Control of cast iron and casts manufacturing by Inmold method

Directory of Open Access Journals (Sweden)

S. Pietrowski

2009-07-01

Full Text Available In this paper the usability of cast iron spheroidizing process in mould control by ATD method as well as by ultrasonic method were presented. Structure of instrumentation needed for control form performance of cast iron spheroidizing by Inmold method was illustrated. Author, pointed out that amount of magnesium master alloy should obtain 0,8 ÷ 1,0% of mass in form at all. Such quantity of preliminary alloy assure of obtain of nodular graphite in cast iron. In consequence of this, is reduce the cast iron liquidus temperature and decrease of recalescence temperature of graphite-eutectic crystallization in compare with initial cast iron. Control of casts can be carried out by ultrasonic method. In plain cast iron, ferritic-pearlitic microstructure is obtaining. Additives of 1,5% Cu ensure pearlitic structure.

Bainite obtaining in cast iron with carbides castings

Directory of Open Access Journals (Sweden)

S. Pietrowski

2010-01-01

Full Text Available In these paper the possibility of upper and lower bainite obtaining in cast iron with carbides castings are presented. Conditions, when in cast iron with carbides castings during continuous free air cooling austenite transformation to upper bainite or its mixture with lower bainte proceeds, have been given. A mechanism of this transformation has been given, Si, Ni, Mn and Mo distribution in the eutectic cell has been tested and hardness of tested castings has been determined.

49 CFR 192.373 - Service lines: Cast iron and ductile iron.

Science.gov (United States)

2010-10-01

... 49 Transportation 3 2010-10-01 2010-10-01 false Service lines: Cast iron and ductile iron. 192.373... Regulators, and Service Lines § 192.373 Service lines: Cast iron and ductile iron. (a) Cast or ductile iron... cast iron pipe or ductile iron pipe is installed for use as a service line, the part of the service...

Colour Metallography of Cast Iron - Chapter 2: Grey Iron (Ⅱ

Directory of Open Access Journals (Sweden)

Zhou Jiyang

2009-08-01

Full Text Available Cast iron, as a traditional metal material, has advantages of low total cost, good castability and machinability, good wear resistance and low notch sensitivity, and is still facing tough challenge in quality, property and variety of types etc. Experts and engineers studying and producing iron castings all around world extremely concern this serious challenge. Over more than 30 years, a great of research work has been carried out on how to further improve its property, expand its application and combine cast iron technology with some hi-techs (for example, computer technology. Nevertheless, cast iron is a multi-element and multi-phase alloy and has complex and variety of structures and still has great development potential in structure and property. For further studying and developing cast iron, theoretical research work is important promise, and the study on solidification process and control mechanism of graphite morphology is fundamental for improving property of cast iron and developing new type of cast iron. Metallography of cast iron normally includes two sections: liquid phase transformation and solid phase transformation. The book, Colour Metallography of Cast Iron, uses colour metallography technique to study solidification structures of cast irons: graphite, carbides, austenite and eutectics; and focuses on solidification processes. With progress of modern solidification theory, the control of material solidification process becomes important measure for improving traditional materials and developing new materials. Solidification structure not only influences mechanical and physical properties of cast iron, but also affects its internal quality. The book uses a large amount of colour photos to describe the formation of solidification structures and their relations. Crystallization phenomena, which cannot be displayed with traditional metallography, are presented and more phase transformation information is obtained from these colour

Solidification of cast iron - A study on the effect of microalloy elements on cast iron

DEFF Research Database (Denmark)

Moumeni, Elham

The present thesis deals with the heat transfer and solidification of ductile and microalloyed grey cast iron. Heterogeneous nucleation of nodular graphite at inclusions in ductile iron during eutectic solidification has been investigated. A series of ductile iron samples with two different...... of the austenite, in the last region to solidify. The superfine graphite which forms in this type of irons is short (10-20µm) and stubby. The microstructure of this kind of graphite flakes in titanium alloyed cast iron is studied using electron microscopy techniques. The methods to prepare samples of cast iron...... for comprehensive transmission electron microscopy of graphite and the surrounding iron matrix have been developed and explained. Dual beam microscopes are used for sample preparation. A TEM study has been carried out on graphite flakes in grey cast iron using selected area electron diffraction (SAED). Based...

46 CFR 56.60-10 - Cast iron and malleable iron.

Science.gov (United States)

2010-10-01

... 46 Shipping 2 2010-10-01 2010-10-01 false Cast iron and malleable iron. 56.60-10 Section 56.60-10... APPURTENANCES Materials § 56.60-10 Cast iron and malleable iron. (a) The low ductility of cast iron and malleable iron should be recognized and the use of these metals where shock loading may occur should be...

Wear resistance of cast iron

Directory of Open Access Journals (Sweden)

S. Pietrowski

2008-10-01

Full Text Available In this paper investigations of abrasive and adhesive wear resistance of different cast iron grades have been presented. Examinations showed, that the most advantageous pair of materials is the cast iron – the hardened steel with low-tempered martensite. It was found, that martensitic nodular cast iron with carbides is the most resistant material.

An innovative method for nondestructive analysis of cast iron artifacts at Hopewell Furnace National Historic Site, Pennsylvania

Science.gov (United States)

Sloto, R.A.; Helmke, M.F.

2011-01-01

Iron ore containing elevated concentrations of trace metals was smelted at Hopewell Furnace during its 113 years of operation (1771-1883). For this study, we sampled iron ore, cast iron furnace products, slag, soil, groundwater, streamflow, and streambed sediment to determine the fate of trace metals released into the environment during the iron-smelting process. Standard techniques were used to sample and analyze all media except cast iron. We analyzed the trace-metal content of the cast iron using a portable X-ray fluorescence spectrometer, which provided rapid, on-site, nondestructive analyses for 23 elements. The artifacts analyzed included eight cast iron stoves, a footed pot, and a kettle in the Hopewell Furnace museum. We measured elevated concentrations of arsenic, copper, lead, and zinc in the cast iron. Lead concentrations as great as 3,150 parts per million were measured in the stoves. Cobalt was detectable but not quantifiable because of interference with iron. Our study found that arsenic, cobalt, and lead were not released to soil or slag, which could pose a significant health risk to visitors and employees. Instead, our study demonstrates these heavy metals remained with the cast iron and were removed from the site.

Influence of boron on ferrite formation in copper-added spheroidal graphite cast iron

Directory of Open Access Journals (Sweden)

Ying Zou

2014-07-01

Full Text Available This paper reviews the original work of the authors published recently, describing the influence of B on the matrix of the Cuadded spheroidal graphite cast iron. The effect of Cu has been corrected as a ferrite formation promoter in the matrix of the grey cast iron by the usage of high-purity material. Also, this paper focuses on the ferrite formation and the observation of the Cu distribution in the B-added and B-free Cu-containing spheroidal graphite cast iron. The Cu film on the spheroidal graphite can be successfully observed in the B-free sample using a special etching method. However, in the B-added sample, no Cu film could be found, while the secondary graphite was formed on the surface of the spheroidal graphite. The interaction between B and Cu is stressed as a peculiar phenomenon by the employment of a contrast experiment of B and Mn. The heat treatment could make Cu precipitate more significantly in the eutectic cells and in the matrix in the form of large Cu particles because of the limited solubility of Cu.

The anaerobic corrosion of carbon steel and cast iron in artificial groundwaters

Energy Technology Data Exchange (ETDEWEB)

Smart, N.R. [AEA Technology plc, Culham Science Centre (United Kingdom); Blackwood, D.J. [National Univ. of Singapore (Singapore); Werme, L. [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden)

2001-07-01

In Sweden, high level radioactive waste will be disposed of in a canister with a copper outer and a cast iron or carbon steel inner. If the iron insert comes into contact with anoxic geological water, anaerobic corrosion leading to the generation of hydrogen will occur. This paper presents a study of the anaerobic corrosion of carbon steel and cast iron in artificial Swedish granitic groundwaters. Electrochemical methods and gas collection techniques were used to assess the mechanisms and rates of corrosion and the associated hydrogen gas production over a range of conditions. The corrosion rate is high initially but is anodically limited by the slow formation of a duplex magnetite film. The effects of key environmental parameters such as temperature and ionic strength on the anaerobic corrosion rate are discussed.

The anaerobic corrosion of carbon steel and cast iron in artificial groundwaters

International Nuclear Information System (INIS)

Smart, N.R.; Blackwood, D.J.; Werme, L.

2001-07-01

In Sweden, high level radioactive waste will be disposed of in a canister with a copper outer and a cast iron or carbon steel inner. If the iron insert comes into contact with anoxic geological water, anaerobic corrosion leading to the generation of hydrogen will occur. This paper presents a study of the anaerobic corrosion of carbon steel and cast iron in artificial Swedish granitic groundwaters. Electrochemical methods and gas collection techniques were used to assess the mechanisms and rates of corrosion and the associated hydrogen gas production over a range of conditions. The corrosion rate is high initially but is anodically limited by the slow formation of a duplex magnetite film. The effects of key environmental parameters such as temperature and ionic strength on the anaerobic corrosion rate are discussed

Refining processes in the copper casting technology

OpenAIRE

Rzadkosz, S.; Kranc, M.; Garbacz-Klempka, A.; Kozana, J.; Piękoś, M.

2015-01-01

The paper presents the analysis of technology of copper and alloyed copper destined for power engineering casts. The casts quality was assessed based on microstructure, chemical content analysis and strength properties tests. Characteristic deoxidising (Logas, Cup) and modifying (ODM2, Kupmod2) formulas were used for the copper where high electrical conductivity was required. Chosen examples of alloyed copper with varied Cr and Zr content were studied, and the optimal heat treatment parameter...

49 CFR 192.489 - Remedial measures: Cast iron and ductile iron pipelines.

Science.gov (United States)

2010-10-01

... 49 Transportation 3 2010-10-01 2010-10-01 false Remedial measures: Cast iron and ductile iron... for Corrosion Control § 192.489 Remedial measures: Cast iron and ductile iron pipelines. (a) General graphitization. Each segment of cast iron or ductile iron pipe on which general graphitization is found to a...

Numerical Modelling of Mechanical Integrity of the Copper-Cast Iron Canister. A Literature Review

International Nuclear Information System (INIS)

Lanru Jing

2004-04-01

This review article presents a summary of the research works on the numerical modelling of the mechanical integrity of the composite copper-cast iron canisters for the final disposal of Swedish nuclear wastes, conducted by SKB and SKI since 1992. The objective of the review is to evaluate the outstanding issues existing today about the basic design concepts and premises, fundamental issues on processes, properties and parameters considered for the functions and requirements of canisters under the conditions of a deep geological repository. The focus is placed on the adequacy of numerical modelling approaches adopted in regards to the overall mechanical integrity of the canisters, especially the initial state of canisters regarding defects and the consequences of their evolution under external and internal loading mechanisms adopted in the design premises. The emphasis is the stress-strain behaviour and failure/strength, with creep and plasticity involved. Corrosion, although one of the major concerns in the field of canister safety, was not included

Seal welded cast iron nuclear waste container

International Nuclear Information System (INIS)

Filippi, A.M.; Sprecace, R.P.

1987-01-01

An article of manufacture is described comprising a cast iron container having an opening at one end and a cast iron plug; a first nickel-carbon alloy fusion weldable insert surrounding the opening and metallurgically bonded to the cast iron container at the one end of the container; a second nickel-carbon alloy insert metallurgically bonded to the cast iron plug located within the opening and surrounded by the first insert the inserts being jointed by a fusion bond in the opening without heating the cast iron container to an austenite formation temperature thereby sealing the interior of the container from the exterior ambient outside the opening; the nickel-carbon alloy containing about 2 to 5 w% carbon; and both the nickel-carbon alloy insert and the cast iron container have a microstructure containing a graphite phase

Calibration equations for energy-dispersive XRF determination of copper, iron and lead in copper ore slurries

International Nuclear Information System (INIS)

Lakosz, M.

1976-01-01

Calibration equations for the X-ray fluorescence analysis determination of copper, iron and lead in copper ore slurries have been derived and tested. The measurement of Ksub(α) lines of copper and iron and Lsub(α) line of lead excited by rays from 238 Pu source have been used. Si/Li detector coupled to multichannel analyzer and minicomputer have been applied in measurements. The matrix and density effect have been eliminated by additional measurement of back-scattered primary radiation. (author)

The structure of abrasion-resisting castings made of chromium cast iron

Directory of Open Access Journals (Sweden)

D. Kopyciński

2011-01-01

Full Text Available In this study presents the analyse of chrome iron cast structure (as-cast condition which are used in rugged conditions abrasion-percussive and high temperature. While producing the casts of chrome iron major influence has been preserve the structure of technologi cal process parameters. The addition to Fe-C-Cr alloy Ni, Mo or Cu and then proper heat treatment leads to the improvement of functional and mechanical cast qualities. Then it is possible to develop high mechanical properties which are recommended by PN-EN12513. As can it be seen from the above research silicon is an adverse chemical element in this kind of alloy cast iron. However, the reason of cracksappearing in chrome iron casts are phosphorus eutectic microareas. When the compound of Si and P reach the critical point, described inPN-88/H-83144 outdated standard, the microareas might appear.

Delamination wear mechanism in gray cast irons

International Nuclear Information System (INIS)

Salehi, M.

2000-01-01

An investigation of the friction and sliding wear of gray cast iron against chromium plated cast irons was carried out on a newly constructed reciprocating friction and wear tester. The tests were the first to be done on the test rig under dry conditions and at the speed of 170 cm/min, and variable loads of 20-260 N for a duration of 15 min. to 3 hours. The gray cast iron surfaces worn by a process of plastic deformation at the subsurface, crack nucleation, and crack growth leading to formation of plate like debris and therefore the delamination theory applies. No evidence of adhesion was observed. This could be due to formation of oxides on the wear surface which prevent adhesion. channel type chromium plating ''picked'' up cast iron from the counter-body surfaces by mechanically trapping cast iron debris on and within the cracks. The removal of the plated chromium left a pitted surface on the cast iron

Microsegregation in Nodular Cast Iron with Carbides

Directory of Open Access Journals (Sweden)

S. Pietrowski

2012-12-01

Full Text Available In this paper results of microsegregation in the newly developed nodular cast iron with carbides are presented. To investigate the pearlitic and bainitic cast iron with carbides obtained by Inmold method were chosen. The distribution of linear elements on the eutectic cell radius was examined. To investigate the microsegregation pearlitic and bainitic cast iron with carbides obtained by Inmold method were chosen.The linear distribution of elements on the eutectic cell radius was examined. Testing of the chemical composition of cast iron metal matrix components, including carbides were carried out. The change of graphitizing and anti-graphitizing element concentrations within eutectic cell was determined. It was found, that in cast iron containing Mo carbides crystallizing after austenite + graphite eutectic are Si enriched.

Microsegregation in Nodular Cast Iron with Carbides

Directory of Open Access Journals (Sweden)

Pietrowski S.

2012-12-01

Full Text Available In this paper results of microsegregation in the newly developed nodular cast iron with carbides are presented. To investigate the pearlitic and bainitic cast iron with carbides obtained by Inmold method were chosen. The distribution of linear elements on the eutectic cell radius was examined. To investigate the microsegregation pearlitic and bainitic cast iron with carbides obtained by Inmold method were chosen. The linear distribution of elements on the eutectic cell radius was examined. Testing of the chemical composition of cast iron metal matrix components, including carbides were carried out. The change of graphitizing and anti-graphitizing element concentrations within eutectic cell was determined. It was found, that in cast iron containing Mo carbides crystallizing after austenite + graphite eutectic are Si enriched.

40 CFR 464.20 - Applicability; description of the copper casting subcategory.

Science.gov (United States)

2010-07-01

... copper casting subcategory. 464.20 Section 464.20 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS METAL MOLDING AND CASTING POINT SOURCE CATEGORY Copper Casting Subcategory § 464.20 Applicability; description of the copper casting subcategory. The...

Modern Cast Irons in Chemical Engineering

Science.gov (United States)

1934-11-09

fl’ceew. T I SOCIETY OF CHEMICAL INDUSTRY CHEMICAL ENGINEERING GROUP MODERN CAST IRONS IN CHEMICAL ENGINEERING By J. G. PEARCE, M.Sc., F.Inst.P...CAST IRONS IN CHEMICAL ENGINEERING By J. G. PEARCE, M.Sc., F.Inst.P., M.I.E.E.* INTRODUCTION to chemical or thermal resistance. Small blow-holes Any...consideration of modern cast irons in chemical seldom appear to reduce the mechanical strength of engineering should strictly be prefaced by a definition

Experimental Investigation on Corrosion of Cast Iron Pipes

Directory of Open Access Journals (Sweden)

H. Mohebbi

2011-01-01

Full Text Available It is well known that corrosion is the predominant mechanism for the deterioration of cast iron pipes, leading to the reduction of pipe capacity and ultimate collapse of the pipes. In order to assess the remaining service life of corroded cast iron pipes, it is imperative to understand the mechanisms of corrosion over a long term and to develop models for pipe deterioration. Although many studies have been carried out to determine the corrosion behavior of cast iron, little research has been undertaken to understand how cast iron pipes behave over a longer time scale than hours, days, or weeks. The present paper intends to fill the gap regarding the long-term corrosion behaviour of cast iron pipes in the absence of historical data. In this paper, a comprehensive experimental program is presented in which the corrosion behaviour of three exservice pipes was thoroughly examined in three simulated service environments. It has been found in the paper that localised corrosion is the primary form of corrosion of cast iron water pipes. It has also been found that the microstructure of cast irons is a key factor that affects the corrosion behaviour of cast iron pipes. The paper concludes that long-term tests on corrosion behaviour of cast iron pipes can help develop models for corrosion-induced deterioration of the pipes for use in predicting the remaining service life of the pipes.

Inoculation Effects of Cast Iron

Directory of Open Access Journals (Sweden)

E. Fraś

2012-12-01

Full Text Available The paper presents a solidification sequence of graphite eutectic cells of A and D types, as well as globular and cementite eutectics. The morphology of eutectic cells in cast iron, the equations for their growth and the distances between the graphite precipitations in A and D eutectic types were analyzed. It is observed a critical eutectic growth rate at which one type of eutectic transformed into another. A mathematical formula was derived that combined the maximum degree of undercooling, the cooling rate of cast iron, eutectic cell count and the eutectic growth rate. One type of eutectic structure turned smoothly into the other at a particular transition rate, transformation temperature and transformational eutectic cell count. Inoculation of cast iron increased the number of eutectic cells with flake graphite and the graphite nodule count in ductile iron, while reducing the undercooling. An increase in intensity of inoculation caused a smooth transition from a cementite eutectic structure to a mixture of cementite and D type eutectic structure, then to a mixture of D and A types of eutectics up to the presence of only the A type of eutectic structure. Moreover, the mechanism of inoculation of cast iron was studied.

Colour Metallography of Cast Iron - Chapter 1: Introduction (Ⅰ

Directory of Open Access Journals (Sweden)

Zhou Jiyang

2009-02-01

Full Text Available Cast iron, as a traditional metal material, has advantages of low total cost, good castability and machinability, good wear resistance and low notch sensitivity, and is still facing tough challenge in quality, property and variety of types etc. Experts and engineers studying and producing iron castings all around world extremely concern this serious challenge. Over more than 30 years, a great of research work has been carried out on how to further improve its property, expand its application and combine cast iron technology with some hi-techs (for example, computer technology. Nevertheless, cast iron is a multi-element and multi-phase alloy and has complex and variety of structures and still has great development potential in structure and property. For further studying and developing cast iron, theoretical research work is important promise, and the study on solidification process and control mechanism of graphite morphology is fundamental for improving property of cast iron and developing new type of cast iron. Metallography of cast iron normally includes two sections: liquid phase transformation and solid phase transformation. The book, Colour Metallography of Cast Iron, uses colour metallography technique to study solidification structures of cast irons: graphite, carbides, austenite and eutectics; and focuses on solidification processes. With progress of modern solidification theory, the control of material solidification process becomes important measure for improving traditional materials and developing new materials. Solidification structure not only influences mechanical and physical properties of cast iron, but also affects its internal quality. The book uses a large amount of colour photos to describe the formation of solidification structures and their relations. Crystallization phenomena, which cannot be displayed with traditional metallography, are presented and more phase transformation information is obtained from these colour

Fiber laser cladding of nickel-based alloy on cast iron

Energy Technology Data Exchange (ETDEWEB)

Arias-González, F., E-mail: felipeag@uvigo.es [Applied Physics Dpt., University of Vigo, EEI, Lagoas-Marcosende, Vigo E-36310 (Spain); Val, J. del [Applied Physics Dpt., University of Vigo, EEI, Lagoas-Marcosende, Vigo E-36310 (Spain); Comesaña, R. [Materials Engineering, Applied Mechanics and Construction Dpt., University of Vigo, EEI, Lagoas-Marcosende, Vigo E-36310 (Spain); Penide, J.; Lusquiños, F.; Quintero, F.; Riveiro, A.; Boutinguiza, M.; Pou, J. [Applied Physics Dpt., University of Vigo, EEI, Lagoas-Marcosende, Vigo E-36310 (Spain)

2016-06-30

Highlights: • Fiber laser cladding of Ni-based alloy on cast iron was experimentally studied. • Two different types of cast iron have been analyzed: gray and ductile cast iron. • Suitable processing parameters to generate a Ni-based coating were determined. • Dilution is higher in gray cast iron samples than in ductile cast iron. • Ni-based coating presents higher hardness than cast iron but similar Young's modulus. - Abstract: Gray cast iron is a ferrous alloy characterized by a carbon-rich phase in form of lamellar graphite in an iron matrix while ductile cast iron presents a carbon-rich phase in form of spheroidal graphite. Graphite presents a higher laser beam absorption than iron matrix and its morphology has also a strong influence on thermal conductivity of the material. The laser cladding process of cast iron is complicated by its heterogeneous microstructure which generates non-homogeneous thermal fields. In this research work, a comparison between different types of cast iron substrates (with different graphite morphology) has been carried out to analyze its impact on the process results. A fiber laser was used to generate a NiCrBSi coating over flat substrates of gray cast iron (EN-GJL-250) and nodular cast iron (EN-GJS-400-15). The relationship between processing parameters (laser irradiance and scanning speed) and geometry of a single laser track was examined. Moreover, microstructure and composition were studied by Scanning Electron Microscopy (SEM), Energy Dispersive X-Ray Spectroscopy (EDS) and X-Ray Diffraction (XRD). The hardness and elastic modulus were analyzed by means of micro- and nanoindentation. A hardfacing coating was generated by fiber laser cladding. Suitable processing parameters to generate the Ni-based alloy coating were determined. For the same processing parameters, gray cast iron samples present higher dilution than cast iron samples. The elastic modulus is similar for the coating and the substrate, while the Ni

Grain Refinement of Permanent Mold Cast Copper Base Alloys

Energy Technology Data Exchange (ETDEWEB)

M.Sadayappan; J.P.Thomson; M.Elboujdaini; G.Ping Gu; M. Sahoo

2005-04-01

Grain refinement is a well established process for many cast and wrought alloys. The mechanical properties of various alloys could be enhanced by reducing the grain size. Refinement is also known to improve casting characteristics such as fluidity and hot tearing. Grain refinement of copper-base alloys is not widely used, especially in sand casting process. However, in permanent mold casting of copper alloys it is now common to use grain refinement to counteract the problem of severe hot tearing which also improves the pressure tightness of plumbing components. The mechanism of grain refinement in copper-base alloys is not well understood. The issues to be studied include the effect of minor alloy additions on the microstructure, their interaction with the grain refiner, effect of cooling rate, and loss of grain refinement (fading). In this investigation, efforts were made to explore and understand grain refinement of copper alloys, especially in permanent mold casting conditions.

Spall behavior of cast iron with varying microstructures

International Nuclear Information System (INIS)

Plume, Gifford; Rousseau, Carl-Ernst

2014-01-01

The spall strength of cast iron with varying microstructures has been investigated using plate impact at moderate speed. Stress history measurements were made with manganin stress gauges embedded between the back face of the specimen and a low impedance polycarbonate backing. Five separate cast irons were tested. Four of these consisted of gray cast iron with graphite in flake form, with three classified as Type VII A2 and the fourth containing a bimodal distribution of Types VII A4 and VII D8. The fifth casting consisted of ductile cast iron with graphite in nodular form, classified as Type I, size class 5. The spall strength for the Type VII A2 gray cast irons varied between 40 and 370 MPa, and that of the additional gray cast iron, between 410 and 490 MPa. The spall strength of the ductile cast iron fell within the range of 0.94–1.2 GPa. It is shown that the spall strength is linked to the damage level at the spall plane, where an increased level of tensile stress is required to generate higher levels of damage. Post mortem analysis was performed on the recovered samples, revealing the graphite phase to be the primary factor governing the spall fracture of cast irons, where crack nucleation is directly correlated to the debonding of graphite from the metal matrix. The average length of graphite found within a casting is linked to the material's strength, where strength increases as a function of decreasing length. The morphology and mean free path of graphite precipitates further govern the subsequent coalescence of initiated cracks to form a complete fracture plane. In cases where graphite spacing is large, increased energy level is required to complete the fracture process. A secondary factor governing the spall fracture of cast irons has also been linked to the microstructure of the metal matrix, with pearlite yielding higher spall strengths than free ferrite.

Spall behavior of cast iron with varying microstructures

Energy Technology Data Exchange (ETDEWEB)

Plume, Gifford; Rousseau, Carl-Ernst, E-mail: rousseau@uri.edu [Mechanical Engineering, University of Rhode Island, 92 Upper College Rd., Kingston, Rhode Island 02881 (United States)

2014-07-21

The spall strength of cast iron with varying microstructures has been investigated using plate impact at moderate speed. Stress history measurements were made with manganin stress gauges embedded between the back face of the specimen and a low impedance polycarbonate backing. Five separate cast irons were tested. Four of these consisted of gray cast iron with graphite in flake form, with three classified as Type VII A2 and the fourth containing a bimodal distribution of Types VII A4 and VII D8. The fifth casting consisted of ductile cast iron with graphite in nodular form, classified as Type I, size class 5. The spall strength for the Type VII A2 gray cast irons varied between 40 and 370 MPa, and that of the additional gray cast iron, between 410 and 490 MPa. The spall strength of the ductile cast iron fell within the range of 0.94–1.2 GPa. It is shown that the spall strength is linked to the damage level at the spall plane, where an increased level of tensile stress is required to generate higher levels of damage. Post mortem analysis was performed on the recovered samples, revealing the graphite phase to be the primary factor governing the spall fracture of cast irons, where crack nucleation is directly correlated to the debonding of graphite from the metal matrix. The average length of graphite found within a casting is linked to the material's strength, where strength increases as a function of decreasing length. The morphology and mean free path of graphite precipitates further govern the subsequent coalescence of initiated cracks to form a complete fracture plane. In cases where graphite spacing is large, increased energy level is required to complete the fracture process. A secondary factor governing the spall fracture of cast irons has also been linked to the microstructure of the metal matrix, with pearlite yielding higher spall strengths than free ferrite.

46 CFR 153.239 - Use of cast iron.

Science.gov (United States)

2010-10-01

... 46 Shipping 5 2010-10-01 2010-10-01 false Use of cast iron. 153.239 Section 153.239 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SHIPS CARRYING BULK... Systems § 153.239 Use of cast iron. (a) Cast iron used in a cargo containment system must meet the...

Abrasion Resistance of as-Cast High-Chromium Cast Iron

Directory of Open Access Journals (Sweden)

Pokusová Marcela

2014-12-01

Full Text Available High chromium cast irons are widely used as abrasion resistant materials. Their properties and wear resistance depend on carbides and on the nature of the matrix supporting these carbides. The paper presents test results of irons which contain (in wt.% 18-22 Cr and 2-5 C, and is alloyed by 1.7 Mo + 5 Ni + 2 Mn to improve the toughness. Tests showed as-cast irons with mostly austenitic matrix achieved hardness 36-53 HRC but their relative abrasion-resistance was higher than the tool steel STN 19436 heat treated on hardness 60 HRC.

Compacted graphite iron: Cast iron makes a comeback

Science.gov (United States)

Dawson, S.

1994-08-01

Although compacted graphite iron has been known for more than four decades, the absence of a reliable mass-production technique has resulted in relatively little effort to exploit its operational benefits. However, a proven on-line process control technology developed by SinterCast allows for series production of complex components in high-quality CGI. The improved mechanical properties of compacted graphite iron relative to conventional gray iron allow for substantial weight reduction in gasoline and diesel engines or substantial increases in horsepower, or an optimal combination of both. Concurrent with these primary benefits, CGI also provides significant emissions and fuel efficiency benefits allowing automakers to meet legislated performance standards. The operational and environmental benefits of compacted graphite iron together with its low cost and recyclability reinforce cast iron as a prime engineering material for the future.

49 CFR 192.487 - Remedial measures: Distribution lines other than cast iron or ductile iron lines.

Science.gov (United States)

2010-10-01

... cast iron or ductile iron lines. 192.487 Section 192.487 Transportation Other Regulations Relating to... iron or ductile iron lines. (a) General corrosion. Except for cast iron or ductile iron pipe, each... the purpose of this paragraph. (b) Localized corrosion pitting. Except for cast iron or ductile iron...

Cast irons

CERN Document Server

1996-01-01

Cast iron offers the design engineer a low-cost, high-strength material that can be easily melted and poured into a wide variety of useful, and sometimes complex, shapes. This latest handbook from ASM covers the entire spectrum of one of the most widely used and versatile of all engineered materials. The reader will find the basic, but vital, information on metallurgy, solidification characteristics, and properties. Extensive reviews are presented on the low-alloy gray, ductile, compacted graphite, and malleable irons. New and expanded material has been added covering high-alloy white irons used for abrasion resistance and high-alloy graphitic irons for heat and corrosion resistance. Also discussed are melting furnaces and foundry practices such as melting, inoculation, alloying, pouring, gating and rising, and molding. Heat treating practices including stress relieving, annealing, normalizing, hardening and tempering, autempering (of ductile irons), and surface-hardening treatments are covered, too. ASM Spec...

An attempt of assessing the production perspectives concerning malleable iron castings

Directory of Open Access Journals (Sweden)

M.S. Soiński

2009-07-01

Full Text Available The paper presents a historical outline of production of the malleable cast iron castings on the territory of Poland during the past over a hundred years. There have been also gathered data concerning the total quantity of castings and the quantity of malleable iron and nodular iron castings produced in twelve selected countries over the period from 1993 to 2006. The percentage of malleable iron to total production of castings, and for a purpose of comparison the percentage of nodular cast iron to total production of castings, has been determined for these countries. A distinct decreasing tendency can be seen with respect to the production of malleable iron castings, while an increasing trend exists in production of nodular iron castings.

Structure Distribution in Precise Cast Iron Moulded on Meltable Model

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Skrbek B.

2015-12-01

Full Text Available Topic of this work is to compare metalurgy of cast irons poured into sand moulds and into shell molds at IEG Jihlava company and from it following differencies in structures of thin- and thick-walled castings. This work is dealing with investigation and experimental measurement on surfaces and sections suitable thin- and thick-walled investment castings at IEG Jihlava. Cast irons with flake graphite (grey cast iron and cast irons with spheroidal graphite (ductile cast iron. Both mechanical and physical properties are determined using calculations from as measured values of wall thicknesses L and Lu, Vickers hardness and remanent magnetism. Measurement results are discussed, findings are formulated and methods for castings metallurgical quality improvement are recommended finally.

The structure of high-quality aluminium cast iron

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D. Kopyciński

2012-01-01

Full Text Available In this study presents the analyse of aluminium iron cast structure (as-cast condition which are used in high temperature. While producing the casts of aluminium iron major influence has been preserve the structure of technological process parameters. The addition to Fe-C-Al alloy V, Ti, Cr leads to the improvement of functional and mechanical cast qualities. In this study, a method was investigated to eliminate the presence of undesirable Al4C3 phases in a aluminium cast iron structure and thus improve the production process. V and Ti additions in aluminium cast iron allows to development of FeAl - VC or TiC alloys. In particular, V or Ti contents above 5 wt.% were found to totally eliminate the presence of Al4C3. In addition, preliminary work indicates that the alloy with the FeAl - VC or TiC structure reveals high oxidation resistance. The introduction of 5 wt.% chromium to aluminium cast iron strengthened Al4C3 precipitate. Thus, the resultant alloy can be considered an intermetallic FeAl matrix strengthened by VC and TiC or modified Al4C3 reinforcements.

Friction welding of ductile cast iron using interlayers

International Nuclear Information System (INIS)

Winiczenko, Radoslaw; Kaczorowski, Mieczyslaw

2012-01-01

Highlights: → The results of the study of the friction welding of ductile cast iron using interlayers are presented. → The results of the analysis shows that the joint has the tensile strength compared to that of basic material. → In case of ductile cast iron, it is possible to reach the tensile strength equals even 700 MPa. → The process of friction welding was accompanied with diffusion of Cr, Ni and C atoms across the interface. -- Abstract: In this paper, ductile cast iron-austenitic stainless steel, ductile cast iron-pure Armco iron and ductile cast iron-low carbon steel interlayers were welded, using the friction welding method. The tensile strength of the joints was determined, using a conventional tensile test machine. Moreover, the hardness across the interface of materials was measured on metallographic specimens. The fracture surface and microstructure of the joints was examined using either light stereoscope microscopy as well as electron microscopy. In this case, scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were applied. The results of the analysis shows that the joint has the tensile strength compared to that of basic material. In case of ductile cast iron, it is possible to reach the tensile strength equals even 700 MPa. It was concluded that the process of friction welding was accompanied with diffusion of Cr, Ni and C atoms across the ductile cast iron-stainless steel interface. This leads to increase in carbon concentration in stainless steel where chromium carbides were formed, the size and distribution of which was dependent on the distance from the interface.

Effect of Melting Techniques on Ductile Iron castings Properties

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Bockus, S.

2006-01-01

Full Text Available The study was designed to investigate the effects of the charge, melting conditions, nodularizing and inoculation on the ductile iron castings properties. Results showed that the temperature and holding time of the melt in an induction furnace and the intensity of spheroidizing effect on the carbon and residual magnesium contents in the ductile iron castings. The same grade of ductile iron may be obtained using different chemical compositions. The castings of ductile iron will be ferritic as-cast only when large amount of pig iron in the charge and in addition some-steps inoculating treatment are used.

Study on wear resistance of vanadium alloying compacted/vermicular graphite cast iron

International Nuclear Information System (INIS)

Park, Yoon Woo

1987-01-01

Wear resistance of the Compacted/Vermicular graphite cast irons was studied by changing the vanadium content in the cast irons. The results obtained in this work are summarized as follows. 1. When the same amount of vanadium was added to the flake graphite cast iron, spheroidal graphitecast iron and Compacted/Vermicular graphite cast iron, spheroidal graphite cast iron and Compacted/Vermicular graphite cast iron wear resistance decreased in following sequence, that is, flake graphite cast iron> spheroidal graphite cast iron>Compacted/Vermicular graphite cast iron. 2. Addition of vanadium to the Compacted/Vermicular cast iron leaded to a remarkable increase in hardness because it made the amount of pearlite in matrix increase. 3. Addition of vanadium to the compacted/Vermicular graphite cast iron significantly enhanced wear resistance and the maximum resistance was achieved at about 0.36% vanadium. 4. The maximum amount of wear apppeared at sliding speed of about 1.4m/sec and wear mode was considered to be oxidation abrasion from the observation of wear tracks. (Author)

Computer-aided control of high-quality cast iron

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S. Pietrowski

2008-04-01

Full Text Available The study discusses the possibility of control of the high-quality grey cast iron and ductile iron using the author’s genuine computer programs. The programs have been developed with the help of algorithms based on statistical relationships that are said to exist between the characteristic parameters of DTA curves and properties, like Rp0,2, Rm, A5 and HB. It has been proved that the spheroidisation and inoculation treatment of cast iron changes in an important way the characteristic parameters of DTA curves, thus enabling a control of these operations as regards their correctness and effectiveness, along with the related changes in microstructure and mechanical properties of cast iron. Moreover, some examples of statistical relationships existing between the typical properties of ductile iron and its control process were given for cases of the melts consistent and inconsistent with the adopted technology.A test stand for control of the high-quality cast iron and respective melts has been schematically depicted.

Cast iron repair method of stitching pin

International Nuclear Information System (INIS)

Yun, In Sik; Yu, Yeong Chul; Kim, Steve S.; Reed, Gary J.

2003-01-01

Many cast iron parts are welded and suffer from improper pre-heating and poor welding skills which destroy the castings due to new cracks, deformations etc. This is due mainly to the lack of understanding of the properties of cast iron. Welding, however impractical, was the only alternative for many years. Locks are used to add strength across a crack. Special drilling jigs are used to create a precise hole pattern that locks are driven into. Our locks have a unique ability to pull the sides of a crack together. Bottom locks are stacked or laminated to a depth of 80% of the casting thickness. Thicker surface locks finish off lock installation, allowing repairs in irregular shapes and contours. Installing products can be done quickly with pneumatic tools. Up to one inch of repair can be done in 5 minutes in 1/4 inch thick cast iron.

49 CFR 192.369 - Service lines: Connections to cast iron or ductile iron mains.

Science.gov (United States)

2010-10-01

... 49 Transportation 3 2010-10-01 2010-10-01 false Service lines: Connections to cast iron or ductile iron mains. 192.369 Section 192.369 Transportation Other Regulations Relating to Transportation... ductile iron mains. (a) Each service line connected to a cast iron or ductile iron main must be connected...

Evaluation of Accelerated Graphitic Corrosion Test of Gray Cast Iron

International Nuclear Information System (INIS)

Kim, Jeong Hyeon; Hong, Jong Dae; Chang Heui; Na, Kyung Hwan; Lee, Jae Gon

2011-01-01

In operating nuclear power plants, gray cast iron is commonly used as materials for various non-safety system components including pipes in fire water system, valve bodies, bonnets, and pump castings. In such locations, operating condition does not require alloy steels with excellent mechanical properties. But, a few corrosion related degradation, or graphitic corrosion is frequently occurred to gray cast iron during the long-term operation in nuclear power plant. Graphitic corrosion is selective leaching of iron from gray cast iron, where iron gets removed and graphite grains remain intact. In U.S.A., one-time visual inspection and hardness measurement are required from regulatory body to detect the graphitic corrosion for the life extension evaluation of the operating nuclear power plant. In this study, experiments were conducted to make accelerated graphitic corrosion of gray cast iron using electrochemical method, and hardness was measured for the specimens to establish the correlation between degree of graphitic corrosion and surface hardness of gray cast iron

White cast iron with a nano-eutectic microstructure and high tensile strength and considerable ductility prepared by an aluminothermic reaction casting

International Nuclear Information System (INIS)

La, Peiqing; Wei, Fuan; Hu, Sulei; Li, Cuiling; Wei, Yupeng

2013-01-01

A white cast iron with nano-eutectic microstructure was prepared by an aluminothermic reaction casting. Microstructures of the cast iron were investigated by optical microscope (OM), electron probe micro-analyzer (EPMA), scanning electron microscope (SEM) and X-ray diffraction (XRD). Mechanical properties of the cast iron were tested. The results showed that the cast iron consisted of pearlite and cementite phases. Lamellar spacing of the pearlite phase was in a range of 110–275 nm and much smaller than that of the Ni-Hard 2 cast iron. Hardness of the cast iron was 552 Hv, tensile strength was 383 MPa, total elongation was 3% and compressive strength was 2224 MPa. Tensile strength and hardness of the cast iron was same to Ni-Hard 2 cast iron, besides the ductility was much better than that of the Ni-Hard 2 cast iron which is much expensive than the cast iron.

Daily dietary intake of iron, copper, zinc and manganese in a Spanish population.

Science.gov (United States)

Rubio, Carmen; Gutiérrez, Angel José; Revert, Consuelo; Reguera, Juan Ignacio; Burgos, Antonio; Hardisson, Arturo

2009-11-01

To evaluate the daily dietary intake of essential metals in the Canary Islands, the iron, copper, zinc and manganese contents in 420 food and drink samples collected in local markets were analysed by inductively coupled plasma-atomic emission spectrometry (ICP-AES). The estimated daily dietary intakes of iron, copper, zinc and manganese are 13.161 mg/day, 2.098 mg/day, 8.954 mg/day and 2.372 mg/day, respectively. The iron dietary intake was found to be below the recommendations fixed for adult women, while the copper and manganese dietary intakes fulfilled the Recommended Dietary Allowances. The mean daily intake of zinc was below the Recommended Dietary Allowance. Cereals were found to be the food group that contributed most to the intake of these metals. While the island of El-Hierro presented iron, copper, zinc and manganese mean intakes over the estimated intakes for the whole archipelago, Fuerteventura island showed the lowest intakes. Tenerife and Fuerteventura showed the lowest iron intakes, being below the recommendations.

Examination and Elimination of Defects in Cone Casting Made of Ductile Cast Iron

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Guzik E.

2013-12-01

Full Text Available In the scope of existing cooperation with the Foundry of Cast Iron ZM “WSK Rzeszów” Ltd. there was carried out research work of microstructure and mechanical properties in the walls of a cone casting made of ductile cast iron. The particular attention was being put to the search of the potential brittle phases which have deleterious effect on ductility and dynamic properties of highly strained use of the casting prone to the potential risk of cracks during the highly strained use.

Boron solubility in Fe-Cr-B cast irons

International Nuclear Information System (INIS)

Guo Changqing; Kelly, P.M.

2003-01-01

Boron solubility in the as-cast and solution treated martensite of Fe-Cr-B cast irons, containing approximately 1.35 wt.% of boron, 12 wt.% of chromium, as well as other alloying elements, has been investigated using conventional microanalysis. The significant microstructural variations after tempering at 750 deg. C for 0.5-4 h, compared with the original as-cast and solution treated microstructures, indicated that the matrix consisted of boron and carbon supersaturated solid solutions. The boron solubility detected by electron microprobe was between 0.185-0.515 wt.% for the as-cast martensite and 0.015-0.0589 wt.% for the solution treated martensite, much higher than the accepted value of 0.005 wt.% in pure iron. These remarkable increases are thought to be associated with some metallic alloying element addition, such as chromium, vanadium and molybdenum, which have atomic diameters larger than iron, and expand the iron lattice to sufficiently allow boron atoms to occupy the interstitial sites in iron lattice

Spatial Bimetallic Castings Manufactured from Iron Alloys

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M. Cholewa

2007-07-01

Full Text Available In this paper a conception for manufacturing method of skeleton castings with composite features was shown. Main application of such castings are the working organs of machines subjected to intensive abrasive and erosive wear. Skeleton geometry was based on three-dimensional cubic net consisting of circular connectors and nodes joining 6 connectors according to Cartesian co-ordinate system. Dimension of an elementary cell was equal to 10 mm and diameter of single connector was equal to 5 mm. For bimetallic castings preparation two Fe based alloys were used: L25SHMN cast steel for skeleton substrate and ZlCr15NiMo cast iron for working part of the casting. In presented work obtained structure was analyzed with indication of characteristic regions. Authors described phenomena occurring at the alloys interface and phases in transition zone. A thesis was formulated concerning localization of transition zone at the cast iron matrix – cast steel reinforcement interface. Direction of further studies were indicated.

Effect of Cu on the microstructural and mechanical properties of as-cast ductile iron

International Nuclear Information System (INIS)

Tiwari, Siddhartha; Das, J.; Ray, K.K.; Kumar, Hemant; Bhaduri, A.

2012-01-01

The application of ductile cast iron in the heavy engineering components like, cask for the storage and transportation of radioactive materials, demands high strength with improved fracture toughness in as cast condition. The mechanical properties and fracture toughness of as-cast ductile iron (DI) is directly related to its structure property which can be controlled by proper inoculation, alloying elements and cooling rate during solidification. The aim of the present investigation is to study the effect of varying amount of Cu (0.07%, 0.11%, and 0.16%) with 1% Ni in the microstructural development of as-cast ductile iron with emphasis on its mechanical properties and fracture toughness. Three different ductile irons have been prepared using induction furnace in batches of 300 kg following industrial practice. Microstructural features (amount of phases, morphology, size and count of graphite nodules) and mechanical properties (tensile strength and hardness) of prepared DI were determined using standard methods. Dynamic fracture toughness was measured using instrumented Charpy impact test on pre-cracked specimens following the standard ISO-FDIS-26843. Additionally, fracture surfaces of broken tensile and pre-cracked specimens were observed by SEM to study the micro-mechanism of fracture. The pearlite fraction and the nodule count are found to increase with increasing amount of copper in ferritic-pearlitic matrix. The hardness and strength values are found to increase with increasing amount of pearlite whereas fracture toughness decreases. Fractographs of broken specimens exhibited decohesion of graphite, crack propagation from graphite interface and transgranular fracture of ferrite. (author)

PERSPECTIVE SOURCES OF METALS RESOURCES (CU, NI FOR CAST IRON ALLOYING, ARISING ON THE TERRITORY OF THE REPUBLIC OF BELARUS

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V. L. Tribushevski

2005-01-01

Full Text Available The article is dedicated to the practical foundation of combined resources-economy technologies of the alloyed cast iron melting using wastes of galvanic productions, containing sulfates and hydroxides of these metals, instead of metallic nickel and copper.

