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Sample records for cores magnet

  1. Mars' core and magnetism.

    Science.gov (United States)

    Stevenson, D J

    2001-07-12

    The detection of strongly magnetized ancient crust on Mars is one of the most surprising outcomes of recent Mars exploration, and provides important insight about the history and nature of the martian core. The iron-rich core probably formed during the hot accretion of Mars approximately 4.5 billion years ago and subsequently cooled at a rate dictated by the overlying mantle. A core dynamo operated much like Earth's current dynamo, but was probably limited in duration to several hundred million years. The early demise of the dynamo could have arisen through a change in the cooling rate of the mantle, or even a switch in convective style that led to mantle heating. Presently, Mars probably has a liquid, conductive outer core and might have a solid inner core like Earth.

  2. Magnetic Probing of Core Geodynamics

    Science.gov (United States)

    Voorhies, Coerte V.

    2004-01-01

    To better understand geomagnetic theory and observation, we can use spatial magnetic spectra for the main field and secular variation to test core dynmcal hypotheses against seismology. The hypotheses lead to theoretical spectra which are fitted to observational spectra. Each fit yields an estimate of the radius of Earth's core and uncertainty. If this agrees with the seismologic value, then the hypothes pass the test. A new way to obtain theoretical spectra extends the hydromagnetic scale analysis of Benton to scale-variant field and flow. For narrow scale flow and a dynamically weak field by the top of Earth's core, this yields a generalized Stevenson-McLeod spectrum for the core-source field, and a secular variation spectrum modulated by a cubic polynomial in spherical harmonic degree n. The former passes the tests. The latter passes many tests, but does not describe rapid dipole decline and quadrupole rebound; some tests suggest it is a bit hard, or rich in narrow scale change. In a core geodynamo, motion of the fluid conductor does work against the Lorentz force. This converts kinetic into magnetic energy which, in turn, is lost to heat via Ohmic dissipation. In the analysis at lentgh-scale l/k, if one presumes kinetic energy is converted in either eddy- overturning or magnetic free-decay time-scales, then Kolmogorov or other spectra in conflict with observational spectra can result. Instead, the rate work is done roughly balances the dissipation rate, which is consistent with small scale flow. The conversion time-scale depends on dynamical constraints. These are summarized by the magneto-geostrophic vertical vorticity balance by the top of the core, which includes anisotropic effects of rotation, the magnetic field, and the core- mantle boundary. The resulting theoretical spectra for the core-source field and its SV are far more compatible with observation. The conversion time-scale of order l20 years is pseudo-scale-invarient. Magnetic spectra of other

  3. Rotation and Magnetism of Earth's Inner Core

    Science.gov (United States)

    Glatzmaier; Roberts

    1996-12-13

    Three-dimensional numerical simulations of the geodynamo suggest that a super- rotation of Earth's solid inner core relative to the mantle is maintained by magnetic coupling between the inner core and an eastward thermal wind in the fluid outer core. This mechanism, which is analogous to a synchronous motor, also plays a fundamental role in the generation of Earth's magnetic field.

  4. Core Processes: Earth's eccentric magnetic field

    DEFF Research Database (Denmark)

    Finlay, Chris

    2012-01-01

    Earth’s magnetic field is characterized by a puzzling hemispheric asymmetry. Calculations of core dynamo processes suggest that lopsided growth of the planet’s inner core may be part of the cause.......Earth’s magnetic field is characterized by a puzzling hemispheric asymmetry. Calculations of core dynamo processes suggest that lopsided growth of the planet’s inner core may be part of the cause....

  5. Analysis of circuits including magnetic cores (MTRAC)

    Science.gov (United States)

    Hanzen, G. R.; Nitzan, D.; Herndon, J. R.

    1972-01-01

    Development of automated circuit analysis computer program to provide transient analysis of circuits with magnetic cores is discussed. Allowance is made for complications caused by nonlinearity of switching core model and magnetic coupling among loop currents. Computer program is conducted on Univac 1108 computer using FORTRAN IV.

  6. Engineered Magnetic Core-Shell Structures.

    Science.gov (United States)

    Alavi Nikje, Mir Mohammad; Vakili, Maryam

    2015-01-01

    In recent years, engineered magnetic core-shell structures are playing an important role in the wide range of various applications. These magnetic core-shell structures have attracted considerable attention because of their unique properties and various applications. Also, the synthesis of engineered magnetic core-shell structures has attracted practical interest because of potential applications in areas such as ferrofluids, medical imaging, drug targeting and delivery, cancer therapy, separations, and catalysis. So far a large number of engineered magnetic core-shell structures have been successfully synthesized. This review article focuses on the recent progress in synthesis and characterization of engineered magnetic core-shell structures. Also, this review gives a brief description of the various application of these structures. It is hoped that this review will play some small part in helping future developments in important field.

  7. Magnetic induction measurements in distribution transformer cores

    Energy Technology Data Exchange (ETDEWEB)

    Paraskevopoulos, A.A.P.; Bourkas, P.D. [National Technical Univ. of Athens, Athens (Greece). Computer Engineering, High Voltage, and Electrical Measurements Laboratory; Paparigas, D. [Schneider ELVIM Electric Transformer Factory, Athens (Greece)

    2005-07-01

    Transformers need high magnetic field rates in order to operate efficiently. In this study, magnetic induction measurements of distribution transformer cores with power levels of 630 kVA were used to assess the performance of transformers in a city in Greece. A 630 kVA transformer was used to investigate whether magnetic induction measurements of the iron core arcs of the transformer were similar to the rest of the transformer's magnetic rate. Potential load losses were also investigated. Eight cores of 4 different sizes were measured in the study. Voltage transmissions were varied in order to measure the different cores. The voltage transmitted into the coil was calculated in order to compare the transformer's magnetic field with the cores. Average values for the measured cores were then calculated. Leakages were measured using a Gauss meter. Results of the study indicated that the measured values were lower than established safety limits for transformers. It was concluded that the magnetic induction measurements of transformer cores can be used to measure the overall performance of transformers. 18 refs., 8 tabs., 5 figs.

  8. Magnetic core-shell silica particles

    NARCIS (Netherlands)

    Claesson, E.M.

    2007-01-01

    This thesis deals with magnetic silica core-shell colloids and related functionalized silica structures. Synthesis routes have been developed and optimized. The physical properties of these colloids have been investigated, such as the magnetic dipole moment, dipolar structure formation and

  9. Magnetic core-shell silica particles

    NARCIS (Netherlands)

    Claesson, E.M.

    2007-01-01

    This thesis deals with magnetic silica core-shell colloids and related functionalized silica structures. Synthesis routes have been developed and optimized. The physical properties of these colloids have been investigated, such as the magnetic dipole moment, dipolar structure formation and rotationa

  10. Biocompatible magnetic core-shell nanocomposites for engineered magnetic tissues

    Science.gov (United States)

    Rodriguez-Arco, Laura; Rodriguez, Ismael A.; Carriel, Victor; Bonhome-Espinosa, Ana B.; Campos, Fernando; Kuzhir, Pavel; Duran, Juan D. G.; Lopez-Lopez, Modesto T.

    2016-04-01

    The inclusion of magnetic nanoparticles into biopolymer matrixes enables the preparation of magnetic field-responsive engineered tissues. Here we describe a synthetic route to prepare biocompatible core-shell nanostructures consisting of a polymeric core and a magnetic shell, which are used for this purpose. We show that using a core-shell architecture is doubly advantageous. First, gravitational settling for core-shell nanocomposites is slower because of the reduction of the composite average density connected to the light polymer core. Second, the magnetic response of core-shell nanocomposites can be tuned by changing the thickness of the magnetic layer. The incorporation of the composites into biopolymer hydrogels containing cells results in magnetic field-responsive engineered tissues whose mechanical properties can be controlled by external magnetic forces. Indeed, we obtain a significant increase of the viscoelastic moduli of the engineered tissues when exposed to an external magnetic field. Because the composites are functionalized with polyethylene glycol, the prepared bio-artificial tissue-like constructs also display excellent ex vivo cell viability and proliferation. When implanted in vivo, the engineered tissues show good biocompatibility and outstanding interaction with the host tissue. Actually, they only cause a localized transitory inflammatory reaction at the implantation site, without any effect on other organs. Altogether, our results suggest that the inclusion of magnetic core-shell nanocomposites into biomaterials would enable tissue engineering of artificial substitutes whose mechanical properties could be tuned to match those of the potential target tissue. In a wider perspective, the good biocompatibility and magnetic behavior of the composites could be beneficial for many other applications.The inclusion of magnetic nanoparticles into biopolymer matrixes enables the preparation of magnetic field-responsive engineered tissues. Here we

  11. Dismantling OPAL's cylindrical magnet core

    CERN Multimedia

    Laurent Guiraud

    2001-01-01

    Lifting a handling device for dismounting the pressure bells, which are inside the cylindrical magnet coil on the central section of OPAL, on the right part of the photo. OPAL was a detector on the LEP accelerator, which ran from 1989 to 2000.

  12. Electrically Small Magnetic Dipole Antennas with Magnetic Core

    DEFF Research Database (Denmark)

    Kim, Oleksiy S.; Breinbjerg, Olav

    2010-01-01

    This work extends the theory of a spherical magnetic dipole antenna with magnetic core by numerical results for practical antenna configurations that excite higher-order modes besides the main TE10 spherical mode. The multiarm spherical helix (MSH) and the spherical split ring (SSR) antennas...

  13. Magnetic Fields in Quasar Cores, 2

    CERN Document Server

    Taylor, G B

    1999-01-01

    Multi-frequency polarimetry with the Very Long Baseline Array (VLBA) telescope has revealed absolute Faraday Rotation Measures (RMs) in excess of 1000 rad/m/m in the central regions of 7 out of 8 strong quasars studied (e.g., 3C 273, 3C 279, 3C 395). Beyond a projected distance of ~20 pc, however, the jets are found to have |RM| < 100 rad/m/m. Such sharp RM gradients cannot be produced by cluster or galactic-scale magnetic fields, but rather must be the result of magnetic fields organized over the central 1-100 pc. The RMs of the sources studied to date and the polarization properties of BL Lacs, quasars and galaxies are shown to be consistent so far with the predictions of unified schemes. The direct detection of high RMs in these quasar cores can explain the low fractional core polarizations usually observed in quasars at centimeter wavelengths as the result of irregularities in the Faraday screen on scales smaller than the telescope beam. Variability in the RM of the core is reported for 3C 279 between ...

  14. Magnetic to magnetic and kinetic to magnetic energy transfers at the top of the Earth's core

    Science.gov (United States)

    Huguet, Ludovic; Amit, Hagay; Alboussière, Thierry

    2016-11-01

    We develop the theory for the magnetic to magnetic and kinetic to magnetic energy transfer between different spherical harmonic degrees due to the interaction of fluid flow and radial magnetic field at the top of the Earth's core. We show that non-zero secular variation of the total magnetic energy could be significant and may provide evidence for the existence of stretching secular variation, which suggests the existence of radial motions at the top of the Earth's core-whole core convection or MAC waves. However, the uncertainties of the small scales of the geomagnetic field prevent a definite conclusion. Combining core field and flow models we calculate the detailed magnetic to magnetic and kinetic to magnetic energy transfer matrices. The magnetic to magnetic energy transfer shows a complex behaviour with local and non-local transfers. The spectra of magnetic to magnetic energy transfers show clear maxima and minima, suggesting an energy cascade. The kinetic to magnetic energy transfers, which are much weaker due to the weak poloidal flow, are either local or non-local between degree one and higher degrees. The patterns observed in the matrices resemble energy transfer patterns that are typically found in 3-D MHD numerical simulations.

  15. Velocity-Controlled Magnetic Bearings with Solid Cores

    Science.gov (United States)

    Chen, H. Ming; Walton, James

    1996-01-01

    A methodology for designing velocity-controlled magnetic bearings with laminated cores has been extended to those with solid cores. The eddy-current effect of the solid cores is modeled as an opposing magnetomotive force. The bearing control dynamics is formulated in a dimensionless fashion which can be readily reviewed on a root-locus plot for stability. This facilitates the controller design and tuning process for solid core magnetic bearings using no displacement sensors.

  16. Hysteresis effects in the cores of particle accelerator magnets

    CERN Document Server

    AUTHOR|(CDS)2086181; Schoerling, Daniel

    A study of the hysteresis effects in the cores of particle accelerator magnets has been performed in the framework of the work presented in this thesis. This study has been focused on normal conducting particle accelerator magnets whose cores are manufactured using ferromagnetic materials. The magnetic circuits have been modelled using the developed models: one model for the magnetic circuit and one for the magnetization of the material in the core. The parameters of the magnetic circuit model have been identified with the help of simulations which rely on the finite element method (Opera 3D), while the parameters of the magnetic hysteresis model have been identified through experimental measurements performed using a method developed in the framework of this work. The modelling results have been validated by means of experimental measurements performed on two magnets: one small size magnet which has been specifically designed and manufactured, and one magnet which is currently used in a particle accelerator ...

  17. Effects of surface anisotropy on magnetic vortex core

    Energy Technology Data Exchange (ETDEWEB)

    Pylypovskyi, Oleksandr V., E-mail: engraver@univ.net.ua [Taras Shevchenko National University of Kiev, 01601 Kiev (Ukraine); Sheka, Denis D. [Taras Shevchenko National University of Kiev, 01601 Kiev (Ukraine); Kravchuk, Volodymyr P.; Gaididei, Yuri [Institute for Theoretical Physics, 03143 Kiev (Ukraine)

    2014-06-01

    The vortex core shape in the three dimensional Heisenberg magnet is essentially influenced by a surface anisotropy. We predict that depending of the surface anisotropy type there appears barrel- or pillow-shaped deformation of the vortex core along the magnet thickness. Our theoretical study is well confirmed by spin–lattice simulations. - Highlights: • The shape of magnetic vortex core is essentially influenced by SA (surface anisotropy). • We predict barrel- or pillow-shaped deformation of the vortex depending on SA. • The variational approach fully describes the vortex core deformation. • We performed spin–lattice simulations to detect SA influence on the vortex core.

  18. Design considerations for an air core magnetic actuator

    Science.gov (United States)

    Groom, Nelson J.

    1992-01-01

    Equations for the force produced by an air core electromagnet on a permanent magnet core as a function of the coil height, coil inner and outer radii, and core displacement are developed. The magnetization vector of the permanent magnet core is assumed to be aligned with the central axis of the electromagnet and the forces which are produced lie along the same axis. Variations in force due to changes in electromagnet parameters and core displacement are investigated and parameter plots which should be useful for coil design are presented.

  19. Statics of Magnetic Fluid Drop with Compound Magnetic Core in a Wedge-Shaped Channel

    Directory of Open Access Journals (Sweden)

    V. Bashtovoi

    2013-12-01

    Full Text Available A behavior of magnetic fluid drop with compound magnetic core in a wedge-shaped channel was studied experimentally. The study examines influence of magnetic fluid properties, its volume and magnetic field on statics of the system compound magnetmagnetic fluid drop in wedge-shaped channel. The possibility to change the static conditions of such system by altering magnetic field of the core was observed

  20. Effective particle magnetic moment of multi-core particles

    Energy Technology Data Exchange (ETDEWEB)

    Ahrentorp, Fredrik; Astalan, Andrea; Blomgren, Jakob; Jonasson, Christian [Acreo Swedish ICT AB, Arvid Hedvalls backe 4, SE-411 33 Göteborg (Sweden); Wetterskog, Erik; Svedlindh, Peter [Department of Engineering Sciences, Uppsala University, Box 534, SE-751 21 Uppsala (Sweden); Lak, Aidin; Ludwig, Frank [Institute of Electrical Measurement and Fundamental Electrical Engineering, TU Braunschweig, D‐38106 Braunschweig Germany (Germany); IJzendoorn, Leo J. van [Department of Applied Physics, Eindhoven University of Technology, 5600 MB Eindhoven (Netherlands); Westphal, Fritz; Grüttner, Cordula [Micromod Partikeltechnologie GmbH, D ‐18119 Rostock (Germany); Gehrke, Nicole [nanoPET Pharma GmbH, D ‐10115 Berlin Germany (Germany); Gustafsson, Stefan; Olsson, Eva [Department of Applied Physics, Chalmers University of Technology, SE-412 96 Göteborg (Sweden); Johansson, Christer, E-mail: christer.johansson@acreo.se [Acreo Swedish ICT AB, Arvid Hedvalls backe 4, SE-411 33 Göteborg (Sweden)

    2015-04-15

    In this study we investigate the magnetic behavior of magnetic multi-core particles and the differences in the magnetic properties of multi-core and single-core nanoparticles and correlate the results with the nanostructure of the different particles as determined from transmission electron microscopy (TEM). We also investigate how the effective particle magnetic moment is coupled to the individual moments of the single-domain nanocrystals by using different measurement techniques: DC magnetometry, AC susceptometry, dynamic light scattering and TEM. We have studied two magnetic multi-core particle systems – BNF Starch from Micromod with a median particle diameter of 100 nm and FeraSpin R from nanoPET with a median particle diameter of 70 nm – and one single-core particle system – SHP25 from Ocean NanoTech with a median particle core diameter of 25 nm.

  1. Effects of Surface Anisotropy on Magnetic Vortex Core

    OpenAIRE

    Pylypovskyi, Oleksandr V.; Sheka, Denis D.; Kravchuk, Volodymyr P.; Gaididei, Yuri

    2013-01-01

    The vortex core shape in the three dimensional Heisenberg magnet is essentially influenced by a surface anisotropy. We predict that depending of the surface anisotropy type there appears barrel- or pillow-shaped deformation of the vortex core along the magnet thickness. Our theoretical study is well confirmed by spin-lattice simulations.

  2. Rotation and magnetism of Earth`s inner core

    Energy Technology Data Exchange (ETDEWEB)

    Glatzmaier, G.A. [Los Alamos National Lab., NM (United States); Roberts, P.H. [Univ. of California, Los Angeles, CA (United States)

    1996-12-13

    Three-dimensional numerical simulations of the geodynamo suggest that a super-rotation of Earth`s solid inner core relative to the mantle is maintained by magnetic coupling between the inner core and an eastward thermal wind in the fluid outer core. This mechanism, which is analogous to a synchronous motor, also plays a fundamental role in the generation of Earth`s magnetic field. 18 refs., 6 figs.

  3. Building nanocomposite magnets by coating a hard magnetic core with a soft magnetic shell.

    Science.gov (United States)

    Liu, Fei; Zhu, Jinghan; Yang, Wenlong; Dong, Yunhe; Hou, Yanglong; Zhang, Chenzhen; Yin, Han; Sun, Shouheng

    2014-02-17

    Controlling exchange coupling between hard magnetic and soft magnetic phases is the key to the fabrication of advanced magnets with tunable magnetism and high energy density. Using FePt as an example, control over the magnetism in exchange-coupled nanocomposites of hard magnetic face-centered tetragonal (fct) FePt and soft magnetic Co (or Ni, Fe2C) is shown. The dispersible hard magnetic fct-FePt nanoparticles are first prepared with their coercivity (Hc) reaching 33 kOe. Then core/shell fct-FePt/Co (or Ni, Fe2C) nanoparticles are synthesized by reductive thermal decomposition of the proper metal precursors in the presence of fct-FePt nanoparticles. These core/shell nanoparticles are strongly coupled by exchange interactions and their magnetic properties can be rationally tuned by the shell thickness of the soft phase. This work provides an ideal model system for the study of exchange coupling at the nanoscale, which will be essential for building superstrong magnets for various permanent magnet applications in the future.

  4. Synthetic Observations of Magnetic Fields in Protostellar Cores

    CERN Document Server

    Lee, Joyce W Y; Offner, Stella S R

    2016-01-01

    The role of magnetic fields in the early stages of star formation is not well constrained. In order to discriminate between different star formation models, we analyze 3D magnetohydrodynamic simulations of low-mass cores and explore the correlation between magnetic field orientation and outflow orientation over time. We produce synthetic observations of dust polarization at resolutions comparable to millimeter-wave dust polarization maps observed by CARMA and compare these with 2D visualizations of projected magnetic field and column density. Cumulative distribution functions of the projected angle between the magnetic field and outflow show different degrees of alignment in simulations with differing mass-to-flux ratios. The distribution function for the less magnetized core agrees with observations finding random alignment between outflow and field orientations, while the more magnetized core exhibits stronger alignment. We find that fractional polarization increases when the system is viewed such that the ...

  5. Novel Fe-based amorphous magnetic powder cores with ultra-low core losses

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Amorphous magnetic alloy powders were prepared from bulk metallic glasses Fe74Cr2Mo2Sn2P10Si4B4C2 with supercooled liq-uid region of 32 K by water atomization.Amorphous magnetic powder core precursor was produced from a mixture of the amorphous alloy powder with addition of insulation and bonding materials by mold compacting at room temperature.After annealing the core precursor,the amorphous magnetic core exhibits superior magnetic properties as compared with molypermalloy powder core.The initial permeability up to 1 MHz was about 80,the flux density at 300 Oe was 1.06 T and the core loss at 100 kHz for Bm=0.1 T was only 329 kW/m3.The ultra-low core loss is attributed to the combination of relatively high resistivity and the amorphous structure of the Fe-based amorphous powder.Besides the outstanding magnetic properties,the Fe-based amorphous magnetic powder core had a much lower cost which renders the powder cores a potential candidate for a variety of industrial applications.

  6. More on core instabilities of magnetic monopoles

    CERN Document Server

    Striet, J

    2003-01-01

    In this paper we present new results on the core instability of the 't Hooft Polyakov monopoles we reported on before. This instability, where the spherical core decays in a toroidal one, typically occurs in models in which charge conjugation is gauged. In this paper we also discuss a third conceivable configuration denoted as ``split core'', which brings us to some details of the numerical methods we employed. We argue that a core instability of 't Hooft Polyakov type monopoles is quite a generic feature of models with charged Higgs particles.

  7. Core-shell magnetic nanowires fabrication and characterization

    Science.gov (United States)

    Kalska-Szostko, B.; Klekotka, U.; Satuła, D.

    2017-02-01

    In this paper, a new way of the preparation of core-shell magnetic nanowires has been proposed. For the modification Fe nanowires were prepared by electrodeposition in anodic aluminium oxide matrixes, in first step. In second, by wetting chemical deposition, shell layers of Ag, Au or Cu were obtained. Resultant core-shell nanowires structure was characterized by X-ray diffraction, infrared spectroscopy, transmission electron microscopy, and energy dispersive x-ray. Whereas magnetic properties by Mössbauer spectroscopy.

  8. Impedance of a planar solenoid with a thin magnetic core

    NARCIS (Netherlands)

    Rejaei, B.; Vroubel, M.

    2007-01-01

    The high-frequency impedance of a planar solenoid with a thin magnetic core is theoretically investigated using the magnetostatic Green’s function formalism. It is shown that the electrical behavior of the solenoid depends on how the magnetic field induced by the current-carrying coil is coupled to

  9. Misalignment of Magnetic Fields and Outflows in Protostellar Cores

    CERN Document Server

    Hull, Charles L H; Bolatto, Alberto D; Bower, Geoffrey C; Carpenter, John M; Crutcher, Richard M; Fiege, Jason D; Franzmann, Erica; Hakobian, Nicholas S; Heiles, Carl; Houde, Martin; Hughes, A Meredith; Jameson, Katherine; Kwon, Woojin; Lamb, James W; Looney, Leslie W; Matthews, Brenda C; Mundy, Lee; Pillai, Thushara; Pound, Marc W; Stephens, Ian W; Tobin, John J; Vaillancourt, John E; Volgenau, N H; Wright, Melvyn C H

    2012-01-01

    Theoretical models of star formation generally assume that bipolar outflows are parallel to the mean magnetic-field direction in protostellar cores. Here we present results of \\lambda1.3 mm dust polarization observations toward 16 nearby, low-mass protostars, mapped with ~2.5" resolution at CARMA. The results show that magnetic fields in protostellar cores on scales of ~1000 AU are not tightly aligned with outflows from the protostars. If one assumes that outflows emerge along the rotation axes of circumstellar disks, then our results imply that these disks are not aligned with the fields in the cores from which they formed.

  10. Electrochemical synthesis of CORE-shell magnetic nanowires

    KAUST Repository

    Ovejero, Jesús G.

    2015-04-16

    (Fe, Ni, CoFe) @ Au core-shell magnetic nanowires have been synthesized by optimized two-step potentiostatic electrodeposition inside self-assembled nanopores of anodic aluminium templates. The optimal electrochemical parameters (e.g., potential) have been firstly determined for the growth of continuous Au nanotubes at the inner wall of pores. Then, a magnetic core was synthesized inside the Au shells under suitable electrochemical conditions for a wide spectrum of single elements and alloy compositions (e.g., Fe, Ni and CoFe alloys). Novel opportunities offered by such nanowires are discussed particularly the magnetic behavior of (Fe, Ni, CoFe) @ Au core-shell nanowires was tested and compared with that of bare TM nanowires. These core-shell nanowires can be released from the template so, opening novel opportunities for biofunctionalization of individual nanowires.

  11. The Magnetic Furnace: Intense Core Dynamos in B-stars

    CERN Document Server

    Augustson, Kyle C; Toomre, Juri

    2016-01-01

    The dynamo action achieved in the convective cores of main-sequence massive stars is explored here through 3-D global simulations of convective core dynamos operating within a young 10$M_{\\mathrm{sun}}$ B-type star, using the anelastic spherical harmonic (ASH) code. These simulations capture the inner 65% of this star by radius, encompassing the convective nuclear-burning core (about 23% by radius) and a portion of the overlying radiative envelope. Eight rotation rates are considered, ranging from 0.05% to 16% of the surface breakup velocity, thereby capturing both convection barely sensing the effects of rotation to others in which the Coriolis forces are prominent. The vigorous dynamo action realized within all of these turbulent convective cores builds magnetic fields with peak strengths exceeding a megagauss, with the overall magnetic energy (ME) in the faster rotators reaching super-equipartition levels compared to the convective kinetic energy (KE). The core convection typically involves turbulent colum...

  12. Magnetism near Vortex Cores of Cuprate Superconductors

    Science.gov (United States)

    Lee, J. C.; Prudchenko, K.; Launspach, B.; Ruiz, E. J.; Boekema, C.

    2005-03-01

    We examined muon-spin-resonance (μSR) vortex data of Bi2212, Tl2223, and YBCO to search for antiferromagnetism (AF) near the vortex cores. [1] Field distributions were obtained from μSR data using Maximum-Entropy analysis. The grainboundary and vortex signals were fitted by Gaussian and Lorentzian curves, the latter suggestive of extra AF ordering. Narrow Gaussians fit the grainboundary signals well, independent of temperature. For T B17 (2003) 3436.

  13. Accurate Modeling of Buck Converters with Magnetic-Core Inductors

    DEFF Research Database (Denmark)

    Astorino, Antonio; Antonini, Giulio; Swaminathan, Madhavan

    2015-01-01

    In this paper, a modeling approach for buck converters with magnetic-core inductors is presented. Due to the high nonlinearity of magnetic materials, the frequency domain analysis of such circuits is not suitable for an accurate description of their behaviour. Hence, in this work, a timedomain...... model of buck converters with magnetic-core inductors in a SimulinkR environment is proposed. As an example, the presented approach is used to simulate an eight-phase buck converter. The simulation results show that an unexpected system behaviour in terms of current ripple amplitude needs the inductor core...

  14. Submicron magnetic core conducting polypyrrole polymer shell: Preparation and characterization.

    Science.gov (United States)

    Tenório-Neto, Ernandes Taveira; Baraket, Abdoullatif; Kabbaj, Dounia; Zine, Nadia; Errachid, Abdelhamid; Fessi, Hatem; Kunita, Marcos Hiroiuqui; Elaissari, Abdelhamid

    2016-04-01

    Magnetic particles are of great interest in various biomedical applications, such as, sample preparation, in vitro biomedical diagnosis, and both in vivo diagnosis and therapy. For in vitro applications and especially in labs-on-a-chip, microfluidics, microsystems, or biosensors, the needed magnetic dispersion should answer various criteria, for instance, submicron size in order to avoid a rapid sedimentation rate, fast separations under an applied magnetic field, and appreciable colloidal stability (stable dispersion under shearing process). Then, the aim of this work was to prepare highly magnetic particles with a magnetic core and conducting polymer shell particles in order to be used not only as a carrier, but also for the in vitro detection step. The prepared magnetic seed dispersions were functionalized using pyrrole and pyrrole-2-carboxylic acid. The obtained core-shell particles were characterized in terms of particle size, size distribution, magnetization properties, FTIR analysis, surface morphology, chemical composition, and finally, the conducting property of those particles were evaluated by cyclic voltammetry. The obtained functional submicron highly magnetic particles are found to be conducting material bearing function carboxylic group on the surface. These promising conducting magnetic particles can be used for both transport and lab-on-a-chip detection.

  15. Modelling the core magnetic field of the earth

    Science.gov (United States)

    Harrison, C. G. A.; Carle, H. M.

    1982-01-01

    It is suggested that radial off-center dipoles located within the core of the earth be used instead of spherical harmonics of the magnetic potential in modeling the core magnetic field. The off-center dipoles, in addition to more realistically modeling the physical current systems within the core, are if located deep within the core more effective at removing long wavelength signals of either potential or field. Their disadvantage is that their positions and strengths are more difficult to compute, and such effects as upward and downward continuation are more difficult to manipulate. It is nevertheless agreed with Cox (1975) and Alldredge and Hurwitz (1964) that physical realism in models is more important than mathematical convenience. A radial dipole model is presented which agrees with observations of secular variation and excursions.

  16. Core losses of an inverter-fed permanent magnet synchronous motor with an amorphous stator core under no-load

    OpenAIRE

    Nicolas Denis; Yoshiyuki Kato; Masaharu Ieki; Keisuke Fujisaki

    2016-01-01

    In this paper, an interior permanent magnet synchronous motor (IPMSM) with a stator core made of amorphous magnetic material (AMM) is presented. The IPMSM is driven by a voltage source three-phase inverter with classical pulse width modulation (PWM) control. The core losses under no-load condition are measured by experiment and compared to an equivalent IPMSM with a stator core made of NO steel. Under these conditions, the core losses are influenced by the stator, rotor and magnet shapes but ...

  17. Magnetic, Structural, and Particle Size Analysis of Single- and Multi-Core Magnetic Nanoparticles

    DEFF Research Database (Denmark)

    Ludwig, Frank; Kazakova, Olga; Barquin, Luis Fernandez

    2014-01-01

    We have measured and analyzed three different commercial magnetic nanoparticle systems, both multi-core and single-core in nature, with the particle (core) size ranging from 20 to 100 nm. Complementary analysis methods and same characterization techniques were carried out in different labs...... and the results are compared with each other. The presented results primarily focus on determining the particle size—both the hydrodynamic size and the individual magnetic core size—as well as magnetic and structural properties. The used analysis methods include transmission electron microscopy, static...... and dynamic magnetization measurements, and Mössbauer spectroscopy. We show that particle (hydrodynamic and core) size parameters can be determined from different analysis techniques and the individual analysis results agree reasonably well. However, in order to compare size parameters precisely determined...

  18. Size analysis of single-core magnetic nanoparticles

    Science.gov (United States)

    Ludwig, Frank; Balceris, Christoph; Viereck, Thilo; Posth, Oliver; Steinhoff, Uwe; Gavilan, Helena; Costo, Rocio; Zeng, Lunjie; Olsson, Eva; Jonasson, Christian; Johansson, Christer

    2017-04-01

    Single-core iron-oxide nanoparticles with nominal core diameters of 14 nm and 19 nm were analyzed with a variety of non-magnetic and magnetic analysis techniques, including transmission electron microscopy (TEM), dynamic light scattering (DLS), static magnetization vs. magnetic field (M-H) measurements, ac susceptibility (ACS) and magnetorelaxometry (MRX). From the experimental data, distributions of core and hydrodynamic sizes are derived. Except for TEM where a number-weighted distribution is directly obtained, models have to be applied in order to determine size distributions from the measurand. It was found that the mean core diameters determined from TEM, M-H, ACS and MRX measurements agree well although they are based on different models (Langevin function, Brownian and Néel relaxation times). Especially for the sample with large cores, particle interaction effects come into play, causing agglomerates which were detected in DLS, ACS and MRX measurements. We observed that the number and size of agglomerates can be minimized by sufficiently strong diluting the suspension.

  19. Misalignment of Magnetic Fields and Outflows in Protostellar Cores

    OpenAIRE

    Hull, Charles L. H.; Plambeck, Richard L.; Bolatto, Alberto D.; Bower, Geoffrey C.; Carpenter, John M.; Crutcher, Richard M.; Fiege, Jason D.; Franzmann, Erica; Hakobian, Nicholas S.; Heiles, Carl; Houde, Martin; Hughes, A. Meredith; Jameson, Katherine; Kwon, Woojin; Lamb, James W.

    2012-01-01

    We present results of λ1.3 mm dust-polarization observations toward 16 nearby, low-mass protostars, mapped with ~2."5 resolution at CARMA. The results show that magnetic fields in protostellar cores on scales of ~1000 AU are not tightly aligned with outflows from the protostars. Rather, the data are consistent with scenarios where outflows and magnetic fields are preferentially misaligned (perpendicular), or where they are randomly aligned. If one assumes that outflows emerge along the rotati...

  20. Ultrathin Interface Regime of Core-Shell Magnetic Nanoparticles for Effective Magnetism Tailoring.

    Science.gov (United States)

    Moon, Seung Ho; Noh, Seung-Hyun; Lee, Jae-Hyun; Shin, Tae-Hyun; Lim, Yongjun; Cheon, Jinwoo

    2017-02-08

    The magnetic exchange coupling interaction between hard and soft magnetic phases has been important for tailoring nanoscale magnetism, but spin interactions at the core-shell interface have not been well studied. Here, we systematically investigated a new interface phenomenon termed enhanced spin canting (ESC), which is operative when the shell thickness becomes ultrathin, a few atomic layers, and exhibits a large enhancement of magnetic coercivity (HC). We found that ESC arises not from the typical hard-soft exchange coupling but rather from the large magnetic surface anisotropy (KS) of the ultrathin interface. Due to this large increase in magnetism, ultrathin core-shell nanoparticles overreach the theoretical limit of magnetic energy product ((BH)max) and exhibit one of the largest values of specific loss power (SLP), which testifies to their potential capability as an effective mediator of magnetic energy conversion.

  1. Temperature effect on vortex-core reversals in magnetic nanodots

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Bosung; Yoo, Myoung-Woo; Lee, Jehyun; Kim, Sang-Koog, E-mail: sangkoog@snu.ac.kr [Department of Materials Science and Engineering, National Creative Research Initiative Center for Spin Dynamics and Spin-Wave Devices, Nanospinics Laboratory, Research Institute of Advanced Materials, Seoul National University, Seoul 151-744 (Korea, Republic of)

    2015-05-07

    We studied the temperature effect on vortex-core reversals in soft magnetic nanodots by micromagnetic numerical calculations within a framework of the stochastic Landau-Lifshitz-Gilbert scheme. It was determined that vortex-core-switching events at non-zero temperatures occur stochastically, and that the threshold field strength increases with temperature for a given field frequency. The mechanism of core reversals at elevated temperatures is the same as that of vortex-antivortex-pair-mediated core reversals found at the zero temperature. The reversal criterion is also the out-of-plane component of a magnetization dip that should reach −p, which is to say, m{sub z,dip} = −p, where p is the original polarization, p = +1 (−1), for the upward (downward) core. By this criterion, the creation of a vortex-antivortex pair accompanies complete vortex-antivortex-annihilation-mediated core reversals, resulting in the maximum excess of the exchange energy density, ΔE{sub ex}{sup cri} ≈ 15.4 ± 0.2 mJ/cm{sup 3}. This work provides the underlying physics of vortex-core reversals at non-zero temperatures, and potentiates the real application of vortex random access memory operating at elevated temperatures.

  2. The Magnetic Furnace: Intense Core Dynamos in B Stars

    Science.gov (United States)

    Augustson, Kyle C.; Brun, Allan Sacha; Toomre, Juri

    2016-10-01

    The dynamo action achieved in the convective cores of main-sequence massive stars is explored here through three-dimensional (3D) global simulations of convective core dynamos operating within a young 10 {M}⊙ B-type star, using the anelastic spherical harmonic code. These simulations capture the inner 65% of this star by radius, encompassing the convective nuclear-burning core (about 23% by radius) and a portion of the overlying radiative envelope. Eight rotation rates are considered, ranging from 0.05% to 16% of the surface breakup velocity, thereby capturing both convection that barely senses the effects of rotation and other situations in which the Coriolis forces are prominent. The vigorous dynamo action realized within all of these turbulent convective cores builds magnetic fields with peak strengths exceeding a megagauss, with the overall magnetic energy (ME) in the faster rotators reaching super-equipartition levels compared to the convective kinetic energy (KE). The core convection typically involves turbulent columnar velocity structures roughly aligned with the rotation axis, with magnetic fields threading through these rolls and possessing complex linkages throughout the core. The very strong fields are able to coexist with the flows without quenching them through Lorentz forces. The velocity and magnetic fields achieve such a state by being nearly co-aligned, and with peak magnetic islands being somewhat displaced from the fastest flows as the intricate evolution proceeds. As the rotation rate is increased, the primary force balance shifts from nonlinear advection balancing Lorentz forces to a magnetostrophic balance between Coriolis and Lorentz forces.

  3. Magnetic resonance imaging in laboratory petrophysical core analysis

    Science.gov (United States)

    Mitchell, J.; Chandrasekera, T. C.; Holland, D. J.; Gladden, L. F.; Fordham, E. J.

    2013-05-01

    Magnetic resonance imaging (MRI) is a well-known technique in medical diagnosis and materials science. In the more specialized arena of laboratory-scale petrophysical rock core analysis, the role of MRI has undergone a substantial change in focus over the last three decades. Initially, alongside the continual drive to exploit higher magnetic field strengths in MRI applications for medicine and chemistry, the same trend was followed in core analysis. However, the spatial resolution achievable in heterogeneous porous media is inherently limited due to the magnetic susceptibility contrast between solid and fluid. As a result, imaging resolution at the length-scale of typical pore diameters is not practical and so MRI of core-plugs has often been viewed as an inappropriate use of expensive magnetic resonance facilities. Recently, there has been a paradigm shift in the use of MRI in laboratory-scale core analysis. The focus is now on acquiring data in the laboratory that are directly comparable to data obtained from magnetic resonance well-logging tools (i.e., a common physics of measurement). To maintain consistency with well-logging instrumentation, it is desirable to measure distributions of transverse (T2) relaxation time-the industry-standard metric in well-logging-at the laboratory-scale. These T2 distributions can be spatially resolved over the length of a core-plug. The use of low-field magnets in the laboratory environment is optimal for core analysis not only because the magnetic field strength is closer to that of well-logging tools, but also because the magnetic susceptibility contrast is minimized, allowing the acquisition of quantitative image voxel (or pixel) intensities that are directly scalable to liquid volume. Beyond simple determination of macroscopic rock heterogeneity, it is possible to utilize the spatial resolution for monitoring forced displacement of oil by water or chemical agents, determining capillary pressure curves, and estimating

  4. Toroidal-Core Microinductors Biased by Permanent Magnets

    Science.gov (United States)

    Lieneweg, Udo; Blaes, Brent

    2003-01-01

    The designs of microscopic toroidal-core inductors in integrated circuits of DC-to-DC voltage converters would be modified, according to a proposal, by filling the gaps in the cores with permanent magnets that would apply bias fluxes (see figure). The magnitudes and polarities of the bias fluxes would be tailored to counteract the DC fluxes generated by the DC components of the currents in the inductor windings, such that it would be possible to either reduce the sizes of the cores or increase the AC components of the currents in the cores without incurring adverse effects. Reducing the sizes of the cores could save significant amounts of space on integrated circuits because relative to other integrated-circuit components, microinductors occupy large areas - of the order of a square millimeter each. An important consideration in the design of such an inductor is preventing magnetic saturation of the core at current levels up to the maximum anticipated operating current. The requirement to prevent saturation, as well as other requirements and constraints upon the design of the core are expressed by several equations based on the traditional magnetic-circuit approximation. The equations involve the core and gap dimensions and the magnetic-property parameters of the core and magnet materials. The equations show that, other things remaining equal, as the maximum current is increased, one must increase the size of the core to prevent the flux density from rising to the saturation level. By using a permanent bias flux to oppose the flux generated by the DC component of the current, one would reduce the net DC component of flux in the core, making it possible to reduce the core size needed to prevent the total flux density (sum of DC and AC components) from rising to the saturation level. Alternatively, one could take advantage of the reduction of the net DC component of flux by increasing the allowable AC component of flux and the corresponding AC component of current

  5. Multifunctional magnetic and fluorescent core-shell nanoparticles for bioimaging.

    Science.gov (United States)

    Lu, Yanjiao; He, Bicheng; Shen, Jie; Li, Jie; Yang, Wantai; Yin, Meizhen

    2015-02-07

    Novel magnetic and fluorescent core-shell nanoparticles have been fabricated, which exhibit superparamagnetic behavior and emit strong near-infrared fluorescence. The nanoparticles are highly biocompatible and can be internalized into cells with nucleic accumulation via strong interaction with nucleic acids, implying potential applications in the biomedical field.

  6. Misalignment of magnetic fields and outflows in protostellar cores

    NARCIS (Netherlands)

    Hull, Charles L. H.; Plambeck, Richard L.; Bolatto, Alberto D.; Bower, Geoffrey C.; Carpenter, John M.; Crutcher, Richard M.; Fiege, Jason D.; Franzmann, Erica; Hakobian, Nicholas S.; Heiles, Carl; Houde, Martin; Hughes, A. Meredith; Jameson, Katherine; Kwon, Woojin; Lamb, James W.; Looney, Leslie W.; Matthews, Brenda C.; Mundy, Lee; Pillai, Thushara; Pound, Marc W.; Stephens, Ian W.; Tobin, John J.; Vaillancourt, John E.; Volgenau, N. H.; Wright, Melvyn C. H.

    2013-01-01

    We present results of lambda 1.3 mm dust-polarization observations toward 16 nearby, low-mass protostars, mapped with similar to 2 ''.5 resolution at CARMA. The results show that magnetic fields in protostellar cores on scales of similar to 1000 AU are not tightly aligned with outflows from the prot

  7. Analysis of three-phase power transformer laminated magnetic core designs

    Directory of Open Access Journals (Sweden)

    M.I. Levin

    2014-03-01

    Full Text Available Analysis and research into properties and parameters of different-type laminated magnetic cores of three-phase power transformers are conducted. Most of new laminated magnetic core designs are found to have significant shortcomings resulted from design and technological features of their manufacturing. These shortcomings cause increase in ohmic loss in the magnetic core, which eliminates advantages of the new core configurations and makes them uncompetitive as compared with the classical laminated magnetic core design.

  8. Voltage controlled core reversal of fixed magnetic skyrmions without a magnetic field

    Science.gov (United States)

    Bhattacharya, Dhritiman; Al-Rashid, Md Mamun; Atulasimha, Jayasimha

    2016-08-01

    Using micromagnetic simulations we demonstrate core reversal of a fixed magnetic skyrmion by modulating the perpendicular magnetic anisotropy of a nanomagnet with an electric field. We can switch reversibly between two skyrmion states and two ferromagnetic states, i.e. skyrmion states with the magnetization of the core pointing down/up and periphery pointing up/down, and ferromagnetic states with magnetization pointing up/down, by sequential increase and decrease of the perpendicular magnetic anisotropy. The switching between these states is explained by the fact that the spin texture corresponding to each of these stable states minimizes the sum of the magnetic anisotropy, demagnetization, Dzyaloshinskii-Moriya interaction (DMI) and exchange energies. This could lead to the possibility of energy efficient nanomagnetic memory and logic devices implemented with fixed skyrmions without using a magnetic field and without moving skyrmions with a current.

  9. The preparation of core-shell magnetic silica nanospheres for enhancing magnetism and fluorescence intensity.

    Science.gov (United States)

    Yoo, Jeong Ha; Kim, Jong Sung

    2013-11-01

    Recently, magnetic and luminescent composite silica with structure of micro- and nanospheres containing both magnetic (Fe3O4) nanoparticles (MPs) and quantum dots (QDs) has attracted great interests. In this study, we have prepared core-shell structure of silica spheres in which magnets are incorporated into silica core and QDs into a mesoporous silica shell by using C18-TMS (octade-cyltrimethoxysilane). MPs were synthesized by a co-precipitation method from ferrous and ferric solutions with a molecular ratio of 2:3. Monodisperse magnetic silica cores have been prepared via sol-gel reaction of TEOS (tetraethoxysilane) and water using base catalyst. The size of magnetic silica nanospheres was confirmed by dynamic laser light scattering system (DLS) and scanning electoron microscope (SEM). The pore volume and surface area were calculated by using BET after calcination. The core-shell structure plays an important role in providing more domains for MPs in silica Core and QDs in silica shell. QDs were incorporated into the mesoporous shell by hydrophobic interactions. Magnetic characterization was performed using a superconducting quantum interference device (SQUID). The optical properties of the particles were characterized with UV/Vis spectrometer, PL spectrometer, and fluorescence microscope.

  10. Amorphous soft magnetic composite-cores with various orientations of the powder-flakes

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Y.Y.; Wang, Y.G., E-mail: yingang.wang@nuaa.edu.cn; Xia, G.T.

    2015-12-15

    Fe{sub 78}Si{sub 9}B{sub 13} amorphous powder cores were prepared by cold pressing the amorphous powders crushed from amorphous ribbons and orientated with an external magnetic field. Three orientations of magnetic powder cores were obtained: (i) the disorderedly orientated amorphous magnetic powder core (DOAMP), (ii) the circularly orientated amorphous magnetic powder core (COAMP), and (iii) the radially orientated amorphous magnetic powder core (ROAMP). The effect of the shape anisotropy of the flake powders on the magnetic properties of the powder cores was investigated. The powders parallel to external magnetic field is beneficial for achieving the excellent performance of the cores. Below 100 kHz the product of the effective permeability and the quality factor of COAMP core increases by 9.1% and 21.2% compared to that of the DOAMP and the ROAMP cores, respectively, while the coercive field and the magnetic induction intensity keep almost the same. Pressing magnetic powders under a magnetic field to form preferred orientation is suitable for optimal design of soft magnetic cores toward practical applications. - Highlights: • The powders can be orientated to form ordered structure along the magnetic lines. • Circular orientation of the powders improves soft magnetic properties of cores. • Reduction of the demagnetizing field within the powders can increase the µ{sub e}. • Structural ordering can be used for optimal design of magnetic composite materials.

  11. MISALIGNMENT OF MAGNETIC FIELDS AND OUTFLOWS IN PROTOSTELLAR CORES

    Energy Technology Data Exchange (ETDEWEB)

    Hull, Charles L. H.; Plambeck, Richard L.; Bower, Geoffrey C.; Heiles, Carl; Meredith Hughes, A. [Astronomy Department and Radio Astronomy Laboratory, University of California, Berkeley, CA 94720-3411 (United States); Bolatto, Alberto D.; Jameson, Katherine; Mundy, Lee; Pound, Marc W. [Astronomy Department and Laboratory for Millimeter-wave Astronomy, University of Maryland, College Park, MD 20742 (United States); Carpenter, John M.; Lamb, James W.; Pillai, Thushara [Department of Astronomy, California Institute of Technology, 1200 E. California Blvd., MC 249-17, Pasadena, CA 91125 (United States); Crutcher, Richard M.; Hakobian, Nicholas S.; Kwon, Woojin; Looney, Leslie W. [Department of Astronomy, University of Illinois at Urbana-Champaign, 1002 W Green Street, Urbana, IL 61801 (United States); Fiege, Jason D.; Franzmann, Erica [Department of Physics and Astronomy, University of Manitoba, Winnipeg, MB R3T 2N2 (Canada); Houde, Martin [Department of Physics and Astronomy, University of Western Ontario, London, ON N6A 3K7 (Canada); Matthews, Brenda C., E-mail: chat@astro.berkeley.edu [Department of Physics and Astronomy, University of Victoria, 3800 Finnerty Rd., Victoria, BC V8P 5C2 (Canada); and others

    2013-05-10

    We present results of {lambda}1.3 mm dust-polarization observations toward 16 nearby, low-mass protostars, mapped with {approx}2.''5 resolution at CARMA. The results show that magnetic fields in protostellar cores on scales of {approx}1000 AU are not tightly aligned with outflows from the protostars. Rather, the data are consistent with scenarios where outflows and magnetic fields are preferentially misaligned (perpendicular), or where they are randomly aligned. If one assumes that outflows emerge along the rotation axes of circumstellar disks, and that the outflows have not disrupted the fields in the surrounding material, then our results imply that the disks are not aligned with the fields in the cores from which they formed.

  12. Pulsed Magnetic Welding for Advanced Core and Cladding Steel

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Guoping [Univ. of Wisconsin, Madison, WI (United States); Yang, Yong [Univ. of Florida, Gainesville, FL (United States)

    2013-12-19

    To investigate a solid-state joining method, pulsed magnetic welding (PMW), for welding the advanced core and cladding steels to be used in Generation IV systems, with a specific application for fuel pin end-plug welding. As another alternative solid state welding technique, pulsed magnetic welding (PMW) has not been extensively explored on the advanced steels. The resultant weld can be free from microstructure defects (pores, non-metallic inclusions, segregation of alloying elements). More specifically, the following objectives are to be achieved: 1. To design a suitable welding apparatus fixture, and optimize welding parameters for repeatable and acceptable joining of the fuel pin end-plug. The welding will be evaluated using tensile tests for lap joint weldments and helium leak tests for the fuel pin end-plug; 2 Investigate the microstructural and mechanical properties changes in PMW weldments of proposed advanced core and cladding alloys; 3. Simulate the irradiation effects on the PWM weldments using ion irradiation.

  13. Measurement of the nonmagnetic coating thickness of core-shell magnetic nanoparticles by controlled magnetization magnetic force microscopy

    Science.gov (United States)

    Angeloni, L.; Passeri, D.; Scaramuzzo, F. A.; Di Iorio, D.; Barteri, M.; Mantovani, D.; Rossi, M.

    2016-06-01

    Magnetic nanoparticles (MNPs) represent an interesting tool for several biomedical applications. In order to improve the dispersion stability, the biocompatibility and bio-functionality, MNPs need to be coated with non-magnetic films. The optimization of these systems requires the deep characterization not only of the magnetic core, but also of the coating features. Beside the chemical and physical properties of the coating, its thickness is another important property which can influence the size, the shape and the overall magnetic behavior of the NPs system. In this work we propose a possible method to measure the thickness of the non-magnetic coating of core-shell MNPs through the use of controlled magnetization-magnetic force microscopy (CM-MFM). A preliminary study on the applicability of the proposed method has been performed on Fe3O4 NPs coated with a Cu film.

  14. Ferrite core non-linearity in coils for magnetic neurostimulation.

    Science.gov (United States)

    RamRakhyani, Anil Kumar; Lazzi, Gianluca

    2014-10-01

    The need to correctly predict the voltage across terminals of mm-sized coils, with ferrite core, to be employed for magnetic stimulation of the peripheral neural system is the motivation for this work. In such applications, which rely on a capacitive discharge on the coil to realise a transient voltage curve of duration and strength suitable for neural stimulation, the correct modelling of the non-linearity of the ferrite core is critical. A demonstration of how a finite-difference model of the considered coils, which include a model of the current-controlled inductance in the coil, can be used to correctly predict the time-domain voltage waveforms across the terminals of a test coil is presented. Five coils of different dimensions, loaded with ferrite cores, have been fabricated and tested: the measured magnitude and width of the induced pulse are within 10% of simulated values.

  15. Young starless cores embedded in the magnetically dominated Pipe Nebula

    CERN Document Server

    Frau, Pau; Beltran, Maria T; Morata, Oscar; Masque, Josep Maria; Busquet, Gemma; Alves, Felipe O; Sanchez-Monge, Alvaro; Estalella, Robert; Franco, Gabriel A P

    2010-01-01

    The Pipe Nebula is a massive, nearby dark molecular cloud with a low star-formation efficiency which makes it a good laboratory to study the very early stages of the star formation process. The Pipe Nebula is largely filamentary, and appears to be threaded by a uniform magnetic field at scales of few parsecs, perpendicular to its main axis. The field is only locally perturbed in a few regions, such as the only active cluster forming core B59. The aim of this study is to investigate primordial conditions in low-mass pre-stellar cores and how they relate to the local magnetic field in the cloud. We used the IRAM 30-m telescope to carry out a continuum and molecular survey at 3 and 1 mm of early- and late-time molecules toward four selected starless cores inside the Pipe Nebula. We found that the dust continuum emission maps trace better the densest regions than previous 2MASS extinction maps, while 2MASS extinction maps trace better the diffuse gas. The properties of the cores derived from dust emission show av...

  16. Accounting for crustal magnetization in models of the core magnetic field

    Science.gov (United States)

    Jackson, Andrew

    1990-01-01

    The problem of determining the magnetic field originating in the earth's core in the presence of remanent and induced magnetization is considered. The effect of remanent magnetization in the crust on satellite measurements of the core magnetic field is investigated. The crust as a zero-mean stationary Gaussian random process is modelled using an idea proposed by Parker (1988). It is shown that the matrix of second-order statistics is proportional to the Gram matrix, which depends only on the inner-products of the appropriate Green's functions, and that at a typical satellite altitude of 400 km the data are correlated out to an angular separation of approximately 15 deg. Accurate and efficient means of calculating the matrix elements are given. It is shown that the variance of measurements of the radial component of a magnetic field due to the crust is expected to be approximately twice that in horizontal components.

  17. Broadband magnetic losses of nanocrystalline ribbons and powder cores

    Science.gov (United States)

    Beatrice, Cinzia; Dobák, Samuel; Ferrara, Enzo; Fiorillo, Fausto; Ragusa, Carlo; Füzer, Ján; Kollár, Peter

    2016-12-01

    Finemet type alloys have been investigated from DC to 1 GHz at different induction levels upon different treatments: as amorphous precursors, as ribbons nanocrystallized with and without an applied saturating field, as consolidated powders. The lowest energy losses at all frequencies and maximum Snoek's product are exhibited by the transversally field-annealed ribbons. This is understood in terms of rotation-dominated magnetization process in the low-anisotropy material. Intergrain eddy currents are responsible for the fast increase of the losses with frequency and for early permeability relaxation of the powder cores. Evidence for resonant phenomena at high frequencies and for the ensuing inadequate role of the static magnetic constitutive equation of the material in solving the magnetization dynamics via the Maxwell's diffusion equation of the electromagnetic field is provided. It is demonstrated that, by taking the Landau-Lifshitz-Gilbert equation as a constitutive relation, the excellent frequency response of the transverse anisotropy ribbons can be described by analytical method.

  18. Error Analysis of High Frequency Core Loss Measurement for Low-Permeability Low-Loss Magnetic Cores

    DEFF Research Database (Denmark)

    Niroumand, Farideh Javidi; Nymand, Morten

    2016-01-01

    in magnetic cores is B-H loop measurement where two windings are placed on the core under test. However, this method is highly vulnerable to phase shift error, especially for low-permeability, low-loss cores. Due to soft saturation and very low core loss, low-permeability low-loss magnetic cores are favorable....... The analysis has been validated by experimental measurements for relatively low-loss magnetic cores with different permeability values.......Magnetic components significantly contribute to the dissipated loss in power electronic converters. Measuring the true value of dissipated power in these components is highly desirable, since it can be used to verify the optimum design of these components. The common approach for measuring the loss...

  19. The universal criterion for switching a magnetic vortex core in soft magnetic nanodots

    Energy Technology Data Exchange (ETDEWEB)

    Lee, K.-S.; Kim, S.-K.; Yu, Y.-S.; Choi, Y.-S.; Guslienko, K. Y.; Jung, H.; Fischer, P.

    2008-10-01

    The universal criterion for ultrafast vortex core switching between core-up and -down vortex bi-states in soft magnetic nanodots was empirically investigated by micromagnetic simulations and combined with an analytical approach. Vortex-core switching occurs whenever the velocity of vortex core motion reaches a critical value, which is {nu}{sub c} = 330 {+-} 37 m/s for Permalloy, as estimated from numerical simulations. This critical velocity was found to be {nu}{sub c} = {eta}{sub c}{gamma} {radical}A{sub ex} with A{sub ex} the exchange stiffness, {gamma} the gyromagnetic ratio, and an estimated proportional constant {eta}{sub c} = 1.66 {+-} 0.18. This criterion does neither depend on driving force parameters nor on the dimension or geometry of the magnetic specimen. The phase diagrams for the vortex core switching criterion and its switching time with respect to both the strength and angular frequency of circular rotating magnetic fields were derived, which offer practical guidance for implementing vortex core switching into future solid state information storage devices.

  20. Core losses of an inverter-fed permanent magnet synchronous motor with an amorphous stator core under no-load

    Directory of Open Access Journals (Sweden)

    Nicolas Denis

    2016-05-01

    Full Text Available In this paper, an interior permanent magnet synchronous motor (IPMSM with a stator core made of amorphous magnetic material (AMM is presented. The IPMSM is driven by a voltage source three-phase inverter with classical pulse width modulation (PWM control. The core losses under no-load condition are measured by experiment and compared to an equivalent IPMSM with a stator core made of NO steel. Under these conditions, the core losses are influenced by the stator, rotor and magnet shapes but also by the PWM carrier signal that implies a high frequency harmonic in the magnetic flux density. It is demonstrated that the AMM can reduce the core losses by about 56 %.

  1. Modelling of Permanent Magnet Synchronous Motor Incorporating Core-loss

    Directory of Open Access Journals (Sweden)

    K. Suthamno

    2012-08-01

    Full Text Available This study proposes a dq-axis modelling of a Permanent Magnet Synchronous Motor (PMSM with copper-loss and core-loss taken into account. The proposed models can be applied to PMSM control and drive with loss minimization in simultaneous consideration. The study presents simulation results of direct drive of a PMSM under no-load and loaded conditions using the proposed models with MATLAB codes. Comparisons of the results are made among those obtained from using PSIM and SIMULINK software packages. The comparison results indicate very good agreement.

  2. SPIN POLARIZATION AND MAGNETIC DICHROISM IN PHOTOEMISSION FROM CORE AND VALENCE STATES IN LOCALIZED MAGNETIC SYSTEMS

    NARCIS (Netherlands)

    THOLE, BT; VANDERLAAN, G

    1991-01-01

    Using group theory we derive a general model for spin polarization and magnetic dichroism in photo-emission in the presence of atomic interactions between the hole created and the valence holes. We predict strong effects in the photoemission from core levels and localized valence levels of

  3. SPIN POLARIZATION AND MAGNETIC DICHROISM IN PHOTOEMISSION FROM CORE AND VALENCE STATES IN LOCALIZED MAGNETIC SYSTEMS

    NARCIS (Netherlands)

    THOLE, BT; VANDERLAAN, G

    1991-01-01

    Using group theory we derive a general model for spin polarization and magnetic dichroism in photo-emission in the presence of atomic interactions between the hole created and the valence holes. We predict strong effects in the photoemission from core levels and localized valence levels of transitio

  4. Analysis of ringing effects due to magnetic core materials in pulsed nuclear magnetic resonance circuits

    Energy Technology Data Exchange (ETDEWEB)

    Prabhu Gaunkar, N., E-mail: neelampg@iastate.edu; Bouda, N. R. Y.; Nlebedim, I. C.; Hadimani, R. L.; Mina, M.; Jiles, D. C. [Department of Electrical and Computer Engineering, Iowa State University, Ames, Iowa 50011 (United States); Bulu, I.; Ganesan, K.; Song, Y. Q. [Schlumberger-Doll Research, Cambridge, Massachusetts 02139 (United States)

    2015-05-07

    This work presents investigations and detailed analysis of ringing in a non-resonant pulsed nuclear magnetic resonance (NMR) circuit. Ringing is a commonly observed phenomenon in high power switching circuits. The oscillations described as ringing impede measurements in pulsed NMR systems. It is therefore desirable that those oscillations decay fast. It is often assumed that one of the causes behind ringing is the role of the magnetic core used in the antenna (acting as an inductive load). We will demonstrate that an LRC subcircuit is also set-up due to the inductive load and needs to be considered due to its parasitic effects. It is observed that the parasitics associated with the inductive load become important at certain frequencies. The output response can be related to the response of an under-damped circuit and to the magnetic core material. This research work demonstrates and discusses ways of controlling ringing by considering interrelationships between different contributing factors.

  5. Core-level magnetic circular dichroism in 3d and 4f magnetic systems (invited) (abstract)

    Science.gov (United States)

    Koide, T.

    1994-05-01

    With the recent availability of circulary polarized synchrotron radiation over a wide photon energy range from VUV to hard X rays, the magnetic circular dichroism (MCD) in core-level photoabsorption has rapidly attracted growing interest, both experimentally and theoretically. This novel technique can provide element-specific and site-selective information about the magnetic and the electronic states in various magnetic substances because the core-level MCD process involves optical transitions in which the one-electron initial states are well localized and have well-defined angular momenta. In order to get insight into the local magnetic states in 3d and 4f magnetic systems, we have studied MCD of ferrites, Fe1-xPtx alloys, and mixed-valence CeRh3B2 at the core-absorption edges in the VUV˜soft x-ray region. The experiments were performed by utilizing directly characterized, circularly polarized undulator radiation and off-plane synchrotron radiation1 in conjunction with an ultrahigh vacuum compatible superconducting magnet of special design.2 Clear MCD signals were observed for CeRh3B2 in the prethreshold region of the Ce 4d→4f (N4,5) edges. A comparison of the experimental MCD spectrum with theoretical ones3 for uniaxial crystal fields of Δc=0 and 0.2 eV shows that the experimental spectrum qualitatively agrees with the theoretical one for Δc=0 eV. Theory predicts that the MCD pattern for ΔcCeRh3B2. We will also present the MCD data in the M2,3 core-absorption region for ferrites (Fe3O4 and CoFe2O4) and Fe1-xPtx alloys, discussing the results.

  6. Investigation of the influence of magnetostriction and magnetic forces on transformer core noise and vibration

    Science.gov (United States)

    Phophongviwat, Teeraphon

    Transformer noise is of increasing environmental concern so continued efforts are being made by electrical steel and transformer producers to satisfy users by reducing the noise. Magnetostriction and magnetic forces are the main causes of transformer core noise and vibration. Understanding of the relationship from the core material to core structure and core vibration to core noise can help the design of low noise transformer cores. The most appropriate parameter for investigating the relationship between noise and vibration is sound pressure (in the unit of Pascals) in the frequency domain because it is not A-weighted. In this study, the side surfaces of transformer cores were found to emit higher noise than front and top surfaces at low magnetic induction. When the magnetic induction was increased, the effect of magnetic force increased and caused the front surfaces to emit higher noise. For three phase three limb transformer cores, the front surface of the middle limb generated higher noise than the outer limbs due to the effect of T-joint. However this does not translate higher noise level because of the phase difference of the vibration between the limbs. Due to this A-weighted sound power level of three phase, three limb transformer cores were shown to be lower than single phase transformer cores, although at the same cross sectional area and core window size the three phase cores has larger size.. A model, developed to separate the effects of magnetostriction and magnetic forces on transformer core vibration, showed that at low induction, magnetostriction is more significant than magnetic forces. The magnetic forces become more significant than magnetostriction when the induction is increased. Magnetostriction primarily depends on material and stress but magnetic forces principally depend on core building. Louder noise can be generated from a core built with low magnetostriction material than higher magnetostriction if the building tolerances are worse. The

  7. Structural and Magnetic Response in Bimetallic Core/Shell Magnetic Nanoparticles

    Directory of Open Access Journals (Sweden)

    Adeela Nairan

    2016-04-01

    Full Text Available Bimagnetic monodisperse CoFe2O4/Fe3O4 core/shell nanoparticles have been prepared by solution evaporation route. To demonstrate preferential coating of iron oxide onto the surface of ferrite nanoparticles X-ray diffraction (XRD, High resolution transmission electron microscope (HR-TEM and Raman spectroscopy have been performed. XRD analysis using Rietveld refinement technique confirms single phase nanoparticles with average seed size of about 18 nm and thickness of shell is 3 nm, which corroborates with transmission electron microscopy (TEM analysis. Low temperature magnetic hysteresis loops showed interesting behavior. We have observed large coercivity 15.8 kOe at T = 5 K, whereas maximum saturation magnetization (125 emu/g is attained at T = 100 K for CoFe2O4/Fe3O4 core/shell nanoparticles. Saturation magnetization decreases due to structural distortions at the surface of shell below 100 K. Zero field cooled (ZFC and Field cooled (FC plots show that synthesized nanoparticles are ferromagnetic till room temperature and it has been noticed that core/shell sample possess high blocking temperature than Cobalt Ferrite. Results indicate that presence of iron oxide shell significantly increases magnetic parameters as compared to the simple cobalt ferrite.

  8. Structural and Magnetic Response in Bimetallic Core/Shell Magnetic Nanoparticles

    Science.gov (United States)

    Nairan, Adeela; Khan, Usman; Iqbal, Munawar; Khan, Maaz; Javed, Khalid; Riaz, Saira; Naseem, Shahzad; Han, Xiufeng

    2016-01-01

    Bimagnetic monodisperse CoFe2O4/Fe3O4 core/shell nanoparticles have been prepared by solution evaporation route. To demonstrate preferential coating of iron oxide onto the surface of ferrite nanoparticles X-ray diffraction (XRD), High resolution transmission electron microscope (HR-TEM) and Raman spectroscopy have been performed. XRD analysis using Rietveld refinement technique confirms single phase nanoparticles with average seed size of about 18 nm and thickness of shell is 3 nm, which corroborates with transmission electron microscopy (TEM) analysis. Low temperature magnetic hysteresis loops showed interesting behavior. We have observed large coercivity 15.8 kOe at T = 5 K, whereas maximum saturation magnetization (125 emu/g) is attained at T = 100 K for CoFe2O4/Fe3O4 core/shell nanoparticles. Saturation magnetization decreases due to structural distortions at the surface of shell below 100 K. Zero field cooled (ZFC) and Field cooled (FC) plots show that synthesized nanoparticles are ferromagnetic till room temperature and it has been noticed that core/shell sample possess high blocking temperature than Cobalt Ferrite. Results indicate that presence of iron oxide shell significantly increases magnetic parameters as compared to the simple cobalt ferrite.

  9. Photoemission and core-level magnetic circular dichroism studies of diluted magnetic semiconductors

    Energy Technology Data Exchange (ETDEWEB)

    Fujimori, A. [Department of Complexity Science and Engineering, Universtiy of Tokyo, 1-5-1 Kashiwanoha, Kashiwa, Chiba 277-8561 (Japan) and Synchrotron Radiation Research Center, Japan Atomic Energy Research Institute, SPring-8, Mikazuki, Hyogo 679-5148 (Japan)]. E-mail: fujimori@phys.s.u-tokyo.ac.jp; Okabayashi, J. [Department of Applied Chemistry, University of Tokyo, 7-3-1 Hongo, Bunkyou-ku, Tokyo 113-8656 (Japan); Takeda, Y. [Synchrotron Radiation Research Center, Japan Atomic Energy Research Institute, SPring-8, Mikazuki, Hyogo 679-5148 (Japan); Mizokawa, T. [Department of Complexity Science and Engineering, Universtiy of Tokyo, 1-5-1 Kashiwanoha, Kashiwa, Chiba 277-8561 (Japan); Okamoto, J. [Synchrotron Radiation Research Center, Japan Atomic Energy Research Institute, SPring-8, Mikazuki, Hyogo 679-5148 (Japan); Mamiya, K. [Photon Factory, IMSS, High Energy Accelerator Research Organization, Tsukuba, Ibaraki 305 (Japan); Saitoh, Y. [Synchrotron Radiation Research Center, Japan Atomic Energy Research Institute, SPring-8, Mikazuki, Hyogo 679-5148 (Japan); Muramatsu, Y. [Synchrotron Radiation Research Center, Japan Atomic Energy Research Institute, SPring-8, Mikazuki, Hyogo 679-5148 (Japan); Oshima, M. [Department of Applied Chemistry, University of Tokyo, 7-3-1 Hongo, Bunkyou-ku, Tokyo 113-8656 (Japan); Ohya, S. [Department of Electronic Engineering, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan); Tanaka, M. [Department of Electronic Engineering, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

    2005-06-15

    An overview is given on the photoemission studies of the electronic structure of diluted magnetic semiconductors (DMS's), in particular of the prototypical ferromagnetic DMS Ga{sub 1-x}Mn{sub x}As. Configuration-interaction cluster-model analyses of the photoemission data allow us to estimate the p-d exchange coupling constant and hence to predict how to increase the Curie temperature in new materials. Spectra near the Fermi level combined with the transport and optical properties suggest a highly incoherent metallic state for the ferromagnetic metallic phase. It is shown that new insight into the chemically and magnetically inhomogeneous states of DMS's can be gained by the temperature and magnetic field dependence of core-level magnetic circular dichroism signals.

  10. Criterion of Magnetic Saturation and Simulation of Nonlinear Magnetization for a Linear Multi-core Pulse Transformer

    Institute of Scientific and Technical Information of China (English)

    曾正中; 蒯斌; 孙凤举; 丛培天; 邱爱慈

    2002-01-01

    The linear multi-core pulse transformer is an important primary driving source usedin pulsed power apparatus for the production of dense plasma owing to its compact, relatively low-cost and easy-to-handle characteristics. The evaluation of the magnetic saturation of the transformer cores is essential to the transformer design, because the energy transfer efficiency of the transformer will degrade significantly after magnetic saturation. This work proposes analytical formulas of the criterion of magnetic saturation for the cores when the transformer drives practical loads. Furthermore, an electric circuit model based on a dependent source treatment for simulating the electric behavior of the cores related to their nonlinear magnetization is developed using the initial magnetization curve of the cores. The numerical simulation with the model is used to evaluate the validity of the criterion. Both the criterion and the model are found to be in agreement with the experimental data.

  11. Phase locking of vortex cores in two coupled magnetic nanopillars

    Directory of Open Access Journals (Sweden)

    Qiyuan Zhu

    2014-11-01

    Full Text Available Phase locking dynamics of the coupled vortex cores in two identical magnetic spin valves induced by spin-polarized current are studied by means of micromagnetic simulations. Our results show that the available current range of phase locking can be expanded significantly by the use of constrained polarizer, and the vortices undergo large orbit motions outside the polarization areas. The effects of polarization areas and dipolar interaction on the phase locking dynamics are studied systematically. Phase locking parameters extracted from simulations are discussed by theoreticians. The dynamics of vortices influenced by spin valve geometry and vortex chirality are discussed at last. This work provides deeper insights into the dynamics of phase locking and the results are important for the design of spin-torque nano-oscillators.

  12. Numerical Analysis of Magnetic Force of Dry-Type Air-Core Reactor

    Institute of Scientific and Technical Information of China (English)

    LIUZhi-gang; GENGYing-san; WANGJian-hua

    2004-01-01

    This paper presents a coupled magnetic-circuit method for computing the magnetic force of air-core reactor under short-time current. The current and the magnetic flux density are computed first and then the magnetic force is obtained. Thus, the dynamic stability performance of air-core reactor can be analyzed at the design stage to reduce experimental cost and shorten the lead-time of product development.

  13. Nanoscale switch for vortex polarization mediated by Bloch core formation in magnetic hybrid systems

    Science.gov (United States)

    Wohlhüter, Phillip; Bryan, Matthew Thomas; Warnicke, Peter; Gliga, Sebastian; Stevenson, Stephanie Elizabeth; Heldt, Georg; Saharan, Lalita; Suszka, Anna Kinga; Moutafis, Christoforos; Chopdekar, Rajesh Vilas; Raabe, Jörg; Thomson, Thomas; Hrkac, Gino; Heyderman, Laura Jane

    2015-08-01

    Vortices are fundamental magnetic topological structures characterized by a curling magnetization around a highly stable nanometric core. The control of the polarization of this core and its gyration is key to the utilization of vortices in technological applications. So far polarization control has been achieved in single-material structures using magnetic fields, spin-polarized currents or spin waves. Here we demonstrate local control of the vortex core orientation in hybrid structures where the vortex in an in-plane Permalloy film coexists with out-of-plane maze domains in a Co/Pd multilayer. The vortex core reverses its polarization on crossing a maze domain boundary. This reversal is mediated by a pair of magnetic singularities, known as Bloch points, and leads to the transient formation of a three-dimensional magnetization structure: a Bloch core. The interaction between vortex and domain wall thus acts as a nanoscale switch for the vortex core polarization.

  14. Homogeneous protein analysis by magnetic core-shell nanorod probes

    KAUST Repository

    Schrittwieser, Stefan

    2016-03-29

    Studying protein interactions is of vital importance both to fundamental biology research and to medical applications. Here, we report on the experimental proof of a universally applicable label-free homogeneous platform for rapid protein analysis. It is based on optically detecting changes in the rotational dynamics of magnetically agitated core-shell nanorods upon their specific interaction with proteins. By adjusting the excitation frequency, we are able to optimize the measurement signal for each analyte protein size. In addition, due to the locking of the optical signal to the magnetic excitation frequency, background signals are suppressed, thus allowing exclusive studies of processes at the nanoprobe surface only. We study target proteins (soluble domain of the human epidermal growth factor receptor 2 - sHER2) specifically binding to antibodies (trastuzumab) immobilized on the surface of our nanoprobes and demonstrate direct deduction of their respective sizes. Additionally, we examine the dependence of our measurement signal on the concentration of the analyte protein, and deduce a minimally detectable sHER2 concentration of 440 pM. For our homogeneous measurement platform, good dispersion stability of the applied nanoprobes under physiological conditions is of vital importance. To that end, we support our measurement data by theoretical modeling of the total particle-particle interaction energies. The successful implementation of our platform offers scope for applications in biomarker-based diagnostics as well as for answering basic biology questions.

  15. High performance multi-core iron oxide nanoparticles for magnetic hyperthermia: microwave synthesis, and the role of core-to-core interactions

    Science.gov (United States)

    Blanco-Andujar, C.; Ortega, D.; Southern, P.; PankhurstJoint Last Authors., Q. A.; Thanh, N. T. K.

