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Sample records for counterflow nonpremixed flames

  1. Nonpremixed flame in a counterflow under electric fields

    KAUST Repository

    Park, Daegeun

    2016-05-08

    Electrically assisted combustion has been studied in order to control or improve flame characteristics, and emphasizing efficiency and emission regulation. Many phenomenological observations have been reported on the positive impact of electric fields on flame, however there is a lack of detailed physical mechanisms for interpreting these. To clarify the effects of electric fields on flame, I have investigated flame structure, soot formation, and flow field with ionic wind electrical current responses in nonpremixed counterflow flames. The effects of direct current (DC) electric field on flame movement and flow field was also demonstrated in premixed Bunsen flames. When a DC electric field was applied to a lower nozzle, the flames moved toward the cathode side due to Lorentz force action on the positive ions, soot particles simultaneously disappeared completely and laser diagnostics was used to identify the results from the soot particles. To understand the effects of an electric field on flames, flow visualization was performed by Mie scattering to check the ionic wind effect, which is considered to play an important role in electric field assisted combustion. Results showed a bidirectional ionic wind, with a double-stagnant flow configuration, which blew from the flame (ionic source) toward both the cathode and the anode. This implies that the electric field affects strain rate and the axial location of stoichiometry, important factors in maintaining nonpremixed counterflow flames; thus, soot formation of the counterflow flame can also be affected by the electric field. In a test of premixed Bunsen flames having parallel electrodes, flame movement toward the cathode and bidirectional ionic wind were observed. Using PIV measurement it was found that a created radial velocity caused by positive ions (i.e. toward a cathode), was much faster than the velocity toward the anode. Even in a study of alternating current (AC) electric fields, bidirectional ionic wind could

  2. Effects of the Burner Diameter on the Flame Structure and Extinction Limit of Counterflow Non-Premixed Flames

    Directory of Open Access Journals (Sweden)

    Chang Bo Oh

    2010-09-01

    Full Text Available Experiments and numerical simulations were conducted to investigate the effects of the burner diameter on the flame structure and extinction limit of counterflow non-premixed methane flames in normal gravity and microgravity. Experiments were performed for counterflow flames with a large inner diameter (d of 50 mm in normal gravity to compare the extinction limits with those obtained by previous studies where a small burner (d < 25 mm was used. Two-dimensional (2D simulations were performed to clarify the flame structure and extinction limits of counterflow non-premixed flame with a three-step global reaction mechanism. One-dimensional (1D simulations were also performed with the same three-step global reaction mechanism to provide reference data for the 2D simulation and experiment. For microgravity, the effect of the burner diameter on the flame location at the centerline was negligible at both high (ag = 50 s−1 and low (ag = 10 s−1 strain rates. However, a small burner flame (d = 15 mm in microgravity showed large differences in the maximum flame temperature and the flame size in radial direction compared to a large burner flame (d = 50 mm at low strain rate. In addition, for normal gravity, a small burner flame (d = 23.4 mm showed differences in the flame thickness, flame location, local strain rate, and maximum heat release rate compared to a large burner flame (d = 50 mm at low strain rate. Counterflow non-premixed flames with low and high strain rates that were established in a large burner were approximated by 1D simulation for normal gravity and microgravity. However, a counterflow non-premixed flame with a low strain rate in a small burner could not be approximated by 1D simulation for normal gravity due to buoyancy effects. The 2D simulations of the extinction limits correlated well with experiments for small and large burner flames. For microgravity, the extinction limit of a small burner flame (d = 15 mm was much lower than that

  3. Bidirectional ionic wind in nonpremixed counterflow flames with DC electric fields

    KAUST Repository

    Park, Daegeun

    2016-05-05

    Under an electric field, ions in the reaction zone of a flame generate a bulk flow motion called ionic wind. Because the majority of ions are positive, ionic wind is commonly considered to be unidirectional toward the cathode. A more thorough understanding of the effects of electric fields on flames could be obtained by clarifying the role of minor negative ions in the ionic wind. Here, we report on the effects of direct current on nonpremixed counterflow flames by visualizing the ionic wind. We found that the original flow field separates near the flame when it locates at a flow stagnation plane, resulting in a double-stagnant flow configuration. This evidences a bidirectional ionic wind blowing from the flame to both the cathode and the anode due to the positive and the negative ions, respectively. Meanwhile, an electric body force pulls the flame toward the cathode. Thus, the electric field affects the strain rate and the axial location of the stoichiometry, which are important for characterizing nonpremixed counterflow flames. In addition, measurement of the electric current density roughly showed a nearly saturated current when these flames restabilized under relatively high voltage. Detailed explanations of flame behavior, electric currents, and flow characteristics of various fuels are discussed in this study.

  4. Time evolution of propagating nonpremixed flames in a counterflow, annular slot burner under AC electric fields

    KAUST Repository

    Tran, Vu Manh

    2016-06-19

    The mechanism behind improved flame propagation speeds under electric fields is not yet fully understood. Although evidence supports that ion movements cause ionic wind, how this wind affects flame propagation has not been addressed. Here, we apply alternating current electric fields to a gap between the upper and lower parts of a counterflow, annular slot burner and present the characteristics of the propagating nonpremixed edge-flames produced. Contrary to many other previous studies, flame displacement speed decreased with applied AC voltage, and, depending on the applied AC frequency, the trailing flame body took on an oscillatory wavy motion. When flame displacement speeds were corrected using measured unburned flow velocities, we found no significant difference in flame propagation speeds, indicating no thermal or chemical effects by electric fields on the burning velocity. Thus, we conclude that the generation of bidirectional ionic wind is responsible for the impact of electric fields on flames and that an interaction between this bidirectional ionic wind and the flame parameters creates visible and/or measurable phenomenological effects. We also explain that the presence of trailing flame bodies is a dynamic response to an electric body force on a reaction zone, an area that can be considered to have a net positively charged volume. In addition, we characterize the wavy motion of the transient flame as a relaxation time independent of mixture strength, strain rate, and Lewis number.

  5. Propagating nonpremixed edge-flames in a counterflow, annular slot burner under DC electric fields

    KAUST Repository

    Tran, Vu Manh

    2016-09-11

    Characteristics of propagating nonpremixed edge-flames were investigated in a counterflow, annular slot burner. A high-voltage direct current (DC) was applied to the lower part of the burner and the upper part was grounded, creating electric field lines perpendicular to the direction of edge-flame propagation. Upon application of an electric field, an ionic wind is caused by the migration of positive and negative ions to lower and higher electrical potential sides of a flame, respectively. Under an applied DC, we found a significant decrease in edge-flame displacement speeds unlike several previous studies, which showed an increase in displacement speed. Within a moderate range of field intensity, we found effects on flame propagation speeds to be negligible after correcting the flame displacement speed with respect to the unburned flow velocity ahead of the flame edge. This indicates that the displacement speed of an edge-flame strongly depends on ionic wind and that an electric field has little or no impact on propagation speed. The ionic wind also influenced the location of the stoichiometric contour in front of the propagating edge in a given configuration such that a propagating edge was relocated to the higher potential side due to an imbalance between ionic winds originating from positive and negative ions. In addition, we observed a steadily wrinkled flame following transient propagation of the edge-flame, a topic for future research. © 2016 The Combustion Institute

  6. Soot reduction under DC electric fields in counterflow non-premixed laminar ethylene flames

    KAUST Repository

    Park, Daegeun

    2014-04-23

    The effects of DC electric fields on non-premixed ethylene flames in a counterflow burner were studied experimentally with a focus on the reduction of soot particles. The experiment was conducted by connecting a high voltage terminal and a ground terminal to a lower (fuel) and upper (oxidizer) nozzle, respectively. We applied direct current (DC) potentials in a range of -5 kV < Vdc < 5 kV. Uniform electric fields were then generated in the gap between the two nozzles. The experimental conditions were selected to cover both soot formation (SF) and soot formation oxidation (SFO) flames. The flames subjected to the negative electric fields moved toward the fuel nozzle because of an ionic wind due to the Lorentz force acting on the positive ions in the flames. In addition, the yellow luminosity significantly decreased, indicating changes in the sooting characteristics. To analyze the sooting characteristics under the electric fields, planar laser induced incandescence (PLII) and fluorescence (PLIF) techniques were used to visualize the soot, polycyclic aromatic hydrocarbons (PAHs), and OH radicals. The sooting limits in terms of the fuel and oxygen mole fractions were measured. No substantial soot formation due to the effects of the DC electric fields for the tested range of voltages and reactant mole fractions could be identified. The detailed flame behaviors and sooting characteristics under the DC electric fields are discussed. Copyright © Taylor & Francis Group, LLC.

  7. Role of the outer-edge flame on flame extinction in nitrogen-diluted non-premixed counterflow flames with finite burner diameters

    KAUST Repository

    Chung, Yong Ho

    2013-03-01

    This study of nitrogen-diluted non-premixed counterflow flames with finite burner diameters investigates the important role of the outer-edge flame on flame extinction through experimental and numerical analyses. It explores flame stability diagrams mapping the flame extinction response of nitrogen-diluted non-premixed counterflow flames to varying global strain rates in terms of burner diameter, burner gap, and velocity ratio. A critical nitrogen mole fraction exists beyond which the flame cannot be sustained; the critical nitrogen mole fraction versus global strain rate curves have C-shapes for various burner diameters, burner gaps, and velocity ratios. At sufficiently high strain-rate flames, these curves collapse into one curve; therefore, the flames follow the one-dimensional flame response of a typical diffusion flame. Low strain-rate flames are significantly affected by radial conductive heat loss, and therefore flame length. Three flame extinction modes are identified: flame extinction through shrinkage of the outer-edge flame with or without oscillations at the outer-edge flame prior to the extinction, and flame extinction through a flame hole at the flame center. The extinction modes are significantly affected by the behavior of the outer-edge flame. Detailed explanations are provided based on the measured flame-surface temperature and numerical evaluation of the fractional contribution of each term in the energy equation. Radial conductive heat loss at the flame edge to ambience is the main mechanism of extinction through shrinkage of the outer-edge flame in low strain-rate flames. Reduction of the burner diameter can extend the flame extinction mode by shrinking the outer-edge flame in higher strain-rate flames. © 2012 Elsevier Ltd. All rights reserved.

  8. A computational study of the effects of DC electric fields on non-premixed counterflow methane-air flames

    KAUST Repository

    Belhi, Memdouh

    2017-10-19

    Two-dimensional axisymmetric simulations for counterflow nonpremixed methane-air flames were undertaken as an attempt to reproduce the experimentally observed electro-hydrodynamic effect, also known as the ionic wind effect, on flames. Incompressible fluid dynamic solver was implemented with a skeletal chemical kinetic mechanism and transport property evaluations. The simulation successfully reproduced the key characteristics of the flames subjected to DC bias voltages at different intensity and polarity. Most notably, the simulation predicted the flame positions and showed good qualitative agreement with experimental data for the current-voltage curve. The flame response to the electric field with positive and negative polarity exhibited qualitatively different characteristics. In the negative polarity of the configuration considered, a non-monotonic variation of the current with the voltage was observed along with the existence of an unstable regime at an intermediate voltage level. With positive polarity, a typical monotonic current-voltage curve was obtained. This behavior was attributed to the asymmetry in the distribution of the positive and negative ions resulting from ionization processes. The present study demonstrated that the mathematical and computational models for the ion chemistry, transport, and fluid dynamics were able to describe the key processes responsible for the flame-electric field interaction.

  9. A computational study of the effects of DC electric fields on non-premixed counterflow methane-air flames

    Science.gov (United States)

    Belhi, Memdouh; Lee, Bok Jik; Bisetti, Fabrizio; Im, Hong G.

    2017-12-01

    Two-dimensional axisymmetric simulations for counterflow non-premixed methane-air flames were undertaken as an attempt to reproduce the experimentally observed electro-hydrodynamic effect, also known as the ionic wind effect, on flames. Incompressible fluid dynamic solver was implemented with a skeletal chemical kinetic mechanism and transport property evaluations. The simulation successfully reproduced the key characteristics of the flames subjected to DC bias voltages at different intensity and polarity. Most notably, the simulation predicted the flame positions and showed good qualitative agreement with experimental data for the current–voltage curve. The flame response to the electric field with positive and negative polarity exhibited qualitatively different characteristics. In the negative polarity of the configuration considered, a non-monotonic variation of the current with the voltage was observed, along with the existence of an unstable regime at an intermediate voltage level. With positive polarity, a typical monotonic current–voltage curve was obtained. This behavior was attributed to the asymmetry in the distribution of the positive and negative ions resulting from ionization processes. The present study demonstrated that the mathematical and computational models for the ion chemistry, transport, and fluid dynamics were able to describe the key processes responsible for the flame-electric field interaction.

  10. Strain rate and fuel composition dependence of chemiluminescent species profiles in non-premixed counterflow flames: comparison with model results

    Science.gov (United States)

    Prabasena, B.; Röder, M.; Kathrotia, T.; Riedel, U.; Dreier, T.; Schulz, C.

    2012-06-01

    A detailed comparison has been conducted between chemiluminescence (CL) species profiles of OH∗, CH∗, and C2 ∗, obtained experimentally and from detailed flame kinetics modeling, respectively, of atmospheric pressure non-premixed flames formed in the forward stagnation region of a fuel flow ejected from a porous cylinder and an air counterflow. Both pure methane and mixtures of methane with hydrogen (between 10 and 30 % by volume) were used as fuels. By varying the air-flow velocities methane flames were operated at strain rates between 100 and 350 s-1, while for methane/hydrogen flames the strain rate was fixed at 200 s-1. Spatial profiles perpendicular to the flame front were extracted from spectrograms recorded with a spectrometer/CCD camera system and evaluating each spectral band individually. Flame kinetics modeling was accomplished with an in-house chemical mechanism including C1-C4 chemistry, as well as elementary steps for the formation, removal, and electronic quenching of all measured active species. In the CH4/air flames, experiments and model results agree with respect to trends in profile peak intensity and position. For the CH4/H2/air flames, with increasing H2 content in the fuel the experimental CL peak intensities decrease slightly and their peak positions shift towards the fuel side, while for the model the drop in mole fraction is much stronger and the peak positions move closer to the fuel side. For both fuel compositions the modeled profiles peak closer to the fuel side than in the experiments. The discrepancies can only partly be attributed to the limited attainable spatial resolution but may also necessitate revised reaction mechanisms for predicting CL species in this type of flame.

  11. Effects of DME mixing on number density and size properties of soot particles in counterflow non-premixed ethylene flames

    KAUST Repository

    Choi, J. H.

    2015-05-01

    In order to investigate the effect of DME mixing on the number density and size of soot particles, DME was mixed in a counter flow non-premixed ethylene flame with mixture ratios of 5%, 14% and 30%. A laser extinction/scattering technique has been adopted to measure the volume fraction, number density, and mean size of soot particles. The experimental results showed that the highest soot concentrations were observed for flames with mixture ratios of 5% and 14%; however, for a mixture ratio of 30% the soot concentration decreased. Numerical results showed that the concentrations of propargyl radicals (C3H3) at the 5% and 14% ratios were higher than those measured in the ethylene-based flame, and the production of benzene (C6H6) in the 5% and 14% DME mixture flames was also increased. This indicates the crucial role of propargyl in benzene ring formation. These reactions generally become stronger with increased DME mixing, except for A1- + H2 → A1 + H (-R554) and n-C4H5 + C2H2 → A1 + H (R542). Therefore, it is indicated that adding DME to ethylene flames promotes benzene ring formation. Note that although the maximum C6H6 concentration is largest in the 30% DME mixing flame, the soot volume fraction is smaller than those for the 5% and 14% mixture ratios. This is because the local C6H6 concentration decreases in the relatively low temperature region in the fuel side where soot growth occurs. © 2015, The Korean Society of Mechanical Engineers and Springer-Verlag Berlin Heidelberg.

  12. Hysteresis and transition in swirling nonpremixed flames

    NARCIS (Netherlands)

    Tummers, M.J.; Hübner, A.W.; van Veen, E.H.; Hanjalic, K.; van der Meer, Theodorus H.

    2009-01-01

    Strongly swirling nonpremixed flames are known to exhibit a hysteresis when transiting from an attached long, sooty, yellow flame to a short lifted blue flame, and vice versa. The upward transition (by increasing the air and fuel flow rates) corresponds to a vortex breakdown, i.e. an abrupt change

  13. On Soot Inception in Nonpremixed Flames and the Effects of Flame Structure

    Science.gov (United States)

    Chao, B. H.; Liu, S.; Axelbaum, R. L.; Gokoglu, Suleyman (Technical Monitor)

    1998-01-01

    A simplified three-step model of soot inception has been employed with high activation energy asymptotics to study soot inception in nonpremixed counterflow systems with emphasis on understanding the effects of hydrodynamics and transport. The resulting scheme yields three zones: (1) a fuel oxidation zone wherein the fuel and oxidizer react to form product as well as a radical R, (e.g., H), (2) a soot/precursor formation zone where the radical R reacts with fuel to form "soot/precursor" S, and (3) a soot/precursor consumption zone where S reacts with the oxidizer to form product. The kinetic scheme, although greatly simplified, allows the coupling between soot inception and flame structure to be assessed. The results yield flame temperature, flame location, and a soot/precursor index S(sub I) as functions of Damkohler number for S formation. The soot/precursor index indicates the amount of S at the boundary of the formation region. The flame temperature indirectly indicates the total amount of S integrated over the formation region because as S is formed less heat release is available. The results show that unlike oxidation reactions, an extinction turning-point behavior does not exist for soot. Instead, the total amount of S slowly decreases with decreasing Damkohler number (increasing strain rate), which is consistent with counterflow flame experiments. When the Lewis number of the radical is decreased from unity, the total S reduces due to reduced residence time for the radical in the soot formation region. Similarly, when the Lewis number of the soot/precursor is increased from unity the amount of S increases for all Damkohler numbers. In addition to studying fuel-air (low stoichiometric mixture fraction) flames, the air-side nitrogen was substituted into the fuel, yielding diluted fuel-oxygen (high stoichiometric mixture fraction) flames with the same flame temperature as the fuel - air flames. The relative flame locations were different however, and

  14. Effects of Large Polycyclic Aromatic Hydrocarbons on the Soot Formation in Ethylene-Air Nonpremixed Flames

    KAUST Repository

    Prabhu, S.

    2015-03-30

    This study presents updated comprehensive gas-phase kinetic mechanism and aerosol models to predict soot formation characteristics in ethylene-air nonpremixed flames. A main objective is to investigate the sensitivity of the soot formation rate to various chemical pathways for large polycyclic aromatic hydrocarbons (PAH). In this study, the detailed chemical mechanism was reduced from 397 to 99 species using directed relation graph (DRG) and sensitivity analysis. The method of moments with interpolative closure (MOMIC) was employed for the soot aerosol model. Counterflow nonpremixed flames of pure ethylene at low strain rate sooting conditions are considered, for which the sensitivity of soot formation characteristics with respect to hetrogeneous nucleation is investigated. Results show that higher PAH concentrations result in higher soot nucleation rate, and that the average size of the particles are in good agreement with experimental results. It is found that the nucleation processes (i.e., soot inception) from higher PAH precursors, coronene in particular, is critical for accurate prediction of the overall soot formation.

  15. Effects of pressure on syngas/air turbulent nonpremixed flames

    Science.gov (United States)

    Lee, Bok Jik; Im, Hong G.; Ciottoli, Pietro Paolo; Valorani, Mauro

    2016-11-01

    Large eddy simulations (LES) of turbulent non-premixed jet flames were conducted to investigate the effects of pressure on the syngas/air flame behavior. The software to solve the reactive Navier-Stokes equations was developed based on the OpenFOAM framework, using the YSLFM library for the flamelet-based chemical closure. The flamelet tabulation is obtained by means of an in-house code designed to solve unsteady flamelets of both ideal and real fluid mixtures. The validation of the numerical setup is attained by comparison of the numerical results with the Sandia/ETH-Zurich experimental database of the CO/H2/N2 non-premixed, unconfined, turbulent jet flame, referred to as "Flame A". Two additional simulations, at pressure conditions of 2 and 5 atm, are compared and analyzed to unravel computational and scientific challenges in characterizing turbulent flames at high pressures. A set of flamelet solutions, representative of the jet flames under review, are analyzed following a CSP approach. In particular, the Tangential Stretching Rate (TSR), representing the reciprocal of the most energetic time scale associated with the chemical source term, and its extension to reaction-diffusion systems (extended TSR), are adopted.

  16. NO concentration imaging in turbulent nonpremixed flames

    Energy Technology Data Exchange (ETDEWEB)

    Schefer, R.W. [Sandia National Laboratories, Livermore, CA (United States)

    1993-12-01

    The importance of NO as a pollutant species is well known. An understanding of the formation characteristics of NO in turbulent hydrocarbon flames is important to both the desired reduction of pollutant emissions and the validation of proposed models for turbulent reacting flows. Of particular interest is the relationship between NO formation and the local flame zone, in which the fuel is oxidized and primary heat release occurs. Planar imaging of NO provides the multipoint statistics needed to relate NO formation to the both the flame zone and the local turbulence characteristics. Planar imaging of NO has been demonstrated in turbulent flames where NO was seeded into the flow at high concentrations (2000 ppm) to determine the gas temperature distribution. The NO concentrations in these experiments were significantly higher than those expected in typical hydrocarbon-air flames, which require a much lower detectability limit for NO measurements. An imaging technique based on laser-induced fluorescence with sufficient sensitivity to study the NO formation mechanism in the stabilization region of turbulent lifted-jet methane flames.

  17. Numerical Investigation of Soot Formation in Non-premixed Flames

    KAUST Repository

    Abdelgadir, Ahmed Gamaleldin

    2017-05-01

    Soot is a carbon particulate formed as a result of the combustion of fossil fuels. Due to the health hazard posed by the carbon particulate, government agencies have applied strict regulations to control soot emissions from road vehicles, airplanes, and industrial plants. Thus, understanding soot formation and evolution is critical. Practical combustion devices operate at high pressure and in the turbulent regime. Elevated pressures and turbulence on soot formation significantly and fundamental understanding of these complex interactions is still poor. In this study, the effects of pressure and turbulence on soot formation and growth are investigated numerically. As the first step, the evolution of the particle size distribution function (PSDF) and soot particles morphology are investigated in turbulent non-premixed flames. A Direct Simulation Monte Carlo (DSMC) code is developed and used. The stochastic reactor describes the evolution of soot in fluid parcels following Lagrangian trajectories in a turbulent flow field. The trajectories are sampled from a Direct Numerical Simulation (DNS) of an n-heptane turbulent non-premixed flame. Although individual trajectories display strong bimodality as in laminar flames, the ensemble-average PSDF possesses only one mode and a broad tail, which implies significant polydispersity induced by turbulence. Secondly, the effect of the flow and mixing fields on soot formation at atmospheric and elevated pressures is investigated in coflow laminar diffusion flames. The experimental observation and the numerical prediction of the spatial distribution are in good agreement. Based on the common scaling methodology of the flames (keeping the Reynolds number constant), the scalar dissipation rate decreases as pressure increases, promoting the formation of PAH species and soot. The decrease of the scalar dissipation rate significantly contributes to soot formation occurring closer to the nozzle and outward on the flames wings as pressure

  18. Ozone Activated Cool Diffusion Flames of Butane Isomers in a Counterflow Facility

    KAUST Repository

    Al Omier, Abdullah Abdulaziz

    2017-04-01

    Proceeding from the aim to reduce global pollution emissions from the continuous burning of hydrocarbons stimulated by increasing energy demand, more efficient and ultra-low emissions’ combustion concepts such as the homogenous charge compression ignition engines (HCCI) have been developed. These new engines rely on the low temperature chemistry (LTC) combustion concept. A detailed investigation of the properties of cool flames, governed by LTC, is essential for the design of these new engines. The primary goal of this work was to build a fundamental counterflow experiment for cool flames studies in a diffusive system, to better understand combustion in LTC engines. The project was intended to provide a basic understanding of the low-temperature reactivity and cool flames properties of butane isomers under atmospheric pressure conditions. This was achieved by establishing self-sustaining cool flames through a novel technique of ozone addition to an oxygen stream in a non-premixed counterflow model. The ignition and extinction limits of butane isomers’ cool flames have been investigated under a variety of strain rates. Results revealed that establishment of cool flames are favored at lower strain rates. Iso-butane was less reactive than n-butane by showing higher ignition and extinction limits. Ozone addition showed a significant influence on cool flame ignition and sustenance; it was found that increasing ozone concentration in the oxidizer stream dramatically increased the reactivity of both fuels. Results showed increased fuel reactivity as the temperature of the fuel stream outlet increased. 4 A numerical analysis was performed to simulate ignition and extinction of the cool flame in diffusive systems. The results revealed that ignition and extinction limits of cool flames are predominantly governed by LTC. The model qualitatively captured experimental trends for both fuels; however, it overpredicted both ignition and extinction limits under all strain rates

  19. Simulation of soot size distribution in an ethylene counterflow flame

    KAUST Repository

    Zhou, Kun

    2014-01-06

    Soot, an aggregate of carbonaceous particles produced during the rich combustion of fossil fuels, is an undesirable pollutant and health hazard. Soot evolution involves various dynamic processes: nucleation soot formation from polycyclic aromatic hydrocarbons (PAHs) condensation PAHs condensing on soot particle surface surface processes hydrogen-abstraction-C2H2-addition, oxidation coagulation two soot particles coagulating to form a bigger particle This simulation work investigates soot size distribution and morphology in an ethylene counterflow flame, using i). Chemkin with a method of moments to deal with the coupling between vapor consumption and soot formation; ii). Monte Carlo simulation of soot dynamics.

  20. Conical quarl swirl stabilized non-premixed flames: flame and flow field interaction

    KAUST Repository

    Elbaz, Ayman M.

    2017-09-19

    The flame-flow field interaction is studied in non-premixed methane swirl flames stabilized in quartz quarl via simultaneous measurements of the flow field using a stereo PIV and OH-PLIF at 5 KHz repetition rate. Under the same swirl intensity, two flames with different fuel jet velocity were investigated. The time-averaged flow field shows a unique flow pattern at the quarl exit, where two recirculation vortices are formed; a strong recirculation zone formed far from the quarl exit and a larger recirculation zone extending inside the quarl. However, the instantaneous images show that, the flow pattern near the quarl exit plays a vital role in the spatial location and structure of the reaction zone. In the low fuel jet velocity flame, a pair of vortical structures, located precisely at the corners of the quarl exit, cause the flame to roll up into the central region of low speed flow, where the flame sheet then tracks the axial velocity fluctuations. The vorticity field reveals a vortical structure surrounding the reaction zones, which reside on a layer of low compressive strain adjacent to that vortical structure. In the high fuel jet velocity flame, initially a laminar flame sheet resides at the inner shear layer of the main jet, along the interface between incoming fresh gas and high temperature recirculating gas. Further downstream, vortex breakdown alters the flame sheet path toward the central flame region. The lower reaction zones show good correlation to the regions of maximum vorticity and track the regions of low compressive strain associated with the inner shear layer of the jet flow. In both flames the reactions zones conform the passage of the large structure while remaining inside the low speed regions or at the inner shear layer.

  1. Investigating Soot Morphology in Counterflow Flames at Elevated Pressures

    KAUST Repository

    Amin, Hafiz Muhammad Fahid

    2018-01-01

    Practical combustion devices such as gas turbines and diesel engines operate at high pressures to increase their efficiency. Pressure significantly increases the overall soot yield. Morphology of these ultra-fine particles determines their airborne lifetime and their interaction with the human respiratory system. Therefore, investigating soot morphology at high pressure is of practical relevance. In this work, a novel experimental setup has been designed and built to study the soot morphology at elevated pressures. The experimental setup consists of a pressure vessel, which can provide optical access from 10° to 165° for multi-angle light scattering, and a counterflow burner which produces laminar flames at elevated pressures. In the first part of the study, N2-diluted ethylene/air and ethane air counterflow flames are stabilized from 2 to 5 atm. Two-angle light scattering and extinction technique have been used to study the effects of pressure on soot parameters. Path averaged soot volume fraction is found to be very sensitive to pressure and increased significantly from 2 to 5 atm. Primary particle size and aggregate size also increased with pressure. Multi-angle light scattering is also performed and flames are investigated from 3 to 5 atm. Scattering to absorption ratio is calculated from multi-angle light scattering and extinction data. Scattering to absorption ratio increased with pressure whereas the number of primary particles in an aggregate decreased with increasing pressure. In the next part of the study, Thermophoretic Sampling of soot is performed, in counterflow flames from 3 to 10 atm, followed by transmission electron microscopy. Mean primary particle size increased with pressure and these trends are consistent withour light scattering measurements. Fractal properties of soot aggregates are found to be insensitive to pressure. 2D diffused light line of sight attenuation (LOSA) and Laser Induced Incandescence (LII) are used to measure local soot

  2. Quantification of extinction mechanism in counterflow premixed flames

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Sang Kyu [Korea Institute of Machinery and Materials, Daejeon (Korea, Republic of); Cho, Eun Seong [Doosan Heavy Industries and Construction, Changwon (Korea, Republic of); Chung, Suk Ho [Abdullah University of Science and Technology, Thuwal (Saudi Arabia)

    2014-09-15

    The extinction mechanisms of stretched premixed flames have been investigated numerically for the fuels of CH{sub 4}, C{sub 3}H{sub 8}, H{sub 2}, CO and for the mixture fuels of CH{sub 4}+H{sub 2} and CO+H{sub 2} by adopting symmetric double premixed flames in a counterflow configuration. The local equilibrium temperature concept was used as a measure of energy loss or gain in order to quantify the extinction mechanism by preferential diffusion and/or incomplete reaction. The energy loss ratio from preferential diffusion arising from non-unity Lewis number and the loss ratio from incomplete reaction were calculated at various equivalence ratios near flame extinction. The results showed that the extinction of lean H{sub 2} , CH{sub 4}, CH{sub 4}+H{sub 2}, CO+H{sub 2}, and rich C{sub 3}H{sub 8} premixed flames was caused by incomplete reaction due to insufficient reaction time, indicating that the effective Lewis number was smaller than unity, while the effect of preferential diffusion resulted in energy gain. However, the extinction of rich H{sub 2}, CH{sub 4}, CH{sub 4}+H{sub 2}, CO+H{sub 2}, and lean C{sub 3}H{sub 8} premixed flames was affected by the combined effects of preferential diffusion and incomplete reaction indicating that the effective Lewis number was larger than unity. In CO premixed flames, incomplete reaction was dominant in both lean and rich cases due to the effective Lewis number close to unity. The effect of H{sub 2} mixing to CO is found to be quite significant as compared to CH{sub 4}+H{sub 2} cases, which can alter the flame behavior of CO flames to that of H{sub 2}.

  3. Quantification of extinction mechanism in counterflow premixed flames

    International Nuclear Information System (INIS)

    Choi, Sang Kyu; Cho, Eun Seong; Chung, Suk Ho

    2014-01-01

    The extinction mechanisms of stretched premixed flames have been investigated numerically for the fuels of CH 4 , C 3 H 8 , H 2 , CO and for the mixture fuels of CH 4 +H 2 and CO+H 2 by adopting symmetric double premixed flames in a counterflow configuration. The local equilibrium temperature concept was used as a measure of energy loss or gain in order to quantify the extinction mechanism by preferential diffusion and/or incomplete reaction. The energy loss ratio from preferential diffusion arising from non-unity Lewis number and the loss ratio from incomplete reaction were calculated at various equivalence ratios near flame extinction. The results showed that the extinction of lean H 2 , CH 4 , CH 4 +H 2 , CO+H 2 , and rich C 3 H 8 premixed flames was caused by incomplete reaction due to insufficient reaction time, indicating that the effective Lewis number was smaller than unity, while the effect of preferential diffusion resulted in energy gain. However, the extinction of rich H 2 , CH 4 , CH 4 +H 2 , CO+H 2 , and lean C 3 H 8 premixed flames was affected by the combined effects of preferential diffusion and incomplete reaction indicating that the effective Lewis number was larger than unity. In CO premixed flames, incomplete reaction was dominant in both lean and rich cases due to the effective Lewis number close to unity. The effect of H 2 mixing to CO is found to be quite significant as compared to CH 4 +H 2 cases, which can alter the flame behavior of CO flames to that of H 2 .

  4. Quantification of extinction mechanism in counterflow premixed flames

    KAUST Repository

    Choi, Sangkyu

    2014-09-01

    The extinction mechanisms of stretched premixed flames have been investigated numerically for the fuels of CH4, C3H8, H2, CO and for the mixture fuels of CH4+H2 and CO+H2 by adopting symmetric double premixed flames in a counterflow configuration. The local equilibrium temperature concept was used as a measure of energy loss or gain in order to quantify the extinction mechanism by preferential diffusion and/or incomplete reaction. The energy loss ratio from preferential diffusion arising from non-unity Lewis number and the loss ratio from incomplete reaction were calculated at various equivalence ratios near flame extinction. The results showed that the extinction of lean H2, CH4, CH4+H2, CO+H2, and rich C3H8 premixed flames was caused by incomplete reaction due to insufficient reaction time, indicating that the effective Lewis number was smaller than unity, while the effect of preferential diffusion resulted in energy gain. However, the extinction of rich H2, CH4, CH4+H2, CO+H2, and lean C3H8 premixed flames was affected by the combined effects of preferential diffusion and incomplete reaction indicating that the effective Lewis number was larger than unity. In CO premixed flames, incomplete reaction was dominant in both lean and rich cases due to the effective Lewis number close to unity. The effect of H2 mixing to CO is found to be quite significant as compared to CH4+H2 cases, which can alter the flame behavior of CO flames to that of H2.

  5. Near-field local flame extinction of oxy-syngas non-premixed jet flames: a DNS study

    OpenAIRE

    Ranga Dinesh, K.K.J.; Van Oijen, J.A; Luo, K.H.; Jiang, X.

    2014-01-01

    An investigation of the local flame extinction of H2/CO oxy-syngas and syngas-air nonpremixed jet flames was carried out using three-dimensional direct numerical simulations (DNS) with detailed chemistry by using flamelet generated manifold chemistry (FGM). The work has two main objectives: identify the influence of the Reynolds number on the oxy-syngas flame structure, and to clarify the local flame extinction of oxy-syngas and syngas-air flames at a higher Reynolds number.Two oxy-syngas fla...

  6. Experimental data regarding the characterization of the flame behavior near lean blowout in a non-premixed liquid fuel burner

    Directory of Open Access Journals (Sweden)

    Maria Grazia De Giorgi

    2016-03-01

    The data are related to the research article “Image processing for the characterization of flame stability in a non-premixed liquid fuel burner near lean blowout” in Aerospace Science and Technology [1].

  7. Chemical structures of an n-butanol counterflow flame

    Energy Technology Data Exchange (ETDEWEB)

    Sarathy, S.M.; Thomson, M.J. [Toronto Univ., ON (Canada). Dept. of Mechanical and Industrial Engineering

    2007-07-01

    N-butanol, also known as biobutanol, is an attractive alternative biofuel that can replace gasoline in transportation applications. Biobutanol can be produced via the fermentation of sugars, starches, and lignocellulose obtained from agricultural feedstocks. Although biobutanol offers several advantages over ethanol, its detailed combustion characteristics are not well known. In order to determine the effect of fuel structure on combustion products, this paper presented the results of a study that examined the emission and temperature profiles of an n-butanol counterflow flame. The paper presented the experimental data and discussed the potential reaction mechanisms that rationalized the observed species profiles. It was found that significant quantities of acetylene, acetaldehyde, ethane, and propene were measured in the n-butanol flame and that the reaction pathways leading to the formation of these compounds were yet to be identified. In addition, significant concentrations of formaldehyde and acetaldehyde were found. Results will be utilized to validate a detailed chemical kinetic model for n-butanol combustion. 13 refs., 3 figs.

  8. Combustion Dynamics of Plasma-Enhanced Premixed and Nonpremixed Flames

    Science.gov (United States)

    2010-12-01

    flame stability is dominated by the plasma discharge. The number density of the OH was calibrated from the LIF signal using a Hencken Burner with a...the typical OH production level in a Bunsen flame without plasma enhancement. This is an indication that the plasma is mostly acting to dissociate and...remains relatively stable on the outer flame front and is close to the Burner flame OH production rates, which indicates that the outer flame has little

  9. Effects of AC Electric Field on Small Laminar Nonpremixed Flames

    KAUST Repository

    Xiong, Yuan

    2015-04-01

    Electric field can be a viable method in controlling various combustion properties. Comparing to traditional actuators, an application of electric field requires very small power consumption. Especially, alternating current (AC) has received attention recently, since it could modulate flames appreciably even for the cases when direct current (DC) has minimal effects. In this study, the effect of AC electric fields on small coflow diffusion flames is focused with applications of various laser diagnostic techniques. Flow characteristics of baseline diffusion flames, which corresponds to stationary small coflow diffusion flames when electric field is not applied, were firstly investigated with a particular focus on the flow field in near-nozzle region with the buoyancy force exerted on fuels due to density differences among fuel, ambient air, and burnt gas. The result showed that the buoyancy force exerted on the fuel as well as on burnt gas significantly distorted the near-nozzle flow-fields. In the fuels with densities heavier than air, recirculation zones were formed very close to the nozzle exit. Nozzle heating effect influenced this near-nozzle flow-field particularly among lighter fuels. Numerical simulations were also conducted and the results showed that a fuel inlet boundary condition with a fully developed velocity profile for cases with long fuel tubes should be specified inside the fuel tube to obtain satisfactory agreement in both the flow and temperature fields with those from experiment. With sub-critical AC applied to the baseline flames, particle image velocimetry (PIV), light scattering, laser-induced incandescence (LII), and laser-induced fluores- cence (LIF) techniques were adopted to identify the flow field and the structures of OH, polycyclic aromatic hydrocarbons (PAHs), soot zone. Under certain AC condi- tions of applied voltage and frequency, the distribution of PAHs and the flow field near the nozzle exit were drastically altered from the

  10. Understanding and predicting soot generation in turbulent non-premixed jet flames.

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Hai (University of Southern California, Los Angeles, CA); Kook, Sanghoon; Doom, Jeffrey; Oefelein, Joseph Charles; Zhang, Jiayao; Shaddix, Christopher R.; Schefer, Robert W.; Pickett, Lyle M.

    2010-10-01

    This report documents the results of a project funded by DoD's Strategic Environmental Research and Development Program (SERDP) on the science behind development of predictive models for soot emission from gas turbine engines. Measurements of soot formation were performed in laminar flat premixed flames and turbulent non-premixed jet flames at 1 atm pressure and in turbulent liquid spray flames under representative conditions for takeoff in a gas turbine engine. The laminar flames and open jet flames used both ethylene and a prevaporized JP-8 surrogate fuel composed of n-dodecane and m-xylene. The pressurized turbulent jet flame measurements used the JP-8 surrogate fuel and compared its combustion and sooting characteristics to a world-average JP-8 fuel sample. The pressurized jet flame measurements demonstrated that the surrogate was representative of JP-8, with a somewhat higher tendency to soot formation. The premixed flame measurements revealed that flame temperature has a strong impact on the rate of soot nucleation and particle coagulation, but little sensitivity in the overall trends was found with different fuels. An extensive array of non-intrusive optical and laser-based measurements was performed in turbulent non-premixed jet flames established on specially designed piloted burners. Soot concentration data was collected throughout the flames, together with instantaneous images showing the relationship between soot and the OH radical and soot and PAH. A detailed chemical kinetic mechanism for ethylene combustion, including fuel-rich chemistry and benzene formation steps, was compiled, validated, and reduced. The reduced ethylene mechanism was incorporated into a high-fidelity LES code, together with a moment-based soot model and models for thermal radiation, to evaluate the ability of the chemistry and soot models to predict soot formation in the jet diffusion flame. The LES results highlight the importance of including an optically-thick radiation

  11. Sounding Solid Combustibles: Non-Premixed Flame Sound Synthesis for Different Solid Combustibles.

    Science.gov (United States)

    Yin, Qiang; Liu, Shiguang

    2018-02-01

    With the rapidly growing VR industry, in recent years, more and more attention has been paid for fire sound synthesis. However, previous methods usually ignore the influences of the different solid combustibles, leading to unrealistic sounding results. This paper proposes SSC (sounding solid combustibles), which is a new recording-driven non-premixed flame sound synthesis framework accounting for different solid combustibles. SSC consists of three components: combustion noise, vortex noise and popping sounds. The popping sounds are the keys to distinguish the differences of solid combustibles. To improve the quality of fire sound, we extract the features of popping sounds from the real fire sound examples based on modified Empirical Mode Decomposition (EMD) method. Unlike previous methods, we take both direct combustion noise and vortex noise into account because the fire model is non-premixed flame. In our method, we also greatly resolve the synchronization problem during blending the three components of SSC. Due to the introduction of the popping sounds, it is easy to distinguish the fire sounds of different solid combustibles by our method, with great potential in practical applications such as games, VR system, etc. Various experiments and comparisons are presented to validate our method.

  12. Correction of edge-flame propagation speed in a counterflow, annular slot burner

    KAUST Repository

    Tran, Vu Manh

    2015-10-22

    To characterize the propagation modes of flames, flame propagation speed must be accurately calculated. The impact of propagating edge-flames on the flow fields of unburned gases is limited experimentally. Thus, few studies have evaluated true propagation speeds by subtracting the flow velocities of unburned gases from flame displacement speeds. Here, we present a counterflow, annular slot burner that provides an ideal one-dimensional strain rate and lengthwise zero flow velocity that allowed us to study the fundamental behaviors of edge-flames. In addition, our burner has easy optical access for detailed laser diagnostics. Flame displacement speeds were measured using a high-speed camera and related flow fields of unburned gases were visualized by particle image velocimetry. These techniques allowed us to identify significant modifications to the flow fields of unburned gases caused by thermal expansion of the propagating edges, which enabled us to calculate true flame propagation speeds that took into account the flow velocities of unburned gases.

  13. Error analysis of large-eddy simulation of the turbulent non-premixed sydney bluff-body flame

    NARCIS (Netherlands)

    Kempf, A.M.; Geurts, Bernardus J.; Oefelein, J.C.

    2011-01-01

    A computational error analysis is applied to the large-eddy simulation of the turbulent non-premixed Sydney bluff-body flame, where the error is defined with respect to experimental data. The errorlandscape approach is extended to heterogeneous compressible turbulence, which is coupled to combustion

  14. Soot Particle Size Distribution Functions in a Turbulent Non-Premixed Ethylene-Nitrogen Flame

    KAUST Repository

    Boyette, Wesley

    2017-02-21

    A scanning mobility particle sizer with a nano differential mobility analyzer was used to measure nanoparticle size distribution functions in a turbulent non-premixed flame. The burner utilizes a premixed pilot flame which anchors a C2H4/N2 (35/65) central jet with ReD = 20,000. Nanoparticles in the flame were sampled through a N2-filled tube with a 500- μm orifice. Previous studies have shown that insufficient dilution of the nanoparticles can lead to coagulation in the sampling line and skewed particle size distribution functions. A system of mass flow controllers and valves were used to vary the dilution ratio. Single-stage and two-stage dilution systems were investigated. A parametric study on the effect of the dilution ratio on the observed particle size distribution function indicates that particle coagulation in the sampling line can be eliminated using a two-stage dilution process. Carbonaceous nanoparticle (soot) concentration particle size distribution functions along the flame centerline at multiple heights in the flame are presented. The resulting distributions reveal a pattern of increasing mean particle diameters as the distance from the nozzle along the centerline increases.

  15. A NEW DOUBLE-SLIT CURVED WALL-JET (CWJ) BURNER FOR STABILIZING TURBULENT PREMIXED AND NON-PREMIXED FLAMES

    KAUST Repository

    Mansour, Morkous S.

    2015-06-30

    A novel double-slit curved wall-jet (CWJ) burner was proposed and employed, which utilizes the Coanda effect by supplying fuel and air as annular-inward jets over a curved surface. We investigated the stabilization characteristics and structure of methane/air, and propane/air turbulent premixed and non-premixed flames with varying global equivalence ratio, , and Reynolds number, Re. Simultaneous time-resolved measurements of particle image velocimetry and planar laser-induced fluorescence of OH radicals were conducted. The burner showed potential for stable operation for methane flames with relatively large fuel loading and overall rich conditions. These have a non-sooting nature. However, propane flames exhibit stable mode for a wider range of equivalence ratio and Re. Mixing characteristics in the cold flow of non-premixed cases were first examined using acetone fluorescence technique, indicating substantial transport between the fuel and air by exhibiting appreciable premixing conditions.PIV measurements revealed that velocity gradients in the shear layers at the boundaries of the annularjets generate the turbulence, enhanced with the collisions in the interaction jet, IJ,region. Turbulent mean and rms velocities were influenced significantly by Re and high rms turbulent velocities are generated within the recirculation zone improving the flame stabilization in this burner.Premixed and non-premixed flames with high equivalence ratio were found to be more resistant to local extinction and exhibited a more corrugated and folded nature, particularly at high Re. For flames with low equivalence ratio, the processes of local quenching at IJ region and of re-ignition within merged jet region maintained these flames further downstream particularly for non-premixed methane flame, revealing a strong intermittency.

  16. Reduced Kinetic Mechanisms for Counterflow Methanol Diffusion Flames

    Science.gov (United States)

    Müller, C. M.; Seshadri, K.; Chen, J. Y.

    Studies on the oxidation of methanol in laminar flames are of practical importance, because methanol is considered for use as an alternate fuel for propulsion of internal combustion engines. Numerous experimental and theoretical studies on the combustion of methanol in premixed flames are available and they have been briefly reviewed in Chap. 9. However, such an extensive study is not available for diffusion flames. The present chapter concerns the structure and extinction characteristics of methanol-air diffusion flames.

  17. Numerical Analysis of Characteristics of Cellular Counterflow Diffusion Flames near Radiative Extinction Limit

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Su Ryong [Seoul National University of Technology, Seoul (Korea, Republic of)

    2014-06-15

    Nonlinear characteristics of cellular counterflow diffusion flame near the radiative extinction limit at large Damköhler number are numerically investigated. Lewis number is assumed to be 0.5 and flame evolution is calculated by imposing an infinitesimal disturbance to a one-dimensional(1-D) steady state flame. The early stage of nonlinear development is very similar to that predicted in a linear stability analysis. The disturbance with the wavenumber of the fastest growing mode emerges and grows gradually. Eventual, an alternating pattern of reacting and quenching stripes is developed. The cellular flame temperature is higher than that of 1-D flame because of the gain of the total enthalpy. As the Damköhler number is further increased, the shape of the cell becomes circular to increase the surface area per unit reacting volume. The cellular flames do not extinguish but survive even above the 1-D steady state extinction condition.

  18. Simulation and analysis of the soot particle size distribution in a turbulent nonpremixed flame

    KAUST Repository

    Lucchesi, Marco

    2017-02-05

    A modeling framework based on Direct Simulation Monte Carlo (DSMC) is employed to simulate the evolution of the soot particle size distribution in turbulent sooting flames. The stochastic reactor describes the evolution of soot in fluid parcels following Lagrangian trajectories in a turbulent flow field. The trajectories are sampled from a Direct Numerical Simulation (DNS) of a n-heptane turbulent nonpremixed flame. The DSMC method is validated against experimentally measured size distributions in laminar premixed flames and found to reproduce quantitatively the experimental results, including the appearance of the second mode at large aggregate sizes and the presence of a trough at mobility diameters in the range 3–8 nm. The model is then applied to the simulation of soot formation and growth in simplified configurations featuring a constant concentration of soot precursors and the evolution of the size distribution in time is found to depend on the intensity of the nucleation rate. Higher nucleation rates lead to a higher peak in number density and to the size distribution attaining its second mode sooner. The ensemble-averaged PSDF in the turbulent flame is computed from individual samples of the PSDF from large sets of Lagrangian trajectories. This statistical measure is equivalent to time-averaged, scanning mobility particle size (SMPS) measurements in turbulent flames. Although individual trajectories display strong bimodality as in laminar flames, the ensemble-average PSDF possesses only one mode and a long, broad tail, which implies significant polydispersity induced by turbulence. Our results agree very well with SMPS measurements available in the literature. Conditioning on key features of the trajectory, such as mixture fraction or radial locations does not reduce the scatter in the size distributions and the ensemble-averaged PSDF remains broad. The results highlight and explain the important role of turbulence in broadening the size distribution of

  19. Decomposition and hydrocarbon growth processes for esters in non-premixed flames.

    Science.gov (United States)

    Schwartz, William R; McEnally, Charles S; Pfefferle, Lisa D

    2006-06-01

    Biomass fuels are a promising renewable energy source, and so, the mechanisms that may produce toxic oxygenated byproducts and aromatic hydrocarbons from oxygenated hydrocarbons are of interest. Esters have the form R-(C=O)-O-R' and are components of biodiesel fuels. The five specific esters studied here are isomers of C5H10O2. The experiments were performed in atmospheric pressure coflowing methane/air non-premixed flames. A series of flames were generated by separately doping the fuel mixture with 5,000 ppm of each ester. This concentration is sufficiently large to produce measurable changes in intermediate hydrocarbon concentrations, yet small enough to not disturb the overall flame structure. Since the overall structure is not perturbed, the measured changes in the intermediate hydrocarbons can be directly attributed to the reactions of the esters. Analysis of these changes reveals that unimolecular six-centered dissociation is the primary decomposition pathway for the three esters with molecular arrangements capable of undergoing that mechanism. The remaining two esters exhibited decomposition rates and products that are consistent with simple fission as the dominant decomposition mechanism, though we do not exclude other pathways from playing a significant role in their decomposition. All of the esters produce aromatic hydrocarbons at higher rates than the undoped fuel, and the molecular arrangement of the ester isomers plays a role in the degree of aromatic formation. Isomer variations also influence the type and quantity of toxic oxygenates that are produced in the flames.

  20. Electric fields effect on liftoff and blowoff of nonpremixed laminar jet flames in a coflow

    KAUST Repository

    Kim, Minkuk

    2010-01-01

    The stabilization characteristics of liftoff and blowoff in nonpremixed laminar jet flames in a coflow have been investigated experimentally for propane fuel by applying AC and DC electric fields to the fuel nozzle with a single-electrode configuration. The liftoff and blowoff velocities have been measured by varying the applied voltage and frequency of AC and the voltage and the polarity of DC. The result showed that the AC electric fields extended the stabilization regime of nozzle-attached flame in terms of jet velocity. As the applied AC voltage increased, the nozzle-attached flame was maintained even over the blowout velocity without having electric fields. In such a case, a blowoff occurred directly without experiencing a lifted flame. While for the DC cases, the influence on liftoff was minimal. There existed three different regimes depending on the applied AC voltage. In the low voltage regime, the nozzle-detachment velocity of either liftoff or blowoff increased linearly with the applied voltage, while nonlinearly with the AC frequency. In the intermediate voltage regime, the detachment velocity decreased with the applied voltage and reasonably independent of the AC frequency. At the high voltage regime, the detachment was significantly influenced by the generation of discharges. © 2009 The Combustion Institute.

  1. Damköhler number effects on soot formation and growth in turbulent nonpremixed flames

    KAUST Repository

    Attili, Antonio

    2015-01-01

    The effect of Damköhler number on turbulent nonpremixed sooting flames is investigated via large scale direct numerical simulation in three-dimensional n-heptane/air jet flames at a jet Reynolds number of 15,000 and at three different Damköhler numbers. A reduced chemical mechanism, which includes the soot precursor naphthalene, and a high-order method of moments are employed. At the highest Damköhler number, local extinction is negligible, while flames holes are observed in the two lowest Damköhler number cases. Compared to temperature and other species controlled by fuel oxidation chemistry, naphthalene is found to be affected more significantly by the Damköhler number. Consequently, the overall soot mass fraction decreases by more than one order of magnitude for a fourfold decrease of the Damköhler number. On the contrary, the overall number density of soot particles is approximately the same, but its distribution in mixture fraction space is different in the three cases. The total soot mass growth rate is found to be proportional to the Damköhler number. In the two lowest Da number cases, soot leakage across the flame is observed. Leveraging Lagrangian statistics, it is concluded that soot leakage is due to patches of soot that cross the stoichiometric surface through flame holes. These results show the leading order effects of turbulent mixing in controlling the dynamics of soot in turbulent flames. © 2014 The Combustion Institute. Published by Elsevier Inc. All rights reserved.

  2. Investigation on Effect of Air Velocity in Turbulent Non-Premixed Flames

    Directory of Open Access Journals (Sweden)

    Namazian Zafar

    2016-09-01

    Full Text Available In this study, the turbulent non-premixed methane-air flame is simulated to determine the effect of air velocity on the length of flame, temperature distribution and mole fraction of species. The computational fluid dynamics (CFD technique is used to perform this simulation. To solve the turbulence flow, k-ε model is used. In contrast to the previous works, in this study, in each one of simulations the properties of materials are taken variable and then the results are compared. The results show that at a certain flow rate of fuel, by increasing the air velocity, similar to when the properties are constant, the width of the flame becomes thinner and the maximum temperature is higher; the penetration of oxygen into the fuel as well as fuel consumption is also increased. It is noteworthy that most of the pollutants produced are NOx, which are strongly temperature dependent. The amount of these pollutants rises when the temperature is increased. As a solution, decreasing the air velocity can decrease the amount of these pollutants. Finally, comparing the result of this study and the other work, which considers constant properties, shows that the variable properties assumption leads to obtaining more exact solution but the trends of both results are similar.

  3. Dynamics of flow–soot interaction in wrinkled non-premixed ethylene–air flames

    KAUST Repository

    Arias, Paul G.

    2015-08-17

    A two-dimensional simulation of a non-premixed ethylene–air flame was conducted by employing a detailed gas-phase reaction mechanism considering polycyclic aromatic hydrocarbons, an aerosol-dynamics-based soot model using a method of moments with interpolative closure, and a grey gas and soot radiation model using the discrete transfer method. Interaction of the sooting flame with a prescribed decaying random velocity field was investigated, with a primary interest in the effects of velocity fluctuations on the flame structure and the associated soot formation process for a fuel-strip configuration and a composition with mature soot growth. The temporally evolving simulation revealed a multi-layered soot formation process within the flame, at a level of detail not properly described by previous studies based on simplified soot models utilizing acetylene or naphthalene precursors for initial soot inception. The overall effect of the flame topology on the soot formation was found to be consistent with previous experimental studies, while a unique behaviour of localised strong oxidation was also noted. The imposed velocity fluctuations led to an increase of the scalar dissipation rate in the sooting zone, causing a net suppression in the soot production rate. Considering the complex structure of the soot formation layer, the effects of the imposed fluctuations vary depending on the individual soot reactions. For the conditions under study, the soot oxidation reaction was identified as the most sensitive to the fluctuations and was mainly responsible for the local suppression of the net soot production. © 2015 Taylor & Francis

  4. Numerical study of laminar nonpremixed methane flames in coflow jets: Autoignited lifted flames with tribrachial edges and MILD combustion at elevated temperatures

    KAUST Repository

    M. Al-Noman, Saeed

    2016-07-07

    Autoignition characteristics of laminar nonpremixed methane jet flames in high-temperature coflow air are studied numerically. Several flame configurations are investigated by varying the initial temperature and fuel mole fraction. At a relatively low initial temperature, a non-autoignited nozzle-attached flame is simulated at relatively low jet velocity. When the initial temperature is higher than that required for autoignition, two regimes are investigated: an autoignited lifted flame with tribrachial edge structure and an autoignited lifted flame with Mild combustion. The autoignited lifted flame with tribrachial edge exhibited three branches: lean and rich premixed flame wings and a trailing diffusion flame. Characteristics of kinetic structure for autoignited lifted flames are discussed based on the kinetic structures of homogeneous autoignition and flame propagation of stoichiometric mixture. Results showed that a transition from autoignition to flame propagation modes occurs for reasonably stoichiometric mixtures. The autoignited lifted flame with Mild combustion occurs when methane fuel is highly diluted with nitrogen. The kinetic structure analysis shows that the characteristics of Mild combustion can be treated as an autoignited lean premixed lifted flame. Transition behavior from Mild combustion to nozzle-attached flame was investigated by increasing the fuel mole fraction. As the maximum flame temperature increases with decreasing liftoff height, the kinetic structure showed a transition behavior from autoignition to flame propagation of a lean premixed flame. © 2016 The Combustion Institute

  5. A numerical study on extinction and NOx formation in nonpremixed flames with syngas fuel

    KAUST Repository

    Chun, Kangwoo

    2011-11-01

    The flame structure, extinction, and NOx emission characteristics of syngas/air nonpremixed flames, have been investigated numerically. The extinction stretch rate increased with the increase in the hydrogen proportion in the syngas and with lower fuel dilution and higher initial temperature. It also increased with pressure, except for the case of highly diluted fuel at high pressure. The maximum temperature and the emission index of nitric oxides (EINOx) also increased in aforementioned conditions. The EINOx decreased with stretch rate in general, while the decreasing rate was found to be somewhat different between the cases of N2 and CO2 dilutions. The reaction paths of NOx formation were analyzed and represented as NO reaction path diagram. The increase in N radical resulted in larger NOx production at high initial temperature and pressure. As the pressure increases, EINOx increases slower due to the third-body recombination. The thermal NO mechanism is weakened for high dilution cases and non-thermal mechanisms prevail. The combustion conditions achieving higher extinction stretch rate can be lead to more NOx emission, therefore that the selection of optimum operation range is needed in syngas combustion. © 2011 The Korean Society of Mechanical Engineers and Springer-Verlag Berlin Heidelberg.

  6. On the formation and early evolution of soot in turbulent nonpremixed flames

    KAUST Repository

    Bisetti, Fabrizio

    2012-01-01

    A Direct Numerical Simulation (DNS) of soot formation in an n-heptane/air turbulent nonpremixed flame has been performed to investigate unsteady strain effects on soot growth and transport. For the first time in a DNS of turbulent combustion, Polycyclic Aromatic Hydrocarbons (PAH) are included via a validated, reduced chemical mechanism. A novel statistical representation of soot aggregates based on the Hybrid Method of Moments is used [M.E. Mueller, G. Blanquart, H. Pitsch, Combust. Flame 156 (2009) 1143-1155], which allows for an accurate state-of-the-art description of soot number density, volume fraction, and morphology of the aggregates. In agreement with previous experimental studies in laminar flames, Damköhler number effects are found to be significant for PAH. Soot nucleation and growth from PAH are locally inhibited by high scalar dissipation rate, thus providing a possible explanation for the experimentally observed reduction of soot yields at increasing levels of mixing in turbulent sooting flames. Furthermore, our data indicate that soot growth models that rely on smaller hydrocarbon species such as acetylene as a proxy for large PAH molecules ignore or misrepresent the effects of turbulent mixing and hydrodynamic strain on soot formation due to differences in the species Damköhler number. Upon formation on the rich side of the flame, soot is displaced relative to curved mixture fraction iso-surfaces due to differential diffusion effects between soot and the gas-phase. Soot traveling towards the flame is oxidized, and aggregates displaced away from the flame grow primarily by condensation of PAH on the particle surface. In contrast to previous DNS studies based on simplified soot and chemistry models, surface reactions are found to contribute barely to the growth of soot, for nucleation and condensation processes occurring in the fuel stream are responsible for the most of soot mass generation. Furthermore, the morphology of the soot aggregates is

  7. Direct numerical simulations of non-premixed ethylene-air flames: Local flame extinction criterion

    KAUST Repository

    Lecoustre, Vivien R.

    2014-11-01

    Direct Numerical Simulations (DNS) of ethylene/air diffusion flame extinctions in decaying two-dimensional turbulence were performed. A Damköhler-number-based flame extinction criterion as provided by classical large activation energy asymptotic (AEA) theory is assessed for its validity in predicting flame extinction and compared to one based on Chemical Explosive Mode Analysis (CEMA) of the detailed chemistry. The DNS code solves compressible flow conservation equations using high order finite difference and explicit time integration schemes. The ethylene/air chemistry is simulated with a reduced mechanism that is generated based on the directed relation graph (DRG) based methods along with stiffness removal. The numerical configuration is an ethylene fuel strip embedded in ambient air and exposed to a prescribed decaying turbulent flow field. The emphasis of this study is on the several flame extinction events observed in contrived parametric simulations. A modified viscosity and changing pressure (MVCP) scheme was adopted in order to artificially manipulate the probability of flame extinction. Using MVCP, pressure was changed from the baseline case of 1 atm to 0.1 and 10 atm. In the high pressure MVCP case, the simulated flame is extinction-free, whereas in the low pressure MVCP case, the simulated flame features frequent extinction events and is close to global extinction. Results show that, despite its relative simplicity and provided that the global flame activation temperature is correctly calibrated, the AEA-based flame extinction criterion can accurately predict the simulated flame extinction events. It is also found that the AEA-based criterion provides predictions of flame extinction that are consistent with those provided by a CEMA-based criterion. This study supports the validity of a simple Damköhler-number-based criterion to predict flame extinction in engineering-level CFD models. © 2014 The Combustion Institute.

  8. Cool diffusion flames of butane isomers activated by ozone in the counterflow

    KAUST Repository

    Alfazazi, Adamu

    2018-02-02

    Ignition in low temperature combustion engines is governed by a coupling between low-temperature oxidation kinetics and diffusive transport. Therefore, a detailed understanding of the coupled effects of heat release, low-temperature oxidation chemistry, and molecular transport in cool flames is imperative to the advancement of new combustion concepts. This study provides an understanding of the low temperature cool flame behavior of butane isomers in the counterflow configuration through the addition of ozone. The initiation and extinction limits of butane isomers’ cool flames have been investigated under a variety of strain rates. Results revealed that, with ozone addition, establishment of butane cool diffusion flames was successful at low and moderate strain rates. iso-Butane has lower reactivity than n-butane, as shown by higher fuel mole fractions needed for cool flame initiation and lower extinction strain rate limits. Ozone addition showed a significant influence on the initiation and sustenance of cool diffusion flames; as ozone-less cool diffusion flame of butane isomers could not be established even at high fuel mole fractions. The structure of a stable n-butane cool diffusion flame was qualitatively examined using a time of flight mass spectrometer. Numerical simulations were performed using a detailed chemical kinetic model and molecular transport to simulate the extinction limits of the cool diffusion flames of the tested fuels. The model qualitatively captured experimental trends for both fuels and ozone levels, but over-predicted extinction limits of the flames. Reactions involving low-temperature species predominantly govern extinction limits of cool flames. The simulations were used to understand the effects of methyl branching on the behavior of n-butane and iso-butane cool diffusion flames.

  9. Effect of ac electric fields on counterflow diffusion flame of methane

    KAUST Repository

    Chul Choi, Byung

    2012-08-01

    The effect of electric fields on the response of diffusion flames in a counterflow has been investigated experimentally by varying the AC voltage and frequency. The result showed that the flame was stationary with high AC frequency above the threshold frequency, and it increased with the applied voltage and then leveled off at 35 Hz. Below the threshold frequency, however, the flame oscillated with a frequency that was synchronized with the applied AC frequency. This oscillation can be attributed to the ionic wind effect due to the generation of bulk flow, which arises from the momentum transfer by molecular collisions between neutral molecules and ions, where the ions in the reaction zone were accelerated by the Lorentz force. © 2012 The Korean Society of Mechanical Engineers.

  10. Sooting Characteristics and Modeling in Counterflow Diffusion Flames

    KAUST Repository

    Wang, Yu

    2013-11-01

    Soot formation is one of the most complex phenomena in combustion science and an understanding of the underlying physico-chemical mechanisms is important. This work adopted both experimental and numerical approaches to study soot formation in laminar counterfl ow diffusion flames. As polycyclic aromatic hydrocarbons (PAHs) are the precursors of soot particles, a detailed gas-phase chemical mechanism describing PAH growth upto coronene for fuels with 1 to 4 carbon atoms was validated against laminar premixed and counter- flow diffusion fl ames. Built upon this gas-phase mechanism, a soot model was then developed to describe soot inception and surface growth. This soot model was sub- sequently used to study fuel mixing effect on soot formation in counterfl ow diffusion flames. Simulation results showed that compared to the baseline case of the ethylene flame, the doping of 5% (by volume) propane or ethane in ethylene tends to increase the soot volume fraction and number density while keeping the average soot size almost unchanged. These results are in agreement with experimental observations. Laser light extinction/scattering as well as laser induced fluorescence techniques were used to study the effect of strain rate on soot and PAH formation in counterfl ow diffusion ames. The results showed that as strain rate increased both soot volume fraction and PAH concentrations decreased. The concentrations of larger PAH were more sensitive to strain rate compared to smaller ones. The effect of CO2 addition on soot formation was also studied using similar experimental techniques. Soot loading was reduced with CO2 dilution. Subsequent numerical modeling studies were able to reproduce the experimental trend. In addition, the chemical effect of CO2 addition was analyzed using numerical data. Critical conditions for the onset of soot were systematically studied in counterfl ow diffusion ames for various gaseous hydrocarbon fuels and at different strain rates. A sooting

  11. Blow-out of nonpremixed turbulent jet flames at sub-atmospheric pressures

    KAUST Repository

    Wang, Qiang

    2016-12-09

    Blow-out limits of nonpremixed turbulent jet flames in quiescent air at sub-atmospheric pressures (50–100 kPa) were studied experimentally using propane fuel with nozzle diameters ranging 0.8–4 mm. Results showed that the fuel jet velocity at blow-out limit increased with increasing ambient pressure and nozzle diameter. A Damköhler (Da) number based model was adopted, defined as the ratio of characteristic mixing time and characteristic reaction time, to include the effect of pressure considering the variations in laminar burning velocity and thermal diffusivity with pressure. The critical lift-off height at blow-out, representing a characteristic length scale for mixing, had a linear relationship with the theoretically predicted stoichiometric location along the jet axis, which had a weak dependence on ambient pressure. The characteristic mixing time (critical lift-off height divided by jet velocity) adjusted to the characteristic reaction time such that the critical Damköhler at blow-out conditions maintained a constant value when varying the ambient pressure.

  12. Experimental study of the stabilization process of a non-premixed flame via the destabilization analysis of the blue ring flame

    Energy Technology Data Exchange (ETDEWEB)

    Pinguet, Guillaume; Escudie, Dany [Centre de Thermique de Lyon (CETHIL) UMR 5008 CNRS-INSA-UCBL, INSA de Lyon, 20 av. A. Einstein, 69621 Villeurbanne cedex (France)

    2007-04-15

    The flame stabilization phenomenon remains a crucial issue. The experimental study of flame stabilization behind a tulip-shaped flame-holder is addressed in this paper. The process leading to the transition between specific modes - the blue ring flame and the instable ring - of a non-premixed flame stabilized on a tulip-shaped bluff-body is detailed. The aim of this study is to provide an accurate description of the destabilization of specific combustion modes, which enables a further understanding of the entire stabilization mechanism. The aerodynamic and mixing fields are described by laser Doppler anemometry and concentration measurements by sampling probe respectively. The behaviour of shear layers developing at the wake and jet boundaries are characterized by means of a spectral analysis of the fluctuating radial velocity. Results show that the destabilization process is related to the intensification of hot gas recirculation, inducing an upheaval of the dynamical condition of stabilization and a transition of mixing phenomena. (author)

  13. CONDITIONAL FLOW STATISTICS AND ALIGNMENT OF PRINCIPAL STRAIN RATES, VORTICITY, AND SCALAR GRADIENTS IN A TURBULENT NONPREMIXED JET FLAME

    KAUST Repository

    Attili, Antonio

    2015-06-30

    The alignment of vorticity and gradients of conserved and reactive scalars with the eigenvectors of the strain rate tensor (i.e., the principal strains) is investigated in a direct numerical simulation of a turbulent nonpremixed flame achieving a Taylor’s scale Reynolds number in the range 100≤Reλ≤150 (Attili et al. Comb. Flame, 161, 2014). The vorticity vector displays a pronounced tendency to align with the direction of the intermediate strain. These alignment statistics are in almost perfect agreement with those in homogeneous isotropic turbulence (Ashurst et al. Physics of Fluids 30, 1987) and differ significantly from the results obtained in other nonpremixed flames in which vorticity alignment with the most extensive strain was observed (Boratavet al. Physics of Fluids 8, 1996). The gradients of conserved and reactive scalars align with the most compressive strain. It is worth noting that conditioning on the local values of the mixture fraction, or equivalently conditioning on the distance from the flame sheet, does not affect the statistics. Our results suggest that turbulence overshadows the effects of heat release and chemical reactions. This may be due to the larger Reynolds number achieved in the present study compared to that in previous works.