Analysis of nucleation modelling in ductile cast iron

DEFF Research Database (Denmark)

Moumeni, Elham; Tutum, Cem Celal; Tiedje, Niels Skat

2012-01-01

Heterogeneous nucleation of nodular graphite at inclusions in ductile iron during eutectic solidification has been investigated. The experimental part of this work deals with casting of ductile iron samples with two different inoculants in four different thicknesses. Chemical analysis, metallogra......Heterogeneous nucleation of nodular graphite at inclusions in ductile iron during eutectic solidification has been investigated. The experimental part of this work deals with casting of ductile iron samples with two different inoculants in four different thicknesses. Chemical analysis...

The nucleation of austenite in ferritic ductile cast iron

International Nuclear Information System (INIS)

Chou, J.M.; Hon, M.H.; Lee, J.L.

1992-01-01

Austempered ductile cast iron has recently been receiving increasing attention because of its excellent combination of strength and ductility. Since the austenitization process has a significant influence on the mechanical properties of austempered ductile cast iron, several investigations on the nucleation sites of austenite and diffusion paths of carbon from spheroidal graphite have been reported in ferritic ductile cast iron. However, agreement on this subject has not ben reached. The purpose of this paper is to study the preferential nucleation sites of austenite during austenitization at two austenitizing temperatures in ferritic ductile cast iron. An attempt was made to understand the reasons which give rise to preferential austenite nucleation sites. The carbon diffusion paths from spheroidal graphite were also investigated

Development of fabrication technology for copper canisters with cast inserts. Status report in August 2001

Energy Technology Data Exchange (ETDEWEB)

Andersson, Claes-Goeran

2002-04-01

This report contains an account of the results of trial fabrication of copper canisters with cast inserts carried out during the period 1998 - 2001. The work of testing of fabrication methods is being focused on a copper thickness of 50 mm. Occasional canisters with 30 mm copper thickness are being fabricated for the purpose of gaining experience and evaluating fabrication and inspection methods for such canisters. For the fabrication of copper tubes, SKB has concentrated its efforts on seamless tubes made by extrusion and pierce and draw processing. Five tubes have been extruded and two have been pierced and drawn during the period. Materials testing has shown that the resultant structure and mechanical properties of these tubes are good. Despite certain problems with dimensional accuracy, it can be concluded that both of these methods can be developed for use in the serial production of SKB' copper tubes. No new trial fabrication with roll forming of copper plate and longitudinal welding has been done. This method is nevertheless regarded as a potential alternative. Copper lids and bottoms are made by forging of continuous-cast bars. The forged blanks are machined to the desired dimensions. Due to the Canister Laboratory's need for lids to develop the technique for sealing welding, a relatively large number of forged blanks have been fabricated. It is noted in the report that the grain size obtained in lids and bottoms is much coarser than in fabricated copper tubes. Development work has been commenced for the purpose of optimizing the forging process. Nine cast inserts have been cast during the three-year period. The results of completed material testing of test pieces taken at different places along the length of the inserts have in several cases shown an unacceptable range of variation in strength properties and structure. In the continued work, insert fabrication will be developed in terms of both casting technique and iron composition. Development

Development of fabrication technology for copper canisters with cast inserts. Status report in August 2001

International Nuclear Information System (INIS)

Andersson, Claes-Goeran

2002-04-01

This report contains an account of the results of trial fabrication of copper canisters with cast inserts carried out during the period 1998 - 2001. The work of testing of fabrication methods is being focused on a copper thickness of 50 mm. Occasional canisters with 30 mm copper thickness are being fabricated for the purpose of gaining experience and evaluating fabrication and inspection methods for such canisters. For the fabrication of copper tubes, SKB has concentrated its efforts on seamless tubes made by extrusion and pierce and draw processing. Five tubes have been extruded and two have been pierced and drawn during the period. Materials testing has shown that the resultant structure and mechanical properties of these tubes are good. Despite certain problems with dimensional accuracy, it can be concluded that both of these methods can be developed for use in the serial production of SKB' copper tubes. No new trial fabrication with roll forming of copper plate and longitudinal welding has been done. This method is nevertheless regarded as a potential alternative. Copper lids and bottoms are made by forging of continuous-cast bars. The forged blanks are machined to the desired dimensions. Due to the Canister Laboratory's need for lids to develop the technique for sealing welding, a relatively large number of forged blanks have been fabricated. It is noted in the report that the grain size obtained in lids and bottoms is much coarser than in fabricated copper tubes. Development work has been commenced for the purpose of optimizing the forging process. Nine cast inserts have been cast during the three-year period. The results of completed material testing of test pieces taken at different places along the length of the inserts have in several cases shown an unacceptable range of variation in strength properties and structure. In the continued work, insert fabrication will be developed in terms of both casting technique and iron composition. Development work on

THE EFFECT OF PREPARATION CONDITIONS OF RAPIDLY SOLIDIFIED IRON BASED GRANULES ON PROPERTIES OF COMPOSITE MATERIAL FORMED BY CASTING TECHNOLOGY

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A. S. Kalinichenko

2017-01-01

Full Text Available The variety of requirements for friction pairs requires the development of different technologies for the production of tribological materials with reference to the operation modes. Composite materials obtained by the casting technology have been successfully applied for the normalization of the thermomechanical state of the steam turbines. These composites consist of the matrix based on copper alloys reinforced with cast iron granules. Because the structure and properties of cast iron are determined by the conditions of their production studies have been conducted on determination of preparation conditions on grain structure and properties of the synthesized composite material. Using an upgraded unit for production of granules technological regimes were determined providing narrow fractional composition. It has been found that granules formed are characterized with typical microstructure of white cast iron containing perlite and ledeburite. Microhardness of pilot cast iron granules is characterized by high values (from 7450 up to 9450 MPa and depends on the size of the fraction. Composite materials obtained using experimental granules had a microhardness of the reinforcing cast iron granules about 3500 MPa, and a bronze matrix – 1220 MPa, which is higher than the hardness of the composite material obtained by using the annealed DCL-1granules (2250 MPa. Metal base of experimental granules in the composite material has the structure of perlitic ductile iron with inclusions of ferrite not exceeding 10–15% and set around a flocculent graphite. As a result, the increase of physical-mechanical properties of finished products made of composite material is observed. 

Electronic and magnetic coupling of iron and copper phthalocyanine to ferromagnetic Co(100) surfaces

Energy Technology Data Exchange (ETDEWEB)

Schmidt, Felix; Sauther, Jens; Lach, Stefan; Ziegler, Christiane [Department of Physics, University of Kaiserslautern, Erwin Schroedinger Str. 56, D-67663 Kaiserslautern (Germany); Ali, Ehesan; Oppeneer, Peter [Department of Physics and Materials Science, Box 530, Uppsala University, S-75121 Uppsala (Sweden)

2009-07-01

Metallo-phthalocyanines are organic semiconductors which show in certain cases promising magnetic properties, advertising them for use in organic spintronics. Here, copper (CuPc) and iron phthalocyanine (FePc) were grown on ultra thin layers of Co(100) substrates with well known highly spin-polarized electron injection capability. Photoelectron spectroscopy (XPS) reveals different interactions between the pyrolytic nitrogen atoms and the cobalt surface for the two phthalocyanines. The analysis of the different multiplet structures appearing for the nitrogen core levels in the submonolayer regime and UPS investigations of the valence band electronic structure of the Co dominated region near the Fermi level indicates a particularly electronic coupling and a rehybridisation of the molecular orbitals with the cobalt orbitals. In order to clarify the influence of the two different central atoms on the electronic- and subsequently the magnetic coupling to the Co substrate, theoretical calculations using the GGA and GGA+U methodologies on a structure of Fe/Cu-phthalocyanine adsorbed on a 3-layered cobalt surface were performed indicating a ferromagnetic coupling between FePc and Co.

Cast iron for reactor technology - special structural and mechanical properties

International Nuclear Information System (INIS)

Janakiev, N.

The graphitic phase, its formation and the effect on the mechanical properties of cast iron used for reactor shielding are described. Tensile strength, bending strength and Brinell hardness were studied. With the specimen wall thickness of 400 mm the average measured tensile strength was 180 N/mm 2 , which satisfies the given requirements as do the values of bending strength and material hardness. As against materials 200 mm in thickness, graphite was found by metallographic tests to be of a significantly coarser structure, which may be explained by slower cooling. Tensile strength was also tested for nodular cast irons and lamellar graphite cast irons. It was shown that compression increased with decreasing specimen diameter at constant pressure, at a constant diameter compression increased nearly in proportion to compressive stress. No significant differences were found if compressive stress was 80% of fracture stress. The modulus of elasticity was found to decrease with increasing graphite content while it was found to increase with fine graphite lamellae at the same carbon concentration. It also decreased with increasing straining. A Mo-alloyed cast iron was found to show slower creep rates at a compressive stress of up to 90 N/mm 2 (calculated to the same initial strengths) than Cu-alloyed cast iron. Upon increasing compressive stress to 140 N/mm 2 and creep time to more than 2000 hours, the creep behaviour of Cu-alloyed cast iron was better. Coarser perlite is likely to be more creep resistant than fine perlite. In neutron irradiation of cast iron a clear trend towards hardening was found due to the effect of neutrons on the cast iron structure. (J.B.)

Mixed graphite cast iron for automotive exhaust component applications

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De-lin Li

2017-11-01

Full Text Available Both spheroidal graphite iron and compacted graphite iron are used in the automotive industry. A recently proposed mixed graphite iron exhibits a microstructure between the conventional spheroidal graphite iron and compacted graphite iron. Evaluation results clearly indicate the suitability and benefits of mixed graphite iron for exhaust component applications with respect to casting, machining, mechanical, thermophysical, oxidation, and thermal fatigue properties. A new ASTM standard specification (A1095 has been created for compacted, mixed, and spheroidal graphite silicon-molybdenum iron castings. This paper attempts to outline the latest progress in mixed graphite iron published.

Die casting copper motor rotors: mold materials and processing for cost-effective manufacturing

Energy Technology Data Exchange (ETDEWEB)

Peters, D.T.; Cowie, J.G.; Brush, E.F. Jr.

2000-07-01

This project seeks to demonstrate mold materials for copper pressure die-casting that are cost-effective and practical for production use in die-casting copper motor rotors. The incorporation of die-cast copper for conductor bars and end rings of the induction motor in place of aluminum would result in attractive improvements in motor energy efficiency through reductions in motor losses ranging from 15% to 20%. Die-cast motor rotors are produced in aluminum today because rotor fabrication by pressure die-casting is an established practice. Lack of a durable and cost-effective mold material has been the technical barrier preventing manufacture of the die-cast copper rotor. This project tested H-13 steel die inserts that establish the baseline. Nickel-, tungsten-, and molybdenum-based high temperature alloys were extensively tested. Results indicate that substantially extended die life is possible using high temperature die materials, pre-heated and operated at elevated temperatures. Pre-heating and high operating temperatures were shown to be critical in extending the die life by decreasing the cyclic stresses associated with thermal expansion. Extended die life provides the opportunity for economically viable copper motor rotor die-casting. (orig.)

Fatigue behaviour of synthetic nodular cast irons

Directory of Open Access Journals (Sweden)

A. Vaško

2015-01-01

Full Text Available The paper shows the influence of charge composition on microstructure, fatigue properties and failure micromechanisms of nodular cast irons. The additive of metallurgical silicon carbide (SiC in analysed specimens increases the content of ferrite in the matrix, decreases the size of graphite and increases the average count of graphitic nodules per unit of area. Consequently, the mechanical and fatigue properties of nodular cast iron are improved. The best fatigue properties (fatigue strength were reached in the melt which was created by 60 % of steel scrap and 40 % of pig iron in the basic charge with SiC additive.

Bainitic high-strength cast iron with globular graphite

Science.gov (United States)

Silman, G. I.; Makarenko, K. V.; Kamynin, V. V.; Zentsova, E. A.

2013-07-01

Special features of formation of bainitic structures in grayed cast irons are considered. The influence of the graphite phase and of the special features of chemical composition of the iron on the intermediate transformation in high-carbon alloys is allowed for. The range of application of high-strength cast irons with bainitic structure is determined. The paper is the last and unfinished work of G. I. Silman completed by his disciples as a tribute to their teacher.

Control of chilling tendency in grey cast iron reuse

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Saliu Ojo Seidu

2013-02-01

Full Text Available In grey cast iron remelt and recycling, white iron can result in the cast product if careful control of the chilling tendency is not ensured. Many jobbing foundries are constrained in furnace types and available foundry additives that the operation always results in white irons. This study is towards ensuring grey iron is reproduced from cast iron scrap auto engine blocks, when using a diesel fired rotary furnace and a FeSi alloy for structural modification (inoculation. With varying addition rate of the FeSi alloy to the tapped molten metal, chill wedge tests were performed on two different wedge samples of type W (according to ASTM A367- wedge test with cooling modulus of 0.45 cm (W3½ and 0.54 cm (W4. The carbon equivalents for the test casts were within hypoeutectic range (3.85 wt. (% to 4.11 wt. (%. In the W4 wedge sample, at 2.0 wt. (% addition rate of the FeSi alloy, the relative clear chill was totally reduced to zero from 19.76%, while the relative mottled chill was brought down to 9.59% from 33.71%. The microstructure from the cast at this level of addition was free of carbidic phases; it shows randomly oriented graphite flakes evenly distributed in the iron matrix. Hardness assessment shows that increasing rate of FeSi addition results in decreasing hardness, with maximum effect at 2.0 wt. (% addition. With equivalent aspect ratio (cooling modulus in a target cast product, this addition rate for this FeSi alloy under this furnace condition will attain graphitized microstructure in the cast product.

Control of chilling tendency in grey cast iron reuse

Directory of Open Access Journals (Sweden)

Saliu Ojo Seidu

2012-01-01

Full Text Available In grey cast iron remelt and recycling, white iron can result in the cast product if careful control of the chilling tendency is not ensured. Many jobbing foundries are constrained in furnace types and available foundry additives that the operation always results in white irons. This study is towards ensuring grey iron is reproduced from cast iron scrap auto engine blocks, when using a diesel fired rotary furnace and a FeSi alloy for structural modification (inoculation. With varying addition rate of the FeSi alloy to the tapped molten metal, chill wedge tests were performed on two different wedge samples of type W (according to ASTM A367- wedge test with cooling modulus of 0.45 cm (W3½ and 0.54 cm (W4. The carbon equivalents for the test casts were within hypoeutectic range (3.85 wt. (% to 4.11 wt. (%. In the W4 wedge sample, at 2.0 wt. (% addition rate of the FeSi alloy, the relative clear chill was totally reduced to zero from 19.76%, while the relative mottled chill was brought down to 9.59% from 33.71%. The microstructure from the cast at this level of addition was free of carbidic phases; it shows randomly oriented graphite flakes evenly distributed in the iron matrix. Hardness assessment shows that increasing rate of FeSi addition results in decreasing hardness, with maximum effect at 2.0 wt. (% addition. With equivalent aspect ratio (cooling modulus in a target cast product, this addition rate for this FeSi alloy under this furnace condition will attain graphitized microstructure in the cast product.

THE INFLUENCE OF PRE-HEAT TREATMENT ON WHITE CAST IRONS PLASTICITY

Directory of Open Access Journals (Sweden)

T. M. Myronova

2013-11-01

Full Text Available Purpose. The development of heat treatment modes of white cast irons for structure changes in their eutectic constituent, namely in disturbing the monolithic structure of ledeburite colonies cementite structure and eutectic net continuity. Also the mentioned heat treatment modes are targeted to the eutectic net shift for the most suitable position from the point of plastic deforming. Methodology. The hypoeutectic white cast irons with 2.92…3.35 % carbon content and additionally alloyed by 3.18 % vanadium have been used as the research materials. The mentioned alloys have been pre-heat treated and hot twist tested. Findings. The research results showed that the carbide net breaking by plastic deforming leads to cast irons mechanical properties increasing but has difficulties in implementation due to the white cast irons low plasticity. The influence of different pre-heat treatment modes on structure and plasticity of white hypoeutectic cast irons have been investigated. They include the isotherm soaking under the different temperatures as well as multiply soakings and thermo-cycling. The influence of eutectic level, as well as pre heat treatment modes on different composition white cast irons hot plasticity have been investigated. Originality. It was determined that the heat treatment, which leads to double α→γ recrystallization under 860 – 950 °С and reperlitization under 720-680 °С results in significant increase of plasticity, as well as in un-alloyed and alloyed by vanadium white cast irons. It takes place due to carbide matrix phase separation in ledeburite colonies by new phase boundaries forming especially due to carbide transformations under vanadium alloying. Practical value. The implementation of pre-heat treatment with phase recrystallization resulted in hypoeutectic white cast irons plasticity increasing. The obtained level of cast iron plasticity corresponds to the one of carbide class steels, which ensures the successful

The temperature gradient on section of casting in process of primary crystallization of chromium cast iron

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A. Studnicki

2008-08-01

Full Text Available The methodology of defining in article was introduced the temperature gradient in process of primary crystallization during cooling the casting from chromium cast iron on basis of measurements of thermal field in test DTA-K3. Insert also the preliminary results of investigations of influence temperature gradient on structure of studied wear resistance chromium cast iron.

In-situ surface hardening of cast iron by surface layer metallurgy

International Nuclear Information System (INIS)

Fischer, Sebastian F.; Muschna, Stefan; Bührig-Polaczek, Andreas; Bünck, Matthias

2014-01-01

Abrasive wear is a serious problem in many cast iron castings used in industry. To minimize failure and repair of these components, different strategies exist to improve their surface microhardness thus enhancing their wear resistance. However, most of these methods lead to very brittle and/or expensive castings. In the current work a new method for surface hardening is presented which utilizes surface layer metallurgy to generate in-situ a boron-enriched white cast iron surface layer with a high microhardness on a gray cast iron casting. To do this, sand molds are coated with a ferroboron suspension and cast with a cast iron melt. After solidification, a 100–900 µm thick layer of boron-enriched ledeburite is formed on the surface of the casting which produces an increase in the average microhardness from 284 HV 0.1 ±52 HV 0.1 to 505 HV 0.1 ±87 HV 0.1 . Analyses of the samples' core reveal a typical cast iron microstructure which leads to the conclusion that the coating mainly affects the castings' surface. By varying the grain size of the ferroboron powder in the coatings, it is shown that a powder size ≤100 µm is most suitable to create a boron-enriched ledeburite surface layer possessing high hardness values

Determination of low alloying element concentrations in cast iron by laser induced breakdown spectroscopy based on TEA CO2 laser system

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Savović Jelena J.

2017-01-01

Full Text Available The analytical capability of laser-produced plasma for the analysis of low alloying elements in cast iron samples has been investigated. The plasma was induced by irradiation of a sample in air at atmospheric pressure using an infrared CO2 laser. Emission spectra were recorded by time-integrated spatially- resolved measurement technique. A set of ten cast iron samples in a powder or particulate form were provided by BAM (Bundesanstalt für Material Forschung und Prüfung, Deutschland, seven of which were used for calibration, and three were treated as unknowns. Linear calibration curves were obtained for copper, chromium, and nickel, with correlation coefficients above 0.99. Precision and accuracy of the LIBS method was evaluated and compared to those obtained by the inductively coupled plasma (ICP analysis of the same samples. Detection limits for Cu, Cr and Ni were close to those reported in the literature for other comparable iron-based alloys obtained using different LIBS systems. Analytical figures of merit of the studied LIBS system may be considered as satisfying, especially in the light of other advantages of the method, like cost effective and fast analysis with no sample preparation, and with a possibility for real-time on-site analysis. [Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. 172019

Technology for producing synthetic cast iron for nuclear power station parts

International Nuclear Information System (INIS)

Blozhko, N.K.; Kurochkin, V.S.; Narkevich, E.A.; Nikitin, L.A.; Petrov, L.A.

1984-01-01

A technology was developed and implemented for producing grades SCh-30 through SCh-40 synthetic cast iron in industrial-frequency induction melting furnaces. Alternative innoculations with ferrosilicon and silicocalcium and alloying with chrome and nickel were studied. The mechanical properties and structure of cast irons produced by various technological methods were studied. The research showed that the sector's plants, equipped with industrial-frequency induction furnaces, can produce high-quality synthetic cast irons containing flake graphite for nuclear-power-station casting, without the use of expensive innoculants. Careful observance of the melting and innoculating technologies makes it possible to produce SCh 40 cast iron, without cementite inclusions, by innoculating with FS 75 ferrosilicon in the amount of 0.7% of the total melt weight. Using an innoculant mixture of 0.2% FS 75 and 0.5% SK 30 and low alloying with nickel and chromium, the cast-iron strength can be increased to 440-450 MPa, although the danger of cementite inclusions increase

Imposed Thermal Fatigue and Post-Thermal-Cycle Wear Resistance of Biomimetic Gray Cast Iron by Laser Treatment

Science.gov (United States)

Sui, Qi; Zhou, Hong; Zhang, Deping; Chen, Zhikai; Zhang, Peng

2017-08-01

The present study aims to create coupling biomimetic units on gray cast iron substrate by laser surface treatment (LST). LSTs for single-step (LST1) and two-step (LST2) processes, were carried out on gray cast iron in different media (air and water). Their effects on microstructure, thermal fatigue, and post-thermal-cycle wear (PTW) resistance on the specimens were studied. The tests were carried out to examine the influence of crack-resistance behavior as well as the biomimetic surface on its post-thermal-cycle wear behavior and different units, with different laser treatments for comparison. Results showed that LST2 enhanced the PTW behaviors of gray cast iron, which then led to an increase in its crack resistance. Among the treated cast irons, the one treated by LST2 in air showed the lowest residual stress, due to the positive effect of the lower steepness of the thermal gradient. Moreover, the same specimen showed the best PTW performance, due to its superior crack resistance and higher hardness as a result of it.

Multi-Copper Oxidases and Human Iron Metabolism

Science.gov (United States)

Vashchenko, Ganna; MacGillivray, Ross T. A.

2013-01-01

Multi-copper oxidases (MCOs) are a small group of enzymes that oxidize their substrate with the concomitant reduction of dioxygen to two water molecules. Generally, multi-copper oxidases are promiscuous with regards to their reducing substrates and are capable of performing various functions in different species. To date, three multi-copper oxidases have been detected in humans—ceruloplasmin, hephaestin and zyklopen. Each of these enzymes has a high specificity towards iron with the resulting ferroxidase activity being associated with ferroportin, the only known iron exporter protein in humans. Ferroportin exports iron as Fe2+, but transferrin, the major iron transporter protein of blood, can bind only Fe3+ effectively. Iron oxidation in enterocytes is mediated mainly by hephaestin thus allowing dietary iron to enter the bloodstream. Zyklopen is involved in iron efflux from placental trophoblasts during iron transfer from mother to fetus. Release of iron from the liver relies on ferroportin and the ferroxidase activity of ceruloplasmin which is found in blood in a soluble form. Ceruloplasmin, hephaestin and zyklopen show distinctive expression patterns and have unique mechanisms for regulating their expression. These features of human multi-copper ferroxidases can serve as a basis for the precise control of iron efflux in different tissues. In this manuscript, we review the biochemical and biological properties of the three human MCOs and discuss their potential roles in human iron homeostasis. PMID:23807651

Influence of reaction chamber shape on cast-iron spheroidization process in-mold

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S. Pietrowski

2010-01-01

Full Text Available This paper presents a results concerning the influence of reaction chamber shape on cast – iron spheroidization process in form. The volume of the tested reaction chambers was about 118000mm3. Reaction chambers in the shape of: rectangular, cylinder and spherical cap were examined. It has been shown that the best graphite spheroidizing process was provided by spherical cap chamber shape. The reaction of cast – iron with magnesium in reaction chamber depends on the flow of cast – iron in the chamber. In rectangular and cylinder shape chambers proceed the impact of diphase stream on flat bottom wall. It causes the creation on its surface film, called: cast – iron “film”, where single grains of magnesium master alloy exist. The largest part of master alloy is drifted by liquid cast – iron to the top and only there graphite spheroidization process proceed. In the spherical cap shape reaction chamber, as a result of rotation movement of liquid cast – iron throughout its volume, graphite spheroidization process proceed. Apart from the reaction chamber shape, applying of mixing chamber ensure full cast – iron spheroidization process.

Anaerobic Copper Toxicity and Iron-Sulfur Cluster Biogenesis in Escherichia coli.

Science.gov (United States)

Tan, Guoqiang; Yang, Jing; Li, Tang; Zhao, Jin; Sun, Shujuan; Li, Xiaokang; Lin, Chuxian; Li, Jianghui; Zhou, Huaibin; Lyu, Jianxin; Ding, Huangen

2017-08-15

While copper is an essential trace element in biology, pollution of groundwater from copper has become a threat to all living organisms. Cellular mechanisms underlying copper toxicity, however, are still not fully understood. Previous studies have shown that iron-sulfur proteins are among the primary targets of copper toxicity in Escherichia coli under aerobic conditions. Here, we report that, under anaerobic conditions, iron-sulfur proteins in E. coli cells are even more susceptible to copper in medium. Whereas addition of 0.2 mM copper(II) chloride to LB (Luria-Bertani) medium has very little or no effect on iron-sulfur proteins in wild-type E. coli cells under aerobic conditions, the same copper treatment largely inactivates iron-sulfur proteins by blocking iron-sulfur cluster biogenesis in the cells under anaerobic conditions. Importantly, proteins that do not have iron-sulfur clusters (e.g., fumarase C and cysteine desulfurase) in E. coli cells are not significantly affected by copper treatment under aerobic or anaerobic conditions, indicating that copper may specifically target iron-sulfur proteins in cells. Additional studies revealed that E. coli cells accumulate more intracellular copper under anaerobic conditions than under aerobic conditions and that the elevated copper content binds to the iron-sulfur cluster assembly proteins IscU and IscA, which effectively inhibits iron-sulfur cluster biogenesis. The results suggest that the copper-mediated inhibition of iron-sulfur proteins does not require oxygen and that iron-sulfur cluster biogenesis is the primary target of anaerobic copper toxicity in cells. IMPORTANCE Copper contamination in groundwater has become a threat to all living organisms. However, cellular mechanisms underlying copper toxicity have not been fully understood up to now. The work described here reveals that iron-sulfur proteins in Escherichia coli cells are much more susceptible to copper in medium under anaerobic conditions than they

Niobium in gray cast iron

International Nuclear Information System (INIS)

Castello Branco, C.H.; Beckert, E.A.

1984-03-01

The potential for utilization of niobium in gray cast iron is appraised and reviewed. Experiments described in literature indicate that niobium provides structural refinement of the eutectic cells and also promotes pearlite formation. (Author) [pt

Cast iron as structural material for hot-working reactor vessels (PCIV)

International Nuclear Information System (INIS)

Ostendorf, H.; Schmidt, G.; Pittack, W.

1977-01-01

Cast iron with lamellar graphite is best suited for prestressed structures, because its compressive strength is nearly 4 times its tensile strength. In comparison to room temperature, cast iron with lamellar graphite shows essentially no loss of strength up to temperatures of 400 0 C. Under the particular aspect to use cast iron for hot-working prestressed reactor pressure vessels (PCIV) (Prestressed cast iron vessel=PCIV) a materials testing program is carried out, which meets the strict certification requirements for materials in the construction of reactor pressure vessels and which completes the presently available knowledge of cast iron. Especially in the following fields an extension and supplement of the present level of knowledge is necessary. - Mechanical properties under compressive stresses. - Material properties at elevated temperatures. - Influence of irradiation on mechanical and physical properties. - Production standards and quality control. The state of the research and the available data of the material testing program are reported. (Auth.)

Cast iron as structural material for hot-working reactor vessels (PCIV)

International Nuclear Information System (INIS)

Ostendorf, H.; Schmidt, G.; Pittack, W.

1977-01-01

Cast iron with lamellar graphite is best suited for prestressed structures, because its compressive strength is nearly 4 times its tensile strength. In comparison to room temperature, cast iron with lamellar graphite shows essentially no loss of strength up to temperatures of 400 0 C. Under the particular aspect to use cast iron for hot-working prestressed reactor pressure vessels (PCIV) (Prestressed cast iron vessel=PCIV) a materials testing program is carried out, which meets the strict certification requirements for materials in the construction of reactor pressure vessels and which completes the presently available knowledge of cast iron. Especially in the following fields an extension and supplement of the present level of knowledge is necessary: mechanical properties under compressive stresses; material properties at elevated temperatures; influence of irradiation on mechanical and physical properties; production standards and quality control. The state of the research and the available data of the material testing program are reported

Surface hardening of two cast irons by friction stir processing

International Nuclear Information System (INIS)

Fujii, Hidetoshi; Kikuchi, Toshifumi; Nogi, Kiyoshi; Yamaguchi, Yasufumi; Kiguchi, Shoji

2009-01-01

The Friction Stir Processing (FSP) was applied to the surface hardening of cast irons. Flake graphite cast iron (FC300) and nodular graphite cast iron (FCD700) were used to investigate the validity of this method. The matrices of the FC300 and FC700 cast irons are pearlite. The rotary tool is a 25mm diameter cylindrical tool, and the travelling speed was varied between 50 and 150mm/min in order to control the heat input at the constant rotation speed of 900rpm. As a result, it has been clarified that a Vickers hardness of about 700HV is obtained for both cast irons. It is considered that a very fine martensite structure is formed because the FSP generates the heat very locally, and a very high cooling rate is constantly obtained. When a tool without an umbo (probe) is used, the domain in which graphite is crushed and striated is minimized. This leads to obtaining a much harder sample. The hardness change depends on the size of the martensite, which can be controlled by the process conditions, such as the tool traveling speed and the load. Based on these results, it was clarified that the FSP has many advantages for cast irons, such as a higher hardness and lower distortion. As a result, no post surface heat treatment and no post machining are required to obtain the required hardness, while these processes are generally required when using the traditional methods.

Research of complex briquetted modifiers influence on cast iron properties

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Наталя Валеріївна Сусло

2016-07-01

Full Text Available Such properties of cast iron as hardness and shock resistance are relevant and have been investigated. Some possible ways to improve these properties have been studied and solutions to the assigned tasks in accordance with modern trends have been found. The use of nano-dispersed modifiers is most promising in modification. The compositions of experimental complex briquetted modifiers have been developed. The technology of cast iron processing with complex briquetted modifiers has been developed. A series of experiments on the effect of a complex briquetted modifier introduced into cast iron on its properties were carried out. The rational content of components in the briquette that makes maximum use of the modifying effect and improves such service characteristics of cast iron as hardness, impact - and wear-resistance has been defined. Ways of a briquette destruction in metal have been explored. The effect of an organic binder amount on the destruction of a briquette and its dissolution in the melt has been investigated. Rational composition of the briquetted modifier that makes it possible to increase hardness and impact resistance of cast iron has been developed

Properties shaping and repair of selected types of cast iron

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J. Szajnar

2007-04-01

Full Text Available The paper presents research results of twofold use of TIG - Tungsten Inert Gas also known as GTA - Gas Tungsten Arc. First is surfacing by welding on cold and hot-cold to repair chromium cast iron with chromium content about 15%. Second is remelting with electric arc of selected gray (with pearlitic matrix and ductile (with ferritic-pearlitic matrix cast iron. Repair of cast iron elements was realized in order to cut out a casting defects. Defects decrease a usability of castings for constructional application and increase a manufacturing costs. Application of surface heat treatment guarantees mechanical properties i.e. hardness and wear resistance improvement. The result of investigations show possibility of castings repair by put on defects a good quality padding welds, which have comparable properties with base material. Use of electric arc surface heat treatment resulted in increase of hardness and wear resistance, which was measured on the basis of ASTM G 65 - 00 standard.

Wearing Quality of Austenitic, Duplex Cast Steel, Gray and Spheroidal Graphite Iron

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S. Pietrowski

2012-04-01

Full Text Available The current work presents the research results of abrasion wear and adhesive wear at rubbing and liquid friction of new austenitic, austenitic-ferritic (“duplex” cast steel and gray cast iron EN-GJL-250, spheroidal graphite iron EN-GJS-600-3, pearlitic with ledeburitic carbides and spheroidal graphite iron with ledeburitic carbides with a microstructure of the metal matrix: pearlitic, upper bainite, mixture of upper and lower bainite, martensitic with austenite, pearlitic-martensitic-bainitic-ausferritic obtained in the raw state. The wearing quality test was carried out on a specially designed and made bench. Resistance to abrasion wear was tested using sand paper P40. Resistance to adhesive wear was tested in interaction with steel C55 normalized, hardened and sulfonitrided. The liquid friction was obtained using CASTROL oil. It was stated that austenitic cast steel and “duplex” are characterized by a similar value of abrasion wear and adhesive wear at rubbing friction. The smallest decrease in mass was shown by the cast steel in interaction with the sulfonitrided steel C55. Austenitic cast steel and “duplex��� in different combinations of friction pairs have a higher wear quality than gray cast iron EN-GJL- 250 and spheroidal graphite iron EN-GJS-600-3. Austenitic cast steel and “duplex” are characterized by a lower wearing quality than the spheroidal graphite iron with bainitic-martensitic microstructure. In the adhesive wear test using CASTROL oil the tested cast steels and cast irons showed a small mass decrease within the range of 1÷2 mg.

Improving Beneficiation of Copper and Iron from Copper Slag by Modifying the Molten Copper Slag

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Zhengqi Guo

2016-04-01

Full Text Available In the paper, a new technology was developed to improve the beneficiation of copper and iron components from copper slag, by modifying the molten slag to promote the mineralization of valuable minerals and to induce the growth of mineral grains. Various parameters, including binary basicity, dosage of compound additive, modification temperature, cooling rate and the end point temperature of slow cooling were investigated. Meanwhile, optical microscope, scanning electron microscope and energy dispersive spectrometer (SEM-EDS was employed to determine the mineralogy of the modified and unmodified slag, as well as to reveal the mechanisms of enhancing beneficiation. The results show that under the proper conditions, the copper grade of rougher copper concentrate was increased from 6.43% to 11.04%, iron recovery of magnetic separation was increased significantly from 32.40% to 63.26%, and other evaluation indexes were changed slightly, in comparison with unmodified copper slag. Moreover, matte and magnetite grains in the modified slag aggregated together and grew obviously to the mean size of over 50 μm, resulting in an improvement of beneficiation of copper and iron.

Test manufacturing of copper canisters with cast inserts. Assessment report

Energy Technology Data Exchange (ETDEWEB)

Andersson, C.G

1998-08-01

The current design of canisters for the deep repository for spent nuclear fuel consists of an outer corrosion-protective copper casing in the form of a tubular section with lid and bottom and an inner pressure-resistant insert. The insert is designed to be manufactured by casting and inside are channels in which the fuel assemblies are to be placed. Over the last years, a number of full-scale manufacturing tests of all canister components have been carried out. The purpose has been to determine and develop the best manufacturing technique and to establish long-term contacts with the best suppliers of material and technology. Part of the work has involved the developing and implementing of a quality assurance system in accordance with ISO 9001, covering the whole chain from suppliers of material up to and including the delivery of assembled canisters. This report consists of a description of the design of the canister together with current drawings and complementary technical specifications stipulating, among other things, requirements placed on different materials. The different manufacturing methods that have been used are also described and commented on in both text and illustrations. For the manufacturing of copper tubes, the roll-forming of rolled plate to tube halves and longitudinal welding is a method that has been tested on a relatively large number of tubes by now, and that probably can be developed into a functioning production method. However, the very promising outcome of performed tests on seamless tube manufacturing, has resulted in a change in direction in tube manufacturing, focusing on continued testing of extrusion as well as pierce and draw processing in the immediate future. In connection with ongoing operations, new manufacturing tests of tubes with less material thickness will be carried out. Test manufacturing of cast inserts has resulted in the choice of nodular iron as material in the continued work. This improvement in design has resulted

Test manufacturing of copper canisters with cast inserts. Assessment report

International Nuclear Information System (INIS)

Andersson, C.G.

1998-08-01

The current design of canisters for the deep repository for spent nuclear fuel consists of an outer corrosion-protective copper casing in the form of a tubular section with lid and bottom and an inner pressure-resistant insert. The insert is designed to be manufactured by casting and inside are channels in which the fuel assemblies are to be placed. Over the last years, a number of full-scale manufacturing tests of all canister components have been carried out. The purpose has been to determine and develop the best manufacturing technique and to establish long-term contacts with the best suppliers of material and technology. Part of the work has involved the developing and implementing of a quality assurance system in accordance with ISO 9001, covering the whole chain from suppliers of material up to and including the delivery of assembled canisters. This report consists of a description of the design of the canister together with current drawings and complementary technical specifications stipulating, among other things, requirements placed on different materials. The different manufacturing methods that have been used are also described and commented on in both text and illustrations. For the manufacturing of copper tubes, the roll-forming of rolled plate to tube halves and longitudinal welding is a method that has been tested on a relatively large number of tubes by now, and that probably can be developed into a functioning production method. However, the very promising outcome of performed tests on seamless tube manufacturing, has resulted in a change in direction in tube manufacturing, focusing on continued testing of extrusion as well as pierce and draw processing in the immediate future. In connection with ongoing operations, new manufacturing tests of tubes with less material thickness will be carried out. Test manufacturing of cast inserts has resulted in the choice of nodular iron as material in the continued work. This improvement in design has resulted

X-ray fluorescence control of chemical composition of cast iron

International Nuclear Information System (INIS)

Prekina, I.M.; Rozova, O.F.; Loran, A.V.; Teplitskaya, G.A.; Smagunova, A.N.

1995-01-01

A method of x-ray fluorescence analysis developed for analytical set (KRF-18 diffractometer/DVK-3 computer) is used to control cast iron composition. A quantitative evaluation of errors attributed to the violation of conditions of cast iron sampling from the flow and to the quality of preparing samples for XFA is obtained. It is shown that the main component of the integral experimental error is attributed to nonuniformity of chemical composition of cast iron. Metrological studies show that reproductibility, convergence, accuracy, and sensitivity of the method match the requirements characteristic of the control process. 4 refs.; 2 tabs

Investigation of friction and wear characteristics of cast iron material under various conditions

Energy Technology Data Exchange (ETDEWEB)

Joo, Ji Hoon; Kim, Chang Lae; Oh, Jeong Taek; Kim, Dae Eun [Yonsei University, Seoul (Korea, Republic of); Nemati, Narguess [School of Materials and Metallurgy, University of Tehran, Tehran (Iran, Islamic Republic of)

2015-08-15

Cast iron is widely used in fields such as the transport and heavy industries. For parts where contact damage is expected to occur, it is necessary to understand the friction and wear characteristics of cast iron. In this study, we use cast iron plates as the specimens to investigate their friction and wear characteristics. We perform various experiments using a reciprocating type tribotester. We assess the frictional characteristics by analyzing the friction coefficient values that were obtained during the sliding tests. We observe the wear surfaces of cast iron and steel balls using a scanning electron microscope, confocal microscope, and 3D profiler. We investigate the friction and wear characteristics of cast iron by injecting sand and alumina particles having various sizes. Furthermore, we estimate the effect of temperature on the friction and wear characteristics. The results obtained are expected to aid in the understanding of the tribological characteristics of cast iron in industry.

The interplay between siderophore secretion and coupled iron and copper transport in the heterocyst-forming cyanobacterium Anabaena sp. PCC 7120.

Science.gov (United States)

Nicolaisen, Kerstin; Hahn, Alexander; Valdebenito, Marianne; Moslavac, Suncana; Samborski, Anastazia; Maldener, Iris; Wilken, Corinna; Valladares, Ana; Flores, Enrique; Hantke, Klaus; Schleiff, Enrico

2010-11-01

Iron uptake is essential for Gram-negative bacteria including cyanobacteria. In cyanobacteria, however, the iron demand is higher than in proteobacteria due to the function of iron as a cofactor in photosynthesis and nitrogen fixation, but our understanding of iron uptake by cyanobacteria stands behind the knowledge in proteobacteria. Here, two genes involved in this process in the heterocyst-forming cyanobacterium Anabaena sp. PCC 7120 were identified. ORF all4025 encodes SchE, a putative cytoplasmic membrane-localized transporter involved in TolC-dependent siderophore secretion. Inactivation of schE resulted in an enhanced sensitivity to high metal concentrations and decreased secretion of hydroxamate-type siderophores. ORF all4026 encodes a predicted outer membrane-localized TonB-dependent iron transporter, IacT. Inactivation of iacT resulted in decreased sensitivity to elevated iron and copper levels. Expression of iacT from the artificial trc promoter (P(trc)) resulted in sensitization against tested metals. Further analysis showed that iron and copper effects are synergistic because a decreased supply of iron induced a significant decrease of copper levels in the iacT insertion mutant but an increase of those levels in the strain carrying P(trc)-iacT. Our results unravel a link between iron and copper homeostasis in Anabaena sp. PCC 7120. Copyright © 2010 Elsevier B.V. All rights reserved.

The micro-mechanisms of failure of nodular cast iron

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Alan Vaško

2014-12-01

Full Text Available The contribution deals with a comparison of the micro-mechanisms of failure of nodular cast irons at static, impact and fatigue stress. Several specimens of ferrite-pearlitic nodular cast irons with different content of ferrite in a matrix were used for metallographic analysis, mechanical tests and micro-fractographic analysis. Mechanical properties were found by static tensile test, impact bending test and fatigue tests. The micro-fractographic analysis was made with use of scanning electron microscope VEGA II LMU on fracture surfaces of the specimens fractured by these mechanical and fatigue tests. Fracture surfaces of analysed specimens are characteristic of mixed mode of fracture. Micro-mechanism of failure of nodular cast irons is dependent on the method of stress.

Metabolism of manganese, iron, copper, and selenium in calves

International Nuclear Information System (INIS)

Ho, S.Y.

1981-01-01

Sixteen male Holstein calves were used to study manganese and iron metabolism. The calves were fed one of the following diets for 18 days: control, control + iron, control + manganese, and control + iron and manganese. All calves were dosed orally with manganese-54. Tissue concentrations of manganese, iron and manganese-54 were determined. Small intestinal iron was lower in calves fed the high manganese diet than in controls. Tissue manganese-54 was lower in calves fed a high manganese diet. Fecal manganese content increased in calves fed both high manganese and high manganese-high iron diets. Serum total iron was not affected by the dietary treatments. To study the effects of high dietary levels of copper and selenium on the intracellular distributions of these two elements in liver and kidney cytosol, calves were fed one of four diets for 15 days. These were 0 and 100 ppM supplemental copper and 0 and 1 ppM added selenium. The control diet containing 0.1 ppM of selenium and 15 ppM of copper. All calves were orally dosed 48 hrs prior to sacrifice with selenium-75. A high copper diet increased copper concentrations in all intracellular liver fractions and most kidney fractions. Only the effects in the liver were significant. Less copper was found in the mitochondria fractions in liver and kidney of calves fed a high selenium diet. Three major copper-binding protein peaks were separated from the soluble fractions of calf liver and kidney. Peak 1 appeared to be the major copper-binding protein in liver and kidney cytosol of copper-loaded animals. Added selenium alone or in combination with copper accentuated the copper accumulation in this peak. Most of selenium-75 was recovered in the same peak as the copper. The results of this experiment indicated that the large molecular proteins in liver and kidney cytosol of calves play an important role in copper and selenium-75 metabolism

Investigations of Ferritic Nodular Cast Iron Containing About 5-6% Aluminium

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Soiński M.S.

2016-12-01

Full Text Available The work presents results of investigations concerning the production of cast iron containing about 5-6% aluminium, with the ferritic matrix in the as-cast state and nodular or vermicular graphite precipitates. The examined cast iron came from six melts produced under the laboratory conditions. It contained aluminium in the amount of 5.15% to 6.02% (carbon in the amount of 2.41% to 2.87%, silicon in the amount of 4.50% to 5.30%, and manganese in the amount of 0.12% to 0.14%. After its treatment with cerium mixture and graphitization with ferrosilicon (75% Si, only nodular and vermicular graphite precipitates were achieved in the examined cast iron. Moreover, it is possible to achieve the alloy of pure ferritic matrix, even after the spheroidizing treatment, when both the aluminium and the silicon occur in cast iron in amounts of about 5.2÷5.3%.

The effect of microstructure of low-alloy spheroidal cast iron on impact strength

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T. Szykowny

2010-01-01

Full Text Available The study presents an evaluation of the effect of microstructure of low-alloy spheroidal cast iron on impact strength within the temperature range from –60 to 100°C. Analyses were conducted on one type of cast iron containing 0.51% Cu and 0.72% Ni. Cast iron was austempered or normalized. Values of KCV and static mechanical properties were determined. Structural and fractographic analyses were based on light and scanning microscopy as well as X-ray diffraction. It was found that thermal processing considerably improves impact strength in relation to cast iron after casting. At the same time static mechanical properties are enhanced.

Dissolution of copper and iron from malachite ore and precipitation of copper sulfate pentahydrate by chemical process

OpenAIRE

H. Kokes; M.H. Morcali; E. Acma

2014-01-01

The present work describes an investigation of a chemical process for the recovery of copper and iron from malachite ore. For the dissolution of copper and iron, H2SO4 was employed as well as H2O2 as an oxidizing agent. The effects of reaction temperature and time, acid concentration, liquid-to-solid ratio and agitation rate on the copper and iron percentage were investigated. Following the steps of dissolving the copper and iron sulfate and filtering, iron (III) hydroxide was precipitated by...

