WorldWideScience

Sample records for corrosion performance evaluation

  1. Performance evaluation of corrosion-affected reinforced concrete ...

    Indian Academy of Sciences (India)

    M B Anoop

    Abstract. A methodology for performance evaluation of reinforced concrete bridge girders in corrosive ... concrete (RC) members of infrastructural systems, espe- ... bility will be useful for making engineering decisions for ...... Water-cement ratio.

  2. Evaluation of corrosion on the fuel performance of stainless steel cladding

    Directory of Open Access Journals (Sweden)

    de Souza Gomes Daniel

    2016-01-01

    Full Text Available In nuclear reactors, the use of stainless steel (SS as the cladding material offers some advantages such as good mechanical and corrosion resistance. However, its main advantage is the reduction in the amount of the hydrogen released during loss-of-coolant accident, as observed in the Fukushima Daiichi accident. Hence, research aimed at developing accident tolerant fuels should consider SS as an important alternative to existing materials. However, the available computational tools used to analyze fuel rod performance under irradiation are not capable of assessing the effectiveness of SS as the cladding material. This paper addresses the SS corrosion behavior in a modified fuel performance code in order to evaluate its effect on the global fuel performance. Then, data from the literature concerning to SS corrosion are implemented in the specific code subroutines, and the results obtained are compared to those for Zircaloy-4 (Zy-4 under the same power history. The results show that the effects of corrosion on SS are considerably different from those on Zy-4. The thickness of the oxide layer formed on the SS surface is considerably lower than that formed on Zy-4. As a consequence of this, the global fuel performance of SS under irradiation should be less affected by the corrosion.

  3. Electrochemical techniques for practical evaluation of corrosion inhibitor effectiveness. Performance of cerium nitrate as corrosion inhibitor for AA2024T3 alloy

    International Nuclear Information System (INIS)

    Rosero-Navarro, N.C.; Curioni, M.; Bingham, R.; Duran, A.; Aparicio, M.; Cottis, R.A.; Thompson, G.E.

    2010-01-01

    In this work, a split-cell technique and image-assisted electrochemical noise analysis, which provide minimal perturbation of the freely corroding system and good time resolution, are proposed as a tool for simultaneous investigation of the corrosion inhibition mechanism and assessment of performance. The results obtained are compared with results from traditional electrochemical impedance spectroscopy, disclosing the advantages of these techniques in the evaluation of inhibitor performance. Specific attention is also given to the investigation of corrosion inhibition by cerium nitrate.

  4. Evaluation of corrosive behavior of SAE 5155 by corrosion environment

    International Nuclear Information System (INIS)

    An, Jae Pil; Park, Keyung Dong

    2005-01-01

    In this study, the influence of shot peening and corrosive condition for corrosion property was investigated on immersed in 3.5% NaCl, 10% HNO 3 + 3% HF, 6% FeCl 3 . The immersion test was performed on two kinds of specimen. The immersion periods was performed 30days. Corrosion potential, weight loss were investigated from experimental results. From test results, the effect of shot peening on the corrosion was evaluated

  5. Performance evaluation of corrosion probes in simulated WVNS tank 8D-2 waste: WVNS tank farm process support

    International Nuclear Information System (INIS)

    Elmore, M.R.

    1994-07-01

    Five corrosion probes were received from West Valley Nuclear Services for evaluation in simulated tank 8D-2 3rd-stage sludge wash slurry. The same waste slurry simulated was also used in a series of ongoing corrosion studies assessing the effects of in-tank sludge washing on the integrity of tank 8D-2. Two of the corrosion probes were installed in the coupon corrosion test vessels operating at ∼150 degrees F to compare performance of the probes with that observed by coupon tests conducted in the same vessels. Corrosion rate data calculated from electrical resistance measurements of the corrosion probes were evaluated for this study using two slightly different approaches. One approach uses the total length of exposure of the probe to give a ''time-averaged'' value of the corrosion rate. The other approach uses a shorter period of time (relative to the length of the test) in the calculation of corrosion rate, and is referred to as the ''instantaneous'' rate. The interpretation of the probe data and the implications of corrosion rates calculated with either of these methods are discussed in this report

  6. Corrosion evaluation technology

    International Nuclear Information System (INIS)

    Kim, Uh Chul; Han, Jeong Ho; Nho, Kye Ho; Lee, Eun Hee; Kim, Hong Pyo; Hwang, Seong Sik; Lee, Deok Hyun; Hur, Do Haeng; Kim, Kyung Mo.

    1997-09-01

    A multifrequency ACPD system was assembled which can measure very small crack. Stress corrosion cracking test system with SSRT operating high temperature was installed. Stress corrosion cracking test of newly developed alloy 600 and existing alloy 600 was carried out in steam atmosphere of 400 deg C. No crack was observed in both materials within a test period of 2,000 hrs. Corrosion fatigue test system operating at high temperature was installed in which fatigue crack was measured by CDPD. Lead enhanced the SCC of the Alloy 600 in high temperature water, had a tendency to modify a cracking morphology from intergranular to transgranular. Pit initiation preferentially occurred at Ti-rich carbide. Resistance to pit initiation decreased with increasing temperature up to 300 deg C. Test loop for erosion corrosion was designed and fabricated. Thin layer activation technique was very effective in measuring erosion corrosion. Erosion corrosion of a part of secondary side pipe was evaluated by the Check Family Codes of EPRI. Calculated values of pipe thickness by Check Family Codes coincided with the pipe thickness measured by UT with an error of ± 20%. Literature review on turbine failure showed that failure usually occurred in low pressure turbine rotor disc and causes of failure are stress corrosion cracking and corrosion fatigue. (author). 12 refs., 20 tabs., 77 figs

  7. Tests with Inconel 600 to obtain quantitative stress-corrosion cracking data for evaluating service performance

    International Nuclear Information System (INIS)

    Bandy, R.; van Rooyen, D.

    1982-09-01

    Inconel 600 tubes in pressurized water reactor (PWR) steam generators form a pressure boundary between radioactive primary water and secondary water which is converted to steam and used for generating electricity. Under operating conditions the performance of alloy 600 has been good, but with some occasional small leaks resulting from stress corrosion cracking (SCC), related to the presence of unusually high residual or operating stresses. The suspected high stresses can result from either the deformation of tubes during manufacture, or distortion during abnormal conditions such as denting. The present experimental program addresses two specific conditions, i.e., (1) where deformation occurs but is no longer active, such as when denting is stopped and (2) where plastic deformation of the metal continues, as would occur during denting. Laboratory media consist of pure water as well as solutions to simulate environments that would apply in service; tubing from actual production is used in carrying out these tests. The environments include both normal and off chemistries for primary and secondary water. The results reported here were obtained in several different tests. The main ones are (1) split tube reverse U-bends, (2) constant extension rate tests (CERT), and (3) constant load. The temperature range covered is 290 to 365 0 C

  8. Evaluation of steel corrosion by numerical analysis

    OpenAIRE

    Kawahigashi, Tatsuo

    2017-01-01

    Recently, various non-destructive and numerical methods have been used and many cases of steel corrosion are examined. For example, methods of evaluating corrosion through various numerical methods and evaluating macrocell corrosion and micro-cell corrosion using measurements have been proposed. However, there are few reports on estimating of corrosion loss with distinguishing the macro-cell and micro-cell corrosion and with resembling an actuality phenomenon. In this study, for distinguishin...

  9. Seismic load resistance of reinforcing steels in the as delivered condition and after corrosion - relevant material characteristics for performance evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Moersch, Ing. Joerg [Max Aicher Engineering GmbH, Freilassing (Germany)

    2016-10-15

    This type of accelerated corrosion test was used to study the high number of test samples in due time. The corrosion phenomena obtained in salt spray testing deviate significantly from corrosion phenomena (pitting factor) obtained in practical conditions. Salt spray testing represents practical conditions for the more uniform corrosion as a result of a severe carbonation of the concrete and/or for higher chloride contents at the surface of the rebar. At low corrosion current densities the effect of pit depth on residual mechanical performance might be underestimated. Reinforced concrete (r.c.) buildings in seismic areas shall be designed to guarantee enough ductile resources as for example a sufficient rotational capacity to allow for load re-distribution. The rotational capacity is directly dependent on the ductility of the reinforcing steel which is generally expressed as elongation at maximum load (A+g{sub t}) and the hardening ratio (R{sub m}/R{sub e}). A direct testing of the seismic load resistance of reinforcing steels is not part of the construction product standards. Therefore it was decided by European Commission to introduce this performance requirement in the mandate for the revision of EN 10080:2005. In parallel to the standardization process a research project was carried out to deliver the scientific background.

  10. Corrosion Evaluation and Corrosion Control of Steam Generators

    International Nuclear Information System (INIS)

    Maeng, W. Y.; Kim, U. C.; Sung, K. W.; Na, J. W.; Lee, Y. H.; Lee, D. H.; Kim, K. M.

    2008-06-01

    Corrosion damage significantly influences the integrity and efficiency of steam generator. Corrosion problems of steam generator are unsolved issues until now even though much effort is made around world. Especially the stress corrosion cracking of heat exchange materials is the first issue to be solved. The corrosion protection method of steam generator is important and urgent for the guarantee of nuclear plant's integrity. The objectives of this study are 1) to evaluate the corrosion properties of steam generator materials, 2) to optimize the water chemistry of steam generator and 3) to develop the corrosion protection method of primary and secondary sides of steam generator. The results will be reflected to the water chemistry guideline for improving the integrity and efficiency of steam generator in domestic power plants

  11. Corrosion Evaluation and Corrosion Control of Steam Generators

    Energy Technology Data Exchange (ETDEWEB)

    Maeng, W. Y.; Kim, U. C.; Sung, K. W.; Na, J. W.; Lee, Y. H.; Lee, D. H.; Kim, K. M

    2008-06-15

    Corrosion damage significantly influences the integrity and efficiency of steam generator. Corrosion problems of steam generator are unsolved issues until now even though much effort is made around world. Especially the stress corrosion cracking of heat exchange materials is the first issue to be solved. The corrosion protection method of steam generator is important and urgent for the guarantee of nuclear plant's integrity. The objectives of this study are 1) to evaluate the corrosion properties of steam generator materials, 2) to optimize the water chemistry of steam generator and 3) to develop the corrosion protection method of primary and secondary sides of steam generator. The results will be reflected to the water chemistry guideline for improving the integrity and efficiency of steam generator in domestic power plants.

  12. Corrosion evaluation of service water system materials

    International Nuclear Information System (INIS)

    Stein, A.A.; Felder, C.M.; Martin, R.L.

    1994-01-01

    The availability and reliability of the service water system is critical for safe operation of a nuclear power plant. Degradation of the system piping and components has forced utilities to re-evaluate the corrosion behavior of current and alternative system materials, to support assessments of the remaining service life of the service water system, selection of replacement materials, implementation of corrosion protection methods and corrosion monitoring programs, and identification of maintenance and operational constraints consistent with the materials used. TU Electric and Stone and Webster developed a service water materials evaluation program for the Comanche Peak Steam Electric Station. Because of the length of exposure and the generic interest in this program by the nuclear power industry, EPRI joined TU to co-sponsor the test program. The program was designed to evaluate the corrosion behavior of current system materials and candidate replacement materials and to determine the operational and design changes which could improve the corrosion performance of the system. Although the test program was designed to be representative of service water system materials and environments targeted to conditions at Comanche Peak, these conditions are typical of and relevant to other fresh water cooled nuclear service water systems. Testing was performed in raw water and water treated with biocide under typical service water operating conditions including continuous flow, intermittent flow, and stagnant conditions. The test program evaluated the 300 Series and 6% molybdenum stainless steels, copper-nickel, titanium, carbon steel, and a formed-in-place nonmetallic pipe lining to determine susceptibility to general, crevice, and microbiologically influenced corrosion and pitting attack. This report presents the results of the test program after 4 years of exposure

  13. The SKB spent fuel corrosion programme. An evaluation of results from the experimental programme performed in the Studsvik Hot Cell Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Forsyth, R. [Forsyth Consulting, Nykoeping (Sweden)

    1997-12-01

    During the last few years, many of the specimens in the SKB programme on the corrosion of spent fuel have been analysed by the ICP-MS technique, shortly after conclusion of the corrosion tests, or by the analysis of archive samples. Together with the previous results, this has made available a much more extended analytical data base than that available before, and this has been used in a new evaluation which complements those published earlier. Some of the new analytical data is for tests performed on fuel specimens (from two reference fuel rods, one BWR and one PWR) which have been corrosion tested for over ten years. Most of the data refers to 16 fuel/clad specimens from a short BWR fuel rod, which had burnups over a range of 27.0 to 48.8 MWd/kg U. Detailed examination and characterisation of three other fuel specimens from the rod had shown that the specimens with the higher burnups in this series would have a fuel microstructure and alpha activity content and distribution which, theoretically, may promote enhanced corrosion. These specimens had been exposed to over 5 years of corrosion during nine water contact periods. The corrodants used were a simulated bicarbonate groundwater and de-ionised water, and both oxic and nominally anoxic conditions were included in the test matrix. Most of the emphasis in the evaluation has, therefore, been on the possible effects on corrosion behaviour of the linear heat rating and burnup of the fuels. However, examination of the variation with water contact time of the fractional release rates of selected fission products and their total release over the five years of corrosion, have shown that the corrosion rates during the first few weeks of corrosion of the specimens with the higher burnups were lower than those for specimens with slightly lower burnup. Later, the corrosion rates converged for all specimens. This has been interpreted to be due to burnup-related differences in the fuel microstructure, particularly in the

  14. Predicting the Performance of Organic Corrosion Inhibitors

    Directory of Open Access Journals (Sweden)

    David A. Winkler

    2017-12-01

    Full Text Available The withdrawal of effective but toxic corrosion inhibitors has provided an impetus for the discovery of new, benign organic compounds to fill that role. Concurrently, developments in the high-throughput synthesis of organic compounds, the establishment of large libraries of available chemicals, accelerated corrosion inhibition testing technologies, and the increased capability of machine learning methods have made discovery of new corrosion inhibitors much faster and cheaper than it used to be. We summarize these technical developments in the corrosion inhibition field and describe how data-driven machine learning methods can generate models linking molecular properties to corrosion inhibition that can be used to predict the performance of materials not yet synthesized or tested. We briefly summarize the literature on quantitative structure–property relationships models of small organic molecule corrosion inhibitors. The success of these models provides a paradigm for rapid discovery of novel, effective corrosion inhibitors for a range of metals and alloys in diverse environments.

  15. The corrosion and corrosion mechanical properties evaluation for the LBB concept in VVERs

    Energy Technology Data Exchange (ETDEWEB)

    Ruscak, M.; Chvatal, P.; Karnik, D.

    1997-04-01

    One of the conditions required for Leak Before Break application is the verification that the influence of corrosion environment on the material of the component can be neglected. Both the general corrosion and/or the initiation and, growth of corrosion-mechanical cracks must not cause the degradation. The primary piping in the VVER nuclear power plant is made from austenitic steels (VVER 440) and low alloy steels protected with the austenitic cladding (VVER 1000). Inspection of the base metal and heterogeneous weldments from the VVER 440 showed that the crack growth rates are below 10 m/s if a low oxygen level is kept in the primary environment. No intergranular cracking was observed in low and high oxygen water after any type of testing, with constant or periodic loading. In the framework of the LBB assessment of the VVER 1000, the corrosion and corrosion mechanical properties were also evaluated. The corrosion and corrosion mechanical testing was oriented predominantly to three types of tests: stress corrosion cracking tests corrosion fatigue tests evaluation of the resistance against corrosion damage. In this paper, the methods used for these tests are described and the materials are compared from the point of view of response on static and periodic mechanical stress on the low alloyed steel 10GN2WA and weld metal exposed in the primary circuit environment. The slow strain rate tests and static loading of both C-rings and CT specimens were performed in order to assess the stress corrosion cracking characteristics. Cyclic loading of CT specimens was done to evaluate the kinetics of the crack growth under periodical loading. Results are shown to illustrate the approaches used. The data obtained were evaluated also from the point of view of comparison of the influence of different structure on the stress corrosion cracking appearance. The results obtained for the base metal and weld metal of the piping are presented here.

  16. Evaluation of the mechanical and corrosion protection performance of electrodeposited hydroxyapatite on the high energy electron beam treated titanium alloy

    International Nuclear Information System (INIS)

    Gopi, D.; Sherif, El-Sayed M.; Rajeswari, D.; Kavitha, L.; Pramod, R.; Dwivedi, Jishnu; Polaki, S.R.

    2014-01-01

    Graphical abstract: - Highlights: • Ti–6Al–4V alloy was surface treated by high energy low current DC electron beam. • Successful electrodeposition of HAP was achieved on surface treated Ti–6Al–4V. • The as-formed coating possessed improved surface wettability and adhesion strength. • Maximum corrosion protection performance was exhibited by the as-formed coating. - Abstract: In our present study, the Ti–6Al–4V alloy surface was modified by irradiating with the high energy low current DC electron beam (HELCDEB) using 700 keV DC accelerator. Following this, the HELCDEB treated surface was coated with hydroxyapatite by adopting electrodeposition method. The microstructure and hardness of HELCDEB treated Ti–6A1–4V alloy with and without electrodeposited hydroxyapatite were investigated. Also, the electrochemical corrosion characteristics of the samples in simulated body fluid (SBF) was studied by potentiodynamic polarisation and electrochemical impedence techniques (EIS) which showed an enhanced corrosion resistance and revealed an improved life time for the hydroxyapatite coating developed on the HELCDEB treated Ti–6A1–4V alloy than the untreated sample

  17. Structural performance evaluation on aging underground reinforced concrete structures. Part 6. An estimation method of threshold value in performance verification taking reinforcing steel corrosion

    International Nuclear Information System (INIS)

    Matsuo, Toyofumi; Matsumura, Takuro; Miyagawa, Yoshinori

    2009-01-01

    This paper discusses applicability of material degradation model due to reinforcing steel corrosion for RC box-culverts with corroded reinforcement and an estimation method for threshold value in performance verification reflecting reinforcing steel corrosion. First, in FEM analyses, loss of reinforcement section area and initial tension strain arising from reinforcing steel corrosion, and deteriorated bond characteristics between reinforcement and concrete were considered. The full-scale loading tests using corroded RC box-culverts were numerically analyzed. As a result, the analyzed crack patterns and load-strain relationships were in close agreement with the experimental results within the maximum corrosion ratio 15% of primary reinforcement. Then, we showed that this modeling could estimate the load carrying capacity of corroded RC box-culverts. Second, a parametric study was carried out for corroded RC box culverts with various sizes, reinforcement ratios and levels of steel corrosion, etc. Furthermore, as an application of analytical results and various experimental investigations, we suggested allowable degradation ratios for a modification of the threshold value, which corresponds to the chloride induced deterioration progress that is widely accepted in maintenance practice for civil engineering reinforced concrete structures. Finally, based on these findings, we developed two estimation methods for threshold value in performance verification: 1) a structural analysis method using nonlinear FEM included modeling of material degradation, 2) a practical method using a threshold value, which is determined by structural analyses of RC box-culverts in sound condition, is multiplied by the allowable degradation ratio. (author)

  18. Corrosion Monitors for Embedded Evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Robinson, Alex L. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Pfeifer, Kent B. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Casias, Adrian L. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Howell, Stephen W. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Sorensen, Neil R. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Missert, Nancy A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-05-01

    We have developed and characterized novel in-situ corrosion sensors to monitor and quantify the corrosive potential and history of localized environments. Embedded corrosion sensors can provide information to aid health assessments of internal electrical components including connectors, microelectronics, wires, and other susceptible parts. When combined with other data (e.g. temperature and humidity), theory, and computational simulation, the reliability of monitored systems can be predicted with higher fidelity.

  19. Effect of Wall Shear Stress on Corrosion Inhibitor Film Performance

    Science.gov (United States)

    Canto Maya, Christian M.

    films. Different scenarios were evaluated in this section of the work, such as the loss of corrosion inhibitor due to the formation of foam, and the effect of different substrates on the adsorption of corrosion inhibitor. Erosion/corrosion effects due to solids carried by a multiphase flow were investigated both on a small and large scale. Small scale experiments were performed in order to determine whether the corrosion inhibitor concentration was diminished because of adsorption onto the large surface area of entrained solid particles. The large scale experiments were done to evaluate the effect of mechanical erosion corrosion on inhibitor film performance, and vice versa. The analysis of the results obtained by electrochemical characterization shows that the adsorption mechanism having a corrosion inhibitor competing with water molecules for a place on the steel surface is an accurate approach to describe this phenomenon. From the experimental results obtained in the multiphase part of this research project, it can be concluded that the performance of corrosion inhibitor films is not significantly impacted by mechanical forces alone; even under the worst case scenarios tested here (standing slug and erosion/corrosion). Reduction of inhibitor performance was found to be primarily due to the loss of inhibitor due to consumption by adsorption particularly when a gas phase was present, leading to foam formation.

  20. Plant corrosion: prediction of materials performance

    International Nuclear Information System (INIS)

    Strutt, J.E.; Nicholls, J.R.

    1987-01-01

    Seventeen papers have been compiled forming a book on computer-based approaches to corrosion prediction in a wide range of industrial sectors, including the chemical, petrochemical and power generation industries. Two papers have been selected and indexed separately. The first describes a system operating within BNFL's Reprocessing Division to predict materials performance in corrosive conditions to aid future plant design. The second describes the truncation of the distribution function of pit depths during high temperature oxidation of a 20Cr austenitic steel in the fuel cladding in AGR systems. (U.K.)

  1. Corrosive wear. Evaluation of wear and corrosive resistant materials; Noetningskorrosion. Utvaerdering av noetnings- och korrosionsbestaendiga material

    Energy Technology Data Exchange (ETDEWEB)

    Persson, H.; Hjertsen, D.; Waara, P.; Prakash, B.; Hardell, J.

    2007-12-15

    With a new purchase of a waste conveyer screw at hand, for the 'A-warehouse' at the combined power and heating plant at E.ON Norrkoeping, the request for improved construction materials was raised. The previous screw required maintenance with very short intervals due to the difficult operation conditions. With the new screw the expectation is to manage 6 months of operation without interruption. The environment for the screw has two main components that sets the demand on the materials, on one hand the corrosive products that comes along and which forms at digestion of the waste and on the other hand the abrasive content in the waste. The term of the mechanism is wear-corrosion and can give considerably higher material loss than the two mechanisms wear and corrosion separately. Combination of a strong corrosive environment together with extensive wear is something that we today have limited knowledge about. The overall objective of the project has been to establish better wear and corrosive resistant construction materials for a waste conveyer screw that will lead to reduced operational disturbance costs. The evaluation has been performed in both controlled laboratory environments and in field tests, which has given us a better understanding of what materials are more suitable in this tough environment and has given us a tool for future predictions of the wear rate of the different material. The new conveyer screw, installed in February 2007 and with which the field test have been performed, has considerably reduced the wear of the construction and the target of 6 month maintenance-free operation is met with this screw for all the evaluated materials. The wear along the screw varies very much and with a clear trend for all the materials to increase towards the feeding direction of the screw. As an example, the wear plate SS2377 (stainless duplex steel) has a useful life at the most affected areas that is calculated to be 1077 days of operation with the

  2. Evaluation of seawater corrosion of SSCs

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-08-15

    In the unit 1 to unit 4 of the Fukushima Daiichi Nuclear Power Plant, seawater was injected in reactor pressure vessels and spent fuel pools in order to cool nuclear fuel after the disaster of the 2011 off the Pacific coast of Tohoku Earthquake and Tsunami. In fiscal 2012, overall plan of this project has been developed in consideration of corrosion events that might be assumed reactor pressure vessels, spent fuel pools and primary containment vessels of Fukushima Daiichi Nuclear Power Station that was designated to be as the 'Specified Nuclear Power Facilities'. In this project, crevice corrosion susceptibility of stainless steel, galvanic corrosion of aluminum alloy, and uniform corrosion of carbon steel piping will be evaluated. (author)

  3. Performance of HVOF carbide coatings under erosion/corrosion

    International Nuclear Information System (INIS)

    Simard, S.; Arsenault, B.; Legoux, J.G.; Hawthorne, H.M.

    1999-01-01

    Cermet based materials are known to have an excellent performance under several wear conditions. High velocity oxy-fuel (HVOF) technology allows the deposition of such hard materials in the form of protective coatings onto different surfaces. Under slurry erosion, the performance of the coatings is influenced by the occurrence of corrosion reactions on the metallic matrix. Indeed, wet conditions promote the dissolution of metallic binder resulting in a potential synergic effect between the corrosion and wear mechanisms. The composition of the metallic matrix plays a key role on the stability of the coatings and their degradation rate. In this work, four coatings based on tungsten carbide embedded in different metallic binders were evaluated with regard to corrosion and wear. (author)

  4. Corrosion allowances for sodium heated steam generators: evaluation of effects and extrapolation to component life time

    Energy Technology Data Exchange (ETDEWEB)

    Grosser, E E; Menken, G

    1975-07-01

    Steam generator tubes are subjected to two categories of corrosion; metal/sodium reactions and metal/water-steam interactions. Referring to these environmental conditions the relevant parameters are discussed. The influences of these parameters on the sodium corrosion and water/steam-reactions are evaluated. Extrapolations of corrosion values to steam generator design conditions are performed and discussed in detail. (author)

  5. Corrosion allowances for sodium heated steam generators: evaluation of effects and extrapolation to component life time

    International Nuclear Information System (INIS)

    Grosser, E.E.; Menken, G.

    1975-01-01

    Steam generator tubes are subjected to two categories of corrosion; metal/sodium reactions and metal/water-steam interactions. Referring to these environmental conditions the relevant parameters are discussed. The influences of these parameters on the sodium corrosion and water/steam-reactions are evaluated. Extrapolations of corrosion values to steam generator design conditions are performed and discussed in detail. (author)

  6. Wear and corrosion performance of metallurgical coatings in sodium

    International Nuclear Information System (INIS)

    Johnson, R.N.; Farwick, D.G.

    1980-01-01

    The friction, wear, and corrosion performance of several metallurgical coatings in 200 to 650 0 C sodium are reviewed. Emphasis is placed on those coatings which have successfully passed the qualification tests necessary for acceptance in breeder reactor environments. Tests include friction, wear, corrosion, thermal cycling, self-welding, and irradiation exposure under as-prototypic-as-possible service conditions. Materials tested were coatings of various refractory metal carbides in metallic binders, nickel-base and cobalt-base alloys and intermetallic compounds such as the aluminides and borides. Coating processes evaluated included plasma spray, detonation gun, sputtering, spark-deposition, and solid-state diffusion

  7. Corrosion performance tests for reinforcing steel in concrete : technical report.

    Science.gov (United States)

    2009-10-01

    The existing test method used to assess the corrosion performance of reinforcing steel embedded in : concrete, mainly ASTM G 109, is labor intensive, time consuming, slow to provide comparative results, : and can be expensive. However, with corrosion...

  8. Corrosion performance tests for reinforcing steel in concrete : test procedures.

    Science.gov (United States)

    2009-09-01

    The existing test method to assess the corrosion performance of reinforcing steel embedded in concrete, mainly : ASTM G109, is labor intensive, time consuming, slow to provide comparative results, and often expensive. : However, corrosion of reinforc...

  9. Evaluation of properties of low activation Mn-Cr steel. 3. Evaluation of corrosion resistance

    Energy Technology Data Exchange (ETDEWEB)

    Saito, Shigeru [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Fukaya, Kiyoshi [Nihon Advanced Technology Co., Ltd., Tokai, Ibaraki (Japan); Ishiyama, Shintaro [Japan Atomic Energy Research Inst., Oarai, Ibaraki (Japan). Oarai Research Establishment; Sato, Ikuo; Kusuhashi, Mikio; Hatakeyama, Takeshi [Japan Steel Works Ltd., Muroran, Hokkaido (Japan). Muroran Plant; Takahashi, Heishichiro [Hokkaido Univ., Sapporo, Hokkaido (Japan); Kikuchi, Mitsuru [Japan Atomic Energy Research Inst., Naka, Ibaraki (Japan). Naka Fusion Research Establishment

    2002-05-01

    JAERI and the Japan Steel Works LTD. (JSW) have developed new Mn-Cr steels as low induced activation material. Until now, chemical composition and metallurgical processes were optimized and some steels named VC-series were selected. The properties of the steels have been evaluated and reported elsewhere. In this study, corrosion resistance of VC-series was studied. Corrosion tests for stainless steels were performed to investigate a relationship between corrosion rate and chemical composition or sensitization. Furthermore, corrosion tests under actual environment for the vacuum vessel of the reinforced JT-60 were done for non-magnetic steels. As a result, almost no weight change was observed for uniform and gap corrosion tests, No crack was shown for double U-bend corrosion tests. (author)

  10. Corrosion Performance of Inconel 625 in High Sulphate Content

    Science.gov (United States)

    Ismail, Azzura

    2016-05-01

    Inconel 625 (UNS N06625) is a type of nickel-chromium-molybdenum alloy with excellent corrosion resistance in a wide range of corrosive media, being especially resistant to pitting and crevice corrosion. However, in aggressive environment, Inconel 625 will suffer corrosion attack like other metals. This research compared the corrosion performance of Inconel 625 when exposed to higher sulphate content compared to real seawater. The results reveal that Inconel 625 is excellent in resist the corrosion attack in seawater. However, at increasing temperature, the corrosion resistance of this metal decrease. The performance is same in seawater with high sulphate content at increasing temperature. It can be concluded that sulphate promote perforation on Inconel 625 and become aggressive agents that accelerate the corrosion attack.

  11. Evaluation of several corrosion protective coating systems on aluminum

    Science.gov (United States)

    Higgins, R. H.

    1981-01-01

    A study of several protective coating systems for use on aluminum in seawater/seacoast environments was conducted to review the developments made on protective coatings since early in the Space Shuttle program and to perform comparative studies on these coatings to determine their effectiveness for providing corrosion protection during exposure to seawater/seacoast environments. Panels of 2219-T87 aluminum were coated with 21 different systems and exposed to a 5 percent salt spray for 4000 hr. Application properties, adhesion measurements, heat resistance and corrosion protection were evaluated. For comparative studies, the presently specified Bostik epoxy system used on the SRB structures was included. Results of these tests indicate four systems with outstanding performance and four additional systems with protection almost as good. These systems are based on a chromated pretreatment, a chromate epoxy primer, and a polyurethane topcoat. Consideration for one of these systems should be included for those applications where superior corrosion protection for aluminum surfaces is required.

  12. Corrosion performance of epoxy-coated reinforcement in aggressive environments

    Science.gov (United States)

    Vaca Cortes, Enrique

    The objective of this research was to investigate the integrity and corrosion performance of epoxy-coated reinforcement in aggressive environments. A series of experimental studies were conducted: (a) hot water immersion and knife adhesion testing for assessment of coating adhesion; (b) materials and procedures for repairing coating damage; (c) degree of mechanical damage caused during concrete placement when using metal head and rubber head vibrators; (d) accelerated corrosion of coated bars embedded in macrocell and beam specimens placed in a corrosive environment for more than four years. The effects of coating condition and amount of damage, repaired vs. unrepaired damage, bar fabrication, and concrete cracking were studied. Regardless of coating condition, the performance of epoxy-coated bars was better than that of uncoated bars. Unlike black bars, coated bars did not exhibit deep pitting or substantial loss of cross section at crack locations. Damage to epoxy coating was the most significant factor affecting corrosion performance. Bars with coating in good condition, without any visible damage, performed best. The greater the size and frequency of damage, the more severe and extensive the amount of corrosion. The performance of bars that were fabricated or bent after coating was worse than that of coated straight bars. Mixing coated and uncoated bars in the same concrete member led to undesirable performance. Patching damaged coating reduced but did not prevent corrosion, particularly at bar ends. The most important factor in coating repair was the type and properties of the patching material. Surface preparation prior to coating had little effect. The absence of cracks in the concrete delayed, but did not prevent the onset of corrosion of coated bars. During consolidation of concrete, rubber head vibrators caused less damage to epoxy-coated reinforcement than did comparable metal heads. Hot water and adhesion tests were useful and practical for evaluating

  13. Analysis of electrochemical noise data in both time and frequency domains to evaluate the effect of ZnO nanopowder addition on the corrosion protection performance of epoxy coatings

    Directory of Open Access Journals (Sweden)

    H. Ashassi-Sorkhabi

    2016-11-01

    Full Text Available Epoxy–ZnO nanocomposite coatings have been developed for corrosion protection of steel. Structural characterization of the prepared nanocomposites was performed using scanning electron microscopy (SEM. The anti-corrosive properties of the coatings were evaluated by electrochemical noise (EN. On the basis of the EN results in both time and frequency domains, the nanocomposite material with low ZnO concentration (0.1% wt.% was found to be much superior in corrosion protection when tested in aqueous NaCl electrolyte. Finally, EIS measurements were carried out and the data fitted with suitable equivalent circuit. Resistance parameters obtained by both techniques were found to be in relatively good agreement.

  14. Energy evaluations, graphite corrosion in Bugey I

    International Nuclear Information System (INIS)

    Brisbois, J.; Fiche, C.

    1967-01-01

    Bugey I presents a problem of radiolytic corrosion of the graphite by the CO 2 under pressure at high temperature. This report aims to evaluate the energy transferred to the gas by a Bugey I core cell, in normal operating conditions. The water, the carbon oxides and the hydrogen formed quantities are deduced as the consumed graphite and methane. Experimental studies are realized in parallel to validate the presented results. (A.L.B.)

  15. Evaluation of Encapsulated Inhibitor for Autonomous Corrosion Protection

    Science.gov (United States)

    Johnsey, M. N.; Li, W.; Buhrow, J. W.; Calle, L. M.; Pearman, B. P.; Zhang, X.

    2015-01-01

    This work concerns the development of smart coating technologies based on microencapsulation for the autonomous control of corrosion. Microencapsulation allows the incorporation of corrosion inhibitors into coating which provides protection through corrosion-controlled release of these inhibitors.One critical aspect of a corrosion protective smart coating is the selection of corrosion inhibitor for encapsulation and comparison of the inhibitor function before and after encapsulation. For this purpose, a systematic approach is being used to evaluate free and encapsulated corrosion inhibitors by salt immersion. Visual, optical microscope, and Scanning Electron Microscope (with low-angle backscatter electron detector) are used to evaluate these inhibitors. It has been found that the combination of different characterization tools provide an effective method for evaluation of early stage localized corrosion and the effectiveness of corrosion inhibitors.

  16. Tank 241-AY-102 Secondary Liner Corrosion Evaluation - 14191

    International Nuclear Information System (INIS)

    Boomer, Kayle D.; Washenfelder, Dennis J.; Johnson, Jeremy M.

    2014-01-01

    In October 2012, Washington River Protection Solutions, LLC (WRPS) determined that the primary tank of 241-AY-102 (AY-102) was leaking. A number of evaluations were performed after discovery of the leak which identified corrosion from storage of waste at the high waste temperatures as one of the major contributing factors in the failure of the tank. The propensity for corrosion of the waste on the annulus floor will be investigated to determine if it is corrosive and must be promptly removed or if it is benign and may remain in the annulus. The chemical composition of waste, the temperature and the character of the steel are important factors in assessing the propensity for corrosion. Unfortunately, the temperatures of the wastes in contact with the secondary steel liner are not known; they are estimated to range from 45 deg C to 60 deg C. It is also notable that most corrosion tests have been carried out with un-welded, stress-relieved steels, but the secondary liner in tank AY-102 was not stress-relieved. In addition, the cold weather fabrication and welding led to many problems, which required repeated softening of the metal to flatten secondary bottom during its construction. This flame treatment may have altered the microstructure of the steel

  17. Statistical evaluation of unobserved nonuniform corrosion in A216 steel

    International Nuclear Information System (INIS)

    Pulsipher, B.A.

    1988-07-01

    Tests designed to promote nonuniform corrosion have been conducted at PNL on A216 steel. In all of the tests performed to date, there have been no manifestations of significant nonuniform corrosion. Although this may suggest that nonuniform corrosion in A216 steel may not be a significant problem in the nuclear waste repository, a question arises as to whether enough tests have been conducted for a sufficient length of time to rule out nonuniform corrosion of A216 steel. In this report, a method for determining the required number of tests is examined for two of the mechanisms of nonuniform corrosion: pitting and crevice corrosion

  18. Performance of epoxy-nanocomposite under corrosive environment

    Directory of Open Access Journals (Sweden)

    2007-06-01

    Full Text Available Nanocomposite materials consisting of polymeric matrix materials and natural or synthetic layered minerals like clay are currently an expanding field of study because these new materials often exhibit a wide range of improved properties over their unmodified starting polymers. Epoxy/organoclay nanocomposites have been prepared by intercalating epoxy into the organoclay via direct mixing process. The clay exfoliation was monitored by X-ray diffraction (XRD and transmission electron microscopy (TEM. Water diffusion and sulfuric acid corrosion resistance of epoxy-based nanocomposites were evaluated. Diffusion was studied through epoxy samples containing up to 6 phr (parts per hundred resin of an organically treated montmorillonite. The diffusion of the environmental solution was measured by noting the increase in weight of the samples as a function of immersion time in these solutions at 80°C. The effect of the degree of exfoliation of the organoclay on water barrier and corrosion resistance was specifically studied. The data have been compared to those obtained from the neat epoxy resin to evaluate the diffusion properties of the nanocomposites. The flexural strength of the epoxy/organoclay nanocomposites samples made was examined to compare their mechanical performance under corrosive conditions as a function of immersion time and temperature. It was found, that the organoclay was mainly intercalated with some exfoliation and that addition of the organoclay yields better flexural strength retention under immersion into sulfuric acid.

  19. Corrosion performance of several metals in plutonium nitrate solution

    International Nuclear Information System (INIS)

    Takeda, Seiichiro; Nagai, Takayuki; Yasu, Shozo; Koizumi, Tsutomu

    1995-01-01

    Corrosion behavior of several metals exposed in plutonium nitrate solution was studied. Plutonium nitrate solution with the plutonium concentration ranging from 0.01 to 300 g/l was used as a corrosive medium. Specimens tested were type 304 ULC (304 ULC) stainless steel, type 310 Nb (310 Nb) stainless steel, titanium (Ti), titanium-5% tantalum alloy (Ti-5Ta), and zirconium (Zr). Corrosion behavior of these metals in plutonium nitrate solution was evaluated through examining electrochemical characteristics and corrosion rates obtained by weight loss measurement. From the results of the corrosion tests, it was found that the corrosion rate of stainless steels i.e. 304 ULC and 310 Nb, increases by the presence of plutonium in nitric acid solution. The corrosion potential of the stainless steels shifted linearly towards the noble direction as the concentration of plutonium increases. It is thought that the shifts in corrosion potential of the stainless steels to the noble direction results an increase in anodic current and, hence, corrosion rate. Valve metals, i.e. Ti, Ti-5Ta and Zr, showed good corrosion resistance over the whole range of plutonium concentration examined here. (author)

  20. Corrosion and deposit evaluation in large diameter pipes using radiography

    International Nuclear Information System (INIS)

    Boateng, A.

    2012-01-01

    The reliability and safety of industrial equipment in the factories and processing industries are substantially influenced by degradation processes such as corrosion, erosion, deposits and blocking of pipes. These might lead to low production, unpredictable and costly shutdowns due to repair and replacement and sometimes combined environmental pollution and risk of personnel injuries. Only periodic inspection for the integrity of pipes and equipment can reduce the risk in connection with other maintenance activities. The research explored two methods of radiographic inspection techniques, the double wall technique and the tangential radiographic technique using Ir-192 for evaluating deposits and corrosion attacks across the inner and outer walls of steel pipes with diameter greater than 150 mm with or without insulation. The application of both techniques was conducted depending on pipe diameter, wall thickness, radiation source (Ir-92) and film combination. The iridium source was positioned perpendicular with respect to the pipe axis projecting the double wall of the pipe on the plated radiographic film. With the tangential radiographic technique, the source was placed tangential to the pipe wall and because of its large diameter, the source was collimated to prevent backscatter and also to focus the beam at the target area of interest. All measurements were performed on special designed test pieces to simulate corrosion attack and deposits on industrial pipes. Pitting corrosion measurements based on Tangential Radiographic Technique were more sophisticated, and therefore magnification factor and correction were used to establish the estimated pit depth on the film. The insulating material used to conserve the thermodynamic properties of the transported media had relatively negligible attenuation coefficient compared to the concrete deposit. The two explored techniques were successful in evaluating corrosion attack and deposit on the walls of the pipe and the risk

  1. Durability evaluation method on rebar corrosion of reinforced concrete

    International Nuclear Information System (INIS)

    Kitsutaka, Yoshinori

    2013-01-01

    In this paper, method on the durability evaluation in nuclear power plant concrete structures was investigated. In view of the importance of evaluating the degree of deterioration of reinforced concrete structures, relationships should be formulated among the number of years elapsed, t, the amount of action of a deteriorative factor, F, the degree of material deterioration, D, and the performance of the structure, P. Evaluation by PDFt diagrams combining these relationships may be effective. A detailed procedure of durability evaluation for a reinforced concrete structure using PDFt concept is presented for the deterioration of rebar corrosion caused by neutralization and penetration of salinity by referring to the recent papers. (author)

  2. Corrosion resistance of high-performance materials titanium, tantalum, zirconium

    CERN Document Server

    2012-01-01

    Corrosion resistance is the property of a material to resist corrosion attack in a particular aggressive environment. Although titanium, tantalum and zirconium are not noble metals, they are the best choice whenever high corrosion resistance is required. The exceptionally good corrosion resistance of these high–performance metals and their alloys results from the formation of a very stable, dense, highly adherent, and self–healing protective oxide film on the metal surface. This naturally occurring oxide layer prevents chemical attack of the underlying metal surface. This behavior also means, however, that high corrosion resistance can be expected only under neutral or oxidizing conditions. Under reducing conditions, a lower resistance must be reckoned with. Only very few inorganic and organic substances are able to attack titanium, tantalum or zirconium at ambient temperature. As the extraordinary corrosion resistance is coupled with an excellent formability and weldability these materials are very valua...

  3. Mechanical Performance versus Corrosion Damage Indicators for Corroded Steel Reinforcing Bars

    Directory of Open Access Journals (Sweden)

    Silvia Caprili

    2015-01-01

    Full Text Available The experimental results of a testing campaign including tensile and low-cycle fatigue tests on different reinforcing steel bar types in the as-delivered and corroded condition are presented. Experimental data were statistically analyzed adopting ANOVA technique; Performance Indicators (PIs, describing the mechanical performance characteristics of reinforcements, and Corrosion Damage Indicators (CDIs, describing the detrimental effects of corrosion phenomena, were determined and correlated in order to evaluate the influence of corrosion on the behaviour of reinforcing steels, providing useful information for designers in addition to what is presented in current standards.

  4. The Corrosion of High Performance Steel in Adverse Environments

    International Nuclear Information System (INIS)

    Cook, Desmond C.

    2005-01-01

    The corrosion products that have formed on weathering steel bridges exposed to different weather conditions in the United States have been evaluated. They have been analyzed by spectroscopic techniques to determine the relationship between protective and non-protective rust coatings, and their relationship to the exposure conditions. Bridges constructed recently using High Performance Steel, as well as older bridges built with Type A588B weathering steel, were evaluated for corrosion performance of the rust coatings. In locations where the steel is subjected to regular wet-dry cycling, where the surface is wet for less than about 20% of the time, a protective patina starts to form after a few months exposure, and continues to an adherent, impervious coating after a decade. The protective patina is characterized by the formation of only goethite and lepidocrocite. The goethite makes up about 80% of the rust, and itself consists of a nanophase component, 40%, or infrequent drying cycles (regions close to waterways, fog or having high humidity), the weathering steel forms a rust coating that consists of a large amount of maghemite, and goethite that contains very little of the nanophase component. The rust coating ex-foliates from the steel and is not protective. Under exposure conditions in which chlorides are deposited onto the weathering steel surface (marine or de-icing salt locations), the protective patina also does not form. Instead, the rust coating consists of a large fraction of akaganeite that forms at the expense of the lepidocrocite and nanophase goethite. The bridges exposed to high chloride concentrations, 1.5 wt%, and therefore having no protective patina, have corrosion rates measured to be 6 times larger than expected for weathering steel with the protective patina

  5. Effect of flow on corrosion in catenary risers and its corrosion inhibitor performance

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Pedro Altoe; Magalhaes, Alvaro Augusto Oliveira; Silva, Jussara de Mello [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil); Kang, Cheolho; More, Parimal P. [Det Norske Veritas (DNV), Oslo (Norway)

    2009-07-01

    In oil and gas production, multiphase flow is often encountered and a range of different flow patterns can be experienced in pipelines. The flow regime transition and flow characteristics can be changed with the change of pipeline topography, which affects the corrosion and the performance of corrosion inhibitor in these multiphase pipelines. This paper outlines on the effect of inclination on the flow characteristics and their subsequent effect on corrosion rates. Also, this paper presents on the performance of three candidate corrosion inhibitors under severe slugging conditions at low water cut. For the simulation of offshore flow lines and risers, the experiments were carried out in a 44 m long, 10 cm diameter, three different pipeline inclinations of 0, 3 and 45 degrees. Light condensate oil with a viscosity of 2.5 cP at room temperature was used and water cut was 20%. The results indicated that the baseline corrosion rate in 45 degrees showed higher than other inclinations. Each corrosion inhibitor showed a different inhibitor performance. (author)

  6. Corrosion

    Science.gov (United States)

    Slabaugh, W. H.

    1974-01-01

    Presents some materials for use in demonstration and experimentation of corrosion processes, including corrosion stimulation and inhibition. Indicates that basic concepts of electrochemistry, crystal structure, and kinetics can be extended to practical chemistry through corrosion explanation. (CC)

  7. Evaluation of corrosion attack of chimney liners

    Directory of Open Access Journals (Sweden)

    Blahetová M.

    2016-06-01

    Full Text Available The case study of chimney liner corrosion addresses three specific cases of damage of chimney systems from of stainless steels. These systems were used for flue of gas arising from the combustion of brown coal in small automatic boilers, which are used for heating. Detailed analyzes implied that the cause of devastating corrosion of the steel AISI 316 and 304 steel (CSN 17349, 17241 was particularly high content of halides (chlorides and fluorides, which caused a severe pitting corrosion, which led up to the perforation of the liner material. Simultaneous reduction of the thickness of the used sheets was due to by the general corrosion, which was caused by the sulfur in the solid fuel. The condensation then led to acid environment and therefore the corrosion below the dew point of the sulfuric acid has occurred. All is documented by metallographic analysis and microanalysis of the corrosion products.

  8. Corrosion performance of inorganic coatings in seawater

    NARCIS (Netherlands)

    Zhang, X.; Buter, S.J.; Ferrari, G.M.; Westing, E. van; Kowalski, L.

    2011-01-01

    Inorganic coatings are widely used to protect carbon steel hydraulic cylinder rods from wear and corrosion in aggressive offshore environment. Different types of lay-ers such as Ni/Cr, Al2O3, Cr2O3, TiO2, and Inconel 625 layers were applied to the carbon steels by plasma, High Velocity Oxygen Fuel

  9. Evaluation of local corrosion life by statistical method

    International Nuclear Information System (INIS)

    Kato, Shunji; Kurosawa, Tatsuo; Takaku, Hiroshi; Kusanagi, Hideo; Hirano, Hideo; Kimura, Hideo; Hide, Koichiro; Kawasaki, Masayuki

    1987-01-01

    In this paper, for the purpose of achievement of life extension of light water reactor, we examined the evaluation of local corrosion by satistical method and its application of nuclear power plant components. There are many evaluation examples of maximum cracking depth of local corrosion by dowbly exponential distribution. This evaluation method has been established. But, it has not been established that we evaluate service lifes of construction materials by satistical method. In order to establish of service life evaluation by satistical method, we must strive to collect local corrosion dates and its analytical researchs. (author)

  10. Corrosion models for predictions of performance of high-level radioactive-waste containers

    Energy Technology Data Exchange (ETDEWEB)

    Farmer, J.C.; McCright, R.D. [Lawrence Livermore National Lab., CA (United States); Gdowski, G.E. [KMI Energy Services, Livermore, CA (United States)

    1991-11-01

    The present plan for disposal of high-level radioactive waste in the US is to seal it in containers before emplacement in a geologic repository. A proposed site at Yucca Mountain, Nevada, is being evaluated for its suitability as a geologic repository. The containers will probably be made of either an austenitic or a copper-based alloy. Models of alloy degradation are being used to predict the long-term performance of the containers under repository conditions. The models are of uniform oxidation and corrosion, localized corrosion, and stress corrosion cracking, and are applicable to worst-case scenarios of container degradation. This paper reviews several of the models.

  11. Corrosion performance of new Zircaloy-2-based alloys

    International Nuclear Information System (INIS)

    Rudling, P.; Mikes-Lindbaeck, M.; Lethinen, B.; Andren, H.O.; Stiller, K.

    1994-01-01

    A material development project was initiated to develop a new zirconium alloy, outside the ASTM specifications for Zircaloy-2 and Zircaloy-4, with optimized hydriding and corrosion properties for both boiling water reactors and pressurized water reactors. A number of different alloys were manufactured. These alloys were long-term corrosion tested in autoclaves at 400 C in steam. Also, a 520 C/24 h steam test was carried out. The zirconium metal microstructure and the chemistry of precipitates were characterized by analytical electron microscopy. The metal matrix chemistry was determined by atom probe analysis. The paper describes the correlations between corrosion material performance and zirconium alloy microstructure

  12. Corrosion evaluation in insulated pipes by non destructive testing method

    International Nuclear Information System (INIS)

    Abd Razak Hamzah; Azali Muhammad; Mohammad Pauzi Ismail; Abd Nassir Ibrahim; Abd Aziz Mohamed; Sufian Saad; Saharuddin Sayuti; Shukri Ahmad

    2002-01-01

    In engineering plants, detection of corrosion and evaluation of deposit in insulated pipes using radiography method are considered as a very challenging tasks. In General this degradation problem is attributed to water condensation. It causes the formation of deposit and scale inside the pipe, as well as between the insulation and pipe in cold temperature pipes. On the other hand, for hot temperature pipes the main problem is mainly due to corrosion/erosion attack inside the pipe. In the study of corrosion in pipelines, one of the most important parameters to be monitored and measured is the wall thickness. Currently, most pipeline corrosion monitoring and evaluation for both insulated and non-insulated pipes is performed using an ultrasonic method. The most common technique is that based on the A-Scan, using either a normal flaw detector or some form of dedicated equipment. However, with recent development of ultrasonic technology, more advance method, namely B-Scan and C-scan techniques are also available. The most notable disadvantage of using this method is that the insulation covering the pipe has to be removed before the inspection can be carried out and this is considered as not so cost effective. Due to this reason, the possibility of employing other alternative NDT method, namely radiographic testing method were studied. The technique used in this studied are known as tangential technique. In this study it was found that the result found using tangential technique is consistent with the actual thickness of the pipe. Result of this study is presented and discussed in this paper. (Author)

  13. Evaluation of intergranular corrosion rate and microstructure of forged 316L round bar

    International Nuclear Information System (INIS)

    Lim, H. K.; Kim, Y. S.

    2009-01-01

    When austenitic stainless steels are heat treated in the range of 500∼850 .deg. C, the alloys are sensitized due to the formation of chromium carbide at grain boundaries and then intergranular corrosion occurs. This paper aims to evaluate the intergranular corrosion rate and microstructural change of forged 316L stainless steel. To analyze the microstructure by forging conditions, ferrite phase, sigma phase, intergranular precipitation were observed. In order to evaluate the intergranular corrosion rate. Huey test was performed by ASTM A262. On the base of microstructural observation, ferrite and sigma phases were not detected, and also intergranular precipitation was not revealed in optical microscopic observation. By ASTM A262 Practice A, step structure was shown in all forging conditions. Intergranular corrosion rate gradually increased by Huey test periods but average corrosion rate was under 0.03 mm/month

  14. Evaluation of intergranular corrosion rate and microstructure of forged 316L round bar

    Energy Technology Data Exchange (ETDEWEB)

    Lim, H. K.; Kim, Y. S. [Andong National University, Andong (Korea, Republic of)

    2009-12-15

    When austenitic stainless steels are heat treated in the range of 500{approx}850 .deg. C, the alloys are sensitized due to the formation of chromium carbide at grain boundaries and then intergranular corrosion occurs. This paper aims to evaluate the intergranular corrosion rate and microstructural change of forged 316L stainless steel. To analyze the microstructure by forging conditions, ferrite phase, sigma phase, intergranular precipitation were observed. In order to evaluate the intergranular corrosion rate. Huey test was performed by ASTM A262. On the base of microstructural observation, ferrite and sigma phases were not detected, and also intergranular precipitation was not revealed in optical microscopic observation. By ASTM A262 Practice A, step structure was shown in all forging conditions. Intergranular corrosion rate gradually increased by Huey test periods but average corrosion rate was under 0.03 mm/month.

  15. benzoic acid Schiff base and evaluation as corrosion

    African Journals Online (AJOL)

    user

    acid Schiff base and evaluation as corrosion inhibitor of steel in 2.0 M H2SO4. *. 1. ECHEM .... adopted for this experiment was in accordance with .... Table 4: Kinetic data for mild steel corrosion in 2M H2SO4 containing SBDAB from weight loss measurement. inhibitor .... and anti-bacterial activity of Schiff base derived.

  16. Corrosion evaluation of materials in sulfur compound environments

    International Nuclear Information System (INIS)

    Maoying Teng; Iuanjou Yang

    1993-01-01

    The para-toluene sulfonic acid (PTSA) serves as a catalyst in producing diethylene glycol dibenzoate (DEGDB) and decomposes with increasing time at elevated temperature. Due to the presence of bisulfite ion, it is important to evaluate the corrosion properties of materials in this metastable environments. A potentiodynamic method was used to screen materials' properties in a PTSA solution. A surface analysis technique was also performed to investigate the oxide films. The critical current density and passive current density were substantially reduced when Fe alloyed with Cr and/or Ni. With the addition of Mo in Fe-Ni-Cr alloys, the critical current density was lowered further to show the beneficial effect of alloyed Mo. A plot of the corrosion rate of materials in DEGDB as a function of Ni/Cr ratio shows the linearity with increasing Ni/Cr ratio, disregard the type of materials. The corrosion rate of pure chromium can be estimated as ∼ 2.0 mpy by extrapolation of the linearity to Ni/Cr = 0. This is also the minimum corrosion rate that even Fe-Ni-Cr alloys were alloyed with Mo. Surface analysis results showed that the dissolution of Fe and/or Ni leads to a higher surface chromium content and results in the formation of chromium oxide on metal surface. This chromium oxide then prevents metal from corrosion. It is concluded that the higher the nickel content the higher the corrosion rate of materials. The composition potential-pH diagrams for Fe-S-H 2 O and Ni-S-H 2 O show that the stability fields of FeS and NiS cover a wide range of pH. The effect of sulfur or sulfide ions in promoting dissolution of Fe and/or Ni are highly possible. The activating influence of sulfur compounds on Ni is stronger than that of Fe, although the highly electronic conductivity of iron sulfides can catalyze the cathodic reaction. Undoubtedly, sulfur compound strongly depassivates high Ni contents materials

  17. Standard practice for preparing, cleaning, and evaluating corrosion test specimens

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2003-01-01

    1.1 This practice covers suggested procedures for preparing bare, solid metal specimens for tests, for removing corrosion products after the test has been completed, and for evaluating the corrosion damage that has occurred. Emphasis is placed on procedures related to the evaluation of corrosion by mass loss and pitting measurements. (Warning—In many cases the corrosion product on the reactive metals titanium and zirconium is a hard and tightly bonded oxide that defies removal by chemical or ordinary mechanical means. In many such cases, corrosion rates are established by mass gain rather than mass loss.) 1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific precautionary statements, see 1 and 7.2.

  18. FY05 HPCRM Annual Report: High-Performance Corrosion-Resistant Iron-Based Amorphous Metal Coatings Evaluation of Corrosion Resistance FY05 HPCRM Annual Report No. Rev. 1DOE-DARPA Co-Sponsored Advanced Materials Program

    International Nuclear Information System (INIS)

    Farmer, J C; Haslam, J J; Day, S D

    2007-01-01

    New corrosion-resistant, iron-based amorphous metals have been identified from published data or developed through combinatorial synthesis, and tested to determine their relative corrosion resistance. Many of these materials can be applied as coatings with advanced thermal spray technology. Two compositions have corrosion resistance superior to wrought nickel-based Alloy C-22 (UNS No. N06022) in some very aggressive environments, including concentrated calcium-chloride brines at elevated temperature. Two Fe-based amorphous metal formulations have been found that appear to have corrosion resistance comparable to, or better than that of Ni-based Alloy C-22, based on breakdown potential and corrosion rate. Both Cr and Mo provide corrosion resistance, B enables glass formation, and Y lowers critical cooling rate (CCR). SAM1651 has yttrium added, and has a nominal critical cooling rate of only 80 Kelvin per second, while SAM2X7 (similar to SAM2X5) has no yttrium, and a relatively high critical cooling rate of 610 Kelvin per second. Both amorphous metal formulations have strengths and weaknesses. SAM1651 (yttrium added) has a low critical cooling rate (CCR), which enables it to be rendered as a completely amorphous thermal spray coating. Unfortunately, it is relatively difficult to atomize, with powders being irregular in shape. This causes the powder to be difficult to pneumatically convey during thermal spray deposition. Gas atomized SAM1651 powder has required cryogenic milling to eliminate irregularities that make flow difficult. SAM2X5 (no yttrium) has a high critical cooling rate, which has caused problems associated with devitrification. SAM2X5 can be gas atomized to produce spherical powders of SAM2X5, which enable more facile thermal spray deposition. The reference material, nickel-based Alloy C-22, is an outstanding corrosion-resistant engineering material. Even so, crevice corrosion has been observed with C-22 in hot sodium chloride environments without buffer

  19. EVALUATION OF CORROSION COST OF CRUDE OIL PROCESSING INDUSTRY

    Directory of Open Access Journals (Sweden)

    ADESANYA A.O.

    2012-08-01

    Full Text Available Crude oil production industry as the hub of Nigeria Economy is not immune to the global financial meltdown being experienced world over which have resulted in a continual fall of oil price. This has necessitated the need to reduce cost of production. One of the major costs of production is corrosion cost, hence, its evaluation. This research work outlined the basic principles of corrosion prevention, monitoring and inspection and attempted to describe ways in which these measures may be adopted in the context of oil production. A wide range of facilities are used in crude oil production making it difficult to evaluate precisely the extent of corrosion and its cost implication. In this study, cost of corrosion per barrel was determined and the annualized value of corrosion cost was also determined using the principles of engineering economy and results analyzed using descriptive statistics. The results showed that among the corrosion prevention methods identified, the use of chemical treatment gave the highest cost contribution (81% of the total cost of prevention while coating added 19%. Cleaning pigging and cathodic protection gave no cost. The contribution of corrosion maintenance methods are 60% for repairs and 40% for replacement. Also among the corrosion monitoring and inspection identified, NDT gave the highest cost contribution of 41% of the total cost, followed by coating survey (34%. Cathodic protection survey and crude analysis gives the lowest cost contribution of 19% and 6% respectively. Corrosion control cost per barrel was found to be 77 cent/barrel. The significance of this cost was not much due to high price of crude oil in the international market. But the effect of corrosion in crude oil processing takes its toll on crude oil production (i.e. deferment.

  20. High performance polypyrrole coating for corrosion protection and biocidal applications

    Science.gov (United States)

    Nautiyal, Amit; Qiao, Mingyu; Cook, Jonathan Edwin; Zhang, Xinyu; Huang, Tung-Shi

    2018-01-01

    Polypyrrole (PPy) coating was electrochemically synthesized on carbon steel using sulfonic acids as dopants: p-toluene sulfonic acid (p-TSA), sulfuric acid (SA), (±) camphor sulfonic acid (CSA), sodium dodecyl sulfate (SDS), and sodium dodecylbenzene sulfonate (SDBS). The effect of acidic dopants (p-TSA, SA, CSA) on passivation of carbon steel was investigated by linear potentiodynamic and compared with morphology and corrosion protection performance of the coating produced. The types of the dopants used were significantly affecting the protection efficiency of the coating against chloride ion attack on the metal surface. The corrosion performance depends on size and alignment of dopant in the polymer backbone. Both p-TSA and SDBS have extra benzene ring that stack together to form a lamellar sheet like barrier to chloride ions thus making them appropriate dopants for PPy coating in suppressing the corrosion at significant level. Further, adhesion performance was enhanced by adding long chain carboxylic acid (decanoic acid) directly in the monomer solution. In addition, PPy coating doped with SDBS displayed excellent biocidal abilities against Staphylococcus aureus. The polypyrrole coatings on carbon steels with dual function of anti-corrosion and excellent biocidal properties shows great potential application in the industry for anti-corrosion/antimicrobial purposes.

  1. Performance investigation of low-toxic organic corrosion inhibitors in amine treating unit

    International Nuclear Information System (INIS)

    Veawab, A.; Tanthapanichakoon, W.

    2003-01-01

    Amine treating unit is constantly subject to severe corrosion problems leading to extra expenditure and operational limitations. Heavy-metal vanadium compounds are extensively used as corrosion inhibitors to suppress the severe corrosion to an acceptable level. In recent years, the fact that these vanadium compounds are inherently toxic and can potentially pose adverse impacts on the human health and the environment has brought about environmental awareness that causes their uses costly due to the difficulty in waste disposal. To respond to the environmental concern and reduce cost of waste disposal as well as prepare for more stringent regulations for chemical uses, the development of low-toxic corrosion inhibitors is necessary. This work therefore focuses on an investigation of inhibition performance of a number of organic and inorganic compounds that have relatively low toxicity in comparison with conventional inhibitors. The performance evaluation was carried out through corrosion experiments using carbon steel specimens. The experiments were done in 3 and 5 kmol/m 3 monoethanolamine (MEA) solution saturated with CO 2 at 80 o C. It was found that several tested compounds have potential to be effective low-toxic corrosion inhibitors. The promising compounds provide reasonable and in some cases comparable protection performance to the conventional inhibitor. (author)

  2. Corrosion Evaluation of Tank 40 Leak Detection Box

    Energy Technology Data Exchange (ETDEWEB)

    Mickalonis, J.I.

    1999-07-29

    'Leak detection from the transfer lines in the tank farm has been a concern for many years because of the need to minimize exposure of personnel and contamination of the environment. The leak detection box (LDB) is one line of defense, which must be maintained to meet this objective. The evaluation of a failed LDB was one item from an action plan aimed at minimizing the degradation of LDBs. The Tank 40 LDB, which failed in service, was dug up and shipped to SRTC for evaluation. During a video inspection while in service, this LDB was found to have black tubercles on the interior, which suggested possible microbial involvement. The failure point, however, was believed to have occurred in the drain line from the transfer line jacket. Visual, metallurgical, and biological analyses were performed on the LDB. The analysis results showed that there was not any adverse microbiological growth or significant localized corrosion. The corrosion of the LDB was caused by exposure to aqueous environments and was typical of carbon steel pipes in soil environments.'

  3. Assessment of high performance concrete containing fly ash and calcium nitrite based corrosion inhibitor as a mean to prevent the corrosion of reinforcing steel

    International Nuclear Information System (INIS)

    Montes-García, P; Jiménez-Quero, V; López-Calvo, H

    2015-01-01

    This research analyses the effectiveness of the water-to-cement ratio (w/c), fly ash and a calcium nitrite based corrosion inhibitor to prevent the corrosion of reinforcing steel embedded in high performance concrete. The interactive effect between the inhibitor and fly ash was evaluated because the occurrence of a negative effect when both ingredients are added together in a concrete mixture has been reported. All the concrete mixtures studied in this investigation had 8.2% of silica fume. Twenty seven prismatic concrete specimens were fabricated with dimensions of 55 × 230 × 300 mm each containing two steel rods embedded for the purpose of corrosion monitoring. The specimens were exposed to a simulated marine environment with two daily cycles of wetting and drying for one year. To evaluate the deterioration of the specimens corrosion potentials and linear polarization resistance tests were carried out. The results indicate that the use of a low w/c, the addition of fly ash and the addition of the corrosion inhibitor contributed to the reduction of the corrosion of steel in the concrete specimens. The results further suggest that the combination of fly ash and corrosion inhibitor does not promote the deterioration of the concrete matrix

  4. Shadow corrosion evaluation in the Studsvik R2 reactor

    International Nuclear Information System (INIS)

    Sanders, Ch.; Lysell, G.

    2000-01-01

    Post-irradiation examination has shown that increased corrosion occurs when zirconium alloys are in contact with or in proximity to other metallic objects. The observations indicate an influence of irradiation from the adjacent component as the enhanced corrosion occurs as a 'shadow' of the metallic object on the zirconium surface. This phenomenon could ultimately limit the lifetime of certain zirconium alloy components in the reactor. The Studsvik R2 materials test reactor has an In-Core Autoclave (INCA) test facility especially designed for water chemistry and materials research. The INCA facility has been evaluated and found suitable for shadow corrosion studies. The R2 reactor core containing the INCA facility was modeled with the Monte Carlo N-Particle (MCNP) code in order to evaluate the electron deposition in various materials and to develop a hypothesis of the shadow corrosion mechanism. (authors)

  5. Corrosion Performance of Fe-Cr-Ni Alloys in Artificial Saliva and Mouthwash Solution

    Science.gov (United States)

    Porcayo-Calderon, J.; Casales-Diaz, M.; Salinas-Bravo, V. M.; Martinez-Gomez, L.

    2015-01-01

    Several austenitic stainless steels suitable for high temperature applications because of their high corrosion resistance and excellent mechanical properties were investigated as biomaterials for dental use. The steels were evaluated by electrochemical techniques such as potentiodynamic polarization curves, cyclic polarization curves, measurements of open circuit potential, and linear polarization resistance. The performance of steels was evaluated in two types of environments: artificial saliva and mouthwash solution at 37°C for 48 hours. In order to compare the behavior of steels, titanium a material commonly used in dental applications was also tested in the same conditions. Results show that tested steels have characteristics that may make them attractive as biomaterials for dental applications. Contents of Cr, Ni, and other minor alloying elements (Mo, Ti, and Nb) determine the performance of stainless steels. In artificial saliva steels show a corrosion rate of the same order of magnitude as titanium and in mouthwash have greater corrosion resistance than titanium. PMID:26064083

  6. Corrosion evaluation of uranyl nitrate solution evaporator and denitrator in Tokai reprocessing plant

    International Nuclear Information System (INIS)

    Yamanaka, Atsushi; Hashimoto, Kowa; Uchida, Toyomi; Shirato, Yoji; Isozaki, Toshihiko; Nakamura, Yoshinobu

    2011-01-01

    The Tokai reprocessing plant (TRP) adopted the PUREX method in 1977 and has reprocessed spent nuclear fuel of 1140 tHM (tons of heavy metals) since then. The reprocessing equipment suffers from various corrosion phenomena because of high nitric acidity, solution ion concentrations, such as uranium, plutonium, and fission products, and temperature. Therefore, considering corrosion performance in such a severe environment, stainless steels, titanium steel, and so forth were employed as corrosion resistant materials. The severity of the corrosive environment depends on the nitric acid concentration and the temperature of the solution, and uranium in the solution reportedly does not significantly affect the corrosion of stainless steels and controls the corrosion rates of titanium steel. The TRP equipment that handles uranyl nitrate solution operates at a low nitric acid concentration and has not experienced corrosion problems until now. However, there is a report that corrosion rates of some stainless steels increase in proportion to rising uranium concentrations. The equipment that handles the uranyl nitrate solution in the TRP includes the evaporators, which concentrate uranyl nitrate to a maximum concentration of about 1000 gU/L (grams of uranium per liter), and the denitrator, where uranyl nitrate is converted to UO 3 powder at about 320degC. These equipments are therefore required to grasp the degree of the progress of corrosion to handle high-temperature and high-concentration uranyl nitrate. The evaluation of this equipment on the basis of thickness measurement confirmed only minor corrosion and indicated that the equipment would be fully adequate for future operation. (author)

  7. Corrosion resistance of high performance stainless steels in cooling water and other refinery environments

    International Nuclear Information System (INIS)

    Kovach, C.W.; Redmerski, L.S.

    1984-01-01

    The recent successful introduction of high performance stainless steels as tubing for seawater cooled electric utility condensers suggests that these alloys can also provide useful service in refinery heat exchanger applications. Since many of these applications involve higher temperature exposure than steam condensers, a study was conducted to evaluate crevice corrsion resistance over a range of cooling water temperature and chloride concentrations, and also to evaluate general corrosion resistance in some strong chemical and refinery environments. These stainless steels display excellent crevice corrosion resistance as well as good resistance to a variety of chemical environments that may be encountered in refinery, petrochemical and chemical plant service

  8. Corrosion performance of iron aluminides in fossil energy environments

    Energy Technology Data Exchange (ETDEWEB)

    Natesan, K. [Argonne National Lab., IL (United States). Energy Technology Div.

    1997-12-01

    Corrosion of metallic structural materials in complex gas environments of coal gasification and combustion is a potential problem. The corrosion process is dictated by concentrations of two key constituents: sulfur as H{sub 2}S or SO{sub 2} and chlorine as HCl. This paper presents a comprehensive review of the current status of the corrosion performance of alumina scales that are thermally grown on Fe-base alloys, including iron aluminides, in multicomponent gas environments of typical coal-conversion systems. Mechanisms of scale development/breakdown, performance envelopes for long-term usage of these materials, approaches to modifying the surfaces of engineering alloys by cladding or coating them with intermetallics, and in-service experience with these materials are emphasized. The results are compared with the performance of chromia-forming alloys in similar environments. The paper also discusses the available information on corrosion performance of alloys whose surfaces were enriched with Al by the electrospark deposition process or by weld overlay techniques.

  9. Development and evaluation of an instantaneous atmospheric corrosion rate monitor

    Science.gov (United States)

    Mansfeld, F.; Jeanjaquet, S. L.; Kendig, M. W.; Roe, D. K.

