml enzyme solution, 14.33–17.65% (w/w) PEG 6000, 14.27–14.42% (w/w) NaH2PO4/K2HPO4 and pH 5.77–6.30 at 20°C. An in situ enzyme immobilization approach, carried out by directly dispersing aminated supports and chitosan beads into the PEG phase, was investigated to recover papain, in which a high immobilization yield (>90%) and activity recovery (>40%) was obtained. Moreover, CLEAs were successfully used in recovering papain from PEG phase with a hydrolytic activity hundreds times higher than the carrier-bound immobilized papain. PMID:21179198

  2. Dispersive Liquid-Liquid Microextraction Using Low-Toxic Solvent for the Determination of Heavy Metals in Water Samples by Inductively Coupled Plasma-Mass Spectrometry. (United States)

    Peng, Guilong; Lu, Ying; He, Qiang; Mmereki, Daniel; Zhou, Guangming; Chen, Junhua; Tang, Xiaohui


    A low-toxic dispersive liquid-liquid microextraction (DLLME) combined with inductively coupled plasma-MS was used for preconcentration and determination of Cu, Cr, Cd, Ni, Mn, and Pb in real-water samples. In traditional DLLME analysis, chlorinated solvents have been widely used as extraction solvents. However, these solvents are not environmentally friendly. To overcome this problem, we used a low-toxic bromosolvent (1-bromo-3-methylbutane; lethal concentration, 50%, 6150 mg/kg) as the extraction solvent. To study the effects of different parameters on the extraction efficiency, an orthogonal array experimental design with an L16(4(5)) matrix was used. Under the best experimental conditions (i.e., concentration of complexing reagent 1-(2-pyridylazo)-2-naphthol, 1.5 × 10(-3) mol/L; pH, 7.0; volume of acetone, 0.5 mL; volume of 1-bromo-3 methylbutane, 30 μL; and without salt addition), the enhancement factor ranged from 34 to 40. The linear dynamic range was 1-1000 μg/L with r(2) values of 0.9984-0.9999, and the LODs were between 0.042 and 0.53 μg/L. RSDs (at metal ion concentrations of 20 μg/L, n = 6) were 2.12 to 3.42%. The developed method was successfully applied to the extraction and determination of the mentioned metal ions in real-water samples, and satisfactory results were obtained.

  3. Dispersive liquid-liquid microextraction for the determination of phenols by acetonitrile stacking coupled with sweeping-micellar electrokinetic chromatography with large-volume injection. (United States)

    He, Hui; Liu, Shuhui; Meng, Zhaofu; Hu, Shibing


    The current routes to couple dispersive liquid-liquid microextraction (DLLME) with capillary electrophoresis (CE) are evaporation of water immiscible extractants and backextraction of analytes. The former is not applicable to extractants with high boiling points, the latter being effective only for acidic or basic analytes, both of which limit the further application of DLLME-CE. In this study, with 1-octanol as a model DLLME extractant and six phenols as model analytes, a novel method based on acetonitrile stacking and sweeping is proposed to accomplish large-volume injection of 1-octanol diluted with a solvent-saline mixture before micellar electrokinetic chromatography. Brij-35 and β-cyclodextrin were employed as pseudostationary phases for sweeping and also for improving the compatibility of sample zone and aqueous running buffer. A short solvent-saline plug was used to offset the adverse effect of the water immiscible extractant on focusing efficiency. The key parameters affecting separation and concentration were systematically optimized; the effect of Brij-35 and 1-octanol on focusing mechanism was discussed. Under the optimized conditions, with ∼ 30-fold concentration enrichment by DLLME, the diluted extractant (8×) was then injected into the capillary with a length of 21 cm (42% of the total length), which yielded the overall improvements in sensitivity of 170-460. Limits of detection and qualification ranged from 0.2 to 1.0 ng/mL and 1.0 to 3.4 g/mL, respectively. Acceptable repeatability lower than 3.0% for migration time and 9.0% for peak areas were obtained. The developed method was successfully applied for analysis of the phenol pollutants in real water samples. Copyright © 2014 Elsevier B.V. All rights reserved.

  4. Two-phase aqueous micellar systems: an alternative method for protein purification


    Rangel-Yagui C. O.; Pessoa-Jr A.; Blankschtein D.


    Two-phase aqueous micellar systems can be exploited in separation science for the extraction/purification of desired biomolecules. This article reviews recent experimental and theoretical work by Blankschtein and co-workers on the use of two-phase aqueous micellar systems for the separation of hydrophilic proteins. The experimental partitioning behavior of the enzyme glucose-6-phosphate dehydrogenase (G6PD) in two-phase aqueous micellar systems is also reviewed and new results are presented. ...

  5. Aqueous two-phase system based on natural quaternary ammonium compounds for the extraction of proteins. (United States)

    Zeng, Chao-Xi; Xin, Rui-Pu; Qi, Sui-Jian; Yang, Bo; Wang, Yong-Hua


    Aqueous two-phase systems, based on the use of natural quaternary ammonium compounds, were developed to establish a benign biotechnological route for efficient protein separation. In this study, aqueous two-phase systems of two natural resources betaine and choline with polyethyleneglycol (PEG400/600) or inorganic salts (K2 HPO4 /K3 PO4 ) were formed. It was shown that in the K2 HPO4 -containing aqueous two-phase system, hydrophobic interactions were an important driving force of protein partitioning, while protein size played a vital role in aqueous two-phase systems that contained polyethylene glycol. An extraction efficiency of more than 90% for bovine serum albumin in the betaine/K2 HPO4 aqueous two-phase system can be obtained, and this betaine-based aqueous two-phase system provided a gentle and stable environment for the protein. In addition, after investigation of the cluster phenomenon in the betaine/K2 HPO4 aqueous two-phase systems, it was suggested that this phenomenon also played a significant role for protein extraction in this system. The development of aqueous two-phase systems based on natural quaternary ammonium compounds not only provided an effective and greener method of aqueous two-phase system to meet the requirements of green chemistry but also may help to solve the mystery of the compartmentalization of biomolecules in cells. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Modeling of annular two-phase flow using a unified CFD approach

    Energy Technology Data Exchange (ETDEWEB)

    Li, Haipeng, E-mail:; Anglart, Henryk, E-mail:


    Highlights: • Annular two-phase flow has been modeled using a unified CFD approach. • Liquid film was modeled based on a two-dimensional thin film assumption. • Both Eulerian and Lagrangian methods were employed for the gas core flow modeling. - Abstract: A mechanistic model of annular flow with evaporating liquid film has been developed using computational fluid dynamics (CFD). The model is employing a separate solver with two-dimensional conservation equations to predict propagation of a thin boiling liquid film on solid walls. The liquid film model is coupled to a solver of three-dimensional conservation equations describing the gas core, which is assumed to contain a saturated mixture of vapor and liquid droplets. Both the Eulerian–Eulerian and the Eulerian–Lagrangian approach are used to describe the droplet and vapor motion in the gas core. All the major interaction phenomena between the liquid film and the gas core flow have been accounted for, including the liquid film evaporation as well as the droplet deposition and entrainment. The resultant unified framework for annular flow has been applied to the steam-water flow with conditions typical for a Boiling Water Reactor (BWR). The simulation results for the liquid film flow rate show good agreement with the experimental data, with the potential to predict the dryout occurrence based on criteria of critical film thickness or critical film flow rate.

  7. A new treatment of capillarity to improve the stability of IMPES two-phase flow formulation

    KAUST Repository

    Kou, Jisheng


    In this paper, we present an efficient numerical method for two-phase immiscible flow in porous media with different capillarity pressures. In highly heterogeneous permeable media, the saturation is discontinuous due to different capillary pressure functions. One popular scheme is to split the system into a pressure and a saturation equation, and to apply IMplicit Pressure Explicit Saturation (IMPES) approach for time stepping. One disadvantage of IMPES is instability resulting from the explicit treatment for capillary pressure. To improve stability, the capillary pressure is usually incorporated in the saturation equation which gradients of saturation appear. This approach, however, does not apply to the case of different capillary pressure functions for multiple rock-types, because of the discontinuity of saturation across rock interfaces. In this paper, we present a new treatment of capillary pressure, which appears implicitly in the pressure equation. Using an approximation of capillary function, we substitute the implicit saturation equation into the pressure equation. The coupled pressure equation will be solved implicitly and followed by the explicit saturation equation. Five numerical examples are provided to demonstrate the advantages of our approach. Comparison shows that our proposed method is more efficient and stable than the classical IMPES approach. © 2010 Elsevier Ltd.

  8. Gradient-augmented hybrid interface capturing method for incompressible two-phase flow (United States)

    Zheng, Fu; Shi-Yu, Wu; Kai-Xin, Liu


    Motivated by inconveniences of present hybrid methods, a gradient-augmented hybrid interface capturing method (GAHM) is presented for incompressible two-phase flow. A front tracking method (FTM) is used as the skeleton of the GAHM for low mass loss and resources. Smooth eulerian level set values are calculated from the FTM interface, and are used for a local interface reconstruction. The reconstruction avoids marker particle redistribution and enables an automatic treatment of interfacial topology change. The cubic Hermit interpolation is employed in all steps of the GAHM to capture subgrid structures within a single spacial cell. The performance of the GAHM is carefully evaluated in a benchmark test. Results show significant improvements of mass loss, clear subgrid structures, highly accurate derivatives (normals and curvatures) and low cost. The GAHM is further coupled with an incompressible multiphase flow solver, Super CE/SE, for more complex and practical applications. The updated solver is evaluated through comparison with an early droplet research. Project supported by the National Natural Science Foundation of China (Grant Nos. 10972010, 11028206, 11371069, 11372052, 11402029, and 11472060), the Science and Technology Development Foundation of China Academy of Engineering Physics (CAEP), China (Grant No. 2014B0201030), and the Defense Industrial Technology Development Program of China (Grant No. B1520132012).

  9. Simulation of plasma discharge in liquids: A detailed two-phase fluid approach (United States)

    Charchi Aghdam, Ali; Farouk, Tanvir; Reacting Systems; Advanced Energy Research Laboratory Team


    Plasma discharge in liquids has gained great attention recently due to its applications in biomedical engineering, fuel processing, and water treatment and so on. Despite the tremendous interest, a comprehensive understanding of the underlying physics still remains limited. In the current work, an attempt is made to present a mathematical multi-physics model to describe the discharge of plasma in liquids. An in-house modeling platform is developed for simulating plasma formation in multiphase fluids. The model resolves a detailed two-phase fluid including viscous effects, surface tension, gravitational forces and electrical body force. All the governing equations are solved for gas and liquid phases. Electric field and charged species equations along with the plasma reaction kinetics are solved to get the charge distribution in the different phases as well as at the gas-liquid interface to obtain the electric body force acting at the interface. By coupling the above sub-models, a comprehensive multi-physics model for plasma discharge in liquids is constructed which is able to capture several physical aspects of the phenomena especially the role of the bubble, its motion and distortion on plasma characteristics.

  10. Vertically stratified two-phase flow in a curved channel: Insights from a domain perturbation analysis

    Energy Technology Data Exchange (ETDEWEB)

    Garg, P. [Department of Chemical Engineering, Indian Institute of Technology Roorkee, Roorkee 247 667 (India); Picardo, J. R.; Pushpavanam, S., E-mail: [Department of Chemical Engineering, Indian Institute of Technology Madras, Chennai 600 036 (India)


    In this work, we investigate the fully developed flow field of two vertically stratified fluids (one phase flowing above the other) in a curved channel of rectangular cross section. The domain perturbation technique is applied to obtain an analytical solution in the asymptotic limit of low Reynolds numbers and small curvature ratios (the ratio of the width of the channel to its radius of curvature). The accuracy of this solution is verified by comparison with numerical simulations of the nonlinear equations. The flow is characterized by helical vortices within each fluid, which are driven by centrifugal forces. The number of vortices and their direction of circulation varies with the parameters of the system (the volume fraction, viscosity ratio, and Reynolds numbers). We identify nine distinct flow patterns and organize the parameter space into corresponding flow regimes. We show that the fully developed interface between the fluids is not horizontal, in general, but is deformed by normal stresses associated with the circulatory flow. The results are especially significant for flows in microchannels, where the Reynolds numbers are small. The mathematical results in this paper include an analytical solution to two coupled biharmonic partial differential equations; these equations arise in two-phase, two-dimensional Stokes flows.

  11. An adaptive level set approach for incompressible two-phase flows

    Energy Technology Data Exchange (ETDEWEB)

    Sussman, M.; Almgren, A.S.; Bell, J.B. [and others


    In Sussman, Smereka and Osher, a numerical method using the level set approach was formulated for solving incompressible two-phase flow with surface tension. In the level set approach, the interface is represented as the zero level set of a smooth function; this has the effect of replacing the advection of density, which has steep gradients at the interface, with the advection of the level set function, which is smooth. In addition, the interface can merge or break up with no special treatment. The authors maintain the level set function as the signed distance from the interface in order to robustly compute flows with high density ratios and stiff surface tension effects. In this work, they couple the level set scheme to an adaptive projection method for the incompressible Navier-Stokes equations, in order to achieve higher resolution of the interface with a minimum of additional expense. They present two-dimensional axisymmetric and fully three-dimensional results of air bubble and water drop computations.

  12. Thermal diffusion characteristics of atmosphere-particle two phase flow in dust storm (United States)

    Wang, Xihua; Wang, Tijian; Tang, Jianping; Gu, Fan


    A model, coupling metrological dynamic model MM5 and dust transport model, is developed for the atmosphere-particle two phases flow of dust storm. The simulations of the dust storm events in north China with a geographic information database are performed using the model, and represent an overview of dust transport pathways and particles concentration distribution over the north China. The comparison between computations and practical observations shows that the simulations succeed in description of dust storm evolvement and particle transport behavior. Based on the computations and analysis, the characteristics of particle transport, especially well-concerning the factor of the particle thermal diffusion, are studied. A new definition of mass transfer Grd is put forward to discover the internal principle of particle thermal diffusion at various atmospheric layers. Several phenomena, such as thermal diffusion item QT Grd distribution, and relationships, Particle Grd probability function, are obtained. The investigation indicates particle thermal diffusion can be not ignored in mesoscale atmospheric-particle multiphase flow.

  13. Flow Patterns Transition Law of Oil-Water Two-Phase Flow under a Wide Range of Oil Phase Viscosity Condition


    Wei Wang(College of William and Mary); Wei Cheng; Kai Li; Chen Lou; Jing Gong


    A systematic work on the prediction of flow patterns transition of the oil-water two-phase flows is carried out under a wide range of oil phase viscosities, where four main flow regimes are considered including stratified, dispersed, core-annular, and intermittent flow. For oil with a relatively low viscosity, VKH criterion is considered for the stability of stratified flow, and critical drop size model is distinguished for the transition of o/w and w/o dispersed flow. For oil with a high vis...

  14. Thermodynamically consistent modeling and simulation of multi-component two-phase flow with partial miscibility

    KAUST Repository

    Kou, Jisheng


    A general diffuse interface model with a realistic equation of state (e.g. Peng-Robinson equation of state) is proposed to describe the multi-component two-phase fluid flow based on the principles of the NVT-based framework which is an attractive alternative recently over the NPT-based framework to model the realistic fluids. The proposed model uses the Helmholtz free energy rather than Gibbs free energy in the NPT-based framework. Different from the classical routines, we combine the first law of thermodynamics and related thermodynamical relations to derive the entropy balance equation, and then we derive a transport equation of the Helmholtz free energy density. Furthermore, by using the second law of thermodynamics, we derive a set of unified equations for both interfaces and bulk phases that can describe the partial miscibility of multiple fluids. A relation between the pressure gradient and chemical potential gradients is established, and this relation leads to a new formulation of the momentum balance equation, which demonstrates that chemical potential gradients become the primary driving force of fluid motion. Moreover, we prove that the proposed model satisfies the total (free) energy dissipation with time. For numerical simulation of the proposed model, the key difficulties result from the strong nonlinearity of Helmholtz free energy density and tight coupling relations between molar densities and velocity. To resolve these problems, we propose a novel convex-concave splitting of Helmholtz free energy density and deal well with the coupling relations between molar densities and velocity through very careful physical observations with a mathematical rigor. We prove that the proposed numerical scheme can preserve the discrete (free) energy dissipation. Numerical tests are carried out to verify the effectiveness of the proposed method.

  15. Microfluidic generation of aqueous two-phase-system (ATPS) droplets by oil-droplet choppers. (United States)

    Zhou, Chunmei; Zhu, Pingan; Tian, Ye; Tang, Xin; Shi, Rui; Wang, Liqiu


    Existing approaches for droplet generation with an ultra-low interfacial tension using aqueous two-phase systems, ATPS, are either constricted by a narrow range of flow conditions using passive methods or subjected to complex chip fabrication with the integration of external components using active actuation. To address these issues, we present a simple approach to produce uniform ATPS droplets facilitated by oil-droplet choppers in microfluidics. Our solution counts on the synchronized formation of high-interfacial-tension oil-in-water and low-interfacial-tension water-in-water droplets, where the ATPS interface is distorted by oil droplets and decays into water-in-water droplets. In the synchronization regime, the size and generation frequency of ATPS droplets can be controlled independently by tuning the flow rates of the dispersed aqueous and oil phases, respectively. Our method demonstrates high uniformity of droplets (coefficient of variation between 0.75% and 2.45%), a wide range of available droplet size (droplet radius from 5 μm to 180 μm), and a maximum generation frequency of about 2.1 kHz that is nearly two orders of magnitude faster than that in existing methods. We develop theoretical models to precisely predict the minimum and maximum frequencies of droplet generation and the droplet size. The produced ATPS droplets and oil choppers are separated in the channel using density difference. Our method would boost emulsion-based biological applications such as cell encapsulation, biomolecule delivery, bioreactors, and biomaterials synthesis with ATPS droplets.

  16. NASA Physical Sciences - Presentation to Annual Two Phase Heat Transfer International Topical Team Meeting (United States)

    Chiaramonte, Francis; Motil, Brian; McQuillen, John


    The Two-phase Heat Transfer International Topical Team consists of researchers and members from various space agencies including ESA, JAXA, CSA, and RSA. This presentation included descriptions various fluid experiments either being conducted by or planned by NASA for the International Space Station in the areas of two-phase flow, flow boiling, capillary flow, and crygenic fluid storage.

  17. 48 CFR 570.105-2 - Two-phase design-build selection procedures. (United States)


    ... 48 Federal Acquisition Regulations System 4 2010-10-01 2010-10-01 false Two-phase design-build...-phase design-build selection procedures. Unless you use another acquisition procedure authorized by law, you must use the two-phase design-build selection procedures in section 303M of the Federal Property...

  18. Extraction and stability of selected proteins in ionic liquid based aqueous two phase systems

    NARCIS (Netherlands)

    Desai, R.K.; Streefland, M.; Wijffels, R.H.; Eppink, M.H.M.


    Ionic liquid-based aqueous two-phase extraction of a plant protein, Rubisco (Ribulose-1,5-biphosphate carboxylase oxygenase), using Iolilyte 221 PG and sodium potassium phosphate buffer, was investigated as a new alternative extraction method and compared with a conventional PEG-based two-phase

  19. Numerical experiments on breaking waves on contrasting beaches using a two-phase flow approach (United States)

    Bakhtyar, R.; Barry, D. A.; Kees, C. E.


    A mechanistic understanding of beach environments needs to account for interactions of oceanic forcing and beach materials, in particular the role of waves on the evolution of the beach profile. A fully coupled two-phase flow model was used to simulate nearshore fluid-sediment turbulent flow in the cross-shore direction. It includes the Reynolds-Averaged Navier-Stokes equations and turbulent stress closures for each phase, and accounts for inter-granular stresses. The model has previously been validated using laboratory-scale data, so the results are likely more reliable for that scale. It was used to simulate wave breaking and the ensuing hydrodynamics and sediment transport processes in the surf/swash zones. Numerical experiments were conducted to investigate the effects of varying beach and wave characteristics (e.g., beach slope, sediment grain size, wave periods and heights) on the foreshore profile changes. Spilling and plunging breakers occur on dissipative and intermediate beaches, respectively. The impact of these wave/beach types on nearshore zone hydrodynamics and beach morphology was determined. The numerical results showed that turbulent kinetic energy, sediment concentrations and transport rate are greater on intermediate than on dissipative beaches. The results confirmed that wave energy, beach grain size and bed slope are main factors for sediment transport and beach morphodynamics. The location of the maximum sediment transport is near the breaking point for both beach types. Coarse- and fine-sand beaches differ significantly in their erosive characteristics (e.g., foreshore profile evolutions are erosive and accretionary on the fine and coarse sand beaches, respectively). In addition, a new parameter (based on main driving factors) is proposed that can characterize the sediment transport in the surf and swash zones. The results are consistent with existing physical observations, suggesting that the two-phase flow model is suitable for the

  20. Two-phase anaerobic digestion of vegetable market waste fraction of municipal solid waste and development of improved technology for phase separation in two-phase reactor. (United States)

    Majhi, Bijoy Kumar; Jash, Tushar


    Biogas production from vegetable market waste (VMW) fraction of municipal solid waste (MSW) by two-phase anaerobic digestion system should be preferred over the single-stage reactors. This is because VMW undergoes rapid acidification leading to accumulation of volatile fatty acids and consequent low pH resulting in frequent failure of digesters. The weakest part in the two-phase anaerobic reactors was the techniques applied for solid-liquid phase separation of digestate in the first reactor where solubilization, hydrolysis and acidogenesis of solid organic waste occur. In this study, a two-phase reactor which consisted of a solid-phase reactor and a methane reactor was designed, built and operated with VMW fraction of Indian MSW. A robust type filter, which is unique in its implementation method, was developed and incorporated in the solid-phase reactor to separate the process liquid produced in the first reactor. Experiments were carried out to assess the long term performance of the two-phase reactor with respect to biogas production, volatile solids reduction, pH and number of occurrence of clogging in the filtering system or choking in the process liquid transfer line. The system performed well and was operated successfully without the occurrence of clogging or any other disruptions throughout. Biogas production of 0.86-0.889m(3)kg(-1)VS, at OLR of 1.11-1.585kgm(-3)d(-1), were obtained from vegetable market waste, which were higher than the results reported for similar substrates digested in two-phase reactors. The VS reduction was 82-86%. The two-phase anaerobic digestion system was demonstrated to be stable and suitable for the treatment of VMW fraction of MSW for energy generation. Copyright © 2016 Elsevier Ltd. All rights reserved.

  1. A two phase Mach number description of the equilibrium flow of nitrogen in ducts (United States)

    Bursik, J. W.; Hall, R. M.; Adcock, J. B.


    Some additional thermodynamic properties of the usual two-phase form which is linear in the moisture fraction are derived which are useful in the analysis of many kinds of duct flow. The method used is based on knowledge of the vapor pressure and Gibbs function as functions of temperature. With these, additional two-phase functions linear in moisture fraction are generated, which ultimately reveal that the squared ratio of mixture specific volume to mixture sound speed depends on liquid mass fraction and temperature in the same manner as do many weighted mean two-phase properties. This leads to a simple method of calculating two-phase Mach numbers for various duct flows. The matching of one- and two-phase flows at a saturated vapor point with discontinuous Mach number is also discussed.

  2. Production Decline Analysis for Two-Phase Flow in Multifractured Horizontal Well in Shale Gas Reservoirs

    Directory of Open Access Journals (Sweden)

    Wei-Yang Xie


    Full Text Available After multistage fracturing, the flowback of fracturing fluid will cause two-phase flow through hydraulic fractures in shale gas reservoirs. With the consideration of two-phase flow and desorbed gas transient diffusion in shale gas reservoirs, a two-phase transient flow model of multistage fractured horizontal well in shale gas reservoirs was created. Accurate solution to this flow model is obtained by the use of source function theory, Laplace transform, three-dimensional eigenvalue method, and orthogonal transformation. According to the model’s solution, the bilogarithmic type curves of the two-phase model are illustrated, and the production decline performance under the effects of hydraulic fractures and shale gas reservoir properties are discussed. The result obtained in this paper has important significance to understand pressure response characteristics and production decline law of two-phase flow in shale gas reservoirs. Moreover, it provides the theoretical basis for exploiting this reservoir efficiently.

  3. On-demand generation of aqueous two-phase microdroplets with reversible phase transitions (United States)

    Collier, Charles


    Aqueous two-phase systems contained within microdroplets enable a bottom-up approach to mimicking the dynamic microcompartmentation of biomaterial that naturally occurs within the cytoplasm of cells. Here, we demonstrate the on-demand generation of femtolitre aqueous two-phase droplets within a microfluidic oil channel. Gated pressure pulses were used to generate individual, stationary two-phase microdroplets with a well-defined time zero for carrying out controlled and sequential phase transformations over time. Reversible phase transitions between single-phase, two-phase, and core-shell microbead states were obtained via evaporation-induced dehydration and on-demand water rehydration. In contrast to other microfluidic aqueous two-phase droplets, which require continuous flows and high-frequency droplet formation, our system enables the controlled isolation and reversible transformation of a single microdroplet and is expected to be useful for future studies in dynamic microcompartmentation and affinity partitioning.

  4. Detailed source term estimation of the atmospheric release for the Fukushima Daiichi Nuclear Power Station accident by coupling simulations of an atmospheric dispersion model with an improved deposition scheme and oceanic dispersion model

    Energy Technology Data Exchange (ETDEWEB)

    Katata, G.; Chino, M.; Kobayashi, T. [Japan Atomic Energy Agency (JAEA), Ibaraki (Japan); and others


    Temporal variations in the amount of radionuclides released into the atmosphere during the Fukushima Daiichi Nuclear Power Station (FNPS1) accident and their atmospheric and marine dispersion are essential to evaluate the environmental impacts and resultant radiological doses to the public. In this paper, we estimate the detailed atmospheric releases during the accident using a reverse estimation method which calculates the release rates of radionuclides by comparing measurements of air concentration of a radionuclide or its dose rate in the environment with the ones calculated by atmospheric and oceanic transport, dispersion and deposition models. The atmospheric and oceanic models used are WSPEEDI-II (Worldwide version of System for Prediction of Environmental Emergency Dose Information) and SEA-GEARN-FDM (Finite difference oceanic dispersion model), both developed by the authors. A sophisticated deposition scheme, which deals with dry and fog-water depositions, cloud condensation nuclei (CCN) activation, and subsequent wet scavenging due to mixed-phase cloud microphysics (in-cloud scavenging) for radioactive iodine gas (I{sub 2} and CH{sub 3}I) and other particles (CsI, Cs, and Te), was incorporated into WSPEEDI-II to improve the surface deposition calculations. The results revealed that the major releases of radionuclides due to the FNPS1 accident occurred in the following periods during March 2011: the afternoon of 12 March due to the wet venting and hydrogen explosion at Unit 1, midnight of 14 March when the SRV (safety relief valve) was opened three times at Unit 2, the morning and night of 15 March, and the morning of 16 March. According to the simulation results, the highest radioactive contamination areas around FNPS1 were created from 15 to 16 March by complicated interactions among rainfall, plume movements, and the temporal variation of release rates. The simulation by WSPEEDI-II using the new source term reproduced the local and regional patterns of

  5. Loose-coupling an air dispersion model and a geographic information system (GIS) for studying air pollution and asthma in the Bronx, New York City. (United States)

    Maantay, Juliana A; Tu, Jun; Maroko, Andrew R


    This study developed new procedures to loosely integrate an air dispersion model, AERMOD, and a geographic information system (GIS) package, ArcGIS, to simulate air dispersion from stationary sources in the Bronx, New York City, for five pollutants: PM(10), PM(2.5), NO(x), CO, and SO(2). Plume buffers created from the model results were used as proxies of human exposure to the pollution from the sources and they modified the commonly used fixed-distance proximity buffers by considering the realities of air dispersion. The application of the plume buffers confirmed that the higher asthma hospitalization rates were associated with the higher potential exposure to local air pollution. The air dispersion modeling exhibited advantages over proximity analysis and geostatistical methods for environmental health research. The loose integration provides a relatively simple and feasible method for health scientists to take advantage of both air dispersion modeling and GIS by avoiding the need for intensive programming and substantial GIS expertise.

  6. Evaluation of EIT systems and algorithms for handling full void fraction range in two-phase flow measurement (United States)

    Jia, Jiabin; Wang, Mi; Faraj, Yousef


    In the aqueous-based two-phase flow, if the void fraction of dispersed phase exceeds 0.25, conventional electrical impedance tomography (EIT) produces a considerable error due to the linear approximation of the sensitivity back-projection (SBP) method, which limits the EIT’s wider application in the process industry. In this paper, an EIT sensing system which is able to handle full void fraction range in two-phase flow is reported. This EIT system employs a voltage source, conducts true mutual impedance measurement and reconstructs an online image with the modified sensitivity back-projection (MSBP) algorithm. The capability of the Maxwell relationship to convey full void fraction is investigated. The limitation of the linear sensitivity back-projection method is analysed. The MSBP algorithm is used to derive relative conductivity change in the evaluation. A series of static and dynamic experiments demonstrating the mean void fraction obtained using this EIT system has a good agreement with reference void fractions over the range from 0 to 1. The combination of the new EIT system and MSBP algorithm would significantly extend the applications of EIT in industrial process measurement.

  7. An accurate quantification of the flow structure along the acoustic signal cycle in a forced two-phase jet

    Directory of Open Access Journals (Sweden)

    Calvo Bernad Esteban


    Full Text Available This paper provides an experimental study of an acoustically forced two-phase air jet generated by a convergent nozzle. The used particles are transparent glass spheres with diameters between 2 and 50 μm (which gives Stokes number of order 1 and the selected forcing frequency (f=400 Hz induces a powerful nearly periodic flow pattern. Measurements were done by a two-colour Phase-Doppler Anemometer. The experimental setup is computer-controlled to provide an accurate control with a high long-term stability. Measurements cover the whole forcing signal cycle. Raw measurements were carefully post-processed to avoid bias induced by the forcing and the instrument setup, as well as obtain right mean values of the dispersed flow. The effect of the forcing and the particle load allows authors to establish the effect of the acoustic forcing and the particle load on the jet.

  8. Two-phase aqueous micellar systems: an alternative method for protein purification

    Directory of Open Access Journals (Sweden)

    Rangel-Yagui C. O.


    Full Text Available Two-phase aqueous micellar systems can be exploited in separation science for the extraction/purification of desired biomolecules. This article reviews recent experimental and theoretical work by Blankschtein and co-workers on the use of two-phase aqueous micellar systems for the separation of hydrophilic proteins. The experimental partitioning behavior of the enzyme glucose-6-phosphate dehydrogenase (G6PD in two-phase aqueous micellar systems is also reviewed and new results are presented. Specifically, we discuss very recent work on the purification of G6PD using: i a two-phase aqueous micellar system composed of the nonionic surfactant n-decyl tetra(ethylene oxide (C10E4, and (ii a two-phase aqueous mixed micellar system composed of C10E4 and the cationic surfactant decyltrimethylammonium bromide (C10TAB. Our results indicate that the two-phase aqueous mixed (C10E4/C10TAB micellar system can improve significantly the partitioning behavior of G6PD relative to that observed in the two-phase aqueous C10E4 micellar system.

  9. Numerical investigation on the characteristics of two-phase flow in fuel assemblies with spacer grid

    Energy Technology Data Exchange (ETDEWEB)

    Chen, D.; Yang, Z.; Zhong, Y.; Xiao, Y.; Hu, L. [Chongqing Univ. (China). Key Lab. of Low-grade Energy Utilization Technologies and Systems


    In pressurized water reactors (PWRs), the spacer grids of the fuel assembly has significant impact on the thermal-hydraulic performance of the fuel assembly. Particularly, the spacer grids with the mixing vanes can dramatically enhance the secondary flow and have significant effect on the void distribution in the fuel assembly. In this paper, the CFD study has been carried out to analyze the effects of the spacer grid with the steel contacts, dimples and mixing vanes on the boiling two-phase flow characteristics, such as the two-phase flow field, the void distribution, and so on. Considered the influence of the boiling phase change on two-phase flow, a boiling model was proposed and applied in the CFD simulation by using the UDF (User Defined Function) method. Furthermore, in order to analyze the effects of the spacer grid with mixing vanes, the adiabatic (without boiling) two-phase flow has also been investigated as comparison with the boiling two-phase flow in the fuel assembly with spacer grids. The CFD simulation on two-phase flow in the fuel assembly with the proposed boiling model can predict the characteristics of two-phase flow better.

