WorldWideScience

Sample records for copper smelter dust

  1. Hydrometallurgical treatment of copper smelter dusts. Desarsenification of leaching solutions

    International Nuclear Information System (INIS)

    Alguacil, F.J.; Magne, L.; Navarro, P.; Simpson, J.

    1996-01-01

    Copper smelter dusts contain along with this metal, which is amenable for its recovery, a number of other metals (especially arsenic) which are considered as toxic. Different alternatives have been proposed for the treatment of such metallurgical residues and among them Hydrometallurgy shows good perspectives for its application in this field. In the present work different hydrometallurgical processes proposed for the treatment of copper smelter dusts are described and evaluated together with different alternatives given for the Desarsenification of the leaching solutions. (Author) 36 refs

  2. Improved dust handling at Inco's Copper Cliff smelter

    International Nuclear Information System (INIS)

    Dutton, A.; Warner, A.E.M.; Humphris, M.J.

    1989-01-01

    The Cooper Cliff Smelter Complex comprises three major production departments - a Nickel Smelter for the processing of nickel concentrated to a low iron, nickel - copper sulphide (Bessemer) matte; a Matte Processing plant for the separation of matte sulphides and the production of market nickel oxides and refinery feeds and a Copper Smelter to process copper concentrates to blister copper. Annual production is currently -114,000 tonnes of copper as blister and -110,000 tonnes of nickel. The nickel concentrate (11-13% Ni, 2-3% Cu) is roasted in multi-hearth roasters, smelted in oxy-fuel fired reverberatory furnaces to a 30-35% CuNiCo matte and converted to Bessemer matte (75% CuNiCo) in Peirce-Smith converters. The Bessemer matte is slow cooled and crushed for subsequent separation by mineral dressing techniques in the Matte Processing plant into nickel (sulphide and metallic) concentrates and a copper (chalcocite) concentrate. Nickel sulphides are further processed in fluid bed reactors to oxide market product or refinery feedstock. The copper concentrate (29-30% Cu, 0.9% No.) is dried in fluid bed driers, smelted to a 40-50% copper matte in an Inco oxygen flash furnace and converted to blister copper in Peirce-Smith converters. The chalcocite concentrate from the matte separation stage is flash converted to a semi-blister (3-4% S, 4-5% Ni) and then finished to lighter conventionally. A schematic process flowsheet of the Smelter Complex is shown in this paper

  3. Ammonia leaching of copper smelter dust and precipitation as copper sulphide; Lixiviacion amoniacal de polvos de fundicion de cobre y precipitacion como sulfuro de cobre

    Energy Technology Data Exchange (ETDEWEB)

    Morales, A.; Hevia, J. F.; Cifuentes, G.

    2009-07-01

    The effect of ammonia on the leaching of copper smelter dust and copper precipitation from these solutions as sulphide using sulfur and sulfur dioxide was studied. The precipitation was done in ammoniacal media because this solution produced more satisfactory results at room temperature that a sulphuric media. A solid was precipitated containing 60 % of copper of the dust smelter. The other waste generated contained around 80 % of the arsenic of the original copper smelter dust. Based on the preliminary results obtained in this work it will propose a procedure for the recovery of copper as sulphide from copper smelter dust with parallel confinement of arsenic. (Author) 14 refs.

  4. Transformation of arsenic-rich copper smelter flue dust in contrasting soils: A 2-year field experiment.

    Science.gov (United States)

    Jarošíková, Alice; Ettler, Vojtěch; Mihaljevič, Martin; Penížek, Vít; Matoušek, Tomáš; Culka, Adam; Drahota, Petr

    2018-06-01

    Dust emissions from copper smelters processing arsenic-bearing ores represent a risk to soil environments due to the high levels of As and other inorganic contaminants. Using an in situ experiment in four different forest and grassland soils (pH 3.2-8.0) we studied the transformation of As-rich (>50 wt% As) copper smelter dust over 24 months. Double polyamide bags with 1 g of flue dust were buried at different depths in soil pits and in 6-month intervals; then those bags, surrounding soil columns, and soil pore waters were collected and analysed. Dust dissolution was relatively fast during the first 6 months (5-34%), and mass losses attained 52% after 24 months. The key driving forces affecting dust dissolution were not only pH, but also the water percolation/retention in individual soils. Primary arsenolite (As 2 O 3 ) dissolution was responsible for high As release from the dust (to 72%) and substantial increase of As in the soil (to a 56 × increase; to 1500 mg kg -1 ). Despite high arsenolite solubility, this phase persisted in the dust after 2 years of exposure. Mineralogical investigation indicated that mimetite [Pb 5 (AsO 4 ) 3 (Cl,OH)], unidentified complex Ca-Pb-Fe-Zn arsenates, and Fe oxyhydroxides partly controlled the mobility of As and other metal(loid)s. Compared to As, other less abundant contaminants (Bi, Cu, Pb, Sb, Zn) were released into the soil to a lesser extent (8-40% of total). The relatively high mobility of As in the soil can be seen from decreases of bulk As concentrations after spring snowmelt, high water-extractable fractions with up to ∼50% of As(III) in extracts, and high As concentrations in soil pore waters. Results indicate that efficient controls of emissions from copper smelters and flue dust disposal sites are needed to prevent extensive contamination of nearby soils by persistent As. Copyright © 2018 Elsevier Ltd. All rights reserved.

  5. Transformation of arsenic-rich copper smelter flue dust in contrasting soils: A 2-year field experiment

    Czech Academy of Sciences Publication Activity Database

    Jarošíková, A.; Ettler, V.; Mihaljevič, M.; Penížek, V.; Matoušek, Tomáš; Culka, A.; Drahota, P.

    2018-01-01

    Roč. 237, JUN (2018), s. 83-92 ISSN 0269-7491 Institutional support: RVO:68081715 Keywords : arsenic * smelter dust * soil Subject RIV: CB - Analytical Chemistry, Separation OBOR OECD: Analytical chemistry Impact factor: 5.099, year: 2016

  6. Bio-processing of copper from combined smelter dust and flotation concentrate: A comparative study on the stirred tank and airlift reactors

    Energy Technology Data Exchange (ETDEWEB)

    Vakylabad, Ali Behrad, E-mail: alibehzad86@yahoo.co.uk [Department of Mining Engineering, Shahid Bahonar University, Kerman (Iran, Islamic Republic of); Engineers of Nano and Bio Advanced Sciences Company (ENBASCo.), ATIC, Mohaghegh University (Iran, Islamic Republic of); Schaffie, Mahin [Department of Chemical Engineering, Shahid Bahonar University of Kerman, Kerman (Iran, Islamic Republic of); Mineral Industries Research Centre (MIRC), Shahid Bahonar University of Kerman, Kerman (Iran, Islamic Republic of); Ranjbar, Mohammad [Department of Mining Engineering, Shahid Bahonar University, Kerman (Iran, Islamic Republic of); Mineral Industries Research Centre (MIRC), Shahid Bahonar University of Kerman, Kerman (Iran, Islamic Republic of); Manafi, Zahra [Sarcheshmeh Copper Complex, National Iranian Copper Industry Company (Iran, Islamic Republic of); Darezereshki, Esmaeel [Mineral Industries Research Centre (MIRC), Shahid Bahonar University of Kerman, Kerman (Iran, Islamic Republic of); Energy and Environmental Engineering Research Center (EERC), Shahid Bahonar University of Kerman, Kerman (Iran, Islamic Republic of)

    2012-11-30

    Highlights: Black-Right-Pointing-Pointer Flotation concentrate and smelter dust were sampled and combined. Black-Right-Pointing-Pointer Copper bioleaching from the combined was investigated. Black-Right-Pointing-Pointer Two bio-reactors were investigated and optimized: stirred and airlift. Black-Right-Pointing-Pointer STRs had better technical conditions and situations for bacterial leaching. - Abstract: To scrutinize the influence of the design and type of the bioreactors on the bioleaching efficiency, the bioleaching were evaluated in a batch airlift and a batch stirred tank bioreactors with mixed mesophilic and mixed moderately thermophilic bacteria. According to the results, maximum copper recoveries were achieved using the cultures in the stirred tank bioreactors. It is worth noting that the main phase of the flotation concentrate was chalcopyrite (as a primary sulphide), but the smelter dust mainly contained secondary copper sulphides such as Cu{sub 2}S, CuS, and Cu{sub 5}FeS{sub 4}.Under optimum conditions, copper dissolution from the combined flotation concentrate and smelter dust (as an environmental hazard) reached 94.50% in the STR, and 88.02% in the airlift reactor with moderately thermophilic, after 23 days. Also, copper extractions calculated for the bioleaching using mesophilic bacteria were 48.73% and 37.19% in the STR (stirred tank reactor) and the airlift bioreactor, respectively. In addition, the SEM/EDS, XRD, chemical, and mineralogical analyses and studies confirmed the above results.

  7. Bio-processing of copper from combined smelter dust and flotation concentrate: A comparative study on the stirred tank and airlift reactors

    International Nuclear Information System (INIS)

    Vakylabad, Ali Behrad; Schaffie, Mahin; Ranjbar, Mohammad; Manafi, Zahra; Darezereshki, Esmaeel

    2012-01-01

    Highlights: ► Flotation concentrate and smelter dust were sampled and combined. ► Copper bioleaching from the combined was investigated. ► Two bio-reactors were investigated and optimized: stirred and airlift. ► STRs had better technical conditions and situations for bacterial leaching. - Abstract: To scrutinize the influence of the design and type of the bioreactors on the bioleaching efficiency, the bioleaching were evaluated in a batch airlift and a batch stirred tank bioreactors with mixed mesophilic and mixed moderately thermophilic bacteria. According to the results, maximum copper recoveries were achieved using the cultures in the stirred tank bioreactors. It is worth noting that the main phase of the flotation concentrate was chalcopyrite (as a primary sulphide), but the smelter dust mainly contained secondary copper sulphides such as Cu 2 S, CuS, and Cu 5 FeS 4 .Under optimum conditions, copper dissolution from the combined flotation concentrate and smelter dust (as an environmental hazard) reached 94.50% in the STR, and 88.02% in the airlift reactor with moderately thermophilic, after 23 days. Also, copper extractions calculated for the bioleaching using mesophilic bacteria were 48.73% and 37.19% in the STR (stirred tank reactor) and the airlift bioreactor, respectively. In addition, the SEM/EDS, XRD, chemical, and mineralogical analyses and studies confirmed the above results.

  8. Bio-processing of copper from combined smelter dust and flotation concentrate: a comparative study on the stirred tank and airlift reactors.

    Science.gov (United States)

    Vakylabad, Ali Behrad; Schaffie, Mahin; Ranjbar, Mohammad; Manafi, Zahra; Darezereshki, Esmaeel

    2012-11-30

    To scrutinize the influence of the design and type of the bioreactors on the bioleaching efficiency, the bioleaching were evaluated in a batch airlift and a batch stirred tank bioreactors with mixed mesophilic and mixed moderately thermophilic bacteria. According to the results, maximum copper recoveries were achieved using the cultures in the stirred tank bioreactors. It is worth noting that the main phase of the flotation concentrate was chalcopyrite (as a primary sulphide), but the smelter dust mainly contained secondary copper sulphides such as Cu(2)S, CuS, and Cu(5)FeS(4).Under optimum conditions, copper dissolution from the combined flotation concentrate and smelter dust (as an environmental hazard) reached 94.50% in the STR, and 88.02% in the airlift reactor with moderately thermophilic, after 23 days. Also, copper extractions calculated for the bioleaching using mesophilic bacteria were 48.73% and 37.19% in the STR (stirred tank reactor) and the airlift bioreactor, respectively. In addition, the SEM/EDS, XRD, chemical, and mineralogical analyses and studies confirmed the above results. Copyright © 2012 Elsevier B.V. All rights reserved.

  9. Comparative results of copper flotation from smelter slag and granulated smelter slag

    OpenAIRE

    Milanović, Dragan; Stanujkić, Dragiša; Ignjatović, Miroslav R.

    2013-01-01

    Smelter slag is obtained in the process of metallurgical converting of copper concentrate in the Smelter Plant in Bor, Serbia. Today, the reserves of this material are evaluated at about more of a year, with the average copper content of 0.6-0.9%. Production of copper concentrate by flotation of smelter slag has started in 2001. Flotation concentrate goes to the Copper Smelter once more for production of copper cathodes and the rough flotation tailings go to the flotation tailing dump. Copper...

  10. Heavy metals in the atmosphere coming from a copper smelter in Chile

    Science.gov (United States)

    Romo-Kröger, C. M.; Morales, J. R.; Dinator, M. I.; Llona, F.; Eaton, L. C.

    The Chilean mine El Teniente is the world's largest underground copper mine. It operates a giant smelter at Caletones (34° 7' S, 70° 27' W) and we have found it is the major source of air contamination in the region. In August 1991 a special circumstance occurred due to a labor strike, with total cessation of activities. A time series analysis of airborne particles collected at a site about 13 km from the smelter was performed in a period including the strike. The PIXE method and other techniques were used to analyse fine (Elemental characterization of soil samples by radioactive source analysis demonstrated that this group of elements did not come from airborne soil dust. Cluster analyses of the interelement correlation matrices, resulting from PIXE data, showed one group (Si, K, Ca, Fe) with main origin in soil and another group (S, Cu, Zn, As) coming from the copper smelter.

  11. Dust from Zambian smelters: mineralogy and contaminant bioaccessibility

    Czech Academy of Sciences Publication Activity Database

    Ettler, V.; Vítková, M.; Mihaljevič, M.; Šebek, O.; Klementová, Mariana; Veselovský, F.; Vybíral, P.; Kříbek, B.

    2014-01-01

    Roč. 36, č. 5 (2014), s. 919-933 ISSN 0269-4042 Institutional support: RVO:61388980 Keywords : Dust * Metal smelting * Copper * Cobalt * Solid speciation Subject RIV: CA - Inorganic Chemistry Impact factor: 2.566, year: 2014

  12. Environmental Exposure to Arsenic, Lead, and Cadmium in People Living near Janghang Copper Smelter in Korea.

    Science.gov (United States)

    Kim, Yong-Dae; Eom, Sang-Yong; Yim, Dong-Hyuk; Kim, In-Soo; Won, Hee-Kwan; Park, Choong-Hee; Kim, Guen-Bae; Yu, Seung-Do; Choi, Byung-Sun; Park, Jung-Duck; Kim, Heon

    2016-04-01

    Concentrations of heavy metals exceed safety thresholds in the soil near Janghang Copper Refinery, a smelter in Korea that operated from 1936 to 1989. This study was conducted to evaluate the level of exposure to toxic metals and the potential effect on health in people living near the smelter. The study included 572 adults living within 4 km of the smelter and compared them with 413 controls group of people living similar lifestyles in a rural area approximately 15 km from the smelter. Urinary arsenic (As) level did not decrease according to the distance from the smelter, regardless of gender and working history in smelters and mines. However, in subjects who had no occupational exposure to toxic metals, blood lead (Pb) and cadmium (Cd) and urinary Cd decreased according to the distance from the smelter, both in men and women. Additionally, the distance from the smelter was a determinant factor for a decrease of As, Pb, and Cd in multiple regression models, respectively. On the other hands, urinary Cd was a risk factor for renal tubular dysfunction in populations living near the smelter. These results suggest that Janghang copper smelter was a main contamination source of As, Pb, and Cd, and populations living near the smelter suffered some adverse health effects as a consequence. The local population should be advised to make efforts to reduce exposure to environmental contaminants, in order to minimize potential health effects, and to pay close attention to any health problems possibly related to toxic metal exposure.

  13. Sulfur dioxide emissions from Peruvian copper smelters detected by the ozone monitoring instrument

    NARCIS (Netherlands)

    Carn, S.A.; Krueger, A.J.; Krotkov, N.A.; Yang, Kai; Levelt, P.F.

    2007-01-01

    We report the first daily observations of sulfur dioxide (SO2) emissions from copper smelters by a satellite-borne sensor - the Ozone Monitoring Instrument (OMI) on NASA's EOS/Aura spacecraft. Emissions from two Peruvian smelters (La Oroya and Ilo) were detected in up to 80% of OMI overpasses

  14. Natural environment in the area of copper smelter plants. Trend of changes

    Directory of Open Access Journals (Sweden)

    Łucja Strzelec

    2012-06-01

    Full Text Available Findings of air quality are brought forward in the area of copper industry impact with particular attention paid to copper smelter plants located in Legnica and Głogów area covering the period from 1980 to 2010. The paper identifies occurring changes and trends in the course of years. Lowering of dust-gaseous emissions from the most crucial sources in the area of LegnicaGłogów Copper Mining Region improved air quality in this region in the significant way. The fact is also of some importance that emission of pollutants from big sources combusting fuels for energy generation was reduced either by rundown of production or liquidation of some plants. Based on the conducted state environmental monitoring it is concluded that at present emission of pollutants from industrial sources affects air quality to a lesser degree. There are still problems of air protection waiting to be solved which are connected with: – emission of gaseous-dust pollutants from domestic-municipal sector i. e. so called low emission from individual heating of dwellings. The sources are low emitters where often coal is combusted together with various types of waste. Therefore after starting the period of centrally heated dwellings air quality monitoring stations recorded evidently the increase of dust and gaseous pollutants including benzo (a pirene. – pollutants emission from road transport which is the cause of high concentration of nitrogen oxides, carbon monoxide and hydrocarbons particularly in the vicinity of roads and streets of big road traffic density. Materials and methods: The base of the study were findings obtained from District Inspectorate of Environmental Protection in Legnica in the framework of carried out since 1991 the state environmental monitoring in national, regional and local network. In the period from 1980 till 1990 the studies performed Research Centre of Environmental Control in Legnica.

  15. Selecting an oxygen plant for a copper smelter modernization

    Science.gov (United States)

    Larson, Kenneth H.; Hutchison, Robert L.

    1994-10-01

    The selection of an oxygen plant for the Cyprus Miami smelter modernization project began with a good definition of the use requirements and the smelter process variables that can affect oxygen demand. To achieve a reliable supply of oxygen with a reasonable amount of capital, critical equipment items were reviewed and reliability was added through the use of installed spares, purchase of insurance spare parts or the installation of equipment design for 50 percent of the production design such that the plant could operate with one unit while the other unit is being maintained. The operating range of the plant was selected to cover variability in smelter oxygen demand, and it was recognized that the broader operating range sacrificed about two to three percent in plant power consumption. Careful consideration of the plant "design point" was important to both the capital and operating costs of the plant, and a design point was specified that allowed a broad range of operation for maximum flexibility.

  16. Removal of Arsenic from Wastewaters by Airlift Electrocoagulation: Part 3: Copper Smelter Wastewater Treatment

    DEFF Research Database (Denmark)

    Hansen, H.K.; Ottosen, Lisbeth M.

    2010-01-01

    The arsenic content in wastewater is of major concern for copper smelters. A typical complex wastewater treatment is needed with a combination of chemical and physical processes. Electrocoagulation (EC) has shown its potential for arsenic removal due to the formation of ferric hydroxide-arsenate ...... threshold value for wastewater discharge could rapidly be reached when the conventional method did not clean the wastewater sufficiently....

  17. Reductive-sulfurizing smelting treatment of smelter slag for copper and cobalt recovery

    Directory of Open Access Journals (Sweden)

    Li Y.

    2018-01-01

    Full Text Available Recovery of copper and cobalt from smelter slag using reductive-sulfurizing smelting method was performed in this study. The effects of reductive agent (coke, sulfurizing agent (pyrite, slag modifier (CaO and smelting temperature and duration on the extractive efficiencies of Cu, Co and Fe were discussed. The phase compositions and microstructure of the materials, copper-cobalt matte and cleaned slag were determined. The results showed that copper and cobalt contents in cleaned slag could decrease averagely to 0.18% and 0.071% respectively after cleaning. 91.99% Cu and 92.94% Co and less than 38.73% Fe were recovered from the smelter slag under the optimum conditions: 6 wt.% coke, 20 wt.% pyrite and 6 wt.% CaO addition to the smelter slag, smelting temperature of 1350°C and smelting duration of 3h. The addition of CaO can increase the selectivity of Co recovery. The cleaning products were characterized by XRD and SEM-EDS analysis. The results showed that the main phases of copper-cobalt matte were iron sulfide (FeS, geerite (Cu8S5, iron cobalt sulfide (Fe0.92Co0.08S and Fe-Cu-Co alloy. The cleaned slag mainly comprised fayalite (Fe2SiO4, hedenbergite (CaFe(Si2O6 and magnetite (Fe3O4.

  18. Analysis of copper losses throughout weak acid effluent flows generated during off-gas treatment in the New Copper Smelter RTB Bor

    Directory of Open Access Journals (Sweden)

    Dragana Ivšić-Bajčeta

    2013-09-01

    Full Text Available The previous inadequate treatment of off-gas in RTB Bor in Serbia has resulted in serious pollution of the environment and the possibly high losses of copper through the effluent flows. The project of New Copper Smelter RTB Bor, besides the new flash smelting furnace (FSF and the reconstruction of Pierce-Smith converter (PSC, includes more effective effluent treatment. Paper presents an analysis of the new FSF and PSC off-gas treatment, determination of copper losses throughout generated wastewaters and discussion of its possible valorization. Assumptions about the solubility of metals phases present in the FSF and PSC off-gas, obtained by the treatment process simulation, were compared with the leaching results of flue dusts. Determined wastewaters characteristics indicate that the PSC flow is significantly richer in copper, mostly present in insoluble metallic/sulfide form, while the FSF flow has low concentration of copper in the form of completely soluble oxide/sulfate. The possible scenario for the copper valorization, considering arsenic and lead as limiting factors, is the separation of the FSF and PSC flows, return of the metallic/sulfide solid phase to the smelting process and recovery from the sulfate/oxide liquid phase.

  19. Bioindication of air pollution effects near a copper smelter in Brazil using mango trees and soil microbiological properties

    International Nuclear Information System (INIS)

    Klumpp, Andreas; Hintemann, Therese; Santana Lima, Josanidia; Kandeler, Ellen

    2003-01-01

    A field study near the copper smelter of a large industrial complex examined air pollution effects on vegetation and soil parameters in Camacari (northeast Brazil). Close to the smelter, soil pH-value was lower and total acidity as well as organic carbon contents were higher compared with a site far from the source and two reference sites. The acidification of top soil particularly and the drastically enhanced plant-available copper concentrations were caused by atmospheric deposition. High sulphur and copper deposition significantly reduced microbial biomass and altered functional diversity of soil microorganisms (arylsulphatase and xylanase). Large accumulations of sulphur, arsenic and copper were detected in mango leaves (Mangifera indica) growing downwind from the smelter suggesting potential food chain-mediated risk. - Atmospheric emissions in northeast Brazil have transformed soil pH, accumulated in soil and plants as sulphur and heavy metals, and affected the functional diversity of soil microorganisms

  20. Bioindication of air pollution effects near a copper smelter in Brazil using mango trees and soil microbiological properties

    Energy Technology Data Exchange (ETDEWEB)

    Klumpp, Andreas; Hintemann, Therese; Santana Lima, Josanidia; Kandeler, Ellen

    2003-12-01

    A field study near the copper smelter of a large industrial complex examined air pollution effects on vegetation and soil parameters in Camacari (northeast Brazil). Close to the smelter, soil pH-value was lower and total acidity as well as organic carbon contents were higher compared with a site far from the source and two reference sites. The acidification of top soil particularly and the drastically enhanced plant-available copper concentrations were caused by atmospheric deposition. High sulphur and copper deposition significantly reduced microbial biomass and altered functional diversity of soil microorganisms (arylsulphatase and xylanase). Large accumulations of sulphur, arsenic and copper were detected in mango leaves (Mangifera indica) growing downwind from the smelter suggesting potential food chain-mediated risk. - Atmospheric emissions in northeast Brazil have transformed soil pH, accumulated in soil and plants as sulphur and heavy metals, and affected the functional diversity of soil microorganisms.

  1. Preliminary studies of airborne particulate emmisions from the Ampellum S.A. copper smelter, Zlatna, Romania

    Directory of Open Access Journals (Sweden)

    Ben J. Williamson

    2003-04-01

    Full Text Available Preliminary studies have been carried on the characterization of particulate emissions from the Ampellum S.A. copper smelter in the town of Zlatna, Romania. The particulates studied were collected on polycarbonate filters using air pump apparatus and on the surfaces of lichens. Mass of total suspended particulates (TSP and PM10 varied from 19 to 230 μg/m3 and 3 to 146 μg/m3, respectively (PM10/TSP = 0.14 to 1.0, depending on wind direction and proximity to the smelter. Particulates on collection filters from a site directly downwind from the smelter have a mean equivalent spherical diameter (ESD of 0.94 μm (s.d. 1.1 and are dominantly made up of material with the composition of anglesite (PbSO4. The remainder of the material is a heterogeneous mixture of silicates and Fe-, Pb- and Cu-bearing phases. Particulates > 5 μm ESD are rare on the TSP filters, mainly due to the restricted sampling durations possible with the equipment used (<3 hours. Particulates have therefore been studied in the lichen Acarospora smaragdula, which was growing on posts downwind from the smelter and which was found to contain high levels and a broader range of particulates compared with the filters (<5 to 100 μm in diameter. Larger particles include 20-30 μm diameter Fe-rich spherules, which occasionally have Pb- and S-rich encrustations on their surfaces. The nature and possible health effects of the particulates are discussed and recommendations made for future studies.

  2. Recirculation of Chilean copper smelting dust with high impurities contents to the smelting process

    Energy Technology Data Exchange (ETDEWEB)

    Sano, H.; Fujisawa, T. [Nagoya Univ., Nagoya (Japan). EcoTopia Science Inst.; Montenegro, V. [Nagoya Univ., Nagoya (Japan). Dept. of Materials Science and Engineering

    2007-07-01

    Dust generated during the copper smelting process is generally stabilized using hydrometallurgical methods as it contains high concentrations of arsenic. In this laboratory study, dust was recirculated during the smelting process in order to recover more copper and decrease dust emissions while recovering more copper. The behaviour of impurities and their influence on matte quality was also investigated. Industrial matte, flue dust, slag, and copper concentrates from a Chilean smelter were used as test materials. Dust recirculation tests were conducted in a simulated electric furnace. Off-gases were collected in a reaction tube, and the condensed volatile matter, slag, and matte phases were analyzed for their elemental content by inductively coupled plasma atomic emission spectrometry. The distribution of arsenic (As); antimony (Sb), bismuth (Bi), lead (Pb), and zinc (Zn) were investigated by varying the amounts of dust recirculating to the smelting stage with 21 per cent of the oxygen. Results showed that distributions of all analyzed elements increased with recirculation. It was concluded that copper can be recovered using the dust recirculation technique. However, impurities may limit the efficacy of the dust recirculation process. 6 refs., 3 tabs., 4 figs.

  3. Plant reactions as indicators of air pollution in the vicinity of a copper smelter

    Directory of Open Access Journals (Sweden)

    Jerzy Fabiszewski

    2014-01-01

    Full Text Available Several higher plant species and epiphytic lichen Hypogymnia physodes (L. Nyl. were examined in the vicinity of a copper smelter. The investigations included field experiments. Ecological surveys of some biotests and bioreactions using exposure of higher plants and transplanted lichens were critically appraised. Such basic processes of plants as photosynthesis and respiration, as well as the quantitative composition of chlorophyll pigments were used as biotests. The results indicate that the photosynthesis intensity is the most useful measure for the estimation of the effect of both heavy metal and SO2 pollutants. The degrees of chlorophyll degradation were in keeping with visual symptoms of injuries. For the ecological monitoring the measurement of respiration intensity, especially in lichens is not recommended. All applied biotests are presented in maps illustrating the degree of degradation of the area examined.

  4. Mercury contamination in vicinity of secondary copper smelters in Fuyang, Zhejiang Province, China: Levels and contamination in topsoils

    International Nuclear Information System (INIS)

    Yin Xuebin; Yao Chunxia; Song Jing; Li Zhibo; Zhang Changbo; Qian Wei; Bi De; Li Chenxi; Teng Ying; Wu Longhua; Wan Hongdong; Luo Yongming

    2009-01-01

    In the present study, we aim to investigate the extent of soil contamination by Hg, particularly by anthropogenic Hg, and tentatively estimate the total Hg (Hg T ) accumulation in topsoils (0-15 cm) in Fuyang, Zhejiang Province-a secondary Cu smelter of China. The results show that the levels of soil Hg in the vicinity of the smelters have been substantially elevated following local smelting activities. The spatial distribution of soil Hg in this area reveals a rapid decrease as the distance from the smelter reaches 1.5 km, which is probably due to the quick deposition process of particulate Hg and reactive gaseous Hg emitted from the smelters. The total accumulation of Hg T in the topsoils of the study area of 10.9 km 2 is approximately 365-561 kg and of which 346-543 kg might be contributed by anthropogenic emission alone with an annual emission of 17.3-27.2 kg Hg to the topsoils. - Secondary copper smelters in Fuyang release a considerable amount of mercury into topsoils.

  5. The structure of spruce-fir tree stands mortality under impact of the Middle Ural copper smelter emissions

    Directory of Open Access Journals (Sweden)

    I. E. Bergman

    2015-04-01

    Full Text Available The influence of industrial pollution on mortality values (dead fallen wood and dead standing trees and its distribution by degrees of decomposition were investigated in spruce-fir forest stands in the vicinity of the Middle Ural copper smelter (the city of Revda, Sverdlovsk region. The total mortality and mortality in each size category did not depend on the distance to the source of pollution. At the same time, the amount of dead fallen wood was significantly greater (1.9 times in the polluted area (2 and 4 km from the smelter as compared with the background territory (30 km from the smelter. Mortality proportion out of the total number of the trees (both live and dead did not differ significantly between the sites, although this parameter tended to increase nearer the smelter. The distribution of mortality by size categories revealed significant differences between background territory and site with average level of contamination, as well as background territory and highly contaminated site. Observed differences are associated with an increased proportion of lesser mortality near the smelter (by 15 % and 12 % as compared with areas of background and middle levels of contamination, respectively, as well as because of double-declining of medium- and large-sized mortality near the smelter. The distribution of the living tree stands by size categories also has a connection with level of contamination. The average diameters of the living tree stand and the elements of coarse woody debris (dead fallen wood and dead standing trees do not differ significantly between sites with different levels of contamination. For the small-sized dead fallen wood, the proportion of weakly decomposed stems increased with the level of pollution, while proportion of strongly decomposed stems decreased. The distribution of medium- and large-sized dead fallen wood on the stages of decomposition does not vary between sites with different levels of pollution.

  6. Long-term dynamics of heavy metals in the upper horizons of soils in the region of a copper smelter impacts during the period of reduced emission

    Science.gov (United States)

    Vorobeichik, E. L.; Kaigorodova, S. Yu.

    2017-08-01

    The 23-year-long dynamics of actual acidity (pHwater) and acid-soluble heavy metals (Cu, Pb, Cd, Zn) in the forest litter and humus horizon of soils in spruce-fir forests were studied in the area subjected to the long-term (since 1940) pollution with atmospheric emissions from the Middle Ural Copper Smelter (Revda, Sverdlovsk oblast). For this purpose, 25 permanent sample plots were established on lower slopes at different distances from the enterprise (30, 7, 4, 2, and 1 km; 5 plots at each distance) in 1989. The emissions from the smelter have decreased since the early 1990s. In 2012, the emissions of sulfur dioxide and dust decreased by 100 and 40 times, respectively, as compared with the emissions in 1980. Samples of litter and humus horizons were collected on permanent plots in 1989, 1999, and 2012. The results indicate that the pH of the litter and humus horizons restored to the background level 10 and 23 years after the beginning of the reduction in emissions, respectively. However, these characteristics in the impact zone still somewhat differ from those in the background area. In 2012, the content of Cu in the litter decreased compared to 1989 on all the plots; the content of Cu in the humus horizon decreased only in the close vicinity of the smelter. The contents of other metals in the litter and humus horizons remain constant or increased (probably because of the pH-dependent decrease in migration capacity). The absence of pronounced removal of metals from soils results in the retention of high contamination risk and the conservation of the suppressed state of biota within the impact zone.

  7. Rapid Analysis of Copper Ore in Pre-Smelter Head Flow Slurry by Portable X-ray Fluorescence.

    Science.gov (United States)

    Burnett, Brandon J; Lawrence, Neil J; Abourahma, Jehad N; Walker, Edward B

    2016-05-01

    Copper laden ore is often concentrated using flotation. Before the head flow slurry can be smelted, it is important to know the concentration of copper and contaminants. The concentration of copper and other elements fluctuate significantly in the head flow, often requiring modification of the concentrations in the slurry prior to smelting. A rapid, real-time analytical method is needed to support on-site optimization of the smelter feedstock. A portable, handheld X-ray fluorescence spectrometer was utilized to determine the copper concentration in a head flow suspension at the slurry origin. The method requires only seconds and is reliable for copper concentrations of 2.0-25%, typically encountered in such slurries. © The Author(s) 2016.

  8. The impact of a copper smelter on adjacent soil zinc and cadmium fractions and soil organic carbon

    Energy Technology Data Exchange (ETDEWEB)

    Liu Ling; Wu Longhua; Luo Yongming [Key Lab. of Soil Environment and Pollution Remediation, Chinese Academy of Sciences, NJ (China); Zhang Changbo [Shanghai Academy of Environmental Sciences, SH (China); Jiang Yugen; Qiu Xiya [Soils and Fertilisers Div., Fuyang City Agricultural Bureau, Hangzhou, ZJ (China)

    2010-07-15

    Purpose: We investigated the chemical fractions of Zn, Cd and Cu in soils collected from positions at different distances from a copper smelter and studied the relationships between distribution patterns of Zn, Cd and Cu, fractions and soil organic carbon (SOC), especially ''black carbon'' (BC), in contaminated soils. The relationships between soil particle size and concentrations of Zn and Cd in contaminated soil were also examined. Materials and methods: Soil samples were collected from field sites at different distances from the copper smelter, air-dried and passed through 0.25-mm and 0.149-mm nylon mesh sieves. The SOC and BC were determined. Aqua regia and sequentially extracted Zn, Cd and Cu fractions in soil and the different sizes of soil particles, and metal concentrations (Zn, Cd and Cu) in BC were also determined. Results and discussion: The soils were heavily contaminated by fly ash from the copper smelter. Concentrations of Zn, Cd and Cu in soil and SOC decreased with increasing distance from the smelter. Concentrations of Zn and Cd in the surface soil (0-15 cm) decreased from 27,017 to 892 mg kg{sup -1} and from 18.7 to 1.04 mg kg{sup -1}, respectively. Soil BC and concentrations of Zn, Cd and Cu in the BC fraction showed significant and positive relationships with the corresponding aqua regia metal concentrations in soil. Soil Zn and Cd occurred predominantly in the exchangeable and reducible fractions, but residual and oxidisable fractions of Cu that were not considered mobile or bioavailable were predominant (>60%). Concentrations of Zn and Cd in the soil particle size fractions tended to increase with decreasing particle size. Conclusions: The Cd and Zn and BC were all derived from the fly ash of the smelter. Concentrations of Zn and Cd and BC in the soil decreased significantly with increasing distance from the smelter. Zinc and Cd in contaminated soils increased as particle size decreased, and were mainly in highly available

  9. A solidification/stabilization process for wastewater treatment sludge from a primary copper smelter

    Directory of Open Access Journals (Sweden)

    Ivšić-Bajčeta Dragana

    2013-01-01

    Full Text Available Wastewater treatment sludge from primary copper smelter is characterized as hazardous waste that requires treatment prior disposal due to significant amount of heavy metals and arsenic. The aim of the presented study was to investigate the feasibility and the effectiveness of solidification/stabilization process of the sludge using fly ash and lime as binders. The effectiveness of the process was evaluated by Unconfined Compressive Strength (UCS testing, leaching tests (EN 12457-4 and Toxicity Characteristic Leaching Procedure (TCLP and Acid Neutralization Capacity (ANC test. All samples reached target UCS of 0.35 MPa. Calcium to silicon concentration ratio (cCa/cSi, determined by X-Ray Fluorescence (XRF analysis, was identified as main factor governing strength development. Inductively coupled plasma-optical emission spectrometry (ICP-OES analyses of solutions after leaching tests showed excellent stabilization of Cu, Ni, Pb and Zn (above 99 % and arsenic (above 90 % in samples with high Ca(OH2 content. Results of ANC test indicated that buffering capacity of solidified material linearly depended on Ca concentration in FA and lime. Sample with 20 % of binder heaving 50 % of FA and 50 % of lime met all requirements to be safely disposed. [Projekat Ministarstva nauke Republike Srbije, br. 34033

  10. Reactivity of fly ash from copper smelters in an Oxisol: implications for smelter-polluted soil systems in the tropics

    Czech Academy of Sciences Publication Activity Database

    Ettler, V.; Petráňová, Veronika; Vítková, M.; Mihaljevič, M.; Šebek, O.; Kříbek, B.

    2016-01-01

    Roč. 16, č. 1 (2016), s. 115-124 ISSN 1439-0108 Institutional support: RVO:68378297 Keywords : cobalt * copper * fly ash * leaching * Oxisol * smelting Subject RIV: DD - Geochemistry Impact factor: 2.522, year: 2016 http://link.springer.com/article/10.1007%2Fs11368-015-1174-7

  11. Heavy metal tolerance in Agropyron repens (L. P. Bauv. populations from the Legnica copper smelter area, Lower Silesia

    Directory of Open Access Journals (Sweden)

    Teresa Brej

    2014-01-01

    Full Text Available The copper smelter "Legnica" is one of the oldest plants in Lower Silesia. Among the few weed species spontaneously migrating to the area around the emitter there is couch grass (Agropyron repens (L. P. Bauv.. The purpose of this study was to analyse whether the local couch grass populations, growing at various distances from the smelter, differ in tolerance to heavy metals occurring in this area. The populations were tested for tolerance to five metals (Cu, Zn, Pb, Cd, Ni using the root elongation method. The highest tolerance to Pb developed in two populations localized nearest the smelter. Similarly, all populations of couch grass from the vicinity of the smelter show a high tolerance to copper, particularly the plants from the most contaminated site. The IT for the latter population is almost 1509r, even at the highest dose of Cu. For Zn a nearing IT as for Cu was obtained. Comparing the shape of IT curves for Cd, special emphasis is put on the fact that a fixed tolerance to cadmium occurs only in the population localized closest to the emitter. The analysis of Ni-tolerance curves, of which the content in local soil is minimal, does not confirm the thesis on possibility of development of co-tolerance in the surveyed populations. It appeared that stress conditions existing near the smelter do not inhibit seed production in couch grass, but prevent a successful course of their germination on polluted soil. The improvement of soil even by 50% (addition of unpolluted soil does not improve the poor process of germination in couch grass growing nearest to the smelter. Of importance is the fact that the highest number of seeds germinated on their own, polluted soil. The need of metals' content for plant germination in populations most distant from the smelter is evidenced by an almost 30% reduction of germination ability of local seeds after addition of unpolluted soil. Another significant observation was the fact that, in spite of a poor

  12. The heavy metal partition in size-fractions of the fine particles in agricultural soils contaminated by waste water and smelter dust

    International Nuclear Information System (INIS)

    Zhang, Haibo; Luo, Yongming; Makino, Tomoyuki; Wu, Longhua; Nanzyo, Masami

    2013-01-01

    Highlights: ► A continuous flow ultra-centrifugation method has been developed to obtain fine particles from polluted agricultural soil. ► Pollution source affected the heavy metal fractionation in size-fractions by changing soil particle properties. ► The iron oxides affected the distribution of lead species more than other metals in the smelter dust polluted particles. -- Abstract: The partitioning of pollutant in the size-fractions of fine particles is particularly important to its migration and bioavailability in soil environment. However, the impact of pollution sources on the partitioning was seldom addressed in the previous studies. In this study, the method of continuous flow ultra-centrifugation was developed to separate three size fractions (<1 μm, <0.6 μm and <0.2 μm) of the submicron particles from the soil polluted by wastewater and smelter dust respectively. The mineralogy and physicochemical properties of each size-fraction were characterized by X-ray diffraction, transmission electron microscope etc. Total content of the polluted metals and their chemical speciation were measured. A higher enrichment factor of the metals in the fractions of <1 μm or less were observed in the soil contaminated by wastewater than by smelter dust. The organic substance in the wastewater and calcite from lime application were assumed to play an important role in the metal accumulation in the fine particles of the wastewater polluted soil. While the metal accumulation in the fine particles of the smelter dust polluted soil is mainly associated with Mn oxides. Cadmium speciation in both soils is dominated by dilute acid soluble form and lead speciation in the smelter dust polluted soil is dominated by reducible form in all particles. This implied that the polluted soils might be a high risk to human health and ecosystem due to the high bioaccessblity of the metals as well as the mobility of the fine particles in soil

  13. The heavy metal partition in size-fractions of the fine particles in agricultural soils contaminated by waste water and smelter dust

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Haibo, E-mail: hbzhang@yic.ac.cn [Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003 (China); Luo, Yongming, E-mail: ymluo@yic.ac.cn [Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003 (China); Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008 (China); Makino, Tomoyuki [National Institute for Agro-Environmental Sciences, Tsukuba 3058604 (Japan); Wu, Longhua [Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008 (China); Nanzyo, Masami [Tohoku University, Sendai 9808576 (Japan)

    2013-03-15

    Highlights: ► A continuous flow ultra-centrifugation method has been developed to obtain fine particles from polluted agricultural soil. ► Pollution source affected the heavy metal fractionation in size-fractions by changing soil particle properties. ► The iron oxides affected the distribution of lead species more than other metals in the smelter dust polluted particles. -- Abstract: The partitioning of pollutant in the size-fractions of fine particles is particularly important to its migration and bioavailability in soil environment. However, the impact of pollution sources on the partitioning was seldom addressed in the previous studies. In this study, the method of continuous flow ultra-centrifugation was developed to separate three size fractions (<1 μm, <0.6 μm and <0.2 μm) of the submicron particles from the soil polluted by wastewater and smelter dust respectively. The mineralogy and physicochemical properties of each size-fraction were characterized by X-ray diffraction, transmission electron microscope etc. Total content of the polluted metals and their chemical speciation were measured. A higher enrichment factor of the metals in the fractions of <1 μm or less were observed in the soil contaminated by wastewater than by smelter dust. The organic substance in the wastewater and calcite from lime application were assumed to play an important role in the metal accumulation in the fine particles of the wastewater polluted soil. While the metal accumulation in the fine particles of the smelter dust polluted soil is mainly associated with Mn oxides. Cadmium speciation in both soils is dominated by dilute acid soluble form and lead speciation in the smelter dust polluted soil is dominated by reducible form in all particles. This implied that the polluted soils might be a high risk to human health and ecosystem due to the high bioaccessblity of the metals as well as the mobility of the fine particles in soil.

  14. Preliminary analysis of levels of arsenic and other metalic elements in PM10 sampled near Copper Smelter Bor (Serbia

    Directory of Open Access Journals (Sweden)

    Renata Kovačević

    2010-09-01

    Full Text Available In this paper, the levels of twenty one elements (Ag, Al, As, B, Ba, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Mo, Na, Ni, Pb, S, Se, Sr and Zn in PM10 are presented, as well as SO2 concentration, measured at the sampling site in an urban area of the town of Bor (40,000 inhabitants in eastern Serbia. The sampling site was located in a densely populated city center about 0.65 km away from one of the largest copper mines and copper smelters in Europe. For the first time PM10 was collected using the European standard sampler, during a preliminary campaign in duration of 7 days in early spring 2009. PM10 were sampled on PTFE membrane filters and element concentrations were quantified by GF AAS and ICP AES. Concentration levels and correlations within trace elements, PM10 and SO2 indicated that industrial activities underpinned with meteorological conditions of low wind speed (calm are the main factors that influence air pollution in a densely populated area. It was evident that both PM10 mass concentration and SO2 concentration once exceeded the daily limit values during a measuring period of seven days. Strong relationship was found between PM10 and Mn, Mg, Ca and B daily average concentrations. On the other hand, SO2 correlated strongly with As, Pb, Cd, Cu and S daily average concentrations. These results confirm the relationship between emissions of SO2 from the Copper Smelter Bor and calm meteorological conditions (wind speed less than 0.5 m/sec with the concentration levels of carcinogenic substances of arsenic, lead and cadmium in ambient air.

  15. Micro-spatial variation of soil metal pollution and plant recruitment near a copper smelter in Central Chile

    International Nuclear Information System (INIS)

    Ginocchio, Rosanna; Carvallo, Gaston; Toro, Ignacia; Bustamante, Elena; Silva, Yasna; Sepulveda, Nancy

    2004-01-01

    Soil chemical changes produced by metal smelters have mainly been studied on a large scale. In terms of plant survival, determination of small scale variability may be more important because less toxic microhabitats may represent safe sites for successful recruitment and thus for plant survival. Three dominant microhabitats (open spaces and areas below the canopy of Sphaeralcea obtusiloba and Baccharis linearis shrubs) were defined in a heavily polluted area near a copper smelter and characterised in terms of microclimate, general soil chemistry, total and extractable metal concentrations in the soil profile (A 0 horizon, 0-5 and 15-20 cm depth), and seedling densities. Results indicated a strong variability in microclimate and soil chemistry not only in the soil profile but also among microhabitats. Air/soil temperatures, radiation and wind speed were much lower under the canopy of shrubs, particularly during the plant growth season. Soil acidification was detected on top layers (0-5 cm depth) of all microhabitats while higher concentrations of N, Cu and Cd were detected on litter and top soil layers below shrubs when compared to open spaces; however, high organic matter content below shrubs decreased bioavailability of metals. Plant recruitment was concentrated under shrub canopies; this may be explained as a result of the nursery effect exerted by shrubs in terms of providing a more favourable microclimate, along with better soil conditions in terms of macronutrients and metal bioavailability. - Metal availability was different under shrub canopies than in open spaces

  16. Sulphur loading of respirable and inhalable dust at a platinum smelter / Swanepoel J.D.

    OpenAIRE

    Swanepoel, Johannes Deon.

    2012-01-01

    The contribution that sulphur, in the form of sulphates, has on ill health is still a focal point of many a study, especially in environmental studies depicting the effects that particulate air pollution has on health. Although the implication of sulphur on particulate matter is not yet well defined, numerous studies do state that the presence of sulphur on particulate matter contributes to poor health. Sulphur adhered to dust has been associated with cardiovascular mortality and the ability ...

  17. Multi-criteria Analysis of Air Pollution with SO(2) and PM(10) in Urban Area Around the Copper Smelter in Bor, Serbia.

    Science.gov (United States)

    Nikolić, Djordje; Milošević, Novica; Mihajlović, Ivan; Zivković, Zivan; Tasić, Viša; Kovačević, Renata; Petrović, Nevenka

    2010-02-01

    This work presents the results of 4 years long monitoring of concentrations of SO(2) gas and PM(10) in the urban area around the copper smelter in Bor. The contents of heavy metals Pb, Cd, Cu, Ni, and As in PM(10) were determined and obtained values were compared to the limit values provided in EU Directives. Manifold excess concentrations of all the components in the atmosphere of the urban area of the townsite Bor were registered. Through application of a multi-criteria analysis by using PROMETHEE/GAIA method, the zones were ranked according to the level of pollution.

  18. Mixing Phenomena in a Bottom Blown Copper Smelter: A Water Model Study

    Science.gov (United States)

    Shui, Lang; Cui, Zhixiang; Ma, Xiaodong; Akbar Rhamdhani, M.; Nguyen, Anh; Zhao, Baojun

    2015-03-01

    The first commercial bottom blown oxygen copper smelting furnace has been installed and operated at Dongying Fangyuan Nonferrous Metals since 2008. Significant advantages have been demonstrated in this technology mainly due to its bottom blown oxygen-enriched gas. In this study, a scaled-down 1:12 model was set up to simulate the flow behavior for understanding the mixing phenomena in the furnace. A single lance was used in the present study for gas blowing to establish a reliable research technique and quantitative characterisation of the mixing behavior. Operating parameters such as horizontal distance from the blowing lance, detector depth, bath height, and gas flow rate were adjusted to investigate the mixing time under different conditions. It was found that when the horizontal distance between the lance and detector is within an effective stirring range, the mixing time decreases slightly with increasing the horizontal distance. Outside this range, the mixing time was found to increase with increasing the horizontal distance and it is more significant on the surface. The mixing time always decreases with increasing gas flow rate and bath height. An empirical relationship of mixing time as functions of gas flow rate and bath height has been established first time for the horizontal bottom blowing furnace.

  19. Selective leaching process for the recovery of copper and zinc oxide from copper-containing dust.

    Science.gov (United States)

    Wu, Jun-Yi; Chang, Fang-Chih; Wang, H Paul; Tsai, Ming-Jer; Ko, Chun-Han; Chen, Chih-Cheng

    2015-01-01

    The purpose of this study was to develop a resource recovery procedure for recovering copper and zinc from dust produced by copper smelting furnaces during the manufacturing of copper-alloy wires. The concentrations of copper in copper-containing dust do not meet the regulation standards defined by the Taiwan Environmental Protection Administration; therefore, such waste is classified as hazardous. In this study, the percentages of zinc and copper in the dust samples were approximately 38.4% and 2.6%, respectively. To reduce environmental damage and recover metal resources for industrial reuse, acid leaching was used to recover metals from these inorganic wastes. In the first stage, 2 N of sulphuric acid was used to leach the dust, with pH values controlled at 2.0-3.0, and a solid-to-liquid ratio of 1:10. The results indicated that zinc extraction efficiency was higher than 95%. A selective acid leaching process was then used to recover the copper content of the residue after filtration. In the second stage, an additional 1 N of sulphuric acid was added to the suspension in the selective leaching process, and the pH value was controlled at 1.5-2.0. The reagent sodium hydroxide (2 N) was used as leachate at a pH greater than 7. A zinc hydroxide compound formed during the process and was recovered after drying. The yields for zinc and copper were 86.9-93.5% and 97.0-98.9%, respectively.

  20. Primary Copper Smelter and Refinery as a Recycling Plant—A System Integrated Approach to Estimate Secondary Raw Material Tolerance

    Directory of Open Access Journals (Sweden)

    Olof Forsén

    2017-10-01

    Full Text Available The primary production of sulfide concentrates includes smelting to copper matte or blister copper, conversion of matte to blister copper, and refining to copper. Smelting, converting, and fire-refining can use a limited amount of secondary materials. Molten copper can effectively dissolve many metals, from valuable noble metals to harmful impurities such as bismuth. However, some of the impurity metals in copper are valuable in other applications. In this paper, we outline the main material flows in copper smelting and electrorefining and describe how minor metals can be recovered from secondary raw materials using copper as a carrier material. We will use a system integrated approach to define the factors that affect the recovery of different metals and copper quality. Metals typical in copper production are used as examples, like noble metals, As, Bi, Se, and Te, including metals in the EU critical raw materials list like PGM and Sb.

  1. Sources of variation in concentrations of nickel and copper in mountain birch foliage near a nickel-copper smelter at Monchegorsk, north-western Russia: results of long-term monitoring

    International Nuclear Information System (INIS)

    Kozlov, Mikhail V.

    2005-01-01

    Concentrations of nickel and copper, two principal metal pollutants of the 'Severonikel' smelter at Monchegorsk, NW Russia, were measured in unwashed leaves of mountain birch, Betula pubescens subsp. czerepanovii, collected in eight study sites along the pollution gradient during 1991-2003. In spite of significant decline in metal emissions, concentrations of foliar metals in most of the study sites did not decrease, indicating that soil contamination remains extremely high. Multiyear mean values peaked at 6.6 km S of the smelter, where they were 20-25 times higher than in the most distant study site. Concentrations of both metals demonstrated pronounced annual variation, which was explained by the meteorological conditions of early summer: higher precipitation in May increased foliar concentrations of both metals, whereas higher precipitation in June resulted in lower foliar concentrations of nickel. These data suggest that ecotoxicological situation in metal-contaminated areas can be modified by the expected climate change. In heavily polluted sites individual birch trees generally retained their ranks in terms of metal contamination during 1995-2003, demonstrating that the use of the same set of trees can significantly increase the accuracy of the monitoring data. - Foliar concentrations of nickel and copper did not reflect emission decline during 1991-2003; annual variation was explained by weather conditions

  2. A Heavy Metal Atmospheric Deposition Study Around the Lead and Copper-Zinc Smelters in Baia Mare, Romania, Employing the Moss Biomonitoring Technique, ENAA and FAAS

    CERN Document Server

    Culicov, O A; Steinnes, E; Okina, O S; Santa, Z; Todoran, R

    2001-01-01

    The mosses Pleurozium schreberi, Pseudoscleropodium purum and Rhytidiadelphus squarrosus were used as biomonitors to study the atmospheric deposition of metals around the lead and copper-zinc smelters in Baia Mare. Samples representing the last three years' growth of moss or its green part, collected on the ground at 28 sites located 2-20 km from the source area, were analyzed by instrumental neutron activation analysis using epithermal neutrons (ENAA) and by flame atomic absorption spectrometry (FAAS). A total of 30 elements were determined, including most of the heavy metals known to be released into the air from this kind of industry. Obtained concentrations for As and Cu are comparable with those observed in Karabash, South Ural Mountains, one of the most polluted regions in Europe. Besides, these two elements correlate very well with each other. The mean values for Zn (136 ppm) and Pb (41 ppm) are substantially higher than those normally found in the literature. The highest value for Pb (175 ppm) was obs...

  3. Possible use of electron beam treatment for removal of SO2 in off-gases from copper smelters. Preliminary tests results

    International Nuclear Information System (INIS)

    Villanueva, L.; Ahumanda, L.; Chmielewski, A.; Zimek, A.; Budka, S.; Licki, J.