    2015-01-01

    The adoption of magnetic hyperthermia as either a stand-alone or adjunct therapy for cancer is still far from being optimised due to the variable performance found in many iron oxide nanoparticle systems, including commercially available formulations. Herein, we present a reproducible and potentially scalable microwave-based method to make stable citric acid coated multi-core iron oxide nanoparticles, with exceptional magnetic heating parameters, viz. intrinsic loss parameters (ILPs) of up to 4.1 nH m2 kg-1, 35% better than the best commercial equivalents. We also probe the core-to-core magnetic interactions in the particles via remanence-derived Henkel and ΔM plots. These reveal a monotonic dependence of the ILP on the magnetic interaction field Hint, and show that the interactions are demagnetising in nature, and act to hinder the magnetic heating mechanism.The adoption of magnetic hyperthermia as either a stand-alone or adjunct therapy for cancer is still far from being optimised due to the variable performance found in many iron oxide nanoparticle systems, including commercially available formulations. Herein, we present a reproducible and potentially scalable microwave-based method to make stable citric acid coated multi-core iron oxide nanoparticles, with exceptional magnetic heating parameters, viz. intrinsic loss parameters (ILPs) of up to 4.1 nH m2 kg-1, 35% better than the best commercial equivalents. We also probe the core-to-core magnetic interactions in the particles via remanence-derived Henkel and ΔM plots. These reveal a monotonic dependence of the ILP on the magnetic interaction field Hint, and show that the interactions are demagnetising in nature, and act to hinder the magnetic heating mechanism. Electronic supplementary information (ESI) available: Reproducibility studies and additional characterisation data including SQUID Magnetometry, TEM, ATR-FTIR, XRD and Mossbauer spectroscopy. See DOI: 10.1039/c4nr06239f

  16. Magnetic properties of Ni/Au core/shell studied by Monte Carlo simulations

    Energy Technology Data Exchange (ETDEWEB)

    Masrour, R., E-mail: rachidmasrour@hotmail.com [Laboratory of Materials, Processes, Environment and Quality, Cady Ayyed University, National School of Applied Sciences, Sidi Bouzid, Safi, 63 4600 (Morocco); LMPHE (URAC 12), Faculté des Sciences, Université Mohammed V-Agdal, Av. Ibn Batouta, B.P. 1014, Rabat (Morocco); Bahmad, L. [LMPHE (URAC 12), Faculté des Sciences, Université Mohammed V-Agdal, Av. Ibn Batouta, B.P. 1014, Rabat (Morocco); Hamedoun, M. [Institute of Nanomaterials and Nanotechnologies, MAScIR, Rabat (Morocco); Benyoussef, A. [LMPHE (URAC 12), Faculté des Sciences, Université Mohammed V-Agdal, Av. Ibn Batouta, B.P. 1014, Rabat (Morocco); Institute of Nanomaterials and Nanotechnologies, MAScIR, Rabat (Morocco); Hassan II Academy of Science and Technology, Rabat (Morocco); Hlil, E.K. [Institut Néel, CNRS et Université Joseph Fourier, BP 166, F-38042 Grenoble cedex 9 (France)

    2014-01-10

    The magnetic properties of ferromagnetic Ni/Au core/shell have been studied using Monte Carlo simulations within the Ising model framework. The considered Hamiltonian includes the exchange interactions between Ni–Ni, Au–Au and Ni–Au and the external magnetic field. The thermal total magnetizations and total magnetic susceptibilities of core/shell Ni/Au are computed. The critical temperature is deduced. The exchange interaction between Ni and Au atoms is obtained. In addition, the total magnetizations versus the external magnetic field and crystal filed for different temperature are also established.

  17. Correlation between the Earth's Magnetic Field and the Gravitational Mass of the Outer Core

    OpenAIRE

    De Aquino, Fran

    2013-01-01

    The theory accepted today for the origin of the Earth's magnetic field is based on convection currents created in the Earth's outer core due to the rotational motion of the planet Earth around its own axis. In this work, we show that the origin of the Earth's magnetic field is related to the gravitational mass of the outer core.

  18. Quality factor of an electrically small magnetic dipole antenna with magneto-dielectric core

    DEFF Research Database (Denmark)

    Kim, Oleksiy S.; Breinbjerg, Olav

    2010-01-01

    In this work, we investigate the radiation Q of electrically small magnetic dipole antennas with magneto-dielectric core versus the antenna electrical size, permittivity and permeability of the core. The investigation is based on the exact theory for a spherical magnetic dipole antenna...

  19. Non-Equilibrium Chemistry of Dynamically Evolving Prestellar Cores: I. Basic Magnetic and Non-Magnetic Models and Parameter Studies

    CERN Document Server

    Tassis, Konstantinos; Yorke, Harold W; Turner, Neal

    2011-01-01

    We combine dynamical and non-equilibrium chemical modeling of evolving prestellar molecular cloud cores, and explore the evolution of molecular abundances in the contracting core. We model both magnetic cores, with varying degrees of initial magnetic support, and non-magnetic cores, with varying collapse delay times. We explore, through a parameter study, the competing effects of various model parameters in the evolving molecular abundances, including the elemental C/O ratio, the temperature, and the cosmic-ray ionization rate. We find that different models show their largest quantitative differences at the center of the core, whereas the outer layers, which evolve slower, have abundances which are severely degenerate among different dynamical models. There is a large range of possible abundance values for different models at a fixed evolutionary stage (central density), which demonstrates the large potential of chemical differentiation in prestellar cores. However, degeneracies among different models, compou...

  20. Effect of annealing process of iron powder on magnetic properties and losses of motor cores

    Indian Academy of Sciences (India)

    Fuzheng Yin; Haibo Yang; Jianjun Tian; De-An Pan; Jian Wang; Shengen Zhang

    2011-07-01

    Iron powder magnetic cores are used as soft magnetic rotors, in micro special motors such as BS brake motors, refrigerator compressor motors and brushless servo motors. Heat treatment of iron powder played an important role in the magnetic properties and loss of the motor cores. After the annealing process, the cracks and the pores on the surface of the powder decreased which in turn decreased the micro-hardness. The Vickers-hardness of the powder decreased from 50–42, while the resistance of the cores increased by 87% after annealing at 400°C for 30 min. The amplitude permeability and magnetic loss of the cores reached the maximum and minimum values, respectively. The magnetic loss of the cores was separated into hysteresis loss and eddy current loss by Stoppels Method which were decreased by the annealing process.

  1. Engineered magnetic core shell nanoprobes:Synthesis and applications to cancer imaging and therapeutics

    Institute of Scientific and Technical Information of China (English)

    Samir Mandal; Keya Chaudhuri

    2016-01-01

    Magnetic core shell nanoparticles are composed of a highly magnetic core material surrounded by a thin shell of desired drug, polymer or metal oxide. These magnetic core shell nanoparticles have a wide range of applications in biomedical research, more specifically in tissue imaging, drug delivery and therapeutics. The present review discusses the up-to-date knowledge on the various procedures for synthesis of magnetic core shell nanoparticles along with their applications in cancer imaging, drug delivery and hyperthermia or cancer therapeutics. Literature in this area shows that magnetic core shell nanoparticle-based imaging, drug targeting and therapy through hyperthermia can potentially be a powerful tool for the advanced diagnosis and treatment of various cancers.

  2. Engineered magnetic core shell nanoprobes: Synthesis and applications to cancer imaging and therapeutics.

    Science.gov (United States)

    Mandal, Samir; Chaudhuri, Keya

    2016-02-26

    Magnetic core shell nanoparticles are composed of a highly magnetic core material surrounded by a thin shell of desired drug, polymer or metal oxide. These magnetic core shell nanoparticles have a wide range of applications in biomedical research, more specifically in tissue imaging, drug delivery and therapeutics. The present review discusses the up-to-date knowledge on the various procedures for synthesis of magnetic core shell nanoparticles along with their applications in cancer imaging, drug delivery and hyperthermia or cancer therapeutics. Literature in this area shows that magnetic core shell nanoparticle-based imaging, drug targeting and therapy through hyperthermia can potentially be a powerful tool for the advanced diagnosis and treatment of various cancers.

  3. Microwave-induced dynamic switching of magnetic skyrmion cores in nanodots

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Bin; Kuch, Wolfgang, E-mail: kuch@physik.fu-berlin.de [Institut für Experimentalphysik, Freie Universität Berlin, Arnimallee 14, 14195 Berlin (Germany); Wang, Weiwei; Beg, Marijan; Fangohr, Hans [Faculty of Engineering and the Environment, University of Southampton, SO17 1BJ Southampton (United Kingdom)

    2015-03-09

    The nonlinear dynamic behavior of a magnetic skyrmion in circular nanodots was studied numerically by solving the Landau-Lifshitz-Gilbert equation with a classical spin model. We show that a skyrmion core reversal can be achieved within nanoseconds using a perpendicular oscillating magnetic field. Two symmetric switching processes that correspond to excitations of the breathing mode and the mixed mode (combination of the breathing mode and a radial spin-wave mode) are identified. For excitation of the breathing mode, the skyrmion core switches through nucleation of a new core from a transient uniform state. In the mixed mode, the skyrmion core reverses with the help of spins excited both at the edge and core regions. Unlike the magnetic vortex core reversal, the excitation of radial spin waves does not dominate the skyrmion core reversal process.

  4. Analysis and experiment of eddy current loss in Homopolar magnetic bearings with laminated rotor cores

    Science.gov (United States)

    Jinji, Sun; Dong, Chen

    2013-08-01

    This paper analyses the eddy current loss in Homopolar magnetic bearings with laminated rotor cores produced by the high speed rotation in order to reduce the power loss for the aerospace applications. The analytical model of rotational power loss is proposed in Homopolar magnetic bearings with laminated rotor cores considering the magnetic circuit difference between Homopolar and Heteropolar magnetic bearings. Therefore, the eddy current power loss can be calculated accurately using the analytical model by magnetic field solutions according to the distribution of magnetic fields around the pole surface and boundary conditions at the surface of the rotor cores. The measurement method of rotational power loss in Homopolar magnetic bearing is proposed, and the results of the theoretical analysis are verified by experiments in the prototype MSCMG. The experimental results show the correctness of calculation results.

  5. The simulation of low core loss high speed permanent magnet motor based on soft-magnetic ferrite

    Science.gov (United States)

    Wang, Xinghua; Fang, Xue; Guo, Yingjie; Wang, Xiuhe

    2006-11-01

    High core loss is the most outstanding problem in high speed permanent magnet motors. To solve this problem, water cooling or oil cooling is usually adopted, which increase the complexity and cost. Considering the characters of high permeability, high resistivity, low loss and low cost for soft magnetic ferrite, this paper proposes a novel high speed PM motor based on soft magnetic ferrite. Soft magnetic ferrite ring is used as stator core, rare earth PM ring serves as the rotor poles, and the slotless configuration with long effective air gap is adopted. The size matching design between the stator magnetic ring and the PM magnetic ring can make themselves work in their best operating points respectively, lower core loss and higher power density will be ensured in the motor. The results of magnetic field analysis, core loss analysis and the prototype test prove that the core loss can be greatly reduced, which verifies that the high speed PM BLDC motor based on soft magnetic ferrite is feasible.

  6. Insulator coated magnetic nanoparticulate composites with reduced core loss and method of manufacture thereof

    Science.gov (United States)

    Zhang, Yide (Inventor); Wang, Shihe (Inventor); Xiao, Danny (Inventor)

    2004-01-01

    A series of bulk-size magnetic/insulating nanostructured composite soft magnetic materials with significantly reduced core loss and its manufacturing technology. This insulator coated magnetic nanostructured composite is comprises a magnetic constituent, which contains one or more magnetic components, and an insulating constituent. The magnetic constituent is nanometer scale particles (1-100 nm) coated by a thin-layered insulating phase (continuous phase). While the intergrain interaction between the immediate neighboring magnetic nanoparticles separated by the insulating phase (or coupled nanoparticles) provide the desired soft magnetic properties, the insulating material provides the much demanded high resistivity which significantly reduces the eddy current loss. The resulting material is a high performance magnetic nanostructured composite with reduced core loss.

  7. Reduction of the unbalanced magnetic force of a transverse flux machine by using symmetric multipair cores

    Science.gov (United States)

    Jang, G. H.; Park, N. K.; Lee, C. I.; Chang, J. H.; Jeong, S. W.; Kang, D. H.

    2008-04-01

    This paper investigates the characteristics of the magnetic force and the torque in the conventional rotatory two-phase transverse flux machine (TFM) by using the three-dimensional finite element method. This research shows that the unbalanced magnetic force is one of the dominant excitation forces in this machine, and it proposes a TFM with symmetric multipair cores in which each stator core of phases A and B is divided into two and the divided cores are disposed symmetrically to cancel the unbalanced magnetic force of each phase of a TFM. However, symmetric multipair cores of a TFM may reduce the winding space of coil which results in the reduction of torque and power. This research performs the optimization of teeth-slot configuration of the stator to overcome this shortcoming. It shows that the unbalance magnetic force of a TFM can be effectively eliminated without sacrificing torque or power by introducing symmetric multipair cores.

  8. X-ray imaging of vortex cores in confined magnetic structures

    Energy Technology Data Exchange (ETDEWEB)

    Fischer, P; Im, M -Y; Kasai, S; Yamada, K; Ono, T; Thiaville, A

    2011-02-11

    Cores of magnetic vortices in micron-sized NiFe disk structures, with thicknesses between 150 and 50 nm, were imaged and analyzed by high-resolution magnetic soft x-ray microscopy. A decrease of the vortex-core radius was observed from approximately 38 to 18 nm with decreasing disk thickness. By comparing with full three-dimensional micromagnetic simulations showing the well-known barrel structure, we obtained excellent agreement, taking into account instrumental broadening and a small perpendicular anisotropy. The proven magnetic spatial resolution of better than 25 nm was sufficient to identify a negative dip close to the vortex core, originating from stray fields of the core. Magnetic vortex structures can serve as test objects for evaluating sensitivity and spatial resolution of advanced magnetic microscopy techniques.

  9. Magnetic core-shell nanoparticles for drug delivery by nebulization

    Directory of Open Access Journals (Sweden)

    Verma Navin Kumar

    2013-01-01

    Full Text Available Abstract Background Aerosolized therapeutics hold great potential for effective treatment of various diseases including lung cancer. In this context, there is an urgent need to develop novel nanocarriers suitable for drug delivery by nebulization. To address this need, we synthesized and characterized a biocompatible drug delivery vehicle following surface coating of Fe3O4 magnetic nanoparticles (MNPs with a polymer poly(lactic-co-glycolic acid (PLGA. The polymeric shell of these engineered nanoparticles was loaded with a potential anti-cancer drug quercetin and their suitability for targeting lung cancer cells via nebulization was evaluated. Results Average particle size of the developed MNPs and PLGA-MNPs as measured by electron microscopy was 9.6 and 53.2 nm, whereas their hydrodynamic swelling as determined using dynamic light scattering was 54.3 nm and 293.4 nm respectively. Utilizing a series of standardized biological tests incorporating a cell-based automated image acquisition and analysis procedure in combination with real-time impedance sensing, we confirmed that the developed MNP-based nanocarrier system was biocompatible, as no cytotoxicity was observed when up to 100 μg/ml PLGA-MNP was applied to the cultured human lung epithelial cells. Moreover, the PLGA-MNP preparation was well-tolerated in vivo in mice when applied intranasally as measured by glutathione and IL-6 secretion assays after 1, 4, or 7 days post-treatment. To imitate aerosol formation for drug delivery to the lungs, we applied quercitin loaded PLGA-MNPs to the human lung carcinoma cell line A549 following a single round of nebulization. The drug-loaded PLGA-MNPs significantly reduced the number of viable A549 cells, which was comparable when applied either by nebulization or by direct pipetting. Conclusion We have developed a magnetic core-shell nanoparticle-based nanocarrier system and evaluated the feasibility of its drug delivery capability via aerosol

  10. Magnetic core-shell nanoparticles for drug delivery by nebulization

    LENUS (Irish Health Repository)

    Verma, Navin Kumar

    2013-01-23

    AbstractBackgroundAerosolized therapeutics hold great potential for effective treatment of various diseases including lung cancer. In this context, there is an urgent need to develop novel nanocarriers suitable for drug delivery by nebulization. To address this need, we synthesized and characterized a biocompatible drug delivery vehicle following surface coating of Fe3O4 magnetic nanoparticles (MNPs) with a polymer poly(lactic-co-glycolic acid) (PLGA). The polymeric shell of these engineered nanoparticles was loaded with a potential anti-cancer drug quercetin and their suitability for targeting lung cancer cells via nebulization was evaluated.ResultsAverage particle size of the developed MNPs and PLGA-MNPs as measured by electron microscopy was 9.6 and 53.2 nm, whereas their hydrodynamic swelling as determined using dynamic light scattering was 54.3 nm and 293.4 nm respectively. Utilizing a series of standardized biological tests incorporating a cell-based automated image acquisition and analysis procedure in combination with real-time impedance sensing, we confirmed that the developed MNP-based nanocarrier system was biocompatible, as no cytotoxicity was observed when up to 100 mug\\/ml PLGA-MNP was applied to the cultured human lung epithelial cells. Moreover, the PLGA-MNP preparation was well-tolerated in vivo in mice when applied intranasally as measured by glutathione and IL-6 secretion assays after 1, 4, or 7 days post-treatment. To imitate aerosol formation for drug delivery to the lungs, we applied quercitin loaded PLGA-MNPs to the human lung carcinoma cell line A549 following a single round of nebulization. The drug-loaded PLGA-MNPs significantly reduced the number of viable A549 cells, which was comparable when applied either by nebulization or by direct pipetting.ConclusionWe have developed a magnetic core-shell nanoparticle-based nanocarrier system and evaluated the feasibility of its drug delivery capability via aerosol administration. This study has

  11. Magnetic field amplification and magnetically supported explosions of collapsing, non-rotating stellar cores

    CERN Document Server

    Obergaulinger, Martin; Toras, Miguel Angel Aloy

    2014-01-01

    We study the amplification of magnetic fields in the collapse and the post-bounce evolution of the core of a non-rotating star of 15 solar masses in axisymmetry. To this end, we solve the coupled equations of magnetohydrodynamics and neutrino transport in the two-moment approximation. The pre-collapse magnetic field is strongly amplified by compression in the infall. Initial fields of the order of 1010 G translate into proto-neutron star fields similar to the ones observed in pulsars, while stronger initial fields yield magnetar-like final field strengths. After core bounce, the field is advected through the hydrodynamically unstable neutrino-heating layer, where non-radial flows due to convection and the standing accretion shock instability amplify the field further. Consequently, the resulting amplification factor of order five is the result of the number of small-eddy turnovers taking place within the time scale of advection through the post-shock layer. Due to this limit, most of our models do not reach e...

  12. Effect of superconducting solenoid model cores on spanwise iron magnet roll control

    Science.gov (United States)

    Britcher, C. P.

    1985-01-01

    Compared with conventional ferromagnetic fuselage cores, superconducting solenoid cores appear to offer significant reductions in the projected cost of a large wind tunnel magnetic suspension and balance system. The provision of sufficient magnetic roll torque capability has been a long-standing problem with all magnetic suspension and balance systems; and the spanwise iron magnet scheme appears to be the most powerful system available. This scheme utilizes iron cores which are installed in the wings of the model. It was anticipated that the magnetization of these cores, and hence the roll torque generated, would be affected by the powerful external magnetic field of the superconducting solenoid. A preliminary study has been made of the effect of the superconducting solenoid fuselage model core concept on the spanwise iron magnet roll torque generation schemes. Computed data for one representative configuration indicate that reductions in available roll torque occur over a range of applied magnetic field levels. These results indicate that a 30-percent increase in roll electromagnet capacity over that previously determined will be required for a representative 8-foot wind tunnel magnetic suspension and balance system design.

  13. Inner Core Anisotropy Due to the Magnetic Field--induced Preferred Orientation of Iron.

    Science.gov (United States)

    Karato, S

    1993-12-10

    Anisotropy of the inner core of the Earth is proposed to result from the lattice preferred orientation of anisotropic iron crystals during their solidification in the presence of a magnetic field. The resultant seismic anisotropy is related to the geometry of the magnetic field in the core. This hypothesis implies that the observed anisotropy (fast velocity along the rotation axis) indicates a strong toroidal field in the core, which supports a strong field model for the geodynamo if the inner core is made of hexagonal close-packed iron.

  14. Coercivity enhancement in Ce-Fe-B based magnets by core-shell grain structuring

    Directory of Open Access Journals (Sweden)

    M. Ito

    2016-05-01

    Full Text Available Ce-based R2Fe14B (R= rare-earth nano-structured permanent magnets consisting of (Ce,Nd2Fe14B core-shell grains separated by a non-magnetic grain boundary phase, in which the relative amount of Nd to Ce is higher in the shell of the magnetic grain than in its core, were fabricated by Nd-Cu infiltration into (Ce,Nd2Fe14B hot-deformed magnets. The coercivity values of infiltrated core-shell structured magnets are superior to those of as-hot-deformed magnets with the same overall Nd content. This is attributed to the higher value of magnetocrystalline anisotropy of the shell phase in the core-shell structured infiltrated magnets compared to the homogeneous R2Fe14B grains of the as-hot-deformed magnets, and to magnetic isolation of R2Fe14B grains by the infiltrated grain boundary phase. First order reversal curve (FORC diagrams suggest that the higher anisotropy shell suppresses initial magnetization reversal at the edges and corners of the R2Fe14B grains.

  15. Method for introducing bias magnetization in ungaped cores

    DEFF Research Database (Denmark)

    Aguilar, Andres Revilla; Munk-Nielsen, Stig

    2014-01-01

    The use of permanent magnets for bias magnetization is a known technique to increase the energy storage capability in DC inductors, resulting in a size reduction or increased current rating. This paper presents a brief introduction on the different permanent magnet inductor’s configurations found...

  16. Mechanically strong nanocrystalline Fe-Si-B-P-Cu soft magnetic powder cores utilizing magnetic metallic glass as a binder

    Directory of Open Access Journals (Sweden)

    Jian Luan

    2016-05-01

    Full Text Available We report on the fabrication and properties of soft magnetic powder cores with superior mechanical strength as well as low core loss (W. Development of such cores is important for applications in automobiles/devices operating in motion. High saturation magnetic flux density (Bs Fe-Si-B-P-Cu powder was sintered with Fe55C10B5P10Ni15Mo5 metallic glass (MG powder in its supercooled liquid state by spark plasma sintering. The sintered cores are made from the nanocrystalline powder particles of Fe-Si-B-P-Cu alloy, which are separated through a magnetic Fe55C10B5P10Ni15Mo5 MG alloy. Low W of ∼ 2.2 W/kg (at 1T and 50 Hz, and high fracture strength (yielding stress ∼500 MPa, which is an order of magnitude higher than the conventional powder cores, were obtained. Stronger metal-metal bonding and magnetic nature of MG binder (which is very different than the conventional polymer based binders are responsible for the superior mechanical and magnetic properties. The MG binder not only helps in improving the mechanical properties but it also enhances the overall Bs of the core.

  17. Core-shell magnetic nanoparticles for on-chip RF inductors

    KAUST Repository

    Koh, Kisik

    2013-01-01

    FeNi3 based core-shell magnetic nanoparticles are demonstrated as the magnetic core material for on-chip, radio frequency (RF) inductors. FeNi3 nanoparticles with 50-150 nm in diameter with 15-20 nm-thick SiO2 coating are chemically synthesized and deposited on a planar inductor as the magnetic core to enhance both inductance (L) and quality factor (Q) of the inductor. Experimentally, the ferromagnetic resonant frequency of the on-chip inductors based on FeNi3 core-shell nanoparticles has been shown to be over several GHz. A post-CMOS process has been developed to integrate the magnetic nanoparticles to a planar inductor and inductance enhancements up to 50% of the original magnitude with slightly enhanced Q-factor up to 1 GHz have been achieved. © 2013 IEEE.

  18. Outstanding efficiency in energy conversion for electric motors constructed by nanocrystalline soft magnetic alloy "NANOMET®" cores

    Science.gov (United States)

    Nishiyama, N.; Tanimoto, K.; Makino, A.

    2016-05-01

    Recently updated nanocrystalline soft magnetic Fe-Co-Si-B-P-Cu alloys "NANOMET®" exhibit high saturation magnetic flux density (Bs > 1.8 T), low coercivity (Hc DC motor using NANOMET® core exhibited remarkable improvement in energy consumption. The prototype motor with an outer core diameter of 70 mm and a core thickness of 50 mm was constructed using laminated nano-crystallized NANOMET® ribbons. Core-loss for the constructed motor was improved from 1.4 W to 0.4 W only by replacing the non-oriented Si-steel core with NANOMET® one. The overall motor efficiency is evaluated to be 3% improvement. In this work, the relation between processing and resulting magnetic properties will be presented. In addition, feasibility for commercialization will also be discussed.

  19. DC bias immune nanocrystalline magnetic cores made of Fe73Nb3Cu1B7Si16 ribbon with induced transverse magnetic anisotropy

    Science.gov (United States)

    Nosenko, Anton; Rudenko, Olexandr; Mika, Taras; Yevlash, Igor; Semyrga, Olexandr; Nosenko, Viktor

    2016-02-01

    The comparative analysis of magnetic properties of cut cores made of nanocrystalline Fe73Nb3Cu1B7Si16 alloy ribbon and cores made of the same ribbon with preliminary tension-induced transverse magnetic anisotropy was carried out. The possibility of improving magnetic properties of cut cores, decreasing loss, and increasing DC bias immunity of reversible magnetic permeability is presented. The influence of induced magnetic anisotropy on DC bias immunity of reversible magnetic permeability was investigated. The advantages and disadvantages of new cores (made of ribbon heated under tensile stress) over cut ones were determined.

  20. DC bias immune nanocrystalline magnetic cores made of Fe73Nb3Cu1B7Si16 ribbon with induced transverse magnetic anisotropy.

    Science.gov (United States)

    Nosenko, Anton; Rudenko, Olexandr; Mika, Taras; Yevlash, Igor; Semyrga, Olexandr; Nosenko, Viktor

    2016-12-01

    The comparative analysis of magnetic properties of cut cores made of nanocrystalline Fe73Nb3Cu1B7Si16 alloy ribbon and cores made of the same ribbon with preliminary tension-induced transverse magnetic anisotropy was carried out. The possibility of improving magnetic properties of cut cores, decreasing loss, and increasing DC bias immunity of reversible magnetic permeability is presented. The influence of induced magnetic anisotropy on DC bias immunity of reversible magnetic permeability was investigated. The advantages and disadvantages of new cores (made of ribbon heated under tensile stress) over cut ones were determined.

  1. Effects of magnetic core geometry on false detection in residual current sensor

    Energy Technology Data Exchange (ETDEWEB)

    Colin, Bruno [Laboratoire d' Electrotechnique de Grenoble INPG UJF-CNRS UMR 5529, 38400 Saint Martin d' Heres (France) and Schneider-Electric, Rue Pierre Mendes France, 38320 Eybens (France)]. E-mail: bruno.colin@leg.ensieg.inpg.fr; Chillet, Christian [Laboratoire d' Electrotechnique de Grenoble INPG UJF-CNRS UMR 5529, 38400 Saint Martin d' Heres (France); Kedous-Lebouc, Afef [Laboratoire d' Electrotechnique de Grenoble INPG UJF-CNRS UMR 5529, 38400 Saint Martin d' Heres (France); Mas, Patrick [Schneider-Electric, Rue Pierre Mendes France, 38320 Eybens (France)

    2006-09-15

    Under high-supply current, residual circuit breakers are subject to abnormal tripping, caused by false residual currents. Geometric or magnetic anomalies in the circuit breaker ring core seem to be responsible for these abnormal currents. This paper studies a few anomalies (spiral shape effect, conductor eccentricity, lamination effect) and calculates different contributions using the finite element simulations. The results show that the ring core, made of thin wound magnetic tape, is particularly sensitive to primary conductor eccentricity.

  2. Design of air-gapped magnetic-core inductors for superimposed direct and alternating currents

    Science.gov (United States)

    Ohri, A. K.; Wilson, T. G.; Owen, H. A., Jr.

    1976-01-01

    Using data on standard magnetic-material properties and standard core sizes for air-gap-type cores, an algorithm designed for a computer solution is developed which optimally determines the air-gap length and locates the quiescent point on the normal magnetization curve so as to yield an inductor design with the minimum number of turns for a given ac voltage and frequency and with a given dc bias current superimposed in the same winding. Magnetic-material data used in the design are the normal magnetization curve and a family of incremental permeability curves. A second procedure, which requires a simpler set of calculations, starts from an assigned quiescent point on the normal magnetization curve and first screens candidate core sizes for suitability, then determines the required turns and air-gap length.

  3. Protostellar disk formation and transport of angular momentum during magnetized core collapse

    CERN Document Server

    Joos, Marc; Ciardi, Andrea

    2012-01-01

    Theoretical studies of collapsing clouds found that the presence of a relatively strong magnetic field may prevent the formation of disks and their fragmentation. However most previous studies have been limited to cases where the magnetic field and the rotation axis of the cloud are aligned. We study the transport of angular momentum, and the effects on disk formation, for non-aligned initial configurations, and for a range magnetic intensities. We perform three-dimensional, adaptive mesh, numerical simulations of magnetically supercritical collapsing dense cores using the magneto-hydrodynamic code Ramses. At variance to earlier analysis, we show that the transport of angular momentum acts less efficiently in collapsing cores with non-aligned rotation and magnetic field. Analytically this result can be understood by taking into account the bending of field lines occurring during the gravitational collapse. We find that massive disks, containing at least 10% of the intial core mass, can form during the earlies...

  4. Steady state toroidal magnetic field at earth's core-mantle boundary

    Science.gov (United States)

    Levy, Eugene H.; Pearce, Steven J.

    1991-01-01

    Measurements of the dc electrical potential near the top of earth's mantle have been extrapolated into the deep mantle in order to estimate the strength of the toroidal magnetic field component at the core-mantle interface. Recent measurements have been interpreted as indicating that at the core-mantle interface, the magnetic toroidal and poloidal field components are approximately equal in magnitude. A motivation for such measurements is to obtain an estimate of the strength of the toroidal magnetic field in the core, a quantity important to our understanding of the geomagnetic field's dynamo generation. Through the use of several simple and idealized calculation, this paper discusses the theoretical relationship between the amplitude of the toroidal magnetic field at the core-mantle boundary and the actual amplitude within the core. Even with a very low inferred value of the toroidal field amplitude at the core-mantle boundary, (a few gauss), the toroidal field amplitude within the core could be consistent with a magnetohydrodynamic dynamo dominated by nonuniform rotation and having a strong toroidal magnetic field.

  5. Steady state toroidal magnetic field at earth's core-mantle boundary

    Science.gov (United States)

    Levy, Eugene H.; Pearce, Steven J.

    1991-01-01

    Measurements of the dc electrical potential near the top of earth's mantle have been extrapolated into the deep mantle in order to estimate the strength of the toroidal magnetic field component at the core-mantle interface. Recent measurements have been interpreted as indicating that at the core-mantle interface, the magnetic toroidal and poloidal field components are approximately equal in magnitude. A motivation for such measurements is to obtain an estimate of the strength of the toroidal magnetic field in the core, a quantity important to our understanding of the geomagnetic field's dynamo generation. Through the use of several simple and idealized calculation, this paper discusses the theoretical relationship between the amplitude of the toroidal magnetic field at the core-mantle boundary and the actual amplitude within the core. Even with a very low inferred value of the toroidal field amplitude at the core-mantle boundary, (a few gauss), the toroidal field amplitude within the core could be consistent with a magnetohydrodynamic dynamo dominated by nonuniform rotation and having a strong toroidal magnetic field.

  6. Supercooling Self-Assembly of Magnetic Shelled Core/Shell Supraparticles.

    Science.gov (United States)

    Zheng, Xiaotong; Yan, Bingyun; Wu, Fengluan; Zhang, Jinlong; Qu, Shuxin; Zhou, Shaobing; Weng, Jie

    2016-09-14

    Molecular self-assembly has emerged as a powerful technique for controlling the structure and properties of core/shell structured supraparticles. However, drug-loading capacities and therapeutic effects of self-assembled magnetic core/shell nanocarriers with magnetic nanoparticles in the core are limited by the intervention of the outer organic or inorganic shell, the aggregation of superparamagnetic nanoparticles, the narrowed inner cavity, etc. Here, we present a self-assembly approach based on rebalancing hydrogen bonds between components under a supercooling process to form a new core/shell nanoscale supraparticle with magnetic nanoparticles as the shell and a polysaccharide as a core. Compared with conventional iron oxide nanoparticles, this magnetic shelled core/shell nanoparticle possesses an optimized inner cavity and a loss-free outer magnetic property. Furthermore, we find that the drug-loaded magnetic shelled nanocarriers showed interesting in vitro release behaviors at different pH conditions, including "swelling-broken", "dissociating-broken", and "bursting-broken" modes. Our experiments demonstrate the novel design of the multifunctional hybrid nanostructure and provide a considerable potential for the biomedical applications.

  7. Labview based testing system for the aim of construction of energy efficient magnetic cores

    Directory of Open Access Journals (Sweden)

    Pluta Wojciech

    2017-01-01

    The paper presents an example of an application for testing the system based on Labview platform for quality checking of large magnetic cores in the order of 1000 kg. Example of testing data for one and three phase core are presented.

  8. Expanded Equations for Torque and Force on a Cylindrical Permanent Magnet Core in a Large-Gap Magnetic Suspension System

    Science.gov (United States)

    Groom, Nelson J.

    1997-01-01

    The expanded equations for torque and force on a cylindrical permanent magnet core in a large-gap magnetic suspension system are presented. The core is assumed to be uniformly magnetized, and equations are developed for two orientations of the magnetization vector. One orientation is parallel to the axis of symmetry, and the other is perpendicular to this axis. Fields and gradients produced by suspension system electromagnets are assumed to be calculated at a point in inertial space which coincides with the origin of the core axis system in its initial alignment. Fields at a given point in the core are defined by expanding the fields produced at the origin as a Taylor series. The assumption is made that the fields can be adequately defined by expansion up to second-order terms. Examination of the expanded equations for the case where the magnetization vector is perpendicular to the axis of symmetry reveals that some of the second-order gradient terms provide a method of generating torque about the axis of magnetization and therefore provide the ability to produce six-degree-of-freedom control.

  9. Sensitive magnetic biodetection using magnetic multi-core nanoparticles and RCA coils

    Science.gov (United States)

    Ahrentorp, Fredrik; Blomgren, Jakob; Jonasson, Christian; Sarwe, Anna; Sepehri, Sobhan; Eriksson, Emil; Kalaboukhov, Alexei; Jesorka, Aldo; Winkler, Dag; Schneiderman, Justin F.; Nilsson, Mats; Albert, Jan; de la Torre, Teresa Zardán Gómez; Strømme, Maria; Johansson, Christer

    2017-04-01

    We use functionalized iron oxide magnetic multi-core particles of 100 nm in size (hydrodynamic particle diameter) and AC susceptometry (ACS) methods to measure the binding reactions between the magnetic nanoparticles (MNPs) and bio-analyte products produced from DNA segments using the rolling circle amplification (RCA) method. We use sensitive induction detection techniques in order to measure the ACS response. The DNA is amplified via RCA to generate RCA coils with a specific size that is dependent on the amplification time. After about 75 min of amplification we obtain an average RCA coil diameter of about 1 μm. We determine a theoretical limit of detection (LOD) in the range of 11 attomole (corresponding to an analyte concentration of 55 fM for a sample volume of 200 μL) from the ACS dynamic response after the MNPs have bound to the RCA coils and the measured ACS readout noise. We also discuss further possible improvements of the LOD.

  10. New sintering process adjusts magnetic value of ferrite cores

    Science.gov (United States)

    Vinal, A. W.

    1964-01-01

    A two-phase sintering technique based on time and temperature permits reversible control of the coercive threshold of sintered ferrite cores. Threshold coercivity may be controlled over a substantial range of values by selective control of the cooling rate.

  11. Electrospinning fabrication and characterization of magnetic-upconversion fluorescent bifunctional core-shell nanofibers

    Science.gov (United States)

    Ma, Qianli; Wang, Jinxian; Dong, Xiangting; Yu, Wensheng; Liu, Guixia

    2014-02-01

    Novel magnetic-upconversion fluorescent bifunctional core-shell nanofibers have been successfully fabricated by coaxial electrospinning technology. NaYF4:Yb3+,Er3+ and Fe3O4 nanoparticles (Nps) were incorporated into polyvinylpyrrolidone (PVP) and electrospun into core-shell nanofibers with Fe3O4/PVP as core and NaYF4:Yb3+,Er3+/PVP as the shell. The morphology and properties of the final products were investigated in detail by X-ray diffractometry, scanning electron microscopy, transmission electron microscopy, vibrating sample magnetometer, and fluorescence spectroscopy. The core contained magnetic Nps was ca. 100 nm in diameter, and the shell scattered with NaYF4:Yb3+, Er3+ Nps was ca. 80 nm in thickness. Fluorescence emission peaks of Er3+ in the [Fe3O4/PVP]@[NaYF4:Yb3+,Er3+/PVP] core-shell nanofibers were observed. Compared with Fe3O4/NaYF4:Yb3+,Er3+/PVP composite nanofibers, the luminescent intensity of the [Fe3O4/PVP]@[NaYF4:Yb3+,Er3+/PVP] core-shell nanofibers was much higher, because the Fe3O4 Nps were only distributed in the core of the core-shell nanofibers, thus the manufactured core-shell nanofibers possessed excellent magnetic properties. The new type magnetic-upconversion fluorescent bifunctional [Fe3O4/PVP]@[NaYF4:Yb3+,Er3+/PVP] core-shell nanofibers have many potential applications in display device, nanorobots, protein determination, and target delivery of drug owing to their excellent magnetism and fluorescence.

  12. Techniques and Apparatus for Measuring Rotational Core Losses of Soft Magnetic Materials

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    In many situations such as the cores of a rotating electrical machine and the T joints of a multiphase transformer, the local flux density varies with time in terms of both magnitude and direction, i.e. the flux density vector is rotating. Therefore, the magnetic properties of the core materials under the rotating flux density vector excitation should be properly measured, modeled and applied in the design and analysis of these electromagnetic devices. This paper presents an extensive review on the development of techniques and apparatus for measuring the rotational core losses of soft magnetic materials based on the experiences of various researchers in the last hundred years.

  13. Investigation of influence of micro-structure on magnetic properties of amorphous powder core

    Institute of Scientific and Technical Information of China (English)

    GUO Feng; BA Shan; LI Deren; LU Zhichao; LU Caowei; WANG Jun

    2006-01-01

    The influence of micro-structure on magnetic properties of amorphous powder core was investigated. The results show that the amorphous powders of the powder core become crystallized with the increase of annealing temperature, and the permeability decreases from 60 to 12, the core loss increases from 0.2 to 0.3 W·cm-3 , DC-bias characteristic was improved with further increase of annealing temperature, and the magnetic properties become deteriorated due to decrease of permeability and enhancement of coercive force resulting from the crystallization of amorphous powder.

  14. Changes in Earth's core-generated magnetic field, as observed by Swarm

    DEFF Research Database (Denmark)

    Finlay, Chris; Olsen, Nils; Gillet, Nicolas

    By far the largest part of the Earth's magnetic field is generated by motions taking place within our planet's liquid metal outer core. Variations of this core-generated field thus provide us with a unique means of probing the dynamics taking place in the deepest reaches of the Earth....... In this contribution, we will present the core-generated magnetic field, and its recent time changes, as seen by ESA's Earth explorer mission Swarm. We will present a new time-dependent geomagnetic field model, called CHAOS-6, derived from satellite data collected by the Swarm constellation, as well as data from...

  15. Analysis and Design of Double-sided Air core Linear Servo Motor with Trapezoidal Permanent Magnets

    DEFF Research Database (Denmark)

    Zhang, Yuqiu; Yang, Zilong; Yu, Minghu;

    2011-01-01

    In order to reduce the thrust ripple of linear servo system, a double-sided air core permanent magnet linear servo motor with trapezoidal shape permanent magnets (TDAPMLSM) is proposed in this paper. An analytical model of the motor for predicting the magnetic field in the air-gap at no......-load is introduced. This model is derived based on the equivalent magnetization intensity method, and its accuracy is validated by using the results obtained from the finite-element method. The key dimensions that affect the air-gap magnetic field are analyzed based on the analytical model, and the design...

  16. Exfoliated BN shell-based high-frequency magnetic core-shell materials.

    Science.gov (United States)

    Zhang, Wei; Patel, Ketan; Ren, Shenqiang

    2017-09-14

    The miniaturization of electric machines demands high frequency magnetic materials with large magnetic-flux density and low energy loss to achieve a decreased dimension of high rotational speed motors. Herein, we report a solution-processed high frequency magnetic composite (containing a nanometal FeCo core and a boron nitride (BN) shell) that simultaneously exhibits high electrical resistivity and magnetic permeability. The frequency dependent complex initial permeability and the mechanical robustness of nanocomposites are intensely dependent on the content of BN insulating phase. The results shown here suggest that insulating magnetic nanocomposites have potential for application in next-generation high-frequency electric machines with large electrical resistivity and permeability.

  17. Novel magnetic core materials impact modelling and analysis for minimization of RF heating loss

    Science.gov (United States)

    Ghosh, Bablu Kumar; Mohamad, Khairul Anuar; Saad, Ismail

    2016-02-01

    The eddy current that exists in RF transformer/inductor leads to generation of noise/heat in the circuit and ultimately reduces efficiency in RF system. Eddy current is generated in the magnetic core of the inductor/transformer largely determine the power loss for power transferring process. The losses for high-frequency magnetic components are complicated due to both the eddy current variation in magnetic core and copper windings reactance variation with frequency. Core materials permeability and permittivity are also related to variation of such losses those linked to the operating frequency. This paper will discuss mainly the selection of novel magnetic core materials for minimization of eddy power loss by using the approach of empirical equation and impedance plane simulation software TEDDY V1.2. By varying the operating frequency from 100 kHz to 1GHz and magnetic flux density from 0 to 2 Tesla, the eddy power loss is evaluated in our study. The Nano crystalline core material is found to be the best core material due to its low eddy power loss at low conductivity for optimum band of frequency application.

  18. Single axis controlled hybrid magnetic bearing for left ventricular assist device: hybrid core and closed magnetic circuit.

    Science.gov (United States)

    da Silva, Isaias; Horikawa, Oswaldo; Cardoso, Jose R; Camargo, Fernando A; Andrade, Aron J P; Bock, Eduardo G P

    2011-05-01

    In previous studies, we presented main strategies for suspending the rotor of a mixed-flow type (centrifugal and axial) ventricular assist device (VAD), originally presented by the Institute Dante Pazzanese of Cardiology (IDPC), Brazil. Magnetic suspension is achieved by the use of a magnetic bearing architecture in which the active control is executed in only one degree of freedom, in the axial direction of the rotor. Remaining degrees of freedom, excepting the rotation, are restricted only by the attraction force between pairs of permanent magnets. This study is part of a joint project in development by IDPC and Escola Politecnica of São Paulo University, Brazil. This article shows advances in that project, presenting two promising solutions for magnetic bearings. One solution uses hybrid cores as electromagnetic actuators, that is, cores that combine iron and permanent magnets. The other solution uses actuators, also of hybrid type, but with the magnetic circuit closed by an iron core. After preliminary analysis, a pump prototype has been developed for each solution and has been tested. For each prototype, a brushless DC motor has been developed as the rotor driver. Each solution was evaluated by in vitro experiments and guidelines are extracted for future improvements. Tests have shown good results and demonstrated that one solution is not isolated from the other. One complements the other for the development of a single-axis-controlled, hybrid-type magnetic bearing for a mixed-flow type VAD.

  19. Structural and magnetic properties of core-shell iron-iron oxide nanoparticles

    DEFF Research Database (Denmark)

    Kuhn, Luise Theil; Bojesen, A.; Timmermann, L.

    2002-01-01

    We present studies of the structural and magnetic properties of core-shell iron-iron oxide nanoparticles. alpha-Fe nanoparticles were fabricated by sputtering and subsequently covered with a protective nanocrystalline oxide shell consisting of either maghaemite (gamma-Fe2O3) or partially oxidized...... magnetite (Fe3O4). We observed that the nanoparticles were stable against further oxidation, and Mossbauer spectroscopy at high applied magnetic fields and low temperatures revealed a stable form of partly oxidized magnetite. The nanocrystalline structure of the oxide shell results in strong canting...... of the spin structure in the oxide shell, which thereby modifies the magnetic properties of the core-shell nanoparticles....

  20. Synthesis of core-shell structured magnetic nanoparticles with a carbide shell

    Science.gov (United States)

    Hou, Shushan; Chi, Yue; Zhao, Zhankui

    2017-03-01

    Core-shell structured materials combining the functionalities of the core and shell have great application potential in many fields. In this work, by combining solvothermal, polymerization and the high temperature carbonization, we have successfully developed a facile method to generate core-shell structured nanoparticles which possess an internal magnetic nanoparticle with a carbide shell. The thickness of resorcinol formaldehyde resin as intermediate transition shell could be easily adjusted by changing the concentration of the RF precursor. The resulting nanoparticles possess well-defined structure, uniform size and high magnetization. The unique nanostructure of the magnetic core-shell structured nanoparticles could lead to many promising applications in areas ranging from drug delivery to the purifyication of sewage.

  1. Effects of magnetic fields on the cosmic-ray ionization of molecular cloud cores

    CERN Document Server

    Padovani, Marco

    2011-01-01

    Low-energy cosmic rays are the dominant source of ionization for molecular cloud cores. The ionization fraction, in turn, controls the coupling of the magnetic field to the gas and hence the dynamical evolution of the cores. The purpose of this work is to compute the attenuation of the cosmic-ray flux rate in a cloud core taking into account magnetic focusing, magnetic mirroring, and all relevant energy loss processes. We adopt a standard cloud model characterized by a mass-to-flux ratio supercritical by a factor of about 2 to describe the density and magnetic field distribution of a low-mass starless core, and we follow the propagation of cosmic rays through the core along flux tubes enclosing different amount of mass. We then extend our analysis to cores with different mass-to-flux ratios. We find that mirroring always dominates over focusing, implying a reduction of the cosmic-ray ionization rate by a factor of about 2-3 over most of a solar-mass core with respect to the value in the intercloud medium outs...

  2. MAGNETIZATION OF CLOUD CORES AND ENVELOPES AND OTHER OBSERVATIONAL CONSEQUENCES OF RECONNECTION DIFFUSION

    Energy Technology Data Exchange (ETDEWEB)

    Lazarian, A. [Astronomy Department, University of Wisconsin, Madison, WI 53706 (United States); Esquivel, A. [Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico, Apartado Postal 70-543, 04510 Mexico D.F. (Mexico); Crutcher, R. [Department of Astronomy, University of Illinois at Urbana-Champaign, 1002 W. Green Street, Urbana, IL 61801 (United States)

    2012-10-01

    Recent observational results for magnetic fields in molecular clouds reviewed by Crutcher seem to be inconsistent with the predictions of the ambipolar diffusion theory of star formation. These include the measured decrease in mass to flux ratio between envelopes and cores, the failure to detect any self-gravitating magnetically subcritical clouds, the determination of the flat probability distribution function (PDF) of the total magnetic field strengths implying that there are many clouds with very weak magnetic fields, and the observed scaling B{proportional_to}{rho}{sup 2/3} that implies gravitational contraction with weak magnetic fields. We consider the problem of magnetic field evolution in turbulent molecular clouds and discuss the process of magnetic field diffusion mediated by magnetic reconnection. For this process that we termed 'reconnection diffusion', we provide a simple physical model and explain that this process is inevitable in view of the present-day understanding of MHD turbulence. We address the issue of the expected magnetization of cores and envelopes in the process of star formation and show that reconnection diffusion provides an efficient removal of magnetic flux that depends only on the properties of MHD turbulence in the core and the envelope. We show that as the amplitude of turbulence as well as the scale of turbulent motions decrease from the envelope to the core of the cloud, the diffusion of the magnetic field is faster in the envelope. As a result, the magnetic flux trapped during the collapse in the envelope is being released faster than the flux trapped in the core, resulting in much weaker fields in envelopes than in cores, as observed. We provide simple semi-analytical model calculations which support this conclusion and qualitatively agree with the observational results. Magnetic reconnection is also consistent with the lack of subcritical self-gravitating clouds, with the observed flat PDF of field strengths, and

  3. Magnetization of cloud cores and envelopes and other observational consequences of reconnection diffusion

    CERN Document Server

    Lazarian, A; Crutcher, R

    2012-01-01

    Recent observational results for magnetic fields in molecular clouds reviewed by Crutcher (2012) seem to be inconsistent with the predictions of the ambipolar diffusion theory of star formation. These include the measured decrease in mass to flux ratio between envelopes and cores, the failure to detect any self-gravitating magnetically subcritical clouds, the determination of the flat PDF of the total magnetic field strengths implying that there are many clouds with very weak magnetic fields, and the observed scaling $B \\propto \\rho^{2/3}$ that implies gravitational contraction with weak magnetic fields. We consider the problem of magnetic field evolution in turbulent molecular clouds and discuss the process of magnetic field diffusion mediated by magnetic reconnection. For this process that we termed "reconnection diffusion" we provide a simple physical model and explain that this process is inevitable in view of the present day understanding of MHD turbulence. We address the issue of the expected magnetizat...

  4. Polymer Magnetic Composite Core Based Microcoils and Microtransformers for Very High Frequency Power Applications

    Directory of Open Access Journals (Sweden)

    Saravana Guru Mariappan

    2016-04-01

    Full Text Available We present a rapid prototyping and a cost effective fabrication process on batch fabricated wafer-level micro inductive components with polymer magnetic composite (PMC cores. The new PMC cores provide a possibility to bridge the gap between the non-magnetic and magnetic core inductive devices in terms of both the operating frequency and electrical performance. An optimized fabrication process of molding, casting, and demolding which uses teflon for the molding tool is presented. High permeability NiFeZn powder was mixed with Araldite epoxy to form high resistive PMC cores. Cylindrical PMC cores having a footprint of 0.79 mm 2 were fabricated with varying percentage of the magnetic powder on FR4 substrates. The core influence on the electrical performance of the inductive elements is discussed. Inductor chips having a solenoidal coil as well as transformer chips with primary and secondary coils wound around each other have been fabricated and evaluated. A core with 65% powder equipped with a solenoid made out of 25 µm thick insulated Au wire having 30 turns, yielded a constant inductance value of 2 µH up to the frequency of 50 MHz and a peak quality factor of 13. A 1:1 transformer with similar PMC core and solenoidal coils having 10 turns yielded a maximum efficiency of 84% and a coupling factor of 96%. In order to protect the solenoids and to increase the mechanical robustness and handling of the chips, a novel process was developed to encapsulate the components with an epoxy based magnetic composite. The effect on the electrical performance through the magnetic composite encapsulation is reported as well.

  5. Multifunctional Core@Shell Magnetic Nanoprobes for Enhancing Targeted Magnetic Resonance Imaging and Fluorescent Labeling in Vitro and in Vivo.

    Science.gov (United States)

    Zhang, Qian; Yin, Ting; Gao, Guo; Shapter, Joseph G; Lai, Weien; Huang, Peng; Qi, Wen; Song, Jie; Cui, Daxiang

    2017-05-31

    Core@shell magnetic nanoparticles (core@shell MNPs) are attracting widespread attention due to their enhancement properties for potential applications in hyperthermia treatment, magnetic resonance imaging (MRI), diagnostics, and so forth. Herein, we developed a facile thermal decomposition method for controllable synthesis of a superparamagnetic, monodispersed core@shell structure (Co@Mn = CoFe2O4@MnFe2O4) with uniform size distribution (σ core could enhance magnetic anisotropy, and the MnFe2O4 shell could improve the magnetization value. The Co@Mn MNPs were transferred into aqueous solution with an amphiphilic polymer (labeled 2% TAMRA) and functionalized with PEG2k and target molecules (folic acid, FA) to fabricate multifunctional PMATAMRA-Co@Mn-PEG2k-FA nanoprobes. The obtained PMATAMRA-Co@Mn-PEG2k-FA nanoprobes exhibit good biocompatibility, high T2 relaxation values, and long-term fluorescence stability (at least 6 months). Our results demonstrate that the synthesized PMATAMRA-Co@Mn-PEG2k-FA nanoprobes can effectively enhance the targeted MRI and fluorescent labeling in vitro and in vivo. The research outcomes will contribute to the rational design of new nanoprobes and provide a promising pathway to promote core@shell nanoprobes for further clinical contrast MRI and photodynamic therapy in the near future.

  6. Performance of High-frequency High-flux Magnetic Cores at Cryogenic Temperatures

    Science.gov (United States)

    Gerber, Scott S.; Hammoud, Ahmad; Elbuluk, Malik E.; Patterson, Richard L.

    2002-01-01

    Three magnetic powder cores and one ferrite core, which are commonly used in inductor and transformer design for switch mode power supplies, were selected for investigation at cryogenic temperatures. The powder cores are Molypermalloy Core (MPC), High Flux Core (HFC), and Kool Mu Core (KMC). The performance of four inductors utilizing these cores has been evaluated as a function of temperature from 20 C to -180 C. All cores were wound with the same wire type and gauge to obtain equal values of inductance at room temperature. Each inductor was evaluated in terms of its inductance, quality (Q) factor, resistance, and dynamic hysteresis characteristics (B-H loop) as a function of temperature and frequency. Both sinusoidal and square wave excitations were used in these investigations. Measured data obtained on the inductance showed that both the MPC and the HFC cores maintain a constant inductance value, whereas with the KMC and ferrite core hold a steady value in inductance with frequency but decrease as temperature is decreased. All cores exhibited dependency, with varying degrees, in their quality factor and resistance on test frequency and temperature. Except for the ferrite, all cores exhibited good stability in the investigated properties with temperature as well as frequency. Details of the experimental procedures and test results are presented and discussed in the paper.

  7. Multi-Sensor Core Logger (MSCL) P-wave velocity, gamma-ray density, and magnetic susceptibility whole-core logs of sediment cores collected in 2009 offshore from Palos Verdes, California

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This part of the data release includes Multi-Sensor Core Logger (MSCL) P-wave velocity, gamma-ray density, and magnetic susceptibility whole-core logs of sediment...

  8. Collapse and Fragmentation of Magnetic Molecular Cloud Cores with the Enzo AMR MHD Code. II. Prolate and Oblate Cores

    CERN Document Server

    Boss, A P

    2014-01-01

    We present the results of a large suite of three-dimensional (3D) models of the collapse of magnetic molecular cloud cores using the adaptive mesh refinement (AMR) code Enzo2.2 in the ideal magnetohydrodynamics (MHD) approximation. The cloud cores are initially either prolate or oblate, centrally condensed clouds with masses of 1.73 or 2.73 $M_\\odot$, respectively. The radial density profiles are Gaussian, with central densities 20 times higher than boundary densities. A barotropic equation of state is used to represent the transition from low density, isothermal phases, to high density, optically thick phases. The initial magnetic field strength ranges from 6.3 to 100 $\\mu$G, corresponding to clouds that are strongly to marginally supercritical, respectively, in terms of the mass to magnetic flux ratio. The magnetic field is initially uniform and aligned with the clouds' rotation axes, with initial ratios of rotational to gravitational energy ranging from $10^{-4}$ to 0.1. Two significantly different outcome...

  9. Core surface magnetic field evolution 2000–2010

    DEFF Research Database (Denmark)

    Finlay, Chris; Jackson, A.; Gillet, N.;

    2012-01-01

    traditional quadratic or maximum entropy regularization in space, and second or third time derivative regularization in time. Entropy regularization allows the construction of models with approximately constant spectral slope at the core surface, avoiding both the divergence characteristic of the crustal...

  10. Interface effect of magnetic properties in Ni nanoparticles with a hcp core and fcc shell structure.

    Science.gov (United States)

    Choo, Seongmin; Lee, Kyujoon; Jo, Younghun; Yoon, Seon-Mi; Choi, Jae-Young; Kim, Jea-Young; Park, Jea-Hoon; Lee, Kyung-Jin; Lee, Jong-Heun; Jung, Myung-Hwa

    2011-07-01

    We have fabricated hexagonal close-packed (hcp) Ni nanoparticles covered by a face-centered cubic (fcc) Ni surface layer by polyol method. The magnetic properties have been investigated as a function of temperature and applied magnetic field. The magnetic behavior reveals that the system should be divided magnetically into three distinct phases with different origins. The fcc Ni phase on the shell contributes to the superparamagnetism through a wide temperature range up to 360 K. The hcp Ni phase at the core is associated with antiferromagnetic nature below 12 K. These observations are in good agreement with the X-ray absorption spectroscopy and magnetic circular dichroism measurements. In our particular case, the unique hcp core and fcc shell structure gives rise to an additional anomaly at 20 K in the zero-field-cooled magnetization curve. Its position is barely affected by the magnetic field but its structure disappears above 30 kOe, showing a metamagnetic transition in the magnetization versus magnetic field curve. This new phase originates from the magnetic exchange at the interface between the hcp and fcc Ni sublattices.

  11. Biomonitoring of atmospheric particulate matter using magnetic properties of Salix matsudana tree ring cores.

    Science.gov (United States)

    Zhang, Chunxia; Huang, Baochun; Piper, John D A; Luo, Rensong

    2008-04-01

    Magnetic properties of atmospheric particulate matter collected by both natural and artificial dust receptors are increasingly being used as proxy parameters for environmental analyses. This study reports the first investigation of the relationship between smelting factory activity and the impact on the environment as recorded by the magnetic signature in Salix matsudana tree rings. Magnetic techniques including low-temperature experiments, successive acquisition of isothermal remanent magnetisation (IRM), hysteresis loops and measurements of saturated IRM (SIRM) indicated that magnetic particles were omnipresent in tree bark and trunk wood, and that these particles were predominantly magnetite with multidomain properties. The magnetic properties of tree trunk and branch cores sampled from different directions and heights implied that the acquisition of magnetic particles by a tree depends on both orientation and height. The differences of SIRM values of tree ring cores indicated that pollution source-facing tree trunk wood contained significantly more magnetic particles than other faces. The results indicated that magnetic particles are most likely to be intercepted and collected by tree bark and then enter into tree xylem tissues during the growing season to become finally enclosed into the tree ring by lignification. There was a significant correlation between time-dependent SIRM values of tree ring cores and the annual iron production of the smelting factory. From the dependence of magnetic properties with sampling direction and height, it is argued that magnetic particles in the xylem cannot move between tree rings. Accordingly, the SIRM of tree ring cores from the source-facing side can contribute to historic studies of atmospheric particulate matter produced by heavy metal smelting activities.

  12. Polystyrene-Core-Silica-Shell Hybrid Particles Containing Gold and Magnetic Nanoparticles.

    Science.gov (United States)

    Tian, Jia; Vana, Philipp

    2016-02-18

    Polystyrene-core-silica-shell hybrid particles were synthesized by combining the self-assembly of nanoparticles and the polymer with a silica coating strategy. The core-shell hybrid particles are composed of gold-nanoparticle-decorated polystyrene (PS-AuNP) colloids as the core and silica particles as the shell. PS-AuNP colloids were generated by the self-assembly of the PS-grafted AuNPs. The silica coating improved the thermal stability and dispersibility of the AuNPs. By removing the "free" PS of the core, hollow particles with a hydrophobic cage having a AuNP corona and an inert silica shell were obtained. Also, Fe3O4 nanoparticles were encapsulated in the core, which resulted in magnetic core-shell hybrid particles by the same strategy. These particles have potential applications in biomolecular separation and high-temperature catalysis and as nanoreactors.

  13. GaAs-Fe₃Si core-shell nanowires: nanobar magnets.

    Science.gov (United States)

    Hilse, Maria; Herfort, Jens; Jenichen, Bernd; Trampert, Achim; Hanke, Michael; Schaaf, Peter; Geelhaar, Lutz; Riechert, Henning

    2013-01-01

    Semiconductor-ferromagnet GaAs-Fe3Si core-shell nanowires were grown by molecular beam epitaxy and analyzed by scanning and transmission electron microscopy, X-ray diffraction, Mössbauer spectroscopy, and magnetic force microscopy. We obtained closed and smooth Fe3Si shells with a crystalline structure that show ferromagnetic properties with magnetizations along the nanowire axis (perpendicular to the substrate). Such nanobar magnets are promising candidates to enable the fabrication of new forward-looking devices in the field of spintronics and magnetic recording.

  14. Glucose Sensors Based on Core@Shell Magnetic Nanomaterials and Their Application in Diabetes Management: A Review.

    Science.gov (United States)

    Liu, Lin; Lv, Hongying; Teng, Zhenyuan; Wang, Chengyin; Wang, Guoxiu

    2015-01-01

    This review presents a comprehensive attempt to conclude and discuss various glucose biosensors based on core@shell magnetic nanomaterials. Owing to good biocompatibility and stability, the core@shell magnetic nanomaterials have found widespread applications in many fields and draw extensive attention. Most magnetic nanoparticles possess an intrinsic enzyme mimetic activity like natural peroxidases, which invests magnetic nanomaterials with great potential in the construction of glucose sensors. We summarize the synthesis of core@shell magnetic nanomaterials, fundamental theory of glucose sensor and the advances in glucose sensors based on core@shell magnetic nanomaterials. The aim of the review is to provide an overview of the exploitation of the core@shell magnetic nanomaterials for glucose sensors construction.

  15. Determining the size of nanoparticles in the example of magnetic iron oxide core-shell systems

    Science.gov (United States)

    Jarzębski, Maciej; Kościński, Mikołaj; Białopiotrowicz, Tomasz

    2017-08-01

    The size of nanoparticles is one of the most important factors for their possible applications. Various techniques for the nanoparticle size characterization are available. In this paper selected techniques will be considered base on the prepared core-shell magnetite nanoparticles. Magnetite is one of the most investigated and developed magnetic material. It shows interesting magnetic properties which can be used for biomedical applications, such as drug delivery, hypothermia and also as a contrast agent. To reduce the toxic effects of Fe3O4, magnetic core was covered by dextran and gelatin. Moreover, the shell was doped by fluorescent dye for confocal microscopy investigation. The main investigation focused on the methods for particles size determination of modified magnetite nanoparticles prepared with different techniques. The size distribution were obtained by nanoparticle tracking analysis, dynamic light scattering and transmission electron microscopy. Furthermore, fluorescent correlation spectroscopy (FCS) and confocal microscopy were used to compare the results for particle size determination of core-shell systems.

  16. Magnetic properties of mixed spin (1, 3/2) Ising nanoparticles with core-shell structure

    Science.gov (United States)

    Deviren, Bayram; Şener, Yunus

    2015-07-01

    The magnetic properties of mixed spin-1 and spin-3/2 Ising nanoparticles with core/shell structure are studied by using the effective-field theory with correlations. We investigate the thermal variations of the core, shell and total magnetizations and the Q-, R-, P-, S-, N- and L-types of compensation behavior in Néel classification nomenclature exists in the system. The effects of the crystal-field, core and shell interactions and interface coupling, on the phase diagrams are investigated in detail and the obtained phase diagrams are presented in three different planes. The system exhibits both second- and first-order phase transitions besides tricritical point, double critical end point, triple point and critical end point depending on the appropriate values of the interaction parameters. The system strongly affected by the surface situations and some characteristic phenomena are found depending on the ratio of the physical parameters in the surface shell and the core.

  17. Changes in Earth's core-generated magnetic field, as observed by Swarm

    DEFF Research Database (Denmark)

    Finlay, Chris; Olsen, Nils; Gillet, Nicolas

    By far the largest part of the Earth's magnetic field is generated by motions taking place within our planet's liquid metal outer core. Variations of this core-generated field thus provide us with a unique means of probing the dynamics taking place in the deepest reaches of the Earth....... In this contribution, we will present the core-generated magnetic field, and its recent time changes, as seen by ESA's Earth explorer mission Swarm. We will present a new time-dependent geomagnetic field model, called CHAOS-6, derived from satellite data collected by the Swarm constellation, as well as data from...... of the source region, the core-mantle boundary, we present maps of the detailed structure of the geodynamo, and how this is presently evolving. Both the trend (secular variation) and accelerations in the field changes since the launch of the Swarm mission will be presented. Assuming that field changes...

  18. The origin of magnetic alloy core buckling in J-PARC 3 GeV RCS

    Energy Technology Data Exchange (ETDEWEB)

    Nomura, M., E-mail: masahiro.nomura@j-parc.j [JAEA, 2-4, Shirakata-shirane, Tokai, Ibaraki 319-1195 (Japan); Yamamoto, M.; Schnase, A.; Shimada, T.; Suzuki, H.; Tamura, F. [JAEA, 2-4, Shirakata-shirane, Tokai, Ibaraki 319-1195 (Japan); Hara, K.; Hasegawa, K.; Ohmori, C.; Toda, M.; Yoshii, M. [KEK, Tsukuba, Ibaraki 305-0801 (Japan)

    2010-11-21

    We have been operating ten RF cavities loaded with magnetic alloy (MA) cores with a high field gradient of more than 20 kV/m in Japan Proton Accelerator Research Complex (J-PARC) 3 GeV Rapid Cycling Synchrotron (RCS) since September 2007. During 3 years operation, we detected three times the impedance reductions of RF cavities resulting from the buckling of MA cores. To find out the origin of the MA core buckling, we evaluated the thermal stress inside the MA cores in operation and studied the relationship between the MA core buckling and core structure. We figured out that the MA core buckling was caused by the thermal stress that was enhanced due to the impregnation with low viscosity epoxy resin. We improved the MA cores without the low viscosity epoxy resin impregnation and replaced all the cores in one RF cavity with them in March 2010. Up to now we operated the RF cavity loaded with the improved MA cores for 1500 h, it showed no impedance reduction and no buckling.

  19. Magnetic Resonance Imaging Guided Vacuum Assisted and Core Needle Biopsies.

    Science.gov (United States)

    Kılıç, Fahrettin; Eren, Abdulkadir; Tunç, Necmettin; Velidedeoğlu, Mehmet; Bakan, Selim; Aydoğan, Fatih; Çelik, Varol; Gazioğlu, Ertuğrul; Yılmaz, Mehmet Halit

    2016-01-01

    The purpose of this study to present the results of Magnetic resonance imaging (MRI) guided cutting needle biopsy procedures of suspicious breast lesions that can be solely detected on Magnetic resonance (MR) examination. The study included 48 patients with 48 lesions which were solely be observed in breast MRI, indistinguishable in ultrasonography and mammography, for MR guided vacuum-assisted cutting needle biopsy and 42 patients with 42 lesions for MR guided cutting needle biopsy for the lesions of the same nature. MR imaging was performed using a 1.5-Tesla MRI device. Acquired MR images were determined and biopsy protocol was performed using computer-aided diagnosis system on the workstation. Vacuum biopsies were performed using 10 G or 12 G automatic biopsy systems, cutting needle biopsy procedures were performed using fully automated 12 G biopsy needle. All biopsy procedures were finalized successfully without major complications. The lesions were 54 mass (60%), 28 were non-mass contrast enhancement (31%) and 8 were foci (9%) in the MR examination. Histopathological evaluation revealed 18 malignant (invasive, in-situ ductal carcinoma and lobular carcinoma), 66 benign (apocrine metaplasia, fibrosis, fibroadenomatoid lesion, sclerosing adenosis, fibrocystic disease and mild-to-severe epithelial proliferation) and 6 high-risk (atypical ductal hyperplasia, intraductal papilloma, radial scar) lesions. Magnetic resonance guided vacuum and cutting needle biopsy methods are successful methods fort he evaluation of solely MRI detected suspicious breast lesions. There are several advantages relative to each other in both methods.

  20. EXPERIMENTAL DETERMINATION OF LONGITUDINAL COMPONENT OF MAGNETIC FLUX IN FERROMAGNETIC WIRE OF SINGLE-CORE POWER CABLE ARMOUR

    Directory of Open Access Journals (Sweden)

    I.A. Kostiukov

    2014-12-01

    Full Text Available A problem of determination of effective longitudinal magnetic permeability of single core power cable armour is defined. A technique for experimental determination of longitudinal component of magnetic flux in armour spiral ferromagnetic wire is proposed.

  1. Electric Dipole Antennas With Magnetic-Coated PEC Cores: Reaching the Chu Lower Bound on Q

    DEFF Research Database (Denmark)

    Kim, Oleksiy S.

    2012-01-01

    The radiation properties of spherical electric dipole antennas with electric current excitation and material-coated perfectly electrically conducting (PEC) cores are investigated analytically using vector spherical wave functions. Closed-form expressions for electric and magnetic stored energy as...... as well as the radiation quality factor $Q$ are derived. Using these, it is shown that properly selected magnetic coating and radius of the PEC core vastly reduce the internal stored energy, and thus make the $Q$ of an electric dipole antenna approach the Chu lower bound....

  2. Observation of magnetic diffusion in the Earth's outer core from Magsat, Orsted, and CHAMP data

    DEFF Research Database (Denmark)

    Chulliat, A.; Olsen, Nils

    2010-01-01

    , Orsted, and CHAMP satellites. A detectable change of magnetic fluxes through patches delimited by curves of zero radial magnetic field at the core-mantle boundary is associated with a failure of the frozen flux assumption. For each epoch (1980 and 2005), we calculate spatially regularized models...... increase of the global misfit. However, applying the constraint leads to a detectable increase of the scalar residuals at satellite altitude in the region of St. Helena, strongly suggesting a local failure of the frozen flux assumption. The observed flux expulsion within the St. Helena patch could result...... from the formation of a pair of "core spots," as predicted by numerical simulations of the geodynamo....

  3. Synthesis and characterization of magnetic polymer microspheres with a core-shell structure

    Institute of Scientific and Technical Information of China (English)

    Ming; Lu; Shu; Bai; Kun; Yang; Yan; Sun

    2007-01-01

    Non-porous magnetic polymer microspheres with a core-shell structure were prepared by a novel micro-suspension polymerization technique.A stable iron oxide ferrofluid was used to supply the magnetic core, and the polymeric shell was made of glycidyl methacrylate (GMA monomer)and ethylene dimethacrylate (cross-linker). In the preparation, polyvinyl alcohol was used as the stabilizer, and a lauryl alcohol mixture as the dispersant. The influence of various conditions such as aqueous phase volume, GMA and initiator amounts, reaction time and stirring speed on the character of the microspheres was investigated. The magnetic microspheres were then characterized briefly. The results indicate that the microspheres with active epoxy groups had a narrow size distribution range from 1 to 10 μm with a volume-weighted mean diameter of 4.5 μm.The saturation magnetization reached 19.9 emu/g with little coercivity and remanence.

  4. The Structure and Evolution of Magnetized Cloud Cores in a Zero--Density Background

    CERN Document Server

    Curry, C L; Curry, Charles L.; Stahler, Steven W.

    2001-01-01

    Molecular-line observations of star-forming cloud cores indicate that they are not the flattened structures traditionally considered by theory. Rather, they are elongated, perhaps in the direction of their internal magnetic field. We are thus motivated to consider the structure and evolution of axisymmetric, magnetized clouds that start from a variety of initial states, both flattened (oblate) and elongated (prolate). We devise a new technique, dubbed the $q$-method, that allows us to construct magnetostatic equilibria of any specified shape. We find, in agreement with previous authors, that the field lines in oblate clouds bend inward. However, those in prolate clouds bow outward, confining the structures through magnetic tension. We next follow the quasi-static evolution of these clouds via ambipolar diffusion, under the assumption of constant core mass. An oblate cloud either relaxes to a magnetically force-free sphere or, if sufficiently massive, flattens along its polar axis as its central density runs a...

  5. Magnetic core-shell chitosan nanoparticles: rheological characterization and hyperthermia application.

    Science.gov (United States)

    Zamora-Mora, Vanessa; Fernández-Gutiérrez, Mar; San Román, Julio; Goya, Gerardo; Hernández, Rebeca; Mijangos, Carmen

    2014-02-15

    Stabilized magnetic nanoparticles are the subject of intense research for targeting applications and this work deals with the design, preparation and application of specific core-shell nanoparticles based on ionic crosslinked chitosan. The nanometric size of the materials was demonstrated by dynamic light scattering (DLS) and field emission scanning electron microscopy (FESEM) that also proved an increase of the size of chitosan nanoparticles (NPs) with the magnetite content. Steady oscillatory rheology measurements revealed a gel-like behavior of aqueous dispersions of chitosan NPs with concentrations ranging from 0.5% to 2.0% (w/v). The cytotoxicity of all the materials synthesized was analyzed in human fibroblasts cultures using the Alamar Blue and lactate dehydrogenase (LDH) assays. The measured specific power absorption under alternating magnetic fields (f = 580 kHz, H = 24 kA/m) indicated that magnetic core-shell chitosan NPs can be useful as remotely driven heaters for magnetic hyperthermia.

  6. Core Polarization and Tensor Coupling Effects on Magnetic Moments of Hypernuclei

    Institute of Scientific and Technical Information of China (English)

    YAO Jiang-Ming; L(U) Hong-Feng; Hillhouse Greg; MENG Jie

    2008-01-01

    Effects of core polarization and tensor coupling on the magnetic moments in 13Λ C,17Λ O,and 41Λ Ca Λ-hypernuclei are studied by employing the Dirac equation with scalar,vector and tensor potentials.It is found that the effect of core polarization on the magnetic moments is suppressed by Λ tensor coupling.The Λ tensor potential reduces the spin-orbit splitting of PΛ states considerably.However,almost the same magnetic moments are obtained using the hyperon wavefunction obtained via the Dirac equation either with or without the Λ tensor potential in the electromagnetic current vertex.The deviations of magnetic moments for pΛ states from the Schmidt values are found to increase with nuclear mass number.

  7. Magnetic Field Generation in Core-Sheath Jets via the Kinetic Kelvin-Helmholtz Instability

    CERN Document Server

    Nishikawa, K -I; Dutan, I; Niemiec, J; Medvedev, M; Mizuno, Y; Meli, A; Sol, H; Zhang, B; Pohl, M; Hartmann, D H

    2014-01-01

    We have investigated magnetic field generation in velocity shears via the kinetic Kelvin-Helmholtz instability (kKHI) using a relativistic plasma jet core and stationary plasma sheath. Our three-dimensional particle-in-cell simulations consider plasma jet cores with Lorentz factors of 1.5, 5, and 15 for both electron-proton and electron-positron plasmas. For electron-proton plasmas we find generation of strong large-scale DC currents and magnetic fields which extend over the entire shear-surface and reach thicknesses of a few tens of electron skin depths. For electron-positron plasmas we find generation of alternating currents and magnetic fields. Jet and sheath plasmas are accelerated across the shear surface in the strong magnetic fields generated by the kKHI. The mixing of jet and sheath plasmas generates transverse structure similar to that produced by the Weibel instability.

  8. Magnetic field generation in core-sheath jets via the kinetic Kelvin-Helmholtz instability

    Energy Technology Data Exchange (ETDEWEB)

    Nishikawa, K.-I. [Department of Physics, University of Alabama in Huntsville, ZP12, Huntsville, AL 35899 (United States); Hardee, P. E. [Department of Physics and Astronomy, The University of Alabama, Tuscaloosa, AL 35487 (United States); Duţan, I. [Institute of Space Science, Atomistilor 409, Bucharest-Magurele RO-077125 (Romania); Niemiec, J. [Institute of Nuclear Physics PAN, ul. Radzikowskiego 152, 31-342 Kraków (Poland); Medvedev, M. [Department of Physics and Astronomy, University of Kansas, KS 66045 (United States); Mizuno, Y. [Institute of Astronomy, National Tsing-Hua University, Hsinchu, Taiwan 30013 (China); Meli, A. [Department of Physics and Astronomy, University of Gent, Proeftuinstraat 86 B-9000, Gent (Belgium); Sol, H. [LUTH, Observatore de Paris-Meudon, 5 place Jules Jansen, F-92195 Meudon Cedex (France); Zhang, B. [Department of Physics, University of Nevada, Las Vegas, NV 89154 (United States); Pohl, M. [Institut fur Physik und Astronomie, Universität Potsdam, D-14476 Potsdam-Golm (Germany); Hartmann, D. H., E-mail: ken-ichi.nishikawa@nasa.gov [Department of Physics and Astronomy, Clemson University, Clemson, SC 29634 (United States)

    2014-09-20

    We have investigated magnetic field generation in velocity shears via the kinetic Kelvin-Helmholtz instability (kKHI) using a relativistic plasma jet core and stationary plasma sheath. Our three-dimensional particle-in-cell simulations consider plasma jet cores with Lorentz factors of 1.5, 5, and 15 for both electron-proton and electron-positron plasmas. For electron-proton plasmas, we find generation of strong large-scale DC currents and magnetic fields that extend over the entire shear surface and reach thicknesses of a few tens of electron skin depths. For electron-positron plasmas, we find generation of alternating currents and magnetic fields. Jet and sheath plasmas are accelerated across the shear surface in the strong magnetic fields generated by the kKHI. The mixing of jet and sheath plasmas generates a transverse structure similar to that produced by the Weibel instability.