    1985-06-01

    A research program was carried out in which a new instantaneous atmospheric corrosion rate monitor (ACRM) was developed and evaluated, and equipment was constructed which will allow the use of many sensors in an economical way in outdoor exposures. In the first task, the ACRM was developed and tested in flow chambers in which relative humidity and gaseous and particulate pollutant levels can be controlled. Diurnal cycles and periods of rain were simulated. The effects of aerosols were studied. A computerized system was used for collection, storage, and analysis of the electrochemical data. In the second task, a relatively inexpensive electronics system for control of the ACRM and measurement of atmospheric corrosion rates was designed and built. In the third task, calibration of deterioration rates of various metallic and nonmetallic materials with the response of the ACRMs attached to these materials was carried out under controlled environmental conditions using the system developed in the second task. A Quality Assurance project plan was prepared with inputs from the Rockwell International Environmental Monitoring and Service Center and Quality Assurance System audits were performed.

  10. Corrosion of experimental magnesium alloys in blood and PBS: A gravimetric and microscopic evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Schille, Ch., E-mail: Christine.Schille@med.uni-tuebingen.de [University Hospital Tuebingen, Center for Dentistry, Oral Medicine and Maxillofacial Surgery, Section Medical Materials and Technology, Osianderstr. 2-8, D-72076 Tuebingen (Germany); Braun, M.; Wendel, H.P. [University Hospital Tuebingen, Div. Congenital and Paediatric Cardiac Surgery, University Children' s Hospital, Tuebingen, Germany, Calwerstr. 7/1, D-72076 Tuebingen (Germany); Scheideler, L. [University Hospital Tuebingen, Center for Dentistry, Oral Medicine and Maxillofacial Surgery, Section Medical Materials and Technology, Osianderstr. 2-8, D-72076 Tuebingen (Germany); Hort, N. [GKSS Research Centre, Institute of Materials Research, Max-Planck-Str. 1, D-21502 Geesthacht (Germany); Reichel, H.-P. [Weissensee Company, Buergermeister-Ebert-Str. 30-32, D-36124 Eichenzell (Germany); Schweizer, E.; Geis-Gerstorfer, J. [University Hospital Tuebingen, Center for Dentistry, Oral Medicine and Maxillofacial Surgery, Section Medical Materials and Technology, Osianderstr. 2-8, D-72076 Tuebingen (Germany)

    2011-12-15

    Highlights: Black-Right-Pointing-Pointer Corrosion of eight Mg-based Biomaterials was tested in saline and human blood. Black-Right-Pointing-Pointer Corrosion behaviour in physiological saline and in blood was entirely different. Black-Right-Pointing-Pointer Al and Zn had the highest influence on corrosion behaviour in both electrolytes. Black-Right-Pointing-Pointer MgAl9 and MgAl9Zn1 showed least corrosion in human whole blood. Black-Right-Pointing-Pointer Tests in buffered corrosion media are not sufficient to predict corrosion in vivo. - Abstract: Corrosion tests for medical materials are often performed in simulated body fluids (SBF). When SBF are used for corrosion measurement, the open question is, how well they match the conditions in the human body. The aim of the study was to compare the corrosion behaviour of different experimental magnesium alloys in human whole blood and PBS{sup minus} (phosphate buffered saline w/o Ca and Mg) as a simulated body fluid by gravimetric weight measurements and microscopic evaluation. Eight different experimental magnesium alloys, containing neither Mn nor other additives, were manufactured. With these alloys, a static immersion test in PBS{sup minus} and a dynamic test using the Chandler-loop model with human whole blood over 6 h were performed. During the static immersion test, the samples were weighed every hour. During the dynamic test, the specimens were weighed before and after the 6 h incubation period in the Chandler-loop. From both tests, the total mass change was calculated for each alloy and the values were compared. Additionally, microscopic pictures from the samples were taken at the end of the test period. All alloys showed different corrosion behaviour in both tests, especially the alloys with high aluminium content, MgAl9 and MgAl9Zn1. Generally, alloys in PBS showed a weight gain due to generation of a microscopically visible corrosion layer, while in the blood test system a more or less distinct weight

  11. Corrosion of experimental magnesium alloys in blood and PBS: A gravimetric and microscopic evaluation

    International Nuclear Information System (INIS)

    Schille, Ch.; Braun, M.; Wendel, H.P.; Scheideler, L.; Hort, N.; Reichel, H.-P.; Schweizer, E.; Geis-Gerstorfer, J.

    2011-01-01

    Highlights: ► Corrosion of eight Mg–based Biomaterials was tested in saline and human blood. ► Corrosion behaviour in physiological saline and in blood was entirely different. ► Al and Zn had the highest influence on corrosion behaviour in both electrolytes. ► MgAl9 and MgAl9Zn1 showed least corrosion in human whole blood. ► Tests in buffered corrosion media are not sufficient to predict corrosion in vivo. - Abstract: Corrosion tests for medical materials are often performed in simulated body fluids (SBF). When SBF are used for corrosion measurement, the open question is, how well they match the conditions in the human body. The aim of the study was to compare the corrosion behaviour of different experimental magnesium alloys in human whole blood and PBS minus (phosphate buffered saline w/o Ca and Mg) as a simulated body fluid by gravimetric weight measurements and microscopic evaluation. Eight different experimental magnesium alloys, containing neither Mn nor other additives, were manufactured. With these alloys, a static immersion test in PBS minus and a dynamic test using the Chandler-loop model with human whole blood over 6 h were performed. During the static immersion test, the samples were weighed every hour. During the dynamic test, the specimens were weighed before and after the 6 h incubation period in the Chandler-loop. From both tests, the total mass change was calculated for each alloy and the values were compared. Additionally, microscopic pictures from the samples were taken at the end of the test period. All alloys showed different corrosion behaviour in both tests, especially the alloys with high aluminium content, MgAl9 and MgAl9Zn1. Generally, alloys in PBS showed a weight gain due to generation of a microscopically visible corrosion layer, while in the blood test system a more or less distinct weight loss was observed. When alloys are ranked according to corrosion susceptibility, the results differ also between the test systems. The

  12. Corrosion rate of steel in concrete - Evaluation of confinement techniques for on-site corrosion rate

    DEFF Research Database (Denmark)

    Nygaard, Peter Vagn; Geiker, Mette Rica; Elsener, Bernhard

    2009-01-01

    Earlier on-site investigations and laboratory studies have shown that varying corrosion rates are obtained when different commercially available instruments are used. The different confinement techniques, rather than the different electrochemical techniques used in the instruments, are considered...... to be the main reason for the discrepancies. This paper presents a method for the quantitative assessment of confinement techniques based on monitoring the operation of the corrosion rate instrument and the current distribution between the electrode assembly on the concrete surface and a segmented reinforcement...... bar embedded in the concrete. The applicability of the method was demonstrated on two commercially available corrosion rate instruments based on different confinement techniques. The method provided an explanation of the differences in performance of the two instruments. Correlated measurements...

  13. Corrosion protection performance of single and dual Plasma Electrolytic Oxidation (PEO) coating for aerospace applications

    International Nuclear Information System (INIS)

    Madhan Kumar, A.; Kwon, Sun Hwan; Jung, Hwa Chul; Shin, Kwang Seon

    2015-01-01

    Plasma Electrolytic Oxidation (PEO) coatings are known to be one of the most appropriate method for corrosion protection of magnesium (Mg) alloy. The improvement of PEO coatings and the optimization of their surface aspects are of major importance. In this current work, the influence of dual PEO coating on strip-cast AZ31 Mg alloy substrate has been evaluated with the aim of improving the surface and corrosion protection aspects. For this purpose, AZ31 Mg substrates are subjected to single and dual PEO processing in silicate and phosphate electrolyte under similar condition. Scanning electron microscopy (SEM) analysis confirmed that the number of pores in PEO coating processed in silicate electrolyte is higher than others. X-ray diffraction analysis of PEO coatings showed that the surface coating is mainly comprised of Mg 2 SiO 4 , Mg 3 (PO 4 ) 2 and MgO with different quantity based on PEO processing. Compared with the AZ31 Mg, the corrosion potential (E corr ) of both type PEO coatings was positively shifted about 250–400 mV and the corrosion current density (i corr ) was lowered by 3-4 orders of magnitude as result of adequate corrosion protection to the Mg alloy in 3.5% NaCl solution. All of the observation obviously showed that the dual PEO coating provides better corrosion protection performance than their respective single due to its synergistic beneficial effect. - Highlights: • Influence of dual PEO coating on AZ31 Mg alloy substrate was evaluated. • XRD confirmed formation of thin MgO inner, Mg 3 (PO 4 ) 2 and Mg 2 SiO 4 outer layer. • SEM results showed uniform coating with no cracks and relatively less micro pores. • Micro hardness of dual PEO coatings is higher than single PEO coatings. • Dual coating provides superior corrosion performance due to its synergistic effect

  14. Corrosion Performance of Nano-ZrO₂ Modified Coatings in Hot Mixed Acid Solutions.

    Science.gov (United States)

    Xu, Wenhua; Wang, Zhenyu; Han, En-Hou; Wang, Shuai; Liu, Qian

    2018-06-01

    A nano-ZrO₂ modified coating system was prepared by incorporation of nano-ZrO₂ concentrates into phenolic-epoxy resin. The corrosion performance of the coatings was evaluated in hot mixed acid solution, using electrochemical methods combined with surface characterization, and the effects of nano-ZrO₂ content were specially focused on. The results showed that 1% and 3% nano-ZrO₂ addition enhanced the corrosion resistance of the coatings, while 5% nano-ZrO₂ addition declined it. The coating with 3% nano-ZrO₂ presented the minimum amount of species diffusion, the lowest average roughness (5.94 nm), and the highest C/O ratio (4.55) and coating resistance, and it demonstrated the best corrosion performance among the coating specimens.

  15. Evaluation of Accelerated Graphitic Corrosion Test of Gray Cast Iron

    International Nuclear Information System (INIS)

    Kim, Jeong Hyeon; Hong, Jong Dae; Chang Heui; Na, Kyung Hwan; Lee, Jae Gon

    2011-01-01

    In operating nuclear power plants, gray cast iron is commonly used as materials for various non-safety system components including pipes in fire water system, valve bodies, bonnets, and pump castings. In such locations, operating condition does not require alloy steels with excellent mechanical properties. But, a few corrosion related degradation, or graphitic corrosion is frequently occurred to gray cast iron during the long-term operation in nuclear power plant. Graphitic corrosion is selective leaching of iron from gray cast iron, where iron gets removed and graphite grains remain intact. In U.S.A., one-time visual inspection and hardness measurement are required from regulatory body to detect the graphitic corrosion for the life extension evaluation of the operating nuclear power plant. In this study, experiments were conducted to make accelerated graphitic corrosion of gray cast iron using electrochemical method, and hardness was measured for the specimens to establish the correlation between degree of graphitic corrosion and surface hardness of gray cast iron

  16. Electrochemical evaluation of under-deposit corrosion and its inhibition using the wire beam electrode method

    Energy Technology Data Exchange (ETDEWEB)

    Tan Yongjun, E-mail: yj.tan@curtin.edu.a [Western Australian Corrosion Research Group, Department of Chemistry, Curtin University, GPO Box U1987, Perth (Australia); Fwu, Young; Bhardwaj, Kriti [Western Australian Corrosion Research Group, Department of Chemistry, Curtin University, GPO Box U1987, Perth (Australia)

    2011-04-15

    Research highlights: A new experiment method for evaluating under-deposit corrosion and its inhibitors. Under-deposit corrosion did not occur in a CO{sub 2} saturated pure brine solution. Inhibitor imidazoline addition and O{sub 2} contamination initiated under-deposit corrosion. Inhibitor imidazoline reduced general corrosion but enhanced localised corrosion. - Abstract: A new experimental method has been applied to evaluate under-deposit corrosion and its inhibition by means of an electrochemically integrated multi-electrode array, namely the wire beam electrode (WBE). Maps showing galvanic current and corrosion potential distributions were measured from a WBE surface that was partially covered by sand. Under-deposit corrosion did not occur during the exposure of the WBE to carbon dioxide saturated brine under ambient temperature. The introduction of corrosion inhibitor imidazoline and oxygen into the brine was found to significantly affect the patterns and rates of corrosion, leading to the initiation of under-deposit corrosion over the WBE.

  17. Bridge maintenance to enhance corrosion resistance and performance of steel girder bridges

    Science.gov (United States)

    Moran Yanez, Luis M.

    The integrity and efficiency of any national highway system relies on the condition of the various components. Bridges are fundamental elements of a highway system, representing an important investment and a strategic link that facilitates the transport of persons and goods. The cost to rehabilitate or replace a highway bridge represents an important expenditure to the owner, who needs to evaluate the correct time to assume that cost. Among the several factors that affect the condition of steel highway bridges, corrosion is identified as the main problem. In the USA corrosion is the primary cause of structurally deficient steel bridges. The benefit of regular high-pressure superstructure washing and spot painting were evaluated as effective maintenance activities to reduce the corrosion process. The effectiveness of steel girder washing was assessed by developing models of corrosion deterioration of composite steel girders and analyzing steel coupons at the laboratory under atmospheric corrosion for two alternatives: when high-pressure washing was performed and when washing was not considered. The effectiveness of spot painting was assessed by analyzing the corrosion on steel coupons, with small damages, unprotected and protected by spot painting. A parametric analysis of corroded steel girder bridges was considered. The emphasis was focused on the parametric analyses of corroded steel girder bridges under two alternatives: (a) when steel bridge girder washing is performed according to a particular frequency, and (b) when no bridge washing is performed to the girders. The reduction of structural capacity was observed for both alternatives along the structure service life, estimated at 100 years. An economic analysis, using the Life-Cycle Cost Analysis method, demonstrated that it is more cost-effective to perform steel girder washing as a scheduled maintenance activity in contrast to the no washing alternative.

  18. Corrosion protection performance of palm and mineral oil media

    International Nuclear Information System (INIS)

    Wan Nik Sani, W.B.; Ani, F.N.; Masjuki, H.H.

    2002-01-01

    In European forest, especially Scandinavian, almost all forest machines are filled with biodegradable fluid. The fluid is of synthetic type. The ratio between the lowest cost of mineral oil and the synthetic fluid is about 1:4. The high cost of this biodegradable fluid can be a major obstacle to be used in developing countries. Malaysia and South East Asia are known for its natural beauties. However, a spill of mineral based oils to their land and seas may result in long term water and soil contamination. Thus crop or agricultural based oil product can provide the solution to this problem. However, considering the demand placed on the oil in service, the service performance such as relation to component compatibility with the crop based oil is crucial to be investigated. The ability of crop based oils to protect and reduce corrosion formation is still unexplored. It is important for each oil to preserve its oxidation stability and remain non-corrosive during service. This paper reports the results of copper corrosion tests. The test includes mass change monitoring, oxide scales and microscopic analysis using Scanning Electron Microscope (SEM). Relative Increase of total acid number and weight loss during copper immersion has proved that metal corrosion in contact with oil was caused by oil degradation that produces acidic compounds. Coppers that were immersed in oil temperature of 60 0 C show that increase of temperature in presence of transition metal induces oil degradation. (Author)

  19. Evaluating Steam Generator Tubing Corrosion through Shutdown Nickel and Cobalt Releases

    International Nuclear Information System (INIS)

    Marks, Chuck; Little, Mike; Krull, Peter; Dennis Hussey; Kenny Epperson

    2012-09-01

    During power operation in PWRs, steam generator tubing corrodes. In PWRs with nickel alloy steam generator tubing this leads to the release of nickel into the coolant. While not structurally significant, this process leads to corrosion product deposition on the fuel surfaces that can threaten fuel integrity, provide a site for boron precipitation, and, through activation and subsequent release, lead to increased out-of-core radiation fields. During shutdown, decreases in temperature and pH and an increase in the oxidation potential lead to dissolution of some corrosion products from the core. This work evaluated the masses of corrosion products released during shutdown as a proxy for steam generator tubing corrosion rates. The masses were evaluated for trends with time (e.g., the number of cycles) and for the influence of design and operating features such as tubing manufacturer, plant design (e.g., three loop versus four loop), and operating chemistry program. This project utilized the EPRI PWR Chemistry Monitoring and Assessment database. Data from over 20 units, many over several cycles, were assessed. The focus was on corrosion product release from Alloy 690TT tubing and all data were from units that had replaced steam generators. Data were analyzed using models developed from corrosion rate test data reported in the literature with a heavy reliance on data from the EDF BOREAL testing. The most striking result of this analysis was a clear division between plants that exhibited corrosion with a falling rate (i.e., following an exponential decay as has been observed, for example, in the BOREAL testing) and those that showed a constant corrosion rate, sustained for many outages. This difference appears to be most closely correlated with the manufacturer of the tubing. Within the two distinct plant groups (decaying corrosion rate and constant corrosion rate), details of the trends were evaluated for correlation with zinc addition history, plant type, and operating

  20. Morphology evaluation of ZrO2 dip coating on mild steel and its corrosion performance in NaOH solution

    Science.gov (United States)

    Anwar, M. A.; Kurniawan, T.; Asmara, Y. P.; Harun, W. S. W.; Oumar, A. N.; Nandyanto, A. B. D.

    2017-10-01

    In this work, the morphology of ZrO2 thin film from dip coating process on mild steel has been investigated. Mild steel was dip-coated on solution made of zirconium butoxide as a precursor, ethanol as solvent, acetylacetone as chelating agent and water for hydrolysis. Number of dipping was adjusted at 3, 5 and 7 times. The dipped sample then annealed at 350°C for two hours by adjusting the heating rate at 1°C/min respectively. The optical microscope showed that micro-cracks were observed on the surface of the coating with its concentration reduced as dipping sequence increased. The XRD result showed that annealing process can produce polycrystalline tetragonal-ZrO2. Meanwhile, SEM image showed that the thicknesses of the ZrO2 coatings were in between 400-600 nm. The corrosion resistance of uncoated and coated substrates was studied by polarization test through potentio-dynamic polarization curve at 1mV/s immersed in with 3.5% NaCl. The coating efficiency was improved as the number of layer dip coated increased, which showed improvement in corrosion protection.

  1. Corrosion behavior of boride layers evaluated by the EIS technique

    Energy Technology Data Exchange (ETDEWEB)

    Campos, I. [Instituto Politecnico Nacional. SEPI-ESIME U.P. Adolfo Lopez Mateos, Zacatenco, Mexico D.F. 07738 (Mexico)], E-mail: icampos@ipn.mx; Palomar-Pardave, M. [Universidad Autonoma Metropolitana-Azcapotzalco, Materials Department, Avenue San Pablo 180 Col. Reynosa Tamaulipas, Mexico D.F. 02200 (Mexico); Amador, A. [Tecnologico de Monterrey, Campus Ciudad de Mexico, Calle del Puente 222 Col. Ejidos de Huipulco, Mexico D.F. 14380 (Mexico); VillaVelazquez, C. [Instituto Politecnico Nacional. SEPI-ESIME U.P. Adolfo Lopez Mateos, Zacatenco, Mexico D.F. 07738 (Mexico); Hadad, J. [Tecnologico de Monterrey, Campus Ciudad de Mexico, Calle del Puente 222 Col. Ejidos de Huipulco, Mexico D.F. 14380 (Mexico)

    2007-09-30

    The corrosion behavior of boride layers at the AISI 304 steel surface is evaluated in the present study. Electrochemical impedance spectroscopy (EIS) technique was used for the evaluation of the polarization resistance at the steel surface, with the aid of AUTOLAB potentiostat. Samples were treated with boron paste thickness of 4 and 5 mm, in the range of temperatures 1123 {<=} T {<=} 1273 K and exposed time of 4 and 6 h. The electrochemical technique employed 10 mV AC with a frequency scan range from 8 kHz to 3 mHz in deaerated 0.1 M NaCl solution. Nyquist diagrams show that the highest values of corrosion resistance are present in the samples borided at the temperature of 1273 K, with treatment time of 4 h and 4 mm of boron paste thickness. The values of corrosion resistance on borided steels are compared with the porosity exhibited in the layers.

  2. Methods to Evaluate Corrosion in Buried Steel Structures: A Review

    Directory of Open Access Journals (Sweden)

    Lorena-de Arriba-Rodriguez

    2018-05-01

    Full Text Available Around the world, there are thousands of metal structures completely or partially buried in the soil. The main concern in their design is corrosion. Corrosion is a mechanism that degrades materials and causes structural failures in infrastructures, which can lead to severe effects on the environment and have direct impact on the population health. In addition, corrosion is extremely complex in the underground environment due to the variability of the local conditions. The problem is that there are many methods to its evaluation but none have been clearly established. In order to ensure the useful life of such structures, engineers usually consider an excess thickness that increases the economic cost of manufacturing and does not satisfy the principles of efficiency in the use of resources. In this paper, an extended revision of the existing methods to evaluate corrosion is carried out to optimize the design of buried steel structures according to their service life. Thus, they are classified into two categories depending on the information they provide: qualitative and quantitative methods. As a result, it is concluded that the most exhaustive methodologies for estimating soil corrosion are quantitative methods fed by non-electrochemical data based on experimental studies that measure the mass loss of structures.

  3. Evaluation of stress corrosion crack growth in BWR piping systems

    International Nuclear Information System (INIS)

    Kassir, M.; Sharma, S.; Reich, M.; Chang, M.T.

    1985-05-01

    This report presents the results of a study conducted to evaluate the effects of stress intensity factor and environment on the growth behavior of intergranular stress corrosion cracks in type 304 stainless steel piping systems. Most of the detected cracks are known to be circumferential in shape, and initially started at the inside surface in the heat affected zone near girth welds. These cracks grow both radially in-depth and circumferentially in length and, in extreme cases, may cause leakage in the installation. The propagation of the crack is essentially due to the influence of the following simultaneous factors: (1) the action of applied and residual stress; (2) sensitization of the base metal in the heat affected zone adjacent to girth weld; and (3) the continuous exposure of the material to an aggressive environment of high temperature water containing dissolved oxygen and some levels of impurities. Each of these factors and their effects on the piping systems is discussed in detail in the report. The report also evaluates the time required for hypothetical cracks in BWR pipes to propagate to their critical size. The pertinent times are computed and displayed graphically. Finally, parametric study is performed in order to assess the relative influence and sensitivity of the various input parameters (residual stress, crack growth law, diameter of pipe, initial size of defect, etc.) which have bearing on the growth behavior of the intergranular stress corrosion cracks in type 304 stainless steel. Cracks in large-diameter as well as in small-diameter pipes are considered and analyzed. 27 refs., 25 figs., 10 tabs

  4. Corrosion performance of tube support materials

    International Nuclear Information System (INIS)

    Malagola, P.

    1985-01-01

    The problem of denting in steam generators leads to change in the conception of the tube support plates. A new material is now used for this component, a 13% Cr steel, which composition has been adjusted for weldability and mechanical resistance criteria. The geometry of trefoil support plate (TSP) has also been improved, using a broached TSP (quadrifoiled holes) instead of a drilled TSP. Tests have been performed on 13% Cr and C-steel broached TSP, and drilled TSP, to confirm the better resistance to denting of this new configuration

  5. Corrosion Evaluation of INTEC Waste Storage Tank WM-182

    International Nuclear Information System (INIS)

    Dirk, W. J.; Anderson, P. A.

    1999-01-01

    Irradiated nuclear fuel has been stored and reprocessed at the Idaho National Engineering and Environmental Laboratory since 1953 using facilities located at the Idaho Nuclear Technology and Engineering Center (INTEC). This reprocessing produced radioactive liquid waste which was stored in the Tank Farm. The INTEC Tank Farm consists of eleven vaulted 300,000-gallon underground tanks including Tank WM-182. Tank WM-182 was put into service in 1955, has been filled four times, and has contained aluminum and zirconium fuel reprocessing wastes as well as sodium bearing waste. A program to monitor corrosion in the waste tanks was initiated in 1953 when the first of the eleven Tank Farm tanks was placed in service. Austenitic stainless steel coupons representative of the materials of construction of the tanks are used to monitor internal tank corrosion. This report documents the final inspection of the WM-182 corrosion coupons. Physical examination of the welded corrosion test coupons exposed to the tank bottom conditions of Tank WM-182 revealed very light uniform corrosion. Examination of the external surfaces of the extruded pipe samples showed very light uniform corrosion with slight indications of preferential attack parallel to extrusion marks and start of end grain attack of the cut edges. These indications were only evident when examined under stereo microscope at magnifications of 20X and above. There were no definite indications of localized corrosion, such as cracking, pitting, preferential weld attack, or weld heat affected zone attack on either the welded or extruded coupons. Visual examination of the coupon support cables, where they were not encased in plastic, failed to reveal any indication of liquid-liquid interface attack of any crevice corrosion. Based on the WM-182 coupon evaluations, which have occurred throughout the life of the tank, the metal loss from the tank wall due to uniform corrosion is not expected to exceed 5.5 x 10-1 mil (0.00 055 inch

  6. Evaluation of corrosion inhibitors for high temperature decontamination applications

    International Nuclear Information System (INIS)

    Sathyaseelan, V.S.; Rufus, A.L.; Velmurugan, S.

    2015-01-01

    Normally, chemical decontamination of coolant systems of nuclear power reactors is carried out at temperatures less than 90 °C. At these temperatures, though magnetite dissolves effectively, the rate of dissolution of chromium and nickel containing oxides formed over stainless steel and other non-carbon steel coolant system surfaces is not that appreciable. A high temperature dissolution process using 5 mM NTA at 160 °C developed earlier by us was very effective in dissolving the oxides such as ferrites and chromites. However, the corrosion of structural materials such as carbon steel (CS) and stainless steel (SS) also increased beyond the acceptable limits at elevated temperatures. Hence, the control of base metal corrosion during the high temperature decontamination process is very important. In view of this, it was felt essential to investigate and develop a suitable inhibitor to reduce the corrosion that can take place on coolant structural material surfaces during the high temperature decontamination applications with weak organic acids. Three commercial inhibitors viz., Philmplus 5K655, Prosel PC 2116 and Ferroqest were evaluated at ambient and at 160 °C temperature in NTA formulation. Preliminary evaluation of these corrosion inhibitors carried out using electrochemical techniques showed maximum corrosion inhibition efficiency for Philmplus. Hence, it was used for high temperature applications. A concentration of 500 ppm was found to be optimum at 160 °C and at this concentration it showed an inhibition efficiency of 62% for CS. High temperature dissolution of oxides such as Fe 3 O 4 and NiFe 2 O 4 , which are relevant to nuclear reactors, was also carried out and the rate of dissolution observed was less in the presence of Philmplus. Studies were also carried out to evaluate hydrazine as a corrosion inhibitor for high temperature applications. The results revealed that for CS inhibition efficiency of hydrazine is comparable to that of Philmplus, while

  7. General corrosion, irradiation-corrosion, and environmental-mechanical evaluation of nuclear-waste-package structural-barrier materials. Progress report

    International Nuclear Information System (INIS)

    Westerman, R.E.; Pitman, S.G.; Nelson, J.L.

    1982-09-01

    Pacific Northwest Laboratory is studying the general corrosion, irradiation-corrosion, and environmentally enhanced crack propagation of five candidate materials in high-temperature aqueous environments simulating those expected in basalt and tuff repositories. The materials include three cast ferrous materials (ductile cast iron and two low-alloy Cr-Mo cast steels) and two titanium alloys, titanium Grade 2 (commercial purity) and Grade 12 (a Ti-Ni-Mo alloy). The general corrosion results are being obtained by autoclave exposure of specimens to slowly replenished simulated ground water flowing upward through a bed of the appropriate crushed rock (basalt or tuff), which is maintained at the desired test temperature (usually 250 0 C). In addition, tests are being performed in deionized water. Metal penetration rates of iron-base alloys are being derived by stripping off the corrosion product film and weighing the specimen after the appropriate exposure time. The corrosion of titanium alloy specimens is being determined by weight gain methods. The irradiation-corrosion studies are similar to the general corrosion tests, except that the specimen-bearing autoclaves are held in a 60 Co gamma radiation field at dose rates up to 2 x 10 6 rad/h. For evaluating the resistance of the candidate materials to environmentally enhanced crack propagation, three methods are being used: U-bend and fracture toughness specimens exposed in autoclaves; slow strain rate studies in repository-relevant environments to 300 0 C; and fatigue crack growth rate studies at ambient pressure and 90 0 C. The preliminary data suggest a 1-in. corrosion allowance for iron-base barrier elements intended for 1000-yr service in basalt or tuff repositories. No evidence has yet been found that titanium Grade 2 or Grade 12 is susceptible to environmentally induced crack propagation or, by extension, to stress corrosion cracking

  8. Effect of zinc injection on BWR fuel cladding corrosion. Pt. 1. Study on an accelerated corrosion condition to evaluate corrosion resistance of zircaloy-2 fuel cladding

    International Nuclear Information System (INIS)

    Kawamura, Hirotaka; Kanbe, Hiromu; Furuya, Masahiro

    2002-01-01

    Japanese BWR utilities have a plan to apply zinc injection to the primary coolant in order to reduce radioactivity accumulation on the structure. Prior to applying the zinc injection to BWR plants, it is necessary to evaluate the effect of zinc injection on corrosion resistance of fuel cladding. The objective of this report was to examine the accelerated corrosion condition for evaluation of BWR fuel cladding corrosion resistance under non-irradiated conditions, as the first step of a zinc injection evaluation study. A heat transfer corrosion test facility, in which a two phase flow condition could be achieved, was designed and constructed. The effects of heat flux, void fraction and solution temperature on BWR fuel cladding corrosion resistance were quantitatively investigated. The main findings were as follows. (1) In situ measurements using high speed camera and a void sensor together with one dimensional two phase flow analysis results showed that a two phase flow simulated BWR core condition can be obtained in the corrosion test facility. (2) The heat transfer corrosion test results showed that the thickness of the zirconium oxide layer increased with increasing solution temperature and was independent of heat flux and void fraction. The corrosion accelerating factor was about 2.5 times in the case of a temperature increase from 288degC to 350degC. (author)

  9. Stress Corrosion Evaluation of Various Metallic Materials for the International Space Station Water Recycling System

    Science.gov (United States)

    Torres, P. D.

    2015-01-01

    A stress corrosion evaluation was performed on Inconel 625, Hastelloy C276, titanium commercially pure (TiCP), Ti-6Al-4V, Ti-6Al-4V extra low interstitial, and Cronidur 30 steel as a consequence of a change in formulation of the pretreatment for processing the urine in the International Space Station Environmental Control and Life Support System Urine Processing Assembly from a sulfuric acid-based to a phosphoric acid-based solution. The first five listed were found resistant to stress corrosion in the pretreatment and brine. However, some of the Cronidur 30 specimens experienced reduction in load-carrying ability.

  10. Study on the Synthesis and Corrosion Inhibition Performance of Mannich-Modified Imidazoline

    Directory of Open Access Journals (Sweden)

    Xiangjun Kong

    2016-07-01

    Full Text Available A novel Mannich-modified imidazoline (MMI as cationic emulsifier was synthesised for corrosion harm reduction, through three steps — acylation, cyclization, and Mannich reaction. The surface activity was characterized by determination of surface tensions and critical micelle concentration (CMC. The corrosion inhibition performance of five types of steels in the simulated corrosion solution in the presence of the MMI was investigated by static weight loss tests. The results showed that the MMI had good surface activities, with CMC of 19.8 μg g−1 and surface tension of 36.4 mN m−1. The corrosion test results indicated that the corrosion rates of different materials were decreased significantly, and degrees of corrosion inhibition were always higher than 80.0 %. The main inhibition mechanism was most likely due to the adsorption of the corrosion inhibitor on the steel surface, leading to the prevention of corrosion medium from the metal surface.

  11. Evaluation and rehabilitation of corrosion damaged reinforced concrete structures

    International Nuclear Information System (INIS)

    Paul, I.S.

    1999-01-01

    For the last two decades, rehabilitation of corrosion damaged concrete structures has been one of the most important challenges faced by the construction industry throughout the world. The extent of the damage is significant in cold climates and also in hot and humid climates. In both cases, the corrosion is invariably initiated by ingress of salts into the concrete either from de-icing salts used on roads, or from salt-laden air, soils or ground water. However, there is a contrast in sites of distress in the two climatic regions mentioned above. In cold climates, where de-icing salts are used, the damage is generally to superstructures and is therefore visible, but in hot, humid coastal regions damage is primarily in the substructures and may not be so clearly apparent. This paper presents the corrosion mechanism in concrete deterioration, the methods of evaluation of the damaged structures, and rehabilitation strategies. A case history of a concrete rehabilitation project is included together with some lessons learned in rehabilitation of corrosion damaged structures. Recommendations are made for maintenance of concrete structures and a warning is issued that salt run-off from roads in cold climates may cause distress in below ground concrete structures, similar to structures in hot and humid climates with saline groundwater and soils. (author)

  12. Evaluation of Corrosion of Aluminum Based Reactor Fuel Cladding Materials During Dry Storage

    International Nuclear Information System (INIS)

    Peacock, H.B. Jr.

    1999-01-01

    This report provides an evaluation of the corrosion behavior of aluminum cladding alloys and aluminum-uranium alloys at conditions relevant to dry storage. The details of the corrosion program are described and the results to date are discussed

  13. Evaluation of High Temperature Corrosion Resistance of Finned Tubes Made of Austenitic Steel And Nickel Alloys

    Directory of Open Access Journals (Sweden)

    Turowska A.

    2016-06-01

    Full Text Available The purpose of the paper was to evaluate the resistance to high temperature corrosion of laser welded joints of finned tubes made of austenitic steel (304,304H and nickel alloys (Inconel 600, Inconel 625. The scope of the paper covered the performance of corrosion resistance tests in the atmosphere of simulated exhaust gases of the following chemical composition: 0.2% HCl, 0.08% SO2, 9.0% O2 and N2 in the temperature of 800°C for 1000 hours. One found out that both tubes made of austenitic steel and those made of nickel alloy displayed good resistance to corrosion and could be applied in the energy industry.

  14. Evaluation of the electrical conductivity and corrosion resistance for layers deposited via sputtering on stainless steel

    Science.gov (United States)

    Blanco, J.; Salas, Y.; Jiménez, C.; Pineda, Y.; Bustamante, A.

    2017-12-01

    In some Engineering fields, we need that conductive materials have a mechanic performance and specific electrical for that they maintain conditions or corrosive attack if they are in the environment or if they are closed structure. The stainless steels have an inert film on their surface and it has the function to act in contrast to external agents who generates the corrosion, especially for stings, spoiling the film until to fail. We found a solution taking into account the electrical performance and the anticorrosive; into the process we put recovering of specific oxides on, stainless steel using the method of sputtering with Unbalanced Magnetron, (UBM) varying the oxygen in the reactive environment. The coating obtained had a thickness one micron approximately and we saw on serious structural uniformity [1]. The corrosion resistance was evaluated through the potentiodynamics polarization and electrochemical spectroscopy impedance in NACL according to the standard. The cathode protection is the most important method employed for the corrosion prevention of metallic structures in the soil or immersed on the water. The electrical resistivity was evaluated with the four points methods and it showed a behaviour of diode type in some substrates with a threshold potential in several volts. We noticed a simple resistance solution when it was analysed in the Nyquist graphics whit the Electrochemical Impedance Spectroscopy technique. With on equivalent circuit, for this reason we determinate a variation in the corrosion speed in almost two orders of magnitude when we analysed the potentiodynamics curve by Tafel approximation. The data obtained and analysed show that this type of surface modification maintains the conductivity condition at the interface, improving the resistance in relation whit the corrosion of these elements where the recovering allowed the ionic flow wished for overcoming threshold voltage, acting as an insulator in different cases.

  15. Stress Corrosion Evaluation of Nitinol 60 for the International Space Station Water Recycling System

    Science.gov (United States)

    Torres, P. D.

    2016-01-01

    A stress corrosion cracking (SCC) evaluation of Nitinol 60 was performed because this alloy is considered a candidate bearing material for the Environmental Control and Life Support System (ECLSS), specifically in the Urine Processing Assembly of the International Space Station. An SCC evaluation that preceded this one during the 2013-2014 timeframe included various alloys: Inconel 625, Hastelloy C-276, titanium (Ti) commercially pure (CP), Ti 6Al-4V, extra-low interstitial (ELI) Ti 6Al-4V, and Cronidur 30. In that evaluation, most specimens were exposed for a year. The results of that evaluation were published in NASA/TM-2015-218206, entitled "Stress Corrosion Evaluation of Various Metallic Materials for the International Space Station Water Recycling System,"1 available at the NASA Scientific and Technical Information program web page: http://www.sti.nasa.gov. Nitinol 60 was added to the test program in 2014.

  16. Corrosion performance of advanced structural materials in sodium.

    Energy Technology Data Exchange (ETDEWEB)

    Natesan, K.; Momozaki, Y.; Li, M.; Rink, D.L. (Nuclear Engineering Division)

    2012-05-16

    This report gives a description of the activities in design, fabrication, construction, and assembling of a pumped sodium loop for the sodium compatibility studies on advanced structural materials. The work is the Argonne National Laboratory (ANL) portion of the effort on the work project entitled, 'Sodium Compatibility of Advanced Fast Reactor Materials,' and is a part of Advanced Materials Development within the Reactor Campaign. The objective of this project is to develop information on sodium corrosion compatibility of advanced materials being considered for sodium reactor applications. This report gives the status of the sodium pumped loop at Argonne National Laboratory, the specimen details, and the technical approach to evaluate the sodium compatibility of advanced structural alloys. This report is a deliverable from ANL in FY2010 (M2GAN10SF050302) under the work package G-AN10SF0503 'Sodium Compatibility of Advanced Fast Reactor Materials.' Two reports were issued in 2009 (Natesan and Meimei Li 2009, Natesan et al. 2009) which examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design specifications for the ANL pumped loop for testing advanced structural materials. Available information was presented on solubility of several metallic and nonmetallic elements along with a discussion of the possible mechanisms for the accumulation of impurities in sodium. That report concluded that the solubility of many metals in sodium is low (<1 part per million) in the temperature range of interest in sodium reactors and such trace amounts would not impact the mechanical integrity of structural materials and components. The earlier report also analyzed the solubility and transport mechanisms of nonmetallic elements such as oxygen, nitrogen, carbon, and hydrogen in laboratory sodium loops and in reactor systems such as Experimental Breeder Reactor-II, Fast Flux

  17. Corrosion performance of advanced structural materials in sodium

    International Nuclear Information System (INIS)

    Natesan, K.; Momozaki, Y.; Li, M.; Rink, D.L.

    2012-01-01

    This report gives a description of the activities in design, fabrication, construction, and assembling of a pumped sodium loop for the sodium compatibility studies on advanced structural materials. The work is the Argonne National Laboratory (ANL) portion of the effort on the work project entitled, 'Sodium Compatibility of Advanced Fast Reactor Materials,' and is a part of Advanced Materials Development within the Reactor Campaign. The objective of this project is to develop information on sodium corrosion compatibility of advanced materials being considered for sodium reactor applications. This report gives the status of the sodium pumped loop at Argonne National Laboratory, the specimen details, and the technical approach to evaluate the sodium compatibility of advanced structural alloys. This report is a deliverable from ANL in FY2010 (M2GAN10SF050302) under the work package G-AN10SF0503 'Sodium Compatibility of Advanced Fast Reactor Materials.' Two reports were issued in 2009 (Natesan and Meimei Li 2009, Natesan et al. 2009) which examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design specifications for the ANL pumped loop for testing advanced structural materials. Available information was presented on solubility of several metallic and nonmetallic elements along with a discussion of the possible mechanisms for the accumulation of impurities in sodium. That report concluded that the solubility of many metals in sodium is low (<1 part per million) in the temperature range of interest in sodium reactors and such trace amounts would not impact the mechanical integrity of structural materials and components. The earlier report also analyzed the solubility and transport mechanisms of nonmetallic elements such as oxygen, nitrogen, carbon, and hydrogen in laboratory sodium loops and in reactor systems such as Experimental Breeder Reactor-II, Fast Flux Test Facility, and

  18. Evaluation of Corrosion Inhibitors as Lubricity Improvers

    Science.gov (United States)

    1988-07-01

    Whatman, obtained from Alltech Associates). 10 The mobile phase compositions evaluated included blends of methanol, isopropanol, and aqueous buffers...developed takes advantage of the unique properties of the CI components and the ability of RPHPLC to resolve those components. All of the approved CI

  19. Corrosion evaluation of alloys for nuclear waste processing

    International Nuclear Information System (INIS)

    Corbett, R.A.; Bickford, D.F.; Morrison, W.S.

    1986-01-01

    Corrosion scouting tests were performed on stainless steel and nickel-based alloys in simulated process solutions to be used in a facility to immobilize high-level radioactive waste by incorporating it into borosilicate glass. Alloys with combined chromium plus molybdenum contents >30% and also >9% molybdenum, were the most resistant to general and local attack. Alloy C-276 was selected as the reference process equipment material, with Alloy 690 and ALLCORR selected for specific applications

  20. Evaluation of Flow Accelerated Corrosion of Carbon Steel with Rotating Cylinder

    International Nuclear Information System (INIS)

    Park, Tae Jun; Lee, Eun Hee; Kim, Kyung Mo; Kim, Hong Pyo

    2012-01-01

    Flow accelerated corrosion (FAC) of the carbon steel piping in nuclear power plants (NPPs) has been major issue in nuclear industry. Rotating cylinder FAC test facility was designed and fabricated and then performance of the facility was evaluated. The facility is very simple in design and economic in fabrication and can be used in material and chemistry screening test. The facility is equipped with on line monitoring of pH, conductivity, dissolved oxygen(DO), and temperature. Fluid velocity is controlled with rotating speed of the cylinder with a test specimen. FAC test of SA106 Gr. B carbon steel under 4 m/s flow velocity was performed with the rotating cylinder at DO concentration of less than 1 ppb and of 1.3 ppm. Also a corrosion test of the carbon steel at static condition, that is at zero fluid velocity, of test specimen and solution was performed at pH from 8 to 10 for comparison with the FAC data. For corrosion test in static condition, the amount of non adherent corrosion product was almost constant at pH ranging from 8 to 10. But adherent corrosion product decreased with increasing pH. This trend is consistent with decrease of Fe solubility with an increase in pH. For FAC test with rotating cylinder FAC test facility, the amount of non adherent corrosion product was also almost same for both DO concentrations. The rotating cylinder FAC test facility will be further improved by redesigning rotating cylinder and FAC specimen geometry for future work

  1. Evaluation of new technology for detection of erosion-corrosion

    International Nuclear Information System (INIS)

    Walker, S.M.; Martinez, E.

    1994-01-01

    Faster and more accurate methods of wall thickness measurement have received considerable attention by utilities. Examination without removing insulation has been of particularly high interest because insulation removal is the largest component of the inspection cost. Several inspection systems have been developed which are touted as applicable to erosion corrosion detection through insulation. The Electric Power Research Institute (EPRI) Nondestructive Evaluation (NDE) Center has recently evaluated two of these systems. During the evaluation, accuracy and repeatability measurements were made on insulated pipe of known thickness

  2. Corrosion Protection of Al Alloys for Aircraft by Coatings With Advanced Properties and Enhanced Performance

    National Research Council Canada - National Science Library

    Bierwagen, Gordon; Croll, Stuart; Webster, Dean; Tallman, Dennis; Huo, Qun; Allahar, Brian; Su, Quan; Bonitz, Verena; Fernando, Dilhan; Wang, Duhua

    2007-01-01

    The report presents research that addresses research performed at NDSU for environmentally compliant corrosion protection in coatings systems of greatly extended lifetimes for present and future aircraft...

  3. Microstructural evaluation of the lacquered layer quality after corrosion load

    Directory of Open Access Journals (Sweden)

    Jaroslava Svobodova

    2015-03-01

    Full Text Available Surface pre-treatment is one of the most important steps before applying the final surface treatment. These pre-treatments, like phosphating, alkaline degreasing, pickling in acids, is used to remove impurities from the surface of the base material and to create appropri-ate conditions for adhesion of the final coating (metal coatings, organic coatings. Currently are on the rise surface treatments technologies, which are based on nanotechnology. It's a new generation of chemical products for the chemical surface preparation. This paper deals with the evaluation of microstructure of painted sheet metal after corrosion load with salt spray in the corrosion chamber. Metal sheets used for the experiment have been produced from low-carbon non alloy steel. For pre-treatment of the sheet metal was used alkaline degreasing (CC, iron phosphating (Feph and nanotechnology based product Alfipas (Zr in combinations: group A - CC + Zr, group B - Feph + Zr and group C - CC + Feph + Zr. The aim of this paper is to analyze the behavior of painted sheet metal after corrosion load and evaluate the effect of pretreatment to resistance of painted surface layer.

  4. Quantitative evaluation of safety use limit for crevice corrosion in Ni-Cr-Mo alloys

    International Nuclear Information System (INIS)

    Fukaya, Yuichi; Akashi, Masatsune; Sasaki, Hidetsugu; Tsujikawa, Shigeo

    2007-01-01

    The most important problem with corrosion-resistant alloys such as stainless steels is localized corrosion. Crevice corrosion, which is a typical localized corrosion, occurs under the mildest environmental conditions. Consequently, whether crevice corrosion occurs or not is an important issue in structural material selection. This study investigated highly corrosion-resistant Ni-Cr-Mo alloys whose resistance for crevice corrosion is difficult to evaluate with the JIS G 0592 standard for common strainless steels. The optimized procedures for determining the critical potential and temperature for crevice corrosion of the alloys were developed based on the JIS method. The limits of safety usage of various Ni-Cr-Mo alloys were evaluated quantitatively in chloride solution environments. (author)

  5. Evaluation of corrosion characteristics of SMART materials (III)

    International Nuclear Information System (INIS)

    Jeong, Y. H.; Park, S. Y.; Baek, J. H.; Choi, B. K.; Park, J. Y.; Lee, M. H.; Kim, J. H.; Bang, J. G.

    2006-02-01

    The corrosion characteristics of materials (Low-Sn Zircaloy-4, Zr-1.0Nb, PT-7M, ASTM Gr. 2 Ti, Inconel-690 alloys) for cladding and heat-exchanger tubes of SMART were evaluated in ammonia aqueous solution contained recirculating loop of pH 9.98 at 360 .deg. C 300 .deg. C. And CEDM materials (ball bearing, ball screw, magnetic material) were evaluated in ammonia aqueous solution contained static autoclave of pH 9.98 at 120 .deg. C

  6. Finite element evaluation of erosion/corrosion affected reducing elbow

    International Nuclear Information System (INIS)

    Basavaraju, C.

    1996-01-01

    Erosion/corrosion is a primary source for wall thinning or degradation of carbon steel piping systems in service. A number of piping failures in the power industry have been attributed to erosion/corrosion. Piping elbow is one of such susceptible components for erosion/corrosion because of increased flow turbulence due to its geometry. In this paper, the acceptability of a 12 in. x 8 in. reducing elbow in RHR service water pump discharge piping, which experienced significant degradation due to wall thinning in localized areas, was evaluated using finite element analysis methodology. Since the simplified methods showed very small margin and recommended replacement of the elbow, a detailed 3-D finite element model was built using shell elements and analyzed for internal pressure and moment loadings. The finite element analysis incorporated the U.T. measured wall thickness data at various spots that experienced wall thinning. The results showed that the elbow is acceptable as-is until the next fuel cycle. FEA, though cumbersome, and time consuming is a valuable analytical tool in making critical decisions with regard to component replacement of border line situation cases, eliminating some conservatism while not compromising the safety

  7. Performance of RC columns with partial length corrosion

    International Nuclear Information System (INIS)

    Wang Xiaohui; Liang Fayun

    2008-01-01

    Experimental and analytical studies on the load capacity of reinforced concrete (RC) columns with partial length corrosion are presented, where only a fraction of the column length was corroded. Twelve simply supported columns were eccentrically loaded. The primary variables were partial length corrosion in tensile or compressive zone and the corrosion level within this length. The failure of the corroded column occurs in the partial length, mainly developed from or located nearby or merged with the longitudinal corrosion cracks. For RC column with large eccentricity, load capacity of the column is mainly influenced by the partial length corrosion in tensile zone; while for RC column with small eccentricity, load capacity of the column greatly decreases due to the partial length corrosion in compressive zone. The destruction of the longitudinally mechanical integrality of the column in the partial length leads to this great reduction of the load capacity of the RC column

  8. Evaluation of the protection behaviour of reinforcement steel against corrosion induced by chlorides in reinforced mortar specimens

    International Nuclear Information System (INIS)

    Crivelaro, Marcos

    2002-01-01

    In this work various treatments for protecting reinforcing steels against corrosion induced by chlorides have been evaluated. Additives to mortars and surface treatments given to reinforcing steels were evaluated as corrosion protection measures. In the preliminary tests the corrosion resistance of a CA 50 steel treated by immersion in nearly 50 different solutions, was determined. The solutions were prepared with tannins (from various sources) and/or benzotriazole, and during immersion, a surface film formed on the steel. The corrosion resistance of the coated steels was evaluated in a saturated Ca(OH) 2 solution with 5% (wt) NaCl. Preliminary tests were also carried out with mortars reinforced with uncoated steel to which tannin or lignin was added. Two organic coatings, a monocomponent and a bicomponent type, formulated specially for this investigation, with both tannin and benzotriazole, were also tested in the preliminary tests to select the coating with better corrosion protection property. The bicomponent type (epoxy coating) showed better performance than the monocomponent type coating, and the former was therefore chosen to investigate the corrosion performance on CA 50 steel inside mortar specimens. From the preliminary tests, two solutions with tannin from two sources, Black Wattle (Acacia mearnsii) and Brazilian tea (Ilex paraguariensis St. Hill), to which benzotriazole and phosphoric acid were added, were chosen. Mortar specimens reinforced with CA50 steel treated by immersion in these two solutions were prepared. Also, epoxy coated CA50 steel was tested as reinforcement inside mortar specimens. Mortars reinforced with uncoated CA50 steel were also prepared and corrosion tested for comparison. The effect of tannin and lignin as separate additives to the mortar on the corrosion resistance of uncoated steel was also studied. The reinforced mortar specimens were tested with various cycles of immersion for 2 days in 3.5% (wt) NaCl followed by with air

  9. Evaluation of the flow-accelerated corrosion downstream of an orifice. 2. Measurement of corrosion rate and evaluation on the effects of the flow field

    International Nuclear Information System (INIS)

    Nagaya, Yukinori; Utanohara, Yoichi; Nakamura, Akira; Murase, Michio

    2008-01-01

    In this study, in order to evaluate the effects of flow field on corrosion rate due to flow accelerated corrosion (FAC), a corrosion rate downstream of an orifice was measured using the electric resistance method. The diameter of the pipe is 50 mm and that of the orifice is 24.3 mm, and flow velocity of the experimental loop was set at 5m/s, and the temperature of water was controlled within ±1 at 150deg-C. There were no significant circumferential difference in measured corrosion rate, and the maximum corrosion rate was observed at 1D or 2D downstream from the orifice. The ratios of the measured corrosion rate and the calculated wall shear stress at the 1D downstream from the orifice to the value at upstream under well developed flow agreed well. (author)

  10. Evaluation of erosion-corrosion resistance in Fe-Mn-Al austenitic steels

    Directory of Open Access Journals (Sweden)

    William Arnulfo Aperador

    2013-04-01

    Full Text Available In this paper, the effects of Mn and Al against corrosion/errosion resistance of three samples of the Fe-Mn-Al austenitic alloys are evaluated. The samples have composition Fe-(4,9 ~ 11,0 wt. (% Al-(17,49 ~ 34,3 wt. (% Mn-(0,43 ~ 1,25 wt. (%C, those were prepared in an induction furnace from high purity materials. The alloys were evaluated in a composed solution of NaCl 0,5 M and Silica in a special chamber and AISI 316 stainless steel as reference material. The electrochemical characterization was performed by Tafel curve polarizations technique. This microstructural characterization was by Scanning Electron Microscopy (SEM. It was observed the significant decrease in the corrosion rate for steels Fermanal with a lower percentage of aluminum and manganese under conditions of dynamic corrosion and erosion-corrosion. SEM allows assessment of the dominant damage mechanisms and corroborated the results obtained by electrochemical measurements.

  11. Ultimate strength performance of tankers associated with industry corrosion addition practices

    Directory of Open Access Journals (Sweden)

    Kim Do Kyun

    2014-09-01

    Full Text Available In the ship and offshore structure design, age-related problems such as corrosion damage, local denting, and fatigue damage are important factors to be considered in building a reliable structure as they have a significant influence on the residual structural capacity. In shipping, corrosion addition methods are widely adopted in structural design to prevent structural capacity degradation. The present study focuses on the historical trend of corrosion addition rules for ship structural design and investigates their effects on the ultimate strength performance such as hull girder and stiffened panel of double hull oil tankers. Three types of rules based on corrosion addition models, namely historic corrosion rules (pre-CSR, Common Structural Rules (CSR, and harmonised Common Structural Rules (CSRH are considered and compared with two other corrosion models namely UGS model, suggested by the Union of Greek Shipowners (UGS, and Time-Dependent Corrosion Wastage Model (TDCWM. To identify the general trend in the effects of corrosion damage on the ultimate longitudinal strength performance, the corrosion addition rules are applied to four representative sizes of double hull oil tankers namely Panamax, Aframax, Suezmax, and VLCC. The results are helpful in understanding the trend of corrosion additions for tanker structures

  12. Ultimate strength performance of tankers associated with industry corrosion addition practices

    Directory of Open Access Journals (Sweden)

    Do Kyun Kim

    2014-09-01

    Full Text Available In the ship and offshore structure design, age-related problems such as corrosion damage, local denting, and fatigue damage are important factors to be considered in building a reliable structure as they have a significant influence on the residual structural capacity. In shipping, corrosion addition methods are widely adopted in structural design to prevent structural capacity degradation. The present study focuses on the historical trend of corrosion addition rules for ship structural design and investigates their effects on the ultimate strength performance such as hull girder and stiffened panel of double hull oil tankers. Three types of rules based on corrosion addition models, namely historic corrosion rules (pre-CSR, Common Structural Rules (CSR, and harmonised Common Structural Rules (CSRH are considered and compared with two other corrosion models namely UGS model, suggested by the Union of Greek Shipowners (UGS, and Time-Dependent Corrosion Wastage Model (TDCWM. To identify the general trend in the effects of corrosion damage on the ultimate longitudinal strength performance, the corrosion addition rules are applied to four representative sizes of double hull oil tankers namely Panamax, Aframax, Suezmax, and VLCC. The results are helpful in understanding the trend of corrosion additions for tanker structures.

  13. Evaluation method of corrosive conditions in cooling systems of nuclear power plants by combined analyses of flow dynamics and corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Uchida, Shunsuke [Nuclear Power Engineering Corporation (NUPEC), Tokyo (Japan); Atomic Energy Society of Japan (AESJ) (Japan). Research Committee on Water Chemistry Standard; Naitoh, Masanori [Nuclear Power Engineering Corporation (NUPEC), Tokyo (Japan); Atomic Energy Society of Japan (AESJ) (Japan). Computational Science and Engineering Div.; Uehara, Yasushi; Okada, Hidetoshi [Nuclear Power Engineering Corporation (NUPEC), Tokyo (Japan); Hotta, Koji [ITOCHU Techno-Solutions Corporation (Japan); Ichikawa, Ryoko [Mizuho Information and Research Inst., Inc. (Japan); Koshizuka, Seiichi [Tokyo Univ. (Japan)

    2007-03-15

    Problems in major components and structural materials in nuclear power plants have often been caused by flow induced vibration, corrosion and their overlapping effects. In order to establish safe and reliable plant operation, it is necessary to predict future problems for structural materials based on combined analyses of flow dynamics and corrosion and to mitigate them before they become serious issues for plant operation. The analysis models are divided into two types. 1. Prediction models for future problems with structural materials: Distributions of oxidant concentrations along flow paths are obtained by solving water radiolysis reactions in the boiling water reactor (BWR) primary cooling water and hydrazine-oxygen reactions in the pressurized water reactor (PWR) secondary cooling water. Then, the electrochemical corrosion potential (ECP) at the point of interest is also obtained by the mixed potential model using oxidant concentration. Higher ECP enhances the possibility of intergranular stress corrosion cracking (IGSCC) in the BWR primary system, while lower ECP enhances flow accelerated corrosion (FAC) in the PWR secondary system. 2. Evaluation models of wall thinning caused by flow accelerated corrosion: The degree of wall thinning is evaluated at a location with a higher possibility of FAC occurrence, and lifetime is estimated for preventive maintenance. General features of models are reviewed in this paper and the prediction models for oxidant concentrations are briefly introduced. (orig.)

  14. Evaluation method of corrosive conditions in cooling systems of nuclear power plants by combined analyses of flow dynamics and corrosion

    International Nuclear Information System (INIS)

    Uchida, Shunsuke; Hotta, Koji; Ichikawa, Ryoko; Koshizuka, Seiichi

    2007-01-01

    Problems in major components and structural materials in nuclear power plants have often been caused by flow induced vibration, corrosion and their overlapping effects. In order to establish safe and reliable plant operation, it is necessary to predict future problems for structural materials based on combined analyses of flow dynamics and corrosion and to mitigate them before they become serious issues for plant operation. The analysis models are divided into two types. 1. Prediction models for future problems with structural materials: Distributions of oxidant concentrations along flow paths are obtained by solving water radiolysis reactions in the boiling water reactor (BWR) primary cooling water and hydrazine-oxygen reactions in the pressurized water reactor (PWR) secondary cooling water. Then, the electrochemical corrosion potential (ECP) at the point of interest is also obtained by the mixed potential model using oxidant concentration. Higher ECP enhances the possibility of intergranular stress corrosion cracking (IGSCC) in the BWR primary system, while lower ECP enhances flow accelerated corrosion (FAC) in the PWR secondary system. 2. Evaluation models of wall thinning caused by flow accelerated corrosion: The degree of wall thinning is evaluated at a location with a higher possibility of FAC occurrence, and lifetime is estimated for preventive maintenance. General features of models are reviewed in this paper and the prediction models for oxidant concentrations are briefly introduced. (orig.)

  15. Improving corrosion resistance of post-tensioned substructures emphasizing high performance grouts

    Science.gov (United States)

    Schokker, Andrea Jeanne

    The use of post-tensioning in bridges can provide durability and structural benefits to the system while expediting the construction process. When post-tensioning is combined with precast elements, traffic interference can be greatly reduced through rapid construction. Post-tensioned concrete substructure elements such as bridge piers, hammerhead bents, and straddle bents have become more prevalent in recent years. Chloride induced corrosion of steel in concrete is one of the most costly forms of corrosion each year. Coastal substructure elements are exposed to seawater by immersion or spray, and inland bridges may also be at risk due to the application of deicing salts. Corrosion protection of the post-tensioning system is vital to the integrity of the structure because loss of post-tensioning can result in catastrophic failure. Documentation for durability design of the grout, ducts, and anchorage systems is very limited. The objective of this research is to evaluate the effectiveness of corrosion protection measures for post-tensioned concrete substructures by designing and testing specimens representative of typical substructure elements using state-of-the-art practices in aggressive chloride exposure environments. This was accomplished through exposure testing of twenty-seven large-scale beam specimens and ten large-scale column specimens. High performance grout for post-tensioning tendon injection was also developed through a series of fresh property tests, accelerated exposure tests, and a large-scale pumping test to simulate field conditions. A high performance fly ash grout was developed for applications with small vertical rises, and a high performance anti-bleed grout was developed for applications involving large vertical rises such as tall bridge piers. Long-term exposure testing of the beam and column specimens is ongoing, but preliminary findings indicate increased corrosion protection with increasing levels of post-tensioning, although traditional

  16. Evaluation of taper joints with combined fatigue and crevice corrosion testing: Comparison to human explanted modular prostheses

    Energy Technology Data Exchange (ETDEWEB)

    Reclaru, L., E-mail: lucien.reclaru@pxgroup.com [PX Group S.A., Dep R and D Corrosion and Biocompatibility Group, Bd. des Eplatures 42, CH-2304 La Chaux-de-Fonds (Switzerland); Brooks, R.A. [Orthopaedic Research, Addenbrooke' s Hospital, University of Cambridge, Box 180 Hills Road, CB2 0QQ Cambridge (United Kingdom); Zuberbühler, M. [Smith and Nephew Orthopaedics AG, Schachenalle 29, 5001 Aarau (Switzerland); Eschler, P.-Y.; Constantin, F. [PX Group S.A., Dep R and D Corrosion and Biocompatibility Group, Bd. des Eplatures 42, CH-2304 La Chaux-de-Fonds (Switzerland); Tomoaia, G. [University of Medicine and Pharmacy Iuliu Hateganu of Cluj-Napoca, Dept. of Orthopaedics and Traumatology, Cluj-Napoca (Romania)

    2014-01-01

    The requirement for revision surgery of total joint replacements is increasing and modular joint replacement implants have been developed to provide adjustable prosthetic revision systems with improved intra-operative flexibility. An electrochemical study of the corrosion resistance of the interface between the distal and proximal modules of a modular prosthesis was performed in combination with a cyclic fatigue test. The complexity resides in the existence of interfaces between the distal part, the proximal part, and the dynamometric screw. A new technique for evaluating the resistance to cyclic dynamic corrosion with crevice stimulation was used and the method is presented. In addition, two components of the proximal module of explanted Ti6Al4V and Ti6Al7Nb prostheses were investigated by optical and electron microscopy. Our results reveal that: The electrolyte penetrates into the interface between the distal and proximal modules during cyclic dynamic fatigue tests, the distal module undergoes cracking and corrosion was generated at the interface between the two models; The comparison of the explanted proximal parts with the similar prostheses evaluated following cyclic dynamic crevice corrosion testing showed that there were significant similarities indicating that this method is suitable for evaluating materials used in the fabrication of modular prostheses. - Highlights: • Electrochemical crevice corrosion testing combined with fatigue test conducted on Ti6Al7Nb and Ti6Al4V modular prostheses • Cations released from integral prostheses • Comparison of human explanted modular prostheses with the similar prostheses evaluated in cyclic dynamic crevice corrosion.

  17. Corrosion performance of some titanium-based hard coatings

    International Nuclear Information System (INIS)

    Matthes, B.; Broszeit, E.; Aromaa, J.; Ronkainen, H.; Hannula, S.P.; Leyland, A.; Matthews, A.

    1991-01-01

    Tools and machine parts which could benefit from wear-resistant titanium-based hard films are often subject to corrosive environments. Physically vapour-deposited coatings frequently exhibit porosity and even small defects, which can cause rapid local corrosion of the substrate material; there is therefore a requirement for dense and chemically inert coatings. This paper presents corrosion data for titanium-based hard coatings such as TiN, (Ti, Al)N, Ti(B, N) and TiB 2 and also for multilayered structures where additional aluminium-based insulating surface layers (AlN and Al 2 O 3 ) were deposited. The corrosion resistance and porosity of the films were analysed by electrochemical techniques. The degree of metallic bonding can play a significant role in influencing the corrosion resistance of refractory transition-metal-based ceramic coatings. Here we demonstrate that, under potentiodynamic corrosion test conditions, resistance to corrosive attack was relatively poor for TiB 2 , better for (Ti, Al)N and Ti(B, N) and best for TiN. It is also shown that applying the additional protective aluminium-based insulating surface layers on the coating can further improve corrosion resistance. (orig.)

  18. An evaluation of corrosion resistant alloys by field corrosion test in Japanese refuse incineration plants

    International Nuclear Information System (INIS)

    Kawahara, Yuuzou; Nakamura, Masanori; Shibuya, Eiichi; Yukawa, Kenichi

    1995-01-01

    As the first step for development of the corrosion resistant superheater tube materials of 500 C, 100 ata used in high efficient waste-to-energy plants, field corrosion tests of six conventional alloys were carried out at metal temperatures of 450 C and 550 C for 700 and 3,000 hours in four typical Japanese waste incineration plants. The test results indicate that austenitic alloys containing approximately 80 wt% [Cr+Ni] show excellent corrosion resistance. When the corrosive environment is severe, intergranular corrosion of 40∼200 microm depth occurs in stainless steel and high alloyed materials. It is confirmed quantitatively that corrosion behavior is influenced by environmental corrosion factors such as Cl concentration and thickness of deposits on tube surface, metal temperature, and flue gas temperature. The excellent corrosion resistance of high [Cr+Ni+Mo] alloys such as Alloy 625 is explained by the stability of its protective oxide, such that the time dependence of corrosion nearly obeys the parabolic rate law

  19. Atmospheric corrosion performance of different steels in early exposure in the coastal area region West Java, Indonesia

    Science.gov (United States)

    Nuraini, Lutviasari; Prifiharni, Siska; Priyotomo, Gadang; Sundjono, Gunawan, Hadi; Purawiardi, Ibrahim

    2018-05-01

    The performance of carbon steel, galvanized steel and aluminium after one month exposed in the atmospheric coastal area, which is in Limbangan and Karangsong Beach, West Java, Indonesia was evaluated. The corrosion rate was determined by weight loss method and the morphology of the steel after exposed was observed by Scanning Electron Microscopy(SEM)/Energy Dispersive X-Ray Analysis(EDX). The site was monitored to determine the chloride content in the marine atmosphere. Then, the corrosion products formed at carbon steel were characterized by X-Ray diffraction (XRD). The result showed the aggressively corrosion in Karangsong beach, indicated from the corrosion rate of carbon steel, galvanized steel and aluminium were 38.514 mpy; 4.7860 mpy and 0.5181 mpy, respectively. While in Limbangan Beach the corrosion rate of specimen carbon steel, galvanized steel and aluminium were 3.339; 0.219 and 0.166 mpy, respectively. The chloride content was found to be the main factor that influences in the atmospheric corrosion process in this area. Chloride content accumulated in Karangsong and Limbangan was 497 mg/m2.day and 117 mg/m2.day, respectively. The XRD Analysis on each carbon steel led to the characterization of a complex mixture of iron oxides phases.

  20. Stress corrosion cracking evaluation of precipitation-hardening stainless steel

    Science.gov (United States)

    Humphries, T. S.; Nelson, E. E.

    1970-01-01

    Accelerated test program results show which precipitation hardening stainless steels are resistant to stress corrosion cracking. In certain cases stress corrosion susceptibility was found to be associated with the process procedure.

  1. Self-cleaning performance of superhydrophobic hybrid nanocomposite coatings on Al with excellent corrosion resistance

    International Nuclear Information System (INIS)

    Raj, V.; Mohan Raj, R.

    2016-01-01

    Highlights: • Ceramic-poly(Ani-co-oPD) coatings were formed on Al by anodization and electro-polymerisation techniques. • The superhydrophobic coating was fabricated on copolymer by electrodeposition of zinc stearate. • The superhydrophobicity mechanism relies on morphologies and chemical components on surface is the key factor. • Ceramic-poly(Ani-co-oPD)-zinc stearate coated Al has excellent corrosion resistance and good self-cleaning performance. - Abstract: Protective ceramic-PANI, ceramic-poly(Ani-co-oPD) and ceramic-poly(Ani-co-oPD)-zinc stearate nanocomposite coatings were formed on Al surface by the processes involving anodization, electropolymerisation and electrodeposition under optimum conditions. The prepared nanocomposite coatings were evaluated by ATR-IR and XRD studies. SEM studies performed on nanocomposite coatings reveal that ceramic-poly(Ani-co-oPD)-zinc stearate nanocomposite coating shows a cauliflower-like cluster with crack-free morphology compared to ceramic-PANI and ceramic-poly(Ani-co-oPD) nanocomposite coatings. The mechanical properties of different nanocomposite coatings were measured using Vicker microhardness tester and Taber Abrasion tester. The ceramic-poly(Ani-co-oPD)-zinc stearate nanocomposite has higher mechanical stability. The corrosion resistance of the coatings measured by Tafel polarization and electrochemical impedance spectroscopy, shows that ceramic-poly(Ani-co-oPD)-zinc stearate nanocomposite coated aluminum has higher corrosion resistance than other coatings and bare Al. Wettability studies prove that superhydrophobic nature of ceramic-poly(Ani-co-oPD)-zinc stearate nanocomposite coating with contact angle of 155.8° is responsible for good self-cleaning property and excellent corrosion resistance of aluminum.

  2. Self-cleaning performance of superhydrophobic hybrid nanocomposite coatings on Al with excellent corrosion resistance

    Energy Technology Data Exchange (ETDEWEB)

    Raj, V., E-mail: alaguraj2@rediffmail.com; Mohan Raj, R., E-mail: chem_mohan@rediffmail.com

    2016-12-15

    Highlights: • Ceramic-poly(Ani-co-oPD) coatings were formed on Al by anodization and electro-polymerisation techniques. • The superhydrophobic coating was fabricated on copolymer by electrodeposition of zinc stearate. • The superhydrophobicity mechanism relies on morphologies and chemical components on surface is the key factor. • Ceramic-poly(Ani-co-oPD)-zinc stearate coated Al has excellent corrosion resistance and good self-cleaning performance. - Abstract: Protective ceramic-PANI, ceramic-poly(Ani-co-oPD) and ceramic-poly(Ani-co-oPD)-zinc stearate nanocomposite coatings were formed on Al surface by the processes involving anodization, electropolymerisation and electrodeposition under optimum conditions. The prepared nanocomposite coatings were evaluated by ATR-IR and XRD studies. SEM studies performed on nanocomposite coatings reveal that ceramic-poly(Ani-co-oPD)-zinc stearate nanocomposite coating shows a cauliflower-like cluster with crack-free morphology compared to ceramic-PANI and ceramic-poly(Ani-co-oPD) nanocomposite coatings. The mechanical properties of different nanocomposite coatings were measured using Vicker microhardness tester and Taber Abrasion tester. The ceramic-poly(Ani-co-oPD)-zinc stearate nanocomposite has higher mechanical stability. The corrosion resistance of the coatings measured by Tafel polarization and electrochemical impedance spectroscopy, shows that ceramic-poly(Ani-co-oPD)-zinc stearate nanocomposite coated aluminum has higher corrosion resistance than other coatings and bare Al. Wettability studies prove that superhydrophobic nature of ceramic-poly(Ani-co-oPD)-zinc stearate nanocomposite coating with contact angle of 155.8° is responsible for good self-cleaning property and excellent corrosion resistance of aluminum.

  3. An evaluation of highly insulated cold zinc roofs in a moderate humid region - Part II: Corrosion behavior of zinc sheeting

    NARCIS (Netherlands)

    Zheng, R.; Janssens, A.; Carmeliet, J.; Bogaerts, W.; Hens, H.

    2004-01-01

    In a previous paper [Zheng et al., Hygrothermal Performance, Part I; Const Building Mater, Vol. 18, Issue 1, pp. 49-59], the hygrothermal performances of four well-insulated cold zinc roofs were evaluated. This paper investigates the corrosion behavior of the zinc sheeting used in the roofs. The

  4. Corrosion and corrosion control

    International Nuclear Information System (INIS)

    Khanna, A.S.; Totlani, M.K.

