WorldWideScience

Sample records for corrosion current density

  1. Effect of current density on the microstructure and corrosion resistance of microarc oxidized ZK60 magnesium alloy.

    Science.gov (United States)

    You, Qiongya; Yu, Huijun; Wang, Hui; Pan, Yaokun; Chen, Chuanzhong

    2014-09-01

    The application of magnesium alloys as biomaterials is limited by their poor corrosion behavior. Microarc oxidation (MAO) treatment was used to prepare ceramic coatings on ZK60 magnesium alloys in order to overcome the poor corrosion resistance. The process was conducted at different current densities (3.5 and 9.0 A/dm(2)), and the effect of current density on the process was studied. The microstructure, elemental distribution, and phase composition of the MAO coatings were characterized by scanning electron microscopy, energy-dispersive x-ray spectrometry, and x-ray diffraction, respectively. The increment of current density contributes to the increase of thickness. A new phase Mg2SiO4 was detected as the current density increased to 9.0 A/dm(2). A homogeneous distribution of micropores could be observed in the coating produced at 3.5 A/dm(2), while the surface morphology of the coating formed at 9.0 A/dm(2) was more rough and apparent microcracks could be observed. The coating obtained at 3.5 A/dm(2) possessed a better anticorrosion behavior.

  2. Effects of Duty Cycle, Current Frequency, and Current Density on Corrosion Behavior of the Plasma Electrolytic Oxidation Coatings on 6061 Al Alloy in Artificial Seawater

    Science.gov (United States)

    Vakili-Azghandi, Mojtaba; Fattah-alhosseini, Arash

    2017-10-01

    In this study, the effects of duty cycle, current frequency, and current density on corrosion behavior of the plasma electrolytic oxidation (PEO) coatings on 6061 Al alloy in artificial seawater (3.5 wt pct NaCl solution) were investigated. To serve this purpose, the electrical parameters of a unipolar pulsed current were applied during the PEO process on 6061 Al alloy in alkaline silicate electrolyte with and without Al2O3 nanoparticles. The coating morphology and microstructure were characterized by the scanning electron microscopy. The corrosion behavior and electrochemical response of the specimens treated by plasma electrolytic oxidation were analyzed by the electrochemical impedance spectroscopy and the potentiodynamic polarization in artificial seawater. It was found that PEO coatings formed in the presence of Al2O3 nanoparticle had lower porosity and exhibited better corrosion behavior compared with the coatings formed in the absence of Al2O3 nanoparticle in the structure. This can be attributed to the nanoparticles' incorporation and penetration through the PEO coatings. On the other hand, the decrease in the current density and increases in the duty cycle and frequency lead to further reduction of the nanoparticles' incorporation and distribution on the coating surface.

  3. Effects of gadolinium content in the Gd-doped UO{sub 2} pellet on the corrosion current density

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jandee; Lee, Jeongmook; Yoon, Young-Sang; Kim, Jong-Goo; Ha, Yeong-Keong; Bae, Sang-Eun; Kim, Jong-Yun [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Liu, Nazhen [Western University, London (Canada)

    2015-10-15

    Container failure is not expected, since model calculations predict a loss of wall thickness by general corrosion of only a few microns. However, it can be assumed that some containers will fail allowing groundwater to contact the fuel causing radionuclide release. Because the majority of the radio nuclides in used fuel are located within the oxide matrix, their release rate to the groundwater will be controlled by the fuel corrosion/dissolution rate. In determining fuel corrosion and radionuclide release rates, the reactivity of the UO{sub 2} matrix and how it is modified by prior irradiation, is important. The one of the important changes expected to influence the reactivity of the fuel is the rare earth doping of UO{sub 2} which will change the conductivity and structural properties of the UO{sub 2} matrix. In this work, UO{sub 2} and Gd doped UO{sub 2} pellets were prepared and investigated to study about influences of trivalent rare earth of Gd(III) doped UO{sub 2} on corrosion and dissolution rates. Gd doped UO{sub 2} pellets are prepared by compress the Gd{sub 2}O{sub 3} and UO{sub 2} mixed powder following sinter at high temperature in reducing mood. The reproducibility of pellets preparation has been verified by observing resistivity of pellets using 4-probe method. The effect of Gd doping (0 to 10 mol% of Gd) on the electrochemical behavior of UO{sub 2} has been investigated in slightly alkaline solutions with carbonate.

  4. Corrosion of high-density sintered tungsten alloys. Part 3

    International Nuclear Information System (INIS)

    Batten, J.J.; Bombaci, S.A.; Garrard, W.N.C.; Moore, B.T.; Smith, B.S.

    1988-12-01

    The corrosion behaviour of tungsten and high-density tungsten alloys (W ≥ 90 weight %) has been examined electrochemically through anodic polarization measurements, instantaneous corrosion rate measurements, galvanic coupling, and surface potential mapping. In the anodic polarization tests, pure tungsten and the four alloys studied underwent transitions from an active state to a state where any further increase in potential produced no further increase in current. The presence of chloride ions increased corrosion rates. Predictions of likely trends in corrosion rates from the above electrochemical tests were not in complete agreement with those obtained by the long-term immersion tests. Similarly, a consistent prediction of the likely nature of the corrosion products that would result from long-term immersion testing was not obtained from the above studies. Predictions about which alloys would be susceptible to a crevice effect were in agreement with the immersion testing results, namely those alloys not containing Cu would be the most susceptible. Some insight into the nature of the corrosion mechanism is afforded by the work on galvanic coupling and surface potential mapping. This supported the view that galvanic corrosion plays a part in the corrosion process. 15 refs., 5 tabs., 19 figs

  5. Scattering length density profile of Ni film under controlled corrosion ...

    Indian Academy of Sciences (India)

    Abstract. We report the density depth profile of an as-deposited Ni film and density profile for the same film after controlled electrochemical corrosion by chloride ions, mea- sured by unpolarized neutron reflectometry. The neutron reflectometry measurement of the film after corrosion shows density degradation along the ...

  6. Scattering length density profile of Ni film under controlled corrosion ...

    Indian Academy of Sciences (India)

    We report the density depth profile of an as-deposited Ni film and density profile for the same film after controlled electrochemical corrosion by chloride ions, measured by unpolarized neutron reflectometry. The neutron reflectometry measurement of the film after corrosion shows density degradation along the thickness of ...

  7. Corrosion of high-density sintered tungsten alloys. Part 2

    International Nuclear Information System (INIS)

    Batten, J.J.; Moore, B.T.

    1988-12-01

    The behaviour of four high-density sintered tungsten alloys has been evluated and compared with that of pure tungsten. Rates of corrosion during the cyclic humidity and the salt mist tests were ascertained from weight loss measurements. Insight into the corrosion mechanism was gained from the nature of the corrosion products and an examination of the corroded surfaces. In the tests, the alloy 95% W, 2.5% Ni, 1.5% Fe was the most corrosion resistant. The data showed that copper as an alloying element accelerates corrosion of tungsten alloys. Both attack on the tungsten particles and the binder phase were observed together with tungsten grain loss. 6 refs., 3 tabs.,

  8. Current interruption by density depression

    International Nuclear Information System (INIS)

    Wagner, J.S.; Tajima, T.; Akasofu, S.I.

    1985-04-01

    Using a one-dimensional electrostatic particle code, we examine processes associated with current interruption in a collisionless plasma when a density depression is present along the current channel. Current interruption due to double layers was suggested by Alfven and Carlqvist (1967) as a cause of solar flares. At a local density depression, plasma instabilities caused by an electron current flow are accentuated, leading to current disruption. Our simulation study encompasses a wide range of the parameters in such a way that under appropriate conditions, both the Alfven and Carlqvist (1967) regime and the Smith and Priest (1972) regime take place. In the latter regime the density depression decays into a stationary structure (''ion-acoustic layer'') which spawns a series of ion-acoustic ''solitons'' and ion phase space holes travelling upstream. A large inductance of the current circuit tends to enhance the plasma instabilities

  9. Research on the influence of ac current overflowing on grounding electrode corrosion

    Science.gov (United States)

    Liu, Guohua; Wu, Zhen; Li, Wei; Zhang, Zhanlong; Mei, Daojun

    2017-09-01

    In the power system, earth electrode is laid in the soil for current overflowing, to ensure secure and stable operation of power grid and electric accessory. Compared with general pipeline laid in the soil, earth electrode is under the circumstance of unbalanced grounding current of neutral point and electric field induced by high-voltage transmission line, so there is current straightly overflowing from electrode surface to the earth. Grounding current density carried by earth electrode is large, with an important effect on electrochemical corrosion of earth electrode in the soil. Based on the established corrosion model, this paper makes research on the influence of AC current overflowing on corrosion potential, current and deformation, without considering the effect of species diffusion. What is more, the relationship between the amount of corrosion deformation and the frequency of ground current is also studied.

  10. Measurement of weak magnetic field of corrosion current of isolated corrosion center

    Directory of Open Access Journals (Sweden)

    I. V. Bardin

    2015-01-01

    Full Text Available A very small magnetic field of corrosion current, of the order of 10−4 Oe, generated by isolated zinc inclusion in a copper platelet placed in electrolyte has been measured for the first time with a highly sensitive giant magneto-impedance magnetometer. The total corrosion current of the inclusion is estimated comparing the measured magnetic field distribution with corresponding theoretical calculation. The estimated value of the total corrosion current turns out to be in reasonable agreement with that one obtained in the standard gravimetric measurement.

  11. NASA's Beachside Corrosion Test Site and Current Environmentally Friendly Corrosion Control Initiatives

    Science.gov (United States)

    Russell, Richard W.; Calle, Luz Marina; Johnston, Frederick; Montgomery, Eliza L.; Curran, Jerome P.; Kolody, Mark R.

    2013-01-01

    NASA began corrosion studies at the Kennedy Space Center (KSC) in 1966 during the Gemini/Apollo Programs with the evaluation of long-term corrosion protective coatings for carbon steel. KSC's Beachside Corrosion Test Site (BCTS), which has been documented by the American Society of Materials (ASM) as one of the most corrosive, naturally occurring, environments in the world, was established at that time. With the introduction of the Space Shuttle in 1981, the already highly corrosive conditions at the launch pad were rendered even more severe by the acid ic exhaust from the solid rocket boosters. In the years that followed, numerous studies have identified materials, coatings, and maintenance procedures for launch hardware and equipment exposed to the highly corrosive environment at the launch pad. This paper presents a historical overview of over 45 years of corrosion and coating evaluation studies and a description of the BCTS's current capabilities. Additionally, current research and testing programs involving chromium free coatings, environmentally friendly corrosion preventative compounds, and alternates to nitric acid passivation will be discussed.

  12. Monitoring dc stray current corrosion at sheet pile structures

    NARCIS (Netherlands)

    Peelen, W.H.A.; Neeft, E.A.C.; Leegwater, G.; Kanten-Roos, W. van; Courage, W.M.G.

    2012-01-01

    Steel is discarded by railway owners as a material for underground structures near railway lines, due to uncertainty over increased corrosion by DC stray currents stemming from the traction power system. This paper presents a large scale field test in which stray currents interference of a sheet

  13. Research on corrosion mechanism of suspension insulator steel foot of direct current system and measures for corrosion inhibition

    Science.gov (United States)

    Chen, He; Yang, Yueguang; Su, Guolei; Wang, Xiaoqing; Zhang, Hourong; Sun, Xiaoyu; Fan, Youping

    2017-09-01

    There are increasingly serious electrocorrosion phenomena on insulator hardware caused by direct current transmission due to the wide-range popularization of extra high voltage direct current transmission engineering in our country. Steel foot corrosion is the main corrosion for insulators on positive polarity side of transmission lines. On one hand, the corrosion leads to the tapering off of steel foot diameter, having a direct influence on mechanical property of insulators; on the other hand, in condition of corrosion on steel foot wrapped in porcelain ware, the volume of the corrosion product is at least 50% more than that of the original steel foot, leading to bursting of porcelain ware, threatening safe operation of transmission lines. Therefore, it is necessary to conduct research on the phenomenon and propose feasible measures for corrosion inhibition. Starting with the corrosion mechanism, this article proposes two measures for corrosion inhibition, and verifies the inhibition effect in laboratory conditions, providing reference for application in engineering.

  14. Corrosion behaviour of zinc deposits obtained under pulse current electrodeposition: Effects of coumarin as additive

    International Nuclear Information System (INIS)

    Mouanga, M.; Ricq, L.; Douglade, J.; Bercot, P.

    2009-01-01

    The corrosion behaviour of zinc deposits obtained under pulsed current electrodeposition from an acidic chloride bath in the presence and absence of coumarin has been investigated. The effects of pulse peak current density (J p ) on the morphology of zinc deposits were studied by scanning electron microscopy. An increase in J p from 40 to 280 A dm -2 yields deposits with a finer grain size. The refinement of the grain size was more considerable in the presence of coumarin (J p = 280 A dm -2 ). The preferred orientation of zinc deposits was studied by X-ray diffraction. At J p = 40 A dm -2 , the preferred orientation of zinc deposits was (1 0 3) and changed to (0 0 2) at J p = 80 A dm -2 . An increase in J p to 280 A dm -2 did not change the preferred crystallographic orientations except for an increase in the peak intensity of the (0 0 2) plane. In the presence of coumarin, the preferred crystallographic orientations changed at J p = 280 A dm -2 from the (0 0 2) plane to the (1 0 3) plane. The corrosion behaviour was investigated in an aerated 3.5% NaCl solution; the anodic polarization and electrochemical impedance spectroscopy curves were performed. The corrosion resistance of zinc deposits was improved by increasing the pulse peak current density (J p ); whereas, the presence of coumarin did not improve the corrosion resistance

  15. Corrosion of high-density sintered tungsten alloys. Part 1

    International Nuclear Information System (INIS)

    Batten, J.J.; McDonald, I.G.; Moore, B.T.; Silva, V.M.

    1988-10-01

    The corrosion behaviour of four tungsten alloys has been evaluated through weight loss measurements after total immersion in both distilled water insight into the mechanism of corrosion was afforded by an examination of the and 5% sodium chloride solutions. Some insight the mechanism of corrosion was afforded by using the Scanning Electron Microscopy and through an analysis of the corrosion products. Pure tungsten and all the alloys studied underwent corrosion during the tests, and in each case the rare of corrosion in sodium chloride solution was markedly less than that in distilled water. A 95% W, 3.5% Ni, 1.5% Fe alloy was found to be the most corrosion resistant of the alloys under the experimental conditions. Examination of the data shows that for each of the tests, copper as an alloying element accelerates corrosion of tungsten alloys. 9 refs., 7 tabs., 12 figs

  16. Measuring the corrosion rate of steel in concrete – effect of measurement technique, polarisation time and current

    DEFF Research Database (Denmark)

    Nygaard, Peter Vagn; Geiker, Mette Rica

    2012-01-01

    , are in some studies considered the main reasons for the variations. This paper presents an experimental study on the quantitative effect of polarisation time and current on the measured polarisation resistance – and thus the corrosion current density – of passively and actively corroding steel. Two...... electrochemical techniques often used in instruments for on-site corrosion rate measurements are investigated. On passively corroding reinforcement the measured polarisation resistance was for both techniques found to be highly affected by the polarisation time and current and no plateaus at either short or long......Both on-site investigations and laboratory studies have shown that different corrosion rates are obtained when different commercially available corrosion rate instruments are used. The different electrochemical techniques and the measurement parameters used, i.e. polarisation current and time...

  17. Stray current vs anodic polarization in reinforced mortar: a comparative study on steel corrosion behaviour in both regimes

    NARCIS (Netherlands)

    Chen, Zhipei; Koleva, D.A.; van Breugel, K.

    2015-01-01

    Stray current arising from direct current electrified traction systems and then circulat-ing in reinforced concrete structures may initiate corrosion or even accelerate existing corrosion processes on embedded reinforcement. Therefore, stray-current induced corrosion of nearby reinforced concrete

  18. Critical current densities in superconducting materials

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    Critical current density; superconducting materials; magnetic-field ... As current densities are raised to higher than JC the material does not go suddenly from the superconducting state to the normal resistive state, but develops a .... to the superconducting state with liquid nitrogen, but whose commercial exploitation has.

  19. Corrosion Protection Systems and Fatigue Corrosion in Offshore Wind Structures: Current Status and Future Perspectives

    Directory of Open Access Journals (Sweden)

    Seth J. Price

    2017-02-01

    Full Text Available Concerns over reducing CO2 emissions associated with the burning of fossil fuels in combination with an increase in worldwide energy demands is leading to increased development of renewable energies such as wind. The installation of offshore wind power structures (OWS is one of the most promising approaches for the production of renewable energy. However, corrosion and fatigue damage in marine and offshore environments are major causes of primary steel strength degradation in OWS. Corrosion can reduce the thickness of structural components which may lead towards fatigue crack initiation and buckling. These failure mechanisms affect tower service life and may result in catastrophic structural failure. Additionally, environmental pollution stemming from corrosion’s by-products is possible. As a result, large financial investments are made yearly for both the prevention and recovery of these drawbacks. The corrosion rate of an OWS is dependent on different characteristics of attack which are influenced by access to oxygen and humidity. Structural degradation can occur due to chemical attack, abrasive action of waves, and microorganism attacks. Inspired by technological and scientific advances in recent years, the purpose of this paper is to discuss the current protective coating system technologies used to protect OWS as well as future perspectives.

  20. Steam generator degradation: Current mitigation strategies for controlling corrosion

    International Nuclear Information System (INIS)

    Millett, P.

    1997-01-01

    Steam Generator degradation has caused substantial losses of power generation, resulted in large repair and maintenance costs, and contributed to significant personnel radiation exposures in Pressurized Water Reactors (PWRs) operating throughout the world. EPRI has just published the revised Steam Generator Reference Book, which reviews all of the major forms of SG degradation. This paper discusses the types of SG degradation that have been experienced with emphasis on the mitigation strategies that have been developed and implemented in the field. SG degradation is presented from a world wide perspective as all countries operating PWRs have been effected to one degree or another. The paper is written from a US. perspective where the utility industry is currently undergoing tremendous change as a result of deregulation of the electricity marketplace. Competitive pressures are causing utilities to strive to reduce Operations and Maintenance (O ampersand M) and capital costs. SG corrosion is a major contributor to the O ampersand M costs of PWR plants, and therefore US utilities are evaluating and implementing the most cost effective solutions to their corrosion problems. Mitigation strategies developed over the past few years reflect a trend towards plant specific solutions to SG corrosion problems. Since SG degradation is in most cases an economic problem and not a safety problem, utilities can focus their mitigation strategies on their unique financial situation. Accordingly, the focus of R ampersand D has shifted from the development of more expensive, prescriptive solutions (e.g. reduced impurity limits) to corrosion problems to providing the utilities with a number of cost effective mitigation options (e.g. molar ratio control, boric acid treatment)

  1. Probability density fittings of corrosion test-data: Implications on ...

    Indian Academy of Sciences (India)

    the use of corrosion inhibitor admixture in concrete had been identified as an easy, effective and economical ... for acceptable reduction in corrosion rate had been recommended by others. The American .... immersed, longitudinally, in plastic bowls containing respective test solution of aggressive agent. Each of the first ...

  2. Current density profile evolution in JET

    International Nuclear Information System (INIS)

    Stubberfield, P.M.; Balet, B.; Campbell, D.; Challis, C.D.; Cordey, J.G.; O'Rourke, J.; Hammett, G.; Schmidt, G.L.

    1989-01-01

    Simulation studies have been made of the current density profile evolution in discharges where the bootstrap current is expected to be significant. The changes predicted in the total current profile have been confirmed by comparison with experimental results. (author) 8 refs., 6 figs

  3. Current distribution tomography for determination of internal current density distributions

    International Nuclear Information System (INIS)

    Gailey, P.C.

    1993-01-01

    A method is presented for determination of current densities inside a cylindrical object using measurements of the magnetic fields outside the object. The cross section of the object is discretized with the current assumed constant over each defined region. Magnetic fields outside the object are related to the internal current densities through a geometry matrix which can be inverted to yield a solution for the current densities in terms of the measured fields. The primary limitation of this technique results from singularities in the geometry matrix that arise due to cylindrical symmetry of the problem. Methods for circumventing the singularities to obtain information about the distribution of current densities are discussed. This process of current distribution tomography is designed to determine internal body current densities using measurements of the external magnetic field distribution. It is non-invasive, and relatively simple to implement. Although related to a more general study of magnetic imaging which has been used to investigate endogenous currents in the brain and other parts of the body, it is restricted to currents either applied directly or induced by exposure to an external field. The research is related to public concern about the possibility of health effects resulting from exposure to power frequency electric and magnetic fields

  4. A review on stray current-induced steel corrosion in infrastructure

    NARCIS (Netherlands)

    Chen, Zhipei; Koleva, D.A.; van Breugel, K.

    2017-01-01

    Metallic corrosion can cause substantial damage at various levels and in almost all types of infrastructure. For metallic corrosion to occur, a certain external environment and the presence of corrodents are the prerequisites. Stray current-induced corrosion, however, is a rather underestimated

  5. Critical current densities in superconducting materials

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    at this field value, and the net pinning force remains large. The pinning force prevents the motion of vortices until the Lorentz force(J×B)exceeds the pinning force FP . This defines a critical current density JC = FP /B below which transport current is carried without any resistance, and above which flux-flow resistivity sets in.

  6. Corrosion

    Science.gov (United States)

    Slabaugh, W. H.

    1974-01-01

    Presents some materials for use in demonstration and experimentation of corrosion processes, including corrosion stimulation and inhibition. Indicates that basic concepts of electrochemistry, crystal structure, and kinetics can be extended to practical chemistry through corrosion explanation. (CC)

  7. A Galvanic Sensor for Monitoring the Corrosion Condition of the Concrete Reinforcing Steel: Relationship Between the Galvanic and the Corrosion Currents

    Directory of Open Access Journals (Sweden)

    Elsa Vaz Pereira

    2009-10-01

    Full Text Available This work reports a study carried out on the design and performance of galvanic and polarization resistance sensors to be embedded in concrete systems for permanent monitoring of the corrosion condition of reinforcing steel, aiming to establish a correlation between the galvanic currents, Igal, and the corrosion currents, Icorr, estimated from the polarization resistance, Rp. Sensors have been tested in saturated Ca(OH2 aqueous solutions, under a variety of conditions, simulating the most important parameters that can accelerate the corrosion of concrete reinforcing steel, such as carbonation, ingress of chloride ions, presence or absence of O2. For all the conditions, the influence of temperature (20 to 55 ºC has also been considered. From this study, it could be concluded that the galvanic currents are sensitive to the various parameters following a trend similar to that of the Rp values. A relationship between the galvanic and the corrosion current densities was obtained and the limiting values of the Igal, indicative of the state condition of the reinforcing steel for the designed sensor, were established.

  8. Field Testing of High Current Electrokinetic Nanoparticle Treatment for Corrosion Mitigation in Reinforced Concrete

    Science.gov (United States)

    Cardenas, Henry; Alexander, Joshua; Kupwade-Patil, Kunal; Calle, Luz marina

    2010-01-01

    Electrokinetic Nanoparticle (EN) treatment was used as a rapid repair measure to mitigate chloride induced corrosion of reinforced concrete in the field. EN treatment uses an electric field to transport positively charged nanoparticles to the reinforcement through the concrete capillary pores. Cylindrical reinforced concrete specimens were batched with 4.5 wt % salt content (based on cement mass). Three distinct electrokinetic treatments were conducted using high current density (up to 5 A/m2) to form a chloride penetration barrier that was established in 5 days, as opposed to the traditional 6-8 weeks, generally required for electrochemical chloride extraction (ECE). These treatments included basic EN treatment, EN with additional calcium treatment, and basic ECE treatment. Field exposures were conducted at the NASA Beachside Corrosion Test Site, Kennedy Space Center, Florida, USA. The specimens were subjected to sea water immersion at the test site as a posttreatment exposure. Following a 30-day post-treatment exposure period, the specimens were subjected to indirect tensile testing to evaluate treatment impact. The EN treated specimens exhibited 60% and 30% increases in tensile strength as compared to the untreated controls and ECE treated specimens respectively. The surfaces of the reinforcement bars of the control specimens were 67% covered by corrosion products. In contrast, the EN treated specimens exhibited corrosion coverage of only 4%. Scanning electron microscopy (SEM) revealed a dense concrete microstructure adjacent to the bars of the treated specimens as compared to the control and ECE specimens. Energy dispersive spectroscopic (EDS) analysis of the polished EN treated specimens showed a reduction in chloride content by a factor of 20 adjacent to the bars. This study demonstrated that EN treatment was successful in forming a chloride penetration barrier rapidly. This work also showed that the chloride barrier was effective when samples were exposed to

  9. Critical current densities in superconducting materials

    Indian Academy of Sciences (India)

    We discuss recent research in the area of critical current densities ( J C ) in superconductors. This shall cover recent work on newly discovered superconductors, as well as on the magnetic-field dependence of J C . Author Affiliations. P Chaddah1. Cryogenics and Superconductivity Section, Centre for Advanced Technology ...

  10. Surface current density K: an introduction

    DEFF Research Database (Denmark)

    McAllister, Iain Wilson

    1991-01-01

    The author discusses the vector surface of current density K used in electrical insulation studies. K is related to the vector tangential electric field Kt at the surface of a body by the vector equation K=ΓE t where Γ represents the surface conductivity. The author derives a surface continuity...

  11. Influence of Direct Current Electric Field on Corrosion Behavior of Tin Under a Thin Electrolyte Layer

    Science.gov (United States)

    Huang, H. L.; Bu, F. R.; Tian, J.; Liu, D.

    2017-12-01

    The influence of a direct current electric field (DCEF) on corrosion behavior of tin under a thin electrolyte layer was investigated based on an array electrode technology by polarization, electrochemical impedance spectroscopy and surface analysis. The experimental results indicate that the corrosion rate of tin near the positive plate of DCEF increases with increased electric field intensity, which could be attributed to the acceleration of the migration of ions, the removal of corrosion products under DCEF and the damage of tin surface oxide film. Furthermore, tin at different positions in a DCEF exhibits different corrosion behavior, which could be ascribed to the difference of the local corrosion environment caused by the DCEF.

  12. Probability density fittings of corrosion test-data

    Indian Academy of Sciences (India)

    In this study, corrosion test-data of steel-rebar in concrete were subjected to the fittings of the Normal, Gumbel and the Weibull probability distribution functions. This was done to investigate the suitability of the results of the fitted test-data, by these distributions, for modelling the effectiveness of C6H15NO3, triethanolamine ...

  13. Influence of alloying elements and density on aqueous corrosion behaviour of some sintered low alloy steels

    International Nuclear Information System (INIS)

    Kandavel, T.K.; Chandramouli, R.; Karthikeyan, P.

    2012-01-01

    Highlights: ► Corrosion of low alloy P/M steels under HCl acid pickling environment has been studied. ► Influence of density, strain and alloying elements on the rate of corrosion of the steels has been investigated. ► Residual porosity has significant effect on acid corrosion. ► Addition of the alloying elements Cu, Mo and Ti reduces the corrosion rate significantly. ► Carbide forming elements Mo and Ti improve further the resistance of the steels to aqueous corrosion. -- Abstract: Low alloy steels produced through powder metallurgy route of sintering followed by forging are promising candidate materials for high strength small components. Porosity in such steels poses a real challenge during acid pickling treatment, which is one of the processing steps during manufacturing. The present research work attempts to investigate the mechanism underlying the acid corrosion behaviour of some sintered low alloy steels under induced acid pickling conditions. Sintered-forged low alloy steel samples containing molybdenum (Mo), copper (Cu) and titanium (Ti) were subjected to aqueous corrosion attack by immersing the samples in 18% HCl (Hydrochloric acid) solution for 25 h. Sample weight loss and Fe (Iron) loss were estimated for the corroded samples. The morphology of the corroded surfaces was studied through metallography and scanning electron microscopy. Higher porosity alloys underwent enhanced corrosion rates. Both corrosion rate and iron loss are found to decrease linearly with reduction in porosity in all cases of the alloys. The alloying elements Mo, Ti and Cu, when added in combination, have played a complementary role in the reduction of corrosion rate by almost one order of magnitude compared to unalloyed steel. Presence of carbides of the carbide forming elements Mo and Ti played a positive role on the corrosion behaviour of the low alloy steels.

  14. Alternating current techniques for corrosion monitoring in water reactor systems

    International Nuclear Information System (INIS)

    Isaacs, H.S.; Weeks, J.R.

    1977-01-01

    Corrosion in both nuclear and fossil fueled steam generators is generally a consequence of the presence of aggressive impurities introduced into the coolant system through condenser leakage. The impurities concentrate in regions of the steam generator protected from coolant flow, in crevices or under deposited corrosion products and adjacent to heat transfer surfaces. These three factors, the aggressive impurity, crevice type areas and heat transfer surfaces appear to be the requirements for the onset of rapid corrosion. Under conditions where coolant impurities do not concentrate the corrosion rates are low, easily measured and can be accounted for by allowances in the design of the steam generator. Rapid corrosion conditions cannot be designed for and must be suppressed. The condition of the surfaces when rapid corrosion develops must be markedly different from those during normal operation and these changes should be observable using electrochemical techniques. This background formed the basis of a design of a corrosion monitoring device, work on which was initiated at BNL. The basic principles of the technique are described. The object of the work is to develop a corrosion monitoring device which can be operated with PWR steam generator secondary coolant feed water

  15. Direct current testing to measure corrosiveness of wood preservatives

    Science.gov (United States)

    Samuel L. Zelinka; Douglas R. Rammer; Donald S. Stone; James T. Gilbertson

    2007-01-01

    A qualitative test that mimics the corrosion behaviour of metals in contact with treated wood without using wood specimens would be of great value in rapidly evaluating the corrosiveness of new wood preservatives. The objective of this study was to determine whether the linear polarisation resistance of metals immersed in a solution of preservative chemicals is related...

  16. Current drive in high density tokamak plasma

    International Nuclear Information System (INIS)

    Sakaguchi, Seiichiro; Jotaki, Eriko; Kawasaki, Shoji; Moriyama, Shin-ichi; Nagao, Akihiro; Nakamura, Kazuo; Nakamura, Yukio; Hiraki, Naoki; Itoh, Satoshi

    1989-01-01

    Current drive in high density tokamak plasma is investigated, with special attention given to mode conversion and proximity conditions that characterize the propagation of electromagnetic waves in the case of current drive by lower hybrid waves. A simple model is used to evaluate the current drive efficiency, and its dependence on various parameters associated with equipment is investigated to provide information required in designing experimental equipment. A strong troidal magnetic field is necessary to produce high density plasma, and incident electromagnetic waves should have a high frequency to prevent the mode conversion, suggesting that a high frequency and a strong troidal field are essential to permit desirable propagation of incident electromagnetic waves. The evaluation of the current drive efficiency shows that the proximity conditions and the power spectrum of the lower hybrid waves entering the plasma are of importance. The average refraction factor in the direction of the troidal field should be larger than but close to that determined from the proximity conditions in order to increase the drive efficiency. As the intensity of the troidal field increases, the refraction factor determined from the proximity conditions decreases, leading to an increase in the drive efficiency. (N.K.)

  17. Field Testing of High Current Electrokinetic Nanoparticle Treatment for Corrosion Mitigation in Reinforced Concrete

    Science.gov (United States)

    Calle, Luz Marina; Alexander, Joshua B.; Cardenas, Henry E.; Kupwade-Patil, Kunal

    2008-01-01

    This work examines field performance of nanoscale pozzolan treatments delivered el ctrokinetically to suppress chloride induced corrosion of concrete reinforcement. The particles are 20 nm silica spheres coated with 2 nm alumina particles that carry a net positive charge. Earlier work demonstrated that the alumina particles were stripped from the silica carriers and formed a dense phase with an interparticle spacing that is small enough to inhibit the transport of solvated chlorides. A D.C. field was used to inject the particles into the pores of concrete specimens, directly toward the mild steel bars that were embedded within each 3 inch diameter by 6 inch length concrete specimen. The voltage was held constant at 25 v per inch of concrete cover for a period of 7 days. These voltages permitted current densities as high as 3 A/sq m. During the final 3 days, a 1 molar solution of calcium nitrate tetrahydrate was used to provide a source of calcium to facilitate stronger and more densified phase formation within the pores. In a departure from prior work the particle treatments were started concurrent with chloride extraction in order to determine if particle delivery would inhibit chloride transport. Following treatment the specimens were immersed in seawater for 4 weeks. After this posttreatment exposure, the specimens were tested for tensile strength and the steel reinforcement was examined for evidence of corrosion. Scanning electron microscopy was conducted to assess impact on microstructure.

  18. Scattering length density profile of Ni film under controlled corrosion ...

    Indian Academy of Sciences (India)

    the fundamental aspects of the mechanisms operating in the early stages of pitting. (leading to passivity breakdown ... The sample thickness was monitored by quartz crystal system during growth. The electrochemical ... system, N is the number density at a depth z and b is the coherent nuclear scat- tering length. From the ...

  19. Effect of areal power density and relative humidity on corrosion resistant container performance

    International Nuclear Information System (INIS)

    Gansemer, J.D.

    1994-10-01

    The impact of the rewetting process on the performance of waste containers at the Yucca Mountain repository is analyzed. This paper explores the impact of the temperature-humidity relationships on pitting corrosion failure of stainless steel containers for different areal power densities (APDs)in the repository. It compares the likely performance of containers in a repository with a low APD, 55 Kw/acre, and a high APD, 110 kW/acre

  20. The influence of current collector corrosion on the performance of electrochemical capacitors

    Science.gov (United States)

    Wojciechowski, Jarosław; Kolanowski, Łukasz; Bund, Andreas; Lota, Grzegorz

    2017-11-01

    This paper discusses the effect of current collector (stainless steel 316L) corrosion on the performance of electrochemical capacitors operated in aqueous electrolytes. This topic seems to be often neglected in scientific research. The studied electrolytes were 1 M H2SO4, 1 M KI, 1 M Na2SO4, 1 M KOH and 6 M KOH. The corrosion process was investigated by means of selected direct and alternating current techniques. The surface of the current collectors as well as the corrosion products were characterised using scanning electron microscopy, energy-dispersive X-ray spectroscopy, Raman spectroscopy and atomic force microscopy. Stainless steel 316L in alkaline solutions is characterised by the lowest values of corrosion potentials whereas the potentials in acidic media become the most noble. Our studies show that corrosion potentials increase with decreasing pH value. This phenomenon can be explained with the formation of passive oxide films on the stainless steel current collectors. The passive oxide films are usually thicker and more porous in alkaline solutions than that in the other electrolytes. The processes occurring at the electrode/electrolyte interfaces strongly influence the working parameters of electrochemical capacitors such as voltage, working potentials of single electrodes, self-discharge as well as the internal resistance and cycling stability.

  1. A degradation model for stray current induced corrosion in underground reinforced concrete structures

    NARCIS (Netherlands)

    Polder, R.B.; Peelen, W.H.A.

    2003-01-01

    This paper describes the effects of stray currents on durability and reinforcement corrosion of underground concrete structures. Cathodic protection of underground pipelines are stationary sources of stray current interference with concrete, and rail traction systems are non-stationary sources. The

  2. Current density in radiation stimulated superconductors

    International Nuclear Information System (INIS)

    Wafelbakker, C.K.

    1977-01-01

    Eliashberg's theory of stimulated superconductivity is reviewed and discussed within the BCS-Mattis formalism for impure superconductors. Stimulation by microwaves as well as by acoustical fields is considered. Eliashberg's results are completed by obtaining the nonequilibrium current response to an applied transverse vector potential. The resulting expression may be used to obtain the critical current of small specimens. (Auth.)

  3. Fast wave current drive above the slow wave density limit

    International Nuclear Information System (INIS)

    McWilliams, R.; Sheehan, D.P.; Wolf, N.S.; Edrich, D.

    1989-01-01

    Fast wave and slow wave current drive near the mean gyrofrequency were compared in the Irvine Torus using distinct phased array antennae of similar principal wavelengths, frequencies, and input powers. The slow wave current drive density limit was measured for 50ω ci ≤ω≤500ω ci and found to agree with trends in tokamaks. Fast wave current drive was observed at densities up to the operating limit of the torus, demonstrably above the slow wave density limit

  4. Influence of current density on microstructure and properties of electrodeposited nickel-alumina composite coatings

    International Nuclear Information System (INIS)

    Góral, Anna; Nowak, Marek; Berent, Katarzyna; Kania, Bogusz

    2014-01-01

    Highlights: • Current density of the electrodeposition affects the incorporation of Al 2 O 3 in Ni matrix. • Ni/Al 2 O 3 composite coatings exhibit changes in crystallographic texture. • The pitting corrosion effects were observed in Ni/Al 2 O 3 coatings. • Residual stresses were decreased with increasing current density and coating thickness. - Abstract: Electrodeposition process is a very promising method for producing metal matrix composites reinforced with ceramic particles. In this method insoluble particles suspended in an electrolytic bath are embedded in a growing metal layer. This paper is focused on the investigations of the nickel matrix nanocomposite coatings with hard α-Al 2 O 3 nano-particles, electrochemically deposited from modified Watts-type baths on steel substrates. The influence of various current densities on the microstructure, residual stresses, texture, hardness and corrosion resistance of the deposited nickel/alumina coatings was investigated. The surface morphology, cross sections of the coatings and distribution of the ceramic particles in the metal matrix were examined by scanning electron microscopy. The phase composition, residual stresses and preferred grain orientation of the coatings were characterized using X-ray diffraction techniques. The coating morphology revealed that α-Al 2 O 3 particles show a distinct tendency to form agglomerates, approximately uniformly distributed into the nickel matrix

  5. Current Source Density Estimation for Single Neurons

    Directory of Open Access Journals (Sweden)

    Dorottya Cserpán

    2014-03-01

    Full Text Available Recent developments of multielectrode technology made it possible to measure the extracellular potential generated in the neural tissue with spatial precision on the order of tens of micrometers and on submillisecond time scale. Combining such measurements with imaging of single neurons within the studied tissue opens up new experimental possibilities for estimating distribution of current sources along a dendritic tree. In this work we show that if we are able to relate part of the recording of extracellular potential to a specific cell of known morphology we can estimate the spatiotemporal distribution of transmembrane currents along it. We present here an extension of the kernel CSD method (Potworowski et al., 2012 applicable in such case. We test it on several model neurons of progressively complicated morphologies from ball-and-stick to realistic, up to analysis of simulated neuron activity embedded in a substantial working network (Traub et al, 2005. We discuss the caveats and possibilities of this new approach.

  6. Diagnostic of corrosion defects in steam generator tubes using advanced signal processing from Eddy current testing

    International Nuclear Information System (INIS)

    Formigoni, Andre L.; Lopez, Luiz A.N.M.; Ting, Daniel K.S.

    2009-01-01

    Recently, the Brazilian Angra I PWR nuclear power plant went into a programmed shutdown for substitution of its Steam Generator (SG) which life was shortened due to stress corrosion in its tubes. The total cost of investment were around R$724 million. The signals generated during an Eddy-current Testing (ECT) inspection in SG tubes of nuclear plant allows for the localization and dimensioning of defects in the tubes. The defects related with corrosion generate complex signals that are difficult to analyze and are the most common cause in SG replacement in nuclear power plants around the world. The objective of this paper is the development of a methodology that allows for the characterization of corrosion signals by ECT inspections applied in the heat exchangers tubes of SG of a nuclear power plant. In this present work, the aim is to investigate distributed type defects by inducing controlled corrosion in sample tubes of different materials The ECT signals obtained from these samples tubes with corrosion implanted, will be analyzed using Zetec ECT equipment, the MIZ-17ET and its probes. The data acquisition will use a NI PC A/D CARD 700 card and the LabVIEW program. Subsequently, we will apply mathematical tools for signal processing like time windowed Fast Fourier transforms and Wavelets transforms, in MATLAB platform, which will allow effectiveness to remove the noises and to extract representative characteristics for the defect being analyzed. Previously obtained results as well as the proposal for the future work will be presented. (author)

  7. Inhibition of anodic corrosion of aluminium cathode current collector on recharging in lithium imide electrolytes

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xianming; Yasukawa, Eiki; Mori, Shoichiro [Tsukuba Research Center, Mitsubishi Chemical Corp., Ibaraki (Japan)

    2000-07-01

    Pitting corrosion of aluminum as cathode current collector for lithium rechargeable batteries was found to take place at potential positive of 3.5 V in 1 mol dm {sup -3} LiN(SO{sub 2}CF{sub 3}){sub 2} /EC + DME (1:1) electrolyte. The corrosion mechanism of aluminum in the presence of LiN(SO{sub 2}CF{sub 3}){sub 2} was proposed, and three methods were deduced to inhibit the aluminum corrosion based on this mechanism. As a result, an additive of lithium salts based on perfluorinated inorganic anions, especially LiPF{sub 6}, was found to inhibit the aluminum corrosion to a certain extent by forming a protective film on aluminum surface. The oxidation stability of aluminum in LiN(SO{sub 2}CF{sub 3}){sub 2} -containing electrolytes depended strongly on the solvent structure. The ether solvents such as tetrahydrofuran (THF) and dimethoxyethane (DME) were effective in preventing aluminum corrosion due to their low dielectric constants. Furthermore, LiN(SO{sub 2}C{sub 2}F{sub 5}){sub 2} salt with a larger anion than that of LiN(SO{sub 2}CF{sub 3}){sub 2} was evaluated and good oxidation stability of aluminum was obtained regardless of the kind of solvents. (Author)

  8. Corrosion protection of Arctic offshore structures: Final report. [Effects of temperature and salinity on required cathodic protection current

    Energy Technology Data Exchange (ETDEWEB)

    Sackinger, W.M.; Rogers, J.C.; Feyk, C.; Theuveny, B.

    1985-10-01

    Results are presented for a research program on corrosion prevention for Arctic offshore structures which are in contact with sea ice for a significant portion of the year. The electrical method most adaptable for structure protection involves the injection of impressed current from several remote anodes buried just beneath the sea floor. The electrical resistivity of annual sea ice as a function of temperature and salinity is presented. Details of the interface layers formed between sea ice and steel in the presence of current injection are shown. A computer program was developed to enable the calculation of protective current density into the structure, in the presence of ice rubble and ridges around the structure. The program and the results of an example calculation are given for a caisson- retained island structure. 81 refs., 103 figs., 3 tabs.

  9. Electromagnetic considerations for RF current density imaging [MRI technique].

    Science.gov (United States)

    Scott, G C; Joy, M G; Armstrong, R L; Henkelman, R M

    1995-01-01

    Radio frequency current density imaging (RF-CDI) is a recent MRI technique that can image a Larmor frequency current density component parallel to B(0). Because the feasibility of the technique was demonstrated only for homogeneous media, the authors' goal here is to clarify the electromagnetic assumptions and field theory to allow imaging RF currents in heterogeneous media. The complete RF field and current density imaging problem is posed. General solutions are given for measuring lab frame magnetic fields from the rotating frame magnetic field measurements. For the general case of elliptically polarized fields, in which current and magnetic field components are not in phase, one can obtain a modified single rotation approximation. Sufficient information exists to image the amplitude and phase of the RF current density parallel to B(0) if the partial derivative in the B(0) direction of the RF magnetic field (amplitude and phase) parallel to B(0) is much smaller than the corresponding current density component. The heterogeneous extension was verified by imaging conduction and displacement currents in a phantom containing saline and pure water compartments. Finally, the issues required to image eddy currents are presented. Eddy currents within a sample will distort both the transmitter coil reference system, and create measurable rotating frame magnetic fields. However, a three-dimensional electro-magnetic analysis will be required to determine how the reference system distortion affects computed eddy current images.

  10. A point defect model for the general and pitting corrosion on iron-oxide-electrolyte interface deduced from current oscillations

    CERN Document Server

    Pagitsas, M; Sazou, D

    2003-01-01

    Analysis of the passive-active oscillatory region of the Fe-0.75 M H sub 2 SO sub 4 system, perturbed by adding small amounts of halide species, allow the distinction between pitting and general corrosion. Complex periodic and aperiodic current oscillations characterize pitting corrosion whereas monoperiodic oscillations of a relaxation type indicate general corrosion. A point defect model (PDM) is considered for the microscopic description of the growth and breakdown of the iron oxide film. The physicochemical processes leading to different types of corrosion can be clarified in terms of the PDM. Occupation of an anion vacancy by a halide ion results in the localized attack of the passive oxide and pitting corrosion. On the other hand, the formation of surface soluble iron complexes is related to the uniform dissolution of the passive oxide and general corrosion.

  11. Corrosion Behavior of X80 Steel with Coupled Coating Defects under Alternating Current Interference in Alkaline Environment.

    Science.gov (United States)

    Li, Zhong; Li, Caiyu; Qian, Hongchang; Li, Jun; Huang, Liang; Du, Cuiwei

    2017-06-28

    The corrosion behavior of X80 steel in the presence of coupled coating defects was simulated and studied under the interference of alternating current (AC) in an alkaline environment. The results from electrochemical measurements showed that the electrode potential of the coating defect with the smaller exposed area was lower than that with the larger area, which indicated that the steel with the smaller coating defect was more prone to corrosion. The result of weight loss tests also showed that the smaller coating defect had induced a higher corrosion rate. However, the corrosion rate of X80 steel at the larger coating defect decreased gradually with the increase of the larger defect area at a constant smaller defect area. The corrosion morphology images showed that the coating defects with smaller areas suffered from more severe pitting corrosion.

  12. Effect of stray current on corrosion behavior of reinforcing steel: importance of cell geometry and orientation with respect to the electrical field

    NARCIS (Netherlands)

    Chen, Zhipei; Koleva, D.A.

    2016-01-01

    Stray current circulating in reinforced concrete structures may initiate corrosion or accelerate existing corrosion processes on embedded reinforcement. In some cases, the range of dangerous or unwanted interactions of stray currents under favorable conditions (environment), is much broader than is

  13. Effect of electrodeposition current density on the microstructure and the degradation of electroformed iron for degradable stents

    Energy Technology Data Exchange (ETDEWEB)

    Moravej, Maryam [Laboratory for Biomaterials and Bioengineering, Department of Mining, Metallurgy and Materials Engineering and University Hospital Research Center, Universite Laval, Quebec City, Que. G1V 0A6 (Canada); Department of Mining, Metallurgy and Materials Engineering, Pavillon Adrien-Pouliot, 1065 avenue de la Medecine, Local 1745-E, Universite Laval, Quebec City, Que. G1V 0A6 (Canada); Amira, Sofiene [Aluminium Technology Centre, Industrial Materials Institute, National Research Council Canada, 501, boul. de l' Universite Est, Saguenay, Que. G7H 8C3 (Canada); Prima, Frederic [Laboratory for Physical Metallurgy, Ecole Nationale Superieure de Chimie de Paris, Universite Pierre et Marie Curie, Paris 6 (France); Rahem, Ahmed [Aluminium Technology Centre, Industrial Materials Institute, National Research Council Canada, 501, boul. de l' Universite Est, Saguenay, Que. G7H 8C3 (Canada); Fiset, Michel [Department of Mining, Metallurgy and Materials Engineering, Pavillon Adrien-Pouliot, 1065 avenue de la Medecine, Local 1745-E, Universite Laval, Quebec City, Que. G1V 0A6 (Canada); and others

    2011-12-15

    Pure iron has become one of the most interesting candidate materials for degradable metallic stents due to its high mechanical properties and moderate degradation. In this work we studied the effect of electrodeposition current density on microstructure and degradation of pure iron films electrodeposited on Ti alloy substrate for degradable metallic stent application. Iron sheets were produced by electrodeposition using four different current densities 1, 2, 5 and 10 A dm{sup -2}. The films were then studied by SEM (scanning electron microscope) and EBSD (electron backscatter diffraction) to observe the surface morphology, grain size and orientation. Potentiodynamic polarization and static immersion tests were used to determine the corrosion rate and to study the degradation behavior of iron films, respectively. The current density was found to significantly influence the texture, the grain size and the grain shape of the electrodeposited iron. At current densities of 1, 5 and 10 A dm{sup -2}, weak textures corresponding to Left-Pointing-Angle-Bracket 1 0 1 Right-Pointing-Angle-Bracket , Left-Pointing-Angle-Bracket 1 1 1 Right-Pointing-Angle-Bracket and Left-Pointing-Angle-Bracket 1 1 2 Right-Pointing-Angle-Bracket in the normal (electrodeposition) direction were obtained, respectively. At these current densities, average grain sizes smaller than 3 {mu}m were also obtained. However, at 2 A dm{sup -2}, a strong Left-Pointing-Angle-Bracket 1 1 1 Right-Pointing-Angle-Bracket //ND texture with density of 7.4 MUD was obtained with larger average grain size of 4.4 {mu}m. The microstructure of iron samples changed after annealing at 550 Degree-Sign C because of the induced recrystallization. Different corrosion rates were obtained from potentiodynamic polarization curves of iron films deposited at different current densities because of their microstructures. Fe-2 showed the lowest corrosion rate due to its larger grains size and its texture. The corrosion rates of all

  14. Succinonitrile as a corrosion inhibitor of copper current collectors for overdischarge protection of lithium ion batteries.

    Science.gov (United States)

    Kim, Young-Soo; Lee, Seon-Ha; Son, Mi-Young; Jung, Young Mee; Song, Hyun-Kon; Lee, Hochun

    2014-02-12

    Succinonitrile (SN) is investigated as an electrolyte additive for copper corrosion inhibition to provide overdischarge (OD) protection to lithium ion batteries (LIBs). The anodic Cu corrosion, occurring above 3.5 V (vs Li/Li(+)) in conventional LIB electrolytes, is suppressed until a voltage of 4.5 V is reached in the presence of SN. The corrosion inhibition by SN is ascribed to the formation of an SN-induced passive layer, which spontaneously develops on the copper surface during the first anodic scan. The passive layer is composed mainly of Cu(SN)2PF6 units, which is evidenced by Raman spectroscopy and electrochemical quartz crystal microbalance measurements. The effects of the SN additive on OD protection are confirmed by using 750 mAh pouch-type full cells of LiCoO2 and graphite with lithium metal as a reference electrode. Addition of SN completely prevents corrosion of the copper current collector in the full cell configuration, thereby tuning the LIB chemistry to be inherently immune to the OD abuses.

  15. Determining the Limiting Current Density of Vanadium Redox Flow Batteries

    Directory of Open Access Journals (Sweden)

    Jen-Yu Chen

    2014-09-01

    Full Text Available All-vanadium redox flow batteries (VRFBs are used as energy storage systems for intermittent renewable power sources. The performance of VRFBs depends on materials of key components and operating conditions, such as current density, electrolyte flow rate and electrolyte composition. Mass transfer overpotential is affected by the electrolyte flow rate and electrolyte composition, which is related to the limiting current density. In order to investigate the effect of operating conditions on mass transport overpotential, this study established a relationship between the limiting current density and operating conditions. First, electrolyte solutions with different states of charge were prepared and used for a single cell to obtain discharging polarization curves under various operating conditions. The experimental results were then analyzed and are discussed in this paper. Finally, this paper proposes a limiting current density as a function of operating conditions. The result helps predict the effect of operating condition on the cell performance in a mathematical model.

  16. Solid Oxide Electrolysis Cells: Degradation at High Current Densities

    DEFF Research Database (Denmark)

    Knibbe, Ruth; Traulsen, Marie Lund; Hauch, Anne

    2010-01-01

    The degradation of Ni/yttria-stabilized zirconia (YSZ)-based solid oxide electrolysis cells operated at high current densities was studied. The degradation was examined at 850°C, at current densities of −1.0, −1.5, and −2.0 A/cm2, with a 50:50 (H2O:H2) gas supplied to the Ni/YSZ hydrogen electrode...

  17. A high current density DC magnetohydrodynamic (MHD) micropump

    NARCIS (Netherlands)

    Homsy, Alexandra; Koster, Sander; Hogen-Koster, S.; Eijkel, Jan C.T.; van den Berg, Albert; Lucklum, F.; Verpoorte, E.; de Rooij, Nico F.

    2005-01-01

    This paper describes the working principle of a DC magnetohydrodynamic (MHD) micropump that can be operated at high DC current densities (J) in 75-µm-deep microfluidic channels without introducing gas bubbles into the pumping channel. The main design feature for current generation is a micromachined

  18. A high current density DC magnetohydrodynamic (MHD) micropump

    NARCIS (Netherlands)

    Homsy, A; Koster, Sander; Eijkel, JCT; van den Berg, A; Lucklum, F; Verpoorte, E; de Rooij, NF

    2005-01-01

    This paper describes the working principle of a DC magnetohydrodynamic (MHD) micropump that can be operated at high DC current densities (J) in 75-mu m-deep microfluidic channels without introducing gas bubbles into the pumping channel. The main design feature for current generation is a

  19. Estimation of current density distribution under electrodes for external defibrillation

    Directory of Open Access Journals (Sweden)

    Papazov Sava P

    2002-12-01

    Full Text Available Abstract Background Transthoracic defibrillation is the most common life-saving technique for the restoration of the heart rhythm of cardiac arrest victims. The procedure requires adequate application of large electrodes on the patient chest, to ensure low-resistance electrical contact. The current density distribution under the electrodes is non-uniform, leading to muscle contraction and pain, or risks of burning. The recent introduction of automatic external defibrillators and even wearable defibrillators, presents new demanding requirements for the structure of electrodes. Method and Results Using the pseudo-elliptic differential equation of Laplace type with appropriate boundary conditions and applying finite element method modeling, electrodes of various shapes and structure were studied. The non-uniformity of the current density distribution was shown to be moderately improved by adding a low resistivity layer between the metal and tissue and by a ring around the electrode perimeter. The inclusion of openings in long-term wearable electrodes additionally disturbs the current density profile. However, a number of small-size perforations may result in acceptable current density distribution. Conclusion The current density distribution non-uniformity of circular electrodes is about 30% less than that of square-shaped electrodes. The use of an interface layer of intermediate resistivity, comparable to that of the underlying tissues, and a high-resistivity perimeter ring, can further improve the distribution. The inclusion of skin aeration openings disturbs the current paths, but an appropriate selection of number and size provides a reasonable compromise.

  20. Rf Gun with High-Current Density Field Emission Cathode

    International Nuclear Information System (INIS)

    Jay L. Hirshfield

    2005-01-01

    High current-density field emission from an array of carbon nanotubes, with field-emission-transistor control, and with secondary electron channel multiplication in a ceramic facing structure, have been combined in a cold cathode for rf guns and diode guns. Electrodynamic and space-charge flow simulations were conducted to specify the cathode configuration and range of emission current density from the field emission cold cathode. Design of this cathode has been made for installation and testing in an existing S-band 2-1/2 cell rf gun. With emission control and modulation, and with current density in the range of 0.1-1 kA/cm2, this cathode could provide performance and long-life not enjoyed by other currently-available cathodes

  1. Superconducting toroidal field coil current densities for the TFCX

    International Nuclear Information System (INIS)

    Kalsi, S.S.; Hooper, R.J.

    1985-04-01

    A major goal of the Tokamak Fusion Core Experiment (TFCX) study was to minimize the size of the device and achieve lowest cost. Two key factors influencing the size of the device employing superconducting magnets are toroidal field (TF) winding current density and its nuclear heat load withstand capability. Lower winding current density requires larger radial build of the winding pack. Likewise, lower allowable nuclear heating in the winding requires larger shield thickness between the plasma and coil. In order to achieve a low-cost device, it is essential to maximize the winding's current density and nuclear heating withhstand capability. To meet the above objective, the TFCX design specification adopted as goals a nominal winding current density of 3500 A/cm 2 with 10-T peak field at the winding and peak nuclear heat load limits of 1 MW/cm 3 for the nominal design and 50 MW/cm 3 for an advanced design. This study developed justification for these current density and nuclear heat load limits

  2. Regional absolute conductivity reconstruction using projected current density in MREIT

    International Nuclear Information System (INIS)

    Sajib, Saurav Z K; Kim, Hyung Joong; Woo, Eung Je; Kwon, Oh In

    2012-01-01

    Magnetic resonance electrical impedance tomography (MREIT) is a non-invasive technique for imaging the internal conductivity distribution in tissue within an MRI scanner, utilizing the magnetic flux density, which is introduced when a current is injected into the tissue from external electrodes. This magnetic flux alters the MRI signal, so that appropriate reconstruction can provide a map of the additional z-component of the magnetic field (B z ) as well as the internal current density distribution that created it. To extract the internal electrical properties of the subject, including the conductivity and/or the current density distribution, MREIT techniques use the relationship between the external injection current and the z-component of the magnetic flux density B = (B x , B y , B z ). The tissue studied typically contains defective regions, regions with a low MRI signal and/or low MRI signal-to-noise-ratio, due to the low density of nuclear magnetic resonance spins, short T 2 or T* 2 relaxation times, as well as regions with very low electrical conductivity, through which very little current traverses. These defective regions provide noisy B z data, which can severely degrade the overall reconstructed conductivity distribution. Injecting two independent currents through surface electrodes, this paper proposes a new direct method to reconstruct a regional absolute isotropic conductivity distribution in a region of interest (ROI) while avoiding the defective regions. First, the proposed method reconstructs the contrast of conductivity using the transversal J-substitution algorithm, which blocks the propagation of severe accumulated noise from the defective region to the ROI. Second, the proposed method reconstructs the regional projected current density using the relationships between the internal current density, which stems from a current injection on the surface, and the measured B z data. Combining the contrast conductivity distribution in the entire imaging

  3. Albumin coatings by alternating current electrophoretic deposition for improving corrosion resistance and bioactivity of titanium implants.

    Science.gov (United States)

    Höhn, Sarah; Braem, Annabel; Neirinck, Bram; Virtanen, Sannakaisa

    2017-04-01

    Although Ti alloys are generally regarded to be highly corrosion resistant, inflammatory conditions following surgery can instigate breakdown of the TiO 2 passivation layer leading to an increased metal ion release. Furthermore proteins present in the surrounding tissue will readily adsorb on a titanium surface after implantation. In this paper alternating current electrophoretic deposition (AC-EPD) of bovine serum albumin (BSA) on Ti6Al4V was investigated in order to increase the corrosion resistance and control the protein adsorption capability of the implant surface. The Ti6Al4V surface was characterized with SEM, XPS and ToF-SIMS after long-term immersion tests under physiological conditions and simulated inflammatory conditions either in Dulbecco's Modified Eagle Medium (DMEM) or DMEM supplemented with fetal calf serum (FCS). The analysis showed an increased adsorption of amino acids and proteins from the different immersion solutions. The BSA coating was shown to prevent selective dissolution of the vanadium (V) rich β-phase, thus effectively limiting metal ion release to the environment. Electrochemical impedance spectroscopy measurements confirmed an increase of the corrosion resistance for BSA coated surfaces as a function of immersion time due to the time-dependent adsorption of the different amino acids (from DMEM) and proteins (from FCS) as observed by ToF-SIMS analysis. Copyright © 2017 Elsevier B.V. All rights reserved.

  4. Current Density Measurements of an Annular-Geometry Ion Engine

    Science.gov (United States)

    Shastry, Rohit; Patterson, Michael J.; Herman, Daniel A.; Foster, John E.

    2012-01-01

    The concept of the annular-geometry ion engine, or AGI-Engine, has been shown to have many potential benefits when scaling electric propulsion technologies to higher power. However, the necessary asymmetric location of the discharge cathode away from thruster centerline could potentially lead to non-uniformities in the discharge not present in conventional geometry ion thrusters. In an effort to characterize the degree of this potential non-uniformity, a number of current density measurements were taken on a breadboard AGI-Engine. Fourteen button probes were used to measure the ion current density of the discharge along a perforated electrode that replaced the ion optics during conditions of simulated beam extraction. Three Faraday probes spaced apart in the vertical direction were also used in a separate test to interrogate the plume of the AGI-Engine during true beam extraction. It was determined that both the discharge and the plume of the AGI-Engine are highly uniform, with variations under most conditions limited to +/-10% of the average current density in the discharge and +/-5% of the average current density in the plume. Beam flatness parameter measured 30 mm from the ion optics ranged from 0.85 - 0.95, and overall uniformity was shown to generally increase with increasing discharge and beam currents. These measurements indicate that the plasma is highly uniform despite the asymmetric location of the discharge cathode.

  5. Influence of Macrocyclic Ring Size on the Corrosion Inhibition Efficiency of Dibenzo Crown Ether: A Density Functional Study

    Directory of Open Access Journals (Sweden)

    Saprizal Hadisaputra

    2017-11-01

    Full Text Available The effect of macrocycle ring size on the corrosion inhibition efficiency of dibenzo-12-crown-4 (DB12C4, dibenzo-15-crown-5 (DB15C5, dibenzo-18-crown-6 (DB18C6, dibenzo-21-crown-7 (DB21C7 and dibenzo-24-crown-8 (DB24C8 have been elucidated by mean of density functional calculation at B3LYP/6-31G(d level of theory in the gas and aqueous environment. The quantum chemical parameters including the frontier orbital energies (EHOMO, ELUMO, ionization potential (I, electron affinity (A, the absolute electronegativity (χ, hardness (η, softness (σ, and the fraction of electron transferred (ΔN are positively correlated to the corrosion inhibition efficiency (IE% of the studied crown ethers. The calculation results indicate that DB24C8 exhibits the highest corrosion inhibition efficiency, whereas DB12C4 exhibits the lowest corrosion inhibition efficiency. The results of this study will contribute to design crown ethers potential as corrosion inhibitors.

  6. High-current discharge channel contraction in high density gas

    International Nuclear Information System (INIS)

    Rutberg, Ph. G.; Bogomaz, A. A.; Pinchuk, M. E.; Budin, A. V.; Leks, A. G.; Pozubenkov, A. A.

    2011-01-01

    Research results for discharges at current amplitudes of 0.5-1.6 MA and current rise rate of ∼10 10 A/s are presented. The discharge is performed in the hydrogen environment at the initial pressure of 5-35 MPa. Initiation is implemented by a wire explosion. The time length of the first half-period of the discharge current is 70-150 μs. Under such conditions, discharge channel contraction is observed; the contraction is followed by soft x-ray radiation. The phenomena are discussed, which are determined by high density of the gas surrounding the discharge channel. These phenomena are increase of the current critical value, where the channel contraction begins and growth of temperature in the axis region of the channel, where the initial density of the gas increases.

  7. Electron and current density measurements on tokamak plasmas

    International Nuclear Information System (INIS)

    Lammeren, A.C.A.P. van.

    1991-01-01

    The first part of this thesis describes the Thomson-scattering diagnostic as it was present at the TORTUR tokamak. For the first time with this diagnostic a complete tangential scattering spectrum was recorded during one single laser pulse. From this scattering spectrum the local current density was derived. Small deviations from the expected gaussian scattering spectrum were observed indicating the non-Maxwellian character of the electron-velocity distribution. The second part of this thesis describes the multi-channel interferometer/ polarimeter diagnostic which was constructed, build and operated on the Rijnhuizen Tokamak Project (RTP) tokamak. The diagnostic was operated routinely, yielding the development of the density profiles for every discharge. When ECRH (Electron Cyclotron Resonance Heating) is switched on the density profile broadens, the central density decreases and the total density increases, the opposite takes place when ECRH is switched off. The influence of MHD (magnetohydrodynamics) activity on the density was clearly observable. In the central region of the plasma it was measured that in hydrogen discharges the so-called sawtooth collapse is preceded by an m=1 instability which grows rapidly. An increase in radius of this m=1 mode of 1.5 cm just before the crash is observed. In hydrogen discharges the sawtooth induced density pulse shows an asymmetry for the high- and low-field side propagation. This asymmetry disappeared for helium discharges. From the location of the maximum density variations during an m=2 mode the position of the q=2 surface is derived. The density profiles are measured during the energy quench phase of a plasma disruption. A fast flattening and broadening of the density profile is observed. (author). 95 refs.; 66 figs.; 7 tabs

  8. Current density functional theory for optical spectra : A polarization functional

    NARCIS (Netherlands)

    Boeij, P.L. de; Kootstra, F.; Berger, J.A.; Leeuwen, R. van; Snijders, J.G.

    2001-01-01

    In this paper we present a new approach to calculate optical spectra, which for the first time uses a polarization dependent functional within current density functional theory (CDFT), which was proposed by Vignale and Kohn. This polarization dependent functional includes exchange-correlation (xc)

  9. Density currents as a desert dust mobilization mechanism

    Directory of Open Access Journals (Sweden)

    S. Solomos

    2012-11-01

    Full Text Available The formation and propagation of density currents are well studied processes in fluid dynamics with many applications in other science fields. In the atmosphere, density currents are usually meso-β/γ phenomena and are often associated with storm downdrafts. These storms are responsible for the formation of severe dust episodes (haboobs over desert areas. In the present study, the formation of a convective cool pool and the associated dust mobilization are examined for a representative event over the western part of Sahara desert. The physical processes involved in the mobilization of dust are described with the use of the integrated atmospheric-air quality RAMS/ICLAMS model. Dust is effectively produced due to the development of near surface vortices and increased turbulent mixing along the frontal line. Increased dust emissions and recirculation of the elevated particles inside the head of the density current result in the formation of a moving "dust wall". Transport of the dust particles in higher layers – outside of the density current – occurs mainly in three ways: (1 Uplifting of preexisting dust over the frontal line with the aid of the strong updraft (2 Entrainment at the upper part of the density current head due to turbulent mixing (3 Vertical mixing after the dilution of the system. The role of the dust in the associated convective cloud system was found to be limited. Proper representation of convective processes and dust mobilization requires the use of high resolution (cloud resolving model configuration and online parameterization of dust production. Haboob-type dust storms are effective dust sources and should be treated accordingly in dust modeling applications.

  10. Ionospheric midlatitude electric current density inferred from multiple magnetic satellites

    DEFF Research Database (Denmark)

    Shore, R. M.; Whaler, K. A.; Macmillan, S.

    2013-01-01

    A method for inferring zonal electric current density in the mid-to-low latitude F region ionosphere is presented. We describe a method of using near-simultaneous overflights of the Ørsted and CHAMP satellites to define a closed circuit for an application of Ampère's integral law to magnetic data....... Zonal current density from sources in only the region between the two satellites is estimated for the first time. Six years of mutually available vector magnetic data allows overlaps spanning the full 24 h range of local time twice. Solutions are computed on an event-by-event basis after correcting...... for estimates of main and crustal magnetic fields. Current density in the range ±0.1 μA/m2 is resolved, with the distribution of electric current largely matching known features such as the Appleton anomaly. The currents appear unmodulated at times of either high-negative Dst or high F10.7, which has...

  11. High current density aluminum stabilized conductor concepts for space applications

    International Nuclear Information System (INIS)

    Huang, X.; Eyssa, Y.M.; Hilal, M.A.

    1989-01-01

    Lightweight conductors are needed for space magnets to achieve values of E/M (energy stored per unit mass) comparable to the or higher than advanced batteries. High purity aluminum stabilized NbTi composite conductors cooled by 1.8 K helium can provide a winding current density up to 15 kA/cm/sup 2/ at fields up to 10 tesla. The conductors are edge cooled with enough surface area to provide recovery following a normalizing disturbance. The conductors are designed so that current diffusion time in the high purity aluminum is smaller than thermal diffusion time in helium. Conductor design, stability and current diffusion are considered in detail

  12. Current density profile inside q=1 on Tore Supra

    International Nuclear Information System (INIS)

    Joffrin, E.; Desgranges, C.; Sabot, R.; Dubois, M.A.

    1995-01-01

    The Tore Supra polarimeter used to measure the poloidal field distribution is described. The current density profiles are computed in two different ways using the interferometric and polarimetric data in conjunction with the magnetic data and the location of the inversion radius determined by the soft X-ray camera. The current density inside the q=1 surface is investigated for normal and monster sawteeth. Its variation are also measured by the polarimeter and compared with that predicted by the current diffusion equation assuming complete reconnection. Finally, the safety factor profile is compared with that obtained with the striation data of the pellet ablation. The results of the evolution of the q profile during sawteeth are in good agreement with those obtained in other devices. (author) 9 refs.; 4 figs

  13. High current density magnets for INTOR and TIBER

    International Nuclear Information System (INIS)

    Miller, J.R.; Henning, C.D.; Kerns, J.A.; Slack, D.S.; Summers, L.T.; Zbasnik, J.P.

    1986-12-01

    The adoption of high current density, high field, superconducting magnets for INTOR and TIBER would prove beneficial. When combined with improved radiation tolerance of the magnets to minimize the inner leg shielding, a substantial reduction in machine dimensions and capital costs can be achieved. Fortunately, cable-in-conduit conductors (CICC) which are capable of the desired enhancements are being developed. Because conductor stability in a CICC depends more on the trapped helium enthalpy, rather than the copper resistivity, higher current densities of the order of 40 A/mm 2 at 12 T are possible. Radiation damage to the copper stabilizer is less important because the growth in resistance is a second-order effect on stability. Such CICC conductors lend themselves naturally to niobium-tin utilization, with the benefits of the high current-sharing temperature of this material being taken to advantage in absorbing radiation heating. When the helium coolant is injected at near the critical pressure, Joule-Thompson expansion in the flow path tends to stabilize the fluid temperature at under 6 K. Thus, higher fields, as well as higher current densities, can be considered for INTOR or TIBER

  14. Numerical Simulation of Density Current Evolution in a Diverging Channel

    Directory of Open Access Journals (Sweden)

    Mitra Javan

    2012-01-01

    Full Text Available When a buoyant inflow of higher density enters a reservoir, it sinks below the ambient water and forms an underflow. Downstream of the plunge point, the flow becomes progressively diluted due to the fluid entrainment. This study seeks to explore the ability of 2D width-averaged unsteady Reynolds-averaged Navier-Stokes (RANS simulation approach for resolving density currents in an inclined diverging channel. 2D width-averaged unsteady RANS equations closed by a buoyancy-modified − turbulence model are integrated in time with a second-order fractional step approach coupled with a direct implicit method and discretized in space on a staggered mesh using a second-order accurate finite volume approach incorporating a high-resolution semi-Lagrangian technique for the convective terms. A series of 2D width-averaged unsteady simulations is carried out for density currents. Comparisons with the experimental measurements and the other numerical simulations show that the predictions of velocity and density field are with reasonable accuracy.