  10. Analytical solution for two-phase flow in a wellbore using the drift-flux model

    Energy Technology Data Exchange (ETDEWEB)

    Pan, L.; Webb, S.W.; Oldenburg, C.M.


    This paper presents analytical solutions for steady-state, compressible two-phase flow through a wellbore under isothermal conditions using the drift flux conceptual model. Although only applicable to highly idealized systems, the analytical solutions are useful for verifying numerical simulation capabilities that can handle much more complicated systems, and can be used in their own right for gaining insight about two-phase flow processes in wells. The analytical solutions are obtained by solving the mixture momentum equation of steady-state, two-phase flow with an assumption that the two phases are immiscible. These analytical solutions describe the steady-state behavior of two-phase flow in the wellbore, including profiles of phase saturation, phase velocities, and pressure gradients, as affected by the total mass flow rate, phase mass fraction, and drift velocity (i.e., the slip between two phases). Close matching between the analytical solutions and numerical solutions for a hypothetical CO{sub 2} leakage problem as well as to field data from a CO{sub 2} production well indicates that the analytical solution is capable of capturing the major features of steady-state two-phase flow through an open wellbore, and that the related assumptions and simplifications are justified for many actual systems. In addition, we demonstrate the utility of the analytical solution to evaluate how the bottomhole pressure in a well in which CO{sub 2} is leaking upward responds to the mass flow rate of CO{sub 2}-water mixture.

  11. Single and two-phase flow fluid dynamics in parallel helical coils (United States)

    De Salve, M.; Orio, M.; Panella, B.


    The design of helical coiled steam generators requires the knowledge of the single and two-phase fluid dynamics. The present work reports the results of an experimental campaign on single-phase and two phase pressure drops and void fraction in three parallel helicoidal pipes, in which the total water flow rate is splitted by means of a branch. With this test configuration the distribution of the water flow rate in the helicoidal pipes and the phenomena of the instability of the two-phase flow have been experimentally investigated.

  12. Symmetrical components and power analysis for a two-phase microgrid system

    DEFF Research Database (Denmark)

    Alibeik, M.; Santos Jr., E. C. dos; Blaabjerg, Frede


    This paper presents a mathematical model for the symmetrical components and power analysis of a new microgrid system consisting of three wires and two voltages in quadrature, which is designated as a two-phase microgrid. The two-phase microgrid presents the following advantages: 1) constant power...... through the power line at balanced condition; 2) two voltages available by using a three-wire system; 3) optimized voltage utilization compared to a three-phase system; and 4) a direct connection of both symmetrical two-phase and single-phase machines. Unlike the unbalanced three-phase system, which can...

  13. The Analysis of Nonlinear Vibrations of Top-Tensioned Cantilever Pipes Conveying Pressurized Steady Two-Phase Flow under Thermal Loading

    Directory of Open Access Journals (Sweden)

    Adeshina S. Adegoke


    Full Text Available This paper studied the nonlinear vibrations of top-tensioned cantilevered pipes conveying pressurized steady two-phase flow under thermal loading. The coupled axial and transverse governing partial differential equations of motion of the system were derived based on Hamilton’s mechanics, with the centerline assumed to be extensible. Using the multiple-scale perturbation technique, natural frequencies, mode shapes, and first order approximate solutions of the steady-state response of the pipes were obtained. The multiple-scale assessment reveals that at some frequencies the system is uncoupled, while at some frequencies a 1:2 coupling exists between the axial and the transverse frequencies of the pipe. Nonlinear frequencies versus the amplitude displacement of the cantilever pipe, conveying two-phase flow at super-critical mixture velocity for the uncoupled scenario, exhibit a nonlinear hardening behavior; an increment in the void fractions of the two-phase flow results in a reduction in the pipe’s transverse vibration frequencies and the coupled amplitude of the system. However, increases in the temperature difference, pressure, and the presence of top tension were observed to increase the pipe’s transverse vibration frequencies without a significant change in the coupled amplitude of the system.

  14. Prediction of friction pressure drop for low pressure two-phase flows on the basis of approximate analytical models (United States)

    Zubov, N. O.; Kaban'kov, O. N.; Yagov, V. V.; Sukomel, L. A.


    Wide use of natural circulation loops operating at low redused pressures generates the real need to develop reliable methods for predicting flow regimes and friction pressure drop for two-phase flows in this region of parameters. Although water-air flows at close-to-atmospheric pressures are the most widely studied subject in the field of two-phase hydrodynamics, the problem of reliably calculating friction pressure drop can hardly be regarded to have been fully solved. The specific volumes of liquid differ very much from those of steam (gas) under such conditions, due to which even a small change in flow quality may cause the flow pattern to alter very significantly. Frequently made attempts to use some or another universal approach to calculating friction pressure drop in a wide range of steam quality values do not seem to be justified and yield predicted values that are poorly consistent with experimentally measured data. The article analyzes the existing methods used to calculate friction pressure drop for two-phase flows at low pressures by comparing their results with the experimentally obtained data. The advisability of elaborating calculation procedures for determining the friction pressure drop and void fraction for two-phase flows taking their pattern (flow regime) into account is demonstrated. It is shown that, for flows characterized by low reduced pressures, satisfactory results are obtained from using a homogeneous model for quasi-homogeneous flows, whereas satisfactory results are obtained from using an annular flow model for flows characterized by high values of void fraction. Recommendations for making a shift from one model to another in carrying out engineering calculations are formulated and tested. By using the modified annular flow model, it is possible to obtain reliable predictions for not only the pressure gradient but also for the liquid film thickness; the consideration of droplet entrainment and deposition phenomena allows reasonable

  15. Verification, validation and application of NEPTUNE-CFD to two-phase Pressurized Thermal Shocks

    Energy Technology Data Exchange (ETDEWEB)

    Mérigoux, N., E-mail: [Electricité de France, R& D Division, 6 Quai Watier, 78401 Chatou (France); Laviéville, J.; Mimouni, S.; Guingo, M.; Baudry, C. [Electricité de France, R& D Division, 6 Quai Watier, 78401 Chatou (France); Bellet, S., E-mail: [Electricité de France, Thermal & Nuclear Studies and Projects Division, 12-14 Avenue Dutriévoz, 69628 Villeurbanne (France)


    Nuclear Power Plants are subjected to a variety of ageing mechanisms and, at the same time, exposed to potential Pressurized Thermal Shock (PTS) – characterized by a rapid cooling of the Reactor Pressure Vessel (RPV) wall. In this context, NEPTUNE-CFD is developed and used to model two-phase PTS in an industrial configuration, providing temperature and pressure fields required to assess the integrity of the RPV. Furthermore, when using CFD for nuclear safety demonstration purposes, EDF applies a methodology based on physical analysis, verification, validation and application to industrial scale (V&V), to demonstrate the quality of, and the confidence in results obtained. By following this methodology, each step must be proved to be consistent with the others, and with the final goal of the calculations. To this effect, a chart demonstrating how far the validation step of NEPTUNE-CFD is covering the PTS application will be drawn. A selection of the code verification and validation cases against different experiments will be described. For results consistency, a single and mature set of models – resulting from the knowledge acquired during the code development over the last decade – has been used. From these development and validation feedbacks, a methodology has been set up to perform industrial computations. Finally, the guidelines of this methodology based on NEPTUNE-CFD and SYRTHES coupling – to take into account the conjugate heat transfer between liquid and solid – will be presented. A short overview of the engineering approach will be given – starting from the meshing process, up to the results post-treatment and analysis.

  16. Elastically mediated interactions between grain boundaries and precipitates in two-phase coherent solids (United States)

    Xu, Ye-Chuan; Geslin, Pierre-Antoine; Karma, Alain


    We investigate analytically and numerically the interaction between grain boundaries and second phase precipitates in two-phase coherent solids in the presence of misfit strain. Our numerical study uses amplitude equations that describe the interaction of composition and stress [R. Spatschek and A. Karma, Phys. Rev. B 81, 214201 (2010), 10.1103/PhysRevB.81.214201] and free-energies corresponding to two-dimensional hexagonal and three-dimensional BCC crystal structures that exhibit isotropic and anisotropic elastic properties, respectively. We consider two experimentally motivated geometries where (i) a lamellar precipitate nucleates along a planar grain boundary that is centered inside the precipitate, and (ii) a circular precipitate nucleates inside a grain at a finite distance to an initially planar grain boundary. For the first geometry, we find that the grain boundary becomes morphologically unstable due to the combination of long-range elastic interaction between the grain boundary and compositional domain boundaries, and shear-coupled grain boundary motion. We characterize this instability analytically by extending the linear stability analysis carried out recently [P.-A. Geslin, Y.-C. Xu, and A. Karma, Phys. Rev. Lett. 114, 105501 (2015), 10.1103/PhysRevLett.114.105501] to the more general case of elastic anisotropy. The analysis predicts that elastic anisotropy hinders but does not suppress the instability. Simulations also reveal that, in a well-developed nonlinear regime, this instability can lead to the break-up of low-angle grain boundaries when the misfit strain exceeds a threshold that depends on the grain boundary misorientation. For the second geometry, simulations show that the elastic interaction between an initially planar grain boundary and an adjacent circular precipitate causes the precipitate to migrate to and anchor at the grain boundary.

  17. On the nonequilibrium segregation state of a two-phase mixture in a porous column

    DEFF Research Database (Denmark)

    Shapiro, Alexander; Stenby, Erling Halfdan


    The problem of segregation of a two-phase multicomponent mixture under the action of thermal gradient, gravity and capillary forces is studied with respect to component distribution in a thick oil-gas-condensate reservoir. Governing equations are derived on the basis of nonequilibrium thermodynam......The problem of segregation of a two-phase multicomponent mixture under the action of thermal gradient, gravity and capillary forces is studied with respect to component distribution in a thick oil-gas-condensate reservoir. Governing equations are derived on the basis of nonequilibrium...... thermodynamics. A steady state of the two-phase mixture with nonzero diffusion fluxes and exchange between phases is described. In the case of binary mixtures analytical formulae for saturation, component distribution and flow in the two-phase zone are obtained....

  18. Two-phase mixed media dielectric with macro dielectric beads for enhancing resistivity and breakdown strength (United States)

    Falabella, Steven; Meyer, Glenn A; Tang, Vincent; Guethlein, Gary


    A two-phase mixed media insulator having a dielectric fluid filling the interstices between macro-sized dielectric beads packed into a confined volume, so that the packed dielectric beads inhibit electro-hydrodynamically driven current flows of the dielectric liquid and thereby increase the resistivity and breakdown strength of the two-phase insulator over the dielectric liquid alone. In addition, an electrical apparatus incorporates the two-phase mixed media insulator to insulate between electrical components of different electrical potentials. And a method of electrically insulating between electrical components of different electrical potentials fills a confined volume between the electrical components with the two-phase dielectric composite, so that the macro dielectric beads are packed in the confined volume and interstices formed between the macro dielectric beads are filled with the dielectric liquid.

  19. Non-local two phase flow momentum transport in S BWR

    Energy Technology Data Exchange (ETDEWEB)

    Espinosa P, G.; Salinas M, L.; Vazquez R, A., E-mail: [Universidad Autonoma Metropolitana, Unidad Iztapalapa, Area de Ingenieria en Recursos Energeticos, Apdo. Postal 55-535, 09340 Ciudad de Mexico (Mexico)


    The non-local momentum transport equations derived in this work contain new terms related with non-local transport effects due to accumulation, convection, diffusion and transport properties for two-phase flow. For instance, they can be applied in the boundary between a two-phase flow and a solid phase, or in the boundary of the transition region of two-phase flows where the local volume averaging equations fail. The S BWR was considered to study the non-local effects on the two-phase flow thermal-hydraulic core performance in steady-state, and the results were compared with the classical local averaging volume conservation equations. (Author)

  20. Aqueous two-phase system (ATPS): an overview and advances in its applications

    National Research Council Canada - National Science Library

    Iqbal, Mujahid; Tao, Yanfei; Xie, Shuyu; Zhu, Yufei; Chen, Dongmei; Wang, Xu; Huang, Lingli; Peng, Dapeng; Sattar, Adeel; Shabbir, Muhammad Abu Bakr; Hussain, Hafiz Iftikhar; Ahmed, Saeed; Yuan, Zonghui


    Aqueous two-phase system (ATPS) is a liquid-liquid fractionation technique and has gained an interest because of great potential for the extraction, separation, purification and enrichment of proteins, membranes, viruses, enzymes...

  1. A Rotational Pressure-Correction Scheme for Incompressible Two-Phase Flows with Open Boundaries.

    Directory of Open Access Journals (Sweden)

    S Dong

    Full Text Available Two-phase outflows refer to situations where the interface formed between two immiscible incompressible fluids passes through open portions of the domain boundary. We present several new forms of open boundary conditions for two-phase outflow simulations within the phase field framework, as well as a rotational pressure correction based algorithm for numerically treating these open boundary conditions. Our algorithm gives rise to linear algebraic systems for the velocity and the pressure that involve only constant and time-independent coefficient matrices after discretization, despite the variable density and variable viscosity of the two-phase mixture. By comparing simulation results with theory and the experimental data, we show that the method produces physically accurate results. We also present numerical experiments to demonstrate the long-term stability of the method in situations where large density contrast, large viscosity contrast, and backflows occur at the two-phase open boundaries.

  2. Numerical simulation of two-phase flow with front-capturing

    Energy Technology Data Exchange (ETDEWEB)

    Tzanos, C. P.; Weber, D. P.


    Because of the complexity of two-phase flow phenomena, two-phase flow codes rely heavily on empirical correlations. This approach has a number of serious shortcomings. Advances in parallel computing and continuing improvements in computer speed and memory have stimulated the development of numerical simulation tools that rely less on empirical correlations and more on fundamental physics. The objective of this work is to take advantage of developments in massively parallel computing, single-phase computational fluid dynamics of complex systems, and numerical methods for front capturing in two-phase flows to develop a computer code for direct numerical simulation of two-phase flow. This includes bubble/droplet transport, interface deformation and topology change, bubble/droplet interactions, interface mass, momentum and energy transfer.

  3. Reversible, on-demand generation of aqueous two-phase microdroplets

    Energy Technology Data Exchange (ETDEWEB)

    Collier, Charles Patrick; Retterer, Scott Thomas; Boreyko, Jonathan Barton; Mruetusatorn, Prachya


    The present invention provides methods of on-demand, reversible generation of aqueous two-phase microdroplets core-shell microbeads, microparticle preparations comprising the core-shell microbeads, and drug delivery formulation comprising the microparticle preparations. Because these aqueous microdroplets have volumes comparable to those of cells, they provide an approach to mimicking the dynamic microcompartmentation of biomaterial that naturally occurs within the cytoplasm of cells. Hence, the present methods generate femtoliter aqueous two-phase droplets within a microfluidic oil channel using gated pressure pulses to generate individual, stationary two-phase microdroplets with a well-defined time zero for carrying out controlled and sequential phase transformations over time. Reversible phase transitions between single-phase, two-phase, and core-shell microbead states are obtained via evaporation-induced dehydration and water rehydration.

  4. Single and two-phase flow pressure drop for CANFLEX bundle

    Energy Technology Data Exchange (ETDEWEB)

    Park, Joo Hwan; Jun, Ji Su; Suk, Ho Chun [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of); Dimmick, G. R.; Bullock, D. E. [Atomic Energy of Canada Limited, Ontario (Canada)


    Friction factor and two-phase flow frictional multiplier for a CANFLEX bundle are newly developed and presented in this paper. CANFLEX as a 43-element fuel bundle has been developed jointly by AECL/KAERI to provide greater operational flexibility for CANDU reactor operators and designers. Friction factor and two-phase flow frictional multiplier have been developed by using the experimental data of pressure drops obtained from two series of Freon-134a (R-134a) CHF tests with a string of simulated CANFLEX bundles in a single phase and a two-phase flow conditions. The friction factor for a CANFLEX bundle is found to be about 20% higher than that of Blasius for a smooth circular pipe. The pressure drop predicted by using the new correlations of friction factor and two-phase frictional multiplier are well agreed with the experimental pressure drop data of CANFLEX bundle within {+-} 5% error. 11 refs., 5 figs. (Author)

  5. Critical Regimes of Two-Phase Flows with a Polydisperse Solid Phase

    CERN Document Server

    Barsky, Eugene


    This book brings to light peculiarities of the formation of critical regimes of two-phase flows with a polydisperse solid phase. A definition of entropy is formulated on the basis of statistical analysis of these peculiarities. The physical meaning of entropy and its correlation with other parameters determining two-phase flows are clearly defined. The interrelations and main differences between this entropy and the thermodynamic one are revealed. The main regularities of two-phase flows both in critical and in other regimes are established using the notion of entropy. This parameter serves as a basis for a deeper insight into the physics of the process and for the development of exhaustive techniques of mass exchange estimation in such flows. The book is intended for graduate and postgraduate students of engineering studying two-phase flows, and to scientists and engineers engaged in specific problems of such fields as chemical technology, mineral dressing, modern ceramics, microelectronics, pharmacology, po...

  6. Hybrid finite volume scheme for a two-phase flow in heterogeneous porous media*

    Directory of Open Access Journals (Sweden)

    Brenner Konstantin


    Full Text Available We propose a finite volume method on general meshes for the numerical simulation of an incompressible and immiscible two-phase flow in porous media. We consider the case that can be written as a coupled system involving a degenerate parabolic convection-diffusion equation for the saturation together with a uniformly elliptic equation for the global pressure. The numerical scheme, which is implicit in time, allows computations in the case of a heterogeneous and anisotropic permeability tensor. The convective fluxes, which are non monotone with respect to the unknown saturation and discontinuous with respect to the space variables, are discretized by means of a special Godunov scheme. We prove the existence of a discrete solution which converges, along a subsequence, to a solution of the continuous problem. We present a number of numerical results in space dimension two, which confirm the efficiency of the numerical method. Nous proposons un schéma de volumes finis hybrides pour la discrétisation d’un problème d’écoulement diphasique incompressible et immiscible en milieu poreux. On suppose que ce problème a la forme d’une équation parabolique dégénérée de convection-diffusion en saturation couplée à une équation uniformément elliptique en pression. On considère un schéma implicite en temps, où les flux diffusifs sont discrétisés par la méthode des volumes finis hybride, ce qui permet de pouvoir traiter le cas d’un tenseur de perméabilité anisotrope et hétérogène sur un maillage très général, et l’on s’appuie sur un schéma de Godunov pour la discrétisation des flux convectifs, qui peuvent être non monotones et discontinus par rapport aux variables spatiales. On démontre l’existence d’une solution discrète, dont une sous-suite converge vers une solution faible du problème continu. On présente finalement des cas test bidimensionnels.

  7. Bioconversion of apigenin-7-O-β-glucoside in aqueous two-phase system

    Directory of Open Access Journals (Sweden)

    Ilić Sanja M.


    Full Text Available The study is concerned with the conversion of apigenin-7-O-β-glucoside into apigenin in polyethylene glycol 6000 / dextran 20000 aqueous two-phase system by β-glucosidase. Apigenin was separated from apigenin-7-O-β-glucoside and β-glucosidase by their partition into opposite phases. In 14% PEG / 22.5% DEX aqueous two-phase system obtained yield of apigenin in top phase was 108%.

  8. Estimation of the sugar cane cultivated area from LANDSAT images using the two phase sampling method (United States)

    Parada, N. D. J. (Principal Investigator); Cappelletti, C. A.; Mendonca, F. J.; Lee, D. C. L.; Shimabukuro, Y. E.


    A two phase sampling method and the optimal sampling segment dimensions for the estimation of sugar cane cultivated area were developed. This technique employs visual interpretations of LANDSAT images and panchromatic aerial photographs considered as the ground truth. The estimates, as a mean value of 100 simulated samples, represent 99.3% of the true value with a CV of approximately 1%; the relative efficiency of the two phase design was 157% when compared with a one phase aerial photographs sample.

  9. In-step Two-phase Flow (TPF) Thermal Control Experiment (United States)


    The Two-Phase Flow Thermal Control Experiment is part of the NASA/OAST In-Space Technology Experiments (In-STEP) Program. The experiment is configured for the Hitchhiker Shuttle payload system and consists of a capillary pumped loop, heatpipe radiator, and two-phase flow heat exchanger. The flight experiment design approach, test plan, payload design, and test components are described in outline and graphic form.

  10. Measurement of local two-phase flow parameters of nanofluids using conductivity double-sensor probe

    Directory of Open Access Journals (Sweden)

    Park Yu sun


    Full Text Available Abstract A two-phase flow experiment using air and water-based γ-Al2O3 nanofluid was conducted to observe the basic hydraulic phenomenon of nanofluids. The local two-phase flow parameters were measured with a conductivity double-sensor two-phase void meter. The void fraction, interfacial velocity, interfacial area concentration, and mean bubble diameter were evaluated, and all of those results using the nanofluid were compared with the corresponding results for pure water. The void fraction distribution was flattened in the nanofluid case more than it was in the pure water case. The higher interfacial area concentration resulted in a smaller mean bubble diameter in the case of the nanofluid. This was the first attempt to measure the local two-phase flow parameters of nanofluids using a conductivity double-sensor two-phase void meter. Throughout this experimental study, the differences in the internal two-phase flow structure of the nanofluid were identified. In addition, the heat transfer enhancement of the nanofluid can be resulted from the increase of the interfacial area concentration which means the available area of the heat and mass transfer.

  11. Measurement of local two-phase flow parameters of nanofluids using conductivity double-sensor probe. (United States)

    Park, Yu Sun; Chang, Soon Heung


    A two-phase flow experiment using air and water-based γ-Al2O3 nanofluid was conducted to observe the basic hydraulic phenomenon of nanofluids. The local two-phase flow parameters were measured with a conductivity double-sensor two-phase void meter. The void fraction, interfacial velocity, interfacial area concentration, and mean bubble diameter were evaluated, and all of those results using the nanofluid were compared with the corresponding results for pure water. The void fraction distribution was flattened in the nanofluid case more than it was in the pure water case. The higher interfacial area concentration resulted in a smaller mean bubble diameter in the case of the nanofluid. This was the first attempt to measure the local two-phase flow parameters of nanofluids using a conductivity double-sensor two-phase void meter. Throughout this experimental study, the differences in the internal two-phase flow structure of the nanofluid were identified. In addition, the heat transfer enhancement of the nanofluid can be resulted from the increase of the interfacial area concentration which means the available area of the heat and mass transfer.

  12. Two-Phase Bactericidal Mechanism of Silver Nanoparticles against Burkholderia pseudomallei.

    Directory of Open Access Journals (Sweden)

    Pawinee Siritongsuk

    Full Text Available Silver nanoparticles (AgNPs have a strong antimicrobial activity against a variety of pathogenic bacteria. The killing mechanism of AgNPs involves direct physical membrane destruction and subsequent molecular damage from both AgNPs and released Ag+. Burkholderia pseudomallei is the causative agent of melioidosis, an endemic infectious disease primarily found in northern Australia and Southeast Asia. B. pseudomallei is intrinsically resistant to most common antibiotics. In this study, the antimicrobial activity and mechanism of AgNPs (10-20 nm against B. pseudomallei were investigated. The MIC and MBC for nine B. pseudomallei strains ranged from 32-48 μg/mL and 96-128 μg/mL, respectively. Concentrations of AgNPs less than 256 μg/mL were not toxic to human red blood cells. AgNPs exhibited a two-phase mechanism: cell death induction and ROS induction. The first phase was a rapid killing step within 5 min, causing the direct damage of the cytoplasmic membrane of the bacterial cells, as observed by a time-kill assay and fluorescence microscopy. During the period of 5-30 min, the cell surface charge was rapidly neutralized from -8.73 and -7.74 to 2.85 and 2.94 mV in two isolates of B. pseudomallei, as revealed by zeta potential measurement. Energy-dispersive X-ray (EDX spectroscopy showed the silver element deposited on the bacterial membrane, and TEM micrographs of the AgNP-treated B. pseudomallei cells showed severe membrane damage and cytosolic leakage at 1/5 MIC and cell bursting at MBC. During the killing effect the released Ag+ from AgNPs was only 3.9% from the starting AgNPs concentration as observed with ICP-OES experiment. In the second phase, the ROS induction occurred 1-4 hr after the AgNP treatment. Altogether, we provide direct kinetic evidence of the AgNPs killing mechanism, by which cell death is separable from the ROS induction and AgNPs mainly contributes in the killing action. AgNPs may be considered a potential candidate to

  13. Design, Modelling and Simulation of Two-Phase Two-Stage Electronic System with Orthogonal Output for Supplying of Two-Phase ASM

    Directory of Open Access Journals (Sweden)

    Michal Prazenica


    Full Text Available This paper deals with the two-stage two-phase electronic systems with orthogonal output voltages and currents - DC/AC/AC. Design of two-stage DC/AC/AC high frequency converter with two-phase orthogonal output using single-phase matrix converter is also introduced. Output voltages of them are strongly nonharmonic ones, so they must be pulse-modulated due to requested nearly sinusoidal currents with low total harmonic distortion. Simulation experiment results of matrix converter for both steady and transient states for IM motors are given in the paper, also experimental verification under R-L load, so far. The simulation results confirm a very good time-waveform of the phase current and the system seems to be suitable for low-cost application in automotive/aerospace industries and application with high frequency voltage sources.

  14. Determination of the major constituents in fruit of Arctium lappa L. by matrix solid-phase dispersion extraction coupled with HPLC separation and fluorescence detection. (United States)

    Liu, He; Zhang, Yupu; Sun, Yantao; Wang, Xue; Zhai, Yujuan; Sun, Ye; Sun, Shuo; Yu, Aimin; Zhang, Hanqi; Wang, Yinghua


    The arctiin and arctigenin in the fruit of Arctium lappa L. were extracted by matrix solid-phase dispersion (MSPD) and determined by high-performance liquid chromatography (HPLC) with fluorescence detection. The experimental conditions for the MSPD were optimized. Silica gel was selected as dispersion adsorbent and methanol as elution solvent. The calibration curve showed good relationship (r>0.9998) in the concentration range of 0.010-5.0μgmL(-1) for arctiin and 0.025-7.5μgmL(-1) for arctigenin. The recoveries were between 74.4% and 100%. The proposed method consumed less sample, time and solvent compared with conventional methods, including ultrasonic and Soxhlet extraction. Copyright © 2010 Elsevier B.V. All rights reserved.

  15. Ionic-liquid-based dispersive liquid-liquid microextraction coupled with high-performance liquid chromatography for the forensic determination of methamphetamine in human urine. (United States)

    Wang, Ruifeng; Qi, Xiujuan; Zhao, Lei; Liu, Shimin; Gao, Shuang; Ma, Xiangyuan; Deng, Youquan


    Determination of methamphetamine in forensic laboratories is a major issue due to its health and social harm. In this work, a simple, sensitive, and environmentally friendly method based on ionic liquid dispersive liquid-liquid microextraction combined with high-performance liquid chromatography was established for the analysis of methamphetamine in human urine. 1-Octyl-3-methylimidazolium hexafluorophosphate with the help of disperser solvent methanol was selected as the microextraction solvent in this process. Various parameters affecting the extraction efficiency of methamphetamine were investigated systemically, including extraction solvent and its volume, disperser solvent and its volume, sample pH, extraction temperature, and centrifugal time. Under the optimized conditions, a good linearity was obtained in the concentration range of 10-1000 ng/mL with determination coefficient >0.99. The limit of detection calculated at a signal-to-noise ratio of 3 was 1.7 ng/mL and the relative standard deviations for six replicate experiments at three different concentration levels of 100, 500, and 1000 ng/mL were 6.4, 4.5, and 4.7%, respectively. Meanwhile, up to 220-fold enrichment factor of methamphetamine and acceptable extraction recovery (>80.0%) could be achieved. Furthermore, this method has been successfully employed for the sensitive detection of a urine sample from a suspected drug abuser. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. High resolution NMR study of T1 magnetic relaxation dispersion. III. Influence of spin 1/2 hetero-nuclei on spin relaxation and polarization transfer among strongly coupled protons. (United States)

    Korchak, Sergey E; Ivanov, Konstantin L; Pravdivtsev, Andrey N; Yurkovskaya, Alexandra V; Kaptein, Robert; Vieth, Hans-Martin


    Effects of spin-spin interactions on the nuclear magnetic relaxation dispersion (NMRD) of protons were studied in a situation where spin ½ hetero-nuclei are present in the molecule. As in earlier works [K. L. Ivanov, A. V. Yurkovskaya, and H.-M. Vieth, J. Chem. Phys. 129, 234513 (2008); S. E. Korchak, K. L. Ivanov, A. V. Yurkovskaya, and H.-M. Vieth, ibid. 133, 194502 (2010)], spin-spin interactions have a pronounced effect on the relaxivity tending to equalize the longitudinal relaxation times once the spins become strongly coupled at a sufficiently low magnetic field. In addition, we have found influence of (19)F nuclei on the proton NMRD, although in the whole field range, studied protons and fluorine spins were only weakly coupled. In particular, pronounced features in the proton NMRD were found; but each feature was predominantly observed only for particular spin states of the hetero-nuclei. The features are explained theoretically; it is shown that hetero-nuclei can affect the proton NMRD even in the limit of weak coupling when (i) protons are coupled strongly and (ii) have spin-spin interactions of different strengths with the hetero-nuclei. We also show that by choosing the proper magnetic field strength, one can selectively transfer proton spin magnetization between spectral components of choice.

  17. Scale-up of two-phase flow in heterogeneous chalk. Matrix properties

    Energy Technology Data Exchange (ETDEWEB)



    This investigation presents scale-up of a detailed heterogeneous geostatistical model to a full field reservoir simulation model, considering both single and two-phase flow properties. The model represents a typical low permeability Danish North Sea chalk reservoir and includes capillary pressure and saturation end-point variations. Two new up-scaling methods has been investigated, all based on fine scale simulation on a cross section of the geomodel. The first methods assumes piston style behaviour and a coupled viscosity is introduced into the basic Darcy`s equations. The second method is a modification of the JBN method traditionally applied in analysing results from core flooding experiments, which emerged as the most successful and therefore also the recommended method. 1. In addition to the up scaling work we review the Equivalent Radius Method for capillary pressure normalisation with explicit derivation of type functions for Maastrichtian and Danian chalk types. Implementation of the Equivalent Radiuo Method in the COSI reservoir simulator by an optikal set of key-words. There are six specific results from this work: 1. The equivalent radius method is robust to changes of scale and yields model initialisations by initial and irreducible water saturations on a full field simulation scale that agree well with values derived from averaging on a fine-scale. 2. The residual oil saturations are strongly scale dependent and the description of the residual oil as a function of the irreducible water is not applicable on a full field scale and will lead to an overestimation of the residual oil present in the reservoir. The effective residual oil saturations on a full field-scale must be considered functions of the effective initial water saturations, in order to take into account fine-scale variations in the oil/water contacts. 3. The effective permeability as calculated by statistical averages does not differ seriously from results obtained by fine-grid numerical

  18. An experimental study of single-phase and two-phase flow in annular helicoidal pipes

    Energy Technology Data Exchange (ETDEWEB)

    Xin, R.C.; Awwad, A.; Dong, Z.F.; Ebadian, M.A. [Florida International Univ., Miami, FL (United States). Hemispheric Center for Environmental Technology


    In this study, experimental investigations were conducted for single-phase and two-phase flow in annular helicoidal pipes with vertical and horizontal orientations using air and water as working fluids. Three test sections were tested. The outer diameters of the inner tube were 12.7 mm, 9.525 mm, and 6.35 mm, while the inner diameters of the outer tube were 21.18 mm, 15.748 mm, and 10.21 mm, respectively. The experiments were performed for superficial water Reynolds numbers in the range of 210--23,000 and superficial air Reynolds numbers in the range of 30--30,000. The effects of coil geometry and the flow rates of air and water on single-phase and two-phase flow pressure drop were experimentally investigated for annular helicoidal pipes. The data were correlated as the relationship of the pressure drop multiplier versus the Lockhart-Martinelli parameter for the two-phase flow. The average void fraction was also measured in the experiments by means of the quick acting valve method. Unlike two-phase flow in straight pipe, the pressure drop multiplier of two-phase flow in annular helicoidal pipe has been found to be dependent on the flow rate besides the Lockhart-Martinelli parameter for large pipe diameter in annular helicoidal pipe. The Lockhart-Martinelli correlation is not valid in the prediction. Correlations for two-phase flow in horizontal and vertical annular helicoidal pipe have been established for both single-phase and two-phase flow based on the present experimental data.