    1995-01-01

    Corrosion has always been associated with structures, plants, installations and equipment exposed to aggressive environments. It effects economy, safety and product reliability. Monitoring of component corrosion has thus become an essential requirement for the plant health and safety. Protection methods such as appropriate coatings, cathodic protection and use of inhibitors have become essential design parameters. High temperature corrosion, especially hot corrosion, is still a difficult concept to accommodate in corrosion allowance; there is a lack of harmonized system of performance testing of materials at high temperatures. In order to discuss and deliberate on these aspects, National Association for Corrosion Engineers International organised a National Conference on Corrosion and its Control in Bombay during November 28-30, 1995. This volume contains papers presented at the symposium. Paper relevant to INIS is indexed separately. refs., figs., tabs

  5. Corrosion performance of prestressing strands in contact with dissimilar grouts.

    Science.gov (United States)

    2013-01-01

    To improve the corrosion protection provided to prestressing strands, anti-bleed grouts are used to fill voids in post-tensioning : ducts that result from bleeding and shrinkage of older Portland Cement grouts. Environmental differences caused by exp...

  6. Corrosion performance of 7075 alloy under laser heat treatment

    Science.gov (United States)

    Liu, Tong; Su, Ruiming; Qu, Yingdong; Li, Rongde

    2018-05-01

    Microstructure, exfoliation corrosion (EXCO), intergranular corrosion (IGC) and potentidynamic polarization test of the 7075 aluminum alloy after retrogression and re-aging (RRA) treatment, and laser retrogression and re-aging (LRRA), respectively, were studied by using scanning electron microscope, and transmission electron microscope (TEM). The results show that after pre-aging, laser treatment (650 W, 2 mm s‑1) and re-aging a lot of matrix precipitates of alloy were precipitated again. The semi-continuous grain boundary precipitates and the wider precipitate-free zones (PFZ) improve the corrosion resistance of the alloy. The corrosion properties of the alloy after LRRA (650 W, 2 mm s‑1) treatment are better than that after RRA treatment.

  7. Intelligent Evaluation Method of Tank Bottom Corrosion Status Based on Improved BP Artificial Neural Network

    Science.gov (United States)

    Qiu, Feng; Dai, Guang; Zhang, Ying

    According to the acoustic emission information and the appearance inspection information of tank bottom online testing, the external factors associated with tank bottom corrosion status are confirmed. Applying artificial neural network intelligent evaluation method, three tank bottom corrosion status evaluation models based on appearance inspection information, acoustic emission information, and online testing information are established. Comparing with the result of acoustic emission online testing through the evaluation of test sample, the accuracy of the evaluation model based on online testing information is 94 %. The evaluation model can evaluate tank bottom corrosion accurately and realize acoustic emission online testing intelligent evaluation of tank bottom.

  8. Corrosion Performance of New Generation Aluminum-Lithium Alloys for Aerospace Applications

    Science.gov (United States)

    Moran, James P.; Bovard, Francine S.; Chrzan, James D.; Vandenburgh, Peter

    Over the past several years, a new generation of aluminum-lithium alloys has been developed. These alloys are characterized by excellent strength, low density, and high modulus of elasticity and are therefore of interest for lightweight structural materials applications particularly for construction of current and future aircraft. These new alloys have also demonstrated significant improvements in corrosion resistance when compared with the legacy and incumbent alloys. This paper documents the superior corrosion resistance of the current commercial tempers of these materials and also discusses the corrosion performance as a function of the degree of artificial aging. Results from laboratory corrosion tests are compared with results from exposures in a seacoast atmosphere to assess the predictive capability of the laboratory tests. The correlations that have been developed between the laboratory tests and the seacoast exposures provide confidence that a set of available methods can provide an accurate assessment of the corrosion performance of this new generation of alloys.

  9. Development of corrosion testing equipment under heat transfer and irradiation conditions to evaluate corrosion resistance of materials used in acid recovery evaporator. Contract research

    International Nuclear Information System (INIS)

    Motooka, Takafumi; Numata, Masami; Kiuchi, Kiyoshi

    2002-01-01

    We have been evaluated the safety for corrosion of various metals applied to acid recovery evaporators by the mock-up tests using small scaled equipment and the reference tests in laboratories with small specimens. These tests have been conducted under-radioactive environment. The environment in practical reprocessing plants has many radioactive species. Therefore, the effect of irradiation on corrosion should be evaluated in detail. In this study, we have developed the corrosion testing equipment, which is employed to simulate environments in the acid recovery evaporators. This report describes the specification of corrosion testing equipment and the results of primary, reference and hot tests. Using the equipment, the corrosion test under heat transfer and irradiation conditions have been carried out for 930 hours in safety. It is expectable that useful corrosion test data in radioactive environment are accumulated with this equipment in future, and help the adequate choice of corrosion test condition in laboratories. (author)

  10. Influence of nanoclay particles modification by polyester-amide hyperbranched polymer on the corrosion protective performance of the epoxy nanocomposite

    International Nuclear Information System (INIS)

    Ganjaee Sari, M.; Ramezanzadeh, B.; Shahbazi, M.; Pakdel, A.S.

    2015-01-01

    Highlights: • Nanoclay particles were modified with polyester-amide hyperbranched polymer. • Epoxy/clay nanocomposites were prepared using modified clay particles. • Surface modification enhanced the clay particles exfoliation properties. • Surface modified clay particles enhanced corrosion resistance of the epoxy coating. - Abstract: Surface modification of nanoclay particles was carried out by various amounts of polyester-amide hyperbranched polymer (HBP). Thermal gravimetric analysis and X-ray diffraction analysis were performed to estimate the efficiency of the HPB grafting on the clay particles. Epoxy/clay nanocomposites were prepared by addition of 1 wt.% unmodified and modified clays. The corrosion protection properties of the nanocomposites were evaluated by electrochemical impedance spectroscopy (EIS). Results revealed that surface modification of the clay particles by HBP caused significant enhancement of the epoxy coating corrosion resistance especially when the ‘polymer/clay’ ratios were 10/1 and 5/1

  11. Evaluation of Corrosion Resistance of Titanium Alloys Used for Medical Implants

    Directory of Open Access Journals (Sweden)

    Szewczenko J.

    2016-06-01

    Full Text Available The study presents the results of investigations of modeling the usable properties of implant surfaces made of Ti6Al7Nb alloy, using the example of a dynamic hip screw (DHS applied in surgical treatment of intertrochanteric femoral neck fractures. Numerical simulation has been performed for the model load of femoral fixation with DHS screw. The load simulation results provided the basis to select mechanical properties of the fixator elements and to define those fixation areas which are mostly susceptible to development of corrosion. The surfaces of Ti6Al7Nb alloy were ground, vibro-abrasive machined, mechanically polished, sandblasted, anode oxidized at different voltage values and steam sterilized. Results of surface topography evaluation, resistance to pitting and crevice corrosion as well as degradation kinetics of the outer layer were presented. Usability of the formed passive layer in clinical applications was evaluated through wear and corrosion tests of the femoral fixation model. The test results proved usefulness of the proposed surface modification methods for clinical application of different size and shape implants

  12. Evaluations of corrosion resistance of Ni-Cr plated and Zn-plated Fe Substrates Using an Electrolytic Corrosion Test

    International Nuclear Information System (INIS)

    Lee, Jaebong; Kim, Kyungwook; Park, Minwoo; Song, Taejun; Lee, Chaeseung; Lee, Euijong; Kim, Sangyeol

    2013-01-01

    An Eectrolytic Corrosion(EC) test method was evaluated by the comparison with Copper Accelerated Acetic Salt Spray(CASS) and Neutral Salt Spray(SS) tests. Those methods were applied in order to evaluate corrosion resistance of Ni-Cr plated and Zn-plated Fe substrates. The correlations between results obtained by different test methods were investigated. Results showed that the electrochemical method such as the EC test method was superior to the conventional methods such as CASS and SS, in terms of the quantitative accuracy and the test-time span. Furthermore, the EC test method provided the useful means to estimate the initiation of corrosion of each layer by monitoring the rest potentials of the coated layers such as Ni, Cr, and Zn on Fe substrate. With regard to test time spans, the EC test provided the 78 times and 182 times faster results than the CASS test in cases of Fe + 5μm Ni + 0.5 μm Cr and Fe + 20 μm Ni + 0.5 μm Cr respectively, while the EC test was 85 times faster results than the Salt Spray test in the case of Fe + 20 g/m 2 Zn. Therefore, the EC test can be the better method to evaluate the resistance to corrosion of coated layers than the conventional methods such as the SS test and the CASS

  13. Corrosion performance of SiCsubp/6061 Al metal matrix composites in sodium chloride solution

    International Nuclear Information System (INIS)

    Mohmad Soib bin Selamat

    1995-01-01

    The corrosion performance of silicon carbide particle/aluminium metal matrix composites (SiCsubp/Al) were studied in sodium chloride solution by means of electrochemical, microscopic, gravimetric and analytical techniques. The materials under investigation were compocasting processed 6061 Al reinforced with increasing amounts of SiC particles. Potentiostatic polarization tests were done in 0.1M NaCl solutions that were aerated or deaerated to observe overall corrosion behaviour. It was seen that the corrosion potentials did not vary greatly in relation to the amounts of SiCsubp reinforcement. Corrosion tests showed that the degree of corrosion increased with increasing SiCsubp content. SEM analysis technique was used to study the corroded samples and the pitting morphology. By TEM, no intermetallic layer was found at SiC/Al interface. A model for pitting process was proposed

  14. evaluation of pawpaw leaves extract as anti-corrosion agent

    African Journals Online (AJOL)

    user

    2 DEPARTMENT OF CHEMICAL ENGINEERING, NNAMDI AZIKIWE UNIVERSITY, AWKA ... and corrosion product were analyzed using Fourier transform infrared spectrophotometer (FTIR). ... They are used as reaction vessels, pipes,.

  15. Evaluation of electrochemical techniques for measurement of fireside corrosion in thermal power plants; Utvaerdering av elektrokemiska tekniker foer maetning av roekgassidig hoegtemperaturkorrosion i pannor

    Energy Technology Data Exchange (ETDEWEB)

    Hjorrnhede, Anders

    2007-12-15

    The possibility to measure the corrosion rate on-line, in situ, is getting more and more interesting due to increased corrosion. The worsening may be a result of lower fuel quality or increased steam data due to raised efficiency demands. Also the use of inhibitors can be improved and the lifetime of important components can be increased. Today, virtually all corrosion measurements of materials used for waterwalls, superheaters, economisers and other heat-transferring surfaces are based on in-situ probe tests of coupons or rings. The aim of the project is to evaluate the practicability of commercial or semicommercial on-line in-situ corrosion probes for use in waste fired boilers. The target groups are owners of boilers, operators, service personnel but also boiler manufacturer and material producers. Since the use of on-line, in situ, corrosion probes is substantial, some of the most promising corrosion probes have been tested in a waste fired boiler in Hamburg, Germany. Tests in waste fired boiler have never before been performed. The MECO CB, a Linear Polarisation Resistance (LPR) corrosion probe from Coresto Oy, Finland was tested and from Lehrstuhl fuer Umweltverfahrenstechnik und Anlagentechnik (LUAT) der Universitaet Duisburg-Essen, Germany an Electrochemical Noise (EN) - probe was tested. From Pepperl + Fuchs both EN- and LPR-CorrTran corrosion sensors were tested. The test periods were lasting from 1050h to 3750h. The test materials were the low alloyed steel 15Mo3, the Ni-based super alloys Sanicro 63 and Haynes Hastelloy C-2000. The fluegas temperatures were 635 deg C or 520 deg C. The material temperatures were 440 deg C, 420 deg, 350 deg C and was swept from 400 deg C to 300 deg C. All probes are measuring a signal which has a correlation to the corrosion process, but the quantification procedure is not working well. The results achieved from the corrosion probes must be calibrated against corrosion rates measured by means of conventional corrosion

  16. Steam assisted oxide growth on aluminium alloys using oxidative chemistries: Part II corrosion performance

    DEFF Research Database (Denmark)

    Din, Rameez Ud; Jellesen, Morten Stendahl; Ambat, Rajan

    2015-01-01

    the protection provided by steam treatment with HNO3was a function of the concentration of NO3−ions. The coating generated by inclusion of KMnO4showed highest resistance to filiform corrosion. Overall, the performance of the steam treated surfaces under filiform corrosion and AASS test was a result of the local......Surface treatment of aluminium alloys using steam with oxidative chemistries, namely KMnO4 and HNO3 resulted in accelerated growth of oxide on aluminium alloys. Detailed investigation of the corrosion performance of the treated surfaces was carried out using potentiodynamic polarisation...

  17. Microstructural characterisation and corrosion performance of old railway girder bridge steel and modern weathering structural steel

    International Nuclear Information System (INIS)

    Tewary, N.K.; Kundu, A.; Nandi, R.; Saha, J.K.; Ghosh, S.K.

    2016-01-01

    Highlights: • Microstructure and corrosion performance are compared for two structural steels. • Microstructure evolution shows primarily ferrite-pearlite in both the steels. • Steels show higher corrosion rate in 1% HCl solution than in 3.5% NaCl solution. • The corrosion products show the presence of oxide, hydroxide and oxy-hydroxides. • The corroded surface reveals morphologies like flowery, cotton balls and rosette. - Abstract: A comparison on microstructure and corrosion performance has been made between the two structural steels used in old railway girder bridge (Sample A) and modern grades of weathering structural steel (Sample B). The microstructures, viewed under optical microscope and scanning electron microscope (SEM), show mainly ferrite-pearlite phase constituents in both the steels, A and B. The phase fraction analysis shows higher amount of pearlite in steel A compared to that of steel B. The grain size of steel A is larger than that of steel B under identical processing condition. The immersion corrosion test in 3.5% NaCl shows that the corrosion rate of steel A increases with time, while the same for steel B decreases with time. On the other hand, corrosion test in 1% HCl shows that the corrosion rate of both steel A and B is higher as compared to that of NaCl which always decreases with time. The XRD analysis of corrosion products show the presence of many oxides, hydroxide and oxy-hydroxide like Lepidocrocite (γ-FeOOH), Goethite (α-FeOOH), Akaganeite (β-FeOOH), Magnetite (Fe_3O_4) and Maghemite (γ-Fe_2O_3) in both the steels. The SEM images of corroded surfaces reveal different morphologies like flowery, cotton balls and rosette etc. which indicate that the corrosion products primarily contain Lepidocrocite (γ-FeOOH), Goethite (α-FeOOH) and Akaganeite (β-FeOOH).

  18. Promising Hard Carbon Coatings on Cu Substrates: Corrosion and Tribological Performance with Theoretical Aspect

    Science.gov (United States)

    Kumar, A. Madhan; Babu, R. Suresh; Obot, I. B.; Adesina, Akeem Yusuf; Ibrahim, Ahmed; de Barros, A. L. F.

    2018-05-01

    Protecting the surface of metals and alloys against corrosion and wear is of abundant importance owing to their widespread applications. In the present work, we report the improved anticorrosion and tribo-mechanical performance of copper (Cu) by a hard carbon (HC) coating synthesized in different pyrolysis temperature. Structural and surface characterization with roughness measurements was systematically investigated using various techniques. Effect of pyrolysis temperature on the corrosion behavior of coated Cu substrates in 0.6 M NaCl solution was evaluated via electrochemical impedance spectroscopy, potentiodynamic polarization. Pin-on-disk wear test of coated Cu substrate showed the influence of the pyrolysis temperature on the wear resistance performance of the HC coatings. According to the obtained results, it could be concluded that the HC coatings synthesized at 1100 °C revealed an enhanced comprehensive performance, revealing their possible utilization as a protective coating for Cu substrates in chloride environment. Monte Carlo simulations have been utilized to elucidate the interaction between the Cu surface and HC coatings.

  19. Six Sigma Evaluation of the High Level Waste Tank Farm Corrosion Control Program at the Savannah River Site

    International Nuclear Information System (INIS)

    Hill, P. J.

    2003-01-01

    Six Sigma is a disciplined approach to process improvement based on customer requirements and data. The goal is to develop or improve processes with defects that are measured at only a few parts per million. The process includes five phases: Identify, Measure, Analyze, Improve, and Control. This report describes the application of the Six Sigma process to improving the High Level Waste (HLW) Tank Farm Corrosion Control Program. The report documents the work performed and the tools utilized while applying the Six Sigma process from September 28, 2001 to April 1, 2002. During Fiscal Year 2001, the High Level Waste Division spent $5.9 million to analyze samples from the F and H Tank Farms. The largest portion of these analytical costs was $2.45 million that was spent to analyze samples taken to support the Corrosion Control Program. The objective of the Process Improvement Project (PIP) team was to reduce the number of analytical tasks required to support the Corrosion Control Program by 50 percent. Based on the data collected, the corrosion control decision process flowchart, and the use of the X-Y Matrix tool, the team determined that analyses in excess of the requirements of the corrosion control program were being performed. Only two of the seven analytical tasks currently performed are required for the 40 waste tanks governed by the Corrosion Control Program. Two additional analytical tasks are required for a small subset of the waste tanks resulting in an average of 2.7 tasks per sample compared to the current 7 tasks per sample. Forty HLW tanks are sampled periodically as part of the Corrosion Control Program. For each of these tanks, an analysis was performed to evaluate the stability of the chemistry in the tank and then to determine the statistical capability of the tank to meet minimum corrosion inhibitor limits. The analyses proved that most of the tanks were being sampled too frequently. Based on the results of these analyses and th e use of additional

  20. Evaluation of the reinforcing steel corrosion in concrete mixes that will be used for constructing mid activity disposal repositories

    International Nuclear Information System (INIS)

    Moreno, Manuel; Alvarez, Marta G.; Duffo, Gustavo S.

    2000-01-01

    This study presents an evaluation of the reinforcing steel bars (rebars) corrosion behavior embedded in high performance concrete's prepared with three different cement types (normal Portland, Sulfate resistant and with furnace slag). The results of the study will provide the basis to select the materials used for constructing the mid activity radioactive disposals containers. The effect of aggressive ions such as chlorides and sulfates, as well as concrete carbonation, on the rebar corrosion process is evaluated using concrete specimens containing rebar segments. The electrochemical parameters that characterize the rebar corrosion process (corrosion potential (E corr ), polarization resistance (Rp) and electrical resistivity of concrete (ρ)) where periodically monitored after a conditioning period of 100 days. The results show that under all exposure conditions evaluated the rebar segments in contact with the three concrete mixes achieve a passive state of corrosion. Due to the continuos curing process of concrete the values of ρ present an increasing trend within time, even in the specimens exposed to the immersed conditions. (author)

  1. Corrosion evaluation of metallic HLW/spent fuel disposal containers - review

    International Nuclear Information System (INIS)

    Kursten, B.; Smailos, E.; Azkarate, I.; Werme, L.; Smart, N.R.; Marx, G.; Cunado, M.A.; Santarini, G.

    2004-01-01

    Over the years a lot of investigations have been performed to choose suitable container materials and to characterize their long-term corrosion behaviour in contact with their potential disposal environments, i.e. salt, clay, and granite. Carbon steels, stainless steels, nickel-based alloys, titanium-based alloys, and copper have been widely investigated as potential container materials depending on the studied host rock formation. The results obtained in salt environments indicate that the passively corroding Ti99.8-Pd is the primary choice for the thin-walled corrosion-resistant concept, since its general corrosion rate is negligible and it is highly resistant to localized corrosion and stress corrosion cracking (SCC) in salt brines. The TStE 355 carbon steel is the first candidate for the corrosion-allowance concept because it is resistant to pitting corrosion and SCC and its general corrosion rates are sufficiently low to provide corrosion allowance acceptable for thick-walled containers. Stainless steels, Ni-based alloys, and Ti-based alloys are the most important candidate container materials in clay for the thin-walled concept, while carbon steel is considered the main choice for the thick-walled corrosion-allowance concept. Studies performed in granite seem to indicate that copper containers provide an excellent corrosion barrier with an estimated lifetime exceeding 100,000 years. The TStE 355 carbon steel is also a valid option for a thick-walled container concept in granite. In this paper, some relevant corrosion data of carbon steel and stainless steel in cementitious environments are given in addition because large amounts of concrete will be used as structural materials in most of the envisaged repository design concepts. This paper also provides recommendations for future studies. (authors)

  2. Evaluation of annual corrosion tests for aggressive water

    Science.gov (United States)

    Dubová, V.; Ilavský, J.; Barloková, D.

    2011-12-01

    Internal corrosion has a significant effect on the useful life of pipes, the hydraulic conditions of a distribution system and the quality of the water transported. All water is corrosive under some conditions, and the level of this corrosion depends on the physical and chemical properties of the water and properties of the pipe material. Galvanic treatment is an innovation for protecting against corrosion, and this method is also suitable for removal of water stone too. This method consists of the electrogalvanic principle, which is generated by the flowing of water between a zinc anode and the cupro-alloy cover of a column. This article presents experimental corrosion tests at water resource Pernek (This water resource-well marked as HL-1 is close to the Pernek of village), where the device is operating based on this principle.

  3. Corrosion performance of atmospheric plasma sprayed alumina coatings on AZ31B magnesium alloy under immersion environment

    OpenAIRE

    D. Thirumalaikumarasamy; K. Shanmugam; V. Balasubramanian

    2014-01-01

    Plasma sprayed ceramic coatings are successfully used in many industrial applications, where high wear and corrosion resistance with thermal insulation are required. The alumina powders were plasma sprayed on AZ31B magnesium alloy with three different plasma spraying parameters. In the present work, the influence of plasma spray parameters on the corrosion behavior of the coatings was investigated. The corrosion behavior of the coated samples was evaluated by immersion corrosion test in 3.5 w...

  4. Lead corrosion evaluation in high activity nuclear waste container (Argentina)

    International Nuclear Information System (INIS)

    Guasp, R.; Lanzani, L.; Bruzzoni, P.; Cufre, W.; Semino, C.J.

    2000-01-01

    This report describes a study of high activity nuclear waste canister corrosion in a deep geological disposal. In this canister design, the vitrified nuclear waste stainless steel container is shielded by a 100 mm thick lead wall. For mechanical resistance, the canister will also have a thin carbon steel external liner. Experimental and mathematical modeling studies are aimed to asses the corrosion kinetics of the carbon steel liner in first instance and then, once this liner has been corroded away, the corrosion kinetics of the main lead barrier. Being that oxygen reduction is the main cathodic reaction that supports the anodic oxidation of iron, a model is described predicting the rate of oxygen consumption in a sealed deep nuclear waste disposal vault as a result of the canister corrosion. Oxidation processes other than container corrosion, and that can account also for oxygen depletion, are not taken into consideration. Corrosion experimental studies on lead and its alloys in groundwater are also reported. These experiments are aimed to improve the corrosion resistance of commercial lead in groundwater. (author)

  5. Synthesis of Dipeptide Benzoylalanylglycine Methyl Ester and Corrosion Inhibitor Evaluation by Tafel Equation

    International Nuclear Information System (INIS)

    Abdurrahman, J.; Wahyuningrum, D.; Achmad, S.; Bundjali, B.

    2011-01-01

    Corrosion is one of the major problems in petroleum mining and processing industry. The pipelines used to transport crude oil from reservoir to the processing installation were made from carbon steel that is susceptible towards corrosion. One of the best methods to prevent corrosion that occurred at the inner parts of carbon steel pipelines is to use organic corrosion inhibitor. One of the potent organic corrosion inhibitors is amino acids derivatives. In this study, dipeptide compound namely benzoylalanylglycine methyl ester and benzoylalanylglycine have been synthesized. The structure elucidation of the products was performed by IR, MS and NMR spectroscopy. The determination of corrosion inhibition activity utilized the Tafel method. The corrosion inhibition efficiency of glycine methyl ester, benzoyl alanine, dipeptide benzoylalanylglycine methyl ester and dipeptide benzoylalanylglycine were 63.34 %, 35.86 %, 68.40 % and 27.72 %, respectively. These results showed that the formation of dipeptide benzoylalanylglycine methyl ester, derived from carboxylic protected glycine and amine protected alanine, increased the corrosion inhibition activity due to the loss of acidity center in the structure of glycine and L-alanine that would induce the corrosive environment towards carbon steel. (author)

  6. Localized corrosion of high performance metal alloys in an acid/salt environment

    Science.gov (United States)

    Macdowell, L. G.; Ontiveros, C.

    1991-01-01

    Various vacuum jacketed cryogenic supply lines at the Space Shuttle launch site at Kennedy Space Center use convoluted flexible expansion joints. The atmosphere at the launch site has a very high salt content, and during a launch, fuel combustion products include hydrochloric acid. This extremely corrosive environment has caused pitting corrosion failure in the thin walled 304L stainless steel flex hoses. A search was done to find a more corrosion resistant replacement material. The study focussed on 19 metal alloys. Tests which were performed include electrochemical corrosion testing, accelerated corrosion testing in a salt fog chamber, and long term exposure at a beach corrosion testing site. Based on the results of these tests, several nickel based alloys were found to have very high resistance to this corrosive environment. Also, there was excellent agreement between the electrochemical tests and the actual beach exposure tests. This suggests that electrochemical testing may be useful for narrowing the field of potential candidate alloys before subjecting samples to long term beach exposure.

  7. Research on Performance and Microstructure of Sewage Pipe Mortar Strengthened with Different Anti-Corrosion Technologies

    Science.gov (United States)

    Mu, Song; Zhou, Huaxin; Shi, Liang; Liu, Jianzhong; Cai, Jingshun; Wang, Feng

    2017-10-01

    Mostly urban underground sewage is the acidic corrosion environment with a high concentration of aggressive ions and microbe, which resulted in performance deterioration and service-life decrease of sewage concrete pipe. In order to effectively protect durability of the concrete pipe, the present paper briefly analysed the main degradation mechanism of concrete pipe attacked by urban underground sewage, and proposed that using penetrating and strengthening surface sealer based on inorganic chemistry. In addition, using index of compressive strength, weight loss and appearance level to investigate the influence of the sealer on corrosion resistance of mortar samples after different dry-wet cycles. Besides, comparative research on effect of the sealer, aluminate cement and admixture of corrosion resistance was also addressed. At last, the SEM technology was used to reveal the improvement mechanism of different technologies of corrosion resistance. The results indicated that the sealer and aluminate cement can significantly improve corrosion resistance of mortar. Besides, the improvement effect can be described as the descending order: the penetrating and strengthening surface sealer > aluminate cement > admixture of corrosion resistance. The mortar sample treated with the sealer displayed the condensed and sound microstructure which proved that the sealer can improve the corrosion resistance to urban underground sewage.

  8. Corrosion and mechanical performance of AZ91 exposed to simulated inflammatory conditions.

    Science.gov (United States)

    Brooks, Emily K; Der, Stephanie; Ehrensberger, Mark T

    2016-03-01

    Magnesium (Mg) and its alloys, including Mg-9%Al-1%Zn (AZ91), are biodegradable metals with potential use as temporary orthopedic implants. Invasive orthopedic procedures can provoke an inflammatory response that produces hydrogen peroxide (H2O2) and an acidic environment near the implant. This study assessed the influence of inflammation on both the corrosion and mechanical properties of AZ91. The AZ91 samples in the inflammatory protocol were immersed for three days in a complex biologically relevant electrolyte (AMEM culture media) that contained serum proteins (FBS), 150 mM of H2O2, and was titrated to a pH of 5. The control protocol immersed AZ91 samples in the same biologically relevant electrolyte (AMEM & FBS) but without H2O2 and the acid titration. After 3 days all samples were switched into fresh AMEM & FBS for an additional 3-day immersion. During the initial immersion, inflammatory protocol samples showed increased corrosion rate determined by mass loss testing, increased Mg and Al ion released to solution, and a completely corroded surface morphology as compared to the control protocol. Although corrosion in both protocols slowed once the test electrolyte solution was replaced at 3 days, the samples originally exposed to the simulated inflammatory conditions continued to display enhanced corrosion rates as compared to the control protocol. These lingering effects may indicate the initial inflammatory corrosion processes modified components of the surface oxide and corrosion film or initiated aggressive localized processes that subsequently left the interface more vulnerable to continued enhanced corrosion. The electrochemical properties of the interfaces were also evaluated by EIS, which found that the corrosion characteristics of the AZ91 samples were potentially influenced by the role of intermediate adsorption layer processes. The increased corrosion observed for the inflammatory protocol did not affect the flexural mechanical properties of the AZ91

  9. Developing a Systematic Corrosion Control Evaluation Approach in Flint

    Science.gov (United States)

    Presentation covers what the projects were that were recommended by the Flint Safe Drinking Water Task Force for corrosion control assessment for Flint, focusing on the sequential sampling project, the pipe rigs, and pipe scale analyses.

  10. Evaluation of corrosion resistance of various concrete reinforcing materials.

    Science.gov (United States)

    2013-06-01

    The Vermont Agency of Transportation undertook a simple experiment to determine the corrosion : resistance ability of various reinforcing steels (rebar) that may be used in bridges and other concrete : structures. Eight types of rebar were used in th...

  11. An Evaluation of Carbon Steel Corrosion Under Stagnant Seawater Conditions

    National Research Council Canada - National Science Library

    Lee, Jason

    2004-01-01

    Corrosion, of 1020 carbon steel coupons in, natural seawater over a six-month period was more aggressive under stagnant anaerobic conditions than stagnant aerobic conditions as measured by weight loss...

  12. Adsorption and performance of the 2-mercaptobenzimidazole as a carbon steel corrosion inhibitor in EDTA solutions

    International Nuclear Information System (INIS)

    Calderón, J.A.; Vásquez, F.A.; Carreño, J.A.

    2017-01-01

    This study presents a thermodynamic analysis of the adsorption and anti-corrosion performance of 2-mercaptobenzimidazole (2-MBI) on carbon steel in EDTA-Na2 solutions. The adsorption of the inhibitor on the metal surface was studied as a function of the concentration of the inhibiting species and the temperature of the system. The corrosion inhibition efficiency was studied by electrochemical impedance spectroscopy and mass loss tests. The results show that the adsorption of the inhibitor onto the metal surface behaves according to the Langmuir model, following an endothermic process. The inhibitor is chemically adsorbed onto the carbon steel surface. The efficiency of corrosion inhibition was above 93%, which was confirmed by both mass loss tests and the electrochemical impedance technique. The good performance of the corrosion inhibitor was maintained up to 24 h after the inhibitor was added to the corrosive EDTA-Na2 solutions. When the ratio of the volume of solution/exposed area was reduced, a decrease in the area covered by the inhibitor was observed. The best cost/benefit ratio for the corrosion protection of carbon steel was obtained when the number of moles of the inhibitor per surface area was maintained at 2.68 mmol cm"−"2. - Highlights: • Adsorption of the inhibitor on the metal surface is confirmed by thermodynamic data. • Adsorption of the inhibitor onto the metal behaves according to the Langmuir model. • Endothermic adsorption process indicates that the inhibitor is chemically adsorbed. • The efficiency of corrosion inhibition was above 93%. • The good performance of the corrosion inhibitor was maintained up to 24 h.

  13. Adsorption and performance of the 2-mercaptobenzimidazole as a carbon steel corrosion inhibitor in EDTA solutions

    Energy Technology Data Exchange (ETDEWEB)

    Calderón, J.A., E-mail: andres.calderon@udea.edu.co [Centro de Investigación, Innovación y Desarrollo de Materiales –CIDEMAT, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia); Vásquez, F.A. [Centro de Investigación, Innovación y Desarrollo de Materiales –CIDEMAT, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia); Carreño, J.A. [Laboratório de H2S, CO2 e Corrosividade, Instituto Nacional De Tecnologia (INT), Av. Venezuela, 82 – Térreo, Anexo 01, Sala 101A, Saúde, Rio de Janeiro, RJ (Brazil)

    2017-01-01

    This study presents a thermodynamic analysis of the adsorption and anti-corrosion performance of 2-mercaptobenzimidazole (2-MBI) on carbon steel in EDTA-Na2 solutions. The adsorption of the inhibitor on the metal surface was studied as a function of the concentration of the inhibiting species and the temperature of the system. The corrosion inhibition efficiency was studied by electrochemical impedance spectroscopy and mass loss tests. The results show that the adsorption of the inhibitor onto the metal surface behaves according to the Langmuir model, following an endothermic process. The inhibitor is chemically adsorbed onto the carbon steel surface. The efficiency of corrosion inhibition was above 93%, which was confirmed by both mass loss tests and the electrochemical impedance technique. The good performance of the corrosion inhibitor was maintained up to 24 h after the inhibitor was added to the corrosive EDTA-Na2 solutions. When the ratio of the volume of solution/exposed area was reduced, a decrease in the area covered by the inhibitor was observed. The best cost/benefit ratio for the corrosion protection of carbon steel was obtained when the number of moles of the inhibitor per surface area was maintained at 2.68 mmol cm{sup −2}. - Highlights: • Adsorption of the inhibitor on the metal surface is confirmed by thermodynamic data. • Adsorption of the inhibitor onto the metal behaves according to the Langmuir model. • Endothermic adsorption process indicates that the inhibitor is chemically adsorbed. • The efficiency of corrosion inhibition was above 93%. • The good performance of the corrosion inhibitor was maintained up to 24 h.

  14. Evaluation of corrosion and corrosion control on interstate 89 bridge #30 and #31.

    Science.gov (United States)

    2015-06-01

    This report summarizes the evaluation of the performance of cathodic protection installed on I-89 bridges over : Gile Pond Road (NH Route 114) during a rehabilitation project in 1987. : Control bridges of I-89 over Hominy Pot Road, approximately 1.5 ...

  15. A clustering based method to evaluate soil corrosivity for pipeline external integrity management

    International Nuclear Information System (INIS)

    Yajima, Ayako; Wang, Hui; Liang, Robert Y.; Castaneda, Homero

    2015-01-01

    One important category of transportation infrastructure is underground pipelines. Corrosion of these buried pipeline systems may cause pipeline failures with the attendant hazards of property loss and fatalities. Therefore, developing the capability to estimate the soil corrosivity is important for designing and preserving materials and for risk assessment. The deterioration rate of metal is highly influenced by the physicochemical characteristics of a material and the environment of its surroundings. In this study, the field data obtained from the southeast region of Mexico was examined using various data mining techniques to determine the usefulness of these techniques for clustering soil corrosivity level. Specifically, the soil was classified into different corrosivity level clusters by k-means and Gaussian mixture model (GMM). In terms of physical space, GMM shows better separability; therefore, the distributions of the material loss of the buried petroleum pipeline walls were estimated via the empirical density within GMM clusters. The soil corrosivity levels of the clusters were determined based on the medians of metal loss. The proposed clustering method was demonstrated to be capable of classifying the soil into different levels of corrosivity severity. - Highlights: • The clustering approach is applied to the data extracted from a real-life pipeline system. • Soil properties in the right-of-way are analyzed via clustering techniques to assess corrosivity. • GMM is selected as the preferred method for detecting the hidden pattern of in-situ data. • K–W test is performed for significant difference of corrosivity level between clusters

  16. Friction, adhesion and corrosion performance of metallurgical coatings in HTGR-helium

    International Nuclear Information System (INIS)

    Engel, R.; Kleemann, W.

    1981-01-01

    The friction-, adhesion-, thermal cycling- and corrosion performance of several metallurgical coating systems have been tested in a simulated HTGR-test atmosphere at elevated temperatures. The coatings were applied to a solid solution strengthened Ni-based superalloy. Component design requires coatings for the protection of mating surfaces, since under reactor operating conditions, contacting surfaces of metallic components under high pressures are prone to friction and wear damage. The coatings will have to protect the metal surface for 30 years up to 950 0 C in HTGR-helium. The materials tested were various refractory carbides with or without metallic binders and intermetallic compounds. The coatings evaluated were applied by plasma spraying-, detonation gun- and chemical vapor deposition techniques. These yielded two types of coatings which employ different mechanisms to improve the tribiological properties and maintain coating integrity. (Auth.)

  17. Development of stress corrosion techniques for structural integrity evaluation and life extension of PWR facilities

    International Nuclear Information System (INIS)

    Moreira, Pedro A.L.D.L. Pinheiro; Vilela, Jeferson J.; Lorenzo, Roberto F. Di; Lopes, Jadir A.M.

    2000-01-01

    The stress corrosion is a mechanism of degradation present in the nuclear plants. To extend the life of the plants components, this corrosion type it should be known. An evaluation for the implantation of methodologies of stress corrosion study in CDTN/CNEN, shows that the technique of slow deformation can be used in the evaluation of integrity structural nuclear power stations. This technique consists of straining a sample slowly, usually, in strain rate between 10 -4 and 10- 8 s -1 and in conditions that simulate the reactivity of the metal in environment (pressure, temperature, chemical composition of the water and etc) similar to the found at the nuclear power power stations. This simulation allows evaluating susceptibility the stress corrosion of components mechanical and structure that operate in central nuclear. (author)

  18. Implementation of Localized Corrosion in the Performance Assessment Model for Yucca Mountain

    International Nuclear Information System (INIS)

    Vivek Jain, S.; David Sevougian; Patrick D. Mattie; Kevin G. Mon; Robert J. Mackinnon

    2006-01-01

    A total system performance assessment (TSPA) model has been developed to analyze the ability of the natural and engineered barriers of the Yucca Mountain repository to isolate nuclear waste over the 10,000-year period following repository closure. The principal features of the engineered barrier system (EBS) are emplacement tunnels (or ''drifts'') containing a two-layer waste package (WP) for waste containment and a titanium drip shield to protect the waste package from seeping water and falling rock, The 20-mm-thick outer shell of the WP is composed of Alloy 22, a highly corrosion-resistant nickel-based alloy. The barrier function of the EBS is to isolate the waste from migrating water. The water and its associated chemical conditions eventually lead to degradation of the waste packages and mobilization of the radionuclides within the packages. There are five possible waste package degradation modes of the Alloy 22: general corrosion, microbially influenced corrosion, stress corrosion cracking, early failure due to manufacturing defects, and localized corrosion. This paper specifically examines the incorporation of the Alloy-22 localized corrosion model into the Yucca Mountain TSPA model, particularly the abstraction and modeling methodology, as well as issues dealing with scaling, spatial variability, uncertainty, and coupling to other sub-models that are part of the total system model

  19. Effect of mixed alloy combinations on fretting corrosion performance of spinal screw and rod implants.

    Science.gov (United States)

    Mali, Sachin A; Singh, Vaneet; Gilbert, Jeremy L

    2017-07-01

    Spinal implants are made from a variety of materials to meet the unique mechanical demands of each application. However, the medical device community has raised concern about mixing dissimilar metals in an implant because of fear of inducing corrosion. There is a lack of systematic studies on the effects of mixing metals on performance of spinal implants, especially in fretting corrosion conditions. Hence, the goal was to determine whether mixing stainless steel (SS316L), titanium alloy (Ti6Al4V) and cobalt chromium (CoCrMo) alloy components in a spinal implant leads to any increased risk of corrosion degradation. Spinal constructs consisting of single assembly screw-connector-rod components were tested using a novel short-term cyclic fretting corrosion test method. A total of 17 alloy component combinations (comprised of SS316L, Ti6Al4V-anodized and CoCrMo alloy for rod, screws and connectors) were tested under three anatomic orientations. Spinal constructs having all SS316L were most susceptible to fretting-initiated crevice corrosion attack and showed higher average fretting currents (∼25 - 30 µA), whereas constructs containing all Ti6Al4V components were less susceptible to fretting corrosion with average fretting currents in the range of 1 - 6 µA. Mixed groups showed evidence of fretting corrosion but they were not as severe as all SS316L group. SEM results showed evidence of severe corrosion attack in constructs having SS316L components. There also did not appear to be any galvanic effects of combining alloys together. © 2016 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 105B: 1169-1177, 2017. © 2016 Wiley Periodicals, Inc.

  20. Corrosion evaluation of traditional and new bronzes for artistic castings

    International Nuclear Information System (INIS)

    Chiavari, C.; Colledan, A.; Frignani, A.; Brunoro, G.

    2006-01-01

    By electrochemical and accelerated weathering tests, the corrosion behaviour of a new type of tin-bronze, containing about 3 wt.% silicon (SI3 bronze) was compared to a traditional 5% Sn, 5% Zn, 5% Pb bronze used for artistic castings (G85 bronze) under conditions simulating urban-industrial and marine environments. The aggressive media were: a synthetic pH 3.1 acid rain (AR) solution; a typical moist SO 2 -NO x for a climatic chamber and AR or 3.5% NaCl aqueous solution for salt spray cabinet. In all the environments the corrosion product layers formed on SI3 bronze were more uniform and protective than those formed on the traditional G85 bronze. The nature and morphology of the corrosion products were investigated by X-ray diffraction (XRD), optical and scanning electron microscopy with microprobe (SEM-EDS), atomic force microscopy (AFM)

  1. Evaluating Corrosion in SAVY Containers using Non-Destructive Techniques

    Energy Technology Data Exchange (ETDEWEB)

    Davenport, Matthew Nicholas [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Vaidya, Rajendra U. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Abeyta, Adrian Anthony [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-11-16

    Powerpoint presentation on Ultrasonic and Eddy Current NDT; UT Theory; Eddy current (ECA): How it works; Controlled Corrosion at NM Tech; Results – HCl Corrosion; Waveform Data for 10M HCl; Accuracy Statistics; Results – FeCl3 Pitting; Waveforms for Anhydrous FeCl3; Analyzing Corroded Stainless Steel 316L Plates; 316L Plate to Imitate Pitting; ECA Pit Depth Calibration Curve; C Scan Imaging; UT Pit Detection; SST Containers: Ultrasonic (UT) vs. CMM; UT Data Analysis; UT Conclusions and Observations; ECA Conclusions; Automated System Vision.

  2. Radiographic evaluation of corrosion/erosion failures in pressure vessels and pipings in fertilizer industry

    International Nuclear Information System (INIS)

    Sinha, G.S.; Sahay, K.N.; Sundaram, K.V.; Banerji, K.C.

    1977-01-01

    The uses of radiography in combating the corrosion/erosion failures of pressure equipments used in the fertilizer industry are highlighted. Premature failures in fertilizer plants have proved to be very costly. One of the principal agencies responsible for such failures in process industry is corrosion/erosion. Radiography, when supplemented with other NDT-techniques, has been found to be ideal and highly useful method for on-stream inspection and evaluation of corrosion/erosion failures of pressure vessels and pipings. Three case-histories have been presented to illustrate the importance of radiography. (author)

  3. Evaluation of hydrogen production from CO2 corrosion of steel drums in SFR, Part 2

    International Nuclear Information System (INIS)

    Dugstad, A.; Videm, K.

    1987-06-01

    An experimental program has been carried out for the investigation of the hydrogen formation due to corrosion of steel by water containing CO 2 produced by microbiologic decomposition of paper in waste drums. The hydrogen production will be limited by a limited rate of CO 2 production, as CO 2 is consumed by corrosive reactions producing carbonate containing corrosion products. Experiments indicated that also iron oxide and hydroxides were formed together with FeCO 3 at low CO 2 partial pressures but at a rate which leads to a rather slow increase in hydrogen production. Hydrogen evaluation has been overestimated in previous reports on this subject. (authors)

  4. Stress corrosion evaluation of powder metallurgy aluminum alloy 7091 with the breaking load test method

    Science.gov (United States)

    Domack, Marcia S.

    1987-01-01

    The stress corrosion behavior of the P/M aluminum alloy 7091 is evaluated in two overaged heat treatment conditions, T7E69 and T7E70, using an accelerated test technique known as the breaking load test method. The breaking load data obtained in this study indicate that P/M 7091 alloy is highly resistant to stress corrosion in both longitudinal and transverse orientations at stress levels up to 90 percent of the material yield strength. The reduction in mean breaking stress as a result of corrosive attack is smallest for the more overaged T7E70 condition. Details of the test procedure are included.

  5. The effect of Sn on autoclave corrosion performance and corrosion mechanisms in Zr–Sn–Nb alloys

    International Nuclear Information System (INIS)

    Wei, J.; Frankel, P.; Polatidis, E.; Blat, M.; Ambard, A.; Comstock, R.J.; Hallstadius, L.; Hudson, D.; Smith, G.D.W.; Grovenor, C.R.M.; Klaus, M.; Cottis, R.A.; Lyon, S.; Preuss, M.

    2013-01-01

    The desire to improve the corrosion resistance of Zr cladding material for high burn-up has resulted in a general trend among fuel manufacturers to develop alloys with reduced levels of Sn. While commonly accepted, the reason for the improved corrosion performance observed for low-tin zirconium alloys in high-temperature aqueous environments remains unclear. High-energy synchrotron X-ray diffraction was used to characterize the oxides formed by autoclave exposure on Zr–Sn–Nb alloys with tin concentration ranging from 0.01 to 0.92 wt.%. The alloys studied included the commercial alloy ZIRLO® (ZIRLO® is a registered trademark of Westinghouse Electric Company LLC in the USA and may be registered in other countries throughout the world. All rights reserved. Unauthorized use is strictly prohibited.) and two variants of ZIRLO with significantly lower tin levels, referred to here as A-0.6Sn and A-0.0Sn. The nature of the oxide grown on tube samples from each alloy was investigated via cross-sectional scanning electron microscopy. Atom probe analysis of ZIRLO demonstrated that the tin present in the alloy passes into the oxide as it forms, with no significant difference in the Sn/Zr ratio between the two. Synchrotron X-ray diffraction measurements on the oxides formed on each alloy revealed that the monoclinic and tetragonal oxide phases display highly compressive in-plane residual stresses with the magnitudes dependent on the phase and alloy. The amount of tetragonal phase present and, more importantly, the level of tetragonal-to-monoclinic phase transformation both decrease with decreasing tin levels, suggesting that tin is a tetragonal oxide phase stabilizing element. It is proposed that in Zr–Nb–Sn alloys with low Sn, the tetragonal phase is mainly stabilized by very small grain size and therefore remains stable throughout the corrosion process. In contrast, alloys with higher tin levels can in addition grow larger, stress stabilized, tetragonal grains that

  6. Corrosion performance of metals and alloys in a tuff geochemical environment

    International Nuclear Information System (INIS)

    Van Konynenburg, R.A.; McCright, R.D.

    1985-01-01

    Reference and alternate alloy systems have been chosen for use in fabricating waste packages for a potential high-level nuclear waste repository in tuff. The main corrosion concerns have been identified. Testing performed to date indicates that austenitic stainless steels woul perform well as package materials under the expected conditions as well as the less likely extreme conditions so far postulated. Carbon steel appears to be adequate as a material for borehole liners. Copper-based alloys and Zircaloys are also undergoing corrosion testing, the former as alternate package materials, and the latter because of their presence as spent fuel cladding. 17 references, 2 tables

  7. Corrosion performance of MAO coatings on AZ31 Mg alloy in simulated body fluid vs. Earle's Balance Salt Solution

    Energy Technology Data Exchange (ETDEWEB)

    Wilke, Benjamin M. [Department of Mechanical Engineering, PO Box 755905, University of Alaska Fairbanks, Fairbanks, AK 99775 (United States); Zhang, Lei, E-mail: lzhang14@alaska.edu [Department of Mechanical Engineering, PO Box 755905, University of Alaska Fairbanks, Fairbanks, AK 99775 (United States); Li, Weiping; Ning, Chengyun [School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641 (China); Chen, Cheng-fu [Department of Mechanical Engineering, PO Box 755905, University of Alaska Fairbanks, Fairbanks, AK 99775 (United States); Gu, Yanhong [College of Mechanical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617 (China)

    2016-02-15

    Graphical abstract: - Highlights: • MAO coating is deposited on AZ31 Mg alloy by microarc oxidation. • Corrosion performance of MAO-coated AZ31 in EBSS vs. c-SBF is studied. • MAO-coated AZ31 exhibits enhanced corrosion resistance compared to bare AZ31. • Samples in EBSS show slower corrosion progression than the samples in c-SBF. • CO{sub 2} buffer and less chloride in EBSS cause corrosion rate gap in c-SBF and EBSS. - Abstract: Earle's Balance Salt Solution (EBSS) provides an alternative to the conventional simulated body fluids (c-SBF) and has been shown to better simulate the corrosion conditions in vivo. In this work, a series of tests were conducted to explore the corrosion performance of MAO-coated AZ31 samples in EBSS vs. c-SBF. Samples were produced by varying MAO process parameters and then immersed up to 21 days in both EBSS and c-SBF. The corrosion rates were evaluated by the electrochemical impedance spectroscopy and potentiodynamic scanning. Scanning electron microscope (SEM) was used to compare the progression of microcracks across the surface of the coatings. The evaluation of cross-sectional thickness showed an increase in MAO coating thickness with the process voltage. MAO samples with a thicker coating generally have higher impedance and lower current density at the initial immersion time point of 0.5 h. Samples in EBSS showed higher initial impedance and lower current density values as compared to c-SBF counterparts for all process groups. Samples in EBSS demonstrated a much slower corrosion rate than c-SBF samples because of the decreased chloride content and CO{sub 2} buffering mechanism of the EBSS.

  8. Corrosion performance of MAO coatings on AZ31 Mg alloy in simulated body fluid vs. Earle's Balance Salt Solution

    International Nuclear Information System (INIS)

    Wilke, Benjamin M.; Zhang, Lei; Li, Weiping; Ning, Chengyun; Chen, Cheng-fu; Gu, Yanhong

    2016-01-01

    Graphical abstract: - Highlights: • MAO coating is deposited on AZ31 Mg alloy by microarc oxidation. • Corrosion performance of MAO-coated AZ31 in EBSS vs. c-SBF is studied. • MAO-coated AZ31 exhibits enhanced corrosion resistance compared to bare AZ31. • Samples in EBSS show slower corrosion progression than the samples in c-SBF. • CO 2 buffer and less chloride in EBSS cause corrosion rate gap in c-SBF and EBSS. - Abstract: Earle's Balance Salt Solution (EBSS) provides an alternative to the conventional simulated body fluids (c-SBF) and has been shown to better simulate the corrosion conditions in vivo. In this work, a series of tests were conducted to explore the corrosion performance of MAO-coated AZ31 samples in EBSS vs. c-SBF. Samples were produced by varying MAO process parameters and then immersed up to 21 days in both EBSS and c-SBF. The corrosion rates were evaluated by the electrochemical impedance spectroscopy and potentiodynamic scanning. Scanning electron microscope (SEM) was used to compare the progression of microcracks across the surface of the coatings. The evaluation of cross-sectional thickness showed an increase in MAO coating thickness with the process voltage. MAO samples with a thicker coating generally have higher impedance and lower current density at the initial immersion time point of 0.5 h. Samples in EBSS showed higher initial impedance and lower current density values as compared to c-SBF counterparts for all process groups. Samples in EBSS demonstrated a much slower corrosion rate than c-SBF samples because of the decreased chloride content and CO 2 buffering mechanism of the EBSS.

  9. Development of protocols for corrosion and deposits evaluation in pipes by radiography

    International Nuclear Information System (INIS)

    2005-04-01

    The International Atomic Energy Agency is promoting industrial applications of non-destructive testing (NDT) technology, which includes radiography testing (RT) and related methods, to assure safety and reliability of operation of nuclear, petrochemical and other industrial facilities. In many industries such as petroleum, power stations, refineries, petrochemical and chemical plants, desalination pipelines and urban gas installations, the reliability and safety of equipment can be substantially influenced by degradation processes such as corrosion, erosion, deposits and blocking of pipes, which can seriously affect the security and consistency. One of the most important parameters in a piping or pipeline to be monitored and measured is the wall thickness. Among NDT methods, radiography has the advantage in that in the process of an inspection it eliminates the need for the costly removal of the pipe insulation and also the added benefit that it can be carried out in high temperature environments. The Coordinated Research Project (CRP) on Validation of Protocols for Corrosion and Deposits Determination in Small Diameter Pipes by Radiography (CORDEP) was implemented from 1997 to 2000 with the participation of 11 NDT laboratories from Algeria, China, Costa Rica, France, India, Republic of Korea, Malaysia, Sri Lanka, Syrian Arab Republic, Tunisia and Turkey. The CRP tested and validated radiographic measurement of corrosion and deposits in straight and bent pipes made of carbon or stainless steels corroded/eroded on the outer or inner surfaces with or without insulation. Each participating laboratory produced three test specimens of straight and bent pipes containing natural as well as simulated corrosion defects. Typical diameters of these pipes were up to 168 mm. Radiography using X ray machines and radioisotopes of Iridium-192 and Cobalt-60 in conjunction with radiographic film using single and double wall penetrations for total inspection was performed. Selected

  10. Stress corrosion cracking evaluation of martensitic precipitation hardening stainless steels

    Science.gov (United States)

    Humphries, T. S.; Nelson, E. E.

    1980-01-01

    The resistance of the martensitic precipitation hardening stainless steels PH13-8Mo, 15-5PH, and 17-4PH to stress corrosion cracking was investigated. Round tensile and c-ring type specimens taken from several heats of the three alloys were stressed up to 100 percent of their yield strengths and exposed to alternate immersion in salt water, to salt spray, and to a seacoast environment. The results indicate that 15-5PH is highly resistant to stress corrosion cracking in conditions H1000 and H1050 and is moderately resistant in condition H900. The stress corrosion cracking resistance of PH13-8Mo and 17-4PH stainless steels in conditions H1000 and H1050 was sensitive to mill heats and ranged from low to high among the several heats included in the tests. Based on a comparison with data from seacoast environmental tests, it is apparent that alternate immersion in 3.5 percent salt water is not a suitable medium for accelerated stress corrosion testing of these pH stainless steels.

  11. The corrosion performance of microcrystalline titanium-modified 316 stainless steel

    International Nuclear Information System (INIS)

    Saito, N.; Searson, P.C.; Latanision, R.M.

    1986-01-01

    The corrosion performance of rapidly solidified (RS), consolidated RS and conventionally processed titanium-modified nuclear grade 316 stainless steel was studied. As-solidified RS foils exhibited general corrosion behavior identical to that of the conventionally processed alloy, but inferior pitting resistance, due to the presence of dendritic microsegregation. The consolidated RS alloy exhibited inferior general and pitting corrosion performance due to the detrimental effect of the prior foil boundary formed during the consolidation process. The results of immersion tests in 6% FeC1 3 .6H 2 O solution showed that pit initiation occured primarily at the prior foil boundaries in the consolidated RS alloy. Studies of sensitization were inconclusive due to preferential attack on prior foil boundaries in the consolidated RS specimens which made the determination of the degree of sensitization difficult. (author)

  12. Corrosion inhibition performance of imidazolium ionic liquids and their influence on surface ferrous carbonate layer formation

    Science.gov (United States)

    Yang, Dongrui

    Corrosion inhibitors as effective anti-corrosion applications were widely studied and drawn much attention in both academe and industrial area. In this work, a systematic work, including inhibitors selection, anti-corrosion property and characterization, influence on scale formation, testing system design and so on, were reported. The corrosion inhibition performance of four imidazolium ionic liquids in carbon dioxide saturated NaCl solution was investigated by using electrochemical and surface analysis technologies. The four compounds are 1-ethyl-3-methylimidazolium chloride (a), 1-butyl-3-methylimidazolium chloride (b), 1-hexyl-3-methylimidazolium chloride (c), 1-decyl-3-methylimidazolium chloride (d). Under the testing conditions, compound d showed the highest inhibition efficiency and selected as the main object of further study. As a selected representative formula, 1-decyl-3-methylimidazolium chloride was studied in detail about its corrosion inhibition performance on mild steel in carbon dioxide saturated NaCl brine at pH 3.8 and 6.8. Electrochemical and surface analysis techniques were used to characterize the specimen corrosion process during the immersion in the blank and inhibiting solutions. The precorrosion of specimen surface showed significant and different influences on the anti-corrosion property of DMICL at pH 3.8 and 6.8. The corrosion inhibition efficiency (IE) was calculated based on parameters obtained from electrochemical techniques; the achieved IE was higher than 98% at the 25th hour for the steel with a well-polished surface at pH 3.8. The fitting parameters obtained from electrochemical data helped to account for the interfacial changes. As proved in previous research, 1-decyl-3-methylimidazolium chloride could be used as good corrosion inhibitors under certain conditions. However, under other conditions, such chemicals, as well as other species in oil transporting system, could be a factor influencing the evolution of protective surface

  13. Evaluation of alternatives for upgrading double shell tank corrosion monitoring at Hanford

    International Nuclear Information System (INIS)

    Nelson, J.L.

    1996-01-01

    Recent discovery of low hydroxide conditions in Double Shell Tanks have demonstrated that the current corrosion control system of waste sampling and analysis is inadequate to monitor and maintain specified chemistries for dilute and low volume waste tanks. Moreover, waste sampling alone cannot provide adequate information to resolve the questions raised regarding tank corrosion. This report evaluates available technologies which could be used to improve on the existing corrosion control system. The evaluation concludes that a multi-technique corrosion monitoring system is necessary, utilizing ultrasonic and visual examinations for direct evaluation of tank liner condition, probes for rapid detection (alarm) of corrosive conditions, and waste sampling and analysis for determination of corrective action. The probes would incorporate electrochemical noise and linear polarization resistance techniques. When removed from the waste tank, the probe electrodes would be physically examined as corrosion coupons. The probes would be used in addition to a modified regimen of waste sampling and the existing schedule for ultrasonic examination of the tank liners. Supporting information would be obtained by examination of in-tank equipment as it is removed

  14. The Evaluation of the Corrosion Resistance of the Al-Si Alloys Antimony Alloyed

    Directory of Open Access Journals (Sweden)

    Svobodova J.

    2014-06-01

    Full Text Available This paper deals with the evaluation of the corrosion resistance of the Al-Si alloys alloyed with the different amount of antimony. Specifically it goes about the alloy AlSi7Mg0,3 which is antimony alloyed in the concentrations 0; 0,001; 0,005; 0,01 a 0,05 wt. % of antimony. The introduction of the paper is dedicated to the theory of the aluminium alloys corrosion resistance, testing and evaluation of the corrosion resistance. The influence of the antimony to the Al-Si alloys properties is described further in the introduction. The experimental part describes the experimental samples which were prepared for the experiment and further they were exposed to the loading in the atmospheric conditions for a period of the 3 months. The experimental samples were evaluated macroscopically and microscopically. The results of the experiment were documented and the conclusions in terms of the antimony impact to the corrosion resistance of the Al-Si alloy were concluded. There was compared the corrosion resistance of the Al-Si alloy antimony alloyed (with the different antimony content with the results of the Al-Si alloy without the alloying after the corrosion load in the atmospheric conditions in the experiment.

  15. Human Performance Evaluation System

    International Nuclear Information System (INIS)

    Hardwick, R.J. Jr.

    1985-01-01

    Operating nuclear power plants requires high standards of performance, extensive training and responsive management. Despite our best efforts inappropriate human actions do occur, but they can be managed. An extensive review of License Event Reports (LERs) was conducted which indicated continual inadequacy in human performance and in evaluation of root causes. Of some 31,000 LERs, about 5,000 or 16% were directly attributable to inappropriate actions. A recent analysis of 87 Significant Event Reports (issued by INPO in 1983) identified inappropriate actions as being the most frequent root cause (44% of the total). A more recent analysis of SERs issued in 1983 and 1984 indicate that 52% of the root causes were attributed to human performance. The Human Performance Evaluation System (HPES) is a comprehensive, coordinated utility/industry system for evaluating and reporting human performance situtations. HPES is a result of the realization that current reporting system provide limited treatment of human performance and rarely provide adequate information about root causes of inappropriate actions by individuals. The HPES was implemented to identify and eliminate root causes of inappropriate actions

  16. Performance Analysis of Retrofitted Tribo-Corrosion Test Rig for Monitoring In Situ Oil Conditions

    Directory of Open Access Journals (Sweden)

    Arpith Siddaiah

    2017-09-01

    Full Text Available Oils and lubricants, once extracted after use from a mechanical system, can hardly be reused, and should be refurbished or replaced in most applications. New methods of in situ oil and lubricant efficiency monitoring systems have been introduced for a wide variety of mechanical systems, such as automobiles, aerospace aircrafts, ships, offshore wind turbines, and deep sea oil drilling rigs. These methods utilize electronic sensors to monitor the “byproduct effects” in a mechanical system that are not indicative of the actual remaining lifecycle and reliability of the oils. A reliable oil monitoring system should be able to monitor the wear rate and the corrosion rate of the tribo-pairs due to the inclusion of contaminants. The current study addresses this technological gap, and presents a novel design of a tribo-corrosion test rig for oils used in a dynamic system. A pin-on-disk tribometer test rig retrofitted with a three electrode-potentiostat corrosion monitoring system was used to analyze the corrosion and wear rate of a steel tribo-pair in industrial grade transmission oil. The effectiveness of the retrofitted test rig was analyzed by introducing various concentrations of contaminants in an oil medium that usually leads to a corrosive working environment. The results indicate that the retrofitted test rig can effectively monitor the in situ tribological performance of the oil in a controlled dynamic corrosive environment. It is a useful method to understand the wear–corrosion synergies for further experimental work, and to develop accurate predictive lifecycle assessment and prognostic models. The application of this system is expected to have economic benefits and help reduce the ecological oil waste footprint.

  17. Performance Analysis of Retrofitted Tribo-Corrosion Test Rig for Monitoring In Situ Oil Conditions.

    Science.gov (United States)

    Siddaiah, Arpith; Khan, Zulfiqar Ahmad; Ramachandran, Rahul; Menezes, Pradeep L

    2017-09-28

    Oils and lubricants, once extracted after use from a mechanical system, can hardly be reused, and should be refurbished or replaced in most applications. New methods of in situ oil and lubricant efficiency monitoring systems have been introduced for a wide variety of mechanical systems, such as automobiles, aerospace aircrafts, ships, offshore wind turbines, and deep sea oil drilling rigs. These methods utilize electronic sensors to monitor the "byproduct effects" in a mechanical system that are not indicative of the actual remaining lifecycle and reliability of the oils. A reliable oil monitoring system should be able to monitor the wear rate and the corrosion rate of the tribo-pairs due to the inclusion of contaminants. The current study addresses this technological gap, and presents a novel design of a tribo-corrosion test rig for oils used in a dynamic system. A pin-on-disk tribometer test rig retrofitted with a three electrode-potentiostat corrosion monitoring system was used to analyze the corrosion and wear rate of a steel tribo-pair in industrial grade transmission oil. The effectiveness of the retrofitted test rig was analyzed by introducing various concentrations of contaminants in an oil medium that usually leads to a corrosive working environment. The results indicate that the retrofitted test rig can effectively monitor the in situ tribological performance of the oil in a controlled dynamic corrosive environment. It is a useful method to understand the wear-corrosion synergies for further experimental work, and to develop accurate predictive lifecycle assessment and prognostic models. The application of this system is expected to have economic benefits and help reduce the ecological oil waste footprint.

  18. Evaluation of austenitic stainless steels for transpassive corrosion by metal purification technology. Synergistic effect of Si and P on intergranular corrosion of Fe-18Cr-14Ni alloys

    International Nuclear Information System (INIS)

    Mayuzumi, Masami; Ohta, Joji; Kako, Kenji; Kawakami, Eishi

    2001-01-01

    The synergistic effect of Si, Mn, C, P, and S on the transpassive corrosion of HP18Cr-14Ni alloys was studied in 13N nitric acid. The specimens were fabricated using a cold crucible method in a high-vacuum chamber to reduce contamination. The additions of Si<1% and Mn<2% had no effect on the corrosion behavior of HP18Cr-14Ni alloys, and the addition of Si<1% also had no effect on the corrosion behavior of HP18Cr-14Ni-1Mn alloys, although 1% Si induced intergranular corrosion in both the alloys. Thus, HP18Cr-14Ni-1Mn-0.5Si alloys were selected to evaluate the effects of C, P and S (100 ppm each). The addition of P, and the co-addition of C, P, and S to HP18Cr-14Ni-1Mn-0.5Si induced intergranular corrosion of the same degree in the solution annealed condition. This result suggests the synergistic effect of Si and P to induce intergranular corrosion, since the single addition of Si or P to this level did not lead to intergranular corrosion of HP18Cr-14Ni alloys. HP18Cr-14Ni-1Mn-0.5Si alloys containing C, P, and S at the 100 ppm level each showed superior corrosion resistance compared to a commercial Type 304L in 13N nitric acid. (author)

  19. Evaluation of nitrogen containing reducing agents for the corrosion control of materials relevant to nuclear reactors

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, Padma S. [Water and Steam Chemistry Division, BARC Facilities, Kalpakkam, Tamilnadu (India); Mohan, D. [Department of Chemistry, Anna University, Chennai, Tamilnadu (India); Chandran, Sinu; Rajesh, Puspalata; Rangarajan, S. [Water and Steam Chemistry Division, BARC Facilities, Kalpakkam, Tamilnadu (India); Velmurugan, S., E-mail: svelu@igcar.gov.in [Water and Steam Chemistry Division, BARC Facilities, Kalpakkam, Tamilnadu (India)

    2017-02-01

    Materials undergo enhanced corrosion in the presence of oxidants in aqueous media. Usually, hydrogen gas or water soluble reducing agents are used for inhibiting corrosion. In the present study, the feasibility of using alternate reducing agents such as hydrazine, aqueous ammonia, and hydroxylamine that can stay in the liquid phase was investigated. A comparative study of corrosion behavior of the structural materials of the nuclear reactor viz. carbon steel (CS), stainless steel (SS-304 LN), monel-400 and incoloy-800 in the oxidizing and reducing conditions was also made. In nuclear industry, the presence of radiation field adds to the corrosion problems. The radiolysis products of water such as oxygen and hydrogen peroxide create an oxidizing environment that enhances the corrosion. Electrochemical studies at 90 °C showed that the reducing agents investigated were efficient in controlling corrosion processes in the presence of oxygen and hydrogen peroxide. Evaluation of thermal stability of hydrazine and its effect on corrosion potential of SS-304 LN were also investigated in the temperature range of 200–280 °C. The results showed that the thermal decomposition of hydrazine followed a first order kinetics. Besides, a change in electrochemical corrosion potential (ECP) was observed from −0.4 V (Vs SHE) to −0.67 V (Vs SHE) on addition of 5 ppm of hydrazine at 240 °C. Investigations were also made to understand the distribution behavior of hydrogen peroxide and hydrazine in water-steam phases and it was found that both the phases showed identical behavior. - Highlights: • Hydrazine was found to be a promising reducing agent for oxidant control. • In presence of hydrazine corrosion potential of SS304 LN was well below −230 mV. • SS304LN could be protected from IGSCC by hydrazine addition. • Thermal and radiation stability of hydrazine at 285 °C was found satisfactory.

  20. Enamel coated steel reinforcement for improved durability and life-cycle performance of concrete structures: microstructure, corrosion, and deterioration

    Science.gov (United States)

    Tang, Fujian

    This study is aimed (a) to statistically characterize the corrosion-induced deterioration process of reinforced concrete structures (concrete cracking, steel mass loss, and rebar-concrete bond degradation), and (b) to develop and apply three types of enamel-coated steel bars for improved corrosion resistance of the structures. Commercially available pure enamel, mixed enamel with 50% calcium silicate, and double enamel with an inner layer of pure enamel and an outer layer of mixed enamel were considered as various steel coatings. Electrochemical tests were respectively conducted on steel plates, smooth bars embedded in concrete, and deformed bars with/without concrete cover in 3.5 wt.% NaCl or saturated Ca(OH)2 solution. The effects of enamel microstructure, coating thickness variation, potential damage, mortar protection, and corrosion environment on corrosion resistance of the steel members were investigated. Extensive test results indicated that corrosion-induced concrete cracking can be divided into four stages that gradually become less correlated with corrosion process over time. The coefficient of variation of crack width increases with the increasing level of corrosion. Corrosion changed the cross section area instead of mechanical properties of steel bars. The bond-slip behavior between the corroded bars and concrete depends on the corrosion level and distribution of corrosion pits. Although it can improve the chemical bond with concrete and steel, the mixed enamel coating is the least corrosion resistant. The double enamel coating provides the most consistent corrosion performance and is thus recommended to coat reinforcing steel bars for concrete structures applied in corrosive environments. Corrosion pits in enamel-coated bars are limited around damage locations.

  1. Evaluation of Electrochemical Behavior of Nopal Extract (Opuntia Ficus- Indica as Possible Corrosion Inhibitor

    Directory of Open Access Journals (Sweden)

    Araceli Mandujano-Ruíz

    2017-11-01

    Full Text Available Corrosion is one of the main problems of degradation in components, tooling, equipment and even in structural applications, examples of this are the carbon steels. In the present work, the capacity of corrosion inhibition of a biodegradable organic extract from the Nopal plant (Opuntia ficus-indica, for the protection of carbon steel type AISI 1018 was studied adding 50% v/v of the Nopal extract (EN in a solution of H2SO4 (0.6 mol.l-1. Polarization Resistance (LPR and Electrochemical Impedance Spectroscopy (EIS techniques were used for the electrochemical evaluation at room temperature for 24 h in order to obtain corrosion rates (Vcorr and inhibition efficiency (IE. Metallographic examination was also carried out to register the surface damage by corrosion. The results showed a reduction of the Vcorr with a maximum IE value of about 84% by adding the organic- liquid extracted from Nopal.

  2. Acoustic emission reviling and danger level evaluation of stress corrosion cracking in stainless steel pipes

    International Nuclear Information System (INIS)

    Muravin, Gregory; Muravin, Boris; Lezvinsky, Luidmila

    2000-01-01

    Breakdowns and catastrophic damage occurring during the operation of nuclear power stations pipelines cause substantial economic and social loss annually throughout the world. Stress corrosion, vibration, fatigue, erosion, water shock, dynamic load, construction defects/errors are the main causes of pipes failures. For these reasons and in view of the age of nuclear power station pipes, there is an increased interest in finding means to prevent potential pipe failures. Nevertheless, statistical data of pipe failures continues to show significant numbers of accidents mainly due to stress corrosion cracking (about 65-80% of total number). To this end, a complex of investigations was carried out for the reliable AE diagnosis of pipes undergone stress corrosion cracking. These include: finding AE indications (fingerprints) of flaws developing in the metal in original condition as well as in metal subjected to stress corrosion; preparing AE criteria for evaluating the danger level of defects. (author)

  3. Effect of red mud addition on the corrosion parameters of reinforced concrete evaluated by electrochemical methods

    Directory of Open Access Journals (Sweden)

    D.V. Ribeiro

    Full Text Available Red mud, the main waste generated in aluminum and alumina production from bauxite ore by the Bayer process, is considered "hazardous" due to its high pH. The high pH also provides greater protection of rebars, which is reflected in the low corrosion potential and high electrical resistivity (filler effect of concrete. The corrosion potential was monitored by electrochemical measurements and the electrical resistivity was evaluated using sensors embedded in concrete test specimens. The results showed that the addition of red mud is beneficial to concrete, reducing its corrosion potential and increasing its electrical resistivity. Red mud proved to be a promising additive for concrete to inhibit the corrosion process.