  15. Evidence for explosive volcanic density currents on certain Martian volcanoes

    Science.gov (United States)

    Reimers, C. E.; Komar, P. D.

    1979-01-01

    The morphologies of certain of the smaller Martian volcanoes are discussed as possible results of explosive volcanic density currents. An examination of newly-photographed flank and caldera features of the Martian volcanoes Ceraunius Tholus, Uranius Tholus, Uranius Patera and Hecates Tholus, including steep slope angles, Krakatoa-type caldera morphologies, erosional features (radial channels and anastamosing gullies) and constructional features (blanketed flanks and possible lava deltas) reveals their similarity to terrestrial cones and composite volcanoes such as Barcena Volcano. Crater age data from the surface of Martian domes and shields indicates that such explosive activity occurred more frequently early in Martian geologic history, consistent with the view that the volcanic density currents were base surges rather than nuees ardentes, with the melting of permafrost supplying the water required in base surge generation.

  16. Vortex edge barriers and critical current density in granular superconductors

    CERN Document Server

    Belevtsov, L V

    2003-01-01

    Type-II superconductors, even without bulk pinning and in the absence of a macroscopic Bean-Livingston surface barrier for vortex penetration, can exhibit barriers for flux penetration. We investigated some new edge barriers based on the laminar model, that are governed by the anisotropy ratio, grain coupling strength, and grain size. Expressions describing the pinning potential U sub p and critical current density J sub c are derived for magnetic fields near H sub c sub 1. It is shown that edge barrier effects play a substantial role in a realistic description of the critical current density for both MgB sub 2 and high-T sub c superconductors. (Abstract Copyright [2003], Wiley Periodicals, Inc.)

  17. Current density profile measurements in the Proto-Cleo Torsatron

    International Nuclear Information System (INIS)

    Schaeffer, R.C.; Shohet, J.L.

    1979-10-01

    Current density profile measurements were obtained in the Proto-Cleo Torsatron (R = 40 cm, a = 5 cm, l = 3, B/sub T/ = 3 kG, anti n approx. 10 11 cm -3 , T/sub e/ approx. 20 eV) by using a small, back-to-back flat double probe. Three different operating circuits used with this probe are presented, along with experimental results, all showing good agreement. Current is seen to flow only within the separatrix, in channels which follow the magnetic surfaces as they move radially inward with time due to changing vertical magnetic flux

  18. Morphology and Density Structure of Post-CME Current Sheets

    Science.gov (United States)

    Vrsnak, B.; Poletto, G.; Vujic, E.; Vourlidas, A.

    2009-01-01

    Eruption of a coronal mass ejection (CME) is believed to drag and open the coronal magnetic field, presumably leading to the formation of a large-scale current sheet and field relaxation by magnetic reconnection. This paper analyzes the physical characteristics of ray-like coronal features formed in the aftermath of CMEs, to confirm whether interpreting such phenomena in terms of a reconnecting current sheet is consistent with observations. Methods: The study focuses on UVCS/SOHO and LASCO/SOHO measurements of the ray width, density excess, and coronal velocity field as a function of the radial distance. The morphology of the rays implies that they are produced by Petschek-like reconnection in the large-scale current sheet formed in the wake of CME. The hypothesis is supported by the flow pattern, often showing outflows along the ray, and sometimes also inflows into the ray. The inferred inflow velocities range from 3 to 30 km/s, and are consistent with the narrow opening-angle of rays, which add up to a few degrees. The density of rays is an order of magnitude higher than in the ambient corona. The model results are consistent with the observations, revealing that the main cause of the density excess in rays is a transport of the dense plasma from lower to higher heights by the reconnection outflow.

  19. Stress corrosion cracking test with slow strain rate and constant current

    International Nuclear Information System (INIS)

    Ondrejcin, R.S.

    1976-01-01

    A rapid electrochemical tensile test was developed for evaluating stress corrosion crack initiation in carbon steel. Constant anodic current was imposed on smooth-bar tensile specimens as the specimens were slowly strained to fracture at cross-head speeds of 1.3 x 10 -6 /sec. Equivalent response results were obtained for all ductility properties measured; uniform elongation, total elongation and reduction of area. Total elongation was chosen as the index for stress corrosion crack initiation. An equation was developed that allowed calculation of total elongation of specimens in electrolytes (test solutions) with composition ranges of 1.5 to 5.5 M nitrate, 0 to 3.5 M nitrite, and 0 to 5.0 M hydroxide, and a temperature range of 50 0 C to 100 0 C. A minimum of 13 percent total elongation was selected to indicate the possible initiation of cracking in A 285-B steel alloy. The test was used to evaluate relative aggressiveness of synthetic nuclear wastes on A 285-B carbon steel and the relative resistances of several steels to given solution compositions. Test results formed one of the bases for setting temperature limits and concentration limits for several ions in nuclear wastes that are stored in carbon steel tanks at the Savannah River Plant

  20. Microstructure and Properties of Ni and Ni/Al2O3 Coatings Electrodeposited at Various Current Densities

    Directory of Open Access Journals (Sweden)

    Góral A.

    2016-03-01

    Full Text Available The study presents investigations of an influence of various direct current densities on microstructure, residual stresses, texture, microhardness and corrosion resistance of the nickel coatings electrodeposited from modified Watt’s baths. The properties of obtained coatings were compared to the nano-crystalline composite Ni/Al2O3 coatings prepared under the same plating conditions. The similarities and differences of the obtained coatings microstructures visible on both their surfaces and cross sections and determined properties were presented. The differences in the growth character of the Ni matrix and in the microstructural properties were observed. All electrodeposited Ni and Ni/Al2O3 coatings were compact and well adhering to the steel substrates. The thickness and the microhardness of the Ni and Ni/Al2O3 deposits increased significantly with the current density in the range 2 - 6 A/dm2. Residual stresses are tensile and they reduced as the current density increased. The composite coatings revealed better protection from the corrosion of steel substrate than pure nickel in solution 1 M NaCl.

  1. Current density monitor for intense relativistic electron beams

    International Nuclear Information System (INIS)

    Fiorito, R.B.; Raleigh, M.; Seltzer, S.M.

    1986-01-01

    We describe a new type of electric probe which is capable of measuring the time-resolved current density profile of a stable, reproducible, high-energy (>4-MeV) high-current (>1-kA) electron beam. The sensing element of this probe is an open-ended but capped-off 50-Ω coaxial line constructed of graphite. The graphite sensor is 4.3 mm in diameter, 6 cm long, and is range thin to the primary beam electrons. The probe produces a signal proportional to the intercepted beam current. When the sensor is scanned radially through the beam during repeated pulses, a curve of signal versus depth of insertion is produced from which the radial current density profile can be determined. Measurements are presented of the profile of the electron beam from the Experimental Test Accelerator (4.5 MeV, 10 kA) at Lawrence Livermore National Laboratory. Good agreement is shown between measurements made with this probe and the beam radius as predicted by transport codes. The advantage of the electric probe lies in its ruggedness, simplicity, inherent fast rise time, and low cost. In contrast to other systems it requires no radiation shielding, water cooling, or auxiliary support equipment to operate in an intense beam environment

  2. Magnetohydrodynamically stable plasma with supercritical current density at the axis

    Science.gov (United States)

    Burdakov, A. V.; Postupaev, V. V.; Sudnikov, A. V.

    2014-05-01

    In this work, an analysis of magnetic perturbations in the GOL-3 experiment is given. In GOL-3, plasma is collectively heated in a multiple-mirror trap by a high-power electron beam. During the beam injection, the beam-plasma interaction maintains a high-level microturbulence. This provides an unusual radial profile of the net current (that consists of the beam current, current of the preliminary discharge, and the return current). The plasma core carries supercritical current density with the safety factor well below unity, but as a whole, the plasma is stable with q(a) ≈ 4. The net plasma current is counter-directed to the beam current; helicities of the magnetic field in the core and at the edge are of different signs. This forms a system with a strong magnetic shear that stabilizes the plasma core in good confinement regimes. We have found that the most pronounced magnetic perturbation is the well-known n = 1, m = 1 mode for both stable and disruptive regimes.

  3. Magnetohydrodynamically stable plasma with supercritical current density at the axis

    International Nuclear Information System (INIS)

    Burdakov, A. V.; Postupaev, V. V.; Sudnikov, A. V.

    2014-01-01

    In this work, an analysis of magnetic perturbations in the GOL-3 experiment is given. In GOL-3, plasma is collectively heated in a multiple-mirror trap by a high-power electron beam. During the beam injection, the beam-plasma interaction maintains a high-level microturbulence. This provides an unusual radial profile of the net current (that consists of the beam current, current of the preliminary discharge, and the return current). The plasma core carries supercritical current density with the safety factor well below unity, but as a whole, the plasma is stable with q(a) ≈ 4. The net plasma current is counter-directed to the beam current; helicities of the magnetic field in the core and at the edge are of different signs. This forms a system with a strong magnetic shear that stabilizes the plasma core in good confinement regimes. We have found that the most pronounced magnetic perturbation is the well-known n = 1, m = 1 mode for both stable and disruptive regimes

  4. RF Current Density Measurements and Mode Coupling in Helicon Discharges

    Science.gov (United States)

    Madziwa, T. G.; Blackwell, D. D.; Arnush, D.; Chen, F. F.

    1999-10-01

    It has been suggested that the high RF power absorption efficiency in helicon discharges is due to the transfer of energy to electron cyclotron waves called Trivelpiece-Gould (TG) modes.(K. P. Shamrai, V. P. Pavlenko, and V. B. Taranov, Plasma Phys. Control. Fusion 39), 505 (1997). To test this theory, measurements have been performed using magnetic and current density probes to detect TG waves. The experiments are performed in a 10-cm diam chamber with B_circ=25-55 G, n=10^11-10^12 cm-3, p=3 mTorr of argon, and P_rf=0.2-1 kW at 11 MHz. A two-turn m=0 antenna is used to excite the helicon wave plasma. Measurements are compared with a numerical code developed by Arnush and Chen(D. Arnush and F. F. Chen, Phys. Plasmas 5), 1239 (1998). which calculates the wave profiles given the antenna geometry, plasma density profile, and neutral pressure. The results show that, as predicted by theory, the RF current density is strongly influenced by the TG mode, causing broadening and ripples in the profile, while the magnetic field is influenced to a lesser extent.

  5. High current density, cryogenically cooled sliding electrical joint development

    International Nuclear Information System (INIS)

    Murray, H.

    1986-09-01

    In the past two years, conceptual designs for fusion energy research devices have focussed on compact, high magnetic field configurations. The concept of sliding electrical joints in the large magnets allows a number of technical advantages including enhanced mechanical integrity, remote maintainability, and reduced project cost. The rationale for sliding electrical joints is presented. The conceptual configuration for this generation of experimental devices is highlghted by an ∼ 20 T toroidal field magnet with a flat top conductor current of ∼ 300 kA and a sliding electrical joint with a gross current density of ∼ 0.6 kA/cm 2 . A numerical model was used to map the conductor current distribution as a function of time and position in the conductor. A series of electrical joint arrangements were produced against the system code envelope constraints for a specific version of the Ignition Studies Project (ISP) which is designated as 1025

  6. The dynamics of pyroclastic density currents on Mars

    Science.gov (United States)

    Brand, B. D.; Clarke, A. B.

    2010-12-01

    The products of explosive volcanism have long been observed on the surface of Mars, and their corresponding dynamics, associated with phenomenon such as dike propagation, magma fragmentation, and eruption columns under Martian conditions, have been modeled with significant success (e.g., Wilson, L., J. W. Head (1994), Mars- Review and analysis of volcanic eruption theory and relationships to observed landforms, Rev. Geophy, 32, 221-263). However, the dynamics of pyroclastic density currents (PDCs) under Martian conditions is still poorly constrained. Our increasing capability to image the surface at high resolution, both from orbit and from rovers, presents an opportunity for more rigorous deposit observations and descriptions. For example, observations and measurements from Orbiters identify what have been interpreted as extensive aprons of volcanic ash deposits in several volcanic regions, namely those surrounding several southern highland patera, which have been interpreted as the deposits of PDCs. In addition the bedded deposits identified by the Spirit rover at “Home Plate,” an outcrop within the Columbia Hills in Gusev Crater, have been interpreted by many as the deposits of dilute pyroclastic density currents. This demonstrates that the need to understand the role of the Martian atmosphere on flow dynamics and depositional processes is much more important and relevant than it has been in the past. We have developed a quantitative, axi-symmetric model for flow of and sedimentation from a steady-state, vertically uniform dilute density current for application to PDCs on Earth and Mars (following Bursik, M. I., A. W. Woods, 1996, The dynamics and thermodynamics of large ash flows, Bull Volcan, 58, 175-193). The conservation of mass, momentum, and energy are solved simultaneously, and include the effects of atmospheric entrainment, particle sedimentation, basal friction, temperature changes, and variations in current thickness and density. For a given set of

  7. Computation of superconductor critical current densities and magnetization curves

    International Nuclear Information System (INIS)

    Hodgdon, M.L.

    1991-01-01

    Using a constitutive law for superconductor hysteresis and the ideas of the critical state model, a system of equations is developed for the critical current density J c , the equilibrium magnetization M e , the upper and lower portions M U and M L of the major hysteresis loop, and their derivatives with respect to the applied field. The constitutive law consists of the differential equation dB/dH=α(H)s(H)[f(H)-B]+g(H) for H≠0, and a rule governing the abrupt changes observed at the turning points of H. For the case presented here in which f, g, and α have analytic forms, the constitutive law yields an easily differentiable expression for the major loop. Hysteresis curves computed from this constitutive law are shown to be in good agreement with experiments. Exponential approximations are given for the critical current densities computed by this method for a polycrystalline sample of YBa 2 Cu 3 O x between 5 and 40 K

  8. Online diagnoses of high current-density beams

    International Nuclear Information System (INIS)

    Gilpatrick, J.D.

    1994-01-01

    Los Alamos National Laboratory has proposed several CW-proton-beam facilities for production of tritium or transmutation of nuclear waste with beam-current densities greater than 5 mA/mm 2 . The primary beam-diagnostics-instrumentation requirement for these facilities is provision of sufficient beam information to understand and minimize beam-loss. To accomplish this task, the beam-diagnostics instrumentation must measure beam parameters such as the centroids and profiles, total integrated current, and particle loss. Noninterceptive techniques must be used for diagnosis of high-intensity CW beam at low energies due to the large quantity of power deposited in an interceptive diagnostic device by the beam. Transverse and longitudinal centroid measurements have been developed for bunched beams by measuring and processing image currents on the accelerator walls. Transverse beam-profile measurement-techniques have also been developed using the interaction of the particle beam with the background gases near the beam region. This paper will discuss these noninterceptive diagnostic Techniques

  9. Ultra-high current density thin-film Si diode

    Science.gov (United States)

    Wang, Qi [Littleton, CO

    2008-04-22

    A combination of a thin-film .mu.c-Si and a-Si:H containing diode structure characterized by an ultra-high current density that exceeds 1000 A/cm.sup.2, comprising: a substrate; a bottom metal layer disposed on the substrate; an n-layer of .mu.c-Si deposited the bottom metal layer; an i-layer of .mu.c-Si deposited on the n-layer; a buffer layer of a-Si:H deposited on the i-layer, a p-layer of .mu.c-Si deposited on the buffer layer; and a top metal layer deposited on the p-layer.

  10. Critical current densities in Bi-2223 sinter forgings.

    Energy Technology Data Exchange (ETDEWEB)

    Balachandran, U.; Fisher, B. L.; Goretta, K. C.; Harris, N. C.; Murayama, N.

    1999-07-23

    (Bi,Pb){sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub x} (Bi-2223) bars, prepared by sinter forging, exhibited good phase purity and strong textures with the c axes of the Bi-2223 grains parallel to the forging direction. The initial zero-field critical current density (J{sub c}) of the bars was 10{sup 3} A/cm{sup 2}, but because the forged bars were uncoated, this value decreased with repeated thermal cycling. J{sub c} as a function of applied magnetic field magnitude and direction roughly followed the dependencies exhibited by Ag-sheathed Bi-2223 tapes, but the forged bars were more strongly dependent on field strength and less strongly dependent on field angle.

  11. Development of high temperature superconductors having high critical current density

    Energy Technology Data Exchange (ETDEWEB)

    Hong, Gye Wong; Kim, C. J.; Lee, H.G.; Kwon, S. C.; Lee, H. J.; Kim, K. B.; Park, J. Y.; Jung, C. H

    2000-08-01

    Fabrication of high T{sub c} superconductors and its applications for electric power device were carried out for developing superconductor application technologies. High quality YBCO superconductors was fabricated by melt texture growth, top-seeded melt growth process and multi-seeded melt growth process and the properties was compared. The critical current density of the melt processed YBCO superconductors was about few 10,000 A/cm{sup 2} and the levitation force was 50 N. The processing time needed for the growth of the 123 single grain was greatly reduced by applying multi-seeding without no significant degradation of the levitation force. The multi-seeded melt growth process was confirmed as a time-saving and cost-effective method for the fabrication of bulk superconductors with controlled crystallographic orientation.

  12. A distributed current stimulator ASIC for high density neural stimulation.

    Science.gov (United States)

    Jeong Hoan Park; Chaebin Kim; Seung-Hee Ahn; Tae Mok Gwon; Joonsoo Jeong; Sang Beom Jun; Sung June Kim

    2016-08-01

    This paper presents a novel distributed neural stimulator scheme. Instead of a single stimulator ASIC in the package, multiple ASICs are embedded at each electrode site for stimulation with a high density electrode array. This distributed architecture enables the simplification of wiring between electrodes and stimulator ASIC that otherwise could become too complex as the number of electrode increases. The individual ASIC chip is designed to have a shared data bus that independently controls multiple stimulating channels. Therefore, the number of metal lines is determined by the distributed ASICs, not by the channel number. The function of current steering is also implemented within each ASIC in order to increase the effective number of channels via pseudo channel stimulation. Therefore, the chip area can be used more efficiently. The designed chip was fabricated with area of 0.3 mm2 using 0.18 μm BCDMOS process, and the bench-top test was also conducted to validate chip performance.

  13. Propagation of steel corrosion in concrete: Experimental and numerical investigations

    DEFF Research Database (Denmark)

    Michel, Alexander; Otieno, M.; Stang, Henrik

    2016-01-01

    This paper focuses on experimental and numerical investigations of the propagation phase of reinforcement corrosion to determine anodic and cathodic Tafel constants and exchange current densities, from corrosion current density and corrosion potential measurements. The experimental program includ...... through numerical simulations of the experimental data. Anodic and cathodic exchange current densities ranged from 1.0E-12 to 1.0E-09 A/mm2 and 1.0E-12 to 1.1E-09 A/mm2, respectively.......This paper focuses on experimental and numerical investigations of the propagation phase of reinforcement corrosion to determine anodic and cathodic Tafel constants and exchange current densities, from corrosion current density and corrosion potential measurements. The experimental program included....... The numerical model was, furthermore, used to identify electrochemical parameters, which are independent of concrete cover thickness and crack width and at the same time allow for determination of the corrosion current density and corrosion potential of concrete structures within an acceptable error.Very good...

  14. Comparison of exact-exchange calculations for solids in current-spin-density- and spin-density-functional theory

    DEFF Research Database (Denmark)

    Sharma, S.; Pittalis, S.; Kurth, S.

    2007-01-01

    The relative merits of current-spin-density- and spin-density-functional theory are investigated for solids treated within the exact-exchange-only approximation. Spin-orbit splittings and orbital magnetic moments are determined at zero external magnetic field. We find that for magnetic (Fe, Co......, and Ni) and nonmagnetic (Si and Ge) solids, the exact-exchange current-spin-density functional approach does not significantly improve the accuracy of the corresponding spin-density functional results....

  15. Probability density fittings of corrosion test-data: Implications on C 6 ...

    Indian Academy of Sciences (India)

    This was done to investigate the suitability of the results of the fitted test-data, by these distributions, for modelling the effectiveness of C6H15NO3, triethanolamine (TEA), admixtures on the corrosion of steel-rebar in concrete in NaCl and in H2SO4 test-media. For this, six different concentrations of TEA were admixed in ...

  16. Orbital functionals in density-matrix- and current-density-functional theory

    Energy Technology Data Exchange (ETDEWEB)

    Helbig, N.

    2006-05-15

    Density-Functional Theory (DFT), although widely used and very successful in the calculation of several observables, fails to correctly describe strongly correlated materials. In the first part of this work we, therefore, introduce reduced-densitymatrix- functional theory (RDMFT) which is one possible way to treat electron correlation beyond DFT. Within this theory the one-body reduced density matrix (1- RDM) is used as the basic variable. Our main interest is the calculation of the fundamental gap which proves very problematic within DFT. In order to calculate the fundamental gap we generalize RDMFT to fractional particle numbers M by describing the system as an ensemble of an N and an N+1 particle system (with N{<=}M{<=}N+1). For each fixed particle number, M, the total energy is minimized with respect to the natural orbitals and their occupation numbers. This leads to the total energy as a function of M. The derivative of this function with respect to the particle number has a discontinuity at integer particle number which is identical to the gap. In addition, we investigate the necessary and sufficient conditions for the 1- RDM of a system with fractional particle number to be N-representable. Numerical results are presented for alkali atoms, small molecules, and periodic systems. Another problem within DFT is the description of non-relativistic many-electron systems in the presence of magnetic fields. It requires the paramagnetic current density and the spin magnetization to be used as basic variables besides the electron density. However, electron-gas-based functionals of current-spin-density-functional Theory (CSDFT) exhibit derivative discontinuities as a function of the magnetic field whenever a new Landau level is occupied, which makes them difficult to use in practice. Since the appearance of Landau levels is, intrinsically, an orbital effect it is appealing to use orbital-dependent functionals. We have developed a CSDFT version of the optimized

  17. Differential modulation of corticospinal excitability by different current densities of anodal transcranial direct current stimulation.

    Directory of Open Access Journals (Sweden)

    Andisheh Bastani

    Full Text Available BACKGROUND: Novel non-invasive brain stimulation techniques such as transcranial direct current stimulation (tDCS have been developed in recent years. TDCS-induced corticospinal excitability changes depend on two important factors current intensity and stimulation duration. Despite clinical success with existing tDCS parameters, optimal protocols are still not entirely set. OBJECTIVE/HYPOTHESIS: The current study aimed to investigate the effects of four different anodal tDCS (a-tDCS current densities on corticospinal excitability. METHODS: Four current intensities of 0.3, 0.7, 1.4 and 2 mA resulting in current densities (CDs of 0.013, 0.029, 0.058 and 0.083 mA/cm(2 were applied on twelve right-handed (mean age 34.5±10.32 yrs healthy individuals in different sessions at least 48 hours apart. a-tDCS was applied continuously for 10 minute, with constant active and reference electrode sizes of 24 and 35 cm(2 respectively. The corticospinal excitability of the extensor carpi radialis muscle (ECR was measured before and immediately after the intervention and at 10, 20 and 30 minutes thereafter. RESULTS: Post hoc comparisons showed significant differences in corticospinal excitability changes for CDs of 0.013 mA/cm(2 and 0.029 mA/cm(2 (P = 0.003. There were no significant differences between excitability changes for the 0.013 mA/cm(2 and 0.058 mA/cm(2 (P = 0.080 or 0.013 mA/cm(2 and 0.083 mA/cm(2 (P = 0.484 conditions. CONCLUSION: This study found that a-tDCS with a current density of 0.013 mA/cm(2 induces significantly larger corticospinal excitability changes than CDs of 0.029 mA/cm(2. The implication is that might help to avoid applying unwanted amount of current to the cortical areas.

  18. Comparison of current density profiles based on particle orbit-driven current in steady-state plasma on QUEST

    Energy Technology Data Exchange (ETDEWEB)

    Alam, Md Mahbub, E-mail: m.alam@triam.kyushu-u.ac.jp [IGSES, Kyushu University, 6-1 Kasuga-koen, Kasuga, Fukuoka 816-8580 (Japan); Nakamura, Kazuo [RIAM, Kyushu University, 6-1 Kasuga-koen, Kasuga, Fukuoka 816-8580 (Japan); Xia, Fan [CFS, SWIP, P.O. Box 432, 610041 Chengdu (China); Mitarai, Osamu [Tokai University, Kumamoto 862-8652 (Japan); Hasegawa, Makoto; Tokunaga, Kazutoshi; Araki, Kuniaki; Zushi, Hideki; Hanada, Kazuaki; Fujisawa, Akihide; Idei, Hiroshi; Nagashima, Yoshihiko; Kawasaki, Shoji; Nakashima, Hisatoshi; Higashijima, Aki; Nagata, Takahiro [RIAM, Kyushu University, 6-1 Kasuga-koen, Kasuga, Fukuoka 816-8580 (Japan)

    2016-11-01

    Highlights: • Electron cyclotron resonance heating (ECRH) of QUEST. • Particle guiding center orbit calculation. • Orbit-driven current density profile. • Hollow current density. • Equilibrium condition for steady-state operation of QUEST. - Abstract: In the present RF-driven divertor plasma of QUEST, it has been observed that orbit-driven current flows in the open magnetic surfaces outside of the closed magnetic surfaces. To observe this phenomenon and the characteristics of the orbit-driven current, current density profiles have been calculated on two different equilibrium conditions. We calculated current density profiles from particle guiding center orbits both for the fundamental and the second harmonic resonances for the 8.2 GHz electron cyclotron current drive. From this calculation, hollow current density profiles have been obtained with significant characteristics on both conditions. Only positive current distribution has been observed in the open magnetic surfaces outside of the closed magnetic surfaces.

  19. High-density matter: current status and future challenges

    Directory of Open Access Journals (Sweden)

    Stone J. R.

    2015-01-01

    Full Text Available There are many fascinating processes in the Universe which we observe in more and more in detail thanks to increasingly sophisticated technology. One of the most interesting phenomena is the life cycle of stars, their birth, evolution and death. If the stars are massive enough, they end their lives in the core-collapse supernova explosion, the one of the most violent events in the Universe. As the result, the densest objects in the Universe, neutron stars and/or black holes are created. Naturally, the physical basis of these events should be understood in line with observation. The current status of our knowledge of processes in the life of stars is far from adequate for their true understanding. We show that although many models have been constructed their detailed ability to describe observations is limited or non-existent. Furthermore the general failure of all models means that we cannot tell which are heading in the right direction. A possible way forward in modeling of high-density matter is outlined, exemplified by the quark-meson-coupling model (QMC. This model has a natural explanation for the saturation of nuclear forces and depends on very few adjustable parameters, strongly constrained by the underlying physics. Latest QMC results for compact objects and finite nuclei are presented.

  20. Characteristic corrosion resistance of nanocrystalline TiN films prepared by high density plasma reactive magnetron sputtering.

    Science.gov (United States)

    Kim, J H; Kang, C G; Kim, Y T; Cheong, W S; Song, P K

    2013-07-01

    Nanocytalline TiN films were deposited on non-alkali glass and Al substrates by reactive DC magnetron sputtering (DCMS) with an electromagnetic field system (EMF). The microstructure and corrosion resistance of the TiN-coated Al substrates were estimated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrochemical methods. All the TiN films shows that they have a (111) preferred orientation at room temperature. TiN films deposited on Al substrate using only DCMS 400 W showed a sheet resistance of 3.22 x 10-1 omega/symbol see texts (resistivity, 3.22 x 10-5 omegacm). On the other hand, a relatively low sheet resistance of 1.91 x 10-1 omega/symbol see text (1.91 x 10-5 omegacm) was obtained for the dense nanocrystalline TiN film deposited on Al substrate using DCMS 375 W+ EMF 25 W, indicating that the introduction of an EMF system enhanced the electrical properties of the TiN film. TiN films deposited on Al substrate at 400 degreesC had a (200) preferred orientation with the lowest sheet resistance of 1.28x10-1 omega/symbol see texts (1.28 x 10-5 omegacm) which was attributed to reduced nano size defects and an improvement of the crystallinity. Potentiostatic and Potentiodynamic tests with a TiN-coated Al showed good corrosion resistance (l/corr, = 2.03 microA/cm2, Ecorr = -348 mV) compared to the uncoated Al substrate (/corr = 4.45 microA/cm2, Ecorr = -650 mV). Furthermore, EMF system showed that corrosion resistance of the TiN film also was enhanced compared to DCMS only. For the TiN film deposited on Al substrate at 400 degreesC, corrosion current and potential was 0.63 micro/cm2 and -1.5 mV, respectively. This improved corrosion resistance of the TiN film could be attributed to the densification of the film caused by enhancement of nitrification with increasing high reactive nitrogen radicals.

  1. Corrosion of Co-Cr alloys in aqueous environments.

    Science.gov (United States)

    Kuhn, A T

    1981-04-01

    The literature relating to the corrosion in aqueous media of the Co-Cr alloys is reviewed. Data are surveyed for their corrosion in sulphuric acid, alkalis and in hydrochloric acid and chloride media. In the latter category, the information is sub-divided into single corrosion, crevice and stress corrosion, fretting corrosion and data obtained from 'in vivo' experiments. It is clear that the very low current densities which result from 'in vitro' experiments present abnormal experimental problems and may not, in every case, actually represent the dissolution process.

  2. Corrosion and Erosion-Corrosion Processes of Metal-Matrix Composites in Slurry Conditions

    Science.gov (United States)

    Flores, J. F.; Neville, A.; Kapur, N.; Gnanavelu, A.

    2012-03-01

    The corrosion and erosion-corrosion (EC) processes of four metal-matrix composites (MMCs) in a simulated cooling water environment have been assessed in this article. The MMCs consisted of two Ni-base and two Fe-base matrices alloyed with different concentrations of chromium, molybdenum, boron, silicon, and carbon; the matrices were reinforced with tungsten carbide (WC) particles. The corrosion behavior has been investigated using a combination of potentiostatic polarization and post-tests surface analysis. The EC processes were studied by in situ electrochemical techniques measuring the current density and corrosion potential response at different slurry temperatures and sand content. At static conditions it was found that as the temperature increased, there was a transition from a homogeneous corrosion of the matrix to an interfacial corrosion mechanism. The Ni-base MMCs showed a better corrosion resistance and interestingly a highly alloyed matrix did not significantly improved MMC's corrosion resistance. In the in situ EC tests, the Fe-base MMCs showed a constant increase in the current density at all sand contents. Whereas, significant changes were not observed in the Ni-base MMCs below 0.5 g/L. Although sand content had an effect on the monitored current density (the current increased as the sand content increased) this effect was less pronounced above 3 g/L.

  3. Valley current characterization of high current density resonant tunnelling diodes for terahertz-wave applications

    Science.gov (United States)

    Jacobs, K. J. P.; Stevens, B. J.; Baba, R.; Wada, O.; Mukai, T.; Hogg, R. A.

    2017-10-01

    We report valley current characterisation of high current density InGaAs/AlAs/InP resonant tunnelling diodes (RTDs) grown by metal-organic vapour phase epitaxy (MOVPE) for THz emission, with a view to investigate the origin of the valley current and optimize device performance. By applying a dual-pass fabrication technique, we are able to measure the RTD I-V characteristic for different perimeter/area ratios, which uniquely allows us to investigate the contribution of leakage current to the valley current and its effect on the PVCR from a single device. Temperature dependent (20 - 300 K) characteristics for a device are critically analysed and the effect of temperature on the maximum extractable power (PMAX) and the negative differential conductance (NDC) of the device is investigated. By performing theoretical modelling, we are able to explore the effect of typical variations in structural composition during the growth process on the tunnelling properties of the device, and hence the device performance.

  4. Improved corrosion behavior of nanocrystalline zinc produced by pulse-current electrodeposition

    International Nuclear Information System (INIS)

    Youssef, Kh.M.S.; Koch, C.C.; Fedkiw, P.S.

    2004-01-01

    Pulse electrodeposition was used to produce nanocrystalline (nc) zinc from zinc chloride electrolyte with polyacrylamide and thiourea as additives. Field emission scanning electron microscopy (FESEM) was used to study the grain size and surface morphology of the deposits and X-ray diffraction was used to examine their preferred orientation. Corrosion behavior of the electrodeposited nc zinc in comparison with electrogalvanized (EG) steel in de-aerated 0.5 N NaOH solution was studied using potentiodynamic polarization and impedance measurements. A scanning electron microscope (SEM) was used to characterize the surface morphology of the EG steel before corrosion testing. Surface morphologies of nc zinc deposits and EG steel were also studied after potentiondynamic polarization by SEM. Nanocrystalline zinc (56 nm) with random orientation was produced. The estimated corrosion rate of nc zinc was found to be about 60% lower than that of EG steel, 90 and 229 μA/cm 2 , respectively. The surface morphology of corroded nc zinc was characterized by discrete etch pits, however, uniform corrosion was obtained after potentiodynamic polarization of EG steel. The passive film formed on the nc zinc surface seems to be a dominating factor for the corrosion behavior observed

  5. Resistance of Magnesium Alloys to Corrosion Fatigue for Biodegradable Implant Applications: Current Status and Challenges

    Science.gov (United States)

    Raman, R. K. Singh; Harandi, Shervin Eslami

    2017-01-01

    Magnesium (Mg) alloys are attracting increasing interest as the most suitable metallic materials for construction of biodegradable and bio-absorbable temporary implants. However, Mg-alloys can suffer premature and catastrophic fracture under the synergy of cyclic loading and corrosion (i.e., corrosion fatigue (CF)). Though Mg alloys are reported to be susceptible to CF also in the corrosive human body fluid, there are very limited studies on this topic. Furthermore, the in vitro test parameters employed in these investigations have not properly simulated the actual conditions in the human body. This article presents an overview of the findings of available studies on the CF of Mg alloys in pseudo-physiological solutions and the employed testing procedures, as well as identifying the knowledge gap. PMID:29144428

  6. Current state of knowledge in radiolysis effects on spent fuel corrosion

    International Nuclear Information System (INIS)

    Christensen, H.; Sunder, S.

    1998-09-01

    Literature data on the effect of water radiolysis products on spent fuel oxidation and dissolution have been reviewed. Effects of γ-radiolysis, α-radiolysis and dissolved O 2 or H 2 O 2 in unirradiated solutions have been discussed separately. Also the effect of carbonate in γ-irradiated solutions and radiolysis effects on leaching of spent fuels have been reviewed. In addition a radiolysis model for calculation of corrosion rates of UO 2 , presented previously, has been discussed. The model has been shown to give a good agreement between calculated and measured corrosion rates in the case of γ-radiolysis and in unirradiated solutions of dissolved oxygen or hydrogen peroxide. The model has failed to predict the results of α-radiolysis. In a recent study it was shown that the model gave a good agreement with measured corrosion rates of spent fuel exposed in deionized water

  7. Current state of knowledge of water radiolysis effects on spent nuclear fuel corrosion

    International Nuclear Information System (INIS)

    Christensen, H.; Sunder, S.

    2000-07-01

    Literature data on the effect of water radiolysis products on spent-fuel oxidation and dissolution are reviewed. Effects of gamma radiolysis, alpha radiolysis, and dissolved O 2 or H 2 O 2 in unirradiated solutions are discussed separately. Also, the effect of carbonate in gamma-irradiated solutions and radiolysis effects on leaching of spent fuel are reviewed. In addition, a kinetic model for calculating the corrosion rates of UO 2 in solutions undergoing radiolysis is discussed. The model gives good agreement between calculated and measured corrosion rates in the case of gamma radiolysis and in unirradiated solutions containing dissolved oxygen or hydrogen peroxide. However, the model fails to predict the results of alpha radiolysis. In a recent study , it was shown that the model gave good agreement with measured corrosion rates of spent fuel exposed in deionized water. The applications of radiolysis studies for geologic disposal of used nuclear fuel are discussed. (author)

  8. Electrochemical corrosion and bioactivity of Ti-Nb-Sn-hydroxyapatite composites fabricated by pulse current activated sintering.

    Science.gov (United States)

    Xiaopeng, Wang; Fantao, Kong; Biqing, Han; Yuyong, Chen

    2017-11-01

    Ti-Nb-Sn-hydroxyapatite (HA) composites were prepared by mechanical alloying for different times (unmilled, 4, 8 and 12h), followed by pulse current activated sintering. The effects of the milling time on the electrochemical corrosion resistance and bioactivity of the sintered Ti-35Nb-2.5Sn-15HA composites were investigated. Potentiodynamic polarization test results indicated that the sintered Ti-35Nb-2.5Sn-15HA composites exhibited higher corrosion resistance with increasing milling time. The corrosion potential and current of the Ti-35Nb-2.5Sn-15HA composite sintered by 12h milled powders were - 0.261V and 0.18μA/cm 2 , respectively, and this sintered composite showed a stable and wide passivation region. The hemolysis rate of the sintered Ti-35Nb-2.5Sn-15HA composites reduced with increasing milling time and the lowest hemolytic rate of the composites was 0.87%. In addition, the in vitro cell culture results indicated that the composite sintered by 12h milled powders had good biocompatibility. These results indicate the significant potential of Ti-35Nb-2.5Sn/xHA composites for biomedical implant applications. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Current density profile control by programming of gas puffing and plasma current waveform in the JIPPT-II tokamak

    International Nuclear Information System (INIS)

    Toi, K.; Itoh, S.; Kadota, K.; Kawahata, K.; Noda, N.

    1979-03-01

    In the resistive shell tokamak, JIPP T-II, the current density profile control is carried out by pre-programming of both gas puffing and plasma current waveform. The major disruptions are completely suppressed by the method and a high density tokamak plasma with low q(a) is obtained with better MHD stability, where the line-average electron density n sub(e) 13 cm -3 and safety factor at plasma surface q(a) >= 2.2. The control criterion that the current density profile is successfully controlled is derived as a function of the ratio of plasma current to the electron density I sub(p)/n sub(e) in the current rising phase, i.e., 20 x 10 -13 -13 kA.cm 3 . (author)

  10. Frequency-dependent alternating-current scanning electrochemical microscopy (4D AC-SECM) for local visualisation of corrosion sites.

    Science.gov (United States)

    Eckhard, Kathrin; Erichsen, Thomas; Stratmann, Martin; Schuhmann, Wolfgang

    2008-01-01

    For a better understanding of the initiation of localised corrosion, there is a need for analytical tools that are capable of imaging corrosion pits and precursor sites with high spatial resolution and sensitivity. The lateral electrochemical contrast in alternating-current scanning electrochemical microscopy (AC-SECM) has been found to be highly dependent on the frequency of the applied alternating voltage. In order to be able to obtain data with optimum contrast and high resolution, the AC frequency is swept in a full spectrum at each point in space instead of performing spatially resolved measurements at one fixed perturbation frequency. In doing so, four-dimensional data sets are acquired (4D AC-SECM). Here, we describe the instrument set-up and modus operandi, along with the first results from the imaging of corroding surfaces. Corrosion precursor sites and local defects in protective organic coatings, as well as an actively corroding pit on 304 stainless steel, have been successfully visualised. Since the lateral electrochemical contrast in these images varies with the perturbation frequency, the proposed approach constitutes an indispensable tool for obtaining optimum electrochemical contrast.

  11. Combined Effect of Alternating Current Interference and Cathodic Protection on Pitting Corrosion and Stress Corrosion Cracking Behavior of X70 Pipeline Steel in Near-Neutral pH Environment

    Directory of Open Access Journals (Sweden)

    Liwei Wang

    2018-03-01

    Full Text Available Influence of alternating current (AC on pitting corrosion and stress corrosion cracking (SCC behavior of X70 pipeline steel in the near-neutral pH environment under cathodic protection (CP was investigated. Both corrosion and SCC are inhibited by −0.775 VSCE CP without AC interference. With the superimposition of AC current (1–10 mA/cm2, the direct current (DC potential shifts negatively under the CP of −0.775 VSCE and the cathodic DC current decreases and shifts to the anodic direction. Under the CP potential of −0.95 VSCE and −1.2 VSCE, the applied AC current promotes the cathodic reaction and leads to the positive shift of DC potential and increase of cathodic current. Local anodic dissolution occurs attributing to the generated anodic current transients in the positive half-cycle of the AC current, resulting in the initiation of corrosion pits (0.6–2 μm in diameter. AC enhances the SCC susceptibility of X70 steel under −0.775 VSCE CP, attributing to the promotion of anodic dissolution and hydrogen evolution. Even an AC current as low as 1 mA/cm2 can enhance the SCC susceptibility.

  12. Combined Effect of Alternating Current Interference and Cathodic Protection on Pitting Corrosion and Stress Corrosion Cracking Behavior of X70 Pipeline Steel in Near-Neutral pH Environment.

    Science.gov (United States)

    Wang, Liwei; Cheng, Lianjun; Li, Junru; Zhu, Zhifu; Bai, Shuowei; Cui, Zhongyu

    2018-03-22

    Influence of alternating current (AC) on pitting corrosion and stress corrosion cracking (SCC) behavior of X70 pipeline steel in the near-neutral pH environment under cathodic protection (CP) was investigated. Both corrosion and SCC are inhibited by -0.775 V SCE CP without AC interference. With the superimposition of AC current (1-10 mA/cm²), the direct current (DC) potential shifts negatively under the CP of -0.775 V SCE and the cathodic DC current decreases and shifts to the anodic direction. Under the CP potential of -0.95 V SCE and -1.2 V SCE , the applied AC current promotes the cathodic reaction and leads to the positive shift of DC potential and increase of cathodic current. Local anodic dissolution occurs attributing to the generated anodic current transients in the positive half-cycle of the AC current, resulting in the initiation of corrosion pits (0.6-2 μm in diameter). AC enhances the SCC susceptibility of X70 steel under -0.775 V SCE CP, attributing to the promotion of anodic dissolution and hydrogen evolution. Even an AC current as low as 1 mA/cm² can enhance the SCC susceptibility.

  13. Evidence for intrinsic critical current density in high Tc superconductors

    International Nuclear Information System (INIS)

    Freltoft, T.; Minnhagen, P.; Jeldtoft Jensen, H.

    1991-01-01

    We present measurements of the voltage-current characteristics of high quality epitaxial YBaCuO films in zero magnetic field. According to the predictions of a current induced vortex pair breaking picture the voltage should follow the functional form V∝I(I-I c ) a-1 . An analysis designed to test this functional behavior is carried out. Consistency is found. (orig.)

  14. Lower hybrid current drive for edge current density modification in DIII-D: Final status report

    Energy Technology Data Exchange (ETDEWEB)

    Fenstermacher, M.E. [Lawrence Livermore National Lab., CA (United States); Porkolab, M. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Plasma Fusion Center

    1993-08-04

    Application of Lower Hybrid (LH) Current Drive (CD) in the DIII-D tokamak has been studied at LLNL, off and on, for several years. The latest effort began in February 1992 in response to a letter from ASDEX indicating that the 2.45 GHz, 3 MW system there was available to be used on another device. An initial assessment of the possible uses for such a system on DIII-D was made and documented in September 1992. Multiple meetings with GA personnel and members of the LH community nationwide have occurred since that time. The work continued through the submission of the 1995 Field Work Proposals in March 1993 and was then put on hold due to budget limitations. The purpose of this document is to record the status of the work in such a way that it could fairly easily be restarted at a future date. This document will take the form of a collection of Appendices giving both background and the latest results from the FY 1993 work, connected by brief descriptive text. Section 2 will describe the final workshop on LHCD in DIII-D held at GA in February 1993. This was an open meeting with attendees from GA, LLNL, MIT and PPPL. Summary documents from the meeting and subsequent papers describing the results will be included in Appendices. Section 3 will describe the status of work on the use of low frequency (2.45 GHZ) LH power and Parametric Decay Instabilities (PDI) for the special case of high dielectric in the edge regions of the DIII-D plasma. This was one of the critical issues identified at the workshop. Other potential issues for LHCD in the DIII-D scenarios are: (1) damping of the waves on fast ions from neutral beam injection, (2) runaway electrons in the low density edge plasma, (3) the validity of the WKB approximation used in the ray-tracing models in the steep edge density gradients.

  15. CdS-metal contact at higher current densities.

    Science.gov (United States)

    Stirn, R. J.; Boeer, K. W.; Dussel, G. A.

    1973-01-01

    An investigation is conducted concerning the mechanisms by which a steady flow of current proceeds through the contact when an external voltage is applied. The main characteristics of current mechanisms are examined, giving attention to photoemission from the cathode, thermionic emission, minority-carrier extraction, and the tunneling of electrons. A high-field domain analysis is conducted together with experimental studies. Particular attention is given to the range in which tunneling predominates.

  16. Eddy Current Testing with Giant Magnetoresistance (GMR) Sensors and a Pipe-Encircling Excitation for Evaluation of Corrosion under Insulation.

    Science.gov (United States)

    Bailey, Joseph; Long, Nicholas; Hunze, Arvid

    2017-09-28

    This work investigates an eddy current-based non-destructive testing (NDT) method to characterize corrosion of pipes under thermal insulation, one of the leading failure mechanisms for insulated pipe infrastructure. Artificial defects were machined into the pipe surface to simulate the effect of corrosion wall loss. We show that by using a giant magnetoresistance (GMR) sensor array and a high current (300 A), single sinusoidal low frequency (5-200 Hz) pipe-encircling excitation scheme it is possible to quantify wall loss defects without removing the insulation or weather shield. An analysis of the magnetic field distribution and induced currents was undertaken using the finite element method (FEM) and analytical calculations. Simple algorithms to remove spurious measured field variations not associated with defects were developed and applied. The influence of an aluminium weather shield with discontinuities and dents was ascertained and found to be small for excitation frequency values below 40 Hz. The signal dependence on the defect dimensions was analysed in detail. The excitation frequency at which the maximum field amplitude change occurred increased linearly with the depth of the defect by about 3 Hz/mm defect depth. The change in magnetic field amplitude due to defects for sensors aligned in the azimuthal and radial directions were measured and found to be linearly dependent on the defect volume between 4400-30,800 mm³ with 1.2 × 10 -3 -1.6 × 10 -3 µT/mm³. The results show that our approach is well suited for measuring wall loss defects similar to the defects from corrosion under insulation.

  17. Analysis of Eddy Current Capabilities for the Detection of Outer Diameter Stress Corrosion Cracking in Small Bore Metallic Structures

    Science.gov (United States)

    Wincheski, Buzz; Williams, Phillip; Simpson, John

    2007-01-01

    The use of eddy current techniques for the detection of outer diameter damage in tubing and many complex aerospace structures often requires the use of an inner diameter probe due to a lack of access to the outside of the part. In small bore structures the probe size and orientation are constrained by the inner diameter of the part, complicating the optimization of the inspection technique. Detection of flaws through a significant remaining wall thickness becomes limited not only by the standard depth of penetration, but also geometrical aspects of the probe. Recently, an orthogonal eddy current probe was developed for detection of such flaws in Space Shuttle Primary Reaction Control System (PRCS) Thrusters. In this case, the detection of deeply buried stress corrosion cracking by an inner diameter eddy current probe was sought. Probe optimization was performed based upon the limiting spatial dimensions, flaw orientation, and required detection sensitivity. Analysis of the probe/flaw interaction was performed through the use of finite and boundary element modeling techniques. Experimental data for the flaw detection capabilities, including a probability of detection study, will be presented along with the simulation data. The results of this work have led to the successful deployment of an inspection system for the detection of stress corrosion cracking in Space Shuttle Primary Reaction Control System (PRCS) Thrusters.

  18. Critical current density for spin transfer torque switching with composite free layer structure

    OpenAIRE

    You, Chun-Yeol

    2009-01-01

    Critical current density of composite free layer (CFL) in magnetic tunneling junction is investigated. CFL consists of two exchange coupled ferromagnetic layers, where the coupling is parallel or anti-parallel. Instability condition of the CFL under the spin transfer torque, which is related with critical current density, is obtained by analytic spin wave excitation model and confirmed by macro-spin Landau-Lifshitz-Gilbert equation. The critical current densities for the coupled two identical...

  19. Corrosion of circulating water pipings in thermal and nuclear power stations and corrosion prevention measures

    International Nuclear Information System (INIS)

    Hachiya, Minoru

    1982-01-01

    In the age of energy conservation at present, the power generation facilities have been examined from the viewpoint of performance, endurance and economy, and in particular, the prevention of the loss due to the corrosion of various facilities is one of most important problems. Since circulating water pipings are in contact with sea water and soil, the peculiar corrosion phenomena are brought about on their external and internal surfaces. Namely, the pitting corrosion due to the environment of soil quality difference, the defects of coating and the contact with reinforcing bars in concrete occurs on the external surface, and the overall corrosion due to the increase of flow velocity and the pitting corrosion due to the defects of coating, the contact with different kinds of metals and the gap in corrosion-resistant steel occur on the internal surface. As the measures for corrosion prevention, corrosion-preventive coating and electric corrosion prevention are applied. The principle, the potential and current density, the system, the design procedure and the examples of application of electric corrosion prevention are described. (Kako, I.)

  20. Effects of electrolyte concentration and current density on the ...

    Indian Academy of Sciences (India)

    The results show that upon increasing the concentration of FeCl 2 , initially the Fe content of the coating increased and then tended to be stable; the deposition rate and microhardness of coating decreased when the cathodic current efficiency ( η ) initially increased and then decreased; and for a FeCl 2 concentration of 3.6 ...

  1. Peltier effect in multilayered nanopillars under high density charge current

    International Nuclear Information System (INIS)

    Gravier, L; Fukushima, A; Kubota, H; Yamamoto, A; Yuasa, S

    2006-01-01

    From the basic equations of thermoelectricity, we model the thermal regimes that develop in multilayered nanopillar elements experiencing continuous charge currents. The energy conservation principle was applied to all layer-layer and layer-electrode junctions. The obtained set of equations was solved to derive the temperature of each junction. The contribution of the Peltier effect is included in an effective resistance. This model gives satisfactory fits to experimental data obtained on a series of reference nanopillar elements

  2. Corrosive characteristics of surface-modified stainless steel bipolar plate in solid polymer fuel cell

    Science.gov (United States)

    Zhang, Xiaowen; Wang, Lixia; Sun, Juncai

    2015-03-01

    In this paper, corrosion behavior of an AISI 304 stainless steel modified by niobium or niobium nitride (denoted as niobized 304 SS and Nb-N 304 SS, respectively) is investigated in simulated solid polymer fuel cell (SPFC) operating conditions. Potentiodynamic polarizations show that the corrosion potentials of surface modified 304 SS shift to positive direction while the corrosion current densities decrease greatly comparing with the bare 304 SS in simulated anodic SPFC environments. The order of corrosive resistance in corrosive potential, corrosive current density and pitting potential is: Nb-N 304 SS > niobized 304 SS > bare 304 SS. In the methanol-fueled SPFC operating conditions, the results show that the corrosion resistance of bare and niobized 304 SS increases with the methanol concentration increasing in the test solutions.

  3. High current densities in superconducting films from magnetization

    International Nuclear Information System (INIS)

    McGuire, T.R.; Gupta, A.; Koren, G.; Gross, R.

    1990-01-01

    Epitaxial thin films of YBa 2 Cu 3 O 7-x made by laser ablation have the CuO planes parallel to the film surface. In the CuO planes critical currents of J C ∼40 x 10 6 amps/cm 2 are found at 5K in zero field. Multi-layered films with Gd replacing Y each .01μm in thickness have J C nearly 140 x 10 6 amps/cm 2 . This higher value is perhaps due to additional point defects. Perpendicular to the CuO planes magnetization studies indicate strong pinning effects attributed to the CuO planes acting as barriers to flux motion

  4. Density-Driven Currents and Deposition of Fine Materials

    DEFF Research Database (Denmark)

    Saremi, Sina

    . Dredging activities always make changes to the environment, such as alteration of the coastal or river morphology, currents and wave climates, and water quality. Such changes may be considered improving or degrading to the environment. The type of material being dredged, type of the dredging equipment...... and type of sediments change along and into the seabed. Variations in the material entering the hopper have been studied by assuming fluctuating inflow concentrations. The fluctuations impose a mean net change on the overflow concentrations. In the third part of this study, the above described CFD model......Dredging is a key element in river, ports, coastal and offshore development. In general dredging is conducted for excavation at the river,lake or seabed, relocation of the material, maintenance of the navigation channels, mining underwater deposits, land reclamation or cleaning up the environment...

  5. Evaluation of current densities and total contact currents in occupational exposure at 400 kV substations and power lines.

    Science.gov (United States)

    Korpinen, Leena H; Elovaara, Jarmo A; Kuisti, Harri A

    2009-04-01

    This investigation studied the current densities in the neck and total contact currents in occupational exposure at 400 kV substations and power lines. Eight voluntary workers simulated their normal work tasks using the helmet-mask measuring system. In all, 151 work tasks with induced current measurements were made. Work situations were: tasks in 400 kV substations, tasks in 400-110 kV towers and the cutting of vegetation under 400 kV power lines. The average current density in the neck was estimated from the current induced in the helmet. The calculated maximum average current densities in the neck varied from 1.5 to 6.4 mA/m(2) and the maximum total contact currents from 66.8 to 458.4 microA. The study shows that the maximum average current densities and the total contact currents (caused by electric field) in occupational exposure at 400 kV substations and power lines does not exceed the limit and action values (10 mA/m(2) and 1 mA) of the new EU-directive 2004/40/EC (live-line bare-hand works excluded). (c) 2009 Wiley-Liss, Inc.

  6. High Density Infrared (HDI) Transient Liquid Coatings for Improved Wear and Corrosion Resistance

    Energy Technology Data Exchange (ETDEWEB)

    Ronald W. Smith

    2007-07-05

    This report documents a collaborative effort between Oak Ridge National Laboratory (ORNL), Materials Resources International and an industry team of participants to develop, evaluate and understand how high density infrared heating technology could be used to improve infiltrated carbide wear coatings and/or to densify sprayed coatings. The research included HDI fusion evaluations of infiltrated carbide suspensions such (BrazeCoat® S), composite suspensions with tool steel powders, thermally sprayed Ni-Cr- B-Si (self fluxing alloy) and nickel powder layers. The applied work developed practical HDI / transient liquid coating (TLC) procedures on test plates that demonstrated the ability to fuse carbide coatings for industrial applications such as agricultural blades, construction and mining vehicles. Fundamental studies helped create process models that led to improved process understanding and control. The coating of agricultural blades was demonstrated and showed the HDI process to have the ability to fuse industrial scale components. Sliding and brasive wear tests showed that high degree of wear resistance could be achieved with the addition of tool steel powders to carbide particulate composites.

  7. Analysis of copper corrosion in compacted bentonite clay as a function of clay density and growth conditions for sulfate-reducing bacteria.

    Science.gov (United States)

    Pedersen, K

    2010-03-01

    To investigate the relationships between sulfate-reducing bacteria (SRB), growth conditions, bentonite densities and copper sulfide generation under circumstances relevant to underground, high-level radioactive waste repositories. Experiments took place 450 m underground, connected under in situ pressure to groundwater containing SRB. The microbial reduction of sulfate to sulfide and subsequent corrosion of copper test plates buried in compacted bentonite were analysed using radioactive sulfur (35SO4(2-)) as tracer. Mass distribution of copper sulfide on the plates indicated a diffusive process. The relationship between average diffusion coefficients (Ds) and tested density (rho) was linear. Ds (m2 s(-1))=-0.004xrho (kg m(-3))+8.2, decreasing by 0.2 Ds units per 50 kg m(-3) increase in density, from 1.2x10(-11) m2 s(-1) at 1750 kg m(-3) to 0.2x10(-11) m2 s(-1) at 2000 kg m(-3). It is possible that sulfide corrosion of waste canisters in future radioactive waste repositories depends mainly on sulfide concentration at the boundary between groundwater and the buffer, which in turn depends on SRB growth conditions (e.g., sulfate accessibility, carbon availability and electron donors) and geochemical parameters (e.g., presence of ferrous iron, which immobilizes sulfide). Maintaining high bentonite density is also important in mitigating canister corrosion. The sulfide diffusion coefficients can be used in safety calculations regarding waste canister corrosion. The work supports findings that microbial activity in compacted bentonite will be restricted. The study emphasizes the importance of growth conditions for sulfate reduction at the groundwater boundary of the bentonite buffer and linked sulfide production.

  8. In vivo mapping of current density distribution in brain tissues during deep brain stimulation (DBS

    Directory of Open Access Journals (Sweden)

    Saurav Z. K. Sajib

    2017-01-01

    Full Text Available New methods for in vivo mapping of brain responses during deep brain stimulation (DBS are indispensable to secure clinical applications. Assessment of current density distribution, induced by internally injected currents, may provide an alternative method for understanding the therapeutic effects of electrical stimulation. The current flow and pathway are affected by internal conductivity, and can be imaged using magnetic resonance-based conductivity imaging methods. Magnetic resonance electrical impedance tomography (MREIT is an imaging method that can enable highly resolved mapping of electromagnetic tissue properties such as current density and conductivity of living tissues. In the current study, we experimentally imaged current density distribution of in vivo canine brains by applying MREIT to electrical stimulation. The current density maps of three canine brains were calculated from the measured magnetic flux density data. The absolute current density values of brain tissues, including gray matter, white matter, and cerebrospinal fluid were compared to assess the active regions during DBS. The resulting current density in different tissue types may provide useful information about current pathways and volume activation for adjusting surgical planning and understanding the therapeutic effects of DBS.

  9. In vivo mapping of current density distribution in brain tissues during deep brain stimulation (DBS)

    Science.gov (United States)

    Sajib, Saurav Z. K.; Oh, Tong In; Kim, Hyung Joong; Kwon, Oh In; Woo, Eung Je

    2017-01-01

    New methods for in vivo mapping of brain responses during deep brain stimulation (DBS) are indispensable to secure clinical applications. Assessment of current density distribution, induced by internally injected currents, may provide an alternative method for understanding the therapeutic effects of electrical stimulation. The current flow and pathway are affected by internal conductivity, and can be imaged using magnetic resonance-based conductivity imaging methods. Magnetic resonance electrical impedance tomography (MREIT) is an imaging method that can enable highly resolved mapping of electromagnetic tissue properties such as current density and conductivity of living tissues. In the current study, we experimentally imaged current density distribution of in vivo canine brains by applying MREIT to electrical stimulation. The current density maps of three canine brains were calculated from the measured magnetic flux density data. The absolute current density values of brain tissues, including gray matter, white matter, and cerebrospinal fluid were compared to assess the active regions during DBS. The resulting current density in different tissue types may provide useful information about current pathways and volume activation for adjusting surgical planning and understanding the therapeutic effects of DBS.

  10. Density-functional theory investigation of Al pitting corrosion in electrolyte containing chloride ions

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Min [National Center for Materials Service Safety, University of Science and Technology Beijing, Beijing 100083 (China); Jin, Ying, E-mail: yjin@ustb.edu.cn [National Center for Materials Service Safety, University of Science and Technology Beijing, Beijing 100083 (China); Zhang, Chuanhui [National Center for Materials Service Safety, University of Science and Technology Beijing, Beijing 100083 (China); Leygraf, Christofer [Division of Surface and Corrosion Science, Department of Chemistry, KTH Royal Institute of Technology, SE-10044 Stockholm (Sweden); Wen, Lei [National Center for Materials Service Safety, University of Science and Technology Beijing, Beijing 100083 (China)

    2015-12-01

    Highlights: • Cl{sup −} led to the elongation of Al−O bond and the weakened binding between Al layers in scenario i. • Al−O interaction weakened whereas an intensive hybridization peak at −0.18 Ha between Al-3p with Cl-3p showed in scenario ii. • Substructures such as AlCl{sub 3} and Al{sub 2}Cl{sub 5} formed in scenario iii when the Cl{sup −} coverage was larger than 2/3 ML of a monolayer. - Abstract: The behavior of chloride ions (Cl{sup −}) and oxygen species (the oxygen atom, O or molecular oxygen, O{sub 2}) on Al(1 1 1) surface has been studied by density functional theory calculations in order to deepen the molecular understanding of fundamental processes leading to pitting of aluminum (Al). The adsorption behavior of individual species, Cl{sup −}, O atom and O{sub 2} was determined first. Subsequently, three possible scenarios in different pitting stages were modeled exploring the repassivation and dissolution of Al in neutral electrolyte containing Cl{sup −}. In scenario i, it was found that Cl{sup −} can hardly destroy even an O-monolayer on Al(1 1 1) surface, however may lead to the elongation of Al−O bond and the weakened binding between the first Al layer and subsequent Al layers. Both O{sub 2} and Cl{sup −} were simultaneously introduced onto Al(1 1 1) in scenario ii. The result showed a weakened Al−O interaction and an intensive hybridization peak at −0.18 Ha between Al-3p with Cl-3p suggesting insufficient repassivation behavior of Al under this condition. Finally, scenario iii mimicked different local environmental conditions in pits formed on Al. At low coverage of Cl{sup −}, chloride ions had little effect on surface relaxation. The interaction among chloride ions and Al surface became stronger as Cl{sup −} coverage increased. Surface Al atoms dissolved gradually and substructures such as AlCl{sub 3} and Al{sub 2}Cl{sub 5} formed when the coverage was larger than 2/3 ML of a monolayer.

  11. Inertial electron instability of current-carrying low-density plasma

    International Nuclear Information System (INIS)

    Basova, S.V.; Varentsova, S.A.; Gordeev, A.V.; Gulin, A.V.; Shuvaev, V.Yu.

    1991-01-01

    Current-carrying low-density plasma instability is investigated taking into account electron inertia at stationary ions. By analytic and numeric methods it is shown that in a constant density plasma the instability occurs under condition that the value H-tilde=H+(m e c/e)dv/dr, where H is the magnetic field, v - electron current velocity, changes the sign as the function of coordinate. Numeric calculations allowed to derive the increments for specific current configurations

  12. Role of perfluoropolyether-based electrolytes in lithium metal batteries: Implication for suppressed Al current collector corrosion and the stability of Li metal/electrolytes interfaces

    Science.gov (United States)

    Cong, Lina; Liu, Jia; Armand, Michel; Mauger, Alain; Julien, Christian M.; Xie, Haiming; Sun, Liqun

    2018-03-01

    The development of safe and high performance lithium metal batteries represents a major technological challenge for this new century. Historically, intrinsic instabilities of conventional liquid organic electrolytes induced battery failures and safety issues that hinder the practical utilization of advanced rechargeable lithium metal batteries. Herein, we report a multifunctional perfluoropolyether-based liquid polymer electrolyte (PFPE-MC/LiTFSI), presenting a unique "anion-solvent" interaction. This interaction optimizes the interfacial chemistry of lithium metal batteries, which effectively inhibits the corrosion of aluminum current collectors, suppresses lithium dendrite growth, and also facilitates the formation of a thin and stable SEI layer on Li anode. Even at a high current density of 0.7 mA cm-2, the lithium dendrites do not form after 1360 h of continuous operation. The LiFePO4|PFPE-MC/LiTFSI|Li cell delivers a stable cycling performance with over 99.9% columbic efficiency either at ambient temperature or high temperature, which is significantly superior to those using traditional carbonate electrolytes. In addition, PFPE-MC/LiTFSI electrolyte also possesses eye-catching properties, such as being non-flammable, non-volatile, non-hygroscopic, and existing in the liquid state between -90 °C and 200 °C, which further ensures the high safety of the lithium metal batteries, making this electrolyte promising for the development of high energy lithium metal batteries.

  13. Development of an Accelerated Test Method for the Determination of Susceptibility to Atmospheric Corrosion

    Science.gov (United States)

    Ambrose, John R.

    1991-01-01

    The theoretical rationale is presented for use of a repetitive cyclic current reversal voltammetric technique for characterization of localized corrosion processes, including atmospheric corrosion. Applicability of this proposed experimental protocol is applied to characterization of susceptibility to crevice and pitting corrosion, atmospheric corrosion and stress corrosion cracking. Criteria upon which relative susceptibility is based were determined and tested using two iron based alloys commonly in use at NASA-Kennedy; A36 (a low carbon steel) and 4130 (a low alloy steel). Practicality of the procedure was demonstrated by measuring changes in anodic polarization behavior during high frequency current reversal cycles of 25 cycles per second with 1 mA/sq cm current density amplitude in solutions containing Cl anions. The results demonstrated that, due to excessive polarization which affects conductivity of barrier corrosion product layers, A36 was less resistant to atmospheric corrosion than its 4130 counterpart; behavior which was also demonstrated during exposure tests.

  14. Electrolytic deposition and corrosion resistance of Zn–Ni coatings ...

    Indian Academy of Sciences (India)

    Zn–Ni coatings were deposited under galvanostatic conditions on steel substrate (OH18N9). The influence of current density of deposition on the surface morphology, chemical and phase composition was investigated. The corrosion resistance of Zn–Ni coatings obtained at current density 10–25 mA cm-2 are measured, ...

  15. Electrolytic deposition and corrosion resistance of Zn–Ni coatings

    Indian Academy of Sciences (India)

    Zn–Ni coatings were deposited under galvanostatic conditions on steel substrate (OH18N9). The influence of current density of deposition on the surface morphology, chemical and phase composition was investigated. The corrosion resistance of Zn–Ni coatings obtained at current density 10–25 mA cm-2 are measured, ...

  16. Corrosion in Electronics

    DEFF Research Database (Denmark)

    Ambat, Rajan; Gudla, Helene Virginie Conseil; Verdingovas, Vadimas

    2017-01-01

    and high density packing combined with the use of several materials, which can undergo electrochemical corrosion in the presence of water film formed due to humidity exposure and bias conditions on the PCBA surface. This article provides a short review of the corrosion reliability issues of electronics due...... to the use of electronics under varying humidity conditions. Important PCBA aspects, which are fundamental to the corrosion cell formation under humid conditions, are discussed. Effect of hygroscopic residues from the process and service and their role in assisting water film build up and corrosion...... is presented. Various failure modes resulting from the corrosion and influence factors are discussed including humid and gaseous conditions....

  17. Experimental study on electrochemical corrosion of FV520B in natural gas environment

    Directory of Open Access Journals (Sweden)

    Juyi Pan

    Full Text Available The electrochemical corrosion of the FV520B stainless steel for natural gas compressor impeller is studied by means of the uniform experimental method. The electrochemical corrosion potential, current density and Tafel slope of the material are measured, and the polarization resistance is solved. The experimental results show that FV520B material does not appear passivation area in the presence of the natural gas environment with H2S, and the material has been in the activation and dissolved state. When the temperature is below 130 °C, the corrosion is dominated by the process of the anode reaction, the concentration of H2S is the decisive factor to determine the occurrence of stress corrosion, the increase of H2S concentration significantly accelerates the corrosion process of the specimen, CO2 inhibits the occurrence of the stress corrosion to a certain extent. Keywords: FV520B, Stress corrosion, Electrochemical corrosion, Natural gas

  18. Studies on plant extracts as corrosion inhibitors for mild steel in air saturated water

    International Nuclear Information System (INIS)

    Mohamad Daud; Abdul Razak Daud; Zainal Abidin Sidi

    1988-01-01

    The effectiveness in inhibiting corrosion by garlic, soya bean, and tobacco extracts and their combinations in air saturated water at ambient temperature were studied by using electrochemical corrosion test. The range of inhibitor concentration studied was from 0.1 to 1.0 g/l. The variations of corrosion potential and corrosion current density was recorded and the results showed that the extracts have inhibitive properties in the corrosion of mild stee. The effectiveness of the inhibitors is in the following order: extract mixture > tobacco > garlic > soya bean extracts. (author)

  19. Technique of Critical Current Density Measurement of Bulk Superconductor with Linear Extrapolation Method

    International Nuclear Information System (INIS)

    Adi, Wisnu Ari; Sukirman, Engkir; Winatapura, Didin S.

    2000-01-01

    Technique of critical current density measurement (Jc) of HTc bulk ceramic superconductor has been performed by using linear extrapolation with four-point probes method. The measurement of critical current density HTc bulk ceramic superconductor usually causes damage in contact resistance. In order to decrease this damage factor, we introduce extrapolation method. The extrapolating data show that the critical current density Jc for YBCO (123) and BSCCO (2212) at 77 K are 10,85(6) Amp.cm - 2 and 14,46(6) Amp.cm - 2, respectively. This technique is easier, simpler, and the use of the current flow is low, so it will not damage the contact resistance of the sample. We expect that the method can give a better solution for bulk superconductor application. Key words. : superconductor, critical temperature, and critical current density

  20. The actual current density of gas-evolving electrodes—Notes on the bubble coverage

    International Nuclear Information System (INIS)

    Vogt, H.

    2012-01-01

    All investigations of electrochemical reactors with gas-evolving electrodes must take account of the fact that the actual current density controlling cell operation commonly differs substantially from the nominal current density used for practical purposes. Both quantities are interrelated by the fractional bubble coverage. This parameter is shown to be affected by a large number of operational quantities. However, available relationships of the bubble coverage take account only of the nominal current density. A further essential insufficiency is their inconsistency with reality for very large values of the bubble coverage being of relevance for operation conditions leading to anode effects. An improved relationship applicable to the total range is proposed.

  1. Estimation of current density distribution of PAFC by analysis of cell exhaust gas

    Energy Technology Data Exchange (ETDEWEB)

    Kato, S.; Seya, A. [Fuji Electric Co., Ltd., Ichihara-shi (Japan); Asano, A. [Fuji Electric Corporate, Ltd., Yokosuka-shi (Japan)

    1996-12-31

    To estimate distributions of Current densities, voltages, gas concentrations, etc., in phosphoric acid fuel cell (PAFC) stacks, is very important for getting fuel cells with higher quality. In this work, we leave developed a numerical simulation tool to map out the distribution in a PAFC stack. And especially to Study Current density distribution in the reaction area of the cell, we analyzed gas composition in several positions inside a gas outlet manifold of the PAFC stack. Comparing these measured data with calculated data, the current density distribution in a cell plane calculated by the simulation, was certified.

  2. Critical current density of domain wall oscillation due to spin-transfer torque

    Energy Technology Data Exchange (ETDEWEB)

    Taniguchi, T; Imamura, H, E-mail: tomohiro-taniguchi@aist.go.jp, E-mail: h-imamura@aist.go.jp [Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology, 1-1-1 Umezono, Tsukuba, Ibaraki 305-8568 (Japan)

    2011-04-01

    The domain wall oscillation due to spin-transfer torque was studied by numerically solving the Landau-Lifshitz-Gilbert (LLG) equation. For a domain wall whose rotation angle {theta}{sub max} is less than 180{sup 0}, we found the existence of the critical current density above which the magnetization dynamics are induced. We studied the dependence of the critical current density on the rotation angle {theta}{sub max} and found that the critical current density is proportional to 180{sup 0} - {theta}{sub max}.