Melting of Grey Cast Iron Based on Steel Scrap Using Silicon Carbide

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Stojczew A.

2014-08-01

Full Text Available The paper presents the issue of synthetic cast iron production in the electric induction furnace exclusively on the steel scrap base. Silicon carbide and synthetic graphite were used as carburizers. The carburizers were introduced with solid charge or added on the liquid metal surface. The chemical analysis of the produced cast iron, the carburization efficiency and microstructure features were presented in the paper. It was stated that ferrosilicon can be replaced by silicon carbide during the synthetic cast iron melting process. However, due to its chemical composition (30% C and 70% Si which causes significant silicon content in iron increase, the carbon deficit can be partly compensated by the carburizer introduction. Moreover it was shown that the best carbon and silicon assimilation rate is obtained where the silicon carbide is being introduced together with solid charge. When it is thrown onto liquid alloy surface the efficiency of the process is almost two times less and the melting process lasts dozen minutes long. The microstructure of the cast iron produced with the silicon carbide shows more bulky graphite flakes than inside the microstructure of cast iron produced on the pig iron base.

The sort of carburization and the quality of obtained cast iron

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K. Janerka

2008-12-01

Full Text Available In the production of cast iron, the pig iron’s amount in charge material is more and more often limited, and replaced by steel scrap. That extorts the necessity of know-how the carburization and one is looking for carburizers, which ensure obtaining big carbon increment as quickly as possible with the high repeatability and the ones which ensure getting the adequate quality of cast iron. The object of presented research was definition of the influence of charge materials’ sort on the structure, course of solidification, and the effectiveness of process. The cast iron melts, which are presented below, are made only on the basis of steel scrap with portion of graphitoidal, coke and anthracite carburizers, which were added to the charge in solid. In the article one compared the carburizers in respect of their structure, chemical constitution and the effectiveness obtained during the carburization of liquid metal. The melting of cast iron, based on the special pig iron, was carried out as well. The course of melts, chemical constitution of obtained cast iron and its structure were presented. The comparison between quality distribution and the volume fraction of graphite in classes of size for the individual melts were achieved and the TDA curves were inserted.

Investigation of the tensile properties of continuous steel wire-reinforced gray cast iron composite

Energy Technology Data Exchange (ETDEWEB)

Akdemir, Ahmet [Department of Mechanical Engineering, Selcuk University, Konya (Turkey); Kus, Recai [Department of Mechanical Education, Selcuk University, Konya (Turkey); Simsir, Mehmet, E-mail: msimsir@cumhuriyet.edu.tr [Department of Metallurgical and Materials Engineering, Cumhuriyet University, Kayseri Yolu 7. Km, 58140 Sivas (Turkey)

2011-04-25

Research highlights: {yields} Metal matrix composite (MMC) is an important structural material. {yields} Gray cast irons as a matrix material in MMC have more advantages than other cast irons. {yields} Interface greatly determines the mechanical properties of MMC. {yields} Interface formed by diffusion of carbon atoms. {yields} While decarburizing takes place in gray cast iron, carburiszing takes place in steel near the interface. - Abstract: The aim of the present study was to improve the tensile properties of gray cast iron by reinforcing the material with a steel wire. The composite was produced by sand mold casting, and the specimens were normalized by applying heat treatments at 800 deg. C, 850 deg. C, and 900 deg. C. Tension tests were conducted on gray cast iron and composite specimens, and the microstructure of the specimens was examined with an optical microscope. The fracture surface of the tension test specimens was examined with a scanning electron microscope (SEM), and graphite-free transition regions with high degrees of hardness were observed due to the diffusion of carbon from the cast iron to the steel wire. The microstructure of the transition region (fine pearlitic phase with partially dissolved graphite flakes) and the bond quality in the transition region increased the tensile properties of cast iron composites. Also, it is concluded that the tensile properties of gray cast iron increased with an increase in the normalization temperature.

Investigation of the tensile properties of continuous steel wire-reinforced gray cast iron composite

International Nuclear Information System (INIS)

Akdemir, Ahmet; Kus, Recai; Simsir, Mehmet

2011-01-01

Research highlights: → Metal matrix composite (MMC) is an important structural material. → Gray cast irons as a matrix material in MMC have more advantages than other cast irons. → Interface greatly determines the mechanical properties of MMC. → Interface formed by diffusion of carbon atoms. → While decarburizing takes place in gray cast iron, carburiszing takes place in steel near the interface. - Abstract: The aim of the present study was to improve the tensile properties of gray cast iron by reinforcing the material with a steel wire. The composite was produced by sand mold casting, and the specimens were normalized by applying heat treatments at 800 deg. C, 850 deg. C, and 900 deg. C. Tension tests were conducted on gray cast iron and composite specimens, and the microstructure of the specimens was examined with an optical microscope. The fracture surface of the tension test specimens was examined with a scanning electron microscope (SEM), and graphite-free transition regions with high degrees of hardness were observed due to the diffusion of carbon from the cast iron to the steel wire. The microstructure of the transition region (fine pearlitic phase with partially dissolved graphite flakes) and the bond quality in the transition region increased the tensile properties of cast iron composites. Also, it is concluded that the tensile properties of gray cast iron increased with an increase in the normalization temperature.

THE CORROSION BEHAVIOR AND WEAR RESISTANCE OF GRAY CAST IRON

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Lina F. Kadhim

2018-01-01

Full Text Available Gray cast iron has many applications as pipes , pumps and valve bodies where it has influenced by heat and contact with other solutions . This research has studied the corrosion behavior and Vickers hardness of gray cast iron by immersion in four strong alkaline solutions (NaOH, KOH, Ca(OH2, LiOHwith three concentrations (1%,2%,3% of each solution. Dry sliding wear has carried out before and after the heat treatments (stress relief ,normalizing, hardening and tempering. In this work ,maximum wear strength has obtained at tempered gray cast iron and minimum corrosion rate has obtained in LiOH solution by forming protective white visible oxide layer.

Dissolution of copper and iron from malachite ore and precipitation of copper sulfate pentahydrate by chemical process

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H. Kokes

2014-03-01

Full Text Available The present work describes an investigation of a chemical process for the recovery of copper and iron from malachite ore. For the dissolution of copper and iron, H2SO4 was employed as well as H2O2 as an oxidizing agent. The effects of reaction temperature and time, acid concentration, liquid-to-solid ratio and agitation rate on the copper and iron percentage were investigated. Following the steps of dissolving the copper and iron sulfate and filtering, iron (III hydroxide was precipitated by adjusting the pH level of the solution. Subsequently, copper sulfate pentahydrate was obtained by using various precipitants (i.e. ethanol, methanol and sulfuric acid.

Thin wall ductile iron casting as a substitute for aluminum alloy casting in automotive industry

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M. Górny

2009-01-01

Full Text Available In paper it is presented thin wall ductile iron casting (TWDI as a substitute of aluminium alloy casting. Upper control arm made of ductile iron with wall thickness ranging from 2 – 3.7 mm was produced by inmold process. Structure, mechanical properties and computer simulations were investigated. Structural analysis of TWDI shows pearlitic-ferritic matrix free from chills and porosity. Mechanical testing disclose superior ultimate tensile strength (Rm, yield strength (Rp0,2 and slightly lower elongation (E of TWDI in comparison with forged control arm made of aluminium alloy (6061-T6. Moreover results of computer simulation of static loading for tested control arms are presented. Analysis show that the light-weight ductile iron casting can be loaded to similar working conditions as the forged Al alloy without any potential failures.

Cast Iron in The 19th Century Building Equipment

Science.gov (United States)

Kwasek, Michał; Piwek, Aleksander

2017-10-01

Cast iron is a material, characteristics of which enable to receive extremely artistic elements. It maintains good strength properties at the same time. That combination of these seemingly contrary traits makes it a commodity that was widely used in the 19th century industry and architecture. These usages were not only as decorative elements, technical and structural ones. The production of new household utilities started, which made people’s lives more comfortable. Cast iron allowed for fast and cheap production while maintaining high aesthetic qualities. Useful elements, which often were ornamental parts of buildings were created. The aim of the article is to characterise elements of interior equipment of the 19th century building that are made of cast iron. As it appears from performed bibliography, archival and field studies, the ways of exploitation are very broad. Some were mounted into the building; the others were a mobile equipment. As it occurred they were most commonly used as functional items. Cast iron was used to produce the minor elements, which were only parts of the bigger wooden or stone items. Notwithstanding, there were also bigger ones casted as a whole, and frequently ones that were assembled from many elements. Nowadays, elements of an interior feature are one of the subjects of study during the restoration work of the buildings. They can provide important information about the building and the way people lived and are considered as the essential part of historical objects.

Magnetic and Structural Properties of Electrodeposited Iron on Copper and Silver

International Nuclear Information System (INIS)

Koempe, K.; Kuehl, E.; Nagorny, K.

2002-01-01

Electrodeposition of iron on copper or silver leads to the formation of bcc-iron or amorphous iron. Thermal annealing usually results in soluted iron (also γ-iron and clusters) in copper. On silver the insolubility of iron never causes the formation of bcc-iron. Instead on copper as well as on silver fcc-iron states are formed, especially at relatively low temperatures with short times of annealing. Moessbauer spectroscopy accompanied by X-ray diffraction (XRD) and vibrating sample magnetometry (VSM) are applied for characterisation of the iron states.

Effect of Heating Time on Hardness Properties of Laser Clad Gray Cast Iron Surface

Science.gov (United States)

Norhafzan, B.; Aqida, S. N.; Mifthal, F.; Zulhishamuddin, A. R.; Ismail, I.

2018-03-01

This paper presents effect of heating time on cladded gray cast iron. In this study, the effect of heating time on cladded gray cast iron and melted gray cast iron were analysed. The gray cast iron sample were added with mixed Mo-Cr powder using laser cladding technique. The mixed Mo and Cr powder was pre-placed on gray cast iron surface. Modified layer were sectioned using diamond blade cutter and polish using SiC abrasive paper before heated. Sample was heated in furnace for 15, 30 and 45 minutes at 650 °C and cool down in room temperature. Metallographic study was conduct using inverted microscope while surface hardness properties were tested using Wilson hardness test with Vickers scale. Results for metallographic study showed graphite flakes within matrix of pearlite. The surface hardness for modified layer decreased when increased heating time process. These findings are significant to structure stability of laser cladded gray cast iron with different heating times.

Studying and improving blast furnace cast iron quality

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Т. К. Balgabekov

2014-10-01

Full Text Available In the article there are presented the results of studies to improve the quality of blast furnace cast iron. It was established that using fire clay suspension for increasing the mould covering heat conductivity improves significantly pig iron salable condition and filtration refining method decreases iron contamination by nonmetallic inclusions by 50 – 70 %.

Mixed graphite cast iron for automotive exhaust component applications

OpenAIRE

De-lin Li

2017-01-01

Both spheroidal graphite iron and compacted graphite iron are used in the automotive industry. A recently proposed mixed graphite iron exhibits a microstructure between the conventional spheroidal graphite iron and compacted graphite iron. Evaluation results clearly indicate the suitability and benefits of mixed graphite iron for exhaust component applications with respect to casting, machining, mechanical, thermophysical, oxidation, and thermal fatigue properties. A new ASTM standard speci...

Improvement in thermal fatigue resistance of cast iron piston; Chutetsu piston no tainetsu hiro sekkei

Energy Technology Data Exchange (ETDEWEB)

Amano, K; Uosaki, Y; Takeshige, N [Mazda Motor Corp., Hiroshima (Japan)

1997-10-01

Cast iron piston is superior in reduction of diesel engine emission to aluminum piston because of its characteristic of heat insulation. In order to study thermal fatigue characteristics of cast iron, thermal fatigue tests were carried out on two kinds of ferrite ductile cast iron. Differences between cast iron piston and aluminum piston in thermal fatigue resistance have been investigated by using FEM analysis. 5 refs., 14 figs., 1 tab.

Influence of microscopic casting defects on fatigue endurance of ductile cast iron

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Nový František

2018-01-01

Full Text Available In this work, there are published results about fatigue endurance of ductile cast iron obtained at high-frequency sinusoidal cyclic push-pull loading in the ultra-high cycle fatigue region. The main attention was focused on the fatigue lifetime data scatter caused by the influence of microscopic casting defects (microshrinkages, microbubbles, microcracks, non-metallic inclusions and local clusters of big graphitic nodules.

Residual stresses in a cast iron automotive brake disc rotor

International Nuclear Information System (INIS)

Ripley, Maurice I.; Kirstein, Oliver

2006-01-01

Runout, and consequent juddering and pulsation through the brake pedal, is a multi-million dollar per year warranty problem for car manufacturers. There is some suspicion that the runout can be caused by relaxation of residual casting stresses when the disc is overheated during severe-braking episodes. We report here neutron-diffraction measurements of the levels and distribution of residual strains in a used cast iron brake disc rotor. The difficulties of measuring stresses in grey cast iron are outlined and three-dimensional residual-strain distributions are presented and their possible effects discussed

Performance of heavy ductile iron castings for windmills

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Iulian Riposan

2010-05-01

Full Text Available The main objective of the present paper is to review the specific characteristics and performance obtaining conditions of heavy ductile iron (DI castings, typically applied in windmills industry, such as hubs and rotor housings. The requirements for high impact properties in DI at low temperatures are part of the EN-GJS-400-18U-LT (SRN 1563 commonly referred to as GGG 40.3 (DIN 1693. Pearlitic influence factor (Px and antinodularising action factor (K1 were found to have an important influence on the structure and mechanical properties, as did Mn and P content, rare earth (RE addition and inoculation power. The presence of high purity pig iron in the charge is extremely beneficial, not only to control the complex factors Px and K1, but also to improve the ‘metallurgical quality’ of the iron melt. A correlation of C and Si limits with section modulus is very important to limit graphite nodule flotation. Chunky and surface-degenerated graphite are the most controlled graphite morphologies in windmills castings. The paper concluded on the optimum iron chemistry and melting procedure, Mg-alloys and inoculants peculiar systems, as well as on the practical solutions to limit graphite degeneration and to ensure castings of the highest integrity, typically for this field.

Microstructure and properties of TP2 copper tube with La microalloying by horizontal continuous casting

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Jin-hu Wu

2018-01-01

Full Text Available The TP2 copper tube was prepared with La microalloying by horizontal continuous casting (HCC. The absorptivity of La and its effects on microstructure, tensile and corrosion properties of HCC TP2 copper tube were studied by means of the inductively coupled plasma optical emission spectrometer (ICP-OES, optical microscope (OM, scanning electron microscope (SEM and potentiodynamic polarization measurements. The results show that the absorptivity of La in the HCC TP2 copper tube is about 15% under antivacuum conditions due to the good chemical activities of La. The impurity elements in copper tube such as O, S, Pb and Si can be significantly reduced, and the average columnar dendrite spacing of the copper tube can also be reduced from 2.21 mm to 0.93 mm by adding La. The ultimate tensile strength and the elongation with and without La addition are almost unchanged. However, the annual corrosion rate of the HCC TP2 copper tube is reduced from 10.18 mm•a-1 to 9.37 mm•a-1 by the purification effect of trace La.

THE INFLUENCE OF CHEMICAL COMPOSITION OF HIGH-CHROMIUM CAST IRONS ON THE MACHINABILITY

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V. V. Netrebko

2016-02-01

Full Text Available Purpose. This research is aimed to obtain the regression dependence of the machinability on the chemical composition of pig iron (C, Cr, Mn and Ni in cast state. Methodology. The method of active experiment planning was used to build a mathematical model. Cast irons of composition 1.09…3.91 % С; 11.43…25.57 % Cr; 0.6…5.4 % Mn; 0.19…3.01 % Ni were studied. Cutting tools with plates 10х10 mm out of ВК8 according to State Standard 19051-80 were used for turning. Cutting modes: cutting depth – 0.8 mm, longitudinal feed – 0.15 mm/rot., spindle’s rotation frequency during turning – 200…360 rot./min. Lubricating and cooling liquids were not applied. Evaluation of iron workability was produced by determining the linear tool flank wear per unit length of the cutting path. Findings. Mathematically probabilistic equation of the regression dependence of the cutting tool’s wear on the C, Cr, Mn and Ni content in the machined cast iron were obtained. It was established that with the increase of Cr content in the cast iron to 14.8 % the cutting tool’s wear decreased as a result of formation of carbide eutectic which destroyed the doped ledeburite continuous frame. Further increase of chromium content promoted appearing of chromic carbides with high microhardness which considerably increased the tool’s wear. The conducted research shown that the minimum cutting tool’s wear 0,18 mkm/m was observed during the machining of cast iron containing: 1.09 % C, 14.8 % Cr, 2.3 % Mn and 1.2 % Ni; and the maximum wear is 48,96 mkm/m – when the content was: 3.91 % C, 11.43 % Cr, 5.4 % Mn and 0.19 % Ni. The tool’s wear reached 47.61 mkm/m during the treatment of cast iron containing 3.91 % C, 25.57 % Cr, 5.4 % Mn and 0.19 % Ni. Originality. Mathematically probabilistic model of the dependence of the cutting tool’s wear on the C, Cr, Mn and Ni content in the machined cast iron has been elaborated by the author. Practical value. The model

Evaluation of static and dynamic fracture toughness in ductile cast iron

International Nuclear Information System (INIS)

Kobayashi, Toshiro; Yamada, Shinya

1994-01-01

Ductile cast irons have been explored as a cask (container for spent nuclear fuel) material because of their low cost and good formability. The cask, which is a huge casting with 400-mm thickness and 100-Mg weight, envelops the nuclear material. Therefore, the fracture toughness of cask must be evaluated not only under the static loading condition but also under the dynamic loading condition to ensure its safety against an accident during the transport. In this article, crack extension behavior and fracture toughness of ductile cast iron were examined by three-point bend tests, where various detection methods of crack initiation under static and dynamic loading conditions were adopted. Loading on the specimens was interrupted at various displacement points, and the final fracture surfaces of the specimen were observed via scanning electron microscopy (SEM). Crack-tip opening displacement (CTOD) obtained under the dynamic loading conditions was smaller than that under the static loading condition in ferritic ductile cast iron, and CTOD additionally decreased with increasing pearlite content in the matrix. The relationship between J(ΔC) obtained by the compliance changing rate method and J(R) established by the intersection of the crack extension resistance curve and the theoretical blunting line varied with pearlite content. The average value of J(ΔC) and J(R), that is J(mid), was proposed to define the fracture toughness of ductile cast iron; J(mid) was considered to be a reasonable measure for the fracture toughness of ductile cast iron, irrespective of loading condition and the pearlite content in the matrix

Ductile cast iron obtaining by Inmold method with use of LOST FOAM process

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T. Pacyniak

2010-01-01

Full Text Available The possibility of manufacturing of ductile cast iron castings by Inmold method with use of LOST FOAM process was presented in this work. The spheroidization was carried out by magnesium master alloy in amounts of 1% casting mass. Nodulizer was located in the reactive chamber in the gating system made of foamed polystyrene. Pretests showed, that there are technical possibilities of manufacturing of casts from ductile cast iron in the LOST FOAM process with use of spheroidization in mould.

Anodic Dissolution of Spheroidal Graphite Cast Iron with Different Pearlite Areas in Sulfuric Acid Solutions

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Yoshikazu Miyata

2013-01-01

Full Text Available The rate equation of anodic dissolution reaction of spheroidal graphite cast iron in sulfuric acid solutions at 298 K has been studied. The cast irons have different areas of pearlite. The anodic Tafel slope of 0.043 V decade−1 and the reaction order with respect to the hydroxyl ion activity of 1 are obtained by the linear potential sweep technique. The anodic current density does not depend on the area of pearlite. There is no difference in the anodic dissolution reaction mechanisms between pure iron and spheroidal graphite cast iron. The anodic current density of the cast iron is higher than that of the pure iron.

USE OF HIGH-STRENGTH BAINITIC CAST IRON FOR PRODUCING GEAR WHEELS

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A. I. Pokrovskiy

2015-01-01

Full Text Available The advantages and drawbacks of high-strength cast irons with bainitic structure are reviewed basing on the authors’ own experience in the production of critical partsfrom this material and on the analysis of world trends. A possibility of the replacement of alloy steels by bainitic cast iron in manufacturing critical machine parts is discussed.

The application of fracture mechanics on nodular cast iron

International Nuclear Information System (INIS)

Kussmaul, K.; Blind, D.; Kockelmann, H.; Roos, E.; Eisele, U.

1987-01-01

A series of studies on predominantly thick-walled castings was the first attempt at a characterization of the material of ferritization-annealed ductile cast iron under aspects of fracture mechanics according to today's state of fracture-mechanics research and testing. As in static and dynamic tensile testing, ferritic cast iron meeting specifications was found to be tough down -40 0 C and below in fracture mechanical testing without substantial reduction of the corresponding characteristics at room temperature; this is true for a temperature range where the lowest point of impact notch work has been reached already. Impact-type stresses with and without notching resulted in enhanced deformation resistance and deformability in the longitudinal samples taken from tubes. (orig./DG) [de

Mechanisms and mechanics of porosity formation in ductile iron castings

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M. Perzyk

2007-12-01

Full Text Available Shrinkage defects in ductile iron castings can be of two basic types: shrinkage cavities associated with the liquid contraction prior to the expansion period of the iron as well as the porosity, which may appear even if the liquid shrinkage is fully compensated. In the present paper two possible mechanisms of the porosity are presented and analyzed. The first one is the Karsay’s mechanism based on the secondary shrinkage concept. The second one is the mechanism acting during the expansion period of the iron, first suggested by Ohnaka and co-authors and essentially modified by the present authors. The mechanical interactions between casting and mould are determined for the both mechanisms. Their analysis leads to the conclusion, that porosity forms during expansion period of the melt. The direct cause is the negative pressure which appears in the central part of the casting due to the differences in expansion coefficients of the fast cooling surface layer and slow cooling inner region. Observations concerning feeding behavior of ductile iron castings, based on this mechanism, agree well with industrial practice. The secondary shrinkage is not only needless to induce the porosity, but the corresponding mechanism of its occurrence, proposed by Karsay, does not seem to be valid.

Effect of Microstructure on the Thermal Properties of Sintered Iron-copper Composites

OpenAIRE

Ugarteche, Caroline Velasques; Furlan, Kaline Pagnan; Pereira, Rafaela do Vale; Trindade, Gabriel; Binder, Roberto; Binder, Cristiano; Klein, Aloisio Nelmo

2015-01-01

Copper is a well know material for use as heat sink or heat exchanger. However, copper has a considerable low tensile strength and temperature limit. A material that has a good thermal conductivity, low cost, but also resistance is the desired. Effects of copper on the sintering and thermal properties of iron-copper composites produced by powder metallurgy and Fe on copper-iron composites have been investigated. Copper and iron were varied from 20 to 80 vol.% in the samples, alternating the c...

Numerical modelling of solidification of thin walled hypereutectic ductile cast iron

DEFF Research Database (Denmark)

Pedersen, Karl Martin; Hattel, Jesper; Tiedje, Niels

2006-01-01

Numerical simulation of solidification of ductile cast iron is normally based on a model where graphite nodules are surrounded by an austenite shell. The two phases are then growing as two concentric spheres governed by diffusion of carbon through the austenite shell. Experiments have however shown...... simulation of thin-walled ductile iron castings. Simulations have been performed with a 1-D numerical solidi¬fication model that includes the precipitation of non-eutectic austenite during the eutectic stage. Results from the simulations have been compared with experimental castings with wall thick...

Experimental analysis of flow of ductile cast iron in stream lined gating systems

DEFF Research Database (Denmark)

Skov-Hansen, Søren Peter; Tiedje, Niels Skat

2008-01-01

Streamlined gating systems have been developed for production of high integrity ductile cast iron parts. Flow of ductile cast iron in streamlined gating systems was studied in glass fronted sand moulds where flow in the gating system and casting was recorded by a digital video camera. These results...... show how the quality of pouring, design of ingates, design of bends and flow over cores influence melt flow and act to determine the quality of the castings....

Development of a manufacturing technology of compacted graphite iron castings from a cupola furnace

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O. Bouska

2012-01-01

Full Text Available Compacted graphite iron, also known as vermicular cast iron or semiductile cast iron is a modern material, the production of which is increasing globaly. Recently this material has been very often used in automotive industry. This paper reviews some findigs gained during the development of the manufacturing technology of compacted graphite iron under the conditions in Slévárna Heunisch Brno, Ltd. The new technology assumes usage of cupola furnace for melting and is beeing developed for production of castings weighing up to 300 kilograms poured into bentonite sand moulds.

Solidification, processing and properties of ductile cast iron

DEFF Research Database (Denmark)

Tiedje, Niels Skat

2010-01-01

Ductile cast iron has been an important engineering material in the past 50 years. In that time, it has evolved from a complicated material that required the foundry metallurgist's highest skill and strict process control to being a commonly used material that can easily be produced with modern...... of the latest years of research indicate that ductile cast iron in the future will become a highly engineered material in which strict control of a range of alloy elements combined with intelligent design and highly advanced processing allows us to target properties to specific applications to a much higher...... degree than we have seen previously. It is the aim of the present paper to present ductile iron as a modern engineering material and present the many different possibilities that the material hides. Focus will be on the latest research in solidification and melt treatment. But for completeness...

Comparative performance of aluminium copper and iron solar stills

International Nuclear Information System (INIS)

Dioha, I.J.; Nwagbo, E.E.; Gulma, N.A.

1990-12-01

Three different metal sheets have been used in the fabrication of three different single sloping solar stills of the same surface geometry. The metals were galvanized iron, aluminium and copper. This paper presents the performance of the different stills operating under the same environmental conditions. The observed distillate yields was greatest for copper, then aluminium and lastly, iron still. The differences in the yields is attributed to the differences in the thermal conductivities of the metals. The equivalent local costs for the fabrication of the copper, aluminium and iron stills are respectively $160, $95 and $60. Taking the long run costs into consideration, the copper still is preferred because of its availability, durability, weldability and relatively higher conductivity of 380Wm -1 K -1 value. (author). 9 refs, 2 figs, 2 tabs

Carbon in condensed hydrocarbon phases, steels and cast irons

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GAFAROVA Victoria Alexandrovna

2017-11-01

Full Text Available The article presents a review of studies carried out mainly by the researchers of the Ufa State Petroleum Technological University, which are aimed at detection of new properties of carbon in such condensed media as petroleum and coal pitches, steels and cast irons. Carbon plays an important role in the industry of construction materials being a component of road and roof bitumen and setting the main mechanical properties of steels. It was determined that crystal-like structures appear in classical glass-like substances – pitches which contain several thousands of individual hydrocarbons of various compositions. That significantly extends the concept of crystallinity. In structures of pitches, the control parameter of the staged structuring process is paramagnetism of condensed aromatic hydrocarbons. Fullerenes were detected in steels and cast irons and identified by various methods of spectrometry and microscopy. Fullerene С60, which contains 60 carbon atoms, has diameter of 0,7 nm and is referred to the nanoscale objects, which have a significant influence on the formation of steel and cast iron properties. It was shown that fullerenes appear at all stages of manufacture of cast irons; they are formed during introduction of carbon from the outside, during crystallization of metal in welded joints. Creation of modified fullerene layers in steels makes it possible to improve anticorrosion and tribological properties of structural materials. At the same time, outside diffusion of carbon from the carbon deposits on the metal surface also leads to formation of additional amount of fullerenes. This creates conditions for occurrence of local microdistortions of the structure, which lead to occurrence of cracks. Distribution of fullerenes in iron matrix is difficult to study as the method is labor-intensive, it requires dissolution of the matrix in the hydrofluoric acid and stage fullerene separation with further identification by spectral methods.

Effect of molybdenum, vanadium, boron on mechanical properties of high chromium white cast iron in as-cast condition

Science.gov (United States)

Nurjaman, F.; Sumardi, S.; Shofi, A.; Aryati, M.; Suharno, B.

2016-02-01

In this experiment, the effect of the addition carbide forming elements on high chromium white cast iron, such as molybdenum, vanadium and boron on its mechanical properties and microstructure was investigated. The high chromium white cast iron was produced by casting process and formed in 50 mm size of grinding balls with several compositions. Characterization of these grinding balls was conducted by using some testing methods, such as: chemical and microstructure analysis, hardness, and impact test. From the results, the addition of molybdenum, vanadium, and boron on high chromium white cast iron provided a significant improvement on its hardness, but reduced its toughness. Molybdenum induced fully austenitic matrix and Mo2C formation among eutectic M7C3 carbide. Vanadium was dissolved in the matrix and carbide. While boron was played a role to form fine eutectic carbide. Grinding balls with 1.89 C-13.1 Cr-1.32 Mo-1.36 V-0.00051 B in as-cast condition had the highest hardness, which was caused by finer structure of eutectic carbide, needle like structure (upper bainite) matrix, and martensite on its carbide boundary.

Cavitation Erosion of Nodular Cast Iron − Microstructural Effects

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Orłowicz A.W.

2017-12-01

Full Text Available The paper deals with susceptibility of nodular cast iron with ferritic-pearlitic matrix on cavitation erosion. Cavitation tests were carried out with the use of a cavitation erosion vibratory apparatus employing a vibration exciter operated at frequency of 20 kHz. The study allowed to determine the sequence of subsequent stages in which microstructure of cast iron in superficial regions is subject to degradation. The first features to be damaged are graphite precipitates. The ferritic matrix of the alloy turned out to be definitely less resistant to cavitation erosion compared to the pearlitic matrix component.

Quality and Safety Assurance of Iron Casts and Manufacturing Processes

OpenAIRE

Kukla S.

2016-01-01

The scope of this work focuses on the aspects of quality and safety assurance of the iron cast manufacturing processes. Special attention was given to the processes of quality control and after-machining of iron casts manufactured on automatic foundry lines. Due to low level of automation and huge work intensity at this stage of the process, a model area was established which underwent reorganization in accordance with the assumptions of the World Class Manufacturing (WCM). An analysis of wor...

Casting Ductile Iron in Layer Moulds Made from Ecological Sands

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M. Rączka

2012-09-01

Full Text Available The article contains the results of tests performed under the target project in Hardtop Foundry Charsznica.The objective of the tests and studies was to develop a technology of making high-quality ductile iron castings, combined witheffective means of environmental protection. The studies presented in this article related to castings weighing from 1 to 300 kg made from ductile iron of grades 400-15 and 500-7, using two-layer moulds, where the facing and core sand was the sand with an alkaline organic binder, while backing sand was the sand with an inorganic geopolymer binder.A simplified method of sand reclamation was applied with possible reuse of the reclaim as an addition to the backing sand. The castiron spheroidising treatment and inoculation were selected taking into account the specific conditions of Hardtop Foundry. A pilot batch of castings was made, testing the gating and feeding systems and using exothermic sleeves on risers. The study confirmed the validity of the adopted concept of making ductile iron castings in layer moulds, while maintaining the content of sand with an organic binder at a level of maximum 15%.

Interesting properties of some iron(II), copper(I) and copper(II ...

Indian Academy of Sciences (India)

Administrator

Tridendate ligands with nitrogen centers, generally well-known as the tripod ligands, have been of considerable interest to inorganic chemists dealing with the preparation of model compounds for hemocyanin, tyrosinase etc. We have found that such ligands when complexed with iron(II) and copper(II) and copper(I) ions ...

Numerical modelling of thin-walled hypereutectic ductile cast iron parts

DEFF Research Database (Denmark)

Pedersen, Karl Martin; Hattel, Jesper Henri; Tiedje, Niels Skat

2006-01-01

Solidification of hypereutectic thin-walled ductile cast iron has been modelled in one dimension taking into account the precipitation of off-eutectic austenite dendrites during solidification. The simulations have been compared with casting experiments on plate geometries with plate thicknesses...

Thermodynamic stability of austenitic Ni-Mn-Cu cast iron

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A. Janus

2014-07-01

Full Text Available The performed research was aimed at determining thermodynamic stability of structures of Ni-Mn-Cu cast iron castings. Examined were 35 alloys. The castings were tempered at 900 °C for 2 hours. Two cooling speeds were used: furnace-cooling and water-cooling. In the alloys with the nickel equivalent value less than 20,0 %, partial transition of austenite to martensite took place. The austenite decomposition ratio and the related growth of hardness was higher for smaller nickel equivalent value and was clearly larger in annealed castings than in hardened ones. Obtaining thermodynamically stable structure of castings requires larger than 20,0 % value of the nickel equivalent.

Role of the preliminary heat treatment in anisothermic eutectoid change of the cast iron

Directory of Open Access Journals (Sweden)

T. Szykowny

2011-07-01

Full Text Available Preliminary heat treatment, preceding continuous cooling of the iron casting, assumed in the research, complies with the applied in prac- tice single normalization, double normalization or normalization with slow cooling. In each of these cases continuous cast iron cooling has been begun from the same temperature 925°C. CCT diagrams have been made with use of metallographic method. The mechanism, kinet- ics and the final structure of eutectoid change of the cast iron after such treatment have been traced.

Application of complex inoculants in improving the process-ability of grey cast iron for cylinder blocks

Directory of Open Access Journals (Sweden)

LIU Wei-ming

2006-05-01

Full Text Available Effect of several complex inoculants on mechanical properties, process-ability and sensibility of grey cast iron used in cylinder block were investigated. The experimental results showed that the grey cast iron treated with 60%FeSi75+40%RE complex inoculants has tensile strength consistently at about 295 MPa along with good hardness and improved metallurgy quality. While the grey cast iron inoculated with 20%FeSi75+80%Sr compound inoculants has the best process-ability, the lowest cross-section sensibility and the least microhardness difference. The wear amount of the drill increases correspondingly with the increase of the microhardness difference of matrix structure, indicating the great effect of homogeneousness of matrix structure in the grey cast iron on the machinability of the grey cast iron.

Effect of Sr on the graphitisation of white cast iron

International Nuclear Information System (INIS)

Taran, Y.N.; Chernovol, A.; Kurepina, V.

2001-01-01

Graphitising annealing is the basis of the production of malleable cast iron. In this case, hypoeutectic low-silicon cast iron with a wide structure I use. A significant role in the precipitation of graphite may be played by the micropores of shrinkage energy and which usually formalism result of insufficient supply and feeding between the dendrite arms of the primary austenite and the eutectic component. The formation of additional graphitisation centres is strongly affected also by the preliminary low-temperature holding (or slow heating)

Influence of Cast Iron Structure on the Glassmold Equipment Operational Defects

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I. O. Leushin

2015-01-01

Full Text Available The growing demand for glass packaging contributes to the increase in production capacity of glass-container plants. Their equipment (cast iron glass-forming sets operates in continuous mode under complex cyclic thermal loads, which lead to the formation of operational defects on the working surfaces of details: graphite falling, cracks, oxidation, etc. Particular influence on the formation of these defects renders the microstructure of the material at the time of installation of details on the line.The article identifies the causes for formation of operational defects, formulates the ways to remedy them and prevent their occurrence.The authors studied details made from grey cast iron with flake and spherical forms of graphite. It is found that in the process of exploitation of the material is greatly reducing its hardness, strength, resistance to oxidation through of graphitization processes, chemical interaction of glass and iron, shock loads working edges. It is proved that the choice of initial microstructure of cast iron (the metal base, the graphite form, the presence of structural-free cementite exercises a determining influence on the durability of the mold tooling. The article proposes differential (layered arrangement of the graphite phase of cast iron in the alloy matrix (ferrite. This arrangement of high-carbon phase can simultaneously increase the thermal and oxidation resistance of the material. The formation of a layered structure of iron is produced by the intensification of the processes of alloying, modifying and directional freezing the melt.These data can be used to select the material of details by manufacturers glass-molds tooling.

Further fields of application for prestressed cast iron pressure vessels (PCIV)

International Nuclear Information System (INIS)

Guelicher, L.; Schilling, F.E.

1977-01-01

The redundancy of the prestressing system of prestressed structures as well as the clear separation of sealing and load-carrying functions of prestressed cast iron pressure vessels offer substantial advantages over conventional welded steel pressure vessels. Because of the temperature resistance of cast iron up to 400 0 C it is possible to build prestressed pressure vessels commercially as hot-working structures. The compressive strength of cast iron, which is 25 times as high as that of concrete allows for a very compact design of the PCIV. Further specific properties of the PCIV like pre-fabrication of the vessel in the production plant - made possible by a structure assembled from segments - short assembly periods at the construction site etc., may open more fields of application. - PCIV as pressurized storage tanks for the emergency shut down system in nuclear power stations. - PCIV as high pressure vessel for the chemical industry. - PCIV as energy storage. - PCIV for light water reactors. - PCIV as burst protection. It is concluded that the application of prestressed cast iron promises to be successful where either structures with large volumes and high pressures and/or temperatures are required or where aspects of safety allow for efficient use of prestressed structures. (Auth.)

Costs Analysis of Iron Casts Manufacturing

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S. Kukla

2012-04-01

Full Text Available The article presents the issues of costs analysis of iron casts manufacturing using automated foundry lines. Particular attention was paid to departmental costs, conversion costs and costs of in-plant transport. After the Pareto analysis had been carried out, it was possible to set the model area of the process and focus on improving activities related to finishing of a chosen group of casts. In order to eliminate losses, the activities realised in this domain were divided into activities with added value, activities with partially added value and activities without added value. To streamline the production flow, it was proposed to change the location of workstations related to grinding, control and machining of casts. Within the process of constant improvement of manufacturing processes, the aspect of work ergonomics at a workstation was taken into account. As a result of the undertaken actions, some activities without added value were eliminated, efficiency was increased and prime costs of manufacturing casts with regard to finishing treatment were lowered.

Growth of Legionella anisa in a model drinking water system to evaluate different shower outlets and the impact of cast iron rust.

Science.gov (United States)

van der Lugt, Wilco; Euser, Sjoerd M; Bruin, Jacob P; Den Boer, Jeroen W; Walker, Jimmy T; Crespi, Sebastian

2017-11-01

Legionella continues to be a problem in water systems. This study investigated the influence of different shower mixer faucets, and the influence of the presence of cast iron rust from a drinking water system on the growth of Legionella. The research is conducted using a model of a household containing four drinking water systems. All four systems, which contained standard plumbing components including copper pipes and a water heater, were filled with unchlorinated drinking water. Furthermore, all systems had three different shower faucets: (A) a stainless-steel faucet, (B) a brass-ceramic faucet, and (C) a brass thermostatic faucet. System 1 was solely filled with drinking water. System 2 was filled with drinking water, and cast iron rust. System 3 was contaminated with Legionella, and system 4 was contaminated with a Legionella, and cast iron rust. During a period of 34 months, 450 cold water samples were taken from 15 sample points of the four drinking water systems, and tested for Legionella according to the Dutch Standard (NEN 6265). In system 4, with added cast iron rust, the stainless-steel mixer faucet (A) had the highest concentration of Legionella at >4.3log10CFU/l (>20,000CFU/l) and was positive in 46.4% of samples. In contrast, the stainless-steel mixer faucet (A) of system 3 without cast iron rust showed 14.3% positive samples with a maximum concentration of 3.9log10CFU/l (7600CFU/l) Legionella. Additionally, both contaminated systems (3 and 4), with the brass thermostatic faucet (C), tested positive for Legionella. System 3 in 85.7% of the samples, with a maximum concentration of 4.38log10CFU/l (24,200CFU/l), and system 4 in 64.3% of the samples with a maximum concentration of 4.13log10CFU/l (13.400CFU/l). These results suggest that both the type of faucet used in a drinking water system and the presence or absence of cast iron rust influence the growth of Legionella. Copyright © 2017 Elsevier GmbH. All rights reserved.

CHANGE OF CONNECTION BETWEEN MAGNETIC PARAMETERS OF CAST IRON IN COMPARISON WITH STEEL UNDER INFLUENCE OF INTERNAL DEMAGNETIZATION

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S. G. Sandomirsky

2014-01-01

Full Text Available Connection of maximum magnetic permeability µm of cast irons with coercive force Нс and residual magnetism Мr is established in all size of changing of the magnetic characteristics of cast iron. Differences of this connection for steels and cast irons are revealed. Formula for calculation µm of steels by Нс and Мr is corrected for calculation µm of cast irons. As a result of correction the calculation error of cast irons µm is diminished. The results can be used in magnetic structural analysis instead of labor-consuming measurement µm.

New developments in high quality grey cast irons

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Iulian Riposan

2014-07-01

Full Text Available The paper reviews original data obtained by the present authors, revealed in recent separate publications, describing specific procedures for high quality grey irons, and reflecting the forecast needs of the worldwide iron foundry industry. High power, medium frequency coreless induction furnaces are commonly used in electric melting grey iron foundries. This has resulted in low sulphur (1,500 °C, contributing to unfavourable conditions for graphite nucleation. Thin wall castings are increasingly produced by these electric melt shops with a risk of greater eutectic undercooling during solidification. The paper focused on two groups of grey cast irons and their specific problems: carbides and graphite morphology control in lower carbon equivalent high strength irons (CE=3.4%-3.8%, and austenite dendrite promotion in eutectic and slightly hypereutectic irons (CE=4.1%-4.5%, in order to increase their strength characteristics. There are 3 stages and 3 steps involving graphite formation, iron chemistry and iron processing that appear to be important. The concept in the present paper sustains a threestage model for nucleating flake graphite [(Mn,XS type nuclei]. There are three important groups of elements (deoxidizer, Mn/S, and inoculant and three technological stages in electric melting of iron (superheat, pre-conditioning of base iron, final inoculation. Attention is drawn to a control factor (%Mn x (%S ensuring it equals to 0.03 – 0.06, accompanied by 0.005wt.%–0.010wt.% Al and/or Zr content in inoculated irons. It was found that iron powder addition promotes austenite dendrite formation in eutectic and slightly eutectic, acting as reinforcement for the eutectic cells. But, there is an accompanying possible negative influence on the characteristics of the (Mn,XS type graphite nuclei (change the morphology of nuclei from polygonal compact to irregular polygonal, and therefore promote chill tendency in treated irons. A double addition (iron

Maintenance system improvement in cast iron foundry

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S. Kukla

2011-07-01

Full Text Available The work presents the issue of technical equipment management in an iron foundry basing on the assumptions of the TPM system (Total Productive Maintenance. Exploitation analysis of automatic casting lines has been carried out and their work’s influence on the whole production system’s functioning has been researched. Within maintenance system improvement, implementation of autonomic service and planned lines’ review have been proposed in order to minimize the time of breakdown stoppages. The SMED method was used to optimize changeover time, and the OEE (Overall Equipment Effectiveness was applied to evaluate the level of resources usage before and after implementing changes. Further, the influence of the maintenance strategy of casting devices’ efficiency on own costs of casting manufac- ture was estimated.

Modelling of solidification processing and continuous strip casting for copper-base alloys

Energy Technology Data Exchange (ETDEWEB)

Mahmoudi, Jafar [Royal Inst. of Tech., Stockholm (Sweden). Dept. of Materials Processing

2000-04-01

An experimental and numerical study was carried out to investigate the solidification process in a copper continuous strip casting process. Heat flow and solidification process has been experimentally studied. Cooling curves during solidification were registered using a thermocouple of type K connected to a data acquisition system. Temperature measurements in the mould and cooling water were also performed. The numerical model considers a generalized set of mass, momentum and heat equations that is valid for the solid, liquid and solidification interval in the cast. A k-{epsilon} turbulence model, produced with the commercial program CFX, is used to analyse the solidification process of pure copper in the mould region of the caster. The fluid flow, temperature and heat flux distributions in the mould region of the caster were computed. The shape and location of the solidification front were also determined. The effects of the parameters such as heat transfer coefficient, casting speed, casting temperature, heat of fusion and specific heat on the shape and location of the solidification front and the heat transport at the mould-cast interface were investigated. The predicted temperature and heat flux distributions were compared with experimental measurements, and reasonable agreement was obtained. The solidification behaviour of pure copper and different copper base alloys has been studied. A series of solidification experiments using DTA furnace, mirror furnace and levitation technique were performed on different copper-base alloys. The undercooling, cooling rates of the liquid and the solid states, solidification times and temperatures were evaluated from the curves. The cooling curves for different samples were simulated using a FEM solidification program. It was found that the calculated values of the heat of fusion were much lower than the tabulated ones. The fraction of solid formed before quenching, in the DTA experiments, has been observed to be much higher

Structural and compositional analysis of a casting mold sherd from ancient China.

Science.gov (United States)

Zong, Yunbing; Yao, Shengkun; Lang, Jianfeng; Chen, Xuexiang; Fan, Jiadong; Sun, Zhibin; Duan, Xiulan; Li, Nannan; Fang, Hui; Zhou, Guangzhao; Xiao, Tiqiao; Li, Aiguo; Jiang, Huaidong

2017-01-01

Casting had symbolic significance and was strictly controlled in the Shang dynasty of ancient China. Vessel casting was mainly distributed around the Shang capital, Yin Ruins, which indicates a rigorous centralization of authority. Thus, for a casting mold to be excavated far from the capital region is rare. In addition to some bronze vessel molds excavated at the Buyao Village site, another key discovery of a bronze vessel mold occurred at Daxinzhuang. The Daxinzhuang site was a core area in the east of Shang state and is an important site to study the eastward expansion of the Shang. Here, combining synchrotron X-rays and other physicochemical analysis methods, nondestructive three-dimensional structure imaging and different elemental analyses were conducted on this mold sherd. Through high penetration X-ray tomography, we obtained insights on the internal structure and discovered some pores. We infer that the generation of pores inside the casting mold sherd was used to enhance air permeability during casting. Furthermore, we suppose that the decorative patterns on the surface were carved and not pasted onto it. Considering the previous compositional studies of bronze vessels, the copper and iron elements were analyzed by different methods. Unexpectedly, a larger amount of iron than of copper was detected on the surface. According to the data analysis and archaeological context, the source of iron on the casting mold sherd could be attributed to local soil contamination. A refined compositional analysis confirms that this casting mold was fabricated locally and used for bronze casting.