  4. The influence of current collector corrosion on the performance of electrochemical capacitors

    Science.gov (United States)

    Wojciechowski, Jarosław; Kolanowski, Łukasz; Bund, Andreas; Lota, Grzegorz

    2017-11-01

    This paper discusses the effect of current collector (stainless steel 316L) corrosion on the performance of electrochemical capacitors operated in aqueous electrolytes. This topic seems to be often neglected in scientific research. The studied electrolytes were 1 M H2SO4, 1 M KI, 1 M Na2SO4, 1 M KOH and 6 M KOH. The corrosion process was investigated by means of selected direct and alternating current techniques. The surface of the current collectors as well as the corrosion products were characterised using scanning electron microscopy, energy-dispersive X-ray spectroscopy, Raman spectroscopy and atomic force microscopy. Stainless steel 316L in alkaline solutions is characterised by the lowest values of corrosion potentials whereas the potentials in acidic media become the most noble. Our studies show that corrosion potentials increase with decreasing pH value. This phenomenon can be explained with the formation of passive oxide films on the stainless steel current collectors. The passive oxide films are usually thicker and more porous in alkaline solutions than that in the other electrolytes. The processes occurring at the electrode/electrolyte interfaces strongly influence the working parameters of electrochemical capacitors such as voltage, working potentials of single electrodes, self-discharge as well as the internal resistance and cycling stability.

  5. Corrosion protection performance of waterborne epoxy coatings containing self-doped polyaniline nanofiber

    International Nuclear Information System (INIS)

    Qiu, Shihui; Chen, Cheng; Cui, Mingjun; Li, Wei; Zhao, Haichao; Wang, Liping

    2017-01-01

    Highlights: • Self-dopedpolyaniline (SPANi) with good conductivity and dispersibility in water was copolymerized by aniline and its derivative. • Environmental friendly SPANi/epoxy composite coating with remarkable anti-corrosion performance was prepared. • The corrosion product of pure epoxy or composite coating was characterized by X-ray diffraction pattern and scanning electron microscope (SEM). - Abstract: Self-doped sulfonated polyaniline (SPANi) nanofiber was synthesized by the copolymerization of 2-aminobenzenesulfonic acid (ASA) and aniline via a rapid mixing polymerization approach. The chemical structure of SPANi was investigated by the Fourier-transform infrared (FT-IR), Raman, X-ray photoelectron spectroscopy (XPS), UV–vis spectra and X-ray diffraction (XRD) pattern. The as-prepared SPANi nanofibers had 45 nm average diameter and length up to 750 nm as measured by scanning electron microscope (SEM) and transmission electron microscope (TEM). The self-doped SPANi nanofiber possessed excellent aqueous solubility, good conductivity (0.11 S/cm) and reversible redox activity, making it suitable as a corrosion inhibitor for waterborne coatings. The prepared SPANi/waterborne epoxy composite coatings exhibited remarkably improved corrosion protection compared with pure waterborne epoxy coating as proved by the polarization curves and electrochemical impedance spectroscopy (EIS). The passivation effect of SPANi nanofiber and the corrosion products beneath the epoxy coatings immersed in 3.5% NaCl solution as a function of time were also investigated in this study.

  6. Corrosion protection performance of waterborne epoxy coatings containing self-doped polyaniline nanofiber

    Energy Technology Data Exchange (ETDEWEB)

    Qiu, Shihui [Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201 (China); Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, 315211 (China); Chen, Cheng; Cui, Mingjun [Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201 (China); Li, Wei [Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, 315211 (China); Zhao, Haichao, E-mail: zhaohaichao@nimte.ac.cn [Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201 (China); Wang, Liping, E-mail: wangliping@nimte.ac.cn [Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201 (China)

    2017-06-15

    Highlights: • Self-dopedpolyaniline (SPANi) with good conductivity and dispersibility in water was copolymerized by aniline and its derivative. • Environmental friendly SPANi/epoxy composite coating with remarkable anti-corrosion performance was prepared. • The corrosion product of pure epoxy or composite coating was characterized by X-ray diffraction pattern and scanning electron microscope (SEM). - Abstract: Self-doped sulfonated polyaniline (SPANi) nanofiber was synthesized by the copolymerization of 2-aminobenzenesulfonic acid (ASA) and aniline via a rapid mixing polymerization approach. The chemical structure of SPANi was investigated by the Fourier-transform infrared (FT-IR), Raman, X-ray photoelectron spectroscopy (XPS), UV–vis spectra and X-ray diffraction (XRD) pattern. The as-prepared SPANi nanofibers had 45 nm average diameter and length up to 750 nm as measured by scanning electron microscope (SEM) and transmission electron microscope (TEM). The self-doped SPANi nanofiber possessed excellent aqueous solubility, good conductivity (0.11 S/cm) and reversible redox activity, making it suitable as a corrosion inhibitor for waterborne coatings. The prepared SPANi/waterborne epoxy composite coatings exhibited remarkably improved corrosion protection compared with pure waterborne epoxy coating as proved by the polarization curves and electrochemical impedance spectroscopy (EIS). The passivation effect of SPANi nanofiber and the corrosion products beneath the epoxy coatings immersed in 3.5% NaCl solution as a function of time were also investigated in this study.

  7. Corrosion Performance of Composite Galvanic Coatings with Variable Concentration of Polymeric Nanoaggregates and/or Cr(III) Conversion Layers

    NARCIS (Netherlands)

    Koleva, D.A.; Taheri, P.; Tsvetkova, N.; Boshkov, N.; Van Breugel, K.; De Wit, J.H.W.; Mol, J.M.C.

    2011-01-01

    This paper reports on the corrosion performance of composite zinc layers (~ 8µm) on a steel substrate, considering the influence of nano-aggregates and Cr(III) conversion layers, compared to control (only Zn layers) conditions. The main factors, influencing the corrosion performance of Zn in this

  8. Laser beam welding of Waspaloy: Characterization and corrosion behavior evaluation

    Science.gov (United States)

    Shoja Razavi, Reza

    2016-08-01

    In this work, a study on Nd:YAG laser welding of Waspaloy sheets has been made. Microstructures, phase changes and hardness of the laser joint were investigated using optical microscopy, scanning electron microscopy (SEM), field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS), X-ray diffraction analysis (XRD) and vickers microhardness (HV0.3). Corrosion behavior of the weldment at low temperature in 3.5%wt NaCl solution at room temperature was also investigated using open circuit potential and cyclic potentiodynamic polarization tests. Hot corrosion studies were conducted on samples in the molten salt environment (Na2SO4-60%V2O5) at 900 °C for 50 h. Results indicated that the microstructure of weld zone was mainly dendritic grown epitaxially in the direction perpendicular to the weld boundary and heat transfer. Moreover, the Ti-Mo carbide particles were observed in the structure of the weld zone and base metal. The average size of carbides formed in the base metal (2.97±0.5 μm) was larger than that of the weld zone (0.95±0.2 μm). XRD patterns of the weld zone and base metal showed that the laser welding did not alter the phase structure of the weld zone, being in γ-Ni(Cr) single phase. Microhardness profile showed that the hardness values of the weld zone (210-261 HV) were lower than that of the base metal (323-330 HV). Electrochemical and hot corrosion tests indicated that the corrosion resistance of the weld metal was greater than the base metal in both room and high temperatures.

  9. Radionuclide calibrators performance evaluation

    International Nuclear Information System (INIS)

    Mora Ramirez, E.; Zeledon Fonseca, P.; Jimenez Cordero, M.

    2008-01-01

    Radionuclide calibrators are used to estimate accurately activity prior to administration to a patient, so it is very important that this equipment meets its performance requirements. The purpose of this paper is to compare the commercially available 'Calicheck' (Calcorp. Inc), used to assess linearity, versus the well-known source decay method, and also to show our results after performing several recommended quality control tests. The parameters that we wanted to evaluate were carried on using the Capintec CRC-15R and CRC-15 β radionuclide calibrators. The evaluated tests were: high voltage, display, zero adjust, background, reproducibility, source constancy, accuracy, precision and linearity. The first six tests were evaluated on the daily practice, here we analyzed the 2007 recorded data; and the last three were evaluated once a year. During the daily evaluation both calibrators performance were satisfactory comparing with the manufacture's requirements. The accuracy test show result within the ± 10% allowed for a field instrument. Precision performance is within the ± 1 % allowed. On the other hand, the linearity test shows that using the source decay method the relative coefficient is 0.9998, for both equipment and using the Calicheck the relative coefficient is 0.997. However, looking the percentage of error, during the 'Calicheck' test, its range goes from 0.0 % up to -25.35%, and using the source decay method, the range goes from 0.0 % up to -31.05 %, taking into account both instruments. Checking the 'Calicheck' results we can see that the results varying randomly, but using the source decay method the percentage of error increase as the source activity decrease. We conclude that both devices meet its manufactures requirements, in the case of the linearity using the decay method, decreasing the activity source, increasing the percentage of error, this may happen because of the equipment age. (author)

  10. Development of evaluation method on flow-induced vibration and corrosion of components in two-phase flow by coupled analysis. 2. Evaluation of corrosive conditions in cooling systems of nuclear power plants

    International Nuclear Information System (INIS)

    Uchida, Shunsuke; Naitoh, Masanori; Okada, Hidetoshi; Uehara, Yasushi; Katono, Kenichi; Ichikawa, Ryoko; Hotta, Koji

    2007-01-01

    In order to establish safety and reliable plant operation, it is required to forecast future troubles on structural materials based on combined analyses of flow dynamics and corrosion and to mitigate them before they become serious problems on plant operation. The models are divided into two parts, which are as follows. 1. Prediction model of future trouble on structural materials based on evaluation of corrosive conditions. 2. Evaluation model of wall thinning caused by flow accelerated corrosion. (author)

  11. Health evaluation of drinking water regarding to scaling and corrosion potential using corrosion indexes in Noorabad city, Iran

    Directory of Open Access Journals (Sweden)

    ghodratolah Shams Khorramabadi

    2016-05-01

    Conclusion: Result obtained from studied indexes showed that the drinking water in Noorabad is corrosive and so the water quality in water supply system should be monitored continuously. The best applicable practices for decreasing water corrosion in water supply system are including continuous control of pH, chlorination mechanism and the use of corrosion resistant pipelines and facilities.

  12. EVALUATION OF CORROSION RESISTANCE OF STEEL SHEETS FOR AUTOMOTIVE INDUSTRY WITH THE USE OF THE SPOTFACE TECHNIQUE

    Directory of Open Access Journals (Sweden)

    Alberto Nei Carvalho Costa

    2013-03-01

    Full Text Available Innovation, leading to weight and cost reduction, is a key word concerning the design of steel auto body for auto makers that aim to keep and improve their market share worldwide. On the other hand, auto body life, which is related to the corrosion resistance of the materials employed, should always be considered. The latter has led the auto makers to team up with suppliers to find the best solutions concerning the materials selection. The end result always points towards different sets of steels either zinc-coated or zinc alloyed-coated. Taking all these aspects into consideration, the overall challenge the auto makers face is to mitigate the time required for selection and narrow down the options available. This paper studies the corrosion resistance of several materials applied on steel auto bodies using the technique named spotface, which main advantage is reducing the time required by the traditional scribe to evaluate and compare different materials, when they are submitted either to accelerated or field corrosion testing. Concerning the accelerated corrosion testing, they were performed according to the General Motors do Brasil’s requirements.

  13. Supercapacitors Performance Evaluation

    OpenAIRE

    Zhang, S; Pan, N

    2015-01-01

    The performance of a supercapacitor can be characterized by a series of key parameters, including the cell capacitance, operating voltage, equivalent series resistance, power density, energy density, and time constant. To accurately measure these parameters, a variety of methods have been proposed and are used in academia and industry. As a result, some confusion has been caused due to the inconsistencies between different evaluation methods and practices. Such confusion hinders effective com...

  14. Evaluation of initial degradation in stress corrosion cracking by magnetic methods

    International Nuclear Information System (INIS)

    Takaya, Shigeru; Suzuki, Takayuki; Matsumoto, Yoshihiro; Demachi, Kazuyuki; Uesaka, Mitsuru

    2003-01-01

    Two magnetic methods are proposed for the evaluation of initial degradations of type 304 stainless steel in stress corrosion cracking (SCC). The first one is the measurement of the distribution of chromium depletion by means of a magnetic force microscope (MFM). MFM observations are performed for some samples sensitized in various conditions, and the obtained results coincide with the expected ones from the chromium behavior. Moreover, the phase distributions in the solution-annealed and sensitized states are observed by electron backscatter pattern technique. The observation results show that the phase transformation from the austenite phase to the martensite phase occurred along grain boundaries where the chromium was depleted. The second one is the detection of initial SCC cracks by measurement of magnetic flux densities. In-situ measurement of magnetic flux density during the SCC test and MFM observation reveal the relation of initial SCC cracks and magnetic properties. (author)

  15. Development of a corrosion detection experiment to evaluate conventional and advanced NDI techniques

    Energy Technology Data Exchange (ETDEWEB)

    Roach, D.

    1995-12-31

    The Aging Aircraft NDI Validation Center (AANC) was established by the Federal Aviation Administration Technical Center (FAATC) at Sandia National Laboratories in August of 1991. The goal of the AANC is to provide independent validation of technologies intended to enhance the structural inspection of aging commuter and transport aircraft. The deliverables from the AANC`s validation activities are assessments of the reliability of existing and emerging inspection technologies as well as analyses of the cost benefits to be derived from their implementation. This paper describes the methodology developed by the AANC to assess the performance of NDI techniques. In particular, an experiment being developed to evaluate corrosion detection devices will be presented. The experiment uses engineered test specimens, as well as complete aircraft test beds to provide metrics for NDI validation.

  16. Factors affecting the silver corrosion performance of jet fuel from the Merox process

    Energy Technology Data Exchange (ETDEWEB)

    Viljoen, C.L. [Sasol Oil R& D (South Africa); Hietkamp, S. [CSIR, Pretoria (South Africa); Marais, B.; Venter, J.J. [National Petroleum Refineries of South Africa, Sasolburg (South Africa)

    1995-05-01

    The Natref refinery at Sasolburg, South Africa, which is 63,6% owned by Sasol and 36,5% by Total, is producing Jet A-1 fuel at a rate of 80 m{sup 3}/h by means of a UOP Merox process. A substantial part of the crude oil slate is made up from crudes which have been stored for considerable times in underground mines. Since the 1970`s, Natref has experienced sporadic non-conformance of its treated jet fuel to the silver corrosion (IP 227) test. Various causes and explanations for the sporadic silver corrosion occurrence have been put forward but a direct causal link has remained obscure. The paper addresses these possible causes for silver corrosion and some of the process changes which have been made to alleviate the problem. Emphasis is placed on the most recent approaches which were taken to identify the origin of the sporadic silver corrosion. An inventory of all the potential causes was made, such a bacterial action, elemental sulphur formation in storage, etc. and experiments designed to test the validity of these causes, are discussed. A statistical evaluation which was done of the historical process data over a 2 year period, failed to link the use of mine crudes directly to Ag-corrosion occurrence. However, a correlation between elemental sulphur and H{sub 2}S levels in the feed to the Merox reactor and Ag-corrosion was observed. Finally, the outcome of the experiments are discussed, as well as the conclusions which were reached from the observed results.

  17. Evaluation of nondestructive evaluation size measurement for integrity assessment of axial outside diameter stress corrosion cracking in steam generator tubes

    International Nuclear Information System (INIS)

    Joo, Kyung Mun; Hong, Jun Hee

    2015-01-01

    Recently, the initiation of outside diameter stress corrosion cracking (ODSCC) at the tube support plate region of domestic steam generators (SG) with Alloy 600 HTMA tubes has been increasing. As a result, SGs with Alloy 600 HTMA tubes must be replaced early or are scheduled to be replaced prior to their designed lifetime. ODSCC is one of the biggest threats to the integrity of SG tubes. Therefore, the accurate evaluation of tube integrity to determine ODSCC is needed. Eddy current testing (ECT) is conducted periodically, and its results could be input as parameters for evaluating the integrity of SG tubes. The reliability of an ECT inspection system depends on the performance of the inspection technique and ability of the analyst. The detection probability and ECT sizing error of degradation are considered to be the performance indices of a nondestructive evaluation (NDE) system. This paper introduces an optimized evaluation method for ECT, as well as the sizing error, including the analyst performance. This study was based on the results of a round robin program in which 10 inspection analysts from 5 different companies participated. The analysis of ECT sizing results was performed using a linear regression model relating the true defect size data to the measured ECT size data.

  18. Evaluation of nondestructive evaluation size measurement for integrity assessment of axial outside diameter stress corrosion cracking in steam generator tubes

    Energy Technology Data Exchange (ETDEWEB)

    Joo, Kyung Mun [Korea Hydro and Nuclear Power Company Ltd., Central Research Institute, Daejeon (Korea, Republic of); Hong, Jun Hee [Dept. of mechanical Engineering, Chungnam National University, Daejeon (Korea, Republic of)

    2015-02-15

    Recently, the initiation of outside diameter stress corrosion cracking (ODSCC) at the tube support plate region of domestic steam generators (SG) with Alloy 600 HTMA tubes has been increasing. As a result, SGs with Alloy 600 HTMA tubes must be replaced early or are scheduled to be replaced prior to their designed lifetime. ODSCC is one of the biggest threats to the integrity of SG tubes. Therefore, the accurate evaluation of tube integrity to determine ODSCC is needed. Eddy current testing (ECT) is conducted periodically, and its results could be input as parameters for evaluating the integrity of SG tubes. The reliability of an ECT inspection system depends on the performance of the inspection technique and ability of the analyst. The detection probability and ECT sizing error of degradation are considered to be the performance indices of a nondestructive evaluation (NDE) system. This paper introduces an optimized evaluation method for ECT, as well as the sizing error, including the analyst performance. This study was based on the results of a round robin program in which 10 inspection analysts from 5 different companies participated. The analysis of ECT sizing results was performed using a linear regression model relating the true defect size data to the measured ECT size data.

  19. Comparative evaluation of corrosion behaviour of type K thin film thermocouple and its bulk counterpart

    International Nuclear Information System (INIS)

    Mukherjee, S.K.; Barhai, P.K.; Srikanth, S.

    2011-01-01

    Highlights: → Anodic vacuum arc deposited chromel and alumel films are more 'noble' in 5% NaCl solution than their respective wires. → Chromel undergoes localised corrosion while alumel shows uniform corrosion. → Virgin samples of chromel-alumel TFTCs exhibit good thermoelectric response. → Their thermoelectric outputs remain largely unaffected when shelved under normal atmospheric conditions. → After 288 h of exposure in salt spray environment, their thermoelectric outputs show noticeable change due to size effects. - Abstract: This paper investigates the corrosion behaviour of type K thermoelements and their thin films, and compares the performance of chromel-alumel thin film thermocouple with its wire counterpart before and after exposure to 5% NaCl medium. Potentiodynamic polarisation tests reveal that chromel and alumel films are more 'noble' than their respective wires. Alumel corrodes faster when coupled with chromel in films than as wires. Secondary electron micrographs and electrochemical impedance spectroscopy measurements suggest that chromel shows localised corrosion while alumel undergoes uniform corrosion. Corrosion adversely affects the thermocouple output and introduces an uncertainty in the measurement.

  20. Non-Destructive Evaluation for Corrosion Monitoring in Concrete: A Review and Capability of Acoustic Emission Technique

    Science.gov (United States)

    Zaki, Ahmad; Chai, Hwa Kian; Aggelis, Dimitrios G.; Alver, Ninel

    2015-01-01

    Corrosion of reinforced concrete (RC) structures has been one of the major causes of structural failure. Early detection of the corrosion process could help limit the location and the extent of necessary repairs or replacement, as well as reduce the cost associated with rehabilitation work. Non-destructive testing (NDT) methods have been found to be useful for in-situ evaluation of steel corrosion in RC, where the effect of steel corrosion and the integrity of the concrete structure can be assessed effectively. A complementary study of NDT methods for the investigation of corrosion is presented here. In this paper, acoustic emission (AE) effectively detects the corrosion of concrete structures at an early stage. The capability of the AE technique to detect corrosion occurring in real-time makes it a strong candidate for serving as an efficient NDT method, giving it an advantage over other NDT methods. PMID:26251904

  1. Non-Destructive Evaluation for Corrosion Monitoring in Concrete: A Review and Capability of Acoustic Emission Technique

    Directory of Open Access Journals (Sweden)

    Ahmad Zaki

    2015-08-01

    Full Text Available Corrosion of reinforced concrete (RC structures has been one of the major causes of structural failure. Early detection of the corrosion process could help limit the location and the extent of necessary repairs or replacement, as well as reduce the cost associated with rehabilitation work. Non-destructive testing (NDT methods have been found to be useful for in-situ evaluation of steel corrosion in RC, where the effect of steel corrosion and the integrity of the concrete structure can be assessed effectively. A complementary study of NDT methods for the investigation of corrosion is presented here. In this paper, acoustic emission (AE effectively detects the corrosion of concrete structures at an early stage. The capability of the AE technique to detect corrosion occurring in real-time makes it a strong candidate for serving as an efficient NDT method, giving it an advantage over other NDT methods.

  2. Evaluation of mechanically treated cerium (IV) oxides as corrosion inhibitors for galvanized steel

    Energy Technology Data Exchange (ETDEWEB)

    Deflorian, F., E-mail: flavio.deflorian@ing.unitn.it [Department of Materials Engineering and Industrial Technology, University of Trento, Via Mesiano 77, 38123 Trento (Italy); Fedel, M.; Rossi, S. [Department of Materials Engineering and Industrial Technology, University of Trento, Via Mesiano 77, 38123 Trento (Italy); Kamarchik, P. [PPG Industries, Coatings Innovation Center, 4325 Rosanna Drive, Allison Park, PA 15101 (United States)

    2011-09-30

    The use of cerium salts as corrosion inhibitors for hot dip galvanized steel has been object of a numerous studies in the last few years. The role of cerium ions as corrosion inhibitors was proved: cerium is able to block the cathodic sites of the metal, forming insoluble hydroxides and oxides on the zinc surface. This fact leads to a dramatic decrease of the cathodic current densities and, therefore, to a reduction the overall corrosion processes. On the other hand, the potential of cerium oxides as corrosion inhibitors was also proposed. However, the real effectiveness of this kind of anticorrosive pigments has not been clarified yet. In this work cerium (IV) oxides are considered as corrosion inhibitors for galvanized steel. The corrosion inhibition mechanism of mechanically treated (milled) CeO{sub 2} alone and in combination with milled SiO{sub 2} nanoparticles was investigated. For this purpose milled CeO{sub 2}, CeO{sub 2} and SiO{sub 2} milled together and milled SiO{sub 2} particles were studied as corrosion inhibitors in water solution. Therefore, the different mechanically treated particles were dispersed in 0.1 M NaCl solution to test their effectiveness as corrosion inhibitors for galvanized steel. The galvanized steel was immersed in the different solutions and the corrosion inhibition efficiency of the different particles was measured by means of electrochemical techniques. For this purpose, electrochemical impedance spectroscopy (EIS) measurements were carried out, monitoring the evolution of the corrosion processes occurring at the metal surface with the immersion time in the solution. The effect of the different pigments was also investigated by carrying out anodic and cathodic polarization measurements. The polarization curves were acquired under conditions of varied pH. The experimental measurements suggest that the mechanical treatment performed on the SiO{sub 2} and CeO{sub 2} particles promote the formation of an effective corrosion pigment

  3. Evaluation of the Corrosion Protection Coating in Accordance with Burn Damage

    International Nuclear Information System (INIS)

    Seo, ChangHo; Park, JinHwan

    2016-01-01

    This study was conducted in order to examine the effect of burn damage and the resultant anti-corrosion performance. The breakdown and defect of the paint film caused by burn damage are considered to affect not only the macroscopic appearance but also the adhesive force and the anti-corrosion performance of the paint film. The material of the paint film was epoxy paint that is used most widely for heavy-duty coating, and in order to induce burn damage, heat treatment with a torch was applied to the other side of the paint film. Surface and chemical structure changes according to aging were analyzed using FE-SEM and infrared absorption spectroscopy, and variation in the anti-corrosion performance was analyzed through the AC impedance test.

  4. Corrosion evaluation of cooling-water treatments for gas centrifuge facilities

    International Nuclear Information System (INIS)

    Schmidt, C.R.; Meredith, P.F.

    1980-01-01

    The corrosion resistance of six different types of weighted metal coupons was evaluated at 29 0 C (84 0 F) in flowing water containing nitrite-borate-silicate corrosion inhibitors. The question for evaluation was whether it would be more advantageous: (1) to drain the treated cooling water from the centrifuge machine and to expose them to moisture-laden air over an assumed shop downtime and repair perid of 1 month; or (2) to let the treated cooling water remain stagnant in the machines during this downtime. The moisture-laden-air exposure was more detrimental

  5. Standard practice for conducting and evaluating laboratory corrosions tests in soils

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    1999-01-01

    1.1 This practice covers procedures for conducting laboratory corrosion tests in soils to evaluate the corrosive attack on engineering materials. 1.2 This practice covers specimen selection and preparation, test environments, and evaluation of test results. 1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

  6. Effect of areal power density and relative humidity on corrosion resistant container performance

    International Nuclear Information System (INIS)

    Gansemer, J.D.

    1994-10-01

    The impact of the rewetting process on the performance of waste containers at the Yucca Mountain repository is analyzed. This paper explores the impact of the temperature-humidity relationships on pitting corrosion failure of stainless steel containers for different areal power densities (APDs)in the repository. It compares the likely performance of containers in a repository with a low APD, 55 Kw/acre, and a high APD, 110 kW/acre

  7. An accurately controllable imitative stress corrosion cracking for electromagnetic nondestructive testing and evaluations

    International Nuclear Information System (INIS)

    Yusa, Noritaka; Uchimoto, Tetsuya; Takagi, Toshiyuki; Hashizume, Hidetoshi

    2012-01-01

    Highlights: ► We propose a method to simulate stress corrosion cracking. ► The method offers nondestructive signals similar to those of actual cracking. ► Visual and eddy current examinations validate the method. - Abstract: This study proposes a simple and cost-effective approach to fabricate an artificial flaw that is identical to stress corrosion cracking especially from the viewpoint of electromagnetic nondestructive evaluations. The key idea of the approach is to embed a partially-bonded region inside a material by bonding together surfaces that have grooves. The region is regarded as an area of uniform non-zero conductivity from an electromagnetic nondestructive point of view, and thus simulates the characteristics of stress corrosion cracking. Since the grooves are introduced using electro-discharge machining, one can control the profile of the imitative stress corrosion cracking accurately. After numerical simulation to evaluate the spatial resolution of conventional eddy current testing, six specimens made of type 316L austenitic stainless steel were fabricated on the basis of the results of the simulations. Visual and eddy current examinations were carried out to demonstrate that the artificial flaws well simulated the characteristics of actual stress corrosion cracking. Subsequent destructive test confirmed that the bonding did not change the depth profiles of the artificial flaw.

  8. Waterwall corrosion evaluation in coal-fired boilers using electrochemical measurements

    Energy Technology Data Exchange (ETDEWEB)

    Davis, K.; Lee, C.; Seeley, R.; Harding, S.; Heap, M.; Cox, W.

    2000-07-01

    Until recently, waterwall corrosion in North American coal-fired boilers was uncommon and relatively mild. However, the introduction of combustion modifications to reduce in-furnace NOx formation has led to notable increases in the frequency and severity of waterwall wastage. Reaction Engineering International (REI) has worked with the Department of Energy and EPRI to improve predictive capabilities and provide solutions for furnace wall wastage for a wide range of coal-fired furnaces. To date, this work has emphasized computational simulations. More recently, REI in partnership with Corrosion Management has begun complementary efforts to improve their services by evaluating technologies capable of determining the location/rate of high water wall wastage resulting from corrosion. After an evaluation of commercially available options, electrochemical noise (EN) technology has been chosen for continued development. This approach has been successfully applied to corrosion-related problems involving acid dewpoint corrosion in flue gas ductwork, FGD systems, cooling water systems, oil and gas production, and acid cleaning (Cox et al, 1999). This paper presents the results of preliminary testing of an EN probe in a high temperature environment typical of the lower furnace of a cyclone-fired boiler operating under staged conditions. The relationship between electrochemical responses and (1) stoichiometry and (2) local hydrogen sulfide concentration is investigated and the qualitative and quantitative usefulness of the approach for on-line risk management is considered.

  9. Evaluation on corrosively dissolved gold induced by alkanethiol monolayer with atomic absorption spectroscopy

    International Nuclear Information System (INIS)

    Cao Zhong; Zhang Ling; Guo Chaoyan; Gong Fuchun; Long Shu; Tan Shuzhen; Xia Changbin; Xu Fen; Sun Lixian

    2009-01-01

    We have monitored a gold corrosive dissolution behavior accompanied in n-alkanethiol like n-dodecanethiol assembled process with in situ quartz crystal microbalance (QCM), and then observed it with atomic force microscopy (AFM) which showed an evident image of corrosive defects or holes produced on gold substrate, corresponding to gold dissolution induced by the alkanethiol molecules in the presence of oxygen. For detection of the dissolved gold defects during alkanethiol assembled process, an atomic absorption spectroscopy (AAS) has been carried out in this paper, and the detection limit for the dissolved gold could be evaluated to be 15.4 ng/mL. The amount of dissolved gold from the substrates of gold plates as functions of immersion time, acid media, solvents and thiol concentration has been examined in the oxygen saturated solutions. In comparison with in situ QCM method, the kinetics behavior of the long-term gold corrosion on the gold plates in 1.0 mmol/L of n-dodecanethiol solution determined with AAS method was a slow process, and its corrosion rate on gold dissolution could be evaluated to be about 4.4 x 10 -5 ng.cm -2 .s -1 , corresponding to 1.3 x 10 8 Au atoms.cm -2 .s -1 , that was much smaller than that of initial rate monitored with in situ QCM. Both kinetics equations obtained with QCM and AAS showed a consistent corrosion behavior on gold surfaces.

  10. Corrosion Performance of Friction Stir Linear Lap Welded AM60B Joints

    Science.gov (United States)

    Kish, J. R.; Birbilis, N.; McNally, E. M.; Glover, C. F.; Zhang, X.; McDermid, J. R.; Williams, G.

    2017-11-01

    A corrosion investigation of friction stir linear lap welded AM60B joints used to fabricate an Mg alloy-intensive automotive front end sub-assembly was performed. The stir zone exhibited a slightly refined grain size and significant break-up and re-distribution of the divorced Mg17Al12 (β-phase) relative to the base material. Exposures in NaCl (aq) environments revealed that the stir zone was more susceptible to localized corrosion than the base material. Scanning vibrating electrode technique measurements revealed differential galvanic activity across the joint. Anodic activity was confined to the stir zone surface and involved initiation and lateral propagation of localized filaments. Cathodic activity was initially confined to the base material surface, but was rapidly modified to include the cathodically-activated corrosion products in the filament wake. Site-specific surface analyses revealed that the corrosion observed across the welded joint was likely linked to variations in Al distribution across the surface film/metal interface.

  11. Nondestructive evaluation algorithm of fatigue cracks and far-side corrosion around a rivet fastener in multi-layered structures

    Energy Technology Data Exchange (ETDEWEB)

    Le, Min Hhuy; Kim, Jung Min [Research Center for IT-based Real Time NDT for Nano-Damage Tolerance, Chosun University, Gwangju (Korea, Republic of); Kim, Sejin; Wang, Dabin [Dept. of Control and Instrumentation Engineering, Graduate School, Chosun University, Gwangju (Korea, Republic of); Hwang, Young Ha [Avionics System Technology Center, KITECH, Youngcheon (Korea, Republic of)

    2016-09-15

    This research proposes a nondestructive inspection system for inspecting and localizing corrosion and fatigue cracks around rivets in air-intake structures. The system uses 64 InSb Hall sensor elements arrayed at a high spatial interval of 0.52 mm. Rivet detection and damage detection algorithms will be proposed. Analysis of the receiver operating characteristic curve and Probability of detection (POD) will be carried out to evaluate the performance of the system and detection algorithms. Artificial corrosion around a rivet with a minimum volume of 11.02 mm{sup 3} could be detected with 90/95% POD and artificial fatigue crack with minimum length of 2.95 mm from rivet body.

  12. Criteria for performance evaluation

    Directory of Open Access Journals (Sweden)

    David J. Weiss

    2009-03-01

    Full Text Available Using a cognitive task (mental calculation and a perceptual-motor task (stylized golf putting, we examined differential proficiency using the CWS index and several other quantitative measures of performance. The CWS index (Weiss and Shanteau, 2003 is a coherence criterion that looks only at internal properties of the data without incorporating an external standard. In Experiment 1, college students (n = 20 carried out 2- and 3-digit addition and multiplication problems under time pressure. In Experiment 2, experienced golfers (n = 12, also college students, putted toward a target from nine different locations. Within each experiment, we analyzed the same responses using different methods. For the arithmetic tasks, accuracy information (mean absolute deviation from the correct answer, MAD using a coherence criterion was available; for golf, accuracy information using a correspondence criterion (mean deviation from the target, also MAD was available. We ranked the performances of the participants according to each measure, then compared the orders using Spearman's rextsubscript{s}. For mental calculation, the CWS order correlated moderately (rextsubscript{s} =.46 with that of MAD. However, a different coherence criterion, degree of model fit, did not correlate with either CWS or accuracy. For putting, the ranking generated by CWS correlated .68 with that generated by MAD. Consensual answers were also available for both experiments, and the rankings they generated correlated highly with those of MAD. The coherence vs. correspondence distinction did not map well onto criteria for performance evaluation.

  13. Stress corrosion evaluation on stainless steel 304 pipes in Laguna Verde Nuclear Power Plant

    International Nuclear Information System (INIS)

    Arganis J, C.R.

    1996-01-01

    Inside the frame of the project IAEA/MEX-41044 'Stress corrosion as a starting event of accidents in nuclear plants', and of the institutional project IA-252 under the same name, it was required from the Laguna Verde Nuclear Plant, material equivalent to the one employed in the piping of the primary recycling system. Laguna Verde Nuclear Plant granted two tracks of tubes, that could be used to substitute the ones that are in operation, as is the tube SA-358TP304 CL-QC with transversal welding, designated as ER-316-LQA. According to the report entitles 'Revision of the operational experience related to corrosion in the nuclear plants' it was found that the stress corrosion is the principal mechanism of corrosion present in the nuclear plants. Previous records indicate that sensitized stainless steels are resistant to stress corrosion in testings of constant loading in sea water (3.5% of chlorides approximately) to 80 Centigrade and to 80% of the limit of conveyance and that a solution of 22% of NaCl to 90 Centigrade, produces cracking due to stress corrosion in highly sensitized steels, in tests of speed of slow extension (SSRT), to a speed of 1x10 -6 s -1 . Daniels reports that there is a direct relation between the speed limit of detection of the SSRT test and the concentration of chlorides, for stainless steels tested to 100 Centigrade. The minimum detection speed of susceptibility to stress corrosion for solution to 20% of NaCl, is of 1x10 -7 s -1 . Taking into account these considerations, the employment of a solution with 22% of NaCl to 90 Centigrade to a speed of 1x10 -6 s -1 seems a good choice for the evaluation of stainless steel. (Author)

  14. Evaluation of susceptibility of high strength steels to delayed fracture by using cyclic corrosion test and slow strain rate test

    International Nuclear Information System (INIS)

    Li Songjie; Zhang Zuogui; Akiyama, Eiji; Tsuzaki, Kaneaki; Zhang Boping

    2010-01-01

    To evaluate susceptibilities of high strength steels to delayed fracture, slow strain rate tests (SSRT) of notched bar specimens of AISI 4135 with tensile strengths of 1300 and 1500 MPa and boron-bearing steel with 1300 MPa have been performed after cyclic corrosion test (CCT). During SSRT the humidity around the specimen was kept high to keep absorbed diffusible hydrogen. The fracture stresses of AISI 4135 steels decreased with increment of diffusible hydrogen content which increased with CCT cycles. Their delayed fracture susceptibilities could be successfully evaluated in consideration of both influence of hydrogen content on mechanical property and hydrogen entry.

  15. Evaluation of susceptibility of high strength steels to delayed fracture by using cyclic corrosion test and slow strain rate test

    Energy Technology Data Exchange (ETDEWEB)

    Li Songjie [School of Materials Science and Engineering, University of Science and Technology Beijing, No. 30 Xueyuan Road, Hidian Zone, Beijing 100083 (China); Structural Metals Center, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Zhang Zuogui [Structural Metals Center, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Akiyama, Eiji [Structural Metals Center, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan)], E-mail: AKIYAMA.Eiji@nims.go.jp; Tsuzaki, Kaneaki [Structural Metals Center, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Zhang Boping [School of Materials Science and Engineering, University of Science and Technology Beijing, No. 30 Xueyuan Road, Hidian Zone, Beijing 100083 (China)

    2010-05-15

    To evaluate susceptibilities of high strength steels to delayed fracture, slow strain rate tests (SSRT) of notched bar specimens of AISI 4135 with tensile strengths of 1300 and 1500 MPa and boron-bearing steel with 1300 MPa have been performed after cyclic corrosion test (CCT). During SSRT the humidity around the specimen was kept high to keep absorbed diffusible hydrogen. The fracture stresses of AISI 4135 steels decreased with increment of diffusible hydrogen content which increased with CCT cycles. Their delayed fracture susceptibilities could be successfully evaluated in consideration of both influence of hydrogen content on mechanical property and hydrogen entry.

  16. RTD-Incotest for evaluation of corrosion under insulation

    Energy Technology Data Exchange (ETDEWEB)

    Witts, J., E-mail: Jason.Witts@applusrtd.com [Applus-RTD Canada, Edmonton, AB (Canada)

    2015-07-01

    RTD-Incotest or insulated component testing, a method of pulsed eddy current, is designed and developed by Applus-RTD for the detection and sizing of corrosion under insulation. RTD-Incotest measures average wall loss over an area beneath the probe. This is accomplished by measuring the decay curve of the eddy current and then utilizes a software algorithm to determine percent wall loss. If there is a verification point this can also give average remaining wall thickness. The benefits for the nuclear industry are: 1) No need to remove insulation. Only requires one verification point. 2) Reduces potential exposure/ maintains ALARA 3) Quick and accurate screening method. For exposed piping there is no need for contact with the piping. So it can be applied for high temperature or for increasing standoff to reduce exposure. (author)

  17. RTD-Incotest for evaluation of corrosion under insulation

    International Nuclear Information System (INIS)

    Witts, J.

    2015-01-01

    RTD-Incotest or insulated component testing, a method of pulsed eddy current, is designed and developed by Applus-RTD for the detection and sizing of corrosion under insulation. RTD-Incotest measures average wall loss over an area beneath the probe. This is accomplished by measuring the decay curve of the eddy current and then utilizes a software algorithm to determine percent wall loss. If there is a verification point this can also give average remaining wall thickness. The benefits for the nuclear industry are: 1) No need to remove insulation. Only requires one verification point. 2) Reduces potential exposure/ maintains ALARA 3) Quick and accurate screening method. For exposed piping there is no need for contact with the piping. So it can be applied for high temperature or for increasing standoff to reduce exposure. (author)

  18. Galvanic corrosion evaluation of high activity nuclear waste container metals components

    International Nuclear Information System (INIS)

    Semino, C.J.

    1990-04-01

    The final disposal container for vitrified high-level waste is assumed to have three metallic layers: a stainless steel inner layer, and external one of a metal to be selected and a thick lead layer (10 cm) in the middle. As design limit, the container shall act as an engineering barrier, granting the isolation of the radionuclides for approximately 1000 years. Preliminary titanium-lead galvanic couple tests showed that titanium behaved always as a cathode in the galvanic couple, promoting the galvanic corrosion of lead. This corrosion study focused on the behaviour of lead-AISI 304 stainless steel and lead-carbon steel (SAE 1010 and 1020) galvanic couples with different area relationships, temperature and media composition. High purity lead (99,999%) and commercial lead (99,9%) were used for galvanic couples tests. Tests were performed at 75, 50, 45 and 40 deg. C. Test solution was either synthetic groundwater, a suspension of 10% bentonite in groundwater, or synthetic sea water. The synthetic sea water was used at 100, 50 and 25% concentration by dilution with distilled water. Tests with lead-304 stainless steel galvanic couples showed that lead always behaves as an anode, corroding preferentially. Very low lead corrosion rates were found in lead-carbon steel galvanic couple in 10% bentonite suspension in synthetic groundwater test at 75 deg. C. An increase of carbon content in steel has very little influence on steel corrosion rate. Commercial lead has a higher corrosion rate and presented a more pronounced attack than high purity lead. Its corrosion rate is at least twice when lead-carbon steel area relationship increases from 1:10 to 1:40. There are higher steel corrosion rates in sea water than in groundwater. Lead behaves as a cathode to the end of the test. 8 refs, 85 figs, 10 tabs

  19. Effect of Surface Contaminants Remained on the Blasted Surface on Epoxy Coating Performance and Corrosion Resistance

    International Nuclear Information System (INIS)

    Baek, Kwang Ki; Park, Chung Seo; Kim, Ki Hong; Chung, Mong Kyu; Park, Jin Hwan

    2006-01-01

    One of the critical issues in the coating specification is the allowable limit of surface contaminant(s) - such as soluble salt(s), grit dust, and rust - after grit blasting. Yet, there is no universally accepted data supporting the relationship between the long-term coating performance and the amount of various surface contaminants allowed after grit blasting. In this study, it was attempted to prepare epoxy coatings applied on grit-blasted steel substrate dosed with controlled amount of surface contaminants - such as soluble salt(s), grit dust, and rust. Then, coating samples were subjected to 4,200 hours of cyclic test(NORSOK M-501), which were then evaluated in terms of resistance to rust creepage, blistering, chalking, rusting, cracking and adhesion strength. Additional investigations on the possible damage at the paint/steel interface were carried out using an Electrochemical Impedance Spectroscopy(EIS) and observations of under-film-corrosion. Test results suggested that the current industrial specifications were well matched with the allowable degree of rust, whereas the allowable amount of soluble salt and grit dust after grit blasting showed a certain deviation from the specifications currently employed for fabrication of marine vessels and offshore facilities

  20. Evaluation of effect of surface treatment on corrosion resistance of Nd-Fe-B magnets

    International Nuclear Information System (INIS)

    Martins, Emerson Alves

    2009-01-01

    Nd-Fe-B magnets produced by powder metallurgy are highly susceptible to corrosion due to their complex microstructure and intrinsic porosity due to their fabrication process. Moreover, these magnets have excellent magnetic properties and find many applications. In the nuclear area, permanent magnets based on rare earth transition-iron-boron (Ne-Fe-B) are used in the manufacture of magnetic media (magnetic levitation) for ultra-centrifuges used for isotopic enrichment of uranium employed in nuclear reactors. In dentistry these types of magnets are used to fix total and partial prostheses on implants; in orthodontics to correct dental malocclusion and make moves; in buco-maxillo-facial surgery for setting facial prostheses of large defects of the face. In electronic equipment, they are used in scales, locks, electric motors and particularly in the manufacturing of hard drives of computers. The objective of this study is to evaluate the corrosion resistance of the magnet tested and surface treatments that could replace chromating that generates toxic residues and present high cost of processing waste with treatments that are environmentally friendly. The evaluation of the corrosion resistance was carried out through the analysis potentiodynamic polarization curves, electrochemical impedance spectroscopy, monitoring of corrosion potential as a function of test time and scanning electron microscopy to try to correlate the magnet microstructure with its corrosion resistance. The results show that these magnets are highly susceptible to corrosion that occurs preferentially in the Nd-rich phase, located in the boundaries of the magnetic matrix phase (ψ). Treatment with silane, cerium, sam, Cr 6 + , tricationic phosphate followed by bath of chromium trioxide and in NaH 2 PO 4 solution for 24 hours followed by bath of zinc sulphate did not improve the corrosion resistance of the magnet. Among the treatments used, immersion in NaH 2 PO 4 solution for 24 hours pH=3.8 was the

  1. Makeup water system performance and impact on PWR steam generator corrosion

    International Nuclear Information System (INIS)

    Bell, M.J.; Sawocha, S.G.; Smith, L.A.

    1984-01-01

    The object of this EPRI-funded project was to assess the possible relation of pressurized water reactor (PWR) steam generator corrosion at fresh water sites to makeup water impurity ingress. Makeup water system design, operation and performance reviews were based on site visits, plant design documents, performance records and grab sample analyses. Design features were assessed in terms of their effect on makeup system performance. Attempts were made to correlate the makeup plant source water, system design characteristics, and typical makeup water qualities to steam generator corrosion observations, particularly intergranular attack (IGA). Direct correlations were not made since many variables are involved in the corrosion process and in the case of IGA, the variables have not been clearly established. However, the study did demonstrate that makeup systems can be a significant source of contaminants that are suspected to lead to both IGA and denting. Additionally, it was noted that typical makeup system performance with respect to organic removal was not good. The role of organics in steam generator damage has not been quantified and may deserve further study

  2. Method for Evaluating the Corrosion Resistance of Aluminum Metallization of Integrated Circuits under Multifactorial Influence

    Science.gov (United States)

    Kolomiets, V. I.

    2018-03-01

    The influence of complex influence of climatic factors (temperature, humidity) and electric mode (supply voltage) on the corrosion resistance of metallization of integrated circuits has been considered. The regression dependence of the average time of trouble-free operation t on the mentioned factors has been established in the form of a modified Arrhenius equation that is adequate in a wide range of factor values and is suitable for selecting accelerated test modes. A technique for evaluating the corrosion resistance of aluminum metallization of depressurized CMOS integrated circuits has been proposed.

  3. Evaluation of the Microbiologically Influenced Corrosion in a carbon steel making use of electrochemical techniques

    International Nuclear Information System (INIS)

    Diaz S, A.C.; Arganis, C.; Ayala, V.; Gachuz, M.; Merino, J.; Suarez, S.; Brena, M.; Luna, P.

    2001-01-01

    The Microbiologically Influenced Corrosion (MIC) has been identified as a problem of the nuclear plants systems in the last years. The electrochemical behavior of metal coupons of carbon steel submitted to the action of sulfate reducing bacteria (SRB) was evaluated, making use of the electrochemical techniques of direct current as well as electrochemical noise. The generated results show a little variation in the corrosion velocities which obtained by Tafel extrapolation and resistance to the linear polarization, whereas the electrochemical noise technique presented important differences as regards the registered behavior in environment with and without microorganisms. (Author)

  4. Fabrication of imitative stress corrosion cracking specimens suitable for electromagnetic nondestructive evaluations using solid state bonding

    International Nuclear Information System (INIS)

    Yusa, Noritaka; Hashizume, Hidetoshi; Uchimoto, Tetsuya; Takagi, Toshiyuki

    2010-01-01

    This study proposes a method to fabricate artificial defects that is almost identical to stress corrosion cracking from the viewpoint of electromagnetic nondestructive evaluations. The key idea is to realize a region having electrical resistance embedded inside a conductive materials using solid state bonding. A rough region is introduced into the surface of the materials so that the region is partially bonded to realize electrical resistance. The validity of the method is demonstrated using type 316L austenitic stainless steels. Eddy current tests and subsequent destructive tests confirm that signals due to the fabricated specimens are very similar to those due to stress corrosion cracks. (author)

  5. Accessibility evaluation of the IFMIF liquid lithium loop considering activated erosion/corrosion materials deposition

    International Nuclear Information System (INIS)

    Nakamura, H.; Takemura, M.; Yamauchi, M.; Fischer, U.; Ida, M.; Mori, S.; Nishitani, T.; Simakov, S.; Sugimoto, M.

    2005-01-01

    This paper presents an evaluation of accessibility of the Li loop piping considering activated corrosion product. International Fusion Materials Irradiation Facility (IFMIF) is a deuteron-lithium (Li) stripping reaction neutron source for fusion materials testing. Target assembly and back wall are designed as fully remote maintenance component. Accessibility around the Li loop piping will depend on activation level of the deposition materials due to the back wall erosion/corrosion process under liquid Li flow. Activation level of the corrosion products coming from the AISI 316LN back wall is calculated by the ACT-4 of the THIDA-2 code system. The total activities after 1 day, 1 week, 1 month and 1 year cooling are 3.1 x 10 14 , 2.8 x 10 14 , 2.3 x 10 14 and 7.5 x 10 13 Bq/kg, respectively. Radiation dose rate around the Li loop pipe is calculated by QAD-CGGP2R code. Activated area of the back wall is 100 cm 2 . Corrosion rate is assumed 1 μm/year. When 10% of the corrosion material is supposed to be deposited on the inner surface of the pipe, the dose rate is calculated to be less than a permissible level of 10 μSv/h for hands-on maintenance, therefore, the maintenance work is assessed to be possible

  6. Evaluation of precipitates used in strainer head loss testing: Part II. Precipitates by in situ aluminum alloy corrosion

    International Nuclear Information System (INIS)

    Bahn, Chi Bum; Kasza, Ken E.; Shack, William J.; Natesan, Ken; Klein, Paul

    2011-01-01

    Graphical abstract: Display Omitted Research highlights: → Sump strainer head loss testing to evaluate chemical effects. → Aluminum hydroxide precipitates by in situ Al alloy corrosion caused head loss. → Intermetallic particles released from Al alloy can also cause significant head loss. → When evaluating Al effect on head loss, intermetallics should be considered. - Abstract: Vertical loop head loss tests were performed with 6061 and 1100 aluminum (Al) alloy plates immersed in borated solution at pH = 9.3 at room temperature and 60 o C. The results suggest that the potential for corrosion of an Al alloy to result in increased head loss across a glass fiber bed may depend on its microstructure, i.e., the size distribution and number density of intermetallic particles that are present in Al matrix and FeSiAl ternary compounds, as well as its Al release rate. Per unit mass of Al removed from solution, the WCAP-16530 aluminum hydroxide (Al(OH) 3 ) surrogate was more effective in increasing head loss than the Al(OH) 3 precipitates formed in situ by corrosion of Al alloy. However, in choosing a representative amount of surrogate for plant specific testing, consideration should be given to the potential for additional head losses due to intermetallic particles and the apparent reduction in the effective solubility of Al(OH) 3 when intermetallic particles are present.

  7. Pilot-scale cooling tower to evaluate corrosion, scaling, and biofouling control strategies for cooling system makeup water.

    Science.gov (United States)

    Chien, S H; Hsieh, M K; Li, H; Monnell, J; Dzombak, D; Vidic, R

    2012-02-01

    Pilot-scale cooling towers can be used to evaluate corrosion, scaling, and biofouling control strategies when using particular cooling system makeup water and particular operating conditions. To study the potential for using a number of different impaired waters as makeup water, a pilot-scale system capable of generating 27,000 kJ∕h heat load and maintaining recirculating water flow with a Reynolds number of 1.92 × 10(4) was designed to study these critical processes under conditions that are similar to full-scale systems. The pilot-scale cooling tower was equipped with an automatic makeup water control system, automatic blowdown control system, semi-automatic biocide feeding system, and corrosion, scaling, and biofouling monitoring systems. Observed operational data revealed that the major operating parameters, including temperature change (6.6 °C), cycles of concentration (N = 4.6), water flow velocity (0.66 m∕s), and air mass velocity (3660 kg∕h m(2)), were controlled quite well for an extended period of time (up to 2 months). Overall, the performance of the pilot-scale cooling towers using treated municipal wastewater was shown to be suitable to study critical processes (corrosion, scaling, biofouling) and evaluate cooling water management strategies for makeup waters of complex quality.

  8. Smart aircraft fastener evaluation (SAFE) system: a condition-based corrosion detection system for aging aircraft

    Science.gov (United States)

    Schoess, Jeffrey N.; Seifert, Greg; Paul, Clare A.

    1996-05-01

    The smart aircraft fastener evaluation (SAFE) system is an advanced structural health monitoring effort to detect and characterize corrosion in hidden and inaccessible locations of aircraft structures. Hidden corrosion is the number one logistics problem for the U.S. Air Force, with an estimated maintenance cost of $700M per year in 1990 dollars. The SAFE system incorporates a solid-state electrochemical microsensor and smart sensor electronics in the body of a Hi-Lok aircraft fastener to process and autonomously report corrosion status to aircraft maintenance personnel. The long-term payoff for using SAFE technology will be in predictive maintenance for aging aircraft and rotorcraft systems, fugitive emissions applications such as control valves, chemical pipeline vessels, and industrial boilers. Predictive maintenance capability, service, and repair will replace the current practice of scheduled maintenance to substantially reduce operational costs. A summary of the SAFE concept, laboratory test results, and future field test plans is presented.

  9. Evaluation on mechanical and corrosion properties of steam generator tubing materials

    Energy Technology Data Exchange (ETDEWEB)

    Kim, In Sup; Lee, Byong Whi; Lee, Sang Kyu; Lee, Young Ho; Kim, Jun Whan; Lee, Ju Seok; Kwon, Hyuk Sang; Kim, Su Jung [Korea Advanced Institute of Science and Technology, Taejon (Korea, Republic of)

    1998-06-15

    Steam generator is one of the major components of nuclear reactor pressure boundary. It's main function os transferring heat which generated in the reactor to turbine generator through steam generator tube. In these days, steam generator tubing materials of operating plant are used Inconel 600 alloys. But according to the operation time, there are many degradation phenomena which included mechanical damage due to flow induced vibration and corrosion damage due to PWSCC, IGA/SCC and pitting etc. Recently Inconel 690 alloys are selected as new and replacement steam generator tubes for domestic nuclear power plant. But there are few study about mechanical and corrosion properties of Inconel 600 and 690. The objectives of this study is to evaluate and compare mechanical and corrosion propertied of steam generator tube materials.

  10. Evaluation on mechanical and corrosion properties of steam generator tubing materials

    International Nuclear Information System (INIS)

    Kim, In Sup; Lee, Byong Whi; Lee, Sang Kyu; Lee, Young Ho; Kim, Jun Whan; Lee, Ju Seok; Kwon, Hyuk Sang; Kim, Su Jung

    1998-06-01

    Steam generator is one of the major components of nuclear reactor pressure boundary. It's main function os transferring heat which generated in the reactor to turbine generator through steam generator tube. In these days, steam generator tubing materials of operating plant are used Inconel 600 alloys. But according to the operation time, there are many degradation phenomena which included mechanical damage due to flow induced vibration and corrosion damage due to PWSCC, IGA/SCC and pitting etc. Recently Inconel 690 alloys are selected as new and replacement steam generator tubes for domestic nuclear power plant. But there are few study about mechanical and corrosion properties of Inconel 600 and 690. The objectives of this study is to evaluate and compare mechanical and corrosion propertied of steam generator tube materials

  11. A High-Performance Corrosion-Resistant Iron-Based Amorphous Metal - The Effects of Composition, Structure and Environment on Corrosion Resistance

    International Nuclear Information System (INIS)

    Farmer, J.; Haslam, J.; Day, D.; Lian, T.; Saw, C.; Hailey, P.; Choi, J.S.; Rebak, R.; Yang, N.; Bayles, R.; Aprigliano, L.; Payer, J.; Perepezko, J.; Hildal, K.; Lavernia, E.; Ajdelsztajn, L.; Branagan, D.; Beardsley, B.

    2007-01-01

    The passive film stability of several Fe-based amorphous metal formulations have been found to be comparable to that of high-performance Ni-based alloys, and superior to that of stainless steels, based on electrochemical measurements of the passive film breakdown potential and general corrosion rates. Chromium (Cr), molybdenum (Mo) and tungsten (W) provide corrosion resistance; boron (B) enables glass formation; and rare earths such as yttrium (Y) lower critical cooling rate (CCR). The high boron content of this particular amorphous metal also makes it an effective neutron absorber, and suitable for criticality control applications, as discussed in companion publications. Corrosion data for SAM2X5 (Fe 49.7 Cr 17.7 Mn 1.9 Mo 7.4 W 1.6 B 15.2 C 3.8 Si 2.4 ) is discussed here. (authors)

  12. Evaluation of corrosion products formed by sulfidation as inhibitors of the naphthenic corrosion of AISI-316 steel

    Science.gov (United States)

    Sanabria-Cala, J. A.; Montañez, N. D.; Laverde Cataño, D.; Y Peña Ballesteros, D.; Mejía, C. A.

    2017-12-01

    Naphthenic acids present in oil from most regions worldwide currently stand as the main responsible for the naphthenic corrosion problems, affecting the oil-refining industry. The phenomenon of sulfidation, accompanying corrosion processes brought about by naphthenic acids in high-temperature refining plant applications, takes place when the combination of sulfidic acid (H2S) with Fe forms layers of iron sulphide (FeS) on the material surface, layers with the potential to protect the material from attack by other corrosive species like naphthenic acids. This work assessed corrosion products formed by sulfidation as inhibitors of naphthenic corrosion rate in AISI-316 steel exposed to processing conditions of simulated crude oil in a dynamic autoclave. Calculation of the sulfidation and naphthenic corrosion rates were determined by gravimetry. The surfaces of the AISI-316 gravimetric coupons exposed to acid systems; were characterized morphologically by X-Ray Diffraction (XRD) and X-ray Fluorescence by Energy Dispersive Spectroscopy (EDS) combined with Scanning Electron Microscopy (SEM). One of the results obtained was the determination of an inhibiting effect of corrosion products at 250 and 300°C, where lower corrosion rate levels were detected. For the temperature of 350°C, naphthenic corrosion rates increased due to deposition of naphthenic acids on the areas where corrosion products formed by sulfidation have lower homogeneity and stability on the surface, thus accelerating the destruction of AISI-316 steel. The above provides an initial contribution to oil industry in search of new alternatives to corrosion control by the attack of naphthenic acids, from the formation of FeS layers on exposed materials in the processing of heavy crude oils with high sulphur content.

  13. Evaluation of the corrosion behavior of the al-356 alloy in NaCl solutions

    Directory of Open Access Journals (Sweden)

    Mauricio Vásquez Rendón

    2011-01-01

    Full Text Available Cellular metals are a new class of materials with promising applications and a unique combination of physical, chemical and mechanical properties. The Al-356 alloy is used to manufacture metal foams from NaCl preforms. Despite the usefulness of these materials, their performance may be affected by corrosion due to residual salt. This paper reports the study of the behavior of the Al-356 alloy in chloride solutions by electrochemical techniques in rotating disk electrode. The cathodic reaction of oxygen reduction is the crucial stage of process dissolution of the material, which shows that is the oxygen transport which limits the corrosion process.

  14. Eco-Friendly Inhibitors for Copper Corrosion in Nitric Acid: Experimental and Theoretical Evaluation

    Science.gov (United States)

    Savita; Mourya, Punita; Chaubey, Namrata; Singh, V. K.; Singh, M. M.

    2016-02-01

    The inhibitive performance of Vitex negundo, Adhatoda vasica, and Saraka asoka leaf extracts on corrosion of copper in 3M HNO3 solution was investigated using gravimetric, potentiodynamic polarization, and electrochemical impedance spectroscopic techniques. Potentiodynamic polarization studies indicated that these extracts act as efficient and predominantly cathodic mixed inhibitor. Thermodynamic parameters revealed that the adsorption of these inhibitors on copper surface was spontaneous, controlled by physiochemical processes and occurred according to the Langmuir adsorption isotherm. AFM examination of copper surface confirmed that the inhibitor prevented corrosion by forming protective layer on its surface. The correlation between inhibitive effect and molecular structure was ascertained by density functional theory data.

  15. Evaluation of steam corrosion and water quenching behavior of zirconium-silicide coated LWR fuel claddings

    Science.gov (United States)

    Yeom, Hwasung; Lockhart, Cody; Mariani, Robert; Xu, Peng; Corradini, Michael; Sridharan, Kumar

    2018-02-01

    This study investigates steam corrosion of bulk ZrSi2, pure Si, and zirconium-silicide coatings as well as water quenching behavior of ZrSi2 coatings to evaluate its feasibility as a potential accident-tolerant fuel cladding coating material in light water nuclear reactor. The ZrSi2 coating and Zr2Si-ZrSi2 coating were deposited on Zircaloy-4 flats, SiC flats, and cylindrical Zircaloy-4 rodlets using magnetron sputter deposition. Bulk ZrSi2 and pure Si samples showed weight loss after the corrosion test in pure steam at 400 °C and 10.3 MPa for 72 h. Silicon depletion on the ZrSi2 surface during the steam test was related to the surface recession observed in the silicon samples. ZrSi2 coating (∼3.9 μm) pre-oxidized in 700 °C air prevented substrate oxidation but thin porous ZrO2 formed on the coating. The only condition which achieved complete silicon immobilization in the oxide scale in aqueous environments was the formation of ZrSiO4 via ZrSi2 coating oxidation in 1400 °C air. In addition, ZrSi2 coatings were beneficial in enhancing quenching heat transfer - the minimum film boiling temperature increased by 6-8% in the three different environmental conditions tested. During repeated thermal cycles (water quenching from 700 °C to 85 °C for 20 s) performed as a part of quench tests, no spallation and cracking was observed and the coating prevented oxidation of the underlying Zircaloy-4 substrate.

  16. Comparative study on Ti/Zr/V and chromate conversion treated aluminum alloys: Anti-corrosion performance and epoxy coating adhesion properties

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Wen; Li, Wenfang, E-mail: mewfli@163.com; Mu, Songlin; Fu, Nianqing; Liao, Zhongmiao

    2017-05-31

    Highlights: • The surface roughness and surface free energy of the AA6063 are significantly increased after TZVCC treatment. • The anti-corrosion performance of the AA6063 is effectively enhanced after TZVCC treatment. • Both the corrosion resistance and wet adhesion properties of the epoxy coating on the AA6063 are noticeably improved after TZVCC treatment. - Abstract: In this study, a Ti/Zr/V conversion coating (TZVCC) was deposited on the surface of aluminum alloy 6063 (AA6063) as an alternative of the chromate conversion coating (CCC). Both the TZVCC treated AA6063 (TZVCC/AA6063) and CCC treated AA6063 (CCC/AA6063) were characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), atomic force microscope (AFM) and contact angle measuring device. The anti-corrosion performance of the TZVCC/AA6063 and CCC/AA6063 was evaluated by electrochemical measurements and neutral salt spray tests. It showed that both the surface roughness and surface free energy of the AA6063 were significantly increased after TZVCC treatment. The anti-corrosion performance of TZVCC/AA6063 was superior to that of CCC/AA6063. In addition, the effects of the TZVCC and CCC on the adhesion properties and anti-corrosion performance of epoxy coating applied on samples were examined by pull-off tests and electrochemical impedance spectroscopy (EIS). The dry, wet and recovery adhesive strengths of the epoxy coating on TZVCC treated samples (epoxy coated TZVCC/AA6063) were very close to those of epoxy coating on CCC treated ones (epoxy coated CCC/AA6063). The epoxy coated TZVCC/AA6063 showed better corrosion resistance than the epoxy coated CCC/AA6063 and epoxy coated AA6063.

  17. Evaluation of aluminum-clad spent fuel corrosion in Argentine basins

    International Nuclear Information System (INIS)

    Haddad, R.; Loberse, A.N.; Semino, C.J.; Guasp, R.

    2001-01-01

    An IAEA sponsored Coordinated Research Program was extended to study corrosion effects in several sites. Racks containing Aluminum samples were placed in different positions of each basin and periodic sampling of all the waters was performed to conduct chemical analysis. Different forms of corrosion have been encountered during the programme. In general, the degree of degradation is inversely proportional to the purity of the water. Maximum pit depths after 2 years of exposure are in the range of 100-200 μm. However, sediments deposited on the coupon surfaces seem to be responsible for the developing of large pits (1-2 mm in diameter). In many cases, what appears to be iron oxide particles were found originated by the corrosion of carbon steel components present elsewhere in the basin. These results correlate with observations made on the fuel itself, during exhaustive visual inspection. (author)

  18. Study of the Effect of Sol pH and Nanoclay Incorporation on the Corrosion Protection Performance of a Silane Sol-Gel Coating

    Directory of Open Access Journals (Sweden)

    Najmeh Asadi

    2014-06-01

    Full Text Available This work is aimed to evaluate the role of nanoclay in the protective performance of an eco-friendly silane sol-gel layer applied on mild steel substrate in 0.1M sodium chloride solution. At the first step, the effect of pH of the silane solution, consisting of a mixture of γ-glycidoxypropiltrimethoxysilane and methyltriethoxysilane and tetraethoxysilane, on the coating performance was evaluated through electrochemical noise measurements. The values of characteristic charge as a parameter extracted from shot noise theory revealed that the sol pH determining the rate of hydrolysis can play an important role in the corrosion protection behavior of silane coatings. Then, the influence of clay nanoparticles on the corrosion protective performance of the hybrid silane film was studied through taking advantage of electrochemical techniques, including electrochemical impedance spectroscopy and polarization curves, as well as surface analysis methods. The obtained electrochemical data including the values of charge transfer resistance, coating resistance, low frequency impedance and corrosion current density showed that the silane sol gel film in the presence of clay nanoparticles can present an improved corrosion protection. The behavior was connected to an enhancement in the coating barrier properties. Moreover, FESEM and water contact angle confirmed the higher reticulation in case of the coating incorporating nanoclay.

  19. Vehicle accelerated corrosion test procedures for automotive in Malaysia

    Directory of Open Access Journals (Sweden)

    Anuar Liza

    2017-01-01

    Full Text Available An accelerated corrosion test, known as proving ground accelerated test, is commonly performed by automotive manufacturers to evaluate the corrosion performance of a vehicle. The test combines corrosion and durability inputs to detect potential failures that may occur during in-service conditions. Currently, the test is conducted at an external test center overseas. Such test is aimed to simulate the effects of one year accelerated corrosion in severe corrosive environment of the north-east and south east of America. However, the test results obtained do not correlate with the actual corrosion conditions observed in the Malaysian market, which is likely attributed to the different test environment of the tropical climate of vehicles in service. Therefore, a vehicle accelerated corrosion test procedure that suits the Malaysian market is proposed and benchmarked with other global car manufacturers that have their own dedicated corrosion test procedure. In the present work, a test track is used as the corrosion test ground and consists of various types of roads for structural durability exposures. Corrosion related facilities like salt trough, mud trough and gravel road are constructed as addition to the existing facilities. The establishment of accelerated corrosion test facilities has contributed to the development of initial accelerated corrosion test procedure for the national car manufacturer. The corrosion exposure is monitored by fitting test coupons at the underbody of test vehicle using mass loss technique so that the desired corrosion rate capable of simulating the real time corrosion effects for its target market.

  20. Evaluation of flow accelerated corrosion by coupled analysis of corrosion and flow dynamics (1), major features of coupled analysis and application for evaluation of wall thinning rate

    International Nuclear Information System (INIS)

    Naitoh, Masanori; Uchida, Shunsuke; Okada, Hidetoshi; Uehara, Yasushi; Koshizuka, Seiichi

    2009-01-01

    Six calculation steps have been prepared for predicting flow accelerated corrosion (FAC) occurrence and evaluating wall thinning rate. (1) Flow pattern and temperature in each elemental volume along the flow path are obtained with a 1D plant system code, (2) Corrosive conditions, e.g., oxygen concentration and electrochemical corrosion potential (ECP) along the flow path are calculated with a hydrazine-oxygen reaction code, (3) Precise flow patterns and mass transfer coefficients at the structure surface are calculated with a 3D CFD code, (4) Danger zones are evaluated by combining major FAC parameters, (5) Wall thinning rates are calculated with the coupled models of static electrochemical analysis and dynamic double oxide layer analysis at the identified danger zone, and then, (6) Residual life and effects of countermeasures can be evaluated. Anodic and cathodic current densities and ECPs were calculated with the static electrochemistry model, and ferrous ion release rate determined by the anodic current density was used as input for the dynamic double oxide layer model. Thickness of the oxide film and its characteristics determined by the dynamic double oxide layer model were used for the electrochemistry model to determine the resistances of cathodic current from the bulk to the surface and anodic current from the surface to the bulk. The calculated results of the coupled models had been compared with the data measured at operating Boiling Water Reactor (BWR) plants and it was demonstrated that the calculated results had good agreements with the measured ones. 6 step-evaluation procedures for liquid droplet impingement (LDI) were also proposed. (author)

  1. The Many Faces of Graphene as Protection Barrier. Performance under Microbial Corrosion and Ni Allergy Conditions

    Science.gov (United States)

    Gentil, Dana; del Campo, Valeria; Henrique Rodrigues da Cunha, Thiago; Henríquez, Ricardo; Garín, Carolina; Ramírez, Cristian; Flores, Marcos; Seeger, Michael

    2017-01-01

    In this work we present a study on the performance of CVD (chemical vapor deposition) graphene coatings grown and transferred on Ni as protection barriers under two scenarios that lead to unwanted metal ion release, microbial corrosion and allergy test conditions. These phenomena have a strong impact in different fields considering nickel (or its alloys) is one of the most widely used metals in industrial and consumer products. Microbial corrosion costs represent fractions of national gross product in different developed countries, whereas Ni allergy is one of the most prevalent allergic conditions in the western world, affecting around 10% of the population. We found that grown graphene coatings act as a protective membrane in biological environments that decreases microbial corrosion of Ni and reduces release of Ni2+ ions (source of Ni allergic contact hypersensitivity) when in contact with sweat. This performance seems not to be connected to the strong orbital hybridization that Ni and graphene interface present, indicating electron transfer might not be playing a main role in the robust response of this nanostructured system. The observed protection from biological environment can be understood in terms of graphene impermeability to transfer Ni2+ ions, which is enhanced for few layers of graphene grown on Ni. We expect our work will provide a new route for application of graphene as a protection coating for metals in biological environments, where current strategies have shown short-term efficiency and have raised health concerns. PMID:29292763

  2. The Many Faces of Graphene as Protection Barrier. Performance under Microbial Corrosion and Ni Allergy Conditions

    Directory of Open Access Journals (Sweden)

    Carolina Parra

    2017-12-01

    Full Text Available In this work we present a study on the performance of CVD (chemical vapor deposition graphene coatings grown and transferred on Ni as protection barriers under two scenarios that lead to unwanted metal ion release, microbial corrosion and allergy test conditions. These phenomena have a strong impact in different fields considering nickel (or its alloys is one of the most widely used metals in industrial and consumer products. Microbial corrosion costs represent fractions of national gross product in different developed countries, whereas Ni allergy is one of the most prevalent allergic conditions in the western world, affecting around 10% of the population. We found that grown graphene coatings act as a protective membrane in biological environments that decreases microbial corrosion of Ni and reduces release of Ni2+ ions (source of Ni allergic contact hypersensitivity when in contact with sweat. This performance seems not to be connected to the strong orbital hybridization that Ni and graphene interface present, indicating electron transfer might not be playing a main role in the robust response of this nanostructured system. The observed protection from biological environment can be understood in terms of graphene impermeability to transfer Ni2+ ions, which is enhanced for few layers of graphene grown on Ni. We expect our work will provide a new route for application of graphene as a protection coating for metals in biological environments, where current strategies have shown short-term efficiency and have raised health concerns.