  3. Stray current induced corrosion in lightning rod cables of 525 kV power lines towers: a case study

    Directory of Open Access Journals (Sweden)

    Wojcicki, F. R.

    2003-12-01

    Full Text Available With the growth of several areas in modem society, the necessity to generate and carry electrical energy to big cities has greatly increased. Cables supported by power towers with galvanized steel foundation usually carry energy. As the foundations are underground they may cause high rates of corrosion. These are usually detected by a conventional potential measurement using a Cu/CuSO4 reference electrode. It is believed that corrosion results from stray currents that flow through the ground to close the loop between neighboring towers. Stray currents originate in the lightning rod cables of the power line towers, induced by the strong electromagnetic and electric fields of the energized power lines. The intensity and direction of those currents were measured, indicating substantial values of both their AC and DC components. The potential of the tower ground system, measured in the perpendicular direction of the main axis of the power line, was plotted as a function of the distance to the tower base. The results clearly indicated the tendency to corrosive attack in the anodic towers as reflected by the slope of the plot, whereas no signs of corrosion could be found in the reverse slope, confirming the visual inspection of the foundation. The profile of the potential plots could be changed providing the electric insulation of the lightning rod cable.

    Con el crecimiento de varias áreas en la sociedad moderna, la necesidad de generar y conducir la energía eléctrica a las grandes ciudades ha aumentado enormemente. La energía, normalmente, se transporta por cables sostenidos por torres de energía con base de acero galvanizado. Cuando las bases son subterráneas, pueden ocasionar altas tasas de corrosión. Estas, normalmente, se detectan por la medida convencional del potencial empleando un electrodo de referencia de Cu/CuSO4. Se cree que la corrosión es el resultado de corrientes perdidas que fluyen a través de la

  4. Simulations of current density profile control using lower hybrid current drive in the TdeV tokamak

    International Nuclear Information System (INIS)

    Fuchs, V.; Bonoli, P.T.; Shkarofsky, I.P.; Cote, A.; Demers, Y.; Janicki, C.

    1995-01-01

    The physics basis of a simulation model for lower hybrid current drive (LHCD) is discussed. Issues associated with LH power deposition - wave propagation, mode conversion and cut-offs in toroidal geometry, as well as linear and quasi-linear Landau damping - are analysed. A simulation model (ACCOME) is applied to the LHCD experiment now operating on the Tokamak de Varennes (TdeV). The profiles and values of density and temperature needed as inputs to ACCOME are taken from the experiment. The predictions of current density and loop voltage from ACCOME are then compared with experimental LHCD results. Possible LH current profile control experiments are also analysed for TdeV using composite LH spectra to control the location of RF power deposition. Finally, the relevance of these current profile control results to future devices is discussed and an example is shown for ITER-like parameters. (author). 44 refs, 15 figs, 4 tabs

  5. Study and characterization by acoustic emission and electrochemical measurements of the stress corrosion cracking of the 304L steel in chloride environment; Etude et caracterisation par emission acoustique et mesures electrochimiques de la corrosion sous contrainte de l'acier 304L en milieu chlorure

    Energy Technology Data Exchange (ETDEWEB)

    Tshimombo, A.; Delaunois, F. [UMONS, Faculte Polytechnique, Mons (Belgium); Tshimombo, A.; Idrissi, H. [INSA-Lyon, Laboratoire MATEIS, 69 - Villeurbanne (France)

    2010-03-15

    As the prediction of stress corrosion cracking risks is a matter of interest, the authors report the development and the application of the acoustic emission technique to characterize and control this corrosion mode. They describe the choice of an accelerated test as experiment conditions, comment and discuss the correlation between acoustic emission and corrosion current density measurements

  6. Effect of coating current density on the wettability of electrodeposited copper thin film on aluminum substrate

    Directory of Open Access Journals (Sweden)

    Arun Augustin

    2016-09-01

    Full Text Available Copper is the only one solid metal registered by the US Environmental Protection Agency as an antimicrobial touch surface. In touch surface applications, wettability of the surface has high significance. The killing rate of the harmful microbes depends on the wetting of pathogenic solution. Compared to the bulk copper, coated one on aluminum has the advantage of economic competitiveness and the possibility of manufacturing complex shapes. In the present work, the copper coating on the aluminum surface has successfully carried out by electrodeposition using non cyanide alkaline bath. To ensure good adhesion strength, the substrate has been pre-zincated prior to copper deposition. The coating current density is one of the important parameters which determine the nucleation density of the copper on the substrate. To understand the effect of current density on wettability, the coating has done at different current densities in the range of 3 A dm−2 to 9 A dm−2 for fixed time interval. The grain size has been measured from TEM micrographs and showed that as current density increases, grain size reduces from 62 nm to 35 nm. Since the grain size reduces, grain boundary volume has increases. As a result the value of strain energy (calculated by Williamson–Hall method has increased. The density of nodular morphology observed in SEM analysis has been increased with coating current density. Further, wettability studies with respect to double distilled water on the electrodeposited copper coatings which are coated at different current densities are carried out. At higher current density the coating is more wettable by water because at these conditions grain size of the coating decreases and morphology of grain changes to a favorable dense nodularity.

  7. Effect of via depth on the TSV filling process for different current densities

    Science.gov (United States)

    Wang, Feng; Zhao, Zhipeng; Nie, Nantian; Wang, Fuliang; Zhu, Wenhui

    2018-04-01

    Through-silicon-via (TSV) filling with optimum electrodeposition parameters is still a challenge in the industry, especially for via with different depths. Herein, the effects of via depth on optimum current density and filling patterns were investigated. It was found that the deeper the via, the lower the optimum current density. At low current density (4 mA cm-2), the via depth only affects the size of the defect, but does not change the filling pattern. However, at medium current density (7 mA cm-2), the filling pattern changes from super-conformal filling to sub-conformal filling with the increase of via depth, the pinch-off position remaining constant at a depth of about 70 µm from the top surface. Simulations of the TSV filling process using COMSOL modeling software revealed that the local concentration of additives, which is affected by the via depth, determine the morphology of the electrodeposition, matching well the experimental results.

  8. Preparation and characterization of high-Tc superconducting thin films with high critical current densities

    International Nuclear Information System (INIS)

    Vase, P.

    1991-08-01

    The project was carried out in relation to possible cable and electronics applications of high-T c materials. Laser ablation was used as the deposition technique because of its stoichiometry conservation. Films were made in the YBa 2 Cu 3 O 7 compound due to its relatively simple stoichiometry compared to other High-T c compounds. Much attention was paid to the critical current density. A very high critical current density was reached. By using texture analysis by X-ray diffraction, it was found that films with high critical current densities were epitaxial, while films with low critical current densities contained several crystalline orientations. Four techniques for patterning the films were used - photo lithography and wet etch, laser ablation lithography, laser writing and electron beam lithography and ion milling. Sub-micron patterning has been demonstrated without degradation of the superconducting properties. The achieved patterning resolution is sufficient for preparation of many superconducting components. (AB)

  9. Dependence of the Spin Transfer Torque Switching Current Density on the Exchange Stiffness Constant

    OpenAIRE

    You, Chun-Yeol

    2012-01-01

    We investigate the dependence of the switching current density on the exchange stiffness constant in the spin transfer torque magnetic tunneling junction structure with micromagnetic simulations. Since the widely accepted analytic expression of the switching current density is based on the macro-spin model, there is no dependence of the exchange stiffness constant. When the switching is occurred, however, the spin configuration forms C-, S-type, or complicated domain structures. Since the spi...

  10. Maximum current density and beam brightness achievable by laser-driven electron sources

    Science.gov (United States)

    Filippetto, D.; Musumeci, P.; Zolotorev, M.; Stupakov, G.

    2014-02-01

    This paper discusses the extension to different electron beam aspect ratio of the Child-Langmuir law for the maximum achievable current density in electron guns. Using a simple model, we derive quantitative formulas in good agreement with simulation codes. The new scaling laws for the peak current density of temporally long and transversely narrow initial beam distributions can be used to estimate the maximum beam brightness and suggest new paths for injector optimization.

  11. Maximum current density and beam brightness achievable by laser-driven electron sources

    Directory of Open Access Journals (Sweden)

    D. Filippetto

    2014-02-01

    Full Text Available This paper discusses the extension to different electron beam aspect ratio of the Child-Langmuir law for the maximum achievable current density in electron guns. Using a simple model, we derive quantitative formulas in good agreement with simulation codes. The new scaling laws for the peak current density of temporally long and transversely narrow initial beam distributions can be used to estimate the maximum beam brightness and suggest new paths for injector optimization.

  12. Expanding the reduced-current approach for thermoelectric generators to achieve higher volumetric power density

    DEFF Research Database (Denmark)

    Wijesooriyage, Waruna Dissanayaka; Rosendahl, Lasse

    2015-01-01

    current approach (RCA) for TE module design, where the same current is induced through the p and n legs of the thermoelectric generator (TEG). The current density of each element is manipulated by changing the area of both legs. This technique leads to a TE module architecture based on the most efficient...... configuration of both p and n legs. In the current paper, we apply an extended version of this technique, to show how a TE module with a higher volumetric power density can be designed, compared to the original RCA. Our studies indicate that for some combinations of p and n material properties, optima yielding...

  13. Development of Eddy Current Technique for the Detection of Stress Corrosion Cracking in Space Shuttle Primary Reaction Control Thrusters

    Science.gov (United States)

    Wincheski, Buzz; Simpson, John; Koshti, Ajay

    2006-01-01

    A recent identification of stress corrosion cracking in the Space Shuttle Primary Reaction Control System (PRCS) thrusters triggered an extensive nondestructive evaluation effort to develop techniques capable of identifying such damage on installed shuttle hardware. As a part of this effort, specially designed eddy current probes inserted into the acoustic cavity were explored for the detection of such flaws and for evaluation of the remaining material between the crack tip and acoustic cavity. The technique utilizes two orthogonal eddy current probes which are scanned under stepper motor control in the acoustic cavity to identify cracks hidden with as much as 0.060 remaining wall thickness to the cavity. As crack growth rates in this area have been determined to be very slow, such an inspection provides a large safety margin for continued operation of the critical shuttle hardware. Testing has been performed on thruster components with both actual and fabricated defects. This paper will review the design and performance of the developed eddy current inspection system. Detection of flaws as a function of remaining wall thickness will be presented along with the proposed system configuration for depot level or on-vehicle inspection capabilities.

  14. Corrosion and corrosion control

    International Nuclear Information System (INIS)

    Khanna, A.S.; Totlani, M.K.

    1995-01-01

    Corrosion has always been associated with structures, plants, installations and equipment exposed to aggressive environments. It effects economy, safety and product reliability. Monitoring of component corrosion has thus become an essential requirement for the plant health and safety. Protection methods such as appropriate coatings, cathodic protection and use of inhibitors have become essential design parameters. High temperature corrosion, especially hot corrosion, is still a difficult concept to accommodate in corrosion allowance; there is a lack of harmonized system of performance testing of materials at high temperatures. In order to discuss and deliberate on these aspects, National Association for Corrosion Engineers International organised a National Conference on Corrosion and its Control in Bombay during November 28-30, 1995. This volume contains papers presented at the symposium. Paper relevant to INIS is indexed separately. refs., figs., tabs

  15. Corrosion of Steel in High-Strength Self-Compacting Concrete Exposed to Saline Environment

    Directory of Open Access Journals (Sweden)

    Hana A. Yousif

    2014-01-01

    Full Text Available A research work was carried out to investigate the effectiveness of high-strength self-compacting concrete (SF-R in controlling corrosion of embedded steel. Reinforced concrete cylinders and plain cubes were subjected to 5% NaCl solution. Slump flow, J-ring, V-funnel, compressive strength, electrical resistance, and electrochemical tests were conducted. Corrosion resisting characteristics of steel were examined by monitoring corrosion potential, polarization resistance, corrosion currents, and Tafel plots. The relationship between corrosion current density and corrosion potential was established. Results were compared with characteristics of a grade 40 MPa reference concrete (R and grade 70 MPa conventional self-compacting concrete (SP. Results indicated that at 270 days of exposure, the corrosion currents for steel in SF-R were 63- and 16-fold lower compared to those of steel in R and SP concretes, respectively. This concrete showed a considerable increase in electrical resistance and compressive strength of 96 MPa at 28 days of exposure. Relying on corrosion risk classification based on corrosion current densities and corrosion potentials, the steel in SF-R concrete is definitely in the passive condition. The splendid durability performance of steel in SF-R concrete linked to adorable self-compacting features could furnish numerous opportunities for future structural applications in severe environmental conditions.

  16. Software Toolbox for Low-Frequency Conductivity and Current Density Imaging Using MRI.

    Science.gov (United States)

    Sajib, Saurav Z K; Katoch, Nitish; Kim, Hyung Joong; Kwon, Oh In; Woo, Eung Je

    2017-11-01

    Low-frequency conductivity and current density imaging using MRI includes magnetic resonance electrical impedance tomography (MREIT), diffusion tensor MREIT (DT-MREIT), conductivity tensor imaging (CTI), and magnetic resonance current density imaging (MRCDI). MRCDI and MREIT provide current density and isotropic conductivity images, respectively, using current-injection phase MRI techniques. DT-MREIT produces anisotropic conductivity tensor images by incorporating diffusion weighted MRI into MREIT. These current-injection techniques are finding clinical applications in diagnostic imaging and also in transcranial direct current stimulation (tDCS), deep brain stimulation (DBS), and electroporation where treatment currents can function as imaging currents. To avoid adverse effects of nerve and muscle stimulations due to injected currents, conductivity tensor imaging (CTI) utilizes B1 mapping and multi-b diffusion weighted MRI to produce low-frequency anisotropic conductivity tensor images without injecting current. This paper describes numerical implementations of several key mathematical functions for conductivity and current density image reconstructions in MRCDI, MREIT, DT-MREIT, and CTI. To facilitate experimental studies of clinical applications, we developed a software toolbox for these low-frequency conductivity and current density imaging methods. This MR-based conductivity imaging (MRCI) toolbox includes 11 toolbox functions which can be used in the MATLAB environment. The MRCI toolbox is available at http://iirc.khu.ac.kr/software.html . Its functions were tested by using several experimental datasets, which are provided together with the toolbox. Users of the toolbox can focus on experimental designs and interpretations of reconstructed images instead of developing their own image reconstruction softwares. We expect more toolbox functions to be added from future research outcomes. Low-frequency conductivity and current density imaging using MRI includes

  17. Current density imaging using directly measured harmonic Bz data in MREIT.

    Science.gov (United States)

    Park, Chunjae; Kwon, Oh In

    2013-01-01

    Magnetic resonance electrical impedance tomography (MREIT) measures magnetic flux density signals through the use of a magnetic resonance imaging (MRI) in order to visualize the internal conductivity and/or current density. Understanding the reconstruction procedure for the internal current density, we directly measure the second derivative of Bz data from the measured k-space data, from which we can avoid a tedious phase unwrapping to obtain the phase signal of Bz . We determine optimal weighting factors to combine the derivatives of magnetic flux density data, [Symbol: see text](2) Bz , measured using the multi-echo train. The proposed method reconstructs the internal current density using the relationships between the induced internal current and the measured [Symbol: see text](2) Bz data. Results from a phantom experiment demonstrate that the proposed method reduces the scanning time and provides the internal current density, while suppressing the background field inhomogeneity. To implement the real experiment, we use a phantom with a saline solution including a balloon, which excludes other artifacts by any concentration gradient in the phantom.

  18. Current Density Imaging Using Directly Measured Harmonic Bz Data in MREIT

    Directory of Open Access Journals (Sweden)

    Chunjae Park

    2013-01-01

    Full Text Available Magnetic resonance electrical impedance tomography (MREIT measures magnetic flux density signals through the use of a magnetic resonance imaging (MRI in order to visualize the internal conductivity and/or current density. Understanding the reconstruction procedure for the internal current density, we directly measure the second derivative of Bz data from the measured k-space data, from which we can avoid a tedious phase unwrapping to obtain the phase signal of Bz. We determine optimal weighting factors to combine the derivatives of magnetic flux density data, ∇2Bz, measured using the multi-echo train. The proposed method reconstructs the internal current density using the relationships between the induced internal current and the measured ∇2Bz data. Results from a phantom experiment demonstrate that the proposed method reduces the scanning time and provides the internal current density, while suppressing the background field inhomogeneity. To implement the real experiment, we use a phantom with a saline solution including a balloon, which excludes other artifacts by any concentration gradient in the phantom.

  19. Anisotropy and intergrain current density in oriented grained bulk YBa2Cu3Ox superconductor

    International Nuclear Information System (INIS)

    Selvamanickam, V.; Salama, K.

    1990-01-01

    The intergrain transport current density and its anisotropy have been studied in oriented grained bulk YBa 2 Cu 3 O x superconductors fabricated by the liquid phase processing method. Current density measurements were performed on oriented grained samples with the transport current aligned at different angles to the a-b plane. In these measurements, the transport current passed through several oriented grain boundaries. The results indicate that the critical current density drops rapidly when the transport current flows at small angles to the a-b plane and then decreases slowly at larger angles. At 77 K and zero magnetic field, an anisotropy ratio of about 25 is observed between J c along a-b plane and that perpendicular to the plane. Further, the critical current density in these samples is found to depend weakly on magnetic field even though the current crosses grain boundaries. These results support the notion that grain boundaries of these superconductors are different in nature from those of solid-state sintered samples.

  20. Formation of ion beam with high current density for micro irradiation techniques

    Energy Technology Data Exchange (ETDEWEB)

    Romanenko, A.V.; Ponomarev, A.G.

    2015-04-01

    The paper describes a study of the ion beam formation for irradiation of microareas of construction materials with individual grains. A numerical simulation of the microbeam formation was performed with profiles of current density distribution close to rectangular to obtain uniform dose. Ion beams with the total current on the target 10–100 nA were considered. An approach for beam focusing with energy variation without moving a sample was considered. The ability to create current density distributions close to uniform in the target plane was experimentally validated.

  1. High current densities enable exoelectrogens to outcompete aerobic heterotrophs for substrate

    KAUST Repository

    Ren, Lijiao

    2014-08-05

    © 2014 Wiley Periodicals, Inc. Chemical oxygen demand (COD) removal rates could be described by first-order kinetics with respect to COD concentration at different current densities, even under open circuit conditions with no current generation. The COD concentration was reduced more quickly with current generation due to the greater consumption of substrate by exoelectrogens, and less substrate was lost to aerobic heterotrophs. Higher current densities enabled exoelectrogens to outcompete aerobic heterotrophs for substrate, allowing for increased coulombic efficiencies with current densities. © 2014 Wiley Periodicals, Inc. In mixed-culture microbial fuel cells (MFCs), exoelectrogens and other microorganisms compete for substrate. It has previously been assumed that substrate losses to other terminal electron acceptors over a fed-batch cycle, such as dissolved oxygen, are constant. However, a constant rate of substrate loss would only explain small increases in coulombic efficiencies (CEs, the fraction of substrate recovered as electrical current) with shorter cycle times, but not the large increases in CE that are usually observed with higher current densities and reduced cycle times. To better understand changes in CEs, COD concentrations were measured over time in fed-batch, single-chamber, air-cathode MFCs at different current densities (external resistances). COD degradation rates were all found to be first-order with respect to COD concentration, even under open circuit conditions with no current generation (first-order rate constant of 0.14±0.01h-1). The rate of COD removal increased when there was current generation, with the highest rate constant (0.33±0.02h-1) obtained at the lowest external resistance (100Ω). Therefore, as the substrate concentration was reduced more quickly due to current generation, the rate of loss of substrate to non-exoelectrogens decreased due to this first-order substrate-concentration dependence. As a result, coulombic

  2. First current density measurements in the ring current region using simultaneous multi-spacecraft CLUSTER-FGM data

    Directory of Open Access Journals (Sweden)

    C. Vallat

    2005-07-01

    Full Text Available The inner magnetosphere's current mapping is one of the key elements for current loop closure inside the entire magnetosphere. A method for directly computing the current is the multi-spacecraft curlometer technique, which is based on the application of Maxwell-Ampère's law. This requires the use of four-point magnetic field high resolution measurements. The FGM experiment on board the four Cluster spacecraft allows, for the first time, an instantaneous calculation of the magnetic field gradients and thus a measurement of the local current density. This technique requires, however, a careful study concerning all the factors that can affect the accuracy of the J estimate, such as the tetrahedral geometry of the four spacecraft, or the size and orientation of the current structure sampled. The first part of this paper is thus providing a detailed analysis of the method accuracy, and points out the limitations of this technique in the region of interest. The second part is an analysis of the ring current region, which reveals, for the first time, the large latitudinal extent of the ring current, for all magnetic activity levels, as well as the latitudinal evolution of the perpendicular (and parallel components of the current along the diffuse auroral zone. Our analysis also points out the sharp transition between two distinct plasma regions, with the existence of high diamagnetic currents at the interface, as well as the filamentation of the current inside the inner plasma sheet. A statistical study over multiple perigee passes of Cluster (at about 4 RE from the Earth reveals the azimuthal extent of the partial ring current. It also reveals that, at these distances and all along the evening sector, there isn't necessarily a strong dependence of the local current density value on the magnetic activity level. This is a direct consequence of the ring current morphology evolution, as well as the relative

  3. First current density measurements in the ring current region using simultaneous multi-spacecraft CLUSTER-FGM data

    Directory of Open Access Journals (Sweden)

    C. Vallat

    2005-07-01

    Full Text Available The inner magnetosphere's current mapping is one of the key elements for current loop closure inside the entire magnetosphere. A method for directly computing the current is the multi-spacecraft curlometer technique, which is based on the application of Maxwell-Ampère's law. This requires the use of four-point magnetic field high resolution measurements. The FGM experiment on board the four Cluster spacecraft allows, for the first time, an instantaneous calculation of the magnetic field gradients and thus a measurement of the local current density. This technique requires, however, a careful study concerning all the factors that can affect the accuracy of the J estimate, such as the tetrahedral geometry of the four spacecraft, or the size and orientation of the current structure sampled. The first part of this paper is thus providing a detailed analysis of the method accuracy, and points out the limitations of this technique in the region of interest. The second part is an analysis of the ring current region, which reveals, for the first time, the large latitudinal extent of the ring current, for all magnetic activity levels, as well as the latitudinal evolution of the perpendicular (and parallel components of the current along the diffuse auroral zone. Our analysis also points out the sharp transition between two distinct plasma regions, with the existence of high diamagnetic currents at the interface, as well as the filamentation of the current inside the inner plasma sheet. A statistical study over multiple perigee passes of Cluster (at about 4 RE from the Earth reveals the azimuthal extent of the partial ring current. It also reveals that, at these distances and all along the evening sector, there isn't necessarily a strong dependence of the local current density value on the magnetic activity level. This is a direct consequence of the ring current morphology evolution, as well as the relative positioning of the spacecraft with respect to

  4. Gauge-Origin Independent Calculations of the Anisotropy of the Magnetically Induced Current Densities.

    Science.gov (United States)

    Fliegl, Heike; Jusélius, Jonas; Sundholm, Dage

    2016-07-21

    Gauge-origin independent current density susceptibility tensors have been computed using the gauge-including magnetically induced current (GIMIC) method. The anisotropy of the magnetically induced current density (ACID) functions constructed from the current density susceptibility tensors are therefore gauge-origin independent. The ability of the gauge-origin independent ACID function to provide quantitative information about the current flow along chemical bonds has been assessed by integrating the cross-section area of the ACID function in the middle of chemical bonds. Analogously, the current strength susceptibility passing a given plane through the molecule is obtained by numerical integration of the current flow parallel to the normal vector of the integration plane. The cross-section area of the ACID function is found to be strongly dependent on the exact location of the integration plane, which is in sheer contrast to the calculated ring-current strength susceptibilities that are practically independent of the chosen position of the integration plane. The gauge-origin independent ACID functions plotted for different isosurface values show that a visual assessment of the current flow and degree of aromaticity depends on the chosen isosurface. The present study shows that ACID functions are not an unambiguous means to estimate the degree of molecular aromaticity according to the magnetic criterion and to determine the current pathway of complex molecular rings.

  5. Microstructure and critical current density in high-Tc metal oxide superconductors

    International Nuclear Information System (INIS)

    Johnson, S.M.; Gusman, M.I.

    1992-03-01

    Superconductor powders in the U-Ba-Cu-O (YBCO) and Bi-Pb-Sr-Ca-Cu-O (BSCCO) systems were synthesized by freeze-drying. Powders were characterized, and processed into samples for evaluation of superconducting behavior. Freeze-drying is attractive because the powders have high purity, are homogeneous, have a small size and are active. YBCO powders can be sintered to high density at 890 degrees C. Many compositions, processing approaches and heat treatments were explored in an effort to understand relations between microstructure and critical density, and to improve the critical current density. Powders were also formed into sputtering targets for coating preparation at Stanford University. The highest critical current density achieved with the YBCO powders was ∼15,000 A/cm 2 at 4.2K and 0.5T using powders treated to prevent carbon contamination. The BSCCO materials with the highest critical current density, ∼30,000 A/cm 2 at the same conditions were formed by heat treating melted and quenched samples. All critical current density measurements were made by Stanford University, a subcontractor to this effort. Stanford University also prepared coatings by off-axis magnetron sputtering

  6. Current density reversibly alters metabolic spatial structure of exoelectrogenic anode biofilms

    Science.gov (United States)

    Sun, Dan; Cheng, Shaoan; Zhang, Fang; Logan, Bruce E.

    2017-07-01

    Understanding how current densities affect electrogenic biofilm activity is important for wastewater treatment as current densities can substantially decrease at COD concentrations greater than those suitable for discharge to the environment. We examined the biofilm's response, in terms of viability and enzymatic activity, to different current densities using microbial electrolysis cells with a lower (0.7 V) or higher (0.9 V) added voltage to alter current production. Viability was assessed using florescent dyes, with dead cells identified on the basis of dye penetration due to a compromised cell outer-membrane (red), and live cells (intact membrane) fluorescing green. Biofilms operated with 0.7 V produced 2.4 ± 0.2 A m-2, and had an inactive layer near the electrode and a viable layer at the biofilm-solution interface. The lack of cell activity near the electrode surface was confirmed by using an additional dye that fluoresces only with enzymatic activity. Adding 0.9 V increased the current by 61%, and resulted in a single, more homogeneous and active biofilm layer. Switching biofilms between these two voltages produced outcomes associated with the new current rather than the previous biofilm conditions. These findings suggest that maintaining higher current densities will be needed to ensure long-term viability electrogenic biofilms.

  7. Research and development of an aimed magnetic lead current density-magnetic field diagnostic. Final report

    International Nuclear Information System (INIS)

    1985-01-01

    A diagnostics survey was made to provide a clear definition of advanced diagnostic needs and the limitations of current approaches in addressing those needs. Special attention was given to the adequacy with which current diagnostics are interfaced to signal processing/data acquisition devices and systems. Critical evaluations of selected alternative diagnostic techniques for future R and D activities are presented. The conceptual basis of the Aimed Magnetic Lead Gradiometric system as a current density/magnetic field diagnostic is established

  8. Inertial electron instability in low-density current-carrying plasmas

    International Nuclear Information System (INIS)

    Basova, S.V.; Varentsova, S.A.; Gordeev, A.V.; Gulin, A.V.; Shuvaev, V.Yu.

    1991-01-01

    The stability of a low-density current-carrying plasma with finite electron inertia and motionless ions is studied. It is shown analytically and numerically that an instability exists when the quantity H = H + (m e c/e)dv/dr changes sign as a function of position, where H is the magnetic field and v is the current drift velocity of the electrons. The growth rates for specific current configurations are obtained by numerical calculation

  9. Effect of current density and pH in obtaining the Ni-Fe alloy by electrodeposition; Efeito da densidade de corrente e pH na obtencao da liga Ni-Fe por eletrodeposicao

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Jose Anderson Machado; Raulino, Anamelia de Medeiros Dantas; Raulino, Jose Leonardo Costa; Campos, Ana Regina Nascimento; Prasad, Shiva; Santana, Renato Alexandre Costa de, E-mail: jmo.anderson@gmail.com, E-mail: anameliadantas@yahoo.com.br, E-mail: leonardo.jcr@hotmail.com, E-mail: arncampos@yahoo.com.br, E-mail: prasad@deq.ufcg.edu.br, E-mail: renatoacs@ufcg.edu.br [Universidade Federal de Campina Grande (UFCG), Cuite, PB (Brazil). Lab. de Eletroquimica e Corrosao

    2017-01-15

    Metallic coatings can be applied for different purposes, for example to improve the mechanical, catalytic, anti corrosive properties or simply to improve the decorative appearance. In the work the Fe-Ni alloys have been obtained by electrodeposition process using a simple electrolytic bath containing the reagents, nickel sulfate, iron sulfate and sodium tartrate. A complete experimental design 2{sup 2} , associated with the response surface methodology (RSM) technique was used as optimization tool. Chemical composition, current efficiency, surface morphology and electrochemical corrosion measures were performed. It was observed that a decrease in the pH favored an increase in iron and decrease in nickel contents in the alloy. The iron content influenced the alloy morphology. The best experiment showed an average corrosion resistance 5471.5 Ω.cm² and a corrosion current density 4.814x10{sup -6} A/cm². This experiment presented a composition of 70 wt% Ni and 30 wt% Fe in the alloy and an average deposition current efficiency of 58.7%. (author)

  10. Intelligence and EEG current density using low-resolution electromagnetic tomography (LORETA).

    Science.gov (United States)

    Thatcher, R W; North, D; Biver, C

    2007-02-01

    The purpose of this study was to compare EEG current source densities in high IQ subjects vs. low IQ subjects. Resting eyes closed EEG was recorded from 19 scalp locations with a linked ears reference from 442 subjects ages 5 to 52 years. The Wechsler Intelligence Test was administered and subjects were divided into low IQ (90 to or =120) groups. Low-resolution electromagnetic tomographic current densities (LORETA) from 2,394 cortical gray matter voxels were computed from 1-30 Hz based on each subject's EEG. Differences in current densities using t tests, multivariate analyses of covariance, and regression analyses were used to evaluate the relationships between IQ and current density in Brodmann area groupings of cortical gray matter voxels. Frontal, temporal, parietal, and occipital regions of interest (ROIs) consistently exhibited a direct relationship between LORETA current density and IQ. Maximal t test differences were present at 4 Hz, 9 Hz, 13 Hz, 18 Hz, and 30 Hz with different anatomical regions showing different maxima. Linear regression fits from low to high IQ groups were statistically significant (P microstates is hypothesized to explain the results.

  11. Focused current density imaging using internal electrode in magnetic resonance electrical impedance tomography (MREIT).

    Science.gov (United States)

    Jeong, Woo Chul; Sajib, Saurav; Kim, Hyung Joong; Kwon, Oh In

    2014-07-01

    Magnetic resonance electrical impedance tomography (MREIT) is an imaging modality capable of visualizing cross-sectional current density and/or conductivity distributions inside an electrically conducting object. It uses an MRI scanner to measure one component of the magnetic flux density induced by an externally injected current through a pair of surface electrodes. For the cases of deep brain stimulation (DBS), electroporation, and radio frequency (RF) ablation, internal electrodes can be used to improve the quality of the MREIT images. In this paper, we propose a new MREIT imaging method using internal electrodes to visualize a current density distribution within a local region around them. To evaluate its performance, we conducted and analyzed a series of numerical simulations and phantom imaging experiments. We compared the reconstructed current density images using the internal electrodes with the obtained using only the external electrodes. We found that the proposed method using the internal electrodes stably determines the current density in the focused region with better accuracy.

  12. Multishot echo-planar MREIT for fast imaging of conductivity, current density, and electric field distributions.

    Science.gov (United States)

    Chauhan, Munish; Vidya Shankar, Rohini; Ashok Kumar, Neeta; Kodibagkar, Vikram D; Sadleir, Rosalind

    2018-01-01

    Magnetic resonance electrical impedance tomography (MREIT) sequences typically use conventional spin or gradient echo-based acquisition methods for reconstruction of conductivity and current density maps. Use of MREIT in functional and electroporation studies requires higher temporal resolution and faster sequences. Here, single and multishot echo planar imaging (EPI) based MREIT sequences were evaluated to see whether high-quality MREIT phase data could be obtained for rapid reconstruction of current density, conductivity, and electric fields. A gel phantom with an insulating inclusion was used as a test object. Ghost artifact, geometric distortion, and MREIT correction algorithms were applied to the data. The EPI-MREIT-derived phase-projected current density and conductivity images were compared with simulations and spin-echo images as a function of EPI shot number. Good agreement among measures in simulated, spin echo, and EPI data was achieved. Current density errors were stable and below 9% as the shot number decreased from 64 to 2, but increased for single-shot images. Conductivity reconstruction relative contrast ratios were stable as the shot number decreased. The derived electric fields also agreed with the simulated data. The EPI methods can be combined successfully with MREIT reconstruction algorithms to achieve fast imaging of current density, conductivity, and electric field. Magn Reson Med 79:71-82, 2018. © 2017 International Society for Magnetic Resonance in Medicine. © 2017 International Society for Magnetic Resonance in Medicine.

  13. LORETA current source density for duration mismatch negativity and neuropsychological assessment in early schizophrenia.

    Directory of Open Access Journals (Sweden)

    Tomohiro Miyanishi

    Full Text Available INTRODUCTION: Patients with schizophrenia elicit cognitive decline from the early phase of the illness. Mismatch negativity (MMN has been shown to be associated with cognitive function. We investigated the current source density of duration mismatch negativity (dMMN, by using low-resolution brain electromagnetic tomography (LORETA, and neuropsychological performance in subjects with early schizophrenia. METHODS: Data were obtained from 20 patients meeting DSM-IV criteria for schizophrenia or schizophreniform disorder, and 20 healthy control (HC subjects. An auditory odd-ball paradigm was used to measure dMMN. Neuropsychological performance was evaluated by the brief assessment of cognition in schizophrenia Japanese version (BACS-J. RESULTS: Patients showed smaller dMMN amplitudes than those in the HC subjects. LORETA current density for dMMN was significantly lower in patients compared to HC subjects, especially in the temporal lobes. dMMN current density in the frontal lobe was positively correlated with working memory performance in patients. CONCLUSIONS: This is the first study to identify brain regions showing smaller dMMN current density in early schizophrenia. Further, poor working memory was associated with decreased dMMN current density in patients. These results are likely to help understand the neural basis for cognitive impairment of schizophrenia.

  14. Two-dimensional electron density characterisation of arc interruption phenomenon in current-zero phase

    Science.gov (United States)

    Inada, Yuki; Kamiya, Tomoki; Matsuoka, Shigeyasu; Kumada, Akiko; Ikeda, Hisatoshi; Hidaka, Kunihiko

    2018-01-01

    Two-dimensional electron density imaging over free burning SF6 arcs and SF6 gas-blast arcs was conducted at current zero using highly sensitive Shack-Hartmann type laser wavefront sensors in order to experimentally characterise electron density distributions for the success and failure of arc interruption in the thermal reignition phase. The experimental results under an interruption probability of 50% showed that free burning SF6 arcs with axially asymmetric electron density profiles were interrupted with a success rate of 88%. On the other hand, the current interruption of SF6 gas-blast arcs was reproducibly achieved under locally reduced electron densities and the interruption success rate was 100%.

  15. Arrays of Synthetic Atoms: Nanocapacitor Batteries with Large Energy Density and Small Leak Currents

    Science.gov (United States)

    2017-11-28

    AFRL-RV-PS- AFRL-RV-PS- TR-2017-0169 TR-2017-0169 ARRAYS OF SYNTHETIC ATOMS : NANOCAPACITOR BATTERIES WITH LARGE ENERGY DENSITY AND SMALL LEAK...1-0247 Arrays of Synthetic Atoms : Nanocapacitor Batteries with Large Energy Density and Small Leak Currents 5b. GRANT NUMBER 5c. PROGRAM ELEMENT...large dielectric strength to a nanoscale rechargeable battery. We fabricated arrays of one-, two- and three-dimensional synthetic atoms and comparison

  16. Eddy current density asymmetric distribution of damper bars in bulb tubular turbine generator

    Directory of Open Access Journals (Sweden)

    Qiu Hongbo

    2017-09-01

    Full Text Available The major reasons that cause the damage of damper bars in the leeward side are found in this paper. It provides a route for the structure optimization design of a hydro generator. Firstly, capacity of a 24 MW bulb tubular turbine generator is taken as an example in this paper. The transient electromagnetic field model is established, and the correctness of the model is verified by the comparison of experimental results and simulation data. Secondly, when the generator is operated at rated condition, the eddy current density distributions of damper bars are studied. And the asymmetric phenomenon of the eddy current density on damper bars is discovered. The change laws of the eddy currents in damper bars are determined through further analysis. Thirdly, through the study of eddy current distributions under different conditions, it is confirmed that the stator slots and armature reaction are the main factors to affect the asymmetric distribution of the eddy current in damper bars. Finally, the studies of the magnetic density distribution and theoretical analysis revealed the asymmetric distribution mechanism of eddy current density.

  17. Ultrathin silicon dioxide layers with a low leakage current density formed by chemical oxidation of Si

    Science.gov (United States)

    Asuha,; Kobayashi, Takuya; Maida, Osamu; Inoue, Morio; Takahashi, Masao; Todokoro, Yoshihiro; Kobayashi, Hikaru

    2002-10-01

    Chemical oxidation of Si by use of azeotrope of nitric acid and water can form 1.4-nm-thick silicon dioxide layers with a leakage current density as low as those of thermally grown SiO2 layers. The capacitance-voltage (C-V) curves for these ultrathin chemical SiO2 layers have been measured due to the low leakage current density. The leakage current density is further decreased to approx1/5 (cf. 0.4 A/cm2 at the forward gate bias of 1 V) by post-metallization annealing at 200 degC in hydrogen. Photoelectron spectroscopy and C-V measurements show that this decrease results from (i) increase in the energy discontinuity at the Si/SiO2 interface, and (ii) elimination of Si/SiO2 interface states and SiO2 gap states.

  18. Current densities in a pregnant woman model induced by simultaneous ELF electric and magnetic field exposure

    International Nuclear Information System (INIS)

    Cech, R; Leitgeb, N; Pediaditis, M

    2008-01-01

    The pregnant woman model SILVY was studied to ascertain to what extent the electric current densities induced by 50 Hz homogeneous electric and magnetic fields increase in the case of simultaneous exposure. By vectorial addition of the electric current densities, it could be shown that under worst case conditions the basic restrictions recommended by ICNIRP (International Commission on Non-Ionizing Radiation Protection) guidelines are exceeded within the central nervous system (CNS) of the mother, whereas in sole field exposure they are not. However, within the foetus the induced current densities do not comply with basic restrictions, either from single reference-level electric fields or from simultaneous exposure to electric and magnetic fields. Basic limits were considerably exceeded

  19. Towards the definition of AMS facies in the deposits of pyroclastic density currents

    Science.gov (United States)

    Ort, M.H.; Newkirk, T.T.; Vilas, J.F.; Vazquez, J.A.; Ort, M.H.; Porreca, Massimiliano; Geissman, J.W.

    2014-01-01

    Anisotropy of magnetic susceptibility (AMS) provides a statistically robust technique to characterize the fabrics of deposits of pyroclastic density currents (PDCs). AMS fabrics in two types of pyroclastic deposits (small-volume phreatomagmatic currents in the Hopi Buttes volcanic field, Arizona, USA, and large-volume caldera-forming currents, Caviahue Caldera, Neuquén, Argentina) show similar patterns. Near the vent and in areas of high topographical roughness, AMS depositional fabrics are poorly grouped, with weak lineations and foliations. In a densely welded proximal ignimbrite, this fabric is overprinted by a foliation formed as the rock compacted and deformed. Medial deposits have moderate–strong AMS lineations and foliations. The most distal deposits have strong foliations but weak lineations. Based on these facies and existing models for pyroclastic density currents, deposition in the medial areas occurs from the strongly sheared, high-particle-concentration base of a density-stratified current. In proximal areas and where topography mixes this denser base upwards into the current, deposition occurs rapidly from a current with little uniformity to the shear, in which particles fall and collide in a chaotic fashion. Distal deposits are emplaced by a slowing or stalled current so that the dominant particle motion is vertical, leading to weak lineation and strong foliation.

  20. The study of dynamics of electrons in the presence of large current densities

    International Nuclear Information System (INIS)

    Garcia, G.

    2007-11-01

    The runaway electron effect is considered in different fields: nuclear fusion, or the heating of the solar corona. In this thesis, we are interested in runaway electrons in the ionosphere. We consider the issue of electrons moving through an ionospheric gas of positive ions and neutrals under the influence of a parallel electric field. We develop a kinetic model of collisions including electrons/electrons, electrons/ions and electrons/neutrals collisions. We use a Fokker-Planck approach to describe binary collisions between charged particles with a long-range interaction. A computational example is given illustrating the approach to equilibrium and the impact of the different terms. Then, a static electric field is applied in a new sample run. In this run, the electrons move in the z direction, parallel to the electric field. The first results show that all the electron distribution functions are non-Maxwellian. Furthermore, runaway electrons can carry a significant part of the total current density up to 20% of the total current density. Nevertheless, we note that the divergence free of the current density is not conserved. We introduce major changes in order to take into account the variation of the different moments of the ion distribution functions. We observe that the electron distribution functions are still non-Maxwellian. Runaway electrons are created and carry the current density. The core distribution stay at rest. As these electrons undergo less collisions, they increase the plasma conductivity. We make a parametric study. We fit the electron distribution function by two Maxwellian. We show that the time to reach the maximal current density is a key point. Thus, when we increase this time, we modify the temperatures. The current density plays a primary role. When the current density increases, all the moments of the distributions increase: electron density and mean velocity of the suprathermal distribution and the electron temperature of the core and

  1. Corrosion Behavior and Durability of Low-Alloy Steel Rebars in Marine Environment

    Science.gov (United States)

    Liu, Ming; Cheng, Xuequn; Li, Xiaogang; Yue, Pan; Li, Jun

    2016-11-01

    The corrosion resistance of Cr-modified low-alloy steels and HRB400 carbon steel was estimated using the open-circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopic, and weight loss methods in simulated concrete pore solution. Results show that Cr-modified steels exhibit a higher corrosion resistance with a higher critical chloride level (CTL), lower corrosion current density, and higher impedance than carbon steel. The CTL of the steels significantly reduces with increasing temperature. Weight loss measurement shows that the Cr-modified steels exhibit low corrosion rates and small corrosion pitting. The primary constituents of the corrosion scales are Fe2O3, Fe3O4, β-FeOOH, γ-FeOOH, and α-FeOOH. A large amount of α-FeOOH could be detected in the Cr-modified steel corrosion products. Moreover, the Cr-modified steels demonstrate a higher durability than HRB400 carbon steel.

  2. Corrosion behavior of low-alloy steel in the presence of Desulfotomaculum sp

    International Nuclear Information System (INIS)

    Cetin, Demet; Aksu, Mehmet Levent

    2009-01-01

    The objective of this study was to determine the effect of sulfate-reducing Desulfotomaculum sp. bacteria isolated from a crude oil field on the corrosion of low-alloy steel. The corrosion rate and mechanism were determined with the use of Tafel slopes, mass loss method and electrochemical impedance spectroscopy (EIS). The formation of the biofilm and the corrosion products on the steel surface was determined with scanning electron microscopy (SEM) micrographs and energy dispersive X-ray spectra (EDS) analysis. It was observed from the Tafel plots that the corrosion potential exhibited a cathodic shift that verifies an increase in the corrosion rates. The semicircles tended to open at lower frequencies in the Nyquist plots which indicates the rupture of the protective film. The corrosion current density reached its maximum value at the 14th hour after the inoculation and decreased afterwards. This was attributed to the accumulation of corrosion products on the surface.

  3. Microstructure characterisation of solid oxide electrolysis cells operated at high current density

    DEFF Research Database (Denmark)

    Bowen, Jacob R.; Bentzen, Janet Jonna; Chen, Ming

    quantified using the mean linear intercept method as a function of current density and correlated to increases in serial resistance. The above structural changes are then compared in terms of electrode degradation observed during the co-electrolysis of steam and CO2 at current densities up to -1.5 A cm-2......High temperature solid oxide cells can be operated either as fuel cells or electrolysis cells for efficient power generation or production of hydrogen from steam or synthesis gas (H2 + CO) from steam and CO2 respectively. When operated under harsh conditions, they often exhibit microstructural...

  4. Multipole lenses with implicit poles and with harmonic distribution of current density in a coil

    International Nuclear Information System (INIS)

    Skachkov, V.S.

    1984-01-01

    General theory of the multipole lense with implicit poles is presented. The thickness of lense coil is finite. Current density distribution in the coil cross section is harmonic in the azimuth direction and arbitrary in the radial one. The calculation of yoke contribution in the lence field is given. Two particular lense variants differing from each other in the method of current density radial distribution are considered and necessary calculated relations for the lense with and without yoke ar presented. A comparative analysis of physical and technological peculiarities of these lenses is performed

  5. Measurement of current density fluctuations and ambipolar particle flux due to magnetic fluctuations in MST

    International Nuclear Information System (INIS)

    Shen, Weimin.

    1992-08-01

    Studies of magnetic fluctuation induced particle transport on Reversed Field Pinch plasmas were done on the Madison Symmetric Torus. Plasma current density and current density fluctuations were measured using a multi-coil magnetic probes. The low frequency (f parallel B r >. The result of zero net charged particle loss was obtained, meaning the flux is ambipolar. The ambipolarity of low frequency global tearing modes is satisfied through the phase relations determined by tearing instabilities. The ambipolarity of high frequency localized modes could be partially explained by the simple model of Waltz based on the radial average of small scale turbulence

  6. Particle-bearing currents in uniform density and two-layer fluids

    Science.gov (United States)

    Sutherland, Bruce R.; Gingras, Murray K.; Knudson, Calla; Steverango, Luke; Surma, Christopher

    2018-02-01

    Lock-release gravity current experiments are performed to examine the evolution of a particle bearing flow that propagates either in a uniform-density fluid or in a two-layer fluid. In all cases, the current is composed of fresh water plus micrometer-scale particles, the ambient fluid is saline, and the current advances initially either over the surface as a hypopycnal current or at the interface of the two-layer fluid as a mesopycnal current. In most cases the tank is tilted so that the ambient fluid becomes deeper with distance from the lock. For hypopycnal currents advancing in a uniform density fluid, the current typically slows as particles rain out of the current. While the loss of particles alone from the current should increase the current's buoyancy and speed, in practice the current's speed decreases because the particles carry with them interstitial fluid from the current. Meanwhile, rather than settling on the sloping bottom of the tank, the particles form a hyperpycnal (turbidity) current that advances until enough particles rain out that the relatively less dense interstitial fluid returns to the surface, carrying some particles back upward. When a hypopycnal current runs over the surface of a two-layer fluid, the particles that rain out temporarily halt their descent as they reach the interface, eventually passing through it and again forming a hyperpycnal current. Dramatically, a mesopycnal current in a two-layer fluid first advances along the interface and then reverses direction as particles rain out below and fresh interstitial fluid rises above.

  7. Calculation of induced current densities for humans by magnetic fields from electronic article surveillance devices

    Science.gov (United States)

    Gandhi, Om P.; Kang, Gang

    2001-11-01

    This paper illustrates the use of the impedance method to calculate the electric fields and current densities induced in millimetre resolution anatomic models of the human body, namely an adult and 10- and 5-year-old children, for exposure to nonuniform magnetic fields typical of two assumed but representative electronic article surveillance (EAS) devices at 1 and 30 kHz, respectively. The devices assumed for the calculations are a solenoid type magnetic deactivator used at store checkouts and a pass-by panel-type EAS system consisting of two overlapping rectangular current-carrying coils used at entry and exit from a store. The impedance method code is modified to obtain induced current densities averaged over a cross section of 1 cm2 perpendicular to the direction of induced currents. This is done to compare the peak current densities with the limits or the basic restrictions given in the ICNIRP safety guidelines. Because of the stronger magnetic fields at lower heights for both the assumed devices, the peak 1 cm2 area-averaged current densities for the CNS tissues such as the brain and the spinal cord are increasingly larger for smaller models and are the highest for the model of the 5-year-old child. For both the EAS devices, the maximum 1 cm2 area-averaged current densities for the brain of the model of the adult are lower than the ICNIRP safety guideline, but may approach or exceed the ICNIRP basic restrictions for models of 10- and 5-year-old children if sufficiently strong magnetic fields are used.

  8. On the estimation of the current density in space plasmas: Multi- versus single-point techniques

    Science.gov (United States)

    Perri, Silvia; Valentini, Francesco; Sorriso-Valvo, Luca; Reda, Antonio; Malara, Francesco

    2017-06-01

    Thanks to multi-spacecraft mission, it has recently been possible to directly estimate the current density in space plasmas, by using magnetic field time series from four satellites flying in a quasi perfect tetrahedron configuration. The technique developed, commonly called ;curlometer; permits a good estimation of the current density when the magnetic field time series vary linearly in space. This approximation is generally valid for small spacecraft separation. The recent space missions Cluster and Magnetospheric Multiscale (MMS) have provided high resolution measurements with inter-spacecraft separation up to 100 km and 10 km, respectively. The former scale corresponds to the proton gyroradius/ion skin depth in ;typical; solar wind conditions, while the latter to sub-proton scale. However, some works have highlighted an underestimation of the current density via the curlometer technique with respect to the current computed directly from the velocity distribution functions, measured at sub-proton scales resolution with MMS. In this paper we explore the limit of the curlometer technique studying synthetic data sets associated to a cluster of four artificial satellites allowed to fly in a static turbulent field, spanning a wide range of relative separation. This study tries to address the relative importance of measuring plasma moments at very high resolution from a single spacecraft with respect to the multi-spacecraft missions in the current density evaluation.

  9. Environmental and Geometrical Conditions to Sustain Crevice Corrosion in Alloy 22

    Energy Technology Data Exchange (ETDEWEB)

    Carranza, R M; Rodr?guez, M A; Rebak, R B

    2006-11-10

    Alloy 22 (N06022) is highly resistant to localized corrosion. Under aggressive environmental conditions Alloy 22 may be susceptible to crevice corrosion in hot chloride (Cl{sup -}) solutions. The objective of the present work was to explore the environmental and geometrical conditions for crevice corrosion to occur. Electrochemical tests were performed using PCA and prismatic mill annealed Alloy 22 specimens in chloride solutions. Crevice corrosion current density was found to be a function of applied potential. i{sub CREV} values ranged from 40 {micro}A/cm{sup 2} to 20 mA/cm{sup 2}. Such low values of current density explained the absence of pitting corrosion in Alloy 22 at any potential. Decreasing of the effective diffusion distance in a propagating crevice is thought to cause crevice corrosion stifling or repassivation after long anodic polarization. Crevice corrosion breakdown potential is expected to decrease with potential scan rate, approaching repassivation potential for low scan rates. The lowest corrosion potential of Alloy 22 in hydrochloric acid solutions at which active corrosion exists was proposed as the lowest possible repassivation potential for crevice corrosion.

  10. Effects of copper and titanium on the corrosion behavior of newly fabricated nanocrystalline aluminum in natural seawater

    International Nuclear Information System (INIS)

    Sherif, El-Sayed M.; Ammar, Hany Rizk; Khalil, Khalil Abdelrazek

    2014-01-01

    Graphical abstract: - Highlights: • We fabricated nanocrystalline Al and some of its alloys by mechanical alloying method. • The corrosion behavior of the fabricated materials in natural seawater was reported. • We found that Al suffers both uniform and localized corrosion in the seawater. • The presence of Cu significantly decreased the corrosion of Al. • The addition of Ti to the Al–Cu alloy presented more protection to Al against corrosion. - Abstract: Fabrication of a newly nanocrystalline Al and two of its alloys, namely Al–10%Cu; and Al–10%Cu–5%Ti has been carried out using mechanical alloying (MA) technique. The corrosion behavior of these materials in aerated stagnant Arabian Gulf seawater (AGSW) at room temperature has been reported. Cyclic potentiodynamic polarization (CPP), chronoamperometric current-time (CCT) and electrochemical impedance spectroscopy (EIS) measurements along with scanning electron microscopy (SEM) and X-ray energy dispersive (EDX) investigations were employed to report the corrosion behavior of the fabricated materials. All results indicated that Al suffers both uniform and localized corrosion in the AGSW test solution. The presence of 10%Cu decreases the corrosion current density, the anodic and cathodic currents and corrosion rate and increases the corrosion resistance of Al. The addition of 5%Ti to the Al–10%Cu alloy produced further decreases in the corrosion parameters. Measurements together confirmed that the corrosion of the fabricated materials in AGSW decreases in the order Al > Al–10%Cu > Al–10%Cu–5%Ti

  11. Effects of copper and titanium on the corrosion behavior of newly fabricated nanocrystalline aluminum in natural seawater

    Energy Technology Data Exchange (ETDEWEB)

    Sherif, El-Sayed M., E-mail: esherif@ksu.edu.sa [Mechanical Engineering Department, College of Engineering, King Saud University, P.O. Box 800, Al-Riyadh 11421 (Saudi Arabia); Electrochemistry and Corrosion Laboratory, Department of Physical Chemistry, National Research Centre , (NRC), Dokki, 12622, Cairo 8 (Egypt); Ammar, Hany Rizk [Metallurgical and Materials Engineering Department, Faculty of Petroleum and Mining Engineering, Suez University, Suez (Egypt); Khalil, Khalil Abdelrazek [Metallurgical and Materials Engineering Department, Faculty of Petroleum and Mining Engineering, Suez University, Suez (Egypt); Mechanical Design and Materials Department, Faculty of Energy Engineering, Aswan University, Aswan (Egypt)

    2014-05-01

    Graphical abstract: - Highlights: • We fabricated nanocrystalline Al and some of its alloys by mechanical alloying method. • The corrosion behavior of the fabricated materials in natural seawater was reported. • We found that Al suffers both uniform and localized corrosion in the seawater. • The presence of Cu significantly decreased the corrosion of Al. • The addition of Ti to the Al–Cu alloy presented more protection to Al against corrosion. - Abstract: Fabrication of a newly nanocrystalline Al and two of its alloys, namely Al–10%Cu; and Al–10%Cu–5%Ti has been carried out using mechanical alloying (MA) technique. The corrosion behavior of these materials in aerated stagnant Arabian Gulf seawater (AGSW) at room temperature has been reported. Cyclic potentiodynamic polarization (CPP), chronoamperometric current-time (CCT) and electrochemical impedance spectroscopy (EIS) measurements along with scanning electron microscopy (SEM) and X-ray energy dispersive (EDX) investigations were employed to report the corrosion behavior of the fabricated materials. All results indicated that Al suffers both uniform and localized corrosion in the AGSW test solution. The presence of 10%Cu decreases the corrosion current density, the anodic and cathodic currents and corrosion rate and increases the corrosion resistance of Al. The addition of 5%Ti to the Al–10%Cu alloy produced further decreases in the corrosion parameters. Measurements together confirmed that the corrosion of the fabricated materials in AGSW decreases in the order Al > Al–10%Cu > Al–10%Cu–5%Ti.

  12. Corrosion control of vanadium in aqueous solutions by amino acids

    International Nuclear Information System (INIS)

    El-Rabiee, M.M.; Helal, N.H.; El-Hafez, Gh.M. Abd; Badawy, W.A.

    2008-01-01

    The electrochemical behavior of vanadium in amino acid free and amino acid containing aqueous solutions of different pH was studied using open-circuit potential measurements, polarization techniques and electrochemical impedance spectroscopy (EIS). The corrosion current density, i corr , the corrosion potential, E corr and the corrosion resistance, R corr , were calculated. A group of amino acids, namely, glycine, alanine, valine, histidine, glutamic and cysteine has been investigated as environmentally safe inhibitors. The effect of Cl - on the corrosion inhibition efficiency especially in acid solutions was investigated. In neutral and basic solutions, the presence of amino acids increases the corrosion resistance of the metal. The electrochemical behavior of V before and after the corrosion inhibition process has shown that some amino acids like glutamic acid and histidine have promising corrosion inhibition efficiency at low concentration (≅25 mM). The inhibition efficiency (η) was found to depend on the structure of the amino acid and the constituents of the corrosive medium. The corrosion inhibition process is based on the adsorption of the amino acid molecules on the metal surface and the adsorption process follows the Freundlich isotherm. The adsorption free energy for valine on V in acidic solutions was found to be -9.4 kJ/mol which reveals strong physical adsorption of the amino acid molecules on the vanadium surface

  13. Crack problem in superconducting cylinder with exponential distribution of critical-current density

    Science.gov (United States)

    Zhao, Yufeng; Xu, Chi; Shi, Liang

    2018-04-01

    The general problem of a center crack in a long cylindrical superconductor with inhomogeneous critical-current distribution is studied based on the extended Bean model for zero-field cooling (ZFC) and field cooling (FC) magnetization processes, in which the inhomogeneous parameter η is introduced for characterizing the critical-current density distribution in inhomogeneous superconductor. The effect of the inhomogeneous parameter η on both the magnetic field distribution and the variations of the normalized stress intensity factors is also obtained based on the plane strain approach and J-integral theory. The numerical results indicate that the exponential distribution of critical-current density will lead a larger trapped field inside the inhomogeneous superconductor and cause the center of the cylinder to fracture more easily. In addition, it is worth pointing out that the nonlinear field distribution is unique to the Bean model by comparing the curve shapes of the magnetization loop with homogeneous and inhomogeneous critical-current distribution.

  14. Effect of electrolysis parameters on the morphologies of copper powder obtained at high current densities

    Directory of Open Access Journals (Sweden)

    Orhan Gökhan

    2012-01-01

    Full Text Available The effects of copper ion concentrations and electrolyte temperature on the morphologies and on the apparent densities of electrolytic copper powders at high current densities under galvanostatic regime were examined. These parameters were evaluated by the current efficiency of hydrogen evolution. In addition, scanning electron microscopy was used for analyzing the morphology of the copper powders. It was found that the morphology was dependent over the copper ion concentration and electrolyte temperature under same current density (CD conditions. At 150 mA cm-2 and the potential of 1000±20 mV (vs. SCE, porous and disperse copper powders were obtained at low concentrations of Cu ions (0.120 M Cu2+ in 0.50 M H2SO4. Under this condition, high rate of hydrogen evolution reaction took place parallel to copper electrodeposition. The morphology was changed from porous, disperse and cauliflower-like to coral-like, shrub-like and stalk-stock like morphology with the increasing of Cu ion concentrations towards 0.120 M, 0.155 M, 0.315 M, 0.475 M and 0.630 M Cu2+ in 0.5 M H2SO4 respectively at the same CD. Similarly, as the temperature was increased, powder morphology and apparent density were observed to be changed. The apparent density values of copper powders were found to be suitable for many of the powder metallurgy applications.

  15. Effect of a superconducting coil as a fault current limiter on current density distribution in BSCCO tape after an over-current pulse

    Science.gov (United States)

    Tallouli, M.; Shyshkin, O.; Yamaguchi, S.

    2017-07-01

    The development of power transmission lines based on long-length high temperature superconducting (HTS) tapes is complicated and technically challenging task. A serious problem for transmission line operation could become HTS power cable damage due to over-current pulse conditions. To avoid the cable damage in any urgent case the superconducting coil technology, i.e. superconductor fault current limiter (SFCL) is required. Comprehensive understanding of the current density characteristics of HTS tapes in both cases, either after pure over-current pulse or after over-current pulse limited by SFCL, is needed to restart or to continue the operation of the power transmission line. Moreover, current density distribution along and across the HTS tape provides us with the sufficient information about the quality of the tape performance in different current feeding regimes. In present paper we examine BSCCO HTS tape under two current feeding regimes. The first one is 100A feeding preceded by 900A over-current pulse. In this case none of tape protection was used. The second scenario is similar to the fist one but SFCL is used to limit an over-current value. For both scenarios after the pulse is gone and the current feeding is set up at 100A we scan magnetic field above the tape by means of Hall probe sensor. Then the feeding is turned of and the magnetic field scanning is repeated. Using the inverse problem numerical solver we calculate the corresponding direct and permanent current density distributions during the feeding and after switch off. It is demonstrated that in the absence of SFCL the current distribution is highly peaked at the tape center. At the same time the current distribution in the experiment with SFCL is similar to that observed under normal current feeding condition. The current peaking in the first case is explained by the effect of an opposite electric field induced at the tape edges during the overcurrent pulse decay, and by degradation of

  16. Effect of a superconducting coil as a fault current limiter on current density distribution in BSCCO tape after an over-current pulse

    International Nuclear Information System (INIS)

    Tallouli, M; Yamaguchi, S.; Shyshkin, O.

    2017-01-01

    The development of power transmission lines based on long-length high temperature superconducting (HTS) tapes is complicated and technically challenging task. A serious problem for transmission line operation could become HTS power cable damage due to over-current pulse conditions. To avoid the cable damage in any urgent case the superconducting coil technology, i.e. superconductor fault current limiter (SFCL) is required. Comprehensive understanding of the current density characteristics of HTS tapes in both cases, either after pure over-current pulse or after over-current pulse limited by SFCL, is needed to restart or to continue the operation of the power transmission line. Moreover, current density distribution along and across the HTS tape provides us with the sufficient information about the quality of the tape performance in different current feeding regimes. In present paper we examine BSCCO HTS tape under two current feeding regimes. The first one is 100A feeding preceded by 900A over-current pulse. In this case none of tape protection was used. The second scenario is similar to the fist one but SFCL is used to limit an over-current value. For both scenarios after the pulse is gone and the current feeding is set up at 100A we scan magnetic field above the tape by means of Hall probe sensor. Then the feeding is turned of and the magnetic field scanning is repeated. Using the inverse problem numerical solver we calculate the corresponding direct and permanent current density distributions during the feeding and after switch off. It is demonstrated that in the absence of SFCL the current distribution is highly peaked at the tape center. At the same time the current distribution in the experiment with SFCL is similar to that observed under normal current feeding condition. The current peaking in the first case is explained by the effect of an opposite electric field induced at the tape edges during the overcurrent pulse decay, and by degradation of

  17. A mathematical model of the current density distribution in electrochemical cells - AUTHORS’ REVIEW

    Directory of Open Access Journals (Sweden)

    PREDRAG M. ŽIVKOVIĆ

    2011-06-01

    Full Text Available An approach based on the equations of electrochemical kinetics for the estimation of the current density distribution in electrochemical cells is presented. This approach was employed for a theoretical explanation of the phenomena of the edge and corner effects. The effects of the geometry of the system, the kinetic parameters of the cathode reactions and the resistivity of the solution are also discussed. A procedure for a complete analysis of the current distribution in electrochemical cells is presented.

  18. Critical current densities in thick yttrium-barium cuprate (1-2-3) films

    International Nuclear Information System (INIS)

    Ryvkina, G.G.; Gorlanov, S.F.; Vedernikov, G.E.; Telegin, A.B.; Ryabin, V.A.; Khodos, M.Ya.

    1993-01-01

    The study of critical current densities j c of oxide superconductors and their thick films is a very important practical task because the value of j c is one of the main criteria for their utilization in modern cryoelectronics. For most devices based on the Josephson effect, the value of j c ∼ 10 2 - 10 3 A/cm 2 is acceptable, which is easily attainable for polycrystalline thick films obtained by stenciling. The study of the current-transport phenomenon involves a number of difficulties, especially for direct current, because both the sample itself and the lead-in contacts are resistance-heated during the measurements, which, in turn, results in lower values of the j c . Measurements with pulsed currents allow one to lower the power that is applied to the sample; the heat that is released in the sample is reduced, in comparison to measurements with direct current, by a factor of the pulsed-current duty cycle. In addition, measurements with direct current detects only the appearance of resistance; it provides no information on the rest of the transition from the normal to the superconductive state, i.e., on the so-called 'tail' of the transition. In this work, the authors studied critical current densities of thick HTSC yttrium-barium cuprate films of the 1-2-3 composition using pulsed current

  19. Measurement of electrical current density distribution in a simple head phantom with magnetic resonance imaging

    Science.gov (United States)

    Gamba, Humberto R.; Bayford, Richard; Holder, David

    1999-01-01

    Knowledge of the influence of the human skull on the electrical current (d.c.) distribution within the brain tissue could prove useful in measuring impedance changes inside the human head. These changes can be related to physiological functions. The studies presented in this paper examine the current density distribution in a simple phantom consisting of a saline filled tank (to simulate scalp and brain) and a ring made of dental grade plaster of Paris (to simulate the human skull). Images of the distribution of the d.c. density of the phantom with and without the plaster of Paris ring were produced using a magnetic resonance imaging technique. These images indicate that the skull is likely to produce a more uniform d.c. density within the brain.

  20. Lower hybrid current drive at ITER-relevant high plasma densities

    International Nuclear Information System (INIS)

    Cesario, R.; Amicucci, L.; Cardinali, A.; Castaldo, C.; Marinucci, M.; Panaccione, L.; Pericoli-Ridolfini, V.; Tuccillo, A. A.; Tudisco, O.; Calabro, G.

    2009-01-01

    Recent experiments indicated that a further non-inductive current, besides bootstrap, should be necessary for developing advanced scenario for ITER. The lower hybrid current drive (LHCD) should provide such tool, but its effectiveness was still not proved in operations with ITER-relevant density of the plasma column periphery. Progress of the LH deposition modelling is presented, performed considering the wave physics of the edge, and different ITER-relevant edge parameters. Operations with relatively high edge electron temperatures are expected to reduce the LH || spectral broadening and, consequently, enabling the LH power to propagate also in high density plasmas ( || is the wavenumber component aligned to the confinement magnetic field). New results of FTU experiments are presented, performed by following the aforementioned modeling: they indicate that, for the first time, the LHCD conditions are established by operating at ITER-relevant high edge densities.

  1. Critical current density measurement of thin films by AC susceptibility based on the penetration parameter h

    DEFF Research Database (Denmark)

    Li, Xiao-Fen; Grivel, Jean-Claude; Abrahamsen, Asger B.

    2012-01-01

    current density Jc of superconducting thin films by AC susceptibility. Compared with the normally used method based on the peak of the imaginary part, our method uses a much larger range of the AC susceptibility curve, thus allowing determination of the temperature (T) dependence of Jc from a normally...

  2. Influence of electropolishing current densities on sulfur generation at niobium surface

    Energy Technology Data Exchange (ETDEWEB)

    Tyagi, P.V., E-mail: tyagipv@ornl.gov [The Graduate University for Advanced Studies, Tsukuba, Ibaraki (Japan); Nishiwaki, M.; Noguchi, T.; Sawabe, M.; Saeki, T.; Hayano, H.; Kato, S. [KEK, High Energy Accelerator Research Organization, Tsukuba, Ibaraki (Japan)

    2013-11-15

    We report the effect of different current densities on sulfur generation at Nb surface in the electropolishing (EP) with aged electrolyte. In this regard, we conducted a series of electropolishing (EP) experiments in aged EP electrolyte with high (≈50 mA/cm{sup 2}) and low (≈30 mA/cm{sup 2}) current densities on Nb surfaces. The experiments were carried out both for laboratory coupons and a real Nb single cell cavity with six witness samples located at three typical positions (equator, iris and beam pipe). Sample's surfaces were investigated by XPS (X-ray photoelectron spectroscopy), SEM (scanning electron microscope) and EDX (energy dispersive X-ray spectroscopy). The surface analysis showed that the EP with a high current density produced a huge amount of sulfate/sulfite particles at Nb surface whereas the EP with a low current density was very helpful to mitigate sulfate/sulfite at Nb surface in both the experiments.

  3. Contributions for the modelling of submarine cables – current density and simplified modelling of wired layers

    DEFF Research Database (Denmark)

    Silva, Filipe Miguel Faria da; Bak, Claus Leth; Ebdrup, Thomas

    2015-01-01

    This article researches two topics relevant for the development of accurate formulae able to estimate the ampacity of HVAC submarine cables. Simplified formulae for estimating the current density distribution, which can be used for theoretical analyses, are developed and compared with the exact...

  4. The Keldysh formalism applied to time-dependent current-density-functional theory

    NARCIS (Netherlands)

    Gidopoulos, NI; Wilson, S

    2003-01-01

    In this work we demonstrate how to derive the Kohn-Sham equations of time-dependent current-density functional theory from a generating action functional defined on a Keldysh time contour. These Kohn-Sham equations contain an exchange-correlation contribution to the vector potential. For this

  5. Particle image velocimetry measurements and numerical modeling of a saline density current

    CSIR Research Space (South Africa)

    Gerber, G

    2011-03-01

    Full Text Available turbulence collapsed. A two-dimensional, unsteady, Reynolds-averaged Navier-Stokes (2DV-URANS) simulation was also performed on this density current. Good agreement was found between the modeled and measured normalized mean flow profiles. A comparison...

  6. Transition from Fowler-Nordheim field emission to space charge limited current density

    International Nuclear Information System (INIS)

    Feng, Y.; Verboncoeur, J. P.

    2006-01-01

    The Fowler-Nordheim law gives the current density extracted from a surface under strong fields, by treating the emission of electrons from a metal-vacuum interface in the presence of an electric field normal to the surface as a quantum mechanical tunneling process. Child's law predicts the maximum transmitted current density by considering the space charge effect. When the electric field becomes high enough, the emitted current density will be limited by Child's law. This work analyzes the transition of the transmitted current density from the Fowler-Nordheim law to Child's law space charge limit using a one-dimensional particle-in-cell code. Also studied is the response of the emission model to strong electric fields near the transition point. We find the transition without geometrical effort is smooth and much slower than reported previously [J. P. Barbour, W. W. Dolan, J. K. Trolan, E. E. Martin, and W. P. Dyke, Phys. Rev. 92, 45 (1953)]. We analyze the effects of geometric field enhancement and work function on the transition. Using our previous model for effective field enhancement [Y. Feng and J. P. Verboncoeur, Phys. Plasmas 12, 103301 (2005)], we find the geometric effect dominates, and enhancement β>10 can accelerate the approach to the space charge limit at practical electric field. A damped oscillation near the local plasma frequency is observed in the transient system response

  7. Magnetically Filtered Faraday Probe for Measuring the Ion Current Density Profile of a Hall Thruster

    National Research Council Canada - National Science Library

    Rovey, Joshua L; Walker, Mitchell L. R; Gallimore, Alec D; Peterson, Peter Y

    2006-01-01

    .... In this study, a MFFP, Faraday probe with a reduced acceptance angle (BFP), and nude Faraday probe are used to measure the ion current density profile of a 5 kW Hall thruster operating over the range of 300-500 V and 5-10 mg...