    1996-01-01

    The Chilean Nuclear Energy Commission is currently performing a previous feasibility study concerning possible utilization of electron-beam process for removal of SO 2 from different types of sulfurous streams from copper smelters. First part of the project was related to verify, in a experimental line at Institute of Nuclear Chemistry and Technology, INCT, Poland, the behaviour of the process for simulated off-gases with very high SO 2 content, between 5% to 15% by volume. Tests were performed at laboratory stage and with flowrate of 5 Nm 3 /hr, using an ILU-6 electron accelerator, with the following results: High removal efficiencies of SO 2 , up to 90% were achieved for simulated off-gases containing up to 15% of SO 2 ; Required dose was in the range 5 to 8 kGy; Big influence of NH 3 stoichiometry and gas humidity on SO 2 removal efficiency; Rapid generation of sub-micron solid by-product, in great amount, that causes deposits on ducts and filtration units. This work presents the experimental results and discuss is technical projections in the field of interest. (author)

  4. The Impact of a Nickel-Copper Smelter on Concentrations of Toxic Elements in Local Wild Food from the Norwegian, Finnish, and Russian Border Regions.

    Science.gov (United States)

    Hansen, Martine D; Nøst, Therese H; Heimstad, Eldbjørg S; Evenset, Anita; Dudarev, Alexey A; Rautio, Arja; Myllynen, Päivi; Dushkina, Eugenia V; Jagodic, Marta; Christensen, Guttorm N; Anda, Erik E; Brustad, Magritt; Sandanger, Torkjel M

    2017-06-28

    Toxic elements emitted from the Pechenganickel complex on the Kola Peninsula have caused concern about potential effects on local wild food in the border regions between Norway, Finland and Russia. The aim of this study was to assess Ni, Cu, Co, As, Pb, Cd, and Hg concentrations in local wild foods from these border regions. During 2013-2014, we collected samples of different berry, mushroom, fish, and game species from sites at varying distances from the Ni-Cu smelter in all three border regions. Our results indicate that the Ni-Cu smelter is the main source of Ni, Co, and As in local wild foods, whereas the sources of Pb and Cd are more complex. We observed no consistent trends for Cu, one of the main toxic elements emitted by the Ni-Cu smelter; nor did we find any trend for Hg in wild food. Concentrations of all investigated toxic elements were highest in mushrooms, except for Hg, which was highest in fish. EU maximum levels of Pb, Cd, and Hg were exceeded in some samples, but most had levels considered safe for human consumption. No international thresholds exist for the other elements under study.

  5. Size-resolved dust and aerosol contaminants associated with copper and lead smelting emissions: Implications for emission management and human health

    Energy Technology Data Exchange (ETDEWEB)

    Csavina, Janae [Department of Chemical and Environmental Engineering, The University of Arizona, Tucson, AZ 85721 (United States); Taylor, Mark P. [Environmental Science, Faculty of Science, Macquarie University, North Ryde, Sydney, NSW 2109 (Australia); Félix, Omar [Department of Chemical and Environmental Engineering, The University of Arizona, Tucson, AZ 85721 (United States); Rine, Kyle P. [Department of Atmospheric Sciences, The University of Arizona, Tucson, AZ 85721 (United States); Eduardo Sáez, A., E-mail: esaez@email.arizona.edu [Department of Chemical and Environmental Engineering, The University of Arizona, Tucson, AZ 85721 (United States); Betterton, Eric A., E-mail: betterton@atmo.arizona.edu [Department of Atmospheric Sciences, The University of Arizona, Tucson, AZ 85721 (United States)

    2014-09-15

    Mining operations, including crushing, grinding, smelting, refining, and tailings management, are a significant source of airborne metal and metalloid contaminants such as As, Pb and other potentially toxic elements. In this work, we show that size-resolved concentrations of As and Pb generally follow a bimodal distribution with the majority of contaminants in the fine size fraction (< 1 μm) around mining activities that include smelting operations at various sites in Australia and Arizona. This evidence suggests that contaminated fine particles (< 1 μm) are the result of vapor condensation and coagulation from smelting operations while coarse particles are most likely the result of windblown dust from contaminated mine tailings and fugitive emissions from crushing and grinding activities. These results on the size distribution of contaminants around mining operations are reported to demonstrate the ubiquitous nature of this phenomenon so that more effective emission management and practices that minimize health risks associated with metal extraction and processing can be developed. - Highlights: • Lead and copper smelting produce significant atmospheric concentrations of lead and arsenic. • Atmospheric lead and arsenic concentrations depend on particle size. • Lead isotopic analysis can be used to assess source of atmospheric contamination from smelters.

  6. Occurrence of lead, copper, zinc, and arsenic compounds in atmospheric dusts, and the sources of these impurities

    Energy Technology Data Exchange (ETDEWEB)

    Dunn, J T; Bloxam, H C.L.

    1933-06-30

    The authors indicate that the combustion of fossil fuels such as coal for industrial and electrical power causes the deposition of zinc, arsenic, copper, and lead which are then found in the dust and soots of most urban areas. They express the fear that these dusts, if not poisonous, may be expected to be injurious to the health of man, animals, and plants.

  7. Phytoremediation Reduces Dust Emissions from Metal(loid)-Contaminated Mine Tailings.

    Science.gov (United States)

    Gil-Loaiza, Juliana; Field, Jason P; White, Scott A; Csavina, Janae; Felix, Omar; Betterton, Eric A; Sáez, A Eduardo; Maier, Raina M

    2018-04-27

    Environmental and health risk concerns relating to airborne particles from mining operations have focused primarily on smelting activities. However, there are only three active copper smelters and less than a dozen smelters for other metals compared to an estimated 500000 abandoned and unreclaimed hard rock mine tailings in the US that have the potential to generate dust. The problem can also extend to modern tailings impoundments, which may take decades to build and remain barren for the duration before subsequent reclamation. We examined the impact of vegetation cover and irrigation on dust emissions and metal(loid) transport from mine tailings during a phytoremediation field trial at the Iron King Mine and Humboldt Smelter Superfund (IKMHSS) site. Measurements of horizontal dust flux following phytoremediation reveals that vegetated plots with 16% and 32% canopy cover enabled an average dust deposition of 371.7 and 606.1 g m -2 y -1 , respectively, in comparison to the control treatment which emitted dust at an average rate of 2323 g m -2 y -1 . Horizontal dust flux and dust emissions from the vegetated field plots are comparable to emission rates in undisturbed grasslands. Further, phytoremediation was effective at reducing the concentration of fine particulates, including PM 1 , PM 2.5 , and PM 4 , which represent the airborne particulates with the greatest health risks and the greatest potential for long-distance transport. This study demonstrates that phytoremediation can substantially decrease dust emissions as well as the transport of windblown contaminants from mine tailings.

  8. Were mercury emission factors for Chinese non-ferrous metal smelters overestimated? Evidence from onsite measurements in six smelters

    International Nuclear Information System (INIS)

    Zhang Lei; Wang Shuxiao; Wu Qingru; Meng Yang; Yang Hai; Wang Fengyang; Hao Jiming

    2012-01-01

    Non-ferrous metal smelting takes up a large proportion of the anthropogenic mercury emission inventory in China. Zinc, lead and copper smelting are three leading sources. Onsite measurements of mercury emissions were conducted for six smelters. The mercury emission factors were 0.09–2.98 g Hg/t metal produced. Acid plants with the double-conversion double-absorption process had mercury removal efficiency of over 99%. In the flue gas after acid plants, 45–88% was oxidized mercury which can be easily scavenged in the flue gas scrubber. 70–97% of the mercury was removed from the flue gas to the waste water and 1–17% to the sulfuric acid product. Totally 0.3–13.5% of the mercury in the metal concentrate was emitted to the atmosphere. Therefore, acid plants in non-ferrous metal smelters have significant co-benefit on mercury removal, and the mercury emission factors from Chinese non-ferrous metal smelters were probably overestimated in previous studies. - Highlights: ► Acid plants in smelters provide significant co-benefits for mercury removal (over 99%). ► Most of the mercury in metal concentrates for smelting ended up in waste water. ► Previously published emission factors for Chinese metal smelters were probably overestimated. - Acid plants in smelters have high mercury removal efficiency, and thus mercury emission factors for Chinese non-ferrous metal smelters were probably overestimated.

  9. Health and Safety Laboratory environmental quarterly, March 1, 1977--June 1, 1977. [Air pollution in environs of Cu smelter and fallout radionuclides in food chains

    Energy Technology Data Exchange (ETDEWEB)

    Hardy, E.P. Jr.

    1977-07-01

    This report presents current information from the HASL environmental programs, The Technical University of Wroclaw, Poland, and the Radiological and Environmental Research Division of Argonne National Laboratory. The initial section consists of interpretive reports and notes on environmental levels of lead and mercury in the area of a copper smelter, radionuclide uptake by cultivated dusts in crops, and fallout strontium-90 in diet through 1976. Subsequent sections include tabulations of radionuclide concentrations in stratospheric air, radionuclide and stable lead concentrations in surface air, strontium-90 in deposition, milk, diet, and tapwater and cesium-137 in diet and tapwater. A bibliography of recent publications related to environmental studies is also presented.

  10. Exposure to Fluoride in Smelter Workers in a Primary Aluminum Industry in India

    Directory of Open Access Journals (Sweden)

    AK Susheela

    2013-04-01

    Full Text Available Background: Fluoride is used increasingly in a variety of industries in India. Emission of fluoride dust and fumes from the smelters of primary aluminum producing industries is dissipated in the work environment and poses occupational health hazards. Objective: To study the prevalence of health complaints and its association with fluoride level in body fluids of smelter workers in a primary aluminum producing industry. Methods: In an aluminum industry, health status of 462 smelter workers, 60 supervisors working in the smelter unit, 62 non-smelter workers (control group 1 and 30 administration staff (control group 2 were assessed between 2007 and 2009. Their health complaints were recorded and categorized into 4 groups: 1 gastro-intestinal complaints; 2 non-skeletal manifestations; 3 skeletal symptoms; and (4 respiratory problems. Fluoride level in body fluids, nails, and drinking water was tested by an ion selective electrode; hemoglobin level was tested using HemoCue. Results: The total complaints reported by study groups were significantly higher than the control groups. Smelter workers had a significantly (p<0.001 higher urinary and serum fluoride level than non-smelter workers; the nail fluoride content was also higher in smelter workers than non-smelter workers (p<0.001. The smelter workers with higher hemoglobin level had a significantly (p<0.001 lower urinary fluoride concentration and complained less frequently of health problems. Only 1.4% of the smelter workers were consuming water with high fluoride concentrations. A high percentage of participants was using substances with high fluoride contents. Conclusions: Industrial emission of fluoride is not the only important sources of fluoride exposure—consumption of substance with high levels of fluoride is another important route of entry of fluoride into the body. Measurement of hemoglobin provides a reliable indicator for monitoring the health status of employees at risk of fluorosis.

  11. The impact of industrial emissions of copper-nickel smelter complex on the status of populations and communities of small mammals in the Kola Peninsula

    Directory of Open Access Journals (Sweden)

    Gennadiy D. Kataev

    2017-08-01

    Full Text Available The population status of the small mammals, Micromammalia, was studied in the central mountain and taiga part of the Kola Peninsula in the Lapland Biosphere Reserve and its buffer zone. For this purpose, control groups of animals were selected at a different distance from the Severonikel' industrial complex which is considered as the largest metallurgical company in Europe. It produces nickel, copper and other non-ferrous metals. The study sites were located at 4–30 km from the local source of industrial pollution. The analysis of population dynamics, faunistic structure and biological parameters of mass species of Soricidae, Myomorpha has revealed the differences in habitats depending on the distance to the industrial complex. The results of the chemical analysis of organs and tissue samples of small rodents, their morpho-physiological and genetic characteristics within emission plume were analysed. The abundance of the studied Mammalia species was the lowest at 5 km north and 7 km south of the metallurgical industrial complex. According to our results, animals in a zone of increased industrial emission (sulfur dioxide, compounds of heavy metals concentrations had more deviations from the biological norms in comparison with the same species from less polluted areas. Long-term (1936–2014 abundance dynamics of Clethrionomys glareolus was presented due to the new ecological situation in the region and reduction of the volume of sulfur dioxide emission by the Severonikel' industrial complex. This biotesting method using mammals as study objects may be applied for the definition of ecologically safe level criteria of heavy metal production and it may be used in studies of similar ecological situations.

  12. Speciation of Cr(VI) in environmental samples in the vicinity of the ferrochrome smelter

    Energy Technology Data Exchange (ETDEWEB)

    Sedumedi, Hilda N. [Department of Chemistry, Tshwane University of Technology, P.O. Box 56208, Arcadia, 0007, Pretoria (South Africa); Mandiwana, Khakhathi L., E-mail: MandiwanaKL@tut.ac.za [Department of Chemistry, Tshwane University of Technology, P.O. Box 56208, Arcadia, 0007, Pretoria (South Africa); Ngobeni, Prince; Panichev, Nikolay [Department of Chemistry, Tshwane University of Technology, P.O. Box 56208, Arcadia, 0007, Pretoria (South Africa)

    2009-12-30

    The impact of ferrochrome smelter on the contamination of its environment with toxic hexavalent chromium, Cr(VI), was assessed by analyzing smelter dusts, soil, grass and tree barks. For the separation of Cr(VI) from Cr(III), solid samples were treated with 0.1 M Na{sub 2}CO{sub 3} and filtered through hydrophilic PDVF 0.45 {mu}m filter prior to the determination of Cr(VI) by electrothermal atomic absorption spectrometry (ET-AAS). Ferrochrome smelter dust was found to contain significant levels of Cr(VI), viz. 43.5 {mu}g g{sup -1} (cyclone dust), 2710 {mu}g g{sup -1} (fine dust), and 7800 {mu}g g{sup -1} (slimes dust) which exceeded the maximum acceptable risk concentration (20 {mu}g g{sup -1}). The concentration of Cr(VI) in environmental samples of grass (3.4 {+-} 0.2), soil (7.7 {+-} 0.2), and tree bark (11.8 {+-} 1.2) collected in the vicinity of the chrome smelter were higher as compared with the same kind of samples collected from uncontaminated area. The results of the investigation show that ferrochrome smelter is a source of environmental pollution with contamination factors of Cr(VI) ranging between 10 and 50.

  13. Speciation of Cr(VI) in environmental samples in the vicinity of the ferrochrome smelter.

    Science.gov (United States)

    Sedumedi, Hilda N; Mandiwana, Khakhathi L; Ngobeni, Prince; Panichev, Nikolay

    2009-12-30

    The impact of ferrochrome smelter on the contamination of its environment with toxic hexavalent chromium, Cr(VI), was assessed by analyzing smelter dusts, soil, grass and tree barks. For the separation of Cr(VI) from Cr(III), solid samples were treated with 0.1M Na(2)CO(3) and filtered through hydrophilic PDVF 0.45 microm filter prior to the determination of Cr(VI) by electrothermal atomic absorption spectrometry (ET-AAS). Ferrochrome smelter dust was found to contain significant levels of Cr(VI), viz. 43.5 microg g(-1) (cyclone dust), 2710 microg g(-1) (fine dust), and 7800 microg g(-1) (slimes dust) which exceeded the maximum acceptable risk concentration (20 microg g(-1)). The concentration of Cr(VI) in environmental samples of grass (3.4+/-0.2), soil (7.7+/-0.2), and tree bark (11.8+/-1.2) collected in the vicinity of the chrome smelter were higher as compared with the same kind of samples collected from uncontaminated area. The results of the investigation show that ferrochrome smelter is a source of environmental pollution with contamination factors of Cr(VI) ranging between 10 and 50.

  14. Speciation of Cr(VI) in environmental samples in the vicinity of the ferrochrome smelter

    International Nuclear Information System (INIS)

    Sedumedi, Hilda N.; Mandiwana, Khakhathi L.; Ngobeni, Prince; Panichev, Nikolay

    2009-01-01

    The impact of ferrochrome smelter on the contamination of its environment with toxic hexavalent chromium, Cr(VI), was assessed by analyzing smelter dusts, soil, grass and tree barks. For the separation of Cr(VI) from Cr(III), solid samples were treated with 0.1 M Na 2 CO 3 and filtered through hydrophilic PDVF 0.45 μm filter prior to the determination of Cr(VI) by electrothermal atomic absorption spectrometry (ET-AAS). Ferrochrome smelter dust was found to contain significant levels of Cr(VI), viz. 43.5 μg g -1 (cyclone dust), 2710 μg g -1 (fine dust), and 7800 μg g -1 (slimes dust) which exceeded the maximum acceptable risk concentration (20 μg g -1 ). The concentration of Cr(VI) in environmental samples of grass (3.4 ± 0.2), soil (7.7 ± 0.2), and tree bark (11.8 ± 1.2) collected in the vicinity of the chrome smelter were higher as compared with the same kind of samples collected from uncontaminated area. The results of the investigation show that ferrochrome smelter is a source of environmental pollution with contamination factors of Cr(VI) ranging between 10 and 50.

  15. The Effect of Deposit Temperature on the Catalytic SO2-to-SO3 Conversion in a Copper Flash Smelting Heat Recovery Boiler

    Science.gov (United States)

    Lehmusto, Juho; Vainio, Emil; Laurén, Tor; Lindgren, Mari

    2018-02-01

    The aim of the work was to study the catalytic role of copper flash smelter deposit in the SO2-to-SO3 conversion. In addition, the effect of process gas temperature at 548 K to 1173 K (275 °C to 900 °C) on the amount of SO3 formed was addressed both in the absence and presence of genuine copper flash smelter deposit. The SO3 conversion rate changed as a function of process gas temperature, peaking at 1023 K (750 °C). A dramatic increase in the SO2-to-SO3 conversion was observed when process dust was present, clearly indicating that process dust catalyzes the SO2-to-SO3 conversion. Based on these results, the catalytic ability of the deposit may lead to sulfuric acid dew point corrosion.

  16. Influence of Matrix Composition on the Bioaccessibility of Copper, Zinc and Nickel in Urban Residential Dust and Soil

    International Nuclear Information System (INIS)

    Rasmussen, P.; Beauchemin, S.; Nugent, M.; Dugandzic, R.; Lanouette, M.; Chenier, M.

    2008-01-01

    This study examines factors affecting oral bioaccessibility of metals in household dust, in particular metal speciation, organic carbon content, and particle size, with the goal of addressing risk assessment information requirements. Investigation of copper (Cu) and zinc (Zn) speciation in two size fractions of dust (< 36 μ m and 80-150 μ m) using synchrotron X-ray absorption spectroscopy (XAS) indicates that the two metals are bound to different components of the dust: Cu is predominately associated with the organic phase of the dust, while Zn is predominately associated with the mineral fraction. Total and bioaccessible Cu, nickel (Ni), and Zn were determined (on dry weight basis) in the < 150 μ m size fraction of a set of archived indoor dust samples (n = 63) and corresponding garden soil samples (n = 66) from the City of Ottawa, Canada. The median bioaccessible Cu content is 66 μ g g-1 in dust compared to 5 μ g g-1 in soil; the median bioaccessible Ni content is 16 μ g g-1 in dust compared to 2 μ g g-1 in soil; and the median bioaccessible Zn content is 410 μ g g-1 in dust compared to 18 μ g g-1 in soil. For the same data set, the median total Cu content is 152 μ g g-1 in dust compared to 17 μ g g-1 in soil; the median total Ni content is 41 μ g g-1 in dust compared to 13 μ g g-1 in soil; and the median total Zn content is 626 μ g g-1 in dust compared to 84 μ g g-1 in soil. Organic carbon is elevated in indoor dust (median 28%) compared to soil (median 5%), and is a key factor controlling metal partitioning and therefore bioaccessibility. The results show that house dust and soil have distinct geochemical signatures and should not be treated as identical media in exposure and risk assessments. Separate measurements of the indoor and outdoor environment are essential to improve the accuracy of residential risk assessments.

  17. Identification of historical lead sources in roof dust and recent lake sediments from an industrialized are: Indications from lead isotopes

    International Nuclear Information System (INIS)

    Chenhall, B.E.; Depers, A.M.; Jones, B.G.; Chiaradia, M.

    1997-01-01

    X-ray fluorescence and stable lead (Pb) isotopic analyses have been undertaken on dusts, known from microscopic investigation to contain significant quantities of industrially- and urban-derived particulate matter, present in the roof cavities of houses in the Illawarra region (N.S.W., Australia), with the objective of examining the historic record of Pb pollution. All investigated houses contained in excess of 250 μg g -1 Pb, with dwellings close to a copper smelter, in a large industrial complex including a major steelworks, containing higher (>2500 μg g -1 ) Pb concentrations. The isotopic composition in the dusts, expressed here as 206 Pb/ 204 Pb, is relatively constant at 17.0, irrespective of dwelling age or distance from the industrial complex. Contamination of the dusts by Pb sourced from paint cannot explain the isotopic uniformity of the dust samples. Isotopic modelling indicates that the dusts contain Pb derived from the copper smelter, gasoline-air Pb and a minor contribution from the steelworks. Isotopic calculations, together with records of particulate pollution emission, indicate a link between the Pb in roof dusts and Pb contamination of the near surface lagoonal sediments. Over the last five decades, atmospheric fallout of Pb-bearing particulate matter appears to have been the dominant pathway for addition of Pb to the lagoon and dwellings in the Illawarra region

  18. Arsenic pollution in the Yellowknife area from gold smelter activities

    International Nuclear Information System (INIS)

    Hutchinson, T.C.; Aufreiter, S.; Hancock, R.G.V.

    1982-01-01

    Gold mined at Yelloknife in the North West Territories of Canada is associated with arsenopyrite ores which necessitates the oxidation of the arsenic and sulphur by roasting at two Yellowknife smelters. As 2 O 3 and SO 2 are emitted into the atmosphere, and despite improvements in emission control, significant emissions still occur. In order to asses the arsenic contamination in the local environment and the potential exposures to man, soil samples and samples of the native vegetation were collected in and around Yellowknife and the two smelters. Arsenic and antimony analyses were done by instrumental neutron activation analysis using the SLOWPOKE facility at University of Toronto. Zinc, copper, lead and cadmium analyses were done by atomic adsorption spectrophotometry. Arsenic was found to be accumulated in the soils in the vicinity of the two smelters to levels of several thousand ppm. Antimony levels were about 10% of arsenic and were highly correlated with arsenic. Zinc occured to 500 ppm around the smelters. Soil arsenic levels are sufficiently high to inhibit root growth in soils over a very extensive area. (author)

  19. Feasibility study of a portable smelter for scrap metals

    International Nuclear Information System (INIS)

    Cavendish, J.H.

    1976-06-01

    The use of a portable smelter to process uranium-contaminated scrap metals was studied. Objectives were to convert scrap metal located at many diverse sites into a form which would be suitable for unlicensed sale and reduce the problems associated with storing the scrap. The Foundry Design Company study indicated the portable smelter concept was feasible from an equipment and transportation standpoint. Capital costs for a 5-ton/hour (steel) nominal capacity unit were estimated to be $2,349,000. Technical evaluation indicates that all the common metals considered, i.e., iron, nickel, copper, and aluminum, are amenable to uranium decontamination by smelting except aluminum. An economic evaluation of the processing of the 30,000 tons of steel scrap to be generated by the Cascade Improvement Program by a portable smelter was made based upon information supplied by Foundry Design Company, plus the assumption that the product metal could be sold for $120.00 per ton. This evaluation indicated a net return of $2,424,000 to the government could be realized. The Health and Safety study indicated no major problems of this nature would be encountered in operating a portable smelter. The legal review indicated the proposed operation fell within the authority of existing regulations. Consideration of possible conflicts with regard to competition with the private sector was suggested

  20. Composition and fate of mine- and smelter-derived particles in soils of humid subtropical and hot semi-arid areas

    Energy Technology Data Exchange (ETDEWEB)

    Ettler, Vojtěch, E-mail: ettler@natur.cuni.cz [Institute of Geochemistry, Mineralogy and Mineral Resources, Faculty of Science, Charles University in Prague, Albertov 6, 128 43 Praha 2 (Czech Republic); Johan, Zdenek [BRGM, Avenue Claude Guillemin, 45082 Orléans Cedex 2 (France); Kříbek, Bohdan; Veselovský, František [Czech Geological Survey, Geologická 6, 152 00 Praha 5 (Czech Republic); Mihaljevič, Martin [Institute of Geochemistry, Mineralogy and Mineral Resources, Faculty of Science, Charles University in Prague, Albertov 6, 128 43 Praha 2 (Czech Republic); Vaněk, Aleš; Penížek, Vít [Department of Soil Science and Soil Protection, Faculty of Agrobiology, Food and Natural Resources, Czech University of Life Sciences Prague, Kamýcká 129, 165 21 Praha 6 (Czech Republic); Majer, Vladimír [Czech Geological Survey, Geologická 6, 152 00 Praha 5 (Czech Republic); Sracek, Ondra [Department of Geology, Faculty of Science, Palacký University in Olomouc, 17. listopadu 12, 771 46 Olomouc (Czech Republic); Mapani, Ben; Kamona, Fred [Department of Geology, Faculty of Science, University of Namibia, Private Bag 13301, Windhoek (Namibia); Nyambe, Imasiku [University of Zambia, School of Mines, P. O. Box 32 379, Lusaka (Zambia)

    2016-09-01

    We studied the heavy mineral fraction, separated from mining- and smelter-affected topsoils, from both a humid subtropical area (Mufulira, Zambian Copperbelt) and a hot semi-arid area (Tsumeb, Namibia). High concentrations of metal(loid)s were detected in the studied soils: up to 1450 mg As kg{sup −1}, 8980 mg Cu kg{sup −1}, 4640 mg Pb kg{sup −1}, 2620 mg Zn kg{sup −1}. A combination of X-ray diffraction analysis (XRD), scanning electron microscopy (SEM/EDS), and electron probe microanalysis (EPMA) helped to identify the phases forming individual metal(loid)-bearing particles. Whereas spherical particles originate from the smelting and flue gas cleaning processes, angular particles have either geogenic origins or they are windblown from the mining operations and mine waste disposal sites. Sulphides from ores and mine tailings often exhibit weathering rims in contrast to smelter-derived high-temperature sulphides (chalcocite [Cu{sub 2}S], digenite [Cu{sub 9}S{sub 5}], covellite [CuS], non-stoichiometric quenched Cu–Fe–S phases). Soils from humid subtropical areas exhibit higher available concentrations of metal(loids), and higher frequencies of weathering features (especially for copper-bearing oxides such as delafossite [Cu{sup 1+} Fe{sup 3+} O{sub 2}]) are observed. In contrast, metal(loid)s are efficiently retained in semi-arid soils, where a high proportion of non-weathered smelter slag particles and low-solubility Ca–Cu–Pb arsenates occur. Our results indicate that compared to semi-arid areas (where inorganic contaminants were rather immobile in soils despite their high concentrations) a higher potential risk exists for agriculture in mine- and smelter-affected humid subtropical areas (where metal(loid) contaminants can be highly available for the uptake by crops). - Highlights: • Mining- and smelter-derived particles identified in subtropical and semi-arid soils • Sulphides, oxides, and metal-bearing arsenates most frequently encountered

  1. A CFD study on the dust behaviour in a metallurgical waste-heat boiler

    Energy Technology Data Exchange (ETDEWEB)

    Yongxiang, Yang; Jokilaakso, A [Helsinki Univ. of Technology, Otaniemi (Finland). Lab. of Materials Processing and Powder Metallurgy

    1998-12-31

    A waste-heat boiler forms an essential part for the treatment of high temperature flue-gases in most metallurgical processes. Flue-dust carried by the furnace off-gas has to be captured efficiently in the waste-heat boilers before entering the downstream gas purification equipment. Flue dust may accumulate and foul on the heat transfer surfaces such as tube-walls, narrow conjunctions between the boiler and the furnace uptake, and thus may cause smelter shutdown, and interrupt the production. A commercial CFD package is used as the major tool on modelling the dust flow and settling in the waste-heat boiler of an industrial copper flash smelter. In the presentation, dust settling behaviour is illustrated for a wide range of particle sizes, and dust capture efficiency in the radiation section of the boiler for different particle sizes has been shown with the transient simulation. The simulation aims at providing detailed information of dust behaviour in the waste-heat boiler in sulphide smelting. (author) 11 refs.

  2. A CFD study on the dust behaviour in a metallurgical waste-heat boiler

    Energy Technology Data Exchange (ETDEWEB)

    Yang Yongxiang; Jokilaakso, A. [Helsinki Univ. of Technology, Otaniemi (Finland). Lab. of Materials Processing and Powder Metallurgy

    1997-12-31

    A waste-heat boiler forms an essential part for the treatment of high temperature flue-gases in most metallurgical processes. Flue-dust carried by the furnace off-gas has to be captured efficiently in the waste-heat boilers before entering the downstream gas purification equipment. Flue dust may accumulate and foul on the heat transfer surfaces such as tube-walls, narrow conjunctions between the boiler and the furnace uptake, and thus may cause smelter shutdown, and interrupt the production. A commercial CFD package is used as the major tool on modelling the dust flow and settling in the waste-heat boiler of an industrial copper flash smelter. In the presentation, dust settling behaviour is illustrated for a wide range of particle sizes, and dust capture efficiency in the radiation section of the boiler for different particle sizes has been shown with the transient simulation. The simulation aims at providing detailed information of dust behaviour in the waste-heat boiler in sulphide smelting. (author) 11 refs.

  3. Exposure to fluoride in smelter workers in a primary aluminum industry in India.

    Science.gov (United States)

    Susheela, A K; Mondal, N K; Singh, A

    2013-04-01

    Fluoride is used increasingly in a variety of industries in India. Emission of fluoride dust and fumes from the smelters of primary aluminum producing industries is dissipated in the work environment and poses occupational health hazards. To study the prevalence of health complaints and its association with fluoride level in body fluids of smelter workers in a primary aluminum producing industry. In an aluminum industry, health status of 462 smelter workers, 60 supervisors working in the smelter unit, 62 non-smelter workers (control group 1) and 30 administration staff (control group 2) were assessed between 2007 and 2009. Their health complaints were recorded and categorized into 4 groups: 1) gastro-intestinal complaints; 2) non-skeletal manifestations; 3) skeletal symptoms; and (4) respiratory problems. Fluoride level in body fluids, nails, and drinking water was tested by an ion selective electrode; hemoglobin level was tested using HemoCue. The total complaints reported by study groups were significantly higher than the control groups. Smelter workers had a significantly (pworkers; the nail fluoride content was also higher in smelter workers than non-smelter workers (pworkers with higher hemoglobin level had a significantly (pworkers were consuming water with high fluoride concentrations. A high percentage of participants was using substances with high fluoride contents. Industrial emission of fluoride is not the only important sources of fluoride exposure--consumption of substance with high levels of fluoride is another important route of entry of fluoride into the body. Measurement of hemoglobin provides a reliable indicator for monitoring the health status of employees at risk of fluorosis.

  4. Potential for improved extraction of tellurium as a byproduct of current copper mining processes

    Science.gov (United States)

    Hayes, S. M.; Spaleta, K. J.; Skidmore, A. E.

    2016-12-01

    Tellurium (Te) is classified as a critical element due to its increasing use in high technology applications, low average crustal abundance (3 μg kg-1), and primary source as a byproduct of copper extraction. Although Te can be readily recovered from copper processing, previous studies have estimated a 4 percent extraction efficiency, and few studies have addressed Te behavior during the entire copper extraction process. The goals of the present study are to perform a mass balance examining Te behavior during copper extraction and to connect these observations with mineralogy of Te-bearing phases which are essential first steps in devising ways to optimize Te recovery. Our preliminary mass balance results indicate that less than 3 percent of Te present in copper ore is recovered, with particularly high losses during initial concentration of copper ore minerals by flotation. Tellurium is present in the ore in telluride minerals (e.g., Bi-Te-S phases, altaite, and Ag-S-Se-Te phases identified using electron microprobe) with limited substitution into sulfide minerals (possibly 10 mg kg-1 Te in bulk pyrite and chalcopyrite). This work has also identified Te accumulation in solid-phase intermediate extraction products that could be further processed to recover Te, including smelter dusts (158 mg kg-1) and pressed anode slimes (2.7 percent by mass). In both the smelter dusts and anode slimes, X-ray absorption spectroscopy indicates that about two thirds of the Te is present as reduced tellurides. In anode slimes, electron microscopy shows that the remaining Te is present in an oxidized form in a complex Te-bearing oxidate phase also containing Pb, Cu, Ag, As, Sb, and S. These results clearly indicate that more efficient, increased recovery of Te may be possible, likely at minimal expense from operating copper processing operations, thereby providing more Te for manufacturing of products such as inexpensive high-efficiency solar panels.

  5. Canadian House Dust Study: Population-based concentrations, loads and loading rates of arsenic, cadmium, chromium, copper, nickel, lead, and zinc inside urban homes

    Energy Technology Data Exchange (ETDEWEB)

    Rasmussen, Pat E. [Exposure and Biomonitoring Division, Healthy Environments and Consumer Safety Branch, Health Canada, 50 Colombine Driveway, Ottawa, ON, Canada K1A 0K9 (Canada); Department of Earth Sciences, University of Ottawa, 140 Louis Pasteur, Ottawa, ON, Canada K1N 6N5 (Canada); Levesque, Christine [Exposure and Biomonitoring Division, Healthy Environments and Consumer Safety Branch, Health Canada, 50 Colombine Driveway, Ottawa, ON, Canada K1A 0K9 (Canada); Chénier, Marc; Gardner, H. David [Exposure and Biomonitoring Division, Healthy Environments and Consumer Safety Branch, Health Canada, 50 Colombine Driveway, Ottawa, ON, Canada K1A 0K9 (Canada); Department of Earth Sciences, University of Ottawa, 140 Louis Pasteur, Ottawa, ON, Canada K1N 6N5 (Canada); Jones-Otazo, Heather [Regions and Programs Branch, Health Canada, 180 Queen Street West, Toronto, ON, Canada M5V 3L7 (Canada); Petrovic, Sanya [Contaminated Sites Division, Healthy Environments and Consumer Safety Branch, Health Canada, 269 Laurier Ave West, Ottawa, ON, Canada K1A 0K9 (Canada)

    2013-01-15

    The Canadian House Dust Study was designed to obtain nationally representative urban house dust metal concentrations (μg g{sup −1}) and metal loadings (μg m{sup −2}) for arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), nickel (Ni), lead (Pb), and zinc (Zn). Consistent sampling of active dust of known age and provenance (area sampled) also permitted the calculation of indoor loading rates (mg m{sup −2} day{sup −1} for dust and μg m{sup −2} day{sup −1} for metals) for the winter season (from 2007 to 2010) when houses are most tightly sealed. Geomean/median indoor dust loading rates in homes located more than 2 km away from industry of any kind (9.6/9.1 mg m{sup −2} day{sup −1}; n = 580) were significantly lower (p < .001) than geomean (median) dust loading rates in homes located within 2 km of industry (13.5/13.4 mg m{sup −2} day{sup −1}; n = 421). Proximity to industry was characterized by higher indoor metal loading rates (p < .003), but no difference in dust metal concentrations (.29 ≥ p ≤ .97). Comparisons of non-smokers' and smokers' homes in non-industrial zones showed higher metal loading rates (.005 ≥ p ≤ .038) in smokers' homes, but no difference in dust metal concentrations (.15 ≥ p ≤ .97). Relationships between house age and dust metal concentrations were significant for Pb, Cd and Zn (p < .001) but not for the other four metals (.14 ≥ p ≤ .87). All seven metals, however, displayed a significant increase in metal loading rates with house age (p < .001) due to the influence of higher dust loading rates in older homes (p < .001). Relationships between three measures of metals in house dust – concentration, load, and loading rate – in the context of house age, smoking behavior and urban setting consistently show that concentration data is a useful indicator of the presence of metal sources in the home, whereas dust mass is the overriding influence on metal loadings and loading rates

  6. Smelters as Analogs for a Volcanic Eruption at Yucca Mountain

    International Nuclear Information System (INIS)

    Ross, Benjamin

    2004-01-01

    The distribution of trace radionuclides in secondary metal smelters provides an analog for spent fuel released from packages during a volcanic eruption. The fraction of the inventory of a radionuclide that would be released into the air in a volcanic eruption is called the dust partitioning factor. In consequence analyses of a volcanic eruption at Yucca Mountain, a value of one has been used for this parameter for all elements. This value is too high for the refractory elements. Reducing the dust partitioning factor for refractory elements to a value equal to the fraction of the magma that becomes ash would still yield conservative estimates of how much radioactivity would be released in an eruption

  7. Copper Powder and Chemicals: edited proceedings of a seminar

    Energy Technology Data Exchange (ETDEWEB)

    1980-12-01

    Various papers are presented covering the following topics: Status of Copper Chemical Industry in India, Copper Powder from Industrial Wastes, Manufacture of Copper Hydroxide and High Grade Cement Copper from Low Grade Copper Ore, Manufacture of Copper Sulphate as a By-Product, Hydrometallurgical Treatments of Copper Converter and Smelter Slage for Recovering Copper and other Non-Ferrous Metals, Recovery of Copper from Dilute Solutions, Use of Copper Compounds as Fungicides in India, Copper in Animal Husbandry, and Use of Copper Powder and Chemicals for Marine Applications. The keynote paper given at the Seminar was on Conservation of Copper for Better Use.

  8. Accumulation of heavy metals (cadmium, zinc, and copper) from smelter in forest ecosystems and their uptakes by Shiitake mushroom (Lentinus edodes (Berk) Sing. ) and Nameko mushroom (Pholiota glutinosa Kawamura) through polluted bed logs

    Energy Technology Data Exchange (ETDEWEB)

    Nishimoto, T.; Fujita, K.; Furukawa, H.; Yoshimoto, M.

    1977-12-01

    Mushrooms cultivated on sawdust medium which had been innoculated with heavy metals accumulated the metals increasingly in stems, pileus, gill and spores, in that order. There were strain differences, in accumulation, and highest concentration was found in the first-born fruit body. At 2 ppm, cadmium did not affect yield of the fruiting body. At 20 ppm, however, yield was seriously reduced. Species differences in absorption capacity for heavy metals were noted. Seasonal variations in cadmium and copper accumulation were noted, along with zinc. Cadmium concentration in fruiting bodies increased with increase of cadmium concentration in the growth substrate. 23 figures, 16 tables.

  9. Detection and removal of fluorine in the waste gases of a steel smelter and measuring air quality in its surroundings

    Energy Technology Data Exchange (ETDEWEB)

    Graue, G; Nagel, H

    1968-01-01

    Plant damage in the Duisburg area was attributed to the action of fluoride supposedly originating in industrial waste gases, particularly of steel smelters. Air quality measurements were taken near a large steel smelter for a period of three years. After eliminating errors the total concentration of fluoride in the course of 3 years was established as between 2 and 6 mg/m/sup 2/ per day. Clearly, no free fluorine is emitted by steel smelters, although gaseous fluoride compounds can occur. Downstream from metallurgical furnaces, particularly where brown smoke is emitted, this fluoride is almost completely adsorbed by the dust. Ores and other raw materials in steel smelters are liable to contain fluorides, usually in the form of fluorite. Only a small proportion of this is liberated on the sintering band. However, since the sintering waste gases are acid, less fluoride is adsorbed by dust at this point and separated during dust collection. The use of desulfurization units downstream of the sintering bands could solve this problem. If, for the time being, nothing is done in this direction, it is because the fluoride contents of these gases do not play a significant role, due to the height of the stacks in use. This is supported by the results of extensive air purity measurements in the Duisburg region, in which fluoride levels between 1 and 3 ..mu..g were found per m/sup 3/ STP of air.

  10. Patterns of insect communities along a stress gradient following decommissioning of a Cu-Ni smelter

    International Nuclear Information System (INIS)

    Babin-Fenske, Jennifer; Anand, Madhur

    2011-01-01

    The diversity, estimated richness and abundance of terrestrial insect communities were examined along a stress gradient of past pollution in the region of Sudbury, Ontario, Canada. This gradient represents the natural recovery and lingering effects of a decommissioned copper-nickel smelting complex. Ant genera and sixteen higher taxonomic groups (family and order) had the highest abundance at the sites with intermediate stress. Eight families increased in abundance with distance from the decommissioned source of pollution and eleven families decreased reflecting a complex response of diversity to pollution. Carabid beetles show an increase in diversity further from the smelter; however, examination of the species composition reveals a distinct carabid community closest to the smelter, emphasizing the unique habitat created by severe pollution. Although almost forty years since decomissioning of the smelter complex, the terrestrial insect community in the vicinity remains significantly impacted suggesting slow recovery. - Highlights: → Several taxonomic groups had highest abundance at intermediate stress. → Eight families increased in abundance with distance from the source of pollution. → Eleven families decreased in abundance with distance. → Species composition reveals a distinct carabid community closest to the smelter. → Terrestrial insect community still significantly impacted suggesting slow recovery. - Our study finds both unexpected and expected responses of insect communities to a landscape gradient of past pollution suggesting the emergence of novel ecosystems.

  11. Patterns of insect communities along a stress gradient following decommissioning of a Cu-Ni smelter

    Energy Technology Data Exchange (ETDEWEB)

    Babin-Fenske, Jennifer [Department of Biology, Laurentian University, Sudbury, Ontario, P3E 2C6 (Canada); Anand, Madhur, E-mail: manand@uoguelph.ca [School of Environmental Sciences, University of Guelph, Guelph, Ontario, N1G 2W1 (Canada)

    2011-10-15

    The diversity, estimated richness and abundance of terrestrial insect communities were examined along a stress gradient of past pollution in the region of Sudbury, Ontario, Canada. This gradient represents the natural recovery and lingering effects of a decommissioned copper-nickel smelting complex. Ant genera and sixteen higher taxonomic groups (family and order) had the highest abundance at the sites with intermediate stress. Eight families increased in abundance with distance from the decommissioned source of pollution and eleven families decreased reflecting a complex response of diversity to pollution. Carabid beetles show an increase in diversity further from the smelter; however, examination of the species composition reveals a distinct carabid community closest to the smelter, emphasizing the unique habitat created by severe pollution. Although almost forty years since decomissioning of the smelter complex, the terrestrial insect community in the vicinity remains significantly impacted suggesting slow recovery. - Highlights: > Several taxonomic groups had highest abundance at intermediate stress. > Eight families increased in abundance with distance from the source of pollution. > Eleven families decreased in abundance with distance. > Species composition reveals a distinct carabid community closest to the smelter. > Terrestrial insect community still significantly impacted suggesting slow recovery. - Our study finds both unexpected and expected responses of insect communities to a landscape gradient of past pollution suggesting the emergence of novel ecosystems.

  12. Distribution of chemical elements in attic dust as reflection of their geogenic and anthropogenic sources in the vicinity of the copper mine and flotation plant.

    Science.gov (United States)

    Balabanova, Biljana; Stafilov, Trajče; Sajn, Robert; Bačeva, Katerina

    2011-08-01

    The main aim of this article was to assess the atmospheric pollution with heavy metals due to copper mining Bučim near Radoviš, the Republic of Macedonia. The open pit and mine waste and flotation tailings are continually exposed to open air, which leads to winds carrying the fine particles into the atmosphere. Samples of attic dust were examined as historical archives of mine emissions, with the aim of elucidating the pathways of pollution. Dust was collected from the attics of 29 houses, built between 1920 and 1970. Nineteen elements (Ag, Al, As, Ba, Ca, Cd, Co, Cr, Cu, Li, Fe, K, Mg, Mn, Na, Ni, Pb, Sr, and Zn) were analyzed by atomic emission spectrometry with inductively coupled plasma. The obtained values of the investigated elements in attic dust samples were statistically processed using nonparametric and parametric analysis. Factor analysis revealed three factors governing the source of individual chemical elements. Two of them grouping Ca, Li, Mg, Mn, and Sr (Factor 1) and Co, Cr, and Ni (Factor 2) can be characterized as geogenic. The third factor grouping As, Cu, and Pb is anthropogenic and mirrors dust fallout from mining operation and from flotation tailings. Maps of areal deposition were prepared for this group of elements, from which correlation of these anthropogenic born elements was confirmed.

  13. Lead exposure in children living in a smelter community in region Lagunera, Mexico.

    Science.gov (United States)

    García Vargas, G G; Rubio Andrade, M; Del Razo, L M; Borja Aburto, V; Vera Aguilar, E; Cebrián, M E

    2001-03-23

    Industrial growth has created the potential for environmental problems in Mexico, since attention to environmental controls and urban planning has lagged behind the pace of industrialization. The aim of this cross-sectional study was to assess lead exposure in children aged 6-9 yr attending 3 primary schools and living in the vicinity of the largest smelter complex in Mexico. One of the schools is located 650 m distant from a smelter complex that includes a lead smelter (close school); the second is located 1750 m away from the complex and at the side of a heavy traffic road (intermediate school) in Torreon, Coahuila. The third school is located in Comez Palacio, Durango, 8100 m away from the smelter complex and distant from heavy vehicular traffic or industrial areas (remote school). Lead was measured in air, soil, dust, and well water. Lead in blood (PbB) was determined in 394 children attending the above mentioned schools. Determinations were performed by atomic absorption spectrometry. Diet, socioeconomic status, hygienic habits, and other variables were assessed by questionnaire. Median (range) PbB values were 7.8 microg/dl (3.54-29.61) in the remote school, 21.8 microg/dl (8.37-52.08) in the intermediate school and 27.6 microg/dl (7.37-58.53) in children attending the close school. The percentage of children with PbB > 15 microg/dl was 6.80%, 84.9%, and 92.1% respectively. In this order, the geometric means (range) of Pb concentrations in air were 2.5 microg/m3 (1.1-7.5), 5.8 microg/m3 (4.3-8.5), and 6.1 microg/m3 (1.6-14.9). The Pb concentrations in dust from playgrounds areas in the intermediate and close school settings ranged from 1,457 to 4,162.5 mg/kg. Pb concentrations in drinking water were less than 5 microg/L. Soil and dust ingestion and inhalation appear to be the main routes of exposure. Our results indicate that environmental contamination has resulted in an increased body burden of Pb, suggesting that children living in the vicinity of the

  14. Heavy metal content of lichens in relation to distance from a nickel smelter in Sudbury, Ontario

    Energy Technology Data Exchange (ETDEWEB)

    Nieboer, E; Ahmed, H M; Puckett, K J; Richardson, D H.S.

    1972-01-01

    The Sudbury region of Ontario has large deposits of nickel, iron, and copper, and thus a number of smelting plants which produce sulfur dioxide and heavy metal pollution. Since lichens are good indicators of SO/sub 2/ pollution levels, the pattern of heavy metal content in lichen species in the area of a copper smelter in Sudbury was correlated with distance from the smelter to ascertain whether lichens might also be good indicators of the amount of heavy metal fallout. The lichens were analyzed qualitatively and quantitatively. All seven species of lichens contained copper, iron, zinc, nickel, manganese, and lead. Cadmium and cobalt were detected in two species. Neither gold nor silver could be identified in lichen material with the tests used. A pollution model was developed and compared to field results. The simple dilution of the stack effluent was consistent with the fact that the lichen metal content was related to the reciprocal of the distance from the pollution source. The lichens from the area could tolerate simultaneously high concentrations of several heavy metals that are known to be toxic to other plants. The mechanism of metal uptake was not clearly established. The study showed that lichens and other epiphytes are potentially the most useful indicators of heavy metal fallout around industrial plants.

  15. Spatial distribution and risk assessment of heavy metals in soil near a Pb/Zn smelter in Feng County, China.

    Science.gov (United States)

    Shen, Feng; Liao, Renmei; Ali, Amjad; Mahar, Amanullah; Guo, Di; Li, Ronghua; Xining, Sun; Awasthi, Mukesh Kumar; Wang, Quan; Zhang, Zengqiang

    2017-05-01

    A large scale survey and a small scale continuous monitoring was conducted to evaluate the impact of Pb/Zn smelting on soil heavy metals (HMs) accumulation and potential ecological risk in Feng County, Shaanxi province of China. Soil parameters including pH, texture, CEC, spatial and temporal distribution of HMs (Cd, Cu, Ni, Pb and Zn), and BCR fractionation were monitored accordingly. The results showed the topsoil in the proximity of smelter, especially the smelter area and county seat, were highly polluted by HMs in contrast to the river basins. Fractionation of Cd and Zn in soil samples revealed higher proportion of mobile fractions than other HMs. The soil Cd and Zn contents decreased vertically, but still exceeded the second level limits of Environmental Quality Standard for Soils of China (EQSS) within 80cm. The dominated soil pollutant (Cd) had higher ecological risk than Cu, Ni, Zn and Pb. The potential ecological risk (PER) factor of Cd were 65.7% and 100% in surrounding county and smelter area, respectively. The long-term smelter dust emission mainly contributed to the HMs pollution and posed serious environment risk to living beings. Copyright © 2017 Elsevier Inc. All rights reserved.

  16. Thermodynamic analysis of dust sulphation reactions

    Energy Technology Data Exchange (ETDEWEB)

    Yang Yongxiang; Jokilaakso, A.

    1997-12-31

    Sulphation reactions of metal oxides with SO{sub 2} and O. or SO{sub 3} play significant roles in sulphation roasting of sulphide and oxide minerals as well as in desulphurisation process of combustion gases. In metallurgical waste-heat boilers for sulphide smelting, the sulphation of the oxidic flue dust in the atmosphere containing sulphur oxides is an unavoidable process, and the sulphation reactions have to be guided in a controlled way in the proper parts of the gas handling equipment. In this report, some thermodynamic analyses were conducted for the oxide sulphation reactions in relation to sulphide smelting processes. The phase stability of Me-S-O systems especially for oxides - sulphates equilibrium was studied under different thermodynamic conditions of gas compositions and temperatures. The sulphate stability was analysed for an example of gas compositions in the copper flash smelter of Outokumpu Harjavalta Metals Oy, in relation to temperature. In the report, most of the information was from literature. Moreover, a number of thermodynamic computations were carried out with the HSC program, and the constructed phase stability diagrams were compared with those from the literature whenever possible. The maximum temperatures for stable sulphates under normal operating conditions of the waste-heat boilers in sulphide smelting processes were obtained. This report will serve as the basis for the kinetic studies of the sulphation reactions and the sulphation reaction modelling in pyrometallurgical processes. (orig.) SULA 2 Programme. 36 refs.

  17. Arsenic exposure to smelter workers. Clinical and neurophysiological studies

    Energy Technology Data Exchange (ETDEWEB)

    Blom, S.; Lagerkvist, B.; Linderholm, H.

    1985-08-01

    Forty-seven copper smelter workers, exposed to airborne arsenic for 8-40 years, were examined clinically with electromyography, and the motor and sensory conduction velocities in their arms and legs were determined. Fifty age-matched industrial workers not exposed to arsenic formed a reference group. The level of arsenic in the air at the smeltery was estimated to be below 500 micrograms/mT before 1975 and approximately 50 micrograms/mT thereafter. Urine analyses of arsenic showed a mean value of 71 micrograms/l (1 mumol/l) in the exposed group; this value is lower than that found in earlier studies reporting clinically detectable neuropathy. A slightly reduced nerve conduction velocity in two or more peripheral nerves was more common among the arsenic workers than the referents, and a statistically significant correlation between cumulative exposure to arsenic and reduced nerve conduction velocity in three peripheral motor nerves was found. This occurrence was interpreted as a sign of slight subclinical neuropathy. In conclusion the risk of clinically significant neuropathy is small when exposure is kept below 50 micrograms/mT in workroom air. The subclinical findings may be of interest in relation to the prevention of early adverse health effects from arsenic exposure.

  18. Decreasing emissions of a secondary lead smelter by installation of a battery breaker. Emissionsminderung einer Sekundaerbleihuette durch Integration einer Akkuschrott-Aufbereitung

    Energy Technology Data Exchange (ETDEWEB)

    Lamm, K F

    1986-11-01

    Dust and lead emissions of a secondary lead smelter mainly from the area of stockyards, handling, transport, charge preparing as well as the further treatment in rotary furnaces. A 60% decrease is obtained by compact assembling of covered battery stockyard, battery breaker and charge preparation and direct connection to the existing smelter area. The breaker itself contains a wet screen trommel and a filter press for separation of paste. The heavy-media sink-float-system has been replaced by dynamic water separation, which results in cleaner qualities of all fractions. In spite of a 100% wet separation plant, a bagfilter can be used with expected clean gas dust contents below 5 mg/m{sup 3} and below 2.5 mg Pb/m{sup 3}. Over a 2 years-period, dust and lead contents have been below 1 mg/m{sup 3}. (orig.) With 5 refs., 2 flowsheets, 10 figs.

  19. Characterisation of airborne particulate pollution in the Cu smelter and former mining town of Karabash, South Ural Mountains of Russia.

    Science.gov (United States)

    Williamson, B J; Udachin, V; Purvis, O W; Spiro, B; Cressey, G; Jones, G C

    2004-11-01

    Airborne total suspended particulates (TSP), dusts from smelter blast furnace and converter stacks, and filtrates of snow melt waters have been characterised in the Cu smelter and former mining town of Karabash, Russia. TSP was collected at sites up- and downwind of the smelter and large waste and tailings dumps (Oct. 2000 and July 2001). Methods for particle size, mineralogical and elemental determinations have been tested and described, and a new PSD-MicroSOURCE XRD technique developed for the mineralogical analysis of microsamples on filter substrates. TSP in downwind samples has a mean equivalent spherical diameter of 0.5 microm (s.d. = 0.2) and was found to be 100% respirable. The main element of human health/environmental concern, above Russian maximum permitted levels (1 microg m(-3), average over any time period), was Pb which was measured at 16-30 microg m(-3) in downwind samples. Individual particulates mainly consisted of complex mixtures of anglesite (PbSO4), Zn2SnO4 and poorly ordered Zn sulphates. From experimental and theoretical considerations, a high proportion of contained Pb, Zn, Cd and As in this material is considered to be in a readily bioavailable form. Chemical and mineralogical differences between the TSP, stack dusts and snow samples are discussed, as well as the implications for human and regional environmental health.

  20. The influence of the intensity of smoking and years of work in the metallurgy on pro-oxidant/antioxidant balance in the blood of smelters.