  3. Pressurized water reactor fuel performance problems connected with fuel cladding corrosion processes

    International Nuclear Information System (INIS)

    Dobrevski, I.; Zaharieva, N.

    2008-01-01

    Generally, Pressurized Water Reactor (WWER, PWR) Fuel Element Performance is connected with fuel cladding corrosion and crud deposition processes. By transient to extended fuel cycles in nuclear power reactors, aiming to achieve higher burnup and better fuel utilization, the role of these processes increases significantly. This evolution modifies the chemical and electrochemical conditions in the reactor primary system, including change of fuel claddings' environment. The higher duty cores are always attended with increased boiling (sub-cooled nucleate boiling) mainly on the feed fuel assemblies. This boiling process on fuel cladding surfaces can cause different consequences on fuel element cladding's environment characteristics. In the case of boiling at the cladding surfaces without or with some cover of corrosion product deposition, the behavior of gases dissolved in water phase is strongly influenced by the vapor generation. The increase of vapor partial pressure will reduce the partial pressures of dissolved gases and will cause their stripping out. By these circumstances the concentrations of dissolved gases in cladding wall water layer can dramatically decrease, including also the case by which all dissolved gases to be stripped out. On the other hand it is known that the hydrogen is added to primary coolant in order to avoid the production of oxidants by radiolysis of water. It is clear that if boiling strips out dissolved hydrogen, the creation of oxidizing conditions at the cladding surfaces will be favored. In this case the local production of oxidants will be a result from local processes of water radiolysis, by which not only both oxygen (O 2 ) and hydrogen (H 2 ) but also hydrogen peroxide (H 2 O 2 ) will be produced. While these hydrogen and oxygen will be stripped out preferentially by boiling, the bigger part of hydrogen peroxide will remain in wall water phase and will act as the most important factor for creation of oxidizing conditions in fuel

  4. Corrosion evaluation of materials from the second deployment of the Gulf of Mexico Experiment

    Energy Technology Data Exchange (ETDEWEB)

    Zeman, G.J.

    1979-10-01

    The corrosion behavior and nature of films formed on 5052 aluminum, CA706 copper-nickel alloy, AL-6X stainless alloy, and grade 2 titanium in seawater during the second deployment of the Gulf of Mexico Experiment (GOME II) were evaluated by optical and scanning-electron microscopy as well as gravimetric measurements. The thickness of the corrosion-product and biofouling film on the copper-nickel alloy increased linearly with time over the 99-day duration of the experiment, whereas the film thickness on aluminum was independent of exposure time. The uniform corrosion of aluminum and the copper-nickel alloy, based upon defilmed metal loss from preweighed ring specimens, was approx. 0.3 and 0.7 mils, respectively, for the 55-day exposure period. The thin films formed on stainless alloy and titanium were composed primarily of organic residues. The corrosion resistance of titanium and stainless alloy was excellent under the conditions in this experiment, although some evidence for pitting attack was found for the latter material. This study is directed toward the evaluation of candidate materials for OTEC heat exchangers.

  5. Development of the advanced nuclear materials -Materials performance evaluation-

    International Nuclear Information System (INIS)

    Kim, Woo Chul; Noh, Kye Hoh; Han, Jung Hoh; Jung, Han Sub; Kim, Hong Pyo; Lee, Duk Hyun; Lee, Eun Heui; Hwang, Sung Sik; Huh, Doh Haeng

    1995-07-01

    The software for ACPD was modified to use multi-specimens and multi-frequency. The stress corrosion cracking resistance test of Alloy 600 in Pb contained water was performed by slow strain rate tester. The corrosion fatigue test machine was installed, and an autoclave for this test was purchased. The fatigue test was conducted in air. The stability for the long term test in DCPD was evaluated, and the improvement of current source and the revision of potential drop difference according to temperature variation increased the detection accuracy. A Ag/AgCl reference electrode and electrode support were assembled and the performance test was carried out at high temperature under high pressure. The zirconia pH electrode was assembled. The specimens with SUS304, Zr-2.5Nb were machined for irradiation assisted degradation test. The erosion/corrosion for the selected secondary side piping of Kori-1 was evaluated by CHECKMATE code. The chemical analysis and metallurgical inspection of the secondary piping of Kori-1 were conducted, and the erosion/corrosion test loop was made. 29 figs, 12 tabs, 11 refs. (Author)

  6. General Corrosion and Localized Corrosion of Waste Package Outer Barrier

    Energy Technology Data Exchange (ETDEWEB)

    K.G. Mon

    2004-10-01

    The waste package design for the License Application is a double-wall waste package underneath a protective drip shield (BSC 2004 [DIRS 168489]; BSC 2004 [DIRS 169480]). The purpose and scope of this model report is to document models for general and localized corrosion of the waste package outer barrier (WPOB) to be used in evaluating waste package performance. The WPOB is constructed of Alloy 22 (UNS N06022), a highly corrosion-resistant nickel-based alloy. The inner vessel of the waste package is constructed of Stainless Steel Type 316 (UNS S31600). Before it fails, the Alloy 22 WPOB protects the Stainless Steel Type 316 inner vessel from exposure to the external environment and any significant degradation. The Stainless Steel Type 316 inner vessel provides structural stability to the thinner Alloy 22 WPOB. Although the waste package inner vessel would also provide some performance for waste containment and potentially decrease the rate of radionuclide transport after WPOB breach before it fails, the potential performance of the inner vessel is far less than that of the more corrosion-resistant Alloy 22 WPOB. For this reason, the corrosion performance of the waste package inner vessel is conservatively ignored in this report and the total system performance assessment for the license application (TSPA-LA). Treatment of seismic and igneous events and their consequences on waste package outer barrier performance are not specifically discussed in this report, although the general and localized corrosion models developed in this report are suitable for use in these scenarios. The localized corrosion processes considered in this report are pitting corrosion and crevice corrosion. Stress corrosion cracking is discussed in ''Stress Corrosion Cracking of the Drip Shield, the Waste Package Outer Barrier, and the Stainless Steel Structural Material'' (BSC 2004 [DIRS 169985]).

  7. In vitro and in vivo corrosion evaluation of nickel-chromium- and copper-aluminum-based alloys.

    Science.gov (United States)

    Benatti, O F; Miranda, W G; Muench, A

    2000-09-01

    The low resistance to corrosion is the major problem related to the use of copper-aluminum alloys. This in vitro and in vivo study evaluated the corrosion of 2 copper-aluminum alloys (Cu-Al and Cu-Al-Zn) compared with a nickel-chromium alloy. For the in vitro test, specimens were immersed in the following 3 corrosion solutions: artificial saliva, 0.9% sodium chloride, and 1.0% sodium sulfide. For the in vivo test, specimens were embedded in complete dentures, so that one surface was left exposed. The 3 testing sites were (1) close to the oral mucosa (partial self-cleaning site), (2) surface exposed to the oral cavity (self-cleaning site), and (3) specimen bottom surface exposed to the saliva by means of a tunnel-shaped perforation (non-self-cleaning site). Almost no corrosion occurred with the nickel-chromium alloy, for either the in vitro or in vivo test. On the other hand, the 2 copper-aluminum-based alloys exhibited high corrosion in the sulfide solution. These same alloys also underwent high corrosion in non-self-cleaning sites for the in vivo test, although minimal attack was observed in self-cleaning sites. The nickel-chromium alloy presented high resistance to corrosion. Both copper-aluminum alloys showed considerable corrosion in the sulfide solution and clinically in the non-self-cleaning site. However, in self-cleaning sites these 2 alloys did not show substantial corrosion.

  8. Development of Electrodeposited Zn/nano-TiO2 Composite Coatings with Enhanced Corrosion Performance

    Science.gov (United States)

    Benea, L.; Dănăilă, E.

    2017-06-01

    Pure zinc coatings have been found ineffective when are used in aggressive environments such as those which contain chlorides or industrial pollutants [1]. In this paper, Zn/nano-TiO2 composite coatings with various contents of TiO2 nanoparticles (diameter size of 10 nm) were prepared on low-carbon steel by electro-codeposition technique. The deposition was carried out at different cathodic potentials ranging from -1600 mV to -2100 mV for different deposition times between 5-15 min. Pure Zn coatings were also produced under the same experimental conditions for comparison. Present work aims to investigate the effects of selected electrodeposition parameters (cathodic potential, TiO2 nanoparticle concentration in the plating bath and electrodeposition time) on the corrosion behavior of electrodeposited Zn/nano-TiO2 composite obtained. The corrosion experiments were performed in natural seawater, using electrochemical methods such as open circuit potential, potentiodynamic polarization and linear polarization resistance. The results showed that the inclusion of TiO2 nanoparticles into zinc matrix lead to an improved corrosion resistance comparatively with pure zinc coatings obtained under similar conditions.

  9. TEACHER PERFORMANCE EVALUATION

    Directory of Open Access Journals (Sweden)

    Guadalupe Iván Martínez-Chairez

    2015-07-01

    Full Text Available This research report comes from a study that was developed during the school years 2013-2014, 2014-2015, in the southern state of Chihuahua central region, in the education sector 25 consisting of five school zones that provide services to Meoqui municipalities, Julimes and Delicias. The study is a mixed court, correlational comprehensive sequential procedure. Some of the results is that there is a correlation between the 578 years of service of teachers and the score assigned to students in teaching career, but there is no association between teacher performance and the context in which it works, in addition there is no relationship between the teacher performance and school performance of students on standardized tests. 2.4% of the representative sample presented an excellent teacher performance, 7.3% have a bad teacher performance, but it is noteworthy that 39% of teachers observed lies with good teaching performance.

  10. Corrosion/94 conference papers

    International Nuclear Information System (INIS)

    Anon.

    1994-01-01

    The approximately 500 papers from this conference are divided into the following sections: Rail transit systems--stray current corrosion problems and control; Total quality in the coatings industry; Deterioration mechanisms of alloys at high temperatures--prevention and remediation; Research needs and new developments in oxygen scavengers; Computers in corrosion control--knowledge based system; Corrosion and corrosivity sensors; Corrosion and corrosion control of steel reinforced concrete structures; Microbiologically influenced corrosion; Practical applications in mitigating CO 2 corrosion; Mineral scale deposit control in oilfield-related operations; Corrosion of materials in nuclear systems; Testing nonmetallics for life prediction; Refinery industry corrosion; Underground corrosion control; Mechanisms and applications of deposit and scale control additives; Corrosion in power transmission and distribution systems; Corrosion inhibitor testing and field application in oil and gas systems; Decontamination technology; Ozone in cooling water applications, testing, and mechanisms; Corrosion of water and sewage treatment, collection, and distribution systems; Environmental cracking of materials; Metallurgy of oil and gas field equipment; Corrosion measurement technology; Duplex stainless steels in the chemical process industries; Corrosion in the pulp and paper industry; Advances in cooling water treatment; Marine corrosion; Performance of materials in environments applicable to fossil energy systems; Environmental degradation of and methods of protection for military and aerospace materials; Rail equipment corrosion; Cathodic protection in natural waters; Characterization of air pollution control system environments; and Deposit-related problems in industrial boilers. Papers have been processed separately for inclusion on the data base

  11. Corrosion and deposit evaluation in industrial plants by non destructive testing method

    International Nuclear Information System (INIS)

    Azali Muhammad; Abd Razak Hamzah; Abd Aziz Mohamed; Mohd Pauzi Ismail; S Saad; S Sayuti; S Ahmad

    2000-01-01

    In petrochemical plants, the detection of corrosion and evaluation of deposit in insulated pipes using a radiography method are very challenging tasks. This main degradation problem experienced by pipelines is due to water condensation. It will cause deposit and scale inside the pipe, as well as between the insulation and pipe for the cold temperature pipes. On the other hand, for the hot temperature pipes the main problem is mainly due to corrosion/erosion attack inside the pipe. In the case of corrosion study one of the most important parameters in a piping or pipeline to be monitored and measured is that the wall thickness. In general, most pipeline corrosion monitoring and evaluation for both insulated and non-insulated pipes is done by using an ultrasonic method. The most common technique for corrosion is that based on the A-Scan, using either a normal flow detector or some form of dedicated equipment. However, with recent development of ultrasonic technology, more advance method, namely B-Scan and C-scan techniques are also available. The most notable disadvantage of using this current method is that the insulation covered the pipe has to be removed before the inspection can be carried out and this is considered as not so cost effective. Due to this reason other alternative NDT method, namely radiographic testing method has been studied. The testing technique used in this studied are tangential technique and double wall radiographic technique which involve studying the changing in density of radiographic film. The result found using tangential technique is consistent with real thickness of the pipe. However for the later technique the result is only achieved with a reasonable accuracy when the changing in wall thickness is very small. The result of the studies is discussed in this paper

  12. Evaluation of flow accelerated corrosion by coupled analysis of corrosion and flow dynamics (2), flow dynamics calculations for determining mixing factors and mass transfer coefficients

    International Nuclear Information System (INIS)

    Uehara, Yasushi; Uchida, Shunsuke; Naitoh, Masanori; Okada, Hidetoshi; Koshizuka, Seiichi

    2009-01-01

    In order to predict and mitigate flow accelerated corrosion (FAC) of carbon steel piping in PWR and BWR secondary systems, computer program packages for evaluating FAC have been developed by coupling one through three dimensional (1-3D) computational flow dynamics (CFD) models and corrosion models. To evaluate corrosive conditions, e.g., oxygen concentration and electrochemical corrosion potential (ECP) along the flow path, flow pattern and temperature in each elemental volume were obtained with 1D computational flow dynamics (CFD) codes. Precise flow turbulence and mass transfer coefficients at the structure surface were calculated with 3D CFD codes to determine wall thinning rates. One of the engineering options is application of k-ε calculation as a 3D CFD code, which has limitation of detail evaluation of flow distribution at very surface of large scale piping. A combination of k-ε calculation and wall function was proposed to evaluate precise distribution of mass transfer coefficients with reasonable CPU volume and computing time and, at the same time, reasonable accuracy. (author)

  13. High-Performance Corrosion-Resistant Materials: Iron-Based Amorphous-Metal Thermal-Spray Coatings

    International Nuclear Information System (INIS)

    Farmer, J C; Haslam, J J; Wong, F; Ji, X; Day, S D; Branagan, D J; Marshall, M C; Meacham, B E; Buffa, E J; Blue, C A; Rivard, J K; Beardsley, M B; Weaver, D T; Aprigliano, L F; Kohler, L; Bayles, R; Lemieux, E J; Wolejsza, T M; Martin, F J; Yang, N; Lucadamo, G; Perepezko, J H; Hildal, K; Kaufman, L; Heuer, A H; Ernst, F; Michal, G M; Kahn, H; Lavernia, E J

    2004-01-01

    The multi-institutional High Performance Corrosion Resistant Materials (HPCRM) Team is cosponsored by the Defense Advanced Projects Agency (DARPA) Defense Science Office (DSO) and the Department of Energy (DOE) Office of Civilian Radioactive Waste Management (OCRWM), and has developed new corrosion-resistant, iron-based amorphous metals that can be applied as coatings with advanced thermal spray technology. Two compositions have corrosion resistance superior to wrought nickel-based Alloy C-22 (UNS No. N06022) in very aggressive environments, including concentrated calcium-chloride brines at elevated temperature. Corrosion costs the Department of Defense billions of dollars every year, with an immense quantity of material in various structures undergoing corrosion. For example, in addition to fluid and seawater piping, ballast tanks, and propulsions systems, approximately 345 million square feet of structure aboard naval ships and crafts require costly corrosion control measures. The use of advanced corrosion-resistant materials to prevent the continuous degradation of this massive surface area would be extremely beneficial. The Fe-based corrosion-resistant, amorphous-metal coatings under development may prove of importance for applications on ships. Such coatings could be used as an ''integral drip shield'' on spent fuel containers, as well as protective coatings that could be applied over welds, thereby preventing exposure to environments that might cause stress corrosion cracking. In the future, such new high-performance iron-based materials could be substituted for more-expensive nickel-based alloys, thereby enabling a reduction in the $58-billion life cycle cost for the long-term storage of the Nation's spent nuclear fuel by tens of percent

  14. Evaluation of cytotoxicity and corrosion resistance of orthodontic mini-implants

    Directory of Open Access Journals (Sweden)

    Celha Borges Costa Alves

    Full Text Available ABSTRACT Objective: To evaluate and compare in vitro cytotoxicity and corrosion resistance of mini-implants from three different commercial brands used for orthodontic anchorage. Methods: Six mini-implants (Conexão(tm, Neodent(tm and SIN(tm were separately immersed in artificial saliva (pH 6.76 for 30 and 60 days. The cytotoxicity of the corrosion extracts was assessed in L929 cell cultures using the violet crystal and MTT assays, as well as cell morphology under light microscopy. Metal surface characteristics before and after immersion in artificial saliva were assessed by means of scanning electron microscopy (SEM. The samples underwent atomic absorption spectrophotometry to determine the concentrations of aluminum and vanadium ions, constituent elements of the alloy that present potential toxicity. For statistical analysis, one-way ANOVA/Bonferroni tests were used for comparisons among groups with p < 0.05 considered significant. Statistical analysis was carried out with Graph Pad PRISM software Version 4.0. Results: No changes in cell viability or morphology were observed. Mini-implants SEM images revealed smooth surfaces with no obvious traces of corrosion. The extracts assessed by means of atomic absorption spectrophotometry presented concentrations of aluminum and vanadium ions below 1.0 µg/mL and 0.5 µg/mL, respectively. Conclusion: Orthodontic mini-implants manufactured by Conexão(tm, Neodent(tm and SIN(tm present high corrosion resistance and are not cytotoxic.

  15. Evaluation of cytotoxicity and corrosion resistance of orthodontic mini-implants.

    Science.gov (United States)

    Alves, Celha Borges Costa; Segurado, Márcio Nunes; Dorta, Miriam Cristina Leandro; Dias, Fátima Ribeiro; Lenza, Maurício Guilherme; Lenza, Marcos Augusto

    2016-01-01

    To evaluate and compare in vitro cytotoxicity and corrosion resistance of mini-implants from three different commercial brands used for orthodontic anchorage. Six mini-implants (Conexão(tm), Neodent(tm) and SIN(tm)) were separately immersed in artificial saliva (pH 6.76) for 30 and 60 days. The cytotoxicity of the corrosion extracts was assessed in L929 cell cultures using the violet crystal and MTT assays, as well as cell morphology under light microscopy. Metal surface characteristics before and after immersion in artificial saliva were assessed by means of scanning electron microscopy (SEM). The samples underwent atomic absorption spectrophotometry to determine the concentrations of aluminum and vanadium ions, constituent elements of the alloy that present potential toxicity. For statistical analysis, one-way ANOVA/Bonferroni tests were used for comparisons among groups with p < 0.05 considered significant. Statistical analysis was carried out with Graph Pad PRISM software Version 4.0. No changes in cell viability or morphology were observed. Mini-implants SEM images revealed smooth surfaces with no obvious traces of corrosion. The extracts assessed by means of atomic absorption spectrophotometry presented concentrations of aluminum and vanadium ions below 1.0 µg/mL and 0.5 µg/mL, respectively. Orthodontic mini-implants manufactured by Conexão(tm), Neodent(tm) and SIN(tm) present high corrosion resistance and are not cytotoxic.

  16. Evaluation of cytotoxicity and corrosion resistance of orthodontic mini-implants

    Science.gov (United States)

    Alves, Celha Borges Costa; Segurado, Márcio Nunes; Dorta, Miriam Cristina Leandro; Dias, Fátima Ribeiro; Lenza, Maurício Guilherme; Lenza, Marcos Augusto

    2016-01-01

    ABSTRACT Objective: To evaluate and compare in vitro cytotoxicity and corrosion resistance of mini-implants from three different commercial brands used for orthodontic anchorage. Methods: Six mini-implants (Conexão(tm), Neodent(tm) and SIN(tm)) were separately immersed in artificial saliva (pH 6.76) for 30 and 60 days. The cytotoxicity of the corrosion extracts was assessed in L929 cell cultures using the violet crystal and MTT assays, as well as cell morphology under light microscopy. Metal surface characteristics before and after immersion in artificial saliva were assessed by means of scanning electron microscopy (SEM). The samples underwent atomic absorption spectrophotometry to determine the concentrations of aluminum and vanadium ions, constituent elements of the alloy that present potential toxicity. For statistical analysis, one-way ANOVA/Bonferroni tests were used for comparisons among groups with p corrosion. The extracts assessed by means of atomic absorption spectrophotometry presented concentrations of aluminum and vanadium ions below 1.0 µg/mL and 0.5 µg/mL, respectively. Conclusion: Orthodontic mini-implants manufactured by Conexão(tm), Neodent(tm) and SIN(tm) present high corrosion resistance and are not cytotoxic. PMID:27901227

  17. Influence of hydroxyapatite coating thickness and powder particle size on corrosion performance of MA8M magnesium alloy

    Energy Technology Data Exchange (ETDEWEB)

    Sonmez, S. [Hakkari University, Dept. of Biomedical Eng., 30000 Hakkari (Turkey); Aksakal, B., E-mail: baksakal@yildiz.edu.tr [Yildiz Technical University, Chemical Metallurgy Faculty, Dept. of Metall and Mater Eng., Istanbul (Turkey); Dikici, B. [Yuzuncu Yil University, Dept. of Mechanical Eng., 65080 Van (Turkey)

    2014-05-01

    Graphical abstract: The corrosion resistance of magnesium alloys is the primary concern in biomedical applications. Micron and nano-scale hydroxyapatite (HA) was coated successfully on MA8M magnesium alloy substrates by using a sol–gel deposition. In this study, the effects of coating thicknesses and HA powder particle sizes on the adhesion strength and corrosion behavior were investigated. Potentiodynamic polarization tests were performed in a Ringer solution. The coatings before and after corrosion tests were characterized by adhesion tests, scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. The micro-scale-HA coated Mg substrates were more corrosion resistant than the nano-scale-HA coatings. The anodic activity of the micro-scale-HA coatings increased with increased coating thickness and the corrosion resistance of Mg substrates decreased. Corrosion susceptibilities of the nano-scale-HA coated samples were affected inversely. The coated film provided good barrier characteristics and achieved good corrosion protection for Mg substrates when compared to substrates without coatings. For micro-scale-HA coatings, anodic and cathodic activities were more intense for thicker films. When HA coatings are compared to nano-scale HA coatings, the micro-scale-HA coatings produced better current density values. Overall, as shown in Fig. 1, the best corrosion behavior of the Mg alloys was achieved using micro-scale HA powders at 30 μm coating thickness. - Highlights: • Nano and micro-scale-HA coatings provided good anti-corrosion performance compared to the uncoated ones. • The micro-scale-HA coated Mg substrates were more corrosion resistant than the nano-scale-HA coatings. • The best corrosion behavior was achieved for the micro-scale HA powders at 30 μm coating thickness. • Anodic activity decrease and cathodic activity increase with increasing film thickness. - Abstract: To improve the corrosion resistance of MA8M magnesium alloy, sol

  18. Corrosion performance of atmospheric plasma sprayed alumina coatings on AZ31B magnesium alloy under immersion environment

    Directory of Open Access Journals (Sweden)

    D. Thirumalaikumarasamy

    2014-12-01

    Full Text Available Plasma sprayed ceramic coatings are successfully used in many industrial applications, where high wear and corrosion resistance with thermal insulation are required. The alumina powders were plasma sprayed on AZ31B magnesium alloy with three different plasma spraying parameters. In the present work, the influence of plasma spray parameters on the corrosion behavior of the coatings was investigated. The corrosion behavior of the coated samples was evaluated by immersion corrosion test in 3.5 wt% NaCl solution. Empirical relationship was established to predict the corrosion rate of plasma sprayed alumina coatings by incorporating process parameters. The experiments were conducted based on a three factor, five-level, central composite rotatable design matrix. The developed relationship can be effectively used to predict the corrosion rate of alumina coatings at 95% confidence level. The results indicate that the input power has the greatest influence on corrosion rate, followed by stand-off distance and powder feed rate.

  19. Final examination of IDMS corrosion coupons

    International Nuclear Information System (INIS)

    Imrich, K.J.; Jenkins, C.F.

    1993-01-01

    The metallurgical examination of corrosion coupons removed from the Integrated DWPF Melter System (IDMS) was performed as part of the IDMS Materials Evaluation Program. The findings and conclusions of the evaluation program are presented in this report

  20. Corrosion of several components of the in-situ test performed in a deep geological granite disposal site

    International Nuclear Information System (INIS)

    Madina, Virginia; Azkarate, Inaki; Insausti, Mikel

    2004-01-01

    The corrosion damage experienced by different components in a deep geological disposal in a granite formation has been analysed. This in-situ test is part of the Full-scale Engineered Barriers EXperiment project (FEBEX) carried out in Grimsel (Switzerland). Two heaters, simulating the canister and the heat generated, were installed horizontally inside the guide tubes or liners and surrounded by highly compacted bentonite blocks. Coupons of several candidate metals for manufacturing HLW containers were introduced in these bentonite blocks, as well as sensors in order to monitor different physicochemical parameters during the test. The in- situ test began in July 1996 and in June 2002 one of the heaters, a section of the liner, several corrosion coupons and four sensors were extracted. The studied heater is a carbon steel cylinder with welded lids, with a wall thickness of 100 mm and 4.54 m long. The liner consists of a perforated carbon steel tube, 970 mm in diameter and 15 mm thick. Corrosion coupons were made of carbon steel, stainless steel, titanium, copper and cupronickel alloys. Two extensometer type sensors with an outer protection tube made of austenitic stainless steel were also analysed. Visual inspection of the above mentioned components, optical and scanning electron microscope study, together with EDS and XRD analyses of corrosion products, have been performed in order to analyse the corrosion suffered by these components. This has been complemented with the chemical and microbiological characterisation of bentonite samples. Results obtained in the study indicate a slight generalised corrosion for the heater, liner and corrosion coupons. The low humidity content of the bentonite surrounding the liner and the corrosion coupons, is the responsible of this practical absence of corrosion. The sensors studied show, however, an important corrosion damage. The sulphur rich corrosion products, the presence of Sulphate Reducing Bacteria (SRB) in the bentonite

  1. Evaluation methods for corrosion damage of components in cooling systems of nuclear power plants by coupling analysis of corrosion and flow dynamics (1). Major targets and development strategies of the evaluation methods

    International Nuclear Information System (INIS)

    Naitoh, Masanori; Uchida, Shunsuke; Koshizuka, Seiichi; Ninokata, Hisashi; Hiranuma, Naoki; Dosaki, Koji; Nishida, Koji; Akiyama, Minoru; Saitoh, Hiroaki

    2008-01-01

    Problems in major components and structural materials in nuclear power plants have often been caused by flow induced vibration and corrosion and their overlapping effects. In order to establish safe and reliable plant operation, future problems for structural materials should be predicted based on combined analyses of flow dynamics and corrosion and they should be mitigated before becoming serious issues for plant operation. Three approaches have been prepared for predicting future problems in structural materials: 1. Computer program packages for predicting future corrosion fatigue on structural materials, 2. Computer program packages for predicting future corrosion damage on structural materials, and 3. Computer program packages for predicting wall thinning caused by flow accelerated corrosion. General features of evaluation methods and their computer packages, technical innovations required for their development, and application plans for the developed approaches for plant operation are introduced in this paper. (author)

  2. Corrosion evaluation and control of cooling systems of nuclear power plants

    International Nuclear Information System (INIS)

    Kim, U. C.; Sung, K. W.; Na, J. W.

    2002-04-01

    We supplemented a database for evaluation of problems in high temperature corrosion degradation at domestic NPPs, and investigated corrosion mitigation methodologies for modification of water chemistry guidelines and operating conditions for life extension as follows: 1) crevice chemistry evaluation by using CAP code, hide-out return tests in a Crevice Test Apparatus, analysis of water chemistry guideline revision history; 2) analysis on main steam generator tube damages, H 2 -dependent crack propagation rate tests of Alloy 600 CRDM material, SCC test of Ni-based alloy in mid-ranged pH by electrochemical polarization and of reduced sulfur influence by corrosion potential measurement, Pb-and CuO-SCC behavior tests, TiO 2 inhibitor penetration test, SCC evaluation, electrochemical observation; 3) loop tests on erosion-corrosion resistance of piping material with ICr-1/2Mo and 21/4 Cr-1Mo, evaluation of current pH-controlling agents based on thermodynamic analysis of amines; 4) SCC susceptibility and H 2 -embrittlement tests of turbine material(3.5NiCrMoV); 5) analyses of Zn-compound for radioactivity reduction and of hydrolysis equilibrium with adsorption test against resins, CERT tests on PWSCC susceptibility of Alloy 600, evaluation of operation mode-dependent radiation level by using CRUSIM code; 6) solubility calculation of radiolysis products of NH 3 , the pH-controlling agent of small-and medium-sized reactors, temperature estimation for obtaining lowest N 2 solubility and of NH 3 content required for optimum pH control, fatigue crack growth test of SG materials(ASTM Grade 2 Ti)

  3. Evaluation of stabilization of steel surface corrosion by paints

    Directory of Open Access Journals (Sweden)

    Aleš Dvořák

    2005-01-01

    Full Text Available This article deals with laboratory experiments focused on protective and stabilizing effects of paints designed to protect rusted steel surfaces. Two well-known paints (the Hammerite No.1 Rustbeater synthetic paint and the Antirezin water-soluble paint have been evaluated. The standardized tests according to ČSN have been used for the evaluation. Stabilization of rusted steel surface hasn’t been demonstrated during the tests. The SEM test method that covers micro-analysis of elements has been used for the evaluation as well.

  4. Corrosion Resistance Evaluation of Welded AISI 316 Stainless Steel by Electrochemical Method

    International Nuclear Information System (INIS)

    Baik, Shin Young; Kim, Kwan Hyu

    1990-01-01

    Electrochemical potentiokinetic polarization technique is known as quantitative, non-destructive and a rapid method for detecting sensitization and is essentially suitable for use in industrial fields and as laboratory research tools. In this study, electrochemical method was tested as a convenient means of the corrosion resistance evaluation for AISI 316L and 316 stainless steel(SS) and their welded sections. The sections were welded by TIG, MIG, CO 2 and ARC in 0.5N HCl as well as 1N H 2 SO 4 electrolyte with or without 0.01N KSCN. The results confirmed that electrochemical method could be used conveniently for corrosion resistance evaluation except reactivation aspect

  5. Electrochemical noise evaluation of anodized aluminum. Comparative study against corrosion behaviour in the atmosphere

    International Nuclear Information System (INIS)

    Betancourt, N.; Corvo, F.; Mendoza, A.; Simancas, J.; Morcillo, M.; Gonzalez, J. A.; Fragata, F.; Pena, J. J.; Sanchez de Villalaz, M.; Flores, S.; Almeida, E.; Rivero, S.; Rincon, O. T. de.

    2003-01-01

    The present work reports the evaluation of aluminum and anodized aluminum by electrochemical noise, as a part of the PATINE/CYTED project of the working group NS5. A visual examination is also made. The samples were exposed at several Ibero-American atmospheres up to 2 years of exposure. Different thickness of anodized aluminum were evaluated. The electrochemical potential noise of the 5 μm unexposed sample (pattern) showed a different behaviour to that showed by the other anodized specimens. This could be due to a slower sealed of the samples of higher thickness. The same behavior was observed on the samples exposed at the rural station. el Pardo. According to the visual examination, the samples of bare aluminum and those of anodized 5 μm thickness were the most affected by pitting corrosion in the highly polluted atmospheres. A good correlation between corrosion behaviour determined by visual examination and EN was obtained. (Author) 4 refs

  6. Evaluation of flow accelerated corrosion by coupled analysis of corrosion and flow dynamics. Relationship of oxide film thickness, hematite/magnetite ratio, ECP and wall thinning rate

    International Nuclear Information System (INIS)

    Uchida, Shunsuke; Naitoh, Masanori; Okada, Hidetoshi; Uehara, Yasushi; Koshizuka, Seiichi

    2011-01-01

    Systematic approaches to evaluate flow accelerated corrosion (FAC) are desired before discussing application of countermeasures for FAC. First, future FAC occurrence should be evaluated to identify locations where a higher possibility of FAC occurrence exists, and then, wall thinning rate at the identified FAC occurrence zone is evaluated to obtain the preparation time for applying countermeasures. Wall thinning rates were calculated with two coupled models: 1.static electrochemical analysis and 2.dynamic oxide layer growth analysis. The anodic current density and the electrochemical corrosion potential (ECP) were calculated with the static electrochemistry model based on an Evans diagram. The ferrous ion release rate, determined by the anodic current density, was applied as input for the dynamic double oxide layer model. Some of the dissolved ferrous ion was removed to the bulk water and others precipitated on the surface as magnetite particles. The thickness of oxide layer was calculated with the dynamic oxide layer growth model and then its value was used as input in the electrochemistry model. It was confirmed that the calculated results (corrosion rate and ECP) based on the coupled models were in good agreement with the measured ones. Higher ECP was essential for preventing FAC rate. Moderated conditions due to lower mass transfer coefficients resulted in thicker oxide layer thickness and then higher ECP, while moderated corrosion conditions due to higher oxidant concentrations resulted in larger hematite/magnetite rate and then higher ECP.

  7. Instrument performance evaluation

    International Nuclear Information System (INIS)

    Swinth, K.L.

    1993-03-01

    Deficiencies exist in both the performance and the quality of health physics instruments. Recognizing the implications of such deficiencies for the protection of workers and the public, in the early 1980s the DOE and the NRC encouraged the development of a performance standard and established a program to test a series of instruments against criteria in the standard. The purpose of the testing was to establish the practicality of the criteria in the standard, to determine the performance of a cross section of available instruments, and to establish a testing capability. Over 100 instruments were tested, resulting in a practical standard and an understanding of the deficiencies in available instruments. In parallel with the instrument testing, a value-impact study clearly established the benefits of implementing a formal testing program. An ad hoc committee also met several times to establish recommendations for the voluntary implementation of a testing program based on the studies and the performance standard. For several reasons, a formal program did not materialize. Ongoing tests and studies have supported the development of specific instruments and have helped specific clients understand the performance of their instruments. The purpose of this presentation is to trace the history of instrument testing to date and suggest the benefits of a centralized formal program

  8. Long-term corrosion studies

    International Nuclear Information System (INIS)

    Gdowski, G.

    1998-01-01

    The scope of this activity is to assess the long-term corrosion properties of metallic materials under consideration for fabricating waste package containers. Three classes of metals are to be assessed: corrosion resistant, intermediate corrosion resistant, and corrosion allowance. Corrosion properties to be evaluated are general, pitting and crevice corrosion, stress-corrosion cracking, and galvanic corrosion. The performance of these materials will be investigated under conditions that are considered relevant to the potential emplacement site. Testing in four aqueous solutions, and vapor phases above them, and at two temperatures are planned for this activity. (The environmental conditions, test metals, and matrix are described in detail in Section 3.0.) The purpose and objective of this activity is to obtain the kinetic and mechanistic information on degradation of metallic alloys currently being considered for waste package containers. This information will be used to provide assistance to (1) waste package design (metal barrier selection) (E-20-90 to E-20-92), (2) waste package performance assessment activities (SIP-PA-2), (3) model development (E-20-75 to E-20-89). and (4) repository license application

  9. Accelerated Test Method for Corrosion Protective Coatings Project

    Science.gov (United States)

    Falker, John; Zeitlin, Nancy; Calle, Luz

    2015-01-01

    This project seeks to develop a new accelerated corrosion test method that predicts the long-term corrosion protection performance of spaceport structure coatings as accurately and reliably as current long-term atmospheric exposure tests. This new accelerated test method will shorten the time needed to evaluate the corrosion protection performance of coatings for NASA's critical ground support structures. Lifetime prediction for spaceport structure coatings has a 5-year qualification cycle using atmospheric exposure. Current accelerated corrosion tests often provide false positives and negatives for coating performance, do not correlate to atmospheric corrosion exposure results, and do not correlate with atmospheric exposure timescales for lifetime prediction.

  10. Standard guide for conducting and evaluating galvanic corrosion tests in electrolytes

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    1981-01-01

    1.1 This guide covers conducting and evaluating galvanic corrosion tests to characterize the behavior of two dissimilar metals in electrical contact in an electrolyte under low-flow conditions. It can be adapted to wrought or cast metals and alloys. 1.2 This guide covers the selection of materials, specimen preparation, test environment, method of exposure, and method for evaluating the results to characterize the behavior of galvanic couples in an electrolyte. Note 1—Additional information on galvanic corrosion testing and examples of the conduct and evaluation of galvanic corrosion tests in electrolytes are given in Refs (1) through (7). 1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicabil...

  11. Electrosynthesis of Polyaniline-TiO2 Nanocomposite Films on Aluminum Alloy 3004 Surface and its Corrosion Protection Performance

    Directory of Open Access Journals (Sweden)

    M. Shabani-Nooshabadi

    2013-03-01

    Full Text Available The direct synthesis of polyaniline-TiO2 nanocomposite coatings on aluminum alloy 3004 (AA3004 surface has been investigated by using the galvanostatic method. The synthesized coatings were characterized by FT-IR, SEM-EDX, SEM and AFM. Optical absorption spectroscopy reveals the formation of the emeraldine oxidation state form of polyaniline-TiO2 nanocomposite. The corrosion performances of polyaniline-TiO2 nanocomposite coatings were investigated in 3.5% NaCl solution by Tafel polarization and Electrochemical Impedance Spectroscopy (EIS methods. The corrosion rate of polyaniline-TiO2 nanocomposite coating on AA3004 was found ∼260 times lower than bare AA3004 and corrosion potentials of these coatings have shifted to more positive potentials (105 mV. The results of this study clearly ascertain that the polyaniline-TiO2 nanocomposite coating has outstanding potential to protect the AA3004 against corrosion in a chloride environment.

  12. Corrosion and Materials Performance in biomass fired and co-fired power plants

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Larsen, OH; Biede, O

    2003-01-01

    not previously encountered in coal-fired power plants. The type of corrosion attack can be directly ascribed to the composition of the deposit and the metal surface temperature. In woodchip boilers, a similar corrosion rate and corrosion mechanism has on some occasions been observed. Co-firing of straw (10...... and 20% energy basis) with coal has shown corrosion rates lower than those in straw-fired plants. With both 10 and 20% straw, no chlorine corrosion was seen. This paper will describe the results from in situ investigations undertaken in Denmark on high temperature corrosion in biomass fired plants....... Results from 100% straw-firing, woodchip and co-firing of straw with coal will be reported. The corrosion mechanisms observed are summarized and the corrosion rates for 18-8 type stainless steels are compared....

  13. HLA RTI performance evaluation

    CSIR Research Space (South Africa)

    Malinga, L

    2009-07-01

    Full Text Available size of the UDP packet of the network, namely 64 KB, when using the best effort mode. The performance analysis task of the different RTIs was undertaken for two reasons. The first is to re-establish a High Level Architecture (HLA) in our Research... exchange messages over the network with the RTI Gateway process, via TCP sockets or UDP in order to realise the services associated with the RTI. The allocation of CPU resources to the federate and the RTIA process is exclusively managed...

  14. On the application of thermodynamics of corrosion for service life design of concrete structures

    DEFF Research Database (Denmark)

    Küter, Andre; Geiker, Mette Rica; Møller, Per

    2010-01-01

    There are unexploited possibilities in the application of thermodynamics of corrosion for service life design (SLD) of concrete structures. Thermodynamics provides means for insightful descriptions of corrosion mechanisms and of corrosion protection mechanisms. Strategies for corrosion protection...... of the application of thermodynamics for SLD and gives examples of two applications: description of corrosion processes and design of countermeasures. Emphasis is set on chloride induced corrosion....... can be based on thermodynamically consistent corrosion mechanisms and evaluation of existing and design of new countermeasures can be performed using thermodynamics. Similarly, materials concepts for embedded electrodes can be designed using thermodynamics. The present paper provides a brief outline...

  15. Lifetime evaluation of superheater tubes exposed to steam oxidation, high temperature corrosion and creep

    Energy Technology Data Exchange (ETDEWEB)

    Henriksen, N [Elsamprojekt A/S, Faelleskemikerne, Fredericia (Denmark); Hede Larsen, O; Blum, R [I/S Fynsvaerket, Faelleskemikerne, Odense (Denmark)

    1996-12-01

    Advanced fossil fired plants operating at high steam temperatures require careful design of the superheaters. The German TRD design code normally used in Denmark is not precise enough for the design of superheaters with long lifetimes. The authors have developed a computer program to be used in the evaluation of superheater tube lifetime based on input related to tube dimensions, material, pressure, steam temperature, mass flux, heat flux and estimated corrosion rates. The program is described in the paper. As far as practically feasible, the model seems to give a true picture of the reality. For superheaters exposed to high heat fluxes or low internal heat transfer coefficients as is the case for superheaters located in fluidized bed environments or radiant environments, the program has been extremely useful for evaluation of surface temperature, oxide formation and lifetime. The total uncertainty of the method is mainly influenced by the uncertainty of the determination of the corrosion rate. More precise models describing the corrosion rate as a function of tube surface temperature, fuel parameters and boiler parameters need to be developed. (au) 21 refs.

  16. Evaluation of the corrosion resistance of AISI 316 stainless steel filters

    Directory of Open Access Journals (Sweden)

    Luzinete Pereira Barbosa

    2005-06-01

    Full Text Available In this investigation, the corrosion resistance of AISI 316 SS filters prepared with powders in the size ranges 74-44 µm and 210-105 µm and compacted with pressures of 300 MPa and 400 MPa has been evaluated in naturally aerated 0.5 M H2SO4 solution at 25 °C. Weight loss of filters manufactured with compacting pressure of 400 MPa were significantly higher than that of filters compacted at 300 MPa. The filter compacted at 400 MPa had higher carbon and nitrogen contents compared to those compacted at 300 MPa. The former also had chromium rich precipitates and oxides in the grain boundaries. The pores in filters compacted at 400 MPa were smaller than in filters compacted at 300 MPa. Smaller pores favor the formation of concentration cells and consequently, increased crevice corrosion.

  17. Electrochemical impedance spectroscopy (EIS) as a tool for measuring corrosion of polymer-coated fasteners used in treated wood

    Science.gov (United States)

    Samuel L. Zelinka; Lorraine Ortiz-Candelaria; Donald S. Stone; Douglas R. Rammer

    2009-01-01

    Currently, many of the polymer-coated fasteners on the market are designed for improved corrosion performance in treated wood; yet, there is no way to evaluate their corrosion performance. In this study, a common technique for measuring the corrosion performance of polymer-coated metals, electrochemical impedance spectroscopy (EIS), was used to evaluate commercial...

  18. Biodegradable Orthopedic Magnesium-Calcium (MgCa Alloys, Processing, and Corrosion Performance

    Directory of Open Access Journals (Sweden)

    Yuebin Guo

    2012-01-01

    Full Text Available Magnesium-Calcium (Mg-Ca alloy has received considerable attention as an emerging biodegradable implant material in orthopedic fixation applications. The biodegradable Mg-Ca alloys avoid stress shielding and secondary surgery inherent with permanent metallic implant materials. They also provide sufficient mechanical strength in load carrying applications as opposed to biopolymers. However, the key issue facing a biodegradable Mg-Ca implant is the fast corrosion in the human body environment. The ability to adjust degradation rate of Mg-Ca alloys is critical for the successful development of biodegradable orthopedic implants. This paper focuses on the functions and requirements of bone implants and critical issues of current implant biomaterials. Microstructures and mechanical properties of Mg-Ca alloys, and the unique properties of novel magnesium-calcium implant materials have been reviewed. Various manufacturing techniques to process Mg-Ca based alloys have been analyzed regarding their impacts on implant performance. Corrosion performance of Mg-Ca alloys processed by different manufacturing techniques was compared. In addition, the societal and economical impacts of developing biodegradable orthopedic implants have been emphasized.

  19. Evaluation of the corrosion resistance of Ni-Co-B coatings in simulated PEMFC environment

    Energy Technology Data Exchange (ETDEWEB)

    Gamboa, S.A.; Valenzuela, E.; Sebastian, P.J. [CIE-UNAM, 62580 Temixco, Morelos (Mexico); Gonzalez-Rodriguez, J.G. [UAEM-CIICAp, Av. Universidad 1001, Col. Chamilpa, 62210 Cuernavaca, Mor. (Mexico); Campillo, B. [Facultad de Quimica-UNAM, Cd. Universitaria, DF, CP 04510 (Mexico); Reyes-Rojas, A. [CIMAV, Miguel de Cervantes 120, Complejo Ind. Chihuahua, 31109 Chihuahua, Chih. (Mexico)

    2006-05-20

    The corrosion resistance behavior of Ni-Co-B coated carbon steel, Al 6061 alloy and 304 stainless steel was evaluated in simulated proton exchange membrane fuel cell (PEMFC) environment. The phase structure of the NiCoB based alloy was determined by Rietveld analysis. The PEMFC environment was constituted of 0.5M H{sub 2}SO{sub 4} at 60{sup o}C and the evaluation techniques employed included potentiodynamic polarization, linear polarization resistance, open circuit potential measurements and electrochemical impedance spectroscopy. The results showed that in all cases the corrosion resistance of the Ni-Co-B coating was higher than that of the uncoated alloys; about two orders of magnitude with respect to carbon steel and an order of magnitude compared to 304 stainless steel. Except for the uncoated 304 type stainless steel, the polarization curves for the coated specimens did not exhibit a passive region but only anodic dissolution. The corrosion potential value, E{sub corr}, was always nobler for the coated samples than for the uncoated specimens. This was true for the stainless steel in the passive region, but in the active state for the carbon steel and Al 6061 alloy. The corrosion of the underlying alloy occurred due to filtering of the solution through coating defects like microcracks, pinholes, etc. During the filtering process the E{sub corr} value of the coating decreased slowly until it reached a steady state value, close to the E{sub corr} value of the underlying alloy. (author)

  20. Corrosion Performance of AISI-309 Exposed to Molten Salts V2O5-Na2SO4 at 700°C Applying EIS and Rp Electrochemical Techniques

    Directory of Open Access Journals (Sweden)

    E. F. Diaz

    2015-01-01

    Full Text Available The corrosion performance of AISI-309 exposed 5 days to molten salts 50 mol% V2O5-50 mol% Na2SO4 at 700°C is reported in this paper. Such evaluation was made using three electrochemical techniques: potentiodynamic polarization curve (PC, electrochemical impedance spectroscopy (EIS, and linear polarization resistance (Rp. From PC, the Tafel slopes, Icorr, and Ecorr were obtained. From Nyquist and Bode plots, it was possible to determine two different stages; the first one showed just one loop, which indicated the initial formation of Cr2O3 layer over the metallic surface; after that, the dissolution of Cr2O3 formed a porous layer, which became part of the corrosion products; at the same time a NiO layer combined with sulfur was forming, which was suggested as the second stage, represented by two capacitive loops. EIS plots were in agreement with the physical characterization made from SEM and EDS analyses. Fitting of EIS experimental data allowed us to propose two electrical circuits, being in concordance with the corrosion stages. Parameters obtained from the simulation of EIS data are also reported. From the results, it was stated that AISI-309 suffered intergranular corrosion due to the presence of sulfur, which diffused to the metallic surface through a porous Cr2O3 layer.

  1. Environmental variables evaluation on concrete structures corrosion for medium level activities repositories

    International Nuclear Information System (INIS)

    Requena, Carlos; Alvarez, Marta G.; Duffo, Gustavo S.

    2000-01-01

    The main purpose of this work was to evaluate the long term durability of reinforced concrete structures as medium-level waste container material. Electrochemical techniques have been used to evaluate the corrosion behaviour of steel rebars in several solutions simulating the liquid present in the pores of both alkaline and carbonated concrete in the presence of sulphate ions. Results shown that a decrease in p H has an adverse effect on the critical sulphate concentration. The inhibition effect of high carbonate/bicarbonate concentration is also shown. (author)

  2. Virtual reality presentation for nondestructive evaluation of rebar corrosion in concrete based on IBEM

    International Nuclear Information System (INIS)

    Kyung, Je Woon; Leelarkiet, V.; Ohtsu, Masayasu; Yokata, Masaru

    2004-01-01

    In order to evaluate the corrosion of reinforcing steel-bars (rebar) in concrete, a nondestructive evaluation by the half-cell potential method is currently applied. In this study, potentials measured on a concrete surface are compensated into those on the concrete-rebar interface by the inverse boundary element method (IBEM). Because these potentials are obtained three-dimensionally (3-D), 3-D visualization is desirable. To this end, a visualization system has been developed by using VRML (Virtual Reality Modeling Language). As an application, results of a reinforced concrete (RC) slab with corroded rebars are visualized and discussed.

  3. Fabrication of imitative stress corrosion cracking specimens suitable for electromagnetic nondestructive evaluations using solid state bonding

    International Nuclear Information System (INIS)

    Yusa, Noritaka; Hashizume, Hidetoshi; Uchimoto, Tetsuya; Takagi, Toshiyuki

    2011-01-01

    This study proposes a method to fabricate an artificial defect that is almost identical to stress corrosion cracking from the viewpoint of electromagnetic nondestructive evaluations. The key idea is to realize a region having electrical resistance embedded inside a conductive materials using solid state bonding. A rough region is introduced into the surface of the materials to be bonded so that the region is partially bonded to realize electrical resistance. Experimental demonstrations are carried out using type 316L austenitic stainless steels. Eddy current tests and subsequent numerical evaluations are conducted to discuss the validity of the proposed method. (author)

  4. Method of evaluation of stress corrosion cracking susceptibility of clad fuel tubes

    International Nuclear Information System (INIS)

    Takase, Iwao; Yoshida, Toshimi; Ikeda, Shinzo; Masaoka, Isao; Nakajima, Junjiro.

    1986-01-01

    Purpose: To determine, by an evaluation in out-pile test, the stress corrosion cracking susceptibility of clad fuel tubes in the reactor environment. Method: A plurality of electrodes are mounted in the circumferential direction on the entire surface of cladding tubes. Of the electrodes, electrodes at two adjacent places are used as measuring terminals and electrodes at another two places adjacent thereto are used as constant-current terminals. With a specific current flowing in the constant-current terminals, measurements are made of a potential difference between the terminals to be measured, and from a variation in the potential difference the depth of cracking of the cladding tube surface is presumed to determine the stress corrosion cracking susceptibility of the cladding tube. To check the entire surface of the cladding tube, the cladding tube is moved by each block in the circumferential direction by a contact changeover system, repeating the measurements of the potential difference. Contact type electrodes are secured with an insulator and held in uniform contact with the cladding tube by a spring. It is detachable by use of a locking system and movable as desired. Thus the stress corrosion cracking susceptibility can be determined without mounting the cladding tube through and also a fuel failure can be prevented. (Horiuchi, T.)

  5. Evaluation of the susceptibility to corrosion by pites of supermartensitic stainless steel with different superficial finishing

    International Nuclear Information System (INIS)

    Freitas, Mario Jose Bueno de Souza

    2015-01-01

    The objective of this study is to evaluate the susceptibility by pitting corrosion in a supermartensitic stainless steel (13%Cr) with different surface finishes, in an environment that simulates the conditions found in the range of the Brazilian marine subsoil before the dense layer of salt - the so-called pre-salt. In this study were conducted electrochemical tests of potentiodynamic anodic polarization and electrochemical impedance spectroscopy (EIS) in environment containing 35, 50 and 190 g/L of NaCl and dissolved oxygen concentrations <10, 100 and 500ppb. Were also used the techniques of Moessbauer spectroscopy and EDS (Energy Dispersive Spectrometry) coupled to a scanning electron microscope (SEM) for microstructural characterization of 13%Cr steel. It was observed by the electrochemical tests, the increase in the concentration of chloride ions in solution makes the studied steel more susceptible to localized corrosion. It was also observed that the material showed less susceptibility to pitting corrosion when its surface was less rough. (author)

  6. Evaluation of stress corrosion cracking as a function of its resistance to eddy currents

    International Nuclear Information System (INIS)

    Yusa, Noritaka; Hashizume, Hidetoshi

    2009-01-01

    This study discusses the equivalent conductivity, the equivalent width, and the equivalent resistance of stress corrosion cracks from the viewpoint of eddy current testing. Four artificial stress corrosion cracks were prepared for this study, and their eddy current signals were gathered using two absolute pancake probes and two differential type plus point probes. Then their numerical models were evaluated using finite element simulations on the basis of the measured eddy current signals and their profiles revealed by destructive tests. The results of this study revealed that whereas the equivalent conductivity and the equivalent width depend on the exciting frequency utilized, the equivalent resistance of a crack has much less dependency, which agrees well with an earlier report. This study also revealed that the resistance of a crack depends on probe utilized. Larger probes tend to lead to smaller crack resistance. Pancake type probes tend to lead to larger crack resistance than plus point probes. Analyzing the results together with earlier reports indicates that cracks with a large equivalent conductivity tend to have large equivalent width, and supports the validity of assuming the minimum resistance of a stress corrosion crack whereas considering the conductivity and the width individually would not be viable.

  7. Corrosion test by alternated immersion. Evaluation of the real meaning of the values of electrode potential

    International Nuclear Information System (INIS)

    Rend M, J.L.; Valencia, G.

    1996-01-01

    In the rehearsal of alternate immersion, type CEBELCOR, is usually carried out the pursuit of the variation of the potential of the electrode of the sample of interest. With the time, the obtained data become an important tool in the analysis of the evolution of the answer of the material it attacks corrosive of the means, with the time of material exhibition, with the advance of the exhibition that in it finishes instance it refers to different superficial conditions. In this work the chemical and thermodynamic aspects of the system potential the layout of the diagrams of electrode potential and the differences are revised in the capacity protector versus pH, or Pourbaix diagrams, the analysis is revised usually accepted in the determination of the biggest or smaller capacity protector in a quantity of energy required for the removal of a rust, starting from the difference in the potential in the electron of the atomic structure of the element or moment in that the test tube enters in the composed solution that is oxidized and the inclusion of the electron in the simulator and the value in the moment of the exit. With base in the first approach to the thermodynamic relationships and the corrosion phenomena, the investigation is analyzed by the GROUP OF CORROSION AND PROTECTION of the Antioquia University. It is shown as, for studies in similar materials and in means with small differences, the use of the potentials, loses validity like tool for comparative evaluations

  8. Evaluation of the protection behaviour of reinforcement steel against corrosion induced by chlorides in reinforced mortar specimens; Avaliacao do comportamento frente a corrosao pelo ataque de cloreto de argamassa armada apos varios tratamentos protetores

    Energy Technology Data Exchange (ETDEWEB)

    Crivelaro, Marcos

    2002-07-01

    In this work various treatments for protecting reinforcing steels against corrosion induced by chlorides have been evaluated. Additives to mortars and surface treatments given to reinforcing steels were evaluated as corrosion protection measures. In the preliminary tests the corrosion resistance of a CA 50 steel treated by immersion in nearly 50 different solutions, was determined. The solutions were prepared with tannins (from various sources) and/or benzotriazole, and during immersion, a surface film formed on the steel. The corrosion resistance of the coated steels was evaluated in a saturated Ca(OH){sub 2} solution with 5% (wt) NaCl. Preliminary tests were also carried out with mortars reinforced with uncoated steel to which tannin or lignin was added. Two organic coatings, a monocomponent and a bicomponent type, formulated specially for this investigation, with both tannin and benzotriazole, were also tested in the preliminary tests to select the coating with better corrosion protection property. The bicomponent type (epoxy coating) showed better performance than the monocomponent type coating, and the former was therefore chosen to investigate the corrosion performance on CA 50 steel inside mortar specimens. From the preliminary tests, two solutions with tannin from two sources, Black Wattle (Acacia mearnsii) and Brazilian tea (Ilex paraguariensis St. Hill), to which benzotriazole and phosphoric acid were added, were chosen. Mortar specimens reinforced with CA50 steel treated by immersion in these two solutions were prepared. Also, epoxy coated CA50 steel was tested as reinforcement inside mortar specimens. Mortars reinforced with uncoated CA50 steel were also prepared and corrosion tested for comparison. The effect of tannin and lignin as separate additives to the mortar on the corrosion resistance of uncoated steel was also studied. The reinforced mortar specimens were tested with various cycles of immersion for 2 days in 3.5% (wt) NaCl followed by with air

  9. Dry Process Fuel Performance Evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Myung Seung; Song, K. C.; Moon, J. S. and others

    2005-04-15

    The objective of the project is to establish the performance evaluation system of DUPIC fuel during the Phase II R and D. In order to fulfil this objectives, irradiation test of DUPIC fuel was carried out in HANARO using the non-instrumented and SPND-instrumented rig. Also, the analysis on the in-reactor behavior analysis of DUPIC fuel, out-pile test using simulated DUPIC fuel as well as performance and integrity assessment in a commercial reactor were performed during this Phase. The R and D results of the Phase II are summarized as follows : - Performance evaluation of DUPIC fuel via irradiation test in HANARO - Post irradiation examination of irradiated fuel and performance analysis - Development of DUPIC fuel performance code (modified ELESTRES) considering material properties of DUPIC fuel - Irradiation behavior and integrity assessment under the design power envelope of DUPIC fuel - Foundamental technology development of thermal/mechanical performance evaluation using ANSYS (FEM package)

  10. Dry Process Fuel Performance Evaluation

    International Nuclear Information System (INIS)

    Yang, Myung Seung; Song, K. C.; Moon, J. S. and others

    2005-04-01

    The objective of the project is to establish the performance evaluation system of DUPIC fuel during the Phase II R and D. In order to fulfil this objectives, irradiation test of DUPIC fuel was carried out in HANARO using the non-instrumented and SPND-instrumented rig. Also, the analysis on the in-reactor behavior analysis of DUPIC fuel, out-pile test using simulated DUPIC fuel as well as performance and integrity assessment in a commercial reactor were performed during this Phase. The R and D results of the Phase II are summarized as follows : - Performance evaluation of DUPIC fuel via irradiation test in HANARO - Post irradiation examination of irradiated fuel and performance analysis - Development of DUPIC fuel performance code (modified ELESTRES) considering material properties of DUPIC fuel - Irradiation behavior and integrity assessment under the design power envelope of DUPIC fuel - Foundamental technology development of thermal/mechanical performance evaluation using ANSYS (FEM package)

  11. Nondestructive technique application for corrosion evaluation by hydrogen charging of stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jin Kyung, E-mail: leejink@deu.ac.kr [Department of Mechanical Engineering, Dongeui University, Busan (Korea, Republic of); Bae, Dong Su [Department of Advanced Materials Engineering, Dongeui University, Busan (Korea, Republic of); Lee, Sang Pill; Hwang, Sung Guk [Department of Mechanical Engineering, Dongeui University, Busan (Korea, Republic of); Lee, Joon Hyun [School of Mechanical Engineering, Pusan National University, Busan (Korea, Republic of)

    2016-11-01

    Highlights: • We have studied on the nondestructive technique application for corrosion evaluation by hydrogen charging of stainless steel. An ultrasonic test (UT) is an useful method to evaluate the mechanical properties of material. By measuring the velocity and the attenuation of ultrasonic wave propagating the hydrogen charged stainless steel, the relation of ultrasonic wave and mechanical properties of hydrogen charged 316L stainless steel was discussed. However, in order to evaluate the dynamic behavior of materials, an acoustic emission (AE) technique was applied to investigate the corrosion characteristics of hydrogen charged specimen. Acoustic emission is one of elastic waves caused by dislocation, cracks initiation and propagation within material from loading outside. The waveform of the acoustic emission is different depending on the damage mechanism of material. Lots of AE parameters such as energy, duration time, event and amplitude were used to analyze the dynamic behavior of the hydrogen charged specimen. • A conventional 316L stainless steel was used in this study, and electrochemical treat system for hydrogen charging of the specimen. ASTM (G142) type tensile specimens (diameter 6.0 mm, gage length 28.6 mm) were prepared, and sulfuric acid(H{sub 2}SO{sub 4}) and arsenic trioxide(As{sub 2}O{sub 3}) were used as the electrolyte, and potentiostat(HA 151) supplied the current to platinum wire and specimen. • Tensile strength and attenuation coefficient has a relation to some extent. Therefore, we could estimate the tensile strength and the hydrogen charging time by measuring the attenuation coefficient using ultrasonic wave nondestructively. • Acoustic emission technique was useful to evaluate the dynamic damage because AE parameters of AE event, average energy and average frequency showed various change by external loading at the specimens with and without hydrogen. - Abstract: Caused corrosion by hydrogen on stainless steel using

  12. Development of corrosion models to ensure reliable performance of nuclear power plants

    International Nuclear Information System (INIS)

    Kritzky, V.G.; Stjazhkin, P.S.

    1993-01-01

    The safety and reliability of the coolant circuits in nuclear power plants depend much on corrosion and corrosion products transfer processes. Various empirical models have been developed which are applicable to particular sets of operational conditions. In our laboratory a corrosion model has been worked out, which is based on the thermodynamic properties of the compounds, participating in corrosion process and on the assumption, that the corrosion process is controlled by the solubilities of the corrosion products forming the surface oxide layer. The validity of the model has been verified by use of retrospective experimental data, which have been obtained for a series of structural materials such as e.g., carbon and stainless steels, Cu-, Al-, and Zr alloys. With regard for hydriding the model satisfactorily describes stress corrosion cracking process in water-salt environments. This report describes a model based on the thermodynamic properties of the compounds participating in the corrosion process, and on the assumption that the corrosion process is controlled by the solubilities of the corrosion products forming the surface oxide layer

  13. Evaluation of flow accelerated corrosion by coupled analysis of corrosion and flow dynamics (3), relationship of oxide film thickness, hematite/magnetite ratio, ECP and wall thinning rate

    International Nuclear Information System (INIS)

    Uchida, Shunsuke; Naitoh, Masanori; Okada, Hidetoshi; Uehara, Yasushi; Koshizuka, Seiichi

    2009-01-01

    Systematic approaches for evaluating flow accelerated corrosion (FAC) are desired before discussing application of countermeasures for FAC. Firstly, future FAC occurrence should be evaluated to identify locations where a higher possibility of FAC occurrence exists, and then, wall thinning rate at the identified FAC occurrence zone is evaluated to obtain the preparation time for applying countermeasures. Wall thinning rates were calculated with the coupled models of static electrochemical analysis and dynamic double oxide layer analysis. Anodic current density and electrochemical corrosion potential (ECP) were calculated with the static electrochemistry model based on an Evans diagram and ferrous ion release rate determined by the anodic current density was applied as input for the dynamic double oxide layer model. Some of the dissolved ferrous ion was removed to the bulk water and others precipitated on the surface as magnetite particles. The thickness of oxide layer was calculated with the dynamic double oxide layer model and then was applied as input for the electrochemistry model. It was confirmed that the calculated results based on the coupled models resulted good agreement with the measured ones. Higher ECP was essential for preventing FAC rate. Moderated conditions due to lower mass transfer coefficients resulted in thicker oxide layer thickness and then higher ECP, while moderated corrosion conditions due to higher oxidant concentrations resulted in larger hematite/magnetite rate and then higher ECP. (author)

  14. The influence of loading on the corrosion of steel in cracked ordinary Portland cement and high performance concretes

    Science.gov (United States)

    Jaffer, Shahzma Jafferali

    Most studies that have examined chloride-induced corrosion of steel in concrete have focused on sound concrete. However, reinforced concrete is seldom uncracked and very few studies have investigated the influence of cracked concrete on rebar corrosion. Furthermore, the studies that have examined the relationship between cracks and corrosion have focused on unloaded or statically loaded cracks. However, in practice, reinforced concrete structures (e.g. bridges) are often dynamically loaded. Hence, the cracks in such structures open and close which could influence the corrosion of the reinforcing steel. Consequently, the objectives of this project were (i) to examine the effect of different types of loading on the corrosion of reinforcing steel, (ii) the influence of concrete mixture design on the corrosion behaviour and (iii) to provide data that can be used in service-life modelling of cracked reinforced concretes. In this project, cracked reinforced concrete beams made with ordinary Portland cement concrete (OPCC) and high performance concrete (HPC) were subjected to no load, static loading and dynamic loading. They were immersed in salt solution to just above the crack level at their mid-point for two weeks out of every four (wet cycle) and, for the remaining two weeks, were left in ambient laboratory conditions to dry (dry cycle). The wet cycle led to three conditions of exposure for each beam: (i) the non-submerged region, (ii) the sound, submerged region and (iii) the cracked mid-section, which was also immersed in the solution. Linear polarization resistance and galvanostatic pulse techniques were used to monitor the corrosion in the three regions. Potentiodynamic polarization, electrochemical current noise and concrete electrical resistance measurements were also performed. These measurements illustrated that (i) rebar corroded faster at cracks than in sound concrete, (ii) HPC was more protective towards the rebar than OPCC even at cracks and (iii) there

  15. Effects of laser remelting on microstructures and immersion corrosion performance of arc sprayed Al coating in 3.5% NaCl solution

    Science.gov (United States)

    Sun, Ze; Zhang, Donghui; Yan, Baoxu; Kong, Dejun

    2018-02-01

    An arc sprayed aluminum (Al) coating on S355 steel was processed using a laser remelting (LR). The microstructures, chemical element composition, and phases of the obtained Al coating were analyzed using a field mission scanning electronic microscope (FESEM), energy dispersive spectrometer (EDS), and X-ray diffractometer (XRD), respectively, and the residual stresses were measured using an X-ray diffraction stress tester. The immersion corrosion tests and potentiodynamic polarization of Al coating in 3.5% NaCl solution were performed to investigate the effects of LR on its immersion corrosion behaviors, and the corrosion mechanism of Al coating was also discussed. The results show that the arc sprayed Al coating is composed of Al phase, while that by LR is composed of Al-Fe and AlO4FeO6 phases, and the porosities and cracks in the arc sprayed Al coating are eliminated by LR, The residual stress of arc sprayed Al coating is -5.6 ± 18 MPa, while that after LR is 137.9 ± 12 MPa, which deduces the immersion corrosion resistance of Al coating. The corrosion mechanism of arc sprayed Al coating is pitting corrosion and crevice corrosion, while that by LR is uniform corrosion and pitting corrosion. The corrosion potential of arc sprayed Al coating by LR shifts positively, which improves its immersion corrosion resistance.

  16. Corrosion characteristics of K-claddings

    International Nuclear Information System (INIS)

    Park, J. Y.; Choi, B. K.; Jung, Y. H.; Jung, Y. H.

    2004-01-01

    The Improvement of the corrosion resistance of nuclear fuel claddings is the critical issue for the successful development of the high burn-up fuel. KAERI have developed the K-claddings having a superior corrosion resistance by controlling the alloying element addition and optimizing the manufacturing process. The comparative evaluation of the corrosion resistance for K-claddings and the foreign claddings was performed and the effect of the heat treatment on the corrosion behavior of K-claddings was also examined. Corrosion tests were carried out in the conditions of 360 .deg. C pure water, PWR-simulating loop and 400 .deg. C steam, From the results of the corrosion tests, it was found that the corrosion resistance of K-claddings is superior to those of Zry4 and A claddings and K6 showed a better corrosion resistance than K3. The corrosion behavior of K-cladding was strongly influenced by the final annealing rather than the intermediate annealing, and the corrosion resistance increased with decreasing the final annealing temperature

  17. Evaluation of thiosulfate as a substitute for hydrogen sulfide in sour corrosion fatigue studies

    Science.gov (United States)

    Kappes, Mariano Alberto

    This work evaluates the possibility of replacing hydrogen sulfide (H 2S) with thiosulfate anion (S2O32- ) in sour corrosion fatigue studies. H2S increases the corrosion fatigue crack growth rate (FCGR) and can be present in carbon steel risers and flowlines used in off-shore oil production. Corrosion tests with gaseous H2S require special facilities with safety features, because H2S is a toxic and flammable gas. The possibility of replacing H2S with S2O32-, a non-toxic anion, for studying stress corrosion cracking of stainless and carbon steels in H2S solutions was first proposed by Tsujikawa et al. ( Tsujikawa et al., Corrosion, 1993. 49(5): p. 409-419). In this dissertation, Tsujikawa work will be extended to sour corrosion fatigue of carbon steels. H2S testing is often conducted in deareated condition to avoid oxygen reaction with sulfide that yields sulfur and to mimic oil production conditions. Nitrogen deareation was also adopted in S2O3 2- testing, and gas exiting the cell was forced through a sodium hydroxide trap. Measurements of the sulfide content of this trap were used to estimate the partial pressure of H2S in nitrogen, and Henry's law was used to estimate the content of H2S in the solution in the cell. H2S was produced by a redox reaction of S2O 32-, which required electrons from carbon steel corrosion. This reaction is spontaneous at the open circuit potential of steel. Therefore, H2S concentration was expected to be maximum at the steel surface, and this concentration was estimated by a mass balance analysis. Carbon steel specimens exposed to S2O32- containing solutions developed a film on their surface, composed by iron sulfide and cementite. The film was not passivating and a good conductor of electrons. Hydrogen permeation experiments proved that this film controls the rate of hydrogen absorption of steels exposed to thiosulfate containing solutions. The absorption of hydrogen in S2O3 2- solutions was compared with the absorption of hydrogen in

  18. Performance Evaluations in Audit Firms

    DEFF Research Database (Denmark)

    Riise Johansen, Thomas; Christoffersen, Jeppe

    2017-01-01

    Previous research has only minimally examined the association between the behaviour and performance evaluations of individual auditors beyond the use of efficiency-focused evaluations. We examine the association between dysfunctional auditor behaviour and three evaluation foci: an efficiency focus......, a client focus and a quality focus. Our results, which are based on questionnaire responses from 196 auditors, demonstrate that an efficiency focus is not associated with dysfunctional behaviour. A client focus is found to be associated with dysfunctional behaviour. Finally, and perhaps most importantly......, our results show that it seems possible to limit dysfunctional behaviours through a quality focus in performance evaluations. Our results provide insights of use to practitioners and regulators on how performance evaluations may not only induce but also reduce dysfunctional auditor behaviours....