Structural and compositional analysis of a casting mold sherd from ancient China.

Directory of Open Access Journals (Sweden)

Yunbing Zong

Full Text Available Casting had symbolic significance and was strictly controlled in the Shang dynasty of ancient China. Vessel casting was mainly distributed around the Shang capital, Yin Ruins, which indicates a rigorous centralization of authority. Thus, for a casting mold to be excavated far from the capital region is rare. In addition to some bronze vessel molds excavated at the Buyao Village site, another key discovery of a bronze vessel mold occurred at Daxinzhuang. The Daxinzhuang site was a core area in the east of Shang state and is an important site to study the eastward expansion of the Shang. Here, combining synchrotron X-rays and other physicochemical analysis methods, nondestructive three-dimensional structure imaging and different elemental analyses were conducted on this mold sherd. Through high penetration X-ray tomography, we obtained insights on the internal structure and discovered some pores. We infer that the generation of pores inside the casting mold sherd was used to enhance air permeability during casting. Furthermore, we suppose that the decorative patterns on the surface were carved and not pasted onto it. Considering the previous compositional studies of bronze vessels, the copper and iron elements were analyzed by different methods. Unexpectedly, a larger amount of iron than of copper was detected on the surface. According to the data analysis and archaeological context, the source of iron on the casting mold sherd could be attributed to local soil contamination. A refined compositional analysis confirms that this casting mold was fabricated locally and used for bronze casting.

Tissue levels of iron, copper, zinc and magnesium in iron deficient rats

African Journals Online (AJOL)

The effects of iron deficiency on the levels of iron, copper, zinc and magnesium in the brain, liver, kidney, heart and lungs of albino rats (Rattus novergicus) was investigated. Forty rats were divided into two groups and the first group was fed a control diet containing 1.09g iron/kg diet while the test group was fed diet ...

Laser surface treatment of grey cast iron for automotive applications

NARCIS (Netherlands)

Ocelik, V.; Tang, P.N.; de Boer, M.C.; de Oliveira, U.; de Hosson, J.T.M.; DeHosson, JTM; Brebbia, CA; Nishida, SI

2005-01-01

The surface of pearlitic grey cast iron was treated using a 2 kW Nd:YAG laser beam with the final aim to improve its surface properties, mainly for automotive applications. Two kinds of laser surface treatments were experimentally applied. In the laser surface hardening approach the surface of cast

The effect of pearlite on the hydrogen-induced ductility loss in ductile cast irons

Science.gov (United States)

Matsuo, T.

2017-05-01

Hydrogen energy systems, such as a hydrogen fuel cell vehicle and a hydrogen station, are rapidly developing to solve global environmental problems and resource problems. The available structural materials used for hydrogen equipments have been limited to only a few relatively expensive metallic materials that are tolerant for hydrogen embrittlement. Therefore, for the realization of a hydrogen society, it is important to expand the range of materials available for hydrogen equipment and thereby to enable the use of inexpensive common materials. Therefore, ductile cast iron was, in this study, focused as a structural material that could contribute to cost reduction of hydrogen equipment, because it is a low-cost material having good mechanical property comparable to carbon steels in addition to good castability and machinability. The strength and ductility of common ductile cast irons with a ferritic-pearlitic matrix can be controlled by the volume fraction of pearlitic phase. In the case of carbon steels, the susceptibility to hydrogen embrittlement increases with increase in the pearlite fraction. Toward the development of ferritic-pearlitic ductile cast iron with reasonable strength for hydrogen equipment, it is necessary to figure out the effect of pearlite on the hydrogen embrittlement of this cast iron. In this study, the tensile tests were conducted using hydrogen-precharged specimens of three kinds of ferritic-pearlitic ductile cast irons, JIS-FCD400, JIS-FCD450 and JIS-FCD700. Based on the results, the role of pearlite in characterizing the hydrogen embrittlement of ductile cast iron was discussed.

Development of Nanostructured Austempered Ductile Cast Iron

Science.gov (United States)

Panneerselvam, Saranya

Austempered Ductile Cast Iron is emerging as an important engineering materials in recent years because of its excellent combination of mechanical properties such as high strength with good ductility, good fatigue strength and fracture toughness together with excellent wear resistance. These combinations of properties are achieved by the microstructure consisting of acicular ferrite and high carbon austenite. Refining of the ausferritic microstructure will further enhance the mechanical properties of ADI and the presence of proeutectoid ferrite in the microstructure will considerably improve the ductility of the material. Thus, the focus of this investigation was to develop nanostructured austempered ductile cast iron (ADI) consisting of proeutectoid ferrite, bainitic ferrite and high carbon austenite and to determine its microstructure-property relationships. Compact tension and cylindrical tensile test samples were prepared as per ASTM standards, subjected to various heat treatments and the mechanical tests including the tensile tests, plane strain fracture toughness tests, hardness tests were performed as per ASTM standards. Microstructures were characterized by optical metallography, X-ray diffraction, SEM and TEM. Nanostructured ADI was achieved by a unique heat treatment consisting of austenitization at a high temperature and subsequent plastic deformation at the same austenitizing temperature followed by austempering. The investigation also examined the effect of cryogenic treatment, effect of intercritical austenitizing followed by single and two step austempering, effect of high temperature plastic deformation on the microstructure and mechanical properties of the low alloyed ductile cast iron. The mechanical and thermal stability of the austenite was also investigated. An analytical model has been developed to understand the crack growth process associated with the stress induced transformation of retained austenite to martensite.

Modelling the solidification of ductile cast iron parts with varying wall thicknesses

DEFF Research Database (Denmark)

Bjerre, Mathias Karsten; Tiedje, Niels Skat; Thorborg, Jesper

2015-01-01

] with a 2D FE solution of the heat conduction equation is developed in an in-house code and model parameters are calibrated using experimental data from representative castings made of ductile cast iron. The main focus is on the influence of casting thickness and resulting local cooling conditions...

TO SELECTION OF TECHNOLOGICAL SCHEME OF SOFTENING HEAT TREATMENT FOR HIGH CHROMIUM CAST IRON

Directory of Open Access Journals (Sweden)

V. G. Efremenko

2014-03-01

Full Text Available Purpose. High chromium cast irons with austenitic matrix have low machinability. The aim of work is search of new energy-saving modes of preliminary softening heat treatment enhancing the machinability of castings by forming an optimum microstructure. Methodology. Metallographic analysis, hardness testing and machinability testing are applied. Findings. It was found out that high temperature annealing with continuous cooling yields to martensite-austenite matrix in cast iron 270Х15Г2Н1MPhT, which abruptly affects the machinability of cast iron. Significant improvement of machinability is achieved by forming of structure "ferrite + granular carbides" and by decline of hardness to 37-39 HRC in the case of two-stage isothermal annealing in the subcritical temperature range or by the use of quenching and tempering (two-step or cyclic. Originality. It was found that the formation of the optimal structure of the matrix and achievement of desired hardness level needed for improving machinability of high chromium cast iron containing 3 % austenite-forming elements, can be obtained: 1 due to pearlite original austenite followed by spherodization eutectoid carbides, and 2 by getting predominantly martensite structure followed by the decay of martensite and carbides coagulation at high-temperature tempering. Practical value. The new energy-saving schemes of softening heat treatment to ensure the growth of machinability of high chromium cast iron, alloyed by higher quantity of austenite forming elements, are proposed.

The microstructure of steels and cast irons. History and interpretation

International Nuclear Information System (INIS)

Durand-Charre, M.

2003-01-01

The microstructure of steels and cast irons is a monograph on the history and interpretation of the microstructure of steels and iron alloys. Its 400 pages are illustrated by a lot of micrographies of commercial alloys or model alloys at each the available scales with the modern investigations means of electronic microscopy and the optical macro/microscopy. The first part of this book is an historical introduction on the development of the metallurgical structures manually forged for the iron knowledge, in particular the famous structures called damask. The second part of this book deals with the fundamental notions in order to give all the reasoning bases required on the phases equilibria and the transformations kinetics. Concerning the phases equilibria, a lot of diagrams are included. The reading of ternary systems is analyzed for six systems representative of the reactions encountered in steels, Fe-Cr-C, Fe-Ni-Cr, Fe-Mn-S, Fe-Co-Cu, Fe-Mo-Cr and Fe-C-V. The solidification structures are studied through all the classical cases but in others too as the markings of peritectic or metatectic reactions or transformations in series. Solid phases transformations are illustrated and commented with recent interpretations, in particular in the case of bainitic structures. A lot of references allow to deepen the non developed aspects. The third part is a guide to understand and discuss on scientific bases the role of alloy elements and those of different specific treatments resulting to the optimisation of steels and iron casts, to define the micrographic characteristics in relation with the use properties. Steels are classified in series for the very low alloy steels to steels with high amounts in alloy elements resulting of a very fine composition adjustment. Cast irons are presented naturally according to their microstructure, classified in white irons, lamellar grey and nodular irons. (O.M.)

Integrated System of Thermal/Dimensional Analysis for Quality Control of Metallic Melt and Ductile Iron Casting Solidification

Science.gov (United States)

Stan, Stelian; Chisamera, Mihai; Riposan, Iulian; Neacsu, Loredana; Cojocaru, Ana Maria; Stan, Iuliana

2018-03-01

The main objective of the present work is to introduce a specific experimental instrument and technique for simultaneously evaluating cooling curves and expansion or contraction of cast metals during solidification. Contraction/expansion analysis illustrates the solidification parameters progression, according to the molten cast iron characteristics, which are dependent on the melting procedure and applied metallurgical treatments, mold media rigidity and thermal behavior [heat transfer parameters]. The first part of the paper summarizes the performance of this two-mold device. Its function is illustrated by representative shrinkage tendency results in ductile cast iron as affected by mold rigidity (green sand and furan resin sand molds) and inoculant type (FeSi-based alloys), published in part previously. The second part of the paper illustrates an application of this equipment adapted for commercial foundry use. It conducts thermal analysis and volume change measurements in a single ceramic cup so that mold media as well as solidification conditions are constants, with cast iron quality as the variable. Experiments compared gray and ductile cast iron solidification patterns. Gray iron castings are characterized by higher undercooling at the beginning and at the end of solidification and lower graphitic expansion. Typically, ductile cast iron exhibits higher graphitic, initial expansion, conducive for shrinkage formation in soft molds.

Quality and Safety Assurance of Iron Casts and Manufacturing Processes

Directory of Open Access Journals (Sweden)

Kukla S.

2016-06-01

Full Text Available The scope of this work focuses on the aspects of quality and safety assurance of the iron cast manufacturing processes. Special attention was given to the processes of quality control and after-machining of iron casts manufactured on automatic foundry lines. Due to low level of automation and huge work intensity at this stage of the process, a model area was established which underwent reorganization in accordance with the assumptions of the World Class Manufacturing (WCM. An analysis of work intensity was carried out and the costs were divided in order to identify operations with no value added, particularly at individual manufacturing departments. Also an analysis of ergonomics at work stations was carried out to eliminate activities that are uncomfortable and dangerous to the workers' health. Several solutions were proposed in terms of rationalization of work organization at iron cast after-machining work stations. The proposed solutions were assessed with the use of multi-criteria assessment tools and then the best variant was selected based on the assumed optimization criteria. The summary of the obtained results reflects benefits from implementation of the proposed solutions.

The surface layer of austempered ductile iron investment castings properties

Directory of Open Access Journals (Sweden)

D. Myszka

2009-01-01

Full Text Available The article presents a unique process of carbonnitriding and nitriding the precision casting surfaces of austempered ductile iron. The results of the research are pointing that adequate process parameters allow to obtain multiple increase of wear resistance and a significant increase of corrosion resistance. Also, changes of cast microstructure and hardness are presented.

Effect of vibration frequency on microstructure and performance of high chromium cast iron prepared by lost foam casting

Directory of Open Access Journals (Sweden)

Wen-qi Zou

2016-07-01

Full Text Available In the present research, high chromium cast irons (HCCIs were prepared using the lost foam casting (LFC process. To improve the wear resistance of the high chromium cast irons (HCCIs, mechanical vibration was employed during the solidification of the HCCIs. The effects of vibration frequency on the microstructure and performance of the HCCIs under as-cast, as-quenched and as-tempered conditions were investigated. The results indicated that the microstructures of the LFC-produced HCCIs were refined due to the introduction of mechanical vibration, and the hardness was improved compared to that of the alloy without vibration. However, only a slight improvement in hardness was found in spite of the increase of vibration frequency. In contrast, the impact toughness of the as-tempered HCCIs increased with an increase in the vibration frequency. In addition, the wear resistance of the HCCIs was improved as a result of the introduction of vibration and increased with an increase in the vibration frequency.

The Effect of Ductile Cast Iron Matrix on Zinc Coating During Hot Dip Galvanising of Castings

Directory of Open Access Journals (Sweden)

D. Kopyciński

2012-12-01

Full Text Available The growth kinetics of the zinc coating formed on the surface of casting made from ductile iron grade EN-GJS-500-3 was investigated. To produce homogenous metal matrix in test samples, the normalising and ferritising annealing was carried out. Studies showeda heterogeneous structure of cast iron with varying content of the phases formed. This was followed by hot dip galvanising treatment at450°C to capture the growth kinetics of the zinc coating (the time of the treatment ranged from 60 to 600 seconds. Nonlinear estimation of the determined growth kinetics of the alloyed layer of a zinc coating was made and an equation of the zinc coating growth was derived.Based on the results of the investigations it was concluded that thickness of the zinc coating formed on the surface of casting with a 100% pearlitic matrix makes 55% of the thickness of coating formed on the surface in 100% ferritic.

The Effect of Ductile Cast Iron Matrix on Zinc Coating During Hot Dip Galvanising of Castings

Directory of Open Access Journals (Sweden)

Kopyciński D.

2012-12-01

Full Text Available The growth kinetics of the zinc coating formed on the surface of casting made from ductile iron grade EN-GJS-500-3 was investigated. To produce homogenous metal matrix in test samples, the normalising and ferritising annealing was carried out. Studies showed a heterogeneous structure of cast iron with varying content of the phases formed. This was followed by hot dip galvanising treatment at 450°C to capture the growth kinetics of the zinc coating (the time of the treatment ranged from 60 to 600 seconds. Nonlinear estimation of the determined growth kinetics of the alloyed layer of a zinc coating was made and an equation of the zinc coating growth was derived. Based on the results of the investigations it was concluded that thickness of the zinc coating formed on the surface of casting with a 100% pearlitic matrix makes 55% of the thickness of coating formed on the surface in 100% ferritic.

Draft ASME code case on ductile cast iron for transport packaging

International Nuclear Information System (INIS)

Saegusa, T.; Arai, T.; Hirose, M.; Kobayashi, T.; Tezuka, Y.; Urabe, N.; Hueggenberg, R.

2004-01-01

The current Rules for Construction of ''Containment Systems for Storage and Transport Packagings of Spent Nuclear Fuel and High Level Radioactive Material and Waste'' of Division 3 in Section III of ASME Code (2001 Edition) does not include ductile cast iron in its list of materials permitted for use. The Rules specify required fracture toughness values of ferritic steel material for nominal wall thickness 5/8 to 12 inches (16 to 305 mm). New rule for ductile cast iron for transport packaging of which wall thickness is greater than 12 inches (305mm) is required

A study on the effects of artifacts on fatigue limit of ductile cast iron with ferritic structure

International Nuclear Information System (INIS)

Kim, Jin Hak; Kim, Min Gun

2000-01-01

In this study, fatigue tests were performed to examine the effects of micro drill hole on fatigue limit of as cast and Austempered Ductile cast Iron (ADI) using the rotary bending fatigue tester. As results, micro drill holes (diameter≤0.4mm) did not influence the fatigue limit of ADI, compared to annealed ductile cast iron; the critical defect size of crack initiation, in ADI was larger than as cast. If the √areas of micro drill hole and graphite nodule in ADI are comparable, crack initiates at the graphite nodule. When the ruggedness develops through austempering treatment process, microstructure on crack initiation at micro drill hole is tougher than that of as cast ductile cast iron

Carbides in Nodular Cast Iron with Cr and Mo

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S. Pietrowski

2007-07-01

Full Text Available In these paper results of elements microsegregation in carbidic nodular cast iron have been presented. A cooling rate in the centre of the cross-section and on the surface of casting and change of moulding sand temperature during casting crystallization and its self-cooling have been investigated. TDA curves have been registered. The linear distribution of elements concentration in an eutectic grain, primary and secondary carbides have been made. It was found, that there are two kinds of carbides: Cr and Mo enriched. A probable composition of primary and secondary carbides have been presented.

Graphite nodules in fatigue-tested cast iron characterized in 2D and 3D

DEFF Research Database (Denmark)

Mukherjee, Krishnendu; Fæster, Søren; Hansen, Niels

2017-01-01

Thick-walled ductile iron casts have been studied by applying (i) cooling rate calculations by FVM, (ii) microstructural characterization by 2D SEM and 3D X-ray tomography techniques and (iii) fatigue testing of samples drawn from components cast in sand molds and metal molds. An analysis has shown...... correlations between cooling rate, structure and fatigue strengths demonstrating the benefit of 3D structural characterization to identify possible causes of premature fatigue failure of ductile cast iron....

Impairment of Interrelated Iron- and Copper Homeostatic Mechanisms in Brain Contributes to the Pathogenesis of Neurodegenerative Disorders

Science.gov (United States)

Skjørringe, Tina; Møller, Lisbeth Birk; Moos, Torben

2012-01-01

Iron and copper are important co-factors for a number of enzymes in the brain, including enzymes involved in neurotransmitter synthesis and myelin formation. Both shortage and an excess of iron or copper will affect the brain. The transport of iron and copper into the brain from the circulation is strictly regulated, and concordantly protective barriers, i.e., the blood-brain barrier (BBB) and the blood-cerebrospinal fluid (CSF) barrier (BCB) have evolved to separate the brain environment from the circulation. The uptake mechanisms of the two metals interact. Both iron deficiency and overload lead to altered copper homeostasis in the brain. Similarly, changes in dietary copper affect the brain iron homeostasis. Moreover, the uptake routes of iron and copper overlap each other which affect the interplay between the concentrations of the two metals in the brain. The divalent metal transporter-1 (DMT1) is involved in the uptake of both iron and copper. Furthermore, copper is an essential co-factor in numerous proteins that are vital for iron homeostasis and affects the binding of iron-response proteins to iron-response elements in the mRNA of the transferrin receptor, DMT1, and ferroportin, all highly involved in iron transport. Iron and copper are mainly taken up at the BBB, but the BCB also plays a vital role in the homeostasis of the two metals, in terms of sequestering, uptake, and efflux of iron and copper from the brain. Inside the brain, iron and copper are taken up by neurons and glia cells that express various transporters. PMID:23055972

Solubility of Hydrogen and Nitrogen in liquid cast iron during melting and mold filling

OpenAIRE

Diószegi, Attila; Elfsberg, Jessica; Diószegi, Zoltán

2016-01-01

Defect formation like gas- and shrinkage porosity at cast iron component production is related to the content of gaseous elements in the liquid metal. The present work investigate the solubility of hydrogen and nitrogen in liquid iron aimed for production of lamellar and compacted graphite cast iron. The used methods and instruments are a combination of commercial measuring devices and novel experimental assemblies for measuring solubility of hydrogen and nitrogen during melting and mold fill...

Undercooling, nodule count and carbides in thin walled ductile cast iron

DEFF Research Database (Denmark)

Pedersen, Karl Martin; Tiedje, Niels Skat

2008-01-01

Ductile cast iron has been cast in plate thicknesses between 2 to 8 mm. The temperature has been measured during the solidification and the graphite nodule count and size distribution together with the type and amount of carbides have been analysed afterwards. Low nodule count gives higher...

Energy Saving Melting and Revert Reduction Technology: Aging of Graphitic Cast Irons and Machinability

Energy Technology Data Exchange (ETDEWEB)

Richards, Von L. [Advanced Technology Inst., Virginia Beach, VA (United States)

2012-09-19

The objective of this task was to determine whether ductile iron and compacted graphite iron exhibit age strengthening to a statistically significant extent. Further, this effort identified the mechanism by which gray iron age strengthens and the mechanism by which age-strengthening improves the machinability of gray cast iron. These results were then used to determine whether age strengthening improves the machinability of ductile iron and compacted graphite iron alloys in order to develop a predictive model of alloy factor effects on age strengthening. The results of this work will lead to reduced section sizes, and corresponding weight and energy savings. Improved machinability will reduce scrap and enhance casting marketability. Technical Conclusions: Age strengthening was demonstrated to occur in gray iron ductile iron and compacted graphite iron. Machinability was demonstrated to be improved by age strengthening when free ferrite was present in the microstructure, but not in a fully pearlitic microstructure. Age strengthening only occurs when there is residual nitrogen in solid solution in the Ferrite, whether the ferrite is free ferrite or the ferrite lamellae within pearlite. Age strengthening can be accelerated by Mn at about 0.5% in excess of the Mn/S balance Estimated energy savings over ten years is 13.05 trillion BTU, based primarily on yield improvement and size reduction of castings for equivalent service. Also it is estimated that the heavy truck end use of lighter castings for equivalent service requirement will result in a diesel fuel energy savings of 131 trillion BTU over ten years.

Thermal distortion of disc-shaped ductile iron castings in vertically parted moulds

DEFF Research Database (Denmark)

Vedel-Smith, Nikolaj Kjelgaard; Rasmussen, Jakob; Tiedje, Niels Skat

2015-01-01

A disc-shaped casting with an inner boss and an outer rim, separated by a thin walled section, was examined. This measurable deformation varied with the feeding modulus. The influence of alloy composition, particularly Si content, was examined with a pearlitic ductile iron (EN-GJS-500-7) and a fu......A disc-shaped casting with an inner boss and an outer rim, separated by a thin walled section, was examined. This measurable deformation varied with the feeding modulus. The influence of alloy composition, particularly Si content, was examined with a pearlitic ductile iron (EN-GJS-500......-7) and a fully ferritic ductile iron (EN-GJS-450-10). The experiment showed that both the alloy composition and choice of feeder influenced the degreeof deformation measured in the finished casting. It was found that the deformation of the pearlitic alloy was influenced controllably by changing the feeder...

Interface Structure and Elements Diffusion of As-Cast and Annealed Ductile Iron/Stainless Steel Bimetal Castings

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M. Ramadan

2018-04-01

Full Text Available Bimetal casting is considered to a promising technique for the production of high performance function materials. Heat treatment process for bimetal castings became an essential tool for improving interface structure and metallurgical diffusion bond. Molten iron alloy with carbon equivalent of 4.40 is poured into sand mold cavities containing solid 304 stainless steel strips insert. Specimens are heated to 7200C in an electrical heating furnace and holded at 720 0C for 60min and 180min. For as-cast specimens, a good coherent interface structure of ductile cast iron/304 stainless bimetal with four layers interfacial microstructure are obtained. Low temperature annealing at 720oC has a significat effect on the interface layers structure, where, three layers of interface structure are obtained after 180min annealing time because of the complete dissolving of thin layer of ferrite and multi carbides (Layer 2. Low temperature annealing shows a significant effect on the diffusion of C and otherwise shows slightly effect on the diffusion of Cr and Ni. Plearlite phase of Layer 3 is trsformed to spheroidal shape instead of lamallar shape in as-cast bimetals by low tempeature annealing at 720oC. The percent of the performed spheroidal cementit increases by increasing anneaaling time. Hardness of interface layers is changed by low temperauture annealing due to the significant carbon deffussion.

The Tendencies of Piece Casting from Modified Irons

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Cinca Ionel Lupinca

2010-10-01

Full Text Available In this paper we have presented the metalographic studies made on the grey cast irons treated with complex modifying substances, type FeSiMgRE (Mg alloy and their influence on the compactness degree of graphite separations. For research and experiments, a melt of grey iron was produced in an induction furnace of a capacity of 5to, starting with a metallic charge made from 100% synthetic pig iron. We realized eight practical charge made modification, by using different combinations of modifying substance and in different concentrations. The addition of carbon to the melt was performed using electrode graphite powder in the metallic charge.

Mapping of mechanical properties of cast iron melts using non-destructive structuroscopy

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J. Dočekal

2008-07-01

Full Text Available The contribution is focused on mapping of mechanical properties using methods of non-destructive structuroscopy of cast irons, which are a result of research at TU of Liberec and Institute of Physics of ASCR. Investigated samples become from melts of FOCAM s.r.o Olomouc Foundry shop. It compares data of mechanical properties obtained using ultrasound method with data from magnetic spot method and MAT. These are interpreted by mathematic models applicable in practice. In the following it concerns to derivation of loading tensile curve method, which can be used to obtain yield and fatigue strength limits even for cast irons with flake graphite. In spite of promising results reported by literature the experiments are bothered with error. This method can be applied to structure checking both before casting and at vendor inspection of castings.

An approach for the fatigue estimation of porous cast iron based on non-destructive testing results

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Heinrietz André

2014-06-01

Full Text Available Big cast iron components made of spheroidal cast iron allow constructing big structures such as stone mills, engine blocks or wind mills with acceptable expenses. Thus, in economically optimized cast processes pores cannot be always prevented in thick walled cast iron components and these components are often rejected because of safety reasons. On the one hand the fatigue performance of high loadable spheroidal cast iron components is reduced significantly by the presence of local porosities which has been pointed out in the past. On the other hand concepts for the fatigue estimation based on fracture mechanics which take the size and localization of the defect into account can lead to erroneous estimations because the defect is modelled as a crack. The challenge of an estimation method is to derive a fatigue life without the necessity to perform component tests. In the contribution an estimation method is presented which is able to determine the fatigue strength of a material volume taking the pores into account. The method can be applied based on data from computer tomographic X-ray (CT or Sampling Phased Array (SPA ultrasonic analyses. The method is presented for three spheroidal cast iron types: ferritic GJS-400-18, ferritic GJS-450-15 with high silicon content and perlitic GJS-700-3.

Application of welding technology TIG to cast iron repair

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J. Szajnar

2008-03-01

Full Text Available Rcpnir nT cnst imn clcrncnts rcaEi7c in ordcr to cut out a sltpcrficial casting dcfcc~s, Dcrccis clccrcasc ;z usahiliny nt ca~rings torconsin~ciionaal pplication m d incrcasc a manufacturing costs. Thc pnpcr prcsclrls rcscarch rcsufts or itsc o r '1'IG - Tun~stcnI ncn Gas alsokncwn RS GTA - Gas Tunpstcn Arc surfacin: hy wclding on colt1 and half-hot to rcpnls chrninil~m cnsr iron EN-GJN-XCrlS withcliro~niurnc ontcnt nhout 3 5% and nodular ({vi~hF crritic-pcarli~ic matrix cast iron EN-GJS-500-7. Thc rcsttl~o r invcsiigations showpossibility of cns~ings rcpais hy put on derccts a good quality padding wclds, which havc compamhlc nr hcricr propcrtlcs than hnsc~naicrial.

On Degradation of Cast Iron Surface-Protective Paint Coat Joint

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Tupaj M.

2016-09-01

Full Text Available The paper is a presentation of a study on issues concerning degradation of protective paint coat having an adverse impact on aesthetic qualities of thin-walled cast-iron castings fabricated in furan resin sand. Microscopic examination and microanalyses of chemistry indicated that under the coat of paint covering the surface of a thin-walled casting, layers of oxides could be found presence of which can be most probably attributed to careless cleaning of the casting surface before the paint application process, as well as corrosion pits evidencing existence of damp residues under the paint layers contributing to creation of corrosion micro-cells

Microstructure, Tensile Strength and Probabilistic Fatigue Life Evaluation of Gray Cast Iron

Energy Technology Data Exchange (ETDEWEB)

Sung, Yong Hyeon; Han, Seung-Wook; Choi, Nak-Sam [Hanyang Univ., Seoul (Korea, Republic of)

2017-08-15

High-grade gray cast iron (HCI350) was prepared by adding Cr, Mo and Cu to the gray cast iron (GC300). Their microstructure, mechanical properties and fatigue strength were studied. Cast iron was made from round bar and plate-type castings, and was cut and polished to measure the percentage of each microstructure. The size of flake graphite decreased due to additives, while the structure of high density pearlite increased in volume percentage improving the tensile strength and fatigue strength. Based on the fatigue life data obtained from the fatigue test results, the probability - stress - life (P-S-N) curve was calculated using the 2-parameter Weibull distribution to which the maximum likelihood method was applied. The P-S-N curve showed that the fatigue strength of HCI350 was significantly improved and the dispersion of life data was lower than that of GC300. However, the fatigue life according to fatigue stress alleviation increased further. Data for reliability life design was presented by quantitatively showing the allowable stress value for the required life cycle number using the calculated P-S-N curve.

Determination of iron and copper contents in certain indigenous varieties of wheat (Triticum aestivum, L.)

International Nuclear Information System (INIS)

Akhtar, M.S.; Abbas, N.; Shaheen, A.

2004-01-01

Forty seven wheat varieties were tested for their iron and copper contents. The iron and copper contents were found to differ significantly (P 0.05) with respect to iron and copper contents. The variety named Dirk was found to possess the highest iron contents, while the variety Pasban-90 showed the highest copper contents. The varieties Dirk, Sariab, Tandojam-83, Punjab-88, Sarsabz, Punjab-81, Sandal and Sind-81 contained significantly higher iron contents as compared to other wheat varieties. The varieties, which contained the highest concentrations of copper, were Pasban-90, Chenab-79, Faisalabad-85, Lyp-73, Sind-81, Anmol-91, C-271, Rohtas-90 and Chakwal-86. However, the differences in copper contents among all these wheat varieties were non-significant (P>0.05). These varieties can therefore, be recommended to be included for future breeding and commercial exploitation. (author)

Structure fields in the solidifying cast iron roll

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W.S. Wołczyński

2010-01-01

Full Text Available Some properties of the rolls depend on the ratio of columnar structure area to equiaxed structure area created during roll solidification. The transition is fundamental phenomenon that can be apply to characterize massive cast iron rolls produced by the casting house. As the first step of simulation, a temperature field for solidifying cast iron roll was created. The convection in the liquid is not comprised since in the first approximation, the convection does not influence the studied occurrence of the (columnar to equiaxed grains transition in the roll. The obtained temperature field allows to study the dynamics of its behavior observed in the middle of the mould thickness. This midpoint of the mould thickness was treated as an operating point for the transition. A full accumulation of the heat in the mould was postulated for the transition. Thus, a plateau at the curve was observed at the midpoint. The range of the plateau existence corresponded to the incubation period , that appeared before fully equiaxed grains formation. At the second step of simulation, behavior of the thermal gradients field was studied. Three ranges within the filed were visible: EC→EC→EC→EC→(tTECtt↔RERCtt↔a/ for the formation of columnar structure (the C – zone: ( and 0>>T&0>>=−>−=REREttGttG.The columnar structure formation was significantly slowed down during incubation period. It resulted from a competition between columnar growth and equiaxed growth expected at that period of time. The 0≈=−=RERCttGttG relationship was postulated to correspond well with the critical thermal gradient, known in the Hunt’s theory. A simulation was performed for the cast iron rolls solidifying as if in industrial condition. Since the incubation divides the roll into two zones: C and E; (the first with columnar structure and the second with fully equiaxed structure some experiments dealing with solidification were made on semi-industrial scale.

ASSESSMENT OF RANGES OF POSSIBLE CHANGE OF TEMPORARY RESISTANCE OF CAST IRON WITH LAMELLAR AND FLAKED GRAPHITE ON THEIR HARDNESS

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S. G. Sandomirskii

2017-01-01

Full Text Available The analysis of ranges of possible change of temporary resistance of sB of castings from ductile and gray cast iron is carried out. The analytical description of ranges of change of sВ depending on casting BH hardness is developed. It is shown that the range of change of sВ of pig-iron castings, wider in comparison with steel, with the measured hardness of BH is caused variations of forms and the amount of graphite inclusions at the considered classes of cast iron and influence of thickness of a wall of casting from gray cast iron on dependence of sВ (HB. The result is intended for determination of the guaranteed casting size sВ without her destruction, when there is no information on sВ of check test pieces.

Sintering studies on iron-carbon-copper compacts

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Perianayagam Philomen-D-Anand Raj

2016-01-01

Full Text Available Sintered Iron-Carbon-Copper parts are among the most widely used powder metallurgy product in automobile. In this paper, studies have been carried out to find out the sintering characteristics of iron-carbon-copper compacts when sintered in nitrogen atmosphere. The effects of various processing parameters on the sintering characteristics were studied. The various processing parameters considered were compaction pressure, green density and sintering temperature. The sintering characteristics determined were sintered density, porosity, dimensional change, micro hardness and radial crush strength. The results obtained have been discussed on the basis of micro structural observations. The characteristics of SEM fractography were also used to determine the mechanism of fracture. The fracture energy is strongly dependent on density of the compact.

ASME codification of ductile cast iron cask for transport and storage of spent nuclear fuel

International Nuclear Information System (INIS)

Saegusa, Toshiari; Arai, Taku

2012-01-01

The CRIEPI has been executing research and development on ductile cast iron cask for transport and storage of spent nuclear fuel in order to diversify options of the casks. Based on the research results, the CRIEPI proposed materials standards (Section II) and structural design standards (Section III) for the ductile cast iron cask to the authoritative and international ASME (American Society of Mechanical Engineers) Codes. For the Section II, the CRIEPI proposed the JIS G 5504 material with additional requirement prohibiting repair of cast body by welding, etc. as well as the ASTM A874 material to the Part A. In addition, the CRIEPI proposed design stress allowables, physical properties (thermal conductivity, modulus of elasticity, etc.), and external pressure chart to the Part D. For the Section III, the CRIEPI proposed a fracture toughness requirement of the ductile cast iron cask at -40degC to WB and WC of Division 3. Additionally, the CRIEPI proposed a design fatigue curve of the ductile cast iron cask to Appendix of Division 1. This report describes the outline of the proposed standards, their bases, and the deliberation process in order to promote proper usage of the code, future improvement, etc. (author)

In situ observations of graphite formation during solidification of cast iron

DEFF Research Database (Denmark)

Bjerre, Mathias Karsten

solidification and growth continues throughout solid state cooling and the eutectoid transformation. Years of research have greatly improved the understanding of the basic mechanisms that control graphite growth as well as the ability to control graphite morphology during industrial production of cast components......, the solidification of cast iron is studied with focus on formation and growth of spheroidal graphite. To this end, an experiment is conducted at the Diamond Light Source synchrotron facility in Harwell, UK: Employing an environmental cell devel-oped at the Manchester X-ray Imaging Facility at the University...... state growth presented in the present thesis. From the analysis it is clear that the presented data is of an unprecedented quality and that it represents a solid basis for validation of future models. Solidification simulations of a ductile cast iron component highlights the importance of the nucleation...

Flake graphite cast iron investigated by a magnetic method

Czech Academy of Sciences Publication Activity Database

Vértesy, G.; Uchimoto, T.; Takagi, T.; Tomáš, Ivan

2014-01-01

Roč. 50, č. 4 (2014), s. 6200404 ISSN 0018-9464 Institutional support: RVO:68378271 Keywords : cast iron * magnetic adaptive testing (MAT) * magnetic nondestructive evaluation Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.386, year: 2014

Influence of rare earths on shrinkage porosity in thin walled ductile cast iron

DEFF Research Database (Denmark)

Pedersen, Karl Martin; Tiedje, Niels Skat

2009-01-01

Ductile cast iron has been cast in test bars with thickness from 2 to 10 mm. The rare earth elements La and Ce have been added to some of the castings to evaluate their influence on microstructure and shrinkage tendency. Both La and Ce increased the graphite nodule count, especially for thickness...

Changes of gas pressure in sand mould during cast iron pouring

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J. Mocek

2011-10-01

Full Text Available The paper presents a test method developed to measure changes of gas pressure in sand moulds during manufacture of iron castings. The pressure and temperature measurements were taken in the sand mould layers directly adjacent to the metal – mould interface. A test stand was described along with the measurement methodology. The sensors used allowed studying the fast-changing nature of the processes which give rise to the gas-originated casting defects. The study examined the influence of binders, clays and refining additives on the nature of the gas evolution process. The effect of the base sand type - quartz or olivine - on the nature of pressure changes was compared. The test stand design ensured the stability of technological parameters in the examined mould elements, and a repeatable process of making pilot castings. The main outcome was classification of sand mixtures in terms of pressure occurring during pouring of iron castings. The obtained results confirm the usefulness of the described method for testing gas pressure occurrence in a sand mould.

INFLUENCE OF ANNEALING ON HARDNESS OF Cr-Mn-Ni CAST IRONS

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V. V. Netrebko

2015-01-01

Full Text Available The necessary level of material’s hardness is determined by the exploitation conditions and presence of technological operations during manufacturing of articles. Mechanical edge cutting machining of wear resistant materials is impeded because of their high hardness. It is recommended to apply annealing in order to decrease hardness and improve machinability. The purpose of the work consisted in obtaining of regression dependences of cast iron’s macrohardness on its chemical content after annealing at 730 °С. With the use of mathematical experimental design the regression dependences of cast iron’s macrohardness and structural components’ microhardness on С, Cr, Mn, Ni content have been established. The minimal hardness of 27,6 HRC after annealing at 730 °С is obtained in the cast iron containing: 3,9% С; 11,4% Cr; 0,6% Mn; 0,2% Ni. The maximal hardness of 70,4 HRC is obtained when the content is as follows: 1,1% С; 25,6% Cr; 5,4% Mn; 3,0% Ni. Annealing at 730 °С decreases the cast irons’ hardness containing the minimal amount of Cr, Mn and Ni. Annealing at 730 °С is recommended for cast irons alloyed by Mn and Ni for increasing of hardness.

Laser processing of cast iron for enhanced erosion resistance

International Nuclear Information System (INIS)

Chen, C.H.; Altstetter, C.J.; Rigsbee, J.M.

1984-01-01

The surfaces of nodular and gray cast iron have been modified by CO 2 laser processing for enhanced hardness and erosion resistance. Control of the near-surface microstructure was achieved primarily by controlling resolidification of the laser melted layer through variations in laser beam/target interaction time and beam power density. Typical interaction times and power densities used were 5 msec and 500 kW/cm 2 . Two basic kinds of microstructure can be produced-a feathery microstructure with high hardness (up to 1245 HV) and a dendritic microstructure with a metastable, fully austenitic matrix and lower hardness (600 to 800 HV). Erosion testing was done using slurries of SiO 2 or SiC in water. Weight loss and crater profile measurements were used to evaluate the erosion characteristics of the various microstructures. Both ductile and gray cast iron showed marked improvement in erosion resistance after laser processing

Investigation of effects of boron additives and heat treatment on carbides and phase transition of highly alloyed duplex cast iron

International Nuclear Information System (INIS)

Tasgin, Yahya; Kaplan, Mehmet; Yaz, Mehmet

2009-01-01

The effect of boron additives and heat treatment on the microstructural morphology of the transition zone in a duplex cast iron, which has an outer shell of white cast iron (with a high Cr-content and containing boron additives) and an inner side composed of normal gray cast iron, has been investigated. For this purpose, two experimental materials possessing different compositions of white-gray duplex cast iron were produced. Subsequently, metallographic investigations were carried out to study the effect of heat treatment applied to the experimental materials by using the scanning electron microscopy technique, along with optical microscopy and energy dispersive X-ray spectroscopy. Moreover, the formation of various phases and carbide composites in the samples and their effects on the hardness were also investigated using X-ray diffraction techniques. The results of investigations, and hardness showed that addition of the elements Cr and B to high-alloyed white cast iron affected carbide formation significantly, while simultaneously hardening the microstructure, and consequently the carbide present in the transition area of white-gray cast iron was spread out and became thinner. However, B additives and heat treatment did not cause any damage to the transition region of high Cr-content duplex cast iron.

Selective Leaching of Gray Cast Iron: Electrochemical Aspects

International Nuclear Information System (INIS)

Na, Kyung Hwan; Yun, Eun Sub; Park, Young Sheop

2010-01-01

Currently, to keep step with increases in energy consumption, much attention has been paid to the construction of new nuclear power plants (NPPs) and to the continued operation of NPPs. For continued operation, the selective leaching of materials should be evaluated by visual inspections and hardness measurements as a part of One-Time Inspection Program according to the requirements of the guidelines for continued operation of pressured water reactors (PWRs) in Korea and license renewals in the United States, entitled the 'Generic Aging Lessons Learned (GALL) report.' However, the acceptance criteria for hardness have yet to be provided. Recently, USNRC released a new draft of the GALL report for comment and plans to publish its formal version by the end of 2010. In the new draft, the quantitative acceptance criteria for hardness are given at last: no more than a 20 percent decrease in hardness for gray cast iron and brass containing more than 15 percent zinc. Selective leaching is the preferential removal of one of the alloying elements from a solid alloy by corrosion processes, leaving behind a weakened spongy or porous residual structure. The materials susceptible to selective leaching include gray cast iron and brass, which are mainly used as pump casings and valve bodies in the fire protection systems of NPPs. Since selective leaching proceeds slowly during a long period of time and causes a decrease in strength without changing the overall dimensions of original material, it is difficult to identify. In the present work, the selective leaching of gray cast iron is investigated in terms of its electrochemical aspects as part of an ongoing research project to study the changes in metal properties by selective leaching

Effect of alloying elements on solidification of primary austenite in Ni-Mn-Cu cast iron

Directory of Open Access Journals (Sweden)

A. Janus

2011-04-01

Full Text Available Within the research, determined were direction and intensity of alloying elements influence on solidification way (directional orvolumetric of primary austenite dendrites in hypoeutectic austenitic cast iron Ni-Mn-Cu. 50 cast shafts dia. 20 mm were analysed.Chemical composition of the alloy was as follows: 1.7 to 3.3 % C, 1.4 to 3.1 % Si, 2.8 to 9.9 % Ni, 0.4 to 7.7 % Mn, 0 to 4.6 % Cu, 0.14 to0.16 % P and 0.03 to 0.04 % S. The discriminant analysis revealed that carbon influences solidification of primary austenite dendrites most intensively. It clearly increases the tendency to volumetric solidification. Influence of the other elements is much weaker. This means that the solidification way of primary austenite dendrites in hypoeutectic austenitic cast iron Ni-Mn-Cu does not differ from that in an unalloyed cast iron.

Rapid Separation of Copper Phase and Iron-Rich Phase From Copper Slag at Low Temperature in a Super-Gravity Field

Science.gov (United States)

Lan, Xi; Gao, Jintao; Huang, Zili; Guo, Zhancheng

2018-06-01

A novel approach for quickly separating a metal copper phase and iron-rich phase from copper slag at low temperature is proposed based on a super-gravity method. The morphology and mineral evolution of the copper slag with increasing temperature were studied using in situ high-temperature confocal laser scanning microscopy and ex situ scanning electron microscopy and X-ray diffraction methods. Fe3O4 particles dispersed among the copper slag were transformed into FeO by adding an appropriate amount of carbon as a reducing agent, forming the slag melt with SiO2 at low temperature and assisting separation of the copper phase from the slag. Consequently, in a super-gravity field, the metallic copper and copper matte were concentrated as the copper phase along the super-gravity direction, whereas the iron-rich slag migrated in the opposite direction and was quickly separated from the copper phase. Increasing the gravity coefficient (G) significantly enhanced the separation efficiency. After super-gravity separation at G = 1000 and 1473 K (1200 °C) for 3 minutes, the mass fraction of Cu in the separated copper phase reached 86.11 wt pct, while that in the separated iron-rich phase was reduced to 0.105 wt pct. The recovery ratio of Cu in the copper phase was as high as up to 97.47 pct.

Effects of alloying elements on the microstructure and fatigue properties of cast iron for internal combustion engine exhaust manifolds

Science.gov (United States)

Eisenmann, David J.