    Science.gov (United States)

    Bizon, Anna; Antonowicz-Juchniewicz, Jolanta; Andrzejak, Ryszard; Milnerowicz, Halina

    2013-03-01

    The aim of this study was to investigate the effect of cigarette smoking and occupational exposure to heavy metals on the degree of pro-oxidant/antioxidant imbalance in smelters. The investigations were performed on the blood and urine of 400 subjects: 300 male copper smelters and 100 nonexposed male subjects. Biological material was divided into three groups: nonsmokers, those who smoked less than 20 cigarettes a day and those who smoked more than 20 cigarettes a day. The results showed a significant increase in the concentration of lead, cadmium and arsenic in the blood and urine of smelters, while smoking more than 20 cigarettes a day caused a further increase in the concentration of these metals. The level of malondialdehyde was approximately twofold higher in the plasma of the smelters compared to the control group. We have observed a disturbance in the level of antioxidants in erythrocyte lysate manifested by an increase in metallothionein and glutathione concentrations as well as superoxide dismutase and glutathione peroxidase activities and the decrease in glutathione S-transferase activity. Cigarette smoking, years of work in metallurgy and age of smelters were additional factors significantly affecting the pro-oxidant/antioxidant balance.

  1. Spatial clustering of toxic trace elements in adolescents around the Torreón, Mexico lead–zinc smelter

    Science.gov (United States)

    Garcia-Vargas, Gonzalo G.; Rothenberg, Stephen J.; Silbergeld, Ellen K.; Weaver, Virginia; Zamoiski, Rachel; Resnick, Carol; Rubio-Andrade, Marisela; Parsons, Patrick J.; Steuerwald, Amy J.; Navas-Acién, Ana; Guallar, Eliseo

    2016-01-01

    High blood lead (BPb) levels in children and elevated soil and dust arsenic, cadmium, and lead were previously found in Torreón, northern Mexico, host to the world’s fourth largest lead–zinc metal smelter. The objectives of this study were to determine spatial distributions of adolescents with higher BPb and creatinine-corrected urine total arsenic, cadmium, molybdenum, thallium, and uranium around the smelter. Cross-sectional study of 512 male and female subjects 12–15 years of age was conducted. We measured BPb by graphite furnace atomic absorption spectrometry and urine trace elements by inductively coupled plasma-mass spectrometry, with dynamic reaction cell mode for arsenic. We constructed multiple regression models including sociodemographic variables and adjusted for subject residence spatial correlation with spatial lag or error terms. We applied local indicators of spatial association statistics to model residuals to identify hot spots of significant spatial clusters of subjects with higher trace elements. We found spatial clusters of subjects with elevated BPb (range 3.6–14.7 µg/dl) and urine cadmium (0.18–1.14 µg/g creatinine) adjacent to and downwind of the smelter and elevated urine thallium (0.28–0.93 µg/g creatinine) and uranium (0.07–0.13 µg/g creatinine) near ore transport routes, former waste, and industrial discharge sites. The conclusion derived from this study was that spatial clustering of adolescents with high BPb and urine cadmium adjacent to and downwind of the smelter and residual waste pile, areas identified over a decade ago with high lead and cadmium in soil and dust, suggests that past and/or present plant operations continue to present health risks to children in those neighborhoods. PMID:24549228

  2. Impact of Site Elevation on Mg Smelter Design

    Science.gov (United States)

    Baker, Phillip W.

    Site elevation has many surprising and significant impacts on the engineering design of metallurgical plant of all types. Electrolytic magnesium smelters maybe built at high elevation for a variety of reasons including availability of raw material, energy or electric power. Because of the unit processes they typically involve, Mg smelters can be extensively impacted by site elevation. In this paper, generic examples of the design changes required to adapt a smelter originally designed for sea level to operate at 2700 m are presented. While the examples are drawn from a magnesium plant design case, these changes are generically applicable to all industrial plants utilizing similar unit processes irrespective of product.

  3. Reaction Mechanism and Distribution Behavior of Arsenic in the Bottom Blown Copper Smelting Process

    Directory of Open Access Journals (Sweden)

    Qinmeng Wang

    2017-08-01

    Full Text Available The control of arsenic, a toxic and carcinogenic element, is an important issue for all copper smelters. In this work, the reaction mechanism and distribution behavior of arsenic in the bottom blown copper smelting process (SKS process were investigated and compared to the flash smelting process. There are obvious differences of arsenic distribution in the SKS process and flash process, resulting from the differences of oxygen potentials, volatilizations, smelting temperatures, reaction intensities, and mass transfer processes. Under stable production conditions, the distributions of arsenic among matte, slag, and gas phases are 6%, 12%, and 82%, respectively. Less arsenic is reported in the gas phase with the flash process than with the SKS process. The main arsenic species in gas phase are AsS (g, AsO (g, and As2 (g. Arsenic exists in the slag predominantly as As2O3 (l, and in matte as As (l. High matte grade is harmful to the elimination of arsenic to gas. The changing of Fe/SiO2 has slight effects on the distributions of arsenic. In order to enhance the removal of arsenic from the SKS smelting system to the gas phase, low oxygen concentration, low ratios of oxygen/ore, and low matte grade should be chosen. In the SKS smelting process, no dust is recycled, and almost all dust is collected and further treated to eliminate arsenic and recover valuable metals by other process streams.

  4. Recirculation effect of Chilean copper smelting dust with high impurities contents on the impurity distributions during smelting process; Efecto de la recirculacion de polvo de fundicion de cobre de Chile con altos contenidos de impurezas en la distribucion de impurezas durante el proceso de fusion

    Energy Technology Data Exchange (ETDEWEB)

    Montenegro, V.; Sano, H.; Fujisawa, T.

    2010-07-01

    Usually, dust generated during the copper smelting process by the Teniente Converter and the Flash Smelting Furnaces in Chile, contains high concentrations of copper, zinc, arsenic, antimony and other metals. In general, the dust is recirculated to the smelting process or it is directed to hydrometallurgical process for recovery and stabilization. However, in recent years the generation of dust has increased because of the degradation of the quality of the concentrate. In addition, the environmental regulations have become stricter. It is therefore desirable to understand the behavior of those elements, when the smelting process operates with recirculation of dust. In this study, the effect of dust recirculation to smelting process on the distribution among the matte, slag and gas phases was evaluated, as a function of matte grade, amount of recirculated dust, oxygen enrichment and temperature. It was found that the concentration in the matte of the impurities such as arsenic, antimony and bismuth, increased slightly with recirculation of dust. On the other hand, the concentration of lead and zinc depend of the direct recirculation of dust to the process. Additionally, it was found that high concentrations of arsenic and antimony in the dust may lead to the formation and precipitation of copper arsenates and other metals (speiss), which may generates important operational problems. (Author) 15 refs.

  5. Soil microbial effects of smelter induced heavy metal contamination

    Energy Technology Data Exchange (ETDEWEB)

    Nordgren, A

    1986-01-01

    The soil concentrations of Cu and Zn at the secondary smelter were 20 00 mu g/g dry soil. Close to the primary smelter the soil was contaminated with more than ten elements including Pb, Zn, Cu and As at levels ranging between 6000 and 1000 mu g/g dry soil. The correlations between the concentrations of the metals were high at both smelters. Soil respiration rate decreased by about 75% close to both smelters. Total and fluorescein diacetate stained mycelial lengths decrease with increasing heavy metal pollution at the secondary but not at the primary smelter. The fungal community structure was strongly affected by the contamination. General common in coniferous forest soils such as Penicillium and Oidiodendron virtually vanished, while less frequent species like Paecilomyces farinosus and Geomyces pannorum dominated the site close to the smelter. Colony forming units of a number of functional groups of bacteria were found to be very sensitive to metal contamination. The urease activity of the soil was inhibited. Multivariate statistical analyses showed that the metal contamination was the major environmental influence on the microbiotain the soils studied. A study of about 200 decomposition curves resulting from glutamic acid additions to the different soils produced four microbially related parameters: basal respiration rate, initial respiration rate after the addition of the glutamic acid, specific respiration rate during the exponential increase of the respiration rate and the lag time before the exponential phase. With 53 refs.

  6. Treatment of metallurgical wastes : recovery of metal values from smelter slags by pressure oxidative leaching

    Energy Technology Data Exchange (ETDEWEB)

    Li, Y.; Perederiy, I.; Papangelakis, V.G. [Toronto Univ., ON (Canada). Dept. of Chemical Engineering and Applied Chemistry

    2008-07-01

    Vast quantities of slag are produced and dumped as waste by-products during the production of base metals by smelting operations. These slags contain large amounts of valuable metals which lead to a decrease in metal yield and, combined with the entrapped sulphur, pose a danger to the environment. The dissolution of fayalite is important for the selective recovery of valuable metals and the cleanup of slags in high pressure oxidative leaching. The nature of base metals and iron in solidified slag must be investigated in order to understand the mechanism of the process. This paper discussed the application of powder X-ray diffraction (PXRD) and scanning electron microscopy (SEM) for the characterization of a smelter slag microstructure. The study used leaching tests with the same smelter slag to measure and monitor the results of leaching, including metal extraction levels, the extent of iron dissolution as well as impurity contents. The paper provided information on the experiment with particular reference to slag leaching, chemical analysis, and characterization. It was concluded that slag consists of several solid phases with base metal sulfide and oxide droplets entrapped in the fayalite matrix or silica regions. Therefore, nickel, copper, cobalt, and zinc need to be exposed either chemically or mechanically to promote their recovery. 21 refs., 4 tabs., 5 figs.

  7. Effects of emission reductions from the smelters in Sudbury on recovery of lakes within the metal deposition zone

    Energy Technology Data Exchange (ETDEWEB)

    Keller, W.; Heneberry, J.; Clark, M.; Malette, M.; Gunn, J. [Laurentian Univ., Sudbury, ON (Canada) Dept. of Biology

    1999-07-01

    Recent trends are examined in the chemistry of Sudbury lakes for evidence of further chemical recovery, as well as some of the biological characteristics of recovering Sudbury lakes. Preliminary results are provided from studies investigating physical, chemical and biological factors that may influence the lake recovery process with a focus on the lakes close to Sudbury that were historically the most severely affected. Smelter emission reductions in the Sudbury area have led to substantial changes in the water quality of area lakes, and decreases in acidity, sulfate, and copper and nickel concentrations followed the substantial decreases in emissions during the 1970s and similar trends are continuing after the implementation of large additional smelter emission reductions in the 1990s. Some of the most highly affected lakes close to the Sudbury smelters have showed very dramatic reductions in acidity and metal concentrations during the 1990s. Evaluation of the direct effects of the recent emissions reductions is confounded by the potential continuing effects of previous emission reductions and the effects of weather variations on chemistry time trends in Sudbury lakes. Continued monitoring of Sudbury lakes is essential to evaluate the ultimate effect of emission reduction programs, to develop an understanding of the recovery process, and to determine the need for any additional emission reduction requirements. 38 refs., 7 figs.

  8. Food chain transfer of cadmium and lead to cattle in a lead-zinc smelter in Guizhou, China

    International Nuclear Information System (INIS)

    Cai Qiu; Long Meili; Zhu Ming; Zhou Qingzhen; Zhang Ling; Liu Jie

    2009-01-01

    Cadmium (Cd) and Lead (Pb) are environmental pollutants. Environmental samples and bovine tissues were collected from the areas around a lead-zinc smelter in Guizhou, China for Cd, Pb, zinc (Zn) and copper (Cu) analysis. Cd in soil (10 mg/kg) and feed (6.6 mg/kg) from the polluted areas was 10 times higher than the Chinese Standards, resulting in higher Cd in bovine kidney (38 mg/kg) and liver (2.5 mg/kg). Pb in feed (132 mg/kg) from the polluted area was much higher than unpolluted areas, causing higher Pb levels in bovine tissues. Environmental Zn was elevated, but bovine tissue Zn was normal. Cu in bovine liver decreased with increased Cd and Pb. Metals in drinking water and in bovine muscle were within the Standard range. Thus, in the areas of this lead-zinc smelter, the environment has been contaminated with Cd and Pb, which has been transferred to cattle through the food chain. - Cd and Pb from lead-zinc smelters contaminate the environment and accumulate in bovine tissues.

  9. Arsenic and cadmium exposure in children living near a smelter complex in San Luis Potosi, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Diaz-Barriga, F.; Santos, M.A.; Mejia, J.J.; Batres, L.; Yanez, L.; Carrizales, L.; Vera, E.; del Razo, L.M.; Cebrian, M.E. (Universidad Autonoma de San Luis Potosi (Mexico))

    1993-08-01

    The main purpose of this study was to assess environmental contamination by arsenic and cadmium in a smelter community (San Luis Potosi City, Mexico) and its possible contribution to an increased body burden of these elements in children. Arsenic and cadmium were found in the environment (air, soil, and household dust, and tap water) as well as in the urine and hair from children. The study was undertaken in three zones: Morales, an urban area close to the smelter complex; Graciano, an urban area 7 km away from the complex; and Mexquitic, a small rural town 25 km away. The environmental study showed that Morales is the most contaminated of the zones studied. The range of arsenic levels in soil (117-1396 ppm), dust (515-2625 ppm), and air (0.13-1.45 micrograms/m3) in the exposed area (Morales) was higher than those in the control areas. Cadmium concentrations were also higher in Morales. Estimates of the arsenic ingestion rate in Morales (1.0-19.8 micrograms/kg/day) were equal to or higher than the reference dose of 1 microgram/kg/day calculated by the Environmental Protection Agency. The range of arsenic levels in urine (69-594 micrograms/g creatinine) and hair (1.4-57.3 micrograms/g) and that of cadmium in hair (0.25-3.5 micrograms/g) indicated that environmental exposure has resulted in an increased body burden of these elements in children, suggesting that children living in Morales are at high risk of suffering adverse health effects if exposure continues.

  10. Lixiviación amoniacal de polvos de fundición de cobre y precipitación como sulfuro de cobre

    OpenAIRE

    Morales, A.; Hevia, J. F.; Cifuentes, G.

    2009-01-01

    The effect of ammonia on the leaching of copper smelter dust and copper precipitation from these solutions as sulphide using sulfur and sulfur dioxide was studied. The precipitation was done in ammoniacal media because this solution produced more satisfactory results at room temperature that a sulphuric media. A solid was precipitated containing 60 % of copper of the dust smelter. The other waste generated contained around 80 % of the arsenic of the original copper smelter dust. Based on the ...

  11. Biogeochemical studies of lead isotopes near a smelter

    International Nuclear Information System (INIS)

    Landrigan, P.J.; Baker, E.L. Jr.; Earl, J.L.; Chow, T.J.

    1975-01-01

    Ninety-nine percent of 1 to 9 year-old children living within 1 mile of a primary lead smelter in Idaho were found to have whole blood lead levels equal to or greater than 40μg/100 ml, a level indicative of excess lead absorption. To define the sources of this lead, isotope ratios were determined in lead from human and environmental samples obtained near the smelter; determinations were performed using a 30-cm radius, solid-source mass spectrometer with an electron multiplier. The Idaho ore is a pre-Cambrian lead deposit with 206 Pb/ 204 Pb = 16.43, 206 Pb = 1.0543 and 206 Pb/ 208 Pb = 0.4518. An ingot smelted in 1974 showed isotope ratios of 206 Pb/ 204 Pb = 17.66, 206 Pb/ 207 Pb = 1.1312 and 206 Pb/ 208 Pb = 0.4694, indicating a mixture of ore sources. Three surface soil samples from within 2 miles of the smelter had lead ratios similar to those in the ingot. A fourth soil sample from beside an interstate highway 32 miles east of the smelter showed different ratios: 206 Pb/ 204 Pb = 18.47, 206 Pb/ 207 Pb = 1.1826 and 206 Pb/ 208 Pb = 0.4823. Aerosol samples collected from October 4, 1974, to February 1, 1975, near the smelter showed considerable variation in ratios; these variations resulted from smelting of ores from differing sources

  12. Using microtherm microporous insulation in smelter applications

    Science.gov (United States)

    MacKenzie, Iain

    2000-02-01

    Microtherm is effective in reducing shell temperatures in confined spaces where compression is severe and much insulation is required. This material can prove beneficial for applications such as cement and lime rotary kiln transition and hot zones; copper converters and anode furnaces; steel and iron ladles, tundishes, RH vessels, and blast furnaces; and aluminum filter boxes, runners, and metal transporters.

  13. 76 FR 64943 - Proposed Cercla Administrative Cost Recovery Settlement; ACM Smelter and Refinery Site, Located...

    Science.gov (United States)

    2011-10-19

    ... Settlement; ACM Smelter and Refinery Site, Located in Cascade County, MT AGENCY: Environmental Protection... projected future response costs concerning the ACM Smelter and Refinery NPL Site (Site), Operable Unit 1..., Helena, MT 59626. Mr. Sturn can be reached at (406) 457-5027. Comments should reference the ACM Smelter...

  14. Some effects of smelter pollution northeast of Falconbridge, Ontario

    Energy Technology Data Exchange (ETDEWEB)

    Gorham, E

    1960-01-01

    A study along a line northwest from the metal smelter at Falconbridge, Ontario, reveals that strong sulphate accumulation in the surface soil occurs only within about one mile of the chimneys emitting sulphur dioxide pollution while effects upon the soil drainage waters are marked to a distance of nearly two miles, and still clearly evident 10 or more miles away. The number of species present in the flora declines sharply within about four miles of the smelter, but certain species (e.g. Pinus strobus, Vaccinium myrtilloides) disappear at much greater distances. Among the most tolerant species are Acer rubrum, Quercus rubra, Sambucus pubens, and Polygonum cilinode.

  15. Copper : recession and recovery

    International Nuclear Information System (INIS)

    Warwick-Ching, T.

    2002-01-01

    In 2002, the world output for copper will fall for the first time in nearly a decade because of financial pressure and voluntary constraints. Cutbacks at copper mines amount to 760,000 tonnes per year. These cutbacks have occurred mostly in the United States which holds the largest share of high cost mines. This paper discussed recent developments in both copper supply and demand. The United States is unique as both a large consumer and producer of copper. At 1.35 million tonnes, US mine output in 2001 was at its lowest since 1987. The cutbacks in mining in general were described in this paper with particular reference to the huge loss of mining and metallurgical activity in the United States during a prolonged period of low prices in the mid 1980s. The author noted that this period was followed by an exceptional decade when much of the industry rebounded. Only 8 mines closed outright in the United States and a handful in Canada since the recession of the 1980s, but that is partly because mines got bigger and there are fewer small mines in North America. There are only 4 electrolytic refineries and 3 smelters still active in the entire United States, of which 2 are operating at a fraction of capacity. It was noted that only the buoyancy of China prevented a much bigger decline in copper demand on a global scale

  16. Composition and fate of mine- and smelter-derived particulates in soils from humid subtropical and semiarid areas

    Science.gov (United States)

    Ettler, Vojtech; Kribek, Bohdan; Mihaljevic, Martin; Vanek, Ales; Penizek, Vit; Sracek, Ondra; Mapani, Ben; Kamona, Fred; Nyambe, Imasiku

    2017-04-01

    Soils in the vicinity of non-ferrous metal smelters are often highly polluted by inorganic contaminants released from particulate emissions, which undergo weathering processes and release contaminants when deposited in soils. We studied the heavy mineral fraction, separated from mining- and smelter-affected topsoils, from both a humid subtropical area in the Zambian Copperbelt and a hot semi-arid area in the northern Namibia. High concentrations of metal(loid)s were detected in the studied soils: up to 1450 ppm As, 8980 ppm Cu, 4640 ppm Pb, 2620 ppm Zn. A combination of X-ray diffraction analysis (XRD), scanning electron microscopy (SEM/EDS), and electron probe microanalysis (EPMA) helped to identify the phases forming individual metal(loid)-bearing particles. Whereas spherical particles originate from the smelting and flue gas cleaning processes, angular particles either have geogenic origins or they are windblown from the mining operations and mine waste disposal sites. Sulphides from ores and mine tailings often exhibit weathering rims in contrast to smelter-derived high-temperature sulphides (chalcocite [Cu2S], digenite [Cu9S5], covellite [CuS], non-stoichiometric quenched Cu-Fe-S phases). Soils from humid subtropical areas exhibit higher available concentrations of metal(loids), and higher frequencies of weathering features (especially for copper-bearing oxides such as delafossite [CuFeO2]) are observed. In contrast, metal(loid)s are efficiently retained in semi-arid soils, where a high proportion of non-weathered smelter slag particles and low-solubility Ca-Cu-Pb arsenates occur. Our results indicate that compared to semi-arid areas (where inorganic contaminants were rather immobile in soils despite their high concentrations) a higher potential risk exists for agriculture in mine- and smelter-affected humid subtropical areas (where metal(loid) contaminants can be highly available for the uptake by crops). This study was supported by the Czech Science

  17. Arsenic in industrial waste water from copper production technological process

    OpenAIRE

    Biljana Jovanović; Milana Popović

    2013-01-01

    Investigation of arsenic in industrial waste water is of a great importance for environment. Discharge of untreated waste water from a copper production process results in serious pollution of surface water, which directly affects flora and fauna, as well as humans. There is a need for efficient and environmentally acceptable treament of waste waters containing heavy metals and arsenic. The paper presents an analyisis of the waste water from The Copper Smelter which is discharged into the Bor...

  18. Arsenic accumulation in people working with and living near a gold smelter

    International Nuclear Information System (INIS)

    Jervis, R.E.; Tiefenbach, B.; Toronto Univ., Ontario

    1979-01-01

    The processing of arsenic-containing ores for the recovery of metals such as gold, copper or lead can cause both an occupational health hazard to smelter workers and an environmental health problem to persons living downwind from the refineries. The study reported is a follow-up to preliminary investigations of possible arsenic ingestion by native children living near a gold refinery at Yellowknife, N.W.T., Canada and of a few mine-mill workers. Instrumental neutron activation of lake water and melted snow used as drinking water as well as of scalp hair gave evidence of appreciable intake of arsenic and some mercury. A further set of 67 hair samples was obtained from most of the smelter workers and from children in a native settlement who were considered most vulnerable, augmented by a set of 26 control samples from steel workers and children living in a comparable (but arsenic-free) northern area about 1000 km distance at Whitehorse, Yukon. Hair arsenic levels were consistently elevated above the controls, ranging to 280 ppm in one worker. The water supplies ranged up to 3 ppm, well above the 0.05 ppm MPC for drinking water. A larger epidemiological study of the area and of Hay River, N.W.T. controls, done in association with electromyography, was just completed and involved a further 414 children and workers from Yellowknife and 105 from the control area. The mean hair arsenic of 6.7 ppm for the former was quite different from a result of 0.33 ppm for the Hay River group, and 33% of the Yellowknife subjects were elevated above 1 ppm but none of the controls were above this concentration. Four workers were above 100 ppm, ranging as high as 620 ppm hair arsenic

  19. Toxicity of smelter slag-contaminated sediments from Upper Lake Roosevelt and associated metals to early life stage White Sturgeon (Acipenser transmontanus Richardson, 1836)

    Science.gov (United States)

    Little, E.E.; Calfee, R.D.; Linder, G.

    2014-01-01

    The toxicity of five smelter slag-contaminated sediments from the upper Columbia River and metals associated with those slags (cadmium, copper, zinc) was evaluated in 96-h exposures of White Sturgeon (Acipenser transmontanus Richardson, 1836) at 8 and 30 days post-hatch. Leachates prepared from slag-contaminated sediments were evaluated for toxicity. Leachates yielded a maximum aqueous copper concentration of 11.8 μg L−1 observed in sediment collected at Dead Man's Eddy (DME), the sampling site nearest the smelter. All leachates were nonlethal to sturgeon that were 8 day post-hatch (dph), but leachates from three of the five sediments were toxic to fish that were 30 dph, suggesting that the latter life stage is highly vulnerable to metals exposure. Fish maintained consistent and prolonged contact with sediments and did not avoid contaminated sediments when provided a choice between contaminated and uncontaminated sediments. White Sturgeon also failed to avoid aqueous copper (1.5–20 μg L−1). In water-only 96-h exposures of 35 dph sturgeon with the three metals, similar toxicity was observed during exposure to water spiked with copper alone and in combination with cadmium and zinc. Cadmium ranging from 3.2 to 41 μg L−1 or zinc ranging from 21 to 275 μg L−1 was not lethal, but induced adverse behavioral changes including a loss of equilibrium. These results suggest that metals associated with smelter slags may pose an increased exposure risk to early life stage sturgeon if fish occupy areas contaminated by slags.

  20. Long term insight into biodiversity of a smelter wasteland reclaimed with biosolids and by-product lime.

    Science.gov (United States)

    Siebielec, Sylwia; Siebielec, Grzegorz; Stuczyński, Tomasz; Sugier, Piotr; Grzęda, Emilia; Grządziel, Jarosław

    2018-09-15

    Smelter wastelands containing high amounts of zinc, lead, cadmium, and arsenic constitute a major problem worldwide. Serious hazards for human health and ecosystem functioning are related to a lack of vegetative cover, causing fugitive dust fluxes, runoff and leaching of metals, affecting post-industrial ecosystems, often in heavily populated areas. Previous studies demonstrated the short term effectiveness of assisted phytostabilisation of zinc and lead smelter slags, using biosolids and liming. However, a long term persistence of plant communities introduced for remediation and risk reduction has not been adequately evaluated. The work was aimed at characterising trace element solubility, plant and microbial communities of the top layer of the reclaimed zinc and lead smelter waste heaps in Piekary Slaskie, Poland, 20 years after the treatment and revegetation. The surface layer of the waste heaps treated with various rates of biosolids and the by-product lime was sampled for measuring chemical and biochemical parameters, which are indicative for metals bioavailability as well as for microorganisms activity. Microbial processes were characterised by enzyme activities, abundance of specific groups of microorganisms and identification of N fixing bacteria. Plant communities of the area were characterised by a percent coverage of the surface and by a composition of plant species and plant diversity. The study provides a strong evidence that the implemented remediation approach enables a sustainable functioning of the ecosystem established on the toxic waste heaps. Enzyme activities and the count of various groups of microorganisms were the highest in areas treated with both biosolids and lime, regardless their rates. A high plant species diversity and microbial activities are sustainable after almost two decades from the treatment, which is indicative of a strong resistance of the established ecosystem to a metal stress and a poor physical quality of the

  1. The mineralogy of bauxite for producing smelter-grade alumina

    Science.gov (United States)

    Authier-Martin, M.; Forte, G.; Ostap, S.; See, J.

    2001-12-01

    Aluminum-producing companies rely on low-cost, high-purity, smelter-grade alumina (aluminum oxide), and alumina production utilizes the bulk of bauxites mined world-wide. The mineralogy of the bauxites has a significant impact on the operation of the Bayer process for alumina production. Typically, the Bayer process produces smelter-grade alumina of 99.5% Al2O3, starting from bauxite containing 30% to 60% Al2O3. The main objective of the Bayer process is to extract the maximum amount of aluminum from the bauxite at as high an aluminate concentration in solution as possible, while limiting any troublesome side reactions. Only with a better understanding of the chemistry of the mineral species and a strict control of the operating/processing conditions can the Bayer process produce efficiently, a low cost, high-quality alumina with minimum detrimental environmental impact.

  2. Cancer risk among workers of a secondary aluminium smelter.

    Science.gov (United States)

    Maltseva, A; Serra, C; Kogevinas, M

    2016-07-01

    Cancer risk in secondary aluminium production is not well described. Workers in this industry are exposed to potentially carcinogenic agents from secondary smelters that reprocess aluminium scrap. To evaluate cancer risk in workers in a secondary aluminium plant in Spain. Retrospective cohort study of male workers employed at an aluminium secondary smelter (1960-92). Exposure histories and vital status through 2011 were obtained through personal interviews and hospital records, respectively. Standardized mortality (SMRs) and incidence ratios (SIRs) were calculated. The study group consisted of 98 workers. We found increased incidence and mortality from bladder cancer [SIR = 2.85, 95% confidence interval (CI) 1.23-5.62; SMR = 5.90, 95% CI 1.58-15.11]. Increased incidence was also observed for prostate cancer and all other cancers but neither were statistically significant. No increased risk was observed for lung cancer. Results of this study suggest that work at secondary aluminium smelters is associated with bladder cancer risk. Identification of occupational carcinogens in this industry is needed. © The Author 2016. Published by Oxford University Press on behalf of the Society of Occupational Medicine. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  3. Modeling and evaluation of urban pollution events of atmospheric heavy metals from a large Cu-smelter.

    Science.gov (United States)

    Chen, Bing; Stein, Ariel F; Castell, Nuria; Gonzalez-Castanedo, Yolanda; Sanchez de la Campa, A M; de la Rosa, J D

    2016-01-01

    Metal smelting and processing are highly polluting activities that have a strong influence on the levels of heavy metals in air, soil, and crops. We employ an atmospheric transport and dispersion model to predict the pollution levels originated from the second largest Cu-smelter in Europe. The model predicts that the concentrations of copper (Cu), zinc (Zn), and arsenic (As) in an urban area close to the Cu-smelter can reach 170, 70, and 30 ng m−3, respectively. The model captures all the observed urban pollution events, but the magnitude of the elemental concentrations is predicted to be lower than that of the observed values; ~300, ~500, and ~100 ng m−3 for Cu, Zn, and As, respectively. The comparison between model and observations showed an average correlation coefficient of 0.62 ± 0.13. The simulation shows that the transport of heavy metals reaches a peak in the afternoon over the urban area. The under-prediction in the peak is explained by the simulated stronger winds compared with monitoring data. The stronger simulated winds enhance the transport and dispersion of heavy metals to the regional area, diminishing the impact of pollution events in the urban area. This model, driven by high resolution meteorology (2 km in horizontal), predicts the hourly-interval evolutions of atmospheric heavy metal pollutions in the close by urban area of industrial hotspot.

  4. Use of neutron activation analysis to determine arsenic and antimony concentrations in creosote bushes collected near a lead smelter in El Paso, Texas

    International Nuclear Information System (INIS)

    Gardea-Torresdey, J.; Tiemann, K.J.; Parsons, J.G.; Landsberger, S.; O'Kelly, D.

    2001-01-01

    It his been found that some soils adjacent to a lead smelter in El Paso, Texas possess lead and copper concentrations as high as 5,067 mg/kg (parts per million) and 4,955 mg/kg, respectively. These concentrations are at least one order of magnitude higher than naturally occurring levels. The objective of this work is to determine the amount of metal accumulation within creosote bush, as it is found naturally growing in metal contaminated soils through analysis of soil and plant tissue samples. (R.P.)

  5. Possibilities of radioisotopic fluorescence analysis application in copper industry

    International Nuclear Information System (INIS)

    Parus, J.; Kierzek, J.

    1983-01-01

    The main applications of X-ray fluorescence analysis in copper industry such as: copper ores and other materials from flotation analysis, lead and silver determination in blister copper, analysis of metallurgic dusts and copper base alloys analysis are presented. (A.S.)

  6. Effects of soil copper and nickel on survival and growth of Scots pine.

    Science.gov (United States)

    Nieminen, Tiina Maileena

    2004-11-01

    The contribution of soil Cu and Ni pollution to the poor vitality and growth rate of Scots pine growing in the vicinity of a Cu-Ni smelter was investigated in two manipulation experiments. In the first manipulation, Cu-Ni smelter-polluted soil cores were transported from a smelter-pollution gradient to unpolluted greenhouse conditions. A 4-year-old pine seedling was planted in each core and cultivated for a 17-month period. In the second manipulation, pine seedlings from the same lot were cultivated for the same 17-month period in a quartz sand medium containing increasing doses of copper sulfate, nickel sulfate, and a combination of both. The variation in the biomass growth of the seedlings grown in the smelter-polluted soil cores was very similar to that of mature pine stands growing along the same smelter-pollution gradient in the field. In addition, the rate of Cu and Ni exposure explained a high proportion of the biomass growth variation, and had an effect on the Ca, K, and Mg status of the seedlings. According to the lethal threshold values determined on the basis of the metal sulfate exposure experiments, both the Cu and Ni content of the 0.5 km smelter-polluted soil cores were high enough to cause the death of most of the seedlings. The presence of Cu seemed to increase Ni toxicity.

  7. Local survival of pied flycatcher males and females in a pollution gradient of a Cu smelter

    International Nuclear Information System (INIS)

    Eeva, T.; Hakkarainen, H.; Belskii, E.

    2009-01-01

    Survival is one of the most central population measures when the effects of the pollution are studied in natural bird populations. However, only few studies have actually measured rigorous survival estimates on adult birds. In recent years there has been a methodological advance in survival analyses by mark-recapture models. We modelled local survival (including mortality and emigration) with the program MARK in a population of a small insectivorous passerine bird, the pied flycatcher (Ficedula hypoleuca), around a point source of heavy metals. The local survival of females in the polluted area was about 50% lower than in the other areas. Males, however, survived relatively well in the heavily polluted area, but showed somewhat lower survival in the moderately polluted area. Different pollution effects between two sexes might be due to pollution-related differences in reproductive effort in females and males, and/or more intensive uptake of heavy metals by laying females. - Female pied flycatchers (Ficedula hypoleuca) show decreased local survival around a copper smelter.

  8. Lunar Dust Mitigation Screens

    Science.gov (United States)

    Knutson, Shawn; Holloway, Nancy

    being developed in a collaborative effort between Langley Research Center and Kennedy Space Center. The screens typically consist of spiral shaped conductive traces patterned on high dielectric substrates (i.e. glass, quartz, polyimide film, etc.). Two broad categories of substrate materials are being investigated for the screens. One category consists of transparent substrates (i.e. glass, quartz, sapphire, etc.), and the other non-transparent sub-strates (Kapton, polyimide films, metals, etc.). The transparent screens utilize patterns made from indium tin oxide (ITO), a transparent conductive material, on clear substrates while the non-transparent screens use copper patterns on a transluscent or opaque substrates. Further, the screen is coated with a high dielectric polyimide cover layer to protect the screen pattern. One promising cover layer material that is currently being investigated is Langley Research Center-Soluble Imide (LaRC-SI), a NASA LaRC developed polyimide. Lastly, a top-coat of hard, inorganic material is evaporated onto the cover layer for protection from scratches due to abrasive nature of the dust. Of note, several top-coat materials are under investigation and include: aluminum oxide, silicon dioxide, titanium oxide, yttrium oxide, zirconium oxide, and zinc sulfide. The electrostatic dust mitigation screens function when a high voltage (700V or greater) is applied to the screen electrodes, thus creating an electromagnetic wave across the surface of the screen that repels the dust. Lunar dust typically contains a high positive charge; therefore, the screens are charged with a higher positive charge that effectively repels dust from the surface (i.e. like charges repel, unlike charges attract). It is anticipated that full development and maturation of this technology will enable humans to sustain a long term presence on the moon, and other planets where dust may have negative implications.

  9. EMERGING TECHNOLOGY BULLETIN: RECLAMATION OF LEAD FROM SUPERFUND WASTE MATERIAL USING SECONDARY LEAD SMELTERS

    Science.gov (United States)

    This process involves incorporating lead-contaminated Superfund waste with the regular feed to a secondary lead smelter. Since secondary lead smelters already recover lead from recycled automobile batteries, it seems likely that this technology could be used to treat waste from ...

  10. Characterization and recovery of copper values from discarded slag.

    Science.gov (United States)

    Das, Bisweswar; Mishra, Barada Kanta; Angadi, Shivakumar; Pradhan, Siddharth Kumar; Prakash, Sandur; Mohanty, Jayakrushna

    2010-06-01

    In any copper smelter large quantities of copper slag are discarded as waste material causing space and environmental problems. This discarded slag contains important amounts of metallic values such as copper and iron. The recovery of copper values from an Indian smelter slag that contains 1.53% Cu, 39.8% Fe and 34.65% SiO(2) was the focus of the present study. A complete investigation of the different phases present in the slag has been carried out by means of optical microscopy, Raman spectroscopy, scanning electron microscopy (SEM), and X-ray diffraction (XRD) techniques. It is observed that iron and silica are mostly associated with the fayalite phase whereas copper is present in both oxide and sulfide phases. These oxide and sulfide phases of copper are mostly present within the slag phase and to some extent the slag is also embedded inside the oxide and sulfide phases. The recovery of copper values from the discarded slag has been explored by applying a flotation technique using conventional sodium isopropyl xanthate (SIX) as the collector. The effects of flotation parameters such as pH and collector concentration are investigated. Under optimum flotation conditions, it is possible to achieve 21% Cu with more than 80% recovery.

  11. Assessment of a remediation technique using the replacement of contaminated soils in kitchen gardens nearby a former lead smelter in Northern France.

    Science.gov (United States)

    Douay, F; Roussel, H; Pruvot, C; Loriette, A; Fourrier, H

    2008-08-15

    Vegetables cultivated in kitchen gardens that are strongly contaminated by heavy metals (Pb, Cd) may represent to consumers a means of exposure to these metals. This exposure is more problematic for those families that include a large quantity of home-grown vegetables in their diet. Researchers have shown that the majority of vegetables produced in kitchen gardens in the vicinity of the Metaleurop Nord smelter (Northern France) do not conform to European regulations. This study was carried out in three of these kitchen gardens. The concentrations of Cd and Pb in the topsoils were up to 24 and 3300 mg kg(-1) respectively. The method consisted of delineating a surface area of about 50 to 100 m(2) for each garden, then removing the contaminated soil and replacing it with a clean one. Seven species of vegetables were cultivated from 2003 to 2005 in the original contaminated soils and the remediated ones. The data showed a clear improvement of the quality of the vegetables cultivated in remediated soils, although 17% of them were still over the European legislative limits for foodstuffs. This suggested that there was a foliar contamination due to contaminated dust fallout coming from the closed smelter site and the adjacent polluted soils. In addition, the measurement of the Cd and Pb concentrations in the dust fallout showed that the substantial rise in metal concentrations in the remediated soil was not only due to atmospheric fallout. These results raise questions about possible technical, economic and sociological problems associated with this kind of remediation.

  12. Osmium isotopic tracing of atmospheric emissions from an aluminum smelter

    Science.gov (United States)

    Gogot, Julien; Poirier, André; Boullemant, Amiel

    2015-09-01

    We present for the first time the use of osmium isotopic composition as a tracer of atmospheric emissions from an aluminum smelter, where alumina (extracted from bauxite) is reduced through electrolysis into metallic aluminum using carbonaceous anodes. These anodes are consumed in the process; they are made of petroleum coke and pitch and have high Re/Os elementary ratio. Due to the relatively large geological age of their source material, their osmium shows a high content of radiogenic 187Os produced from in situ187Re radioactive decay. The radiogenic isotopic composition (187Os/188Os ∼ 2.5) of atmospheric particulate emissions from this smelter is different from that of other typical anthropogenic osmium sources (that come from ultramafic geological contexts with unradiogenic Os isotopes, e.g., 187Os/188Os < 0.2) and also different from average eroding continental crust 187Os/188Os ratios (ca. 1.2). This study demonstrates the capacity of osmium measurements to monitor particulate matter emissions from the Al-producing industry.

  13. Isotopic signatures suggest important contributions from recycled gasoline, road dust and non-exhaust traffic sources for copper, zinc and lead in PM10 in London, United Kingdom

    Science.gov (United States)

    Dong, Shuofei; Ochoa Gonzalez, Raquel; Harrison, Roy M.; Green, David; North, Robin; Fowler, Geoff; Weiss, Dominik

    2017-09-01

    The aim of this study was to improve our understanding of what controls the isotope composition of Cu, Zn and Pb in particulate matter (PM) in the urban environment and to develop these isotope systems as possible source tracers. To this end, isotope ratios (Cu, Zn and Pb) and trace element concentrations (Fe, Al, Cu, Zn, Sb, Ba, Pb, Cr, Ni and V) were determined in PM10 collected at two road sites with contrasting traffic densities in central London, UK, during two weeks in summer 2010, and in potential sources, including non-combustion traffic emissions (tires and brakes), road furniture (road paint, manhole cover and road tarmac surface) and road dust. Iron, Ba and Sb were used as proxies for emissions derived from brake pads, and Ni, and V for emissions derived from fossil fuel oil. The isotopic composition of Pb (expressed using 206Pb/207Pb) ranged between 1.1137 and 1.1364. The isotope ratios of Cu and Zn expressed as δ65CuNIST976 and δ66ZnLyon ranged between -0.01‰ and +0.51‰ and between -0.21‰ and +0.33‰, respectively. We did not find significant differences in the isotope signatures in PM10 over the two weeks sampling period and between the two sites, suggesting similar sources for each metal at both sites despite their different traffic densities. The stable isotope composition of Pb suggests significant contribution from road dust resuspension and from recycled leaded gasoline. The Cu and Zn isotope signatures of tires, brakes and road dust overlap with those of PM10. The correlation between the enrichments of Sb, Cu, Ba and Fe in PM10 support the previously established hypothesis that Cu isotope ratios are controlled by non-exhaust traffic emission sources in urban environments (Ochoa Gonzalez et al., 2016). Analysis of the Zn isotope signatures in PM10 and possible sources at the two sites suggests significant contribution from tire wear. However, temporary additional sources, likely high temperature industrial emissions, need to be invoked

  14. Wood Dust

    Science.gov (United States)

    Learn about wood dust, which can raise the risk of cancers of the paranasal sinuses and nasal cavity. High amounts of wood dust are produced in sawmills, and in the furniture-making, cabinet-making, and carpentry industries.

  15. Electrometallurgy of copper refinery anode slimes

    Science.gov (United States)

    Scott, J. D.

    1990-08-01

    High-selenium copper refinery anode slimes form two separate and dynamically evolving series of compounds with increasing electrolysis time. In one, silver is progressively added to non-stoichiometric copper selenides, both those originally present in the anode and those formed subsequently in the slime layer, and in the other, silver-poor copper selenides undergo a dis-continuous crystallographic sequence of anodic-oxidative transformations. The silver-to-selenium molar ratio in the as-cast anode and the current density of electrorefining can be used to construct predominance diagrams for both series and, thus, to predict the final bulk “mineralogy” of the slimes. Although totally incorrect in detail, these bulk data are sufficiently accurate to provide explanations for several processing problems which have been experienced by Kidd Creek Division, Falconbridge Ltd., in its commercial tankhouse. They form the basis for a computer model which predicts final cathode quality from chemical analyses of smelter feed.

  16. Copper metallurgy at the crossroads

    Directory of Open Access Journals (Sweden)

    Habashi F.

    2007-01-01

    Full Text Available Copper technology changed from the vertical to the horizontal furnace and from the roast reaction to converting towards the end of the last century. However, the horizontal furnace proved to be an inefficient and polluting reactor. As a result many attempts were made to replace it. In the past 50 years new successful melting processes were introduced on an industrial scale that were more energy efficient and less polluting. In addition, smelting and converting were conducted in a single reactor in which the concentrate was fed and the raw copper was produced. The standing problem in many countries, however, is marketing 3 tonnes of sulfuric acid per tonne of copper produced as well as emitting large amounts of excess SO2 in the atmosphere. Pressure hydrometallurgy offers the possibility of liberating the copper industry from SO2 problem. Heap leaching technology has become a gigantic operation. Combined with solvent extraction and electrowinning it contributes today to about 20% of copper production and is expected to grow. Pressure leaching offers the possibility of liberating the copper industry from SO2 problem. The technology is over hundred years old. It is applied for leaching a variety of ores and concentrates. Hydrothermal oxidation of sulfide concentrates has the enormous advantage of producing elemental sulfur, hence solving the SO2 and sulfuric acid problems found in smelters. Precipitation of metals such as nickel and cobalt under hydrothermal conditions has been used for over 50 years. It has the advantage of a compact plant but the disadvantage of producing ammonium sulfate as a co-product. In case of copper, however, precipitation takes place without the need of neutralizing the acid, which is a great advantage and could be an excellent substitute for electrowinning which is energy intensive and occupies extensive space. Recent advances in the engineering aspects of pressure equipment design open the door widely for increased

  17. Metal contamination in wildlife living near two zinc smelters

    Science.gov (United States)

    Beyer, W.N.; Pattee, O.H.; Sileo, L.; Hoffman, D.J.; Mulhern, B.M.

    1985-01-01

    Wildlife in an oak forest on Blue Mountain was studied 10 km upwind (Bake Oven Knob site) and 2 km downwind (Palmerton site) of two zinc smelters in eastern Pennsylvania, USA. Previous studies at sites near these smelters had shown changes in populations of soil microflora, lichens, green plants and litter-inhabiting arthropods. The 02 soil litter horizon at Palmerton was heavily contaminated with Pb (2700 mg kg-1), Zn (24000 mg kg-1), and Cd (710 mg kg-1), and to a lesser extent with Cu (440 mg kg-1). Various kinds of invertebrates (earthworms, slugs and millipedes) that feed on soil litter or soil organic matter were rare at, or absent from, the Palmerton site. Those collected at Bake Oven Knob tended to have much higher concentrations of metals than did other invertebrates. Frogs, toads and salamanders were very rare at, or absent from, the Palmerton site, but were present at Bake Oven Knob and at other sites on Blue Mountain farther from the smelters. Metal concentrations (dry wt) in different organisms from Palmerton were compared. Concentrations of Pb were highest in shrews (110 mg kg-1), followed by songbirds (56 mg kg-1), leaves (21 mg kg-1), mice (17 mg kg-1), carrion insects (14 mg kg-1), berries (4.0 mg kg-1), moths (4,3 mg kg-1) and fungi (3.7 mg kg-1). Concentrations of Cd, in contrast, were highest in carrion insects (25 mg kg-1 ),followed by fungi (9.8 mg kg-1), leaves (8.1 mg kg-1), shrews (7.3 mg kg-I), moths (4.9 mg kg-1), mice (2.6 mg kg -1), songbirds (2.5 mg kg -1) and berries (1.2 mg kg-1). Concentrations of Zn and Cu tended to be highest in the same organisms that had the highest concentrations of Cd. Only a small proportion of the metals in the soil became incorporated into plant foliage, and much of the metal contamination detected in the biota probably came from aerial deposition. The mice from both sites seemed to be healthy. Shrews had higher concentrations of metals than did mice, and one shrew showed evidence of Pb poisoning; its red

  18. Economic cost of electricity sold to new aluminium smelters

    International Nuclear Information System (INIS)

    Belanger, G.; Bernard, J.T.

    2008-01-01

    Low cost electricity was a key factor for establishing an aluminium industry in Quebec. Smelters in the province use 50 terawatt hours of electricity per year, which represents 25 per cent of the total consumed in Quebec. This article assessed the profitability of new industrial projects that require large quantities of electricity at a time when the cost of new power plants is increasing. However, electricity is being sold below cost and the difference is subsidized by the government. The investment is justified by the government because these new projects create high paying jobs. The authors presented cases of 2 new aluminium plants, and concluded that they represented a very high economic cost for the province. 1 tab

  19. Arsenic in industrial waste water from copper production technological process

    Directory of Open Access Journals (Sweden)

    Biljana Jovanović

    2013-12-01

    Full Text Available Investigation of arsenic in industrial waste water is of a great importance for environment. Discharge of untreated waste water from a copper production process results in serious pollution of surface water, which directly affects flora and fauna, as well as humans. There is a need for efficient and environmentally acceptable treament of waste waters containing heavy metals and arsenic. The paper presents an analyisis of the waste water from The Copper Smelter which is discharged into the Bor river. The expected arsenic content in treated waste water after using HDS procedure is also presented.

  20. More evidence of unpublished industry studies of lead smelter/refinery workers

    Science.gov (United States)

    2015-01-01

    Background Lead smelter/refinery workers in the US have had significant exposure to lead and are an important occupational group to study to understand the health effects of chronic lead exposure in adults. Recent research found evidence that studies of lead smelter/refinery workers have been conducted but not published. This paper presents further evidence for this contention. Objectives To present further evidence of industry conducted, unpublished epidemiologic studies of lead smelter/refinery workers and health outcomes. Methods Historical research relying on primary sources such as internal industry documents and published studies. Results ASARCO smelter/refinery workers were studied in the early 1980s and found to have increased risk of lung cancer and stroke in one study, but not in another. Conclusions Because occupational lead exposure is an on-going concern for US and overseas workers, all epidemiologic studies should be made available to evaluate and update occupational health and safety standards. PMID:26070220

  1. COPPER CABLE RECYCLING TECHNOLOGY

    International Nuclear Information System (INIS)

    Chelsea Hubbard

    2001-01-01

    The United States Department of Energy (DOE) continually seeks safer and more cost-effective technologies for use in deactivation and decommissioning (D and D) of nuclear facilities. The Deactivation and Decommissioning Focus Area (DDFA) of the DOE's Office of Science and Technology (OST) sponsors large-scale demonstration and deployment projects (LSDDPs). At these LSDDPs, developers and vendors of improved or innovative technologies showcase products that are potentially beneficial to the DOE's projects and to others in the D and D community. Benefits sought include decreased health and safety risks to personnel and the environment, increased productivity, and decreased costs of operation. The Idaho National Engineering and Environmental Laboratory (INEEL) generated a list of statements defining specific needs and problems where improved technology could be incorporated into ongoing D and D tasks. One such need is to reduce the volume of waste copper wire and cable generated by D and D. Deactivation and decommissioning activities of nuclear facilities generates hundreds of tons of contaminated copper cable, which are sent to radioactive waste disposal sites. The Copper Cable Recycling Technology separates the clean copper from contaminated insulation and dust materials in these cables. The recovered copper can then be reclaimed and, more importantly, landfill disposal volumes can be reduced. The existing baseline technology for disposing radioactively contaminated cables is to package the cables in wooden storage boxes and dispose of the cables in radioactive waste disposal sites. The Copper Cable Recycling Technology is applicable to facility decommissioning projects at many Department of Energy (DOE) nuclear facilities and commercial nuclear power plants undergoing decommissioning activities. The INEEL Copper Cable Recycling Technology Demonstration investigated the effectiveness and efficiency to recycle 13.5 tons of copper cable. To determine the effectiveness

  2. Antimony distribution and environmental mobility at an historic antimony smelter site, New Zealand

    International Nuclear Information System (INIS)

    Wilson, N.J.; Craw, D.; Hunter, K.

    2004-01-01

    A historic antimony smelter site at Endeavour Inlet, New Zealand has smelter residues with up to 17 wt.% antimony. Residues include coarse tailings (cm scale particles, poorly sorted), sand tailings (well sorted) and smelter slag (blocks up to 30 cm across). All of this material has oxidised to some degree over the ca. 100 years since the site was abandoned. Oxidation has resulted in acidification of the residues down to pH 2-5. Smelter slag contains pyrrhotite (FeS) and metallic antimony, and oxidation is restricted to surfaces only. The coarse tailings are the most oxidised, and few sulfide grains persist. Unoxidised sand tailings contain 10-20 vol.% stibnite (Sb 2 S 3 ) containing up to 5% As, with subordinate arsenopyrite (FeAsS), and minor pyrite (FeS 2 ). The sand tailings are variably oxidised on a scale of 2-10 cm, but original depositional layering is preserved during oxidation and formation of senarmontite (Sb 2 O 3 ). Oxidation of sand tailings has resulted in localised mobility of both Sb and As on the cm scale, resulting in redistribution of these metalloids with iron oxyhydroxide around sand grain boundaries. Experiments demonstrate that Sb mobility decreases with time on a scale of days. Attenuation of both As and Sb occurs due to adsorption on to iron oxyhydroxides which are formed during oxidation of the smelter residues. There is no detectable loss of Sb or As from the smelter site into the adjacent river, <50 m away, which has elevated Sb (ca. 20 μg/l) and As (ca. 7 μg /l) from mineralised rocks upstream. Despite the high concentrations of Sb and As in the smelter residues, these metalloids are not being released into the environment. - High levels of antimony in primitive smelter soils remain largely immobile on the metre scale

  3. Lead identification in soil surrounding a used lead acid battery smelter area in Banten, Indonesia

    International Nuclear Information System (INIS)

    Adventini, N; Santoso, M; Lestiani, D D; Syahfitri, W Y N; Rixson, L

    2017-01-01

    A used lead acid battery smelter generates particulates containing lead that can contaminate the surrounding environment area. Lead is a heavy metal which is harmful to health if it enters the human body through soil, air, or water. An identification of lead in soil samples surrounding formal and informal used lead acid battery smelters area in Banten, Indonesia using EDXRF has been carried out. The EDXRF accuracy and precision evaluated from marine sediment IAEA 457 gave a good agreement to the certified value. A number of 16 soil samples from formal and informal areas and 2 soil samples from control area were taken from surface and subsurface soils. The highest lead concentrations from both lead smelter were approximately 9 folds and 11 folds higher than the reference and control samples. The assessment of lead contamination in soils described in C f index was in category: moderately and strongly polluted by lead for formal and informal lead smelter. Daily lead intake of children in this study from all sites had exceeded the recommended dietary allowance. The HI values for adults and children living near both lead smelter areas were greater than the value of safety threshold 1. This study finding confirmed that there is a potential health risk for inhabitants surrounding the used lead acid battery smelter areas in Banten, Indonesia. (paper)

  4. Cometary Dust

    Science.gov (United States)

    Levasseur-Regourd, Anny-Chantal; Agarwal, Jessica; Cottin, Hervé; Engrand, Cécile; Flynn, George; Fulle, Marco; Gombosi, Tamas; Langevin, Yves; Lasue, Jérémie; Mannel, Thurid; Merouane, Sihane; Poch, Olivier; Thomas, Nicolas; Westphal, Andrew

    2018-04-01

    This review presents our understanding of cometary dust at the end of 2017. For decades, insight about the dust ejected by nuclei of comets had stemmed from remote observations from Earth or Earth's orbit, and from flybys, including the samples of dust returned to Earth for laboratory studies by the Stardust return capsule. The long-duration Rosetta mission has recently provided a huge and unique amount of data, obtained using numerous instruments, including innovative dust instruments, over a wide range of distances from the Sun and from the nucleus. The diverse approaches available to study dust in comets, together with the related theoretical and experimental studies, provide evidence of the composition and physical properties of dust particles, e.g., the presence of a large fraction of carbon in macromolecules, and of aggregates on a wide range of scales. The results have opened vivid discussions on the variety of dust-release processes and on the diversity of dust properties in comets, as well as on the formation of cometary dust, and on its presence in the near-Earth interplanetary medium. These discussions stress the significance of future explorations as a way to decipher the formation and evolution of our Solar System.