  14. Formation of Soot in Counterflow Diffusion Flames with Carbon Dioxide Dilution

    KAUST Repository

    Wang, Yu

    2016-05-04

    Experimental and numerical modeling studies have been performed to investigate the effect of CO2 dilution on soot formation in ethylene counterflow diffusion flames. Thermal and chemical effects of CO2 addition on soot growth was numerically identified by using a fictitious CO2 species, which was treated as inert in terms of chemical reactions. The results showed that CO2 addition reduces soot formation both thermodynamically and chemically. In terms of chemical effect, the addition of CO2 decreases soot formation through various pathways, including: (1) reduced soot precursor (PAH) formation leading to lower inception rates and soot number density, which in turn results in lower surface area for soot mass addition; (2) reduced H, CH3, and C3H3 concentrations causing lower H abstraction rate and therefore less active site per surface area for soot growth; and (3) reduced C2H2 mole fraction and thus a slower C2H2 mass addition rate. In addition, the sooting limits were also measured for ethylene counterflow flames in both N2 and CO2 atmosphere and the results showed that sooting region was significantly reduced in the CO2 case compared to the N2 case. © 2016 Taylor & Francis.

  15. A PAH growth mechanism and synergistic effect on PAH formation in counterflow diffusion flames

    KAUST Repository

    Wang, Yu

    2013-09-01

    A reaction mechanism having molecular growth up to benzene for hydrocarbon fuels with up to four carbon-atoms was extended to include the formation and growth of polycyclic aromatic hydrocarbons (PAHs) up to coronene (C24H12). The new mechanism was tested for ethylene premixed flames at low (20torr) and atmospheric pressures by comparing experimentally observed species concentrations with those of the computed ones for small chemical species and PAHs. As compared to several existing mechanisms in the literature, the newly developed mechanism showed an appreciable improvement in the predicted profiles of PAHs. The new mechanism was also used to simulate PAH formation in counterflow diffusion flames of ethylene to study the effects of mixing propane and benzene in the fuel stream. In the ethylene-propane flames, existing experimental results showed a synergistic effect in PAH concentrations, i.e. PAH concentrations first increased and then decreased with increasing propane mixing. This PAH behavior was successfully captured by the new mechanism. The synergistic effect was predicted to be more pronounced for larger PAH molecules as compared to the smaller ones, which is in agreement with experimental observations. In the experimental study in which the fuel stream of ethylene-propane flames was doped with benzene, a synergistic effect was mitigated for benzene, but was observed for large PAHs. This effect was also predicted in the computed PAH profiles for these flames. To explain these responses of PAHs in the flames of mixture fuels, a pathway analysis has been conducted, which show that several resonantly stabilized species as well as C4H4 and H atom contribute to the enhanced synergistic behaviors of larger PAHs as compared to the small ones in the flames of mixture fuels. © 2013 The Combustion Institute.

  16. Flame characteristics and NO emission in methane/air-air counterflow premixed flames with applying FIR and FGR

    Energy Technology Data Exchange (ETDEWEB)

    Lim, In Gweon [Dept. of Mechanical Engineering, Myongji University, Yongin (Korea, Republic of); Park, Jeong [Dept. of Mechanical Engineering, Pukyong National University, Busan (Korea, Republic of)

    2016-08-15

    Numerical study was conducted to grasp flame characteristics and NO emission behaviors in CH4/air-air premixed counterflow flames with applying Fuel induced recirculation (FIR) and Flue gas recirculation (FGR) with CO{sub 2} and H{sub 2}O by varying global strain rate and the ratios of FIR and FGR. Chemical effects of additional CO{sub 2} and H{sub 2}O via FIR and FGR were analyzed through comparing flame characteristics and NO behaviors from real species (CO{sub 2} and H{sub 2}O) with those from their artificial species (XCO{sub 2} and XH{sub 2}O) which have the same thermochemical, radiative, and transport properties to those for the real species. The results showed that flame temperature and NO emission with FIR varied much more sensitively than that with FGR. Those varied little via FIR with CO{sub 2} and H{sub 2}O as well as XCO{sub 2} and XH{sub 2}O. However, those varied complicatedly by chemical effects of added CO{sub 2} and H{sub 2}O via FGR. In particular, there is a critical ratio of FGR below which NO emission index can be larger than those without applying FGR. Detailed analyses for them were made and discussed.

  17. Experimental and numerical investigation of fuel mixing effects on soot structures in counterflow diffusion flames

    KAUST Repository

    Choi, Byungchul

    2011-03-26

    Experimental and numerical analyses of laminar diffusion flames were performed to identify the effect of fuel mixing on soot formation in a counterflow burner. In this experiment, the volume fraction, number density, and particle size of soot were investigated using light extinction/scattering systems. The experimental results showed that the synergistic effect of an ethylene-propane flame is appreciable. Numerical simulations showed that the benzene (C6H6) concentration in mixture flames was higher than in ethylene-base flames because of the increase in the concentration of propargyl radicals. Methyl radicals were found to play an important role in the formation of propargyl, and the recombination of propargyl with benzene was found to lead to an increase in the number density for cases exhibiting synergistic effects. These results imply that methyl radicals play an important role in soot formation, particularly with regard to the number density. © 2011 The Korean Society of Automotive Engineers and Springer-Verlag Berlin Heidelberg.

  18. Soot formation characteristics of gasoline surrogate fuels in counterflow diffusion flames

    KAUST Repository

    Choi, Byungchul

    2011-01-01

    The characteristics of polycyclic aromatic hydrocarbon (PAH) and soot for gasoline surrogate fuels have been investigated in counterflow diffusion flames by adopting laser-induced fluorescence (LIF) and laser-induced incandescence (LII) techniques for both soot formation and soot formation/oxidation flames. Tested fuels were three binary mixtures from the primary reference fuels of n-heptane, iso-octane, and toluene. The result showed that PAH and soot maintained near zero level for all mixtures of n-heptane/iso-octane case under present experimental conditions. For n-heptane/toluene and iso-octane/toluene mixtures, PAH initially increased and then decreased with the toluene ratio, exhibiting a synergistic effect. The soot formation increased monotonically with the toluene ratio, however the effect of toluene on soot formation was minimal for relatively small toluene ratios. These results implied that even though toluene had a dominant role in soot and PAH formations, small amount of toluene had a minimal effect on soot formation. Numerical simulations have also been conducted by adopting recently proposed two kinetic mechanisms. The synergistic behavior of aromatic rings was predicted similar to the experimental PAH measurement, however, the degree of the synergistic effect was over-predicted for the soot formation flame, indicating the need for refinements in the kinetic mechanisms. © 2010 Published by Elsevier Inc. on behalf of The Combustion Institute. All rights reserved.

  19. Sooting limit in counterflow diffusion flames of ethylene/propane fuels and implication to threshold soot index

    KAUST Repository

    Joo, Peter H.

    2013-01-01

    Sooting limits in counterflow diffusion flames of propane/ethylene fuels have been studied experimentally using a light scattering technique, including the effects of dilution, fuel mixing, and strain rate. The results are discussed in view of the threshold soot index (TSI). In soot-formation (SF) flames, where the flame is located on the oxidizer side of the stagnation plane, the sooting limit depends critically on fuel type and subsequently on flame temperature. The sooting limit has a non-linear dependence on the fuel-mixing ratio, which is similar to the non-linear mixing rule for TSI observed experimentally in rich premixed flames, where soot oxidation is absent for both SF and rich premixed flames. In soot-formation-oxidation (SFO) flames, where the flame is located on the fuel side, the sooting limit depends critically on flame temperature, while it is relatively independent on fuel type. This result suggests a linear mixing rule for sooting limits in SFO flames, which is similar to the TSI behavior for coflow diffusion flames. Soot oxidation takes place for both types of flames. The aerodynamic strain effect on the sooting limits has also been studied and an appreciable influence has been observed. Under sooting conditions, soot volume fraction was measured using a light extinction technique. The soot loadings in SF flames of the mixture fuels demonstrated a synergistic effect, i.e., soot production increased for certain mixture fuels as compared to the respective singlecomponent fuels. © 2012 The Combustion Institute.

  20. Strain rate effect on sooting characteristics in laminar counterflow diffusion flames

    KAUST Repository

    Wang, Yu

    2016-01-20

    The effects of strain rate, oxygen enrichment and fuel type on the sooting characteristics of counterflow diffusion flames were studied. The sooting structures and relative PAH concentrations were measured with laser diagnostics. Detailed soot modeling using recently developed PAH chemistry and surface reaction mechanism was performed and the results were compared with experimental data for ethylene flames, focusing on the effects of strain rates. The results showed that increase in strain rate reduced soot volume fraction, average size and peak number density. Increase in oxygen mole fraction increased soot loading and decreased its sensitivity on strain rate. The soot volume fractions of ethane, propene and propane flames were also measured as a function of global strain rate. The sensitivity of soot volume fraction to strain rate was observed to be fuel dependent at a fixed oxygen mole fraction, with the sensitivity being higher for more sooting fuels. However, when the soot loadings were matched at a reference strain rate for different fuels by adjusting oxygen mole fraction, the dependence of soot loading on strain rate became comparable among the tested fuels. PAH concentrations were shown to decrease with increase in strain rate and the dependence on strain rate is more pronounced for larger PAHs. Soot modeling was performed using detailed PAH growth chemistry with molecular growth up to coronene. A qualitative agreement was obtained between experimental and simulation results, which was then used to explain the experimentally observed strain rate effect on soot growth. However, quantitatively, the simulation result exhibits higher sensitivity to strain rate, especially for large PAHs and soot volume fractions.

  1. Blow-out limits of nonpremixed turbulent jet flames in a cross flow at atmospheric and sub-atmospheric pressures

    KAUST Repository

    Wang, Qiang

    2015-07-22

    The blow-out limits of nonpremixed turbulent jet flames in cross flows were studied, especially concerning the effect of ambient pressure, by conducting experiments at atmospheric and sub-atmospheric pressures. The combined effects of air flow and pressure were investigated by a series of experiments conducted in an especially built wind tunnel in Lhasa, a city on the Tibetan plateau where the altitude is 3650 m and the atmospheric pressure condition is naturally low (64 kPa). These results were compared with results obtained from a wind tunnel at standard atmospheric pressure (100 kPa) in Hefei city (altitude 50 m). The size of the fuel nozzles used in the experiments ranged from 3 to 8 mm in diameter and propane was used as the fuel. It was found that the blow-out limit of the air speed of the cross flow first increased (“cross flow dominant” regime) and then decreased (“fuel jet dominant” regime) as the fuel jet velocity increased in both pressures; however, the blow-out limit of the air speed of the cross flow was much lower at sub-atmospheric pressure than that at standard atmospheric pressure whereas the domain of the blow-out limit curve (in a plot of the air speed of the cross flow versus the fuel jet velocity) shrank as the pressure decreased. A theoretical model was developed to characterize the blow-out limit of nonpremixed jet flames in a cross flow based on a Damköhler number, defined as the ratio between the mixing time and the characteristic reaction time. A satisfactory correlation was obtained at relative strong cross flow conditions (“cross flow dominant” regime) that included the effects of the air speed of the cross flow, fuel jet velocity, nozzle diameter and pressure.

  2. Investigation of soot morphology and particle size distrib ution in a turbulent nonpremixed flame via Monte Carlo simulations

    KAUST Repository

    Abdelgadir, Ahmed

    2015-03-30

    Recently, our group performed a set of direct numerical simulations (DNS) of soot formation and growth in a n-heptane three dimensional non-premixed jet flame [Attili et al., Proc. Comb. Inst, 35, 2015], [Attili et al., Comb. Flame, 161, 2014], [Bisetti et al.,Trans of the Royal Soc, 372, 2014]. The evolution of species relevant to soot formation and growth have been sampled along a large number of Lagrangian trajectories in the DNS. In this work, the DNS results are post-processed to compute the soot evolution along selected Lagrangian trajectories using a Monte Carlo method. An operator splitting approach is adopted to split the deterministic processes (nucleation, surface growth and oxidation) from coagulation, which is treated stochastically. The morphological properties of soot and the particlesize distribution are investigated. For trajectories that experience an early strong nucleation event, the particle size distribution is found to be bimodal, as the soot particles have enough time to coagulate and grow while it is unimodal for trajectories characterized by only late nucleation events. As a results, the average size distribution at two different crosswise positions in the flame is unimodal.

  3. Effects of Turbulence on Flame Structure and NOx Emission of Turbulent Jet Non-Premixed Flames in High-Temperature Air Combustion

    Science.gov (United States)

    Kobayashi, Hideaki; Oono, Ken; Cho, Eun-Seong; Hagiwara, Hirokazu; Ogami, Yasuhiro; Niioka, Takashi

    Turbulent jet non-premixed flame under the conditions of High Temperature Air Combustion (HiCOT) was investigated. Air diluted with nitrogen was preheated up to about 1300K. Propane was injected through a fuel tube parallel to the preheated airflow. LDV measurement of turbulence, CH-PLIF for reaction zone visualization, and NOx concentration measurements in the burnt gas were performed and the relations between these characteristics were examined. Results showed that turbulence intensity generated by perforated plate installed upstream of the fuel tube was high at high-temperature airflow due to high velocity compared with that at room temperature airflow when the flow rate was controlled to keep the excess air ratio constant regardless of preheating. The reaction zone represented by the CH-PLIF images still had a thin structure even in the HiCOT condition of oxygen concentration of 8vol.%. The flow turbulence in the combustion duct played a significant role in decreasing NOx emission. Due to turbulence, flame was broken and a bubble-like flame structure was generated, especially in the lifted flame cases, implying that the burning fuel lumps flow a considerable distance in air with a low oxygen concentration and generate uniform heat release profiles in HiCOT furnaces.

  4. Compositional effects on PAH and soot formation in counterflow diffusion flames of gasoline surrogate fuels

    KAUST Repository

    Park, Sungwoo

    2017-02-05

    Gasoline surrogate fuels are widely used to understand the fundamental combustion properties of complex refinery gasoline fuels. In this study, the compositional effects on polycyclic aromatic hydrocarbons (PAHs) and soot formation were investigated experimentally for gasoline surrogate mixtures comprising n-heptane, iso-octane, and toluene in counterflow diffusion flames. A comprehensive kinetic model for the gasoline surrogate mixtures was developed to accurately predict the fuel oxidation along with the formation of PAHs and soot in flames. This combined model was first tested against ignition delay times and laminar burning velocities data. The proposed model for the formation and growth of PAHs up to coronene (C24H12) was based on previous studies and was tested against existing and present new experimental data. Additionally, in the accompanied soot model, PAHs with sizes larger than (including) pyrene were used for the inception of soot particles, followed by particle coagulations and PAH condensation/chemical reactions on soot surfaces. The major pathways for the formation of PAHs were also identified for the surrogate mixtures. The model accurately captures the synergistic PAH formation characteristics observed experimentally for n-heptane/toluene and iso-octane/toluene binary mixtures. Furthermore, the present experimental and modeling results also elucidated different trends in the formation of larger PAHs and soot between binary n-heptane/iso-octane and ternary n-heptane/iso-octane/toluene mixtures. Propargyl radicals (C3H3) were shown to be important in the formation and growth of PAHs for n-heptane/iso-octane mixtures when the iso-octane concentration increased; however, reactions involving benzyl radicals (C6H5CH2) played a significant role in the formation of PAHs for n-heptane/iso-octane/toluene mixtures. These results indicated that the formation of PAHs and subsequently soot was strongly affected by the composition of gasoline surrogate mixtures.

  5. Formation, growth, and transport of soot in a three-dimensional turbulent non-premixed jet flame

    KAUST Repository

    Attili, Antonio

    2014-07-01

    The formation, growth, and transport of soot is investigated via large scale numerical simulation in a three-dimensional turbulent non-premixed n-heptane/air jet flame at a jet Reynolds number of 15,000. For the first time, a detailed chemical mechanism, which includes the soot precursor naphthalene and a high-order method of moments are employed in a three-dimensional simulation of a turbulent sooting flame. The results are used to discuss the interaction of turbulence, chemistry, and the formation of soot. Compared to temperature and other species controlled by oxidation chemistry, naphthalene is found to be affected more significantly by the scalar dissipation rate. While the mixture fraction and temperature fields show fairly smooth spatial and temporal variations, the sensitivity of naphthalene to turbulent mixing causes large inhomogeneities in the precursor fields, which in turn generate even stronger intermittency in the soot fields. A strong correlation is apparent between soot number density and the concentration of naphthalene. On the contrary, while soot mass fraction is usually large where naphthalene is present, pockets of fluid with large soot mass are also frequent in regions with very low naphthalene mass fraction values. From the analysis of Lagrangian statistics, it is shown that soot nucleates and grows mainly in a layer close to the flame and spreads on the rich side of the flame due to the fluctuating mixing field, resulting in more than half of the total soot mass being located at mixture fractions larger than 0.6. Only a small fraction of soot is transported towards the flame and is completely oxidized in the vicinity of the stoichiometric surface. These results show the leading order effects of turbulent mixing in controlling the dynamics of soot in turbulent flames. Finally, given the difficulties in obtaining quantitative data in experiments of turbulent sooting flames, this simulation provides valuable data to guide the development of

  6. Soot modeling of counterflow diffusion flames of ethylene-based binary mixture fuels

    KAUST Repository

    Wang, Yu

    2015-03-01

    A soot model was developed based on the recently proposed PAH growth mechanism for C1-C4 gaseous fuels (KAUST PAH Mechanism 2, KM2) that included molecular growth up to coronene (A7) to simulate soot formation in counterflow diffusion flames of ethylene and its binary mixtures with methane, ethane and propane based on the method of moments. The soot model has 36 soot nucleation reactions from 8 PAH molecules including pyrene and larger PAHs. Soot surface growth reactions were based on a modified hydrogen-abstraction-acetylene-addition (HACA) mechanism in which CH3, C3H3 and C2H radicals were included in the hydrogen abstraction reactions in addition to H atoms. PAH condensation on soot particles was also considered. The experimentally measured profiles of soot volume fraction, number density, and particle size were well captured by the model for the baseline case of ethylene along with the cases involving mixtures of fuels. The simulation results, which were in qualitative agreement with the experimental data in the effects of binary fuel mixing on the sooting structures of the measured flames, showed in particular that 5% addition of propane (ethane) led to an increase in the soot volume fraction of the ethylene flame by 32% (6%), despite the fact that propane and ethane are less sooting fuels than is ethylene, which is in reasonable agreement with experiments of 37% (14%). The model revealed that with 5% addition of methane, there was an increase of 6% in the soot volume fraction. The average soot particle sizes were only minimally influenced while the soot number densities were increased by the fuel mixing. Further analysis of the numerical data indicated that the chemical cross-linking effect between ethylene and the dopant fuels resulted in an increase in PAH formation, which led to higher soot nucleation rates and therefore higher soot number densities. On the other hand, the rates of soot surface growth per unit surface area through the HACA mechanism were

  7. A comparative study on the sooting tendencies of various 1-alkene fuels in counterflow diffusion flames

    KAUST Repository

    Wang, Yu

    2018-02-19

    Alkenes are important components in transportation fuels, and are known to have increased sooting tendencies compared to analogous saturated hydrocarbons with the same carbon number. This work aims to understand the sooting tendencies of various 1-alkenes through experiments and numerical simulations for counterflow diffusion flames. Soot and PAH formation tendencies of 1-alkene fuels, including ethylene (C2H4), propene (C3H6), 1-butene (1-C4H8), 1-pentene (1-C5H10), 1-hexene (1-C6H12) and 1-octene (1-C8H16), were experimentally studied using laser induced-incandescence (LII) and laser-induced fluorescence (LIF) techniques, respectively. From the LII results, 1-C4H8 was found to be the most sooting fuel, followed by C3H6 > 1-C5H10 > 1-C6H12 > 1-C8H16 > C2H4. The LIF data with a detection wavelength of 500 nm indicated the PAH formation tendencies followed the order of 1-C4H8 > 1-C5H10 ∼1-C6H12 > C3H6 > 1-C8H16 > C2H4, which were different from the order of sooting tendencies. Numerical simulations with a comprehensive chemical kinetic model including PAH growth chemistry for the tested 1-alkene fuels were conducted to elucidate the aromatic formation pathways and rationalize the experimentally observed trends. The numerical results highlighted the importance of intermediate species with odd carbon numbers in aromatic species formation, such as propargyl, allyl, cyclopentadienyl and indenyl radicals. Their concentration differences, which could be traced back to the parent fuel molecules through rate of production analysis, rationalize the experimentally observed differences in soot and PAH formation tendencies.

  8. Computational and Experimental Study of Ammonium Perchlorate/Ethylene Counterflow Diffusion Flames

    National Research Council Canada - National Science Library

    Smooke, M. D; Yetter, Richard A; Parr, T. P; Hanson-Parr, D. M; Tanoff, M. A; Colket, M. B; Hall, R. J

    2000-01-01

    ...) combustion were counterflowed against an ethylene fuel stream. The two-dimensional problem can be reduced to a one-dimensional boundary value problem along the stagnation point streamline through the introduction of a similarity transformation...

  9. A parametric study of AC electric field-induced toroidal vortex formation in laminar nonpremixed coflow flames

    KAUST Repository

    Xiong, Yuan

    2017-05-02

    This study presents an experimental work investigating the controlling parameters on the formation of an electrically-induced inner toroidal vortex (ITV) near a nozzle rim in small, laminar nonpremixed coflow flames, when an alternating current is applied to the nozzle. A systematic parametric study was conducted by varying the flow parameters of the fuel and coflowing-air velocities, and the nozzle diameter. The fuels tested were methane, ethylene, ethane, propane, n-butane, and i-butane, each representing different ion-generation characteristics and sooting tendencies. The results showed that the fluid dynamic effects on ITV formation were weak, causing only mild variation when altering flow velocities. However, increased fuel velocity resulted in increased polycyclic aromatic hydrocarbon (PAH) formation, which promoted ITV formation. When judging the ITV-formation tendency based on critical applied voltage and frequency, it was qualitatively well correlated with the PAH concentration and the relative location of PAHs to the nozzle rim. The sooting tendency of the fuels did not affect the results much. A change in the nozzle diameter highlighted the importance of the relative distance between the PAH zone and the nozzle rim, indicating the role of local electric-field intensity on ITV formation. Detailed onset conditions, characteristics of near-nozzle flow patterns, and PAH distributions are also discussed.

  10. Structure of turbulent non-premixed flames modeled with two-step chemistry

    Science.gov (United States)

    Chen, J. H.; Mahalingam, S.; Puri, I. K.; Vervisch, L.

    1992-01-01

    Direct numerical simulations of turbulent diffusion flames modeled with finite-rate, two-step chemistry, A + B yields I, A + I yields P, were carried out. A detailed analysis of the turbulent flame structure reveals the complex nature of the penetration of various reactive species across two reaction zones in mixture fraction space. Due to this two zone structure, these flames were found to be robust, resisting extinction over the parameter ranges investigated. As in single-step computations, mixture fraction dissipation rate and the mixture fraction were found to be statistically correlated. Simulations involving unequal molecular diffusivities suggest that the small scale mixing process and, hence, the turbulent flame structure is sensitive to the Schmidt number.

  11. Influence of G-jitter on the characteristics of a non-premixed flame: Experimental approach

    Science.gov (United States)

    Joulain, Pierre; Cordeiro, Pierre; Rouvreau, Sébastien; Legros, Guillaume; Fuentes, Andres; Torero, José L.

    2005-03-01

    The combustion of a flat plate in a boundary layer under microgravity conditions, which was first described by Emmons, is studied using a gas burner. Magnitude of injection and blowing velocities are chosen to be characteristic of pyrolyzing velocity of solid fuels, and of ventilation systems in space stations. These velocities are about 0.1 m/s for oxidiser flow and 0.004m/s for fuel flow. In this configuration, flame layout results from a coupled interaction between oxidiser flow, fuel flow and thermal expansion. Influences of these parameters are studied experimentally by means of flame length and standoff distance measurements using CH* chemiluminescence's and visible emission of the flame. Flow was also studied with Particle Image Velocimetry (PIV). Inert flows, with and without injection, and reacting flow in a microgravity environment were considered to distinguish aerodynamic from thermal effect. Thermal expansion effects have been shown by means of the acceleration of oxidiser flow. Three-dimensional effects, which are strongly marked for high injection velocities were studied. Three-dimensional tools adaptability to parabolic flights particular conditions were of concern. Flame sensitivity to g-jitters was investigated according to g-jitters frequency and range involved by parabolic flights. It appears that flame location (standoff distance), flame characteristics (length, thickness, brightness) and the aerodynamic field of the low velocity reacting flow are very much affected by the fluctuation of the gravity level or g-jitter. The lower the g-jitter frequency is, the higher the perturbation. Consequently it is difficult to perform relevant experiments for a main flow velocity lower than 0.05m/s. DNS calculations confirm the present observations, but most of the results are presented elsewhere.

  12. Modeling and Simulation of Swirl Stabilized Turbulent Non-Premixed Flames

    Science.gov (United States)

    Badillo-Rios, Salvador; Karagozian, Ann

    2017-11-01

    Flame stabilization is an important design criterion for many combustion chambers, especially at lean conditions and/or high power output, where insufficient stabilization can result in dangerous oscillations and noisy or damaged combustors. At high flow rates, swirling flow can offer a suitable stabilization mechanism, although understanding the dynamics of swirl-stabilized turbulent flames remains a significant challenge. Utilizing the General Equation and Mesh Solver (GEMS) code, which solves the Navier-Stokes equations along with the energy equation and five species equations, 2D axisymmetric and full 3D parametric studies and simulations are performed to guide the design and development of an experimental swirl combustor configuration and to study the effects of swirl on statistically stationary combustion. Results show that as the momentum of air is directed into the inner air inlet rather than the outer inlet of the swirl combustor, the central recirculating region becomes stronger and more unsteady, improving mixing and burning efficiency in that region. A high temperature region is found to occur as a result of burning of the trapped fuel from the central toroidal vortex. The effects of other parameters on flowfield and flame-stabilization dynamics are explored. Supported by ERC, Inc. (PS150006) and AFOSR (Dr. Chiping Li).

  13. Predicting the Effects of Fuel Composition and Flame Structure on Soot Generation in Turbulent Non-Premixed Flames

    Science.gov (United States)

    2011-03-01

    conditions for takeoff in a gas turbine engine. Fuels investigated included ethylene and a JP-8 surrogate consisting of n-dodecane and m- xylene . The...recirculation EPA Environmental Protection Agency FSK full-spectrum k-distribution FT Fischer-Tropsch FTIR fourier transform infrared GE General...19 Figure 9. Comparison of experimental m- xylene -air flame speed measurements [83] (left) and ignition

  14. Transported PDF Modeling of Nonpremixed Turbulent CO/H-2/N-2 Jet Flames

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, xinyu; Haworth, D. C.; Huckaby, E. David

    2012-01-01

    Turbulent CO/H{sub 2}/N{sub 2} (“syngas”) flames are simulated using a transported composition probability density function (PDF) method. A consistent hybrid Lagrangian particle/Eulerian mesh algorithm is used to solve the modeled PDF transport equation. The model includes standard k–ϵ turbulence, gradient transport for scalars, and Euclidean minimum spanning tree (EMST) mixing. Sensitivities of model results to variations in the turbulence model, the treatment of radiation heat transfer, the choice of chemical mechanism, and the PDF mixing model are explored. A baseline model reproduces the measured mean and rms temperature, major species, and minor species profiles reasonably well, and captures the scaling that is observed in the experiments. Both our results and the literature suggest that further improvements can be realized with adjustments in the turbulence model, the radiation heat transfer model, and the chemical mechanism. Although radiation effects are relatively small in these flames, consideration of radiation is important for accurate NO prediction. Chemical mechanisms that have been developed specifically for fuels with high concentrations of CO and H{sub 2} perform better than a methane mechanism that was not designed for this purpose. It is important to account explicitly for turbulence–chemistry interactions, although the details of the mixing model do not make a large difference in the results, within reasonable limits.

  15. Ammonia conversion and NOx formation in laminar coflowing nonpremixed methane-air flames

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, Neal; Jensen, Anker; Glarborg, Peter; Day, Marcus S.; Grcar, Joseph F.; Bell, John B.; Pope, Christopher J.; Kee, Robert J.

    2002-01-07

    This paper reports on a combined experimental and modeling investigation of NOx formation in nitrogen-diluted laminar methane diffusion flames seeded with ammonia. The methane-ammonia mixture is a surrogate for biomass fuels which contain significant fuel-bound nitrogen. The experiments use flue-gas sampling to measure the concentration of stable species in the exhaust gas, including NO, O2, CO, and CO2. The computations evolve a two-dimensional low Mach number model using a solution-adaptive projection algorithm to capture fine-scale features of the flame. The model includes detailed thermodynamics and chemical kinetics, differential diffusion, buoyancy, and radiative losses. The model shows good agreement with the measurements over the full range of experimental NH3 seeding amounts. As more NH3 is added, a greater percentage is converted to N2 rather than to NO. The simulation results are further analyzed to trace the changes in NO formation mechanisms with increasing amounts of ammonia in the fuel.

  16. Counterflow diffusion flames of hydrogen, and hydrogen plus methane, ethylene, propane, and silane vs. air - Strain rates at extinction

    Science.gov (United States)

    Pellett, G. L.; Northam, G. Burton; Wilson, L. G.

    1991-01-01

    Five coaxial tubular opposed jet burners (OJBs) with tube diameter D(T) of 1.8-10 mm and 5 mm conical nozzles were used to form dish-shaped counterflow diffusion flames centered by opposing laminar jets of nitrogen and hydrocarbon-diluted H2 versus air in an argon-purged chamber at 1 atm. Area-averaged air jet velocities at blowoff of the central flame, U(air), characterized extinction of the airside flame as functions of input H2 concentration on the fuelside. A master plot of extensive U(air) data at blowoff versus D(T) shows that U(air) varies linearly with D(T). This and other data sets are used to find that nozzle OJB results for U(air)/diameter average 4.24 + or - 0.28 times larger than tubular OJB results for the same fuel compositions. Critical radial velocity gradients consistent with one-dimensional stagnation point boundary theory and with plug flow inputs are estimated. The results compare favorably with published numerical results based only on potential flow.

  17. Formation of carbon nanotubes in counter-flow, oxy-methane diffusion flames without catalysts

    Science.gov (United States)

    Merchan-Merchan, Wilson; Saveliev, Alexei; Kennedy, Lawrence A.; Fridman, Alexander

    2002-03-01

    In oxygen enriched methane diffusion flames, carbon nanotubes were discovered to be formed in the region on the fuel-rich side of the flame front at an oxygen enrichment of 50%. No catalyst was employed. An opposed flow diffusion flames with varying strain rate and oxygen content in the oxidizer stream was used. Substantial quantities of nanotube material are produced at atmospheric pressure in this continuous (non-batch) process. Thermophoretic sampling of the flame and collecting the carbon material deposited near the exhaust was done. Both confirm the growth of carbon nanotubes and other carbon clusters.

  18. Volumetric PIV and 2D OH PLIF imaging in the far-field of a low Reynolds number nonpremixed jet flame

    International Nuclear Information System (INIS)

    Gamba, M; Clemens, N T; Ezekoye, O A

    2013-01-01

    Cinematographic stereoscopic PIV with temporal and spatial resolution ranging from 2.6 to 5.5 Kolmogorov scales, which is sufficient to accurately represent most of the dissipation structures, is used in conjunction with Taylor’s frozen flow hypothesis to generate quasi-instantaneous pseudo-volumes of the three-component velocity field in the far-field of a nonpremixed jet flame at the jet exit Reynolds number (Re d ) of 8000. The 3D data enable the computation of the nine components of the velocity gradient tensor and other important kinematic quantities. The volumetric PIV is combined with single-shot simultaneous OH PLIF imaging to mark the instantaneous reaction zone at one plane in the reconstructed volume. The combined datasets enable the investigation of the relationship between the reaction zone and the fully-3D representations of strain, vorticity, kinetic energy dissipation and dilatation, and of the impact of heat release on the structure of turbulence. In this Re d = 8000 flame, it is observed that sheet-like layers of vorticity and dissipation tend to coincide and are aligned with the OH layers, an effect that is believed to be due to the stabilizing effect of heat release on this relatively low Reynolds number jet flame. Furthermore, the spatial organization of the strain field is predominantly driven by the presence of the flame rather than turbulence. Finally, intense dissipation is mostly due to the laminar shear caused by the presence of the flame rather than to the strain generated by vortical structures as typically observed in nonreacting jets. (paper)

  19. Investigation of the effects of quarl and initial conditions on swirling non-premixed methane flames: Flow field, temperature, and species distributions

    KAUST Repository

    Elbaz, Ayman M.

    2015-12-19

    Detailed measurements are presented of the turbulent flow field, gas species concentrations and temperature field in a non-premixed methane swirl flame. Attention is given to the effect of the quarl geometry on the flame structure and emission characteristics due to its importance in gas turbine and industrial burner applications. Two different quarls were fitted to the burner exit, one a straight quarl and the other a diverging quarl of 15° half cone angle. Stereoscopic Particle Image Velocimetry (SPIV) was applied to obtain the three components of the instantaneous velocity on a vertical plane immediately downstream of the quarl exit. Temperature and gaseous species measurements were made both inside and downstream of the quarls, using a fine wire thermocouple and sampling probe, respectively. This work provides experimental verification by complementary techniques. The results showed that although the main flame structures were governed by the swirl motion imparted to the air stream, the quarl geometry, fuel loading and air loading also had a significant effect on the flow pattern, turbulence intensity, mixture formation, temperature distribution, emissions and flame stabilization. Particularly, in the case of the straight quarl flame, the flow pattern leads to strong, rapid mixing and reduces the residence time for NO formation within the internal recirculation zone (IRZ). However, for the diverging quarl flames, the recirculation zone is shifted radially outward, and the turbulent interaction between the central fuel jet and the internal recirculation zone IRZ induces another small vortex between these two flow features. Less mixing near the diverging quarl exit is observed, with a higher concentration of NO and CO in the post-combustion zone. The instantaneous flow field for both flames showed the existence of small scale vortical structure near the shear layers which were not apparent in the time averaged flow field. These structures, along with high levels

  20. Soot measurements by two angle scattering and extinction in an N 2 -diluted ethylene/air counterflow diffusion flame from 2 to 5 atm

    KAUST Repository

    Amin, Hafiz M.F.

    2016-06-27

    The soot formed in an N-diluted ethylene/air counterflow diffusion flame at elevated pressure was investigated using two angle light scattering/extinction technique. To provide a well-controlled pressurized environment for the flame, a novel pressure vessel was built with the required optical access. The soot parameters were measured along the centerline of the counterflow flame. These properties included soot volume fraction (f ), primary particle diameter (d ), population averaged radius of gyration (R ) and number density of primary particles (n ). The Rayleigh-Debye-Gans theory for Fractal Aggregates (RDG-FA) was used to retrieve these properties from scattering and extinction measurements. Soot volume fraction was measured via light extinction from 2 to 5atm while maintaining the same global strain rate at all pressures. Scattered light from soot particles was measured at 45° and 135° and primary particle diameter was calculated using scattering/extinction ratio and the radius of gyration was determined from the dissymmetry ratio. Soot volume fraction, primary particle diameter and radius of gyration all increased with pressure while the number density of primary particles decreased with increasing pressure.

  1. Extinction Conditions of Non-Premixed Flames with Fine Droplets of Water and Water/NaOH Solutions

    National Research Council Canada - National Science Library

    Lazzarini, A. K; Krauss, R. H; Chelliah, H. K; Linteris, G. T

    2000-01-01

    .... Comparisons of the measured flame extinction condition as a function of droplet mass fraction in the air stream indicate a trend similar to that predicted previously using 20 micrometers monodisperse water droplets...

  2. An experimental study of the stability of natural gas and propane turbulent non-premixed flame under diluting condition

    Directory of Open Access Journals (Sweden)

    Kashir Babak

    2012-01-01

    Full Text Available The stability behavior of a jet diffusion flame developing in a co-flowing stream is studied experimentally, using natural gas and propane as fuel gases. Effects of oxidant and fuel stream velocities and oxidant stream dilution have been studied. The results of experiments showed that with increasing fuel jet Reynolds number, there appears along the flame a point that is accompanied by reaction zone sudden expansion. Flame becomes turbulent downstream from this point. This point is called transition point. More increment of fuel jet Reynolds number moves the transition point to the upstream. Furthermore, two types of stability limits are observed. Blow-off of the rim-stabilized flame is the first stability limit. The second one is the break-off or extinction of the turbulent portion of the flame at the transition point from laminar to turbulent flow. The oxidant and fuel streams are in environmental temperature. In dilution experiments, the oxidant primary stream is oxygen that is diluted with nitrogen or carbon dioxide. In the other experiments oxidant is environmental air.

  3. Experimental and Kinetic Modeling Study of Extinction and Ignition of Methyl Decanoate in Laminar Nonpremixed Flows

    Energy Technology Data Exchange (ETDEWEB)

    Seshadri, K; Lu, T; Herbinet, O; Humer, S; Niemann, U; Pitz, W J; Law, C K

    2008-01-09

    Methyl decanoate is a large methyl ester that can be used as a surrogate for biodiesel. In this experimental and computational study, the combustion of methyl decanoate is investigated in nonpremixed, nonuniform flows. Experiments are performed employing the counterflow configuration with a fuel stream made up of vaporized methyl decanoate and nitrogen, and an oxidizer stream of air. The mass fraction of fuel in the fuel stream is measured as a function of the strain rate at extinction, and critical conditions of ignition are measured in terms of the temperature of the oxidizer stream as a function of the strain rate. It is not possible to use a fully detailed mechanism for methyl decanoate to simulate the counterflow flames because the number of species and reactions is too large to employ with current flame codes and computer resources. Therefore a skeletal mechanism was deduced from a detailed mechanism of 8555 elementary reactions and 3036 species using 'directed relation graph' method. This skeletal mechanism has only 713 elementary reactions and 125 species. Critical conditions of ignition were calculated using this skeletal mechanism and are found to agree well with experimental data. The predicted strain rate at extinction is found to be lower than the measurements. In general, the methyl decanoate mechanism provides a realistic kinetic tool for simulation of biodiesel fuels.

  4. Analysis of turbulence and surface growth models on the estimation of soot level in ethylene non-premixed flames

    Science.gov (United States)

    Yunardi, Y.; Munawar, Edi; Rinaldi, Wahyu; Razali, Asbar; Iskandar, Elwina; Fairweather, M.

    2018-02-01

    Soot prediction in a combustion system has become a subject of attention, as many factors influence its accuracy. An accurate temperature prediction will likely yield better soot predictions, since the inception, growth and destruction of the soot are affected by the temperature. This paper reported the study on the influences of turbulence closure and surface growth models on the prediction of soot levels in turbulent flames. The results demonstrated that a substantial distinction was observed in terms of temperature predictions derived using the k-ɛ and the Reynolds stress models, for the two ethylene flames studied here amongst the four types of surface growth rate model investigated, the assumption of the soot surface growth rate proportional to the particle number density, but independent on the surface area of soot particles, f ( A s ) = ρ N s , yields in closest agreement with the radial data. Without any adjustment to the constants in the surface growth term, other approaches where the surface growth directly proportional to the surface area and square root of surface area, f ( A s ) = A s and f ( A s ) = √ A s , result in an under- prediction of soot volume fraction. These results suggest that predictions of soot volume fraction are sensitive to the modelling of surface growth.

  5. Effects of non-unity Lewis number of gas-phase species in turbulent nonpremixed sooting flames

    KAUST Repository

    Attili, Antonio

    2016-02-13

    Turbulence statistics from two three-dimensional direct numerical simulations of planar n-heptane/air turbulent jets are compared to assess the effect of the gas-phase species diffusion model on flame dynamics and soot formation. The Reynolds number based on the initial jet width and velocity is around 15, 000, corresponding to a Taylor scale Reynolds number in the range 100 ≤ Reλ ≤ 150. In one simulation, multicomponent transport based on a mixture-averaged approach is employed, while in the other the gas-phase species Lewis numbers are set equal to unity. The statistics of temperature and major species obtained with the mixture-averaged formulation are very similar to those in the unity Lewis number case. In both cases, the statistics of temperature are captured with remarkable accuracy by a laminar flamelet model with unity Lewis numbers. On the contrary, a flamelet with a mixture-averaged diffusion model, which corresponds to the model used in the multi-component diffusion three-dimensional DNS, produces significant differences with respect to the DNS results. The total mass of soot precursors decreases by 20-30% with the unity Lewis number approximation, and their distribution is more homogeneous in space and time. Due to the non-linearity of the soot growth rate with respect to the precursors\\' concentration, the soot mass yield decreases by a factor of two. Being strongly affected by coagulation, soot number density is not altered significantly if the unity Lewis number model is used rather than the mixture-averaged diffusion. The dominant role of turbulent transport over differential diffusion effects is expected to become more pronounced for higher Reynolds numbers. © 2016 The Combustion Institute.

  6. Turbulent Non-Premixed Flames Stabilized on Double-Slit Curved Wall-Jet Burner with Simultaneous OH-Planar Laser-Induced Fluorescence and Particle Image Velocimetry Measurements

    KAUST Repository

    Mansour, Morkous S.

    2015-04-29

    A double-slit curved wall-jet (CWJ) burner utilizing a Coanda effect by supplying fuel and air as annular-inward jets over a curved surface was employed to investigate the stabilization characteristics and structure of propane/air turbulent non-premixed flames with varying global equivalence ratio and Reynolds number. Simultaneous time-resolved measurements of particle image velocimetry (PIV) and planar laser-induced fluorescence (PLIF) of OH radicals were conducted. The burner showed a potential of stable and non-sooting operation for relatively large fuel loading and overall rich conditions. Mixing characteristics in cold flow were first examined using an acetone fluorescence technique, indicating substantial transport between the fuel and air by exhibiting appreciable premixing conditions. PIV measurements revealed that the flow field consisted of a wall-jet region leading to a recirculation zone through flow separation, an interaction jet region resulting from the collision of annular-inward jets, followed by a merged-jet region. The flames were stabilized in the recirculation zone and, in extreme cases, only a small flame seed remained in the recirculation zone. Together with the collision of the slit jets in the interaction jet region, the velocity gradients in the shear layers at the boundaries of the annular jets generate the turbulence. Turbulent mean and rms velocities were influenced by the presence of the flame, particularly in the recirculation zone. Flames with a high equivalence ratio were found to be more resistant to local extinction and exhibited a more corrugated and folded nature, particularly at high Reynolds numbers. For flames with a low equivalence ratio, local quenching and re-ignition processes maintained flames in the merged jet region, revealing a strong intermittency, which was substantiated by the increased principal strain rates for these flames. © 2015 Taylor & Francis Group, LLC.

  7. Effect of strain rate on sooting limits in counterflow diffusion flames of gaseous hydrocarbon fuels: Sooting temperature index and sooting sensitivity index

    KAUST Repository

    Wang, Yu

    2014-05-01

    The effect of the strain rate on the sooting limits in counterflow diffusion flames was investigated in various gaseous hydrocarbon fuels by varying the nitrogen dilution in the fuel and oxidizer streams. The sooting limit was defined as the critical fuel and oxygen mole fraction at which soot started to appear in the elastic light scattering signal. The sooting region for normal alkane fuels at a specified strain rate, in terms of the fuel and oxygen mole fraction, expanded as the number of carbon atoms increased. The alkene fuels (ethylene, propene) tested had a higher propensity for sooting as compared with alkane fuels with the same carbon numbers (ethane, propane). Branched iso-butane had a higher propensity for sooting than did n-butane. An increase in the strain rate reduced the tendency for sooting in all the fuels tested. The sensitivity of the sooting limit to the strain rate was more pronounced for less sooting fuels. When plotted in terms of calculated flame temperature, the critical oxygen mole fraction exhibited an Arrhenius form under sooting limit conditions, which can be utilized to significantly reduce the effort required to determine sooting limits at different strain rates. We found that the limiting temperatures of soot formation flames are viable sooting metrics for quantitatively rating the sooting tendency of various fuels, based on comparisons with threshold soot index and normalized smoke point data. We also introduce a sooting temperature index and a sooting sensitivity index, two quantitative measures to describe sooting propensity and its dependence on strain rate. © 2013 The Combustion Institute.

  8. A computational study of soot formation in opposed-flow diffusion flame interacting with vortices

    KAUST Repository

    Selvaraj, Prabhu

    2017-01-05

    The flame-vortex interaction enables the study of basic phenomena that control the coupling between combustion and turbulence. Employing a gas phase reaction mechanism considering polycyclic aromatic hydrocarbons (PAH), a two dimensional counterflow ethylene-air flame is simulated. A reduced mechanism with PAH pathways that includes until coronene and method of moments with interpolative closure (MOMIC) has been employed to calculate the soot characteristics. Interaction of sooting flame with a prescribed decaying random velocity field is being investigated. Counterflow nonpremixed flames at low strain rate sooting conditions are considered. Effects of vortices are studied on the flame structures and its sensitivity on the soot formation characteristics. As the vortex rolls up the flame, integrated soot volume fraction is found to be larger for the air-side vortex. A detailed analysis on the flame structure and its influence on the formation of soot were carried out. The results indicate that the larger PAH species contributes to the soot formation in the airside perturbation regimes, whereas the soot formation is dominated by the soot transport in fuel-side perturbation.

  9. Comprehensive Validation of Skeletal Mechanism for Turbulent Premixed Methane–Air Flame Simulations

    KAUST Repository

    Luca, Stefano

    2017-08-01

    A new skeletal mechanism, consisting of 16 species and 72 reactions, has been developed for lean methane–air premixed combustion from the GRI-Mech 3.0. The skeletal mechanism is validated for elevated unburnt temperatures (800 K) and pressures up to 4 atm, thereby addressing realistic gas turbine conditions. The skeletal mechanism is obtained by applying the directed relation graph method and performing sensitivity analysis on the detailed mechanism. The mechanism has been validated for flame speed and flame structure in a wide range of conditions and configurations. A good agreement between the skeletal mechanism and GRI-3.0 was obtained. The configurations considered include one-dimension laminar premixed flames, laminar non-premixed counterflow burners, and two- and three-dimensional unsteady configurations with variations of temperature, pressure, and composition. The skeletal mechanism allows for the inclusion of accurate finite rate chemistry in large-scale direct numerical simulations of lean turbulent premixed flames. In a large-scale direct numerical simulation, the use of the skeletal mechanism reduces the memory requirements by more than a factor of 3 and accelerates the simulation by a factor of 7 compared with the detailed mechanism. The skeletal mechanism is suitable for unsteady three-dimensional simulations of methane turbulent premixed, non-premixed, and globally lean partially premixed flames and is available as supplementary material.

  10. The i-V curve characteristics of burner-stabilized premixed flames: detailed and reduced models

    KAUST Repository

    Han, Jie

    2016-07-17

    The i-V curve describes the current drawn from a flame as a function of the voltage difference applied across the reaction zone. Since combustion diagnostics and flame control strategies based on electric fields depend on the amount of current drawn from flames, there is significant interest in modeling and understanding i-V curves. We implement and apply a detailed model for the simulation of the production and transport of ions and electrons in one-dimensional premixed flames. An analytical reduced model is developed based on the detailed one, and analytical expressions are used to gain insight into the characteristics of the i-Vcurve for various flame configurations. In order for the reduced model to capture the spatial distribution of the electric field accurately, the concept of a dead zone region, where voltage is constant, is introduced, and a suitable closure for the spatial extent of the dead zone is proposed and validated. The results from the reduced modeling framework are found to be in good agreement with those from the detailed simulations. The saturation voltage is found to depend significantly on the flame location relative to the electrodes, and on the sign of the voltage difference applied. Furthermore, at sub-saturation conditions, the current is shown to increase linearly or quadratically with the applied voltage, depending on the flame location. These limiting behaviors exhibited by the reduced model elucidate the features of i-V curves observed experimentally. The reduced model relies on the existence of a thin layer where charges are produced, corresponding to the reaction zone of a flame. Consequently, the analytical model we propose is not limited to the study of premixed flames, and may be applied easily to others configurations, e.g.~nonpremixed counterflow flames.

  11. Effects of substitution on counterflow ignition and extinction of C3 and C4 alcohols

    KAUST Repository

    Alfazazi, Adamu

    2016-06-17

    Dwindling reserves and inherent uncertainty in the price of conventional fuels necessitates a search for alternative fuels. Alcohols represent a potential source of energy for the future. The structural features of an alcohol fuel have a direct impact on combustion properties. In particular, substitution in alcohols can alter the global combustion reactivity. In this study, experiments and numerical simulations were conducted to investigate the critical conditions of extinction and autoignition of n-propanol, 1-butanol, iso-propanol and iso-butanol in non-premixed diffusion flames. Experiments were carried out in the counterflow configuration, while simulations were conducted using a skeletal chemical kinetic model for the C3 and C4 alcohols. The fuel stream consists of the pre-vaporized fuel diluted with nitrogen, while the oxidizer stream is air. The experimental results show that autoignition temperatures of the tested alcohols increase in the following order: iso-propanol > iso-butanol > 1-butanol ≈ n-propanol. The simulated results for the branched alcohols agree with the experiments, while the autoignition temperature of 1-butanol is slightly higher than that of n-propanol. For extinction, the experiments show that the extinction limits of the tested fuels increase in the following order: n-propanol ≈ 1-butanol > iso-butanol > iso-propanol. The model suggests that the extinction limits of 1-butanol is slightly higher than n-propanol with extinction strain rate of iso-butanol and iso-propanol maintaining the experimentally observed trend. The transport weighted enthalpy (TWE) and radical index (Ri) concepts were utilized to rationalize the observed reactivity trends for these fuels.

  12. A computational study of ethylene–air sooting flames: Effects of large polycyclic aromatic hydrocarbons

    KAUST Repository

    Selvaraj, Prabhu

    2015-11-05

    An updated reduced gas-phase kinetic mechanism was developed and integrated with aerosol models to predict soot formation characteristics in ethylene nonpremixed and premixed flames. A primary objective is to investigate the sensitivity of the soot formation to various chemical pathways for large polycyclic aromatic hydrocarbons (PAH). The gas-phase chemical mechanism adopted the KAUST-Aramco PAH Mech 1.0, which utilized the AramcoMech 1.3 for gas-phase reactions validated for up to C2 fuels. In addition, PAH species up to coronene (C24H12 or A7) were included to describe the detailed formation pathways of soot precursors. In this study, the detailed chemical mechanism was reduced from 397 to 99 species using directed relation graph with expert knowledge (DRG-X) and sensitivity analysis. The method of moments with interpolative closure (MOMIC) was employed for the soot aerosol model. Counterflow nonpremixed flames at low strain rate sooting conditions were considered, for which the sensitivity of soot formation characteristics to different nucleation pathways were investigated. Premixed flame experiment data at different equivalence ratios were also used for validation. The findings show that higher PAH concentrations result in a higher soot nucleation rate, and that the total soot volume and average size of the particles are predicted in good agreement with experimental results. Subsequently, the effects of different pathways, with respect to pyrene- or coronene-based nucleation models, on the net soot formation rate were analyzed. It was found that the nucleation processes (i.e., soot inception) are sensitive to the choice of PAH precursors, and consideration of higher PAH species beyond pyrene is critical for accurate prediction of the overall soot formation.

  13. Counterflow Regolith Heat Exchanger

    Science.gov (United States)

    Zubrin, Robert; Jonscher, Peter

    2013-01-01

    A problem exists in reducing the total heating power required to extract oxygen from lunar regolith. All such processes require heating a great deal of soil, and the heat energy is wasted if it cannot be recycled from processed material back into new material. The counterflow regolith heat exchanger (CoRHE) is a device that transfers heat from hot regolith to cold regolith. The CoRHE is essentially a tube-in-tube heat exchanger with internal and external augers attached to the inner rotating tube to move the regolith. Hot regolith in the outer tube is moved in one direction by a right-hand - ed auger, and the cool regolith in the inner tube is moved in the opposite direction by a left-handed auger attached to the inside of the rotating tube. In this counterflow arrangement, a large fraction of the heat from the expended regolith is transferred to the new regolith. The spent regolith leaves the heat exchanger close to the temperature of the cold new regolith, and the new regolith is pre-heated close to the initial temperature of the spent regolith. Using the CoRHE can reduce the heating requirement of a lunar ISRU system by 80%, reducing the total power consumption by a factor of two. The unique feature of this system is that it allows for counterflow heat exchange to occur between solids, instead of liquids or gases, as is commonly done. In addition, in variants of this concept, the hydrogen reduction can be made to occur within the counterflow heat exchanger itself, enabling a simplified lunar ISRU (in situ resource utilization) system with excellent energy economy and continuous nonbatch mode operation.

  14. Conditional budgets of second-order statistics in nonpremixed and premixed turbulent combustion

    Science.gov (United States)

    Macart, Jonathan F.; Grenga, Temistocle; Mueller, Michael E.

    2016-11-01

    Combustion heat release modifies or introduces a number of new terms to the balance equations for second-order turbulence statistics (turbulent kinetic energy, scalar variance, etc.) compared to incompressible flow. A major modification is a significant increase in viscosity and dissipation in the high-temperature combustion products, but new terms also appear due to density variation and gas expansion (dilatation). Previous scaling analyses have hypothesized that dilatation effects are important in turbulent premixed combustion but are unimportant in turbulent nonpremixed combustion. To explore this hypothesis, a series of DNS calculations have been performed in the low Mach number limit for spatially evolving turbulent planar jet flames of hydrogen and air in both premixed and nonpremixed configurations. Unlike other studies exploring the effects of heat release on turbulence, the turbulence is not forced, and detailed chemical kinetics are used to describe hydrogen-air combustion. Budgets for second-order statistics are computed conditioned on progress variable in the premixed flame and on mixture fraction in the nonpremixed flame in order to locate regions with respect to the flame structure where dilatation effects are strongest.

  15. Turbulent jet in confined counterflow

    Indian Academy of Sciences (India)

    However, in many engineering applications the jet does not issue into a quies- cent stream but interacts with an external stream. This interaction can be classified as co-flow, crossflow or counterflow depending on the direction of interaction between the jet and the exter- nal stream. Of these interactions, the jet in counterflow ...

  16. Turbulent jet in confined counterflow

    Indian Academy of Sciences (India)

    Abstract. The mean flowfield of a turbulent jet issuing into a confined, uniform counterflow was investigated computationally. Based on dimensional analysis, the jet penetration length was shown to scale with jet-to-counterflow momentum flux ratio. This scaling and the computational results reproduce the well-known correct ...

  17. Turbulent jet in confined counterflow

    Indian Academy of Sciences (India)

    The mean flowfield of a turbulent jet issuing into a confined, uniform counterflow was investigated computationally. Based on dimensional analysis, the jet penetration length was shown to scale with jet-to-counterflow momentum flux ratio. This scaling and the computational results reproduce the well-known correct limit of ...

  18. Counterflow Regolith Heat Exchanger Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The counterflow regolith heat exchanger (CoRHE) is a device that transfers heat from hot regolith to cold regolith. The CoRHE is essentially a tube-in-tube heat...

  19. FORMATION OF POLYCYCLIC AROMATIC HYDROCARBONS IN AN ATMOSPHERIC PRESSURE ETHYLENE DIFFUSION FLAME. (R825412)

    Science.gov (United States)

    AbstractThe microstructure of an atmospheric pressure, counterflow, sooting, flat, laminar ethylene diffusion flame has been studied experimentally by withdrawing samples from within the flame using a heated quartz microprobe coupled to an online gas chromatograph/mas...

  20. Numerical investigation of biogas diffusion flames characteristics under several operation conditions in counter-flow configuration with an emphasis on thermal and chemical effects of CO2 in the fuel mixture

    Science.gov (United States)

    Mameri, A.; Tabet, F.; Hadef, A.

    2017-08-01

    This study addresses the influence of several operating conditions (composition and ambient pressure) on biogas diffusion flame structure and NO emissions with particular attention on thermal and chemical effect of CO2. The biogas flame is modeled by a counter flow diffusion flame and analyzed in mixture fraction space using flamelet approach. The GRI Mech-3.0 mechanism that involves 53 species and 325 reactions is adopted for the oxidation chemistry. It has been observed that flame properties are very sensitive to biogas composition and pressure. CO2 addition decreases flame temperature by both thermal and chemical effects. Added CO2 may participate in chemical reaction due to thermal dissociation (chemical effect). Excessively supplied CO2 plays the role of pure diluent (thermal effect). The ambient pressure rise increases temperature and reduces flame thickness, radiation losses and dissociation amount. At high pressure, recombination reactions coupled with chain carrier radicals reduction, diminishes NO mass fraction.

  1. Visualization of ionic wind in laminar jet flames

    KAUST Repository

    Park, Daegeun

    2017-07-03

    Electric field, when it is applied to hydrocarbon flames, generates ionic wind due to the electric body force on charge carrying species. Ionic wind has been shown to influence soot emission, propagation speed, and stability of flames; however, a detailed behavior of ionic wind and its effects on flames is still not clear. Here, we investigated the dynamic behaviors of flames and ionic wind in the presence of direct current (DC) and alternating current (AC) electric fields in nonpremixed and premixed jet flames with a jet nozzle placed between two parallel electrodes. We observed a skewed flame toward a lower potential electrode with DC and lower frequency AC (e.g., 10Hz) and a steady flame with higher frequencies AC (1000Hz), while we found that the ionic wind blew toward both the anode and cathode regardless of flame type (nonpremixed or premixed) or the source of the electric field (DC and AC).

  2. Development of a Spherical Combustion Chamber for Measuring Laminar Flame Speeds in Navy Bulk Fuels and Biofuel Blends

    Science.gov (United States)

    2011-12-01

    to measure flame speeds as discussed by Kuo et al. [5], each utilizing different flame configurations, such as the spherical flame method, Bunsen ... burner method, counterflow method, the flat-flame burner method and the transparent-tube method. Depending on the pressure, the spherical flame

  3. A parallel adaptive mesh refinement algorithm for predicting turbulent non-premixed combusting flows

    International Nuclear Information System (INIS)

    Gao, X.; Groth, C.P.T.

    2005-01-01

    A parallel adaptive mesh refinement (AMR) algorithm is proposed for predicting turbulent non-premixed combusting flows characteristic of gas turbine engine combustors. The Favre-averaged Navier-Stokes equations governing mixture and species transport for a reactive mixture of thermally perfect gases in two dimensions, the two transport equations of the κ-ψ turbulence model, and the time-averaged species transport equations, are all solved using a fully coupled finite-volume formulation. A flexible block-based hierarchical data structure is used to maintain the connectivity of the solution blocks in the multi-block mesh and facilitate automatic solution-directed mesh adaptation according to physics-based refinement criteria. This AMR approach allows for anisotropic mesh refinement and the block-based data structure readily permits efficient and scalable implementations of the algorithm on multi-processor architectures. Numerical results for turbulent non-premixed diffusion flames, including cold- and hot-flow predictions for a bluff body burner, are described and compared to available experimental data. The numerical results demonstrate the validity and potential of the parallel AMR approach for predicting complex non-premixed turbulent combusting flows. (author)

  4. Two- and Three-Dimensional Measurements in Turbulent Nonpremixed Flames

    National Research Council Canada - National Science Library

    Long, Marshall

    2000-01-01

    ... and fuel Raman scattering. These experiments showed that proper parameterization of mixture fraction-dependent terms appearing in the expression for mixture fraction can improve accuracy for lean values of mixture fraction...

  5. Effects of mesh type on a non-premixed model in a flameless combustion simulation

    Science.gov (United States)

    Komonhirun, Seekharin; Yongyingsakthavorn, Pisit; Nontakeaw, Udomkiat

    2018-01-01

    Flameless combustion is a recently developed combustion system, which provides zero emission product. This phenomenon requires auto-ignition by supplying high-temperature air with low oxygen concentration. The flame is vanished and colorless. Temperature of the flameless combustion is less than that of a conventional case, where NOx reactions can be well suppressed. To design a flameless combustor, the computational fluid dynamics (CFD) is employed. The designed air-and-fuel injection method can be applied with the turbulent and non-premixed models. Due to the fact that nature of turbulent non-premixed combustion is based on molecular randomness, inappropriate mesh type can lead to significant numerical errors. Therefore, this research aims to numerically investigate the effects of mesh type on flameless combustion characteristics, which is a primary step of design process. Different meshes, i.e. tetrahedral, hexagonal are selected. Boundary conditions are 5% of oxygen and 900 K of air-inlet temperature for the flameless combustion, and 21% of oxygen and 300 K of air-inlet temperature for the conventional case. The results are finally presented and discussed in terms of velocity streamlines, and contours of turbulent kinetic energy and viscosity, temperature, and combustion products.

  6. Large eddy simulation of premixed and non-premixed combustion in a Stagnation Point Reverse Flow combustor

    Science.gov (United States)

    Undapalli, Satish

    A new combustor referred to as Stagnation Point Reverse Flow (SPRF) combustor has been developed at Georgia Tech to meet the increasingly stringent emission regulations. The combustor incorporates a novel design to meet the conflicting requirements of low pollution and high stability in both premixed and non-premixed modes. The objective of this thesis work is to perform Large Eddy Simulations (LES) on this lab-scale combustor and elucidate the underlying physics that has resulted in its excellent performance. To achieve this, numerical simulations have been performed in both the premixed and non-premixed combustion modes, and velocity field, species field, entrainment characteristics, flame structure, emissions, and mixing characteristics have been analyzed. Simulations have been carried out first for a non-reactive case to resolve relevant fluid mechanics without heat release by the computational grid. The computed mean and RMS quantities in the non-reacting case compared well with the experimental data. Next, the simulations were extended for the premixed reactive case by employing different sub-grid scale combustion chemistry closures: Eddy Break Up (EBU), Artificially Thickened Flame (TF) and Linear Eddy Mixing (LEM) models. Results from the EBU and TF models exhibit reasonable agreement with the experimental velocity field. However, the computed thermal and species fields have noticeable discrepancies. Only LEM with LES (LEMLES), which is an advanced scalar approach, has been able to accurately predict both the velocity and species fields. Scalar mixing plays an important role in combustion, and this is solved directly at the sub-grid scales in LEM. As a result, LEM accurately predicts the scalar fields. Due to the two way coupling between the super-grid and sub-grid quantities, the velocity predictions also compare very well with the experiments. In other approaches, the sub-grid effects have been either modeled using conventional approaches (EBU) or need

  7. Physical and Chemical Processes in Flames

    Science.gov (United States)

    2010-02-15

    turbulent slot- burner Bunsen flame [20]. The simulation is performed for three flow- through times, long enough to achieve statistical stationarity. The...constants. Compared with previous fitting formulas, notably that by Troe (Troe, J Ber Bunsen -Ges Phys Chern 87, 161 , 1983), the present expression...extinction and ignition of methyl decanoate in laminar nonpremixed flows," by K. Seshadri, T. F. Lu, 0 . Herbinet, S. Burner , U. Niemann, W. J. Pitz and C

  8. Active Control of High Speed Jet Flames Using Counterflow

    National Research Council Canada - National Science Library

    Krothapalli, Anjaneyulu

    2003-01-01

    .... An optical temperature measurement technique, refereed to as Laser Speckle Displacement (LSD) was developed for instantaneous temperature field measurements. It is shown that the technique is easy to implement and can be used in conjunction with PIV for simultaneous velocity and temperature measurements in reacting flows.

  9. Behaviors of tribrachial edge flames and their interactions in a triple-port burner

    KAUST Repository

    Yamamoto, Kazuhiro

    2015-05-01

    In a triple-port burner, various non-premixed flames have been observed previously. Especially for the case with two lifted flames, such configuration could be suitable in studying interaction between two tribrachial flames. In the present study, the flame characteristics have been investigated numerically by adopting a reduced kinetic mechanism in the triple-port burner. Four different types of flame configurations, including two attached flames, inner lifted/outer attached flames, inner attached/outer lifted flames, and twin lifted flames, were successfully simulated depending on the flow conditions. The representative edge propagation speed of a single lifted flame or an upstream lifted flame in the case of twin lifted flames increased as the liftoff height became higher. In the twin lifted flames, the inner lifted flame was affected appreciably when the other flame was located further upstream such that the lifted flame located further downstream encountered the axial velocity acceleration induced by the gas expansion from the lifted flame located upstream, while thermal effects were not observed since the temperature of the incoming flow toward the lifted flame was not affected. A unique flip-flop behavior between the inner and outer flames, observed experimentally previously, was successfully captured in the simulation such that the inner lifted flame became attached to the nozzle as the liftoff height of the outer lifted flame grew higher with an increase in the outer air velocity.

  10. Tomographic PIV measurements in a turbulent lifted jet flame

    Science.gov (United States)

    Weinkauff, J.; Michaelis, D.; Dreizler, A.; Böhm, B.

    2013-12-01

    Measurements of instantaneous volumetric flow fields are required for an improved understanding of turbulent flames. In non-reacting flows, tomographic particle image velocimetry (TPIV) is an established method for three-dimensional (3D) flow measurements. In flames, the reconstruction of the particles location becomes challenging due to a locally varying index of refraction causing beam-steering. This work presents TPIV measurements within a turbulent lifted non-premixed methane jet flame. Solid seeding particles were used to provide the 3D flow field in the vicinity of the flame base, including unburned and burned regions. Four cameras were arranged in a horizontal plane around the jet flame. Following an iterative volumetric self-calibration procedure, the remaining disparity caused by the flame was less than 0.2 pixels. Comparisons with conventional two-component PIV in terms of mean and rms values provided additional confidence in the TPIV measurements.

  11. Optical investigation of gas-phase KCl/KOH sulfation in post flame conditions

    DEFF Research Database (Denmark)

    Weng, Wubin; chen, Shuang; Wu, Hao

    2018-01-01

    A counter-flow reactor setup was designed to investigate the gas-phase sulfation and homogeneous nucleation of potassium salts. Gaseous KOH and KCl were introduced into the post-flame zone of a laminar flat flame. The hot flame products mixed in the counter-flow with cold N2, with or without....... Depending on the potassium speciation in the inlet and the presence of SO2, they consisted of K2SO4, KCl, or K2CO3, respectively. The experiments showed that KOH was sulphated more readily than KCl, resulting in larger quantities of aerosols. The sulfation process in the counter-flow setup was simulated...... using a chemical kinetic model including a detailed subset for the Cl/S/K chemistry. Similar to the experimental results, much more potassium sulfate was predicted when seeding KOH compared to seeding KCl. For both KOH and KCl, sulfation was predicted to occur primarily through the reactions among...