  19. Fundamentals of gravity level dependent two-phase flow and heat transfer-A tutorial (United States)

    Delil, A. A. M.


    Multiphase flow, the simultaneous flow of the different phases (states of matter) gas, liquid and solid, strongly depends on the level and direction of gravitation, since these influence the spatial distribution of the phases, having different densities. Many investigations concern behavior of liquid-solid flows (e.g. in mixing, crystal growing, or materials processing) or gas-solid flows (e.g. in cyclones or combustion equipment). But of major interest for aerospace applications are the more complicated liquid-vapor or liquid-gas flows, being characteristic for aerospace thermal control systems, life sciences systems and propellant systems. Especially for liquid-vapor flow in aerospace two-phase thermal control systems, the phenomena become extremely complicated, because of heat and mass exchange between the phases by evaporation, condensation, and flashing. Though very many publications (textbooks, conference proceedings, journal articles) concern two-phase flow and heat transfer, publications on the impact of reduced gravity are very scarce. This is the main driver for carrying out research in micro-gravity. Various heat and mass transfer issues of two-phase heat transport technology for space applications are discussed, focusing on the most complicated case of liquid-vapor flow with heat and mass exchange. Simpler cases, like adiabatic or isothermal liquid-vapor flow or liquid-gas flow, can be derived from this case, by setting various terms in the constitutive equations equal to zero. The discussions start with the background of the research, followed by a short description of two-phase flow and heat transfer phenomena. The impact of the gravity level will be assessed, including development supporting theoretical work: Thermal/gravitational scaling of two-phase flow and heat transport in two-phase thermal control loops, including gravity level dependent two-phase flow pattern mapping and condensation issues. Outcomes of theoretical work are compared with

  20. First demonstration of THGEM/GAPD-matrix optical readout in a two-phase Cryogenic Avalanche Detector in Ar

    Energy Technology Data Exchange (ETDEWEB)

    Bondar, A. [Budker Institute of Nuclear Physics, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, Pirogov Street 2, 630090 Novosibirsk (Russian Federation); Buzulutskov, A., E-mail: [Budker Institute of Nuclear Physics, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, Pirogov Street 2, 630090 Novosibirsk (Russian Federation); Dolgov, A. [Novosibirsk State University, Pirogov Street 2, 630090 Novosibirsk (Russian Federation); Grebenuk, A. [Budker Institute of Nuclear Physics, 630090 Novosibirsk (Russian Federation); Shemyakina, E.; Sokolov, A. [Budker Institute of Nuclear Physics, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, Pirogov Street 2, 630090 Novosibirsk (Russian Federation); Breskin, A. [Weizmann Institute of Science, 76100 Rehovot (Israel); Thers, D. [SUBATECH, Ecole des Mines de Nantes, CNRS/In2p3, Université de Nantes, 44307 Nantes Cedex 3 (France)


    The multi-channel optical readout of a THGEM multiplier coupled to a matrix of 3×3 Geiger-mode APDs (GAPDs) was demonstrated in a two-phase Cryogenic Avalanche Detector (CRAD) in Ar. The GAPDs recorded THGEM-hole avalanches in the Near Infrared (NIR) spectral range. At an avalanche charge gain of 160, the yield of the combined THGEM/GAPD-matrix multiplier amounted to ∼80 photoelectrons per 20 keV X-ray absorbed in the liquid phase. A spatial resolution of 2.5 mm (FWHM) has been measured for the impinging X-rays. This technique has potential applications in coherent neutrino-nucleus scattering and in dark matter search experiments.

  1. Simultaneous determination of eight alkaloids and oleandrin in herbal cosmetics by dispersive solid-phase extraction coupled with ultra high performance liquid chromatography and tandem mass spectrometry. (United States)

    Xun, Zhiqing; Liu, Donghong; Huang, Rongrong; He, Shuang; Hu, Du; Guo, Xindong; Xian, Yanping


    We utilized ultra-high performance liquid chromatography with tandem mass spectrometry and dispersive solid-phase extraction to develop a new method for the detection of nine analytes (scopolamine, cephaeline, strychnine, hyoscyamine, brucine, hydrastine, ajmalicine, colchicine, and oleandrin) in herbal cosmetics. Acetonitrile/water and 2-propylaminoethylamine were used to disperse and purify during the dispersive solid-phase extraction step. The analytes were separated by a Waters UPLC HSS T3 column and detected through electrospray ionization source in the positive mode with multi-reaction monitoring conditions. Under the optimal conditions, the calibration curves were linear in the range of 0.2-100.0 μg/L with the correlation coefficients higher than 0.995. The method limit of quantitation (S/N = 10) were 5.0 μg/kg for oleandrin and 1.0 μg/kg for the other eight alkaloids. The mean recoveries at three spiked concentration levels of 1.0-10.0 μg/kg were in the range of 86.9-116.5% with the intra-day relative standard deviations (n = 6) ranging from 2.4 to 8.8%, and inter-day relative standard deviations ranging from 2.7 to 5.7%. This method is accurate, simple and rapid, and has been applied to the quality supervision of herbal cosmetics in Guangzhou. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. A coupled nearfield and farfield large-eddy simulation for oil transport from deep-water blowouts - a study of the effects of dispersant in the Deepwater Horizon accident (United States)

    Chamecki, M.; Chen, B.; Yang, D.; Meneveau, C. V.


    The Deepwater Horizon accident and the ensuing oil leak at 1.5 km depth in the Gulf of Mexico focused attention on the challenges associated with underwater blowouts in the deep ocean. The strategy adopted for use of chemical dispersants during the leak was, and it still is, one of the most controversial points in the response effort. This work investigates the effects of dispersant applications to oil transport using idealized high-resolution numerical simulations. Deep-water blowouts generate plumes of oil droplets and gas bubbles that rise through, and interact with, various layers of the ocean. The different scales and physical processes governing the dynamics of the oil plume at each layer require different numerical simulation strategies. We develop a high-fidelity turbulence-resolving numerical model using the large-eddy simulation technique which consists of two modules targeting two distinguished stages of the oil plume dispersion: "nearfiled" and "farfield". The "nearfield module" simulates the dynamics of the multiphase plume containing gas bubbles and oil droplets originating from the oil well and rising through the 1.5 km stratified water column. The formation of deep-water intrusions and the separation of oil and gas plumes due to weak crossflow is captured by LES. As the oil plume approaches the bottom of the ocean mixed layer, the "farfield module" takes over and simulates the near-surface oil transport using a new numerical approach called ENDLESS (extended nonperiodic domain LES for scalars) to accommodate the fairly large horizontal extent of the plume. ENDLESS is a multiscale plume modeling approach, which permits simulations of oil plumes including effects of submesoscale eddies, surface waves, Langmuir cells, and 3D small-scale turbulence with reasonable computing power. The two simulation modules are coupled, allowing the representation of the entire plume in a turbulence-resolving context. Simulations are performed to elucidate the effect of

  3. Biofilm Dispersal (United States)


    Like all sessile organisms, surface-attached communities of bacteria known as biofilms must release and disperse cells into the environment to colonize new sites. For many pathogenic bacteria, biofilm dispersal plays an important role in the transmission of bacteria from environmental reservoirs to human hosts, in horizontal and vertical cross-host transmission, and in the exacerbation and spread of infection within a host. The molecular mechanisms of bacterial biofilm dispersal are only beginning to be elucidated. Biofilm dispersal is a promising area of research that may lead to the development of novel agents that inhibit biofilm formation or promote biofilm cell detachment. Such agents may be useful for the prevention and treatment of biofilms in a variety of industrial and clinical settings. This review describes the current status of research on biofilm dispersal, with an emphasis on studies aimed to characterize dispersal mechanisms, and to identify environmental cues and inter- and intracellular signals that regulate the dispersal process. The clinical implications of biofilm dispersal and the potential therapeutic applications of some of the most recent findings will also be discussed. PMID:20139339

  4. Design and evaluation of a two-phase turbine for low quality steam--water mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Comfort, W.J. III


    A new two-phase turbine was designed and built for testing in the laboratory, using a low quality steam-water mixture as a working fluid. The measured performance compares well with performance predictions of a numerical model of the expander. Details of the selection of the type of expander are given. The design of an experimental expander for use in a clean two-phase flow laboratory experiment and the development of a numerical model for performance analysis and extrapolations are described. Experiments including static cascade performance with two-phase fluid, disk friction and windage measurements, and two-phase performance measurements of the experimental expander are reported. Comparisons of the numerical model and experimental results, and the prediction of the performance of an advanced design, indicating how performance improvements can be achieved, are also included. An engine efficiency of 23 percent for a single-nozzle test was measured. Full admission performance, based upon the numerical model and achievable nozzle thrust coefficients indicate that an engine efficiency of between 38 and 48 percent can be realized with present technology. If maximum liquid removal loss is assumed, this performance range is predicted to be 38 to 41 percent. Droplet size reduction and the development and implementation of enhanced two-phase flow analysis techniques should make it possible to achieve the research goal of 70 percent engine efficiency.

  5. Evaluation of outflow boundary conditions for two-phase lattice Boltzmann equation. (United States)

    Lou, Qin; Guo, Zhaoli; Shi, Baochang


    Outflow boundary condition (OBC) is a critical issue in computational fluid dynamics. As a type of numerical method for fluid flows, the lattice Boltzmann equation (LBE) method has gained much success in a variety of complex flows, and certain OBCs have been suggested for the LBE in simulating simple single-phase flows. However, very few discussions on the OBCs have been made for the two-phase LBE method. In this work, three types of OBCs that are widely used in the LBE for single-phase flows, i.e., the Neumann boundary condition, the convective boundary condition, and the extrapolation boundary condition, are extended to a two-phase LBE method and their performances are investigated. The comprehensive results of several two-phase flows show that these boundary conditions behave quite differently in the simulations of two-phase flows. Specifically, it is found that the Neumann boundary condition and the extrapolation boundary condition give rather poor predictions, while the type of convective boundary conditions work well, although the choice of the convection velocity has some slight influences on the results. We also apply these OBC schemes to some other two-phase models, and similar observations are found.

  6. A Robust Asymptotically Based Modeling Approach for Two-Phase Flows

    Directory of Open Access Journals (Sweden)

    M. M. Awad


    Full Text Available A simple semitheoretical method for calculating two-phase frictional pressure gradient in horizontal circular pipes using asymptotic analysis to develop a robust compact model is presented. Two-phase frictional pressure gradient is expressed in terms of the asymptotic single-phase frictional pressure gradients for liquid and gas flowing alone. The proposed model can be transformed into either a two-phase frictional multiplier for liquid flowing alone (ϕl2 or two-phase frictional multiplier for gas flowing alone (ϕg2 as a function of the Lockhart-Martinelli parameter, X. Single-phase friction factors are calculated using the Churchill model which allows for prediction over the full range of laminar-transition-turbulent regions and allows for pipe roughness effects. The proposed model is compared against published data to show the asymptotic behavior. Comparison with other existing correlations for two-phase frictional pressure gradient such as the Chisholm correlation, the Friedel correlation, and the Müller-Steinhagen and Heck correlation, is also presented. Comparison with experimental data for both ϕl and ϕl versus X is also presented. At the end of the paper, the present asymptotic model is also extended to minichannels and microchannels.

  7. Quantification of endogenous brassinosteroids in sub-gram plant tissues by in-line matrix solid-phase dispersion-tandem solid phase extraction coupled with high performance liquid chromatography-tandem mass spectrometry. (United States)

    Wang, Lu; Duan, Chunfeng; Wu, Dapeng; Guan, Yafeng


    A matrix solid-phase dispersion (MSPD)-tandem mixed mode anion exchange (MAX)-mixed mode cation exchange (MCX) solid phase extraction-high performance liquid chromatography coupled with tandem mass spectrometry (HPLC-MS/MS) method was developed for quantification of six endogenous brassinosteroids (BRs) (24-epibrassinolide, 24-epicastasterone, 6-deoxo-24-epicastasterone, dolichosterone, teasterone and typhasterol) in rice plant tissues. Non-polar interferences were removed effectively by C8 dispersant used in MSPD, while the following tandem MAX-MCX process facilitated the elimination of polar and ionizable compounds. The weak reversed-phase retention feature of MAX-MCX leaded to good compatibility of the elution solvents in the in-line coupled MSPD-MAX-MCX system. This system was optimized for extraction and purification of BRs in plant samples. The effects of the type of solid phase, the elution solvent, the extraction temperature and the clean-up material were studied. Before HPLC separation, BRs purified were derivatized by m-aminophenylboronic acid to enhance the sensitivity of MS/MS to BRs. Compared with traditional liquid-liquid extraction and solid phase extraction (LLE-SPE), the proposed MSPD-MAX-MCX method showed higher extraction efficiency, lower matrix effect, and advantages of easy manipulation and time-saving. The in-line MSPD-MAX-MCX coupled with HPLC-MS/MS method provided a linear response over two orders of magnitude of BRs concentration with correlation coefficients above 0.9982, limits of detection between 0.008 and 0.04ngmL(-1), relative standard deviations (RSDs) below 29.4%, and recoveries above 77.8%. The proposed method has been successfully applied to analysis of endogenous BRs in rice plant at booting stage and maturity stage. Copyright © 2014 Elsevier B.V. All rights reserved.

  8. Development of matrix solid-phase dispersion coupled with high-performance liquid chromatography for determination of jolkinolide A and jolkinolide B in Euphorbia fischeriana Steud. (United States)

    Cai, Defu; Zhai, Weiyu; Zhang, Qi; Liu, Jianhua; Sun, Yu; Liu, Lei; Liu, Jicheng


    A novel and simple method was established for the extraction and determination of jolkinolide A and B in Euphorbia fischeriana Steud. using matrix solid-phase dispersion (MSPD) extraction and high-performance liquid chromatography (HPLC). The optimised conditions for the MSPD extraction were determined to be that silica gel was served as dispersant, the mass ratio of sample to silica gel was selected to be 1:4, and 5 mL of acetonitrile was used as elution solvent. The method exhibited a good performance in terms of linearity (r2 ≥ 0.9997) and the limits of detection in the range of 0.052-0.065 μg mL-1. The recoveries were in the range of 90.2-98.9% with relative standard deviations (RSDs) ranging from 1.3 to 3.5%. The extraction efficiencies obtained by the MSPD were higher than other extraction method with less cost of sample and solvent. At last, the optimised method was applied for analysing real samples.

  9. Determination of coumaphos, chlorpyrifos and ethion residues in propolis tinctures by matrix solid-phase dispersion and gas chromatography coupled to flame photometric and mass spectrometric detection. (United States)

    Pérez-Parada, Andrés; Colazzo, Marcos; Besil, Natalia; Geis-Asteggiante, Lucía; Rey, Federico; Heinzen, Horacio


    A new analytical method has been developed and successfully evaluated in routine application for the quantitative analysis of a selected group of organophosphate pesticides (coumaphos, chlorpyrifos and ethion) which can be found at trace levels in propolis tinctures (ethanolic propolis extracts); a valuable commodity used as raw material in the food and pharmaceutical industries for which there have been few attempts for pesticide residue analysis reported in the literature. The proposed methodology is based on matrix solid phase dispersion (MSPD) using aluminum sulfate anh. a novel dispersant material and subsequent column chromatography clean-up in silica gel prior to gas chromatography (GC) with both flame photometric detector (FPD) and mass spectrometry (MS) detection used for the routine quantification and identification of the residues, respectively. The limits of detection, for coumaphos, chlorpyrifos and ethion were below 26.0 μg/kg in FPD and 1.43 μg/kg for MS detection. Mean recoveries were in the range of 85-123% with RSD values below 13%, which suggests that the proposed method is fit for the purpose of analyzing pesticides in propolis tinctures containing high concentration of polyphenolics. The method has been successfully applied in our laboratory for the last 2 year in the analysis of real propolis tinctures samples. Copyright © 2011 Elsevier B.V. All rights reserved.

  10. Determination of strobilurin fungicides in cotton seed by combination of acetonitrile extraction and dispersive liquid-liquid microextraction coupled with gas chromatography. (United States)

    Xue, Jiaying; Li, Huichen; Liu, Fengmao; Jiang, Wenqing; Chen, Xiaochu


    The simultaneous determination of four strobilurin fungicides (picoxystrobin, kresoxim-methyl, trifloxystrobin, and azoxystrobin) in cotton seed by combining acetonitrile extraction and dispersive liquid-liquid microextraction was developed prior to GC with electron capture detection. Several factors, including the type and volume of the extraction and dispersive solvents, extraction condition and time, and salt addition, were optimized. The analytes were extracted with acetonitrile from cotton seed and the clean-up was carried out by primary secondary amine. Afterwards, 60 μL of n-hexane/toluene (1:1, v/v) with a lower density than water was mixed with 1 mL of the acetonitrile extract, then the mixture was injected into 7 mL of distilled water. A 0.1 mL pipette was used to collect a few microliters of n-hexane/toluene from the top of the aqueous solution. The enrichment factors of the analytes ranged from 36 to 67. The LODs were in the range of 0.1 × 10(-3) -2 × 10(-3) mg/kg. The relative recoveries varied from 87.7 to 95.2% with RSDs of 4.1-8.5% for the four fungicides. The good performance of the method, compared with the conventional pretreatments, has demonstrated it is suitable for determining low concentrations of strobilurin fungicide residues in cotton seed. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Optical biosensor with dispersion compensation. (United States)

    Zong, W; Thirstrup, C; Sørensen, M H; Pedersen, H C


    Dispersion limits performance in many optical systems. In surface plasmon resonance (SPR) biosensors, the sensing area is an optical element in which the dispersion depends on the effective refractive index of the biochemical compounds to be measured. We report a method of compensating for wavelength dispersion in SPR biosensors employing two integrated diffractive optical coupling elements in a polymer substrate. The dispersion compensation is achieved over the whole dynamic measurement range and provides a biosensor more robust to wavelength fluctuations than prism-coupler SPR systems. The concept can readily be employed in other types of sensor measuring refractive-index changes.

  12. Two-fluid model for reacting turbulent two-phase flows (United States)

    Chan, S. H.; Abou-Ellail, M. M. M.


    A reacting two-fluid model, based on the solution of separate transport equations for reacting gas-liquid two-phase flow, is presented. New time-mean transport equations for two-phase mixture fraction bar-f and its variance g are derived. The new two-fluid transport equations for bar-f and g are useful for two-phase reacting flows in which phases strongly interact. They are applicable to both submerged and nonsubmerged combustion. A pdf approach to the reaction process is adopted. The mixture fraction pdf assumes the shape of a beta function while the instantaneous thermochemical properties are computed from an equilibrium model. The proposed two-fluid model is verified by predicting turbulent flow structures of an n-pentane spray flame and a nonreacting bubbly jet flow for which experimental data exist. Good agreement is found between the predictions and the corresponding experimental data.

  13. A flow pattern map for two-phase liquid-gas flow under reduced gravity conditions (United States)

    Rezkallah, K. S.; Zhao, L.


    Two-phase gas-liquid flows have a wide range of applications in space including the flow of cryogenics in transport lines and heat-transfer fluids in a thermal control system. The behavior of these systems under reduced gravity must be understood in order to optimize the design and maintenance of such systems. Experimental studies on two-phase flow patterns and their transitions were conducted aboard the NASA KC-135 aircraft. A large set of flow pattern data for water-air and glycerin/water-air of different viscosities was reported. It was shown that two-phase flow under reduced gravity can be classified into four glow patterns: bubbly, slug, frothy slug-annular, and annular flows. Transitions between slug and frothy slug-annular, and frothy slug-annular and annular flows were predicted well using the liquid and gas Weber numbers as the mapping coordinates.

  14. Adaptive sampling in two-phase designs: a biomarker study for progression in arthritis (United States)

    McIsaac, Michael A; Cook, Richard J


    Response-dependent two-phase designs are used increasingly often in epidemiological studies to ensure sampling strategies offer good statistical efficiency while working within resource constraints. Optimal response-dependent two-phase designs are difficult to implement, however, as they require specification of unknown parameters. We propose adaptive two-phase designs that exploit information from an internal pilot study to approximate the optimal sampling scheme for an analysis based on mean score estimating equations. The frequency properties of estimators arising from this design are assessed through simulation, and they are shown to be similar to those from optimal designs. The design procedure is then illustrated through application to a motivating biomarker study in an ongoing rheumatology research program. Copyright © 2015 © 2015 The Authors. Statistics in Medicine Published by John Wiley & Sons Ltd. PMID:25951124

  15. Gas Bubbles and Slugs Crossover in Air-Water Two-phase Flow by Multifractals (United States)

    Gorski, Grzegorz; Litak, Grzegorz; Mosdorf, Romuald; Rysak, Andrzej


    Slugs and bubbles two-phase flow patterns dynamics in a minichannel are analysed. During the experiment, the volume flow rates of air and water were changed. We study transition of bubbles to slugs two-phase flow patterns using Fourier and multifractal approaches to optical transitivity signal. The sequences of light transmission time series are recorded by a laser-phototransistor sensor. Multifractal analysis helps to identify the two-phase structure and estimate the signal complexity. Especially, we discuss occurrence and identification of a self-aggregation phenomenon. These results are compared to corresponding Fourier spectra. The results indicate that the fractality is a an important factor influencing the distribution of the gas phase in water.

  16. Study on performance of squeeze film damper with oil-air two-phase fluid (United States)

    Shen, Xinmin; Li, Qihan; Du, Lijie


    This paper presents an analytical method for the lubrication film performance of a squeeze film damper with oil-air two-phase fluid, on the basis of the testing results and numerical analysis of oil film cavitation. The calculational results for the pressure distribution of lubrication oil film are in good agreement with the experimental results. The damper performance data obtained from two-phase fluid analysis are also compared with the results calculated by pure oil film damper. It is proven that the data can be used for the engineering analyses. The analytical method can be extended for the other bearings with similar lubrication film of oil-air two-phase fluid.

  17. Chirality Separation of Single-Wall Carbon Nanotubes using Aqueous Two-Phase Extraction (United States)

    Fagan, Jeffrey


    Aqueous two-phase extraction (ATPE) was recently demonstrated to enable the separation of individual species of single-wall carbon nanotubes (SWCNTs) across the separated phases. In this presentation I will describe the use of a dextran - polyethylene glycol aqueous two-phase system along with a separation scheme of varying surfactant concentrations to enable isolation at high purity of specific small diameter SWCNT species. Separation by ATPE is rapid and robust, with a remarkable tunability that allows isolation of most single nanotube chiralities at high purity. Choice of surfactant(s), temperature, polymer concentrations, and the addition of small molecule salts can all be used to tune the exact partitioning of single SWCNT species between the two phases.

  18. Hydraulic Behaviour of He II in Stratified Counter-Current Two-Phase Flow

    CERN Document Server

    Rousset, B; Jäger, B; Van Weelderen, R; Weisend, J G


    Future large devices using superconducting magnets or RF cavities (e.g. LHC or TESLA) need He II two-phase flow for cooling. The research carried out into counter-current superfluid two-phase flow was the continuation of work on co-current flow and benefited from all the knowledge acquired both experimentally and theoretically. Experiments were conducted on two different pipe diameters (40 and 65 m m I.D. tube) for slopes ranging between 0 and 2%, and for temperatures ranging between 1.8 and 2 K. This paper introduces the theoretical model, describes the tests, and provides a critical review of the results obtained in He II counter current two-phase flow.

  19. Investigation of two-phase heat transfer coefficients of argon-freon cryogenic mixed refrigerants (United States)

    Baek, Seungwhan; Lee, Cheonkyu; Jeong, Sangkwon


    Mixed refrigerant Joule Thomson refrigerators are widely used in various kinds of cryogenic systems these days. Although heat transfer coefficient estimation for a multi-phase and multi-component fluid in the cryogenic temperature range is necessarily required in the heat exchanger design of mixed refrigerant Joule Thomson refrigerators, it has been rarely discussed so far. In this paper, condensation and evaporation heat transfer coefficients of argon-freon mixed refrigerant are measured in a microchannel heat exchanger. A Printed Circuit Heat Exchanger (PCHE) with 340 μm hydraulic diameter has been developed as a compact microchannel heat exchanger and utilized in the experiment. Several two-phase heat transfer coefficient correlations are examined to discuss the experimental measurement results. The result of this paper shows that cryogenic two-phase mixed refrigerant heat transfer coefficients can be estimated by conventional two-phase heat transfer coefficient correlations.

  20. Interfacial Area and Interfacial Transfer in Two-Phase Flow Systems (Volume IV. Chapters 15-19)

    Energy Technology Data Exchange (ETDEWEB)

    Guo, T.; Park, J.; Kojasoy, G.


    Experiments were performed on horizontal air-water bubbly two-phase flow, axial flow, stratified wavy flow, and annular flow. Theoretical studies were also undertaken on interfacial parameters for a horizontal two-phase flow.

  1. Interfacial Area and Interfacial Transfer in Two-Phase Flow Systems (Volume III. Chapters 11-14)

    Energy Technology Data Exchange (ETDEWEB)

    Guo, T.; Park, J.; Kojasoy, G.


    Experiments were performed on horizontal air-water bubbly two-phase flow, axial flow, stratified wavy flow, and annular flow. Theoretical studies were also undertaken on interfacial parameters for a horizontal two-phase flow.

  2. Interfacial Area and Interfacial Transfer in Two-Phase Flow Systems (Volume I. Chapters 1-5)

    Energy Technology Data Exchange (ETDEWEB)

    Guo, T.; Park, J.; Kojasoy, G.


    Experiments were performed on horizontal air-water bubbly two-phase flow, axial flow, stratified wavy flow, and annular flow. Theoretical studies were also undertaken on interfacial parameters for a horizontal two-phase flow.

  3. Interfacial Area and Interfacial Transfer in Two-Phase Flow Systems (Volume II. Chapters 6-10)

    Energy Technology Data Exchange (ETDEWEB)

    Guo, T.; Park, J.; Kojasoy, G.


    Experiments were performed on horizontal air-water bubbly two-phase flow, axial flow, stratified wavy flow, and annular flow. Theoretical studies were also undertaken on interfacial parameters for a horizontal two-phase flow.

  4. A Three-dimensional Two-phase Mixture Model for Sediment Transport (United States)

    Huang, Hai; Zhong, Deyu; Zhang, Hongwu; Zhang, Yinglong J.; Li, Xiaonan


    Suspended load often constitutes a large portion of the total load in a fluvial river. In classical fluvial numeric models, flows carrying suspended sediment are usually modeled by the Reynolds averaged equations directly borrowed from the classical fluid dynamics for single-phase flows with an advection-diffusion equation and single-phase turbulence model is adopted to close the equations. Due to the omission of the effect of the sediment on fluid, results from the classical models can deviate significantly from experimental and field observations. In this paper, we develop a three-dimensional numerical model based on two-phase mixture theory to study the sediment-laden flows. The two-phase mixture equations are closed by a two-phase mixture turbulence model derived from two-fluid turbulence model. The two-phase mixture model therefore inherits the essential capabilities of two-fluid models in considering inter-phase interaction, but without solving the full set of governing equations for the two-fluid models. Two-phase mixture equations have similar form to the governing equations for classical fluvial hydraulics, thus allowing us to embed the two-phase mixture model into SCHISM, a 3D unstructured-grid model for oceans, estuaries and rivers. We verify the new model with a set of experiments , and the results show that the new model is valid for sediment-laden flows covering a wide range of particle diameters and concentrations. We also apply the new model to the study of representative flood events in the Lower Yellow River (LYR), and investigate sediment distributions, velocity profiles, circulation flows in river bends, flood propagation and erosion and deposition patterns. The computed water surface elevation, cross-sectional bathymetry and sediment concentration show good agreement with the measured data.

  5. Analytic approximations for the elastic moduli of two-phase materials

    DEFF Research Database (Denmark)

    Zhu, Y. K.; Zhang, P.; Zhang, Y. Y.


    Based on the models of series and parallel connections of the two phases in a composite, analytic approximations are derived for the elastic constants (Young's modulus, shear modulus, and Poisson's ratio) of elastically isotropic two-phase composites containing second phases of various volume...... fractions, shapes, and regular distributions. Comparison with a plentitude of finite element simulations and numerous previous experimental investigations shows a large consistency between the results and the analytic expressions derived, confirming the adequacy of the present approach. Compared...... with previous classical models, the present model has several advantages, including its simplicity, accuracy of prediction, and universal applicability....

  6. Two-Phase Nozzle Theory and Parametric Analysis. Phase III. Off-Design Performance Analysis. (United States)


    111.7 and noting that A2 2VAV, the result is: tA -2 A LX = 2V2 p rGP 2 g + r(I-0 In the examination of Eq. III.10, the following points can be observed... complication to the system, it does not appear that heat transfer enhancement is particularly advantageous for the improvement of nozzle performance...parameters. For two-phase systems, however, the concept of a two-phase sonic velocity is more complicated because of the various possible flow regimes

  7. Camomile autofermentation in polyethylene glycol/dextran two-phase system

    Directory of Open Access Journals (Sweden)

    Đaković Sanja D.


    Full Text Available The objective of this study was the investigation of the extractive bioconversion of apigenin-7-O-β-glucoside in camomile ligulate flowers into apigenin by autofermentation in polyethylene glycol 6000/dextran 200000 two-phase system. In 22.5% polyethylene glycol/14% dextran aqueous two-phase system the obtained yield of apigenin in the top phase was 96.5%. In the presence of plant material that partiotioned to the interphase, the yield of apigenin in the top phase was 3.5 times higher in comparison to the model system.

  8. Conceptual design of two-phase fluid mechanics and heat transfer facility for spacelab (United States)

    North, B. F.; Hill, M. E.


    Five specific experiments were analyzed to provide definition of experiments designed to evaluate two phase fluid behavior in low gravity. The conceptual design represents a fluid mechanics and heat transfer facility for a double rack in Spacelab. The five experiments are two phase flow patterns and pressure drop, flow boiling, liquid reorientation, and interface bubble dynamics. Hardware was sized, instrumentation and data recording requirements defined, and the five experiments were installed as an integrated experimental package. Applicable available hardware was selected in the experiment design and total experiment program costs were defined.