  8. Behaviour of bipolar membranes at high current density. Water diffusion limitation

    NARCIS (Netherlands)

    Krol, J.J.; Jansink, M.G.J.; Wessling, Matthias; Strathmann, H.

    1998-01-01

    In this paper the behaviour of bipolar membranes at very high current density is discussed. Current–voltage curves are determined, both for the Tokuyama Soda BP-1 and the WSI Technologies bipolar membrane. The current–voltage curves are characterised by an inflection point at which a drastic

  9. Use of cyclic current reversal polarization voltammetry for investigating the relationship between corrosion resistance and heat-treatment induced variations in microstructures of 400 C martensitic stainless steels

    Science.gov (United States)

    Ambrose, John R.

    1992-01-01

    Software for running a cyclic current reversal polarization voltammagram has been developed for use with a EG&G Princeton Applied Research Model 273 potentiostat/galvanostat system. The program, which controls the magnitude, direction and duration of an impressed galvanostatic current, will produce data in ASCII spreadsheets (Lotus, Quattro) for graphical representation of CCRPV voltammograms. The program was used to determine differences in corrosion resistance of 440 C martenstic stainless steel produced as a result of changes in microstructure effected by tempering. It was determined that tempering at all temperatures above 400 F resulted in increased polarizability of the material, with the increased likelihood that pitting would be initiated upon exposure to marine environments. These results will be used in development of remedial procedures for lowering the susceptibility of these alloys toward the stress corrosion cracking experienced in bearings used in high pressure oxygen turbopumps used in the main engines of space shuttle orbiters.

  10. Remarks on time-dependent [current]-density functional theory for open quantum systems.

    Science.gov (United States)

    Yuen-Zhou, Joel; Aspuru-Guzik, Alán

    2013-08-14

    Time-dependent [current]-density functional theory for open quantum systems (OQS) has emerged as a formalism that can incorporate dissipative effects in the dynamics of many-body quantum systems. Here, we review and clarify some formal aspects of these theories that have been recently questioned in the literature. In particular, we provide theoretical support for the following conclusions: (1) contrary to what we and others had stated before, within the master equation framework, there is in fact a one-to-one mapping between vector potentials and current densities for fixed initial state, particle-particle interaction, and memory kernel; (2) regardless of the first conclusion, all of our recently suggested Kohn-Sham (KS) schemes to reproduce the current and particle densities of the original OQS, and in particular, the use of a KS closed driven system, remains formally valid; (3) the Lindblad master equation maintains the positivity of the density matrix regardless of the time-dependence of the Hamiltonian or the dissipation operators; (4) within the stochastic Schrödinger equation picture, a one-to-one mapping from stochastic vector potential to stochastic current density for individual trajectories has not been proven so far, except in the case where the vector potential is the same for every member of the ensemble, in which case, it reduces to the Lindblad master equation picture; (5) master equations may violate certain desired properties of the density matrix, such as positivity, but they remain as one of the most useful constructs to study OQS when the environment is not easily incorporated explicitly in the calculation. The conclusions support our previous work as formally rigorous, offer new insights into it, and provide a common ground to discuss related theories.

  11. Finite temperature fermion condensate, charge and current densities in a (2+1)-dimensional conical space

    Energy Technology Data Exchange (ETDEWEB)

    Bellucci, S. [INFN, Laboratori Nazionali di Frascati, Frascati (Italy); Bezerra de Mello, E.R. [Universidade Federal da Parai ba, Departamento de Fisica, 58.059-970, Joao Pessoa, PB (Brazil); Braganca, E. [INFN, Laboratori Nazionali di Frascati, Frascati (Italy); Universidade Federal da Parai ba, Departamento de Fisica, 58.059-970, Joao Pessoa, PB (Brazil); Saharian, A.A. [Yerevan State University, Department of Physics, Yerevan (Armenia)

    2016-06-15

    We evaluate the fermion condensate and the expectation values of the charge and current densities for a massive fermionic field in (2+1)-dimensional conical spacetime with a magnetic flux located at the cone apex. The consideration is done for both irreducible representations of the Clifford algebra. The expectation values are decomposed into the vacuum expectation values and contributions coming from particles and antiparticles. All these contributions are periodic functions of the magnetic flux with the period equal to the flux quantum. Related to the non-invariance of the model under the parity and time-reversal transformations, the fermion condensate and the charge density have indefinite parity with respect to the change of the signs of the magnetic flux and chemical potential. The expectation value of the radial current density vanishes. The azimuthal current density is the same for both the irreducible representations of the Clifford algebra. It is an odd function of the magnetic flux and an even function of the chemical potential. The behavior of the expectation values in various asymptotic regions of the parameters are discussed in detail. In particular, we show that for points near the cone apex the vacuum parts dominate. For a massless field with zero chemical potential the fermion condensate and charge density vanish. Simple expressions are derived for the part in the total charge induced by the planar angle deficit and magnetic flux. Combining the results for separate irreducible representations, we also consider the fermion condensate, charge and current densities in parity and time-reversal symmetric models. Possible applications to graphitic nanocones are discussed. (orig.)

  12. Microbially influenced corrosion of stainless steel by marine bacterium Vibrio natriegens: (I) Corrosion behavior

    International Nuclear Information System (INIS)

    Cheng Sha; Tian Jintao; Chen Shougang; Lei Yanhua; Chang Xueting; Liu Tao; Yin Yansheng

    2009-01-01

    The microbially influenced corrosion of stainless steel (SS) by marine bacterium Vibrio natriegens (V. natriegens) was investigated using surface analysis (atomic force microscopy (AFM), scanning electron microscopy (SEM), and energy dispersive X-ray analysis (EDXA)) and electrochemical techniques (the open circuit potential, electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization curves ). AFM images corroborated the results from the EIS models which show biofilm attachment and subsequent detachment over time. The SEM images revealed the occurrence of micro-pitting corrosion underneath the biofilms on the metal surface after the biofilm removal. The presence of carbon, oxygen, phosphor and sulfur obtained from EDXA proved the formation of biofilm. The electrochemical results showed that the corrosion of SS was accelerated in the presence of V. natriegens based on the decrease in the resistance of the charge transfer resistance (R ct ) obtained from EIS and the increase in corrosion current densities obtained from potentiodynamic polarization curves.

  13. EFFECT OF THE HEAT AND SURFACE LASER TREATMENT ON THE CORROSION DEGRADATION OF THE Mg-Al ALLOYS

    Directory of Open Access Journals (Sweden)

    Leszek A. Dobrzański

    2011-09-01

    Full Text Available In this paper there is presented the corrosion behavior of the cast magnesium alloys as cast state, after heat and laser treatment. Pitting corrosion resistance of the analyzed alloys was carried out using the potentiodynamic electrochemical method (direct current, based on a anodic polarization curve. On the basis of the achieved anodic polarization curves, using the Tefel extrapolation method near to the corrosion potential, the quantitative data were determined, which describe the electrochemical corrosion process of the investigated alloys: value of the corrosion potential Ecorr (mV, polarization resistance RP (kohm.cm2, corrosion current density icorr (10-6A/cm2, corrosion rate Vcorr (mm/year as well the mass loss Vc (g/m2<.

  14. A study on current density distribution reproduction by bounded-eigenfunction expansion for a tokamak plasma

    International Nuclear Information System (INIS)

    Kurihara, Kenichi

    1997-11-01

    Plasma current density distribution is one of the most important controlled variables to determine plasma performance of energy confinement and stability in a tokamak. However, its reproduction by using magnetic measurements solely is recognized to yield an ill-posed problem. A method to presume the formulas giving profiles of plasma pressure and current has been adopted to regularize the ill-posedness, and hence it has been reported the current density distribution can be reproduced as a solution of Grad-Shafranov equation within a certain accuracy. In order to investigate its strict reproducibility from magnetic measurements in this inverse problem, a new method of 'bounded-eigenfunction expansion' is introduced, and it was found that the reproducibility directly corresponds to the independence of a series of the special function. The results from various investigations in an aspect of applied mathematics concerning this inverse problem are presented in detail. (author)

  15. Measurement of levitation force and critical current density of melt textured YBa2Cu3Ox

    International Nuclear Information System (INIS)

    Lehndorff, B.; Kuerschner, H.G.; Busch, D.; Fischer, B.; Piel, H.

    1993-01-01

    By various Melt Textured Growth (MTG) processes YBa 2 Cu 3 O x (Y-123) samples have been prepared with high critical current densities and high levitation forces. The best value of both have been reported by Murakami et al., who used the melt powder melt growth (MPMG) process with platinum addition. These melt textured samples are applicable to magnetic bearings (3). The goal of this work is to develop technical High Temperature Superconductors (HTSC) for bearings and magnet application. In order to optimize the HTSC material for this purpose, levitation force and critical current measurements were carried out. Within this work samples were prepared by the modified Salama method. Levitation force was measured as a function of the distance between the magnet and the superconductor. The critical current density was determined by an inductive method. (orig.)

  16. Monitoring corrosion rates and localised corrosion in low conductivity water

    DEFF Research Database (Denmark)

    Hilbert, Lisbeth Rischel

    2006-01-01

    Monitoring of low corrosion rates and localised corrosion in a media with low conductivity is a challenge. In municipal district heating, quality control may be improved by implementing on-line corrosion monitoring if a suitable technique can be identified to measure both uniform and localised...... corrosion. Electrochemical techniques (LPR, EIS, crevice corrosion current) as well as direct measurement techniques (high-sensitive electrical resistance, weight loss) have been applied in operating plants. Changes in the corrosion processes are best monitored in non-aggressive, low conductivity media...

  17. 'Anomalous electron transport' with 'Giant Current Density' at room temperature observed with nanogranular materials

    International Nuclear Information System (INIS)

    Koops, Hans W.P.

    2013-01-01

    Focused electron beam induced deposition is a novel bottom up nano-structurization technology. An electron beam of high power density is used to generate nano- structures with dimensions > 20 nm, but being composed from amorphous or nanogranular materials with crystals of 2 to 5 nm diameter embedded in a Fullerene matrix. Those compounds are generated in general by secondary or low energy electrons in layers of inorganic, organic, organometallic compounds absorbed to the sample. Those are converted into nanogranular materials by the electron beam following chemical and physical laws, as given by 'Mother Nature'. Metals and amorphous mixtures of chemical compounds from metals are normal resistors, which can carry a current density J 2 . Nanogranular composites like Au/C or Pt/C with metal nanocrystals embedded in a Fullerene matrix have hopping conduction with 0-dimensional Eigen-value characteristics and show 'anomalous electron transport' and can carry 'Giant Current Densities' with values from > 1 MA/cm 2 to 0.1 GA/cm 2 without destruction of the materials. However the area connecting the nanogranular material with a metal with a 3-dimensional electron gas needs to be designed, that the flowing current is reduced to the current density values which the 3-D metal can support without segregation. The basis for a theoretical explanation of the phenomenon can be geometry quantization for Coulomb blockade, of electron surface orbitals around the nanocrystals, hopping conduction, and the limitation of the density of states for phonons in geometry confined non percolated granular materials with strong difference in mass and orientation. Several applications in electronics, signal generators, light sources, detectors, and solar energy harvesting are suggested. (author)

  18. Application of electrochemical frequency modulation for monitoring corrosion and corrosion inhibition of iron by some indole derivatives in molar hydrochloric acid

    International Nuclear Information System (INIS)

    Khaled, K.F.

    2008-01-01

    The corrosion inhibition effect of four indole derivatives, namely indole (IND), benzotriazole (BTA), benzothiazole (BSA) and benzoimidazole (BIA), have been used as possible corrosion inhibitors for pure iron in 1 M HCl. In this study, electrochemical frequency modulation, EFM was used as an effective method for corrosion rate determination in corrosion inhibition studies. By using EFM measurements, corrosion current density was determined without prior knowledge of Tafel slopes. Corrosion rates obtained using EFM, were compared to that obtained from other chemical and electrochemical techniques. The results obtained from EFM, EIS, Tafel and weight loss measurements were in good agreement. Tafel polarization measurements show that indole derivatives are cathodic-type inhibitors. Molecular simulation studies were applied to optimize the adsorption structures of indole derivatives. The inhibitor/iron/solvent interfaces were simulated and the adsorption energies of these inhibitors were calculated. Quantum chemical calculations have been performed and several quantum chemical indices were calculated and correlated with the corresponding inhibition efficiencies

  19. Human in-vivo brain magnetic resonance current density imaging (MRCDI)

    DEFF Research Database (Denmark)

    Göksu, Cihan; Hanson, Lars G.; Siebner, Hartwig R

    2017-01-01

    Magnetic resonance current density imaging (MRCDI) and MR electrical impedance tomography (MREIT) are two emerging modalities, which combine weak time-varying currents injected via surface electrodes with magnetic resonance imaging (MRI) to acquire information about the current flow and ohmic...... is modulated by these shifts, allowing to determine ΔBz,c for the reconstruction of the current flow and ohmic conductivity. Here, we demonstrate reliable ΔBz,c measurements in-vivo in the human brain based on multi-echo spin echo (MESE) and steady-state free precession free induction decay (SSFP......-FID measurements, we demonstrate a strong influence of magnetic stray fields on the ΔBz,c images, caused by non-ideal paths of the electrode cables, and validate a correction method. Finally, we perform measurements with two different current injection profiles in five subjects. We demonstrate reliable recordings...

  20. Responsivity Dependent Anodization Current Density of Nanoporous Silicon Based MSM Photodetector

    Directory of Open Access Journals (Sweden)

    Batool Eneaze B. Al-Jumaili

    2016-01-01

    Full Text Available Achieving a cheap and ultrafast metal-semiconductor-metal (MSM photodetector (PD for very high-speed communications is ever-demanding. We report the influence of anodization current density variation on the response of nanoporous silicon (NPSi based MSM PD with platinum (Pt contact electrodes. Such NPSi samples are grown from n-type Si (100 wafer using photoelectrochemical etching with three different anodization current densities. FESEM images of as-prepared samples revealed the existence of discrete pores with spherical and square-like shapes. XRD pattern displayed the growth of nanocrystals with (311 lattice orientation. The nanocrystallite sizes obtained using Scherrer formula are found to be between 20.8 nm and 28.6 nm. The observed rectifying behavior in the I-V characteristics is ascribed to the Pt/PSi/n-Si Schottky barrier formation, where the barrier height at the Pt/PSi interface is estimated to be 0.69 eV. Furthermore, this Pt/PSi/Pt MSM PD achieved maximum responsivity of 0.17 A/W and quantum efficiency as much as 39.3%. The photoresponse of this NPSi based MSM PD demonstrated excellent repeatability, fast response, and enhanced saturation current with increasing anodization current density.

  1. A simple and reliable setup for monitoring corrosion rate of steel rebars in concrete.

    Science.gov (United States)

    Ahmad, Shamsad; Jibran, Mohammed Abdul Azeem; Azad, Abul Kalam; Maslehuddin, Mohammed

    2014-01-01

    The accuracy in the measurement of the rate of corrosion of steel in concrete depends on many factors. The high resistivity of concrete makes the polarization data erroneous due to the Ohmic drop. The other source of error is the use of an arbitrarily assumed value of the Stern-Geary constant for calculating corrosion current density. This paper presents the outcomes of a research work conducted to develop a reliable and low-cost experimental setup and a simple calculation procedure that can be utilised to calculate the corrosion current density considering the Ohmic drop compensation and the actual value of the Stern-Geary constants calculated using the polarization data. The measurements conducted on specimens corroded to different levels indicate the usefulness of the developed setup to determine the corrosion current density with and without Ohmic drop compensation.

  2. Towards time-dependent current-density-functional theory in the non-linear regime.

    Science.gov (United States)

    Escartín, J M; Vincendon, M; Romaniello, P; Dinh, P M; Reinhard, P-G; Suraud, E

    2015-02-28

    Time-Dependent Density-Functional Theory (TDDFT) is a well-established theoretical approach to describe and understand irradiation processes in clusters and molecules. However, within the so-called adiabatic local density approximation (ALDA) to the exchange-correlation (xc) potential, TDDFT can show insufficiencies, particularly in violently dynamical processes. This is because within ALDA the xc potential is instantaneous and is a local functional of the density, which means that this approximation neglects memory effects and long-range effects. A way to go beyond ALDA is to use Time-Dependent Current-Density-Functional Theory (TDCDFT), in which the basic quantity is the current density rather than the density as in TDDFT. This has been shown to offer an adequate account of dissipation in the linear domain when the Vignale-Kohn (VK) functional is used. Here, we go beyond the linear regime and we explore this formulation in the time domain. In this case, the equations become very involved making the computation out of reach; we hence propose an approximation to the VK functional which allows us to calculate the dynamics in real time and at the same time to keep most of the physics described by the VK functional. We apply this formulation to the calculation of the time-dependent dipole moment of Ca, Mg and Na2. Our results show trends similar to what was previously observed in model systems or within linear response. In the non-linear domain, our results show that relaxation times do not decrease with increasing deposited excitation energy, which sets some limitations to the practical use of TDCDFT in such a domain of excitations.

  3. Towards time-dependent current-density-functional theory in the non-linear regime

    Energy Technology Data Exchange (ETDEWEB)

    Escartín, J. M. [Université de Toulouse, UPS, Laboratoire de Physique Théorique, IRSAMC, F-31062 Toulouse Cedex (France); CNRS, UMR5152, F-31062 Toulouse Cedex (France); Theory of Condensed Matter Group, Cavendish Laboratory, University of Cambridge, J.J. Thomson Avenue, Cambridge CB3 0HE (United Kingdom); Vincendon, M.; Dinh, P. M.; Suraud, E. [Université de Toulouse, UPS, Laboratoire de Physique Théorique, IRSAMC, F-31062 Toulouse Cedex (France); CNRS, UMR5152, F-31062 Toulouse Cedex (France); Romaniello, P. [Laboratoire de Physique Théorique, CNRS, IRSAMC, Université Toulouse III - Paul Sabatier and European Theoretical Spectroscopy Facility, 118 Route de Narbonne, 31062 Toulouse Cedex (France); Reinhard, P.-G. [Institut für Theoretische Physik, Universität Erlangen, Staudtstraße 7, D-91058 Erlangen (Germany)

    2015-02-28

    Time-Dependent Density-Functional Theory (TDDFT) is a well-established theoretical approach to describe and understand irradiation processes in clusters and molecules. However, within the so-called adiabatic local density approximation (ALDA) to the exchange-correlation (xc) potential, TDDFT can show insufficiencies, particularly in violently dynamical processes. This is because within ALDA the xc potential is instantaneous and is a local functional of the density, which means that this approximation neglects memory effects and long-range effects. A way to go beyond ALDA is to use Time-Dependent Current-Density-Functional Theory (TDCDFT), in which the basic quantity is the current density rather than the density as in TDDFT. This has been shown to offer an adequate account of dissipation in the linear domain when the Vignale-Kohn (VK) functional is used. Here, we go beyond the linear regime and we explore this formulation in the time domain. In this case, the equations become very involved making the computation out of reach; we hence propose an approximation to the VK functional which allows us to calculate the dynamics in real time and at the same time to keep most of the physics described by the VK functional. We apply this formulation to the calculation of the time-dependent dipole moment of Ca, Mg and Na{sub 2}. Our results show trends similar to what was previously observed in model systems or within linear response. In the non-linear domain, our results show that relaxation times do not decrease with increasing deposited excitation energy, which sets some limitations to the practical use of TDCDFT in such a domain of excitations.

  4. Integrated modelling of corrosion-induced deterioration in rein-forced concrete structures

    DEFF Research Database (Denmark)

    Michel, Alexander; Geiker, M.R.; Stang, Henrik

    2013-01-01

    An integrated finite element based modelling approach is presented, which allows for fully coupled simulation of reinforcement corrosion and corrosion-induced concrete damage. While a finite element method (FEM) based corrosion model was used to describe electrochemical processes at the reinforce...... use of the modelling approach, a numerical example is presented which illustrates full coupling of formation of corrosion cells, propagation of corrosion, and subsequent development of corrosion-induced concrete damage.......An integrated finite element based modelling approach is presented, which allows for fully coupled simulation of reinforcement corrosion and corrosion-induced concrete damage. While a finite element method (FEM) based corrosion model was used to describe electrochemical processes...... at the reinforcement surface, a FEM based me-chanical model was used to simulate corrosion-induced concrete damage. Both FEM models were fully coupled, i.e. information, such as corrosion current density, dam-age state of concrete cover, etc., were constantly exchanged between the models. To demonstrate the potential...

  5. Current and future research on corrosion and thermalhydraulic issues of HLM cooled reactors and on LMR fuels for fast reactor systems

    International Nuclear Information System (INIS)

    Knebel, J.U.; Konings, R.J.M.

    2002-01-01

    Heavy liquid metals (HLM) such as lead (Pb) or lead-bismuth eutectic (Pb-Bi) are currently investigated world-wide as coolant for nuclear power reactors and for accelerator driven systems (ADS). Besides the advantages of HLM as coolant and spallation material, e.g. high boiling point, low reactivity with water and air and a high neutron yield, some technological issues, such as high corrosion effects in contact with steels and thermalhydraulic characteristics, need further experimental investigations and physical model improvements and validations. The paper describes some typical HLM cooled reactor designs, which are currently considered, and outlines the technological challenges related to corrosion, thermalhydraulic and fuel issues. In the first part of the presentation, the status of presently operated or planned test facilities related to corrosion and thermalhydraulic questions will be discussed. First approaches to solve the corrosion problem will be given. The approach to understand and model thermalhydraulic issues such as heat transfer, turbulence, two-phase flow and instrumentation will be outlined. In the second part of the presentation, an overview will be given of the advanced fuel types that are being considered for future liquid metal reactor (LMR) systems. Advantages and disadvantages will be discussed in relation to fabrication technology and fuel cycle considerations. For the latter, special attention will be given to the partitioning and transmutation potential. Metal, oxide and nitride fuel materials will be discussed in different fuel forms and packings. For both parts of the presentation, an overview of existing co-operations and networks will be given and the needs for future research work will be identified. (authors)

  6. Time-dependent current-density functional theory for generalized open quantum systems.

    Science.gov (United States)

    Yuen-Zhou, Joel; Rodríguez-Rosario, César; Aspuru-Guzik, Alán

    2009-06-14

    In this article, we prove the one-to-one correspondence between vector potentials and particle and current densities in the context of master equations with arbitrary memory kernels, therefore extending time-dependent current-density functional theory (TD-CDFT) to the domain of generalized many-body open quantum systems (OQS). We also analyse the issue of A-representability for the Kohn-Sham (KS) scheme proposed by D'Agosta and Di Ventra for Markovian OQS [Phys. Rev. Lett. 2007, 98, 226403] and discuss its domain of validity. We suggest ways to expand their scheme, but also propose a novel KS scheme where the auxiliary system is both closed and non-interacting. This scheme is tested numerically with a model system, and several considerations for the future development of functionals are indicated. Our results formalize the possibility of practising TD-CDFT in OQS, hence expanding the applicability of the theory to non-Hamiltonian evolutions.

  7. High current density and low emission field of carbon nanotube array microbundle

    Science.gov (United States)

    Zhang, Quan; Wang, Xi-juan; Meng, Peng; Yue, Hong-xin; Zheng, Rui-ting; Wu, Xiao-ling; Cheng, Guo-an

    2018-01-01

    Field electron emission from carbon nanotubes shows promising application potential in devices. Low adhesive bonding strength between the carbon nanotubes and the substrate presents a practical challenge in environments such as high field emission current density. In this paper, we report on the performance of a carbon nanotube microbundle attached to a tungsten needle by a uniform glue layer. The device is easily fabricated without complex fixture and possesses a complete array structure. After curing the glue in air, the adhesive strength between the carbon nanotubes and the needle is over 2000 N/cm2. Field emission measurements demonstrate that the maximum current density of the emitters is over 20 A/cm2 under a low applied field (X-ray tubes, and lamps.

  8. Distributions of the ion temperature, ion pressure, and electron density over the current sheet surface

    Energy Technology Data Exchange (ETDEWEB)

    Kyrie, N. P., E-mail: kyrie@fpl.gpi.ru; Markov, V. S., E-mail: natalya.kyrie@yandex.ru; Frank, A. G.; Vasilkov, D. G.; Voronova, E. V. [Russian Academy of Sciences, Prokhorov General Physics Institute (Russian Federation)

    2016-06-15

    The distributions of the ion temperature, ion pressure, and electron density over the width (the major transverse dimension) of the current sheet have been studied for the first time. The current sheets were formed in discharges in argon and helium in 2D and 3D magnetic configurations. It is found that the temperature of argon ions in both 2D and 3D magnetic configurations is almost uniform over the sheet width and that argon ions are accelerated by the Ampère force. In contrast, the distributions of the electron density and the temperature of helium ions are found to be substantially nonuniform. As a result, in the 2D magnetic configuration, the ion pressure gradient across the sheet width makes a significant contribution (comparable with the Ampère force) to the acceleration of helium ions, whereas in the 3D magnetic configuration, the Ampère force is counterbalanced by the pressure gradient.

  9. Large high current density superconducting solenoid for the time projection chamber experiment

    International Nuclear Information System (INIS)

    Green, M.A.; Burns, W.A.; Eberhard, P.H.; Gibson, G.H.; Miller, P.B.; Ross, R.R.; Smits, R.G.; Taylor, J.D.

    1978-06-01

    One of the experiments for the PEP storage rings at the Stanford Linear Accelerator Center uses a superconducting magnet to provide the magnetic field for the Time Projection Chamber detector. This magnet has an inside diameter of 2.04 m and a gap of 3.26 m. The magnet central induction is 1.5 T. This magnetic induction is supplied by a thin high current density superconducting coil which is less than 0.4 radiation lengths thick. The magnet stored energy will be 10.9 MJ; the coil superconductor matrix current density will be about 7.0 x 10 8 Am -2 . The TPC magnet uses a two-phase forced flow tubular cooling system which combines many of the advantages of single-phase supercritical helium cooling with those of boiling helium bath cooling

  10. Morphological features of the copper surface layer under sliding with high density electric current

    Energy Technology Data Exchange (ETDEWEB)

    Fadin, V. V., E-mail: fvv@ispms.ru [Institute of Strength Physics and Materials Science SB RAS, Tomsk, 634055 (Russian Federation); Aleutdinova, M. I., E-mail: aleut@ispms.ru [Institute of Strength Physics and Materials Science SB RAS, Tomsk, 634055 (Russian Federation); Seversk Technological Institute, Branch of State Autonomous Educational Institution of Higher Professional Education “National Research Nuclear University “MEPhI”, Seversk, 636036 (Russian Federation); Rubtsov, V. Ye., E-mail: rvy@ispms.ru [Institute of Strength Physics and Materials Science SB RAS, Tomsk, 634055 (Russian Federation); National Research Tomsk Polytechnic University, Tomsk, 634050 (Russian Federation); Aleutdinova, V. A., E-mail: valery-aleut@yandex.ru [National Research St. Petersburg State Polytechnical University, St. Petersburg, 195251 (Russian Federation)

    2015-10-27

    Conductivity and wear intensity of copper under the influence of dry friction and electric current with contact density higher 100 A/cm{sup 2} are presented. It is shown that an increase in hardness and heat outflow from a friction zone leads to the reduction of wear intensity and current contact density increase corresponding to the beginning of catastrophic wear. Structural changes, such as the formation of FeO oxide and α-Fe particles in the copper surface layer, have also been found. It is observed that a worn surface is deformed according to a viscous liquid mechanism. Such singularity is explained in terms of appearance of high-excited atomic states in deforming micro-volumes near contact spots that lead to easy stress relaxation by local plastic shears in the vicinity of stress concentrators. In common this effect allows to achieve high wear resistance.

  11. Degradation of Solid Oxide Electrolysis Cells Operated at High Current Densities

    DEFF Research Database (Denmark)

    Tao, Youkun; Ebbesen, Sune Dalgaard; Mogensen, Mogens Bjerg

    2014-01-01

    In this work the durability of solid oxide cells for co-electrolysis of steam and carbon dioxide (45 % H2O + 45 % CO2 + 10 % H2) at high current densities was investigated. The tested cells are Ni-YSZ electrode supported, with a YSZ electrolyte and either a LSM-YSZ or LSCF-CGO oxygen electrode....... A current density of -1.5 and -2.0 A/cm2 was applied to the cell and the gas conversion was 45 % and 60 %, respectively. The cells were operated for a period of up to 700 hours. The electrochemical analysis revealed significant performance degradation for the ohmic process, oxygen ion interfacial transfer...

  12. Distribution of the Current Density in Electrolyte of the Pem Fuel Cell

    Directory of Open Access Journals (Sweden)

    Eugeniusz Kurgan

    2004-01-01

    Full Text Available In this paper water management in proton exchange membrane (PEM fuel cell is considered. Firt mass convervation law for water is applied. Next proton transport is described by the Nernst-Planck equation and liqid water convection velocity is eliminated by the Schlogl equation. Electro-osmotic drag coefficient is related to hydrogen index and experimentally determined swelling coefficient. Three partial differential equations for molar water concentration Cw, electric potential ϕ and water pressure Pw are formulated. Current density vector i is derived from proton flux expression. These equations together with adequate boundary conditions were solved using finite element method. The distribution of electric potential and current density in function of geometrical parametres is investigated. At the end some illustrative example is given.

  13. Results of Current Density Distribution Mapping in PEM Fuel Cells Dependent on Operation Parameters

    Directory of Open Access Journals (Sweden)

    Zbigniew A. Styczynski

    2013-07-01

    Full Text Available This paper presents in situ measurements of a newly developed current density measurement system for proton exchange membrane fuel cells (PEMFC. While the functional principle and technical evaluation of the measurement system were presented in a previous paper, this paper analyzes the influence of various operation parameters, including multiple start-stop operation, at the anode, cathode and cooling locations on the distribution and long-term development of the current density. The system was operated for 500 h over two years with long periods of inactivity between measurements. The measurement results are evaluated and provide additional information on how to optimize the operation modes of fuel cells, including the start and stop of such systems as well as the water balance.

  14. Effect of Current Density on Optical Properties of Anisotropic Photoelectrochemical Etched Silicon (110)

    Science.gov (United States)

    Amirhoseiny, M.; Hassan, Z.; Ng, S. S.

    2012-08-01

    Photoelectrochemical etched Si layers were prepared on n-type (110) oriented silicon wafer. The photoluminescence (PL), Fourier transformed infrared (FTIR) absorption and Raman spectroscopies of etched Si (110) at two different current densities were studied. Both samples showed PL peak in the visible spectral range situated from 650 nm to 750 nm. The corresponding changes in Raman spectra at different current density are discussed. The blue shift in the PL and Raman peaks is consequent of the quantum confinement effect and defect states of surface Si nanocrystallites complexes and hydrogen atoms of the photoelectrochemical etched Si (110) samples. The attenuated total reflection (ATR) results show both hydrogen and oxygen related IR modes in the samples which can be used to explain the PL effect.

  15. Attenuation, phase velocity and current density distribution in high critical temperature superconducting planar transmission lines

    Energy Technology Data Exchange (ETDEWEB)

    Cabon, B.; Vu Dinh, T.; Chilo, J. [URA CNRS 833, Grenoble (France). Lab. d`Electromagnetisme

    1995-05-01

    Electromagnetic calculation of propagation parameters for high {Tc} superconductive coplanar and microstrip transmission lines is presented. Calculations are performed by a nodal circuit simulator (SPICE), with possibility of direct interfacing with CAE standards. The results are in good agreement with data obtained with a full-wave analysis and CPU time is much smaller than in standard MW applications. Then, current density distributions are shown.

  16. A new wavelet transform to sparsely represent cortical current densities for EEG/MEG inverse problems.

    Science.gov (United States)

    Liao, Ke; Zhu, Min; Ding, Lei

    2013-08-01

    The present study investigated the use of transform sparseness of cortical current density on human brain surface to improve electroencephalography/magnetoencephalography (EEG/MEG) inverse solutions. Transform sparseness was assessed by evaluating compressibility of cortical current densities in transform domains. To do that, a structure compression method from computer graphics was first adopted to compress cortical surface structure, either regular or irregular, into hierarchical multi-resolution meshes. Then, a new face-based wavelet method based on generated multi-resolution meshes was proposed to compress current density functions defined on cortical surfaces. Twelve cortical surface models were built by three EEG/MEG softwares and their structural compressibility was evaluated and compared by the proposed method. Monte Carlo simulations were implemented to evaluate the performance of the proposed wavelet method in compressing various cortical current density distributions as compared to other two available vertex-based wavelet methods. The present results indicate that the face-based wavelet method can achieve higher transform sparseness than vertex-based wavelet methods. Furthermore, basis functions from the face-based wavelet method have lower coherence against typical EEG and MEG measurement systems than vertex-based wavelet methods. Both high transform sparseness and low coherent measurements suggest that the proposed face-based wavelet method can improve the performance of L1-norm regularized EEG/MEG inverse solutions, which was further demonstrated in simulations and experimental setups using MEG data. Thus, this new transform on complicated cortical structure is promising to significantly advance EEG/MEG inverse source imaging technologies. Copyright © 2013 Elsevier Ireland Ltd. All rights reserved.

  17. Contactless estimation of critical current density and its temperature dependence using magnetic measurements

    Czech Academy of Sciences Publication Activity Database

    Youssef, A.; Baničová, L.; Švindrych, Zdeněk; Janů, Zdeněk

    2010-01-01

    Roč. 118, č. 5 (2010), s. 1036-1037 ISSN 0587-4246. [Czech and Slovak Conference on Magnetism /14./. Košice, 06.07.2010-09.07.2010] R&D Projects: GA MŠk(CZ) ME10069 Institutional research plan: CEZ:AV0Z10100520 Keywords : superconductivity * critical state * Bean model * critical current density Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 0.467, year: 2010

  18. Measurements of current density distribution in shaped e-beam writers

    Czech Academy of Sciences Publication Activity Database

    Bok, Jan; Horáček, Miroslav; Kolařík, Vladimír; Urbánek, Michal; Matějka, Milan; Krzyžánek, Vladislav

    2016-01-01

    Roč. 149, JAN 5 (2016), s. 117-124 ISSN 0167-9317 R&D Projects: GA ČR(CZ) GA14-20012S; GA MŠk(CZ) LO1212; GA MŠk ED0017/01/01 Institutional support: RVO:68081731 Keywords : shaped e-beam writer * electron beam * current density Subject RIV: JB - Sensors, Measurment, Regulation Impact factor: 1.806, year: 2016

  19. Dependence of critical current density on crystalline direction in thin YBCO films

    DEFF Research Database (Denmark)

    Paturi, P.; Peurla, M.; Raittila, J.

    2005-01-01

    The dependence of critical current density (J(c)) on the angle between the current direction and the (100) direction in the ab-plane of thin YBCO films deposited on (001)-SrTiO3 from natiocrystalline and microcrystalline targets is studied using magneto-optical microscopy. In the films made from...... the nanocrystalline target it is found that J(c) does not depend on the angle whereas J(c) decreases with increasing angle in the films made from the microcrystalline target. The films were characterized by detailed X-ray diffraction measurements. The findings are explained in terms of a network of planar defects...

  20. Reduction in Recombination Current Density in Boron Doped Silicon Using Atomic Hydrogen

    Science.gov (United States)

    Young, Matthew Garett

    The solar industry has grown immensely in recent years and has reached a point where solar energy has now become inexpensive enough that it is starting to emerge as a mainstream electrical generation source. However, recent economic analysis has suggested that for solar to become a truly wide spread source of electricity, the costs still need to plummet by a factor of 8x. This demands new and innovative concepts to help lower such cost. In pursuit of this goal, this dissertation examines the use of atomic hydrogen to lessen the recombination current density in the boron doped region of n-type silicon solar cells. This required the development of a boron diffusion process that maintained the bulk lifetime of n-type silicon such that the recombination current density could be extracted by photoconductance spectroscopy. It is demonstrated that by hydrogenating boron diffusions, the majority carrier concentration can be controlled. By using symmetrically diffused test structures with quinhydrone-methanol surface passivation the recombination current density of a hydrogenated boron profile is shown to be less than that of a standard boron profile, by as much as 30%. This is then applied to a modified industrial silicon solar cell process to demonstrate an efficiency enhancement of 0.4%.

  1. Development of large high current density superconducting solenoid magnets for use in high energy physics experiments

    International Nuclear Information System (INIS)

    Green, M.A.

    1977-05-01

    The development of a unique type of large superconducting solenoid magnet, characterized by very high current density windings and a two-phase helium tubular cooling system is described. The development of the magnet's conceptual design and the construction of two test solenoids are described. The successful test of the superconducting coil and its tubular cooling refrigeration system is presented. The safety, environmental and economic impacts of the test program on future developments in high energy physics are shown. Large solid angle particle detectors for colliding beam physics will analyze both charged and neutral particles. In many cases, these detectors will require neutral particles, such as gamma rays, to pass through the magnet coil with minimum interaction. The magnet coils must be as thin as possible. The use of superconducting windings allows one to minimize radiation thickness, while at the same time maximizing charged particle momentum resolution and saving substantial quantities of electrical energy. The results of the experimental measurements show that large high current density solenoid magnets can be made to operate at high stored energies. The superconducting magnet development described has a positive safety and environmental impact. The use of large high current density thin superconducting solenoids has been proposed in two high energy physics experiments to be conducted at the Stanford Linear Accelerator Center and Cornell University as a result of the successful experiments described

  2. High current density in bulk YBa2Cu3O/sub x/ superconductor

    International Nuclear Information System (INIS)

    Salama, K.; Selvamanickam, V.; Gao, L.; Sun, K.

    1989-01-01

    A liquid phase processing method for the fabrication of bulk YBa 2 Cu 3 O/sub x/ superconductors with large current carrying capacity has been developed. Slow cooling through the peritectic transformation (1030--980 degree C) has been shown to control the microstructure of these superconductors. A cooling rate of 1 degree C/h in this temperature range has yielded a microstructure with long plate type, thick grains oriented over a wide area. Current density up to 18 500 A/cm 2 has been obtained by continuous direct current measurements and in excess of 62 000 A/cm 2 with pulse current of 10 ms duration and 75 000 A/cm 2 using 1 ms pulse. The strong magnetic field dependence observed in sintered bulk 1-2-3 superconductors is also minimized to a large extent where a current density in excess of 37 000 A/cm 2 is obtained in a field of 6000 G

  3. Fast electron current density profile and diffusion studies during LHCD in PBX-M

    Energy Technology Data Exchange (ETDEWEB)

    Jones, S.E.; Kesner, J.; Luckhardt, S.; Paoletti, F. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Plasma Fusion Center; von Goeler, S.; Bernabei, S.; Kaita, R. [Princeton Univ., NJ (United States). Plasma Physics Lab.; Rimini, F. [JET Joint Undertaking, Abingdon (United Kingdom)

    1993-08-01

    Successful current profile control experiments using lower hybrid current drive (LCHD) clearly require knowledge of (1) the location of the driven fast electrons and (2) the ability to maintain that location from spreading due to radial diffusion. These issues can be addressed by examining the data from the hard x-ray camera on PBX-M, a unique diagnostic producing two-dimensional, time resolved tangential images of fast electron bremsstrahlung. Using modeling, these line-of-sight images are inverted to extract a radial fast electron current density profile. We note that ``hollow`` profiles have been observed, indicative of off-axis current drive. These profiles can then be used to calculate an upper bound for an effective fast electron diffusion constant: assuming an extremely radially narrow lower hybrid absorption profile and a transport model based on Rax and Moreau, a model fast electron current density profile is calculated and compared to the experimentally derived profile. The model diffusion constant is adjusted until a good match is found. Applied to steady-state quiescent modes on PBX-M, we obtain an upper limit for an effective diffusion constant of about D*=1.1 m{sup 2}/sec.

  4. [Corrosion resistant properties of different anodized microtopographies on titanium surfaces].

    Science.gov (United States)

    Fangjun, Huo; Li, Xie; Xingye, Tong; Yueting, Wang; Weihua, Guo; Weidong, Tian

    2015-12-01

    To investigate the corrosion resistant properties of titanium samples prepared by anodic oxidation with different surface morphologies. Pure titanium substrates were treated by anodic oxidation to obtain porous titanium films in micron, submicron, and micron-submicron scales. The surface morphologies, coating cross-sectional morphologies, crystalline structures, and surface roughness of these samples were characterized. Electrochemical technique was used to measure the corrosion potential (Ecorr), current density of corrosion (Icorr), and polarization resistance (Rp) of these samples in a simulated body fluid. Pure titanium could be modified to exhibit different surface morphologies by the anodic oxidation technique. The Tafel curve results showed that the technique can improve the corrosion resistance of pure titanium. Furthermore, the corrosion resistance varied with different surface morphologies. The submicron porous surface sample demonstrated the best corrosion resistance, with maximal Ecorr and Rp and minimal Icorr. Anodic oxidation technology can improve the corrosion resistance of pure titanium in a simulated body fluid. The submicron porous surface sample exhibited the best corrosion resistance because of its small surface area and thick barrier layer.

  5. The effect of current density and saccharin addition on the grain size of nickel coatings

    Energy Technology Data Exchange (ETDEWEB)

    Uhm, Young Rang; Park, Keun Yung; Son, Kwang Jae; Shim, Young Ho; Choi, Sun Ju [KAERI, Daejeon (Korea, Republic of)

    2012-10-15

    Recently, the main advantage of a radioisotope 'fuel' is concentrated, because it is 'burned' at the rate of the isotopes half life. In other words, given a half life of 100 years, a nuclear battery would still produce half of its initial starting power after 100 years. A speck of a radioisotope like nickel 63, for example, contains enough energy to power a nano nuclear battery for decades, and to do so safely. Ni 63, a beta radiation source, is prepared by electrical deposition of radioactive Ni 63 ions on thin non radioactive nickel foil. Ni 63 plating is similar to other electroplating processes that employ soluble metal anodes. It requires the passage of a direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. The charged Ni ions are formed by sulfate, sulfamate, chloride, and a Watts bath. However, the charged Ni 63 ions are formed by dissolving metal Ni 63. To establish the coating condition of Ni 63, non radioactive metal Ni particles were dissolved in an acid solution and electroplated on the Ni sheet. A continuous increase in the grain size versus current density has also been recognized in the direct current electrodeposition of nickel coating. On the other hand, A runa et al. reported that the current density has no significant effect on the grain size of nickel electro deposits. A review of the literature shows that saccharin has often been added to a nickel plating bath since the 1980s to improve the ductility and brightness, and in later periods as a grain refiner agent. In the present paper, not only the preparation of the Ni plating solution prepared by dissolving metal particles but also an optimization of the deposition conditions, such as the influence of current density and saccharin concentration on the grain size, was investigated. The proposed model can also be applied for radioactive Ni 63 electroplating.

  6. Corrosion of 304 stainless steel exposed to nitric acid-chloride environments

    International Nuclear Information System (INIS)

    Kolman, D.G.; Ford, D.K.; Butt, D.P.; Nelson, T.O.

    1997-01-01

    In an effort to examine the combined effect of HNO 3 , NaCl, and temperature on the general corrosion behavior of 304 stainless steel (SS), electrochemical studies were performed. It was found that the corrosion response of 304 SS was bifurcated: materials were either continuously passive following immersion or spontaneously passivated following a period of active dissolution. Increasing NaCl concentrations promoted pitting, active dissolution upon initial immersion, a smaller potential range for passivity, longer active corrosion periods, larger active anodic charge densities preceding spontaneous passivation, and larger corrosion current and peak current densities. In contrast, intermediate HNO 3 concentrations were found to promote active dissolution, with continuous passivity noted at HNO 3 concentration extremes. During active corrosion, increasing HNO 3 concentration increased anodic charge density, corrosion current density, and peak current density. The time required for spontaneous passivation was found to be maximized at intermediate HNO 3 concentrations. Susceptibility to pitting was found to be highest at intermediate HNO 3 concentrations. The pit initiation and repassivation potentials decreased with increasing HNO 3 until the HNO 3 concentration exceeded a critical concentration where pitting susceptibility was entirely eliminated. No differences between 304 SS, 304 L SS, and sensitized 304 SS were apparent in solutions yielding active dissolution, passive, dissolution or pitting. Increasing solution temperatures increased the susceptibility to both pitting and active dissolution. 53 refs

  7. Dynamics of low density coronal plasma in low current x-pinches

    International Nuclear Information System (INIS)

    Haas, D; Bott, S C; Vikhrev, V; Eshaq, Y; Ueda, U; Zhang, T; Baranova, E; Krasheninnikov, S I; Beg, F N

    2007-01-01

    Experiments were performed on an x-pinch using a pulsed power current generator capable of producing an 80 kA current with a rise time of 50 ns. Molybdenum wires with and without gold coating were employed to study the effect of high z coating on the low-density ( 18 cm -3 ) coronal plasma dynamics. A comparison of images from XUV frames and optical probing shows that the low density coronal plasma from the wires initially converges at the mid-plane immediately above and below the cross-point. A central jet is formed which moves with a velocity of 6 x 10 4 ms -1 towards both electrodes forming a z-pinch column before the current maximum. A marked change in the low density coronal plasma dynamics was observed when molybdenum wires coated with ∼ 0.09 μm of gold were used. The processes forming the jet structure were delayed relative to bare Mo x-pinches, and the time-resolved x-ray emission also showed differences. An m = 0 instability was observed in the coronal plasma along the x-pinch legs, which were consistent with x-ray PIN diode signals in which x-ray pulses were observed before x-ray spot formation. These early time x-ray pulses were not observed with pure molybdenum x-pinches. These observations indicate that a thin layer of gold coating significantly changes the coronal plasma behaviour. Two dimensional MHD simulations were performed and qualitatively agree with experimental observations of low density coronal plasma

  8. Effect of Nitrite Inhibitor on the Macrocell Corrosion Behavior of Reinforcing Steel

    Directory of Open Access Journals (Sweden)

    Zhonglu Cao

    2015-01-01

    Full Text Available The effect of nitrite ions on the macrocell corrosion behavior of reinforcing steel embedded in cement mortar was investigated by comparing and analyzing the macrocell corrosion current, macrocell polarization ratios, and slopes of anodic and cathodic steels. Based on the experimental results, the relationship between macrocell potential difference and macrocell current density was analyzed, and the mechanism of macrocell corrosion affected by nitrite ions was proposed. The results indicated that nitrite ions had significant impact on the macrocell polarization ratios of cathode and anode. The presence of nitrite could reduce the macrocell current by decreasing the macrocell potential difference and increasing the macrocell polarization resistance of the anode.

  9. Impurities, temperature, and density in a miniature electrostatic plasma and current source

    International Nuclear Information System (INIS)

    Den Hartog, D.J.; Craig, D.J.; Fiksel, G.; Sarff, J.S.

    1996-10-01

    We have spectroscopically investigated the Sterling Scientific miniature electrostatic plasma source-a plasma gun. This gun is a clean source of high density (10 19 - 10 20 m -3 ), low temperature (5 - 15 eV) plasma. A key result of our investigation is that molybdenum from the gun electrodes is largely trapped in the internal gun discharge; only a small amount escapes in the plasma flowing out of the gun. In addition, the gun plasma parameters actually improve (even lower impurity contamination and higher ion temperature) when up to 1 kA of electron current is extracted from the gun via the application of an external bias. This improvement occurs because the internal gun anode no longer acts as the current return for the internal gun discharge. The gun plasma is a virtual plasma electrode capable of sourcing an electron emission current density of 1 kA/cm 2 . The high emission current, small size (3 - 4 cm diameter), and low impurity generation make this gun attractive for a variety of fusion and plasma technology applications

  10. Polarization Potential Has No Effect on Maximum Current Density Produced by Halotolerant Bioanodes

    Directory of Open Access Journals (Sweden)

    Muriel González-Muñoz

    2018-03-01

    Full Text Available Halotolerant bioanodes are considered an attractive alternative in microbial electrochemical systems, as they can operate under higher conductive electrolytes, in comparison with traditional wastewater and freshwater bioanodes. The dependency between energetic performance and polarization potential has been addressed in several works; however the vast majority discusses its effect when wastewater or freshwater inocula are employed, and fewer reports focus on inocula from highly-saline environments. Moreover, the effect of the polarization potential on current production is not fully understood. To determine if the polarization potential has a significant effect on current production, eight bioanodes were grown by chronoamperometry at positive and negative potentials relative to the reference electrode (+0.34 V/SHE and −0.16 V/SHE, in a three-electrode set-up employing sediments from a hyperhaline coastal lagoon. The maximum current density obtained was the same, despite the differences in the applied potential. Our findings indicate that even if differences in organic matter removal and coulombic efficiency are obtained, the polarization potential had no statistically significant effect on overall current density production.

  11. Public magnetic field exposure based on internal current density for electric low voltage systems.

    Science.gov (United States)

    Keikko, Tommi; Seesvuori, Reino; Hyvönen, Martti; Valkealahti, Seppo

    2009-04-01

    A measurement concept utilizing a new magnetic field exposure metering system has been developed for indoor substations where voltage is transformed from a medium voltage of 10 or 20 kV to a low voltage of 400 V. The new metering system follows the guidelines published by the International Commission on Non-Ionizing Radiation Protection. It can be used to measure magnetic field values, total harmonic distortion of the magnetic field, magnetic field exposure ratios for public and workers, load current values, and total harmonic distortion of the load current. This paper demonstrates how exposure to non-sinusoidal magnetic fields and magnetic flux density exposure values can be compared directly with limit values for internal current densities in a human body. Further, we present how the magnetic field and magnetic field exposure behaves in the vicinity of magnetic field sources within the indoor substation and in the neighborhood. Measured magnetic fields around the substation components have been used to develop a measurement concept by which long-term measurements in the substations were performed. Long-term measurements revealed interesting and partly unexpected dependencies between the measured quantities, which have been further analyzed. The principle of this paper is to substitute a demanding exposure measurement with measurements of the basic quantities like the 50 Hz fundamental magnetic field component, which can be estimated based on the load currents for certain classes of substation lay-out.

  12. Human in-vivo brain magnetic resonance current density imaging (MRCDI).

    Science.gov (United States)

    Göksu, Cihan; Hanson, Lars G; Siebner, Hartwig R; Ehses, Philipp; Scheffler, Klaus; Thielscher, Axel

    2018-05-01

    Magnetic resonance current density imaging (MRCDI) and MR electrical impedance tomography (MREIT) are two emerging modalities, which combine weak time-varying currents injected via surface electrodes with magnetic resonance imaging (MRI) to acquire information about the current flow and ohmic conductivity distribution at high spatial resolution. The injected current flow creates a magnetic field in the head, and the component of the induced magnetic field ΔB z,c parallel to the main scanner field causes small shifts in the precession frequency of the magnetization. The measured MRI signal is modulated by these shifts, allowing to determine ΔB z,c for the reconstruction of the current flow and ohmic conductivity. Here, we demonstrate reliable ΔB z,c measurements in-vivo in the human brain based on multi-echo spin echo (MESE) and steady-state free precession free induction decay (SSFP-FID) sequences. In a series of experiments, we optimize their robustness for in-vivo measurements while maintaining a good sensitivity to the current-induced fields. We validate both methods by assessing the linearity of the measured ΔB z,c with respect to the current strength. For the more efficient SSFP-FID measurements, we demonstrate a strong influence of magnetic stray fields on the ΔB z,c images, caused by non-ideal paths of the electrode cables, and validate a correction method. Finally, we perform measurements with two different current injection profiles in five subjects. We demonstrate reliable recordings of ΔB z,c fields as weak as 1 nT, caused by currents of 1 mA strength. Comparison of the ΔB z,c measurements with simulated ΔB z,c images based on FEM calculations and individualized head models reveals significant linear correlations in all subjects, but only for the stray field-corrected data. As final step, we reconstruct current density distributions from the measured and simulated ΔB z,c data. Reconstructions from non-corrected ΔB z,c measurements

  13. Corrosion cracking

    International Nuclear Information System (INIS)

    Goel, V.S.

    1985-01-01

    This book presents the papers given at a conference on alloy corrosion cracking. Topics considered at the conference included the effect of niobium addition on intergranular stress corrosion cracking, corrosion-fatigue cracking in fossil-fueled-boilers, fracture toughness, fracture modes, hydrogen-induced thresholds, electrochemical and hydrogen permeation studies, the effect of seawater on fatigue crack propagation of wells for offshore structures, the corrosion fatigue of carbon steels in seawater, and stress corrosion cracking and the mechanical strength of alloy 600

  14. The effect of urea on the corrosion behavior of different dental alloys.

    Science.gov (United States)

    Geckili, Onur; Bilhan, Hakan; Bilgin, Tayfun; Anthony von Fraunhofer, J

    2012-01-01

    Intraoral corrosion of dental alloys has biological, functional, and esthetic consequences. Since it is well known that the salivary urea concentrations undergo changes with various diseases, the present study was undertaken to determine the effect of salivary urea concentrations on the corrosion behavior of commonly used dental casting alloys. Three casting alloys were subjected to polarization scans in synthetic saliva with three different urea concentrations. Cyclic polarization clearly showed that urea levels above 20 mg/100 ml decreased corrosion current densities, increased the corrosion potentials and, at much higher urea levels, the breakdown potentials. The data indicate that elevated urea levels reduced the corrosion susceptibility of all alloys, possibly through adsorption of organics onto the metal surface. This study indicates that corrosion testing performed in sterile saline or synthetic saliva without organic components could be misleading.

  15. Marine corrosion protective coatings of hexagonal boron nitride thin films on stainless steel.

    Science.gov (United States)

    Husain, Esam; Narayanan, Tharangattu N; Taha-Tijerina, Jose Jaime; Vinod, Soumya; Vajtai, Robert; Ajayan, Pulickel M

    2013-05-22

    Recently, two-dimensional, layered materials such as graphene and hexagonal boron nitride (h-BN) have been identified as interesting materials for a range of applications. Here, we demonstrate the corrosion prevention applications of h-BN in marine coatings. The performance of h-BN/polymer hybrid coatings, applied on stainless steel, were evaluated using electrochemical techniques in simulated seawater media [marine media]. h-BN/polymer coating shows an efficient corrosion protection with a low corrosion current density of 5.14 × 10(-8) A/cm(2) and corrosion rate of 1.19 × 10(-3) mm/year and it is attributed to the hydrofobic, inert and dielectric nature of boron nitride. The results indicated that the stainless steel with coatings exhibited improved corrosion resistance. Electrochemical impedance spectroscopy and potentiodynamic analysis were used to propose a mechanism for the increased corrosion resistance of h-BN coatings.

  16. Effects of the current boundary conditions at the plasma-gun gap on density in SSPX

    Science.gov (United States)

    Kolesnikov, Roman; Lodestro, L. L.; Meyer, W. H.

    2012-10-01

    The Sustained Spheromak Physics Experiment (SSPX) was a toroidal magnetic-confinement device without toroidal magnetic-field coils or a central transformer but which generated core-plasma currents by dynamo processes driven by coaxial plasma-gun injection into a flux-conserving vessel. Record electron temperatures in a spheromak (Te˜500eV) were achieved, and final results of the SSPX program were reported in [1]. Plasma density, which depended strongly on wall conditions, was an important parameter in SSPX. It was observed that density rises with Igun and that confinement improved as the density was lowered. Shortly after the last experiments, a new feature was added to the Corsica code's solver used to reconstruct SSPX equilibria. Motivated by n=0 fields observed in NIMROD simulations of SSPX, an insulating boundary condition was implemented at the plasma-gun gap. Using this option we will perform new reconstructions of SSPX equilibria and look for correlations between the location of the separatrix (which moves up the gun wall and onto the insulating gap as Igun increases) and plasma density and magnetic-flux amplification [2].[4pt] [1] H. S. McLean, APS, DPP, Dallas, TX, 2008.[0pt] [2] E. B. Hooper et al., Nucl. Fusion 47, 1064 (2007).

  17. Reduction of Gas Bubbles and Improved Critical Current Density in Bi-2212 Round Wire by Swaging

    CERN Document Server

    Jiang, J; Huang, Y; Hong, S; Parrell, J; Scheuerlein, C; Di Michiel, M; Ghosh, A; Trociewitz, U; Hellstrom, E; Larbalestier, D

    2013-01-01

    Bi-2212 round wire is made by the powder-in-tube technique. An unavoidable property of powder-in-tube conductors is that there is about 30% void space in the as-drawn wire. We have recently shown that the gas present in the as-drawn Bi-2212 wire agglomerates into large bubbles and that they are presently the most deleterious current limiting mechanism. By densifying short 2212 wires before reaction through cold isostatic pressing (CIPping), the void space was almost removed and the gas bubble density was reduced significantly, resulting in a doubled engineering critical current density (JE) of 810 A/mm2 at 5 T, 4.2 K. Here we report on densifying Bi-2212 wire by swaging, which increased JE (4.2 K, 5 T) from 486 A/mm2 for as-drawn wire to 808 A/mm2 for swaged wire. This result further confirms that enhancing the filament packing density is of great importance for making major JE improvement in this round-wire magnet conductor.

  18. Studies in High Current Density Ion Sources for Heavy Ion Fusion Applications

    International Nuclear Information System (INIS)

    Chacon-Golcher, E.

    2002-01-01

    This dissertation develops diverse research on small (diameter ∼ few mm), high current density (J ∼ several tens of mA/cm 2 ) heavy ion sources. The research has been developed in the context of a programmatic interest within the Heavy Ion Fusion (HIF) Program to explore alternative architectures in the beam injection systems that use the merging of small, bright beams. An ion gun was designed and built for these experiments. Results of average current density yield ( ) at different operating conditions are presented for K + and Cs + contact ionization sources and potassium aluminum silicate sources. Maximum values for a K + beam of ∼90 mA/cm 2 were observed in 2.3 (micro)s pulses. Measurements of beam intensity profiles and emittances are included. Measurements of neutral particle desorption are presented at different operating conditions which lead to a better understanding of the underlying atomic diffusion processes that determine the lifetime of the emitter. Estimates of diffusion times consistent with measurements are presented, as well as estimates of maximum repetition rates achievable. Diverse studies performed on the composition and preparation of alkali aluminosilicate ion sources are also presented. In addition, this work includes preliminary work carried out exploring the viability of an argon plasma ion source and a bismuth metal vapor vacuum arc (MEVVA) ion source. For the former ion source, fast rise-times (∼ 1 (micro)s), high current densities (∼ 100 mA/cm 2 ) and low operating pressures ( e psilon) n (le) 0.006 π mm · mrad) although measured currents differed from the desired ones (I ∼ 5mA) by about a factor of 10

  19. Studies in High Current Density Ion Sources for Heavy Ion Fusion Applications

    Energy Technology Data Exchange (ETDEWEB)

    Chacon-Golcher, Edwin [Univ. of California, Berkeley, CA (United States)

    2002-06-01

    This dissertation develops diverse research on small (diameter ~ few mm), high current density (J ~ several tens of mA/cm2) heavy ion sources. The research has been developed in the context of a programmatic interest within the Heavy Ion Fusion (HIF) Program to explore alternative architectures in the beam injection systems that use the merging of small, bright beams. An ion gun was designed and built for these experiments. Results of average current density yield () at different operating conditions are presented for K+ and Cs+ contact ionization sources and potassium aluminum silicate sources. Maximum values for a K+ beam of ~90 mA/cm2 were observed in 2.3 μs pulses. Measurements of beam intensity profiles and emittances are included. Measurements of neutral particle desorption are presented at different operating conditions which lead to a better understanding of the underlying atomic diffusion processes that determine the lifetime of the emitter. Estimates of diffusion times consistent with measurements are presented, as well as estimates of maximum repetition rates achievable. Diverse studies performed on the composition and preparation of alkali aluminosilicate ion sources are also presented. In addition, this work includes preliminary work carried out exploring the viability of an argon plasma ion source and a bismuth metal vapor vacuum arc (MEVVA) ion source. For the former ion source, fast rise-times (~ 1 μs), high current densities (~ 100 mA/cm+) and low operating pressures (< 2 mtorr) were verified. For the latter, high but acceptable levels of beam emittance were measured (εn ≤ 0.006 π· mm · mrad) although measured currents differed from the desired ones (I ~ 5mA) by about a factor of 10.

  20. High current density Esaki tunnel diodes based on GaSb-InAsSb heterostructure nanowires.

    Science.gov (United States)

    Ganjipour, Bahram; Dey, Anil W; Borg, B Mattias; Ek, Martin; Pistol, Mats-Erik; Dick, Kimberly A; Wernersson, Lars-Erik; Thelander, Claes

    2011-10-12

    We present electrical characterization of broken gap GaSb-InAsSb nanowire heterojunctions. Esaki diode characteristics with maximum reverse current of 1750 kA/cm(2) at 0.50 V, maximum peak current of 67 kA/cm(2) at 0.11 V, and peak-to-valley ratio (PVR) of 2.1 are obtained at room temperature. The reverse current density is comparable to that of state-of-the-art tunnel diodes based on heavily doped p-n junctions. However, the GaSb-InAsSb diodes investigated in this work do not rely on heavy doping, which permits studies of transport mechanisms in simple transistor structures processed with high-κ gate dielectrics and top-gates. Such processing results in devices with improved PVR (3.5) and stability of the electrical properties.

  1. Increasing Extracted Beam Current Density in Ion Thrusters through Plasma Potential Modification

    Science.gov (United States)

    Arthur, Neil; Foster, John

    2015-09-01

    A gridded ion thruster's maximum extractable beam current is determined by the space charge limit. The classical formulation does not take into account finite ion drift into the acceleration gap. It can be shown that extractable beam current can be increased beyond the conventional Child-Langmuir law if the ions enter the gap at a finite drift speed. In this work, ion drift in a 10 cm thruster is varied by adjusting the plasma potential relative to the potential at the extraction plane. Internal plasma potential variations are achieved using a novel approach involving biasing the magnetic cusps. Ion flow variations are assessed using simulated beam extraction in conjunction with a retarding potential analyzer. Ion beam current density changes at a given total beam voltage in full beam extraction tests are characterized as a function of induced ion drift velocity as well.

  2. Confinement bifurcation by current density profile perturbation in TUMAN-3M tokamak

    International Nuclear Information System (INIS)

    Lebedev, S.V.; Andreiko, M.V.; Askinazi, L.G.

    2001-01-01

    In the recent experiments performed on TUMAN-3M the possibility to switch on/off the H-mode by current density profile perturbations has been shown. The j(r) perturbations were created by fast Current Ramp Up/Down or by Magnetic Compression produced by a fast increase of the toroidal magnetic field. It was found that the Current Ramp Up (CRU) and Magnetic Compression (MC) are useful means for H-mode triggering. The Current Ramp Down (CRD) triggers H-L transition. The difference in the j(r) behavior in these experiments suggests the peripheral current density may not be the critical parameter controlling L-H and H-L transitions. Confinement bifurcation in the above experiments could be explained by the unified mechanism: variation of a turbulent transport resulting from radial electric field emerging near the edge in the conditions of alternating toroidal electric field Ej and different electron and ion collisionalities. According to the suggested model the toroidal field E φ arising in the periphery during the CRU and MC processes amplifies Ware drift, which mainly influences electron component. As a result the favorable for the transition negative (inward directed) E r emerges. In the CRD scenario, when E φ is opposite to the total plasma current direction, the mechanism should generate positive E r , which is thought to be unfavorable for the H-mode. The experimental data on L-H and H-L transitions in various scenarios and the results of the modeling of E r emerging in the CRU experiment are presented in the paper. (author)

  3. Comparative Evaluation of the Initial Corrosion of Four Brands of High Copper Dental Amalgams

    Directory of Open Access Journals (Sweden)

    V. Mortazavi

    2004-09-01

    Full Text Available Statement of Problem: Many attempts have been made in order to evaluate the amalgam corrosion behavior as an indicator of biocompatibility. Purpose: The aim of this study was to evaluate and compare the initial corrosion of four different brands of dental amalgams. Materials and Methods: Four different types of commercial high copper dental amalgam were studied. A special mold was used and twenty-one samples of each type of commercial dental amalgams were prepared. X-ray diffraction technique was used to investigate the microstructure of freshly prepared specimens. Electrochemical potentiodynamic tests were performed in physiological solutions in order to determine and compare the corrosion behavior of freshly prepared sample of four brands of dental amalgams. The physiological solutions were the Ringer’s solution and physiological normal saline. Five replicate tests on each group of specimens were performed. Tafel extrapolation and linear polarization methods determined corrosion potentials and corrosion current densities. The mean value and standard deviations of the results were calculated. The mean values were statistically compared by ANOVA and Duncan methods at 95% level of confidence. Results: Gamma-2 phase was present in freshly prepared sample of each type of commercial amalgam. The results showed statistically significant differences between the mean corrosion current density values of freshly prepared sample of four brands of amalgams (P<0.05. The freshly prepared specimen of Sybraloy dental amalgam possesses the higher initial corrosion resistance than the other three, and Cinaalloy dental amalgam possesses the lowest corrosion resistance. This trend is independent to the type of physiological environment. Conclusion: Initial corrosion resistance of each type of commercial dental amalgam is much less than its corrosion resistance that could be obtained after one week. From the viewpoint of the corrosion behavior as an indication of

  4. Numerical versus analytical Ic(H) patterns in Josephson junctions with periodically alternating critical current density

    International Nuclear Information System (INIS)

    Lazarides, N

    2004-01-01

    An analytical expression for the magnetic-field-dependent critical current I c (H) of Josephson junctions with periodically alternating critical current density J c (x) is derived within the uniform field approximation. Comparison with numerically calculated I c (H) patterns for junctions with identical, thick, periodically arranged defects with the corresponding analytical expression reveals fair agreement for a wide range of parameters, due to increased characteristic length. Based on qualitative arguments, we give the dependence of the new characteristic length on the geometrical parameters of the junction, which is in agreement with self-consistent calculations with the static sine-Gordon equation. The analytical expression captures the observed qualitative features of the I c (H) patterns, while it is practically exact for short junctions or high fields. It also produces the shift of the major peak from the zero-field position of the standard Fraunhofer pattern to another position related to the periodicity of the critical current density in φ-junctions

  5. Localized corrosion of carbon steels due to sulfate-reducing bacteria. Development of a specific sensor; Corrosion localisee des aciers au carbone induite par des bacteries sulfato-reductrices. Developpement d'un capteur specifique

    Energy Technology Data Exchange (ETDEWEB)

    Monfort Moros, N.

    2001-11-01

    This work concerns the microbiologically influenced corrosion of carbon steels in saline anaerobic media (3% of NaCl) containing sulfato-reducing bacteria (Desulfovibrio gabonensis, DSM 10636). In these media, extreme localised corrosion occurs by pitting under the bio-film covering the metallic substrate. A sensor with concentric electrodes was designed to initiate the phenomenon of bio-corrosion, recreating the favourable conditions for growth of a corrosion pit, and then measuring the corrosion current maintained by bacterial activity. The pit initiation was achieved through either of two methods. The electrochemical conditioning involved driving the potential difference between inner and outer electrodes to values corresponding to a galvanic corrosion that can be maintained by the bacterial metabolism. The mechanical process involved removal of a portion of the bio-film by scratching, yielding galvanic potential differences equivalent to that found by the conditioning technique. This protocol was found to be applicable to a bio-corrosion study on industrial site for the monitoring of the metallic structures deterioration (patent EN 00/06114, May 2000). Thereafter, a fundamental application uses the bio-corrosion sensor for Electrochemical Impedance Spectroscopy (EIS), Electrochemical Noise Analysis (ENA) and current density cartography by the means of micro-electrodes. Thus, the EIS technique reveals the importance of the FeS corrosion products for initiation of bio-corrosion start on carbon steel. In addition, depending on the method used to create a pit, the ENA gives rise to supplementary processes (gaseous release) disturbing the bio-corrosion detection. The beginning of a bio-corrosion process on a clean surface surrounded with bio-film was confirmed by the current density cartography. These different results establish the sensor with concentric electrodes as an indispensable tool for bio-corrosion studies, both in the laboratory and on industrial sites

  6. Effect of Nb3Sn layer structure and morphology on critical current density of multifilamentary superconductors

    Science.gov (United States)

    Deryagina, I. L.; Popova, E. N.; Patrakov, E. I.; Valova-Zaharevskaya, E. G.

    2017-10-01

    The microstructure and morphology of superconducting Nb3Sn layers in multifilamentary composites differing in the fabrication route (bronze technology and internal-tin method), the shape of Nb filaments (continuous, coupled and tubular) and in the mode of Ti doping (doping of bronze matrix or Nb filaments) have been studied. Significant factors determining critical current density of these wires are the average grain sizes and the fraction of equiaxed grains in the superconducting layers. The minimal grain sizes are characteristic of the composites with tubular Nb filaments, whereas the maximal fraction of equiaxed grains is obtained in the internal-tin wires.

  7. Test data on electrical contacts at high surface velocities and high current densities for homopolar generators

    International Nuclear Information System (INIS)

    Brennan, M.; Tolk, K.M.; Weldon, W.F.; Rylander, H.G.; Woodson, H.H.

    1977-01-01

    Test data is presented for one grade of copper graphite brush material, Morganite CMlS, over a wide range of surface velocities, atmospheres, and current densities that are expected for fast discharge (<100 ms) homopolar generators. The brushes were run on a copper coated 7075-T6 aluminum disk at surface speeds up to 277 m/sec. One electroplated copper and three flame sprayed copper coatings were used during the tests. Significant differences in contact voltage drops and surface mechanical properties of the copper coatings were observed

  8. Migrational polarization in high-current density molten salt electrochemical devices

    Energy Technology Data Exchange (ETDEWEB)

    Braunstein, J.; Vallet, C.E.