  9. Simulations of core convection in rotating A-type stars: Magnetic dynamo action

    CERN Document Server

    Brun, A S; Toomre, J; Brun, Allan Sacha; Browning, Matthew K.; Toomre, Juri

    2005-01-01

    Core convection and dynamo activity deep within rotating A-type stars of 2 solar masses are studied with 3--D nonlinear simulations. Our modeling considers the inner 30% by radius of such stars, thus capturing within a spherical domain the convective core and a modest portion of the surrounding radiative envelope. The MHD equations are solved using the ASH code to examine turbulent flows and magnetic fields, both of which exhibit intricate time dependence. By introducing small seed magnetic fields into our progenitor hydrodynamic models rotating at one and four times the solar rate, we assess here how the vigorous convection can amplify those fields and sustain them against ohmic decay. Dynamo action is indeed realized, ultimately yielding magnetic fields that are in energy equipartion with the flow. Such magnetism reduces the differential rotation obtained in the progenitors, partly by Maxwell stresses that transport angular momentum poleward and oppose the Reynolds stresses in the latitudinal balance. In co...

  10. Micro fluxgate magnetic sensors using planar coils wrapped around a film core

    Energy Technology Data Exchange (ETDEWEB)

    Kawahito, S.; Suto, M.; Yamasawa, A.; Tadokoro, Y. [Toyohashi University of Technology, Aichi (Japan)

    1996-11-20

    This paper presents highly-sensitive fluxgate magnetic sensors based on silicon microtechnology and electrodeposited magnetic thin films. To achieve high sensitivity, we propose a coil structure that both the excitation and the pickup coils are wrapped around a thin-film core. The optimal coupling structure between excitation and pickup coils is investigated. The closely-coupled coil structure that a one turn of excitation coil and a few turns of pick-up coil are wound alternatively around the magnetic core is effective to achieve high sensitivity. In general, the magnetic performance of the core prepared by electrodeposition is degraded due to the thermal treatment process during the fabrication. The addition of indium in the plating bath of Permalloy greatly reduces the degradation of magnetic core due to the thermal treatment process. An improved basic micro fluxgate sensing element chip employing new-type coil structures and the indium-added permalloy prepared by electrodeposition is fabricated. The maximum sensitivity of the fabricated sensor is measured to be 2700V/T at the excitation frequency of 3MHz. The noise spectral density is measured to be 0.6nT/Hz at 10Hz. 24 refs., 11 figs., 1 tab.

  11. Biodegradable and magnetic core-shell composite particle prepared by emulsion solvent diffusion method

    Science.gov (United States)

    Oka, Chiemi; Ushimaru, Kazunori; Horiishi, Nanao; Tsuge, Takeharu; Kitamoto, Yoshitaka

    2016-02-01

    The present paper describes optimization of preparation conditions of a core-shell composite particle, and its heat generation by alternating magnetic fields. The composite particles are prepared with a modified emulsion solvent diffusion method, which is combined with Pickering emulsion stabilized by magnetic nanoparticles. In this method, the magnetic nanoparticles act as an emulsifier, and its amount and size are crucial to morphology of the composite particles. The magnetic nanoparticles of 8-9 nm would be strongly adsorbed at a liquid-liquid interface rather than the larger nanoparticles. At the optimized concentration of the magnetic nanoparticle’s suspension for the preparation, small and uniform composite particles are obtained since the amount of the nanoparticles is enough to prevent coalescence of droplets during the formation of the composites. The heat generation by alternating magnetic fields emerged certainly. This result suggests the composite particles have a property as a heat-generating carrier for hyperthermia treatment.

  12. Controlled stimulation-burst targeted release by smart decentered core-shell microcapsules in gravity and magnetic field.

    Science.gov (United States)

    Ge, Xue-Hui; Huang, Jin-Pei; Xu, Jian-Hong; Luo, Guang-Sheng

    2014-12-07

    By combining gravity and magnetic force, we have developed a versatile and facile microfluidic method for forming magnetic decentered core-shell microcapsules in which the directions of the oil core and the magnetic nanoparticles are either opposed or the same. When the temperature rises above the LCST of the PNIPAm, the shell shrinks rapidly and the core targets burst release towards the converse or the same direction as the magnet. By adjusting the direction of the magnet, the release direction of the active substance could be correspondingly accurately controlled.

  13. Magnetic processes in a collapsing dense core. II. Fragmentation. Is there a fragmentation crisis?

    Science.gov (United States)

    Hennebelle, P.; Teyssier, R.

    2008-01-01

    Context: A large fraction of stars are found in binary systems. It is therefore important for our understanding of the star formation process, to investigate the fragmentation of dense molecular cores. Aims: We study the influence of the magnetic field, ideally coupled to the gas, on the fragmentation in multiple systems of collapsing cores. Methods: We present high resolution numerical simulations performed with the RAMSES MHD code starting with a uniform sphere in solid body rotation and a uniform magnetic field parallel to the rotation axis. We pay particular attention to the strength of the magnetic field and interpret the results using the analysis presented in a companion paper. Results: The results depend much on the amplitude, A, of the perturbations seeded initially. For a low amplitude, A=0.1, we find that for values of the mass-to-flux over critical mass-to-flux ratio, μ, as high as μ = 20, the centrifugally supported disk which fragments in the hydrodynamical case is stabilized and remains axisymmetric. Detailed investigations reveal that this is due to the rapid growth of the toroidal magnetic field induced by the differential motions within the disk. For values of μ smaller than ≃5, corresponding to higher magnetic intensities, there is no centrifugally supported disk because of magnetic braking. When the amplitude of the perturbation is equal to A=0.5, each initial peak develops independently and the core fragments for a large range of μ. Only for values of μ close to 1 is the magnetic field able to prevent the fragmentation. Conclusions: Since a large fraction of stars are binaries, the results of low magnetic intensities preventing the fragmentation in the case of weak perturbations is problematic. We discuss three possible mechanisms which could lead to the formation of binary systems, namely the presence of high amplitude fluctuations in the core initially, ambipolar diffusion and fragmentation during the second collapse.

  14. Magnetic properties of a ferrimagnetic core/shell nanocube Ising model: A Monte Carlo simulation study

    Energy Technology Data Exchange (ETDEWEB)

    Zaim, A. [LPMMS, Faculte des Sciences, B.P. 11201, Zitoune, Meknes (Morocco); LPSMS, FST Errachidia, B.P. 509, Boutalamine, Errachidia (Morocco); Kerouad, M. [LPMMS, Faculte des Sciences, B.P. 11201, Zitoune, Meknes (Morocco)], E-mail: kerouad@fs-umi.ac.ma; EL Amraoui, Y. [LPSMS, FST Errachidia, B.P. 509, Boutalamine, Errachidia (Morocco)

    2009-04-15

    Monte Carlo simulation has been used to study the magnetic properties and hysteresis loops of a single nanocube, consisting of a ferromagnetic core of spin-1/2 surrounded by a ferromagnetic shell of spin-1 with antiferromagnetic interface coupling. We find a number of characteristic phenomena. In particular, the effects of the shell coupling and the interface coupling on both the compensation temperature and the magnetization profiles are investigated. The effects of the interface coupling on the hysteresis loops are also examined.

  15. Analysis and Design of Double-sided Air core Linear Servo Motor with Trapezoidal Permanent Magnets

    DEFF Research Database (Denmark)

    Zhang, Yuqiu; Yang, Zilong; Yu, Minghu

    2011-01-01

    In order to reduce the thrust ripple of linear servo system, a double-sided air core permanent magnet linear servo motor with trapezoidal shape permanent magnets (TDAPMLSM) is proposed in this paper. An analytical model of the motor for predicting the magnetic field in the air-gap at no-load is i......In order to reduce the thrust ripple of linear servo system, a double-sided air core permanent magnet linear servo motor with trapezoidal shape permanent magnets (TDAPMLSM) is proposed in this paper. An analytical model of the motor for predicting the magnetic field in the air-gap at no......-load is introduced. This model is derived based on the equivalent magnetization intensity method, and its accuracy is validated by using the results obtained from the finite-element method. The key dimensions that affect the air-gap magnetic field are analyzed based on the analytical model, and the design...... is optimized by using genetic algorithm. A thrust ripple reduction of 70.6% is achieved by optimization. The proposed analytical model may be used for a quick and reliable design and design optimization of the TDAPMLSM....

  16. Synthesis of core-shell gold coated magnetic nanoparticles and their interaction with thiolated DNA.

    Science.gov (United States)

    Robinson, Ian; Tung, Le D; Maenosono, Shinya; Wälti, Christoph; Thanh, Nguyen T K

    2010-12-01

    Core-shell magnetic nanoparticles have received significant attention recently and are actively investigated owing to their large potential for a variety of applications. Here, the synthesis and characterization of bimetallic nanoparticles containing a magnetic core and a gold shell are discussed. The gold shell facilitates, for example, the conjugation of thiolated biological molecules to the surface of the nanoparticles. The composite nanoparticles were produced by the reduction of a gold salt on the surface of pre-formed cobalt or magnetite nanoparticles. The synthesized nanoparticles were characterized using ultraviolet-visible absorption spectroscopy, transmission electron microscopy, energy dispersion X-ray spectroscopy, X-ray diffraction and super-conducting quantum interference device magnetometry. The spectrographic data revealed the simultaneous presence of cobalt and gold in 5.6±0.8 nm alloy nanoparticles, and demonstrated the presence of distinct magnetite and gold phases in 9.2±1.3 nm core-shell magnetic nanoparticles. The cobalt-gold nanoparticles were of similar size to the cobalt seed, while the magnetite-gold nanoparticles were significantly larger than the magnetic seeds, indicating that different processes are responsible for the addition of the gold shell. The effect on the magnetic properties by adding a layer of gold to the cobalt and magnetite nanoparticles was studied. The functionalization of the magnetic nanoparticles is demonstrated through the conjugation of thiolated DNA to the gold shell.

  17. Power-law Magnetic Field Decay and Constant Core Temperatures of Magnetars, Normal and Millisecond Pulsars

    CERN Document Server

    Xie, Yi

    2011-01-01

    The observed correlations, between the characteristic ages and dipole surface magnetic field strengths of all pulsars, can be well explained by magnetic field decay with core temperatures of $~2\\times10^{8}$ K, $\\sim2\\times10^{7}$ K, and $\\sim10^{5}$ K, for magnetars, normal radio pulsars, and millisecond pulsars, respectively; assuming that their characteristic ages are about two orders of magnitude larger than their true ages, the required core temperatures may be reduced by about a factor of 10. The magnetic decay follows a power-law and is dominated by the solenoidal component of the ambipolar diffusion mode. In this model, all NSs are assumed to have the same initial magnetic field strength, but different core temperature which do not change as the magnetic field decays. This suggests that the key distinguishing property between magnetars and normal pulsars is that magnetars were born much hotter than normal pulsars, and thus have much longer magnetic field decay time scales, resulting in higher surface ...

  18. Synthesis and magnetic properties of cobalt-iron/cobalt-ferrite soft/hard magnetic core/shell nanowires.

    Science.gov (United States)

    Londoño-Calderón, César Leandro; Moscoso-Londoño, Oscar; Muraca, Diego; Arzuza, Luis; Carvalho, Peterson; Pirota, Kleber Roberto; Knobel, Marcelo; Pampillo, Laura Gabriela; Martínez-García, Ricardo

    2017-06-16

    A straightforward method for the synthesis of CoFe2.7/CoFe2O4 core/shell nanowires is described. The proposed method starts with a conventional pulsed electrodeposition procedure on alumina nanoporous template. The obtained CoFe2.7 nanowires are released from the template and allowed to oxidize at room conditions over several weeks. The effects of partial oxidation on the structural and magnetic properties were studied by x-ray spectrometry, magnetometry, and scanning and transmission electron microscopy. The results indicate that the final nanowires are composed of 5 nm iron-cobalt alloy nanoparticles. Releasing the nanowires at room conditions promoted surface oxidation of the nanoparticles and created a CoFe2O4 shell spinel-like structure. The shell avoids internal oxidation and promotes the formation of bi-magnetic soft/hard magnetic core/shell nanowires. The magnetic properties of both the initial single-phase CoFe2.7 nanowires and the final core/shell nanowires, reveal that the changes in the properties from the array are due to the oxidation more than effects associated with released processes (disorder and agglomeration).

  19. Shell thickness and dynamic magnetic field effects on the critical phenomena of magnetic core-shell nanoparticles with spherical geometry

    Science.gov (United States)

    Yüksel, Yusuf

    2017-03-01

    By using Monte Carlo simulations for classical Heisenberg spins, we study the critical phenomena and ferrimagnetic properties of spherical nanoparticles with core-shell geometry. The particle core is composed of ferromagnetic spins, and it is coated by a ferromagnetic shell. Total size of the particle is fixed but the thickness of the shell is varied in such a way that the shell layer is grown at the expense of the core. Effects of the shell thickness, as well as dynamic magnetic field parameters such as oscillation period and field amplitude on the magnetization profiles, dynamic hysteresis loops and phase diagrams have been investigated for the present system. It has been found that as the shell thickness varies then the easy axis magnetization of the overall system may exhibit Q-, P-, L- and N- type behaviors based on the Neél terminology. We also found that three distinct anomalies originate in the thermal variation of specific heat with increasing field period. Dynamic hysteresis loops corresponding to off-axial magnetization components exhibit unconventional behavior such as double rings with symmetric shapes around the vertical axis over the h (t) = 0 line which may originate due to the stochastic resonance behavior of these components.

  20. A single-molecule magnet featuring a parallelogram [Dy4(OCH2-)4] core and two magnetic relaxation processes.

    Science.gov (United States)

    Liu, Cai-Ming; Zhang, De-Qing; Zhu, Dao-Ben

    2013-10-01

    An alkoxido-bridged tetranuclear Dy(iii) complex, [Dy4(H3L)2(OAc)6]·2EtOH {, H6L = 1,3-bis[tris(hydroxymethyl)methylamino]propane}, has been solvothermally synthesized and characterized. An X-ray crystallographic study revealed that complex possesses a novel "parallelogram" [Dy4(OCH2-)4] core, and a new binding mode η(3):η(3):η(1):η(1):η(1):η(2):μ(4) of the Bis-tris propane ligand was observed. Magnetic investigations indicated that it is a single-molecule magnet (SMM), showing two distinct magnetic relaxation processes with the energy barriers of 44 K and 107 K, respectively. Such a two-step magnetic relaxation process could be well described by the sum of two modified Debye functions.

  1. Control of Electron Beam Using Strong Magnetic Field for Efficient Core Heating in Fast Ignition

    CERN Document Server

    Johzaki, T; Sentoku, Y; Sunahara, A; Nagatomo, H; Sakagami, H; Mima, K; Fujioka, S; Shiraga, H

    2014-01-01

    For enhancing the core heating efficiency in electron-driven fast ignition, we proposed the fast electron beam guiding using externally applied longitudinal magnetic fields. Based on the PIC simulations for the FIREX-class experiments, we demonstrated the sufficient beam guiding performance in the collisional dense plasma by kT-class external magnetic fields for the case with moderate mirror ratio (~<10 ). Boring of the mirror field was found through the formation of magnetic pipe structure due to the resistive effects, which indicates a possibility of beam guiding in high mirror field for higher laser intensity and/or longer pulse duration.

  2. Decreasing the radiation quality factor of magnetic dipole antennas by a magnetic-coated metal core

    DEFF Research Database (Denmark)

    Kim, Oleksiy S.; Breinbjerg, Olav

    2010-01-01

    To achieve the Chu lower bound for the radiation Q, an electrically small magnetic dipole antenna should not store any magnetic energy internally to the minimum sphere enclosing the antenna. As shown in our previous works, the internal stored magnetic energy can be reduced, although not entirely...

  3. Magnetically Induced "Dry" Water Like Structure of Charged Fluid at the Core of a Magnetar

    CERN Document Server

    Ghosh, S; Ghosh, Sutapa; Chakrabarty, Somenath

    2001-01-01

    It is shown that charged fluid, e.g., electron gas or proton matter at the core of a magnetar exhibit super-fluid (frictionless) like property if the magnetic field strength is high enough to populate only the zeroth Landau levels.

  4. Lower Bound for the Radiation $Q$ of Electrically Small Magnetic Dipole Antennas With Solid Magnetodielectric Core

    DEFF Research Database (Denmark)

    Kim, Oleksiy S.; Breinbjerg, Olav

    2011-01-01

    A new lower bound for the radiation $Q$ of electrically small spherical magnetic dipole antennas with solid magnetodielectric core is derived in closed form using the exact theory. The new bound approaches the Chu lower bound from above as the antenna electrical size decreases. For $ka, the new...

  5. Magnetic proximity effect features in antiferromagnetic/ferrimagnetic core-shell nanoparticles

    OpenAIRE

    Golosovsky, I. V.; Suriñach, Santiago

    2009-01-01

    A study of “inverted” core-shell, MnO/γ-Mn2O3, nanoparticles is presented. Crystal and magnetic structures and characteristic sizes have been determined by neutron diffraction for the antiferromagnetic core (MnO) and the ferrimagnetic shell (γ-Mn2O3). Remarkably, while the MnO core is found to have a TN not far from its bulk value, the magnetic order of the γ-Mn2O3 shell is stable far above TC, exhibiting two characteristic temperatures, at T~ 40  K [TC(γ-Mn2O3)] and at T~120  K [~ TN(MnO)]. ...

  6. Spin polarization and magnetic dichroism in core-level photoemission from ferromagnets

    Energy Technology Data Exchange (ETDEWEB)

    Menchero, Jose Gabriel [Univ. of California, Berkeley, CA (United States). Dept. of Physics

    1997-05-01

    In this thesis we present a theoretical investigation of angle- and spin-resolved core-level photoemission from ferromagnetic Fe and Ni. We also consider magneto-dichroic effects due to reversal of the photon helicity or reversal of the sample magnetization direction. In chapter 1, we provide a brief outline of the history of photoemission, and show how it has played an important role in the development of modern physics. We then review the basic elements of the theory of core-level photoemission, and discuss the validity of the some of the commonly-used approximations. In chapter 2, we present a one-electron theory to calculate spin- and angle-resolved photoemission spectra for an arbitrary photon polarization. The Hamiltonian includes both spin-orbit and exchange interactions. As test cases for the theory, we calculate the spin polarization and magnetic dichroism for the Fe 2p core level, and find that agreement with experiment is very good.

  7. Preparation of novel magnetic polyurethane foam nanocomposites by using core-shell nanoparticles

    Directory of Open Access Journals (Sweden)

    Mir Mohammad Alavi Nikje

    Full Text Available Abstract Iron oxide magnetic nanoparticles (NP's converted to the core- shell structres by reacting with by n-(2-aminoethyl-3-aminopropyl trimethoxysilane (AEAP incorporated in polyurethane flexible (PUF foam formulations. Fourier transform spectra, thermal gravimetric analysis, scanning electron images, thermo-mechanical analysis and magnetic properties of the prepared nanocomposites were studied. Obtained data shown that by the increasing of the amine modified magnetic iron oxide NP's up to 3% in the polymer matrix, thermal and magnetic properties improved in comparison with pristine foams. In addition, due to the presence of functional groups on the magnetic NP's surface, hard phases formation decrease in the bulk polymer and cause decreasing of glass transition temperature.

  8. Wide range tuning of resonant frequency for a vortex core in a regular triangle magnet.

    Science.gov (United States)

    Yakata, Satoshi; Tanaka, Terumitsu; Kiseki, Kohei; Matsuyama, Kimihide; Kimura, Takashi

    2013-12-20

    A magnetic vortex structure stabilized in a micron or nano-sized ferromagnetic disk has a strong potential as a unit cell for spin-based nano-electronic devices because of negligible magnetostatic interaction and superior thermal stability. Moreover, various intriguing fundamental physics such as bloch point reversal and symmetry breaking can be induced in the dynamical behaviors in the magnetic vortex. The static and dynamic properties of the magnetic vortex can be tuned by the disk dimension and/or the separation distance between the disks. However, to realize these modifications, the preparations of other devices with different sample geometries are required. Here, we experimentally demonstrate that, in a regular-triangle Permalloy dot, the dynamic properties of a magnetic vortex are greatly modified by the application of the in-plane magnetic field. The obtained wide range tunability based on the asymmetric position dependence of the core potential provides attractive performances in the microwave spintronic devices.

  9. Young starless cores embedded in the magnetically dominated Pipe Nebula. II. Extended dataset

    CERN Document Server

    Frau, P; Beltran, M T; Padovani, M; Busquet, G; Morata, O; Masque, J M; Alves, F O; Sanchez-Monge, A; Franco, G A P; Estalella, R

    2012-01-01

    The Pipe nebula is a massive, nearby, filamentary dark molecular cloud with a low star-formation efficiency threaded by a uniform magnetic field perpendicular to its main axis. It harbors more than a hundred, mostly quiescent, very chemically young starless cores. The cloud is, therefore, a good laboratory to study the earliest stages of the star-formation process. We aim to investigate the primordial conditions and the relation among physical, chemical, and magnetic properties in the evolution of low-mass starless cores. We used the IRAM 30-m telescope to map the 1.2 mm dust continuum emission of five new starless cores, which are in good agreement with previous visual extinction maps. For the sample of nine cores, which includes the four cores studied in a previous work, we derived a Av to NH2 factor of (1.27$\\pm$0.12)$\\times10^{-21}$ mag cm$^{2}$ and a background visual extinction of ~6.7 mag possibly arising from the cloud material. We derived an average core diameter of ~0.08 pc, density of ~10$^5$ cm$^{...

  10. Hybrid Magnetic Core-Shell Nanophotocatalysts for Environmental Applications

    Energy Technology Data Exchange (ETDEWEB)

    Gaulden, Patrick [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Murph, Simona Hunyadi [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Univ. of Georgia, Athens, GA (United States). Dept. of Physics and Astronomy

    2016-07-29

    This research study describes a facile sol-gel method to creating hybrid iron (III) oxide/silica/titania nanomaterials decorated with gold nanoparticles for use in environmental applications. The multi-functional composition of the nanomaterials allows for photocatalyzed reactions to occur in both the visible and the UV range. The morphologies, elemental composition, and surface charge of the nanoparticles were determined by Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDS), and Phase Analysis Light Scattering (PALS), respectively. The photocatalytic activity of the synthesized hybrid nanoparticles for breaking down a model analyte, methyl orange (MO), was then evaluated using UV-Vis Spectroscopy. The efficiency of the photocatalyst under UV light irradiation was measured and compared to other well-studied nanophotocatalysts, namely titanium oxide and iron oxide nanoparticles. The concentration dependence of both the photocatalyst and the analyte was also investigated. By utilizing the known UV-active properties of TiO2, the magnetic properties of Fe2O3, the optical properties of gold in the visible range of the spectrum, and the high stability of silica, a novel, highly efficient photocatalyst that is active on a broad range of the spectrum (UV-Vis) can be created to destroy organic pollutants in wastewater streams.

  11. Scientific Drilling of Impact Craters - Well Logging and Core Analyses Using Magnetic Methods (Invited)

    Science.gov (United States)

    Fucugauchi, J. U.; Perez-Cruz, L. L.; Velasco-Villarreal, M.

    2013-12-01

    Drilling projects of impact structures provide data on the structure and stratigraphy of target, impact and post-impact lithologies, providing insight on the impact dynamics and cratering. Studies have successfully included magnetic well logging and analyses in core and cuttings, directed to characterize the subsurface stratigraphy and structure at depth. There are 170-180 impact craters documented in the terrestrial record, which is a small proportion compared to expectations derived from what is observed on the Moon, Mars and other bodies of the solar system. Knowledge of the internal 3-D deep structure of craters, critical for understanding impacts and crater formation, can best be studied by geophysics and drilling. On Earth, few craters have yet been investigated by drilling. Craters have been drilled as part of industry surveys and/or academic projects, including notably Chicxulub, Sudbury, Ries, Vredefort, Manson and many other craters. As part of the Continental ICDP program, drilling projects have been conducted on the Chicxulub, Bosumtwi, Chesapeake, Ries and El gygytgyn craters. Inclusion of continuous core recovery expanded the range of paleomagnetic and rock magnetic applications, with direct core laboratory measurements, which are part of the tools available in the ocean and continental drilling programs. Drilling studies are here briefly reviewed, with emphasis on the Chicxulub crater formed by an asteroid impact 66 Ma ago at the Cretaceous/Paleogene boundary. Chicxulub crater has no surface expression, covered by a kilometer of Cenozoic sediments, thus making drilling an essential tool. As part of our studies we have drilled eleven wells with continuous core recovery. Magnetic susceptibility logging, magnetostratigraphic, rock magnetic and fabric studies have been carried out and results used for lateral correlation, dating, formation evaluation, azimuthal core orientation and physical property contrasts. Contributions of magnetic studies on impact

  12. Hydrazide functionalized core-shell magnetic nanocomposites for highly specific enrichment of N-glycopeptides.

    Science.gov (United States)

    Liu, Liting; Yu, Meng; Zhang, Ying; Wang, Changchun; Lu, Haojie

    2014-05-28

    In view of the biological significance of glycosylation for human health, profiling of glycoproteome from complex biological samples is highly inclined toward the discovery of disease biomarkers and clinical diagnosis. Nevertheless, because of the existence of glycopeptides at relatively low abundances compared with nonglycosylated peptides and glycan microheterogeneity, glycopeptides need to be highly selectively enriched from complex biological samples for mass spectrometry analysis. Herein, a new type of hydrazide functionalized core-shell magnetic nanocomposite has been synthesized for highly specific enrichment of N-glycopeptides. The nanocomposites with both the magnetic core and the polymer shell hanging high density of hydrazide groups were prepared by first functionalization of the magnetic core with polymethacrylic acid by reflux precipitation polymerization to obtain the Fe3O4@poly(methacrylic acid) (Fe3O4@PMAA) and then modification of the surface of Fe3O4@PMAA with adipic acid dihydrazide (ADH) to obtain Fe3O4@poly(methacrylic hydrazide) (Fe3O4@PMAH). The abundant hydrazide groups toward highly specific enrichment of glycopeptides and the magnetic core make it suitable for large-scale, high-throughput, and automated sample processing. In addition, the hydrophilic polymer surface can provide low nonspecific adsorption of other peptides. Compared to commercially available hydrazide resin, Fe3O4@PMAH improved more than 5 times the signal-to-noise ratio of standard glycopeptides. Finally, this nanocomposite was applied in the profiling of N-glycoproteome from the colorectal cancer patient serum. In total, 175 unique glycopeptides and 181 glycosylation sites corresponding to 63 unique glycoproteins were identified in three repeated experiments, with the specificities of the enriched glycopeptides and corresponding glycoproteins of 69.6% and 80.9%, respectively. Because of all these attractive features, we believe that this novel hydrazide functionalized

  13. On the maximum magnetic field amplification by the magnetorotational instability in core-collapse supernovae

    CERN Document Server

    Rembiasz, Tomasz; Obergaulinger, Martin; Cerdá-Durán, Pablo; Aloy, Miguel-Ángel; Müller, Ewald

    2016-01-01

    Whether the magnetorotational instability (MRI) can amplify initially weak magnetic fields to dynamically relevant strengths in core collapse supernovae is still a matter of active scientific debate. Recent numerical studies have shown that, in accordance with the parasitic model, given the core collapse supernova conditions, the MRI is terminated by parasitic instabilities of the Kelvin-Helmholtz type that disrupt MRI channel flows and quench further magnetic field growth. However, it remains to be properly assessed by what factor the initial magnetic field can be amplified and how it depends on the initial field strength and the amplitude of the perturbations. Different termination criteria which lead to different estimates of the amplification factor were proposed within the parasitic model. To determine the amplification factor and test which criterion is a better predictor of the MRI termination, we perform three-dimensional shearing-disc and shearing-box simulations of a region close to the surface of a...

  14. Investigating the Effects of I-Shaped Cores in an Outer-Rotor Transverse Flux Permanent Magnet Generator

    DEFF Research Database (Denmark)

    Hosseini, Seyedmohsen; Moghani, Javad Shokrollahi; Jensen, Bogi Bech

    2011-01-01

    This paper deals with the effects of I-shaped cores in an outer-rotor transverse flux permanent magnet generator. Performance characteristics of a typical outer-rotor transverse flux permanent magnet generator are obtained in two cases; with and without I-shaped cores. The results show...... the advantages and disadvantage of using I-shaped cores and emphasizes the necessity of performing a tradeoff study between using and not using I-shaped cores in practical transverse flux permanent magnet generators....

  15. In vitro hyperthermia with improved colloidal stability and enhanced SAR of magnetic core/shell nanostructures.

    Science.gov (United States)

    Patil, R M; Thorat, N D; Shete, P B; Otari, S V; Tiwale, B M; Pawar, S H

    2016-02-01

    Magnetic core/shell nanostructures of Fe3O4 nanoparticles coated with oleic acid and betaine-HCl were studied for their possible use in magnetic fluid hyperthermia (MFH). Their colloidal stability and heat induction ability were studied in different media viz. phosphate buffer solution (PBS), saline solution and glucose solution with different physiological conditions and in human serum. The results showed enhanced colloidal stability in these media owing to their high zeta potential values. Heat induction studies showed that specific absorption rates (SAR) of core/shells were 82-94W/g at different pH of PBS and concentrations of NaCl and glucose. Interestingly, core/shells showed 78.45±3.90W/g SAR in human serum. The cytotoxicity of core/shells done on L929 and HeLa cell lines using 3-(4,5-dimethylthiazol-2-yl)2,5-diphenyl tetrazolium bromide and trypan blue dye exclusion assays showed >89% and >80% cell viability for 24 and 48h respectively. Core/shell structures were also found to be very efficient for in vitro MFH on cancer cell line. About 95% cell death was occurred in 90min after hyperthermia treatment. The mechanism of cell death was found to be elevated ROS generation in cells after exposure to core/shells in external magnetic field. This study showed that these core/shells have a great potential to be used in in vivo MFH. Copyright © 2015 Elsevier B.V. All rights reserved.

  16. Electrical Core Transformer for Grid Improvement Incorporating Wire Magnetic Components

    Energy Technology Data Exchange (ETDEWEB)

    Harrie R. Buswell, PhD; Dennis Jacobs, PhD; Steve Meng

    2012-03-26

    The research reported herein adds to the understanding of oil-immersed distribution transformers by exploring and demonstrating potential improvements in efficiency and cost utilizing the unique Buswell approach wherein the unit is redesigned, replacing magnetic sheet with wire allowing for improvements in configuration and increased simplicity in the build process. Exploration of new designs is a critical component in our drive to assure reduction of energy waste, adequate delivery to the citizenry, and the robustness of U.S. manufacturing. By moving that conversation forward, this exploration adds greatly to our base of knowledge and clearly outlines an important avenue for further exploration. This final report shows several advantages of this new transformer type (outlined in a report signed by all of our collaborating partners and included in this document). Although materials development is required to achieve commercial potential, the clear benefits of the technology if that development were a given is established. Exploration of new transformer types and further work on the Buswell design approach is in the best interest of the public, industry, and the United States. Public benefits accrue from design alternatives that reduce the overall use of energy, but it must be acknowledged that new DOE energy efficiency standards have provided some assurance in that regard. Nonetheless the burden of achieving these new standards has been largely shifted to the manufacturers of oil-immersed distribution transformers with cost increasing up to 20% of some units versus 2006 when this investigation was started. Further, rising costs have forced the industry to look closely are far more expensive technologies which may threaten U.S. competitiveness in the distribution transformer market. This concern is coupled with the realization that many units in the nation's grid are beyond their optimal life which suggests that the nation may be headed for an infrastructure

  17. YOUNG STARLESS CORES EMBEDDED IN THE MAGNETICALLY DOMINATED PIPE NEBULA. II. EXTENDED DATA SET

    Energy Technology Data Exchange (ETDEWEB)

    Frau, P.; Girart, J. M.; Padovani, M. [Institut de Ciencies de l' Espai (CSIC-IEEC), Campus UAB, Facultat de Ciencies, Torre C-5p, E-08193 Bellaterra, Catalunya (Spain); Beltran, M. T.; Sanchez-Monge, A. [INAF-Osservatorio Astrofisico di Arcetri, Largo Enrico Fermi 5, I-50125 Firenze (Italy); Busquet, G. [INAF-Istituto di Astrofisica e Planetologia Spaziali, via Fosso del Cavaliere 100, I-00133 Roma (Italy); Morata, O. [Institute of Astronomy and Astrophysics, Academia Sinica, P.O. Box 23-141, Taipei 10617, Taiwan (China); Masque, J. M.; Estalella, R. [Departament d' Astronomia i Meteorologia and Institut de Ciencies del Cosmos (IEEC-UB), Universitat de Barcelona, Marti i Franques 1, E-08028 Barcelona, Catalunya (Spain); Alves, F. O. [Argelander-Institut fuer Astronomie der Universitaet Bonn, Auf dem Huegel 71, D-53121 Bonn (Germany); Franco, G. A. P. [Departamento de Fisica-ICEx-UFMG, Caixa Postal 702, 30.123-970, Belo Horizonte (Brazil)

    2012-11-01

    The Pipe nebula is a massive, nearby, filamentary dark molecular cloud with a low star formation efficiency threaded by a uniform magnetic field perpendicular to its main axis. It harbors more than a hundred, mostly quiescent, very chemically young starless cores. The cloud is therefore a good laboratory to study the earliest stages of the star formation process. We aim to investigate the primordial conditions and the relation among physical, chemical, and magnetic properties in the evolution of low-mass starless cores. We used the IRAM 30 m telescope to map the 1.2 mm dust continuum emission of five new starless cores, which are in good agreement with previous visual extinction maps. For the sample of nine cores, which includes the four cores studied in a previous work, we derived an A {sub V} to N{sub H{sub 2}} factor of (1.27 {+-} 0.12) Multiplication-Sign 10{sup -21} mag cm{sup 2} and a background visual extinction of {approx}6.7 mag possibly arising from the cloud material. We derived an average core diameter of {approx}0.08 pc, density of {approx}10{sup 5} cm{sup -3}, and mass of {approx}1.7 M {sub Sun }. Several trends seem to exist related to increasing core density: (1) the diameter seems to shrink, (2) the mass seems to increase, and (3) the chemistry tends to be richer. No correlation is found between the direction of the surrounding diffuse medium magnetic field and the projected orientation of the cores, suggesting that large-scale magnetic fields seem to play a secondary role in shaping the cores. We also used the IRAM 30 m telescope to extend the previous molecular survey at 1 and 3 mm of early- and late-time molecules toward the same five new Pipe nebula starless cores, and analyzed the normalized intensities of the detected molecular transitions. We confirmed the chemical differentiation toward the sample and increased the number of molecular transitions of the 'diffuse' (e.g., the 'ubiquitous' CO, C{sub 2}H, and CS), &apos

  18. Selection of Soft Magnetic Core Materials Used on an LVDT Prototype

    Directory of Open Access Journals (Sweden)

    R. Yañez-Valdez

    2012-04-01

    Full Text Available Traditionally, the use of ferrite as a core of the linear variable differential transformer (LVDT is suggested in its designs. Nevertheless, problems related to its brittleness and low tensile strength may be considered as important drawbacks for its use as a core material, especially when its geometry is likely to be modified. This work explores other alternatives related to soft magnetic materials, less used in applications of an LVDT core. By means of a decision matrix, from an assortment of different materials, three alternatives were selected. This proposal provides the identification of those materials with higher qualification values to be used as core material. In order to validate the performance of the selected materials, a prototype of LVDT was designed and fabricated. The design was carried out taking into consideration typical performance specifications. Finally, a comparison of the measurements of sensitivity and linearity of the proposed and traditional materials was made.

  19. Hierarchical magnetic core-shell nanostructures for microwave absorption:Synthesis,microstructure and property studies

    Institute of Scientific and Technical Information of China (English)

    LIU JiWei; XU JunJie; LIU ZhengWang; LIU XiaLin; CHE RenChao

    2014-01-01

    Core-shell nanostructures have attracted considerable attention in the past decades because of their fundamental scientific significance and many technological applications.Recently,it has been reported that the core-shell nanostructures with advanced compositions and complicated morphologies show great potential as high-performance microwave absorbers due to their unique properties,such as large surface areas,multi-functionalities and synergistic effects between the interior core and outer shell.This review article focuses on the recent progress in synthesis and characterization of hierarchical magnetic core-shell nanostructures for microwave absorption applications based on our own work.In addition,several future trends in this field for next-generation microwave absorbers are discussed.

  20. Core-shell composite particles composed of biodegradable polymer particles and magnetic iron oxide nanoparticles for targeted drug delivery

    Science.gov (United States)

    Oka, Chiemi; Ushimaru, Kazunori; Horiishi, Nanao; Tsuge, Takeharu; Kitamoto, Yoshitaka

    2015-05-01

    Core-shell composite particles with biodegradability and superparamagnetic behavior were prepared using a Pickering emulsion for targeted drug delivery based on magnetic guidance. The composite particles were composed of a core of biodegradable polymer and a shell of assembled magnetic iron oxide nanoparticles. It was found that the dispersibility of the nanoparticles is crucial for controlling the core-shell structure. The addition of a small amount of dispersant into the nanoparticle's suspension could improve the dispersibility and led to the formation of composite particles with a thin magnetic shell covering a polymeric core. The composite particles were also fabricated with a model drug loaded into the core, which was released via hydrolysis of the core under strong alkaline conditions. Because the core can also be biodegraded by lipase, this result suggests that the slow release of the drug from the composite particles should occur inside the body.

  1. Distortion of Magnetic Fields in a Starless Core: Near-infrared Polarimetry of FeSt 1-457

    Science.gov (United States)

    Kandori, Ryo; Tamura, Motohide; Kusakabe, Nobuhiko; Nakajima, Yasushi; Kwon, Jungmi; Nagayama, Takahiro; Nagata, Tetsuya; Tomisaka, Kohji; Tatematsu, Ken'ichi

    2017-08-01

    Magnetic fields are believed to play an important role in controlling the stability and contraction of the dense condensations of gas and dust that lead to the formation of stars and planetary systems. In the present study, the magnetic field of FeSt 1-457, a cold starless molecular cloud core, was mapped on the basis of the polarized near-infrared light from 185 background stars after being dichroically absorbed by dust aligned with the magnetic field in the core. A distinct “hourglass-shaped” magnetic field was identified in the region of the core, and was interpreted as the first evidence of a magnetic field structure distorted by mass condensation in a starless core. The steep curvature of the magnetic field lines obtained in the present study indicates that the distortion was mainly created during the formation phase of the dense core. The derived mass-to-magnetic flux ratio indicates that the core is in a magnetically supercritical state. However, the stability of the core can be considered to be in a nearly critical state if the additional contributions from the thermal and turbulent support are included. Further diffusion of the magnetic field and/or turbulent dissipation would cause the onset of the dynamical collapse of the core. The geometrical relationship between the direction of the magnetic field lines and the elongation of the core was found to be in good agreement with theoretical predictions for the formation of Sun-like stars under the influence of a magnetic field.

  2. Deuterium fractionation and H2D+ evolution in turbulent and magnetized cloud cores

    Science.gov (United States)

    Körtgen, Bastian; Bovino, Stefano; Schleicher, Dominik R. G.; Giannetti, Andrea; Banerjee, Robi

    2017-08-01

    High-mass stars are expected to form from dense prestellar cores. Their precise formation conditions are widely discussed, including their virial condition, which results in slow collapse for supervirial cores with strong support by turbulence or magnetic fields, or fast collapse for subvirial sources. To disentangle their formation processes, measurements of the deuterium fractions are frequently employed to approximately estimate the ages of these cores and to obtain constraints on their dynamical evolution. We here present 3D magnetohydrodynamical simulations including for the first time an accurate non-equilibrium chemical network with 21 gas-phase species plus dust grains and 213 reactions. With this network we model the deuteration process in fully depleted prestellar cores in great detail and determine its response to variations in the initial conditions. We explore the dependence on the initial gas column density, the turbulent Mach number, the mass-to-magnetic flux ratio and the distribution of the magnetic field, as well as the initial ortho-to-para ratio (OPR) of H2. We find qualitatively good agreement with recent observations of deuterium fractions in quiescent sources. Our results show that deuteration is rather efficient, even when assuming a conservative OPR of 3 and highly subvirial initial conditions, leading to large deuterium fractions already within roughly a free-fall time. We discuss the implications of our results and give an outlook to relevant future investigations.

  3. A prevalence of dynamo-generated magnetic fields in the cores of intermediate-mass stars.

    Science.gov (United States)

    Stello, Dennis; Cantiello, Matteo; Fuller, Jim; Huber, Daniel; García, Rafael A; Bedding, Timothy R; Bildsten, Lars; Aguirre, Victor Silva

    2016-01-21

    Magnetic fields play a part in almost all stages of stellar evolution. Most low-mass stars, including the Sun, show surface fields that are generated by dynamo processes in their convective envelopes. Intermediate-mass stars do not have deep convective envelopes, although 10 per cent exhibit strong surface fields that are presumed to be residuals from the star formation process. These stars do have convective cores that might produce internal magnetic fields, and these fields might survive into later stages of stellar evolution, but information has been limited by our inability to measure the fields below the stellar surface. Here we report the strength of dipolar oscillation modes for a sample of 3,600 red giant stars. About 20 per cent of our sample show mode suppression, by strong magnetic fields in the cores, but this fraction is a strong function of mass. Strong core fields occur only in red giants heavier than 1.1 solar masses, and the occurrence rate is at least 50 per cent for intermediate-mass stars (1.6-2.0 solar masses), indicating that powerful dynamos were very common in the previously convective cores of these stars.

  4. Impact of Protostellar Outflows on Turbulence and Star Formation Efficiency in Magnetized Dense Cores

    Science.gov (United States)

    Offner, Stella S. R.; Chaban, Jonah

    2017-10-01

    The star-forming efficiency of dense gas is thought to be set within cores by outflow and radiative feedback. We use magnetohydrodynamic simulations to investigate the relation between protostellar outflow evolution, turbulence, and star formation efficiency. We model the collapse and evolution of isolated dense cores for ≳0.5 Myr including the effects of turbulence, radiation transfer, and both radiation and outflow feedback from forming protostars. We show that outflows drive and maintain turbulence in the core environment even with strong initial fields. The star formation efficiency decreases with increasing field strength, and the final efficiencies are 15%–40%. The Stage 0 lifetime, during which the protostellar mass is lower than that of the dense envelope, increases proportionally with the initial magnetic field strength and ranges from ∼ 0.1 {to} 0.4 {Myr}. The average accretion rate is well represented by a tapered turbulent core model, which is a function of the final protostellar mass and is independent of the magnetic field strength. By tagging material launched in the outflow, we demonstrate that the outflow entrains about three times the actual launched gas mass, a ratio that remains roughly constant in time regardless of the initial magnetic field strength. However, turbulent driving increases for stronger fields since momentum is more efficiently imparted to non-outflow material. The protostellar outflow momentum is highest during the first 0.1 Myr and declines thereafter by a factor of ≳ 10 as the accretion rate diminishes.

  5. Pole-strength of the earth from Magsat and magnetic determination of the core radius

    Science.gov (United States)

    Voorhies, G. V.; Benton, E. R.

    1982-01-01

    A model based on two days of Magsat data is used to numerically evaluate the unsigned magnetic flux linking the earth's surface, and a comparison of the 16.054 GWb value calculated with values from earlier geomagnetic field models reveals a smooth, monotonic, and recently-accelerating decrease in the earth's pole strength at a 50-year average rate of 8.3 MWb, or 0.052%/year. Hide's (1978) magnetic technique for determining the radius of the earth's electrically-conducting core is tested by (1) extrapolating main field models for 1960 and 1965 downward through the nearly-insulating mantle, and then separately comparing them to equivalent, extrapolated models of Magsat data. The two unsigned fluxes are found to equal the Magsat values at a radius which is within 2% of the core radius; and (2) the 1960 main field and secular variation and acceleration coefficients are used to derive models of 1930, 1940 and 1950. The same core magnetic radius value, within 2% of the seismic value, is obtained. It is concluded that the mantle is a nearly-perfect insulator, while the core is a perfect conductor, on the decade time scale.

  6. A prevalence of dynamo-generated magnetic fields in the cores of intermediate-mass stars

    CERN Document Server

    Stello, D; Fuller, J; Huber, D; Garcia, R A; Bedding, T R; Bildsten, L; Aguirre, V Silva

    2016-01-01

    Magnetic fields play a role in almost all stages of stellar evolution. Most low-mass stars, including the Sun, show surface fields that are generated by dynamo processes in their convective envelopes. Intermediate-mass stars do not have deep convective envelopes, although 10% exhibit strong surface fields that are presumed to be residuals from the stellar formation process. These stars do have convective cores that might produce internal magnetic fields, and these might even survive into later stages of stellar evolution, but information has been limited by our inability to measure the fields below the stellar surface. Here we use asteroseismology to study the occurrence of strong magnetic fields in the cores of low- and intermediate-mass stars. We have measured the strength of dipolar oscillation modes, which can be suppressed by a strong magnetic field in the core, in over 3600 red giant stars observed by Kepler. About 20% of our sample show mode suppression but this fraction is a strong function of mass. S...

  7. Contributed Review: Nuclear magnetic resonance core analysis at 0.3 T

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, Jonathan, E-mail: JMitchell16@slb.com; Fordham, Edmund J. [Schlumberger Gould Research, High Cross, Madingley Road, Cambridge CB3 0EL (United Kingdom)

    2014-11-15

    Nuclear magnetic resonance (NMR) provides a powerful toolbox for petrophysical characterization of reservoir core plugs and fluids in the laboratory. Previously, there has been considerable focus on low field magnet technology for well log calibration. Now there is renewed interest in the study of reservoir samples using stronger magnets to complement these standard NMR measurements. Here, the capabilities of an imaging magnet with a field strength of 0.3 T (corresponding to 12.9 MHz for proton) are reviewed in the context of reservoir core analysis. Quantitative estimates of porosity (saturation) and pore size distributions are obtained under favorable conditions (e.g., in carbonates), with the added advantage of multidimensional imaging, detection of lower gyromagnetic ratio nuclei, and short probe recovery times that make the system suitable for shale studies. Intermediate field instruments provide quantitative porosity maps of rock plugs that cannot be obtained using high field medical scanners due to the field-dependent susceptibility contrast in the porous medium. Example data are presented that highlight the potential applications of an intermediate field imaging instrument as a complement to low field instruments in core analysis and for materials science studies in general.

  8. First Observations of the Magnetic Field Geometry in Pre-stellar Cores

    CERN Document Server

    Ward-Thompson, D; Crutcher, R M; Greaves, J S; Holland, W S; André, P

    2000-01-01

    We present the first published maps of magnetic fields in pre-stellar cores, to test theoretical ideas about the way in which the magnetic field geometry affects the star formation process. The observations are JCMT-SCUBA maps of 850 micron thermal emission from dust. Linear polarizations at typically ten or more independent positions in each of three objects, L1544, L183 and L43 were measured, and the geometries of the magnetic fields in the plane of the sky were mapped from the polarization directions. The observed polarizations in all three objects appear smooth and fairly uniform. In L1544 and L183 the mean magnetic fields are at an angle of around 30 degrees to the minor axes of the cores. The L43 B-field appears to have been influenced in its southern half, such that it is parallel to the wall of a cavity produced by a CO outflow from a nearby T Tauri star, whilst in the northern half the field appears less disturbed and has an angle of 44 degrees to the core minor axis. We briefly compare our results w...

  9. Contributed review: nuclear magnetic resonance core analysis at 0.3 T.

    Science.gov (United States)

    Mitchell, Jonathan; Fordham, Edmund J

    2014-11-01

    Nuclear magnetic resonance (NMR) provides a powerful toolbox for petrophysical characterization of reservoir core plugs and fluids in the laboratory. Previously, there has been considerable focus on low field magnet technology for well log calibration. Now there is renewed interest in the study of reservoir samples using stronger magnets to complement these standard NMR measurements. Here, the capabilities of an imaging magnet with a field strength of 0.3 T (corresponding to 12.9 MHz for proton) are reviewed in the context of reservoir core analysis. Quantitative estimates of porosity (saturation) and pore size distributions are obtained under favorable conditions (e.g., in carbonates), with the added advantage of multidimensional imaging, detection of lower gyromagnetic ratio nuclei, and short probe recovery times that make the system suitable for shale studies. Intermediate field instruments provide quantitative porosity maps of rock plugs that cannot be obtained using high field medical scanners due to the field-dependent susceptibility contrast in the porous medium. Example data are presented that highlight the potential applications of an intermediate field imaging instrument as a complement to low field instruments in core analysis and for materials science studies in general.

  10. One-pot synthesis and characterization of rhodamine derivative-loaded magnetic core-shell nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Jin, E-mail: jzhang@eng.uwo.ca; Li Jiaxin [University of Western Ontario, Department of Chemical and Biochemical Engineering (Canada); Razavi, Fereidoon S. [Brock University, Department of Physics (Canada); Mumin, Abdul Md. [University of Western Ontario, Department of Chemical and Biochemical Engineering (Canada)

    2011-05-15

    A new method to produce elaborate nanostructure with magnetic and fluorescent properties in one entity is reported in this article. Magnetite (Fe{sub 3}O{sub 4}) coated with fluorescent silica (SiO{sub 2}) shell was produced through the one-pot reaction, in which one reactor was utilized to realize the synthesis of superparamagnetic core of Fe{sub 3}O{sub 4}, the formation of SiO{sub 2} coating through the condensation and polymerization of tetraethylorthosilicate (TEOS), and the encapsulation of tetramethyl rhodamine isothiocyanate-dextran (TRITC-dextran) within silica shell. Transmission electron microscopy (TEM), energy dispersive X-ray (EDX) analysis, and X-ray diffraction (XRD) were carried out to investigate the core-shell structure. The magnetic core of the core-shell nanoparticles is 60 {+-} 10 nm in diameter. The thickness of the fluorescent SiO{sub 2} shell is estimated at 15 {+-} 5 nm. In addition, the fluorescent signal of the SiO{sub 2} shell has been detected by the laser confocal scanning microscopy (LCSM) with emission wavelength ({lambda}{sub em}) at 566 nm. In addition, the magnetic properties of TRITC-dextran loaded silica-coating iron oxide nanoparticles (Fe{sub 3}O{sub 4}-SiO{sub 2} NPs) were studied. The hysteresis loop of the core-shell NPs measured at room temperature shows that the saturation magnetization (M{sub s}) is not reached even at the field of 70 kOe (7T). Meanwhile, the very low coercivity (H{sub c}) and remanent magnetization (M{sub r}) are 0.375 kOe and 6.6 emu/g, respectively, at room temperature. It indicates that the core-shell particles have the superparamagnetic properties. The measured blocking temperature (T{sub B}) of the TRITC-dextran loaded Fe{sub 3}O{sub 4}-SiO{sub 2} NPs is about 122.5 K. It is expected that the multifunctional core-shell nanoparticles can be used in bio-imaging.

  11. Tunable multiple Fano resonances in magnetic single-layered core-shell particles

    CERN Document Server

    Arruda, Tiago Jose; Pinheiro, Felipe Arruda

    2015-01-01

    We investigate multiple Fano, comblike scattering resonances in single-layered, concentric core-shell nanoparticles composed of magnetic materials. Using the Lorenz-Mie theory, we derive, in the long-wavelength limit, an analytical condition for the occurrence of comblike resonances in the single scattering by coated spheres. This condition establishes that comblike scattering response uniquely depends on material parameters and thickness of the shell, provided that it is magnetic and thin compared to the scatterer radius. We also demonstrate that comblike scattering response shows up beyond the long-wavelength limit and it is robust against absorption. Since multiple Fano resonances are shown to depend explicitly on the magnetic permeability of the shell, we argue that both the position and profile of the comblike, morphology-dependent resonances could be externally tuned by exploiting the properties of engineered magnetic materials.

  12. High permeability cores to optimize the stimulation of deeply located brain regions using transcranial magnetic stimulation

    Energy Technology Data Exchange (ETDEWEB)

    Salvador, R; Miranda, P C [Institute of Biophysics and Biomedical Engineering, Faculty of Sciences, University of Lisbon, 1749-016 Lisbon (Portugal); Roth, Y [Advanced Technology Center, Sheba Medical Center, Tel-Hashomer (Israel); Zangen, A [Neurobiology Department, Weizmann Institute of Science, Rehovot 76100 (Israel)], E-mail: rnsalvador@fc.ul.pt

    2009-05-21

    Efficient stimulation of deeply located brain regions with transcranial magnetic stimulation (TMS) poses many challenges, arising from the fact that the induced field decays rapidly and becomes less focal with depth. We propose a new method to improve the efficiency of TMS of deep brain regions that combines high permeability cores, to increase focality and field intensity, with a coil specifically designed to induce a field that decays slowly with increasing depth. The performance of the proposed design was investigated using the finite element method to determine the total electric field induced by this coil/core arrangement on a realistically shaped homogeneous head model. The calculations show that the inclusion of the cores increases the field's magnitude by as much as 25% while also decreasing the field's decay with depth along specific directions. The focality, as measured by the area where the field's norm is greater than 1/{radical}2 of its maximum value, is also improved by as much as 15% with some core arrangements. The coil's inductance is not significantly increased by the cores. These results show that the presence of the cores might make this specially designed coil even more suited for the effective stimulation of deep brain regions.

  13. On the magnetic field evolution time-scale in superconducting neutron star cores

    Science.gov (United States)

    Passamonti, Andrea; Akgün, Taner; Pons, José A.; Miralles, Juan A.

    2017-08-01

    We revisit the various approximations employed to study the long-term evolution of the magnetic field in neutron star cores and discuss their limitations and possible improvements. A recent controversy on the correct form of the induction equation and the relevant evolution time-scale in superconducting neutron star cores is addressed and clarified. We show that this ambiguity in the estimation of time-scales arises as a consequence of nominally large terms that appear in the induction equation, but which are, in fact, mostly irrotational. This subtlety leads to a discrepancy by many orders of magnitude when velocity fields are absent or ignored. Even when internal velocity fields are accounted for, only the solenoidal part of the electric field contributes to the induction equation, which can be substantially smaller than the irrotational part. We also argue that stationary velocity fields must be incorporated in the slow evolution of the magnetic field as the next level of approximation.

  14. First experimental demonstration of magnetic-field assisted fast heating of a dense plasma core

    Science.gov (United States)

    Fujioka, Shinsuke; Sakata, Shohei; Lee, Seung Ho; Matsuo, Kazuki; Sawada, Hiroshi; Iwasa, Yuki; Law, King Fai Farley; Morita, Hitoki; Kojima, Sadaoki; Abe, Yuki; Yao, Akira; Hata, Masayasu; Johzaki, Tomoyuki; Sunahara, Atsushi; Ozaki, Tetsuo; Sakagami, Hitoshi; Morace, Alessio; Arikawa, Yasunobu; Yogo, Akifumi; Nishimura, Hiroaki; Nakai, Mitsuo; Shiraga, Hiroyuki; Sentoku, Yasuhiko; Nagatomo, Hideo; Azechi, Hiroshi; Firex Project Team

    2016-10-01

    Fast heating of a dense plasma core by an energetic electron beam is being studied on GEKKO-LFEX laser facility. Here, we introduce a laser-driven kilo-tesla external magnetic field to guide the diverging electron beam to the dense plasma core. This involve placing a spherical target in the magnetic field, compressing it with the GEKKO-XII laser beams and then using the LFEX laser beams injected into the dense plasma to generate the electron beam which do the fast heating. Cu-Ka emission is used to visualize transport or heating processes of a dense plasma. X-ray spectrum from a highly ionized Cu ions indicates several keV of the temperature increment induced by the LFEX.

  15. Parameters Identification of Fluxgate Magnetic Core Adopting the Biogeography-Based Optimization Algorithm

    Directory of Open Access Journals (Sweden)

    Wenjuan Jiang

    2016-06-01

    Full Text Available The main part of the magnetic fluxgate sensor is the magnetic core, the hysteresis characteristic of which affects the performance of the sensor. When the fluxgate sensors are modelled for design purposes, an accurate model of hysteresis characteristic of the cores is necessary to achieve good agreement between modelled and experimental data. The Jiles-Atherton model is simple and can reflect the hysteresis properties of the magnetic material precisely, which makes it widely used in hysteresis modelling and simulation of ferromagnetic materials. However, in practice, it is difficult to determine the parameters accurately owing to the sensitivity of the parameters. In this paper, the Biogeography-Based Optimization (BBO algorithm is applied to identify the Jiles-Atherton model parameters. To enhance the performances of the BBO algorithm such as global search capability, search accuracy and convergence rate, an improved Biogeography-Based Optimization (IBBO algorithm is put forward by using Arnold map and mutation strategy of Differential Evolution (DE algorithm. Simulation results show that IBBO algorithm is superior to Genetic Algorithm (GA, Particle Swarm Optimization (PSO algorithm, Differential Evolution algorithm and BBO algorithm in identification accuracy and convergence rate. The IBBO algorithm is applied to identify Jiles-Atherton model parameters of selected permalloy. The simulation hysteresis loop is in high agreement with experimental data. Using permalloy as core of fluxgate probe, the simulation output is consistent with experimental output. The IBBO algorithm can identify the parameters of Jiles-Atherton model accurately, which provides a basis for the precise analysis and design of instruments and equipment with magnetic core.

  16. Single-core magnetic markers in rotating magnetic field based homogeneous bioassays and the law of mass action

    Energy Technology Data Exchange (ETDEWEB)

    Dieckhoff, Jan, E-mail: j.dieckhoff@tu-bs.de [Institut fuer Elektrische Messtechnik und Grundlagen der Elektrotechnik, TU Braunschweig, Braunschweig (Germany); Schrittwieser, Stefan; Schotter, Joerg [Molecular Diagnostics, AIT Austrian Institute of Technology, Vienna (Austria); Remmer, Hilke; Schilling, Meinhard; Ludwig, Frank [Institut fuer Elektrische Messtechnik und Grundlagen der Elektrotechnik, TU Braunschweig, Braunschweig (Germany)

    2015-04-15

    In this work, we report on the effect of the magnetic nanoparticle (MNP) concentration on the quantitative detection of proteins in solution with a rotating magnetic field (RMF) based homogeneous bioassay. Here, the phase lag between 30 nm iron oxide single-core particles and the RMF is analyzed with a fluxgate-based measurement system. As a test analyte anti-human IgG is applied which binds to the protein G functionalized MNP shell and causes a change of the phase lag. The measured phase lag changes for a fixed MNP and a varying analyte concentration are modeled with logistic functions. A change of the MNP concentration results in a nonlinear shift of the logistic function with the analyte concentration. This effect results from the law of mass action. Furthermore, the bioassay results are used to determine the association constant of the binding reaction. - Highlights: • A rotating magnetic field based homogeneous bioassay concept was presented. • Here, single-core iron oxide nanoparticles are applied as markers. • The impact of the particle concentration on the bioassay results is investigated. • The relation between particle concentration and bioassay sensitivity is nonlinear. • This finding can be reasonably explained by the law of mass action.

  17. Influence of time dependent longitudinal magnetic fields on the cooling process, exchange bias and magnetization reversal mechanism in FM core/AFM shell nanoparticles: a Monte Carlo study

    Science.gov (United States)

    Yüksel, Yusuf; Akıncı, Ümit

    2016-12-01

    Using Monte Carlo simulations, we have investigated the dynamic phase transition properties of magnetic nanoparticles with ferromagnetic core coated by an antiferromagnetic shell structure. Effects of field amplitude and frequency on the thermal dependence of magnetizations, magnetization reversal mechanisms during hysteresis cycles, as well as on the exchange bias and coercive fields have been examined, and the feasibility of applying dynamic magnetic fields on the particle have been discussed for technological and biomedical purposes.

  18. Defected-core photonic crystal fiber magnetic field sensor based on Sagnac interferometer

    Science.gov (United States)

    Liu, Qiang; Li, Shuguang; Dou, Chao; Wang, Xinyu

    2017-03-01

    A high-sensitivity magnetic field sensor based on photonic crystal fiber (PCF) Sagnac interferometer is proposed by finite element method (FEM). The elliptical-hole PCF is injected with water-based magnetic fluid. The fiber core is introduced in an elliptical hole to act as a defected core. The sensitivities are 13.25 and -14.32 nm/Oe at the wavelength of 1750 and 1780 nm, respectively, as the magnetic field H is 100 Oe. The simulation result shows that the sensitivity is extremely high near the wavelength of 1765 nm, because the group birefringence Bg is about zero at that wavelength. The above theory is examined in a different configuration by the transmission mode. The average sensitivities are 0.265, 1.63 and -1.915 nm/Oe, respectively, for the dip wavelength A, B and C as the fiber length is 5 cm. The detecting window is 60Oe. We also demonstrate that the sensitivity can be greatly enhanced by 1-2 orders of magnitude by introducing a defected core.

  19. Directed Fluid Flow Produced by Arrays of Magnetically Actuated Core-Shell Biomimetic Cilia

    Science.gov (United States)

    Fiser, B. L.; Shields, A. R.; Evans, B. A.; Superfine, R.

    2010-03-01

    We have developed a novel core-shell microstructure that we use to fabricate arrays of flexible, magnetically actuated biomimetic cilia. Our biomimetic cilia mimic the size and beat shape of biological cilia in order to replicate the transport of fluid driven by cilia in many biological systems including the determination of left-right asymmetry in the vertebrate embryonic nodal plate and mucociliary clearance in the lung. Our core-shell structures consist of a flexible poly(dimethylsiloxane) (PDMS) core surrounded by a shell of nickel approximately forty nanometers thick; by using a core-shell structure, we can tune the mechanical and magnetic properties independently. We present the fabrication process and the long-range transport that occurs above the beating biomimetic cilia tips and will report on progress toward biomimetic cilia induced flow in viscoelastic fluids similar to mucus in the human airway. These flows may have applications in photonics and microfluidics, and our structures may be further useful as sensors or actuators in microelectromechanical systems.

  20. Porous TiO2-coated Magnetic Core-Shell Nanocomposites: Preparation and Enhanced Photocatalytic Activity

    Institute of Scientific and Technical Information of China (English)

    LIU Hongfei; JI Shengfu; ZHENG Yuanyuan; LI Ming; YANG Hao

    2013-01-01

    The core-shell structured TiO2/SiO2@Fe3O4 photocatalysts were prepared using Fe3O4 as magnetic core,tetraethoxysilane (TEOS) as silica source and tetrabutyl titanate (TBOT) as titanium sources.The as-obtained structure was composed of a SiO2@Fe3O4 core and a porous TiO2 shell.The diameter of SiO2@Fe3O4 core was about 205 nm with thickness of porous TiO2 of about 5-6 nm.The 9%TiO2/6% SiO2@Fe3O4 microspheres possess the highest BET surface area and the BJH pore volume,which are 373.5 m2·g-1 and 0.28 cm3·g-1,respectively.The 9%TiO2/6%SiO2@Fe3O4 photocatalyst exhibited an excellent performance for the degradation of methyl orange and methylene blue dyes.Two different dyes were completely decolorized in 60 rain under UV irradiation.The photocatalytic activity and the amount of catalyst were almost not decrease after recycling for 6 times by using external magnetic field.

  1. Structural and magnetic properties of core-shell Au/Fe3O4 nanoparticles

    Science.gov (United States)

    León Félix, L.; Coaquira, J. A. H.; Martínez, M. A. R.; Goya, G. F.; Mantilla, J.; Sousa, M. H.; Valladares, L. De Los Santos; Barnes, C. H. W.; Morais, P. C.

    2017-02-01

    We present a systematic study of core-shell Au/Fe3O4 nanoparticles produced by thermal decomposition under mild conditions. The morphology and crystal structure of the nanoparticles revealed the presence of Au core of d = (6.9 ± 1.0) nm surrounded by Fe3O4 shell with a thickness of ~3.5 nm, epitaxially grown onto the Au core surface. The Au/Fe3O4 core-shell structure was demonstrated by high angle annular dark field scanning transmission electron microscopy analysis. The magnetite shell grown on top of the Au nanoparticle displayed a thermal blocking state at temperatures below TB = 59 K and a relaxed state well above TB. Remarkably, an exchange bias effect was observed when cooling down the samples below room temperature under an external magnetic field. Moreover, the exchange bias field (HEX) started to appear at T~40 K and its value increased by decreasing the temperature. This effect has been assigned to the interaction of spins located in the magnetically disordered regions (in the inner and outer surface of the Fe3O4 shell) and spins located in the ordered region of the Fe3O4 shell.

  2. The influence of turbulence during magnetized core collapse and its consequences on low-mass star formation

    CERN Document Server

    Joos, Marc; Ciardi, Andrea; Fromang, Sebastien

    2013-01-01

    [Abridged] Theoretical and numerical studies of star formation have shown that magnetic field (B) has a strong influence on both disk formation and fragmentation; even a relatively low B can prevent these processes. However, very few studies investigated the combined effects of B and turbulence. We study the effects of turbulence in magnetized core collapse, focusing on the magnetic diffusion, the orientation of the angular momentum (J) of the protostellar core, and on its consequences on disk formation, fragmentation and outflows. We perform 3D, AMR, MHD simulations of magnetically supercritical collapsing dense cores of 5 Msun using the MHD code RAMSES. A turbulent velocity field is imposed as initial conditions, characterised by a Kolmogorov power spectrum. Different levels of turbulence and magnetization are investigated, as well as 3 realisations for the turbulent velocity field. Magnetic diffusion, orientation of the rotation axis with respect to B, transport of J, disk formation, fragmentation and outf...

  3. Magnetic model for a horse-spleen ferritin with a three-phase core structure

    Energy Technology Data Exchange (ETDEWEB)

    Jung, J.H.; Eom, T.W. [Quantum Photonic Science Research Center, Department of Physics and Research Institute for Natural Sciences, Hanyang University, Seoul 133-791 (Korea, Republic of); Lee, Y.P., E-mail: yplee@hanyang.ac.kr [Quantum Photonic Science Research Center, Department of Physics and Research Institute for Natural Sciences, Hanyang University, Seoul 133-791 (Korea, Republic of); Rhee, J.Y. [Department of Physics, Sungkyunkwan University, Suwon (Korea, Republic of); Choi, E.H. [Kwangwoon University, Seoul (Korea, Republic of)

    2011-12-15

    The increasing interests in magnetic nanoparticles has prompted research on ferritin, which is naturally a well-defined iron-storage protein in most living organisms. However, the exact magnetic behavior of ferritin is not well understood, because the crystal structures of ferritin and ferrihydrite, its major component, are not fully understood. Briefly, we discuss the previous magnetization models of ferritin and ferrihydrite and we present a new model ({Sigma}3L) of the initial magnetization of ferritin, considering its different phases. The new model includes three Langevin-function terms, which represent three different magnetic moments provided by the likely hydroxide and oxide mineral phases in ferritin. Compared to previous models, our simple model fits the experimental data 12 times better in terms of the sum of least squares. The magnetic independence of each component supports the multi-phase compositional model of the mineral core of horse-spleen ferritin. This {Sigma}3L model gives a quantization of the amounts of the different phases within horse-spleen ferritins that matches other published experimental data: 60-80% ferrihydrite, 15-25% maghemite/magnetite, and 1-10% hematite. - Highlights: > We present a new model ({Sigma}3L) of the initial magnetization of ferritin, considering its different phases. > New model includes three Langevin-function terms, which represent three different magnetic moments provided by ferritin phases. > Compared to previous models, our simple model fits the experimental data 12 times better in terms of the sum of least square. > The magnetic independence of each component supports that ferritin and ferrihydrite are composed of different phases.

  4. CORE

    DEFF Research Database (Denmark)

    Krigslund, Jeppe; Hansen, Jonas; Hundebøll, Martin

    2013-01-01

    different flows. Instead of maintaining these approaches separate, we propose a protocol (CORE) that brings together these coding mechanisms. Our protocol uses random linear network coding (RLNC) for intra- session coding but allows nodes in the network to setup inter- session coding regions where flows...... intersect. Routes for unicast sessions are agnostic to other sessions and setup beforehand, CORE will then discover and exploit intersecting routes. Our approach allows the inter-session regions to leverage RLNC to compensate for losses or failures in the overhearing or transmitting process. Thus, we...... increase the benefits of XORing by exploiting the underlying RLNC structure of individual flows. This goes beyond providing additional reliability to each individual session and beyond exploiting coding opportunistically. Our numerical results show that CORE outperforms both forwarding and COPE...

  5. CORE

    DEFF Research Database (Denmark)

    Krigslund, Jeppe; Hansen, Jonas; Hundebøll, Martin

    2013-01-01

    different flows. Instead of maintaining these approaches separate, we propose a protocol (CORE) that brings together these coding mechanisms. Our protocol uses random linear network coding (RLNC) for intra- session coding but allows nodes in the network to setup inter- session coding regions where flows...... intersect. Routes for unicast sessions are agnostic to other sessions and setup beforehand, CORE will then discover and exploit intersecting routes. Our approach allows the inter-session regions to leverage RLNC to compensate for losses or failures in the overhearing or transmitting process. Thus, we...... increase the benefits of XORing by exploiting the underlying RLNC structure of individual flows. This goes beyond providing additional reliability to each individual session and beyond exploiting coding opportunistically. Our numerical results show that CORE outperforms both forwarding and COPE...

  6. Resonantly exited precession motion of three-dimensional vortex core in magnetic nanospheres

    Science.gov (United States)

    Kim, Sang-Koog; Yoo, Myoung-Woo; Lee, Jehyun; Lee, Ha-Youn; Lee, Jae-Hyeok; Gaididei, Yuri; Kravchuk, Volodymyr P.; Sheka, Denis D.

    2015-01-01

    We found resonantly excited precession motions of a three-dimensional vortex core in soft magnetic nanospheres and controllable precession frequency with the sphere diameter 2R, as studied by micromagnetic numerical and analytical calculations. The precession angular frequency for an applied static field HDC is given as ωMV = γeffHDC, where γeff = γ〈mΓ〉 is the effective gyromagnetic ratio in collective vortex dynamics, with the gyromagnetic ratio γ and the average magnetization component 〈mΓ〉 of the ground-state vortex in the core direction. Fitting to the micromagnetic simulation data for 〈mΓ〉 yields a simple explicit form of 〈mΓ〉 ≈ (73.6 ± 3.4)(lex/2R)2.20±0.14, where lex is the exchange length of a given material. This dynamic behavior might serve as a foundation for potential bio-applications of size-specific resonant excitation of magnetic vortex-state nanoparticles, for example, magnetic particle resonance imaging. PMID:26079895

  7. Resonantly excited precession motion of three-dimensional vortex core in magnetic nanospheres [corrected].

    Science.gov (United States)

    Kim, Sang-Koog; Yoo, Myoung-Woo; Lee, Jehyun; Lee, Ha-Youn; Lee, Jae-Hyeok; Gaididei, Yuri; Kravchuk, Volodymyr P; Sheka, Denis D

    2015-01-01

    We found resonantly excited precession motions of a three-dimensional vortex core in soft magnetic nanospheres and controllable precession frequency with the sphere diameter 2R, as studied by micromagnetic numerical and analytical calculations. The precession angular frequency for an applied static field HDC is given as ωMV = γeffHDC, where γeff = γ〈mΓ〉 is the effective gyromagnetic ratio in collective vortex dynamics, with the gyromagnetic ratio γ and the average magnetization component 〈mΓ〉 of the ground-state vortex in the core direction. Fitting to the micromagnetic simulation data for 〈mΓ〉 yields a simple explicit form of 〈mΓ〉 ≈ (73.6 ± 3.4)(lex/2R)(2.20±0.14), where lex is the exchange length of a given material. This dynamic behavior might serve as a foundation for potential bio-applications of size-specific resonant excitation of magnetic vortex-state nanoparticles, for example, magnetic particle resonance imaging.

  8. All-fiber optical modulator based on no-core fiber and magnetic fluid as cladding

    Science.gov (United States)

    Chen, Yao-Fei; Han, Qun; Liu, Tie-Gen

    2015-01-01

    An all-fiber optical modulator, which is composed of a piece of no-core fiber spliced between two sections of single-mode fibers and uses magnetic fluid (MF) as the cladding of the no-core fiber section, is proposed and investigated experimentally. Due to the tunable refractive index and absorption coefficient of MF, the output intensity can be modulated by controlling an applied magnetic field. The dependences of the modulator’s temporal response on the working wavelength, the magnetic field strength (H), and the MF’s concentration are investigated experimentally. The results are explained qualitatively by the dynamic response process of MF under the action of a magnetic field. The findings are helpful for optimizing this kind of modulator. Project supported by the Natural Science Foundation of Tianjin City, China (Grant No. 13JCYBJC16100), the National Natural Science Foundation of China (Grant No. 61107035), the National Key Scientific Instrument and Equipment Development Project of China (Grant No. 2013YQ03091502), and the National Basic Research Program of China (Grant Nos. 2010CB327802 and 2010CB327806).

  9. Effects of the random field on the magnetic behavior of nanowires with core/shell morphology

    Energy Technology Data Exchange (ETDEWEB)

    Zaim, A., E-mail: ah_zaim@yahoo.fr [Laboratoire Physique des Matériaux et Modélisation des Systèmes (LP2MS), Unité Associée au CNRST-URAC: 08, Faculty of Sciences, University Moulay Ismail, B.P. 11201, Zitoune, Meknes (Morocco); Kerouad, M., E-mail: kerouad@fs-umi.ac.ma [Laboratoire Physique des Matériaux et Modélisation des Systèmes (LP2MS), Unité Associée au CNRST-URAC: 08, Faculty of Sciences, University Moulay Ismail, B.P. 11201, Zitoune, Meknes (Morocco); Boughrara, M. [Laboratoire Physique des Matériaux et Modélisation des Systèmes (LP2MS), Unité Associée au CNRST-URAC: 08, Faculty of Sciences, University Moulay Ismail, B.P. 11201, Zitoune, Meknes (Morocco)

    2013-04-15

    We have used the effective field theory based on probability distribution method to investigate the hysteresis behavior of the magnetic nanowires with core/shell morphology in a random magnetic field. The hysteresis curves are obtained for different values of the random magnetic field, both ferromagnetic and antiferromagnetic couplings between the shell and the core are considered. A number of characteristic behaviors are find, such as the existence of double or triple hysteresis loops for appropriate values of the system parameters affected by the random magnetic field, temperature, and interfacial coupling. -- Highlights: ► The hysteresis behavior of the Ising nanowires has been studied by EFT. ► The effects of the random field on the hysteresis loops have been examined. ► The hysteresis loops are obtained for different values of the interfacial coupling constant. ► The triple hysteresis loops occur for the larger antiferromagnetic coupling constant. ► The dependence of the coercive field on the temperature is investigated.