  5. Immobilization of copper flotation waste using red mud and clinoptilolite.

    Science.gov (United States)

    Coruh, Semra

    2008-10-01

    The flash smelting process has been used in the copper industry for a number of years and has replaced most of the reverberatory applications, known as conventional copper smelting processes. Copper smelters produce large amounts of copper slag or copper flotation waste and the dumping of these quantities of copper slag causes economic, environmental and space problems. The aim of this study was to perform a laboratory investigation to assess the feasibility of immobilizing the heavy metals contained in copper flotation waste. For this purpose, samples of copper flotation waste were immobilized with relatively small proportions of red mud and large proportions of clinoptilolite. The results of laboratory leaching demonstrate that addition of red mud and clinoptilolite to the copper flotation waste drastically reduced the heavy metal content in the effluent and the red mud performed better than clinoptilolite. This study also compared the leaching behaviour of metals in copper flotation waste by short-time extraction tests such as the toxicity characteristic leaching procedure (TCLP), deionized water (DI) and field leach test (FLT). The results of leach tests showed that the results of the FLT and DI methods were close and generally lower than those of the TCLP methods.

  6. Identification of threats to the position of a transport worker in Legnica Copper Smelter and Refinery

    Directory of Open Access Journals (Sweden)

    J. Pietruszka

    2010-04-01

    Full Text Available The paper presents the major issues concerning the assessment of working conditions - harmful and disruptive factors occurring in theselected position of the transport worker at HM Legnica. To assess the risk of occupational hazard two methods have been applied: themethod according to PN-N-18002: 2000 (a 3-step method and Risk Score method. The applied methods were compared and assessedpaying special attention to usefulness and accuracy in carrying out further assessments of test positions in HM Legnica. Additionally, thework carried out in this paper includes detailed analysis of: the organization of the work process, the type of instruments and carrying out operations as well as the conditions of the working environment. The most important threats were identified. An important element of this work was to make a risk assessment of occupational hazard and give the necessary actions which should be taken to minimize all risks.

  7. Influence of humic substances on enhanced remediation of soil polluted by a copper-nickel smelter

    Science.gov (United States)

    Tregubova, Polina; Turbaevskaya, Valeria; Korneecheva, Mariya; Kupriyanova, Yuliya; Koptsik, Galina

    2017-04-01

    The problem of technogenic contamination through the anthropogenic activity is quite urgent nowadays. Long-term air pollution with sulphur dioxide and heavy metals (HM) by injuring vegetation and inhibition of plant and soil microorganisms growth and activity causes appearance of the barren areas - highly damaged eroded ecosystems requiring remediation. There are a lot of remediation ways, but an appropriate restoration method, which does not expensive, does not demand special technical support and corresponds to the natural conditions of soil development is still open to question. We suggest application of exogenous humic substances as the possible environmentally friendly solution of HM toxicity problem and soil health restoration. Using of humates can result in the improvement of soil properties, localization of contamination by decreasing of HM mobility and bioavailability through binding them in relatively immobile complexes, and in stabilization of organic pool. But practice of scientific society as well as our previous investigations demonstrates ambiguous influence of exogenic humic substances on the behavior of HM depending on origin, doses, molecular weight of organic matter and state of microorganisms. In this research we have provided series of short-term (45 days) experiments dedicated to the evaluation of suitable doses of humates of different origin - coal and peat - inoculated by nitrogen fixers and mycorhizae-forming fungi in comparison with lime and NPK-fertilizer on the properties of contaminated soil and mobility of HM. The object of investigation was Al-Fe-humus abrazems from the vicinity of mining-and-metallurgical integrated work located in the Kola Peninsula, Russia. This soil is characterized by the absence of vegetation, complete loss of the organic horizon in result of the erosion processes, low pH (pH H2O 4.1-5.0), low exchangeable acidity (0.8-1.6 cmolc/kg), and depletion of organic mater (content of total carbon is 0.3-0.5%). The main pollutants are Ni and Cu. The efficiency of the proposed method was estimated by state of test-culture, native for the object in undisturbed conditions, and by the dynamics of microbiological activity (measurements was taken during the whole time of experiment). Experiments were provided in the climatic chamber in typical for summer period in the Kola sub-Arctic region conditions. The obtained data show that peat-humates in chosen doses without combination with lime and NPK-fertilizer have no influence on pH, HM mobility, dissolved organic carbon concentrations and microbiological activity, but favorable for test-culture growing. Coal-humates application in chosen doses raises pH to 5.5-6.0, decreases HM mobility (from 4 mg/kg and 12 mg/kg to 1 mg/kg and 2 mg/kg for Ni and Cu accordingly) , does not require lime application and has positive influence on test-culture growing and microbiological activity. Inoculation of humates by nitrogen fixers has no effect while mycorhizae-forming fungi positively work in combination with coal-humates and cause development of root system of test-culture. Promising results obtained in short-term experiments should be supported by further investigations.

  8. Electron beam irradiation of simulated diluted sulfurous off-gases from copper smelters

    International Nuclear Information System (INIS)

    Villanueva, L.; Ahumada, L.; Chmielewski, A.G.; Zimek, Z.; Bulka, S.; Licki, J.

    1998-01-01

    An experimental work for the verification of potential use of electron-beam irradiation processing for S O 2 removal from reduced-S O 2 -strength gases, between 1,000 and 10,000 ppm, was conducted in a laboratory unit equipped with a multi-purpose electron accelerator working with beam energy of 800 keV. During experimental tests performed, influence of different operating parameters on the overall S O 2 removal process was established. Tests were conducted under two main conditions, using only electron beam irradiation and using electron beam irradiation plus ammonia injection. Tests results proved the technical feasibility to move S O 2 from off-gases under working experimental conditions, i.e., S O 2 removal is achieved under the two modes of operation. When using only electron beam irradiation S O 2 removal efficiencies found were rather low, up to 40%, but in the case of using electron beam irradiation in conjunction with ammonia injection, it was found that S O 2 removal efficiency raises up to 85% under experimental conditions. (author)

  9. Electrochemical peroxidation as a tool to remove arsenic and copper from smelter wastewater

    DEFF Research Database (Denmark)

    Gutiérrez, Claudia; Hansen, Henrik K.; Nuñez, Patricio

    2010-01-01

    Electrochemical peroxidation (ECP) is a method that recently has been applied in the treatment of heavy metal polluted wastewater. This method is based on the anodic dissolution of iron to ferrous ions that reacts with H2O2 to produce tiny particles of ferric oxides. These oxides adsorb metals ef...

  10. Isotopically constrained lead sources in fugitive dust from unsurfaced roads in the southeast Missouri mining district

    Science.gov (United States)

    Witt, Emitt C.; Pribil, Michael; Hogan, John P; Wronkiewicz, David

    2016-01-01

    The isotopic composition of lead (Pb) in fugitive dust suspended by a vehicle from 13 unsurfaced roads in Missouri was measured to identify the source of Pb within an established long-term mining area. A three end-member model using 207Pb/206Pb and concentration as tracers resulted in fugitive dust samples plotting in the mixing field of well characterized heterogeneous end members. End members selected for this investigation include the 207Pb/206Pb for 1) a Pb-mixture representing mine tailings, 2) aerosol Pb-impacted soils within close proximity to the Buick secondary recycling smelter, and 3) an average of soils, rock cores and drill cuttings representing the background conditions. Aqua regia total concentrations and 207Pb/206Pb of mining area dust suggest that 35.4–84.3% of the source Pb in dust is associated with the mine tailings mixture, 9.1–52.7% is associated with the smelter mixture, and 0–21.6% is associated with background materials. Isotope ratios varied minimally within the operational phases of sequential extraction suggesting that mixing of all three Pb mixtures occurs throughout. Labile forms of Pb were attributed to all three end members. The extractable carbonate phase had as much as 96.6% of the total concentration associated with mine tailings, 51.8% associated with smelter deposition, and 34.2% with background. The next most labile geochemical phase (Fe + Mn Oxides) showed similar results with as much as 85.3% associated with mine tailings, 56.8% associated with smelter deposition, and 4.2% associated with the background soil.

  11. Stability and leaching of cobalt smelter fly ash

    DEFF Research Database (Denmark)

    Vítková, Martina; Hyks, Jiri; Ettler, Vojtěch

    2013-01-01

    The leaching behaviour of fly ash from a Co smelter situated in the Zambian Copperbelt was studied as a function of pH (5–12) using the pH-static leaching test (CEN/TS 14997). Various experimental time intervals (48h and 168h) were evaluated. The leaching results were combined with the ORCHESTRA...... modelling framework and a detailed mineralogical investigation was performed on the original FA and leached solid residues. The largest amounts of Co, Cu, Pb and Zn were leached at pH 5, generally with the lowest concentrations between pH 9 and 11 and slightly increased concentrations at pH 12. For most...... detected using SEM/EDS and/or TEM/EDS. The leaching of metals was mainly attributed to the dissolution of metallic particles. Partial dissolution of silicate and glass fractions was assumed to significantly influence the release of Ca, Mg, Fe, K, Al and Si as well as Cu, Co and Zn. The formation of illite...

  12. Alcan Kitimat smelter modernization project remedial action scheme functional requirements

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-09-09

    This paper identified remedial actions for reducing islanding and voltage collapse at the Alcan Kitimat smelter modernization project. The study was conducted after an earlier study indicated that the proposed project significantly increased electricity loads and stresses on Alcan's power system. Remedial actions included shedding the appropriate number of Kemano (KMO) generators; reducing Kitimat potline loads by de-saturating saturable reactors and lowering tap changers; and shedding potlines to preserve the Kitimat auxiliary load and facilitate power restoration. Power flow and transient stability studies were conducted to evaluate the impact of the remedial actions on the KMO generators and the transmission system. Results showed that fast load reduction improved power system response. Load reduction by changing the converter transformer tap reduced significant amounts of loads, but was too slow to be effective during fast voltage collapse. The study showed that although the remedial action scheme (RAS) reduced the impact of various contingencies on the Alcan system, performance was degraded due to the significant load increase. Fast load shedding capability was also reduced. It was concluded that further research is needed to develop and implement the RAS. 3 tabs., 7 figs.

  13. Selective Sulfidation of Lead Smelter Slag with Sulfur

    Science.gov (United States)

    Han, Junwei; Liu, Wei; Wang, Dawei; Jiao, Fen; Qin, Wenqing

    2016-02-01

    The selective sulfidation of lead smelter slag with sulfur was studied. The effects of temperature, sulfur dosage, carbon, and Na salts additions were investigated based on thermodynamic calculation. The results indicated that more than 96 pct of zinc in the slag could be converted into sulfides. Increasing temperature, sulfur dosage, or Na salts dosage was conducive to the sulfidation of the zinc oxides in the slag. High temperature and excess Na salts would result in the more consumption of carbon and sulfur. Carbon addition not only promoted the selective sulfidation but reduced the sulfur dosage and eliminated the generation of SO2. Iron oxides had a buffering role on the sulfur efficient utilization. The transformation of sphalerite to wurtzite was feasible under reducing condition at high temperature, especially above 1273 K (1000 °C). The growth of ZnS particles largely depended upon the roasting temperature. They were significantly increased when the temperature was above 1273 K (1000 °C), which was attributed to the formation of a liquid phase.

  14. Allergies, asthma, and dust

    Science.gov (United States)

    Reactive airway disease - dust; Bronchial asthma - dust; Triggers - dust ... Things that make allergies or asthma worse are called triggers. Dust is a common trigger. When your asthma or allergies become worse due to dust, you are ...

  15. Dust deposit in recirculation regions

    International Nuclear Information System (INIS)

    Griemert, R.

    1985-03-01

    The present report shows investigations, which have been carried out in a closed duct at forward and backward facing steps. Distribution of fluid velocity and fluid fluctuations in and normal to main flow direction as well as the distribution of Reynolds shear stress have been measured. The mass transfer downstream of a backward facing step has been investigated as well. By using graphite-, copper-, tin- and rubber dust, conditions of deposition have been defined experimentally. A serie of photos shows the filling of a recirculation region downstream of a backward facing step with graphite dust. The present investigations allow to avoid deposition of dust in recirculation regions by selecting the fluid numbers in an appropriate way. (orig.) [de

  16. Generic assessment of radiation exposures to workers in a portable smelter and to the surrounding population

    International Nuclear Information System (INIS)

    Randolph, M.L.; Watson, A.P.; O'Donnell, F.R.

    1978-10-01

    A scenario for operation of a proposed portable smelter has been developed by National Lead Company of Ohio to recycle radioactively contaminated ferrous scrap arising from modifications at nuclear facilities of the Department of Energy. The current generic study complements that work by developing tables of radiation dose conversion factors for estimation of external whole-body doses and 50-year whole-body internal dose commitments to routine workers in the smelter and to the public within 50 miles of the smelter. Applications of the tables to specific cases require site-specific source terms consisting of amounts of radionuclides present in scrap metal, separation efficiency for radionuclides, concentration of contaminated airborne particulates, ingested amount of contaminated material, and amount of metal released through the stack. Equations relating doses to tabular values and these source terms are developed, and hypothetical sample calculations are given. Assumptions, approximations, and limitations of the methods are discussed as well as nonroutine operations and nonradioactive hazards

  17. Copper hypersensitivity

    DEFF Research Database (Denmark)

    Fage, Simon W; Faurschou, Annesofie; Thyssen, Jacob P

    2014-01-01

    hypersensitivity, a database search of PubMed was performed with the following terms: copper, dermatitis, allergic contact dermatitis, contact hypersensitivity, contact sensitization, contact allergy, patch test, dental, IUD, epidemiology, clinical, and experimental. Human exposure to copper is relatively common...

  18. Heavy metals in white-tailed deer living near a zinc smelter in Pennsylvania

    Science.gov (United States)

    Sileo, Louis; Beyer, W. Nelson

    1985-01-01

    White-tailed deer (Odocoileus virginianus (Zimmermann)) shot within 20 km of the zinc smelters in the Palmerton, Pennsylvania area contained extremely high renal concentrations of cadmium (372 ppm dry weight (dw)) and zinc (600 ppm dw). The deer with the highest renal zinc concentration was shot 4 km from the smelters and had joint lesions similar to those seen in zinc-poisoned horses from the same area. The highest concentrations of lead in both hard and soft tissues were relatively low, 10.9 ppm dw in a sample of teeth, 17.4 ppm dw in a metacarpus, and 4.9 ppm dw in a kidney.

  19. Copper in Surface Soil of Veles Region, Macedonia

    International Nuclear Information System (INIS)

    Panchevski, Zlatko; Stafilov, Trajche; Frontasyeva, Marina V.

    2006-01-01

    For the first time a systematic study of copper distribution in surface soil over of the Veles region, known for its lead and zinc industrial activity, was undertaken. A total of 201 soil samples were collected according to a dense net (0.5 km) in urban and less dense net (1 km) in rural areas. Copper was determined by flame atomic absorption spectrometry (FAAS) using microwave digestion technique with two different types of solvents: aqua regia (HCI and HNO 3 )and the mixture of strong acids (HNO 3 , HCI, and HF). So far the same soil samples were subjected to reactor non-destructive multi-element instrumental neutron activation analysis (INAA), it served as a reference analytical technique for bulk copper determination. The results obtained by two methods of FAAS and INAA are discussed. GIS technology was applied to reveal the areas most affected by copper contamination. It was found that the content of copper in soil samples around the lead and zinc smelter plant is the highest and reaches 1800 mg/kg. Copper content in surface soil all around the town of Veles exceeds maximum permissible level for urban surface soil. Elevated copper content in some rural areas of the Veles region most likely could be explained through using copper containing fungicides for agricultural needs. (Author)

  20. Investigation of possibility of recovery nonferrous metals and producing building materials from copper-nickel smelterslag

    Directory of Open Access Journals (Sweden)

    Svetlov A.V.

    2015-06-01

    Full Text Available Pelletized slag of copper-nickel smelter ("Pechenganikel" combine, "Kola MMC" JSC has been investigated as a potential technogenic deposit. It has been shown that nonferrous metals can be re-extracted from slag using flotation. The work presents the results of laboratory simulation of heap leaching of non-ferrous metals. Ceramic building materials from slag-based feed have been produced and their main properties have been studied

  1. Metal pollution around an iron smelter complex in northern Norway at different modes of operation

    International Nuclear Information System (INIS)

    Steinnes, E.; Sjoebakk, T.E.; Frontas'eva, M.V.; Varskog, P.

    2003-01-01

    The moss biomonitoring technique was employed to study the atmospheric deposition in and around the town of Mo i Rana, northern Norway, before and after closing an iron smelter and establishing alternative ferrous metal industries. Samples of Hylocomium splendens were collected from the same sites in 1989 and 1993. A combination of instrumental neutron activation analysis (INAA) and atomic absorption spectrometry was used to obtain data for 38 elements in these moss samples, and the analytical data were subjected to factor analysis. In general, the deposition was higher when the iron smelter was still in operation, in particular for Fe and for many elements normally associated with crustal matter. For Cr there was a substantially increased deposition due to the operation of a new ferrochrome smelter. Also for Ni and Au an increased deposition was observed, whereas for metals such as Mn, Co, Ag, Sb, and W there was no appreciable change. INAA proved to be a powerful tool for this kind of study. The regional distribution of pollutants was strongly dependent on the local topography. Samples of natural surface soils collected simultaneously with the first moss series showed clear signs of contamination with a number of metals from atmospheric deposition. The approach described in this work could be advantageously used to study atmospheric deposition of heavy metals around iron smelters in Russia and elsewhere

  2. 40 CFR Appendix A to Part 57 - Primary Nonferrous Smelter Order (NSO) Application

    Science.gov (United States)

    2010-07-01

    .... Background information on the firm's organizational structure and its associated accounting and financial.... Interim control waiver requests based on the smelter's projected inability to earn adequate income after installation of interim pollution control equipment will be subject to the permanent waiver test. 1.2.3...

  3. Modelling assessment of regional groundwater contamination due to historic smelter emissions of heavy metals

    NARCIS (Netherlands)

    Grift, B. van der; Griffioen, J.

    2008-01-01

    Historic emissions from ore smelters typically cause regional soil contamination. We developed a modelling approach to assess the impact of such contamination on groundwater and surface water load, coupling unsaturated zone leaching modelling with 3D groundwater transport modelling. Both historic

  4. Controls on Metal Leaching from Secondary Pb Smelter Air-Pollution-Control Residues

    Czech Academy of Sciences Publication Activity Database

    Ettler, V.; Šebek, O.; Grygar, Tomáš; Klementová, Mariana; Bezdička, Petr

    2008-01-01

    Roč. 42, č. 21 (2008), s. 7878-7884 ISSN 0013-936X Institutional research plan: CEZ:AV0Z40320502 Keywords : lead smelter * waste incineration * soils Subject RIV: CA - Inorganic Chemistry Impact factor: 4.458, year: 2008

  5. Influence of smelter fumes on the growth of white pine in the Sudbury region

    Energy Technology Data Exchange (ETDEWEB)

    Linzon, S N

    1958-01-01

    An additional study was started in 1949 to determine the effects on neighboring white pine forests of sulfur fumes discharged from large smelters operated by two mining companies in the Sudbury district of Ontario. A number of sample timber areas, near to, farther removed, and remote from the sources of the fumes, were placed under observation. Approximately 7000 white pine trees in the vigorous age class of 50 to 90 years had been examined annually by 1954. Foliage on the white pine trees located less than 25 miles northeast of Sudbury showed more extensive injuries every year than foliage on trees located at greater distances from the smelters. Studies of diameter increment showed that there was a gradual decline in the annual growth of white pine in the areas near to the smelters, whereas a constant pattern was maintained in areas located farther from the sources of smoke. Further, in the areas close to the smelters, the volume of white pine lost through excessive tree mortality of all crown class sizes exceeded the volume added by the surviving trees. However, at distances beyond 25 to 30 miles northeast of Sudbury in the direction of the prevailing wind the condition of white pine improved remarkably. It is indicated that the combination of concentration frequency, and duration of atmospheric sulfur dioxide visitations has here declined to a threshold value for the inhibition of growth of white pine. 25 references, 25 figures, 23 tables.

  6. Socio-demographic characteristics of traditional gold smelters in Makassar, south Sulawesi, Indonesia

    Science.gov (United States)

    Habo Abbas, Hasriwiani; Sakakibara, Masayuki; Hakim Arma, Lukmanul; Hardi Yanti, Iva

    2017-06-01

    The traditional gold smelting in Makassar, South Sulawesi, Indonesia, is an informal work with the manufacture of gold jewelry as the core activity. Stages of the gold processing include panning, smelting, and refining with mercury. In the current study, we used a social demography analysis to classify the traditional gold smelter workers in this region. Data (e.g. sex, age, education level, time working, and income) were obtained from a questionnaire survey of 58 smelter workers in the Wajo and Tallo Sub-districts of Makassar. Results showed that 84.5% of the workers were males aged from 21 to 50 years with on the average 15 year of work. The gold smelter were last educated in elementary school (31.0%), junior high school (36.2%), and senior high school (27.6%) levels whereas 5.1% have no education. We found that the monthly income of an un-skilled worker was ∼Rp. 2 million (USD 147.0) whereas that of a skilled worker was between Rp. 2.5 million (USD 183.76) and Rp. 5 million (USD 367.51). An owner could earn over Rp. 5 million (USD 367.51) per month. The result suggested that the traditional gold smelting used rudimentary technique and attracted young people with a low education level. This business continues to exist because the worker earn sufficient income and may higher through mastering gold smelter proficiency.

  7. Concentrations of arsenic, copper, cobalt, lead and zinc in cassava (Manihot esculenta Crantz) growing on uncontaminated and contaminated soils of the Zambian Copperbelt

    Science.gov (United States)

    Kříbek, B.; Majer, V.; Knésl, I.; Nyambe, I.; Mihaljevič, M.; Ettler, V.; Sracek, O.

    2014-11-01

    The concentrations of arsenic (As), copper (Cu), cobalt (Co), lead (Pb) and zinc (Zn) in washed leaves and washed and peeled tubers of cassava (Manihot esculenta Crantz, Euphorbiaceae) growing on uncontaminated and contaminated soils of the Zambian Copperbelt mining district have been analyzed. An enrichment index (EI) was used to distinguish between contaminated and uncontaminated areas. This index is based on the average ratio of the actual and median concentration of the given contaminants (As, Co, Cu, mercury (Hg), Pb and Zn) in topsoil. The concentrations of copper in cassava leaves growing on contaminated soils reach as much as 612 mg kg-1 Cu (total dry weight [dw]). Concentrations of copper in leaves of cassava growing on uncontaminated soils are much lower (up to 252 mg kg-1 Cu dw). The concentrations of Co (up to 78 mg kg-1 dw), As (up to 8 mg kg-1 dw) and Zn (up to 231 mg kg-1 dw) in leaves of cassava growing on contaminated soils are higher compared with uncontaminated areas, while the concentrations of lead do not differ significantly. The concentrations of analyzed chemical elements in the tubers of cassava are much lower than in its leaves with the exception of As. Even in strongly contaminated areas, the concentrations of copper in the leaves and tubers of cassava do not exceed the daily maximum tolerance limit of 0.5 mg kg-1/human body weight (HBW) established by the Joint FAO/WHO Expert Committee on Food Additives (JECFA). The highest tolerable weekly ingestion of 0.025 mg kg-1/HBW for lead and the highest tolerable weekly ingestion of 0.015 mg kg-1/HBW for arsenic are exceeded predominantly in the vicinity of smelters. Therefore, the preliminary assessment of dietary exposure to metals through the consumption of uncooked cassava leaves and tubers has been identified as a moderate hazard to human health. Nevertheless, as the surfaces of leaves are strongly contaminated by metalliferous dust in the polluted areas, there is still a potential hazard

  8. Thyroid function in smelters after long-term exposure to heavy metals; Funkcja tarczycy u hutnikow dlugoletnio narazonych na metale ciezkie

    Energy Technology Data Exchange (ETDEWEB)

    Andrzejak, R.; Antonowicz, J.; Bolanowska, B.; Kabacinska-Knapik, D.; Hebdzinski, L.; Smolik, R. [Przychodnia Przyzakladowa Huty Miedzi `Legnica`, Legnica (Poland)

    1996-12-31

    In the year 1995 in a group of 93 male workers of a copper smelter (mean age = 40.7 years, exposure time = 8.5 years) following parameters were measured: blood levels of: lead and cadmium; serum levels of copper, zinc, calcium and magnesium-with use of atomic absorption spectrophotometry; FEP -with Piomelli`s method; and T3, T4 and TSH in serum with radioimmunometric method. Mean blood lead level was 38.2 micrograms/dl, and concentrations of other metals and hormones were within norm limits. Mean level of FEP was slightly above norm (FEP = 106.5 micrograms/100 ml E). We found no correlation between investigated hormones (T3, T4 and TSH) and age, length of exposure nor blood lead level. We found a significant inverse correlation between FEP and TSH (r = -0.207; p < 0.047). This correlation could point to the fact that lead burden (expressed not in the actual blood level but in the FEP concentration) could negatively influence endocrine functions through hypothalamic-pituitary axis. (author). 18 refs, 1 fig., 1 tab.

  9. Effects of zinc smelter emissions on farms and gardens at Palmerton, PA

    Science.gov (United States)

    Chaney, R.L.; Beyer, W.N.; Gifford, C.H.; Sileo, L.

    1988-01-01

    In 1979, before the primary Zn smelter at Palmerton was closed due to excessive Zn and Cd emissions and change in the price of Zn, we were contacted by a local veterinarian regarding death of foals (young horses) on farms near the smelter. To examine whether Zn or Cd contamination of forage or soils could be providing potentially toxic levels of Zn or other elements in the diets of foals, we measured metals in forages, soils, and feces of grazing livestock on two farms near Palmerton. The farms were about 2.5 and about 10 km northeast of the East stack. Soils, forages, and feces were greatly increased in Zn and Cd. Soil, forage, and fecal Zn were near 1000 mg/kg and Cd, 10-20 mg/kg at farm A (2.5 km) compared to normal background levels of 43 mg Zn and 0.2 mg Cd/kg, respectively. Liver and kidney of cattle raised on Farm A were increased in Zn and Cd, indicating that at least part of the Zn and Cd in smelter contaminated forages was bioavailable. During the farm sampling, we obtained soil from one garden in Palmerton within 200 m of the primary (West) smelter. The Borough surrounds the smelter facility in a valley. Because soil Cd was near 100 mg/kg, we sampled garden soils and vegetables from over 40 gardens in 6 randomly selected blocks and in rural areas at different distances from the smelter during September, 1980. All homes were contacted on each sampled block. Nearly all homes had some garden, while at least 2 appeared to grow over 50% of their annual vegetable and potato consumption. Palmerton garden soils averaged 76 mg Cd/kg and 5830 mg Zn/kg. Gardeners had been taught to add limestone and organic fertilizers to counteract yield reduction and chlorosis due to the excessive soil Zn. Gardens with over 5000 mg Zn/kg were nearly allover pH 7, and many were calcareous. Because the smelter had not yet ceased operations in 1980, crops could have been polluted by aerosol Zn and Cd emitted by the smelter. Crop Zn and Cd were extremely high, about 100 times normal

  10. Arsenic exposure levels in relation to different working departments in a copper mining and smelting plant

    Science.gov (United States)

    Sun, Qingshan; Song, Yingli; Liu, Shengnan; Wang, Fei; Zhang, Lin; Xi, Shuhua; Sun, Guifan

    2015-10-01

    The investigation was carried out to evaluate arsenic exposure and the urine metabolite profiles of workers with different working departments, including administration (Group1), copper ore mining (Group2), copper ore grinding (Group3), electrolytic procession (Group4) and copper smelting (Group5) in a Copper mining and processing plant in China. Information about characteristics of each subject was obtained by questionnaire and inorganic arsenic (iAs), monomethylarsonic acid (MMA), dimethylarsinic acid (DMA) in urine were determined. The highest urinary levels of iAs, MMA and DMA all were found in the Group 5. Group 4 workers had a higher iAs% and a lower PMI compared to Group 3. The urinary total As (TAs) levels of 54.7% subjects exceeded 50 μg/g Cr, and the highest percentage (93.3%) was found in Group 5, smelters. The results of the present study indicate that workers in copper production plant indeed exposed to As, especially for smelters and workers of electrolytic process.

  11. The copper losses in the slags from the El Teniente process

    International Nuclear Information System (INIS)

    Imris, I.; Rebolledo, S.; Sanchez, M.; Castro, G.; Achurra, G.; Hernandez, F.

    2000-01-01

    The current El Teniente Pyrometallurgical Process for copper concentrate was commissioned at Caletones Smelter during the period 1988 - 1991 following an intensive research and development program that led to several improvements to the original process developed during the seventies. The Caletones Smelter production capacity is 370,000 tons of cast copper annually related to a concentrate smelting capacity of 1,250,000 tons per year. Several industrial applications of the process, in Chile and abroad, have shown its capability to treat copper concentrates in a wide range of chemical and mineralogical compositions. The main operational parameters that determine the performance of the process are oxygen enriched air flow rate, degree of oxygen enrichment, moisture content of the solid materials processed, molten material levels inside the vessel, frequency of molten materials tapping, bath temperature and copper losses in slags. The copper losses in the slags from the El Teniente Pyrometallurgical Process, predicted by calculation from thermodynamic data, have been compared with those determined by microscopic examination and quantitative electron microprobe analysis of the slag samples and by flotation tests of finely ground slag. (author)

  12. Use of catchment liming for the improvement of drainage water quality from smelter-impacted lands near Coniston, Ontario

    Energy Technology Data Exchange (ETDEWEB)

    Gunn, J.M.; Sein, R.; Keller, B. [Laurentian Univ., Sudbury, ON (Canada) Dept. of Biology

    1999-07-01

    A study was carried out to test whether INCO Ltd.'s aerial land liming program, designed solely for revegetation purposes, was improving water quality from the treated sites in an area affected by air pollution from acidic nickel and copper smelters. A wetland application mehod was tested as a potentially improved technique of drainage water treatment. A summary is included of the results of water quality assessment and bioassay toxicity testing for the experimental catchments during the study period 1991-1997. There were immediate spin-off benefits from the stream monitoring study that were rapidly applied to the larger land reclamation effort. The identified effectivess of the coarse limestone led to testing and adoption of new methods of aerial liming in which finer pelletized materials were used both reducing the application rate and the associated costs. The decline in Cu and Ni during 1991-1994 indicated that the metal contamination of the site was declining even before the first limestone treatment. The occurrence of a brief pulse in metal concentrations immediately after the wetland liming treatments is consistent with an earlier occurrence and supports the hypothesis that liming may temporarily increase metal concentrations in stream water through displacement of metal cations at the soil exchange sites by the added Ca. The presence of acidic groundwater proved to be a confounding factor that reduced the effectiveness of soil and wetland treatments at the site. In spite of surprises, the catchment treatments, particularly the wetland applications, proved to be very effective at improving water quality in much of the catchment stream. 14 refs., 2 figs., 1 tab.

  13. Effective radium concentration in topsoils contaminated by lead and zinc smelters

    Energy Technology Data Exchange (ETDEWEB)

    Girault, Frédéric, E-mail: girault@ipgp.fr [Institut de Physique du Globe de Paris, Sorbonne Paris Cité, Université Paris Diderot, CNRS, Paris, France. (France); Perrier, Frédéric; Poitou, Charles; Isambert, Aude [Institut de Physique du Globe de Paris, Sorbonne Paris Cité, Université Paris Diderot, CNRS, Paris, France. (France); Théveniaut, Hervé; Laperche, Valérie [Bureau de Recherches Géologiques et Minières, Orléans, France. (France); Clozel-Leloup, Blandine [Bureau de Recherches Géologiques et Minières, Villeurbanne, France. (France); Douay, Francis [Laboratoire Génie Civil et géo Environnement, ISA Lille, Lille, France. (France)

    2016-10-01

    Trace elements (TE) are indicative of industrial pollution in soils, but geochemical methods are difficult to implement in contaminated sites with large numbers of samples. Therefore, measurement of soil magnetic susceptibility (MS) has been used to map TE pollutions, albeit with contrasted results in some cases. Effective radium concentration (EC{sub Ra}), product of radium concentration by the emanation factor, can be measured in a cost-effective manner in the laboratory, and could then provide a useful addition. We evaluate this possibility using 186 topsoils sampled over about 783 km{sup 2} around two former lead and zinc smelters in Northern France. The EC{sub Ra} values, obtained from 319 measurements, range from 0.70 ± 0.06 to 12.53 ± 0.49 Bq·kg{sup −1}, and are remarkably organized spatially, away from the smelters, in domains corresponding to geographical units. Lead-contaminated soils, with lead concentrations above 100 mg·kg{sup −1} < 3 km from the smelters, are characterized on average by larger peak EC{sub Ra} values and larger dispersion. At large scales, away from the smelters, spatial variations of EC{sub Ra} correlate well with spatial variations of MS, thus suggesting that, at distance larger than 5 km, variability of MS contains a significant natural component. Larger EC{sub Ra} values are correlated with larger fine fraction and, possibly, mercury concentration. While MS is enhanced in the vicinity of the smelters and is associated with the presence of soft ferrimagnetic minerals such as magnetite, it does not correlate systematically with metal concentrations. When multiple industrial and urban sources are present, EC{sub Ra} mapping, thus, can help in identifying at least part of the natural spatial variability of MS. More generally, this study shows that EC{sub Ra} mapping provides an independent and reliable assessment of the background spatial structure which underlies the structure of a given contamination. Furthermore, EC{sub Ra

  14. Effective radium concentration in topsoils contaminated by lead and zinc smelters

    International Nuclear Information System (INIS)

    Girault, Frédéric; Perrier, Frédéric; Poitou, Charles; Isambert, Aude; Théveniaut, Hervé; Laperche, Valérie; Clozel-Leloup, Blandine; Douay, Francis

    2016-01-01

    Trace elements (TE) are indicative of industrial pollution in soils, but geochemical methods are difficult to implement in contaminated sites with large numbers of samples. Therefore, measurement of soil magnetic susceptibility (MS) has been used to map TE pollutions, albeit with contrasted results in some cases. Effective radium concentration (EC_R_a), product of radium concentration by the emanation factor, can be measured in a cost-effective manner in the laboratory, and could then provide a useful addition. We evaluate this possibility using 186 topsoils sampled over about 783 km"2 around two former lead and zinc smelters in Northern France. The EC_R_a values, obtained from 319 measurements, range from 0.70 ± 0.06 to 12.53 ± 0.49 Bq·kg"−"1, and are remarkably organized spatially, away from the smelters, in domains corresponding to geographical units. Lead-contaminated soils, with lead concentrations above 100 mg·kg"−"1 < 3 km from the smelters, are characterized on average by larger peak EC_R_a values and larger dispersion. At large scales, away from the smelters, spatial variations of EC_R_a correlate well with spatial variations of MS, thus suggesting that, at distance larger than 5 km, variability of MS contains a significant natural component. Larger EC_R_a values are correlated with larger fine fraction and, possibly, mercury concentration. While MS is enhanced in the vicinity of the smelters and is associated with the presence of soft ferrimagnetic minerals such as magnetite, it does not correlate systematically with metal concentrations. When multiple industrial and urban sources are present, EC_R_a mapping, thus, can help in identifying at least part of the natural spatial variability of MS. More generally, this study shows that EC_R_a mapping provides an independent and reliable assessment of the background spatial structure which underlies the structure of a given contamination. Furthermore, EC_R_a may provide a novel index to identify soils

  15. Metal Pollution Around an Iron Smelter Complex in Northern Norway at Different Modes of Operation

    CERN Document Server

    Steinnes, E; Eidhammer-Sjobakk, T; Varskog, P

    2003-01-01

    The moss biomonitoring technique was employed to study the atmospheric deposition in and around the town of Mo i Rana, northern Norway, before and after closing an iron smelter and establishing alternative ferrous metal industries. Samples of Hylocomium splendens were collected from the same sites in 1989 and 1993. A combination of instrumental neutron activation analysis (INAA) and atomic absorption spectrometry was used to obtain data for 38 elements in these moss samples, and the analytical data were subjected to factor analysis. In general, the deposition was higher when the iron smelter was still in operation, in particular for Fe and for many elements normally associated with crustal matter. For Cr there was a substantially increased deposition due to the operation of a new ferrochrome smelter. Also for Ni and Au an increased deposition was observed, whereas for metals such as Mn, Co, Ag, Sb, and W there was no appreciable change. INAA proved to be a powerful tool for this kind of study. The regional di...

  16. Assessment of Fluoride Concentration of Soil and Vegetables in Vicinity of Zinc Smelter, Debari, Udaipur, Rajasthan.

    Science.gov (United States)

    Bhat, Nagesh; Jain, Sandeep; Asawa, Kailash; Tak, Mridula; Shinde, Kushal; Singh, Anukriti; Gandhi, Neha; Gupta, Vivek Vardhan

    2015-10-01

    As of late, natural contamination has stimulated as a reaction of mechanical and other human exercises. In India, with the expanding industrialization, numerous unsafe substances are utilized or are discharged amid generation as cleans, exhaust, vapours and gasses. These substances at last are blended in the earth and causes health hazards. To determine concentration of fluoride in soils and vegetables grown in the vicinity of Zinc Smelter, Debari, Udaipur, Rajasthan. Samples of vegetables and soil were collected from areas situated at 0, 1, 2, 5, and 10 km distance from the zinc smelter, Debari. Three samples of vegetables (i.e. Cabbage, Onion and Tomato) and 3 samples of soil {one sample from the upper layer of soil (i.e. 0 to 20 cm) and one from the deep layer (i.e. 20 - 40 cm)} at each distance were collected. The soil and vegetable samples were sealed in clean polythene bags and transported to the laboratory for analysis. One sample each of water and fertilizer from each distance were also collected. The mean fluoride concentration in the vegetables grown varied between 0.36 ± 0.69 to 0.71 ± 0.90 ppm. The fluoride concentration in fertilizer and water sample from various distances was found to be in the range of 1.4 - 1.5 ppm and 1.8 - 1.9 ppm respectively. The fluoride content of soil and vegetables was found to be higher in places near to the zinc smelter.

  17. Estimating mercury emissions from a zinc smelter in relation to China's mercury control policies

    International Nuclear Information System (INIS)

    Wang, S.X.; Song, J.X.; Li, G.H.; Wu, Y.; Zhang, L.; Wan, Q.; Streets, D.G.; Chin, Conrad K.; Hao, J.M.

    2010-01-01

    Mercury concentrations of flue gas at inlet/outlet of the flue gas cleaning, electrostatic demister, reclaiming tower, acid plant, and mercury contents in zinc concentrate and by-products were measured in a hydrometallurgical zinc smelter. The removal efficiency of flue gas cleaning, electrostatic demister, mercury reclaiming and acid plant was about 17.4%, 30.3%, 87.9% and 97.4% respectively. Flue gas cleaning and electrostatic demister captured 11.7% and 25.3% of the mercury in the zinc concentrate, respectively. The mercury reclaiming tower captured 58.3% of the mercury in the zinc concentrate. About 4.2% of the mercury in the zinc concentrate was captured by the acid plant. Consequently, only 0.8% of the mercury in the zinc concentrate was emitted to the atmosphere. The atmospheric mercury emission factor was 0.5 g t -1 of zinc produced for the tested smelter, indicating that this process offers the potential to effectively reduce mercury emissions from zinc smelting. - Modern scale production equipped with acid plant and Hg reclaiming tower will significantly reduce Hg emissions from zinc smelters in China.

  18. Catchment liming creates recolonization opportunity for sensitive invertebrates in a smelter impacted landscape

    Directory of Open Access Journals (Sweden)

    John M. Gunn

    2016-04-01

    Full Text Available The response of a sensitive indicator species to the effects of catchment liming was assessed in a lake severely impacted by atmospheric emissions from a metal smelter in Sudbury, Canada. The lake chemistry recovered following the closure of the local smelter and major reductions (approximately 95% in acid and metal emissions from other area smelters, leading to recolonization of the lake with fish and other biota. However, the littoral macrobenthos community remain severely impoverished. The catchment liming sustained improved stream water quality for 20 years after the initial aerial treatment and created a littoral zone hot spot for the recolonization of Hyalella azteca. Colonization at delta sites of untreated catchment drainage areas, in the same lake, were low and highly variable, and these sites appeared to be impacted from soil erosion and episodic release of acid and metals. This study demonstrated the need to both reduce air pollutants and to conduct land reclamation in severely damaged watersheds, before lake ecosystems themselves can be fully recovered.

  19. New insight into atmospheric mercury emissions from zinc smelters using mass flow analysis.

    Science.gov (United States)

    Wu, Qingru; Wang, Shuxiao; Hui, Mulin; Wang, Fengyang; Zhang, Lei; Duan, Lei; Luo, Yao

    2015-03-17

    The mercury (Hg) flow paths from three zinc (Zn) smelters indicated that a large quantity of Hg, approximately 38.0-57.0% of the total Hg input, was stored as acid slag in the landfill sites. Approximately 15.0-27.1% of the Hg input was emitted into water or stored as open-dumped slags, and 3.3-14.5% of the Hg input ended in sulfuric acid. Atmospheric Hg emissions, accounting for 1.4-9.6% of the total Hg input, were from both the Zn production and waste disposal processes. Atmospheric Hg emissions from the waste disposal processes accounted for 40.6, 89.6, and 94.6% of the total atmospheric Hg emissions of the three studied smelters, respectively. The Zn production process mainly contributed to oxidized Hg (Hg2+) emissions, whereas the waste disposal process generated mostly elemental Hg (Hg0) emissions. When the emissions from these two processes are considered together, the emission proportion of the Hg2+ mass was 51, 46, and 29% in smelters A, B, and C, respectively. These results indicated that approximately 10.8±5.8 t of atmospheric Hg emissions from the waste disposal process were ignored in recent inventories. Therefore, the total atmospheric Hg emissions from the Zn industry of China should be approximately 50 t.

  20. Lead distribution in soils impacted by a secondary lead smelter: Experimental and modelling approaches

    Energy Technology Data Exchange (ETDEWEB)

    Schneider, Arnaud R., E-mail: arnaud.schneider@univ-reims.fr [GEGENAA, EA 3795, Université de Reims Champagne-Ardenne, SFR Condorcet FR CNRS 3417, 2 esplanade Roland Garros, 51100 Reims (France); Cancès, Benjamin; Ponthieu, Marie [GEGENAA, EA 3795, Université de Reims Champagne-Ardenne, SFR Condorcet FR CNRS 3417, 2 esplanade Roland Garros, 51100 Reims (France); Sobanska, Sophie [Laboratoire de Spectrochimie IR et Raman, UMR-CNRS 8516, Bât. C5 Université de Lille I, 59655 Villeneuve d' Ascq Cedex (France); Benedetti, Marc F. [Institut de Physique du Globe de Paris, Sorbonne Paris Cité, Université Paris Diderot, UMR 7154, CNRS, F-75005 Paris (France); Pourret, Olivier [HydrISE, Institut Polytechnique LaSalle Beauvais, FR-60000 Beauvais (France); Conreux, Alexandra; Calandra, Ivan; Martinet, Blandine; Morvan, Xavier; Gommeaux, Maxime; Marin, Béatrice [GEGENAA, EA 3795, Université de Reims Champagne-Ardenne, SFR Condorcet FR CNRS 3417, 2 esplanade Roland Garros, 51100 Reims (France)

    2016-10-15

    Smelting activities are one of the most common sources of trace elements in the environment. The aim of this study was to determine the lead distribution in upper horizons (0–5 and 5–10 cm) of acidic soils in the vicinity of a lead-acid battery recycling plant in northern France. The combination of chemical methods (sequential extractions), physical methods (Raman microspectroscopy and scanning electron microscopy with an energy dispersive spectrometer) and multi-surface complexation modelling enabled an assessment of the behaviour of Pb. Regardless of the studied soil, none of the Pb-bearing phases commonly identified in similarly polluted environments (e.g., anglesite) were observed. Lead was mainly associated with organic matter and manganese oxides. The association of Pb with these soil constituents can be interpreted as evidence of Pb redistribution in the studied soils following smelter particle deposition. - Highlights: • Lead behavior was studied in smelter impacted soils. • A combination of experimental methods and modelling was employed. • Pb was mainly associated with organic matter and to a lesser degree with Mn oxides. • Pb was redistributed in soils after smelter particle deposition.

  1. Lead distribution in soils impacted by a secondary lead smelter: Experimental and modelling approaches

    International Nuclear Information System (INIS)

    Schneider, Arnaud R.; Cancès, Benjamin; Ponthieu, Marie; Sobanska, Sophie; Benedetti, Marc F.; Pourret, Olivier; Conreux, Alexandra; Calandra, Ivan; Martinet, Blandine; Morvan, Xavier; Gommeaux, Maxime; Marin, Béatrice

    2016-01-01

    Smelting activities are one of the most common sources of trace elements in the environment. The aim of this study was to determine the lead distribution in upper horizons (0–5 and 5–10 cm) of acidic soils in the vicinity of a lead-acid battery recycling plant in northern France. The combination of chemical methods (sequential extractions), physical methods (Raman microspectroscopy and scanning electron microscopy with an energy dispersive spectrometer) and multi-surface complexation modelling enabled an assessment of the behaviour of Pb. Regardless of the studied soil, none of the Pb-bearing phases commonly identified in similarly polluted environments (e.g., anglesite) were observed. Lead was mainly associated with organic matter and manganese oxides. The association of Pb with these soil constituents can be interpreted as evidence of Pb redistribution in the studied soils following smelter particle deposition. - Highlights: • Lead behavior was studied in smelter impacted soils. • A combination of experimental methods and modelling was employed. • Pb was mainly associated with organic matter and to a lesser degree with Mn oxides. • Pb was redistributed in soils after smelter particle deposition.

  2. Copper Test

    Science.gov (United States)

    ... in the arm and/or a 24-hour urine sample is collected. Sometimes a health practitioner performs a liver ... disease , a rare inherited disorder that can lead to excess storage of copper in the liver, brain, and other ...

  3. Dust Removal Technology Demonstration for a Lunar Habitat

    Science.gov (United States)

    Calle, C. I.; Chen, A.; Immer, C. D.; Csonka, M.; Hogue, M. D.; Snyder, S. J.; Rogriquez, M.; Margiotta, D. V.

    2010-01-01

    We have developed an Electrodynamic Dust Shield (EDS), an active dust mitigation technology with applications to solar panels, thermal radiators, optical systems, visors, seals and connectors. This active technology is capable of removing dust and granular material with diameters as large as several hundred microns. In this paper, we report on the development of three types of EDS systems for NASA's Habitat Demonstration Unit (HDU). A transparent EDS 20 cm in diameter with indium tin oxide electrodes on a 0.1 mm-thick polyethylene terephtalate (PET) film was constructed for viewport dust protection. Two opaque EDS systems with copper electrodes on 0.1 mm-thick Kapton were also built to demonstrate dust removal on the doors of the HDU. A lotus coating that minimizes dust adhesion was added to one of the last two EDS systems to demonstrate the effectiveness of the combined systems.

  4. Dust collector

    Energy Technology Data Exchange (ETDEWEB)

    Sahourin, H.

    1988-03-22

    This invention relates to a dust collector or filter which may be used for large volume cleaning air for gases or for separating out industrial byproducts such as wood chips, sawdust, and shavings. It relies on filtration or separation using only a uniquely configured medium. A primary, but not exclusive, purpose of the invention is to enable very large throughput, capable of separating or filtering of gases containing up to three or more tons of byproduct with a minimum pressure-drop across the device. No preliminary cycloning, to remove major particulates is necessary. The collector generally comprises a continuous and integral filter medium which is suspended from a plurality of downwardly extending frames forming a series of separate elements having a triangular cross-section, each element being relatively wide at the top and narrow at the bottom to define, between adjacent elements, a divergent collecting space which is wide at the bottom. 11 figs.

  5. Dust Measurements in Tokamaks

    International Nuclear Information System (INIS)

    Rudakov, D; Yu, J; Boedo, J; Hollmann, E; Krasheninnikov, S; Moyer, R; Muller, S; Yu, A; Rosenberg, M; Smirnov, R; West, W; Boivin, R; Bray, B; Brooks, N; Hyatt, A; Wong, C; Fenstermacher, M; Groth, M; Lasnier, C; McLean, A; Stangeby, P; Ratynskaia, S; Roquemore, A; Skinner, C; Solomon, W M

    2008-01-01

    Dust production and accumulation impose safety and operational concerns for ITER. Diagnostics to monitor dust levels in the plasma as well as in-vessel dust inventory are currently being tested in a few tokamaks. Dust accumulation in ITER is likely to occur in hidden areas, e.g. between tiles and under divertor baffles. A novel electrostatic dust detector for monitoring dust in these regions has been developed and tested at PPPL. In DIII-D tokamak dust diagnostics include Mie scattering from Nd:YAG lasers, visible imaging, and spectroscopy. Laser scattering resolves size of particles between 0.16-1.6 (micro)m in diameter; the total dust content in the edge plasmas and trends in the dust production rates within this size range have been established. Individual dust particles are observed by visible imaging using fast-framing cameras, detecting dust particles of a few microns in diameter and larger. Dust velocities and trajectories can be determined in 2D with a single camera or 3D using multiple cameras, but determination of particle size is problematic. In order to calibrate diagnostics and benchmark dust dynamics modeling, pre-characterized carbon dust has been injected into the lower divertor of DIII-D. Injected dust is seen by cameras, and spectroscopic diagnostics observe an increase of carbon atomic, C2 dimer, and thermal continuum emissions from the injected dust. The latter observation can be used in the design of novel dust survey diagnostics

  6. Kennecott Utah Copper Corporation: Facility Utilizes Energy Assessments to Identify $930,000 in Potential Annual Savings

    Energy Technology Data Exchange (ETDEWEB)

    2004-07-01

    Kennecott Utah Copper Corporation (KUCC) used targeted energy assessments in the smelter and refinery at its Bingham Canyon Mine, near Salt Lake City, Utah. The assessment focused mainly on the energy-intensive processes of copper smelting and refining. By implementing the projects identified, KUCC could realize annual cost savings of $930,000 and annual energy savings of 452,000 MMBtu. The projects would also reduce maintenance, repair costs, waste, and environmental emissions. One project would use methane gas from an adjacent municipal dump to replace natural gas currently used to heat the refinery electrolyte.

  7. A Water Model Study on Mixing Behavior of the Two-Layered Bath in Bottom Blown Copper Smelting Furnace

    Science.gov (United States)

    Shui, Lang; Cui, Zhixiang; Ma, Xiaodong; Jiang, Xu; Chen, Mao; Xiang, Yong; Zhao, Baojun

    2018-05-01

    The bottom-blown copper smelting furnace is a novel copper smelter developed in recent years. Many advantages of this furnace have been found, related to bath mixing behavior under its specific gas injection scheme. This study aims to use an oil-water double-phased laboratory-scale model to investigate the impact of industry-adjustable variables on bath mixing time, including lower layer thickness, gas flow rate, upper layer thickness and upper layer viscosity. Based on experimental results, an overall empirical relationship of mixing time in terms of these variables has been correlated, which provides the methodology for industry to optimize mass transfer in the furnace.

  8. Impact of mercury mine and smelter St. Ana – Podljubelj on spatial distribution of chemical elements in soil

    Directory of Open Access Journals (Sweden)

    Tamara Teršič

    2005-06-01

    Full Text Available The objective of the research project was to establish the extension of Hg pollution as a consequence of mining and smelting activities in a narrow Alpine valley. The St. Ana mine was first exploited as early as in 1557 and was finally abandoned in 1902. The entire operating period yielded about 110.000 tons of ore, from which 360 tons of Hg was produced. By soil sampling it was established that on about 9 ha the Hg contents in soil exceed the Slovenian critical values for soil (10 mg/kg. The estimated mercury mean for the studied area is 1.3 mg/kg (0.17 – 718 mg/kg. The highest contents of mercury in soilswere found in the area of the mercury smelter.That is a consequence of former atmospheric emissions and technological losses. High values of Hg were found also in soil on the mine and smelter waste dump. The highest determined contents of Hg (108 mg/kg in this area are almost 7-times lower than thecontents of Hg in the area of the smelter. Mercury in soils generally decrease with depth and distance from the mine and smelter. Apart from the area around the former mine and smelter, mercury appear in higher concentrations also along the road that runs along thevalley, which is due to the use of Hg bearing mine tailings in road construction.

  9. Polychlorinated dibenzo-p-dioxin and dibenzofuran and polychlorinated biphenyl emissions from different smelting stages in secondary copper metallurgy.

    Science.gov (United States)

    Hu, Jicheng; Zheng, Minghui; Nie, Zhiqiang; Liu, Wenbin; Liu, Guorui; Zhang, Bing; Xiao, Ke

    2013-01-01

    Secondary copper production has received much attention for its high emissions of polychlorinated dibenzo-p-dioxin and dibenzofuran (PCDD/F) reported in previous studies. These studies focused on the estimation of total PCDD/F and polychlorinated biphenyl (PCB) emissions from secondary copper smelters. However, large variations in PCDD/F and PCB emissions reported in these studies were not analyzed and discussed further. In this study, stack gas samples at different smelting stages (feeding-fusion, oxidation and deoxidization) were collected from four plants to investigate variations in PCDD/F and PCB emissions and characteristics during the secondary copper smelting process. The results indicate that PCDD/F emissions occur mainly at the feeding-fusion stage and these emissions contribute to 54-88% of the total emissions from the secondary copper smelting process. The variation in feed material and operating conditions at different smelting stages leads to the variation in PCDD/F emissions during the secondary copper smelting process. The total PCDD/F and PCB discharge (stack gas emission+fly ash discharge) is consistent with the copper scrap content in the raw material in the secondary copper smelters investigated. On a production basis of 1 ton copper, the total PCDD/F and dl-PCB discharge was 102, 24.8 and 5.88 μg TEQ t(-1) for the three plants that contained 100%, 30% and 0% copper scrap in their raw material feed, respectively. Copyright © 2012 Elsevier Ltd. All rights reserved.