  9. Two-phase pressure drops for CANDU fuel bundles in uncrept and crept channels

    Energy Technology Data Exchange (ETDEWEB)

    Sutradhar, S.C. [Atomic Energy of Canada Ltd., Chalk River, Ontario (Canada)


    Pressure-drop tests in Freon-134a were performed on aligned and misaligned 37-element CANDU (C6) fuel bundles in uncrept and 3% crept channels. The results indicate that the two-phase pressure-drop profiles are similar in shape, but higher in magnitude, compared with the single-phase pressure-drop profiles. The two-phase multipliers (TPMs) are a strong function of the thermodynamic quality of the fluid. The measured TPMs of the bundles in the uncrept channel are higher than those in the crept channel. The measured TPMs for the aligned bundles agree well with the Beattie correlation. (author)

  10. Preliminary Two-Phase Terry Turbine Nozzle Models for RCIC Off-Design Operation Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Haihua [Idaho National Lab. (INL), Idaho Falls, ID (United States); O' Brien, James [Idaho National Lab. (INL), Idaho Falls, ID (United States)


    This report presents the effort to extend the single-phase analytical Terry turbine model to cover two-phase off-design conditions. The work includes: (1) adding well-established two-phase choking models – the Isentropic Homogenous Equilibrium Model (IHEM) and Moody’s model, and (2) theoretical development and implementation of a two-phase nozzle expansion model. The two choking models provide bounding cases for the two-phase choking mass flow rate. The new two-phase Terry turbine model uses the choking models to calculate the mass flow rate, the critical pressure at the nozzle throat, and steam quality. In the divergent stage, we only consider the vapor phase with a similar model for the single-phase case by assuming that the liquid phase would slip along the wall with a much slower speed and will not contribute the impulse on the rotor. We also modify the stagnation conditions according to two-phase choking conditions at the throat and the cross-section areas for steam flow at the nozzle throat and at the nozzle exit. The new two-phase Terry turbine model was benchmarked with the same steam nozzle test as for the single-phase model. Better agreement with the experimental data is observed than from the single-phase model. We also repeated the Terry turbine nozzle benchmark work against the Sandia CFD simulation results with the two-phase model for the pure steam inlet nozzle case. The RCIC start-up tests were simulated and compared with the single-phase model. Similar results are obtained. Finally, we designed a new RCIC system test case to simulate the self-regulated Terry turbine behavior observed in Fukushima accidents. In this test, a period inlet condition for the steam quality varying from 1 to 0 is applied. For the high quality inlet period, the RCIC system behaves just like the normal operation condition with a high pump injection flow rate and a nominal steam release rate through the turbine, with the net addition of water to the primary system; for

  11. Problems of heat transfer and hydraulics of two-phase media

    CERN Document Server

    Kutateladze, S S


    Problems of Heat Transfer and Hydraulics of Two-Phase Media presents the theory of heat transfer and hydrodynamics. This book discusses the various aspects of heat transfer and the flow of two-phase systems. Organized into two parts encompassing 22 chapters, this book starts with an overview of the laws of similarity for heat transfer to or from a flowing liquid with various physical properties and allowed for variation in viscosity and thermal conductivity. This book then explores the general functional relationship that exists between viscosity and thermal conductivity for thermodynamically

  12. Two-dimensional Green's functions for fluid and thermoelastic two-phase plane

    Directory of Open Access Journals (Sweden)

    Peng-Fei Hou


    Full Text Available The two-dimensional Green's functions for a steady-state line heat source in the interior of fluid and thermoelastic two-phase plane are derived in this paper. By virtue of the compact two-dimensional general solutions which are expressed in harmonic functions, four newly introduced harmonic functions with undetermined constants are constructed. Then, all the thermoelastic components in the fluid and thermoelastic two-phase plane can be derived by substituting these harmonic functions into the corresponding general solutions. And the undetermined constants can be obtained by the corresponding conditions of compatibility, boundary and equilibrium. Numerical results are given graphically by contours.

  13. Two-Phase Flow in Geothermal Wells: Development and Uses of a Good Computer Code

    Energy Technology Data Exchange (ETDEWEB)

    Ortiz-Ramirez, Jaime


    A computer code is developed for vertical two-phase flow in geothermal wellbores. The two-phase correlations used were developed by Orkiszewski (1967) and others and are widely applicable in the oil and gas industry. The computer code is compared to the flowing survey measurements from wells in the East Mesa, Cerro Prieto, and Roosevelt Hot Springs geothermal fields with success. Well data from the Svartsengi field in Iceland are also used. Several applications of the computer code are considered. They range from reservoir analysis to wellbore deposition studies. It is considered that accurate and workable wellbore simulators have an important role to play in geothermal reservoir engineering.

  14. Affinity partitioning of proteins tagged with choline-binding modules in aqueous two-phase systems. (United States)

    Maestro, Beatriz; Velasco, Isabel; Castillejo, Isabel; Arévalo-Rodríguez, Miguel; Cebolla, Angel; Sanz, Jesús M


    We present a novel procedure for affinity partitioning of recombinant proteins fused to the choline-binding module C-LytA in aqueous two-phase systems containing poly(ethylene glycol) (PEG). Proteins tagged with the C-LytA module and exposed to the two-phase systems are quantitatively localized in the PEG-rich phase, whereas subsequent addition of the natural ligand choline specifically shifts their localization to the PEG-poor phase by displacement of the polymer from the binding sites. The described procedure is simple, scalable and reproducible, and has been successfully applied to the purification of four diverse proteins, resulting in high yields and purity.

  15. Hierarchy of two-phase flow models for autonomous control of cryogenic loading operation (United States)

    Luchinskiy, Dmitry G.; Ponizovskaya-Devine, Ekaterina; Hafiychuk, Vasyl; Kashani, Ali; Khasin, Michael; Timucin, Dogan; Sass, Jared; Perotti, Jose; Brown, Barbara


    We report on the development of a hierarchy of models of cryogenic two-phase flow motivated by NASA plans to develop and maturate technology of cryogenic propellant loading on the ground and in space. The solution of this problem requires models that are fast and accurate enough to identify flow conditions, detect faults, and to propose optimal recovery strategy. The hierarchy of models described in this presentation is ranging from homogeneous moving- front approximation to separated non-equilibrium two-phase cryogenic flow. We compare model predictions with experimental data and discuss possible application of these models to on-line integrated health management and control of cryogenic loading operation.

  16. Evaluation of Low-Cost Topologies for Two-Phase Induction Motor Drives, in Industrial Applications

    DEFF Research Database (Denmark)

    Blaabjerg, Frede; Lungeanu, Florin; Skaug, Kenneth


    This paper investigates and compares the potential of the two-phase induction motors to accommodate variable speed operation in ac drive. The analysis is based on both theory and experimental work, showing a conflict between the performances on one side, and the cost/complexity for such ac drives...... on the other side. Another contradiction comes from the benefits as well as from the drawbacks related with the ac running capacitor. It is concluded that the two-phase induction motor drives are more depending on the load characteristic than the three-phase motor drives, while the best topology...

  17. Simplified pesticide multiresidue analysis of soybean oil by low-temperature cleanup and dispersive solid-phase extraction coupled with gas chromatography/mass spectrometry. (United States)

    Li, Li; Xu, Yanjun; Pan, Canping; Zhou, Zhiqiang; Jianc, Shuren; Liu, Fengmao


    A simple, fast, and economical method has been developed for the simultaneous determination of 28 various types of pesticides in soybean oil. Pesticides of low molecular mass were separated from the fat of the oil, which has a high molecular mass, by using low-temperature fat precipitation, followed by a cleanup process based on dispersive solid-phase extraction with primary secondary amine and C18 as sorbents and magnesium sulfate for the removal of residual water. The results for all pesticides determined by gas chromatography with mass spectrometry in the selected-ion monitoring mode were linear, and the matrix effect of the method was evaluated. Recoveries of most pesticides were acceptable at fortification levels of 0.02, 0.05, 0.2, and 1 mg/kg. The relative standard deviation was <20% even for determinations without internal standards. Limits of quantitation ranged from 20 to 250 microg/kg.

  18. Experimental and CFD Simulations of Vertical Two-Phase Slug Flow for Gas-Newtonian and Non-Newtonian Liquids

    DEFF Research Database (Denmark)

    Ratkovich, Nicolas Rios; Bentzen, Thomas Ruby; Majumder, S.

    Gas-liquid two-phase flows are presented everywhere in industrial processes (i.e. gas-oil pipelines). In spite of the common occurrence of these two-phase flows, their understanding is limited compared to single-phase flows. Different studies on two-phase flow have focus on developing empirical c...

  19. On-chip aqueous two-phase system (ATPS) formation, consequential self-mixing, and their influence on drop-to-drop aqueous two-phase extraction kinetics (United States)

    Wijethunga, Pavithra A. L.; Moon, Hyejin


    Aqueous two-phase systems (ATPSs) allow an advantageous aqueous two-phase extraction process (ATPE), a special type of liquid-liquid extraction. Compared with conventional liquid-liquid extraction using aqueous/organic extraction media, ATPE is known to provide relatively easy mass transfer and a gentle environment for biological separation applications. Considering the recent interest in microscale ATPE, we aimed to study (i) the potential of preparing ATPS droplets on a digital microfluidic device, and (ii) the influence of the fluidic dynamics created during the formation of ATPS, with the goal of enhancing on-chip ATPE process. On-chip ATPS formation was evaluated by preparing a series of ATPSs on electrowetting on dielectric digital microfluidic chips and comparing their characteristics with the same ATPSs prepared at macroscale using conventional procedures. An enhanced on-chip drop-to-drop ATPE process was achieved by incorporating a self-mixing condition created during ATPSformation. Results indicate a successful on-chip ATPS preparation as well as enhanced extraction performance by self-mixing in the absence of forced mixing. Findings of this research suggest an alternative, simple, yet adequate technique to provide mixing for on-chip applications, such as sample preparation in portable microfluidics, for which it is unfavorable to implement complicated mixing sequences or complex device geometries.

  20. Dispersion Forces

    CERN Document Server

    Buhmann, Stefan Yoshi


    In this book, a modern unified theory of dispersion forces on atoms and bodies is presented which covers a broad range of advanced aspects and scenarios. Macroscopic quantum electrodynamics is shown to provide a powerful framework for dispersion forces which allows for discussing general properties like their non-additivity and the relation between microscopic and macroscopic interactions. It is demonstrated how the general results can be used to obtain dispersion forces on atoms in the presence of bodies of various shapes and materials. Starting with a brief recapitulation of volume I, this volume II deals especially with bodies of irregular shapes, universal scaling laws, dynamical forces on excited atoms, enhanced forces in cavity quantum electrodynamics, non-equilibrium forces in thermal environments and quantum friction. The book gives both the specialist and those new to the field a thorough overview over recent results in the field. It provides a toolbox for studying dispersion forces in various contex...

  1. Aqueous two-phase assisted by ultrasound for the extraction of anthocyanins from Lycium ruthenicum Murr. (United States)

    Qin, Benlin; Liu, Xuecong; Cui, Haiming; Ma, Yue; Wang, Zimin; Han, Jing


    In this study, an efficient ultrasound-assisted aqueous two-phase extraction method was used for the extraction of anthocyanins from Lycium ruthenicum Murr. An ethanol/ammonium sulfate system was chosen for the aqueous two-phase system due to its fine partitioning and recycling behaviors. Single-factor experiments were conducted to determine the optimized composition of the system, and the response surface methodology was used for the further optimization of the ultrasound-assisted aqueous two-phase extraction. The optimal conditions were as follows: a salt concentration of 20%, an ethanol concentration of 25%, an extraction time of 33.7 min, an extraction temperature of 25°C, a liquid/solid ratio of 50:1 w/w, pH value of 3.98, and an ultrasound power of 600 W. Under the above conditions, the yields of anthocyanins reached 4.71 mg/g dry sample. For the further purification, D-101 resin was used, and the purity of anthocyanins reached 25.3%. In conclusion, ultrasound-assisted aqueous two-phase extraction was an efficient, ecofriendly, and economical method, and it may be a promising technique for extracting bioactive components from plants.

  2. Experimental Study of Two-Phase Thermosyphon using R-22 as a Working Fluid

    Directory of Open Access Journals (Sweden)

    Theeb Maathe. А.


    Full Text Available The two-phase closed thermosyphon (TPCT is an effective heat transfer device decreasing the ground temperature around it in cold season. In this paper an experimental study has been done by using R-22 as a working fluids, the temperature and the pressure of the TPCT where measured with time (Transient study.

  3. Measurements of solids concentration and axial solids velocity in gas-solid two-phase flows.

    NARCIS (Netherlands)

    Nieuwland, J.J.; Nieuwland, J.J.; Meijer, R.; Kuipers, J.A.M.; van Swaaij, Willibrordus Petrus Maria


    Several techniques reported in the literature for measuring solids concentration and solids velocity in (dense) gas-solid two-phase flow have been briefly reviewed. An optical measuring system, based on detection of light reflected by the suspended particles, has been developed to measure local

  4. Analysis of two-phased approaches to load balancing in cloud ...

    African Journals Online (AJOL)

    No Abstract. Keywords: Cloud Computing, Load Balancing, Resource Management, Two-phased Approaches, Resource Allocation. Full Text: EMAIL FULL TEXT EMAIL FULL TEXT · DOWNLOAD FULL TEXT DOWNLOAD FULL TEXT · AJOL African Journals Online. HOW TO USE AJOL... for Researchers · for Librarians ...

  5. Comparison of two-phase and three-phase methanol synthesis processes

    NARCIS (Netherlands)

    van de Graaf, G.H; Beenackers, A.A C M


    A comparison is made between the ICI (two-phase) methanol synthesis process and a three-phase slurry process based on a multi-stage agitated reactor. The process calculations are based on a complete reactor system consisting of the reactor itself, a recycling system and a gas-liquid separator. The

  6. Statistical modelling of a stratified two-phase flow; Statistische Modellierung einer geschichteten Zweiphasenstroemung

    Energy Technology Data Exchange (ETDEWEB)

    Benz, Matthias


    A new modeling approach for stratified two-phase flows has been developed. The two-layer turbulence model is a simple method to model the interaction between turbulence and surface waves. The wave amplitude is used here as turbulent length scale in the inner wavy region. It can be calculated from a statistical equilibrium between turbulent kinetic, turbulent potential and turbulent surface energy.

  7. Phase distribution of nitrogen-water two-phase flow in parallel micro channels (United States)

    Zhou, Mi; Wang, Shuangfeng; Zhou, You


    The present work experimentally investigated the phase splitting characteristics of gas-liquid two-phase flow passing through a horizontal-oriented micro-channel device with three parallel micro-channels. The hydraulic diameters of the header and the branch channels were 0.6 and 0.4 mm, respectively. Five different liquids, including de-ionized water and sodium dodecyl sulfate (SDS) solution with different concentration were employed. Different from water, the surface tension of SDS solution applied in this work decreased with the increment of mass concentration. Through series of visual experiments, it was found that the added SDS surfactant could obviously facilitate the two-phase flow through the parallel micro channels while SDS solution with low concentration would lead to an inevitable blockage of partial outlet branches. Experimental results revealed that the two phase distribution characteristics depended highly on the inlet flow patterns and the outlet branch numbers. To be specific, at the inlet of slug flow, a large amount of gas preferred flowing into the middle branch channel while the first branch was filled with liquid. However, when the inlet flow pattern was shifted to annular flow, all of the gas passed through the second and the last branches, with a little proportion of liquid flowing into the first channel. By comparison with the experimental results obtained from a microchannel device with five parallel micro-T channels, uneven distribution of the two phase can be markedly noticed in our present work.

  8. Modeling of Two-Phase Flow in Rough-Walled Fracture Using Level Set Method

    Directory of Open Access Journals (Sweden)

    Yunfeng Dai


    Full Text Available To describe accurately the flow characteristic of fracture scale displacements of immiscible fluids, an incompressible two-phase (crude oil and water flow model incorporating interfacial forces and nonzero contact angles is developed. The roughness of the two-dimensional synthetic rough-walled fractures is controlled with different fractal dimension parameters. Described by the Navier–Stokes equations, the moving interface between crude oil and water is tracked using level set method. The method accounts for differences in densities and viscosities of crude oil and water and includes the effect of interfacial force. The wettability of the rough fracture wall is taken into account by defining the contact angle and slip length. The curve of the invasion pressure-water volume fraction is generated by modeling two-phase flow during a sudden drainage. The volume fraction of water restricted in the rough-walled fracture is calculated by integrating the water volume and dividing by the total cavity volume of the fracture while the two-phase flow is quasistatic. The effect of invasion pressure of crude oil, roughness of fracture wall, and wettability of the wall on two-phase flow in rough-walled fracture is evaluated.

  9. Effects of Gravity and Inlet Location on a Two-Phase Countercurrent Imbibition in Porous Media

    Directory of Open Access Journals (Sweden)

    M. F. El-Amin


    Full Text Available We introduce a numerical investigation of the effect of gravity on the problem of two-phase countercurrent imbibition in porous media. We consider three cases of inlet location, namely, from, side, top, and bottom. A 2D rectangular domain is considered for numerical simulation. The results indicate that gravity has a significant effect depending on open-boundary location.

  10. Severe slugging in gas-liquid two-phase pipe flow

    NARCIS (Netherlands)

    Malekzadeh, R.


    transportation facilities. In an offshore oil and gas production facility, pipeline-riser systems are required to transport two-phase hydrocarbons from subsurface oil and gas wells to a central production platform. Severe slugs reaching several thousands pipe diameters may occur when transporting

  11. Two-phase flow boiling in small channels: A brief review

    Indian Academy of Sciences (India)

    Steam generators. Evaporators. Refrigerators. Condensers. Refrigerator. Electronic micro chips. Compact heat exchangers. Compact evaporators. Cooling devices. Figure 1. (a) Schematic representation of gaps identified in literature on channel size. (b) Pictorial view of industrial equipments where two-phase flow is shown ...

  12. Effects of gravity and inlet location on a two-phase countercurrent imbibition in porous media

    KAUST Repository

    El-Amin, Mohamed


    We introduce a numerical investigation of the effect of gravity on the problem of two-phase countercurrent imbibition in porous media. We consider three cases of inlet location, namely, from, side, top, and bottom. A 2D rectangular domain is considered for numerical simulation. The results indicate that gravity has a significant effect depending on open-boundary location.

  13. Unsteady experimental and numerical analysis of a two-phase closed thermosyphon at different filling ratios

    NARCIS (Netherlands)

    Jafari, Davoud; Filippeschi, Sauro; Franco, Alessandro; Di Marco, Paolo


    This paper deals with the experimental analysis and numerical simulation of a two-phase closed thermosyphon (TPCT) in the aim to predict its transient performances. A concern in the design and operation of the TPCT is evaluating working fluid loading charge to maximize performance while avoiding

  14. Two-phase (bio)catalytic reactions in a table-top centrifugal contact separator

    NARCIS (Netherlands)

    Kraai, Gerard N.; Zwol, Floris van; Schuur, Boelo; Heeres, Hero J.; Vries, Johannes G. de


    A new spin on catalysis: A table-top centrifugal contact separator allows for fast continuous two-phase reactions to be performed by intimately mixing two immiscible phases and then separating them. Such a device has been used to produce biodiesel from sunflower oil and MeOH/NaOMe. A

  15. Effects of Particles Collision on Separating Gas–Particle Two-Phase Turbulent Flows

    KAUST Repository

    Sihao, L. V.


    A second-order moment two-phase turbulence model incorporating a particle temperature model based on the kinetic theory of granular flow is applied to investigate the effects of particles collision on separating gas–particle two-phase turbulent flows. In this model, the anisotropy of gas and solid phase two-phase Reynolds stresses and their correlation of velocity fluctuation are fully considered using a presented Reynolds stress model and the transport equation of two-phase stress correlation. Experimental measurements (Xu and Zhou in ASME-FED Summer Meeting, San Francisco, Paper FEDSM99-7909, 1999) are used to validate this model, source codes and prediction results. It showed that the particles collision leads to decrease in the intensity of gas and particle vortices and takes a larger effect on particle turbulent fluctuations. The time-averaged velocity, the fluctuation velocity of gas and particle phase considering particles colli-sion are in good agreement with experimental measurements. Particle kinetic energy is always smaller than gas phase due to energy dissipation from particle collision. Moreover, axial– axial and radial–radial fluctuation velocity correlations have stronger anisotropic behaviors. © King Fahd University of Petroleum and Minerals 2013

  16. Ultralow-power GaAs MESFET MSI circuits using two-phase dynamic FET logic

    DEFF Research Database (Denmark)

    Lassen, Peter Stuhr; Long, S. I.; Nary, K. R.


    Two-phase dynamic FET logic (TDFL) gates are used in GaAs MESFET MSI circuits to implement very low power 4-b ripple carry adders and a variable modulus (2 to 31) prescaler. Operation of the adders is demonstrated at 500 MHz with an associated power dissipation of less than 1.0 mW and at 750 MHz...

  17. Hydrodynamics of two phase flow through homogeneous and stratified porous layers

    Energy Technology Data Exchange (ETDEWEB)

    Chu, W; Lee, H; Dhir, V K; Catton, I


    An experimental investigation of two-phase flow through porous layers formed of nonheated glass particles has been made. The effect of particle size, particle size distribution, bed porosity and bed stratification on void fraction and pressure drop through particulate beds formed in a cylindrical and rectangular test section has been investigated. A model based on drift flux approach has been developed for the void fraction in homogeneous beds. Using the two phase friction pressure drop data, the relative permeabilities of the two phases have been concluded with void fraction. The void fraction and two-phase friction pressure gradient in beds composed of mixtures of spherical particles as well as sharps of different nominal sizes have also been examined. It is found that the models for single size particles are also applicable to mixtures of particles if a mean particle diameter for the mixture is defined. The observations in stratified beds indicate depletion or build up of voids at the interface between high and low permeability regions. Blocking of the flow into one of the layers of laterally stratified beds caused the pressures at different horizontal locations at the same bed height to be different from each other.

  18. Strong enhancement of straeming current power by application of two phase flow

    NARCIS (Netherlands)

    Xie, Yanbo; Sherwood, John D.; Shui, Lingling; van den Berg, Albert; Eijkel, Jan C.T.


    We show that the performance of a streaming-potential based microfluidic energy conversion system can be strongly enhanced by the use of two phase flow. Injection of gas bubbles into a liquid-filled channel increases both the maximum output power and the energy conversion efficiency. In single-phase

  19. Hardening in Two-Phase Materials. II. Plastic Strain and Mean Stress Hardening Rate

    DEFF Research Database (Denmark)

    Lilholt, Hans


    The strain parameters which are relevant in a tensile experiment, are analysed and related to the geometry of deformation and to the mean stress of two-phase materials. The hardening rate of the mean stress with respect to plastic strain is found to be useful in comparison between experiments...

  20. Lattice-Boltzmann-based two-phase thermal model for simulating phase change

    NARCIS (Netherlands)

    Kamali, M.R.; Gillissen, J.J.J.; Van den Akker, H.E.A.; Sundaresan, S.


    A lattice Boltzmann (LB) method is presented for solving the energy conservation equation in two phases when the phase change effects are included in the model. This approach employs multiple distribution functions, one for a pseudotemperature scalar variable and the rest for the various species. A

  1. Entrainment phenomenon in gas–liquid two-phase flow: A review

    Indian Academy of Sciences (India)

    over in two-phase systems based on the experiments. Iyer et al (2010) .... Entrainment phenomenon in gas–liquid flows. 1179. T able. 1 . Summary of prev ious analytical w o rk. Geometrical parameters. Ph ysical. Properties. R ange. D. H. D i. D o. HH. M ...... Sterman L S 1958 On the theory of steam separation. Sovt. Phys.

  2. Colloid transport, retention, and remobilization during two-phase flow: Micro-model investigation and modeling

    NARCIS (Netherlands)

    Zhang, Q.


    In this study the transport of colloids in a two-phase fluid system is investigated. In particular, the effects on the interface of two immiscible fluids in steady-state and transient circumstances in a micro-porous network are investigated. The experimental setup is designed consisting of micro

  3. Visualization and research of gas-liquid two phase flow structures in cylindrical channel

    Directory of Open Access Journals (Sweden)

    Stefański Sebastian


    Full Text Available Two-phase flows are commonly found in many industries, especially in systems, where efficient and correct functioning depend on specific values of flow parameters. In thermal engineering and chemical technology the most popular types of two-phase mixture are gas-liquid or liquid-vapour mixtures. Bubbles can create in flow different structures and determine diverse properties of flow (velocity of phase, void fraction, fluctuations of pressure, pipe vibrations, etc.. That type of flow is difficult to observe, especially in liquid-vapour mixture, where vapour is being made by heating the medium. Production of vapour and nucleation process are very complicated issues, which are important part of two-phase flow phenomenon. Gas-liquid flow structures were observed and described with figures, but type of structure depends on many parameters. Authors of this paper made an attempt to simulate gas-liquid flow with air and water. In the paper there was presented specific test stand built to observe two-phase flow structures, methodology of experiment and conditions which were maintained during observation. The paper presents also the structures which were observed and the analysis of results with reference to theoretical models and diagrams available in literature.

  4. Affinity partitioning of human antibodies in aqueous two-phase systems

    NARCIS (Netherlands)

    Rosa, P. A. J.; Azevedo, A. M.; Ferreira, I. F.; de Vries, J.; Korporaal, R.; Verhoef, H. J.; Visser, T. J.; Aires-Barros, M. R.


    The partitioning of human immunoglobulin (IgG) in a polymer-polymer and polymer-salt aqueous two-phase system (ATPS) in the presence of several functionalised polyethylene glycols (PEGs) was studied. As a first approach, the partition studies were performed with pure IgG using systems in which the

  5. Liquid-liquid extraction of enzymes by affinity aqueous two-phase systems

    Directory of Open Access Journals (Sweden)

    Xu Yan


    Full Text Available From analytical to commercial scale, aqueous two-phase systems have their application in the purification, characterization and study of biomaterials. In order to improve the selectivity of the systems, the biospecific affinity ligands were introduced. In the affinity partitioning aqueous two-phase system, have many enzymes been purified. This review discusses the partitioning of some enzymes in the affinity aqueous two-phase systems in regard to the different ligands, including reactive dyes, metal ions and other ligands. Some integration of aqueous two-phase system with other techniques for more effective purification of enzymes are also presented.Tanto em escala de laboratório como industrial, os sistemas de duas fases aquosas podem ser utilizados para a purificação, caracterização e estudos de biomateriais. Para aumentar a seletividade desse sistema, ligantes de afinidade bioespecíficos podem ser utilizados. No sistema de duas fases aquosas por afinidade, muitas enzimas podem ser purificadas. Neste artigo de revisão, a partição de algumas enzimas por esse tipo de afinidade, utilizando diferentes ligantes como corantes e íons metálicos, são discutidas. Além disso, a integração desse sistema de duas fases aquosas com outras técnicas de purificação estão sendo apresentados, com o objetivo mostrar a melhoria da eficiência do processo.

  6. Milking microalga Dunaliella salina for Beta-carotene production in two-phase bioreactors

    NARCIS (Netherlands)

    Hejazi, M.; Holwerda, E.; Wijffels, R.H.


    A new method was developed for production of beta-carotene from Dunaliella salina. Cells were grown in low light intensity and then transferred to a production bioreactor illuminated at a higher light intensity. It was a two-phase bioreactor consisting of an aqueous and a biocompatible organic

  7. Differentiation of surface properties of chlorococcalean algae by means of aqueous two phase systems

    Directory of Open Access Journals (Sweden)

    Jan Burczyk


    Full Text Available Algal cells belonging to various strains of Chlorococcales (Chlorophyta have been partitioned in aqueous two-phase systems containing ionogenic polymers, DEAE-dextran or SDS-dextran, at various pH values. Strain-specific differences of partition type which have been found in the phase systems used can be useful for distinguishing of algal cells.

  8. Process Intensification. Continuous Two-Phase Catalytic Reactions in a Table-Top Centrifugal Contact Separator

    NARCIS (Netherlands)

    Kraai, Gerard N.; Schuur, Boelo; van Zwol, Floris; Haak, Robert M.; Minnaard, Adriaan J.; Feringa, Ben L.; Heeres, Hero J.; de Vries, Johannes G.; Prunier, ML


    Production of fine chemicals is mostly performed in batch reactors. Use of continuous processes has many advantages which may reduce the cost of production. We have developed the use of centrifugal contact separators (CCSs) for continuous two-phase catalytic reactions. This equipment has previously

  9. Theoretical aspects of electrical power generation from two-phase flow streaming potentials

    NARCIS (Netherlands)

    Sherwood, J.D.; Xie, Yanbo; van den Berg, Albert; Eijkel, Jan C.T.

    A theoretical analysis of the generation of electrical streaming currents and electrical power by two-phase flow in a rectangular capillary is presented. The injection of a second, non-conducting fluid phase tends to increase the internal electrical resistance of the electrical generator, thereby

  10. modeling and performance of a self-excited two-phase reluctance

    African Journals Online (AJOL)

    ES Obe

    Department of Electrical Engineering, University of Nigeria, Nsukka, Nigeria. Abstract. A self-excited two-phase reluctance generator ... engines employing alternators. Not only are these expensive and beyond the reach of the .... (19) where F represents any variable such as voltage, current, flux linkages, or electric charge.

  11. A new correlation of two-phase frictional pressure drop for condensing flow in pipes

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Yu; Fang, Xiande, E-mail:


    Highlights: • Survey of two-phase frictional pressure drop (THFPD) experimental data of condensing flow is conducted. • Applicability of the existing THFPD correlations to condensing flow is assessed. • A new THFPD correlation for condensing flow in pipes is proposed. -- Abstract: The calculation of two-phase frictional pressure drop for condensing flow in pipes is essential in many areas. Although numerous studies concerning this issue have been conducted, an accurate correlation is still required. In this paper, an overall survey of correlations and experimental investigations of two-phase frictional pressure drop is carried out. There 525 experimental data points of 9 refrigerants are gathered from literature, with hydraulic diameter from 0.1 to 10.07 mm, mass flux from 20 to 800 kg/m{sup 2} s, and heat flux from 2 to 55.3 kW/m{sup 2}. The 29 existing correlations are evaluated against the experimental database, among which the best one has a mean absolute relative deviation (MARD) of 25.2%. Based on all the experimental data, a new correlation which has an MARD of 19.4% is proposed, improving significantly the prediction of two-phase frictional pressure drop for pipe condensing flow.

  12. Forced Two-Phase Helium Cooling Scheme for the Mu2e Transport Solenoid

    Energy Technology Data Exchange (ETDEWEB)

    Tatkowski, G. [Fermilab; Cheban, S. [Fermilab; Dhanaraj, N. [Fermilab; Evbota, D. [Fermilab; Lopes, M. [Fermilab; Nicol, T. [Fermilab; Sanders, R. [Fermilab; Schmitt, R. [Fermilab; Voirin, E. [Fermilab


    The Mu2e Transport Solenoid (TS) is an S-shaped magnet formed by two separate but similar magnets, TS-u and TS-d. Each magnet is quarter-toroid shaped with a centerline radius of approximately 3 m utilizing a helium cooling loop consisting of 25 to 27 horizontal-axis rings connected in series. This cooling loop configuration has been deemed adequate for cooling via forced single phase liquid helium; however it presents major challenges to forced two-phase flow such as “garden hose” pressure drop, concerns of flow separation from tube walls, difficulty of calculation, etc. Even with these disadvantages, forced two-phase flow has certain inherent advantages which make it a more attractive option than forced single phase flow. It is for this reason that the use of forced two-phase flow was studied for the TS magnets. This paper will describe the analysis using helium-specific pressure drop correlations, conservative engineering approach, helium properties calculated and updated at over fifty points, and how the results compared with those in literature. Based on the findings, the use of forced-two phase helium is determined to be feasible for steady-state cooling of the TS solenoids

  13. Variable and space steps solution of a two phase moving boundary ...

    African Journals Online (AJOL)

    Equations of a two phase moving boundary problem in cylindrical coordinates are obtained from the formulation of a transient shrinking core model of whole tree combustion in a one dimensional steady state fixed-bed reactor. An hybrid Variable Grid Method is developed to solve the non linear equations and the results are ...

  14. Effects of Parallel Channel Interactions on Two-Phase Flow Split in ...

    African Journals Online (AJOL)

    The tests would aid the development of a realistic transient computer model for tracking the distribution of two-phase flows into the multiple parallel channels of a Nuclear Reactor, during Loss of Coolant Accidents (LOCA), and were performed at the General Electric Nuclear Energy Division Laboratory, California. The test ...

  15. Synthesis of some novel biologically active disperse dyes derived from 4-methyl-2,6-dioxo-1-propyl-1,2,5,6-tetrahydro-pyridine-3-carbonitrile as coupling component and their colour assessment on polyester fabrics. (United States)

    Ashkar, Samar M; El-Apasery, Morsy A; Touma, Marwan M; Elnagdi, Mohamed H


    A series of novel azo-disperse dyes containing alkylhydrazonopyridinone structures were synthesized. 4-Methyl-2,6-dioxo-1-propyl-1,2,5,6-tetrahydropyridine-3-carbonitrile (8) is synthesized by one-pot synthesis using ethyl cyanoacetate, propylamine, and ethyl acetoacetate. Compound 8 is then coupled with aromatic and heteroaromatic diazonium salts to afford the corresponding aryl- and heteroaryl-4-methyl-2,6-dioxo-1-propyl-1,2,5,6-tetrahydropyridine-3-carbonitriles 12a,b and 13a-c. Structural assignments to the dyes were made using NMR spectroscopic methods. A high temperature dyeing method was employed to apply these dyes to polyester fabrics. Most of the dyed fabrics tested displayed very good light fastness levels and good wash fastness. Finally, the biological activity of the prepared dyes against Gram positive bacteria and Gram negative bacteria were evaluated.