In the design of exhaust manifolds for internal combustion engines the materials used must exhibit resistance to corrosion at high temperatures while maintaining a stable microstructure. Cast iron has been used for manifolds for many years by auto manufacturers due to a combination of suitable mechanical properties, low cost, and ease of casting. Over time cast iron is susceptible to microstructural changes, corrosion, and oxidation which can result in failure due to fatigue. This thesis seeks to answer the question: "Can observed microstructural changes and measured high temperature fatigue life in cast iron alloys be used to develop a predictive model for fatigue life?" the importance of this question lies in the fact that there is little data for the behavior of cast iron alloys at high temperature. For this study two different types of cast iron, 50HS and HSM will be examined. Of particular concern for the high Si+C cast irons (and Mo in the case of the HSM cast iron) are subsurface microstructural changes that result due to heat treatment including (1) decarburization, (2) ferrite formation, (3) graphitization, (4) internal oxidation of the Si, (5) high temperature fatigue resistance, and (6) creep potential. Initial results obtained include microstructure examination after being exposed to high temperatures, grain size, nodule size, and hardness measurements. The initial examinations concluded that both cast irons performed fairly similarly, although the microstructure of the HSM samples did show slightly better resistance to high temperature as compared to that of the 50HS. Follow on work involved high temperature fatigue testing of these two materials in order to better determine if the newer alloy, HSM is a better choice for exhaust manifolds. Correlations between fatigue performance and microstructure were made and discussed, with the results examined in light of current and proposed models for predicting fatigue performance based on computational methods

Residual analysis applied to S-N data of a surface rolled cast iron

Directory of Open Access Journals (Sweden)

Omar Maluf

2005-09-01

Full Text Available Surface rolling is a process extensively employed in the manufacture of ductile cast iron crankshafts, specifically in regions containing stress concentrators with the main aim to enhance fatigue strength. Such process hardens and introduces compressive residual stresses to the surface as a result of controlled strains, reducing cyclic tensile stresses near the surface of the part. The main purpose of this work was to apply the residual analysis to check the suitability of the S-N approach to describe the fatigue properties of a surface rolled cast iron. The analysis procedure proved to be very efficient and easy to implement and it can be applied in the verification of any other statistical model used to describe fatigue behavior. Results show that the conventional S-N methodology is able to model the high cycle fatigue behavior of surface rolled notch testpieces of a pearlitic ductile cast iron submitted to rotating bending fatigue tests.

Value/impact of design criteria for cast ductile iron shipping casks

International Nuclear Information System (INIS)

1983-01-01

The ductile failure criteria proposed in the Base report appear appropriate except that stress intensity values, S/sub m/ should be based on lower safety factors and ductility should be added as a criterion. A safety factor for stress intensity, s/sub m/ of 4 is recommended rather than 3 on minimum ultimate tensile strength, S/sub u/ in accordance with ASME code philosophy of assigning higher safety factors to cast ductile iron than to steel. This more conservative approach has no impact on costs since the selection of wall thickness is controlled by shielding rather than by stress considerations. The addition of a ductility criterion is recommended because of the problems associated with the selection of appropriate brittle failure criteria and the potential for cast ductile iron to have extremely low elongation at failure. Neither a materials nor a linear elastic fracture mechanics (LEFM) approach appear to be viable for demonstrating the prevention of brittle failure in cast ductile iron shipping casks. It is possible that the analytic methods predict brittle failure because of extremely conservative assumptions whereas real casks may not fail. Model drop tests could be used to demonstrate containment integrity. It is estimated that a risk committment of at least $1,000,000 would be required for engineering, design, model fabrication and testing. Before taking such risks, a mechanism should be found to obtain concurrence from NRC that the results of the test would be acceptable. Probabilistic approaches or model testing could be used to demonstrate the acceptability of cast ductile iron casks from a brittle failure point of view. Before probabilistic methods can be used, the NRC would have to be persuaded to accept the approach of the Competent Authority in West Germany or more formalized methods for probabilistic risk assessments

Review of current research and application of ductile cast iron quality monitoring technologies in Chinese foundry industry

Directory of Open Access Journals (Sweden)

Da-yong Li

2015-07-01

Full Text Available There is a long history of studying and making use of ductile cast iron in China. Over the years, the foundrymen in China have carried out a lot of valuable research and development work for measuring parameters and controlling the quality in ductile cast iron production. Many methods, such as rapid metallographic phase, thermal analysis, eutectic expansion ratio, surface tension measurement, melt electrical resistivity, oxygen and sulfur activity measurement, ultrasonic measurement and sound frequency measurement, have been used and have played important roles in Chinese casting production in the past. These methods can be generally classified as liquid testing and solid testing according to the sample state. Based on the analysis of the present situation of these methods applied in the Chinese metal casting industry, the authors consider that there are two difficult technical problems to be currently solved in monitoring ductile iron quality. One is to seek an effective method for quickly evaluating the nodularizing result through on-the-spot sample analysis before the liquid iron is poured into the mould. The other is to find a nondestructive method for accurately identifying casting quality before castings are delivered.

Crystallization of nodular cast iron with carbides

Directory of Open Access Journals (Sweden)

S. Pietrowski

2008-12-01

Full Text Available In this paper a crystallization process of nodular cast iron with carbides having a different chemical composition have been presented. It have been found, that an increase of molybdenum above 0,30% causes the ledeburutic carbides crystallization after (γ+ graphite eutectic phase crystallization. When Mo content is lower, these carbides crystallize as a pre-eutectic phase. In this article causes of this effect have been given.

SEALING LARGE-DIAMETER CAST-IRON PIPE JOINTS UNDER LIVE CONDITIONS

Energy Technology Data Exchange (ETDEWEB)

Kiran M. Kothari; Gerard T. Pittard

2004-04-01

Utilities in the U.S. operate over 75,000 km (47,000 miles) of old cast-iron pipes for gas distribution. The bell-and-spigot joints that connect pipe sections together tend to leak as these pipes age. Current repair practices are costly and highly disruptive. The objective of this program is to design, test and commercialize a robotic system capable of sealing multiple cast-iron bell and spigot joints from a single pipe entry point. The proposed system will perform repairs while the pipe remains in service by traveling through the pipe, cleaning each joint surface, and installing a stainless-steel sleeve lined with an epoxy-impregnated felt across the joint. This approach will save considerable time and labor, avoid traffic disruption, and eliminate any requirement to interrupt service to customers (which would result in enormous expense to utilities). Technical challenges include: (1) repair sleeves must compensate for diametric variation and eccentricity of cast-iron pipes; (2) the assembly must travel long distances through pipes containing debris; (3) the pipe wall must be effectively cleaned in the immediate area of the joint to assure good bonding of the sleeve; and (4) an innovative bolt-on entry fitting is required to conduct repair operations on live mains. The development effort is divided into eleven tasks. Task 1--Program Management and Task 2--were completed in prior quarters while Task 3--Design and Fabricate Ratcheting Stainless-Steel Repair Sleeves has progressed to installing prototype sleeves in cast iron test pipe segments. Efforts in this quarter continued to focus on Tasks 4--8, with significant progress made in each. Task 4 (Design, Fabricate and Test Patch Setting Robotic Train) progressed to the design of the control electronics and pneumatic system to inflate the bladder robotic patch setting module. Task 5 (Design & Fabricate Pipe-Wall Cleaning Robot Train with Pan/Zoom/Tilt Camera) continued with additional in-pipe testing required to

An Electron Microscopy Study of Graphite Growth in Nodular Cast Irons

Science.gov (United States)

Laffont, L.; Jday, R.; Lacaze, J.

2018-04-01

Growth of graphite during solidification and high-temperature solid-state transformation has been investigated in samples cut out from a thin-wall casting which solidified partly in the stable (iron-graphite) and partly in the metastable (iron-cementite) systems. Transmission electron microscopy has been used to characterize graphite nodules in as-cast state and in samples having been fully graphitized at various temperatures in the austenite field. Nodules in the as-cast material show a twofold structure characterized by an inner zone where graphite is disoriented and an outer zone where it is well crystallized. In heat-treated samples, graphite nodules consist of well-crystallized sectors radiating from the nucleus. These observations suggest that the disoriented zone appears because of mechanical deformation when the liquid contracts during its solidification in the metastable system. During heat-treatment, the graphite in this zone recrystallizes. In turn, it can be concluded that nodular graphite growth mechanism is the same during solidification and solid-state transformation.

Effect of microstructure and surface features on wetting angle of a Fe-3.2 wt%C.E. cast iron with water

Science.gov (United States)

Riahi, Samira; Niroumand, Behzad; Dorri Moghadam, Afsaneh; Rohatgi, Pradeep K.

2018-05-01

In the present study, variation in surface wetting behavior of a hypoeutectic cast iron with its microstructural features and surface roughness was investigated. Samples with an identical composition, i.e. Fe-3.2 wt%C.E., and different microstructures (a gray cast iron with A-type flake graphite and a white cast iron) were fabricated by gravity casting of molten cast iron in a chill mold at different cooling rates. A variation of surface roughness was also developed by polishing, a four-stage electroetching and a four-stage mechanical abrading on the samples. Roughness and water contact angles of all surfaces were then measured. The surface roughness factor and the solid fraction in contact with water by the Wenzel and Cassie-Baxter contact models were also calculated and compared with the corresponding measured contact angles to find out which regime was active. Results indicated that the surface microstructure and the type of constituents present at the surface influenced the cast iron surface wettability and that it was possible to change the surface contact angle by modification of the surface microstructure. The mechanically abraded gray cast iron followed the Wenzel-type regime while the electroetched surfaces of gray cast iron exhibited a transition from Wenzel to Cassie-Baxter type regime. In white cast iron, the results indicated Wenzel type behavior in the electroetched samples while for the mechanically abraded samples, none of these two models could predict the wetting behavior. Furthermore, the wetting angles of both gray and white cast irons were measured after 1, 2, 3 and 4 weeks of air exposure. The results showed that the wetting angles of both samples increased to above 90° after one week of air exposure which was likely due to adsorption of low surface energy hydrocarbons on the surfaces.

Fatigue properties of ductile cast iron containing chunky graphite

Energy Technology Data Exchange (ETDEWEB)

Ferro, P., E-mail: ferro@gest.unipd.it [Department of Management and Engineering, University of Padova, Stradella S. Nicola 3, I-36100 Vicenza (Italy); Lazzarin, P.; Berto, F. [Department of Management and Engineering, University of Padova, Stradella S. Nicola 3, I-36100 Vicenza (Italy)

2012-09-30

Highlights: Black-Right-Pointing-Pointer Experimental determination of high cycle fatigue properties of EN-GJS-400. Black-Right-Pointing-Pointer Evaluation of the influence of chunky graphite morphology on fatigue life. Black-Right-Pointing-Pointer Metallurgical analysis and microstructural parameters determination. Black-Right-Pointing-Pointer Nodule counting and nodularity rating. - Abstract: This work deals with experimental determination of high cycle fatigue properties of EN-GJS-400 ductile cast iron containing chunky graphite. Constant amplitude axial tests were performed at room temperature under a nominal load ratio R = 0. In order to evaluate the influence of chunky graphite morphology on fatigue life, fatigue tests were carried out also on a second set of specimens without this microstructural defect. All samples were taken from the core of a large casting component. Metallurgical analyses were performed on all the samples and some important microstructural parameters (nodule count and nodularity rating, among others) were measured and compared. It was found that a mean content of 40% of chunky graphite in the microstructure (with respect to total graphite content) does not influence significantly the fatigue strength properties of the analysed cast iron. Such result was attributed to the presence of microporosity detected on the surface fracture of the specimens by means of electron scanning microscope.

Fatigue properties of ductile cast iron containing chunky graphite

International Nuclear Information System (INIS)

Ferro, P.; Lazzarin, P.; Berto, F.

2012-01-01

Highlights: ► Experimental determination of high cycle fatigue properties of EN-GJS-400. ► Evaluation of the influence of chunky graphite morphology on fatigue life. ► Metallurgical analysis and microstructural parameters determination. ► Nodule counting and nodularity rating. - Abstract: This work deals with experimental determination of high cycle fatigue properties of EN-GJS-400 ductile cast iron containing chunky graphite. Constant amplitude axial tests were performed at room temperature under a nominal load ratio R = 0. In order to evaluate the influence of chunky graphite morphology on fatigue life, fatigue tests were carried out also on a second set of specimens without this microstructural defect. All samples were taken from the core of a large casting component. Metallurgical analyses were performed on all the samples and some important microstructural parameters (nodule count and nodularity rating, among others) were measured and compared. It was found that a mean content of 40% of chunky graphite in the microstructure (with respect to total graphite content) does not influence significantly the fatigue strength properties of the analysed cast iron. Such result was attributed to the presence of microporosity detected on the surface fracture of the specimens by means of electron scanning microscope.

Rolling Contact Fatigue Failure Mechanisms of Plasma-Nitrided Ductile Cast Iron

Science.gov (United States)

Wollmann, D.; Soares, G. P. P. P.; Grabarski, M. I.; Weigert, N. B.; Escobar, J. A.; Pintaude, G.; Neves, J. C. K.

2017-05-01

Rolling contact fatigue (RCF) of a nitrided ductile cast iron was investigated. Flat washers machined from a pearlitic ductile cast iron bar were quenched and tempered to maximum hardness, ground, polished and divided into four groups: (1) specimens tested as quenched and tempered; (2) specimens plasma-nitrided for 8 h at 400 °C; (3) specimens plasma-nitrided and submitted to a diffusion process for 16 h at 400 °C; and (4) specimens submitted to a second tempering for 24 h at 400 °C. Hardness profiles, phase analyses and residual stress measurements by x-ray diffraction, surface roughness and scanning electron microscopy were applied to characterize the surfaces at each step of this work. Ball-on-flat washer tests were conducted with a maximum contact pressure of 3.6 GPa, under flood lubrication with a SAE 90 API GL-5 oil at 50 °C. Test ending criterion was the occurrence of a spalling. Weibull analysis was used to characterize RCF's lifetime data. Plasma-nitrided specimens exhibited a shorter RCF lifetime than those just quenched and tempered. The effects of nitriding on the mechanical properties and microstructure of the ductile cast iron are discussed in order to explain the shorter endurance of nitrided samples.

The commercialization of the FENIX iron control system for purifying copper electrowinning electrolytes

Science.gov (United States)

Shaw, D. R.; Dreisinger, D. B.; Lancaster, T.; Richmond, G. D.; Tomlinson, M.

2004-07-01

The FENIX Hydromet Iron Control System was installed at Western Metals Copper Ltd.’s Mt. Gordon Operations in Queensland, Australia. The system uses a novel and patented ion-exchange resin to selectively remove iron from copper electrolyte at the solvent extraction/electrowinning plant. At Mt. Gordon, the system delivered significant savings in reagent consumption (acid and cobalt sulfate for electrowinning and lime for neutralization of the raffinate bleed) and has the potential to deliver higher current efficiencies in copper electrowinning, leading to increased copper production.

Dynamic fracture toughness and evaluation of fracture in a ferritic nodular cast iron for casks

International Nuclear Information System (INIS)

Yasunaka, T.; Nakano, K.

1993-01-01

The effect of loading rate and temperature on fracture toughness of a ferritic nodular cast iron obtained from a thick-walled cylindrical casting has been investigated. Based upon this result, the cast iron is evaluated as a material for casks. (1) In the ductile fracture region, fracture toughness increases with increases in loading rate. (2) Ductile-brittle transition temperature is linearly related to the logarithm of stress intensity rate. (3) In the ductile fracture region, converted plain strain fracture toughness divided by yield stress can be adopted as a material constant which is independent of loading rate and temperature. From the result of a static fracture toughness test, the evaluation of fracture in high loading rate can be made. (4) In the ductile fracture region of the material investigated, the maximum allowable flaw depth exceeded the minimum detectable flaw size by a nondestructive inspection. Ferritic nodular cast iron can be used as a material for casks in the ductile fracture region at least. (J.P.N.)

Serum Zinc, Iron and Copper Concentrations in Dogs Infected with Hepatozoon canis

Directory of Open Access Journals (Sweden)

Kamil Seyrek

2009-01-01

Full Text Available In Turkey, canine hepatozoonosis is an emerging infection with a large number of cases detected during the past five years. In the present study, serum zinc, copper and iron concentrations of dogs infected with Hepatozoon canis were measured for the first time. Compared to the controls (n = 10, serum zinc and iron concentrations in infected animals (n = 14 decreased significantly (p p p Hepatozoon canis infection may cause alterations in serum zinc iron and copper concentrations. Furthermore, in the treatment of infected animals addition of zinc and iron to the ration of infected animals should be taken into consideration.

Copper and ectopic expression of the Arabidopsis transport protein COPT1 alter iron homeostasis in rice (Oryza sativa L.).

Science.gov (United States)

Andrés-Bordería, Amparo; Andrés, Fernando; Garcia-Molina, Antoni; Perea-García, Ana; Domingo, Concha; Puig, Sergi; Peñarrubia, Lola

2017-09-01

Copper deficiency and excess differentially affect iron homeostasis in rice and overexpression of the Arabidopsis high-affinity copper transporter COPT1 slightly increases endogenous iron concentration in rice grains. Higher plants have developed sophisticated mechanisms to efficiently acquire and use micronutrients such as copper and iron. However, the molecular mechanisms underlying the interaction between both metals remain poorly understood. In the present work, we study the effects produced on iron homeostasis by a wide range of copper concentrations in the growth media and by altered copper transport in Oryza sativa plants. Gene expression profiles in rice seedlings grown under copper excess show an altered expression of genes involved in iron homeostasis compared to standard control conditions. Thus, ferritin OsFER2 and ferredoxin OsFd1 mRNAs are down-regulated whereas the transcriptional iron regulator OsIRO2 and the nicotianamine synthase OsNAS2 mRNAs rise under copper excess. As expected, the expression of OsCOPT1, which encodes a high-affinity copper transport protein, as well as other copper-deficiency markers are down-regulated by copper. Furthermore, we show that Arabidopsis COPT1 overexpression (C1 OE ) in rice causes root shortening in high copper conditions and under iron deficiency. C1 OE rice plants modify the expression of the putative iron-sensing factors OsHRZ1 and OsHRZ2 and enhance the expression of OsIRO2 under copper excess, which suggests a role of copper transport in iron signaling. Importantly, the C1 OE rice plants grown on soil contain higher endogenous iron concentration than wild-type plants in both brown and white grains. Collectively, these results highlight the effects of rice copper status on iron homeostasis, which should be considered to obtain crops with optimized nutrient concentrations in edible parts.

Casting and stress-strain simulations of a cast ductile iron component using microstructure based mechanical behavior

International Nuclear Information System (INIS)

Olofsson, Jakob; Svensson, Ingvar L

2012-01-01

The industrial demand for increased component performance with concurrent reductions in component weight, development times and verifications using physical prototypes drives the need to use the full potential of casting and Finite Element Method (FEM) simulations to correctly predict the mechanical behavior of cast components in service. The mechanical behavior of the component is determined by the casting process, and factors as component geometry and casting process parameters are known to affect solidification and microstructure formation throughout the component and cause local variations in mechanical behavior as well as residual stresses. Though residual stresses are known to be an important factor in the mechanical behavior of the component, the importance of local mechanical behavior is not well established and the material is typically considered homogeneous throughout the component. This paper deals with the influence of solidification and solid state transformation on microstructure formation and the effect of local microstructure variations on the mechanical behavior of the cast component in service. The current work aims to investigate the coupling between simulation of solidification, microstructure and local variations in mechanical behavior and stress-strain simulation. This is done by performing several simulations of a ductile iron component using a recently developed simulation strategy, a closed chain of simulations for cast components, able to predict and describe the local variations in not only elastic but also plastic behavior throughout the component by using microstructural parameters determined by simulations of microstructural evolution in the component during the casting process. In addition the residual stresses are considered. The results show that the FEM simulation results are significantly affected by including microstructure based mechanical behavior. When the applied load is low and the component is subjected to stress levels

Formation of microstructure and properties on hot working and heat treatment of high strength modular cast iron

International Nuclear Information System (INIS)

Trajno, A.I.; Yusupov, V.S.; Kugushin, A.A.

1999-01-01

The possibility of plastic deformation of high strength modular cast iron (HSNCI) is under study. The microstructure and mechanical properties of hot worked and heat treated cast iron are investigated for the composition, %: Fe - 2.9 C - 2.4 Si - 0.7 Ni - 0.05 Mg - 0.04 Ce. It is stated that HSNCI can withstand various types of hot working without fracturing. Graphite inclusions lose their modular shape irreversibly during plastic deformation. Subsequent heat treatment affects the metal matrix only. The heating in oxidizing environment is noted to result in cast iron surface decarbonization [ru

Relation between serum lipoperoxide concentrations and iron or copper status over one year in Cuban adult men

Energy Technology Data Exchange (ETDEWEB)

Arnaud, J.; Renversez, J.C.; Favier, A.E. [Dept. de Biologie Integree, CHUG, Grenoble (France); Fleites, P.; Perez-Cristia, R. [Centro national de Toxicologia (CENATOX), La Habana (Cuba); Chassagne, M.; Barnouin, J. [INRA, Unite d' Ecopathologie, Saint Genes Champanelle (France); Verdura, T. [Inst. Finlay, La Lisa, La Habana (Cuba); Garcia, I.G. [Inst. de Farmacia y Alimentos, La Coronela, La Lisa, Ciudad de la Habana (Cuba); Tressol, J.C. [INRA, Unite maladies metaboliques et micronutriments, Saint Genes Champanelle (France)

2001-07-01

The aims of this study were to determine the relations between iron and copper status and lipid peroxidation at different periods over one year in low-income and low-energy intake healthy subjects. The study was conducted in 199 middle-aged healthy Cuban men from March 1995 to February 1996. Iron status was assessed by the determination of serum ferritin, transferrin saturation, whole blood hemoglobin and iron intakes. Copper status was evaluated by the determination of serum copper and copper intakes. Serum thiobarbituric acid substances (TBARS) determination was used as an index of lipid peroxidation. Rank correlations were observed between serum TBARS concentrations and iron or copper status indices at different periods. In period 3 (end of the rainy season), serum TBARS and ferritin concentrations were maximum whereas blood hemoglobin levels and iron intake were minimum. Serum TBARS concentrations were significantly higher than the reference values of the laboratory whereas, iron and copper status were within the reference ranges. These results suggested that iron and copper status may be associated with lipid peroxidation in subjects without metal overloads and that variations over the year needed to be taken in account. (orig.)

Diffusion Coefficient in the Zinc Coating Shaped on the Surface of Cast Iron and Steel Alloys

Directory of Open Access Journals (Sweden)

Kopyciński D.

2015-06-01

Full Text Available The article presents the method to assess the diffusion coefficient D in the sub-layer of intermetallic phases formed during hot-dip galvanizing “Armco” iron and ductile cast iron EN-GJS-500-7. Hot-dip galvanizing is one of the most popular forms of long-term protection of Fe-C alloys against corrosion. The process for producing a protective layer of sufficient quality is closely related to diffusion of atoms of zinc and iron. The simulation consist in performed a hot-dip galvanizing in laboratory condition above Fe-C alloys, in the Department of Engineering of Cast Alloys and Composites. Galvanizing time ranged from 15 to 300 seconds. Then metallographic specimens were prepared, intermetallic layers were measured and diffusion coefficient (D were calculated. It was found that the diffusion coefficient obtained during hot-dip galvanizing “Armco” iron and zinc is about two orders of magnitude less than the coefficient obtained on ductile cast iron EN-GJS-500-7.

Ceramic port shields cast in an iron engine head

Science.gov (United States)

Hakim, Nabil S.; Groeneweg, Mark A.

1989-01-01

Silicon nitride exhaust and intake port shields have been successfully cast into a gray iron cylinder head of a heavy duty diesel single cylinder research engine. Careful design considerations, finite element, and probability of survival analyses indicated viability of the design. Foundry experience, NDE, and failure investigations are reported.

Effect of medium on friction and wear properties of compacted graphite cast iron processed by biomimetic coupling laser remelting process

International Nuclear Information System (INIS)

Guo Qingchun; Zhou Hong; Wang Chengtao; Zhang Wei; Lin Pengyu; Sun Na; Ren Luquan

2009-01-01

Stimulated by the cuticles of soil animals, an attempt to improve the wear resistance of compact graphite cast iron (CGI) with biomimetic units on the surface was made by using a biomimetic coupled laser remelting process in air and various thicknesses water film, respectively. The microstructures of biomimetic units were examined by scanning electron microscope and X-ray diffraction was used to describe the microstructure and identify the phases in the melted zone. Microhardness was measured and the wear behaviors of biomimetic specimens as functions of different mediums as well as various water film thicknesses were investigated under dry sliding condition, respectively. The results indicated that the microstructure zones in the biomimetic specimens processed with water film are refined compared with that processed in air and had better wear resistance increased by 60%, the microhardness of biomimetic units has been improved significantly. The application of water film provided finer microstructures and much more regular grain shape in biomimetic units, which played a key role in improving the friction properties and wear resistance of CGI.

Effect of medium on friction and wear properties of compacted graphite cast iron processed by biomimetic coupling laser remelting process

Science.gov (United States)

Guo, Qing-chun; Zhou, Hong; Wang, Cheng-tao; Zhang, Wei; Lin, Peng-yu; Sun, Na; Ren, Luquan

2009-04-01

Stimulated by the cuticles of soil animals, an attempt to improve the wear resistance of compact graphite cast iron (CGI) with biomimetic units on the surface was made by using a biomimetic coupled laser remelting process in air and various thicknesses water film, respectively. The microstructures of biomimetic units were examined by scanning electron microscope and X-ray diffraction was used to describe the microstructure and identify the phases in the melted zone. Microhardness was measured and the wear behaviors of biomimetic specimens as functions of different mediums as well as various water film thicknesses were investigated under dry sliding condition, respectively. The results indicated that the microstructure zones in the biomimetic specimens processed with water film are refined compared with that processed in air and had better wear resistance increased by 60%, the microhardness of biomimetic units has been improved significantly. The application of water film provided finer microstructures and much more regular grain shape in biomimetic units, which played a key role in improving the friction properties and wear resistance of CGI.

The Role of Serum Copper and Iron in Oral Submucous Fibrosis

Directory of Open Access Journals (Sweden)

Master Luquman

2004-01-01

Full Text Available Oral submucous fibrosis (OSMF is a chronic insidious disease of multifactorial etiology. The habit of chewing arecanut is thought to be one of the most important etiologic factors. Copper and iron are elements in the human body that form part of important enzymes. We estimated the serum copper and iron in patients with OSMF as well as normal controls and discuss the role of these elements in the etiology of OSMF.

Extraction of copper zinc and iron from hydrochloric acid solutions by means of different extractants

Energy Technology Data Exchange (ETDEWEB)

Zhivkova, Svetlana [Institute of Chemical Engineering - Bulgarian Academy of Sciences, Sofia (Bulgaria)

2011-07-01

The extraction of copper, zinc and iron from hydrochloric acid solutions has been studied. The experiments have been carried out using various solvents, involving different extraction mechanisms – solvating, anion-exchange, cation-exchange, bifunctional . Mixtures of these extractants have been also used. The extraction properties of these extractant mixtures toward copper, zinc and iron, the effect of used modifiers and diluents have been also investigated. Key words: Copper, Zinc, Iron, Extraction, Extractant, Modifier, Diluent.

Effect of Bi on graphite morphology and mechanical properties of heavy section ductile cast iron

Directory of Open Access Journals (Sweden)

Song Liang

2014-03-01

Full Text Available To improve the mechanical properties of heavy section ductile cast iron, bismuth (Bi was introduced into the iron. Five castings with different Bi content from 0 to 0.014 wt.% were prepared; and four positions in the casting from the edge to the center, with different solidification cooling rates, were chosen for microstructure observation and mechanical properties test. The effect of the Bi content on the graphite morphology and mechanical properties of heavy section ductile cast iron were investigated. Results show that the tensile strength, elongation and impact toughness at different positions in the five castings decrease with a decrease in cooling rate. With an increase in Bi content, the graphite morphology and the mechanical properties at the same position are improved, and the improvement of mechanical properties is obvious when the Bi content is no higher than 0.011wt.%. But when the Bi content is further increased to 0.014wt.%, the improvement of mechanical properties is not obvious due to the increase of chunky graphite number and the aggregation of chunky graphite. With an increase in Bi content, the tensile fracture mechanism is changed from brittle to mixture ductile-brittle fracture.

SEALING LARGE-DIAMETER CAST-IRON PIPE JOINTS UNDER LIVE CONDITIONS

Energy Technology Data Exchange (ETDEWEB)

Kiran M. Kothari; Gerard T. Pittard

2005-01-01

Utilities in the U.S. operate over 75,000 km (47,000 miles) of old cast-iron pipes for gas distribution. The bell-and-spigot joints that connect pipe sections together tend to leak as these pipes age. Current repair practices are costly and highly disruptive. The objective of this program is to design, test and commercialize a robotic system capable of sealing multiple cast-iron bell and spigot joints from a single pipe entry point. The proposed system will perform repairs while the pipe remains in service by traveling through the pipe, cleaning each joint surface, and installing a stainless-steel sleeve lined with an epoxy-impregnated felt across the joint. This approach will save considerable time and labor, avoid traffic disruption, and eliminate any requirement to interrupt service to customers (which would result in enormous expense to utilities). Technical challenges include: (1) repair sleeves must compensate for diametric variation and eccentricity of cast-iron pipes; (2) the assembly must travel long distances through pipes containing debris; (3) the pipe wall must be effectively cleaned in the immediate area of the joint to assure good bonding of the sleeve; and (4) an innovative bolt-on entry fitting is required to conduct repair operations on live mains. The development effort is divided into eleven tasks. Task 1 (Program Management) and Task 2 (Establishment of Detailed Design Specifications) were completed in prior quarters while Task 3 (Design and Fabricate Ratcheting Stainless-Steel Repair Sleeves) has progressed to installing prototype sleeves in cast-iron test pipe segments. Efforts in the current quarter continued to focus on Tasks 4-8. Highly valuable lessons were learned from field tests of the 4-inch gas pipe repair robot in cast-iron pipe at Public Service Electric & Gas. (These field tests were conducted and reported last quarter.) These tests identified several design issues which need to be implemented in both the small- and large

Arsenic, chromium, copper, iron, manganese, lead, selenium and ...

African Journals Online (AJOL)

Arsenic, chromium, copper, iron, manganese, lead, selenium and zinc in the tissues of the largemouth yellowfish, Labeobarbus kimberleyensis (Gilchrist and Thompson, 1913), from the Vaal Dam, South Africa, and associated consumption risks.

Influence of mean stress on fatigue strength of ferritic-pearlite ductile cast iron with small defects

Science.gov (United States)

Deguchi, T.; Kim, H. J.; Ikeda, T.; Yanase, K.

2017-05-01

Because of their excellent mechanical properties, low cost and good workability, the application of ductile cast iron has been increased in various industries such as the automotive, construction and rail industries. For safety designing of the ductile cast iron component, it is necessary to understand the effect of stress ratio, R, on fatigue limit of ductile cast iron in the presence of small defects. Correspondingly in this study, rotating bending fatigue tests at R = -1 and tension-compression fatigue tests at R = -1 and 0.1 were performed by using a ferritic-pearlitic ductile cast iron. To study the effects of small defects, we introduced a small drilled hole at surface of a specimen. The diameter and depth of a drilled hole were 50, 200 and 500 μm, respectively. The non-propagating cracks emanating from graphite particles and holes edge were observed at fatigue limit, irrespective of the value of stress ratio. From the microscopic observation of crack propagation behavior, it can be concluded that the fatigue limit is determined by the threshold condition for propagation of a small crack. It was found that the effect of stress ratio on the fatigue limit of ductile cast iron with small defects can be successfully predicted based on \\sqrt {area} parameter model. Furthermore, a use of the tensile strength, σ B, instead of the Vickers hardness, HV, is effective for fatigue limit prediction.

Copper Deficiency Leads to Anemia, Duodenal Hypoxia, Upregulation of HIF-2α and Altered Expression of Iron Absorption Genes in Mice

Science.gov (United States)

Matak, Pavle; Zumerle, Sara; Mastrogiannaki, Maria; El Balkhi, Souleiman; Delga, Stephanie; Mathieu, Jacques R. R.; Canonne-Hergaux, François; Poupon, Joel; Sharp, Paul A.; Vaulont, Sophie; Peyssonnaux, Carole

2013-01-01

Iron and copper are essential trace metals, actively absorbed from the proximal gut in a regulated fashion. Depletion of either metal can lead to anemia. In the gut, copper deficiency can affect iron absorption through modulating the activity of hephaestin - a multi-copper oxidase required for optimal iron export from enterocytes. How systemic copper status regulates iron absorption is unknown. Mice were subjected to a nutritional copper deficiency-induced anemia regime from birth and injected with copper sulphate intraperitoneally to correct the anemia. Copper deficiency resulted in anemia, increased duodenal hypoxia and Hypoxia inducible factor 2α (HIF-2α) levels, a regulator of iron absorption. HIF-2α upregulation in copper deficiency appeared to be independent of duodenal iron or copper levels and correlated with the expression of iron transporters (Ferroportin - Fpn, Divalent Metal transporter – Dmt1) and ferric reductase – Dcytb. Alleviation of copper-dependent anemia with intraperitoneal copper injection resulted in down regulation of HIF-2α-regulated iron absorption genes in the gut. Our work identifies HIF-2α as an important regulator of iron transport machinery in copper deficiency. PMID:23555700

Fatigue strength of nodular cast iron with regard to heavy-wall applications

Energy Technology Data Exchange (ETDEWEB)

Bleicher, Christoph; Wagener, Rainer; Kaufmann, Heinz [Fraunhofer-Institut fuer Betriebsfestigkeit und Systemzuverlaessigkeit LBF, Darmstadt (Germany); Melz, Tobias [Fraunhofer-Institut fuer Betriebsfestigkeit und Systemzuverlaessigkeit LBF, Darmstadt (Germany); TU Darmstadt (Germany). Faculty of Mechanical Engineering

2015-11-01

For a proper estimation of the fatigue life of a heavy-walled cast component made of nodular cast iron, sufficient knowledge regarding the cyclic properties of the material is necessary. Based on the material parameters at hand for component design, different fatigue analysis procedures can be used. Elastic and elastic-plastic approaches can be adopted, with the latter being reserved only for local approaches. The present publication summarizes the cyclic material parameters gained during a research project by extensive material tests under stress and strain controlled cyclic loading at different load ratios for three nodular cast iron grades. In addition to an improved knowledge of the cyclic material behavior, the notch, the size effects and the mean stress sensitivity were of special concern during the investigations in order to provide an entire overview of the tested materials and thus input information for both stress and strain based design approaches. Tests were performed for specimens taken from large cast blocks of the nodular cast iron grades EN-GJS-400-18U-LT and EN-GJS-450-18, both with ferritic matrices, and EN-GJS-700-2 with a pearlitic matrix. For some of these materials, mean stress sensitivities above 0.5 were obtained during the investigations. These values are not covered by the common standards, which calculate lower values for the mean stress sensitivity. Cyclic material parameters for stress and strain controlled tests are given in this paper as well as values for the size effect, based on the concept of the highly stressed volume. The effect of different specimen sizes could be shown not only by stress but also by strain controlled tests.

Fractomechanical Properties of As-Cast and Austempered SG Cast Iron Between -40 °C and +20 °C

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V.E. Fierro

2002-06-01

Full Text Available The spheroidal graphite (SG cast iron fractomechanical response varies with the test temperature and with the microstructure parameters. In the present paper, we analyze this variation performing fractomechanical tests in a temperature range from -40°C to +20°C, doing also Charpy and tensile tests for material characterization. The tests were carried out on as-cast samples and heat treated samples to obtain an ADI grade 1. In both cases, we studied samples taken from two well differentiated "Y" block sizes. The results obtained show that, for the chemical composition analyzed, both castings have a fractomechanical response decrease as the temperature diminishes. Besides, the block size enlargement produce a deterioration of the mechanical properties (the fracture toughness, mainly, for both castings.

Arabidopsis copper transport protein COPT2 participates in the cross talk between iron deficiency responses and low-phosphate signaling.

Science.gov (United States)

Perea-García, Ana; Garcia-Molina, Antoni; Andrés-Colás, Nuria; Vera-Sirera, Francisco; Pérez-Amador, Miguel A; Puig, Sergi; Peñarrubia, Lola

2013-05-01

Copper and iron are essential micronutrients for most living organisms because they participate as cofactors in biological processes, including respiration, photosynthesis, and oxidative stress protection. In many eukaryotic organisms, including yeast (Saccharomyces cerevisiae) and mammals, copper and iron homeostases are highly interconnected; yet, such interdependence is not well established in higher plants. Here, we propose that COPT2, a high-affinity copper transport protein, functions under copper and iron deficiencies in Arabidopsis (Arabidopsis thaliana). COPT2 is a plasma membrane protein that functions in copper acquisition and distribution. Characterization of the COPT2 expression pattern indicates a synergic response to copper and iron limitation in roots. We characterized a knockout of COPT2, copt2-1, that leads to increased resistance to simultaneous copper and iron deficiencies, measured as reduced leaf chlorosis and improved maintenance of the photosynthetic apparatus. We propose that COPT2 could play a dual role under iron deficiency. First, COPT2 participates in the attenuation of copper deficiency responses driven by iron limitation, possibly to minimize further iron consumption. Second, global expression analyses of copt2-1 versus wild-type Arabidopsis plants indicate that low-phosphate responses increase in the mutant. These results open up new biotechnological approaches to fight iron deficiency in crops.

SURFACE CAST IRON STRENGTHENING USING COMBINED LASER AND ULTRASONIC PROCESSING

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O. G. Devojno

2013-01-01

Full Text Available The paper provides an analysis of ultrasonic surface plastic deformation and subsequent laser thermal strengthening of gray cast iron parts in the regime of hardening from a solid state with the purpose to obtain strengthened surface layers of bigger depth and less roughness of the processed surface. Program complex ANSYS 11.0 has been used for calculation of temperature fields induced by laser exposure.  The appropriate regime of laser processing without surface fusion has been selected on the basis of the applied complex. The possibility of displacement in the bottom boundary of α–γ-transformation temperature  for СЧ20 with 900 °С up to 800 °С is confirmed due to preliminary ultrasonic surface plastic deformation of the surface that allows to expand technological opportunities of laser quenching  of gray  cast iron from a solid state. 

Product and process innovation of grey cast iron brake discs

Energy Technology Data Exchange (ETDEWEB)

Schorn, M. [Brembo S.P.A. (Italy)

2006-07-01

The brake disc out of grey cast iron often seems to be playing the role of the ''underdog'' in the technical examinations of the entire brake system. This is also reflected by the 25 year history of the {mu}-club. In a total of 93 presentations in those 25 years, only 3 were related to the topic of grey cast iron discs. This is not a correct relation to the importance of this component within the brake system. The disc, although per definition with a lower specific load than the pad, has the major task to store and dissipate the heat in which the kinetic energy of the vehicle is transformed. The disc also has a significant effect on NVH behaviour, particularly in the low frequency range. It also has a permanent fight with its weight as an unsprung mass. (orig.)

Investigation of Bond Strength in Centrifugal Lining of Babbitt on Cast Iron

Science.gov (United States)

Diouf, Papa; Jones, Alan

2010-03-01

The quality of the bond between Babbitt metal and a cast iron substrate was evaluated for centrifugal casting and static casting using the Chalmers bond strength method and scanning electron microscopy (SEM). The effect of three different centrifugal casting parameters, the speed of revolution, the pouring rate, and the cooling rate, was investigated. The bond strength and the microstructure at the bond interface were predominantly affected by the cooling rate, with a fast cooling rate resulting in better properties. The speed of revolution and the pouring rate only had a small effect on the bond strength, with faster revolution and faster pouring rate resulting in slightly better bonds.

A Contribution to the Understanding of the Combined Effect of Nitrogen and Boron in Grey Cast Iron

DEFF Research Database (Denmark)

Strande, Knud; Tiedje, Niels Skat; Chen, Ming

2017-01-01

and in practice—to be effective in most cases. But it has the disadvantage that the nucleation effect fades away over time. In particular, in heavy castings (slow cooling) this effect may cause non-uniform and unacceptable material properties in some parts of the casting. Nitrogen is also known to influence grey...... iron microstructure. Both graphite flake formation and matrix formation are influenced. However, the obtained effects differ considerably between different reported investigations. This investigation deals with the combined effect of nitrogen and boron and how it is possible to utilize this effect...... to enhance material properties in heavy grey iron castings. It is shown that the controlled additions of nitrogen and boron can be used to control the microstructure of thick section grey iron castings. A plausible theory for the formation of boron nitride nuclei effective for graphite growth is presented....

Graphite nodule count and size distribution in thin-walled ductile cast iron

DEFF Research Database (Denmark)

Pedersen, Karl Martin; Tiedje, Niels Skat

2008-01-01

Graphite nodule count and size distribution have been analysed in thin walled ductile cast iron. The 2D nodule counts have been converted into 3D nodule count by using Finite Difference Method (FDM). Particles having a diameter smaller than 5 µm should be neglected in the nodule count as these ar......Graphite nodule count and size distribution have been analysed in thin walled ductile cast iron. The 2D nodule counts have been converted into 3D nodule count by using Finite Difference Method (FDM). Particles having a diameter smaller than 5 µm should be neglected in the nodule count...... as these are inclusions and micro porosities that do not influence the solidification morphology. If there are many small graphite nodules as in thin walled castings only 3D nodule count calculated by FDM will give reliable results. 2D nodule count and 3D nodule count calculated by simple equations will give too low...

SEALING LARGE-DIAMETER CAST-IRON PIPE JOINTS UNDER LIVE CONDITIONS

Energy Technology Data Exchange (ETDEWEB)

Kiran M. Kothari; Gerard T. Pittard

2005-04-01

Utilities in the U.S. operate over 75,000 km (47,000 miles) of old cast-iron pipes for gas distribution. The bell-and-spigot joints that connect pipe sections together tend to leak as these pipes age. Current repair practices are costly and highly disruptive. The objective of this program is to design, test and commercialize a robotic system capable of sealing multiple cast-iron bell and spigot joints from a single pipe entry point. The proposed system will perform repairs while the pipe remains in service by traveling through the pipe, cleaning each joint surface, and installing a stainless-steel sleeve lined with an epoxy-impregnated felt across the joint. This approach will save considerable time and labor, avoid traffic disruption, and eliminate any requirement to interrupt service to customers (which would result in enormous expense to utilities). Technical challenges include: (1) repair sleeves must compensate for diametric variation and eccentricity of old cast-iron pipes; (2) the assembly must travel long distances through pipes containing debris; (3) the pipe wall must be effectively cleaned in the immediate area of the joint to assure good bonding of the sleeve; and (4) an innovative bolt-on entry fitting is required to conduct repair operations on live mains. The development effort is divided into eleven tasks. Task 1 (Program Management) and Task 2 (Establishment of Detailed Design Specifications) were completed previously. Task 3 (Design and Fabricate Ratcheting Stainless-Steel Repair Sleeves) has progressed to installing prototype sleeves in test cast-iron pipe segments. Efforts in the current quarter continued to be focused on Tasks 4-8. Highly valuable lessons were learned from field tests of the 4-inch gas pipe repair robot in cast-iron pipe at Public Service Electric & Gas. (These field tests were conducted and reported previously.) Several design issues were identified which need to be implemented in both the small- and large-diameter repair

Influencing factors on as-cast and heat treated 400-18 ductile iron grade characteristics

Directory of Open Access Journals (Sweden)

I. Riposan

2007-11-01

Full Text Available As-cast and heat-treated 400-18 ductile iron (DI grade was obtained in different foundry conditions, as metallic charge, Mg-treatment alloy and inoculation. It was found that the Pearlitic Influence Factor (Px and Antinodulizing Complex Factor (K1 have an important influence on property of DI, depending on the Mn and P level, the metallurgical quality of iron melt, rare earth (RE and inoculation. It was also found that the influence of Mn is depended on the phosphorus and residual elements level in ductile iron. Less than 0.03%P and 0.2%Mn and Px2.0 determines presence of pearlite in as-cast structure, while ferrite structure is obtained after a short annealing heat treatment. Lower level of phosphorus (P1.2. Si has a significant influence on the mechanical properties of heat treated ductile irons: an important decreasing of elongation level and a moderate increasing of yield and tensile strength and their ratio in 150-170 HB typical hardness field. A typical final chemical composition for as-cast 400-18 ductile iron could include 3.5%-3.7%C, 2.4%-2.5%Si, max.0.18%Mn, max.0.025%P, max.0.01%S, 0.04%-0.05%Mgres. for Px<1.5 and K1<1.1. High purity pig iron, RE-bearing FeSiMg and powerful inoculant are also recommended.

Microstructures and formation mechanism of hypoeutectic white cast iron by isothermal electromagnetic rheocast process

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Zhang Wanning

2010-05-01

Full Text Available An investigation was made on the evolution of microstructures of hypoeutectic white cast iron slurry containing 2.5wt.%C and 1.8wt.%Si produced by rheocasting in which the solidifying alloy was vigorously agitated by electromagnetic stirrer during isothermal cooling processes. The results indicated that under the proper agitating temperatures and speeds applied, the dendrite structures in white cast iron slurry were gradually evolved into spherical structures during a certain agitating time. It also revealed that the bent dendrites were formed by either convection force or by the growth of the dendrites themselves in the bending direction; then, as they were in solidifying, they were gradually being alternated into separated particles and into more spherical structures at the end of the isothermal cooling process. Especially, the dendrites were granulated as the bending process proceeding, which suggested that they were caused by unwanted elements such as sulfur and phosphor usually contained in engineering cast iron. Convective flow of the melt caused corrosion on the dendritic segments where they were weaker in strength and lower in melting temperature because of higher concentration of sulfur or phosphor. And the granulation process for such dendrites formed in the melt became possible under the condition. Certainly, dendrite fragments are another factors considerable to function for spherical particles formation. A new mechanism, regarding to the rheocast structure formation of white cast iron, was suggested based on the structural evolution observed in the study.