    1977-01-01

    Electrochemical flux equations based on the thermodynamics of irreversible processes have been derived in terms of experimental transport coefficients for binary molten salt mixtures analogous to those proposed for high temperature batteries and fuel cells. The equations and some numerical solutions indicate steady state composition gradients of significant magnitude. The effects of migrational separation must be considered along with other melt properties in the characterization of electrode behavior, melt composition, operating temperatures and differences of phase stability, wettability and other physicochemical properties at positive and negative electrodes of high current density devices with mixed electrolytes.

  9. Corrosion of steel in concrete

    International Nuclear Information System (INIS)

    Preece, C.M.

    1982-10-01

    A comparative study has been made of those properties of Massiv and Standard cements which are considered to determine their ability to protect steel reinforcement from corroding. Saturated Massiv cement has a higher evaporabel water content, but a significantly finer pore structure than has saturated Standard cement. This fine structure resulted in an electrical resistivity ten times higher and chloride diffusivity ten times lower than those of Standard cement. Electrochemical measurements have shown that the passive current density of steel in Massiv mortar is higher than that of steel in Standard mortar, but the higher current should lead to a more rapid decrease in potential to a level at which neither chloride attack of hydrogen evolution will occur. Whereas steel in Standard mortar was found to be highly susceptible to crevice corrosion, no such attack has been observed in Massiv mortar. Moreover, the initiation of chloride induced corrosion and the subsequent rates of corrosion were both lower in Massiv mortar than in Standard mortar. Thus, it may be predicted that Massiv cement would provide greater protection for steel reinforcement in underground structures exposed to chloride containing ground water than would Standard cement. (author)

  10. Corrosion Behavior of 7B04 Al-alloy in Simulated Marine Atmospheric Environment

    Directory of Open Access Journals (Sweden)

    WANG Chenguang

    2017-01-01

    Full Text Available The corrosion of aluminum alloy in marine atmospheric environment was an essential electrochemical corrosion under thin electrolyte film, which was different from the corrosion in bulk solution, the corrosion rate was related to the thickness and composition of thin electrolyte film. The relationship among film thickness, relative humidity and salt deposit on aluminum alloy surface was established and verified by experiment. The electrochemical properties of 7B04 Al-alloy under thin electrolyte film with different thickness and different NaCl concentration were studied. The results indicate that the free-corrosion potential of 7B04 Al-alloy under thin electrolyte film is easier to reach steady state than that in bulk solution, both free-corrosion potential and corrosion rate are higher under thin electrolyte film. With the decrease of film thickness, the cathodic polarization current density of 7B04 Al-alloy increases, and the anode reaction is suppressed. With the increase of NaCl concentration in thin electrolyte film, the free-corrosion potential of 7B04 Al-alloy decreases, and the corrosion rate increases, but the polarization of the anode and cathode have little effect on the change of NaCl concentration. The free-corrosion potential of 7B04 Al-alloy is no longer changed when the mass fraction of NaCl reaches 5%.

  11. Electrodynamic wear of rails in high current density rail gun discharges

    International Nuclear Information System (INIS)

    Edwards, W.T.; Caldwell, S.G.

    1984-01-01

    Significant advances in high current, high speed power sources, has in recent years allowed rail guns to produce very high velocity (> 10 km/sec) macroscopic particles (> 1/10 grams). A continuing problem is the structural integrity of the components under these loadings and in particular, the rail wear due to the high current density plasma contacts. In this investigation a small bore rail gun (6x5 mm) was used with a 10.6 kjoule capacitor energy source to examine the modes of rail damage. The rails were constructed of 110 copper base material. These rails were used in an uncoated condition and also with plasma sprayed coatings of W and W/WC. The resulting surface wear was characterized by standard metallurgical techniques and analyzed for the various coatings

  12. Critical current density of MgB2 thin films and the effect of interface pinning

    International Nuclear Information System (INIS)

    Choi, Eun-Mi; Gupta, S K; Sen, Shashwati; Lee, Hyun-Sook; Kim, Hyun-Jung; Lee, Sung-Ik

    2004-01-01

    Preferentially oriented MgB 2 thin films with c-axis normal to the surface have been prepared and characterized for microstructure and transport properties. The magnetic field dependence of superconducting critical current density J c has been determined from the magnetization hysteresis (M-H) loops at various temperatures using the Bean's critical state model. High J c of these films show their potential for applications. We have also measured the angular dependences of J c . The angular dependence is seen to be in agreement with the anisotropic Ginzburg-Landau model except that at angles close to the ab plane, increased pinning due to film-substrate interaction is observed. The angular range where interface pinning is effective has been determined by measurement of asymmetry in dissipation on reversal of current for fields applied at angles close to the ab plane

  13. Electrical design of a high current density air-core reversed-field pinch ''ZTP''

    International Nuclear Information System (INIS)

    Reass, W.A.; Cribble, R.F.; Melton, J.G.

    1983-01-01

    This paper describes the electrical design of a small, high current density (10 MA/m 2 ) toroidal reversed-field Z-Pinch (RFP) presently being constructed at Los Alamos. Special purpose magnetic field programs were used to calculate self and mutual inductances for the poloidal field windings. The network analysis program MINI-SCEPTRE was then used to predict plasma current, including the interaction between toroidal and poloidal field circuits, as described by the Bessel function model for RFP's. Using these programs, coil geometry was obtained for minimal field errors and the pulse power systems were optimized to minimize equilibrium control power. Results of computer modeling and implementation of the electrical circuits are presented

  14. Density-matrix renormalization-group study of current and activity fluctuations near nonequilibrium phase transitions.

    Science.gov (United States)

    Gorissen, Mieke; Hooyberghs, Jef; Vanderzande, Carlo

    2009-02-01

    Cumulants of a fluctuating current can be obtained from a free-energy-like generating function, which for Markov processes equals the largest eigenvalue of a generalized generator. We determine this eigenvalue with the density-matrix renormalization group for stochastic systems. We calculate the variance of the current in the different phases, and at the phase transitions, of the totally asymmetric exclusion process. Our results can be described in the terms of a scaling ansatz that involves the dynamical exponent z . We also calculate the generating function of the dynamical activity (total number of configuration changes) near the absorbing-state transition of the contact process. Its scaling properties can be expressed in terms of known critical exponents.

  15. Multiphase modeling of channelized pyroclastic density currents and the effect of confinement on mobility and entrainment

    Science.gov (United States)

    Kubo, A. I.; Dufek, J.

    2017-12-01

    Around explosive volcanic centers such as Mount Saint Helens, pyroclastic density currents (PDCs) pose a great risk to life and property. Understanding of the mobility and dynamics of PDCs and other gravity currents is vital to mitigating hazards of future eruptions. Evidence from pyroclastic deposits at Mount Saint Helens and one-dimensional modeling suggest that channelization of flows effectively increases run out distances. Dense flows are thought to scour and erode the bed leading to confinement for subsequent flows and could result in significant changes to predicted runout distance and mobility. Here, we present the results of three-dimensional multiphase models comparing confined and unconfined flows using simplified geometries. We focus on bed stress conditions as a proxy for conditions that could influence subsequent erosion and self-channelization. We also explore the controls on gas entrainment in all scenarios to determine how confinement impacts the particle concentration gradient, granular interactions, and mobility.

  16. Thermally oxidized titania nanotubes enhance the corrosion resistance of Ti6Al4V.

    Science.gov (United States)

    Grotberg, John; Hamlekhan, Azhang; Butt, Arman; Patel, Sweetu; Royhman, Dmitry; Shokuhfar, Tolou; Sukotjo, Cortino; Takoudis, Christos; Mathew, Mathew T

    2016-02-01

    The negative impact of in vivo corrosion of metallic biomedical implants remains a complex problem in the medical field. We aimed to determine the effects of electrochemical anodization (60V, 2h) and thermal oxidation (600°C) on the corrosive behavior of Ti-6Al-4V, with serum proteins, at physiological temperature. Anodization produced a mixture of anatase and amorphous TiO2 nanopores and nanotubes, while the annealing process yielded an anatase/rutile mixture of TiO2 nanopores and nanotubes. The surface area was analyzed by the Brunauer-Emmett-Teller method and was estimated to be 3 orders of magnitude higher than that of polished control samples. Corrosion resistance was evaluated on the parameters of open circuit potential, corrosion potential, corrosion current density, passivation current density, polarization resistance and equivalent circuit modeling. Samples both anodized and thermally oxidized exhibited shifts of open circuit potential and corrosion potential in the noble direction, indicating a more stable nanoporous/nanotube layer, as well as lower corrosion current densities and passivation current densities than the smooth control. They also showed increased polarization resistance and diffusion limited charge transfer within the bulk oxide layer. The treatment groups studied can be ordered from greatest corrosion resistance to least as Anodized+Thermally Oxidized > Anodized > Smooth > Thermally Oxidized for the conditions investigated. This study concludes that anodized surface has a potential to prevent long term implant failure due to corrosion in a complex in-vivo environment. Copyright © 2015 Elsevier B.V. All rights reserved.

  17. Growth and characterization of high current density, high-speed InAs/AlSb resonant tunneling diodes

    Science.gov (United States)

    Soderstrom, J. R.; Brown, E. R.; Parker, C. D.; Mahoney, L. J.; Yao, J. Y.

    1991-01-01

    InAs/AlSb double-barrier resonant tunneling diodes with peak current densities up to 370,000 A/sq cm and high peak-to-valley current ratios of 3.2 at room temperature have been fabricated. The peak current density is well-explained by a stationary-state transport model with the two-band envelope function approximation. The valley current density predicted by this model is less than the experimental value by a factor that is typical of the discrepancy found in other double-barrier structures. It is concluded that threading dislocations are largely inactive in the resonant tunneling process.

  18. Frequency spectra from current vs. magnetic flux density measurements for mobile phones and other electrical appliances.

    Science.gov (United States)

    Straume, Aksel; Johnsson, Anders; Oftedal, Gunnhild; Wilén, Jonna

    2007-10-01

    The frequency spectra of electromagnetic fields have to be determined to evaluate human exposure in accordance to ICNIRP guidelines. In the literature, comparisons with magnetic field guidelines have been performed by using the frequency distribution of the current drawn from the battery. In the present study we compared the frequency spectrum in the range 217 Hz to 2.4 kHz of the magnetic flux density measured near the surface of a mobile phone with the frequency spectrum of the supply current. By using the multiple frequency rule, recommended in the ICNIRP guidelines, we estimated the magnetic field exposure in the two cases. Similar measurements and estimations were done for an electric drill, a hair dryer, and a fluorescent desk lamp. All the devices have a basic frequency of 50 Hz, and the frequency spectra were evaluated up to 550 Hz. We also mapped the magnetic field in 3D around three mobile phones. The frequency distributions obtained from the two measurement methods are not equal. The frequency content of the current leads to an overestimation of the magnetic field exposure by a factor up to 2.2 for the mobile phone. For the drill, the hair dryer, and the fluorescent lamp, the supply current signal underestimated the exposure by a factor up to 2.3. In conclusion, an accurate exposure evaluation requires the magnetic flux density spectrum of the device to be measured directly. There was no indication that the devices studied would exceed the reference levels at the working distances normally used.

  19. Current Density Distribution Mapping in PEM Fuel Cells as An Instrument for Operational Measurements

    Directory of Open Access Journals (Sweden)

    Martin Geske

    2010-04-01

    Full Text Available A newly developed measurement system for current density distribution mapping has enabled a new approach for operational measurements in proton exchange membrane fuel cells (PEMFC. Taking into account previously constructed measurement systems, a method based on a multi layer printed circuit board was chosen for the development of the new system. This type of system consists of a sensor, a special electronic device and the control and visualization PC. For the acquisition of the current density distribution values, a sensor device was designed and installed within a multilayer printed circuit board with integrated shunt resistors. Varying shunt values can be taken into consideration with a newly developed and evaluated calibration method. The sensor device was integrated in a PEM fuel cell stack to prove the functionality of the whole measurement system. A software application was implemented to visualize and save the measurement values. Its functionality was verified by operational measurements within a PEMFC system. Measurement accuracy and possible negative reactions of the sensor device during PEMFC operation are discussed in detail in this paper. The developed system enables operational measurements for different operating phases of PEM fuel cells. Additionally, this can be seen as a basis for new opportunities of optimization for fuel cell design and operation modes.

  20. High wall-plug efficiency blue III-nitride LEDs designed for low current density operation.

    Science.gov (United States)

    Kuritzky, Leah Y; Espenlaub, Andrew C; Yonkee, Benjamin P; Pynn, Christopher D; DenBaars, Steven P; Nakamura, Shuji; Weisbuch, Claude; Speck, James S

    2017-11-27

    Commercial LEDs for solid-state lighting are often designed for operation at current densities in the droop regime (~35 A/cm 2 ) to minimize costly chip area; however, many benefits can be realized by operating at low current density (J ≈1 - 5 A/cm 2 ). Along with mitigation of droop losses and reduction of the operating voltage, low J operation of LEDs opens the design space for high light extraction efficiency (LEE). This work presents detailed ray tracing simulations of an LED design for low J operation with LEE ≈94%. The design is realized experimentally resulting in a peak wall-plug efficiency of 78.1% occurring at 3.45 A/cm 2 and producing an output power of 7.2 mW for a 0.1 mm 2 emitting area. At this operation point, the photon voltage V p =hνq exceeds the forward voltage (V), corresponding to a Vp/V = 103%.

  1. Inverse current source density method in two dimensions: inferring neural activation from multielectrode recordings.

    Science.gov (United States)

    Łęski, Szymon; Pettersen, Klas H; Tunstall, Beth; Einevoll, Gaute T; Gigg, John; Wójcik, Daniel K

    2011-12-01

    The recent development of large multielectrode recording arrays has made it affordable for an increasing number of laboratories to record from multiple brain regions simultaneously. The development of analytical tools for array data, however, lags behind these technological advances in hardware. In this paper, we present a method based on forward modeling for estimating current source density from electrophysiological signals recorded on a two-dimensional grid using multi-electrode rectangular arrays. This new method, which we call two-dimensional inverse Current Source Density (iCSD 2D), is based upon and extends our previous one- and three-dimensional techniques. We test several variants of our method, both on surrogate data generated from a collection of Gaussian sources, and on model data from a population of layer 5 neocortical pyramidal neurons. We also apply the method to experimental data from the rat subiculum. The main advantages of the proposed method are the explicit specification of its assumptions, the possibility to include system-specific information as it becomes available, the ability to estimate CSD at the grid boundaries, and lower reconstruction errors when compared to the traditional approach. These features make iCSD 2D a substantial improvement over the approaches used so far and a powerful new tool for the analysis of multielectrode array data. We also provide a free GUI-based MATLAB toolbox to analyze and visualize our test data as well as user datasets.

  2. Current Controlled Magnetization Switching in Cylindrical Nanowires for High-Density 3D Memory Applications

    KAUST Repository

    Mohammed, Hanan

    2018-04-18

    A next-generation memory device utilizing a three-dimensional nanowire system requires the reliable control of domain wall motion. In this letter, domain walls are studied in cylindrical nanowires consisting of alternating segments of cobalt and nickel. The material interfaces acting as domain wall pinning sites, are utilized in combination with current pulses, to control the position of the domain wall, which is monitored using magnetoresistance measurements. Magnetic force microscopy results further confirm the occurrence of current assisted domain wall depinning. Data bits are therefore shifted along the nanowire by sequentially pinning and depinning a domain wall between successive interfaces, a requirement necessary for race-track type memory devices. We demonstrate that the direction, amplitude and duration of the applied current pulses determine the propagation of the domain wall across pinning sites. These results demonstrate a multi-bit cylindrical nanowire device, utilizing current assisted data manipulation. The prospect of sequential pinning and depinning in these nanowires allows the bit density to increase by several Tbs, depending on the number of segments within these nanowires.

  3. Plasma electrolytic oxidation treatment mode influence on corrosion properties of coatings obtained on Zr-1Nb alloy in silicate-phosphate electrolyte

    Science.gov (United States)

    Farrakhov, R. G.; Mukaeva, V. R.; Fatkullin, A. R.; Gorbatkov, M. V.; Tarasov, P. V.; Lazarev, D. M.; Babu, N. Ramesh; Parfenov, E. V.

    2018-01-01

    This research is aimed at improvement of corrosion properties for Zr-1Nb alloy via plasma electrolytic oxidation (PEO). The coatings obtained in DC, pulsed unipolar and pulsed bipolar modes were assessed using SEM, XRD, PDP and EIS techniques. It was shown that pulsed unipolar mode provides the PEO coatings having promising combination of the coating thickness, surface roughness, porosity, corrosion potential and current density, and charge transfer resistance, all contributing to corrosion protection of the zirconium alloy for advanced fuel cladding applications.

  4. Study on Corrosion of Macroporous Silicon in Sodium Hydroxide Solution by Electrochemical Methods and Scanning Electron Microscopy

    Directory of Open Access Journals (Sweden)

    Chuan Lai

    2015-01-01

    Full Text Available The fabricated macroporous silicon with a porosity of 26.33% corrosion in NaOH solution was systemically investigated by open circuit potential measurements, linear polarization measurements, potentiodynamic polarization measurements, and scanning electron microscopy, respectively. Results show that the potential open circuit and linear polarization resistance decreases with the NaOH concentration increasing. The corrosion potential shifts significantly to more negative potentials and corrosion current density increases with NaOH concentration increasing. Adding ethanol to 1.0 M NaOH can lead to the linear polarization resistance decrease, corrosion potentials shift in the positive direction, and corrosion current density increase. In addition, the scanning electron microscopy images demonstrate that the macroporous silicon samples are seriously damaged by 1.0 M NaOH and 1.0 M NaOH/EtOH (30%.

  5. Corrosion of alloys of the niobium--titanium--aluminium system

    International Nuclear Information System (INIS)

    Andreeva, V.V.; Alekseeva, E.L.; Dontsov, S.N.; Moiseeva, I.S.

    The mechanical properties and corrosion resistance of niobium--titanium--aluminum alloys in 20 percent HCl and 40--75 percent H 2 SO 4 at 40 and 100 0 C are considered. Current density vs potential and corrosion rate vs potential potentiostatic curves plotted in 75 percent H 2 SO 4 at 140 0 C for the alloys with different titanium contents at a constant content of aluminum and also for alloys with a constant titanium content at different contents of aluminum are given. It was shown that the corrosion resistance of the alloys in 75 percent H 2 SO 4 at 140 0 C is an exponential function of the atomic content of the alloying components (Ti, Al) in them; aluminum vitiates the corrosion resistance very strongly

  6. Modeling space-charge-limited currents in organic semiconductors: Extracting trap density and mobility

    KAUST Repository

    Dacuña, Javier

    2011-11-28

    We have developed and have applied a mobility edge model that takes drift and diffusion currents to characterize the space-charge-limited current in organic semiconductors into account. The numerical solution of the drift-diffusion equation allows the utilization of asymmetric contacts to describe the built-in potential within the device. The model has been applied to extract information of the distribution of traps from experimental current-voltage measurements of a rubrene single crystal from Krellner showing excellent agreement across several orders of magnitude in the current. Although the two contacts are made of the same metal, an energy offset of 580 meV between them, ascribed to differences in the deposition techniques (lamination vs evaporation) was essential to correctly interpret the shape of the current-voltage characteristics at low voltage. A band mobility of 0.13cm 2V-1s-1 for holes is estimated, which is consistent with transport along the long axis of the orthorhombic unit cell. The total density of traps deeper than 0.1 eV was 2.2×1016cm -3. The sensitivity analysis and error estimation in the obtained parameters show that it is not possible to accurately resolve the shape of the trap distribution for energies deeper than 0.3 eV or shallower than 0.1 eV above the valence-band edge. The total number of traps deeper than 0.3 eV, however, can be estimated. Contact asymmetry and the diffusion component of the current play an important role in the description of the device at low bias and are required to obtain reliable information about the distribution of deep traps. © 2011 American Physical Society.

  7. Aircraft Corrosion

    Science.gov (United States)

    1981-08-01

    transport anciens dont il a fallu remplacer les panneaux extrados en raison de is corrosion profonde des lisses. Ce type d’avion a etc mis en service h partir...as six years) where lavatories are placed above the lower section of the aft pressure dome bulkhead (fig.8)., corrosion Is found in the bulkhead web ...due to leakage of toilet fluids. One of the most severe corrosion ever found In this area was with the corrosion completely penetrated through the web

  8. Effects of volcano profile on dilute pyroclastic density currents: Numerical simulations

    Science.gov (United States)

    Doronzo, D. M.; Valentine, G. A.; Dellino, P.; de Tullio, M. D.

    2012-04-01

    Explosive activity and lava dome collapse at stratovolcanoes can lead to pyroclastic density currents (PDCs; mixtures of volcanic gas, air, and volcanic particles) that produce complex deposits and pose a hazard to surrounding populations. Two-dimensional numerical simulations of dilute PDCs (characterized by a turbulent suspended load and deposition through a bed load) are carried out with the Euler-Lagrange approach of multiphase physics. The fluid phase is modeled as a dusty gas (1.88 kg/m3 dense), and the solid phase is modeled as discrete particles (1 mm, 5 mm, and 10 mm; 1500 kg/m3 dense and irregularly-shaped), which are two-way coupled to the gas, i.e. they affect the fluid turbulence. The initial PDC, which enters a volcano domain 5 km long and 1.9 km high, has the following characteristics: thickness of 200 m, velocity of 20 m/s, temperature of 573 K, turbulence of 5 %, and sediment concentration of 3 % by volume. The actual physics of flow boundary zone is simulated at the PDC base, by monitoring the sediment flux toward the substrate, which acts through the flow boundary zone, and the grain-size distribution. Also, the PDC velocity and dynamic pressure are calculated. The simulations show that PDC transport, deposition, and hazard potential are sensitive to the shape of the volcano slope (profile) down which they flow. In particular, three generic volcano profiles, straight, concave-upward, and convex-upward are focused on. Dilute PDCs that flow down a constant slope gradually decelerate over the simulated run-out distance (5 km in the horizontal direction) due to a combination of sedimentation, which reduces the density of the PDC, and mixing with the atmosphere. However, dilute PDCs down a concave-upward slope accelerate high on the volcano flanks and have less sedimentation until they begin to decelerate over the shallow lower slopes. A convex-upward slope causes dilute PDCs to lose relatively more of their pyroclast load on the upper slopes of a

  9. Modelling of the reactive sputtering process with non-uniform discharge current density and different temperature conditions

    Science.gov (United States)

    Vašina, P; Hytková, T; Eliáš, M

    2009-05-01

    The majority of current models of the reactive magnetron sputtering assume a uniform shape of the discharge current density and the same temperature near the target and the substrate. However, in the real experimental set-up, the presence of the magnetic field causes high density plasma to form in front of the cathode in the shape of a toroid. Consequently, the discharge current density is laterally non-uniform. In addition to this, the heating of the background gas by sputtered particles, which is usually referred to as the gas rarefaction, plays an important role. This paper presents an extended model of the reactive magnetron sputtering that assumes the non-uniform discharge current density and which accommodates the gas rarefaction effect. It is devoted mainly to the study of the behaviour of the reactive sputtering rather that to the prediction of the coating properties. Outputs of this model are compared with those that assume uniform discharge current density and uniform temperature profile in the deposition chamber. Particular attention is paid to the modelling of the radial variation of the target composition near transitions from the metallic to the compound mode and vice versa. A study of the target utilization in the metallic and compound mode is performed for two different discharge current density profiles corresponding to typical two pole and multipole magnetics available on the market now. Different shapes of the discharge current density were tested. Finally, hysteresis curves are plotted for various temperature conditions in the reactor.

  10. Corrosion and tribocorrosion of hafnium in simulated body fluids.

    Science.gov (United States)

    Rituerto Sin, J; Neville, A; Emami, N

    2014-08-01

    Hafnium is a passive metal with good biocompatibility and osteogenesis, however, little is known about its resistance to wear and corrosion in biological environments. The corrosion and tribocorrosion behavior of hafnium and commercially pure (CP) titanium in simulated body fluids were investigated using electrochemical techniques. Cyclic polarization scans and open circuit potential measurements were performed in 0.9% NaCl solution and 25% bovine calf serum solution to assess the effect of organic species on the corrosion behavior of the metal. A pin-on-plate configuration tribometer and a three electrode electrochemical cell were integrated to investigate the tribocorrosion performance of the studied materials. The results showed that hafnium has good corrosion resistance. The corrosion density currents measured in its passive state were lower than those measured in the case of CP titanium; however, it showed a higher tendency to suffer from localized corrosion, which was more acute when imperfections were present on the surface. The electrochemical breakdown of the oxide layer was retarded in the presence of proteins. Tribocorrosion tests showed that hafnium has the ability to quickly repassivate after the oxide layer was damaged; however, it showed higher volumetric loss than CP titanium in equivalent wear-corrosion conditions. © 2013 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 102B: 1157-1164, 2014. © 2013 Wiley Periodicals, Inc.

  11. Research of the Ion Current Density Influence on the Glass-Ceramics Surface Defects Forming under Ion-Beam Processing

    Directory of Open Access Journals (Sweden)

    V. G. Pozdnyakov

    2015-01-01

    Full Text Available Development of modern optics is primarily determined by manufacturing accuracy of the working surfaces of optical parts. Therefore, at the last stage of manufacturing optical parts the ion-beam treatment is applied. This method uses spraying the high-energy ions of heavy gases on the surface of a solid body. After an intense ion treatment there are microscopic defects, resembling chips, on the surface of polycrystalline glass. The aim of this work is to study distribution of the surface density of defects by sizes, depending on the density of ion current.Accelerator with an anode layer and a focused ion beam was used as an ion source. The accelerator worked on argon and created ion beam with Gaussian distribution of current density along the radius. The excess positive charge of the ion beam was compensated owing to ionization of residual gas. To eliminate the influence of slow ions with peripheral regions of the ion beam, the etching was performed through a circular aperture with a diameter of 40 mm.Surface treatment of the sample was carried out at the discharge voltage of 3800 V and current of 50 mA for 30 min. The maximum ion current density on the sample surface was 20.2 A/m2 and a power density was of 5.4·104 W/m2 .Distribution of defects by size was measured in three areas of the treated surface corresponding to different densities of ion current, namely: 20.2 A/m2 , 11.3A/m2 , and 3.4 A/m2 . Their number per area unit defines a density of defects.The results show that with increasing ion current density the density of defects on the surface of polycrystalline glass decreases. Thus a view of distribution function of defect density according to size is changed: density of small defects is reduced, and density of large ones increases. Also with increasing ion current density is observed an increase in the size of defects: a 6 times increase of the average size of defects results in 1.6 times increasing ion current density.These data will

  12. Galvanokinetic polarization method applied to the pitting corrosion study of stainless steels

    International Nuclear Information System (INIS)

    Le Xuan, Q.; Vu Quang, K.

    1992-01-01

    Galvanokinetic (GK) polarisation method was used to study the pitting corrosion of 316L stainless steel in chloride solution. Current scan rate effect on the pitting characteristic parameters was pointed out. Specific relations between current scan rate and some pitting characteristic parameters, such as critical current density I c , stable current density I s , critical time t c , stable time t s , were established. Some advantages of the GK polarisation method were discussed

  13. Flux pinning and Critical current density in La2-xSrxCuO4+d

    Science.gov (United States)

    Mohottala, Hashini; Wells, B. O.; Budnick, J. I.; Hines, W. A.; Moodenbaugh, A. R.; Chou, F. C.

    2006-03-01

    We have studied the magnetic characteristics of the critical states in a series of samples of the type La2-xSrxCuO4+d that is doped with both Sr and excess O incorporated using electrochemistry. These samples spontaneously phase separate and show both a superconducting phase with TC near 40 K and a magnetic phase with TM near 40 K. Our previous studies established that the superconducting phase is similar to an optimally doped sample while the magnetic phase is consistent with the static spin density wave reported for x=1/8 Sr or Ba doped samples. Magnetization data at various temperatures showed large reversibility in all the samples. The critical current densities JC(0) values were at least an order of magnitude smaller than that of the reported values for YBa2Cu3O7-d and La2-xSrxCuO4. At higher fields JC(H) was smaller indicating the existence of weak flux pinning in the system. Based on our magnetization data we conclude that the vortex lattice pinning is different from non-phase separated cuprates. This work was partially supported by the US-DOE through contract DE-FG02-00ER45801 and the Cottrell Scholar Program of the Research Corporation.

  14. Experimental study on magnetically insulated transmission line electrode surface evolution process under MA/cm current density

    International Nuclear Information System (INIS)

    Zhang, PengFei; Qiu, Aici; Hu, Yang; Yang, HaiLiang; Sun, Jiang; Wang, Liangping; Cong, Peitian

    2016-01-01

    The design of high-current density magnetically insulated transmission line (MITL) is a difficult problem of current large-scale Z-pinch device. In particular, a thorough understanding of the MITL electrode surface evolution process under high current density is lacking. On the “QiangGuang-I” accelerator, the load area possesses a low inductance short-circuit structure with a diameter of 2.85 mm at the cathode, and three reflux columns with a diameter of 3 mm and uniformly distributed circumference at the anode. The length of the high density MITL area is 20 mm. A laser interferometer is used to assess and analyze the state of the MITL cathode and anode gap, and their evolution process under high current density. Experimental results indicate that evident current loss is not observed in the current density area at pulse leading edge, and peak when the surface current density reaches MA/cm. Analysis on electrode surface working conditions indicates that when the current leading edge is at 71.5% of the peak, the total evaporation of MITL cathode structure can be realized by energy deposition caused by ohmic heating. The electrode state changes, and diffusion conditions are reflected in the laser interferometer image. The MITL cathode area mainly exists in metal vapor form. The metal vapor density in the cathode central region is higher than the upper limit of laser penetration density (∼4 × 10 21 /cm 3 ), with an expansion velocity of ∼0.96 km/s. The metal vapor density in the electrode outer area may lead to evident distortion of fringes, and its expansion velocity is faster than that in the center area (1.53 km/s).

  15. Soft x-ray camera for internal shape and current density measurements on a noncircular tokamak

    International Nuclear Information System (INIS)

    Fonck, R.J.; Jaehnig, K.P.; Powell, E.T.; Reusch, M.; Roney, P.; Simon, M.P.

    1988-05-01

    Soft x-ray measurements of the internal plasma flux surface shaped in principle allow a determination of the plasma current density distribution, and provide a necessary monitor of the degree of internal elongation of tokamak plasmas with a noncircular cross section. A two-dimensional, tangentially viewing, soft x-ray pinhole camera has been fabricated to provide internal shape measurements on the PBX-M tokamak. It consists of a scintillator at the focal plane of a foil-filtered pinhole camera, which is, in turn, fiber optically coupled to an intensified framing video camera (/DELTA/t />=/ 3 msec). Automated data acquisition is performed on a stand-alone image-processing system, and data archiving and retrieval takes place on an optical disk video recorder. The entire diagnostic is controlled via a PDP-11/73 microcomputer. The derivation of the polodial emission distribution from the measured image is done by fitting to model profiles. 10 refs., 4 figs

  16. Density dependence of 2p-2h meson-exchange currents

    Science.gov (United States)

    Amaro, J. E.; Barbaro, M. B.; Caballero, J. A.; De Pace, A.; Donnelly, T. W.; Megias, G. D.; Ruiz Simo, I.

    2017-06-01

    We analyze the density dependence of the contribution of meson-exchange currents to the lepton-nucleus inclusive cross section in the two-particle two-hole channel. The model is based on the relativistic Fermi gas, where each nucleus is characterized by its Fermi momentum kF. We find that the 2p-2h nuclear response functions at their peaks scale as A kF2 for Fermi momentum going from 200 to 300 MeV/c and momentum transfer q from 2 kF to 2 GeV /c . This behavior is different from what is found for the quasielastic response, which scales as A /kF . Additionally, the deep scaling region is also discussed and there the usual scaling behavior is found to be preferable.

  17. Study of Chromium Multilayers Properties Obtained by Pulsed Current Density: Residual Stress and Microhardness

    Directory of Open Access Journals (Sweden)

    Julieta TORRES-GONZÁLEZ

    2010-12-01

    Full Text Available Chromium multilayers deposits were obtained from three different bath solutions, they were prepared by switching current density between 10 and 70 Adm-2. Two temperatures were studied, 35°C and 55°C. At 35°C two different microstructures are alternated: columnar obtained at 10 Adm-2 and equiaxial obtained at 70 Adm-2. At 55°C only the columnar type microstructure is present, at 10 and 70 Adm-2, the only difference among the layers is a slight disorientation of grains. The properties of these chromium multilayers were characterized by scanning electron microscopy (SEM and X-ray diffraction (XRD. In general the deposits are microcracked with a high microhardness, high residual stress and a small grain size.

  18. Table 5.1. Exchange current densities and rate constants in aqueous systems

    Science.gov (United States)

    Holze, R.

    This document is part of Volume 9 `Electrochemistry', Subvolume A, of Landolt-Börnstein - Group IV `Physical Chemistry'. This document lists the exchange current densities and the electrode reaction rate constants of the following metallic electrodes in aqueous systems for various electrolyte reactions: silver (Ag), aluminium (Al), gold (Au), bismuth (Bi), carbon (C), cadmium (Cd), cobalt (Co), chromium (Cr), cesium (Cs), copper (Cu), iron (Fe), gallium (Ga), mercury (Hg), indium (In), iridium (Ir), potassium (K), lithium (Li), molybdenum (Mo), natrium (Na), niobium (Nb), nickel (Ni), lead (Pb), palladium (Pd), platinum (Pt), rubidium (Rb), rhodium (Rh), ruthenium (Ru), antimony (Sb), tin (Sn), tantalum (Ta), titanium (Ti), thallium (Tl), vanadium (V), tungsten (W), zinc (Zn). For each electrolyte reaction the electrolyte solution, the educt, product and concentration are specified along with the temperature of determination of the given values.

  19. Higher critical current density achieved in Bi-2223 High-Tc superconductors

    Directory of Open Access Journals (Sweden)

    M.S. Shalaby

    2016-07-01

    Full Text Available Bi2Sr2Ca2Cu3Ox (Bi-2223 were prepared using a solid state reaction method at different sintering times and temperatures. Structural phase identifications have been done using X-Ray analysis and refinement by Reitveld method which proves the coexistence of Bi-2223 and Bi-2212 phases. The critical transition temperature Tc and critical current density Jc values were measured using superconducting quantum interference device magnetometer (SQUID and by the magneto-optics technique. A remarkable rapid decrease to the diamagnetic signal in the magnetization versus temperature M(T at 110 K and Jc around 1.2 × 107 A/m2 at 5 K are confirmed for the Bi-2223 compound.

  20. Large high current density superconducting solenoids for use in high energy physics experiments

    International Nuclear Information System (INIS)

    Green, M.A.; Eberhard, P.H.; Taylor, J.D.

    1976-05-01

    Very often the study of high energy physics in colliding beam storage-rings requires a large magnetic field volume in order to detect and analyze charged particles which are created from the collision of two particle beams. Large superconducting solenoids which are greater than 1 meter in diameter are required for this kind of physics. In many cases, interesting physics can be done outside the magnet coil, and this often requires that the amount of material in the magnet coil be minimized. As a result, these solenoids should have high current density (up to 10 9 A m -2 ) superconducting windings. The methods commonly used to stabilize large superconducting magnets cannot be employed because of this need to minimize the amount of material in the coils. A description is given of the Lawrence Berkeley Laboratory program for building and testing prototype solenoid magnets which are designed to operate at coil current densities in excess of 10 9 A m -2 with magnetic stored energies which are as high as 1.5 Megajoules per meter of solenoid length. The coils use intrinsically stable multifilament Nb--Ti superconductors. Control of the magnetic field quench is achieved by using a low resistance aluminum bore tube which is inductively coupled to the coil. The inner cryostat is replaced by a tubular cooling system which carries two phase liquid helium. The magnet coil, the cooling tubes, and aluminum bore tube are cast in epoxy to form a single unified magnet and cryogenic system which is about 2 centimeters thick. The results of the magnet coil tests are discussed

  1. Modeling the short-circuit current density of polymer solar cells based on P3HT:PCBM blend

    Energy Technology Data Exchange (ETDEWEB)

    Monestier, Florent; Simon, Jean-Jacques; Torchio, Philippe; Escoubas, Ludovic; Flory, Francois [Institut FRESNEL, UMR-CNRS 6133, Domaine Universitaire de St-Jerome, 13397 Marseille Cedex 20 (France); Bailly, Sandrine; de Bettignies, Remi; Guillerez, Stephane [INES CEA/DRT/LITEN/DTS/LCS, BP 332 50, av. du lac Leman 73370, Le Bourget du lac (France); Defranoux, Christophe [SOPRA-SA, Bois Colombes (France)

    2007-03-06

    We have investigated the short-circuit current density of organic solar cells based on poly (3-hexylthiophene)(P3HT)/6,6-phenyl C61-butyric acid methyl ester (PCBM) blend. In order to model charge collection efficiencies with respect to short circuit density in such blends, a full optical modeling of the cell is performed. From the distribution of the electromagnetic field, we compute the rate of exciton generation. This exciton generation rate is used as input in the transport equations of holes and electrons. Charge densities at steady state are obtained as solutions are used for computing short-circuit current densities generated in the cell. The dependence of short-circuit current densities versus the thickness of the blend is analyzed and compared with our experimental data and with data extracted from the literature. (author)

  2. Pitting corrosion

    International Nuclear Information System (INIS)

    Allgaier, W.

    1985-01-01

    Pitting corrosion is a kind of electrolytic corrosion by which the surface of a material is locally affected owing to inhomogeneities on the part of the material or medium. The paper deals briefly with questions relating to the importance, to parameters medium or materialwise, influence on production and construction, as well as the general conditions for pitting corrosion. In particular oxygen corrosion in unalloyed and low-alloy steel, and pitting corrosion in ferritic chromium-steel and austenitic chromium-nickel (molybdenum) steel is described. (DG) [de

  3. The study of Zn–Co alloy coatings electrochemically deposited by pulse current

    Directory of Open Access Journals (Sweden)

    Tomić Milorad V.

    2012-01-01

    Full Text Available The electrochemical deposition by pulse current of Zn-Co alloy coatings on steel was examined, with the aim to find out whether pulse plating could produce alloys that could offer a better corrosion protection. The influence of on-time and the average current density on the cathodic current efficiency, coating morphology, surface roughness and corrosion stability in 3% NaCl was examined. At the same Ton/Toff ratio the current efficiency was insignificantly smaller for deposition at higher average current density. It was shown that, depending on the on-time, pulse plating could produce more homogenous alloy coatings with finer morphology, as compared to deposits obtained by direct current. The surface roughness was the greatest for Zn-Co alloy coatings deposited with direct current, as compared with alloy coatings deposited with pulse current, for both examined average current densities. It was also shown that Zn-Co alloy coatings deposited by pulse current could increase the corrosion stability of Zn-Co alloy coatings on steel. Namely, alloy coatings deposited with pulse current showed higher corrosion stability, as compared with alloy coatings deposited with direct current, for almost all examined cathodic times, Ton. Alloy coatings deposited at higher average current density showed greater corrosion stability as compared with coatings deposited by pulse current at smaller average current density. It was shown that deposits obtained with pulse current and cathodic time of 10 ms had the poorest corrosion stability, for both investigated average deposition current density. Among all investigated alloy coatings the highest corrosion stability was obtained for Zn-Co alloy coatings deposited with pulsed current at higher average current density (jav = 4 A dm-2.

  4. Magmas in motion: Degassing in volcanic conduits and fabrics of pyroclastic density current

    Science.gov (United States)

    Burgisser, Alain

    Volcanoes are caused by the transport of magma batches from the Earth's crust to the surface. These magmas in motion undergo drastic changes of rheologic properties during their journey to the surface and this work explores how these changes affect volcanic eruptions. The first part of this study is devoted to the dynamic aspects of degassing and permeability in magmas with high pressure, high temperature experiments on natural volcanic rocks. Degassing is measured by the influence of decompression rate on the growth of the bubbles present in the magma while permeability is deduced from the temporal evolution of these bubbles. The parameterization of our results in a numerical model of volcanic conduit flow show that previous models based on equilibrium degassing overestimate the acceleration and the decompression rate of the magma. Assessing permeability effects derived form our results show that the transition between explosive and effusive eruptions is a strong function of the magma initial ascent rate. The second part of this work is a unification of two end-members of pyroclastic currents (highly concentrated pyroclastic flows and dilute, turbulent pyroclastic surges) using theoretical scaling arguments based on multiphase physics. Starting from the dynamics of the particle interactions with a fundamental eddy, we consider the full spectrum of eddies generated within a turbulent current. We demonstrate that the presence of particles with various sizes induces a density stratification of the current, leading to its segregation into a basal concentrated part overlain by a dilute cloud. To verify our predictions on the interactions of such a segregated pyroclastic current with its surroundings (hills and sea), we studied the products of the 2050 BP caldera-forming eruption of Okmok Volcano (Alaska). This field study allowed us to reconstruct the eruptive sequence and to validate the main aspects of our theoretical model, such as the superposition of a dense and

  5. Status Epilepticus Induced Spontaneous Dentate Gyrus Spikes: In Vivo Current Source Density Analysis.

    Directory of Open Access Journals (Sweden)

    Sean P Flynn

    Full Text Available The dentate gyrus is considered to function as an inhibitory gate limiting excitatory input to the hippocampus. Following status epilepticus (SE, this gating function is reduced and granule cells become hyper-excitable. Dentate spikes (DS are large amplitude potentials observed in the dentate gyrus (DG of normal animals. DS are associated with membrane depolarization of granule cells, increased activity of hilar interneurons and suppression of CA3 and CA1 pyramidal cell firing. Therefore, DS could act as an anti-excitatory mechanism. Because of the altered gating function of the dentate gyrus following SE, we sought to investigate how DS are affected following pilocarpine-induced SE. Two weeks following lithium-pilocarpine SE induction, hippocampal EEG was recorded in male Sprague-Dawley rats with 16-channel silicon probes under urethane anesthesia. Probes were placed dorso-ventrally to encompass either CA1-CA3 or CA1-DG layers. Large amplitude spikes were detected from EEG recordings and subject to current source density analysis. Probe placement was verified histologically to evaluate the anatomical localization of current sinks and the origin of DS. In 9 of 11 pilocarpine-treated animals and two controls, DS were confirmed with large current sinks in the molecular layer of the dentate gyrus. DS frequency was significantly increased in pilocarpine-treated animals compared to controls. Additionally, in pilocarpine-treated animals, DS displayed current sinks in the outer, middle and/or inner molecular layers. However, there was no difference in the frequency of events when comparing between layers. This suggests that following SE, DS can be generated by input from medial and lateral entorhinal cortex, or within the dentate gyrus. DS were associated with an increase in multiunit activity in the granule cell layer, but no change in CA1. These results suggest that following SE there is an increase in DS activity, potentially arising from

  6. Direct numerical simulations of particle-laden density currents with adaptive, discontinuous finite elements

    Directory of Open Access Journals (Sweden)

    S. D. Parkinson

    2014-09-01

    Full Text Available High-resolution direct numerical simulations (DNSs are an important tool for the detailed analysis of turbidity current dynamics. Models that resolve the vertical structure and turbulence of the flow are typically based upon the Navier–Stokes equations. Two-dimensional simulations are known to produce unrealistic cohesive vortices that are not representative of the real three-dimensional physics. The effect of this phenomena is particularly apparent in the later stages of flow propagation. The ideal solution to this problem is to run the simulation in three dimensions but this is computationally expensive. This paper presents a novel finite-element (FE DNS turbidity current model that has been built within Fluidity, an open source, general purpose, computational fluid dynamics code. The model is validated through re-creation of a lock release density current at a Grashof number of 5 × 106 in two and three dimensions. Validation of the model considers the flow energy budget, sedimentation rate, head speed, wall normal velocity profiles and the final deposit. Conservation of energy in particular is found to be a good metric for measuring model performance in capturing the range of dynamics on a range of meshes. FE models scale well over many thousands of processors and do not impose restrictions on domain shape, but they are computationally expensive. The use of adaptive mesh optimisation is shown to reduce the required element count by approximately two orders of magnitude in comparison with fixed, uniform mesh simulations. This leads to a substantial reduction in computational cost. The computational savings and flexibility afforded by adaptivity along with the flexibility of FE methods make this model well suited to simulating turbidity currents in complex domains.

  7. Hot Corrosion Behavior of Ti-48Al and Ti-48Al-2Cr Intermetallic Alloys Produced by Electric Current Activated Sintering

    Science.gov (United States)

    Garip, Y.; Ozdemir, O.

    2018-03-01

    In this study, Ti-48Al and Ti-48Al-2Cr (at. pct) intermetallic alloys were produced by electric current activated sintering (ECAS). In order to characterize the phase formation and microstructures of these alloys, scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), and X-ray diffraction (XRD) analysis were used. The XRD result shows that the intermetallic alloys are composed of γ-TiAl and α 2-Ti3Al phases. The microstructure is dense with a low amount of porosity. The hot corrosion behavior of intermetallic alloys was carried out in a salt mixture of 25 wt pct K2SO4 and 75 wt pct Na2SO4 at 700 °C for 180 hours. The morphology of corroded surfaces was observed by SEM-EDS and XRD. Corrosion phases were identified as TiO2 and Al2O3. Well-adhering oxide scale was detected on the corroded sample surface at the end of 180 hours, and no spallation was observed. In addition, a parabolic curve was obtained at the weight change rate vs time.

  8. Characterization of the Nova Scotia Coastally-Trapped Current and Monitoring of the Associated Density Front Using Underwater Gliders

    Science.gov (United States)

    Dever, M.; Hebert, D.; Greenan, B. J. W.; Sheng, J.

    2016-02-01

    Repeated glider transects across the Scotian Shelf, near Halifax, Nova Scotia, Canada, completed between 2011 and 2015 provide a dataset with high temporal and spatial resolutions. This new dataset is used to characterize the seasonal variability of the Nova Scotia Current (NSC): a southwestward, coastally-trapped, alongshore current flowing from the Gulf of St. Lawrence to the Gulf of Maine. Alongshore currents are estimated by scaling the geostrophic flow, derived from the density field, with the drift experienced by the glider during each dives. The results are compared to concurrent ADCP observations to assess the reliability of the technique and then used to characterize the alongshore circulation across the Halifax Line. It demonstrates that most of the alongshore transport is associated with the density front separating the low-density NSC from denser shelf water. An automated algorithm is then developed to monitor the major characteristics of the density front (e.g. width, frontal depth, density gradient). We find that the persistent summer stratification explains the lag observed between the seasonal pulse of buoyant water coming for the Gulf of St. Lawrence in the fall and the maximum alongshore current in the winter. This reveals that the density gradient is not the only major parameter explaining the seasonal and inter-annual variability of the NSC: the geometry of the density front also plays an important role. This makes wind forcing a potential major driving mechanism of the NSC, as alongshore winds can significantly affect the geometry of the density front via Ekman transport.

  9. Analysis of plasma equilibrium based on orbit-driven current density profile in steady-state plasma on QUEST

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, K., E-mail: nakamura@triam.kyushu-u.ac.jp [RIAM, Kyushu University, Kasuga 816-8580 (Japan); Alam, M.M. [IGSES, Kyushu University, Kasuga 816-8580 (Japan); Jiang, Y.Z. [Tsinghua University, Beijing 100084 (China); Mitarai, O. [Tokai University, Kumamoto 862-8652 (Japan); Kurihara, K.; Kawamata, Y.; Sueoka, M.; Takechi, M. [Japan Atomic Energy Agency, Naka 311-0193 (Japan); Hasegawa, M.; Tokunaga, K.; Araki, K.; Zushi, H.; Hanada, K.; Fujisawa, A.; Idei, H.; Nagashima, Y.; Kawasaki, S.; Nakashima, H.; Higashijima, A.; Nagata, T. [RIAM, Kyushu University, Kasuga 816-8580 (Japan); and others

    2016-11-01

    Highlights: • High energy particle guiding center orbit is calculated as a contour plot of conserved variable. • Current density profile is analyzed based on the orbit-driven current. • Plasma equilibrium is reconstructed by considering the hollow current profile. - Abstract: In the present RF-driven (ECCD) steady-state plasma on QUEST (B{sub t} = 0.25 T, R = 0.68 m, a = 0.40 m), plasma current seems to flow in the open magnetic surface outside of the closed magnetic surface in the low-field region according to plasma current fitting (PCF) method. We consider that the current in the open magnetic surface is due to orbit-driven current by high-energy particles in RF-driven plasma. So based on the analysis of current density profile based on the orbit-driven current, plasma equilibrium is to be calculated. We calculated high energy particles guiding center orbits as a contour plot of conserved variable in Hamiltonian formulation and considered particles initial position with different levels of energy and pitch angles that satisfy resonance condition. Then the profile of orbit-driven current is estimated by multiplying the particle density on the resonance surface and the velocity on the orbits. This analysis shows negative current near the magnetic axis and hollow current profile is expected even if pressure driven current is considered. Considering the hollow current profile shifted toward the low-field region, the equilibrium is fitted by J-EFIT coded by MATLAB.

  10. Numerically simulated cardiac exposure to electric current densities induced by TASER X-26 pulses in adult men

    Energy Technology Data Exchange (ETDEWEB)

    Leitgeb, N; Niedermayr, F; Neubauer, R; Loos, G, E-mail: norbert.leitgeb@tugraz.a [Institute of Clinical Engineering with European Notified Body of Medical Devices, Graz University of Technology, Inffeldgasse 18, A-8010 Graz (Austria)

    2010-10-21

    There is still an ongoing debate whether or not electronic stun devices (ESDs) induce cardiac fibrillation. To assess the ventricular fibrillation risk of law enforcing electronic control devices, quantitative estimates of cardiac electric current densities induced by delivered electric pulses are essential. Numerical simulations were performed with the finite integration technique and the anatomical model of a standardized European man (NORMAN) segmented into 2 mm voxels and 35 different tissues. The load-dependent delivery of TASER X-26 pulses has been taken into account. Cardiac exposure to electric current densities of vertically and horizontally aligned dart electrodes was quantified and different hit scenarios compared. Since fibrillation thresholds critically depend on exposed volume, the provided quantitative data are essential for risk assessment. The maximum cardiac rms current densities amounted to 7730 A m{sup -2}. Such high current densities and exposed cardiac volumes do not exclude ventricular fibrillation.

  11. Numerically simulated cardiac exposure to electric current densities induced by TASER X-26 pulses in adult men

    Science.gov (United States)

    Leitgeb, N.; Niedermayr, F.; Neubauer, R.; Loos, G.

    2010-10-01

    There is still an ongoing debate whether or not electronic stun devices (ESDs) induce cardiac fibrillation. To assess the ventricular fibrillation risk of law enforcing electronic control devices, quantitative estimates of cardiac electric current densities induced by delivered electric pulses are essential. Numerical simulations were performed with the finite integration technique and the anatomical model of a standardized European man (NORMAN) segmented into 2 mm voxels and 35 different tissues. The load-dependent delivery of TASER X-26 pulses has been taken into account. Cardiac exposure to electric current densities of vertically and horizontally aligned dart electrodes was quantified and different hit scenarios compared. Since fibrillation thresholds critically depend on exposed volume, the provided quantitative data are essential for risk assessment. The maximum cardiac rms current densities amounted to 7730 A m-2. Such high current densities and exposed cardiac volumes do not exclude ventricular fibrillation.

  12. Investigation into the erosive capacity of pyroclastic density currents at Mount Saint Helens, Washington (USA)

    Science.gov (United States)

    Pollock, N. M.; Brand, B. D.

    2012-12-01

    Two fundamental aspects of PDC dynamics that remain poorly understood are the primary control(s) on substrate erosion and the effect of erosion on downstream flow dynamics. The gap in understanding reflects the lack of sufficient field exposures with evidence for these processes. In the 32 years since the May 18th, 1980 eruption of Mount St Helens (MSH), kilometers of new outcrops have been exposed throughout the PDC and debris avalanche hummock deposits that provide substantial evidence of substrate erosion and entrainment by the PDCs produced throughout the afternoon of the eruption. Field observations include a reappearance of large lithics (>1 m) in PDC deposits at distances of 4-5 km from the vent, suggesting that these lithics were entrained locally. For this study, detailed componentry and roundness analyses are utilized to determine the source of lithics in PDC deposits and to quantify the erosive capacity of the PDCs at MSH. Comparison of componentry data from the PDC deposits with debris avalanche deposits ~200 m upstream indicate that >50% of the lithics were locally entrained. The entrainment of these lithics appears to have significantly altered the dynamics of the current as contacts between flow units change from purely depositional upstream from the hummocks to erosive and scouring following the entrainment of dense lithics. This evidence suggests that the capacity of a PDC to behave erosively could be a self-perpetuating process; entrainment of dense lithics at the base of the current results in an increased density gradient, which in turn enhances a current's ability to continue to erode. In addition, the presence of locally entrained lithics at various heights within a single flow unit and within close proximity to the source of the lithics suggests both a progressive entrainment of the substrate as well as a progressive aggradation of the deposits, depending on localized flow conditions. While erosion may have initially occurred due to the

  13. Multilayered Zn-Ni alloy coatings for better corrosion protection of mild steel

    Directory of Open Access Journals (Sweden)

    Sadananda Rashmi

    2017-06-01

    Full Text Available A simple aqueous electrolyte for the deposition of anti-corrosive Zn-Ni alloy coatings was optimized using conventional Hull cell method. The corrosion protection value of the electrodeposited coatings at a current density (c.d. range of 2.0–5.0 A dm−2 has been testified in 5 wt% NaCl solution, as representative corrosion medium. The electrochemical behavior of the coatings towards corrosion was related to its surface topography, elemental composition and phase structure using scanning electron microscopy (SEM, energy dispersive spectroscopy (EDS and X-ray diffraction (XRD analyses, respectively. Among the monolithic coatings developed at different c.d.’s, the coating obtained at 3.0 A dm−2 was found to be the best with least corrosion current (icorr value. Further, the corrosion protection efficacy of the monolayer coatings were improved to many folds through multilayer coating approach, by modulating the cyclic cathode current densities (CCCD’s. The composition modulated multilayer (CMM Zn-Ni alloy coating with 60 layers, developed from the combination of CCCD’s 3.0 and 5.0 A dm−2 was found to be the best with 3 fold enhancement in corrosion protection efficiency. The formation of multilayer coatings was confirmed using cross-sectional SEM, and the experimental results are discussed with tables and figures.

  14. Recognition and Analysis of Corrosion Failure Mechanisms

    Directory of Open Access Journals (Sweden)

    Steven Suess

    2006-02-01

    Full Text Available Corrosion has a vast impact on the global and domestic economy, and currently incurs losses of nearly $300 billion annually to the U.S. economy alone. Because of the huge impact of corrosion, it is imperative to have a systematic approach to recognizing and mitigating corrosion problems as soon as possible after they become apparent. A proper failure analysis includes collection of pertinent background data and service history, followed by visual inspection, photographic documentation, material evaluation, data review and conclusion procurement. In analyzing corrosion failures, one must recognize the wide range of common corrosion mechanisms. The features of any corrosion failure give strong clues as to the most likely cause of the corrosion. This article details a proven approach to properly determining the root cause of a failure, and includes pictographic illustrations of the most common corrosion mechanisms, including general corrosion, pitting, galvanic corrosion, dealloying, crevice corrosion, microbiologically-influenced corrosion (MIC, corrosion fatigue, stress corrosion cracking (SCC, intergranular corrosion, fretting, erosion corrosion and hydrogen damage.

  15. First test of BNL electron beam ion source with high current density electron beam

    International Nuclear Information System (INIS)

    Pikin, Alexander; Alessi, James G.; Beebe, Edward N.; Shornikov, Andrey; Mertzig, Robert; Wenander, Fredrik; Scrivens, Richard

    2015-01-01

    A new electron gun with electrostatic compression has been installed at the Electron Beam Ion Source (EBIS) Test Stand at BNL. This is a collaborative effort by BNL and CERN teams with a common goal to study an EBIS with electron beam current up to 10 A, current density up to 10,000 A/cm 2 and energy more than 50 keV. Intensive and pure beams of heavy highly charged ions with mass-to-charge ratio < 4.5 are requested by many heavy ion research facilities including NASA Space Radiation Laboratory (NSRL) at BNL and HIE-ISOLDE at CERN. With a multiampere electron gun, the EBIS should be capable of delivering highly charged ions for both RHIC facility applications at BNL and for ISOLDE experiments at CERN. Details of the electron gun simulations and design, and the Test EBIS electrostatic and magnetostatic structures with the new electron gun are presented. The experimental results of the electron beam transmission are given

  16. Effects of filament size on critical current density in overpressure processed Bi-2212 round wire.

    Science.gov (United States)

    Jiang, Jianyi; Francis, Ashleigh; Alicea, Ryan; Matras, Maxime; Kametani, Fumitake; Trociewitz, Ulf P; Hellstrom, Eric E; Larbalestier, David C

    2017-06-01

    Bi 2 Sr 2 CaCu 2 O x (Bi-2212) conductor is the only high temperature superconductor manufactured as a round wire and is a very promising conductor for very high field applications. One of the key design parameters of Bi-2212 wire is its filament size, which has been previously reported to affect the critical current density ( J c ) and ac losses. Work with 1 bar heat treatment showed that the optimal filament diameter was about 15 μm but it was not well understood at that time that gas bubbles were the main current limiting mechanism. Here we investigated a recent Bi-2212 wire with a 121×18 filament architecture with varying wire diameter (1.0 to 1.5 mm) using 50 bar overpressure processing. This wire is part of a 1.2 km piece length of 1.0 mm diameter made by Oxford Superconducting Technology. We found that J c is independent of the filament size in the range from 9 to 14 μm, although the n value increased with increasing filament size. A new record J c (4.2 K, 15 T) of 4200 A/mm 2 and J E (4.2 K, 15 T) of 830 A/mm 2 were achieved.

  17. Impact of the storm-time plasma sheet ion composition on the ring current energy density

    Science.gov (United States)

    Mouikis, C.; Kistler, L. M.; Petrinec, S. M.; Fuselier, S. A.; Cohen, I.

    2017-12-01

    The adiabatic inward transport of the night-side near-earth ( 6 Re) hot plasma sheet is the dominant contributor to the ring current pressure during storm times. During storm times, the plasma sheet composition in the 6 - 12 Re tail region changes due to O+ entry from the lobes (from the cusp) and the direct feeding from the night side auroral region. In addition, at substorm onset the plasma sheet O+ ions can be preferentially accelerated. We use MMS and observations during two magnetic storms, 5/8/2016 and 7/16/2017, to monitor the composition changes and energization in the 6 - 12 Re plasma sheet region. For both storms the MMS apogee was in the tail. In addition, we use subsequent Van Allen Probe observations (with apogee in the dawn and dusk respectively) to test if the 6-12 Re plasma sheet, observed by MMS, is a sufficient source of the O+ in the ring current. For this we will compare the phase space density (PSD) of the plasma sheet source population and the PSD of the inner magnetosphere at constant magnetic moment values as used in Kistler et al., [2016].

  18. Pyroclastic density currents at Stromboli volcano (Aeolian Islands, Italy): a case study of the 1930 eruption

    Science.gov (United States)

    Di Roberto, A.; Bertagnini, A.; Pompilio, M.; Bisson, M.

    2014-06-01

    Pyroclastic density currents (PDC) related to paroxysmal eruptions have caused a large number of casualties in the recent history of Stromboli. We combine here a critical review of historical chronicles with detailed stratigraphic, textural, and petrographic analyses of PDC deposits emplaced at Stromboli over the last century to unravel the origin of currents, their flow mechanism and the depositional dynamics. We focus on the 1930 PDC as they are well described in historical accounts and because the 1930 eruption stands as the most voluminous and destructive paroxysm of the last 13 centuries. Stromboli PDC deposits are recognizable from their architecture and the great abundance of fresh, well-preserved juvenile material. General deposit features indicate that Stromboli PDC formed due to the syn-eruptive gravitational collapse of hot pyroclasts rapidly accumulated over steep slopes. Flow channelization within the several small valleys cut on the flanks of the volcano can enhance the mobility of PDC, as well as the production of fine particles by abrasion and comminution of hot juvenile fragments, thereby increasing the degree of fluidization. Textural analyses and historical accounts also indicate that PDC can be fast (15-20 m/s) and relatively hot (360-700 °C). PDC can thus flow right down the slopes of the volcano, representing a major hazard. For this reason, they must be adequately taken into account when compiling risk maps and evaluating volcanic hazard on the Island of Stromboli.

  19. Flexible polyimide microelectrode array for in vivo recordings and current source density analysis.

    Science.gov (United States)

    Cheung, Karen C; Renaud, Philippe; Tanila, Heikki; Djupsund, Kaj

    2007-03-15

    This work presents implantable, flexible polymer-based probes with embedded microelectrodes for acute and chronic neural recordings in vivo, as tested on rodents. Acute recordings using this array were done in mice under urethane anesthesia and compared to those made using silicon-based probes manufactured at the Center for Neural Communication Technology, University of Michigan. The two electrode arrays yielded similar results. Recordings with chronically implanted polymer-based electrodes were performed for 60 days post-surgically in awake, behaving rats. The microelectrodes were used to monitor local field potentials and capture laminar differences in function of cortex and hippocampus, and produced response waveforms of undiminished amplitude and signal-to-noise ratios 8 weeks after chronic implantation. The polymer-based electrodes could also be connected to a lesion current to mark specific locations in the tissue. Current source density (CSD) analysis from the recordings depicted a source - sink-composition. Tissue response was assessed 8 weeks after insertion by immunochemical labeling with glial fibrillary acidic protein (GFAP) to identify astrocytes, and histological analysis showed minimal tissue reaction to the implanted structures.

  20. Current-density functional theory study of the H2 molecule evolving under a strong ultrashort magnetic field

    Science.gov (United States)

    Vikas, Hash(0xb7f6e60)

    2012-01-01

    Hydrogen molecule in a strong ultrashort magnetic field is investigated through a current-density functional theory (CDFT) and quantum fluid dynamics (QFD) based approach employing current-density dependent vector exchange-correlation potential and energy density functional derived with a vorticity variable. The numerical computations through the CDFT based approach are performed for the H2 molecule, starting initially from its field-free ground state, in a parallel internuclear axis and magnetic field-axis configuration with the internuclear separation R ranging from 0.1 a.u. to 14.0 a.u., and the strength of the time-dependent (TD) magnetic field varying between 0-1011 G over a few femtoseconds. The numerical results are compared with that obtained using an approach based on the current-density independent approximation under similar computational constraints but employing only scalar exchange-correlation potential dependent on the electronic charge-density alone. The current-density based approach yields exchange- and correlation energy as well as electronic charge-density of the H2 molecule drastically different from that obtained using current-independent approach, in particular, at TD magnetic field-strengths >109 G during a typical time-period of the field when the magnetic-field had attained maximum applied field-strength and is switched to a decreasing ramp function. This nonadiabatic behavior of the TD electronic charge-density is traced to the TD vorticity-dependent vector exchange-correlation potential of the CDFT based approach. The interesting electron dynamics of the H2 molecule in strong TD magnetic field is further elucidated by treating electronic charge-density as an `electron-fluid'. The present work also reveals interesting real-time dynamics on the attosecond time-scale in the electronic charge-density distribution of the hydrogen molecule.

  1. Change of the dominant luminescent mechanism with increasing current density in molecularly doped organic light-emitting devices

    International Nuclear Information System (INIS)

    Zhou Liang; Zhang Hongjie; Meng Qingguo; Liu Fengyi; Yu Jiangbo; Deng Ruiping; Peng Zeping; Li Zhefeng; Guo Zhiyong

    2007-01-01

    We have fabricated and measured a series of electroluminescent devices with the structure of ITO/TPD/Eu(TTA) 3 phen (x):CBP/BCP/ALQ/LiF/Al, where x is the weight percentage of Eu(TTA) 3 phen (from 0% to 6%). At very low current density, carrier trapping is the dominant luminescent mechanism and the 4% doped device shows the highest electroluminescence (EL) efficiency among all these devices. With increasing current density, Foerster energy transfer participates in EL process. At the current density of 10.0 and 80.0 mA/cm 2 , 2% and 3% doped devices show the highest EL efficiency, respectively. From analysis of the EL spectra and the EL efficiency-current density characteristics, we found that the EL efficiency is manipulated by Foerster energy transfer efficiency at high current density. So we suggest that the dominant luminescent mechanism changes gradually from carrier trapping to Foerster energy transfer with increasing current density. Moreover, the conversion of dominant EL mechanism was suspected to be partly responsible for the EL efficiency roll-off because of the lower EL quantum efficiency of Foerster energy transfer compared with carrier trapping

  2. A novel model for through-silicon via (TSV) filling process simulation considering three additives and current density effect

    Science.gov (United States)

    Wang, Fuliang; Zhao, Zhipeng; Wang, Feng; Wang, Yan; Nie, Nantian

    2017-12-01

    Through-silicon via (TSV) filling by electrochemical deposition is still a challenge for 3D IC packaging, and three-component additive systems (accelerator, suppressor, and leveler) were commonly used in the industry to achieve void-free filling. However, models considering three additive systems and the current density effect have not been fully studied. In this paper, a novel three-component model was developed to study the TSV filling mechanism and process, where the interaction behavior of the three additives (accelerator, suppressor, and leveler) were considered, and the adsorption, desorption, and consumption coefficient of the three additives were changed with the current density. Based on this new model, the three filling types (seam void, ‘V’ shape, and key hole) were simulated under different current density conditions, and the filling results were verified by experiments. The effect of the current density on the copper ion concentration, additives surface coverage, and local current density distribution during the TSV filling process were obtained. Based on the simulation and experimental results, the diffusion–adsorption–desorption–consumption competition behavior between the suppressor, the accelerator, and the leveler were discussed. The filling mechanisms under different current densities were also analyzed.

  3. Topographic control on pyroclastic density currents: the example of Mount St. Helens 1980 blast

    Science.gov (United States)

    Esposti Ongaro, T.; Clarke, A. B.; Voight, B.; Neri, A.; Widiwijayanti, C.

    2012-04-01

    Volcanic lateral blasts are among the most spectacular and devastating of natural phenomena, characterized by the violent release of a relatively low mass of magma producing a remarkably broad area of significant damage. The most known volcanic blast at Mount Saint Helens, on 18 May 1980, devastated an area of 600 squared km in about five minutes, being able to override topographic obstacles of several hundreds of metres. By means of 3D multiphase numerical simulations we demonstrate that Mount St. Helens blast was generated by the rapid expansion (burst) of a pressurized polydisperse mixture of gas and particles and its subsequent gravitational collapse and that the observed front propagation, final runout and damage can be explained by the emplacement of an unsteady, stratified pyroclastic density current (PDC), controlled by gravity and terrain morphology. Numerical results are able to describe the non-equilibrium sedimentation dynamics of volcanic particles during PDC propagation across the rugged topography characterizing the area devastated by the blast. In valleys and topographic lows, pyroclasts accumulate progressively at the base of the flow, after the passage of the flow head, forming a dense basal flow depleted in fines. Blocking and channelling of such basal flow by topographic ridges provides the mechanism for progressive current unloading. On ridges, sedimentation occurs from the upper, dilute wake region, which follows the current head. Although the model formulation and the vertical numerical resolution do not yet allow the direct simulation of the deposit consolidation, present results provide a consistent, quantitative model able to interpret the observed stratigraphic sequence.

  4. Influence of MAO Treatment on the Galvanic Corrosion Between Aluminum Alloy and 316L Steel

    Science.gov (United States)

    Yang, Yuanhang; Gu, Yanhong; Zhang, Lei; Jiao, Xiangdong; Che, Juntie

    2017-12-01

    To slow down the galvanic corrosion of aluminum alloy and 316L stainless steel in subsea water, a micro-arc oxidation (MAO) coating was prepared on the surface of the Al alloy, and no treatment was performed on the surface of the 316L. The surface morphology of MAO-coated Al alloy was evaluated using a scanning electron microscope (SEM) before and after corrosion. A micro-hardness tester was used to measure the micro-hardness. Corrosion behaviors were evaluated by open-circuit potential (OCP), potentiodynamic polarization (PDP) and electrode impedance spectroscopy (EIS) tests in a 3.5 g/L NaCl solution. The results of PDP testing show that the corrosion potential of the MAO-coated galvanic pair was more positive than that of the uncoated galvanic pair and that the corrosion current density was smaller than that of the uncoated galvanic pair. EIS results show that the impedance of the galvanic pair increased after MAO coating. SEM images show that the corrosion damage of the uncoated Al alloy was more severe than that of the MAO-coated one, and the post-corrosion images of the surface of the 316L connected with MAO-coated Al alloy were more compact than those of the 316L connected with uncoated Al alloy. A physical model was developed to discuss the influence of MAO treatment on the galvanic corrosion process and corrosion mechanism.

  5. Effect of Multipass Friction Stir Processing on Mechanical and Corrosion Behavior of 2507 Super Duplex Stainless Steel

    Science.gov (United States)

    Mishra, M. K.; Gunasekaran, G.; Rao, A. G.; Kashyap, B. P.; Prabhu, N.

    2017-02-01

    The microstructure, mechanical properties, and corrosion behavior of 2507 super duplex stainless steel after multipass friction stir processing (FSP) were examined. A significant refinement in grain size of both ferrite and austenite was observed in stir zone resulting in improved yield and tensile strength. Electrochemical impedance spectroscopy and anodic polarization studies in 3.5 wt.% NaCl solution showed nobler corrosion characteristics with increasing number of FSP passes. This was evident from the decrease in corrosion current density, decrease in passive current density, and increase in polarization resistance. Also, the decrease in density of defects, based on Mott-Schottky analysis, further confirms the improvement in corrosion resistance of 2507 super duplex stainless steel after multipass FSP.