  12. CSP-based chemical kinetics mechanisms simplification strategy for non-premixed combustion: An application to hybrid rocket propulsion

    KAUST Repository

    Ciottoli, Pietro P.

    2017-08-14

    A set of simplified chemical kinetics mechanisms for hybrid rocket applications using gaseous oxygen (GOX) and hydroxyl-terminated polybutadiene (HTPB) is proposed. The starting point is a 561-species, 2538-reactions, detailed chemical kinetics mechanism for hydrocarbon combustion. This mechanism is used for predictions of the oxidation of butadiene, the primary HTPB pyrolysis product. A Computational Singular Perturbation (CSP) based simplification strategy for non-premixed combustion is proposed. The simplification algorithm is fed with the steady-solutions of classical flamelet equations, these being representative of the non-premixed nature of the combustion processes characterizing a hybrid rocket combustion chamber. The adopted flamelet steady-state solutions are obtained employing pure butadiene and gaseous oxygen as fuel and oxidizer boundary conditions, respectively, for a range of imposed values of strain rate and background pressure. Three simplified chemical mechanisms, each comprising less than 20 species, are obtained for three different pressure values, 3, 17, and 36 bar, selected in accordance with an experimental test campaign of lab-scale hybrid rocket static firings. Finally, a comprehensive strategy is shown to provide simplified mechanisms capable of reproducing the main flame features in the whole pressure range considered.

  13. Computatonal and experimental study of laminar flames

    Energy Technology Data Exchange (ETDEWEB)

    Smooke, M.D.; Long, M.B. [Yale Univ., New Haven, CT (United States)

    1993-12-01

    This research has centered on an investigation of the effects of complex chemistry and detailed transport on the structure and extinction of hydrocarbon flames in counterflow, cylindrical and coflowing axisymmetric configurations. The authors have pursued both computational and experimental aspects of the research in parallel. The computational work has focused on the application of accurate and efficient numerical methods for the solution of the one and two-dimensional nonlinear boundary value problems describing the various reacting systems. Detailed experimental measurements were performed on axisymmetric coflow flames using two-dimensional imaging techniques. In particular, spontaneous Raman scattering and laser induced fluorescence were used to measure the temperature, major and minor species profiles.

  14. Effects of Structure and Hydrodynamics on the Sooting Behavior of Spherical Microgravity Diffusion Flames

    Science.gov (United States)

    Sunderland, P. B.; Axelbaum, R. L.; Urban, D. L.

    1999-01-01

    Recent experimental, numerical and analytical work has shown that the stoichiometric mixture fraction (Z(sub st)) can have a profound effect on soot formation in diffusion flames. These findings were obtained at constant flame temperature (T(sub ad)), employing the approach described in Du and Axelbaum (1995, 1996). For example, a fuel mixture containing 1 mole of ethylene and 11.28 moles of nitrogen burning in pure oxygen ((Z(sub st)) = 0.78) has the same adiabatic flame temperature (2370 K) as that of pure ethylene burning in air ((Z(sub st)) = 0.064). An important finding of these works was that at sufficiently high (Z(sub st)), flames remain blue as strain rate approaches zero in counterflow flames, or as flame height and residence time approach infinity in coflowing flames. Lin and Faeth (1996a) coined the term permanently blue to describe such flames. Two theories have been proposed to explain the appearance of permanently-blue flames at high (Z(sub st)). They are based on (1) hydrodynamics and (2) flame structure. Previous experimental studies in normal gravity are not definitive as to which, if either, mechanism is dominant because both hydrodynamics and structure suppress soot formation at high (Z(sub st)) in coflowing and counterflowing diffusion flames. In counterflow flames with (Z(sub st)) 0.5, convection at the flame is toward the oxidizer, thus enhancing soot oxidization. Thus, in counterflow flames, hydrodynamics causes soot to be convected towards the oxidizer at high (Z(sub st)) which suppresses soot formation. Axelbaum and co-workers maintain that while the direction of convection can impact soot growth and oxidation, these processes alone cannot cause permanently-blue flames. Soot growth and oxidation are dependent on the existence of soot particles and the presence of soot is invariably accompanied by yellow luminosity. Soot-particle inception, on the other hand, arises from gas-phase reactions and its dependence on flow direction is weak

  15. Numerical solution of an edge flame boundary value problem

    Science.gov (United States)

    Shields, Benjamin; Freund, Jonathan; Pantano, Carlos

    2016-11-01

    We study edge flames for modeling extinction, reignition, and flame lifting in turbulent non-premixed combustion. An adaptive resolution finite element method is developed for solving a strained laminar edge flame in the intrinsic moving frame of reference of a spatially evolving shear layer. The variable-density zero Mach Navier-Stokes equations are used to solve for both advancing and retreating edge flames. The eigenvalues of the system are determined simultaneously (implicitly) with the scalar fields using a Schur complement strategy. A homotopy transformation over density is used to transition from constant- to variable-density, and pseudo arc-length continuation is used for parametric tracing of solutions. Full details of the edge flames as a function of strain and Lewis numbers will be discussed. This material is based upon work supported [in part] by the Department of Energy, National Nuclear Security Administration, under Award Number DE-NA0002374.

  16. The Effects of Flame Structure on Extinction of CH4-O2-N2 Diffusion Flames

    Science.gov (United States)

    Du, J.; Axelbaum, R. L.; Gokoglu, S. (Technical Monitor)

    1996-01-01

    The effects of flame structure on the extinction limits of CH4-O2-N2 counterflow diffusion flames were investigated experimentally and numerically by varying the stoichiometric mixture fraction Z(sub st), Z(sub st) was varied by varying free-stream concentrations, while the adiabatic flame temperature T(sub ad) was held fixed by maintaining a fixed amount of nitrogen at the flame. Z(sub st) was varied between 0.055 (methane-air flame) and 0.78 (diluted- methane-oxygen flame). The experimental results yielded an extinction strain rate K(sub ext) of 375/s for the methane-air flame, increasing monotonically to 1042/s for the diluted-methane-oxygen flame. Numerical results with a 58-step Cl mechanism yielded 494/s and 1488/s, respectively. The increase in K(sub ext) with Z(sub st) for a fixed T(sub ad) is explained by the shift in the O2 profile toward the region of maximum temperature and the subsequent increase in rates for chain-branching reactions. The flame temperature at extinction reached a minimum at Z(sub st) = 0.65, where it was 200 C lower than that of the methane-air flame. This significant increase in resistance to extinction is seen to correspond to the condition in which the OH and O production zones are centered on the location of maximum temperature.

  17. Experimental characterization of onset of acoustic instability in a nonpremixed half-dump combustor.

    Science.gov (United States)

    Chakravarthy, Satyanarayanan R; Shreenivasan, Obla J; Boehm, Benjamin; Dreizler, Andreas; Janicka, Johannes

    2007-07-01

    This paper reports work on a nonpremixed half-dump combustor, in which methane is injected at the backward-facing step, and mixes and burns with the air flowing past the step in the unsteady recirculation zone. The flow and geometric parameters are widely varied, to gradually change from conditions of low-amplitude noise to excitation of high-amplitude discrete tones. The purpose of the work is to focus on the transition from the former condition to the latter, and to mark the onset of instability. Dimensionless groups such as the Helmholtz and Strouhal numbers are formed based on the observed dominant frequencies, whose variation with the air flow Reynolds number is used to identify the oscillations as those due to the natural acoustic modes or the vortex shedding process. High-speed chemiluminescence imaging reveals shedding of vortical structures in the flame zone. With variation in the conditions, flow-acoustic lock-on and transition from one vortex shedding mode to another is marked by nonlinearity in the corresponding amplitude variations. Such conditions are identified as the onset of instability in terms of the ratio of the flow time scale to the acoustic time scale and mapped against the operating fuel-air equivalence ratio of the combustor.

  18. Numerical simulation of autoigniting flames

    Science.gov (United States)

    Asaithambi, Rajapandiyan; Mahesh, Krishnan

    2012-11-01

    Autoignition is highly sensitive to temperature and mixing. A density based method for DNS/LES of compressible chemically reacting flows is proposed with an explicit predictor step for advection and diffusion terms, and a semi-implicit corrector step for stiff chemical source terms. This segregated approach permits independent modification of the Navier-Stokes solver and the time integration algorithm for the chemical source term. The algorithm solves the total chemical and sensible energy equation and heat capacities of species are obtained from thermodynamic tables. Chemical mechanisms in the Chemkin format is parsed and source terms are automatically linearized allowing the ability to simulate multiple fuels with minimal effort. Validation of the algorithm is presented and results from autoigniting non-premixed flames in vitiated coflow with different fuels are discussed.

  19. PIV Measurements of He II Counterflow Around a Cylinder

    International Nuclear Information System (INIS)

    Fuzier, S.; Van Stiver, S. W.; Zhang, T.

    2006-01-01

    The induced flow field of counterflow He II across a circular cylinder has been quantitatively studied using the particle image velocimetry (PIV) technique. Two different size cylinders (6.35 mm and 2 mm in diameter) were used and placed in a 20 mm wide rectangular channel. In these experiments, large-scale eddy motion generated by the He II counterflow was observed both in front of and behind the cylinder, an effect which has no analogue in classical fluids

  20. Numerical assessment of accurate measurements of laminar flame speed

    Science.gov (United States)

    Goulier, Joules; Bizon, Katarzyna; Chaumeix, Nabiha; Meynet, Nicolas; Continillo, Gaetano

    2016-12-01

    In combustion, the laminar flame speed constitutes an important parameter that reflects the chemistry of oxidation for a given fuel, along with its transport and thermal properties. Laminar flame speeds are used (i) in turbulent models used in CFD codes, and (ii) to validate detailed or reduced mechanisms, often derived from studies using ideal reactors and in diluted conditions as in jet stirred reactors and in shock tubes. End-users of such mechanisms need to have an assessment of their capability to predict the correct heat released by combustion in realistic conditions. In this view, the laminar flame speed constitutes a very convenient parameter, and it is then very important to have a good knowledge of the experimental errors involved with its determination. Stationary configurations (Bunsen burners, counter-flow flames, heat flux burners) or moving flames (tubes, spherical vessel, soap bubble) can be used. The spherical expanding flame configuration has recently become popular, since it can be used at high pressures and temperatures. With this method, the flame speed is not measured directly, but derived through the recording of the flame radius. The method used to process the radius history will have an impact on the estimated flame speed. Aim of this work is to propose a way to derive the laminar flame speed from experimental recording of expanding flames, and to assess the error magnitude.

  1. On the dynamics of flame edges in diffusion-flame/vortex interactions

    Energy Technology Data Exchange (ETDEWEB)

    Hermanns, Miguel; Linan, Amable [Departamento de Motopropulsion y Termofluidodinamica, Universidad Politecnica de Madrid, Pza. Cardenal Cisneros 3, 28040 Madrid (Spain); Vera, Marcos [Area de Mecanica de Fluidos, Universidad Carlos III de Madrid, 28911 Leganes (Spain)

    2007-04-15

    We analyze the local flame extinction and reignition of a counterflow diffusion flame perturbed by a laminar vortex ring. Local flame extinction leads to the appearance of flame edges separating the burning and extinguished regions of the distorted mixing layer. The dynamics of these edges is modeled based on previous numerical results, with heat release effects fully taken into account, which provide the propagation velocity of triple and edge flames in terms of the upstream unperturbed value of the scalar dissipation. The temporal evolution of the mixing layer is determined using the classical mixture fraction approach, with both unsteady and curvature effects taken into account. Although variable density effects play an important role in exothermic reacting mixing layers, in this paper the description of the mixing layer is carried out using the constant density approximation, leading to a simplified analytical description of the flow field. The mathematical model reveals the relevant nondimensional parameters governing diffusion-flame/vortex interactions and provides the parameter range for the more relevant regime of local flame extinction followed by reignition via flame edges. Despite the simplicity of the model, the results show very good agreement with previously published experimental results. (author)

  2. Experiment and Simulation of Autoignition in Jet Flames and its Relevance to Flame Stabilization and Structure

    KAUST Repository

    Al-Noman, Saeed M.

    2016-06-01

    mainly between the fuel nozzle and the lifted flame edge. On the other hand, they were formed just prior to the flame edge for the non-autoignited lifted flames. The effect of fuel pyrolysis and partial oxidation were found to be important in explaining autoignited liftoff heights, especially in the Mild combustion regime. Flame structures of autoignited flames were investigated numerically for syngas (CO/H2) and methane fuels. The simulations of syngas fuel accounting for the differential diffusion have been performed by adopting several kinetic mechanisms to test the models ability in predicting the flame behaviors observed previously. The results agreed well with the observed nozzle-attached flame characteristics in case of non-autoignited flames. For autoignited lifted flames in high temperature regime, a unique autoignition behavior can be predicted having HO2 and H2O2 radicals in a broad region between the nozzle and stabilized lifted flame edge. Autoignition characteristics of laminar nonpremixed methane jet flames in high- temperature coflow air were studied numerically. Several flame configurations were investigated by varying the initial temperature and fuel mole fraction. Characteristics of chemical kinetics structures for autoignited lifted flames were discussed based on the kinetic structures of homogeneous autoignition and flame propagation of premixed mixtures. Results showed that for autoignited lifted flame with tribrachial structure, a transition from autoignition to flame propagation modes occurs for reasonably stoichiometric mixtures. Characteristics of Mild combustion can be treated as an autoignited lean premixed lifted flame. Transition behavior from Mild combustion to a nozzle-attached flame was also investigated by increasing the fuel mole fraction.

  3. A Numerical Study on Effect of Gas-Phase Radiative Heat Loss on Extinction of Hydrogen Diffusion Flames

    International Nuclear Information System (INIS)

    Sohn, Chae Hoon

    2007-01-01

    Extinction characteristics of hydrogen-air diffusion flames are investigated numerically by adopting counterflow flame configuration. At various pressures, effect of radiative heat loss on flame extinction is examined. Only gas-phase radiation is considered here. Radiative heat loss depends on flame thickness, temperature, H 2 O concentration, and pressure. From flame structures at various pressures, flame thickness decreases with pressure, but its gradient decreases at high pressure. Flame temperature and mole fraction of H 2 O increase slightly with pressure. Accordingly, as pressure increases, radiative heat loss becomes dominant. When radiative heat loss is considered, radiation-induced extinction is observed at low strain rate in addition to transport-induced extinction. As pressure increases, flammable region shifts to the high-temperature region and then, shrunk to the point on the coordinate plane of flame temperature and strain rate

  4. Influence of Pilot Flame Parameters on the Stability of Turbulent Jet Flames

    KAUST Repository

    Guiberti, Thibault F.

    2016-11-08

    This paper presents a comprehensive study of the effects of pilot parameters on flame stability in a turbulent jet flame. The Sydney inhomogeneous piloted burner is employed as the experimental platform with two main fuels, namely, compressed natural gas and liquefied petroleum gas. Various concentrations of five gases are used in the pilot stream, hydrogen, acetylene, oxygen, nitrogen, and argon, to enable a sufficient range in exploring the following parameters: pilot heat release, temperature, burnt gas velocity, equivalence ratio, and H/C ratio. The experimental results are mainly presented in the form of blow-off limits and supported by simple calculations, which simulate various conditions of the pilot–mixture interface. It is found that increasing the pilot adiabatic flame temperature benefits the flame stability and has an even greater influence than the heat release, which is also known to enhance the blow-off limits. Conversely, increasing the pilot burnt gas velocity reduces the blow-off velocity, except for the limiting case when the jet is fully non-premixed. The H/C ratio has negligible effects, while resorting to lean pilots significantly increases the stability of globally rich partially premixed and premixed jets. Such findings are consistent with trends obtained from laminar flame calculations for rich fuel/air mixtures issuing against hot combustion products to simulate the pilot stream.

  5. PDF Calculations of Turbulent CH4 Flames with Detailed Chemistry using In Situ Adaptive Tabulation

    Science.gov (United States)

    Saxena, Vivek; Pope, Stephen B.

    1996-11-01

    It is now generally accepted that the probability density function (PDF) approach is the most suited method for turbulent-reactive flows since complex reactions can be treated without modeling assumptions. Integration of detailed chemistry in PDF methods, however, has generally been prohibitively expensive computationally. The technique of In Situ Adaptive Tabulation (ISAT) allows us to accomplish this integration since it can reduce the required computer time by three orders of magnitude. The results of calculations for non-premixed piloted jet diffusion CH4 flames are presented. These calculations are the first successful attempt at representing detailed kinetics in PDF calculations of methane flames.

  6. Depolarization of decaying counterflow turbulence in He II

    Czech Academy of Sciences Publication Activity Database

    Barenghi, C.F.; Gordeev, A. V.; Skrbek, Ladislav

    2006-01-01

    Roč. 74, č. 2 (2006), 026309/1-026309/6 ISSN 1539-3755 R&D Projects: GA ČR GA202/05/0218 Institutional research plan: CEZ:AV0Z10100520 Keywords : superfluid He * counterflow * quantum turbulence Subject RIV: BK - Fluid Dynamics Impact factor: 2.438, year: 2006

  7. Dynamics of a spreading thin film with gravitational counterflow ...

    Indian Academy of Sciences (India)

    ... Refresher Courses · Symposia · Live Streaming. Home; Journals; Sadhana; Volume 40; Issue 3. Dynamics of a spreading thin film with gravitational counterflow using slip model. Naveen Tiwari. Section II - International Union of Theoretical and Applied Mechanics (IUTAM) Volume 40 Issue 3 May 2015 pp 1023-1031 ...

  8. Large volume continuous counterflow dialyzer has high efficiency

    Science.gov (United States)

    Mandeles, S.; Woods, E. C.

    1967-01-01

    Dialyzer separates macromolecules from small molecules in large volumes of solution. It takes advantage of the high area/volume ratio in commercially available 1/4-inch dialysis tubing and maintains a high concentration gradient at the dialyzing surface by counterflow.

  9. Visualization of He II counterflow around a cylinder

    Czech Academy of Sciences Publication Activity Database

    Chagovets, Tymofiy; Van Sciver, S.W.

    2013-01-01

    Roč. 25, č. 10 (2013), "105104-1"-"105104-6" ISSN 1070-6631 R&D Projects: GA ČR GP13-03806P Institutional support: RVO:68378271 Keywords : He II * thermal counterflow * visualization technique Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.040, year: 2013 http://dx.doi.org/10.1063/1.4824004

  10. Computational Flame Diagnostics for Direct Numerical Simulations with Detailed Chemistry of Transportation Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Tianfeng [Univ. of Connecticut, Storrs, CT (United States)

    2017-02-16

    The goal of the proposed research is to create computational flame diagnostics (CFLD) that are rigorous numerical algorithms for systematic detection of critical flame features, such as ignition, extinction, and premixed and non-premixed flamelets, and to understand the underlying physicochemical processes controlling limit flame phenomena, flame stabilization, turbulence-chemistry interactions and pollutant emissions etc. The goal has been accomplished through an integrated effort on mechanism reduction, direct numerical simulations (DNS) of flames at engine conditions and a variety of turbulent flames with transport fuels, computational diagnostics, turbulence modeling, and DNS data mining and data reduction. The computational diagnostics are primarily based on the chemical explosive mode analysis (CEMA) and a recently developed bifurcation analysis using datasets from first-principle simulations of 0-D reactors, 1-D laminar flames, and 2-D and 3-D DNS (collaboration with J.H. Chen and S. Som at Argonne, and C.S. Yoo at UNIST). Non-stiff reduced mechanisms for transportation fuels amenable for 3-D DNS are developed through graph-based methods and timescale analysis. The flame structures, stabilization mechanisms, local ignition and extinction etc., and the rate controlling chemical processes are unambiguously identified through CFLD. CEMA is further employed to segment complex turbulent flames based on the critical flame features, such as premixed reaction fronts, and to enable zone-adaptive turbulent combustion modeling.

  11. Numerical study of flame structure in the mild combustion regime

    Directory of Open Access Journals (Sweden)

    Mardani Amir

    2015-01-01

    Full Text Available In this paper, turbulent non-premixed CH4+H2 jet flame issuing into a hot and diluted co-flow air is studied numerically. This flame is under condition of the moderate or intense low-oxygen dilution (MILD combustion regime and related to published experimental data. The modelling is carried out using the EDC model to describe turbulence-chemistry interaction. The DRM-22 reduced mechanism and the GRI2.11 full mechanism are used to represent the chemical reactions of H2/methane jet flame. The flame structure for various O2 levels and jet Reynolds numbers are investigated. The results show that the flame entrainment increases by a decrease in O2 concentration at air side or jet Reynolds number. Local extinction is seen in the upstream and close to the fuel injection nozzle at the shear layer. It leads to the higher flame entertainment in MILD regime. The turbulence kinetic energy decay at centre line of jet decreases by an increase in O2 concentration at hot Co-flow. Also, increase in jet Reynolds or O2 level increases the mixing rate and rate of reactions.

  12. Measurements of He II Thermal Counterflow Using PIV Technique

    International Nuclear Information System (INIS)

    Zhang, T.; Van Sciver, S.W.

    2004-01-01

    Our previous experiments on the measurements of He II thermal counterflow using Particle Image Velocimetry (PIV) have shown that there exists a substantial discrepancy between the measured and theoretical values of normal fluid velocity. It was assumed that this is due to the slip velocity between tracer particles and liquid helium. In the present work, tracer particles with a much smaller mean diameter and a more uniform size distribution were selected in order to reduce the effect of slip velocity, and an improved two phase fluidized bed technique was used to introduce the particles into liquid helium. The normal fluid velocity of thermal counterflow was then measured using the PIV technique at various heat fluxes and bath temperatures. The experimental results, however, still show the existence of discrepancy between PIV measured particle velocities and the theoretical normal fluid velocity. A preliminary explanation of these results is given based on an interaction of tracer particles with the superfluid component in the He II

  13. Sound generation in coflow and counterflow mixing layers

    OpenAIRE

    Song, Ge; Gloerfelt, Xavier; Robinet, Jean-Christophe

    2010-01-01

    National audience; In this study, nonlinear disturbance equations are solved in two and three dimensions to investigate the sound generated by compressible plane mixing layers. Two flow regimes are distinguished : coflow and counterflow mixing layers. The simulations of coflow shear layers has been carried out in two- and threedimensions. In both cases, the main radiation is attributed to the pairing events leading to a quadrupolar signature. The convective nature of the flow is conform with ...

  14. Combustion rate limits of hydrogen plus hydrocarbon fuel: Air diffusion flames from an opposed jet burner technique

    Science.gov (United States)

    Pellett, Gerald L.; Guerra, Rosemary; Wilson, Lloyd G.; Reeves, Ronald N.; Northam, G. Burton

    1987-01-01

    Combustion of H2/hydrocarbon (HC) fuel mixtures may be considered in certain volume-limited supersonic airbreathing propulsion applications. Effects of HC addition to H2 were evaluated, using a recent argon-bathed, coaxial, tubular opposed jet burner (OJB) technique to measure the extinction limits of counterflow diffusion flames. The OJB flames were formed by a laminar jet of (N2 and/or HC)-diluted H2 mixture opposed by a similar jet of air at ambient conditions. The OJB data, derived from respective binary mixtures of H2 and methane, ethylene, or propane HCs, were used to characterize BLOWOFF and RESTORE. BLOWOFF is a sudden breaking of the dish-shaped OJB flame to a stable torus or ring shape, and RESTORE marks sudden restoration of the central flame by radial inward flame propagation. BLOWOFF is a measure of kinetically-limited flame reactivity/speed under highly stretched, but relatively ideal impingement flow conditions. RESTORE measures inward radial flame propagation rate, which is sensitive to ignition processes in the cool central core. It is concluded that relatively small molar amounts of added HC greatly reduce the reactivity characteristics of counterflow hydrogen-air diffusion flames, for ambient initial conditions.

  15. Investigation of noise radiation from a swirl stabilized diffusion flame with an array of microphones

    International Nuclear Information System (INIS)

    Singh, A.V.; Yu, M.; Gupta, A.K.; Bryden, K.M.

    2013-01-01

    Highlights: • Acoustic spectral characteristics independent of equivalence ratio and flow velocity. • Combustion noise dependent on global equivalence ratio and flow velocity. • Increased global equivalence ratio decreased the frequency of peak. • Decay and growth coefficients largely independent of different flow conditions. • Acoustic radiation coherent up to 1.5 kHz for spatially separated microphones. - Abstract: Next generation of combustors are expected to provide significant improvement on efficiency and reduced pollutants emission. In such combustors, the challenges of local flow, pressure, chemical composition and thermal signatures as well as their interactions will require detailed investigation for seeking optimum performance. Sensor networks with a large number of sensors will be employed in future smart combustors, which will allow one to obtain fast and comprehensive information on the various ongoing processes within the system. In this paper sensor networks with specific focus on an array of homogeneous microphones are used examine the spectral characteristics of combustion noise from a non-premixed combustor. A non-premixed double concentric swirl-flame burner was used. Noise spectra were determined experimentally for the non-premixed swirl flame at various fuel–air ratios using an array of homogeneous condenser microphones. Multiple microphones positioned at discrete locations around the turbulent diffusion flame, provided an understanding of the total sound power and their spectral characteristics. The growth and decay coefficients of total sound power were investigated at different test conditions. The signal coherence between different microphone pairs was also carried out to determine the acoustic behavior of a swirl stabilized turbulent diffusion flame. The localization of acoustic sources from the multiple microphones was examined using the noise spectra. The results revealed that integration of multiple sensors in combustors

  16. Flame Length

    Data.gov (United States)

    Earth Data Analysis Center, University of New Mexico — Flame length was modeled using FlamMap, an interagency fire behavior mapping and analysis program that computes potential fire behavior characteristics. The tool...

  17. Flame synthesis of zinc oxide nanocrystals

    Energy Technology Data Exchange (ETDEWEB)

    Merchan-Merchan, Wilson, E-mail: wmerchan-merchan@ou.edu [School of Aerospace and Mechanical Engineering, University of Oklahoma, Norman, OK 73019 (United States); Farahani, Moien Farmahini [School of Aerospace and Mechanical Engineering, University of Oklahoma, Norman, OK 73019 (United States)

    2013-02-01

    Highlights: Black-Right-Pointing-Pointer We report a single-step flame method for the synthesis of Zn oxide nanocrystals. Black-Right-Pointing-Pointer Diverse flame positions lead to a variation of Zn oxide nanocrystal growth. Black-Right-Pointing-Pointer The synthesized crystals have polyhedral, pipet- and needle-like shape. Black-Right-Pointing-Pointer High length-to-diameter aspect-ratio crystals appear in a higher temperature flame. Black-Right-Pointing-Pointer The crystal growth mechanism corresponds to vapor-to-solid conversion. - Abstract: Distinctive zinc oxide (ZnO) nanocrystals were synthesized on the surface of Zn probes using a counter-flow flame medium formed by methane/acetylene and oxygen-enriched air streams. The source material, a zinc wire with a purity of {approx}99.99% and diameter of 1 mm, was introduced through a sleeve into the oxygen rich region of the flame. The position of the probe/sleeve was varied within the flame medium resulting in growth variation of ZnO nanocrystals on the surface of the probe. The shape and structural parameters of the grown crystals strongly depend on the flame position. Structural variations of the synthesized crystals include single-crystalline ZnO nanorods and microprisms (ZMPs) (the ZMPs have less than a few micrometers in length and several hundred nanometers in cross section) with a large number of facets and complex axial symmetry with a nanorod protruding from their tips. The protruding rods are less than 100 nm in diameter and lengths are less than 1 {mu}m. The protruding nanorods can be elongated several times by increasing the residence time of the probe/sleeve inside the oxygen-rich flame or by varying the flame position. At different flame heights, nanorods having higher length-to-diameter aspect-ratio can be synthesized. A lattice spacing of {approx}0.26 nm was measured for the synthesized nanorods, which can be closely correlated with the (0 0 2) interplanar spacing of hexagonal ZnO (Wurtzite) cells

  18. Autoignition characteristics of laminar lifted jet flames of pre-vaporized iso-octane in heated coflow air

    KAUST Repository

    Alnoman, Saeed

    2015-12-01

    The stabilization characteristics of laminar non-premixed jet flames of pre-vaporized iso-octane, one of the primary reference fuels for octane rating, have been studied experimentally in heated coflow air. Non-autoignited and autoignited lifted flames were analyzed. With the coflow air at relatively low initial temperatures below 940 K, an external ignition source was required to stabilize the flame. These lifted flames had tribrachial edge structures and their liftoff heights correlated well with the jet velocity scaled by stoichiometric laminar burning velocity, indicating the importance of the edge propagation speed on flame stabilization. At high initial temperatures over 940 K, the autoignited flames were stabilized without requiring an external ignition source. These autoignited lifted flames exhibited either tribrachial edge structures or mild combustion behaviors depending on the level of fuel dilution. Two distinct transition behaviors were observed in the autoignition regime from a nozzle-attached flame to a lifted tribrachial-edge flame and then to lifted mild combustion as the jet velocity increased at a certain fuel dilution level. The liftoff data of the autoignited flames with tribrachial edges were analyzed based on calculated ignition delay times. Analysis of the experimental data suggested that ignition delay time may be much less sensitive to initial temperature under atmospheric pressure conditions as compared with predictions. © 2015 Elsevier Ltd. All rights reserved.

  19. Reynolds number and geometry effects in laminar axisymmetric isothermal counterflows

    KAUST Repository

    Scribano, Gianfranco

    2016-12-29

    The counterflow configuration is a canonical stagnation flow, featuring two opposed impinging round jets and a mixing layer across the stagnation plane. Although counterflows are used extensively in the study of reactive mixtures and other applications where mixing of two streams is required, quantitative data on the scaling properties of the flow field are lacking. The aim of this work is to characterize the velocity and mixing fields in isothermal counterflows over a wide range of conditions. The study features both experimental data from particle image velocimetry and results from detailed axisymmetric simulations. The scaling laws for the nondimensional velocity and mixture fraction are obtained as a function of an appropriate Reynolds number and the ratio of the separation distance of the nozzles to their diameter. In the range of flow configurations investigated, the nondimensional fields are found to depend primarily on the separation ratio and, to a lesser extent, the Reynolds number. The marked dependence of the velocity field with respect to the separation ratio is linked to a high pressure region at the stagnation point. On the other hand, Reynolds number effects highlight the role played by the wall boundary layer on the interior of the nozzles, which becomes less important as the separation ratio decreases. The normalized strain rate and scalar dissipation rate at the stagnation plane are found to attain limiting values only for high values of the Reynolds number. These asymptotic values depend markedly on the separation ratio and differ significantly from the values produced by analytical models. The scaling of the mixing field does not show a limiting behavior as the separation ratio decreases to the smallest practical value considered.

  20. Nosehouse: heat-conserving ventilators based on nasal counterflow exchangers.

    Science.gov (United States)

    Vogel, Steven

    2009-12-01

    Small birds and mammals commonly minimize respiratory heat loss with reciprocating counterflow exchangers in their nasal passageways. These animals extract heat from the air in an exhalation to warm those passageways and then use that heat to warm the subsequent inhalation. Although the near-constant volume of buildings precludes direct application of the device, a pair of such exchangers located remotely from each other circumvents that problem. A very simple and crudely constructed small-scale physical model of the device worked well enough as a heat conserver to suggest utility as a ventilator for buildings.

  1. Numerical study of turbulent normal diffusion flame CH4-air stabilized by coaxial burner

    Directory of Open Access Journals (Sweden)

    Riahi Zouhair

    2013-01-01

    Full Text Available The practical combustion systems such as combustion furnaces, gas turbine, engines, etc. employ non-premixed combustion due to its better flame stability, safety, and wide operating range as compared to premixed combustion. The present numerical study characterizes the turbulent flame of methane-air in a coaxial burner in order to determine the effect of airflow on the distribution of temperature, on gas consumption and on the emission of NOx. The results in this study are obtained by simulation on FLUENT code. The results demonstrate the influence of different parameters on the flame structure, temperature distribution and gas emissions, such as turbulence, fuel jet velocity, air jet velocity, equivalence ratio and mixture fraction. The lift-off height for a fixed fuel jet velocity is observed to increase monotonically with air jet velocity. Temperature and NOx emission decrease of important values with the equivalence ratio, it is maximum about the unity.

  2. Impact of Equivalence Ratio on the Macrostructure of Premixed Swirling CH 4 /Air and CH 4 /O 2 /CO 2 Flames

    KAUST Repository

    Watanabe, Hirotatsu

    2015-06-15

    Premixed CH4/O2/CO2 flames (oxy-flames) and CH4/air flames (air-flames) were experimentally studied in a swirl-stabilized combustor. For comparing oxy and air flames, the same equivalence ratio and adiabatic flame temperature were used. CO2 dilution was adjusted to attain the same adiabatic temperature for the oxy-flame and the corresponding air-flame while keeping the equivalence ratio and Reynolds number (=20,000) the same. For high equivalence ratios, we observed flames stabilized along the inner and outer shear layers of the swirling flow and sudden expansion, respectively, in both flames. However, one notable difference between the two flames appears as the equivalence ratio reaches 0.60. At this point, the outer shear layer flame disappears in the air-flame while it persists in the oxy-flame, despite the lower burning velocity of the oxy-flame. Prior PIV measurements (Ref. 9) showed that the strains along the outer shear layer are higher than along the inner shear layer. Therefore, the extinction strain rates in both flames were calculated using a counter-flow premixed twin flame configuration. Calculations at the equivalence ratio of 0.60 show that the extinction strain rate is higher in the oxy than in the air flame, which help explain why it persists on the outer shear layer with higher strain rate. It is likely that extinction strain rates contribute to the oxy-flame stabilization when air flame extinguish in the outer shear layer. However, the trend reverses at higher equivalence ratio, and the cross point of the extinction strain rate appears at equivalence ratio of 0.64.

  3. Flames in vortices & tulip-flame inversion

    Science.gov (United States)

    Dold, J. W.

    This article summarises two areas of research regarding the propagation of flames in flows which involve significant fluid-dynamical motion [1]-[3]. The major difference between the two is that in the first study the fluid motion is present before the arrival of any flame and remains unaffected by the flame [1, 2] while, in the second study it is the flame that is responsible for all of the fluid dynamical effects [3]. It is currently very difficult to study flame-motion in which the medium is both highly disturbed before the arrival of a flame and is further influenced by the passage of the flame.

  4. Flame synthesis of carbon nanotubes and related carbon nano-materials

    Science.gov (United States)

    Merchan-Merchan, Wilson Eduardo

    The work of this thesis is the experimental investigation of various types of carbon nanostructures formed in the oxy-fuel flame media. Soot volume fraction (particle density), soot morphology (primary particle diameter, degree of agglomeration, and the internal and external particle structure), CNTs (synthesis optimization and morphology), and fullerenes are being investigated in this work. These materials are characterized by means of light scattering and optical analysis, transmission electron microscopy (TEM), and scanning electron microscopy (SEM). Soot particles were investigated using the laser extinction method and by thermophoretic sampling technique. It was found that as the oxygen content increased, the soot volume fraction also tended to increase. High-resolution TEM imaging on the trapped material reveals the presence of highly crystalline soot structures. A catalytic support was positioned at the fuel side of the counter-flow flame formed by fuel (96%CH4+4%C2H2) and oxidizer (50%O2+50%N2) streams. TEM and SEM studies reveal the presence of a variety of highly organized carbonaceous structures with the configurations showing strong dependence on the flame location. It is observed that when a catalytic probe is inserted in the flame under an electric field control, a coating layer of vertically aligned carbon nanotubes covering the catalytic surface of the probe is formed. These results show that electric fields can be applied as a means to control CNT structure and growth rates. Overall, the electric field control method demonstrates stabilization of the structure in a wide flame region while growth rate remains dependent on flame location. The presence of fullerenes produced in the flame was detected using high resolution TEM and high pressure liquid chromatography. We found that large amounts of fullerenes (C60+ C70) can be generated using the counter-flow flame at normal atmospheric conditions.

  5. The flow field structure of highly stabilized partially premixed flames in a concentric flow conical nozzle burner with coflow

    KAUST Repository

    Elbaz, Ayman M.

    2015-08-29

    The stability limits, the stabilization mechanism, and the flow field structure of highly stabilized partially premixed methane flames in a concentric flow conical nozzle burner with air co-flow have been investigated and presented in this work. The stability map of partial premixed flames illustrates that the flames are stable between two extinction limits. A low extinction limit when partial premixed flames approach non-premixed flame conditions, and a high extinction limit, with the partial premixed flames approach fully premixed flame conditions. These two limits showed that the most stable flame conditions are achieved at a certain degree of partial premixed. The stability is improved by adding air co-flow. As the air co-flow velocity increases the most stable flames are those that approach fully premixed. The turbulent flow field of three flames at 0, 5, 10 m/s co-flow velocity are investigated using Stereo Particle Image Velocimetry (SPIV) in order to explore the improvement of the flame stability due to the use of air co-flow. The three flames are all at a jet equivalence ratio (Φj) of 2, fixed level of partial premixing and jet Reynolds number (Rej) of 10,000. The use of co-flow results in the formation of two vortices at the cone exit. These vortices act like stabilization anchors for the flames to the nozzle tip. With these vortices in the flow field, the reaction zone shifts toward the reduced turbulence intensity at the nozzle rim of the cone. Interesting information about the structure of the flow field with and without co-flow are identified and reported in this work.

  6. Modeling of Shipboard Smoke Propagation with a Forced Counter-Flow Air Supply

    National Research Council Canada - National Science Library

    Farman, Garrett

    2001-01-01

    The propagation of fire-generated smoke with a counter-flow air supply in, a horizontal arrangement of shipboard compartments and passageways was modeled using a computational fluid dynamics program...

  7. OLYMPEX Counterflow Spectrometer and Impactor Field Campaign Report

    Energy Technology Data Exchange (ETDEWEB)

    Poellot, Michael [Univ. of North Dakota, Grand Forks, ND (United States)

    2016-07-01

    The U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Climate Research Facility’s ARM Aerial Facility (AAF) Counterflow Spectrometer and Impactor (CSI) probe was flown on the University of North Dakota Cessna Citation research aircraft during the Olympic Mountain Experiment (OLYMPEX). The field campaign took place from November 12 through December 19, 2015, over the Olympic Mountains and coastal waters of Washington State as part of a National Aeronautics and Space Administration (NASA) Global Precipitation Measurement (GPM) validation campaign. The CSI was added to the Citation instrument suite to support the NASA Aerosol-Cloud Ecosystem (ACE) satellite program and flights of the NASA Lockheed Earth Resources (ER-2) aircraft. ACE funded extra ER-2 flights to focus on clouds that are weakly precipitating, which are also of interest to the DOE Atmospheric System Research (ASR) program.

  8. Counterflow Dielectrophoresis for Trypanosome Enrichment and Detection in Blood

    Science.gov (United States)

    Menachery, Anoop; Kremer, Clemens; Wong, Pui E.; Carlsson, Allan; Neale, Steven L.; Barrett, Michael P.; Cooper, Jonathan M.

    2012-10-01

    Human African trypanosomiasis or sleeping sickness is a deadly disease endemic in sub-Saharan Africa, caused by single-celled protozoan parasites. Although it has been targeted for elimination by 2020, this will only be realized if diagnosis can be improved to enable identification and treatment of afflicted patients. Existing techniques of detection are restricted by their limited field-applicability, sensitivity and capacity for automation. Microfluidic-based technologies offer the potential for highly sensitive automated devices that could achieve detection at the lowest levels of parasitemia and consequently help in the elimination programme. In this work we implement an electrokinetic technique for the separation of trypanosomes from both mouse and human blood. This technique utilises differences in polarisability between the blood cells and trypanosomes to achieve separation through opposed bi-directional movement (cell counterflow). We combine this enrichment technique with an automated image analysis detection algorithm, negating the need for a human operator.

  9. Wake Capture, Particle Breakup, and Other Artifacts Associated with Counterflow Virtual Impaction

    OpenAIRE

    Pekour, Mikhail S.; Cziczo, Daniel James

    2010-01-01

    Counterflow virtual impaction is used to inertially separate cloud elements from inactivated aerosol. Previous airborne, ground-based, and laboratory studies using this technique exhibit artifacts that are not fully explained by the impaction theory. We have performed laboratory studies that show small particles can be carried across the inertial barrier of the counterflow by collision and/or coalescence or riding the wake of larger particles with sufficient inertia. We have also performed th...

  10. The formation of aromatics and PAH's in laminar flames

    International Nuclear Information System (INIS)

    Marinov, N M; Pitz, W J; Westbrook, C K

    1999-01-01

    The formation of aromatics and PAH's is an important problem in combustion. These compounds are believed to contribute to the formation of soot whose emission from diesel engines is regulated widely throughout the industrial world. Additionally, the United States Environmental Protection Agency regulates the emission of many aromatics and PAH species from stationary industrial burners, under the 1990 Clean Air Act Amendments. The above emission regulations have created much interest in understanding how these species are formed in combustion systems. Much previous work has been done on aromatics and PAH's. The work is too extensive to review here, but is reviewed in Reference 1. A few recent developments are highlighted here. McEnally, Pfefferle and coworkers have studied aromatic, PAH and soot formation in a variety of non-premixed flames with hydrocarbon additives[2-4]. They found additives that contain a C5 ring increase the concentration of aromatics and soot[4]. Howard and coworkers have studied the formation of aromatic and PAH's in low pressure, premixed, laminar hydrocarbon flames. They found the cyclopentadienyl radical to be a key species in naphthalene formation in a fuel-rich, benzene/Ar/O2 flame[5

  11. Response mechanisms of attached premixed flames subjected to harmonic forcing

    Science.gov (United States)

    Shreekrishna

    The persistent thrust for a cleaner, greener environment has prompted air pollution regulations to be enforced with increased stringency by environmental protection bodies all over the world. This has prompted gas turbine manufacturers to move from nonpremixed combustion to lean, premixed combustion. These lean premixed combustors operate quite fuel-lean compared to the stochiometric, in order to minimize CO and NOx productions, and are very susceptible to oscillations in any of the upstream flow variables. These oscillations cause the heat release rate of the flame to oscillate, which can engage one or more acoustic modes of the combustor or gas turbine components, and under certain conditions, lead to limit cycle oscillations. This phenomenon, called thermoacoustic instabilities, is characterized by very high pressure oscillations and increased heat fluxes at system walls, and can cause significant problems in the routine operability of these combustors, not to mention the occasional hardware damages that could occur, all of which cumulatively cost several millions of dollars. In a bid towards understanding this flow-flame interaction, this research works studies the heat release response of premixed flames to oscillations in reactant equivalence ratio, reactant velocity and pressure, under conditions where the flame preheat zone is convectively compact to these disturbances, using the G-equation. The heat release response is quantified by means of the flame transfer function and together with combustor acoustics, forms a critical component of the analytical models that can predict combustor dynamics. To this end, low excitation amplitude (linear) and high excitation amplitude (nonlinear) responses of the flame are studied in this work. The linear heat release response of lean, premixed flames are seen to be dominated by responses to velocity and equivalence ratio fluctuations at low frequencies, and to pressure fluctuations at high frequencies which are in the

  12. LES of Sooting Flames

    Science.gov (United States)

    2006-12-01

    investigated the formation of carbon in a well-stirred reactor. The critical C/O ratio for soot inception was observed and compared to Bunsen -Type flames ...The computations reproduced the flame structure, with reasonable agreement of the velocity field. They designed the swirl burner to match the...the vortex breakdown. 121 [203] introduced the compositional structure and flow field of two flames on the same burner . The two flames have the same

  13. Effect of turbulence modelling to predict combustion and nanoparticle production in the flame assisted spray dryer based on computational fluid dynamics

    Science.gov (United States)

    Septiani, Eka Lutfi; Widiyastuti, W.; Winardi, Sugeng; Machmudah, Siti; Nurtono, Tantular; Kusdianto

    2016-02-01

    Flame assisted spray dryer are widely uses for large-scale production of nanoparticles because of it ability. Numerical approach is needed to predict combustion and particles production in scale up and optimization process due to difficulty in experimental observation and relatively high cost. Computational Fluid Dynamics (CFD) can provide the momentum, energy and mass transfer, so that CFD more efficient than experiment due to time and cost. Here, two turbulence models, k-ɛ and Large Eddy Simulation were compared and applied in flame assisted spray dryer system. The energy sources for particle drying was obtained from combustion between LPG as fuel and air as oxidizer and carrier gas that modelled by non-premixed combustion in simulation. Silica particles was used to particle modelling from sol silica solution precursor. From the several comparison result, i.e. flame contour, temperature distribution and particle size distribution, Large Eddy Simulation turbulence model can provide the closest data to the experimental result.

  14. An old flame

    Science.gov (United States)

    Thompson, Frank

    2014-07-01

    Flames are seen more often in chemistry than in physics laboratories. However, as a continuation of the previous colourful demonstration of a levitating Bunsen flame described recently in this journal (De Carvalho 2012 Phys Educ. 47 517), two short experiments are reported. Firstly, flame rectification is investigated and secondly, the electrical potential around a charged object is measured.

  15. Flame structure of methane inverse diffusion flame

    KAUST Repository

    Elbaz, Ayman M.

    2014-07-01

    This paper presents high speed images of OH-PLIF at 10. kHz simultaneously with 2D PIV (particle image velocimetry) measurements collected along the entire length of an inverse diffusion flame with circumferentially arranged methane fuel jets. For a fixed fuel flow rate, the central air jet Re was varied, leading to four air to fuel velocity ratios, namely Vr = 20.7, 29, 37.4 and 49.8. A double flame structure could be observed composed of a lower fuel entrainment region and an upper mixing and intense combustion region. The entrainment region was enveloped by an early OH layer, and then merged through a very thin OH neck to an annular OH layer located at the shear layer of the air jet. The two branches of this annular OH layer broaden as they moved downstream and eventfully merged together. Three types of events were observed common to all flames: breaks, closures and growing kernels. In upstream regions of the flames, the breaks were counterbalanced by flame closures. These breaks in OH signal were found to occur at locations where locally high velocity flows were impinging on the flame. As the Vr increased to 37.4, the OH layers became discontinuous over the downstream region of the flame, and these regions of low or no OH moved upstream. With further increases in Vr, these OH pockets act as flame kernels, growing as they moved downstream, and became the main mechanism for flame re-ignition. Along the flame length, the direction of the two dimensional principle compressive strain rate axis exhibited a preferred orientation of approximately 45° with respect to the flow direction. Moreover, the OH zones were associated with elongated regions of high vorticity. © 2013 Elsevier Inc.

  16. Extended Shvab-Zel'dovich formulation for multicomponent-fuel diffusion flames

    Energy Technology Data Exchange (ETDEWEB)

    Fachini, Fernando F. [Instituto Nacional de Pesquisas Espaciais, Rod. Presidente Dutra Km 40, 12630-000 Cachoeira Paulista, SP (Brazil)

    2007-03-15

    In this paper an extension of the Shvab-Zel'dovich formulation is presented. This extended formulation, based on the Burke-Schumann kinetic mechanism, describes the combustion of multicomponent fuels in a diffusion flame in terms of mixture fraction and the excess enthalpy. Under the condition of Burke-Schumann kinetic mechanism, the multicomponent fuel is burned in a single flame. The model is applied to a diffusion flame generated by the burning of mixtures of n-heptane and hydrogen diluted in nitrogen in a counterflow configuration. Due to the very small ratio of the hydrogen molecular weight to the n-heptane molecular weight, small quantities of hydrogen (in terms of mass) in the mixture does not change significantly the properties related to the mass, like as the total heat released per unit of mass at the flame. However, properties related to the hydrogen mole fraction does change expressively with small quantities, like as the radiative energy loss from the hot region around the flame. The results show the flame properties as a function of the reciprocal scalar dissipation and hydrogen quantity in the mixture. It is observed that, by reducing the reciprocal scalar dissipation, the radiative energy loss decreases and by increasing the presence of the hydrogen, the sensitivity of the flame properties with the reciprocal scalar dissipation reduces. It is also revealed by the results, the effects of the potentiated preferential hydrogen mass diffusion in compositions in which nitrogen and n-heptane are the majority species, and the potentiated preferential n-heptane thermal diffusion in compositions in which nitrogen and hydrogen are the majority species, on the flame properties. Although, this work do not treat the extinction problem, the fluid dynamical results will be properly handled to provide information about the reciprocal scalar dissipation and the Linan's parameter necessary for future flame stability analyses. (author)

  17. Negativly streched premixed flames

    Science.gov (United States)

    Krikunova, A. I.; Saveliev, A. S.; Son, E. E.

    2018-01-01

    An experimental study of gravity effect on the blow-off and flash-back borders of the conical methane–air flame (normal and ring-stabilized) was performed. The influence of the preferential diffusion on the flame behavior in vicinity of flash-back boundaries was observed. Under conditions at Lewis number Le > 1, the radius of curvature of the flame tip increased gradually approaching flash-back boundaries while for the lean methane–air flames (Le < 1) the radius decreased abruptly. It was shown that the burning velocity for lean flames is less than that for reach ones, so the flash-back occurs at higher strains.

  18. Steady and decaying quantum turbulence generated in He II flow channel by counterflow and pure superflow

    Czech Academy of Sciences Publication Activity Database

    Chagovets, Tymofiy; Gordeev, A. V.; Rotter, M.; Soukup, František; Šindelář, J.; Skrbek, Ladislav

    2006-01-01

    Roč. 56, č. 2 (2006), s. 169-172 ISSN 0323-0465. [Conference of Czech and Slovak Physicist /15./. Košice, 05.09.2005-08.09.2005] Institutional research plan: CEZ:AV0Z10100520 Keywords : superfluid helium * counterflow * pure superflow * second sound * quantum turbulence Subject RIV: BK - Fluid Dynamics Impact factor: 0.647, year: 2006

  19. An experimental study on turbulent lifted flames of methane in coflow jets at elevated temperatures

    KAUST Repository

    Choi, Byungchul

    2013-01-01

    An experimental study was conducted on the effects of initial temperature variation on the stabilization characteristics of turbulent nonpremixed flames in coflow jets of methane fuel diluted by nitrogen. The typical behavior seen in the study showed that the liftoff height increased linearly with the jet velocity regardless of the initial temperature in the turbulent regime. Two models were investigated for predicting liftoff heights in the methane jets: the premixed flame model and the large-scale mixing model. For the premixed flame model, the liftoff heights in the methane jets were accurately predicted using the thermal diffusivity of the unburned gas temperature αst,0, instead of that of the burned gas temperature αst,b. For the large-scale mixing model, however, the prediction of liftoff heights differed slightly for the various fuel mole fractions. However, when considering the initial fuel mass fraction YF,0, the liftoff heights were successfully predicted. This result implies that the characteristics of the unburned fuel-air mixture play a crucial role for flame stabilization in coflow jets for a variety of initial conditions. In the turbulent regime, the blowout velocity and the liftoff height at blowout could be accurately predicted by the two models based on a consideration of the physical properties and the buoyancy effect of the initial temperature variation. © 2012 Elsevier Ltd. All rights reserved.

  20. Application of Shear Plate Interferometry to Jet Diffusion Flame Temperature Measurements

    Science.gov (United States)

    VanDerWege, Brad A.; OBrien, Chris J.; Hochgreb, Simone

    1997-01-01

    The recent ban on the production of bromotrifluoromethane (CF3Br) because of its high stratospheric ozone depletion potential has led to interest in finding alternative agents for fire extinguishing applications. Some of the promising alternatives are fluorinated hydrocarbons. A clear understanding of the effects of CF3Br and alternative chemical suppressants on diffusion flames is therefore necessary in the selection of alternative suppressants for use in normal and microgravity. The flame inhibition effects of halogen compounds have been studied extensively in premixed systems. The effect of addition of halocarbons (carbon-halogen compounds) to diffusion flames has been studied experimentally in coflow configurations and in counterflow gaseous and liquid-pool flames. Halogenated compounds are believed to inhibit combustion by scavenging hydrogen radicals to form the relatively unreactive compound HF, or through a catalytic recombination cycle involving HBr to form H2. Comparisons between halogens show that bromine inhibition is significantly more effective than chlorine or fluorine. Although fluorinated compounds are only slightly more effective inhibitors on a mass basis than nitrogen, they are more effective on a volume basis and are easily stored in liquid form. The objectives of this study are (a) to determine the stability limits of laminar jet diffusion flames with respect to inhibitor concentration in both normal and microgravity, and (b) to investigate the structure of halocarbon-inhibited flames. In the initial phase of this project, visual diagnostics were used to observe the structure and behavior of normal and microgravity flames. The initial observations showed significant changes in the structure of the flames with the addition of halocarbons to the surrounding environment, as discussed below. Furthermore, the study established that the flames are more stable relative to the addition of halocarbons in microgravity than in normal gravity. Visual

  1. INVESTIGATION ON THE FLAME EXTINCTION LIMIT OF FUEL BLENDS

    Energy Technology Data Exchange (ETDEWEB)

    Ahsan R. Choudhuri

    2005-02-01

    Lean flame extinction limits of binary fuel mixtures of methane (CH{sub 4}), propane (C{sub 3}H{sub 8}), and ethane (C{sub 2}H{sub 6}) were measured using a twin-flame counter-flow burner. Experiments were conducted to generate an extinction equivalence ratio vs. global stretch rate plot and an extrapolation method was used to calculate the equivalence ratio corresponding to an experimentally unattainable zero-stretch condition. The foregoing gases were selected because they are the primary constitutes of natural gas, which is the primary focus of the present study. To validate the experimental setup and methodology, the flame extinction limit of pure fuels at zero stretch conditions were also estimated and compared with published values. The lean flame extinction limits of methane (f{sub ext} = 4.6%) and propane (f{sub ext} = 2.25%) flames measured in the present study agreed with the values reported in the literature. It was observed that the flame extinction limit of fuel blends have a polynomial relation with the concentration of component fuels in the mixture. This behavior contradicts with the commonly used linear Le Chatelier's approximation. The experimentally determined polynomial relations between the flame extinction limits of fuel blends (i.e. methane-propane and methane-ethane) and methane concentration are as follows: (1) Methane-Propane--%f{sub ext} = (1.05 x 10{sup -9}) f{sup 5}-(1.3644 x 10{sup -7}) f{sup 4}+(6.40299 x 10{sup -6}) f{sup 3}-(1.2108459 x 10{sup -4}) f{sup 2}+(2.87305329 x 10{sup -3}) f+2.2483; (2) Methane-Ethane--%f{sub ext} = (2.1 x 10{sup -9})f{sup 5}-(3.5752 x 10{sup -7}) f{sup 4}+(2.095425 x 10{sup -5}) f{sup 3}-(5.037353 x 10{sup -4}) f{sup 2} + 6.08980409 f + 2.8923. Where f{sub ext} is the extinction limits of methane-propane and methane-ethane fuel blends, and f is the concentration (% volume) of methane in the fuel mixture. The relations were obtained by fitting fifth order curve (polynomial regression) to

  2. Time-averaged probability density functions of soot nanoparticles along the centerline of a piloted turbulent diffusion flame using a scanning mobility particle sizer

    KAUST Repository

    Chowdhury, Snehaunshu

    2017-01-23

    In this study, we demonstrate the use of a scanning mobility particle sizer (SMPS) as an effective tool to measure the probability density functions (PDFs) of soot nanoparticles in turbulent flames. Time-averaged soot PDFs necessary for validating existing soot models are reported at intervals of ∆x/D∆x/D = 5 along the centerline of turbulent, non-premixed, C2H4/N2 flames. The jet exit Reynolds numbers of the flames investigated were 10,000 and 20,000. A simplified burner geometry based on a published design was chosen to aid modelers. Soot was sampled directly from the flame using a sampling probe with a 0.5-mm diameter orifice and diluted with N2 by a two-stage dilution process. The overall dilution ratio was not evaluated. An SMPS system was used to analyze soot particle concentrations in the diluted samples. Sampling conditions were optimized over a wide range of dilution ratios to eliminate the effect of agglomeration in the sampling probe. Two differential mobility analyzers (DMAs) with different size ranges were used separately in the SMPS measurements to characterize the entire size range of particles. In both flames, the PDFs were found to be mono-modal in nature near the jet exit. Further downstream, the profiles were flatter with a fall-off at larger particle diameters. The geometric mean of the soot size distributions was less than 10 nm for all cases and increased monotonically with axial distance in both flames.

  3. Analysis of Heat Transfers inside Counterflow Plate Heat Exchanger Augmented by an Auxiliary Fluid Flow

    Science.gov (United States)

    Khaled, A.-R. A.

    2014-01-01

    Enhancement of heat transfers in counterflow plate heat exchanger due to presence of an intermediate auxiliary fluid flow is investigated. The intermediate auxiliary channel is supported by transverse conducting pins. The momentum and energy equations for the primary fluids are solved numerically and validated against a derived approximate analytical solution. A parametric study including the effect of the various plate heat exchanger, and auxiliary channel dimensionless parameters is conducted. Different enhancement performance indicators are computed. The various trends of parameters that can better enhance heat transfer rates above those for the conventional plate heat exchanger are identified. Large enhancement factors are obtained under fully developed flow conditions. The maximum enhancement factors can be increased by above 8.0- and 5.0-fold for the step and exponential distributions of the pins, respectively. Finally, counterflow plate heat exchangers with auxiliary fluid flows are recommended over the typical ones if these flows can be provided with the least cost. PMID:24719572

  4. Analysis of heat transfers inside counterflow plate heat exchanger augmented by an auxiliary fluid flow.

    Science.gov (United States)

    Khaled, A-R A

    2014-01-01

    Enhancement of heat transfers in counterflow plate heat exchanger due to presence of an intermediate auxiliary fluid flow is investigated. The intermediate auxiliary channel is supported by transverse conducting pins. The momentum and energy equations for the primary fluids are solved numerically and validated against a derived approximate analytical solution. A parametric study including the effect of the various plate heat exchanger, and auxiliary channel dimensionless parameters is conducted. Different enhancement performance indicators are computed. The various trends of parameters that can better enhance heat transfer rates above those for the conventional plate heat exchanger are identified. Large enhancement factors are obtained under fully developed flow conditions. The maximum enhancement factors can be increased by above 8.0- and 5.0-fold for the step and exponential distributions of the pins, respectively. Finally, counterflow plate heat exchangers with auxiliary fluid flows are recommended over the typical ones if these flows can be provided with the least cost.

  5. Flow instability in laminar jet flames driven by alternating current electric fields

    KAUST Repository

    Kim, Gyeong Taek

    2016-10-13

    The effect of electric fields on the instability of laminar nonpremixed jet flames was investigated experimentally by applying the alternating current (AC) to a jet nozzle. We aimed to elucidate the origin of the occurrence of twin-lifted jet flames in laminar jet flow configurations, which occurred when AC electric fields were applied. The results indicated that a twin-lifted jet flame originated from cold jet instability, caused by interactions between negative ions in the jet flow via electron attachment as O +e→O when AC electric fields were applied. This was confirmed by conducting systematic, parametric experiment, which included changing gaseous component in jets and applying different polarity of direct current (DC) to the nozzle. Using two deflection plates installed in parallel with the jet stream, we found that only negative DC on the nozzle could charge oxygen molecules negatively. Meanwhile, the cold jet instability occurred only for oxygen-containing jets. A shedding frequency of jet stream due to AC driven instability showed a good correlation with applied AC frequency exhibiting a frequency doubling. However, for the applied AC frequencies over 80Hz, the jet did not respond to the AC, indicating an existence of a minimum flow induction time in a dynamic response of negative ions to external AC fields. Detailed regime of the instability in terms of jet velocity, AC voltage and frequency was presented and discussed. Hypothesized mechanism to explain the instability was also proposed.

  6. Unsteady Flame Embedding

    KAUST Repository

    El-Asrag, Hossam A.

    2011-01-01

    Direct simulation of all the length and time scales relevant to practical combustion processes is computationally prohibitive. When combustion processes are driven by reaction and transport phenomena occurring at the unresolved scales of a numerical simulation, one must introduce a dynamic subgrid model that accounts for the multiscale nature of the problem using information available on a resolvable grid. Here, we discuss a model that captures unsteady flow-flame interactions- including extinction, re-ignition, and history effects-via embedded simulations at the subgrid level. The model efficiently accounts for subgrid flame structure and incorporates detailed chemistry and transport, allowing more accurate prediction of the stretch effect and the heat release. In this chapter we first review the work done in the past thirty years to develop the flame embedding concept. Next we present a formulation for the same concept that is compatible with Large Eddy Simulation in the flamelet regimes. The unsteady flame embedding approach (UFE) treats the flame as an ensemble of locally one-dimensional flames, similar to the flamelet approach. However, a set of elemental one-dimensional flames is used to describe the turbulent flame structure directly at the subgrid level. The calculations employ a one-dimensional unsteady flame model that incorporates unsteady strain rate, curvature, and mixture boundary conditions imposed by the resolved scales. The model is used for closure of the subgrid terms in the context of large eddy simulation. Direct numerical simulation (DNS) data from a flame-vortex interaction problem is used for comparison. © Springer Science+Business Media B.V. 2011.

  7. Ignition time of hydrogen-air diffusion flames

    Science.gov (United States)

    Sánchez, Antonio L.; Fernández-Tarrazo, Eduardo; Boivin, Pierre; Liñán, Amable; Williams, Forman A.

    2012-11-01

    The ignition time of hydrogen-air diffusion flames is a quantity of utmost interest in a large number of applications, with implications regarding the viability of supersonic combustion and the safe operation of gas turbines. The underlying chemistry and the associated ignition history are very different depending on the initial temperature and pressure. This article addresses conditions that place the system above the so-called second explosion limit, as is typically the case in SCRAMJET operation, so that a branched-chain explosion characterizes the ignition process. The roles of local radical accumulation, molecular transport, and chemical reaction in nonpremixed ignition are clarified by considering the temporal evolution of an unstrained mixing layer formed between two semi-infinite spaces of hydrogen and air. The problem is formulated in terms of a radical-pool mass fraction, whose evolution in time is studied with a WKB expansion that exploits the disparity of chemical time scales present in the problem, leading to an explicit expression for the ignition time. The applicability of the analytical results for obtaining predictions of ignition distances in supersonic-combustion applications is also considered.

  8. Flame Shapes of Nonbuoyant Laminar Jet Diffusion Flames. Appendix K

    Science.gov (United States)

    Xu, F.; Faeth, G. M.; Urban, D. L. (Technical Monitor); Yuan, Z.-G. (Technical Monitor)

    2000-01-01

    The shapes (flame-sheet and luminous-flame boundaries) of steady nonbuoyant round hydrocarbon-fueled laminar-jet diffusion flames in still and coflowing air were studied both experimentally and theoretically. Flame-sheet shapes were measured from photographs using a CH optical filter to distinguish flame-sheet boundaries in the presence of blue C02 and OH emissions and yellow continuum radiation from soot. Present experimental conditions included acetylene-, methane-, propane-, and ethylene-fueled flames having initial reactant temperatures of 300 K, ambient pressures of 4-50 kPa, jet exit Reynolds number of 3-54, initial air/fuel velocity ratios of 0-9 and luminous flame lengths of 5-55 mm; earlier measurements for propylene- and 1,3-butadiene-fueled flames for similar conditions were considered as well. Nonbuoyant flames in still air were observed at micro-gravity conditions; essentially nonbuoyant flames in coflowing air were observed at small pressures to control effects of buoyancy. Predictions of luminous flame boundaries from soot luminosity were limited to laminar smoke-point conditions, whereas predictions of flame-sheet boundaries ranged from soot-free to smoke-point conditions. Flame-shape predictions were based on simplified analyses using the boundary layer approximations along with empirical parameters to distinguish flame-sheet and luminous-flame (at the laminar smoke point) boundaries. The comparison between measurements and predictions was remarkably good and showed that both flame-sheet and luminous-flame lengths are primarily controlled by fuel flow rates with lengths in coflowing air approaching 2/3 lengths in still air as coflowing air velocities are increased. Finally, luminous flame lengths at laminar smoke-point conditions were roughly twice as long as flame-sheet lengths at comparable conditions due to the presence of luminous soot particles in the fuel-lean region of the flames.

  9. Flame Shapes of Nonbuoyant Laminar Jet Diffusion Flames

    Science.gov (United States)

    Xu, F.; Dai, Z.; Faeth, G. M.; Urban, D. L. (Technical Monitor); Yuan, Z. G. (Technical Monitor)

    2001-01-01

    The shapes (flame-sheet and luminous-flame boundaries) of steady nonbuoyant round hydrocarbon-fueled laminar-jet diffusion flames in still and coflowing air were studied both experimentally and theoretically. Flame-sheet shapes were measured from photographs using a CH optical filter to distinguish flame-sheet boundaries in the presence of blue CO2 and OH emissions and yellow continuum radiation from soot. Present experimental conditions included acetylene-, methane-, propane-, and ethylene-fueled flames having initial reactant temperatures of 300 K, ambient pressures of 4-50 kPa, jet exit Reynolds number of 3-54, initial air/fuel velocity ratios of 0-9 and luminous flame lengths of 5-55 mm; earlier measurements for propylene- and 1,3-butadiene-fueled flames for similar conditions were considered as well. Nonbuoyant flames in still air were observed at micro-gravity conditions; essentially nonbuoyant flames in coflowing air were observed at small pressures to control effects of buoyancy. Predictions of luminous flame boundaries from soot luminosity were limited to laminar smokepoint conditions, whereas predictions of flame-sheet boundaries ranged from soot-free to smokepoint conditions. Flame-shape predictions were based on simplified analyses using the boundary layer approximations along with empirical parameters to distinguish flame-sheet and luminous flame (at the laminar smoke point) boundaries. The comparison between measurements and predictions was remarkably good and showed that both flame-sheet and luminous-flame lengths are primarily controlled by fuel flow rates with lengths in coflowing air approaching 2/3 lengths in still air as coflowing air velocities are increased. Finally, luminous flame lengths at laminar smoke-point conditions were roughly twice as long as flame-sheet lengths at comparable conditions due to the presence of luminous soot particles in the fuel-lean region of the flames.

  10. DC field response of one-dimensional flames using an ionized layer model

    KAUST Repository

    Xiong, Yuan

    2015-11-18

    We develop a simplified model to better explain electric current response when direct current (DC) is applied to a flame. In particular, different current responses have been observed by changing the polarity of the DC in a sub-saturated current regime that results from the presence of ions and electrons in the flame zone. A flame zone was modeled as a thin, ionized layer located in one-dimensional DC electric fields. We derived simplified model-governing equations from species equations by implementing mobility differences dependent on the type of charged particle, particularly between ions and electrons; we performed experiments to substantiate the model. Results showed that the sub-saturated current and local field intensity were significantly influenced by the polarity of the DC because of the combined effect of unequal mobility of charged particles and the position of the ionized layer in the gap relative to two electrodes. When an energized electrode is close to the ionized layer, applying a negative DC causes a more rapid increase in current than by applying a positive DC to the same electrode. Results from our experimental measurement of current using counterflow diffusion flames agreed qualitatively well with the model predictions. A sensitivity analysis using dimensional and non-dimensional parameters also supported the importance of the mobility difference and the relative location of the ionized layer on the electric current response.