Adsorption studies of water on copper, nickel, and iron: assessment of the polarization model

International Nuclear Information System (INIS)

Lee, S.; Staehle, R.W.

1997-01-01

In the atmospheric corrosion of copper, nickel, and iron, the adsorption of water affects the corrosion rates. Knowledge of water adsorption and metal oxyhydroxide formation is important in understanding the atmospheric corrosion process. The purposes of the present research were (i) to measure the adsorption of water on metal surfaces as a function of temperature and relative humidity (RH) and (ii) to assess Bradley's polarization model of adsorption. In the present research, the quartz-crystal microbalance (QCM) technique was used to measure the mass changes of copper, nickel, and iron at 0 to 100% relative humidity and 7 to 90 C under nitrogen and air environments. Less water was adsorbed on copper, nickel, and iron which form oxides than on gold. The amount of water adsorption was similar on copper, nickel, and iron under N 2 and air carrier gases. Functional relationship was first proposed as a way to include dipole/induced dipole interactions between the adsorbents and water layers. (orig.)

Ultrasonic testing of large blocks for prestressed cast iron pressure vessels

International Nuclear Information System (INIS)

Stelling, H.A.

1979-01-01

Ultrasonic tests were made on plate specimen and large blocks of perlit cast iron with lamellar graphite. Aims of the investigations were the control of material porperties, the flaw detection and flaw classification. The material properties were classified by sound velocity and attenuation measurements. Flaw detection and flaw size estimation methods were modified with regard to the acoustic properties, the microstructure and the reflectivity of typical flaws in castings. Special localisation and flaw size estimation techniques are discussed. (orig.)

Partial electron beam hardening of cast iron camshafts

Energy Technology Data Exchange (ETDEWEB)

Csizmazia, A.; Reti, T. [Szechenyi Istvan Univ., Gyoer (Hungary); Horvath, M.; Olah, I. [Audi Hungaria Motor Kft., Gyoer (Hungary)

2005-07-01

In order to improve the local surface properties (hardness, wear and contact fatigue resistance) of cast iron camshafts, detailed experiments with partial electron beam hardening have been performed. It was found that the required case depth of 0.3-0.5 mm and surface hardness of 600-700 HV can be achieved by using appropriately selected, computer-controlled processing parameters (angular speed, specific energy input, beam deflection). (orig.)

Manufacturing of thin walled near net shape iron castings

DEFF Research Database (Denmark)

Larsen, Per Leif

2003-01-01

The demand for near net shape thin walled iron castings is growing. This has several reasons, the main one is the need for lowering the fuel consumption of cars; the easiest way to do that is to lower the weight of the cars. The best way to do this was for a period of time believed...

Sputtering and emission intensity of cast irons with different metallurgical structures in a Grimm glow lamp

International Nuclear Information System (INIS)

Fujita, M.; Kashima, J.; Naganuma, K.

1981-01-01

The cathodic sputtering and emission intensities for the white, gray and malleable cast irons in the Grimm glow lamp are discussed. The intensities of the Fe 247.98-nm line for the samples of the three types depend linearly on the electrical power but the slopes of the plots differ. The intensity of the carbon line at 247.86 nm for malleable cast iron is weaker than those for the others. Sputtering is influenced by the form of the graphite, which can lead to distortion of the electrical field. Graphite on malleable cast iron is sputtered not only as atomic carbon but also as moieties containing several carbon atoms. The higher the supplied voltage, the shorter the time for the intensities of the Fe I and C I lines to reach constant values. (Auth.)

A reliable and consistent production technology for high volume compacted graphite iron castings

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Liu Jincheng

2014-07-01

Full Text Available The demands for improved engine performance, fuel economy, durability, and lower emissions provide a continual challenge for engine designers. The use of Compacted Graphite Iron (CGI has been established for successful high volume series production in the passenger vehicle, commercial vehicle and industrial power sectors over the last decade. The increased demand for CGI engine components provides new opportunities for the cast iron foundry industry to establish efficient and robust CGI volume production processes, in China and globally. The production window range for stable CGI is narrow and constantly moving. Therefore, any one step single addition of magnesium alloy and the inoculant cannot ensure a reliable and consistent production process for complicated CGI engine castings. The present paper introduces the SinterCast thermal analysis process control system that provides for the consistent production of CGI with low nodularity and reduced porosity, without risking the formation of flake graphite. The technology is currently being used in high volume Chinese foundry production. The Chinese foundry industry can develop complicated high demand CGI engine castings with the proper process control technology.

Evaluation of the Mechanical Properties of Gray Cast Iron Using Electrical Resistivity Measurement

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Bieroński M.

2016-12-01

Full Text Available In this paper an attempt to determine the relationship between the electrical resistivity and the tensile strength and hardness of cast iron of carbon equivalent in the range from 3.93% to 4.48%. Tests were performed on the gray cast iron for 12 different melts with different chemical composition. From one melt poured 6 samples. Based on the study of mechanical and electro-resistive determined variation characteristics of tensile strength, hardness and resistivity as a function of the carbon equivalent. Then, regression equations were developed as power functions describing the relationship between the resistivity of castings and their tensile strength and hardness. It was found a high level of regression equations to measuring points, particularly with regard to the relationship Rm=f(ρ. The obtained preliminary results indicate the possibility of application of the method of the resistance to rapid diagnostic casts on the production line, when we are dealing with repeatable production, in this case non variable geometry of the product for which it has been determinated before a regression equation.

The low-aluminium cast iron of reduced silicon content treated with cerium mischmetal

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M. S. Soiński

2008-07-01

Full Text Available The work presents the effect of cerium mischmetal used in quantities of 0.1 and 0.2 wt-% and ferrosilicon used in quantities from 0.5% to 1.5% on the alloy matrix and the shape of graphite precipitates in the low-aluminium cast iron from seven heats, basing on the examination of its structure. The hypereutectic cast iron of the relatively high carbon content (4.0÷4.2% at the prior-to-treatment silicon and manganese content equal to ca. 0.6% and ca. 0.04%, respectively, has been examined.It has been found that the performed treatment leads to the change in the alloy matrix from the nearly almost pearlitic to the ferritic-pearlitic one accompanied by changes in the shape of graphite precipitates. Due to applying both of the mentioned substances in the above stated amounts the graphite precipitates in cast iron have taken the shape of nodular and vermicular ones, and no presence of flake graphite has been revealed. A quantitative analysis of the performed treatment i.e. determining the fractions of graphite precipitates of different shapes has been possible by means of a computer image analyser.

Phormidium autumnale Growth and Anatoxin-a Production under Iron and Copper Stress

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Francine M. J. Harland

2013-12-01

Full Text Available Studies on planktonic cyanobacteria have shown variability in cyanotoxin production, in response to changes in growth phase and environmental factors. Few studies have investigated cyanotoxin regulation in benthic mat-forming species, despite increasing reports on poisoning events caused by ingestion of these organisms. In this study, a method was developed to investigate changes in cyanotoxin quota in liquid cultures of benthic mat-forming cyanobacteria. Iron and copper are important in cellular processes and are well known to affect growth and selected metabolite production in cyanobacteria and algae. The effect of iron (40–4000 μg L−1 and copper (2.5–250 μg L−1 on growth and anatoxin-a quota in Phormidium autumnale was investigated in batch culture. These concentrations were chosen to span those found in freshwater, as well as those previously reported to be toxic to cyanobacteria. Anatoxin-a concentrations varied throughout the growth curve, with a maximum quota of between 0.49 and 0.55 pg cell−1 measured within the first two weeks of growth. Growth rates were significantly affected by copper and iron concentrations (P < 0.0001; however, no statistically significant difference between anatoxin-a quota maxima was observed. When the iron concentrations were 800 and 4000 μg L−1, the P. autumnale cultures did not firmly attach to the substratum. At 250 μg L−1 copper or either 40 or 4000 μg L−1 iron, growth was suppressed.

Analysis of serum copper and iron levels in oral submucous fibrosis patients: A case–control study

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Harshal Kumar

2016-01-01

Full Text Available Background: Oral submucous fibrosis (OSF is a chronic debilitating disease and a potentially malignant disorder of the oral cavity. The pathogenesis of the disease is not well established. Trace elements such as copper and iron play an important role in the pathogenesis of OSF. Estimation of these elements in serum of the patients may be helpful in understanding the pathologic mechanism. Therefore, a study was carried out to analyze the level of serum copper and iron in the population of Central India. Materials and Methods: A case–control study was carried out on 35 patients with clinically diagnosed of OSF and 35 healthy controls. OSF patients were categorized by clinical staging. Serum copper and iron concentrations were measured by atomic absorption spectrophotometry. Results: Results of the study shows that the mean serum copper concentration was greater in study group (133.3 ± 19.2 compared to control group (113.9 ± 22.1 and the mean serum iron was lower in study group (116.0 ± 24.1 compared to control group (128.2 ± 23.4. The result obtained was statistically significant. The serum copper level increases as the clinical staging of OSF progresses, whereas serum iron level decreases as clinical staging progresses. Conclusion: There was an increase in copper level and decrease in iron level in study group compared to control group; this suggests that there is an increase in copper level with the advancement of clinical staging of OSF.

The effect of silver (Ag) addition to mechanical and electrical properties of copper alloy (Cu) casting product

Science.gov (United States)

Felicia, Dian M.; Rochiem, R.; Laia, Standley M.

2018-04-01

Copper have good mechanical properties and good electrical conductivities. Therefore, copper usually used as electrical components. Silver have better electrical conductivities than copper. Female contact resistor is one of the electrical component used in circuit breaker. This study aims to analyze the effect of silver addition to hardness, strength, and electric conductivity properties of copper alloy. This study uses variation of 0; 0.035; 0.07; 0.1 wt. % Ag (silver) addition to determine the effect on mechanical properties and electrical properties of copper alloy through sand casting process. Modelling of thermal analysis and structural analysis was calculated to find the best design for the sand casting experiments. The result of Cu-Ag alloy as cast will be characterized by OES test, metallography test, Brinell hardness test, tensile test, and LCR meter test. The result of this study showed that the addition of silver increase mechanical properties of Cu-Ag. The maximum hardness value of this alloy is 83.1 HRB which is Cu-0.01 Ag and the lowest is 52.26 HRB which is pure Cu. The maximum strength value is 153.2 MPa which is Cu-0.07 Ag and the lowest is 94.6 MPa which is pure Cu. Silver addition decrease electrical properties of this alloy. The highest electric conductivity is 438.98 S/m which is pure Cu and the lowest is 52.61 S.m which is Cu-0.1 Ag.

Examination of Cast Iron Material Properties by Means of the Nanoindentation Method

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Trytek A.

2012-12-01

Full Text Available The paper presents results of examination of material parameters of cast iron with structure obtained under rapid resolidification conditions carried out by means of the nanoindentation method.

The forty years of vermicular graphite cast iron development in China (PartⅠ

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CHEN Zheng-de

2007-05-01

Full Text Available In China, the research and development of vermicular graphite cast iron (VGCI as a new type of engineering material, were started in the same period as in other developed countries; however, its actual industrial application was even earlier. In China, the deep and intensive studies on VGCI began as early as the 1960s. According to the incomplete statistics to date, more than 600 papers on VGCI have been published by Chinese researchers and scholars at national and international conferences, and in technical journals. More than ten types of production methods and more than thirty types of treatment alloy have been studied. Formulae for calculating the critical addition of treatment alloy required to produce VGCI have been put forward, and mechanisms for explaining the formation of dross during treatment were brought forward. The casting properties, metallographic structure, mechanical and physical properties and machining performance of VGCI, as well as the relationships between them, have all been studied in detail. The Chinese Standards for VGCI and VGCI metallographic structure have been issued. In China, the primary crystallization of VGCI has been studied by many researchers and scholars. The properties of VGCI can be improved by heat treatment and addition of alloying elements enabling its applications to be further expanded. Hundreds of kinds of VGCI castings have been produced and used in vehicles, engines, mining equipment, metallurgical products serviced under alternating thermal load, machinery, hydraulic components, textile machine parts and military applications. The heaviest VGCI casting produced is 38 tons and the lightest is only 1 kg. Currently, the annual production of the VGCI in China is about 200 000 tons. The majority of castings are made from cupola iron without pre-treatment, however, they are also produced from electric furnaces and by duplex melting from cupolaelectric furnaces or blast furnace-electric furnace

Impairment of interrelated iron- and copper homeostatic mechanisms in brain contributes to the pathogenesis of neurodegenerative disorders

DEFF Research Database (Denmark)

Skjørringe, Tina; Møller, Lisbeth Birk; Moos, Torben

2012-01-01

is strictly regulated, and concordantly protective barriers, i.e., the blood-brain barrier (BBB) and the blood-cerebrospinal fluid (CSF) barrier (BCB) have evolved to separate the brain environment from the circulation. The uptake mechanisms of the two metals interact. Both iron deficiency and overload lead...... involved in iron transport. Iron and copper are mainly taken up at the BBB, but the BCB also plays a vital role in the homeostasis of the two metals, in terms of sequestering, uptake, and efflux of iron and copper from the brain. Inside the brain, iron and copper are taken up by neurons and glia cells...

Analysis of cracking in glass molds made of cast iron

Science.gov (United States)

Leushin, I. O.; Chistyakov, D. G.

2014-09-01

The cracking in the parts of cast iron molds intended for glass is considered, and this cracking substantially affects the operation of glass-blowing equipment, maintainability, and the replacement of mold sets. The processes that cause cracking in the parts of glass molds and initiate crack growth are studied.

Aspects of the design and structural analysis of the prestressed cast iron nuclear reactor pressure vessel

International Nuclear Information System (INIS)

Thomas, R.G.

1978-09-01

The development of the prestressed cast iron nuclear reactor pressure vessel up to the present time is reviewed, and the current status is outlined of the techniques used for its structural analysis. Details of the manufacturing processes involved in the production of the castings, and problems of inspecting them to the standards required for a nuclear application are discussed. A method for the detailed modelling of the cast iron segments is proposed, using the finite element technique with plate bending elements, and criteria for obtaining accurate results are derived. The application of the technique to the analysis of a single cast segment situated in the wall of a PCIPV has enabled an accurate determination of the stress field to be made. Account is taken of the effect of the vessel displacements on the tendon stresses at normal vault pressure and at high overpressure. Studies by this method of several different casting designs have identified favourable features, which have been incorporated into an optimised design. The sensitivity of the structure to a machining error in a casting and to the failure or removal of circumferential and axial tendons is examined, making use of axisymmetric and three-dimensional global finite element solutions to provide boundary conditions for detailed local analyses. Some aspects of the economics of the cast iron reactor pressure vessel are discussed, and recommendations are made for further research in areas relevant to the assessment of the reliability of the vessel. (author)

Mechanical properties of ductile cast iron and cast steel for intermediate level waste transport containers

International Nuclear Information System (INIS)

Gray, I.L.S.; Sievwright, R.W.T.; Egid, B.; Ajayi, F.; Donelan, P.

1994-01-01

UK Nirex Ltd is developing Type B re-usable shielded transport containers (RSTCs) in a range of shielding thicknesses to transport intermediate level radioactive waste (ILW) to a deep repository. The designs are of an essentially monolithic construction and rely principally on the plastic flow of their material to absorb the energies involved in impact events. Nirex has investigated the feasibility of manufacturing the RSTCs from ductile cast iron (DCI) or cast steel instead of from forgings, since this would bring advantages of reduced manufacturing time and costs. However, cast materials are perceived to lack toughness and ductility and it is necessary to show that sufficient fracture toughness can be obtained to preclude brittle failure modes, particularly at low temperatures. The mechanical testing carried out as part of that programme is described. It shows how the measured properties have been used to demonstrate avoidance of brittle fracture and provide input to computer modelling of the drop tests. (author)

Microstructure and properties of cast iron after laser surface hardening

Directory of Open Access Journals (Sweden)

Stanislav

2013-12-01

Full Text Available Laser surface hardening of cast iron is not trivial due to the material’s heterogeneity and coarse-grained microstructure, particularly in massive castings. Despite that, hardening of heavy moulds for automotive industry is in high demand. The present paper summarises the findings collected over several years of study of materials structure and surface properties. Phase transformations in the vicinity of graphite are described using examples from production of body parts in automotive industry. The description relates to formation of martensite and carbide-based phases, which leads to hardness values above 65 HRC and to excellent abrasion resistance.

The Influence of Different Assist Gases on Ductile Cast Iron Cutting by CO2 Laser

Directory of Open Access Journals (Sweden)

Meško J.

2017-12-01

Full Text Available This article deals with the technology and principles of the laser cutting of ductile cast iron. The properties of the CO2 laser beam, input parameters of the laser cutting, assist gases, the interaction of cut material and the stability of cutting process are described. The commonly used material (nodular cast iron - share of about 25% of all castings on the market and the method of the laser cutting of that material, including the technological parameters that influence the cutting edge, are characterized. Next, the application and use of this method in mechanical engineering practice is described, focusing on fixing and renovation of mechanical components such as removing the inflow gate from castings with the desired quality of the cut, without the further using of the chip machining technology. Experimental samples from the nodular cast iron were created by using different technological parameters of laser cutting. The heat affected zone (HAZ, its width, microstructure and roughness parameter Pt was monitored on the experimental samples (of thickness t = 13 mm. The technological parameters that were varied during the experiments included the type of assist gases (N2 and O2, to be more specific the ratio of gases, and the cutting speed, which ranged from 1.6 m/min to 0.32 m/min. Both parameters were changed until the desired properties were achieved.

Corrosion resistance of cast irons and titanium alloys as reference engineered metal barriers for use in basalt geologic storage: a literature assessment

International Nuclear Information System (INIS)

Charlot, L.A.; Westerman, R.E.

1981-07-01

A survey and assessment of the literature on the corrosion resistance of cast irons and low-alloy titanium are presented. Selected engineering properties of cast iron and titanium are briefly described; however, the corrosion resistance of cast iron and titanium in aqueous solutions or in soils and their use in a basalt repository are emphasized. In evaluating the potential use of cast iron and titanium as structural barrier materials for long-lived nuclear waste packages, it is assumed that titanium has the general corrosion resistance to be used in relatively thin cross sections whereas the cost and availability of cast iron allows its use even in very thick cross sections. Based on this assumption, the survey showed that: The uniform corrosion of low-alloy titanium in a basalt environment is expected to be extremely low. A linear extrapolation of general corrosion rates with an added corrosion allowance suggests that a 3.2- to 6.4-mm-thick wall may have a life of 1000 yr. Pitting and crevice corrosion are not likely corrosion modes in basalt ground waters. It is also unlikely that stress corrosion cracking (SCC) will occur in the commercially pure (CP) titanium alloy or in palladiumor molybdenum-alloyed titanium materials. Low-alloy cast irons may be used as barrier metals if the environment surrounding the metal keeps the alloy in the passive range. The solubility of the corrosion product and the semipermeable nature of the oxide film allow significant uniform corrosion over long time periods. A linear extrapolation of high-temperature corrosion rates on carbon steels and corrosion rates of cast irons in soils gives an estimated metal penetration of 51 to 64 mm after 1000 yr. A corrosion allowance of 3 to 5 times that suggests that an acceptable cast iron wall may be from 178 to 305 mm thick. Although they cannot be fully assessed, pitting and crevice corrosion should not affect cast iron due to the ground-water chemistry of basalt

Shape Accuracy of Iron Precision Castings in Terms of Ceramic Moulds Physical Properties Anisotropy

Directory of Open Access Journals (Sweden)

Biernacki R.

2014-03-01

Full Text Available While analyzing shape accuracy of ferroalloy precision castings in terms of ceramic moulds physical anisotropy, low-alloy steel castings ("cover" and cast iron ("plate" were included. The basic parameters in addition to the product linear shape accuracy are flatness deviations, especially due to the expanded flat surface which is cast plate. For mentioned castings surface micro-geometry analysis was also carried, favoring surface load capacity tp50 for Rmax = 50%. Surface load capacity tp50 obtained for the cast cover was compared with machined product, and casting plate surface was compared with wear part of the conveyor belt. The results were referred to anisotropy of ceramic moulds physical properties, which was evaluated by studying ceramic moulds samples in computer tomography equipment Metrotom 800

Hereditary iron and copper deposition

DEFF Research Database (Denmark)

Aaseth, Jan; Flaten, Trond Peder; Andersen, Ole

2007-01-01

Hereditary deposition of iron (primary haemochromatosis) or copper (Wilson's disease) are autosomal recessive metabolic disease characterized by progressive liver pathology and subsequent involvement of various other organs. The prevalence of primary haemochromatosis is approximately 0.5%, about......, they may be inadequate in patients diagnosed so late that extensive body deposits of metal have been developed. The main research needs in this field are to further clarify molecular mechanisms of disease progression and to develop new chelators that are more effective and less toxic than those presently...

The effect of iron and copper impurities on the wettability of sphalerite (110) surface.

Science.gov (United States)

Simpson, Darren J; Bredow, Thomas; Chandra, Anand P; Cavallaro, Giuseppe P; Gerson, Andrea R

2011-07-15

The effect of impurities in the zinc sulfide mineral sphalerite on surface wettability has been investigated theoretically to shed light on previously reported conflicting results on sphalerite flotation. The effect of iron and copper impurities on the sphalerite (110) surface energy and on the water adsorption energy was calculated with the semi-empirical method modified symmetrically orthogonalized intermediate neglect of differential overlap (MSINDO) using the cyclic cluster model. The effect of impurities or dopants on surface energies is small but significant. The surface energy increases with increasing surface iron concentration while the opposite effect is reported for increasing copper concentration. The effect on adsorption energies is much more pronounced with water clearly preferring to adsorb on an iron site followed by a zinc site, and copper site least favorable. The theoretical results indicate that a sphalerite (110) surface containing iron is more hydrophilic than the undoped zinc sulfide surface. In agreement with the literature, the surface containing copper (either naturally or by activation) is more hydrophobic than the undoped surface. Copyright © 2011 Wiley Periodicals, Inc.

The Influence of Corrosion Attack on Grey Cast Iron Brittle‑Fracture Behaviour and Its Impact on the Material Life Cycle

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Jiří Švarc

2017-01-01

Full Text Available The paper is concerned with brittle‑fracture behaviour of grey cast iron attacked by corrosion and its impact on the life cycle of a spare part made of grey cast iron. In a corrosion chamber, outdoor climatic conditions (temperature and relative air humidity were simulated in which degradation processes, induced by material corrosion, degrading mechanical properties of a material and possibly leading to irreversible damage of a machine component, occur in the material of maintenance vehicles that are out of operation for the period of one year. The corrosion degradation of grey cast iron, which the spare parts constituting functional parts of an engine are made of grey cast iron, is described with regard to brittle‑fracture behaviour of the material. For the description of corrosion impact on grey cast iron, an instrumented impact test was employed. A corrosion degradation effect on grey cast iron was identified based on measured values of total energy, macro plastic deformation limit, initiation force of unstable crack propagation and force exerted on unstable crack arrest. In the first part of the experiment, a corrosion test of the material concerned was simulated in a condensation chamber; in the second part of the experiment, research results are provided for the measured quantities describing the material brittle‑fracture behaviour; this part is supplemented with a table of results and figures showing the changes in the values of the measured quantities in relation to test temperatures. In the discussion part, the influence of corrosion on the values of unstable crack initiation and arrest forces is interpreted. In the conclusion, an overview of the most significant research findings concerning the impact of corrosion on the life cycle of grey cast iron material is provided.

Eutectic cell and nodule count as the quality factors of cast iron

Directory of Open Access Journals (Sweden)

E. Fraś

2008-10-01

Full Text Available In this work the predictions based on a theoretical analysis aimed at elucidating of eutectic cell count or nodule counts N wereexperimentally verified. The experimental work was focused on processing flake graphite and ductile iron under various inoculationconditions in order to achieve various physicochemical states of the experimental melts. In addition, plates of various wall thicknesses, s were cast and the resultant eutectic cell or nodule counts were established. Moreover, thermal analysis was used to find out the degree of maximum undercooling for the graphite eutectic, Tm. A relationship was found between the eutectic cell or nodule count and the maximum undercooling Tm.. In addition it was also found that N can be related to the wall thickness of plate shaped castings. Finally, the present work provides a rational for the effect of technological factors such as the melt chemistry, inoculation practice, and holding temperature and time on the resultant cell count or nodule count of cast iron. In particular, good agreement was found between the predictions of the theoretical analysis and the experimental data.

Characterization of copper oxides, iron oxides, and zinc copper ferrite desulfurization sorbents by X-ray photoelectron spectroscopy and scanning electron microscopy

Science.gov (United States)

Siriwardane, Ranjani V.; Poston, James A.

1993-05-01

Characterization of copper oxides, iron oxides, and zinc copper ferrite desulfurization sorbents was performed by X-ray photoelectron spectroscopy and scanning electron microscopy/energy-dispersive spectroscopy at temperatures of 298 to 823 K. Analysis of copper oxides indicated that the satellite structure of the Cu22p region was absent in the Cu(I) state but was present in the Cu(II) state. Reduction of CuO at room temperature was observed when the ion gauge was placed close to the sample. The satellite structure was absent in all the copper oxides at 823 K in vacuum. Differentiation of the oxidation state of copper utilizing both Cu(L 3M 4,5M 4,5) X-ray-induced Auger lines and Cu2p satellite structure, indicated that the copper in zinc copper ferrite was in the + 1 oxidation state at 823 K. This + 1 state of copper was not significantly changed after exposure to H 2, CO, and H 2O. There was an increase in Cu/Zn ratio and a decrease in Fe/Zn ratio on the surface of zinc copper ferrite at 823 K compared to that at room temperature. These conditions of copper offered the best sulfidation equilibrium for the zinc copper ferrite desulfurization sorbent. Analysis of iron oxides indicated that there was some reduction of both Fe 2O 3 and FeO at 823K. The iron in zinc copper ferrite was similar to that of Fe 2O 3 at room temperature but there was some reduction of this Fe(III) state to Fe(II) at 823 K. This reduction was more enhanced in the presence of H 2 and CO. Reduction to Fe(II) may not be desirable for the lifetime of the sorbent.

Effects of Si on microstructure and phase transformation at elevated temperatures in ferritic white cast irons

Energy Technology Data Exchange (ETDEWEB)

Wiengmoon, A., E-mail: ampornw@nu.ac.th [Department of Physics, Faculty of Science, Naresuan University, Phitsanulok 65000 (Thailand); Pearce, J.T.H. [Panyapiwat Institute of Management, Nonthaburi 11120 (Thailand); Nusen, S.; Chairuangsri, T. [Department of Industrial Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai 50200 (Thailand)

2016-10-15

The effects of Si on microstructure and phase transformation at elevated temperature of ferritic 31wt.%Cr-1.1wt.%C white cast irons with up to 3wt.%Si have been studied. Applications of these irons include parts requiring heat resistance at elevated temperature. The irons were produced by sand casting. The microstructure in as-cast condition and after being subjected to high temperature (700 to 1000 °C) was investigated by light microscopy, X-ray diffraction, and electron microscopy. The results revealed that the as-cast microstructure consisted mainly of primary ferrite dendrites and eutectic (ferrite + M{sub 7}C{sub 3}). Si promotes M{sub 7}C{sub 3}-to-M{sub 23}C{sub 6} transformation in the irons subjected to transformation at elevated temperature, but no sigma phase was found. The extent of M{sub 7}C{sub 3}-to-M{sub 23}C{sub 6} transformation increases proportional to the increasing transformation temperature, holding time and Si content in the irons. For the iron with 1.0wt.%Si content after holding at elevated temperatures, martensite was also found, which could be attributed to carbon accretion effects in eutectic ferrite. Si was incorporated in M{sub 23}C{sub 6} such that M{sub 23}C{sub 6} containing Si can show darker contrast under SEM-BEI as compared to M{sub 7}C{sub 3}; this is the opposite to what has been observed for the cases of typical M{sub 23}C{sub 6} and M{sub 23}C{sub 6} containing Mo or W. The results obtained are important to understand the change in properties of ferritic, high chromium irons containing Si subjected to elevated temperature.

77 FR 17119 - Pipeline Safety: Cast Iron Pipe (Supplementary Advisory Bulletin)

Science.gov (United States)

2012-03-23

... DEPARTMENT OF TRANSPORTATION Pipeline and Hazardous Materials Safety Administration [Docket No... national attention and highlight the need for continued safety improvements to aging gas pipeline systems... 26, 1992) covering the continued use of cast iron pipe in natural gas distribution pipeline systems...

Determination of copper and iron in the human aqueous humor by atomic absorption spectrometer with graphite furnace

International Nuclear Information System (INIS)

Iqbal, Z.; Mohammad, Z.; Shah, M.T.; Saeed, M.; Imdadullah

1999-01-01

The concentration of copper and iron was determined in human aqueous humor using atomic absorption spectrophotometer equipped with graphite furnace. The mean (+- SEM) concentrations of copper (n=16) and iron (n=14) were 0.0234 -+ 0.0045 mu g.ml/sup -1/ and 0.045 -+ 0.0092 mu.ml/sup -1/ respectively. In male and female, the concentrations of copper (p< 0.82) and iron (p<0.38) were not significantly different. (author)

Electroerosion formation and technology of cast iron coatings on aluminum alloys

Directory of Open Access Journals (Sweden)

Smolentsev Vladislav P.

2017-01-01

Full Text Available At present in the course of designing basic production parts and industrial equipment designers pay more and more attention to aluminum alloys having a number of properties compared favorably with other materials. In particular, technological aluminum tool electrodes without coating in the presence of products of processing with alkali in the composition of operation environment are being destroyed at the expense of intensified material dissolution. It is shown in the paper that the method offered by the authors and covered by the patents on cast iron coating of products made of aluminum alloys, allows obtaining on a product surface the layers with high adhesion durability ensuring a high protection against destruction in the friction units including operation in hostile environment. Thereupon, aluminum, as compared with iron-based alloys used at manufacturing technological equipment for electrical methods of processing, has a high electrical and thermal conduction, its application will allow achieving considerable energy-saving in the course of parts production. A procedure for the design of a technological process of qualitative cast iron coatings upon aluminum tool electrodes and parts of basic production used in different branches of mechanical engineering is developed.

Crystallization and structure of chromium cast iron with addition of Mo and Ni

International Nuclear Information System (INIS)

Pietrowski, S.

1998-01-01

The aim of the presented paper is to show the results of examination of the crystallization process using the method of thermal-derivative analysis (ATD) and the structure examination of chromium cast iron, chromium molybdenum c. i. and chromium molybdenum nickel c.i. It was found that molybdenum in amount over 2 wt % causes the crystallization of eutectic carbides M 23 C 6 and M 6 C. The M 23 C 6 carbide crystallizes upon the crystallization of eutectic carbides M 3 C and M 7 C 3 . It is shown that ATD method facilitates both interpretation and control of the crystallization as well as formation of the cast iron structure at the solid state. (author)

MATH MODELING OF CAST FINE-GRAINED CONCRETE WITH INDUSTRIAL WASTES OF COPPER PRODUCTION

Directory of Open Access Journals (Sweden)

Tsybakin Sergey Valerievich

2017-10-01

Full Text Available Subject: applying mineral microfillers on the basis of technogenic wastes of non-ferrous metallurgy in the technology of cast and self-compacting concrete. The results of experiments of scientists from Russia, Kazakhstan, Poland and India show that copper smelting granulated slag can be used when grinding construction cements as a mineral additive up to 30 % without significantly reducing activity of the cements. However, there are no results of a comprehensive study of influence of the slag on plastic concrete mixtures. Research objectives: establishment of mathematical relationship of the influence of copper slag on the compressive strength and density of concrete after 28 days of hardening in normal conditions using the method of mathematical design of experiments; statistical processing of the results and verification of adequacy of the developed model. Materials and methods: mathematical experimental design was carried out as a full 4-factor experiment using rotatable central composite design. The mathematical model is selected in the form of a polynomial of the second degree using four factors of the response function. Results: 4-factor mathematical model of concrete strength and density after curing is created, regression equation is derived for dependence of the 28-days strength function and density on concentration of the cement stone, true water-cement ratio, dosage of fine copper slag and superplasticizer on the basis of ether polycarboxylates. Statistical processing of the results of mathematical design of experiments is carried out, estimate of adequacy of the constructed mathematical model is obtained. Conclusions: it is established that introduction of copper smelting slag in the range of 30…50 % by weight of cement positively affects the strength of concrete when used together with the superplasticizer. Increasing the dosage of superplasticizer in excess of 0.16 % of the dry component leads to a decrease in the strength of cast

Effect of Heat treatment on Hardness and Corrosion Resistance of Super Cast Iron

Energy Technology Data Exchange (ETDEWEB)

Lee, Roun; Kim, Young Sik [Andong National University, Andong (Korea, Republic of)

2014-07-15

In fossil-fuel-fired power plants, a variety of pollutants are produced from the combustion of conventional fuels such as coal, oil and gas. Major component of such pollution are ash and corrosive chemicals, which also destroy pumps and piping; by causing erosion/corrosion, pitting, and wear. In order to over come such damage, materials with high hardness and high corrosion resistance are needed. In this work, we melted super-cast-iron with excellent corrosion resistance and high hardness. To elucidate the effect of heat treatment, microstructural analysis, hardness measurement, and corrosion tests were performed. Test results revealed that the super-cast-iron had several tens better corrosion resistance than 316 L stainless steel, and it also had a high surface hardness (> HRC45). High hardness, in spite of its low carbon content (0.74%C), could resulted from a hardening heat treatment to precipitate sufficient Cr{sub 7}C{sub 3} and Cr{sub 2}3C{sub 6}. Also, it was concluded that the excellent corrosion resistance of the super-cast-iron was due to the increase of the relative chromium content by minimizing the carbon content, and by the enhancement of passive film by the addition of Cr, Mo, Cu, and W.

SEALING LARGE-DIAMETER CAST-IRON PIPE JOINTS UNDER LIVE CONDITIONS

Energy Technology Data Exchange (ETDEWEB)

Kiran M. Kothari; Gerard T. Pittard

2004-11-01

Utilities in the U.S. operate over 75,000 km (47,000 miles) of old cast-iron pipes for gas distribution. The bell-and-spigot joints that connect pipe sections together tend to leak as these pipes age. Current repair practices are costly and highly disruptive. The objective of this program is to design, test and commercialize a robotic system capable of sealing multiple castiron bell and spigot joints from a single pipe entry point. The proposed system will perform repairs while the pipe remains in service by traveling through the pipe, cleaning each joint surface, and installing a stainless-steel sleeve lined with an epoxy-impregnated felt across the joint. This approach will save considerable time and labor, avoid traffic disruption, and eliminate any requirement to interrupt service to customers (which would result in enormous expense to utilities). Technical challenges include: (1) repair sleeves must compensate for diametric variation and eccentricity of cast-iron pipes; (2) the assembly must travel long distances through pipes containing debris; (3) the pipe wall must be effectively cleaned in the immediate area of the joint to assure good bonding of the sleeve; and (4) an innovative bolt-on entry fitting is required to conduct repair operations on live mains. The development effort is divided into eleven tasks. Task 1 (Program Management) and Task 2 (Establishment of Detailed Design Specifications) were completed in prior quarters while Task 3 (Design and Fabricate Ratcheting Stainless-Steel Repair Sleeves) has progressed to installing prototype sleeves in cast iron test pipe segments. Efforts in this quarter continued to focus on Tasks 4-8, with significant progress made in each as well as field testing of the 4-inch gas pipe repair robot in cast iron pipe at Public Service Electric & Gas. The field tests were conducted August 23-26, 2004 in Oradell, New Jersey. The field tests identified several design issues which need to be implemented in both the small

Arsenic, chromium, copper, iron, manganese, lead, selenium and ...

African Journals Online (AJOL)

2014-05-20

May 20, 2014 ... Arsenic, chromium, copper, iron, manganese, lead, selenium and zinc in the ... and sediment were collected and trace element concentrations were measured with an ICP-MS. ..... Clay minerals are known to have high sorption affinities ..... sediment/water quality interaction with particular reference to the.

Influence of shrinkage porosity on fatigue performance of iron castings and life estimation method

Directory of Open Access Journals (Sweden)

Wei Liu

2016-01-01

Full Text Available Shrinkage porosity exists more or less in heavy castings, and it plays an important role in the fatigue behavior of cast materials. In this study, fatigue tests were carried out on the QT400-18 cast iron specimens containing random degrees of shrinkage porosity defect. Experimental results showed that the order of magnitude of life scattered from 103 to 106 cycles when the shrinkage percentage ranged from 0.67% to 5.91%. SEM analyses were carried out on the shrinkage porosity region. The inter-granular discontinuous, micro cracks and inclusions interfered with the fatigue sliding or hindering process. The slip in shrinkage porosity region was not as orderly as the ordinary continuous medium. The shrinkage porosity area on fracture surface (SPAFS and alternating stress intensity factor (ASIF were applied to evaluate the tendency of residual life distribution; their relationship was fitted by negative exponent functions. Based on the intermediate variable of ASIF, a fatigue life prediction model of nodular cast iron containing shrinkage porosity defects was established. The modeling prediction was in agreement with the experimental results.

Fatigue limit prediction of ferritic-pearlitic ductile cast iron considering stress ratio and notch size

Science.gov (United States)

Deguchi, T.; Kim, H. J.; Ikeda, T.

2017-05-01

The mechanical behavior of ductile cast iron is governed by graphite particles and casting defects in the microstructures, which can significantly decrease the fatigue strength. In our previous study, the fatigue limit of ferritic-pearlitic ductile cast iron specimens with small defects ((\\sqrt{{area}}=80˜ 1500{{μ }}{{m}})) could successfully be predicted based on the \\sqrt{{area}} parameter model by using \\sqrt{{area}} as a geometrical parameter of defect as well as the tensile strength as a material parameter. In addition, the fatigue limit for larger defects could be predicted based on the conventional fracture mechanics approach. In this study, rotating bending and tension-compression fatigue tests with ferritic-pearlitic ductile cast iron containing circumferential sharp notches as well as smooth specimens were performed to investigate quantitatively the effects of defect. The notch depths ranged 10 ˜ 2500 μm and the notch root radii were 5 and 50 μm. The stress ratios were R = -1 and 0.1. The microscopic observation of crack propagation near fatigue limit revealed that the fatigue limit was determined by the threshold condition for propagation of a small crack emanating from graphite particles. The fatigue limit could be successfully predicted as a function of R using a method proposed in this study.

EFFECT OF ALLOYING ON TEMPERATURE OF TRANSFORMATION «PEARLITE – AUSTENITE» IN COMPLEX-ALLOYED WHITE CAST IRONS

Directory of Open Access Journals (Sweden)

T. V. Pastukhova

2014-11-01

Full Text Available Purpose. Pearlite is not accepted in the microstructure of wear resistant steels and cast irons. To prevent the pearlite by means of appropriate selection of mode of quenching requires the knowledge of the temperature of the critical points Ac1 and Ac3 for various steels and cast irons. Purpose of work is determine the effect of V (5-10% and Cr (up to 9% on the temperature range of the phase-structural transformation "pearlite®austenite in the complex-alloyed V-Cr-Mn-Ni white cast irons with spheroidal vanadium carbides. Methodology. Nine Mg-treated cast irons smelted in laboratory furnace were used for investigation. The metallographic and optical dilatometric analysis methods as well as energy-dispersive spectroscopy were used. Findings. It is shown that in irons studied the critical point Ac1 is in a temperature range from 710-780 °C (lower limit up to 730-850 °C (upper limit. The data on the concentrations of chromium and vanadium in a matrix of iron are presented, the regression equation describing the effect of vanadium and chromium on the temperature limits of the transformation «pearlite ® austenite» are obtained. Originality. It is shown that increase the chromium content leads to growth of lower and upper limits of the temperature interval of transformation "pearlite ® austenite"; vanadium increases only the upper limit of the range. It was found that the effect of chromium on the critical point Ac1 is attributed to its solubility in the metallic matrix (concentration of Cr in the austenite reaches 7%; vanadium, due to its slight dissolution in the matrix (vanadium content does not exceed 1.75%, affects the critical point indirectly by increasing of chromium concentration in the matrix due to enhanced carbon sequestration in VC carbides. Practical value. The temperature ranges of heating for quenching of V-Cr-Mn-Ni cast irons with spheroidal vanadium carbides, which provides the formation of austenitic-martensitic matrix without

Investigation of Dendrite Coarsening in Complex Shaped Lamellar Graphite Iron Castings

Directory of Open Access Journals (Sweden)

Péter Svidró

2017-07-01

Full Text Available Shrinkage porosity and metal expansion penetration are two casting defects that appear frequently during the production of complex-shaped lamellar graphite iron components. These casting defects are formed during the solidification and usually form in the part of the casting which solidifies last. The position of the area that solidifies last is dependent on the thermal conditions. Test castings with thermal conditions like those existing in a complex-shaped casting were successfully applied to provoke a shrinkage porosity defect and a metal expansion penetration defect. The investigation of the primary dendrite morphology in the defected positions indicates a maximum intradendritic space, where the shrinkage porosity and metal expansion penetration defects appear. Moving away from the defect formation area, the intradendritic space decreases. A comparison of the intradendritic space with the simulated local solidification times indicates a strong relationship, which can be explained by the dynamic coarsening process. More specifically, long local solidification times facilitates the formation of a locally coarsened austenite morphology. This, in turn, enables the formation of a shrinkage porosity or a metal expansion penetration.

Estimation of integrity of cast-iron cask against impact due to free drop test, (1)

International Nuclear Information System (INIS)

Itoh, Chihiro

1988-01-01

Ductile cast iron is examined to use for shipping and storage cask from a economic point of view. However, ductile cast iron is considered to be a brittle material in general. Therefore, it is very important to estimate the integrity of cast iron cask against brittle failure due to impact load at 9 m drop test and 1 m derop test on to pin. So, the F.E.M. analysis which takes nonlinearity of materials into account and the estimation against brittle failure by the method which is proposed in this report were carried out. From the analysis, it is made clear that critical flaw depth (the minimum depth to initiate the brittle failure) is 21.1 mm and 13.1 mm in the case of 9 m drop test and 1 m drop test on to pin respectively. These flaw depth can be detected by ultrasonic test. Then, the cask is assured against brittle failure due to impact load at 9 m drop test and 1 m drop test on to pin. (author)

SEALING LARGE-DIAMETER CAST-IRON PIPE JOINTS UNDER LIVE CONDITIONS

Energy Technology Data Exchange (ETDEWEB)

Kiran M. Kothari, Gerard T. Pittard

2004-01-01

Utilities in the U.S. operate over 75,000 km (47,000 miles) of old cast-iron pipes for gas distribution. The bell-and-spigot joints that connect pipe sections together tend to leak as these pipes age. Current repair practices are costly and highly disruptive. The objective of this program is to design, test and commercialize a robotic system capable of sealing multiple cast iron bell and spigot joints from a single pipe entry point. The proposed system will perform repairs while the pipe remains in service by traveling through the pipe, cleaning each joint surface, and installing a stainless-steel sleeve lined with an epoxy-impregnated felt across the joint. This approach will save considerable time and labor, avoid traffic disruption, and eliminate any requirement to interrupt service to customers (which would result in enormous expense to utilities). Technical challenges include: (1) repair sleeves must compensate for diametric variation and eccentricity of cast-iron pipes; (2) the assembly must travel long distances through pipes containing debris; (3) the pipe wall must be effectively cleaned in the immediate area of the joint to assure good bonding of the sleeve; and (4) an innovative bolt-on entry fitting is required to conduct repair operations on live mains. The development effort is divided into eleven tasks. Task 1--Program Management and Task 2--were completed in prior quarters while Task 3--Design and Fabricate Ratcheting Stainless-Steel Repair Sleeves has progressed to installing prototype sleeves in cast iron test pipe segments. Efforts in this quarter continued to focus on Tasks 4--8, with significant progress made in each. Task 4 (Design, Fabricate and Test Patch Setting Robotic Train) progressed to the design of the control electronics and pneumatic system to inflate the bladder robotic patch setting module. Task 5 (Design & Fabricate Pipe-Wall Cleaning Robot Train with Pan/Zoom/Tilt Camera) continued with additional in-pipe testing required to

SEALING LARGE-DIAMETER CAST-IRON PIPE JOINTS UNDER LIVE CONDITIONS

Energy Technology Data Exchange (ETDEWEB)

Kiran M Kothari; Gerard T. Pittard

2004-07-01

Utilities in the U.S. operate over 75,000 km (47,000 miles) of old cast-iron pipes for gas distribution. The bell-and-spigot joints that connect pipe sections together tend to leak as these pipes age. Current repair practices are costly and highly disruptive. The objective of this program is to design, test and commercialize a robotic system capable of sealing multiple castiron bell and spigot joints from a single pipe entry point. The proposed system will perform repairs while the pipe remains in service by traveling through the pipe, cleaning each joint surface, and installing a stainless-steel sleeve lined with an epoxy-impregnated felt across the joint. This approach will save considerable time and labor, avoid traffic disruption, and eliminate any requirement to interrupt service to customers (which would result in enormous expense to utilities). Technical challenges include: (1) repair sleeves must compensate for diametric variation and eccentricity of cast-iron pipes; (2) the assembly must travel long distances through pipes containing debris; (3) the pipe wall must be effectively cleaned in the immediate area of the joint to assure good bonding of the sleeve; and (4) an innovative bolt-on entry fitting is required to conduct repair operations on live mains. The development effort is divided into eleven tasks. Task 1 (Program Management) and Task 2 (Establishment of Detailed Design Specifications) were completed in prior quarters while Task 3 (Design and Fabricate Ratcheting Stainless-Steel Repair Sleeves) has progressed to installing prototype sleeves in cast iron test pipe segments. Efforts in this quarter continued to focus on Tasks 4-8, with significant progress made in each. Task 4 (Design, Fabricate and Test Patch Setting Robotic Train) progressed to the design of the control electronics and pneumatic system to inflate the bladder robotic patch setting module. Task 5 (Design & Fabricate Pipe-Wall Cleaning Robot Train with Pan/Zoom/Tilt Camera

The mutual co-regulation of extracellular polymeric substances and iron ions in biocorrosion of cast iron pipes.