  6. Metal alloys for the new generation of compressors at hydrogen stations: Parametric study of corrosion behavior

    DEFF Research Database (Denmark)

    Arjomand Kermani, Nasrin; Petrushina, Irina; Nikiforov, Aleksey Valerievich

    2017-01-01

    the corrosion rate. However, even at 80 °C, the very low corrosion current densities proved that all of the tested alloys are safe to use as construction materials. AISI 347 showed very high corrosion resistance in all of the ionic liquids. The highest corrosion resistance among all of the tested alloys......, consequently, significantly reduce the final cost of hydrogen production. The correct choice of ionic liquid and construction materials is critical for avoiding significant corrosion problems. Hence, the objective of this study is to evaluate the compatibility of various austenitic stainless steels and nickel......-based alloys as construction materials in contact with 80 °C ionic liquids in an ionic liquid hydrogen compressor, considering the role of parameters such as the temperature, viscosity, ionic liquid cation and anion, and water absorption. The results show that temperature contributes to increasing...

  7. Electrochemical Corrosion Characteristics of Arc-Ion-Plated AlTiN Coating for Marine Application.

    Science.gov (United States)

    Lee, Jung-Hyung; Kim, MyoungJun; Kim, Seong-Jong

    2016-02-01

    In this study, aluminum titanium nitride (AlTiN) coating was deposited by arc ion plating onto mirror finish STS 304 plate. The surface and cross-section of the coating was characterized by SEM and EDX analysis. Several electrochemical corrosion experiments were performed including rest potential measurement, potentiodynamic polarization experiment and Tafel analysis. The result of the experiments indicated that the AlTiN coating presented lower corrosion current density than the substrate material (STS 304) under uniform corrosion environment. It was also observed that AlTiN coating may have a risk of being attacked by localized corrosion attack such as pitting when pores or micro/nano particles in the coating are exposed to chloride ion containing corrosion environment, especially marine environment.

  8. He 2++ molecular ion in a strong time-dependent magnetic field: a current-density functional study.

    Science.gov (United States)

    Vikas

    2011-08-01

    The He 2++ molecular ion exposed to a strong ultrashort time-dependent (TD) magnetic field of the order of 10(9) G is investigated through a quantum fluid dynamics (QFD) and current-density functional theory (CDFT) based approach using vector exchange-correlation (XC) potential and energy density functional that depend not only on the electronic charge-density but also on the current density. The TD-QFD-CDFT computations are performed in a parallel internuclear-axis and magnetic field-axis configuration at the field-free equilibrium internuclear separation R = 1.3 au with the field-strength varying between 0 and 10(11) G. The TD behavior of the exchange- and correlation energy of the He 2++ is analyzed and compared with that obtained using a [B-TD-QFD-density functional theory (DFT)] approach based on the conventional TD-DFT under similar computational constraints but using only scalar XC potential and energy density functional dependent on the electronic charge-density alone. The CDFT based approach yields TD exchange- and correlation energy and TD electronic charge-density significantly different from that obtained using the conventional TD-DFT based approach, particularly, at typical magnetic field strengths and during a typical time period of the TD field. This peculiar behavior of the CDFT-based approach is traced to the TD current-density dependent vector XC potential, which can induce nonadiabatic effects causing retardation of the oscillating electronic charge density. Such dissipative electron dynamics of the He 2++ molecular ion is elucidated by treating electronic charge density as an electron-"fluid" in the terminology of QFD. Copyright © 2011 Wiley Periodicals, Inc.

  9. 3-D time-domain induced polarization tomography: a new approach based on a source current density formulation

    Science.gov (United States)

    Soueid Ahmed, A.; Revil, A.

    2018-04-01

    Induced polarization (IP) of porous rocks can be associated with a secondary source current density, which is proportional to both the intrinsic chargeability and the primary (applied) current density. This gives the possibility of reformulating the time domain induced polarization (TDIP) problem as a time-dependent self-potential-type problem. This new approach implies a change of strategy regarding data acquisition and inversion, allowing major time savings for both. For inverting TDIP data, we first retrieve the electrical resistivity distribution. Then, we use this electrical resistivity distribution to reconstruct the primary current density during the injection/retrieval of the (primary) current between the current electrodes A and B. The time-lapse secondary source current density distribution is determined given the primary source current density and a distribution of chargeability (forward modelling step). The inverse problem is linear between the secondary voltages (measured at all the electrodes) and the computed secondary source current density. A kernel matrix relating the secondary observed voltages data to the source current density model is computed once (using the electrical conductivity distribution), and then used throughout the inversion process. This recovered source current density model is in turn used to estimate the time-dependent chargeability (normalized voltages) in each cell of the domain of interest. Assuming a Cole-Cole model for simplicity, we can reconstruct the 3-D distributions of the relaxation time τ and the Cole-Cole exponent c by fitting the intrinsic chargeability decay curve to a Cole-Cole relaxation model for each cell. Two simple cases are studied in details to explain this new approach. In the first case, we estimate the Cole-Cole parameters as well as the source current density field from a synthetic TDIP data set. Our approach is successfully able to reveal the presence of the anomaly and to invert its Cole

  10. Prior knowledge on cortex organization in the reconstruction of source current densities from EEG.

    Science.gov (United States)

    Knösche, Thomas R; Gräser, Markus; Anwander, Alfred

    2013-02-15

    The reconstruction of the generators of electroencephalographic (EEG) signals is important for understanding brain processes. Since the inverse problem has no unique solution, additional knowledge or assumptions are needed. Often, results from other anatomical or functional measurement modalities are difficult to interpret directly in terms of EEG source strengths, but they provide valuable information about the functional similarity between brain regions, for example, in form of parcellations. We propose a novel approach to the incorporation of such parcellations as priors into the reconstruction of distributed source current densities from EEG. Two algorithms are described, based on a surface-constrained LORETA (Low Resolution Electromagnetic TomogrAphy) approach. The first, patchLORETA1, uses both topological neighborhood and prior information to define smoothness, while the second, patchLORETA2, neglects topological neighborhood. Computer simulations, using a smooth reconstruction surface on the brain envelope, reveal important aspects of the algorithms' performance, in particular the influences of noise and incongruence between measurements and prior information. It turns out that patchLORETA1 makes efficient use of the provided prior information and at the same time is quite robust towards faulty priors as well as noise. The algorithms are also tested on the localization of the sources of event-related potentials. Here, both the smooth brain and folded cortical surfaces serve as reconstruction spaces. We find that patchLORETA1 becomes ineffective on the folded cortex, while patchLORETA2 yields plausible results. We also discuss the extension of the proposed algorithms to other types of priors and propose ways to overcome shortcomings of the current implementation. Copyright © 2012 Elsevier Inc. All rights reserved.

  11. Induced current density in the foetus of pregnant workers in high magnetic field environments

    International Nuclear Information System (INIS)

    Xue, C.; Wood, A.W.

    2004-01-01

    Full text: There are moves to limit by legislation the amount of electric and magnetic fields that workers and the general public are exposed to. In work locations near wiring, cables and equipment carrying high electric currents, there are situations in which the proposed magnetic field limits could be exceeded. Since the limits for the general public are more conservative than those for workers and since the foetus or a pregnant worker should be afforded the status of a member of the general public, it is important to assess a worst-case scenario for the purposes of a general code of practice. Three different magnetic field exposures are modelled, which include the worst case - the body of a pregnant woman at a smallest distance of 30 cm to the conductor. All computations were done by using Multiple Multipole Program (MMP), which is based on the Generalized Multipole Technique (GMT) from ETH (Swiss Federal Institute of Technology), Zurich, Switzerland. The torso was modelled as a capped cylinder containing concentric placental and amniotic fluid layers containing a foetus. Appropriate values for conductivity and permittivity were applied to these layers and the Maxwell Equation solver applied for the situations of: cable beneath, alongside perpendicular and alongside parallel to the long axis of the body. Induced current density values were computed for cable distances of 0.3 and 0.5 m from the body and compared to the recommended limit values of 10 and 2 mA/m 2 for Occupational and General Public populations respectively. Regions where these values would be exceeded have been identified in this analysis. In a worst-case scenario the proposed basic restrictions would be exceeded slightly in both maternal and foetal tissue. With appropriate pre-placement assessment, these over-exposures can be avoided. Copyright (2004) Australasian College of Physical Scientists and Engineers in Medicine

  12. Current source density analysis of the potential evoked in hippocampus by perirhinal cortex stimulation.

    Science.gov (United States)

    Liu, P; Bilkey, D K

    1997-01-01

    Previous anatomical research has demonstrated that the perirhinal cortex (PRC) projects to the dorsal hippocampal CA1 field. We have recently presented data (Liu and Bilkey, Hippocampus 1996; 6:125-135) which suggests that this pathway courses via the lateral perforant path (LPP). In the present study, laminar profiles of the average evoked potentials and current source density (CSD) analysis were used to study the input from the perirhinal cortex to the dorsal hippocampus in the urethane-anaesthetized rat. Stimulation of the lateral perforant path activated a current sink in the stratum lacunosum-moleculare of CA1 and the outer molecular layer of the dentate gyrus with an onset latency of 3.5 ms. Stimulation of the perirhinal cortex produced a very similar sink-source pattern with an onset latency of 4.0 ms. Higher-intensity stimulation of lateral entorhinal cortex also produced a similar pattern with an onset latency of 4.5 ms. Electrolytic lesions of PRC conducted 4-5 days prior to testing resulted in a major decrease (58%) in the amplitude of the LPP-elicited potentials and a corresponding reduction across the whole source-sink pattern. A similar result was observed following ibotenic acid lesions of PRC. In contrast, similar-sized electrolytic lesions of lateral entorhinal cortex produced a much smaller (16%) decrease in potential amplitude and little change in the source-sink pattern. These data provide further support for the hypothesis that perirhinal cortex projects to both the dentate gyrus and CA1 regions of the hippocampus via the lateral perforant path.

  13. Standard practice for calculation of corrosion rates and related information from electrochemical measurements

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    1989-01-01

    1.1 This practice covers the providing of guidance in converting the results of electrochemical measurements to rates of uniform corrosion. Calculation methods for converting corrosion current density values to either mass loss rates or average penetration rates are given for most engineering alloys. In addition, some guidelines for converting polarization resistance values to corrosion rates are provided. 1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

  14. Adhesion and corrosion studies of a lithium based conversion coating film on the 2024 aluminum alloy

    International Nuclear Information System (INIS)

    Castro, M.R.S.; Nogueira, J.C.; Thim, G.P.; Oliveira, M.A.S.

    2004-01-01

    AA2024-T3-aluminum alloy surfaces were coated using non-chromate and chromate conversion coatings. All coatings were painted with the 10P4-2-primer epoxy resin. Independent on the film formation process, films passed on the substrate/conversion coating wet tape adhesion test. However, only the chromate conversion coating passed on the conversion coating/primer epoxy resin adhesion test. Electrochemical corrosion measurements showed that non-chromate conversion coated surfaces present lower corrosion current density, bigger polarization resistance and less negative corrosion potential than chromate conversion coated surfaces

  15. Enhancement of transport critical current density of epitaxial Nb film by lithography

    Science.gov (United States)

    Yamada, H.; Harada, N.; Kanayama, K.; Nakagawa, S.; Yamasaki, H.; Hamajima, T.

    2005-12-01

    The critical current density, JC, of a superconductor is controlled by the pinning interaction between the flux line lattice and pinning centers. Artificial flux pinning centers are necessary for high- TC superconductors, because JC decreases markedly when a magnetic field of a few Tesla is applied at the temperature of liquid nitrogen. Here, we discuss the effects of groove-shaped artificial pinning centers introduced by microlithography. Superconducting Nb film was deposited epitaxially on Al 2O 3(1 1 0 2) substrates and grooves with a period of 4-μm were introduced. The micro-fabricated film had about 2-fold greater transport JC = 4.1 × 10 9 A/m 2 as compared with the value of JC = 2.1 × 10 9 A/m 2 of the standard film at 4.2 K, 0.1 T. This JC enhancement was observed over a wide temperature range of 4.2-9.0 K.

  16. Development of Ti-sheathed MgB2 wires with high critical current density

    International Nuclear Information System (INIS)

    Liang, G; Fang, H; Hanna, M; Yen, F; Lv, B; Alessandrini, M; Keith, S; Hoyt, C; Tang, Z; Salama, K

    2006-01-01

    Working towards developing lightweight superconducting magnets for future space and other applications, we have successfully fabricated mono-core Ti-sheathed MgB 2 wires by the powder-in-tube method. The wires were characterized by magnetization, electrical resistivity, x-ray diffraction, scanning electron microscopy, and energy dispersive spectrometry measurements. The results indicate that the Ti sheath does not react with the magnesium and boron, and the present wire rolling process can produce MgB 2 wires with a superconducting volume fraction of at least 64% in the core. Using the Bean model, it was found that at 5 K, the magnetic critical current densities, J c , measured in magnetic fields of 0, 5, and 8 T are about 4.2 x 10 5 , 3.6 x 10 4 , and 1.4 x 10 4 A cm -2 , respectively. At 20 K and 0 T, the magnetic J c is about 2.4 x 10 5 A cm -2 . These results show that at zero and low fields, the values of the magnetic J c for Ti-sheathed MgB 2 wires are comparable with the best results available for the Fe-sheathed MgB 2 wires. At high fields, however, the J c for Ti-sheathed MgB 2 wires appears higher than that for the Fe-sheathed MgB 2 wires

  17. Semantic category interference in overt picture naming: sharpening current density localization by PCA.

    Science.gov (United States)

    Maess, Burkhard; Friederici, Angela D; Damian, Markus; Meyer, Antje S; Levelt, Willem J M

    2002-04-01

    The study investigated the neuronal basis of the retrieval of words from the mental lexicon. The semantic category interference effect was used to locate lexical retrieval processes in time and space. This effect reflects the finding that, for overt naming, volunteers are slower when naming pictures out of a sequence of items from the same semantic category than from different categories. Participants named pictures blockwise either in the context of same- or mixed-category items while the brain response was registered using magnetoencephalography (MEG). Fifteen out of 20 participants showed longer response latencies in the same-category compared to the mixed-category condition. Event-related MEG signals for the participants demonstrating the interference effect were submitted to a current source density (CSD) analysis. As a new approach, a principal component analysis was applied to decompose the grand average CSD distribution into spatial subcomponents (factors). The spatial factor indicating left temporal activity revealed significantly different activation for the same-category compared to the mixed-category condition in the time window between 150 and 225 msec post picture onset. These findings indicate a major involvement of the left temporal cortex in the semantic interference effect. As this effect has been shown to take place at the level of lexical selection, the data suggest that the left temporal cortex supports processes of lexical retrieval during production.

  18. Field and temperature scaling of the critical current density in commercial REBCO coated conductors

    CERN Document Server

    Senatore, Carmine; Bonura, Marco; Kulich, Miloslav; Mondonico, Giorgio

    2016-01-01

    Scaling relations describing the electromagnetic behaviour of coated conductors (CCs) greatly simplify the design of REBCO-based devices. The performance of REBCO CCs is strongly influenced by fabrication route, conductor architecture and materials, and these parameters vary from one manufacturer to the others. In the present work we have examined the critical surface for the current density, Jc(T,B,θ ), of coated conductors from six different manufacturers: American Superconductor Co. (US), Bruker HTS GmbH (Germany), Fujikura Ltd. (Japan), SuNAM Co. Ltd. (Korea), SuperOx ZAO (Russia) and SuperPower Inc. (US). Electrical transport and magnetic measurements were performed at temperatures between 4.2 K and 77 K and in magnetic field up to 19 T. Experiments were conducted at three different orientations of the field with respect to the crystallographic c-axis of the REBCO layer, θ = 0deg , 45deg and 90deg , in order to probe the angular anisotropy of Jc. In spite of the large variability of CCs performance, ...

  19. High critical current density YBCO films and fabrication of dc-SQUIDs

    CERN Document Server

    Kuriki, S; Kawaguchi, Y; Matsuda, M; Otowa, T

    2002-01-01

    In order to improve the sensitivity of SQUID magnetometers made of high-T sub c films, we have studied the conditions of pulsed-laser deposition of YBCO films. Among the different deposition parameters examined, extensive degassing of the vacuum chamber before and precise control of the substrate temperature during the film deposition were found effective for obtaining high critical temperature T sub c and high critical current density J sub c. It was also found that the residual-resistance ratio has a clear correlation with J sub c , indicating that it can be a good, and easy to measure, index of the film quality. Films having T sub c approx 89-90 K and J sub c >= 5x10 sup 6 A cm sup - sup 2 at 77 K were used to fabricate SQUIDs without a pickup loop. Grain-boundary junctions formed on bicrystal substrates with a 30 deg. misorientation angle exhibited I sub c R sub n values of more than 100 mu V at 77 K. The well-known scaling behaviour of the relation I sub c R sub n propor to (J sup G sup B sub c) sup 1 su...

  20. A dense voltage-mode Josephson memory cell insensitive to systematic variations in critical current density

    International Nuclear Information System (INIS)

    Bradley, P.; Van Duzer, T.

    1985-01-01

    A destructive read-out (DRO) memory cell using three Josephson junctions has been devised whose operation depends only on the ratio of critical currents and application of the proper read/write voltages. The effects of run-to-run and across-thewafer variations in I /SUB c/ are minimized since all three junctions for a given cell are quite close to each other. Additional advantages are: immunity from flux trapping, high circuit density, and fast switching. Since destructive read-out is generally undesirable, a self-rewriting scheme is necessary. Rows and columns of cells with drivers and sense circuits, as well as small memory arrays and decoders have been simulated on SPICE. Power dissipation of cells and bias circuits for a 1K-bit RAM is estimated at about 2 mW. Inclusion of peripheral circuitry raises this by as much as a factor of five depending on the driving scheme and speed desired. Estimated access time is appreciably less than a nanosecond. Preliminary experimental investigations are reported

  1. Photoelectrolysis of water at high current density - Use of ultraviolet laser excitation

    Science.gov (United States)

    Bocarsly, A. B.; Bolts, J. M.; Cummins, P. G.; Wrighton, M. S.

    1977-01-01

    The behavior of TiO2 and SrTiO3 photoanodes in cells for the photoelectrolysis of H2O has been investigated for high-intensity 351-,364-nm excitation from an Ar ion laser. Intensities up to 380 W/sq cm have been used. For TiO2 a small amount of surface decomposition is found after irradiation at high intensity, whereas SrTiO3 undergoes no detectable changes. Current-voltage properties for both electrodes are essentially independent of light intensity up to the level of 380 W/sq cm, and there is little if any change in quantum efficiency for electron flow. Photocurrent densities have been shown to exceed 5 A/sq cm for O2 evolution. Data show that the energy storage rate associated with the SrTiO3 photoelectrolysis can exceed 30 W/sq cm; this represents the highest demonstrated rate of sustained optical-to-chemical energy conversion.

  2. Physiology of the entorhinal and perirhinal projections to the hippocampus studied by current source density analysis.

    Science.gov (United States)

    Canning, K J; Wu, K; Peloquin, P; Kloosterman, F; Leung, L S

    2000-06-01

    Evoked field potentials and current-source-density analysis were used to study the olfactory, entorhinal, and perirhinal projections to the hippocampus. In urethane-anesthetized rats, various structures were electrically stimulated, and evoked potentials were mapped using glass micropipettes or multichannel silicon probes. Stimulation of the olfactory bulb, lateral olfactory tract, piriform cortex, amygdala-entorhinal transition, lateral entorhinal cortex, or lateral perforant path (LPP) evoked an outer molecular layer sink (inferred distal dendritic excitation) in the dentate gyrus, with progressively decreasing onset latency. Medial perforant path (MPP) stimulation evoked a middle molecular layer sink (mid-dendritic excitation) in the dentate gyrus. LPP and MPP were also inferred to monosynaptically excite the distal dendrites of CA3, often resulting in a population spike in CA3. CA3 spiking, in turn, was often followed by excitation at the inner molecular layer of the dentate gyrus. LPP and MPP evoked distal dendritic sinks but no population spikes in CA1. Stimulation of the perirhinal cortex activated a sink in the subiculum/CA1 border without activating the dentate gyrus. In addition, reverberatory activity through a hippocampal-entorhinal-hippocampal pathway may be activated by MPP or CA3 stimulation. It is suggested that the parallel projections of the entorhinal and perirhinal inputs to the distal dendrites of hippocampal principal neurons enhance local and distributed processing as characterized by CA3 to dentate gyrus feedback, and hippocampal-entorhinal reverberation.

  3. Corrosion protection

    Science.gov (United States)

    Brown, Donald W.; Wagh, Arun S.

    2003-05-27

    There has been invented a chemically bonded phosphate corrosion protection material and process for application of the corrosion protection material for corrosion prevention. A slurry of iron oxide and phosphoric acid is used to contact a warm surface of iron, steel or other metal to be treated. In the presence of ferrous ions from the iron, steel or other metal, the slurry reacts to form iron phosphates which form grains chemically bonded onto the surface of the steel.

  4. Electrochemical anodizing treatment to enhance localized corrosion resistance of pure titanium.

    Science.gov (United States)

    Prando, Davide; Brenna, Andrea; Bolzoni, Fabio M; Diamanti, Maria V; Pedeferri, Mariapia; Ormellese, Marco

    2017-01-26

    Titanium has outstanding corrosion resistance due to the thin protective oxide layer that is formed on its surface. Nevertheless, in harsh and severe environments, pure titanium may suffer localized corrosion. In those conditions, costly titanium alloys containing palladium, nickel and molybdenum are used. This purpose investigated how it is possible to control corrosion, at lower cost, by electrochemical surface treatment on pure titanium, increasing the thickness of the natural oxide layer. Anodic oxidation was performed on titanium by immersion in H2SO4 solution and applying voltages ranging from 10 to 80 V. Different anodic current densities were considered. Potentiodynamic tests in chloride- and fluoride-containing solutions were carried out on anodized titanium to determine the pitting potential. All tested anodizing treatments increased corrosion resistance of pure titanium, but never reached the performance of titanium alloys. The best corrosion behavior was obtained on titanium anodized at voltages lower than 40 V at 20 mA/cm2. Titanium samples anodized at low cell voltage were seen to give high corrosion resistance in chloride- and fluoride-containing solutions. Electrolyte bath and anodic current density have little effect on the corrosion behavior.

  5. Influence of the solution temperature on the corrosion behavior of an austenitic stainless steel in phosphoric acid medium

    Energy Technology Data Exchange (ETDEWEB)

    Ibanez-Ferrandiz, M.V.; Blasco-Tamarit, E.; Garcia-Garcia, D.M.; Garcia-Anton, J. [Valencia Univ. Politecnica, Dept. de Ingenieria Quimica y Nuclear. ETSI Industriales, Valencia (Spain); Guenbour, A.; Bakour, S.; Benckokroun, A. [University Mohammed V-Agdal, Lab. Corrosion-Electrochimie, Faculty of Sciences, Rabat (Morocco)

    2009-07-01

    The objective of the present work is to study the effect of the solution temperature on the corrosion resistance of a highly alloyed austenitic stainless steel (UNS N08031) used as base metal, the welded metal obtained by TIG (Tungsten Inert Gas) welding using a Nickel-base alloy (UNS N06059) as filler metal, and the Heat Affected Zone (HAZ) of the base metal. The materials were tested in 5.5 M phosphoric acid solution at 25 C, 40 C, 60 C and 80 C. Open Circuit Potential tests and potentiodynamic anodic polarization curves have been carried out to obtain information about the electrochemical behavior of the materials. Corrosion potentials and corrosion current densities were obtained from Tafel analysis. The critic potentials and passivation current densities of the studied materials were also analyzed. The galvanic corrosion generated by the electrical contact between the welded metal, the base metal and the HAZ, was estimated from the polarisation diagrams according to the Mixed Potential Theory. The samples were etched to study their microstructure by Optical Microscopy. Results demonstrated that the corrosion potential values shift to more anodic potentials as temperature increases. The corrosion current densities and the passive current densities increased with temperature. Open circuit potential values were located in the passive zone of the potentiodynamic curves, which means that the materials passivated spontaneously. (authors)

  6. ac impedance, X-ray photoelectron spectroscopy and density functional theory studies of 3,5-bis(n-pyridyl)-1,2,4-oxadiazoles as efficient corrosion inhibitors for carbon steel surface in hydrochloric acid solution

    Energy Technology Data Exchange (ETDEWEB)

    Outirite, Moha; Lagrenee, Michel; Lebrini, Mounim [Unite de Catalyse et de Chimie du Solide, UMR-CNRS 8181, ENSCL, B.P. 90108, F-59652 Villeneuve d' Ascq Cedex (France); Traisnel, Michel; Jama, Charafeddine [Laboratoire des Procedes d' Elaboration des Revetements Fonctionnels, PERF UMR-CNRS 8008, ENSCL, B.P. 90108, F-59652 Villeneuve d' Ascq Cedex (France); Vezin, Herve [Laboratoire de Chimie Organique et Macromoleculaire, UMR-CNRS 8009, USTL Bat C4, F-59655 Villeneuve d' Ascq Cedex (France); Bentiss, Fouad, E-mail: fbentiss@enscl.f [Laboratoire de Chimie de Coordination et d' Analytique, Faculte des Sciences, Universite Chouaib Doukkali, B.P. 20, M-24000 El Jadida (Morocco)

    2010-02-01

    The corrosion inhibition properties of a new class of oxadiazole derivatives, namely 3,5-bis(n-pyridyl)-1,2,4-oxadiazoles (n-DPOX) for C38 carbon steel corrosion in 1 M HCl medium were analysed by electrochemical impedance spectroscopy (EIS). An adequate structural model of the interface was used and the values of the corresponding parameters were calculated and discussed. The experimental results showed that these compounds are excellent inhibitors for the C38 steel corrosion in acid solution and that the protection efficiency increased with increasing the inhibitors concentration. Electrochemical impedance data demonstrate that the addition of the n-DPOX derivatives in the corrosive solution decreases the charge capacitance and simultaneously increases the function of the charge/discharge of the interface, facilitating the formation of an adsorbed layer over the steel surface. Adsorption of these inhibitors on the steel surface obeys to the Langmuir adsorption isotherm. X-ray photoelectron spectroscopy (XPS) and the thermodynamic data of adsorption showed that inhibition of steel corrosion in normal hydrochloric solution by n-DPOX is due to the formation of a chemisorbed film on the steel surface. Quantum chemical calculations using the Density Functional Theory (DFT) and the Quantitative Structure Activity Relationship (QSAR) approach were performed on n-DPOX derivatives to determine the relationship between molecular structure and their inhibition efficiencies. The results of the quantum chemical calculations and experimental inhibition efficiency were subjected to correlation analysis and indicate that their inhibition effect is closely related to E{sub HOMO}, E{sub LUMO}, and dipole moment (mu).

  7. Pyroclastic Density Current Hazards in the Auckland Volcanic Field, New Zealand

    Science.gov (United States)

    Brand, B. D.; Gravley, D.; Clarke, A. B.; Bloomberg, S. H.

    2012-12-01

    The most dangerous phenomena associated with phreatomagmatic eruptions are dilute pyroclastic density currents (PDCs). These are turbulent, ground-hugging sediment gravity currents that travel radially away from the explosive center at up to 100 m/s. The Auckland Volcanic Field (AVF), New Zealand, consists of approximately 50 eruptive centers, at least 39 of which have had explosive phreatomagmatic behaviour. A primary concern for future AVF eruptions is the impact of dilute PDCs in and around the Auckland area. We combine field observations from the Maungataketake tuff ring, which has one of the best exposures of dilute PDC deposits in the AVF, with a quantitative model for flow of and sedimentation from a radially-spreading, steady-state, depth-averaged dilute PDC (modified from Bursik and Woods, 1996 Bull Volcanol 58:175-193). The model allows us to explore the depositional mechanisms, macroscale current dynamics, and potential impact on societal infrastructure of dilute PDCs from a future AVF eruption. The lower portion of the Maungataketake tuff ring pyroclastic deposits contains trunks, limbs and fragments of Podocarp trees (strength of the wood, we calculate that dynamic pressures (Pdyn) of 10-75 kPa are necessary to topple trees of this size and composition. Thus the two main criteria for model success based on the field evidence include (a) Pdyn must be >10 kPa nearer than 0.9 km to the vent, and 35 kPa can be expected within 3 km from source, ensuring complete destruction of the area; Pdyn > 15 kPa up to 5 km from source, resulting in heavy structural damage to most buildings and near destruction of weaker buildings; and Pdyn <10 kPa at ~6 km from source, resulting in severe damage to weaker structures at least up to this distance. This exercise illustrates our ability to combine field measurements with numerical techniques to explore controlling parameters of dilute PDC dynamics. These tools can be used to understand and estimate the damage potential and

  8. Investigation of electrodes under flow of a submicrosecond current pulse with linear density up to 3 MA/cm

    International Nuclear Information System (INIS)

    Branitskii, A. V.; Grabovskii, E. V.; Dzhangobegov, V. V.; Laukhin, Ya. N.; Mitrofanov, K. N.; Oleinik, G. M.; Sasorov, P. V.; Tkachenko, S. I.; Frolov, I. N.

    2016-01-01

    The states of current-carrying elements at the transmission of megaampere current into load are studied. It is determined that the expansion velocity of plasma generated at the outer surface of cylindrical tubes produced of stainless steel, at flowing through them of submicrosecond current pulses with linear density of 3 MA/cm is 5.5 km/s. The evolution of various modes of instability is analyzed.

  9. Preliminary scaling laws for plasma current, ion kinetic temperature, and plasma number density in the NASA Lewis bumpy torus plasma

    Science.gov (United States)

    Roth, J. R.

    1976-01-01

    Parametric variation of independent variables which may affect the characteristics of bumpy torus plasma have identified those which have a significant effect on the plasma current, ion kinetic temperature, and plasma number density, and those which do not. Empirical power law correlations of the plasma current, and the ion kinetic temperature and number density were obtained as functions of potential applied to the midplane electrode rings, the background neutral gas pressure, and the magnetic field strength. Additional parameters studied included the type of gas, the polarity of the midplane electrode rings, the mode of plasma operation, and the method of measuring the plasma number density. No significant departures from the scaling laws appear to occur at the highest ion kinetic temperatures or number densities obtained to date.

  10. Preliminary scaling laws for plasma current, ion kinetic temperature, and plasma number density in the NASA Lewis Bumpy Torus plasma

    Science.gov (United States)

    Roth, J. R.

    1976-01-01

    Parametric variation of independent variables which may affect the characteristics of the NASA Lewis Bumpy Torus plasma have identified those which have a significant effect on the plasma current, ion kinetic temperature, and plasma number density, and those which do not. Empirical power-law correlations of the plasma current, and the ion kinetic temperature and number density were obtained as functions of the potential applied to the midplane electrode rings, the background neutral gas pressure, and the magnetic field strength. Additional parameters studied include the type of gas, the polarity of the midplane electrode rings (and hence the direction of the radial electric field), the mode of plasma operation, and the method of measuring the plasma number density. No significant departures from the scaling laws appear to occur at the highest ion kinetic temperatures or number densities obtained to date.

  11. Early effect of NEURAPAS® balance on current source density (CSD of human EEG

    Directory of Open Access Journals (Sweden)

    Koch Klaus

    2011-08-01

    Full Text Available Abstract Psychiatric patients often suffer from stress, anxiety and depression. Various plant extracts are known to fight stress (valerian, anxiety (passion flower or depression (St. John's wort. NEURAPAS® balance is a mixture of these three extracts and has been designed to cover this complex of psychiatric conditions. The study was initiated to quantitatively assess the effect of this combination on brain electric activity. Method Quantitative electroencephalogram (EEG current source density (CSD recording from 16 healthy male and female human volunteers (average age 49 years was used in a randomized, placebo-controlled cross over study. Recordings were performed 0. 5, 1. 5, 3 and 4 hours after administration of the preparations under the conditions of 6 min eyes open and 5 min d2 concentration test, mathematical calculation test and memory test, respectively. All variables (electric power within 6 frequency ranges at 17 electrode positions were fed into a linear discriminant analysis (eyes open condition. In the presence of mental load these variables were used to construct brain maps of frequency changes. Results Under the condition of mental load, centro-parietal spectral power remained statistically significantly lower within alpha1, alpha2 and beta1 frequencies in the presence of verum in comparison to placebo. Discriminant analysis revealed a difference to placebo 3 and 4 hours after intake of 6 tablets of NEURAPAS® balance. Data location within the polydimensional space was projected into the area of the effects of sedative and anti-depressive reference drugs tested earlier under identical conditions. Results appeared closer to the effects of fluoxetine than to St. John's wort. Conclusions Analysis of the neurophysiological changes following the intake of NEURAPAS® balance revealed a similarity of frequency changes to those of calming and anti-depressive drugs on the EEG without impairment of cognition. Trial registration Clinical

  12. Geomagnetic paleointensity in historical pyroclastic density currents: Testing the effects of emplacement temperature and postemplacement alteration

    Science.gov (United States)

    Bowles, Julie A.; Gee, Jeffrey S.; Jackson, Mike J.; Avery, Margaret S.

    2015-10-01

    Thellier-type paleointensity experiments were conducted on welded ash matrix or pumice from the 1912 Novarupta (NV) and 1980 Mt. St. Helens (MSH) pyroclastic density currents (PDCs) with the intention of evaluating their suitability for geomagnetic paleointensity studies. PDCs are common worldwide, but can have complicated thermal and alteration histories. We attempt to address the role that emplacement temperature and postemplacement hydrothermal alteration may play in nonideal paleointensity behavior of PDCs. Results demonstrate two types of nonideal behavior: unstable remanence in multidomain (MD) titanomagnetite, and nonideal behavior linked to fumarolic and vapor phase alteration. Emplacement temperature indirectly influences MSH results by controlling the fraction of homogenous MD versus oxyexsolved pseudo-single domain titanomagnetite. NV samples are more directly influenced by vapor phase alteration. The majority of NV samples show distinct two-slope behavior in the natural remanent magnetization—partial thermal remanent magnetization plots. We interpret this to arise from a (thermo)chemical remanent magnetization associated with vapor phase alteration, and samples with high water content (>0.75% loss on ignition) generate paleointensities that deviate most strongly from the true value. We find that PDCs can be productively used for paleointensity, but that—as with all paleointensity studies—care should be taken in identifying potential postemplacement alteration below the Curie temperature, and that large, welded flows may be more alteration-prone. One advantage in using PDCs is that they typically have greater areal (spatial) exposure than a basalt flow, allowing for more extensive sampling and better assessment of errors and uncertainty.

  13. The effect of aging on the critical current density in superconducting Nb-Ti-Zr alloys

    International Nuclear Information System (INIS)

    Ishida, Fumihiko; Doi, Toshio

    1979-01-01

    The effect of aging temperature, cold-reduction prior to aging, O 2 content and composition on the variation in the critical current density, J sub(c), by isothermal aging was investigated in heavily cold-worked Nb-Ti-Zr alloys on the Nb-Ti side. The results are summarized as follows: (1) When these alloys are aged isothermally at temperatures from 350 to 500 0 C, J sub(c) increases initially, reaches a maximum value and then decreases. Increase in J sub(c) of three orders of magnitude is possible as a result of aging. (2) The maximum value of J sub(c) on the isothermal aging curve becomes higher at a lower aging temperature, at a less cold-reduction prior to aging or with a higher O 2 content. (3) The J sub(c) of aged alloy becomes a maximum in composition containing 35 at%Nb, 60 to 65 at%Ti and less than 5 at%Zr. (4) The maximum value of J sub(c) was obtained for Nb-60.0 at%Ti-5.0 at%Zr alloy containing 1200 wt ppm O 2 , aged at 350 0 C for 330 h after 98.44% cold-reduction. The values of J sub(c) at 4.2 K were 2.4 x 10 9 A/m 2 at 5.0 T, 1.1 x 10 9 A/m 2 at 7.0 T and 3.0 x 10 8 A/m 2 at 9.0 T, respectively. The upper critical field of this specimen was 11.3 T at 4.2 K and its critical temperature was 8.6 K. (author)

  14. Pipe Lines – External Corrosion

    Directory of Open Access Journals (Sweden)

    Dan Babor

    2008-01-01

    Full Text Available Two areas of corrosion occur in pipe lines: corrosion from the medium carried inside the pipes; corrosion attack upon the outside of the pipes (underground corrosion. Electrolytic processes are also involved in underground corrosion. Here the moisture content of the soil acts as an electrolyte, and the ions required to conduct the current are supplied by water-soluble salts (chlorides, sulfates, etc. present in the soil. The nature and amount of these soluble materials can vary within a wide range, which is seen from the varying electrical conductivity and pH (varies between 3 and 10. Therefore the characteristics of a soil will be an important factor in under-ground corrosion.

  15. Calculations on the current density and the voltage-current relation under a.c. conditions of filaments

    NARCIS (Netherlands)

    Hartmann, R.A.; Dijkstra, D.; van Beckum, F.P.H.; van de Klundert, L.J.M.

    1989-01-01

    Technical applications of multifilamentary wires indicate that filaments are used in complex magnetic fields (a combination of non-parallel a.c./d.c. transverse and rotating fields) carrying an a.c./d.c. transport current of various frequency. Furthermore, due to technical manufacturing processes

  16. Corrosion resistant metallic glasses for biosensing applications

    Science.gov (United States)

    Sagasti, Ariane; Lopes, Ana Catarina; Lasheras, Andoni; Palomares, Verónica; Carrizo, Javier; Gutierrez, Jon; Barandiaran, J. Manuel

    2018-04-01

    We report the fabrication by melt spinning, the magnetic and magnetoelastic characterization and corrosion behaviour study (by potentiodynamic methods) of an Fe-based, Fe-Ni-Cr-Si-B metallic glass to be used as resonant platform for biological and chemical detection purposes. The same study has been performed in Fe-Co-Si-B (with excellent magnetoelastic properties) and Fe-Ni-B (with good corrosion properties due to the substitution of Co by Ni) composition amorphous alloys. The well-known, commercial metallic glass with high corrosion resistance Metglas 2826MB®(Fe40Ni38Mo4B18), widely used for such biological and chemical detection purposes, has been also fully characterized and used as reference. For our Fe-Ni-Cr-Si-B alloy, we have measured values of magnetization (1.22 T), magnetostriction (11.5 ppm) and ΔE effect (6.8 %) values, as well as corrosion potential (-0.25 V), current density (2.54 A/m2), and polarization resistance (56.22 Ω.cm2) that make this composition very promising for the desired biosensing applications. The obtained parameters from our exhaustive characterization are compared with the values obtained for the other different composition metallic glasses and discussed in terms of Ni and Cr content.

  17. Corrosion Engineering.

    Science.gov (United States)

    White, Charles V.

    A description is provided for a Corrosion and Corrosion Control course offered in the Continuing Engineering Education Program at the General Motors Institute (GMI). GMI is a small cooperative engineering school of approximately 2,000 students who alternate between six-week periods of academic study and six weeks of related work experience in…

  18. On the toroidal current density flowing across a poloidal-magnetic-field null in an axisymmetric plasma

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, Paulo; Bizarro, Joao P. S. [Associacao Euratom-IST, Instituto de Plasmas e Fusao Nuclear, Instituto Superior Tecnico, Universidade Tecnica de Lisboa, 1049-001 Lisboa (Portugal)

    2013-04-15

    The axisymmetry condition and two of Maxwell's equations are used to show that, in general, there are no nested magnetic surfaces around a poloidal-magnetic-field null for a sufficiently small value of the toroidal current density flowing there. Hence, the toroidal current density at the axis of a magnetic configuration with extreme shear reversal cannot continuously approach zero unless nested surfaces are first broken or particular values are assigned to boundary conditions and other plasma parameters. The threshold of the toroidal current-density at which the topology changes is shown to be set by such parameters, and some examples of the predicted topology transition are presented using analytical solutions of the Grad-Shafranov equation.

  19. Structural and phase transformations in zinc and brass wires under heating with high-density current pulse

    Energy Technology Data Exchange (ETDEWEB)

    Pervikov, A. V. [Laboratory of Physical Chemistry of Ultrafine Materials, Institute of Strength Physics and Materials Science, 2/4, pr. Akademicheskii, 634021 Tomsk, Russia and Department of High Voltage Electrophysics and High Current Electronics, Tomsk Polytechnic University, 30 Lenin Avenue, 634050 Tomsk (Russian Federation)

    2016-06-15

    The work is focused on revealing the mechanism of structure and phase transformations in the metal wires under heating with a high-density current pulse (the electric explosion of wires, EEWs). It has been demonstrated on the example of brass and zinc wires that the transition of a current pulse with the density of j ≈ 3.3 × 10{sup 7} A/cm{sup 2} results in homogeneous heating of the crystalline structure of the metal/alloy. It has been determined that under heating with a pulse of high-density current pulse, the electric resistance of the liquid phases of zinc and brass decreases as the temperature increases. The results obtained allow for a conclusion that the presence of the particles of the condensed phase in the expanding products of EEW is the result of overheating instabilities in the liquid metal.

  20. Optimization of a ribbon diode with magnetic insulation for increasing the current density in a high-current relativistic electron beam

    Science.gov (United States)

    Astrelin, V. T.; Arzhannikov, A. V.; Burdakov, A. V.; Sinitskii, S. L.; Stepanov, V. D.

    2009-05-01

    The geometry of the ribbon diode of the U-2 accelerator is optimized to increase both the current density and the total current of the relativistic electron beam for its subsequent injection into the plasma of a multimirror GOL-3 trap. Beam simulation in the diode was performed using the POISSON-2 applied software modified on the basis of the results obtained using the theory of a planar diode in an inclined magnetic field. As a result of the optimization, the diode geometry and the magnetic field configuration were found that should provide a factor of 1.5-2 increase in the current density in experiments with a small angular divergence of electron velocities.

  1. Separation Test Method for Investigation of Current Density Effects on Bond Wires of SiC Power MOSFET Modules

    DEFF Research Database (Denmark)

    Luo, Haoze; Iannuzzo, Francesco; Blaabjerg, Frede

    2017-01-01

    In this paper, a separation test method for eliminating the effects of different current densities on the bond wires is proposed. The separation test method makes it possible to study the effect of different current density on the fatigue damage of bond wires without changing the temperature swing...... and average temperature during the test. By analyzing the output characteristics of the linear region of MOSFET, the constraint relations among the gate voltage, on-state voltage drop and junction temperature are revealed in this paper. The one-to-one correspondence between gate voltage and conduction power...

  2. Corrosion measurements on apt prototypic materials in the Lansce high-power proton beam and applicability to other systems

    International Nuclear Information System (INIS)

    Lillard, R.S.; Gac, F.D.; James, M.R.; Maloy, S.A.; Paciotti, M.A.; Waters, L.S.; Willcutt, G.J.; Chandler, G.T.; Ferguson, P.D.

    2003-01-01

    The corrosion rates of several corrosion resistant materials behave in a similar manner even under the intense radiation of the LANSCE high-power beam. A second observation was made, showing that the corrosion rates saturated under high instantaneous radiation intensity in corrosion experiments conducted for the accelerator production of tritium (APT) programme. The LANSCE H + beam is not prototypic of the proposed APT production plant in several respects. The instantaneous proton flux in the APT production plant beam is about 10 times that of the LANSCE beam. The small transverse APT beam spot is rastered to spread the power density over the area of the target, and as the beam rasters, it creates a pulsed character to the beam at a specific location. In order to develop correlations that would enable extrapolation of the corrosion data to the proposed APT production plant, the experimental programme included measurements over a range of average beam currents, measurements at high and low instantaneous beam current, and measurements at various combinations of pulse width and repetition rate. The correlations that were developed are based on an approximately linear dependence of corrosion rate on average beam current (average radiation intensity) and the saturation effect observed at high instantaneous radiation intensity. For a given transverse beam profile and for the same average beam current, the correlations predict the highest corrosion rate in a do beam and the lowest corrosion rate in the lowest duty cycle beams. In the case of the APT extrapolation, the predicted corrosion rates were a factor of 5 lower than for a do beam depositing the same average power density. The measured corrosion rates and the formulated extrapolations are applicable to water-cooled targets and components in proton beams. (authors)

  3. Corrosion problems and solutions in oil refining and petrochemical industry

    CERN Document Server

    Groysman, Alec

    2017-01-01

    This book addresses corrosion problems and their solutions at facilities in the oil refining and petrochemical industry, including cooling water and boiler feed water units. Further, it describes and analyzes corrosion control actions, corrosion monitoring, and corrosion management. Corrosion problems are a perennial issue in the oil refining and petrochemical industry, as they lead to a deterioration of the functional properties of metallic equipment and harm the environment – both of which need to be protected for the sake of current and future generations. Accordingly, this book examines and analyzes typical and atypical corrosion failure cases and their prevention at refineries and petrochemical facilities, including problems with: pipelines, tanks, furnaces, distillation columns, absorbers, heat exchangers, and pumps. In addition, it describes naphthenic acid corrosion, stress corrosion cracking, hydrogen damages, sulfidic corrosion, microbiologically induced corrosion, erosion-corrosion, and corrosion...

  4. Part I. Corrosion studies of continuous alumina fiber reinforced aluminum-matrix composites. Part II. Galvanic corrosion between continuous alumina fiber reinforced aluminum-matrix composites and 4340 steel

    Science.gov (United States)

    Zhu, Jun

    Part I. The corrosion performance of continuous alumina fiber reinforced aluminum-matrix composites (CF-AMCs) was investigated in both the laboratory and field environments by comparing them with their respective monolithic matrix alloys, i.e., pure Al, A1-2wt%Cu T6, and Al 6061 T6. The corrosion initiation sites were identified by monitoring the changes in the surface morphology. Corrosion current densities and pH profiles at localized corrosion sites were measured using the scanning-vibrating electrode technique and the scanning ion-selective electrode technique, respectively. The corrosion damage of the materials immersed in various electrolytes, as well as those exposed in a humidity chamber and outdoor environments, was evaluated. Potentiodynamic polarization behavior was also studied. The corrosion initiation for the composites in 3.15 wt% NaCl occurred primarily around the Fe-rich intermetallic particles, which preferentially existed around the fiber/matrix interface on the composites. The corrosion initiation sites were also caused by physical damage (e.g., localized deformation) to the composite surface. At localized corrosion sites, the buildup of acidity was enhanced by the formation of micro-crevices resulting from fibers left in relief as the matrix corroded. The composites that were tested in exposure experiments exhibited higher corrosion rates than their monolithic alloys. The composites and their monolithic alloys were subjected to pitting corrosion when anodically polarized in the 3.15 wt% NaCl, while they passivated when anodically polarized in 0.5 M Na2SO4. The experimental results indicated that the composites exhibited inferior corrosion resistance compared to their monolithic matrix alloys. Part II. Galvanic corrosion studies were conducted on CF-AMCs coupled to 4340 steel since CF-AMCs have low density and excellent mechanical properties and are being considered as potential jacketing materials for reinforcing steel gun barrels. Coupled and

  5. Influence of Electrolyte Modulus on the Local Current Density at a Dendrite Tip on a Lithium Metal Electrode

    Energy Technology Data Exchange (ETDEWEB)

    Harry, KJ; Higa, K; Srinivasan, V; Balsara, NP

    2016-08-10

    Understanding and controlling the electrochemical deposition of lithium is imperative for the safe use of rechargeable batteries with a lithium metal anode. Solid block copolymer electrolyte membranes are known to enhance the stability of lithium metal anodes by mechanically suppressing the formation of lithium protrusions during battery charging. Time-resolved hard X-ray microtomography was used to monitor the internal structure of a symmetric lithium-polymer cell during galvanostatic polarization. The microtomography images were used to determine the local rate of lithium deposition, i.e. local current density, in the vicinity of a lithium globule growing through the electrolyte. Measurements of electrolyte displacement enabled estimation of local stresses in the electrolyte. At early times, the current density was maximized at the globule tip, as expected from simple current distribution arguments. At later times, the current density was maximized at the globule perimeter. We show that this phenomenon is related to the local stress fields that arise as the electrolyte is deformed. The local current density, normalized for the radius of curvature, decreases with increasing compressive stresses at the lithium-polymer interface. To our knowledge, our study provides the first direct measurement showing the influence of local mechanical stresses on the deposition kinetics at lithium metal electrodes.

  6. Critical current densities amd pinning mechanisms of high-Tc films on single crystalline and technologically relevant substrates. Final report

    International Nuclear Information System (INIS)

    Adrian, H.

    1995-12-01

    The report deals with six project tasks: (1) Effects of impurity additions at atomic level on the pinning behaviour and the critical current densities, examined in epitactic YBA 2 (Cu 1-x Ni x ) 3 O 7 films. It could be proven that the Ni atoms increase the activation energy for flux movement and the critical current density in a concentration range of 0 2 Sr 2 Ca n-1 Cu n O 2n+4+δ films (n = 2 and 3) with good crystalline properties, high critical currents, and high current densities were prepared. Thin YBa 2 Cu 3 O 7 films of high quality could be grown on saphire substrates, both by the MO-CVD process and by MBE. The aim of depositing biaxially textured YBa 2 Cu 3 O 7 films with high critical current densities on polycrystalline, metallic substrates was achieved by the IBAD process combined with MBE. The buffer layer was YSZ. Heterostructures of the layer sequence YBa 2 Cu 3 O 7 /CeO 2 /Y 0.3 Pr 0.7 Ba 2 Cu 3 O 7 /YBa 2 Cu 3 O 7 and YBa 2 Cu 3 O 7 /CeO 2 /Au were prepared by laser ablation and sputtering processes, in order to examine Josephson ramp contacts and superconducting field-effect transistors. (orig./MM) [de

  7. The Effect of Friction Stir Welding on Corrosion Behavior of Ti-6Al-4V

    Science.gov (United States)

    Nasresfahani, Ali Reza; Soltanipur, Abdol Reza; Farmanesh, Khosro; Ghasemi, Ali

    2017-09-01

    Fusion welding can deteriorate corrosion behavior of Ti-6Al-4V alloy. However, the use of friction stir welding leads to a more appropriate corrosion resistance. In this study, the corrosion resistance of welded zones of Ti-6Al-4V alloy using friction stir welding technique is evaluated. For these purposes, the study of structural characteristics using SEM and FESEM equipped with EDS micro-analyses was conducted. Micro-hardness test was also employed to estimate the hardness of welded zones. Corrosion behavior was investigated by a potentiostat instrument. SEM micrographs, EDS and XRD analyses confirmed non-uniformity of chemical composition within the welded zones. The results reveal that the stir zone contains typical alpha and prior beta phases. Nevertheless, thermomechanical zone included equiaxed and bimodal lamellae structure. Furthermore, the presence of different types of phases and microstructure in the thermomechanical zone led to reduced corrosion resistance. The corresponding values of corrosion current density in the stir zone, thermomechanical zone and base metal were 0.048, 0.55 and 0.032 µA, respectively. Corresponding corrosion potential for these zones was estimated as -207, -110 and -157 mV. Evidently, the results show that corrosion resistance of thermomechanical zone is less than that of the stir zone and both zones have lower value than the base metal.

  8. Dependence of corrosion properties of AISI 304L stainless steel on the austenite grain size

    Energy Technology Data Exchange (ETDEWEB)

    Sabooni, Soheil; Rashtchi, Hamed; Eslami, Abdoulmajid; Karimzadeh, Fathallah; Enayati, Mohammad Hossein; Raeissi, Keyvan; Imani, Reihane Faghih [Isfahan Univ. of Technology, Isfahan (Iran, Islamic Republic of). Dept. of Materials Engineering; Ngan, Alfonso Hing Wan [The Univ. of Hong Kong (China). Dept. of Mechanical Engineering

    2017-07-15

    The corrosion resistance of austenitic stainless steels is known to be hampered by the loss of chromium available for passive surface layer formation as a result of chromium carbide precipitation at austenite grain boundaries during annealing treatments. Although high-temperature annealing can promote carbide dissolution leading to better corrosion resistance, grain coarsening also results, which would lead to poorer mechanical properties. Processing methods to achieve both good corrosion resistance and mechanical properties are thus highly desirable for austenitic stainless steels. In the present study, we show that the corrosion resistance of AISI 304L stainless steel can be improved by grain refinement into the ultrafine-grained regime. Specifically, samples with different austenite grain sizes in the range of 0.65-12 μm were studied by potentiodynamic polarization and electrochemical impedance spectroscopy tests in a 3.5 wt.% NaCl solution. All samples showed a typical passive behavior with similar corrosion potential, but the corrosion current density decreased significantly with decreasing grain size. The results show that the sample with the finest grain size had the best corrosion resistance due to a higher resistance of the passive layer to pitting attacks. This study indicates that grain refinement which improves mechanical properties can also significantly improve the corrosion resistance of AISI 304L stainless steel.

  9. The Merapi 2010 eruption: An interdisciplinary impact assessment methodology for studying pyroclastic density current dynamics

    Science.gov (United States)

    Jenkins, S.; Komorowski, J.-C.; Baxter, P. J.; Spence, R.; Picquout, A.; Lavigne, F.; Surono

    2013-07-01

    The large explosive eruption of Merapi volcano, Indonesia, in 2010 presented a key, and rare, opportunity to study the impacts of a major explosive eruption in a densely populated area. Pyroclastic density currents (PDCs) produced throughout the 2010 eruption were unusually destructive, causing near complete devastation across a 22 km2 swath of the densely populated southern flanks and casualties to the end of their runout at 15.5 km from the volcano. The majority (> 120) of the more than 200 fatalities occurred more than 12 km from the volcano, where many people were caught in PDCs as they were evacuating. The 2010 eruption (VEI 4) exhibited a range of PDC behaviour in a complex multi-stage event that marked a change in eruption behaviour at Merapi, being the first eruption of this magnitude and style since 1872. This shift in style may mark a change in regime, and so understanding the potential impact of such large explosive eruptions is essential for future risk-assessment at Merapi. We describe a new impact assessment methodology that allowed us to collect important empirical geological, damage and casualty information and reconstruct impact dynamics associated with the PDCs. In contrast to previous PDC impact studies, we combined remote, field, laboratory and GIS assessments and were able to enter the affected areas safely and before their disturbance by rains or human activity. By integrating the results of our geological, damage and medical studies, we could reconstruct the spatial and temporal dynamics of the PDCs and their main hazard characteristics. Our interdisciplinary methods and preliminary findings are discussed here. In the areas damaged by PDCs, we used empirical damage data and calculations of material and structural resistance to lateral force to estimate approximate dynamic pressures. Dynamic pressures associated with the 5 November paroxysm exceeded 15 kPa more than 6 km from source and rapidly attenuated over a distance of less than 1 km at

  10. Functional interconnections between CA3 and the dentate gyrus revealed by current source density analysis.

    Science.gov (United States)

    Wu, K; Canning, K J; Leung, L S

    1998-01-01

    The physiological interactions between the dentate gyrus (DG) and CA3 were studied in urethane-anesthetized rats by using field potential recording and current source density (CSD) analysis. Stimulation of CA3b resulted in a short-latency (sink) at the middle molecular layer (MML) was observed at 3-ms latency, possibly mediated by the backfiring of perforant path fibers that projected to both DG and CA3. CA3 stimulation also resulted in a sink at the dendritic layers of CA3c, which was likely mediated by excitatory CA3 recurrent collaterals. It was inferred that the DG was excited at the inner molecular layer (IML) after stimulation near the CA3b/CA3c border. This IML excitation (sink) probably resulted from orthodromic CA3 or hilar projections to the IML and not from mossy fiber backfiring. The IML and the CA3c dendritic sinks were blocked by an intracerebroventricular injection of a non-N-methyl-D-aspartate receptor antagonist, 6-cyano-7-nitroquinoxaline-2, 3-dione, but not by a gamma-aminobutyric acid type A (GABA(A)) receptor antagonist, bicuculline. CA3b stimulation evoked population spike bursts (3-7-ms latency) in both DG and CA3c when GABA(A) inhibition was suppressed by bicuculline, thus confirming that the excitatory afferents project from CA3b to DG and CA3c. A CA3 conditioning stimulus pulse given 30-200 ms before a perforant-path test pulse increased the amplitude of the perforant-path-evoked DG population spike (as compared with the test response without conditioning). After a moderate-intensity stimulation of CA3, a late (<20-ms latency) excitation of the MML of the DG was found. The late DG excitation was blocked by procaine injection at the medial perforant path, suggesting its origin from the medial entorhinal cortex. In conclusion, rich interactions between CA3 and other hippocampal structures were studied quantitatively by CSD analysis in vivo. We infer that CA3 provides an early excitatory feedback path to DG through recurrent collaterals or

  11. Ultrasound Current Source Density Imaging in live rabbit hearts using clinical intracardiac catheter

    Science.gov (United States)

    Li, Qian

    Ultrasound Current Source Density Imaging (UCSDI) is a noninvasive modality for mapping electrical activities in the body (brain and heart) in 4-dimensions (space + time). Conventional cardiac mapping technologies for guiding the radiofrequency ablation procedure for treatment of cardiac arrhythmias have certain limitations. UCSDI can potentially overcome these limitations and enhance the electrophysiology mapping of the heart. UCSDI exploits the acoustoelectric (AE) effect, an interaction between ultrasound pressure and electrical resistivity. When an ultrasound beam intersects a current path in a material, the local resistivity of the material is modulated by the ultrasonic pressure, and a change in voltage signal can be detected based on Ohm's Law. The degree of modulation is determined by the AE interaction constant K. K is a fundamental property of any type of material, and directly affects the amplitude of the AE signal detected in UCSDI. UCSDI requires detecting a small AE signal associated with electrocardiogram. So sensitivity becomes a major challenge for transferring UCSDI to the clinic. This dissertation will determine the limits of sensitivity and resolution for UCSDI, balancing the tradeoff between them by finding the optimal parameters for electrical cardiac mapping, and finally test the optimized system in a realistic setting. This work begins by describing a technique for measuring K, the AE interaction constant, in ionic solution and biological tissue, and reporting the value of K in excised rabbit cardiac tissue for the first time. K was found to be strongly dependent on concentration for the divalent salt CuSO4, but not for the monovalent salt NaCl, consistent with their different chemical properties. In the rabbit heart tissue, K was determined to be 0.041 +/- 0.012 %/MPa, similar to the measurement of K in physiologic saline: 0.034 +/- 0.003 %/MPa. Next, this dissertation investigates the sensitivity limit of UCSDI by quantifying the relation

  12. Effects of copper and titanium on the corrosion behavior of newly fabricated nanocrystalline aluminum in natural seawater

    Science.gov (United States)

    Sherif, El-Sayed M.; Ammar, Hany Rizk; Khalil, Khalil Abdelrazek

    2014-05-01

    Fabrication of a newly nanocrystalline Al and two of its alloys, namely Al-10%Cu; and Al-10%Cu-5%Ti has been carried out using mechanical alloying (MA) technique. The corrosion behavior of these materials in aerated stagnant Arabian Gulf seawater (AGSW) at room temperature has been reported. Cyclic potentiodynamic polarization (CPP), chronoamperometric current-time (CCT) and electrochemical impedance spectroscopy (EIS) measurements along with scanning electron microscopy (SEM) and X-ray energy dispersive (EDX) investigations were employed to report the corrosion behavior of the fabricated materials. All results indicated that Al suffers both uniform and localized corrosion in the AGSW test solution. The presence of 10%Cu decreases the corrosion current density, the anodic and cathodic currents and corrosion rate and increases the corrosion resistance of Al. The addition of 5%Ti to the Al-10%Cu alloy produced further decreases in the corrosion parameters. Measurements together confirmed that the corrosion of the fabricated materials in AGSW decreases in the order Al > Al-10%Cu > Al-10%Cu-5%Ti.

  13. Negative-ion current density dependence of the surface potential of insulated electrode during negative-ion implantation

    International Nuclear Information System (INIS)

    Tsuji, Hiroshi; Okayama, Yoshio; Toyota, Yoshitaka; Gotoh, Yasuhito; Ishikawa, Junzo; Sakai, Shigeki; Tanjyo, Masayasu; Matsuda, Kouji.

    1994-01-01

    Positive ion implantation has been utilized as the method of impurity injection in ultra-LSI production, but the problem of substrate charging cannot be resolved by conventional charge compensation method. It was forecast that by negative ion implantation, this charging problem can be resolved. Recently the experiment on the negative ion implantation into insulated electrodes was carried out, and the effect of negative ion implantation to this problem was proved. However, the dependence of charged potential on the increase of negative ion current at the time of negative ion implantation is a serious problem in large current negative ion implantation hereafter. The charged potential of insulated conductor substrates was measured by the negative ion implantation using the current up to several mA/cm 2 . The experimental method is explained. Medium current density and high current density negative ion implantation and charged potential are reported. Accordingly in negative ion implantation, if current density is optimized, the negative ion implantation without charging can be realized. (K.I.)

  14. Influences of the current density on the performances of the chrome-plated layer in deterministic electroplating repair

    Science.gov (United States)

    Xia, H.; Shen, X. M.; Yang, X. C.; Xiong, Y.; Jiang, G. L.

    2018-01-01

    Deterministic electroplating repair is a novel method for rapidly repairing the attrited parts. By the qualitative contrast and quantitative comparison, influences of the current density on performances of the chrome-plated layer were concluded in this study. The chrome-plated layers were fabricated under different current densities when the other parameters were kept constant. Hardnesses, thicknesses and components, surface morphologies and roughnesses, and wearability of the chrome-plated layers were detected by the Vickers hardness tester, scanning electron microscope / energy dispersive X-ray detector, digital microscope in the 3D imaging mode, and the ball-milling instrument with profilograph, respectively. In order to scientifically evaluate each factor, the experimental data was normalized. A comprehensive evaluation model was founded to quantitative analyse influence of the current density based on analytic hierarchy process method and the weighted evaluation method. The calculated comprehensive evaluation indexes corresponding to current density of 40A/dm2, 45A/dm2, 50A/dm2, 55A/dm2, 60A/dm2, and 65A/dm2 were 0.2246, 0.4850, 0.4799, 0.4922, 0.8672, and 0.1381, respectively. Experimental results indicate that final optimal option was 60A/dm2, and the priority orders were 60A/dm2, 55A/dm2, 45A/dm2, 50A/dm2, 40A/dm2, and 65A/dm2.

  15. Effect of preionization, fluorine concentration, and current density on the discharge uniformity in F2 excimer laser gas mixtures

    NARCIS (Netherlands)

    Mathew, D.; Bastiaens, Hubertus M.J.; Boller, Klaus J.; Peters, P.J.M.

    2007-01-01

    The discharge homogeneity in F2-based excimer laser gas mixtures and its dependence on various key parameters, such as the degree of preionization, preionization delay time, F2 concentration and current density, is investigated in a small x-ray preionized discharge chamber. The spatial and temporal

  16. The role of relativity in the optical response of gold within the time-dependent current-density-functional theory

    NARCIS (Netherlands)

    Romaniello, P; de Boeij, PL

    2005-01-01

    We included relativistic effects in the formulation of the time-dependent current-density-functional theory for the calculation of linear response properties of metals [P. Romaniello and P. L. de Boeij, Phys. Rev. B (to be published)]. We treat the dominant scalar-relativistic effects using the

  17. Charge and current density profiles of a degenerate magnetized free-electron gas near a hard wall

    NARCIS (Netherlands)

    Kettenis, M.M.; Suttorp, L.G.

    1998-01-01

    The charge and current densities of a completely degenerate free-electron gas in a uniform magnetic field are found to have a damped oscillatory spatial dependence near a wall that is parallel to the magnetic field. For large distances from the wall the behaviour of the associated profile functions

  18. Experimental investigation of the effect of titanium dioxide and barium titanate additives on DC transient currents in low density polyethylene

    DEFF Research Database (Denmark)

    Khalil, M.S; Henk, Peter O; Henriksen, Mogens

    1988-01-01

    The effect of titanium dioxide as a semiconductive additive and barium titanate as a highly polar additive on the DC transient currents in low-density polyethylene is investigated. Experiments were made using thick specimens under a high electric field (>25×106 V/m) and a constant temperature of 40...

  19. Improved critical current densities of bulk MgB.sub.2./sub. using carbon-coated amorphous boron

    Czech Academy of Sciences Publication Activity Database

    Muralidhar, M.; Higuchi, M.; Jirsa, Miloš; Diko, P.; Kokal, I.; Murakami, M.

    2017-01-01

    Roč. 27, č. 4 (2017), s. 1-4, č. článku 6201104. ISSN 1051-8223 Institutional support: RVO:68378271 Keywords : carbon-encapsulated boron * critical current density * flux pinning * micro-structure Subject RIV: BM - Solid Matter Physics ; Magnetism OBOR OECD: Condensed matter physics (including formerly solid state physics, supercond.) Impact factor: 1.092, year: 2015

  20. Evaluation of a Magnetically-Filtered Faraday Probe for Measuring the ion Current Density Profile of a Hall Thruster

    National Research Council Canada - National Science Library

    Rovey, Joshua L; Walker, Micthell L; Gallimore, Alec D; Peterson, Peter Y

    2004-01-01

    .... In this study, a MFFP, boxed Faraday probe (BFP), and nude Faraday probe are used to measure the ion current density profile of a 5 kW Hall thruster operated over the range of 300-500 V and 5-10 mg...

  1. High Current, High Density Arc Plasma as a New Source for WiPAL

    Science.gov (United States)

    Waleffe, Roger; Endrizzi, Doug; Myers, Rachel; Wallace, John; Clark, Mike; Forest, Cary; WiPAL Team

    2016-10-01

    The Wisconsin Plasma Astrophysics Lab (WiPAL) has installed a new array of nineteen plasma sources (plasma guns) on its 3 m diameter, spherical vacuum vessel. Each gun is a cylindrical, molybdenum, washer-stabilized, arc plasma source. During discharge, the guns are maintained at 1.2 kA across 100 V for 10 ms by the gun power supply establishing a high density plasma. Each plasma source is fired independently allowing for adjustable plasma parameters, with densities varying between 1018 -1019 m-3 and electron temperatures of 5-15 eV. Measurements were characterized using a 16 tip Langmuir probe. The plasma source will be used as a background plasma for the magnetized coaxial plasma gun (MCPG), the Terrestrial Reconnection Experiment (TREX), and as the plasma source for a magnetic mirror experiment. Temperature, density, and confinement results will be presented. This work is supported by the DoE and the NSF.

  2. The corrosion behaviour of carbon steel in Portland cement

    International Nuclear Information System (INIS)

    Grauer, R.

    1988-01-01

    The production of hydrogen can cause problems in a repository for low- and intermediate-level waste. Since gas production is mainly due to the corrosion of carbon steel, it is important to have as reliable data as possible on the corrosion rate of steel in anaerobic cement. A review of the literature shows that the corrosion current densities lie in the range 0.01 to 0.1 μA/cm 2 (corresponding to corrosion rates between 0.1 and 1.2 μm/a). This implies hydrogen production rates between 0.022 and 0.22 mol/(m 2 .a). Corrosion rates of this order of magnitude are technically irrelevant, with the result that there is very little interest in determining them accurately. Furthermore, their determination entails problems of measurement technique. Given the current situation, it would appear somewhat risky to accept the lower value for hydrogen production as proven. Proposals are made for experiments which would reduce this element of uncertainty. (author) 10 figs., 35 refs

  3. [Study on the corrosion resistance of Cr ahoy in the artificial saliva with different pH value].

    Science.gov (United States)

    Su, Run-Gang; Li, Chun-Hua; Qian, Ye

    2010-02-01

    To study the effect on the corrosion resistance of Cr alloy in the artificial saliva with different pH value in vitro. Compared to Ti alloy, electrochemical technique was used to measure the electric potential of corrosion (E(corr)), current density of corrosion (I(corr)) Cr alloy in the artificial saliva with different pH value. The corrosion and corrosion resistance mechanism on Cr alloy in the artificial saliva with different pH value had been investigated by the EIS curves. The corrosion resistance of Co-Cr alloy was better than Ti alloy. The value of I(corr) was lower and the value of R(p) was larger than Ti alloy. The corrosion resistance of Ni-Cr alloy was worse than Ti alloy. The value of I(corr) was larger and the value of R(p) was lower than Ti alloy. The pH value in the artificial saliva was decreased, the I(corr) value of three types of alloy increased, the R(p) value of three types of alloy decreased. But the changes of Co-Cr alloy was smaller than that of Ti alloy or Ni-Cr alloy. The corrosion resistance of Co-Cr alloy was superior to that of Ni-Cr alloy and Ti alloy. In the acid artificial saliva, the corrosion resistance of three types of alloy descended evidently.

  4. Calculation of induced current densities and specific absorption rates (SAR) for pregnant women exposed to hand-held metal detectors

    Science.gov (United States)

    Kainz, Wolfgang; Chan, Dulciana D.; Casamento, Jon P.; Bassen, Howard I.

    2003-08-01

    The finite difference time domain (FDTD) method in combination with a well established frequency scaling method was used to calculate the internal fields and current densities induced in a simple model of a pregnant woman and her foetus, when exposed to hand-held metal detectors. The pregnant woman and foetus were modelled using a simple semi-heterogeneous model in 10 mm resolution, consisting of three different types of tissue. The model is based on the scanned shape of a pregnant woman in the 34th gestational week. Nine different representative models of hand-held metal detectors operating in the frequency range from 8 kHz to 2 MHz were evaluated. The metal detectors were placed directly on the abdomen of the computational model with a spacing of 1 cm. Both the induced current density and the specific absorption rate (SAR) are well below the recommended limits for exposure of the general public published in the ICNIRP Guidelines and the IEEE C95.1 Standard. The highest current density is 8.3 mA m-2 and the highest SAR is 26.5 µW kg-1. Compared to the limits for the induced current density recommended in the ICNIRP Guidelines, a minimum safety factor of 3 exists. Compared to the IEEE C95.1 Standard, a safety factor of 60 000 for the specific absorption rate was found. Based on the very low specific absorption rate and an induced current density below the recommended exposure limits, significant temperature rise or nerve stimulation in the pregnant woman or in the foetus can be excluded.