  10. RECONCILING MODELS OF LUMINOUS BLAZARS WITH MAGNETIC FLUXES DETERMINED BY RADIO CORE-SHIFT MEASUREMENTS

    Energy Technology Data Exchange (ETDEWEB)

    Nalewajko, Krzysztof; Begelman, Mitchell C. [JILA, University of Colorado and National Institute of Standards and Technology, 440 UCB, Boulder, CO 80309 (United States); Sikora, Marek, E-mail: knalew@stanford.edu [Nicolaus Copernicus Astronomical Center, Bartycka 18, 00-716 Warsaw (Poland)

    2014-11-20

    Estimates of magnetic field strength in relativistic jets of active galactic nuclei, obtained by measuring the frequency-dependent radio core location, imply that the total magnetic fluxes in those jets are consistent with the predictions of the magnetically arrested disk (MAD) scenario of jet formation. On the other hand, the magnetic field strength determines the luminosity of the synchrotron radiation, which forms the low-energy bump of the observed blazar spectral energy distribution (SED). The SEDs of the most powerful blazars are strongly dominated by the high-energy bump, which is most likely due to the external radiation Compton mechanism. This high Compton dominance may be difficult to reconcile with the MAD scenario, unless (1) the geometry of external radiation sources (broad-line region, hot-dust torus) is quasi-spherical rather than flat, or (2) most gamma-ray radiation is produced in jet regions of low magnetization, e.g., in magnetic reconnection layers or in fast jet spines.

  11. Reconciling models of luminous blazars with magnetic fluxes determined by radio core shift measurements

    CERN Document Server

    Nalewajko, Krzysztof; Begelman, Mitchell C

    2014-01-01

    Estimates of magnetic field strength in relativistic jets of active galactic nuclei (AGN), obtained by measuring the frequency-dependent radio core location, imply that the total magnetic fluxes in those jets are consistent with the predictions of the magnetically-arrested disk (MAD) scenario of jet formation. On the other hand, the magnetic field strength determines the luminosity of the synchrotron radiation, which forms the low-energy bump of the observed blazar spectral energy distribution (SED). The SEDs of the most powerful blazars are strongly dominated by the high-energy bump, which is most likely due to the external radiation Compton (ERC) mechanism. This high Compton dominance may be difficult to reconcile with the MAD scenario, unless 1) the geometry of external radiation sources (broad-line region, hot-dust torus) is quasi-spherical rather than flat, or 2) most gamma-ray radiation is produced in jet regions of low magnetization, e.g., in magnetic reconnection layers or in fast jet spines.

  12. SXR-XUV Diagnostics for Edge and Core of Magnetically Confined Plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Stutman, Dan [Johns Hopkins University

    2014-09-10

    The present report summarizes the results obtained during a one-year extension of DoE grant “SXR-XUV Diagnostics for Edge and Core of Magnetically Confined Plasmas”, at Johns Hopkins University, aimed at completing the development of a new type of magnetic fusion plasma diagnostic, the XUV Transmission Grating Imaging Radiometer (TGIR). The TGIR enables simultaneous spatially and spectrally resolved measurements of the XUV/VUV radiated power from impurities in fusion plasmas, with high speed. The instrument was successfully developed and qualified in the laboratory and in experiments on a tokamak. Its future applications will be diagnostic of the impurity content and transport in the divertor and edge of advanced magnetic fusion experiments, such as NSTX Upgrade.

  13. Solid-core and hollow magnetic nanostructures: Synthesis, surface modifications and biological applications.

    Science.gov (United States)

    Nieciecka, Dorota; Nawara, Krzysztof; Kijewska, Krystyna; Nowicka, Anna M; Mazur, Maciej; Krysinski, Pawel

    2013-10-01

    In the need of development of versatile and flexible platforms for sensing, nanostructured particles are one of the systems of choice. Additionally, the state-of-the-art, controlled surface modifications of these structures offer broad possibilities of using such systems for diagnostics and therapy, often referred to as thera(g)nostics. In this brief review we will focus on the synthesis and surface modifications of solid-core magnetic nanostructures and polymeric capsules containing nanoferrites modified with anti-cancer drug--doxorubicin, designed for magnetic field-driven drug delivery for cancer therapy. We will also outline some problems related to the usage of such structures. The encapsulation and distribution of magnetic iron oxide nanoparticles modified with doxorubicin will be demonstrated in the polypyrrole spherical microvessels.

  14. Gravitational Radiation from Rotational Core Collapse: Effects of Magnetic Fields and Realistic Equation of States

    CERN Document Server

    Kotake, K; Sato, K; Sumiyoshi, K; Ono, H; Suzuki, H; Kotake, Kei; Yamada, Shoichi; Sato, Katsuhiko; Sumiyoshi, Kohsuke; Ono, Hiroyuki; Suzuki, Hideyuki

    2004-01-01

    We perform a series of two-dimensional, axisymmetric, magnetohydrodynamic simulations of the rotational collapse of a supernova core. In order to calculate the waveforms of the gravitational wave, we derive the quadrupole formula including the contributions from the electromagnetic fields. Recent stellar evolution calculations imply that the magnetic fields of the toroidal components are much stronger than those of the poloidal ones at the presupernova stage. Thus, we systematically investigate the effects of the toroidal magnetic fields on the amplitudes and waveforms. Furthermore, we employ the two kinds of the realistic equation of states, which are often used in the supernova simulations. Then, we investigate the effects of the equation of states on the gravitational wave signals. With these computations, we find that the peak amplitudes are lowered by an order of 10% for the models with the strongest toroidal magnetic fields. However, the peak amplitudes are mostly within sensitivity range of laser inter...

  15. Three-Dimensional Self-Assembly of Core/Shell-Like Nanostructures for High-Performance Nanocomposite Permanent Magnets.

    Science.gov (United States)

    Li, Hailing; Li, Xiaohong; Guo, Defeng; Lou, Li; Li, Wei; Zhang, Xiangyi

    2016-09-14

    Core/shell nanostructures are fascinating for many advanced applications including strong permanent magnets, magnetic recording, and biotechnology. They are generally achieved via chemical approaches, but these techniques limit them to nanoparticles. Here, we describe a three-dimensional (3D) self-assembly of core/shell-like nanocomposite magnets, with hard-magnetic Nd2Fe14B core of ∼45 nm and soft-magnetic α-Fe shell of ∼13 nm, through a physical route. The resulting Nd2Fe14B/α-Fe core/shell-like nanostructure allows both large remanent magnetization and high coercivity, leading to a record-high energy product of 25 MGOe which reaches the theoretical limit for isotropic Nd2Fe14B/α-Fe nanocomposite magnets. Our approach is based on a sequential growth of the core and shell nanocrystals in an alloy melt. These results make an important step toward fabricating core/shell-like nanostructure in 3D materials.

  16. Magnetically self-assembled SrFe12O19/Fe-Co core/shell particles

    Energy Technology Data Exchange (ETDEWEB)

    Xu, X; Park, J; Hong, YK; Lane, AM

    2015-02-15

    Epitaxial growth to synthesize core/shell-structured materials is limited because large lattice mismatches are common between materials. Magnetically hard/soft, core/shell-structured materials can be potentially used for rare-earth free permanent magnets, but their synthesis presents a challenge. We report a wet chemistry method to synthesize core/shell structured particles consisting of a magnetically hard SrFe12O19 core and a soft Fe-Co shell, with a lattice mismatch of similar to 100%, which cannot be achieved by conventional epitaxial growth or other alternative methods. When decreasing the size of the magnetically soft Fe-Co nanoclusters to below 5 nm, we show that they can be magnetically attracted by the hard SrFe12O19 to form core/shell structured particles. An AC demagnetization experiment demonstrates the formation mechanism of the core/shell particles, and their magnetic hysteresis loop shows potential for use as rare-earth free permanent magnets. Published by Elsevier B.V.

  17. Development of a Magnetic-Core, Transverse-Field AF Demagnetizer

    Science.gov (United States)

    Schillinger, W. E.; Morris, E. R.; Coe, R. S.; Finn, D. R.

    2016-12-01

    A standard cleaning technique in the study of a rock's natural remanent magnetization (NRM) is progressive Alternating Field Demagnetization (AFD). However, for a significant fraction of samples, demagnetization is not completed by the maximum field of 200 mT or less available in commercial instruments; a field at least two or three times higher is needed. The data from 0 to 160 mT for a resistant red bed sample from Tibet is shown below. It just starts to reveal the sample's characteristic component, but this interpretation would have been tenuous, since 85% of the NRM remained untouched. Continued demagnetization to 500 mT helps a great deal, reducing the NRM to just 30% of its initial value and proving that the segment from 160 to 500 mT indeed trends toward the origin. We have constructed an alternating field (AF) demagnetizer that can routinely operate at fields of up to 0.6 Tesla. It uses a magnetic core in an air-cooled coil and is compatible with our existing sample handler for automated demagnetization and measurement experiments. Nonlinearities of the magnetic core are not a significant problem; even harmonics of the magnetic field are ≤1 ppm of the fundamental and so generate negligible anhysteretic remanence. A surprising result during the testing was that the coil's inductance changed with magnetic field. This made it necessary to add an auto-tuning feature, to keep the drive's frequency on the coil's resonance. We have recently added the ability to include a DC field of up to 0.5 mT, parallel to the alternating field, to perform Anhysteretic Remanent Magnetization (ARM), partial ARM experiments and anisotropy of ARM. We will report on these ARM results at the AGU meeting. Currently the maximum field we can obtain is 600 mT, but by reshaping the core to minimize flux leakage, significantly higher fields should be attainable, since the saturation flux density of the core material is 1.5T.

  18. Disc formation in turbulent cloud cores: is magnetic flux loss necessary to stop the magnetic braking catastrophe or not?

    CERN Document Server

    Santos-Lima, R; Lazarian, A

    2012-01-01

    Recent numerical analysis of Keplerian disk formation in turbulent, magnetized cloud cores by Santos-Lima, de Gouveia Dal Pino, & Lazarian (2012) demonstrated that reconnection diffusion is an efficient process to remove the magnetic flux excess during the build up of a rotationally supported disk. This process is induced by fast reconnection of the magnetic fields in a turbulent flow. In a similar numerical study, Seifried et al. (2012) concluded that reconnection diffusion or any other non-ideal MHD effects would not be necessary and turbulence shear alone would provide a natural way to build up a rotating disk without requiring magnetic flux loss. Their conclusion was based on the fact that the mean mass-to-flux ratio ({\\mu}) evaluated over a spherical region with a radius much larger than the disk is nearly constant in their models. In this letter we compare the two sets of simulations and show that this averaging over large scales can mask significant real increases of {\\mu} in the inner regions wher...

  19. MAGNETIC CORE SHELL STRUCTURES: from 0D to 1D assembling.

    Science.gov (United States)

    Ficai, Denisa; Ficai, Anton; Dinu, Elena; Oprea, Ovidiu; Sonmez, Maria; Keler, Memduh Kagan; Sahin, Yesim Muge; Ekren, Nazmi; Inan, Ahmet Talat; Daglilar, Sibel; Gunduz, Oguzhan

    2015-01-01

    Material research and development studies are focused on different techniques of bringing out nanomaterials with desired characteristics and properties. From the point of view of materials development, nowadays scientists are strongly focused on obtaining materials with predefined characteristics and properties. The morphology control seems to be a determinant factor and increasing attention is devoted to this aspect. At this moment it is possible to engineer the material's features by using different methods and materials combination for both medical and industrial applications. In the applications of chemistry and synthesis, biology, mechanics, optics solar cells and microelectronics tailoring the adjustable parameters of stoichiometry, chemical structure, shape and segregation are evaluated and opens new fields. Because of the magnetic features of nanoparticles and durable particle size, less than 100 nm, this study is aiming to describe their uses in practical applications. That's why the whole hydrodynamic magnetic core shell topic will be reviewed on this paper. Additionally, the properties acting in general sight in solid-state physics are utilized for material selection and for defining issue connecting the core, shell structure and their producing properties. Here, in the study of core/shell nanoparticle various physical and chemical synthesis routes and the effect of electrospun method are briefly discussed. Starting from a real void of the scientific literature, the existent data related to the 1D magnetic electrospun materials are reviewed. The perspectives in the medical, environmental or energetic sector is great and bring some real advantages related to the 0D core@shell structures because both mechanical and biological properties are dependent on the morphology of the materials.

  20. Magnetic core test stand for energy loss and permeability measurements at a high constant magnetization rate and test results for nanocrystalline and ferrite materials.

    Science.gov (United States)

    Burdt, Russell; Curry, Randy D

    2008-09-01

    A test stand was developed to measure the energy losses and unsaturated permeability of toroidal magnetic cores, relevant to applications of magnetic switching requiring a constant magnetization rate of the order of 1-10 T/micros. These applications in pulsed power include linear induction accelerators, pulse transformers, and discharge switches. The test stand consists of a coaxial transmission line pulse charged up to 100 kV that is discharged into a magnetic core load. Suitable diagnostics measure the voltage across and the current through a winding on the magnetic core load, from which the energy losses and unsaturated permeability are calculated. The development of the test stand is discussed, and test results for ferrite CN20 and the nanocrystalline material Finemet FT-1HS are compared to demonstrate the unique properties of a nanocrystalline material. The experimental data are compared with published data in a similar parameter space to demonstrate the efficacy of the experimental methods.

  1. Mixing of Impactor Liquid Cores and Planetesimals Constrained by Single Silicate Crystal Magnetism

    Science.gov (United States)

    Bono, R. K.; Tarduno, J. A.; Nimmo, F.; Scott, E.; Ferrière, L.

    2014-12-01

    The formation of pallasites, meteorites composed mainly of intermixed FeNi metal and angular to rounded olivine crystals, has been a paradox because these components should have separated into distinct layers at their putative location of origin: the core-mantle boundary (CMB) of an asteroid. Paleomagnetic study of gem-like angular olivine bearing minute magnetic inclusions from the main group Esquel and Imilac pallasite meteorites, however, reveals the past presence of strong magnetic fields requiring a core dynamo. A CMB location is too hot for pallasites to record these magnetizations. Alternatively, the paleomagnetic field strengths, combined with cooling rate data and thermal modeling, suggest an origin for main group pallasites in the shallow mantle of a parent body, with the FeNi metal originating from the liquid core of an impactor (Tarduno et al., Science, 2012). Here, we extend this model to include the origin of main group pallasite meteorites with rounded olivine, and pallasites of the Eagle Station group. Main group pallasites with rounded olivine (e.g., Springwater) could have formed in larger intruded liquid FeNi masses relative to the thinner dikes envisioned for the formation of pallasites with angular olivine crystals. Pallasites of the Eagle Station group have an oxygen isotope composition different from that of the main group and thus require a separate parent body. Olivine from the Eagle Station pallasite also carries a paleomagnetic record; therefore pallasites from this group may have also formed by collision. Interestingly, the magnetization of the Eagle Station pallasite is multi-component and distinctly different from the main group. This signal potentially records a combination of a dynamo signal and a later shock heating event. Mesosiderites may represent a third parent body formed by impactor liquid FeNi metal injected into the crust of an asteroid. These observations suggest liquid metal intrusion from differentiated impactors may have

  2. Fast torsional waves and strong magnetic field within the Earth's core.

    Science.gov (United States)

    Gillet, Nicolas; Jault, Dominique; Canet, Elisabeth; Fournier, Alexandre

    2010-05-06

    The magnetic field inside the Earth's fluid and electrically conducting outer core cannot be directly probed. The root-mean-squared (r.m.s.) intensity for the resolved part of the radial magnetic field at the core-mantle boundary is 0.3 mT, but further assumptions are needed to infer the strength of the field inside the core. Recent diagnostics obtained from numerical geodynamo models indicate that the magnitude of the dipole field at the surface of a fluid dynamo is about ten times weaker than the r.m.s. field strength in its interior, which would yield an intensity of the order of several millitesla within the Earth's core. However, a 60-year signal found in the variation in the length of day has long been associated with magneto-hydrodynamic torsional waves carried by a much weaker internal field. According to these studies, the r.m.s. strength of the field in the cylindrical radial direction (calculated for all length scales) is only 0.2 mT, a figure even smaller than the r.m.s. strength of the large-scale (spherical harmonic degree n geodynamo models with studies of geostrophic motions in the Earth's core that rely on geomagnetic data. From an ensemble inversion of core flow models, we find a torsional wave recurring every six years, the angular momentum of which accounts well for both the phase and the amplitude of the six-year signal for change in length of day detected over the second half of the twentieth century. It takes about four years for the wave to propagate throughout the fluid outer core, and this travel time translates into a slowness for Alfvén waves that corresponds to a r.m.s. field strength in the cylindrical radial direction of approximately 2 mT. Assuming isotropy, this yields a r.m.s. field strength of 4 mT inside the Earth's core.

  3. A temperature-independent fibre-optic magnetic-field sensor using thin-core fibre tailored fibre Bragg grating

    Science.gov (United States)

    Tian, Qin; Feng, Zhongyao; Rong, Qiangzhou; Wan, Yun; Qiao, Xueguang; Hu, Manli; Yang, Hangzhou; Wang, Ruohui; Shao, Zhihua; Yang, Tingting

    2017-06-01

    A temperature-independent fibre-optic magnetic-field sensor is proposed and demonstrated experimentally. The device consists of a thin-core fibre (TCF) sandwiched in the upstream of a fibre Bragg grating (FBG). Because of the core-mismatch between the TCF and the single-mode fibre (SMF), the core mode is coupled to the cladding modes within the TCF cladding, and parts of them are recoupled back to the leading-in SMF by the downstream FBG. The cladding modes are sensitive to the ambient refractive index (RI), and therefore have the ability to respond to a RI change in the magnetic fluid determined by the ambient magnetic field. The intensities of the cladding-mode resonances are highly sensitive to the magnetic field change, while, in contrast, the resonance wavelengths always remain unchanged. This property can allow the sensor to act as a power-referenced reflection probe for magnetic field measurements.

  4. What does determine the sign of core in Magnetic Flux Rope structures of the Earth's magnetotail

    Directory of Open Access Journals (Sweden)

    D. V. Sarafopoulos

    2014-09-01

    Full Text Available This paper primarily examines the key factors being involved in precisely determining the sign of the core field in a magnetic flux rope (MFR like structure embedded in the tailward plasma flow associated with the Earth's magnetotail. Magnetic flux ropes are frequently detected by satellites moving smoothly northwards (upwards or southwards (downwards and crossing almost the whole plasma sheet; the sign of the rope's core is associated with the local tail's motion: If the tail is bending to an upward or downward direction, then the sign of the rope's core, being essentially an intense By deviation, will be positive or negative correspondingly. On the basis of this observational finding, a major question concerns the mechanism by which the tail's motion is dictated. The reconnection process acting in the tail will obviously produce symmetric structures of MFRs (with respect to the neutral sheet plane; therefore, the detected organized asymmetry may be an additional indication in the whole magnetotail' s dynamics. Moreover, we discuss the issue of the core's sign in cases without any significant magnetotail's motion. A model interpreting the diagnosed behavior is introduced: Once a tailward ion jet is produced in a thinned plasma sheet, it might form clockwise or counterclockwise ion vortices (i.e., loop-like ion currents providing the "magnetic core" with the appropriate sign. The crucial role of the interplanetary By deviation of the magnetic field (IMF is scrutinized and taken into account. The whole model is tested under the condition of long-lasting extraordinary events characterized by a persistent-intense By deviation with a duration up to 34 min. This work, based on Geotail single-satellite measurements, is not a statistical one; it is a first approach allowing the reconstruction of measurements in the whole range of the magnetotail's deflections, from negligible up to stronger significant magnetotail movements, and should be therefore

  5. Characterization of single-core magnetite nanoparticles for magnetic imaging by SQUID relaxometry.

    Science.gov (United States)

    Adolphi, Natalie L; Huber, Dale L; Bryant, Howard C; Monson, Todd C; Fegan, Danielle L; Lim, Jitkang; Trujillo, Jason E; Tessier, Trace E; Lovato, Debbie M; Butler, Kimberly S; Provencio, Paula P; Hathaway, Helen J; Majetich, Sara A; Larson, Richard S; Flynn, Edward R

    2010-10-07

    Optimizing the sensitivity of SQUID (superconducting quantum interference device) relaxometry for detecting cell-targeted magnetic nanoparticles for in vivo diagnostics requires nanoparticles with a narrow particle size distribution to ensure that the Néel relaxation times fall within the measurement timescale (50 ms-2 s, in this work). To determine the optimum particle size, single-core magnetite nanoparticles (with nominal average diameters 20, 25, 30 and 35 nm) were characterized by SQUID relaxometry, transmission electron microscopy, SQUID susceptometry, dynamic light scattering and zeta potential analysis. The SQUID relaxometry signal (detected magnetic moment/kg) from both the 25 nm and 30 nm particles was an improvement over previously studied multi-core particles. However, the detected moments were an order of magnitude lower than predicted based on a simple model that takes into account the measured size distributions (but neglects dipolar interactions and polydispersity of the anisotropy energy density), indicating that improved control of several different nanoparticle properties (size, shape and coating thickness) will be required to achieve the highest detection sensitivity. Antibody conjugation and cell incubation experiments show that single-core particles enable a higher detected moment per cell, but also demonstrate the need for improved surface treatments to mitigate aggregation and improve specificity.

  6. Characterization of single-core magnetite nanoparticles for magnetic imaging by SQUID relaxometry

    Energy Technology Data Exchange (ETDEWEB)

    Adolphi, Natalie L [Department of Biochemistry and Molecular Biology, University of New Mexico, Albuquerque, NM 87131 (United States); Huber, Dale L; Monson, Todd C; Provencio, Paula P [Sandia National Laboratories, P. O. Box 5800, Albuquerque, NM 87185 (United States); Bryant, Howard C; Fegan, Danielle L; Tessier, Trace E; Flynn, Edward R [Senior Scientific, LLC, 11109 Country Club NE, Albuquerque, NM 87111 (United States); Lim, JitKang; Majetich, Sara A [Department of Physics, Carnegie Mellon University, Pittsburgh, PA 15213 (United States); Trujillo, Jason E; Lovato, Debbie M; Butler, Kimberly S; Larson, Richard S [Department of Pathology, Cancer Research and Treatment Center, University of New Mexico, Albuquerque, NM 87131 (United States); Hathaway, Helen J, E-mail: NAdolphi@salud.unm.ed [Department of Cell Biology and Physiology, University of New Mexico, Albuquerque, NM 87131 (United States)

    2010-10-07

    Optimizing the sensitivity of SQUID (superconducting quantum interference device) relaxometry for detecting cell-targeted magnetic nanoparticles for in vivo diagnostics requires nanoparticles with a narrow particle size distribution to ensure that the Neel relaxation times fall within the measurement timescale (50 ms-2 s, in this work). To determine the optimum particle size, single-core magnetite nanoparticles (with nominal average diameters 20, 25, 30 and 35 nm) were characterized by SQUID relaxometry, transmission electron microscopy, SQUID susceptometry, dynamic light scattering and zeta potential analysis. The SQUID relaxometry signal (detected magnetic moment/kg) from both the 25 nm and 30 nm particles was an improvement over previously studied multi-core particles. However, the detected moments were an order of magnitude lower than predicted based on a simple model that takes into account the measured size distributions (but neglects dipolar interactions and polydispersity of the anisotropy energy density), indicating that improved control of several different nanoparticle properties (size, shape and coating thickness) will be required to achieve the highest detection sensitivity. Antibody conjugation and cell incubation experiments show that single-core particles enable a higher detected moment per cell, but also demonstrate the need for improved surface treatments to mitigate aggregation and improve specificity.

  7. Newly fabricated magnetic lanthanide oxides core-shell nanoparticles in phosphoproteomics.

    Science.gov (United States)

    Jabeen, Fahmida; Najam-Ul-Haq, Muhammad; Rainer, Matthias; Güzel, Yüksel; Huck, Christian W; Bonn, Guenther K

    2015-01-01

    Metal oxides show high selectivity and sensitivity toward mass spectrometry based enrichment strategies. Phosphopeptides/phosphoproteins enrichment from biological samples is cumbersome because of their low abundance. Phosphopeptides are of interest in enzymes and phosphorylation pathways which lead to the clinical links of a disease. Magnetic core-shell lanthanide oxide nanoparticles (Fe3O4@SiO2-La2O3 and Fe3O4@SiO2-Sm2O3) are fabricated, characterized by SEM, FTIR, and EDX and employed in the enrichment of phosphopeptides. The nanoparticles enrich phosphopeptides from casein variants, nonfat milk, egg yolk, human serum and HeLa cell extract. The materials and enrichment protocols are designed in a way that there are almost no nonspecific bindings. The selectivity is achieved up to 1:8500 using β-casein/BSA mixture and sensitivity down to 1 atto-mole. Batch-to-batch reproducibility is high with the reuse of core-shell nanoparticles up to four cycles. The enrichment followed by MALDI-MS analyses is carried out for the identification of phosphopeptides from serum digest and HeLa cell extract. Characteristic phosphopeptides of phosphoproteins are identified from human serum after the enrichment, which have the diagnostic potential toward prostate cancer. Thus, the lanthanide based magnetic core-shell materials offer a highly selective and sensitive workflow in phosphoproteomics.

  8. Instability of quark matter core in a compact newborn neutron star with moderately strong magnetic field

    Indian Academy of Sciences (India)

    Sutapa Ghosh; Somenath Chakrabarty

    2003-05-01

    It is explicitly shown that if phase transition occurs at the core of a newborn neutron star with moderately strong magnetic field strength, which populates only the electron’s Landau levels, then in the -equilibrium condition, the quark core is energetically much more unstable than the neutron matter of identical physical condition.

  9. THE EVOLUTION AND IMPACTS OF MAGNETOROTATIONAL INSTABILITY IN MAGNETIZED CORE-COLLAPSE SUPERNOVAE

    Energy Technology Data Exchange (ETDEWEB)

    Sawai, Hidetomo [Research Organization for Information Science and Technology, Kobe, Hyogo 650-0047 (Japan); Yamada, Shoichi, E-mail: hsawai@rist.or.jp [Waseda University, Shinjuku, Tokyo 169-8555 (Japan)

    2016-02-01

    We carried out two-dimensional axisymmetric MHD simulations of core-collapse supernovae for rapidly rotating magnetized progenitors. By changing both the strength of the magnetic field and the spatial resolution, the evolution of the magnetorotational instability (MRI) and its impacts upon the dynamics are investigated. We found that the MRI greatly amplifies the seed magnetic fields in the regime where the buoyant mode, not the Alfvén mode, plays a primary role in the exponential growth phase. The MRI indeed has a powerful impact on the supernova dynamics. It makes the shock expansion faster and the explosion more energetic, with some models being accompanied by the collimated jet formations. These effects, however, are not made by the magnetic pressure except for the collimated jet formations. The angular momentum transfer induced by the MRI causes the expansion of the heating region, by which the accreting matter gain additional time to be heated by neutrinos. The MRI also drifts low-Y{sub p} matter from deep inside of the core to the heating region, which makes the net neutrino heating rate larger by the reduction of the cooling due to the electron capture. These two effects enhance the efficiency of the neutrino heating, which is found to be the key to boosting the explosion. Indeed, we found that our models explode far more weakly when the net neutrino heating is switched off. The contribution of the neutrino heating to the explosion energy could reach 60% even in the case of strongest magnetic field in the current simulations.

  10. Magnetic processes in a collapsing dense core. II Fragmentation. Is there a fragmentation crisis ?

    CERN Document Server

    Hennebelle, P

    2007-01-01

    Abridged. A large fraction of stars are found in binary systems. It is therefore important for our understanding of the star formation process, to investigate the fragmentation of dense molecular cores. We study the influence of the magnetic field, ideally coupled to the gas, on the fragmentation in multiple systems of collapsing cores. We present high resolution numerical simulations performed with the RAMSES MHD code starting with a uniform sphere in solid body rotation and a uniform magnetic field parallel to the rotation axis. We pay particular attention to the strength of the magnetic field and interpret the results using the analysis presented in a companion paper. The results depend much on the amplitude, $A$, of the perturbations seeded initially. For a low amplitude, $A=0.1$, we find that for values of the mass-to-flux over critical mass-to-flux ratio, $\\mu$, as high as $\\mu = 20$, the centrifugally supported disk which fragments in the hydrodynamical case, is stabilized and remains axisymmetric. Det...

  11. On the maximum magnetic field amplification by the magnetorotational instability in core-collapse supernovae

    Science.gov (United States)

    Rembiasz, T.; Guilet, J.; Obergaulinger, M.; Cerdá-Durán, P.; Aloy, M. A.; Müller, E.

    2016-08-01

    Whether the magnetorotational instability (MRI) can amplify initially weak magnetic fields to dynamically relevant strengths in core-collapse supernovae is still a matter of active scientific debate. Recent numerical studies have shown that the first phase of MRI growth dominated by channel flows is terminated by parasitic instabilities of the Kelvin-Helmholtz type that disrupt MRI channel flows and quench further magnetic field growth. However, it remains to be properly assessed by what factor the initial magnetic field can be amplified and how it depends on the initial field strength and the amplitude of the perturbations. Different termination criteria leading to different estimates of the amplification factor were proposed within the parasitic model. To determine the amplification factor and test which criterion is a better predictor of the MRI termination, we perform three-dimensional shearing-disc and shearing-box simulations of a region close to the surface of a differentially rotating protoneutron star in non-ideal magnetohydrodynamics with two different numerical codes. We find that independently of the initial magnetic field strength, the MRI channel modes can amplify the magnetic field by, at most, a factor of 100. Under the conditions found in protoneutron stars, a more realistic value for the magnetic field amplification is of the order of 10. This severely limits the role of the MRI channel modes as an agent amplifying the magnetic field in protoneutron stars starting from small seed fields. A further amplification should therefore rely on other physical processes, such as for example an MRI-driven turbulent dynamo.

  12. Determination of Magnetic Parameters of Maghemite (γ-Fe2O3) Core-Shell Nanoparticles from Nonlinear Magnetic Susceptibility Measurements

    Science.gov (United States)

    Syvorotka, Ihor I.; Pavlyk, Lyubomyr P.; Ubizskii, Sergii B.; Buryy, Oleg A.; Savytskyy, Hrygoriy V.; Mitina, Nataliya Y.; Zaichenko, Oleksandr S.

    2017-04-01

    Method of determining of magnetic moment and size from measurements of dependence of the nonlinear magnetic susceptibility upon magnetic field is proposed, substantiated and tested for superparamagnetic nanoparticles (SPNP) of the "magnetic core-polymer shell" type which are widely used in biomedical technologies. The model of the induction response of the SPNP ensemble on the combined action of the magnetic harmonic excitation field and permanent bias field is built, and the analysis of possible ways to determine the magnetic moment and size of the nanoparticles as well as the parameters of the distribution of these variables is performed. Experimental verification of the proposed method was implemented on samples of SPNP with maghemite core in dry form as well as in colloidal systems. The results have been compared with the data obtained by other methods. Advantages of the proposed method are analyzed and discussed, particularly in terms of its suitability for routine express testing of SPNP for biomedical technology.

  13. Magnetic core-shell fluorescent pH ratiometric nanosensor using a Stoeber coating method

    Energy Technology Data Exchange (ETDEWEB)

    Lapresta-Fernandez, A., E-mail: lapresta@ugr.es [Institute of Physical Chemistry, Friedrich-Schiller-University Jena, Lessingstrasse 10, 07743 Jena (Germany); Instituto de Ciencia de Materiales de Sevilla, centro mixto CSIC-Univ. Sevilla, Avda. Americo Vespucio 49, 41092 Sevilla (Spain); Doussineau, T. [Institute of Physical Chemistry, Friedrich-Schiller-University Jena, Lessingstrasse 10, 07743 Jena (Germany); Universite Lyon 1, CNRS, UMR 5579, LASIM, F-69622 Villeurbanne (France); Moro, A.J. [Institute of Physical Chemistry, Friedrich-Schiller-University Jena, Lessingstrasse 10, 07743 Jena (Germany); REQUIMTE, Departamento de Quimica, Faculdade de Ciencias e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica (Portugal); Dutz, S. [Institute of Photonic Technology, Department of Nano Biophotonics, Jena (Germany); Steiniger, F. [Center for Electron Microscopy of the Medical Faculty, Jena (Germany); Mohr, G.J. [Fraunhofer Research Institution for Modular Solid State Technologies, Department of Polytronic Systems, Workgroup Sensor Materials, Josef-Engert-Strasse 13, D-93053 Regensburg (Germany)

    2011-11-30

    Highlights: Black-Right-Pointing-Pointer Architecture combination of magnetic core with two fluorescence silica shells. Black-Right-Pointing-Pointer Both shells properly functionalized which develops ratiometric pH measurements. Black-Right-Pointing-Pointer Reference dye does not change significantly ({approx}1.9%) by modifying the pH. Black-Right-Pointing-Pointer Sensitivity range between 2.0% and 4.9% and a few seconds of response time. Black-Right-Pointing-Pointer One month stability with a signal variation of 4.3%. - Abstract: We describe the use of a modified Stoeber method for coating maghemite ({gamma}-Fe{sub 2}O{sub 3}) nanocrystals with silica shells in order to built magnetic fluorescent sensor nanoparticles in the 50-70 nm diameter range. In detail, the magnetic cores were coated by two successive silica shells embedding two fluorophores (two different silylated dye derivatives), which allows for ratiometric pH-measurements in the pH range 5-8. Silica coated magnetic nanoparticles were prepared using maghemite nanocrystals as cores (5-10 nm in diameter) coated by tetraethoxyorthosilicate via hydrolysis/condensation in ethanol, catalyzed by ammonia. In the inner shell was covalently attached a sulforhodamine B, which was used as a reference dye; while a pH-sensitive fluorescein was incorporated into the outer shell. Once synthesized, the particles were characterized in terms of morphology, size, composition and magnetization, using dynamic light scattering (DLS), transmission electron microscopy (TEM), X-ray diffraction (XRD) and vibrating sample magnetometry (VSM). TEM analysis showed the nanoparticles to be very uniform in size. Wide-angle X-ray diffractograms showed, for uncoated as well as coated nanoparticles, typical peaks for the spinel structure of maghemite at the same diffraction angle, with no structural changes after coating. When using VSM, we obtained the magnetization curves of the resulting nanoparticles and the typical magnetization

  14. Relationship between chemical composition and magnetic susceptibility in sediment cores from Central Indian Ocean Basin

    Indian Academy of Sciences (India)

    J N Pattan; G Parthiban; V K Banakar; A Tomer; M Kulkarni

    2008-04-01

    Three sediment cores in a north–south transect (3°N to 13°S) from different sediment types of the Central Indian Ocean Basin (CIOB) are studied to understand the possible relationship between magnetic susceptibility () and Al, Fe, Ti and Mn concentrations. The calcareous ooze core exhibit lowest (12.32 × 10-7m3 kg−1), Al (2.84%), Fe (1.63%) and Ti (0.14%), terrigenous clay core with moderate (29.9 × 10-7 m3 kg−1) but highest Al (6.84%), Fe (5.20%) and Ti (0.44%), and siliceous ooze core with highest (38.06 × 10-7 m3 kg−1) but moderate Al (4.49%), Fe (2.80%) and Ti (0.19%) contents. The distribution of and detrital proxy elements (Al, Fe, and Ti) are identical in both calcareous and siliceous ooze. Interestingly, in terrigenous core, the behaviour of is identical to only Ti content but not with Al and Fe suggesting possibility of Al and Fe having a non-detrital source. The occurrence of phillipsite in terrigenous clay is evident by the Al-K scatter plot where trend line intersects K axis at more than 50% of total K suggesting excess K in the form of phillipsite. Therefore, the presence of phillipsite might be responsible for negative correlation between and Al ( = −0.52). In siliceous ooze the strong positive correlations among , Alexc and Feexc suggest the presence of authigenic Fe-rich smectite. High Mn content (0.5%) probably in the form of manganese micronodules is also contributing to in both calcareous and siliceous ooze but not in the terrigenous core where mean Mn content (0.1%) is similar to crustal abundance. Thus, systematically records the terrigenous variation in both the biogenic sediments but in terrigenous clay it indirectly suggests the presence of authigenic minerals.

  15. Core/shell magnetic mesoporous silica nanoparticles with radially oriented wide mesopores

    Directory of Open Access Journals (Sweden)

    Nikola Ž. Knežević

    2014-06-01

    Full Text Available Core/shell nanoparticles, containing magnetic iron-oxide (maghemite core and mesoporous shell with radial porous structure, were prepared by dispersing magnetite nanoparticles and adding tetraethylorthosilicate to a basic aqueous solution containing structure-templating cetyltrimethylammonium bromide and a pore-swelling mesithylene. The material is characterized by SEM and TEM imaging, nitrogen sorption and powder X-ray diffraction. Distinctive features of the prepared material are its high surface area (959 m2/g, wide average pore diameter (12.4 nm and large pore volume (2.3 cm3/g. The material exhibits radial pore structure and the high angle XRD pattern characteristic for maghemite nanoparticles, which are obtained upon calcination of the magnetite-containing material. The observed properties of the prepared material may render the material applicable in separation, drug delivery, sensing and heterogeneous catalysis.

  16. Towards magnetic sounding of the Earth's core by an adjoint method

    Science.gov (United States)

    Li, K.; Jackson, A.; Livermore, P. W.

    2013-12-01

    Earth's magnetic field is generated and sustained by the so called geodynamo system in the core. Measurements of the geomagnetic field taken at the surface, downwards continued through the electrically insulating mantle to the core-mantle boundary (CMB), provide important constraints on the time evolution of the velocity, magnetic field and temperature anomaly in the fluid outer core. The aim of any study in data assimilation applied to the Earth's core is to produce a time-dependent model consistent with these observations [1]. Snapshots of these ``tuned" models provide a window through which the inner workings of the Earth's core, usually hidden from view, can be probed. We apply a variational data assimilation framework to an inertia-free magnetohydrodynamic system (MHD) [2]. Such a model is close to magnetostrophic balance [3], to which we have added viscosity to the dominant forces of Coriolis, pressure, Lorentz and buoyancy, believed to be a good approximation of the Earth's dynamo in the convective time scale. We chose to study the MHD system driven by a static temperature anomaly to mimic the actual inner working of Earth's dynamo system, avoiding at this stage the further complication of solving for the time dependent temperature field. At the heart of the models is a time-dependent magnetic field to which the core-flow is enslaved. In previous work we laid the foundation of the adjoint methodology, applied to a subset of the full equations [4]. As an intermediate step towards our ultimate vision of applying the techniques to a fully dynamic mode of the Earth's core tuned to geomagnetic observations, we present the intermediate step of applying the adjoint technique to the inertia-free Navier-Stokes equation in continuous form. We use synthetic observations derived from evolving a geophysically-reasonable magnetic field profile as the initial condition of our MHD system. Based on our study, we also propose several different strategies for accurately

  17. Hierarchically functionalized magnetic core/multishell particles and their postsynthetic conversion to polymer capsules.

    Science.gov (United States)

    Schmitt, Sophia; Silvestre, Martin; Tsotsalas, Manuel; Winkler, Anna-Lena; Shahnas, Artak; Grosjean, Sylvain; Laye, Fabrice; Gliemann, Hartmut; Lahann, Joerg; Bräse, Stefan; Franzreb, Matthias; Wöll, Christof

    2015-01-01

    The controlled synthesis of hierarchically functionalized core/multishell particles is highly desirable for applications in medicine, catalysis, and separation. Here, we describe the synthesis of hierarchically structured metal-organic framework multishells around magnetic core particles (magMOFs) via layer-by-layer (LbL) synthesis. The LbL deposition enables the design of multishell systems, where each MOF shell can be modified to install different functions. Here, we used this approach to create controlled release capsules, in which the inner shell serves as a reservoir and the outer shell serves as a membrane after postsynthetic conversion of the MOF structure to a polymer network. These capsules enable the controlled release of loaded dye molecules, depending on the surrounding media.

  18. High frequency, high temperature specific core loss and dynamic B-H hysteresis loop characteristics of soft magnetic alloys

    Science.gov (United States)

    Wieserman, W. R.; Schwarze, G. E.; Niedra, J. M.

    1990-01-01

    Limited experimental data exists for the specific core loss and dynamic B-H loops for soft magnetic materials for the combined conditions of high frequency and high temperature. This experimental study investigates the specific core loss and dynamic B-H loop characteristics of Supermalloy and Metglas 2605SC over the frequency range of 1 to 50 kHz and temperature range of 23 to 300 C under sinusoidal voltage excitation. The experimental setup used to conduct the investigation is described. The effects of the maximum magnetic flux density, frequency, and temperature on the specific core loss and on the size and shape of the B-H loops are examined.

  19. Dual spiral sandwiched magnetic thin film inductor using Fe-Hf-N soft magnetic films as a magnetic core

    Energy Technology Data Exchange (ETDEWEB)

    Kim, K.H.; Yoo, D.W.; Jeong, J.H.; Kim, J.; Han, S.H. E-mail: sukhan@kist.re.kr; Kim, H.J

    2002-02-01

    Dual spiral sandwiched magnetic thin film inductors are fabricated using as-deposited Fe-Hf-N soft magnetic thin films. The hard axis of the magnetic film is aligned transverse to the direction of coil conductor current, which is expected to result in high inductance values as well as excellent frequency response. The inductance, Q factor and resistance are measured using impedance analyzer from 1 to 10 MHz. The inductance of fabricated thin film inductors are obtained within the range of 1.1-1.5 {mu}H. Also, the quality factor and coil resistance is obtained in the range of 3-38 at 8 MHz and 1-2.5 {omega}, respectively.

  20. Modeling Overlapping Laminations in Magnetic Core Materials Using 2-D Finite-Element Analysis

    DEFF Research Database (Denmark)

    Jensen, Bogi Bech; Guest, Emerson David; Mecrow, Barrie C.

    2015-01-01

    and a composite material is created, which has the same magnetization characteristic. The benefit of this technique is that it allows a designer to perform design and optimization of magnetic cores with overlapped laminations using a 2-D FE model rather than a 3-D FE model, which saves modeling and simulation...... time. The modeling technique is verified experimentally by creating a composite material of a lap joint with a 3-mm overlapping region and using it in a 2-D FE model of a ring sample made up of a stack of 20 laminations. The B-H curve of the simulated ring sample is compared with the B-H curve obtained...

  1. Cloud core collapse and the role of turbulent magnetic reconnection diffusion

    CERN Document Server

    Leão, M R M; Santos-Lima, R; Lazarian, A

    2012-01-01

    For a molecular cloud clump to form stars some transport of magnetic flux is required from the denser, inner regions to the outer regions of the cloud, otherwise this can prevent the gravitational collapse. Fast magnetic reconnection which takes place in the presence of turbulence can induce a process of reconnection diffusion. This paper continues our numerical study of this process and its implications. In particular, extending our earlier studies of reconnection diffusion in cylindrical clouds we consider more realistic clouds with spherical gravitational potentials (from embedded stars) and also account for the effects of the gas self-gravity. We demonstrate that within our setup reconnection diffusion takes place. We have also derived the conditions under which reconnection diffusion becomes efficient enough to make an initially subcritical cloud clump to become supercritical and collapse. Our results indicate that the formation of a supercritical core is regulated by a complex interplay between gravity,...

  2. Local magnetic moments in iron and nickel at ambient and Earth's core conditions

    Science.gov (United States)

    Hausoel, A.; Karolak, M.; Şaşɩoğlu, E.; Lichtenstein, A.; Held, K.; Katanin, A.; Toschi, A.; Sangiovanni, G.

    2017-07-01

    Some Bravais lattices have a particular geometry that can slow down the motion of Bloch electrons by pre-localization due to the band-structure properties. Another known source of electronic localization in solids is the Coulomb repulsion in partially filled d or f orbitals, which leads to the formation of local magnetic moments. The combination of these two effects is usually considered of little relevance to strongly correlated materials. Here we show that it represents, instead, the underlying physical mechanism in two of the most important ferromagnets: nickel and iron. In nickel, the van Hove singularity has an unexpected impact on the magnetism. As a result, the electron-electron scattering rate is linear in temperature, in violation of the conventional Landau theory of metals. This is true even at Earth's core pressures, at which iron is instead a good Fermi liquid. The importance of nickel in models of geomagnetism may have therefore to be reconsidered.

  3. Spectroscopic characterization of magnetic Fe3O4@Au core shell nanoparticles

    Science.gov (United States)

    Fouad, Dina M.; El-Said, Waleed A.; Mohamed, Mona B.

    2015-04-01

    The magnetic nanoparticles iron oxide (Fe3O4) nanoparticles and iron oxide/gold core-shell (Fe3O4/Au) nanoparticles were synthesized and their catalytic photo-degradation activity towards malathion as example of organophosphorus pesticides were reported. Iron oxide (Fe3O4) magnetic nanoparticle was successfully prepared through co-precipitation method by the reduction of ferric chloride (FeCl3) using ascorbic acid. The morphology of the prepared nanoparticles was characterized by the TEM and XRD (X-ray diffraction) techniques. Degradation of 10 ppm of malathion in the presence of these nanoparticles under UV radiation was monitored using (HPLC) and UV-visible spectra. Fe3O4/Au nanoparticles showed higher efficiency in photo-degradation of malathion than Fe3O4 ones.

  4. Design and characterization of antimicrobial usnic acid loaded-core/shell magnetic nanoparticles.

    Science.gov (United States)

    Taresco, Vincenzo; Francolini, Iolanda; Padella, Franco; Bellusci, Mariangela; Boni, Adriano; Innocenti, Claudia; Martinelli, Andrea; D'Ilario, Lucio; Piozzi, Antonella

    2015-01-01

    The application of magnetic nanoparticles (MNPs) in medicine is considered much promising especially because they can be handled and directed to specific body sites by external magnetic fields. MNPs have been investigated in magnetic resonance imaging, hyperthermia and drug targeting. In this study, properly functionalized core/shell MNPs with antimicrobial properties were developed to be used for the prevention and treatment of medical device-related infections. Particularly, surface-engineered manganese iron oxide MNPs, produced by a micro-emulsion method, were coated with two different polymers and loaded with usnic acid (UA), a dibenzofuran natural extract possessing antimicrobial activity. Between the two polymer coatings, the one based on an intrinsically antimicrobial cationic polyacrylamide (pAcDED) resulted to be able to provide MNPs with proper magnetic properties and basic groups for UA loading. Thanks to the establishment of acid-base interactions, pAcDED-coated MNPs were able to load and release significant drug amounts resulting in good antimicrobial properties versus Staphylococcus epidermidis (MIC = 0.1 mg/mL). The use of pAcDED having intrinsic antimicrobial activity as MNP coating in combination with UA likely contributed to obtain an enhanced antimicrobial effect. The developed drug-loaded MNPs could be injected in the patient soon after device implantation to prevent biofilm formation, or, later, in presence of signs of infection to treat the biofilm grown on the device surfaces.

  5. The Evolution and Impacts of Magnetorotational Instability in Magnetized Core-Collapse Supernovae

    CERN Document Server

    Sawai, Hidetomo

    2015-01-01

    We carried out 2D-axisymmetric MHD simulations of core-collapse supernovae for rapidly-rotating magnetized progenitors. By changing both the strength of the magnetic field and the spatial resolution, the evolution of the magnetorotational instability (MRI) and its impacts upon the dynamics are investigated. We found that the MRI greatly amplifies the seed magnetic fields in the regime where not the Alfv\\'en mode but the buoyant mode plays a primary role in the exponential growth phase. The MRI indeed has a powerful impact on the supernova dynamics. It makes the shock expansion faster and the explosion more energetic, with some models being accompanied by the collimated-jet formations. These effects, however, are not made by the magnetic pressure except for the collimated-jet formations. The angular momentum transfer induced by the MRI causes the expansion of the heating region, by which the accreting matter gain an additional time to be heated by neutrinos. The MRI also drifts low-$Y_p$ matter from the deep i...

  6. Magnetic records of Core MD77-181 in the Bay of Bengal and their paleoenvironmental implications

    Institute of Scientific and Technical Information of China (English)

    LI Haiyan; ZHANG Shihong; FANG Nianqiao; WANG Hongqiang

    2006-01-01

    High-resolution environmental magnetic measurements were carried out on Core MD77-181 in the Bay of Bengal, including magnetic susceptibility, anhysteretic remanent magnetization, isothermal remanent magnetization of all samples, and temperature-dependence of magnetic susceptibilities and magnetic hysteresis parameters of representative samples. The results suggest that (1) the magnetic mineral assemblage of the upper 9.82 m sediments (corresponding to the last 160 ka) is dominated by pseudo-single domain magnetite, with more abundant coarse grains in glacial periods than in interglacial periods; (2) the uppermost 6.50 m of sediments (corresponding to the last 70 ka) shows significant temporal variations in grain sizes of magnetic minerals, possibly reflecting the teleconnection between variations of the Indian summer monsoon and rapid cold events of the North Atlantic (Heinrich events); (3) the sediments below 9.82 m are dominated by paramagnetic minerals (probably including pyrites), suggesting reductive diagenesis. The magnetic records of Core MD77-181 are comparable to those of Core MD77-180 in the Bay of Bengal, and ODP Hole 722B in the Arabian Sea. This study suggests that the paleoceanographic event at ~160 ka significantly changed the redox state of the northern Indian Ocean, from a reductive environment before the event to an oxic or suboxic environment after the event.

  7. Magnetoelastoelectric coupling in core-shell nanoparticles enabling directional and mode-selective magnetic control of THz beam propagation.

    Science.gov (United States)

    Dutta, Moumita; Natarajan, Kamaraju; Betal, Soutik; Prasankumar, Rohit P; Bhalla, Amar S; Guo, Ruyan

    2017-09-14

    Magnetoelastoelectric coupling in an engineered biphasic multiferroic nanocomposite enables a novel magnetic field direction-defined propagation control of terahertz (THz) waves. These core-shell nanoparticles are comprised of a ferromagnetic cobalt ferrite core and a ferroelectric barium titanate shell. An assembly of these nanoparticles, when operated in external magnetic fields, exhibits a controllable amplitude modulation when the magnetic field is applied antiparallel to the THz wave propagation direction; yet the same assembly displays an additional phase modulation when the magnetic field is applied along the propagation direction. While field-induced magnetostriction of the core leads to amplitude modulation, phase modulation is a result of stress-mediated piezoelectricity of the outer ferroelectric shell.

  8. Collapse and Fragmentation of Magnetic Molecular Cloud Cores with the Enzo AMR MHD Code. I. Uniform Density Sphere

    CERN Document Server

    Boss, Alan P

    2013-01-01

    Magnetic fields are important contributers to the dynamics of collapsing molecular cloud cores, and can have a major effect on whether collapse results in a single protostar or fragmentation into a binary or multiple protostar system. New models are presented of the collapse of magnetic cloud cores using the adaptive mesh refinement (AMR) code Enzo2.0. The code was used to calculate the ideal magnetohydrodynamics (MHD) of initially spherical, uniform density and rotation clouds with density perturbations, i.e., the Boss and Bodenheimer (1979) standard isothermal test case for three dimensional (3D) hydrodynamics (HD) codes. After first verifying that Enzo reproduces the binary fragmentation expected for the non-magnetic test case, a large set of models was computed with varied initial magnetic field strengths and directions with respect to the cloud core axis of rotation (parallel or perpendicular), density perturbation amplitudes, and equations of state. Three significantly different outcomes resulted: (1) c...

  9. A DETERMINATION OF THE FLUX DENSITY IN CORE OF DISTRIBUTION TRANSFORMERS, WHAT BUILT WITH THE COMMON USING OF GRAIN AND NON GRAIN ORIENTED MAGNETIC STEELS

    Directory of Open Access Journals (Sweden)

    I.V. Pentegov

    2015-12-01

    Full Text Available Purpose. The development of calculation method to determinate the flux densities in different parts of the magnetic cores of distribution transformers, what built from different types magnetic steel (mixed core. Methodology. The method is based on the scientific positions of Theoretical Electrical Engineering – the theory of the electromagnetic field in nonlinear mediums to determine the distribution of magnetic flux in mixed core of transformer, what are using different types of steel what have the different magnetic properties. Results. The developed method gives possible to make calculation of the flux density and influence of skin effect in different parts of the magnetic cores of distribution transformer, where are used mix of grain oriented (GO and non grain oriented (NGO steels. Was determinate the general basic conditions for the calculation of flux density in the laminations from grain and non grain oriented steels of the magnetic core: the strength of magnetic field for the laminations of particular part of mixed core is the same; the sum of the magnetic fluxes in GO and NGO steels in particular part of mixed core is equal with the designed magnetic flux in this part of mixed core. Discover, the magnetic flux in mixed core of the transformer has specific distribution between magnetic steels. The flux density is higher in laminations from GO steel and smaller in laminations from the NGO steel. That is happened because for magnetic flux is easier pass through laminations from GO steel, what has better magnetic conductance than laminations from NGO steel. Originality. The common using of different types of magnetic steels in cores for distribution transformers gives possibility to make design of transformer with low level of no load losses, high efficiency and with optimal cost. Practical value. The determination of the flux density in different parts of magnetic core with GO and NGO steels gives possibility make accurate calculation of

  10. Ribbon thickness dependence of the Magnetic Alloy core characteristics in the accelerating frequency region of the J-PARC synchrotrons

    Science.gov (United States)

    Nomura, M.; Shimada, T.; Tamura, F.; Yamamoto, M.; Hara, K.; Hasegawa, K.; Ohmori, C.; Takata, K.; Toda, M.; Yoshii, M.; Schnase, A.

    2014-06-01

    We employ Magnetic Alloy (MA) core loaded RF cavities for the J-PARC synchrotrons to achieve a high field gradient. The MA core has a laminated structure of 18 μm thick ribbon layers. We have been developing high shunt impedance MA cores to prepare for an increase of beam power. At low frequencies, it is well known that the eddy current loss in the ribbon is proportional to the square of the ribbon thickness. The MA core shunt impedance can be increased by using thinner ribbons. On the other hand, at high frequencies, the MA core magnetic characteristics are largely different from low frequencies. Using thinner ribbons might be effective to increase the MA core shunt impedance in the accelerating frequency region of the J-PARC synchrotrons. We reviewed the theoretical calculations of the ribbon thickness dependence of the MA core magnetic characteristics and we derived the ribbon thickness dependence from measured data. The measured data show that the MA core shunt impedance is inversely proportional to the ribbon thickness in the accelerating frequency region of the J-PARC synchrotrons, which is consistent with our calculations.

  11. Induced Core Formation Time in Subcritical Magnetic Clouds by Large-Scale Trans-Alfv\\'enic Flows

    CERN Document Server

    Kudoh, Takahiro

    2014-01-01

    We clarify the mechanism of accelerated core formation by large-scale nonlinear flows in subcritical magnetic clouds by finding a semi-analytical formula for the core formation time and describing the physical processes that lead to them. Recent numerical simulations show that nonlinear flows induce rapid ambipolar diffusion that leads to localized supercritical regions that can collapse. Here, we employ non-ideal magnetohydrodynamic simulations including ambipolar diffusion for gravitationally stratified sheets threaded by vertical magnetic fields. One of the horizontal dimensions is eliminated, resulting in a simpler two-dimensional simulation that can clarify the basic process of accelerated core formation. A parameter study of simulations shows that the core formation time is inversely proportional to the square of the flow speed when the flow speed is greater than the Alfv\\'en speed. We find a semi-analytical formula that explains this numerical result. The formula also predicts that the core formation t...

  12. Reaching the Chu Lower Bound on Q With Magnetic Dipole Antennas Using a Magnetic-Coated PEC Core

    DEFF Research Database (Denmark)

    Kim, Oleksiy S.; Breinbjerg, Olav

    2011-01-01

    We analytically solve the radiation problem for a spherical magnetic dipole antenna with a material-coated perfectly electrically conducting core. Using the closed-form expressions derived for the internal and external stored energies as well as for the radiation quality factor $Q$, we determine...... the optimal geometrical and material parameters of the antenna. We show that the optimal permeability of the coating increases as the coating becomes thinner; as a result, the energy stored in it and the radiation quality factor $Q$ reduce. In the limit of an infinitely thin coating, the optimal permeability...... tends to infinity, the internal stored energy vanishes, and the $Q$ reaches the Chu lower bound, irrespective of the antenna electrical size $ka$ and permittivity of the coating....

  13. Diagenetic effects on magnetic minerals in a Holocene lacustrine sediment core from Huguangyan maar lake, southeast China

    Science.gov (United States)

    Wu, Xudong; Wang, Yong; Bian, Liu; Shen, Ji

    2016-09-01

    Post-depositional reductive diagenesis usually results in partial or entire cleansing of the pristine palaeomagnetic signal, therefore, its intensity is important to be assessed for sediments that are in the purpose of retrieving palaeomagnetic information. Grain size, rock magnetic and geochemical studies on the entire core, along with scanning electron microscope observations and X-ray diffraction analyses for representative samples were carried out on a Holocene sediment core retrieved from the deep water part of Huguangyan maar lake (HGY), southeast China. The pristine magnetic mineral assemblage of the studied core is domianted by superparamagnetic (SP) and stable single domain titanomagnetite, and high coercivity minerals are not detectable. Based on down-core variations of the average grain size (MZ), total organic carbon (TOC), detrital elements (Al, Ti, Fe and Mn) and the concentration and mineralogy of magnetic minerals, the studied core could be divided into three subsections. The uppermost subsection is the least affected by diagenesis, with detrital titanomagnetite as the dominant magnetic mineral. This is owing to low TOC contents, but high detrital input generated by weak Asian summer monsoon intensity during the late Holocene. The intermediate subsection shows down-core progressively enhanced dissolution of detrital titanomagnetite, and concomitant formation of authigenic pyrite and siderite, which indicates down-core progressively enhanced diagenesis generated by down-core progressive increasing TOC content, but decreasing detrital input as the result of down-core progressively strengthened Asian summer monsoon intensity. The pristine magnetic mineral assemblage has been profoundly modified in the lowermost subsection. At certain positions of the lowermost subsection, detrital titanomagnetite has been even completely dissolved via diagenesis, giving place to authigenic pyrite and siderite. High TOC content, but low detrital input generated from

  14. Shape-dependent exchange bias effect in magnetic nanoparticles with core-shell morphology

    Science.gov (United States)

    Dimitriadis, V.; Kechrakos, D.; Chubykalo-Fesenko, O.; Tsiantos, V.

    2015-08-01

    We study the low-temperature isothermal magnetic hysteresis of cubical and spherical nanoparticles with ferromagnetic-core/antiferromagnetic-shell morphology, in order to elucidate the sensitivity of the exchange bias effect to the shape of the particles and the structural imperfections at the core-shell interface. We model the magnetic structure using a classical Heisenberg Hamiltonian with uniaxial anisotropy and simulate the hysteresis loop using the metropolis Monte Carlo algorithm. For nanoparticles with geometrically sharp interfaces, we find that cubes exhibit a higher coercivity and lower exchange bias field than spheres of the same size. With increasing interface roughness, the shape dependence of the characteristic fields gradually decays, and eventually, the distinction between cubical and spherical particles is lost for moderately rough interfaces. The sensitivity of the exchange bias field to the microstructural details of the interface is quantified by a scaling factor (b ) relating the bias field to the net moment of the antiferromagnetic shell (Heb=b MAF+Ho) . Cubical particles exhibit a lower sensitivity to the dispersed values of the net interfacial moment.

  15. Synthesis, structural characterization and magnetic properties of Fe/Pt core-shell nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Pisane, K. L.; Singh, Sobhit; Seehra, M. S., E-mail: mseehra@wvu.edu [Department of Physics and Astronomy, West Virginia University, Morgantown, West Virginia 26506-6315 (United States)

    2015-05-07

    Structural and magnetic properties of Fe/Pt core-shell nanostructure prepared by a sequential reduction process are reported. Transmission electron microscopy shows nearly spherical particles fitting a lognormal size distribution with D{sub o} = 3.0 nm and distribution width λ{sub D} = 0.31. In x-ray diffraction, Bragg lines only from the Pt shell are clearly identified with line-widths yielding crystallite size = 3.1 nm. Measurements of magnetization M vs. T (2 K–350 K) in magnetic fields up to 90 kOe show a blocking temperature T{sub B} = 13 K below which hysteresis loops are observed with coercivity H{sub C} increasing with decreasing T reaching H{sub C} = 750 Oe at 2 K. Temperature dependence of the ac susceptibilities at frequencies f{sub m} = 10 Hz–5 kHz is measured to determine the change in T{sub B} with f{sub m} using the Vogel-Fulcher law. This analysis shows the presence of significant interparticle interaction, the Neel-Brown relaxation frequency f{sub o} = 5.3 × 10{sup 10 }Hz and anisotropy constant K{sub a} = 3.6 × 10{sup 6 }ergs/cm{sup 3}. A fit of the M vs. H data up to H = 90 kOe for T > T{sub B} to the modified Langevin function taking particle size distribution into account yields magnetic moment per particle consistent with the proposed core-shell structure; Fe core of 2.2 nm diameter and Pt shell of 0.4 nm thickness.

  16. Mean-field and linear regime approach to magnetic hyperthermia of core-shell nanoparticles: can tiny nanostructures fight cancer?

    Science.gov (United States)

    Carrião, Marcus S.; Bakuzis, Andris F.

    2016-04-01

    The phenomenon of heat dissipation by magnetic materials interacting with an alternating magnetic field, known as magnetic hyperthermia, is an emergent and promising therapy for many diseases, mainly cancer. Here, a magnetic hyperthermia model for core-shell nanoparticles is developed. The theoretical calculation, different from previous models, highlights the importance of heterogeneity by identifying the role of surface and core spins on nanoparticle heat generation. We found that the most efficient nanoparticles should be obtained by selecting materials to reduce the surface to core damping factor ratio, increasing the interface exchange parameter and tuning the surface to core anisotropy ratio for each material combination. From our results we propose a novel heat-based hyperthermia strategy with the focus on improving the heating efficiency of small sized nanoparticles instead of larger ones. This approach might have important implications for cancer treatment and could help improving clinical efficacy.The phenomenon of heat dissipation by magnetic materials interacting with an alternating magnetic field, known as magnetic hyperthermia, is an emergent and promising therapy for many diseases, mainly cancer. Here, a magnetic hyperthermia model for core-shell nanoparticles is developed. The theoretical calculation, different from previous models, highlights the importance of heterogeneity by identifying the role of surface and core spins on nanoparticle heat generation. We found that the most efficient nanoparticles should be obtained by selecting materials to reduce the surface to core damping factor ratio, increasing the interface exchange parameter and tuning the surface to core anisotropy ratio for each material combination. From our results we propose a novel heat-based hyperthermia strategy with the focus on improving the heating efficiency of small sized nanoparticles instead of larger ones. This approach might have important implications for cancer

  17. Magnetic Properties of Amorphous Fe-Si-B Powder Cores Mixed with Pure Iron Powder

    Science.gov (United States)

    Kim, Hyeon-Jun; Nam, Seul Ki; Kim, Kyu-Sung; Yoon, Sung Chun; Sohn, Keun-Yong; Kim, Mi-Rae; Sul Song, Yong; Park, Won-Wook

    2012-10-01

    Amorphous Fe-Si-B alloy was prepared by melt-spinning, and then the ribbons were pulverized and ball-milled to make the amorphous powder of ˜25 µm in size. Subsequently those were mixed with pure iron powders with an average particle size of 3 µm, and 1.5 wt % water glass diluted by distilled water at the ratio of 1:2. The powder mixtures were cold compacted at 650 MPa in toroid die, and heat treated at 430-440 °C under a nitrogen atmosphere for 1 h and 30 min, respectively. The soft magnetic properties of powder core were investigated using a B-H analyzer and a flux meter at the frequency range of ˜100 kHz. The microstructure was observed using scanning electron microscope (SEM), and the density of the core was measured using the principle of Archimedes. Based on the experimental results, the amorphous powder mixed with pure iron powder showed the improved powder compactability, which resulted in the increased permeability and the reduced core loss.

  18. Effects of Heat Treatment on the Magnetic Properties of Polymer-Bound Iron Particle Cores

    Science.gov (United States)

    Namkung, M.; Wincheski, B.; Bryant, R. G.; Buchman, A.

    1998-01-01

    Spherical iron particles of three different size distributions, 6-10 micrometers in diameter, 100 mesh and 30-80 mesh, were mixed with 2.0 wt % of soluble imide and compression molded at 300 C under 131 MPa. Post-fabrication heat treatments were performed at 960 C for 6 h resulting in a significant enhancement of the permeability in low field region for all the specimens except for the one made of 30-80 mesh particles. The rate of core loss of these specimens at a magnetic induction of 5 kG measured up to 1 kHz shows a noticeable. increase after heat treatment which, along with the permeability enhancement, can be explained by the coalescence of particles forming a network of conductivity paths in the specimens. ne scanning electron micrographs taken for the 6-10 micrometer particle specimens show no evidence of heat treatment-induced grain growth. The untreated specimens show a very weak f(sup 2) -dependence of the core loss which clearly indicates a negligible contribution from the eddy current loss. In particular, an almost perfect linearity was found in the frequency dependence of the core loss of the untreated specimen made of 100 mesh iron particles.

  19. Magnetic properties of core-shell catalyst nanoparticles for carbon nanotube growth

    Science.gov (United States)

    Fleaca, C. T.; Morjan, I.; Alexandrescu, R.; Dumitrache, F.; Soare, I.; Gavrila-Florescu, L.; Le Normand, F.; Derory, A.

    2009-03-01

    Two types of core-shell nanoparticles have been prepared by laser pyrolysis using Fe(CO) 5 and C 2H 2 or [(CH 3) 3Si] 2O as precursors and C 2H 4 as sensitizer. The first type (about 4 nm diameter) - produced by the decomposition of Fe(CO) 5 in the presence of C 2H 4 and C 2H 2 - consists of Fe cores protected by graphenic layers. The second type (mean particle size of about 14 nm) consists also of Fe cores, yet covered by few nm thick γ-Fe 2O 3/porous polycarbosiloxane shells resulted from the [(CH 3) 3Si] 2O decomposition and superficial oxidation after air exposure. The hysteresis loops suggest a room temperature superparamagnetic behavior of the Fe-C nanopowder and a weak ferromagnetic one for larger particles in the Fe-Fe 2O 3-polymer sample. Both types of nanoparticles were finally used as a catalyst for the carbon nanotube growth by seeding Si(100) substrates via drop-casting method. CNTs were grown by Hot-Filament Direct. Current PE CVD technique from C 2H 2 and H 2 at 980 K. It is suggested that the increased density and orientation degree observed for the multiwall nanotubes grown from Fe-Fe 2O 3-polymer nanoparticles could be due to their magnetic behavior and surface composition.

  20. Anti-cancer drug loaded iron-gold core-shell nanoparticles (Fe@Au) for magnetic drug targeting.

    Science.gov (United States)

    Kayal, Sibnath; Ramanujan, Raju Vijayaraghavan

    2010-09-01

    Magnetic drug targeting, using core-shell magnetic carrier particles loaded with anti-cancer drugs, is an emerging and significant method of cancer treatment. Gold shell-iron core nanoparticles (Fe@Au) were synthesized by the reverse micelle method with aqueous reactants, surfactant, co-surfactant and oil phase. XRD, XPS, TEM and magnetic property measurements were utilized to characterize these core-shell nanoparticles. Magnetic measurements showed that the particles were superparamagnetic at room temperature and that the saturation magnetization decreased with increasing gold concentration. The anti-cancer drug doxorubicin (DOX) was loaded onto these Fe@Au nanoparticle carriers and the drug release profiles showed that upto 25% of adsorbed drug was released in 80 h. It was found that the amine (-NH2) group of DOX binds to the gold shell. An in vitro apparatus simulating the human circulatory system was used to determine the retention of these nanoparticle carriers when exposed to an external magnetic field. A high percentage of magnetic carriers could be retained for physiologically relevant flow speeds of fluid. The present findings show that DOX loaded gold coated iron nanoparticles are promising for magnetically targeted drug delivery.

  1. Preparation and microwave absorbing properties of the core-nanoshell composite absorbers with the magnetic fly-ash hollow cenosphere as core.

    Science.gov (United States)

    Che, Ruxin; Wang, Chunxia; Ni, Yingjuan; Yu, Bing

    2011-06-01

    Electromagnetic (EM) wave pollution has become the chief physical pollution for environment. The core-nanoshell composite absorbers with magnetic fly-ash hollow cenosphere as core and nanocrystalline magnetic material as shell were prepared by high-energy ball milling. The results of X-ray diffraction analysis (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM) and vector network analyzer (VNA) analysis indicated that perfect-crystalline nanomagnetic material coating was gotten with a particle size of 12 nm, being dried at 60°C for 2 hr and calcined at 400°C for 1 hr after ball milling. The exchange-coupling interaction happened between ferrite of cenosphere and soft magnet γ-Fe203 coating, it enhances magnetic loss of composite absorbers. In the frequency between 1 MHz and 1 GHz, the absorbing effectiveness of the core-nanoshell composite absorbers can achieve -30 dB, it is better than single material and is consistent with requirements of the microwave absorbing material at the low-frequency absorption.

  2. Outstanding efficiency in energy conversion for electric motors constructed by nanocrystalline soft magnetic alloy “NANOMET®” cores

    Directory of Open Access Journals (Sweden)

    N. Nishiyama

    2016-05-01

    Full Text Available Recently updated nanocrystalline soft magnetic Fe-Co-Si-B-P-Cu alloys “NANOMET®” exhibit high saturation magnetic flux density (Bs > 1.8 T, low coercivity (Hc < 10 A/m and low core loss (W1.7/50 ∼ 0.4 W/kg even in a ribbon form with a thickness of up to 40 μm. By utilize excellent magnetic softness, several products such as motors or transformers for electrical appliances are now under developing by industry-academia collaboration. In particular, it is found that a brushless DC motor using NANOMET® core exhibited remarkable improvement in energy consumption. The prototype motor with an outer core diameter of 70 mm and a core thickness of 50 mm was constructed using laminated nano-crystallized NANOMET® ribbons. Core-loss for the constructed motor was improved from 1.4 W to 0.4 W only by replacing the non-oriented Si-steel core with NANOMET® one. The overall motor efficiency is evaluated to be 3% improvement. In this work, the relation between processing and resulting magnetic properties will be presented. In addition, feasibility for commercialization will also be discussed.

  3. Carboxymethyl chitosan-modified magnetic-cored dendrimer as an amphoteric adsorbent

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Hye-Ran [Department of Civil and Environmental Engineering, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 133-791 (Korea, Republic of); Jang, Jun-Won [Pohang Institute of Metal Industry Advancement, 56 Jigok-ro, Nam-gu, Pohang-si, Gyeongsangbuk-do 790-834 (Korea, Republic of); Park, Jae-Woo, E-mail: jaewoopark@hanyang.ac.kr [Department of Civil and Environmental Engineering, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 133-791 (Korea, Republic of)

    2016-11-05

    Highlights: • Carboxymethyl chitosan was attached to magnetic-cored dendrimer as terminal groups. • High sorptive capacity of carboxymethyl chitosan is added to dendritic structure. • This new adsorbent can be easily separated from water with magnetic force. • It could be reused as an adsorbent more than five-times with simple pH adjustment. - Abstract: Carboxymethyl chitosan-modified magnetic-cored dendrimers (CCMDs) were successfully synthesized in a three step method. The synthesized samples were characterized using X-ray diffraction, transmission electron microscopy, scanning electron microscopy, vibrating sample magnetometer, thermogravimetry analysis, zeta potential analyzer, X-ray photoelectron spectroscopy, surface area analysis, and Fourier transform infrared spectroscopy. The CCMD exhibited selective adsorption for anionic and cationic compounds at specific pH conditions. With the substitution of amino groups of MD with carboxymethyl chitosan moieties, the adsorption sites for cationic compounds were greatly increased. Since the adsorption onto CCMD was mainly electrostatic interaction, the adsorption of MB and MO was significantly affected by the pHs. The optimal adsorption pH values were 3 and 11 for MO and MB. The maximal adsorption of MO and MB on the CCMD at pH values of 3 and 11 were 20.85 mg g{sup −1} and 96.31 mg g{sup −1}, respectively. Reuse of the CCMD as an adsorbent was experimentally tested through adsorption and desorption with simple pH control. More than 99% and 91% of the initial adsorption of MB and MO on the CCMD was maintained with five consecutive recycling.

  4. Spin flip of neutrinos with magnetic moment in core-collapse supernova

    CERN Document Server

    Lychkovskiy, Oleg

    2009-01-01

    Neutrino with magnetic moment can experience a chirality flip while scattering off charged particles. This effect may lead to important consequences for the dynamics and the neutrino signal of the core-collapse supernova. It is known that if neutrino is a Dirac fermion, then nu_L->nu_R transition induced by the chirality flip leads to the emission of sterile right-handed neutrinos. The typical energies of these neutrinos are rather high, E ~ (100-200)MeV. Neutrino spin precession in the magnetic field either inside the collapsing star or in the interstellar space may lead to the backward transition, nu_R->nu_L. Both possibilities are known to be interesting. In the former case high-energy neutrinos can deliver additional energy to the supernova envelope, which can help the supernova to explode. In the latter case high-energy neutrinos may be detected simultaneously with the "normal" supernova neutrino signal, which would be a smoking gun for the Dirac neutrino magnetic moment. We report the results of the cal...

  5. Update of the European Association of Cardiovascular Imaging (EACVI) Core Syllabus for the European Cardiovascular Magnetic Resonance Certification Exam.

    Science.gov (United States)

    Petersen, Steffen E; Almeida, Ana G; Alpendurada, Francisco; Boubertakh, Redha; Bucciarelli-Ducci, Chiara; Cosyns, Bernard; Greil, Gerald F; Karamitsos, Theodoros D; Lancellotti, Patrizio; Stefanidis, Alexandros S; Tann, Oliver; Westwood, Mark; Plein, Sven

    2014-07-01

    An updated version of the European Association of Cardiovascular Imaging (EACVI) Core Syllabus for the European Cardiovascular Magnetic Resonance (CMR) Certification Exam is now available online. The syllabus lists key elements of knowledge in CMR. It represents a framework for the development of training curricula and provides expected knowledge-based learning outcomes to the CMR trainees, in particular those intending to demonstrate CMR knowledge in the European CMR exam, a core requirement in the CMR certification process.

  6. Magnetized Converging Flows toward the Hot Core in the Intermediate/High-mass Star-forming Region NGC 6334 V

    Science.gov (United States)

    Juárez, Carmen; Girart, Josep M.; Zamora-Avilés, Manuel; Tang, Ya-Wen; Koch, Patrick M.; Liu, Hauyu Baobab; Palau, Aina; Ballesteros-Paredes, Javier; Zhang, Qizhou; Qiu, Keping

    2017-07-01

    We present Submillimeter Array (SMA) observations at 345 GHz toward the intermediate/high-mass cluster-forming region NGC 6334 V. From the dust emission we spatially resolve three dense condensations, the brightest one presenting the typical chemistry of a hot core. The magnetic field (derived from the dust polarized emission) shows a bimodal converging pattern toward the hot core. The molecular emission traces two filamentary structures at two different velocities, separated by 2 km s-1, converging to the hot core and following the magnetic field distribution. We compare the velocity field and the magnetic field derived from the SMA observations with magnetohydrodynamic simulations of star-forming regions dominated by gravity. This comparison allows us to show how the gas falls in from the larger-scale extended dense core (˜0.1 pc) of NGC 6334 V toward the higher-density hot core region (˜0.02 pc) through two distinctive converging flows dragging the magnetic field, whose strength seems to have been overcome by gravity.