  16. Wedge-shaped parenchymal enhancement peripheral to the hepatic hemangioma : two-phase spiral CT findings

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Kyoung Won; Kim, Tae Kyoung; Han, Joon Koo [College of Medicine and The Institute of Radiation Medicine, Seoul National University, Seoul (Korea, Republic of); Kim, Ah Young; Lee, Hyun Ju [Asan Medical Center, University of Ulsan , Asan (Korea, Republic of); Song, Chi Sung; Choi, Byung Ihn [Seoul City Boramae Hospital, Seoul (Korea, Republic of)


    To determine the incidence of hepatic hemangiomas associated with wedge-shaped parenchymal enhancements adjacent to the tumors as seen on two-phase spiral CT images obtained during the hepatic arterial phase and to characterize the two-phase spiral CT findings of those hemangiomas. One hundred and eight consecutive hepatic hemangiomas in 63 patients who underwent two-phase spiral CT scanning during an 11-month period were included in this study. Two-phase spiral CT scans were obtained during the hepatic arterial phase (30-second delay) and portal venous phase (65-second delay) after injection of 120 mL of contrast material at a rate of 3 mL/sec. We evaluated the frequency with which wedge-shaped parenchymal enhancement was adjacent to the hemangiomas during the hepatic arterial phase and divided hemangiomas into two groups according to whether or not wedge-shaped parenchymal enhancement was noted (Group A and Group B). The presence of such enhancement in hemangiomas was correlated with tumor size and the grade of intratumoral enhancement. In 24 of 108 hemangiomas, wedge-shaped parenchymal enhancement adjacent to hepatic tumors was seen on two-phase CT images obtained during the hepatic arterial phase. Mean hemangioma size was 22mm in group A and 24mm in group B. There was no statistically significant relationship between lesion size and the presence of wedge-shaped parenchymal enhancement adjacent to a hemangioma. In 91.7% and 100% of tumors in Group A, and in 9.6% and 17.8% in Group B, hemangiomas showed more than 50% intratumoral enhancement during the arterial and portal venous phase, respectively. Wedge-shaped parenchymal enhancements peripheral to hepatic hemangiomas was more frequently found in tumors showing more than 50% intratumoral enhancement during these two phases (p less than 0.01). Wedge-shaped parenchymal enhancements is not uncommonly seen adjacent to hepatic hemangiomas on two-phase spiral CT images obtained during the hepatic arterial phase. A

  17. Dispersive liquid-phase microextraction with solidification of floating organic droplet coupled with high-performance liquid chromatography for the determination of Sudan dyes in foodstuffs and water samples. (United States)

    Chen, Bo; Huang, Yuming


    Dispersive liquid-phase microextraction with solidification of floating organic drop (SFO-DLPME) is one of the most interesting sample preparation techniques developed in recent years. In this paper, a new, rapid, and efficient SFO-DLPME coupled with high-performance liquid chromatography (HPLC) was established for the extraction and sensitive detection of banned Sudan dyes, namely, Sudan I, Sudan II, Sudan III, and Sudan IV, in foodstuff and water samples. Various factors, such as the type and volume of extractants and dispersants, pH and volume of sample solution, extraction time and temperature, ion strength, and humic acid concentration, were investigated and optimized to achieve optimal extraction of Sudan dyes in one single step. After optimization of extraction conditions using 1-dodecanol as an extractant and ethanol as a dispersant, the developed procedure was applied for extraction of the target Sudan dyes from 2 g of food samples and 10 mL of the spiked water samples. Under the optimized conditions, all Sudan dyes could be easily extracted by the proposed SFO-DLPME method. Limits of detection of the four Sudan dyes obtained were 0.10-0.20 ng g(-1) and 0.03 μg L(-1) when 2 g of foodstuff samples and 10 mL of water samples were adopted, respectively. The inter- and intraday reproducibilities were below 4.8% for analysis of Sudan dyes in foodstuffs. The method was satisfactorily used for the detection of Sudan dyes, and the recoveries of the target for the spiked foodstuff and water samples ranged from 92.6 to 106.6% and from 91.1 to 108.6%, respectively. These results indicated that the proposed method is simple, rapid, sensitive, and suitable for the pre-concentration and detection of the target dyes in foodstuff samples.

  18. Computational design and fabrication of core-shell magnetic molecularly imprinted polymer for dispersive micro-solid-phase extraction coupled with high-performance liquid chromatography for the determination of rhodamine 6G. (United States)

    Xie, Jin; Xie, Jie; Deng, Jian; Fang, Xiangfang; Zhao, Haiqing; Qian, Duo; Wang, Hongjuan


    A novel core-shell magnetic nano-adsorbent with surface molecularly imprinted polymer coating was fabricated and then applied to dispersive micro-solid-phase extraction followed by determination of rhodamine 6G using high-performance liquid chromatography. The molecularly imprinted polymer coating was prepared by copolymerization of dopamine and m-aminophenylboronic acid (functional monomers), in the presence of rhodamine 6G (template). The selection of the suitable functional monomers was based on the interaction between different monomers and the template using the density functional theory. The ratios of the monomers to template were further optimized by an OA9 (3(4) ) orthogonal array design. The binding performances of the adsorbent were evaluated by static, kinetic, and selective adsorption experiments. The results reveal that the adsorbent possesses remarkable affinity and binding specificity for rhodamine 6G because of the enhanced Lewis acid-base interaction between the B(Ш) embedded in the imprinted cavities and the template. The nano-adsorbent was successfully applied to dispersive micro-solid-phase extraction coupled to high-performance liquid chromatography for the trace determination of rhodamine 6G in samples with a detection limit of 2.7 nmol/L. Spiked recoveries ranged from 93.0-99.1, 89.5-92.7, and 86.9-105% in river water, matrimony vine and paprika samples, respectively, with relative standard deviations of less than 4.3%. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Determination of organophosphorus pesticides in bovine tissue by an on-line coupled matrix solid-phase dispersion-solid phase extraction-high performance liquid chromatography with diode array detection method. (United States)

    Gutiérrez Valencia, Tania M; García de Llasera, Martha P


    A miniaturized method based on matrix solid-phase dispersion coupled to solid phase extraction and high performance liquid chromatography with diode array detection (MSPD-SPE-HPLC/DAD) was developed for the trace simultaneous determination of the following organophosphorus pesticides (OPPs) in bovine tissue: parathion-methyl, fenitrothion, parathion, chlorfenvinphos, diazinon, ethion, fenchlorphos, chlorpyrifos and carbophenothion. To perform the coupling between MSPD and SPE, 0.05 g of sample was dispersed with 0.2 g of C(18) silica sorbent and packed into a stainless steel cartridge containing 0.05 g of silica gel in the bottom. After a clean-up of high and medium polarity interferences with water and an acetonitrile:water mixture, the OPPs were desorbed from the MSPD cartridge with pure acetonitrile and directly transferred to a dynamic mixing chamber for dilution with water and preconcentration into an SPE 20 mm × 2.0 mm I.D. C(18) silica column. Subsequently, the OPPs were eluted on-line with the chromatographic mobile phase to the analytical column and the diode array detector for their separation and detection, respectively. The method was validated and yielded recovery values between 91% and 101% and precision values, expressed as relative standard deviations (RSD), which were less than or equal to 12%. Linearity was good and ranged from 0.5 to 10 μg g(-1), and the limits of detection of the OPPs were in the range of 0.04-0.25 μg g(-1). The method was satisfactorily applied to the analysis of real samples and is recommended for food control, research efforts when sample amounts are limited, and laboratories that have ordinary chromatographic instrumentation. Copyright © 2011 Elsevier B.V. All rights reserved.

  20. Experimental investigation of two-phase flow patterns in minichannels at horizontal orientation (United States)

    Saljoshi, P. S.; Autee, A. T.


    Two-phase flow is the simplest case of multiphase flow in which two phases are present for a pure component. The mini channel is considered as diameter below 3.0-0.2 mm and conventional channel is considered diameter above 3.0 mm. An experiment was conducted to study the adiabatic two-phase flow patterns in the circular test section with inner diameter of 1.1, 1.63, 2.0, 2.43 and 3.0 mm for horizontal orientation using air and water as a fluid. Different types of flow patterns found in the experiment. The parameters that affect most of these patterns and their transitions are channel size, phase superficial velocities (air and liquid) and surface tension. The superficial velocity of liquid and gas ranges from 0.01 to 66.70 and 0.01 to 3 m/s respectively. Two-phase flow pattern photos were recorded using a high speed CMOS camera. In this experiment different flow patterns were identified for different tube diameters that confirm the diameter effect on flow patterns in two-phase flows. Stratified flow was not observed for tube diameters less than 3.0 mm. Similarly, wavy-annular flow pattern was not observed in 1.6 and 1.0 mm diameter tubes due to the surface-tension effect and decrease in tube diameter. Buoyancy effects were clearly visible in 2.43 and 3.0 mm diameter tubes flow pattern. It has also observed that as the test-section diameter decreases the transition lines shift towards the higher gas and liquid velocity. However, the result of flow pattern lines in the present study has good agreement with the some of the existing flow patterns maps.

  1. Experimental study on the two-phase pressure drop in copper foams (United States)

    Ji, Xianbing; Xu, Jinliang


    Experiments were performed to study pressure drops in copper foams embedded in a rectangular copper channel. De-ionized water was used as the working fluid with mass fluxes of 30-200 kg/m2 s, and inlet temperature of 40-80°C. The copper foam has the porosity of 0.88 and the pore densities of 30, 60 and 90 ppi (pores per inch). Both single-phase liquid flow and boiling two-phase flow are studied. Effects of mass fluxes, vapor mass qualities, and average pore diameters of metallic foams are investigated. It is found that friction factors for the single-phase liquid flow are mainly dependent on the Reynolds number and the average pore diameter of metallic foams. The friction factors are decreased with increases in the Reynolds numbers, and will approach 0.22 at high Reynolds numbers. For the boiling two-phase flow, two-phase pressure drops are increased with increases in the outlet vapor mass qualities, mass fluxes, and ppi values. The two-phase multiplier is increased with increases in the outlet vapor mass qualities and mass fluxes, and it is decreased with increases in the Martinelli parameter and will attain a constant value depending on the mass fluxes. The larger the mass fluxes, the larger the constant value is. An experimental correlation considering the effects of vapor mass qualities, mass fluxes, and average pore diameters of metallic foams is recommended, showing good accuracy to predict the two-phase pressure drops in metallic foams.

  2. Dynamic Modeling Strategy for Flow Regime Transition in Gas-Liquid Two-Phase Flows

    Directory of Open Access Journals (Sweden)

    Xia Wang


    Full Text Available In modeling gas-liquid two-phase flows, the concept of flow regimes has been widely used to characterize the global interfacial structure of the flows. Nearly all constitutive relations that provide closures to the interfacial transfers in two-phase flow models, such as the two-fluid model, are flow regime dependent. Current nuclear reactor safety analysis codes, such as RELAP5, classify flow regimes using flow regime maps or transition criteria that were developed for steady-state, fully-developed flows. As two-phase flows are dynamic in nature, it is important to model the flow regime transitions dynamically to more accurately predict the two-phase flows. The present work aims to develop a dynamic modeling strategy to determine flow regimes in gas-liquid two-phase flows through introduction of interfacial area transport equations (IATEs within the framework of a two-fluid model. The IATE is a transport equation that models the interfacial area concentration by considering the creation of the interfacial area, fluid particle (bubble or liquid droplet disintegration, boiling and evaporation, and the destruction of the interfacial area, fluid particle coalescence and condensation. For flow regimes beyond bubbly flows, a two-group IATE has been proposed, in which bubbles are divided into two groups based on their size and shapes, namely group-1 and group-2 bubbles. A preliminary approach to dynamically identify the flow regimes is discussed, in which discriminators are based on the predicted information, such as the void fraction and interfacial area concentration. The flow regime predicted with this method shows good agreement with the experimental observations.

  3. Mechanistic analysis of solute transport in an in vitro physiological two-phase dissolution apparatus (United States)

    Mudie, Deanna M.; Shi, Yi; Ping, Haili; Gao, Ping; Amidon, Gordon L.; Amidon, Gregory E.


    In vitro dissolution methodologies that adequately capture the oral bioperformance of solid dosage forms are critical tools needed to aid formulation development. Such methodologies must encompass important physiological parameters and be designed with drug properties in mind. Two-phase dissolution apparatuses, which contain an aqueous phase in which the drug dissolves (representing the dissolution/solubility component) and an organic phase into which the drug partitions (representing the absorption component), have the potential to provide meaningful predictions of in vivo oral bioperformance for some BCS II, and possibly some BCS IV drug products. Before such an apparatus can be evaluated properly, it is important to understand the kinetics of drug substance partitioning from the aqueous to the organic medium. A mass transport analysis was performed of the kinetics of partitioning of drug substance solutions from the aqueous to the organic phase of a two-phase dissolution apparatus. Major assumptions include pseudo-steady-state conditions, a dilute aqueous solution and diffusion-controlled transport. Input parameters can be measured or estimated a priori. This paper presents the theory and derivation of our analysis, compares it with a recent kinetic approach, and demonstrates its effectiveness in predicting in vitro partitioning profiles of three BCS II weak acids in four different in vitro two-phase dissolution apparatuses. Very importantly, the paper discusses how a two-phase apparatus can be scaled to reflect in vivo absorption kinetics and for which drug substances the two-phase dissolution systems may be appropriate tools for measuring oral bioperformance. PMID:22847296

  4. Two-phase flow instabilities in a silicon microchannels heat sink

    Energy Technology Data Exchange (ETDEWEB)

    Bogojevic, D. [School of Engineering, University of Edinburgh, Mayfield Road, King' s Buildings, EH9 3JL Edinburgh (United Kingdom); Sefiane, K. [School of Engineering, University of Edinburgh, Mayfield Road, King' s Buildings, EH9 3JL Edinburgh (United Kingdom)], E-mail:; Walton, A.J.; Lin, H.; Cummins, G. [Scottish Microelectronic Centre, Joint Research Institute for Integrated Systems, School of Engineering, University of Edinburgh, EH9 3JF (United Kingdom)


    Two-phase flow instabilities are highly undesirable in microchannels-based heat sinks as they can lead to temperature oscillations with high amplitudes, premature critical heat flux and mechanical vibrations. This work is an experimental study of boiling instabilities in a microchannel silicon heat sink with 40 parallel rectangular microchannels, having a length of 15 mm and a hydraulic diameter of 194 {mu}m. A series of experiments have been carried out to investigate pressure and temperature oscillations during the flow boiling instabilities under uniform heating, using water as a cooling liquid. Thin nickel film thermometers, integrated on the back side of a heat sink with microchannels, were used in order to obtain a better insight related to temperature fluctuations caused by two-phase flow instabilities. Flow regime maps are presented for two inlet water temperatures, showing stable and unstable flow regimes. It was observed that boiling leads to asymmetrical flow distribution within microchannels that result in high temperature non-uniformity and the simultaneously existence of different flow regimes along the transverse direction. Two types of two-phase flow instabilities with appreciable pressure and temperature fluctuations were observed, that depended on the heat to mass flux ratio and inlet water temperature. These were high amplitude/low frequency and low amplitude/high frequency instabilities. High speed camera imaging, performed simultaneously with pressure and temperature measurements, showed that inlet/outlet pressure and the temperature fluctuations existed due to alternation between liquid/two-phase/vapour flows. It was also determined that the inlet water subcooling condition affects the magnitudes of the temperature oscillations in two-phase flow instabilities and flow distribution within the microchannels.

  5. Simultaneous separation/enrichment and detection of trace ciprofloxacin and lomefloxacin in food samples using thermosensitive smart polymers aqueous two-phase flotation system combined with HPLC. (United States)

    Lu, Yang; Chen, Bo; Yu, Miao; Han, Juan; Wang, Yun; Tan, Zhenjiang; Yan, Yongsheng


    Smart polymer aqueous two phase flotation system (SPATPF) is a new separation and enrichment technology that integrated the advantages of the three technologies, i.e., aqueous two phase system, smart polymer and flotation sublation. Ethylene oxide and propylene oxide copolymer (EOPO)-(NH4)2SO4 SPATPF is a pretreatment technique, and it is coupled with high-performance liquid chromatography to analyze the trace ciprofloxacin and lomefloxacin in real food samples. The optimized conditions of experiment were determined in the multi-factor experiment by using response surface methodology. The flotation efficiency of lomefloxacin and ciprofloxacin was 94.50% and 98.23% under the optimized conditions. The recycling experimentsshowed that the smart polymer EOPO could use repeatedly, which will reduce the cost in the future application. Copyright © 2016 Elsevier Ltd. All rights reserved.

  6. A hybrid level set-front tracking finite element approach for fluid-structure interaction and two-phase flow applications (United States)

    Basting, Steffen; Weismann, Martin


    We present a hybrid level set-front tracking approach suitable for fluid-structure interaction and two-phase flow applications. Our approach aims at extending geometrical flexibility of standard mesh moving/front tracking methods by introducing an additional implicit level set representation of the geometry under consideration. The computational mesh is automatically aligned to the implicitly described geometry by minimizing a nonlinear, constrained functional. Resulting triangulations approximate the geometry accurately while being optimal in a certain sense. Due to the mesh alignment, finite element spaces defined on these triangulations may be easily adjusted to account for special solution properties such as discontinuities across interfaces. In order to demonstrate the flexibility of the proposed approach, we apply it to a simplified one-way coupled fluid-structure interaction problem inspired by the flow induced by a moving cardiac valve. Furthermore we evaluate the approach by solving a two-phase flow benchmark problem.

  7. Determination of phthalate esters in distillates by ultrasound-vortex-assisted dispersive liquid-liquid micro-extraction (USVADLLME) coupled with gas chromatography/mass spectrometry. (United States)

    Montevecchi, Giuseppe; Masino, Francesca; Zanasi, Luca; Antonelli, Andrea


    A method for the extraction of phthalate esters (PAEs) by Ultrasound-Vortex-Assisted Dispersive Liquid-Liquid Micro-Extraction (USVADLLME) approach was optimised and applied for the first time to a historical series of brandies. These contaminants are widely spread in the environment as a consequence of about half century of use in different fields of applications. The concern about these substances and the recent legal restrictions of China in distillates import need a quick and sensitive method for their quantification. The proposed method, moreover, is environmentally oriented due to the disposal of micro-quantities of solvent required. In fact, sub-ppm-limits of detection were achieved with a solvent volume as low as 160μL. The analysed samples were within the legal limits, except for some very ancient brandies whose contamination was probably due to a PAEs concentration effect as a consequence of long ageing and for the use of plastic pipelines no more operative. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. Determination of dyes in cosmetic products by micro-matrix solid phase dispersion and liquid chromatography coupled to tandem mass spectrometry. (United States)

    Guerra, Eugenia; Celeiro, Maria; Lamas, J Pablo; Llompart, Maria; Garcia-Jares, Carmen


    A simple method based on micro-matrix solid phase dispersion (MSPD) followed by liquid chromatography-mass spectrometry (LC-MS/MS) has been developed for the rapid and simultaneous determination of nine regulated water-soluble dyes in personal care and decorative products. The proposed miniaturized extraction procedure was optimized by means of experimental designs in order to obtain the highest extraction efficiency. Under the optimal selected conditions, the method was validated showing satisfactory performance in terms of linearity, sensitivity, and intra-day and inter-day precision. Recoveries were evaluated in different cosmetic matrices and they can be considered quantitative with average values between 70 and 120% with relative standard deviations (RSD) lower than 15%. Finally, the validated method was applied to 24 samples of cosmetic and personal care products, including decorative makeup, lipsticks, lip gloss, toothpastes, regenerating creams, shampoos, and eye shadows, among others, to cover a broad range of commercial real samples. Seven of the analyzed dyes were detected, being declared all of them in the label list of ingredients. More than 50% of the samples contained at least two dyes. Tartrazine was the most frequently found (50% of the samples) at concentration levels of 0.243-79.9μgg(-1). Other targets were found in 1-9 samples, highlighting the presence of Quinoline at high concentration (>500μgg(-1)) in a toothpaste sample. Copyright © 2015 Elsevier B.V. All rights reserved.

  9. Anomalous dispersion and band gap reduction in UO{sub 2+x} and its possible coupling to the coherent polaronic quantum state

    Energy Technology Data Exchange (ETDEWEB)

    Conradson, Steven D. [Synchrotron Soleil, Saint-Aubin BP-48, 91192 (France); Andersson, David A. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Bagus, Paul S. [University of North Texas, Denton, TX 76203 (United States); Boland, Kevin S.; Bradley, Joseph A.; Byler, Darrin D.; Clark, David L.; Conradson, Dylan R. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Espinosa-Faller, Francisco J. [Universidad Marista de Merida, Merida, Yucatan 97300 (Mexico); Lezama Pacheco, Juan S.; Martucci, Mary B. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Nordlund, Dennis [SLAC National Accelerator Laboratory, Menlo Park, CA 94025 (United States); Seidler, Gerald T. [University of Washington, Seattle, WA 98195 (United States); Valdez, James A. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)


    Hypervalent UO{sub 2}, UO{sub 2(+x)} formed by both addition of excess O and photoexcitation, exhibits a number of unusual or often unique properties that point to it hosting a polaronic Bose–Einstein(-Mott) condensate. A more thorough analysis of the O X-ray absorption spectra of UO{sub 2}, U{sub 4}O{sub 9}, and U{sub 3}O{sub 7} shows that the anomalous increase in the width of the spectral features assigned to predominantly U 5f and 6d final states that points to increased dispersion of these bands occurs on the low energy side corresponding to the upper edge of the gap bordered by the conduction or upper Hubbard band. The closing of the gap by 1.5 eV is more than twice as much as predicted by calculations, consistent with the dynamical polaron found by structural measurements. In addition to fostering the excitation that is the proposed mechanism for the coherence, the likely mirroring of this effect on the occupied, valence side of the gap below the Fermi level points to increased complexity of the electronic structure that could be associated with the Fermi topology of BEC–BCS crossover and two band superconductivity.

  10. Determination of antimony and tin in beverages using inductively coupled plasma-optical emission spectrometry after ultrasound-assisted ionic liquid dispersive liquid-liquid phase microextraction. (United States)

    Biata, N Raphael; Nyaba, Luthando; Ramontja, James; Mketo, Nomvano; Nomngongo, Philiswa N


    The aim of this study was to develop a simple and fast ultrasound-assisted ionic liquid dispersive liquid-liquid phase microextraction (UA-IL-DLLME) method for preconcetration of trace antimony and tin in beverage samples. The novelty of this study was based on the application of ligandless UA-IL-DLLME using low-density ionic liquid and organic solvents for preconcentration of Sb and Sn. The concentration of Sb and Sn were quantified using ICP-OES. Under the optimum conditions, the calibration graph was found to be LOQ-250µgL(-1) (r(2)=0.9987) for Sb and LOQ-350µgL(-1) for Sn. The LOD and LOQ of Sb and Sn ranged from 1.2to 2.5ngL(-1) and 4.0 to 8.3ngL(-1), respectively, with high preconcentration factors. The precisions (%RSD) of the proposed method ranged from 2.1% to 2.5% and 3.9% to 4.7% for Sb and Sn, respectively. The proposed method was successfully applied for determination of Sb and Sn in beverages. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. Salting-out assisted liquid-liquid extraction coupled to dispersive liquid-liquid microextraction for the determination of chlorophenols in wine by high-performance liquid chromatography. (United States)

    Fan, Yingying; Hu, Shibin; Liu, Shuhui


    A novel procedure of sample preparation combined with high-performance liquid chromatography with diode array detection is introduced for the analysis of highly chlorinated phenols (trichlorophenols, tetrachlorophenols, and pentachlorophenol) in wine. The main features of the proposed method are (i) low-toxicity diethyl carbonate as extraction solvent to selectively extract the analytes without matrix effect, (ii) the combination of salting-out assisted liquid-liquid extraction and dispersive liquid-liquid microextraction to achieve an enrichment factor of 334-361, and (iii) the extract is analyzed by high-performance liquid chromatography to avoid derivatization. Under the optimum conditions, correlation coefficients (r) were >0.997 for calibration curves in the range 1-80 ng/mL, detection limits and quantification limits ranged from 0.19 to 0.67 and 0.63 to 2.23 ng/mL, respectively, and relative standard deviation was <8%. The method was applied for the determination of chlorophenols in real wines, with recovery rates in the range 82-104%. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. SPE coupled with dispersive liquid-liquid microextraction followed by GC with flame ionization detection for the determination of ultra-trace amounts of benzodiazepines. (United States)

    Ghobadi, Masoomeh; Yamini, Yadollah; Ebrahimpour, Behnam


    SPE combined with dispersive liquid-liquid microextration was used for the extraction of ultra-trace amounts of benzodiazepines (BZPs) including, diazepam, midazolam, and alprazolam, from ultra-pure water, tap water, fruit juices, and urine samples. The analytes were adsorbed from large volume samples (60 mL) onto octadecyl silica SPE columns. After the elution of the desired compounds from sorbents with 2.0 mL acetone, 0.5 mL of eluent containing 40.0 μL chloroform was injected rapidly into 4.5 mL pure water. After extraction and centrifugation, 2 μL of the sedimented phase was injected into a GC equipped with a flame ionization detector. Several parameters affecting this process were investigated and optimized. Under the optimal conditions, LODs ranged from 0.02 to 0.05 μg/L, a linear dynamic range of 0.1-100 μg/L and relative SDs in the range of 4.4-10.7% were attained. Very high preconcentration factors ranging from 3895-7222 were achieved. The applicability of the method for the extraction of BZPs from different types of complicated matrices, such as tap water, fruit juices, and urine samples, was studied. The obtained results reveal that the proposed method is a good technique for the extraction and determination of BZPs in complex matrices. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. Graphene oxide adsorbent based dispersive solid phase extraction coupled with multi-pretreatment clean-up for analysis of trace aflatoxins in traditional proprietary Chinese medicines. (United States)

    Ran, Congcong; Chen, Dan; Ma, Haiyan; Jiang, Ye


    Graphene oxide (GO)-based dispersive solid phase extraction (D-SPE) method combined with multi-step preparation has been proposed for the evaluation of trace aflatoxins in proprietary Chinese medicines (PCM). After being extracted by methanol, the sample was purified based on multi-step preparation, including dehydration with MgSO4/NaCl and cleanup with neutral alumina. Then GO was used as an adsorbent in D-SPE method for further preconcentration of aflatoxins prior to high performance liquid chromatography-fluorescence detection. The selected conditions were investigated. The Box-Behnken design (BBD) was used to optimize factors affecting adsorption procedure. Under the optimized conditions, good linear relationships had been achieved with the correlation coefficient (R(2)) varying from 0.9904 to 0.9990. The LODs and LOQs were ranging from 0.020 to 0.041ng/mL and 0.061 to 0.125ng/mL, respectively. The results of the recoveries were 74.0-102.7% for the four aflatoxins, while the precisions from 1.8% to 7.2% were obtained, which indicated that the method was suitable for the analysis of aflatoxins in PCM. Copyright © 2017 Elsevier B.V. All rights reserved.

  14. Robust Multiscale Modelling Of Two-Phase Steels On Heterogeneous Hardware Infrastructures By Using Statistically Similar Representative Volume Element

    Directory of Open Access Journals (Sweden)

    Rauch Ł.


    Full Text Available The coupled finite element multiscale simulations (FE2 require costly numerical procedures in both macro and micro scales. Attempts to improve numerical efficiency are focused mainly on two areas of development, i.e. parallelization/distribution of numerical procedures and simplification of virtual material representation. One of the representatives of both mentioned areas is the idea of Statistically Similar Representative Volume Element (SSRVE. It aims at the reduction of the number of finite elements in micro scale as well as at parallelization of the calculations in micro scale which can be performed without barriers. The simplification of computational domain is realized by transformation of sophisticated images of material microstructure into artificially created simple objects being characterized by similar features as their original equivalents. In existing solutions for two-phase steels SSRVE is created on the basis of the analysis of shape coefficients of hard phase in real microstructure and searching for a representative simple structure with similar shape coefficients. Optimization techniques were used to solve this task. In the present paper local strains and stresses are added to the cost function in optimization. Various forms of the objective function composed of different elements were investigated and used in the optimization procedure for the creation of the final SSRVE. The results are compared as far as the efficiency of the procedure and uniqueness of the solution are considered. The best objective function composed of shape coefficients, as well as of strains and stresses, was proposed. Examples of SSRVEs determined for the investigated two-phase steel using that objective function are demonstrated in the paper. Each step of SSRVE creation is investigated from computational efficiency point of view. The proposition of implementation of the whole computational procedure on modern High Performance Computing (HPC

  15. A simulation analysis of the advective effect on evaporation using a two-phase heat and mass flow model (United States)

    Zeng, Yijian; Su, Zhongbo; Wan, Li; Wen, Jun


    The concept of enhanced vapor transfer in unsaturated soils has been questioned for its reliance on soil temperature gradient, which leads to consideration of other mechanisms of vapor transfer, e.g., advective vapor transfer due to soil air pressure gradient. Although the advective flux is an important portion of evaporation, there is a lack of knowledge of its effect on evaporation. In order to assess the dependence of evaporation on the soil air pressure gradient, a vertical one-dimensional two-phase heat and mass flow model is developed that fully considers diffusion, advection, and dispersion. The proposed model is calibrated with field measurements of soil moisture content and temperature in the Badain Jaran Desert. The proposed model is then used to investigate the advective effect in both low- and high-permeability soils. The advective effect is reflected by underestimating evaporation when the airflow is neglected and is more evident in the low-permeability soil. Neglecting airflow causes an underestimation error of 53.3% on the day right after a rainfall event in the low-permeability soil (7.9 × 10-4 cm s-1) and 33.3% in the high-permeability soil (2 × 10-3 cm s-1). The comparisons of driving forces and conductivities show that the isothermal liquid flux, driven by the soil matric potential gradient, is the main reason for the underestimation error.

  16. Propagation characteristics of interface waves between a porous medium and a sediment-containing two-phase fluid. (United States)

    Han, Qingbang; Qi, Lihua; Shan, Minglei; Yin, Cheng; Jiang, Xueping; Zhu, Changping


    Based on the modified Biot theory of Johnson, the propagation characteristics of the various interface waves at an interface between a semi-infinite fluid and a porous medium were studied. First, based on the characteristic equations of open-pore and sealed-pore, which were derived from the wave equations, time-domain waveforms at the interface were obtained by inverse Fourier transform. The effects of the longitudinal frame modulus on the interface waves were investigated. For open-pore and sealed-pore, the effect of porosity on the propagation of the interface waves was studied; the porosity was found to strongly influence the true surface wave. Based on four ultrasonic suspension models-Utrick, Utrick-Ament (UA), Harker-Temple (HT) and McClement, the pseudo-Stoneley wave propagation characteristics were analyzed at the interface between the sediment-containing two-phase fluid and the porous medium solid. The effects of volume fraction and particle diameter on the phase velocity, attenuation coefficient and dispersion for the pseudo-Stoneley and true surface wave were discussed, and the results demonstrated that the properties of the fluid strongly impacted the pseudo-Stoneley wave but exerted very little effect on the true surface wave. The conclusions drawn in this paper could contribute to elucidate the parameters of sediment and porous media. Copyright © 2017 Elsevier B.V. All rights reserved.

  17. A rapid MCM-41 dispersive micro-solid phase extraction coupled with LC/MS/MS for quantification of ketoconazole and voriconazole in biological fluids. (United States)

    Yahaya, Noorfatimah; Sanagi, Mohd Marsin; Abd Aziz, Noorizan; Wan Ibrahim, Wan Aini; Nur, Hadi; Loh, Saw Hong; Kamaruzaman, Sazlinda


    A rapid dispersive micro-solid phase extraction (D-μ-SPE) combined with LC/MS/MS method was developed and validated for the determination of ketoconazole and voriconazole in human urine and plasma samples. Synthesized mesoporous silica MCM-41 was used as sorbent in d-μ-SPE of the azole compounds from biological fluids. Important D-μ-SPE parameters, namely type desorption solvent, extraction time, sample pH, salt addition, desorption time, amount of sorbent and sample volume were optimized. Liquid chromatographic separations were carried out on a Zorbax SB-C 18 column (2.1 × 100 mm, 3.5 μm), using a mobile phase of acetonitrile-0.05% formic acid in 5 mm ammonium acetate buffer (70:30, v/v). A triple quadrupole mass spectrometer with positive ionization mode was used for the determination of target analytes. Under the optimized conditions, the calibration curves showed good linearity in the range of 0.1-10,000 μg/L with satisfactory limit of detection (≤0.06 μg/L) and limit of quantitation (≤0.3 μg/L). The proposed method also showed acceptable intra- and inter-day precisions for ketoconazole and voriconazole from urine and human plasma with RSD ≤16.5% and good relative recoveries in the range 84.3-114.8%. The MCM-41-D-μ-SPE method proved to be rapid and simple and requires a small volume of organic solvent (200 μL); thus it is advantageous for routine drug analysis. Copyright © 2016 John Wiley & Sons, Ltd.