  5. Calculation of induced current densities and specific absorption rates (SAR) for pregnant women exposed to hand-held metal detectors

    International Nuclear Information System (INIS)

    Kainz, Wolfgang; Chan, Dulciana D; Casamento, Jon P; Bassen, Howard I

    2003-01-01

    The finite difference time domain (FDTD) method in combination with a well established frequency scaling method was used to calculate the internal fields and current densities induced in a simple model of a pregnant woman and her foetus, when exposed to hand-held metal detectors. The pregnant woman and foetus were modelled using a simple semi-heterogeneous model in 10 mm resolution, consisting of three different types of tissue. The model is based on the scanned shape of a pregnant woman in the 34th gestational week. Nine different representative models of hand-held metal detectors operating in the frequency range from 8 kHz to 2 MHz were evaluated. The metal detectors were placed directly on the abdomen of the computational model with a spacing of 1 cm. Both the induced current density and the specific absorption rate (SAR) are well below the recommended limits for exposure of the general public published in the ICNIRP Guidelines and the IEEE C95.1 Standard. The highest current density is 8.3 mA m -2 and the highest SAR is 26.5 μW kg -1 . Compared to the limits for the induced current density recommended in the ICNIRP Guidelines, a minimum safety factor of 3 exists. Compared to the IEEE C95.1 Standard, a safety factor of 60,000 for the specific absorption rate was found. Based on the very low specific absorption rate and an induced current density below the recommended exposure limits, significant temperature rise or nerve stimulation in the pregnant woman or in the foetus can be excluded

  6. Calculation of induced current densities and specific absorption rates (SAR) for pregnant women exposed to hand-held metal detectors

    Energy Technology Data Exchange (ETDEWEB)

    Kainz, Wolfgang; Chan, Dulciana D; Casamento, Jon P; Bassen, Howard I [Food and Drug Administration, Center for Devices and Radiological Health (CDRH), 12725 Twinbrook Parkway, Rockville, MD 20852 (United States)

    2003-08-07

    The finite difference time domain (FDTD) method in combination with a well established frequency scaling method was used to calculate the internal fields and current densities induced in a simple model of a pregnant woman and her foetus, when exposed to hand-held metal detectors. The pregnant woman and foetus were modelled using a simple semi-heterogeneous model in 10 mm resolution, consisting of three different types of tissue. The model is based on the scanned shape of a pregnant woman in the 34th gestational week. Nine different representative models of hand-held metal detectors operating in the frequency range from 8 kHz to 2 MHz were evaluated. The metal detectors were placed directly on the abdomen of the computational model with a spacing of 1 cm. Both the induced current density and the specific absorption rate (SAR) are well below the recommended limits for exposure of the general public published in the ICNIRP Guidelines and the IEEE C95.1 Standard. The highest current density is 8.3 mA m{sup -2} and the highest SAR is 26.5 {mu}W kg{sup -1}. Compared to the limits for the induced current density recommended in the ICNIRP Guidelines, a minimum safety factor of 3 exists. Compared to the IEEE C95.1 Standard, a safety factor of 60,000 for the specific absorption rate was found. Based on the very low specific absorption rate and an induced current density below the recommended exposure limits, significant temperature rise or nerve stimulation in the pregnant woman or in the foetus can be excluded.

  7. Review of the critical current densities and magnetic irreversibilities in high T_c superconductors

    Science.gov (United States)

    Senoussi, S.

    1992-07-01

    This review article is concerned with critical current density (J) and magnetic irreversibilities in high-T_c superconductors (HTSC). The apparent J derived from different experimental techniques (transport, hysteresis cycle, ac-susceptibility) are compared. The influence of time (relaxation effects) as well as the macroscopic size of the sample on the criteria defining J are discussed. The dependences of the critical current on grain boundaries (“weaks-links”), texturing and other physical and chemical defects are examined in detail. The role of self fields is clarified. The critical current is strongly influenced by the anisotropy of the layered structure practically whatever the experimental conditions. Intrinsic pinning is lowered by defects. Demagnetizing effects and surface pinnings are reviewed. The usual critical state and flux creep models are recalled emphasizing the physical aspects most specific to HTSC. A theoretical model which takes into account the equilibrium magnetization and sample granularity is developed. It reproduces most of the characteristic features of both the hysteresis cycle and ac-susceptibility. A number of new formulae are introduced. They generalize the Bean model and show how to correct for the dimensions of the grains (granular materials), the macroscopic radius of the sample, anisotropy and demagnetization effects in certain situations. Several limits beyond which the usual critical state breaks down are discussed: (1) the quasi elastic limit where the variable field is too weak to depin the vortices, (2) H≈ H_C1 so that the interaction between vortex lines is exponentially weak and (3) T and H close to the “irreversibility line” where the influence of viscous forces are strong. (4) Hgg H_C1 so that J is governed by collective pinning. Ce papier de revue est consacré aux courant critiques (J) et aux irréversibilités magnétiques dans les nouveaux matériaux supraconducteurs (HTSC). Nous y comparons les densités des

  8. Cooling of Water in a Flask: Convection Currents in a Fluid with a Density Maximum

    Science.gov (United States)

    Velasco, S.; White, J. A.; Roman, F. L.

    2010-01-01

    The effect of density inversion on the convective flow of water in a spherical glass flask cooled with the help of an ice-water bath is shown. The experiment was carried out by temperature measurements (cooling curves) taken at three different heights along the vertical diameter of the flask. Flows inside the flask are visualized by seeding the…

  9. ac loss and dc critical current densities of Nb3Sn tapes by the solid state diffusion process

    International Nuclear Information System (INIS)

    Suenaga, M.; Klamut, C.; Bussiere, J.F.

    1976-01-01

    The effects of metallurgical processing on 60 Hz ac losses and dc critical currents in Nb 3 Sn tapes fabricated by the solid state diffusion technique were investigated. An addition of Al to the Cu--Sn alloy for the matrix resulted in large reduction in the ac losses of Nb 3 Sn tapes, but the highest linear critical current densities were observed in Nb 3 Sn tapes produced with a Nb-1 wt percent Zr core in a Cu-13 wt percent Sn matrix. Values of the losses and the critical currents in these tapes can meet the present requirements for the ac superconducting power cables

  10. Effect of Magnetic Flux Density and Applied Current on Temperature, Velocity and Entropy Generation Distributions in MHD Pumps

    Directory of Open Access Journals (Sweden)

    M. Kiyasatfar

    2011-01-01

    Full Text Available In the present study, simulation of steady state, incompressible and fully developed laminar flow has been conducted in a magneto hydrodynamic (MHD pump. The governing equations are solved numerically by finite-difference method. The effect of the magnetic flux density and current on the flow and temperature distributions in a MHD pump is investigated. The obtained results showed that controlling the flow and the temperature is possible through the controlling of the applied current and the magnetic flux. Furthermore, the effects of the magnetic flux density and current on entropy generation in MHD pump are considered. Our presented numerical results are in good agreement with the experimental data showed in literature.

  11. Microstructural and crystallographic imperfections of MgB2 superconducting wire and their correlation with the critical current density

    Science.gov (United States)

    Shahabuddin, Mohammed; Alzayed, Nasser S.; Oh, Sangjun; Choi, Seyong; Maeda, Minoru; Hata, Satoshi; Shimada, Yusuke; Hossain, Md Shahriar Al; Kim, Jung Ho

    2014-01-01

    A comprehensive study of the effects of structural imperfections in MgB2 superconducting wire has been conducted. As the sintering temperature becomes lower, the structural imperfections of the MgB2 material are increased, as reflected by detailed X-ray refinement and the normal state resistivity. The crystalline imperfections, caused by lattice disorder, directly affect the impurity scattering between the π and σ bands of MgB2, resulting in a larger upper critical field. In addition, low sintering temperature keeps the grain size small, which leads to a strong enhancement of pinning, and thereby, enhanced critical current density. Owing to both the impurity scattering and the grain boundary pinning, the critical current density, irreversibility field, and upper critical field are enhanced. Residual voids or porosities obviously remain in the MgB2, however, even at low sintering temperature, and thus block current transport paths.

  12. Wear-corrosion of AISI 316L stainless steel in different concentrations of NaCl solution

    International Nuclear Information System (INIS)

    Quezada, E; Aguilar, W; Angelats, L; De la Cruz, P

    2006-01-01

    AISI 316L austenitic stainless steels have an excellent combination of mechanical and corrosion resistant properties, which means they are used in different fields such as agricultural industry, petrochemistry and marine structures. In this latter area the requirements are more demanding when the offshore structures are exposed to wear-corrosion in the saline environment. This work studied the effect of the concentration of NaCl on the resistance to wear-corrosion of AISI 316L stainless steel submitted to annealing thermal treatment. This resistance was determined by the method for measuring mass loss and the steel's electrochemical parameters from the polarization curves in the different corrosive mediums. The results show that the loss of mass in the stainless steel test pieces and the friction coefficients decrease with the increase in NaCl concentration while the current densities of corrosion increase (CW)

  13. Effects of heat and water transport on the performance of polymer electrolyte membrane fuel cell under high current density operation

    International Nuclear Information System (INIS)

    Tabuchi, Yuichiro; Shiomi, Takeshi; Aoki, Osamu; Kubo, Norio; Shinohara, Kazuhiko

    2010-01-01

    Key challenges to the acceptance of polymer electrolyte membrane fuel cells (PEMFCs) for automobiles are the cost reduction and improvement in its power density for compactness. In order to get the solution, the further improvement in a fuel cell performance is required. In particular, under higher current density operation, water and heat transport in PEMFCs has considerable effects on the cell performance. In this study, the impact of heat and water transport on the cell performance under high current density was investigated by experimental evaluation of liquid water distribution and numerical validation. Liquid water distribution in MEA between rib and channel area is evaluated by neutron radiography. In order to neglect the effect of liquid water in gas channels and reactant species concentration distribution in the flow direction, the differential cell was used in this study. Experimental results suggested that liquid water under the channel was dramatically changed with rib/channel width. From the numerical study, it is found that the change of liquid water distribution was significantly affected by temperature distribution in MEA between rib and channel area. In addition, not only heat transport but also water transport through the membrane also significantly affected the cell performance under high current density operation.

  14. High-current-density electrodeposition using pulsed and constant currents to produce thick CoPt magnetic films on silicon substrates

    Science.gov (United States)

    Ewing, Jacob; Wang, Yuzheng; Arnold, David P.

    2018-05-01

    This paper investigates methods for electroplating thick (>20 μm), high-coercivity CoPt films using high current densities (up to 1 A/cm2) and elevated bath temperatures (70 °C). Correlations are made tying current-density and temperature process parameters with plating rate, elemental ratio and magnetic properties of the deposited CoPt films. It also investigates how pulsed currents can increase the plating rate and film to substrate adhesion. Using 500 mA/cm2 and constant current, high-quality, dense CoPt films were successfully electroplated up to 20 μm thick in 1 hr on silicon substrates (0.35 μm/min plating rate). After standard thermal treatment (675°C, 30 min) to achieve the ordered L10 crystalline phase, strong magnetic properties were measured: coercivities up 850 kA/m, remanences >0.5 T, and maximum energy products up to 46 kJ/m3.

  15. Comparison of ring currents evaluated consistently at density functional and Hartree-Fock levels

    NARCIS (Netherlands)

    Havenith, Remco W. A.; Meijer, Anthony J. H. M.; Irving, Benjamin J.; Fowler, Patrick W.

    2009-01-01

    Ring-current maps give an immediate visualisation of aromaticity on the magnetic criterion-by which a cyclic system that supports diatropic (paratropic) current induced by a perpendicular magnetic field is aromatic (anti-aromatic). Calculations of maps with the ipsocentric choice of origin are made

  16. Spin transfer torques in MnSi at ultralow current densities

    NARCIS (Netherlands)

    Jonietz, F.; Mühlbauer, S.; Pfleiderer, C.; Neubauer, A.; Münzer, W.; Bauer, A.; Adams, T.; Georgii, R.; Böni, P.; Duine, R.A.|info:eu-repo/dai/nl/304830127; Everschor, K.; Garst, M.; Rosch, A.

    2010-01-01

    Spin manipulation using electric currents is one of the most promising directions in the field of spintronics. We used neutron scattering to observe the influence of an electric current on the magnetic structure in a bulk material. In the skyrmion lattice of manganese silicon, where the spins form a

  17. Spin transfer torques in MnSi at ultralow current densities.

    Science.gov (United States)

    Jonietz, F; Mühlbauer, S; Pfleiderer, C; Neubauer, A; Münzer, W; Bauer, A; Adams, T; Georgii, R; Böni, P; Duine, R A; Everschor, K; Garst, M; Rosch, A

    2010-12-17

    Spin manipulation using electric currents is one of the most promising directions in the field of spintronics. We used neutron scattering to observe the influence of an electric current on the magnetic structure in a bulk material. In the skyrmion lattice of manganese silicon, where the spins form a lattice of magnetic vortices similar to the vortex lattice in type II superconductors, we observe the rotation of the diffraction pattern in response to currents that are over five orders of magnitude smaller than those typically applied in experimental studies on current-driven magnetization dynamics in nanostructures. We attribute our observations to an extremely efficient coupling of inhomogeneous spin currents to topologically stable knots in spin structures.

  18. Study of the origin and structure of a nocturnal atmospheric density current from observations and numerical simulations

    Science.gov (United States)

    Ander Arrillaga, Jon; Yagüe, Carlos; Román-Cascón, Carlos; Sastre, Mariano

    2016-04-01

    Density currents are flows generated when a dense fluid passes through a less dense surrounding, under the influence of gravity. They usually appear as a consequence of sea-breeze circulations, thunderstorm outflows or katabatic flows. Density currents acquire a particular relevance during nocturnal stable situations, as their onset causes a significant turbulence increase (both from buoyancy and shear) and they occasionally produce turbulence intermittency through the formation of gravity waves. In this work, the arrival of a density current on 23 September 2015 is analysed in the CIBA site (Spain), which is located in the Spanish Northern Plateau, approximately 200 km away from the sea and 100 km away from the closest mountain ranges. Previous studies at this location associated similar nocturnal events with daytime sea breeze in the eastern Cantabrian coast [1]. Micrometeorological measurements from sonic anemometers and different sensors at multiple levels up to 100 m agl provide a solid database. In this specific case, the outbreak of the density current occurs 2 hours after sunset, causing an abrupt increase of the wind speed and a significant weakening of the surface-based thermal inversion. Besides, turbulent parameters and fluxes such as the friction velocity, the sensible heat flux and the Turbulent Kinetic Energy (TKE) are sharply altered with its arrival. The latter, indeed, increases by two orders of magnitude and the Multi Resolution Flux Decomposition (MRFD) of this and other turbulent variables gives the approximate size of the contributing eddies. Furthermore, simulations with the WRF model, which is tested for different Planetary Boundary Layer (PBL) schemes and the topo_wind option for complex topography [2], give meaningful information about the vertical structure and origin of this density current. [1] Udina, M., Soler, M.R., Viana, S. & Yagüe, C. (2013). Model simulation of gravity waves triggered by a density current. Q J R Meteorol Soc, 139

  19. Preliminary Investigation of the Corrosion Behavior of Proprietary Micro-alloyed Steels in Aerated and Deaerated Brine Solutions

    Science.gov (United States)

    Onyeji, Lawrence; Kale, Girish

    2017-12-01

    The corrosion performance of fairly new generation of micro-alloyed steels was compared in different concentrations of aerated and deaerated brines. Electrochemical polarization, weight loss and surface analyses techniques were employed. The results showed a threshold of corrosion rate at 3.5 wt.% NaCl in both aerated and deaerated solutions. The average corrosion current density for steel B, for example, increased from 1.3 µA cm-2 in 1 wt.% NaCl to 1.5 µA cm-2 in 3.5 wt.% NaCl, but decreased to 1.4 µA cm-2 in 10 wt.% deaerated NaCl solutions. The aerated solutions exhibited an average of over 80% increase in corrosion current density in the respective concentrations when compared with the deaerated solution. These results can be attributed to the effects of dissolved oxygen (DO) which has a maximum solubility in 3.5 wt.% NaCl. DO as a depolarizer and electron acceptor in cathodic reactions accelerates anodic metal dissolution. The difference in carbon content and microstructures occasioned by thermo-mechanical treatment contributed to the witnessed variation in corrosion performance of the steels. Specifically, the results of the various corrosion techniques corroborated each other and showed that the corrosion rate of the micro-alloyed steels can be ranked as CRSteel A < CRX65 < CRSteel B < CRSteel C.

  20. Corrosion protection of AM60B magnesium alloy by application of ...

    Indian Academy of Sciences (India)

    sample plated with the Ce–V conversion coating showed lower corrosion current density than the sample plated with traditional chromium oxide pretreatment. The micro-hardness of the bare alloy was significantly increased after electroless coating. The electroless coating is pore-free and there is suitable adhesion ...

  1. Correlations of current parameters with flash density from winter thunderstorms in Japan

    DEFF Research Database (Denmark)

    Vogel, Stephan; Ishii, M.; Saito, M.

    2017-01-01

    In this work, Lightning Location System (LLS) data from theJapanese Lightning Detection Network (JLDN) are correlated with lightning current measurements from the New Energy and Industrial Technology Development Organization (NEDO) project which conducted lightning measurements on wind turbines...

  2. Transport studies in FTU with decoupled temperature and current density profiles

    International Nuclear Information System (INIS)

    Bracco, G.; Buratti, P.; Micozzi, P.; Tudisco, O.

    1994-01-01

    Electron temperature profiles in tokamaks are subject to global constraints that can be attributed either to their link with current profiles, i.e. to MHD stability conditions, a clear example being sawtooth activity, or to other mechanisms like marginal stability. Also a direct effect on transport coefficients was attributed to the current profile. Fast current ramps in FTU ohmic pulses have been used to study the effect of current profile variations on the energy confinement time. The global profile constraint was transiently removed in these pulses, and variations in the shape of temperature profiles could be observed. Modified profiles were also observed in pulses with a strong central radiative sink; in this case the modification was not transient. Finally, the transport properties in the central region have been studied by the analysis of temperature evolution between crashes of very long period sawteeth; very small electron heat transport was found. (author) 6 refs., 5 figs

  3. Determination of Charge-Carrier Mobility in Disordered Thin-Film Solar Cells as a Function of Current Density

    Science.gov (United States)

    Mäckel, Helmut; MacKenzie, Roderick C. I.

    2018-03-01

    Charge-carrier mobility is a fundamental material parameter, which plays an important role in determining solar-cell efficiency. The higher the mobility, the less time a charge carrier will spend in a device and the less likely it is that it will be lost to recombination. Despite the importance of this physical property, it is notoriously difficult to measure accurately in disordered thin-film solar cells under operating conditions. We, therefore, investigate a method previously proposed in the literature for the determination of mobility as a function of current density. The method is based on a simple analytical model that relates the mobility to carrier density and transport resistance. By revising the theoretical background of the method, we clearly demonstrate what type of mobility can be extracted (constant mobility or effective mobility of electrons and holes). We generalize the method to any combination of measurements that is able to determine the mean electron and hole carrier density, and the transport resistance at a given current density. We explore the robustness of the method by simulating typical organic solar-cell structures with a variety of physical properties, including unbalanced mobilities, unbalanced carrier densities, and for high or low carrier trapping rates. The simulations reveal that near VOC and JSC , the method fails due to the limitation of determining the transport resistance. However, away from these regions (and, importantly, around the maximum power point), the method can accurately determine charge-carrier mobility. In the presence of strong carrier trapping, the method overestimates the effective mobility due to an underestimation of the carrier density.

  4. A theoretical analysis of the electromigration-induced void morphological evolution under high current density

    Science.gov (United States)

    Wang, Yuexing; Yao, Yao

    2017-10-01

    In this work, analysis of electromigration-induced void morphological evolution in solder interconnects is performed based on mass diffusion theory. The analysis is conducted for three typical experimentally observed void shapes: circular, ellipse, and cardioid. Void morphological evolution is governed by the competition between the electric field and surface capillary force. In the developed model, both the electric field and capillary force on the void's surface are solved analytically. Based on the mass conversation principle, the normal velocity on the void surface during diffusion is obtained. The void morphological evolution behavior is investigated, and a physical model is developed to predict void collapse to a crack or to split into sub-voids under electric current. It is noted that when the electric current is being applied from the horizontal direction, a circular void may either move stably along the electric current direction or collapse to a finger shape, depending on the relative magnitude of the electric current and surface capillary force. However, the elliptical-shaped void will elongate along the electric current direction and finally collapse to the finger shape. On the other hand, the cardioid-shaped void could bifurcate into two sub-voids when the electric current reaches a critical value. The theoretical predictions agree well with the experimental observations.

  5. Interacting effects of age, density, and weather on survival and current reproduction for a large mammal.

    Science.gov (United States)

    Richard, Emmanuelle; Simpson, Steven E; Medill, Sarah A; McLoughlin, Philip D

    2014-10-01

    Individual-based study of natural populations allows for accurate and precise estimation of fitness components and the extent to which they might vary with ecological conditions. By tracking the fates of all 701 horses known to have lived on Sable Island, Canada, from 2009 to 2013 (where there is no predation, human interference, or interspecific competition for food), we present a detailed analysis of structured population dynamics with focus on interacting effects of intraspecific competition and weather on reproduction and survival. Annual survival of adult females (0.866 ± 0.107 [[Formula: see text] ± SE]) was lower than that of 3-year-olds (0.955 ± 0.051), although annual fecundity (producing a foal in a year that was observed during our census) was higher in adults (0.616 ± 0.023) compared to 3-year-olds (0.402 ± 0.054). Milder winters and lower densities during gestation increased fecundity. Density negatively impacted survival for all age and sex categories; however, highest adult female survival was observed during high-density years coupled with a harsh winter, the result expected if pregnancy loss during winter or loss of foals in spring improved survival. Three-year-old females, which reproduced at lower rates, experienced higher survival than adults. Our results contrast with a previous study of feral horses that suggested recently feral ungulates might be artificially selected to reproduce even when costs to survival are high. In part, this may be because of the comparably long history of feralization (250 years; at least 25 generations) for Sable Island horses.

  6. Critical current density improvements in MgB2 superconducting bulk samples by K2CO3 additions  

    DEFF Research Database (Denmark)

    Grivel, J.-C.

    2018-01-01

    reaction. The critical current density of MgB2 was improved both in self field and under applied magnetic field for T ≤ 30 K, with optimum results for 1 mol% K2CO3 addition. The normalized flux pinning force (f(b)) shows that the flux pinning mechanism at low field is similar for all samples, following...... the predictions of the point pinning model. In contrast the behavior of f(b) is significantly altered at reduced fields (b) larger than unity by K2CO3 additions, tending towards surface pinning. Besides providing carbon, another effect of K2CO3 may originate from the presence of a transient liquid phase...... that appears to improve the crystallinity and thus the critical current density at low field....

  7. Enhancement of critical current density of in situ processed MgB sub 2 tapes by WB addition

    CERN Document Server

    Fujii, H; Kumakura, H

    2003-01-01

    The effect of tungsten boride (WB) addition on the microstructure and superconducting properties of Fe-sheathed MgB sub 2 tapes has been investigated. The microstructure was not influenced appreciably by the addition, whereas the superconducting properties changed. Even by a 5 mol% addition, the critical temperature (T sub c) decreased by about 0.5 K. However, the field dependence of the inductive critical current density (J sub c sub i) became smaller with the increase in the amount of addition, suggesting that pinning centres effective in a high-field region were possibly introduced. The transport critical current density (J sub c sub t) at 4.2 K increased about twice by the 5 mol% addition and reached 15 and 5 kA cm sup - sup 2 at 8 and 10 T, respectively.

  8. In-situ electric field and current density in Japanese male and female models for uniform magnetic field exposures

    International Nuclear Information System (INIS)

    Hirata, A.; Wake, K.; Watanabe, S.; Taki, M.

    2009-01-01

    The present study quantified the in situ electric field and induced current density in anatomically based numeric Japanese male and female models for exposure to extremely low-frequency magnetic fields. A quasi-static FDTD method was applied to analyse this problem. The computational results obtained herein reveal that the 99. percentile value of the in situ electric field in the nerve tissue and the current density averaged over an area of 1 cm 2 of the nerve tissue (excluding non-nerve tissues in the averaging region) in the female models were less than 35 and 25%, respectively. These induced quantities in the Japanese models were smaller than those for European models reported in a previous study, which is mainly due to the difference in cross-sectional area of the body. (authors)

  9. Sleepwalking episodes are preceded by arousal-related activation in the cingulate motor area: EEG current density imaging.

    Science.gov (United States)

    Januszko, Piotr; Niemcewicz, Szymon; Gajda, Tomasz; Wołyńczyk-Gmaj, Dorota; Piotrowska, Anna Justyna; Gmaj, Bartłomiej; Piotrowski, Tadeusz; Szelenberger, Waldemar

    2016-01-01

    To investigate local arousal fluctuations in adults who received ICSD-2 diagnosis of somnambulism. EEG neuroimaging (eLORETA) was utilized to compare current density distribution for 4s epochs immediately preceding sleepwalking episode (from -4.0 s to 0 s) to the distribution during earlier 4s epochs (from -8.0 s to -4.0 s) in 20 EEG segments from 15 patients. Comparisons between eLORETA images revealed significant (t>4.52; psleepwalking, with greater current density within beta 3 frequency range (24-30 Hz) in Brodmann areas 33 and 24. Sleepwalking motor events are associated with arousal-related activation of cingulate motor area. These results support the notion of blurred boundaries between wakefulness and NREM sleep in sleepwalking. Copyright © 2015 International Federation of Clinical Neurophysiology. Published by Elsevier Ireland Ltd. All rights reserved.

  10. Measurement of Magnetic Field From an Induction Heating Hob and Estimation of Induced Current Density in Human Body

    Science.gov (United States)

    Suzuki, Yukihisa; Taki, Masao

    Magnetic fields around induction heating hobs are measured and evaluated with regard to the compliance with safety guidelines of human exposure. The magnetic flux density distributions are highly inhomogeneous and the maximum can exceed the reference levels of the guideline at the very proximity to the device. The induced current densities in human body exposed to these magnetic fields are estimated by numerical calculations by means of impedance method with an anatomical human model. The results indicate that induced currents are sufficiently lower than the basic restriction of the ICNIRP guideline. It is shown that the spatially peak incident field does not provide a relevant reference to compare with the reference level of guideline because it is too conservative but spatially averaged incident magnetic field provides much more relevant reference.

  11. Application of gamma-ray radiography and gravimetric measurements after accelerated corrosion tests of steel embedded in mortar

    Energy Technology Data Exchange (ETDEWEB)

    Duffó, Gustavo, E-mail: duffo@cnea.gov.ar [Comisión Nacional de Energía Atómica, Gerencia Materiales, Depto. Corrosión, Av. Gral. Paz 1499, 1650 San Martín, Buenos Aires (Argentina); Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Av. Rivadavia 1917, 1033 Buenos Aires (Argentina); Universidad Nacional de San Martín, Av. Gral. Paz 1499, 1650 San Martín, Buenos Aires (Argentina); Gaillard, Natalia [Universidad Nacional de San Martín, Av. Gral. Paz 1499, 1650 San Martín, Buenos Aires (Argentina); Mariscotti, Mario; Ruffolo, Marcelo [Tomografía de Hormigón Armado S.A. (THASA), Reclus 2017, 1609 Boulogne, Buenos Aires (Argentina)

    2015-08-15

    The accelerated corrosion by the impressed current technique is widely used in studies of concrete durability since it has the advantage that tests can be carried out within reasonable periods of time. In the present work the relationship between the applied current density and the resulting damage on the reinforcing steel, by applying optical microscopy, scanning electron microscopy, gamma-ray radiography and gravimetric measurements, was studied by means of the implementation of accelerated corrosion tests on reinforced mortar. The results show that the efficiency of the applied current is between 1 and 77%, regardless of the applied current density, the water/cement ratio and the mortar cover depth of the specimens. The results show the applicability of the gamma-ray radiography technique to detect localized corrosion of steel rebars in laboratory specimens.

  12. Visualizing the mechanism that determines the critical current density in polycrystalline superconductors using time-dependent Ginzburg-Landau theory.

    OpenAIRE

    Carty, G. J.; Hampshire, D. P.

    2008-01-01

    In polycrystalline superconducting materials optimized for high critical current density (JC) in high magnetic fields, the mechanism that determines JC has long remained uncertain because of the complicated manner in which the fluxon-fluxon and fluxon-microstructure forces combine. In this work, the time-dependent Ginzburg-Landau equations are used to produce visualizations of fluxons at JC that show the disorder in the pinned part of the flux-line lattice and the motion of those fluxons alon...

  13. Achieving the Widest Range of Syngas Proportions at High Current Density over Cadmium Sulfoselenide Nanorods in CO2Electroreduction.

    Science.gov (United States)

    He, Rong; Zhang, An; Ding, Yilun; Kong, Taoyi; Xiao, Qing; Li, Hongliang; Liu, Yan; Zeng, Jie

    2018-02-01

    Electroreduction of CO 2 is a sustainable approach to produce syngas with controllable ratios, which are required as specific reactants for the optimization of different industrial processes. However, it is challenging to achieve tunable syngas production with a wide ratio of CO/H 2 , while maintaining a high current density. Herein, cadmium sulfoselenide (CdS x Se 1- x ) alloyed nanorods are developed, which enable the widest range of syngas proportions ever reported at the current density above 10 mA cm -2 in CO 2 electroreduction. Among CdS x Se 1- x nanorods, CdS nanorods exhibit the highest Faradaic efficiency (FE) of 81% for CO production with a current density of 27.1 mA cm -2 at -1.2 V vs. reversible hydrogen electrode. With the increase of Se content in CdS x Se 1- x nanorods, the FE for H 2 production increases. At -1.2 V vs. RHE, the ratios of CO/H 2 in products vary from 4:1 to 1:4 on CdS x Se 1- x nanorods (x from 1 to 0). Notably, all proportions of syngas are achieved with current density higher than ≈25 mA cm -2 . Mechanistic study reveals that the increased Se content in CdS x Se 1- x nanorods strengthens the binding of H atoms, resulting in the increased coverage of H* and thus the enhanced selectivity for H 2 production in CO 2 electroreduction. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  14. In vitro corrosion behavior of bioceramic, metallic, and bioceramic-metallic coated stainless steel dental implants.

    Science.gov (United States)

    Fathi, M H; Salehi, M; Saatchi, A; Mortazavi, V; Moosavi, S B

    2003-05-01

    The most common metals and alloys used in dentistry may be exposed to a process of corrosion in vivo that make them cytotoxic. The biocompatibility of dental alloys is primarily related to their corrosion behavior. The aim of this work was to evaluate the corrosion behavior and thus the biocompatibility of the uncoated and coated stainless steels and compare the effect of type of coatings on corrosion behavior. Three types of coatings, hydroxyapatite (HA), titanium (Ti), and a double-layer HA/Ti on AISI 316L stainless steel were made. HA coating was produced using plasma-spraying technique and Ti coating was made using physical vapor deposition process. In order to perform a novel double-layer composite coating, a top layer of HA was plasma-sprayed over a physical vapor deposited Ti layer on AISI 316L stainless steel. Structural characterization techniques including XRD, SEM and EDX were used to investigate the microstructure, morphology and crystallinity of the coatings. Electrochemical potentiodynamic tests were performed in physiological solutions in order to determine and compare the corrosion behavior of the coated and uncoated specimens as an indication of biocompatibility. Double-layer HA/Ti coating on AISI 316L SS had a positive effect on improvement of corrosion behavior. The decrease in corrosion current densities was significant for these coated specimens and was much lower than the values obtained for uncoated and single HA coated specimens. Ti coating on AISI 316L SS also has a beneficial effect on corrosion behavior. The results were compared with the results of corrosion behavior of HA coated commercially pure titanium (cpTi) and uncoated cpTi. These results demonstrated that the double-layer HA/Ti coated 316L SS can be used as an endodontic implant and two goals including improvement of corrosion resistance and bone osteointegration can be obtained simultaneously.

  15. Corrosion protection application of slippery liquid-infused porous surface based on aluminum foil

    Science.gov (United States)

    Tuo, Yanjing; Zhang, Haifeng; Chen, Weiping; Liu, Xiaowei

    2017-11-01

    Corrosion is a major problem for metal in marine systems. In this research, we fabricated a slippery liquid-infused porous surface (SLIPS) on the aluminum foil to protect the underneath metal. The as-fabricated samples were characterized with EDS, XRD, SEM, and contact angle meter. And the anti-corrosion property was evaluated by electrochemical measurements. The corrosion current density of SLIPS is ca.2 orders of magnitude lower than that of the untreated aluminum and superhydrophobic surface. And the impedance spectra of the SLIPS shows a large impedance semicircle with a diameter of several hundred kΩ.cm2. The SLIPS exhibits an outstanding corrosion protection capability, thus it has a broad application prospect in marine.

  16. Corrosion behaviour of unalloyed steel in Portland cement

    International Nuclear Information System (INIS)

    Grauer, R.

    1988-04-01

    The production of hydrogen can cause problems in a repository for low and intermediate level waste. Since the production of gas is mainly due to the corrosion of unalloyed steel, it is important to have as reliable data as possible for the corrosion rate in anaerobic cement. A review of the literature shows that the corrosion current densities are in the range of 0.01 to 0.1 μA/cm 2 (corresponding to corrosion rates between 0.1 and 1.2 μm/a). This implies hydrogen production rates between 0.022 and 0.22 mol/(m 2 a). Corrosion rates of the abovementioned order of magnitude are technically irrelevant, so that there is little interest in determining them accurately. Furthermore, their determination entails problems of measurement technique. In the present situation it would therefore appear risky to accept the lower value as proven. Experiments are proposed to reduce the present uncertainty. (author) 35 refs., 10 figs

  17. Corrosion behaviour of unalloyed steel in Portland cement

    International Nuclear Information System (INIS)

    Grauer, R.

    1988-01-01

    The production of hydrogen can cause problems in a repository for low and intermediate level waste. Since the production of gas is mainly due to the corrosion of unalloyed steel, it is important to have as reliable data as possible for the corrosion rate in anaerobic cement. A review of the literature shows that the corrosion current densities are in the range of 0.01 to 0.1 μA/cm 2 (corresponding to corrosion rates between 0.1 and 1.2 μm/a). This implies hydrogen production rates between 0.022 and 0.22 mol/(m 2 xa). Corrosion rates of the abovementioned order of magnitude are technically irrelevant, so that there is little interest in determining them accurately. Furthermore, their determination entails problems of measurement technique. In the present situation it would therefore appear risky to accept the lower value as proven. Experiments are proposed to reduce the present uncertainty. (author) 35 refs., 10 figs

  18. Enhanced critical current density in the pressure-induced magnetic state of the high-temperature superconductor FeSe

    Science.gov (United States)

    Jung, Soon-Gil; Kang, Ji-Hoon; Park, Eunsung; Lee, Sangyun; Lin, Jiunn-Yuan; Chareev, Dmitriy A.; Vasiliev, Alexander N.; Park, Tuson

    2015-01-01

    We investigate the relation of the critical current density (Jc) and the remarkably increased superconducting transition temperature (Tc) for the FeSe single crystals under pressures up to 2.43 GPa, where the Tc is increased by ~8 K/GPa. The critical current density corresponding to the free flux flow is monotonically enhanced by pressure which is due to the increase in Tc, whereas the depinning critical current density at which the vortex starts to move is more influenced by the pressure-induced magnetic state compared to the increase of Tc. Unlike other high-Tc superconductors, FeSe is not magnetic, but superconducting at ambient pressure. Above a critical pressure where magnetic state is induced and coexists with superconductivity, the depinning Jc abruptly increases even though the increase of the zero-resistivity Tc is negligible, directly indicating that the flux pinning property compared to the Tc enhancement is a more crucial factor for an achievement of a large Jc. In addition, the sharp increase in Jc in the coexisting superconducting phase of FeSe demonstrates that vortices can be effectively trapped by the competing antiferromagnetic order, even though its antagonistic nature against superconductivity is well documented. These results provide new guidance toward technological applications of high-temperature superconductors. PMID:26548444

  19. Comparison of SAR and induced current densities in adults and children exposed to electromagnetic fields from electronic article surveillance devices

    Science.gov (United States)

    Martínez-Búrdalo, M.; Sanchis, A.; Martín, A.; Villar, R.

    2010-02-01

    Electronic article surveillance (EAS) devices are widely used in most stores as anti-theft systems. In this work, the compliance with international guidelines in the human exposure to these devices is analysed by using the finite-difference time-domain (FDTD) method. Two sets of high resolution numerical phantoms of different size (REMCOM/Hershey and Virtual Family), simulating adult and child bodies, are exposed to a 10 MHz pass-by panel-type EAS consisting of two overlapping current-carrying coils. Two different relative positions between the EAS and the body (frontal and lateral exposures), which imply the exposure of different parts of the body at different distances, have been considered. In all cases, induced current densities in tissues of the central nervous system and specific absorption rates (SARs) are calculated to be compared with the limits from the guidelines. Results show that induced current densities are lower in the case of adult models as compared with those of children in both lateral and frontal exposures. Maximum SAR values calculated in lateral exposure are significantly lower than those calculated in frontal exposure, where the EAS-body distance is shorter. Nevertheless, in all studied cases, with an EAS driving current of 4 A rms, maximum induced current and SAR values are below basic restrictions.

  20. Comparison of SAR and induced current densities in adults and children exposed to electromagnetic fields from electronic article surveillance devices

    International Nuclear Information System (INIS)

    Martinez-Burdalo, M; Sanchis, A; Martin, A; Villar, R

    2010-01-01

    Electronic article surveillance (EAS) devices are widely used in most stores as anti-theft systems. In this work, the compliance with international guidelines in the human exposure to these devices is analysed by using the finite-difference time-domain (FDTD) method. Two sets of high resolution numerical phantoms of different size (REMCOM/Hershey and Virtual Family), simulating adult and child bodies, are exposed to a 10 MHz pass-by panel-type EAS consisting of two overlapping current-carrying coils. Two different relative positions between the EAS and the body (frontal and lateral exposures), which imply the exposure of different parts of the body at different distances, have been considered. In all cases, induced current densities in tissues of the central nervous system and specific absorption rates (SARs) are calculated to be compared with the limits from the guidelines. Results show that induced current densities are lower in the case of adult models as compared with those of children in both lateral and frontal exposures. Maximum SAR values calculated in lateral exposure are significantly lower than those calculated in frontal exposure, where the EAS-body distance is shorter. Nevertheless, in all studied cases, with an EAS driving current of 4 A rms, maximum induced current and SAR values are below basic restrictions.

  1. High Current Density InAsSb/GaSb Tunnel Field Effect Transistors

    OpenAIRE

    Dey, Anil; Borg, Mattias; Ganjipour, Bahram; Ek, Martin; Dick Thelander, Kimberly; Lind, Erik; Nilsson, Peter; Thelander, Claes; Wernersson, Lars-Erik

    2012-01-01

    Steep-slope devices, such as tunnel field-effect transistors (TFETs), have recently gained interest due to their potential for low power operation at room temperature. The devices are based on inter-band tunneling which could limit the on-current since the charge carriers must tunnel through a barrier to traverse the device. The InAs/GaSb heterostructure forms a broken type II band alignment which enables inter-band tunneling without a barrier, allowing high on-currents. We ha...

  2. Density-matrix simulation of small surface codes under current and projected experimental noise

    Science.gov (United States)

    O'Brien, T. E.; Tarasinski, B.; DiCarlo, L.

    2017-09-01

    We present a density-matrix simulation of the quantum memory and computing performance of the distance-3 logical qubit Surface-17, following a recently proposed quantum circuit and using experimental error parameters for transmon qubits in a planar circuit QED architecture. We use this simulation to optimize components of the QEC scheme (e.g., trading off stabilizer measurement infidelity for reduced cycle time) and to investigate the benefits of feedback harnessing the fundamental asymmetry of relaxation-dominated error in the constituent transmons. A lower-order approximate calculation extends these predictions to the distance-5 Surface-49. These results clearly indicate error rates below the fault-tolerance threshold of the surface code, and the potential for Surface-17 to perform beyond the break-even point of quantum memory. However, Surface-49 is required to surpass the break-even point of computation at state-of-the-art qubit relaxation times and readout speeds.

  3. Relationship between anode material, supporting electrolyte and current density during electrochemical degradation of organic compounds in water

    Energy Technology Data Exchange (ETDEWEB)

    Guzmán-Duque, Fernando L. [Grupo de diagnóstico y control de la contaminación, Facultad de ingeniería, Universidad de Antioquia, A.A. 1226, Medellín (Colombia); Palma-Goyes, Ricardo E. [Grupo de Investigación en Remediación Ambiental y Biocatálisis, Instituto de Química, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquía Udea, A.A. 1226, Medellín (Colombia); González, Ignacio [Universidad Autónoma Metropolitana-Iztapalapa, Departamento de Química, Av. San Rafael Atlixco No 186, C.P 09340, México D.F (Mexico); Peñuela, Gustavo [Grupo de diagnóstico y control de la contaminación, Facultad de ingeniería, Universidad de Antioquia, A.A. 1226, Medellín (Colombia); Torres-Palma, Ricardo A., E-mail: rtorres@matematicas.udea.edu.co [Grupo de Investigación en Remediación Ambiental y Biocatálisis, Instituto de Química, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquía Udea, A.A. 1226, Medellín (Colombia)

    2014-08-15

    Highlights: • Pathway and efficiency are linked to the current-electrode–electrolyte interaction. • Unlike BDD, IrO{sub 2} route was independent of current but dependent on the electrolyte. • IrO{sub 2}/SO{sub 4}{sup 2−} and IrO{sub 2}/Cl{sup −} routes were via IrO{sub 3} and chlorine species, respectively. • BDD/SO{sub 4}{sup 2−} and IrO{sub 2}/Cl{sup −} systems were favored at low and high currents, respectively. - Abstract: Taking crystal violet (CV) dye as pollutant model, the electrode, electrolyte and current density (i) relationship for electro-degrading organic molecules is discussed. Boron-doped diamond (BDD) or Iridium dioxide (IrO{sub 2}) used as anode materials were tested with Na{sub 2}SO{sub 4} or NaCl as electrolytes. CV degradation and generated oxidants showed that degradation pathways and efficiency are strongly linked to the current density-electrode–electrolyte interaction. With BDD, the degradation pathway depends on i: If i < the limiting current density (i{sub lim}), CV is mainly degraded by ·OH radicals, whereas if i > i{sub lim}, generated oxidants play a major role in the CV elimination. When IrO{sub 2} was used, CV removal was not dependent on i, but on the electrolyte. Pollutant degradation in Na{sub 2}SO{sub 4} on IrO{sub 2} seems to occur via IrO{sub 3}; however, in the presence of NaCl, degradation was dependent on the chlorinated oxidative species generated. In terms of efficiency, the Na{sub 2}SO{sub 4} electrolyte showed better results than NaCl when BDD anodes were employed. On the contrary, NaCl was superior when combined with IrO{sub 2}. Thus, the IrO{sub 2}/Cl{sup −} and BDD/SO{sub 4}{sup 2−} systems were better at removing the pollutant, being the former the most effective. On the other hand, pollutant degradation with the BDD/SO{sub 4}{sup 2−} and IrO{sub 2}/Cl{sup −} systems is favored at low and high current densities, respectively.

  4. Effect of fluorides and chlorides upon corrosion behavior of alloy C-22

    International Nuclear Information System (INIS)

    Carranza, Ricardo M.

    2003-01-01

    Alloy C-22 is one of the candidates to fabricate the external wall of the high level nuclear waste containers. These packages are designed to maintain isolation of the waste for a minimum of 10,000 years. During this period they must resist atmospheric corrosion. Electrochemical techniques such as cyclic potentiodynamic polarization, electrochemical impedance spectroscopy and variation of corrosion potential in time and non-electrochemical techniques such as X-ray fluorescence (XRF) and microscopy were applied to determine the effect of fluorides and chlorides upon general and localized corrosion of different microstructures of alloy C-22. The corrosion rates obtained were about 0.1 μm/year. Crevice corrosion was detected only in those solutions where chlorides ions were present. Fluoride ions affected the passivity and trans passivity behavior of the alloy. They produced higher current densities than chlorides in both ranges. There were no differences in corrosion behavior of the different microstructures. Mixtures of chlorides and fluorides seem to be more detrimental than the separated ions regarding to localized corrosion and trans passivity. (author)

  5. Corrosion and Wear Response of Oxide-Reinforced Nickel Composite Coatings

    Science.gov (United States)

    Tirlapur, Pradeep; Muniprakash, M.; Srivastava, Meenu

    2016-07-01

    Various grades of fuels are used in automobiles, as a result the engine components are continuously subjected to simultaneous action of corrosion and wear. Ni-SiC composite coating is the most widely investigated and commercialized wear-resistant coating in the automotive industry. However, this coating cannot be used at temperatures above 450 °C due to the tendency of SiC to react with Ni and form brittle silicides. An alternate approach is to use oxide-reinforced coatings. In the present study, zirconia, ZrO2 and, yttria-stabilized zirconia, YSZ-reinforced Ni composite coatings have been developed by electrodeposition method. It was observed from the microhardness studies that there is no significant difference in the values for Ni-SiC and Ni-ZrO2 coatings. The corrosion behavior was evaluated using polarization and electrochemical impedance studies. The studies showed that oxide particle-reinforced Ni coatings possessed better corrosion resistance due to their lower corrosion current density, I corr. Tribo-corrosion studies were carried out to understand the synergistic effect of wear and corrosion on the performance of Ni-based composite coatings in 0.5 M Na2SO4. Among various composite coatings, Ni-YSZ exhibited less material loss thereby showing better tribo-corrosion behavior.

  6. Sedimentology and geomorphology of the deposits from the August 2006 pyroclastic density currents at Tungurahua volcano, Ecuador.

    Science.gov (United States)

    Douillet, Guilhem Amin; Tsang-Hin-Sun, Ève; Kueppers, Ulrich; Letort, Jean; Pacheco, Daniel Alejandro; Goldstein, Fabian; Von Aulock, Felix; Lavallée, Yan; Hanson, Jonathan Bruce; Bustillos, Jorge; Robin, Claude; Ramón, Patricio; Hall, Minard; Dingwell, Donald B

    The deposits of the pyroclastic density currents from the August 2006 eruption of Tungurahua show three facies associations depending on the topographic setting: the massive, proximal cross-stratified, and distal cross-stratified facies. (1) The massive facies is confined to valleys on the slopes of the volcano. It contains clasts of >1 m diameter to fine ash material, is massive, and interpreted as deposited from dense pyroclastic flows. Its surface can exhibit lobes and levees covered with disk-shaped and vesicular large clasts. These fragile large clasts must have rafted at the surface of the flows all along the path in order to be preserved, and thus imply a sharp density boundary near the surface of these flows. (2) The proximal cross-stratified facies is exposed on valley overbanks on the upper part of the volcano and contains both massive coarse-grained layers and cross-stratified ash and lapilli bedsets. It is interpreted as deposited from (a) dense pyroclastic flows that overflowed the gentle ridges of valleys of the upper part of the volcano and (b) dilute pyroclastic density currents created from the dense flows by the entrainment of air on the steep upper flanks. (3) The distal cross-stratified facies outcrops as spatially limited, isolated, and wedge-shaped bodies of cross-stratified ash deposits located downstream of cliffs on valleys overbanks. It contains numerous aggrading dune bedforms, whose crest orientations reveal parental flow directions. A downstream decrease in the size of the dune bedforms, together with a downstream fining trend in the grain size distribution are observed on a 100-m scale. This facies is interpreted to have been deposited from dilute pyroclastic density currents with basal tractional boundary layers. We suggest that the parental flows were produced from the dense flows by entrainment of air at cliffs, and that these diluted currents might rapidly deposit through "pneumatic jumps". Three modes are present in the grain

  7. The effect of surface treatment and position of the dental restoration on amalgam corrosion behavior

    Energy Technology Data Exchange (ETDEWEB)

    Mortazavi, V. [Isfahan Univ. of Medical Sciences, Faculty of Dentistry, Isfahan (Iran, Islamic Republic of); Fathi, M.H. [Isfahan Univ. of Technology, Materials Engineering Dept., Isfahan (Iran, Islamic Republic of)

    2003-07-01

    The aim of this research was to evaluate the effect of surface treatment, clinical operations and the condition and position of the dental restoration on amalgam corrosion behavior. Commercial amalgam alloy namely Oralloy was selected. Twenty-one amalgam samples were prepared. After triturating and condensation, the samples were divided into three groups and each group was finished by using one of three surface clinical procedures; carving, carving-burnishing, carving-burnishing-polishing. A special cylindrical mold was used in order to simulation of the interproximal areas and proximal surfaces of the dental restorations. Stainless steel matrix band was laid on the internal mold surfaces and amalgam paste was compacted in the mold. Electrochemical potentiodynamic tests were performed at a temperature of 37{+-}1 {sup o}C in physiological solution in order to determine and compare the corrosion behavior of dental amalgam samples, as an indication of biocompatibility. The results showed statistically significant differences between the mean corrosion current density values of three different groups of dental amalgam (P<0.05). The polished group possesses the lowest and the carved group shows the highest corrosion current density. The carved group shows more corrosion resistance in compare with the sample near the matrix band as an index of the proximal surfaces of restorations. It was concluded that even a simple clinical operation could effect on dental amalgam corrosion resistance. The proximal surfaces of the class II restorations are not only susceptible to concentration cell corrosion but also possess less corrosion resistance because dentist could perform no clinical surface treatment. (author)

  8. Brain Surface Current Density Mapping in Pianists and Non-Pianists

    Science.gov (United States)

    2001-10-25

    while listening to piano pieces. Keywords - Inverse problems, Biomagnetism I. INTRODUCTION In magnetoencephalography (MEG), one of the common...Number Author(s) Project Number Task Number Work Unit Number Performing Organization Name(s) and Address(es) Biomagnetic Center Friedrich-Schiller...Haueisen, H. Nowak, and H. Brauer, “Equivalent Ellipsoid as an interpretation tool of extended current distributions in biomagnetic inverse problems,” IEEE Trans. Mag., vol. 36, pp. 1692 – 1695, 2000

  9. Corrosion Protection of Al/Au/ZnO Anode for Hybrid Cell Application.

    Science.gov (United States)

    Slaughter, Gymama; Stevens, Brian

    2015-11-16

    Effective protection of power sources from corrosion is critical in the development of abiotic fuel cells, biofuel cells, hybrid cells and biobateries for implantable bioelectronics. Corrosion of these bioelectronic devices result in device inability to generate bioelectricity. In this paper Al/Au/ZnO was considered as a possible anodic substrate for the development of a hybrid cell. The protective abilities of corrosive resistant aluminum hydroxide and zinc phosphite composite films formed on the surface of Al/Au/ZnO anode in various electrolyte environments were examined by electrochemical methods. The presence of phosphate buffer and physiological saline (NaCl) buffer allows for the formation of aluminum hyrdroxide and zinc phosphite composite films on the surface of the Al/Au/ZnO anode that prevent further corrosion of the anode. The highly protective films formed on the Al/Au/ZnO anode during energy harvesting in a physiological saline environment resulted in 98.5% corrosion protective efficiency, thereby demonstrating that the formation of aluminum hydroxide and zinc phosphite composite films are effective in the prevention of anode corrosion during energy harvesting. A cell assembly consisting of the Al/Au/ZnO anode and platinum cathode resulted in an open circuit voltage of 1.03 V. A maximum power density of 955.3 mW/ cm² in physiological saline buffer at a cell voltage and current density of 345 mV and 2.89 mA/ cm², respectively.

  10. Corrosion studies of UNS N08031 in a heavy brine LiBr solution at high temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Garcia, D.M.; Blasco-Tamarit, E.; Igual-Munoz, A.; Garcia-Anton, J. [Valencia Univ. Politecnica, Dept. de Ingenieria Quimica y Nuclear. ETSI Industriales, Valencia (Spain)

    2009-07-01

    Lithium Bromide heavy brine solutions are used as absorbent in LiBr absorption machines. These machines are an alternative to refrigeration compression systems. The double effect absorption machines are more efficient than those of single effect, but they reach higher temperatures and they use higher LiBr concentrations. These conditions aggravate the corrosion problems on the metallic components of these systems. Therefore, it is necessary to study the corrosion resistance of the construction materials of the LiBr absorption machines, like UNS N08031, under these aggressive conditions. The objective of the present work is to study the pitting corrosion resistance and the re-passivation behaviour of a highly alloyed austenitic stainless steel (N08031) in a 1080 g/l heavy brine LiBr solution at 75 C, 100 C, 125 C and 150 C. Open Circuit Potential tests and Potentiodynamic Cyclic curves were carried out to obtain information about the electrochemical behaviour of UNS N08031 alloy. Corrosion potentials and corrosion current densities were obtained from the Tafel Analysis. The pitting corrosion resistance was evaluated from the passivation current density and the pitting potential values. The re-passivation potential and the re-passivation current density provided information about the re-passivation behaviour of UNS N08031. The samples were etched to study the microstructure by Scanning Electron Microscopy (SEM). The results showed that the potentiodynamic curves were typical of a passive material at all temperatures. Pitting corrosion resistance decreased with temperature, as the decrease in pitting potential and the increase in passivation current density evidenced. However, the re-passivation capability increased with temperature, since the width of the hysteresis loop diminished as temperature increased. (authors)

  11. THE INVESTIGATION OF DENSITY CURRENTS AND RATE OF OUTFLOW FROM A SEPTIC TANK

    Directory of Open Access Journals (Sweden)

    Maciej Pawlak

    2015-09-01

    Full Text Available The aim of the study was to verify the possibility of the existence of preferential flow paths in a septic tank and the effect of using various types of inlet and outlet in this context. Two of the most unfavourable variants of favoured flow paths for different types of inlet and outlet were analysed. The first variant was related to the occurrence of the privileged flow path below the water surface level directly to the outlet and the second variant – to the so-called boiling phenomenon in a septic tank. During the study, the intensity of outflow from the septic tank was measured. The time between successive doses also was measured. These studies were carried out using several inlet and outlet structures combinations. It was observed that by introducing a suitable outlet it is possible to limit and in the case of the particular type of filtering basket – to eliminate the unwanted phenomenon of preferential flow paths after hot water introduction. The phenomenon of boiling in the septic tank may occur due to the introduction of wastewater of higher density containing a higher concentration of the suspension. The effect of cooler water introduction on this phenomenon was not observed. The limitation of the maximum intensity of outflow from the septic tank can be achieved by filtering basket using at the outlet, which increases the flow resistance thanks to the low porosity.

  12. The role of relativity in the optical response of gold within the time-dependent current-density-functional theory.

    Science.gov (United States)

    Romaniello, P; de Boeij, P L

    2005-04-22

    We included relativistic effects in the formulation of the time-dependent current-density-functional theory for the calculation of linear response properties of metals [P. Romaniello and P. L. de Boeij, Phys. Rev. B (to be published)]. We treat the dominant scalar-relativistic effects using the zeroth-order regular approximation in the ground-state density-functional theory calculations, as well as in the time-dependent response calculations. The results for the dielectric function of gold calculated in the spectral range of 0-10 eV are compared with experimental data reported in literature and recent ellipsometric measurements. As well known, relativistic effects strongly influence the color of gold. We find that the onset of interband transitions is shifted from around 3.5 eV, obtained in a nonrelativistic calculation, to around 1.9 eV when relativity is included. With the inclusion of the scalar-relativistic effects there is an overall improvement of both real and imaginary parts of the dielectric function over the nonrelativistic ones. Nevertheless some important features in the absorption spectrum are not well reproduced, but can be explained in terms of spin-orbit coupling effects. The remaining deviations are attributed to the underestimation of the interband gap (5d-6sp band gap) in the local-density approximation and to the use of the adiabatic local-density approximation in the response calculation.

  13. Water-induced charge transport in tablets of microcrystalline cellulose of varying density: dielectric spectroscopy and transient current measurements

    International Nuclear Information System (INIS)

    Nilsson, Martin; Alderborn, Goeran; Stroemme, Maria

    2003-01-01

    Room temperature dielectric frequency response data taken over 13 decades in frequency on microcrystalline cellulose (MCC) tablets of varying density are presented. The frequency response shows on three different processes: the first one is a high-frequency relaxation process whose magnitude increases and reaches a plateau as the tablet density increases. This process is associated with orientational motions of local chain segments via glycosidic bonds. The second relaxation process, related to the presence of water in the MCC matrix, is insensitive to changes in tablet density. At lower frequencies, dc-like imperfect charge transport dominates the dielectric spectrum. The dc conductivity was found to decrease with increasing tablet density and increase exponentially with increasing humidity. Transient current measurements indicated that two different ionic species, protons and OH - ions, lied behind the observed conductivity. At ambient humidity of 22%, only one in a billion of the water molecules present in the tablet matrix participated in long range dc conduction. The diffusion coefficient of the protons and OH - ions were found to be of the order of 10 -9 cm 2 /s, which is the same as for small salt building ions in MCC. This shows that ionic drugs leaving a tablet matrix may diffuse in the same manner as the constituent ions of water and, thus, elucidates the necessity to understand the water transport properties of excipient materials to be able to tailor the drug release process from pharmaceutical tablets

  14. The dependence of critical current density of GdFeCo layer on composition of thermally assisted STT-RAM

    Science.gov (United States)

    Dai, B.; Zhu, J.; Liu, K.; Yang, L.; Han, J.

    2017-07-01

    Amorphous rare earth-transitional metal (RETM) GdFeCo memory layer with RE- and TM-rich compositions was fabricated in stacks of GdFeCo (10 nm)/Cu (3 nm)/[Co(0.2 nm)/Pd(0.4 nm)]6. Their magnetic properties and spin transfer torque (STT) switching of magnetization were investigated. The maximum magneto-resistance (MR) was around 0.24% for the TM-rich Gd21.4 (Fe90Co10)78.6 memory layer and was -0.03% for the RE-rich Gd29.0 (Fe90Co10)71.0 memory layer. The critical current densities Jc to switch the GdFeCo memory layers are in the range of 1.4 × 107 A/cm2-4.5 × 107 A/cm2. The dependence of critical current density Jc and effective anisotropy constant Keff on Gd composition were also investigated. Both Jc and Keff have maximum values in the Gd composition range from 21-29 at.%, suitable for thermally assisted STT-RAM for storage density exceeding Gb/inch2.

  15. Analysis of the Corrosion Behavior of an A-TIG Welded SS 409 Weld Fusion Zone

    Science.gov (United States)

    Vidyarthy, R. S.; Dwivedi, D. K.

    2017-11-01

    AISI 409 (SS 409) ferritic stainless steel is generally used as the thick gauge section in freight train wagons, in ocean containers, and in sugar refinery equipment. Activating the flux tungsten inert gas (A-TIG) welding process can reduce the welding cost during fabrication of thick sections. However, corrosion behavior of the A-TIG weld fusion zone is a prime concern for this type of steel. In the present work, the effect of the A-TIG welding process parameters on the corrosion behavior of a weld fusion zone made of 8-mm-thick AISI 409 ferritic stainless-steel plate has been analyzed. Potentiodynamic polarization tests were performed to evaluate the corrosion behavior. The maximum corrosion potential ( E corr) was shown by the weld made using a welding current of 215 A, a welding speed of 95 mm/min, and a flux coating density of 0.81 mg/cm2. The minimum E corr was observed in the weld made using a welding current of 190 A, a welding speed of 120 mm/min, and a flux coating density of 1.40 mg/cm2. The current study also presents the inclusive microstructure-corrosion property relationships using the collective techniques of scanning electron microscopy, energy-dispersive x-ray spectroscopy, and x-ray diffraction.

  16. Ni/YSZ electrode degradation studied by impedance spectroscopy: Effects of gas cleaning and current density

    DEFF Research Database (Denmark)

    Hauch, Anne; Mogensen, Mogens Bjerg

    2010-01-01

    on the anode degradation, tests were set-up both with and without gas cleaning. Gas cleaning was done by passing the H2 over porous nickel at room temperature. It was found that cleaning of the inlet H2 gas more than halved the anode degradation under current load. For tests at OCV the increase in the Ni...... at OCV prior to fuel cell testing provided fuel cell tests with minimal/negligible anode degradation compared to tests where fuel cell testing was started immediately after initial characterization of the cells....

  17. Current-induced spin polarization in InGaAs and GaAs epilayers with varying doping densities

    Science.gov (United States)

    Luengo-Kovac, M.; Huang, S.; Del Gaudio, D.; Occena, J.; Goldman, R. S.; Raimondi, R.; Sih, V.

    2017-11-01

    The current-induced spin polarization and momentum-dependent spin-orbit field were measured in InxGa1 -xAs epilayers with varying indium concentrations and silicon doping densities. Samples with higher indium concentrations and carrier concentrations and lower mobilities were found to have larger electrical spin generation efficiencies. Furthermore, current-induced spin polarization was detected in GaAs epilayers despite the absence of measurable spin-orbit fields, indicating that the extrinsic contributions to the spin-polarization mechanism must be considered. Theoretical calculations based on a model that includes extrinsic contributions to the spin dephasing and the spin Hall effect, in addition to the intrinsic Rashba and Dresselhaus spin-orbit coupling, are found to reproduce the experimental finding that the crystal direction with the smaller net spin-orbit field has larger electrical spin generation efficiency and are used to predict how sample parameters affect the magnitude of the current-induced spin polarization.

  18. Current density and polarization curves for radial flow field patterns applied to PEMFCs (Proton Exchange Membrane Fuel Cells)

    International Nuclear Information System (INIS)

    Cano-Andrade, S.; Hernandez-Guerrero, A.; Spakovsky, M.R. von; Damian-Ascencio, C.E.; Rubio-Arana, J.C.

    2010-01-01

    A numerical solution of the current density and velocity fields of a 3-D PEM radial configuration fuel cell is presented. The energy, momentum and electrochemical equations are solved using a computational fluid dynamics (CFD) code based on a finite volume scheme. There are three cases of principal interest for this radial model: four channels, eight channels and twelve channels placed in a symmetrical path over the flow field plate. The figures for the current-voltage curves for the three models proposed are presented, and the main factors that affect the behavior of each of the curves are discussed. Velocity contours are presented for the three different models, showing how the fuel cell behavior is affected by the velocity variations in the radial configuration. All these results are presented for the case of high relative humidity. The favorable results obtained for this unconventional geometry seems to indicate that this geometry could replace the conventional commercial geometries currently in use.

  19. A comparative corrosion behavior of Mg, AZ31 and AZ91 alloys in 3.5% NaCl solution

    Directory of Open Access Journals (Sweden)

    I.B. Singh

    2015-06-01

    Full Text Available The corrosion behavior of Mg, AZ31 and AZ91 has been evaluated in 3.5% NaCl solution using weight loss, electrochemical polarization and impedance measurements. Corrosion rate derived from the weight losses demonstrated the occurrence of steeply fast corrosion reaction on AZ91 alloy after three hours of immersion, indicating the start of galvanic corrosion. An increase of corrosion rate with immersion time was also observed for AZ31 but with lesser extent than AZ91 alloy. Whereas Mg metals showed a decrease of corrosion rate with immersion time, suggesting the formation of a protective layer on their surfaces. In contrast, the corrosion current density (Icorr derived from the Tafel plots, exhibited their corrosion resistances in order of Mg > AZ91 > AZ31. Electrochemical charge transfer resistance (Rct and double layer capacitance measured by electrochemical impedance spectroscopy (EIS, are well in accordance with the measured Icorr. EIS measurements with time and microstructural examination of the corroded and uncorroded samples are helpful in elucidation of results measured by electrochemical polarization.

  20. Al-Co Alloys Prepared by Vacuum Arc Melting: Correlating Microstructure Evolution and Aqueous Corrosion Behavior with Co Content

    Directory of Open Access Journals (Sweden)

    Angeliki Lekatou

    2016-02-01

    Full Text Available Hypereutectic Al-Co alloys of various Co contents (7–20 weight % (wt.% Co were prepared by vacuum arc melting, aiming at investigating the influence of the cobalt content on the microstructure and corrosion behavior. Quite uniform and directional microstructures were attained. The obtained microstructures depended on the Co content, ranging from fully eutectic growth (7 wt.% and 10 wt.% Co to coarse primary Al9Co2 predominance (20 wt.% Co. Co dissolution in Al far exceeded the negligible equilibrium solubility of Co in Al; however, it was hardly uniform. By increasing the cobalt content, the fraction and coarseness of Al9Co2, the content of Co dissolved in the Al matrix, and the hardness and porosity of the alloy increased. All alloys exhibited similar corrosion behavior in 3.5 wt.% NaCl with high resistance to localized corrosion. Al-7 wt.% Co showed slightly superior corrosion resistance than the other compositions in terms of relatively low corrosion rate, relatively low passivation current density and scarcity of stress corrosion cracking indications. All Al-Co compositions demonstrated substantially higher resistance to localized corrosion than commercially pure Al produced by casting, cold rolling and arc melting. A corrosion mechanism was formulated. Surface films were identified.

  1. Metallic amorphous electrodeposited molybdenum coating from aqueous electrolyte: Structural, electrical and morphological properties under current density

    Energy Technology Data Exchange (ETDEWEB)

    Nemla, Fatima [LEPCM, Department of Physics, University of Batna (Algeria); Cherrad, Djellal, E-mail: cherradphisic@yahoo.fr [Laboratory for Developing New Materials and Their Characterizations, University of Setif (Algeria)

    2016-07-01

    Graphical abstract: - Highlights: • Although difficulties related to electrodeposition of Mo films, we have successfully coated onto a cooper substrate. • A good formation of bcc Mo phase and lattice parameter was very accurate. • It seems that electrical properties of our samples are good and suitable as back contact for thin film solar cells. • It seems that grain size, microstrain and dislocation density are all managed and correlated to retain the resistivity to a considerable minimum value. - Abstract: Molybdenum coatings are extensively utilized as back contact for CIGS-based solar cells. However, their electrodeposition from aqueous electrolyte still sophisticates, since long time, owing to the high reactivity with oxygen. In this study, we present a successful 30 min electrodeposition experiment of somewhat thick (∼0.98–2.9 μm) and of moderate surface roughness RMS (∼47–58 nm), metallic bright Mo coating from aqueous electrolyte containing molybdate ions. XRD analysis and Hall Effect measurements have been used to confirm the presence of Mo. The crystal structure of deposits was slightly amorphous in nature to body centred cubic structure (bcc) Mo (110), (211) and (220) face. Lattice parameters exhibit some weak fluctuated tensile stress when compared to the reference lattice parameter. Additionally, our calculated lattice parameters are in good agreement with some previous works from literature. Discussions on the grain growth prove that they are constrained by grain boundary energy not the thickness effect. Further discussions were made on the electrical resistivity and surface morphology. Resonance scattering of Fermi electrons are expected to contribute towards the variation in the film resistivity through the carrier mobility limitation. However, studied samples might be qualified as candidates for solar cell application.

  2. Corrosion inhibitors

    International Nuclear Information System (INIS)

    El Ashry, El Sayed H.; El Nemr, Ahmed; Esawy, Sami A.; Ragab, Safaa

    2006-01-01

    The corrosion inhibition efficiencies of some triazole, oxadiazole and thiadiazole derivatives for steel in presence of acidic medium have been studied by using AM1, PM3, MINDO/3 and MNDO semi-empirical SCF molecular orbital methods. Geometric structures, total negative charge on the molecule (TNC), highest occupied molecular energy level (E HOMO ), lowest unoccupied molecular energy level (E LUMO ), core-core repulsion (CCR), dipole moment (μ) and linear solvation energy terms, molecular volume (V i ) and dipolar-polarization (π *), were correlated to corrosion inhibition efficiency. Four equations were proposed to calculate corrosion inhibition efficiency. The agreement with the experimental data was found to be satisfactory; the standard deviations between the calculated and experimental results ranged between ±0.03 and ±4.18. The inhibition efficiency was closely related to orbital energies (E HOMO and E LUMO ) and μ. The correlation between quantum parameters and experimental inhibition efficiency has been validated by single point calculations for the semi-empirical AM1 structures using B3LYP/6-31G** as a higher level of theory. The proposed equations were applied to predict the corrosion inhibition efficiency of some related structures to select molecules of possible activity from a presumable library of compounds

  3. Underground pipeline corrosion

    CERN Document Server

    Orazem, Mark

    2014-01-01

    Underground pipelines transporting liquid petroleum products and natural gas are critical components of civil infrastructure, making corrosion prevention an essential part of asset-protection strategy. Underground Pipeline Corrosion provides a basic understanding of the problems associated with corrosion detection and mitigation, and of the state of the art in corrosion prevention. The topics covered in part one include: basic principles for corrosion in underground pipelines, AC-induced corrosion of underground pipelines, significance of corrosion in onshore oil and gas pipelines, n

  4. Effects of chemical composition on the corrosion of dental alloys.

    Science.gov (United States)

    Galo, Rodrigo; Ribeiro, Ricardo Faria; Rodrigues, Renata Cristina Silveira; Rocha, Luís Augusto; de Mattos, Maria da Glória Chiarello

    2012-01-01

    The aim of this study was to determine the effect of the oral environment on the corrosion of dental alloys with different compositions, using electrochemical methods. The corrosion rates were obtained from the current-potential curves and electrochemical impedance spectroscopy (EIS). The effect of artificial saliva on the corrosion of dental alloys was dependent on alloy composition. Dissolution of the ions occurred in all tested dental alloys and the results were strongly dependent on the general alloy composition. Regarding the alloys containing nickel, the Ni-Cr and Ni-Cr-Ti alloys released 0.62 mg/L of Ni on average, while the Co-Cr dental alloy released ions between 0.01 and 0.03 mg/L of Co and Cr, respectively.The open-circuit potential stabilized at a higher level with lower deviation (standard deviation: Ni-Cr-6Ti = 32 mV/SCE and Co-Cr = 54 mV/SCE). The potenciodynamic curves of the dental alloys showed that the Ni-based dental alloy with >70 wt% of Ni had a similar curve and the Co-Cr dental alloy showed a low current density and hence a high resistance to corrosion compared with the Ni-based dental alloys. Some changes in microstructure were observed and this fact influenced the corrosion behavior for the alloys. The lower corrosion resistance also led to greater release of nickel ions to the medium. The quantity of Co ions released from the Co-Cr-Mo alloy was relatively small in the solutions. In addition, the quantity of Cr ions released into the artificial saliva from the Co-Cr alloy was lower than Cr release from the Ni-based dental alloys.

  5. Alternating steady state free precession for estimation of current-induced magnetic flux density: A feasibility study.