  7. The Role of Magnetic Resonance Imaging in Athletic Pubalgia and Core Muscle Injury.

    Science.gov (United States)

    Coker, Dana J; Zoga, Adam C

    2015-08-01

    Magnetic resonance imaging (MRI) has become the standard of care imaging modality for a difficult, often misunderstood spectrum of musculoskeletal injury termed athletic pubalgia or core muscle injury. Armed with a dedicated noncontrast athletic pubalgia protocol and a late model phased array receiver coil, the musculoskeletal imager can play a great role in effective diagnosis and treatment planning for lesions, including osteitis pubis, midline pubic plate lesions, and rectus abdominis/adductor aponeurosis injury. Beyond these established patterns of MRI findings, there are many confounders and contributing pathologies about the pelvis in patients with activity related groin pain, including internal and periarticular derangements of the hip. The MRI is ideally suited to delineate the extent of expected injury and to identify the unexpected visceral and musculoskeletal lesions.

  8. The core structure and pseudo-magnetic field of the dislocation in graphene

    Science.gov (United States)

    Wang, Shaofeng; Wang, Rui

    2013-10-01

    An analytical theory is presented for the dislocation (pentagon-heptagon pair) in graphene. In order to fully determine the nonlinear interaction which is responsible for the appearance of dislocation, a γ-potential is proposed and calculated from the electron-density functional theory. The improved dislocation equation, which takes into account the change in space between the mismatched chains, is solved by the variational principle. The strain and stress, in particular the change in the bond length and bond angle at the dislocation core, are obtained explicitly and verified by the first-principle calculation. The pseudo-magnetic field felt by electrons at the band edge is investigated including contribution from topology as well as deformation.

  9. Gas phase synthesis of core-shell Fe@FeO x magnetic nanoparticles into fluids

    Science.gov (United States)

    Aktas, Sitki; Thornton, Stuart C.; Binns, Chris; Denby, Phil

    2016-12-01

    Sorbitol, short chain molecules, have been used to stabilise of Fe@FeO x nanoparticles produced in the gas phase under the ultra-high vacuum (UHV) conditions. The sorbitol coated Fe@FeO x nanoparticles produced by our method have a narrow size distribution with a hydrodynamic diameter of 35 nm after NaOH is added to the solution. Magnetisation measurement shows that the magnetic nanoparticles are superparamagnetic at 100 K and demonstrate hysteresis at 5 K with an anisotropy constant of 5.31 × 104 J/m3 (similar to bulk iron). Also, it is shown that sorbitol is only suitable for stabilising the Fe@FeO x suspensions, and it does not prevent further oxidation of the metallic Fe core. According to MRI measurement, the nanoparticles have a high transverse relaxation rate of 425 mM-1 s-1.

  10. Relativistic MHD simulations of core-collapse GRB jets: 3D instabilities and magnetic dissipation

    CERN Document Server

    Bromberg, Omer

    2015-01-01

    Relativistic jets naturally occur in astrophysical systems that involve accretion onto compact objects, such as core collapse of massive stars in gamma-ray bursts (GRBs) and accretion onto supermassive black holes in active galactic nuclei (AGN). It is generally accepted that these jets are powered electromagnetically, by the magnetised rotation of a central compact object. However, how they produce the observed emission and survive the propagation for many orders of magnitude in distance without being disrupted by current-driven non-axisymmetric instabilities is the subject of active debate. We carry out time-dependent 3D relativistic magnetohydrodynamic simulations of relativistic, Poynting flux dominated jets. The jets are launched self-consistently by the rotation of a strongly magnetised central compact object. This determines the natural degree of azimuthal magnetic field winding, a crucial factor that controls jet stability. We find that the jets are susceptible to two types of instability: (i) a globa...

  11. INFLUENCE OF MAGNETOROTATIONAL INSTABILITY ON NEUTRINO HEATING: A NEW MECHANISM FOR WEAKLY MAGNETIZED CORE-COLLAPSE SUPERNOVAE

    Energy Technology Data Exchange (ETDEWEB)

    Sawai, Hidetomo; Yamada, Shoichi, E-mail: hsawai@heap.phys.waseda.ac.jp [Waseda University, Shinjuku, Tokyo 169-8555 (Japan)

    2014-03-20

    We investigated the impact of magnetorotational instability (MRI) on the dynamics of weakly magnetized, rapidly rotating core-collapse supernovae by conducting high-resolution axisymmetric MHD simulations with simplified neutrino transfer. We found that an initially sub-magnetar-class magnetic field is drastically amplified by MRI and substantially affects the dynamics thereafter. Although the magnetic pressure is not strong enough to eject matter, the amplified magnetic field efficiently transfers angular momentum from small to large radii and from higher to lower latitudes, which causes the expansion of the heating region due to the extra centrifugal force. This then enhances the efficiency of neutrino heating and eventually leads to neutrino-driven explosion. This is a new scenario of core-collapse supernovae that has never been demonstrated by past numerical simulations.

  12. Enrichment of Fetal Nucleated Red Blood Cells by Multi-core Magnetic Composite Particles for Non-invasive Prenatal Diagnosis

    Institute of Scientific and Technical Information of China (English)

    PAN Ying; ZHANG Ai-chen; WANG Qing; HUANG Wen-jun; QIAO Feng-li; LIU Yu-ping; ZHANG Yu-cheng; HAl De-yang; DU Ying-ting; WANG Wen-yue

    2012-01-01

    A novel kind of multi-core magnetic composite particles,the surfaces of which were respectively modified with goat-anti-mouse IgG and antitransferrin receptor(anti-CD71 ),was prepared.The fetal nucleated red blood cells(FNRBCs) in the peripheral blood of a gravida were rapidly and effectively enriched and separated by the modified multi-core magnetic composite particles in an external magnetic field.The obtained FNRBCs were used for the identification of the fetal sex by means of fluorescence in situ hybridization(FISH) technique.The results demonstrate that the multi-core magnetic composite particles meet the requirements for the enrichment and speration of FNRBCs with a low concentration and the accuracy of detetion for the diagnosis of fetal sex reached to 95%.Moreover,the obtained FNRBCs were applied to the non-invasive diagnosis of Down syndrome and chromosome 3p21 was detected.The above facts indicate that the novel multi-core magnetic composite particles-based method is simple,reliable and cost-effective and has opened up vast vistas for the potential application in clinic non-invasive prenatal diagnosis.

  13. Low-energy magnetic excitations in Co/CoO core/shell nanoparticles

    Science.gov (United States)

    Feygenson, M.; Teng, X.; Inderhees, S. E.; Yiu, Y.; Du, W.; Han, W.; Wen, J.; Xu, Z.; Podlesnyak, A. A.; Niedziela, J. L.; Hagen, M.; Qiu, Y.; Brown, C. M.; Zhang, L.; Aronson, M. C.

    2011-05-01

    We have used inelastic neutron scattering measurements to study the magnetic excitations of Co core/CoO shell nanoparticles for energies from 0 to 50 meV. Above the blocking temperature TB, broad quasielastic scattering is observed, corresponding to the reorientation of the Co core moments and to paramagnetic CoO scattering. Below TB, two nearly dispersionless inelastic peaks are found, whose energies increase with decreasing temperature as order parameters, controlled by the nanoparticle Néel temperature TN=235 K, and saturating as T→0 at 2.7 and 6.7 meV, respectively. Similar excitations were observed in a powdered single crystal of CoO, indicating that both are intrinsic excitations of CoO, resulting from the exchange splitting of single-ion states for T⩽TN. Pronounced finite-size effects are observed for the scattering from the CoO nanoparticle shells, whose thicknesses range from 1.7 to 4.5 nm. These include an enhanced excitation linewidth, as well as a response that is not only spread over a much wider range of wave vectors, but is also significantly more intense in the nanoparticles than in bulk CoO.

  14. Low-energy magnetic excitations in Co/CoO core-shell nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Feygenson, Mikhail [Brookhaven National Laboratory (BNL); Teng, X. [University of New Hampshire; Inderhees, S. E. [University of Michigan; Yiu, Y. [Brookhaven National Laboratory (BNL); Yiu, Y. [State University of New York, Stony Brook; Du, W. [University of New Hampshire; Han, W. [Brookhaven National Laboratory (BNL); Wen, J. [Brookhaven National Laboratory (BNL); Xu, Z. [Brookhaven National Laboratory (BNL); Podlesnyak, Andrey A [ORNL; Niedziela, Jennifer L [ORNL; Hagen, Mark E [ORNL; Qiu, Y. [National Institute of Standards and Technol/University of Maryland, College Park; Brown, Craig [National Institute of Standards and Technology (NIST); Zhang, L. [Brookhaven National Laboratory (BNL); Aronson, Meigan C. [Brookhaven National Laboratory (BNL); Aronson, Meigan C. [State University of New York, Stony Brook

    2011-01-01

    We have used inelastic neutron scattering measurements to study the magnetic excitations of Co core/CoO shell nanoparticles for energies from 0 to 50 meV. Above the blocking temperature T{sub B}, broad quasielastic scattering is observed, corresponding to the reorientation of the Co core moments and to paramagnetic CoO scattering. Below T{sub B}, two nearly dispersionless inelastic peaks are found, whose energies increase with decreasing temperature as order parameters, controlled by the nanoparticle Neel temperature T{sub N} = 235 K, and saturating as T {yields} 0 at 2.7 and 6.7 meV, respectively. Similar excitations were observed in a powdered single crystal of CoO, indicating that both are intrinsic excitations of CoO, resulting from the exchange splitting of single-ion states for T T{sub N}. Pronounced finite-size effects are observed for the scattering from the CoO nanoparticle shells, whose thicknesses range from 1.7 to 4.5 nm. These include an enhanced excitation linewidth, as well as a response that is not only spread over a much wider range of wave vectors, but is also significantly more intense in the nanoparticles than in bulk CoO.

  15. Low-energy Magnetic Excitations in Co/CoO Core/shell Nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Feygenson, M.; Teng, X.; Inderhees, E.; Yiu, Y.; Du, W.; Han, W.; Wen, J.; Xu, Z.; Podlesnyak, A.A.; Niedziela, J.L.; Hagen, M.; Qiu, Y.; Brown, C.M.; Zhang, L.; Aronson, M.C.

    2011-05-05

    We have used inelastic neutron scattering measurements to study the magnetic excitations of Co core/CoO shell nanoparticles for energies from 0 to 50 meV. Above the blocking temperature T{sub B}, broad quasielastic scattering is observed, corresponding to the reorientation of the Co core moments and to paramagnetic CoO scattering. Below T{sub B}, two nearly dispersionless inelastic peaks are found, whose energies increase with decreasing temperature as order parameters, controlled by the nanoparticle Neel temperature T{sub N} = 235 K, and saturating as T {yields} 0 at 2.7 and 6.7 meV, respectively. Similar excitations were observed in a powdered single crystal of CoO, indicating that both are intrinsic excitations of CoO, resulting from the exchange splitting of single-ion states for T-T{sub N}. Pronounced finite-size effects are observed for the scattering from the CoO nanoparticle shells, whose thicknesses range from 1.7 to 4.5 nm. These include an enhanced excitation linewidth, as well as a response that is not only spread over a much wider range of wave vectors, but is also significantly more intense in the nanoparticles than in bulk CoO.

  16. Chemical reduction synthesis and ac field effect of iron based core-shell magnetic nanoparticles

    Science.gov (United States)

    Balakrishnan, Srinivasan; Bonder, Michael J.; Hadjipanayis, George C.

    2009-12-01

    High magnetization nanoparticles coated with a biocompatible polymer have attracted considerable interest in recent times as potential materials for biomedical applications associated with targeted drug delivery, detection and the treatment of cancer. This paper considers the use of sodium borohydride reduction of metal salts to form Fe based nanoparticles coated with carboxyl terminated polyethylene glycol (cPEG). By mixing the reactants in a Y-junction, the synthesis produces uniform nanoparticles in the size range 10-20 nm with a core-shell structure. The particles are subsequently coated with a 1-3 nm thick layer of cPEG. These nanoparticles are soft ferromagnets with Hc = 400 Oe. Exciting these nanoparticles with a 4 Oe, 500 kHz alternating magnetic field leads to particle heating with a maximal increase in the saturation temperature as the particle size is decreased. For the largest particles considered here, the temperature reaches 35 °C with a 10 mg sample mass whilst for the smallest nanoparticles considered the temperature exceeds 40 °C.

  17. Dynamics of multi-cored magnetic structures in the quiet Sun

    CERN Document Server

    Requerey, Iker S; Rubio, Luis R Bellot; Pillet, Valentín Martínez; Solanki, Sami K; Schmidt, Wolfgang

    2015-01-01

    We report on the dynamical interaction of quiet-Sun magnetic fields and granular convection in the solar photosphere as seen by \\textsc{Sunrise}. We use high spatial resolution (0\\farcs 15--0\\farcs 18) and temporal cadence (33 s) spectropolarimetric Imaging Magnetograph eXperiment data, together with simultaneous CN and Ca\\,\\textsc{ii}\\,H filtergrams from \\textsc{Sunrise} Filter Imager. We apply the SIR inversion code to the polarimetric data in order to infer the line of sight velocity and vector magnetic field in the photosphere. The analysis reveals bundles of individual flux tubes evolving as a single entity during the entire 23 minute data set. The group shares a common canopy in the upper photospheric layers, while the individual tubes continually intensify, fragment and merge in the same way that chains of bright points in photometric observations have been reported to do. The evolution of the tube cores are driven by the local granular convection flows. They intensify when they are "compressed" by sur...

  18. Paleomagnetism and environmental magnetism of GLAD800 sediment cores from Bear Lake, Utah and Idaho

    Science.gov (United States)

    Heil, C.W.; King, J.W.; Rosenbaum, J.G.; Reynolds, R.L.; Colman, Steven M.

    2009-01-01

    A ???220,000-year record recovered in a 120-m-long sediment core from Bear Lake, Utah and Idaho, provides an opportunity to reconstruct climate change in the Great Basin and compare it with global climate records. Paleomagnetic data exhibit a geomagnetic feature that possibly occurred during the Laschamp excursion (ca. 40 ka). Although the feature does not exhibit excursional behavior (???40?? departure from the expected value), it might provide an additional age constraint for the sequence. Temporal changes in salinity, which are likely related to changes in freshwater input (mainly through the Bear River) or evaporation, are indicated by variations in mineral magnetic properties. These changes are represented by intervals with preserved detrital Fe-oxide minerals and with varying degrees of diagenetic alteration, including sulfidization. On the basis of these changes, the Bear Lake sequence is divided into seven mineral magnetic zones. The differing magnetic mineralogies among these zones reflect changes in deposition, preservation, and formation of magnetic phases related to factors such as lake level, river input, and water chemistry. The occurrence of greigite and pyrite in the lake sediments corresponds to periods of higher salinity. Pyrite is most abundant in intervals of highest salinity, suggesting that the extent of sulfidization is limited by the availability of SO42-. During MIS 2 (zone II), Bear Lake transgressed to capture the Bear River, resulting in deposition of glacially derived hematite-rich detritus from the Uinta Mountains. Millennial-scale variations in the hematite content of Bear Lake sediments during the last glacial maximum (zone II) resemble Dansgaard-Oeschger (D-O) oscillations and Heinrich events (within dating uncertainties), suggesting that the influence of millennial-scale climate oscillations can extend beyond the North Atlantic and influence climate of the Great Basin. The magnetic mineralogy of zones IV-VII (MIS 5, 6, and 7

  19. Transmission electron microscopy and ab initio calculations to relate interfacial intermixing and the magnetism of core/shell nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Chi, C.-C.; Hsiao, C.-H.; Ouyang, Chuenhou, E-mail: houyang@mx.nthu.edu.tw [Materials Science and Engineering, National Tsing Hua University, Hsinchu, Taiwan (China); Skoropata, E.; Lierop, J. van [Department of Physics and Astronomy, University of Manitoba, Winnipeg, Manitoba R3T 2N2 (Canada)

    2015-05-07

    Significant efforts towards understanding bi-magnetic core-shell nanoparticles are underway currently as they provide a pathway towards properties unavailable with single-phased systems. Recently, we have demonstrated that the magnetism of γ-Fe2O3/CoO core-shell nanoparticles, in particular, at high temperatures, originates essentially from an interfacial doped iron-oxide layer that is formed by the migration of Co{sup 2+} from the CoO shell into the surface layers of the γ-Fe2O3 core [Skoropata et al., Phys. Rev. B 89, 024410 (2014)]. To examine directly the nature of the intermixed layer, we have used high-resolution transmission electron microscopy (HRTEM) and first-principles calculations to examine the impact of the core-shell intermixing at the atomic level. By analyzing the HRTEM images and energy dispersive spectra, the level and nature of intermixing was confirmed, mainly as doping of Co into the octahedral site vacancies of γ-Fe2O3. The average Co doping depths for different processing temperatures (150 °C and 235 °C) were 0.56 nm and 0.78 nm (determined to within 5% through simulation), respectively, establishing that the amount of core-shell intermixing can be altered purposefully with an appropriate change in synthesis conditions. Through first-principles calculations, we find that the intermixing phase of γ-Fe2O3 with Co doping is ferromagnetic, with even higher magnetization as compared to that of pure γ-Fe2O3. In addition, we show that Co doping into different octahedral sites can cause different magnetizations. This was reflected in a change in overall nanoparticle magnetization, where we observed a 25% reduction in magnetization for the 235 °C versus the 150 °C sample, despite a thicker intermixed layer.

  20. Steering the magnetic properties of Ni/NiO/CoO core-shell nanoparticle films: The role of core-shell interface versus interparticle interactions

    Science.gov (United States)

    Ponti, Alessandro; Ferretti, Anna M.; Capetti, Elena; Spadaro, Maria Chiara; Bertoni, Giovanni; Grillo, Vincenzo; Luches, Paola; Valeri, Sergio; D'Addato, Sergio

    2017-08-01

    Supported core-shell Ni/NiO/CoO nanoparticle (NP) films were obtained by deposition of preformed and mass-selected Ni NPs on a buffer layer of CoO, followed by a top CoO layer. The resulting NPs have core/shell morphology, with a McKay icosahedral Ni core and a partially crystalline CoO shell. X-ray photoelectron spectroscopy evidenced the presence of a thin NiO layer, which was shown to be between the Ni core and the CoO shell by elemental TEM mapping. CoO and NiO shells with different thickness values were obtained, allowing us to investigate the evolution of the magnetic properties of the NP assemblies as a function of the oxide shell thickness. Both exchange-coupling and magnetostatic interactions significantly contribute to the magnetic behavior of Ni/NiO/CoO NP films. After the Ni/NiO/CoO NPs are cooled in a weak magnetic field, they have blocking temperature higher than room temperature because of strong magnetostatic interactions, which support the formation of a spin-glass-like state below ˜250 K . Exchange coupling dominates the magnetic behavior after the NPs are cooled in a strong magnetic field. The exchange bias (EB) is in the 0.17-2.35 kOe range and strongly depends on the CoO thickness (0.4-2.7 nm), showing the onset of the EB at the few-nanometer scale. The switching field distribution showed that the EB opposes the magnetization reversal from the direction along the cooling field but it does not significantly ease the opposite process. The EB depends on tCoO only for tNiO≤0.5 nm , but when NiO is 0.7 nm thick it strongly interacts with CoO and a large increase of the EB and coercivity is observed.

  1. Magnetic and fluorescent core-shell nanoparticles for ratiometric pH sensing

    Energy Technology Data Exchange (ETDEWEB)

    Lapresta-Fernandez, Alejandro; Doussineau, Tristan; Moro, Artur J [Institute of Physical Chemistry, Friedrich-Schiller-University Jena, Lessingstrasse 10, 07743 Jena (Germany); Dutz, Silvio [Institute of Photonic Technology, Department of Nano-Biophotonics, Jena (Germany); Steiniger, Frank [Centre for Electron Microscopy of the Medical Faculty, Jena (Germany); Mohr, Gerhard J, E-mail: lapresta@ugr.es [Fraunhofer Research Institution for Modular Solid State Technologies, Department of Polytronic Systems, Workgroup Sensor Materials, Josef-Engert-Strasse 9, D-93053 Regensburg (Germany)

    2011-10-14

    This paper describes the preparation of nanoparticles composed of a magnetic core surrounded by two successive silica shells embedding two fluorophores, showing uniform nanoparticle size (50-60 nm in diameter) and shape, which allow ratiometric pH measurements in the pH range 5-8. Uncoated iron oxide magnetic nanoparticles ({approx}10 nm in diameter) were formed by the coprecipitation reaction of ferrous and ferric salts. Then, they were added to a water-in-oil microemulsion where the hydrophilic silica shells were obtained through hydrolysis and condensation of tetraethoxyorthosilicate together with the corresponding silylated dye derivatives-a sulforhodamine was embedded in the inner silica shell and used as the reference dye while a pH-sensitive fluorescein was incorporated in the outer shell as the pH indicator. The magnetic nanoparticles were characterized using vibrating sample magnetometry, dynamic light scattering, transmission electron microscopy, x-ray diffraction and Fourier transform infrared spectroscopy. The relationship between the analytical parameter, that is, the ratio of fluorescence between the sensing and reference dyes versus the pH was adjusted to a sigmoidal fit using a Boltzmann type equation giving an apparent pK{sub a} value of 6.8. The fluorescence intensity of the reference dye did not change significantly ({approx}3.0%) on modifying the pH of the nanoparticle dispersion. Finally, the proposed method was statistically validated against a reference procedure using samples of water and physiological buffer with 2% of horse serum, indicating that there are no significant statistical differences at a 95% confidence level.

  2. Magnetic and fluorescent core-shell nanoparticles for ratiometric pH sensing.

    Science.gov (United States)

    Lapresta-Fernández, Alejandro; Doussineau, Tristan; Dutz, Silvio; Steiniger, Frank; Moro, Artur J; Mohr, Gerhard J

    2011-10-14

    This paper describes the preparation of nanoparticles composed of a magnetic core surrounded by two successive silica shells embedding two fluorophores, showing uniform nanoparticle size (50-60 nm in diameter) and shape, which allow ratiometric pH measurements in the pH range 5-8. Uncoated iron oxide magnetic nanoparticles (∼10 nm in diameter) were formed by the coprecipitation reaction of ferrous and ferric salts. Then, they were added to a water-in-oil microemulsion where the hydrophilic silica shells were obtained through hydrolysis and condensation of tetraethoxyorthosilicate together with the corresponding silylated dye derivatives-a sulforhodamine was embedded in the inner silica shell and used as the reference dye while a pH-sensitive fluorescein was incorporated in the outer shell as the pH indicator. The magnetic nanoparticles were characterized using vibrating sample magnetometry, dynamic light scattering, transmission electron microscopy, x-ray diffraction and Fourier transform infrared spectroscopy. The relationship between the analytical parameter, that is, the ratio of fluorescence between the sensing and reference dyes versus the pH was adjusted to a sigmoidal fit using a Boltzmann type equation giving an apparent pK(a) value of 6.8. The fluorescence intensity of the reference dye did not change significantly (∼3.0%) on modifying the pH of the nanoparticle dispersion. Finally, the proposed method was statistically validated against a reference procedure using samples of water and physiological buffer with 2% of horse serum, indicating that there are no significant statistical differences at a 95% confidence level.

  3. Watt loss in three-phase transformers with circular and hexagonal forming contours of twisted spatial magnetic core rods

    Directory of Open Access Journals (Sweden)

    E.A. Avdieieva

    2014-04-01

    Full Text Available For spatial three-phase axial electromagnetic systems with circular and hexagonal cross-section configurations of twisted butt-end magnetic core rods, analytical dependences for optimal geometrical relations determination over the transformer minimum watt loss criterion are obtained, comparative analysis of the systems energy efficiency made.

  4. Interstrand contact resistance and magnetization of Nb3Sn Rutherford cables with cores of different materials and widths

    NARCIS (Netherlands)

    Collings, E.W.; Sumption, M.D.; Dietderich, D.R.; Susner, M.; Krooshoop, H.J.G.; Nijhuis, A.

    2012-01-01

    Rutherford cables with cores of E-glass and S-glass woven tape and types AISI-316 and AISI-304 stainless steel (SS) ribbon were subjected to calorimetric AC loss measurement in transverse magnetic fields of amplitude 400 mT and frequencies of up to 90 mHz applied in the face-on (FO) and edge-on (EO)

  5. Hot Core, Outflows and Magnetic Fields in W43-MM1 (G30.79 FIR 10)

    CERN Document Server

    Sridharan, T K; Qiu, K; Cortes, P; Li, H; Pillai, T; Patel, N A; Zhang, Q

    2013-01-01

    We present submillimeter spectral line and dust continuum polarization observations of a remarkable hot core and multiple outflows in the high-mass star-forming region W43-MM1 (G30.79 FIR 10), obtained using the Submillimeter Array (SMA). A temperature of $\\sim$ 400 K is estimated for the hot-core using CH$_3$CN (J=19-18) lines, with detections of 11 K-ladder components. The high temperature and the mass estimates for the outflows indicate high-mass star-formation. The continuum polarization pattern shows an ordered distribution, and its orientation over the main outflow appears aligned to the outflow. The derived magnetic field indicates slightly super-critical conditions. While the magnetic and outflow energies are comparable, the B-field orientation appears to have changed from parsec scales to $\\sim$ 0.1 pc scales during the core/star-formation process.

  6. Tunable High-Field Magnetization in Strongly Exchange-Coupled Freestanding Co/CoO Core/Shell Coaxial Nanowires.

    Science.gov (United States)

    Salazar-Alvarez, German; Geshev, Julian; Agramunt-Puig, Sebastià; Navau, Carles; Sanchez, Alvaro; Sort, Jordi; Nogués, Josep

    2016-08-31

    The exchange bias properties of Co/CoO coaxial core/shell nanowires were investigated with cooling and applied fields perpendicular to the wire axis. This configuration leads to unexpected exchange-bias effects. First, the magnetization value at high fields is found to depend on the field-cooling conditions. This effect arises from the competition between the magnetic anisotropy and the Zeeman energies for cooling fields perpendicular to the wire axis. This allows imprinting predefined magnetization states to the antiferromagnetic (AFM) shell, as corroborated by micromagnetic simulations. Second, the system exhibits a high-field magnetic irreversibility, leading to open hysteresis loops attributed to the AFM easy axis reorientation during the reversal (effect similar to athermal training). A distinct way to manipulate the high-field magnetization in exchange-biased systems, beyond the archetypical effects, was thus experimentally and theoretically demonstrated.

  7. Rock magnetic properties, magnetic susceptibility, and organic geochemistry comparison in core LZ1029-7 Lake El'gygytgyn, Far Eastern Russia

    Directory of Open Access Journals (Sweden)

    K. J. Murdock

    2012-09-01

    Full Text Available Susceptibility measurements performed on initial short (3–16 m cores taken from Lake El'gygytgyn exhibited a large range in values. This observation led to the suggestion of widespread magnetite dissolution within the sediments due to anoxic conditions within the lake. Rock magnetic properties and their comparison with magnetic susceptibility, Total Organic Carbon (TOC, and bulk δ13Corg proxies in core LZ1029-7 provide an insight into the character of the magnetic minerals present within the lake and can further the understanding of processes that may be present in the newer long core sediments Susceptibility measurements (χ of discrete samples corroborate the two order of magnitude difference seen in previous continuous susceptibility measurements (κ, correlating high values with interglacial periods and low values with glacial intervals. Hysteresis parameters defined the majority of the magnetic material to be magnetite of PSD size. TOC values increase while δ13Corg values decrease in one section of LZ1029-7, which is defined as the Last Glacial Maximum (LGM, and help confine the age of the core to approximately 62 kyr. Increases in TOC during the most recent glacial interval suggest increased preservation of organic carbon during these times High TOC and low magnetic susceptibility during the LGM support the theory of perennial ice cover during glacial periods, which would lead to lake stratification and therefore anoxic bottom water conditions. Low temperature magnetic measurements also confirmed the presence of magnetite, but also indicated titanomagnetite, siderite and/or rhodochrosite, and vivianite were present. The latter three minerals are found only in anoxic environments, and further support the notion of magnetite dissolution.

  8. Rock magnetic properties, magnetic susceptibility, and organic geochemistry comparison in core LZ1029-7 Lake El'gygytgyn, Russia Far East

    Directory of Open Access Journals (Sweden)

    K. J. Murdock

    2013-02-01

    Full Text Available Susceptibility measurements performed on initial short (~ 16 m cores PG1351 taken from Lake El'gygytgyn exhibited a large range in values. This observation led to the suggestion of widespread magnetite dissolution within the sediments due to anoxic conditions within the lake. Rock magnetic properties and their comparison with magnetic susceptibility, total organic carbon (TOC, and bulk δ13Corg proxies in core LZ1029-7, taken from the same site as the previously drilled PG1351, provide an insight into the character of the magnetic minerals present within the lake and can further the understanding of processes that may be present in the newer long core sediments. Susceptibility measurements (χ of discrete samples corroborate the two order of magnitude difference seen in previous continuous susceptibility measurements (κ, correlating high values with interglacial periods and low values with glacial intervals. Hysteresis parameters indicate that the majority of the magnetic material to be magnetite of PSD size. TOC values increase while δ13Corg values decrease in one section of LZ1029-7, which is defined as the Last Glacial Maximum (LGM, and help confine the age of the core to approximately 62 ka. Increases in TOC during the most recent glacial interval suggest increased preservation of organic carbon during this period. High TOC and low magnetic susceptibility during the LGM support the theory of perennial ice cover during glacial periods, which would lead to lake stratification and therefore anoxic bottom water conditions. Low temperature magnetic measurements confirmed the presence of magnetite, but also indicated titanomagnetite and possibly siderite, rhodochrosite, and/or vivianite were present. The latter three minerals are found only in anoxic environments, and further support the notion of magnetite dissolution.

  9. Can We Tell the Inner Core Size and the Heat Flow Pattern inside a Planet from the Observed Magnetic Field?

    Science.gov (United States)

    Cao, H.; Russell, C. T.; Wicht, J.; Christensen, U. R.

    2012-09-01

    Several distinct features of Saturn's magnetic field have been revealed in a recent study based on in-situ magnetic field measurements made by the Cassini spacecraft [1]. The field at the dynamo surface is found to be strongly concentrated near the spin-poles with little hemispherical asymmetry. This field geometry corresponds to a zig-zag shape magnetic spectrum with pronounced odd degree terms and all odd degree magnetic moments possess the same sign ( , and all be positive in this case). This is in contrast to the field properties at the outer core surface of the Earth, where the field near the spinpoles is at a relative minimum compared to field at mid-latitude (see Fig. 1). An anticyclonic polar vortex with upwelling flow inside the tangent cylinder (the tangent cylinder is an imaginary cylinder parallel to the spin axis and tangent to the inner core surface at the equator) has been inferred at the Earth's core surface from geomagnetic secular variation analyses [2]. The associated advective transport of magnetic field is like responsible for the typical minimum or inverse geomagnetic field at high latitudes and the pronounced flux patches at midlatitudes. This feature is also frequently found in convectively driven geodynamo models [3].

  10. Multifunctional Au-Fe3O4@MOF core-shell nanocomposite catalysts with controllable reactivity and magnetic recyclability

    Science.gov (United States)

    Ke, Fei; Wang, Luhuan; Zhu, Junfa

    2014-12-01

    The recovery and reuse of expensive catalysts are important in both heterogeneous and homogeneous catalysis due to economic and environmental reasons. This work reports a novel multifunctional magnetic core-shell gold catalyst which can be easily prepared and shows remarkable catalytic properties in the reduction of 4-nitrophenol. The novel Au-Fe3O4@metal-organic framework (MOF) catalyst consists of a superparamagnetic Au-Fe3O4 core and a porous MOF shell with controllable thickness. Small Au nanoparticles (NPs) of 3-5 nm are mainly sandwiched between the Fe3O4 core and the porous MOF shell. Catalytic studies show that the core-shell structured Au-Fe3O4@MOF catalyst has a much higher catalytic activity than other reported Au-based catalysts toward the reduction of 4-nitrophenol. Moreover, this catalyst can be easily recycled due to the presence of the superparamagnetic core. Therefore, compared to conventional catalysts used in the reduction of 4-nitrophenol, this porous MOF-based magnetic catalyst is green, cheap and promising for industrial applications.The recovery and reuse of expensive catalysts are important in both heterogeneous and homogeneous catalysis due to economic and environmental reasons. This work reports a novel multifunctional magnetic core-shell gold catalyst which can be easily prepared and shows remarkable catalytic properties in the reduction of 4-nitrophenol. The novel Au-Fe3O4@metal-organic framework (MOF) catalyst consists of a superparamagnetic Au-Fe3O4 core and a porous MOF shell with controllable thickness. Small Au nanoparticles (NPs) of 3-5 nm are mainly sandwiched between the Fe3O4 core and the porous MOF shell. Catalytic studies show that the core-shell structured Au-Fe3O4@MOF catalyst has a much higher catalytic activity than other reported Au-based catalysts toward the reduction of 4-nitrophenol. Moreover, this catalyst can be easily recycled due to the presence of the superparamagnetic core. Therefore, compared to conventional

  11. Electrical measurement of magnetic-field-impeded polarity switching of a ferromagnetic vortex core

    Science.gov (United States)

    Sushruth, Manu; Fried, Jasper P.; Anane, Abdelmadjid; Xavier, Stephane; Deranlot, Cyril; Kostylev, Mikhail; Cros, Vincent; Metaxas, Peter J.

    2016-09-01

    Vortex core polarity switching in NiFe disks has been evidenced using an all-electrical magnetoresistive rectification scheme. Simulation and experiments yield a consistent rectified signal loss when driving core gyration at high powers. With increasing power, the frequency range over which the loss occurs grows and the resonance downshifts in frequency, consistent with nonlinear core dynamics and periodic core polarity switching induced by the core reaching its critical velocity. Core-polarity-dependent rectification signals enable an independent verification of the switched core polarity. We also demonstrate the ability to impede core polarity switching by displacing the core towards the disk's edge where an increased core stiffness reduces the core velocity.

  12. Cu-Ni core-shell nanoparticles: structure, stability, electronic, and magnetic properties: a spin-polarized density functional study

    Science.gov (United States)

    Wang, Qiang; Wang, Xinyan; Liu, Jianlan; Yang, Yanhui

    2017-02-01

    Bimetallic core-shell nanoparticles (CSNPs) have attracted great interest not only because of their superior stability, selectivity, and catalytic activity but also due to their tunable properties achieved by changing the morphology, sequence, and sizes of both core and shell. In this study, the structure, stability, charge transfer, electronic, and magnetic properties of 13-atom and 55-atom Cu and Cu-Ni CSNPs were investigated using the density functional theory (DFT) calculations. The results show that Ni@Cu CSNPs with a Cu surface shell are more energetically favorable than Cu@Ni CSNPs with a Ni surface shell. Interestingly, three-shell Ni@Cu12@Ni42 is more stable than two-shell Cu13@Ni42, while two-shell Ni13@Cu42 is more stable than three-shell Cu@Ni12@Cu42. Analysis of Bader charge illustrates that the charge transfer increases from Cu core to Ni shell in Cu@Ni NPs, while it decreases from Ni core to Cu shell in Ni@Cu NPs. Furthermore, the charge transfer results that d-band states have larger shift toward the Fermi level for the Ni@Cu CSNPs with Cu surface shell, while the Cu@Ni CSNPs with Ni surface shell have similar d-band state curves and d-band centers with the monometallic Ni NPs. In addition, the Cu-Ni CSNPs possess higher magnetic moment when the Ni atoms aggregated at core region of CSNPs, while having lower magnetic moment when the Ni atoms segregate on surface region. The change of the Cu atom location in CSNPs has a weak effect on the total magnetic moment. Our findings provide useful insights for the design of bimetallic core-shell catalysts.

  13. Rock magnetic property of gravity core CSH1 from the northern Okinawa Trough and the effect of early diagenesis

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Detailed rock magnetic investigations were undertaken at 2~4 cm interval for the gravity core CSH1 (with a length of 17.36 m) from the northern Okinawa Trough. Time-scale of the core was constructed by two characteristic tephras and foraminferal assemblages, indicating an age of 50 ka for the bottom of the core. Except for three tephras and abrupt decrease in surface, there are little changes in all kinds of rock magnetic parameters that can be correlated to the climate change for the last 50 ka. Different from the common sediments, most S-ratios (S equals the negative ratio of IRM-0.3T to SIRM, which is an indicator of low coercivity content)of the sediments are smaller than 0.9, which implies a substantial amount of magnetic minerals with high coercivity. The existence of iron sulphide (greigite or pyrrhotite) is revealed by representative susceptibility-temperature curves showing 200~350 ℃ Curie temperature in addition to 580 ℃ of magnetite, and also by awful smell during heating and dark heating products. Both the occurrence of authigenic iron sulphide and quick decrease of magnetic parameters near the surface clearly show that sediments from Core CSH1 have undergone early diagenesis. The featureless magnetic changes of the whole core except for three tephras mean that the post-depositonal alteration is so strong that most original signals have been destroyed. For the same reason, the organic matter in sediment and sulphate in pore water must have been consumed along with dissolution, precipitation of iron and manganese happening sequencially during the redox reaction series. Great caution must be taken when using these altered chemical parameters for the interpretation of climatic changes.

  14. Characterization of a high-temperature superconducting conductor on round core cables in magnetic fields up to 20 T

    Energy Technology Data Exchange (ETDEWEB)

    van der Laan, D. C.; Noyes, P. D.; Miller, G. E.; Weijers, H. W.; Willering, G. P.

    2013-02-13

    The next generation of high-ï¬eld magnets that will operate at magnetic ï¬elds substantially above 20 T, or at temperatures substantially above 4.2 K, requires high-temperature superconductors (HTS). Conductor on round core (CORC) cables, in which RE-Ba{sub 2}Cu{sub 3}O{sub 7-{delta}} (RE = rare earth) (REBCO) coated conductors are wound in a helical fashion on a flexible core, are a practical and versatile HTS cable option for low-inductance, high-field magnets. We performed the first tests of CORC magnet cables in liquid helium in magnetic fields of up to 20 T. A record critical current I{sub c} of 5021 A was measured at 4.2 K and 19 T. In a cable with an outer diameter of 7.5 mm, this value corresponds to an engineering current density J{sub e} of 114 A mm{sup -2} , the highest J{sub e} ever reported for a superconducting cable at such high magnetic fields. Additionally, the first magnet wound from an HTS cable was constructed from a 6 m-long CORC cable. The 12-turn, double-layer magnet had an inner diameter of 9 cm and was tested in a magnetic field of 20 T, at which it had an I{sub c} of 1966 A. The cables were quenched repetitively without degradation during the measurements, demonstrating the feasibility of HTS CORC cables for use in high-field magnet applications.

  15. Characterization of a high-temperature superconducting conductor on round core cables in magnetic fields up to 20 T

    Energy Technology Data Exchange (ETDEWEB)

    van der Laan, D. C.; Noyes, P. D.; Miller, G. E.; Weijers, H. W.; Willering, G. P.

    2013-02-13

    The next generation of high-ï¬eld magnets that will operate at magnetic ï¬elds substantially above 20 T, or at temperatures substantially above 4.2 K, requires high-temperature superconductors (HTS). Conductor on round core (CORC) cables, in which RE-Ba{sub 2}Cu{sub 3}O{sub 7-{delta}} (RE = rare earth) (REBCO) coated conductors are wound in a helical fashion on a flexible core, are a practical and versatile HTS cable option for low-inductance, high-field magnets. We performed the first tests of CORC magnet cables in liquid helium in magnetic fields of up to 20 T. A record critical current I{sub c} of 5021 A was measured at 4.2 K and 19 T. In a cable with an outer diameter of 7.5 mm, this value corresponds to an engineering current density J{sub e} of 114 A mm{sup -2} , the highest J{sub e} ever reported for a superconducting cable at such high magnetic fields. Additionally, the first magnet wound from an HTS cable was constructed from a 6 m-long CORC cable. The 12-turn, double-layer magnet had an inner diameter of 9 cm and was tested in a magnetic field of 20 T, at which it had an I{sub c} of 1966 A. The cables were quenched repetitively without degradation during the measurements, demonstrating the feasibility of HTS CORC cables for use in high-field magnet applications.

  16. Enhanced magnetic resonance imaging and staining of cancer cells using ferrimagnetic H-ferritin nanoparticles with increasing core size

    Directory of Open Access Journals (Sweden)

    Cai Y

    2015-04-01

    Full Text Available Yao Cai,1–3 Changqian Cao,1,2 Xiaoqing He,1 Caiyun Yang,1–3 Lanxiang Tian,1,2 Rixiang Zhu,2 Yongxin Pan1,21France–China Bio-Mineralization and Nano-Structures Laboratory, 2Paleomagnetism and Geochronology Laboratory, Key Laboratory of the Earth and Planetary Physics, Institute of Geology and Geophysics, Chinese Academy of Sciences, 3University of Chinese Academy of Sciences, Beijing, People’s Republic of ChinaPurpose: This study is to demonstrate the nanoscale size effect of ferrimagnetic H-ferritin (M-HFn nanoparticles on magnetic properties, relaxivity, enzyme mimetic activities, and application in magnetic resonance imaging (MRI and immunohistochemical staining of cancer cells.Materials and methods: M-HFn nanoparticles with different sizes of magnetite cores in the range of 2.7–5.3 nm were synthesized through loading different amounts of iron into recombinant human H chain ferritin (HFn shells. Core size, crystallinity, and magnetic properties of those M-HFn nanoparticles were analyzed by transmission electron microscope and low-temperature magnetic measurements. The MDA-MB-231 cancer cells were incubated with synthesized M-HFn nanoparticles for 24 hours in Dulbecco’s Modified Eagle’s Medium. In vitro MRI of cell pellets after M-HFn labeling was performed at 7 T. Iron uptake of cells was analyzed by Prussian blue staining and inductively coupled plasma mass spectrometry. Immunohistochemical staining by using the peroxidase-like activity of M-HFn nanoparticles was carried out on MDA-MB-231 tumor tissue paraffin sections.Results: The saturation magnetization (Ms, relaxivity, and peroxidase-like activity of synthesized M-HFn nanoparticles were monotonously increased with the size of ferrimagnetic cores. The M-HFn nanoparticles with the largest core size of 5.3 nm exhibit the strongest saturation magnetization, the highest peroxidase activity in immunohistochemical staining, and the highest r2 of 321 mM-1 s-1, allowing to

  17. Immobilization of cholesterol oxidase on magnetic fluorescent core-shell-structured nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Jun, E-mail: hjun@whut.edu.cn; Liu, Huichao; Zhang, Peipei; Zhang, Pengfei; Li, Mengshi; Ding, Liyun

    2015-12-01

    The magnetic fluorescent core-shell structured nanoparticles, Fe{sub 3}O{sub 4}@SiO{sub 2}(F)@meso–SiO{sub 2} nanoparticles, were prepared. Cholesterol oxidase (COD) was immobilized on their surface to form Fe{sub 3}O{sub 4}@SiO{sub 2}(F)@meso–SiO{sub 2}@COD nanoparticles. Optimal immobilization was achieved with 2.5% (v/v) APTES, 2.0% (v/v) GA, 10 mg COD (in 15 mg carrier) and solution pH of 7.0. Fe{sub 3}O{sub 4}@SiO{sub 2}(F)@meso–SiO{sub 2}@COD nanoparticles showed maximal catalytic activity at pH 7.0 and 50 °C. The thermal, storage and operational stabilities of COD were improved greatly after its immobilization. After the incubation at 50 °C for 5 h, the nanoparticles and free COD retained 80% and 46% of its initial activity, respectively. After kept at 4 °C for 30 days, the nanoparticles and free COD maintained 86% and 65% of initial activity, respectively. The nanoparticles retained 71% of its initial activity after 7 consecutive operations. Since Fe{sub 3}O{sub 4}@SiO{sub 2}(F)@meso–SiO{sub 2}@COD nanoparticles contained tris(2,2-bipyridyl)dichloro-ruthenium(II) hexahydrate (Ru(bpy){sub 3}Cl{sub 2}) and were optical sensitive to oxygen in solution, it might be used as the sensing material and has the application potential in multi parameter fiber optic biosensor based on enzyme catalysis and oxygen consumption. - Highlights: • COD was immobilized on magnetic fluorescent core-shell structured nanoparticles. • The nanoparticles were optical sensitive to oxygen in water solution. • The nanoparticles have remarkable improved stability compared with free COD. • The nanoparticles can probably be used in multi parameter fiber optic Biosensor.

  18. Determining pore length scales and pore surface relaxivity of rock cores by internal magnetic fields modulation at 2MHz NMR.

    Science.gov (United States)

    Liu, Huabing; Nogueira d'Eurydice, Marcel; Obruchkov, Sergei; Galvosas, Petrik

    2014-09-01

    Pore length scales and pore surface relaxivities of rock cores with different lithologies were studied on a 2MHz Rock Core Analyzer. To determine the pore length scales of the rock cores, the high eigenmodes of spin bearing molecules satisfying the diffusion equation were detected with optimized encoding periods in the presence of internal magnetic fields Bin. The results were confirmed using a 64MHz NMR system, which supports the feasibility of high eigenmode detection at fields as low as 2MHz. Furthermore, this methodology was combined with relaxometry measurements to a two-dimensional experiment, which provides correlation between pore length and relaxation time. This techniques also yields information on the surface relaxivity of the rock cores. The estimated surface relaxivities were then compared to the results using an independent NMR method.

  19. Self-assembled plasmonic core-shell clusters with an isotropic magnetic dipole response in the visible range.

    Science.gov (United States)

    Mühlig, Stefan; Cunningham, Alastair; Scheeler, Sebastian; Pacholski, Claudia; Bürgi, Thomas; Rockstuhl, Carsten; Lederer, Falk

    2011-08-23

    We theoretically analyze, fabricate, and characterize a three-dimensional plasmonic nanostructure that exhibits a strong and isotropic magnetic response in the visible spectral domain. Using two different bottom-up approaches that rely on self-organization and colloidal nanochemistry, we fabricate clusters consisting of dielectric core spheres, which are smaller than the wavelength of the incident radiation and are decorated by a large number of metallic nanospheres. Hence, despite having a complicated inner geometry, such a core-shell particle is sufficiently small to be perceived as an individual object in the far field. The optical properties of such complex plasmonic core-shell particles are discussed for two different core diameters.

  20. Shape-Controlled Synthesis of Magnetic Iron Oxide@SiO₂-Au@C Particles with Core-Shell Nanostructures.

    Science.gov (United States)

    Li, Mo; Li, Xiangcun; Qi, Xinhong; Luo, Fan; He, Gaohong

    2015-05-12

    The preparation of nonspherical magnetic core-shell nanostructures with uniform sizes still remains a challenge. In this study, magnetic iron oxide@SiO2-Au@C particles with different shapes, such as pseduocube, ellipsoid, and peanut, were synthesized using hematite as templates and precursors of magnetic iron oxide. The as-obtained magnetic particles demonstrated uniform sizes, shapes, and well-designed core-shell nanostructures. Transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDX) analysis showed that the Au nanoparticles (AuNPs) of ∼6 nm were uniformly distributed between the silica and carbon layers. The embedding of the metal nanocrystals into the two different layers prevented the aggregation and reduced the loss of the metal nanocrystals during recycling. Catalytic performance of the peanut-like particles kept almost unchanged without a noticeable decrease in the reduction of 4-nitrophenol (4-NP) in 8 min even after 7 cycles, indicating excellent reusability of the particles. Moreover, the catalyst could be readily recycled magnetically after each reduction by an external magnetic field.

  1. Soft magnetic FeCoTaN film cores for new high-frequency CMOS compatible micro-inductors

    Energy Technology Data Exchange (ETDEWEB)

    Seemann, K. [Forschungszentrum Karlsruhe in der Helmholtz-Gemeinschaft, Institut fuer Materialforschung I, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany)]. E-mail: klaus.seemann@imf.fzk.de; Leiste, H. [Forschungszentrum Karlsruhe in der Helmholtz-Gemeinschaft, Institut fuer Materialforschung I, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany); Ziebert, C. [Forschungszentrum Karlsruhe in der Helmholtz-Gemeinschaft, Institut fuer Materialforschung I, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany)

    2007-09-15

    New high-frequency micro-inductors with thin magnetic film cores where developed by R.F.-magnetron sputtering and plasma beam as well as reactive ion etching. In order to realise soft magnetic films with magnetic resonance frequencies in the GHz range determined by frequency-dependent permeability measurements, 6-inch Fe{sub 47}Co{sub 36}Ta{sub 17} and Fe{sub 37}Co{sub 46}Ta{sub 17} targets were used to deposit FeCoTaN-films by reactive R.F.-magnetron sputtering in an Ar/N{sub 2} atmosphere. To obtain soft magnetic film properties with a marked uniaxial in-plane anisotropy needed for the high-frequency suitability, the films were annealed in a static magnetic field at CMOS temperatures of around 400 deg. C. Due to the specific material composition the films possess a nanocrystalline microstructure with a low magnetocrystalline anisotropy. The film material was employed to realise different magnetic cores for new micro-inductor designs fabricated by the CMOS aluminium process.

  2. Magnetism of a red soil core derived from basalt, northern Hainan Island, China: Volcanic ash versus pedogenesis

    Science.gov (United States)

    Liu, Zhifeng; Ma, Jinlong; Wei, Gangjian; Liu, Qingsong; Jiang, Zhaoxia; Ding, Xing; Peng, Shasha; Zeng, Ti; Ouyang, Tingping

    2017-03-01

    Similar to loess-paleosol sequences in northwestern China, terrestrial sedimentary sequences (red soils) in southern China also provide sensitive Quaternary records of subtropical/tropical paleoclimate and paleoenvironment. Compared with red clay sequences originated from eolian dust, red soils derived from bedrock have received little attention. In this study, a long core of red soil derived from weathered basalt in northern Hainan Island, China, was systematically investigated by using detailed magnetic measurements and rare earth element analyses. The results show that an extremely strong magnetic zone with a maximum magnetic susceptibility (>10 × 10-5 m3 kg-1) is interbedded in the middle of the core profile. This layer contains a significant amount of superparamagnetic magnetite/maghemite particles that primarily originated from volcanic ash, with secondary contributions from pedogenesis. The former has an average grain size of 19 nm with a normal distribution of volume, and the latter has a much wider grain size distribution. The presence of volcanic ash within the red soil indicates that these Quaternary basalts were not formed by continuous volcanic eruptions. Moreover, the magnetic enhancement patterns differ between the upper and lower zones. The upper zone is more magnetically enhanced and experienced higher precipitation and temperature than the lower zone. Discrimination of superparamagnetic particles originating from pedogenic processes and volcanic ash thus provides a sound theoretical base for accurate interpretation of magnetism in red soils in this region.

  3. Detent Force Reduction of a C-Core Linear Flux-Switching Permanent Magnet Machine with Multiple Additional Teeth

    Directory of Open Access Journals (Sweden)

    Yi Du

    2017-03-01

    Full Text Available C-core linear flux-switching permanent magnet (PM machines (LFSPMs are attracting more and more attention due to their advantages of simplicity and robustness of the secondary side, high power density and high torque density, in which both PMs and armature windings are housed in the primary side. The primary salient tooth wound with a concentrated winding consists of C-shaped iron core segments between which PMs are sandwiched and the magnetization directions of these PMs are adjacent and alternant in the horizontal direction. On the other hand, the secondary side is composed of a simple iron core with salient teeth so that it is very suitable for long stroke applications. However, the detent force of the C-core LFSPM machine is relatively high and the magnetic circuit is unbalanced due to the end effect. Thus, a new multiple additional tooth which consists of an active and a traditional passive additional tooth, is employed at each end side of the primary in this paper, so that the asymmetry due to end effect can be depressed and the detent force can be reduced by adjusting the passive additional tooth position. By using the finite element method, the characteristics and performances of the proposed machine are analyzed and verified.

  4. Lithology and chronology of ice-sheet fluctuations (magnetic susceptibility of cores from the western Ross Sea)

    Science.gov (United States)

    Jennings, Anne E.

    1993-01-01

    The goals of the marine geology part of WAIS include reconstructing the chronology and areal extent of ice-sheet fluctuations and understanding the climatic and oceanographic influences on ice-sheet history. As an initial step toward attaining these goals, down-core volume magnetic susceptibility (MS) logs of piston cores from three N-S transects in the western Ross Sea are compared. The core transects are within separate petrographic provinces based on analyses of till composition. The provinces are thought to reflect the previous locations of ice streams on the shelf during the last glaciation. Magnetic susceptibility is a function of magnetic mineral composition, sediment texture, and sediment density. It is applied in the western Ross Sea for two purposes: (1) to determine whether MS data differentiates the three transects (i.e., flow lines), and thus can be used to make paleodrainage reconstructions of the late Wisconsinan ice sheet; and (2) to determine whether the MS data can aid in distinguishing basal till diamictons from diamictons of glacial-marine origin and thus, aid paleoenvironmental interpretations. A comparison of the combined data of cores in each transect is presented.

  5. Preparation of Multifunctional Fe@Au Core-Shell Nanoparticles with Surface Grafting as a Potential Treatment for Magnetic Hyperthermia

    Directory of Open Access Journals (Sweden)

    Ren-Jei Chung

    2014-01-01

    Full Text Available Iron core gold shell nanoparticles grafted with Methotrexate (MTX and indocyanine green (ICG were synthesized for the first time in this study, and preliminarily evaluated for their potential in magnetic hyperthermia treatment. The core-shell Fe@Au nanoparticles were prepared via the microemulsion process and then grafted with MTX and ICG using hydrolyzed poly(styrene-alt-maleic acid (PSMA to obtain core-shell Fe@Au-PSMA-ICG/MTX nanoparticles. MTX is an anti-cancer therapeutic, and ICG is a fluorescent dye. XRD, TEM, FTIR and UV-Vis spectrometry were performed to characterize the nanoparticles. The data indicated that the average size of the nanoparticles was 6.4 ± 09 nm and that the Au coating protected the Fe core from oxidation. MTX and ICG were successfully grafted onto the surface of the nanoparticles. Under exposure to high frequency induction waves, the superparamagnetic nanoparticles elevated the temperature of a solution in a few minutes, which suggested the potential for an application in magnetic hyperthermia treatment. The in vitro studies verified that the nanoparticles were biocompatible; nonetheless, the Fe@Au-PSMA-ICG/MTX nanoparticles killed cancer cells (Hep-G2 via the magnetic hyperthermia mechanism and the release of MTX.

  6. From Cores to Envelopes to Disks: A Multi-scale View of Magnetized Star Formation

    Science.gov (United States)

    Hull, Charles L. H.

    2014-12-01

    Observations of polarization in star forming regions have been made across many wavelengths, many size scales, and many stages of stellar evolution. One of the overarching goals of these observations has been to determine the importance of magnetic fields -- which are the cause of the polarization -- in the star formation process. We begin by describing the commissioning and the calibration of the 1.3 mm dual-polarization receiver system we built for CARMA (the Combined Array for Research in Millimeter-wave Astronomy), a radio telescope in the eastern Sierra region of California. One of the primary science drivers behind the polarization system is to observe polarized thermal emission from dust grains in the dense clumps of dust and gas where the youngest, Class 0 protostars are forming. We go on to describe the CARMA TADPOL survey -- the largest high-resolution (~1000 AU scale) survey to date of dust polarization in low-mass protostellar cores -- and discuss our main findings: (1) Magnetic fields (B-fields) on scales of ~1000 AU are not tightly aligned with protostellar outflows. Rather, the data are consistent both with scenarios where outflows and magnetic fields are preferentially misaligned (perpendicular) and where they are randomly aligned. (2) Sources with high CARMA polarization fractions have consistent B-field orientations on large scales (~20'', measured using single-dish submillimeter telescopes) and small scales (~2.5'', measured by CARMA). We interpret this to mean that in at least some cases B-fields play a role in regulating the infall of material all the way down to the ~1000 AU scales of protostellar envelopes. Finally, (3) While on the whole outflows appear to be randomly aligned with B-fields, in sources with low polarization fractions there is a hint that outflows are preferentially perpendicular to small-scale B-fields, which suggests that in these sources the fields have been wrapped up by envelope rotation. This work shows that the ~1000 AU

  7. Copper, gold, and silver decorated magnetic core-polymeric shell nanostructures for destruction of pathogenic bacteria

    Science.gov (United States)

    Padervand, Mohsen; Karanji, Ahmad Kiani; Elahifard, Mohammad Reza

    2017-05-01

    Fe3O4 magnetic nanoparticles (MNPs) were prepared by co-precipitation method. The nanoparticles were silica coated using TEOS, and then modified by the polymeric layers of polypropylene glycol (PPG) and polyethylene glycol (PEG). Finally, the core-shell samples were decorated with Ag, Au, and Cu nanoparticles. The products were characterized by vibrating sample magnetometry (VSM), TGA, SEM, XRD, and FTIR methods. The antibacterial activity of the prepared samples was evaluated in inactivation of E. coli and S. aureus microorganisms, representing the Gram-negative and Gram-positive species, respectively. The effect of solid dosage, bacteria concentration and type of polymeric modifier on the antibacterial activity was investigated. TEM images of the bacteria were recorded after the treatment time and according to the observed changes in the cell wall, the mechanism of antibacterial action was discussed. The prepared nanostructures showed high antibacterial activity against both Gram-negative and Gram-positive bacteria. This was due to the leaching of metal ions which subsequently led to the lysis of bacteria. A theoretical investigation was also done by studying the interaction of loaded metals with the nucleotide components of the microorganism DNA, and the obtained results were used to explain the experimental data. Finally, based on the observed inactivation curves, we explain the antibacterial behavior of the prepared nanostructures mathematically.

  8. A compact high-voltage pulse generator based on pulse transformer with closed magnetic core.

    Science.gov (United States)

    Zhang, Yu; Liu, Jinliang; Cheng, Xinbing; Bai, Guoqiang; Zhang, Hongbo; Feng, Jiahuai; Liang, Bo

    2010-03-01

    A compact high-voltage nanosecond pulse generator, based on a pulse transformer with a closed magnetic core, is presented in this paper. The pulse generator consists of a miniaturized pulse transformer, a curled parallel strip pulse forming line (PFL), a spark gap, and a matched load. The innovative design is characterized by the compact structure of the transformer and the curled strip PFL. A new structure of transformer windings was designed to keep good insulation and decrease distributed capacitance between turns of windings. A three-copper-strip structure was adopted to avoid asymmetric coupling of the curled strip PFL. When the 31 microF primary capacitor is charged to 2 kV, the pulse transformer can charge the PFL to 165 kV, and the 3.5 ohm matched load can deliver a high-voltage pulse with a duration of 9 ns, amplitude of 84 kV, and rise time of 5.1 ns. When the load is changed to 50 ohms, the output peak voltage of the generator can be 165 kV, the full width at half maximum is 68 ns, and the rise time is 6.5 ns.

  9. Synthesis of Magnetic Rattle-Type Silica with Controllable Magnetite and Tunable Size by Pre-Shell-Post-Core Method.

    Science.gov (United States)

    Chen, Xue; Tan, Longfei; Meng, Xianwei

    2016-03-01

    In this study, we have developed the pre-shell-post-core route to synthesize the magnetic rattle-type silica. This method has not only simplified the precursor's process and reduced the reacting time, but also ameliorated the loss of magnetite and made the magnetite content and the inner core size controllable and tunable. The magnetite contents and inner core size can be easily controlled by changing the type and concentration of alkali, reaction system and addition of water. The results show that alkali aqueous solution promotes the escape of the precursor iron ions from the inner space of rattle-type silica and results in the loss of magnetite. In this case, NaOH ethanol solution is better for the formation of magnetite than ammonia because it not only offers an appropriate alkalinity to facilitate the synthesis of. magnetic particles, but also avoids the escape of the iron ions from the mesopores of rattle-type silica. The synthesis process is very simple and efficient, and it takes no more than 2 hours to complete the total preparation and handling of the magnetic rattle-type silica. The end-product Fe3O4@SiO2 nanocomposites also have good magnetic properties which will perform potential application in biomedical science.

  10. Statistical analysis of the mass-to-flux ratio in turbulent cores: effects of magnetic field reversals and dynamo amplification

    CERN Document Server

    Bertram, Erik; Banerjee, Robi; Klessen, Ralf S

    2011-01-01

    We study the mass-to-flux ratio (M/\\Phi) of clumps and cores in simulations of supersonic, magnetohydrodynamical turbulence for different initial magnetic field strengths. We investigate whether the (M/\\Phi)-ratio of core and envelope, R = (M/\\Phi)_{core}/(M/\\Phi)_{envelope} can be used to distinguish between theories of ambipolar diffusion and turbulence-regulated star formation. We analyse R for different Lines-of-Sight (LoS) in various sub-cubes of our simulation box. We find that, 1) the average and median values of |R| for different times and initial magnetic field strengths are typically greater, but close to unity, 2) the average and median values of |R| saturate at average values of |R| ~ 1 for smaller magnetic fields, 3) values of |R| < 1 for small magnetic fields in the envelope are caused by field reversals when turbulence twists the field lines such that field components in different directions average out. Finally, we propose two mechanisms for generating values |R| ~< 1 for the weak and st...

  11. Magnetic core/shell Fe3O4/Au nanoparticles for studies of quinolones binding to protein by fluorescence spectroscopy.

    Science.gov (United States)

    Jin, Rui; Song, Daqian; Xiong, Huixia; Ai, Lisha; Ma, Pinyi; Sun, Ying

    2016-03-01

    Magnetic core/shell Fe3O4/Au nanoparticles were used in the determination of drug binding to bovine serum albumin (BSA) using a fluorescence spectroscopic method. The binding constants and number of binding sites for protein with drugs were calculated using the Scatchard equation. Because of their superparamagnetic and biocompatible characteristics, magnetic core/shell Fe3O4/Au nanoparticles served as carrier proteins for fixing proteins. After binding of the protein to a drug, the magnetic core/shell Fe3O4/Au nanoparticles-protein-drug complex was separated from the free drug using an applied magnetic field. The free drug concentration was obtained directly by fluorescence spectrometry and the proteins did not influence the drug determination. So, the achieved number of binding sites should be reliable. The binding constant and site number for ciprofloxacin (CPFX) binding to BSA were 2.055 × 10(5) L/mol and 31.7, and the corresponding values for norfloxacin (NOR) binding to BSA were 1.383 × 10(5) L/mol and 38.8. Based on the achieved results, a suitable method was proposed for the determination of binding constants and the site number for molecular interactions. The method was especially suitable for studies on the interactions of serum albumin with the active ingredients of Chinese medicine.

  12. Multifunctional Au-Fe3O4@MOF core-shell nanocomposite catalysts with controllable reactivity and magnetic recyclability.

    Science.gov (United States)

    Ke, Fei; Wang, Luhuan; Zhu, Junfa

    2015-01-21

    The recovery and reuse of expensive catalysts are important in both heterogeneous and homogeneous catalysis due to economic and environmental reasons. This work reports a novel multifunctional magnetic core-shell gold catalyst which can be easily prepared and shows remarkable catalytic properties in the reduction of 4-nitrophenol. The novel Au-Fe3O4@metal-organic framework (MOF) catalyst consists of a superparamagnetic Au-Fe3O4 core and a porous MOF shell with controllable thickness. Small Au nanoparticles (NPs) of 3-5 nm are mainly sandwiched between the Fe3O4 core and the porous MOF shell. Catalytic studies show that the core-shell structured Au-Fe3O4@MOF catalyst has a much higher catalytic activity than other reported Au-based catalysts toward the reduction of 4-nitrophenol. Moreover, this catalyst can be easily recycled due to the presence of the superparamagnetic core. Therefore, compared to conventional catalysts used in the reduction of 4-nitrophenol, this porous MOF-based magnetic catalyst is green, cheap and promising for industrial applications.

  13. Magnetic Dichroism in the 4d-Core Photoabsorption for the Mixed Valent Ferromagnet CeRh3B2

    Science.gov (United States)

    Jo, Takeo; Imada, Shin

    1989-06-01

    The Ce 4d-core X-ray absorption spectrum (4d XAS) of the mixed valent ferromagnet CeRh3B2 is calculated based on the impurity Anderson model incorporated with electron-electron (or core hole) interactions described by the Slater integrals. The ferromagnetic ordering is taken into account by the molecular field acting on the 4f electron of the impurity atom. The difference in the 4d XAS between the right-hand and left-hand circularly polarized incident photons is predicted to be very remarkable, even for the magnetization of ˜ 1 μB per Ce atom.

  14. Identification of Synchronous Machine Magnetization Characteristics From Calorimetric Core-Loss and No-Load Curve Measurements

    OpenAIRE

    Rasilo, Paavo; Abdallh, Ahmed Abou-Elyazied; Belahcen, Anouar; Arkkio, Antero; Dupre, Luc

    2015-01-01

    The magnetic material characteristics of a wound-field synchronous machine are identified based on global calorimetric core-loss and no-load curve measurements. This is accomplished by solving a coupled experimental-numerical electromagnetic inverse problem, formulated to minimize the difference between a finite-element (FE) simulation-based Kriging surrogate model and the measurement results. The core-loss estimation in the FE model is based on combining a dynamic iron-loss model and a static v...

  15. Synthesis and characterization of Fe3O4@Ag core-shell: structural, morphological, and magnetic properties

    Directory of Open Access Journals (Sweden)

    Mahdi Ghazanfari

    2014-12-01

    Full Text Available This paper is a report on the synthesis of the Fe3O4@Ag core-shell with high saturation magnetization of magnetite nanoparticles as the core, by using polyol route and silver shell by chemical reduction. X-ray diffraction (XRD and Fourier transform infrared spectroscopy analyses confirmed that the particles so produced were monophase. The magnetic properties of the product were investigated by using a vibrating sample magnetometer. Magnetic saturation of magnetite was 91 emu/g that around about bulk magnetization. This high saturation magnetization can be attributed to the thin dead layer. By using polyethylene glycol as a surfactant to separate and restrict the growth of the particles, magnetostatic interactions are in good agreement with the remanence ratio analysis. Morphology and the average size of the particles were determined with field emission scanning electron microscope (FESEM. Spherical aggregates of Fe3O4 (size around 73 nm are composed of a small primary particle size of about 16 nm. Silver deposition was done using butylamine as the reductant of AgNO3 in ethanol with different ratio. The silver layers were estimated using statistical histogram images of FESEM. Silver-coated iron oxide nanohybrids have been used in a broad range of applications, including chemical and biological sensing, due to the broad absorption in the optical region associated with localized surface plasmon resonance.

  16. The biocompatibility and anti-biofouling properties of magnetic core-multishell Fe@C NWs-AAO nanocomposites.

    Science.gov (United States)

    Lindo, André M; Pellicer, Eva; Zeeshan, Muhammad A; Grisch, Roman; Qiu, Famin; Sort, Jordi; Sakar, Mahmut S; Nelson, Bradley J; Pané, Salvador

    2015-05-28

    Soft-magnetic core-multishell Fe@C NWs-AAO nanocomposites were synthesized using anodization, electrodeposition and low-pressure chemical vapour deposition (CVD) at 900 °C. High chemical and mechanical stability is achieved by the conversion from amorphous to θ- and δ-Al2O3 phases above 600 °C. Moreover, the surface properties of the material evolve from bioactive, for porous AAO, to bioinert, for Fe@C NW filled AAO nanocomposite. Although the latter is not cytotoxic, cells do not adhere onto the surface of the magnetic nanocomposite, thus proving its anti-biofouling character.

  17. The thermal behaviors and phase diagrams of the Ising-type endohedral fullerene with magnetic core and diluted magnetic shell (Core@Shell20)

    Science.gov (United States)

    Kantar, Ersin

    2017-08-01

    We have carried out theoretical studies on Ising-type endohedral fullerene (EF) structure with a dopant magnetic atom encaged within the diluted magnetic spherical cage to examine the evolution in magnetic behaviors. We show how the thermal behaviors and phase diagrams of Ising-type EF are affected by diluted surface, crystal field and exchange couplings. We have used to investigate theoretically the effect of Hamiltonian parameters the effective field calculations within Ising model framework. The model Hamiltonian includes nearest neighbor ferromagnetic and antiferromagnetic center-surface (C-S) interaction as well as ferromagnetic surface interaction. We have shown that the system exhibits the first and second order phase transitions as well as tricritical point. In particular, the conditions for the occurrence of these reentrant and double reentrant behaviors are given explicitly.

  18. Effect of magnetic field on quantum state energies of an electron confined in the core of a double walled carbon nanotube

    Science.gov (United States)

    Shah, Khurshed A.; Bhat, Bashir Mohi Ud Din

    2016-10-01

    In this paper we report the effect of external magnetic field and core radius on the excited quantum state energies of an electron confined in the core of a double walled carbon nanotube. The goal is accomplished by using Wentzel-Kramers-Brillioun (WKB) approximation method within the effective mass approximation and confinement potential. All numerical analysis were carried out in a strong confinement regime. The results show that the electron energy increases with the increase in external magnetic field at a given core radii. The electron energy is also found to increase as the core radius of the CNT decreases and for core radius a > 5 nm the energy becomes almost zero. The effect of magnetic field on the excited state energies of the confined electron is more evident for smaller core radius acarbon nanotube quantum dot devices [1].

  19. Chemical synthesis of Fe/Fe3O4 core-shell composites with enhanced soft magnetic performances

    Science.gov (United States)

    Yang, Bai; Li, Xiaopan; Yang, Xueying; Yu, Ronghai

    2017-04-01

    The large-grain Fe/Fe3O4 composite particles with average size of about 1.2 μm have been fabricated by a facile one-step solvothermal method. The formation of high-purity Fe3O4 as the shells (90.14 wt%) and α-Fe as the cores (9.86 wt%) in the Fe/Fe3O4 composites leads to their high saturation magnetization of 119.6 A m2 Kg-1. Very low coercivity of 30 Oe is obtained in the composites due to their uniform cubic-shaped morphologies. Compared with Fe-based nanosized particles, these micron-sized magnetic Fe/Fe3O4 composites exhibit high air stability and good compactibility with high compressed density of 5.9 g cm-3. The fully compacted sample shows good soft magnetic properties including high magnetic induction B1.2k (H=1200 A/m) of 540 mT and good frequency-dependent magnetic properties with operating frequency up to 50 MHz superior to those of the most traditional soft magnetic ferrites, which promotes their potential applications in high-frequency and high-power magnetic devices.

  20. Highly regenerable carbon-Fe3O4 core-satellite nanospheres as oxygen reduction electrocatalyst and magnetic adsorbent

    Science.gov (United States)

    Zhou, Wenqiang; Liu, Minmin; Cai, Chao; Zhou, Haijun; Liu, Rui

    2017-02-01

    We present the synthesis and multifunctional utilization of core-satellite carbon-Fe3O4 nanoparticles to serve as the enabling platform for a range of applications including oxygen reduction reaction (ORR) and magnetic adsorbent. Starting from polydopamine (PDA) nanoparticles and Fe(NO3)3, carbon-Fe3O4 core-satellite nanospheres are synthesized through successive steps of impregnation, ammoniation and carbonization. The synergistic combination of Fe3O4 and N-doped carbon endows the nanocomposite with high electrochemical activity in ORR and mainly four electrons transferred in reaction process. Furthermore, carbon-Fe3O4 nanoparticles used as magnetic adsorbent exhibit the efficient removal of Rhodamine B from an aqueous solution. The recovery and reuse of the adsorbent is demonstrated 5 times without any detectible loss in activity.

  1. Self-Assembly of Crystalline Structures of Magnetic Core-Shell Nanoparticles for Fabrication of Nanostructured Materials.

    Science.gov (United States)

    Xue, Xiaozheng; Wang, Jianchao; Furlani, Edward P

    2015-10-14

    A theoretical study is presented of the template-assisted formation of crystalline superstructures of magnetic-dielectric core-shell particles. The templates produce highly localized gradient fields and a corresponding magnetic force that guides the assembly with nanoscale precision in particle placement. The process is studied using two distinct and complementary computational models that predict the dynamics and energy of the particles, respectively. Both mono- and polydisperse colloids are studied, and the analysis demonstrates for the first time that although the particles self-assemble into ordered crystalline superstructures, the particle formation is not unique. There is a Brownian motion-induced degeneracy in the process wherein various distinct, energetically comparable crystalline structures can form for a given template geometry. The models predict the formation of hexagonal close packed (HCP) and face centered cubic (FCC) structures as well as mixed phase structures due to in-plane stacking disorders, which is consistent with experimental observations. The polydisperse particle structures are less uniform than the monodisperse particle structures because of the irregular packing of different-sized particles. A comparison of self-assembly using soft- and hard-magnetic templates is also presented, the former being magnetized in a uniform field. This analysis shows that soft-magnetic templates enable an order-of-magnitude more rapid assembly and much higher spatial resolution in particle placement than their hard-magnetic counterparts. The self-assembly method discussed is versatile and broadly applies to arbitrary template geometries and multilayered and multifunctional mono- and polydisperse core-shell particles that have at least one magnetic component. As such, the method holds potential for the bottom-up fabrication of functional nanostructured materials for a broad range of applications. This work provides unprecedented insight into the assembly

  2. An active homopolar magnetic bearing with high temperature superconductor (HTS) coils and ferromagnetic cores

    Science.gov (United States)

    Brown, G. V.; Dirusso, E.; Provenza, A. J.

    1995-01-01

    A proof-of-feasibility demonstration showed that high temperature superconductor (HTS) coils can be used in a high-load, active magnetic bearing in liquid nitrogen. A homopolar radial bearing with commercially wound HTS (Bi 2223) bias and control coils produced over 200 lb (890 N) radial load capacity (measured non-rotating) and supported a shaft to 14000 rpm. The goal was to show that HTS coils can operate stably with ferromagnetic cores in a feedback controlled system at a current density similar to that in Cu in liquid nitrogen. Design compromises permitted use of circular coils with rectangular cross section. Conductor improvements will eventually permit coil shape optimization, higher current density and higher bearing load capacity. The bias coil, wound with non-twisted, multifilament HTS conductor, required negligible power to carry its direct current. The control coils were wound with monofilament HTS sheathed in Ag. These dissipated negligible power for direct current (i.e. for steady radial load components). When an alternating current (AC) was added, the AC component dissipated power which increased rapidly with frequency and quadratically with AC amplitude. In fact at frequencies above about 2 hz, the effective resistance of the control coil conductor actually exceeds that of the silver which is in electrical parallel with the oxide superconductor. This is at least qualitatively understandable in the context of a Bean-type model of flux and current penetration into a Type II superconductor. Fortunately the dynamic currents required for bearing stability are of small amplitude. These results show that while twisted multifilament conductor is not needed for stable levitation, twisted multifilaments will be required to reduce control power for sizable dynamic loads, such as those due to unbalance.

  3. Application of magnetic and core-shell nanoparticles to determine enrofloxacin and its metabolite using laser induced fluorescence microscope.

    Science.gov (United States)

    Kim, Suji; Ko, Junga; Lim, H B

    2013-04-10

    A unique analytical method using nanoparticles and laser-induced fluorescence microscopy (LIFM) was developed to determine enrofloxacin in this work. For sample pretreatment, two different kinds of particles, i.e., synthesized dye-doped core-shell silica nanoparticles and magnetic micro-particles (MPs), were used for fluorescent tagging and concentrating the enrofloxacin, respectively. The antibody of enrofloxacin was immobilized on the synthesized FITC-doped core-shell nanoparticles, and the enrofloxacin target was extracted by the MPs. At this moment, the average number of antibodies on each core-shell silica nanoparticle was ~0.9, which was determined by the fluorescence ratiometric method. The described method was demonstrated for a meat sample to determine enrofloxacin using LIFM, and the result was compared with enzyme-linked immunosorbent assay (ELISA). The developed technique allowed the simplified analytical procedure, improved the detection limit about 54-fold compared to ELISA.