  19. Evaluation of atmospheric corrosion on electroplated zinc and zinc nickel coatings by Electrical Resistance (ER) Monitoring

    DEFF Research Database (Denmark)

    Møller, Per

    2013-01-01

    ER (Electrical Resistance) probes provide a measurement of metal loss, measured at any time when a metal is exposed to the real environment. The precise electrical resistance monitoring system can evaluate the corrosion to the level of nanometers, if the conductivity is compensated for temperature...... and magnetic fields. With this technique very important information about the durability of a new conversion coatings for aluminum, zinc and zinc alloys exposed to unknown atmospheric conditions can be gathered. This is expected to have a major impact on a number of industrial segments, such as test cars...

  20. Evaluation of the corrosion of aluminum tubes under conditions of natural imersion in aqueous medium

    International Nuclear Information System (INIS)

    Oliveira, M.F. de

    1985-01-01

    This work evaluates the corrosion of aluminum tubes under conditions of natural immersion in aqueous medium. Local attack was observed on the surface of the tubes for all temperatures studied. It was found that the mass flucturation of the samples tested in deionized water at room temperatures is practically inexistent. However, at temperatures of 45 and 60 0 C the aluminum react rapidly with water forming a film of hydrated oxide of aluminum known as bayerite. It was verified that the contact of graphite and particles containing high content of Cu with aluminum forms a galvanic couple which should be avoided. (Author) [pt

  1. Evaluation of the potential of additives as corrosion inhibitors of CA-50 carbon steel used as reinforcement in concretes

    International Nuclear Information System (INIS)

    Mennucci, Marina Martins

    2006-01-01

    In this work, various compounds were tested to evaluate their potential capability for their use as corrosion inhibitors of carbon steel reinforcement in concretes. The additives tested were sodium benzoate, polyethylene glycol, hexamethylenetetramine, benzotriazole and yttrium carbonate. Initially, exploratory tests were carried out to select the ones to be used as corrosion inhibitors, based on the inhibit ion efficiency determined from electrochemical tests, specifically polarization tests and electrochemical impedance spectroscopy. These tests were carried out in a solution composed of 0.01 N sodium hydroxide (NaOH) and 0.05 N potassium hydroxide (KOH) to simulate the composition of the solution inside the pores in concretes. The additive that presented the most promising potential to be used as corrosion inhibitor was benzotriazole (BTA). After the elimination of some compounds and selection of the additive with higher corrosion inhibit ion efficiency in the test medium, the effect of its concentration on the corrosion inhibition efficiency was evaluated. Sodium nitrite solutions with the same concentrations as those solutions with BTA were tested for comparison reasons. Sodium nitrite is a well established corrosion inhibitor for carbon steel reinforcement in concretes but it has been related to toxic effects. The BTA was associated to higher corrosion inhibition efficiencies than that of sodium nitrite in similar concentrations. A blackish adherent film was formed on the steel surface exposed to BTA solutions during long periods of immersion in the alkaline medium. The results suggest that BTA is a potential candidate for substitution of nitrites as corrosion inhibitor of reinforcements in concrete. (author)

  2. Evaluation of wall thinning profile by flow accelerated corrosion in separation and union pipe

    International Nuclear Information System (INIS)

    Watanabe, Shun; Yoneda, Kimitoshi

    2013-01-01

    Flow Accelerated Corrosion (FAC) is a pipe wall thinning phenomena to be monitored and managed in power plants with high priority. At present, its management has been conducted with conservative evaluation of thinning rate and residual lifetime of the piping based on wall thickness measurements. However, noticeable case of wall thinning was occurred at separation and union pipe. In such pipe system, it is a problem to manage section beneath reinforcing plate of T-tube pipe and 'crotch' of T-joint pipe; the region where wall thickness measurement is difficult to conduct with ordinary ultrasonic testing device. In this study, numerical analysis for separation and union part of T-tube and T-joint pipe was conducted, and wall thinning profile by Flow Accelerated Corrosion was evaluated by calculating mass transfer coefficient and geometry factor. Based on these results, we considered applicable wall thinning management for T-tube and T-joint pipe. In the case of union flow from main and branch pipe, the wall thinning profile of T-tube showed the tendency of increase at main pipe like semielliptical region. On the other hand, noticeable profile appeared at 'crotch' in T-joint. Although it was found that geometry factor of T-joint in this case was half the value of T-tube, an alternative evaluation method to previous one might be needed for the profiles of 'semielliptical region' and 'crotch'. (author)

  3. Analysis of Barrier Performance: Modelling of Copper corrosion scenarios with and without buffer erosion

    International Nuclear Information System (INIS)

    Benbow, Steven J.; Robinson, Peter C.; Watson, Sarah P.

    2011-02-01

    SKB have identified buffer erosion as a process that could potentially lead to increased corrosion of the copper canister. Buffer erosion can be caused by: the formation of bentonite (i.e., montmorillonite) colloids and their transport away from deposition holes in intersecting fractures containing dilute groundwaters (such as subglacial meltwaters); steep hydraulic gradients during buffer resaturation; or shearing of solid bentonite particles by rapidly flowing groundwater. Only colloidal removal of bentonite (the first of the processes listed) is considered in this study. The erosion of the bentonite leads to a reduction in density and swelling potential, and hence a lowering of transport resistances in the buffer that can make it easier for corrosive agents to transported to be the canister surface, resulting in increased levels of corrosion of the canister surface compared with those predicted in 'normal evolution' conditions. The reduction in bentonite density that follows as a consequence of erosion also leads to the possibility of breaching other safety functions of the buffer, for example prevention of canister sinking and resistance to shear deformation. These are not considered in this study. This report describes the modelling of copper corrosion processes in the SKB KBS-3 design concept. The modelling includes an initial representation of all relevant physical processes, but with some processes represented in more detail than others. This allows investigation of the impacts of the processes that are modelled on canister corrosion, allowing identification of the processes that impact most on the key performance measures for the EBS, which will help to focus modelling developments in future work. This work could be taken as the starting point in a longer-term modelling study in which the interactions between processes that affect canister corrosion are further investigated. Two high-level scenarios are considered in this work: a base case scenario in

  4. Analysis of Barrier Performance: Modelling of Copper corrosion scenarios with and without buffer erosion

    Energy Technology Data Exchange (ETDEWEB)

    Benbow, Steven J.; Robinson, Peter C.; Watson, Sarah P. (Quintessa Limited, Henley-on-Thames (United Kingdom))

    2011-02-15

    SKB have identified buffer erosion as a process that could potentially lead to increased corrosion of the copper canister. Buffer erosion can be caused by: the formation of bentonite (i.e., montmorillonite) colloids and their transport away from deposition holes in intersecting fractures containing dilute groundwaters (such as subglacial meltwaters); steep hydraulic gradients during buffer resaturation; or shearing of solid bentonite particles by rapidly flowing groundwater. Only colloidal removal of bentonite (the first of the processes listed) is considered in this study. The erosion of the bentonite leads to a reduction in density and swelling potential, and hence a lowering of transport resistances in the buffer that can make it easier for corrosive agents to transported to be the canister surface, resulting in increased levels of corrosion of the canister surface compared with those predicted in 'normal evolution' conditions. The reduction in bentonite density that follows as a consequence of erosion also leads to the possibility of breaching other safety functions of the buffer, for example prevention of canister sinking and resistance to shear deformation. These are not considered in this study. This report describes the modelling of copper corrosion processes in the SKB KBS-3 design concept. The modelling includes an initial representation of all relevant physical processes, but with some processes represented in more detail than others. This allows investigation of the impacts of the processes that are modelled on canister corrosion, allowing identification of the processes that impact most on the key performance measures for the EBS, which will help to focus modelling developments in future work. This work could be taken as the starting point in a longer-term modelling study in which the interactions between processes that affect canister corrosion are further investigated. Two high-level scenarios are considered in this work: a base case

  5. Corrosion/96 conference papers

    International Nuclear Information System (INIS)

    Anon.

    1996-01-01

    Topics covered by this conference include: cathodic protection in natural waters; cleaning and repassivation of building HVAC systems; worldwide opportunities in flue gas desulfurization; advancements in materials technology for use in oil and gas service; fossil fuel combustion and conversion; technology of corrosion inhibitors; computers in corrosion control--modeling and information processing; recent experiences and advances of austenitic alloys; managing corrosion with plastics; corrosion measurement technology; corrosion inhibitors for concrete; refining industry; advances in corrosion control for rail and tank trailer equipment; CO 2 corrosion--mechanisms and control; microbiologically influenced corrosion; corrosion in nuclear systems; role of corrosion in boiler failures; effects of water reuse on monitoring and control technology in cooling water applications; methods and mechanisms of scale and deposit control; corrosion detection in petroleum production lines; underground corrosion control; environmental cracking--relating laboratory results and field behavior; corrosion control in reinforced concrete structures; corrosion and its control in aerospace and military hardware; injection and process addition facilities; progress reports on the results of reinspection of deaerators inspected or repaired per RP0590 criteria; near 100% volume solids coating technology and application methods; materials performance in high temperature environments containing halides; impact of toxicity studies on use of corrosion/scale inhibitors; mineral scale deposit control in oilfield related operations; corrosion in gas treating; marine corrosion; cold climate corrosion; corrosion in the pulp and paper industry; gaseous chlorine alternatives in cooling water systems; practical applications of ozone in recirculating cooling water systems; and water reuse in industry. Over 400 papers from this conference have been processed separately for inclusion on the data base

  6. Evaluation of tribological wear and corrosion in coatings of diamalloy 4060NS deposited by thermal spray

    Science.gov (United States)

    Acuña R, S. M.; Moreno T, C. M.; Espinosa C, E. J.

    2017-12-01

    Surface engineering seeks the development of new techniques to improve the performance and life of components of machines or industrial facilities, always looking for low costs and the least possible environmental damage. Thermal projection is one of the techniques that is based on the projection of particles of compounds and alloys on properly prepared and heated substrates, these particles are driven by a stream of air passing through an oxyacetylene flame which gives the energy to the process; These coatings give the possibility to improve the properties of the materials or the maintenance of components to maximize the availability of service. In order to reduce the damage caused by wear and corrosion of a low carbon AISI 1020 steel, they were coated with a metal based alloy, studying the effect of the cobalt-chromium-silicon-tungsten carbide alloy coating (DIAMALLLOY 4060 NS). The coating was deposited with two different pressures in the gases supplied to the torch, obtaining two flames and working three thicknesses of coating that oscillate between 100-500μm, according to the number of deposited layers, making use of a projection gun Castolin Eutectic. Powder and substrate characterization was performed using X-Ray Diffraction (XRD) techniques, X-Ray Fluorescence (XRF), Scanning Electron Microscopy (SEM), spark emission spectroscopy and metallographic analysis. The results confirm the chemical nature and structure of the powder of the alloy and the substrate to be used, in addition, the thermal stability of the system was verified. The evaluation of the adhesion of the deposited layers was carried out by the implementation of pull-off tests according to ASTM D4541, in order to determine the type of failure that is presented. Mechanical wear was determined using a MT/60/NI microtest tribometer while electrochemical tests were performed using a suitable experimental unit for this purpose, confirming that the substrate exhibits lower wear levels when coated with

  7. Revisiting Mutual Fund Performance Evaluation

    OpenAIRE

    Angelidis, Timotheos; Giamouridis, Daniel; Tessaromatis, Nikolaos

    2012-01-01

    Mutual fund manager excess performance should be measured relative to their self-reported benchmark rather than the return of a passive portfolio with the same risk characteristics. Ignoring the self-reported benchmark introduces biases in the measurement of stock selection and timing components of excess performance. We revisit baseline empirical evidence in mutual fund performance evaluation utilizing stock selection and timing measures that address these biases. We introduce a new factor e...

  8. Licensee Performance Evaluation: Phase II

    International Nuclear Information System (INIS)

    Chakoff, H.E.; Speaker, D.M.; Thompson, S.R.; Cohen, S.C.

    1979-08-01

    This report details work performed during the second phase of a two-phase contract to develop methodology for Licensee Performance Evaluation. The Phase I report, NUREG/CR-0110 details initial efforts on the contract. The model developed in Phase I was used to evaluate nine additional facilities for this report. Performance indicators from noncompliance data were also evaluated. Methodology was developed employing the noncompliance indicators and used for 12 case studies. It was found that licensee event report indicators could be more easily identified and utilized than noncompliance indicators based on presently available data systems. However, noncompliance data, appropriately related to cause, could provide real insight into why performance was what it was

  9. Preparation of Cu–Ni–Fe alloy coating and its evaluation on corrosion behavior in 3.5% NaCl solution

    International Nuclear Information System (INIS)

    Zhou, Qiongyu; Jiang, Jibo; Zhong, Qingdong; Wang, Yi; Li, Ke; Liu, Huijuan

    2013-01-01

    Highlights: ► An uniform Cu–Ni–Fe alloy coating constituted of homogenous γ-phases was prepared on the surface of low-carbon steel. ► The increase of Ni has a significant promotion to produce a uniform and homogenous Cu–Ni–Fe alloy coating. ► Electrochemical test results indicated the excellent corrosion resistance of the coating with high Ni content. ► EIS test and results demonstrated the surface homogeneity or compactness of the coating with high Ni content. -- Abstract: In this paper, an attempt had been made to prepare a Cu–Ni–Fe alloy coating for improving the corrosion resistance of the low-carbon steel. The surface heat treatment of coated low-carbon steel was performed at 1000 °C for 3 h under hydrogen atmosphere. The structure and microstructure of coatings was separately analyzed by X-ray diffraction (XRD) and scanning electron microscope (SEM). The corrosion resistance of the samples was evaluated by potentiodynamic polarization (Tafel) and electrochemical impedance spectroscopy (EIS). Results indicated that a compact alloy coating was formed on the surface of low-carbon steel and the Ni content had a prodigious impact to the microstructure, composition and structure of Cu–Ni–Fe alloy coating. Apart from that, significant improvements in corrosion resistance were achieved by using the Cu–Ni–Fe alloy coating, which constituting of homogeneous γ-phases

  10. Composite plasma electrolytic oxidation to improve the thermal radiation performance and corrosion resistance on an Al substrate

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Donghyun [Department of Materials Science and Engineering, Pusan National University, Busan 46241 (Korea, Republic of); Sung, Dahye [Department of Materials Science and Engineering, Pusan National University, Busan 46241 (Korea, Republic of); Korea Institute of Industrial Technology (KITECH), Busan 46742 (Korea, Republic of); Lee, Junghoon [Department of Mechanical Engineering, Stevens Institute of Technology, Hoboken, NJ 07030 (United States); Kim, Yonghwan [Korea Institute of Industrial Technology (KITECH), Busan 46742 (Korea, Republic of); Chung, Wonsub, E-mail: wschung1@pusan.ac.kr [Department of Materials Science and Engineering, Pusan National University, Busan 46241 (Korea, Republic of)

    2015-12-01

    Highlights: • Composite plasma electrolytic oxidation was performed using dispersed CuO particles in convectional PEO electrolyte. • Thermal radiation performance and corrosion resistance were examined by FT-IR spectroscopy and electrochemical methods, respectively. • Deposited copper oxide on the surface of the Al substrate was enhanced the corrosion resistance and the emissivity compared with the conventional PEO. - Abstract: A composite plasma electrolytic oxidation (PEO) was performed for enhancing the thermal radiation performance and corrosion resistance on an Al alloy by dispersing cupric oxide (CuO) particles in a conventional PEO electrolyte. Cu-based oxides (CuO and Cu{sub 2}O) formed by composite PEO increased the emissivity of the substrate to 0.892, and made the surface being dark color, similar to a black body, i.e., an ideal radiator. In addition, the corrosion resistance was analyzed using potentio-dynamic polarization and electrochemical impedance spectroscopy tests in 3.5 wt.% NaCl aqueous solution. An optimum condition of 10 ampere per square decimeter (ASD) current density and 30 min processing time produced appropriate surface morphologies and coating thicknesses, as well as dense Cu- and Al-based oxides that constituted the coating layers.

  11. The effect of cerium-based conversion treatment on the cathodic delamination and corrosion protection performance of carbon steel-fusion-bonded epoxy coating systems

    Energy Technology Data Exchange (ETDEWEB)

    Ramezanzadeh, B., E-mail: ramezanzadeh@aut.ac.ir [Department of Surface Coatings and Corrosion, Institute for Color Science and Technology (ICST), 16765-654, Tehran (Iran, Islamic Republic of); Rostami, M. [Department of Nanomaterials and Nanocoatings, Institute for Color Science and Technology (ICST), 16765-654, Tehran (Iran, Islamic Republic of)

    2017-01-15

    Highlights: • Steel surface was treated by Ce and acid phosphoric solutions. • Ce treatment considerably enhanced the surface energy and produce nanoscale roughness. • Ce treated samples showed enhanced adhesion to FBE coating. • Ce treatment of steel significantly reduced the FBE cathodic delamination rate. • Ce treated sample showed enhanced corrosion resistance. - Abstract: The effect of surface pre-treatment of pipe surface by green cerium compound and phosphoric acid solution on the fusion-bonded epoxy (FBE) coating performance was studied. The composition and surface morphology of the steel samples treated by acid and Ce solutions were characterized by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM), equipped with energy dispersive spectroscopy (EDS). Also, the surface free energy was evaluated on these samples through contact angle measurements. In addition, the effect of Ce and acid washing procedures on the adhesion properties and corrosion protection performance of the FBE was examined by pull-off, salt spray and electrochemical impedance spectroscopy (EIS) tests. Results showed that compared to acid washing, the chemical treatment by Ce solution noticeably increased the surface free energy of steel, improved the adhesion properties of FBE, decreased the cathodic delamination rate of FBE, and enhanced the coating corrosion resistance compared to the acid washed samples.

  12. Use of an Electrochemical Split Cell Technique to Evaluate the Influence of Shewanella oneidensis Activities on Corrosion of Carbon Steel.

    Directory of Open Access Journals (Sweden)

    Robert Bertram Miller

    Full Text Available Microbially induced corrosion (MIC is a complex problem that affects various industries. Several techniques have been developed to monitor corrosion and elucidate corrosion mechanisms, including microbiological processes that induce metal deterioration. We used zero resistance ammetry (ZRA in a split chamber configuration to evaluate the effects of the facultatively anaerobic Fe(III reducing bacterium Shewanella oneidensis MR-1 on the corrosion of UNS G10180 carbon steel. We show that activities of S. oneidensis inhibit corrosion of steel with which that organism has direct contact. However, when a carbon steel coupon in contact with S. oneidensis was electrically connected to a second coupon that was free of biofilm (in separate chambers of the split chamber assembly, ZRA-based measurements indicated that current moved from the S. oneidensis-containing chamber to the cell-free chamber. This electron transfer enhanced the O2 reduction reaction on the coupon deployed in the cell free chamber, and consequently, enhanced oxidation and corrosion of that electrode. Our results illustrate a novel mechanism for MIC in cases where metal surfaces are heterogeneously covered by biofilms.

  13. Determination of the Optimum Conditions in Evaluation of Kiwi Juice as Green Corrosion Inhibitor of Steel in Hydrochloric Acid

    Directory of Open Access Journals (Sweden)

    Khalid Hamid Rasheed

    2018-08-01

    Full Text Available The corrosion protection of low carbon steel in 2.5 M HCl solution by kiwi juice was studied at different temperatures and immersion times by weight loss technique. To study the determination of the optimum conditions from statistical design in evaluation of a corrosion inhibitor, three variables, were considered as the most dominant variables. These variables are: temperature, inhibitor concentration (extracted kiwi juice and immersion time at static conditions. These three variables are manipulated through the experimental work using central composite rotatable Box – Wilson Experimental Design (BWED where second order polynomial model was proposed to correlate the studied variables with the corrosion rate of low carbon steel alloy to estimate the coefficients by nonlinear regression analysis method based on Rosenbrock and Quasi-Newton estimation method in as few experiments as possible to determinate of the optimum conditions of the proposed polynomial adopted via STATISTICA software. The parametric study on corrosion inhibition process using response surface methodology (RSM is presented in this paper. The study shows that the immersion time and temperature of corroding medium had shown negative dependence of great significance in increase the corrosion rate while the other studied variable (i.e. inhibitor concentration had shown large positive dependence in reduce the corrosion rate of low carbon steel alloy. Optimum conditions for achieving the minimum corrosion rate are obtained from optimizing the above correlation and are found as follow: 42.86 °C temperature of corroding medium, 29.29 cm3/L inhibitor concentration and 2.65 h immersion time. In these circumstances, the value of inhibition efficiency obtained was 96.09 %. It could be concluded that Box-Wilson experimental design was adequately applicable in the optimization of process variables and that kiwi juice sufficiently inhibited the corrosion for low carbon steel at the

  14. Application of calculated NMR parameters, aromaticity indices and wavefunction properties for evaluation of corrosion inhibition efficiency of pyrazine inhibitors

    Science.gov (United States)

    Behzadi, Hadi; Manzetti, Sergio; Dargahi, Maryam; Roonasi, Payman; Khalilnia, Zahra

    2018-01-01

    In light of the importance of developing novel corrosion inhibitors, a series of quantum chemical calculations were carried out to evaluate 15N chemical shielding CS tensors as well as aromaticity indexes including NICS, HOMA, FLU, and PDI of three pyrazine derivatives, 2-methylpyrazine (MP), 2-aminopyrazine (AP) and 2-amino-5-bromopyrazine (ABP). The NICS parameters have been shown in previous studies to be paramount to the prediction of anti-corrosion properties, and have been combined here with HOMA, FLU and PDI and detailed wavefunction analysis to determine the effects from bromination and methylation on pyrazine. The results show that the electron density around the nitrogens, represented by CS tensors, can be good indicators of anti-corrosion efficiency. Additionally, the NICS, FLU and PDI, as aromaticity indicators of molecule, are well correlated with experimental corrosion inhibition efficiencies of the studied inhibitors. Bader sampling and detailed wavefunction analysis shows that the major effects from bromination on the pyrazine derivatives affect the Laplacian of the electron density of the ring, delocalizing the aromatic electrons of the carbon atoms into lone pairs and increasing polarization of the Laplacian values. This feature is well agreement with empirical studies, which show that ABP is the most efficient anti-corrosion compound followed by AP and MP, a property which can be attributed and predicted by derivation of the Laplacian of the electron density of the ring nuclei. This study shows the importance of devising DFT methods for development of new corrosion inhibitors, and the strength of electronic and nuclear analysis, and depicts most importantly how corrosion inhibitors composed of aromatic moieties may be modified to increase anti-corrosive properties.

  15. The Evaluation of Crevice Corrosion of Inconel-600 and 304 Stainless Steel in Reductive Decontamination Solutions

    International Nuclear Information System (INIS)

    Jung, Junyoung; Park, Sangyoon; Won, Huijun; Choi, Wangkyu; Moon, Jeikwon; Park, Sojin

    2014-01-01

    In this sturdy, we investigated the characteristics of corrosion to Inconel-600 and type 304 stainless steel which are mainly used for the steam generator and primary system of PWR reactor respectively. We conducted the corrosion test for the HYBRID (HYdrazine Based metal Ion Reductive decontamination) which was developed in KAERI, Citrox and Oxalic acid solutions used in reductive decontamination of the inner surface of PWR. Since Citrox and oxalic acid solution were well-known conventional decontamination solutions, it is meaningful to compare the corrosion result of HYBRID with those solutions to confirm the corrosion compatibility. In order to obtain visible results in a limited time, we conducted the crevice corrosion tests under harsh condition. According to the results of crevice corrosion tests, we can conclude that metals such as type 304 stainless steel and Inconel-600 in HYBRID are very stable against crevice corrosion. On the other hand, those metals in Citrox and oxalic acid solutions were very susceptible to the crevice corrosion. Especially when using the oxalic acid solution, severe corrosion was observed not only Inconel-600 but also 304 stainless steel. The degree of corrosion can be expressed as; HYBRID << Citrox < OA. Conclusively, our results support that the HYBRID is more stable to the corrosion of structural materials in primary system than other Citrox and oxalic acid solutions. This finding will appoint the HYBRID solution as a candidate to solve the corrosion problem which is often issued by existing chemical decontamination processes

  16. Timescale Correlation between Marine Atmospheric Exposure and Accelerated Corrosion Testing

    Science.gov (United States)

    Montgomery, Eliza L.; Calle, Luz Marina; Curran, Jerone C.; Kolody, Mark R.

    2011-01-01

    Evaluation of metal-based structures has long relied on atmospheric exposure test sites to determine corrosion resistance in marine environments. Traditional accelerated corrosion testing relies on mimicking the exposure conditions, often incorporating salt spray and ultraviolet (UV) radiation, and exposing the metal to continuous or cyclic conditions of the corrosive environment. Their success for correlation to atmospheric exposure is often a concern when determining the timescale to which the accelerated tests can be related. Accelerated laboratory testing, which often focuses on the electrochemical reactions that occur during corrosion conditions, has yet to be universally accepted as a useful tool in predicting the long term service life of a metal despite its ability to rapidly induce corrosion. Although visual and mass loss methods of evaluating corrosion are the standard and their use is imperative, a method that correlates timescales from atmospheric exposure to accelerated testing would be very valuable. This work uses surface chemistry to interpret the chemical changes occurring on low carbon steel during atmospheric and accelerated corrosion conditions with the objective of finding a correlation between its accelerated and long-term corrosion performance. The current results of correlating data from marine atmospheric exposure conditions at the Kennedy Space Center beachside corrosion test site, alternating seawater spray, and immersion in typical electrochemical laboratory conditions, will be presented. Key words: atmospheric exposure, accelerated corrosion testing, alternating seawater spray, marine, correlation, seawater, carbon steel, long-term corrosion performance prediction, X-ray photoelectron spectroscopy.

  17. Natural analogues of nuclear waste glass corrosion

    International Nuclear Information System (INIS)

    Abrajano, T.A. Jr.; Ebert, W.L.; Luo, J.S.

    1999-01-01

    This report reviews and summarizes studies performed to characterize the products and processes involved in the corrosion of natural glasses. Studies are also reviewed and evaluated on how well the corrosion of natural glasses in natural environments serves as an analogue for the corrosion of high-level radioactive waste glasses in an engineered geologic disposal system. A wide range of natural and experimental corrosion studies has been performed on three major groups of natural glasses: tektite, obsidian, and basalt. Studies of the corrosion of natural glass attempt to characterize both the nature of alteration products and the reaction kinetics. Information available on natural glass was then compared to corresponding information on the corrosion of nuclear waste glasses, specifically to resolve two key questions: (1) whether one or more natural glasses behave similarly to nuclear waste glasses in laboratory tests, and (2) how these similarities can be used to support projections of the long-term corrosion of nuclear waste glasses. The corrosion behavior of basaltic glasses was most similar to that of nuclear waste glasses, but the corrosion of tektite and obsidian glasses involves certain processes that also occur during the corrosion of nuclear waste glasses. The reactions and processes that control basalt glass dissolution are similar to those that are important in nuclear waste glass dissolution. The key reaction of the overall corrosion mechanism is network hydrolysis, which eventually breaks down the glass network structure that remains after the initial ion-exchange and diffusion processes. This review also highlights some unresolved issues related to the application of an analogue approach to predicting long-term behavior of nuclear waste glass corrosion, such as discrepancies between experimental and field-based estimates of kinetic parameters for basaltic glasses

  18. Natural analogues of nuclear waste glass corrosion.

    Energy Technology Data Exchange (ETDEWEB)

    Abrajano, T.A. Jr.; Ebert, W.L.; Luo, J.S.

    1999-01-06

    This report reviews and summarizes studies performed to characterize the products and processes involved in the corrosion of natural glasses. Studies are also reviewed and evaluated on how well the corrosion of natural glasses in natural environments serves as an analogue for the corrosion of high-level radioactive waste glasses in an engineered geologic disposal system. A wide range of natural and experimental corrosion studies has been performed on three major groups of natural glasses: tektite, obsidian, and basalt. Studies of the corrosion of natural glass attempt to characterize both the nature of alteration products and the reaction kinetics. Information available on natural glass was then compared to corresponding information on the corrosion of nuclear waste glasses, specifically to resolve two key questions: (1) whether one or more natural glasses behave similarly to nuclear waste glasses in laboratory tests, and (2) how these similarities can be used to support projections of the long-term corrosion of nuclear waste glasses. The corrosion behavior of basaltic glasses was most similar to that of nuclear waste glasses, but the corrosion of tektite and obsidian glasses involves certain processes that also occur during the corrosion of nuclear waste glasses. The reactions and processes that control basalt glass dissolution are similar to those that are important in nuclear waste glass dissolution. The key reaction of the overall corrosion mechanism is network hydrolysis, which eventually breaks down the glass network structure that remains after the initial ion-exchange and diffusion processes. This review also highlights some unresolved issues related to the application of an analogue approach to predicting long-term behavior of nuclear waste glass corrosion, such as discrepancies between experimental and field-based estimates of kinetic parameters for basaltic glasses.

  19. Erosion-corrosion

    International Nuclear Information System (INIS)

    Aghili, B.

    1999-05-01

    A literature study on erosion-corrosion of pipings in the nuclear industry was performed. Occurred incidents are reviewed, and the mechanism driving the erosion-corrosion is described. Factors that influence the effect in negative or positive direction are treated, as well as programs for control and inspection. Finally, examples of failures from databases on erosion-corrosion are given in an attachment

  20. Significance of steel electrical resistance method in the evaluation of reinforcement corrosion in cementitious systems

    Directory of Open Access Journals (Sweden)

    Krajci, L.

    2004-06-01

    Full Text Available The suitable detection system of steel reinforcement corrosion in concrete structures contributes to the reduction of their maintenance costs. Method of steel electrical resistance represents non-destructive monitoring of steel in cementitious systems. Specially prepared and arranged test specimen of steel as a corrosion sensor is embedded in mortar specimen. Verification tests of this method based on chloride corrosion of steel in mortars as well as its visual inspection are introduced. Significance of steel electrical resistance method lies in the expression of steel corrosion by these quantitative parameters: reduction of cross-section of steel, thickness of corroded layer and loss of weight of steel material. This method is an integral method that allows the indirect determination of mentioned corrosion characteristics. The comparison of verified method with gravimetric evaluation of steel corrosion gives a good correspondence. Test results on mortars with calcium chloride dosages between 0.5% and 4.0% by weight of cement prove high sensitiveness and reliability of steel electrical resistance method.

    La utilización de un sistema de detección de la corrosión de las armaduras en estructuras de hormigón puede contribuir a la reducción de sus costes de mantenimiento. El método de la resistencia eléctrica del acero consiste en la monitorización no-destructiva realizada sobre el acero en sistemas cementantes. Dentro de la muestra de mortero se coloca el sistema de detección, especialmente preparado y fijado, actuando como un sensor de la corrosión. En este trabajo se presentan ensayos de verificación de este método, junto con inspecciones visuales, en morteros sometidos a corrosión de armaduras por efecto de los cloruros. La efectividad de este método de la resistencia eléctrica del acero se expresa, en la corrosión de armaduras, de acuerdo a los siguientes parámetros cuantitativos: reducción de la sección transversal del

  1. Dictionary corrosion and corrosion control

    International Nuclear Information System (INIS)

    1985-01-01

    This dictionary has 13000 entries in both languages. Keywords and extensive accompanying information simplify the choice of word for the user. The following topics are covered: Theoretical principles of corrosion; Corrosion of the metals and alloys most frequently used in engineering. Types of corrosion - (chemical-, electro-chemical, biological corrosion); forms of corrosion (superficial, pitting, selective, intercrystalline and stress corrosion; vibrational corrosion cracking); erosion and cavitation. Methods of corrosion control (material selection, temporary corrosion protection media, paint and plastics coatings, electro-chemical coatings, corrosion prevention by treatment of the corrosive media); Corrosion testing methods. (orig./HP) [de

  2. Evaluation of corrosion of prestressing steel in concrete using non-destructive techniques

    International Nuclear Information System (INIS)

    Ali, M.G.; Maddocks, A.R.

    2003-01-01

    Use of high strength steel in pre-stressed concrete structures has been in use in Australia for many decades. Highway bridges, among other structures, have extensively used pre-stress-ing and post-tensioning techniques. Although prestressing offers many competitive edges to it's traditional rival reinforced concrete, the consequence of damage to prestressing tendons could be catastrophic. Periodic visual inspections of prestressed concrete bridges throughout the world have demonstrated the growing problem of deterioration of prestressing steel as a result of corrosion. Early detection of damage to prestressing steel therefore is of paramount importance. Unfortunately no reliable and practical non-destructive evaluation technique has been available for assessing the condition of prestressing steel within concrete although a number of techniques appear promising. The following inspection methods have been highlighted in recent literature for their use as non-destructive inspection methods for prestressed concrete structures. In addition to the techniques discussed, a number of destructive, or invasive techniques also exist for determination of the corrosion status of prestressing tendons in prestressed structures. The following non-destructive techniques are discussed in some detail: Radiography; Computed Tomography; Surface Penetrating Radar; Impact Echo; Acoustic Emission Monitoring; Magnetic Field Disturbance Technique; Remnant Magnetism Method; Linear Polarisation Method; Electrical Resistance and Surface Potential Survey. The portability, limitations and use in Australia of these techniques are summarised in a table

  3. Evaluation of protective effect of deposits formed by naphthenic corrosion and sulfidation on carbon steel and steel 5Cr-0.5Mo exposed in atmospheric distillation fractions

    Directory of Open Access Journals (Sweden)

    Gloria Duarte

    2017-05-01

    Full Text Available Refining of so-called opportunity crude oils with a high level of naphthenic acids and sulfur compounds has been increasing interest due to limited availability of light crude oils, however, considerable corrosive effects in the processing to high temperature on pipes and distillation towers mainly by the attack of naphthenic acids and sulfur compounds; sulfur compounds could be corrosive or can reduce the attack of naphthenic acids due to the formation of sulfides layers on the metal surface. In this work was evaluated the performance of deposits formed on the surface of carbon steel AISI SAE 1020 and 5% Cr-0.5% Mo steel exposed in crude oil fractions obtained from atmospheric distillation tower. For this, gravimetric tests were performed in dynamic autoclave using metal samples pre-treated in a crude oil fraction obtained from the atmospheric distillation tower of the Crude Distillation Unit (CDU # 1 in order to form layers of sulfides on the surface of the two materials and subsequently to expose pre-treated and non-pretreated samples in two different crude oil fractions obtained from atmospheric distillation tower of Crude Distillation Unit (CDU # 2. The evaluation showed that the samples pretreated decreased tendency to corrosion by naphthenic acids and sulfidation compared to untreated samples.

  4. Evaluation of the corrosion resistance of anodized aluminum 6061 using electrochemical impedance spectroscopy (EIS)

    Energy Technology Data Exchange (ETDEWEB)

    Huang Yuelong [Corrosion and Environmental Effects Laboratory (CEEL), Mork Family Department of Chemical Engineering and Materials Science, University of Southern California, Los Angeles, CA 90089-0241 (United States); Shih Hong [Lam Research Corporation, 4400 Cushing Parkway, Fremont, CA 94538 (United States)], E-mail: hong.shih@lamrc.com; Huang, Huochuan; Daugherty, John; Wu Shun; Ramanathan, Sivakami; Chang, Chris [Lam Research Corporation, 4400 Cushing Parkway, Fremont, CA 94538 (United States); Mansfeld, Florian [Corrosion and Environmental Effects Laboratory (CEEL), Mork Family Department of Chemical Engineering and Materials Science, University of Southern California, Los Angeles, CA 90089-0241 (United States)], E-mail: mansfeld@usc.edu

    2008-12-15

    The corrosion resistance of anodized Al 6061 produced by two different anodizing and sealing processes was evaluated using electrochemical impedance spectroscopy (EIS). The scanning electron microscope (SEM) was employed to determine the surface structure and the thickness of the anodized layers. The EIS data revealed that there was very little change of the properties of the anodized layers for samples that were hard anodized in a mixed acid solution and sealed in hot water over a 365 day exposure period in a 3.5 wt% NaCl solution. The specific admittance A{sub s} and the breakpoint frequency f{sub b} remained constant with exposure time confirming that the hard anodizing process used in this study was very effective in providing excellent corrosion resistance of anodized Al 6061 over extended exposure periods. Some minor degradation of the protective properties of the anodized layers was observed for samples that were hard anodized in H{sub 2}SO{sub 4} and exposed to the NaCl solution for 14 days.

  5. Evaluation of the corrosion resistance of anodized aluminum 6061 using electrochemical impedance spectroscopy (EIS)

    International Nuclear Information System (INIS)

    Huang Yuelong; Shih Hong; Huang, Huochuan; Daugherty, John; Wu Shun; Ramanathan, Sivakami; Chang, Chris; Mansfeld, Florian

    2008-01-01

    The corrosion resistance of anodized Al 6061 produced by two different anodizing and sealing processes was evaluated using electrochemical impedance spectroscopy (EIS). The scanning electron microscope (SEM) was employed to determine the surface structure and the thickness of the anodized layers. The EIS data revealed that there was very little change of the properties of the anodized layers for samples that were hard anodized in a mixed acid solution and sealed in hot water over a 365 day exposure period in a 3.5 wt% NaCl solution. The specific admittance A s and the breakpoint frequency f b remained constant with exposure time confirming that the hard anodizing process used in this study was very effective in providing excellent corrosion resistance of anodized Al 6061 over extended exposure periods. Some minor degradation of the protective properties of the anodized layers was observed for samples that were hard anodized in H 2 SO 4 and exposed to the NaCl solution for 14 days

  6. Corrosion resistance of a copper canister for spent nuclear fuel

    International Nuclear Information System (INIS)

    1983-04-01

    The report presents an evaluation of copper as canister material for spent nuclear fuel. The evaluation is made from the viewpoint of corrosion and applies to a concept of 1977. Supplementary corrosion studies have been performed. The report includes 9 appendices which deal with experimental data. (G.B.)

  7. Steam based conversion coating on AA6060 alloy: Effect of sodium silicate chemistry and corrosion performance

    Science.gov (United States)

    Din, Rameez Ud; Bordo, Kirill; Tabrizian, Naja; Jellesen, Morten Stendahl; Ambat, Rajan

    2017-11-01

    Surface treatment of aluminium alloy AA6060 using an industrially applicable pilot steam jet system with and without silicate chemistry has been investigated. Treatment using steam alone and steam with silicate, resulted in an oxide layer formation with thickness ∼425 nm and ∼160 nm, respectively. Moreover, the use of sodium silicate resulted in the formation of distinct microstructure and incorporation of silicate into the oxide film. These oxide films reduced the anodic activity 4 times, while the corrosion protection by silicate containing oxide was the function of its concentration. Further, in acid salt spray and filiform corrosion tests, oxide layer containing silicate exhibited two times higher corrosion resistance.

  8. Corrosion Protection Performance of Polyester-Melamine Coating with Natural Wood Fiber Using EIS Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Shin, PyongHwa; Shon, MinYoung [Pukyong National University, Busan (Korea, Republic of); Jo, DuHwan [POSCO, Gwangyang (Korea, Republic of)

    2016-04-15

    In the present study, polyester-melamine coating systems with natural wood fiber (NWF) were prepared and the effects of NWF on the corrosion protectiveness of the polyester-melamine coating were examined using EIS analysis. From the results, higher average surface roughness was observed with increase of NWF content. Water diffusivity and water uptake into the polyester-melamine coatings with NWF were much higher than that into the pure polyester-melamine coating. The decrease in the impedance modulus |Z| was associated with the localized corrosion on carbon steel, confirming that corrosion protection of the polyester-melamine coatings with NWF well agrees with its water transport behavior.

  9. Performance Evaluation of Security Protocols

    DEFF Research Database (Denmark)

    Bodei, Chiara; Buchholtz, Mikael; Curti, Michele

    2005-01-01

    We use a special operational semantics which drives us in inferring quantitative measures on systems describing cryptographis cryptographic protocols. We assign rates to transitions by only looking at these labels. The rates reflect the distributed architecture running applications and the use...... of possibly different cryptosystems. We then map transition systems to Markov chains and evaluate performance of systems, using standard tools....

  10. Non-destructive electrochemical techniques applied to the corrosion evaluation of the liner structures in nuclear power plants

    International Nuclear Information System (INIS)

    Martinez, I.; Castillo, A.; Andrade, C.

    2008-01-01

    The liner structure in nuclear power plants provides containment for the operation and therefore the study of its durability and integrity during its service life is an important issue. There are several causes for the deterioration of the liner, which in general involve corrosion due to its metallic nature. The present paper is aimed at describing the assessment of corrosion problems of two liners from two different nuclear power plants, which were evaluated using non-destructive electrochemical techniques. In spite of the testing difficulties arisen, from the results extracted it can be concluded that the electrochemical techniques applied are adequate for the corrosion evaluation. They provide important information about the integrity of the structure and allow for its evolution with time to be assessed

  11. Evaluation of EIT system performance.

    Science.gov (United States)

    Yasin, Mamatjan; Böhm, Stephan; Gaggero, Pascal O; Adler, Andy

    2011-07-01

    An electrical impedance tomography (EIT) system images internal conductivity from surface electrical stimulation and measurement. Such systems necessarily comprise multiple design choices from cables and hardware design to calibration and image reconstruction. In order to compare EIT systems and study the consequences of changes in system performance, this paper describes a systematic approach to evaluate the performance of the EIT systems. The system to be tested is connected to a saline phantom in which calibrated contrasting test objects are systematically positioned using a position controller. A set of evaluation parameters are proposed which characterize (i) data and image noise, (ii) data accuracy, (iii) detectability of single contrasts and distinguishability of multiple contrasts, and (iv) accuracy of reconstructed image (amplitude, resolution, position and ringing). Using this approach, we evaluate three different EIT systems and illustrate the use of these tools to evaluate and compare performance. In order to facilitate the use of this approach, all details of the phantom, test objects and position controller design are made publicly available including the source code of the evaluation and reporting software.

  12. Influence of anti-corrosion additive on the performance, emission and engine component wear characteristics of an IDI diesel engine fueled with palm biodiesel

    International Nuclear Information System (INIS)

    Ashraful, A.M.; Masjuki, H.H.; Kalam, M.A.; Rashedul, H.K.; Sajjad, H.; Abedin, M.J.

    2014-01-01

    Highlights: • Maximum engine performance was obtained at 2000 rpm for all fuel blends. • IRGALUBE 349 additive is enhances diesel engine performance. • Reduction of CO and NOx considerably using anti-corrosion additive except HC. • Engine wear decreases with using blended fuels with anti-corrosion additive. - Abstract: This study evaluates the effect of anti-corrosion additives such as 8% and 16% (vol.%) palm olein oil (PO) with ordinary diesel (OD) fuel on engine operation, emission behavior, engine part wear, and lubrication characteristics. This experiment was conducted on 4-cylinder and 4-stroke IDI diesel engine at different engine speed ranging from 1200 to 2800 RPM with 30% throttle setting under full load condition. The properties of the palm olein oil blends meet the ASTM D6751 and EN 14214 standards. At 2000 rpm, the experimental results revealed that the POD8A (0.2% Additive + 8% PO + 92% OD) and POD16A (0.2% Additive + 16% PO + 84% OD) blended fuels produced 0.5% and 0.51% higher brake power as well as 1.45% and 1.25% higher torque than same blends without additive, respectively. In comparison with ODF, the brake specific fuel consumption (BSFC) was found 1.8% and 3.1% higher for POD8A and POD16A blends, respectively. Anti-corrosion additive is found more effectual in enhancing the engine performance as such additive helps in timely ignition for complete burn in the combustion chamber. The results from engine emission indicated that POD8A and POD16A blended fuel reduced CO emissions by 11% and 6.6% and NOx emission by 2.5% and 1.09%, respectively in compared with OD fuel. Although HC emissions for all blended fuel and OD fuel increased at higher engine speed, the average HC emissions of all blended fuel were not higher than OD fuel. The application of anti-corrosion additives in POD blends reduced ferrous (Fe) wear debris concentration (WBC) by 17.3%. The reductions in WBC were about 16.1%, 10.8%, and 19.3%, 17.6% for copper (Cu) and aluminum

  13. The inhibition performance of long-chain alkyl-substituted benzimidazole derivatives for corrosion of mild steel in HCl

    International Nuclear Information System (INIS)

    Zhang, Dongqin; Tang, Yongming; Qi, Sijun; Dong, Dawei; Cang, Hui; Lu, Gang

    2016-01-01

    Highlights: • Inhibition performance of long-chain alkyl-substituted benzimidazole. • Benzimidazole segment donating electrons to metal surface. • Non-polar long chain enhancing inhibition by the barrier effect. • Molecular form of DBI more tightly adsorbs on the steel than its protonated form. - Abstract: The corrosion inhibition of a new benzimidazole derivative, 6-(dodecyloxy)-1H-benzo[d]imidazole (DBI), for mild steel in 1 M HCl was investigated in this paper. Computational chemistry was performed to explore the adsorption of DBI on metal surface. Inhibition performance of DBI is attributed to both the direct interaction of benzimidazole segment with iron surface and the barrier effect of the non-polar long chain against aggressive solution. Compared to the protonated form, the molecular form of DBI could more tightly interact with iron surface. These results show that the long-chain alkyl-substituted benzimidazole derivative is of great potential application as corrosion inhibitor.

  14. Performance demonstration testing at the EPRI NDE center for intergranular stress corrosion cracking in BWR piping

    International Nuclear Information System (INIS)

    Pherigo, G.

    1986-01-01

    Intergranular stress corrosion cracking (IGSCC) has become a significant concern for the commercial electric utility industry during the past four years. As the IGSCC problem manifested itself, the Nuclear Regulatory Commission (NRC) responded by issuing Inspection and Enforcement (I and E) Bulletin 82-03 which required that ultrasonic inspection procedures be demonstrated on service- removed samples. The ability to reliably detect and discriminate IGSCC was recognized by the industry as a very difficult task, at best. Concurrent with the NRC bulletin, state-of-the-art yet practical techniques for the detection and discrimination of IGSCC had to be developed, demonstrated, and transferred to the field in a relatively short time. With the release of I and E Bulletin 83-02, procedures as well as personnel had to be qualified on service-removed samples. This paper reports how the EPRI Nondestructive Evaluation (NDE) Center developed the necessary technology and a formal training and qualification program to meet these needs on behalf of the industry

  15. The applicability of alkaline-resistant glass fiber in cement mortar of road pavement: Corrosion mechanism and performance analysis

    Directory of Open Access Journals (Sweden)

    Qin Xiaochun

    2017-11-01

    Full Text Available The main technical requirements of road pavement concrete are high flexural strength and fatigue durability. Adding glass fiber into concrete could greatly increase flexural strength and wearing resistance of concrete. However, glass fiber has the great potential of corrosion during the cement hydration, which will directly affect the long-term performance and strength stability. In this paper, accelerated corrosion experiments have been done to find out the corrosion mechanism and property of alkali-resistant glass fiber in cement mortar. The applicability and practicability of alkaline-resistant glass fiber in road concrete have been illustrated in the analysis of flexural strength changing trend of cement mortar mixed with different proportions of activated additives to protect the corrosion of glass fiber by cement mortar. The results have shown that a 30% addition of fly ash or 10% addition of silica fume to cement matrix could effectively improve the corrosion resistance of alkali-resistant glass fiber. The optimal mixing amount of alkali-resistant glass fiber should be about 1.0 kg/m3 in consideration of ensuring the compressive strength of reinforced concrete in road pavement. The closest-packing method has been adopted in the mixture ratio design of alkali-resistant glass fiber reinforced concrete, not only to reduce the alkalinity of the cement matrix through large amount addition of activated additives but also to greatly enhance the flexural performance of concrete with the split pressure ratio improvement of 12.5–16.7%. The results suggested a prosperous application prospect for alkaline-resistant glass fiber reinforced concrete in road pavement.

  16. Implementation of Localized Corrosion in the Performance Assessment Model for Yucca Mountain

    International Nuclear Information System (INIS)

    Jain, V.; SEVOUGIAN, D.S.; MATTIE, P.D.; MACKINNON, R.J.

    2005-01-01

    A total system performance assessment (TSPA) model has been developed to analyze the ability of the natural and engineered barriers of the Yucca Mountain repository to isolate nuclear waste for the 10,000-year period following repository closure. The principal features of the engineered barrier system (EBS) are emplacement tunnels (or ''drifts'') containing a two-layer waste package (WP) for waste containment and a titanium drip shield to protect the waste package from seeping water and falling rock. The 20-mm-thick outer shell of the WP is composed of Alloy 22, a highly corrosion-resistant nickel-based alloy, while the 50-mm inner shell is composed of 316 stainless steel (modified with lower carbon and nitrogen compositions), whose primary purpose is to provide structural strength. The barrier function of the EBS is to isolate the waste from the migrating water with its associated chemical conditions that eventually lead to degradation of the waste packages and mobilization of the radionuclides within the packages

  17. A theoretical evaluation of the oxygen concentration in a corrosion-fatigue crack

    International Nuclear Information System (INIS)

    Turnbull, A.

    1981-01-01

    The oxygen concentration in a corrosion-fatigue crack has been evaluated theoretically by assuming that oxygen was consumed by cathodic reduction on the walls of the crack and mass transport occurred by diffusion and advection (forced convection), with the latter resulting from the sinusoidal variation of the displacement of the crack walls. By using parameters relevant to a compact tension specimen, the time-dependent distribution of the oxygen concentration in the crack was calculated as a function of ΔK (the range of the stress intensity factor), R-value (minimum load/maximum load), frequency, crack length, and electrode potential. The influence of advection was to significantly enhance the mass transport of oxygen in the crack compared with ''diffusion-only'' even at low frequencies and low ΔK. Regions in the crack were identified in which advection dominance or diffusion dominance of the mass transport of oxygen occurred

  18. Finite element modeling of stress corrosion cracking for electromagnetic nondestructive evaluations

    International Nuclear Information System (INIS)

    Wang, J.; Yusa, N.; Hashizume, H.

    2012-01-01

    This paper discusses appropriate numerical model for a stress corrosion crack (SCC) from the viewpoint of anisotropy of their conductivity. Two SCCs, which are introduced into a plate of type 316 stainless steel, are considered. Finite element simulations are carried out to evaluate the conductivity. In the simulations, the cracks are modeled as a region with a constant width on the basis of the destructive tests. The results show the conductivity on direction of width has large effect to the accuracy of numerical modeling of SCC, whereas the conductivities on direction of length and depth almost do not have remarkable effects. The results obtained by this study indicate that distribution of conductivity along the surface of a crack would be more important than the anisotropy in modeling SCCs in finite element simulations

  19. Terahertz NDE application for corrosion detection and evaluation under Shuttle tiles

    Science.gov (United States)

    Anastasi, Robert F.; Madaras, Eric I.; Seebo, Jeffrey P.; Smith, Stephen W.; Lomness, Janice K.; Hintze, Paul E.; Kammerer, Catherine C.; Winfree, William P.; Russell, Richard W.

    2007-04-01

    Pulsed Terahertz NDE is being examined as a method to inspect for possible corrosion under Space Shuttle Tiles. Other methods such as ultrasonics, infrared, eddy current and microwave technologies have demonstrable shortcomings for tile NDE. This work applies Terahertz NDE, in the frequency range between 50 GHz and 1 THz, for the inspection of manufactured corrosion samples. The samples consist of induced corrosion spots that range in diameter (2.54 to 15.2 mm) and depth (0.036 to 0.787 mm) in an aluminum substrate material covered with tiles. Results of these measurements are presented for known corrosion flaws both covered and uncovered and for blind tests with unknown corrosion flaws covered with attached tiles. The Terahertz NDE system is shown to detect all artificially manufactured corrosion regions under a Shuttle tile with a depth greater than 0.13 mm.

  20. Computed radiography systems performance evaluation

    International Nuclear Information System (INIS)

    Xavier, Clarice C.; Nersissian, Denise Y.; Furquim, Tania A.C.

    2009-01-01

    The performance of a computed radiography system was evaluated, according to the AAPM Report No. 93. Evaluation tests proposed by the publication were performed, and the following nonconformities were found: imaging p/ate (lP) dark noise, which compromises the clinical image acquired using the IP; exposure indicator uncalibrated, which can cause underexposure to the IP; nonlinearity of the system response, which causes overexposure; resolution limit under the declared by the manufacturer and erasure thoroughness uncalibrated, impairing structures visualization; Moire pattern visualized at the grid response, and IP Throughput over the specified by the manufacturer. These non-conformities indicate that digital imaging systems' lack of calibration can cause an increase in dose in order that image prob/ems can be so/ved. (author)

  1. Long Term Corrosion/Degradation Test Six Year Results

    Energy Technology Data Exchange (ETDEWEB)

    M. K. Adler Flitton; C. W. Bishop; M. E. Delwiche; T. S. Yoder

    2004-09-01

    The Subsurface Disposal Area (SDA) of the Radioactive Waste Management Complex (RWMC) located at the Idaho National Engineering and Environmental Laboratory (INEEL) contains neutron-activated metals from non-fuel, nuclear reactor core components. The Long-Term Corrosion/Degradation (LTCD) Test is designed to obtain site-specific corrosion rates to support efforts to more accurately estimate the transfer of activated elements to the environment. The test is using two proven, industry-standard methods—direct corrosion testing using metal coupons, and monitored corrosion testing using electrical/resistance probes—to determine corrosion rates for various metal alloys generally representing the metals of interest buried at the SDA, including Type 304L stainless steel, Type 316L stainless steel, Inconel 718, Beryllium S200F, Aluminum 6061, Zircaloy-4, low-carbon steel, and Ferralium 255. In the direct testing, metal coupons are retrieved for corrosion evaluation after having been buried in SDA backfill soil and exposed to natural SDA environmental conditions for times ranging from one year to as many as 32 years, depending on research needs and funding availability. In the monitored testing, electrical/resistance probes buried in SDA backfill soil will provide corrosion data for the duration of the test or until the probes fail. This report provides an update describing the current status of the test and documents results to date. Data from the one-year and three-year results are also included, for comparison and evaluation of trends. In the six-year results, most metals being tested showed extremely low measurable rates of general corrosion. For Type 304L stainless steel, Type 316L stainless steel, Inconel 718, and Ferralium 255, corrosion rates fell in the range of “no reportable” to 0.0002 mils per year (MPY). Corrosion rates for Zircaloy-4 ranged from no measurable corrosion to 0.0001 MPY. These rates are two orders of magnitude lower than those specified in

  2. Evaluation of corrosion behaviour of tantalum coating obtained by low pressure chemical vapor deposition using electrochemical polarization

    Science.gov (United States)

    Levesque, A.; Bouteville, A.; de Baynast, H.; Laveissière, B.

    2002-06-01

    antalum coatings are elaborated on titanium substrates through Low Pressure Chemical Vapor Deposition from tantalum pentachloride-hydrogen gaseous phase at a deposition temperature of 800 °C and a total pressure of 3.3 mbar. The aim of this paper is to evaluate the effectiveness of this tantalum coating in corrosive solution. Optical Microscopy and Scanning Electron Microscopy observations reveal that deposits are of 1.7 μm in thickness and conformal. The corrosion resistance of tantalum coated titanium substrates is quantified through standard potentiodynamic polarization method. Even for tantalum coatings exhibiting some defects as pores, the corrosion current density is as low as 0.25 mA/cm^2.in very agressive solutions like kroll reagent (HN03/HF).

  3. Fabrication of imitative stress corrosion cracking using diffusion bonding for the development of nondestructive testing and evaluations

    International Nuclear Information System (INIS)

    Yusa, Noritaka; Hashizume, Hidetoshi

    2011-01-01

    This study reports a method to fabricate imitative stress corrosion cracking suitable for the development of nondestructive testing and evaluation methods. The method is to embed a partially-bonded region, which simulates the characteristics of stress corrosion cracking, inside a material by bonding together surfaces having artificial grooves. Since the sizes of the grooves are smaller than the spatial resolution of nondestructive testing method applied, the material property realized can be regarded as uniform as the actual stress corrosion cracking. The grooves are introduced using mechanical machining, which enables one to control the characteristics of the simulated flaw. Four specimens made of type 316L austenitic stainless steel are fabricated. The method is demonstrated by visual and eddy current examinations. (author)

  4. In-pile Hydrothermal Corrosion Evaluation of Coated SiC Ceramics and Composites

    Energy Technology Data Exchange (ETDEWEB)

    Carpenter, David [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Ang, Caen [Univ. of Tennessee, Knoxville, TN (United States); Katoh, Yutai [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Linton, Kory D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Terrani, Kurt A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2017-09-01

    Hydrothermal corrosion accelerated by water radiolysis during normal operation is among the most critical technical feasibility issues remaining for silicon carbide (SiC) composite-based cladding that could provide enhanced accident-tolerance fuel technology for light water reactors. An integrated in-pile test was developed and performed to determine the synergistic effects of neutron irradiation, radiolysis, and pressurized water flow, all of which are relevant to a typical pressurized water reactor (PWR). The test specimens were chosen to cover a range of SiC materials and a variety of potential options for environmental barrier coatings. This document provides a summary of the irradiation vehicle design, operations of the experiment, and the specimen loading into the irradiation vehicle.

  5. Corrosion Inhibition of High Speed Steel by Biopolymer HPMC Derivatives

    Directory of Open Access Journals (Sweden)

    Shih-Chen Shi

    2016-07-01

    Full Text Available The corrosion inhibition characteristics of the derivatives of biopolymer hydroxypropyl methylcellulose (HPMC, hydroxypropyl methylcellulose phthalate (HPMCP, and hydroxypropyl methylcellulose acetate succinate (HPMCAS film are investigated. Based on electrochemical impedance spectroscopic measurements and potentiodynamic polarization, the corrosion inhibition performance of high speed steel coated with HPMC derivatives is evaluated. The Nyquist plot and Tafel polarization demonstrate promising anti-corrosion performance of HPMC and HPMCP. With increasing film thickness, both materials reveal improvement in corrosion inhibition. Moreover, because of a hydrophobic surface and lower moisture content, HPMCP shows better anti-corrosion performance than HPMCAS. The study is of certain importance for designing green corrosion inhibitors of high speed steel surfaces by the use of biopolymer derivatives.

  6. Coatings and Corrosion Laboratory

    Data.gov (United States)

    Federal Laboratory Consortium — Purpose: The mission of the Coatings and Corrosion Laboratory is to develop and analyze the effectiveness of innovative coatings test procedures while evaluating the...

  7. The Use of AC-DC-AC Methods in Assessing Corrosion Resistance Performance of Coating Systems for Magnesium Alloys

    Science.gov (United States)

    McCune, Robert C.; Upadhyay, Vinod; Wang, Yar-Ming; Battocchi, Dante

    The potential utility of AC-DC-AC electrochemical methods in comparative measures of corrosion-resisting coating system performance for magnesium alloys under consideration for the USAMP "Magnesium Front End Research and Development" project was previously shown in this forum [1]. Additional studies of this approach using statistically-designed experiments have been conducted with focus on alloy types, pretreatment, topcoat material and topcoat thickness as the variables. Additionally, sample coupons made for these designed experiments were also subjected to a typical automotive cyclic corrosion test cycle (SAE J2334) as well as ASTM B117 for comparison of relative performance. Results of these studies are presented along with advantages and limitations of the proposed methodology.

  8. Microencapsulation Technologies for Corrosion Protective Coating Applications

    Science.gov (United States)

    Li, Wenyan; Buhrow, Jerry; Jolley, Scott; Calle, Luz; Pearman, Benjamin; Zhang, Xuejun

    2015-01-01

    Microencapsulation technologies for functional smart Coatings for autonomous corrosion control have been a research area of strong emphasis during the last decade. This work concerns the development of pH sensitive micro-containers (microparticles and microcapsules) for autonomous corrosion control. This paper presents an overview of the state-of-the-art in the field of microencapsulation for corrosion control applications, as well as the technical details of the pH sensitive microcontainer approach, such as selection criteria for corrosion indicators and corrosion inhibitors; the development and optimization of encapsulation methods; function evaluation before and after incorporation of the microcontainers into coatings; and further optimization to improve coating compatibility and performance.

  9. Active corrosion protection performance of an epoxy coating applied on the mild steel modified with an eco-friendly sol-gel film impregnated with green corrosion inhibitor loaded nanocontainers

    Science.gov (United States)

    Izadi, M.; Shahrabi, T.; Ramezanzadeh, B.

    2018-05-01

    In this study the corrosion resistance, active protection, and cathodic disbonding performance of an epoxy coating were improved through surface modification of steel by a hybrid sol-gel system filled with green corrosion inhibitors loaded nanocontainer as intermediate layer on mild steel substrate. The green inhibitor loaded nanocontainers (GIN) were used to induce active inhibition performance in the protective coating system. The corrosion protection performance of the coated panels was investigated by electrochemical impedance spectroscopy (EIS), salt spray, and cathodic disbonding tests. It was observed that the corrosion inhibition performance of the coated mild steel panels was significantly improved by utilization of active multilayer coating system. The inhibitor release from nanocontainers at the epoxy-silane film/steel interface resulted in the anodic and cathodic reactions restriction, leading to the lower coating delamination from the substrate and corrosion products progress. Also, the active inhibition performance of the coating system was approved by electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM), and energy dispersive X-ray (EDS) analysis on the panels with artificial defects. The inhibitive agents were released to the scratch region and blocked the active sites on the metal surface.

  10. Corrosion performance of Al-Si-Cu hypereutectic alloys in a synthetic condensed automotive solution

    Directory of Open Access Journals (Sweden)

    Hamilta de Oliveira Santos

    2005-06-01

    Full Text Available In this investigation the corrosion resistance of four Al-Si hypereutectic alloys in a solution typical of condensate from automotive fuel combustion products, and referred to here as synthetic condensed automotive solution, has been studied. Three commercial alloys that are used for cylinder liners, and a laboratory made alloy, were studied by electrochemical impedance spectroscopy and measurements were taken after increasing times of immersion in this solution. Comparison of the electrochemical response of the four alloys in the corrosive solution was carried out. Although the mechanisms by which the four alloys corroded were similar, the results indicated differences in corrosion resistances of these alloys, and these differences could be related to their microstructures. The laboratory prepared alloy showed increased susceptibility to pitting corrosion compared to the commercial alloys. The surfaces of the alloys were examined, before and after the corrosion test, by scanning electron microscopy and analyzed by energy dispersive spectroscopy. The results indicated preferential attack of the aluminium matrix phase in all the alloys. The alloy with higher copper content and prepared by spray forming was more susceptible to pitting compared to the other alloys. The EIS response at low frequencies indicated a diffusion-controlled process, probably that of oxygen to the alloy interface.

  11. Performability Modelling Tools, Evaluation Techniques and Applications

    NARCIS (Netherlands)

    Haverkort, Boudewijn R.H.M.

    1990-01-01

    This thesis deals with three aspects of quantitative evaluation of fault-tolerant and distributed computer and communication systems: performability evaluation techniques, performability modelling tools, and performability modelling applications. Performability modelling is a relatively new

  12. Detection and evaluation of corrosion zones at high temperature in steam generators; Deteccion y evaluacion de zonas de corrosion en alta temperatura de generadoras de vapor

    Energy Technology Data Exchange (ETDEWEB)

    Martinez Villafane, Alberto; Chacon Nava, Jose G.; Huerta Espino, Mario; Mojica Calderon, Cecilio; Castillo Viveros, Antonio [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1990-12-31

    This paper presents the methodology for the detection and evaluation of high corrosion zones at high temperature. The results found up to now, show a critical zone in the Babcock Hitachi design, specifically in the high temperature reheater in the zone nearby the outlet header. In the normalized design CE (Mitsubishi) of 300 MW and CE (Canada) of 300 MW, the results found in recent years show small thickness reduction, therefore a good operation of these steam generators is recognized. [Espanol] En este trabajo se presenta la metodologia para la deteccion y evaluacion de zonas de corrosion en alta temperatura. Los resultados encontrados hasta el momento muestran una zona critica en el diseno Babcock Hitachi, especificamente en el recalentador de alta temperatura en la zona cercana al cabezal de salida. En el diseno normalizado CE (Mitsubishi) de 300 MW y CE (Canada) de 300 MW, los resultados encontrados en anos recientes muestran poca disminucion de espesor, por lo que se considera una buena operacion de estos generadores de vapor.

  13. Detection and evaluation of corrosion zones at high temperature in steam generators; Deteccion y evaluacion de zonas de corrosion en alta temperatura de generadoras de vapor

    Energy Technology Data Exchange (ETDEWEB)

    Martinez Villafane, Alberto; Chacon Nava, Jose G; Huerta Espino, Mario; Mojica Calderon, Cecilio; Castillo Viveros, Antonio [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1991-12-31

    This paper presents the methodology for the detection and evaluation of high corrosion zones at high temperature. The results found up to now, show a critical zone in the Babcock Hitachi design, specifically in the high temperature reheater in the zone nearby the outlet header. In the normalized design CE (Mitsubishi) of 300 MW and CE (Canada) of 300 MW, the results found in recent years show small thickness reduction, therefore a good operation of these steam generators is recognized. [Espanol] En este trabajo se presenta la metodologia para la deteccion y evaluacion de zonas de corrosion en alta temperatura. Los resultados encontrados hasta el momento muestran una zona critica en el diseno Babcock Hitachi, especificamente en el recalentador de alta temperatura en la zona cercana al cabezal de salida. En el diseno normalizado CE (Mitsubishi) de 300 MW y CE (Canada) de 300 MW, los resultados encontrados en anos recientes muestran poca disminucion de espesor, por lo que se considera una buena operacion de estos generadores de vapor.

  14. Steam based conversion coating on AA6060 alloy: Effect of sodium silicate chemistry and corrosion performance

    DEFF Research Database (Denmark)

    Din, Rameez Ud; Bordo, Kirill; Tabrizian, Naja

    2017-01-01

    . Moreover, the use of sodium silicate resulted in the formation of distinct microstructure and incorporation of silicate into the oxide film. These oxide films reduced the anodic activity 4 times, while the corrosion protection by silicate containing oxide was the function of its concentration. Further......Surface treatment of aluminium alloy AA6060 using an industrially applicable pilot steam jet system with and without silicate chemistry has been investigated. Treatment using steam alone and steam with silicate, resulted in an oxide layer formation with thickness ∼425 nm and ∼160 nm, respectively......, in acid salt spray and filiform corrosion tests, oxide layer containing silicate exhibited two times higher corrosion resistance....

  15. The jet impingement cell: A valuable device for investigating CO{sub 2} corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Kinsella, Brian; John, Douglas; Bailey, Stuart; De Marco, Roland [Western Australian Corrosion Research Group, School of Applied Chemistry, Curtin University of Technology, GPO Box U1987, Perth WA, 6845 (Australia)

    2004-07-01

    The jet impingement cell (JIC) is a valuable technique for the investigation of carbon dioxide corrosion of steel and its inhibition under high flow conditions or high wall shear stress. Despite the use of the JIC in corrosion testing laboratories not a great deal has been published on the design and calibration of these cells. In the evaluation of corrosion inhibitors, the type of corrosion and relative performance of the inhibitors depends on the metallurgy of the steel used to manufacture electrodes and measure the corrosion rate. This paper covers aspects of cell design and the determination of mass transfer and wall shear stress at electrodes used in the cell. The performance of different generic type corrosion inhibitors and their affect on the type of corrosion (i.e, uniform, pitting and crevice corrosion) is shown and discussed. (authors)

  16. Evaluation of pawpaw leaves extract as anti-corrosion agent for ...

    African Journals Online (AJOL)

    Pawpaw leaves extract was examined as anti-corrosion agent for aluminium in hydrochloric acid medium. The extract and corrosion product were analyzed using Fourier transform infrared spectrophotometer (FTIR). Thermometric, gravimetric, potentiodynamic polarization and scanning electron microscopic methods were ...

  17. Evaluate Data Center Network Performance

    DEFF Research Database (Denmark)

    Pilimon, Artur

    through a data center network, which is usually built with layer 2 switches and layer 3 routers. The topology of the data center network is crucial for latency in the data communication to and from the data center and between servers in the data center. Tests can be conducted to measure latency and other...... Engineering, scientists evaluate data center network topologies with an SDN-based (Software-Defined Networking) control framework measuring network performance – primarily latency. This can be used to plan data center scaling by testing how a new topology will function before changes are made. Data center...... performance parameters for different data center network topologies. It is however important that tests can be repeated and reproduced to have comparable information from the tests. There are, of course, many topologies that can be used for data center networks. At DTU Fotonik, Department of Photonics...

  18. Effect of substrate temperature on corrosion performance of nitrogen doped amorphous carbon thin films in NaCl solution

    Energy Technology Data Exchange (ETDEWEB)

    Khun, N.W. [School of Mechanical and Aerospace Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore); Liu, E., E-mail: MEJLiu@ntu.edu.s [School of Mechanical and Aerospace Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore)

    2009-07-01

    Nitrogen doped amorphous carbon (a-C:N) thin films were deposited on p-Si substrates by DC magnetron sputtering at varying substrate temperature from room temperature (RT) to 300 {sup o}C. The bonding structure, surface morphology and adhesion strength of the a-C:N films were investigated by using X-ray photoelectron spectroscopy (XPS), micro-Raman spectroscopy, atomic force microscopy (AFM) and micro-scratch testing. The corrosion behavior of the a-C:N films was evaluated by potentiodynamic polarization test in a 0.6 M NaCl solution. The results indicated that the corrosion resistance of the films depended on the sp{sup 3}-bonded cross-link structure that was significantly affected by the substrate temperature.

  19. Effect of substrate temperature on corrosion performance of nitrogen doped amorphous carbon thin films in NaCl solution

    International Nuclear Information System (INIS)

    Khun, N.W.; Liu, E.