  18. Zirconium (IV)-based metal organic framework (UIO-67) as efficient sorbent in dispersive solid phase extraction of plant growth regulator from fruits coupled with HPLC fluorescence detection. (United States)

    Liu, Lijie; Xia, Lian; Wu, Chuanxiang; Qu, Fengli; Li, Guoliang; Sun, Zhiwei; You, Jinmao


    A stable zirconium (Ⅳ)-based metal organic frameworks (UIO-67) material possessing good chemical, thermal and water stability was synthesized and applied as a sorbent for the dispersive solid phase extraction (DSPE) of 8 plant growth regulators (PGRs) in fruit samples. Fluorescence labeling combined with high performance liquid chromatography fluorescence detection (HPLC-FLD), was used to quantify the target analytes. Characterization of the UIO-67 material was performed by X-ray diffraction(XRD) and scanning electron microscopy (SEM). The experimental parameters, such as amount of UIO-67, type and volume of eluting solvent, adsorption and desorption time, were optimized. Under the optimized conditions, good linearity was observed in the range of 10-1000 pmol/mL with R(2)>0.9989. The limits of detection and limits of quantification were in the range of 0.21-0.57ng/mL and 0.81-1.91ng/mL, respectively. The intra-day and inter-day precisions (based on the relative standard deviation, n=3) of the PGR derivatives were under 3.1% and 5.3% respectively and the accuracies of the method for the PGRs were in the range from 89.3% to 102.3%. The developed method was successfully applied to analyze PGRs residues in fruit samples. The proposed method is proved to be simple, environment-friendly and inexpensive and it is feasible to directly use UIO-67 as sorbent to extract targets by varying conditions. Copyright © 2016 Elsevier B.V. All rights reserved.

  19. Rapid determination of phthalate esters in alcoholic beverages by conventional ionic liquid dispersive liquid-liquid microextraction coupled with high performance liquid chromatography. (United States)

    Fan, Yingying; Liu, Shuhui; Xie, Qilong


    A very simple, fast and environmentally friendly sample extraction method was proposed for the analysis of phthalate esters (PAEs, di-isobutyl phthalate (DIBP), dibutylphthalate (DBP), butylbenzylphthalate (BBP) and bis(2-ethylhexyl)phthalate (DEHP)) in alcoholic beverages by using conventional ionic liquid dispersive liquid-liquid microextraction. The samples were extracted by 160 μL 1-octyl-3-methylimidazolium hexafluorophosphate in the presence of appropriate amount of ethanol and 10% (w/v) sodium chloride solution; the enriched analytes in sedimented phases were analyzed by high performance liquid chromatography-diode array detector (HPLC-DAD). Under the optimum conditions, a satisfactory linearity (in the range of 0.02-1 μg mL(-1) for white spirits and 0.01-0.5 μg mL(-1) for red wines with the correlation coefficients (r) varying from 0.9983 to 1), acceptable recovery rates (88.5-103.5% for white spirits and 91.6-104.6% for red wines), good repeatability (RSD ≤ 8.0%) and low detection limits (3.1-4.2 ng mL(-1) for white spirits and 1.5-2.2 ng mL(-1) for red wines) were obtained. The developed method was successfully applied for the determination of the four PAEs in 30 white spirits and 11 red wines collected locally, and the DBP content in 63% (19:30) white spirits exceeded the specific migration limit of 0.3 mg kg(-1) established by international regulation. © 2013 Elsevier B.V. All rights reserved.

  20. Flow Patterns Transition Law of Oil-Water Two-Phase Flow under a Wide Range of Oil Phase Viscosity Condition

    Directory of Open Access Journals (Sweden)

    Wei Wang


    Full Text Available A systematic work on the prediction of flow patterns transition of the oil-water two-phase flows is carried out under a wide range of oil phase viscosities, where four main flow regimes are considered including stratified, dispersed, core-annular, and intermittent flow. For oil with a relatively low viscosity, VKH criterion is considered for the stability of stratified flow, and critical drop size model is distinguished for the transition of o/w and w/o dispersed flow. For oil with a high viscousity, boundaries of core-annular flow are based on criteria proposed by Bannwart and Strazza et al. and neutral stability law ignoring that the velocity of the viscous phase is introduced for stratified flow. Comparisons between predictions and quantities of available data in both low and high viscosity oil-water flow from literatures show a good agreement. The framework provides extensive information about flow patterns transition of oil-water two-phase flow for industrial application.

  1. Some numerical methods for two-fluid two-phase flows in oil pipes; Quelques methodes numeriques pour les ecoulements diphasiques bi-fluide en conduites petrolieres

    Energy Technology Data Exchange (ETDEWEB)

    Masella, J.M.


    This thesis is devoted to the numerical simulation of some two-fluid models describing gas-liquid two-phase flow in pipes. The numerical models developed here can be more generally used in the modelling of a wide class of physical models which can be put under an hyperbolic form. We introduce first two isothermal two-fluid models, composed of a mass balance equation and a momentum equation written in each phase, describing respectively a stratified two-phase flow and a dispersed two-phase flow. These models are hyperbolic under some physical assumptions and can be written under a nonconservative vectorial system. We define and analyse a new numerical finite volume scheme (v{integral}Roe) founded on a linearized Riemann solver. This scheme does not need any analytical calculation and gives good results in the tracking of shocks. We compare this new scheme with the classical Roe scheme. Then we propose and study some numerical models, with and without flux splitting method, which are adapted to the discretization of the two-fluid models. This numerical models are given by a finite volume integration of the equations, and lean on the v{integral} scheme. In order to reducing cpu time, due to the low Mach number of two-phase flows, acoustic waves are implicit. Afterwards we proposed a discretization of boundary conditions, which allows the generation of transient flows in pipe. Some numerical academic and more physical tests show the good behaviour of the numerical methods. (author) 77 refs.

  2. Development of a Front Tracking Method for Two-Phase Micromixing of Incompressible Viscous Fluids with Interfacial Tension in Solvent Extraction

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, Yijie [ORNL; Lim, Hyun-Kyung [ORNL; de Almeida, Valmor F [ORNL; Navamita, Ray [State University of New York, Stony Brook; Wang, Shuqiang [State University of New York, Stony Brook; Glimm, James G [ORNL; Li, Xiao-lin [State University of New York, Stony Brook; Jiao, Xiangmin [ORNL


    This progress report describes the development of a front tracking method for the solution of the governing equations of motion for two-phase micromixing of incompressible, viscous, liquid-liquid solvent extraction processes. The ability to compute the detailed local interfacial structure of the mixture allows characterization of the statistical properties of the two-phase mixture in terms of droplets, filaments, and other structures which emerge as a dispersed phase embedded into a continuous phase. Such a statistical picture provides the information needed for building a consistent coarsened model applicable to the entire mixing device. Coarsening is an undertaking for a future mathematical development and is outside the scope of the present work. We present here a method for accurate simulation of the micromixing dynamics of an aqueous and an organic phase exposed to intense centrifugal force and shearing stress. The onset of mixing is the result of the combination of the classical Rayleigh- Taylor and Kelvin-Helmholtz instabilities. A mixing environment that emulates a sector of the annular mixing zone of a centrifugal contactor is used for the mathematical domain. The domain is small enough to allow for resolution of the individual interfacial structures and large enough to allow for an analysis of their statistical distribution of sizes and shapes. A set of accurate algorithms for this application requires an advanced front tracking approach constrained by the incompressibility condition. This research is aimed at designing and implementing these algorithms. We demonstrate verification and convergence results for one-phase and unmixed, two-phase flows. In addition we report on preliminary results for mixed, two-phase flow for realistic operating flow parameters.

  3. Analysis of Two-Phase Flow in Damper Seals for Cryogenic Turbopumps (United States)

    Arauz, Grigory L.; SanAndres, Luis


    Cryogenic damper seals operating close to the liquid-vapor region (near the critical point or slightly su-cooled) are likely to present two-phase flow conditions. Under single phase flow conditions the mechanical energy conveyed to the fluid increases its temperature and causes a phase change when the fluid temperature reaches the saturation value. A bulk-flow analysis for the prediction of the dynamic force response of damper seals operating under two-phase conditions is presented as: all-liquid, liquid-vapor, and all-vapor, i.e. a 'continuous vaporization' model. The two phase region is considered as a homogeneous saturated mixture in thermodynamic equilibrium. Th flow in each region is described by continuity, momentum and energy transport equations. The interdependency of fluid temperatures and pressure in the two-phase region (saturated mixture) does not allow the use of an energy equation in terms of fluid temperature. Instead, the energy transport is expressed in terms of fluid enthalpy. Temperature in the single phase regions, or mixture composition in the two phase region are determined based on the fluid enthalpy. The flow is also regarded as adiabatic since the large axial velocities typical of the seal application determine small levels of heat conduction to the walls as compared to the heat carried by fluid advection. Static and dynamic force characteristics for the seal are obtained from a perturbation analysis of the governing equations. The solution expressed in terms of zeroth and first order fields provide the static (leakage, torque, velocity, pressure, temperature, and mixture composition fields) and dynamic (rotordynamic force coefficients) seal parameters. Theoretical predictions show good agreement with experimental leakage pressure profiles, available from a Nitrogen at cryogenic temperatures. Force coefficient predictions for two phase flow conditions show significant fluid compressibility effects, particularly for mixtures with low mass

  4. Non-thermal equilibrium two-phase flow for melt migration and ascent (United States)

    Schmeling, Harro; Marquart, Gabriele


    We develop a theory for heat exchange between a fluid phase in a solid porous matrix where the temperature of the fluid and of the matrix are different, i. e. not in thermal equilibrium. The formulation considers moving of the fluid within the porous matrix as well as moving of the matrix in an Eulerian grid. The theory can be applied to melts in partially molten rocks, particularly aiming at the transitional regime between melt percolation and flow through dikes, as well as to brine transport in porous rocks. The theory involves the energy conservation equations for the fluid and the solid phase which are coupled by a heat exchange term. We derive an expression based on a Fourier decomposition of a periodic half-waves for a macroscopic description of the non-equal temperatures in the fluid and the solid considering the relative volumetric fractions and surface to volume relations of the pores. We present a formulation for the heat exchange between the two phases taking into account different thermal conductivities of the fluid and the solid and considering the temporal evolution of the heat exchange. The latter leads to a convolution integral in case of a resting matrix. The evolution of the temperature in both phases with time is derived upon inserting the heat exchange term in the energy equations. We test the theory for a simple 1D case of sudden temperature difference between fluid and solid and vary fluid fractions and differential velocities between fluid and solid to obtain the requisites for the maximum Fourier coefficient and the time increments for numerical integration. The necessary time increments are small (between 10^-3 d2 / κ to 10^-5 d^2/ κ, where d is a scaling length, e.g. the pore radius and κ is a scaling diffusivity, e.g. the mean diffusivity) and strongly depend on the fluid fraction. The maximum Fourier coefficient need to be as high as 500 to resolve properly the sudden heat exchange between fluid and solid. Our results agree well with

  5. Ceria nanocubic-ultrasonication assisted dispersive liquid-liquid microextraction coupled with matrix assisted laser desorption/ionization mass spectrometry for pathogenic bacteria analysis. (United States)

    Abdelhamid, Hani Nasser; Bhaisare, Mukesh L; Wu, Hui-Fen


    A new ceria (CeO2) nanocubic modified surfactant is used as the basis of a novel nano-based microextraction technique for highly sensitive detection of pathogenic bacteria (Pseudomonas aeruginosa and Staphylococcus aureus). The technique uses ultrasound enhanced surfactant-assisted dispersive liquid-liquid microextraction (UESA-DLLME) with and without ceria (CeO2) followed by matrix assisted laser desorption/ionization mass spectrometry (MALDI-MS). In order to achieve high separation efficiency, we investigated the influential parameters, including extraction time of ultrasonication, type and volume of the extraction solvent and surfactant. Among various surfactants, the cationic surfactants can selectively offer better extraction efficiency on bacteria analysis than that of the anionic surfactants due to the negative charges of bacteria cell membranes. Extractions of the bacteria lysate from aqueous samples via UESA-DLLME-MALDI-MS were successfully achieved by using cetyltrimethyl ammonium bromide (CTAB, 10.0 µL, 1.0×10(-3) M) as surfactants in chlorobenzene (10.0 µL) and chloroform (10.0 µL) as the optimal extracting solvent for P. aeruginosa and S. aureus, respectively. Ceria nanocubic was synthesized, and functionalized with CTAB (CeO2@CTAB) and then characterized using transmission electron microscopy (TEM) and optical spectroscopy (UV and FTIR). CeO2@CTAB demonstrates high extraction efficiency, improve peaks ionization, and enhance resolution. The prime reasons for these improvements are due to the large surface area of nanoparticles, and its absorption that coincides with the wavelength of MALDI laser (337 nm, N2 laser). CeO2@CTAB-based microextraction offers lowest detectable concentrations tenfold lower than that of without nanoceria. The present approach has been successfully applied to detect pathogenic bacteria at low concentrations of 10(4)-10(5) cfu/mL (without ceria) and at 10(3)-10(4) cfu/mL (with ceria) from bacteria suspensions. Finally, the

  6. Two-phase Lattice Boltzmann modelling of streaming potentials: influence of the air-water interface on the electrokinetic coupling (United States)

    Fiorentino, Eve-Agnès; Toussaint, Renaud; Jouniaux, Laurence


    The streaming potential phenomenon is an electrokinetic effect that occurs in porous media. It is characterized by an electrokinetic (EK) coefficient. The aim of this paper is to simulate the EK coefficient in unsaturated conditions using the Lattice Boltzmann method in a 2-D capillary channel. The multiphase flow is simulated with the model of Shan & Chen. The Poisson-Boltzmann equation is solved by implementing the model of Chai & Shi. The streaming potential response shows a non-monotonous behaviour due to the combination of the increase of charge density and decrease of flow velocity with decreasing water saturation. Using a ζ potential of -20 mV at the air-water interface, an enhancement of a factor 5-30 of the EK coefficient, compared to the saturated state, can be observed due to the positive charge excess at this interface which is magnified by the fluid velocity away from the rock surface. This enhancement is correlated to the fractioning of the bubbles, and to the dynamic state of these bubbles, moving or entrapped in the crevices of the channel.

  7. Moving Boudary Models for Dynamic Simulations of Two-phase Flows

    DEFF Research Database (Denmark)

    Jensen, Jakob Munch; Tummelscheit, H.


    ) and consequently the wall also into three regions corresponding to the flow regions. The flow regions are each described by a mass balance and an energy balance, and the wall regions are each described by an energy balance. Some typical model simplifications in MB-models naturally lead to high DAE-index problems....... The Dymola Modelica translator can automatically reduce the DAE index and thus makes efficient simulation possible. Usually the flow entering a dry-expansion evaporator in a refrigeration system is two-phase, and there is thus no liquid region. The general MB model has a number of special cases where only......Two-phase flows are commonly found in components in energy systems such as evaporators and boilers. The performance of these components depends among others on the controller. Transient models describing the evaporation process are important tools for determining control parameters, and fast low...

  8. Ultrafast X-ray tomography for two-phase flow analysis in centrifugal pumps

    Energy Technology Data Exchange (ETDEWEB)

    Schaefer, Thomas [Helmholtz-Zentrum Dresden-Rossendorf, Dresden (Germany). Inst. of Fluid Dynamics; Hampel, Uwe [Helmholtz-Zentrum Dresden-Rossendorf, Dresden (Germany). Inst. of Fluid Dynamics; Technische Univ. Dresden (Germany). AREVA Endowed Chair of Imaging Techniques in Energy and Process Engineering


    The unsteady behavior of gas-liquid two-phase flow in a centrifugal pump impeller has been visualized, using ultrafast X-ray tomography. Based on the reconstructed tomographic images an evaluation and detailed analysis of the flow conditions has been done. Here, the high temporal resolution of the tomographic images offered the opportunity to get a deep insight into the flow to perform a detailed description of the transient gas-liquid phase distribution inside the impeller. Significant properties of the occurring two-phase flow and characteristic flow patterns have been disclosed. Furthermore, the effects of different air entrainment conditions have been investigated and typical phase distributions inside the impeller have been shown.

  9. The Solution of Two-Phase Inverse Stefan Problem Based on a Hybrid Method with Optimization

    Directory of Open Access Journals (Sweden)

    Yang Yu


    Full Text Available The two-phase Stefan problem is widely used in industrial field. This paper focuses on solving the two-phase inverse Stefan problem when the interface moving is unknown, which is more realistic from the practical point of view. With the help of optimization method, the paper presents a hybrid method which combines the homotopy perturbation method with the improved Adomian decomposition method to solve this problem. Simulation experiment demonstrates the validity of this method. Optimization method plays a very important role in this paper, so we propose a modified spectral DY conjugate gradient method. And the convergence of this method is given. Simulation experiment illustrates the effectiveness of this modified spectral DY conjugate gradient method.


    Directory of Open Access Journals (Sweden)

    Ondrej Burian


    Full Text Available This paper deals with identification of parameters of simple pool boiling in a vertical rectangular channel by analysis of pressure fluctuation. In this work is introduced a small experimental facility about 9 kW power, which was used for simulation of pool boiling phenomena and creation of steam-water volume. Several pressure fluctuations measurements and differential pressure fluctuations measurements at warious were carried out. Main changed parameters were power of heaters and hydraulics resistance of channel internals. Measured pressure data was statistically analysed and compared with goal to find dependencies between parameters of two-phase flow and statistical properties of pressure fluctuation. At the end of this paper are summarized final results and applicability of this method for parameters determination of two phase flow for pool boiling conditions at ambient pressure.

  11. Numerical Study of Two-Phase Flow in Micro-/Nanobubble Generating Pump (United States)

    Syaeful Alam, Hilman; Bahrudin; Sugiarto, Anto Tri


    Gas-liquid mixing pump is one of the multiphase flow problem in industrial applications as a micro-/nanobubble generator. However, very few report that studied the two-phase flow for application of microbubble generation because of the analysis complexity. In this paper, a steady state numerical simulation of gas-liquid two-phase flow in the gas-liquid mixing pump was employed to predict a performance and characteristic of fluid flow. Based on simulation results, it is demonstrated that the pump can work in self suction, and generates a vortex flow pattern at every stage of the impeller as regenerative. Performance pump of the numerical simulation is slightly higher than the design specifications Because of mechanical and volume losses was neglected. However, the evaluation method and simulation results from this work can be used as a reference for the design and improvement of the gas-liquid mixing pump.

  12. An acoustic-convective splitting-based approach for the Kapila two-phase flow model

    Energy Technology Data Exchange (ETDEWEB)

    Eikelder, M.F.P. ten, E-mail: [EDF R& D, AMA, 7 boulevard Gaspard Monge, 91120 Palaiseau (France); Eindhoven University of Technology, Department of Mathematics and Computer Science, P.O. Box 513, 5600 MB Eindhoven (Netherlands); Daude, F. [EDF R& D, AMA, 7 boulevard Gaspard Monge, 91120 Palaiseau (France); IMSIA, UMR EDF-CNRS-CEA-ENSTA 9219, Université Paris Saclay, 828 Boulevard des Maréchaux, 91762 Palaiseau (France); Koren, B.; Tijsseling, A.S. [Eindhoven University of Technology, Department of Mathematics and Computer Science, P.O. Box 513, 5600 MB Eindhoven (Netherlands)


    In this paper we propose a new acoustic-convective splitting-based numerical scheme for the Kapila five-equation two-phase flow model. The splitting operator decouples the acoustic waves and convective waves. The resulting two submodels are alternately numerically solved to approximate the solution of the entire model. The Lagrangian form of the acoustic submodel is numerically solved using an HLLC-type Riemann solver whereas the convective part is approximated with an upwind scheme. The result is a simple method which allows for a general equation of state. Numerical computations are performed for standard two-phase shock tube problems. A comparison is made with a non-splitting approach. The results are in good agreement with reference results and exact solutions.

  13. Optimal Control of Partially Miscible Two-Phase Flow with Applications to Subsurface CO2 Sequestration

    KAUST Repository

    Simon, Moritz


    Motivated by applications in subsurface CO2 sequestration, we investigate constrained optimal control problems with partially miscible two-phase flow in porous media. The objective is, e.g., to maximize the amount of trapped CO2 in an underground reservoir after a fixed period of CO2 injection, where the time-dependent injection rates in multiple wells are used as control parameters. We describe the governing two-phase two-component Darcy flow PDE system and formulate the optimal control problem. For the discretization we use a variant of the BOX method, a locally conservative control-volume FE method. The timestep-wise Lagrangian of the control problem is implemented as a functional in the PDE toolbox Sundance, which is part of the HPC software Trilinos. The resulting MPI parallelized Sundance state and adjoint solvers are linked to the interior point optimization package IPOPT. Finally, we present some numerical results in a heterogeneous model reservoir.

  14. Axi-symmetric simulation of a two phase vertical thermosyphon using Eulerian two-fluid methodology (United States)

    Kafeel, Khurram; Turan, Ali


    Numerical simulation of steady state operation of a vertical two phase closed thermosyphon is performed using the two-fluid methodology within Eulerian multiphase domain. A full scale axi-symmetric model is developed for computational fluid dynamics simulation of thermosyphon using ANSYS/FLUENT 13.0. The effects of evaporation, condensation and interfacial heat and mass transfer are taken into account within the whole domain. Cooling water jacket is also modelled along with the wall of thermosyphon to simulate the effect of conjugate heat transfer between the wall and fluid phase. The results obtained are presented and compared with available experimental investigations for a similar thermosyphon. It is established that two-fluid methodology can be used effectively for the purpose of simulation of two phase system like a typical thermosyphon.

  15. Performance of WPA Conductivity Sensor during Two-Phase Fluid Flow in Microgravity (United States)

    Carter, Layne; O'Connor, Edward W.; Snowdon, Doug


    The Conductivity Sensor designed for use in the Node 3 Water Processor Assembly (WPA) was based on the existing Space Shuttle application for the fuel cell water system. However, engineering analysis has determined that this sensor design is potentially sensitive to two-phase fluid flow (gadliquid) in microgravity. The source for this sensitivity is the fact that gas bubbles will become lodged between the sensor probe and the wall of the housing without the aid of buoyancy in l-g. Once gas becomes lodged in the housing, the measured conductivity will be offset based on the volume of occluded gas. A development conductivity sensor was flown on the NASA Microgravity Plan to measure the offset, which was determined to range between 0 and 50%. Based on these findings, a development program was initiated at the sensor s manufacturer to develop a sensor design fully compatible with two-phase fluid flow in microgravity.

  16. Some issues in the simulation of two-phase flows: The relative velocity

    Energy Technology Data Exchange (ETDEWEB)

    Gräbel, J.; Hensel, S.; Ueberholz, P.; Farber, P. [Niederrhein University of Applied Sciences, Institute for Modelling and High Performance Computing, Reinarzstraße 49, 47805 Krefeld (Germany); Zeidan, D. [School of Basic Sciences and Humanities, German Jordanian University, Amman (Jordan)


    In this paper we compare numerical approximations for solving the Riemann problem for a hyperbolic two-phase flow model in two-dimensional space. The model is based on mixture parameters of state where the relative velocity between the two-phase systems is taken into account. This relative velocity appears as a main discontinuous flow variable through the complete wave structure and cannot be recovered correctly by some numerical techniques when simulating the associated Riemann problem. Simulations are validated by comparing the results of the numerical calculation qualitatively with OpenFOAM software. Simulations also indicate that OpenFOAM is unable to resolve the relative velocity associated with the Riemann problem.

  17. Grid Generation Issues in the CFD Modelling of Two-Phase Flow in a Pipe

    Directory of Open Access Journals (Sweden)

    V. Hernandez-Perez


    Full Text Available The grid generation issues found in the 3D simulation of two-phase flow in a pipe using Computational Fluid Dynamics (CFD are discussed in this paper. Special attention is given to the effect of the element type and structure of the mesh. The simulations were carried out using the commercial software package STAR-CCM+, which is designed for numerical simulation of continuum mechanics problems. The model consisted of a cylindrical vertical pipe. Different mesh structures were employed in the computational domain. The condition of two-phase flow was simulated with the Volume of Fluid (VOF model, taking into consideration turbulence effects using the k-e model. The results showed that there is a strong dependency of the flow behaviour on the mesh employed. The best result was obtained with the grid known as butterfly grid, while the cylindrical mesh produced misleading results. The simulation was validated against experimental results.

  18. Two-phase Cryogenic Avalanche Detector with electroluminescence gap operated in argon doped with nitrogen (United States)

    Bondar, A.; Buzulutskov, A.; Dolgov, A.; Nosov, V.; Shekhtman, L.; Shemyakina, E.; Sokolov, A.


    A two-phase Cryogenic Avalanche Detector (CRAD) with electroluminescence (EL) gap, operated in argon doped with a minor (49±7 ppm) admixture of nitrogen, has been studied. The EL gap was optically read out using cryogenic PMTs located on the perimeter of the gap. We present the results of the measurements of the N2 content, detector sensitivity to X-ray-induced signals, EL gap yield and electron lifetime in the liquid. The detector sensitivity, at a drift field in liquid Ar of 0.6 kV/cm, was measured to be 9 and 16 photoelectrons recorded at the PMTs per keV of deposited energy at 23 and 88 keV respectively. Such two-phase detectors, with enhanced sensitivity to the S2 (ionization-induced) signal, are relevant in the field of argon detectors for dark matter search and low energy neutrino detection.

  19. A continuum theory for two-phase flows of particulate solids: application to Poiseuille flows (United States)

    Monsorno, Davide; Varsakelis, Christos; Papalexandris, Miltiadis V.


    In the first part of this talk, we present a novel two-phase continuum model for incompressible fluid-saturated granular flows. The model accounts for both compaction and shear-induced dilatancy and accommodates correlations for the granular rheology in a thermodynamically consistent way. In the second part of this talk, we exercise this two-phase model in the numerical simulation of a fully-developed Poiseuille flow of a dense suspension. The numerical predictions are shown to compare favorably against experimental measurements and confirm that the model can capture the important characteristics of the flow field, such as segregation and formation of plug zones. Finally, results from parametric studies with respect to the initial concentration, the magnitude of the external forcing and the width of the channel are presented and the role of these physical parameters is quantified. Financial Support has been provided by SEDITRANS, an Initial Training Network of the European Commission's 7th Framework Programme

  20. Feasibility analysis of two-phase MHD energy conversion for liquid metal cooled reactors

    Energy Technology Data Exchange (ETDEWEB)

    Wu Qiao [Department of Nuclear Engineering and Radiation Health Physics, Oregon State University, Corvallis, OR 97331 (United States)], E-mail:; Schubring, DuWayne L. [Department of Nuclear Engineering and Radiation Health Physics, Oregon State University, Corvallis, OR 97331 (United States); Sienicki, James J. [Reactor Engineering Division, Argonne National Laboratory, Argonne, IL 60439 (United States)


    A two-phase MHD energy conversion unit is proposed to a liquid metal cooled fast reactor. Using supercritical CO{sub 2} as the working fluid in the gas cycle without considering friction and heat losses, the optimized cycles efficiency is obtained, which is about 5% higher than that of the gas turbine Brayton cycle with the same regenerator/compressor configurations. Based on a simple MHD power analysis and the two-phase homogeneous flow model, the important system operational conditions were estimated. The results suggest that a liquid lead pump of at least 20% of the MHD power output is needed in order to convert the 400 MW reactor heat into electricity at the specified thermal efficiency, unless a mixture foam flow of void fraction greater than 80% is achievable at very high mixture velocity.

  1. Monte Carlo simulation of a two-phase flow in an unsaturated porous media

    Directory of Open Access Journals (Sweden)

    Xu Peng


    Full Text Available Relative permeability is a significant transport property which describes the simultaneous flow of immiscible fluids in porous media. A pore-scale physical model is developed for the two-phase immiscible flow in an unsaturated porous media according to the statistically fractal scaling laws of natural porous media, and a predictive calculation of two-phase relative permeability is presented by Monte Carlo simulation. The tortuosity is introduced to characterize the highly irregular and convoluted property of capillary pathways for fluid flow through a porous medium. The computed relative permeabilities are compared with empirical formulas and experimental measurements to validate the current model. The effect of fractal dimensions and saturation on the relative permeabilities is also discussed

  2. Interfacial structures of confined air-water two-phase bubbly flow

    Energy Technology Data Exchange (ETDEWEB)

    Kim, S.; Ishii, M.; Wu, Q.; McCreary, D.; Beus, S.G.


    The interfacial structure of the two-phase flows is of great importance in view of theoretical modeling and practical applications. In the present study, the focus is made on obtaining detailed local two-phase parameters in the air-water bubbly flow in a rectangular vertical duct using the double-sensor conductivity probe. The characteristic wall-peak is observed in the profiles of the interracial area concentration and the void fraction. The development of the interfacial area concentration along the axial direction of the flow is studied in view of the interfacial area transport and bubble interactions. The experimental data is compared with the drift flux model with C{sub 0} = 1.35.

  3. Geothermal Two-Phase Wellbore Flow: Pressure Drop Correlations and Flow Pattern Transitions

    Energy Technology Data Exchange (ETDEWEB)

    Ambastha, A.K.; Gudmundsson, J.S.


    In this paper we present some basic concepts of two-phase flow and review the Orkiszewski (1967) correlations which have been suggested by various investigators to perform well for geothermal wellbore flow situations. We also present a flow regime map based on the transition criteria used by Orkiszewski (1967) and show that most geothermal wells flow under slug flow regime. We have rearranged bubble- to slug-flow transition criterion used by Orkiszewski (1967) to show that the transition depends on the dimensionless pipe diameter number in addition to dimensionless liquid and gas velocity numbers. Our aim is also to identify what research may lead to improvements in two-phase pressure drop calculations for geothermal wellbore flow.

  4. Finite difference solution for a generalized Reynolds equation with homogeneous two-phase flow (United States)

    Braun, M. J.; Wheeler, R. L., III; Hendricks, R. C.; Mullen, R. L.

    An attempt is made to relate elements of two-phase flow and kinetic theory to the modified generalized Reynolds equation and to the energy equation, in order to arrive at a unified model simulating the pressure and flows in journal bearings, hydrostatic journal bearings, or squeeze film dampers when a two-phase situation occurs due to sudden fluid depressurization and heat generation. The numerical examples presented furnish a test of the algorithm for constant properties, and give insight into the effect of the shaft fluid heat transfer coefficient on the temperature profiles. The different level of pressures achievable for a given angular velocity depends on whether the bearing is thermal or nonisothermal; upwind differencing is noted to be essential for the derivation of a realistic profile.

  5. Studies on two-phase ionic liquid-aqueous flows in small channels of various sizes (United States)

    Tsaoulidis, Dimitrios; Chinaud, Maxime; Li, Qi; Angeli, Panagiota; University College London Team


    Two-phase flows in intensified small-scale systems find increasing applications in (bio)chemical analysis and synthesis, fuel cells, polymerisation, and separation processes (solvent extraction). Ionic liquids are emerging as a useful chemical in different areas of interest because of their unique properties such as negligible volatility and flammability, and good thermal and radiation stability. In this work, the hydrodynamic characteristics during plug flow have been investigated in detail. Experiments were carried out in Teflon channels of different sizes, i.e. 0.5, 1, and 2 mm internal diameter using two-phase systems relevant to spent nuclear fuel reprocessing, i.e. TBP/ionic liquid (30%, v/v)-nitric acid solutions. Important mixing characteristics and circulation patterns within the aqueous plugs have been studied by means of Particle Image Velocimetry (PIV). Finally, the mechanism of plug flow formation and the resulting plug size were investigated using Computational Fluid Dynamic (CFD).