  4. Improved soft magnetic properties in nanocrystalline FeCuNbSiB Nanophy® cores by intense magnetic field annealing

    Science.gov (United States)

    Madugundo, Rajasekhar; Geoffroy, Olivier; Waeckerle, Thierry; Frincu, Bianca; Kodjikian, Stéphanie; Rivoirard, Sophie

    2017-01-01

    The effect of high external magnetic field (up to 7 T) on soft magnetic properties in nanocrystalline Fe74.1Si15.7Nb3.1B6.1Cu1 Nanophy® cores has been investigated. The as-quenched amorphous ribbons were nanocrystallized by annealing between 540 and 620 °C in transverse magnetic field. By varying annealing field from 0 to 7 T, induced anisotropy ranging from as low as 4 J/m3 to as high as 41 J/m3 is obtained. It is responsible for an increase in the cut-off frequency up to 300 kHz when the material is submitted to dynamic magnetic excitations. A minimum coercivity of 0.74 A/m is observed in the core annealed in 1 T associated to low losses. The relative permeability decreases on increasing the annealing field intensity with a minimum value of 13,654 at 7 T. Such permeability level opens the way to new applications of the Nanophy® alloys.

  5. Synthesis and magnetic properties of core/shell FeO/Fe3O4 nano-octopods

    Science.gov (United States)

    Khurshid, Hafsa; Chandra, Sayan; Li, Wanfeng; Phan, M. H.; Hadjipanayis, G. C.; Mukherjee, P.; Srikanth, H.

    2013-05-01

    We report the synthesis and magnetic properties of core/shell FeO/Fe3O4 nanoparticles with an average size of 30 nm in a complex quasi-octopod shape. FeO nanoparticles were synthesized by a wet chemical synthesis route followed by partial oxidation to form core/shell structured FeO/Fe3O4 octopods. X-ray diffraction and transmission electron microscopy confirmed the presence of iron oxide phases and the formed core/shell FeO/Fe3O4 morphology. Magnetic measurements revealed two distinct temperatures corresponding to the thermally activated Verwey transition (TV ˜ 120 K) of the ferrimagnetic Fe3O4 shell and the Neel temperature (TN ˜ 230 K) of the antiferromagnetic FeO core. The nanoparticles exhibited a strong horizontal shift in the field-cooled hysteresis loop (the so-called exchange bias (EB) effect) accompanied by enhanced coercivity. The Meiklejohn-Bean model has been implemented to quantify the amount of frozen spins that locate at the interface between FeO and Fe3O4 and are responsible for the observed EB effect.

  6. Magnetic Inhibition of Convection and the Fundamental Properties of Low-Mass Stars. I. Stars with a Radiative Core

    CERN Document Server

    Feiden, Gregory A

    2013-01-01

    Magnetic fields are hypothesized to inflate the radii of low-mass stars---defined as less massive than 0.8 solar masses---in detached eclipsing binaries (DEBs). We investigate this hypothesis using the recently introduced magnetic Dartmouth stellar evolution code. In particular, we focus on stars thought to have a radiative core and convective outer envelope by studying in detail three individual DEBs: UV Psc, YY Gem, and CU Cnc. The results suggest that the stabilization of thermal convection by a magnetic field is a plausible explanation for the observed model-radius discrepancies. However, surface magnetic field strengths required by the models are significantly stronger than those estimated from the observed coronal X-ray emission. Agreement between model predicted surface magnetic field strengths and those inferred from X-ray observations can be found by assuming that the magnetic field sources its energy from convection. This approach makes the transport of heat by convection less efficient and is akin ...

  7. Magnetic behaviors of a transverse spin-1/2 Ising cubic nanowire with core/shell structure

    Science.gov (United States)

    El Hamri, M.; Bouhou, S.; Essaoudi, I.; Ainane, A.; Ahuja, R.; Dujardin, F.

    2017-02-01

    The surface shell exchange coupling effect on the magnetic properties (surface shell, core, total longitudinal and total transverse magnetizations, susceptibility, phase diagram and hysteresis loops) of a transverse spin-1/2 Ising cubic nanowire is investigated, in the present work, by employing the effective-field theory based on the probability distribution technique with correlations, for both ferro- and antiferromagnetic cases. We have found that this parameter has a strong effect on the magnetic properties in both cases. In the ferromagnetic case, the total longitudinal magnetization curves display Q- and S-type behaviors and the hysteresis loop has just one loop, whereas in the antiferromagnetic case, the N-type behavior, in which one compensation temperature appears below the critical temperature, exists in the total longitudinal magnetization curve versus reduced temperature, and triple hysteresis loops are found. The effect of applied field is also investigated on the total longitudinal magnetization for the both cases, and we have found that a large applied field value can overcome the antiferromagnetic coupling leading to a ferromagnetic-like behavior.

  8. Near-infrared-absorbing gold nanopopcorns with iron oxide cluster core for magnetically amplified photothermal and photodynamic cancer therapy.

    Science.gov (United States)

    Bhana, Saheel; Lin, Gan; Wang, Lijia; Starring, Hunter; Mishra, Sanjay R; Liu, Gang; Huang, Xiaohua

    2015-06-03

    We present the synthesis and application of a new type of dual magnetic and plasmonic nanostructures for magnetic-field-guided drug delivery and combined photothermal and photodynamic cancer therapy. Near-infrared-absorbing gold nanopopcorns containing a self-assembled iron oxide cluster core were prepared via a seed-mediated growth method. The hybrid nanostructures are superparamagnetic and show great photothermal conversion efficiency (η=61%) under near-infrared irradiation. Compact and stable nanocomplexes for photothermal-photodynamic therapy were formed by coating the nanoparticles with near-infrared-absorbing photosensitizer silicon 2,3-naphthalocyannie dihydroxide and stabilization with poly(ethylene glycol) linked with 11-mercaptoundecanoic acid. The nanocomplex showed enhanced release and cellular uptake of the photosensitizer with the use of a gradient magnetic field. In vitro studies using two different cell lines showed that the dual mode photothermal and photodynamic therapy with the assistance of magnetic-field-guided drug delivery dramatically improved the therapeutic efficacy of cancer cells as compared to the combination treatment without using a magnetic field and the two treatments alone. The "three-in-one" nanocomplex has the potential to carry therapeutic agents deep into a tumor through magnetic manipulation and to completely eradicate tumors by subsequent photothermal and photodynamic therapies without systemic toxicity.

  9. Suzuki cross-coupling reactions on the surface of carbon-coated cobalt: expanding the applicability of core-shell nano-magnets.

    Science.gov (United States)

    Tan, Chun Ghee; Grass, Robert N

    2008-09-28

    To develop magnetic nanomaterials applicable to organic synthesis, the Suzuki cross-coupling method was adapted to attach a range of functional groups to carbon-coated core-shell materials via commercially-available substituted arylboronic acids.

  10. Animal MRI Core

    Data.gov (United States)

    Federal Laboratory Consortium — The Animal Magnetic Resonance Imaging (MRI) Core develops and optimizes MRI methods for cardiovascular imaging of mice and rats. The Core provides imaging expertise,...

  11. Relationship between chemical composition and magnetic susceptibility in sediment cores from Central Indian Ocean Basin

    Digital Repository Service at National Institute of Oceanography (India)

    Pattan, J.N.; Parthiban, G.; Banakar, V.K.; Tomer, A.; Kulkarni, M.

    , Ti and Mn concentrations. The calcareous ooze core exhibit lowest Chi (12.32 x 10 sup(-7) m sup(3) kg sup(-1)), Al (2.84%), Fe (1.63%) and Ti (0.14%), terrigenous clay core with moderate Chi (29.93 x 10 sup(-7) m sup(3) kg sup(-1)) but highest Al (6...

  12. Magnetic properties of the 2D Fen core Xm (X = C, N, O, Cl, S and F) shell clusters embedded in graphene

    Science.gov (United States)

    Zhao, Ming-Yu; Zhao, Ru-Meng; Li, Wei; Ma, Ya-Qiang; Wang, Tian-Xing; Dai, Xian-Qi

    2017-01-01

    Utilizing first-principle calculations, the structural, electronic and magnetic properties of monolayer graphene embedded with Fen/Xm (X = C, N, O, Cl, S and F) core/shell clusters are investigated, where n = 1, 2, 3 and m = 4, 6, respectively. We find that the graphene embedding with the Fen/Xm core/shell clusters are magnetic except the Fe/S4, Fe2/C4 and Fe3/Cl6 core/shell clusters. The graphene embedding with the Fe3/F6 core/shell cluster has the largest magnetic moment in these systems. Magnetism for Fen/Xm core/shell clusters embedded in monolayer graphene can be ascribed to the ferromagnetic coupling between the Fe atoms. Our calculations demonstrate that Fe atoms are successfully isolated at various C, N, O, Cl, S and F shells in graphene to preserve the high-spin state. On the other hand, the high-spin state is also effectively controlled by the amount of Fe atoms. The electron spin can be stored in magnetic thin film, lithographically prepared quantum dots, and electromagnetic traps. The Fen/Xm core/shell clusters embedded in graphene can be considered to have potential applications in nanoelectronics, spintronics and magnetic storage devices.

  13. Magnetic field activated drug delivery using thermodegradable azo-functionalised PEG-coated core-shell mesoporous silica nanoparticles

    Science.gov (United States)

    Saint-Cricq, P.; Deshayes, S.; Zink, J. I.; Kasko, A. M.

    2015-07-01

    Core-shell Fe3O4@SiO2 mesoporous silica nanoparticles coated with a new thermodegradable polymer allowed the release of a model drug through heating caused by a high frequency oscillating magnetic field. The thermodegradable polymer was made of poly(ethylene glycol) (PEG) functionalised with azo bonds that break with an elevation of temperature.Core-shell Fe3O4@SiO2 mesoporous silica nanoparticles coated with a new thermodegradable polymer allowed the release of a model drug through heating caused by a high frequency oscillating magnetic field. The thermodegradable polymer was made of poly(ethylene glycol) (PEG) functionalised with azo bonds that break with an elevation of temperature. Electronic supplementary information (ESI) available: Detailed synthesis of the polymers, core-shell nanoparticles and their functionalisation; 1H-NMR spectrum of Azo-PEG GPC, MALDI-TOF, DSC, TGA of the polymers; real time release profile; cell viability assay; release experiment set-up. See DOI: 10.1039/c5nr03777h

  14. Synthesis and microwave absorption properties of yolk-shell microspheres with magnetic iron oxide cores and hierarchical copper silicate shells.

    Science.gov (United States)

    Liu, Jiwei; Cheng, Jin; Che, Renchao; Xu, Junjie; Liu, Mengmei; Liu, Zhengwang

    2013-04-10

    Yolk-shell microspheres with magnetic Fe3O4 cores and hierarchical copper silicate shells have been successfully synthesized by combining the versatile sol-gel process and hydrothermal reaction. Various yolk-shell microspheres with different core size and shell thickness can be readily synthesized by varying the experimental conditions. Compared to pure Fe3O4, the as-synthesized yolk-shell microspheres exhibit significantly enhanced microwave absorption properties in terms of both the maximum reflection loss value and the absorption bandwidth. The maximum reflection loss value of these yolk-shell microspheres can reach -23.5 dB at 7 GHz with a thickness of 2 mm, and the absorption bandwidths with reflection loss lower than -10 dB are up to 10.4 GHz. Owing to the large specific surface area, high porosity, and synergistic effect of both the magnetic Fe3O4 cores and hierarchical copper silicate shells, these unique yolk-shell microspheres may have the potential as high-efficient absorbers for microwave absorption applications.

  15. Bifunctional luminescent and magnetic core/shell type nanostructures Fe3O4@CeF3 :Tb3+/Si

    Institute of Scientific and Technical Information of China (English)

    M. Runowski; T. Grzyb, S. Lis

    2011-01-01

    A facile co-precipitation and microemulsion methods were applied to obtain core/shell type nanoparticles.Cerium fluoride doped with terbium(Ⅲ) ions supplied intensive green luminescence of the system.Due to the presence of magnetite nanoparticles as cores,the product was highly sensitive to external magnetic field.Both sorts of nanostructures were encapsulated by silica shell.Such external layer of inert oxide can potentially increase the resistance of prepared nanostructures to thermal oxidation,aggressive agents,changing of pH or destructive radiation.Morphology of the product was examined using transmission electron microscopy (TEM).Formations of the core/shell type nanostructures were clearly seen in the TEM pictures.Powder X-ray diffraction (XRD) confirmed the structure of the products,their nanocrystallinity and amorphous nature of silica shell.Optical properties were investigated by measuring excitation and emission spectra.Such multifunctional luminescent and magnetic nanoparticles coated with easily functionalized silica shell could be applied in many field of science.

  16. Multifunctional plasmonic shell-magnetic core nanoparticles for targeted diagnostics, isolation, and photothermal destruction of tumor cells.

    Science.gov (United States)

    Fan, Zhen; Shelton, Melanie; Singh, Anant Kumar; Senapati, Dulal; Khan, Sadia Afrin; Ray, Paresh Chandra

    2012-02-28

    Cancer is the greatest challenge in human healthcare today. Cancer causes 7.6 million deaths and economic losses of around 1 trillion dollars every year. Early diagnosis and effective treatment of cancer are crucial for saving lives. Driven by these needs, we report the development of a multifunctional plasmonic shell-magnetic core nanotechnology-driven approach for the targeted diagnosis, isolation, and photothermal destruction of cancer cells. Experimental data show that aptamer-conjugated plasmonic/magnetic nanoparticles can be used for targeted imaging and magnetic separation of a particular kind of cell from a mixture of different cancer cells. A targeted photothermal experiment using 670 nm light at 2.5 W/cm(2) for 10 min resulted selective irreparable cellular damage to most of the cancer cells. We also showed that the aptamer-conjugated magnetic/plasmonic nanoparticle-based photothermal destruction of cancer cells is highly selective. We discuss the possible mechanism and operating principle for the targeted imaging, separation, and photothermal destruction using magnetic/plasmonic nanotechnology.

  17. Metal-based magnetic fluids with core-shell structure FeB@SiO2 amorphous particles.

    Science.gov (United States)

    Yu, Mengchun; Bian, Xiufang; Wang, Tianqi; Wang, Junzhang

    2017-09-27

    FeB@SiO2 amorphous particles were firstly introduced into Ga85.8In14.2 alloys to prepare metal-based magnetic fluids. The morphology of the FeB amorphous particles is spherical with an average particle size of about 190 nm. The shape of the particles is regular and the particle size is homogeneous. Stable core-shell structure SiO2 modified FeB amorphous particles are obtained and the thickness of the SiO2 coatings is observed to be about 40 nm. The results of VSM confirm that the saturation magnetization of the FeB amorphous particles is 131.5 emu g(-1), which is almost two times higher than that of the Fe3O4 particles. The saturation magnetization of the FeB@SiO2 amorphous particles is 106.9 emu g(-1), an approximate decrease of 18.7% due to the non-magnetic SiO2 coatings. The results from the torsional oscillation viscometer show that the metal-based magnetic fluids with FeB amorphous particles exhibit a desirable high temperature performance and are ideal candidates for high temperature use.

  18. An Optimized Air-Core Coil Sensor with a Magnetic Flux Compensation Structure Suitable to the Helicopter TEM System

    Directory of Open Access Journals (Sweden)

    Chen Chen

    2016-04-01

    Full Text Available The air-core coil sensor (ACS is widely used as a transducer to measure the variation in magnetic fields of a helicopter transient electromagnetic (TEM system. A high periodic emitting current induces the magnetic field signal of the underground medium. However, such current also generates a high primary field signal that can affect the received signal of the ACS and even damage the receiver. To increase the dynamic range of the received signal and to protect the receiver when emitting current rises/falls, the combination of ACS with magnetic flux compensation structure (bucking coil is necessary. Moreover, the optimized ACS, which is composed of an air-core coil and a differential pre-amplifier circuit, must be investigated to meet the requirements of the helicopter TEM system suited to rapid surveying for shallow buried metal mine in rough topography. Accordingly, two ACSs are fabricated in this study, and their performance is verified and compared inside a magnetic shielding room. Using the designed ACSs, field experiments are conducted in Baoqing County. The field experimental data show that the primary field response can be compensated when the bucking coil is placed at an appropriate point in the range of allowed shift distance beyond the center of the transmitting coil and that the damage to the receiver induced by the over-statured signal can be solved. In conclusion, a more suitable ACS is adopted and is shown to have better performance, with a mass of 2.5 kg, resultant effective area of 11.6 m2 (i.e., diameter of 0.496 m, 3 dB bandwidth of 66 kHz, signal-to-noise ratio of 4 (i.e., varying magnetic field strength of 0.2 nT/s, and normalized equivalent input noise of 3.62 nV/m2.

  19. Novel core-shell cerium(IV)-immobilized magnetic polymeric microspheres for selective enrichment and rapid separation of phosphopeptides.

    Science.gov (United States)

    Wang, Zhi-Gang; Cheng, Gong; Liu, Yan-Lin; Zhang, Ji-Lin; Sun, De-Hui; Ni, Jia-Zuan

    2014-03-01

    In this work, novel magnetic polymeric core-shell structured microspheres with immobilized Ce(IV), Fe3O4@SiO2@PVPA-Ce(IV), were designed rationally and synthesized successfully via a facile route for the first time. Magnetic Fe3O4@SiO2 microspheres were first prepared by directly coating a thin layer of silica onto Fe3O4 magnetic particles using a sol-gel method, a poly(vinylphosphonic acid) (PVPA) shell was then coated on the Fe3O4@SiO2 microspheres to form Fe3O4@SiO2@PVPA microspheres through a radical polymerization reaction, and finally Ce(IV) ions were robustly immobilized onto the Fe3O4@SiO2@PVPA microspheres through strong chelation between Ce(IV) ions and phosphate moieties in the PVPA. The applicability of the Fe3O4@SiO2@PVPA-Ce(IV) microspheres for selective enrichment and rapid separation of phosphopeptides from proteolytic digests of standard and real protein samples was investigated. The results demonstrated that the core-shell structured Fe3O4@SiO2@PVPA-Ce(IV) microspheres with abundant Ce(IV) affinity sites and excellent magnetic responsiveness can effectively purify phosphopeptides from complex biosamples for MS detection taking advantage of the rapid magnetic separation and the selective affinity between Ce(IV) ions and phosphate moieties of the phosphopeptides. Furthermore, they can be effectively recycled and show good reusability, and have better performance than commercial TiO2 beads and homemade Fe3O4@PMAA-Ce(IV) microspheres. Thus the Fe3O4@SiO2@PVPA-Ce(IV) microspheres can benefit greatly the mass spectrometric qualitative analysis of phosphopeptides in phosphoproteome research.

  20. Magnetic heating properties and neutron activation of tungsten-oxide coated biocompatible FePt core-shell nanoparticles.

    Science.gov (United States)

    Seemann, K M; Luysberg, M; Révay, Z; Kudejova, P; Sanz, B; Cassinelli, N; Loidl, A; Ilicic, K; Multhoff, G; Schmid, T E

    2015-01-10

    Magnetic nanoparticles are highly desirable for biomedical research and treatment of cancer especially when combined with hyperthermia. The efficacy of nanoparticle-based therapies could be improved by generating radioactive nanoparticles with a convenient decay time and which simultaneously have the capability to be used for locally confined heating. The core-shell morphology of such novel nanoparticles presented in this work involves a polysilico-tungstate molecule of the polyoxometalate family as a precursor coating material, which transforms into an amorphous tungsten oxide coating upon annealing of the FePt core-shell nanoparticles. The content of tungsten atoms in the nanoparticle shell is neutron activated using cold neutrons at the Heinz Maier-Leibnitz (FRMII) neutron facility and thereby transformed into the radioisotope W-187. The sizeable natural abundance of 28% for the W-186 precursor isotope, a radiopharmaceutically advantageous gamma-beta ratio of γβ≈30% and a range of approximately 1mm in biological tissue for the 1.3MeV β-radiation are promising features of the nanoparticles' potential for cancer therapy. Moreover, a high temperature annealing treatment enhances the magnetic moment of nanoparticles in such a way that a magnetic heating effect of several degrees Celsius in liquid suspension - a prerequisite for hyperthermia treatment of cancer - was observed. A rise in temperature of approximately 3°C in aqueous suspension is shown for a moderate nanoparticle concentration of 0.5mg/ml after 15min in an 831kHz high-frequency alternating magnetic field of 250Gauss field strength (25mT). The biocompatibility based on a low cytotoxicity in the non-neutron-activated state in combination with the hydrophilic nature of the tungsten oxide shell makes the coated magnetic FePt nanoparticles ideal candidates for advanced radiopharmaceutical applications.

  1. The magnetic structure of neutron stars and their surface-to-core temperature relation

    CERN Document Server

    Potekhin, A Yu; Chabrier, G

    2005-01-01

    We study the relation between the mean effective surface temperature T_s and the internal temperature T_b for magnetic neutron stars, assuming that the magnetic field near the surface has a presumably small-scale structure. The heavy-element (iron) and light-element (accreted) heat-blanketing envelopes are considered, and the results are compared with the case of a dipole magnetic field. We argue that the difference in the T_b(T_s)-relation for different magnetic configurations is always much smaller than a possible difference caused by variations of the chemical composition in the envelope.

  2. Ultrafast magnetic vortex core switching driven by the topological inverse Faraday effect.

    Science.gov (United States)

    Taguchi, Katsuhisa; Ohe, Jun-ichiro; Tatara, Gen

    2012-09-21

    We present a theoretical discovery of an unconventional mechanism of inverse Faraday effect which acts selectively on topological magnetic structures. The effect, topological inverse Faraday effect, is induced by the spin Berry's phase of the magnetic structure when a circularly polarized light is applied. Thus a spin-orbit interaction is not necessary unlike that in the conventional inverse Faraday effect. We demonstrate by numerical simulation that topological inverse Faraday effect realizes ultrafast switching of a magnetic vortex within a switching time of 150 ps without magnetic field.

  3. One-pot synthesis of magnetic graphene nanocomposites decorated with core@double-shell nanoparticles for fast chromium removal.

    Science.gov (United States)

    Zhu, Jiahua; Wei, Suying; Gu, Hongbo; Rapole, Sowjanya B; Wang, Qiang; Luo, Zhiping; Haldolaarachchige, Neel; Young, David P; Guo, Zhanhu

    2012-01-17

    A facile thermodecomposition process to synthesize magnetic graphene nanocomposites (MGNCs) is reported. High-resolution transmission electron microscopy and energy filtered elemental mapping revealed a core@double-shell structure of the nanoparticles with crystalline iron as the core, iron oxide as the inner shell and amorphous Si-S-O compound as the outer shell. The MGNCs demonstrate an extremely fast Cr(VI) removal from the wastewater with a high removal efficiency and with an almost complete removal of Cr(VI) within 5 min. The adsorption kinetics follows the pseudo-second-order model and the novel MGNC adsorbent exhibits better Cr(VI) removal efficiency in solutions with low pH. The large saturation magnetization (96.3 emu/g) of the synthesized nanoparticles allows fast separation of the MGNCs from liquid suspension. By using a permanent magnet, the recycling process of both the MGNC adsorbents and the adsorbed Cr(VI) is more energetically and economically sustainable. The significantly reduced treatment time required to remove the Cr(VI) and the applicability in treating the solutions with low pH make MGNCs promising for the efficient removal of heavy metals from the wastewater.

  4. MoS2-Gd Chelate Magnetic Nanomaterials with Core-Shell Structure Used as Contrast Agents in in Vivo Magnetic Resonance Imaging.

    Science.gov (United States)

    Anbazhagan, Rajeshkumar; Su, Yu-An; Tsai, Hsieh-Chih; Jeng, Ru-Jong

    2016-01-27

    Despite their frequent usages as contrast agents for in vivo MRI imaging, paramagnetic molecules continue to suffer from low resolution, physicochemical instability, and high toxicity. Herein, we present a molybdenum disulfide and gadolinium complex, as an alternative core-shell magnetic nanomaterial that exhibits enhanced paramagnetic property; 4.5-times longer water proton spin-lattice relaxation time (T1) when compared to commercial gadolinium contrast agents; as well as lowered toxicity, extended blood circulation time, increased stability, and desirable excretion characteristic. Transmission electron microscopy (TEM) revealed smooth core-shell nanoparticles 100 nm in size with a shell width of approximately 10 nm. These findings suggest that the synthesized nanomaterial possesses high potential as a positive contrast agent for the enhancement of MRI imaging.

  5. Ag@ZnO core-shell nanoparticles study by first principle: The structural, magnetic and optical properties

    Science.gov (United States)

    Cheng, Hai-Xia; Wang, Xiao-Xu; Hu, Yao-Wen; Song, Hong-Quan; Huo, Jin-Rong; Li, Lu; Qian, Ping; Song, Yu-Jun

    2016-12-01

    Ag@ZnO core-shell nanoparticles of around 72 atoms have been investigated by the density functional theory, revealing proving for the first time that the core-shell structure exhibits a shrinkage phenomenon from outer shell in agreement with the other studies in literatures. Our calculations predict that the Ag@ZnO core-shell structure is a ferromagnetic spin polarized state, and the magnetism mainly stems from the spin splitting of 2p electrons of O atoms. In addition, the total and partial DOS of Ag@ZnO indicate that the nanostructure is a half-metallic nanoparticle and has the characters of the p-type semiconductor. Furthermore, the optical properties calculations show that the absorption edge of Ag@ZnO have a red shift and good photocatalysis compare to that of the bulk ZnO. These results of the Ag@ZnO core-shell structure obtain a well agreement with the experimental measurement.

  6. Preparation and Magnetic Properties of Cu-Ni Core-shell Nanowires in Ion-track Templates

    Institute of Scientific and Technical Information of China (English)

    CHEN Yonghui; DUAN Jinglai; YAO Huijun; MO Dan; WANG Tieshan; SUN Youmei; LIU Jie

    2015-01-01

    Cu-Ni core-shell nanowires, with an inner Cu core diameter of about 60 nm and varying Ni shell thicknesses (10, 30, 50, 60, and 80 nm), were successfully fabricated in porous polycarbonate (PC) ion-track templates by a two-step etching and electrodeposition method. In our experiment, the thickness of Ni shell can be effectively tuned through the etching time of templates. The core-shell structure was conifrmed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The X-ray diffraction (XRD) pattern elucidates the co-existence of characteristic peaks for both Cu and Ni, indicating no other phases were formed during preparation. Magnetic hysteresis loops measured via vibrating sample magnetometry (VSM) revealed that Cu-Ni core-shell nanowires with thinner Ni shell exhibited obviously diamagnetic character and together with a weak ferromagnetic activity, whereas ferromagnetic behavior was primarily measured for the wires with thicker Ni shell. With increasing Ni shell thickness, the squareness and coercivity value became smaller due to the shape anisotropy and the formation of multi-domain structure.

  7. Air core notch-coil magnet with variable geometry for fast-field-cycling NMR.

    Science.gov (United States)

    Kruber, S; Farrher, G D; Anoardo, E

    2015-10-01

    In this manuscript we present details on the optimization, construction and performance of a wide-bore (71 mm) α-helical-cut notch-coil magnet with variable geometry for fast-field-cycling NMR. In addition to the usual requirements for this kind of magnets (high field-to-power ratio, good magnetic field homogeneity, low inductance and resistance values) a tunable homogeneity and a more uniform heat dissipation along the magnet body are considered. The presented magnet consists of only one machined metallic cylinder combined with two external movable pieces. The optimal configuration is calculated through an evaluation of the magnetic flux density within the entire volume of interest. The magnet has a field-to-current constant of 0.728 mT/A, allowing to switch from zero to 0.125 T in less than 3 ms without energy storage assistance. For a cylindrical sample volume of 35 cm(3) the effective magnet homogeneity is lower than 130 ppm.

  8. Exemplary professional practice: the core of a magnet® organization.

    Science.gov (United States)

    Luzinski, Craig

    2012-02-01

    This month, the director of the Magnet Recognition Program® provides an in-depth look at the Magnet® Model component exemplary professional practice, what it takes to establish such a practice, and how it can help organizations achieve extraordinary results.

  9. A Noninvasive Magnetic Stimulator Utilizing Secondary Ferrite Cores and Resonant Structures for Field Enhancement

    CERN Document Server

    Pradhan, Raunaq

    2016-01-01

    In this paper, secondary ferrite cores and resonant structures have been used for field enhancement. The tissue was placed between the double square source coil and the secondary ferrite core. Resonant coils were added which aided in modulating the electric field in the tissue. The field distribution in the tissue was measured using electromagnetic simulations and ex-vivo measurements with tissue. Calculations involve the use of finite element analysis (Ansoft HFSS) to represent the electrical properties of the physical structure. The setup was compared to a conventional design in which the secondary ferrite cores were absent. It was found that the induced electric field could be increased by 122%, when ferrite cores were placed below the tissue at 450 kHz source frequency. The induced electric field was found to be localized in the tissue, verified using ex-vivo experiments. This preliminary study maybe further extended to establish the verified proposed concept with different complicated body parts modelled...

  10. SPIN POLARIZATION AND MAGNETIC DICHROISM IN PHOTOEMISSION FROM CORE AND VALENCE STATES IN LOCALIZED MAGNETIC SYSTEMS .3. ANGULAR-DISTRIBUTIONS

    NARCIS (Netherlands)

    THOLE, BT; VANDERLAAN, G

    1994-01-01

    A general analysis is presented for angle-dependent photoemission from magnetic and oriented atoms using linearly and circularly polarized x-rays. The anisotropy in the angular distribution in a localized material is due to the polarization of the photon, the polarization of the shell from which the

  11. Analytical core loss calculations for magnetic materials used in high frequency high power converter applications. Ph.D. Thesis - Toledo Univ.

    Science.gov (United States)

    Triner, J. E.

    1979-01-01

    The basic magnetic properties under various operating conditions encountered in the state-of-the-art DC-AC/DC converters are examined. Using a novel core excitation circuit, the basic B-H and loss characteristics of various core materials may be observed as a function of circuit configuration, frequency of operation, input voltage, and pulse-width modulation conditions. From this empirical data, a mathematical loss characteristics equation is developed to analytically predict the specific core loss of several magnetic materials under various waveform excitation conditions.

  12. Strong vortex core pinning and Barkhausen-free magnetization response in thin Permalloy disks induced by implantation of 1 × 10{sup 4} Ga{sup +} ions

    Energy Technology Data Exchange (ETDEWEB)

    Fani Sani, F., E-mail: fanisani@ualberta.ca, E-mail: mark.freeman@ualberta.ca; Losby, J. E.; Diao, Z.; Parsons, L. C.; Burgess, J. A. J.; Hiebert, W. K.; Freeman, M. R., E-mail: fanisani@ualberta.ca, E-mail: mark.freeman@ualberta.ca [Department of Physics, University of Alberta, Edmonton, Alberta T6G 2G7 (Canada); National Institute for Nanotechnology (NINT), Edmonton, Alberta T6G 2M9 (Canada); Vick, D. [National Institute for Nanotechnology (NINT), Edmonton, Alberta T6G 2M9 (Canada)

    2014-05-07

    Artificial vortex core pinning sites are induced in thin Permalloy disks by point exposure to as few as 10 000 ions from a focused Ga{sup +} beam. These pinning sites yield a first-order change in the magnetization response of the disk. A single site can keep the vortex core pinned over an applied field range comparable to the vortex annihilation field of the unaltered disk. Several widely separated sites can work together to keep the core pinned in one place, while the Barkhausen effect is eliminated from the magnetization curve over a range approaching the saturation moment of the disk.

  13. Synthesis and characterization of fluorinated magnetic core-shell nanoparticles for inhibition of insulin amyloid fibril formation

    Energy Technology Data Exchange (ETDEWEB)

    Skaat, Hadas; Margel, Shlomo [Department of Chemistry, Bar-Ilan University, Ramat-Gan 52900 (Israel); Belfort, Georges [Howard P Isermann Department of Chemical and Biological Engineering, Rensselaer Polytechnic Institute, Troy, NY 12180 (United States)], E-mail: ch348@mail.biu.ac.il, E-mail: belfog@rpi.edu, E-mail: Shlomo.margel@mail.biu.ac.il

    2009-06-03

    Maghemite ({gamma}-Fe{sub 2}O{sub 3}) magnetic nanoparticles of 15.0 {+-} 2.1 nm are formed by nucleation followed by controlled growth of maghemite thin films on gelatin-iron oxide nuclei. Uniform magnetic {gamma}-Fe{sub 2}O{sub 3}/poly (2,2,3,3,4,4,4-heptafluorobutyl acrylate) ({gamma}-Fe{sub 2}O{sub 3}/PHFBA) core-shell nanoparticles are prepared by emulsion polymerization of the fluorinated monomer 2,2,3,3,4,4,4-heptafluorobutyl acrylate (HFBA) in the presence of the maghemite nanoparticles. The kinetics of the insulin fibrillation process in the absence and in the presence of the {gamma}-Fe{sub 2}O{sub 3}/PHFBA core-shell nanoparticles are elucidated. A significant direct slow transition from {alpha}-helix to {beta}-sheets during insulin fibril formation is observed in the presence of the {gamma}-Fe{sub 2}O{sub 3}/PHFBA nanoparticles. This is in contradiction to our previous manuscript, which illustrated that the {gamma}-Fe{sub 2}O{sub 3} core nanoparticles do not affect the kinetics of the formation of the insulin fibrils, and to other previous publications that describe acceleration of the fibrillation process by using various types of nanoparticles. These core-shell nanoparticles may therefore be also useful for the inhibition of conformational changes of other amyloidogenic proteins that lead to neurodegenerative diseases such as Alzheimer's, Parkinson's, Huntington's, mad cow and prion diseases.

  14. Enhanced microwave absorption properties and mechanism of core/shell structured magnetic nanoparticles/carbon-based nanohybrids

    Energy Technology Data Exchange (ETDEWEB)

    Qi, Xiaosi, E-mail: sci.xsqi@gzu.edu.cn [Physics Department, Guizhou University, Guiyang 550025 (China); Nanjing National Laboratory of Microstructures and Jiangsu Provincial Laboratory for NanoTechnology, Nanjing University, Nanjing 210093 (China); Hu, Qi; Xu, Jianle; Xie, Ren; Bai, Zhongchen; Jiang, Yang; Qin, Shuijie [Physics Department, Guizhou University, Guiyang 550025 (China); Zhong, Wei, E-mail: wzhong@nju.edu.cn [Nanjing National Laboratory of Microstructures and Jiangsu Provincial Laboratory for NanoTechnology, Nanjing University, Nanjing 210093 (China); Du, Youwei [Nanjing National Laboratory of Microstructures and Jiangsu Provincial Laboratory for NanoTechnology, Nanjing University, Nanjing 210093 (China)

    2016-09-15

    Graphical abstract: In the article, core/shell Fe{sub 3}O{sub 4}/C, Fe/helical carbon nanotubes were synthesized selectively. The results indicated that the optimum reflection loss (RL) could reach −47.1 dB at 17.39 GHz with a matching thickness of 1.39 mm. The absorption bandwidth with the RL below −20 dB was up to 11.59 GHz. Moreover, based on the obtained results, the possibly enhanced microwave absorption mechanisms were also discussed in detail. - Highlights: • An efficient scheme was designed to synthesize core/shell magnetic nanoparticles/carbon-based hybrids. • By controlling the temperature, different categories of core/shell nanohybrids were synthesized. • The obtained Fe/CNT hybrid exhibits enhanced microwave absorption property. • Enhanced microwave absorbing mechanism was discussed in detail. - Abstract: An efficient scheme was designed to selectively synthesize different categories of core/shell structured magnetic nanoparticles/carbon-based nanohybrids such as Fe{sub 3}O{sub 4}/C and Fe/helical carbon nanotubes (HCNTs) through the decomposition of acetylene directly over Fe{sub 2}O{sub 3} nanotubes by controlling the pyrolysis temperature. The measured electromagnetic parameters indicated that the Fe/HCNT nanohybrids exhibited enhanced microwave absorption properties, which may be related to their special structures. The optimum reflection loss (RL) could reach −47.1 dB at 17.39 GHz with a matching thickness of 1.39 mm. The absorption bandwidth with the RL values below −20 dB was up to 11.59 GHz. Moreover, based on the obtained results, the possible enhanced EM absorption mechanisms were also discussed in detail. The results show excellent microwave absorption materials that are lightweight, have strong absorption and a wide absorption frequency band may be realized in these nanohybrids.

  15. Equilibrium reconstruction based on core magnetic measurement and its applications on equilibrium transition in Joint-TEXT tokamak

    Science.gov (United States)

    Chen, J.; Zhuang, G.; Jian, X.; Li, Q.; Liu, Y.; Gao, L.; Wang, Z. J.

    2014-10-01

    Evaluation and reconstruction of plasma equilibrium, especially to resolve the safety factor profile, is imperative for advanced tokamak operation and physics study. Based on core magnetic measurement by the high resolution laser polarimeter-interferometer system (POLARIS), the equilibrium of Joint-TEXT (J-TEXT) plasma is reconstructed and profiles of safety factor, current density, and electron density are, therefore, obtained with high accuracy and temporal resolution. The equilibrium reconstruction procedure determines the equilibrium flux surfaces essentially from the data of POLARIS. Refraction of laser probe beam, a major error source of the reconstruction, has been considered and corrected, which leads to improvement of accuracy more than 10%. The error of reconstruction has been systematically assessed with consideration of realistic diagnostic performance and scrape-off layer region of plasma, and its accuracy has been verified. Fast equilibrium transitions both within a single sawtooth cycle and during the penetration of resonant magnetic perturbation have been investigated.

  16. Monte Carlo study of magnetic and thermodynamic properties of a ferrimagnetic Ising nanoparticle with hexagonal core-shell structure

    Science.gov (United States)

    Wang, Wei; Chen, Dong-dong; Lv, Dan; Liu, Jin-ping; Li, Qi; Peng, Zhou

    2017-09-01

    The Monte Carlo method has been used to study the magnetic and thermodynamic properties of a hexagonal ferrimagnetic Ising nanoparticle with spin-3/2 inner core surrounded by spin-1 surface shell layers. The effects of exchange couplings and crystal-fields on the compensation behaviors and critical phenomena of the system have been investigated in detail. Many types of the magnetization curves have been found, depending on the competitions among the exchange couplings, the crystal-fields and the temperature. The phase diagrams for different exchange couplings and crystal-fields have been also obtained. In Particular, we have discovered the double and triple hysteresis loops for certain physical parameters in the present system. An excellent agreement has been achieved from the comparison between our results and the previous studies.

  17. External magnetic field dependent shift of superparamagnetic blocking temperature due to core/surface disordered spin interactions

    Science.gov (United States)

    Lee, Kwan; Jang, Jung-tak; Nakano, Hiroshi; Nakagawa, Shigeki; Paek, Sun Ha; Bae, Seongtae

    2017-02-01

    Although the blocking temperature of superparamagnetic nanoparticles (SPNPs) is crucial for various spintronics and biomedical applications, the precise determination of the blocking temperature is still not clear. Here, we present ‘intrinsic’ and ‘extrinsic’ characteristics of the blocking temperature in SPNP systems. In zero-field-cooled/field-cooled (ZFC-FC) curves, there was no shift of ‘intrinsic blocking temperature’ at different applied external (excitation) magnetic fields. However, ‘extrinsic blocking temperature’ shift is clearly dependent on the external (excitation) magnetic field. According to our newly proposed physical model, the ‘intermediate spin layer’ located between the core and surface disordered spin layers is primarily responsible for the physical nature of the shift of extrinsic blocking temperature. Our new findings offer possibilities for characterizing the thermally induced physical properties of SPNPs. Furthermore, these findings provide a new empirical approach to indirectly estimate the qualitative degree of the disordered surface spin status in SPNPs.

  18. The first 4d/4f single-molecule magnet containing a {Ru(III)2Dy(III)2} core.

    Science.gov (United States)

    Langley, Stuart K; Wielechowski, Daniel P; Vieru, Veacheslav; Chilton, Nicholas F; Moubaraki, Boujemaa; Chibotaru, Liviu F; Murray, Keith S

    2015-02-07

    We report the synthesis, structure and magnetic properties of the first 4d-4f single-molecule magnet. The complex [Ru(III)2Dy(III)2(OMe)2(O2CPh)4(mdea)2(NO3)2] displays a butterfly type core, with an anisotropy barrier of 10.7 cm(-1). Ab initio and DFT calculations provide insight into the observed magnetic behaviour.

  19. Zero-Bias-Field Spin Torque Induced Oscillation of a Vortex Core in a Magnetic Junction Nano-Pillar with High Magnetoresistance Ratio

    Science.gov (United States)

    Tsukahara, Hiroshi; Imamura, Hiroshi

    2017-06-01

    Spin torque induced dynamics of a vortex core in a magnetic junction nano-pillar is studied by paying special attention to the effect of the in-plane current due to the spatial variation of magnetization. We calculated the motion of the vortex core and the current distribution simultaneously. The current has a considerable in-plane component within the magnetic junction nano-pillar with a high magnetoresistance ratio, and the stable rotational motion of the vortex core is caused by a spin transfer torque from the in-plane current without a bias field when the magnetoresistance ratio is over 180%. It is shown that the zero-bias-field oscillation of the vortex core can be maintained if the magnetoresistance ratio and strength of the in-plane current exceed a certain critical value.

  20. Magnetic Fe2O3-polystyrene/PPy core/shell particles: bioreactivity and self-assembly.

    Science.gov (United States)

    Mangeney, Claire; Fertani, Meriem; Bousalem, Smain; Zhicai, Ma; Ammar, Souad; Herbst, Fréderic; Beaunier, Patricia; Elaissari, Abdelhamid; Chehimi, Mohamed M

    2007-10-23

    This paper describes the synthesis of new magnetic, reactive polystyrene/polypyrrole core/shell latex particles. The core consists of a polystyrene microsphere containing gamma-Fe2O3 superparamagnetic nanoparticles (PSmag), and the shell is made of reactive N-carboxylic acid-functionalized polypyrrole (PPyCOOH). These PSmag-PPyCOOH latex particles, average diameter 220 nm, were prepared by copolymerization of pyrrole (Py) and the active carboxyl-functionalized pyrrole (PyCOOH) in the presence of PSmag particles. PNVP was used as a steric stabilizer. The functionalized polypyrrole-coated PSmag particles were characterized in terms of their particle size, surface morphology, chemical composition, and electrochemical and magnetic properties using transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), cyclic voltammetry, and SQUID magnetometry. Activation of the particle surface carboxyl groups was achieved using 1-ethyl-3-(3-dimethylaminopropyl)-carbodiimide (EDC) and N-hydroxysuccinimide (NHS), which helps transform the carboxyl groups into activated ester groups (NSE). The activated particles, PSmag-PPyNSE, were further evaluated as bioadsorbents of biotin used as a model biomolecule. It was shown that biotin was immobilized at the surface of the PSmag-PPyNSE particles by forming interfacial amide groups. The assemblies of PSmag-PPyCOOH particles on glass plates were further investigated. When no magnetic field is applied, the particles assemble into 3D colloidal crystals. In contrast, under a magnetic field, one-particle-thick chains gathered in hedgehog-like architectures are obtained. Furthermore, PSmag-PPyCOOH coated ITO electrodes were shown to be electroactive and electrochemically stable, thus offering potentialities for creating novel high-specific-area materials for biosensing devices where the conducting polymer component would act as the transducer through its conductive properties.

  1. Cationic Mn4 single-molecule magnet with a sterically isolated core.

    Science.gov (United States)

    Heroux, Katie J; Quddusi, Hajrah M; Liu, Junjie; O'Brien, James R; Nakano, Motohiro; del Barco, Enrique; Hill, Stephen; Hendrickson, David N

    2011-08-15

    The synthesis, structure, and magnetic properties of a ligand-modified Mn(4) dicubane single-molecule magnet (SMM), [Mn(4)(Bet)(4)(mdea)(2)(mdeaH)(2)](BPh(4))(4), are presented, where the cationic SMM units are significantly separated from neighboring molecules in the crystal lattice. There are no cocrystallized solvate molecules, making it an ideal candidate for single-crystal magnetization hysteresis and high-frequency electron paramagnetic resonance studies. Increased control over intermolecular interactions in such materials is a crucial factor in the future application of SMMs.

  2. Local modification of the magnetic vortex-core velocity by gallium implantation

    Energy Technology Data Exchange (ETDEWEB)

    Langner, Hauke H., E-mail: hlangner@physnet.uni-hamburg.de; Vogel, Andreas; Beyersdorff, Björn [Institut für Angewandte Physik und Zentrum für Mikrostrukturforschung, Universität Hamburg, Jungiusstr. 11, 20355 Hamburg (Germany); Weigand, Markus [Max-Planck-Institut für Intelligente Systeme, Heisenbergstraße 3, 70596 Stuttgart (Germany); Frömter, Robert; Peter Oepen, Hans; Meier, Guido [Institut für Angewandte Physik und Zentrum für Mikrostrukturforschung, Universität Hamburg, Jungiusstr. 11, 20355 Hamburg (Germany); The Hamburg Centre for Ultrafast Imaging, Luruper Chaussee 149, 22761 Hamburg (Germany)

    2014-03-14

    The dynamics of magnetic vortices in microsquares with local modifications of magnetic parameters and thickness are investigated. By implanting gallium ions with focussed ion beam into permalloy thin-film elements, we have locally tailored their magnetic properties and the layer thickness. The vortex of the Landau domain pattern of a square is resonantly excited to a gyrotropic motion and crosses regions with and without implantation. With time-resolved scanning transmission x-ray microscopy, we observe an abrupt change in the vortex velocity close to the borders between the two regions.

  3. Functional Fe3O4/TiO2 core/shell magnetic nanoparticles as photokilling agents for pathogenic bacteria.

    Science.gov (United States)

    Chen, Wei-Jen; Tsai, Pei-Jane; Chen, Yu-Chie

    2008-04-01

    A photokilling approach for pathogenic bacteria is demonstrated using a new type of magnetic nanoprobe as the photokilling agent. In addition to their magnetic property, the nanoprobes have other features including a photocatalytic property and the capacity to target bacteria. The nanoprobes comprise iron oxide/titania (Fe(3)O(4)@TiO(2)) core/shell magnetic nanoparticles. As dopamine molecules can self-assemble onto the surface of the titania substrate, dopamine is used as the linker to immobilize succinic anhydride onto the surfaces of the Fe(3)O(4)@TiO(2) nanoparticles. This is followed by the immobilization of IgG via amide bonding. We demonstrate that the IgG-Fe(3)O(4)@TiO(2) magnetic nanoparticles not only have the capacity to target several pathogenic bacteria, but they also can effectively inhibit the cell growth of the bacteria targeted by the nanoparticles under irradiation of a low-power UV lamp within a short period. Staphylococcus saprophyticus, Streptococcus pyogenes, and antibiotic-resistant bacterial strains, such as multiantibiotic-resistant S. pyogenes and methicillin-resistant Staphylococcus aureus (MRSA), are used to demonstrate the feasibility of this approach.

  4. Development and characteristics of metallic magnetic powder cores in China%国内金属磁粉心的开发与特性

    Institute of Scientific and Technical Information of China (English)

    刘建廷

    2012-01-01

    金属磁粉心是一类重要的金属软磁材料.首先介绍了金属磁粉心的特点和一般应用.在此基础上重点介绍了我公司开发的系列金属磁粉心及其性能.最后展望了国内金属磁粉心的未来发展.%Metallic magnetic powder core is an important kind of soft magnetic materials. In this paper, the characteristics and applications of metallic magnetic powder cores were introduced firstly. On this basis, the series of metallic magnetic powder cores of our company and its properties were mainly described. Finally the author proposed the development prospects.

  5. Development and characteristics of metallic magnetic powder cores in China%国内金属磁粉心的开发与特性

    Institute of Scientific and Technical Information of China (English)

    刘建廷

    2013-01-01

      金属磁粉心是一类重要的金属软磁材料。首先介绍了金属磁粉心的特点和一般应用。在此基础上重点介绍了我公司开发的系列金属磁粉心及其性能。最后展望了国内金属磁粉心的未来发展。%  Metallic magnetic powder core is an important kind of soft magnetic materials. In this paper, the characteristics and applications of metallic magnetic powder cores were introduced firstly. On this basis, the series of metallic magnetic powder cores of our company and its properties were mainly described. Finally the author proposed the development prospects.

  6. Magnetic properties of variably serpentinized peridotites and their implication for the evolution of oceanic core complexes

    NARCIS (Netherlands)

    Maffione, M.; Morris, A.; Plümper, O.; van Hinsbergen, D.J.J.

    2014-01-01

    Serpentinization of ultramafic rocks during hydrothermal alteration at mid-ocean ridges profoundly changes the physical, chemical, rheological, and magnetic properties of the oceanic lithosphere. There is renewed interest in this process following the discovery of widespread exposures of serpentiniz

  7. Nano-magnetic particles used in biomedicine: core and coating materials.

    Science.gov (United States)

    Karimi, Z; Karimi, L; Shokrollahi, H

    2013-07-01

    Magnetic nanoparticles for medical applications have been developed by many researchers. Separation, immunoassay, drug delivery, magnetic resonance imaging and hyperthermia are enhanced by the use of suitable magnetic nanoparticles and coating materials in the form of ferrofluids. Due to their low biocompatibility and low dispersion in water solutions, nanoparticles that are used for biomedical applications require surface treatment. Various kinds of coating materials including organic materials (polymers), inorganic metals (gold, platinum) or metal oxides (aluminum oxide, cobalt oxide) have been attracted during the last few years. Based on the recent advances and the importance of nanomedicine in human life, this paper attempts to give a brief summary on the different ferrite nano-magnetic particles and coatings used in nanomedicine.

  8. Exchange-coupled fct-FePd/α-Fe nanocomposite magnets converted from Pd/Fe3O4 core/shell nanoparticles.

    Science.gov (United States)

    Liu, Fei; Dong, Yunhe; Yang, Wenlong; Yu, Jing; Xu, Zhichuan; Hou, Yanglong

    2014-11-10

    We report the controlled synthesis of exchange-coupled face-centered tetragonal (fct) FePd/α-Fe nanocomposite magnets with variable Fe concentration. The composite was converted from Pd/Fe3O4 core/shell nanoparticles through a high-temperature annealing process in a reducing atmosphere. The shell thickness of core/shell Pd/Fe3O4 nanoparticles could be readily tuned, and subsequently the concentration of Fe in nanocomposite magnets was controlled. Upon annealing reduction, the hard magnetic fct-FePd phase was formed by the interdiffusion between reduced α-Fe and face-centered cubic (fcc) Pd, whereas the excessive α-Fe remained around the fct-FePd grains, realizing exchange coupling between the soft magnetic α-Fe and hard magnetic fct-FePd phases. Magnetic measurements showed variation in the magnetic properties of the nanocomposite magnets with different compositions, indicating distinct exchange coupling at the interfaces. The coercivity of the exchange-coupled nanocomposites could be tuned from 0.7 to 2.8 kOe and the saturation magnetization could be controlled from 93 to 160 emu g(-1). This work provides a bottom-up approach using exchange-coupled nanocomposites for engineering advanced permanent magnets with controllable magnetic properties.

  9. Collapse and Fragmentation of Molecular Cloud Cores. IX. Magnetic Braking of Initially Filamentary Clouds

    Science.gov (United States)

    Boss, Alan P.

    2007-04-01

    The collapse and fragmentation of initially filamentary, magnetic molecular clouds are calculated in three dimensions with a gravitational, radiative hydrodynamics code. The code includes magnetic field effects in an approximate manner: magnetic pressure, tension, braking, and ambipolar diffusion are all modeled. The parameters varied are the ratio of the ambipolar diffusion time to the free-fall time at the center of the filamentary cloud (tad/tff=10, 20, or 106~∞), the cloud's reference magnetic field strength (Boi=0, 200, or 300 μG-the latter two values leading to magnetically subcritical clouds), the ratio of rotational to gravitational energy of the filament (10-4 or 10-2), and the efficiency of magnetic braking (represented by a factor fmb=0, 10-4, or 10-3). Three types of outcomes are observed: direct collapse and fragmentation into a multiple protostar system (models with Boi=0), periodic contraction and expansion without collapse (models with tad/tff=106), or periodic contraction and expansion leading eventually to collapse on a timescale of ~6tff-12tff (all other models). Because the computational grid is a finite-volume sphere, the expanding clouds bounce off the spherical boundary and recollapse toward the center of the spherical grid, leading to the periodic formation of shocked regions where the infalling gas collides with itself, forming dense layers susceptible to sustained collapse and eventual fragmentation. The models develop weakly supersonic velocity fields as a result of rebounding prior to collapse. The models show that magnetically supported clouds subject to magnetic braking can undergo dynamic collapse leading to protostellar fragmentation on scales of 10-100 AU, consistent with typical binary star separations.

  10. Velocity field measurements in sedimentary rock cores by magnetization prepared 3D SPRITE.

    Science.gov (United States)

    Romanenko, Konstantin; Xiao, Dan; Balcom, Bruce J

    2012-10-01

    A time-efficient MRI method suitable for quantitative mapping of 3-D velocity fields in sedimentary rock cores, and granular samples is discussed. The method combines the 13-interval Alternating-Pulsed-Gradient Stimulated-Echo (APGSTE) scheme and three-dimensional Single Point Ramped Imaging with T(1) Enhancement (SPRITE). Collecting a few samples near the q-space origin and employing restricted k-space sampling dramatically improves the performance of the imaging method. The APGSTE-SPRITE method is illustrated through mapping of 3-D velocity field in a macroscopic bead pack and heterogeneous sandstone and limestone core plugs. The observed flow patterns are consistent with a general trend for permeability to increase with the porosity. Domains of low permeability obstruct the flow within the core volume. Water tends to flow along macroscopic zones of higher porosity and across zones of lower porosity.

  11. A Novel Acetylcholinesterase Biosensor: Core-Shell Magnetic Nanoparticles Incorporating a Conjugated Polymer for the Detection of Organophosphorus Pesticides.

    Science.gov (United States)

    Dzudzevic Cancar, Hurija; Soylemez, Saniye; Akpinar, Yeliz; Kesik, Melis; Göker, Seza; Gunbas, Gorkem; Volkan, Murvet; Toppare, Levent

    2016-03-01

    To construct a sensing interface, in the present work, a conjugated polymer and core-shell magnetic nanoparticle containing biosensor was constructed for the pesticide analysis. The monomer 4,7-di(furan-2-yl)benzo[c][1,2,5]thiadiazole (FBThF) and core-shell magnetic nanoparticles were designed and synthesized for fabrication of the biosensing device. The magnetic nanoparticles were first treated with silica and then modified using carboxyl groups, which enabled binding of the biomolecules covalently. For the construction of the proposed sensor a two-step procedure was performed. First, the poly(FBThF) was electrochemically generated on the electrode surface. Then, carboxyl group modified magnetic nanoparticles (f-MNPs) and acetylcholinesterase (AChE), the model enzyme, were co-immobilized on the polymer-coated surface. Thereby, a robust and novel surface, conjugated polymer bearing magnetic nanoparticles with pendant carboxyl groups, was constructed, which was characterized using Fourier transform infrared spectrometer, cyclic voltammetry, scanning electron microscopy, and contact angle measurements. This novel architecture was then applied as an immobilization platform to detect pesticides. To the best of our knowledge, a sensor design that combines both conjugated polymer and magnetic nanoparticles was attempted for the first time, and this approach resulted in improved biosensor characteristics. Hence, this approach opens a new perspective in the field of enzyme immobilization and sensing applications. Paraoxon and trichlorfon were selected as the model toxicants. To obtain best biosensor performance, optimization studies were performed. Under optimized conditions, the biosensor in concern revealed a rapid response (5 s), a low detection limit (6.66 × 10(-3) mM), and high sensitivity (45.01 μA mM(-1) cm(-2)). The KM(app) value of poly(FBThF)/f-MNPs/AChE were determined as 0.73 mM. Furthermore, there was no considerable activity loss for 10 d for poly

  12. Ultrafast hydrothermal synthesis of high quality magnetic core phenol-formaldehyde shell composite microspheres using the microwave method.

    Science.gov (United States)

    You, Li-Jun; Xu, Shuai; Ma, Wan-Fu; Li, Dian; Zhang, Yu-Ting; Guo, Jia; Hu, Jack J; Wang, Chang-Chun

    2012-07-17

    An ultrafast, facile, and efficient microwave hydrothermal approach was designed to fabricate magnetic Fe(3)O(4)/phenol-formaldehyde (PF) core-shell microspheres for the first time. The structure of the Fe(3)O(4)/PF core-shell microspheres could be well controlled by the in situ polycondensation of phenol and formaldehyde with magnetic Fe(3)O(4) clusters as the seeds in an aqueous solution without any surfactants. The effect of synthetic parameters, such as the feeding amounts of phenol, the dosages of formaldehyde, the reaction temperatures, and the microwave heating time, on the morphologies and sizes of the Fe(3)O(4)/PF microspheres were investigated in details. The phenol-formaldehyde shell is found to be evenly coated on Fe(3)O(4) clusters within 10 min of the irradiation. The as-prepared microspheres were highly uniform in morphology, and the method was found to allow the shell thickness to be finely controlled in the range of 10-200 nm. The properties of the composite microspheres were characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM), thermogravimetic analysis (TGA), Fourier transform infrared (FT-IR) spectra, X-ray diffraction (XRD), and vibrating sample magnetometer (VSM). The as-prepared Fe(3)O(4)/PF microspheres were monodisperse and highly dispersible in water, ethanol, N,N-dimethyformamide, and acetone, a beneficial quality for the further functionalization and applications of the Fe(3)O(4)/PF microspheres.

  13. An electrochemical biosensor for fructosyl valine for glycosylated hemoglobin detection based on core-shell magnetic bionanoparticles modified gold electrode.

    Science.gov (United States)

    Chawla, Sheetal; Pundir, Chandra Shekhar

    2011-04-15

    A high-performance amperometric fructosyl valine (FV) biosensor was developed, based on immobilization of fructosyl amino-acid oxidase (FAO) on core-shell magnetic bionanoparticles modified gold electrode. Chitosan was used to introduce amino groups onto the surface of core-shell magnetic bionanoparticles (MNPs). With FAO as an enzyme model, a new fructosyl valine biosensor was fabricated. The biosensor showed optimum response, when operated at 50 mVs(-1) in 0.1M potassium phosphate buffer, pH 7.5 and 35°C. The biosensor exhibited excellent sensitivity [the detection limit is down to 0.1mM for FV], fast response time (less than 4s), wide linear range (from 0 to 2mM). Analytical recovery of added FV was 95.00-98.50%. Within batch and between batch coefficients of variation were <2.58% and <5.63%, respectively. The enzyme electrode was used 250 times over 3 months, when stored at 4°C.

  14. Ion irradiation of Fe-Fe oxide core-shell nanocluster films. Effect of interface on stability of magnetic properties

    Energy Technology Data Exchange (ETDEWEB)

    McCloy, John S. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Jiang, Weilin [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Droubay, Timothy C. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Varga, Tamas [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Kovarik, Libor [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Sundararajan, Jennifer A. [Univ. of Idaho, Moscow, ID (United States); Kaur, Maninder [Univ. of Idaho, Moscow, ID (United States); Qiang, You [Univ. of Idaho, Moscow, ID (United States); Burks, Edward [Univ. of California, Davis, CA (United States); Liu, Kai [Univ. of California, Davis, CA (United States)

    2013-08-23

    A cluster deposition method was used to produce films of loosely aggregated nanoclusters (NC) of Fe core-Fe3O4 shell or fully oxidized Fe3O4. Films of these NC on Si(100) or MgO(100)/Fe3O4(100) were irradiated to 1016 Si2+/cm2 near room temperature using an ion accelerator. Ion irradiation creates structural change in the NC film with corresponding chemical and magnetic changes which depend on the initial oxidation state of the cluster. Films were characterized using magnetometry (hysteresis, first order reversal curves), microscopy (transmission electron, helium ion), and x-ray diffraction. In all cases, the particle sizes increased due to ion irradiation, and when a core of Fe is present, irradiation reduces the oxide shells to lower valent Fe species. These results show that ion irradiated behavior of the nanocluster films depends strongly on the initial nanostructure and chemistry, but in general saturation magnetization decreases slightly.

  15. Ion irradiation of Fe-Fe oxide core-shell nanocluster films: Effect of interface on stability of magnetic properties

    Energy Technology Data Exchange (ETDEWEB)

    McCloy, John S.; Jiang, Weilin; Droubay, Timothy C.; Varga, Tamas; Kovarik, Libor [Pacific Northwest National Laboratory, 902 Battelle Blvd., PO Box 999, Richland, Washington 99352 (United States); Sundararajan, Jennifer A.; Kaur, Maninder; Qiang, You [Department of Physics, University of Idaho, Moscow, Idaho 83844 (United States); Burks, Edward C.; Liu, Kai [Department of Physics, University of California, Davis, California 95616 (United States)

    2013-08-28

    A cluster deposition method was used to produce films of loosely aggregated nanoclusters (NCs) of Fe core-Fe{sub 3}O{sub 4} shell or fully oxidized Fe{sub 3}O{sub 4}. Films of these NC on Si(100) or MgO(100)/Fe{sub 3}O{sub 4}(100) were irradiated to 10{sup 16} Si{sup 2+}/cm{sup 2} near room temperature using an ion accelerator. Ion irradiation creates structural change in the NC film with corresponding chemical and magnetic changes which depend on the initial oxidation state of the cluster. Films were characterized using magnetometry (hysteresis, first order reversal curves), microscopy (transmission electron, helium ion), and x-ray diffraction. In all cases, the particle sizes increased due to ion irradiation, and when a core of Fe is present, irradiation reduces the oxide shells to lower valent Fe species. These results show that ion irradiated behavior of the NC films depends strongly on the initial nanostructure and chemistry, but in general saturation magnetization decreases slightly.

  16. Magnetic Fields in Star-Forming Molecular Clouds III. Submillimeter Polarimetry of Intermediate Mass Cores and Filaments in Orion B

    CERN Document Server

    Matthews, B C; Moriarty-Schieven, G H

    2002-01-01

    Using the imaging polarimeter for the Submillimeter Common User Bolometric Array at the James Clerk Maxwell Telescope, we have detected polarized thermal emission at 850 micron from dust toward three star-forming core systems in the Orion B molecular cloud: NGC 2071, NGC 2024 and LBS 23N (HH 24). The polarization patterns are not indicative of those expected for magnetic fields dominated by a single field direction, and all exhibit diminished polarization percentages toward the highest intensity peaks. NGC 2024 has the most organized polarization pattern which is centered consistently along the length of a chain of 7 far-infrared sources. We have modeled NGC 2024 using a helical field geometry threading a curved filament and also as a magnetic field swept up by the ionization front of the expanding HII region. In the latter case, the field is bent by the dense ridge, which accounts for both the polarization pattern and existing measurements of the line-of-sight field strength toward the northern cores FIR 1 t...

  17. Facile synthesis of hairy core-shell structured magnetic polymer submicrospheres and their adsorption of bovine serum albumin.

    Science.gov (United States)

    Yan, Xianming; Kong, Juan; Yang, Chongchong; Fu, Guoqi

    2015-05-01

    Highly magnetic polymer submicrospheres with a hairy core-shell structure were facilely synthesized by combining distillation-precipitation polymerization (DPP) with subsequent surface-initiated atom transfer radical polymerization (SI-ATRP), and then investigated for protein adsorption. A robust polymer shell consisting of poly(divinylbenzene-co-chloromethylstyrene) (P(DVB-co-CMS)) was coated on superparamagnetic submicrometer-sized magnetite colloid nanocrystal clusters (MCNCs) via DPP. With the benzyl chloride groups on the shell as initiator, poly(2-(dimethylamino) ethyl methacrylate) (PDMAEMA) hairs were grafted by SI-ATRP approach. The resulting hairy core-shell structured Fe3O4@ P(DVB-co-CMS)-PDMAEMA microspheres showed pH- and temperature-sensitivity, and high-magnetization. The composite microspheres were further investigated for adsorption of a typical acidic protein, i.e. bovine serum albumin (BSA). They exhibited a high binding capacity up to over 660 mg/g (corresponding to 158 DMAEMA monomer units cooperating for binding one BSA molecule) and could rapidly reach binding equilibrium within 5 min. Moreover, the adsorption of BSA was found to be remarkably dependent on the pH and salt concentration of the protein solutions, and the bound protein could be quantitatively desorbed by washing with a medium with lowered pH or raised salt concentration.

  18. Transformer core

    NARCIS (Netherlands)

    Mehendale, A.; Hagedoorn, Wouter; Lötters, Joost Conrad

    2010-01-01

    A transformer core includes a stack of a plurality of planar core plates of a magnetically permeable material, which plates each consist of a first and a second sub-part that together enclose at least one opening. The sub-parts can be fitted together via contact faces that are located on either side

  19. Transformer core

    NARCIS (Netherlands)

    Mehendale, A.; Hagedoorn, Wouter; Lötters, Joost Conrad

    2008-01-01

    A transformer core includes a stack of a plurality of planar core plates of a magnetically permeable material, which plates each consist of a first and a second sub-part that together enclose at least one opening. The sub-parts can be fitted together via contact faces that are located on either side

  20. A/C magnetic hyperthermia of melanoma mediated by iron(0/iron oxide core/shell magnetic nanoparticles: a mouse study

    Directory of Open Access Journals (Sweden)

    Koper Olga B

    2010-03-01

    Full Text Available Abstract Background There is renewed interest in magnetic hyperthermia as a treatment modality for cancer, especially when it is combined with other more traditional therapeutic approaches, such as the co-delivery of anticancer drugs or photodynamic therapy. Methods The influence of bimagnetic nanoparticles (MNPs combined with short external alternating magnetic field (AMF exposure on the growth of subcutaneous mouse melanomas (B16-F10 was evaluated. Bimagnetic Fe/Fe3O4 core/shell nanoparticles were designed for cancer targeting after intratumoral or intravenous administration. Their inorganic center was protected against rapid biocorrosion by organic dopamine-oligoethylene glycol ligands. TCPP (4-tetracarboxyphenyl porphyrin units were attached to the dopamine-oligoethylene glycol ligands. Results The magnetic hyperthermia results obtained after intratumoral injection indicated that micromolar concentrations of iron given within the modified core-shell Fe/Fe3O4 nanoparticles caused a significant anti-tumor effect on murine B16-F10 melanoma with three short 10-minute AMF exposures. We also observed a decrease in tumor size after intravenous administration of the MNPs followed by three consecutive days of AMF exposure 24 hrs after the MNPs injection. Conclusions These results indicate that intratumoral administration of surface modified MNPs can attenuate mouse melanoma after AMF exposure. Moreover, we have found that after intravenous administration of micromolar concentrations, these MNPs are capable of causing an anti-tumor effect in a mouse melanoma model after only a short AMF exposure time. This is a clear improvement to state of the art.

  1. Analytical Expression of Equivalent Transverse Magnetic Permeability for Three-core Wire Armoured Submarine Cables

    DEFF Research Database (Denmark)

    Viafora, Nicola; Baù, Matteo; Dall, Laurits Bergholdt

    2016-01-01

    As three-core wire-armoured submarine cables become progressively more relevant, the need for refined modelling techniques grows likewise. IEC Standard 60287 indications though are still widely recognized to be insufficiently accurate, since several effects due to the presence of the collective...

  2. Three magnetic reversals recorded in an 80-m organic-rich core from a sinkhole east of Tampa, FL

    Energy Technology Data Exchange (ETDEWEB)

    McCartan, L.; Rubin, M. (Geological Survey, Reston, VA (United States)); Liddicoat, J.C. (Barnard Coll, New York, NY (United States)); Bond, P.A.; Osmond, J.K. (Florida State Univ., Tallahassee, FL (United States))

    1994-03-01

    Preliminary analysis of a continuous 80-m core from a phosphate mines at Bartow, Fla., indicates as many as three magnetically reversed and five normal sections and five upward-fining depositional sequences. The paleomagnetic data are based on analysis of 16 samples; 100 additional samples have been taken for more detailed analysis. The authors estimate the maximum age to be 1.1--2.6 Ma. The core is composed of massive to faintly laminated beds of black to dark-brown, organic-rich, fine quartz sand and silt, kaolinitic and organic clay, and peat, Only the top meter is within the 40 Ka range of [sup 14]C; a sample at 8.5 m yielded an age estimate close to 350,000 years, the limit of the open-system U/Th dating technique. Rates of deposition are 2--7.5 cm/1,000 years, which is much slower than rates in late Quaternary lakes elsewhere in Florida. There is no clear relation between the magnetic stratigraphy and the depositional stratigraphy. The authors assume that most of the sand was derived from dissolved limestone around the sinkhole, but some of the sand as well as the silt and clay may be windborne. Textural variations may be coincident with differences in rainfall, and this concept will be investigated through pollen analysis of approximately 800 samples. The one sample examined so far is from the bottom of the core, and it has an equivocal biostratigraphic age. The high grass pollen content indicates a drier climate than at present; it is from a long interval of peat with sand, which is typically windborne in dry climates.

  3. Demonstration of the self-magnetic-pinch diode as an X-ray source for flash core-punch radiography.

    Energy Technology Data Exchange (ETDEWEB)

    Cordova, Steve Ray; Rovang, Dean Curtis; Portillo, Salvador; Oliver, Bryan Velten; Bruner, Nichelle Lee (Voss Scientific, Albuquerque, NM); Ziska, Derek Raymond (K-Tech Corporation, Albuquerque, NM)

    2007-10-01

    Minimization of the radiographic spot size and maximization of the radiation dose is a continuing long-range goal for development of electron beam driven X-ray radiography sources. In collaboration with members of the Atomic Weapons Establishment(AWE), Aldermaston UK, the Advanced Radiographic Technologies Dept. 1645 is conducting research on the development of X-ray sources for flash core-punch radiography. The Hydrodynamics Dept. at AWE has defined a near term radiographic source requirement for scaled core-punch experiments to be 250 rads{at}m with a 2.75 mm source spot-size. As part of this collaborative effort, Dept. 1645 is investigating the potential of the Self-Magnetic-Pinched (SMP) diode as a source for core-punch radiography. Recent experiments conducted on the RITS-6 accelerator [1,2] demonstrated the potential of the SMP diode by meeting and exceeding the near term radiographic requirements established by AWE. During the demonstration experiments, RITS-6 was configured with a low-impedance (40 {Omega}) Magnetically Insulated Transmission Line (MITL), which provided a 75-ns, 180-kA, 7.5-MeV forward going electrical pulse to the diode. The use of a low-impedance MITL enabled greater power coupling to the SMP diode and thus allowed for increased radiation output. In addition to reconfiguring the driver (accelerator), geometric changes to the diode were also performed which allowed for an increase in dose production without sacrificing the time integrated spot characteristics. The combination of changes to both the pulsed power driver and the diode significantly increased the source x-ray intensity.

  4. Thermo-responsive polymer tethered metal-organic framework core-shell magnetic microspheres for magnetic solid-phase extraction of alkylphenols from environmental water samples.

    Science.gov (United States)

    Jia, Yuqian; Su, Hao; Wong, Y-L Elaine; Chen, Xiangfeng; Dominic Chan, T-W

    2016-07-22

    In this work, the thermo-responsive polymer PNIPAM tethered to Fe3O4@SiO2@MOF core-shell magnetic microspheres was first synthesized by a surface-selective post-synthetic strategy and underwent highly efficient magnetic solid-phase extraction (MSPE) of alkylphenols from aqueous samples. Alkylphenols, including 4-tert-octylphenol (OP) and 4-n-nonylphenol (NP), were selected as target compounds. The sample quantification was carried out using LC-MS/MS in multiple reaction monitor (MRM) mode. Under optimal working conditions, the developed method showed good linearity in the range of 5-1000ngL(-1), a low limit of detection (1.5ngL(-1)), and good repeatability (relative standard deviation, <8%, n=5) for NP and OP. Owning to the hydrophilic/hydrophobic switchable properties of the nanocomposite, high recoveries (78.7-104.3%) of alkylphenols were obtained under different extraction conditions. The levels of OP and NP in environmental samples collected from local river, lake and pond waters were analyzed using the developed method. It was believed that the synthesized material with the thermo-responsive coating, large surface areas and magnetic properties should have great potential in the extraction and removal of alkylphenols from environmental samples.

  5. [Adsorption of Cu on Core-shell Structured Magnetic Particles: Relationship Between Adsorption Performance and Surface Properties].

    Science.gov (United States)

    Li, Qiu-mei; Chen, Jing; Li, Hai-ning; Zhang, Xiao-lei; Zhang, Gao-sheng

    2015-12-01

    In order to reveal the relationship between the adsorption performance of adsorbents and their compositions, structure, and surface properties, the core-shell structured Fe₃O₄/MnO2 and Fe-Mn/Mn₂2 magnetic particles were systematically characterized using multiple techniques and their Cu adsorption behaviors as well as mechanism were also investigated in details. It was found that both Fe₃O4 and Fe-Mn had spinel structure and no obvious crystalline phase change was observed after coating with MnO₂. The introduction of Mn might improve the affinity between the core and the shell, and therefore enhanced the amount and distribution uniformity of the MnO₂ coated. Consequently, Fe-Mn/MnO₂ exhibited a higher BET specific surface area and a lower isoelectric point. The results of sorption experiments showed that Fe-Mn had a higher maximal Cu adsorption capacity of 33.7 mg · g⁻¹ at pH 5.5, compared with 17.5 mg · g⁻¹ of Fe₃O4. After coating, the maximal adsorption capacity of Fe-Mn/MnO₂ was increased to 58.2 mg · g⁻¹, which was 2.6 times as high as that of Fe₃O₄/MnO₂ and outperformed the majority of magnetic adsorbents reported in literature. In addition, a specific adsorption of Cu occurred at the surface of Fe₃O₄/MnO₂ or Fe-Mn/MnO₂ through the formation of inner-sphere complexes. In conclusion, the adsorption performance of the magnetic particles was positively related to their compositions, structure, and surface properties.

  6. A repetitively pulsed xenon chloride excimer laser with all ferrite magnetic cores (AFMC) based all solid state exciter

    Science.gov (United States)

    Benerji, N. S.; Varshnay, N. K.; Ghodke, D. V.; Singh, A.

    2016-10-01

    Performance of repetitively pulsed xenon chloride excimer laser (λ~308 nm) with solid state pulser consisting of magnetic pulse compression circuit (MPC) using all ferrite magnetic cores (AFMC) is reported. Laser system suitable for 100 Hz operation with inbuilt pre-ionizer, compact gas circulation and cooling has been developed and presented. In this configuration, high voltage pulses of ~8 μs duration are compressed to ~100 ns by magnetic pulse compression circuit with overall compression factor of ~80. Pulse energy of ~18 J stored in the primary capacitor is transferred to the laser head with an efficiency of ~85% compared to ~70% that is normally achieved in such configurations using annealed met-glass core. This is a significant improvement of about 21%. Maximum output laser pulse energy of ~100 mJ was achieved at repetition rate of 100 Hz with a typical pulse to pulse energy stability of ±5% and laser pulse energy of 150 mJ was generated at low rep-rate of ~40 Hz. This exciter uses a low current and low voltage solid state switch (SCR) that replaces high voltage and high current switch i. e, thyratron completely. The use of solid state exciter in turn reduces electromagnetic interference (EMI) effects particularly in excimer lasers where high EMI is present due to high di/dt. The laser is focused on a thin copper sheet for generation of micro-hole and the SEM image of the generated micro hole shows the energy stability of the laser at high repetition rate operation. Nearly homogeneous, regular and well developed xenon chloride (XeCl) laser beam spot was achieved using the laser.