  11. Combined Influence of Strain and Heat Loss on Turbulent Premixed Flame Stabilization

    KAUST Repository

    Tay-Wo-Chong, Luis

    2015-11-16

    The present paper argues that the prediction of turbulent premixed flames under non-adiabatic conditions can be improved by considering the combined effects of strain and heat loss on reaction rates. The effect of strain in the presence of heat loss on the consumption speed of laminar premixed flames was quantified by calculations of asymmetric counterflow configurations (“fresh-to-burnt”) with detailed chemistry. Heat losses were introduced by setting the temperature of the incoming stream of products on the “burnt” side to values below those corresponding to adiabatic conditions. The consumption speed decreased in a roughly exponential manner with increasing strain rate, and this tendency became more pronounced in the presence of heat losses. An empirical relation in terms of Markstein number, Karlovitz Number and a non-dimensional heat loss parameter was proposed for the combined influence of strain and heat losses on the consumption speed. Combining this empirical relation with a presumed probability density function for strain in turbulent flows, an attenuation factor that accounts for the effect of strain and heat loss on the reaction rate in turbulent flows was deduced and implemented into a turbulent combustion model. URANS simulations of a premixed swirl burner were carried out and validated against flow field and OH chemiluminescence measurements. Introducing the effects of strain and heat loss into the combustion model, the flame topology observed experimentally was correctly reproduced, with good agreement between experiment and simulation for flow field and flame length.

  12. Premixed conical flame stabilization

    Science.gov (United States)

    Krikunova, A. I.; Son, E. E.; Saveliev, A. S.

    2016-11-01

    In the current work, stabilization of premixed laminar and lean turbulent flames for wide range of flow rates and equivalence ratios was performed. Methane-air mixture was ignited after passing through premixed chamber with beads and grids, and conical nozzle (Bunsen-type burner). On the edge of the nozzle a stabilized body-ring was mounted. Ring geometry was varied to get the widest stable flame parameters. This work was performed as part of the project on experimental investigation of premixed flames under microgravity conditions.

  13. Two-dimensional temperature and carbon dioxide concentration profiles in atmospheric laminar diffusion flames measured by mid-infrared direct absorption spectroscopy at 4.2 μm

    Science.gov (United States)

    Liu, Xunchen; Zhang, Guoyong; Huang, Yan; Wang, Yizun; Qi, Fei

    2018-04-01

    We present a multi-line flame thermometry technique based on mid-infrared direct absorption spectroscopy of carbon dioxide at its v_3 fundamental around 4.2 μm that is particularly suitable for sooting flames. Temperature and concentration profiles of gas phase molecules in a flame are important characteristics to understand its flame structure and combustion chemistry. One of the standard laboratory flames to analyze polycyclic aromatic hydrocarbons (PAH) and soot formation is laminar non-premixed co-flow flame, but PAH and soot introduce artifact to most non-contact optical measurements. Here we report an accurate diagnostic method of the temperature and concentration profiles of CO2 in ethylene diffusion flames by measuring its v_3 vibrational fundamental. An interband cascade laser was used to probe the R-branch bandhead at 4.2 μm, which is highly sensitive to temperature change, free from soot interference and ambient background. Calibration measurement was carried out both in a low-pressure Herriott cell and an atmospheric pressure tube furnace up to 1550 K to obtain spectroscopic parameters for high-temperature spectra. In our co-flow flame measurement, two-dimensional line-of-sight optical depth of an ethylene/N2 laminar sooting flame was recorded by dual-beam absorption scheme. The axially symmetrical attenuation coefficient profile of CO2 in the co-flow flame was reconstructed from the optical depth by Abel inversion. Spatially resolved flame temperature and in situ CO2 volume fraction profiles were derived from the calibrated CO2 spectroscopic parameters and compared with temperature profiles measured by two-line atomic fluorescence.

  14. The application of separated flames in analytical flame spectroscopy.

    Science.gov (United States)

    Kirkbright, G F; West, T S

    1968-07-01

    Premixed hydrocarbon-air flames invariably show two separate reaction zones. In the primary zone, the combustible gas mixture burns principally to carbon monoxide, hydrogen, and water, and in the outer mantle, or secondary diffusion flame, the hot gases burn with atmospheric oxygen to carbon dioxide and water. Teclu [J. Prakt. Chem. 44, 246 (1891)] and Smithells and Ingle [Trans. Chem. Soc. 61, 204 (1892)] independently demonstrated the existence of these two zones in various premixed hydrocarbon-air flames, using the flame separator. This device consists of a wide glass or silica tube fitted over the bunsen type burner to form an extension above the inner burner port. The primary combustion then occurs at the inner burner port, while the pale blue secondary diffusion flame is maintained at the top of the outer glass tube. An alternative method of separation of premixed hydrocarbon-air flames consists of sheathing the flame with an inert gas to lift off or separate the secondary diffusonzone. The interconal zone of flames separated by these methods are extended in length and exhibit very low radiative background. The interconal zone also contains the hottest part of the flame, and can be viewed without interference from radiation produced in a secondary diffusion zone that would normally surround it in separated flames. It is the hot interconal zone of premixed flames that is most frequently employed in analytical flame photometry, because it is in this region that the greatest population of atoms occurs when elements are introduced into the flame by nebulization of solutions of their salts. Thus, separated flames may be employed with advantage in thermal emission, atomic absorption, and atomic fluorescence spectroscopy. This paper describes the separation of the air-acetylene and nitrous oxide-acetylene flames, and some applications of these flames in analytical flame spectroscopy.

  15. Gas turbine flame diagnostic monitor

    Energy Technology Data Exchange (ETDEWEB)

    Morey, W.W.

    1992-09-22

    This patent describes a method for detecting the malfunction of a gas turbine during ignition, start up and under torque load. It comprises: the steps of: optically viewing the entire flame in each combustor of the gas turbine, determining a flame pattern based on electromagnetic radiation from the flame as a function of position in the field of view in each combustor, and comparing the flame pattern of each combustor with predetermined flame patterns, and determining a diagnosis of malfunction associated with one or more combustors of the turbine by the individual and total combustor correlated with the predetermined flame patterns.

  16. Analysis of density wave instability in counter-flow steam generators using STEAMFREQ-X

    International Nuclear Information System (INIS)

    Chan, K.C.; Yadigaroglu, G.

    1986-01-01

    The STEAMFREQ-X computer model was developed to provide a more comprehensive modeling of the different phenomena that are important to stability analysis of counter-flow steam generators. It uses a frequency-domain analysis and considers heat-flux/flow coupling between the primary and secondary fluids in space and time. Predictions by STEAMFREQ-X were compared with data from both a multi-channel liquid-sodium heated steam generator and a set of single pipe test data. Predicted outlet steam qualities at instability thresholds were within 15% of experimental data for all test points. (orig.)

  17. Rubens Flame-Tube Demonstration.

    Science.gov (United States)

    Ficken, George W.; Stephenson, Francis C.

    1979-01-01

    Investigates and explains the phenomenon associated with Rubens flame-tube demonstration, specifically the persistance of flames at regular intervals along the tube for few minutes after the gas is turned off. (GA)

  18. Modelling Detailed-Chemistry Effects on Turbulent Diffusion Flames using a Parallel Solution-Adaptive Scheme

    Science.gov (United States)

    Jha, Pradeep Kumar

    Capturing the effects of detailed-chemistry on turbulent combustion processes is a central challenge faced by the numerical combustion community. However, the inherent complexity and non-linear nature of both turbulence and chemistry require that combustion models rely heavily on engineering approximations to remain computationally tractable. This thesis proposes a computationally efficient algorithm for modelling detailed-chemistry effects in turbulent diffusion flames and numerically predicting the associated flame properties. The cornerstone of this combustion modelling tool is the use of parallel Adaptive Mesh Refinement (AMR) scheme with the recently proposed Flame Prolongation of Intrinsic low-dimensional manifold (FPI) tabulated-chemistry approach for modelling complex chemistry. The effect of turbulence on the mean chemistry is incorporated using a Presumed Conditional Moment (PCM) approach based on a beta-probability density function (PDF). The two-equation k-w turbulence model is used for modelling the effects of the unresolved turbulence on the mean flow field. The finite-rate of methane-air combustion is represented here by using the GRI-Mech 3.0 scheme. This detailed mechanism is used to build the FPI tables. A state of the art numerical scheme based on a parallel block-based solution-adaptive algorithm has been developed to solve the Favre-averaged Navier-Stokes (FANS) and other governing partial-differential equations using a second-order accurate, fully-coupled finite-volume formulation on body-fitted, multi-block, quadrilateral/hexahedral mesh for two-dimensional and three-dimensional flow geometries, respectively. A standard fourth-order Runge-Kutta time-marching scheme is used for time-accurate temporal discretizations. Numerical predictions of three different diffusion flames configurations are considered in the present work: a laminar counter-flow flame; a laminar co-flow diffusion flame; and a Sydney bluff-body turbulent reacting flow

  19. Dynamics of the density of quantized vortex lines in counterflow turbulence: Experimental investigation

    Science.gov (United States)

    Varga, E.; Skrbek, L.

    2018-02-01

    Recently the interest in thermal counterflow of superfluid 4He, the most extensively studied form of quantum turbulence, has been renewed. Particularly, an intense theoretical debate has arisen about what form, if any, of the so-called Vinen equation accurately captures the dynamics of vortex line density, L . We address this problem experimentally, in a 21 cm long channel of square 7 ×7 mm2 cross section. Based on large statistics of second-sound data measured in nonequilibrium square-wave modulated thermally induced counterflow we investigate the phase portrait of the general form of the governing dynamical equation and conclude that for sparse tangles (L ≲105cm-2) all proposed forms of this equation based on the concept of a homogeneous random tangle of quantized vortices provide equally adequate descriptions of the growth of L , while for dense tangles (L >105cm-2) none of them is satisfactory or able to account for the significant slow-down in tangle growth rate as the steady state is approached. We claim, however, that agreement with theory is recovered if the geometrical parameter c2 introduced in numerical studies by K. W. Schwarz [Phys. Rev. B 38, 2398 (1988), 10.1103/PhysRevB.38.2398] is allowed to vary with vortex line density which also greatly improves the prediction of the observed early decay rate.

  20. Isolation of monocytes from whole blood-derived buffy coats by continuous counter-flow elutriation.

    Science.gov (United States)

    Schwanke, Uwe; Nabereit, Anja; Moog, Rainer

    2006-10-01

    Monocytes (MOs) are the most commonly used precursors for the generation of dendritic cells (DCs) in vitro. Continuous counter-flow elutriation represents a promising tool to isolate MOs from white blood cell (WBC) products. Thirty whole blood-derived, AB0-identical buffy coats (BCs) were pooled using sterile technique (n = 5 experiments). For red blood cell (RBC) and polymorphonuclear cell (PMN) depletion, the BC pools were processed in a Cobe Spectra device (Gambro BCT) using the bone marrow program. Subsequently, continuous counter-flow elutriation in an Elutra device (Gambro BCT) was performed to enrich and purify MOs. BC pool volume averaged 1,260 +/- 14 ml containing 7.7 +/- 1.1 x 10(9) MOs. During 107 +/- 7 min, Cobe Spectra operation, the BC pools were processed for several times, and approximately 9,749 +/- 605 ml volume passed the device. Product volume and MO yield averaged 160 +/- 16 ml, and 4.3 +/- 1.3 x 10(9) cells, respectively. Elutra operation was performed within 59 +/- 0 min and yielded 2.5 +/- 0.9 x 10(9) MOs with a purity of 60 +/- 12%. Compared with the Cobe Spectra product cell count, MO recovery by Elutra averaged 59 +/- 10%. Elutriation of MOs from pooled BCs using Elutra exhibited comparatively low recovery and purity rates. This shortcoming may be due to the nature of the source material. Optimization of the elutriation procedure is necessary to improve MO enrichment from BCs.

  1. Flaming on YouTube

    NARCIS (Netherlands)

    Moor, Peter J.; Heuvelman, A.; Verleur, R.

    2010-01-01

    In this explorative study, flaming on YouTube was studied using surveys of YouTube users. Flaming is defined as displaying hostility by insulting, swearing or using otherwise offensive language. Three general conclusions were drawn. First, although many users said that they themselves do not flame,

  2. Decay of counterflow He II turbulence in a finite channel: Possibility of missing links between classical and quantum turbulence

    Czech Academy of Sciences Publication Activity Database

    Skrbek, Ladislav; Gordeev, A. V.; Soukup, F.

    2003-01-01

    Roč. 67, č. 4 (2003), 047302/1-047302/5 ISSN 1063-651X R&D Projects: GA ČR GA202/02/0251 Institutional research plan: CEZ:AV0Z1010914 Keywords : superfluid helium * counterflow * turbulence * decay Subject RIV: BK - Fluid Dynamics Impact factor: 2.202, year: 2003

  3. Development of a non-premix radiant burner. Evaluation of design possibilities

    Energy Technology Data Exchange (ETDEWEB)

    Andersen, P.; Myken, A.N.; Rasmussen, N.B.

    1996-12-31

    The objective of the project period is to: make a study into materials suitable for the NPRB (Non-Premix Radiant Burner); chhose the materials for the construction; make proposals for the design of the NPRB; test the different proposals with a CFD-model (Computational Fluid Dynamics). In pursuit of finding a suitable material it is necessary first to estimate the maximum temperature that will occur in the burner. A realistic temperature was estimated to 2100-2300 K. After the literature study a few materials seemed promising. The final choice was made after having contacted some of the leading producers. One producer could produce burners of one of the suggested materials, zirconia. Several construction ideas for the NPRB have been discussed and some of them tested with a CFD-model. The proposed burner concept has been modified in order to obtain a homogenous temperature distribution, enhance air and gas mixing and reduce the maximum material temperature. The conditions for the CFD-calculations have been as follows: burner height x width: 300 mm x 300 mm; fuel input: 50kW (specific load: 550 kW/m{sup 2}); combustion air temperature: 800 deg. C; furnace temperature: 900 deg. C; excess air: 5%. The most promising way to disbribute the gas in the burner is by using perforated ceramic tubes. The CFD-calculations have been based on ten tubes with an outer diameter of 10 mm, each perforated with 40 1 mm holes. From the CFD-calculations it can be concluded that a cavity for mixing gas and hot air is necessary between two layers of ceramic foam. From the CFD-calculations it also can be concluded that the distance between the gas jets can be increased while the diameter of the jets should be decreased. From the CFD calculations it can be seen that a large amount of unburned fuel will leave the surface of the burner. It is suggested to add an extra ceramic foam to the construction to increase the burnout of the fuel in the burner. This concept has been developed for

  4. Disproportionate entrance length in superfluid flows and the puzzle of counterflow instabilities

    Science.gov (United States)

    Bertolaccini, J.; Lévêque, E.; Roche, P.-E.

    2017-12-01

    Systematic simulations of the two-fluid model of superfluid helium (He-II) encompassing the Hall-Vinen-Bekharevich-Khalatnikov (HVBK) mutual coupling have been performed in two-dimensional pipe counterflows between 1.3 and 1.96 K. The numerical scheme relies on the lattice Boltzmann method. A Boussinesq-like hypothesis is introduced to omit temperature variations along the pipe. In return, the thermomechanical forcings of the normal and superfuid components are fueled by a pressure term related to their mass-density variations under an approximation of weak compressibility. This modeling framework reproduces the essential features of a thermally driven counterflow. A generalized definition of the entrance length is introduced to suitably compare entry effects (of different nature) at opposite ends of the pipe. This definition is related to the excess of pressure loss with respect to the developed Poiseuille-flow solution. At the heated end of the pipe, it is found that the entrance length for the normal fluid follows a classical law and increases linearly with the Reynolds number. At the cooled end, the entrance length for the superfluid is enhanced as compared to the normal fluid by up to one order of magnitude. At this end, the normal fluid flows into the cooling bath of He-II and produces large-scale superfluid vortical motions in the bath that partly re-enter the pipe along its sidewalls before being damped by mutual friction. In the superfluid entry region, the resulting frictional coupling in the superfluid boundary layer distorts the velocity profiles toward tail flattening for the normal fluid and tail raising for the superfluid. Eventually, a simple analytical model of entry effects allows us to re-examine the long-debated thresholds of T 1 and T 2 instabilities in superfluid counterflows. Inconsistencies in the T 1 thresholds reported since the 1960s disappear if an aspect-ratio criterion based on our modeling is used to discard data sets with the

  5. Candle Flames in Microgravity Video

    Science.gov (United States)

    1997-01-01

    This video of a candle flame burning in space was taken by the Candle Flames in Microgravity (CFM) experiment on the Russian Mir space station. It is actually a composite of still photos from a 35mm camera since the video images were too dim. The images show a hemispherically shaped flame, primarily blue in color, with some yellow early int the flame lifetime. The actual flame is quite dim and difficult to see with the naked eye. Nearly 80 candles were burned in this experiment aboard Mir. NASA scientists have also studied how flames spread in space and how to detect fire in microgravity. Researchers hope that what they learn about fire and combustion from the flame ball experiments will help out here on Earth. Their research could help create things such as better engines for cars and airplanes. Since they use very weak flames, flame balls require little fuel. By studying how this works, engineers may be able to design engines that use far less fuel. In addition, microgravity flame research is an important step in creating new safety precautions for astronauts living in space. By understanding how fire works in space, the astronauts can be better prepared to fight it.

  6. Precipitation and Hydrology Experiment Counter-Flow Spectrometer and Impactor Field Campaign Report

    Energy Technology Data Exchange (ETDEWEB)

    Poellot, Michael [University of North Dakota

    2016-03-01

    The U.S. Department of Energy (DOE)’s Atmospheric Radiation Measurement (ARM) Climate Research Facility Aerial Facility (ARM AAF) counter-flow spectrometer and impactor (CSI) probe was flown on the University of North Dakota Cessna Citation research aircraft during the Integrated Precipitation and Hydrology Experiment (IPHEX). The field campaign took place during May and June of 2014 over North Carolina and its coastal waters as part of a National Aeronautics and Space Administration (NASA) Global Precipitation Measurement validation campaign. The CSI was added to the Citation instrument suite to support the involvement of Jay Mace through the NASA Advanced Composition Explorer (ACE) satellite program and flights of the NASA ER-2 aircraft, which is a civilian version of the Air Force’s U2-S reconnaissance platform. The ACE program funded extra ER-2 flights to focus on clouds that are weakly precipitating, which are also of interest to the Atmospheric System Research program sponsored by DOE.

  7. Three-Dimensional Model for Electrospinning Processes in Controlled Gas Counterflow

    Science.gov (United States)

    2016-01-01

    We study the effects of a controlled gas flow on the dynamics of electrified jets in the electrospinning process. The main idea is to model the air drag effects of the gas flow by using a nonlinear Langevin-like approach. The model is employed to investigate the dynamics of electrified polymer jets at different conditions of air drag force, showing that a controlled gas counterflow can lead to a decrease of the average diameter of electrospun fibers, and potentially to an improvement of the quality of electrospun products. We probe the influence of air drag effects on the bending instabilities of the jet and on its angular fluctuations during the process. The insights provided by this study might prove useful for the design of future electrospinning experiments and polymer nanofiber materials. PMID:26859532

  8. Characterisation and airborne deployment of a new counterflow virtual impactor inlet

    Directory of Open Access Journals (Sweden)

    T. Shingler

    2012-06-01

    Full Text Available A new counterflow virtual impactor (CVI inlet is introduced with details of its design, laboratory characterisation tests and deployment on an aircraft during the 2011 Eastern Pacific Emitted Aerosol Cloud Experiment (E-PEACE. The CVI inlet addresses three key issues in previous designs; in particular, the inlet operates with: (i negligible organic contamination; (ii a significant sample flow rate to downstream instruments (∼15 l min−1 that reduces the need for dilution; and (iii a high level of accessibility to the probe interior for cleaning. Wind tunnel experiments characterised the cut size of sampled droplets and the particle size-dependent transmission efficiency in various parts of the probe. For a range of counter-flow rates and air velocities, the measured cut size was between 8.7–13.1 μm. The mean percentage error between cut size measurements and predictions from aerodynamic drag theory is 1.7%. The CVI was deployed on the Center for Interdisciplinary Remotely Piloted Aircraft Studies (CIRPAS Twin Otter for thirty flights during E-PEACE to study aerosol-cloud-radiation interactions off the central coast of California in July and August 2011. Results are reported to assess the performance of the inlet including comparisons of particle number concentration downstream of the CVI and cloud drop number concentration measured by two independent aircraft probes. Measurements downstream of the CVI are also examined from one representative case flight coordinated with shipboard-emitted smoke that was intercepted in cloud by the Twin Otter.

  9. Incomplete combustion in nonadiabatic premixed gas flames

    Science.gov (United States)

    Kagan, L.; Sivashinsky, G.

    1996-06-01

    The inward propagating spherical flame and burner stabilized Bunsen-type flame of low-Lewis-number premixtures are studied numerically. It is shown that reduction of the reaction rate induced by the flame stretch makes the flame vulnerable to the radiative heat losses which may well result in a partial or complete extinction of the flame.

  10. Flame Retardant Epoxy Resins

    Science.gov (United States)

    Thompson, C. M.; Smith, J. G., Jr.; Connell, J. W.; Hergenrother, P. M.; Lyon, R. E.

    2004-01-01

    As part of a program to develop fire resistant exterior composite structures for future subsonic commercial aircraft, flame retardant epoxy resins are under investigation. Epoxies and their curing agents (aromatic diamines) containing phosphorus were synthesized and used to prepare epoxy formulations. Phosphorus was incorporated within the backbone of the epoxy resin and not used as an additive. The resulting cured epoxies were characterized by thermogravimetric analysis, propane torch test, elemental analysis and microscale combustion calorimetry. Several formulations showed excellent flame retardation with phosphorous contents as low as 1.5% by weight. The fracture toughness of plaques of several cured formulations was determined on single-edge notched bend specimens. The chemistry and properties of these new epoxy formulations are discussed.

  11. Antimony: a flame fighter

    Science.gov (United States)

    Wintzer, Niki E.; Guberman, David E.

    2015-01-01

    Antimony is a brittle, silvery-white semimetal that conducts heat poorly. The chemical compound antimony trioxide (Sb2O3) is widely used in plastics, rubbers, paints, and textiles, including industrial safety suits and some children’s clothing, to make them resistant to the spread of flames. Also, sodium antimonate (NaSbO3) is used during manufacturing of high-quality glass, which is found in cellular phones.

  12. Validation of unsteady flamelet models for non-premixed turbulent combustion with intermittency

    International Nuclear Information System (INIS)

    Bourlioux, A.; Volkov, O.

    2003-01-01

    Flamelets play an important role as subgrid models in large eddy simulations of turbulent flames: they are based on a one-dimensional steady asymptotic solution for the flame. The focus of the present study is to validate their use when unsteadiness and multidimensional effects are present, as to be expected for turbulent flows. To shortcut the prohibitively expansive step of solving the complete Navier-Stokes equations in the turbulent regime, a synthetic turbulent-like flow field is specified, which allows for extensive yet affordable simulations and analysis. The flow field consists of a simple steady horizontal shear with a time-periodic vertical sweep. Despite the simplicity of the flow field, the passive scalar response displays qualitatively many characteristics observed in experiments with fully turbulent flow, in particular, in terms of the strong departure from Gaussianity of its probability distribution function. The same set-up is utilized for the reactive case in order to generate challenging conditions to test the robustness of unsteady versions of the laminar flamelet models. We analyze the asymptotic behavior of the models for a large range of Damkoehler and Peclet numbers in the presence of intermittency and confirm for those demanding test-cases the good performance of the models that had been observed for less-demanding one-dimensional test-cases with smooth time behavior. In particular, the performance of the models is quite satisfactory in the intermediate regimes where neither the very fast nor the very slow chemistry asymptotic approximation would be appropriate. (author)

  13. Experimental Investigations Of The Influence Of Pressure On Critical Extinction Conditions Of Laminar Nonpremixed Flames Burning Condensed Hydrocarbon Fuels, Jet Fuels, And Surrogates

    Science.gov (United States)

    2014-10-25

    and the advancement of next-generation engines and power plants . However, due to the hundreds of chemical species found in practical fuels and the...the experimental testing of fuels with high boiling points for which it is difficult to avoid pyrolysis reactions during fuel vaporization [22]. Figure

  14. Electric Fields for Flame Extinguishment

    Science.gov (United States)

    1993-03-01

    ethylene-air and methane-air flames, the application of a DC field of 0.5 kV/cm increased the burning velocity by close to a factor of two. Salamandra and...flame surface area and thus the velocity, but Jaggers and von Engel also saw physical perturbations in flame fronts with no electric field. Salamandra ...Conductivity in Propane-Air Flames by Using Rydberg State Stark Spectroscopy," Proc. Combustion Inst., Fall (1990). 12. Salamandra , G.D., and Mairov, N.I

  15. Subwoofer and nanotube butterfly acoustic flame extinction

    NARCIS (Netherlands)

    Aliev, Ali E.; Mayo, Nathanael K.; Baughman, Ray H.; Mills, Brent T.; Habtour, Ed

    2017-01-01

    Nonchemical flame control using acoustic waves from a subwoofer and a lightweight carbon nanotube thermoacoustic projector was demonstrated. The intent was to manipulate flame intensity, direction and propagation. The mechanisms of flame suppression using low frequency acoustic waves were discussed.

  16. Investigation into periodic process of hydrogen isotope separation by counterflow method in the hydrogen-palladium system

    International Nuclear Information System (INIS)

    Andreev, B.M.; Selivanenko, I.L.; Vedeneev, A.I.; Golubkov, A.N.; Tenyaev, B.N.

    1999-01-01

    The key diagram and results of the investigation into working conditions of the pilot plant for hydrogen isotope separation embodying the concept of continuous counterflow separation in the hydrogen-palladium system are shown. The counterflow of phases in the plant is attained under the motion of palladium solid hydride phase relative to stationary blocks of flow rotation. The column separator is defined as section type one. The plant performs in periodic regime with accumulating vessels for light and heavy components of the separated mixture. Maximum concentration of the separated tritium ranged up to ∼ 96 % in the experiments of the deuterium-tritium separation. Minimum concentration of the residual tritium in the mixture ranged up to ∼ 0.1 %. The plant provides to reprocessing 4.5 moles of the gas a day [ru

  17. Counter-flow elutriation of clinical peripheral blood mononuclear cell concentrates for the production of dendritic and T cell therapies

    OpenAIRE

    Stroncek, David F; Fellowes, Vicki; Pham, Chauha; Khuu, Hanh; Fowler, Daniel H; Wood, Lauren V; Sabatino, Marianna

    2014-01-01

    Introduction Peripheral blood mononuclear cells (PBMC) concentrates collected by apheresis are frequently used as starting material for cellular therapies, but the cell of interest must often be isolated prior to initiating manufacturing. Study design and methods The results of enriching 59 clinical PBMC concentrates for monocytes or lymphocytes from patients with solid tumors or multiple myeloma using a commercial closed system semi-automated counter-flow elutriation instrument (Elutra, Teru...

  18. Heat transfer reduction using combination of spike and counterflow jet on blunt body at high Mach number flow

    Science.gov (United States)

    Eghlima, Z.; Mansour, K.; Fardipour, K.

    2018-02-01

    Heat transfer reduction around blunt bodies is one of the important issues in the field of high speed aerodynamics. Using of spikes and counterflow jets each of them separately for reducing of drag force and heat transfer is well known. The present work is description of flow field around a hemispherical nose cylinder with a combination of spike and counterflow jet at free stream of Mach number of 6. The air gas was injected through the nozzle at the nose of the hemispherical model at sonic speed. In this numerical analysis, axisymmetric Reynolds-averaged Navier-Stokes equations was solved by k-ω (SST) turbulence model. The grid study was done and the results are validated with experimental results for spiked body without jet condition. Then the results presented for different lengths of spike and different pressures of counterflow jets. The results show a significant reduction in the peak heat transfer about 60%-78% for different models compared to the spherical cylinder model without any jet and spike. Furthermore, also our results indicate that the heat transfer reduction is increased even more with increasing of the length of the spike.

  19. Dynamics and structure of stretched flames

    Energy Technology Data Exchange (ETDEWEB)

    Law, C.K. [Princeton Univ., NJ (United States)

    1993-12-01

    This program aims to gain fundamental understanding on the structure, geometry, and dynamics of laminar premixed flames, and relate these understanding to the practical issues of flame extinction and stabilization. The underlying fundamental interest here is the recent recognition that the response of premixed flames can be profoundly affected by flame stretch, as manifested by flow nonuniformity, flame curvature, and flame/flow unsteadiness. As such, many of the existing understanding on the behavior of premixed flames need to be qualitatively revised. The research program consists of three major thrusts: (1) detailed experimental and computational mapping of the structure of aerodynamically-strained planar flames, with emphasis on the effects of heat loss, nonequidiffusion, and finite residence time on the flame thickness, extent of incomplete reaction, and the state of extinction. (2) Analytical study of the geometry and dynamics of stretch-affected wrinkled flame sheets in simple configurations, as exemplified by the Bunsen flame and the spatially-periodic flame, with emphasis on the effects of nonlinear stretch, the phenomena of flame cusping, smoothing, and tip opening, and their implications on the structure and burning rate of turbulent flames. (3) Stabilization and blowoff of two-dimensional inverted premixed and stabilization and determining the criteria governing flame blowoff. The research is synergistically conducted through the use of laser-based diagnostics, computational simulation of the flame structure with detailed chemistry and transport, and mathematical analysis of the flame dynamics.

  20. Turbulent Flame Speed and Self Similarity of Expanding Premixed Flames

    Science.gov (United States)

    Chaudhuri, Swetaprovo; Wu, Fujia; Zhu, Delin; Law, Chung

    2011-11-01

    In this study we present experimental turbulent flame speed data measured in constant-pressure expanding turbulent flames, propagating in nearly homogenous isotropic turbulence, in a dual-chamber, fan-stirred vessel. The cold flow is characterized by high speed particle image velocimetry while the flame propagation rate is obtained by tracking high speed Schlieren images of unity Lewis number methane-air flames over wide ranges of pressure and turbulence intensity. It is found that the normalized turbulent flame speed as a function of the average radius scales as a turbulent Reynolds number to the one-half power, where the average radius is the length scale and thermal diffusivity is the transport property, thus showing self-similar propagation. Utilizing this dependence it is found that the turbulent flame speeds from expanding flames and those from Bunsen geometries can be scaled by a single parameter: the turbulent Reynolds number utilizing recent theoretical results obtained by spectral closure of the G equation, after correcting for gas expansion effects.

  1. Application of a robust and efficient Lagrangian particle scheme to soot transport in turbulent flames

    KAUST Repository

    Attili, Antonio

    2013-09-01

    A Lagrangian particle scheme is applied to the solution of soot dynamics in turbulent nonpremixed flames. Soot particulate is described using a method of moments and the resulting set of continuum advection-reaction equations is solved using the Lagrangian particle scheme. The key property of the approach is the independence between advection, described by the movement of Lagrangian notional particles along pathlines, and internal aerosol processes, evolving on each notional particle via source terms. Consequently, the method overcomes the issues in Eulerian grid-based schemes for the advection of moments: errors in the advective fluxes pollute the moments compromising their realizability and the stiffness of source terms weakens the stability of the method. The proposed scheme exhibits superior properties with respect to conventional Eulerian schemes in terms of stability, accuracy, and grid convergence. Taking into account the quality of the solution, the Lagrangian approach can be computationally more economical than commonly used Eulerian schemes as it allows the resolution requirements dictated by the different physical phenomena to be independently optimized. Finally, the scheme posseses excellent scalability on massively parallel computers. © 2013 Elsevier Ltd.

  2. Large Eddy Simulation of Autoignition in a Turbulent Hydrogen Jet Flame Using a Progress Variable Approach

    Directory of Open Access Journals (Sweden)

    Rohit Kulkarni

    2012-01-01

    Full Text Available The potential of a progress variable formulation for predicting autoignition and subsequent kernel development in a nonpremixed jet flame is explored in the LES (Large Eddy Simulation context. The chemistry is tabulated as a function of mixture fraction and a composite progress variable, which is defined as a combination of an intermediate and a product species. Transport equations are solved for mixture fraction and progress variable. The filtered mean source term for the progress variable is closed using a probability density function of presumed shape for the mixture fraction. Subgrid fluctuations of the progress variable conditioned on the mixture fraction are neglected. A diluted hydrogen jet issuing into a turbulent coflow of preheated air is chosen as a test case. The model predicts ignition lengths and subsequent kernel growth in good agreement with experiment without any adjustment of model parameters. The autoignition length predicted by the model depends noticeably on the chemical mechanism which the tabulated chemistry is based on. Compared to models using detailed chemistry, significant reduction in computational costs can be realized with the progress variable formulation.

  3. Mechanistic aspects of ionic reactions in flames

    DEFF Research Database (Denmark)

    Egsgaard, H.; Carlsen, L.

    1993-01-01

    Some fundamentals of the ion chemistry of flames are summarized. Mechanistic aspects of ionic reactions in flames have been studied using a VG PlasmaQuad, the ICP-system being substituted by a simple quartz burner. Simple hydrocarbon flames as well as sulfur-containing flames have been investigated...

  4. Unsteady-state analysis of a counter-flow dew point evaporative cooling system

    KAUST Repository

    Lin, J.

    2016-07-19

    Understanding the dynamic behavior of the dew point evaporative cooler is crucial in achieving efficient cooling for real applications. This paper details the development of a transient model for a counter-flow dew point evaporative cooling system. The transient model approaching steady conditions agreed well with the steady state model. Additionally, it is able to accurately predict the experimental data within 4.3% discrepancy. The transient responses of the cooling system were investigated under different inlet air conditions. Temporal temperature and humidity profiles were analyzed for different transient and step responses. The key findings from this study include: (1) the response trend and settling time is markedly dependent on the inlet air temperature, humidity and velocity; (2) the settling time of the transient response ranges from 50 s to 300 s when the system operates under different inlet conditions; and (3) the average transient wet bulb effectiveness (1.00–1.06) of the system is observed to be higher than the steady state wet bulb effectiveness (1.01) for our range of study. © 2016 Elsevier Ltd

  5. Experimental and Numerical Design and Optimization of a Counter-Flow Heat Exchanger

    Directory of Open Access Journals (Sweden)

    Bahrami Salman

    2018-01-01

    Full Text Available A new inexpensive counter-flow heat exchanger has been designed and optimized for a vapor-compression cooling system in this research. The main aim is to experimentally and numerically evaluate the effect of an internal heat exchanger (IHX adaptation in an automotive air conditioning system. In this new design of IHX, the high-pressure liquid passes through the central channel and the low-pressure vapor flows in several parallel channels in the opposite direction. The experimental set-up has been made up of original components of the air conditioning system of a medium sedan car, specially designed and built to analyze vehicle A/C equipment under real operating conditions. The results show that this compact IHX may achieve up to 10% of the evaporator capacity while low pressure drop will be imposed on this refrigeration cycle. Also, they confirm considerable decrease of compressor power consumption (CPC, which is intensified at higher evaporator air flow. A significant improvement of the coefficient of performance (COP is achieved with the IHX employment too. The influence of operating conditions has been also discussed in this paper. Finally, numerical analyses have been briefly presented, which bring more details of the flow behavior and heat transfer phenomena, and help to determine the optimal arrangement of channels.

  6. Studying the process following small steam leaks into sodium using the counterflow steam generator model

    International Nuclear Information System (INIS)

    Kozlov, F.A.; Sergeev, G.P.; Volchkov, L.G.; Sednev, A.P.; Makarov, V.M.; Tonov, B.I.

    1982-01-01

    Peculiarities of hydrodynamic conditions arising in a defective tube of the counterflow steam generator following water leaks into the sodium have been studied using suitable models made of 12Kh18N10T and 10Kh2M steels. Data on the rate of the steam leaks spontaneous evolution and corrosive effect on the opposite wall of the tube are obtained as a function of the leak position and sizes. On the basis of the analysis of the experimental results a conclusion is drawn that two stages are distinguished during the leak spontaneous evolution. Changes in the leak sizes occur gradually and remain small during the first stage. The leak increases quickly and exceeds the initial level more than by two orders during the second stage. The results of metallographlic analysis of the tube steels carried out after the experiments confirm the earlier obtianed data on the presence of inter. granular interaction in 12Kh18N10T steel following the effect of of the water-to-sodium reaction products, and on a preferentially frontal type of 10Kh2M steel corrosion

  7. Study on dew point evaporative cooling system with counter-flow configuration

    KAUST Repository

    Lin, J.

    2015-12-18

    Dew point evaporative cooling has great potential as a disruptive process for sensible cooling of air below its entering wet bulb temperature. This paper presents an improved mathematical model for a single-stage dew point evaporative cooler in a counter-flow configuration. Longitudinal heat conduction and mass diffusion of the air streams, channel plate and water film, as well as the temperature difference between the plate and water film, are accounted for in the model. Predictions of the product air temperature are validated using three sets of experimental data within a discrepancy of 4%. The cooler’s heat and mass transfer process is analyzed in terms of its cooling capacity intensity, water evaporation intensity, and overall heat transfer coefficient along the channel. Parametric studies are conducted at different geometric and operating conditions. For the conditions evaluated, the study reveals that (1) the saturation point of the working air occurs at a fixed point regardless of the inlet air conditions, and it is mainly influenced by the working air ratio and channel height; (2) the intensity of the water evaporation approaches a minimum at 0.2 to 0.3m from the entrance; (3) the wet channel can be separated into two zones, and the overall heat transfer coefficient is above 100W/(m2·K) after the temperature of water film becomes higher than the working air temperature.

  8. Flame spraying of polymers

    International Nuclear Information System (INIS)

    Varacalle, D.J. Jr.; Zeek, D.P.; Couch, K.W.; Benson, D.M.; Kirk, S.M.

    1997-01-01

    Statistical design-of-experiment studies of the thermal spraying of polymer powders are presented. Studies of the subsonic combustion (i.e., Flame) process were conducted in order to determine the quality and economics of polyester and urethane coatings. Thermally sprayed polymer coatings are of interest to several industries for anticorrosion applications, including the chemical, automotive, and aircraft industries. In this study, the coating design has been optimized for a site-specific application using Taguchi-type fractional-factorial experiments. Optimized coating designs are presented for the two powder systems. A substantial range of thermal processing conditions and their effect on the resultant polymer coatings is presented. The coatings were characterized by optical metallography, hardness testing, tensile testing, and compositional analysis. Characterization of the coatings yielded the thickness, bond strength, Knoop microhardness, roughness, deposition efficiency, and porosity. Confirmation testing was accomplished to verify the coating designs

  9. Electrical Aspects of Impinging Flames

    Science.gov (United States)

    Chien, Yu-Chien

    This dissertation examines the use of electric fields as one mechanism for controlling combustion as flames are partially extinguished when impinging on nearby surfaces. Electrical aspects of flames, specifically, the production of chemi-ions in hydrocarbon flames and the use of convective flows driven by these ions, have been investigated in a wide range of applications in prior work but despite this fairly comprehensive effort to study electrical aspects of combustion, relatively little research has focused on electrical phenomena near flame extinguishment, nor for flames near impingement surfaces. Electrical impinging flames have complex properties under global influences of ion-driven winds and flow field disturbances from the impingement surface. Challenges of measurements when an electric field is applied in the system have limited an understanding of changes to the flame behavior and species concentrations caused by the field. This research initially characterizes the ability of high voltage power supplies to respond on sufficiently short time scales to permit real time electrical flame actuation. The study then characterizes the influence of an electric field on the impinging flame shape, ion current and flow field of the thermal plume associated with the flame. The more significant further examinations can be separated into two parts: 1) the potential for using electric fields to control the release of carbon monoxide (CO) from surface-impinging flames, and 2) an investigation of controlling electrically the heat transfer to a plate on which the flame impinges. Carbon monoxide (CO) results from the incomplete oxidation of hydrocarbon fuels and, while CO can be desirable in some syngas processes, it is usually a dangerous emission from forest fires, gas heaters, gas stoves, or furnaces where insufficient oxygen in the core reaction does not fully oxidize the fuel to carbon dioxide and water. Determining how carbon monoxide is released and how heat transfer

  10. Neurotoxicity of brominated flame retardants

    Science.gov (United States)

    Polybrominated diphenyl ethers (PBDEs) have been commonly used as commercial flame retardants in a variety of products including plastics and textiles. Despite their decreasing usage worldwide, congeners continue to accumulate in the environment, including soil, dust, food, anima...

  11. Flame stabilization and mixing characteristics in a Stagnation Point Reverse Flow combustor

    Science.gov (United States)

    Bobba, Mohan K.

    A novel combustor design, referred to as the Stagnation Point Reverse-Flow (SPRF) combustor, was recently developed that is able to operate stably at very lean fuel-air mixtures and with low NOx emissions even when the fuel and air are not premixed before entering the combustor. The primary objective of this work is to elucidate the underlying physics behind the excellent stability and emissions performance of the SPRF combustor. The approach is to experimentally characterize velocities, species mixing, heat release and flame structure in an atmospheric pressure SPRF combustor with the help of various optical diagnostic techniques: OH PLIF, chemiluminescence imaging, PIV and Spontaneous Raman Scattering. Results indicate that the combustor is primarily stabilized in a region downstream of the injector that is characterized by low average velocities and high turbulence levels; this is also the region where most of the heat release occurs. High turbulence levels in the shear layer lead to increased product entrainment levels, elevating the reaction rates and thereby enhancing the combustor stability. The effect of product entrainment on chemical timescales and the flame structure is illustrated with simple reactor models. Although reactants are found to burn in a highly preheated (1300 K) and turbulent environment due to mixing with hot product gases, the residence times are sufficiently long compared to the ignition timescales such that the reactants do not autoignite. Turbulent flame structure analysis indicates that the flame is primarily in the thin reaction zones regime throughout the combustor, and it tends to become more flamelet like with increasing distance from the injector. Fuel-air mixing measurements in case of non-premixed operation indicate that the fuel is shielded from hot products until it is fully mixed with air, providing nearly premixed performance without the safety issues associated with premixing. The reduction in NOx emissions in the SPRF

  12. The effects of laser-sheet thickness on dissipation measurements in turbulent non-reacting jets and jet flames

    International Nuclear Information System (INIS)

    Kaiser, Sebastian A; Frank, Jonathan H

    2011-01-01

    The effects of laser-sheet thickness on planar laser measurements of scalar gradients in turbulent flows are studied. Experiments are performed in the near field of a turbulent, non-premixed, axisymmetric jet flame and in the near field of a non-reacting, isothermal turbulent jet. Laser Rayleigh scattering provides two-dimensional measurements of the instantaneous temperature and mixture fraction fields in the flame and non-reacting jet, respectively. The effect of spatial resolution on measurements of the mean dissipation and the power spectral density of axial temperature and mixture-fraction gradients is examined. The effect of varying the laser-sheet thickness is compared to that of spatial filtering within the image plane. Measurements of the mean dissipation and power spectral density are significantly less sensitive to resolution degradation in the non-differentiated dimensions than in the differentiated dimension. For example, on the jet flame centreline, the dissipation-cut-off microscale, which is determined from the measured power spectral density, is overestimated by 9% when the beam-waist thickness is increased from a 1/e-squared width of 160 µm to 624 µm. In contrast, spatial filtering along the direction of differentiation with a smoothing kernel of 624 µm width produces a bias of 76% in the cut-off microscale. These results experimentally confirm the theoretical analysis of previous studies. A simple spatial model illustrates the origin of this difference and approximately predicts its magnitude for both planar and line measurements. A criterion for matching in-plane and out-of-plane resolution is established. For many planar gradient measurements, considerably less out-of-plane resolution is needed than in-plane resolution. The combined effects of noise and spatial averaging on the dissipation measurements are also briefly examined

  13. Investigation of Counter-Flow in a Heat Pipe-Thermoelectric Generator (HPTEG)

    Science.gov (United States)

    Remeli, Muhammad Fairuz; Singh, Baljit; Affandi, Nor Dalila Nor; Ding, Lai Chet; Date, Abhijit; Akbarzadeh, Aliakbar

    2017-05-01

    This study explores a method of generating electricity while recovering waste heat through the integration of heat pipes and thermoelectric generators (i.e. HPTEG system). The simultaneous waste heat recovery and power generation processes are achieved without the use of any moving parts. The HPTEG system consists of bismuth telluride thermoelectric generators (TEG), which are sandwiched between two finned pipes to achieve a temperature gradient across the TEG for electricity generation. A counter-flow heat exchanger was built using two separate air ducts. The air ducts were thermally coupled using the HPTEG modules. The evaporator section of the heat pipe absorbed the waste heat in a hot air duct. The heat was then transferred across the TEG surfaces. The condenser section of the HPTEG collected the excess heat from the TEG cold side before releasing it to the cold air duct. A 2-kW electrical heater was installed in the hot air duct to simulate the exhaust gas. An air blower was installed at the inlet of each duct to direct the flow of air into the ducts. A theoretical model was developed for predicting the performance of the HPTEG system using the effectiveness-number of transfer units method. The developed model was able to predict the thermal and electrical output of the HPTEG, along with the rate of heat transfer. The results showed that by increasing the cold air velocity, the effectiveness of the heat exchanger was able to be increased from approximately 52% to 58%. As a consequence of the improved heat transfer, maximum power output of 4.3 W was obtained.

  14. Emissions of NO and CO from counterflow combustion of CH4 under MILD and oxyfuel conditions

    International Nuclear Information System (INIS)

    Cheong, Kin-Pang; Li, Pengfei; Wang, Feifei; Mi, Jianchun

    2017-01-01

    This paper reports on the NO and CO emission characteristics of counterflow combustion of methane simulated under MILD or/and oxyfuel conditions. Simulations using CHEMKIN are conducted for various injection conditions of fuel and oxidizer. Note that the terms “oxyfuel”, “MILD-N 2 ” and “MILD-CO 2 ” combustion adopted hereafter represent the conventional oxy-combustion and those MILD combustions diluted by N 2 and CO 2 , respectively. It is observed that the NO emission of MILD-CO 2 combustion is ultra-low for all cases of investigation, even when increasing the combustion temperature up to 2000 K or adding more N 2 (up to 20%) to either the fuel stream (to simulate nitrogen-containing fuels like biomass) or the oxidizer stream (to simulate the air-ingress). A higher temperature allowed under MILD-CO 2 combustion suggests the improvement of energy efficiency for the MILD combustion technology. Moreover, the presence of steam in the oxidant reduces both NO and CO emissions of combustion for all cases. The relative importance analysis reveals that the N 2 O-intermediate mechanism for producing NO prevails in MILD-CO 2 combustion while the prompt and thermal mechanisms predominate MILD-N 2 and oxyfuel combustion, respectively. In addition, the sensitivity analysis identifies those main reactions that play important roles for the NO emission under these combustion conditions. - Highlights: • Assessing the NO and CO emissions from MILD combustion diluted by CO 2 . • Examining the possibility of higher combustion intensity in MILD-CO 2 combustion than in MILD-N 2 combustion. • Differentiating the contributions from each NO mechanism to the total NO emission. • Revealing major NO mechanisms under different combustion conditions. • Better understanding the NO formation mechanisms under MILD combustion.

  15. Optimized processing of growth factor mobilized peripheral blood CD34+ products by counterflow centrifugal elutriation.

    Science.gov (United States)

    Tran, Chy-Anh; Torres-Coronado, Monica; Gardner, Agnes; Gu, Angel; Vu, Hieu; Rao, Anitha; Cao, Lan-Feng; Ahmed, Amira; Digiusto, David

    2012-05-01

    Cell separation by counterflow centrifugal elutriation has been described for the preparation of monocytes for vaccine applications, but its use in other current good manufacturing practice (cGMP) operations has been limited. In this study, growth factor-mobilized peripheral blood progenitor cell products were collected from healthy donors and processed by elutriation using a commercial cell washing device. Fractions were collected for each product as per the manufacturer's instructions or using a modified protocol developed in our laboratory. Each fraction was analyzed for cell count, viability, and blood cell differential. Our data demonstrate that, using standard elutriation procedures, >99% of red blood cells and platelets were removed from apheresis products with high recoveries of total white blood cells and enrichment of CD34+ cells in two of five fractions. With modification of the basic protocol, we were able to collect all of the CD34+ cells in a single fraction. The CD34-enriched fractions were formulated, labeled with a ferromagnetic antibody to CD34, washed using the Elutra device, and transferred directly to a magnetic bead selection device for further purification. CD34+ cell purities from the column were extremely high (98.7 ± 0.9%), and yields were typical for the device (55.7 ± 12.3%). The processes were highly automated and closed from receipt of the apheresis product through formulation of target-enriched cell fractions. Thus, elutriation is a feasible method for the initial manipulations associated with primary blood cell therapy products and supports cGMP and current good tissue practice-compliant cell processing.

  16. Study on dew point evaporative cooling system with counter-flow configuration

    International Nuclear Information System (INIS)

    Lin, J.; Thu, K.; Bui, T.D.; Wang, R.Z.; Ng, K.C.; Chua, K.J.

    2016-01-01

    Highlights: • Numerical model for a dew point evaporative cooler verified with experiments. • Saturation point of the working air is independent of the inlet air conditions. • The intensity of cooling capacity and water evaporation are studied. • The overall heat transfer coefficient for the working air is analyzed. • The conditions to achieve sub-wet bulb cooling are examined. - Abstract: Dew point evaporative cooling has great potential as a disruptive process for sensible cooling of air below its entering wet bulb temperature. This paper presents an improved mathematical model for a single-stage dew point evaporative cooler in a counter-flow configuration. Longitudinal heat conduction and mass diffusion of the air streams, channel plate and water film, as well as the temperature difference between the plate and water film, are accounted for in the model. Predictions of the product air temperature are validated using three sets of experimental data within a discrepancy of 4%. The cooler’s heat and mass transfer process is analyzed in terms of its cooling capacity intensity, water evaporation intensity, and overall heat transfer coefficient along the channel. Parametric studies are conducted at different geometric and operating conditions. For the conditions evaluated, the study reveals that (1) the saturation point of the working air occurs at a fixed point regardless of the inlet air conditions, and it is mainly influenced by the working air ratio and channel height; (2) the intensity of the water evaporation approaches a minimum at 0.2 to 0.3 m from the entrance; (3) the wet channel can be separated into two zones, and the overall heat transfer coefficient is above 100 W/(m 2 ·K) after the temperature of water film becomes higher than the working air temperature.

  17. Flame analysis using image processing techniques

    Science.gov (United States)

    Her Jie, Albert Chang; Zamli, Ahmad Faizal Ahmad; Zulazlan Shah Zulkifli, Ahmad; Yee, Joanne Lim Mun; Lim, Mooktzeng

    2018-04-01

    This paper presents image processing techniques with the use of fuzzy logic and neural network approach to perform flame analysis. Flame diagnostic is important in the industry to extract relevant information from flame images. Experiment test is carried out in a model industrial burner with different flow rates. Flame features such as luminous and spectral parameters are extracted using image processing and Fast Fourier Transform (FFT). Flame images are acquired using FLIR infrared camera. Non-linearities such as thermal acoustic oscillations and background noise affect the stability of flame. Flame velocity is one of the important characteristics that determines stability of flame. In this paper, an image processing method is proposed to determine flame velocity. Power spectral density (PSD) graph is a good tool for vibration analysis where flame stability can be approximated. However, a more intelligent diagnostic system is needed to automatically determine flame stability. In this paper, flame features of different flow rates are compared and analyzed. The selected flame features are used as inputs to the proposed fuzzy inference system to determine flame stability. Neural network is used to test the performance of the fuzzy inference system.

  18. The flaming funis.

    Science.gov (United States)

    Young, William W; Dedam, Jean-Paul; Conley, Sarah; Wickner, Paige

    2004-08-01

    The authors observed a Nicaraguan traditional birth attendant burn the fetal end of the umbilical cord with camphor. They review this practice and reflect on the role of foreign medical volunteers in the developing world. There is a long history to the use of camphor in rituals and medicine. No print references to burning the umbilical cord with camphor, its effectiveness, or its safety could be identified. Interviews with Nicaraguan traditional birth attendants revealed that the practice is passed from generation to generation and that it is believed to decrease infections through the medicinal properties of camphor as well as the flame it produces. It is continued in modern times because it is easy and inexpensive and because there are no clearly better and sustainable alternatives available. Gradual and culturally sensitive modernization to improve the health for mothers and babies is appropriate, but it will be a slow process. Health care volunteers in the developing world struggle with doing the best they can despite the limited resources and sometimes the local traditions. Volunteering as a medical worker in the developing world provides inspiring rewards, teaches powerful lessons, and exposes challenging conflicts.

  19. Large Eddy Simulation of Flame Flashback in Swirling Premixed Flames

    Science.gov (United States)

    Lietz, Christopher; Raman, Venkatramanan

    2014-11-01

    In the design of high-hydrogen content gas turbines for power generation, flashback of the turbulent flame by propagation through the low velocity boundary layers in the premixing region is an operationally dangerous event. Predictive models that could accurately capture the onset and subsequent behavior of flashback would be indispensable in gas turbine design. The large eddy simulation (LES) approach is used here to model this process. The goal is to examine the validity of a probability distribution function (PDF) based model in the context of a lean premixed flame in a confined geometry. A turbulent swirling flow geometry and corresponding experimental data is used for validation. A suite of LES calculations are performed on a large unstructured mesh for varying fuel compositions operating at several equivalence ratios. It is shown that the PDF based method can predict some statistical properties of the flame front, with improvement over other models in the same application.

  20. On the Comparison of the Long Penetration Mode (LPM) Supersonic Counterflowing Jet to the Supersonic Screech Jet

    Science.gov (United States)

    Farr, Rebecca A.; Chang, Chau-Lyan.; Jones, Jess H.; Dougherty, N. Sam

    2015-01-01

    The authors provide a brief overview of the classic tonal screech noise problem created by underexpanded supersonic jets, briefly describing the fluid dynamic-acoustics feedback mechanism that has been long established as the basis for this well-known aeroacoustics problem. This is followed by a description of the Long Penetration Mode (LPM) supersonic underexpanded counterflowing jet phenomenon which has been demonstrated in several wind tunnel tests and modeled in several computational fluid dynamics (CFD) simulations. The authors provide evidence from test and CFD analysis of LPM that indicates that acoustics feedback and fluid interaction seen in LPM are analogous to the aeroacoustics interactions seen in screech jets. Finally, the authors propose applying certain methodologies to LPM which have been developed and successfully demonstrated in the study of screech jets and mechanically induced excitation in fluid oscillators for decades. The authors conclude that the large body of work done on jet screech, other aeroacoustic phenomena, and fluid oscillators can have direct application to the study and applications of LPM counterflowing supersonic cold flow jets.

  1. Design and experimental analysis of counter-flow heat and mass exchanger incorporating (M-cycle) for evaporative cooling

    Science.gov (United States)

    Khalid, Omar; Butt, Zubair; Tanveer, Waqas; Rao, Hasan Iqbal

    2017-04-01

    In this paper, the functioning of dew-point cooler is improved in terms of its thermal effectiveness. For this reason, a heat and mass exchanger has been designed by using a counter-flow pattern incorporating Maisotsenko cycle (M-cycle) having effective absorbing material called Kraft paper on wet channel side and improved width to height ratio. Experimentation has been performed under various inlet air working parameters such as humidity, velocity and temperature in addition with changing feed water temperature. The results from the experiments specify that the dew-point and the wet-bulb effectiveness is achieved between 67-87 % and 104-120 % respectively. Analysis is performed with temperature variation between 25 and 45 °C at different absolute humidity levels ranging from 14.4 to 18 g/kg, while the inlet air velocity is varied between 0.88 and 1.50 m/s. Thus, the working ability of the improved design has been found 5 % more effective in terms of wet bulb effectiveness as compared to previous counter-flow designs.

  2. Statistics, distillation, and ordering emergence in a two-dimensional stochastic model of particles in counterflowing streams

    Science.gov (United States)

    Stock, Eduardo Velasco; da Silva, Roberto; Fernandes, H. A.

    2017-07-01

    In this paper, we propose a stochastic model which describes two species of particles moving in counterflow. The model generalizes the theoretical framework that describes the transport in random systems by taking into account two different scenarios: particles can work as mobile obstacles, whereas particles of one species move in the opposite direction to the particles of the other species, or particles of a given species work as fixed obstacles remaining in their places during the time evolution. We conduct a detailed study about the statistics concerning the crossing time of particles, as well as the effects of the lateral transitions on the time required to the system reaches a state of complete geographic separation of species. The spatial effects of jamming are also studied by looking into the deformation of the concentration of particles in the two-dimensional corridor. Finally, we observe in our study the formation of patterns of lanes which reach the steady state regardless of the initial conditions used for the evolution. A similar result is also observed in real experiments involving charged colloids motion and simulations of pedestrian dynamics based on Langevin equations, when periodic boundary conditions are considered (particles counterflow in a ring symmetry). The results obtained through Monte Carlo simulations and numerical integrations are in good agreement with each other. However, differently from previous studies, the dynamics considered in this work is not Newton-based, and therefore, even artificial situations of self-propelled objects should be studied in this first-principles modeling.

  3. Flame Retardants Used in Flexible Polyurethane Foam

    Science.gov (United States)

    The partnership project on flame retardants in furniture seeks to update the health and environmental profiles of flame-retardant chemicals that meet fire safety standards for upholstered consumer products with polyurethane foam

  4. Production of fullerenic nanostructures in flames

    Science.gov (United States)

    Howard, Jack B.; Vander Sande, John B.; Chowdhury, K. Das

    1999-01-01

    A method for the production of fullerenic nanostructures is described in which unsaturated hydrocarbon fuel and oxygen are combusted in a burner chamber at a sub-atmospheric pressure, thereby establishing a flame. The condensibles of the flame are collected at a post-flame location. The condensibles contain fullerenic nanostructures, such as single and nested nanotubes, single and nested nanoparticles and giant fullerenes. The method of producing fullerenic soot from flames is also described.

  5. Flame emission, atomic absorption and fluorescence spectrometry

    International Nuclear Information System (INIS)

    Horlick, G.

    1980-01-01

    Six hundred and thirty references are cited in this review. The information in the review is divided into 12 major areas: books, reviews, and bibliographies; fundamental studies in flames; developments in instrumentation; measurement techniques and procedure; flame emission spectrometry; flame atomic absorption spectrometry; flame molecular absorption spectrometry; electrothermal atomization atomic absorption spectroscopy; hydride generation techniques; graphite furnace atomic emission spectrometry; atomic fluorescence spectrometry; and analytical comparisons

  6. Physical and Chemical Processes in Turbulent Flames

    Science.gov (United States)

    2015-06-23

    used a constant-pressure, fan -stirred combustion chamber to investigate the propagation of a spherically expanding flame (Fig. 1.1). Chambers based...radius, closer to the fans . However during flame expansion, the mean radial flow adjacent to the flame is radially outward in nature shown by the...AFRL-OSR-VA-TR-2015-0136 Physical and Chemical Processes in Turbulent Flames Chung Law TRUSTEES OF PRINCETON UNIVERSITY Final Report 06/23/2015

  7. 30 CFR 14.20 - Flame resistance.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Flame resistance. 14.20 Section 14.20 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR TESTING, EVALUATION, AND APPROVAL OF... § 14.20 Flame resistance. Conveyor belts for use in underground coal mines must be flame-resistant and...

  8. Environmental Considerations for Flame Resistant Textiles

    Science.gov (United States)

    Virtually all common textiles will ignite and burn. There are mandatory and voluntary cigarette and open-flame ignition regulations to address unreasonable fire risks associated with textile products that require them to be treated with and/or contain flame retardant chemicals to make them flame res...

  9. TURBULENT OXYGEN FLAMES IN TYPE Ia SUPERNOVAE

    International Nuclear Information System (INIS)

    Aspden, A. J.; Bell, J. B.; Woosley, S. E.

    2011-01-01

    In previous studies, we examined turbulence-flame interactions in carbon-burning thermonuclear flames in Type Ia supernovae. In this study, we consider turbulence-flame interactions in the trailing oxygen flames. The two aims of the paper are to examine the response of the inductive oxygen flame to intense levels of turbulence, and to explore the possibility of transition to detonation in the oxygen flame. Scaling arguments analogous to the carbon flames are presented and then compared against three-dimensional simulations for a range of Damkoehler numbers (Da 16 ) at a fixed Karlovitz number. The simulations suggest that turbulence does not significantly affect the oxygen flame when Da 16 16 >1, turbulence enhances heat transfer and drives the propagation of a flame that is narrower than the corresponding inductive flame would be. Furthermore, burning under these conditions appears to occur as part of a combined carbon-oxygen turbulent flame with complex compound structure. The simulations do not appear to support the possibility of a transition to detonation in the oxygen flame, but do not preclude it either.

  10. Experimental characterization of methane inverse diffusion flame

    KAUST Repository

    Elbaz, Ayman M.

    2014-06-26

    This article presents 10-kHz images of OH-PLIF simultaneously with 2-D PIV measurements in an inverse methane diffusion flame. Under a constant fuel flow rate, the central air jet Re was varied, leading to air to fuel velocity ratio, Vr, to vary from 8.3 to 66.5. Starting from Vr = 20.7, the flame is commonly characterized by three distinct zones. The length of the lower fuel entrainment region is inversely proportional to Vr. The flames investigated resemble a string shear layer confining this zone, and converging into the second distinct region, the flame neck zone. The third region is the rest of the flame, which spreads in a jet-like manner. The inverse diffusion flames exhibit varying degrees of partial premixing, depending upon on the velocity ratio Vr, and this region of partial premixing evolves into a well-mixed reaction zone along the flame centerline. The OH distribution correlated with the changes in the mean characteristics of the flow through reduction in the local Reynolds number due to heat release. The existence of a flame suppresses or laminarizes the turbulence at early axial locations and promotes fluctuations at the flame tip for flames with Vr < 49.8. In addition, the flame jet width can be correlated to the OH distribution. In upstream regions of the flames, the breaks in OH are counterbalanced by flame closures and are governed by edge flame propagation. These local extinctions were found to occur at locations where large flow structures were impinging on the flame and are associated with a locally higher strain rate or correlated to the local high strain rates at the flame hole edges without this flow impinging. Another contributor to re-ignition was found to be growing flame kernels. As the flames approach global blow-off, these kernels become the main mechanism for re-ignition further downstream of the flames. At low Vr, laminarization within the early regions of the flame provides an effective shield, preventing the jet flow from

  11. Physical and Chemical Process in Flames

    Science.gov (United States)

    2006-06-01

    simulation for a turbulence Bunsen flame through our collaboration with Sandia National Lab. The solver is explicit 6th-order Rounge- Kutta...phenomena. For example, when the Bunsen flame was forced with high frequency, low amplitude disturbances, flame wrinkling was evident only at the flame base...and the wrinkling is 0 1 more evident for the flame surface near the 0 0.2 0.4 0.6 0.8 1 burner rim. This explains the experimental Figure 10

  12. The VLT FLAMES Tarantula Survey

    NARCIS (Netherlands)

    Evans, C.; Taylor, W.; Sana, H.; Hénault-Brunet, V.; Bagnoli, T.; Bastian, N.; Bestenlehner, J.; Bonanos, A.; Bressert, E.; Brott, I.; Campbell, M.; Cantiello, M.; Carraro, G.; Clark, S.; Costa, E.; Crowther, P.; de Koter, A.; de Mink, S.; Doran, E.; Dufton, P.; Dunstall, P.; Garcia, M.; Gieles, M.; Gräfener, G.; Herrero, A.; Howarth, I.; Izzard, R.; Köhler, K.; Langer, N.; Lennon, D.; Maíz Apellániz, J.; Markova, N.; Najarro, P.; Puls, J.; Ramirez, O.; Sabín-Sanjulián, C.; Simón-Díaz, S.; Smartt, S.; Stroud, V.; van Loon, J.; Vink, J.S.; Walborn, N.

    2011-01-01

    We introduce the VLT FLAMES Tarantula Survey, an ESO Large Programme from which we have obtained optical spectroscopy of over 800 massive stars in the spectacular 30 Doradus region of the Large Magellanic Cloud. A key feature is the use of multi-epoch observations to provide strong constraints on

  13. Analysis of cloud condensation nuclei composition and growth kinetics using a pumped counterflow virtual impactor and aerosol mass spectrometer

    Directory of Open Access Journals (Sweden)

    J. G. Slowik

    2011-08-01

    Full Text Available We present a new method of determining the size and composition of CCN-active aerosol particles. Method utility is illustrated through a series of ambient measurements. A continuous-flow thermal-gradient diffusion chamber (TGDC, pumped counterflow virtual impactor (PCVI, and Aerodyne time-of-flight mass spectrometer (AMS are operated in series. Ambient particles are sampled into the TGDC, where a constant supersaturation is maintained, and CCN-active particles grow to ~2.5 ± 0.5 μm. The output flow from the TGDC is directed into the PCVI, where a counterflow of dry N2 gas opposes the particle-laden flow, creating a region of zero axial velocity. This stagnation plane can only be traversed by particles with sufficient momentum, which depends on their size. Particles that have activated in the TGDC cross the stagnation plane and are entrained in the PCVI output flow, while the unactivated particles are diverted to a pump. Because the input gas is replaced by the counterflow gas with better than 99 % efficiency at the stagnation plane, the output flow consists almost entirely of dry N2 and water evaporates from the activated particles. In this way, the system yields an ensemble of CCN-active particles whose chemical composition and size are analyzed using the AMS. Measurements of urban aerosol in downtown Toronto identified an external mixture of CCN-active particles consisting almost entirely of ammonium nitrate and ammonium sulfate, with CCN-inactive particles of the same size consisting of a mixture of ammonium nitrate, ammonium sulfate, and organics. We also discuss results from the first field deployment of the TGDC-PCVI-AMS system, conducted from mid-May to mid-June 2007 in Egbert, Ontario, a semirural site ~80 km north of Toronto influenced both by clean air masses from the north and emissions from the city. Organic-dominated particles sampled during a major biogenic event exhibited higher CCN activity and/or faster

  14. Studies of propane flame soot acting as heterogeneous ice nuclei in conjunction with single particle soot photometer measurements

    Directory of Open Access Journals (Sweden)

    I. Crawford

    2011-09-01

    Full Text Available The ice nucleation efficiency of propane flame soot particles with and without a sulphuric acid coating was investigated using the aerosol and cloud chamber facility AIDA (Aerosol Interaction and Dynamics in the Atmosphere. The test soot for cloud formation simulations was produced using a propane flame Combustion Aerosol Standard generator (CAST, Jing-CAST Technologies. The organic carbon content (OC of the test soot was altered in a reproducible fashion by changing the fuel/air mixture of the generator. The soot content of ice nuclei was subsequently investigated using a combination of a pumped counterflow virtual impactor (PCVI to separate and evaporate the ice crystals, and a DMT single particle soot photometer (SP2 to examine the mixing state of the BC containing ice residuals.

    Ice nucleation was found to be most efficient for uncoated soot of low organic carbon content (~5 % organic carbon content where deposition freezing occurred at an ice saturation ratio Sice ~ 1.22 at a temperature T = 226.6 K with 25 % of the test soot becoming active as ice nuclei. Propane flame soot of higher organic carbon content (~30 % and ~70 % organic carbon content showed significantly lower ice nucleation efficiency (an activated fraction of the order of a few percent in the experiments than the low organic carbon content soot, with water saturation being required for freezing to occur. Ice nucleation occurred over the range Sice = 1.22–1.70, and T = 223.2–226.6 K. Analysis of the SP2 data showed that the 5 % organic carbon content soot had an undetectable OC coating whereas the 30 % organic carbon content soot had a thicker or less volatile OC coating.