  6. The removal of metallic single-walled carbon nanotubes using an aqueous two-phase system. (United States)

    Tang, Malcolm S Y; Whitcher, T J; Yeoh, K H; Chua, C L; Woon, K L; Show, P L; Lin, Y K; Ling, T C


    Here we report our findings on the removal of metallic single-walled carbon nanotubes using an aqueous two-phase system. The aqueous two-phase system contained as received carbon nanotubes, polyethylene glycol, dextran, N-methylpyrrolidone, cetyltrimethylammonium bromide, and water which phase separated into top and bottom phases. The top phase was dominated by polyethylene glycol whereas the bottom phase was dominated by dextran. The dextran-rich phase contained more semiconducting species while metallic species was more abundant in the polyethylene glycol rich-phase. It was found via Fourier-Transform Infrared Spectroscopy that cetyltrimethylammonium bromide only present in the dextran-rich phase. A selectivity mechanism is tentatively proposed and discussed.

  7. Lattice Boltzmann Method for Two-phase Flows on Unstructured Mesh (United States)

    Lee, Taehun; Baroudi, Lina; Wardle, Kent


    A lattice Boltzmann method with Galerkin finite element discretization (FE-LBM) is proposed to simulate incompressible two-phase flows on unstructured mesh. Two-distribution functions are used to recover the transport equations for the order parameter, pressure, and momentum. Consistent treatment of streaming and intermolecular forcing terms in FE-LBM enables us to use small equilibrium interface thickness compared with the existing two-phase LBMs and thus to achieve numerical stability at higher Reynolds number and large material property contrast. Several benchmark test cases with non-trivial wall boundaries will be presented, which include turbulent free surface flow inside a concentric rotating cylinder, drop impact on patterned surfaces, and bubbly flows. This work is partially supported by the DOE's NEUP.

  8. Construction of Representative Pore Morphologies in Disordered Nanoporous Two-Phase Materials

    Energy Technology Data Exchange (ETDEWEB)

    Toney, Michael F


    Materials with nanometer size heterogeneities are commonplace in the physical and biological sciences and often exhibit complex morphologies. Although this morphology has a dramatic effect on the materials' properties (e.g., transport and reaction processes), it is often difficult to accurately characterize. We describe a method, using a novel analysis of small angle x-ray scattering data, of generating representative three-dimensional morphologies of isotropic two-phase materials (one class of heterogeneous materials) where the morphology is disordered. This is applied to thin films containing nanometer sized pores with a range of porosities (4-44%). These representations provide a visualization of the pore morphology, give the pore size scale and extent of interconnection, and permit the determination of the transitions from closed pore to interconnected pores to bicontinuous morphology. This methodology will be valuable for characterizing two-phase systems, such as polymer blends, microemulsions, porous geological materials, bones, cements and ceramics.

  9. Adaptive moving grid methods for two-phase flow in porous media

    KAUST Repository

    Dong, Hao


    In this paper, we present an application of the moving mesh method for approximating numerical solutions of the two-phase flow model in porous media. The numerical schemes combine a mixed finite element method and a finite volume method, which can handle the nonlinearities of the governing equations in an efficient way. The adaptive moving grid method is then used to distribute more grid points near the sharp interfaces, which enables us to obtain accurate numerical solutions with fewer computational resources. The numerical experiments indicate that the proposed moving mesh strategy could be an effective way to approximate two-phase flows in porous media. © 2013 Elsevier B.V. All rights reserved.

  10. Analytical solution of gas bubble dynamics between two-phase flow (United States)

    Mohammadein, S. A.; Shalaby, G. A.; Abu-Bakr, A. F.; Abu-Nab, A. K.

    The growth of a gas bubble between two-phase flow represents the current physical problem. The mathematical model is performed by mass, momentum and diffusion equations. The Problem is solved analytically by using the modified Plesset and Zwick method. The growth process is affected by shear stress, coefficient of consistency, surface tension and void fraction in order to derive the growth of a gas bubble between two-phase in non-Newtonian fluids. The growth of a gas bubble in non-Newtonian fluids flow performs lower values than that in case of Newtonian one. The initial time of bubble growth for the different values of superheating and flow index n in the thermal stage is obtained. Moreover, the effect of critical bubble radius Rcr is studied on the growth process. The results satisfy the growth model in Newtonian fluids given by Foster and Zuber (1954) [34] and Scriven theory (Scriven, 1959) [35] for limited values of physical parameters.

  11. Use of SHPB tests for incorporating a compaction constitutive equation within a two-phase model (United States)

    Weckert, S. A.; Resnyansky, A. D.


    The well-known Split Hopkinson Pressure Bar (SHPB) set-up is used for analysis of compaction of calcite sand samples within a gauge instrumented confinement. A two-phase material model, used previously for simulation of sand behaviour under extreme shock loading, requires a constitutive equation for a parameter responsible for the compaction response within a non-equilibrium loading path tending to the solid Hugoniot. A mathematical formulation approximating the present experimental set-up is suggested and used for inverse adjustment of parameters in the constitutive equation. This equation determined from the SHPB tests and incorporated in the two-phase model is used for description of the behaviour of explosively driven sand with the help of the CTH shock physics code. Comparison with available independent experiments shows a good agreement.

  12. Two phase flow and heat transfer characteristics of a separate-type heat pipe (United States)

    Tang, Zhiwei; Liu, Aijie; Jiang, Zhangyan


    Two phase flow and heat transfer characteristics of a separate-type heat pipe have been studied experimentally and theoretically. The experimental apparatus have the same geometry for the evaporator and the condenser which consist of 5-tube-banks, with working temperature ranges of 80-125°C. The experimental working fluid is dual-distilled water with corrosion-resistant agents. Heat transfer coefficients for boiling and condensation along with heat flux and working temperature are measured at different filling ratio. According to the results of the experiments, the optimized filling ratio ranges from 16 to 36%. Fitted correlations of average heat transfer coefficients of the evaporator and Nusselt numbers of the condenser at the proposed filling ratio are obtained. Two phase flow characteristics of the evaporator and the condenser as well as their influence on heat transfer are described on the basis of simplified analysis. Reasons for the pulse-boiling process remain to be studied.

  13. Recovery of ascorbic oxidoreductase from crude extract with an aqueous two-phase system in a perforated rotating disc contactor

    Directory of Open Access Journals (Sweden)

    Ana Lúcia Figueiredo Porto


    Full Text Available A continuous perforated rotating disc contactor was used to extract the enzyme ascorbic oxidoreductase (E.C. from crude extract of Curcubita maxima with an aqueous two-phase system of poly (ethylene glycol and phosphate salts. The effect of dispersed phase velocity on either protein mass transfer coefficients or separation efficiency at 1, 2 and 3 mL/min was studied. An increase of the mass transfer coefficients was observed with the dispersed phase velocity, while the separation efficiency showed a small decrease with the increase of this parameter. The experimental results obtained during continuous extraction showed that the ascorbic oxidoreductase activity was partitioned preferentially into the salt-rich phase in all conditions studied. The best recovery of enzyme activity was 236%, with a purification factor of 34 in flow rates of 1 mL/min for dispersed phase.Uma coluna de discos perfurados rotativos foi utilizada na extração da enzima ascorbato oxidorredutase (E.C., obtida do extrato bruto de Curcubita maxima, através da utilização do sistema bifásico aquoso Polietilenoglicol-sais de fosfato. Os efeitos da velocidade da fase dispersa nos coeficientes de transferência de massa e na eficiência de separação para valores de 1, 2 e 3 mL/min foram estudados. Observou-se um aumento da transferência de massa com a velocidade da fase dispersa, enquanto que a eficiência de separação demonstrou uma ligeira redução com o aumento deste parâmetro. Os resultados experimentais obtidos durante a extração contínua demonstraram que a atividade da ascorbato oxidorredutase se concentrou preferencialmente na fase rica em sal para todas as condições estudadas. A maior recuperação da atividade enzimática foi de 236%, com um fator de purificação de 34 para o valor de 1 mL/min para a fase dispersa.

  14. Two-phase flow modelling of sediment suspension in the Ems/Dollard estuary (United States)

    Xu, Chunyang; Dong, Ping


    Understanding and quantifying mud suspension and sediment transport processes are of great importance for effective exploitation and sustainable management of estuarine environments. Event-based predictive models are widely used to identify the key interactions and mechanisms that govern the dynamics involved and to provide the essential parameterisation for assessing the long-term morphodynamic evolution of the estuaries. This study develops a one-dimensional-vertical (1DV) Reynolds averaged two-phase model for cohesive sediments resuspension driven by tidal flows. To capture the time-dependent flocculation process more accurately, a new drag force closure which relates empirically to settling velocity of mud flocs with suspended sediment concentration (SSC) is incorporated into the two-phase model. The model is then applied to simulate mud suspension in the Ems/Dollard estuary during two periods (June and August 1996) of tidal forcing. Numerical predictions of bed shear stresses and sediment concentrations at different elevations above the bed are compared with measured variations. The results confirm the importance of including flocculation effects in calculating the settling velocity of mud flocs and demonstrates the sensitivity of prediction with the settling velocity in terms of flocs concentration. Although the two-phase modelling approach can in principle better capture the essential interactions between fluid and sediment phases, its practical advantages over the simpler single phase approach cannot be confirmed for the data periods simulated, partly because the overall suspended sediment concentration measured is rather low and the interaction between the two phases is weak and also because the uncertainties in the relationship between the settling velocity and flocs concentration.

  15. Numerical modelling of the temperature distribution in a two-phase closed thermosyphon


    Fadhl, B; Wrobel, LC; Jouhara, H.


    Interest in the use of heat pipe technology for heat recovery and energy saving in a vast range of engineering applications has been on the rise in recent years. Heat pipes are playing a more important role in many industrial applications, particularly in improving the thermal performance of heat exchangers and increasing energy savings in applications with commercial use. In this paper, a comprehensive CFD modelling was built to simulate the details of the two-phase flow and heat transfer ph...

  16. Lattice Boltzmann Methods to Address Fundamental Boiling and Two-Phase Problems

    Energy Technology Data Exchange (ETDEWEB)

    Uddin, Rizwan


    This report presents the progress made during the fourth (no cost extension) year of this three-year grant aimed at the development of a consistent Lattice Boltzmann formulation for boiling and two-phase flows. During the first year, a consistent LBM formulation for the simulation of a two-phase water-steam system was developed. Results of initial model validation in a range of thermo-dynamic conditions typical for Boiling Water Reactors (BWRs) were shown. Progress was made on several fronts during the second year. Most important of these included the simulation of the coalescence of two bubbles including the surface tension effects. Work during the third year focused on the development of a new lattice Boltzmann model, called the artificial interface lattice Boltzmann model (AILB model) for the 3 simulation of two-phase dynamics. The model is based on the principle of free energy minimization and invokes the Gibbs-Duhem equation in the formulation of non-ideal forcing function. This was reported in detail in the last progress report. Part of the efforts during the last (no-cost extension) year were focused on developing a parallel capability for the 2D as well as for the 3D codes developed in this project. This will be reported in the final report. Here we report the work carried out on testing the AILB model for conditions including the thermal effects. A simplified thermal LB model, based on the thermal energy distribution approach, was developed. The simplifications are made after neglecting the viscous heat dissipation and the work done by pressure in the original thermal energy distribution model. Details of the model are presented here, followed by a discussion of the boundary conditions, and then results for some two-phase thermal problems.

  17. A Critical Assessment of Two-Phase Flow Distribution in Microchannel Heat Exchangers


    Panghat, Karthik; Mehendale, Sunil S


    Due to the many benefits offered by Microchannel Heat Exchangers (MCHX), such as compactness, high heat transfer coefficients, reduced refrigerant charge, and energy and material cost savings, microchannel condensers and evaporators continue to be increasingly applied and investigated in the HVAC&R fields. One of the practical challenges associated with MCHX is the uniform distribution of two-phase refrigerant in the headers and tubes of the heat exchanger. In MCHX, which typically have port ...

  18. Development of a mathematical model of two-phase polymer curing systems

    Directory of Open Access Journals (Sweden)

    V. I. Molchanov


    Full Text Available The formation a heterogeneous structure in two-phase elastomer composites was studied. Computer modeling of curing system in a set of five reaction–diffusion equations was carried out. In numerical experiments it is shown that density of the crosslinking of the entire system increases slower than the cure in the absence of curative’s diffusion, and the cure rate and the total degree of crosslinking of the composite as a whole is reduced.

  19. Hepatic hemangioma with atypical sonographic features : value of two-phase spiral CT

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Young Worl; Cho, June Sik; Lee, Young Hwan; Kang, Yong Soo; Kim, Hyoung Sub; Chung, Yon Su [Chungnam National Univ. College of Medicine, Taejon (Korea, Republic of)


    The purpose of this study was to evaluate enhancement patterns, as seen on two-phase spiral CT, of hepatic hemangiomas in which atypical features had been seen on sonography(US) Two-phase spiral CT scanning was performed in 18 patients in whom 24 atypical hemangiomas had been seen on US. Two-phase images were obtained at 25-45 seconds(arterial dominant phase) and 2-5 minutes(equilibrium phase) after the initiation of a bolus injection of contrast material(150ml, 5ml/sec). Enhancement patterns of hemangiomas during each phase were classified as homogeneous high, peripheral high, or low attenuation, and were retrospectively analyzed. In the arterial dominant phase of spiral CT, low attenuation was seen in nine hemangiomas (38%), globular or spotty peripheral high attenuation in 14(58%), and homogeneous high attenuation in one(4%). In the equilibrium phase, enhancement patterns were peripheral high attenuation(partial fill-in) in 18 lesions (75%), and homogeneous high attenuation(complete fill-in) in three (12.5%), In the other three(12.5%) enhancement showed no significant change;in one of these, density was slightly less than in the arterial phase, and two showed subtle peripheral high attenuation. Fourteen hemangiomas (58%) showed globular or spotty peripheral high attenuation in the arterial dominant phase and peripheral or homogeneous high attenuation with progressive centripetal enhancement in the equilibrium phase. Our results suggest that two-phase spiral CT during the arterial dominant and equilibrium phase is useful in differentiating hepatic hemangiomas with atypical features seen on US from malignant hepatic tumors.

  20. A study of relative permeability parameters on rock cores using a two-phase flow test


    Chung-Hui Chiao; Chi-Wen Yu; Shih-Chang Lei; Jyun-Yu Lin; Chia-Yu Lu


    To ensure sequestration safety, confirming the injectivity of the reservoir rock formation is of critical importance, requiring studies of the rock permeability to uncover the fluid migration scenarios within the porous reservoir rock. Two-phase (super-critical CO2-brine) flow behavior following the post CO2 injection is believed to be a dominating factor; its flooding behavior within the porous rock media needs to be further clarified prior to confirming the feasibility of domestic CO2 geo-s...

  1. One- and two-phase anaerobic digestion of ley crop silage with and without liquid recirculation

    Energy Technology Data Exchange (ETDEWEB)

    Nordberg, Aa.


    In this study the effects of liquid recirculation on hydrolysis and methanogenesis in one- and two-phase biogas processes were investigated in comparison with water-diluted processes. The operation of a water-diluted one-phase process resulted in process imbalances at a low loading rate. In a water-diluted two-phase process the fibre degrading capability was lost. The reason for the poor process performance was due to a deficiency in trace elements, since the supplementation of cobalt resulted in an increased conversion rate of acetate. The recirculation of process liquid resulted in an accumulation of different compounds which initially stabilized one-phase processes and stimulated the hydrolysis and the methane production in the liquefaction-acidogenesis stage of a two-phase process. However, upon continuous recirculation the concentration of free ammonia reached toxic levels, which resulted in a decrease in the methane yield both in the methanogenic reactor of the two-phase process and in the one-phase process. Due to the decreased methane production, acids started to accumulate which subsequently inhibited the hydrolysis in the one-phase process. The systematic variation in the processes were evaluated using principal component analysis and principal component regression. The interpretation of the dynamic behaviour of the processes was facilitated by the use of score plots and loading plots. The results indicate that ley crops do not meet the nutrient requirements of the bacteria in anaerobic digestion. Thus, the low content of trace elements and the high content of protein which subsequently will cause toxic levels of ammonia in digesting system with low water consumption, suggests co-digestion with supplementary feedstocks. 95 refs, 5 figs, 3 tabs

  2. Conceptual plan: Two-Phase Flow Laboratory Program for the Waste Isolation Pilot Plant

    Energy Technology Data Exchange (ETDEWEB)

    Howarth, S.M.


    The Salado Two-Phase Flow Laboratory Program was established to address concerns regarding two-phase flow properties and to provide WIPP-specific, geologically consistent experimental data to develop more appropriate correlations for Salado rock to replace those currently used in Performance Assessment models. Researchers in Sandia`s Fluid Flow and Transport Department originally identified and emphasized the need for laboratory measurements of Salado threshold pressure and relative permeability. The program expanded to include the measurement of capillary pressure, rock compressibility, porosity, and intrinsic permeability and the assessment of core damage. Sensitivity analyses identified the anhydrite interbed layers as the most likely path for the dissipation of waste-generated gas from waste-storage rooms because of their relatively high permeability. Due to this the program will initially focus on the anhydrite interbed material. The program may expand to include similar rock and flow measurements on other WIPP materials including impure halite, pure halite, and backfill and seal materials. This conceptual plan presents the scope, objectives, and historical documentation of the development of the Salado Two-Phase Flow Program through January 1993. Potential laboratory techniques for assessing core damage and measuring porosity, rock compressibility, capillary and threshold pressure, permeability as a function of stress, and relative permeability are discussed. Details of actual test designs, test procedures, and data analysis are not included in this report, but will be included in the Salado Two-Phase Flow Laboratory Program Test Plan pending the results of experimental and other scoping activities in FY93.

  3. A Two-Phase Safe Vehicle Routing and Scheduling Problem: Formulations and Solution Algorithms


    Omidvar, Aschkan; Ozguven, Eren Erman; Vanli, O. Arda; Tavakkoli-Moghaddam, R.


    We propose a two phase time dependent vehicle routing and scheduling optimization model that identifies the safest routes, as a substitute for the classical objectives given in the literature such as shortest distance or travel time, through (1) avoiding recurring congestions, and (2) selecting routes that have a lower probability of crash occurrences and non-recurring congestion caused by those crashes. In the first phase, we solve a mixed-integer programming model which takes the dynamic sp...

  4. Heat pipes et two-phase loops for spacecraft applications. ESA programmes

    Energy Technology Data Exchange (ETDEWEB)

    Supper, W. [European Space Agency / ESTEC. Thermal control and life support division (France)


    This document is a series of transparencies presenting the current and future applications of heat pipes in spacecraft and the activities in the field of capillary pumped two-phase loops: thermal tests, high-efficiency low pressure drop condensers, theoretical understanding of evaporator function, optimization of liquid and vapor flows, trade-off between low and high conductivity wicks, development of high capillary capacity wicks etc.. (J.S.)

  5. Electrostatic interactions and aqueous two-phase separation modes of aqueous mixed oppositely charged surfactants system. (United States)

    Hao, Li-Sheng; Gui, Yuan-Xiang; Chen, Yan-Mei; He, Shao-Qing; Nan, Yan-Qing; You, Yi-Lan


    Electrostatic interactions play an important role in setting the aqueous two-phase separation behaviors of mixtures of oppositely charged surfactants. The aqueous mixture of cetyltrimethylammonium bromide (CTAB) and sodium dodecylsulfonate (AS) is actually a five-component system, comprised of CTAB, AS, complex salt (cetyltrimethylammonium dodecylsulfonate, abbreviated as CTA(+)AS(-)), NaBr, and water. In the three-dimensional pyramid phase diagram, the aqueous two-phase region with excess AS or with excess CTAB extends successively from the region very near to the NaBr-H2O line through the CTAB-AS-H2O conventional mixing plane to the CTA(+)AS(-)-AS-H2O side plane or to the CTA(+)AS(-)-CTAB-H2O side plane, respectively. Large or small molar ratios between the counterions and their corresponding surfactant ions for oppositely charged surfactants located in the NaBr side or the CTA(+)AS(-) side of the pyramid imply strong or weak electrostatic screening. Electrostatic screening of counterions alters the electrostatic attractions between the oppositely charged head groups or the electrostatic repulsions between the like-charged head groups in excess, and the electrostatic free energy of aggregation thus affects the aqueous two-phase separation modes. Composition analysis, rheological property investigation, and TEM images suggest that there are two kinds of aqueous two-phase systems (ATPSs). On the basis of these experimental results and Kaler's cell model, two kinds of phase separation modes were proposed. Experimental results also indicate that all of the top phases are surfactant-rich, and all of the bottom phases are surfactant-poor; the density difference between the top phase and the bottom phase in one ATPS is very small; the interfacial tension (σ) of the ATPS is ultralow.

  6. Interfacial Tension Effect on Cell Partition in Aqueous Two-Phase Systems. (United States)

    Atefi, Ehsan; Joshi, Ramila; Mann, Jay Adin; Tavana, Hossein


    Aqueous two-phase systems (ATPS) provide a mild environment for the partition and separation of cells. We report a combined experimental and theoretical study on the effect of interfacial tension of polymeric ATPS on the partitioning of cells between two phases and their interface. Two-phase systems are generated using polyethylene glycol and dextran of specific properties as phase-forming polymers and culture media as the solvent component. Ultralow interfacial tensions of the solutions are precisely measured using an axisymmetric drop shape analysis method. Partition experiments show that two-phase systems with an interfacial tension of 30 μJ/m(2) result in distribution of majority of cells to the bottom dextran phase. An increase in the interfacial tension results in a distribution of cells toward the interface. An independent cancer cell spheroid formation assay confirms these observations: a drop of the dextran phase containing cancer cells is dispensed into the immersion polyethylene glycol phase to form a cell-containing drop. Only at very small interfacial tensions do cells remain within the drop to aggregate into a spheroid. We perform a thermodynamic modeling of cell partition to determine variations of free energy associated with displacement of cells in ATPS with respect to the ultralow interfacial tensions. This modeling corroborates with the experimental results and demonstrates that at the smallest interfacial tension of 30 μJ/m(2), the free energy is a minimum with cells in the bottom phase. Increasing the interfacial tension shifts the minimum energy and partition of cells toward the interfacial region of the two aqueous phases. Examining differences in the partition behavior and minimum free energy modeling of A431.H9 cancer cells and mouse embryonic stem cells shows that the surface properties of cells further modulate partition in ATPS. This combined approach provides a fundamental understanding of interfacial tension role on cell partition in

  7. A Variational Model for Two-Phase Immiscible Electroosmotic Flow at Solid Surfaces

    KAUST Repository

    Shao, Sihong


    We develop a continuum hydrodynamic model for two-phase immiscible flows that involve electroosmotic effect in an electrolyte and moving contact line at solid surfaces. The model is derived through a variational approach based on the Onsager principle of minimum energy dissipation. This approach was first presented in the derivation of a continuum hydrodynamic model for moving contact line in neutral two-phase immiscible flows (Qian, Wang, and Sheng, J. Fluid Mech. 564, 333-360 (2006)). Physically, the electroosmotic effect can be formulated by the Onsager principle as well in the linear response regime. Therefore, the same variational approach is applied here to the derivation of the continuum hydrodynamic model for charged two-phase immiscible flows where one fluid component is an electrolyte exhibiting electroosmotic effect on a charged surface. A phase field is employed to model the diffuse interface between two immiscible fluid components, one being the electrolyte and the other a nonconductive fluid, both allowed to slip at solid surfaces. Our model consists of the incompressible Navier-Stokes equation for momentum transport, the Nernst-Planck equation for ion transport, the Cahn-Hilliard phase-field equation for interface motion, and the Poisson equation for electric potential, along with all the necessary boundary conditions. In particular, all the dynamic boundary conditions at solid surfaces, including the generalized Navier boundary condition for slip, are derived together with the equations of motion in the bulk region. Numerical examples in two-dimensional space, which involve overlapped electric double layer fields, have been presented to demonstrate the validity and applicability of the model, and a few salient features of the two-phase immiscible electroosmotic flows at solid surface. The wall slip in the vicinity of moving contact line and the Smoluchowski slip in the electric double layer are both investigated. © 2012 Global-Science Press.

  8. Analysis of enhancement pattern of sellar and parasellar tumors using two-phase helical CT

    Energy Technology Data Exchange (ETDEWEB)

    Woo, Ji Young; Na, Dong Gyu; Roh, Hong Gee; Byun, Hong Sik; Ryoo, Jae Wook [Medical School of Sungkyunkwan Univ., Seoul (Korea, Republic of)


    To assess the enhancement patterns of sellar and parasellar tumors at two-phase helical CT. Thirty-two patients with pathologically proven sellar and parasellar tumors (meningioma (n=17), pituitary mocroadenoma (n=6), neurogenic tumor (n=5), cavernous angioma (n=1), chondrosarcoma (n=1), osteosarcoma (n=1), sphenoid carcinoma (n=1)) were included in this study. Two-phase helical CT was performed after the injection of 90 mL of contrast materials at a rate of 3 mL/sec. Transverse helical CT scans were obtained during the early and late phases, with scannin dealys of 30 and 120 seconds, respectively. Delayed coronal images were obtained after delayed axial images. Attenuation change and the enhancement patterns of the tumors were visually assessed; the former was also assessed quantitatively as the ratio of the CT number at late-phase axial and coronal scanning to that at early-phase scanning. Visual assessment of two-phase helical CT images revealed decreased attenuation in all 17 meningiomas, no change in all six pituitary macroadenomas and increased attenuation in 5 all five neurogenic tumors on late-phase axial scans as compared with early phase scans. Coronal images showed decreased attenuation in all 17 meningiomas, increased attenuation in all five neurogenic tumors and no change in four pituitary macroadenomas (66.7%). The ratio of CT numbers was significantly different between meningiomas, neurogenic tumors and pituitary macroadenomas (p< 0.05). According to their histopathology, sellar and parasellar tumors showed characteristic enhancement patterns at two-phase helical CT. An analysis of the observed enhancement patterns can be useful in the differential diagnosis of juxtasellar tumors.

  9. A Heat Transfer Investigation of Liquid and Two-Phase Methane (United States)

    VanNoord, Jonathan


    A heat transfer investigation was conducted for liquid and two-phase methane. The tests were conducted at the NASA Glenn Research Center Heated Tube Facility (HTF) using resistively heated tube sections to simulate conditions encountered in regeneratively cooled rocket engines. This testing is part of NASA s Propulsion and Cryogenics Advanced Development (PCAD) project. Nontoxic propellants, such as liquid oxygen/liquid methane (LO2/LCH4), offer potential benefits in both performance and safety over equivalently sized hypergolic propulsion systems in spacecraft applications. Regeneratively cooled thrust chambers are one solution for high performance, robust LO2/LCH4 engines, but cooling data on methane is limited. Several test runs were conducted using three different diameter Inconel 600 tubes, with nominal inner diameters of 0.0225-, 0.054-, and 0.075-in. The mass flow rate was varied from 0.005 to 0.07 lbm/sec. As the current focus of the PCAD project is on pressure fed engines for LO2/LCH4, the average test section outlet pressures were targeted to be 200 psia or 500 psia. The heat flux was incrementally increased for each test condition while the test section wall temperatures were monitored. A maximum average heat flux of 6.2 Btu/in.2 sec was achieved and, at times, the temperatures of the test sections reached in excess of 1800 R. The primary objective of the tests was to produce heat transfer correlations for methane in the liquid and two-phase regime. For two-phase flow testing, the critical heat flux values were determined where the fluid transitions from nucleate boiling to film boiling. A secondary goal of the testing was to measure system pressure drops in the two-phase regime.

  10. Modelling of two-phase flow based on separation of the flow according to velocity

    Energy Technology Data Exchange (ETDEWEB)

    Narumo, T. [VTT Energy, Espoo (Finland). Nuclear Energy


    The thesis concentrates on the development work of a physical one-dimensional two-fluid model that is based on Separation of the Flow According to Velocity (SFAV). The conventional way to model one-dimensional two-phase flow is to derive conservation equations for mass, momentum and energy over the regions occupied by the phases. In the SFAV approach, the two-phase mixture is divided into two subflows, with as distinct average velocities as possible, and momentum conservation equations are derived over their domains. Mass and energy conservation are treated equally with the conventional model because they are distributed very accurately according to the phases, but momentum fluctuations follow better the flow velocity. Submodels for non-uniform transverse profile of velocity and density, slip between the phases within each subflow and turbulence between the subflows have been derived. The model system is hyperbolic in any sensible flow conditions over the whole range of void fraction. Thus, it can be solved with accurate numerical methods utilizing the characteristics. The characteristics agree well with the used experimental data on two-phase flow wave phenomena Furthermore, the characteristics of the SFAV model are as well in accordance with their physical counterparts as of the best virtual-mass models that are typically optimized for special flow regimes like bubbly flow. The SFAV model has proved to be applicable in describing two-phase flow physically correctly because both the dynamics and steady-state behaviour of the model has been considered and found to agree well with experimental data This makes the SFAV model especially suitable for the calculation of fast transients, taking place in versatile form e.g. in nuclear reactors. 45 refs. The thesis includes also five previous publications by author.

  11. Flow Pattern Identification of Horizontal Two-Phase Refrigerant Flow Using Neural Networks (United States)


    making classification difficult. Consequently, Table 5 shows neural net - work classification results for nine flow patterns. The number of runs...AFRL-RQ-WP-TP-2016-0079 FLOW PATTERN IDENTIFICATION OF HORIZONTAL TWO-PHASE REFRIGERANT FLOW USING NEURAL NETWORKS (POSTPRINT) Abdeel J... NEURAL NETWORKS (POSTPRINT) 5a. CONTRACT NUMBER In-house 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 62203F 6. AUTHOR(S) Abdeel J. Roman and

  12. Development of a two-phase SPH model for sediment laden flows (United States)

    Shi, Huabin; Yu, Xiping; Dalrymple, Robert A.


    A SPH model based on a general formulation for solid-fluid two-phase flows is proposed for suspended sediment motion in free surface flows. The water and the sediment are treated as two miscible fluids, and the multi-fluid system is discretized by a single set of SPH particles, which move with the water velocity and carry properties of the two phases. Large eddy simulation (LES) is introduced to deal with the turbulence effect, and the widely used Smagorinsky model is modified to take into account the influence of sediment particles on the turbulence. The drag force is accurately formulated by including the hindered settling effect. In the model, the water is assumed to be weakly compressible while the sediment is incompressible, and a new equation of state is proposed for the pressure in the sediment-water mixture. Dynamic boundary condition is employed to treat wall boundaries, and a new strategy of Shepard filtering is adopted to damp the pressure oscillation. The developed two-phase SPH model is validated by comparing the numerical results with analytical solutions for idealized cases of still water containing both neutrally buoyant and naturally settling sand and for plane Poiseuille flows carrying neutrally buoyant particles, and is then applied to sand dumping from a line source into a water tank, where the sand cloud settles with a response of the free water surface. It is shown that the numerical results are in good agreement with the experimental data as well as the empirical formulas. The characteristics of the settling sand cloud, the pressure field, and the flow vortices are studied. The motion of the free water surface is also discussed. The proposed two-phase SPH model is proven to be effective for numerical simulation of sand dumping into waters.

  13. Modeling and simulation of nanoparticles transport in a two-phase flow in porous media

    KAUST Repository

    El-Amin, Mohamed


    In the current paper, a mathematical model to describe the nanoparticles transport carried by a two-phase flow in a porous medium is presented. Both capillary forces as well as Brownian diffusion are considered in the model. A numerical example of countercurrent water-oil imbibition is considered. We monitor the changing of the fluid and solid properties due to the addition of the nanoparticles using numerical experiments. Variation of water saturation, nanoparticles concentration and porosity ratio are investigated.

  14. Using a Fast X-Ray Microtomography Study to Better Inform Two-Phase Flow Theories (United States)

    Meisenheimer, D.; Wildenschild, D.