    2009-01-01

    Nitrogen doped amorphous carbon (a-C:N) thin films were deposited on p-Si substrates by DC magnetron sputtering at varying substrate temperature from room temperature (RT) to 300 o C. The bonding structure, surface morphology and adhesion strength of the a-C:N films were investigated by using X-ray photoelectron spectroscopy (XPS), micro-Raman spectroscopy, atomic force microscopy (AFM) and micro-scratch testing. The corrosion behavior of the a-C:N films was evaluated by potentiodynamic polarization test in a 0.6 M NaCl solution. The results indicated that the corrosion resistance of the films depended on the sp 3 -bonded cross-link structure that was significantly affected by the substrate temperature.

  20. Ni-Cr based dental alloys; Ni release, corrosion and biological evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Reclaru, L., E-mail: lucien.reclaru@pxgroup.com [PX Holding S.A., Dep R and D Corrosion and Biocompatibility Group, Bd. des Eplatures 42, CH-2304 La Chaux-de-Fonds (Switzerland); Unger, R.E.; Kirkpatrick, C.J. [Institute for Pathology, REPAIR Lab, University Medical Center, Johannes Gutenberg University Mainz, Langenbeckstr.1, D-55101 Mainz (Germany); Susz, C.; Eschler, P.-Y.; Zuercher, M.-H. [PX Holding S.A., Dep R and D Corrosion and Biocompatibility Group, Bd. des Eplatures 42, CH-2304 La Chaux-de-Fonds (Switzerland); Antoniac, I. [Materials Science and Engineering Faculty, Politehnica of Bucharest, 060042 Bucharest (Romania); Luethy, H. [Institute of Dental Materials Science and Technology, University of Basel, Hebelstrasse 3, CH-4056 Basel (Switzerland)

    2012-08-01

    In the last years the dental alloy market has undergone dramatic changes for reasons of economy and biocompatibility. Nickel based alloys have become widely used substitute for the much more expensive precious metal alloys. In Europe the prevalence of nickel allergy is 10-15% for female adults and 1-3% for male adults. Despite the restrictions imposed by the EU for the protection of the general population in contact dermatitis, the use of Ni-Cr dental alloys is on the increase. Some questions have to be faced regarding the safety risk of nickel contained in dental alloys. We have collected based on many EU markets, 8 Ni-Cr dental alloys. Microstructure characterization, corrosion resistance (generalized, crevice and pitting) in saliva and the quantities of cations released in particular nickel and CrVI have been evaluated. We have applied non parametric classification tests (Kendall rank correlation) for all chemical results. Also cytotoxicity tests and an evaluation specific to TNF-alpha have been conducted. According to the obtained results, it was found that their behavior to corrosion was weak but that nickel release was high. The quantities of nickel released are higher than the limits imposed in the EU concerning contact with the skin or piercing. Surprisingly the biological tests did not show any cytotoxic effect on Hela and L929 cells or any change in TNF-alpha expression in monocytic cells. The alloys did not show any proinflammatory response in endothelial cells as demonstrated by the absence of ICAM-1 induction. We note therefore that there is really no direct relationship between the in vitro biological evaluation tests and the physico-chemical characterization of these dental alloys. Clinical and epidemiological studies are required to clarify these aspects. - Highlights: Black-Right-Pointing-Pointer Nickel released was higher than the limits imposed in EU in contact with the skin. Black-Right-Pointing-Pointer No direct relationship between the

  1. Corrosion behavior of Zircaloy 4 cladding material. Evaluation of the hydriding effect

    International Nuclear Information System (INIS)

    Blat, M.

    1997-04-01

    In this work, particular attention has been paid to the hydriding effect in PIE and laboratory test to validate a detrimental hydrogen contribution on Zircaloy 4 corrosion behavior at high burnup. Laboratory corrosion tests results confirm that hydrides have a detrimental role on corrosion kinetics. This effect is particularly significant for cathodic charged samples with a massive hydride outer layer before corrosion test. PIE show that at high burnup a hydride layer is formed underneath the metal/oxide interface. The results of the metallurgical examinations are discussed with respect to the possible mechanisms involved in this detrimental effect of hydrogen. Therefore, according to the laboratory tests results and PIE, hydrogen could be a strong contributor to explain the increase in corrosion rate at high burnup. (author)

  2. Corrosion evaluation of zirconium doped oxide coatings on aluminum formed by plasma electrolytic oxidation.

    Science.gov (United States)

    Bajat, Jelena; Mišković-Stanković, Vesna; Vasilić, Rastko; Stojadinović, Stevan

    2014-01-01

    The plasma electrolytic oxidation (PEO) of aluminum in sodium tungstate (Na(2)WO(4) · (2)H(2)O) and Na(2)WO(4) · (2)H(2)O doped with Zr was analyzed in order to obtain oxide coatings with improved corrosion resistance. The influence of current density in PEO process and anodization time was investigated, as well as the influence of Zr, with the aim to find out how they affect the chemical content, morphology, surface roughness, and corrosion stability of oxide coatings. It was shown that the presence of Zr increases the corrosion stability of oxide coatings for all investigated PEO times. Evolution of EIS spectra during the exposure to 3% NaCl, as a strong corrosive agent, indicated the highest corrosion stability for PEO coating formed on aluminum at 70 mA/cm(2) for 2 min in a zirconium containing electrolyte.

  3. DOE-DARPA High-Performance Corrosion-Resistant Materials (HPCRM), Annual HPCRM Team Meeting & Technical Review

    Energy Technology Data Exchange (ETDEWEB)

    Farmer, J; Brown, B; Bayles, B; Lemieux, T; Choi, J; Ajdelsztajn, L; Dannenberg, J; Lavernia, E; Schoenung, J; Branagan, D; Blue, C; Peter, B; Beardsley, B; Graeve, O; Aprigliano, L; Yang, N; Perepezko, J; Hildal, K; Kaufman, L; Lewandowski, J; Perepezko, J; Hildal, K; Kaufman, L; Lewandowski, J; Boudreau, J

    2007-09-21

    The overall goal is to develop high-performance corrosion-resistant iron-based amorphous-metal coatings for prolonged trouble-free use in very aggressive environments: seawater & hot geothermal brines. The specific technical objectives are: (1) Synthesize Fe-based amorphous-metal coating with corrosion resistance comparable/superior to Ni-based Alloy C-22; (2) Establish processing parameter windows for applying and controlling coating attributes (porosity, density, bonding); (3) Assess possible cost savings through substitution of Fe-based material for more expensive Ni-based Alloy C-22; (4) Demonstrate practical fabrication processes; (5) Produce quality materials and data with complete traceability for nuclear applications; and (6) Develop, validate and calibrate computational models to enable life prediction and process design.

  4. Anti-Corrosion Performance of 1,3-BENZOTHIAZOLE on 410 Martensitic Stainless Steel in H2SO4

    Science.gov (United States)

    Loto, Roland Tolulope

    The corrosion inhibition effect of synthesized 1,3-benzothiazole at very low concentrations on 410 martensitic stainless steel in 3MH2SO4 solution was studied through potentiodynamic polarization and weight loss measurements. The observation showed that the organic compound performed effectively with average inhibition efficiencies of 94% and 98% at the concentrations studied from both electrochemical methods due to the inhibition action of protonated inhibitor molecules in the acid solution. The amine and aromatics functional groups of the molecules active in the corrosion inhibition reaction were exposed from Attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR) spectroscopic analysis. Thermodynamic calculations showed cationic adsorption to be chemisorption adsorption, obeying the Langmuir adsorption isotherm. Images from optical microscopy showed an improved morphology in comparison to images from corroded stainless steel. Severe surface deterioration and macro-pits were observed in the uninhibited samples.

  5. Properties and performance of spin-on-glass coatings for the corrosion protection of stainless steels in chloride media

    DEFF Research Database (Denmark)

    Lampert, Felix; Jensen, Annemette H.; Din, Rameez U.

    2018-01-01

    Spin-on-glass deposition was investigated as viable alternative to increase the durability and performance of 316L steel in chloride environment. The buildup of a detrimental interface oxide was prevented by non-oxidative thermal curing of the coatings, which leads to a transformation...... silica. Electrochemical analysis by cyclic polarization indicated that the coatings behave as imperfect barrier coatings, which may enhance the passive properties of the substrates; however, there is still some statistical scatter in the quality of the coatings. While there is a tendency for an increase...... of the upper limit of the breakdown potential, there is also a decrease of the lower limit. It was found that such lower quality coatings showed, in association with substrate defects, unevenly distributed coating flaws, which may act as initiation points of pitting corrosion and decrease the corrosion...

  6. Properties and Corrosion Performance of Self-reinforced Composite PEEK for Proposed Use as a Modular Taper Gasket.

    Science.gov (United States)

    Ouellette, Eric S; Gilbert, Jeremy L

    2016-11-01

    Fretting corrosion in medical alloys is a persistent problem, and the need for biomaterials that can effectively suppress mechanically assisted crevice corrosion in modular taper junctions or otherwise insulate metal-on-metal interfaces in mechanically demanding environments is as yet unmet. The purpose of this study is to characterize a novel material, self-reinforced composite polyetheretherketone (SRC-PEEK) and to evaluate its ability to inhibit fretting corrosion in a pin-on-disk metal-on-metal interface test. SRC-PEEK was fabricated by hot compaction of in-house-made PEEK fibers by compacting uniaxial layups at 344°C under a load of 18,000 N for 10 minutes. SRC-PEEK, bulk isotropic PEEK, and the in-house-made PEEK fibers were analyzed for thermal transitions (T g , T m ) through differential scanning calorimetry, crystallinity, crystal size, crystalline orientation (Hermanns orientation parameter) through wide-angle x-ray scattering, and modulus, tensile strength, yield stress, and strain to failure through monotonic tensile testing. SRC-insulated pin-on-disk samples were compared with metal-on-metal control samples in pin-on-disk fretting corrosion experiments using fretting current and fretting mechanics measurements. Fifty-micron cyclic motion at 2.5 Hz was applied to the interface, first over a range of loads (0.5-35 N) while held at -0.05 V versus Ag/AgCl and then over a range of voltages (-0.5 to 0.5 V) at a constant contact stress of 73 ± 19 MPa for SRC-PEEK and 209 ± 41 MPa for metal-on-metal, which were different for each group as a result of changes in true contact area due to variations in modulus between sample groups. Pins, disks, and SRC samples were imaged for damage (on alloy and SRC surfaces) and evidence of corrosion (on alloy pin and disk surfaces). SRC specimens were analyzed for traces of alloy transferred to the surface using energy dispersive spectroscopy after pin-on-disk testing. SRC-PEEK showed improved mechanical properties to

  7. Plant operator performance evaluation system

    International Nuclear Information System (INIS)

    Ujita, Hiroshi; Fukuda, Mitsuko; Kubota, Ryuji.

    1989-01-01

    A plant operator performance evaluation system to analyze plant operation records during accident training and to identify and classify operator errors has been developed for the purpose of supporting realization of a training and education system for plant operators. A knowledge engineering technique was applied to evaluation of operator behavior by both even-based and symptom-based procedures, in various situations including event transition due to multiple failures or operational errors. The system classifies the identified errors as to their single and double types based on Swain's error classification and the error levels reflecting Rasmussen's cognitive level, and it also evaluates the effect of errors on plant state and then classifies error influence, using 'knowledge for phenomena and operations', as represented by frames. It has additional functions for analysis of error statistics and knowledge acquisition support of 'knowledge for operations'. The system was applied to a training analysis for a scram event in a BWR plant, and its error analysis function was confirmed to be effective by operational experts. (author)

  8. 60NiTi Intermetallic Material Evaluation for Lightweight and Corrosion Resistant Spherical Sliding Bearings for Aerospace Applications

    Science.gov (United States)

    DellaCorte, Christopher; Jefferson, Michael

    2015-01-01

    NASA Glenn Research Center and the Kamatics subsidiary of the Kaman Corporation conducted the experimental evaluation of spherical sliding bearings made with 60NiTi inner races. The goal of the project was to assess the feasibility of manufacturing lightweight, corrosion resistant bearings utilizing 60NiTi for aerospace and industrial applications. NASA produced the bearings in collaboration with Abbott Ball Corporation and Kamatics fabricated bearing assemblies utilizing their standard reinforced polymer liner material. The assembled bearings were tested in oscillatory motion at a load of 4.54kN (10,000 lb), according to the requirements of the plain bearing specification SAE AS81820. Several test bearings were exposed to hydraulic fluid or aircraft deicing fluid prior to and during testing. The results show that the 60NiTi bearings exhibit tribological performance comparable to conventional stainless steel (440C) bearings. Further, exposure of 60NiTi bearings to the contaminant fluids had no apparent performance effect. It is concluded that 60NiTi is a feasible bearing material for aerospace and industrial spherical bearing applications.

  9. Effect of sulfur on the SCC and corrosion fatigue performance of stainless steel

    International Nuclear Information System (INIS)

    West, E.; Nolan, T.; Lucente, A.; Morton, D.; Lewis, N.; Morris, R.; Mullen, J.; Newsome, G.

    2015-01-01

    Stress corrosion cracking and corrosion fatigue experiments were conducted on model heats of 304/304L stainless steel with systematically controlled sulfur content to isolate the influence of sulfur on crack growth behavior. The results of the SCC experiments conducted in 338 C. degrees deaerated water on 20% cold worked model heats with 0.006 and 0.012 wt% sulfur showed an order of magnitude or more reduction in the crack growth rate relative to a model heat with <0.001 wt% sulfur. Corrosion fatigue crack growth rates revealed a reduction in the crack growth rates of the elevated sulfur heats relative to model predicted steady state crack growth rates with increasing rise time for nominal loading conditions of a stress ratio of 0.7 and a stress intensity factor range of 6.6 MPa√m. At the longest rise time of 5.330 sec, the corrosion fatigue crack growth rate of the 0.006 wt% sulfur model heat was only 13% of model predictions and the crack growth of the 0.012 wt% sulfur heat completely stalled. Experiments conducted in anion faulted aerated water on stainless steel heats with moderate to high sulfur and variable carbon and boron contents showed that any detrimental effect of sulfur in this environment was secondary to the effect of sensitization in promoting SCC growth. (authors)

  10. Anti-corrosion performance of oxidized and oxygen plasma-implanted NiTi alloys

    International Nuclear Information System (INIS)

    Poon, Ray W.Y.; Ho, Joan P.Y.; Liu, Xuanyong; Chung, C.Y.; Chu, Paul K.; Yeung, Kelvin W.K.; Lu, William W.; Cheung, Kenneth M.C.

    2005-01-01

    Nickel-titanium shape memory alloys are useful orthopedic biomaterials on account of its super-elastic and shape memory properties. However, the problem associated with out-diffusion of harmful nickel ions in prolonged use inside the human body raises a critical safety concern. Titanium oxide films are deemed to be chemically inert and biocompatible and hence suitable to be the barrier layers to impede the leaching of Ni from the NiTi substrate to biological tissues and fluids. In the work reported in this paper, we compare the anti-corrosion efficacy of oxide films produced by atmospheric-pressure oxidation and oxygen plasma ion implantation. Our results show that the oxidized samples do not possess improved corrosion resistance and may even fare worse than the untreated samples. On the other hand, the plasma-implanted surfaces exhibit much improved corrosion resistance. Our work also shows that post-implantation annealing can further promote the anti-corrosion capability of the samples

  11. Corrosion Performance of Carbon Steel in Simulated Pore Solution in the Presence of Micelles

    NARCIS (Netherlands)

    Hu, J.; Koleva, D.A.; De Wit, J.H.W.; Kolev, H.; Van Breugel, K.

    2011-01-01

    This study presents the results on the investigation of the corrosion behavior of carbon steel in model alkaline medium in the presence of very low concentration of polymeric nanoaggregates [0.0024 wt % polyethylene oxide (PEO)113-b-PS70 micelles]. The steel electrodes were investigated in chloride

  12. A new corrosion resistant, martensitic stainless steel for improved performance in miniature bearings

    Energy Technology Data Exchange (ETDEWEB)

    Tomasello, C.M.; Maloney, J.L.; Materkowski, J.P. [Latrobe Steel Co., Latrobe, PA (United States); Ward, P.C. [MPB Corp., Keene, NH (United States)

    1998-12-31

    A new alloy, 440 N-DUR{trademark} has been developed which will provide the corrosion resistance of 440C with improved carbide size and distribution for noiseless miniature precision bearing operation. The alloy may be through hardened to achieve a minimum hardness of 60 HRC. Its nominal composition is 0.65 wt.% C, 14.5 wt.% Cr, 0.30 wt.% Si, 0.45 wt.% Mn and 0.10 wt.% N{sub 2}. The development of the alloy is a result of a factorial experimental design including 17 alloy variants. The optimum alloy provides a combination of the best carbide structure, corrosion resistance and heat treat response. The addition of nitrogen combined with this carbon and chromium content improves the alloy`s hardenability and corrosion resistance. The alloy successfully withstands copper sulfate exposure and is currently being tested in several bearing applications. It also has great potential to outperform 440C and other corrosion resistant alloys for other ambient and low temperature applications because of its improved microstructure and heat treat response.

  13. Tempering effect on corrosion performance of magnesium alloys for biomedical applications

    NARCIS (Netherlands)

    Zhang, X.; Ferrari, G.M.; Erinc, M.; Sillekens, W.H.

    2010-01-01

    The corrosion resistances for magnesium alloys AZ80, AE82 and ZM21 treated at 200 and 330°C for 2 hours, and for AZ80 and AE82 at 415°C for 8 hours were investigated using potentiodynamic polarization measurements in simulated body fluid (SBF) solution at 37°C. The morphology and the Volta potential

  14. 48 CFR 436.604 - Performance evaluation.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 4 2010-10-01 2010-10-01 false Performance evaluation... Performance evaluation. Preparation of performance evaluation reports. (a) In addition to the requirements of FAR 36.604, performance evaluation reports shall be prepared for indefinite-delivery type contracts...

  15. Electrochemical noise evaluation of anodized aluminum. Comparative study against corrosion behaviour in the atmosphere

    Directory of Open Access Journals (Sweden)

    Betancourt, N.

    2003-12-01

    Full Text Available The present work reports the evaluation of aluminum and anodized aluminum by electrochemical noise, as a part of the PATINA/CYTED project of the working group Nº 5. A visual examination is also made. The samples were exposed at several Ibero-American atmospheres up to 2 years of exposure. Different thickness of anodized aluminum were evaluated. The electrochemical potential noise of the 5 μm unexposed sample (pattern showed a different behaviour to that showed by the other anodized specimens. This could be due to a slower sealed of the samples of higher thickness. The same behaviour was observed on the samples exposed at the rural station El Pardo. According to the visual examination, the samples of bare aluminum and those of anodized 5 μm thickness were the most affected by pitting corrosion in the highly polluted atmospheres. A good correlation between corrosion behaviour determined by visual examination and EN was obtained.

    Como parte de las investigaciones de la Red PATINA el grupo de trabajo Nº 5 dedicó su atención al comportamiento del aluminio desnudo y anodizado con diferentes espesores en diferentes atmósferas de Iberoamérica. En el presente trabajo se presenta una evaluación de patrones de aluminio 99,5 % de pureza desnudo y anodizado con espesores de 15 y 25 μm, mediante ruido electroquímico. Los resultados obtenidos se comparan con el comportamiento determinado en diferentes atmósferas durante un período de 2 años. El ruido de voltaje del patrón de 5 μm de espesor presenta un comportamiento diferente al de los restantes espesores, lo que coincide con una mayor susceptibilidad a la corrosión picadura de este primer anodizado. Se reportan también algunas diferencias en el ruido de corriente. Se concluye que mediante la utilización del ruido electroquímico es posible caracterizar el aluminio con respecto a su sensibilidad a la corrosión picadura en condiciones atmosféricas.

  16. Evaluation of microstructural effects on the corrosion behaviour of AZ91D magnesium alloy

    DEFF Research Database (Denmark)

    Ambat, Rajan; Aung, Naing Naing; Zhou, W.

    2000-01-01

    The effect of microconstituents on the corrosion and electrochemical behaviour of AZ91D alloy prepared by die-casting and ingot casting route has been investigated in 3.5% NaCl solution at pH 7.25. The experimental techniques used include constant immersion technique, in-situ corrosion monitoring....... The corrosion products for ingot consisted of Mg(OH)(2) with small amounts beta phase, magnesium-aluminum oxide and MgH2 while for die-cast, the product showed a highly amorphous structure. (C) 2000 Elsevier Science Ltd. All rights reserved....

  17. Methodology for corrosion evaluation in HAZ of 11%-Cr ferritic stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Nascimento, Carmem C. F.; Rodrigues, Samul F. [Dept. of Mechanic and MaterialsFederal Institute of Education, Science and Technology of Maranhao, Sao Luis (Brazil); De Morais, Vinicius M.; Vilarinho, Louriel O. [Dept. of Mechanic Engineering, Federal University of Uberlandia, Uberlandia (Brazil)

    2016-08-15

    A novel methodology is proposed for corrosion-wear measurement in the Heat affected zone (HAZ) of 11%-Cr ferritic stainless steel. Weld beads with different stress-concentration were manufactured by using MIG/MAG process. After, the welded sample is extracted from the plate, the beads were bended and external stress was applied. Finally, they were inserted in ferric-chloride solution. Corrosive wear were assessed by means of optical microscopy in the HAZ by using polymeric resin mask and comparing profiles before and after inserting the sample into the solution. The results demonstrate the feasibility of the proposed methodology for assessing corrosive wear in the HAZ.

  18. Electrochemical evaluation of zinc effect on the corrosion of nickel alloy in PWR solutions with increasing temperature

    International Nuclear Information System (INIS)

    Alvial M, Gaston; Neves, Celia F.C.; Schvartzman, Monica M.A.M.; Quinan, Marco Antonio D.

    2007-01-01

    The main objective for the addition of zinc acetate to the reactor coolant system of PWRs is to effect radiation dose rate reductions. However, zinc is also added as an approach to mitigate the occurrence or severity of primary water stress corrosion cracking of nickel alloy 600. The mechanism by which zinc affects the corrosion of austenitic nickel-base alloys is by incorporation of zinc into the spinel oxide corrosion films. The purpose of this work is to evaluate the influence of zinc on the corrosion behavior of the nickel alloy 600 in PWR chemical environment (1200 ppm B, 2.2 ppm Li, deoxygenated water) with increasing temperature at room pressure. Electrochemical tests (anodic potentiodynamic polarization and electrochemical impedance spectroscopy) were used to characterize the alloy 600. Two conditions were applied: 0 and 100 ppb zinc and the temperature range was 50 - 90 deg C, at ambient pressure. Potentiodynamic polarization was inefficient to present conclusive results. Impedance measurements showed single semicircle in the Nyquist plane suggesting reduction of the charge transference resistance in zinc-containing solutions. This effect is evident at 90 deg C suggesting prejudicial influence of zinc for the alloy 600 at room pressure. (author)

  19. Evaluation of the low corrosion resistant phase formed during the sigma phase precipitation in duplex stainless steels

    Directory of Open Access Journals (Sweden)

    Darlene Yuko Kobayashi

    1999-10-01

    Full Text Available The duplex stainless steels, having a volumetric fraction of 50% ferrite and 50% austenite, conciliate high corrosion resistance with good mechanical properties. But, in many circumstances different phase transformations may occur, such as that responsible for sigma phase precipitation, which make the steel susceptible to localized corrosion. During the sigma phase precipitation a new austenitic phase is formed with a very low corrosion resistance. In the present research the composition of this new austenitic phase was evaluated in four duplex stainless steels, with different Mo, N and Cu contents. After the solution anneal at 1050 °C, samples of these steels were aged at 850 °C during 1 h and 5 h for sigma phase precipitation. Using the ferritoscope and an image analyzer it was possible to determine the volumetric fractions of ferrite and sigma phase, respectively, while those of austenite and the new austenitic phase were determined by difference to 100% volume. Finally, by using mass balance it was possible to determine theoretically the composition of the new austenitic phase. This phase is poor in Cr and Mo free, which explains its poor corrosion resistance.

  20. Evaluation of corrosion resistance of implant-use Ti-Zr binary alloys with a range of compositions.

    Science.gov (United States)

    Akimoto, Teisuke; Ueno, Takeshi; Tsutsumi, Yusuke; Doi, Hisashi; Hanawa, Takao; Wakabayashi, Noriyuki

    2018-01-01

    Although titanium-zirconium (Ti-Zr) alloy has been adopted for clinical applications, the ideal proportion of Zr in the alloy has not been identified. In this study, we investigated the biocompatibility of Ti-Zr alloy by evaluating its corrosion resistance to better understand whether there is an optimal range or value of Zr proportion in the alloy. We prepared pure Ti, Ti-30Zr, Ti-50Zr, Ti-70Zr, and pure Zr (mol% of Zr) samples and subjected them to anodic polarization and immersion tests in a lactic acid + sodium chloride (NaCl) solution and artificial saliva. We observed pitting corrosion in the Ti-70Zr and Zr after exposure to both solutions. After the immersion test, we found that pure Ti exhibited the greatest degree of dissolution in the lactic acid + NaCl solution, with the addition of Zr dramatically reducing Ti ion dissolution, with the reduction ultimately exceeding 90% in the case of the Ti-30Zr. Hence, although the localized corrosion resistance under severe conditions was compromised when the Zr content was more than 70%, metal ion release reduced owing to Zr addition and the corresponding formation of a stable passive layer. The results suggest that Ti-30Zr or a Zr proportion of less than 50% would offer an ideal level of corrosion resistance for clinical applications. © 2016 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 106B: 73-79, 2018. © 2016 Wiley Periodicals, Inc.

  1. Electrochemical evaluation of antibacterial drugs as environment-friendly inhibitors for corrosion of carbon steel in HCl solution

    Energy Technology Data Exchange (ETDEWEB)

    Golestani, Gh.; Shahidi, M., E-mail: shahidi1965@gmail.com; Ghazanfari, D.

    2014-07-01

    The effect of penicillin G, ampicillin and amoxicillin drugs on the corrosion behavior of carbon steel (ASTM 1015) in 1.0 mol L⁻¹ hydrochloric acid solution was investigated using potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical noise (EN) techniques. The inhibition efficiency was found to increase with increasing inhibitor concentration. The effect of temperature on the rate of corrosion in the absence and presence of these drugs was also studied. Some thermodynamic parameters were computed from the effect of temperature on corrosion and inhibition processes. Adsorption of these inhibitors was found to obey Langmuir adsorption isotherm. There was a case of mixed mode of adsorption here but while penicillin was adsorbed mainly through chemisorption, two other drugs were adsorbed mainly through physisorption. Potentiodynamic polarization measurements indicated that the inhibitors were of mixed type. In addition, this paper suggests that the electrochemical noise (EN) technique under open circuit conditions as the truly noninvasive electrochemical method can be employed for the quantitative evaluation of corrosion inhibition. This was done by using the standard deviation of partial signal (SDPS) for calculation of the amount of noise charges at the particular interval of frequency, thereby obtaining the inhibition efficiency (IE) of an inhibitor. These IE values showed a reasonable agreement with those obtained from potentiodynamic polarization and EIS measurements.

  2. Electrochemical evaluation of antibacterial drugs as environment-friendly inhibitors for corrosion of carbon steel in HCl solution

    International Nuclear Information System (INIS)

    Golestani, Gh.; Shahidi, M.; Ghazanfari, D.

    2014-01-01

    The effect of penicillin G, ampicillin and amoxicillin drugs on the corrosion behavior of carbon steel (ASTM 1015) in 1.0 mol L −1 hydrochloric acid solution was investigated using potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical noise (EN) techniques. The inhibition efficiency was found to increase with increasing inhibitor concentration. The effect of temperature on the rate of corrosion in the absence and presence of these drugs was also studied. Some thermodynamic parameters were computed from the effect of temperature on corrosion and inhibition processes. Adsorption of these inhibitors was found to obey Langmuir adsorption isotherm. There was a case of mixed mode of adsorption here but while penicillin was adsorbed mainly through chemisorption, two other drugs were adsorbed mainly through physisorption. Potentiodynamic polarization measurements indicated that the inhibitors were of mixed type. In addition, this paper suggests that the electrochemical noise (EN) technique under open circuit conditions as the truly noninvasive electrochemical method can be employed for the quantitative evaluation of corrosion inhibition. This was done by using the standard deviation of partial signal (SDPS) for calculation of the amount of noise charges at the particular interval of frequency, thereby obtaining the inhibition efficiency (IE) of an inhibitor. These IE values showed a reasonable agreement with those obtained from potentiodynamic polarization and EIS measurements.

  3. Evaluation of CRUDTRAN code to predict transport of corrosion products and radioactivity in the PWR primary coolant system

    International Nuclear Information System (INIS)

    Lee, C.B.

    2002-01-01

    CRUDTRAN code is to predict transport of the corrosion products and their radio-activated nuclides such as cobalt-58 and cobalt-60 in the PWR primary coolant system. In CRUDTRAN code the PWR primary circuit is divided into three principal sections such as the core, the coolant and the steam generator. The main driving force for corrosion product transport in the PWR primary coolant comes from coolant temperature change throughout the system and a subsequent change in corrosion product solubility. As the coolant temperature changes around the PWR primary circuit, saturation status of the corrosion products in the coolant also changes such that under-saturation in steam generator and super-saturation in the core. CRUDTRAN code was evaluated by comparison with the results of the in-reactor loop tests simulating the PWR primary coolant system and PWR plant data. It showed that CRUDTRAN could predict variations of cobalt-58 and cobalt-60 radioactivity with time, plant cycle and coolant chemistry in the PWR plant. (author)

  4. Corrosion evaluation of heat recovery steam generator superheater tube in two methods of testing: Tafel polarization and electrochemical impedance spectroscopy (EIS)

    Science.gov (United States)

    Santoso, Rio Pudjidarma; Riastuti, Rini

    2018-05-01

    The purpose of this research is to evaluate the corrosion process which occurs on the water side of Heat Recovery Steam Generator (HRSG) superheater tube. The tube was 13CrMo44 and divided into 3 types of specimen: new tube, used tube (with oxide layer on surface), cleaned-used tube (without oxide layer on surface). The evaluation of corrosion parameters wasperformed using deaerated ultra-high purity water (boiler feed water) in two methods of testing: Tafel polarization and Electrochemical Impedance Spectroscopy (EIS). Tafel polarization was excellent as its capability to show the value of corrosion current and the corrosion rate explicitly, on the other hand, EIS was excellent as its capability to explain for corrosion mechanism on metal interface in detail. Both methods showed that the increase of electrolyte temperature from 25°C to 55°C would increase the corrosion rate with the mechanism of decreasing polarization resistance due to thinning out the passive film thickness and enlarge the area of reduction reaction of cathode. Magnetite oxide scale which is laid on the surface of used tube specimen shows protective nature to reduce the corrosion rate, and clear up this oxide would increase the corrosion rate back as new tube.

  5. Benchmarking of Zinc Coatings for Corrosion Protection: A Detailed Characterization of Corrosion and Electrochemical Properties of Zinc Coatings

    Energy Technology Data Exchange (ETDEWEB)

    Wijesinghe, Sudesh L; Zixi, Tan [Singapore Institute of Manufacturing Technology, Nanyang Drive (Singapore)

    2017-02-15

    Due to various types of Zn coatings for many decades for various applications, it is imperative to study and compare their corrosion resistance properties of some of these. Here, we introduce a systematic methodology for evaluation and validation of corrosion protection properties of metallic coatings. According to this methodology, samples are were exposed in an advanced cyclic corrosion test chamber according to ISO 14993, and removed at the end of each withdrawal for respective corrosion and electrochemical characterization to evaluate both barrier and galvanic protection properties. Corrosion protection properties of coatings were evaluated by visual examination according to ISO 10289, mass loss and subsequent corrosion rate measurements, electrochemical properties, and advanced electrochemical scanning techniques. In this study, corrosion protection properties of a commercial zinc rich coating (ZRC) on AISI 1020 mild steel substrates were evaluated and benchmarked against hot dip galvanized (HDG). Results were correlated, and corrosion protection capabilities of the two coatings were compared. The zinc rich coating performed better than hot dip galvanized coating in terms of overall corrosion protection properties, according to the exposure and experimental conditions used in this study. It proved to be a suitable candidate to replace hot dip galvanized coatings for desired applications.

  6. Predicting the Oxidation/Corrosion Performance of Structural Alloys in Supercritical CO2

    Energy Technology Data Exchange (ETDEWEB)

    Wright, Ian [Wright HT Inc., Denver, CO (United States); Kung, Steven [Electric Power Research Inst. (EPRI), Charlotte, NC (United States); Shingledecker, John [Electric Power Research Inst. (EPRI), Charlotte, NC (United States)

    2017-12-22

    This project was the first research to address oxidation of alloys under supercritical CO2 conditions relevant to a semi-open Allam Cycle system. The levels of impurities expected in the CO2 for typical operation were determined by thermodynamic and mass balance calculations, and a test rig was assembled and used to run corrosion tests at temperatures from 650 to 750°C in CO2 at 200 bar for up to 5,000h, with and without impurities. Oxidation rates were measured for seven alloys representing high-strength ferritic steels, standard austenitic steels, and Ni-based alloys with higher-temperature capabilities. The very thin, protective scales formed on the high-temperature alloys provided significant challenges in characterization and thickness measurement. The rates of mass gain and scale thickening were possibly slower when oxidizing impurities were present in the sCO2, and the scale morphologies formed on the ferritic and austenitic steels were consistent with expectations, and similar to those formed in high-pressure steam, with some potential influences of C. Some surface hardening (possibly due to carbon uptake) was identified in ferritic steels Grade 91 and VM12, and appeared more severe in commercially-pure CO2. Hardening was also observed in austenitic steel TP304H, but that in HR3C appeared anomalous, probably the result of work-hardening from specimen preparation. No hardening was found in Ni-base alloys IN617 and IN740H. An existing EPRI Oxide Exfoliation Model was modified for this application and used to evaluate the potential impact of the scales grown in sCO2 on service lifetimes in compact heat exchanger designs. Results suggested that reduction in flow area by simple oxide growth as well as by accumulation of exfoliated scale may have a major effect on the design of small-channel heat exchangers. In addition, the specific oxidation behavior of each alloy strongly influences the

  7. Evaluation of Deoxygenation as a Corrosion Control Measure for Ballast Tanks

    National Research Council Canada - National Science Library

    Lee, Jason S; Ray, Richard I; Lemieux, Edward; Little, Brenda J

    2005-01-01

    .... Using a gas mixture it was possible to displace dissolved oxygen in natural seawater. However, aerobic respiration and corrosion reactions consumed oxygen and produced totally anaerobic conditions within the first days of hypoxia...

  8. Evaluation of Deoxygenation as a Corrosion Control Measure for Ballast Tanks

    National Research Council Canada - National Science Library

    Lee, Jason S; Ray, Richard I; Little, Brenda J; Lemieux, Edward

    2006-01-01

    .... Using a gas mixture it was possible to displace dissolved oxygen. However, aerobic respiration and corrosion reactions consumed oxygen and produced totally anaerobic conditions within the first days of hypoxia...

  9. Effect of sewage sludge ash (SSA on the mechanical performance and corrosion levels of reinforced Portland cement mortars

    Directory of Open Access Journals (Sweden)

    Andión, L. G.ª

    2006-06-01

    Full Text Available The article describes a study conducted to determinecorrosion in reinforcement embedded in Portland cement(PC mortars with different percentages of sewage sludgeash (SSA admixtures. The polarization resistancetechnique was used to determine the steel corrosion rate(Icorr in the test specimens. The samples were subjectedto different environmental conditions and aggressiveagents: 100% relative humidity (RH, accelerated carbonationat 70% RH and seawater immersion. Portlandcement was partially substituted for SSA in the mixes atrates of 0, 10, 20, 30 and 60% (by mass to make thedifferent mortars. The results show that where cementwas replaced by SSA at rates of up to 10% by mass,mortar corrosion performance was comparable to thebehaviour observed in SSA-free mortars (control mortar:0% SSA. Data for higher rates are also shown. From themechanical standpoint, SSA exhibited moderate pozzolanicactivity and the best performance when SSA wasadded at a rate of 10% to mixes with a water/(binder:PC + SSA (w/b ratio of 0.5.Se ha estudiado el nivel de corrosion que presentan lasarmaduras embebidas en morteros fabricados con cementoPortland (CP con diferentes porcentajes de sustitucion deceniza de lodo de depuradora (CLD. Se ha utilizado la tecnicade la Resistencia a la Polarizacion para determinar lavelocidad de corrosion del acero embebido en las muestrasestudiadas. Las muestras se han sometido a diferentes condicionesambientales y agentes agresivos: 100% de humedadrelativa (HR, carbonatacion acelerada al 70% HR einmersion en agua de mar. Para la fabricacion de los distintosmorteros, el cemento Portland ha sido parcialmente sustituidopor CLD en los siguientes porcentajes en masa: 0,10, 20, 30 y 60%. Los resultados muestran que sustitucionesde cemento por CLD de hasta el 10% en masa no alteranel comportamiento frente a la corrosion de los morterosal compararlos con los morteros libres de CLD (morteroscontrol: 0% de sustitucion de cemento por CLD. Se

  10. Evaluation of local stress for stress corrosion crack initiation by three-dimensional polycrystal model

    International Nuclear Information System (INIS)

    Kamaya, Masayuki; Kitamura, Takayuki

    2006-01-01

    In order to understand the initiation behavior of microstructurally small cracks in a stress corrosion cracking condition, it is important to know the tensile normal stress acting on the grain boundary (normal G.B. stress). The local stress in a polycrystalline body is greatly influenced by deformation constraint which is caused by anisotropic and/or inhomogeneous property of each grain. In present study, the local normal G.B. stress on bi- and tri-crystal bodies and a three-dimensional polycrystalline body consisting of 100 grains were evaluated by the finite element method under a remote uniform tensile stress condition. The polycrystalline body was generated by using a Monte Carlo procedure and random orientations were assigned to each grain. It was revealed that the local normal G.B. stress on the polycrystalline body is inhomogeneous under uniform applied stress. The stress tends to be large near the triple points due to the deformation constraint caused by adjacent grains, even though the grain boundary inclination to the load axis has large influence. It was also shown that particular high stress was not observed at corners of the polycrystalline body. (author)

  11. Fracture evaluation of an in-service piping flaw caused by microbiologically induced corrosion

    International Nuclear Information System (INIS)

    Rudland, D.L.; Scott, P.M.; Wilkowski, G.M.; Rahman, S.

    1996-01-01

    A pipe fracture experiment was conducted on a section of 6-inch nominal diameter pipe which was degraded by microbiologically induced corrosion (MIC) at a circumferential girth weld. The pipe was a section of one of the service water piping systems to one of the emergency diesel generators at the Haddam Neck (Connecticut Yankee) plant. The experimental results will help validate future ASME Section XI pipe flaw evaluation criteria for other than Class 1 piping. A critical aspect of this experiment was an assessment of the degree of conservatism embodied in the ASME definition of flaw size. The ASME flaw size definition assumes a rectangular shaped, constant depth flaw with a depth equal to its maximum depth for its entire length. Since most service flaws are irregular in shape, this definition may be overly conservative. Results from several fracture prediction models are compared with the experimental results. These results show that, for this case, the ASME Appendix H criteria significantly underpredicted the experimental maximum moment, while other fracture prediction models provided good predictions when accurate pipe, weld and flaw dimensions were used

  12. Evaluation of sensitization and corrosive damages of the weldment for SUS 316 stainless steel

    International Nuclear Information System (INIS)

    Na, Eui Gyun

    2013-01-01

    The anodic polarization method was verified to be suitable for evaluating the degree of sensitization for the weldment of stainless steel at the passive region. Heat treated weldment and parent are more sensitized than untreated weldments and parents. Specifically, weldments treated at 730 .deg. C with a 4 h holding time and then cooled in a furnace are the most sensitized. An unstable passive film formed on the surface of the heated-treated weldment because of the Cr-depletion zone at the passive region. The time to failure (TTF) for the parent in synthetic seawater requires a longer amount of time than that in air. However, the TTF for the weldment is shorter than that in air. The heat treated-weldment in a corrosive environment was the most severely damaged among the specimens. For the heat-treated weldment, most acoustic emission (AE) counts were emitted until 4 x 10 5 s, whereas those for the untreated weldment were produced over the elastic-plastic deformation range. Moreover, the number of AE counts per hour for the heat- treated weldments and parents decreased considerably compared with the untreated weldments and parents

  13. Comparative evaluation of coating techniques for the corrosion protection of disposal container for spent nuclear fuel

    International Nuclear Information System (INIS)

    Chun, Kwan Sik; Kim, Sung Soo; Park, Chong Mook; Choi, Jong Won

    2005-02-01

    To propose a suitable coating technique to prevent corrosion on metal or metal alloys of a waste container to be used for the disposal of spent nuclear fuel, several methods related to spray coating and vapor deposition techniques have been comparatively evaluated, based on some major factors recommended. From these comparative results, it can be suggested that the best coating methods among the existing techniques in Korea would be HVOF and low pressure plasma spray. Even though the surface of the container coated by these methods would be coated, pores could be remained in the coated film. And therefore post-treatment methods for eliminating the pores have been briefly introduced to keep the life time of the container. The other techniques, the cold spray and hollow cathode discharge, may become excellent coating methods in the future if they are extensively researched to apply for coating on the container. An optimal process among the recommended methods should be selected by considering the state of container, such as an empty or a loaded container, and also related coating materials. For the support to this, the characteristics of the coating materials and the coated films and the durability of this film under a repository condition should be analyzed in detail

  14. Corrosion performance of optimised and advanced fuel rod cladding in PWRs at high burnups

    International Nuclear Information System (INIS)

    Jourdain, P.; Hallstadius, L.; Pati, S.R.; Smith, G.P.; Garde, A.M.

    1997-01-01

    The corrosion behaviour both in-pile and out-of-pile for a number of cladding alloys developed by ABB to meet the current and future needs for fuel rod cladding with improved corrosion resistance is presented. The cladding materials include: 1) Zircaloy-4 (OPTIN) with optimised composition and processing and Zircaloy-2 optimised for Pressurised Water Reactors (PWR), (Zircaloy-2P), and 2) several alternative zirconium-based alloys with compositions outside the composition range for Zircaloys. The data presented originate from fuel rods irradiated in six PWRs to burnups up to about 66 MWd/kgU and from tests conducted in 360 o water autoclave. Also included are in-pile fuel rod growth measurements on some of the alloys. (UK)

  15. Amplified OTDR Systems for Multipoint Corrosion Monitoring

    Science.gov (United States)

    Nascimento, Jehan F.; Silva, Marcionilo J.; Coêlho, Isnaldo J. S.; Cipriano, Eliel; Martins-Filho, Joaquim F.

    2012-01-01

    We present two configurations of an amplified fiber-optic-based corrosion sensor using the optical time domain reflectometry (OTDR) technique as the interrogation method. The sensor system is multipoint, self-referenced, has no moving parts and can measure the corrosion rate several kilometers away from the OTDR equipment. The first OTDR monitoring system employs a remotely pumped in-line EDFA and it is used to evaluate the increase in system reach compared to a non-amplified configuration. The other amplified monitoring system uses an EDFA in booster configuration and we perform corrosion measurements and evaluations of system sensitivity to amplifier gain variations. Our experimental results obtained under controlled laboratory conditions show the advantages of the amplified system in terms of longer system reach with better spatial resolution, and also that the corrosion measurements obtained from our system are not sensitive to 3 dB gain variations. PMID:22737017

  16. 48 CFR 2936.604 - Performance evaluation.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 7 2010-10-01 2010-10-01 false Performance evaluation... Performance evaluation. (a) The HCA must establish procedures to evaluate architect-engineer contractor... reports must be made using Standard Form 1421, Performance Evaluation (Architect-Engineer) as prescribed...

  17. 13 CFR 304.4 - Performance evaluations.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false Performance evaluations. 304.4... ECONOMIC DEVELOPMENT DISTRICTS § 304.4 Performance evaluations. (a) EDA shall evaluate the management... of at least one (1) other District Organization in the performance evaluation on a cost-reimbursement...

  18. Development and Evaluation of Cement-Based Materials for Repair of Corrosion-Damaged Reinforced Concrete Slabs

    OpenAIRE

    Liu, Rongtang; Olek, J.

    2001-01-01

    In this study, the results of an extensive laboratory investigation conducted to evaluate the properties of concrete mixes used as patching materials to repair reinforced concrete slabs damaged by corrosion are reported. Seven special concrete mixes containing various combinations of chemical or mineral admixtures were developed and used as a patching material to improve the durability of the repaired slabs. Physical and mechanical properties of these mixes, such as compressive strength, stat...

  19. Evaluation of Corrosion Caused by the use of In Natura Biogas in Steam Generator Boilers of Carbon Steel Structural Elements

    OpenAIRE

    Fontenelle, Marcellus; Alves, Helton José; Monteiro, Marcos Roberto; Higa, Silvia Midori; Rovere, Carlos Alberto Della; Pellizzer, Eder Luis; Fontenelle, Isaddora

    2017-01-01

    This work evaluates the corrosion process caused by the presence of hydrogen sulfide in the biogas in natura, in steels commonly used in the construction of steam generator boilers, simulating conditions close to those found on the real application of these materials, exposing the test bodies directly to biogas in natura, flame of combustion and gases resulting from the combustion of this biofuel, in chimney. After 314 hours of exposure under the specified conditions, the corroded surfaces of...

  20. 48 CFR 236.604 - Performance evaluation.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 3 2010-10-01 2010-10-01 false Performance evaluation... Architect-Engineer Services 236.604 Performance evaluation. (a) Preparation of performance reports. Use DD Form 2631, Performance Evaluation (Architect-Engineer), instead of SF 1421. (2) Prepare a separate...

  1. Evaluation of Iron Nickel Oxide Nanopowder as Corrosion Inhibitor: Effect of Metallic Cations on Carbon Steel in Aqueous NaCl

    Energy Technology Data Exchange (ETDEWEB)

    Chaudhry, A. U.; Mishra, Brajendra [Colorado School of Mines, Denver (United States); Mittal, Vikas [The Petroleum Institute, Abu Dhabi (United Arab Emirates)

    2016-01-15

    The aim of this study was to evaluate the use of iron-nickel oxide (Fe{sub 2}O{sub 3}.NiO) nanopowder (FeNi) as an anti-corrosion pigment for a different application. The corrosion protection ability and the mechanism involved was determined using aqueous solution of FeNi prepared in a corrosive solution containing 3.5 wt.% NaCl. Anti-corrosion abilities of aqueous solution were determined using electrochemical impedance spectroscopy (EIS) on line pipe steel (API 5L X-80). The protection mechanism involved the adsorption of metallic cations on the steel surface forming a protective film. Analysis of EIS spectra revealed that corrosion inhibition occurred at low concentration, whereas higher concentration of aqueous solution produced induction behavior.

  2. Stress Corrosion Cracking of Pipeline Steels in Fuel Grade Ethanol and Blends - Study to Evaluate Alternate Standard Tests and Phenomenological Understanding of SCC

    Science.gov (United States)

    2011-10-30

    Main aim of this project was to evaluate alternate standard test methods for stress corrosion cracking (SCC) and compare them with the results from slow strain rate test (SSRT) results under equivalent environmental conditions. Other important aim of...

  3. Evaluation of iron aluminide weld overlays for erosion - corrosion resistant boiler tube coatings in low NO{sub x} boilers

    Energy Technology Data Exchange (ETDEWEB)

    DuPont, J.N.; Banovic, S.W.; Marder, A.R. [Lehigh Univ., Bethlehem, PA (United States)

    1996-08-01

    Low NOx burners are being installed in many fossil fired power plants in order to comply with new Clean Air Regulations. Due to the operating characteristics of these burners, boiler tube sulfidation corrosion is often enhanced and premature tube failures can occur. Failures due to oxidation and solid particle erosion are also a concern. A program was initiated in early 1996 to evaluate the use of iron aluminide weld overlays for erosion/corrosion protection of boiler tubes in Low NOx boilers. Composite iron/aluminum wires will be used with the Gas Metal Arc Welding (GMAW) process to prepare overlays on boiler tubes steels with aluminum contents from 8 to 16wt%. The weldability of the composite wires will be evaluated as a function of chemical composition and welding parameters. The effect of overlay composition on corrosion (oxidation and sulfidation) and solid particle erosion will also be evaluated. The laboratory studies will be complemented by field exposures of both iron aluminide weld overlays and co-extruded tubing under actual boiler conditions.

  4. Evaluation of emergency department performance

    DEFF Research Database (Denmark)

    Sørup, Christian Michel; Jacobsen, Peter; Forberg, Jakob Lundager

    2013-01-01

    eligibility criteria includes: 1) the main purpose was to discuss, analyse, or promote performance measures best reflecting ED performance, 2) the article was a review article, and 3) the article reported macro-level performance measures, thus reflecting an overall departmental performance level. Results...... measures that related directly to the patient. Performance measures related to employees were only stated in two of the 14 included articles. Conclusions A total of 55 ED performance measures were identified. ED time intervals were the most recommended performance measures followed by patient centeredness...... and safety performance measures. ED employee related performance measures were rarely mentioned in the investigated literature. The study’s results allow for advancement towards improved performance measurement and standardised assessment across EDs....

  5. Monitoring Microbially Influenced Corrosion

    DEFF Research Database (Denmark)

    Hilbert, Lisbeth Rischel

    and diffusional effects and unreliable corrosion rates, when biofilm and ferrous sulphide corrosion products cover the steel surface. Corrosion rates can be overestimated by a factor of 10 to 100 by electrochemical techniques. Weight loss coupons and ER are recommended as necessary basic monitoring techniques......Abstract Microbially influenced corrosion (MIC) of carbon steel may occur in media with microbiological activity of especially sulphate-reducing bacteria (SRB). The applicability and reliability of a number of corrosion monitoring techniques for monitoring MIC has been evaluated in experiments....... EIS might be used for detection of MIC as the appearance of very large capacitances can be attributed to the combined ferrous sulphide and biofilm formation. Capacitance correlates directly with sulphide concentration in sterile sulphide media. Keywords: Corrosion monitoring, carbon steel, MIC, SRB...

  6. A study on corrosive behavior of spring steel by shot-peening process

    International Nuclear Information System (INIS)

    An, Jae Pil; Park, Keyung Dong

    2004-01-01

    In this study, the influence of shot peening on the corrosion was investigated on spring steel immersed in 3.5% NaCl. The immersion test was performed on the two kinds of specimens. Corrosion potential, polarization curve, residual stress and etc. were investigated from experimental results. From test results, the effect of shot peening on the corrosion was evaluated. In case of corrosion potential, shot peened specimen shows more activated negative direction as compared with parent metal. Surface of specimen, which is treated with the shot peened, is placed as more activated state against inner base metal. It can cause the anti-corrosion effect on the base metal

  7. Corrosion behavior of corrosion resistant alloys in stimulation acids

    Energy Technology Data Exchange (ETDEWEB)

    Cheldi, Tiziana [ENI E and P Division, 20097 San Donato Milanese Milano (Italy); Piccolo, Eugenio Lo; Scoppio, Lucrezia [Centro Sviluppo Materiali, via Castel Romano 100, 00128 Rome (Italy)

    2004-07-01

    In the oil and gas industry, selection of CRAs for downhole tubulars is generally based on resistance to corrosive species in the production environment containing CO{sub 2}, H{sub 2}S, chloride and in some case elemental sulphur. However, there are non-production environments to which these materials must also be resistant for either short term or prolonged duration; these environments include stimulation acids, brine and completion fluids. This paper reports the main results of a laboratory study performed to evaluate the corrosion and stress corrosion behaviour to the acidizing treatments of the most used CRAs for production tubing and casing. Laboratory tests were performed to simulate both 'active' and 'spent' acids operative phases, selecting various environmental conditions. The selected steel pipes were a low alloyed steel, martensitic, super-martensitic, duplex 22 Cr, superduplex 25 Cr and super-austenitic stainless steels (25 Cr 35 Ni). Results obtained in the 'active' acid environments over the temperature range of 100-140 deg. C, showed that the blend acids with HCl at high concentration and HCl + HF represented too much severe conditions, where preventing high general corrosion and heavy localised corrosion by inhibition package becomes very difficult, especially for duplex steel pipe, where, in some case, the specimens were completely dissolved into the solution. On the contrary, all steels pipes were successfully protected by inhibitor when organic acid solution (HCOOH + CH{sub 3}COOH) were used. Furthermore, different effectiveness on corrosion protection was showed by the tested inhibitors packages: e.g. in the 90% HCl at 12% + 10 CH{sub 3}COOH acid blend. In 'spent' acid environments, all steel pipes showed to be less susceptible to the localised and general corrosion attack. Moreover, no Sulphide Stress Corrosion Cracking (SSC) was observed. Only one super-austenitic stainless steel U-bend specimen showed

  8. Energy performance evaluation of AAC

    Science.gov (United States)

    Aybek, Hulya

    The U.S. building industry constitutes the largest consumer of energy (i.e., electricity, natural gas, petroleum) in the world. The building sector uses almost 41 percent of the primary energy and approximately 72 percent of the available electricity in the United States. As global energy-generating resources are being depleted at exponential rates, the amount of energy consumed and wasted cannot be ignored. Professionals concerned about the environment have placed a high priority on finding solutions that reduce energy consumption while maintaining occupant comfort. Sustainable design and the judicious combination of building materials comprise one solution to this problem. A future including sustainable energy may result from using energy simulation software to accurately estimate energy consumption and from applying building materials that achieve the potential results derived through simulation analysis. Energy-modeling tools assist professionals with making informed decisions about energy performance during the early planning phases of a design project, such as determining the most advantageous combination of building materials, choosing mechanical systems, and determining building orientation on the site. By implementing energy simulation software to estimate the effect of these factors on the energy consumption of a building, designers can make adjustments to their designs during the design phase when the effect on cost is minimal. The primary objective of this research consisted of identifying a method with which to properly select energy-efficient building materials and involved evaluating the potential of these materials to earn LEED credits when properly applied to a structure. In addition, this objective included establishing a framework that provides suggestions for improvements to currently available simulation software that enhance the viability of the estimates concerning energy efficiency and the achievements of LEED credits. The primary objective

  9. Comparison of corrosion performance of grade 316 and grade 347H stainless steels in molten nitrate salt

    Science.gov (United States)

    Trent, M. C.; Goods, S. H.; Bradshaw, R. W.

    2016-05-01

    Stainless steel samples machined from SA-312 TP316 and SA-213 TP347H pipe were exposed to a molten nitrate salt environment at 600°C (1112°F) for up to 3000 hours in order to generate corrosion rates for use in concentrated solar power (CSP) facilities. Descaled weight loss measurements were made at 1000, 2000, and 3000 hours, with optical and scanning electron microscopy being performed on samples at the longest exposure time. The 316 and 347H alloys exhibited metal losses of 4.4 and 4.8 um respectively at 3000 hours. A linear fit to the data sets yielded annualized metal loss rates of 8.4 and 8.8 um/yr. The oxides were relatively uniform in thickness and multilayered. The inner layer consisted of a (Fe, Cr)-spinel with appreciable amounts of Mn while the outer layer was an oxide composed of only Fe. No pitting, intergranular attack, or other localized attack was found, despite the presence of a sensitized microstructure in both alloys and chloride impurity in the salt mixture. The observations presented here indicate that the two alloys perform quite comparably with respect to molten salt-induced corrosion and in that regard; either would be expected to perform satisfactorily in the intended application.

  10. Effect of steel reinforcement with different degree of corrosion on degeneration of mechanical performance of reinforced concrete frame joints

    Directory of Open Access Journals (Sweden)

    Wu Xu

    2016-02-01

    Full Text Available Beam-column joints which shoulders high-level and vertical shearing effect that maintains balance of beam and column end is the major component influencing the performance of the whole framework. Post earthquake investigation suggests that collapse of frame structure is induced by failure of joints in most cases. Thus, beam-column joints must have strong bearing capacity and good ductility, and reinforced concrete structure just meets the above requirement. But corrosion caused by long time use of reinforced concrete framework will lead to degeneration of mechanical performance of joints. To find out the rule of effect of steel reinforcement with different corrosion rate on degeneration of bearing capacity of reinforced concrete framework joints, this study made a nonlinear numerical analysis on fifteen models without stirrup in the core area of reinforced concrete frame joints using displacement method considering axial load ratio of column end and constraint condition. This work aims to find out the key factor that influences mechanical performance of joints, thus to provide a basis for repair and reinforcement of degenerated framework joints.

  11. Accelerated growth of oxide film on aluminium alloys under steam: Part II: Effects of alloy chemistry and steam vapour pressure on corrosion and adhesion performance

    DEFF Research Database (Denmark)

    Din, Rameez Ud; Bordo, Kirill; Jellesen, Morten Stendahl

    2015-01-01

    The steam treatment of aluminium alloys with varying vapour pressure of steamresulted in the growth of aluminium oxyhydroxide films of thickness range between 450 - 825nm. The surface composition, corrosion resistance, and adhesion of the produced films was characterised by XPS, potentiodynamic p...... of the vapour pressure of the steam. The accelerated corrosion and adhesion tests on steam generated oxide films with commercial powder coating verified that the performance of the oxide coating is highly dependent on the vapour pressure of the steam....... polarization, acetic acid salt spray, filiform corrosion test, and tape test. The oxide films formed by steam treatment showed good corrosion resistance in NaCl solution by significantly reducing anodic and cathodic activities. The pitting potential of the surface treated with steam was a function...

  12. The Effect of Impingement Velocity and Angle Variation on the Erosion Corrosion Performance of API 5L-X65 Carbon Steel in a Flow Loop

    Directory of Open Access Journals (Sweden)

    Ihsan UlHaq Toor

    2018-05-01

    Full Text Available Erosion corrosion performance of API 5L-X65 carbon steel was investigated at three different impingement velocities (3, 6 & 12 m/s, five different angles (15, 30, 45, 60, & 90°, and with/without solid particles (average particle size of 314 µm. The experiments were conducted in 0.2 M NaCl solution at room temperature for a duration of 24 h and the results showed that the maximum erosion corrosion rate was observed at 45° irrespective of the velocity. The highest erosion corrosion rate at 45° was due to the balance between the shear and normal impact stress at this angle. Ploughing, deep craters, and micro-forging/plastic deformation were found to be the main erosion corrosion mechanisms. The maximum wear scar depth measured using optical profilometery was found to be 51 µm (average at an impingement angle of 45°.

  13. Evaluation of Nitrate and Nitrite Reduction Kinetics Related to Liquid-Air-Interface Corrosion

    International Nuclear Information System (INIS)

    Li, Xiaoji; Gui, F.; Cong, Hongbo; Brossia, C.S.; Frankel, G.S.

    2014-01-01

    Liquid-air interface (LAI) corrosion has been a concern for causing leaks in the carbon steel tanks used for holding high-level radioactive liquid waste. To assist in understanding the mechanism of LAI corrosion, the kinetics of nitrate and nitrite reduction reactions were investigated electrochemically. Cyclic voltammetry and cathodic polarization measurements indicated that the nitrite reduction reaction exhibited faster kinetics than the nitrate reduction reaction at higher cathodic overpotential. However, the primary reduction reaction at the open circuit potential under aerated conditions was the oxygen reduction reaction. The reduction of residual oxygen was also the dominant cathodic reaction at open circuit potential in deaerated conditions. Moreover, the kinetics of oxygen reduction on steel electrodes were significantly influenced by the sample immersion conditions (partial vs. full) for aerated liquid nuclear waste simulants, but not for deaerated conditions. Lastly, the gaseous products formed during LAI corrosion were analyzed using the gas detector tube method and gas chromatography-mass spectrometry and found to contain NH 3 , NO 2 and NO. However, the results suggested that these products were caused by the local acidification generated by the hydrolysis of cations after LAI corrosion underwent extensive propagation, instead of being directly reduced in alkaline conditions. Thus, the results in this work showed that the kinetics of nitrate and nitrite reduction could not generate a salt concentration cell in the meniscus region to cause LAI corrosion

  14. Evaluation of corrosion caused by the use of in natura biogas in steam generator boilers of carbon steel structural elements

    Energy Technology Data Exchange (ETDEWEB)

    Fontenelle, Marcellus; Alves, Helton Jose, E-mail: helquimica@gmail.com [Universidade Estadual do Oeste do Parana (UNIOESTE), Cascavel, PR (Brazil); Pellizzer, Eder Luis [Universidade do Oeste de Santa Catarina (UNOESC), Xanxere, SC (Brazil); Monteiro, Marcos Roberto; Rovere, Carlos Alberto Della [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil); Higa, Silvia Midori [Universidade Tecnologica Federal do Parana (UTFPR), Londrina, PR (Brazil); Fontenelle, Isaddora [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil)

    2017-05-15

    This work evaluates the corrosion process caused by the presence of hydrogen sulfide in the biogas in natura, in steels commonly used in the construction of steam generator boilers, simulating conditions close to those found on the real application of these materials, exposing the test bodies directly to biogas in natura, flame of combustion and gases resulting from the combustion of this biofuel, in chimney. After 314 hours of exposure under the specified conditions, the corroded surfaces of ASTM A178 and ASTM A516 were analyzed, by optical microscopy, electronic scanning microscopy, X-ray diffraction and surface hardness. The determination of corrosion rates for each test condition and each material tested can be used as a parameter for the determination of the minimum tolerance for mechanical stability, in the calculation of the minimum required thickness of the structural elements of the steam generator boilers fed to biogas. (author)

  15. Evaluation of corrosion caused by the use of in natura biogas in steam generator boilers of carbon steel structural elements

    International Nuclear Information System (INIS)

    Fontenelle, Marcellus; Alves, Helton Jose; Pellizzer, Eder Luis; Monteiro, Marcos Roberto; Rovere, Carlos Alberto Della; Higa, Silvia Midori; Fontenelle, Isaddora

    2017-01-01

    This work evaluates the corrosion process caused by the presence of hydrogen sulfide in the biogas in natura, in steels commonly used in the construction of steam generator boilers, simulating conditions close to those found on the real application of these materials, exposing the test bodies directly to biogas in natura, flame of combustion and gases resulting from the combustion of this biofuel, in chimney. After 314 hours of exposure under the specified conditions, the corroded surfaces of ASTM A178 and ASTM A516 were analyzed, by optical microscopy, electronic scanning microscopy, X-ray diffraction and surface hardness. The determination of corrosion rates for each test condition and each material tested can be used as a parameter for the determination of the minimum tolerance for mechanical stability, in the calculation of the minimum required thickness of the structural elements of the steam generator boilers fed to biogas. (author)

  16. Evaluation of the flow-accelerated corrosion downstream of an orifice. 1. Measurements and numerical analysis of flow field

    International Nuclear Information System (INIS)

    Utanohara, Yoichi; Nagaya, Yukinori; Nakamura, Akira; Murase, Michio

    2008-01-01

    In this study, in order to evaluate the effects of flow field on corrosion rate due to flow accelerated corrosion (FAC), an orifice flow was measured and calculated. The diameter of pipe is 50 mm and that of the orifice is 24.3 mm, and flow velocity in a water loop was set at 2.41 m/s. Flow field was measured by laser Doppler velocimetry (LDV) and particle image velocimetry (PIV), and compared with a calculation for the same flow conditions. Measurements of wall shear stress downstream of the orifice was also planed. The calculated velocity distribution of standard k-□ agreed qualitatively with PIV data and quantitatively with LDV data. Instantaneous flow field measured by PIV showed vortices around the jet from the orifice and some of them reached near the pipe wall. (author)

  17. Evaluation of Test Methodologies for Dissolution and Corrosion of Al-SNF

    International Nuclear Information System (INIS)

    Wiersma, B.J.; Mickalonis, J.I.; Louthan, M.R.

    1998-09-01

    The performance of aluminum-based spent nuclear fuel (Al-SNF) in the repository will differ from that of the commercial nuclear fuels and the high level waste glasses. The program consists of evaluating three test methods

  18. Corrosion aspects of steel radioactive waste containers in cementitious materials

    International Nuclear Information System (INIS)

    Smart, Nick

    2012-01-01

    Nick Smart from Serco, UK, gave an overview of the effects of cementitious materials on the corrosion of steel during storage and disposal of various low- and intermediate-level radioactive wastes. Steel containers are often used as an overpack for the containment of radioactive wastes and are routinely stored in an open atmosphere. Since this is an aerobic and typically humid environment, the steel containers can start to corrode whilst in storage. Steel containers often come into contact with cementitious materials (e.g. grout encapsulants, backfill). An extensive account of different steel container designs and of steel corrosion mechanisms was provided. Steel corrosion rates under conditions buffered by cementitious materials have been evaluated experimentally. The main conclusion was that the cementitious environment generally facilitates the passivation of steel materials. Several general and localised corrosion mechanisms need to be considered when evaluating the performance of steel containers in cementitious environments, and environmental thresholds can be defined and used with this aim. In addition, the consequences of the generation of gaseous hydrogen by the corrosion of carbon steel under anoxic conditions must be taken into account. Discussion of the paper included: Is crevice corrosion really significant in cementitious systems? Crevice corrosion is unlikely in the cementitious backfill considered because it will tend to neutralise any acidic conditions in the crevice. What is the role of microbially-induced corrosion (MIC) in cementitious systems? Microbes are likely to be present in a disposal facility but their effect on corrosion is uncertain

  19. Correlation between the oxide impedance and corrosion behavior of Zr-Nb-Sn-Fe-Cu alloys

    Science.gov (United States)

    Park, Sang-Yoon; Lee, Myung-Ho; Jeong, Yong-Hwan; Jung, Youn-Ho

    2004-12-01

    The correlation between the oxide impedance and corrosion behavior of two series of Zr-Nb-Sn-Fe-Cu alloys was evaluated. Corrosion tests were performed in a 70 ppm LiOH aqueous solution at 360°C for 300 days. The results of the corrosion tests revealed that the corrosion behavior of the alloys depended on the Nb and Sn content. The impedance characteristics for the pre- and post-transition oxide layers formed on the surface of the alloys were investigated in sulfuric acid at room temperature. From the results, a pertinent equivalent circuit model was preferably established, explaining the properties of double oxide layers. The impedance of the oxide layers correlated with the corrosion behavior; better corrosion resistance always showed higher electric resistance for the inner layers. It is thus concluded that a pertinent equivalent circuit model would be useful for evaluating the long-term corrosion behavior of Zr-Nb-Sn-Fe-Cu alloys.

  20. 48 CFR 36.604 - Performance evaluation.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 1 2010-10-01 2010-10-01 false Performance evaluation. 36.604 Section 36.604 Federal Acquisition Regulations System FEDERAL ACQUISITION REGULATION SPECIAL... Performance evaluation. See 42.1502(f) for the requirements for preparing past performance evaluations for...

  1. Performance evaluation and financial market runs

    NARCIS (Netherlands)

    Wagner, W.B.

    2013-01-01

    This paper develops a model in which performance evaluation causes runs by fund managers and results in asset fire sales. Performance evaluation nonetheless is efficient as it disciplines managers. Optimal performance evaluation combines absolute and relative components in order to make runs less

  2. Corrosion cracking

    International Nuclear Information System (INIS)

    Goel, V.S.

    1985-01-01

    This book presents the papers given at a conference on alloy corrosion cracking. Topics considered at the conference included the effect of niobium addition on intergranular stress corrosion cracking, corrosion-fatigue cracking in fossil-fueled-boilers, fracture toughness, fracture modes, hydrogen-induced thresholds, electrochemical and hydrogen permeation studies, the effect of seawater on fatigue crack propagation of wells for offshore structures, the corrosion fatigue of carbon steels in seawater, and stress corrosion cracking and the mechanical strength of alloy 600

  3. Corrosion of magnesium and aluminum in palm biodiesel: A comparative evaluation

    International Nuclear Information System (INIS)

    Chew, K.V.; Haseeb, A.S.M.A.; Masjuki, H.H.; Fazal, M.A.; Gupta, M.

    2013-01-01

    The present study aims to investigate the comparative corrosion of light-weight metals such as aluminum and magnesium in palm biodiesel. Immersion test at room temperature was carried out for each metal for 1440 h. Sample characterization techniques employed include weight loss measurement, SEM (scanning electron microscope), XRD (X-ray diffraction), TAN (total acid number) and FTIR (Fourier transform infrared spectroscopy). Results showed that the corrosion rate of magnesium was much higher compared to that of aluminum. The surface morphology revealed a significant difference between the biodiesel exposed aluminum and magnesium specimens. Upon exposure to biodiesel, the magnesium surface was found to be fully covered by gel-like sticky mass while the aluminum surface remained clean. - Highlights: • Biodiesel is highly corrosive for magnesium. • Biodiesel exposed magnesium surface showed yellowish gel-like sticky mass. • Biodiesel undergoes significant degradation upon exposure to metals

  4. In-vitro evaluation of corrosion resistance of nitrogen ion implanted titanium simulated body fluid

    International Nuclear Information System (INIS)

    Subbaiyan, M.; Sundararajian, T.; Rajeswari, S.; Kamachi Mudali, U.; Nair, K.G.M.; Thampi, N.S.

    1997-01-01

    Titanium and its alloy Ti6Al4V enjoy widespread use in various biomedical applications because of favourable local tissue response, higher corrosion resistance and fatigue strength than the stainless steels and cobalt-chromium alloy previously used. The study reported in this paper aims to optimize the conditions of nitrogen ion implantation on commercially pure titanium and to correlate the implantation parameters to the corrosion resistance. X-ray photoelectron spectroscopy was used to analyse surface concentration and the implantation processes. An improvement in the electrochemical behaviour of the passive film was shown to occur with nitrogen ion implantation on titanium, in simulated body fluids. (UK)

  5. Research Opportunities in Corrosion Science for Long-Term Prediction of Materials Performance: A Report of the DOE Workshop on ''Corrosion Issues of Relevance to the Yucca Mountain Waste Repository''

    International Nuclear Information System (INIS)

    Payer, Joe H.; Scully, John R.

    2003-01-01

    The report summarizes the findings of a U.S. Department of Energy workshop on ''Corrosion Issues of Relevance to the Yucca Mountain Waste Repository''. The workshop was held on July 29-30, 2003 in Bethesda, MD, and was co-sponsored by the Office of Basic Energy Sciences and Office of Civilian Radioactive Waste Management. The workshop focus was corrosion science relevant to long-term prediction of materials performance in hostile environments, with special focus on relevance to the permanent disposal of nuclear waste at the Yucca Mountain Repository. The culmination of the workshop is this report that identifies both generic and Yucca Mountain Project-specific research opportunities in basic and applied topic areas. The research opportunities would be realized well after the U.S. Nuclear Regulatory Commission's initial construction-authorization licensing process. At the workshop, twenty-three invited scientists deliberated on basic and applied science opportunities in corrosion science relevant to long-term prediction of damage accumulation by corrosive processes that affect materials performance.