    The application of a sulphuric acid coating to the flame soot shifted the threshold of the onset of freezing towards that of the homogeneous freezing of sulphuric acid; for the minimum OC flame soot this inhibited nucleation since the

  15. Application of the conditional source-term estimation model for turbulence-chemistry interactions in a premixed flame

    Science.gov (United States)

    Salehi, M. M.; Bushe, W. K.; Daun, K. J.

    2012-04-01

    Conditional Source-term Estimation (CSE) is a closure model for turbulence-chemistry interactions. This model uses the first-order CMC hypothesis to close the chemical reaction source terms. The conditional scalar field is estimated by solving an integral equation using inverse methods. It was originally developed and has been used extensively in non-premixed combustion. This work is the first application of this combustion model for a premixed flame. CSE is coupled with a Trajectory Generated Low-Dimensional Manifold (TGLDM) model for chemistry. The CSE-TGLDM combustion model is used in a RANS code to simulate a turbulent premixed Bunsen burner. Along with this combustion model, a similar model which relies on the flamelet assumption is also used for comparison. The results of these two approaches in the prediction of the velocity field, temperature and species mass fractions are compared together. Although the flamelet model is less computationally expensive, the CSE combustion model is more general and does not have the limiting assumption underlying the flamelet model.

  16. Numerical and experimental studies of ethanol flames and autoignition theory for higher alkanes

    Science.gov (United States)

    Saxena, Priyank

    elementary steps and the addition and deletion of a few key steps relevant to these tests. A mechanism developed in such a hierarchical way starting with simpler fuels such as hydrogen and carbon monoxide to the fuels with one and two carbon atoms has reduced uncertainties in the combustion chemistry of a fuel. This reaction mechanism, consisting of 137 reactions among 30 species, provides a robust building block upon which an ethanol mechanism is developed. The San Diego Mech is extended for ethanol combustion by adding 55 new reactions and 6 new species. Specifically, 33 reactions are added that involve C 2H5OH or one of the three isomers produced by abstraction of an H atom from it, CH3CHOH, CH2CH2OH and CH3CH2O, and 22 reactions are added that involve acetaldehyde or one of the two isomers produced by abstraction of H from it, CH2CHO and CH3CO. Ethanol combustion is investigated on the basis of a new reaction mechanism, thus developed, consisting of 192 elementary steps among 36 species, augmented by 53 additional steps and 14 additional species to address the formation of the oxides of nitrogen and 43 steps and 7 species to address formation of compounds involving three carbon atoms. The mechanism is tested against shock-tube autoignition-delay data, laminar burning velocities, counterflow diffusion-flame extinction and measurements of structures of counterflow partially premixed and diffusion flames. Measurements on ethanol-air flames at a strain rate of 100 s-1, employing prevaporized ethanol with a mole fraction of 0.3 in a nitrogen carrier stream, were made for the pure diffusion flame and for a partially premixed flame with a fuel-side equivalence ratio of 2.3 and involved thermocouple measurements of temperature profiles and determination of concentration profiles of C2H5OH, CO, CO2, H2, H2O, O2, N2, CH4, C2H6 and C2H2+C 2H4 by gas chromatographic analysis of samples withdrawn through fine quartz probes. Computational investigations also were made of profiles of

  17. Flex-flame burner and combustion method

    Science.gov (United States)

    Soupos, Vasilios; Zelepouga, Serguei; Rue, David M.; Abbasi, Hamid A.

    2010-08-24

    A combustion method and apparatus which produce a hybrid flame for heating metals and metal alloys, which hybrid flame has the characteristic of having an oxidant-lean portion proximate the metal or metal alloy and having an oxidant-rich portion disposed above the oxidant lean portion. This hybrid flame is produced by introducing fuel and primary combustion oxidant into the furnace chamber containing the metal or metal alloy in a substoichiometric ratio to produce a fuel-rich flame and by introducing a secondary combustion oxidant into the furnace chamber above the fuel-rich flame in a manner whereby mixing of the secondary combustion oxidant with the fuel-rich flame is delayed for a portion of the length of the flame.

  18. Flame Dynamics inside Rectangular Meso scale Channels

    Science.gov (United States)

    Anwar, Muzammil; Naseer Mohammad, Abdul; Mohammad, Akram; Juhany, Khalid A.

    2018-03-01

    The present work is focused on the experimental study of flame dynamics in preheated meso-scale straight channels of various aspect ratios (2, 5, 12 and 15) and inlet dimensions.Premixed methane-air mixture were used for the reported experiments. To maintain a positive wall temperature gradient inside the channel, the lower part of the rectangular channels were heated at a constant temperature using an external electric heater. Laminar premixed flames were stabilized inside these channels. Various flame propagation modes such as concave, planar, and convex flames with respect to unburned mixture. Concave flames lead to flashback whereas convex flames lead to blowout. Increase in aspect ratio and decrease of flow velocity leads to flame flashback.

  19. A comprehensive experimental and modeling study of iso-pentanol combustion

    KAUST Repository

    Sarathy, Mani

    2013-12-01

    Biofuels are considered as potentially attractive alternative fuels that can reduce greenhouse gas and pollutant emissions. iso-Pentanol is one of several next-generation biofuels that can be used as an alternative fuel in combustion engines. In the present study, new experimental data for iso-pentanol in shock tube, rapid compression machine, jet stirred reactor, and counterflow diffusion flame are presented. Shock tube ignition delay times were measured for iso-pentanol/air mixtures at three equivalence ratios, temperatures ranging from 819 to 1252. K, and at nominal pressures near 40 and 60. bar. Jet stirred reactor experiments are reported at 5. atm and five equivalence ratios. Rapid compression machine ignition delay data was obtained near 40. bar, for three equivalence ratios, and temperatures below 800. K. Laminar flame speed data and non-premixed extinction strain rates were obtained using the counterflow configuration. A detailed chemical kinetic model for iso-pentanol oxidation was developed including high- and low-temperature chemistry for a better understanding of the combustion characteristics of higher alcohols. First, bond dissociation energies were calculated using ab initio methods, and the proposed rate constants were based on a previously presented model for butanol isomers and n-pentanol. The model was validated against new and existing experimental data at pressures of 1-60. atm, temperatures of 650-1500. K, equivalence ratios of 0.25-4.0, and covering both premixed and non-premixed environments. The method of direct relation graph (DRG) with expert knowledge (DRGX) was employed to eliminate unimportant species and reactions in the detailed mechanism, and the resulting skeletal mechanism was used to predict non-premixed flames. In addition, reaction path and temperature A-factor sensitivity analyses were conducted for identifying key reactions at various combustion conditions. © 2013 The Combustion Institute.

  20. A flame particle tracking analysis of turbulence–chemistry interaction in hydrogen–air premixed flames

    KAUST Repository

    Uranakara, Harshavardhana A.

    2015-11-21

    Interactions of turbulence, molecular transport, and energy transport, coupled with chemistry play a crucial role in the evolution of flame surface geometry, propagation, annihilation, and local extinction/re-ignition characteristics of intensely turbulent premixed flames. This study seeks to understand how these interactions affect flame surface annihilation of lean hydrogen–air premixed turbulent flames. Direct numerical simulations (DNSs) are conducted at different parametric conditions with a detailed reaction mechanism and transport properties for hydrogen–air flames. Flame particle tracking (FPT) technique is used to follow specific flame surface segments. An analytical expression for the local displacement flame speed (Sd) of a temperature isosurface is considered, and the contributions of transport, chemistry, and kinematics on the displacement flame speed at different turbulence-flame interaction conditions are identified. In general, the displacement flame speed for the flame particles is found to increase with time for all conditions considered. This is because, eventually all flame surfaces and their resident flame particles approach annihilation by reactant island formation at the end of stretching and folding processes induced by turbulence. Statistics of principal curvature evolving in time, obtained using FPT, suggest that these islands are ellipsoidal on average enclosing fresh reactants. Further examinations show that the increase in Sd is caused by the increased negative curvature of the flame surface and eventual homogenization of temperature gradients as these reactant islands shrink due to flame propagation and turbulent mixing. Finally, the evolution of the normalized, averaged, displacement flame speed vs. stretch Karlovitz number are found to collapse on a narrow band, suggesting that a unified description of flame speed dependence on stretch rate may be possible in the Lagrangian description.

  1. Steady and decaying quantum turbulence generated in He II flow channel by counterflow and pure super flow

    International Nuclear Information System (INIS)

    Chagovets, T.V.; Gordeev, A.V.; Rotter, M.; Soukup, F.; Sindelar, J.; Skrbek, J.

    2006-01-01

    We report experimental investigations of He II turbulence and its decay. Turbulent state was generated by counterflow and pure super flow in channels of circular and square cross-section. The steady-state turbulence is generated by applying power to the heater placed either in the dead end of the channel or immersed in He II in a volume adjacent to one of the silver sintered super leaks having an outlet above the helium bath level When this power is switched off, quantum turbulence displays a complex decay. We discuss the steady state data and forms of the observed decays in terms of available models and compare with quantum turbulence generated by towing a grid of bars through a stationary sample of He II (Authors)

  2. Extinction of corrugated hydrogen/air flames

    International Nuclear Information System (INIS)

    Mizomoto, M.; Asaka, Y.; Ikai, S.; Law, C.K.

    1982-01-01

    Recent studies on flammability limits reveal the importance of flow nonuniformity, flame curvature, and molecular and thermal diffusivities in determining the extinguishability and the associated limits of premixed fuel/air flames. In particular, it is found that conditions which favor extinction of a lean flame may cause intensification of a rich flame. In the present study the authors have experimentally determined the extinction characteristics and limits of highly curved hydrogen/air flames as represented by the opening of bunsen flame tips. Results show that the tip opens at a constant fuel equivalence ratio of phi = 1.15, regardless of the velocity and uniformity of the upstream flow. This critical mixture concentration, while being rich, is still on the lean side of that corresponding to the maximum burning velocity (phi = 1.8), implying that for highly diffusive systems, the relevant reference concentration is that for maximum burning velocity instead of stoichiometry

  3. The role of shock-flame interactions on flame acceleration in an obstacle laden channel

    Energy Technology Data Exchange (ETDEWEB)

    Ciccarelli, Gaby; Johansen, Craig T.; Parravani, Michael [Mechanical and Materials Engineering, Queen' s University, Kingston, Ontario (Canada)

    2010-11-15

    Flame acceleration was investigated in an obstructed, square-cross-section channel. Flame acceleration was promoted by an array of top and bottom surface mounted obstacles that were distributed along the entire channel length at an equal spacing corresponding to one channel height. This work is based on a previous investigation of the effects of blockage ratio on the early stage of flame acceleration. This study is focused on the later stage of flame acceleration when compression waves, and eventually a shock wave, form ahead of the flame. The objective of the study is to investigate the effect of obstacle blockage on the rate of flame acceleration and on the final quasi-steady flame-tip velocity. Schlieren photography was used to track the development of the shock-flame complex. It was determined that the interaction between the flame front and the reflected shock waves produced from contact of the lead shock wave with the channel top, channel bottom, and obstacle surfaces govern the late stage of flame acceleration process. The shock-flame interactions produce oscillations in the flame-tip velocity similar to that observed in the early stage of flame acceleration, but only much larger in magnitude. Eventually the flame achieves a globally quasi-steady velocity. For the lowest blockage obstacles, the velocity approaches the speed of sound of the combustion products. The final quasi-steady flame velocity was lower in tests with the higher obstacle blockage. In the quasi-steady propagation regime with the lowest blockage obstacles, burning pockets of gas extended only a few obstacles back from the flame-tip, whereas burning pockets were observed further back in tests with the higher obstacle blockage. (author)

  4. Flame Surface Density Measurements and Curvature Statistics for Turbulent Premixed Bunsen Flames

    OpenAIRE

    Capil, Tyler George

    2017-01-01

    In this work, turbulent premixed combustion was analyzed through CH (methylidyne) planar laser induced fluorescence (PLIF). Flame topography measurements in terms of flame surface density and curvature were calculated based on the flame front detected by the CH PLIF signal. The goal of this work was to investigate turbulent flames with extremely high turbulence intensity using a recently developed HiPilot burner (a Bunsen-type burner). The studies were first conducted on a series of piloted j...

  5. Physical and Chemical Processing in Flames

    Science.gov (United States)

    2013-08-12

    type of the burner used in the investigation – a major hindrance that has prevented its utilization as a meaningful physical quantity for predictions...turbulent flame speeds measured from the present spherically expanding flames, as well as those from literature data on Bunsen flames, can be scaled by...Prezhdo, J Phys Chem, 99, 8633–8637 (1995). P. Zhang, C K Law, Int J Chem Kinet, 41, 727–734 (2009) R G Gilbert, K. Luther, and J Troe, Ber Bunsen

  6. Microgravity Turbulent Gas-Jet Diffusion Flames

    Science.gov (United States)

    1996-01-01

    A gas-jet diffusion flame is similar to the flame on a Bunsen burner, where a gaseous fuel (e.g., propane) flows from a nozzle into an oxygen-containing atmosphere (e.g., air). The difference is that a Bunsen burner allows for (partial) premixing of the fuel and the air, whereas a diffusion flame is not premixed and gets its oxygen (principally) by diffusion from the atmosphere around the flame. Simple gas-jet diffusion flames are often used for combustion studies because they embody the mechanisms operating in accidental fires and in practical combustion systems. However, most practical combustion is turbulent (i.e., with random flow vortices), which enhances the fuel/air mixing. These turbulent flames are not well understood because their random and transient nature complicates analysis. Normal gravity studies of turbulence in gas-jet diffusion flames can be impeded by buoyancy-induced instabilities. These gravitycaused instabilities, which are evident in the flickering of a candle flame in normal gravity, interfere with the study of turbulent gas-jet diffusion flames. By conducting experiments in microgravity, where buoyant instabilities are avoided, we at the NASA Lewis Research Center hope to improve our understanding of turbulent combustion. Ultimately, this could lead to improvements in combustor design, yielding higher efficiency and lower pollutant emissions. Gas-jet diffusion flames are often researched as model flames, because they embody mechanisms operating in both accidental fires and practical combustion systems (see the first figure). In normal gravity laboratory research, buoyant air flows, which are often negligible in practical situations, dominate the heat and mass transfer processes. Microgravity research studies, however, are not constrained by buoyant air flows, and new, unique information on the behavior of gas-jet diffusion flames has been obtained.

  7. Pole solutions for flame front propagation

    CERN Document Server

    Kupervasser, Oleg

    2015-01-01

    This book deals with solving mathematically the unsteady flame propagation equations. New original mathematical methods for solving complex non-linear equations and investigating their properties are presented. Pole solutions for flame front propagation are developed. Premixed flames and filtration combustion have remarkable properties: the complex nonlinear integro-differential equations for these problems have exact analytical solutions described by the motion of poles in a complex plane. Instead of complex equations, a finite set of ordinary differential equations is applied. These solutions help to investigate analytically and numerically properties of the flame front propagation equations.

  8. Imaging of premixed flames in microgravity

    Science.gov (United States)

    Kostiuk, L. W.; Cheng, R. K.

    1994-12-01

    A laser schlieren system which uses video recording and digital images analysis has been developed and applied successfully to microgravity combustion experiments performed in a drop-tower. The optical system and the experiment are installed within a small package which is subjected to free-fall. The images are recorded on video tape and are digitized and analyzed by a computer-controlled image processor. The experimental results include laminar and turbulent premixed conical flames in microgravity, normal positive gravity (upward), and reverse gravity (downward). The procedures to extract frequency information from the digitized images are described. Many gross features of the effects of gravity on premixed conical flames are found. Flames that ignite easily in normal gravity fail to ignite in microgravity. Buoyancy driven instabilities associated with an interface formed between the hot products and the cold surrounding air is the mechanism through which gravity influences premixed laminar and turbulent flames. In normal gravity, this causes the flame to flicker. In reverse gravity, - g, and microgravity, μg, the interface is stable and flame flickering ceases. The flickering frequencies of + g flames vary with changing upstream boundary conditions. The absence of flame flickering in μg suggest that μg flames would be less sensitive to these changes.

  9. Mathematical model of quasi-equilibrium counter-flow processes of rare earth metal separation by solvent extraction when varying the composition of initial raw materials

    International Nuclear Information System (INIS)

    Pyartman, A.K.; Puzikov, E.A.

    1994-01-01

    A mathematical model for the description of rare earths (3) distribution, depending on the number of contact steps for quasiequilibrium counter-flow processes of rare earths separation by the method of solvent extraction with varying the composition of initial source material, has been suggested. Algorithm of computer calculation is provided. The mathematical model has been employed to choose the optimal conditions for didymium concentrate separation. 7 refs.; 3 figs.; 1 tab

  10. A mathematical model of quasi-equilibrium counter-flow processes of rare earth metal separation by solvent extraction when varying the composition of raw material

    International Nuclear Information System (INIS)

    Pyartman, A.K.; Puzikov, E.A.; Kopyrin, A.A.

    1994-01-01

    A mathematical model for description of rare earth metals (3) distribution, depending on the number of contact steps, for quasiequilibrium counter-flow processes of rare earth metals (3) separation by the method of solvent extraction with varying the composition of initial source material is suggested. Algorithm of calculation using computer is provided. The mathematical model is employed for selecting the optimal conditions of didymium concentrate separation. 7 refs., 3 figs., 1 tab

  11. Energy performance of an innovative liquid desiccant dehumidification system with a counter-flow heat and mass exchanger using potassium formate

    DEFF Research Database (Denmark)

    Jradi, Muhyiddine; Riffat, Saffa

    2014-01-01

    An innovative micro-scale liquid desiccant dehumidification system is numerically investigated. The liquid desiccant dehumidification unit employs a counter-flow low-cost and efficient heat and mass exchange core, improving the thermal performance and eliminating desiccant carryover...... that the dehumidifier effectiveness is directly proportional to the intake air temperature, intake air relative humidity and liquid desiccant flow rate where the effectiveness is inversely proportional to the intake air velocity and the heat exchanger air channel height....

  12. Experimental studies of flame stability limits of biogas flame

    International Nuclear Information System (INIS)

    Dai Wanneng; Qin Chaokui; Chen Zhiguang; Tong Chao; Liu Pengjun

    2012-01-01

    Highlights: ► Premixed biogas flame stability for RTBs was studied on different conditions. ► An unusual “float off” phenomenon was observed. ► Decrease of port diameter or gas temperature or methane content motivates lifting. ► Increase of methane content or gas temperature or port diameter motivates yellow tipping. ► Lifting curves become straight lines when semi-logarithmic graph paper is applied. - Abstract: Flame stability of premixed biogas flame for Reference Test Burner (RTB) was investigated. In this study, six kinds of test gases were used to simulate biogas in which CO 2 volume fraction varied from 30% to 45%. A series of experiments were conducted on two RTBs with different port diameters and at different outlet unburned mixture temperatures. It was found that the lifting and yellow tipping limits show similar trends regardless of the biogas components, port diameters and mixture temperatures. A “float off” phenomenon could be observed at low gas flow rate and low primary air ratio. Low mixture temperature, small ports and high CO 2 concentration in biogas can lead to the unstable condition of “float off”. The lifting limits are enhanced with an increase of port diameter or mixture temperature and with a decrease of CO 2 concentration. The yellow tipping limits are extended with an increase of CO 2 concentration and with a decrease of mixture temperature or port diameter. In addition, the lifting limit curve becomes a straight line when semi-logarithmic graph paper is applied. The intercept increases with a decrease of the CO 2 concentration in biogas and with an increase of port diameter or gas temperature.

  13. Flame dynamics of a meso-scale heat recirculating combustor

    Energy Technology Data Exchange (ETDEWEB)

    Vijayan, V.; Gupta, A.K. [Department of Mechanical Engineering, University of Maryland, College Park, MD 20742 (United States)

    2010-12-15

    The dynamics of premixed propane-air flame in a meso-scale ceramic combustor has been examined here. The flame characteristics in the combustor were examined by measuring the acoustic emissions and preheat temperatures together with high-speed cinematography. For the small-scale combustor, the volume to surface area ratio is small and hence the walls have significant effect on the global flame structure, flame location and flame dynamics. In addition to the flame-wall thermal coupling there is a coupling between flame and acoustics in the case of confined flames. Flame-wall thermal interactions lead to low frequency flame fluctuations ({proportional_to}100 Hz) depending upon the thermal response of the wall. However, the flame-acoustic interactions can result in a wide range of flame fluctuations ranging from few hundred Hz to few kHz. Wall temperature distribution is one of the factors that control the amount of reactant preheating which in turn effects the location of flame stabilization. Acoustic emission signals and high-speed flame imaging confirmed that for the present case flame-acoustic interactions have more significant effect on flame dynamics. Based on the acoustic emissions, five different flame regimes have been identified; whistling/harmonic mode, rich instability mode, lean instability mode, silent mode and pulsating flame mode. (author)

  14. In-Flame Characterization of a 30 MWth Bio-Dust Flame

    DEFF Research Database (Denmark)

    Johansen, Joakim Myung; Jensen, Peter Arendt; Clausen, Sønnik

    This work presents a comprehensive flame characterization campaign on an operating full-scale Danish power plant. Amagerværket Unit 1 (AMV1, 350 MWth, 12 identical burners on 3 burner levels) is 100 % fuelled with wood dust burned in suspension and stabilized by swirling flows in a triple...... (LDA) velocity measurements, flame shape observations by video imaging, and particle entrainment by high speed infrared (IR) imaging. The flame is characterized along the geometrical centreline as well as in the horizontal and vertical plane of the flame. The results shed light on the flame anatomy...

  15. Tulip flames: changes in shape of premixed flames propagating in closed tubes

    Science.gov (United States)

    Dunn-Rankin, D.; Sawyer, R. F.

    The experimental results that are the subject of this communication provide high-speed schlieren images of the closed-tube flame shape that has come to be known as the tulip flame. The schlieren images, along with in-chamber pressure records, help demonstrate the effects of chamber length, equivalence ratio, and igniter geometry on formation of the tulip flame. The pressure/time records show distinct features which correlate with flame shape changes during the transition to tulip. The measurements indicate that the basic tulip flame formation is a robust phenomenon that depends on little except the overall geometry of the combustion vessel.

  16. Impact of flame-wall interaction on premixed flame dynamics and transfer function characteristics

    KAUST Repository

    Kedia, K.S.

    2011-01-01

    In this paper, we numerically investigate the response of a perforated-plate stabilized laminar methane-air premixed flame to imposed inlet velocity perturbations. A flame model using detailed chemical kinetics mechanism is applied and heat exchange between the burner plate and the gas mixture is incorporated. Linear transfer functions, for low mean inlet velocity oscillations, are analyzed for different equivalence ratio, mean inlet velocity, plate thermal conductivity and distance between adjacent holes. The oscillations of the heat exchange rate at the top of the burner surface plays a critical role in driving the growth of the perturbations over a wide range of conditions, including resonance. The flame response to the perturbations at its base takes the form of consumption speed oscillations in this region. Flame stand-off distance increases/decreases when the flame-wall interaction strengthens/weakens, impacting the overall dynamics of the heat release. The convective lag between the perturbations and the flame base response govern the phase of heat release rate oscillations. There is an additional convective lag between the perturbations at the flame base and the flame tip which has a weaker impact on the heat release rate oscillations. At higher frequencies, the flame-wall interaction is weaker and the heat release oscillations are driven by the flame area oscillations. The response of the flame to higher amplitude oscillations are used to gain further insight into the mechanisms. © 2010 Published by Elsevier Inc. on behalf of The Combustion Institute. All rights reserved.

  17. Simulations of flame generated particles

    KAUST Repository

    Patterson, Robert

    2016-01-05

    The nonlinear structure of the equations describing the evolution of a population of coagulating particles in a flame make the use of stochastic particle methods attractive for numerical purposes. I will present an analysis of the stochastic fluctuations inherent in these numerical methods leading to an efficient sampling technique for steady-state problems. I will also give some examples where stochastic particle methods have been used to explore the effect of uncertain parameters in soot formation models. In conclusion I will try to indicate some of the issues in optimising these methods for the study of uncertain model parameters.

  18. Nonequilibrium theory of flame propagation

    International Nuclear Information System (INIS)

    Merzhanov, A.G.

    1995-01-01

    The nonequilibrium theory of flame propagation is considered as applied to the following three processes of wave propagation: the combustion waves of the second kind, the combustion waves with broad reaction zones, and the combustion waves with chemical stages. Kinetic and combustion wave parameters are presented for different in composition mixtures of boron and transition metals, such as Zr, Hf, Ti, Nb, Ta, Mo, as well as for the Ta-N, Zr-C-H, Nb-B-O systems to illustrate specific features of the above-mentioned processes [ru

  19. Effect of Reynolds Number in Turbulent-Flow Range on Flame Speeds of Bunsen Burner Flames

    Science.gov (United States)

    Bollinger, Lowell M; Williams, David T

    1949-01-01

    The effect of flow conditions on the geometry of the turbulent Bunsen flame was investigated. Turbulent flame speed is defined in terms of flame geometry and data are presented showing the effect of Reynolds number of flow in the range of 3000 to 35,000 on flame speed for burner diameters from 1/4 to 1 1/8 inches and three fuels -- acetylene, ethylene, and propane. The normal flame speed of an explosive mixture was shown to be an important factor in determining its turbulent flame speed, and it was deduced from the data that turbulent flame speed is a function of both the Reynolds number of the turbulent flow in the burner tube and of the tube diameter.

  20. Flaming in CMC: Prometheus' Fire or Inferno's?

    Science.gov (United States)

    Abrams, Zsuzsanna Ittzes

    2003-01-01

    Reports on a descriptive study with 75 intermediate college learners of German participating in two sessions of synchronous computer mediated communication during the course of a semester that investigated students' flaming behavior--aggressive interpersonal language and rude behavior. Shows that not only is flaming a very infrequent occurrence,…

  1. Active control for turbulent premixed flame simulations

    Energy Technology Data Exchange (ETDEWEB)

    Bell, John B.; Day, Marcus S.; Grcar, Joseph F.; Lijewski, Michael J.

    2004-03-26

    Many turbulent premixed flames of practical interest are statistically stationary. They occur in combustors that have anchoring mechanisms to prevent blow-off and flashback. The stabilization devices often introduce a level of geometric complexity that is prohibitive for detailed computational studies of turbulent flame dynamics. As a result, typical detailed simulations are performed in simplified model configurations such as decaying isotropic turbulence or inflowing turbulence. In these configurations, the turbulence seen by the flame either decays or, in the latter case, increases as the flame accelerates toward the turbulent inflow. This limits the duration of the eddy evolutions experienced by the flame at a given level of turbulent intensity, so that statistically valid observations cannot be made. In this paper, we apply a feedback control to computationally stabilize an otherwise unstable turbulent premixed flame in two dimensions. For the simulations, we specify turbulent in flow conditions and dynamically adjust the integrated fueling rate to control the mean location of the flame in the domain. We outline the numerical procedure, and illustrate the behavior of the control algorithm. We use the simulations to study the propagation and the local chemical variability of turbulent flame chemistry.

  2. Flame Imaging of Gas-Turbine Relight

    DEFF Research Database (Denmark)

    Read, Robert; Rogerson, J.W.; Hochgreb, S.

    2010-01-01

    . The motion of hot gases during the early stages of relight is recorded using a high-speed camera. An algorithm is developed to track the flame movement and breakup, revealing important characteristics of the flame development process, including stabilization timescales, spatial trajectories, and typical...

  3. Development of PIV for Microgravity Diffusion Flames

    Science.gov (United States)

    Greenberg, Paul S.; Wernet, Mark P.; Yanis, William; Urban, David L.; Sunderland, Peter B.

    2003-01-01

    Results are presented from the application of Particle Image Velocimetry(PIV) to the overfire region of a laminar gas jet diffusion flame in normal gravity. A methane flame burning in air at 0.98 bar was considered. The apparatus demonstrated here is packaged in a drop rig designed for use in the 2.2 second drop tower.

  4. Flame retardant cotton based highloft nonwovens

    Science.gov (United States)

    Flame retardancy has been a serious bottleneck to develop cotton blended very high specific volume bulky High loft fabrics. Alternately, newer approach to produce flame retardant cotton blended High loft fabrics must be employed that retain soft feel characteristics desirable of furnishings. Hence, ...

  5. Flame retardant cotton barrier nonwovens for mattresses

    Science.gov (United States)

    According to regulation CPSC 16 CFR 1633, every new residential mattress sold in the United States since July 2007 must resist ignition by open flame. An environmentally benign “green”, inexpensive way to meet this regulation is to use a low-cost flame retardant (FR) barrier fabric. In this study, a...

  6. Propagation of a Free Flame in a Turbulent Gas Stream

    Science.gov (United States)

    Mickelsen, William R; Ernstein, Norman E

    1956-01-01

    Effective flame speeds of free turbulent flames were measured by photographic, ionization-gap, and photomultiplier-tube methods, and were found to have a statistical distribution attributed to the nature of the turbulent field. The effective turbulent flame speeds for the free flame were less than those previously measured for flames stabilized on nozzle burners, Bunsen burners, and bluff bodies. The statistical spread of the effective turbulent flame speeds was markedly wider in the lean and rich fuel-air-ratio regions, which might be attributed to the greater sensitivity of laminar flame speed to flame temperature in those regions. Values calculated from the turbulent free-flame-speed analysis proposed by Tucker apparently form upper limits for the statistical spread of free-flame-speed data. Hot-wire anemometer measurements of the longitudinal velocity fluctuation intensity and longitudinal correlation coefficient were made and were employed in the comparison of data and in the theoretical calculation of turbulent flame speed.

  7. Explosion triggering by an accelerating flame.

    Science.gov (United States)

    Bychkov, Vitaly; Akkerman, V'yacheslav

    2006-06-01

    The analytical theory of explosion triggering by an accelerating flame is developed. The theory describes the structure of a one-dimensional isentropic compression wave pushed by the flame front. The condition of explosion in the gas mixture ahead of the flame front is derived; the instant of the explosion is determined provided that a mechanism of chemical kinetics is known. As an example, it is demonstrated how the problem is solved in the case of a single reaction of Arrhenius type, controlling combustion both inside the flame front and ahead of the flame. The model of an Arrhenius reaction with a cutoff temperature is also considered. The limitations of the theory due to the shock formation in the compression wave are found. Comparison of the theoretical results to the previous numerical simulations shows good agreement.

  8. Simulasi Numeris Karakteristik Pembakaran CH4/CO2/Udara dan CH4/CO2/O2 pada Counterflow Premixed Burner

    Directory of Open Access Journals (Sweden)

    Hangga Wicaksono

    2017-08-01

    Full Text Available The high amount of CO2 produced in a conventional biogas reactor needs to be considered. A further analysis is needed in order to investigate the effect of CO2 addition especially in thermal and chemical kinetics aspect. This numerical study has been held to analyze the effect of CO2 in CH4/CO2/O­2 and CH4/CO2/Air premixed combustion. In this study one dimensional analisys in a counterflow burner has been performed. The volume fraction of CO2 used in this study was 0%-40% from CH4’s volume fraction, according to the amount of CO2 in general phenomenon. Based on the flammability limits data, the volume fraction of CH4 used was 5-61% in O2 environment and 5-15% in air environment. The results showed a decreasing temperature along with the increasing percentage of CO2 in each mixtures, but the effect was quite smaller especially in stoichiometric and lean mixture. CO2 could affects thermally (by absorbing heat due to its high Cp and also made the production of unburnt fuel species such as CO relatively higher.

  9. Algorithms and programs for solution of static and dynamic characteristics of counterflow heat exchangers with dissociating coolant

    International Nuclear Information System (INIS)

    Nitej, N.V.; Sharovarov, G.A.

    1982-01-01

    The method of estimation of counterflow heat exchanger characteristics is presented. Mathematical description of the processes is presented by the mass, energy and pulse conservation equations for both coolants and energy conservation equation for the wall which devides them. In the presence of chemical reactions the system is supplemented by equations, characterizing the kinetics of their progress. The methods of numerical solution of static and dynamic problems have been chosen, and the computer programs on the Fortran language have been developed. The schemes of solution of both problems are so constructed, that the conservation equations are placed in the main program, and such characteristics of the coolants as properties, heat transfer and friction coefficients, the mechanism of chemical reaction are concentrated in the subprogram unit. This allows to create the single method of solution with the flow of single-phase and two-phase coolants of abovecritical and supercritical paramters. The evaluation results of three heat exchangers are given: with heating of N 2 O 4 gas phase by heat of flue gas; with cooling of N 2 O 4 supercritical parameters by water; regenerator on N 2 O 4

  10. Perspectives of advanced thermal management in solar thermochemical syngas production using a counter-flow solid-solid heat exchanger

    Science.gov (United States)

    Falter, Christoph; Sizmann, Andreas; Pitz-Paal, Robert

    2017-06-01

    A modular reactor model is presented for the description of solar thermochemical syngas production involving counter-flow heat exchangers that recuperate heat from the solid phase. The development of the model is described including heat diffusion within the reactive material as it travels through the heat exchanger, which was previously identified to be a possibly limiting factor in heat exchanger design. Heat transfer within the reactive medium is described by conduction and radiation, where the former is modeled with the three-resistor model and the latter with the Rosseland diffusion approximation. The applicability of the model is shown by the analysis of heat exchanger efficiency for different material thicknesses and porosities in a system with 8 chambers and oxidation and reduction temperatures of 1000 K and 1800 K, respectively. Heat exchanger efficiency is found to rise strongly for a reduction of material thickness, as the element mass is reduced and a larger part of the elements takes part in the heat exchange process. An increase of porosity enhances radiation heat exchange but deteriorates conduction. The overall heat exchange in the material is improved for high temperatures in the heat exchanger, as radiation dominates the energy transfer. The model is shown to be a valuable tool for the development and analysis of solar thermochemical reactor concepts involving heat exchange from the solid phase.

  11. DISTRIBUTED FLAMES IN TYPE Ia SUPERNOVAE

    International Nuclear Information System (INIS)

    Aspden, A. J.; Bell, J. B.; Woosley, S. E.

    2010-01-01

    At a density near a few x10 7 g cm -3 , the subsonic burning in a Type Ia supernova (SN) enters the distributed regime (high Karlovitz number). In this regime, turbulence disrupts the internal structure of the flame, and so the idea of laminar burning propagated by conduction is no longer valid. The nature of the burning in this distributed regime depends on the turbulent Damkoehler number (Da T ), which steadily declines from much greater than one to less than one as the density decreases to a few x10 6 g cm -3 . Classical scaling arguments predict that the turbulent flame speed s T , normalized by the turbulent intensity u-check, follows s T /u-check = Da T 1/2 for Da T ∼ T ∼ 1, and the flame burns as a turbulently broadened effective unity Lewis number flame. This flame burns locally with speed s λ and width l λ , and we refer to this kind of flame as a λ-flame. The burning becomes a collection of λ-flames spread over a region approximately the size of the integral scale. While the total burning rate continues to have a well-defined average, s T ∼u-check, the burning is unsteady. We present a theoretical framework, supported by both one-dimensional and three-dimensional numerical simulations, for the burning in these two regimes. Our results indicate that the average value of s T can actually be roughly twice u-check for Da T ∼> 1, and that localized excursions to as much as 5 times u-check can occur. We also explore the properties of the individual flames, which could be sites for a transition to detonation when Da T ∼ 1. The λ-flame speed and width can be predicted based on the turbulence in the star (specifically the energy dissipation rate ε*) and the turbulent nuclear burning timescale of the fuel τ T nuc . We propose a practical method for measuring s λ and l λ based on the scaling relations and small-scale computationally inexpensive simulations. This suggests that a simple turbulent flame model can be easily constructed suitable for

  12. Thermal-diffusional Instability in White Dwarf Flames: Regimes of Flame Pulsation

    Science.gov (United States)

    Xing, Guangzheng; Zhao, Yibo; Modestov, Mikhail; Zhou, Cheng; Gao, Yang; Law, Chung K.

    2017-05-01

    Thermal-diffusional pulsation behaviors in planar as well as outwardly and inwardly propagating white dwarf (WD) carbon flames are systematically studied. In the 1D numerical simulation, the asymptotic degenerate equation of state and simplified one-step reaction rates for nuclear reactions are used to study the flame propagation and pulsation in WDs. The numerical critical Zel’dovich numbers of planar flames at different densities (ρ = 2, 3, and 4 × 107 g cm-3) and of spherical flames (with curvature c = -0.01, 0, 0.01, and 0.05) at a particular density (ρ = 2 × 107 g cm-3) are presented. Flame front pulsation in different environmental densities and temperatures are obtained to form the regime diagram of pulsation, showing that carbon flames pulsate in the typical density of 2 × 107 g cm-3 and temperature of 0.6 × 109 K. While being stable at higher temperatures, at relatively lower temperatures, the amplitude of the flame pulsation becomes larger. In outwardly propagating spherical flames the pulsation instability is enhanced and flames are also easier to quench due to pulsation at small radius, while the inwardly propagating flames are more stable.

  13. Analysis of flame shapes in turbulent hydrogen jet flames with coaxial air

    International Nuclear Information System (INIS)

    Moon, Hee Jang

    2009-01-01

    This paper addresses the characteristics of flame shapes and flame length in three types of coaxial air flames realizable by varying coaxial air and/or fuel velocity. Forcing coaxial air into turbulent jet flames induces substantial changes in flame shapes and NOx emissions through the complex flow interferences that exist within the mixing region. Mixing enhancement driven by coaxial air results in flame volume decrease, and such a diminished flame volume finally reduces NOx emissions significantly by decreasing NOx formation zone where a fuel/air mixture burns. It is found that mixing in the vicinity of high temperature zone mainly results from the increase of diffusive flux than the convective flux, and that the increase of mass diffusion is amplified as coaxial air is increased. Besides, it is reaffirmed that nonequilibrium chemistry including HO 2 /H 2 O 2 should be taken into account for NOx prediction and scaling analysis by comparing turbulent combustion models. In addition, it is found that coaxial air can break down the self-similarity law of flames by changing mixing mechanism, and that EINOx scaling parameters based on the self-similarity law of simple jet flames may not be eligible in coaxial air flames

  14. Flame Structure and Chemiluminescence Emissions of Inverse Diffusion Flames under Sinusoidally Driven Plasma Discharges

    Directory of Open Access Journals (Sweden)

    Maria Grazia De Giorgi

    2017-03-01

    Full Text Available Reduction of nitric oxides (NOx in aircraft engines and in gas turbines by lean combustion is of great interest in the design of novel combustion systems. However, the stabilization of the flame under lean conditions is a main issue. In this context, the present work investigates the effects of sinusoidal dielectric barrier discharge (DBD on a lean inverse diffusive methane/air flame in a Bunsen-type burner under different actuation conditions. The flame appearance was investigated with fixed methane loading (mass flux, but with varying inner airflow rate. High-speed flame imaging was done by using an intensified (charge-coupled device CCD camera equipped with different optical filters in order to selectively record signals from the chemiluminescent species OH*, CH*, or CO2* to evaluate the flame behavior in presence of plasma actuation. The electrical power consumption was less than 33 W. It was evident that the plasma flame enhancement was significantly influenced by the plasma discharges, particularly at high inner airflow rates. The flame structure changes drastically when the dissipated plasma power increases. The flame area decreases due to the enhancement of mixing and chemical reactions that lead to a more anchored flame on the quartz exit with a reduction of the flame length.

  15. Thermal-diffusional Instability in White Dwarf Flames: Regimes of Flame Pulsation

    Energy Technology Data Exchange (ETDEWEB)

    Xing, Guangzheng; Zhao, Yibo; Zhou, Cheng; Gao, Yang; Law, Chung K. [Center for Combustion Energy, Tsinghua University, Beijing 100084 (China); Modestov, Mikhail, E-mail: gaoyang-00@mails.tsinghua.edu.cn [Nordita, KTH Royal Institute of Technology and Stockholm University, SE-10691, Stockholm (Sweden)

    2017-05-20

    Thermal-diffusional pulsation behaviors in planar as well as outwardly and inwardly propagating white dwarf (WD) carbon flames are systematically studied. In the 1D numerical simulation, the asymptotic degenerate equation of state and simplified one-step reaction rates for nuclear reactions are used to study the flame propagation and pulsation in WDs. The numerical critical Zel’dovich numbers of planar flames at different densities ( ρ = 2, 3, and 4 × 10{sup 7} g cm{sup −3}) and of spherical flames (with curvature c = −0.01, 0, 0.01, and 0.05) at a particular density ( ρ = 2 × 10{sup 7} g cm{sup −3}) are presented. Flame front pulsation in different environmental densities and temperatures are obtained to form the regime diagram of pulsation, showing that carbon flames pulsate in the typical density of 2 × 10{sup 7} g cm{sup −3} and temperature of 0.6 × 10{sup 9} K. While being stable at higher temperatures, at relatively lower temperatures, the amplitude of the flame pulsation becomes larger. In outwardly propagating spherical flames the pulsation instability is enhanced and flames are also easier to quench due to pulsation at small radius, while the inwardly propagating flames are more stable.

  16. Scaling of turbulent flame speed for expanding flames with Markstein diffusion considerations

    Science.gov (United States)

    Chaudhuri, Swetaprovo; Wu, Fujia; Law, Chung K.

    2013-09-01

    In this paper we clarify the role of Markstein diffusivity, which is the product of the planar laminar flame speed and the Markstein length, on the turbulent flame speed and its scaling, based on experimental measurements on constant-pressure expanding turbulent flames. Turbulent flame propagation data are presented for premixed flames of mixtures of hydrogen, methane, ethylene, n-butane, and dimethyl ether with air, in near-isotropic turbulence in a dual-chamber, fan-stirred vessel. For each individual fuel-air mixture presented in this work and the recently published iso-octane data from Leeds, normalized turbulent flame speed data of individual fuel-air mixtures approximately follow a ReT,f0.5 scaling, for which the average radius is the length scale and thermal diffusivity is the transport property of the turbulence Reynolds number. At a given ReT,f, it is experimentally observed that the normalized turbulent flame speed decreases with increasing Markstein number, which could be explained by considering Markstein diffusivity as the leading dissipation mechanism for the large wave number flame surface fluctuations. Consequently, by replacing thermal diffusivity with the Markstein diffusivity in the turbulence Reynolds number definition above, it is found that normalized turbulent flame speeds could be scaled by ReT,M0.5 irrespective of the fuel, equivalence ratio, pressure, and turbulence intensity for positive Markstein number flames.

  17. Flame Color as a Lean Blowout Predictor

    Directory of Open Access Journals (Sweden)

    Rajendra R. Chaudhari

    2013-03-01

    Full Text Available The study characterizes the behavior of a premixed swirl stabilized dump plane combustor flame near its lean blow-out (LBO limit in terms of CH* chemiluminiscence intensity and observable flame color variations for a wide range of equivalence ratio, flow rates and degree of premixing (characterized by premixing length, Lfuel. LPG and pure methane are used as fuel. We propose a novel LBO prediction strategy based solely on the flame color. It is observed that as the flame approaches LBO, its color changes from reddish to blue. This observation is found to be valid for different levels of fuel-air premixing achieved by changing the available mixing length of the air and the fuel upstream of the dump plane although the flame dynamics were significantly different. Based on this observation, the ratio of the intensities of red and blue components of the flame as captured by a color CCD camera was used as a metric for detecting the proximity of the flame to LBO. Tests were carried out for a wide range of air flow rates and using LPG and CH4 as fuel. For all the operating conditions and both fuels tested, this ratio was found to monotonically decrease as LBO was approached. Moreover, the value of this ratio was within a small range close to LBO for all the cases investigated. This makes the ratio suitable as a metric for LBO detection at all levels of premixing.

  18. The FLAME project in Atomki

    International Nuclear Information System (INIS)

    Hunyadi, M.; Iski, N.

    2011-01-01

    Complete text of publication follows. Eleven regions of eight Central European countries have launched the FLAME Project in 2010 (Future Laboratory for the diffusion and Application of innovation in Material Sciences and Engineering) to start and manage a new initiative of a network for innovation activities in the MS and E sector. The project aimed at supporting actors in the field of materials science and exploiting their research and commercial potentials. FLAME partners encourage trans-regional cooperation between R and D centres, universities, start-ups and SMEs by helping companies to distribute their innovations and supporting research in transferring results to the market. The project will implement a new cooperation model: the 'Future Lab', where duly trained 'regional facilitation coaches' will assist SMEs in accessing the whole Central European MS and E market and research potential. Each Future Lab will be specialized on thematic fields and help to make efficient use of local and regional potentials. The three Future Labs will be hosted by the Austrian, Italian and Slovenian partner organizations. Figure 1. Competence and innovation landscape on the FLAME website. Source: http://www.flameurope.eu/mse-actors-145.html As the first step of project implementation in 2011 the competence and innovation maps within the participating regions were elaborated in order to list the relevant actors in the MS and E sector (Figure 1). In 2011, each project partner delegated two regional professionals as facilitation coaches to attend four training weeks across Europe. The facilitation coaches play an active role in the exchange of information and in motivating collaboration between research institutions and enterprises on technology based projects. The training sessions were located at four of the project partners: Kapfenberg/Austria (lead partner - Area m Styria); Warsaw/Poland (PP2 - Warsaw University of Technology); Debrecen/Hungary (PP5 - Atomki); Milan/Italy (PP

  19. The dilution effect on the extinction of wall diffusion flame

    Directory of Open Access Journals (Sweden)

    Ghiti Nadjib

    2014-12-01

    Full Text Available The dynamic process of the interaction between a turbulent jet diffusion methane flame and a lateral wall was experimentally studied. The evolution of the flame temperature field with the Nitrogen dilution of the methane jet flame was examined. The interaction between the diffusion flame and the lateral wall was investigated for different distance between the wall and the central axes of the jet flame. The dilution is found to play the central role in the flame extinction process. The flame response as the lateral wall approaches from infinity and the increasing of the dilution rate make the flame extinction more rapid than the flame without dilution, when the nitrogen dilution rate increase the flame temperature decrease.

  20. Flame Speed and Self-Similar Propagation of Expanding Turbulent Premixed Flames

    Science.gov (United States)

    Chaudhuri, Swetaprovo; Wu, Fujia; Zhu, Delin; Law, Chung K.

    2012-01-01

    In this Letter we present turbulent flame speeds and their scaling from experimental measurements on constant-pressure, unity Lewis number expanding turbulent flames, propagating in nearly homogeneous isotropic turbulence in a dual-chamber, fan-stirred vessel. It is found that the normalized turbulent flame speed as a function of the average radius scales as a turbulent Reynolds number to the one-half power, where the average radius is the length scale and the thermal diffusivity is the transport property, thus showing self-similar propagation. Utilizing this dependence it is found that the turbulent flame speeds from the present expanding flames and those from the Bunsen geometry in the literature can be unified by a turbulent Reynolds number based on flame length scales using recent theoretical results obtained by spectral closure of the transformed G equation.

  1. Flaming alcoholic drinks: flirting with danger.

    Science.gov (United States)

    Tan, Alethea; Frew, Quentin; Yousif, Ali; Ueckermann, Nicola; Dziewulksi, Peter

    2014-01-01

    Alcohol-related burn injuries carry significant mortality and morbidity rates. Flaming alcoholic beverages served in trendy bars and clubs are becoming increasingly popular. The dangers associated with an ignited alcoholic drink are often underestimated by party goers whose risk assessment ability is already impaired by heavy alcohol consumption. The authors present two cases demonstrating the varied severity of burn injuries associated with flaming alcoholic drinks, and their clinical management. Consumption of flaming alcoholic drinks poses potential risks for burn injuries. Further support is required to enable national and local agencies to implement effective interventions in drinking environments.

  2. Systems and methods for controlling flame instability

    KAUST Repository

    Cha, Min Suk

    2016-07-21

    A system (62) for controlling flame instability comprising: a nozzle (66) coupled to a fuel supply line (70), an insulation housing (74) coupled to the nozzle, a combustor (78) coupled to the nozzle via the insulation housing, where the combustor is grounded (80), a pressure sensor (82) coupled to the combustor and configured to detect pressure in the combustor, and an instability controlling assembly coupled to the pressure sensor and to an alternating current power supply (86), where, the instability controlling assembly can control flame instability of a flame in the system based on pressure detected by the pressure sensor.

  3. Aromatics oxidation and soot formation in flames

    Energy Technology Data Exchange (ETDEWEB)

    Howard, J.B.; Pope, C.J.; Shandross, R.A.; Yadav, T. [Massachusetts Institute of Technology, Cambridge (United States)

    1993-12-01

    This project is concerned with the kinetics and mechanisms of aromatics oxidation and soot and fullerenes formation in flames. The scope includes detailed measurements of profiles of stable and radical species concentrations in low-pressure one-dimensional premixed flames. Intermediate species identifications and mole fractions, fluxes, and net reaction rates calculated from the measured profiles are used to test postulated reaction mechanisms. Particular objectives are to identify and to determine or confirm rate constants for the main benzene oxidation reactions in flames, and to characterize fullerenes and their formation mechanisms and kinetics.

  4. Theory of Colored Flame Production

    Science.gov (United States)

    1964-03-20

    which should be considered in addition to thermal Spossibilities. He stated, "Another persistent impurity in the spectra 4 ±of CO flames is CuCi . These...is something of a mystery; it is possible that CuCI acts as a catalyst in the oxidation and receives ox- citation energy from the process". (f) Metal...2130~.0 1u.2 3274.0 3.8 9 3247.S 3.8 10 2. Cubr Land SpucztWu S032.2 4883.4 4810.4 72 4954.7 4 4879,3 8 4341.1 10 4288.u 7 S. Cuci band spectrwSA I A I

  5. Insights into flame-flow interaction during boundary layer flashback of swirl flames

    Science.gov (United States)

    Ranjan, Rakesh; Ebi, Dominik; Clemens, Noel

    2017-11-01

    Boundary layer flashback in swirl flames is a frequent problem in industrial gas turbine combustors. During this event, an erstwhile stable swirl flame propagates into the upstream region of the combustor, through the low momentum region in the boundary layer. Owing to the involvement of various physical factors such as turbulence, flame-wall interactions and flame-flow interactions, the current scientific understanding of this phenomenon is limited. The transient and three-dimensional nature of the swirl flow, makes it even more challenging to comprehend the underlying physics of the swirl flame flashback. In this work, a model swirl combustor with an axial swirler and a centerbody was used to carry out the flashback experiments. We employed high-speed chemiluminescence imaging and simultaneous stereoscopic PIV to understand the flow-flame interactions during flashback. A novel approach to reconstruct the three-dimensional flame surface using time-resolved slice information is utilized to gain insight into the flame-flow interaction. It is realized that the blockage effect imposed by the flame deflects the approaching streamlines in axial as well as azimuthal directions. A detailed interpretation of streamline deflection during boundary layer flashback shall be presented. This work was sponsored by the DOE NETL under Grant DEFC2611-FE0007107.

  6. Burning velocity and flame surface area in high Karlovitz number flames

    Science.gov (United States)

    Lapointe, Simon; Cheng, Lionel; Blanquart, Guillaume

    2017-11-01

    Accurate knowledge of the burning velocity of turbulent flames is of importance for many combustion devices. For low Karlovitz number flames, Damkohler proposed that the ratio of turbulent to laminar flame speed is proportional to the ratio of turbulent to laminar flame surface area. In recent DNS studies, it has been observed that Damkolher's scaling for low Karlovitz number flames still holds for high Karlovitz number flames. However, recent experimental studies have reported notable differences between global burning velocities and flame surface area measurements. In this work, the numerical and experimental results are further analyzed to explain the apparent contradiction. Emphasis is placed on identifying and quantifying potential experimental limitations at high Karlovitz numbers. More specifically, experimental flame surface measurements typically use binarized PLIF images. These images are two-dimensional and their resolution is limited by that of the PLIF system. The implications of using a two-dimensional iso-contour and the effects of the image resolution are assessed through post-processing of DNS datasets. Furthermore, the effects of integral length scale, Karlovitz number, and differential diffusion on the flame surface area are considered separately.

  7. Nanocellular foam with solid flame retardant

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Liang; Kelly-Rowley, Anne M.; Bunker, Shana P.; Costeux, Stephane

    2017-11-21

    Prepare nanofoam by (a) providing an aqueous solution of a flame retardant dissolved in an aqueous solvent, wherein the flame retardant is a solid at 23.degree. C. and 101 kiloPascals pressure when in neat form; (b) providing a fluid polymer composition selected from a solution of polymer dissolved in a water-miscible solvent or a latex of polymer particles in a continuous aqueous phase; (c) mixing the aqueous solution of flame retardant with the fluid polymer composition to form a mixture; (d) removing water and, if present, solvent from the mixture to produce a polymeric composition having less than 74 weight-percent flame retardant based on total polymeric composition weight; (e) compound the polymeric composition with a matrix polymer to form a matrix polymer composition; and (f) foam the matrix polymer composition into nanofoam having a porosity of at least 60 percent.

  8. Flame assisted synthesis of catalytic ceramic membranes

    DEFF Research Database (Denmark)

    Johansen, Johnny; Mosleh, Majid; Johannessen, Tue

    2004-01-01

    Membranes consisting of one or more metal oxides can be synthesized by flame pyrolysis. The general principle behind flame pyrolysis is the decomposition and oxidation of evaporated organo-metallic precursors in a flame, thereby forming metal oxide monomers. Because of the extreme supersaturation...... technology it is possible to make supported catalysts, composite metal oxides, catalytically active surfaces, and porous ceramic membranes. Membrane layers can be formed by using a porous substrate tube (or surface) as a nano-particle filter. The aerosol gas from the flame is led through a porous substrate......, membranes with pore sizes below 5 nm have been produced by this continuous filtration of nano-particles. In this way, top-layers with Knudsen separation have been achieved by a reduction of the pore size of three orders of magnitude within an hour. It has previously been shown that it also is possible...

  9. Counter-flow elutriation of clinical peripheral blood mononuclear cell concentrates for the production of dendritic and T cell therapies.

    Science.gov (United States)

    Stroncek, David F; Fellowes, Vicki; Pham, Chauha; Khuu, Hanh; Fowler, Daniel H; Wood, Lauren V; Sabatino, Marianna

    2014-09-17

    Peripheral blood mononuclear cells (PBMC) concentrates collected by apheresis are frequently used as starting material for cellular therapies, but the cell of interest must often be isolated prior to initiating manufacturing. The results of enriching 59 clinical PBMC concentrates for monocytes or lymphocytes from patients with solid tumors or multiple myeloma using a commercial closed system semi-automated counter-flow elutriation instrument (Elutra, Terumo BCT) were evaluated for quality and consistency. Elutriated monocytes (n = 35) were used to manufacture autologous dendritic cells and elutriated lymphocytes (n = 24) were used manufacture autologous T cell therapies. Elutriated monocytes with >10% neutrophils were subjected to density gradient sedimentation to reduce neutrophil contamination and elutriated lymphocytes to RBC lysis. Elutriation separated the PBMC concentrates into 5 fractions. Almost all of the lymphocytes, platelets and red cells were found in fractions 1 and 2; in contrast, most of the monocytes, 88.6 ± 43.0%, and neutrophils, 74.8 ± 64.3%, were in fraction 5. In addition, elutriation of 6 PBMCs resulted in relatively large quantities of monocytes in fractions 1 or 2. These 6 PBMCs contained greater quantities of monocytes than the other 53 PBMCs. Among fraction 5 isolates 38 of 59 contained >10% neutrophils. High neutrophil content of fraction 5 was associated with greater quantities of neutrophils in the PBMC concentrate. Following density gradient separation the neutrophil counts fell to 3.6 ± 3.4% (all products contained <10% neutrophils). Following red cell lysis of the elutriated lymphocyte fraction the lymphocyte recovery was 86.7 ± 24.0% and 34.3 ± 37.4% of red blood cells remained. Elutriation was consistent and effective for isolating monocytes and lymphocytes from PBMC concentrates for manufacturing clinical cell therapies, but further processing is often required.

  10. Efficient clinical-scale enrichment of lymphocytes for use in adoptive immunotherapy using a modified counterflow centrifugal elutriation program.

    Science.gov (United States)

    Powell, Daniel J; Brennan, Andrea L; Zheng, Zhaohui; Huynh, Hong; Cotte, Julio; Levine, Bruce L

    2009-01-01

    Clinical-scale lymphocyte enrichment from a leukapheresis product has been performed most routinely using costly magnetic bead separation systems that deplete monocytes, but this procedure may leave behind residual beads or antibodies in the enriched cell product. Counterflow centrifugal elutriation has been demonstrated previously to enrich monocytes efficiently for generation of dendritic cells. This study describes a modified elutriation procedure for efficient bead-free economical enrichment of lymphocytes from leukapheresis products from healthy donors and study subjects with human immunodeficiency virus (HIV) infection or malignancy. Modified program settings and conditions for the CaridianBCT Elutra device were investigated to optimize lymphocyte enrichment and recovery. Lymphocyte enrichment was measured using a novel approach utilizing cell sizing analysis on a Beckman Coulter Multisizer and confirmed by flow cytometry phenotypic analysis. Efficient enrichment and recovery of lymphocytes from leukapheresis cell products was achieved using modified elutriation settings for flow rate and fraction volume. Elutriation allowed for enrichment of larger numbers of lymphocytes compared with depletion of monocytes by bead adherence, with a trend toward increased lymphocyte purity and yield via elutriation, resulting in a substantial reduction in the cost of enrichment per cell. Importantly, significant lymphocyte enrichment could be accomplished using leukapheresis samples from healthy donors (n=12) or from study subjects with HIV infection (n=15) or malignancy (n=12). Clinical-scale closed-system elutriation can be performed efficiently for the selective enrichment of lymphocytes for immunotherapy protocols. This represents an improvement in cost, yield and purity over current methods that require the addition of monocyte-depleting beads.

  11. Characterization of flame radiosity in shrubland fires

    Science.gov (United States)

    Miguel G. Cruz; Bret W. Butler; Domingos X. Viegas; Pedro Palheiro

    2011-01-01

    The present study is aimed at quantifying the flame radiosity vertical profile and gas temperature in moderate to high intensity spreading fires in shrubland fuels. We report on the results from 11 experimental fires conducted over a range of fire rate of spread and frontal fire intensity varying respectively between 0.04-0.35ms-1 and 468-14,973kWm-1. Flame radiosity,...

  12. Analysis of radiation polymerization of flame retarder

    International Nuclear Information System (INIS)

    Enomoto, Ichiro; Sawai, Takeshi; Ametani, Kazuo

    1990-01-01

    It was found that when vinyl phosphonate oligomer was irradiated with electron beam, the decrease of thermogravity in three steps arose. It was presumed that the first decrease of weight was due to the vaporization of water. This value is nearly constant independent of dose, but when divided irradiation was carried out, as dose increased, the decrease of weight became less. Fire damages have increased as population concentrates into cities and overcrowding occurs. To make combustible materials as well as the textile products belonging to people flame-retardant has become a social problem. The flame retarders and the method of processing which do not generate harmful gas in combustion are demanded. The practical test on making fibers flame-retardant by using radiation graft polymerization has been carried out since 1984, and the method of processing without generating harmful gas was obtained. It is necessary to elucidate the basic property of flame retarders due to irradiation for further developing the technology of flame retardation. This time, the thermogravimetric change of the flame retarders polymerized with radiation was examined. The experimental method and the results are reported. (K.I.)

  13. Sensing flame structure by process tomography.

    Science.gov (United States)

    Liu, Jing; Liu, Shi; Zhou, Wanting; Qi, Xin; Lei, Jing; Mu, Huaiping

    2016-06-28

    Non-intrusive visualization of the structure of flames can offer us many advantages in studying the reaction mechanisms of combustion and observing special distributions of the parameters required for the development of equipment such as jet engines and gas turbines. Process tomography is a relatively new technique for such a task, but is useful owing to its fast speed and capability of detecting signals related to ionizations caused by chemical reactions and thermal effects. Electric capacitance tomography (ECT) is one of the process tomographic techniques. ECT usually comprises a sensor array of electrodes that detect permittivity variations in the measuring zone, a data-logging device and a computer that controls data acquisition and carries out image reconstruction. There have been studies on ECT imaging of flames; however, ECT has not been exploited sufficiently to reveal the inner structure of the flames. In this study, a sensor with planar electrodes is created, and the associated three-dimensional sensitivity map is generated by the finite-element method to detect flame structure. A series of experiments are carried out covering a range of feed rates of fuel and air. Data are collected by the ECT sensor and hardware. The results of the ECT reconstruction show good agreement with actual features, and the structure of the flame is found. This opens up a new route for the study of flames. This article is part of the themed issue 'Supersensing through industrial process tomography'. © 2016 The Author(s).

  14. Preparation of Flame Retardant Modified with Titanate for Asphalt Binder

    Directory of Open Access Journals (Sweden)

    Bo Li

    2014-01-01

    Full Text Available Improving the compatibility between flame retardant and asphalt is a difficult task due to the complex nature of the materials. This study explores a low dosage compound flame retardant and seeks to improve the compatibility between flame retardants and asphalt. An orthogonal experiment was designed taking magnesium hydroxide, ammonium polyphosphate, and melamine as factors. The oil absorption and activation index were tested to determine the effect of titanate on the flame retardant additive. The pavement performance test was conducted to evaluate the effect of the flame retardant additive. Oxygen index test was conducted to confirm the effect of flame retardant on flame ability of asphalt binder. The results of this study showed that the new composite flame retardant is more effective in improving the compatibility between flame retardant and asphalt and reducing the limiting oxygen index of asphalt binder tested in this study.

  15. A, a Brominated Flame Retardant

    Directory of Open Access Journals (Sweden)

    Tomomi Takeshita

    2013-01-01

    Full Text Available Tetrabromobisphenol A (TBBPA, a brominated flame retardant, has been found to exacerbate pneumonia in respiratory syncytial virus- (RSV- infected mice. We examined the effect of Brazilian propolis (AF-08 on the exacerbation of RSV infection by TBBPA exposure in mice. Mice were fed a powdered diet mixed with 1% TBBPA alone, 0.02% AF-08 alone, or 1% TBBPA and 0.02% AF-08 for four weeks and then intranasally infected with RSV. TBBPA exposure increased the pulmonary virus titer and level of IFN-γ, a representative marker of pneumonia due to RSV infection, in the lungs of infected mice without toxicity. AF-08 was significantly effective in reducing the virus titers and IFN-γ level increased by TBBPA exposure. Also, AF-08 significantly reduced proinflammatory cytokine (TNF-α and IL-6 levels in the lungs of RSV-infected mice with TBBPA exposure, but Th2 cytokine (IL-4 and IL-10 levels were not evidently increased. Neither TBBPA exposure nor AF-08 treatment affected the anti-RSV antibody production in RSV-infected mice. In flow cytometry analysis, AF-08 seemed to be effective in reducing the ratio of pulmonary CD8a+ cells in RSV-infected mice with TBBPA exposure. TBBPA and AF-08 did not exhibit anti-RSV activity in vitro. Thus, AF-08 probably ameliorated pneumonia exacerbated by TBBPA exposure in RSV-infected mice by limiting excess cellular immune responses.

  16. Turbulence-flame interactions in DNS of a laboratory high Karlovitz premixed turbulent jet flame

    Science.gov (United States)

    Wang, Haiou; Hawkes, Evatt R.; Chen, Jacqueline H.

    2016-09-01

    In the present work, direct numerical simulation (DNS) of a laboratory premixed turbulent jet flame was performed to study turbulence-flame interactions. The turbulent flame features moderate Reynolds number and high Karlovitz number (Ka). The orientations of the flame normal vector n, the vorticity vector ω and the principal strain rate eigenvectors ei are examined. The in-plane and out-of-plane angles are introduced to quantify the vector orientations, which also measure the flame geometry and the vortical structures. A general observation is that the distributions of these angles are more isotropic downstream as the flame and the flow become more developed. The out-of-plane angle of the flame normal vector, β, is a key parameter in developing the correction of 2D measurements to estimate the corresponding 3D quantities. The DNS results show that the correction factor is unity at the inlet and approaches its theoretical value of an isotropic distribution downstream. The alignment characteristics of n, ω and ei, which reflect the interactions of turbulence and flame, are also studied. Similar to a passive scalar gradient in non-reacting flows, the flame normal has a tendency to align with the most compressive strain rate, e3, in the flame, indicating that turbulence contributes to the production of scalar gradient. The vorticity dynamics are examined via the vortex stretching term, which was found to be the predominant source of vorticity generation balanced by dissipation, in the enstrophy transport equation. It is found that although the vorticity preferentially aligns with the intermediate strain rate, e2, the contribution of the most extensive strain rate, e1, to vortex stretching is comparable with that of the intermediate strain rate, e2. This is because the eigenvalue of the most extensive strain rate, λ1, is always large and positive. It is confirmed that the vorticity vector is preferentially positioned along the flame tangential plane, contributing

  17. Flame Quenching Dynamics of High Velocity Flames in Rectangular Cross-section Channels

    KAUST Repository

    Mahuthannan, Ariff Magdoom

    2017-01-05

    Understanding flame quenching for different conditions is necessary to develop safety devices like flame arrestors. In practical applications, the speed of a deflagration in the lab-fixed reference frame will be a strong function of the geometry through which the deflagration propagates. This study reports on the effect of the flame speed, at the entrance of a quenching section, on the quenching distance. A 2D rectangular channel joining two main spherical vessels is considered for studying this effect. Two different velocity regimes are investigated and referred to as configurations A, and B. For configuration A, the velocity of the flame is 20 m/s, while it is about 100 m/s for configuration B. Methane-air stoichiometric mixtures at 1 bar and 298 K are used. Simultaneous dynamic pressure measurements along with schlieren imaging are used to analyze the quenching of the flame. Risk assessment of re-ignition is also reported and analyzed.

  18. Launch Pad Flame Trench Refractory Materials

    Science.gov (United States)

    Calle, Luz M.; Hintze, Paul E.; Parlier, Christopher R.; Bucherl, Cori; Sampson, Jeffrey W.; Curran, Jerome P.; Kolody, Mark; Perusich, Steve; Whitten, Mary

    2010-01-01

    The launch complexes at NASA's John F. Kennedy Space Center (KSC) are critical support facilities for the successful launch of space-based vehicles. These facilities include a flame trench that bisects the pad at ground level. This trench includes a flame deflector system that consists of an inverted, V-shaped steel structure covered with a high temperature concrete material five inches thick that extends across the center of the flame trench. One side of the "V11 receives and deflects the flames from the orbiter main engines; the opposite side deflects the flames from the solid rocket boosters. There are also two movable deflectors at the top of the trench to provide additional protection to shuttle hardware from the solid rocket booster flames. These facilities are over 40 years old and are experiencing constant deterioration from launch heat/blast effects and environmental exposure. The refractory material currently used in launch pad flame deflectors has become susceptible to failure, resulting in large sections of the material breaking away from the steel base structure and creating high-speed projectiles during launch. These projectiles jeopardize the safety of the launch complex, crew, and vehicle. Post launch inspections have revealed that the number and frequency of repairs, as well as the area and size of the damage, is increasing with the number of launches. The Space Shuttle Program has accepted the extensive ground processing costs for post launch repair of damaged areas and investigations of future launch related failures for the remainder of the program. There currently are no long term solutions available for Constellation Program ground operations to address the poor performance and subsequent failures of the refractory materials. Over the last three years, significant liberation of refractory material in the flame trench and fire bricks along the adjacent trench walls following Space Shuttle launches have resulted in extensive investigations of

  19. Chaotic radiation/turbulence interactions in flames

    Energy Technology Data Exchange (ETDEWEB)

    Menguec, M.P.; McDonough, J.M.