  10. Strategies for implementing zero discharge in an industrial smelter : 1. Managing fluroide in groundwater

    Science.gov (United States)

    Stagnitti, F.; Salzman, S.; Thwaites, L.; Allinson, G.; Le Blanc, M.; Hill, J.; Doerr, S.; de Rooij, G.

    2003-04-01

    The Portland Aluminium smelter produces approximately 75 ML of process wastewater each year. This is combined with storm water runoff from the site to give an annual production of 715 ML. In common with many other smelters, this wastewater stream is currently discharged to the ocean. However, although the quality of the water Portland Aluminium discharges currently meets all Australian Environmental Protection Agency license requirements, this mode of release is unlikely to be acceptable in the near future, and alternative disposal options for the water are required. The Portland smelter has developed strategies which will enable it to achieve zero-discharge within 5 years. These strategies include separating process water from storm water, recycling storm water, construction of evaporation ponds to receive process water, irrigation of process water and storm water on lands within the site and maintenance of important wetland functions. The poster presents a summary of the management strategies currently being trialed and in particular focuses on modeling the spatial and temporal variations of fluoride found in the shallow groundwater and the implications of achieving zero-discharge. The poster also discusses the possible impacts on the distribution of fluoride and other solutes in the vadose zone by the irrigation of treated process water on blue-gum plantations. Computer simulations indicate that irrigation of process water (either treated or untreated) on the land poses no significant long-term threat to regional or surficial groundwater. However the impacts of increased solute transport through the vadose zone on changes in soil structure and nutrition require further investigation.

  11. The environmental rules of economic development: Governing air pollution from smelters in Chuquicamata and La Oroya

    OpenAIRE

    Orihuela, José Carlos

    2015-01-01

    Why and how do societies transform the environmental rules of economic development, or fail to do so? This article compares the experiences of Chile and Peru in the regulation of smelting activities between 1990 and 2010. Air pollution from smelters in  Chuquicamata  and  La Oroya, each emblematic of the two countries’ mining industries, did not give rise to nationally destabilising protest. Nevertheless, despite the absence of pressing discontent with pollution, the environmental rules for m...

  12. Effects of air pollution on landscape and land-use around Norwegian aluminium smelters

    Energy Technology Data Exchange (ETDEWEB)

    Gilbert, O L

    1975-01-01

    Investigations around three aluminium smelters in Norway revealed that air pollution emanating from the works was affecting landscape and land-use for a distance of several kilometers. A zonal pattern of damage to the total flora is described in sufficient detail to act as a field guide for the recognition of this type of fume damage. Reasons for believing the observed effects to be due to fluorides are given and the visual and ecological consequences discussed. It is important that when expansion of the aluminium producing industry occurs this is undertaken in full realization of the possible consequences.

  13. Aluminum smelter-derived polycyclic aromatic hydrocarbons and flatfish health in the Kitimat marine ecosystem, British Columbia, Canada.

    Science.gov (United States)

    Johnson, Lyndal L; Ylitalo, Gina M; Myers, Mark S; Anulacion, Bernadita F; Buzitis, Jon; Collier, Tracy K

    2015-04-15

    From 2000-2004 a monitoring study was conducted to evaluate the impacts of aluminum smelter-derived polycyclic aromatic hydrocarbons (PAHs) on the health of fish in the marine waters of Kitimat, British Columbia, Canada. These waters are part of the historical fishing grounds of the Haisla First Nation, and since the 1950s the Alcan Primary Metal Company has operated an aluminum smelter at the head of the Kitimat Arm embayment. As a result, adjacent marine and estuarine sediments have been severely contaminated with a mixture of smelter-associated PAHs in the range of 10,000-100,000 ng/g dry wt. These concentrations are above those shown to cause adverse effects in fish exposed to PAHs in urban estuaries, but it was uncertain whether comparable effects would be seen at the Kitimat site due to limited bioavailability of smelter-derived PAHs. Over the 5-year study we conducted biennial collections of adult English sole (Parophrys vetulus) and sediment samples at the corresponding capture sites. Various tissue samples (e.g. liver, kidney, gonad, stomach contents) and bile were taken from each animal to determine levels of exposure and biological effects, and compare the uptake and toxicity of smelter-derived PAHs with urban mixtures of PAHs. Results showed significant intersite differences in concentrations of PAHs. Sole collected at sites nearest the smelter showed increased PAH exposure, as well as significantly higher prevalences of PAH-associated liver disease, compared to sites within Kitimat Arm that were more distant from the smelter. However, measures of PAH exposure (e.g., bile metabolites) were surprisingly high in sole from the reference sites outside of Kitimat Arm, though sediment and dietary PAHs at these sites were low, and fish from the areas showed no biological injury. PAH uptake, exposure, and biological effects in Kitimat English sole were relatively lower when compared to English sole collected from urban sites contaminated with PAH mixtures from

  14. Biological response of lichens and bryophytes to environmental pollution in the Murdochville copper mine area, Quebec

    Energy Technology Data Exchange (ETDEWEB)

    LeBlanc, F.; Robitaille, G.; Rao, D.N.

    1974-07-01

    The index of Atmospheric Purity (IAP) is a mathematical formula to correlate the lichen and bryophyte vegetation of an area with the quality of its ambient air. This IAP method has been used in the present study to determine the pollution pattern in the Murdochville Gaspe Copper Mine area, Quebec, where the environment is contaminated with emissions from a copper smelter. Sulfur dioxide, fluoride, lead, cadmium, arsenic, zinc, and copper were the contaminants found in the area. On the basis of this study, the authors concluded that the IAP method can be used for mapping heavy metal pollution more or less in the same manner and with the same degree of efficiency as it has been used for mapping SO/sub 2/ or fluoride pollution.

  15. Bioavailability and uptake of smelter emissions in freshwater zooplankton in northeastern Washington, USA lakes using Pb isotope analysis and trace metal concentrations.

    Science.gov (United States)

    Child, A W; Moore, B C; Vervoort, J D; Beutel, M W

    2018-07-01

    The upper Columbia River and associated valley systems are highly contaminated with metal wastes from nearby smelting operations in Trail, British Columbia, Canada (Teck smelter), and to a lesser extent, Northport, Washington, USA (Le Roi smelter). Previous studies have investigated depositional patterns of airborne emissions from these smelters, and documented the Teck smelter as the primary metal contamination source. However, there is limited research directed at whether these contaminants are bioavailable to aquatic organisms. This study investigates whether smelter derived contaminants are bioavailable to freshwater zooplankton. Trace metal (Zn, Cd, As, Sb, Pb and Hg) concentrations and Pb isotope compositions of zooplankton and sediment were measured in lakes ranging from 17 to 144 km downwind of the Teck smelter. Pb isotopic compositions of historic ores used by both smelters are uniquely less radiogenic than local geologic formations, so when zooplankton assimilate substantial amounts of smelter derived metals their compositions deviate from local baseline compositions toward ore compositions. Sediment metal concentrations and Pb isotope compositions in sediment follow significant (p < 0.001) negative exponential and sigmoidal patterns, respectively, as distance from the Teck smelting operation increases. Zooplankton As, Cd, and Sb contents were related to distance from the Teck smelter (p < 0.05), and zooplankton Pb isotope compositions suggest As, Cd, Sb and Pb from historic and current smelter emissions are biologically available to zooplankton. Zooplankton from lakes within 86 km of the Teck facility display isotopic evidence that legacy ore pollution is biologically available for assimilation. However, without water column data our study is unable to determine if legacy contaminants are remobilized from lake sediments, or erosional pathways from the watershed. Copyright © 2018 Elsevier Ltd. All rights reserved.

  16. Environmental impact of active and abandoned mines and metal smelters in Slovenia

    Directory of Open Access Journals (Sweden)

    Tomaž Budkovič

    2003-06-01

    Full Text Available Slovenia has long been known for its numerous mines and ore processing. From the times of the Roman Empire to now, 49 mines and open pits were opened, four of them were large (Idrija, Mežica – Topla, Litija and Žirovski vrh. There were also 25 oreprocessing plants and smelters, which were operating mostly in the vicinity of larger mines (Idrija, Žerjav, Celje. Due to the lack of written sources, we probably haven succeeded in making a complete list of them. There were 33 iron works operating in the vicinity ofmines and open pits, three large ones have further developed and are still operating (Jesenice, Ravne na Koroškem and Štore. As the ore processing capacities have far exceeded the capacities of the Slovenian mining, ore has long been imported and only processed in Slovenia. On the basis of the results of our investigations in the vicinity of larger mines and smelters we estimated that in Slovenia the areas in which critical limit for heavy metal content is exceeded sums up to about 80 km2.

  17. Heavy metal contamination of topsoils around a lead and zinc smelter in the Republic of Macedonia

    International Nuclear Information System (INIS)

    Stafilov, Trajce; Sajn, Robert; Pancevski, Zlatko; Boev, Blazo; Frontasyeva, Marina V.; Strelkova, Lyudmila P.

    2010-01-01

    The results of a first systematic study of spatial distribution of different elements in surface soil over the Veles region (50 km 2 ) known for its lead and zinc industrial activity in the recent past are reported. A total of 201 soil samples were collected according to a dense net in urban area and less dense net in rural area. The total of 42 elements were analyzed by epithermal neutron activation analysis (ENAA) and by atomic absorption spectrometry (AAS). The content of elements such as As, Au, Cd, Cu, Hg, In, Pb, Sb, Se, Zn in soil samples around the lead and zinc smelter and in the adjacent part of the town of Veles has appeared to be much higher than in those collected in the surrounding areas due to the pollution from the plant. Thus, the content of Cd (three times); Pb and Zn (two times) is even higher than the corresponding intervention (critical) values according to the Dutch standards. The results obtained by two complementary analytical techniques, AAS and ENAA, are discussed in terms of multivariate statistics. GIS technology was applied to depict the areas most affected by contamination from the lead and zinc smelter.

  18. Lead isotopes in soils near five historic American lead smelters and refineries

    International Nuclear Information System (INIS)

    Rabinowitz, Michael B.

    2005-01-01

    This survey of soil lead in the vicinity of old industrial sites examines how the stable isotope patterns vary among the sites according to the sources of the lead ore processed at each site. Lead smelters and refineries, which closed down decades ago, are the basis of this investigation. Samples were taken from near five old factory sites in Collinsville and Alton (Illinois), Ponderay (Idaho), East Chicago (Indiana) and Omaha (Nebraska). Historical records were searched for accounts of the sources of the lead. Lead concentrations were measured by atomic absorption flame spectrophotometry, and stable isotopic analysis was done by plasma ionization mass spectrometry. At every site visited, remnants of the old factories, in terms of soil lead pollution, could be found. In spite of potential complications of varying smelter feedstock sourced from mines of different geological age, it was possible to match the isotopic patterns in the soils with the documented sources of the ores. The Collinsville and Alton sites resembled Missouri lead. The Ponderay value was higher than major Bunker Hill, Idaho deposits, but closer to the minor, nearby Oreille County, Washington ores. Mostly Utah ore was used in East Chicago. The Omaha soil reflects lead from Mexico, Colorado and Montana

  19. Copper recovery from slag by indirect bio leaching

    International Nuclear Information System (INIS)

    Mazuelos, A.; Iglesias, N.; Romero, R.; Forcat, O.; Carranza, F.

    2009-01-01

    The main source of copper loss from a smelter is copper in discard slag. Slag can contain Cu in concentrations very much higher than those of many ores. Cu is present in slag entrained in very small drops of matte, white metal and blister copper occluded in fayalitic phase. In this work, the technical viability of the BRISA process, that is based on the indirect bio leaching, for this residue has been proved. A sample of slag, containing 2 % of copper, has been chemical, granulometric and metallographic characterized and it has been leached with ferric sulphate solutions in agitated reactors. The influence of several variables have been investigated. Once the best operating conditions had been selecting and an economic estimation had been done (with very really attractive results), the leaching stage has been designed for a plant of 30 tonnes per hour capacity. Cu extractions higher than 70% can be achieved with a residence time of only five hours. Despite of Cu(II) concentration in fed is as high as 30 g/l, bio oxidation stage can supply Fe(III) demanded by ferric leaching stage. (Author) 17 refs

  20. LADEE LUNAR DUST EXPERIMENT

    Data.gov (United States)

    National Aeronautics and Space Administration — This archive bundle includes data taken by the Lunar Dust Experiment (LDEX) instrument aboard the Lunar Atmosphere and Dust Environment Explorer (LADEE) spacecraft....

  1. Construction dust amelioration techniques.

    Science.gov (United States)

    2012-04-01

    Dust produced on seasonal road construction sites in Alaska is both a traffic safety and environmental concern. Dust emanating from : unpaved road surfaces during construction severely reduces visibility and impacts stopping sight distance, and contr...

  2. On Dust Charging Equation

    OpenAIRE

    Tsintsadze, Nodar L.; Tsintsadze, Levan N.

    2008-01-01

    A general derivation of the charging equation of a dust grain is presented, and indicated where and when it can be used. A problem of linear fluctuations of charges on the surface of the dust grain is discussed.

  3. Monitoring of Soil Contamination by Heavy Metals in the Impact Zone of Copper-Nickel Smelter on the Kola Peninsula

    Science.gov (United States)

    Kashulina, G. M.

    2018-04-01

    The results of landscape monitoring of the concentrations of acid-extractable Ni, Cu, Co, Mn, and Zn in soils of the local impact zone of the Severonikel industrial complex on the Kola Peninsula are discussed. The aim of monitoring studies was to reveal the spatial and temporal regularities of variation in the degree of soil contamination by heavy metals. In 2001-2011, the concentrations of acid-extractable compounds of the elements in the upper part of organic soil horizons around this plant exceeded their background concentrations by two orders of magnitude for Cu and Co and by three orders of magnitude for Ni. The degree of topsoil contamination with Ni, Cu, and Co generally corresponded to the distance of the plots from the contamination source and to the modern technogenic load. However, because of the long period of the emissions, their extreme amounts, and complex composition, indirect factors—the degree of technogenic soil degradation, the loss of soil organic matter, saturation of the surface soil layers by the contaminating metals, and competitive relationships between the elements—also affect soil contamination level. The concentrations of all the studied metals in the topsoil are characterized by considerable (1.5 to 7 times) variability in their long-term dynamics. The most important factors of this variability for Ni, Cu, and Co are the organic matter content of the samples and the amount of atmospheric precipitation in the year preceding the sampling. An inverse relationship between element concentrations in the soils and the amount of atmospheric precipitation attests to the dynamic nature and reversible character of the accumulation of heavy metals in the soils.

  4. Physics of interstellar dust

    CERN Document Server

    Krugel, Endrik

    2002-01-01

    The dielectric permeability; How to evaluate grain cross sections; Very small and very big particles; Case studies of Mie calculus; Particle statistics; The radiative transition probability; Structure and composition of dust; Dust radiation; Dust and its environment; Polarization; Grain alignment; PAHs and spectral features of dust; Radiative transport; Diffuse matter in the Milky Way; Stars and their formation; Emission from young stars. Appendices Mathematical formulae; List of symbols.

  5. Dust as a surfactant

    International Nuclear Information System (INIS)

    Ignatov, A M; Schram, P P J M; Trigger, S A

    2003-01-01

    We argue that dust immersed in a plasma sheath acts as a surfactant. By considering the momentum balance in a plasma sheath, we evaluate the dependence of the plasma surface pressure on the dust density. It is shown that the dust may reduce the surface pressure, giving rise to a sufficiently strong tangential force. The latter is capable of confining the dust layer inside the sheath in the direction perpendicular to the ion flow

  6. Dust Combustion Safety Issues for Fusion Applications

    Energy Technology Data Exchange (ETDEWEB)

    L. C. Cadwallader

    2003-05-01

    This report summarizes the results of a safety research task to identify the safety issues and phenomenology of metallic dust fires and explosions that are postulated for fusion experiments. There are a variety of metal dusts that are created by plasma erosion and disruptions within the plasma chamber, as well as normal industrial dusts generated in the more conventional equipment in the balance of plant. For fusion, in-vessel dusts are generally mixtures of several elements; that is, the constituent elements in alloys and the variety of elements used for in-vessel materials. For example, in-vessel dust could be composed of beryllium from a first wall coating, tungsten from a divertor plate, copper from a plasma heating antenna or diagnostic, and perhaps some iron and chromium from the steel vessel wall or titanium and vanadium from the vessel wall. Each of these elements has its own unique combustion characteristics, and mixtures of elements must be evaluated for the mixture’s combustion properties. Issues of particle size, dust temperature, and presence of other combustible materials (i.e., deuterium and tritium) also affect combustion in air. Combustion in other gases has also been investigated to determine if there are safety concerns with “inert” atmospheres, such as nitrogen. Several coolants have also been reviewed to determine if coolant breach into the plasma chamber would enhance the combustion threat; for example, in-vessel steam from a water coolant breach will react with metal dust. The results of this review are presented here.

  7. Influences of smelter fumes upon the chemical composition of lake waters near Sudbury, Ontario, and upon the surrounding vegetation

    Energy Technology Data Exchange (ETDEWEB)

    Gorham, E; Gordon, A G

    1960-01-01

    Analyses for sulphate, calcium, and pH have been made on surface waters from 102 lakes and ponds in the Sudbury metal-smelting district, and data are presented for 35 of these. Sulphur pollution is frequently high within about 5 miles of the three smelters, many ponds exhibiting more than three times the sulphate concentration normal for this area, and three waters more than 10 times this level. Outside about 15 miles distance the influence of smelter pollution upon sulphate concentrations in surface waters is negligible. As expected, many of the most polluted waters are strongly acid, with pH values going as low as 3.3. Sulphuric acid from air pollution has also led to increased weathering of calcium from soils and rocks, so that this ion tends to rise in concentration not only in waters above pH 6 (as expected) but also in those below pH 5. Damage to terrestrial vegetation is frequently marked within about 5 miles of the smelters, while it is seldom obvious to the untrained eye beyond this distance. Severe damage occurs chiefly within about 2 miles of the smelters.

  8. Mercury deposition/accumulation rates in the vicinity of a lead smelter as recorded by a peat deposit

    Czech Academy of Sciences Publication Activity Database

    Ettler, V.; Navrátil, Tomáš; Mihaljevič, M.; Rohovec, Jan; Zuna, M.; Šebek, O.; Strnad, L.; Hojdová, Maria

    2008-01-01

    Roč. 42, č. 24 (2008), s. 5968-5977 ISSN 1352-2310 R&D Projects: GA ČR GP526/07/P170 Institutional research plan: CEZ:AV0Z30130516 Keywords : mercury * deposition * Pb Smelter, * peat * historical record Subject RIV: DD - Geochemistry Impact factor: 2.890, year: 2008

  9. Effects of a reducer type on copper flash smelting slag decopperisation

    Directory of Open Access Journals (Sweden)

    B. Oleksiak

    2015-01-01

    Full Text Available In the paper, results of investigations on coke dust, anthracite dust and coal flotation concentrate application in the technology of copper flash smelting slag processing are presented. The results show that the selected reducers can be used as substitutes for the conventional coke.

  10. Contamination and health risks of soil heavy metals around a lead/zinc smelter in southwestern China.

    Science.gov (United States)

    Li, Peizhong; Lin, Chunye; Cheng, Hongguang; Duan, Xiaoli; Lei, Kai

    2015-03-01

    Anthropogenic emissions of toxic metals from smelters are a global problem. The objective of this study was to investigate the distribution of toxic metals in soils around a 60 year-old Pb/Zn smelter in a town in Yunnan Province of China. Topsoil and soil core samples were collected and analyzed to determine the concentrations of various forms of toxic metals. The results indicated that approximately 60 years of Pb/Zn smelting has led to significant contamination of the local soil by Zn, Pb, Cd, As, Sb, and Hg, which exhibited maximum concentrations of 8078, 2485, 75.4, 71.7, 25.3, and 2.58mgkg(-1), dry wet, respectively. Other metals, including Co, Cr, Cu, Mn, Ni, Sc, and V, were found to originate from geogenic sources. The concentrations of smelter driven metals in topsoil decreased with increasing distance from the smelter. The main contamination by Pb, Zn, and Cd was found in the upper 40cm of soil around the Pb/Zn smelter, but traces of Pb, Zn, and Cd contamination were found below 100cm. Geogenic Ni in the topsoil was mostly bound in the residual fraction (RES), whereas anthropogenic Cd, Pb, and Zn were mostly associated with non-RES fractions. Therefore, the smelting emissions increased not only the concentrations of Cd, Pb, and Zn in the topsoil but also their mobility and bioavailability. The hazard quotient and hazard index showed that the topsoil may pose a health risk to children, primarily due to the high Pb and As contents of the soil. Copyright © 2014 Elsevier Inc. All rights reserved.

  11. Characterization of the lead smelter slag in Santo Amaro, Bahia, Brazil

    International Nuclear Information System (INIS)

    Andrade Lima, L.R.P. de; Bernardez, L.A.

    2011-01-01

    For 33 years, a primary lead smelter operated in Santo Amaro (Brazil). Since the 1970s, large amounts of Pb and Cd have been widely documented in the blood and hair of people living near the smelter. The plant closed down in 1993, and several years later, the Pb levels in the blood of children under 4 years of age living near the smelter were high, where the disposed lead slag was suspected to be the main source of this contamination. The objective of this study is to elucidate the source of the Pb contamination and any other potentially toxic contamination, focusing on the characterization of the slag. The samples used for this characterization study were taken from the slag heaps. The results of the chemical analysis showed that the major constituents of the slag, in decreasing order of wt%, were the following: Fe 2 O 3 (28.10), CaO (23.11), SiO 2 (21.39), ZnO (9.47), MgO (5.44), PbO (4.06), Al 2 O 3 (3.56), C (2.26), MnO (1.44), Na 2 O (0.27), S (0.37), K 2 O (0.26), and TiO 2 (0.25). The Cd content of the slag was 57.3 mg/kg, which is relatively low. The X-ray diffraction and the electron probe microanalyzer X-ray mapping indicated that the major phases in the slag were wuestite, olivine, kirschsteinite, and franklinite. Only spheroidal metallic Pb was found in the slag. The leaching study showed that the slag was stable at a pH greater than 2.8, and only in an extremely acidic environment was the solubilization of the Pb enhanced significantly. The solubilization of Zn was very limited in the acidic and alkaline environments. These results can be explained by the limited leachability of the metallic Pb and Zn-bearing compounds. The leaching study used TCLP, SPLP, and SWEP and indicated that the lead slag was stable in weak acidic environments for short contact times.

  12. Visualisation and quantification of heavy metal accessibility in smelter slags: The influence of morphology on availability

    International Nuclear Information System (INIS)

    Morrison, Anthony L.; Swierczek, Zofia; Gulson, Brian L.

    2016-01-01

    The Imperial Smelting Furnace (ISF) for producing lead and zinc simultaneously has operated on four continents and in eleven countries from the 1950's. One of the process changes that the ISF introduced was the production of a finely granulated slag waste. Although this slag contained significant amounts of residual lead (Pb) and zinc (Zn), because of its glassy nature it was considered environmentally benign. From the Cockle Creek smelter near Boolaroo at the northern end of Lake Macquarie, NSW, Australia, it is estimated that around 2.1 million tonnes of the fine slag was distributed into the community and most remains where it was originally utilised. Residual tonnages of slag of this magnitude are common worldwide wherever the ISF operated. Studies of base metal smelting slags have concluded that mineralogical and morphological characteristics of the slag play a critical role in moderating environmental release of toxic elements. Scanning electron microscopy (SEM) and microanalysis of the ISF slags has shown that the Pb and associated elements are present as discrete nodules (∼6–22 μm) in the slag and that they are not associated with Zn which is contained in the glass slag phase. Using an automated SEM and analysis technique (QEMSCAN"®) to “map” the mineralogical structure of the particles, it was possible to quantitatively determine the degree of access infiltrating fluids might have to the reaction surface of the Pb phases. The level of access decreases with increasing particle size, but in even the largest sized particles (−3350 + 2000 μm) nearly 80% of the Pb-containing phases were totally or partially accessible. These results provide evidence that the toxic elements in the slags are not contained by the glassy phase and will be vulnerable to leaching over time depending on their individual phase reactivity. - Highlights: • QEMSCAN"® allowed determination of access to infiltrating fluids to Pb in smelter slags. • Pb and associated

  13. Characterization of the lead smelter slag in Santo Amaro, Bahia, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Andrade Lima, L.R.P. de, E-mail: lelo@ufba.br [Department of Materials Science and Technology, Federal University of Bahia, C.P. 6974, Salvador, BA 41810-971 (Brazil); Bernardez, L.A. [Ingenium Consultoria em Engenharia Ltda (Brazil)

    2011-05-30

    For 33 years, a primary lead smelter operated in Santo Amaro (Brazil). Since the 1970s, large amounts of Pb and Cd have been widely documented in the blood and hair of people living near the smelter. The plant closed down in 1993, and several years later, the Pb levels in the blood of children under 4 years of age living near the smelter were high, where the disposed lead slag was suspected to be the main source of this contamination. The objective of this study is to elucidate the source of the Pb contamination and any other potentially toxic contamination, focusing on the characterization of the slag. The samples used for this characterization study were taken from the slag heaps. The results of the chemical analysis showed that the major constituents of the slag, in decreasing order of wt%, were the following: Fe{sub 2}O{sub 3} (28.10), CaO (23.11), SiO{sub 2} (21.39), ZnO (9.47), MgO (5.44), PbO (4.06), Al{sub 2}O{sub 3} (3.56), C (2.26), MnO (1.44), Na{sub 2}O (0.27), S (0.37), K{sub 2}O (0.26), and TiO{sub 2} (0.25). The Cd content of the slag was 57.3 mg/kg, which is relatively low. The X-ray diffraction and the electron probe microanalyzer X-ray mapping indicated that the major phases in the slag were wuestite, olivine, kirschsteinite, and franklinite. Only spheroidal metallic Pb was found in the slag. The leaching study showed that the slag was stable at a pH greater than 2.8, and only in an extremely acidic environment was the solubilization of the Pb enhanced significantly. The solubilization of Zn was very limited in the acidic and alkaline environments. These results can be explained by the limited leachability of the metallic Pb and Zn-bearing compounds. The leaching study used TCLP, SPLP, and SWEP and indicated that the lead slag was stable in weak acidic environments for short contact times.

  14. Geochemical position of Pb, Zn and Cd in soils near the Olkusz mine/smelter, South Poland: effects of land use, type of contamination and distance from pollution source.

    Science.gov (United States)

    Chrastný, Vladislav; Vaněk, Aleš; Teper, Leslaw; Cabala, Jerzy; Procházka, Jan; Pechar, Libor; Drahota, Petr; Penížek, Vít; Komárek, Michael; Novák, Martin

    2012-04-01

    The soils adjacent to an area of historical mining, ore processing and smelting activities reflects the historical background and a mixing of recent contamination sources. The main anthropogenic sources of metals can be connected with historical and recent mine wastes, direct atmospheric deposition from mining and smelting processes and dust particles originating from open tailings ponds. Contaminated agriculture and forest soil samples with mining and smelting related pollutants were collected at different distances from the source of emission in the Pb-Zn-Ag mining area near Olkusz, Upper Silesia to (a) compare the chemical speciation of metals in agriculture and forest soils situated at the same distance from the point source of pollution (paired sampling design), (b) to evaluate the relationship between the distance from the polluter and the retention of the metals in the soil, (c) to describe mineralogy transformation of anthropogenic soil particles in the soils, and (d) to assess the effect of deposited fly ash vs. dumped mining/smelting waste on the mobility and bioavailability of metals in the soil. Forest soils are much more affected with smelting processes than agriculture soils. However, agriculture soils suffer from the downward metal migration more than the forest soils. The maximum concentrations of Pb, Zn, and Cd were detected in a forest soil profile near the smelter and reached about 25 g kg(- 1), 20 g kg(- 1) and 200 mg kg(- 1) for Pb, Zn and Cd, respectively. The metal pollutants from smelting processes are less stable under slightly alkaline soil pH then acidic due to the metal carbonates precipitation. Metal mobility ranges in the studied forest soils are as follows: Pb > Zn ≈ Cd for relatively circum-neutral soil pH (near the smelter), Cd > Zn > Pb for acidic soils (further from the smelter). Under relatively comparable pH conditions, the main soil properties influencing metal migration are total organic carbon and cation exchange

  15. Simulation of windblown dust transport from a mine tailings impoundment using a computational fluid dynamics model

    Science.gov (United States)

    Stovern, Michael; Felix, Omar; Csavina, Janae; Rine, Kyle P.; Russell, MacKenzie R.; Jones, Robert M.; King, Matt; Betterton, Eric A.; Sáez, A. Eduardo

    2014-01-01

    Mining operations are potential sources of airborne particulate metal and metalloid contaminants through both direct smelter emissions and wind erosion of mine tailings. The warmer, drier conditions predicted for the Southwestern US by climate models may make contaminated atmospheric dust and aerosols increasingly important, due to potential deleterious effects on human health and ecology. Dust emissions and dispersion of dust and aerosol from the Iron King Mine tailings in Dewey-Humboldt, Arizona, a Superfund site, are currently being investigated through in situ field measurements and computational fluid dynamics modeling. These tailings are heavily contaminated with lead and arsenic. Using a computational fluid dynamics model, we model dust transport from the mine tailings to the surrounding region. The model includes gaseous plume dispersion to simulate the transport of the fine aerosols, while individual particle transport is used to track the trajectories of larger particles and to monitor their deposition locations. In order to improve the accuracy of the dust transport simulations, both regional topographical features and local weather patterns have been incorporated into the model simulations. Results show that local topography and wind velocity profiles are the major factors that control deposition. PMID:25621085

  16. Simulation of windblown dust transport from a mine tailings impoundment using a computational fluid dynamics model.

    Science.gov (United States)

    Stovern, Michael; Felix, Omar; Csavina, Janae; Rine, Kyle P; Russell, MacKenzie R; Jones, Robert M; King, Matt; Betterton, Eric A; Sáez, A Eduardo

    2014-09-01

    Mining operations are potential sources of airborne particulate metal and metalloid contaminants through both direct smelter emissions and wind erosion of mine tailings. The warmer, drier conditions predicted for the Southwestern US by climate models may make contaminated atmospheric dust and aerosols increasingly important, due to potential deleterious effects on human health and ecology. Dust emissions and dispersion of dust and aerosol from the Iron King Mine tailings in Dewey-Humboldt, Arizona, a Superfund site, are currently being investigated through in situ field measurements and computational fluid dynamics modeling. These tailings are heavily contaminated with lead and arsenic. Using a computational fluid dynamics model, we model dust transport from the mine tailings to the surrounding region. The model includes gaseous plume dispersion to simulate the transport of the fine aerosols, while individual particle transport is used to track the trajectories of larger particles and to monitor their deposition locations. In order to improve the accuracy of the dust transport simulations, both regional topographical features and local weather patterns have been incorporated into the model simulations. Results show that local topography and wind velocity profiles are the major factors that control deposition.

  17. Multiple causes of anaemia amongst children living near a lead smelter in Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, F M; Barreto, M L; Silvany-Neto, A M; Waldron, H A; Tavares, T M

    1984-04-05

    A prevalence study of anaemia was carried out amongst children, aged one to nine years, living near a lead smelter in Santo Amaro City, Northeast Brazil. It was found that the variation in haemoglobin levels was significantly associated with malnutrition and with the interaction between malnutrition and iron deficiency, but not with lead poisoning, iron deficiency, or hookworm infection, having allowed for the effects of age, area of residence, family per capita income and race. The effect of the interaction between malnutrition and iron deficiency on haemoglobin levels was most prominent amongst children aged one year and amongst those living in the most deprived area. The lack of demonstrable interaction between lead poisoning and iron deficiency in the causation of anaemia amongst these children is discussed.

  18. Minimum and Full Fluidization Velocity for Alumina Used in the Aluminum Smelter

    Directory of Open Access Journals (Sweden)

    Paulo Douglas S. de Vasconcelos

    2011-11-01

    Full Text Available Fluidization is an engineering unit operation that occurs when a fluid (liquid or gas ascends through a bed of particles, and these particles get a velocity of minimum fluidization enough to stay in suspension, but without carrying them in the ascending flow. As from this moment the powder behaves as liquid at boiling point, hence the term “fluidization”. This operation is widely used in the aluminum smelter processes, for gas dry scrubbing (mass transfer and in a modern plant for continuous alumina pot feeding (particles’ momentum transfer. The understanding of the alumina fluoride rheology is of vital importance in the design of fluidized beds for gas treatment and fluidized pipelines for pot feeding. This paper shows the results of the experimental and theoretical values of the minimum and full fluidization velocities for the alumina fluoride used to project the state of the art round non‐metallic air‐fluidized conveyor of multiples outlets.

  19. The Lunar Dust Environment

    Science.gov (United States)

    Szalay, Jamey Robert

    Planetary bodies throughout the solar system are continually bombarded by dust particles, largely originating from cometary activities and asteroidal collisions. Surfaces of bodies with thick atmospheres, such as Venus, Earth, Mars and Titan are mostly protected from incoming dust impacts as these particles ablate in their atmospheres as 'shooting stars'. However, the majority of bodies in the solar system have no appreciable atmosphere and their surfaces are directly exposed to the flux of high speed dust grains. Impacts onto solid surfaces in space generate charged and neutral gas clouds, as well as solid secondary ejecta dust particles. Gravitationally bound ejecta clouds forming dust exospheres were recognized by in situ dust instruments around the icy moons of Jupiter and Saturn, and had not yet been observed near bodies with refractory regolith surfaces before NASA's Lunar Dust and Environment Explorer (LADEE) mission. In this thesis, we first present the measurements taken by the Lunar Dust Explorer (LDEX), aboard LADEE, which discovered a permanently present, asymmetric dust cloud surrounding the Moon. The global characteristics of the lunar dust cloud are discussed as a function of a variety of variables such as altitude, solar longitude, local time, and lunar phase. These results are compared with models for lunar dust cloud generation. Second, we present an analysis of the groupings of impacts measured by LDEX, which represent detections of dense ejecta plumes above the lunar surface. These measurements are put in the context of understanding the response of the lunar surface to meteoroid bombardment and how to use other airless bodies in the solar system as detectors for their local meteoroid environment. Third, we present the first in-situ dust measurements taken over the lunar sunrise terminator. Having found no excess of small grains in this region, we discuss its implications for the putative population of electrostatically lofted dust.

  20. Characterisation of atmospheric deposited particles during a dust storm in urban areas of Eastern Australia

    Energy Technology Data Exchange (ETDEWEB)

    Gunawardena, Janaka, E-mail: j.gunawardena@qut.edu.au; Ziyath, Abdul M., E-mail: mohamed.ziyath@qut.edu.au; Bostrom, Thor E., E-mail: t.bostrom@qut.edu.au; Bekessy, Lambert K., E-mail: l.bekessy@qut.edu.au; Ayoko, Godwin A., E-mail: g.ayoko@qut.edu.au; Egodawatta, Prasanna, E-mail: p.egodawatta@qut.edu.au; Goonetilleke, Ashantha, E-mail: a.goonetilleke@qut.edu.au

    2013-09-01

    The characteristics of dust particles deposited during the 2009 dust storm in the Gold Coast and Brisbane regions of Australia are discussed in this paper. The study outcomes provide important knowledge in relation to the potential impacts of dust storm related pollution on ecosystem health in the context that the frequency of dust storms is predicted to increase due to anthropogenic desert surface modifications and climate change impacts. The investigated dust storm contributed a large fraction of fine particles to the environment with an increased amount of total suspended solids, compared to dry deposition under ambient conditions. Although the dust storm passed over forested areas, the organic carbon content in the dust was relatively low. The primary metals present in the dust storm deposition were aluminium, iron and manganese, which are common soil minerals in Australia. The dust storm deposition did not contain significant loads of nickel, cadmium, copper and lead, which are commonly present in the urban environment. Furthermore, the comparison between the ambient and dust storm chromium and zinc loads suggested that these metals were contributed to the dust storm by local anthropogenic sources. The potential ecosystem health impacts of the 2009 dust storm include, increased fine solids deposition on ground surfaces resulting in an enhanced capacity to adsorb toxic pollutants as well as increased aluminium, iron and manganese loads. In contrast, the ecosystem health impacts related to organic carbon and other metals from dust storm atmospheric deposition are not considered to be significant. - Highlights: • The dust storm contributed a large fraction of fine particles to pollutant build-up. • The dust storm increased TSS, Al, Fe and Mn loads in build-up on ground surfaces. • Dust storm did not significantly increase TOC, Ni, Cu, Pb and Cd loads in build-up. • Cr and Zn in dust storm deposition were contributed by local anthropogenic sources.

  1. Characterisation of atmospheric deposited particles during a dust storm in urban areas of Eastern Australia

    International Nuclear Information System (INIS)

    Gunawardena, Janaka; Ziyath, Abdul M.; Bostrom, Thor E.; Bekessy, Lambert K.; Ayoko, Godwin A.; Egodawatta, Prasanna; Goonetilleke, Ashantha

    2013-01-01

    The characteristics of dust particles deposited during the 2009 dust storm in the Gold Coast and Brisbane regions of Australia are discussed in this paper. The study outcomes provide important knowledge in relation to the potential impacts of dust storm related pollution on ecosystem health in the context that the frequency of dust storms is predicted to increase due to anthropogenic desert surface modifications and climate change impacts. The investigated dust storm contributed a large fraction of fine particles to the environment with an increased amount of total suspended solids, compared to dry deposition under ambient conditions. Although the dust storm passed over forested areas, the organic carbon content in the dust was relatively low. The primary metals present in the dust storm deposition were aluminium, iron and manganese, which are common soil minerals in Australia. The dust storm deposition did not contain significant loads of nickel, cadmium, copper and lead, which are commonly present in the urban environment. Furthermore, the comparison between the ambient and dust storm chromium and zinc loads suggested that these metals were contributed to the dust storm by local anthropogenic sources. The potential ecosystem health impacts of the 2009 dust storm include, increased fine solids deposition on ground surfaces resulting in an enhanced capacity to adsorb toxic pollutants as well as increased aluminium, iron and manganese loads. In contrast, the ecosystem health impacts related to organic carbon and other metals from dust storm atmospheric deposition are not considered to be significant. - Highlights: • The dust storm contributed a large fraction of fine particles to pollutant build-up. • The dust storm increased TSS, Al, Fe and Mn loads in build-up on ground surfaces. • Dust storm did not significantly increase TOC, Ni, Cu, Pb and Cd loads in build-up. • Cr and Zn in dust storm deposition were contributed by local anthropogenic sources

  2. Antwerp Copper Plates

    DEFF Research Database (Denmark)

    Wadum, Jørgen

    1999-01-01

    In addition to presenting a short history of copper paintings, topics detail artists’ materials and techniques, as well as aspects of the copper industry, including mining, preparation and trade routes.......In addition to presenting a short history of copper paintings, topics detail artists’ materials and techniques, as well as aspects of the copper industry, including mining, preparation and trade routes....

  3. Copper and Copper Proteins in Parkinson's Disease

    Science.gov (United States)

    Rivera-Mancia, Susana; Diaz-Ruiz, Araceli; Tristan-Lopez, Luis; Rios, Camilo

    2014-01-01

    Copper is a transition metal that has been linked to pathological and beneficial effects in neurodegenerative diseases. In Parkinson's disease, free copper is related to increased oxidative stress, alpha-synuclein oligomerization, and Lewy body formation. Decreased copper along with increased iron has been found in substantia nigra and caudate nucleus of Parkinson's disease patients. Copper influences iron content in the brain through ferroxidase ceruloplasmin activity; therefore decreased protein-bound copper in brain may enhance iron accumulation and the associated oxidative stress. The function of other copper-binding proteins such as Cu/Zn-SOD and metallothioneins is also beneficial to prevent neurodegeneration. Copper may regulate neurotransmission since it is released after neuronal stimulus and the metal is able to modulate the function of NMDA and GABA A receptors. Some of the proteins involved in copper transport are the transporters CTR1, ATP7A, and ATP7B and the chaperone ATOX1. There is limited information about the role of those biomolecules in the pathophysiology of Parkinson's disease; for instance, it is known that CTR1 is decreased in substantia nigra pars compacta in Parkinson's disease and that a mutation in ATP7B could be associated with Parkinson's disease. Regarding copper-related therapies, copper supplementation can represent a plausible alternative, while copper chelation may even aggravate the pathology. PMID:24672633

  4. Dust Devil Tracks

    Science.gov (United States)

    2002-01-01

    (Released 8 May 2002) The Science This image, centered near 50.0 S and 17.7 W displays dust devil tracks on the surface. Most of the lighter portions of the image likely have a thin veneer of dust settled on the surface. As a dust devil passes over the surface, it acts as a vacuum and picks up the dust, leaving the darker substrate exposed. In this image there is a general trend of many of the tracks running from east to west or west to east, indicating the general wind direction. There is often no general trend present in dust devil tracks seen in other images. The track patterns are quite ephemeral and can completely change or even disappear over the course of a few months. Dust devils are one of the mechanisms that Mars uses to constantly pump dust into the ubiquitously dusty atmosphere. This atmospheric dust is one of the main driving forces of the present Martian climate. The Story Vrrrrooooooooom. Think of a tornado, the cartoon Tasmanian devil, or any number of vacuum commercials that powerfully suck up swirls of dust and dirt. That's pretty much what it's like on the surface of Mars a lot of the time. Whirlpools of wind called

  5. Separation of copper-64 from copper phthalocyanine

    International Nuclear Information System (INIS)

    Battaglin, R.I.M.

    1979-01-01

    The separation of copper-64 from irradiated copper phthalocyanine by Szilard-Chalmers effect is studied. Two methods of separation are used: one of them is based on the dissolution of the irradiated dry compound in concentrated sulfuric acid following its precipitation in water. In the other one the compound is irradiated with water in paste form following treatment with water and hydrochloric acid. The influence of the crystal form of the copper phthalocyanine on the separation yield of copper-64 is shown. Preliminary tests using the ionic exchange technique for purification and changing of copper-64 sulfate to chloride form are carried out. The specific activity using the spectrophotometric technique, after the determination of the copper concentration in solution of copper-64, is calculated. (Author) [pt

  6. Lead in residential soil and dust in a mining and smelting district in northern Armenia: a pilot study

    International Nuclear Information System (INIS)

    Petrosyan, Varduhi; Orlova, Anna; Dunlap, Charles E.; Babayan, Emil; Farfel, Mark; Braun, Margrit von

    2004-01-01

    This pilot study of sources of lead exposure in residential settings was conducted in a mining and smelting district in northern Armenia. Samples of exterior soil and dust and interior house dust were collected in and around apartment buildings in Alaverdi where the country's largest polymetallic smelter is located, and in nearby mining towns of Aghtala and Shamlugh. The NITON XL-723 Multi-Element XRF analyzer was used for lead testing. Lead levels in samples from Alaverdi were higher than those in Shamlugh and Aghtala. In all three towns, the highest lead levels were found in loose exterior dust samples, and lead concentrations in yard soil were higher than those in garden soil. Many soil samples (34%) and the majority of loose dust samples (77%) in Alaverdi exceeded the US Environmental Protection Agency standard of 400 mg/kg for bare soil in children's play areas. In addition, 36% of floor dust samples from apartments in Alaverdi exceeded the US Environmental Protection Agency standard of 40 μg/ft 2 for lead loading in residential floor dust. The Armenian Ministry of Health and other interested agencies are being informed about the findings of the study so that they can consider and develop educational and preventive programs including blood lead screening among sensitive populations

  7. Whither Cometary Dust?

    Science.gov (United States)

    Lisse, Carey M.

    2010-10-01

    In this paper I will discuss recent findings that have important implications for our understanding of the formation and evolution of primitive solar system dust, including: - Nesvorny et al. (2010), following up on their dynamical analyses of the zodiacal dust bands as sourced by the breakup of the Karin (5Mya) and Veritas (8Mya) asteroid families, argue that over 90% of the interplanetary dust cloud at 1 AU comes from JFC comets with near-circularized, low inclination orbits. This implies that the noted IPD collections of anhydrous and hydrous dust particles are likely to be from Oort cloud and JFC comets, respectively, not from asteroids and comets as thought in the past. Hydrous dust particles from comets like 85P/Wild2 and 9P/Tempel 1 would be consistent with results from the STARDUST and Deep Impact experiments. - Estimates of the dust particle size distributions (PSDs) in the comae of 85P/Wild2 (Green et al. 2004, 2007) and 73P/SW-3 (Sitko et al. 2010, Vaubaillon & Reach 2010) and in the trails of comets (Reach et al. 2007) have broken power law structure, with a plateau enhancement of particles of 1 mm - 1 cm in size. This size is also the size of most chondritic inclusions, and the predicted size range of the "aggregational barrier", where collisions between dust particles become destructive. - Studies of the albedo and polarization properties of cometary dust (Kolokolova et al. 2007) suggest there are 2 major groupings, one with low scattering capability and one with high. While these families could possibly have been explained by systematics in the PSDs of the emitted dust, independent work by Lisse et al. (2008) on the mineralogy of a number of highly dusty comets has shown evidence for one family of comets with highly crystalline dust and another with highly amorphous dust.

  8. Elemental properties of copper slag and measured airborne exposures at a copper slag processing facility.

    Science.gov (United States)

    Mugford, Christopher; Gibbs, Jenna L; Boylstein, Randy

    2017-08-01

    In 1974, the National Institute for Occupational Safety and Health recommended a ban on the use of abrasives containing >1% silica, giving rise to abrasive substitutes like copper slag. We present results from a National Institute for Occupational Safety and Health industrial hygiene survey at a copper slag processing facility that consisted of the collection of bulk samples for metals and silica; and full-shift area and personal air samples for dust, metals, and respirable silica. Carcinogens, suspect carcinogens, and other toxic elements were detected in all bulk samples, and area and personal air samples. Area air samples identified several areas with elevated levels of inhalable and respirable dust, and respirable silica: quality control check area (236 mg/m 3 inhalable; 10.3 mg/m 3 respirable; 0.430 mg/m 3 silica), inside the screen house (109 mg/m 3 inhalable; 13.8 mg/m 3 respirable; 0.686 mg/m 3 silica), under the conveyor belt leading to the screen house (19.8 mg/m 3 inhalable), and inside a conveyor access shack (11.4 mg/m 3 inhalable; 1.74 mg/m 3 respirable; 0.067 mg/m 3 silica). Overall, personal dust samples were lower than area dust samples and did not exceed published occupational exposure limits. Silica samples collected from a plant hand and a laborer exceeded the American Conference of Governmental Industrial Hygienist Threshold Limit Value of 0.025 µg/m 3 . All workers involved in copper slag processing (n = 5) approached or exceeded the Occupational Safety and Health Administration permissible exposure limit of 10 µg/m 3 for arsenic (range: 9.12-18.0 µg/m 3 ). Personal total dust levels were moderately correlated with personal arsenic levels (R s = 0.70) and personal respirable dust levels were strongly correlated with respirable silica levels (R s = 0.89). We identified multiple areas with elevated levels of dust, respirable silica, and metals that may have implications for personal exposure at other facilities if preventive

  9. Communication plan for windblown dust.

    Science.gov (United States)

    2015-05-01

    Windblown dust events occur in Arizona, and blowing dust has been considered a contributing factor to serious crashes on the : segment of Interstate 10 (I10) between Phoenix and Tucson, as well as on other Arizona roadways. Arizonas dust events...

  10. Dust in planetary nebulae

    International Nuclear Information System (INIS)

    Mathis, J.S.

    1978-01-01

    The author's review concentrates on theoretical aspects of dust in planetary nebulae (PN). He considers the questions: how much dust is there is PN; what is its composition; what effects does it have on the ionization structure, on the dynamics of the nebula. (Auth.)

  11. Toxicity of lunar dust

    NARCIS (Netherlands)

    Linnarsson, D.; Carpenter, J.; Fubini, B.; Gerde, P.; Loftus, D.; Prisk, K.; Staufer, U.; Tranfield, E.; van Westrenen, W.

    2012-01-01

    The formation, composition and physical properties of lunar dust are incompletely characterised with regard to human health. While the physical and chemical determinants of dust toxicity for materials such as asbestos, quartz, volcanic ashes and urban particulate matter have been the focus of

  12. Combustible dust tests

    Science.gov (United States)

    The sugar dust explosion in Georgia on February 7, 2008 killed 14 workers and injured many others (OSHA, 2009). As a consequence of this explosion, OSHA revised its Combustible Dust National Emphasis (NEP) program. The NEP targets 64 industries with more than 1,000 inspections and has found more tha...

  13. Respirable dust measured downwind during rock dust application.

    Science.gov (United States)

    Harris, M L; Organiscak, J; Klima, S; Perera, I E

    2017-05-01

    The Pittsburgh Mining Research Division of the U.S. National Institute for Occupational Safety and Health (NIOSH) conducted underground evaluations in an attempt to quantify respirable rock dust generation when using untreated rock dust and rock dust treated with an anticaking additive. Using personal dust monitors, these evaluations measured respirable rock dust levels arising from a flinger-type application of rock dust on rib and roof surfaces. Rock dust with a majority of the respirable component removed was also applied in NIOSH's Bruceton Experimental Mine using a bantam duster. The respirable dust measurements obtained downwind from both of these tests are presented and discussed. This testing did not measure miners' exposure to respirable coal mine dust under acceptable mining practices, but indicates the need for effective continuous administrative controls to be exercised when rock dusting to minimize the measured amount of rock dust in the sampling device.

  14. Isotopic characterisation of lead in contaminated soils from the vicinity of a non-ferrous metal smelter near Plovdiv, Bulgaria

    Energy Technology Data Exchange (ETDEWEB)

    Bacon, Jeffrey R. [Macaulay Institute, Craigiebuckler, Aberdeen AB15 8QH (United Kingdom)]. E-mail: j.bacon@macaulay.ac.uk; Dinev, Nikolai S. [N Poushkarov Institute of Soil Science and Agroecology, Sofia (Bulgaria)

    2005-03-01

    Soil samples from the vicinity of a non-ferrous metal smelter near Plovdiv, Bulgaria contained very high concentrations of cadmium, lead and zinc (up to 140, 4900 and 5900 mg kg{sup -1}, respectively). A roadside soil in a relatively uncontaminated area also contained high concentrations of the same metals (24, 1550 and 1870 mg kg{sup -1}, respectively) indicating that the transport of ores could be a source of contamination. Even though the lead isotope ratios in all the samples fell within a very narrow range (for example, 1.186-1.195 for {sup 206}Pb/{sup 207}Pb), the samples could be differentiated into three distinct groups: ores ({sup 206}Pb/{sup 207}Pb and {sup 208}Pb/{sup 207}Pb ratios of 1.1874-1.1884 and 2.4755-2.4807, respectively), current deposition (1.1864 and 2.4704-2.4711, respectively) and local background (1.1927-1.1951 and 2.4772-2.4809, respectively). Although most of the current deposition has its origin in the ores used at the smelter, up to 12% could be from other sources such as petrol lead. - Although soils in the vicinity of a non-ferrous metal smelter near Plovdiv, Bulgaria, have become highly contaminated with the ores used, lead isotope analysis has revealed that up to 12% of current deposition could be from other sources such as petrol lead.

  15. Isotopic characterisation of lead in contaminated soils from the vicinity of a non-ferrous metal smelter near Plovdiv, Bulgaria

    International Nuclear Information System (INIS)

    Bacon, Jeffrey R.; Dinev, Nikolai S.

    2005-01-01

    Soil samples from the vicinity of a non-ferrous metal smelter near Plovdiv, Bulgaria contained very high concentrations of cadmium, lead and zinc (up to 140, 4900 and 5900 mg kg -1 , respectively). A roadside soil in a relatively uncontaminated area also contained high concentrations of the same metals (24, 1550 and 1870 mg kg -1 , respectively) indicating that the transport of ores could be a source of contamination. Even though the lead isotope ratios in all the samples fell within a very narrow range (for example, 1.186-1.195 for 206 Pb/ 207 Pb), the samples could be differentiated into three distinct groups: ores ( 206 Pb/ 207 Pb and 208 Pb/ 207 Pb ratios of 1.1874-1.1884 and 2.4755-2.4807, respectively), current deposition (1.1864 and 2.4704-2.4711, respectively) and local background (1.1927-1.1951 and 2.4772-2.4809, respectively). Although most of the current deposition has its origin in the ores used at the smelter, up to 12% could be from other sources such as petrol lead. - Although soils in the vicinity of a non-ferrous metal smelter near Plovdiv, Bulgaria, have become highly contaminated with the ores used, lead isotope analysis has revealed that up to 12% of current deposition could be from other sources such as petrol lead

  16. Effects of dust accumulation and removal on radiator surfaces on Mars

    International Nuclear Information System (INIS)

    Gaier, J.R.; Perez-Davis, M.E.; Rutledge, S.K.; Hotes, D.; Olle, R.

    1991-01-01

    Tests were carried out to assess the impact of wind blown dust accumulation and abrasion on radiator surfaces on Mars. High emittance arc-textured copper (Cu) and niobium-1%-zirconium (Nb-1%Zr) samples were subjected to basaltic dust laden wind at Martian pressure (1000 Pa) at speeds varying from 19 to 97 m/s in the Martian Surface Wind Tunnel at NASA Ames Research Center. The effect of accumulated dust was also observed by pre-dusting some of the samples before the test. Radiator degradation was determined by measuring the change in the emittance after dust was deposited and/or removed. The principal mode of degradation was abrasion. Arc-textured Nb-1%Zr proved to be more susceptible to degradation than Cu, and pre-dusting appeared to have lessened the abrasion

  17. Modeling the emission, transport and deposition of contaminated dust from a mine tailing site.

    Science.gov (United States)

    Stovern, Michael; Betterton, Eric A; Sáez, A Eduardo; Villar, Omar Ignacio Felix; Rine, Kyle P; Russell, Mackenzie R; King, Matt

    2014-01-01

    Mining operations are potential sources of airborne particulate metal and metalloid contaminants through both direct smelter emissions and wind erosion of mine tailings. The warmer, drier conditions predicted for the Southwestern US by climate models may make contaminated atmospheric dust and aerosols increasingly important, due to potential deleterious effects on human health and ecology. Dust emissions and dispersion of contaminants from the Iron King Mine tailings in Dewey-Humboldt, Arizona, a Superfund site, are currently being investigated through in situ field measurements and computational fluid dynamics modeling. These tailings are significantly contaminated with lead and arsenic with an average soil concentration of 1616 and 1420 ppm, respectively. Similar levels of these contaminants have also been measured in soil samples taken from the area surrounding the mine tailings. Using a computational fluid dynamics model, we have been able to model dust transport from the mine tailings to the surrounding region. The model includes a distributed Eulerian model to simulate fine aerosol transport and a Lagrangian approach to model fate and transport of larger particles. In order to improve the accuracy of the dust transport simulations both regional topographical features and local weather patterns have been incorporated into the model simulations.