    Understanding multiphase flow in porous media is important to many fields including groundwater management and remediation, soil and agricultural practices, petroleum engineering, and geologic sequestration of CO2. Scientists and engineers in these fields require experimental data acquired under field conditions to accurately create models of the dynamic multiphase flow processes being studied. The recent introduction of fast x-ray microtomography (fast-µCT) allows multiphase flow experiments to be performed in 3-dimensions under field-consistent pressure conditions removing the decision to either sacrifice the 3rd dimension with 2D micromodels or impose a pseudo-equilibrium pressure condition using standard-µCT methods. This new experimental method allows for the acquisition of data under more relevant conditions to validate multiphase theories with greater confidence and inform more accurate models. One such multiphase flow theory introduces interfacial area as a state variable that can be used to better describe the characteristics of two-phase flow by reducing or eliminating the hysteric effect that is prevalent in many two-phase models. Using fast-µCT, interfacial area production and evolution can unprecedentedly be tracked in 3D under valid flow conditions. Previously, we presented a preliminary analysis that suggested that the capillary pressure-saturation-interfacial area (Pc-Sw-Awn) surface established under flow conditions does not coincide with the surface obtained under pseudo-equilibrium conditions, which is complementary to work done in 2D micromodel studies. Here we present a more in-depth analysis on the relationship between Pc-Sw-Anw surfaces obtained under flow or pseudo-equilibrium conditions. In addition, we present an analysis of the measured interfacial area production rate term (Ewn) in relation to the rate of change of saturation (dS/dt) during the two-phase flow experiments which is an important relationship in two-phase theories.

  15. Chemical dispersants

    NARCIS (Netherlands)

    Rahsepar, Shokouhalsadat; Smit, Martijn P.J.; Murk, Albertinka J.; Rijnaarts, Huub H.M.; Langenhoff, Alette A.M.


    Chemical dispersants were used in response to the Deepwater Horizon oil spill in the Gulf of Mexico, both at the sea surface and the wellhead. Their effect on oil biodegradation is unclear, as studies showed both inhibition and enhancement. This study addresses the effect of Corexit on oil

  16. Preparative crystallization of a single chain antibody using an aqueous two-phase system. (United States)

    Huettmann, Hauke; Berkemeyer, Matthias; Buchinger, Wolfgang; Jungbauer, Alois


    A simultaneous crystallization and aqueous two-phase extraction of a single chain antibody was developed, demonstrating process integration. The process conditions were designed to form an aqueous two-phase system, and to favor crystallization, using sodium sulfate and PEG-2000. At sufficiently high concentrations of PEG, a second phase was generated in which the protein crystallization occurred simultaneously. The single chain antibody crystals were partitioned to the top, polyethylene glycol-rich phase. The crystal nucleation took place in the sodium sulfate-rich phase and at the phase boundary, whereas crystal growth was progressing mainly in the polyethylene glycol-rich phase. The crystals in the polyethylene glycol-rich phase grew to a size of >50 µm. Additionally, polyethylene glycol acted as an anti-solvent, thus, it influenced the crystallization yield. A phase diagram with an undersaturation zone, crystallization area, and amorphous precipitation zone was established. Only small differences in polyethylene glycol concentration caused significant shifts of the crystallization yield. An increase of the polyethylene glycol content from 2% (w/v) to 4% (w/v) increased the yield from approximately 63-87%, respectively. Our results show that crystallization in aqueous two-phase systems is an opportunity to foster process integration. © 2014 Wiley Periodicals, Inc.

  17. Simulation of two-phase flow in horizontal fracture networks with numerical manifold method (United States)

    Ma, G. W.; Wang, H. D.; Fan, L. F.; Wang, B.


    The paper presents simulation of two-phase flow in discrete fracture networks with numerical manifold method (NMM). Each phase of fluids is considered to be confined within the assumed discrete interfaces in the present method. The homogeneous model is modified to approach the mixed fluids. A new mathematical cover formation for fracture intersection is proposed to satisfy the mass conservation. NMM simulations of two-phase flow in a single fracture, intersection, and fracture network are illustrated graphically and validated by the analytical method or the finite element method. Results show that the motion status of discrete interface significantly depends on the ratio of mobility of two fluids rather than the value of the mobility. The variation of fluid velocity in each fracture segment and the driven fluid content are also influenced by the ratio of mobility. The advantages of NMM in the simulation of two-phase flow in a fracture network are demonstrated in the present study, which can be further developed for practical engineering applications.

  18. A Novel Hyperbolization Procedure for The Two-Phase Six-Equation Flow Model

    Energy Technology Data Exchange (ETDEWEB)

    Samet Y. Kadioglu; Robert Nourgaliev; Nam Dinh


    We introduce a novel approach for the hyperbolization of the well-known two-phase six equation flow model. The six-equation model has been frequently used in many two-phase flow applications such as bubbly fluid flows in nuclear reactors. One major drawback of this model is that it can be arbitrarily non-hyperbolic resulting in difficulties such as numerical instability issues. Non-hyperbolic behavior can be associated with complex eigenvalues that correspond to characteristic matrix of the system. Complex eigenvalues are often due to certain flow parameter choices such as the definition of inter-facial pressure terms. In our method, we prevent the characteristic matrix receiving complex eigenvalues by fine tuning the inter-facial pressure terms with an iterative procedure. In this way, the characteristic matrix possesses all real eigenvalues meaning that the characteristic wave speeds are all real therefore the overall two-phase flowmodel becomes hyperbolic. The main advantage of this is that one can apply less diffusive highly accurate high resolution numerical schemes that often rely on explicit calculations of real eigenvalues. We note that existing non-hyperbolic models are discretized mainly based on low order highly dissipative numerical techniques in order to avoid stability issues.

  19. Two-phase Flow Ejector as Water Refrigerant by Using Waste Heat (United States)

    Yamanaka, H.; Nakagawa, M.


    Energy saving and the use of clean energy sources have recently become significant issues. It is expected that clean energy sources such as solar panels and fuel cells will be installed in many private dwellings. However, when electrical power is generated, exhaust heat is simultaneously produced. Especially for the summer season, the development of refrigeration systems that can use this waste heat is highly desirable. One approach is an ejector that can reduce the mechanical compression work required in a normal refrigeration cycle. We focus on the use of water as a refrigerant, since this can be safely implemented in private dwellings. Although the energy conversion efficiency is low, it is promising because it can use heat that would otherwise be discarded. However, a steam ejector refrigeration cycle requires a large amount of energy to change saturated water into vapour. Thus, we propose a more efficient two-phase flow ejector cycle. Experiments were carried out in which the quality of the two-phase flow from a tank was varied, and the efficiency of the ejector and nozzle was determined. The results show that a vacuum state can be achieved and suction exerted with a two-phase flow state at the ejector nozzle inlet.

  20. Study of nitrogen two-phase flow pressure drop in horizontal and vertical orientation (United States)

    Koettig, T.; Kirsch, H.; Santandrea, D.; Bremer, J.


    The large-scale liquid argon Short Baseline Neutrino Far-detector located at Fermilab is designed to detect neutrinos allowing research in the field of neutrino oscillations. It will be filled with liquid argon and operate at almost ambient pressure. Consequently, its operation temperature is determined at about 87 K. The detector will be surrounded by a thermal shield, which is actively cooled with boiling nitrogen at a pressure of about 2.8 bar absolute, the respective saturation pressure of nitrogen. Due to strict temperature gradient constraints, it is important to study the two-phase flow pressure drop of nitrogen along the cooling circuit of the thermal shield in different orientations of the flow with respect to gravity. An experimental setup has been built in order to determine the two-phase flow pressure drop in nitrogen in horizontal, vertical upward and vertical downward direction. The measurements have been conducted under quasi-adiabatic conditions and at a saturation pressure of 2.8 bar absolute. The mass velocity has been varied in the range of 20 kg·m‑2·s‑1 to 70 kg·m‑2·s‑1 and the pressure drop data has been recorded scanning the two-phase region from vapor qualities close to zero up to 0.7. The experimental data will be compared with several established predictions of pressure drop e.g. Mueller-Steinhagen and Heck by using the void fraction correlation of Rouhani.

  1. Nonlinear analysis of gas-water/oil-water two-phase flow in complex networks

    CERN Document Server

    Gao, Zhong-Ke; Wang, Wen-Xu


    Understanding the dynamics of multi-phase flows has been a challenge in the fields of nonlinear dynamics and fluid mechanics. This chapter reviews our work on two-phase flow dynamics in combination with complex network theory. We systematically carried out gas-water/oil-water two-phase flow experiments for measuring the time series of flow signals which is studied in terms of the mapping from time series to complex networks. Three network mapping methods were proposed for the analysis and identification of flow patterns, i.e. Flow Pattern Complex Network (FPCN), Fluid Dynamic Complex Network (FDCN) and Fluid Structure Complex Network (FSCN). Through detecting the community structure of FPCN based on K-means clustering, distinct flow patterns can be successfully distinguished and identified. A number of FDCN’s under different flow conditions were constructed in order to reveal the dynamical characteristics of two-phase flows. The FDCNs exhibit universal power-law degree distributions. The power-law exponent ...

  2. A Simple and Efficient Diffuse Interface Method for Compressible Two-Phase Flows

    Energy Technology Data Exchange (ETDEWEB)

    Ray A. Berry; Richard Saurel; Fabien Petitpas


    In nuclear reactor safety and optimization there are key issues that rely on in-depth understanding of basic two-phase flow phenomena with heat and mass transfer. For many reasons, to be discussed, there is growing interest in the application of two-phase flow models to provide diffuse, but nevertheless resolved, simulation of interfaces between two immiscible compressible fluids – diffuse interface method (DIM). Because of its ability to dynamically create interfaces and to solve interfaces separating pure media and mixtures for DNS-like (Direct Numerical Simulation) simulations of interfacial flows, we examine the construction of a simple, robust, fast, and accurate numerical formulation for the 5-equation Kapila et al. [1] reduced two-phase model. Though apparently simple, the Kapila et al. model contains a volume fraction differential transport equation containing a nonlinear, non-conservative term which poses serious computational challenges. To circumvent the difficulties encountered with the single velocity and single pressure Kapila et al. [1] multiphase flow model, a 6-equation relaxation hyperbolic model is built to solve interface problems with compressible fluids. In this approach, pressure non-equilibrium is first restored, followed by a relaxation to an asymptotic solution which is convergent to the solutions of the Kapila et al. reduced model. The apparent complexity introduced with this extended hyperbolic model actually leads to considerable simplifications regarding numerical resolution, and the various ingredients used by this method are general enough to consider future extensions to problems involving complex physics.


    Directory of Open Access Journals (Sweden)

    V. V. Sorokin


    Full Text Available Sufficient atomic power generation safety increase may be done with microfuel adapting to reactor plants with water coolant. Microfuel particle is a millimeter size grain containing fission material core in a protecting coverage. The coverage protects fuel contact with coolant and provides isolation of fission products inside. Well thermophysical properties of microfuel bed in a direct contact with water coolant excludes fuel overheating when accidents. Microfuel use was suggested for a VVER, а direct flow reactor for superheat steam generation, a reactor with neutron spectra adjustment by the steam partial content varying in the coolant.Nonuniformities of two-phase coolant distribution in a heat generating particles bed are predicted by calculations in this text. The one is due to multiple-valuedness of pressure drop across the bed on the steam quality dependency. The nonuniformity decreases with flow rate and particle size growths absolute pressure diminishing while porosity effect is weak. The worse case is for pressure quality of order of one. Some pure steam filled pores appears parallel to steam water mixture filled pores, latter steam quality is less than the mean of the bed. Considering this regime for the direct flow reactor for superheat steam generation we predict some water drops at the exit flow. The two-phase coolant filtration with subcooled water feed is unstable to strong disturbance effects are found. Uniformity of two-phase coolant distribution is worse than for one-phase in the same radial type reactor.

  4. Two-phase flow properties of a horizontal fracture: The effect of aperture distribution (United States)

    Ye, Zuyang; Liu, Hui-Hai; Jiang, Qinghui; Zhou, Chuangbing


    A systematic numerical method has been presented to investigate the constitutive relationships between two-phase flow properties of horizontal fractures and aperture distributions. Based on fractal geometry, single rough-walled fractures are generated numerically by modified successive random addition (SRA) method and then aperture distributions with truncated Gaussian distribution are formed by shear displacement between lower and upper surfaces. (The truncated Gaussian distribution is used to describe aperture evolution under different normal stresses.) According to the assumption of two-dimensional porous media and local parallel plate model, invasion percolation approach is employed to model the two-phase flow displacement (imbibition) in generated horizontal fractures, in which capillary forces are dominant over viscous and gravity forces. For truncated Gaussian distributions, constitutive relationships from numerical simulation are compared to closed-form relationships and a good agreement is obtained. The simulation results indicate strong phase interference with the sum of two phase relative permeability values being less than one in the intermediate saturations. It is found that fracture properties related to residual saturations depend on spatial correlation of aperture distributions. Based on the simulation results, we proposed an empirical relationship between the fracture residual-saturation-rated parameters and the corresponding aperture distributions.

  5. Two-phase flow in geothermal energy sources. Final technical report

    Energy Technology Data Exchange (ETDEWEB)


    A geothermal well consisting of single and two-phase flow sections was modeled in order to explore the variables important to the process. For this purpose a computer program was developed in a versatile form in order to be able to incorporate a variety of two phase flow void fraction and friction correlations. A parametric study indicated that the most significant variables controlling the production rate are: hydrostatic pressure drop or void fraction in the two-phase mixture; and, heat transfer from the wellbore to the surrounding earth. Downhole instrumentation was developed and applied in two flowing wells to provide experimental data for the computer program. The wells (East Mesa 8-1, and a private well) behaved differently. Well 8-1 did not flash and numerous shakedown problems in the probe were encountered. The private well did flash and the instrumentation detected the onset of flashing. A Users Manual was developed and presented in a workshop held in conjunction with the Geothermal Resources Council.

  6. Aqueous Two-Phase Systems formed by Biocompatible and Biodegradable Polysaccharides and Acetonitrile (United States)

    de Brito Cardoso, Gustavo; Souza, Isabela Nascimento; Pereira, Matheus M.; Freire, Mara G.; Soares, Cleide Mara Faria; Lima, Álvaro Silva


    In this work, it is shown that novel aqueous two-phase systems can be formed by the combination of acetonitrile and polysaccharides, namely dextran. Several ternary phase diagrams were determined at 25 °C for the systems composed of water + acetonitrile + dextran. The effect of the dextran molecular weight (6,000, 40,000 and 100,000 g.mol−1) was ascertained toward their ability to undergo liquid-liquid demixing. An increase in the dextran molecular weight favors the phase separation. Furthermore, the effect of temperature (25, 35 and 45 °C) was evaluated for the system constituted by the dextran of higher molecular weight. Lower temperatures are favorable for phase separation since lower amounts of dextran and acetonitrile are required for the creation of aqueous two-phase systems. In general, acetonitrile is enriched in the top phase while dextran is majorly concentrated in the bottom phase. The applicability of this new type of two-phase systems as liquid-liquid extraction approaches was also evaluated by the study of the partition behavior of a well-known antioxidant – vanillin - and used here as a model biomolecule. The optimized conditions led to an extraction efficiency of vanillin of 95% at the acetonitrile-rich phase. PMID:25729320

  7. Electrical Capacitance Probe Characterization in Vertical Annular Two-Phase Flow

    Directory of Open Access Journals (Sweden)

    Grazia Monni


    Full Text Available The paper presents the experimental analysis and the characterization of an electrical capacitance probe (ECP that has been developed at the SIET Italian Company, for the measurement of two-phase flow parameters during the experimental simulation of nuclear accidents, as LOCA. The ECP is used to investigate a vertical air/water flow, characterized by void fraction higher than 95%, with mass flow rates ranging from 0.094 to 0.15 kg/s for air and from 0.002 to 0.021 kg/s for water, corresponding to an annular flow pattern. From the ECP signals, the electrode shape functions (i.e., the signals as a function of electrode distances in single- and two-phase flows are obtained. The dependence of the signal on the void fraction is derived and the liquid film thickness and the phase’s velocity are evaluated by means of rather simple models. The experimental analysis allows one to characterize the ECP, showing the advantages and the drawbacks of this technique for the two-phase flow characterization at high void fraction.

  8. Central upwind scheme for a compressible two-phase flow model.

    Directory of Open Access Journals (Sweden)

    Munshoor Ahmed

    Full Text Available In this article, a compressible two-phase reduced five-equation flow model is numerically investigated. The model is non-conservative and the governing equations consist of two equations describing the conservation of mass, one for overall momentum and one for total energy. The fifth equation is the energy equation for one of the two phases and it includes source term on the right-hand side which represents the energy exchange between two fluids in the form of mechanical and thermodynamical work. For the numerical approximation of the model a high resolution central upwind scheme is implemented. This is a non-oscillatory upwind biased finite volume scheme which does not require a Riemann solver at each time step. Few numerical case studies of two-phase flows are presented. For validation and comparison, the same model is also solved by using kinetic flux-vector splitting (KFVS and staggered central schemes. It was found that central upwind scheme produces comparable results to the KFVS scheme.

  9. Simulation experiments for hot-leg U-bend two-phase flow phenomena

    Energy Technology Data Exchange (ETDEWEB)

    Ishii, M.; Hsu, J.T.; Tucholke, D.; Lambert, G.; Kataoka, I.


    In order to study the two-phase natural circulation and flow termination during a small break loss of coolant accident in LWR, simulation experiments have been performed. Based on the two-phase flow scaling criteria developed under this program, an adiabatic hot leg U-bend simulation loop using nitrogen gas and water and a Freon 113 boiling and condensation loop were built. The nitrogen-water system has been used to isolate key hydrodynamic phenomena from heat transfer problems, whereas the Freon loop has been used to study the effect of phase changes and fluid properties. Various tests were carried out to establish the basic mechanism of the flow termination and reestablishment as well as to obtain essential information on scale effects of parameters such as the loop frictional resistance, thermal center, U-bend curvature and inlet geometry. In addition to the above experimental study, a preliminary modeling study has been carried out for two-phase flow in a large vertical pipe at relatively low gas fluxes typical of natural circulation conditions.

  10. Two-phase cooling system with a jet pump for spacecraft (United States)

    Fairuzov, Yuri V.; Bredikhin, Victor V.


    A two-phase cooling system with a jet pump is proposed for the thermal control of spacecraft. The system does not require an external source of energy, the pumping of the working fluid is performed by the work that is produced in a thermodynamic cycle being carried out in the heat transport loop. The cooling system has no moving parts or control devices, with the exception of a mechanical pump and an actuated valve, that are used only for the startup sequence. This article reports on the results of the theoretical and experimental studies of the two-phase thermal control system with a jet pump for spacecraft application. A mathematical model for the steady-state analysis of the proposed system was developed. The model was applied to predict overall performance characteristics and operating range for a specific spacecraft two-phase cooling system. The possible reasons for the fluid loop operation failures were identified. The influence of the accumulator volume on the system characteristics was also investigated. Three jet pumps of various configurations were tested and stable operational regimes of the cooling system were obtained under different heat-load and heat-rejection conditions on a ground experimental facility.

  11. Aqueous Two-Phase Systems formed by Biocompatible and Biodegradable Polysaccharides and Acetonitrile. (United States)

    de Brito Cardoso, Gustavo; Souza, Isabela Nascimento; Pereira, Matheus M; Freire, Mara G; Soares, Cleide Mara Faria; Lima, Álvaro Silva


    In this work, it is shown that novel aqueous two-phase systems can be formed by the combination of acetonitrile and polysaccharides, namely dextran. Several ternary phase diagrams were determined at 25 °C for the systems composed of water + acetonitrile + dextran. The effect of the dextran molecular weight (6,000, 40,000 and 100,000 g.mol(-1)) was ascertained toward their ability to undergo liquid-liquid demixing. An increase in the dextran molecular weight favors the phase separation. Furthermore, the effect of temperature (25, 35 and 45 °C) was evaluated for the system constituted by the dextran of higher molecular weight. Lower temperatures are favorable for phase separation since lower amounts of dextran and acetonitrile are required for the creation of aqueous two-phase systems. In general, acetonitrile is enriched in the top phase while dextran is majorly concentrated in the bottom phase. The applicability of this new type of two-phase systems as liquid-liquid extraction approaches was also evaluated by the study of the partition behavior of a well-known antioxidant - vanillin - and used here as a model biomolecule. The optimized conditions led to an extraction efficiency of vanillin of 95% at the acetonitrile-rich phase.

  12. Two-phase distribution in the vertical flow line of a domestic wet central heating system

    Directory of Open Access Journals (Sweden)

    Ge Y.T.


    Full Text Available The theoretical and experimental aspects of bubble distribution in bubbly two-phase flow are reviewed in the context of the micro bubbles present in a domestic gas fired wet central heating system. The latter systems are mostly operated through the circulation of heated standard tap water through a closed loop circuit which often results in water supersaturated with dissolved air. This leads to micro bubble nucleation at the primary heat exchanger wall, followed by detachment along the flow. Consequently, a bubbly two-phase flow characterises the flow line of such systems. The two-phase distribution across the vertical and horizontal pipes was measured through a consideration of the volumetric void fraction, quantified through photographic techniques. The bubble distribution in the vertical pipe in down flow conditions was measured to be quasi homogenous across the pipe section with a negligible reduction in the void fraction at close proximity to the pipe wall. Such a reduction was more evident at lower bulk fluid velocities.

  13. Taylor dispersion in peristaltic pumping (United States)

    Saintillan, David; Chakrabarti, Brato


    The diffusivity of a Brownian tracer in unidirectional flow is generally enhanced due to shear by the classic phenomenon of Taylor dispersion. At long times, the average concentration of the tracer follows a simplified advection-diffusion equation with an effective shear-dependent dispersivity. In this work, we make use of Brenner's generalized Taylor theory for periodic domains to study dispersion in peristaltic pumping. In channels with small aspect ratios, asymptotic expansions are employed to obtain analytical expressions for the dispersivity at both small and high Peclet numbers. Channels of arbitrary aspect ratios are also considered using a boundary integral formulation for the flow coupled to a hyperbolic conservation equation for the effective dispersivity, which is solved by the finite-volume method. Our numerical results show good agreement with theoretical predictions and provide a basis for understanding passive scalar transport in peristaltic flow, for instance in the ureter or in microfluidic peristaltic pumps.

  14. Generalization of two-phase model with topology microstructure of mixture to Lagrange-Euler methodology

    Energy Technology Data Exchange (ETDEWEB)

    Vladimir V Chudanov; Alexei A Leonov [Nuclear Safety Institute, Russian Academy of Sciences 52, Bolshaya Tulskaya, Moscow 113191 (Russian Federation)


    Full text of publication follows: One of the mathematical models (hyperbolic type) for describing evolution of compressible two-phase mixtures was offered in [1] to deal with the following applications: interfaces between compressible materials; shock waves in multiphase mixtures; evolution of homogeneous two-phase flows; cavitation in liquids. The basic difficulties of this model was connected to discretization of the non-conservative equation terms. As result, the class of problems concerned with passage of shock waves through fields with a discontinuing profile of a volume fraction was not described by means of this model. A class of schemes that are able to converge to the correct solution of such problems was received in [2] due to a deeper analysis of two-phase model. The technique offered in [2] was implemented on a Eulerian grid via the Godunov scheme. In present paper the additional analysis of two-phase model in view of microstructure of an mixture topology is carried out in Lagrange mass coordinates. As result, the equations averaged over the set of all possible realizations for two-phase mixture are received. The numerical solution is carried out with use of PPM method [3] in two steps: at first - the equations averaged over mass variable are solved; on the second - the solution, found on the previous step, is re-mapped to a fixed Eulerian grid. Such approach allows to expand the proposed technique on two-dimensional (three-dimensional) case, as in the Lagrange variables the Euler equations system is split on two (three) identical subsystems, each of which describes evolution of considered medium in the given direction. The accuracy and robustness of the described procedure are demonstrated on a sequence of the numerical problems. References: (1). R. Saurel, R. Abgrall, A multiphase Godunov method for compressible multi-fluid and multiphase flows, J. Comput. Phys. 150 (1999) 425-467; (2). R. Saurel, R. Abgrall, Discrete equations for physical and

  15. Gas-liquid two-phase flows in rectangular polymer micro-channels (United States)

    Kim, Namwon; Evans, Estelle T.; Park, Daniel S.; Soper, Steven A.; Murphy, Michael C.; Nikitopoulos, Dimitris E.


    This study addresses gas-liquid two-phase flows in polymer (PMMA) micro-channels with non-molecularly smooth and poorly wetting walls (typical contact angle of 65°) unlike previous studies conducted on highly wetting molecularly smooth materials (e.g., glass/silicon). Four fundamentally different topological flow regimes (Capillary Bubbly, Segmented, Annular, Dry) were identified along with two transitory ones (Segmented/Annular, Annular/Dry) and regime boundaries were identified from the two different test chips. The regime transition boundaries were influenced by the geometry of the two-phase injection, the aspect ratio of the test micro-channels, and potentially the chip material as evidenced from comparisons with the results of previous studies. Three principal Segmented flow sub-regimes (1, 2, and 3) were identified on the basis of quantified topological characteristics, each closely correlated with two-phase flow pressure drop trends. Irregularity of the Segmented regimes and related influencing factors were addressed and discussed. The average bubble length associated with the Segmented flows scaled approximately with a power law of the liquid volumetric flow ratio, which depends on aspect ratio, liquid superficial velocity, and the injection system. A simplified semi-empirical geometric model of gas bubble and liquid plug volumes provided good estimates of liquid plug length for most of the segmented regime cases and for all test-channel aspect ratios. The two-phase flow pressure drop was measured for the square test channels. Each Segmented flow sub-regime was associated with different trends in the pressure drop scaled by the viscous scale. These trends were explained in terms of the quantified flow topology (measured gas bubble and liquid plug lengths) and the number of bubble/plug pairs. Significant quantitative differences were found between the two-phase pressure drop in the polymer micro-channels of this study and those obtained from previous glass

  16. Two-Phase Solid/Fluid Simulation of Dense Granular Flows With Dilatancy Effects (United States)

    Mangeney, Anne; Bouchut, Francois; Fernandez-Nieto, Enrique; Narbona-Reina, Gladys; Kone, El Hadj


    Describing grain/fluid interaction in debris flows models is still an open and challenging issue with key impact on hazard assessment [1]. We present here a two-phase two-thin-layer model for fluidized debris flows that takes into account dilatancy effects. It describes the velocity of both the solid and the fluid phases, the compression/ dilatation of the granular media and its interaction with the pore fluid pressure [2]. The model is derived from a 3D two-phase model proposed by Jackson [3] and the mixture equations are closed by a weak compressibility relation. This relation implies that the occurrence of dilation or contraction of the granular material in the model depends on whether the solid volume fraction is respectively higher or lower than a critical value. When dilation occurs, the fluid is sucked into the granular material, the pore pressure decreases and the friction force on the granular phase increases. On the contrary, in the case of contraction, the fluid is expelled from the mixture, the pore pressure increases and the friction force diminishes. To account for this transfer of fluid into and out of the mixture, a two-layer model is proposed with a fluid or a solid layer on top of the two-phase mixture layer. Mass and momentum conservation are satisfied for the two phases, and mass and momentum are transferred between the two layers. A thin-layer approximation is used to derive average equations. Special attention is paid to the drag friction terms that are responsible for the transfer of momentum between the two phases and for the appearance of an excess pore pressure with respect to the hydrostatic pressure. Interestingly, when removing the role of water, our model reduces to a dry granular flow model including dilatancy. We first compare experimental and numerical results of dilatant dry granular flows. Then, by quantitatively comparing the results of simulation and laboratory experiments on submerged granular flows, we show that our model

  17. Transport, geometrical, and topological properties of stealthy disordered hyperuniform two-phase systems (United States)

    Zhang, G.; Stillinger, F. H.; Torquato, S.


    Disordered hyperuniform many-particle systems have attracted considerable recent attention, since they behave like crystals in the manner in which they suppress large-scale density fluctuations, and yet also resemble statistically isotropic liquids and glasses with no Bragg peaks. One important class of such systems is the classical ground states of "stealthy potentials." The degree of order of such ground states depends on a tuning parameter χ. Previous studies have shown that these ground-state point configurations can be counterintuitively disordered, infinitely degenerate, and endowed with novel physical properties (e.g., negative thermal expansion behavior). In this paper, we focus on the disordered regime (0 interior and exterior to the spheres, respectively. The hyperuniformity of such two-phase media depends on the sphere sizes: While it was previously analytically proven that the resulting two-phase media maintain hyperuniformity if spheres do not overlap, here we show numerically that they lose hyperuniformity whenever the spheres overlap. We study certain transport properties of these systems, including the effective diffusion coefficient of point particles diffusing in the void phase as well as static and time-dependent characteristics associated with diffusion-controlled reactions. Besides these effective transport properties, we also investigate several related structural properties, including pore-size functions, quantizer error, an order metric, and percolation thresholds. We show that these transport, geometrical, and topological properties of our two-phase media derived from decorated stealthy ground states are distinctly different from those of equilibrium hard-sphere systems and spatially uncorrelated overlapping spheres. As the extent of short-range order increases, stealthy disordered two-phase media can attain nearly maximal effective diffusion coefficients over a broad range of volume fractions while also maintaining isotropy, and therefore

  18. Design and Implementation of a Novel Control System for Four Quadrant Operation of a Two-Phase Switched Reluctance Motor


    Morse, Justin C.


    In the emergence of switched reluctance motors to the commercial market, two-phase motors have received relatively little attention. Higher power and industrial applications have focused on the use of three and occasionally four phase machines, while low cost applications demanding only modest performance have largely been the domain of single phase machines. By contrast, while two phase systems have been the subject of occasional studies, they have not been widely applied. Two phase...

  19. Experimental Study of the Interfacial Waves in Horizontal Stratified Gas-liquid Two-phase Flows by Using the Developed Image Processing Technique

    CERN Document Server

    Kuntoro, Hadiyan Yusuf; Dinaryanto, Okto; Deendarlianto,; Indarto,


    Experimental series of stratified gas-liquid two-phase flows had been carried out in a 26 mm i.d. transparent acrylic horizontal pipe. The study was aimed to determine the interfacial wave characteristics of the flow and to develop a high quality database of it. The longitudinal section of the pipe was used as the reference section of image recording. Air and water were used as the test fluids, flowing co-currently inside the pipe. The flow behavior was recorded by using a high-speed video camera around 5 m in axial distance from the inlet pipe to ensure the fully-developed stratified gas-liquid two-phase flow. To correct the refraction due to the acrylic pipe, a correction box was employed in the visualization test section. The group of stratified smooth and wavy two-phase flows were successfully recorded and classified on the basis of the visualization study from 24 couples of test condition of superficial water and air velocities. Digital image processing technique was then used to perform quantitative ana...

  20. A dispersive liquid-liquid microextraction based on solidification of floating organic droplet followed by injector port silylation coupled with gas chromatography-tandem mass spectrometry for the determination of nine bisphenols in bottled carbonated beverages. (United States)

    Mandrah, Kapil; Satyanarayana, G N V; Roy, Somendu Kumar


    In the present study, a method has been efficiently developed for the first time to determine nine bisphenol analogues [bisphenol A (BPA), bisphenol C (BPC), bisphenol AF (BPAF), bisphenol E (BPE), bisphenol F (BPF), bisphenol G (BPG), bisphenol M (BPM), bisphenol S (BPS), and bisphenol Z (BPZ)] together in bottled carbonated beverages (collected from the local market of Lucknow, India) using dispersive liquid-liquid microextraction process. This is based on solidification of floating organic droplet (DLLME-SFO) followed by injector port silylation coupled with gas chromatography-tandem mass spectrometry. The process investigated parameters of DLLME-SFO (including the type of extraction and disperser solvents with their volumes, effect of pH, ionic strength, and the sample volume), factors influencing to injection port derivatization like, collision energy, injector port temperature, derivatizing reagent with sample injection volume, and type of organic solvent. BPA, BPF, BPZ, and BPS were detected in each sample; whereas, other bisphenols were also detected in some carbonated beverage samples. After optimizing the required conditions, good linearity of analytes was achieved in the range of 0.097-100ngmL-1 with coefficients of determination (R2)≥0.995. Intra-day and inter day precision of the method was good, with relative standard deviation (% RSD)≤10.95%. The limits of detection (LOD) and limits of quantification (LOQ) values of all bisphenols were ranged from 0.021 to 0.104ngmL-1 and 0.070 to 0.343ngmL-1, respectively. The recovery of extraction was good (73.15-95.08%) in carbonated beverage samples and good enrichment factors (96.36-117.33) were found. Thus, the developed method of microextraction was highly precise, fast, and reproducible to determine the level of contaminants in bottled carbonated beverages. Copyright © 2017 Elsevier B.V. All rights reserved.