    1998-11-01

    In this paper, the authors present a review of their recent efforts to model chaotic radiation-turbulence interactions in flames. The main focus is to characterize soot volume fraction fluctuations in turbulent diffusion flames, as they strongly contribute to these interaction. The approach is based on the hypothesis that the fluctuations of properties in turbulent flames are deterministic in nature, rather than random. The authors first discuss the theoretical details and then they briefly outline the experiments conducted to measure the scattered light signals from fluctuating soot particles along the axis of an ethylene-air diffusion flame. They compare the power spectra and time series obtained from experiments against the ad-hoc and rigorous models derived using a series of logistic maps. These logistic maps can be used in simulation of the fluctuations in these type of flames, without extensive computational effort or sacrifice of physical detail. Availability of accurate models of these kinds allows investigation of radiation-turbulence interactions at a more fundamental level than it was previously possible.

  20. Characteristics of diffusion flames with accelerated motion

    Directory of Open Access Journals (Sweden)

    Lou Bo

    2016-01-01

    Full Text Available The aim of this work is to present an experiment to study the characteristics of a laminar diffusion flame under acceleration. A Bunsen burner (nozzle diameter 8 mm, using liquefied petroleum gas as its fuel, was ignited under acceleration. The temperature field and the diffusion flame angle of inclination were visualised with the assistance of the visual display technology incorporated in MATLAB™. Results show that the 2-d temperature field under different accelerations matched the variation in average temperatures: they both experience three variations at different time and velocity stages. The greater acceleration has a faster change in average temperature with time, due to the accumulation of combustion heat: the smaller acceleration has a higher average temperature at the same speed. No matter what acceleration was used, in time, the flame angle of inclination increased, but the growth rate decreased until an angle of 90°: this could be explained by analysis of the force distribution within the flame. It is also found that, initially, the growth rate of angle with velocity under the greater acceleration was always smaller than that at lower accelerations; it was also different in flames with uniform velocity fire conditions.

  1. Daphnid life cycle response to new generation of flame retardants

    NARCIS (Netherlands)

    Waaijers, S.L.; Bleyenberg, T.E.; Dits, A; Schoorl, M.; Schütt, J; Kools, S.A.E.; de Voogt, P.; Admiraal, W.; Parsons, J.R.; Kraak, M.H.S.

    2013-01-01

    Relatively hazardous brominated flame retardants (BFRs) are currently substituted with halogen-free flame retardants (HFFRs). Consequently, information on their persistence, bioaccumulation and toxicity (PBT) is urgently needed. Therefore, we investigated the chronic toxicity to the water flea

  2. Beam steering effects in turbulent high pressure flames

    Energy Technology Data Exchange (ETDEWEB)

    Hemmerling, B.; Kaeppeli, B. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    The propagation of a laser beam through a flame is influenced by variations of the optical density. Especially in turbulent high pressure flames this may seriously limit the use of laser diagnostic methods. (author) 1 fig., 2 refs.

  3. Flame acceleration in the early stages of burning in tubes

    Energy Technology Data Exchange (ETDEWEB)

    Bychkov, Vitaly; Fru, Gordon; Petchenko, Arkady [Institute of Physics, Umeaa University, S-901 87 Umeaa (Sweden); Akkerman, V' yacheslav [Institute of Physics, Umeaa University, S-901 87 Umeaa (Sweden); Nuclear Safety Institute (IBRAE) of Russian Academy of Sciences, B. Tulskaya 52, 115191 Moscow (Russian Federation); Eriksson, Lars-Erik [Department of Applied Mechanics, Chalmers University of Technology, 412 96 Goeteborg (Sweden)

    2007-09-15

    Acceleration of premixed laminar flames in the early stages of burning in long tubes is considered. The acceleration mechanism was suggested earlier by Clanet and Searby [Combust. Flame 105 (1996) 225]. Acceleration happens due to the initial ignition geometry at the tube axis when a flame develops to a finger-shaped front, with surface area growing exponentially in time. Flame surface area grows quite fast but only for a short time. The analytical theory of flame acceleration is developed, which determines the growth rate, the total acceleration time, and the maximal increase of the flame surface area. Direct numerical simulations of the process are performed for the complete set of combustion equations. The simulations results and the theory are in good agreement with the previous experiments. The numerical simulations also demonstrate flame deceleration, which follows acceleration, and the so-called ''tulip flames''. (author)

  4. Aerothermodynamic properties of stretched flames in enclosures

    Science.gov (United States)

    Rotman, D. A.; Oppenheim, A. K.

    Flames are stretched by being pulled along their frontal surface by the flow field in which they reside. Their trajectories tend to approach particle paths, acquiring eventually the role of contact boundaries, -interfaces between the burnt and unburnt medium that may broaden solely as a consequence of diffusion. Fundamental properties of flow fields governing such flames are determined here on the basis of the zero Mach number model, providng a rational method of approach to the computational analysis of combustion fields in enclosures where, besides the aerodynamic properties flow, the thermodynamic process of compression must be taken into account. To illustrate its application, the method is used to reveal the mechanism of formation of a tulip-shape flame in a rectangular enclosure under nonturbulent flow conditions.

  5. Effectiveness of Flame Retardants in TufFoam.

    Energy Technology Data Exchange (ETDEWEB)

    Abelow, Alexis Elizabeth [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Nissen, April [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Massey, Lee Taylor [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Whinnery, LeRoy L. [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

    2017-12-01

    An investigation of polyurethane foam filled with known flame retardant fillers including hydroxides, melamine, phosphate-containing compounds, and melamine phosphates was carried out to produce a low-cost material with high flame retardant efficiency. The impact of flame retardant fillers on the physical properties such a s composite foam density, glass transition temperature, storage modulus, and thermal expansion of composite foams was investigated with the goal of synthesizing a robust rigid foam with excellent flame retardant properties.

  6. Numerical modelling of ion transport in flames

    KAUST Repository

    Han, Jie

    2015-10-20

    This paper presents a modelling framework to compute the diffusivity and mobility of ions in flames. The (n, 6, 4) interaction potential is adopted to model collisions between neutral and charged species. All required parameters in the potential are related to the polarizability of the species pair via semi-empirical formulas, which are derived using the most recently published data or best estimates. The resulting framework permits computation of the transport coefficients of any ion found in a hydrocarbon flame. The accuracy of the proposed method is evaluated by comparing its predictions with experimental data on the mobility of selected ions in single-component neutral gases. Based on this analysis, the value of a model constant available in the literature is modified in order to improve the model\\'s predictions. The newly determined ion transport coefficients are used as part of a previously developed numerical approach to compute the distribution of charged species in a freely propagating premixed lean CH4/O2 flame. Since a significant scatter of polarizability data exists in the literature, the effects of changes in polarizability on ion transport properties and the spatial distribution of ions in flames are explored. Our analysis shows that changes in polarizability propagate with decreasing effect from binary transport coefficients to species number densities. We conclude that the chosen polarizability value has a limited effect on the ion distribution in freely propagating flames. We expect that the modelling framework proposed here will benefit future efforts in modelling the effect of external voltages on flames. Supplemental data for this article can be accessed at http://dx.doi.org/10.1080/13647830.2015.1090018. © 2015 Taylor & Francis.

  7. Numerical modelling of ion transport in flames

    Science.gov (United States)

    Han, Jie; Belhi, Memdouh; Bisetti, Fabrizio; Mani Sarathy, S.

    2015-11-01

    This paper presents a modelling framework to compute the diffusivity and mobility of ions in flames. The (n, 6, 4) interaction potential is adopted to model collisions between neutral and charged species. All required parameters in the potential are related to the polarizability of the species pair via semi-empirical formulas, which are derived using the most recently published data or best estimates. The resulting framework permits computation of the transport coefficients of any ion found in a hydrocarbon flame. The accuracy of the proposed method is evaluated by comparing its predictions with experimental data on the mobility of selected ions in single-component neutral gases. Based on this analysis, the value of a model constant available in the literature is modified in order to improve the model's predictions. The newly determined ion transport coefficients are used as part of a previously developed numerical approach to compute the distribution of charged species in a freely propagating premixed lean CH4/O2 flame. Since a significant scatter of polarizability data exists in the literature, the effects of changes in polarizability on ion transport properties and the spatial distribution of ions in flames are explored. Our analysis shows that changes in polarizability propagate with decreasing effect from binary transport coefficients to species number densities. We conclude that the chosen polarizability value has a limited effect on the ion distribution in freely propagating flames. We expect that the modelling framework proposed here will benefit future efforts in modelling the effect of external voltages on flames. Supplemental data for this article can be accessed at http://dx.doi.org/10.1080/13647830.2015.1090018.

  8. Thermal-Diffusional Instability in White Dwarf Flames: Regimes of Flame Pulsation

    OpenAIRE

    Xing, Guangzheng; Zhao, Yibo; Modestov, Mikhail; Zhou, Cheng; Gao, Yang; Law, Chung K.

    2017-01-01

    Thermal-diffusional pulsation behaviors in planar as well as outwardly and inwardly propagating white dwarf carbon flames are systematically studied. In the 1D numerical simulation, the asymptotic degenerate equation of state and simplified one-step reaction rates for nuclear reactions are used to study the flame propagation and pulsation in white dwarfs. The numerical critical Zel'dovich numbers of planar flames at different densities ($\\rho=2$, 3 and 4$\\times 10^7$~g/cm$^3$) and of spherica...

  9. The Interaction of High-Speed Turbulence with Flames: Global Properties and Internal Flame Structure

    Science.gov (United States)

    2009-09-28

    piloted premixed jet burner was used to achieve Ul/S L in the range 40 − 390, corresponding to Karlovitz numbers Ka = 100 − 3500 and Damköhler...configuration and Ul/S L = 20 in the case of a bunsen flame [14] (also see the review by [5]). In all of these studies, the reaction zone has a thin sheet...of high-speed turbulent combustion in such different systems as the flat thermonuclear flame in degenerate matter and the jet- burner flame in

  10. Synthesis of Nano-Particles in Flames

    DEFF Research Database (Denmark)

    Johannessen, Tue

    The scope of this work is to investigate the synthesis of aluminum oxide particles in flames from the combustion of an aluminum alkoxide precursor.A general introduction to particles formation in the gas phase is presented with emphasis on the mechanisms that control the particle morphology after...... energy expression.Furthermore, the model is validated by comparison with experimental data of the flame synthesis of titania by combustion of TiCl4 previously presented by Pratsinis et al. (1996).The combination of particle dynamics and CFD simulations has proved to be an efficient method...

  11. 30 CFR 75.600-1 - Approved cables; flame resistance.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Approved cables; flame resistance. 75.600-1 Section 75.600-1 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE... cables; flame resistance. Cables shall be accepted or approved by MSHA as flame resistant. [57 FR 61223...

  12. Phosphorus flame retardants: Properties, production, environmental occurrence, toxicity and analysis

    NARCIS (Netherlands)

    van der Veen, I.; de Boer, J.

    2012-01-01

    Since the ban on some brominated flame retardants (BFRs), phosphorus flame retardants (PFRs), which were responsible for 20% of the flame retardant (FR) consumption in 2006 in Europe, are often proposed as alternatives for BFRs. PFRs can be divided in three main groups, inorganic, organic and

  13. Preparation and characterizations of flame retardant polyamide 66 fiber

    Science.gov (United States)

    Li, Y. Y.; Liu, K.; Xiao, R.

    2017-06-01

    The polyamide 66 (PA66) is one of the most important thermoplastic materials, but it has the drawback of flammability. So the flame retardant PA66 was prepared by condensation polymerization using nylon salt and DOPO-based flame retardant in this paper. Then the flame retardant PA66 fiber was manufactured via melt spinning. The properties of flame retardant PA66 and flame retardant PA66 fiber were investigated by relative viscosity, differential scanning calorimetry (DSC), tensile test, vertical burning test (UL94) and limiting oxygen index (LOI) test. Although the loading of the DOPO-based flame retardant decreased the molecular weight, the melting temperature, the crystallinity and the mechanical properties of flame retardant PA66, the flame retardancy properties improved. The flame retardant PA66 loaded with 5.5 wt% of DOPO-based flame retardant can achieve a UL94 V-0 rating with a LOI value of 32.9%. The tenacity at break decreased from 4.51 cN·dtex-1 for PA66 fiber to 2.82 cN·dtex-1 for flame retardant PA66 fiber which still satisfied the requirements for fabrics. The flame retardant PA66 fiber expanded the application of PA66 materials which had a broad developing prospect.

  14. Energy cascade with small-scale thermalization, counterflow metastability, and anomalous velocity of vortex rings in Fourier-truncated Gross-Pitaevskii equation

    International Nuclear Information System (INIS)

    Krstulovic, Giorgio; Brachet, Marc

    2011-01-01

    The statistical equilibria of the (conservative) dynamics of the Gross-Pitaevskii equation (GPE) with a finite range of spatial Fourier modes are characterized using a new algorithm, based on a stochastically forced Ginzburg-Landau equation (SGLE), that directly generates grand-canonical distributions. The SGLE-generated distributions are validated against finite-temperature GPE-thermalized states and exact (low-temperature) results obtained by steepest descent on the (grand-canonical) partition function. A standard finite-temperature second-order λ transition is exhibited. A mechanism of GPE thermalization through a direct cascade of energy is found using initial conditions with mass and energy distributed at large scales. A long transient with partial thermalization at small scales is observed before the system reaches equilibrium. Vortices are shown to disappear as a prelude to final thermalization and their annihilation is related to the contraction of vortex rings due to mutual friction. Increasing the amount of dispersion at the truncation wave number is shown to slow thermalization and vortex annihilation. A bottleneck that produces spontaneous effective self-truncation with partial thermalization is characterized in the limit of large dispersive effects. Metastable counterflow states, with nonzero values of momentum, are generated using the SGLE algorithm. Spontaneous nucleation of the vortex ring is observed and the corresponding Arrhenius law is characterized. Dynamical counterflow effects on vortex evolution are investigated using two exact solutions of the GPE: traveling vortex rings and a motionless crystal-like lattice of vortex lines. Longitudinal effects are produced and measured on the crystal lattice. A dilatation of vortex rings is obtained for counterflows larger than their translational velocity. The vortex ring translational velocity has a dependence on temperature that is an order of magnitude above that of the crystal lattice, an effect

  15. Flame exposure time on Langmuir probe degradation, ion density, and thermionic emission for flame temperature

    Science.gov (United States)

    Doyle, S. J.; Salvador, P. R.; Xu, K. G.

    2017-11-01

    The paper examines the effect of exposure time of Langmuir probes in an atmospheric premixed methane-air flame. The effects of probe size and material composition on current measurements were investigated, with molybdenum and tungsten probe tips ranging in diameter from 0.0508 to 0.1651 mm. Repeated prolonged exposures to the flame, with five runs of 60 s, resulted in gradual probe degradations (-6% to -62% area loss) which affected the measurements. Due to long flame exposures, two ion saturation currents were observed, resulting in significantly different ion densities ranging from 1.16 × 1016 to 2.71 × 1019 m-3. The difference between the saturation currents is caused by thermionic emissions from the probe tip. As thermionic emission is temperature dependent, the flame temperature could thus be estimated from the change in current. The flame temperatures calculated from the difference in saturation currents (1734-1887 K) were compared to those from a conventional thermocouple (1580-1908 K). Temperature measurements obtained from tungsten probes placed in rich flames yielded the highest percent error (9.66%-18.70%) due to smaller emission current densities at lower temperatures. The molybdenum probe yielded an accurate temperature value with only 1.29% error. Molybdenum also demonstrated very low probe degradation in comparison to the tungsten probe tips (area reductions of 6% vs. 58%, respectively). The results also show that very little exposure time (<5 s) is needed to obtain a valid ion density measurement and that prolonged flame exposures can yield the flame temperature but also risks damage to the Langmuir probe tip.

  16. On open and closed tips of bunsen burner flames

    Science.gov (United States)

    Kozlovsky, G.; Sivashinsky, G. I.

    1994-04-01

    An adiabatic, constant-density reaction-diffusion-advection model for the Bunsen burner flame tip is studied numerically. It is shown that for Lewis numbers exceeding unity the reaction rate and flame speed gradually increase toward the flame tip. For small Lewis numbers the picture is quite different. The reaction rate drops near the tip. In spite of this the flame survives and, moreover, manages to consume all the fuel supplied to the reaction zone. There is no leakage of the fuel through the front. The flame speed varies nonmonotonously along the front from gradual reduction to steep increase near the tip.

  17. Flexible PVC flame retarded with expandable graphite

    CSIR Research Space (South Africa)

    Focke, WW

    2014-02-01

    Full Text Available The utility of expandable graphite as a flame retardant for PVC, plasticized with 60 phr of a phosphate ester, was investigated. Cone calorimeter results, at a radiant flux of 35 kW m 2, revealed that adding only 5 wt.% expandable graphite lowered...

  18. Hormonal activities of new brominated flame retardants

    Czech Academy of Sciences Publication Activity Database

    Ezechiáš, Martin; Svobodová, Kateřina; Cajthaml, Tomáš

    2012-01-01

    Roč. 87, č. 7 (2012), s. 820-824 ISSN 0045-6535 R&D Projects: GA ČR GA104/09/0694 Institutional research plan: CEZ:AV0Z50200510 Keywords : Brominated flame retardants * 2,4,6-Tribromophenol * Endocrine disruptors Subject RIV: EE - Microbiology, Virology Impact factor: 3.137, year: 2012

  19. Optimization of Flame Atomic Absorption Spectrometry for ...

    African Journals Online (AJOL)

    Optimization of Flame Atomic Absorption Spectrometry for Measurement of High Concentrations of Arsenic and Selenium. ... This procedure allowed a rapid determination of As from minimum 4.462 mg/L to higher concentrations without sample pretreatment. Besides As, this method successfully measured Se concentrations ...

  20. Radical recombinations in acetylene-air flames

    NARCIS (Netherlands)

    Zeegers, P.J.Th.; Alkemade, C.T.J.

    In this paper an analysis is given of the behaviour of excess radical concentrations, H, OH and O as a function of height above the reaction zone in premixed acetylene-air flames at 2–200° to 2400°K and 1 atmosphere pressure. The intensity was measured of the Li resonance line which is related to

  1. Brominated flame retardants and endocrine disruption

    NARCIS (Netherlands)

    Vos, J.G.; Becher, G.; Berg, van den M.; Boer, de J.; Leonards, P.E.G.

    2003-01-01

    From an environmental point of view, an increasing important group of organohalogen compounds are the brominated flame retardants (BFRs), which are widely used in polymers and textiles and applied in construction materials, furniture, and electronic equipment. BFRs with the highest production volume

  2. Brominated flame retardants and endocrine disruption

    NARCIS (Netherlands)

    Vos, Joseph G.; Becher, Georg; Van Den Berg, Martin; Leonards, Pim E G

    2003-01-01

    From an environmental point of view, an increasing important group of organo-halogen compounds are the brominated flame retardants (BFRs), which are widely used in polymers and textiles and applied in construction materials, furniture, and electronic equipment. BFRs with the highest production

  3. The VLT-FLAMES Tarantula survey

    NARCIS (Netherlands)

    Taylor, W.D.; Evans, C.J.; Henault-Brunet, V.; Bastian, N.; Beletsky, Y.; Bestenlehner, J.; Brott, I.; Cantiello, M.; Carraro, G.; Clark, J.S.; Crowther, P.A.; de Koter, A.; de Mink, S.E.; Doran, E.; Dufton, P.L.; Dunstall, P.; Gieles, M.; Grafener, G.; Herrero, A.; Howarth, I.D.; Langer, N.; Lennon, D.J.; Maiz-Apellaniz, J; Markova, N.; Najarro, P.; Puls, J.; Sana, H.A.A.; Simon-Diaz, S.; Smartt, S.J.; Stroud, V.E.; van Loon, J.T.; Vink, J.S.; Walborn, N.R.

    2011-01-01

    The VLT-FLAMES Tarantula Survey is an ESO Large Programme that has provided multi-epoch spectroscopy of over 1000 stars in the 30 Doradus region in the Large Magellanic Cloud. Armed with this unique dataset the assembled consortium is now addressing a broad range of fundamental questions in both

  4. Effect of Oxygen Enrichment in Propane Laminar Diffusion Flames under Microgravity and Earth Gravity Conditions

    Science.gov (United States)

    Bhatia, Pramod; Singh, Ravinder

    2017-06-01

    Diffusion flames are the most common type of flame which we see in our daily life such as candle flame and match-stick flame. Also, they are the most used flames in practical combustion system such as industrial burner (coal fired, gas fired or oil fired), diesel engines, gas turbines, and solid fuel rockets. In the present study, steady-state global chemistry calculations for 24 different flames were performed using an axisymmetric computational fluid dynamics code (UNICORN). Computation involved simulations of inverse and normal diffusion flames of propane in earth and microgravity condition with varying oxidizer compositions (21, 30, 50, 100 % O2, by mole, in N2). 2 cases were compared with the experimental result for validating the computational model. These flames were stabilized on a 5.5 mm diameter burner with 10 mm of burner length. The effect of oxygen enrichment and variation in gravity (earth gravity and microgravity) on shape and size of diffusion flames, flame temperature, flame velocity have been studied from the computational result obtained. Oxygen enrichment resulted in significant increase in flame temperature for both types of diffusion flames. Also, oxygen enrichment and gravity variation have significant effect on the flame configuration of normal diffusion flames in comparison with inverse diffusion flames. Microgravity normal diffusion flames are spherical in shape and much wider in comparison to earth gravity normal diffusion flames. In inverse diffusion flames, microgravity flames were wider than earth gravity flames. However, microgravity inverse flames were not spherical in shape.

  5. Laminar Flame Speeds of Gasoline Surrogates Measured with the Flat Flame Method

    KAUST Repository

    Liao, Y.-H.

    2016-01-27

    © 2016 American Chemical Society. The adiabatic, laminar flame speeds of gasoline surrogates at atmospheric pressure over a range of equivalence ratios of = 0.8-1.3 and unburned gas temperatures of 298-400 K are measured with the flat flame method, which produces a one-dimensional flat flame free of stretch. Surrogates used in the current work are the primary reference fuels (PRFs, mixtures of n-heptane and isooctane), the toluene reference fuels (TRFs, mixtures of toluene and PRFs), and the ethanol reference fuels (ERFs, mixtures of ethanol and PRFs). In general, there is good agreement between the present work and the literature data for single-component fuel and PRF mixtures. Surrogates of TRF mixtures are found to exhibit comparable flame speeds to a real gasoline, while there is discrepancy observed between isooctane and gasoline. Moreover, the laminar flame speeds of TRF mixtures with similar fractions of n-heptane are found to be insensitive to the quantity of toluene in the mixture. Mixtures of ERFs exhibit comparable flame speeds to those of TRFs with similar mole fractions of n-heptane and isooctane.

  6. Analysis of Flame Extinguishment and Height in Low Frequency Acoustically Excited Methane Jet Diffusion Flame

    Science.gov (United States)

    Zong, Ruowen; Kang, Ruxue; Liu, Chen; Zhang, Zhiyang; Zhi, Youran

    2018-01-01

    The exploration of microgravity conditions in space is increasing and existing fire extinguishing technology is often inadequate for fire safety in this special environment. As a result, improving the efficiency of portable extinguishers is of growing importance. In this work, a visual study of the effects on methane jet diffusion flames by low frequency sound waves is conducted to assess the extinguishing ability of sound waves. With a small-scale sound wave extinguishing bench, the extinguishing ability of certain frequencies of sound waves are identified, and the response of the flame height is observed and analyzed. Results show that the flame structure changes with disturbance due to low frequency sound waves of 60-100 Hz, and quenches at effective frequencies in the range of 60-90 Hz. In this range, 60 Hz is considered to be the quick extinguishing frequency, while 70-90 Hz is the stable extinguishing frequency range. For a fixed frequency, the flame height decreases with sound pressure level (SPL). The flame height exhibits the greatest sensitivity to the 60 Hz acoustic waves, and the least to the 100 Hz acoustic waves. The flame height decreases almost identically with disturbance by 70-90 Hz acoustic waves.

  7. Turbulent Flame Speed Scaling for Positive Markstein Number Expanding Flames in Near Isotropic Turbulence

    Science.gov (United States)

    Chaudhuri, Swetaprovo; Wu, Fujia; Law, Chung

    2012-11-01

    In this work we clarify the role of Markstein diffusivity on turbulent flame speed and it's scaling, from analysis and experimental measurements on constant-pressure expanding flames propagating in near isotropic turbulence. For all C0-C4 hydrocarbon-air mixtures presented in this work and recently published C8 data from Leeds, the normalized turbulent flame speed data of individual mixtures approximately follows the recent theoretical and experimental ReT, f 0 . 5 scaling, where the average radius is the length scale and thermal diffusivity is the transport property. We observe that for a constant ReT, f 0 . 5 , the normalized turbulent flame speed decreases with increasing Mk. This could be explained by considering Markstein diffusivity as the large wavenumber, flame surface fluctuation dissipation mechanism. As originally suggested by the theory, replacing thermal diffusivity with Markstein diffusivity in the turbulence Reynolds number definition above, the present and Leeds dataset could be scaled by the new ReT, f 0 . 5 irrespective of the fuel considered, equivalence ratio, pressure and turbulence intensity for positive Mk flames. This work was supported by the Combustion Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Basic Energy Sciences under Award Number DE-SC0001198 and by the Air Force Office of Scientific Research.

  8. Flame retardancy and thermal degradation of cotton textiles based on UV-curable flame retardant coatings

    International Nuclear Information System (INIS)

    Xing, Weiyi; Jie, Ganxin; Song, Lei; Hu, Shuang; Lv, Xiaoqi; Wang, Xin; Hu, Yuan

    2011-01-01

    The flame retardant coatings were prepared through UV-curable technique using tri(acryloyloxyethyl) phosphate (TAEP) and triglycidyl isocyanurate acrylate (TGICA). Results from FTIR-ATR spectroscopy and scanning electron microscopy (SEM) showed that flame retardant coatings were successfully coated onto the surface of cotton fabrics. The flame retardancy of the treated fabrics was studied by Micro-scale Combustion Calorimeter (MCC) and limited oxygen index (LOI). The cottons coated flame retardant coatings had the lower peak heat release rate (PHRR), heat release capacity (HRC), total heat of combustion (THC) and higher LOI value compared with untreated cotton. The results from TGA test showed that the flame retardant coatings lowered the decomposition temperature of treated fabric. The thermal decomposition of cottons was monitored by real time FTIR analysis and thermogravimetric analysis/infrared spectrometry (TGA-IR). The enhanced flame retardant action might be caused by thermal decomposition of TAEP structure, producing acidic intermediates, which could react with fabrics to alter its thermal decomposition process.

  9. Leading-Edge Velocities and Lifted Methane Jet Flame Stability

    Directory of Open Access Journals (Sweden)

    W. Wang

    2010-01-01

    Full Text Available Current interest exists in understanding reaction-zone dynamics and mechanisms with respect to how they counterpropagate against incoming reactants. Images of flame position and flow-field morphology are presented from flame chemiluminescence and particle image velocimetry (PIV measurements. In the present study, PIV experiments were carried out to measure the methane jet lifted-flame flow-field velocities in the vicinity of the flame leading edge. Specifically, velocity fields within the high-temperature zone were examined in detail, which complements previous studies, whose prime focus is the flow-field upstream of the high-temperature boundary. PIV data is used not only to determine the velocities, but, along with chemiluminescence images, to also indicate the approximate location of the reaction zone (further supported by/through the leading-edge flame velocity distributions. The velocity results indirectly support the concept that the flame is anchored primarily through the mechanism of partially premixed flame propagation.

  10. Unsteady motion of a Bunsen type premixed flame with burner rotation

    OpenAIRE

    後藤田, 浩; 植田, 利久; Hiroshi, Gotoda; Toshihisa, Ueda; 慶大理工; 慶大理工; School of Science for Open and Environmental Systems, Keio University; School of Science for Open and Environmental Systems, Keio University

    2001-01-01

    Characteristics of the unsteady motion of a Bunsen type premixed flame with bumer rotation are experimentally investigated. Time variations of the flame tip location are measured by using a laser tomographic mcthod. A non-periodically oscillating flame is observed between the periodically oscillating flame and the eccentric flame. The results show that the attracter of the periodically oscillating flame becomes stable limit cycle and the attractor of the eccentric flame is concentrated on a p...

  11. Highly turbulent combustion: A study of lifted and shredded flames

    Science.gov (United States)

    Ratner, Albert

    The impact of turbulence on flame chemistry in highly turbulent flames has been studied in order to test existing theories and produce data that are useful to the computer modeling community. In these flames, the fuel is injected separately from the air, but a significant amount of premixing occurs prior to combustion. By employing Particle Image Velocimetry (PIV), Planar Laser Induced Fluorescence (PLIF) of chemical species, and exhaust gas sampling, the effect of turbulence on flame chemistry has been quantified for a highly lifted, supersonic flame and for a highly swirled, shredded flame. In the supersonic flame, OH PLIF measurements were combined with combustion efficiency measurements and PIV to help to understand the mixing and flame structure. Negative velocities of more than 200 m/s were identified in the recirculating zones. Mechanisms of fuel-air mixing that result in decreased combustion efficiencies were identified. In the shredded flame, an ultra-high turbulence region was generated to examine what occurs when reaction layers encounter high turbulence levels. The flame was probed with simultaneous CH and OH PLIF and then simultaneous PIV and OH PLIF. It was found that the normalized turbulence level, even though it was ten-times greater than any previous imaging study, still produced no measurable impact on flame reaction layer thickness. This flame was also quantified by measurements of Flame Surface Density (Sigma). The thin flamelet assumption of flamelet theory is found to be valid in these highly turbulent flames. Data are presented that can be used to assess computational models as well as to provide insight into the physical processes of turbulent combustion.

  12. Phase-resolved characterization of vortex-flame interaction in a turbulent swirl flame

    Science.gov (United States)

    Stöhr, M.; Sadanandan, R.; Meier, W.

    2011-10-01

    The relation between flow field and flame structure of a turbulent swirl flame is investigated using simultaneous particle image velocimetry (PIV) and planar laser-induced fluorescence of OH (OH-PLIF). The measurements are performed in one axial and three transverse sections through the combustion chamber of a gas turbine model combustor, which is operated with methane and air under atmospheric pressure. Analysis of the velocity fields using proper orthogonal decomposition (POD) shows that the dominant unsteady flow structure is a so-called precessing vortex core (PVC). In each of the four sections, the PVC is represented by a characteristic pair of POD eigenmodes, and the phase angle of the precession can be determined for each instantaneous velocity field from its projection on this pair. Phase-conditioned averages of velocity field and OH distribution are thereby obtained and reveal a pronounced effect of the PVC in the form of convection-enhanced mixing. The increased mixing causes a rapid ignition of the fresh gas, and the swirling motion of the PVC leads to an enlarged flame surface due to flame roll-up. A three-dimensional representation shows that the PVC is accompanied by a co-precessing vortex in the outer shear layer, which, however, has no direct impact on the flame. As an alternative to phase averaging, a low-order representation of the phase-resolved dynamics is calculated based on the first pair of POD modes. It is found that small-scale structures are represented more accurately in the phase averages, whereas the low-order model has a considerable smoothing effect and therefore provides less detailed information. The findings demonstrate that the combined application of POD, PIV, and PLIF can provide detailed insights into flow-flame interaction in turbulent flames.

  13. Experimental Investigation of Premixed Turbulent Hydrocarbon/Air Bunsen Flames

    Science.gov (United States)

    Tamadonfar, Parsa

    Through the influence of turbulence, the front of a premixed turbulent flame is subjected to the motions of eddies that leads to an increase in the flame surface area, and the term flame wrinkling is commonly used to describe it. If it is assumed that the flame front would continue to burn locally unaffected by the stretch, then the total turbulent burning velocity is expected to increase proportionally to the increase in the flame surface area caused by wrinkling. When the turbulence intensity is high enough such that the stretch due to hydrodynamics and flame curvature would influence the local premixed laminar burning velocity, then the actual laminar burning velocity (that is, flamelet consumption velocity) should reflect the influence of stretch. To address this issue, obtaining the knowledge of instantaneous flame front structures, flame brush characteristics, and burning velocities of premixed turbulent flames is necessary. Two axisymmetric Bunsen-type burners were used to produce premixed turbulent flames, and three optical measurement techniques were utilized: Particle image velocimetry to measure the turbulence statistics; Rayleigh scattering method to measure the temperature fields of premixed turbulent flames, and Mie scattering method to visualize the flame front contours of premixed turbulent flames. Three hydrocarbons (methane, ethane, and propane) were used as the fuel in the experiments. The turbulence was generated using different perforated plates mounted upstream of the burner exit. A series of comprehensive parameters including the thermal flame front thickness, characteristic flame height, mean flame brush thickness, mean volume of the turbulent flame region, two-dimensional flame front curvature, local flame front angle, two-dimensional flame surface density, wrinkled flame surface area, turbulent burning velocity, mean flamelet consumption velocity, mean turbulent flame stretch factor, mean turbulent Markstein length and number, and mean

  14. A simple one-step chemistry model for partially premixed hydrocarbon combustion

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez-Tarrazo, Eduardo [Instituto Nacional de Tecnica Aeroespacial, Madrid (Spain); Sanchez, Antonio L. [Area de Mecanica de Fluidos, Universidad Carlos III de Madrid, Leganes 28911 (Spain); Linan, Amable [ETSI Aeronauticos, Pl. Cardenal Cisneros 3, Madrid 28040 (Spain); Williams, Forman A. [Department of Mechanical and Aerospace Engineering, University of California San Diego, La Jolla, CA 92093-0411 (United States)

    2006-10-15

    This work explores the applicability of one-step irreversible Arrhenius kinetics with unity reaction order to the numerical description of partially premixed hydrocarbon combustion. Computations of planar premixed flames are used in the selection of the three model parameters: the heat of reaction q, the activation temperature T{sub a}, and the preexponential factor B. It is seen that changes in q with equivalence ratio f need to be introduced in fuel-rich combustion to describe the effect of partial fuel oxidation on the amount of heat released, leading to a universal linear variation q(f) for f>1 for all hydrocarbons. The model also employs a variable activation temperature T{sub a}(f) to mimic changes in the underlying chemistry in rich and very lean flames. The resulting chemistry description is able to reproduce propagation velocities of diluted and undiluted flames accurately over the whole flammability limit. Furthermore, computations of methane-air counterflow diffusion flames are used to test the proposed chemistry under nonpremixed conditions. The model not only predicts the critical strain rate at extinction accurately but also gives near-extinction flames with oxygen leakage, thereby overcoming known predictive limitations of one-step Arrhenius kinetics. (author)

  15. Assessing Pediatric Nurses' Knowledge About Chemical Flame Retardants.

    Science.gov (United States)

    Distelhorst, Laura; Bieda, Amy; DiMarco, Marguerite; Tullai-McGuinness, Susan

    Chemical flame retardants are routinely applied to children's products and are harmful to their health. Pediatric nurses are in a key position to provide education to caregivers on methods to decrease their children's exposure to these harmful chemicals. However, a critical barrier is the absence of any program to educate nurses about chemical flame retardants. In order to overcome this barrier, we must first assess their knowledge. This article provides key highlights every pediatric nurse should know about chemical flame retardants and reports the results of a knowledge assessment study. The purpose of this study was to (1) assess pediatric nurses' knowledge of chemical flame retardants, (2) determine what topic areas of chemical flame retardants pediatric nurses lack knowledge in, and (3) determine the best method to educate nurses about chemical flame retardants. A single sample cross-sectional questionnaire design was used. A total sample of 417 advanced practice registered nurses and registered nurses completed an online survey about chemical flame retardants. Pediatric nurses' knowledge of chemical flame retardants was low (M=13.4 out of 51). Articles, webinars, and e-mails were the primary preferred methods for education on the subject identified as a result of the survey. Pediatric nurses have a large knowledge deficit related to chemical flame retardants. The data collected from this study will help structure future educational formats for pediatric nurses on chemical flame retardants to increase their knowledge. Copyright © 2016 Elsevier Inc. All rights reserved.

  16. Analysis of flame surface density measurements in turbulent premixed combustion

    Energy Technology Data Exchange (ETDEWEB)

    Halter, Fabien [Institut PRISME, Universite d' Orleans, 45072 Orleans (France); Chauveau, Christian; Goekalp, Iskender [Institut de Combustion, Aerothermique, Reactivite et Environnement, Centre National de la Recherche Scientifique, 45071 Orleans (France); Veynante, Denis [Laboratoire E.M2.C, Centre National de la Recherche Scientifique, Ecole Centrale Paris, 92295 Chatenay-Malabry (France)

    2009-03-15

    In premixed turbulent combustion, reaction rates can be estimated from the flame surface density. This parameter, which measures the mean flame surface area available per unit volume, may be obtained from algebraic expressions or by solving a transport equation. In this study, detailed measurements were performed on a Bunsen-type burner fed with methane/air mixtures in order to determine the local flame surface density experimentally. This burner, located in a high-pressure combustion chamber, allows investigation of turbulent premixed flames under various flow, mixture, and pressure conditions. In the present work, equivalence ratio was varied from 0.6 to 0.8 and pressure from 0.1 to 0.9 MPa. Flame front visualizations by Mie scattering laser tomography are used to obtain experimental data on the instantaneous flame front dynamics. The exact equation given by Pope is used to obtain flame surface density maps for different flame conditions. Some assumptions are made in order to access three-dimensional information from our two-dimensional experiments. Two different methodologies are proposed and tested in term of global mass balance (what enters compared to what is burned). The detailed experimental flame surface data provided for the first time in this work should progressively allow improvement of turbulent premixed flame modeling approaches. (author)

  17. Turbulent premixed flames on fractal-grid-generated turbulence

    Science.gov (United States)

    Soulopoulos, N.; Kerl, J.; Sponfeldner, T.; Beyrau, F.; Hardalupas, Y.; Taylor, A. M. K. P.; Vassilicos, J. C.

    2013-12-01

    A space-filling, low blockage fractal grid is used as a novel turbulence generator in a premixed turbulent flame stabilized by a rod. The study compares the flame behaviour with a fractal grid to the behaviour when a standard square mesh grid with the same effective mesh size and solidity as the fractal grid is used. The isothermal gas flow turbulence characteristics, including mean flow velocity and rms of velocity fluctuations and Taylor length, were evaluated from hot-wire measurements. The behaviour of the flames was assessed with direct chemiluminescence emission from the flame and high-speed OH-laser-induced fluorescence. The characteristics of the two flames are considered in terms of turbulent flame thickness, local flame curvature and turbulent flame speed. It is found that, for the same flow rate and stoichiometry and at the same distance downstream of the location of the grid, fractal-grid-generated turbulence leads to a more turbulent flame with enhanced burning rate and increased flame surface area.

  18. Early structure of LPG partially premixed conically stabilized flames

    KAUST Repository

    Elbaz, Ayman M.

    2013-01-01

    This paper presents experimental investigation of LPG partially premixed turbulent flames stabilized within a conical nozzle burner under constant degree of partial premixing. The stability limits and mean flame structure are presented based on the mean gas temperature and the concentration of CO, O 2, NO, and HC at the flame early region of reaction. The investigation covered the influence of the nozzle cone angle, the jet exit velocity and the jet equivalence ratio. The stability results show that the flames with cone are more stable than those without cone. For conical stabilized flames, the stability results exhibit three different sensitivity regions between the jet velocity and equivalence ratio. The inflame measurements prove that the flame stability could be attributed to the triple flame structure at the flame leading edge. The data show that the triple flame structure is influenced by cone angle, the jet velocity and the equivalence ratio. The flame is believed to be controlled by the recirculation flow inside the cone. Increasing the cone angle induced higher air entrainment to the reaction zone as depicted by a higher O 2 concentration within the flame leading edge. Increasing the jet velocity to a certain limit enhances the intensity of combustion at the flame leading edge, while excessive increase in jet velocity reduces this intensity. At a fixed jet velocity the higher the equivalence ratio, the higher the amount of fuel diffused and engulfed to the reaction zone, the more delay of the combustion completion and the higher the emission concentrations of the flame. © 2012 Elsevier Inc.

  19. Flame spread over inclined electrical wires with AC electric fields

    KAUST Repository

    Lim, Seung J.

    2017-07-21

    Flame spread over polyethylene-insulated electrical wires was studied experimentally with applied alternating current (AC) by varying the inclination angle (θ), applied voltage (VAC), and frequency (fAC). For the baseline case with no electric field applied, the flame spread rate and the flame width of downwardly spreading flames (DSFs) decreased from the horizontal case for −20° ≤ θ < 0° and maintained near constant values for −90° ≤ θ < −20°, while the flame spread rate increased appreciably as the inclination angle of upwardly spreading flames (USFs) increased. When an AC electric field was applied, the behavior of flame spread rate in DSFs (USFs) could be classified into two (three) sub-regimes characterized by various functional dependences on VAC, fAC, and θ. In nearly all cases of DSFs, a globular molten polyethylene formed ahead of the spreading flame edge, occasionally dripping onto the ground. In these cases, an effective flame spread rate was defined to represent the burning rate by measuring the mass loss due to dripping. This effective spread rate was independent of AC frequency, while it decreased linearly with voltage and was independent of the inclination angle. In DSFs, when excessively high voltage and frequency were applied, the dripping led to flame extinction during propagation and the extinction frequency correlated well with applied voltage. In USFs, when high voltage and frequency were applied, multiple globular molten PEs formed at several locations, leading to ejections of multiple small flame segments from the main flame, thereby reducing the flame spread rate, which could be attributed to the electrospray phenomenon.

  20. Effect of Wind Velocity on Flame Spread in Microgravity

    Science.gov (United States)

    Prasad, Kuldeep; Olson, Sandra L.; Nakamura, Yuji; Fujita, Osamu; Nishizawa, Katsuhiro; Ito, Kenichi; Kashiwagi, Takashi; Simons, Stephen N. (Technical Monitor)

    2002-01-01

    A three-dimensional, time-dependent model is developed describing ignition and subsequent transition to flame spread over a thermally thin cellulosic sheet heated by external radiation in a microgravity environment. A low Mach number approximation to the Navier Stokes equations with global reaction rate equations describing combustion in the gas phase and the condensed phase is numerically solved. The effects of a slow external wind (1-20 cm/s) on flame transition are studied in an atmosphere of 35% oxygen concentration. The ignition is initiated at the center part of the sample by generating a line-shape flame along the width of the sample. The calculated results are compared with data obtained in the 10s drop tower. Numerical results exhibit flame quenching at a wind speed of 1.0 cm/s, two localized flames propagating upstream along the sample edges at 1.5 cm/s, a single line-shape flame front at 5.0 cm/s, three flames structure observed at 10.0 cm/s (consisting of a single line-shape flame propagating upstream and two localized flames propagating downstream along sample edges) and followed by two line-shape flames (one propagating upstream and another propagating downstream) at 20.0 cm/s. These observations qualitatively compare with experimental data. Three-dimensional visualization of the observed flame complex, fuel concentration contours, oxygen and reaction rate isosurfaces, convective and diffusive mass flux are used to obtain a detailed understanding of the controlling mechanism, Physical arguments based on lateral diffusive flux of oxygen, fuel depletion, oxygen shadow of the flame and heat release rate are constructed to explain the various observed flame shapes.

  1. The effect of unburned gas axial velocity on the characteristics of rotational flame during flashback

    Science.gov (United States)

    Bufares, Ahmed M.; Wahid, M. A.

    2012-06-01

    The qualitative study has been carried out to investigate the effect of axial velocity of unburned gases on the flame characteristics during flame flashback in rotating burner. Our focus of study mainly on the flame shape and its behavior during flashback. It is found that the flame shape has been affected by the unburned gases axial velocity. Two flame shapes have been noticed the plate shape with cusp flame "fish flame" and upset dome flame. The cases that have been studied are flames at rotating speed 1200 rpm and 1620 rpm and several unburned gases axial velocity. Double concentric Bunsen rotating burner has been used in the study.

  2. CoFlame: A refined and validated numerical algorithm for modeling sooting laminar coflow diffusion flames

    Science.gov (United States)

    Eaves, Nick A.; Zhang, Qingan; Liu, Fengshan; Guo, Hongsheng; Dworkin, Seth B.; Thomson, Murray J.

    2016-10-01

    Mitigation of soot emissions from combustion devices is a global concern. For example, recent EURO 6 regulations for vehicles have placed stringent limits on soot emissions. In order to allow design engineers to achieve the goal of reduced soot emissions, they must have the tools to so. Due to the complex nature of soot formation, which includes growth and oxidation, detailed numerical models are required to gain fundamental insights into the mechanisms of soot formation. A detailed description of the CoFlame FORTRAN code which models sooting laminar coflow diffusion flames is given. The code solves axial and radial velocity, temperature, species conservation, and soot aggregate and primary particle number density equations. The sectional particle dynamics model includes nucleation, PAH condensation and HACA surface growth, surface oxidation, coagulation, fragmentation, particle diffusion, and thermophoresis. The code utilizes a distributed memory parallelization scheme with strip-domain decomposition. The public release of the CoFlame code, which has been refined in terms of coding structure, to the research community accompanies this paper. CoFlame is validated against experimental data for reattachment length in an axi-symmetric pipe with a sudden expansion, and ethylene-air and methane-air diffusion flames for multiple soot morphological parameters and gas-phase species. Finally, the parallel performance and computational costs of the code is investigated.

  3. Computational and experimental study of laminar flames

    Energy Technology Data Exchange (ETDEWEB)

    Smooke, Mitchell [Yale Univ., New Haven, CT (United States)

    2015-05-29

    During the past three years, our research has centered on an investigation of the effects of complex chemistry and detailed transport on the structure and extinction of hydrocarbon flames in coflowing axisymmetric configurations. We have pursued both computational and experimental aspects of the research in parallel on both steady-state and time-dependent systems. The computational work has focused on the application of accurate and efficient numerical methods for the solution of the steady-state and time-dependent boundary value problems describing the various reacting systems. Detailed experimental measurements were performed on axisymmetric coflow flames using two-dimensional imaging techniques. Previously, spontaneous Raman scattering, chemiluminescence, and laser-induced fluorescence were used to measure the temperature, major and minor species profiles. Particle image velocimetry (PIV) has been used to investigate velocity distributions and for calibration of time-varying flames. Laser-induced incandescence (LII) with an extinction calibration was used to determine soot volume fractions, while soot surface temperatures were measured with three-color optical pyrometry using a color digital camera. A blackbody calibration of the camera allows for determination of soot volume fraction as well, which can be compared with the LII measurements. More recently, we have concentrated on a detailed characterization of soot using a variety of techniques including time-resolved LII (TiRe-LII) for soot primary particles sizes, multi-angle light scattering (MALS) for soot radius of gyration, and spectrally-resolved line of sight attenuation (spec-LOSA). Combining the information from all of these soot measurements can be used to determine the soot optical properties, which are observed to vary significantly depending on spatial location and fuel dilution. Our goal has been to obtain a more fundamental understanding of the important fluid dynamic and chemical interactions in

  4. Flame-sintered ceramic exoelectron dosimeter samples

    International Nuclear Information System (INIS)

    Petel, M.; Holzapfel, G.

    1979-01-01

    New techniques for the preparation of integrating solid state dosimeters, particularly exoelectron dosimeters, have been initiated. The procedure consists in melting the powdered dosimeter materials in a hot, fast gas stream and depositing the ceramic layer. The gas stream is generated either through a chemical flame or by an electrical arc plasma. Results will be reported on the system Al 2 O 3 /stainless steel as a first step to a usable exoelectron dosimeter

  5. Chemical Kinetic and Aerodynamic Structures of Flames

    Science.gov (United States)

    1992-06-11

    and Aerodynamic PE - 61102F Structures of Flames PR - 2308 SA - BSG - 89-0293 C.K. Law 7. PWORPOG ORGANIZATION NAME(S) AND ADODRSS(ES) L PERFORMING...activation energy (E) for the equivalent one-step overall reaction. The results show that these values are far from being constants. Instead they vary...significantly not only with the equivalence ratio, but also with the system pressure. For example, the activation energy is 4 found to continuously increase

  6. Simple Flame Test Techniques Using Cotton Swabs

    Science.gov (United States)

    Sanger, Michael J.; Phelps, Amy J.

    2004-07-01

    This article describes three new methods for performing simple flame tests using cotton swabs. The first method uses a Bunsen burner and solid metal salts; the second method uses a Bunsen burner and 1 M aqueous solutions of metal salts; and the third method uses candles, rubbing alcohol, and solid metal salts. These methods have the advantage of being easy to perform, require inexpensive and easily-obtained materials, and have easy cleanup and disposal methods. See the Discussion on this Tested Demonstation .

  7. Similarity and Scaling of Turbulent Flame Speeds for Expanding Premixed Flames of C4-C8 n -alkanes

    Science.gov (United States)

    Wu, Fujia; Saha, Abhishek; Chaudhuri, Swetaprovo; Yang, Sheng; Law, Chung K.

    2013-11-01

    We experimentally investigated the propagation speed of constant-pressure expanding flames in near isotropic turbulence using a dual-chamber, fan-stirred vessel. The motivation is to test whether the fuel similarity concept among C4-C8 n-alkanes on laminar flames also holds for turbulent flames. Previously it was found that the laminar flame speed and Markstein length are almost identical for C4-C8 n-alkanes. If this fuel similarity concept can also be shown for turbulent flames, it will suggest a canonical flame structure for large hydrocarbon fuels, i . e . , large fuels always decompose to small C0-C4 fuel fragments before being oxidized, and would significantly simplify the description of the flames. Preliminary results show that in the flamelet and thin-reaction zone, turbulent flame speeds of C4-C8 n-alkanes are indeed largely similar at various conditions, thereby suggesting the fuel similarity for turbulent flames. In addition, it is found that the normalized turbulent flame speed also approximately scales with the square root of an appropriately-defined Reynolds number recently found for C0-C4 fuels. This work was supported by the AFOSR under the technical monitoring of Dr. Chiping Li.

  8. Stability of a laminar flame front propagating within a tube

    Energy Technology Data Exchange (ETDEWEB)

    Salamandra, G.D.; Maiorov, N.I.

    1983-01-01

    The present study examines the deformation of a flame propagating in a semi-closed horizontal tube under the action of perturbations artificially created on the flame surface by brief action of a transverse electrical field on the combustion zone. The fuel mixture used was a dry methane-air mixture containing 10% CH4, which produced a flame front with relatively low convexity. Flame front propagation was recorded by high-speed photographic methods. Interpretation of the photographs reveals that the magnitude of the perturbations increases by an exponential law; fine scale perturbations on the flame surface are suppressed by coarse scale perturbations, while the stable curved form of the flame front in the tube is ensured by the stabilizing action of the tube walls.

  9. Methane Formation by Flame-Generated Hydrogen Atoms in the Flame Ionization Detector

    DEFF Research Database (Denmark)

    Holm, Torkil; Madsen, Jørgen Øgaard

    1996-01-01

    , and conceivably all hydrocarbons are quantitatively converted into methane at temperatures below 600 C, that is, before the proper combustion has started. The splitting of the C-C bonds is preceded by hydrogenation of double and triple bonds and aromatic rings. The reactions, no doubt, are caused by hydrogen......The precombustion degradation of organic compounds in the flame ionization detector has been studied (1) by heating the additives in hydrogen in a quartz capillary and analyzing the reaction products by GC and (2) by following the degradation of the additives in a hydrogen flame, by means of a thin...... atoms, which are formed in the burning hydrogen and which diffuse into the inner core of the flame. The quantitative formation of methane appears to explain the "equal per carbon" rule for the detector response of hydrocarbons, since all carbons are "exchanged" for methane molecules....

  10. Polysiloxane-Based Organoclay Nanocomposites as Flame Retardants

    Science.gov (United States)

    2013-01-01

    Polysiloxanes INTRODUCTION Halogen -based flame - retardant (FR) polymers and additives have been a cost-effective solution for FR appli- cations. However, there...D ec em be r 20 13 non- halogenated flame retardant polymers. Green Chem. 2011, 13 (3), 659–665. 7. Lewicki, J.P.; Liggat, J.J.; Patel, M. The...blended through several techniques with organoclays Cloisite 30B, 10A and Naþ ranging from 1 to 5 wt.%. Thermal and flame - retardant analysis

  11. Effect of Intense Sound Waves on a Stationary Gas Flame

    Science.gov (United States)

    Hahnemann, H; Ehret, L

    1950-01-01

    Intense sound waves with a resonant frequency of 5000 cycles per second were imposed on a stationary propane-air flame issuing from a nozzle. In addition to a slight increase of the flame velocity, a fundamental change both in the shape of the burning zone and in the flow pattern could be observed. An attempt is made to explain the origin of the variations in the flame configuration on the basis of transition at the nozzle from jet flow to potential flow.

  12. Curvature and velocity of methane-air Bunsen flame tips.

    OpenAIRE

    García-Soriano, G.; García-Ybarra, P.L.; Higuera Antón, Francisco

    2012-01-01

    PIV and photographic recording are used to measure the velocity of the fresh gas and the shape of the reaction layer in a region around the tip of a methane-air Bunsen flame attached to a cylindrical burner. The results compare well with numerical simulations carried out with an infinite activation energy reaction model. The experimental and numerical results confirm that the well-known linear relation between flame velocity and flame stretch derived from asymptotic theory for weakly curved a...

  13. Investigation of flame structure in plasma-assisted turbulent premixed methane-air flame

    Science.gov (United States)

    Hualei, ZHANG; Liming, HE; Jinlu, YU; Wentao, QI; Gaocheng, CHEN

    2018-02-01

    The mechanism of plasma-assisted combustion at increasing discharge voltage is investigated in detail at two distinctive system schemes (pretreatment of reactants and direct in situ discharge). OH-planar laser-induced fluorescence (PLIF) technique is used to diagnose the turbulent structure methane-air flame, and the experimental apparatus consists of dump burner, plasma-generating system, gas supply system and OH-PLIF system. Results have shown that the effect of pretreatment of reactants on flame can be categorized into three regimes: regime I for voltage lower than 6.6 kV; regime II for voltage between 6.6 and 11.1 kV; and regime III for voltage between 11.1 and 12.5 kV. In regime I, aerodynamic effect and slower oxidation of higher hydrocarbons generated around the inner electrode tip plays a dominate role, while in regime III, the temperature rising effect will probably superimpose on the chemical effect and amplify it. For wire-cylinder dielectric barrier discharge reactor with spatially uneven electric field, the amount of radicals and hydrocarbons are decreased monotonically in radial direction which affects the flame shape. With regard to in situ plasma discharge in flames, the discharge pattern changes from streamer type to glow type. Compared with the case of reactants pretreatment, the flame propagates further in the upstream direction. In the discharge region, the OH intensity is highest for in situ plasma assisted combustion, indicating that the plasma energy is coupled into flame reaction zone.

  14. FIELD TEST OF THE FLAME QUALITY INDICATOR

    Energy Technology Data Exchange (ETDEWEB)

    Rudin, Andrew M; Butcher, Thomas; Troost, Henry

    2003-02-04

    The flame quality indicator concept was developed at BNL specifically to monitor the brightness of the flame in a small oil burner and to provide a ''call for service'' notification when the brightness has changed from its setpoint, either high or low. In prior development work BNL has explored the response of this system to operational upsets such as excess air changes, fouled atomizer nozzles, poor fuel quality, etc. Insight Technologies, Inc. and Honeywell, Inc. have licensed this technology from the U.S. Department of Energy and have been cooperating to develop product offerings which meet industry needs with an optimal combination of function and price. Honeywell has recently completed the development of the Flame Quality Monitor (FQM or Honeywell QS7100F). This is a small module which connects via a serial cable to the burners primary operating control. Primary advantages of this approach are simplicity, cost, and ease of installation. Call-for-service conditions are output in the form of front panel indicator lights and contact closure which can trigger a range of external communication options. Under this project a field test was conducted of the FQM in cooperation with service organizations in Virginia, Pennsylvania, New Jersey, New York, and Connecticut. At total of 83 field sites were included. At each site the FQM was installed in parallel with another embodiment of this concept--the Insight AFQI. The AFQI incorporates a modem and provides the ability to provide detailed information on the trends in the flame quality over the course of the two year test period. The test site population was comprised of 79.5% boilers, 13.7% warm air furnaces, and 6.8% water heaters. Nearly all were of residential size--with firing rates ranging from 0.6 gallons of oil per hour to 1.25. During the course of the test program the monitoring equipment successfully identified problems including: plugged fuel lines, fouled nozzles, collapsed combustion

  15. Flame dynamics in a micro-channeled combustor

    International Nuclear Information System (INIS)

    Hussain, Taaha; Balachandran, Ramanarayanan; Markides, Christos N.

    2015-01-01

    The increasing use of Micro-Electro-Mechanical Systems (MEMS) has generated a significant interest in combustion-based power generation technologies, as a replacement of traditional electrochemical batteries which are plagued by low energy densities, short operational lives and low power-to-size and power-to-weight ratios. Moreover, the versatility of integrated combustion-based systems provides added scope for combined heat and power generation. This paper describes a study into the dynamics of premixed flames in a micro-channeled combustor. The details of the design and the geometry of the combustor are presented in the work by Kariuki and Balachandran [1]. This work showed that there were different modes of operation (periodic, a-periodic and stable), and that in the periodic mode the flame accelerated towards the injection manifold after entering the channels. The current study investigates these flames further. We will show that the flame enters the channel and propagates towards the injection manifold as a planar flame for a short distance, after which the flame shape and propagation is found to be chaotic in the middle section of the channel. Finally, the flame quenches when it reaches the injector slots. The glow plug position in the exhaust side ignites another flame, and the process repeats. It is found that an increase in air flow rate results in a considerable increase in the length (and associated time) over which the planar flame travels once it has entered a micro-channel, and a significant decrease in the time between its conversion into a chaotic flame and its extinction. It is well known from the literature that inside small channels the flame propagation is strongly influenced by the flow conditions and thermal management. An increase of the combustor block temperature at high flow rates has little effect on the flame lengths and times, whereas at low flow rates the time over which the planar flame front can be observed decreases and the time of

  16. Electrical perturbation of cellular premixed propane/air flames

    Energy Technology Data Exchange (ETDEWEB)

    Maupin, C.L.; Harris, H.H. (Univ. of Missouri, St. Louis, MO (United States). Dept. of Chemistry)

    1994-06-01

    The phenomenon originally called polyhedral flame structure was first reported 100 years ago. Subsequent investigations showed that polyhedral structure was only one example of a more general phenomenon known now as cellular flame structure, and the range of combustion mixtures that produce them has been broadened to include lean mixtures of H[sub 2]/air, lean H[sub 2]/Br[sub 2], and rich mixtures of hydrocarbons from ethylene to octane with air. Of particular interest to the authors is the role of charged species in flames, and especially in flames that exhibit cellular structure. The electrical aspects of combustion has a long and distinguished history and this subject has been the subject of a classic monograph by Lawton and Weinberg. Electrical perturbation has been reported to affect the temperature of flames, to stabilize them at high flow rates and, in the absence of gravity, to change the speed of flame propagation, and to affect the amount of soot produced. The authors report here that premixed propane/air flames exhibiting cellular structure are quite susceptible to perturbation by electric fields. Since only charged species in the flame would be affected by the potential, and a small current would not modify transport properties of neutral species appreciably, this observation suggests that studies of this type may be useful in helping to further elucidate the role of charged species in flames.

  17. Structure of Partially Premixed Flames and Advanced Solid Propellants

    National Research Council Canada - National Science Library

    Branch, Melvyn

    1998-01-01

    The combustion of solid rocket propellants of advanced energetic materials involves a complex process of decomposition and condensed phase reactions in the solid propellant, gaseous flame reactions...

  18. Active Control for Statistically Stationary Turbulent PremixedFlame Simulations

    Energy Technology Data Exchange (ETDEWEB)

    Bell, J.B.; Day, M.S.; Grcar, J.F.; Lijewski, M.J.

    2005-08-30

    The speed of propagation of a premixed turbulent flame correlates with the intensity of the turbulence encountered by the flame. One consequence of this property is that premixed flames in both laboratory experiments and practical combustors require some type of stabilization mechanism to prevent blow-off and flashback. The stabilization devices often introduce a level of geometric complexity that is prohibitive for detailed computational studies of turbulent flame dynamics. Furthermore, the stabilization introduces additional fluid mechanical complexity into the overall combustion process that can complicate the analysis of fundamental flame properties. To circumvent these difficulties we introduce a feedback control algorithm that allows us to computationally stabilize a turbulent premixed flame in a simple geometric configuration. For the simulations, we specify turbulent inflow conditions and dynamically adjust the integrated fueling rate to control the mean location of the flame in the domain. We outline the numerical procedure, and illustrate the behavior of the control algorithm on methane flames at various equivalence ratios in two dimensions. The simulation data are used to study the local variation in the speed of propagation due to flame surface curvature.

  19. Soot precursor measurements in benzene and hexane diffusion flames

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, Y.; Furuhata, T.; Amagai, K.; Arai, M. [Department of Mechanical System Engineering, Graduate School of Engineering, Gunma University, 1-5-1 Tenjin-cho, Kiryu-shi, Gunma 376-8515 (Japan)

    2008-08-15

    To clarify the mechanism of soot formation in diffusion flames of liquid fuels, measurements of soot and its precursors were carried out. Sooting diffusion flames formed by a small pool combustion equipment system were used for this purpose. Benzene and hexane were used as typical aromatic and paraffin fuels. A laser-induced fluorescence (LIF) method was used to obtain spatial distributions of polycyclic aromatic hydrocarbons (PAHs), which are considered as soot particles. Spatial distributions of soot in test flames were measured by a laser-induced incandescence (LII) method. Soot diameter was estimated from the temporal change of LII intensity. A region of transition from PAHs to soot was defined from the results of LIF and LII. Flame temperatures, PAH species, and soot diameters in this transition region were investigated for both benzene and hexane flames. The results show that though the flame structures of benzene and hexane were different, the temperature in the PAHs-soot transition region of the benzene flame was similar to that of the hexane flame. Furthermore, the relationship between the PAH concentrations measured by gas chromatography in both flames and the PAH distributions obtained from LIF are discussed. It was found that PAHs with smaller molecular mass, such as benzene and toluene, remained in both the PAHs-soot transition and sooting regions, and it is thought that molecules heavier than pyrene are the leading candidates for soot precursor formation. (author)

  20. Separation and sampling of ice nucleation chamber generated ice particles by means of the counterflow virtual impactor technique for the characterization of ambient ice nuclei.

    Science.gov (United States)

    Schenk, Ludwig; Mertes, Stephan; Kästner, Udo; Schmidt, Susan; Schneider, Johannes; Frank, Fabian; Nillius, Björn; Worringen, Annette; Kandler, Konrad; Ebert, Martin; Stratmann, Frank

    2014-05-01

    In 2011, the German research foundation (DFG) research group called Ice Nuclei Research Unit (INUIT (FOR 1525, project STR 453/7-1) was established with the objective to achieve a better understanding concerning heterogeneous ice formation. The presented work is part of INUIT and aims for a better microphysical and chemical characterization of atmospheric aerosol particles that have the potential to act as ice nuclei (IN). For this purpose a counterflow virtual impactor (Kulkarni et al., 2011) system (IN-PCVI) was developed and characterized in order to separate and collect ice particles generated in the Fast Ice Nucleus Chamber (FINCH; Bundke et al., 2008) and to release their IN for further analysis. Here the IN-PCVI was used for the inertial separation of the IN counter produced ice particles from smaller drops and interstitial particles. This is realized by a counterflow that matches the FINCH output flow inside the IN-PCVI. The choice of these flows determines the aerodynamic cut-off diameter. The collected ice particles are transferred into the IN-PCVI sample flow where they are completely evaporated in a particle-free and dry carrier air. In this way, the aerosol particles detected as IN by the IN counter can be extracted and distributed to several particle sensors. This coupled setup FINCH, IN-PCVI and aerosol instrumentation was deployed during the INUIT-JFJ joint measurement field campaign at the research station Jungfraujoch (3580m asl). Downstream of the IN-PCVI, the Aircraft-based Laser Ablation Aerosol Mass Spectrometer (ALABAMA; Brands et al., 2011) was attached for the chemical analysis of the atmospheric IN. Also, number concentration and size distribution of IN were measured online (TROPOS) and IN impactor samples for electron microscopy (TU Darmstadt) were taken. Therefore the IN-PCVI was operated with different flow settings than known from literature (Kulkarni et al., 2011), which required a further characterisation of its cut

  1. THE INTERNAL STRUCTURE AND PROPAGATION OF MAGNETOHYDRODYNAMICAL THERMONUCLEAR FLAMES

    Energy Technology Data Exchange (ETDEWEB)

    Remming, Ian S. [Department of Astronomy and Astrophysics, The University of Chicago, Chicago, IL 60637 (United States); Khokhlov, Alexei M. [Department of Astronomy and Astrophysics, the Enrico Fermi Institute, and the Computational Institute, The University of Chicago, Chicago, IL 60637 (United States)

    2016-11-10

    We present general equations for non-ideal, reactive flow magnetohydrodynamics (RFMHD) in the form best suited for describing thermonuclear combustion in high-density degenerate matter of SNe Ia. The relative importance of various non-ideal effects is analyzed as a function of characteristic spatial and temporal scales of the problem. From the general RFMHD equations, we derive the one-dimensional ordinary differential equations describing the steady-state propagation of a planar thermonuclear flame front in a magnetic field. The physics of the flame is first studied qualitatively using a simple case of one-step Arrhenius kinetics, a perfect gas equation of state (EOS), and constant thermal conductivity coefficients. After that, the equations are solved, the internal flame front structure is calculated, and the flame velocity, S {sub l} , and flame thickness, δ {sub l} , are found for carbon–oxygen degenerate material of supernovae using a realistic EOS, transport properties, and detailed nuclear kinetics. The magnetic field changes the flame behavior significantly, both qualitatively and quantitatively, as compared to the non-magnetic case of classical combustion. (1) The magnetic field influences the evolutionarity of a flame front and makes it impossible for a flame to propagate steadily in a wide range of magnetic field strengths and orientations relative to the front. (2) When the flame moves steadily, it can propagate in several distinct modes, the most important being the slow C {sub S} and super-Alfvénic C {sub sup} modes. (3) The speed of the flame can be diminished or enhanced by up to several factors relative to the non-magnetic laminar flame speed.