    Science.gov (United States)

    Lee, Hyunyeol; Jeong, Woo Chul; Kim, Hyung Joong; Woo, Eung Je; Park, Jaeseok

    2016-05-01

    To develop a novel, current-controlled alternating steady-state free precession (SSFP)-based conductivity imaging method and corresponding MR signal models to estimate current-induced magnetic flux density (Bz ) and conductivity distribution. In the proposed method, an SSFP pulse sequence, which is in sync with alternating current pulses, produces dual oscillating steady states while yielding nonlinear relation between signal phase and Bz . A ratiometric signal model between the states was analytically derived using the Bloch equation, wherein Bz was estimated by solving a nonlinear inverse problem for conductivity estimation. A theoretical analysis on the signal-to-noise ratio of Bz was given. Numerical and experimental studies were performed using SSFP-FID and SSFP-ECHO with current pulses positioned either before or after signal encoding to investigate the feasibility of the proposed method in conductivity estimation. Given all SSFP variants herein, SSFP-FID with alternating current pulses applied before signal encoding exhibits the highest Bz signal-to-noise ratio and conductivity contrast. Additionally, compared with conventional conductivity imaging, the proposed method benefits from rapid SSFP acquisition without apparent loss of conductivity contrast. We successfully demonstrated the feasibility of the proposed method in estimating current-induced Bz and conductivity distribution. It can be a promising, rapid imaging strategy for quantitative conductivity imaging. © 2015 Wiley Periodicals, Inc.

  6. Corrosion/95 conference papers

    International Nuclear Information System (INIS)

    Anon.

    1995-01-01

    The papers in this conference represent the latest technological advances in corrosion control and prevention. The following subject areas are covered: cathodic protection in natural waters; materials for fossil fuel combustion and conversion systems; modern problems in atmospheric corrosion; innovative ideas for controlling the decaying infrastructure; deposits and their effects on corrosion in industry; volatile high temperature and non aqueous corrosion inhibitors; corrosion of light-weight and precoated metals for automotive application; refining industry corrosion; corrosion in pulp and paper industry; arctic/cold weather corrosion; materials selection for waste incinerators and associated equipment; corrosion measurement technology; environmental cracking of materials; advancing technology in the coating industry; corrosion in gas treating; green inhibition; recent advances in corrosion control of rail equipment; velocity effects and erosion corrosion in oil and gas production; marine corrosion; corrosion of materials in nuclear systems; underground corrosion control; corrosion in potable and industrial water systems in buildings and its impact on environmental compliance; deposit related boiler tube failures; boiler systems monitoring and control; recent developments and experiences in reactive metals; microbiologically influenced corrosion; corrosion and corrosion control for steel reinforced concrete; international symposium on the use of 12 and 13 Cr stainless steels in oil and gas production environments; subsea corrosion /erosion monitoring in production facilities; fiberglass reinforced pipe and tubulars in oilfield service; corrosion control technology in power transmission and distribution; mechanisms and methods of scale and deposit control; closing the loop -- results oriented cooling system monitoring and control; and minimization of aqueous discharge

  7. A process study of the interaction of tidal currents, tidal mixing and density gradients in a region of freshwater influence

    Science.gov (United States)

    Xing, Jiuxing; Chen, Shengli

    2017-08-01

    A three dimensional unstructured grid model of the west coast of Britain is used to study the process of the interaction of tidal currents, tidal mixing and density gradient in the Liverpool Bay region. Calculations with M2 tidal forcing and omitting freshwater discharge show that tidal currents in the region are strong (of order 1 ms- 1), with tidal current ellipses essentially rectilinear in the surface and bottom. In the absence of tidal forcing, the freshwater is confined to a thin surface layer. With the inclusion of tidal mixing the surface layer thickens, and in the shallow water area mixed layer occupies the whole water depth. This has a significant effect of reducing its lateral spread. A detailed study of time series of velocity, salinity and turbulence reveals that at flood tide, more saline water is advected into the coastal region and rapid vertical mixing occurs, whereas at ebb tide, fresher water is advected over more saline water. The induced strong pycnocline uncouples surface and bottom layers leading to more circular tidal ellipses which rotate in opposite directions in the vertical, as found in observations. The three dimensional nature of the model reveals that this process involves both horizontal and vertical density gradients, and shows significant horizontal variability in the Liverpool Bay region.

  8. Intracranial current density (LORETA) differences in QEEG frequency bands between depressed and non-depressed alcoholic patients.

    Science.gov (United States)

    Coutin-Churchman, Pedro; Moreno, Rocío

    2008-04-01

    To assess possible differences in intracranial source distribution of surface QEEG power between depressed and non-depressed alcoholic patients in order to find any symptom-related topographic features of physiopathologic relevance. Low-Resolution Electromagnetic Tomography (LORETA) for the delta, theta, alpha and beta bands of EEG spectra was estimated from 38 alcoholic patients, 20 with and 18 without clinical depression, in which QEEG showed decreased slow and increased beta activity diffusely. Statistical non-parametric mapping was used to compare depressed and non-depressed groups. Measures of intracranial current density in individual patients at areas of significant differences were correlated with BDI scores. Patients with clinical depression showed areas of significantly lower current density than non-depressed patients in delta band at left anterior temporal, left midtemporal (including amygdala and hippocampus), and both frontopolar cortices mostly on the right; and in theta band at bilateral parietal lobe, anterior cingulate and medial frontal cortex. No differences were found at alpha and beta band. Intracranial current density in delta band at left parahippocampal, left midfrontal cortex and right frontopolar cortex was negatively correlated with BDI score. Theta band also showed negative correlations with BDI at sites of significant differences. Diffusely decreased delta and theta activity in the surface QEEG of alcoholic patients has a different intracranial distribution linked to the presence or not of clinical depression that seems to reveal a dysfunctional neuronal state at several specific limbic and other cortical locations that have been related to a specific clinical disorder such as depression. These results provided further evidence on the effects of depression in the context of alcohol dependence, in this case decreased slow activity as a possible marker of neuronal damage secondary to alcohol toxicity, clinically expressed as depressive

  9. Corrosion Behavior of E690 High-Strength Steel in Alternating Wet-Dry Marine Environment with Different pH Values

    Science.gov (United States)

    Wu, W.; Hao, W. K.; Liu, Z. Y.; Li, X. G.; Du, C. W.; Liao, W. J.

    2015-12-01

    The corrosion behavior and mechanism of E690 high-strength steel in marine environment with different pH values were studied through electrochemical technology and long-term alternating wet-dry cycle experiments combined with SEM and XRD. Results showed that the corrosion current density of E690 high-strength steel gradually increased with decreased pH. After long-term tests in alternating wet-dry marine environment with various pH values, uniform corrosion mainly occurred on E690 steel, accompanied by vast corrosion pitting. Weight loss analysis demonstrated that corrosion rate decreased with increased pH. Moreover, corrosion mechanism varied with pH, and hydrogen-evolution reaction greatly increased the E690 steel corrosion rate at low pH. Meanwhile, the compositions of corrosion products slightly differed with pH; these products consisted of Fe3O4, Fe2O3, α-FeOOH, β-FeOOH, γ-FeOOH, and amorphous substances. However, the rust-layer density varied. Cr in the rust layer promoted the densification of rust layer and improved the decay resistance of E690 steel.

  10. The dual role of microbes in corrosion

    Science.gov (United States)

    Kip, Nardy; van Veen, Johannes A

    2015-01-01

    Corrosion is the result of a series of chemical, physical and (micro) biological processes leading to the deterioration of materials such as steel and stone. It is a world-wide problem with great societal and economic consequences. Current corrosion control strategies based on chemically produced products are under increasing pressure of stringent environmental regulations. Furthermore, they are rather inefficient. Therefore, there is an urgent need for environmentally friendly and sustainable corrosion control strategies. The mechanisms of microbially influenced corrosion and microbially influenced corrosion inhibition are not completely understood, because they cannot be linked to a single biochemical reaction or specific microbial species or groups. Corrosion is influenced by the complex processes of different microorganisms performing different electrochemical reactions and secreting proteins and metabolites that can have secondary effects. Information on the identity and role of microbial communities that are related to corrosion and corrosion inhibition in different materials and in different environments is scarce. As some microorganisms are able to both cause and inhibit corrosion, we pay particular interest to their potential role as corrosion-controlling agents. We show interesting interfaces in which scientists from different disciplines such as microbiology, engineering and art conservation can collaborate to find solutions to the problems caused by corrosion. PMID:25259571

  11. The dual role of microbes in corrosion.

    Science.gov (United States)

    Kip, Nardy; van Veen, Johannes A

    2015-03-01

    Corrosion is the result of a series of chemical, physical and (micro) biological processes leading to the deterioration of materials such as steel and stone. It is a world-wide problem with great societal and economic consequences. Current corrosion control strategies based on chemically produced products are under increasing pressure of stringent environmental regulations. Furthermore, they are rather inefficient. Therefore, there is an urgent need for environmentally friendly and sustainable corrosion control strategies. The mechanisms of microbially influenced corrosion and microbially influenced corrosion inhibition are not completely understood, because they cannot be linked to a single biochemical reaction or specific microbial species or groups. Corrosion is influenced by the complex processes of different microorganisms performing different electrochemical reactions and secreting proteins and metabolites that can have secondary effects. Information on the identity and role of microbial communities that are related to corrosion and corrosion inhibition in different materials and in different environments is scarce. As some microorganisms are able to both cause and inhibit corrosion, we pay particular interest to their potential role as corrosion-controlling agents. We show interesting interfaces in which scientists from different disciplines such as microbiology, engineering and art conservation can collaborate to find solutions to the problems caused by corrosion.

  12. Quench Analysis of High Current Density Nb3Sn Conductors in Racetrack Coil Configuration

    CERN Document Server

    Bajas, H; Bordini, B; Bottura, L; Izquierdo Bermudez, S; Feuvrier, J; Chiuchiolo, A; Perez, J C; Willering, G

    2015-01-01

    The luminosity upgrade of the Large Hadron Collider (HL-LHC) requires the development of new type of superconducting cables based on advanced Nb3Sn strands. In the framework of the FP7 European project EUCARD the cables foreseen for the HL-LHC project have been tested recently in a simplified racetrack coil configuration, the so-called Short Model Coil (SMC). In 2013 to 2014, two SMCs wound with 40-strand (RRP 108/127) cables, with different heat treatment processes, reached during training at 1.9 K a current and peak magnetic field of 15.9 kA, 13.9T,and 14.3 kA, 12.7 Trespectively. Using the measured signals from the voltage taps, the behavior of the quenches is analyzed in terms of transverse and longitudinal propagation velocity and hot spot temperature. These measurements are compared with both analytical and numerical calculations from adiabatic models.The coherence of the results from the presented independent methods helps in estimating the relevance of the material properties and the adiabatic assump...

  13. Carbon Corrosion at Pt/C Interface in Proton Exchange Membrane Fuel Cell Environment

    International Nuclear Information System (INIS)

    Choi, Min Ho; Beam, Won Jin; Park, Chan Jin

    2010-01-01

    This study examined the carbon corrosion at Pt/C interface in proton exchange membrane fuel cell environment. The Pt nano particles were electrodeposited on carbon substrate, and then the corrosion behavior of the carbon electrode was examined. The carbon electrodes with Pt nano electrodeposits exhibited the higher oxidation rate and lower oxidation overpotential compared with that of the electrode without Pt. This phenomenon was more active at 75 .deg. C than 25 .deg. C. In addition, the current transients and the corresponding power spectral density (PSD) of the carbon electrodes with Pt nano electrodeposits were much higher than those of the electrode without Pt. The carbon corrosion at Pt/C interface was highly accelerated by Pt nano electrodeposits. Furthermore, the polarization and power density curves of PEMFC showed degradation in the performance due to a deterioration of cathode catalyst material and Pt dissolution

  14. Visualizing the mechanism that determines the critical current density in polycrystalline superconductors using time-dependent Ginzburg-Landau theory

    Science.gov (United States)

    Carty, George J.; Hampshire, Damian P.

    2008-05-01

    In polycrystalline superconducting materials optimized for high critical current density (JC) in high magnetic fields, the mechanism that determines JC has long remained uncertain because of the complicated manner in which the fluxon-fluxon and fluxon-microstructure forces combine. In this work, the time-dependent Ginzburg-Landau equations are used to produce visualizations of fluxons at JC that show the disorder in the pinned part of the flux-line lattice and the motion of those fluxons along grain boundaries that cause dissipation. Calculated values of JC are consistent with experimental data.

  15. Simultaneous enhancement of open-circuit voltage, short-circuit current density, and fill factor in polymer solar cells

    Energy Technology Data Exchange (ETDEWEB)

    He, Zhicai; Zhong, Chengmei; Wu, Hongbin; Su, Shijian; Cao, Yong [Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640 (China); Huang, Xun; Chen, Liwei [Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, 398 Ruoshui Road, Suzhou Industrial Park, Suzhou 215123 (China); Wong, Wai-Yeung [Institute of Molecular Functional Materials (Areas of Excellence Scheme, University Grants Committee, Hong Kong) and Department of Chemistry and Centre for Advanced Luminescence Materials, Hong Kong Baptist University, Waterloo Road, Hong Kong (China)

    2011-10-25

    Simultaneous enhancement of open-circuit voltage, short-circuit current density, and fill factor in highly efficient polymer solar cells by incorporating an alcohol/water-soluble conjugated polymer as cathode interlayer is domonstrated. When combined with a low-bandgap polymer PTB7 as the electron donor material, the power efficiency of the devices is improved to certified 8.370%. Due to drastic improvement in efficiency and easy utilization, this method opens new opportunities for PSCs from various material systems to improve towards 10% efficiency. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  16. Fermion condensate and vacuum current density induced by homogeneous and inhomogeneous magnetic fields in (2+1) dimensions

    International Nuclear Information System (INIS)

    Raya, Alfredo; Reyes, Edward

    2010-01-01

    We calculate the condensate and the vacuum current density induced by external static magnetic fields in (2+1) dimensions. At the perturbative level, we consider an exponentially decaying magnetic field along one Cartesian coordinate. Nonperturbatively, we obtain the fermion propagator in the presence of a uniform magnetic field by solving the Schwinger-Dyson equation in the rainbow-ladder approximation. In the large flux limit, we observe that both these quantities, either perturbative (inhomogeneous) and nonperturbative (homogeneous), are proportional to the external field, in agreement with early expectations.

  17. Measurements of Pfirsch-Schlueter current and pressure profile for the high density ECH plasmas in Heliotron DR

    International Nuclear Information System (INIS)

    Morimoto, S.; Yanagi, N.; Nakasuga, M.; Obiki, T.; Iiyoshi, A.; Uo, K.

    1988-01-01

    The Pfirsch-Schlueter current and pressure profiles are estimated from magnetic measurements for high density electron cyclotron heating (ECH) plasmas (n-bar e =(2-3)x10 13 cm -3 , T e0 =200-400 eV, (β) 0 (1-(r/a) 2 ) s , is about two in macroscopically stable plasmas. A fast loss of plasma energy from the centre to the periphery is observed during the onset of the MHD instability. This method of measuring the pressure profile shape is simple and useful for heliotron type devices. (author). 20 refs, 8 figs, 1 tab

  18. Enhancement of short-circuit current density in polymer bulk heterojunction solar cells comprising plasmonic silver nanowires

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Yuzhao; Lin, Xiaofeng; Ou, Jiemei; Chen, Xudong, E-mail: cescxd@mail.sysu.edu.cn, E-mail: stszx@mail.sysu.edu.cn, E-mail: chenyj69@mail.sysu.edu.cn [Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education of China, Sun Yat-sen University, Guangzhou 510275 (China); Qing, Jian; Zhong, Zhenfeng; Zhou, Xiang, E-mail: cescxd@mail.sysu.edu.cn, E-mail: stszx@mail.sysu.edu.cn, E-mail: chenyj69@mail.sysu.edu.cn; Chen, Yujie, E-mail: cescxd@mail.sysu.edu.cn, E-mail: stszx@mail.sysu.edu.cn, E-mail: chenyj69@mail.sysu.edu.cn [State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-sen University, Guangzhou 510275 (China); Hu, Chenglong [Key Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of Education, Jianghan University, Wuhan 430056 (China)

    2014-03-24

    We demonstrate that the influence of plasmonic effects based on silver nanowires (Ag NWs) on the characteristics of polymer solar cells (PSCs). The solution-processed Ag NWs are situated at the interface of anode buffer layer and active layer, which could enhance the performance especially the photocurrent of PSCs by scattering, localized surface plasmon resonance, and surface plasmon polaritons. Plasmonic effects are confirmed by the enhancement of extinction spectra, external quantum efficiency, and steady state photoluminescence. Consequently, the short-circuit current density (J{sub sc}) and power conversion efficiency enhance about 24% and 18%, respectively, under AM1.5 illumination when Ag NWs plasmonic nanostructure incorporated into PSCs.

  19. Co-current Doping Effect of Nanoscale Carbon and Aluminum Nitride on Critical Current Density and Flux Pinning Properties of Bulk MgB2 Superconductors

    Science.gov (United States)

    Tripathi, D.; Dey, T. K.

    2018-01-01

    The effect of nanoscale aluminum nitride (n-AlN) and carbon (n-C) co-doping on superconducting properties of polycrystalline bulk MgB2 superconductor has been investigated. Polycrystalline pellets of MgB2 , MgB2 + 0.5 wt% AlN (nano), MgB_{1.99}C_{0.01} and MgB_{1.99}C_{0.01} + 0.5 wt% AlN (nano) have been synthesized by a solid reaction process under inert atmosphere. The transition temperature (TC) estimated from resistivity measurement indicates only a small decrease for C (nano) and co-doped MgB2 samples. The magnetic field response of investigated samples has been measured at 4, 10, and 20 K in the field range ± 6 T. MgB2 pellets co-doped with 0.5 wt% n-AlN and 1 wt% n-C display appreciable enhancement in critical current density (J_C ) of MgB2 in both low (≥ 3 times), as well as, high-field region (≥ 15 times). J_C versus H behavior of both pristine and doped MgB2 pellets is well explained in the light of the collective pinning model. Further, the normalized pinning force density f_p(= F_p/F_{pmax}) displays a fair correspondence with the scaling procedure proposed by Eisterer et al. Moreover, the scaled data of the pinning force density (i.e., f_p{-}h data) of the investigated pellets at different temperature are well interpreted by a modified Dew-Hughes expression reported by Sandu and Chee.

  20. Suppression of external quantum efficiency roll-off of nanopatterned organic-light emitting diodes at high current densities

    Energy Technology Data Exchange (ETDEWEB)

    Kuwae, Hiroyuki; Kasahara, Takashi [Nano-Science and Nano-Engineering, Waseda University, 3-4-1 Okubo, Shinjuku, Tokyo 169-8555 (Japan); JST, ERATO, Adachi Molecular Exciton Engineering Project, Kyushu University, 744 Motooka, Nishi, Fukuoka 819-0395 (Japan); Nitta, Atsushi; Yoshida, Kou; Inoue, Munetomo [Center for Organic Photonics and Electronics Research (OPERA), Kyushu University, 744 Motooka, Nishi, Fukuoka 819-0395 (Japan); Matsushima, Toshinori; Adachi, Chihaya, E-mail: adachi@cstf.kyushu-u.ac.jp [JST, ERATO, Adachi Molecular Exciton Engineering Project, Kyushu University, 744 Motooka, Nishi, Fukuoka 819-0395 (Japan); Center for Organic Photonics and Electronics Research (OPERA), Kyushu University, 744 Motooka, Nishi, Fukuoka 819-0395 (Japan); Shoji, Shuichi [Nano-Science and Nano-Engineering, Waseda University, 3-4-1 Okubo, Shinjuku, Tokyo 169-8555 (Japan); Mizuno, Jun [JST, ERATO, Adachi Molecular Exciton Engineering Project, Kyushu University, 744 Motooka, Nishi, Fukuoka 819-0395 (Japan); Research Organization for Nano and Life Innovation, Waseda University, 513 Waseda Tsurumaki-cho, Shinjuku, Tokyo 162-0041 (Japan)

    2015-10-21

    We developed organic light-emitting diodes (OLEDs) with nanopatterned current flow regions using electron-beam lithography with the aim of suppressing singlet–polaron annihilation (SPA). Nanopatterns composed of lines and circles were used in the current flow regions of nano-line and nano-dot OLEDs, respectively. Excitons partially escape from the current flow regions where SPA takes place. As such, current densities where external quantum efficiencies were half of their initial values (J{sub 0}) increased as line width and circle diameter were decreased to close to the exciton diffusion length. Circles were more efficient at enhancing exciton escape and increasing J{sub 0} than lines. The J{sub 0} increase in the nano-dot OLEDs containing nanopatterned circles with a diameter of 50 nm was approximately 41-fold that of a conventional OLED with a current flow region of 4 mm{sup 2}. The dependence of J{sub 0} on the size and shape of the nanopatterns was well explained by an SPA model that considered exciton diffusion. Nanopatterning of OLEDs is a feasible method of obtaining large J{sub 0}.

  1. Detection of microbiologically influenced corrosion by electrochemical noise transients

    NARCIS (Netherlands)

    Homborg, A.M.; Morales, C.F. Leon; Tinga, Tiedo; de Wit, J.H.W.; Mol, J.M.C.

    2014-01-01

    This work investigates the electrochemical processes involved in pitting corrosion induced by microbiologically influenced corrosion by using time-resolved instantaneous frequency information of electrochemical current noise (ECN) transients obtained from Hilbert spectra. In addition to the

  2. Minimizing corrosive action in timber bridges treated with waterborne preservatives

    Science.gov (United States)

    Samuel L. Zelinka; Douglas R. Rammer; James P. Wacker

    2007-01-01

    This work will briefly review published literature and current research activities on the corrosion of metals in contact with wood treated with waterborne alternatives to CCA. In addition, recommendations to minimize these corrosive effects in timber bridges will be discussed.

  3. Corrosion rates of fasteners in treated wood exposed to 100% relative humidity

    Science.gov (United States)

    Samuel L. Zelinka; Douglas R. Rammer

    2009-01-01

    In the past, gravimetric corrosion data for fasteners exposed to treated wood has been reported as a percent weight loss. Although percent weight loss is a valid measure of corrosion for comparing identical fasteners, it can distort the corrosion performance of fasteners with different geometries and densities. This report reevaluates a key report on the corrosiveness...

  4. V-I curves and plasma parameters in a high density DC glow discharge generated by a current-source

    International Nuclear Information System (INIS)

    Granda-Gutierrez, E E; Lopez-Callejas, R; Piedad-Beneitez, A de la; BenItez-Read, J S; Pacheco-Sotelo, J O; Pena-Eguiluz, R; A, R Valencia; Mercado-Cabrera, A; Barocio, S R

    2008-01-01

    Nitrogen DC glow discharges, conducted in a cylindrical geometry, have been characterized using a new current-source able to provide 10 -3 - 3 A for the sustainment of the discharge, instead of a conventional voltage-source. The V-I characteristic curves obtained from these discharges were found to fit the general form i(v) = A(p)v k(p) , whereby the plasma itself can be modeled as a voltage-controlled current-source. We conclude that the fitting parameters A and k, which mainly depend on the gas pressure p, are strongly related to the plasma characteristics, so much so that they can indicate the pressure interval in which the maximum plasma density is located, with values in the order of 10 16 m -3 at reduced discharge potential (300-600 V) and low working pressure (10 -1 - 10 1 Pa)

  5. Development of a phosphating process for corrosion protection in NdFeB magnets

    International Nuclear Information System (INIS)

    Silva, Adonis Marcelo Saliba

    2001-01-01

    NdFeB magnets are important materials, which produce better energy efficiency in electrical devices, but they are rather vulnerable to corrosion. In this study, a phosphating treatment for protection against corrosion of NdFeB magnets has been investigated. Phosphating is generally used as a pretreatment in the application of protective coatings. This treatment increases the corrosion assistance in defective areas of the coating as well as improves the adhesion between coating and substrate. A commercial NdFeB magnet produced by powder metallurgy has been used and the effect of the following parameters on phosphating was studied: time of phosphating; pH of phosphating solution; anodic polarization and molybdate addition to the phosphating solution. The results showed a significant increase in the corrosion resistance of magnets phosphated in a solution concentrated between 10-20 g/L NaH 2 PO 4 , pH in the range of 3 to 4.6, acidulated preferably with H 3 PO 4 at room temperature (20±1) deg C. Conversion coatings formed at solutions of pH 3.8 showed better corrosion resistance. Phosphating times longer than 4 hours increased the magnet corrosion resistance 10 to 20 times. This resistance improves with higher immersion times. Anodic polarization of the magnet in the range 200-400 mV SCE accelerated phosphating. Results indicated that molybdate interacts preferentially with Nd rich phase of the magnet. In addition to the newly developed technology in this work for NdFeB corrosion protection, two methodologies have been introduced to facilitate electrochemical analyses: selection of samples of similar electrochemical behavior, based on the current density after 200s of constant anodic polarization; and evaluation of the corrosion protection provided by conversion coatings by monitoring of gas evolution during corrosion in acid solution. (author)

  6. Corrosion of high purity copper as engineering barrier in deep geological repositories

    International Nuclear Information System (INIS)

    Ochoa, Maité; Rodríguez Martín, A.; Farina Silvia, B.

    2013-01-01

    Pure copper with oxygen content below 5 ppm (to minimize segregation at grain boundaries) and doped with phosphorus (to increase creep resistance) is the chosen material for the corrosion-resistant barrier of the High Level Radioactive 2 Wastecontainers in the Swedish and Finnish repository models. These models include the construction of the repository below the water table, which is a reducing environment in which copper has excellent resistance to general and localized corrosion in aqueous electrolytes. The aim of this work is contribute to determine the durability of the material, given that deep geological repositories of HLW are designed to ensure the protection of the environment for periods of hundreds of thousands years. As a first step in a more general analysis the effects of chloride, one of the main aggressive species of corrosion, are evaluated. To this purpose corrosion potential was determined and anodic polarization curves were performed in deaerated solutions varying the chloride concentration between 0.01 and 1M and the temperature between 30 and 90°C. Several electrochemical techniques were used: the evolution of corrosion potential was measured, anodic polarization curves were obtained and electrochemical impedance tests were performed. The analysis was complemented with microscopic observations of the type of corrosive attack, as well as determinations of the eventual corrosion products formed using Energy-Dispersive X-ray Analysis (EDS). Results show that the corrosion potential decreases with the increase of temperature and with the increase of chloride concentration. A correlation of the corrosion potential as a function of temperature and chloride concentration was obtained, with the purpose of making predictions in variable conditions.The current density increases both with temperature and with chloride concentration. A pitting potential is observed in certain conditions. (author)

  7. The effect of some metallurgical factors on the corrosion behaviour of austenitic stainless steels in 3% NaCl aqueous solutions

    International Nuclear Information System (INIS)

    El-Sayed, A.A.; Morsy, S.M.; El-Raghy, S.M.

    1979-01-01

    The effect of cold work and subsequent heat treatment on the corrosion behaviour of austenitic stainless steels in 3% NaCl aqueous solutions was studied. Cold work was found to increase the corrosion rate, and heat treatment at 1050 C followed by water-quenching was found reduce to the rate of attack. The increase in the corrosion rate accompanied with a shift in the less noble direction of the steady state potential, an increase in the exchange current density and a decrease in the value of the activation energy. The results indicated that the corrosion potentials are less noble than the critical potentials for pitting, and they are discussed in terms of a simple dissolution process. A correlation is made between the corrosion rate, as expresses in weight loss, and the electrode properties of the corroding material

  8. Corrosion study of Fe-based bulk metallic glasses in chloride medium

    International Nuclear Information System (INIS)

    Waqas, M.U.

    2010-01-01

    Bulk metallic glasses (amorphous metals) are an emerging class of alloys due to their unique set of properties. They exhibit excellent mechanical strength, high hardness and corrosion resistance. Unlike other new materials, which are developed to fulfill a particular need, BMGs came to existence without any application, so the uses of BMGs are yet to be exploited. Before putting BMGs into applications, their properties must be fully understood, particularly the corrosion resistance against a working environment. Fe-based amorphous alloys are particularly important for their future use as structural materials due to their high strength and cheap raw materials. Some Fe-based amorphous alloys exhibit excellent soft magnetic properties, which make them feasible to be used as transformer materials. Some compositions are also competitive to replace the existing bio-materials like 316L SS due to their better biocompatibility. Fe-based amorphous alloys can also be used as thermal-spray coatings due to their unchanged corrosion resistance as compared to bulk alloy. Many electrochemical studies have been done to investigate the corrosion resistance of Fe- based BMG that showed its excellent corrosion resistance. Still not enough data is available and further work is needed to be done in this field. In the present study, corrosion of Fe/sub 50/Cr/sub 14/Mo/sub 14/C/sub 14/B/sub 6/X/sub 2/ (X = Y, Gd, and Dy), designated as S1, S2 and S3 respectively, was investigated in 4M NaCI solution. The corrosion study was done using potentiodynamic polarization test and accelerated corrosion test at a current density of 6mA.cm/sup -2/. Following this; corrosion morphology was investigated by scanning electron microscope, while compositional analysis was done by energy dispersive x-ray spectroscope (EDX) attached with SEM. S1 and S3 showed similar corrosion behavior with S3 having the highest corrosion resistance while S2 have different corrosion behavior as well as least corrosion

  9. Inhibitive Behaviour of Corrosion of Aluminium Alloy in NaCl by Mangrove Tannin

    International Nuclear Information System (INIS)

    Solhan Yahya; Afidah Abdul Rahim; Affaizza Mohd Shah; Rohana Adnan

    2011-01-01

    Anticorrosion potential of mangrove tannins on aluminium alloys AA6061 in NaCl solution has been studied using potentiodynamic polarisation method and scanning electron microscopy (SEM). The study was carried out in different pH of corrosive medium in the absence and presence of various concentrations of tannin. The corrosion inhibition behaviour of the mangrove tannin on AA6061 aluminium alloy corrosion was found to be dependant on the pH of NaCl solution. Our results showed that the inhibition efficiency increased with increasing tannins concentration in chloride solution at pH 6. Treatment of aluminium alloy 6061 with all concentrations of mangrove tannins reduced the current density, thus decreased the corrosion rate. Tannins behaved as mixed inhibitors at pH 6 and reduction in current density predominantly affected in cathodic reaction. Meanwhile, at pH 12, addition of tannins shifted the corrosion potential to more cathodic potentials and a passivating effect was observed in anodic potentials. SEM studies have shown that the addition of tannins in chloride solution at pH 12 reduced the surface degradation and the formation of pits. (author)

  10. Topographic controls on pyroclastic density current dynamics: Insight from 18 May 1980 deposits at Mount St. Helens, Washington (USA)

    Science.gov (United States)

    Brand, Brittany D.; Bendaña, Sylvana; Self, Stephen; Pollock, Nicholas

    2016-07-01

    Our ability to interpret the deposits of pyroclastic density currents (PDCs) is critical for understanding the transport and depositional processes that control PDC dynamics. This paper focuses on the influence of slope on flow dynamics and criticality as recorded in PDC deposits from the 18 May 1980 eruption of Mt. St. Helens (USA). PDC deposits are found along the steep flanks (10°-30°) and across the pumice plain ( 5°) up to 8 km north of the volcano. Granulometry, componentry and descriptions of depositional characteristics (e.g., bedform morphology) are recorded with distance from source. The pumice plain deposits are primarily thick (3-12 m), massive and poorly-sorted, and represent deposition from a series of concentrated PDCs. By contrast, the steep flank deposits are stratified to cross-stratified, suggesting deposition from PDCs where turbulence strongly influenced transport and depositional processes. We propose that acceleration of the concentrated PDCs along the steep flanks resulted in thinning of the concentrated, basal region of the current(s). Enhanced entrainment of ambient air, and autofluidization from upward fluxes of air from substrate interstices and plunging breakers across rugged, irregular topography further inflated the currents to the point that the overriding turbulent region strongly influenced transport and depositional mechanisms. Acceleration in combination with partial confinement in slot canyons and high surface roughness would also increase basal shear stress, further promoting shear and traction transport in the basal region of the current. Conditions along the steep flank resulted in supercritical flow, as recorded by regressive bedforms, which gradually transitioned to subcritical flow downstream as the concentrated basal region thickness increased as a function of decreasing slope and flow energy. We also find that (1) PDCs were erosive into the underlying granular substrate along high slopes (> 25°) where currents were

  11. A high critical current density MOCVD coated conductor with strong vortex pinning centers suitable for very high field use

    International Nuclear Information System (INIS)

    Chen, Z; Kametani, F; Larbalestier, D C; Chen, Y; Xie, Y; Selvamanickam, V

    2009-01-01

    We have made extensive low temperature and high field evaluations of a recent 2.1 μm thick coated conductor (CC) grown by metal-organic chemical vapor deposition (MOCVD) with a view to its use for high field magnet applications, for which its very strong Hastelloy substrate makes it very suitable. This conductor contains dense three-dimensional (Y,Sm) 2 O 3 nanoprecipitates, which are self-aligned in planes tilted ∼7 deg. from the tape plane. Very strong vortex pinning is evidenced by high critical current density J c values of ∼3.1 MA cm -2 at 77 K and ∼43 MA cm -2 at 4.2 K, and by a strongly enhanced irreversibility field H irr , which reaches that of Nb 3 Sn (∼28 T at 1.5 K) at 60 K, even in the inferior direction of H parallel c axis. At 4.2 K, J c values are ∼15% of the depairing current density J d , much the highest of any superconductor suitable for magnet construction.

  12. A high critical current density MOCVD coated conductor with strong vortex pinning centers suitable for very high field use

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Z; Kametani, F; Larbalestier, D C [National High Magnetic Field Laboratory, Florida State University, Tallahassee, FL 32310 (United States); Chen, Y; Xie, Y; Selvamanickam, V [SuperPower Incorporated, Schenectady, NY 12304 (United States)], E-mail: zhijun@asc.magnet.fsu.edu

    2009-05-15

    We have made extensive low temperature and high field evaluations of a recent 2.1 {mu}m thick coated conductor (CC) grown by metal-organic chemical vapor deposition (MOCVD) with a view to its use for high field magnet applications, for which its very strong Hastelloy substrate makes it very suitable. This conductor contains dense three-dimensional (Y,Sm){sub 2}O{sub 3} nanoprecipitates, which are self-aligned in planes tilted {approx}7 deg. from the tape plane. Very strong vortex pinning is evidenced by high critical current density J{sub c} values of {approx}3.1 MA cm{sup -2} at 77 K and {approx}43 MA cm{sup -2} at 4.2 K, and by a strongly enhanced irreversibility field H{sub irr}, which reaches that of Nb{sub 3}Sn ({approx}28 T at 1.5 K) at 60 K, even in the inferior direction of H parallel c axis. At 4.2 K, J{sub c} values are {approx}15% of the depairing current density J{sub d}, much the highest of any superconductor suitable for magnet construction.

  13. Microstructural analysis of mass transport phenomena in gas diffusion media for high current density operation in PEM fuel cells

    Science.gov (United States)

    Kotaka, Toshikazu; Tabuchi, Yuichiro; Mukherjee, Partha P.

    2015-04-01

    Cost reduction is a key issue for commercialization of fuel cell electric vehicles (FCEV). High current density operation is a solution pathway. In order to realize high current density operation, it is necessary to reduce mass transport resistance in the gas diffusion media commonly consisted of gas diffusion layer (GDL) and micro porous layer (MPL). However, fundamental understanding of the underlying mass transport phenomena in the porous components is not only critical but also not fully understood yet due to the inherent microstructural complexity. In this study, a comprehensive analysis of electron and oxygen transport in the GDL and MPL is conducted experimentally and numerically with three-dimensional (3D) microstructural data to reveal the structure-transport relationship. The results reveal that the mass transport in the GDL is strongly dependent on the local microstructural variations, such as local pore/solid volume fractions and connectivity. However, especially in the case of the electrical conductivity of MPL, the contact resistance between carbon particles is the dominant factor. This suggests that reducing the contact resistance between carbon particles and/or the number of contact points along the transport pathway can improve the electrical conductivity of MPL.

  14. Magnetic properties and critical current density of bulk MgB2 polycrystalline with Bi-2212 addition

    International Nuclear Information System (INIS)

    Shen, T M; Li, G; Zhu, X T; Cheng, C H; Zhao, Y

    2005-01-01

    Bulk samples of MgB 2 were prepared with 0, 3, 5, and 10 wt% Bi 2 Sr 2 CaCu 2 O 8 (Bi-2212) particles, added using a simple solid-state reaction route in order to investigate the effect of inclusions of a material with higher T c than the superconducting matrix. The density, diamagnetic signal, and critical current density, J c , of the samples change significantly with the doping level. It is found that J c is significantly enhanced by the Bi-2212 addition. Microstructural analysis indicates that a small amount of Bi-2212 is decomposed into Cu 2 O and other impurity phases while a significant amount of unreacted Bi-2212 particles remains in MgB 2 matrix, and these act as effective pinning centres for vortices. The enhanced pinning force is mainly attributable to these highly dispersed inclusions inserted in the MgB 2 grains. Despite the effectiveness of the high-T c inclusions in increasing superconducting critical currents in our experiment, our results seem to demonstrate the superiority of attractive centres over repulsive ones. A pinning mechanism is proposed to account for the contribution of this type of pinning centre in MgB 2 superconductors. (rapid communication)

  15. Stress-Corrosion Cracking Property of Aluminum-Magnesium Alloy Processed by Equal-Channel Angular Pressing

    Directory of Open Access Journals (Sweden)

    Hiroaki Nakano

    2012-01-01

    Full Text Available Stress-corrosion cracking property of an aluminum-magnesium alloy processed by equal-channel angular pressing (ECAP was investigated by a slow strain-rate tensile technique in a 3% NaCl solution of pH 4.2 at 303 K. The maximum stress and elongation of the Al-Mg alloy were lower in the NaCl solution than in air. The stress-corrosion cracking property was evaluated by the decrease ratio of maximum stress and elongation of the Al-Mg alloy with NaCl solution, (max and (, respectively. (max and ( were lower with ECAP than without it, showing that the susceptibility of stress-corrosion cracking decreased with ECAP. The polarization curve and time dependence of the anodic current density at constant potential of the Al-Mg alloy in the NaCl solution revealed that the anodic current density was lower with ECAP than without it, or the corrosion resistance of the Al-Mg alloy was improved by ECAP. The decrease in stress-corrosion crack susceptibility of the Al-Mg alloy with ECAP is attributed to an improvement in corrosion resistance afforded by ECAP.

  16. Study on lower hybrid current drive efficiency at high density towards long-pulse regimes in Experimental Advanced Superconducting Tokamak

    International Nuclear Information System (INIS)

    Li, M. H.; Ding, B. J.; Zhang, J. Z.; Gan, K. F.; Wang, H. Q.; Zhang, L.; Wei, W.; Li, Y. C.; Wu, Z. G.; Ma, W. D.; Jia, H.; Chen, M.; Yang, Y.; Feng, J. Q.; Wang, M.; Xu, H. D.; Shan, J. F.; Liu, F. K.; Peysson, Y.

    2014-01-01

    Significant progress on both L- and H-mode long-pulse discharges has been made recently in Experimental Advanced Superconducting Tokamak (EAST) with lower hybrid current drive (LHCD) [J. Li et al., Nature Phys. 9, 817 (2013) And B. N. Wan et al., Nucl. Fusion 53, 104006 (2013).]. In this paper, LHCD experiments at high density in L-mode plasmas have been investigated in order to explore possible methods of improving current drive (CD) efficiency, thus to extend the operational space in long-pulse and high performance plasma regime. It is observed that the normalized bremsstrahlung emission falls much more steeply than 1/n e-av (line-averaged density) above n e-av  = 2.2 × 10 19  m −3 indicating anomalous loss of CD efficiency. A large broadening of the operating line frequency (f = 2.45 GHz), measured by a radio frequency (RF) probe located outside the EAST vacuum vessel, is generally observed during high density cases, which is found to be one of the physical mechanisms resulting in the unfavorable CD efficiency. Collisional absorption of lower hybrid wave in the scrape off layer (SOL) may be another cause, but this assertion needs more experimental evidence and numerical analysis. It is found that plasmas with strong lithiation can improve CD efficiency largely, which should be benefited from the changes of edge parameters. In addition, several possible methods are proposed to recover good efficiency in future experiments for EAST

  17. Recognition and Analysis of Corrosion Failure Mechanisms

    OpenAIRE

    Steven Suess

    2006-01-01

    Corrosion has a vast impact on the global and domestic economy, and currently incurs losses of nearly $300 billion annually to the U.S. economy alone. Because of the huge impact of corrosion, it is imperative to have a systematic approach to recognizing and mitigating corrosion problems as soon as possible after they become apparent. A proper failure analysis includes collection of pertinent background data and service history, followed by visual inspection, photographic documentation, materi...

  18. Effect of compressive deformation on thermal and corrosive properties of Zr61.7Al8Ni13Cu17Sn0.3 bulk metallic glass

    Science.gov (United States)

    Xu, Yuanli; Shi, Bo

    2018-03-01

    The effect of compressive deformation on thermal stability and corrosive property of Zr61.7Al8Ni13Cu17Sn0.3 bulk metallic glass with a strain of 80% was investigated in this work. The corresponding thermal stability is found to decrease after deformation and this can probably be attributed to the reduction of the viscosity and the increase of the Gibbs free energy after compressive deformation. In addition, the corrosion current density increases and this suggests that the corrosion resistance decreases for the deformed sample in comparison with the as-cast sample.

  19. Surface engineering for corrosion and wear resistance

    National Research Council Canada - National Science Library

    Davis, J. R

    2001-01-01

    ... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .16 Pitting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .19 Crevice Corrosion . . . . . . . . ....

  20. Current source density of sustained potential shifts associated with electrographic seizures and with spreading depression in rat hippocampus.

    Science.gov (United States)

    Wadman, W J; Juta, A J; Kamphuis, W; Somjen, G G

    1992-01-20

    The membrane currents responsible for the sustained potential shifts associated with electrographic seizures and with spreading depression in hippocampus were studied in the anesthetized rat. Probes incorporating 16 sensors in a straight line, spaced at 150-microns distances, were recording the potential changes with DC-coupled amplifiers in CA1 and dentate gyrus (DG) of one hemisphere. Seizures and spreading depression were provoked by repetitive stimulation of different afferent pathways. Seizures always began in DG before CA1, regardless of the pathway stimulated. Tonic seizures were associated with a sustained negative potential shift that was largest in the cell body layers. Current source density was computed from these recordings and confirmed the presence of a current sink limited to the cell body layer throughout the duration of electrographic seizures. Spreading depression was associated with a very large sink located in the layer of apical dendrites, maximal among the proximal segment of dendrites, to which the cell body layer served as a source. We conclude that seizures are associated with an inward current in neuron cell bodies, probably flowing through membrane channels of as yet no know physiological function.

  1. Corrosion of beryllium oxide

    International Nuclear Information System (INIS)

    Elston, J.; Caillat, R.

    1958-01-01

    Data are reported on the volatilization rate of beryllium oxide in moist air depending on temperature and water vapour concentration. They are concerned with powder samples or sintered shapes of various densities. For sintered samples, the volatilization rate is very low under the following conditions: - temperature: 1300 deg. C, - water vapour concentration in moist air: 25 g/m 3 , - flow rate: 12 I/hour corresponding to a speed of 40 m/hour on the surface of the sample. For calcinated powders (1300 deg. C), grain growth has been observed under a stream of moist air at 1100 deg. C. For instance, grain size changes from 0,5 to at least 2 microns after 500 hours of exposure at this temperature. Furthermore, results data are reported on corrosion of sintered beryllium oxide in pressurized water. At 250 deg. C, under a pressure of 40 kg/cm 2 water is very slightly corrosive; however, internal strains are revealed. Finally, some features on the corrosion in liquid sodium are exposed. (author) [fr

  2. Corrosion Testing Facility

    Data.gov (United States)

    Federal Laboratory Consortium — The Corrosion Testing Facility is part of the Army Corrosion Office (ACO). It is a fully functional atmospheric exposure site, called the Corrosion Instrumented Test...

  3. Vehicle accelerated corrosion test procedures for automotive in Malaysia

    Directory of Open Access Journals (Sweden)

    Anuar Liza

    2017-01-01

    Full Text Available An accelerated corrosion test, known as proving ground accelerated test, is commonly performed by automotive manufacturers to evaluate the corrosion performance of a vehicle. The test combines corrosion and durability inputs to detect potential failures that may occur during in-service conditions. Currently, the test is conducted at an external test center overseas. Such test is aimed to simulate the effects of one year accelerated corrosion in severe corrosive environment of the north-east and south east of America. However, the test results obtained do not correlate with the actual corrosion conditions observed in the Malaysian market, which is likely attributed to the different test environment of the tropical climate of vehicles in service. Therefore, a vehicle accelerated corrosion test procedure that suits the Malaysian market is proposed and benchmarked with other global car manufacturers that have their own dedicated corrosion test procedure. In the present work, a test track is used as the corrosion test ground and consists of various types of roads for structural durability exposures. Corrosion related facilities like salt trough, mud trough and gravel road are constructed as addition to the existing facilities. The establishment of accelerated corrosion test facilities has contributed to the development of initial accelerated corrosion test procedure for the national car manufacturer. The corrosion exposure is monitored by fitting test coupons at the underbody of test vehicle using mass loss technique so that the desired corrosion rate capable of simulating the real time corrosion effects for its target market.

  4. Microelectrode array analysis of hippocampal network dynamics following theta-burst stimulation via current source density reconstruction by Gaussian interpolation.

    Science.gov (United States)

    Kim, Hyun-Bum; Oh, Tong-In; Swanberg, Kelley M; Lee, Mun-Bae; Kim, Tae-Woo; Woo, Eung-Je; Park, Ji-Ho; Kwon, Oh-In

    2016-05-01

    Multielectrode arrays (MEAs) have been used to understand electrophysiological network dynamics by recording real-time activity in groups of cells. The extent to which the collection of such data enables hypothesis testing on the level of circuits and networks depends largely on the sophistication of the analyses applied. We studied the systemic temporal variations of endogenous signaling within an organotypic hippocampal network following theta-burst stimulation (TBS) to the Schaffer collateral-commissural pathways. The recovered current source density (CSD) information from the raw grid of extracellular potentials by using a Gaussian interpolation method increases spatial resolution and avoids border artifacts by numerical differentials. We compared total sink and source currents in DG, CA3, and CA1; calculated accumulated correlation coefficients to compare pre- with post-stimulation CSD dynamics in each region; and reconstructed functional connectivity maps for regional cross-correlations with respect to temporal CSD variations. The functional connectivity maps for potential correlations pre- and post-TBS were compared to investigate the neural network as a whole, revealing differences post-TBS. Previous MEA work on plasticity in hippocampal evoked potentials has focused on synchronicity across the hippocampus within isolated subregions. Such analyses ignore the complex relationships among diverse components of the hippocampal circuitry, thus failing to capture network-level behaviors integral to understanding hippocampal function. The proposed method of recovering current source density to examine whole-hippocampal function is sensitive to experimental manipulation and is worth further examination in the context of network-level analyses of neural signaling. Copyright © 2016 Elsevier B.V. All rights reserved.

  5. Corrosion evaluation of materials in sulfur compound environments

    International Nuclear Information System (INIS)

    Maoying Teng; Iuanjou Yang

    1993-01-01

    The para-toluene sulfonic acid (PTSA) serves as a catalyst in producing diethylene glycol dibenzoate (DEGDB) and decomposes with increasing time at elevated temperature. Due to the presence of bisulfite ion, it is important to evaluate the corrosion properties of materials in this metastable environments. A potentiodynamic method was used to screen materials' properties in a PTSA solution. A surface analysis technique was also performed to investigate the oxide films. The critical current density and passive current density were substantially reduced when Fe alloyed with Cr and/or Ni. With the addition of Mo in Fe-Ni-Cr alloys, the critical current density was lowered further to show the beneficial effect of alloyed Mo. A plot of the corrosion rate of materials in DEGDB as a function of Ni/Cr ratio shows the linearity with increasing Ni/Cr ratio, disregard the type of materials. The corrosion rate of pure chromium can be estimated as ∼ 2.0 mpy by extrapolation of the linearity to Ni/Cr = 0. This is also the minimum corrosion rate that even Fe-Ni-Cr alloys were alloyed with Mo. Surface analysis results showed that the dissolution of Fe and/or Ni leads to a higher surface chromium content and results in the formation of chromium oxide on metal surface. This chromium oxide then prevents metal from corrosion. It is concluded that the higher the nickel content the higher the corrosion rate of materials. The composition potential-pH diagrams for Fe-S-H 2 O and Ni-S-H 2 O show that the stability fields of FeS and NiS cover a wide range of pH. The effect of sulfur or sulfide ions in promoting dissolution of Fe and/or Ni are highly possible. The activating influence of sulfur compounds on Ni is stronger than that of Fe, although the highly electronic conductivity of iron sulfides can catalyze the cathodic reaction. Undoubtedly, sulfur compound strongly depassivates high Ni contents materials

  6. Multiscale Electrochemical Investigation of the Corrosion Resistance of Various Alloys Used in Dental Prostheses

    Science.gov (United States)

    Iacoban, Sorin; Mareci, Daniel; Bolat, Georgiana; Munteanu, Corneliu; Souto, Ricardo Manuel

    2015-04-01

    The electrochemical behavior of Ag-Pd (Paliag), Ni-Cr (Heraenium NA), and Co-Cr (Heraenium CE) alloys used in dental prosthetics construction of crowns and bridges was studied in 0.9 pct NaCl solution at 298 K (25 °C). The localized electrochemical characteristics related to corrosion resistance and eventual breakdown of the protecting oxide layers were investigated by scanning electrochemical microscopy (SECM), whereas potentiodynamic polarization and electrochemical impedance spectroscopy techniques were employed to establish oxide stability. When the corrosion resistance of the alloys was evaluated by means of the corrosion current value determined around their corresponding open circuit potential in 0.9 pct NaCl solution, good protection can be expected resulting from their spontaneous passivation (low current densities in the order of tenths of μA cm-2). The polarization resistance of all the samples increased with immersion time, in the sequence Ag-Pd Ag-Pd instead.

  7. The ground layer of the Campanian Ignimbrite: an example of deposition from a dilute pyroclastic density current

    Science.gov (United States)

    Scarpati, Claudio; Sparice, Domenico; Perrotta, Annamaria

    2015-11-01

    A thin, fines-poor, and lithic- and crystal-rich layer locally present, from proximal to distal areas, at the base of the pyroclastic density current deposits of the Campanian Ignimbrite eruption (39 ka), sourced from Campi Flegrei (Italy), is interpreted as a ground layer (GL). It has an average lithic and crystal content of 57 and 25 wt%, respectively. The GL rests on a paleosol or an early fall deposit and is capped by a stratified ash deposit. It is bounded by erosion surfaces and its thickness does not change systematically from the source. The occurrences of GL in places separated from the source by a stretch of sea and the angular to sub-angular shape of the lithic clasts are consistent with deposition from a dilute current. The presence of the GL up to 971 m above sea level and beyond 1400-1500-m-high mountain ridges, allows estimation of the thickness of the PDC as having been at least 1.5 km. To investigate the parameters influencing the transport and emplacement mechanisms that produced the GL, we use field and sedimentological data (grain size and componentry), from samples collected between 30 and 70 km from the source. The progressive decrease in maximum lithic clast and median grain-size with distance from the vent and increasing altitude corresponds to lateral and vertical grading of lithic clasts within the current. The coarser clasts moved toward the basal part of the current, settling in more proximal areas and at low altitude. Farther from the vent (45-50 km), the lower part of the pyroclastic current impacted against the reliefs surrounding the Campanian Plain, causing the emplacement of coarser and more poorly sorted deposits on slopes oriented toward the source.

  8. Corrosion Reliability of Electronic Systems

    DEFF Research Database (Denmark)

    Ambat, Rajan; Jensen, Stine G.; Møller, Per

    2008-01-01

    Inherently two factors namely multi-material usage and potential bias makes electronic devices susceptible to corrosion if exposed to humid conditions. The problem is compounded today due to miniaturization and contamination effects. The reduction in size of the components and close spacing...... on a Printed Circuit Board (PCB) for high density packing has greatly increased the risk of corrosion under humid conditions. An important issue is the failures due to electrolytic metal migration. This paper describes an investigation of the electrolytic migration of Sn-Pb solder lines on PCBs in humid...

  9. Generator localization by current source density (CSD): Implications of volume conduction and field closure at intracranial and scalp resolutions

    Science.gov (United States)

    Tenke, Craig E.; Kayser, Jürgen

    2012-01-01

    The topographic ambiguity and reference-dependency that has plagued EEG/ERP research throughout its history are largely attributable to volume conduction, which may be concisely described by a vector form of Ohm’s Law. This biophysical relationship is common to popular algorithms that infer neuronal generators via inverse solutions. It may be further simplified as Poisson’s source equation, which identifies underlying current generators from estimates of the second spatial derivative of the field potential (Laplacian transformation). Intracranial current source density (CSD) studies have dissected the “cortical dipole” into intracortical sources and sinks, corresponding to physiologically-meaningful patterns of neuronal activity at a sublaminar resolution, much of which is locally cancelled (i.e., closed field). By virtue of the macroscopic scale of the scalp-recorded EEG, a surface Laplacian reflects the radial projections of these underlying currents, representing a unique, unambiguous measure of neuronal activity at scalp. Although the surface Laplacian requires minimal assumptions compared to complex, model-sensitive inverses, the resulting waveform topographies faithfully summarize and simplify essential constraints that must be placed on putative generators of a scalp potential topography, even if they arise from deep or partially-closed fields. CSD methods thereby provide a global empirical and biophysical context for generator localization, spanning scales from intracortical to scalp recordings. PMID:22796039

  10. Influence of thermal, morphological and measuring variables on the thermal runaway of superconducting films under high current densities

    International Nuclear Information System (INIS)

    Ferro, G; Maza, J; Ramallo, M V; Veira, J A; Vidal, F

    2009-01-01

    We study the abrupt jump in voltage seen in the current-voltage characteristics of high-T c films at current densities, J*, around 2-3 times the critical one, and for perturbations with characteristic times in the millisecond range. Customarily, even for these long characteristic times, the voltage jump has been ascribed to an electrodynamic vortex instability. Recent results based on finite-element analyses show quantitatively that smooth, i.e., jumpfree isothermal curves may show up themselves as the jumping, i.e., discontinuous curves experimentalists observe, once the nonlinearity, thermal feedback and measurement rate are properly accounted for. The thermal nature of the transition to a highly dissipative state in high-T c superconductors at zero magnetic field makes the control of the instability transition easier in that there are more parameters available to experimentalists that may be tuned to tailor the phenomenon. This is specially relevant for devices working on their superconducting borderline as current-limiters or even magnets. Here we explore through finite-element analysis the role of film geometry, measurement rate and substrate thermal conductivity in the triggering of the thermal runaway.

  11. Bone density loss on computed tomography at 3-year follow-up in current compared to former male smokers

    International Nuclear Information System (INIS)

    Pompe, E.; Bartstra, J.; Verhaar, H.J.; Koning, H.J. de; Aalst, C.M. van der; Oudkerk, M.; Vliegenthart, R.; Lammers, J.-W.J.; Jong, P.A. de; Mohamed Hoesein, F.A.A.

    2017-01-01

    Objectives: Cigarette smoking negatively affects bone quality and increases fracture risk. Little is known on the effect of smoking cessation and computed tomography (CT)-derived bone mineral density (BMD) decline in the spine. We evaluated the association of current and former smoking with BMD decline after 3-year follow-up. Methods: Male current and former smokers participating in a lung cancer screening trial who underwent baseline and 3-year follow-up CT were included. BMD was measured by manual placement of a region of interest in the first lumbar vertebra and expressed in Hounsfield Unit (HU). Multiple linear regression analysis was used to evaluate the association between pack years smoked and smoking status with BMD decline. Results: 408 participants were included with median (25th–75th percentile) age of 59.4 (55.9–63.5) years. At the start of the study, 197 (48.3%) participants were current smokers and 211 (51.7%) were former smokers and had a similar amount of pack years. Current smokers had quit smoking for 6 (4–8) years prior to inclusion. There was no difference in BMD between current and former smokers at baseline (109 ± 34 HU vs. 108 ± 32 HU, p = 0.96). At 3-year follow-up, current smokers had a mean BMD decline of −3 ± 13 HU (p = 0.001), while BMD in former smokers did not change as compared to baseline (1 ± 13 HU, p = 0.34). After adjustment for BMD at baseline and body mass index, current smoking was independently associated with BMD decline (−3.8 HU, p = 0.003). Age, pack years, and the presence of a fracture at baseline did not associate with BMD decline. Conclusions: Current smokers showed a more rapid BMD decline over a 3-year period compared to former smokers. This information might be important to identify subjects at risk for osteoporosis and emphasizes the importance of smoking cessation in light of BMD decline.

  12. Bone density loss on computed tomography at 3-year follow-up in current compared to former male smokers

    Energy Technology Data Exchange (ETDEWEB)

    Pompe, E., E-mail: e.pompe@umcutrecht.nl [Department of Pulmonology, University Medical Center Utrecht, Utrecht (Netherlands); Bartstra, J. [Department of Radiology, University Medical Center Utrecht, Utrecht (Netherlands); Verhaar, H.J. [Department of Geriatric Medicine, University Medical Center Utrecht, Utrecht (Netherlands); Koning, H.J. de; Aalst, C.M. van der [Department of Public Health, Erasmus MC − University Medical Center Rotterdam, Rotterdam (Netherlands); Oudkerk, M. [University of Groningen, University Medical Center Groningen, Groningen, Department of Radiology (Netherlands); Vliegenthart, R. [University of Groningen, University Medical Center Groningen, Groningen, Department of Radiology (Netherlands); University of Groningen, University Medical Center Groningen, Center for Medical Imaging-North East Netherlands, Groningen (Netherlands); Lammers, J.-W.J. [Department of Pulmonology, University Medical Center Utrecht, Utrecht (Netherlands); Jong, P.A. de; Mohamed Hoesein, F.A.A. [Department of Radiology, University Medical Center Utrecht, Utrecht (Netherlands)

    2017-04-15

    Objectives: Cigarette smoking negatively affects bone quality and increases fracture risk. Little is known on the effect of smoking cessation and computed tomography (CT)-derived bone mineral density (BMD) decline in the spine. We evaluated the association of current and former smoking with BMD decline after 3-year follow-up. Methods: Male current and former smokers participating in a lung cancer screening trial who underwent baseline and 3-year follow-up CT were included. BMD was measured by manual placement of a region of interest in the first lumbar vertebra and expressed in Hounsfield Unit (HU). Multiple linear regression analysis was used to evaluate the association between pack years smoked and smoking status with BMD decline. Results: 408 participants were included with median (25th–75th percentile) age of 59.4 (55.9–63.5) years. At the start of the study, 197 (48.3%) participants were current smokers and 211 (51.7%) were former smokers and had a similar amount of pack years. Current smokers had quit smoking for 6 (4–8) years prior to inclusion. There was no difference in BMD between current and former smokers at baseline (109 ± 34 HU vs. 108 ± 32 HU, p = 0.96). At 3-year follow-up, current smokers had a mean BMD decline of −3 ± 13 HU (p = 0.001), while BMD in former smokers did not change as compared to baseline (1 ± 13 HU, p = 0.34). After adjustment for BMD at baseline and body mass index, current smoking was independently associated with BMD decline (−3.8 HU, p = 0.003). Age, pack years, and the presence of a fracture at baseline did not associate with BMD decline. Conclusions: Current smokers showed a more rapid BMD decline over a 3-year period compared to former smokers. This information might be important to identify subjects at risk for osteoporosis and emphasizes the importance of smoking cessation in light of BMD decline.

  13. Entorhinal inputs to hippocampal CA1 and dentate gyrus in the rat: a current-source-density study.

    Science.gov (United States)

    Leung, L S; Roth, L; Canning, K J

    1995-06-01

    1. Laminar profiles of the average evoked potentials and current-source-density analysis were used to study the input provided by the medial perforant path (PP) to the hippocampus in the urethan-anesthetized rat. 2. Stimulation of the PP activated an early latency sink in the middle molecular layer of the dentate gyrus (DG) and in the stratum lacunosum-moleculare in CA1. The DG current sink was generated by excitatory synaptic currents activated by the PP on dentate granule cells. In the normal rat, the peak current sink in the DG was typically five times greater than that of CA1. However, the CA1 sink could be distinguished from the DG sink in several ways: 1) it peaked when the DG sink was subsiding; 2) it showed paired-pulse facilitation, whereas the DG sink did not; and 3) in rats in which the DG was lesioned by local colchicine injection, the DG sink was reduced much more than the CA1 sink. 3. The PP afferents to CA1 required a slightly higher stimulus threshold (> 100 microA) for activation than those projecting to the DG granule cells (sink (2.5 +/- 0.2 ms, mean +/- SE) was also slightly longer than that of the DG sink (1.7 +/- 0.1 ms), suggesting that the axons of entorhinal layer III cells that project to CA1 have a slightly lower conduction velocity than the axons of the layer II cells that project to the DG. 4. The short-latency current sink activated by the PP in the distal dendritic layers of CA1 was likely provided by excitatory currents at the distal apical dendrites of CA1 pyramidal cells. The accompanying current source was mainly confined to stratum radiatum and appeared not to involve the cell body layer. Thus the electrotonic current spread may not be effective enough to depolarize the cell body or axon hillock. Contribution of interneurons to the above source-sink profile is possible, with the provision that these interneurons must have dendritic processes that span strata radiatum and lacunosum moleculare. 5. Extracellular field recordings

  14. Investigation on the corrosion resistance of PIM 316L stainless steel in PEM fuel cell simulated environment

    International Nuclear Information System (INIS)

    Oliveira, Mara Cristina Lopes de; Costa, Isolda; Antunes, Renato Altobelli

    2009-01-01

    Bipolar plates play main functions in PEM fuel cells, accounting for the most part of the weight and cost of these devices. Powder metallurgy may be an interesting manufacturing process of these components owing to the production of large scale, complex near-net shape parts. However, corrosion processes are a major concern due to the increase of the passive film thickness on the metal surface, lowering the power output of the fuel cell. In this work, the corrosion resistance of PIM AISI 316L stainless steel specimens was evaluated in 1M H 2 SO 4 + 2 ppm HF solution at room temperature during 30 days of immersion. The electrochemical measurements comprised potentiodynamic polarization and electrochemical impedance spectroscopy. The surface morphology of the specimens was observed before and after the corrosion tests through SEM images. The material presented low corrosion current density suggesting that it is suitable to operate in the PEM fuel cell environment. (author)

  15. A Comparative Study on the Effect of MWCNT as Reinforcement on the Corrosion Parameters of Different Ni-W/MWCNTs Nanocomposite Coatings in Various Corrosive Media

    Science.gov (United States)

    Mohammadpour, Zahra; Zare, Hamid R.

    2018-03-01

    Nickel-tungsten multi-walled carbon nanotubes (Ni-W/MWCNTs) nanocomposite coatings were co-electrodeposited in the ammonium-free bath by means of constant direct current coulometry. The results indicate that the amount of MWCNTs incorporated into the nanocomposite coatings has a key role in the improvement of their microhardness and corrosion resistance. The corrosion behavior of the coatings was evaluated using potentiodynamic polarization and electrochemical impedance spectroscopy methods in three corrosive media of 3.5 wt% NaCl, 1.0 M NaOH, and 0.5 M H2SO4. The experimental data of the corrosion current density (jcorr), corrosion rate (CR), the polarization resistance (Rp), and microhardness indicate that the presence of MWCNTs in coatings improves the quality of those coatings. The surface morphology of the coatings and the elemental analysis data were obtained by scanning electron microscopy and energy dispersive X-ray microanalysis respectively. As the results showed, the coatings were uniform and crack-free in the presence of 5.3 wt% carbon. Also, a microhardness test revealed that the nanocomposite coating containing 5.3 wt% carbon obtained in an ammonium-free bath which provided the higher content of tungsten had the highest hardness value among others.

  16. [Corrosion resistance of casted titanium by compound treatments in the artificial saliva with different fluoride concentrations].

    Science.gov (United States)

    Wang, Xian-li; Guo, Tian-wen

    2012-09-01

    To study the corrosion resistance of casted titanium by plasma nitriding and TiN-coated compound treatments in the artificial saliva with different fluoride concentrations and to investigate whether compound treatments can increase the corrosion resistance of casted titanium. Potentiodynamic polarization technique was used to depict polarization curve and to measured the current density of corrosion (Icorr) and the electric potential of corrosion (Ecorr) of casted titanium (Group A) and casted titanium by compound treatments (Group B) in the artificial saliva with different fluoride concentrations. After electrochemical experiment, the microstructure was observed by scanning electron microscope (SEM). The Icorrs of Group A and B in the artificial saliva of different fluoride concentrations were (1530.23 ± 340.12), (2290.36 ± 320.10), (4130.52 ± 230.17) nA and (2.62 ± 0.64), (7.37 ± 3.59), (10.76 ± 6.05) nA, respectively. The Ecorrs were (-0.93 ± 0.10), (-0.89 ± 0.21), (-0.57 ± 0.09) V and (-0.21 ± 0.04), (-0.17 ± 0.03), (-0.22 ± 0.03) V, respectively.The Icorrs of Group B were significantly lower (P corrosion resistance of both treated and untreated casted titanium negatively, but plasma nitriding and TiN-coated compound treatments can significantly increase the corrosion resistance of casted titanium.

  17. Structure and corrosion properties of Cr coating deposited on aerospace bearing steel

    Science.gov (United States)

    Wang, Fangfang; Zhang, Fengxiang; Zheng, Lijing; Zhang, Hu

    2017-11-01

    The corrosion protection of chromium coating deposited on aerospace bearing steels by using the Filtered Cathodic Vacuum Arc deposition- Metal Evaporation Vacuum Arc duplex technique (MEVVA-FCVA) had been investigated. The protection efficiency of chromium coating on different substrate materials had also been evaluated. The chromium coating was mainly composed of nanocrystallineα-Cr in a range of 50-200 nm. The orientation distributions of α-Cr film on substrates with different composition had a certain difference to each other. Electrochemical experimental results indicated that the chromium coating significantly improved the corrosion resistance of experimental bearing steels in 3.5% NaCl solution. The protective efficiency of chromium films were all over 98%. The corrosion resistance of chromium coating was influenced by the chemical composition of substrate material. The chromium coatings on higher Cr-containing substrate displayed lower corrosion current density and more positive corrosion potential. The increase of passive film thickness and the formation of a mass of chromium oxide and hydroxide on the surface are responsible for the improved corrosion properties.

  18. Comparative electrochemical investigation of the effect of aging on corrosion of dental amalgam.

    Science.gov (United States)

    Amin, Wala M

    2007-01-01

    To investigate corrosion in dental amalgam and evaluate the effects of composition and long-term aging on the alloy's corrosion behavior. A sample of high-copper and low-copper formulations was employed. Corrosion tests were performed using a 3-electrode polarization cell. Anodic polarization curves were drawn, and the potential and the current density corresponding to the first anodic peak were registered. Scanning electron microscopy was performed, and the different metallurgical phases of the alloy's microstructure were examined and analyzed chemically using an energy-dispersive x-ray technique. The amalgams' corrosion behavior was evaluated at 1 week and after aging in a simulated oral environment for 6 months, 1 year, and 2 years. Data were analyzed using analysis of variance (ANOVA)Scheffe post hoc test at a .05 significance level. The potential values recorded by the high-copper amalgam were higher (P amalgam than in the high-copper alloy. For both formulations the potentials increased significantly (P amalgam. High-copper amalgam exhibited better resistance to corrosion than the low-copper alloy. Aging in a simulated oral environment improved corrosion behavior for both high- and low-copper amalgams.

  19. Influence of surface layer on mechanical and corrosion properties of nickel-titanium orthodontic wires.

    Science.gov (United States)

    Katić, Višnja; Curković, Helena Otmačić; Semenski, Damir; Baršić, Gorana; Marušić, Katarina; Spalj, Stjepan

    2014-11-01

    To analyze the effect of various coating formulations on the mechanical and corrosion properties of nickel-titanium (NiTi) orthodontic wires. Uncoated, rhodium-coated, and nitrified NiTi wires were observed with a three-point-bend test, surface roughness (Ra) measurement, scanning electron microscopy, energy dispersive spectroscopy, and electrochemical testing (open circuit potential, electrochemical impedance spectroscopy, and cyclic polarization scan). Differences in the properties of tested wire types were analyzed with analysis of variance and Tukey post hoc test. Uncoated and nitrified NiTi wires showed similar mechanical and anticorrosive properties, while rhodium-coated NiTi wires showed the highest Ra and significantly higher modulus of elasticity, yield strength, and delivery of forces during loading but not in unloading. Rhodium-coated NiTi wires also had the highest corrosion current density and corrosion potential, lowest impedance modulus, and two time constants on Bode plot, one related to the Rh/Au coating and the other to underlying NiTi. Working properties of NiTi wires were unaffected by various coatings in unloading. Nitrification improved corrosion resistance. Rhodium coating reduced corrosion resistance and pronounced susceptibility to pitting corrosion in artificial saliva because of galvanic coupling between the noble coating and the base alloy.

  20. [Study on corrosion resistance of three non-noble porcelain alloys].

    Science.gov (United States)

    Wu, Zhikai; Xu, Sheng; Li, Wei; Teng, Jin; Li, Ning

    2011-10-01

    To study the electrochemical corrosion behavior of Co-Cr, Ni-Cr and Ni-Cr-Be based porcelain alloys in NaCl solution. Five samples of each alloy were made respectively, electric polarization curve of each alloy was obtained using potentiodynamic polarization technique. Self-corrosion potential (E(corr)), self-corrosion current density (I(corr), passive region and transpassivation potential were tested. Microstructure and constituent was examined using scanning electron microscopy and energy dispersive spectroscopy. Co-Cr alloy possessed the most desirable corrosion resistance because of its integrated, homogeneous and compact passive film. The poor compactness of Ni-Cr alloy's passive film decreased its corrosion resistance. Ni-Cr-Be alloy exhibited the worst corrosion resistance due to the Cr and Mo depleted Ni-Be eutectic phases in the alloy. Taking biological security