Science.gov (United States)

Jin, Juntao; Guan, Yuntao

2014-10-01

New insights into the biocorrosion process may be gained through understanding of the interaction between extracellular polymeric substances (EPS) and iron. Herein, the effect of iron ions on the formation of biofilms and production of EPS was investigated. Additionally, the impact of EPS on the corrosion of cast iron coupons was explored. The results showed that a moderate concentration of iron ions (0.06 mg/L) promoted both biofilm formation and EPS production. The presence of EPS accelerated corrosion during the initial stage, while inhibited corrosion at the later stage. The functional groups of EPS acted as electron shuttles to enable the binding of iron ions. Binding of iron ions with EPS led to anodic dissolution and promoted corrosion, while corrosion was later inhibited through oxygen reduction and availability of phosphorus from EPS. The presence of EPS also led to changes in crystalline phases of corrosion products. Copyright © 2014 Elsevier Ltd. All rights reserved.

Timing of multiple hydrothermal events in the iron oxide-copper-gold deposits of the Southern Copper Belt, Carajás Province, Brazil

Science.gov (United States)

Moreto, Carolina P. N.; Monteiro, Lena V. S.; Xavier, Roberto P.; Creaser, Robert A.; DuFrane, S. Andrew; Melo, Gustavo H. C.; Delinardo da Silva, Marco A.; Tassinari, Colombo C. G.; Sato, Kei

2015-06-01

The Southern Copper Belt, Carajás Province, Brazil, hosts several iron oxide-copper-gold (IOCG) deposits, including Sossego, Cristalino, Alvo 118, Bacuri, Bacaba, Castanha, and Visconde. Mapping and U-Pb sensitive high-resolution ion microprobe (SHRIMP) IIe zircon geochronology allowed the characterization of the host rocks, situated within regional WNW-ESE shear zones. They encompass Mesoarchean (3.08-2.85 Ga) TTG orthogneiss, granites, and remains of greenstone belts, Neoarchean (ca. 2.74 Ga) granite, shallow-emplaced porphyries, and granophyric granite coeval with gabbro, and Paleoproterozoic (1.88 Ga) porphyry dykes. Extensive hydrothermal zones include albite-scapolite, biotite-scapolite-tourmaline-magnetite alteration, and proximal potassium feldspar, chlorite-epidote and chalcopyrite formation. U-Pb laser ablation multicollector inductively coupled mass spectrometry (LA-MC-ICP-MS) analysis of ore-related monazite and Re-Os NTIMS analysis of molybdenite suggest multiple Neoarchean (2.76 and 2.72-2.68 Ga) and Paleoproterozoic (2.06 Ga) hydrothermal events at the Bacaba and Bacuri deposits. These results, combined with available geochronological data from the literature, indicate recurrence of hydrothermal systems in the Southern Copper Belt, including 1.90-1.88-Ga ore formation in the Sossego-Curral ore bodies and the Alvo 118 deposit. Although early hydrothermal evolution at 2.76 Ga points to fluid migration coeval with the Carajás Basin formation, the main episode of IOCG genesis (2.72-2.68 Ga) is related to basin inversion coupled with Neoarchean (ca. 2.7 Ga) felsic magmatism. The data suggest that the IOCG deposits in the Southern Copper Belt and those in the Northern Copper Belt (2.57-Ga Salobo and Igarapé Bahia-Alemão deposits) do not share a common metallogenic evolution. Therefore, the association of all IOCG deposits of the Carajás Province with a single extensive hydrothermal system is precluded.

Temperature measurement during solidification of thin wall ductile cast iron. Part 1: Theory and experiment

DEFF Research Database (Denmark)

Pedersen, Karl Martin; Tiedje, Niels Skat

2008-01-01

cooing curves in thin wall ductile iron castings. The experiments show how TC’s of different design interact with the melt and how TC design and surface quality affect the results of the data acquisition. It is discussed which precautions should be taken to ensure reliable acquisition of cooling curves....... Measurement error depending on TC design and cooling conditions is shown. A method is presented that allows acquisition of cooling curves in thin walled ductile iron castings down to thickness of at least 2.8 mm. The obtained cooling curves can be used to compare nucleation and growth during solidification...

Influence of electromagnetic field parameters on the morphology of graphite in grey cast iron

Directory of Open Access Journals (Sweden)

J. Szajnar

2009-01-01

Full Text Available One way to improve the unification of the casting structure may be the application of forced convection of liquid metal during thecrystallization in the form or continuous casting mould. This paper presents the results describing the influence of selected parameters of rotating electromagnetic field enforcing the movement of liquid metal in the form on the morphology of graphite in grey cast iron. The results were fragmented graphite flakes in conditions of regulating the rate of cooling in the range of temperature TZAL

Minimally-invasive Laser Ablation Inductively Coupled Plasma Mass Spectrometry analysis of model ancient copper alloys

Energy Technology Data Exchange (ETDEWEB)

Walaszek, Damian [University of Warsaw, Faculty of Chemistry, Biological and Chemical Research Centre, Żwirki i Wigury 101, 02-089 Warszawa (Poland); Laboratory for Analytical Chemistry, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf (Switzerland); Senn, Marianne; Wichser, Adrian [Laboratory for Analytical Chemistry, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf (Switzerland); Faller, Markus [Laboratory for Jointing Technology and Corrosion, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf (Switzerland); Wagner, Barbara; Bulska, Ewa [University of Warsaw, Faculty of Chemistry, Biological and Chemical Research Centre, Żwirki i Wigury 101, 02-089 Warszawa (Poland); Ulrich, Andrea [Laboratory for Analytical Chemistry, Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf (Switzerland)

2014-09-01

This work describes an evaluation of a strategy for multi-elemental analysis of typical ancient bronzes (copper, lead bronze and tin bronze) by means of laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS).The samples originating from archeological experiments on ancient metal smelting processes using direct reduction in a ‘bloomery’ furnace as well as historical casting techniques were investigated with the use of the previously proposed analytical procedure, including metallurgical observation and preliminary visual estimation of the homogeneity of the samples. The results of LA-ICPMS analysis were compared to the results of bulk composition obtained by X-ray fluorescence spectrometry (XRF) and by inductively coupled plasma mass spectrometry (ICPMS) after acid digestion. These results were coherent for most of the elements confirming the usefulness of the proposed analytical procedure, however the reliability of the quantitative information about the content of the most heterogeneously distributed elements was also discussed in more detail. - Highlights: • The previously proposed procedure was evaluated by analysis of model copper alloys. • The LA-ICPMS results were comparable to the obtained by means of XRF and ICPMS. • LA-ICPMS results indicated the usefulness of the proposed analytical procedure.

Modelling of Eutectic Saturation Influence on Microstructure in Thin Wall Ductile Iron Casting Using Cellular Automata

Directory of Open Access Journals (Sweden)

Burbelko A.A.

2012-12-01

Full Text Available The mathematical model of the globular eutectic solidification in 2D was designed. Proposed model is based on the Cellular Automaton Finite Differences (CA-FD calculation method. Model has been used for studies of the primary austenite and of globular eutectic grains growth during the ductile iron solidification in the thin wall casting. Model takes into account, among other things, non-uniform temperature distribution in the casting wall cross-section, kinetics of the austenite and graphite grains nucleation, and non-equilibrium nature of the interphase boundary migration. Calculation of eutectic saturation influence (Sc = 0.9 - 1.1 on microstructure (austenite and graphite fraction, density of austenite and graphite grains and temperature curves in 2 mm wall ductile iron casting has been done.

Graphite structure and magnetic parameters of flake graphite cast iron

Czech Academy of Sciences Publication Activity Database

Vértesy, G.; Uchimoto, T.; Takagi, T.; Tomáš, Ivan; Kage, H.

2017-01-01

Roč. 442, Nov (2017), s. 397-402 ISSN 0304-8853 R&D Projects: GA ČR GB14-36566G Institutional support: RVO:68378271 Keywords : magnetic NDE * magnetic adaptive testing * cast iron * graphite structure * pearlite content Subject RIV: BM - Solid Matter Physics ; Magnetism OBOR OECD: Condensed matter physics (including formerly solid state physics, supercond.) Impact factor: 2.630, year: 2016

Nondestructive characterization of ductile cast iron by magnetic adaptive testing

Czech Academy of Sciences Publication Activity Database

Vértesy, G.; Uchimoto, T.; Tomáš, Ivan; Takagi, T.

2010-01-01

Roč. 322, č. 20 (2010), s. 3117-3121 ISSN 0304-8853 R&D Projects: GA ČR GA101/09/1323; GA AV ČR 1QS100100508 Institutional research plan: CEZ:AV0Z10100520 Keywords : magnetic NDE * magnetic adaptive testing * magnetic hysteresis * cast iron Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.689, year: 2010

Numerical modeling and experimental validation of microstructure in gray cast iron

DEFF Research Database (Denmark)

Jabbari, Masoud; Davami, Parviz; Varahram, Naser

2012-01-01

To predict the amount of different phases in gray cast iron by a finite difference model (FDM) on the basis of cooling rate (R), the volume fractions of total γ phase, graphite, and cementite were calculated. The results of phase composition were evaluated to find a proper correlation with cooling...

Cellular automaton modelling of ductile iron microstructure in the thin wall casting

International Nuclear Information System (INIS)

Burbelko, A A; Gurgul, D; Kapturkiewicz, W; Górny, M

2012-01-01

The mathematical model of the globular eutectic solidification in 2D was designed. Proposed model is based on the Cellular Automaton Finite Differences (CA-FD) calculation method. Model has been used for studies of the primary austenite and of globular eutectic grains growth during the ductile iron solidification in the thin wall casting. Model takes into account, among other things, non-uniform temperature distribution in the casting wall cross-section, kinetics of the austenite and graphite grains nucleation, and non-equilibrium nature of the interphase boundary migration.

Microstructure Formation and Fracturing Characteristics of Grey Cast Iron Repaired Using Laser

Science.gov (United States)

Liu, Dan; Shi, Yongjun

2014-01-01

The repairing technology based on laser rapid fusion is becoming an important tool for fixing grey cast iron equipment efficiently. A laser repairing protocol was developed using Fe-based alloy powders as material. The microstructure and fracturing feature of the repaired zone (RZ) were analyzed. The results showed that regionally organized RZ with good density and reliable metallurgical bond can be achieved by laser repairing. At the bottom of RZ, dendrites existed in similar direction and extended to the secondary RZ, making the grains grow extensively with inheritance with isometric grains closer to the surface substrate. The strength of the grey cast iron base material was maintained by laser repairing. The base material and RZ were combined with robust strength and fracture resistance. The prevention and deflection of cracking process were analyzed using a cracking process model and showed that the overall crack toughness of the materials increased. PMID:25032230

Iron and copper in Plagioscion squamosissimus (Piscis: Sciaenidae) of river Orinoco, Venezuela

International Nuclear Information System (INIS)

Gonzalez, A. R.; Marquez, A.; Chung, S.K.

2000-01-01

Bauxite exploitation of the Orinoco River in recent years is an important source of heavy metals discharge in the ecosystem, changing the natural biochemical flow of these elements and their concentrations in water, sediment and organisms. Iron and copper concentrations were measured in the fish Plagioscion squamosissimus in the Orinoco river, by sampling the fish population for three months (September-November 1998) in the main channel of the middle Orinoco. The internal organs of 30 fishes per month and site were stove-dried, pulverized and dried in disecator for 30 min to use as indicators with the acid digestion method for predicting the effect of heavy metals. We found relatively high values of iron and copper concentrations in fishes of the lagoon, and high seasonal variations in the iron concentration. (Author) [es

Effect of Titanium Inoculation on Tribological Properties of High Chromium Cast Iron

Directory of Open Access Journals (Sweden)

Siekaniec D.

2017-12-01

Full Text Available The present investigation focuses on the study of the influence of titanium inoculation on tribological properties of High Chromium Cast Iron. Studies of tribological properties of High Chromium Cast Iron, in particularly the wear resistance are important because of the special application of this material. High Chromium Cast Iron is widely used for parts that require high wear resistance for example the slurry pumps, brick dies, several pieces of mine drilling equipment, rock machining equipment, and similar ones. Presented research described the effects of various amounts of Fe-Ti as an inoculant for wear resistance. The results of wear resistance were collated with microstructural analysis. The melts were conducted in industrial conditions. The inoculation was carried out on the stream of liquid metal. The following amount of inoculants have been used; 0.17% Fe-Ti, 0.33% Fe-Ti and 0.66% Fe-Ti. The tests were performed on the machine type MAN. The assessment of wear resistance was made on the basis of the weight loss. The experimental results indicate that inoculation improve the wear resistance. In every sample after inoculation the wear resistance was at least 20% higher than the reference sample. The best result, thus the smallest wear loss was achieved for inoculation by 0.66% Fe-Ti. There is the correlation between the changing in microstructure and wear resistance. With greater amount of titanium the microstructure is finer. More fine carbides do not crumbling so quickly from the matrix, improving the wear resistance.

Influence of Addition of Briquettes with Dust Content into the Charge of Electric Induction Furnace on Cast Iron Quality

Directory of Open Access Journals (Sweden)

Pribulová A.

2012-09-01

Full Text Available Foundry dust from blasting and grinding of castings contain a high amount of iron, ergo it is possible its recycling in foundry process. Dust was compacted by briquetting, two kinds of briquettes were prepared (A contained 95% magnetic part of dust from casting blasting +5% bentonite and B contained 95% mixture of dust from casting grinding and magnetic part of dust from casting blasting + 5% bentonite and used as a part of charge into the electric induction furnace. It was found that addition of briquettes has had an influence of a chemical composition of cast iron above all on content of sulphur, phosphorus and silicon. It was not reflected in decrease in tensile strength and in microstructure. Yield of metal from briquettes was not lower then 70%.

Influence of Addition of Briquettes with Dust Content into the Charge of Electric Induction Furnace on Cast Iron Quality

Directory of Open Access Journals (Sweden)

A. Pribulová

2012-09-01

Full Text Available Foundry dust from blasting and grinding of castings contain a high amount of iron, ergo it is possible its recycling in foundry process.Dust was compacted by briquetting, two kinds of briquettes were prepared (A contained 95% magnetic part of dust from casting blasting+5% bentonite and B contained 95% mixture of dust from casting grinding and magnetic part of dust from casting blasting + 5%bentonite and used as a part of charge into the electric induction furnace. It was found that addition of briquettes has had an influence of a chemical composition of cast iron above all on content of sulphur, phosphorus and silicon. It was not reflected in decrease in tensile strength and in microstructure. Yield of metal from briquettes was not lower then 70%.

IX - MR Control Chart as a Tool in Assessment of the Cast Iron Properties Stability

Directory of Open Access Journals (Sweden)

F. Binczyk

2007-07-01

Full Text Available The study offers a statistical assessment of the stability of a technological process of melting and pouring low-carbon grey iron assigned for casting of brake discs. Some specific characteristics were presented that should be taken into consideration when statistical methods are used for technology improvement. The stability of the cast iron melting process was evaluated using data read out from the thermal analysis curve and true data, i.e. the results of spectrometric analysis of the chemical composition and measured values of the mechanical properties. The method for assessment of process stability was discussed on the example of carbon content and Brinell hardness. The examined parameters of the technological process of grey iron melting and casting are independent of each other (the results of carbon content determination in successive melts, the results of hardness measurements, etc.. Therefore, for analysis, the IX - MR type charts were chosen, where single measurements of the selected property (n = 1 serve as a measure of location, while a measure of variability are the, so called, Moving Ranges (MR, which are an absolute value of the difference between the two successive measurements.

Optimization of casting defects analysis with supply chain in cast iron foundry process

Directory of Open Access Journals (Sweden)

C. Narayanaswamy

2016-10-01

Full Text Available Some of the foundries are in need of meeting production targets and due to the urgency they ignore the rejections. The objective of this paper is to analyze the various defects, [1] from molding process in a cast iron foundry. The Failure Mode Effects Analysis (FMEA in quality control [2-6] with suitable supply chain for mold making process considering rejection rates are identified and analyzed in terms of Risk Priority Number (RPN to prioritize the attention for each of the problem. The optimum levels of selected parameters [7] are obtained in this analysis.

Thermodynamic Analysis of Cast Irons Solidification With Various Types of Graphite

Directory of Open Access Journals (Sweden)

Elbel T.

2012-12-01

Full Text Available The contribution summarises the results of oxygen activity determinations, which were measured and registered continuously in castings from cast irons with various types of graphite. The results were used to find the relationship between two variables: natural logarithm of oxygen activities and reverse value of thermodynamic temperature 1 /T. Obtained regression lines were used to calculate oxygen activity at different temperatures, to calculate Gibbs free energy ΔG at the different temperatures and to calculate the single ΔG value for significant temperature of the graphite solidification. The results were processed by a statistical analysis of data files for the different types of graphite with flake, vermicular and spheroidal graphite. Each material has its proper typical oxygen activities range and individual temperature function of Gibbs free energy for analysing and governing casting quality.

Synchrotron measurements of local microstructure and residual strains in ductile cast iron

DEFF Research Database (Denmark)

Zhang, Yubin; Andriollo, Tito; Fæster, Søren

2017-01-01

The local microstructure and distribution of thermally induced residual strains in ferrite matrix grains around an individual spherical graphite nodule in ductile cast iron (DCI) were measured using a synchrotron X-ray micro-diffraction technique. It is found that the matrix grains are deformed...

Long term stability analysis of cast iron shaft linings after Coal Mine closure and flooding

Energy Technology Data Exchange (ETDEWEB)

Hadj-Hassen, F. [Ecole des Mines de Paris - CGES, 77 - Fontainebleau (France); Bienvenu, Y. [Ecole des Mines de Paris, CM, 91 - Evry (France); Noirel, J.F. [Charbonnages de France, DTN, 57 - Freyming Merlebach (France); Metz, M. [charbonnages de France, ESA, 57 - Freyming Merlebach (France)

2005-07-01

This paper presents the results of a study conducted to analyse the long term stability of the cast iron shaft lining after coal mine closure and flooding. The attention is mainly focused on the behaviour during the critical phase of flooding as well as the phase corresponding to the disappearance of the water pressure and the stabilization of the environment. This pluri-disciplinary study was conducted by a team combining specialists in rock mechanics who identified the main risks and the conditions of stability of the lining and specialists in metallurgy who studied the composition of the cast iron and its corrosion behaviour after exposure to mine water. (authors)

Long term stability analysis of cast iron shaft linings after Coal Mine closure and flooding

International Nuclear Information System (INIS)

Hadj-Hassen, F.; Bienvenu, Y.; Noirel, J.F.; Metz, M.

2005-01-01

This paper presents the results of a study conducted to analyse the long term stability of the cast iron shaft lining after coal mine closure and flooding. The attention is mainly focused on the behaviour during the critical phase of flooding as well as the phase corresponding to the disappearance of the water pressure and the stabilization of the environment. This pluri-disciplinary study was conducted by a team combining specialists in rock mechanics who identified the main risks and the conditions of stability of the lining and specialists in metallurgy who studied the composition of the cast iron and its corrosion behaviour after exposure to mine water. (authors)

High-Cycle Fatigue Resistance of Si-Mo Ductile Cast Iron as Affected by Temperature and Strain Rate

Science.gov (United States)

Matteis, Paolo; Scavino, Giorgio; Castello, Alessandro; Firrao, Donato

2015-09-01

Silicon-molybdenum ductile cast irons are used to fabricate exhaust manifolds of internal combustion engines of large series cars, where the maximum pointwise temperature at full engine load may be higher than 973 K (700 °C). In this application, high-temperature oxidation and thermo-mechanical fatigue (the latter being caused by the engine start and stop and by the variation of its power output) have been the subject of several studies and are well known, whereas little attention has been devoted to the high-cycle fatigue, arising from the engine vibration. Therefore, the mechanical behavior of Si-Mo cast iron is studied here by means of stress-life fatigue tests up to 10 million cycles, at temperatures gradually increasing up to 973 K (700 °C). The mechanical characterization is completed by tensile and compressive tests and ensuing fractographic examinations; the mechanical test results are correlated with the cast iron microstructure and heat treatment.

Repairs of Damaged Castings Made of Graphitic Cast Iron by Means of Brazing

Directory of Open Access Journals (Sweden)

Mičian M.

2017-09-01

Full Text Available The article summarizes the theoretical knowledge from the field of brazing of graphitic cast iron, especially by means of conventional flame brazing using a filler metal based on CuZn (CuZn40SnSi – brass alloy. The experimental part of the thesis presents the results of performance assessment of brazed joints on other than CuZn basis using silicone (CuSi3Mn1 or aluminium bronze (CuAl10Fe. TIG electrical arc was used as a source of heat to melt these filler materials. The results show satisfactory brazed joints with a CuAl10Fe filler metal, while pre-heating is not necessary, which favours this method greatly while repairing sizeable castings. The technological procedure recommends the use of AC current with an increased frequency and a modified balance between positive and negative electric arc polarity to focus the heat on a filler metal without melting the base material. The suitability of the joint is evaluated on the basis of visual inspection, mechanic and metallographic testing.

Effect of the Surface Layer of Iron Casting on the Growth of Protective Coating During Hot-Dip Galvanizing

Directory of Open Access Journals (Sweden)

Kopyciński D.

2016-03-01

Full Text Available The paper presents the results of investigations of the growth of protective coating on the surface of ductile iron casting during the hot-dip galvanizing treatment. Ductile iron of the EN-GJS-600-3 grade was melted and two moulds made by different technologies were poured to obtain castings with different surface roughness parameters. After the determination of surface roughness, the hot-dip galvanizing treatment was carried out. Based on the results of investigations, the effect of casting surface roughness on the kinetics of the zinc coating growth was evaluated. It was found that surface roughness exerts an important effect on the thickness of produced zinc coating.

Casting defects and fatigue behaviour of ductile cast iron for wind turbine components: A comprehensive study

Energy Technology Data Exchange (ETDEWEB)

Haerkegaard, G. [Norwegian University of Science and Technology, Dept. of Engineering Design and Materials, Trondheim (Norway); Shirani, M.

2011-12-15

Two types of EN-GJS-400-18-LT ductile cast iron were investigated in this research, clean baseline material in the shape of castings with different thicknesses and also defective material from a rejected wind turbine hub. P-S-N curves for baseline EN-GJS-400-18-LT specimens with different dimensions and from castings with different thicknesses at different load ratios were established. Geometrical size effect, technological size effects and mean stress effect on fatigue strength of baseline EN-GJS-400-18-LT were evaluated. Fatigue strength of baseline EN-GJS-400-18-LT was compared with that of defective material from the rejected hub. The effect of defects type, shape, size and position on fatigue strength of this material was evaluated. The hypothesis that the endurance observed in an S-N test can be predicted based on the analysis of crack growth from casting defects through defect-free 'base' material was tested for the analyzed defective material. 3D X-ray computed tomography was use to detect defects in defective specimens and find the defect size distribution. The obtained defect size distribution for the defective material was used in random defect analysis to establish the scatter of fatigue life for defective specimens. Finally both safe-life design and damage tolerant design of wind turbine castings were analyzed and compared. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Influence of New Sol-gel Refractory Coating on the Casting Properties of Cold Box and Furan Cores for Grey Cast iron

DEFF Research Database (Denmark)

Nwaogu, Ugochukwu Chibuzoh; Poulsen, T.; Bischoff, C

2010-01-01

New Sol-Gel coated sand cores made from coldbox and furan binder systems were investigated. The idea of the coating was to improve the surface quality of castings. Grey iron was cast on the cores in a sand casting process. The effect of the high temperature of the melt on the cores was assessed...... by measuring the heating curves. The viscosity of the coating, moisture content and the permeability of the cores were evaluated. The surface quality of the castings was investigated using SEM and OM. The results show that the moisture content of the cores affected the permeability. In furan cores the vapour...... transport zone (VTZ) when in contact with the melt is larger than it is in a coldbox which means the furan cores have higher moisture content. The new sol-gel coating has the potential for improving the surface quality of castings without negative effects on the graphite distribution. The surface...

Corrosion Inhibiting Mechanism of Nitrite Ion on the Passivation of Carbon Steel and Ductile Cast Iron for Nuclear Power Plants

Directory of Open Access Journals (Sweden)

K. T. Kim

2015-01-01

Full Text Available While NaNO2 addition can greatly inhibit the corrosion of carbon steel and ductile cast iron, in order to improve the similar corrosion resistance, ca. 100 times more NaNO2 addition is needed for ductile cast iron compared to carbon steel. A corrosion and inhibition mechanism is proposed whereby NO2- ion is added to oxidize. The NO2- ion can be reduced to nitrogen compounds and these compounds may be absorbed on the surface of graphite. Therefore, since nitrite ion needs to oxidize the surface of matrix and needs to passivate the galvanic corroded area and since it is absorbed on the surface of graphite, a greater amount of corrosion inhibitor needs to be added to ductile cast iron compared to carbon steel. The passive film of carbon steel and ductile cast iron, formed by NaNO2 addition showed N-type semiconductive properties and its resistance, is increased; the passive current density is thus decreased and the corrosion rate is then lowered. In addition, the film is mainly composed of iron oxide due to the oxidation by NO2- ion; however, regardless of the alloys, nitrogen compounds (not nitrite were detected at the outermost surface but were not incorporated in the inner oxide.

New sulphiding method for steel and cast iron parts

Science.gov (United States)

Tarelnyk, V.; Martsynkovskyy, V.; Gaponova, O.; Konoplianchenko, Ie; Dovzyk, M.; Tarelnyk, N.; Gorovoy, S.

2017-08-01

A new method for sulphiding steel and cast iron part surfaces by electroerosion alloying (EEA) with the use of a special electrode is proposed, which method is characterized in that while manufacturing the electrode, on its surface, in any known manner (punching, threading, pulling, etc.), there is formed at least a recess to be filled with sulfur as a consistent material, and then there is produced EEA by the obtained electrode without waiting for the consistent material to become dried.

Modeling of damage in ductile cast iron – The effect of including plasticity in the graphite noduless

DEFF Research Database (Denmark)

Andriollo, Tito; Thorborg, Jesper; Tiedje, Niels Skat

2015-01-01

In the present paper a micro-mechanical model for investigating the stress-strain relation of ductile cast iron subjected to simple loading conditions is presented. The model is based on a unit cell containing a single spherical graphite nodule embedded in a uniform ferritic matrix, under...... the assumption of infinitesimal strains and plane-stress conditions. Despite the latter being a limitation with respect to full 3D models, it allows a direct comparison with experimental investigations of damage evolution on the surface of ductile cast iron components, where the stress state is biaxial in nature...

Structural analysis of cellular blocks for a prestressed cast iron reactor pressure vessel

International Nuclear Information System (INIS)

Thomas, R.G.; Head, J.L.

1979-01-01

The cast segments from which the prestressed cast iron nuclear reactor pressure vessel may be constructed are not readily amenable to detailed three-dimensional finite element analysis because their complex internal web structure requires a very large number of elements if reasonable aspect ratios are to be retained. A technique has been developed of modelling these blocks using plate bending elements from the ASKA code. By this means it has been possible to study in detail several designs of casting and to identify favourable features. The results of these studies, and others in which assessments are made of the sensitivity of the structure to prestressing load changes and machining errors, are reported. (orig.)

Three-body abrasive wear behaviour of metastable spheroidal carbide cast irons with different chromium contents

Energy Technology Data Exchange (ETDEWEB)

Efremenko, Vasily; Pastukhova, Tatiana; Chabak, Yuliia; Efremenko, Alexey [Pryazovskyi State Technical Univ., Mariupol (Ukraine); Shimizu, Kazumichi; Kusumoto, Kenta [Muroran Institute of Technology, Hokkaido (Japan); Brykov, Michail [Zaporozhye National Technical Univ., Zaporozhye (Ukraine)

2018-02-15

The effect of heat treatment and chromium contents (up to 9.1 wt.%) on the wear resistance of spheroidal carbide cast iron (9.5 wt.% V) was studied using optical and scanning electron microscopy, X-ray diffractometry, dilatometry and three-body abrasive testing. It was found that quenching from 760 C and 920 C improved the alloys' wear resistance compared to the as-cast state due to the formation of metastable austenite transforming into martensite under abrasion. The wear characteristics of alloys studied are 1.6 - 2.3 times higher than that of reference cast iron (12 wt.% V) having stable austenitic matrix. Chromium addition decreases surface damage due to the formation of M{sub 7}C{sub 3} carbides, while it reduces wear resistance owing to austenite stabilization to abrasion-induced martensite transformation. The superposition of these factors results in decreasing the alloys' wear behaviour with chromium content increase.

Concept of a Prestressed Cast Iron Pressure Vessel for a Modular High Temperature Reactor

International Nuclear Information System (INIS)

Steinwarz, Wolfgang; Bounin, Dieter

2014-01-01

High Temperature Reactors (HTR) are representing one of the most interesting solutions for the upcoming generation of nuclear technology, especially with view to their inherent safety characteristics. To complete the safety concept of such plants already in the first phase of the technical development, Prestressed Cast Iron Pressure Vessels (PCIV) instead of the established forged steel reactor pressure vessels have been considered under the aspect of safety against bursting. A longterm research and development work, mainly performed in Germany, showed the excellent features of this technical solution. Diverse prototypic vessels were tested and officially proven. Design studies confirmed the feasibility of such a vessel concept also for Light Water Reactor types, too. The main concept elements of such a burst-proof vessel are: Strength and tightness functions are structurally separated. The tensile forces are carried by the prestressing systems consisting of a large number of independent wires. Compressive forces are applied to the vessel walls and heads. These are segmented into blocks of ductile cast iron. All cast iron blocks are prestressed to high levels of compression. The sealing function is assigned to a steel liner fixed to the cast iron blocks. The prestressing system is designed for an ultimate pressure of 2.3 times the design pressure. The prestress of the lids is designed for gapping at a much smaller pressure. Therefore, a drop of pressure will always occur before loss of strength (“leakage before failure”). In addition to these safety features further technical as well as economic aspects generate favorable assessment criteria: high design flexibility, feasibility of large vessel diameters; advantageous conditions for transport, assembly and decommissioning due to the segmented construction; advantage of workshop manufacturing; high-level quality control of components. Nowadays, considering the globally newly standardized safety requirements

Association of Maternal Diet With Zinc, Copper, and Iron Concentrations in Transitional Human Milk Produced by Korean Mothers

Science.gov (United States)

Kim, Ji-Myung; Lee, Ji-Eun; Cho, Mi Sook; Kang, Bong Soo; Choi, Hyeon

2016-01-01

The aims of this study were to evaluate zinc, copper, and iron concentrations in the transitory milk of Korean lactating mothers and to investigate the relationship between these concentrations and maternal diet. Human milk samples were collected between 5 and 15 days postpartum from 96 healthy, lactating mothers in postpartum care centers in Seoul, Korea. Dietary intake during lactation was determined based on a 3-day dietary record. The mean zinc, copper, and iron concentrations in the human milk samples collected were 3.88 ± 1.74 mg/L, 0.69 ± 0.25 mg/L, and 5.85 ± 8.53 mg/L, respectively. The mothers who consumed alcoholic beverages during pregnancy had tended to have lower concentrations of zinc and copper, as well as significantly lower concentrations of iron, in their milk (p < 0.047). In contrast, the mothers who took daily supplements had much higher iron concentrations in their milk (p = 0.002). Dietary intakes of zinc, copper, and iron during lactation did not affect the concentrations of zinc, copper, and iron in the milk samples analyzed. Intakes of vitamin C, selenium, and iodine were associated with the concentration of copper in the milk samples analyzed, and consumption of food categorized as 'meat and meat products' was positively associated with the concentration of zinc. Consumption of rice was the top contributor to the concentrations of all three minerals. In conclusion, associations between maternal diet and nutrient concentrations in transitory human milk can provide useful information, particularly in regard to infant growth. PMID:26839873

SEALING LARGE-DIAMETER CAST-IRON PIPE JOINTS UNDER LIVE CONDITIONS

Energy Technology Data Exchange (ETDEWEB)

Kiran M. Kothari; Gerard T. Pittard

2005-07-01

Utilities in the U.S. operate over 75,000 km (47,000 miles) of old cast-iron pipes for gas distribution. Bell-and-spigot joints that connect pipe sections together tend to leak as these pipes age. Current repair practices are costly and highly disruptive. The objective of this program is to design, test and commercialize a robotic system capable of sealing multiple castiron bell and spigot joints from a single pipe entry point. The proposed system will perform repairs with the pipe in service by traveling through the pipe, cleaning each joint surface, and installing a stainless-steel sleeve lined with an epoxy-impregnated felt across the joint. This approach will save considerable time and labor, minimize excavation, avoid traffic disruption, and eliminate any requirement to interrupt service to customers (which would result in enormous expense to utilities). Technical challenges include: (1) repair sleeves must compensate for diametric variation and eccentricity of old cast-iron pipes; (2) the assembly must travel long distances through pipes containing debris; (3) the pipe wall must be effectively cleaned in the immediate area of the joint to assure good bonding of the sleeve; and (4) an innovative bolt-on entry fitting is required to conduct safe repair operations on live mains.

Multivariate research in areas of phosphorus cast-iron brake shoes manufacturing using the statistical analysis and the multiple regression equations

Science.gov (United States)

Kiss, I.; Cioată, V. G.; Alexa, V.; Raţiu, S. A.

2017-05-01

The braking system is one of the most important and complex subsystems of railway vehicles, especially when it comes for safety. Therefore, installing efficient safe brakes on the modern railway vehicles is essential. Nowadays is devoted attention to solving problems connected with using high performance brake materials and its impact on thermal and mechanical loading of railway wheels. The main factor that influences the selection of a friction material for railway applications is the performance criterion, due to the interaction between the brake block and the wheel produce complex thermos-mechanical phenomena. In this work, the investigated subjects are the cast-iron brake shoes, which are still widely used on freight wagons. Therefore, the cast-iron brake shoes - with lamellar graphite and with a high content of phosphorus (0.8-1.1%) - need a special investigation. In order to establish the optimal condition for the cast-iron brake shoes we proposed a mathematical modelling study by using the statistical analysis and multiple regression equations. Multivariate research is important in areas of cast-iron brake shoes manufacturing, because many variables interact with each other simultaneously. Multivariate visualization comes to the fore when researchers have difficulties in comprehending many dimensions at one time. Technological data (hardness and chemical composition) obtained from cast-iron brake shoes were used for this purpose. In order to settle the multiple correlation between the hardness of the cast-iron brake shoes, and the chemical compositions elements several model of regression equation types has been proposed. Because a three-dimensional surface with variables on three axes is a common way to illustrate multivariate data, in which the maximum and minimum values are easily highlighted, we plotted graphical representation of the regression equations in order to explain interaction of the variables and locate the optimal level of each variable for

On some perculiarities of microstructure formation and the mechanical properties in thick-walled pieces of cast iron and their application as reactor structural materials

International Nuclear Information System (INIS)

Janakiev, N.

1975-01-01

The following problems are dealt with in the present work: Microstructure formation and mechanical properties of thick-walled cast pieces, influence of neutron irradiation on the mechanical properties, manufacture of thick-walled castings for reactor construction, application of cast iron as reactor structural material. It is shown that graphite formation plays an extremely important role regarding the mechanical properties. A new construction for vertically stressed pressure vessels is given. These vessels can be fabricated mainly of cast iron with graphite spheres, cast steel, or a combination of both depending on the operational pressure. (GSCH) [de

Corrosion Resistance of a Cast-Iron Material Coated With a Ceramic Layer Using Thermal Spray Method

Science.gov (United States)

Florea, C. D.; Bejinariu, C.; Munteanu, C.; Istrate, B.; Toma, S. L.; Alexandru, A.; Cimpoesu, R.

2018-06-01

Cast-iron 250 used for breake systems present many corrosion signs after a mean usage time based on the environment conditions they work. In order to improve them corrosion resistance we propose to cover the active part of the material using a ceramic material. The deposition process is an industrial deposition system based on thermal spraying that can cover high surfaces in low time. In this articol we analyze the influence of a ceramic layer (40-50 µm) on the corrosion resistance of FC250 cast iron. The results were analyzed using scanning electron microscopy (SEM), X-ray energy dispersive (EDS) and linear and cyclic potentiometry.

Fatigue and Fracture Resistance of Heavy-Section Ferritic Ductile Cast Iron

Directory of Open Access Journals (Sweden)

Matteo Benedetti

2017-03-01

Full Text Available In this paper, we explore the effect of a long solidification time (12 h on the mechanical properties of an EN-GJS-400-type ferritic ductile cast iron (DCI. For this purpose, static tensile, rotating bending fatigue, fatigue crack growth and fracture toughness tests are carried out on specimens extracted from the same casting. The obtained results are compared with those of similar materials published in the technical literature. Moreover, the discussion is complemented with metallurgical and fractographic analyses. It has been found that the long solidification time, representative of conditions arising in heavy-section castings, leads to an overgrowth of the graphite nodules and a partial degeneration into chunky graphite. With respect to minimum values prescribed for thick-walled (t > 60 mm EN-GJS-400-15, the reduction in tensile strength and total elongation is equal to 20% and 75%, respectively. The rotating bending fatigue limit is reduced by 30% with respect to the standard EN-1563, reporting the results of fatigue tests employing laboratory samples extracted from thin-walled castings. Conversely, the resistance to fatigue crack growth is even superior and the fracture toughness comparable to that of conventional DCI.

75 FR 54595 - Certain Iron Construction Castings From Brazil, Canada, and the People's Republic of China: Final...

Science.gov (United States)

2010-09-08

...] Certain Iron Construction Castings From Brazil, Canada, and the People's Republic of China: Final Results... construction castings from Brazil, Canada, and the People's Republic of China (PRC), pursuant to section 751(c) of the Tariff Act of 1930, as amended (the Act). See Initiation of Five-year (``Sunset'') Review, 75...

Copper metabolism and its interactions with dietary iron, zinc, tin and selenium in rats

NARCIS (Netherlands)

Yu, S.

1993-01-01

This thesis describes various studies on copper metabolism and its interactions with selected dietary trace elements in rats. The rats were fed purified diets throughout. High intakes of iron or tin reduced copper concentrations in plasma, liver and kidneys. The dietary treatments also

Effects of microbial redox cycling of iron on cast iron pipe corrosion in drinking water distribution systems.

Science.gov (United States)

Wang, Haibo; Hu, Chun; Zhang, Lili; Li, Xiaoxiao; Zhang, Yu; Yang, Min

2014-11-15

Bacterial characteristics in corrosion products and their effect on the formation of dense corrosion scales on cast iron coupons were studied in drinking water, with sterile water acting as a reference. The corrosion process and corrosion scales were characterized by electrochemical and physico-chemical measurements. The results indicated that the corrosion was more rapidly inhibited and iron release was lower due to formation of more dense protective corrosion scales in drinking water than in sterile water. The microbial community and denitrifying functional genes were analyzed by pyrosequencing and quantitative polymerase chain reactions (qPCR), respectively. Principal component analysis (PCA) showed that the bacteria in corrosion products played an important role in the corrosion process in drinking water. Nitrate-reducing bacteria (NRB) Acidovorax and Hydrogenophaga enhanced iron corrosion before 6 days. After 20 days, the dominant bacteria became NRB Dechloromonas (40.08%) with the protective corrosion layer formation. The Dechloromonas exhibited the stronger corrosion inhibition by inducing the redox cycling of iron, to enhance the precipitation of iron oxides and formation of Fe3O4. Subsequently, other minor bacteria appeared in the corrosion scales, including iron-respiring bacteria and Rhizobium which captured iron by the produced siderophores, having a weaker corrosion-inhibition effect. Therefore, the microbially-driven redox cycling of iron with associated microbial capture of iron caused more compact corrosion scales formation and lower iron release. Copyright © 2014 Elsevier Ltd. All rights reserved.

Auger electron spectroscopy study of surface segregation in the binary alloys copper-1 atomic percent indium, copper-2 atomic percent tin, and iron-6.55 atomic percent silicon

Science.gov (United States)

Ferrante, J.

1973-01-01

Auger electron spectroscopy was used to examine surface segregation in the binary alloys copper-1 at. % indium, copper-2 at. % tin and iron-6.55 at. % silicon. The copper-tin and copper-indium alloys were single crystals oriented with the /111/ direction normal to the surface. An iron-6.5 at. % silicon alloy was studied (a single crystal oriented in the /100/ direction for study of a (100) surface). It was found that surface segregation occurred following sputtering in all cases. Only the iron-silicon single crystal alloy exhibited equilibrium segregation (i.e., reversibility of surface concentration with temperature) for which at present we have no explanation. McLean's analysis for equilibrium segregation at grain boundaries did not apply to the present results, despite the successful application to dilute copper-aluminum alloys. The relation of solute atomic size and solubility to surface segregation is discussed. Estimates of the depth of segregation in the copper-tin alloy indicate that it is of the order of a monolayer surface film.

OBSERVATION OF FATIGUE CRACK PATHS IN NODULAR CAST IRON AND ADI MICROSTRUCTURES

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Lukáš Bubenko

2009-07-01

Full Text Available When speaking about quality of construction materials, fatigue crack propagation resistance is one of the most important considered properties. That is essentially influenced by character of matrix. Here presented contribution deals with the fatigue crack propagation mode through the matrix of as-cast nodular cast iron (NCI and austempered ductile iron (ADI, whereas influence of microstructure has been considered and discussed. Experimental materials used in presented contribution were pearlitc-ferritic NCI and heat treated ADI 800. Pearlitic-ferritic NCI was used as the base for ADI production. Experiments were performed on mini round compact tension (RCT specimens using an Amsler vibrophore. Fatigue crack paths in both materials were investigated and compared. Light microscopy was used to analyze the microstructure, crack initiation and propagation within broken specimens. In both tested materials fatigue cracks always initiated at graphite-matrix interface, while graphite nodules remained generally unbroken, eventually only surface of nodules was damaged. Though, comparing two materials with different microstructures, the diversity of fatigue crack propagation modes at high deltaK and low deltaK was observed.

Production of spheroidal graphite cast iron (S. G. Iron) for an automobile brake drum

International Nuclear Information System (INIS)

Butt, M.T.Z.; Aziz, S.

2005-01-01

The role of automobile industry for any country has a great importance. Break drum is one of the essential parts of automobile car and its local casting is required in order to achieve the target for automobile industry because it has special significance. Break drum being the important constituent of the system of an automobile requires a great degree of accuracy and reliability. S. G. Iron is preferred because of its mechanical properties i.e., higher strength modulus, impact resistance and ductility along with excellent machinability and manufacturing ease. (author)

Slurry Erosion Behavior of Destabilized and Deep Cryogenically Treated Cr-Mn-Cu White Cast Irons

Directory of Open Access Journals (Sweden)

S. Gupta

2016-12-01

Full Text Available The effects of destabilization treatment and destabilization followed by cryogenic treatment have been evaluated on the microstructural evolution and sand-water slurry erosion behavior of Cr-Mn-Cu white cast irons. The phase transformations after the destabilization and cryotreatment have been characterized by bulk hardness measurement, optical and scanning electron microscopy, x-ray diffraction analysis. The static corrosion rate has been measured in tap water (with pH=7 and the erosion-corrosion behavior has been studied by slurry pot tester using sand-water slurry. The test results indicate that the cryogenic treatment has a significant effect in minimizing the as-cast retained austenite content and transforming into martensitic and bainitic matrix embedded with ultra-fine M7C3 alloy carbides. In contrast, by conventional destabilization treatment retained austenite in the matrix are not fully eliminated. The slurry erosive wear resistance has been compared with reference to destabilized and cryotreated high chromium iron samples which are commonly employed for such applications. The cryotreated Cr-Mn-Cu irons have exhibited a comparable erosive wear performance to those of high chromium irons. Higher hardness combined with improved corrosion resistance result in better slurry erosion resistance.