  18. Analysis of Dust Samples Collected from an Unused Spent Nuclear Fuel Interim Storage Container at Hope Creek, Delaware.

    Energy Technology Data Exchange (ETDEWEB)

    Bryan, Charles R. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Enos, David [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-03-01

    In July, 2014, the Electric Power Research Institute and industry partners sampled dust on the surface of an unused canister that had been stored in an overpack at the Hope Creek Nuclear Generating Station for approximately one year. The foreign material exclusion (FME) cover that had been on the top of the canister during storage, and a second recently - removed FME cover, were also sampled. This report summarizes the results of analyses of dust samples collected from the unused Hope Creek canister and the FME covers. Both wet and dry samples of the dust/salts were collected, using SaltSmart(TM) sensors and Scotch - Brite(TM) abrasive pads, respectively. The SaltSmart(TM) samples were leached and the leachate analyzed chemically to determine the composition and surface load per unit area of soluble salts present on the canister surface. The dry pad samples were analyzed by X-ray fluorescence and by scanning electron microscopy to determine dust texture and mineralogy; and by leaching and chemical analysis to deter mine soluble salt compositions. The analyses showed that the dominant particles on the canister surface were stainless steel particles, generated during manufacturing of the canister. Sparse environmentally - derived silicates and aluminosilicates were also present. Salt phases were sparse, and consisted of mostly of sulfates with rare nitrates and chlorides. On the FME covers, the dusts were mostly silicates/aluminosilicates; the soluble salts were consistent with those on the canister surface, and were dominantly sulfates. It should be noted that the FME covers were w ashed by rain prior to sampling, which had an unknown effect of the measured salt loads and compositions. Sulfate salts dominated the assemblages on the canister and FME surfaces, and in cluded Ca - SO4 , but also Na - SO4 , K - SO4 , and Na - Al - SO4 . It is likely that these salts were formed by particle - gas conversion reactions, either

  19. Distributions, sources and pollution status of 17 trace metal/metalloids in the street dust of a heavily industrialized city of central China

    International Nuclear Information System (INIS)

    Li, Zhonggen; Feng, Xinbin; Li, Guanghui; Bi, Xiangyang; Zhu, Jianming; Qin, Haibo; Dai, Zhihui; Liu, Jinling; Li, Qiuhua; Sun, Guangyi

    2013-01-01

    A series of representative street dust samples were collected from a heavily industrialized city, Zhuzhou, in central China, with the aim to investigate the spatial distribution and pollution status of 17 trace metal/metalloid elements. Concentrations of twelve elements (Pb, Zn, Cu, Cd, Hg, As, Sb, In, Bi, Tl, Ag and Ga) were distinctly amplified by atmospheric deposition resulting from a large scale Pb/Zn smelter located in the northwest fringe of the city, and followed a declining trend towards the city center. Three metals (W, Mo and Co) were enriched in samples very close to a hard alloy manufacturing plant, while Ni and Cr appeared to derive predominantly from natural sources. Other industries and traffic had neglectable effects on the accumulation of observed elements. Cd, In, Zn, Ag and Pb were the five metal/metalloids with highest pollution levels and the northwestern part of city is especially affected by heavy metal pollution. -- Highlights: •Large-scale Pb/Zn smelters contributed to elevated trace elements in the street dust. •The hard alloy processing caused the enrichment of a few elements. •Cd, In, Zn, Ag and Pb were the most polluted elements. •Northwestern Zhuzhou suffered severe contamination for a range of trace elements. -- Pb/Zn smelting and hard alloy processing operations have caused seriously contamination of trace metal/metalloids in the street dust

  20. Quantifying Anthropogenic Dust Emissions

    Science.gov (United States)

    Webb, Nicholas P.; Pierre, Caroline

    2018-02-01

    Anthropogenic land use and land cover change, including local environmental disturbances, moderate rates of wind-driven soil erosion and dust emission. These human-dust cycle interactions impact ecosystems and agricultural production, air quality, human health, biogeochemical cycles, and climate. While the impacts of land use activities and land management on aeolian processes can be profound, the interactions are often complex and assessments of anthropogenic dust loads at all scales remain highly uncertain. Here, we critically review the drivers of anthropogenic dust emission and current evaluation approaches. We then identify and describe opportunities to: (1) develop new conceptual frameworks and interdisciplinary approaches that draw on ecological state-and-transition models to improve the accuracy and relevance of assessments of anthropogenic dust emissions; (2) improve model fidelity and capacity for change detection to quantify anthropogenic impacts on aeolian processes; and (3) enhance field research and monitoring networks to support dust model applications to evaluate the impacts of disturbance processes on local to global-scale wind erosion and dust emissions.

  1. Comparison of two indices of exposure to polycyclic aromatic hydrocarbons in a retrospective aluminium smelter cohort

    Energy Technology Data Exchange (ETDEWEB)

    Friesen, M.C.; Demers, P.A.; Spinelli, J.J.; Lorenzi, M.F.; Le, N.D. [University of British Columbia, Vancouver, BC (Canada)

    2007-04-15

    The association between coal tar-derived substances, a complex mixture of polycyclic aromatic hydrocarbons, and cancer is well established. However, the specific aetiological agents are unknown. The paper compares the dos-response relationships for two common measures of coal tar-derived substances, benzene-soluble material (BSM) and benzo (a) pyrene (BaP), and to evaluate which among these is more strongly related to the health outcomes. The study population consisted of 6423 men with {gt} 3 years of work experience at an aluminium smelter (1954 - 97). Three health outcomes identified from national mortality and cancer databases were evaluated: incidence of bladder cancer (n = 90), incidence of lung cancer (n = 147) and mortality due to acute myocardial infarction (AMI, n = 184). The shape, magnitude and precision of the dose - response relationships and cumulative exposure levels for BSM and BaP were evaluated. Two model structures were assessed, where 1n (relative risk) increased with cumulative exposure (log-linear model) or with log- transformed cumulative exposure (log-log model). It was found that BaP and BSM were both strongly associated with bladder and lung cancer and modestly associated with AMI. Similar conclusions regarding the associations could be made regardless of the exposure metric.

  2. Spirit Feels Dust Gust

    Science.gov (United States)

    2007-01-01

    On sol 1149 (March 28, 2007) of its mission, NASA's Mars Exploration Rover Spirit caught a wind gust with its navigation camera. A series of navigation camera images were strung together to create this movie. The front of the gust is observable because it was strong enough to lift up dust. From assessing the trajectory of this gust, the atmospheric science team concludes that it is possible that it passed over the rover. There was, however, no noticeable increase in power associated with this gust. In the past, dust devils and gusts have wiped the solar panels of dust, making it easier for the solar panels to absorb sunlight.

  3. Aquatic Life Criteria - Copper

    Science.gov (United States)

    Documents pertain to Aquatic Life Ambient Water Quality criteria for Copper (2007 Freshwater, 2016 Estuarine/marine). These documents contain the safe levels of Copper in water that should protect to the majority of species.

  4. Copper Bioleaching in Chile

    OpenAIRE

    Juan Carlos Gentina; Fernando Acevedo

    2016-01-01

    Chile has a great tradition of producing and exporting copper. Over the last several decades, it has become the first producer on an international level. Its copper reserves are also the most important on the planet. However, after years of mineral exploitation, the ease of extracting copper oxides and ore copper content has diminished. To keep the production level high, the introduction of new technologies has become necessary. One that has been successful is bioleaching. Chile had the first...

  5. Demystifying Controlling Copper Corrosion

    Science.gov (United States)

    The LCR systematically misses the highest health and corrosion risk sites for copper. Additionally, there are growing concerns for WWTP copper in sludges and discharge levels. There are many corrosion control differences between copper and lead. This talk explains the sometimes c...

  6. Galactic dust and extinction

    International Nuclear Information System (INIS)

    Lyngaa, G.

    1979-01-01

    The ratio R between visual extinction and colour excess, is slightly larger than 3 and does not vary much throughout our part of the Galaxy. The distribution of dust in the galactic plane shows, on the large scale, a gradient with higher colour excesses towards l=50 0 than towards l=230 0 . On the smaller scale, much of the dust responsible for extinction is situated in clouds which tend to group together. The correlation between positions of interstellar dust clouds and positions of spiral tracers seems rather poor in our Galaxy. However, concentrated dark clouds as well as extended regions of dust show an inclined distribution similar to the Gould belt of bright stars. (Auth.)

  7. Radioisotope dust pollution monitor

    International Nuclear Information System (INIS)

    Szepke, R.; Harasimczuk, J.; Dobrowiecki, J.

    1990-01-01

    Measuring principles and specification of two dust monitors: station-type AMIZ and portable-type PIK-10 for ambient air pollution are presented. The first one, a fully automatic instrument is destined for permanent monitoring of air pollution in preset sampling time from .25 to 24 hours. The second one was developed as a portable working model. Both instruments display their results in digital form in dust concentration units. (author)

  8. Coal dust symposium

    Energy Technology Data Exchange (ETDEWEB)

    1981-03-01

    This paper gives a report of the paper presented at the symposium held in Hanover on 9 and 10 February 1981. The topics include: the behaviour of dust and coal dust on combustion and explosion; a report on the accidents which occurred at the Laegerdorf cement works' coal crushing and drying plant; current safety requirements at coal crushing and drying plant; and coal crushing and drying. Four papers are individually abstracted. (In German)

  9. Dust devil generation

    International Nuclear Information System (INIS)

    G Onishchenko, O; A Pokhotelov, O; Horton, W; Stenflo, L

    2014-01-01

    The equations describing axi-symmetric nonlinear internal gravity waves in an unstable atmosphere are derived. A hydrodynamic model of a dust devil generation mechanism in such an atmosphere is investigated. It is shown that in an unstably stratified atmosphere the convective plumes with poloidal motion can grow exponentially. Furthermore, it is demonstrated that these convective plumes in an atmosphere with weak large scale toroidal motion are unstable with respect to three-dimensional dust devil generation. (papers)

  10. Mapping airborne lead contamination near a metals smelter in Derbyshire, UK: spatial variation of Pb concentration and 'enrichment factor' for tree bark.

    Science.gov (United States)

    Bellis, D; Cox, A J; Staton, I; McLeod, C W; Satake, K

    2001-10-01

    Samples of tree bark, collected over an area of 4 km2 near a small non-ferrous metals smelter in Derbyshire, UK, were analysed for Pb and Al by inductively coupled plasma atomic emission spectroscopy (ICP-AES). Analyte concentrations varied from 100 to over 25,000 mg kg-1 and 5 to 1000 mg kg-1, respectively. While an inverse relationship between the Pb content of bark and distance from the smelter was observed, concentrations fluctuated, indicating a variability in sample collection efficiency and problems in standardization. To overcome these effects, the Pb/Al ratio was calculated and subsequently normalized to the average Pb/Al ratio in continental crust (0.00015). On the assumption that the time-averaged concentration of airborne Al in this area is relatively constant and derived principally from wind-blown soil, the measurement represents an anthropogenic 'enrichment factor' (PbEF). PbEF varied from 10,000 to over 1,000,000, and showed a consistent reduction with distance from the smelter. Isolines of equal PbEF were subsequently defined on a map of the sampled area. Pb contamination was greatest in the vicinity of the smelter, and preferential transport along the NW-SE axis of the valley (in which the smelter is situated) was observed. The use of enrichment factors thus proved valuable in defining the relative level of airborne-derived Pb pollution.

  11. Chemical-mineralogical characterization of copper smelting flue dust

    Directory of Open Access Journals (Sweden)

    Eduardo Balladares

    2014-01-01

    Full Text Available En el procesamiento pirometalúrgico del cobre, hasta 10% de la carga alimentada a los hornos sale de estos en forma de polvo arrastrado por los gases conteniendo la mayor parte de las impurezas presentes en el mineral, así como cantidades significativas de cobre por lo que no pueden ser descartados como residuos industriales y debe tratarse para recuperar el cobre. La conceptualización de nuevos y mejores procesos requiere caracterizaciones de estos materiales más precisas. Se analizaron polvos provenientes de una caldera recuperadora de calor y de un precipitador electrostático, ambos de un horno de fusión instantánea. Las diferentes herramientas analíticas empleadas muestran que el cobre y el hierro se encuentran principalmente en fases solubles en agua tales como chalcantita. La fracción insoluble está formada mayoritariamente por hematita y magnetita, con probable presencia de delafosita. Parte del cobre detectada en la fracción insoluble se asocia al hierro en forma de espinela.

  12. Visualisation and quantification of heavy metal accessibility in smelter slags: The influence of morphology on availability.

    Science.gov (United States)

    Morrison, Anthony L; Swierczek, Zofia; Gulson, Brian L

    2016-03-01

    The Imperial Smelting Furnace (ISF) for producing lead and zinc simultaneously has operated on four continents and in eleven countries from the 1950's. One of the process changes that the ISF introduced was the production of a finely granulated slag waste. Although this slag contained significant amounts of residual lead (Pb) and zinc (Zn), because of its glassy nature it was considered environmentally benign. From the Cockle Creek smelter near Boolaroo at the northern end of Lake Macquarie, NSW, Australia, it is estimated that around 2.1 million tonnes of the fine slag was distributed into the community and most remains where it was originally utilised. Residual tonnages of slag of this magnitude are common worldwide wherever the ISF operated. Studies of base metal smelting slags have concluded that mineralogical and morphological characteristics of the slag play a critical role in moderating environmental release of toxic elements. Scanning electron microscopy (SEM) and microanalysis of the ISF slags has shown that the Pb and associated elements are present as discrete nodules (∼6-22 μm) in the slag and that they are not associated with Zn which is contained in the glass slag phase. Using an automated SEM and analysis technique (QEMSCAN(®)) to "map" the mineralogical structure of the particles, it was possible to quantitatively determine the degree of access infiltrating fluids might have to the reaction surface of the Pb phases. The level of access decreases with increasing particle size, but in even the largest sized particles (-3350 + 2000 μm) nearly 80% of the Pb-containing phases were totally or partially accessible. These results provide evidence that the toxic elements in the slags are not contained by the glassy phase and will be vulnerable to leaching over time depending on their individual phase reactivity. Copyright © 2015 Elsevier Ltd. All rights reserved.

  13. Characterizing Zinc Speciation in Soils from a Smelter-Affected Boreal Forest Ecosystem.

    Science.gov (United States)

    Hamilton, Jordan G; Farrell, Richard E; Chen, Ning; Feng, Renfei; Reid, Joel; Peak, Derek

    2016-03-01

    HudBay Minerals, Inc., has mined and/or processed Zn and Cu ore in Flin Flon, MB, Canada, since the 1930s. The boreal forest ecosystem and soil surrounding these facilities have been severely impacted by mixed metal contamination and HSO deposition. Zinc is one of the most prevalent smelter-derived contaminants and has been identified as a key factor that may be limiting revegetation. Metal toxicity is related to both total concentrations and speciation; therefore, X-ray absorption spectroscopy and X-ray fluorescence mapping were used to characterize Zn speciation in soils throughout the most heavily contaminated areas of the landscape. Zinc speciation was linked to two distinct soil types. Group I soils consist of exposed soils in weathered positions of bedrock outcrops with Zn present primarily as franklinite, a (ZnFeO) spinel mineral. Group II soils are stabilized by an invasive metal-tolerant grass species, with Zn found as a mixture of octahedral (Fe oxides) and tetrahedral Mn oxides) adsorption complexes with a franklinite component. Soil erosion influences Zn speciation through the redistribution of Zn and soil particulates from Group I landscape positions to Group II soils. Despite Group II soils having the highest concentrations of CaCl-extractable Zn, they support metal-tolerant plant growth. The metal-tolerant plants are probably preferentially colonizing these areas due to better soil and nutrient conditions as a result of soil deposition from upslope Group I areas. Zinc concentration and speciation appears to not influence the colonization by metal-tolerant grasses, but the overall soil properties and erosion effects prevent the revegetation by native boreal forest species. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  14. Bioaccumulation of heavy metals, metalloids, and chlorine in ectomycorrhizae from smelter-polluted area.

    Science.gov (United States)

    Cejpková, Jaroslava; Gryndler, Milan; Hršelová, Hana; Kotrba, Pavel; Řanda, Zdeněk; Synková, Iva; Borovička, Jan

    2016-11-01

    Ectomycorrhizal (ECM) fungi contribute to the survival of host trees on metal-rich soils by reducing the transfer of toxic metals into roots. However, little is known about the ability of ECM fungi to accumulate elements in ectomycorrhizae (ECMs). Here we report Ag, As, Cd, Cl, Cu, Sb, V, and Zn contents in wild-grown Norway spruce ECMs collected in a smelter-polluted area at Lhota near Příbram, Czech Republic. The ECMs data were compared with the element concentrations determined in the corresponding non-mycorrhizal fine roots, soils, and soil extracts. Bioaccumulation factors were calculated to differentiate the element accumulation ability of ECMs inhabited by different mycobionts, which were identified by ITS rDNA sequencing. Among the target elements, the highest contents were observed for Ag, Cl, Cd, and Zn; Imleria badia ECMs showed the highest capability to accumulate these elements. ECMs of Amanita muscaria, but not of other species, accumulated V. The analysis of the proportions of I. badia and A. muscaria mycelia in ECMs by using species-specific quantitative real-time PCR revealed variable extent of the colonization of roots, with median values close to 5% (w/w). Calculated Ag, Cd, Zn and Cl concentrations in the mycelium of I. badia ECMs were 1 680, 1 510, 2 670, and 37,100 mg kg -1 dry weight, respectively, indicating substantial element accumulation capacity of hyphae of this species in ECMs. Our data strengthen the idea of an active role of ECM fungi in soil-fungal-plant interactions in polluted environments. Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. Fractal dust grains in plasma

    International Nuclear Information System (INIS)

    Huang, F.; Peng, R. D.; Liu, Y. H.; Chen, Z. Y.; Ye, M. F.; Wang, L.

    2012-01-01

    Fractal dust grains of different shapes are observed in a radially confined magnetized radio frequency plasma. The fractal dimensions of the dust structures in two-dimensional (2D) horizontal dust layers are calculated, and their evolution in the dust growth process is investigated. It is found that as the dust grains grow the fractal dimension of the dust structure decreases. In addition, the fractal dimension of the center region is larger than that of the entire region in the 2D dust layer. In the initial growth stage, the small dust particulates at a high number density in a 2D layer tend to fill space as a normal surface with fractal dimension D = 2. The mechanism of the formation of fractal dust grains is discussed.

  16. Evidence-based integrated environmental solutions for secondary lead smelters: Pollution prevention and waste minimization technologies and practices

    Energy Technology Data Exchange (ETDEWEB)

    Genaidy, A.M., E-mail: world_tek_inc@yahoo.com [University of Cincinnati, Cincinnati, Ohio (United States); Sequeira, R. [University of Cincinnati, Cincinnati, Ohio (United States); Tolaymat, T. [U.S. Environmental Protection Agency, Office of Research and Development, Cincinnati, Ohio (United States); Kohler, J. [US Environmental Protection Agency, Office of Solid Waste and Emergency Response, Washington DC (United States); Rinder, M. [WorldTek Inc, Cincinnati (United States)

    2009-05-01

    An evidence-based methodology was adopted in this research to establish strategies to increase lead recovery and recycling via a systematic review and critical appraisal of the published literature. In particular, the research examines pollution prevention and waste minimization practices and technologies that meet the following criteria: (a) reduce/recover/recycle the largest quantities of lead currently being disposed of as waste, (b) technically and economically viable, that is, ready to be diffused and easily transferable, and (c) strong industry interest (i.e., industry would consider implementing projects with higher payback periods). The following specific aims are designed to achieve the study objectives: Aim 1 - To describe the recycling process of recovering refined lead from scrap; Aim 2 - To document pollution prevention and waste management technologies and practices adopted by US stakeholders along the trajectory of LAB and lead product life cycle; Aim 3 - To explore improved practices and technologies which are employed by other organizations with an emphasis on the aforementioned criteria; Aim 4 - To demonstrate the economic and environmental costs and benefits of applying improved technologies and practices to existing US smelting operations; and Aim 5 - To evaluate improved environmental technologies and practices using an algorithm that integrates quantitative and qualitative criteria. The process of identifying relevant articles and reports was documented. The description of evidence was presented for current practices and technologies used by US smelters as well as improved practices and technologies. Options for integrated environmental solutions for secondary smelters were introduced and rank ordered on the basis of costs (i.e., capital investment) and benefits (i.e., production increases, energy and flux savings, and reduction of SO2 and slag). An example was provided to demonstrate the utility of the algorithm by detailing the costs and

  17. Evidence-based integrated environmental solutions for secondary lead smelters: pollution prevention and waste minimization technologies and practices.

    Science.gov (United States)

    Genaidy, A M; Sequeira, R; Tolaymat, T; Kohler, J; Rinder, M

    2009-05-01

    An evidence-based methodology was adopted in this research to establish strategies to increase lead recovery and recycling via a systematic review and critical appraisal of the published literature. In particular, the research examines pollution prevention and waste minimization practices and technologies that meet the following criteria: (a) reduce/recover/recycle the largest quantities of lead currently being disposed of as waste, (b) technically and economically viable, that is, ready to be diffused and easily transferable, and (c) strong industry interest (i.e., industry would consider implementing projects with higher payback periods). The following specific aims are designed to achieve the study objectives: Aim 1 - To describe the recycling process of recovering refined lead from scrap; Aim 2 - To document pollution prevention and waste management technologies and practices adopted by US stakeholders along the trajectory of LAB and lead product life cycle; Aim 3 - To explore improved practices and technologies which are employed by other organizations with an emphasis on the aforementioned criteria; Aim 4 - To demonstrate the economic and environmental costs and benefits of applying improved technologies and practices to existing US smelting operations; and Aim 5 - To evaluate improved environmental technologies and practices using an algorithm that integrates quantitative and qualitative criteria. The process of identifying relevant articles and reports was documented. The description of evidence was presented for current practices and technologies used by US smelters as well as improved practices and technologies. Options for integrated environmental solutions for secondary smelters were introduced and rank ordered on the basis of costs (i.e., capital investment) and benefits (i.e., production increases, energy and flux savings, and reduction of SO(2) and slag). An example was provided to demonstrate the utility of the algorithm by detailing the costs and

  18. Sahara Dust Cloud

    Science.gov (United States)

    2005-01-01

    [figure removed for brevity, see original site] Dust Particles Click on the image for Quicktime movie from 7/15-7/24 A continent-sized cloud of hot air and dust originating from the Sahara Desert crossed the Atlantic Ocean and headed towards Florida and the Caribbean. A Saharan Air Layer, or SAL, forms when dry air and dust rise from Africa's west coast and ride the trade winds above the Atlantic Ocean. These dust clouds are not uncommon, especially during the months of July and August. They start when weather patterns called tropical waves pick up dust from the desert in North Africa, carry it a couple of miles into the atmosphere and drift westward. In a sequence of images created by data acquired by the Earth-orbiting Atmospheric Infrared Sounder ranging from July 15 through July 24, we see the distribution of the cloud in the atmosphere as it swirls off of Africa and heads across the ocean to the west. Using the unique silicate spectral signatures of dust in the thermal infrared, AIRS can detect the presence of dust in the atmosphere day or night. This detection works best if there are no clouds present on top of the dust; when clouds are present, they can interfere with the signal, making it much harder to detect dust as in the case of July 24, 2005. In the Quicktime movie, the scale at the bottom of the images shows +1 for dust definitely detected, and ranges down to -1 for no dust detected. The plots are averaged over a number of AIRS observations falling within grid boxes, and so it is possible to obtain fractional numbers. [figure removed for brevity, see original site] Total Water Vapor in the Atmosphere Around the Dust Cloud Click on the image for Quicktime movie The dust cloud is contained within a dry adiabatic layer which originates over the Sahara Desert. This Saharan Air Layer (SAL) advances Westward over the Atlantic Ocean, overriding the cool, moist air nearer the surface. This burst of very dry air is visible in the AIRS retrieved total water

  19. Electrodynamic Dust Shield Demonstrator

    Science.gov (United States)

    Stankie, Charles G.

    2013-01-01

    The objective of the project was to design and manufacture a device to demonstrate a new technology developed by NASA's Electrostatics and Surface Physics Laboratory. The technology itself is a system which uses magnetic principles to remove regolith dust from its surface. This project was to create an enclosure that will be used to demonstrate the effectiveness of the invention to The Office of the Chief Technologist. ONE of the most important challenges of space exploration is actually caused by something very small and seemingly insignificant. Dust in space, most notably on the moon and Mars, has caused many unforeseen issues. Dirt and dust on Earth, while a nuisance, can be easily cleaned and kept at bay. However, there is considerably less weathering and erosion in space. As a result, the microscopic particles are extremely rough and abrasive. They are also electrostatically charged, so they cling to everything they make contact with. This was first noted to be a major problem during the Apollo missions. Dust would stick to the spacesuits, and could not be wiped off as predicted. Dust was brought back into the spacecraft, and was even inhaled by astronauts. This is a major health hazard. Atmospheric storms and other events can also cause dust to coat surfaces of spacecraft. This can cause abrasive damage to the craft. The coating can also reduce the effectiveness of thermal insulation and solar panels.' A group of engineers at Kennedy Space Center's Electrostatics and Surface Physics Laboratory have developed a new technology, called the Electrodynamic Dust Shield, to help alleviate these problems. It is based off of the electric curtain concept developed at NASA in 1967. "The EDS is an active dust mitigation technology that uses traveling electric fields to transport electrostatically charged dust particles along surfaces. To generate the traveling electric fields, the EDS consists of a multilayer dielectric coating with an embedded thin electrode grid

  20. Analysis of metal(loid)s contamination and their continuous input in soils around a zinc smelter: Development of methodology and a case study in South Korea.

    Science.gov (United States)

    Yun, Sung-Wook; Baveye, Philippe C; Kim, Dong-Hyeon; Kang, Dong-Hyeon; Lee, Si-Young; Kong, Min-Jae; Park, Chan-Gi; Kim, Hae-Do; Son, Jinkwan; Yu, Chan

    2018-07-01

    Soil contamination due to atmospheric deposition of metals originating from smelters is a global environmental problem. A common problem associated with this contamination is the discrimination between anthropic and natural contributions to soil metal concentrations: In this context, we investigated the characteristics of soil contamination in the surrounding area of a world class smelter. We attempted to combine several approaches in order to identify sources of metals in soils and to examine contamination characteristics, such as pollution level, range, and spatial distribution. Soil samples were collected at 100 sites during a field survey and total concentrations of As, Cd, Cr, Cu, Fe, Hg, Ni, Pb, and Zn were analyzed. We conducted a multivariate statistical analysis, and also examined the spatial distribution by 1) identifying the horizontal variation of metals according to particular wind directions and distance from the smelter and 2) drawing a distribution map by means of a GIS tool. As, Cd, Cu, Hg, Pb, and Zn in the soil were found to originate from smelter emissions, and As also originated from other sources such as abandoned mines and waste landfill. Among anthropogenic metals, the horizontal distribution of Cd, Hg, Pb, and Zn according to the downwind direction and distance from the smelter showed a typical feature of atmospheric deposition (regression model: y = y 0  + αe -βx ). Lithogenic Fe was used as an indicator, and it revealed the continuous input and accumulation of these four elements in the surrounding soils. Our approach was effective in clearly identifying the sources of metals and analyzing their contamination characteristics. We believe this study will provide useful information to future studies on soil pollution by metals around smelters. Copyright © 2018 Elsevier Ltd. All rights reserved.

  1. Comparison of the physical and chemical characteristics of fine road dust at different urban sites.

    Science.gov (United States)

    Lee, Kwang Yul; Batmunkh, Tsatsral; Joo, Hung Soo; Park, Kihong

    2018-04-18

    The size distribution and chemical components of a fine fraction (road dust collected at urban sites in Korea (Gwangju) and Mongolia (Ulaanbaatar) where distinct urban characteristics exist were measured. A clear bimodal size distribution was observed for the resuspended fine road dust at the urban sites in Korea. The first mode peaked at 100-110 nm, and the second peak was observed at 435-570 nm. Ultrafine mode (~30 nm) was found for the fine road dust at the Mongolia site, which was significantly affected by residential coal/biomass burning. The contribution of the water-soluble ions to the fine road dust was higher at the sites in Mongolia (15.8-16.8%) than at those in Korea (1.2-4.8%). Sulfate and chloride were the most dominant ionic species for the fine road dust in Mongolia. As (arsenic) was also much higher for the Mongolian road dust than the others. The sulfate, chloride, and As mainly come from coal burning activity, suggesting that coal and biomass combustion in Mongolia during the heating season should affect the size and chemical components of the fine road dust. Cu (copper) and Zn (zinc), carbonaceous particles (organic carbon [OC] and elemental carbon [EC]) increased at sites in Korea, suggesting that the fine road dust at these sites was significantly affected by the high volume of traffic (engine emission and brake/tire wear). Our results suggest that chemical profiles for road dust specific to certain sites should be applied to more accurately apportion road dust source contributing to the ambient particulate matter. Size and chemical characteristics of fine road dust at sites having distinct urban characteristics were examined. Residential coal and biomass burning and traffic affected physiochemical properties of the fine road dust. Different road dust profiles at different sites should be needed to determine the ambient PM2.5 sources more accurately.

  2. Dust in planetary nebulae

    International Nuclear Information System (INIS)

    Kwok, S.

    1980-01-01

    A two-component dust model is suggested to explain the infrared emission from planetary nebulae. A cold dust component located in the extensive remnant of the red-giant envelope exterior to the visible nebula is responsible for the far-infrared emission. A ward dust component, which is condensed after the formation of the planetary nebula and confined within the ionized gas shell, emits most of the near- and mid-infrared radiation. The observations of NGC 7027 are shown to be consisten with such a model. The correlation of silicate emission in several planetary nebulae with an approximately +1 spectral index at low radio frequencies suggests that both the silicate and radio emissions originate from the remnant of the circumstellar envelope of th precursor star and are observable only while the planetary nebula is young. It is argued that oxygen-rich stars as well as carbon-rich stars can be progenitors of planetary nebulae

  3. Interstellar dust and extinction

    International Nuclear Information System (INIS)

    Mathis, J.S.

    1990-01-01

    It is noted that the term interstellar dust refers to materials with rather different properties, and that the mean extinction law of Seaton (1979) or Savage and Mathis (1979) should be replaced by the expression given by Cardelli et al. (1989), using the appropriate value of total-to-selective extinction. The older laws were appropriate for the diffuse ISM but dust in clouds differs dramatically in its extinction law. Dust is heavily processed while in the ISM by being included within clouds and cycled back into the diffuse ISM many times during its lifetime. Hence, grains probably reflect only a trace of their origin, although meteoritic inclusions with isotopic anomalies demonstrate that some tiny particles survive intact from a supernova origin to the present. 186 refs

  4. Dust control for draglines

    Energy Technology Data Exchange (ETDEWEB)

    Grad, P.

    2009-09-15

    Monitoring dust levels inside draglines reveals room for improvement in how filtration systems are used and maintained. The Australian firm BMT conducted a field test program to measure airflow parameters, dust fallout rates and dust concentrations, inside and outside the machine house, on four draglines and one shovel. The study involved computational fluid dynamics (CFD) simulations. The article describes how the tests were made and gives results. It was not possible to say which of the two main filtration systems currently used on Australian draglines - Dynavane or Floseps - performs better. It would appear that more frequent maintenance and cleaning would increase the overall filtration performance and systems could be susceptible to repeat clogging in a short time. 2 figs., 1 photos.

  5. DustEM: Dust extinction and emission modelling

    Science.gov (United States)

    Compiègne, M.; Verstraete, L.; Jones, A.; Bernard, J.-P.; Boulanger, F.; Flagey, N.; Le Bourlot, J.; Paradis, D.; Ysard, N.

    2013-07-01

    DustEM computes the extinction and the emission of interstellar dust grains heated by photons. It is written in Fortran 95 and is jointly developed by IAS and CESR. The dust emission is calculated in the optically thin limit (no radiative transfer) and the default spectral range is 40 to 108 nm. The code is designed so dust properties can easily be changed and mixed and to allow for the inclusion of new grain physics.

  6. Dust-Plasma Interactions

    International Nuclear Information System (INIS)

    Rosenberg, M.

    2010-01-01

    The objective of our theoretical research under this grant over the past 3 years was to develop new understanding in a range of topics in the physics of dust-plasma interactions, with application to space and the laboratory. We conducted studies related to the physical properties of dust, waves and instabilities in both weakly coupled and strongly coupled dusty plasmas, and innovative possible applications. A major consideration in our choice of topics was to compare theory with experiments or observations, and to motivate new experiments, which we believe is important for developing this relatively new field. Our research is summarized, with reference to our list of journal publications.

  7. Hypervelocity Microparticle Impact Studies: Simulating Cosmic Dust Impacts on the Dustbuster

    Science.gov (United States)

    Austin, D. E.; Manning, H. L. K.; Bailey, C. L.; Farnsworth, J. T.; Ahrens, T. J.; Beauchamp, J. L.

    2002-01-01

    Iron and copper microparticles accelerated to 2-20 km/s in a 2 MV Van de Graaff accelerator were used to test a recently-developed cosmic dust mass spectrometer, known as the Dustbuster. Additional information is contained in the original extended abstract.

  8. The impact of aluminium smelter shut-down on the concentration of fluoride in vegetation and soils

    International Nuclear Information System (INIS)

    Brougham, Kate M.; Roberts, Stephen R.; Davison, Alan W.; Port, Gordon R.

    2013-01-01

    Although a great deal is known about the deposition of fluoride on vegetation, and the hazards associated with uptake by grazing herbivores, little is known about what happens to the concentration of fluoride in vegetation and soil at polluted sites once deposition ceases. The closure of Anglesey Aluminium Metals Ltd smelter, in September 2009, provided a unique opportunity to study fluoride loading once deposition stopped. Fluoride was monitored in plants and soil within 1 km of the former emission source. Fluoride concentrations in a range of plant material had decreased to background levels of 10 mg F kg −1 after 36 weeks. Concentrations of fluoride in mineral-rich soils decreased steadily demonstrating their limited potential to act as contaminating sources of fluoride for forage uptake. There were significant differences in the rate of decline of fluoride concentrations between plant species. -- Highlights: •The impact of aluminium smelter closure on fluoride concentrations was investigated. •Concentrations in forage decreased rapidly to safe levels for livestock grazing. •The concentrations in some species declined to background levels within a year. •Significant interspecies differences in fluoride decline are described. •Mineral-rich soils have limited potential as contaminating sources for forage. -- Fluoride is hazardous to grazing herbivores, but when deposition stops, F-levels in plants and soil fall rapidly, some returning to background concentrations within a year

  9. Impacts of landscape remediation on the heavy metal pollution dynamics of a lake surrounded by non-ferrous smelter waste

    International Nuclear Information System (INIS)

    Blake, William H.; Walsh, Rory P.D.; Reed, Jane M.; Barnsley, Michael J.; Smith, Jamie

    2007-01-01

    Heavy metal concentrations and potential bioavailability are reported for sediment in a shallow flood detention lake surrounded by reclaimed, smelter-contaminated land. A range of sediment column proxy indicators is used to explore changes in pollution dynamics with remediation. Sediment concentrations of Pb and Zn are high at ∼600 and 20 000 mg kg -1 , respectively. Less than 7% of total Pb is potentially bioavailable following sequential extraction as opposed to 47% of Zn. Metal transfer mechanisms to lake sediment include detrital inputs, scavenging by particulates and biogeochemical precipitation. Sedimentary evidence indicates that detrital inputs to the lake declined following land reclamation after which it is proposed that dissolved inputs increased with leaching of reworked waste material. Whilst downcore metal profiles may be subject to post-depositional change, diatom analysis suggests more recent improvements in water quality. The potential for post-remediation pollution episodes relating to metal release from historic sedimentary stores should be considered in future remediation strategies. - The contaminant hydrology of reworked smelter spoil is complex

  10. Impacts of landscape remediation on the heavy metal pollution dynamics of a lake surrounded by non-ferrous smelter waste

    Energy Technology Data Exchange (ETDEWEB)

    Blake, William H. [Department of Geography, University of Wales, Swansea SA2 8PP (United Kingdom)]. E-mail: william.blake@plymouth.ac.uk; Walsh, Rory P.D. [Department of Geography, University of Wales, Swansea SA2 8PP (United Kingdom); Reed, Jane M. [Department of Geography, University of Hull, Cottingham Road, Hull HU6 7RX (United Kingdom); Barnsley, Michael J. [Department of Geography, University of Wales, Swansea SA2 8PP (United Kingdom); Smith, Jamie [Department of Geography, University of Wales, Swansea SA2 8PP (United Kingdom)

    2007-07-15

    Heavy metal concentrations and potential bioavailability are reported for sediment in a shallow flood detention lake surrounded by reclaimed, smelter-contaminated land. A range of sediment column proxy indicators is used to explore changes in pollution dynamics with remediation. Sediment concentrations of Pb and Zn are high at {approx}600 and 20 000 mg kg{sup -1}, respectively. Less than 7% of total Pb is potentially bioavailable following sequential extraction as opposed to 47% of Zn. Metal transfer mechanisms to lake sediment include detrital inputs, scavenging by particulates and biogeochemical precipitation. Sedimentary evidence indicates that detrital inputs to the lake declined following land reclamation after which it is proposed that dissolved inputs increased with leaching of reworked waste material. Whilst downcore metal profiles may be subject to post-depositional change, diatom analysis suggests more recent improvements in water quality. The potential for post-remediation pollution episodes relating to metal release from historic sedimentary stores should be considered in future remediation strategies. - The contaminant hydrology of reworked smelter spoil is complex.

  11. Control of harmful dust in coal mines

    Energy Technology Data Exchange (ETDEWEB)

    Goddard, B; Bower, K; Mitchell, D

    1973-01-01

    This handbook consists of a series of short chapters devoted to: sources of airborne dust; dust standards and methods of sampling; dust prevention on mechanized faces; ventilation and dust extraction; distribution and use of water; dust control on mechanized faces; dust control in drivages and headings; drilling and shotfiring; dust control in transport; some outbye dust control techniques (hygroscopic salts, impingement curtains); water infusion; personal protective equipment. (CIS Abstr.)

  12. Dust evolution in protoplanetary disks

    OpenAIRE

    Gonzalez , Jean-François; Fouchet , Laure; T. Maddison , Sarah; Laibe , Guillaume

    2007-01-01

    6 pages, 5 figures, to appear in the Proceedings of IAU Symp. 249: Exoplanets: Detection, Formation and Dynamics (Suzhou, China); International audience; We investigate the behaviour of dust in protoplanetary disks under the action of gas drag using our 3D, two-fluid (gas+dust) SPH code. We present the evolution of the dust spatial distribution in global simulations of planetless disks as well as of disks containing an already formed planet. The resulting dust structures vary strongly with pa...

  13. Respirable versus inhalable dust sampling

    International Nuclear Information System (INIS)

    Hondros, J.

    1987-01-01

    The ICRP uses a total inhalable dust figure as the basis of calculations on employee lung dose. This paper was written to look at one aspect of the Olympic Dam dust situation, namely, the inhalable versus respirable fraction of the dust cloud. The results of this study will determine whether it is possible to use respirable dust figures, as obtained during routine monitoring to help in the calculations of employee exposure to internal radioactive contaminants

  14. Mineralogy and environmental stability of slags from the Tsumeb smelter, Namibia

    International Nuclear Information System (INIS)

    Ettler, Vojtech; Johan, Zdenek; Kribek, Bohdan; Sebek, Ondrej; Mihaljevic, Martin

    2009-01-01

    Three types of smelting slags originating from historically different smelting technologies in the Tsumeb area (Namibia) were studied: (i) slags from processing of carbonate/oxide ore in a Cu-Pb smelter (1907-1948), (ii) slags from Cu and Pb smelting of sulphide ores (1963-1970) and (iii) granulated Cu smelting slags (1980-2000). Bulk chemical analyses of slags were combined with detailed mineralogical investigation using X-ray diffraction analysis (XRD), scanning electron microscopy (SEM/EDS) and electron microprobe (EPMA). The slags are significantly enriched in metals and metalloids: Pb (0.97-18.4 wt.%), Cu (0.49-12.2 wt.%), Zn (2.82-12.09 wt.%), Cd (12-6940 mg/kg), As (930-75,870 mg/kg) and Sb (67-2175 mg/kg). Slags from the oldest technology are composed of primary Ca- and Pb-bearing feldspars, spinels, complex Cu-Fe and Cu-Cr oxides, delafossite-mcconnellite phases and Ca-Pb arsenates. The presence of arsenates indicates that these slags underwent long-term alteration. More recent slags are composed of high-temperature phases: Ca-Fe alumosilicates (olivine, melilite), Pb- and Zn-rich glass, spinel oxides and small sulphide/metallic inclusions embedded in glass. XRD and SEM/EDS were used to study secondary alteration products developed on the surface of slags exposed for decades to weathering on the dumps. Highly soluble complex Cu-Pb-(Ca) arsenates (bayldonite, lammerite, olivenite, lavendulan) associated with litharge and hydrocerussite were detected. To determine the mineralogical and geochemical parameters governing the release of inorganic contaminants from slags, two standardized short-term batch leaching tests (European norm EN 12457 and USEPA TCLP), coupled with speciation-solubility modelling using PHREEQC-2 were performed. Arsenic in the leachate exceeded the EU regulatory limit for hazardous waste materials (2.5 mg/L). The toxicity limits defined by USEPA for the TCLP test were exceeded for Cd, Pb and As. The PHREEQC-2 calculation predicted that

  15. Paleo-dust insights onto dust-climate interactions

    Science.gov (United States)

    Albani, S.; Mahowald, N. M.

    2017-12-01

    Mineral dust emissions are affected by changing climate conditions, and in turn dust impacts the atmospheric radiation budget, clouds and biogeochemical cycles. Climate and public health dust-related issues call for attention on the fate of the dust cycle in the future, and the representation of the dust cycle is now part of the strategy of the Paleoclimate Modelling Intercomparison Project phase 4 and the Coupled Model Intercomparison Project phase 6 (PMIP4-CMIP6). Since mineral aerosols are one of the most important natural aerosols, understanding past dust responses to climate in the paleoclimate will allow us to better understand mineral aerosol feedbacks with climate and biogeochemistry in the Anthropocene. Modern observations and paleoclimate records offer the possibility of multiple, complementary views on the global dust cycle, and allow to validate and/or constrain the numerical representation of dust in climate and Earth system models. We present our results from a set of simulations with the Community Earth System Model for different climate states, including present and past climates such as the pre-industrial, the mid-Holocene and the Last Glacial Maximum. A set of simulations including a prognostic dust cycle was thoroughly compared with a wide set of present day observations from different platforms and regions, in order to realistically constrain the magnitude of dust load, surface concentration, deposition, optical properties, and particle size distributions. The magnitude of emissions for past climate regimes was constrained based on compilations of paleodust mass accumulation rates and size distributions, as well as based on information on dust provenance. The comparison with a parallel set of simulations without dust allows estimating the impacts of dust on surface climate. We analyze impacts of dust on the mean and variability of surface temperature and precipitation in each climate state, as well as the impacts that changing dust emissions had

  16. Erosion of dust aggregates

    NARCIS (Netherlands)

    Seizinger, A.; Krijt, S.; Kley, W.

    2013-01-01

    Aims: The aim of this work is to gain a deeper insight into how much different aggregate types are affected by erosion. Especially, it is important to study the influence of the velocity of the impacting projectiles. We also want to provide models for dust growth in protoplanetary disks with simple

  17. Dust-Plasma Interactions

    International Nuclear Information System (INIS)

    Rosenberg, Marelene

    2005-01-01

    Our theoretical research on dust-plasma interactions has concentrated on three main areas: (a)studies of grain charging and applications; (b) waves and instabilities in weakly correlated dusty plasma with applications to space and laboratory plasmas; (c) waves in strongly coupled dusty plasmas.

  18. From dust to life

    Science.gov (United States)

    Wickramasinghe, Chandra

    After initially challenging the dirty-ice theory of interstellar grains, Fred Hoyle and the present author proposed carbon (graphite) grains, mixtures of refractory grains, organic polymers, biochemicals and finally bacterial grains as models of interstellar dust. The present contribution summarizes this trend and reviews the main arguments supporting a modern version of panspermia.

  19. Copper Cable Recycling Technology. Innovative Technology Summary Report

    International Nuclear Information System (INIS)

    2001-01-01

    The United States Department of Energy (DOE) continually seeks safer and more cost-effective technologies for use in deactivation and decommissioning (D and D) of nuclear facilities. The Deactivation and Decommissioning Focus Area (DDFA) of the DOE's Office of Science and Technology (OST) sponsors large-scale demonstration and deployment projects (LSDDPs). At these LSDDPs, developers and vendors of improved or innovative technologies showcase products that are potentially beneficial to the DOE's projects and to others in the D and D community. Benefits sought include decreased health and safety risks to personnel and the environment, increased productivity, and decreased costs of operation. The Idaho National Engineering and Environmental Laboratory (INEEL) generated a list of statements defining specific needs and problems where improved technology could be incorporated into ongoing D and D tasks. One such need is to reduce the volume of waste copper wire and cable generated by D and D. Deactivation and decommissioning activities of nuclear facilities generates hundreds of tons of contaminated copper cable, which are sent to radioactive waste disposal sites. The Copper Cable Recycling Technology separates the clean copper from contaminated insulation and dust materials in these cables. The recovered copper can then be reclaimed and, more importantly, landfill disposal volumes can be reduced. The existing baseline technology for disposing radioactively contaminated cables is to package the cables in wooden storage boxes and dispose of the cables in radioactive waste disposal sites. The Copper Cable Recycling Technology is applicable to facility decommissioning projects at many Department of Energy (DOE) nuclear facilities and commercial nuclear power plants undergoing decommissioning activities. The INEEL Copper Cable Recycling Technology Demonstration investigated the effectiveness and efficiency to recycle 13.5 tons of copper cable. To determine the effectiveness

  20. Soil Pollution with Copper, Lead and Zinc in the Surroundings of Large Copper Ore Tailings Impoundment

    Directory of Open Access Journals (Sweden)

    Musztyfaga Elżbieta

    2014-12-01

    Full Text Available Analysis of the top-soil total content of heavy metals was carried out inthe vicinity of large copper ore tailings pound in the south-western Poland with regard to soil properties, direction and distance from the tailings pound. None of the soils under study ex-ceeded the limits admitted in the official standards for soil quality, but the assessment made in accordance with IUNG-guidelines to soil contamination determination showed that more than half of the monitoring sites have elevated metal content, Cu, in par-ticular. The results confirmed high effectiveness of dust control preventing its eolian spread from the tailings pound.

  1. Studying of metals distribution in the Pinus Sylvestris bark and needles in a zone of influence the gradient polluted air stream from Cu-smelter

    International Nuclear Information System (INIS)

    Aminov, P.G.; Lonshchakova, G.F.

    2008-01-01

    In the paper the features of accumulation for heavy metals by pine needles and bark in the gradient dispersion area of technogenic elements and using of the bark as the bioindicator to establish influencing zones of smelter on environment are represented

  2. Modelling dust transport in tokamaks

    International Nuclear Information System (INIS)

    Martin, J.D.; Martin, J.D.; Bacharis, M.; Coppins, M.; Counsell, G.F.; Allen, J.E.; Counsell, G.F.

    2008-01-01

    The DTOKS code, which models dust transport through tokamak plasmas, is described. The floating potential and charge of a dust grain in a plasma and the fluxes of energy to and from it are calculated. From this model, the temperature of the dust grain can be estimated. A plasma background is supplied by a standard tokamak edge modelling code (B2SOLPS5.0), and dust transport through MAST (the Mega-Amp Spherical Tokamak) and ITER plasmas is presented. We conclude that micron-radius tungsten dust can reach the separatrix in ITER. (authors)

  3. Copper and silver halates

    CERN Document Server

    Woolley, EM; Salomon, M

    2013-01-01

    Copper and Silver Halates is the third in a series of four volumes on inorganic metal halates. This volume presents critical evaluations and compilations for halate solubilities of the Group II metals. The solubility data included in this volume are those for the five compounds, copper chlorate and iodate, and silver chlorate, bromate and iodate.

  4. Contrasting isotopic signatures between anthropogenic and geogenic Zn and evidence for post-depositional fractionation processes in smelter-impacted soils from Northern France

    Science.gov (United States)

    Juillot, Farid; Maréchal, Chloe; Morin, Guillaume; Jouvin, Delphine; Cacaly, Sylvain; Telouk, Philipe; Benedetti, Marc F.; Ildefonse, Philippe; Sutton, Steve; Guyot, François; Brown, Gordon E., Jr.

    2011-05-01

    Zinc isotopes have been studied along two smelter-impacted soil profiles sampled near one of the largest Pb and Zn processing plants in Europe located in northern France, about 50 km south of Lille. Mean δ 66Zn values along these two soil profiles range from +0.22 ± 0.17‰ (2 σ) to +0.34 ± 0.17‰ (2 σ) at the lowest horizons and from +0.38 ± 0.45‰ (2 σ) to +0.76 ± 0.14‰ (2 σ) near the surface. The δ 66Zn values in the lowest horizons of the soils are interpreted as being representative of the local geochemical background (mean value +0.31 ± 0.38‰), whereas heavier δ 66Zn values near the surface of the two soils are related to anthropogenic Zn. This anthropogenic Zn occurs in the form of franklinite (ZnFe 2O 4)-bearing slag grains originating from processing wastes at the smelter site and exhibiting δ 66Zn values of +0.81 ± 0.20‰ (2 σ). The presence of franklinite is indicated by EXAFS analysis of the topsoil samples from both soil profiles as well as by micro-XANES analysis of the surface horizon of a third smelter-impacted soil from a distant site. These results indicate that naturally occurring Zn and smelter-derived Zn exhibit significantly different δ 66Zn values, which suggests that zinc isotopes can be used to distinguish between geogenic and anthropogenic sources of Zn in smelter-impacted soils. In addition to a possible influence of additional past sources of light Zn (likely Zn-sulfides and Zn-sulfates directly emitted by the smelter), the light δ 66Zn values in the surface horizons compared to smelter-derived slag materials are interpreted as resulting mainly from fractionation processes associated with biotic and/or abiotic pedological processes (Zn-bearing mineral precipitation, Zn complexation by organic matter, and plant uptake of Zn). This conclusion emphasizes the need for additional Zn isotopic studies before being able to use Zn isotopes to trace sources and pathways of this element in surface environments.

  5. Leaching Behavior of Slags from AN Old Lead Smelter in Chihuahua, Mexico: Metals, Chlorides, Nitrates, Sulfates and Tds Analyses

    Science.gov (United States)

    Espejel-Garcia, D.; Wenglas-Lara, G.; Villalobos-Aragon, A.; Espejel-Garcia, V. V.

    2013-05-01

    Waste materials (such as, smelter slags, waste glass, tires, plastics, rubbish, ashes, etc.), have a large potential to substitute natural materials, reducing costs, especially for the construction industry. Smelter slags are resistant and have better compression strength values in comparison to natural aggregates, and generally are far beyond of what the standard ratios need to qualify a material as a good one for construction. But this material has a big problem within it: the existence of toxic elements and compounds in high concentrations, which means that water and soil contamination can be present after water infiltrates through this material; so we perform leaching experiments to characterize and measure the possible contamination under controlled conditions. To perform the slags-leaching experiments, we used an EA-NEN-7375-2004 tank test standard from Netherlands. This test was selected because to our knowledge it is the only one which allows the use of coarse material, as the one utilized in construction. The leaching experiments sampling was performed at different times: 6, 24, 168 and 360 hours, to compare the leachate concentration at the two different pH's values (5 and 8) selected to simulate real conditions. For the leaching experiments, the slags were mixed with natural road base material (gravel-sands from volcanic rocks) at different proportions of 30% and 50%. In order to understand the slags' leaching behavior, other experiments were carried out with the pure material, for both (slags and natural aggregates). After analyses by ICP-OES , the slags from this smelter in Chihuahua contain Pb (0.5 - 4 wt.%), Zn (15-35 wt.%) and As (0.6 wt.%), as well such as: bicarbonates, chlorides, nitrates, sulfates, Mg, K, Na, Ca and TDS. Based on the results of the leaching analyses, via atomic absorption technique, we conclude that Pb and As concentrations are provided by the slags, meanwhile, the bicarbonates, chlorides, Na and Ca are contributed by the road

  6. THE INFLUENCE OF SELECTED FACTORS ON THE LEACHING OF HEAVY METALS FROM SMELTER WASTE

    OpenAIRE

    Kamila Mizerna; Anna Król

    2015-01-01

    The paper presents the results of leaching research of selected heavy metals (Pb, Cu, Zn, Ni, Cd, Cr) from industrial waste. The impact of waste fragmentation on the level of heavy metals leaching was analyzed. The decrease of copper and zinc release and the increase of nickel leaching were observed with increasing grain size fraction of waste. Furthermore, release of contaminants in different ratio of liquid to solid (L/S = 10 dm3/kg and 2 dm3/kg) was studied. Higher concentrations of heavy ...