  7. Rapid enrichment of leucocytes and genomic DNA from blood based on bifunctional core shell magnetic nanoparticles

    Science.gov (United States)

    Xie, Xin; Nie, Xiaorong; Yu, Bingbin; Zhang, Xu

    2007-04-01

    A series of protocols are proposed to extract genomic DNA from whole blood at different scales using carboxyl-functionalized magnetic nanoparticles as solid-phase absorbents. The enrichment of leucocytes and the adsorption of genomic DNA can be achieved with the same carboxyl-functionalized magnetic nanoparticles. The DNA bound to the bead surfaces can be used directly as PCR templates. By coupling cell separation and DNA purification, the whole operation can be accomplished in a few minutes. Our simplified protocols proved to be rapid, low cost, and biologically and chemically non-hazardous, and are therefore promising for microfabrication of a DNA-preparation chip and routine laboratory use.

  8. Pulsed Magnetic Field Driven Gas Core Reactors for Space Power & Propulsion Applications

    Science.gov (United States)

    Anghaie, Samim; Smith, Blair; Knight, Travis; Butler, Carey

    2003-01-01

    The present results indicated that: 1. A pulsed magnetic driven fission power concept, PMD-GCR is developed for closed (NER) and semi-open (NTR) operations. 2. In power mode, power is generated at alpha less than 1 for power levels of hundreds of KW or higher 3. IN semi open NTR mode, PMD-GCR generates thrust at I(sub sp) approx. 5,000 s and jet power approx. 5KW/Kg. 4. PMD-GCR is highly subcritical and is actively driven to critically. 5. Parallel path with fusion R&D needs in many areas including magnet and plasma.

  9. Ce Core-Level Spectroscopy, and Magnetic and Electrical Transport Properties of Lightly Ce-Doped YCoO3

    Science.gov (United States)

    Kobayashi, Yoshihiko; Koike, Tsuyoshi; Okawa, Mario; Takayanagi, Ryohei; Takei, Shohei; Minohara, Makoto; Kobayashi, Masaki; Horiba, Koji; Kumigashira, Hiroshi; Yasui, Akira; Ikenaga, Eiji; Saitoh, Tomohiko; Asai, Kichizo

    2016-11-01

    We have investigated the Ce and Co core level spectroscopy, and the magnetic and electrical transport properties of lightly Ce-doped YCoO3. We have successfully synthesized single-phase Y1-xCexCoO3 for 0.0 ≤ x ≤ 0.1 by the sol-gel method. Hard X-ray photoelectron and X-ray absorption spectroscopy experiments reveal that the introduced Ce ions are tetravalent, which is considered to be the first case of electron doping into bulk trivalent Co oxides with perovskite RECoO3 (RE: rare-earth element or Y) caused by RE site substitution. The magnitude of the effective magnetic moment peff obtained from the temperature dependence of magnetic susceptibility χ(T) at higher temperatures is close to that for high-spin Co2+ introduced by the Ce doping, implying that the electrons doped into the Co site induce Co2+ with a high-spin state. For x = 0.1, ferromagnetic ordering is observed below about 7 K. Electrical transport properties such as resistivity and thermoelectric power show that negative electron-like carriers are introduced by Ce substitution.

  10. Rapid Legionella pneumophila determination based on a disposable core-shell Fe₃O₄@poly(dopamine) magnetic nanoparticles immunoplatform.

    Science.gov (United States)

    Martín, Miriam; Salazar, Pedro; Jiménez, Carmen; Lecuona, María; Ramos, Ma José; Ode, Jesús; Alcoba, Julia; Roche, Rossany; Villalonga, Reynaldo; Campuzano, Susana; Pingarrón, José Manuel; González-Mora, José Luis

    2015-08-05

    A novel amperometric magnetoimmunoassay, based on the use of core-shell magnetic nanoparticles and screen-printed carbon electrodes, was developed for the selective determination of Legionella pneumophila SG1. A specific capture antibody (Ab) was linked to the poly(dopamine)-modified magnetic nanoparticles (MNPs@pDA-Ab) and incubated with bacteria. The captured bacteria were sandwiched using the antibody labeled with horseradish peroxidase (Ab-HRP), and the resulting MNPs@pDA-Ab-Legionella neumophila-Ab-HRP were captured by a magnetic field on the electrode surface. The amperometric response measured at -0.15 V vs. Ag pseudo-reference electrode of the SPCE after the addition of H2O2 in the presence of hydroquinone (HQ) was used as transduction signal. The achieved limit of detection, without pre-concentration or pre-enrichment steps, was 10(4) Colony Forming Units (CFUs) mL(-1). The method showed a good selectivity and the MNPs@pDA-Ab exhibited a good stability during 30 days. The possibility of detecting L. pneumophila at 10 CFU mL(-1) level in less than 3 h, after performing a membrane-based preconcentration step, was also demonstrated.

  11. Effect of particle-core-vibration coupling near the double closed $^{132}$Sn nucleus from precise magnetic moment measurements

    CERN Multimedia

    Postma, H; Heyde, K; Walker, P; Grant, I; Veskovic, M; Stone, N; Stone, J

    2002-01-01

    % IS301 \\\\ \\\\ Low temperature nuclear orientation of isotope-separator implanted short-lived radio-isotopes makes possible the measurements of nuclear magnetic dipole moments of oriented ground and excited states with half-lives longer than a few seconds. Coupling schemes characterizing the odd nucleons and ground-state deformations can be extracted from the nuclear moments. \\\\ We thus propose to measure the magnetic dipole moments of $^{127-133}$Sb to high precision using NMR/ON at the NICOLE facility. With (double magic +1) $^{133}$Sb as the reference, the main aim of this experiment is to examine whether the collective component in the 7/2$^+$ Sb ground state magnetic dipole moment varies as expected according to particle-core coupling calculations carried out for the Sb (Z=51) isotopes. Comparison of the 1-proton-particle excitations in Sb to 1-proton-hole states in In nuclei will shed light on differences between particle and hole excitations as understood within the present model. Comparison of ...

  12. Glass-NiP-CoFeP triplex-shell particles with hollow cores and tunable magnetic properties.

    Science.gov (United States)

    An, Zhenguo; Zhang, Jingjie

    2013-02-01

    Low density (0.55-0.92g/mL, depending on the shell thickness and composition) glass-metal-metal triplex-shell hollow particles (TSHP) were prepared by a three-step route. First, micrometer-sized silicate glass particles with hollow cores, uniform shells, and high sphericity were prepared through spray drying and subsequent melting. NiP shell was uniformly assembled to the previously obtained glass hollow particles by silver seed induced chemical reduction of Ni(2+) by sodium hypophosphite, and glass-NiP double-shell hollow particles (DSHP) with compact and uniform shells were formed. The as-formed NiP particles further acted as the seeds for the directed formation and assembly of the CoFeP shell on the NiP shell to form the final glass-NiP-CoFeP triplex-shell hollow particles (TSHP). The influences of the component of the reaction system on the composition, structure, and magnetic properties of the hollow particles were studied. The multishell hollow particles thus obtained may have some promising applications in the fields of low-density magnetic materials, conduction, microwave absorbers, catalysis, etc. This work provides an additional strategy to fabricate multishell structured hollow particles with tailored shell composition and magnetic properties, which can be extended to the controlled preparation of multishell composite particles with the shells consisting of metal, oxides, or other compounds.

  13. A novel dual-responsive core-crosslinked magnetic-gold nanogel for triggered drug release.

    Science.gov (United States)

    Ghorbani, Marjan; Hamishehkar, Hamed; Arsalani, Nasser; Entezami, Ali Akbar

    2016-11-01

    A facial approach was reported to prepare a novel dual-responsive core-crosslinked nanogel and investigated for the triggered methotrexate (MTX) release. Nanogels with core-shell architecture were synthesized by decoration of Au/Fe3O4 core/shell NPs using poly(ethylene glycol)-b-poly((N,N-dimethylamino)ethyl methacrylate-co-2-hydroxyethyl methacrylate)-maleic acid (PEG-b-P(DMAEMA-co-HEMA)-MA) for crosslinking and autoreduction processes. The second block containing amino groups and maleate groups as the inner shell was used for the reduction of HAuCl4 (auric cation) in the presence of Fe3O4 NPs and as a crosslinker agent, respectively. Furthermore, to improve the long-term dispersibility of the nanogels, poly(ethylene glycol) was preferred as outer shell even under high ionic strength. After that, NIPAAm was polymerized from the vinyl double bonds for fabricating the thermo and pH-responsive core-crosslinked nanogels. MTX (an anti-cancer agent) was successfully loaded (the loading capacity of 37%) into the nanogels by both ionic interaction and entrapment in polymeric network in the inner shell. The triggered MTX release ability of the synthesized nanocarriers was proved through the comparison of in-vitro drug release at simulated physiological condition and tumor tissue environment. MTT assay showed that MTX-loaded nanocarriers revealed high antitumor activity in MCF7 cell line after incubation following 24 and 48h. It was concluded that the developed nanogels have many promising qualities as an efficient carrier for the targeted MTX delivery to cancer tissues.

  14. Exchange-mediated, nonlinear, out-of-plane magnetic field dependence of the ferromagnetic vortex gyrotropic mode frequency driven by core deformation

    Science.gov (United States)

    Fried, Jasper P.; Fangohr, Hans; Kostylev, Mikhail; Metaxas, Peter J.

    2016-12-01

    We have performed micromagnetic simulations of low-amplitude gyrotropic dynamics of magnetic vortices in the presence of spatially uniform out-of-plane magnetic fields. For disks having small lateral dimensions, we observe a frequency drop-off when approaching the disk's out-of-plane saturation field. This nonlinear frequency response is shown to be associated with a vortex core deformation driven by nonuniform demagnetizing fields that act on the shifted core. The deformation results in an increase in the average out-of-plane magnetization of the displaced vortex state (contrasting the effect of gyrofield-driven deformation at low field), which causes the exchange contribution to the vortex stiffness to switch from positive to negative. This generates an enhanced reduction of the core stiffness at high field, leading to a nonlinear field dependence of the gyrotropic mode frequency.

  15. Effect of Magnetic Field and Shell Thickness on Binding Energies of a ZnSe/ZnS Core Shell Quantum Dot

    Science.gov (United States)

    Bhat, Bashir Mohi ud din; Parvaiz, Muhammad Shunaid; Sen, Pratima

    2017-02-01

    We investigated the effect of external magnetic field and shell thickness on the binding energies of a ZnSe/ZnS core shell quantum dot. The binding energies were calculated using the variational method within the effective mass approximation and confinement potential. The binding energy of the 2 s and 2 p + states was found to increase with magnetic field. However, the 2 p 0 state was found to be independent of the magnetic field at a shell thickness of 0.5 nm. Degeneracy of the lifted 2 p states was found to occur. The results also showed that the electron binding energy increases at the outset with the increasing shell thickness, and at larger shell thicknesses, the binding energy saturates. The binding energy was found to be decreasing with increasing core diameter and becomes appreciably smaller at core radius of 0.42 nm. The observed results were compared with the previously reported results.

  16. Nuclear spins, magnetic moments and quadrupole moments of Cu isotopes from N = 28 to N = 46: probes for core polarization effects

    CERN Document Server

    Vingerhoets, P; Avgoulea, M; Billowes, J; Bissell, M L; Blaum, K; Brown, B A; Cheal, B; De Rydt, M; Forest, D H; Geppert, Ch; Honma, M; Kowalska, M; Kramer, J; Krieger, A; Mane, E; Neugart, R; Neyens, G; Nortershauser, W; Otsuka, T; Schug, M; Stroke, H H; Tungate, G; Yordanov, D T

    2010-01-01

    Measurements of the ground-state nuclear spins, magnetic and quadrupole moments of the copper isotopes from 61Cu up to 75Cu are reported. The experiments were performed at the ISOLDE facility, using the technique of collinear laser spectroscopy. The trend in the magnetic moments between the N=28 and N=50 shell closures is reasonably reproduced by large-scale shell-model calculations starting from a 56Ni core. The quadrupole moments reveal a strong polarization of the underlying Ni core when the neutron shell is opened, which is however strongly reduced at N=40 due to the parity change between the $pf$ and $g$ orbits. No enhanced core polarization is seen beyond N=40. Deviations between measured and calculated moments are attributed to the softness of the 56Ni core and weakening of the Z=28 and N=28 shell gaps.

  17. Spin transfer driven resonant expulsion of a magnetic vortex core for efficient rf detector

    CERN Document Server

    Menshawy, Samh; Merazzo, Karla J; Vila, Laurent; Ferreira, Ricardo; Cyrille, Marie-Claire; Ebels, Ursula; Bortolotti, Paolo; Kermorvant, Julien; Cros, Vincent

    2016-01-01

    Spin transfer magnetization dynamics have led to considerable advances in Spintronics, including opportunities for new nanoscale radiofrequency devices. Among the new functionalities is the radiofrequency(rf) detection using the spin diode rectification effect in spin torque nano-oscillators (STNOs). In this study, we focus on a new phenomenon, the resonant expulsion of a magnetic vortex in STNOs. This effect is observed when the excitation vortex radius, due to spin torques associated to rf currents, becomes larger than the actual radius of the STNO. This vortex expulsion is leading to a sharp variation of the voltage at the resonant frequency. Here we show that the detected frequency can be tuned by different parameters; furthermore, a simultaneous detection of different rf signals can be achieved by real time measurements with several STNOs having different diameters. This result constitutes a first proof-of-principle towards the development of a new kind of nanoscale rf threshold detector.

  18. Behavior of Medium-frequency Core Loss in Fe-based Nanocrystalline Soft Magnetic Alloys

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The dependences of the power loss per cycle on frequency have been investigated in the ranges of 100 Hz< f <25000 Hz and 0.1 T< Brn <1.0 T for three main original magnetic states in five sorts of Fe-based nanocrystalline soft magnetic alloys. The measured and calculated results showed that the total ipower loss per cycle clearly exhibited a nonlinear behavior in the range below 3 kHz~5 kHz depending on both the magnetic state and the value of Bm, whereas it showed a quasi-linear behavior above this range. The total loss was decomposed into hysteresis loss, classical eddy current loss and excess loss, the obvious nonlinear behavior has been confirmed to be completely determined by the dependence of the excess loss on frequency. It has been indicated that the change rate of the excess loss per cycle with respect to frequency sharp decreases with increasing frequency in the range below about 3 kHz~5 kHz, herease the rate of change slowly varies above this range, thus leading to the quasilinear behavior of the total loss per cycle. In this paper, some linear expressions of the total loss per cycle has been given in a wider medium-frequency segment, which can be used for roughly estimating the total loss.

  19. Fractional-order system identification and proportional-derivative control of a solid-core magnetic bearing.

    Science.gov (United States)

    Zhong, Jianpeng; Li, Lichuan

    2014-07-01

    This paper presents the application of fractional-order system identification (FOSI) and proportional-derivative (PD(µ)) control to a solid-core magnetic bearing (MB). A practical strategy for closed-loop incommensurate FOSI along with a modified error criterion is utilized to model the MB system and a corresponding, verification experiment is carried out. Based on the identified model, integer-order (IO) PD and fractional-order (FO) PD(µ) controllers are designed and compared with the same specifications. Besides, the relation between the two categories of controllers is discussed by their feasible control zones. Final simulation and experimental results show that the FO PD(µ) controller can significantly improve the transient and steady-state performance of the MB system comparing with the IO PD controller. Copyright © 2014 ISA. Published by Elsevier Ltd. All rights reserved.

  20. Environmentally friendly electroless plating for Ag/TiO2-coated core-shell magnetic particles using ultrasonic treatment.

    Science.gov (United States)

    Kim, Soo-Dong; Choe, Won-Gyun; Jeong, Jong-Ryul

    2013-11-01

    In this work, high-reflectance brilliant white color magnetic microspheres comprising a Fe/TiO2/Ag core-shell structure with a continuous, uniform compact silver layer were successfully fabricated by TiO2-assisted electroless plating in a simple and eco-friendly method. The coating procedure for TiO2 and Ag involved a sol-gel reaction and electroless plating with ultrasound treatment. The electroless plating step was carried out in an eco-friendly manner in a single process without environmentally toxic additives. The TiO2 layer was used as a modification layer between the Fe microspheres and the silver layer to improve adhesion. A continuous and compact silver layer could be formed with a high degree of morphological control by introducing ultrasonication and adjusting the ammonium hydroxide concentration.

  1. Preparation of Novel Poly(hydroxyethyl methacrylate-co-glycidyl methacrylate-Grafted Core-Shell Magnetic Chitosan Microspheres and Immobilization of Lactase

    Directory of Open Access Journals (Sweden)

    Wendy Katiyo

    2013-06-01

    Full Text Available Poly(hydroxyethyl methacrylate-co-glycidyl methacrylate-grafted magnetic chitosan microspheres (HG-MCM were prepared using reversed-phase suspension polymerization method. The HG-MCM presented a core-shell structure and regular spherical shape with poly(hydroxyethyl methacrylate-co-glycidyl methacrylate grafted onto the chitosan layer coating the Fe3O4 cores. The average diameter of the magnetic microspheres was 10.67 μm, within a narrow size distribution of 6.6–17.4 μm. The saturation magnetization and retentivity of the magnetic microspheres were 7.0033 emu/g and 0.6273 emu/g, respectively. The application of HG-MCM in immobilization of lactase showed that the immobilized enzyme presented higher storage, pH and thermal stability compared to the free enzyme. This indicates that HG-MCM have potential applications in bio-macromolecule immobilization.

  2. Nitrogen rich core-shell magnetic mesoporous silica as an effective adsorbent for removal of silver nanoparticles from water.

    Science.gov (United States)

    Zhang, Xiaoye; Zhang, Yao; Zhang, Xiaodan; Li, Siqi; Huang, Yuming

    2017-09-05

    The production and increasing use of silver nanoparticles (AgNPs) obviously results in their release into the environment, leading to a risk to the environment due to their toxic effects. Thus, the removal of AgNPs from water is highly needed. Here, we demonstrate that nitrogen rich (∼10% nitrogen content) core-shell magnetic mesoporous silica is a promising adsorbent for the removal of AgNPs. For this, the poly(ethylenimine) functionalized core-shell magnetic mesoporous silica composites (Fe3O4@SiO2-PEI) were prepared, and characterized by TEM, FT-IR, XRD, TG and N2 adsorption-desorption. The removal of AgNPs by Fe3O4@SiO2-PEI as a function of contact time, concentration of AgNPs, solution pH and ionic strength were studied. The adsorption kinetic data could be described by the pseudo-second-order rate model. Both Langmuir and Freundlich models fitted the adsorption data well. The adsorption capacity for AgNPs is 909.1mg/g, which is 5-181 times higher than that of the previously reported adsorbents for AgNPs. Interestingly, the silver adsorbed onto Fe3O4@SiO2-PEI exhibits highly catalytic activity for 4-nitropheol (4-NP) reduction with a rate constant of 0.072min(-1), which is much higher than those by other AgNPs reported before. The silver-loaded Fe3O4@SiO2-PEI promises good recyclability for at least five cycles, showing great potential in practical applications. Copyright © 2017 Elsevier B.V. All rights reserved.

  3. Fe3O4@MOF core-shell magnetic microspheres as excellent catalysts for the Claisen-Schmidt condensation reaction

    Science.gov (United States)

    Ke, Fei; Qiu, Ling-Guang; Zhu, Junfa

    2014-01-01

    Separation and recycling of catalysts after catalytic reactions are critically required to reduce the cost of catalysts as well as to avoid the generation of waste in industrial applications. In this work, we present a facile fabrication and characterization of a novel type of MOF-based porous catalyst, namely, Fe3O4@MIL-100(Fe) core-shell magnetic microspheres. It has been shown that these catalysts not only exhibit high catalytic activities for the Claisen-Schmidt condensation reactions under environmentally friendly conditions, but remarkably, they can be easily separated and recycled without significant loss of catalytic efficiency after being used for many times. Therefore, compared to other reported catalysts used in the Claisen-Schmidt condensation reactions, these catalysts are green, cheap and more suitable for large scale industrial applications.Separation and recycling of catalysts after catalytic reactions are critically required to reduce the cost of catalysts as well as to avoid the generation of waste in industrial applications. In this work, we present a facile fabrication and characterization of a novel type of MOF-based porous catalyst, namely, Fe3O4@MIL-100(Fe) core-shell magnetic microspheres. It has been shown that these catalysts not only exhibit high catalytic activities for the Claisen-Schmidt condensation reactions under environmentally friendly conditions, but remarkably, they can be easily separated and recycled without significant loss of catalytic efficiency after being used for many times. Therefore, compared to other reported catalysts used in the Claisen-Schmidt condensation reactions, these catalysts are green, cheap and more suitable for large scale industrial applications. Electronic supplementary information (ESI) available: SEM and TEM images, and GC-MS spectra for chalcones. See DOI: 10.1039/c3nr05051c

  4. Magnetic minerals as recorders of weathering, diagenesis, and paleoclimate: A core-outcrop comparison of Paleocene-Eocene paleosols in the Bighorn Basin, WY, USA

    Science.gov (United States)

    Maxbauer, Daniel P.; Feinberg, Joshua M.; Fox, David L.; Clyde, William C.

    2016-10-01

    Magnetic minerals in paleosols hold important clues to the environmental conditions in which the original soil formed. However, efforts to quantify parameters such as mean annual precipitation (MAP) using magnetic properties are still in their infancy. Here, we test the idea that diagenetic processes and surficial weathering affect the magnetic minerals preserved in paleosols, particularly in pre-Quaternary systems that have received far less attention compared to more recent soils and paleosols. We evaluate the magnetic properties of non-loessic paleosols across the Paleocene-Eocene Thermal Maximum (a short-term global warming episode that occurred at 55.5 Ma) in the Bighorn Basin, WY. We compare data from nine paleosol layers sampled from outcrop, each of which has been exposed to surficial weathering, to the equivalent paleosols sampled from drill core, all of which are preserved below a pervasive surficial weathering front and are presumed to be unweathered. Comparisons reveal an increase in magnetization in outcrops compared with core equivalents, which is principally driven by secondary hematite production. Authigenic hematite production in outcrops presents a complication for goethite-hematite based paleoprecipitation proxies where estimates will be biased toward drier climate regimes. The occurrence of low coercivity minerals is more consistent between core and outcrop. However, we propose an alteration process for pedogenic magnetite that is observed in both core and outcrop, where pedogenic magnetite becomes progressively oxidized leading to higher mean coercivities and broader coercivity distributions compared to modern pedogenic magnetite. This combination of diagenetic processes and surface weathering influences the magnetic properties of paleosols. Despite these changes, magnetic enhancement ratios from B-horizons correlate with independent MAP estimates from geochemical proxies, which suggests that paleoprecipitation information is preserved. Future

  5. Development of europium doped core-shell silica cobalt ferrite functionalized nanoparticles for magnetic resonance imaging.

    Science.gov (United States)

    Kevadiya, Bhavesh D; Bade, Aditya N; Woldstad, Christopher; Edagwa, Benson J; McMillan, JoEllyn M; Sajja, Balasrinivasa R; Boska, Michael D; Gendelman, Howard E

    2017-02-01

    The size, shape and chemical composition of europium (Eu(3+)) cobalt ferrite (CFEu) nanoparticles were optimized for use as a "multimodal imaging nanoprobe" for combined fluorescence and magnetic resonance bioimaging. Doping Eu(3+) ions into a CF structure imparts unique bioimaging and magnetic properties to the nanostructure that can be used for real-time screening of targeted nanoformulations for tissue biodistribution assessment. The CFEu nanoparticles (size ∼7.2nm) were prepared by solvothermal techniques and encapsulated into poloxamer 407-coated mesoporous silica (Si-P407) to form superparamagnetic monodisperse Si-CFEu nanoparticles with a size of ∼140nm. Folic acid (FA) nanoparticle decoration (FA-Si-CFEu, size ∼140nm) facilitated monocyte-derived macrophage (MDM) targeting. FA-Si-CFEu MDM uptake and retention was higher than seen with Si-CFEu nanoparticles. The transverse relaxivity of both Si-CFEu and FA-Si-CFEu particles were r2=433.42mM(-1)s(-1) and r2=419.52mM(-1)s(-1) (in saline) and r2=736.57mM(-1)s(-1) and r2=814.41mM(-1)s(-1) (in MDM), respectively. The results were greater than a log order-of-magnitude than what was observed at replicate iron concentrations for ultrasmall superparamagnetic iron oxide (USPIO) particles (r2=31.15mM(-1)s(-1) in saline) and paralleled data sets obtained for T2 magnetic resonance imaging. We now provide a developmental opportunity to employ these novel particles for theranostic drug distribution and efficacy evaluations.

  6. Realization of RF microinductors with magnetic cores for high quality factor applications

    Energy Technology Data Exchange (ETDEWEB)

    Leiste, H. E-mail: harald.leiste@imf.fzk.de; Seemann, K.; Bekker, V

    2004-05-01

    For the use in CMOS compatible microinductors, single-layer ferromagnetic thin films of FeTaN have been deposited by magnetron sputtering and heat treated in a static magnetic field in a second step to induce an uniaxial anisotropy. The as-deposited films were amorphous. After heat treatment the films contain a small amount of nanosized grains and show a cut-off frequency of 1.2 GHz and an initial permeability of 1000. Patterning of the films was done by photolithography process and plasma beam etching.

  7. Influence of the magnetic field expansion on the core plasma in an axisymmetric mirror trap

    Science.gov (United States)

    Soldatkina, E.; Anikeev, M.; Bagryansky, P.; Korzhavina, M.; Maximov, V.; Savkin, V.; Yakovlev, D.; Yushmanov, P.; Dunaevsky, A.

    2017-02-01

    First measurements of plasma parameters in an expander of a mirror trap with sub-fusion plasma parameters are reported. Potential drop near the end plates of the expander appears to be much lower than the electron temperature in the center of the trap. Characteristic energy of electrons in the expander region is also substantially lower than the electron temperature in the confinement plasma. Variation of the magnetic field expansion ratio K between 30 and 160 does not influence the main parameters of the confinement plasma. Electron temperatures of the confinement plasma of about 700 eV were achieved at K = 30.

  8. Predictive value of negative 3T multiparametric magnetic resonance imaging of the prostate on 12-core biopsy results.

    Science.gov (United States)

    Wysock, James S; Mendhiratta, Neil; Zattoni, Fabio; Meng, Xiaosong; Bjurlin, Marc; Huang, William C; Lepor, Herbert; Rosenkrantz, Andrew B; Taneja, Samir S

    2016-10-01

    To evaluate the cancer detection rates for men undergoing 12-core systematic prostate biopsy with negative prebiopsy multiparametric magnetic resonance imaging (mpMRI) results. Clinical data from consecutive men undergoing prostate biopsy who had undergone prebiopsy 3T mpMRI from December 2011 to August 2014 were reviewed from an institutional review board-approved prospective database. Men with negative prebiospy mpMRI results (negMRI) before biopsy were identified for the present analysis. Clinical features, cancer detection rates and negative predictive values were summarized. Seventy five men with negMRI underwent systematic 12-core biopsy during the study period. In the entire cohort, men with no previous biopsy, men with previously negative biopsy and men enrolled in active surveillance protocols, the overall cancer detection rates were 18.7, 13.8, 8.0 and 38.1%, respectively, and the detection rates for Gleason score (GS) ≥7 cancer were 1.3, 0, 4.0 and 0%, respectively. The NPVs for all cancers were 81.3, 86.2, 92.0, and 61.9, and for GS ≥7 cancer they were 98.7, 100, 96.0 and 100%, respectively. A negative prebiopsy mpMRI confers an overall NPV of 82% on 12-core biopsy for all cancer and 98% for GS ≥7 cancer. Based on biopsy indication, these findings assist in prebiopsy risk stratification for detection of high-risk disease and may provide guidance in the decision to pursue biopsy. © 2016 The Authors BJU International © 2016 BJU International Published by John Wiley & Sons Ltd.

  9. Towards real-time cardiovascular magnetic resonance guided transarterial CoreValve implantation: in vivo evaluation in swine

    Directory of Open Access Journals (Sweden)

    Kahlert Philipp

    2012-03-01

    Full Text Available Abstract Background Real-time cardiovascular magnetic resonance (rtCMR is considered attractive for guiding TAVI. Owing to an unlimited scan plane orientation and an unsurpassed soft-tissue contrast with simultaneous device visualization, rtCMR is presumed to allow safe device navigation and to offer optimal orientation for precise axial positioning. We sought to evaluate the preclinical feasibility of rtCMR-guided transarterial aortic valve implatation (TAVI using the nitinol-based Medtronic CoreValve bioprosthesis. Methods rtCMR-guided transfemoral (n = 2 and transsubclavian (n = 6 TAVI was performed in 8 swine using the original CoreValve prosthesis and a modified, CMR-compatible delivery catheter without ferromagnetic components. Results rtCMR using TrueFISP sequences provided reliable imaging guidance during TAVI, which was successful in 6 swine. One transfemoral attempt failed due to unsuccessful aortic arch passage and one pericardial tamponade with subsequent death occurred as a result of ventricular perforation by the device tip due to an operating error, this complication being detected without delay by rtCMR. rtCMR allowed for a detailed, simultaneous visualization of the delivery system with the mounted stent-valve and the surrounding anatomy, resulting in improved visualization during navigation through the vasculature, passage of the aortic valve, and during placement and deployment of the stent-valve. Post-interventional success could be confirmed using ECG-triggered time-resolved cine-TrueFISP and flow-sensitive phase-contrast sequences. Intended valve position was confirmed by ex-vivo histology. Conclusions Our study shows that rtCMR-guided TAVI using the commercial CoreValve prosthesis in conjunction with a modified delivery system is feasible in swine, allowing improved procedural guidance including immediate detection of complications and direct functional assessment with reduction of radiation and omission of contrast media.

  10. Direct liquid phase deposition fabrication of waxberry-like magnetic Fe{sub 3}O{sub 4}@TiO{sub 2} core-shell microspheres

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Jian, E-mail: zhengjian@swust.edu.cn [State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, Southwest University of Science and Technology, Mianyang 621010 (China); Wu, You; Zhang, Quanping; Li, Yintao [State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, Southwest University of Science and Technology, Mianyang 621010 (China); Wang, Chengyang [Department of Chemistry, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching (Germany); Zhou, Yuanlin, E-mail: zhouyuanlin@swust.edu.cn [State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, Southwest University of Science and Technology, Mianyang 621010 (China)

    2016-09-15

    Magnetic Fe{sub 3}O{sub 4}@TiO{sub 2} core-shell microspheres are ideally applied in several specific fields due to their unique properties. A facile liquid phase deposition route for the fabrication of Fe{sub 3}O{sub 4}@TiO{sub 2} core-shell microspheres was developed. The core-shell structure was obtained by direct deposition of TiO{sub 2} on the surface of Fe{sub 3}O{sub 4} microspheres. The prepared products were characterized by using Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and vibrating sample magnetometer (VSM). The waxberry-like microspheres were nearly spherical with diameters of about 500 nm and average shell thickness of 80 nm. The shell layer was composed of smaller primary TiO{sub 2} nanoparticles with sizes from 10 to 20 nm. A possible growth mechanism of the core-shell structure was proposed. The photo-catalytic decomposition of methylene blue and the recycling of prepared core-shell microspheres were also investigated. - Highlights: • Waxberry-like core-shell Fe3O4@TiO2 microspheres were fabricated by facile LPD route. • They have considerable saturation magnetization and small coercivity. • They can be used as recyclable photocatalyst for removal of dyestuff in aqueous solution. • The growth mechanism of the core-shell structure was proposed.

  11. Synthesis and magnetic properties of carbon-coated Ni/SiO2 core/shell nanocomposites

    Institute of Scientific and Technical Information of China (English)

    AU; ChakTong

    2009-01-01

    A simple method for the synthesis of carbon-coated Ni/SiO2 core/shell nanocomposites is reported. The Ni nanoparticles were coated with silica layers via a combined procedure of sol-gel fabrication and hydrogen reduction prior to carbon coating via acetylene decomposition at an appropriate temperature. It was found that the anti-acid ability of the Ni/SiO2 composites was greatly enhanced after carbon coating. The results of magnetization measurement show that the real part (μ′) of complex permeability of the as-obtained sample is almost independent of frequency, and the imaginary part (μ″) stays small up to a frequency of 1 GHz. The encapsulation of Ni particles with SiO2 results in the rise of Ni nanoparticles resistivity. The outcome is the reduction in effect of eddy current at high frequency, making the real part μ′ almost constant and the imaginary part μ″ very small. Thus, this simple method may be effective for preparing composites of soft magnetic properties, especially in the high-frequency range.

  12. Flow injection chemiluminescence sensor based on core-shell magnetic molecularly imprinted nanoparticles for determination of sulfadiazine.

    Science.gov (United States)

    Lu, Fuguang; Li, Huaijiang; Sun, Min; Fan, Lulu; Qiu, Huamin; Li, Xiangjun; Luo, Chuannan

    2012-03-09

    A novel flow injection chemiluminescence (FI-CL) sensor for determination of sulfadiazine (SDZ) using core-shell magnetic molecularly imprinted polymers (MMIPs) as recognition element is developed. Briefly, a hydrophilic MMIPs layer was produced at the surface of Fe(3)O(4)@SiO(2) magnetic nanoparticles (MNPs) via combination of molecular imprinting and reversible stimuli responsive hydrogel. And it provided the MMIPs with excellent adsorption capacity and rapid adsorption rate due to the imprinted sites mostly situated on the surface of MMIPs. Then the prepared SDZ-MMIPs were packed into flow cell to establish a novel FI-CL sensor. The sensor provided a wide linear range for SDZ of 4.0×10(-7) to 1.0×10(-4) mol L(-1) with a detection limit of 1.54×10(-7) mol L(-1). And the relative standard deviation (RSD) for the determination of 1.0×10(-6) mol L(-1) SDZ was 2.56% (n=11). The proposed method was applied to determine SDZ in urine samples and satisfactory results were obtained.

  13. Copper Ferrocyanide Functionalized Core-Shell Magnetic Silica Composites for the Selective Removal of Cesium Ions from Radioactive Liquid Waste.

    Science.gov (United States)

    Lee, Hyun Kyu; Yang, Da Som; Oh, Wonzin; Choi, Sang-June

    2016-06-01

    The copper ferrocyanide functionalized core-shell magnetic silica composite (mag@silica-CuFC) was prepared and was found to be easily separated from aqueous solutions by using magnetic field. The synthesized mag@silica-CuFC composite has a high sorption ability of Cs owing to its strong affinity for Cs as well as the high surface area of the supports. Cs sorption on the mag@silica-CuFC composite quickly reached the sorption equilibrium after 2 h of contact time. The effect of the presence of salts with a high concentration of up to 3.5 wt% on the efficiency of Cs sorption onto the composites was also studied. The maximum sorption ability was found to be maintained in the presence of up to 3.5 wt% of NaCl in the solution. Considering these results, the mag@silica-CuFC composite has great potential for use as an effective sorbent for the selective removal of radioactive Cs ions.

  14. Synthesis and magnetic properties of carbon-coated Ni/SiO2 core/shell nanocomposites

    Institute of Scientific and Technical Information of China (English)

    TANG NuJiang; L(U) LiYa; ZHONG Wei; AU ChakTong; DU YouWei

    2009-01-01

    A simple method for the synthesis of carbon-coated Ni/Si02 core/shell nanocomposites is reported. The Ni nanoparticles were coated with silica layers via a combined procedure of sol-gel fabrication and hydrogen reduction prior to carbon coating via acetylene decomposition at an appropriate temperature. It was found that the anti-acid ability of the Ni/SiO2 composites was greatly enhanced after carbon coating. The results of magnetization measurement show that the real part (μ') of complex permeability of the as-obtained sample is almost independent of frequency, and the imaginary part (μ") stays small up to a frequency of 1 GHz. The encapsulation of Ni particles with SiO2 results in the rise of Ni nanoparticles resistivity. The outcome is the reduction in effect of eddy current at high frequency, making the real part μ' almost constant and the imaginary part μ" very small. Thus, this simple method may be effective for preparing composites of soft magnetic properties, especially in the high-frequency range.

  15. Exploring the structural and magnetic properties of TiO2/SnO2 core/shell nanocomposite: An experimental and density functional study

    Science.gov (United States)

    Chetri, Pawan; Basyach, Priyanka; Choudhury, Amarjyoti

    2014-12-01

    TiO2/SnO2 core/shell nanocomposite is prepared via a simple sol-gel method and the properties are compared with the individual TiO2 (core) and SnO2 (shell). The corresponding characterizations are carried out in terms of structural and magnetic properties of TiO2/SnO2, TiO2 and SnO2 nanosystems. Structural properties are studied via XRD, TEM, Raman spectroscopy, FTIR and XPS. Magnetic characterization is performed by measuring Moment vs. Applied Field for all the samples and Moment vs. Temperature for TiO2/SnO2 core/shell nanocomposite. We also went for a better insight with the help of theoretical measures. First principle calculations have been executed using “Density Functional Theory” (DFT)-based MedeA VASP package to compare the results of TiO2/SnO2 with TiO2 (1 1 0) and SnO2 (1 1 0) surface calculations and its effect on the magnetic nature of the specific nanoparticles. XRD, RAMAN and FTIR gave indirect evidence of formation of core shell nanostructure while TEM micrographs provide the direct evidence of formation of core shell nanostructure. The magnetic study shows a higher saturation magnetization for the core/shell nanostructure compared to pristine TiO2 and SnO2. In this report, we have attempted to relate this experimental observation with the results of the first principle calculations.

  16. Magnetic nanohybrids loaded with bimetal core-shell-shell nanorods for bacteria capture, separation, and near-infrared photothermal treatment.

    Science.gov (United States)

    Hu, Bo; Wang, Ning; Han, Lu; Chen, Ming-Li; Wang, Jian-Hua

    2015-04-20

    A novel antimicrobial nanohybrid based on near-infrared (NIR) photothermal conversion is designed for bacteria capture, separation, and sterilization (killing). Positively charged magnetic reduced graphene oxide with modification by polyethylenimine (rGO-Fe3 O4 -PEI) is prepared and then loaded with core-shell-shell Au-Ag-Au nanorods to construct the nanohybrid rGO-Fe3 O4 -Au-Ag-Au. NIR laser irradiation melts the outer Au shell and exposes the inner Ag shell, which facilitates controlled release of the silver shell. The nanohybrids combine physical photothermal sterilization as a result of the outer Au shell with the antibacterial effect of the inner Ag shell. In addition, the nanohybrid exhibits high heat conductivity because of the rGO and rapid magnetic-separation capability that is attributable to Fe3 O4 . The nanohybrid provides a significant improvement of bactericidal efficiency with respect to bare Au-Ag-Au nanorods and facilitates the isolation of bacteria from sample matrixes. A concentration of 25 μg mL(-1) of nanohybrid causes 100 % capture and separation of Escherichia coli O157:H7 (1×10(8) cfu mL(-1) ) from an aqueous medium in 10 min. In addition, it causes a 22 °C temperature rise for the surrounding solution under NIR irradiation (785 nm, 50 mW cm(-2) ) for 10 min. With magnetic separation, 30 μg mL(-1) of nanohybrid results in a 100 % killing rate for E. coli O157:H7 cells. The facile bacteria separation and photothermal sterilization is potentially feasible for environmental and/or clinical treatment.

  17. Effects of wound toroidal core dimensional and geometrical parameters on measured magnetic properties of electrical steel

    Directory of Open Access Journals (Sweden)

    Koprivica Branko M.

    2013-01-01

    Full Text Available The aim of this paper is to present the results of measurements for the magnetic hysteresis loop and the specific power loss of the electrical steel obtained with the toroidal samples of various dimensions. All samples have been made of the same material. Numerous measurements have been performed after the annealing of the samples. The measurements have been performed with control of the sinusoidal shape of the secondary voltage. Differences between the results of measurements have been analyzed. Change in the measured results, e.g. the shape of the hysteresis loop or the specific power loss has been correlated to the dimensions of the sample. [Projekat Ministarstva nauke Republike Srbije, br. TR 33016

  18. Preparation of Core-Shell Hybrid Materials by Producing a Protein Corona Around Magnetic Nanoparticles

    Science.gov (United States)

    Weidner, A.; Gräfe, C.; von der Lühe, M.; Remmer, H.; Clement, J. H.; Eberbeck, D.; Ludwig, F.; Müller, R.; Schacher, F. H.; Dutz, S.

    2015-07-01

    Nanoparticles experience increasing interest for a variety of medical and pharmaceutical applications. When exposing nanomaterials, e.g., magnetic iron oxide nanoparticles (MNP), to human blood, a protein corona consisting of various components is formed immediately. The composition of the corona as well as its amount bound to the particle surface is dependent on different factors, e.g., particle size and surface charge. The actual composition of the formed protein corona might be of major importance for cellular uptake of magnetic nanoparticles. The aim of the present study was to analyze the formation of the protein corona during in vitro serum incubation in dependency of incubation time and temperature. For this, MNP with different shells were incubated in fetal calf serum (FCS, serving as protein source) within a water bath for a defined time and at a defined temperature. Before and after incubation the particles were characterized by a variety of methods. It was found that immediately (seconds) after contact of MNP and FCS, a protein corona is formed on the surface of MNP. This formation led to an increase of particle size and a slight agglomeration of the particles, which was relatively constant during the first minutes of incubation. A longer incubation (from hours to days) resulted in a stronger agglomeration of the FCS incubated MNP. Quantitative analysis (gel electrophoresis) of serum-incubated particles revealed a relatively constant amount of bound proteins during the first minutes of serum incubation. After a longer incubation (>20 min), a considerably higher amount of surface proteins was determined for incubation temperatures below 40 °C. For incubation temperatures above 50 °C, the influence of time was less significant which might be attributed to denaturation of proteins during incubation. Overall, analysis of the molecular weight distribution of proteins found in the corona revealed a clear influence of incubation time and temperature on corona

  19. Preparation of Core-Shell Hybrid Materials by Producing a Protein Corona Around Magnetic Nanoparticles.

    Science.gov (United States)

    Weidner, A; Gräfe, C; von der Lühe, M; Remmer, H; Clement, J H; Eberbeck, D; Ludwig, F; Müller, R; Schacher, F H; Dutz, S

    2015-12-01

    Nanoparticles experience increasing interest for a variety of medical and pharmaceutical applications. When exposing nanomaterials, e.g., magnetic iron oxide nanoparticles (MNP), to human blood, a protein corona consisting of various components is formed immediately. The composition of the corona as well as its amount bound to the particle surface is dependent on different factors, e.g., particle size and surface charge. The actual composition of the formed protein corona might be of major importance for cellular uptake of magnetic nanoparticles. The aim of the present study was to analyze the formation of the protein corona during in vitro serum incubation in dependency of incubation time and temperature. For this, MNP with different shells were incubated in fetal calf serum (FCS, serving as protein source) within a water bath for a defined time and at a defined temperature. Before and after incubation the particles were characterized by a variety of methods. It was found that immediately (seconds) after contact of MNP and FCS, a protein corona is formed on the surface of MNP. This formation led to an increase of particle size and a slight agglomeration of the particles, which was relatively constant during the first minutes of incubation. A longer incubation (from hours to days) resulted in a stronger agglomeration of the FCS incubated MNP. Quantitative analysis (gel electrophoresis) of serum-incubated particles revealed a relatively constant amount of bound proteins during the first minutes of serum incubation. After a longer incubation (>20 min), a considerably higher amount of surface proteins was determined for incubation temperatures below 40 °C. For incubation temperatures above 50 °C, the influence of time was less significant which might be attributed to denaturation of proteins during incubation. Overall, analysis of the molecular weight distribution of proteins found in the corona revealed a clear influence of incubation time and temperature on

  20. A Key to Improved Ion Core Confinement in the JET Tokamak: Ion Stiffness Mitigation due to Combined Plasma Rotation and Low Magnetic Shear

    DEFF Research Database (Denmark)

    Mantica, P.; Challis, C.; Peeters, A.G.

    2011-01-01

    New transport experiments on JET indicate that ion stiffness mitigation in the core of a rotating plasma, as described by Mantica et al. Phys. Rev. Lett. 102 175002 (2009)] results from the combined effect of high rotational shear and low magnetic shear. The observations have important implicatio...

  1. First application of core-shell Ag@Ni magnetic nanocatalyst for transfer hydrogenation reactions of aromatic nitro and carbonyl compounds

    Science.gov (United States)

    A magnetic separable core-shell Ag@Ni nanocatalyst was prepared by a simple one-pot synthetic route using oleylamine both as solvent and reducing agent and triphenylphosphine as surfactant. The synthesized nanoparticles were characterized by several techniques such as X-ray diffr...

  2. Optical peak gain in a PbSe/CdSe core-shell quantum dot in the presence of magnetic field for mid-infrared laser applications

    Science.gov (United States)

    Saravanamoorthy, S. N.; John Peter, A.; Lee, Chang Woo

    2017-02-01

    Magnetic field induced electronic properties and some nonlinear optical properties of an exciton are investigated taking into account the geometrical confinement effects in a PbSe/CdSe core-shell heterostructure. The effects of dielectric mismatch between the inner and outer materials, built-in internal electric fields and the self-polarization potential are included in the calculation of obtaining these properties. Self-polarization charges are incorporated at the interface of the core-shell materials. The magnetic field dependent exciton binding energies are found with the ratio of core-shell radii of the dot using variational formulism within the single band effective mass approximation. The magnetic field induced oscillator strength and the radiative life time of the exciton are studied for a constant dot radius. The absorption coefficients and the optical gain as a function of photon energy, the peak gain with the current density are investigated in the PbSe/CdSe core-shell dot for various values of magnetic field strength.

  3. Control of Saturation level in the magnetic core of a welding transformer by Hysteresis Controller (HC and Proportional Integral (PI Controller

    Directory of Open Access Journals (Sweden)

    Rama Subbanna.S

    2016-12-01

    Full Text Available The objective of this paper is to analyse the performances of two controllers such as Hysteresis control (HC and proportional integral (PI control to control saturation level in the magnetic core of a welding transformer in a middle-frequency direct current (MFDC resistance spot welding system(RSWS. It consists of an input converter, welding transformer, and a full-wave rectifier mounted at the transformer secondary. The unequal ohmic resistances of the two transformer’s secondary circuits and the different characteristics of the diodes of output rectifier certainly lead to the magnetic core saturation which, consequently, causes the unwanted spikes in the transformer’s primary current and over-current protection switch-off. The goal is to analyse the performance of both controllers in terms of transients, total harmonic distortion(THD and variations in primary current and flux in the magnetic core of a welding transformer of highly nonlinear system of RSWS. The simulation study has been done in Matlab/Simulink environment and presented performance analysis. The responses shows that from the aforementioned aspects, proportional integral Controller is the better choice for controlling the saturation level in magnetic core of a welding transformer which is widely used in automobile industry welding system.

  4. Synthesis of core-shell magnetic molecular imprinted polymer by the surface RAFT polymerization for the fast and selective removal of endocrine disrupting chemicals from aqueous solutions

    Energy Technology Data Exchange (ETDEWEB)

    Li Ying [Department of Chemistry, Harbin Institute of Technology, Harbin 150090 (China); Li Xin, E-mail: lixin@hit.edu.c [Department of Chemistry, Harbin Institute of Technology, Harbin 150090 (China); Chu Jia; Dong Cunku [Department of Chemistry, Harbin Institute of Technology, Harbin 150090 (China); Qi Jingyao; Yuan Yixing [School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090 (China)

    2010-06-15

    In this study, we present a general protocol for the making of surface-imprinted core-shell magnetic beads via reversible addition-fragmentation chain transfer (RAFT) polymerization using RAFT agent functionalized iron oxide nanoparticles as the chain transfer agent. The resulting composites were characterized by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) analysis, thermogravimetric analysis (TGA), vibrating sample magnetometer (VSM), and scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The surface-imprinted magnetic beads were demonstrated with a homogeneous polymer films (thickness of about 22 nm), spherical shape, and exhibited magnetic property (Ms = 0.41 mA m{sup 2} g{sup -1}) and thermal stability. Rebinding experiments were carried out to determine the specific binding capacity and selective recognition. The as-synthesized surface-imprinted core-shell magnetic beads showed outstanding affinity and selectivity towards bisphenol A over structurally related compounds, and easily reach the magnetic separation under an external magnetic field. In addition, the resulting composites reusability without obviously deterioration in performance was demonstrated at least five repeated cycles. - Magnetic molecular imprinted polymers have potential as adsorptive materials in water treatment.

  5. Exploring the structural and magnetic properties of TiO{sub 2}/SnO{sub 2} core/shell nanocomposite: An experimental and density functional study

    Energy Technology Data Exchange (ETDEWEB)

    Chetri, Pawan; Basyach, Priyanka; Choudhury, Amarjyoti, E-mail: ajc@tezu.ernet.in

    2014-12-15

    TiO{sub 2}/SnO{sub 2} core/shell nanocomposite is prepared via a simple sol–gel method and the properties are compared with the individual TiO{sub 2} (core) and SnO{sub 2} (shell). The corresponding characterizations are carried out in terms of structural and magnetic properties of TiO{sub 2}/SnO{sub 2}, TiO{sub 2} and SnO{sub 2} nanosystems. Structural properties are studied via XRD, TEM, Raman spectroscopy, FTIR and XPS. Magnetic characterization is performed by measuring Moment vs. Applied Field for all the samples and Moment vs. Temperature for TiO{sub 2}/SnO{sub 2} core/shell nanocomposite. We also went for a better insight with the help of theoretical measures. First principle calculations have been executed using “Density Functional Theory” (DFT)-based MedeA VASP package to compare the results of TiO{sub 2}/SnO{sub 2} with TiO{sub 2} (1 1 0) and SnO{sub 2} (1 1 0) surface calculations and its effect on the magnetic nature of the specific nanoparticles. XRD, RAMAN and FTIR gave indirect evidence of formation of core shell nanostructure while TEM micrographs provide the direct evidence of formation of core shell nanostructure. The magnetic study shows a higher saturation magnetization for the core/shell nanostructure compared to pristine TiO{sub 2} and SnO{sub 2}. In this report, we have attempted to relate this experimental observation with the results of the first principle calculations. - Graphical abstract: Above pictorial presentation (from left) represents the model for TS, TiO{sub 2} and SnO{sub 2} used for DFT calculation and the obtained magnetic results for all the prepared systems. - Highlights: • Synthesis of TiO{sub 2}/SnO{sub 2} core/shell nanocomposites by a simple sol–gel technique. • The nanocomposites show better magnetic property than pristine nanoparticles. • DFT based calculations also support the experimental evidences.

  6. A comparison of and the compensation for magnetostrictive core inductances in magnetic transducer systems

    Science.gov (United States)

    Bartlett, P. A.; Meydan, T.; Lea, S. C.; Moses, A. J.; Williams, P. I.; Landini, G.; Walmsley, A. D.

    Magnetostrictive materials have been utilized for the production of ultrasonic frequency vibrations for a number of years. This has particularly been the case in laminated nickel-based ultrasonic dental-scaler cleaning systems. In this study, a comparison has been made between the impedances of a number of magnetostrictive stacks of 50 mm×4 mmט0.3 mm strips at frequencies in the range of 10-50 kHz in a coil used for the excitation of a stack in a dental-scaler system. The magnetostrictive stacks tested comprised of potential replacement materials for standard nickel ones. The study showed that it was possible to compensate for the inductive 'imaginary' components of the impedance through the use of a tuned, series capacitance so that only the 'real' resistive component of the impedance remained. This reduced the electrical losses associated with the excitation of the magnetostrictive stacks as a result of the frequency-dependent inductance of the coil system. Consequently, the maximum power transfer from an amplifier to the transducer was increased. Also, the investigation showed how the 'real' component of impedance of the different stacks varied with frequency. In a tuned resonant electrical circuit, the resistive component of the impedance, if considered as a loss, would be the lowest that could be achieved with such a magnetic circuit. Consequently, the losses associated with resonant magnetostrictive devices, like dental scalers, can be reduced.

  7. Control of the binding energy by tuning the single dopant position, magnetic field strength and shell thickness in ZnS/CdSe core/shell quantum dot

    Science.gov (United States)

    Talbi, A.; Feddi, E.; Zouitine, A.; Haouari, M. El; Zazoui, M.; Oukerroum, A.; Dujardin, F.; Assaid, E.; Addou, M.

    2016-10-01

    Recently, the new tunable optoelectronic devices associated to the inclusion of the single dopant are in continuous emergence. Combined to other effects such as magnetic field, geometrical confinement and dielectric discontinuity, it can constitute an approach to adjusting new transitions. In this paper, we present a theoretical investigation of magnetic field, donor position and quantum confinement effects on the ground state binding energy of single dopant confined in ZnS/CdSe core/shell quantum dot. Within the framework of the effective mass approximation, the Schrödinger equation was numerically been solved by using the Ritz variational method under the finite potential barrier. The results show that the binding energy is very affected by the core/shell sizes and by the external magnetic field. It has been shown that the single dopant energy transitions can be controlled by tuning the dopant position and/or the field strength.

  8. New chrysin-functionalized silica-core shell magnetic nanoparticles for the magnetic solid phase extraction of copper ions from water samples.

    Science.gov (United States)

    Abd Ali, Layth Imad; Ibrahim, Wan Aini Wan; Sulaiman, Azli; Kamboh, Muhammad Afzal; Sanagi, Mohd Marsin

    2016-01-01

    This study describes the synthesis, characterization and application of a new chrysin-based silica core-shell magnetic nanoparticles (Fe3O4@SiO2-N-chrysin) as an adsorbent for the preconcentration of Cu(II) from aqueous environment. The morphology, thermal stability and magnetic property of Fe3O4@SiO2-N-chrysin were analyzed using FTIR, FESEM, TEM, XRD, thermal analysis and VSM. The extraction efficiency of Fe3O4@SiO2-N-chrysin was analyzed using the batch wise method with flame atomic absorption spectrometry. Parameters such as the pH, the sample volume, the adsorption-desorption time, the concentration of the desorption solvent, the desorption volume, the interference effects and the regeneration of the adsorbent were optimized. It was determined that Cu(II) adsorption is highly pH-dependent, and a high recovery (98%) was achieved at a pH 6. The limit of detection (S/N=3), the limit of quantification (S/N=10), the preconcentration factor and the relative standard deviation for Cu(II) extraction were 0.3 ng mL(-1), 1 ng mL(-1), 100 and 1.9% (concentration=30 ng mL(-1), n=7), respectively. Excellent relative recoveries of 97-104% (%RSD<3.12) were achieved from samples from a spiked river, a lake and tap water. The MSPE method was also validated using certified reference materials SLRS-5 with good recovery (92.53%).

  9. Movable magnetic porous cores enclosed within carbon microcapsules: structure-controlled synthesis and promoted carbon-based applications.

    Science.gov (United States)

    You, Lijun; Zhang, Yuting; Xu, Shuai; Guo, Jia; Wang, Changchun

    2014-09-10

    Rattle-type porous carbon microcapsules (RPCMs) were deliberately designed to combine multiple functions with the aim of improving the applicability of amorphous carbon in a synergistic fashion. A movable Fe3O4 nanocluster coated with porous carbon is encapsulated in the cavity of a carbon microcapsule with an eggshell-like characteristic, allowing for storage, adsorption, and exchange of matters through the mesoporous channels of the carbon layer. The synthetic strategy of RPCMs is flexible and universal, involving the constitution and carbonization of Fe3O4@PF@PS@PF template particles. This results in a double carbon shell and a sandwiched hollow cavity with a movable magnetic core. There is evidence that RPCMs possess large surface areas, hierarchical pore sizes, hydrophobicity, and magnetic responsiveness. Hence, diverse applications have been investigated. It is proved that RPCMs exhibit excellent performance in the effective enrichment of peptides/proteins. The detection limit toward peptides could reach as low as 10 nM, and the enrichment capacity toward MYO protein is as high as 410 mg/g (protein/beads). Furthermore, RPCMs are able to harvest proteins in complex real samples such as fetal bovine serum and rabbit blood. In addition, RPCMs could be fabricated in a supercapacitor electrode and display outstanding energy-storage performance. The electrochemical measurements demonstrate that RPCM-based electrodes have a specific capacitance of as high as 216 F/g (0.1 A/g), long-term cycling stability with a capacitance retention of 92.4% over 1000 cycles (0.2 A/g), and good electronic conductivity.

  10. Temperature dependence of magnetic properties of SiO{sub 2}-coated Co nanoparticles[75.50.K; 75.60.E; Co nanoparticles; Oxide core; Saturation magnetization; Coercivity; Exchange anisotropy

    Energy Technology Data Exchange (ETDEWEB)

    Wu Mingzhong E-mail: wumingzhong2000@yahoo.com; Zhang, Y.D.; Hui, S.; Xiao, T.D.; Ge Shihui; Hines, W.A.; Budnick, J.I

    2004-01-01

    SiO{sub 2}-coated Co nanoparticles were synthesized; the different temperature-dependent magnetic behaviors between Co nanoparticles with and without inner Co-oxide cores were observed. For Co nanoparticles free of Co-oxide cores, the magnetization obeyed Bloch's T{sup 3/2} law with a Bloch constant close to the bulk value; the coercivity exhibited a weak and linear dependence on temperature. For Co nanoparticles with Co-oxide cores, the Bloch exponents fell from 1.5 to smaller values and decreased with increasing Co-oxide concentration; the coercivity significantly increased with decreasing temperature due to the presence of exchange anisotropy, which arose from the exchange coupling across the Co/CoO interfaces.

  11. Degradation of synthetic pollutants in real wastewater using laccase encapsulated in core-shell magnetic copper alginate beads.

    Science.gov (United States)

    Le, Thao Thanh; Murugesan, Kumarasamy; Lee, Chung-Seop; Vu, Chi Huong; Chang, Yoon-Seok; Jeon, Jong-Rok

    2016-09-01

    Immobilization of laccase has been highlighted to enhance their stability and reusability in bioremediation. In this study, we provide a novel immobilization technique that is very suitable to real wastewater treatment. A perfect core-shell system composing copper alginate for the immobilization of laccase (Lac-beads) was produced. Additionally, nFe2O3 was incorporated for the bead recycling through magnetic force. The beads were proven to immobilize 85.5% of total laccase treated and also to be structurally stable in water, acetate buffer, and real wastewater. To test the Lac-beads reactivity, triclosan (TCS) and Remazol Brilliant Blue R (RBBR) were employed. The Lac-beads showed a high percentage of TCS removal (89.6%) after 8h and RBBR decolonization at a range from 54.2% to 75.8% after 4h. Remarkably, the pollutants removal efficacy of the Lac-beads was significantly maintained in real wastewater with the bead recyclability, whereas that of the corresponding free laccase was severely deteriorated. Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. Laser-assisted synthesis of magnetic Fe/Fe{sub 2}O{sub 3} core: carbon-shell nanoparticles in organic solvents

    Energy Technology Data Exchange (ETDEWEB)

    Moussa, Sherif; Atkinson, Garrett; El-Shall, M. Samy, E-mail: mselshal@vcu.edu [Virginia Commonwealth University, Department of Chemistry (United States)

    2013-03-15

    This work provides a new approach for the solution laser synthesis of magnetic Fe/Fe{sub 2}O{sub 3} nanoparticles (15-25 nm average size), as well as core-shell nanoparticles consisting of crystalline Fe/Fe{sub 2}O{sub 3} cores (5-15 nm average size), and amorphous carbon-shells. Laser irradiation of iron pentacarbonyl, Fe(CO){sub 5}, in different organic solvents (toluene, tetrahydrofuran, dimethyl sulphoxide, and acetonitrile) using the 532- and 355-nm wavelengths was investigated. The mechanism operating in the laser synthesis involves photodecomposition of Fe(CO){sub 5} and the formation of iron and/or an iron oxide core surrounded by a carbon-shell depending on the nature of the solvent. In the case of toluene as a solvent, a magnetic Fe/Fe{sub 2}O{sub 3} core surrounded by a carbon-shell was formed, while in the other solvents investigated (tetrahydrofuran, dimethyl sulphoxide, and acetonitrile), both Fe and Fe{sub 2}O{sub 3} nanoparticles were formed without carbon-shells. Characterization techniques including X-ray photoelectron spectroscopy, transmission electron microscopy, X-ray diffraction, and Raman spectroscopy were used to determine the composition and morphology of the laser-synthesized magnetic Fe/Fe{sub 2}O{sub 3} nanoparticles and the core-shell nanoparticles. In addition, the data revealed that the Fe/Fe{sub 2}O{sub 3}-nanoparticles produced in all the solvents used except tetrahydrofuran had good magnetic properties.

  13. Spontaneously formed interfacial metal silicates and their effect on the magnetism of superparamagnetic FeCo/SiO₂ core/shell nanoparticles.

    Science.gov (United States)

    Desautels, Ryan D; Rowe, Michael P; Jones, Michael; Whallen, Amanda; van Lierop, Johan

    2015-03-10

    The integration of superparamagnetic core/shell nanoparticles into devices and other nanoscale technological applications requires a detailed understanding of how the intimate contact between core and shell nanophases affects the magnetism. We report how, for single-domain FeCo nanoparticles, an FeCo phase unique to the nanoscale with silica shells of increasing thicknesses spontaneously formed interfacial metal silicates between the core and shell (such as Fe2SiO4 and Co2SiO4) and altered the overall magnetism of the nanomaterial significantly. The influence of this previously overlooked phenomenon on magnetic properties is reported. Evidence of these metal silicate interfacial layers was observed by X-ray absorption spectroscopy (XAS) collected over the L3,2 absorption edges of Fe and X-ray photoelectron spectra (XPS) collected over the 2p transitions of Fe and Co. Through the correlation of magnetometry and XPS data, the evolution of nanoparticle magnetic anisotropy is shown to increase with the metal silicate.

  14. Electrodeposited Co{sub 93.2}P{sub 6.8} nanowire arrays with core-shell microstructure and perpendicular magnetic anisotropy

    Energy Technology Data Exchange (ETDEWEB)

    Nasirpouri, F.; Peighambari, S. M. [Faculty of Materials Engineering, Sahand University of Technology, Tabriz 51335-1996 (Iran, Islamic Republic of); Samardak, A. S., E-mail: asamardak@gmail.com; Ognev, A. V.; Sukovatitsina, E. V.; Modin, E. B.; Chebotkevich, L. A. [School of Natural Sciences, Far Eastern Federal University, Vladivostok (Russian Federation); Komogortsev, S. V. [Institute of Physics, SB Russian Academy of Sciences, Krasnoyarsk 660036 (Russian Federation); Bending, S. J. [Department of Physics, University of Bath, Bath (United Kingdom)

    2015-05-07

    We demonstrate the formation of an unusual core-shell microstructure in Co{sub 93.2}P{sub 6.8} nanowires electrodeposited by alternating current (ac) in an alumina template. By means of transmission electron microscopy, it is shown that the coaxial-like nanowires contain amorphous and crystalline phases. Analysis of the magnetization data for Co-P alloy nanowires indicates that a ferromagnetic core is surrounded by a weakly ferromagnetic or non-magnetic phase, depending on the phosphor content. The nanowire arrays exhibit an easy axis of magnetization parallel to the wire axis. For this peculiar composition and structure, the coercivity values are 2380 ± 50 and 1260 ± 35 Oe, parallel and perpendicular to the plane directions of magnetization, respectively. This effect is attributed to the core-shell structure making the properties and applications of these nanowires similar to pure cobalt nanowires with an improved perpendicular anisotropy.

  15. Postmortem Study of Validation of Low Signal on Fat-Suppressed T1-Weighted Magnetic Resonance Imaging as Marker of Lipid Core in Middle Cerebral Artery Atherosclerosis

    Science.gov (United States)

    Yang, Wen-Jie; Zhao, Hai-Lu; Niu, Chun-Bo; Zhang, Bing; Xu, Yun; Wong, Ka-Sing; Ng, Ho-Keung

    2016-01-01

    Background and Purpose— High signal on T1-weighted fat-suppressed images in middle cerebral artery plaques on ex vivo magnetic resonance imaging was verified to be intraplaque hemorrhage histologically. However, the underlying plaque component of low signal on T1-weighted fat-suppressed images (LST1) has never been explored. Based on our experience, we hypothesized that LST1 might indicate the presence of lipid core within intracranial plaques. Methods— 1.5 T magnetic resonance imaging was performed in the postmortem brains to scan the cross sections of bilateral middle cerebral arteries. Then middle cerebral artery specimens were removed for histology processing. LST1 presence was identified on magnetic resonance images, and lipid core areas were measured on the corresponding histology sections. Results— Total 76 middle cerebral artery locations were included for analysis. LST1 showed a high specificity (96.9%; 95% confidence interval, 82.0%–99.8%) but a low sensitivity (38.6%; 95% confidence interval, 24.7%–54.5%) for detecting lipid core of all areas. However, the sensitivity increased markedly (81.2%; 95% confidence interval, 53.7%–95.0%) when only lipid cores of area ≥0.80 mm2 were included. Mean lipid core area was 5× larger in those with presence of LST1 than in those without (1.63±1.18 mm2 versus 0.32±0.31 mm2; P=0.003). Conclusions— LST1 is a promising imaging biomarker of identifying intraplaque lipid core, which may be useful to distinguish intracranial atherosclerotic disease from other intracranial vasculopathies and to assess plaque vulnerability for risk stratification of patients with intracranial atherosclerotic disease. In vivo clinical studies are required to explore the correlation between LST1 and clinical outcomes of patients with intracranial atherosclerotic disease. PMID:27462119

  16. 超低损耗角磁心高频损耗测量方法%High Frequency Core Loss Measurement of Low Loss Angle Magnetic Component

    Institute of Scientific and Technical Information of China (English)

    汪晶慧; 陈为

    2012-01-01

    针对传统交流功率计法测量阻抗角接近90。的磁件磁心损耗时有很大的测量误差,提出了一种新型的直流测量法,基本思想是通过一个DC.AC逆变电路将直流电压转变为矩形波电压,施加到被测磁件上,测量直流输入的有功功率得到磁心损耗。其中,为了有效扣除磁心损耗外的其他损耗,提出了用空心电感定标的方法。实验结果表明:直流测量法可用来测量小损耗角磁件磁心损耗,且不受阻抗角的影响,具有很高的精度。%The measurement error of core loss by AC meter will be very large especially when the impedance angle of magnetic component is closed to 90°. So a new DC meter method is proposed in this paper. The basic idea is to transform the input DC voltage into a square waveform on the magnetic component by a DC-AC inverter, and obtained the core loss by measuring the input active power. The method could avoid the influence of impedance angle to the measurement accuracy. However, with this method, the losses excepting for core loss should be excluded someway. A method of calibration with air core inductor is proposed to effectively calculate and take out the losses except core loss. The experimental results verify that the DC meter method is accurate to measure the core loss of low loss angle magnetic component.

  17. Abnormality of magnetic behavior and core loss of nanocrystalline Fe73.5Cu1Nb3Si15.5B7 alloy

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    The correlation between microstructure and magnetic properties of Fe73.5Cu1Nb3Si15.5B7 alloy annealed at 360°C—620°C has been investigated. The best static and dynamic soft magnetic properties have been obtained after annealing at 500°C and 550°C for 1 h, respectively. The dependence of annealing temperature on coercivity has shown three magnetic hardenings for the studied alloys annealed at 460°C, 530°C and 620°C, respectively. And the plot of core loss as a function of annealing temperature manifests a peak at 530℃, and this peak increases with increasing magnetic induction at low frequencies. This effect can probably be attributed to the precipitation of a new phase.

  18. Highly selective removal of Hg2+ and Pb2+ by thiol-functionalized Fe3O4@metal-organic framework core-shell magnetic microspheres

    Science.gov (United States)

    Ke, Fei; Jiang, Jing; Li, Yizhi; Liang, Jing; Wan, Xiaochun; Ko, Sanghoon

    2017-08-01

    In this work, we report a novel type of thiol-functionalized magnetic core-shell metal-organic framework (MOF) microspheres that can be potentially used for selective removal of Hg2+ and Pb2+ in the presence of other background ions from wastewater. The monodisperse Fe3O4@Cu3(btc)2 core-shell magnetic microspheres have been fabricated by a versatile step-by-step assembly strategy. Further, the thiol-functionalized Fe3O4@Cu3(btc)2 magnetic microspheres were successfully synthesized by utilizing a facile postsynthetic strategy. Significantly, the thiol-functionalized Fe3O4@Cu3(btc)2 magnetic microspheres exhibit remarkably selective adsorption affinity for Hg2+ (Kd = 5.98 × 104 mL g-1) and Pb2+ (Kd = 1.23 × 104 mL g-1), while a weaker binding affinity occurred for the other background ions such as Ni2+, Na+, Mg2+, Ca2+, Zn2+ and Cd2+. The adsorption kinetics follow the pseudo-second-order rate equation and with an almost complete removal of Hg2+ and Pb2+ from the mixed heavy metal ions wastewater (0.5 mM) within 120 min. Moreover, this adsorbent can be easily recycled because of the presence of the magnetic Fe3O4 core. This work provides a promising functionalized porous magnetic Fe3O4@MOF-based adsorbent with easy recycling property for the selective removal of heavy metal ions from wastewater.

  19. Submillimeter Array Observations of Magnetic Fields in G240.31+0.07: an Hourglass in a Massive Cluster-forming Core

    OpenAIRE

    Qiu, Keping; Zhang, Qizhou; Menten, Karl M.; Liu, Hauyu B.; Tang, Ya-Wen; Girart, Josep M.

    2014-01-01

    We report the first detection of an hourglass magnetic field aligned with a well-defined outflow-rotation system in a high-mass star-forming region. The observations were performed with Submillimeter Array toward G240.31+0.07, which harbors a massive, flattened, and fragmenting molecular cloud core and a wide-angle bipolar outflow. The polarized dust emission at 0.88 mm reveals a clear hourglass-shaped magnetic field aligned within 20 degree of the outflow axis. Maps of high-density tracing s...

  20. Acid-triggered core cross-linked nanomicelles for targeted drug delivery and magnetic resonance imaging in liver cancer cells

    Directory of Open Access Journals (Sweden)

    Li X

    2013-08-01

    Full Text Available Xian Li,1,* Hao Li,2,4,* Wei Yi,3 Jianyu Chen,1 Biling Liang1 1Radiology Department, The Sun Yat-Sen Memorial Hospital, Sun Yat-Sen University, Guangzhou, People's Republic of China; 2Center of Biomedical Engineering, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, People's Republic of China; 3Radiotherapy Department, The First Affiliated Hospital, Guangzhou Medical University, Guangzhou, People's Republic of China; 4School of Engineering, Sun Yat-Sen University, Guangzhou, People's Republic of China *These authors contributed equally to this work Purpose: To research the acid-triggered core cross-linked folate-poly(ethylene glycol-b-poly[N-(N',N'-diisopropylaminoethyl glutamine] (folated-PEG-P[GA-DIP] amphiphilic block copolymer for targeted drug delivery and magnetic resonance imaging (MRI in liver cancer cells. Methods: As an appropriate receptor of protons, the N,N-diisopropyl tertiary amine group (DIP was chosen to conjugate with the side carboxyl groups of poly(ethylene glycol-b-poly (L-glutamic acid to obtain PEG-P(GA-DIP amphiphilic block copolymers. By ultrasonic emulsification, PEG-P(GA-DIP could be self-assembled to form nanosized micelles loading doxorubicin (DOX and superparamagnetic iron oxide nanoparticles (SPIONs in aqueous solution. When PEG-P(GA-DIP nanomicelles were combined with folic acid, the targeted effect of folated-PEG-P(GA-DIP nanomicelles was evident in the fluorescence and MRI results. Results: To further increase the loading efficiency and the cell-uptake of encapsulated drugs (DOX and SPIONs, DIP (pKa≈6.3 groups were linked with ~50% of the side carboxyl groups of poly(L-glutamic acid (PGA, to generate the core cross-linking under neutral or weakly acidic conditions. Under the acidic condition (eg, endosome/lysosome, the carboxyl groups were neutralized to facilitate disassembly of the P(GA-DIP blocks' cross-linking, for duly accelerating the encapsulated drug release. Combined

  1. Optomagnetic Detection of MicroRNA Based on Duplex-Specific Nuclease-Assisted Target Recycling and Multilayer Core-Satellite Magnetic Superstructures

    DEFF Research Database (Denmark)

    Tian, Bo; Ma, Jing; Qiu, Zhen

    2017-01-01

    -efficiency, and potential for bioresponsive multiplexing. Herein, we demonstrate a sensitive and rapid miRNA detection method based on optomagnetic read-out, duplex-specific nuclease (DSN)-assisted target recycling, and the use of multilayer core-satellite magnetic superstructures. Triggered by the presence of target mi......RNA and DSN-assisted target recycling, the core-satellite magnetic superstructures release their "satellites" to the suspension, which subsequently can be quantified accurately in a low-cost and user-friendly optomagnetic setup. Target miRNAs are preserved in the cleaving reaction and can thereby trigger more...... cleavage and release of "satellites". For singleplex detection of let-7b, a linear detection range between 10 fM and 10 nM was observed, and a detection limit of 4.8 fM was obtained within a total assay time of 70 min. Multiplexing was achieved by releasing nanoparticles of different sizes in the presence...

  2. Magnetic field directed assembly of superstructures of ferrite-ferroelectric core-shell nanoparticles and studies on magneto-electric interactions

    Energy Technology Data Exchange (ETDEWEB)

    Srinivasan, G., E-mail: srinivas@oakland.edu; Sreenivasulu, G.; Benoit, Crystal [Physics Department, Oakland University, Rochester, Michigan 48309 (United States); Petrov, V. M. [Physics Department, Oakland University, Rochester, Michigan 48309 (United States); Institute of Electronic and Information Systems, Novgorod State University, Veliky Novgorod 173003 (Russian Federation); Chavez, F. [Chemistry Department, Oakland University, Rochester, Michigan 48309 (United States)

    2015-05-07

    Composites of ferromagnetic and ferroelectric are of interest for studies on mechanical strain mediated magneto-electric (ME) interactions and for useful technologies. Here, we report on magnetic-field-assisted-assembly of barium titanate (BTO)-nickel ferrite (NFO) core-shell particles into linear chains and 2D/3D arrays and measurements of ME effects in such assemblies. First, we synthesized the core-shell nano-particles with 50–600 nm BTO and 10–200 nm NFO by chemical self-assembly by coating the ferroic particles with complementary coupling groups and allowing them to self-assemble in the presence of a catalyst via the “click” reaction. The core-shell structure was confirmed with electron microscopy and scanning probe microscopy. We obtained superstructure of the core-shell particles by subjecting them to a magnetic field gradient that exerts an attractive force on the particles and align them toward the regions of high field strengths. At low particle concentration, linear chains were formed and they evolved into 2D and 3D arrays at high particle concentrations. Magnetoelectric characterization on unassembled films and assembled arrays has been performed through measurements of low-frequency ME voltage coefficient (MEVC) by subjecting the sample to a bias magnetic field and an ac magnetic field. The MEVC is higher for field-assembled samples than for unassembled films and is found to be sensitive to field orientation with a higher MEVC for magnetic fields parallel to the array direction than for magnetic fields perpendicular to the array. A maximum MEVC of 20 mV/cm Oe, one of the highest reported for any bulk nanocomposite, is measured across the array thickness. A model is provided for ME coupling in the superstructures of BTO-NFO particulate composites. First, we estimated the MEVC for a free-standing BTO-NFO core-shell particle and then extended the model to include an array of linear chains of the particles. The theoretical estimates are in

  3. Magnetic resonance metabolic profiling of breast cancer tissue obtained with core needle biopsy for predicting pathologic response to neoadjuvant chemotherapy.