  2. Mass spectrometric characterization of halogenated flame retardants.

    Science.gov (United States)

    Guo, Tan; LaBelle, Bruce; Petreas, Myrto; Park, June-Soo

    2013-07-15

    Concerns about the adverse health effects of ubiquitous flame retardants spurred our interest in the development of a sensitive and reliable analytical method for these toxic compounds in various sample matrices. This study focuses on the investigation of fragmentation pathways and the structures of target ions of thirteen new halogenated flame retardants. In this study, we use gas chromatography (GC)/high-resolution double-focusing sector mass spectrometry to characterize the fragmentation pathways of these new flame retardants. Along with the isotope patterns, accurate mass data were acquired to verify the molecular formula. The fragmentation pathways are classified based on the types of bond dissociations, e.g. σ-bond cleavage, α-bond cleavage and multiple-bond dissociations with a hydrogen shift. The α-bond dissociation occurs among 1,2-bis-(2,4,6-tribromophenoxy)ethane, allyl 2,4,6-tribromophenyl ether (ATE), 2,3-dibromopropyl 2,4,6-tribromophenyl ether (DPTE) and 2-bromoallyl 2,4,6-tribromophenyl ether (BATE). The peak clusters that dominated ATE, BATE and hexachlorocyclopentenyl-dibromocyclooctane (HCDBCO) spectra correspond to two fragments as proved by accurate mass data and isotope patterns. These two fragments are formed as the result of two competing fragmentation pathways of radical loss and hydrogen shift. Fragmentation pathways of the other compounds are complex, involving cleavage of multiple bonds and hydrogen shifts. The accurate-mass-based GC/MS method offers great selectivity and sensitivity for quantitative analysis of the persistent organic pollutants. Thus, elucidation of the structures of the fragments is of prime importance for building an accurate-mass-based isotopic method. In addition, this study is useful for GC/MS/MS method development because multiple reaction monitoring (MRM) transitions of precursor ions and product ions may be easily elucidated based on these fragmentation patterns. Copyright © 2013 John Wiley & Sons, Ltd.

  3. Nanotechnology finding its way into flame retardancy

    Energy Technology Data Exchange (ETDEWEB)

    Schartel, Bernhard, E-mail: bernhard.schartel@bam.de [BAM Federal Institute for Materials Research and Testing, Unter den Eichen 87, 12205 Berlin (Germany)

    2014-05-15

    Nanotechnology is one of the key technologies of the 21{sup st} century. The exploitation of 'new' effects that arise from materials structured on the nano-scale has also been proposed successfully for flame retardancy of polymers since the end of the 90s. Of all of the approaches these include, at this time the use of nanocomposites offers the best potential for industrial application, also some other ideas are sketched, such as using electrospun nanofibers mats or layer-by-layer deposits as protection coatings, as well as sub-micrometer multilayer coatings as effective IR-mirrors. The general phenomena, inducing a flow limit in the pyrolysing melt and changing the fire residue, are identified in nanocomposites. Key experiments are performed such as quasi online investigation of the protection layer formation to understand what is going on in detail. The flame retardancy mechanisms are discussed and their impact on fire behaviour quantified. With the latter, the presentation pushes forward the state of the art. For instance, the heat shielding is experimentally quantified for a layered silicate epoxy resin nanocomposite proving that it is the only import mechanism controlling the reduction in peak heat release rate in the investigated system for different irradiations. The flame retardancy performance is assessed comprehensively illuminating not only the strengths but also the weak points of the concepts. Guidelines for materials development are deduced and discussed. Apart from inorganic fillers (layered silicate, boehmite, etc.) not only carbon nanoobjects such as multiwall carbon nanotubes, multilayer graphene and graphene are investigated, but also nanoparticles that are more reactive and harbor the potential for more beneficial interactions with the polymer matrix.

  4. Spectroscopy of Propellant-Related Flames

    Science.gov (United States)

    1990-06-01

    data. For propellant HMX1, the absorption data of Vanderhoff [12], the CARS data of Stufflebeam [13], and the CN LIF profile [4,5] can be compared...CARS experiments at 23 atm, Stufflebeam measured the concentration of N2, CO, H2 and temperature in an HMX1 propellant flame at distances about 1 mm...Parr, Hanson-Parr PLIF CN, NH, OH, NO, 10 NO2, T Stufflebeam CARS N2, CO, H2, T 13 Vanderhoff Absorption CN, NH, OH, T 12 Edwards LIF CN, NH, OH, T 4

  5. New hybrid halogen-free flame retardants

    Science.gov (United States)

    Kijowska, Dorota; Jankowski, Piotr

    2014-05-01

    The main objective of this work were researches concerning the methods of the in-situ modification of silicate layer-tubular mineral (SL-TM) halloysite, using the salts of melamine, i.e. melamine cyanurate. The modified mineral was used as flame retardant to thermoplastic polymers. In the case of the application of halloysite modified by melamine cyanurate to polyamide 6 (PA6) the highest parameters of vertical and horizontal flammability were achieved. The mechanical properties of filled polyamide 6 have been improved.

  6. 30 CFR 75.600 - Trailing cables; flame resistance.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Trailing cables; flame resistance. 75.600 Section 75.600 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE... cables; flame resistance. [Statutory Provisions] Trailing cables used in coal mines shall meet the...

  7. Flame retardants: Dust - and not food - might be the risk

    NARCIS (Netherlands)

    de Boer, J.; Ballesteros-Gomez, A.M.; Leslie, H.A.; Brandsma, S.H.; Leonards, P.E.G.

    2016-01-01

    Flame retardants (FRs) are used to delay ignition of materials such as furniture and electric and electronic instruments. Many FRs are persistent and end up in the environment. Environmental studies on flame retardants (FRs) took off in the late 1990s. Polybrominated diphenylethers (PBDEs) appeared

  8. Environmental fate & effects of new generation flame retardants

    NARCIS (Netherlands)

    Waaijers, S.L.

    2014-01-01

    There is a pressing need for substituting several halogenated flame retardants, given the human and environmental health concerns of many of these compounds. Halogen Free Flame Retardants (HFFRs) have been suggested as alternatives and are already being marketed, although their potential impact on

  9. Histopathology of the organs of Broiler Chickens exposed to flames ...

    African Journals Online (AJOL)

    Histopathology of the organs of broiler chickens exposed to the flame and fumes of refined petroleum product kerosene at varying distances over a period of 16hrs daily for 56 days in a poultry house were evaluated. Kerosene burning was simulated in a designed burner. Kerosene flame in a designed burner was placed 4, ...

  10. Large eddy simulation of flame flashback in a turbulent channel

    Science.gov (United States)

    Hassanaly, Malik; Lietz, Christopher; Raman, Venkat; Kolla, Hemanth; Chen, Jacqueline; Gruber, Andrea; Computational Flow Physics Group Team

    2014-11-01

    In high-hydrogen content gas turbines, the propagation of a premixed flame along with boundary layers on the combustor walls is a source of failure, whereby the flame could enter the fuel-air premixing region that is not designed to hold high-temperature fluid. In order to develop models for predicting this phenomenon, a large eddy simulation (LES) based study is carried out here. The flow configuration is based on a direct numerical simulation (DNS) of a turbulent channel, where an initial planar flame is allowed to propagate upstream in a non-periodic channel. The LES approach uses a flamelet-based combustion model along with standard models for the unresolved subfilter flux terms. It is found that the LES are very accurate in predicting the structure of the turbulent flame front. However, there was a large discrepancy for the transient evolution of the flame, indicating that the flame-boundary layer interaction modulates flame propagation significantly, and the near-wall flame behavior may be non-flamelet like due to the anisotropic of the flow in this region.

  11. Toxicity of new generation flame retardants to Daphnia magna

    NARCIS (Netherlands)

    Waaijers, S.L.; Hartmann, J; Soeter, A.M.; Helmus, R.; Kools, S.A.E.; de Voogt, P.; Admiraal, W.; Parsons, J.R.; Kraak, M.H.S.

    2013-01-01

    There is a tendency to substitute frequently used, but relatively hazardous brominated flame retardants (BFRs) with halogen-free flame retardants (HFFRs). Consequently, information on the persistence, bioaccumulation and toxicity (PBT) of these HFFRs is urgently needed, but large data gaps and

  12. Diamond growth in premixed propylene-oxygen flames

    OpenAIRE

    Shin, Ho Seon; Goodwin, David G.

    1995-01-01

    Diamond film growth in low-pressure premixed propylene/oxygen flames is demonstrated. Well-faceted films are grown at a pressure of 180 Torr and a fuel/oxygen ratio of 0.47. Using propylene as the fuel may greatly improve the economics of flame synthesis of diamond, since propylene is an order of magnitude cheaper than acetylene.

  13. Flame retardant antibacterial cotton high-loft nonwoven fabrics

    Science.gov (United States)

    Flame retardant treated gray cotton fibers were blended with antibacterial treated gray cotton fibers and polyester/polyester sheath/core bicomponent fibers to form high-loft fabrics. The high flame retardancy (FR) and antibacterial property of these high lofts were evaluated by limiting oxygen inde...

  14. Camping Burner-Based Flame Emission Spectrometer for Classroom Demonstrations

    Science.gov (United States)

    Ne´el, Bastien; Crespo, Gasto´n A.; Perret, Didier; Cherubini, Thomas; Bakker, Eric

    2014-01-01

    A flame emission spectrometer was built in-house for the purpose of introducing this analytical technique to students at the high school level. The aqueous sample is sprayed through a homemade nebulizer into the air inlet of a consumer-grade propane camping burner. The resulting flame is analyzed by a commercial array spectrometer for the visible…

  15. Comparative Analysis of Flame Characteristics of Castor Oil and ...

    African Journals Online (AJOL)

    The flame characteristics of castor oil based foam and that of polyether foam impregnated with inorganic flame retardants (FR) were investigated. The polyether foams were impregnated with measured concentration of Antimony trioxide and Sodium bromide, Ammonium dihydrogen orthophosphate, Diammonium hydrogen ...

  16. Comparative Analysis of Flame Characteristics of Castor Oil and ...

    African Journals Online (AJOL)

    ABSTRACT: The flame characteristics of castor oil based foam and that of polyether foam impregnated with inorganic flame retardants (FR) were investigated. The polyether foams were impregnated with measured concentration of Antimony trioxide and Sodium bromide, Ammonium dihydrogen orthophosphate ...

  17. Life cycle assessment of flame retardants in an electronics application

    NARCIS (Netherlands)

    Jonkers, Niels; Krop, Hildo; van Ewijk, Harry; Leonards, Pim E.G.

    2016-01-01

    Purpose: Flame retardants are added to plastics and textiles to save lives. However, certain brominated flame retardants (BFRs) form an environmental hazard and should be replaced by less harmful alternatives. In the recently completed European research project ENFIRO, we examined which alternatives

  18. Reconstructing the Cryptanalytic Attack behind the Flame Malware

    NARCIS (Netherlands)

    M.J. Fillinger (Max)

    2013-01-01

    textabstractFlame was an advanced malware, used for espionage, which infected computers running a Microsoft Windows operating system. Once a computer in a local network was infected, Flame could spread to the other computers in the network via Windows Update, disguised as a security patch from

  19. A numerical study of laminar flames propagating in stratified mixtures

    Science.gov (United States)

    Zhang, Jiacheng

    Numerical simulations are carried out to study the structure and speed of laminar flames propagating in compositionally and thermally stratified fuel-air mixtures. The study is motivated by the need to understand the physics of flame propagation in stratified-charge engines and model it. The specific question of interest in this work is: how does the structure and speed of the flame in the stratified mixture differ from that of the flame in a corresponding homogeneous mixture at the same equivalence ratio, temperature, and pressure? The studies are carried out in hydrogen-air, methane-air, and n-heptane-air mixtures. A 30-species 184-step skeletal mechanism is employed for methane oxidation, a 9-species 21-step mechanism for hydrogen oxidation, and a 37-species 56-step skeletal mechanism for n-heptane oxidation. Flame speed and structure are compared with corresponding values for homogeneous mixtures. For compositionally stratified mixtures, as shown in prior experimental work, the numerical results suggest that when the flame propagates from a richer mixture to a leaner mixture, the flame speed is faster than the corresponding speed in the homogeneous mixture. This is caused by enhanced diffusion of heat and species from the richer mixture to the leaner mixture. In fact, the effects become more pronounced in leaner mixtures. Not surprisingly, the stratification gradient influences the results with shallower gradients showing less effect. The controlling role that diffusion plays is further assessed and confirmed by studying the effect of a unity Lewis number assumption in the hydrogen/air mixtures. Furthermore, the effect of stratification becomes less important when using methane or n-heptane as fuel. The laminar flame speed in a thermally stratified mixture is similar to the laminar flame speed in homogeneous mixture at corresponding unburned temperature. Theoretical analysis is performed and the ratio of extra thermal diffusion rate to flame heat release rate

  20. Stability of a laminar flame front propagating within a tube

    Energy Technology Data Exchange (ETDEWEB)

    Salamandra, G.D.; Maiorov, N.I.

    1983-01-01

    This study examines the deformation of a flame propagating in a semi-closed horizontal tube under the action of perturbations artifically created on the flame surface by brief action of a transverse electrical field on the combustion zone. The experiments were performed in a tube with square section 36 x 36 mm, with electrodes on the upper and lower walls for application of an electric field to the combustion zone. A high negative voltage was applied to the upper electrode for a regulated time interval, with the lower electrode grounded. Concludes that development of artificially created perturbations on the surface of a flame propagating in a semiclosed horizontal tube has been observed; the magnitude of the perturbations increases by an exponential law; fine scale perturbations on the flame surface are suppressed by coarse scale perturbations; and the stable curved form of the flame front in the tube is ensured by the stabilizing action of the tube walls.

  1. SiC flame sensors for gas turbine control systems

    Science.gov (United States)

    Brown, Dale M.; Downey, Evan; Kretchmer, Jim; Michon, Gerald; Emily Shu; Schneider, Don

    1998-05-01

    The research and development activities carried out to develop a SiC flame sensor for gas turbines utilized for power generation are discussed. These activities included the fabrication and characterization of SiC UV photodiodes and small SiC signal diodes as well as the designing and testing of production flame detector assemblies. The characteristics that make this solid state flame detector particularly useful for dry low NO x (DLN) premixed oil and natural gas fuels will be described. Since this device provides both analog dc and ac output signals, turbine combustor mode tracking, combustion flame dynamics and flame intensity tracking have been demonstrated. Sensors designed for production have been built, qualified and field tested. These sensors are now being installed in gas turbine power plants and are a component part of the turbine control system. This development has resulted in the first commercialized turbine control application to use SiC electronic devices.

  2. Turbulent structure and dynamics of swirled, strongly pulsed jet diffusion flames

    KAUST Repository

    Liao, Ying-Hao

    2013-11-02

    The structure and dynamics of swirled, strongly pulsed, turbulent jet diffusion flames were examined experimentally in a co-flow swirl combustor. The dynamics of the large-scale flame structures, including variations in flame dimensions, the degree of turbulent flame puff interaction, and the turbulent flame puff celerity were determined from high-speed imaging of the luminous flame. All of the tests presented here were conducted with a fixed fuel injection velocity at a Reynolds number of 5000. The flame dimensions were generally found to be more impacted by swirl for the cases of longer injection time and faster co-flow flow rate. Flames with swirl exhibited a flame length up to 34% shorter compared to nonswirled flames. Both the turbulent flame puff separation and the flame puff celerity generally decreased when swirl was imposed. The decreased flame length, flame puff separation, and flame puff celerity are consistent with a greater momentum exchange between the flame and the surrounding co-flow, resulting from an increased rate of air entrainment due to swirl. Three scaling relations were developed to account for the impact of the injection time, the volumetric fuel-to-air flow rate ratio, and the jet-on fraction on the visible flame length. © 2013 Copyright Taylor and Francis Group, LLC.

  3. Development of fiber reactive, non-halogenated flame retardant on cotton fabrics and the enhanced flame retardancy by covalent bonding

    Science.gov (United States)

    The US law requires flame resistant properties on apparel or house hold items to prevent or minimize the fire damage. The objective of this research was to develop a non-halogenated flame retardant for application onto cotton fabrics. These treated fabrics can then be used in clothes or beddings to ...

  4. Aerodynamic characteristics of swirling spray flames

    International Nuclear Information System (INIS)

    Presser, C.; Gupta, A.K.; Semerjian, H.G.

    1993-01-01

    In this paper the effect of swirl on droplet transport processes is examined in a pressure-atomized, hollow-cone kerosene spray, introduced into coflowing nonswirling and swirling air flow fields. An ensemble light scattering technique, based on measurement of the polarization ratio, provided spatially resolved measurements on the local values of droplet mean size and number density in dense regions of the nonburning spray. Laser velocimetry was employed to measure the axial, radial, and tangential velocity components of the droplets and combustion air stream. Droplet velocity distributions and time histories provided information on the transport of individual droplets under nonburning and burning conditions. high-speed cinemathography, short-exposure photography, and video movies were also employed to observe the global features of the spray flame. The results reveal that the spray flame has a complex three-dimensional structure. The introduction of swirl to the combustion air modifies the droplet/air velocity field in addition to the spatial distribution of droplet size and number density

  5. Acute and Developmental Behavioral Effects of Flame ...

    Science.gov (United States)

    As polybrominated diphenyl ethers are phased out, numerous compounds are emerging as potential replacement flame retardants for use in consumer and electronic products. Little is known, however, about the neurobehavioral toxicity of these replacements. This study evaluated the neurobehavioral effects of acute or developmental exposure to t-butylphenyl diphenyl phosphate (BPDP), 2-ethylhexyl diphenyl phosphate (EHDP), isodecyl diphenyl phosphate (IDDP), isopropylated phenyl phosphate (IPP), tricresyl phosphate (TMPP; also abbreviated TCP), triphenyl phosphate (TPHP; also abbreviated TPP), tetrabromobisphenol A (TBBPA), tris (2-chloroethyl) phosphate (TCEP), tris (1,3-dichloroisopropyl) phosphate (TDCIPP; also abbreviated TDCPP), tri-o-cresyl phosphate (TOCP), and 2,2-,4,4’-tetrabromodiphenyl ether (BDE-47) in zebrafish (Danio rerio) larvae. Larvae (n≈24 per dose per compound) were exposed to test compounds (0.4 - 120 µM) at sub-teratogenic concentrations either developmentally or acutely, and locomotor activity was assessed at 6 days post fertilization. When given developmentally, all chemicals except BPDP, IDDP and TBBPA produced behavioral effects. When given acutely, all chemicals produced behavioral effects, with TPHP, TBBPA, EHDP, IPP, and BPDP eliciting the most effects at the most concentrations. The results indicate that these replacement flame retardants may have developmental or pharmacological effects on the vertebrate nervous system. This study

  6. Periodic motion of a bunsen flame tip with burner rotation

    Energy Technology Data Exchange (ETDEWEB)

    Gotoda, Hiroshi; Maeda, Kazuyuki; Ueda, Toshihisa; Cheng, Robert K.

    2003-09-01

    Effects of burner rotation on the shapes and dynamics of premixed Bunsen flames have been investigated experimentally in normal gravity and in microgravity. Mixtures of CH{sub 4}-air and C{sub 3}H{sub 8}-air are issued from the burner tube with mean flow velocity U = 0.6 m/s. The burner tube is rotated up to 1400 rpm (swirl number S = 1.58). An oscillating flame with large amplitude is formed between a conical-shape flame and a plateau flame under the condition of Lewis number Le > 1 mixtures (rich CH{sub 4}-air and lean C{sub 3}H{sub 8}-air mixtures). In contrast, for Le = 1 mixtures (lean CH{sub 4}-air and rich C{sub 3}H{sub 8}-air), asymmetric, eccentric flame or tilted flame is formed under the same swirl number range. Under microgravity condition, the oscillating flames are not formed, indicating that the oscillation is driven by buoyancy-induced instability associated with the unstable interface between the hot products and the ambient air. The flame tip flickering frequency {nu} is insensitive to burner rotation for S < 0.11. For S > 0.11, {nu} decreases linearly with increasing S. As S exceeds 0.11, a minimum value of axial mean velocity along the center line uj,m due to flow divergence is found and it has a linear relationship with {nu}. This result shows that uj,m has direct control of the oscillation frequency. When S approaches unity, the flame oscillation amplitude increases by a factor of 5, compared to the flickering amplitude of a conical-shape flame. This is accompanied by a hysteresis variation in the flame curvature from positive to negative and the thermo-diffusive zone thickness varying from small to large. With S > 1.3, the plateau flame has the same small flickering amplitudes as with S = 0. These results show that the competing centrifugal and buoyancy forces, and the non-unity Lewis number effect, play important roles in amplifying the flame-tip oscillation.

  7. Experimental studies of flame stability limits of CNG-air premixed flame

    Energy Technology Data Exchange (ETDEWEB)

    Mishra, D.P. [Combustion Laboratory, Department of Aerospace Engineering, Indian Institute of Technology, Kanpur, Uttar Pradesh 208 016 (India)

    2007-04-15

    The stability aspects of laminar premixed CNG-air flames are investigated experimentally. Bunsen burners with two different port diameters, such as 12 and 15 mm, are employed to characterize the blowoff and flashback limits of the CNG-air premixed flames. For the two burners, the peak flashback limits occurs at a fuel-air ratio slightly richer than stoichiometric. However, the flashback limits are enhanced with increase in diameter of the burner, but the blowoff limit increases with increase in fuel concentration. Similar trends in increasing blowoff limits are obtained with further increase in burner diameter. The stability plots for burners with two different port diameters have been established, which can be used for designing and developing CNG/air combustion systems. (author)

  8. GRAVITATIONALLY UNSTABLE FLAMES: RAYLEIGH-TAYLOR STRETCHING VERSUS TURBULENT WRINKLING

    International Nuclear Information System (INIS)

    Hicks, E. P.; Rosner, R.

    2013-01-01

    In this paper, we provide support for the Rayleigh-Taylor-(RT)-based subgrid model used in full-star simulations of deflagrations in Type Ia supernovae explosions. We use the results of a parameter study of two-dimensional direct numerical simulations of an RT unstable model flame to distinguish between the two main types of subgrid models (RT or turbulence dominated) in the flamelet regime. First, we give scalings for the turbulent flame speed, the Reynolds number, the viscous scale, and the size of the burning region as the non-dimensional gravity (G) is varied. The flame speed is well predicted by an RT-based flame speed model. Next, the above scalings are used to calculate the Karlovitz number (Ka) and to discuss appropriate combustion regimes. No transition to thin reaction zones is seen at Ka = 1, although such a transition is expected by turbulence-dominated subgrid models. Finally, we confirm a basic physical premise of the RT subgrid model, namely, that the flame is fractal, and thus self-similar. By modeling the turbulent flame speed, we demonstrate that it is affected more by large-scale RT stretching than by small-scale turbulent wrinkling. In this way, the RT instability controls the flame directly from the large scales. Overall, these results support the RT subgrid model.

  9. Flame Retardant Applications in Camping Tents and Potential Exposure.

    Science.gov (United States)

    Keller, Alexander S; Raju, Nikhilesh P; Webster, Thomas F; Stapleton, Heather M

    2014-02-11

    Concern has mounted over health effects caused by exposure to flame retardant additives used in consumer products. Significant research efforts have focused particularly on exposure to polybrominated diphenyl ethers (PBDEs) used in furniture and electronic applications. However, little attention has focused on applications in textiles, particularly textiles meeting a flammability standard known as CPAI-84. In this study, we investigated flame retardant applications in camping tents that met CPAI-84 standards by analyzing 11 samples of tent fabrics for chemical flame retardant additives. Furthermore, we investigated potential exposure by collecting paired samples of tent wipes and hand wipes from 27 individuals after tent setup. Of the 11 fabric samples analyzed, 10 contained flame retardant additives, which included tris(1,3-dichloroisopropyl) phosphate (TDCPP), decabromodiphenyl ether (BDE-209), triphenyl phosphate, and tetrabromobisphenol-A. Flame retardant concentrations were discovered to be as high as 37.5 mg/g (3.8% by weight) in the tent fabric samples, and TDCPP and BDE-209 were the most frequently detected in these samples. We also observed a significant association between TDCPP levels in tent wipes and those in paired hand wipes, suggesting that human contact with the tent fabric material leads to the transfer of the flame retardant to the skin surface and human exposure. These results suggest that direct contact with flame retardant-treated textiles may be a source of exposure. Future studies will be needed to better characterize exposure, including via inhalation and dermal sorption from air.

  10. Effect of Swirl on Flickering Motion of Diffusion Flame

    Science.gov (United States)

    Gotoda, Hiroshi; Hoo Chuah, Keng; Kushida, Genichiro

    2006-11-01

    The buoyancy-induced oscillation is referred to as the so-called flame flickering and its dynamics are important when revealing mechanism of flame oscillations encountered in some combustion systems. Many aspects of flame oscillation / buoyancy coupling have been extensively explored, but the effect of swirling flow on buoyancy-induced flame flickering has yet to be elucidated. The purpose of the present study is to investigate how the buoyancy-induced flame flickering motion is altered by swirl, using a rotating Bunsen burner. The rotating burner tube (Diameter of the burner tube D0 is 10 mm) is vertically supported by bearings, and rotated by a DC motor through a pulley and belt unit. The fuel injection velocity U (= volume flow rate / cross-sectional area of the burner tube) is varied from 0.1 to 0.3 m/s. The rotational speed of the burner tube N is varied up to 2000 rpm. Variations in the flame motion, oscillation frequency, and flame height as a function of burner rotation rate are presented in detail.

  11. PIV Measurements in Weakly Buoyant Gas Jet Flames

    Science.gov (United States)

    Sunderland, Peter B.; Greenbberg, Paul S.; Urban, David L.; Wernet, Mark P.; Yanis, William

    2001-01-01

    Despite numerous experimental investigations, the characterization of microgravity laminar jet diffusion flames remains incomplete. Measurements to date have included shapes, temperatures, soot properties, radiative emissions and compositions, but full-field quantitative measurements of velocity are lacking. Since the differences between normal-gravity and microgravity diffusion flames are fundamentally influenced by changes in velocities, it is imperative that the associated velocity fields be measured in microgravity flames. Velocity measurements in nonbuoyant flames will be helpful both in validating numerical models and in interpreting past microgravity combustion experiments. Pointwise velocity techniques are inadequate for full-field velocity measurements in microgravity facilities. In contrast, Particle Image Velocimetry (PIV) can capture the entire flow field in less than 1% of the time required with Laser Doppler Velocimetry (LDV). Although PIV is a mature diagnostic for normal-gravity flames , restrictions on size, power and data storage complicate these measurements in microgravity. Results from the application of PIV to gas jet flames in normal gravity are presented here. Ethane flames burning at 13, 25 and 50 kPa are considered. These results are presented in more detail in Wernet et al. (2000). The PIV system developed for these measurements recently has been adapted for on-rig use in the NASA Glenn 2.2-second drop tower.

  12. Streamline segment statistics of premixed flames with nonunity Lewis numbers

    Science.gov (United States)

    Chakraborty, Nilanjan; Wang, Lipo; Klein, Markus

    2014-03-01

    The interaction of flame and surrounding fluid motion is of central importance in the fundamental understanding of turbulent combustion. It is demonstrated here that this interaction can be represented using streamline segment analysis, which was previously applied in nonreactive turbulence. The present work focuses on the effects of the global Lewis number (Le) on streamline segment statistics in premixed flames in the thin-reaction-zones regime. A direct numerical simulation database of freely propagating thin-reaction-zones regime flames with Le ranging from 0.34 to 1.2 is used to demonstrate that Le has significant influences on the characteristic features of the streamline segment, such as the curve length, the difference in the velocity magnitude at two extremal points, and their correlations with the local flame curvature. The strengthenings of the dilatation rate, flame normal acceleration, and flame-generated turbulence with decreasing Le are principally responsible for these observed effects. An expression for the probability density function (pdf) of the streamline segment length, originally developed for nonreacting turbulent flows, captures the qualitative behavior for turbulent premixed flames in the thin-reaction-zones regime for a wide range of Le values. The joint pdfs between the streamline length and the difference in the velocity magnitude at two extremal points for both unweighted and density-weighted velocity vectors are analyzed and compared. Detailed explanations are provided for the observed differences in the topological behaviors of the streamline segment in response to the global Le.

  13. Comparative study of the performance of the M-cycle counter-flow and cross-flow heat exchangers for indirect evaporative cooling – Paving the path toward sustainable cooling of buildings

    International Nuclear Information System (INIS)

    Zhan, Changhong; Duan, Zhiyin; Zhao, Xudong; Smith, Stefan; Jin, Hong; Riffat, Saffa

    2011-01-01

    This paper provides a comparative study of the performance of cross-flow and counter-flow M-cycle heat exchangers for dew point cooling. It is recognised that evaporative cooling systems offer a low energy alternative to conventional air conditioning units. Recently emerged dew point cooling, as the renovated evaporative cooling configuration, is claimed to have much higher cooling output over the conventional evaporative modes owing to use of the M-cycle heat exchangers. Cross-flow and counter-flow heat exchangers, as the available structures for M-cycle dew point cooling processing, were theoretically and experimentally investigated to identify the difference in cooling effectiveness of both under the parallel structural/operational conditions, optimise the geometrical sizes of the exchangers and suggest their favourite operational conditions. Through development of a dedicated computer model and case-by-case experimental testing and validation, a parametric study of the cooling performance of the counter-flow and cross-flow heat exchangers was carried out. The results showed the counter-flow exchanger offered greater (around 20% higher) cooling capacity, as well as greater (15%–23% higher) dew-point and wet-bulb effectiveness when equal in physical size and under the same operating conditions. The cross-flow system, however, had a greater (10% higher) Energy Efficiency (COP). As the increased cooling effectiveness will lead to reduced air volume flow rate, smaller system size and lower cost, whilst the size and cost are the inherent barriers for use of dew point cooling as the alternation of the conventional cooling systems, the counter-flow system is considered to offer practical advantages over the cross-flow system that would aid the uptake of this low energy cooling alternative. In line with increased global demand for energy in cooling of building, largely by economic booming of emerging developing nations and recognised global warming, the research

  14. A 0-D flame wrinkling equation to describe the turbulent flame surface evolution in SI engines

    Science.gov (United States)

    Richard, Stéphane; Veynante, Denis

    2015-03-01

    The current development of reciprocating engines relies increasingly on system simulation for both design activities and conception of algorithms for engine control. These numerical simulation tools require high computational efficiencies, as calculations have to be performed in times close to real-time. Then, they are today mainly based on simple empirical laws to describe the combustion processes in the cylinders. However, with the rapid evolution of emission regulations and fuel formulation, more and more physics is expected in combustion models. A solution consists in reducing 3-D combustion models to build 0-dimensional models that are both CPU-efficient and based on physical quantities. This approach has been used in a previous work to reduce the 3-D ECFM (Extended Coherent Flame Model), leading to the so-called CFM1D. A key feature of the latter is to be based on a 0-D equation for the flame wrinkling derived from the 3-D equation for the flame surface density. The objective of this paper is to present in details the theoretical derivation of the wrinkling equation and the underlying modeling assumptions as well. Academic validations are performed against experimental data for several turbulence intensities and fuels. Finally, the proposed model is applied to engine simulations for a wide range of operating conditions. Comparisons are successfully conducted between in-cylinder measurements and the model predictions, highlighting the interest of reducing 3-D CFD models for calculations performed in the context of system simulation.

  15. Halogenated flame retardants in the Great Lakes environment.

    Science.gov (United States)

    Venier, Marta; Salamova, Amina; Hites, Ronald A

    2015-07-21

    Flame retardants are widely used industrial chemicals that are added to polymers, such as polyurethane foam, to prevent them from rapidly burning if exposed to a small flame or a smoldering cigarette. Flame retardants, especially brominated flame retardants, are added to many polymeric products at percent levels and are present in most upholstered furniture and mattresses. Most of these chemicals are so-called "additive" flame retardants and are not chemically bound to the polymer; thus, they migrate from the polymeric materials into the environment and into people. As a result, some of these chemicals have become widespread pollutants, which is a concern given their possible adverse health effects. Perhaps because of their environmental ubiquity, the most heavily used group of brominated flame retardants, the polybrominated diphenyl ethers (PBDEs), was withdrawn from production and use during the 2004-2013 period. This led to an increasing demand for other flame retardants, including other brominated aromatics and organophosphate esters. Although little is known about the use or production volumes of these newer flame retardants, it is evident that some of these chemicals are also becoming pervasive in the environment and in humans. In this Account, we describe our research on the occurrence of halogenated and organophosphate flame retardants in the environment, with a specific focus on the Great Lakes region. This Account starts with a short introduction to the first generation of brominated flame retardants, the polybrominated biphenyls, and then presents our measurements of their replacement, the PBDEs. We summarize our data on PBDE levels in babies, bald eagles, and in air. Once these compounds came off the market, we began to measure several of the newer flame retardants in air collected on the shores of the Great Lakes once every 12 days. These new measurements focus on a tetrabrominated benzoate, a tetrabrominated phthalate, a hexabrominated diphenoxyethane

  16. Thermography of flame during diesel fuel combustion with steam gasification

    Science.gov (United States)

    Anufriev, I. S.; Arsentyev, S. S.; Agafontsev, M. V.; Kopyev, E. P.; Loboda, E. L.; Shadrin, E. Yu; Sharypov, O. V.

    2017-11-01

    The paper represents a study concerning the combustion of liquid hydrocarbon fuel in a perspective burner device with the controlled forced supply of overheated steam into the combustion zone, using diesel fuel. The thermal imaging measurements are conducted for the outer flame of the burner device in the wide range of regime parameters (flow rate and temperature of steam). A thermal imaging camera (FLIR, JADE J530SB) is used in the experiments. The effective emissivity coefficient of flame is obtained versus the flow rate of steam supplied. The steam parameters are found to influence on the temperature in the outer flame of the burner device.

  17. Simulation of flame-vortex interaction using detailed and reduced

    Energy Technology Data Exchange (ETDEWEB)

    Hilka, M. [Gaz de France (GDF), 75 - Paris (France); Veynante, D. [Ecole Centrale de Paris, Laboratoire EM2C. CNRS, 92 - Chatenay-Malabry (France); Baum, M. [CERFACS (France); Poinsot, T.J. [Centre National de la Recherche Scientifique (CNRS), 45 - Orleans-la-Source (France). Institut de Mecanique des Fluides de Toulouse

    1996-12-31

    The interaction between a pair of counter-rotating vortices and a lean premixed CH{sub 4}/O{sub 2}/N{sub 2} flame ({Phi} = + 0.55) has been studied by direct numerical simulations using detailed and reduced chemical reaction schemes. Results from the complex chemistry simulation are discussed with respect to earlier experiments and differences in the simulations using detailed and reduces chemistry are investigated. Transient evolutions of the flame surface and the total heat release rate are compared and modifications in the evolution of the local flame structure are displayed. (authors) 22 refs.

  18. Turbulent Flame Propagation Characteristics of High Hydrogen Content Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Seitzman, Jerry [Georgia Inst. of Technology, Atlanta, GA (United States); Lieuwen, Timothy [Georgia Inst. of Technology, Atlanta, GA (United States)

    2014-09-30

    This final report describes the results of an effort to better understand turbulent flame propagation, especially at conditions relevant to gas turbines employing fuels with syngas or hydrogen mixtures. Turbulent flame speeds were measured for a variety of hydrogen/carbon monoxide (H2/CO) and hydrogen/methane (H2/CH4) fuel mixtures with air as the oxidizer. The measurements include global consumption speeds (ST,GC) acquired in a turbulent jet flame at pressures of 1-10 atm and local displacement speeds (ST,LD) acquired in a low-swirl burner at atmospheric pressure. The results verify the importance of fuel composition in determining turbulent flame speeds. For example, different fuel-air mixtures having the same unstretched laminar flame speed (SL,0) but different fuel compositions resulted in significantly different ST,GC for the same turbulence levels (u'). This demonstrates the weakness of turbulent flame speed correlations based simply on u'/SL,0. The results were analyzed using a steady-steady leading points concept to explain the sensitivity of turbulent burning rates to fuel (and oxidizer) composition. Leading point theories suggest that the premixed turbulent flame speed is controlled by the flame front characteristics at the flame brush leading edge, or, in other words, by the flamelets that advance farthest into the unburned mixture (the so-called leading points). For negative Markstein length mixtures, this is assumed to be close to the maximum stretched laminar flame speed (SL,max) for the given fuel-oxidizer mixture. For the ST,GC measurements, the data at a given pressure were well-correlated with an SL,max scaling. However the variation with pressure was not captured, which may be due to non-quasi-steady effects that are not included in the current model. For the ST,LD data, the leading points model again faithfully captured the variation of turbulent flame speed over a wide range of fuel-compositions and turbulence intensities. These

  19. On the opening of premixed Bunsen flame tips

    Science.gov (United States)

    Law, C. K.; Ishizuka, S.; Cho, P.

    1982-01-01

    The local extinction of Bunsen flame tip and edges of hydrocarbon/air premixtures has been experimentally investigated using a variety of burners. Results show that, while for both rich propane/air and butane/air mixtures tip opening occurs at a constant fuel equivalence ratio of 1.44 and is therefore independent of the intensity, uniformity, and configuration of the approach flow, for rich methane/air flames burning is intensified at the tip and therefore opening is not possible. These results substantiate the concept and dominance of the diffusional stratification mechanism in causing extinction, and clarify the theoretical predictions on the possible opening of two-dimensional flame wedges.

  20. Analysis of polydisperse fuel spray flame

    Science.gov (United States)

    Nave, Ophir; Lehavi, Yaron; Ajadi, Suraju; Gol'dshtein, Vladimir

    2017-02-01

    In this paper we analyzed the model of polydisperse fuel spray flame by using the sectional approach to describe the droplet-droplet interaction within the spray. The radii of the droplets are described by a probability density function. Our numerical simulations include a comparative analysis between three empirical droplet size distributions: the Rosin-Rammler distribution, the log-normal distribution and the Nakiyama-Tanasawa distribution. The log-normal distribution was found to produce a reasonable approximation to both the number and volume size distribution function. In addition our comparative analysis includes the application of the homotopy analysis method which yields convergent solutions for all values of the relevant parameters. We compared the above results to experimental fuel spray data such as {it{Tetralin}}, n-{it{Decane}}, and n-{it{Heptane}}.

  1. CFD simulations on marine burner flames

    DEFF Research Database (Denmark)

    Cafaggi, Giovanni; Jensen, Peter Arendt; Glarborg, Peter

    of marine burners. The resulting auxiliary boilers shall be compact and able to operate with different fuel types, while reducing NOX emissions. The specific boiler object of this study uses a swirl stabilized liquid fuel burner, with a pressure swirl spill-return atomizer (Fig.1). The combustion chamber...... is enclosed in a water jacket used for water heating and evaporation, and a convective heat exchanger at the furnace outlet super-heats the steam. The purpose of the present study is to gather detailed knowledge about the influence of fuel spray conditions on marine utility boiler flames. The main goal...... of work presented in this paper was to obtain a spray description to setup a particle injection region in the CFD simulations of the boiler....

  2. Influence of oblique angle and heating height on flame structure, temperature field and efficiency of an impinging laminar jet flame

    Energy Technology Data Exchange (ETDEWEB)

    Shuhn Shyurng Hou [Kun Shan Univ. of Technology, Yung Kung City, Tainan, Taiwan (China). Dept. of Mechanical Engineering; Yung Chang Ko [National Cheng Kung Univ., Tainan, Taiwan (China). Dept. of Mechanical Engineering

    2005-04-01

    An experimental study is performed to determine the combined effects of oblique angle ({theta}) and heating height (H) on the flame structure, temperature field and thermal efficiency of a laminar premixed methane-air flame impinging on a plane surface. A double-flame burning of a Bunsen flame under a fuel-rich condition is used. It is found that the flame structure, temperature distribution and thermal efficiency depend strongly on the oblique angle and heating height. The influence of the oblique angle on flame structure is stronger for lower heating heights but is relatively weak for higher heating heights. For normal impingement, axisymmetric temperature distributions are found, which is attributed to the axisymmetric flame structure. However, a jet flame impinging at an angle onto the horizontal plate creates an asymmetric flame structure and, thus, results in asymmetric temperature distributions. The results show that as the oblique angle is reduced from 90{sup o} to 60{sup o}, the high-temperature zone shifts toward the major flow region. An optimum operating condition of the burner, identified by the widest high-temperature zone and the highest thermal efficiency, is achieved under the condition of {theta} = 60{sup o} and H = 12 mm. In general, a decrease of the oblique angle leads to a decrease in thermal efficiency. However, for the cases of lower heating heights (i.e. H {<=} 12 mm), the trend may be reversed. Furthermore, for a fixed oblique angle, as the heating height is increased, the thermal efficiency first increases to a maximum value and then decreases. (author)

  3. Properties of plasma flames sustained by microwaves and burning hydrocarbon fuels

    International Nuclear Information System (INIS)

    Hong, Yong Cheol; Uhm, Han Sup

    2006-01-01

    Plasma flames made of atmospheric microwave plasma and a fuel-burning flame were presented and their properties were investigated experimentally. The plasma flame generator consists of a fuel injector and a plasma flame exit connected in series to a microwave plasma torch. The plasma flames are sustained by injecting hydrocarbon fuels into a microwave plasma torch in air discharge. The microwave plasma torch in the plasma flame system can burn a hydrocarbon fuel by high-temperature plasma and high atomic oxygen density, decomposing the hydrogen and carbon containing fuel. We present the visual observations of the sustained plasma flames and measure the gas temperature using a thermocouple device in terms of the gas-fuel mixture and flow rate. The plasma flame volume of the hydrocarbon fuel burners was more than approximately 30-50 times that of the torch plasma. While the temperature of the torch plasma flame was only 868 K at a measurement point, that of the diesel microwave plasma flame with the addition of 0.019 lpm diesel and 30 lpm oxygen increased drastically to about 2280 K. Preliminary experiments for methane plasma flame were also carried out, measuring the temperature profiles of flames along the radial and axial directions. Finally, we investigated the influence of the microwave plasma on combustion flame by observing and comparing OH molecular spectra for the methane plasma flame and methane flame only

  4. Experimental study on flames propagating through zirconium particle clouds

    International Nuclear Information System (INIS)

    Yin Yi; Sun Jinhua; Ding Yibin; Guo Song; He Xuechao

    2009-01-01

    To reveal the mechanisms of flame propagation through the hardly volatile metal dust clouds clearly, the flame propagating through zirconium particle clouds has been examined experimentally. A high-speed video camera was used to record the propagation process of the flame. Combustion zone temperature was detected by a fine thermocouple. Based on the experimental results, structure of flame and combustion courses of zirconium particles were analyzed, the combustion propagation in zirconium dust was investigated, and the velocity and temperature characteristics of the combustion zone were also elucidated. The combustion zone propagating through zirconium particle clouds consists of luminous particles. Particle concentration plays an important role in the combustion zone propagation process. With the increase of zirconium particle concentration, the maximum temperature of the combustion zone increases at the lower concentration, takes a maximum value, and then decreases at the higher concentration. It is also found that the propagation velocity of the combustion zone has a linear relationship with its maximum temperature.

  5. Augmenting the Structures in a Swirling Flame via Diffusive Injection

    Directory of Open Access Journals (Sweden)

    Jonathan Lewis

    2014-01-01

    Full Text Available Small scale experimentation using particle image velocimetry investigated the effect of the diffusive injection of methane, air, and carbon dioxide on the coherent structures in a swirling flame. The interaction between the high momentum flow region (HMFR and central recirculation zone (CRZ of the flame is a potential cause of combustion induced vortex breakdown (CIVB and occurs when the HMFR squeezes the CRZ, resulting in upstream propagation. The diffusive introduction of methane or carbon dioxide through a central injector increased the size and velocity of the CRZ relative to the HMFR whilst maintaining flame stability, reducing the likelihood of CIVB occurring. The diffusive injection of air had an opposing effect, reducing the size and velocity of the CRZ prior to eradicating it completely. This would also prevent combustion induced vortex breakdown CIVB occurring as a CRZ is fundamental to the process; however, without recirculation it would create an inherently unstable flame.

  6. Development of Flame Retardants for Engineering Polymers and Polyurethanes

    Science.gov (United States)

    Desikan, Anantha

    2013-03-01

    With a broad portfolio of brominated, organophosphorus and inorganic flame retardants, ICL Industrial Products (ICL-IP) is engaged in the development of new flame retardants by exploiting the synergism between bromine based, phosphorus based and other halogen-free flame retardants. ICL-IP is also focusing on the development of polymeric and reactive flame retardants. This presentation will give examples of existing and new polymeric and reactive products for applications in thermoplastics, thermosets and polyurethane foam. This presentation will also show examples of phosphorus-bromine synergism allowing partial or complete elimination of antimony trioxide in many thermoplastics for electronic applications. New synergistic combinations of magnesium hydroxide with phosphorus and other halogen-free FRs will be presented. Work done in collaboration with S. Levchik, ICL-IP America, 430 Saw Mill Rriver Rd., Ardsley, NY, 10502, USA and M. Leifer, ICL-IP, P. O. Box 180, Beer Sheva 84101, Israel.

  7. Emission flame spectrophotometry of chromium, cobalt, nickel trace amounts

    International Nuclear Information System (INIS)

    Prudnikov, Y.D.; Shapkina, Y.S.

    1976-01-01

    Chromium, cobalt, and nickel were determined in a flame spectrophotometer with a dual diffraction monochromator, DFS-12, in a high-temperature nitrogen-acetylene flame. The effect of ionization and the elements in the oxidizing flame was small. The lower limit of detection for the three elements is 1x10 -2 to 1 x10 -3 μg/ml, and the high selectivity of the analysis permits determining down to 10 -4 % Cr and Ni and to 10 -3 % Co. These elements may be determined in rocks and minerals from solutions prepared for analysis for alkali and alkali-earth elements. The possibilities of emission flame spectrophotometry are as great as those of atomic-absorption analysis, and it may be used for determining Cr, Co, and Ni in rocks and minerals, especially pure substances, metals, and other materials

  8. Theoretical Adiabatic Temperature and Chemical Composition of Sodium Combustion Flame

    International Nuclear Information System (INIS)

    Okano, Yasushi; Yamaguchi, Akira

    2003-01-01

    Sodium fire safety analysis requires fundamental combustion properties, e.g., heat of combustion, flame temperature, and composition. We developed the GENESYS code for a theoretical investigation of sodium combustion flame.Our principle conclusions on sodium combustion under atmospheric air conditions are (a) the maximum theoretical flame temperature is 1950 K, and it is not affected by the presence of moisture; the uppermost limiting factor is the chemical instability of the condensed sodium-oxide products under high temperature; (b) the main combustion product is liquid Na 2 O in dry air condition and liquid Na 2 O with gaseous NaOH in moist air; and (c) the chemical equilibrium prediction of the residual gaseous reactants in the flame is indispensable for sodium combustion modeling

  9. Experimental study of flame stability in biogas premix system

    International Nuclear Information System (INIS)

    Diaz G, Carlos A; Amell A Andres; Cardona Luis F

    2008-01-01

    Utilization of new renewable energy sources have had a special interest in last years looking for decrease the dependence of fossil fuels and the environmental impact generated for them. This work studies experimentally the flame stability of a simulated biogas with a volumetric composition of 60% methane and 40% carbon dioxide. The objective of this study is to obtain information about design and interchangeability of gases in premixed combustion systems that operate with different fuel gases. The critical velocity gradient was the stability criteria used. Utilization of this criteria and the experimental method followed, using a partial premixed burner, stability flame diagram of biogas studied had been obtained. Presence of carbon dioxide has a negative effect in flame stability, decreasing significantly the laminar flame speed and consequently, the stability range of biogas burners because of apparition of blow off.

  10. Thermal Radiation Properties of Turbulent Lean Premixed Methane Air Flames

    National Research Council Canada - National Science Library

    Ji, Jun; Sivathanu, Y. R; Gore, J. P

    2000-01-01

    ... of turbulent premixed flames. Reduced cooling airflows in lean premixed combustors, miniaturization of combustors, and the possible use of radiation sensors in combustion control schemes are some of the practical reasons...

  11. Aryl Polyphosphonates: Useful Halogen-Free Flame Retardants for Polymers

    Directory of Open Access Journals (Sweden)

    Li Chen

    2010-10-01

    Full Text Available Aryl polyphosphonates (ArPPN have been demonstrated to function in wide applications as flame retardants for different polymer materials, including thermosets, polycarbonate, polyesters and polyamides, particularly due to their satisfactory thermal stability compared to aliphatic flame retardants, and to their desirable flow behavior observed during the processing of polymeric materials. This paper provides a brief overview of the main developments in ArPPN and their derivatives for flame-retarding polymeric materials, primarily based on the authors’ research work and the literature published over the last two decades. The synthetic chemistry of these compounds is discussed along with their thermal stabilities and flame-retardant properties. The possible mechanisms of ArPPN and their derivatives containing hetero elements, which exhibit a synergistic effect with phosphorus, are also discussed.

  12. The Rubens Tube: A Flaming Good Way to Teach Waves

    Science.gov (United States)

    Sandoval, Christopher

    2013-01-01

    The Ruben Flame Tube is named after H. Ruben, who published the demonstration experiment in "Annalen der Physik" in 1905. This article presents one of the many demonstrations the author uses to engage, motivate, and challenge his students.

  13. Persistence, bioaccumulation and toxicity of halogen-free flame retardants.

    NARCIS (Netherlands)

    Waaijers, S.L.; Kong, D; Hendriks, H.S.; de Wit, C.A.; Cousins, I.T.; Westerink, R.H.S.; Leonards, P.E.G.; Kraak, M.H.S.; Admiraal, W.; de Voogt, P.; Parsons, J.R.

    2013-01-01

    Polymers are synthetic organic materials that have a high carbon and hydrogen content, which renders them readily combustible. When used in buildings, electrical appliances, furniture, textiles, transportation, mining, and in many other applications, polymers have to fulfill flame retardancy

  14. Product engineering by high-temperature flame synthesis

    DEFF Research Database (Denmark)

    Johannessen, Tue; Johansen, Johnny; Mosleh, Majid

    also - coalescence of aggregated metal oxide nano-particles. As an example, it is possible produce well-defined spinel structures, e.g. zinc-aluminate (ZnAl2O4), with high specific surface area because the desired phase is formed directly without any need for post calcination. The production of other...... product gas can be applied directly in additional product engineering concepts. A brief overview of on-going product developments and product engineering projects is outlined below. These projects, which are all founded on flame synthesis of nano-structured materials, include: • Preparation of catalyzed......High-temperature flame processes can be applied as a tool for chemical product engineering. The general principle behind flame synthesis is the decomposition/oxidation of evaporated metal-precursors in a flame, thereby forming metal oxide monomers which nucleate, aggregate, and - to some extent...

  15. short communication determination of trace amounts of zinc by flame ...

    African Journals Online (AJOL)

    Preferred Customer

    ______. *Corresponding author. E-mail: amir.saljooghi@yahoo.com. SHORT COMMUNICATION. DETERMINATION OF TRACE AMOUNTS OF ZINC BY FLAME ATOMIC. ABSORPTION SPECTROMETRY AFTER SEPARATION AND. PRECONCENTRATION ONTO MODIFIED NATURAL ANALCIME ZEOLITE. LOADED 2,3 ...

  16. Probing flame chemistry with MBMS, theory, and modeling

    Energy Technology Data Exchange (ETDEWEB)

    Westmoreland, P.R. [Univ. of Massachusetts, Amherst (United States)

    1993-12-01

    The objective is to establish kinetics of combustion and molecular-weight growth in C{sub 3} hydrocarbon flames as part of an ongoing study of flame chemistry. Specific reactions being studied are (1) the growth reactions of C{sub 3}H{sub 5} and C{sub 3}H{sub 3} with themselves and with unsaturated hydrocarbons and (2) the oxidation reactions of O and OH with C{sub 3}`s. This approach combines molecular-beam mass spectrometry (MBMS) experiments on low-pressure flat flames; theoretical predictions of rate constants by thermochemical kinetics, Bimolecular Quantum-RRK, RRKM, and master-equation theory; and whole-flame modeling using full mechanisms of elementary reactions.

  17. Acoustically Forced Coaxial Hydrogen / Liquid Oxygen Jet Flames

    Science.gov (United States)

    2016-05-15

    Conference Paper 3. DATES COVERED (From - To) 18 Mar 2016 – 15 May 2016 4. TITLE AND SUBTITLE Acoustically Forced Coaxial Hydrogen / Liquid Oxygen Jet...ILASS-Americas 2016; Dearborn, MI May 15, 2016. Prepared in collaboration with Sierra Lobo , Inc. 14. ABSTRACT Combustion instabilities can pose...liquid rocket injector flames react to acoustic waves. In this study, a representative coaxial gaseous hydrogen / liquid oxygen (LOX) jet flame is

  18. Shear layer flame stabilization sensitivities in a swirling flow

    Directory of Open Access Journals (Sweden)

    Christopher Foley

    2017-03-01

    Full Text Available A variety of different flame configurations and heat release distributions exist in high swirl, annular flows, due to the existence of inner and outer shear layers as well a vortex breakdown bubble. Each of these different configurations, in turn, has different thermoacoustic sensitivities and influences on combustor emissions, nozzle durability, and liner heating. This paper presents findings on the sensitivities of the outer shear layer- stabilized flames to a range of parameters, including equivalence ratio, bulkhead temperature, flow velocity, and preheat temperature. There is significant hysteresis for flame attachment/detachment from the outer shear layer and this hysteresis is also described. Results are also correlated with extinction stretch rate calculations based on detailed kinetic simulations. In addition, we show that the bulkhead temperature near the flame attachment point has significant impact on outer shear layer detachment. This indicates that understanding the heat transfer between the edge flame stabilized in the shear layer and the nozzle hardware is needed in order to predict shear layer flame stabilization limits. Moreover, it shows that simulations cannot simply assume adiabatic boundary conditions if they are to capture these transitions. We also show that the reference temperature for correlating these transitions is quite different for attachment and local blow off. Finally, these results highlight the deficiencies in current understanding of the influence of fluid mechanic parameters (e.g. velocity, swirl number on shear layer flame attachment. For example, they show that the seemingly simple matter of scaling flame transition points with changes in flow velocities is not understood.

  19. Environmental fate & effects of new generation flame retardants

    OpenAIRE

    Waaijers, S.L.

    2014-01-01

    There is a pressing need for substituting several halogenated flame retardants, given the human and environmental health concerns of many of these compounds. Halogen Free Flame Retardants (HFFRs) have been suggested as alternatives and are already being marketed, although their potential impact on the environment cannot be properly assessed because of a lack of information regarding their environmental and ecotoxicological properties. The aim of this study was to determine the aquatic fate an...

  20. Mode Selection in Flame-Vortex driven Combustion Instabilities

    KAUST Repository

    Speth, Ray

    2011-01-04

    In this paper, we investigate flame-vortex interaction in a lean premixed, laboratory scale, backward-facing step combustor. Two series of tests were conducted, using propane/hydrogen mixtures and carbon monoxide/hydrogen mixtures as fuels, respectively. Pressure measurements and high speed particle imaging velocimetry (PIV) were employed to generate pressure response curves as well as the images of the velocity field and the flame brush. We demonstrate that the step combustor exhibits several operating modes depending on the inlet conditions and fuel composition, characterized by the amplitude and frequency of pressure oscillations along with distinct dynamic flame shapes. We propose a model in which the combustor\\'s selection of the acoustic mode is governed by a combustion-related time delay inversely proportional to the flame speed. Our model predicts the transition between distinct operating modes. We introduce non-dimensional parameters characterizing the flame speed and stretch rate, and develop a relationship between these quantities at the operating conditions corresponding to each mode transition. Based on this relationship, we show that numerically-calculated density-weighted strained flame speed can be used to collapse the combustion dynamics data over the full range of conditions (inlet temperature, fuel composition, and equivalence ratio). Finally, we validate our strain flame based model by measuring the strain rate using the flame image and the velocity field from the PIV measurement. Our results show that the measured strain rates lie in the same range as the critical values at the transitions among distinct modes as those predicted by our model.

  1. Flame Dynamics and Chemistry in LRE Combustion Instability

    Science.gov (United States)

    2016-12-22

    observe the cool flame was conducted by either gradually increasing the N2 temperature to about 700 K under proper flow rate, or gradually varying the...boundary velocity can be varied to change the flow residence time, and dilution can be added to the fuel stream to change the chemical time scale...on the thermal and chemical properties of the flame in such periodically time- varying flows were evaluated. Three regimes were found depending on

  2. Resistivity of flame plasma in an electric field

    International Nuclear Information System (INIS)

    Ikuta, Kazunari.

    1989-01-01

    A generalized Ohm's law is obtained for a flame plasma in an electric field for the study of arc resistivity in an electromagnetic launcher (EML). The effective resistivity of flame plasma is reduced by the source, which suggests the injection of premixed combustible fuel into the arc plasma in EML in order to reduce the electron energy of the arc. The reduction of electron energy in the arc is desirable to minimize the damage of electrodes in EML. (author)

  3. Experimental Studies of Hydrocarbon Flame Phenomena: Enabling Combustion Control

    Science.gov (United States)

    2016-07-30

    et al. [9], will be considered due to considerations on fuel -mixing within the experimental setup. The turbulent intensity theory postulates that...consisted of a delrin plastic case surrounding a 10 7 AWG solid core copper wire charging up to 12 needle electrodes on the same loop, though only...the leading edge of the flame, it was possible to reattach a lifted jet flame, while maintaining a constant fuel flow rate. b) With a negatively

  4. The physics of flames in Type Ia supernovae

    International Nuclear Information System (INIS)

    Zingale, M; Woosley, S E; Bell, J B; Day, M S; Rendleman, C A

    2005-01-01

    We extend a low Mach number hydrodynamics method developed for terrestrial combustion, to the study of thermonuclear flames in Type Ia supernovae. We discuss the differences between 2-D and 3-D Rayleigh-Taylor unstable flame simulations, and give detailed diagnostics on the turbulence, showing that the kinetic energy power spectrum obeys Bolgiano-Obukhov statistics in 2-D, but Kolmogorov statistics in 3-D. Preliminary results from 3-D reacting bubble calculations are shown, and their implications for ignition are discussed

  5. Effect of Electric Field on Outwardly Propagating Spherical Flame

    KAUST Repository

    Mannaa, Ossama

    2012-06-01

    The thesis comprises effects of electric fields on a fundamental study of spheri­cal premixed flame propagation.Outwardly-propagating spherical laminar premixed flames have been investigated in a constant volume combustion vessel by applying au uni-directional electric potential.Direct photography and schlieren techniques have been adopted and captured images were analyzed through image processing. Unstretched laminar burning velocities under the influence of electric fields and their associated Markstein length scales have been determined from outwardly prop­agating spherical flame at a constant pressure. Methane and propane fuels have been tested to assess the effect of electric fields on the differential diffusion of the two fuels.The effects of varying equivalence ratios and applied voltages have been in­vestigated, while the frequency of AC was fixed at 1 KHz. Directional propagating characteristics were analyzed to identify the electric filed effect. The flame morphology varied appreciably under the influence of electric fields which in turn affected the burning rate of mixtures.The flame front was found to propagate much faster toward to the electrode at which the electric fields were supplied while the flame speeds in the other direction were minimally influenced. When the voltage was above 7 KV the combustion is markedly enhanced in the downward direction since intense turbulence is generated and as a result the mixing process or rather the heat and mass transfer within the flame front will be enhanced.The com­bustion pressure for the cases with electric fields increased rapidly during the initial stage of combustion and was relatively higher since the flame front was lengthened in the downward direction.

  6. Transition of carbon nanostructures in heptane diffusion flames

    Energy Technology Data Exchange (ETDEWEB)

    Hu, Wei-Chieh [National Cheng Kung University, Department of Mechanical Engineering (China); Hou, Shuhn-Shyurng [Kun Shan University, Department of Mechanical Engineering (China); Lin, Ta-Hui, E-mail: thlin@mail.ncku.edu.tw [National Cheng Kung University, Department of Mechanical Engineering (China)

    2017-02-15

    The flame synthesis has high potential in industrial production of carbon nanostructure (CNS). Unfortunately, the complexity of combustion chemistry leads to less controlling of synthesized products. In order to improve the understanding of the relation between flames and CNSs synthesized within, experiments were conducted through heptane flames in a stagnation-point liquid-pool system. The operating parameters for the synthesis include oxygen supply, sampling position, and sampling time. Two kinds of nanostructures were observed, carbon nanotube (CNT) and carbon nano-onion (CNO). CNTs were synthesized in a weaker flame near extinction. CNOs were synthesized in a more sooty flame. The average diameter of CNTs formed at oxygen concentration of 15% was in the range of 20–30 nm. For oxygen concentration of 17%, the average diameter of CNTs ranged from 24 to 27 nm, while that of CNOs was around 28 nm. For oxygen concentration of 19%, the average diameter of CNOs produced at the sampling position 0.5 mm below the flame front was about 57 nm, while the average diameters of CNOs formed at the sampling positions 1–2.5 mm below the flame front were in the range of 20–25 nm. A transition from CNT to CNO was observed by variation of sampling position in a flame. We found that the morphology of CNS is directly affected by the presence of soot layer due to the carbonaceous environment and the growth mechanisms of CNT and CNO. The sampling time can alter the yield of CNSs depending on the temperature of sampling position, but the morphology of products is not affected.

  7. Flame image monitoring and analysis in combustion management

    Energy Technology Data Exchange (ETDEWEB)

    Popovic, D. [CEZ, a.s. Elektrarna Detmarovice, Detmarovice (Czech Republic); Huttunen, A.J.; Nihtinen, J.J. [Imatran Voima Oy, IVO Technology Centre, Vantaa (Finland)

    1997-12-31

    When NO{sub x} emissions are reduced with new low-NO{sub x} burners and infurnace modifications in old pulverised fuel boilers, many changes in the firing conditions may occur. Depending on coal quality and the original furnace design, low-NO{sub x} burners, overtire air, low-excess-air firing and other primary modifications in various combinations may cause flame instability, increased slagging, increased minimum load and other difficulties in controlling the burning process. To find and solve these problems quicker, a new type of burner management system for pulverised fuel and oil-fired boilers was developed by Imatran Voima Oy. The DIMAC combustion management system monitors and analyses individually each burner or burner level. There are special software for wall and corner fired boilers. The DIMAC system is comprised of two functional subsystems: flame monitoring and flame analysis. The DIMAC enables the power plant operators to minimise NO{sub x} emissions and optimise the burning efficiency with varying coal qualities and boiler loads at the same time so that slagging, unburnt carbon in fly ash and flame stability stay in acceptable limits. It also guarantees that burners operate in good safety conditions in each burner level. The DIMAC system monitors perpendicularly each individual burner and evaluates flame parameters. Real-time flame monitoring and analysis allows the operator to directly see the effect of changing fuel distribution on flame pattern and flame stability. Based on data from the DIMAC references the system can improve boiler efficiency by 0.2 - 0.5 per cent unit as a result of more efficient control of the burning process. At the same time, the NO{sub x} formation can be reduced by 10 - 20 % 2 refs.

  8. Lagrangian Enstrophy Dynamics in Highly Turbulent Premixed Flames

    Science.gov (United States)

    Darragh, Ryan; Towery, Colin; Poludnenko, Alexei; Hamlington, Peter

    2017-11-01

    Turbulent combustion is a multi-scale and multi-physics problem depending upon both chemical and fluid dynamic processes. These processes are often examined using an Eulerian framework, but recently the Lagrangian framework, a long-time tool in non-reacting flow research, has become increasingly common for the study of turbulent combustion. The two analysis frameworks are in fact equivalent, with the only difference being a change in reference frame. In this study, a Lagrangian fluid parcel tracking algorithm is used to analyze the enstrophy (i.e., vorticity magnitude) dynamics in turbulent premixed reacting flows. The analysis of vorticity dynamics in the premixed flame case is based on data from a three dimensional direct numerical simulation of a premixed stoichiometric hydrogen-air flame in an unconfined domain. Enstrophy budget terms are tracked along Lagrangian trajectories as fluid parcels travel through the flame, with particular focus on understanding the dynamical causes of turbulence variations through the flame preheat and reaction zones with respect to both the fluid parcel and the flame. Additionally, the ability of trajectories to completely sample the flame is discussed.

  9. Onset of Darrieus-Landau Instability in Expanding Flames

    Science.gov (United States)

    Mohan, Shikhar; Matalon, Moshe

    2017-11-01

    The effect of small amplitude perturbations on the propagation of circular flames in unconfined domains is investigated, computationally and analytically, within the context of the hydrodynamic theory. The flame, treated as a surface of density discontinuity separating fresh combustible mixture from the burnt gas, propagates at a speed dependent upon local curvature and hydrodynamic strain. For mixtures with Lewis numbers above criticality, thermodiffusive effects have stabilizing influences which largely affect the flame at small radii. The amplitude of these disturbances initially decay and only begin to grow once a critical radius is reached. This instability is hydrodynamic in nature and is a consequence of thermal expansion. Through linear stability analysis, predictions of critical flame radius at the onset of instability are obtained as functions of Markstein length and thermal expansion coefficients. The flame evolution is also examined numerically where the motion of the interface is tracked via a level-set method. Consistent with linear stability results, simulations show the flame initially remaining stable and the existence of a particular mode that will be first to grow and later determine the cellular structure observed experimentally at the onset of instability.

  10. Ion measurements in premixed methane-oxygen flames

    KAUST Repository

    Alquaity, Awad

    2014-07-25

    Ions are formed as a result of chemi-ionization processes in combustion systems. Recently, there has been an increasing interest in understanding flame ion chemistry due to the possible application of external electric fields to reduce emissions and improve combustion efficiency by active control of combustion process. In order to predict the effect of external electric fields on combustion plasma, it is critical to gain a good understanding of the flame ion chemistry. In this work, a Molecular Beam Mass Spectrometer (MBMS) is utilized to measure ion concentration profiles in premixed methane-oxygen-argon burner-stabilized flames. Lean, stoichiometric and rich flames at atmospheric pressure are used to study the dependence of ion chemistry on equivalence ratio of premixed flames. The relative ion concentration profiles are compared qualitatively with previous methane-oxygen studies and show good agreement. The relative ion concentration data obtained in the present study can be used to validate and improve ion chemistry models for methane-oxygen flames.

  11. PREMIXED FLAME PROPAGATION AND MORPHOLOGY IN A CONSTANT VOLUME COMBUSTION CHAMBER

    Energy Technology Data Exchange (ETDEWEB)

    Hariharan, A; Wichman, IS

    2014-06-04

    This work presents an experimental and numerical investigation of premixed flame propagation in a constant volume rectangular channel with an aspect ratio of six (6) that serves as a combustion chamber. Ignition is followed by an accelerating cusped finger-shaped flame-front. A deceleration of the flame is followed by the formation of a "tulip"-shaped flame-front. Eventually, the flame is extinguished when it collides with the cold wall on the opposite channel end. Numerical computations are performed to understand the influence of pressure waves, instabilities, and flow field effects causing changes to the flame structure and morphology. The transient 2D numerical simulation results are compared with transient 3D experimental results. Issues discussed are the appearance of oscillatory motions along the flame front and the influences of gravity on flame structure. An explanation is provided for the formation of the "tulip" shape of the premixed flame front.