  7. Dust storm, northern Mexico

    Science.gov (United States)

    1983-01-01

    This large dust storm along the left side of the photo, covers a large portion of the state of Coahuila, Mexico (27.5N, 102.0E). The look angle of this oblique photo is from the south to the north. In the foreground is the Sierra Madre Oriental in the states Coahuila and Nuevo Leon with the Rio Grande River, Amistad Reservoir and Texas in the background.

  8. Dust acoustic shock wave at high dust density

    International Nuclear Information System (INIS)

    Ghosh, Samiran; Sarkar, Susmita; Khan, Manoranjan; Avinash, K.; Gupta, M. R.

    2003-01-01

    Dust acoustic (DA) shock wave at high dust density, i.e., the dust electroacoustic (DEA) or dust Coulomb (DC) shock wave has been investigated incorporating the nonadiabatic dust charge variation. The nonlinear DEA (DC) shock wave is seen to be governed by the Korteweg-de Vries Burger equation, in which the Burger term is proportional to the nonadiabaticity generated dissipation. It is seen that the shock strength decreases but after reaching minimum, it increases as the dust space charge density |q d n d | increases and the shock strength of DA wave is greater than that of DEA (DC) wave. Moreover the DEA (DC) shock width increases appreciably with increase mass m i of the ion component of the dusty plasma but for DA shock wave the effect is weak

  9. Dust, Climate, and Human Health

    Science.gov (United States)

    Maynard, Nancy G.

    2003-01-01

    Air pollution from both natural and anthropogenic causes is considered to be one of the most serious world-wide environment-related health problems, and is expected to become worse with changes in the global climate. Dust storms from the atmospheric transport of desert soil dust that has been lifted and carried by the winds - often over significant distances - have become an increasingly important emerging air quality issue for many populations. Recent studies have shown that the dust storms can cause significant health impacts from the dust itself as well as the accompanying pollutants, pesticides, metals, salt, plant debris, and other inorganic and organic materials, including viable microorganisms (bacteria, viruses and fungi). For example, thousands of tons of Asian desert sediments, some containing pesticides and herbicides from farming regions, are commonly transported into the Arctic during dust storm events. These chemicals have been identified in animal and human tissues among Arctic indigenous populations. Millions of tons of airborne desert dust are being tracked by satellite imagery, which clearly shows the magnitude as well as the temporal and spatial variability of dust storms across the "dust belt" regions of North Africa, the Middle East, and China. This paper summarizes the most recent findings on the effects of airborne desert dust on human health as well as potential climate influences on dust and health.

  10. Parameterizing the interstellar dust temperature

    Science.gov (United States)

    Hocuk, S.; Szűcs, L.; Caselli, P.; Cazaux, S.; Spaans, M.; Esplugues, G. B.

    2017-08-01

    The temperature of interstellar dust particles is of great importance to astronomers. It plays a crucial role in the thermodynamics of interstellar clouds, because of the gas-dust collisional coupling. It is also a key parameter in astrochemical studies that governs the rate at which molecules form on dust. In 3D (magneto)hydrodynamic simulations often a simple expression for the dust temperature is adopted, because of computational constraints, while astrochemical modelers tend to keep the dust temperature constant over a large range of parameter space. Our aim is to provide an easy-to-use parametric expression for the dust temperature as a function of visual extinction (AV) and to shed light on the critical dependencies of the dust temperature on the grain composition. We obtain an expression for the dust temperature by semi-analytically solving the dust thermal balance for different types of grains and compare to a collection of recent observational measurements. We also explore the effect of ices on the dust temperature. Our results show that a mixed carbonaceous-silicate type dust with a high carbon volume fraction matches the observations best. We find that ice formation allows the dust to be warmer by up to 15% at high optical depths (AV> 20 mag) in the interstellar medium. Our parametric expression for the dust temperature is presented as Td = [ 11 + 5.7 × tanh(0.61 - log 10(AV) ]χuv1/5.9, where χuv is in units of the Draine (1978, ApJS, 36, 595) UV field.

  11. Copper carrier protein in copper toxic sheep liver

    Energy Technology Data Exchange (ETDEWEB)

    Harris, A L; Dean, P D.G.

    1973-01-01

    The livers of copper-toxic sheep have been analyzed by gel electrophoresis followed by staining the gels for copper with diethyldithiocarbamate and for protein with amido schwartz. These gels were compared with similar gels obtained from the livers of normal and copper-deficient animals. The copper-toxic livers contained an extra protein band which possessed relatively weakly bound copper. Possible origins of this protein are discussed. 8 references, 1 figure, 2 tables.

  12. Canine Copper-Associated Hepatitis

    NARCIS (Netherlands)

    Dirksen, Karen; Fieten, Hille

    2017-01-01

    Copper-associated hepatitis is recognized with increasing frequency in dogs. The disease is characterized by centrolobular hepatic copper accumulation, leading to hepatitis and eventually cirrhosis. The only way to establish the diagnosis is by histologic assessment of copper distribution and copper

  13. Posttranslational regulation of copper transporters

    NARCIS (Netherlands)

    van den Berghe, P.V.E.

    2009-01-01

    The transition metal copper is an essential cofactor for many redox-active enzymes, but excessive copper can generate toxic reactive oxygen species. Copper homeostasis is maintained by highly conserved proteins, to balance copper uptake, distribution and export on the systemic and cellular level.

  14. Alteration of podzolized tills by acid load near Ni-Cu smelters at Monchegorsk, Kola Peninsula, Russia

    Directory of Open Access Journals (Sweden)

    Räisänen, M.L.

    1994-06-01

    Full Text Available Mineralogy and geochemistry of podzolized tills was studied in the area of dieback forest near the Ni-Cu smelters at Monchegorsk, and less extensively forest damage near by Apatity and Kirovsk in the Russian Kola Peninsula. The abundances of main elements (Si, Al, Fe, Mg, Ca, K, Na in the <64 μm fraction were determined by the hot aqua regia digestion method and inductively coupled plasma spectrometry. The clay mineralogy of the silt plus clay fraction was examined by X-ray diffraction after selective extraction and heating treatments. At all study sites, trioctahedral mica and chlorite were totally weathered from the silt and clay fraction (<64 μm of the eluvial layer, leaving behind interstratified mica-vermiculite-smectite clays. In general, the mixed-layer clay of the eluvial layer had low levels of hydroxy interlayering. Illuviated layers were characterized by hydroxy interlayered vermiculite-chlorite. The abundance of chlorite and mica was greater, and the degree of interlayering lower, in parent tills than in the overlying illuviated layers. Regardless of differences in bedrock and till geochemistry, the weathering sequence throughout the podzolized till profile was coherent at most of the sampling sites. Exceptionally, in a few profiles sampled at the totally destroyed forest site, the swelling mixed-layer clay of the eluvial layer displayed a neochloritized structure. On the basis of XRD patterns and geochemistry of the samples, it was inferred that a short-term decomposition of plagioclase had promoted, via inputs of Al-hydroxides, the transformation of mica-vermiculite-smectite to a poorly crystalline interstratification of chlorite-aluminous montmorillonite. The accelerated weathering occurring occasionally in exposed places was probably activated by the strongly acidic load in the vicinity of the smelters and the city of Monchegorsk.

  15. Fabricating Copper Nanotubes by Electrodeposition

    Science.gov (United States)

    Yang, E. H.; Ramsey, Christopher; Bae, Youngsam; Choi, Daniel

    2009-01-01

    Copper tubes having diameters between about 100 and about 200 nm have been fabricated by electrodeposition of copper into the pores of alumina nanopore membranes. Copper nanotubes are under consideration as alternatives to copper nanorods and nanowires for applications involving thermal and/or electrical contacts, wherein the greater specific areas of nanotubes could afford lower effective thermal and/or electrical resistivities. Heretofore, copper nanorods and nanowires have been fabricated by a combination of electrodeposition and a conventional expensive lithographic process. The present electrodeposition-based process for fabricating copper nanotubes costs less and enables production of copper nanotubes at greater rate.

  16. Dust in H II regions

    International Nuclear Information System (INIS)

    Isobe, S.

    1977-01-01

    Several pieces of evidence indicate that H II regions may contain dust: 1) the continuum light scattered by dust grains (O'Dell and Hubbard, 1965), 2) thermal radiation from dust grains at infrared wavelengths (Ney and Allen, 1969), 3) the abnormal helium abundance in some H II regions (Peimbert and Costero, 1969), etc. Although observations of the scattered continuum suggest that the H II region cores may be dust-free, dust grains and gas must be well mixed in view of the infrared observations. This difficulty may be solved by introducing globules with sizes approximately 0.001 pc. These globules and the molecular clouds adjacent to H II regions are the main sources supplying dust to H II regions. (Auth.)

  17. Large Aperture Electrostatic Dust Detector

    International Nuclear Information System (INIS)

    Skinner, C.H.; Hensley, R.; Roquemore, A.L.

    2007-01-01

    Diagnosis and management of dust inventories generated in next-step magnetic fusion devices is necessary for their safe operation. A novel electrostatic dust detector, based on a fine grid of interlocking circuit traces biased to 30 or 50 v has been developed for the detection of dust particles on remote surfaces in air and vacuum environments. Impinging dust particles create a temporary short circuit and the resulting current pulse is recorded by counting electronics. Up to 90% of the particles are ejected from the grid or vaporized suggesting the device may be useful for controlling dust inventories. We report measurements of the sensitivity of a large area (5x5 cm) detector to microgram quantities of dust particles and review its applications to contemporary tokamaks and ITER.

  18. Copper contamination in thin stainless steel sheet

    International Nuclear Information System (INIS)

    Holbert, R.K. Jr.; Dobbins, A.G.; Bennett, R.K. Jr.

    1986-01-01

    The standard welding technique used at Oak Ridge Y-12 Plant for joining thin stainless sheet is the gas tungsten arc (GTA) welding process. One of the reoccurring problems with the sheet welds is surface cracking in the heat-affected zone (HAZ). Metallography shows that the cracks are only about 0.05 mm (0.002 in.) deep which is significant in a 0.25 mm (0.01 in.) thick sheet. Thus, welding requirements do not permit any surfacing cracking as detected by a fluorescent dye penetrant test conducted on every part after welding. Surface cracks have been found in both of the two most common weld designs in the thin sheet fabricated at the Oak Ridge Y-12 Plant. These butt joints are welded between two 0.25 mm thick stainless steel sheets and a tube with eyelet welded to a 25 mm (0.98 in.) thick sheet. The weld between the two sheets is made on a semiautomatic seam welding unit, whereas the tube-to-eyelet-to-sheet welds are done manually. The quality of both welds is very dependent on the welding procedure and the way the parts are placed in the weld fixturing. Metallographic examination has indicated that some welded parts with surface cracking in the weld region had copper particles on the surface, and the question of copper contamination has been raised. With the aid of a scanning electron microscope and an electron microprobe, the existence of copper in an around the surface cracks has been verified. The copper is on the surface of the parts prior to welding in the form of small dust particles

  19. Photoelectric charging of dust grains

    International Nuclear Information System (INIS)

    Ignatov, A. M.

    2009-01-01

    Photoemission from the surface of a dust grain in vacuum is considered. It is shown that the cutoff in the energy spectrum of emitted electrons leads to the formation of a steady-state electron cloud. The equation describing the distribution of the electric potential in the vicinity of a dust grain is solved numerically. The dust grain charge is found as a function of the grain size.

  20. Harmful influence of industrial dusts upon plants and animal organisms

    Energy Technology Data Exchange (ETDEWEB)

    Dziubek, T

    1967-01-01

    Contamination of the atmosphere near aluminum and copper foundries and phosphate fertilizer plants is caused mainly by fluorine compounds. The contamination damages plants, meadows, and pastures adjacent to factories or situated in the vicinity and has an indirect effect on domestic animals fed with fodder from such grasslands. Grassland vegetation 100-3000 m from the factories were investigated by measuring the quality and quantity of dust; 0-30 mg% fluorine compounds were found. Changes in cattle tissue (teeth and bones), a decrease in lactation, and a stunting of young animal growth were noted. A considerable decrease in the hemoglobin in the animals investigated also occurred.

  1. Distribution of copper, silver and gold during thermal treatment with brominated flame retardants

    International Nuclear Information System (INIS)

    Oleszek, Sylwia; Grabda, Mariusz; Shibata, Etsuro; Nakamura, Takashi

    2013-01-01

    Highlights: • Copper, silver and gold during thermal treatment with brominated flame retardants. • Distribution of copper, silver and gold during thermal processing. • Thermodynamic considerations of the bromination reactions. - Abstract: The growing consumption of electric and electronic equipment results in creating an increasing amount of electronic waste. The most economically and environmentally advantageous methods for the treatment and recycling of waste electric and electronic equipment (WEEE) are the thermal techniques such as direct combustion, co-combustion with plastic wastes, pyrolysis and gasification. Nowadays, this kind of waste is mainly thermally treated in incinerators (e.g. rotary kilns) to decompose the plastics present, and to concentrate metals in bottom ash. The concentrated metals (e.g. copper, precious metals) can be supplied as a secondary raw material to metal smelters, while the pyrolysis of plastics allows the recovery of fuel gases, volatilising agents and, eventually, energy. Indeed, WEEE, such as a printed circuit boards (PCBs) usually contains brominated flame retardants (BFRs). From these materials, hydrobromic acid (HBr) is formed as a product of their thermal decomposition. In the present work, the bromination was studied of copper, silver and gold by HBr, originating from BFRs, such as Tetrabromobisphenol A (TBBPA) and Tetrabromobisphenol A-Tetrabromobisophenol A diglycidyl ether (TTDE) polymer; possible volatilization of the bromides formed was monitored using a thermo-gravimetric analyzer (TGA) and a laboratory-scale furnace for treating samples of metals and BFRs under an inert atmosphere and at a wide range of temperatures. The results obtained indicate that up to about 50% of copper and silver can evolve from sample residues in the form of volatile CuBr and AgBr above 600 and 1000 °C, respectively. The reactions occur in the molten resin phase simultaneously with the decomposition of the brominated resin. Gold is

  2. Micromachining with copper lasers

    Science.gov (United States)

    Knowles, Martyn R. H.; Bell, Andy; Foster-Turner, Gideon; Rutterford, Graham; Chudzicki, J.; Kearsley, Andrew J.

    1997-04-01

    In recent years the copper laser has undergone extensive development and has emerged as a leading and unique laser for micromachining. The copper laser is a high average power (10 - 250 W), high pulse repetition rate (2 - 32 kHz), visible laser (511 nm and 578 nm) that produces high peak power (typically 200 kW), short pulses (30 ns) and very good beam quality (diffraction limited). This unique set of laser parameters results in exceptional micro-machining in a wide variety of materials. Typical examples of the capabilities of the copper laser include the drilling of small holes (10 - 200 micrometer diameter) in materials as diverse as steel, ceramic, diamond and polyimide with micron precision and low taper (less than 1 degree) cutting and profiling of diamond. Application of the copper laser covers the electronic, aerospace, automotive, nuclear, medical and precision engineering industries.

  3. Homogeneous weldings of copper

    International Nuclear Information System (INIS)

    Campurri, C.; Lopez, M.; Fernandez, R.; Osorio, V.

    1995-01-01

    This research explored the metallurgical and mechanical properties of arc welding of copper related with influence of Argon, Helium and mixtures of them. Copper plates of 6 mm thickness were welded with different mixtures of the mentioned gases. The radiography of welded specimens with 100% He and 100% Ar does not show show any porosity. On the other hand, the copper plates welded different gas mixtures presented uniform porosity in the welded zone. The metallographies show recrystallized grain in the heat affected zone, while the welding zone showed a dendritic structure. The results of the tensile strength vary between a maximum of 227 MPa for 100% He and a minimum of 174 MOa for the mixture of 60% He and 40% Ar. For the elongation after fracture the best values, about 36%, were obtained for pure gases. As a main conclusion, we can say that arc welding of copper is possible without loosing the mechanical and metallurgical properties of base metal. 6 refs

  4. copper(II)

    Indian Academy of Sciences (India)

    Unknown

    bis(2,2,6,6-tetramethyl-3,5-heptadionato)copper(II) ... Abstract. Equilibrium concentrations of various condensed and gaseous phases have been thermodyna- ... phere, over a wide range of substrate temperatures and total reactor pressures.

  5. Bacterial Killing by Dry Metallic Copper Surfaces▿

    OpenAIRE

    Santo, Christophe Espírito; Lam, Ee Wen; Elowsky, Christian G.; Quaranta, Davide; Domaille, Dylan W.; Chang, Christopher J.; Grass, Gregor

    2010-01-01

    Metallic copper surfaces rapidly and efficiently kill bacteria. Cells exposed to copper surfaces accumulated large amounts of copper ions, and this copper uptake was faster from dry copper than from moist copper. Cells suffered extensive membrane damage within minutes of exposure to dry copper. Further, cells removed from copper showed loss of cell integrity. Acute contact with metallic copper surfaces did not result in increased mutation rates or DNA lesions. These findings are important fir...

  6. THE INFLUENCE OF SELECTED FACTORS ON THE LEACHING OF HEAVY METALS FROM SMELTER WASTE

    Directory of Open Access Journals (Sweden)

    Kamila Mizerna

    2015-07-01

    Full Text Available The paper presents the results of leaching research of selected heavy metals (Pb, Cu, Zn, Ni, Cd, Cr from industrial waste. The impact of waste fragmentation on the level of heavy metals leaching was analyzed. The decrease of copper and zinc release and the increase of nickel leaching were observed with increasing grain size fraction of waste. Furthermore, release of contaminants in different ratio of liquid to solid (L/S = 10 dm3/kg and 2 dm3/kg was studied. Higher concentrations of heavy metals were determined in ratio of L/S = 10 dm3/kg. In order to determine the risk of tested waste to the environment, the results were compared with the current law. This allowed the classification of the waste to hazardous waste.

  7. Dust in cosmic plasma environments

    International Nuclear Information System (INIS)

    Mendis, D.A.

    1979-01-01

    Cosmic dust is invariably immersed in a plasma and a radiative environment. Consequently, it is charged to some electrostatic potential which depends on the properties of the environment as well as the nature of the dust. This charging affects the physical and dynamical properties of the dust. In this paper the basic aspects of this dust-plasma interaction in several cosmic environments - including planetary magnetospheres, the heliosphere and the interstellar medium - are discussed. The physical and dynamical consequences of the interaction, as well as the pertinent observational evidence, are reviewed. Finally, the importance of the surface charge during the condensation process in plasma environments is stressed. (Auth.)

  8. LEP copper accelerating cavities

    CERN Multimedia

    Laurent Guiraud

    1999-01-01

    These copper cavities were used to generate the radio frequency electric field that was used to accelerate electrons and positrons around the 27-km Large Electron-Positron (LEP) collider at CERN, which ran from 1989 to 2000. The copper cavities were gradually replaced from 1996 with new superconducting cavities allowing the collision energy to rise from 90 GeV to 200 GeV by mid-1999.

  9. Copper intoxication in sheep

    Energy Technology Data Exchange (ETDEWEB)

    Gazaryan, V.S.; Sogoyan, I.S.; Agabalov, G.A.; Mesropyan, V.V.

    1966-01-01

    Of 950 sheep fed hay from a vineyard sprayed regularly with copper sulfate, 143 developed clinical copper poisoning and 103 died. The Cu content of the hay was 10.23 mg%, of the liver of dead sheep 17-52 mg%, and of the blood serum of affected sheep 0.86 mg%. The symptoms and the histological findings in kidneys and liver are described.

  10. Air pollution assessment based on elemental concentration of leaves tissue and foliage dust along an urbanization gradient in Vienna.

    Science.gov (United States)

    Simon, Edina; Braun, Mihály; Vidic, Andreas; Bogyó, Dávid; Fábián, István; Tóthmérész, Béla

    2011-05-01

    Foliage dust contains heavy metal that may have harmful effects on human health. The elemental contents of tree leaves and foliage dust are especially useful to assess air environmental pollution. We studied the elemental concentrations in foliage dust and leaves of Acer pseudoplatanus along an urbanization gradient in Vienna, Austria. Samples were collected from urban, suburban and rural areas. We analysed 19 elements in both kind of samples: aluminium, barium, calcium, copper, iron, potassium, magnesium, sodium, phosphor, sulphur, strontium and zinc. We found that the elemental concentrations of foliage dust were significantly higher in the urban area than in the rural area for aluminium, barium, iron, lead, phosphor and selenium. Elemental concentrations of leaves were significantly higher in urban than in rural area for manganese and strontium. Urbanization changed significantly the elemental concentrations of foliage dust and leaves and the applied method can be useful for monitoring the environmental load. Copyright © 2011 Elsevier Ltd. All rights reserved.

  11. Copper wire bonding

    CERN Document Server

    Chauhan, Preeti S; Zhong, ZhaoWei; Pecht, Michael G

    2014-01-01

    This critical volume provides an in-depth presentation of copper wire bonding technologies, processes and equipment, along with the economic benefits and risks.  Due to the increasing cost of materials used to make electronic components, the electronics industry has been rapidly moving from high cost gold to significantly lower cost copper as a wire bonding material.  However, copper wire bonding has several process and reliability concerns due to its material properties.  Copper Wire Bonding book lays out the challenges involved in replacing gold with copper as a wire bond material, and includes the bonding process changes—bond force, electric flame off, current and ultrasonic energy optimization, and bonding tools and equipment changes for first and second bond formation.  In addition, the bond–pad metallurgies and the use of bare and palladium-coated copper wires on aluminum are presented, and gold, nickel and palladium surface finishes are discussed.  The book also discusses best practices and re...

  12. Gravitational radiation from dust

    International Nuclear Information System (INIS)

    Isaacson, R.A.; Welling, J.S.; Winicour, J.

    1985-01-01

    A dust cloud is examined within the framework of the general relativistic characteristic initial value problem. Unique gravitational initial data are obtained by requiring that the space-time be quasi-Newtonian. Explicit calculations of metric and matter fields are presented, which include all post-Newtonian corrections necessary to discuss the major physical properties of null infinity. These results establish a curved space version of the Einstein quadrupole formula, in the form ''news function equals third time derivative of transverse quadrupole moment,'' for this system. However, these results imply that some weakened notion of asymptotic flatness is necessary for the description of quasi-Newtonian systems

  13. Dust coagulation in ISM

    Science.gov (United States)

    Chokshi, Arati; Tielens, Alexander G. G. M.; Hollenbach, David

    1989-01-01

    Coagulation is an important mechanism in the growth of interstellar and interplanetary dust particles. The microphysics of the coagulation process was theoretically analyzed as a function of the physical properties of the coagulating grains, i.e., their size, relative velocities, temperature, elastic properties, and the van der Waal interaction. Numerical calculations of collisions between linear chains provide the wave energy in individual particles and the spectrum of the mechanical vibrations set up in colliding particles. Sticking probabilities are then calculated using simple estimates for elastic deformation energies and for the attenuation of the wave energy due to absorption and scattering processes.

  14. Dust confinement and dust acoustic waves in a magnetized plasma

    Science.gov (United States)

    Piel, A.

    2005-10-01

    Systematic laboratory experiments on dust acoustic waves require the confinement of dust particles. Here we report on new experiments in a magnetized plasma region in front of an additional positively biased disk electrode in a background plasma which is generated in argon at 27MHz between a disk and grid electrode. The plasma diffuses through the grid along the magnetic field. The three-dimensional dust distribution is measured with a horizontal sheet of laser light and a CCD camera, which are mounted on a vertical translation stage. Depending on magnetic field and discharge current, cigar or donut-shaped dust clouds are generated, which tend to rotate about the magnetic field direction. Measurements with emissive probes show that the axial confinement of dust particles with diameters between 0.7-2 μm is achieved by a balance of ion-drag force and electric field force. Dust levitation and radial confinement is due to a strong radial electric field. Dust acoustic waves are destabilized by the ion flow or can be stimulated by a periodic bias on the disk electrode. The observed wave dispersion is compared with fluid and kinetic models of the dust acoustic wave.

  15. Gravimetric dust sampling for control purposes and occupational dust sampling.

    CSIR Research Space (South Africa)

    Unsted, AD

    1997-02-01

    Full Text Available Prior to the introduction of gravimetric dust sampling, konimeters had been used for dust sampling, which was largely for control purposes. Whether or not absolute results were achievable was not an issue since relative results were used to evaluate...

  16. Application of synchrotron microprobe methods to solid-phase speciation of metals and metalloids in house dust.

    Science.gov (United States)

    Walker, S R; Jamieson, H E; Rasmussen, P E

    2011-10-01

    Determination of the source and form of metals in house dust is important to those working to understand human and particularly childhood exposure to metals in residential environments. We report the development of a synchrotron microprobe technique for characterization of multiple metal hosts in house dust. We have applied X-ray fluorescence for chemical characterization and X-ray diffraction for crystal structure identification using microfocused synchrotron X-rays at a less than 10 μm spot size. The technique has been evaluated by application to archived house dust samples containing elevated concentrations of Pb, Zn, and Ba in bedroom dust, and Pb and As in living room dust. The technique was also applied to a sample of soil from the corresponding garden to identify linkages between indoor and outdoor sources of metals. Paint pigments including white lead (hydrocerussite) and lithopone (wurtzite and barite) are the primary source of Pb, Zn, and Ba in bedroom dust, probably related to renovation activity in the home at the time of sampling. The much lower Pb content in the living room dust shows a relationship to the exterior soil and no specific evidence of Pb and Zn from the bedroom paint pigments. The technique was also successful at confirming the presence of chromated copper arsenate treated wood as a source of As in the living room dust. The results of the study have confirmed the utility of this approach in identifying specific metal forms within the dust.

  17. Of data and dust

    CERN Multimedia

    Stephanie Hills

    2016-01-01

    The traditional image of an archive is one of dusty old boxes, books and papers. When your archive is digital, dust spells disaster. An innovative environmental sensor designed and built by a CERN IT specialist has become an essential element in the Laboratory’s data-preservation strategy.   The novel air particle monitoring sensor designed by CERN's Julien Leduc. CERN’s archive holds more than 130 petabytes of data from past and present high-energy physics experiments. Some of it is 40 years old, most of it needs to be kept forever, and all of it is held on tape cartridges (over 20,000 of them). The cartridges are held inside tape libraries with robotic arms that load them into tape drives where they can be read and written. Tape cartridges have many advantages over other data storage media, notably cost and long-term reliability, but topping the list of drawbacks is their vulnerability to contamination from airborne dust particles; a tiny piece of g...

  18. Radionuclides in house dust

    Energy Technology Data Exchange (ETDEWEB)

    Fry, F A; Green, N; Dodd, N J; Hammond, D J

    1985-04-01

    Discharges of radionuclides from the British Nuclear Fuel plc (BNFL) reprocessing plant at Sellafield in Cumbria have led to elevated concentrations radionuclides in the local environment. The major routes of exposure of the public are kept under review by the appropriate authorising Government departments and monitoring is carried out both by the departments and by BNFL itself. Recently, there has been increasing public concern about general environmental contamination resulting from the discharges and, in particular, about possible exposure of members of the public by routes not previously investigated in detail. One such postulated route of exposure that has attracted the interest of the public, the press and Parliament arises from the presence of radionuclides within houses. In view of this obvious and widespread concern, the Board has undertaken a sampling programme in a few communities in Cumbria to assess the radiological significance of this source of exposure. From the results of our study, we conclude that, although radionuclides originating rom the BNFL site can be detected in house dust, this source of contamination is a negligible route of exposure for members of the public in West Cumbria. This report presents the results of the Board's study of house dust in twenty homes in Cumbria during the spring and summer of 1984. A more intensive investigation is being carried out by Imperial College. (author)

  19. Health hazards of cement dust

    International Nuclear Information System (INIS)

    Meo, Sultan A.

    2004-01-01

    ven in the 21st century, millions of people are working daily in a dusty environment. They are exposed to different types of health hazards such as fume, gases and dust, which are risk factors in developing occupational disease. Cement industry is involved in the development of structure of this advanced and modern world but generates dust during its production. Cement dust causes lung function impairment, chronic obstructive lung disease, restrictive lung disease, pneumoconiosis and carcinoma of the lungs, stomach and colon. Other studies have shown that cement dust may enter into the systemic circulation and thereby reach the essentially all the organs of body and affects the different tissues including heart, liver, spleen, bone, muscles and hairs and ultimately affecting their micro-structure and physiological performance. Most of the studies have been previously attempted to evaluate the effects of cement dust exposure on the basis of spirometry or radiology, or both. However, collective effort describing the general effects of cement dust on different organ and systems in humans or animals, or both has not been published. Therefore, the aim of this review is to gather the potential toxic effects of cement dust and to minimize the health risks in cement mill workers by providing them with information regarding the hazards of cement dust. (author)

  20. Dust forecasting system in JMA

    International Nuclear Information System (INIS)

    Mikami, M; Tanaka, T Y; Maki, T

    2009-01-01

    JMAs dust forecasting information, which is based on a GCM dust model, is presented through the JMA website coupled with nowcast information. The website was updated recently and JMA and MOE joint 'KOSA' website was open from April 2008. Data assimilation technique will be introduced for improvement of the 'KOSA' information.

  1. Dust in flowing magnetized plasma

    International Nuclear Information System (INIS)

    Pandey, Birendra P.; Samarian, Alex A.; Vladimirov, Sergey V.

    2009-01-01

    Plasma flows occur in almost every laboratory device and interactions of flowing plasmas with near-wall impurities and/or dust significantly affects the efficiency and lifetime of such devices. The charged dust inside the magnetized flowing plasma moves primarily under the influence of the plasma drag and electric forces. Here, the charge on the dust, plasma potential, and plasma density are calculated self-consistently. The electrons are assumed non-Boltzmannian and the effect of electron magnetization and electron-atom collisions on the dust charge is calculated in a self-consistent fashion. For various plasma magnetization parameters viz. the ratio of the electron and ion cyclotron frequencies to their respective collision frequencies, plasma-atom and ionization frequencies, the evolution of the plasma potential and density in the flow region is investigated. The variation of the dust charge profile is shown to be a sensitive function of plasma parameters. (author)

  2. Dust in protoplanetary disks: observations*

    Directory of Open Access Journals (Sweden)

    Waters L.B.F.M.

    2015-01-01

    Full Text Available Solid particles, usually referred to as dust, are a crucial component of interstellar matter and of planet forming disks surrounding young stars. Despite the relatively small mass fraction of ≈1% (in the solar neighborhood of our galaxy; this number may differ substantially in other galaxies that interstellar grains represent of the total mass budget of interstellar matter, dust grains play an important role in the physics and chemistry of interstellar matter. This is because of the opacity dust grains at short (optical, UV wavelengths, and the surface they provide for chemical reactions. In addition, dust grains play a pivotal role in the planet formation process: in the core accretion model of planet formation, the growth of dust grains from the microscopic size range to large, cm-sized or larger grains is the first step in planet formation. Not only the grain size distribution is affected by planet formation. Chemical and physical processes alter the structure and chemical composition of dust grains as they enter the protoplanetary disk and move closer to the forming star. Therefore, a lot can be learned about the way stars and planets are formed by observations of dust in protoplanetary disks. Ideally, one would like to measure the dust mass, the grain size distribution, grain structure (porosity, fluffiness, the chemical composition, and all of these as a function of position in the disk. Fortunately, several observational diagnostics are available to derive constrains on these quantities. In combination with rapidly increasing quality of the data (spatial and spectral resolution, a lot of progress has been made in our understanding of dust evolution in protoplanetary disks. An excellent review of dust evolution in protoplanetary disks can be found in Testi et al. (2014.

  3. Probing the distribution and contamination levels of 10 trace metal/metalloids in soils near a Pb/Zn smelter in Middle China.

    Science.gov (United States)

    Li, Zhonggen; Feng, Xinbin; Bi, Xiangyang; Li, Guanghui; Lin, Yan; Sun, Guangyi

    2014-03-01

    The horizontal and vertical distribution patterns and contamination status of ten trace metal/metalloids (Ag, Bi, Co, Cr, Ge, In, Ni, Sb, Sn, Tl) in soils around one of the largest Chinese Pb-Zn smelter in Zhuzhou City, Central China, were revealed. Different soil samples were collected from 11 areas, including ten agricultural areas and one city park area, with a total of 83 surface soil samples and six soil cores obtained. Trace metal/metalloids were determined by inductively coupled plasma-mass spectrometry after digestion by an acid mixture of HF and HNO3. The results showed that Ag, Bi, In, Sb, Sn, and Tl contents decreased both with the distance to the Pb-Zn smelter as well as the soil depth, hinting that these elements were mainly originated from the Pb-Zn smelting operations and were introduced into soils through atmospheric deposition. Soil Ge was influenced by the smelter at a less extent, while the distributions of Co, Cr, and Ni were roughly even among most sampling sites and soil depths, suggesting that they were primarily derived from natural sources. The contamination status, as revealed by the geo-accumulation index (I geo), indicated that In and Ag were the most enriched elements, followed by Sb, Bi, and Sn. In general, Cr, Tl, Co, Ni, and Ge were of an uncontaminated status.

  4. COAL DUST EMISSION PROBLEM

    Directory of Open Access Journals (Sweden)

    M. M. Biliaiev

    2016-12-01

    Full Text Available Purpose. The article aims to develop 2D numerical models for the prediction of atmospheric pollution during transportation of coal in the railway car, as well as the ways to protect the environment and the areas near to the mainline from the dust emission due to the air injection installation. Methodology. To solve this problem there were developed numerical models based on the use of the equations of motion of an inviscid incompressible fluid and mass transfer. For the numerical integration of the transport equation of the pollutant the implicit alternating-triangular difference scheme was used. For numerical integration of the 2D equation for the velocity potential the method of total approximation was used. The developed numerical models are the basis of established software package. On the basis of the constructed numerical models it was carried out a computational experiment to assess the level of air pollution when transporting bulk cargo by rail when the railway car has the air injection. Findings. 2D numerical models that belong to the class «diagnostic models» were developed. These models take into account the main physical factors affecting the process of dispersion of dust pollution in the atmosphere during transportation of bulk cargo. The developed numerical models make it possible to calculate the dust loss process, taking into account the use of the air injection of the car. They require a small cost of the computer time during practical realization at the low and medium power machines. There were submitted computational calculations to determine pollutant concentrations and the formation of the zone of pollution near the train with bulk cargo in «microscale» scale taking into account the air curtains. Originality. 2D numerical models taking into account the relevant factors influencing the process of dispersion of pollutants in the atmosphere, and the formation of the zone of pollution during transportation of bulk cargo by

  5. Copper and copper-nickel alloys as zebra mussel antifoulants

    Energy Technology Data Exchange (ETDEWEB)

    Dormon, J.M.; Cottrell, C.M.; Allen, D.G.; Ackerman, J.D.; Spelt, J.K. [Univ. of Toronto, Ontario (Canada)

    1996-04-01

    Copper has been used in the marine environment for decades as cladding on ships and pipes to prevent biofouling by marine mussels (Mytilus edulis L.). This motivated the present investigation into the possibility of using copper to prevent biofouling in freshwater by both zebra mussels and quagga mussels (Dreissena polymorpha and D. bugensis collectively referred to as zebra mussels). Copper and copper alloy sheet proved to be highly effective in preventing biofouling by zebra mussels over a three-year period. Further studies were conducted with copper and copper-nickel mesh (lattice of expanded metal) and screen (woven wire with a smaller hole size), which reduced the amount of copper used. Copper screen was also found to be strongly biofouling-resistant with respect to zebra mussels, while copper mesh reduced zebra mussel biofouling in comparison to controls, but did not prevent it entirely. Preliminary investigations into the mechanism of copper antifouling, using galvanic couples, indicated that the release of copper ions from the surface of the exposed metal into the surrounding water is directly or indirectly responsible for the biofouling resistance of copper.

  6. Electrical conduction in composites containing copper core-copper

    Indian Academy of Sciences (India)

    Composites of nanometre-sized copper core-copper oxide shell with diameters in the range 6.1 to 7.3 nm dispersed in a silica gel were synthesised by a technique comprising reduction followed by oxidation of a suitably chosen precursor gel. The hot pressed gel powders mixed with nanometre-sized copper particles ...

  7. Dust of dark energy

    International Nuclear Information System (INIS)

    Lim, Eugene A.; Sawicki, Ignacy; Vikman, Alexander

    2010-01-01

    We introduce a novel class of field theories where energy always flows along timelike geodesics, mimicking in that respect dust, yet which possess non-zero pressure. This theory comprises two scalar fields, one of which is a Lagrange multiplier enforcing a constraint between the other's field value and derivative. We show that this system possesses no wave-like modes but retains a single dynamical degree of freedom. Thus, the sound speed is always identically zero on all backgrounds. In particular, cosmological perturbations reproduce the standard behaviour for hydrodynamics in the limit of vanishing sound speed. Using all these properties we propose a model unifying Dark Matter and Dark Energy in a single degree of freedom. In a certain limit this model exactly reproduces the evolution history of ΛCDM, while deviations away from the standard expansion history produce a potentially measurable difference in the evolution of structure

  8. Ulysses dust measurements near Jupiter.

    Science.gov (United States)

    Grün, E; Zook, H A; Baguhl, M; Fechtig, H; Hanner, M S; Kissel, J; Lindblad, B A; Linkert, D; Linkert, G; Mann, I B

    1992-09-11

    Submicrometer- to micrometer-sized particles were recorded by the Ulysses dust detector within 40 days of the Jupiter flyby. Nine impacts were recorded within 50 Jupiter radii with most of them recorded after closest approach. Three of these impacts are consistent with particles on prograde orbits around Jupiter and the rest are believed to have resulted from gravitationally focused interplanetary dust. From the ratio of the impact rate before the Jupiter flyby to the impact rate after the Jupiter flyby it is concluded that interplanetary dust particles at the distance of Jupiter move on mostly retrograde orbits. On 10 March 1992, Ulysses passed through an intense dust stream. The dust detector recorded 126 impacts within 26 hours. The stream particles were moving on highly inclined and apparently hyperbolic orbits with perihelion distances of >5 astronomical units. Interplanetary dust is lost rather quickly from the solar system through collisions and other mechanisms and must be almost continuously replenished to maintain observed abundances. Dust flux measurements, therefore, give evidence of the recent rates of production from sources such as comets, asteroids, and moons, as well as the possible presence of interstellar grains.

  9. Experiments on Dust Grain Charging

    Science.gov (United States)

    Abbas, M. N.; Craven, P. D.; Spann, J. F.; Tankosic, D.; LeClair, A.; West, E. A.

    2004-01-01

    Dust particles in various astrophysical environments are charged by a variety of mechanisms generally involving collisional processes with other charged particles and photoelectric emission with UV radiation from nearby sources. The sign and the magnitude of the particle charge are determined by the competition between the charging processes by UV radiation and collisions with charged particles. Knowledge of the particle charges and equilibrium potentials is important for understanding of a number of physical processes. The charge of a dust grain is thus a fundamental parameter that influences the physics of dusty plasmas, processes in the interplanetary medium and interstellar medium, interstellar dust clouds, planetary rings, cometary and outer atmospheres of planets etc. In this paper we present some results of experiments on charging of dust grains carried out on a laboratory facility capable levitating micron size dust grains in an electrodynamic balance in simulated space environments. The charging/discharging experiments were carried out by exposing the dust grains to energetic electron beams and UV radiation. Photoelectric efficiencies and yields of micron size dust grains of SiO2, and lunar simulates obtained from NASA-JSC will be presented.

  10. Study of copper fluorination

    International Nuclear Information System (INIS)

    Gillardeau, J.

    1967-02-01

    This report deals with the action of fluorine on copper. Comprehensive descriptions are given of the particular technological methods and of the preparation of the reactants. This fluorination reaction has been studied at medium and low fluorine pressures. A nucleation and growth phenomenon is described. The influence of a pollution of the gas phase on the fluorination process is described. The solid-state reaction between cupric fluoride and cooper has also been studied. A special study has been made of the growth of copper deposits by thermal decomposition of gaseous fluorides. (author) [fr

  11. Brazing copper to dispersion-strengthened copper

    Science.gov (United States)

    Ryding, David G.; Allen, Douglas; Lee, Richard H.

    1996-11-01

    The advanced photon source is a state-of-the-art synchrotron light source that will produce intense x-ray beams, which will allow the study of smaller samples and faster reactions and processes at a greater level of detail than has ben possible to date. The beam is produced by using third- generation insertion devices in a 7-GeV electron/positron storage ring that is 1,104 meters in circumference. The heat load from these intense high-power devices is very high, and certain components must sustain total heat loads of 3 to 15 kW and heat fluxes of 30 W/mm$_2). Because the beams will cycle on and off many times, thermal shock and fatigue will be a problem. High heat flux impinging on a small area causes a large thermal gradient that results in high stress. GlidCop, a dispersion-strengthened copper, is the desired design material because of its high thermal conductivity and superior mechanical properties as compared to copper and its alloys. GlidCop is not amenable to joining by fusion welding, and brazing requires diligence because of high diffusivity. Brazing procedures were developed using optical and scanning electron microscopy.

  12. A dust-free dock

    Energy Technology Data Exchange (ETDEWEB)

    Merrion, D. [E & F Services Ltd. (United Kingdom)

    2002-10-01

    This paper describes the process of unloading coal, petcoke and other dusty products in environmentally-sensitive areas. It presents a case study of the deepwater Port of Foynes on the west coast of Ireland which imports animal feed, fertiliser, coal and cement clinker, where dockside mobile loaders (DMLs) have eliminated spillage and controlled dust, and a record case study of the Humber International Terminal in the UK, where air curtinas, dust suppression grids and EFFEX{reg_sign} filters overcome the dust problems. 2 photos.

  13. Triton's streaks as windblown dust

    Science.gov (United States)

    Sagan, Carl; Chyba, Christopher

    1990-01-01

    Explanations for the surface streaks observed by Voyager 2 on Triton's southern hemisphere are discussed. It is shown that, despite Triton's tenuous atmosphere, low-cohesion dust trains with diameters of about 5 micron or less may be carried into suspension by aeolian surface shear stress, given expected geostrophic wind speeds of about 10 m/s. For geyser-like erupting dust plumes, it is shown that dust-settling time scales and expected wind velocities can produce streaks with length scales in good agreement with those of the streaks. Thus, both geyserlike eruptions or direct lifting by surface winds appear to be viable mechanisms for the origin of the streaks.

  14. [Asthma due to grain dust].

    Science.gov (United States)

    Baur, X; Preisser, A; Wegner, R

    2003-06-01

    The actual literature as well as two case reports described in detail show that grain dust induces asthmatic reactions and ODTS which are obviously not of allergic origin. For diagnosis occupational-type exposure tests are decisive whereas allergological testing usually is not. Endotoxins which are present in the grain dust samples in high concentrations have to be regarded as the major causative components. To avoid irreversible lung function impairment a comprehensive early diagnosis is necessary. Generally, a remarkable reduction of exposure to dust with high levels of airborne endotoxin in agriculture has to be achieved since in many workplaces corresponding exposures are still rather high.

  15. Dust Dynamics Near Planetary Surfaces

    Science.gov (United States)

    Colwell, Joshua; Hughes, Anna; Grund, Chris

    Observations of a lunar "horizon glow" by several Surveyor spacecraft in the 1960s opened the study of the dynamics of charged dust particles near planetary surfaces. The surfaces of the Moon and other airless planetary bodies in the solar system (asteroids, and other moons) are directly exposed to the solar wind and ionizing solar ultraviolet radiation, resulting in a time-dependent electric surface potential. Because these same objects are also exposed to bombardment by micrometeoroids, the surfaces are usually characterized by a power-law size distribution of dust that extends to sub-micron-sized particles. Individual particles can acquire a charge different from their surroundings leading to electrostatic levitation. Once levitated, particles may simply return to the surface on nearly ballistic trajectories, escape entirely from the moon or asteroid if the initial velocity is large, or in some cases be stably levitated for extended periods of time. All three outcomes have observable consequences. Furthermore, the behavior of charged dust near the surface has practical implications for planned future manned and unmanned activities on the lunar surface. Charged dust particles also act as sensitive probes of the near-surface plasma environment. Recent numerical modeling of dust levitation and transport show that charged micron-sized dust is likely to accumulate in topographic lows such as craters, providing a mechanism for the creation of dust "ponds" observed on the asteroid 433 Eros. Such deposition can occur when particles are supported by the photoelectron sheath above the dayside and drift over shadowed regions of craters where the surface potential is much smaller. Earlier studies of the lunar horizon glow are consistent with those particles being on simple ballistic trajectories following electrostatic launching from the surface. Smaller particles may be accelerated from the lunar surface to high altitudes consistent with observations of high altitude

  16. Tissue metal levels in Muskrat (Ondatra zibethica) collected near the Sudbury (Ontario) ore-smelters; prospects for biomonitoring marsh pollution

    Energy Technology Data Exchange (ETDEWEB)

    Parker, G.H

    2004-05-01

    An examination of tissue metal levels in Sudbury-area muskrat (Ondatra zibethica) revealed that animals collected in the vicinity of the local ore-smelters contained elevated burdens of Cd and Ni in their liver and kidneys. Respective tissue concentrations averaged 2-fold and 3- to 6-fold higher than background values and are believed to reflect accumulations resulting from food chain contamination in regional marshes, including that reportedly characterizing Typha latifolia stands--their primary food source--and adherent sediments which may be consumed inadvertently while feeding. No evidence of site-influence or enhanced tissue metal levels was seen for Cu, Pb or Zn. While Cd : Ni accumulations were positively correlated in both the liver (r=0.78) and the kidneys (r=0.65), between-tissue comparisons indicated that hepatic : renal burdens were significantly correlated (r=0.75) only in the case of Ni. With the exception of 30-35% lower hepatic Zn levels in females relative to males within the Sudbury population, tissue metal levels did not vary according to sex or age class at either site. Our findings substantiate the potential of muskrat to serve as useful bioindicators/monitors of metal pollution in semi-aquatic environments. - Muskrats appear to be useful bioindicators of metal pollution in semi-aquatic environments.

  17. Remediation of contaminated agricultural soils near a former Pb/Zn smelter in Austria: Batch, pot and field experiments

    International Nuclear Information System (INIS)

    Friesl, W.; Friedl, J.; Platzer, K.; Horak, O.; Gerzabek, M.H.

    2006-01-01

    Metal contaminated crops from contaminated soils are possible hazards for the food chain. The aim of this study was to find practical and cost-effective measures to reduce metal uptake in crops grown on metal contaminated soils near a former metal smelter in Austria. Metal-inefficient cultivars of crop plants commonly grown in the area were investigated in combination with in-situ soil amendments. A laboratory batch experiment using 15 potential amendments was used to select 5 amendments to treat contaminated soil in a pot study using two Barley (Hordeum vulgare L.) cultivars that differed in their ability to accumulate cadmium. Results from this experiment identified 3 of these amendments for use in a field trial. In the pot experiment a reduction in ammonium nitrate extractable Cd (<41%) and Pb (<49%) compared to the controls was measured, with a concurrent reduction of uptake into barley grain (Cd < 62%, Pb < 68%). In the field extractable fractions of Cd, Pb, and Zn were reduced by up to 96%, 99%, and 99%, respectively in amended soils. - Gravel sludge and red mud, combined with metal-excluding cultivars, can improve contaminated land

  18. Streptomyces pactum assisted phytoremediation in Zn/Pb smelter contaminated soil of Feng County and its impact on enzymatic activities

    Science.gov (United States)

    Ali, Amjad; Guo, Di; Mahar, Amanullah; Ma, Fang; Li, Ronghua; Shen, Feng; Wang, Ping; Zhang, Zengqiang

    2017-04-01

    Anthropogenic activities, such as industrial expansion, smelting, mining and agricultural practices, have intensified the discharge of potentially toxic trace elements (PTEs) into the environment, threatening human health and other organisms. To assist phytoremediation by sorghum in soil contaminated by smelters/mines in Feng County (FC), a pot experiment was performed to examine the phytoremediation potential of Streptomyces pactum (Act12) + biochar. The results showed that root uptake of Zn and Cd was reduced by 45 and 22%, respectively, while the uptake of Pb and Cu increased by 17 and 47%, respectively. The shoot and root dry weight and chlorophyll content improved after Act12 inoculation. β-glucosidase, alkaline phosphatase and urease activities in soil improved and antioxidant activities (POD, PAL, PPO) decreased after application of Act12 + biochar due to a reduction in stress from PTEs. BCF, TF and MEA confirmed the role of Act12 in the amelioration and translocation of PTEs. PCA analysis showed a correlation between different factors that affect the translocation of PTEs. Overall, Act12 promoted the phytoremediation of PTEs. Field experiments on Act12 + biochar may provide new insights into the rehabilitation and restoration of soils contaminated by mines.

  19. Tissue metal levels in Muskrat (Ondatra zibethica) collected near the Sudbury (Ontario) ore-smelters; prospects for biomonitoring marsh pollution

    International Nuclear Information System (INIS)

    Parker, G.H.

    2004-01-01

    An examination of tissue metal levels in Sudbury-area muskrat (Ondatra zibethica) revealed that animals collected in the vicinity of the local ore-smelters contained elevated burdens of Cd and Ni in their liver and kidneys. Respective tissue concentrations averaged 2-fold and 3- to 6-fold higher than background values and are believed to reflect accumulations resulting from food chain contamination in regional marshes, including that reportedly characterizing Typha latifolia stands--their primary food source--and adherent sediments which may be consumed inadvertently while feeding. No evidence of site-influence or enhanced tissue metal levels was seen for Cu, Pb or Zn. While Cd : Ni accumulations were positively correlated in both the liver (r=0.78) and the kidneys (r=0.65), between-tissue comparisons indicated that hepatic : renal burdens were significantly correlated (r=0.75) only in the case of Ni. With the exception of 30-35% lower hepatic Zn levels in females relative to males within the Sudbury population, tissue metal levels did not vary according to sex or age class at either site. Our findings substantiate the potential of muskrat to serve as useful bioindicators/monitors of metal pollution in semi-aquatic environments. - Muskrats appear to be useful bioindicators of metal pollution in semi-aquatic environments

  20. Urban quality of life and industrial project management: the case of Alcan aluminium smelter in Alma, Quebec, Canada

    International Nuclear Information System (INIS)

    Simard, M.

    2003-01-01

    This quality-of-life study involving the population of Alma (30 126 inhabitants) is part of a five-year, multidisciplinary research program entitled 'Modelisation du suivi des impacts sociaux de l'aluminerie Alma'. The goal of this research program is to document the social impacts arising from the establishment of the Alcan industrial mega-complex in Alma (see Map 1). The Alma smelter began operation in 2001. It employs 865 people and has a production capacity of 407 000 MT of aluminium ingots. The research program is being carried out in parallel with the project, rather than retroactively. Thus, various thematic reports have been published on topics such as the project's economic spin-off and changes in the housing and transportation sectors. More specifically, this study aims to gauge the perceptions of Alma residents regarding their quality of life as stakeholders. In order to ensure that the study produced a more accurate indication of the community's evolution and to tie the study in with the various phases of the implementation of this industrial mega-project, it was conducted in three parts, i.e., in 1998, 2000 and 2002, corresponding to the planning, construction and operation phases. (author)

  1. Bounded dust-acoustic waves in a cylindrically bounded collisional dusty plasma with dust charge variation

    International Nuclear Information System (INIS)

    Wei Nanxia; Xue Jukui

    2006-01-01

    Taking into account the boundary, particle collisions, and dust charging effects, dust-acoustic waves in a uniform cylindrically bounded dusty plasma is investigated analytically, and the dispersion relation for the dust-acoustic wave is obtained. The effects of boundary, dust charge variation, particle collision, and dust size on the dust-acoustic wave are discussed in detail. Due to the bounded cylindrical boundary effects, the radial wave number is discrete, i.e., the spectrum is discrete. It is shown that the discrete spectrum, the adiabatic dust charge variation, dust grain size, and the particle collision have significant effects on the dust-acoustic wave

  2. Copper and Copper Proteins in Parkinson’s Disease

    Directory of Open Access Journals (Sweden)

    Sergio Montes

    2014-01-01

    Full Text Available Copper is a transition metal that has been linked to pathological and beneficial effects in neurodegenerative diseases. In Parkinson’s disease, free copper is related to increased oxidative stress, alpha-synuclein oligomerization, and Lewy body formation. Decreased copper along with increased iron has been found in substantia nigra and caudate nucleus of Parkinson’s disease patients. Copper influences iron content in the brain through ferroxidase ceruloplasmin activity; therefore decreased protein-bound copper in brain may enhance iron accumulation and the associated oxidative stress. The function of other copper-binding proteins such as Cu/Zn-SOD and metallothioneins is also beneficial to prevent neurodegeneration. Copper may regulate neurotransmission since it is released after neuronal stimulus and the metal is able to modulate the function of NMDA and GABA A receptors. Some of the proteins involved in copper transport are the transporters CTR1, ATP7A, and ATP7B and the chaperone ATOX1. There is limited information about the role of those biomolecules in the pathophysiology of Parkinson’s disease; for instance, it is known that CTR1 is decreased in substantia nigra pars compacta in Parkinson’s disease and that a mutation in ATP7B could be associated with Parkinson’s disease. Regarding copper-related therapies, copper supplementation can represent a plausible alternative, while copper chelation may even aggravate the pathology.

  3. Dust particle formation in silane plasmas

    NARCIS (Netherlands)

    Sorokin, M.

    2005-01-01

    Dust can be found anywhere: in the kitchen, in the car, in space… Not surprisingly we also see dust in commercial and laboratory plasmas. Dust can be introduced in the plasma, but it can also grow there by itself. In the microelectronics industry, contamination of the processing plasma by dust is an

  4. PERSPECTIVE: Dust, fertilization and sources

    Science.gov (United States)

    Remer, Lorraine A.