  6. Research Opportunities in Corrosion Science for Long-Term Prediction of Materials Performance: A Report of the DOE Workshop on “Corrosion Issues of Relevance to the Yucca Mountain Waste Repository”.

    Energy Technology Data Exchange (ETDEWEB)

    Payer, Joe H. [Case Western Reserve Univ., Cleveland, OH (United States); Scully, John R. [Univ. of Virginia, Charlottesville, VA (United States)

    2003-07-29

    The report summarizes the findings of a U.S. Department of Energy workshop on “Corrosion Issues of Relevance to the Yucca Mountain Waste Repository”. The workshop was held on July 29-30, 2003 in Bethesda, MD, and was co-sponsored by the Office of Basic Energy Sciences and Office of Civilian Radioactive Waste Management. The workshop focus was corrosion science relevant to long-term prediction of materials performance in hostile environments, with special focus on relevance to the permanent disposal of nuclear waste at the Yucca Mountain Repository. The culmination of the workshop is this report that identifies both generic and Yucca Mountain Project-specific research opportunities in basic and applied topic areas. The research opportunities would be realized well after the U.S. Nuclear Regulatory Commission’s initial construction-authorization licensing process. At the workshop, twenty-three invited scientists deliberated on basic and applied science opportunities in corrosion science relevant to long-term prediction of damage accumulation by corrosive processes that affect materials performance.

  7. Corrosion inhibition by lithium zinc phosphate pigment

    International Nuclear Information System (INIS)

    Alibakhshi, E.; Ghasemi, E.; Mahdavian, M.

    2013-01-01

    Highlights: •Synthesis of lithium zinc phosphate (LZP) by chemical co-precipitation method. •Corrosion inhibition activity of pigments compare with zinc phosphate (ZP). •LZP showed superior corrosion inhibition effect in EIS measurements. •Evaluation of adhesion strength and dispersion stability. -- Abstract: Lithium zinc phosphate (LZP) has been synthesized through a co-precipitation process and characterized by XRD and IR spectroscopy. The inhibitive performances of this pigment for corrosion of mild steel have been discussed in comparison with the zinc phosphate (ZP) in the pigment extract solution by means of EIS and in the epoxy coating by means of salt spray. The EIS and salt spray results revealed the superior corrosion inhibitive effect of LZP compared to ZP. Moreover, adhesion strength and dispersion stability of the pigmented epoxy coating showed the advantage of LZP compared to ZP

  8. The corrosion behavior of hafnium in high-temperature-water environments

    Energy Technology Data Exchange (ETDEWEB)

    Rishel, D.M.; Smee, J.D.; Kammenzind, B.F.

    1999-10-01

    The high-temperature-water corrosion performance of hafnium is evaluated. Corrosion kinetic data are used to develop correlations that are a function of time and temperature. The evaluation is based on corrosion tests conducted in out-of-pile autoclaves and in out-of-flux locations of the Advanced Test Reactor (ATR) at temperatures ranging from 288 to 360 C. Similar to the corrosion behavior of unalloyed zirconium, the high-temperature-water corrosion response of hafnium exhibits three corrosion regimes: pretransition, posttransition, and spalling. In the pretransition regime, cubic corrosion kinetics are exhibited, whereas in the posttransition regime, linear corrosion kinetics are exhibited. Because of the scatter in the spalling regime data, it is not reasonable to use a best fit of the data to describe spalling regime corrosion. Data also show that neutron irradiation does not alter the corrosion performance of hafnium. Finally, the data illustrate that the corrosion rate of hafnium is significantly less than that of Zircaloy-2 and Zircaloy-4.

  9. 40 CFR 63.2354 - What performance tests, design evaluations, and performance evaluations must I conduct?

    Science.gov (United States)

    2010-07-01

    ... evaluations, and performance evaluations must I conduct? 63.2354 Section 63.2354 Protection of Environment... tests, design evaluations, and performance evaluations must I conduct? (a)(1) For each performance test... procedures specified in subpart SS of this part. (3) For each performance evaluation of a continuous emission...

  10. Effects of combined organic and inorganic corrosion inhibitors on the nanostructure cerium based conversion coating performance on AZ31 magnesium alloy: Morphological and corrosion studies

    International Nuclear Information System (INIS)

    Saei, E.; Ramezanzadeh, B.; Amini, R.; Kalajahi, M. Salami

    2017-01-01

    Highlights: •Cn-Mn-polyvinyl alcohol conversion coating led to more uniform and crack free film deposition. •The corrosion resistance of Ce film was noticeably improved by using combination of polyvinyl alchol and Mn2+ cations. •A synergistic effect between polyvinyl alchol-Mn2+ resulted in Ce film with enhanced morphology and corrosion resistance. -- Abstract: Magnesium (Mg) AZ31 samples were chemically treated by a series of room temperature nanostructure cerium based conversion coatings containing Mn(NO 3 ) 2 ·4H 2 O, Co(NO 3 ) 2 ·6H 2 O, and polyvinyl alcohol (PVA). The microstructure and corrosion protection properties of different samples were studied by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), electrochemical impedance spectroscopy (EIS) and polarization test in 3.5 wt.% NaCl solution. Results demonstrated that the AZ31 Mg alloy sample treated by Ce-Mn-PVA showed the highest corrosion resistance. A denser Ce film with lower crack was precipitated on the sample treated by Ce-Mn-PVA conversion coating.

  11. Investigation of structure, adhesion strength, wear performance and corrosion behavior of platinum/ruthenium/nitrogen doped diamond-like carbon thin films with respect to film thickness

    International Nuclear Information System (INIS)

    Khun, N.W.; Liu, E.

    2011-01-01

    Research highlights: → Sputtered PtRuN-DLC thin films were fabricated with different film thicknesses. → The graphitization of the films increased with increased film thickness. → The wear resistance of the films increased though their adhesion strength decreased. → The corrosion potentials of the films shifted to more negative values. → However, the corrosion currents of the films decreased. - Abstract: In this study, the corrosion performance of platinum/ruthenium/nitrogen doped diamond-like carbon (PtRuN-DLC) thin films deposited on p-Si substrates using a DC magnetron sputtering deposition system in a 0.1 M NaCl solution was investigated using potentiodynamic polarization test in terms of film thickness. The effect of the film thickness on the chemical composition, bonding structure, surface morphology, adhesion strength and wear resistance of the PtRuN-DLC films was studied using X-ray photoelectron spectroscopy (XPS), micro-Raman spectroscopy, atomic force microscopy (AFM), micro-scratch test and ball-on-disc tribotest, respectively. It was found that the wear resistance of the PtRuN-DLC films apparently increased with increased film thickness though the adhesion strength of the films decreased. The corrosion results revealed that the increased concentration of sp 2 bonds in the PtRuN-DLC films with increased film thickness shifted the corrosion potentials of the films to more negative values but the decreased porosity density in the films significantly decreased the corrosion currents of the films.

  12. Evaluation of the feasibility for detecting hidden corrosion damage in multi-layer gusset plates using multiple inspection techniques

    International Nuclear Information System (INIS)

    Cobb, Adam C.; Duffer, Charles E.; Light, Glenn M.

    2014-01-01

    Gusset plates are used to connect the members in truss bridges and they are usually inspected using calipers or conventional thickness measurement ultrasonic testing (UT) devices. The damage mechanism of particular concern in gusset plates is corrosion and the regions most susceptible to corrosion damage are on the gusset interior surface where it intersects the chord, diagonal, and vertical members from water collecting at the interfaces. For heavily loaded gusset plates, one or more shingle plates are used to reinforce the gusset plate, creating a multi-layer structure. While the areas with corrosion damage remain near the members on the gusset plate, the shingle plates cover the gusset plate and greatly limit the surface access to the gusset plate, making UT thickness measurement impractical. Because of the critical nature of the gussets, a viable inspection strategy for multi-layer gusset assemblies must be developed. The premise of this research and development effort was to develop viable, field-deployable inspection approaches for this problem area. This paper presents three separate inspection approaches: two ultrasonic-based techniques and one radiographic approach. Each of these techniques was evaluated on a mock-up specimen provided by the Federal Highway Administration (FHWA) that is representative of gusseted connection from a truss bridge

  13. Evaluation of the feasibility for detecting hidden corrosion damage in multi-layer gusset plates using multiple inspection techniques

    Energy Technology Data Exchange (ETDEWEB)

    Cobb, Adam C.; Duffer, Charles E.; Light, Glenn M. [Southwest Research Institute, 6220 Culebra Road, San Antonio, TX 78238-5166 (United States)

    2014-02-18

    Gusset plates are used to connect the members in truss bridges and they are usually inspected using calipers or conventional thickness measurement ultrasonic testing (UT) devices. The damage mechanism of particular concern in gusset plates is corrosion and the regions most susceptible to corrosion damage are on the gusset interior surface where it intersects the chord, diagonal, and vertical members from water collecting at the interfaces. For heavily loaded gusset plates, one or more shingle plates are used to reinforce the gusset plate, creating a multi-layer structure. While the areas with corrosion damage remain near the members on the gusset plate, the shingle plates cover the gusset plate and greatly limit the surface access to the gusset plate, making UT thickness measurement impractical. Because of the critical nature of the gussets, a viable inspection strategy for multi-layer gusset assemblies must be developed. The premise of this research and development effort was to develop viable, field-deployable inspection approaches for this problem area. This paper presents three separate inspection approaches: two ultrasonic-based techniques and one radiographic approach. Each of these techniques was evaluated on a mock-up specimen provided by the Federal Highway Administration (FHWA) that is representative of gusseted connection from a truss bridge.

  14. Development and evaluation of two PVD-coated β-titanium orthodontic archwires for fluoride-induced corrosion protection.

    Science.gov (United States)

    Krishnan, Vinod; Krishnan, Anand; Remya, R; Ravikumar, K K; Nair, S Asha; Shibli, S M A; Varma, H K; Sukumaran, K; Kumar, K Jyothindra

    2011-04-01

    The present research was aimed at developing surface coatings on β titanium orthodontic archwires capable of protection against fluoride-induced corrosion. Cathodic arc physical vapor deposition PVD (CA-PVD) and magnetron sputtering were utilized to deposit thin films of titanium aluminium nitride (TiAlN) and tungsten carbide/carbon (WC/C) coatings on β titanium orthodontic archwires. Uncoated and coated specimens were immersed in a high fluoride ion concentration mouth rinse, following a specially designed cycle simulating daily use. All specimens thus obtained were subjected to critical evaluation of parameters such as electrochemical corrosion behaviour, surface analysis, mechanical testing, microstructure, element release, and toxicology. The results confirm previous research that β titanium archwires undergo a degradation process when in contact with fluoride mouth rinses. The study confirmed the superior nature of the TiAlN coating, evident as many fewer changes in properties after fluoride treatment when compared with the WC/C coating. Thus, coating with TiAlN is recommended in order to reduce the corrosive effects of fluorides on β titanium orthodontic archwires. Copyright © 2010 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

  15. Evaluation of Mid-IR Laser radiation effect on 316l stainless steel corrosion resistance in physiological saline

    International Nuclear Information System (INIS)

    Khosroshahi, M.E.; Valanezhad, A.; Tavakoli, J.

    2004-01-01

    The effects of a short pulsed (∼ 400 ns ) multi line hydrogen fluoride laser radiation operating on average at 2.8 μm has been studied on 316l stainless steel in terms of optical and physical parameters. At low fluences ≤ 8 Jcm -2 (phase l) no morphological changes occurred at the surface and melting began at ∼ 8.8 Jcm -2 (phase l l) which continued up to about 30 Jcm -2 . In this range the melting zone was effectively produced by high temperature surface centres growth which subsequently joined these centres together. Thermal ablation via surface vaporization began at ∼ 33 Jcm -2 (phase lll). The results of scanning electron microscopy evaluation and corrosion resistance experiment which was carried out using Eg and G device with cyclic potentiodynamic polarization method in a physiological (Hank's) solution indicated that pitting corrosion sensitivity was decreased i.e.. enhancement of corrosion resistance. Also, the x-ray diffraction results showed a double increase of γ (lll) at microstructure, thus in effect a super austenite stainless steel was obtained at an optimized melting fluence

  16. Medicare Administrative Contractor Performance Evaluation

    Data.gov (United States)

    U.S. Department of Health & Human Services — The Centers for Medicare and Medicaid Services (CMS) has compiled a summary of overall Medicare Administrative Contractor (MAC) performance information as measured...

  17. Electroless Ni-P/Ni-B duplex coatings: preparation and evaluation of microhardness, wear and corrosion resistance

    International Nuclear Information System (INIS)

    Narayanan, T.S.N. Sankara; Krishnaveni, K.; Seshadri, S.K.

    2003-01-01

    The present work deals with the formation of Ni-P/Ni-B duplex coatings by electroless plating process and evaluation of their hardness, wear resistance and corrosion resistance. The Ni-P/Ni-B duplex coatings were prepared using dual baths (acidic hypophosphite- and alkaline borohydride-reduced electroless nickel baths) with both Ni-P and Ni-B as inner layers and with varying single layer thickness. Scanning electron microscopy (SEM) was used to assess the duplex interface. The microhardness, wear resistance and corrosion resistance of electroless nickel duplex coatings were compared with electroless Ni-P and Ni-B coatings of similar thickness. The study reveals that the Ni-P and Ni-B coatings are amorphous in their as-plated condition and upon heat-treatment at 450 deg. C for 1 h, both Ni-P and Ni-B coatings crystallize and produce nickel, nickel phosphide and nickel borides in the respective coatings. All the three phases are formed when Ni-P/Ni-B and Ni-B/Ni-P duplex coatings are heat-treated at 450 deg. C for 1 h. The duplex coatings are uniform and the compatibility between the layers is good. The microhardness, wear resistance and corrosion resistance of the duplex coating is higher than Ni-P and Ni-B coatings of similar thickness. Among the two types of duplex coatings studied, hardness and wear resistance is higher for coatings having Ni-B coating as the outer layer whereas better corrosion resistance is offered by coatings having Ni-P coating as the outer layer

  18. Evaluation of the corrosion of reinforced concrete designed for low and medium activity level radioactive waste containers

    International Nuclear Information System (INIS)

    Duffo, G.S.; Arva, E.A; Schulz, F.M; Vasquez, D.R

    2010-01-01

    The National Atomic Energy Commission of Argentina (CNEA) is responsible for the design and construction of a monolithic repository for the final disposal of low and medium level radioactive wastes. In order to ensure the protection of people and the environment, the useful life of the repository should be 300 years and the conceptual design selected is based on the use of multiple, independent and redundant barriers. These barriers consist mainly of reinforced concrete. This work aims to establish a methodology to determine the concrete's useful life, evaluating parameters of interest using chemical and electrochemical techniques. For this purpose, reinforced concrete test pieces were made with two formulations - blast furnace cement (BFC) and with BFC plus silica fume admixture (BFC+SF)- and in each of the test pieces segments of reinforcement were included. The development over time of the corrosion potential and speed were evaluated, together with the resistivity of the concrete in the test pieces exposed to the laboratory environment, with an average relative humidity of 50%, a condition that favors the carbonation process. The diffusion coefficients of aggressive species, such as chloride and carbon dioxide, were also determined in test pieces made with the two formulations. In the test pieces exposed to the laboratory environment the reinforcements embedded in the BFC+SF concrete showed a lower corrosion speed compared to the BFC concrete. These results agree with the lower values for the speeds of carbonation and of chloride diffusion that show that the concrete with BFC+SF is more resistant to incoming aggressive species compared with the BFC. A container prototype for mid-level radioactive wastes was built and outfitted with instruments in order to monitor the development over time of the corrosion speed of the reinforcement rods by using corrosion sensors developed by the group. The prototype, exposed to atmospheric conditions, was manufactured with BFC

  19. Aging evaluation of active components by using performance evaluation

    International Nuclear Information System (INIS)

    Jung, S. K.; Jin, T. E.; Kim, J. S.; Jung, I. S.; Kim, T. R.

    2003-01-01

    Risk analysis and performance evaluation methodology were applied to the aging evaluation of active components in the periodic safety review of Wolsung unit 1. We conclude that evaluation of performance is more effective to discriminate the aging degradation of active component than the evaluation of aging mechanism. It is essential to analyze the common cause failures of low performance components to evaluate the properness of present maintenance system. Past 10 years failure history is used for establishing the performance criteria. Past 2 years failure history is used for the evaluating the recent performance condition. We analyze the failure mode of the components to improve the maintenance system. Performance evaluation methodology is useful for the quantitative evaluation of aging degradation of active components. Analysis on the repeated failures can be useful for the feedback to maintenance plan and interval

  20. Evaluation of the cracking by stress corrosion in nuclear reactor environments type BWR

    International Nuclear Information System (INIS)

    Arganis J, C. R.

    2010-01-01

    The stress corrosion cracking susceptibility was studied in sensitized, solution annealed 304 steel, and in 304-L welded with a heat treatment that simulated the radiation induced segregation, by the slow strain rate test technique, in a similar environment of a boiling water reactor (BWR), 288 C, 8 MPa, low conductivity and a electrochemical corrosion potential near 200 mV. vs. standard hydrogen electrode (She). The electrochemical noise technique was used for the detection of the initiation and propagation of the cracking. The steels were characterized by metallographic studies with optical and scanning electronic microscopy and by the electrochemical potentiodynamic reactivation of single loop and double loop. In all the cases, the steels present delta ferrite. The slow strain rate tests showed that the 304 steel in the solution annealed condition is susceptible to transgranular stress corrosion cracking (TGSCC), such as in a normalized condition showed granulated. In the sensitized condition the steel showed intergranular stress corrosion cracking, followed by a transition to TGSCC. The electrochemical noise time series showed that is possible associated different time sequences to different modes of cracking and that is possible detect sequentially cracking events, it is means, one after other, supported by the fractographic studies by scanning electron microscopy. The parameter that can distinguish between the different modes of cracking is the re passivation rate, obtained by the current decay rate -n- in the current transients. This is due that the re passivation rate is a function of the microstructure and the sensitization. Other statistic parameters like the localized index, Kurtosis, Skew, produce results that are related with mixed corrosion. (Author)

  1. Evaluation method for corrosion level of rebar in RC with electrical impedance measurement

    Science.gov (United States)

    Sasamoto, Akira

    2018-04-01

    The author reported that the impedance measurement using the 4-terminal method on the RC surface for diagnosing corrosion of internal rebar. The difference between the maximum value at 0.01 Hz and the minimum value around 10 Hz indicates the corrosion level of rebar in that report. This is successive report on a signal processing method for estimating the corrosion level by the measured impedance data to obtain more high accuracy. In the dielectric, a graph of frequency and dielectric constant (Cole-Cole plot diagram by KS Cole and RH Cole article of 1941) draws a shape of circle if the dielectric is independent of frequency but it draws a shape of ellipse in reality due to frequency dependency. Havriliak and Negami have also presented Havriliak-Negami model which introduced parameter into dielectric constant equation which deforms Cole-Cole plot diagram and showed that acquired dielectric data of polymer materials fit to this model with proper parameters. In this report, we first consider electric model connected with resistance and capacitance as a rough model of RC concrete. If the capacitance in this model circuit has some loss of dielectric, it is stated that graph in impedance plot is expected to take as similar deformation in the dielectric Cole-Cole plot. Then a numerical optimization computer code for obtaining parameters in the Cole-Cole plot diagram and Havriliak-Negami model is constructed, and the correlation between the deformation parameter of each model and corrosion is shown by this code. These results are feasibility study for diagnosis of corrosion level of rebar by associated parameters to a shape of impedance graph.

  2. Evaluation on ultrasonic examination methods applied to Ni-base alloy weld including cracks due to stress corrosion cracking found in BWR reactor internal

    International Nuclear Information System (INIS)

    Aoki, Takayuki; Kobayashi, Hiroyuki; Higuchi, Shinichi; Shimizu, Sadato

    2005-01-01

    A Ni-base alloy weld, including cracks due to stress corrosion cracking found in the reactor internal of the oldest BWR in Japan, Tsuruga unit 1, in 1999, was examined by three (3) types of UT method. After this examination, a depth of each crack was confirmed by carrying out a little excavation with a grinder and PT examination by turns until each crack disappeared. Then, the depth measured by the former method was compared with the one measured by the latter method. In this fashion, performances of the UT methods were verified. As a result, a combination of the three types of UT method was found to meet the acceptance criteria given by ASME Sec.XI Appendix VIII, Performance Demonstration for Ultrasonic Examination Systems-Supplement 6. In this paper, the results of the UT examination described above and their evaluation are discussed. (author)

  3. Portfolio optimization and performance evaluation

    DEFF Research Database (Denmark)

    Juhl, Hans Jørn; Christensen, Michael

    2013-01-01

    Based on an exclusive business-to-business database comprising nearly 1,000 customers, the applicability of portfolio analysis is documented, and it is examined how such an optimization analysis can be used to explore the growth potential of a company. As opposed to any previous analyses, optimal...... customer portfolios are determined, and it is shown how marketing decision-makers can use this information in their marketing strategies to optimize the revenue growth of the company. Finally, our analysis is the first analysis which applies portfolio based methods to measure customer performance......, and it is shown how these performance measures complement the optimization analysis....

  4. Corrosion engineering

    Energy Technology Data Exchange (ETDEWEB)

    Fontana, M.G.

    1986-01-01

    This book emphasizes the engineering approach to handling corrosion. It presents corrosion data by corrosives or environments rather than by materials. It discusses the corrosion engineering of noble metals, ''exotic'' metals, non-metallics, coatings, mechanical properties, and corrosion testing, as well as modern concepts. New sections have been added on fracture mechanics, laser alloying, nuclear waste isolation, solar energy, geothermal energy, and the Statue of Liberty. Special isocorrosion charts, developed by the author, are introduced as a quick way to look at candidates for a particular corrosive.

  5. Evaluating judge performance in sport.

    Science.gov (United States)

    Looney, Marilyn A

    2004-01-01

    Many sports, such as, gymnastics, diving, ski jumping, and figure skating, use judges' scores to determine the winner of a competition. These judges use some type of rating scale when judging performances (e.g., figure skating: 0.0 - 6.0). Sport governing bodies have the responsibility of setting and enforcing quality control parameters for judge performance. Given the judging scandals in figure skating at the 1998 and 2002 Olympics, judge performance in sport is receiving greater scrutiny. The purpose of this article is to illustrate how results from Rasch analyses can be used to provide in-depth feedback to judges about their scoring patterns. Nine judges' scores for 20 pairs of figure skaters who competed at the 2002 Winter Olympics were analyzed using a four-faceted (skater pair ability, skating aspect difficulty, program difficulty, and judge severity) Rasch rating scale model that was not common to all judges. Fit statistics, the logical ordering of skating aspects, skating programs, and separation indices all indicated a good fit of the data to the model. The type of feedback that can be given to judges about their scoring pattern was illustrated for one judge (USA) whose performance was flagged as being unpredictable. Feedback included a detailed description of how the rating scale was used; for example, 10% of all marks given by the American judge were unexpected by the model (Z > |2|). Three figures illustrated differences between the judge's observed and expected marks arranged according to the pairs' skating order and final placement in the competition. Scores which may represent "nationalistic bias" or a skating order influence were flagged by looking at these figures. If sport governing bodies wish to improve the performance of their judges, they need to employ methods that monitor the internal consistency of each judge as a many-facet Rasch analysis does.

  6. Evaluation of the problematic of corrosion in bottoms of tanks of crude oil storage; Evaluacion de la problematica de corrosion en fondos de tanques de almacenamiento de petroleo crudo

    Energy Technology Data Exchange (ETDEWEB)

    Malo T, Jose M; Uruchurtu C, Jorge; Meza, Beatriz [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico); Lopez C, Luis F [Region Marina Suroeste, Pemex (Mexico)

    2003-07-01

    In this article the results related to the corrosive aggressiveness of the water fluids of crude oil of the Marine Terminal of Dos Bocas (TMDB), on the effectiveness of the anticorrosive control methods and on the control measures that could be adopted are presented. Also, this article comprises a work made by personnel of the Instituto de Investigaciones Electricas (IIE) during year 2002. The corrosion in tanks is of electrochemical nature and has its origin in the watery phase that accompanies the crude oil on being extracted from underground. In the case of the storage tanks, the watery phase separates at the bottom, causing the wetness of the bottom steel plates and its degradation. Due to the limited access to the interior of the tank during its operation, a testing device was designed that was connected to a drain valve of a tank of the terminal. The experimental work looked for the evaluation of the aggressiveness of the fluids, the type of corrosion products formed and the effectiveness of the cathodic protection and of the coatings. Additionally, fluid samples were collected, for analyzing the natural aggressiveness level that presents the water contained in the three types of crude: Mayan, Olmeca and Istmo handled in the terminal, studying steel samples and of plant fluids under controlled laboratory conditions. The aggressiveness was obtained from measurements of corrosion rates and analysis of microbial activity. The feasibility of applying the method of cathodic protection was analyzed, observing its effectiveness, as well as particular corrosion forms as the ones that occur in the pontoons. The results of the study lead to propose a monitoring scheme to pursuit the integrity of the coatings, the operation of the cathodic protection and the corrosion in tanks, with which a better control of the operation of the anticorrosive methods and of the degradation that occurs with the corrosion, could be obtained. [Spanish] En este trabajo se presentan

  7. Influence of temperature on corrosion rate and porosity of corrosion products of carbon steel in anoxic bentonite environment

    International Nuclear Information System (INIS)

    Stoulil, J.; Kaňok, J.; Kouřil, M.; Parschová, H.; Novák, P.

    2013-01-01

    Highlights: •The corrosion rate is not significantly dependent on temperature. •Corrosion products at higher temperatures have different color. •Corrosion products at higher temperatures are more compact. •The change in corrosion products nature is reversible. -- Abstract: The study focuses on the porosity of layers of corrosion products and its impact on corrosion rate of carbon steel in moist bentonite. Measurements were performed in an aggressive Czech type of bentonite – Rokle B75 at temperatures of 90 and 40 °C. Aggressiveness of B75 bentonite consists in low content of chlorides. Presence of chlorides in pore solution allows formation of more protective magnetite. The evaluation was made by electrochemical techniques (red/ox potential, open circuit potential, linear polarization resistance, impedance spectroscopy) and resistometric sensor measurements. The result imply that the higher the temperature the more compact is the layer of corrosion products that slightly decelerates corrosion rate compared to the state at 40 °C. The state of corrosion products at both temperatures is reversible

  8. Influence of temperature on corrosion rate and porosity of corrosion products of carbon steel in anoxic bentonite environment

    Energy Technology Data Exchange (ETDEWEB)

    Stoulil, J., E-mail: jan.stoulil@vscht.cz [Department of Metals and Corrosion Engineering, Institute of Chemical Technology, Prague (Czech Republic); Kaňok, J.; Kouřil, M. [Department of Metals and Corrosion Engineering, Institute of Chemical Technology, Prague (Czech Republic); Parschová, H. [Department of Power Engineering, Institute of Chemical Technology, Prague (Czech Republic); Novák, P. [Department of Metals and Corrosion Engineering, Institute of Chemical Technology, Prague (Czech Republic)

    2013-11-15

    Highlights: •The corrosion rate is not significantly dependent on temperature. •Corrosion products at higher temperatures have different color. •Corrosion products at higher temperatures are more compact. •The change in corrosion products nature is reversible. -- Abstract: The study focuses on the porosity of layers of corrosion products and its impact on corrosion rate of carbon steel in moist bentonite. Measurements were performed in an aggressive Czech type of bentonite – Rokle B75 at temperatures of 90 and 40 °C. Aggressiveness of B75 bentonite consists in low content of chlorides. Presence of chlorides in pore solution allows formation of more protective magnetite. The evaluation was made by electrochemical techniques (red/ox potential, open circuit potential, linear polarization resistance, impedance spectroscopy) and resistometric sensor measurements. The result imply that the higher the temperature the more compact is the layer of corrosion products that slightly decelerates corrosion rate compared to the state at 40 °C. The state of corrosion products at both temperatures is reversible.

  9. Corrosion and biofouling resistance evaluation of 90-10 copper-nickel

    Energy Technology Data Exchange (ETDEWEB)

    Powell, Carol [Consultant to Copper Development Association, UK, Square Covert, Caynham, Ludlow, Shropshire (United Kingdom)

    2004-07-01

    Copper-nickel alloys for marine use were developed for naval applications in the early part of the 20. century with a view to improving the corrosion resistance of condenser tubes and seawater piping. They still enjoy widespread use today not only for many navies but also in commercial shipping, floating production, storage and off loading vessels (FPSOs), and in multistage flash desalination. The two popular alloys contain 90% or 70% copper and differ in strength and maximum sea water velocity levels they can handle but it is the 90-10 copper-nickel (CuNi10Fe1Mn) which is the more economic and extensively used. An additional benefit of this alloy is its high resistance to biofouling: in recent years this has led to sheathing developments particularly for structures and boat hulls. This paper provides a review of the corrosion and biofouling resistance of 90-10 copper-nickel based on laboratory test data and documented experience of the alloy in marine environments. Particular attention is given to exposure trials over 8 years in Langstone Harbour, UK, which have recently been completed by Portsmouth University on behalf of the Nickel Institute. These examined four sheathing products; plate and foil as well as two composite products with rubber backing. The latter involved copper-nickel granules and slit sheet. The trial results are consistent with the behaviour of the alloy in the overall review. There is an inherent high resistance to marine biofouling when freely exposed. Prolonged exposure to quiet conditions can result in some growth of marine organisms but this is loosely attached and can readily be removed by wiping or a light scraping. The good corrosion resistance of 90-10 copper-nickel in sea water is also confirmed and associated with the formation of a thin, complex, protective and predominantly cuprous oxide surface film, which forms and matures naturally on exposure to seawater. Sound initial oxide film formation is also known to help protect against

  10. Loudspeaker Design and Performance Evaluation

    Science.gov (United States)

    Mäkivirta, Aki Vihtori

    A loudspeaker comprises transducers converting an electrical driving signal into sound pressure, an enclosure working as a holder for transducers, front baffle and box to contain and eliminate the rear-radiating audio signal, and electronic components. Modeling of transducers as well as enclosures is treated in Chap. 32 of this handbook. The purpose of the present chapter is to shed light on the design choices and options for the electronic circuits conditioning the electrical signal fed into loudspeaker transducers in order to optimize the acoustic performance of the loudspeaker.

  11. Timescale Correlation between Marine Atmospheric Exposure and Accelerated Corrosion Testing - Part 2

    Science.gov (United States)

    Montgomery, Eliza L.; Calle, Luz Marina; Curran, Jerome C.; Kolody, Mark R.

    2012-01-01

    Evaluation of metals to predict service life of metal-based structures in corrosive environments has long relied on atmospheric exposure test sites. Traditional accelerated corrosion testing relies on mimicking the exposure conditions, often incorporating salt spray and ultraviolet (UV) radiation, and exposing the metal to continuous or cyclic conditions similar to those of the corrosive environment. Their reliability to correlate to atmospheric exposure test results is often a concern when determining the timescale to which the accelerated tests can be related. Accelerated corrosion testing has yet to be universally accepted as a useful tool in predicting the long-term service life of a metal, despite its ability to rapidly induce corrosion. Although visual and mass loss methods of evaluating corrosion are the standard, and their use is crucial, a method that correlates timescales from accelerated testing to atmospheric exposure would be very valuable. This paper presents work that began with the characterization of the atmospheric environment at the Kennedy Space Center (KSC) Beachside Corrosion Test Site. The chemical changes that occur on low carbon steel, during atmospheric and accelerated corrosion conditions, were investigated using surface chemistry analytical methods. The corrosion rates and behaviors of panels subjected to long-term and accelerated corrosion conditions, involving neutral salt fog and alternating seawater spray, were compared to identify possible timescale correlations between accelerated and long-term corrosion performance. The results, as well as preliminary findings on the correlation investigation, are presented.

  12. Adsorption of alginate and albumin on aluminum coatings inhibits adhesion of Escherichia coli and enhances the anti-corrosion performances of the coatings

    Energy Technology Data Exchange (ETDEWEB)

    He, Xiaoyan; Liu, Yi; Huang, Jing; Chen, Xiuyong; Ren, Kun; Li, Hua, E-mail: lihua@nimte.ac.cn

    2015-03-30

    Graphical abstract: - Highlights: • Adsorption behaviors of alginate and albumin on Al coatings were investigated at molecular level. • The adsorption inhibits effectively the colonization of Escherichia coli bacteria. • The adsorption alters the wettability of the Al coatings. • The conditioning layer enhances anti-corrosion performances of the Al coatings. - Abstract: Thermal-sprayed aluminum coatings have been extensively used as protective layers against corrosion for steel structures in the marine environment. The corrosion usually deteriorates from marine biofouling, yet the mechanism of accelerated corrosion of the coatings remains elusive. As the first stage participating in biofouling process, adsorption of molecules plays critical roles in mediating formation of biofilm. Here, we report at molecular level the adsorption behaviors of albumin and marine polysaccharide on arc-sprayed aluminum coatings and their influence on adhesion of Escherichia coli. The adsorption of alginate and albumin was characterized by infrared spectra analyses and atomic force microscopic observation. The adsorption inhibits effectively adhesion of the bacteria. Further investigation indicates that alginate/albumin altered the hydrophilicity/hydrophobicity of the coatings instead of impacting the survival of the bacteria to decline their adhesion. The conditioning layer composed of the molecules enhances anti-corrosion performances of the coatings.

  13. Adsorption of alginate and albumin on aluminum coatings inhibits adhesion of Escherichia coli and enhances the anti-corrosion performances of the coatings

    International Nuclear Information System (INIS)

    He, Xiaoyan; Liu, Yi; Huang, Jing; Chen, Xiuyong; Ren, Kun; Li, Hua

    2015-01-01

    Graphical abstract: - Highlights: • Adsorption behaviors of alginate and albumin on Al coatings were investigated at molecular level. • The adsorption inhibits effectively the colonization of Escherichia coli bacteria. • The adsorption alters the wettability of the Al coatings. • The conditioning layer enhances anti-corrosion performances of the Al coatings. - Abstract: Thermal-sprayed aluminum coatings have been extensively used as protective layers against corrosion for steel structures in the marine environment. The corrosion usually deteriorates from marine biofouling, yet the mechanism of accelerated corrosion of the coatings remains elusive. As the first stage participating in biofouling process, adsorption of molecules plays critical roles in mediating formation of biofilm. Here, we report at molecular level the adsorption behaviors of albumin and marine polysaccharide on arc-sprayed aluminum coatings and their influence on adhesion of Escherichia coli. The adsorption of alginate and albumin was characterized by infrared spectra analyses and atomic force microscopic observation. The adsorption inhibits effectively adhesion of the bacteria. Further investigation indicates that alginate/albumin altered the hydrophilicity/hydrophobicity of the coatings instead of impacting the survival of the bacteria to decline their adhesion. The conditioning layer composed of the molecules enhances anti-corrosion performances of the coatings

  14. Strain-Annealing Based Grain Boundary Engineering to Evaluate its Sole Implication on Intergranular Corrosion in Extra-Low Carbon Type 304L Austenitic Stainless Steel

    Science.gov (United States)

    Pradhan, S. K.; Bhuyan, P.; Kaithwas, C.; Mandal, Sumantra

    2018-07-01

    Strain-annealing based thermo-mechanical processing has been performed to promote grain boundary engineering (GBE) in an extra-low carbon type austenitic stainless steel without altering the grain size and residual strain to evaluate its sole influence on intergranular corrosion. Single-step processing comprising low pre-strain ( 5 and 10 pct) followed by annealing at 1273 K for 1 hour have resulted in a large fraction of Σ3 n boundaries and significant disruption in random high-angle grain boundaries (RHAGBs) connectivity. This is due to the occurrence of prolific multiple twinning in these specimens as confirmed by their large twin-related domain and twin-related grain size ratio. Among the iterative processing, the schedule comprising two cycles of 10 and 5 pct deformation followed by annealing at 1173 K for 1 hour has yielded the optimum GBE microstructure with the grain size and residual strain akin to the as-received condition. The specimens subjected to the higher number of iterations failed to realize GBE microstructures due to the occurrence of partial recrystallization. Owing to the optimum grain boundary character distribution, the GBE specimen has exhibited remarkable resistance against sensitization and intergranular corrosion as compared to the as-received condition. Furthermore, the lower depth of percolation in the GBE specimen is due to the significant disruption of RHAGBs connectivity as confirmed from its large twin-related domain and lower fractal dimension.

  15. Evaluation channel performance in multichannel environments

    NARCIS (Netherlands)

    Gensler, S.; Dekimpe, M.; Skiera, B.

    2007-01-01

    Evaluating channel performance is crucial for actively managing multiple sales channels, and requires understanding the customers' channel preferences. Two key components of channel performance are (i) the existing customers' intrinsic loyalty to a particular channel and (ii) the channel's ability

  16. Model Performance Evaluation and Scenario Analysis (MPESA)

    Science.gov (United States)

    Model Performance Evaluation and Scenario Analysis (MPESA) assesses the performance with which models predict time series data. The tool was developed Hydrological Simulation Program-Fortran (HSPF) and the Stormwater Management Model (SWMM)

  17. Performance evaluation of Louisiana superpave mixtures.

    Science.gov (United States)

    2008-12-01

    This report documents the performance of Louisiana Superpave mixtures through laboratory mechanistic tests, mixture : volumetric properties, gradation analysis, and early field performance. Thirty Superpave mixtures were evaluated in this : study. Fo...

  18. Performance evaluation of ventilation radiators

    International Nuclear Information System (INIS)

    Myhren, Jonn Are; Holmberg, Sture

    2013-01-01

    A ventilation radiator is a combined ventilation and heat emission unit currently of interest due to its potential for increasing energy efficiency in exhaust-ventilated buildings with warm water heating. This paper presents results of performance tests of several ventilation radiator models conducted under controlled laboratory conditions. The purpose of the study was to validate results achieved by Computational Fluid Dynamics (CFD) in an earlier study and identify possible improvements in the performance of such systems. The main focus was on heat transfer from internal convection fins, but comfort and health aspects related to ventilation rates and air temperatures were also considered. The general results from the CFD simulations were confirmed; the heat output of ventilation radiators may be improved by at least 20% without sacrificing ventilation efficiency or thermal comfort. Improved thermal efficiency of ventilation radiators allows a lower supply water temperature and energy savings both for heating up and distribution of warm water in heat pumps or district heating systems. A secondary benefit is that a high ventilation rate can be maintained all year around without risk for cold draught. -- Highlights: ► Low temperature heat emitters are currently of interest due to their potential for increasing energy efficiency. ► A ventilation radiator is a combined ventilation and heat emission unit which can be adapted to low temperature heating systems. ► We examine how ventilation radiators can be made to be more efficient in terms of energy consumption and thermal comfort. ► Current work focuses on heat transfer mechanisms and convection fin configuration of ventilation radiators

  19. Evaluation of some phenothiazine derivatives as corrosion inhibitors for bronze in weakly acidic solution

    International Nuclear Information System (INIS)

    Bostan, Roxana; Varvara, Simona; Găină, Luiza; Mureşan, Liana Maria

    2012-01-01

    Highlights: ► Phenothiazine derivatives are efficient inhibitors for bronze corrosion. ► Potentiodynamic polarization and EIS were used to elucidate inhibition mechanism. ► Adsorption of phenothiazine derivatives on bronze surface obeys Langmuir isotherm. ► A correlation between energy gaps and inhibition efficiencies values was obtained. - Abstract: Four phenothiazine derivatives have been tested as inhibitors for bronze corrosion in a solution containing Na 2 SO 4 and NaHCO 3 (pH 5). Electrochemical investigations (potentiodynamic polarisation and impedance measurements) revealed that all phenothiazine derivatives exert a protective effect against bronze corrosion and, in some cases their inhibition efficiency exceeds 90% at concentration level as low as 75 μM. An adherent layer of organic molecules chemisorbed on bronze surface is responsible for the protective effect of the investigated compounds. Adsorption of phenothiazine derivatives on bronze obeys Langmuir isotherm. Correlation between quantum chemical calculations and inhibition efficiency of the investigated compounds was discussed using DFT method.

  20. Zn-ZrO{sub 2} nanocomposite coatings: Elecrodeposition and evaluation of corrosion resistance

    Energy Technology Data Exchange (ETDEWEB)

    Vathsala, Kanagalasara, E-mail: vathsala.mahesh@gmail.com [Department of Studies in Chemistry, School of Chemical Sciences, Kuvempu University, Shankaraghatta-577451, Karnataka (India); Venkatesha, Thimmappa Venkatarangaiah, E-mail: drtvvenkatesha@yahoo.co.uk [Department of Studies in Chemistry, School of Chemical Sciences, Kuvempu University, Shankaraghatta-577451, Karnataka (India)

    2011-08-15

    The Zn and Zn-ZrO{sub 2} composite coatings were produced by electrodeposition technique using sulphate bath. ZrO{sub 2} particles were characterized using scanning electron microscopy (SEM) and X-ray diffraction (XRD). The ZrO{sub 2} particle size distribution in the plating bath and Zeta potential and the ZrO{sub 2} were measured using dynamic light scattering technique (DLS). The corrosion resistance properties of Zn and Zn-ZrO{sub 2} composite coatings were compared by examining the experimental data acquired through polarization, open circuit potential (OCP) and Tafel measurements. The corrosion environment was 3.5 wt% NaCl solution. The variation of amount of ZrO{sub 2} in the solution on their % wt inclusion in the composite and on composite microhardness was investigated. XRD patterns were recorded for Zn and Zn-ZrO{sub 2} coatings to compare their grain size. The SEM images of coatings before and after corrosion under chemical and electrochemical conditions were presented. The results were analyzed to establish the superiority of Zn-ZrO{sub 2} composite over Zn coating.

  1. Electrochemical evaluation of corrosion and tribocorrosion behaviour of amorphous and nanocrystalline cobalt–tungsten electrodeposited coatings

    Energy Technology Data Exchange (ETDEWEB)

    Fathollahzade, N.; Raeissi, K., E-mail: k_raeissi@cc.iut.ac.ir

    2014-11-14

    Amorphous and nanocrystalline Co–W coatings were electrodeposited on copper substrates from a citrate–ammonia bath. The coatings showed nodular surface morphologies, but a microcrack network was detected in the amorphous coating. However, a better corrosion resistance was achieved for the amorphous coating. During sliding under open circuit potential (OCP) condition, the potential of amorphous coating gradually became more active probably due to the widening of wear scar, and thus expansion of active area. The amorphous coatings showed a higher volume loss at OCP probably due to its lower microhardness. In anodic sliding, a sharp increase in current density was observed due to mass transport and depassivation effects. In all sliding conditions, the proportion of mass transport was higher than wear accelerated corrosion, which implied that the dissolution reaction of the coatings was mainly a mass-transport controlled process. The results also showed that the effect of sliding on degradation is more intense for the nanocrystalline coating. For both coatings, the formation of the superficial microcracks in the vicinity of wear scars indicating on a surface fatigue wear mechanism. - Highlights: • Mass-transport effect had higher proportion in tribocorrosion of Co–W coatings. • The major electrochemical-wear degradation was for the nanocrystalline coating. • The higher proportion of wear accelerated corrosion was for the amorphous coating. • Superficial microcracks were formed near scars due to the coatings brittleness.

  2. Evaluation of practicability of aluminosilicate additive fuel. Influence of aluminosilicate for reprocessing and corrosion of pellet

    International Nuclear Information System (INIS)

    Matsunaga, Junji; Kashibe, Shinji; Kinoshita, Mika; Ishimoto, Shinji; Harada, Kenichi

    2014-01-01

    Al-Si-O additive fuel is a modified pellet to improve the pellet-cladding interaction (PCI) resistance. This practicability assessment concerns the effect of Al-Si-O addition on the reprocessing and steam corrosion behavior. To address these concerns, a fuel dissolution test in nitric acid and a pellet corrosion test in humidified gas were carried out using the irradiated Al-Si-O additive fuel. Regardless of the Al-Si-O concentration, the dissolution rates of all Al-Si-O additive fuels were faster than that of the standard fuel. The morphology of the insoluble residue obtained from the irradiated Al-Si-O additive fuel could be considered as acceptable for retrieval by the clarification process using a conventional precipitation model. The corrosion resistance of the irradiated Al-Si-O additive fuel to high-temperature (at 1273 K) humidified gas was comparable to or better than that of the standard fuel. The result was interpreted as being due to a large grain size effect by Al-Si-O addition. (author)

  3. Aqueous Corrosion Rates for Waste Package Materials

    Energy Technology Data Exchange (ETDEWEB)

    S. Arthur

    2004-10-08

    The purpose of this analysis, as directed by ''Technical Work Plan for: Regulatory Integration Modeling and Analysis of the Waste Form and Waste Package'' (BSC 2004 [DIRS 171583]), is to compile applicable corrosion data from the literature (journal articles, engineering documents, materials handbooks, or standards, and national laboratory reports), evaluate the quality of these data, and use these to perform statistical analyses and distributions for aqueous corrosion rates of waste package materials. The purpose of this report is not to describe the performance of engineered barriers for the TSPA-LA. Instead, the analysis provides simple statistics on aqueous corrosion rates of steels and alloys. These rates are limited by various aqueous parameters such as temperature (up to 100 C), water type (i.e., fresh versus saline), and pH. Corrosion data of materials at pH extremes (below 4 and above 9) are not included in this analysis, as materials commonly display different corrosion behaviors under these conditions. The exception is highly corrosion-resistant materials (Inconel Alloys) for which rate data from corrosion tests at a pH of approximately 3 were included. The waste package materials investigated are those from the long and short 5-DHLW waste packages, 2-MCO/2-DHLW waste package, and the 21-PWR commercial waste package. This analysis also contains rate data for some of the materials present inside the fuel canisters for the following fuel types: U-Mo (Fermi U-10%Mo), MOX (FFTF), Thorium Carbide and Th/U Carbide (Fort Saint Vrain [FSVR]), Th/U Oxide (Shippingport LWBR), U-metal (N Reactor), Intact U-Oxide (Shippingport PWR, Commercial), aluminum-based, and U-Zr-H (TRIGA). Analysis of corrosion rates for Alloy 22, spent nuclear fuel, defense high level waste (DHLW) glass, and Titanium Grade 7 can be found in other analysis or model reports.

  4. Aqueous Corrosion Rates for Waste Package Materials

    International Nuclear Information System (INIS)

    Arthur, S.

    2004-01-01

    The purpose of this analysis, as directed by ''Technical Work Plan for: Regulatory Integration Modeling and Analysis of the Waste Form and Waste Package'' (BSC 2004 [DIRS 171583]), is to compile applicable corrosion data from the literature (journal articles, engineering documents, materials handbooks, or standards, and national laboratory reports), evaluate the quality of these data, and use these to perform statistical analyses and distributions for aqueous corrosion rates of waste package materials. The purpose of this report is not to describe the performance of engineered barriers for the TSPA-LA. Instead, the analysis provides simple statistics on aqueous corrosion rates of steels and alloys. These rates are limited by various aqueous parameters such as temperature (up to 100 C), water type (i.e., fresh versus saline), and pH. Corrosion data of materials at pH extremes (below 4 and above 9) are not included in this analysis, as materials commonly display different corrosion behaviors under these conditions. The exception is highly corrosion-resistant materials (Inconel Alloys) for which rate data from corrosion tests at a pH of approximately 3 were included. The waste package materials investigated are those from the long and short 5-DHLW waste packages, 2-MCO/2-DHLW waste package, and the 21-PWR commercial waste package. This analysis also contains rate data for some of the materials present inside the fuel canisters for the following fuel types: U-Mo (Fermi U-10%Mo), MOX (FFTF), Thorium Carbide and Th/U Carbide (Fort Saint Vrain [FSVR]), Th/U Oxide (Shippingport LWBR), U-metal (N Reactor), Intact U-Oxide (Shippingport PWR, Commercial), aluminum-based, and U-Zr-H (TRIGA). Analysis of corrosion rates for Alloy 22, spent nuclear fuel, defense high level waste (DHLW) glass, and Titanium Grade 7 can be found in other analysis or model reports

  5. Evaluation of the optoelectronic properties and corrosion behavior of Al2O3-doped ZnO films prepared by dc pulsed magnetron sputtering

    International Nuclear Information System (INIS)

    Zubizarreta, C; Berasategui, E G; Bayón, R; Barriga, J; Escobar Galindo, R; Barros, R; Gaspar, D; Nunes, D; Calmeiro, T; Martins, R; Fortunato, E

    2014-01-01

    The main requirements for transparent conducting oxide (TCO) films acting as electrodes are a high transmission rate in the visible spectral region and low resistivity. However, in many cases, tolerance to temperature and humidity exposure is also an important requirement to be fulfilled by the TCOs to assure proper operation and durability. Besides improving current encapsulation methods, the corrosion resistance of the developed TCOs must also be enhanced to warrant the performance of optoelectronic devices. In this paper the performance of aluminum-doped zinc oxide (AZO) films deposited by pulsed dc magnetron sputtering has been studied. Structure, optical transmittance/reflectance, electrical properties (resistivity, carrier concentration and mobility) and corrosion resistance of the developed coatings have been analyzed as a function of the doping of the target and the coating thickness. Films grown from a 2.0 wt% Al 2 O 3 target with a thickness of approximately 1 µm showed a very low resistivity of 6.54  ×  10 –4  Ωcm and a high optical transmittance in the visible range of 84%. Corrosion studies of the developed samples have shown very low corrosion currents (nanoamperes), very high corrosion resistances (in the order of 10 7  Ω) and very high electrochemical stability, indicating no tendency for electrochemical corrosion degradation. (paper)

  6. Evaluation of the optoelectronic properties and corrosion behavior of Al2O3-doped ZnO films prepared by dc pulsed magnetron sputtering

    Science.gov (United States)

    Zubizarreta, C.; Berasategui, E. G.; Bayón, R.; Escobar Galindo, R.; Barros, R.; Gaspar, D.; Nunes, D.; Calmeiro, T.; Martins, R.; Fortunato, E.; Barriga, J.

    2014-12-01

    The main requirements for transparent conducting oxide (TCO) films acting as electrodes are a high transmission rate in the visible spectral region and low resistivity. However, in many cases, tolerance to temperature and humidity exposure is also an important requirement to be fulfilled by the TCOs to assure proper operation and durability. Besides improving current encapsulation methods, the corrosion resistance of the developed TCOs must also be enhanced to warrant the performance of optoelectronic devices. In this paper the performance of aluminum-doped zinc oxide (AZO) films deposited by pulsed dc magnetron sputtering has been studied. Structure, optical transmittance/reflectance, electrical properties (resistivity, carrier concentration and mobility) and corrosion resistance of the developed coatings have been analyzed as a function of the doping of the target and the coating thickness. Films grown from a 2.0 wt% Al2O3 target with a thickness of approximately 1 µm showed a very low resistivity of 6.54  ×  10-4 Ωcm and a high optical transmittance in the visible range of 84%. Corrosion studies of the developed samples have shown very low corrosion currents (nanoamperes), very high corrosion resistances (in the order of 107 Ω) and very high electrochemical stability, indicating no tendency for electrochemical corrosion degradation.

  7. Performance of surrogate high-level waste glass in the presence of iron corrosion products

    International Nuclear Information System (INIS)

    Jain, V.; Pan, Y.M.

    2004-01-01

    Radionuclide release from a waste package (WP) is a series of processes that depend upon the composition and flux of groundwater contacting the waste-forms (WF); the corrosion rate of WP containers and internal components made of Alloy 22, 316L SS, 304L SS and carbon steel; the dissolution rate of high-level radioactive waste (HLW) glass and spent nuclear fuel (SNF); the solubility of radionuclides; and the retention of radionuclides in secondary mineral phases. In this study, forward reaction rate measurements were made on a surrogate HLW glass in the presence of FeCl 3 species. Results indicate that the forward reaction rate increases with an increase in the FeCl 3 concentration. The addition of FeCl 3 causes the drop in the pH due to hydrolysis of Fe 3+ ions in the solution. Results based on the radionuclide concentrations and dissolution rates for HLW glass and SNF indicate that the contribution from glass is similar to SNF at 75 deg C. (authors)

  8. Manufacture and evaluation of integrated metal-oxide electrode prototype for corrosion monitoring in high temperature water

    International Nuclear Information System (INIS)

    Hashimoto, Yoshinori; Tani, Jun-ichi

    2014-01-01

    We have developed an integrated metal-oxide (M/O) electrode based on an yttria-stabilized-zirconia-(YSZ)-membrane M/O electrode, which was used as a reference electrode for corrosion monitoring in high temperature water. The YSZ-membrane M/O electrode can operate at high temperatures because of the conductivity of YSZ membrane tube. We cannot utilize it for long term monitoring at a wide range of temperatures. It also has a braze juncture between the YSZ membrane and metal tubes, which may corrode in high-temperature water. This corrosion should be prevented to improve the performance of the M/O electrode. An integrated M/O electrode was developed (i.e., integrated metal-oxide electrode, IMOE) to eliminate the braze juncture and increase the conductivity of YSZ. These issues should be overcome to improve the performance of M/O electrode. So we have developed two type of IMOE prototype with sputter - deposition or thermal oxidation. In this paper we will present and discuss the performance of our IMOEs in buffer solution at room temperature. (author)

  9. Laboratory study of reinforcement protection with corrosion inhibitors

    International Nuclear Information System (INIS)

    Stefanescu, D.; Mihalache, M.; Mogosan, S.

    2013-01-01

    Concrete is a durable material and its performance as part of the containment function in NPPs has been good. However, experience shows that degradation of the reinforced concrete structures caused by the corrosion of the reinforcing steel represents more than 80% of all damages in the world. Much effort has been made to develop a corrosion inhibition process to prolong the life of existing structures and minimize corrosion damages in new structures. Migrating Corrosion Inhibitor technology was developed to protect the embedded steel rebar/concrete structure. These inhibitors can be incorporated as an admixture or can be surface impregnated on existing concrete structures. The effectiveness of two inhibitors (ethanolamine and diethanolamine) mixed in the reinforced concrete was evaluated by gravimetric measurements. The corrosion behavior of the steel rebar and the inhibiting effects of the amino alcohol chemistry in an aggressive environment were monitored using electrochemical measurements and scanning electron microscopy (SEM) investigations. (authors)

  10. Corrosion of thin, magnetron sputtered Nb_2O_5 films

    International Nuclear Information System (INIS)

    Pillis, Marina Fuser; Geribola, Guilherme Altomari; Scheidt, Guilherme; Gonçalves de Araújo, Edval; Lopes de Oliveira, Mara Cristina; Antunes, Renato Altobelli

    2016-01-01

    Highlights: • Niobium oxide based films were obtained by DC magnetron sputtering. • Different deposition times were tested. • The best corrosion resistance was obtained for the Nb_2O_5 film produced at 15′. • Film porosity determines the corrosion resistance. - Abstract: Niobium oxide based thin films were deposited on AISI 316 stainless steel substrates using reactive DC magnetron sputtering. Structure, composition and corrosion resistance of the niobium oxide films were studied. The corrosion behavior of the specimens was evaluated by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization. The concentration of niobium and oxygen in the films was obtained by Rutherford backscattering spectroscopy (RBS). The film structure was analyzed by X-ray diffractometry. The corrosion resistance of the substrate was improved by the Nb_2O_5 layers. The best protective performance was achieved for the deposition time of 15 min.

  11. Methodology for quantitative evaluation of diagnostic performance

    International Nuclear Information System (INIS)

    Metz, C.

    1981-01-01

    Of various approaches that might be taken to the diagnostic performance evaluation problem, Receiver Operating Characteristic (ROC) analysis holds great promise. Further development of the methodology for a unified, objective, and meaningful approach to evaluating the usefulness of medical imaging procedures is done by consideration of statistical significance testing, optimal sequencing of correlated studies, and analysis of observer performance

  12. Effect of molybdate on phosphating of Nd-Fe-B magnets for corrosion protection

    Directory of Open Access Journals (Sweden)

    Adonis Marcelo Saliba-Silva

    2005-06-01

    Full Text Available Nd-Fe-B magnets are highly susceptible to corrosion and need protection against environment attack. The use of organic coatings is one of the main methods of corrosion protection of these materials. Data related to the effect of conversion coatings, such as phosphating, on corrosion performance of these magnets is still scarce. Studies about the effect of phosphating on the corrosion resistance of a commercial Nd-Fe-B sintered magnet indicated that it increases the corrosion resistance of these magnets, compared to non-phosphated magnets. In this study, the solution chemistry of a phosphating bath was altered with the addition of molybdate and its effect on the corrosion resistance of magnets investigated. Sintered magnet specimens were phosphated in solutions of 10 g/L NaH2PO4 (pH 3.8, either with or without molybdate [10-3 M MoO4(2-], to improve their corrosion resistance. The effect of phosphating time was also evaluated, and specimens were phosphated for 4 and 18 hours. To evaluate the corrosion performance of phosphated and unphosphated specimens, a corrosion test based on monitoring hydrogen evolution on the surface of the magnets was used. This technique revealed that the addition of molybdate to the phosphating solution improved the corrosion resistance of the magnets phosphated by immersion for short periods but had no beneficial effect if phosphated by immersion for longer periods.

  13. High temperature solution-nitriding and low-temperature nitriding of AISI 316: Effect on pitting potential and crevice corrosion performance

    DEFF Research Database (Denmark)

    Bottoli, Federico; Jellesen, Morten Stendahl; Christiansen, Thomas Lundin

    2018-01-01

    in a 0.1M NaCl solution and crevice corrosion immersion tests in 3wt% FeCl3 solution were studied before and after the bulk and surface treatments.Nitrogen addition in the bulk proved to have a beneficial effect on the pitting resistance of the alloy. The formation of a zone of expanded austenite...... at the material surface through low-temperature nitriding resulted in a considerable improvement of the pitting potential and the crevice corrosion performance of the steels....

  14. Microstructure Characterization and Stress Corrosion Evaluation of Autogenous and Hybrid Friction Stir Welded Al-Cu-Li 2195 Alloy

    Science.gov (United States)

    Li, Zhixian; Arbegast, William J.; Meletis, Efstathios I.

    1997-01-01

    Friction stir welding process is being evaluated for application on the Al-Cu-Li 2195 Super-Light Weight External Tank of the Space Transportation System. In the present investigation Al-Cu-Li 2195 plates were joined by autogenous friction stir welding (FSW) and hybrid FSW (friction stir welding over existing variable polarity plasma arc weld). Optical microscopy and transmission electron microscopy (TEM) were utilized to characterize microstructures of the weldments processed by both welding methods. TEM observations of autogenous FSW coupons in the center section of the dynamically-recrystallized zone showed an equiaxed recrystallized microstructure with an average grain size of approx. 3.8 microns. No T(sub 1), precipitates were present in the above-mentioned zone. Instead, T(sub B) and alpha precipitates were found in this zone with a lower population. Alternate immersion, anodic polarization, constant load, and slow strain tests were carried out to evaluate the general corrosion and stress-corrosion properties of autogenous and hybrid FSW prepared coupons. The experimental results will be discussed.

  15. The corrosion behavior of mild steel in molten NaNO3-KNO3 salt and its evaluation

    International Nuclear Information System (INIS)

    Tsujino, Bunzo; Oki, Takeo.

    1992-01-01

    The galvanic behavior of mild steel in molten NaNO 3 -KNO 3 salt (equivalent molar fraction) and its evaluation have been investigated by the amount of galvanic current with zero impedance ammeter. The galvanic currents in a galvanic couple consisting of mild steel and platinum so obtained corresponded approximately to the information for dissolution reaction of iron in molten NaNO 3 KNO 3 salt. Further, the galvanic currents proved to be an effective means for evaluating corrosion rate of metals in molten NaNO 3 KNO 3 salt. The effect of NaCl on galvanic behavior of mild steel couple to platinum in molten NaNO 3 -KNO 3 salt did not appear at the NaCl concentration up to 0.05 molar fraction, but the effect appeared as localized corrosion at the NaCl concentration of 0.05 molar fraction or more. The coloration for mild steel due to the oxide film was well controlled by adjusting amount of electricity rather than the temperature. (author)

  16. Evaluation of long-term corrosion durability and self-healing ability of scratched coating systems on carbon steel in a marine environment

    Science.gov (United States)

    Zhao, Xia; Chen, Changwei; Xu, Weichen; Zhu, Qingjun; Ge, Chengyue; Hou, Baorong

    2017-09-01

    Defects in protective-coating systems on steel surfaces are inevitable in practical engineering applications. A composite coating system, including a primer, middle coat and topcoat, were used to protect carbon steel from corrosion in a marine environment. Two environmental additives, glass fibers and thiourea, were applied in the middle coat to modify the coating system. The long-term corrosion durability and self-healing ability of the scratched coating system were evaluated by multiple methods. Results of the electrochemical technologies indicated that the coating system that contained 0.5 wt.% fibers and 0.5 wt.% thiourea presented good corrosion protection and self-healing for carbon steel when immersed in 3.5% NaCl for 120 d. Evolution of localized corrosion factors with time, as obtained from the current distribution showed that fibers combined with thiourea could inhibit the occurrence of local corrosion in scratched coating systems and retarded the corrosion development significantly. Surface characterization suggested that adequate thiourea could be absorbed uniformly on fibers for a long time to play an important role in protecting the carbon steel. Finally, schematic models were established to demonstrate the action of fibers and thiourea on the exposed surface of the carbon steel and the scratched coating system in the entire deterioration process.

  17. PERFORMANCE EVALUATION: LITERATURE REVIEW AND TIME EVOLUTION.

    Directory of Open Access Journals (Sweden)

    Pintea Mirela-Oana

    2012-07-01

    Full Text Available Performance evaluation of an economic entity requires approaching several criteria, such as industry and economic entity type, managerial and entrepreneurial strategy, competitive environment, human and material resources available, using a system of appropriate performance indicators for this purpose.The exigencies of communication occurred on the growing number of phenomena that marked the global economy in recent decades (internationalization and relocation of business crises and turmoil in financial markets, demand performance measurement to be made in a comprehensive way by financial and non-financial criteria. Indicators are measures of performance used by management to measure, report and improve performance of the economic entity. The relationship between indicators and management is ensured by the existence of performance measurement systems. Studies to date indicate that economic entities using balanced performance measurement systems as a key management tool registered superior performance compared to entities not using such systems. This study attempts to address the issue of performance evaluation by presenting opinions of different authors concerning the process of performance measurement and to present, after revising the literature, the evolution of the performance evaluation systems. We tried to do this literature review because sustainable development and, therefore, globalization require new standards of performance that exceeds the economic field, both for domestic companies as well as international ones. So, these standards should be integrated into corporate strategy development to ensure sustainability of activities undertaken by harmonizing the economic, social and environmental objectives. To assess the performance of economic entities it is required that performance evaluation to be done with a balanced multidimensional system, including both financial ratios and non-financial indicators in order to reduce the limits of

  18. Experiments for evaluation of corrosion to develop storage criteria for interim dry storage of aluminum-alloy clad spent nuclear fuel

    International Nuclear Information System (INIS)

    Peacock, H.B.; Sindelar, R.L.; Lam, P.S.; Murphy, T.H.

    1994-01-01

    The technical bases for specification of limits to environmental exposure conditions to avoid excessive degradation are being developed for storage criteria for dry storage of highly-enriched, aluminum-clad spent nuclear fuels owned by the US Department of Energy. Corrosion of the aluminum cladding is a limiting degradation mechanism (occurs at lowest temperature) for aluminum exposed to an environment containing water vapor. Attendant radiation fields of the fuels can lead to production of nitric acid in the presence of air and water vapor and would exacerbate the corrosion of aluminum by lowering the pH of the water solution. Laboratory-scale specimens are being exposed to various conditions inside an autoclave facility to measure the corrosion of the fuel matrix and cladding materials through weight change measurements and metallurgical analysis. In addition, electrochemical corrosion tests are being performed to supplement the autoclave testing by measuring differences in the general corrosion and pitting corrosion behavior of the aluminum cladding alloys and the aluminum-uranium fuel materials in water solutions

  19. Characterization of Encapsulated Corrosion Inhibitors Containing Microparticles for Environmentally Friendly Smart Coatings

    Science.gov (United States)

    Pearman, Benjamin Pieter; Calle, Luz M.

    2015-01-01

    This poster presents the results obtained from experiments designed to evaluate the release properties, as well as the corrosion inhibition effectiveness, of several encapsulated corrosion inhibitors. Microencapsulation has been used in the development of environmentally friendly multifunctional smart coatings. This technique enables the incorporation of autonomous corrosion detection, inhibition and self-healing functionalities into many commercially available coating systems. Select environmentally friendly corrosion inhibitors were encapsulated in organic and inorganic pH-sensitive microparticles and their release in basic solutions was studied. The release rate results showed that the encapsulation can be tailored from fast, for immediate corrosion protection, to slow, which will provide continued long-term corrosion protection. The incorporation of several corrosion inhibitor release profiles into a coating provides effective corrosion protection properties. To investigate the corrosion inhibition efficiency of the encapsulated inhibitors, electrochemical techniques were used to obtain corrosion potential, polarization curve and polarization resistance data. These measurements were performed using the free as well as the encapsulated inhibitors singly or in combinations. Results from these electrochemical tests will be compared to those obtained from weight loss and other accelerated corrosion experiments.

  20. Effect Mo Addition on Corrosion Property and Sulfide Stress Cracking Susceptibility of High Strength Low Alloy Steels

    International Nuclear Information System (INIS)

    Lee, Woo Yong; Koh, Seong Ung; Kim, Kyoo Young

    2005-01-01

    The purpose of this work is to understand the effect of Mo addition on SSC susceptibility of high strength low alloy steels in terms of microstructure and corrosion property. Materials used in this study are high strength low alloy (HSLA) steels with carbon content of 0.04wt% and Mo content varying from 0.1 to 0.3wt%. The corrosion property of steels was evaluated by immersion test in NACE-TM01-77 solution A and by analyzing the growth behavior of surface corrosion products. SSC resistance of steels was evaluated using constant load test. Electrochemical test was performed to investigate initial corrosion rate. Addition of Mo increased corrosion rate of steels by enhancing the porosity of surface corrosion products. however, corrosion rate was not directly related to SSC susceptibility of steels

  1. Evaluation of some non-toxic thiadiazole derivatives as bronze corrosion inhibitors in aqueous solution

    International Nuclear Information System (INIS)

    Varvara, Simona; Muresan, Liana Maria; Rahmouni, Kamal; Takenouti, Hisasi

    2008-01-01

    The inhibiting effect of four innoxious thiadiazole derivatives (2-mercapto-5-amino-1,3,4-thiadiazole (MAT), 2-mercapto-5-acetylamino-1,3,4-thiadiazole (MAcAT), 2-mercapto-5-methyl-1,3,4-thiadiazole (MMeT) and 2-mercapto-5-phenylamino-1,3,4-thiadiazole (MPhAT)) on bronze corrosion in an aerated solution of 0.2 g L -1 Na 2 SO 4 + 0.2 g L -1 NaHCO 3 at pH 5 was studied by potentiodynamic voltammetry and electrochemical impedance spectroscopy. The corrosion parameters determined from the polarisation curves indicate that the addition of the investigated thiadiazole derivatives decreases both cathodic and anodic current densities, due to an inhibition of the corrosion process, through the adsorption of thiadiazoles on the bronze surface. The inhibiting effect of the investigated organic compounds appears to be more pronounced on the anodic process than on the cathodic one and, except for the case MPhAT, it is enhanced by the increases of the inhibitors' concentration. The adsorption of the thiadiazole derivatives on bronze was confirmed by the presence of the nitrogen atoms in the EDX spectra of the bronze exposed to inhibitor-containing solutions. The magnitude of polarisation resistance values and, consequently, the inhibition efficiencies are influenced by the molecular structure of thiadiazole derivatives. The strongest inhibition was noticed in the presence of compounds with phenyl amino- or amino-functionalities in their molecules. The maximum protection efficiencies were obtained by addition of: 5 mM MAT (95.9%), 1 mM MAcAT (95.7%), 5 mM MMeT (92.6%) and 0.1 mM MPhAT (97%). EIS measurements also revealed that the inhibitor effectiveness of the optimal concentrations of thiadiazole is time-dependent

  2. Evaluation of some non-toxic thiadiazole derivatives as bronze corrosion inhibitors in aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Varvara, Simona [Department of Topography, ' 1 Decembrie 1918' University, 11-13 Nicolae Iorga Street, 510009 Alba Iulia (Romania); Muresan, Liana Maria [Department of Physical Chemistry, ' Babes-Bolyai' University, 11 Arany-Janos Street, 400028 Cluj-Napoca (Romania)], E-mail: limur@chem.ubbcluj.ro; Rahmouni, Kamal; Takenouti, Hisasi [UPMC LISE - UPR 15 of the CNRS, ' Pierre and Marie Curie' University, Paris (France)

    2008-09-15

    The inhibiting effect of four innoxious thiadiazole derivatives (2-mercapto-5-amino-1,3,4-thiadiazole (MAT), 2-mercapto-5-acetylamino-1,3,4-thiadiazole (MAcAT), 2-mercapto-5-methyl-1,3,4-thiadiazole (MMeT) and 2-mercapto-5-phenylamino-1,3,4-thiadiazole (MPhAT)) on bronze corrosion in an aerated solution of 0.2 g L{sup -1} Na{sub 2}SO{sub 4} + 0.2 g L{sup -1} NaHCO{sub 3} at pH 5 was studied by potentiodynamic voltammetry and electrochemical impedance spectroscopy. The corrosion parameters determined from the polarisation curves indicate that the addition of the investigated thiadiazole derivatives decreases both cathodic and anodic current densities, due to an inhibition of the corrosion process, through the adsorption of thiadiazoles on the bronze surface. The inhibiting effect of the investigated organic compounds appears to be more pronounced on the anodic process than on the cathodic one and, except for the case MPhAT, it is enhanced by the increases of the inhibitors' concentration. The adsorption of the thiadiazole derivatives on bronze was confirmed by the presence of the nitrogen atoms in the EDX spectra of the bronze exposed to inhibitor-containing solutions. The magnitude of polarisation resistance values and, consequently, the inhibition efficiencies are influenced by the molecular structure of thiadiazole derivatives. The strongest inhibition was noticed in the presence of compounds with phenyl amino- or amino-functionalities in their molecules. The maximum protection efficiencies were obtained