  12. Enhancement of flame development by microwave-assisted spark ignition in constant volume combustion chamber

    KAUST Repository

    Wolk, Benjamin

    2013-07-01

    The enhancement of laminar flame development using microwave-assisted spark ignition has been investigated for methane-air mixtures at a range of initial pressures and equivalence ratios in a 1.45. l constant volume combustion chamber. Microwave enhancement was evaluated on the basis of several parameters including flame development time (FDT) (time for 0-10% of total net heat release), flame rise time (FRT) (time for 10-90% of total net heat release), total net heat release, flame kernel growth rate, flame kernel size, and ignitability limit extension. Compared to a capacitive discharge spark, microwave-assisted spark ignition extended the lean and rich ignition limits at all pressures investigated (1.08-7.22. bar). The addition of microwaves to a capacitive discharge spark reduced FDT and increased the flame kernel size for all equivalence ratios tested and resulted in increases in the spatial flame speed for sufficiently lean flames. Flame enhancement is believed to be caused by (1) a non-thermal chemical kinetic enhancement from energy deposition to free electrons in the flame front and (2) induced flame wrinkling from excitation of flame (plasma) instability. The enhancement of flame development by microwaves diminishes as the initial pressure of the mixture increases, with negligible flame enhancement observed above 3. bar. © 2013 The Combustion Institute.

  13. Flame Front Detection Using Formaldehyde Laser Induced Fluorescence In Turbulent Lean Premixed Flames

    Energy Technology Data Exchange (ETDEWEB)

    Schenker, S.; Tylli, N.; Bombach, R.

    2005-03-01

    The present work aims at suggesting the excitation-detection scheme best suited for laser-induced fluorescence measurements of formaldehyde in turbulent lean premixed flames. In the literature, three different excitation schemes within the A{sup 1} X{sup 1} electronic transition have been suggested, with excitation into the 2{sup 1}{sub 0} 4{sup 1}{sub 0} , 4{sup 1}{sub 0} , and 4{sup 0}{sub 1} vibratoric bands, respectively. These excitation schemes were tested systematically and both advantages and disadvantages for each scheme are discussed. (author)

  14. Simultaneous determination of brominated and phosphate flame retardants in flame-retarded polyester curtains by a novel extraction method.

    Science.gov (United States)

    Miyake, Yuichi; Tokumura, Masahiro; Nakayama, Hayato; Wang, Qi; Amagai, Takashi; Ogo, Sayaka; Kume, Kazunari; Kobayashi, Takeshi; Takasu, Shinji; Ogawa, Kumiko; Kannan, Kurunthachalam

    2017-12-01

    The use of novel brominated flame retardants (BFRs) and phosphate-based flame retardants (PFRs) has increased as substitutes for hexabromocyclododecane (HBCD) in many consumer products. To facilitate collection of data on chemicals used as flame retardants in textiles and fabrics, we developed an analytical method using liquid chromatography interfaced with tandem mass spectrometry (LC-MS/MS). We compared two extraction methods, one involving ultrasonic extraction (traditional method) using dichloromethane, toluene or acetone and the other encompassing complete dissolution of textile with 25% 1,1,1,3,3,3-hexafluoro-2-propanol/chloroform. The dissolution method extracted up to 204 times more BFRs and PFRs than the traditional ultrasonic extraction. Tris(2,3-dibromopropyl) isocyanurate (TDBP-TAZTO), triphenylphosphine oxide (TPhPO), tris(1,3-dichloro-2-propyl) phosphate (TDCPP), tricresyl phosphate (TCsP), and triphenyl phosphate (TPhP) were found in 40 flame-retarded curtain samples purchased from Japanese market in 2014. TDBP-TAZTO was detected in polyester curtains for the first time. Some of the flame-retarded curtain samples did not contain any of the known target analytes, which suggested the presence of other unknown flame retardants in those fabrics. Copyright © 2017. Published by Elsevier B.V.

  15. Formation and stabilization of multiple ball-like flames at Earth gravity

    KAUST Repository

    Zhou, Zhen

    2018-03-20

    Near-limit low-Lewis-number premixed flame behavior is studied experimentally and numerically for flames of H–CH–air mixtures that are located in a 55 mm diameter tube and below a perforated plate in a downward mixture flow. A combustion regime diagram is experimentally identified in terms of equivalence ratio and ratio of H to CH (variation of fuel Lewis number). Planar flames, cell-like flames, distorted cap-like flames, and arrays of ball-like flames are progressively observed in the experiments as the equivalence ratio is decreased. The experimentally observed ball-like lean limit flames experience chaotic motion, which is accompanied by sporadic events of flame splitting and extinction, while the total number of simultaneously burning flamelets remains approximately the same. In separate experiments, the multiple ball-like lean limit flames are stabilized by creating a slightly non-uniform mixture flow field. The CH* chemiluminescence distributions of the lean limit flames are recorded, showing that the ball-like lean limit flame front becomes more uniform in intensity and its shape approaches a spherical one with the increase of H content in the fuel. Numerical simulations are performed for single representative flames of the array of stabilized flamelets observed in the experiments. The simulated ball-like lean limit flame is further contrasted with the single ball-like flame that forms in a narrow tube (13.5 mm inner diameter) with an iso-thermal wall. The numerical results show that the ball-like lean limit flames present in the array of ball-like flames are more affected by the buoyancy-induced recirculation zone, compared with that in the narrow tube, revealing why the shape of the ball-like flame in the array deviates more from a spherical one. All in all, the wall confinement is not crucial for the formation of ball-like flames at terrestrial gravity.

  16. Aromatics Oxidation and Soot Formation in Flames

    Energy Technology Data Exchange (ETDEWEB)

    Howard, J. B.; Richter, H.

    2005-03-29

    This project is concerned with the kinetics and mechanisms of aromatics oxidation and the growth process to polycyclic aromatic hydrocarbons (PAH) of increasing size, soot and fullerenes formation in flames. The overall objective of the experimental aromatics oxidation work is to extend the set of available data by measuring concentration profiles for decomposition intermediates such as phenyl, cyclopentadienyl, phenoxy or indenyl radicals which could not be measured with molecular-beam mass spectrometry to permit further refinement and testing of benzene oxidation mechanisms. The focus includes PAH radicals which are thought to play a major role in the soot formation process while their concentrations are in many cases too low to permit measurement with conventional mass spectrometry. The radical species measurements are used in critical testing and improvement of a kinetic model describing benzene oxidation and PAH growth. Thermodynamic property data of selected species are determined computationally, for instance using density functional theory (DFT). Potential energy surfaces are explored in order to identify additional reaction pathways. The ultimate goal is to understand the conversion of high molecular weight compounds to nascent soot particles, to assess the roles of planar and curved PAH and relationships between soot and fullerenes formation. The specific aims are to characterize both the high molecular weight compounds involved in the nucleation of soot particles and the structure of soot including internal nanoscale features indicative of contributions of planar and/or curved PAH to particle inception.

  17. Sorption of Organophosphorus Flame Retardants (OPFRs) on ...

    Science.gov (United States)

    Organophosphorus flame retardants (OPFRs) are widely used as additives in industrial and consumer products such as electrical and electronic products, furniture, plastics, textiles, and building/construction materials. Due to human exposure and potential health effects, OPFRs including tris(2-chloroethyl) phosphate (TCEP), tris(1-chloro-2-propyl) phosphate (TCPP), and tris(1,3-dichloro-2-propyl) phosphate (TDCPP) are EPA Action Plan chemicals for chemical assessments under the Toxic Substances Control Act (TSCA). This work investigated the sorption of these three compounds from the air to settled Arizona Test Dust (ATD) and house dust (HD) in a dual small chamber system. The OPFR exposed dust was analyzed to determine the sorption concentration and sorption rate of OPFRs on the dust. The effect of the composition of the dust on OPFR sorption was evaluated. The results showed that ATD and HD have varied sorption capacity for OPFRs from air. This work explores the relationship between OPFR concentrations in settled dust and air. The data can be used to determine partitioning of OPFRs between the gas phase and settled dust indoors and to inform strategies to reduce exposure and risk.

  18. CloudFlame: Cyberinfrastructure for combustion research

    KAUST Repository

    Goteng, Gokop

    2013-12-01

    Combustion experiments and chemical kinetics simulations generate huge data that is computationally and data intensive. A cloud-based cyber infrastructure known as Cloud Flame is implemented to improve the computational efficiency, scalability and availability of data for combustion research. The architecture consists of an application layer, a communication layer and distributed cloud servers running in a mix environment of Windows, Macintosh and Linux systems. The application layer runs software such as CHEMKIN modeling application. The communication layer provides secure transfer/archive of kinetic, thermodynamic, transport and gas surface data using private/public keys between clients and cloud servers. A robust XML schema based on the Process Informatics Model (Prime) combined with a workflow methodology for digitizing, verifying and uploading data from scientific graphs/tables to Prime is implemented for chemical molecular structures of compounds. The outcome of using this system by combustion researchers at King Abdullah University of Science and Technology (KAUST) Clean Combustion Research Center and its collaborating partners indicated a significant improvement in efficiency in terms of speed of chemical kinetics and accuracy in searching for the right chemical kinetic data.

  19. Flame-induced atmospheric pressure chemical ionization mass spectrometry.

    Science.gov (United States)

    Cheng, Sy-Chyi; Chen, Yen-Ting; Jhang, Siou-Sian; Shiea, Jentaie

    2016-04-15

    Charged species such as formylium (CHO(+) ), hydronium (H3 O(+) ), and water clusters [H3 O(+) (H2 O)n ] are commonly found in flames. These highly reactive species can react with analytes via ion-molecule reactions (IMRs) to form analyte ions. A new mass spectrometric technique, named flame-induced atmospheric pressure chemical ionization mass spectrometry (FAPCI-MS), was developed to characterize organic compounds via these mechanisms. A commercial corona-discharge atmospheric pressure chemical ionization (APCI) source was modified by replacing the corona needle with a flame to make a FAPCI source. Liquid samples were vaporized in a heated tube and delivered to the IMRs region by nitrogen to react with the charged species generated by a flame. Analytes on surfaces were directly desorbed and ionized by a flame using the technique called desorption-FAPCI-MS (DFAPCI-MS). Intact molecular ions of various chemical and biological compounds were successfully characterized by FAPCI-MS. The FAPCI mass spectra are nearly identical to those obtained by traditional APCI-MS. The limit of detection (LOD) of reserpine by FAPCI-MS was 50 μg L(-1) with a linear calibration curve (R(2) = 0.9947) from 100 μg L(-1) to 10 mg L(-1) . The LOD for ketamine by DFAPCI-MS was estimated to be less than 0.1 ng. In FAPCI, analytes are not incinerated but vaporized and introduced into the ion source to react with the reactive charged species generated by a flame. The features of the FAPCI source include: configuration is very simple, operation is easy, high voltage or inert gas is unnecessary, and the source is maintenance free. Various combustible gases, solvents and solids are useful flame fuels for FAPCI. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.

  20. The evolution of the flame surface in turbulent premixed jet flames at high Reynolds number

    Science.gov (United States)

    Luca, Stefano; Attili, Antonio; Bisetti, Fabrizio

    2017-11-01

    A set of direct numerical simulations of turbulent premixed flames in a spatially developing turbulent slot burner at four Reynolds number is presented. This configuration is of interest since it displays turbulent production by mean shear as in real combustion devices. The gas phase hydrodynamics are modeled with the reactive, unsteady Navier-Stokes equations in the low Mach number limit, with finite-rate chemistry consisting of 16 species and 73 reactions. For the highest jet Reynolds number of 22 ×103, 22 Billion grid points are employed. The jet consists of a lean methane/air mixture at 4 atm and preheated to 800 K. The analysis of stretch statistics shows that the mean total stretch is close to zero. Mean stretch decreases moving downstream from positive to negative values, suggesting a formation of surface area in the near field and destruction at the tip of the flame; the mean contribution of the tangential strain term is positive, while the mean contribution of the propagative term is always negative. Positive values of stretch are due to the tangential strain rate term, while large negative values are associated with the propagative term. Increasing Reynolds number is found to decrease the correlation between stretch and the single contributions.

  1. Perubahan Preheat Zone Thickness dan Bilangan Karlovitz pada Fenomena Flame lift-up Pembakaran Premix Gas Propana

    OpenAIRE

    I Made Kartika Dhiputra; Bambang Sugiarto; Yulianto S. Nugroho; Cokorda Prapti Mahandari

    2009-01-01

    It has been found a phenomenon of flame lift-up on the experiment employing a Bunsen burner. Flame lift-up is the occurrence of flame jumping from the tip burner to the ring that inserting above the burner. Fundamental research on flames did not elaborate the cause of flame jumping. Using flame stretch approach, an initial research on dimensionless number to predict the occasion of this phenomenon was discussed to determine preheat zone thickness and Karlovitz number. Preheat zone thickness w...

  2. Perubahan Preheat Zone Thickness Dan Bilangan Karlovitz Pada Fenomena Flame Lift-up Pembakaran Premix Gas Propana

    OpenAIRE

    Dhiputra, I Made Kartika; Sugiarto, Bambang; Nugroho, Yulianto S; Mahandari, Cokorda Prapti

    2009-01-01

    It has been found a phenomenon of flame lift-up on the experiment employing a Bunsen burner. Flame lift-up is the occurrence of flame jumping from the tip burner to the ring that inserting above the burner. Fundamental research on flames did not elaborate the cause of flame jumping. Using flame stretch approach, an initial research on dimensionless number to predict the occasion of this phenomenon was discussed to determine preheat zone thickness and Karlovitz number. Preheat zone thickness w...

  3. Effect of Lewis number on ball-like lean limit flames

    KAUST Repository

    Zhou, Zhen

    2017-10-13

    The lean limit flames for three different fuel compositions premixed with air, representing three different mixture Lewis numbers, stabilized inside a tube in a downward flow are examined by experiments and numerical simulations. The CH* chemiluminescence distribution in CH4–air and CH4–H2–air flames and the OH* chemiluminescence distribution in H2–air flames are recorded in the experiments. Cell-like flames are observed for the CH4–air mixture for all tested equivalence ratios. However, for CH4–H2–air and H2–air flames, ball-like lean limit flames are observed. Flame temperature fields are measured using Rayleigh scattering. The experimentally observed lean limit flames are predicted qualitatively by numerical simulation with the mixture-averaged transport model and skeletal mechanism of CH4. The results of the simulations show that the entire lean limit flames of CH4–H2–air and H2–air mixtures are located inside a recirculation zone. However, for the lean limit CH4–air flame, only the leading edge is located inside the recirculation zone. A flame structure with negative flame displacement speed is observed for the leading edges of the predicted lean limit flames with all three different fuel compositions. As compared with 1D planar flames, the fuel transport caused by convection is less significant in the present 2D lean limit flames for the three different fuel compositions. For the trailing edges of the three predicted lean limit flames, a diffusion dominated flame structure is observed.

  4. Stabilization and structure of n-heptane tribrachial flames in axisymmetric laminar jets

    KAUST Repository

    Bisetti, Fabrizio

    2015-01-01

    A set of tribrachial flames of n-heptane/air is simulated with finite rate chemistry and detailed transport in a realistic laminar jet configuration for which experimental data are available. The flames differ by the temperature of the unburnt mixture and stabilization height, which controls the mixture fraction gradient ahead of the flame front. The simulations reproduce the lift-off heights in the experiments, showing that the flame stabilizes further downstream as the unburnt temperature decreases. For the lowest unburnt temperature, resulting in a weak mixture fraction gradient at the tribrachial point, positive stretch along the rich premixed wing leads to an increase in the rate of chemical reaction in the whole flame. The tribrachial flame burning velocity exceeds that in the unstretched, one-dimensional flame. For the highest temperature, the flame stabilizes closest to the nozzle. Large flame tilt, large mixture fraction gradient, and small radius of curvature lead to a reduction in the heat release rate and the flame propagates slower than its one-dimensional counterpart. The observed behavior is explained with a detailed analysis of the flame geometry, differential diffusion effects, flame stretch, and transport of heat and mass from the burnt gases to the flame front. © 2014 The Combustion Institute.

  5. Combustion Characteristics for Turbulent Prevaporized Premixed Flame Using Commercial Light Diesel and Kerosene Fuels

    Directory of Open Access Journals (Sweden)

    Mohamed S. Shehata

    2014-01-01

    Full Text Available Experimental study has been carried out for investigating fuel type, fuel blends, equivalence ratio, Reynolds number, inlet mixture temperature, and holes diameter of perforated plate affecting combustion process for turbulent prevaporized premixed air flames for different operating conditions. CO2, CO, H2, N2, C3H8, C2H6, C2H4, flame temperature, and gas flow velocity are measured along flame axis for different operating conditions. Gas chromatographic (GC and CO/CO2 infrared gas analyzer are used for measuring different species. Temperature is measured using thermocouple technique. Gas flow velocity is measured using pitot tube technique. The effect of kerosene percentage on concentration, flame temperature, and gas flow velocity is not linearly dependent. Correlations for adiabatic flame temperature for diesel and kerosene-air flames are obtained as function of mixture strength, fuel type, and inlet mixture temperature. Effect of equivalence ratio on combustion process for light diesel-air flame is greater than for kerosene-air flame. Flame temperature increases with increased Reynolds number for different operating conditions. Effect of Reynolds number on combustion process for light diesel flame is greater than for kerosene flame and also for rich flame is greater than for lean flame. The present work contributes to design and development of lean prevaporized premixed (LPP gas turbine combustors.

  6. Measurements of a high-luminosity flame structure by a shuttered PIV system

    International Nuclear Information System (INIS)

    Li, Yueh-Heng; Wu, Chih-Yung; Chen, Bi-Chian; Chao, Yei-Chin

    2008-01-01

    It is difficult to measure the velocity distribution inside a high-luminosity flame by using the particle image velocimetry (PIV) system with a double-shutter mode CCD camera. The second raw image of the PIV image pair is usually contaminated by flame emission. The main cause of the problem is an excess exposure time which lets the flame emission overlap the particle image in the second frame. If the flame-contamination problem is not significant, for example in faint flames, digital image processing can improve the image to an acceptable level. Nevertheless, when the PIV technique is applied to high-luminosity flames, the second raw particle image would be contaminated by flame emission. In this paper, incorporating a mechanical shutter in the PIV system with a double-shutter CCD camera is proposed to improve PIV measurements in high-luminosity flames. Measurements in faint, high-luminosity as well as very bright flames were tested. The results show that the present setup can accurately resolve the flow velocity field inside the flame cone, through the flame and in the post flame zone for all the flame conditions analyzed. The velocity distributions and streamline patterns measured by the present equipment are reasonable and meaningful

  7. FLAME MONITORING IN POWER STATION BOILERS USING IMAGE PROCESSING

    Directory of Open Access Journals (Sweden)

    K. Sujatha

    2012-05-01

    Full Text Available Combustion quality in power station boilers plays an important role in minimizing the flue gas emissions. In the present work various intelligent schemes to infer the flue gas emissions by monitoring the flame colour at the furnace of the boiler are proposed here. Flame image monitoring involves capturing the flame video over a period of time with the measurement of various parameters like Carbon dioxide (CO2, excess oxygen (O2, Nitrogen dioxide (NOx, Sulphur dioxide (SOx and Carbon monoxide (CO emissions plus the flame temperature at the core of the fire ball, air/fuel ratio and the combustion quality. Higher the quality of combustion less will be the flue gases at the exhaust. The flame video was captured using an infrared camera. The flame video is then split up into the frames for further analysis. The video splitter is used for progressive extraction of the flame images from the video. The images of the flame are then pre-processed to reduce noise. The conventional classification and clustering techniques include the Euclidean distance classifier (L2 norm classifier. The intelligent classifier includes the Radial Basis Function Network (RBF, Back Propagation Algorithm (BPA and parallel architecture with RBF and BPA (PRBFBPA. The results of the validation are supported with the above mentioned performance measures whose values are in the optimal range. The values of the temperatures, combustion quality, SOx, NOx, CO, CO2 concentrations, air and fuel supplied corresponding to the images were obtained thereby indicating the necessary control action taken to increase or decrease the air supply so as to ensure complete combustion. In this work, by continuously monitoring the flame images, combustion quality was inferred (complete/partial/incomplete combustion and the air/fuel ratio can be automatically varied. Moreover in the existing set-up, measurements like NOx, CO and CO2 are inferred from the samples that are collected periodically or by

  8. Exposure to flame retardant chemicals on commercial airplanes.

    Science.gov (United States)

    Allen, Joseph G; Stapleton, Heather M; Vallarino, Jose; McNeely, Eileen; McClean, Michael D; Harrad, Stuart J; Rauert, Cassandra B; Spengler, John D

    2013-02-16

    Flame retardant chemicals are used in materials on airplanes to slow the propagation of fire. These chemicals migrate from their source products and can be found in the dust of airplanes, creating the potential for exposure. To characterize exposure to flame retardant chemicals in airplane dust, we collected dust samples from locations inside 19 commercial airplanes parked overnight at airport gates. In addition, hand-wipe samples were also collected from 9 flight attendants and 1 passenger who had just taken a cross-country (USA) flight. The samples were analyzed for a suite of flame retardant chemicals. To identify the possible sources for the brominated flame retardants, we used a portable XRF analyzer to quantify bromine concentrations in materials inside the airplanes. A wide range of flame retardant compounds were detected in 100% of the dust samples collected from airplanes, including BDEs 47, 99, 153, 183 and 209, tris(1,3-dichloro-isopropyl)phosphate (TDCPP), hexabromocyclododecane (HBCD) and bis-(2-ethylhexyl)-tetrabromo-phthalate (TBPH). Airplane dust contained elevated concentrations of BDE 209 (GM: 500 ug/g; range: 2,600 ug/g) relative to other indoor environments, such as residential and commercial buildings, and the hands of participants after a cross-country flight contained elevated BDE 209 concentrations relative to the general population. TDCPP, a known carcinogen that was removed from use in children's pajamas in the 1970's although still used today in other consumer products, was detected on 100% of airplanes in concentrations similar to those found in residential and commercial locations. This study adds to the limited body of knowledge regarding exposure to flame retardants on commercial aircraft, an environment long hypothesized to be at risk for maximum exposures due to strict flame retardant standards for aircraft materials. Our findings indicate that flame retardants are widely used in many airplane components and all airplane types, as

  9. A Polycarbonate/Magnesium Oxide Nanocomposite with High Flame Retardancy.

    Science.gov (United States)

    Dong, Quanxiao; Gao, Chong; Ding, Yanfen; Wang, Feng; Wen, Bin; Zhang, Shimin; Wang, Tongxin; Yang, Mingshu

    2012-01-15

    A new flame retardant polycarbonate/magnesium oxide (PC/MgO) nanocomposite, with high flame retardancy was developed by melt compounding. The effect of MgO to the flame retardancy, thermal property, and thermal degradation kinetics were investigated. Limited oxygen index (LOI) test revealed that a little amount of MgO (2 wt %) led to significant enhancement (LOI = 36.8) in flame retardancy. Thermogravimetric analysis results demonstrated that the onset temperature of degradation and temperature of maximum degradation rate decreased in both air and N 2 atmosphere. Apparent activation energy was estimated via Flynn-Wall-Ozawa method. Three steps in the thermal degradation kinetics were observed after incorporation of MgO into the matrix and the additive raised activation energies of the composite in the full range except the initial stage. It was interpreted that the flame retardancy of PC was influenced by MgO through the following two aspects: on the one hand, MgO catalyzed the thermal-oxidative degradation and accelerated a thermal protection/mass loss barrier at burning surface; on the other hand, the filler decreased activation energies in the initial step and improved thermal stability in the final period.

  10. Mixture preparation by cool flames for diesel-reforming technologies

    Science.gov (United States)

    Hartmann, L.; Lucka, K.; Köhne, H.

    The separation of the evaporation from the high-temperature reaction zone is crucial for the reforming process. Unfavorable mixtures of liquid fuels, water and air lead to degradation by local hot spots in the sensitive catalysts and formation of unwanted by-products in the reformer. Furthermore, the evaporator has to work with dynamic changes in the heat transfer, residence times and educt compositions. By using exothermal pre-reactions in the form of cool flames it is possible to realize a complete and residue-free evaporation of liquid hydrocarbon mixtures. The conditions whether cool flames can be stabilised or not is related to the heat release of the pre-reactions in comparison to the heat losses of the system. Examinations were conducted in a flow reactor at atmospheric pressure and changing residence times to investigate the conditions under which stable cool flame operation is possible and auto-ignition or quenching occurs. An energy balance of the evaporator should deliver the values of heat release by cool flames in comparison to the heat losses of the system. The cool flame evaporation is applied in the design of several diesel-reforming processes (thermal and catalytic partial oxidation, autothermal reforming) with different demands in the heat management and operation range (air ratio λ, steam-to-carbon ratio, SCR). The results are discussed at the end of this paper.

  11. Temperature measurements in a wall stabilized steady flame using CARS

    KAUST Repository

    Sesha Giri, Krishna

    2017-01-05

    Flame quenching by heat loss to a surface continues to be an active area of combustion research. Close wall temperature measurements in an isothermal wall-stabilized flame are reported in this work. Conventional N-vibrational Coherent Anti-Stokes Raman Scattering (CARS) thermometry as close as 275 μm to a convex wall cooled with water has been carried out. The standard deviation of mean temperatures is observed to be ~6.5% for high temperatures (>2000K) and ~14% in the lower range (<500K). Methane/air and ethylene/air stoichiometric flames for various global strain rates based on exit bulk velocities are plotted and compared. CH* chemiluminescence is employed to determine the flame location relative to the wall. Flame locations are shown to move closer to the wall with increasing strain rates in addition to higher near-wall temperatures. Peak temperatures for ethylene are considerably higher (~250-300K) than peak temperatures for methane. Preheat zone profiles are similar for different strain rates across fuels. This work demonstrates close wall precise temperature measurments using CARS.

  12. Phosphor thermometry on a rotating flame holder for combustion applications

    Science.gov (United States)

    Xavier, Pradip; Selle, Laurent; Oztarlik, Gorkem; Poinsot, Thierry

    2018-02-01

    This study presents a method to measure wall temperatures of a rotating flame holder, which could be used as a combustion control device. Laser-induced phosphorescence is found to be a reliable technique to gather such experimental data. The paper first investigates how the coating (thickness, emissivity and lifetime) influence the flame stabilization. While the low thermal conductivity of the coating is estimated to induce a temperature difference of only 0.08-0.4 K, the emissivity increases by 40%. Nevertheless, the transient and steady-state flame locations are not affected. Second, because temperature measurements on the rotating cylinder are likely to fail due the long phosphor lifetimes, we modify the classical point-wise arrangement. We propose to illuminate a larger area, and to correct the signal with a distortion function that accounts for the displacement of the target. An analytical distortion function is derived and compared to measured ones. It shows that the range of measurements is limited by the signal extinction and the rapid distortion function decay. A diagram summarizes the range of operating conditions where measurements are valid. Finally, these experimental data are used to validate direct numerical simulations. Cylinder temperature variations within the precision of these measurements are shown not to influence the flame location, but larger deviations highlight different trends for the two asymmetric flame branches.

  13. Role of buoyant flame dynamics in wildfire spread.

    Science.gov (United States)

    Finney, Mark A; Cohen, Jack D; Forthofer, Jason M; McAllister, Sara S; Gollner, Michael J; Gorham, Daniel J; Saito, Kozo; Akafuah, Nelson K; Adam, Brittany A; English, Justin D

    2015-08-11

    Large wildfires of increasing frequency and severity threaten local populations and natural resources and contribute carbon emissions into the earth-climate system. Although wildfires have been researched and modeled for decades, no verifiable physical theory of spread is available to form the basis for the precise predictions needed to manage fires more effectively and reduce their environmental, economic, ecological, and climate impacts. Here, we report new experiments conducted at multiple scales that appear to reveal how wildfire spread derives from the tight coupling between flame dynamics induced by buoyancy and fine-particle response to convection. Convective cooling of the fine-sized fuel particles in wildland vegetation is observed to efficiently offset heating by thermal radiation until convective heating by contact with flames and hot gasses occurs. The structure and intermittency of flames that ignite fuel particles were found to correlate with instabilities induced by the strong buoyancy of the flame zone itself. Discovery that ignition in wildfires is critically dependent on nonsteady flame convection governed by buoyant and inertial interaction advances both theory and the physical basis for practical modeling.

  14. Response to acoustic forcing of laminar coflow jet diffusion flames

    KAUST Repository

    Chrystie, Robin

    2014-04-23

    Toward the goal of understanding and controlling instability in combustion systems, we present a fundamental characterization of the interaction of the buoyancy-induced instability in flickering flames with forced excitation of fuel supply. Laminar coflow diffusion flames were acoustically forced, whose frequency responses were recorded as a function of excitation frequency and amplitude. The evolving structure of such flames was also examined through the use of video analysis and particle imaging velocimetry (PIV). For specific combinations of excitation frequency and amplitude, the frequency response of the flames was found to couple to that of the forcing, where the contribution of natural puffing frequency disappears. Such instances of coupling exhibited many harmonics of the excitation frequency, related indirectly to the natural puffing frequency. We showed how such harmonics form, through application of PIV, and furthermore unveiled insight into the physics of how the flame couples to the forcing under certain conditions. Our frequency response characterization provides quantitative results, which are of utility for both modeling studies and active-control strategies. Copyright © Taylor & Francis Group, LLC.

  15. Flame spread behavior over combustible thick solid of paper, bagasse and mixed paper/bagasse

    Science.gov (United States)

    Azahari Razali, Mohd; Mohd, Sofian; Sapit, Azwan; Nizam Mohammed, Akmal; Husaini Ismail, Ahmad; Faisal Hushim, Mohd; Jaat, Norrizam; Khalid, Amir

    2017-09-01

    Flame spread behavior on combustible solid is one of important research related to Fire Safety Engineering. Now, there are a lot of combustible solid composed from mixed materials. In this study, experiments have been conducted to investigate flame spread behavior over combustible solid composed by paper, bagasse and mixed paper/bagasse. Experimental data is captured by using video recording and examined flame spread shape and rate. From the results obtained, shows that the different materials produce different flame spread shape and rate. Different flame shape is seen between all types of samples. Flame spread rate of 100% paper is faster than the one of 100% bagasse. Based on the result, it is also inferred that the material composition can be influenced on the flame spread shape and flame spread rate of mixed paper/bagasse.

  16. Determination of temperature and concentrations of main components in flames by fitting measured Raman spectra

    NARCIS (Netherlands)

    Sepman, A. V.; Toro, V.V.; Mokhov, A. V.; Levinsky, H. B.

    The procedure of deriving flame temperature and major species concentrations by fitting measured Raman spectra in hydrocarbon flames is described. The approach simplifies the calibration procedure to determine temperature and major species concentrations from the measured Raman spectra. The

  17. Effect of CH4–Air Ratios on Gas Explosion Flame Microstructure and Propagation Behaviors

    Directory of Open Access Journals (Sweden)

    Ying Zhang

    2012-10-01

    Full Text Available To reveal the inner mechanism of gas explosion dynamic behavior affected by gas equivalent concentration, a high speed Schlieren image system and flow field measurement technology was applied to record the gas explosion flame propagation and flame structure transition. The results show that a flame front structure transition occurs, followed by a flame accelerating propagation process. The laminar to turbulence transition was the essential cause of the flame structure changes. The laminar flame propagation behavior was influenced mainly by gas expansion and fore-compressive wave effect, while the turbulent flame speed mostly depended on turbulence intensity, which also played an important role in peak value of the explosive pressure and flame speed. On the condition that the laminar-turbulent transition was easier to form, the conclusion was drawn that, the lowest CH4 concentration for maximum overpressure can be obtained, which was the essential reason why the ideal explosive concentration differs under different test conditions.

  18. Instabilities and soot formation in spherically expanding, high pressure, rich, iso-octane-air flames

    Energy Technology Data Exchange (ETDEWEB)

    Lockett, R D [School of Engineering and Mathematical Sciences, City University, Northampton Square, London EC1V OHB (United Kingdom)

    2006-07-15

    Flame instabilities, cellular structures and soot formed in high pressure, rich, spherically expanding iso-octane-air flames have been studied experimentally using high speed Schlieren cinematography, OH fluorescence, Mie scattering and laser induced incandescence. Cellular structures with two wavelength ranges developed on the flame surface. The larger wavelength cellular structure was produced by the Landau-Darrieus hydrodynamic instability, while the short wavelength cellular structure was produced by the thermal-diffusive instability. Large negative curvature in the short wavelength cusps caused local flame quenching and fracture of the flame surface. In rich flames with equivalence ratio {phi} > 1.8, soot was formed in a honeycomb-like structure behind flame cracks associated with the large wavelength cellular structure induced by the hydrodynamic instability. The formation of soot precursors through low temperature pyrolysis was suggested as a suitable mechanism for the initiation of soot formation behind the large wavelength flame cracks.

  19. Simulations of Cavity-Stabilized Flames in Supersonic Flow Using Reduced Chemical Kinetic Mechanisms (Postprint)

    National Research Council Canada - National Science Library

    Liu, Jiwen; Tam, Chung-Jen; Lu, Tianfeng; Law, Chung K

    2006-01-01

    The VULCAN CFD code integrated with a reduced chemical kinetic mechanism was applied to simulate cavity-stabilized ethylene-air flames and to predict flame stability limits in supersonic flows based...

  20. Chemistry of Destroying of Organophosphorus Compounds in Flame and Mechanism of Their Action as Fire Suppressants

    National Research Council Canada - National Science Library

    Korobeinichev, Oleg

    2002-01-01

    .... An influence of TMP additive on the structure of atmospheric flames was demonstrated. A strong influence of equivalence ratio of a flame on the concentration of PO, PO2, HOPO, HOPO2 and OP(OH)3 has been observed...

  1. Research on Forest Flame Recognition Algorithm Based on Image Feature

    Science.gov (United States)

    Wang, Z.; Liu, P.; Cui, T.

    2017-09-01

    In recent years, fire recognition based on image features has become a hotspot in fire monitoring. However, due to the complexity of forest environment, the accuracy of forest fireworks recognition based on image features is low. Based on this, this paper proposes a feature extraction algorithm based on YCrCb color space and K-means clustering. Firstly, the paper prepares and analyzes the color characteristics of a large number of forest fire image samples. Using the K-means clustering algorithm, the forest flame model is obtained by comparing the two commonly used color spaces, and the suspected flame area is discriminated and extracted. The experimental results show that the extraction accuracy of flame area based on YCrCb color model is higher than that of HSI color model, which can be applied in different scene forest fire identification, and it is feasible in practice.

  2. RESEARCH ON FOREST FLAME RECOGNITION ALGORITHM BASED ON IMAGE FEATURE

    Directory of Open Access Journals (Sweden)

    Z. Wang

    2017-09-01

    Full Text Available In recent years, fire recognition based on image features has become a hotspot in fire monitoring. However, due to the complexity of forest environment, the accuracy of forest fireworks recognition based on image features is low. Based on this, this paper proposes a feature extraction algorithm based on YCrCb color space and K-means clustering. Firstly, the paper prepares and analyzes the color characteristics of a large number of forest fire image samples. Using the K-means clustering algorithm, the forest flame model is obtained by comparing the two commonly used color spaces, and the suspected flame area is discriminated and extracted. The experimental results show that the extraction accuracy of flame area based on YCrCb color model is higher than that of HSI color model, which can be applied in different scene forest fire identification, and it is feasible in practice.

  3. Development of low-smoke, flame-retarding cables

    International Nuclear Information System (INIS)

    Kato, H.; Kanemitsuya, K.; Furukawa, K.; Mio, K.

    1983-01-01

    A great deal of attention has been given to the potential fire hazard of combustion gases from organic materials. Although cable industries have developed flame-retarding organic materials for the insulation and jacketing of wires and cables, there was insufficient prevention of toxic gas formation during combustion. To cope with these problems associated with conventional PVC cables, the authors have directed to develop low-smoke, flame-retarding plasticized PVC formulations retaining the original mechanical, electrical and aging properties. A series of basic investigations on smoke suppression followed by an evaluation on practical cables could indicate some effective means to end these problems. This paper describes the results and discussion on smoke suppressing study of plasticized PVC as well as behavior and characteristics of the low-smoke, flame-retarding PVC wires and cables using these materials. (author)

  4. Porosity effects in flame length of the porous burners

    Directory of Open Access Journals (Sweden)

    Fatemeh Bahadori

    2014-10-01

    Full Text Available Furnaces are the devices for providing heat to the industrial systems like boilers, gas turbines and etc. The main challenge of furnaces is emission of huge air pollutants. However, porous burners produce less contaminant compared to others. The quality of the combustion process in the porous burners depends on the length of flame in the porous medium. In this paper, the computational fluid dynamic (CFD is used to investigate the porosity effects on the flame length of the combustion process in porous burner. The simulation results demonstrate that increasing the porosity increases the flame length and the combustion zone extends forward. So, combustion quality increases and production of carbon monoxide decrease. It is possible to conclude that temperature distribution in low porosity burner is lower and more uniform than high porosity one. Therefore, by increasing the porosity of the burner, the production of nitrogen oxides increases. So, using an intermediate porosity in the burner appears to be reasonable.

  5. Investigations of Sooting Laminar Coflow Diffusion Flames at Elevated Pressures

    KAUST Repository

    Steinmetz, Scott A.

    2016-12-01

    Soot is a common byproduct of hydrocarbon based combustion systems. It poses a risk to human and environmental health, and can negatively or positively affect combustor performance. As a result, there is significant interest in understanding soot formation in order to better control it. More recently, the need to study soot formation in engine relevant conditions has become apparent. One engine relevant parameter that has had little focus is the ambient pressure. This body of work focuses on the formation of soot in elevated pressure environments, and a number of investigations are carried out with this purpose. Laminar coflow diffusion flames are used as steady, simple soot producers. First, a commonly studied flame configuration is further characterized. Coflow flames are frequently used for fundamental flame studies, particularly at elevated pressures. However, they are more susceptible to buoyancy induced instabilities at elevated pressures. The velocity of the coflow is known to have an effect on flame stability and soot formation, though these have not been characterized at elevated pressures. A series of flames are investigated covering a range of flowrates, pressures, and nozzle diameters. The stability limits of coflow flames in this range is investigated. Additionally, an alternative strategy for scaling these flames to elevated pressures is proposed. Finally, the effect of coflow rate on soot formation is evaluated. Identification of fundamental flames for coordinated research can facilitate our understanding of soot formation. The next study of this work focuses on adding soot concentration and particle size information to an existing fundamental flame dataset for the purpose of numerical model validation. Soot volume fraction and average particle diameters are successfully measured in nitrogen-diluted ethylene-air laminar coflow flames at pressures of 4, 8, 12, and 16 atm. An increase in particle size with pressure is found up to 12 atm, where particle

  6. Experimental Investigation of Turbulence-Chemistry Interaction in High-Reynolds-Number Turbulent Partially Premixed Flames

    Science.gov (United States)

    2016-06-23

    Malte Kllner, Penelope Monkhouse, and Jrgen Wolfrum. Time-resolved lif of oh in atmospheric - pressure flames using picosecond excitation. Chemical... flames . We use the Sandia flame C, D and E data of Barlow and Karpetis [9, 10] to obtain the dependence of σeff and ρ on ξ and T in the form of look-up... Flames Chenning Tong CLEMSON UNIVERSITY Final Report 06/23/2016 DISTRIBUTION A: Distribution approved for public release. AF Office Of Scientific Research

  7. Flame retardancy and ultraviolet resistance of silk fabric coated by graphene oxide

    OpenAIRE

    Ji Yi-Min; Cao Ying-Ying; Chen Guo-Qiang; Xing Tie-Ling

    2017-01-01

    Silk fabrics were coated by graphene oxide hydrosol in order to improve its flame retardancy and ultraviolet resistance. In addition, montmorillonoid was doped into the graphene oxide hydrosol to further improve the flame retardancy of silk fabrics. The flame retardancy and ultraviolet resistance were mainly characterized by limiting oxygen index, vertical flame test, smoke density test, and ultraviolet protection factor. The synergistic effect of graphene oxide and montmorillonoid on the the...

  8. Correlation of Soot Formation in Turbojet Engines and in Laboratory Flames.

    Science.gov (United States)

    1981-02-01

    tendency of a fuel to soot (cf. Refs. 18 and 19); for Bunsen burner flames the calculated adiabatic flame temperatures at the incipient soot point... flame burner is used to measure the smoke point. An objection can also be made to using a smoke point defined by using small laboratory diffusion...in Appendix A, it is possible to calibrate a wide variety of laboratory-scale diffusion or premixed flame burners so that if soot thresh- olds for a

  9. Halogenated flame retardants in bobcats from the midwestern United States.

    Science.gov (United States)

    Boyles, Esmarie; Tan, Hongli; Wu, Yan; Nielsen, Clayton K; Shen, Li; Reiner, Eric J; Chen, Da

    2017-02-01

    In response to the restrictions of polybrominated diphenyl ether (PBDE) flame retardants in various consumer products, alternative halogenated flame retardants have been subjected to increased use. Compared to aquatic ecosystems, relatively little information is available on the contamination of alternative flame retardants in terrestrial ecosystems, especially with regards to mammalian wildlife. In this study we used a top terrestrial carnivore, the bobcat (Lynx rufus), as a unique biomonitoring species for assessing flame retardant contamination in the Midwestern United States (U.S.) terrestrial ecosystems. Concentrations of ∑PBDEs (including all detectable PBDE congeners) ranged from 8.3 to 1920 ng/g lipid weight (median: 50.3 ng/g lw) in livers from 44 bobcats collected during 2013-2014 in Illinois. Among a variety of alternative flame retardants screened, Dechloranes (including anti- and syn-Dechlorane Plus and Dechlorane-602, 603, and 604), tetrabromo-o-chlorotoluene (TBCT), and hexabromocyclododecane (HBCD) were also frequently detected, with median concentrations of 28.7, 5.2, and 11.8 ng/g lw, respectively. Dechlorane analogue compositions in bobcats were different from what has been reported in other studies, suggesting species- or analogue-dependent bioaccumulation, biomagnification, or metabolism of Dechlorane chemicals in different food webs. Our findings, along with previously reported food web models, suggest Dechloranes may possess substantial bioaccumulation and biomagnification potencies in terrestrial mammalian food webs. Thus, attention should be given to these highly bioavailable flame retardants in future environmental biomonitoring and risk assessments in a post-PBDE era. Copyright © 2016. Published by Elsevier Ltd.

  10. Effects of heating height on flame appearance, temperature field and efficiency of an impinging laminar jet flame used in domestic gas stoves

    International Nuclear Information System (INIS)

    Hou, S.-S.; Ko, Y.-C.

    2004-01-01

    Laminar jet flames are used in most domestic gas burners. However, the literature on combustion characteristics and thermal efficiencies of a single laminar impinging jet flame is very limited. Heating height is a significant operating parameter of a domestic gas stove, but it has received little attention in the literature. In this study, our aim is to simulate and examine the effect of heating height on the flame characteristics of a domestic gas stove. We emphasize the importance of heating height on flame structure, temperature distribution and thermal efficiency for low-Reynolds-number fuel-rich methane-air flames impinging normal to a plane surface, which has not been documented yet. Results show that flame structure, temperature distribution and thermal efficiency are greatly influenced by the heating height. With increasing heating height, the thermal efficiency first increases to a maximum value and then decreases. An optimum heating height, identified by the widest high temperature zone and the highest thermal efficiency, is achieved under the condition of Type-C flame burning, in which both the inner premixed flame and outer diffusion flame are open and diverge. Furthermore, we find that the optimum heating height increases with increasing methane concentration or injection velocity. Note that the maximum thermal efficiency occurs when the heating height is slightly lower than the tip of the inner rich premixed flame. This important characteristic can be applied to the design of domestic gas stoves, and it was not found in the available published work

  11. Compressive sensing for spatial and spectral flame diagnostics.

    Science.gov (United States)

    Starling, David J; Ranalli, Joseph

    2018-02-07

    Combustion research requires the use of state of the art diagnostic tools, including high energy lasers and gated, cooled CCDs. However, these tools may present a cost barrier for laboratories with limited resources. While the cost of high energy lasers and low-noise cameras continues to decline, new imaging technologies are being developed to address both cost and complexity. In this paper, we analyze the use of compressive sensing for flame diagnostics by reconstructing Raman images and calculating mole fractions as a function of radial depth for a highly strained, N 2 -H 2 diffusion flame. We find good agreement with previous results, and discuss the benefits and drawbacks of this technique.

  12. Detection of atomic oxygen in flames by absorption spectroscopy

    International Nuclear Information System (INIS)

    Cheskis, S.; Kovalenko, S.A.

    1994-01-01

    The absolute concentration of atomic oxygen in an atmospheric pressure hydrogen/air flame has been measured using Intracavity Laser Spectroscopy (ICLS) based on a dye laser pumped by an argon-ion laser. Absorptions at the highly forbidden transitions at 630.030 nm and 636.380 nm were observed at an equivalent optical length of up to 10 km. The relatively low intensity of the dye laser avoids photochemical interferences that are inherent to some other methods for detecting atomic oxygen. The detection sensitivity is about 6x10 14 atom/cm 3 and can be improved with better flame and laser stabilization. (orig.)

  13. Rate Controlling Factors in a Bunsen Burner Flame

    Science.gov (United States)

    Andrade-Gamboa, Julio; Corso, Hugo L.; Gennari, Fabiana C.

    2003-05-01

    Combustion and flames have been extensively investigated during past decades due to their industrial importance. The associated phenomena are both physical and chemical in nature, and the rigorous mathematical description is beyond the undergraduate teaching level. While thermodynamic calculations of temperature of a Bunsen burner flame can be made at the college level, there are not accessible chemical kinetic descriptions that can be used for instruction. In this paper we present a simple model that accounts for mass transfer, energy transfer, and kinetics of chemical reaction. From such a description, different controlling regimes can be deduced and tested with experimental data.

  14. Speckle photography applied to the density field of a flame

    Science.gov (United States)

    Shu, J.-Z.; Li, J.-Y.

    1987-11-01

    An optical arrangement combining a set-up for taking speckle records with a shearing interferometer using a Wollaston prism is applied to the study of a fluctuating Bunsen burner flame. The simultaneous recording, in real time, of the interferogram facilitates the interpretation of the data field derived by the point-by-point analysis of the specklegram. The pattern of Young's fringes obtained by analysis of the specklegram at 16 different positions in the field of view is shown, displaying the random variation of the light deflection in the flame.

  15. Turbulent Burning Velocities and Flame Straining in Explosions

    Science.gov (United States)

    Abdel-Gayed, R. G.; Al-Khishali, K. J.; Bradley, D.

    1984-02-01

    Turbulent burning velocities have been measured in an explosion bomb equipped with four high speed fans. Turbulent parameters were measured by laser doppler anemometry. The turbulent Reynolds numbers were significantly higher than in most previous measurements and high rates of strain were achieved until, ultimately, several of the flames quenched. Results are presented in terms of previously used dimensionless parameters plus a Lewis number and a dimensionless activation energy. The two-eddy theory of burning can allow for flame straining reductions in laminar burning velocity and experimental values of u_t/u_1 were compared with those from such a theory.

  16. 46 CFR 32.20-10 - Flame arresters-TB/ALL.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 1 2010-10-01 2010-10-01 false Flame arresters-TB/ALL. 32.20-10 Section 32.20-10 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY TANK VESSELS SPECIAL EQUIPMENT, MACHINERY, AND HULL REQUIREMENTS Equipment Installations § 32.20-10 Flame arresters—TB/ALL. Flame arresters must be of a type and...

  17. 46 CFR 30.10-23 - Flame arrester-TB/ALL.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 1 2010-10-01 2010-10-01 false Flame arrester-TB/ALL. 30.10-23 Section 30.10-23 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY TANK VESSELS GENERAL PROVISIONS Definitions § 30.10-23 Flame arrester—TB/ALL. The term flame arrester means any device or assembly of a cellular, tubular...

  18. 30 CFR 7.408 - Test for flame resistance of signaling cables.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Test for flame resistance of signaling cables..., Signaling Cables, and Cable Splice Kits § 7.408 Test for flame resistance of signaling cables. (a) Test... either and support and the center support. (6) After subjecting the test specimen to external flame for...

  19. A study of flame spread in engineered cardboard fuelbeds: Part I: Correlations and observations

    Science.gov (United States)

    Mark A. Finney; Jason Forthofer; Isaac C. Grenfell; Brittany A. Adam; Nelson K. Akafuah; Kozo Saito

    2013-01-01

    Wind tunnel laboratory fires spreading through laser-cut cardboard fuel beds were instrumented and analyzed for physical processes associated with spread. Flames in the span-wise direction appeared as a regular series of peaks-and-troughs that scaled directly with flame length. Flame structure in the stream-wise direction fluctuated with the forward advection of...

  20. 49 CFR 392.67 - Heater, flame-producing; on commercial motor vehicle in motion.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 5 2010-10-01 2010-10-01 false Heater, flame-producing; on commercial motor... SAFETY REGULATIONS DRIVING OF COMMERCIAL MOTOR VEHICLES Prohibited Practices § 392.67 Heater, flame-producing; on commercial motor vehicle in motion. No open flame heater used in the loading or unloading of...

  1. Mineralisation and primary biodegradation of aromatic organophosphorus flame retardants in activated sludge

    NARCIS (Netherlands)

    Jurgens, S.S.; Helmus, R.; Waaijers, S.L.; Uittenbogaard, D.; Dunnebier, D.; Vleugel, M.; Kraak, M.H.S.; de Voogt, P.; Parsons, J.R.

    2014-01-01

    Halogen-free flame retardants (HFFRs), such as the aromatic organophosphorus flame retardants (OPFRs) triphenyl phosphate (TPHP), resorcinol bis(diphenylphosphate) (PBDPP) and bisphenol A bis(diphenylphosphate) (BPA-BDPP) have been proposed as potential replacements for brominated flame retardants

  2. Blow-off characteristics of turbulent premixed flames in curved-wall Jet Burner

    KAUST Repository

    Mansour, Morkous S.

    2015-08-02

    This study concerns the flame dynamics of a curved-wall jet (CWJ) stabilized turbulent premixed flame as it approaches blow-off conditions. Time resolved OH planar laser-induced fluorescence (PLIF) delineated reaction zone contours and simultaneously stereoscopic particle image velocimetry (SPIV) quantified the turbulent flow field features. Ethylene/air flames were stabilized in CWJ burner to determine the sequence of events leading to blowoff. For stably burning flames far from blowoff, flames are characterized with a recirculation zone (RZ) upstream for flame stabilization followed by an intense turbulent interaction jet (IJ) and merged-jet regions downstream; the flame front counterparts the shear layer vortices. Near blowoff, as the velocity of reactants increases, high local stretch rates exceed the extinction stretch rates instantaneously resulting in localized flame extinction along the IJ region. As Reynolds number (Re) increases, flames become shorter and are entrained by larger amounts of cold reactants. The increased strain rates together with heat loss effects result in further fragmentation of the flame, eventually leading to the complete quenching of the flame. This is explained in terms of local turbulent Karlovitz stretch factor (K) and principal flow strain rates associated with C contours. Hydrogen addition and increasing the RZ size lessen the tendency of flames to be locally extinguished.

  3. Refractory Materials for Flame Deflector Protection System Corrosion Control: Flame Deflector Protection System Life Cycle Cost Analysis Report

    Science.gov (United States)

    Calle, Luz Marina; Hintze, Paul E.; Parlier, Christopher R.; Coffman, Brekke E.; Kolody, Mark R.; Curran, Jerome P.; Trejo, David; Reinschmidt, Ken; Kim, Hyung-Jin

    2009-01-01

    A 20-year life cycle cost analysis was performed to compare the operational life cycle cost, processing/turnaround timelines, and operations manpower inspection/repair/refurbishment requirements for corrosion protection of the Kennedy Space Center launch pad flame deflector associated with the existing cast-in-place materials and a newer advanced refractory ceramic material. The analysis compared the estimated costs of(1) continuing to use of the current refractory material without any changes; (2) completely reconstructing the flame trench using the current refractory material; and (3) completely reconstructing the flame trench with a new high-performance refractory material. Cost estimates were based on an analysis of the amount of damage that occurs after each launch and an estimate of the average repair cost. Alternative 3 was found to save $32M compared to alternative 1 and $17M compared to alternative 2 over a 20-year life cycle.

  4. An experimental study of the effect of a pilot flame on technically pre-mixed, self-excited combustion instabilities

    Science.gov (United States)

    O'Meara, Bridget C.

    Combustion instabilities are a problem facing the gas turbine industry in the operation of lean, pre-mixed combustors. Secondary flames known as "pilot flames" are a common passive control strategy for eliminating combustion instabilities in industrial gas turbines, but the underlying mechanisms responsible for the pilot flame's stabilizing effect are not well understood. This dissertation presents an experimental study of a pilot flame in a single-nozzle, swirl-stabilized, variable length atmospheric combustion test facility and the effect of the pilot on combustion instabilities. A variable length combustor tuned the acoustics of the system to excite instabilities over a range of operating conditions without a pilot flame. The inlet velocity was varied from 25 -- 50 m/s and the equivalence ratio was varied from 0.525 -- 0.65. This range of operating conditions was determined by the operating range of the combustion test facility. Stability at each operating condition and combustor length was characterized by measurements of pressure oscillations in the combustor. The effect of the pilot flame on the magnitude and frequency of combustor stability was then investigated. The mechanisms responsible for the pilot flame effect were studied using chemiluminescence flame images of both stable and unstable flames. Stable flame structure was investigated using stable flame images of CH* chemiluminescence emission. The effect of the pilot on stable flame metrics such as flame length, flame angle, and flame width was investigated. In addition, a new flame metric, flame base distance, was defined to characterize the effect of the pilot flame on stable flame anchoring of the flame base to the centerbody. The effect of the pilot flame on flame base anchoring was investigated because the improved stability with a pilot flame is usually attributed to improved flame anchoring through the recirculation of hot products from the pilot to the main flame base. Chemiluminescence images

  5. Two-dimensional simulations of steady perforated-plate stabilized premixed flames

    Science.gov (United States)

    Murat Altay, H.; Kedia, Kushal S.; Speth, Raymond L.; Ghoniem, Ahmed F.

    2010-03-01

    The objective of this work is to examine the impact of the operating conditions and the perforated-plate design on the steady, lean premixed flame characteristics. We perform two-dimensional simulations of laminar flames using a reduced chemical kinetics mechanism for methane-air combustion, consisting of 20 species and 79 reactions. We solve the heat conduction problem within the plate, allowing heat exchange between the gas mixture and the solid plate. The physical model is based on a zero-Mach-number formulation of the axisymmetric compressible conservation equations. The results suggest that the flame consumption speed, the flame structure, and the flame surface area depend significantly on the equivalence ratio, mean inlet velocity, the distance between the perforated-plate holes and the plate thermal conductivity. In the case of an adiabatic plate, a conical flame is formed, anchored near the corner of the hole. When the heat exchange between the mixture and the plate is finite, the flame acquires a Gaussian shape stabilizing at a stand-off distance, that grows with the plate conductivity. The flame tip is negatively curved; i.e. concave with respect to the reactants. Downstream of the plate, the flame base is positively curved; i.e. convex with respect to the reactants, stabilizing above a stagnation region established between neighboring holes. As the plate's thermal conductivity increases, the heat flux to the plate decreases, lowering its top surface temperature. As the equivalence ratio increases, the flame moves closer to the plate, raising its temperature, and lowering the flame stand-off distance. As the mean inlet velocity increases, the flame stabilizes further downstream, the flame tip becomes sharper, hence raising the burning rate at that location. The curvature of the flame base depends on the distance between the neighboring holes; and the flame there is characterized by high concentration of intermediates, like carbon monoxide.

  6. Unsteady Flame Embedding (UFE) Subgrid Model for Turbulent Premixed Combustion Simulations

    KAUST Repository

    El-Asrag, Hossam

    2010-01-04

    We present a formulation for an unsteady subgrid model for premixed combustion in the flamelet regime. Since chemistry occurs at the unresolvable scales, it is necessary to introduce a subgrid model that accounts for the multi-scale nature of the problem using the information available on the resolved scales. Most of the current models are based on the laminar flamelet concept, and often neglect the unsteady effects. The proposed model\\'s primary objective is to encompass many of the flame/turbulence interactions unsteady features and history effects. In addition it provides a dynamic and accurate approach for computing the subgrid flame propagation velocity. The unsteady flame embedding approach (UFE) treats the flame as an ensemble of locally one-dimensional flames. A set of elemental one dimensional flames is used to describe the turbulent flame structure at the subgrid level. The stretched flame calculations are performed on the stagnation line of a strained flame using the unsteady filtered strain rate computed from the resolved- grid. The flame iso-surface is tracked using an accurate high-order level set formulation to propagate the flame interface at the coarse resolution with minimum numerical diffusion. In this paper the solver and the model components are introduced and used to investigate two unsteady flames with different Lewis numbers in the thin reaction zone regime. The results show that the UFE model captures the unsteady flame-turbulence interactions and the flame propagation speed reasonably well. Higher propagation speed is observed for the lower than unity Lewis number flame because of the impact of differential diffusion.

  7. Flame kernel generation and propagation in turbulent partially premixed hydrocarbon jet

    KAUST Repository

    Mansour, Mohy S.

    2014-04-23

    Flame development, propagation, stability, combustion efficiency, pollution formation, and overall system efficiency are affected by the early stage of flame generation defined as flame kernel. Studying the effects of turbulence and chemistry on the flame kernel propagation is the main aim of this work for natural gas (NG) and liquid petroleum gas (LPG). In addition the minimum ignition laser energy (MILE) has been investigated for both fuels. Moreover, the flame stability maps for both fuels are also investigated and analyzed. The flame kernels are generated using Nd:YAG pulsed laser and propagated in a partially premixed turbulent jet. The flow field is measured using 2-D PIV technique. Five cases have been selected for each fuel covering different values of Reynolds number within a range of 6100-14400, at a mean equivalence ratio of 2 and a certain level of partial premixing. The MILE increases by increasing the equivalence ratio. Near stoichiometric the energy density is independent on the jet velocity while in rich conditions it increases by increasing the jet velocity. The stability curves show four distinct regions as lifted, attached, blowout, and a fourth region either an attached flame if ignition occurs near the nozzle or lifted if ignition occurs downstream. LPG flames are more stable than NG flames. This is consistent with the higher values of the laminar flame speed of LPG. The flame kernel propagation speed is affected by both turbulence and chemistry. However, at low turbulence level chemistry effects are more pronounced while at high turbulence level the turbulence becomes dominant. LPG flame kernels propagate faster than those for NG flame. In addition, flame kernel extinguished faster in LPG fuel as compared to NG fuel. The propagation speed is likely to be consistent with the local mean equivalence ratio and its corresponding laminar flame speed. Copyright © Taylor & Francis Group, LLC.

  8. Two-dimensional simulations of steady perforated-plate stabilized premixed flames

    KAUST Repository

    Altay, H. Murat

    2010-03-17

    The objective of this work is to examine the impact of the operating conditions and the perforated-plate design on the steady, lean premixed flame characteristics. We perform two-dimensional simulations of laminar flames using a reduced chemical kinetics mechanism for methane-air combustion, consisting of 20 species and 79 reactions. We solve the heat conduction problem within the plate, allowing heat exchange between the gas mixture and the solid plate. The physical model is based on a zero-Mach-number formulation of the axisymmetric compressible conservation equations. The results suggest that the flame consumption speed, the flame structure, and the flame surface area depend significantly on the equivalence ratio, mean inlet velocity, the distance between the perforated-plate holes and the plate thermal conductivity. In the case of an adiabatic plate, a conical flame is formed, anchored near the corner of the hole. When the heat exchange between themixture and the plate is finite, the flame acquires a Gaussian shape stabilizing at a stand-off distance, that grows with the plate conductivity. The flame tip is negatively curved; i.e. concave with respect to the reactants. Downstream of the plate, the flame base is positively curved; i.e. convex with respect to the reactants, stabilizing above a stagnation region established between neighboring holes. As the plate\\'s thermal conductivity increases, the heat flux to the plate decreases, lowering its top surface temperature. As the equivalence ratio increases, the flame moves closer to the plate, raising its temperature, and lowering the flame stand-off distance. As the mean inlet velocity increases, the flame stabilizes further downstream, the flame tip becomes sharper, hence raising the burning rate at that location. The curvature of the flame base depends on the distance between the neighboring holes; and the flame there is characterized by high concentration of intermediates, like carbon monoxide. © 2010 Taylor

  9. Effects of Buoyancy on Laminar and Turbulent Premixed V-Flame

    Science.gov (United States)

    Cheng, Robert K.; Bedat, Benoit

    1997-01-01

    Turbulent combustion occurs naturally in almost all combustion systems and involves complex dynamic coupling of chemical and fluid mechanical processes. It is considered as one of the most challenging combustion research problems today. Though buoyancy has little effect on power generating systems operating under high pressures (e.g., IC engines and turbines), flames in atmospheric burners and the operation of small to medium furnaces and boilers are profoundly affected by buoyancy. Changes in burner orientation impacts on their blow-off, flash-back and extinction limits, and their range of operation, burning rate, heat transfer, and emissions. Theoretically, buoyancy is often neglected in turbulent combustion models. Yet the modeling results are routinely compared with experiments of open laboratory flames that are obviously affected by buoyancy. This inconsistency is an obstacle to reconciling experiments and theories. Consequently, a fundamental understanding of the coupling between turbulent flames and buoyancy is significant to both turbulent combustion science and applications. The overall effect of buoyancy relates to the dynamic interaction between the flame and its surrounding, i.e., the so-called elliptical problem. The overall flame shape, its flowfield, stability, and mean and local burning rates are dictated by both upstream and downstream boundary conditions. In steady propagating premixed flames, buoyancy affects the products region downstream of the flame zone. These effects are manifested upstream through the mean and fluctuating pressure fields to influence flame stretch and flame wrinkling. Intuitively, the effects buoyancy should diminish with increasing flow momentum. This is the justification for excluding buoyancy in turbulent combustion models that treats high Reynolds number flows. The objectives of our experimental research program is to elucidate flame-buoyancy coupling processes in laminar and turbulent premixed flames, and to

  10. Flame retardancy and ultraviolet resistance of silk fabric coated by graphene oxide

    Directory of Open Access Journals (Sweden)

    Ji Yi-Min

    2017-01-01

    Full Text Available Silk fabrics were coated by graphene oxide hydrosol in order to improve its flame retardancy and ultraviolet resistance. In addition, montmorillonoid was doped into the graphene oxide hydrosol to further improve the flame retardancy of silk fabrics. The flame retardancy and ultraviolet resistance were mainly characterized by limiting oxygen index, vertical flame test, smoke density test, and ultraviolet protection factor. The synergistic effect of graphene oxide and montmorillonoid on the thermal stabilization property of the treated silk fabrics was also investigated. The results show that the treated silk fabrics have excellent flame retardancy, thermal stability, smoke suppression, and ultraviolet resistance simultaneously.

  11. Modelling of flame temperature of solution combustion synthesis of ...

    Indian Academy of Sciences (India)

    Hydroxyapatite (HAp), an important bio-ceramic was successfully synthesized by combustion in the aqueous system containing calcium nitrate-di-ammonium hydrogen orthophosphate-urea. The combustion flame temperature of solution combustion reaction depends on various process parameters, and it plays a significant ...

  12. The Effect of Gravity on Flame Spread over PMMA Cylinders.

    Science.gov (United States)

    Link, Shmuel; Huang, Xinyan; Fernandez-Pello, Carlos; Olson, Sandra; Ferkul, Paul

    2018-01-09

    Fire safety is a concern in space travel, particularly with the current plans of increasing the length of the manned space missions, and of using spacecraft atmospheres different than in Earth, such as microgravity, low-velocity gas flow, low pressure and elevated oxygen concentration. In this work, the spread of flame over a thermoplastic polymer, polymethyl methacrylate (PMMA), was conducted in the International Space Station and on Earth. The tests consisted of determining the opposed flame spread rate over PMMA cylinders under low-flow velocities ranging from 0.4 to 8 cm/s and oxygen concentrations from 15% to 21%. The data show that as the opposed flow velocity is increased, the flame spread rate first increases, and then decreases, different from that on Earth. The unique data are significant because they have only been predicted theoretically but not been observed experimentally before. Results also show that flame spread in microgravity could be faster and sustained at lower oxygen concentration (17%) than in normal gravity (18%). These findings suggest that under certain environmental conditions there could be a higher fire risk and a more difficult fire suppression in microgravity than on Earth, which would have significant implications for spacecraft fire safety.

  13. Regularization modeling for large-eddy simulation of diffusion flames

    NARCIS (Netherlands)

    Geurts, Bernardus J.; Wesseling, P.; Oñate, E.; Périaux, J.

    We analyze the evolution of a diffusion flame in a turbulent mixing layer using large-eddy simulation. The large-eddy simulation includes Leray regularization of the convective transport and approximate inverse filtering to represent the chemical source terms. The Leray model is compared to the more

  14. MECHANISMS OF NITROUS OXIDE FORMATION IN COAL FLAMES

    Science.gov (United States)

    The paper gives results of a study, using both detailed kinetic modeling and plug-flow simulator experiments, to investigate an unknown mechanism by which N2O is formed in coal flames. This mechanism has considerable importance in determining the influence of common and advanced ...

  15. 30 CFR 7.26 - Flame test apparatus.

    Science.gov (United States)

    2010-07-01

    ... MINING PRODUCTS TESTING BY APPLICANT OR THIRD PARTY Brattice Cloth and Ventilation Tubing § 7.26 Flame... cloth and ventilation tubing shall be constructed as follows: (a) A 16-gauge stainless steel gallery... folds or wrinkles; (c) A tapered 16-gauge stainless steel duct section tapering from a cross sectional...

  16. Deposition of flame-made nanoparticles on porous media

    DEFF Research Database (Denmark)

    Elmøe, Tobias Dokkedal

    2008-01-01

    Deposition of flame-made nanoparticles on porous media Nanopartikler i porøse keramiske materialer har en lang række anvendelsesmuligheder, som f.eks. gas-sensorer, katalysatorer, brændselscelle anoder samt dieselsodfiltre. En hurtig metode til dannelsen af disse er ved direkte deponering. Her...

  17. Demonstrating Sound Wave Propagation with Candle Flame and Loudspeaker

    Science.gov (United States)

    Hrepic, Zdeslav; Nettles, Corey; Bonilla, Chelsea

    2013-01-01

    The motion of a candle flame in front of a loudspeaker has been suggested as a productive demonstration of the longitudinal wave nature of sound. The demonstration has been used also as a research tool to investigate students' understanding about sound. The underpinning of both applications is the expectation of a horizontal, back-and-forth…

  18. Measurement and Modeling of Particle Radiation in Coal Flames

    DEFF Research Database (Denmark)

    Bäckström, Daniel; Johansson, Robert; Andersson, Klas Jerker

    2014-01-01

    flame. Spectral radiation, total radiative intensity, gas temperature, and gas composition were measured, and the radiative intensity in the furnace was modeled with an axisymmetric cylindrical radiation model using Mie theory for the particle properties and a statistical narrow-band model for the gas...

  19. Green Flame Retardant Cotton Highlofts for Mattresses and Upholstered Furniture

    Science.gov (United States)

    Green flame retardant (FR) barrier fabric is environmentally-friendly because it is from a natural renewable resource, biodegradable, economical, employing greige cotton that is soft to touch. Greige unbleached cotton is cheaper and softer than bleached cotton, thus, increasing its marketability par...

  20. Flame generation of sodium chloride aerosol for filter testing

    International Nuclear Information System (INIS)

    Edwards, J.; Kinnear, D.I.

    1975-01-01

    A generator for sodium chloride aerosol is described, which when used in conjunction with a sensitive portable sodium flame detector unit, will permit the in-place testing of large filter installations having air throughputs up to about 80,000 m 3 /h, at penetrations down to at least 0.005 percent. (U.S.)