Thermal analysis control of in-mould and ladle inoculated grey cast irons

Directory of Open Access Journals (Sweden)

Mihai Chisamera

2009-05-01

Full Text Available The effect of addition of 0.05wt.% to 0.25 wt.% Ca, Zr, Al-FeSi alloy on in-ladle and in-mould inoculation of grey cast irons was investigated. In the present paper, the conclusions drawn are based on thermal analysis. For the solidification pattern, some specific cooling curves characteristics, such as the degree of undercooling at the beginning of eutectic solidifi cation and at the end of solidifi cation, as well as the recalescence level, are identifi ed to be more infl uenced by the inoculation technique. The degree of eutectic undercooling of the electrically melted base iron having 0.025% S, 0.003% Al and 3.5% Ce is excessively high (39–40℃, generating a relatively high need for inoculation. Under these conditions, the in-mould inoculation has a more signifi cant effect compared to ladle inoculation, especially at lower inoculant usage (less than 0.20 wt.%. Generally, the efficiency of 0.05wt.%–0.15wt.% of alloy for in-mould inoculation is comparable to, or better than, that of 0.15wt.%–0.25wt.% addition in ladle inoculation procedures. In order to secure stable and controlled processes, representative thermal analysis parameters could be used, especially in thin wall grey iron castings production.

Energy efficiency opportunities in the production process of cast iron foundries: An experience in Italy

International Nuclear Information System (INIS)

Lazzarin, Renato M.; Noro, Marco

2015-01-01

Foundry sector is one of the most energy intensive in industry. Energy audits performed in 5 Italian cast iron foundries allowed to identify energy utilization in the various processes that from the melting of the iron arrive at the finishing of the casting. Main equipment was surveyed, evaluating the influence on the overall energy consumption, producing a detailed analysis of energy use per department and energy performance indexes. A separate study was carried out for foundries with induction furnaces and cold or hot blast cupolas. Possibilities of heat recovery was identified particularly in combustion air preheating, but also for building heating or to power direct cycles to produce electricity. Better insulation and new insulating materials can improve the efficiency and the quality of the processes. Suggestions are supplied in the various foundry departments for energy saving. Possible energy saving actions on the service plants will be dealt with in a separate paper. - Highlights: • The Authors performed energy audits in 5 Italian cast iron foundries. • Main equipment was surveyed, evaluating the influence on the overall energy consumption. • An analysis of energy use per department and energy performance indexes was performed. • Possibilities of heat recovery were identified in combustion air preheating and for building heating. • Better and new insulating materials were analyzed to improve the efficiency and process quality.

APPRAISAL OF APPLICATION OF WEAR-RESISTANT CHROMIC CAST IRONS FOR PRODUCTION OF MOULDED PIECES OF EQUIPMENT ON PRODUCTION OF BRICK OF CLAY

Directory of Open Access Journals (Sweden)

K. E. aranovkij

2007-01-01

Full Text Available The appraisal of application of wear-resistant chromic cast irons of different chemical compositions for production of moulded pieces of equipment on production of bricks of clay is carried out. It is determined that working resource of the details of test cast-irons is correlated with their hardness and not lower than of hardened steel.

Implementation Analysis of Cutting Tool Carbide with Cast Iron Material S45 C on Universal Lathe

Science.gov (United States)

Junaidi; hestukoro, Soni; yanie, Ahmad; Jumadi; Eddy

2017-12-01

Cutting tool is the tools lathe. Cutting process tool CARBIDE with Cast Iron Material Universal Lathe which is commonly found at Analysiscutting Process by some aspects numely Cutting force, Cutting Speed, Cutting Power, Cutting Indication Power, Temperature Zone 1 and Temperatur Zone 2. Purpose of this Study was to determine how big the cutting Speed, Cutting Power, electromotor Power,Temperatur Zone 1 and Temperatur Zone 2 that drives the chisel cutting CARBIDE in the Process of tur ning Cast Iron Material. Cutting force obtained from image analysis relationship between the recommended Component Cuting Force with plane of the cut and Cutting Speed obtained from image analysis of relationships between the recommended Cutting Speed Feed rate.

Determination of iron, copper, manganese and zinc in the soils, grapes and wines of the Azores

Directory of Open Access Journals (Sweden)

María Teresa Ribeiro de Lima

2004-06-01

Full Text Available This paper describes the determination of iron, copper, manganese and zinc in the soils, grapes and wines of the three viticultural regions of the Azores. Iron, copper and zinc were determined by flame atomic absorption spectrometry and manganese by graphite furnace atomic absorption. The concentrations of the four elements differed in soils of the three regions; there was no difference in the concentration in grapes, whereas significant differences were observed for the wines as regards the amounts of iron, manganese and zinc. The concentrations of these four elements in wine correspond with the mean values observed for other European regions.

Effect of Nickel Equivalent on Austenite Transition Ratio in Ni-Mn-Cu Cast Iron

Directory of Open Access Journals (Sweden)

Janus A.

2013-06-01

Full Text Available Determined was quantitative effect of nickel equivalent value on austenite decomposition degree during cooling-down castings of Ni-Mn- Cu cast iron. Chemical composition of the alloy was 1.8 to 5.0 % C, 1.3 to 3.0 % Si, 3.1 to 7.7 % Ni, 0.4 to 6.3 % Mn, 0.1 to 4.9 % Cu, 0.14 to 0.16 % P and 0.03 to 0.04 % S. Analysed were castings with representative wall thickness 10, 15 and 20 mm. Scope of the examination comprised chemical analysis (including WDS, microscopic observations (optical and scanning microscopy, image analyser, as well as Brinell hardness and HV microhardness measurements of structural components.

Experimental validation of error in temperature measurements in thin walled ductile iron castings

DEFF Research Database (Denmark)

Pedersen, Karl Martin; Tiedje, Niels Skat

2007-01-01

An experimental analysis has been performed to validate the measurement error of cooling curves measured in thin walled ductile cast iron. Specially designed thermocouples with Ø0.2 mm thermocouple wire in Ø1.6 mm ceramic tube was used for the experiments. Temperatures were measured in plates...

Effect of cold work on creep properties of oxygen-free copper

International Nuclear Information System (INIS)

Martinsson, Aasa; Andersson-Oestling, Henrik C.M.

2009-03-01

Spent nuclear fuel is in Sweden planned to be disposed by encapsulating in waste packages consisting of a cast iron insert surrounded by a copper canister. The cast iron is load bearing and the copper canister gives corrosion protection. The waste package is heavy. Throughout the manufacturing process from the extrusion/pierce-and-draw manufacturing to the final placement in the repository, the copper is subjected to handling which could introduce cold work in the material. It is well known that the creep properties of engineering materials at higher temperatures are affected by cold working. The study includes creep testing of four series of cold worked, oxygen-free, phosphorus doped copper (Cu-OFP) at 75 deg C. The results are compared to reference series for as series of copper cold worked in tension (12 and 24 %) and two series cold worked in compression (12 % parallel to creep load axis and 15 % perpendicular to creep load axis) were tested. The results show that pre-straining in tension of copper leads to prolonged creep life at 75 deg C. The creep rate and ductility are reduced. The influence on the creep properties increases with the amount of cold work. Cold work in compression applied along the creep load axis has no effect on the creep life or the creep rate. Nonetheless the ductility is still impaired. However, cold work in compression applied perpendicular to the creep load direction has a positive effect on the creep life. Cold work in both tension and compression results in a pronounced reduction of the initial creep strain, which is the strain obtained from the beginning of the loading until full creep load is achieved. Yet the area reduction is unaffected by the degree of cold work

Health implications of PAH release from coated cast iron drinking water distribution systems in The Netherlands.

Science.gov (United States)

Blokker, E J Mirjam; van de Ven, Bianca M; de Jongh, Cindy M; Slaats, P G G Nellie

2013-05-01

Coal tar and bitumen have been historically used to coat the insides of cast iron drinking water mains. Polycyclic aromatic hydrocarbons (PAHs) may leach from these coatings into the drinking water and form a potential health risk for humans. We estimated the potential human cancer risk from PAHs in coated cast iron water mains. In a Dutch nationwide study, we collected drinking water samples at 120 locations over a period of 17 days under various operational conditions, such as undisturbed operation, during flushing of pipes, and after a mains repair, and analyzed these samples for PAHs. We then estimated the health risk associated with an exposure scenario over a lifetime. During flushing, PAH levels frequently exceeded drinking water quality standards; after flushing, these levels dropped rapidly. After the repair of cast iron water mains, PAH levels exceeded the drinking water standards for up to 40 days in some locations. The estimated margin of exposure for PAH exposure through drinking water was > 10,000 for all 120 measurement locations, which suggests that PAH exposure through drinking water is of low concern for consumer health. However, factors that differ among water systems, such as the use of chlorination for disinfection, may influence PAH levels in other locations.

Design basis for the copper/steel canister

International Nuclear Information System (INIS)

Bowyer, W.H.

1996-02-01

The development of the copper/iron canister which has been proposed by SKB for the containment of high level nuclear waste has been studied from the point of view of choice of materials, manufacturing technology and quality assurance. This report describes the observations on progress which have been made between March 1995 and Feb 1996 and the result of further literature studies. A first trial canister has been produced using a fabricated steel liner and an extruded copper tubular, a second one using a fabricated tubular is at an advanced stage. A change from a fabricated steel inner canister to a proposed cast canister has been justified by a criticality argument but the technology for producing a cast canister is at present untried. The microstructure achieved in the extruded copper tubular for the first canister is unacceptable. Similar problems exist with plate used for the fabricated tubular, but some more favourable structures have been achieved already by this route. Seam welding of the first tubular failed through a suspected material problem. The second fabricated tubular welded without difficulty. Welding of lids and bottoms to the copper canister is problematical.There is as yet no satisfactory non destructive test procedures for the parent metal or the welds in the copper canister material, partly due to the coarse grain size which arise in the proposed material processed by the proposed routes. Further studies are also required on crevice corrosion, galvanic attack and stress corrosion cracking in the copper 50 ppm phosphorus alloy. 28 refs

Characterization of pure and copper-doped iron tartrate crystals

Indian Academy of Sciences (India)

Single crystal growth of pure and copper-doped iron tartrate crystals bearing composition Cu Fe(1−) C4H4O6 · H2O, where = 0, 0.07, 0.06, 0.05, 0.04, 0.03, is achieved using gel technique. The elemental analysis has been done using energy-dispersive X-ray analysis (EDAX) spectrum. The characterization studies ...

Synthesis of nanoparticles of vanadium carbide in the ferrite of nodular cast iron

CERN Document Server

Fras, E; Guzik, E; Lopez, H

2005-01-01

The synthesis method of nanoparticles of vanadium carbide in nodular cast iron is presented. After introduction of this method, the nanoparticles with 10-70 nm of diameter was obtained in the ferrite. The diffraction investigations confirmed that these particles are vanadium carbides of type V/sub 3/C/sub 4/.

Anemia and iron, zinc, copper and magnesium deficiency in Mexican adolescents: National Health and Nutrition Survey 2006.

Science.gov (United States)

De la Cruz-Góngora, Vanessa; Gaona, Berenice; Villalpando, Salvador; Shamah-Levy, Teresa; Robledo, Ricardo

2012-01-01

To describe the frequency of anemia and iron, zinc, copper and magnesium deficiencies among Mexican adolescents in the probabilistic survey ENSANUT 2006. The sample included 2447 adolescents aged 12 to 19 y. Capillary hemoglobin and venous blood samples were collected to measure the concentrations of ferritin, sTFR, CRP, zinc, iron, copper and magnesium. Logistic regression models were constructed to assess the risk for mineral deficiencies. The overall prevalence of anemia was 11.8 and 4.6%, body iron deficiency 18.2 and 7.9% for females and males, respectively. Overall prevalence of tissue iron deficiency was 6.9%, low serum copper were 14.4 and 12.25%; zinc 28.4 and 24.5%, magnesium 40 and 35.3%; for females and males, respectively. There is a high prevalence of mineral deficiency in Mexican adolescents; females were more prone to have more mineral deficiencies. Nutritional interventions are necessaries in order to reduce and control them.

Magnetodielectric coupling in multiferroic holmium iron garnets

International Nuclear Information System (INIS)

Malar Selvi, M.; Chakraborty, Deepannita; Venkateswaran, C.

2017-01-01

Single phase magneto-electric multiferroics require a large magnetic or electric field for producing magneto-electric (ME) and magnetodielectric (MD) effects. For utilizing these effects in devices investigations on the room temperature and low field MD studies are necessary. Recently, efforts have been largely devoted to the investigation of rare earth iron garnets. In the physical method, the preparation of rare earth iron garnet requires high sintering temperature and processing time. To solve these problems, ball milling assisted microwave sintering technique is used to prepare nanocrystalline holmium iron garnets (Ho_3Fe_5O_1_2). Magnetic and dielectric properties of the prepared sample are investigated. These properties get enhanced in nanocrystalline form when compared to the bulk. The MD coupling of the prepared sample is evident from the anomaly in the temperature dependent dielectric constant plot and the ME coupling susceptibility is derived from the room temperature MD measurements. - Highlights: • Formation of single phase Holmium iron garnet reported. • Ball milling assisted microwave sintering reduces the sintering temperature and time. • Holmium iron garnet shows enhanced magnetic and dielectric properties. • Pyromagnetic and pyroelectric measurements confirm the magnetoelectric coupling. • Room temperature magnetodielectric measurements show the nonlinear behaviour.

On the Effect of Pouring Temperature on Spheroidal Graphite Cast Iron Solidification

Directory of Open Access Journals (Sweden)

Alex Escobar

2015-04-01

Full Text Available This work is focused on the effect of pouring temperature on the thermal-microstructural response of an eutectic spheroidal graphite cast iron (SGCI. To this end, experiments as well as numerical simulations were carried out. Solidification tests in a wedge-like part were cast at two different pouring temperatures. Five specific locations exhibiting distinct cooling rates along the sample were chosen for temperature measurements and metallographic analysis to obtain the number and size of graphite nodules at the end of the process. The numerical simulations were performed using a multinodular-based model. Reasonably good numerical-experimental agreements were obtained for both the cooling curves and the graphite nodule counts.

Summary of ENDF/B-V evaluations for carbon, calcium, iron, copper, and lead and ENDF/B-V Revision 2 for calcium and iron

Energy Technology Data Exchange (ETDEWEB)

Fu, C Y

1982-09-01

This report, together with documents already published, describes the ENDF/B-V evaluations of the neutron and gamma-ray-production cross sections for carbon, calcium, iron, copper, and lead and the ENDF/B-V Revision 2 evaluations for calcium and iron.

Nondestructive inspection of ductile cast iron by measurement of minor magnetic hysteresis loops

Czech Academy of Sciences Publication Activity Database

Vértesy, G.; Uchimoto, T.; Takagi, T.; Tomáš, Ivan

2010-01-01

Roč. 659, č. 9 (2010), 355-360 ISSN 0255-5476 R&D Projects: GA ČR GA101/09/1323; GA AV ČR 1QS100100508 Institutional research plan: CEZ:AV0Z10100520 Keywords : magnetic NDE * magnetic adaptive testing * cast iron * magnetic hysteresis Subject RIV: BM - Solid Matter Physics ; Magnetism

Manganese, iron and copper contents in leaves of maize plants ...

African Journals Online (AJOL)

Micronutrients such as boron (B), copper (Cu), iron (Fe), manganese (Mn) and zinc (Zn) play important physiological roles in humans and animals. Zn and B are the micronutrients most often deficient in maize, in Iran. A completely randomized factorial block design experiment was carried out at Fars province of Iran during ...

Development of ELID mirror surface grinding by cast iron bond grinding wheel. Ohkochi memorial technology prize; Chutetsu bond toishi ni yoru denkai inpurosesu doresshingu (ELID) kyomen kensakuho no kaihatsu. Okochi kinen gijutsusho jusho ni yosete

Energy Technology Data Exchange (ETDEWEB)

Omori, H.; Takahashi, I. [Institute of Physical and Chemical Research, Tokyo (Japan); Nakagawa, T. [The University of Tokyo, Tokyo (Japan). Institute of Industrial Science; Hagiuda, Y.; Karikome, K. [Tokyo Metropolitan College of Aeronautical Engineering, Tokyo (Japan)

1997-08-01

Development was accomplished on the electrolytic in-process dressing (ELID) mirror surface grinding process using a cast iron bonded grinding wheel. This paper describes the history of the development, which may be summarized as follows: a study was begun on powder forging of cutting chips in 1970; a research was started on powder forging of decarburized cast iron powder; developments were made on powder metallurgy of cast irons and cast iron bonded lapping tools in 1980, and cast iron bonded diamond grinding wheels were put on the market; a high-efficiency grinding process using MC and cast iron fiber-bonded grinding wheels were developed in 1985 and the grinding wheels made therefrom were put on the market; and a study was begun on the ELID grinding in 1987, and marketing was started on power supply, grinding liquid and tools for the ELID grinding process in 1990. Discussions on converting raw materials for the powder forging into cutting chips have triggered developing the cast iron bonded grinding wheel. The cast iron bonded diamond grinding wheel improves dressability and sharpness of conventional grinding wheels. The grinding wheel is fabricated by mixing carbonyl iron powder, diamond grinding grains and cast iron powder, pressing the mixture in a die, sintering it at 1140 degC, and assembling and dressing the sinter. The grinding stone can grind high-tech materials. 4 figs.

ELABORATION OF MANAGEMENT PLAN OF SOLID WASTE FROM SMALL CAST IRON FOUNDRIES

Directory of Open Access Journals (Sweden)

Carlos Alberto Mendes Moraes

2013-12-01

Full Text Available The foundry industry contributes to society meeting the demand of metal scrap recycling, but, at the same time, it brings a high risk of environmental impact for its many potentially pollutant wastes. Among these, there are slag and used foundry sand (cold cure molding. Through a survey about the production process of a small cast iron company, the collected data was compiled to determine the organizational setting in terms of generation and segregation of waste. From a complete environmental diagnosis carried out in eight small cast iron foundries, one of them was chosen to be a basis for the elaboration of an industrial solid waste management plan, which is becoming necessary to know and manage the generation of wastes qualitatively and quantitatively. A data assessment about the production process was carried out and compiled to determine the actual organizational scenario. As a result of that, it is possible to create a favorable environment to develop tools for environmental impacts prevention, which will permit the migration for more complex actions on the direction of more efficient process, cleaner production, and internal and external recycling of exceeding materials.

The study of high-boron steel and high-boron cast iron used for shield

International Nuclear Information System (INIS)

Pan Xuerong; Lu Jixin; Wen Yaozeng; Wang Zhaishu; Cheng Jiantin; Cheng Wen; Shun Danqi; Yu Jinmu

1996-12-01

The smelting, forging, heat-treatment technology and the mechanical properties of three kinds of high-boron steels (type 1: 0.5% boron; type 2: 0.5% boron and 4% or 2% nickel; type 3: 0.5% boron, 0.5% nickel and 0.5% molybdenum) were studied. The test results show that the technology for smelting, forging and heat-treatment (1050 degree C/0.5 h water cooled + 810 degree C/1 h oil cooled) in laboratory is feasible. Being sensitive to notch, the impact toughness of high-boron steel type 1 is not steady and can not meet the technology requirements on mechanical properties. The mechanical properties of both high-boron steel type 2 and type 3 can meet the technological requirements. The smelting technology of high-boron casting iron containing 0.5% boron was researched. The tests show that this casting iron can be smelted in laboratory and its properties can basically satisfy the technology requirements. (10 refs., 6 figs., 11 tab.)

Comparing the Structure and Mechanical Properties of Welds on Ductile Cast Iron (700 MPa under Different Heat Treatment Conditions

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Ronny M. Gouveia

2018-01-01

Full Text Available The weldability of ductile iron, as widely known, is relatively poor, essentially due to its typical carbon equivalent value. The present study was developed surrounding the heat treatability of welded joints made with a high strength ductile cast iron detaining an ultimate tensile strength of 700 MPa, and aims to determine which heat treatment procedures promote the best results, in terms of microstructure and mechanical properties. These types of alloys are suitable for the automotive industry, as they allow engineers to reduce the thickness of parts while maintaining mechanical strength, decreasing the global weight of vehicles and providing a path for more sustainable development. The results allow us to conclude that heat treatment methodology has a large impact on the mechanical properties of welded joints created from the study material. However, the thermal cycles suffered during welding promote the formation of ledeburite areas near the weld joint. This situation could possibly be dealt through the implementation of post-welding heat treatments (PWHT with specific parameters. In contrast to a ductile cast iron tested in a previous work, the bull-eye ductile cast iron with 700 MPa ultimate tensile strength presented better results during the post-welding heat treatment than during preheating.

Corrosion inhibition of Eleusine aegyptiaca and Croton rottleri leaf extracts on cast iron surface in 1 M HCl medium

International Nuclear Information System (INIS)

Rajeswari, Velayutham; Kesavan, Devarayan; Gopiraman, Mayakrishnan; Viswanathamurthi, Periasamy; Poonkuzhali, Kaliyaperumal; Palvannan, Thayumanavan

2014-01-01

Graphical abstract: - Highlights: • Eleusine aegyptiaca and Croton rottleri are commonly available, less-toxic and eco-friendly inhibitors for cast iron corrosion. • The active constituents present in extracts adsorbed on the iron surface to inhibit the acidic corrosion. • The higher values of E a and ΔH * point out the higher inhibition efficiency noticed for the inhibitors. • Weight loss methods at various temperature and spectral data provides evidence for adsorption mechanism of inhibitors. - Abstract: The adsorption and corrosion inhibition activities of Eleusine aegyptiaca (E. aegyptiaca) and Croton rottleri (C. rottleri) leaf extracts on cast iron corrosion in 1 M hydrochloric acid solution were studied first time by weight loss and electrochemical techniques viz., Tafel polarization and electrochemical impedance spectroscopy. The results obtained from the weight loss and electrochemical methods showed that the inhibition efficiency increased with inhibitor concentrations. It was found that the extracts acted as mixed-type inhibitors. The addition of halide additives (KCl, KBr, and KI) on the inhibition efficiency has also been investigated. The adsorption of the inhibitors on cast iron surface both in the presence and absence of halides follows the Langmuir adsorption isotherm model. The inhibiting nature of the inhibitors was supported by FT-IR, UV–vis, Wide-angle X-ray diffraction and SEM methods

Ductile cast irons: microstructure influence on fatigue crack propagation resistance

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Mauro Cavallini

2010-07-01

Full Text Available Microstructure influence on fatigue crack propagation resistance in five different ductile cast irons (DCI was investigated. Four ferrite/pearlite volume fractions were considered, performing fatigue crack propagation tests according to ASTM E647 standard (R equals to 0.1, 0.5 and 0.75, respectively. Results were compared with an austempered DCI. Damaging micromechanisms were investigated according to the following procedures: - “traditional” Scanning Electron Microscope (SEM fracture surfaces analysis; - SEM fracture surface analysis with 3D quantitative analysis; - SEM longitudinal crack profile analysis - Light Optical Microscope (LOM transversal crack profile analysis;

RECYCLING OF SCRAP AND WASTE OF COPPER AND COPPER ALLOYS IN BELARUS

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S. L. Rovin

2017-01-01

Full Text Available The construction of a new casting and mechanical shop of unitary enterprise «Tsvetmet» in December 2015 has allowed to solve the complex problem of processing and utilization of scrap and wastes of copper and copper alloys in the Republic of Belarus. The technological processes of fire refinement of copper and manufacturing of copper rod from scrap and production of brass rod by hot pressing (extrusion of the continuously casted round billet have been mastered for the first time in the Republic of Belarus.

Cast thermally stable high temperature nickel-base alloys and casting made therefrom

International Nuclear Information System (INIS)

Acuncius, D.A.; Herchenroeder, R.B.; Kirchner, R.W.; Silence, W.L.

1977-01-01

A cast thermally stable high temperature nickel-base alloy characterized by superior oxidation resistance, sustainable hot strength and retention of ductility on aging is provided by maintaining the alloy chemistry within the composition molybdenum 13.7% to 15.5%; chromium 14.7% to 16.5%; carbon up to 0.1%, lanthanum in an effective amount to provide oxidation resistance up to 0.08%; boron up to 0.015%; manganese 0.3% to 1.0%; silicon 0.2% to 0.8%; cobalt up to 2.0%; iron up to 3.0%; tungsten up to 1.0%; copper up to 0.4%; phosphorous up to 0.02%; sulfur up to 0.015%; aluminum 0.1% to 0.5% and the balance nickel while maintaining the Nv number less than 2.31

Effects of mine drainage on the River Hayle, Cornwall. Factors affecting concentrations of copper, zinc, and iron in water, sediments and dominant invertebrate fauna

Energy Technology Data Exchange (ETDEWEB)

Brown, B.E.

1977-02-15

Concentrations of copper, zinc and iron were measured in waters, sediments and invertebrates collected from the River Hayle. In river water at least 70% of copper and iron was associated with the ''particulate'' fraction whereas 80% of zinc was in the ''soluble'' form. Although total concentrations of zinc in water exceeded those of copper approximately ten fold, copper predominated over zinc in the sediments by a factor of approximately three. Iron was the most abundant metal recorded in both water and sediments. Seasonal differences in ''total'' metal content of waters suggested that concentrations of copper, zinc and iron increased during periods of high flow and decreased during lower flows. Copper concentrations in the sediment, unlike zinc and iron, showed markedly higher values during the summer sampling period when flows were minimal. In the ''free-living'' Trichoptera larvae, concentrations of copper and zinc in the tissue appeared to follow copper and zinc levels in the water. Similar relationships in Odonata and Plecoptera larvae were not obtained. Factors affecting animal/metal relationships are discussed with particular reference to adaptation shown by organisms exposed to high concentrations of heavy metals in their environment.

Effect of fully and semi austempering treatment on the fatigue properties of ductile cast iron

International Nuclear Information System (INIS)

Kim, Min Gun; Lim, Bok Kyu; Hwang, Jung Gak; Kim, Dong Youl

2005-01-01

Single phase bainite structure which is obtained by the conventional austempering treatment reduces the ductility of ductile cast iron. Because of the reduction of ductility it is possible to worsen the fatigue properties. Therefore, semi austempered ductile iron which is treated from α+γ is prepared to investigate the static strength and fatigue properties in comparison with fully austempered ductile iron (is treated from γ). In spite of semi austempered ductile iron shows the 86% increase of ductility. Also, semi austempered ductile iron shows the higher fatigue limit and lower fatigue crack growth rate as compared with fully austempered ductile iron. By the fractographical analysis, it is revealed that the ferrite obtained by semi austempering process brings about the plastic deformation (ductile striation) of crack tip and gives the prior path of crack propagation. The relatively low crack growth rate in semi austempered specimen is caused by above fractographical reasons

Characterization and hardenability evaluation of gray cast iron used in the manufacture of diesel engine cylinder liners

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Edgar L. Castellanos-Leal

2017-09-01

Full Text Available The increment of the mechanical properties (surface hardness of engine cylinder is one of the principal goals for foundry company, to increase the competitiveness of their products in the local and foreign market. This study focused on the characterization of the gray cast iron used in the production of engine cylinder liners and metallurgical parameters determination in the design of conventional quenching heat treatment. The characterization was performed by material hardenability evaluation using Grossmann method, and Jominy test; the austenitizing temperature and the severity of cooling medium to a proper hardening of material were selected. Results revealed that the excellent hardness value obtained is attributed to the suitable hardenability of the gray cast iron and adequate severity selection for hardening treatment.

The assessment of fire safety of cast iron structures in historical buildings: Theory and practice

NARCIS (Netherlands)

Twilt, L.; Hunen, M. van

2000-01-01

The assessment of structural fire safety of cast iron structures in historical buildings is difficult because the available information on the fire behaviour is limited, whilst the fire design assumptions (if any) often are not well docu-mented. A complicating factor with regard to protective

Statistical experiments using the multiple regression research for prediction of proper hardness in areas of phosphorus cast-iron brake shoes manufacturing

Science.gov (United States)

Kiss, I.; Cioată, V. G.; Ratiu, S. A.; Rackov, M.; Penčić, M.

2018-01-01

Multivariate research is important in areas of cast-iron brake shoes manufacturing, because many variables interact with each other simultaneously. This article focuses on expressing the multiple linear regression model related to the hardness assurance by the chemical composition of the phosphorous cast irons destined to the brake shoes, having in view that the regression coefficients will illustrate the unrelated contributions of each independent variable towards predicting the dependent variable. In order to settle the multiple correlations between the hardness of the cast-iron brake shoes, and their chemical compositions several regression equations has been proposed. Is searched a mathematical solution which can determine the optimum chemical composition for the hardness desirable values. Starting from the above-mentioned affirmations two new statistical experiments are effectuated related to the values of Phosphorus [P], Manganese [Mn] and Silicon [Si]. Therefore, the regression equations, which describe the mathematical dependency between the above-mentioned elements and the hardness, are determined. As result, several correlation charts will be revealed.

Study of biofilm influenced corrosion on cast iron pipes in reclaimed water

International Nuclear Information System (INIS)

Zhang, Haiya; Tian, Yimei; Wan, Jianmei; Zhao, Peng

2015-01-01

Highlights: • Compared to sterile water, biofilm in reclaimed water promoted corrosion process significantly. • Corrosion rate was accelerated by the biofilm in the first 7 days but was inhibited afterwards. • There was an inverse correlation between the biofilm thickness and general corrosion rate. • Corrosion process was influenced by bacteria, EPS and corrosion products comprehensively. • The corrosion process can be divided into three different stages in our study. - Abstract: Biofilm influenced corrosion on cast iron pipes in reclaimed water was systemically studied using the weight loss method and electrochemical impedance spectroscopy (EIS). The results demonstrated that compared to sterile water, the existence of the biofilm in reclaimed water promoted the corrosion process significantly. The characteristics of biofilm on cast iron coupons were examined by the surface profiler, scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The bacterial counts in the biofilm were determined using the standard plate count method and the most probable number (MPN). The results demonstrated that the corrosion process was influenced by the settled bacteria, EPS, and corrosion products in the biofilm comprehensively. But, the corrosion mechanisms were different with respect to time and could be divided into three stages in our study. Furthermore, several corresponding corrosion mechanisms were proposed for different immersion times.

Study of biofilm influenced corrosion on cast iron pipes in reclaimed water

Energy Technology Data Exchange (ETDEWEB)

Zhang, Haiya, E-mail: flying850612@126.com; Tian, Yimei, E-mail: ymtian_2000@126.com; Wan, Jianmei, E-mail: 563926510@qq.com; Zhao, Peng, E-mail: zhpeng@tju.edu.cn

2015-12-01

Highlights: • Compared to sterile water, biofilm in reclaimed water promoted corrosion process significantly. • Corrosion rate was accelerated by the biofilm in the first 7 days but was inhibited afterwards. • There was an inverse correlation between the biofilm thickness and general corrosion rate. • Corrosion process was influenced by bacteria, EPS and corrosion products comprehensively. • The corrosion process can be divided into three different stages in our study. - Abstract: Biofilm influenced corrosion on cast iron pipes in reclaimed water was systemically studied using the weight loss method and electrochemical impedance spectroscopy (EIS). The results demonstrated that compared to sterile water, the existence of the biofilm in reclaimed water promoted the corrosion process significantly. The characteristics of biofilm on cast iron coupons were examined by the surface profiler, scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The bacterial counts in the biofilm were determined using the standard plate count method and the most probable number (MPN). The results demonstrated that the corrosion process was influenced by the settled bacteria, EPS, and corrosion products in the biofilm comprehensively. But, the corrosion mechanisms were different with respect to time and could be divided into three stages in our study. Furthermore, several corresponding corrosion mechanisms were proposed for different immersion times.

Effect of Phosphorylation and Copper(II or Iron(II Ions Enrichment on Some Physicochemical Properties of Spelt Starch

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Jacek Rożnowski

Full Text Available ABSTRACT: This paper provides an assessment of the effect of saturation of spelt starch and monostarch phosphate with copper or iron ions on selected physicochemical properties of the resulting modified starches. Native and modified spelt starch samples were analyzed for selected mineral element content using Atomic Absorption Spectroscopy (AAS. Thermodynamic properties were measured using DSC, and pasting properties by RVA. Flow curves of 5% pastes were plotted and described using the Herschel-Bulkley model. The structure recovery ratio was measured. AAS analysis established the presence of iron(II and copper(II ions in the samples of modified starches and that potassium and magnesium ions had leached from them. In comparison to unfortified samples, enriching native starch with copper(II ions decreases value of all temperatures of phase transformation about 1.3-2.7 °C, but in case of monostarch phosphates bigger changes (2.8-3.7 °C were observed. Fortified native spelt starch with copper(II ions caused increasing the final viscosity of paste from 362 to 429 mPa·s. However, presence iron(II ions in samples caused reduced its final viscosity by 170 (spelt starch and 103 mPa·s (monostarch phosphate. Furthermore, enriching monostarch phosphate contributed to reduce degree of structure recovery of pastes from 70.9% to 66.6% in case of copper(II ions and to 59.9% in case of iron(II ions.

Study on Selective Removal of Impurity Iron from Leached Copper-Bearing Solution Using a Chelating Resin

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Yubiao Li

2016-10-01

Full Text Available In order to selectively remove iron from copper laden solution after leaching but prior to electrowinning, equilibrium, kinetic, and thermodynamic studies have been conducted on an a chelating resin of Rexp-501 at pH 1.0 and at various temperatures. Both Langmuir and Freundlich models were investigated, with the Langmuir model proving to be more suitable for fitting iron removal performance, with little influence from copper concentration. Compared with the pseudo first order kinetic model, the pseudo second order kinetic model fitted the dynamic adsorption process better, indicating a chemisorption mechanism. Fourier transform infrared spectroscopy (FT-IR results indicated that C=O from carbonyl group played a key role in combining with iron and can be regenerated and reused. However, the C=O of the acylamino group combining with iron was not able to be released after oxalic acid was applied.

Effects of striated laser tracks on thermal fatigue resistance of cast iron samples with biomimetic non-smooth surface

International Nuclear Information System (INIS)

Tong, Xin; Zhou, Hong; Liu, Min; Dai, Ming-jiang

2011-01-01

In order to enhance the thermal fatigue resistance of cast iron materials, the samples with biomimetic non-smooth surface were processed by Neodymium:Yttrium Aluminum Garnet (Nd:YAG) laser. With self-controlled thermal fatigue test method, the thermal fatigue resistance of smooth and non-smooth samples was investigated. The effects of striated laser tracks on thermal fatigue resistance were also studied. The results indicated that biomimetic non-smooth surface was benefit for improving thermal fatigue resistance of cast iron sample. The striated non-smooth units formed by laser tracks which were vertical with thermal cracks had the best propagation resistance. The mechanisms behind these influences were discussed, and some schematic drawings were introduced to describe them.

Formation mechanism of spheroidal carbide in ultra-low carbon ductile cast iron

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Bin-guo Fu

2016-09-01

Full Text Available The formation mechanism of the spheroidal carbide in the ultra-low carbon ductile cast iron fabricated by the metal mold casting technique was systematically investigated. The results demonstrated that the spheroidal carbide belonged to eutectic carbide and crystallized in the isolated eutectic liquid phase area. The formation process of the spheroidal carbide was related to the contact and the intersection between the primary dendrite and the secondary dendrite of austenite. The oxides of magnesium, rare earths and other elements can act as heterogeneous nucleation sites for the spheroidal carbide. It was also found that the amount of the spheroidal carbide would increase with an increase in carbon content. The cooling rate has an important influence on the spheroidal carbide under the same chemical composition condition.

Mechanical strength parameters of cast iron with lamellar graphite and their significance for the design of pressure-carrying reactor components

International Nuclear Information System (INIS)

Janakiev, N.

1977-01-01

The tensile strength of thick-walled components in cast iron with lamellar graphite is lower by about 50 to 65% than that stated in DIN 1691. The usable compressive strength of this material under uni-axial load is about twice as high as its tensile strength. The graphite lamellae are not bonded into the metallic matrix. The width of the gaps between the graphite lamellae and the matrix increases with increasing wall thickness of the casting. In stress calculations for design purposes it is advisable to rely only on the permissible tensile stresses. It is shown that cast iron can be used as structural material for shieldings but is unsuitable for thick-walled reactor components carrying compressive and tensile stresses because its mechanical strength parameters decrease rapidly with increasing wall thickness. (orig.) [de

Grindability of cast Ti-6Al-4V alloyed with copper.

Science.gov (United States)

Watanabe, Ikuya; Aoki, Takayuki; Okabe, Toru

2009-02-01

This study investigated the grindability of cast Ti-6Al-4V alloyed with copper. The metals tested were commercially pure titanium (CP Ti), Ti-6Al-4V, experimental Ti-6Al-4V-Cu (1, 4, and 10 wt% Cu), and Co-Cr alloy. Each metal was cast into five blocks (3.0 x 8.0 x 30.0 mm(3)). The 3.0-mm wide surface of each block was ground using a hand-piece engine with an SiC wheel at four circumferential speeds (500, 750, 1000, and 1250 m/min) at a grinding force of 100 g. The grindability index (G-index) was determined as volume loss (mm(3)) calculated from the weight loss after 1 minute of grinding and the density of each metal. The ratio of the metal volume loss and the wheel volume loss was also calculated (G-ratio, %). Data (n = 5) were statistically analyzed using ANOVA (alpha= 0.05). Ti-6Al-4V and the experimental Ti-6Al-4V-Cu alloys exhibited significantly (p grindability of some of the resultant Ti-6Al-4V-Cu alloys.

Copper and Copper Proteins in Parkinson's Disease

Science.gov (United States)

Rivera-Mancia, Susana; Diaz-Ruiz, Araceli; Tristan-Lopez, Luis; Rios, Camilo

2014-01-01

Copper is a transition metal that has been linked to pathological and beneficial effects in neurodegenerative diseases. In Parkinson's disease, free copper is related to increased oxidative stress, alpha-synuclein oligomerization, and Lewy body formation. Decreased copper along with increased iron has been found in substantia nigra and caudate nucleus of Parkinson's disease patients. Copper influences iron content in the brain through ferroxidase ceruloplasmin activity; therefore decreased protein-bound copper in brain may enhance iron accumulation and the associated oxidative stress. The function of other copper-binding proteins such as Cu/Zn-SOD and metallothioneins is also beneficial to prevent neurodegeneration. Copper may regulate neurotransmission since it is released after neuronal stimulus and the metal is able to modulate the function of NMDA and GABA A receptors. Some of the proteins involved in copper transport are the transporters CTR1, ATP7A, and ATP7B and the chaperone ATOX1. There is limited information about the role of those biomolecules in the pathophysiology of Parkinson's disease; for instance, it is known that CTR1 is decreased in substantia nigra pars compacta in Parkinson's disease and that a mutation in ATP7B could be associated with Parkinson's disease. Regarding copper-related therapies, copper supplementation can represent a plausible alternative, while copper chelation may even aggravate the pathology. PMID:24672633

Fatigue crack tip damaging micromechanisms in a ferritic-pearlitic ductile cast iron

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Francesco Iacoviello

2015-07-01

Full Text Available Due to the peculiar graphite elements shape, obtained by means of a chemical composition control (mainly small addition of elements like Mg, Ca or Ce, Ductile Cast Irons (DCIs are able to offer the good castability of gray irons with the high mechanical properties of irons (first of all, toughness. This interesting properties combination can be improved both by means of the chemical composition control and by means of different heat treatments(e.g. annealing, normalizing, quenching, austempering etc. In this work, fatigue crack tip damaging micromechanisms in a ferritic-pearlitic DCI were investigated by means of scanning electron microscope observations performed on a lateral surface of Compact Type (CT specimens during the fatigue crack propagation test (step by step procedure, performed according to the “load shedding procedure”. On the basis of the experimental results, different fatigue damaging micromechanisms were identified, both in the graphite nodules and in the ferritic – pearlitic matrix.

Design basis for the copper/steel canister. Stage four. Final report

Energy Technology Data Exchange (ETDEWEB)

Bowyer, W.H. [Meadow End Farm, Farnham (United Kingdom)

1998-06-01

The development of the copper/iron canister which has been proposed by SKB for the containment of high level nuclear waste has been studied from the points of view of choice of materials, manufacturing technology and quality assurance. Cast steel has been rejected in favour of cast iron as a candidate material for the load bearing liner. Nodular (or ductile) iron is selected and this is capable of providing mechanical properties which are equally suitable as those of the originally selected high strength low alloy steel. The material specified for the overpack is Oxygen free copper with 50 ppm of phosphorus added. Corrosion studies supported by SKB indicate that in the absence of mechanical failure or accelerated localised corrosion the overpack should provide corrosion shielding of the canister for its full design life. Published work claiming that the nodular iron liner would have corrosion characteristics similar to the carbon steel which had been examined in depth is flawed since the microstructures of the iron and carbon steel specimens used were not investigated. It is highly unlikely that nodular irons in the form used for the experiments would have similar structures to nodular iron in the canisters by chance. If the overpack were breached during the aerobic period of the repository life then very rapid penetration of the inner liner could occur. It has been recognised that the roll forming method is not suitable for serial production and alternatives are being sought. The electron beam welding process has been explored with tenacity but has so far failed to produce a satisfactory lid weld. A new welder is being developed for supply to the SKB pilot plant where development will be continued. An alternative welding process, friction stir welding, is being examined as a candidate for attaching lids. Surface breaking defects may be detected using eddy current methods but there is currently no reliable way of detecting small sub surface defects in the overpack

Detection of fatigue fracture in pearlitic flake graphite cast iron with the help of scanning and transmission electron microscopy

International Nuclear Information System (INIS)

Dunger, B.; Hunger, J.

1976-01-01

To prove the existence of the characteristic features of fatigue fracture in a pearlitic flake graphite cast iron, its fracture surface topography revealed by scanning electron microscopy has been compared with that of a pearlitic steel, the fractures having been caused by static tensile and by cyclic bending tests. The characteristic features of fatigue fracture were visible in the pearlitic matrix of the steel and of the flake graphite cast iron as well. These features differ characteristically from the lamellar structure of the pearlite, particularly after etching the surface area of the fractures. The graphite structures as viewed on the electron scanning and the electron transmission microscope are described. (orig.) [de

Material specification for ductile cast iron in the United States

International Nuclear Information System (INIS)

Sorenson, K.B.

1987-01-01

The United States currently does not have formal design criteria for qualifying ductile cast iron (DCI) transportation casks. There is also no dedicated material standard for DCI for this particular application. A draft ASTM material specification has been written and is currently in the ASTM approval process. This paper reviews the brief history of the development of the specification, the technical basis for the material properties, the ASTM approval process and the current status of the draft specification. The expected implications of having an adopted ASTM specification on the licensing process are also discussed. (orig./DG)

Analysis of ambient pH stress response mediated by iron and copper intake in Schizosaccharomyces pombe.

Science.gov (United States)

Higuchi, Yujiro; Mori, Hikari; Kubota, Takeo; Takegawa, Kaoru

2018-01-01

The molecular mechanism of tolerance to alkaline pH is well studied in model fungi Aspergillus nidulans and Saccharomyces cerevisiae. However, how fission yeast Schizosaccharomyces pombe survives under alkaline stress remains largely unknown, as the genes involved in the alkaline stress response pathways of A. nidulans and S. cerevisiae were not found in the genome of this organism. Since uptake of iron and copper into cells is important for alkaline tolerance in S. cerevisiae, here we examined whether iron and copper uptake processes were involved in conferring tolerance to alkaline stress in S. pombe. We first revealed that S. pombe wild-type strain could not grow at a pH higher than 6.7. We further found that the growths of mutants harboring disruption in the iron uptake-related gene frp1 + , fio1 + or fip1 + were severely inhibited under ambient pH stress condition. In contrast, derepression of these genes, by deletion of their repressor gene fep1 + , caused cells to acquire resistance to pH stress. Together, these results suggested that uptake of iron is essential for ambient pH tolerance in S. pombe. We also found that copper is required for the pH stress response because disruptants of ctr4 + , ctr5 + , ccc2 + and cuf1 + genes, all of which are needed for regulating intracellular Cu + , displayed ambient pH sensitivity. Furthermore, supplementing Fe 2+ and Cu 2+ ions to the culture media improved growth under ambient pH stress. Taken together, our results suggested that uptake of iron and copper is the crucial factor needed for the adaptation of S. pombe to ambient pH stress. Copyright © 2017 The Society for Biotechnology, Japan. Published by Elsevier B.V. All rights reserved.

THE RESULTS OF USING OF INDICATORS OF THE HIGH-TEST CAST IRON OF TYPE ICH STRUCTURE IN CONDITIONS OF PRODUCT

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A. L. Majorov

2006-01-01

Full Text Available The results of development of the indicator of highstrength pig-iron are submitted in the report. The indicator using allows to carry out the testing of the pig-iron structure in conditions of manufacture without additional preparation of the casting surface.

Theoretic and Experimental Studies on the Casting of Large Die-Type Parts Made of Lamellar Graphite Grey Pig Irons by Using the Technology of Polystyrene Moulds Casting from Two Sprue Cups

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Constantin Marta

2012-01-01

Full Text Available This paper presents a comparative analysis between the practical results of pig iron die-type part casting and the results reached by simulation. The insert was made of polystyrene, and the casting was downward vertical. As after the part casting and heat treatment cracks were observed in the part, it became necessary to locate and identify these fissures and to establish some measures for eliminating the casting defects and for locating them. The research method was the comparisons of defects identified through verifications, measurements, and metallographic analyses applied to the cast part with the results of some criteria specific to simulation after simulating the casting process. In order to verify the compatibility between reality and simulation, we then simulated the part casting respecting the real conditions in which it was cast. By visualising certain sections of the cast part during solidification, relevant details occur about the possible evolution of defects. The simulation software was AnyCasting, the measurements were done through nondestructive methods.