    Directory of Open Access Journals (Sweden)

    Ji Soo Choi

    Full Text Available The purpose of this study was to determine whether metabolic profiling of core needle biopsy (CNB samples using high-resolution magic angle spinning (HR-MAS magnetic resonance spectroscopy (MRS could be used for predicting pathologic response to neoadjuvant chemotherapy (NAC in patients with locally advanced breast cancer. After institutional review board approval and informed consent were obtained, CNB tissue samples were collected from 37 malignant lesions in 37 patients before NAC treatment. The metabolic profiling of CNB samples were performed by HR-MAS MRS. Metabolic profiles were compared according to pathologic response to NAC using the Mann-Whitney test. Multivariate analysis was performed with orthogonal projections to latent structure-discriminant analysis (OPLS-DA. Various metabolites including choline-containing compounds were identified and quantified by HR-MAS MRS in all 37 breast cancer tissue samples obtained by CNB. In univariate analysis, the metabolite concentrations and metabolic ratios of CNB samples obtained with HR-MAS MRS were not significantly different between different pathologic response groups. However, there was a trend of lower levels of phosphocholine/creatine ratio and choline-containing metabolite concentrations in the pathologic complete response group compared to the non-pathologic complete response group. In multivariate analysis, the OPLS-DA models built with HR-MAS MR metabolic profiles showed visible discrimination between the pathologic response groups. This study showed OPLS-DA multivariate analysis using metabolic profiles of pretreatment CNB samples assessed by HR- MAS MRS may be used to predict pathologic response before NAC, although we did not identify the metabolite showing statistical significance in univariate analysis. Therefore, our preliminary results raise the necessity of further study on HR-MAS MR metabolic profiling of CNB samples for a large number of cancers.

  4. Folic acid-functionalized magnetic ZnFe2O4 hollow microsphere core/mesoporous silica shell composite particles: synthesis and application in drug release.

    Science.gov (United States)

    Yang, Dandan; Wei, Kaiwei; Liu, Qi; Yang, Yong; Guo, Xue; Rong, Hongren; Cheng, Mei-Ling; Wang, Guoxiu

    2013-07-01

    A drug delivery system was designed by deliberately combining the useful functions into one entity, which was composed of magnetic ZnFe2O4 hollow microsphere as the core, and mesoporous silica with folic acid molecules as the outer shell. Amine groups coated magnetic ZnFe2O4 hollow microsphere core/mesoporous silica shell (MZHM-MSS-NH2) composite particles were first synthesized by a one-pot direct co-condensation method. Subsequently a novel kind of folic acid-functionalized magnetic ZnFe2O4 hollow microsphere core/mesoporous silica shell (MZHM-MSS-NHFA) composite particles were synthesized by conjugating folic acid as targeted molecule to MZHM-MSS-NH2. Ibuprofen, a well-known antiphlogistic drug, was used as a model drug to assess the loading and releasing behavior of the composite microspheres. The results show that the MZHM-MSS-NHFA system has the higher capacity of drug storage and good sustained drug-release property.

  5. Size dependent structural, vibrational and magnetic properties of BiFeO3 and core-shell structured BiFeO3@SiO2 nanoparticles

    Science.gov (United States)

    Chauhan, Sunil; Kumar, Manoj; Chhoker, Sandeep; Katyal, S. C.

    2014-04-01

    Bulk BiFeO3, BiFeO3 nanoparticles and core-shell structured BiFeO3@SiO2 nanoparticles were synthesized by solid state reaction method, sol-gel and Stöber process (SiO2 shell) respectively. Transmission electron microscopy image confirmed the core-shell structure of BiFeO3@SiO2 nanoparticles with BiFeO3 core ˜50-90 nm and SiO2 shell ˜16 nm. X-ray diffraction and FTIR spectroscopy results showed the presence of distorted rhombohedral structure with R3c space group in all three samples. The magnetic measurement indicated the existence of room-temperature weak ferromagnetism in core-shell BiFeO3@SiO2 nanoparticles and BiFeO3 nanoparticles, whereas bulk BiFeO3 showed antiferromagnteic nature. Electron Spin Resonance results confirmed the enhancement in magnetic properties of coreshell structured BiFeO3@SiO2 nanoparticles in comparison with BiFeO3 nanoparticles and bulk BiFeO3.

  6. Multifunctional CdS/CoFe2O4 fluorescent/magnetic core/shell nanocomposite structure for bio-applications

    Science.gov (United States)

    Singh, Simrjit; Khare, Neeraj; Sivakumar, Balasubramanian; Aravind, Athulya; Nair Sakthikumar, Dasappan

    2016-04-01

    In this work, self-assembled core/shell nanostructures of CdS/CoFe2O4 (CFO) have been synthesized using a chemical solution method to include magnetic and fluorescent properties in a single composite material for bioapplications. Successful synthesis of the core/shell nanostructure has been evidenced from the transmission electron microscopy and x-ray diffraction results. Alternating gradient magnetometer and photoluminescence spectroscopy results confirm good magnetic and luminescent characteristics of the core/shell nanostructure. The in vitro biocompatibility of the CFO and CdS/CFO nanostructures has been studied in the Alamar blue assay in four different cell lines (MIAPaCa-2, MCF-7, KUSA-A1, and L929 cells) at different concentrations of nanostructures. The CdS/CFO nanostructure shows improved biocompatibility in all the cell lines as compared to bare CFO nanostructures at all concentrations. However, the biocompatibility for both the nanostructures is found to decrease in the KUSA-A1 cell line at higher concentrations of the nanostructures, which is due to the higher sensitivity of the KUSA-A1 cell line to the nanostructures at higher concentrations than other cell lines. Biocompatibility studies show the potentiality of these core/shell nanostructures for bio-applications.

  7. Synthesis, magnetic and optical properties of core/shell Co1-x Zn x Fe2O4/SiO2 nanoparticles

    Directory of Open Access Journals (Sweden)

    Wahsh Mohamed

    2011-01-01

    Full Text Available Abstract The optical properties of multi-functionalized cobalt ferrite (CoFe2O4, cobalt zinc ferrite (Co0.5Zn0.5Fe2O4, and zinc ferrite (ZnFe2O4 nanoparticles have been enhanced by coating them with silica shell using a modified Stöber method. The ferrites nanoparticles were prepared by a modified citrate gel technique. These core/shell ferrites nanoparticles have been fired at temperatures: 400°C, 600°C and 800°C, respectively, for 2 h. The composition, phase, and morphology of the prepared core/shell ferrites nanoparticles were determined by X-ray diffraction and transmission electron microscopy, respectively. The diffuse reflectance and magnetic properties of the core/shell ferrites nanoparticles at room temperature were investigated using UV/VIS double-beam spectrophotometer and vibrating sample magnetometer, respectively. It was found that, by increasing the firing temperature from 400°C to 800°C, the average crystallite size of the core/shell ferrites nanoparticles increases. The cobalt ferrite nanoparticles fired at temperature 800°C; show the highest saturation magnetization while the zinc ferrite nanoparticles coated with silica shell shows the highest diffuse reflectance. On the other hand, core/shell zinc ferrite/silica nanoparticles fired at 400°C show a ferromagnetic behavior and high diffuse reflectance when compared with all the uncoated or coated ferrites nanoparticles. These characteristics of core/shell zinc ferrite/silica nanostructures make them promising candidates for magneto-optical nanodevice applications.

  8. Synthesis, magnetic and optical properties of core/shell Co1-xZnxFe2O4/SiO2 nanoparticles

    Science.gov (United States)

    2011-01-01

    The optical properties of multi-functionalized cobalt ferrite (CoFe2O4), cobalt zinc ferrite (Co0.5Zn0.5Fe2O4), and zinc ferrite (ZnFe2O4) nanoparticles have been enhanced by coating them with silica shell using a modified Stöber method. The ferrites nanoparticles were prepared by a modified citrate gel technique. These core/shell ferrites nanoparticles have been fired at temperatures: 400°C, 600°C and 800°C, respectively, for 2 h. The composition, phase, and morphology of the prepared core/shell ferrites nanoparticles were determined by X-ray diffraction and transmission electron microscopy, respectively. The diffuse reflectance and magnetic properties of the core/shell ferrites nanoparticles at room temperature were investigated using UV/VIS double-beam spectrophotometer and vibrating sample magnetometer, respectively. It was found that, by increasing the firing temperature from 400°C to 800°C, the average crystallite size of the core/shell ferrites nanoparticles increases. The cobalt ferrite nanoparticles fired at temperature 800°C; show the highest saturation magnetization while the zinc ferrite nanoparticles coated with silica shell shows the highest diffuse reflectance. On the other hand, core/shell zinc ferrite/silica nanoparticles fired at 400°C show a ferromagnetic behavior and high diffuse reflectance when compared with all the uncoated or coated ferrites nanoparticles. These characteristics of core/shell zinc ferrite/silica nanostructures make them promising candidates for magneto-optical nanodevice applications. PMID:21774807

  9. Novel ferroferric oxide/polystyrene/silver core-shell magnetic nanocomposite microspheres as regenerable substrates for surface-enhanced Raman scattering

    Science.gov (United States)

    Liu, Bo; Bai, Chong; Zhao, Dan; Liu, Wei-Liang; Ren, Man-Man; Liu, Qin-Ze; Yang, Zhi-Zhou; Wang, Xin-Qiang; Duan, Xiu-Lan

    2016-02-01

    A novel Ag-coated Fe3O4@Polystyrene core-shell microsphere has been designed via fabrication of Fe3O4@Polystyrene core-shell magnetic microsphere through a seed emulsion polymerization, followed by deposition of Ag nanoparticles using in-situ reduction method. Such magnetic microspheres can be utilized as sensitive surface-enhanced Raman scattering (SERS) substrates, using Rhodamine 6G (R6G) as a probe molecule, with both stable and reproducible performances. The SERS detection limit of R6G decreased to 1 × 10-10 M and the enhancement factor of this substrate on the order of 106 was obtained. In addition, owing to possessing excellent magnetic properties, the resultant microspheres could be separated rapidly by an external magnetic field and utilized repeatedly for three times at least. Therefore, the unique renewable property suggests a new route to eliminate the single-use problem of traditional SERS substrates and will be promising for the practical application.

  10. Anisotropy of magnetic susceptibility used to detect coring-induced sediment disturbance and filter palaeomagnetic secular variation data: IODP sites M0061 and M0062 (Baltic Sea)

    Science.gov (United States)

    Snowball, Ian; Almqvist, Bjarne; Lougheed, Bryan; Svensson, Anna; Wiers, Steffen; Herrero-Bervera, Emilio

    2017-04-01

    Inspired by palaeomagnetic data obtained from two sites (M0061 and M0062) cored during IODP Expedition 347 - Baltic Sea Paleoenvironment we studied the Hemsön Alloformation, which is a series of brackish water muds consisting of horizontal planar and parallel laminated (varved) silty clays free from bioturbation. We determined the anisotropy of magnetic susceptibility (AMS) and characteristic remanence (ChRM) directions of a total of 1,102 discrete samples cut from (i) IODP cores recovered by an Advanced Piston corer and (ii) a series of six sediment cores recovered from the same sites by a Kullenberg piston corer. Systematic core splitting, sub-sampling methods and measurements were applied to all sub-samples. We experimentally tested for field-impressed AMS of these muds, in which titanomagnetite carries magnetic remanence and this test was negative. The AMS is likely determined by paramagnetic minerals. As expected for horizontally bedded sediments, the vast majority of the K1 (maximum) and K2 (intermediate) axes had inclinations close to 0 degrees and the AMS shape parameter (T) indicates an oblate fabric. The declinations of the K1 and K2 directions of the sub-samples taken from Kullenberg cores showed a wide distribution around the bedding plane, with no preferred alignment along any specimen axis. Exceptions are samples from the upper 1.5 m of some of these cores, in which the K1 and K2 directions were vertical, the K3 (minimum) axis shallow and T became prolate. We conclude that the Kullenberg corer, which penetrated the top sediments with a pressure of approximately 15 bar, occasionally under-sampled during penetration and vertically stretched the top sediments. Sub-samples from the upper sections of Kullenberg cores had relatively steep ChRM inclinations and we rejected samples that had a prolate, vertically oriented AMS ellipsoid. Surprisingly, the declinations of the K1 axis of all sub-samples taken from IODP APC core sections, which were not oriented

  11. Single domain SmCo5@Co exchange-coupled magnets prepared from core/shell Sm[Co(CN)6]·4H2O@GO particles: a novel chemical approach.

    Science.gov (United States)

    Yang, Ce; Jia, Lihui; Wang, Shouguo; Gao, Chen; Shi, Dawei; Hou, Yanglong; Gao, Song

    2013-12-20

    SmCo5 based magnets with smaller size and larger maximum energy product have been long desired in various fields such as renewable energy technology, electronic industry and aerospace science. However, conventional relatively rough synthetic strategies will lead to either diminished magnetic properties or irregular morphology, which hindered their wide applications. In this article, we present a facile chemical approach to prepare 200 nm single domain SmCo5@Co core/shell magnets with coercivity of 20.7 kOe and saturation magnetization of 82 emu/g. We found that the incorporation of GO sheets is responsible for the generation of the unique structure. The single domain SmCo5 core contributes to the large coercivity of the magnets and the exchange-coupled Co shell enhances the magnetization. This method can be further utilized in the synthesis other Sm-Co based exchange-coupled magnets.

  12. Interchange core/shell assembly of diluted magnetic semiconductor CeO2 and ferromagnetic ferrite Fe3O4 for microwave absorption

    Directory of Open Access Journals (Sweden)

    Jiaheng Wang

    2017-05-01

    Full Text Available Core/shell-structured CeO2/Fe3O4 and Fe3O4/CeO2 nanocapsules are prepared by interchange assembly of diluted magnetic semiconductor CeO2 and ferromagnetic ferrite Fe3O4 as the core and the shell, and vice versa, using a facile two-step polar solvothermal method in order to utilize the room-temperature ferromagnetism and abundant O-vacancies in CeO2, the large natural resonance in Fe3O4, and the O-vacancy-enhanced interfacial polarization between CeO2 and Fe3O4 for new generation microwave absorbers. Comparing to Fe3O4/CeO2 nanocapsules, the CeO2/Fe3O4 nanocapsules show an improved real permittivity of 3–10% and an enhanced dielectric resonance of 1.5 times at 15.3 GHz due to the increased O-vacancy concentration in the CeO2 cores of larger grains as well as the O-vacancy-induced enhancement in interfacial polarization between the CeO2 cores and the Fe3O4 shells, respectively. Both nanocapsules exhibit relatively high permeability in the low-frequency S and C microwave bands as a result of the bi-magnetic core/shell combination of CeO2 and Fe3O4. The CeO2/Fe3O4 nanocapsules effectively enhance permittivity and permeability in the high-frequency Ku band with interfacial polarization and natural resonance at ∼15 GHz, thereby improving absorption with a large reflection loss of -28.9 dB at 15.3 GHz. Experimental and theoretical comparisons with CeO2 and Fe3O4 nanoparticles are also made.

  13. Poly(D,L-lactide-co-glycolide) microcomposite containing magnetic iron core nanoparticles as a drug carrier

    Science.gov (United States)

    Naik, Sweta; Carpenter, Everett E.

    2008-04-01

    Today many potent anticancer drugs like cisplatin are available which carry a number of side effects. A promising way of reducing the side effects is to target the drug to tissue sites by coating it with biocompatible materials like Poly (dl-lactide-co-glycolide) (PLGA) polymer where controlled drug release is achieved during the biodegradation of the polymer. Also the efficacy of anticancer drugs like cisplatin increases at elevated temperatures, so if local heating can be achieved where the drug is targeted. Local heating can be achieved by introducing iron core nanoparticles in the composites along with the drug, which can be heated by the 2.4 GHz microwaves. Local heating of the nanocomposites also helps to swell the polymer shell and enhance the drug release. The magnetic nanocomposites were synthesized using iron nanoparticles, PLGA and a fluorescent dye, tris-(2,2'bipyridyl) dichlororuthenium (II) using an oil-in-emulsion technique. The emulsion contains PLGA, dye, and iron nanoparticles dissolved in the oil phase and polyvinyl alcohol (PVA) as a stabilizer. As the sample is homogenized, and dried, uniform 100 nm composites are formed where the dye and iron nanoparticles are encapsulated in a PLGA shell. Control of the thickness and loading efficiency of the nanocomposite can be controlled by varying the ratio of PLGA, iron, and dye. The amount of loading was determined using TGA confirming from 20-50% (w/w) loading. As the dye is released from the composite the fluorescence intensity decreases due to self-quenching. This self-quenching allows for the determination of the release kinetics as a function of temperature using fluorescence spectroscopy. Initial results suggest that there is a release of 5-10% of the dye from the composite at 25°C and complete release after the nanocomposite reaches 90°C. Using local microwave heating the complete release of the dye can be accomplished with three two second pulses of 2.4 GHz microwaves. This allows for the

  14. Banded transformer cores

    Science.gov (United States)

    Mclyman, C. W. T. (Inventor)

    1974-01-01

    A banded transformer core formed by positioning a pair of mated, similar core halves on a supporting pedestal. The core halves are encircled with a strap, selectively applying tension whereby a compressive force is applied to the core edge for reducing the innate air gap. A dc magnetic field is employed in supporting the core halves during initial phases of the banding operation, while an ac magnetic field subsequently is employed for detecting dimension changes occurring in the air gaps as tension is applied to the strap.

  15. Huge Inverse Magnetization Generated by Faraday Induction in Nano-Sized Au@Ni Core@Shell Nanoparticles

    Directory of Open Access Journals (Sweden)

    Chen-Chen Kuo

    2015-08-01

    Full Text Available We report on the design and observation of huge inverse magnetizations pointing in the direction opposite to the applied magnetic field, induced in nano-sized amorphous Ni shells deposited on crystalline Au nanoparticles by turning the applied magnetic field off. The magnitude of the induced inverse magnetization is very sensitive to the field reduction rate as well as to the thermal and field processes before turning the magnetic field off, and can be as high as 54% of the magnetization prior to cutting off the applied magnetic field. Memory effect of the induced inverse magnetization is clearly revealed in the relaxation measurements. The relaxation of the inverse magnetization can be described by an exponential decay profile, with a critical exponent that can be effectively tuned by the wait time right after reaching the designated temperature and before the applied magnetic field is turned off. The key to these effects is to have the induced eddy current running beneath the amorphous Ni shells through Faraday induction.

  16. Huge Inverse Magnetization Generated by Faraday Induction in Nano-Sized Au@Ni Core@Shell Nanoparticles.

    Science.gov (United States)

    Kuo, Chen-Chen; Li, Chi-Yen; Lee, Chi-Hung; Li, Hsiao-Chi; Li, Wen-Hsien

    2015-08-25

    We report on the design and observation of huge inverse magnetizations pointing in the direction opposite to the applied magnetic field, induced in nano-sized amorphous Ni shells deposited on crystalline Au nanoparticles by turning the applied magnetic field off. The magnitude of the induced inverse magnetization is very sensitive to the field reduction rate as well as to the thermal and field processes before turning the magnetic field off, and can be as high as 54% of the magnetization prior to cutting off the applied magnetic field. Memory effect of the induced inverse magnetization is clearly revealed in the relaxation measurements. The relaxation of the inverse magnetization can be described by an exponential decay profile, with a critical exponent that can be effectively tuned by the wait time right after reaching the designated temperature and before the applied magnetic field is turned off. The key to these effects is to have the induced eddy current running beneath the amorphous Ni shells through Faraday induction.

  17. Synthesis and characterization of Fe3O4/TiO2 magnetic and photocatalyst bifunctional core-shell with superparamagnetic performance

    Science.gov (United States)

    Behrad, F.; Helmi Rashid Farimani, M.; Shahtahmasebi, N.; Rezaee Roknabadi, M.; Karimipour, M.

    2015-07-01

    In this research a simple method has been presented to coat magnetic nanoparticles with TiO2. Firstly, Fe3O4 nanoparticles have been prepared using a co-precipitation method. Thereafter, in order to achieve particles with better dispersibility, the surface of Fe3O4 nanoparticles has been modified with the help of trisodium citrate as stabilizer. Afterward, Fe3O4 / TiO2 core-shell nanocomposites were synthesized by the Stöber method. The prepared samples were characterized by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy, energy dispersive X-ray spectroscopy (EDS) analysis and vibrating sample magnetometer (VSM). XRD results show the formation of two compounds of crystalline magnetite and brookite-type TiO2 . TEM images confirmed the formation of their core-shell structure. The surface modification of magnetite nanoparticles using trisodium citrate was confirmed by FTIR analysis. Magnetic studies also indicated that prepared core-shells exhibit superparamagnetic behavior at room temperature. Combining this property with the photocatalytic ability of TiO2 could result in a synthesized nanocomposite with different medical and environmental applications.

  18. Preparation of amino-functionalized Fe3O4@mSiO2 core-shell magnetic nanoparticles and their application for aqueous Fe(3+) removal.

    Science.gov (United States)

    Meng, Cheng; Zhikun, Wang; Qiang, Lv; Chunling, Li; Shuangqing, Sun; Songqing, Hu

    2018-01-05

    Fe3O4 nanoparticle with magnetic properties and nanoscale features has provoked wide research interest and great potential application. Herein, a modified Stober and template-removing method was adopted to prepare magnetic mesoporous silica nanoparticles (MSNs), comprising a Fe3O4 core and a mesoporous silica shell. The shell was functionalized by amino-groups with tunable removal efficiency for aqueous heavy metals ions. Structural and magnetic properties were characterized by XRD, SEM, FT-IR, vibrating sample magnetometer (VSM) and BET (Brunauer-Emmertt-Teller) techniques. Also, the adsorbing efficiency for heavy metal ions was measured by UV-vis spectrometry. Results revealed that the pure magnetite is cubic with a side length of 40 - 70nm, while the silica-coated magnetite is spherical with a diameter of 220-260nm. The mesoporous silica shell has an average pore size of 2.6nm and a high surface area of 675m(2)·g(-1), which lead to a large adsorption capacity for Fe(3+) (up to 20.66mg of Fe per g of adsorbent). Moreover, rapid magnetic separation and regeneration of as-prepared adsorbent were achieved conveniently. The distinctive structure and the heavy metal ions removal property of magnetic nanocomposites reflect their prospective application in water treatment. Copyright © 2017 Elsevier B.V. All rights reserved.

  19. Preparation of magnetic core-mesoporous shell microspheres with C8-modified interior pore-walls and their application in selective enrichment and analysis of mouse brain peptidome.

    Science.gov (United States)

    Liu, Shasha; Li, Yan; Deng, Chunhui; Mao, Yu; Zhang, Xiangmin; Yang, Pengyuan

    2011-12-01

    In this paper, magnetic mesoporous silica microspheres with C8-modified interior pore-walls were prepared through a facile one-pot sol-gel coating strategy, and were successfully applied for selective enrichment of endogenous peptides in mouse brain for peptidome analysis. Through the one-pot sol-gel approach with surfactant (CTAB) as a template, tetraethyl orthosilicate (TEOS) and n-ctyltriethoxysilane (C8TEOS) as the precursors, C8-modified magnetic mesoporous microspheres (C8-Fe(3)O(4)@mSiO(2)) consisting magnetic core and mesoporous silica shell with C8-groups exposed in the mesopore channels were synthesized. The obtained microspheres possess highly open mesopores of 3.4 nm, high surface area (162.5 m(2)/g), large pore volume (0.17 cm(3)/g), excellent magnetic responsivity (56.3 emu/g) and good dispersibility in aqueous solution. Based on the abundant surface silanol groups, functional C8 groups and the strong magnetic responsivity of the core-shell C8-Fe(3) O(4) @mSiO(2) microspheres, efficient and fast enrichment of peptides was achieved. Additionally, the C8-Fe(3)O(4)@mSiO(2) microspheres exhibit excellent performance in selective enrichment of endogenous peptides from complex samples that are consist of peptides, large proteins and other compounds, including human serum and mouse brain followed by automated nano-LC-ESI-MS/MS analysis. These results indicate C8-Fe(3)O(4)@mSiO(2) microspheres would be a potential candidate for endogenous peptides enrichment and biomarkers discovery in peptidome analysis.

  20. Influence of magnetoplasmonic γ-Fe2O3/Au core/shell nanoparticles on low-field nuclear magnetic resonance

    Science.gov (United States)

    Chen, Kuen-Lin; Yeh, Yao-Wei; Chen, Jian-Ming; Hong, Yu-Jie; Huang, Tsung-Lin; Deng, Zu-Yin; Wu, Chiu-Hsien; Liao, Su-Hsien; Wang, Li-Min

    2016-01-01

    Magnetoplasmonic nanoparticles, composed of a plasmonic layer and a magnetic core, have been widely shown as promising contrast agents for magnetic resonance imaging (MRI) applications. However, their application in low-field nuclear magnetic resonance (LFNMR) research remains scarce. Here we synthesised γ-Fe2O3/Au core/shell (γ-Fe2O3@Au) nanoparticles and subsequently used them in a homemade, high-Tc, superconducting quantum interference device (SQUID) LFNMR system. Remarkably, we found that both the proton spin–lattice relaxation time (T1) and proton spin–spin relaxation time (T2) were influenced by the presence of γ-Fe2O3@Au nanoparticles. Unlike the spin–spin relaxation rate (1/T2), the spin–lattice relaxation rate (1/T1) was found to be further enhanced upon exposing the γ-Fe2O3@Au nanoparticles to 532 nm light during NMR measurements. We showed that the photothermal effect of the plasmonic gold layer after absorbing light energy was responsible for the observed change in T1. This result reveals a promising method to actively control the contrast of T1 and T2 in low-field (LF) MRI applications. PMID:27752101

  1. Synthesis of Fe3O4@phenol formaldehyde resin core-shell nanospheres loaded with Au nanoparticles as magnetic FRET nanoprobes for detection of thiols in living cells.

    Science.gov (United States)

    Yang, Ping; Xu, Qi-Zhi; Jin, Sheng-Yu; Zhao, Yang; Lu, Yang; Xu, Xue-Wei; Yu, Shu-Hong

    2012-01-23

    A magnetic, sensitive, and selective fluorescence resonance energy transfer (FRET) probe for detection of thiols in living cells was designed and prepared. The FRET probe consists of an Fe(3)O(4) core, a green-luminescent phenol formaldehyde resin (PFR) shell, and Au nanoparticles (NPs) as FRET quenching agent on the surface of the PFR shell. The Fe(3)O(4) NPs were used as the core and coated with green-luminescent PFR nanoshells by a simple hydrothermal approach. Au NPs were then loaded onto the surface of the PFR shell by electric charge absorption between Fe(3)O(4)@PFR and Au NPs after modifying the Fe(3)O(4)@PFR nanocomposites with polymers to alter the charge of the PFR shell. Thus, a FRET probe can be designed on the basis of the quenching effect of Au NPs on the fluorescence of Fe(3)O(4)@PFR nanocomposites. This magnetic and sensitive FRET probe was used to detect three kinds of primary biological thiols (glutathione, homocysteine, and cysteine) in cells. Such a multifunctional fluorescent probe shows advantages of strong magnetism for sample separation, sensitive response for sample detection, and low toxicity without injury to cellular components.

  2. Fluoride adsorption from aqueous solution by magnetic core-shell Fe3O4@alginate-La particles fabricated via electro-coextrusion

    Science.gov (United States)

    Zhang, Yahui; Lin, Xiaoyan; Zhou, Quisheng; Luo, Xuegang

    2016-12-01

    The magnetic core-shell Fe3O4@Alg-La particles were fabricated successfully by a simple method of electro-coextrusion, and employed as an adsorbent for separation of fluoride from aqueous solution. Main factors affecting the removal of fluoride, including pH, adsorbent dosage, initial concentration, temperature and contact time were investigated. The adsorption isotherm and adsorption kinetics were studied to understand the adsorption process in detail. The experimental data were fitted well by the non-linear Freundlich isotherm and linear pseudo-second-order model, the maximum fluoride adsorption capacity was 45.230 mg/g at pH 4, 298.15 K. Thermodynamic parameters indicated that the fluoride adsorption process was feasible and spontaneous. The presence of other anions like Cl-, SO42-, HCO3- and PO43- had almost no effect on the fluoride adsorption. The adsorbent can be easily separated from the solution by a magnet. The magnetic core-shell Fe3O4@Alg-La particles before and after fluoride adsorption were studied by SEM, FTIR, EDX and XPS, which indicated that the adsorption mechanism may be related to electrostatic attraction and Lewis acid-base interaction.

  3. Preparation and properties of magnetic alumina microspheres with a γ-Fe2O3/SiO2 core and Al2O3 shell

    Institute of Scientific and Technical Information of China (English)

    Qingtao Fu; Tingting He; Lianqing Yu; Yongming Chai; Chenguang Liu

    2011-01-01

    Magnetic alumina composite microspheres with γ-Fe2O3 core/Al2O3 shell structure were prepared by the oil column method.A dense silica layer was deposited on the surface of γ-Fe2O3 particles(denoted as γ-Fe2O3/SiO2)with a desired thickness to protect the iron oxide core against acidic or high temperature conditions.γ-Fe2O3/SiO2/Al2O3 particles with about 85 wt% Al2O3 were obtained and showed to be suitable for practical applications as a magnetic catalyst or catalyst support due to their magnetic properties and pore structure.The products were characterized with scanning electron microscope(SEM)and transmission electron microscope(TEM),nitrogen adsorption-desorption,and vibrating sample magnetometer(VSM).The specific surface area and pore volume of the γ-Fe2O3/SiO2/Al2O3 composite microspheres calcined at 500 ℃ were 200 m2/g and 0.77 cm3/g,respectively.

  4. Multi-responsive hybrid particles: thermo-, pH-, photo-, and magneto-responsive magnetic hydrogel cores with gold nanorod optical triggers

    Science.gov (United States)

    Rittikulsittichai, Supparesk; Kolhatkar, Arati G.; Sarangi, Subhasis; Vorontsova, Maria A.; Vekilov, Peter G.; Brazdeikis, Audrius; Randall Lee, T.

    2016-06-01

    MNP cores, silica coating procedure, and magnetic characterization (3 pages). See DOI: 10.1039/c5nr09235c

  5. Non-destructive Analysis of Oil-Contaminated Soil Core Samples by X-ray Computed Tomography and Low-Field Nuclear Magnetic Resonance Relaxometry: a Case Study

    Science.gov (United States)

    Mitsuhata, Yuji; Nishiwaki, Junko; Kawabe, Yoshishige; Utsuzawa, Shin; Jinguuji, Motoharu

    2010-01-01

    Non-destructive measurements of contaminated soil core samples are desirable prior to destructive measurements because they allow obtaining gross information from the core samples without touching harmful chemical species. Medical X-ray computed tomography (CT) and time-domain low-field nuclear magnetic resonance (NMR) relaxometry were applied to non-destructive measurements of sandy soil core samples from a real site contaminated with heavy oil. The medical CT visualized the spatial distribution of the bulk density averaged over the voxel of 0.31 × 0.31 × 2 mm3. The obtained CT images clearly showed an increase in the bulk density with increasing depth. Coupled analysis with in situ time-domain reflectometry logging suggests that this increase is derived from an increase in the water volume fraction of soils with depth (i.e., unsaturated to saturated transition). This was confirmed by supplementary analysis using high-resolution micro-focus X-ray CT at a resolution of ∼10 μm, which directly imaged the increase in pore water with depth. NMR transverse relaxation waveforms of protons were acquired non-destructively at 2.7 MHz by the Carr–Purcell–Meiboom–Gill (CPMG) pulse sequence. The nature of viscous petroleum molecules having short transverse relaxation times (T2) compared to water molecules enabled us to distinguish the water-saturated portion from the oil-contaminated portion in the core sample using an M0–T2 plot, where M0 is the initial amplitude of the CPMG signal. The present study demonstrates that non-destructive core measurements by medical X-ray CT and low-field NMR provide information on the groundwater saturation level and oil-contaminated intervals, which is useful for constructing an adequate plan for subsequent destructive laboratory measurements of cores. PMID:21258437

  6. Structural and magnetic properties of CoFe{sub 2}O{sub 4}/NiFe{sub 2}O{sub 4} core/shell nanocomposite prepared by the hydrothermal method

    Energy Technology Data Exchange (ETDEWEB)

    Sattar, A.A. [Department of Physics, Faculty of Science, Ain Shams University, 11566 Abbasia, Cairo (Egypt); EL-Sayed, H.M., E-mail: h_m_elsaid@hotmail.com [Department of Physics, Faculty of Science, Ain Shams University, 11566 Abbasia, Cairo (Egypt); ALsuqia, Ibrahim [Department of Physics, Faculty of Education and Applied Science, Hajjah University, Alshahli, Hajjah (Yemen)

    2015-12-01

    CoFe{sub 2}O{sub 4}/NiFe{sub 2}O{sub 4} core/shell magnetic nanocomposite was synthesized by using hydrothermal method.The analysis of XRD indicated the coexistence of CoFe{sub 2}O{sub 4}, NiFe{sub 2}O{sub 4}as core/shell composite. The core/shell structure of the composite sample has been confirmed by HR-TEM images, EDX and FT-IR measurements. The size of obtained core/shell nanoparticles was 17 nm in core diameter and about 3 nm in shell thickness. The magnetization measurements showed that both the coercive field and the saturation magnetization of the resulting core/shell nanocomposite were slightly decreased compared to those of the CoFe{sub 2}O{sub 4} core but the thermal stability is of the magnetization parameter was enhanced. Furthermore, superparamagnetic phase is established at temperatures higher than the room temperature. The results were discussed in terms of the surface pinning and the magnetic interaction at the interface between the core and shell. - Highlights: • CoFe{sub 2}O{sub 4}/NiFe{sub 2}O{sub 4} core/shell could be prepared by hydrothermal method. • The structural analysis proved the formation of NiFe{sub 2}O{sub 4} shell with thickness 3 nm. • The thermal stability of M{sub s} and H{sub c} is enhanced due to the presence of NiFe{sub 2}O{sub 4} as a shell. • Super paramagnetic transition is confirmed and the effective magnetic anisotropy was calculated.

  7. 高磁通密度铁粉芯的研发进展%Recent developments in iron powder cores with high magnetic flux density

    Institute of Scientific and Technical Information of China (English)

    韩志全

    2011-01-01

    综合评述了国外高磁通密度铁粉芯的性能,介绍了几种材料的制备技术,包括MgO绝缘膜及其铁粉芯的制备,耐高温树脂绝缘膜包覆铁粉芯的制备、Sr-B-P-O磷酸盐绝缘膜及其铁粉芯的制备,以及高密度成型的加热模腔润滑技术等.%The characteristics of iron powder cores with high magnetic flux density were reviewed. And their preparation technique, including the fabrication processes in the MgO insulation coating film and respective iron powder cores, in cores based on the iron powder coating by high operating temperature-resin, and in cores made by iron powder coated with phosphate glass insulator of Sr-B-P-O system, as well as high density compacting method with warm compaction-die wall lubrication, were introduced.

  8. A facile approach for the synthesis of magnetic separable Fe3O4@TiO2, core-shell nanocomposites as highly recyclable photocatalysts

    Science.gov (United States)

    Xin, Tiejun; Ma, Mingliang; Zhang, Hepeng; Gu, Junwei; Wang, Shuangjie; Liu, Mengjiao; Zhang, Qiuyu

    2014-01-01

    A facile and efficient approach for the fabrication of Fe3O4@TiO2 nanocomposites with a good core-shell structure has been demonstrated. The approach employed involved the coating of successive titania shell on Fe3O4 core using a mixed solvent method with the catalysis of ammonia followed by the crystallization of TiO2 through solvothermal method. The as-obtained core-shell structure was composed of a central Fe3O4 core with a strong response to external fields, whereas the outer titanium oxide coating was useful for the degradation of organic contaminants. The results showed that Fe3O4@TiO2 nanocomposites exhibited high degree of crystallinity, excellent magnetic properties at room temperature. Furthermore, the as-prepared Fe3O4@TiO2 nanocomposites exhibited good photocatalytic activity toward the degradation of Rhodamine B (RhB) solution, which meant that they can be used as efficient and conveniently recoverable photocatalysts. In addition, the mechanism of coating by ammonia catalysis was also investigated.

  9. Immobilized lipase on core-shell structured Fe3O4-MCM-41 nanocomposites as a magnetically recyclable biocatalyst for interesterification of soybean oil and lard.

    Science.gov (United States)

    Xie, Wenlei; Zang, Xuezhen

    2016-03-01

    A core-shell structured Fe3O4-MCM-41 nanocomposite was prepared by means of a surfactant-directed sol-gel process. Candida rugosa lipase was then bound to the magnetic core-shell material by using glutaraldehyde as a cross-linking reagent. The as-prepared Fe3O4-MCM-41 support and the immobilized lipase were characterized in detail using enzyme activity assays, TEM, XRD, FTIR, VSM and nitrogen adsorption-desorption techniques. Results showed that the magnetite nanoparticles were coated with the MCM-41 silica with the formation of core-shell structured materials, and the lipase was successfully immobilized on the core-shell structured support. The catalytic performance of the bound lipase was tested in the interesterification of lard and soybean oil. It was shown that the immobilized lipase had a better catalytic activity towards the interesterification reaction. The slip melting point of the final product was lower than that of the original blend, and the interesterification led to an obvious variation in the microstructure of the product.

  10. Facile preparation of boronic acid functionalized Fe-core/Au-shell magnetic nanoparticles for covalent immobilization of adenosine

    NARCIS (Netherlands)

    Pham, Tuan Anh; Kumar, Nanjundan Ashok; Jeong, Yeon Tae

    2010-01-01

    The synthesis of biocompatible magnetic nanoparticles is one of the important topics in nanoscience because such materials have potential biomedical applications. Herein, we report a facile approach for surface functionalization of magnetic nanoparticles (MNPs) with boronic acid and their use for th

  11. Magnetic C-C@Fe3O4 double-shelled hollow microspheres via aerosol-based Fe3O4@C-SiO2 core-shell particles.

    Science.gov (United States)

    Zhu, Yangzhi; Li, Xiangcun; He, Gaohong; Qi, Xinhong

    2015-02-18

    Magnetic C-C@Fe3O4 hollow microspheres were prepared by using aerosol-based Fe3O4@C-SiO2 core-shell particles as templates. The magnetic double-shelled microspheres efficiently worked as carriers to load Pt nanoparticles, thus making the catalyst recyclable and reusable.

  12. Measurement of rock-core capillary pressure curves using a single-speed centrifuge and one-dimensional magnetic-resonance imaging.

    Science.gov (United States)

    Chen, Quan; Balcom, Bruce J

    2005-06-01

    Capillary pressure curves are widely used in materials, soil, and environmental sciences, and especially in the petroleum industry. The traditional (Hassler-Brunner) interpretation of centrifugal capillary pressure data is based on several assumptions. These assumptions are known to lead to significant errors in the measurement of capillary pressure curves. In this work, we propose a new "single-shot" method to measure the capillary pressure curve of a long sedimentary rock core using a single-speed centrifuge experiment and magnetic-resonance imaging to directly determine the water saturation distribution along the length of the sample. Since only a single moderate centrifuge speed is employed, the effect of gravity can be ignored and the outlet boundary condition of the core plug was maintained. The capillary pressure curve obtained by the single-shot method is remarkably consistent with results determined with conventional mercury-intrusion methods. The proposed method is much faster and more precise than traditional centrifuge methods.

  13. Magnetic adsorbent of Fe3O4@SiO2 core-shell nanoparticles modified with thiol group for chloroauric ion adsorption

    Science.gov (United States)

    Roto, Roto; Yusran, Yusran; Kuncaka, Agus

    2016-07-01

    The magnetic adsorbent of Fe3O4@SiO2 core-shell nanoparticles modified with thiol group was synthesized for chloroauric ([AuCl4]-) adsorption. The Fe3O4 nanoparticles were prepared by co-precipitation method under mechanical stirring and coated with SiO2 by acid hydrolysis of Na2SiO3 under N2 purging. The coating of Fe3O4 nanoparticles with SiO2 prevents particles' agglomeration by forming Fe3O4 Fe3O4 Fe3O4@SiO2 core-shell and avoids dissolution of the Fe3O4 core in the acidic medium. The coated Fe3O4 particle was modified with a thiol group using 3-mercaptopropyltrimethoxysilane via silanization reaction. The results suggest that SiO2-coated Fe3O4 particles have a size of 10-20 nm. The FTIR and EDX data indicate that the thiol groups are successfully attached to the surface of the nanoparticles. The [AuCl4]- ion adsorption by the Fe3O4@SiO2 core-shell nanoparticles followed Langmuir isotherm model with a maximum adsorption capacity of 115 mg/g and free energy (ΔG°) of 24.8 kJ/mol. The thiourea solution can be used to desorb most of the adsorbed [AuCl4]- ion. The adsorption using magnetic compounds provides easy access to the separation for both preparation and recovery.

  14. Multifunctional Fe3O4/TaO(x) core/shell nanoparticles for simultaneous magnetic resonance imaging and X-ray computed tomography.

    Science.gov (United States)

    Lee, Nohyun; Cho, Hye Rim; Oh, Myoung Hwan; Lee, Soo Hong; Kim, Kangmin; Kim, Byung Hyo; Shin, Kwangsoo; Ahn, Tae-Young; Choi, Jin Woo; Kim, Young-Woon; Choi, Seung Hong; Hyeon, Taeghwan

    2012-06-27

    Multimodal imaging is highly desirable for accurate diagnosis because it can provide complementary information from each imaging modality. In this study, a sol-gel reaction of tantalum(V) ethoxide in a microemulsion containing Fe(3)O(4) nanoparticles (NPs) was used to synthesize multifunctional Fe(3)O(4)/TaO(x) core/shell NPs, which were biocompatible and exhibited a prolonged circulation time. When the NPs were intravenously injected, the tumor-associated vessel was observed using computed tomography (CT), and magnetic resonance imaging (MRI) revealed the high and low vascular regions of the tumor.

  15. Amino-functionalized Fe(3)O(4)@SiO(2) core-shell magnetic nanomaterial as a novel adsorbent for aqueous heavy metals removal.

    Science.gov (United States)

    Wang, Jiahong; Zheng, Shourong; Shao, Yun; Liu, Jingliang; Xu, Zhaoyi; Zhu, Dongqiang

    2010-09-01

    A novel amino-functionalized Fe(3)O(4)@SiO(2) magnetic nanomaterial with a core-shell structure was developed, aiming to remove heavy metal ions from aqueous media. The structural, surface, and magnetic characteristics of the nanosized adsorbent were investigated by elemental analysis, FTIR, N(2) adsorption-desorption, transmission electron microscopy, powder X-ray diffraction, X-ray photoelectron spectroscopy, vibrating sample magnetometry, thermogravimetric analysis, and zeta-potential measurement. The amino-functionalized Fe(3)O(4)@SiO(2) nanoadsorbent exhibited high adsorption affinity for aqueous Cu(II), Pb(II), and Cd(II) ions, resulting from complexation of the metal ions by surface amino groups. Moreover, the adsorption affinity for heavy metal ions was not much impacted by the presence of a cosolute of humic acid (10.6mg/L) or alkali/earth metal ions (Na(+), K(+), Mg(2+)) (0.025-0.30mmol/L). The metal-loaded Fe(3)O(4)@SiO(2)-NH(2) nanoparticles could be recovered readily from aqueous solution by magnetic separation and regenerated easily by acid treatment. Findings of the present work highlight the potential for using amino-functionalized Fe(3)O(4)@SiO(2) magnetic nanoparticles as an effective and recyclable adsorbent for the removal of heavy metal ions in water and wastewater treatment. Copyright 2010 Elsevier Inc. All rights reserved.

  16. Novel polyazamacrocyclic receptor decorated core-shell superparamagnetic microspheres for selective binding and magnetic enrichment of palladium: synthesis, adsorptive behavior and coordination mechanism.

    Science.gov (United States)

    Wu, Fengcheng; Ye, Gang; Yi, Rong; Sun, Taoxiang; Xu, Chao; Chen, Jing

    2016-06-21

    The development of economical and green technologies for the effective recovery of palladium has attracted worldwide attention in recent years. Magnetic separation involving the use of functional magnetic nanoparticles (MNPs) with superparamagnetic characteristics holds great promise in this respect. This study presents a novel class of core-shell structured superparamagnetic microspheres decorated with polyazamacrocyclic receptors, which show a highly-selective binding to Pd(ii) in HNO3 media. The superparamagnetic microspheres possess a high saturation magnetization (53.8 emu g(-1)) and high adsorption capacity (qmax≈ 105.3 μmol g(-1)), affording efficient enrichment and fast separation (within 13 seconds) of palladium under an applied magnetic field. Adsorptive behavior was fully investigated combined with the corresponding theoretical analysis by using kinetic equations and Langmuir/Freundlich isotherm models. Moreover, the coordination mechanism of the polyazamacrocyclic receptors to Pd(ii) was carefully examined based on high resolution X-ray photoelectron spectroscopy (XPS) and FT-IR spectrophotometry. A suggested mechanism involving the synergistic effect of the cyclic amines and carboxyl arms of the polyazamacrocyclic receptors was proposed to describe the coordination manner, while explaining the selectivity to Pd(ii) in HNO3 solutions. From a practical perspective, the Pd(ii)-enriched microspheres could be readily regenerated for cycle use. We conclude that this kind of polyazamacrocyclic receptor decorated superparamagnetic microsphere is of potential use for the effective recovery of Pd(ii) as well as other precious metals.

  17. Metal-organic framework UiO-66 modified magnetite@silica core-shell magnetic microspheres for magnetic solid-phase extraction of domoic acid from shellfish samples.

    Science.gov (United States)

    Zhang, Wenmin; Yan, Zhiming; Gao, Jia; Tong, Ping; Liu, Wei; Zhang, Lan

    2015-06-26

    Fe3O4@SiO2@UiO-66 core-shell magnetic microspheres were synthesized and characterized by transmission electron microscopy, scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectrometry, vibrating sample magnetometry, nitrogen adsorption porosimetry and zeta potential analyzer. The synthesized Fe3O4@SiO2@UiO-66 microspheres were first used for magnetic solid-phase extraction (MSPE) of domoic acid (DA) in shellfish samples. Combined with high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS), a fast, simple and sensitive method for the determination of DA was established successfully. Under the optimized conditions, the developed method showed short analysis time, good linearity (r(2) = 0.9990), low limit of detection (1.45 pg mL(-1); S/N = 3:1), low limit of quantification (4.82 pg mL(-1); S/N = 10:1), and good extraction repeatability (RSD ≤ 5.0%; n = 5). Real shellfish samples were processed using the developed method, and trace level of DA was detected. The results demonstrate that Fe3O4@SiO2@UiO-66 core-shell magnetic microspheres are the promising sorbents for rapid and efficient extraction of polar analytes from complex biological samples.

  18. Lo cal energy of magnetic vortex core reversal%磁涡旋极性翻转的局域能量∗

    Institute of Scientific and Technical Information of China (English)

    吕刚; 曹学成; 张红; 秦羽丰; 王林辉; 厉桂华; 高峰; 孙丰伟

    2016-01-01

    The polarity of magnetic vortex core can be switched by current or magnetic field through a vortex-antivortex pair creation and annihilation process, in which the significant change of the exchange energy during the switching takes an important role. To further unveil the energetic origin of magnetic vortex switching, we investigate the evolution of the maximum exchange energy density of the sample by using micromagnetic finite-element simulations based on the Landau-Lifshitz-Gilbert equation including the adiabatic and the nonadiabatic spin torque terms. Our micromagnetic calculations indicate that maximum exchange energy density for the considered sample must exceed a critical value of∼3.0 × 106 J/m3 in order to achieve the magnetic vortex switching. The threshold value corresponds to the maximum exchange energy density at the time of creation of new vortex-antivortex pair. Following the nucleation of antivortex, the maximum exchange energy density increases rapidly with the antivortex approaching the original vortex. The maximum exchange energy density can become large at the time of annihilation of two vortexes. To explain well the critical value of the local maximum exchange energy density, we use the rigid vortex model (in which the spin distribution is unchangeable while vortex is displaced) to develop an analytical model. For a magnetic vortex confined in a thin ferromagnetic nanodisk, the magnetization distribution is unchanged along the thickness and can be seen as a two-dimensional model when the thickness is less than or on the order of the exchange length. The components of vortex magnetization vector in a ferromagnetic dot can be expressed by using a complex function w(ζ,ζ¯). Corresponding to the trivortex state appearing in vortex core reversal process, the local exchange energy density Wex around the vortexes cores is obtained. Simultaneously, we obtain the maximum exchange energy density: Wex≈2.3×106 J/m3. In a realistic system, the shape

  19. Shape anisotropy and exchange bias in magnetic flattened nanospindles with metallic/oxide core/shell structures.

    Science.gov (United States)

    Mendoza-Reséndez, Raquel; Luna, Carlos

    2012-09-01

    A preliminary study of the magnetic phenomenology of Fe and Fe90Co10 nanospindles with axial ratio equal to 5 is presented. These nanospindles are constituted by single-domains single-crystals coated by oxide surface layer and assembled in chains into the nanospindle. The thermal dependence of the coercive field and the saturation magnetization in the temperature range from 4 K up to room temperature indicates that the coercive field is roughly proportional to the saturation magnetization (which follows the T3/2 Bloch law) at temperatures above the blocking temperature of the oxide. This suggests that the predominant source of magnetic anisotropy in this temperature range is the shape anisotropy. However, at temperatures below the oxide blocking temperature, the magnetic coupling between the spins of the oxide and the nanocrystals is produced at the interface. This exchange coupling enhances the effective anisotropy of the nanospindles and the coercive field increases more abruptly than the saturation of magnetization as temperature decreases.

  20. Low-frequency core losses of zero-magnetostriction nanocrystalline soft-magnetic Fe-Zr-Si-B alloys

    Energy Technology Data Exchange (ETDEWEB)

    Pelletier, J.F.; Sutton, M. [McGill Univ., Montreal, Que. (Canada). Centre for the Physics of Materials; Schulz, R. [Inst. de Recherche d`Hydro-Quebec, Varennes, QC (Canada)

    1998-08-01

    The development of nanocrystalline alloys showing soft-magnetic properties, such as high saturation magnetization (B{sub s}), high permeability ({mu}), low coercivity (H{sub c}), and very small magnetostriction ({lambda}{sub s}), is the subject of an increasing interest. Materials showing both high saturation magnetization and near-zero magnetostriction are very attractive for applications in particular for microelectronics and power transformers. Recently, it has been shown that rapidly quenched Fe-Zr-B-Si and Fe-Zr-B-Al alloys with subsequent thermal annealing have many of these magnetic properties. In this paper, we present results on the microstructure and magnetic properties of Fe-Zr-Si-B metallic glasses produced using the melt-spinning technique. The best magnetic properties (B{sub s} = 1.54 T, H{sub c} = 38 A/m, and {lambda}{sub s} = 0) are obtained for annealing temperatures in the range between 550 C, where a nanocrystalline bcc-Fe phase is first formed, and 700 C, which is near the onset of crystallization of the remaining amorphous phase. (orig.) 15 refs.

  1. Iron/iron oxide core/shell nanoparticles for magnetic targeting MRI and near-infrared photothermal therapy.

    Science.gov (United States)

    Zhou, Zhiguo; Sun, Yanan; Shen, Jinchao; Wei, Jie; Yu, Chao; Kong, Bin; Liu, Wei; Yang, Hong; Yang, Shiping; Wang, Wei

    2014-08-01

    The development of photothermal agents (PTAs) with good stability, low toxicity, highly targeting ability and photothermal conversion efficiency is an essential pre-requisite to near-infrared photothermal therapy (PTT) in vivo. Herein, we report the readily available PEGylated Fe@Fe3O4 NPs, which possess triple functional properties in one entity - targeting, PTT, and imaging. Compared to Au nanorods, they exhibit comparable photothermal conversion efficiency (∼20%), and much higher photothermal stability. They also show a high magnetization value and transverse relaxivity (∼156 mm(-1) s(-1)), which should be applied for magnetic targeting MRI. With the Nd-Fe-B magnet (0.5 T) beside the tumour for 12 h on the xenograft HeLa tumour model, PEGylated Fe@Fe3O4 NPs exhibit an obvious accumulation. In tumour, the intensity of MRI signal is ∼ three folds and the increased temperature is ∼ two times than those without magnetic targeting, indicating the good magnetic targeting ability. Notably, the intrinsic high photothermal conversion efficiency and selective magnetic targeting effect of the NPs in tumour play synergistically in highly efficient ablation of cancer cells in vitro and in vivo.

  2. A novel europium-sensitive fluorescent nano-chemosensor based on new functionalized magnetic core-shell Fe3O4@SiO2 nanoparticles.

    Science.gov (United States)

    Ganjali, Mohammad Reza; Hosseini, Morteza; Khobi, Mehdi; Farahani, Shima; Shaban, Masoom; Faridbod, Farnoush; Shafiee, Abbas; Norouzi, Parviz

    2013-10-15

    A novel Eu(3+)-sensitive fluorescent chemosensor is introduced. It is based on magnetic core-shell silica nanoparticle which is functionalized by Cinchonidine (CD-Fe3O4@SiO2). The nano-chemosensor was synthesized and characterized by Fourier transform infrared spectroscopy (FT-IR), thermal gravimetric analysis (TGA), transmission electron microscopy (TEM), scanning electron microscopy (SEM), UV-visible absorption and fluorescence emission. The fluorescent nano-chemosensor shows a selective interaction with Eu(3+) ion. Fluorescence studies revealed that the emission intensity of the functionalized magnetic core-shell silica nanoparticles (CD-Fe3O4@SiO2 NPs) increases significantly by addition of various concentrations of Eu(3+) ion. While in case of mono, di, and other trivalent cations, weak changes or either no changes in intensity were observed. The enhancement in fluorescence intensity of nano-chemosensor is because of the strong covalent binding of Eu(3+) ion to CD-Fe3O4@SiO2 NPs with a large binding constant value of 1.7 × 10(5) mol L(-1).

  3. Magnetically separable core-shell structural γ-Fe2O3@Cu/Al-MCM-41 nanocomposite and its performance in heterogeneous Fenton catalysis.

    Science.gov (United States)

    Ling, Yuhan; Long, Mingce; Hu, Peidong; Chen, Ya; Huang, Juwei

    2014-01-15

    To target the low catalytic activity and the inconvenient separation of copper loading nanocatalysts in heterogeneous Fenton-like reaction, a core-shell structural magnetically separable catalyst, with γ-Fe2O3 nanoparticles as the core layer and the copper and aluminum containing MCM-41 as the shell layer, has been fabricated. The role of aluminum has been discussed by comparing the copper containing mesoporous silica with various Cu contents. Their physiochemical properties have been characterized by XRD, UV-vis, FT-IR, TEM, nitrogen physisorption and magnetite susceptibility measurements. Double content Cu incorporation results in an improved catalytic activity for phenol degradation at the given condition (40°C, initial pH=4), but leads to a declined BET surface area and less ordered mesophase structure. Aluminum incorporation helps to retain the high BET surface area (785.2m(2)/g) and the regular hexagonal mesoporous structure of MCM-41, which make the catalyst possess a lower copper content and even a higher catalytic activity than that with the double copper content in the absence of aluminum. The catalysts can be facilely separated by an external magnetic field for recycle usage.

  4. The construction, characterization, Hg(II)-sensing and removal behavior of magnetic core-shell nanospheres loaded with fluorescence "Off-On" probe.

    Science.gov (United States)

    Tan, Jun; Wei, Xiaoyan; Chen, Jie; Sun, Ping; Ouyang, Yuxia; Fan, Juhong; Liu, Rui

    2014-12-10

    The present paper constructed and discussed core-shell structured nanospheres grafted with rhodamine based probe for Hg(II) sensing and removal. Electron microscopy images, XRD curves, thermogravimetric analysis and N2 adsorption/desorption isotherms were used to identify the core-shell structure. The inner core consisted of superparamagnetic Fe3O4 nanoparticles, which made the nanocomposite magnetically removable. The outer shell was constructed with silica molecular sieve which provided large surface area and ordered tunnels for the sensing probe, accelerating analyte adsorption and transportation. The rhodamine based sensing probe emission increased with the increasing Hg(II) concentration, showing emission "Off-On" effect, which could be explained by the structural transformation from a non-emissive one to a highly emissive one. The influence from various metal ions and pH values was also investigated, which suggested this structural transformation could only be triggered by Hg(II), showing high selectivity and linear response. The Hg(II) sensing nanocomposite could be regenerated after usage. The response time was slightly compromised and could be further improved.

  5. Synthesis and study of structural and magnetic properties of superparamagnetic Fe3O4@SiO2 core/shell nanocomposite for biomedical applications

    Directory of Open Access Journals (Sweden)

    Mitra Helmi Rashid Farimani

    2013-09-01

    Full Text Available   Objective(s: This paper describes coating of magnetite nanoparticles (MNPs with amorphous silica shells.   Materials and Methods: First, magnetite (Fe3O4 NPs were synthesized by co-precipitation method and then treated with stabilizer molecule of trisodium citrate to enhance their dispersibility. Afterwards, coating with silica was carried out via a sol-gel approach in which the electrostatically stabilized MNPs were used as seeds. The samples were characterized by means of X-ray diffraction (XRD, transmission electron microscopy (TEM, Fourier transform infrared (FT-IR spectroscopy and vibrating sample magnetometer (VSM. Results: The results of XRD analysis implied that the prepared nanocomposite consists of two compounds of crystalline magnetite and amorphous silica that formation of their core/shell structure with the shell thickness of about 5 nm was confirmed by TEM images. The magnetic studies also indicated that produced Fe3O4@SiO2 core/shell nanocomposite exhibits superparamagnetic properties at room temperature. Conclusion: These core/shell structure due to having superparamagnetic property of Fe3O4 and unique properties of SiO2, offers a high potential for many biomedical applications.

  6. Controllable synthesis, magnetic properties, and enhanced photocatalytic activity of spindlelike mesoporous α-Fe(2)O(3)/ZnO core-shell heterostructures.

    Science.gov (United States)

    Wu, Wei; Zhang, Shaofeng; Xiao, Xiangheng; Zhou, Juan; Ren, Feng; Sun, Lingling; Jiang, Changzhong

    2012-07-25

    Mesoporous spindlelike iron oxide/ZnO core-shell heterostructures are successfully fabricated by a low-cost, surfactant-free, and environmentally friendly seed-mediate strategy with the help of postannealing treatment. The material composition and stoichiometry, as well as these magnetic and optical properties, have been examined and verified by means of high-resolution transmission electron microscopy and X-ray diffraction, the thickness of ZnO layer can be simply tailored by the concentration of zinc precursor. Considering that both α-Fe2O3 and ZnO are good photocatalytic materials, we have investigated the photodegradation performances of the core-shell heterostructures using organic dyes Rhodamin B (RhB). It is interesting to find that the as-obtained iron oxides/ZnO core-shell heterostructures exhibited enhanced visible light or UV photocatalytic abilities, remarkably superior to the as-used α-Fe2O3 seeds and commercial TiO2 products (P25), mainly owing to the synergistic effect between the narrow and wide bandgap semiconductors and effective electron-hole separation at the interfaces of iron oxides/ZnO.

  7. In vitro toxicity of FemOn, FemOn-SiO2 composite, and SiO2-FemOn core-shell magnetic nanoparticles.

    Science.gov (United States)

    Toropova, Yana G; Golovkin, Alexey S; Malashicheva, Anna B; Korolev, Dmitry V; Gorshkov, Andrey N; Gareev, Kamil G; Afonin, Michael V; Galagudza, Michael M

    2017-01-01

    Over the last decade, magnetic iron oxide nanoparticles (IONPs) have drawn much attention for their potential biomedical applications. However, serious in vitro and in vivo safety concerns continue to exist. In this study, the effects of uncoated, FemOn-SiO2 composite flake-like, and SiO2-FemOn core-shell IONPs on cell viability, function, and morphology were tested 48 h postincubation in human umbilical vein endothelial cell culture. Cell viability and apoptosis/necrosis rate were determined using 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide assay and annexin V-phycoerythrin kit, respectively. Cell morphology was evaluated using bright-field microscopy and forward and lateral light scattering profiles obtained with flow cytometry analysis. All tested IONP types were used at three different doses, that is, 0.7, 7.0, and 70.0 μg. Dose-dependent changes in cell morphology, viability, and apoptosis rate were shown. At higher doses, all types of IONPs caused formation of binucleated cells suggesting impaired cytokinesis. FemOn-SiO2 composite flake-like and SiO2-FemOn core-shell IONPs were characterized by similar profile of cytotoxicity, whereas bare IONPs were shown to be less toxic. The presence of either silica core or silica nanoflakes in composite IONPs can promote cytotoxic effects.

  8. In vitro toxicity of FemOn, FemOn-SiO2 composite, and SiO2-FemOn core-shell magnetic nanoparticles

    Science.gov (United States)

    Toropova, Yana G; Golovkin, Alexey S; Malashicheva, Anna B; Korolev, Dmitry V; Gorshkov, Andrey N; Gareev, Kamil G; Afonin, Michael V; Galagudza, Michael M

    2017-01-01

    Over the last decade, magnetic iron oxide nanoparticles (IONPs) have drawn much attention for their potential biomedical applications. However, serious in vitro and in vivo safety concerns continue to exist. In this study, the effects of uncoated, FemOn-SiO2 composite flake-like, and SiO2-FemOn core-shell IONPs on cell viability, function, and morphology were tested 48 h postincubation in human umbilical vein endothelial cell culture. Cell viability and apoptosis/necrosis rate were determined using 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide assay and annexin V-phycoerythrin kit, respectively. Cell morphology was evaluated using bright-field microscopy and forward and lateral light scattering profiles obtained with flow cytometry analysis. All tested IONP types were used at three different doses, that is, 0.7, 7.0, and 70.0 μg. Dose-dependent changes in cell morphology, viability, and apoptosis rate were shown. At higher doses, all types of IONPs caused formation of binucleated cells suggesting impaired cytokinesis. FemOn-SiO2 composite flake-like and SiO2-FemOn core-shell IONPs were characterized by similar profile of cytotoxicity, whereas bare IONPs were shown to be less toxic. The presence of either silica core or silica nanoflakes in composite IONPs can promote cytotoxic effects. PMID:28144141

  9. Synthesis of magnetic core-shell structure Fe3O4@MCM-41 nanoparticle by vesicles in aqueous solutions☆

    Institute of Scientific and Technical Information of China (English)

    Weiming Song; Xuesong Liu; Ying Yang; Xuejia Han; Qigang Deng

    2015-01-01

    In this study, magnetic core–shel structure Fe3O4@MCM-41 nanoparticles were synthesized with vesicles as soft templates. In the preparation, FeCl2 and tetraethy orthosilicate (TEOS) were selected as Fe processor and Si pre-cursor, respectively. Stable vesicles first formed in 0.03 mol·L−1 1:2 mixture of anionic surfactant sodium dode-cyl sulfate and cationic surfactant cetyltrimethyl ammonium bromide. Then, TEOS was added in the vesicle aqueous solution, leading to a highly dispersed solution. After high-temperature calcination, Fe3O4@MCM-41 nanoparticles were obtained. Their structure and morphology were characterized by Saturn Digisizer, transmis-sion electron microscope and vibrating sample magneto-meter. The results indicate that the vesicles are spherical and their size could be tuned between 20 and 50 nm. The average grain diameter of synthesize magnetic core–shel Fe3O4@MCM-41 particles is 100–150 nm and most of them are in el iptical shape. The dispersion of magnet-ic particles is very good and magnetization values are up to 33.44 emu·g−1, which are superior to that of other Fe3O4 materials reported.

  10. Influence of Vector Magnetic Property with Rotational Magnetic Flux, Magnetic Hysteresis and Angle Difference on Stator Core Loss(The 20th MAGDA Conference in Pacific Asia (MAGDA2011))

    OpenAIRE

    Keisuke, FUJISAKI; Shouji, SATOH; Masato, ENOKIZONO; Nippon Steel Corporation:Toyota Technological Institute; N-Tec Oita; Oita University

    2012-01-01

    The influence of rotating magnetic flux and magnetic anisotropic characteristics on the iron loss in the electrical motor is observed by means of the numerical calculation as the φ-anisotropy method and the two-dimensional vector magnetic property method. High grade non-oriented steel (35A210) is used and is applied to the electrical motor with permanent magnet buried and 4 poles, 24 slots. The calculation data show that the magnetic anisotropic characteristics make the iron loss 8 % increase...

  11. Steel Tape-wound Cut Cores as Magnet Yokes for the Beam Dump Kickers of the Large Hadron Collider

    CERN Document Server

    Mayer, M; Jansson, U; Fox, D

    2004-01-01

    Fast pulsed magnets, also called kickers, are used in particle accelerators for beam injection, extraction and similar applications. To excite these magnets, typically current pulses with rise and fall times in the range of 100 ns to 10 µs, with pulse duration of up to 100 µs and amplitudes in the order of kilo Amperes, are used. The short rise time imposes low inductance circuits and high voltage operation. The yokes are usually made out of ferrite, with reaches field saturation at about 0.5 T.

  12. Hybrid Magnetics and Power Applications

    DEFF Research Database (Denmark)

    Mo, Wai Keung; Paasch, Kasper

    A hybrid magnetic approach, merging two different magnetic core properites such as ferrite and iron powder cores, is an effective solution for power converter applications. It can offer similar magnetic properties to that of magnetic powder cores but showing less copper loss than powder cores...

  13. Preparation of a core-shell magnetic ion-imprinted polymer via a sol-gel process for selective extraction of Cu(II) from herbal medicines.

    Science.gov (United States)

    He, Huan; Xiao, Deli; He, Jia; Li, Hui; He, Hua; Dai, Hao; Peng, Jun

    2014-05-21

    A novel magnetic surface ion-imprinted polymer (c-MMWCNTs-SiO2-IIP) was synthesized for the first time using magnetic CNTs/Fe3O4 composites (c-MMWCNTs) as the core, 3-ammonium propyltriethoxysilane (APTES) as the functional monomer, tetraethylorthosilicate (TEOS) as the cross-linker and Cu(II) as the template. c-MMWCNTs-SiO2-IIP was evaluated for selective extraction of Cu(II) from herbal medicines via a magnetic solid phase extraction (M-SPE) procedure. One factor affecting the separation and preconcentration of the target heavy metal was pH. Under the optimized experimental conditions, the adsorption kinetics and adsorption capacity of c-MMWCNTs-SiO2-IIP toward Cu(II) were estimated. The results indicated that the adsorption mechanism corresponds to a pseudo-second order adsorption process, with a correlation coefficient (R(2)) of 0.985 and a maximum adsorption capacity of 42.2 mg g(-1). The relative selectivity factor (β) values of Cu(II)/Zn(II) and Cu(II)/Pb(II) were 38.5 and 34.5, respectively. c-MMWCNTs-SiO2-IIP, combined with flame atomic absorption spectrometry, was successfully applied in the extraction and detection of Cu(II) in herbal medicine, with high recoveries ranging from 95.6% to 108.4%.

  14. Magnetic core-shell iron(II,III) oxide@layered double oxide microspheres for removal of 2,5-dihydroxybenzoic acid from aqueous solutions.

    Science.gov (United States)

    Tang, Sheng; Chia, Guo Hui; Lee, Hian Kee

    2015-01-01

    Magnetic core-shell Fe3O4@layered double oxide (Fe3O4@LDO) microspheres were synthesized and utilized as adsorbent in the removal of 2,5-dihydroxybenzoic acid (2,5-DHBA) from aqueous samples. Due to the "memory effect", the microspheres showed higher adsorption capacity compared with Fe3O4@layered double hydroxide. The Fe3O4@LDO microspheres were easily recovered after the experiment via the application of a magnetic force. The effect of mass of Fe3O4@LDO, temperature and time on adsorption efficiency were investigated using batch experiments. Adsorption was in conformance with the Langmuir model, with a maximum adsorption capacity of 188.7 mg/g. Recyclability experiments indicated that adsorption efficiency did not decrease noticeably after 3 cycles of adsorption-calcination. The Fe3O4@LDO microspheres were evaluated by considering matrix-matched aqueous samples spiked with 2,5-DHBA. Under optimized conditions, 98.4% of the 2,5-DHBA analyte in the sample can be effectively removed from an aqueous solution within 4 h. The results indicate that Fe3O4@LDO microspheres have the potential to be employed as highly efficient, convenient, and low-cost magnetic adsorbents in the removal of 2,5-DHBA from water. Copyright © 2014 Elsevier Inc. All rights reserved.

  15. Design of single-winding energy-storage reactors for dc-to-dc converters using air-gapped magnetic-core structures

    Science.gov (United States)

    Ohri, A. K.; Wilson, T. G.; Owen, H. A., Jr.

    1977-01-01

    A procedure is presented for designing air-gapped energy-storage reactors for nine different dc-to-dc converters resulting from combinations of three single-winding power stages for voltage stepup, current stepup and voltage stepup/current stepup and three controllers with control laws that impose constant-frequency, constant transistor on-time and constant transistor off-time operation. The analysis, based on the energy-transfer requirement of the reactor, leads to a simple relationship for the required minimum volume of the air gap. Determination of this minimum air gap volume then permits the selection of either an air gap or a cross-sectional core area. Having picked one parameter, the minimum value of the other immediately leads to selection of the physical magnetic structure. Other analytically derived equations are used to obtain values for the required turns, the inductance, and the maximum rms winding current. The design procedure is applicable to a wide range of magnetic material characteristics and physical configurations for the air-gapped magnetic structure.

  16. Synthesis, photophysical analysis, and in vitro cytotoxicity assessment of the multifunctional (magnetic and luminescent) core@shell nanomaterial based on lanthanide-doped orthovanadates

    Energy Technology Data Exchange (ETDEWEB)

    Szczeszak, Agata [Adam Mickiewicz University, Department of Rare Earths, Faculty of Chemistry (Poland); Ekner-Grzyb, Anna [Adam Mickiewicz University, Department of Behavioural Ecology, Faculty of Biology (Poland); Runowski, Marcin [Adam Mickiewicz University, Department of Rare Earths, Faculty of Chemistry (Poland); Mrówczyńska, Lucyna [Adam Mickiewicz University, Department of Cell Biology, Faculty of Biology (Poland); Grzyb, Tomasz; Lis, Stefan, E-mail: blis@amu.edu.pl [Adam Mickiewicz University, Department of Rare Earths, Faculty of Chemistry (Poland)

    2015-03-15

    Rare earths orthovanadates (REVO{sub 4}) doped with luminescent lanthanide ions (Ln{sup 3+}) play an important role as promising light-emitting materials. Gadolinium orthovanadate exhibits strong absorption of ultraviolet radiation and as a matrix doped with Eu{sup 3+} ions is well known for its efficient and intense red emission, induced by energy transfer from the VO{sub 4}{sup 3−} groups to Eu{sup 3+} ions. In the presented study, Fe{sub 3}O{sub 4}@SiO{sub 2}@GdVO{sub 4}:Eu{sup 3+} 5 % nanomaterial was investigated. The core@shell structures demonstrate attractive properties, such as higher thermal stability, enhanced water solubility, increased optical response, higher luminescence, longer decay times, and magnetic properties. Silica coating may protect nanocrystals from the surrounding environment. Therefore, such silica-covered nanoparticles (NPs) are successfully utilized in biomedical research. Multifunctional magnetic nanophosphors are very interesting due to their potential biomedical applications such as magnetic resonance imaging, hyperthermic treatment, and drug delivery. Therefore, the aim of our study was to investigate photophysical, chemical, and biological properties of multifunctional REVO{sub 4} doped with Ln{sup 3+}. Moreover, the studied NPs did not affect erythrocyte sedimentation rate, cell membrane permeability, and morphology of human red blood cells.

  17. Structural and magnetic properties of nanosized iron-polyoxocarbosilane core-shell composites prepared by laser pyrolysis

    Science.gov (United States)

    Alexandrescu, R.; Morjan, I.; Dumitrache, F.; Pola, J.; Vorlicek, V.; Marysko, M.; Gavrila, L.; Scarisoreanu, M.; Voicu, I.; Sandu, I.; Fleaca, C.; Popovici, E.; Prodan, G.

    2007-03-01

    Because of their quantum-scale dimensions, nanoparticles exhibit properties different from those of the bulk. As a result of their unique properties, numerous efforts have been made to disperse nanoparticles in polymers to enhance or modify their structural and magnetic properties. A new in situ synthesis method was used to incorporate small iron nanoparticles into a polyoxocarbosilane polymer matrix. Nano-magnetic iron-based composites were obtained by a one-step procedure consisting of the IR laser co-pyrolysis of a sensitized (with ethylene) gaseous mixture containing gaseous iron pentacarbonyl and hexamethyldisiloxane in argon. The simultaneously occurring formation of iron from iron pentacarbonyl and that of organosilicon polymer from hexamethyldisiloxane yield iron nanoparticles surrounded by an organosilicon polymer shell. The particles become superficially oxidized in the atmosphere. They were characterized by Raman analysis, electron microscopy and magnetic measurements. The properties of the nanocomposite particles depend on the experimental synthesis parameters such as flow rates of precursors, total pressure and laser power. Magnetization curves, exchange bias Hex at T = 5 K and AC susceptibility were studied in the temperature range 5-400 K. It was found that the nanocomposite should be in a ferromagnetic blocked state with a minor superparamagnetic contribution of the smallest nanoparticles.

  18. Pathogen detection in complex samples by quartz crystal microbalance sensor coupled to aptamer functionalized core-shell type magnetic separation.

    Science.gov (United States)

    Ozalp, Veli C; Bayramoglu, Gulay; Erdem, Zehra; Arica, M Yakup

    2015-01-01

    A quartz crystal microbalance sensor (QCM) was developed for sensitive and specific detection of Salmonella enterica serovar typhimurium cells in food samples by integrating a magnetic bead purification system. Although many sensor formats based on bioaffinity agents have been developed for sensitive and specific detection of bacterial cells, the development of robust sensor applications for food samples remained a challenging issue. A viable strategy would be to integrate QCM to a pre-purification system. Here, we report a novel and sensitive high throughput strategy which combines an aptamer-based magnetic separation system for rapid enrichment of target pathogens and a QCM analysis for specific and real-time monitoring. As a proof-of-concept study, the integration of Salmonella binding aptamer immobilized magnetic beads to the aptamer-based QCM system was reported in order to develop a method for selective detection of Salmonella. Since our magnetic separation system can efficiently capture cells in a relatively short processing time (less than 10 min), feeding captured bacteria to a QCM flow cell system showed specific detection of Salmonella cells at 100 CFU mL(-1) from model food sample (i.e., milk). Subsequent treatment