    2006-11-01

    Aerosols, tiny suspended particles in the atmosphere, play an important role in modifying the Earth's energy balance and are essential for the formation of cloud droplets. Suspended dust particles lifted from the world's arid regions by strong winds contain essential minerals that can be transported great distances and deposited into the ocean or on other continents where productivity is limited by lack of usable minerals [1]. Dust can transport pathogens as well as minerals great distance, contributing to the spread of human and agricultural diseases, and a portion of dust can be attributed to human activity suggesting that dust radiative effects should be included in estimates of anthropogenic climate forcing. The greenish and brownish tints in figure 1 show the wide extent of monthly mean mineral dust transport, as viewed by the MODerate resolution Imaging Spectroradiometer (MODIS) satellite sensor. The monthly mean global aerosol system for February 2006 from the MODIS aboard the Terra satellite Figure 1. The monthly mean global aerosol system for February 2006 from the MODIS aboard the Terra satellite. The brighter the color, the greater the aerosol loading. Red and reddish tints indicate aerosol dominated by small particles created primarily from combustion processes. Green and brownish tints indicate larger particles created from wind-driven processes, usually transported desert dust. Note the bright green band at the southern edge of the Saharan desert, the reddish band it must cross if transported to the southwest and the long brownish transport path as it crosses the Atlantic to South America. Image courtesy of the NASA Earth Observatory (http://earthobservatory.nasa.gov). Even though qualitatively we recognize the extent and importance of dust transport and the role that it plays in fertilizing nutrient-limited regions, there is much that is still unknown. We are just now beginning to quantify the amount of dust that exits one continental region and the

  5. High-temperature experimental and thermodynamic modelling research on the pyrometallurgical processing of copper

    Science.gov (United States)

    Hidayat, Taufiq; Shishin, Denis; Decterov, Sergei A.; Hayes, Peter C.; Jak, Evgueni

    2017-01-01

    Uncertainty in the metal price and competition between producers mean that the daily operation of a smelter needs to target high recovery of valuable elements at low operating cost. Options for the improvement of the plant operation can be examined and decision making can be informed based on accurate information from laboratory experimentation coupled with predictions using advanced thermodynamic models. Integrated high-temperature experimental and thermodynamic modelling research on phase equilibria and thermodynamics of copper-containing systems have been undertaken at the Pyrometallurgy Innovation Centre (PYROSEARCH). The experimental phase equilibria studies involve high-temperature equilibration, rapid quenching and direct measurement of phase compositions using electron probe X-ray microanalysis (EPMA). The thermodynamic modelling deals with the development of accurate thermodynamic database built through critical evaluation of experimental data, selection of solution models, and optimization of models parameters. The database covers the Al-Ca-Cu-Fe-Mg-O-S-Si chemical system. The gas, slag, matte, liquid and solid metal phases, spinel solid solution as well as numerous solid oxide and sulphide phases are included. The database works within the FactSage software environment. Examples of phase equilibria data and thermodynamic models of selected systems, as well as possible implementation of the research outcomes to selected copper making processes are presented.

  6. Creative Copper Crests

    Science.gov (United States)

    Knab, Thomas

    2011-01-01

    In this article, the author discusses how to create an art activity that would link the computer-created business cards of fourth-grade students with an upcoming school-wide medieval event. Creating family crests from copper foil would be a great connection, since they, like business cards, are an individual's way to identify themselves to others.…

  7. and copper(II)

    Indian Academy of Sciences (India)

    Unknown

    (II) and copper(II)–zinc(II) complexes. SUBODH KUMAR1, R N PATEL1*, P V KHADIKAR1 and. K B PANDEYA2. 1 Department of Chemistry, APS University, Rewa 486 003, India. 2 CSJM University, Kanpur 208 016, India e-mail: (R N Patel) ...

  8. Modeling of surface dust concentrations using neural networks and kriging

    Science.gov (United States)

    Buevich, Alexander G.; Medvedev, Alexander N.; Sergeev, Alexander P.; Tarasov, Dmitry A.; Shichkin, Andrey V.; Sergeeva, Marina V.; Atanasova, T. B.

    2016-12-01

    Creating models which are able to accurately predict the distribution of pollutants based on a limited set of input data is an important task in environmental studies. In the paper two neural approaches: (multilayer perceptron (MLP)) and generalized regression neural network (GRNN)), and two geostatistical approaches: (kriging and cokriging), are using for modeling and forecasting of dust concentrations in snow cover. The area of study is under the influence of dust emissions from a copper quarry and a several industrial companies. The comparison of two mentioned approaches is conducted. Three indices are used as the indicators of the models accuracy: the mean absolute error (MAE), root mean square error (RMSE) and relative root mean square error (RRMSE). Models based on artificial neural networks (ANN) have shown better accuracy. When considering all indices, the most precision model was the GRNN, which uses as input parameters for modeling the coordinates of sampling points and the distance to the probable emissions source. The results of work confirm that trained ANN may be more suitable tool for modeling of dust concentrations in snow cover.

  9. Reagent conditions of the flotation of copper, copper - molybdenum and copper -zinc ores in foreing countries

    International Nuclear Information System (INIS)

    Nevaeva, L.M.

    1983-01-01

    Reagents-collectors and frothers, used abroad in reagent regimes of flotation of copper, copper-molybdenum and copper zinc ores, have been considered. Xanthogenates, aerofloats, xanthogenformiates, thionocarbamates are mainly used as reagents-collectors. Methylizobutylcarbinol and Daufros are used as reagents-frothers

  10. Hypoxia targeting copper complexes

    International Nuclear Information System (INIS)

    Dearling, J.L.

    1998-11-01

    The importance and incidence of tumour hypoxia, its measurement and current treatments available, including pharmacological and radiopharmacological methods of targeting hypoxia, are discussed. A variety of in vitro and in vivo methods for imposing hypoxia have been developed and are reviewed. Copper, its chemistry, biochemistry and radiochemistry, the potential for use of copper radionuclides and its use to date in this field is considered with particular reference to the thiosemicarbazones. Their biological activity, metal chelation, in vitro and in vivo studies of their radiocopper complexes and the potential for their use as hypoxia targeting radiopharmaceuticals is described. The reduction of the copper(II) complex to copper(l), its pivotal importance in their biological behaviour, and the potential for manipulation of this to effect hypoxia selectivity are described. An in vitro method for assessing the hypoxia selectivity of radiopharmaceuticals is reported. The rapid deoxygenation and high viability of a mammalian cell culture in this system is discussed and factors which may affect the cellular uptake of a radiopharmaceutical are described. The design, synthesis and complexation with copper and radiocopper of a range of bis(thiosemicarbazones) is reported. Synthesis of these compounds is simple giving high yields of pure products. The characteristics of the radiocopper complexes ( 64 Cu) including lipophilicity and redox activity are reported (reduction potentials in the range -0.314 - -0.590 V). High cellular uptakes of the radiocopper complexes of the ligands, in hypoxic and normoxic EMT6 and CHO320 cells, were observed. Extremes of selectivity are shown ranging from the hypoxia selective 64 Cu(II)ATSM to normoxic cell selective 64 Cu(II)GTS. The selectivities observed are compared with the physico chemical characteristics of the complexes. A good correlation exists between selectivity of the complex and its Cu(II)/Cu(I) reduction potential, with hypoxia

  11. Loess and Eolian Dust Data

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Records of past environment derived from Loess and Eolian dust (silt-sized material deposited on the Earth surface by the surface winds. Parameter keywords describe...

  12. 75 FR 3881 - Combustible Dust

    Science.gov (United States)

    2010-01-25

    ..., rubber, drugs, dried blood, dyes, certain textiles, and metals (such as aluminum and magnesium..., furniture manufacturing, metal processing, fabricated metal products and machinery manufacturing, pesticide... standard that will comprehensively address the fire and explosion hazards of combustible dust. The Agency...

  13. Rethinking wood dust safety standards

    OpenAIRE

    Ratnasingam, Jega; Wai, Lim Tau; Ramasamy, Geetha; Ioras, Florin; Tadin, Ishak; Universiti Putra Malaysia; Buckinghamshire New University; Centre for Occupational Safety and Health Singapore

    2015-01-01

    The current universal work safety and health standards pertaining to wood dust in factories lack the localisation required. As a study has shown, there is a urgent need to reevaluate the current guidelines and practices.

  14. Book review: Hollowed ground—Copper mining and community building on Lake Superior, 1840s–1990s

    Science.gov (United States)

    Schulz, Klaus J.

    2010-01-01

    In 1843, six years before the Forty-niners headed west for the goldfields of California, the United States’ first great mineral rush began to a land that was, as Patrick Henry told Congress, “beyond the most distant wilderness and remote as the moon.” He was referring to the Keweenaw Peninsula of northern Michigan. This rush was not for gold or silver, but for copper. And not just any copper, but native copper, so pure it required little refining before use. The early horde of fortune-seekers came with visions of finding mountains of solid copper, spurred on by stories of large masses of “float copper” that included the famous Ontonagon Boulder, a large mass of native copper originally found lying 32 km up the steep and rugged valley of the Ontonagon River (and now gathering dust in the Smithsonian Museum).

  15. Precursors for formation of copper selenide, indium selenide, copper indium diselenide, and/or copper indium gallium diselenide films

    Science.gov (United States)

    Curtis, Calvin J; Miedaner, Alexander; Van Hest, Maikel; Ginley, David S

    2014-11-04

    Liquid-based precursors for formation of Copper Selenide, Indium Selenide, Copper Indium Diselenide, and/or copper Indium Galium Diselenide include copper-organoselenides, particulate copper selenide suspensions, copper selenide ethylene diamine in liquid solvent, nanoparticulate indium selenide suspensions, and indium selenide ethylene diamine coordination compounds in solvent. These liquid-based precursors can be deposited in liquid form onto substrates and treated by rapid thermal processing to form crystalline copper selenide and indium selenide films.

  16. Physical properties of five grain dust types.

    OpenAIRE

    Parnell, C B; Jones, D D; Rutherford, R D; Goforth, K J

    1986-01-01

    Physical properties of grain dust derived from five grain types (soybean, rice, corn, wheat, and sorghum) were measured and reported. The grain dusts were obtained from dust collection systems of terminal grain handling facilities and were assumed to be representative of grain dust generated during the handling process. The physical properties reported were as follows: particle size distributions and surface area measurements using a Coulter Counter Model TAII; percent dust fractions less tha...

  17. Efficient radiative transfer in dust grain mixtures

    OpenAIRE

    Wolf, S.

    2002-01-01

    The influence of a dust grain mixture consisting of spherical dust grains with different radii and/or chemical composition on the resulting temperature structure and spectral energy distribution of a circumstellar shell is investigated. The comparison with the results based on an approximation of dust grain parameters representing the mean optical properties of the corresponding dust grain mixture reveal that (1) the temperature dispersion of a real dust grain mixture decreases substantially ...

  18. Grain dust and the lungs.

    Science.gov (United States)

    Chan-Yeung, M.; Ashley, M. J.; Grzybowski, S.

    1978-01-01

    Grain dust is composed of a large number of materials, including various types of grain and their disintegration products, silica, fungi, insects and mites. The clinical syndromes described in relation to exposure to grain dust are chronic bronchitis, grain dust asthma, extrinsic allergic alveolitis, grain fever and silo-filler's lung. Rhinitis and conjunctivitis are also common in grain workers. While the concentration and the quality of dust influence the frequency and the type of clinical syndrome in grain workers, host factors are also important. Of the latter, smoking is the most important factor influencing the frequency of chronic bronchitis. The role of atopy and of bronchial hyperreactivity in grain dust asthma has yet to be assessed. Several well designed studies are currently being carried out in North America not only to delineate the frequency of the respiratory abnormalities, the pathogenetic mechanisms and the host factors, but also to establish a meaningful threshold limit concentration for grain dust. Images p1272-a PMID:348288

  19. Charged dust structures in plasmas

    International Nuclear Information System (INIS)

    Cramer, N.F.; Vladimirov, S.V.

    1999-01-01

    We report here on theoretical investigations of the mechanical-electrostatic modes of vibration of a dust-plasma crystal, extending earlier work on the transverse modes of a horizontal line of grains (where the ions flow vertically downward to a plane horizontal cathode), the modes of two such lines of grains, and the modes of a vertical string of grains. The last two arrangements have the unique feature that the effect of the background plasma on the mutual grain interaction is asymmetric because of the wake downstream of the grains studied in. The characteristic frequencies of the vibrations are dependent on the parameters of the plasma and the dust grains, such as the Debye length and the grain charge, and so measurement of the frequencies could provide diagnostics of these quantities. Although the current boom in dusty plasma research is driven mainly by such industrial applications as plasma etching, sputtering and deposition, the physical outcomes of investigations in this rapidly expanding field cover many important topics in space physics and astrophysics as well. Examples are the interaction of dust with spacecraft, the structure of planetary rings, star formation, supernova explosions and shock waves. In addition, the study of the influence of dust in environmental research, such as in the Earth's ionosphere and atmosphere, is important. The unique binding of dust particles in a plasma opens possibilities for so-called super-chemistry, where the interacting bound elements are not atoms but dust grains

  20. Suspended dust in Norwegian cities

    International Nuclear Information System (INIS)

    2001-01-01

    According to calculations, at least 80 000 people in Oslo and 8 000 in Trondheim were annoyed by too much suspended dust in 2000. The dust concentration is greatest in the spring, presumably because dust is swirling up from melting snow and ice on the streets. Car traffic is the main source of the dust, except for some of the most highly exposed regions where wood-firing from old stoves contributes up to 70 percent of the dust. National targets for air quality include suspended dust, nitrogen dioxide, sulphur dioxide and benzene. Calculations show that nitrogen dioxide emissions exceeding the limit affected 4 000 people in Oslo and 1 000 people in Trondheim. The sulphur dioxide emissions in the major cities did non exceed the national quality limit; they did exceed the limit in some of the smaller industrial centres. In Trondheim, measurements show that the national limit for benzene was exceeded. Most of the emission of nitrogen dioxide comes from the road traffic. Local air pollution at times causes considerable health- and well-being problems in the larger cities and industrial centres, where a great part of the population may be at risk of early death, infection of the respiratory passage, heart- and lung diseases and cancer

  1. Study on treatment of dust by dismantling

    International Nuclear Information System (INIS)

    Torikai, K.; Suzuki, K.

    1987-01-01

    In dismantling of nuclear reactors, various kinds of treatment of dust generated by cutting or dismantling concrete structures of components of reactors are evaluated for safety, cost, and performance comparing the work in air with water. A method of dust treatment for work in air is discussed. The dry method has an easy operation in practice and a good performance in the equipment, but has problem on the prevention from radioactive contamination by diffusion of dust in air. For the purpose of advancing the strong points and eliminating the weak points in dry method, an improved venturi scrubber system is proposed for dismantling work as a dust collecting system. The system consists of dust absorbing pipe, dust collector, separator of dust and water and dust transfer equipment to a storage of waste. This system would be expected to have better performance and lower operating cost in decommissioning nuclear reactors, especially, the number of dust filters, for example, HEPA filters, will be considerably saved

  2. 40 CFR Appendix Xi to Part 266 - Lead-Bearing Materials That May be Processed in Exempt Lead Smelters

    Science.gov (United States)

    2010-07-01

    ... PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS... pallets Water treatment sludges, filter cakes, residues, and solids Emission control dusts, sludges, filter cakes, residues, and solids from lead-associated industries (e.g., K069 and D008 wastes) Spent...

  3. The effect of the hemochromatosis (HFE genotype on lead load and iron metabolism among lead smelter workers.

    Directory of Open Access Journals (Sweden)

    Guangqin Fan

    Full Text Available Both an excess of toxic lead (Pb and an essential iron disorder have been implicated in many diseases and public health problems. Iron metabolism genes, such as the hemochromatosis (HFE gene, have been reported to be modifiers for lead absorption and storage. However, the HFE gene studies among the Asian population with occupationally high lead exposure are lacking.To explore the modifying effects of the HFE genotype (wild-type, H63D variant and C282Y variant on the Pb load and iron metabolism among Asian Pb-workers with high occupational exposure.Seven hundred and seventy-one employees from a lead smelter manufacturing company were tested to determine their Pb intoxication parameters, iron metabolic indexes and identify the HFE genotype. Descriptive and multivariate analyses were conducted.Forty-five H63D variant carriers and no C282Y variant carrier were found among the 771 subjects. Compared with subjects with the wild-type genotype, H63D variant carriers had higher blood lead levels, even after controlling for factors such as age, sex, marriage, education, smoking and lead exposure levels. Multivariate analyses also showed that the H63D genotype modifies the associations between the blood lead levels and the body iron burden/transferrin.No C282Y variant was found in this Asian population. The H63D genotype modified the association between the lead and iron metabolism such that increased blood lead is associated with a higher body iron content or a lower transferrin in the H63D variant. It is indicated that H63D variant carriers may be a potentially highly vulnerable sub-population if they are exposed to high lead levels occupationally.

  4. The effect of the hemochromatosis (HFE) genotype on lead load and iron metabolism among lead smelter workers.

    Science.gov (United States)

    Fan, Guangqin; Du, Guihua; Li, Huijun; Lin, Fen; Sun, Ziyong; Yang, Wei; Feng, Chang; Zhu, Gaochun; Li, Yanshu; Chen, Ying; Jiao, Huan; Zhou, Fankun

    2014-01-01

    Both an excess of toxic lead (Pb) and an essential iron disorder have been implicated in many diseases and public health problems. Iron metabolism genes, such as the hemochromatosis (HFE) gene, have been reported to be modifiers for lead absorption and storage. However, the HFE gene studies among the Asian population with occupationally high lead exposure are lacking. To explore the modifying effects of the HFE genotype (wild-type, H63D variant and C282Y variant) on the Pb load and iron metabolism among Asian Pb-workers with high occupational exposure. Seven hundred and seventy-one employees from a lead smelter manufacturing company were tested to determine their Pb intoxication parameters, iron metabolic indexes and identify the HFE genotype. Descriptive and multivariate analyses were conducted. Forty-five H63D variant carriers and no C282Y variant carrier were found among the 771 subjects. Compared with subjects with the wild-type genotype, H63D variant carriers had higher blood lead levels, even after controlling for factors such as age, sex, marriage, education, smoking and lead exposure levels. Multivariate analyses also showed that the H63D genotype modifies the associations between the blood lead levels and the body iron burden/transferrin. No C282Y variant was found in this Asian population. The H63D genotype modified the association between the lead and iron metabolism such that increased blood lead is associated with a higher body iron content or a lower transferrin in the H63D variant. It is indicated that H63D variant carriers may be a potentially highly vulnerable sub-population if they are exposed to high lead levels occupationally.

  5. Feasibility of biochar manufactured from organic wastes on the stabilization of heavy metals in a metal smelter contaminated soil.

    Science.gov (United States)

    Abdelhafez, Ahmed A; Li, Jianhua; Abbas, Mohamed H H

    2014-12-01

    The main objectives of the current study were to evaluate the potential effects of biochar derived from sugar cane bagasse (SC-BC) and orange peel (OP-BC) on improving the physicochemical properties of a metal smelter contaminated soil, and determining its potentiality for stabilizing Pb and As in soil. To achieve these goals, biochar was produced in a small-scale biochar producing plant, and an incubation experiment was conducted using a silt loam metal-contaminated soil treated with different application rates of biochar (0-10% w/w). The obtained results showed that, the addition of SC-BC and OP-BC increased significantly the soil aggregate stability, water-holding capacity, cation exchange capacity, organic matter and N-status in soil. SC-BC considerably decreased the solubility of Pb to values lower than the toxic regulatory level of the toxicity characteristics leaching procedure extraction (5 mg L(-1)). The rise in soil pH caused by biochar application, and the increase of soil organic matter transformed the labile Pb into less available fractions i.e. "Fe-Mn oxides" and "organic" bound fractions. On the other hand, As was desorbed from Fe-Mn oxides, which resulted in greater mobility of As in the treated soil. We concluded that SC-BC and OP-BC could be used successfully for remediating soils highly contaminated with Pb. However, considerable attention should be paid when using it in soil contaminated with As. Copyright © 2014 Elsevier Ltd. All rights reserved.

  6. SEASONAL IMPACT ANALYSIS ON POPULATION DUE TO CONTINUOUS SULPHUR EMISSIONS FROM SEVERONIKEL SMELTERS OF THE KOLA PENINSULA

    Directory of Open Access Journals (Sweden)

    Alexander Mahura

    2018-01-01

    Full Text Available This study is devoted to investigation of total deposition and loading patterns for population of the North-West Russia and Scandinavian countries due to continuous emissions (following “mild emission scenario” of sulphates from the Cu-Ni smelters (Severonikel enterprise, Murmansk region, Russia. The Lagrangian long-range dispersion model (Danish Emergency Response Model for Atmosphere was run in a long-term mode to simulate atmospheric transport, dispersion and deposition over the Northern Hemispheric’s domain north of 10°N, and results were integrated and analyzed in the GIS environment. Analysis was performed on annual and seasonal scales, including depositions, impact on urban areas and calculating individual and collective loadings on population in selected regions ofRussiaand Scandinavian countries.It was found that wet deposition dominates, and it is higher in winter. The North-West Russia is more influenced by the Severonikel emissions compared with the Scandinavian countries. Among urban areas, the Russian cities ofMurmansk(due to its proximity to the source andArkhangelsk(due to dominating atmospheric flows are under the highest impact. The yearly individual loadings on population are the largest (up to 120 kg/person for theMurmanskregion; lower (15 kg/person for territories of the northernNorway, and the smallest (less than 5 kg/person for the easternFinland,KareliaRepublic, andArkhangelskregion. These loadings have distinct seasonal variability with a largest contribution during winter-spring for Russia, spring – for Norway, and autumn – for Finland and Sweden; and the lowest during summer (i.e. less than 10 and 1 kg/person for the Russia and Scandinavian countries, respectively. The yearly collective loadings for population living on the impacted territories inRussia,Finland,Norway, and Swedenare 2628, 140.4, 13, and 10.7 tonnes, respectively.

  7. The Effect of Copper

    African Journals Online (AJOL)

    environment, where fishes are found, stuns them ... of earthen ponds are springing up near cocoa ... farm, which posses toxicological risk to farmed ... Veg. oil. 1.0. 1.0. 1.0. 1.0. 1.0. Copper sulphate 0. 1.0. 2.5. 5.0. 7.5. Total ..... Cellulase Production by Wild Strains of Aspergillus Niger, ... Mangrove Area of Lagos, Nigeria.

  8. Copper Pyrimidine based MOFs

    Indian Academy of Sciences (India)

    Synthesized hydrothermally in a 23-mL Teflon lined stainless steel bomb by heating copper(II) 2-pyrazinecarboxylate (31 mg, 0.1 mmol) and tin(II) iodide (75 mg, 0.2 mmol) in 4 mL water at 150±C for 24 h. The reaction vessel was subsequently cooled to 70±C at 1±C/min and held at that temperature for 6 h before returning ...

  9. Simulating STARDUST: Reproducing Impacts of Interstellar Dust in the Laboratory

    Science.gov (United States)

    Postberg, F.; Srama, R.; Hillier, J. K.; Sestak, S.; Green, S. F.; Trieloff, M.; Grün, E.

    2008-09-01

    Our experiments are carried out to support the analysis of interstellar dust grains, ISDGs, brought to earth by the STARDUST mission. Since the very first investigations, it has turned out that the major problem of STARDUST particle analysis is the modification (partly even the destruction) during capture when particles impact the spacecraft collectors with a velocity of up to 20 km/s. While it is possible to identify, extract, and analyse cometary grains larger than a few microns in aerogel and on metal collector plates, the STARDUST team is not yet ready for the identification, extraction, and analysis of sub-micron sized ISDGs with impact speeds of up to 20 km/s. Reconstructing the original particle properties requires a simulation of this impact capture process. Moreover, due to the lack of laboratory studies of high speed impacts of micron scale dust into interstellar STARDUST flight spares, the selection of criteria for the identification of track candidates is entirely subjective. Simulation of such impact processes is attempted with funds of the FRONTIER program within the framework of the Heidelberg University initiative of excellence. The dust accelerator at the MPI Kernphysik is a facility unique in the world to perform such experiments. A critical point is the production of cometary and interstellar dust analogue material and its acceleration to very high speeds of 20 km/s, which has never before been performed in laboratory experiments. Up to now only conductive material was successfully accelerated by the 2 MV Van de Graaf generator of the dust accelerator facility. Typical projectile materials are Iron, Aluminium, Carbon, Copper, Silver, and the conducting hydrocarbon Latex. Ongoing research now enables the acceleration of any kind of rocky planetary and interstellar dust analogues (Hillier et al. 2008, in prep.). The first batch of dust samples produced with the new method consists of micron and submicron SiO2 grains. Those were successfully

  10. Four Interstellar Dust Candidates from the Stardust Interstellar Dust Collector

    Science.gov (United States)

    Westphal, A. J.; Allen, C.; Bajt, S.; Bechtel, H. A.; Borg, J.; Brenker, F.; Bridges, J.; Brownlee, D. E.; Burchell, M.; Burghammer, M.; hide

    2011-01-01

    In January 2006, the Stardust sample return capsule returned to Earth bearing the first solid samples from a primitive solar system body, Comet 81P/Wild2, and a collector dedicated to the capture and return of contemporary interstellar dust. Both collectors were approx. 0.1 sq m in area and were composed of aerogel tiles (85% of the collecting area) and aluminum foils. The Stardust Interstellar Dust Collector (SIDC) was exposed to the interstellar dust stream for a total exposure factor of 20 sq m/day. The Stardust Interstellar Preliminary Examination (ISPE) is a consortium-based project to characterize the collection using nondestructive techniques. The goals and restrictions of the ISPE are described . A summary of analytical techniques is described.

  11. Supersonic copper clusters

    International Nuclear Information System (INIS)

    Powers, D.E.; Hansen, S.G.; Geusic, M.E.; Michalopoulos, D.L.; Smalley, R.E.

    1983-01-01

    Copper clusters ranging in size from 1 to 29 atoms have been prepared in a supersonic beam by laser vaporization of a rotating copper target rod within the throat of a pulsed supersonic nozzle using helium for the carrier gas. The clusters were cooled extensively in the supersonic expansion [T(translational) 1 to 4 K, T(rotational) = 4 K, T(vibrational) = 20 to 70 K]. These clusters were detected in the supersonic beam by laser photoionization with time-of-flight mass analysis. Using a number of fixed frequency outputs of an exciplex laser, the threshold behavior of the photoionization cross section was monitored as a function of cluster size.nce two-photon ionization (R2PI) with mass selective detection allowed the detection of five new electronic band systems in the region between 2690 and 3200 A, for each of the three naturally occurring isotopic forms of Cu 2 . In the process of scanning the R2PI spectrum of these new electronic states, the ionization potential of the copper dimer was determined to be 7.894 +- 0.015 eV

  12. Native copper as a natural analogue for copper canisters

    International Nuclear Information System (INIS)

    Marcos, N.

    1989-12-01

    This paper discusses the occurrence of native copper as found in geological formations as a stability analogue of copper canisters that are planned to be used for the disposal of spent nuclear fuel in the Finnish bedrock. A summary of several publications on native copper occurrences is presented. The present geochemical and geohydrological conditions in which copper is met with in its metallic state show that metallic copper is stable in a wide range of temperatures. At low temperatures native copper is found to be stable where groundwater has moderate pH (about 7), low Eh (< +100 mV), and low total dissolved solids, especially chloride. Microscopical and microanalytical studies were carried out on a dozen of rock samples containing native copper. The results reveal that the metal shows no significant alteration. Only the surface of copper grains is locally coated. In the oldest samples there exist small corrosion cracks; the age of the oldest samples is over 1,000 million years. A review of several Finnish groundwater studies suggests that there are places in Finland where the geohydrological conditions are favourable for native copper stability. (orig.)

  13. Cosmic dust investigations. Pt. 2

    International Nuclear Information System (INIS)

    Simpson, J.A.; Tuzzolino, A.J.

    1989-01-01

    A series of experiments have been completed using accelerator dust particles in the mass range ≅ 10 -9 -10 -6 g and velocity range ≅ 2-12 km/s to measure the velocity loss and degree of fragmentation for dust particles penetrating 6 and 28 μm thick polyvinylidene fluoride (PVDF) dust detectors. These measurements prove that even for a ratio of PVDF foil thickness to particle diameter as large as 0.6, the velocity loss and fragmentation is far less than expected from earlier reports in the literature. For 6 μm thick foils the velocity loss is ≤5%. These experiments are based on an extension of our earlier work which showed that two PVDF foils spaced a given distance apart could provide accurate time-of-flight (TOF) information due to the fast pulse rise time of PVDF detector response. We also report on our present state of development of PVDF position-sensing detectors which identify the x, y coordinates of particle impact, using detector and electronic pulse techniques adapted from our semiconductor position-sensing cosmic-ray detectors. Typical position errors of ≅ 1 mm are readily achieved. Finally, we have combined the above developments into a dust-particle telescope which accurately (≅ 1 0 angular accuracy) measures the trajectory of the incident particle as well as its mass and incident velocity, irrespective of whether it is a charged or neutral particle. We discuss how this practical dust telescope can be combined with dust capture cells for space flight and later recovery for laboratory determination of elemental and isotopic composition of captured dust. We also describe a simpler trajectory array based on discrete mosaics of thin detectors which would measure trajectories with a mean angular error of ≅ 4 0 . We discuss the application of these instruments for distinguishing between interplanetary dust of cometary and asteroidal origin, and for measurements on a space station, from near-Earth trapped dust of artificial origin. (orig.)

  14. Charged dust in saturn's magnetosphere

    International Nuclear Information System (INIS)

    Mendis, D.A.; Hill, J.R.; Houpis, H.L.F.

    1983-01-01

    Gravito-electrodynamic theory of charged dust grains is used to explain a variety of phenomena in those portions of the Saturnian ring system that are known to be dominated by fine (micron- and submicron-sized) dust, and in which collisional forces and Coulomb drag can be neglected. Among the phenomena discussed are the formation and evolution of the rotating near-radial spokes in the B-ring, the formation of waves in the F-ring, the cause of eccentricities of certain isolated ringlets, and the origin and morphology of the broad diffuse E-ring. Several novel processes predicted by the gravitoelectrodynamic theory, including 'magneto-gravitational capture' of exogenic dust by the magnetosphere, '1:1 magneto-gravitational orbital resonances' of charged dust with nearby satellites, and 'gyro-orbital resonances,' are used to explain individual observations. The effect of a ring current associated with this charged dust is also evaluated. Finally, the cosmogonic implications of the magneto-gravitational theory are briefly discussed. While several (although not all) of these processes have been discussed by one or more of the present authors elsewhere, the purpose of this paper is to synthesize all these processes within the framework of gravito-electrodynamics, and also to show its range of applicability within Saturn's ring system

  15. Spring Dust Storm Smothers Beijing

    Science.gov (United States)

    2002-01-01

    A few days earlier than usual, a large, dense plume of dust blew southward and eastward from the desert plains of Mongolia-quite smothering to the residents of Beijing. Citizens of northeastern China call this annual event the 'shachenbao,' or 'dust cloud tempest.' However, the tempest normally occurs during the spring time. The dust storm hit Beijing on Friday night, March 15, and began coating everything with a fine, pale brown layer of grit. The region is quite dry; a problem some believe has been exacerbated by decades of deforestation. According to Chinese government estimates, roughly 1 million tons of desert dust and sand blow into Beijing each year. This true-color image was made using two adjacent swaths (click to see the full image) of data from the Sea-viewing Wide Field-of-view Sensor (SeaWiFS), flying aboard the OrbView-2 satellite, on March 17, 2002. The massive dust storm (brownish pixels) can easily be distinguished from clouds (bright white pixels) as it blows across northern Japan and eastward toward the open Pacific Ocean. The black regions are gaps between SeaWiFS' viewing swaths and represent areas where no data were collected. Image courtesy the SeaWiFS Project, NASA/Goddard Space Flight Center, and ORBIMAGE

  16. Physical properties of five grain dust types.

    Science.gov (United States)

    Parnell, C B; Jones, D D; Rutherford, R D; Goforth, K J

    1986-01-01

    Physical properties of grain dust derived from five grain types (soybean, rice, corn, wheat, and sorghum) were measured and reported. The grain dusts were obtained from dust collection systems of terminal grain handling facilities and were assumed to be representative of grain dust generated during the handling process. The physical properties reported were as follows: particle size distributions and surface area measurements using a Coulter Counter Model TAII; percent dust fractions less than 100 micron of whole dust; bulk density; particle density; and ash content. PMID:3709482

  17. LIGNOCELLULOSE NANOCOMPOSITE CONTAINING COPPER SULFIDE

    OpenAIRE

    Sanchi Nenkova; Peter Velev; Mirela Dragnevska; Diyana Nikolova; Kiril Dimitrov

    2011-01-01

    Copper sulfide-containing lignocellulose nanocomposites with improved electroconductivity were obtained. Two methods for preparing the copper sulfide lignocellulose nanocomposites were developed. An optimization of the parameters for obtaining of the nanocomposites with respect to obtaining improved electroconductivity, economy, and lower quantities and concentration of copper and sulfur ions in waste waters was conducted. The mechanisms and schemes of delaying and subsequent connection of co...

  18. Copper tolerance in Becium homblei

    Energy Technology Data Exchange (ETDEWEB)

    Reilly, C; Stone, J

    1971-04-09

    Analyses show that Becium homblei has apparently no mechanism for limiting copper uptake. As growth proceeds, the concentration of metal increases in leaves and stems. Much of the copper is bound to structural material of the cells. There is a significant difference between the amount of extractable material in root and leaf tissues. These differences, in conjunction with the extrinsic factor of regular bush fires, were important factors in the evolution of this copper-resistant species of Becium. 9 references.

  19. Glass Frit Clumping And Dusting

    International Nuclear Information System (INIS)

    Steimke, J. L.

    2013-01-01

    DWPF mixes a slurry of glass frit (Frit 418) and dilute (1.5 wt%) formic acid solution with high level waste in the Slurry Mix Evaporator (SME). There would be advantages to introducing the frit in a non-slurry form to minimize water addition to the SME, however, adding completely dry frit has the potential to generate dust which could clog filters or condensers. Prior testing with another type of frit, Frit 320, and using a minimal amount of water reduced dust generation, however, the formation of hard clumps was observed. To examine options and behavior, a TTQAP [McCabe and Stone, 2013] was written to initiate tests that would address these concerns. Tests were conducted with four types of glass frit; Frit 320, DWPF Frit 418, Bekeson Frit 418 and Multi-Aspirator Frit 418. The last two frits are chemically identical to DWPF Frit 418 but smaller particles were removed by the respective vendors. Test results on Frit Clumping and Dusting are provided in this report. This report addresses the following seven questions. Short answers are provided below with more detailed answers to follow. 1. Will the addition of a small amount of water, 1.5 wt%, to dry DWPF Frit 418 greatly reduce the dust generation during handling at DWPF? a. Yes, a small scale test showed that adding a little water to the frit greatly reduced dust generation during handling. 2. Will the addition of small amounts of water to the frit cause clumping that will impair frit handling at DWPF? a. No, not with Frit 418. Although clumps were observed to form when 1.5 wt% water was mixed with DWPF Frit 418, then compressed and air-dried overnight, the clumps were easily crushed and did not form the hardened material noted when Frit 320 was tested. 3. What is the measured size distribution of dust generated when dry frit is handled? (This affects the feasibility and choice of processing equipment for removing the dust generating fraction of the frit before it is added to the SME.) a. The size distribution for

  20. Glass Frit Clumping And Dusting

    Energy Technology Data Exchange (ETDEWEB)

    Steimke, J. L.

    2013-09-26

    DWPF mixes a slurry of glass frit (Frit 418) and dilute (1.5 wt%) formic acid solution with high level waste in the Slurry Mix Evaporator (SME). There would be advantages to introducing the frit in a non-slurry form to minimize water addition to the SME, however, adding completely dry frit has the potential to generate dust which could clog filters or condensers. Prior testing with another type of frit, Frit 320, and using a minimal amount of water reduced dust generation, however, the formation of hard clumps was observed. To examine options and behavior, a TTQAP [McCabe and Stone, 2013] was written to initiate tests that would address these concerns. Tests were conducted with four types of glass frit; Frit 320, DWPF Frit 418, Bekeson Frit 418 and Multi-Aspirator Frit 418. The last two frits are chemically identical to DWPF Frit 418 but smaller particles were removed by the respective vendors. Test results on Frit Clumping and Dusting are provided in this report. This report addresses the following seven questions. Short answers are provided below with more detailed answers to follow. 1. Will the addition of a small amount of water, 1.5 wt%, to dry DWPF Frit 418 greatly reduce the dust generation during handling at DWPF? a. Yes, a small scale test showed that adding a little water to the frit greatly reduced dust generation during handling. 2. Will the addition of small amounts of water to the frit cause clumping that will impair frit handling at DWPF? a. No, not with Frit 418. Although clumps were observed to form when 1.5 wt% water was mixed with DWPF Frit 418, then compressed and air-dried overnight, the clumps were easily crushed and did not form the hardened material noted when Frit 320 was tested. 3. What is the measured size distribution of dust generated when dry frit is handled? (This affects the feasibility and choice of processing equipment for removing the dust generating fraction of the frit before it is added to the SME.) a. The size distribution for

  1. Dust Storm Hits Canary Islands

    Science.gov (United States)

    2002-01-01

    A thick pall of sand and dust blew out from the Sahara Desert over the Atlantic Ocean yesterday (January 6, 2002), engulfing the Canary Islands in what has become one of the worst sand storms ever recorded there. In this scene, notice how the dust appears particularly thick in the downwind wake of Tenerife, the largest of the Canary Islands. Perhaps the turbulence generated by the air currents flowing past the island's volcanic peaks is churning the dust back up into the atmosphere, rather than allowing it to settle toward the surface. This true-color image was captured by the Moderate-resolution Imaging Spectroradiometer (MODIS), flying aboard NASA's Terra satellite, on January 7, 2002. Image courtesy Jacques Descloitres, MODIS Land Rapid Response Team at NASA GSFC

  2. Mechanisms of metal dusting corrosion

    DEFF Research Database (Denmark)

    Hummelshøj, Thomas Strabo

    In this thesis the early stages of metal dusting corrosion is addressed; the development of carbon expanded austenite, C, and the decomposition hereof into carbides. Later stages of metal dusting corrosion are explored by a systematic study of stainless steel foils exposed to metal dusting...... deformed stainless steel flakes is transformed to expanded martensite/austenite during low-temperature carburization. Various experimental procedures to experimentally determine the concentration dependent diffusion coefficient of carbon in expanded austenite are evaluated. The most promising procedure...... powders and flakes. The nature of the decomposition products, carbides of the form M23C6 and M7C3, were evaluated by X-ray diffraction, light optical microscopy, scanning electron microscopy and thermodynamic modelling. The decomposition was found to be dependent on several parameters such as thermal...

  3. Copper toxicity in housed lambs

    Energy Technology Data Exchange (ETDEWEB)

    Adamson, A H; Valks, D A; Appleton, M A; Shaw, W B

    1969-09-27

    Copper toxicity among 170 lambs artificially reared indoors at High Mowthorpe NAAS Experimental Husbandry Farm is reported. Although only three lambs were lost it is not unreasonable to suggest that the liver copper levels of the lambs which were slaughtered would have been high and losses could have been much heavier had there been any further copper supplementation. Even a copper level of 20 ppm in lamb concentrates given to lambs reared artificially indoors is dangerous, and intakes of much less than 38 mg per lamb per day can be fatal if given of a prolonged period. 5 references, 1 table.

  4. Copper and copper-nickel-alloys - An overview

    Energy Technology Data Exchange (ETDEWEB)

    Klassert, Anton; Tikana, Ladji [Deutsches Kupferinstitut e.V. Am Bonneshof 5, 40474 Duesseldorf (Germany)

    2004-07-01

    With the increasing level of industrialization the demand for and the number of copper alloys rose in an uninterrupted way. Today, the copper alloys take an important position amongst metallic materials due to the large variety of their technological properties and applications. Nowadays there exist over 3.000 standardized alloys. Copper takes the third place of all metals with a worldwide consumption of over 15 millions tons per year, following only to steel and aluminum. In a modern industrial society we meet copper in all ranges of the life (electro-technology, building and construction industry, mechanical engineering, automotive, chemistry, offshore, marine engineering, medical applications and others.). Copper is the first metal customized by humanity. Its name is attributed to the island Cyprus, which supplied in the antiquity copper to Greece, Rome and the other Mediterranean countries. The Romans called it 'ore from Cyprus' (aes cyprium), later cuprum. Copper deposited occasionally also dapper and could be processed in the recent stone age simply by hammering. Already in early historical time copper alloys with 20 to 50 percent tin was used for the production of mirrors because of their high reflecting power. Although the elementary nickel is an element discovered only recently from a historical perspective, its application in alloys - without any knowledge of the alloy composition - occurred at least throughout the last 2.000 years. The oldest copper-nickel coin originates from the time around 235 B.C.. Only around 1800 AD nickel was isolated as a metallic element. In particular in the sea and offshore technology copper nickel alloys found a broad field of applications in piping systems and for valves and armatures. The excellent combination of characteristics like corrosion resistance, erosion stability and bio-fouling resistance with excellent mechanical strength are at the basis of this success. An experience of many decades supports the use

  5. Intergalactic dust and quasar distribution

    International Nuclear Information System (INIS)

    Soltan, A.

    1979-01-01

    Non-homogeneous intergalactic extinction may considerably affect the quasar distribution. Especially samples of quasars isolated on the basis of B-V colours are subject to this phenomenon. Apparent grouping and close pairs of quasars reported in the literature may be a result of intergalactic dust. Using surface distribution of faint blue objects selected by Hawkins and Reddish it is estimated that intergalactic extinction in B should reach approximately 1 mag out to the redshift of approximately 1. This is slightly larger than predicted by theory and comparable to the mean dust density derived from observations. (Author)

  6. The distribution of interstellar dust

    International Nuclear Information System (INIS)

    Clocchiatti, A.; Marraco, H.G.

    1986-01-01

    We propose the interstellar matter structural function as a tool to derive the features of the interstellar dust distribution. We study that function resolving some ideal dust distribution models. Later we describe the method used to find a reliable computing algorithm for the observational case. Finally, we describe the steps to build a model for the interstellar matter composed by spherically symmetrical clouds. The density distribution for each of these clouds is D(r) = D 0 .esup(-r/r 0 ) 2 . The preliminary results obtained are summarised. (author)

  7. Electrostatic Dust Detector with Improved Sensitivity

    International Nuclear Information System (INIS)

    Boyle, D.P.; Skinner, C.H.; Roquemore, A.L.

    2008-01-01

    Methods to measure the inventory of dust particles and to remove dust if it approaches safety limits will be required in next-step tokamaks such as ITER. An electrostatic dust detector, based on a fine grid of interlocking circuit traces, biased to 30 or 50 V, has been developed for the detection of dust on remote surfaces in air and vacuum environments. Gaining operational experience of dust detection on surfaces in tokamaks is important, however the level of dust generated in contemporary short-pulse tokamaks is comparatively low and high sensitivity is necessary to measure dust on a shot-by-shot basis. We report on modifications in the detection electronics that have increased the sensitivity of the electrostatic dust detector by a factor of up to 120, - a level suitable for measurements on contemporary tokamaks.

  8. Infrared Observations of Cometary Dust and Nuclei

    Science.gov (United States)

    Lisse, Carey

    2004-01-01

    This bibliography lists citations for publications published under the grant. Subjects of the publications include cometary dust, instellar and interplanetary dust, comet nuclei and comae, Comet Hale-Bopp, infrared observations of comets, mass loss, and comet break-up.

  9. The global distribution of mineral dust

    International Nuclear Information System (INIS)

    Tegen, I; Schepanski, K

    2009-01-01

    Dust aerosol particles produced by wind erosion in arid and semi arid regions affect climate and air quality, but the magnitude of these effects is largely unquantified. The major dust source regions include the Sahara, the Arabian and Asian deserts; global annual dust emissions are currently estimated to range between 1000 and 3000 Mt/yr. Dust aerosol can be transported over long distances of thousands of kilometers, e.g. from source regions in the Saharan desert over the North Atlantic, or from the Asian deserts towards the Pacific Ocean. The atmospheric dust load varies considerably on different timescales. While dust aerosol distribution and dust effects are important on global scales, they strongly depend on dust emissions that are controlled on small spatial and temporal scales.

  10. Spectrographic determination of impurities in copper and copper oxide

    International Nuclear Information System (INIS)

    Sabato, S.F.; Lordello, A.R.

    1990-11-01

    An emission spectrographic method for the determination of Al, Bi, Ca, Cd, Cr, Fe, Ge, Mg, Mn, Mo, Ni, Pb, Sb, Si, Sn and Zn in copper and copper oxide is described. Two mixtures (Graphite and ZnO: graphite and GeO sub(2)) were used as buffers. The standard deviation lies around 10%. (author)

  11. Nickel, copper and cobalt coalescence in copper cliff converter slag

    Directory of Open Access Journals (Sweden)

    Wolf A.

    2016-01-01

    Full Text Available The aim of this investigation is to assess the effect of various additives on coalescence of nickel, copper and cobalt from slags generated during nickel extraction. The analyzed fluxes were silica and lime while examined reductants were pig iron, ferrosilicon and copper-silicon compound. Slag was settled at the different holding temperatures for various times in conditions that simulated the industrial environment. The newly formed matte and slag were characterized by their chemical composition and morphology. Silica flux generated higher partition coefficients for nickel and copper than the addition of lime. Additives used as reducing agents had higher valuable metal recovery rates and corresponding partition coefficients than fluxes. Microstructural studies showed that slag formed after adding reductants consisted of primarily fayalite, with some minute traces of magnetite as the secondary phase. Addition of 5 wt% of pig iron, ferrosilicon and copper-silicon alloys favored the formation of a metallized matte which increased Cu, Ni and Co recoveries. Addition of copper-silicon alloys with low silicon content was efficient in copper recovery but coalescence of the other metals was low. Slag treated with the ferrosilicon facilitated the highest cobalt recovery while copper-silicon alloys with silicon content above 10 wt% resulted in high coalescence of nickel and copper, 87 % and 72 % respectively.

  12. Experimental investigation of flow induced dust acoustic shock waves in a complex plasma

    Energy Technology Data Exchange (ETDEWEB)

    Jaiswal, S., E-mail: surabhijaiswal73@gmail.com; Bandyopadhyay, P.; Sen, A. [Institute for Plasma Research, Bhat, Gandhinagar, Gujarat 382428 (India)

    2016-08-15

    We report on experimental observations of flow induced large amplitude dust-acoustic shock waves in a complex plasma. The experiments have been carried out in a Π shaped direct current glow discharge experimental device using kaolin particles as the dust component in a background of Argon plasma. A strong supersonic flow of the dust fluid is induced by adjusting the pumping speed and neutral gas flow into the device. An isolated copper wire mounted on the cathode acts as a potential barrier to the flow of dust particles. A sudden change in the gas flow rate is used to trigger the onset of high velocity dust acoustic shocks whose dynamics are captured by fast video pictures of the evolving structures. The physical characteristics of these shocks are delineated through a parametric scan of their dynamical properties over a range of flow speeds and potential hill heights. The observed evolution of the shock waves and their propagation characteristics are found to compare well with model numerical results based on a modified Korteweg-de-Vries-Burgers type equation.

  13. Exact solutions for rotating charged dust

    International Nuclear Information System (INIS)

    Islam, J.N.

    1984-01-01

    Earlier work by the author on rotating charged dust is summarized. An incomplete class of exact solutions for differentially rotating charged dust in Newton-Maxwell theory for the equal mass and charge case that was found earlier is completed. A new global exact solution for cylindrically symmetric differentially rotating charged dust in Newton-Maxwell theory is presented. Lastly, a new exact solution for cylindrically symmetric rigidly rotating charged dust in general relativity is given. (author)

  14. Studies of dust shells around stars

    International Nuclear Information System (INIS)

    Bedijn, P.J.

    1977-01-01

    This thesis deals with some aspects of circumstellar dust shells. This dust shell, emitting infrared radiation, is described by way of its absorptive and emissive properties as well as by the transfer of radiation through the dust shell itself. Model calculations are compared to experimental results and agree reasonably well. The author also discusses the dynamics of the extended shells of gas and dust around newly formed stars

  15. Radio frequency discharge with dust particles

    NARCIS (Netherlands)

    Chutov, Y. I.; W. J. Goedheer,; Kravchenko, O. Y.; Zuz, V. M.; Yan, M.; Martins, R.; Ferreira, I.; Fortunato, E.; Kroesen, G.

    2000-01-01

    A 1D PIC/MCC method has been developed for computer simulations of low-pressure RF discharges with dust particles using the method for dust-free discharges. A RF discharge in argon with dust particles distributed uniformly in the interelectrode gap is simulated at parameters providing a possibility

  16. Thirteen years of Aeolian dust dynamics in a desert region (Negev desert, Israel): analysis of horizontal and vertical dust flux, vertical dust distribution and dust grain size

    NARCIS (Netherlands)

    Offer, Z.Y.; Goossens, D.

    2004-01-01

    At Sede Boqer (northern Negev desert, Israel), aeolian dust dynamics have been measured during the period 1988–2000. This study focuses on temporal records of the vertical and horizontal dust flux, the vertical distribution of the dust particles in the atmosphere, and the grain size of the

  17. Dust Measurements Onboard the Deep Space Gateway

    Science.gov (United States)

    Horanyi, M.; Kempf, S.; Malaspina, D.; Poppe, A.; Srama, R.; Sternovsky, Z.; Szalay, J.

    2018-02-01

    A dust instrument onboard the Deep Space Gateway will revolutionize our understanding of the dust environment at 1 AU, help our understanding of the evolution of the solar system, and improve dust hazard models for the safety of crewed and robotic missions.

  18. Properties of interstellar dust in reflection nebulae

    International Nuclear Information System (INIS)

    Sellgren, K.

    1988-01-01

    Observations of interstellar dust in reflection nebulae are the closest analog in the interstellar medium to studies of cometary dust in our solar system. The presence of a bright star near the reflection nebula dust provides the opportunity to study both the reflection and emission characteristics of interstellar dust. At 0.1 to 1 micrometer, the reflection nebula emission is due to starlight scattered by dust. The albedo and scattering phase function of the dust is determined from observations of the scattered light. At 50 to 200 micrometers, thermal emission from the dust in equilibrium with the stellar radiation field is observed. The derived dust temperature determines the relative values of the absorption coefficient of the dust at wavelengths where the stellar energy is absorbed and at far infrared wavelengths where the absorbed energy is reradiated. These emission mechanisms directly relate to those seen in the near and mid infrared spectra of comets. In a reflection nebula the dust is observed at much larger distances from the star than in our solar system, so that the equilibrium dust temperature is 50 K rather than 300 K. Thus, in reflection nebulae, thermal emission from dust is emitted at 50 to 200 micrometer

  19. House dust extracts contain potent immunological adjuvants

    NARCIS (Netherlands)

    Beukelman, C.J.; Dijk, H. van; Aerts, P.C.; Rademaker, P.M.; Berrens, L.; Willers, J.M.N.

    1987-01-01

    A crude aqueous extract of house dust and two house dust subfractions were tested for adjuvant activity in a sensitivity assay performed in mice. Evidence is presented that house dust contains at least two potent immunological adjuvants. One of these, present in both subfractions, was probably

  20. Removal of arsenic from Janghang smelter site and energy crops-grown soil with soil washing using magnetic iron oxide

    Science.gov (United States)

    Han, Jaemaro; Zhao, Xin; Lee, Jong Keun; Kim, Jae Young

    2014-05-01

    Arsenic compounds are considered carcinogen and easily enter drinking water supplies with their natural abundance. US Environmental Protection Agency is finalizing a regulation to reduce the public health risks from arsenic in drinking water by revising the current drinking water standard for arsenic from 50 ppb to 10 ppb in 2001 (USEPA, 2001). Therefore, soil remediation is also growing field to prevent contamination of groundwater as well as crop cultivation. Soil washing is adjusted as ex-situ soil remediation technique which reduces volume of the contaminated soil. The technique is composed of physical separation and chemical extraction to extract target metal contamination in the soil. Chemical extraction methods have been developed solubilizing contaminants containing reagents such as acids or chelating agents. And acid extraction is proven as the most commonly used technology to treat heavy metals in soil, sediment, and sludge (FRTR, 2007). Due to the unique physical and chemical properties, magnetic iron oxide have been used in diverse areas including information technology and biomedicine. Magnetic iron oxides also can be used as adsorbent to heavy metal enhancing removal efficiency of arsenic concentration. In this study, magnetite is used as the washing agent with acid extraction condition so that the injected oxide can be separated by magnetic field. Soil samples were collected from three separate areas in the Janghang smelter site and energy crops-grown soil to have synergy effect with phytoremediation. Each sample was air-dried and sieved (2mm). Soil washing condition was adjusted on pH in the range of 0-12 with hydrogen chloride and sodium hydroxide. After performing soil washing procedure, arsenic-extracted samples were analyzed for arsenic concentration by inductively coupled plasma optical emission spectrometer (ICP-OES). All the soils have exceeded worrisome level of soil contamination for region 1 (25mg/kg) so the soil remediation techniques are

  1. Observed spectral features of dust

    International Nuclear Information System (INIS)

    Willner, S.P.

    1984-01-01

    The author concentrates on the observed properties of dust spectral features. Identifications, based on laboratory data, are given whenever plausible ones exist. There are a very large number of papers in the literature of even such a young field as infrared spectroscopy, and therefore the author refers only to the most recent paper on a topic or to another review. (Auth.)

  2. Meteors, meteorites and cosmic dust

    International Nuclear Information System (INIS)

    Lebedinets, V.N.

    1987-01-01

    The problem of meteorite origin and meteorite composition is discussed. Nowadays, most scientists suppose that the giant Oort cloud consisting of ice comet nuclei is the sourse of the meteor matter. A principle unity of the matter of meteorites falling to the Earth and cosmic dust is noted as well as that of meteorite bodies evaporating in the atmosphere and bearing meteors and bodies

  3. Occupational diseases of dust etiology

    International Nuclear Information System (INIS)

    Sokolik, L.I.; Shkondin, A.N.

    1981-01-01

    Detailed etiologic and clinico-roentgenological characteristics of pneumoconiosis, as widely spread occupational disease caused by different kinds of dust, are given. The course of pneumoconiosis is discussed depending on working conditions of patients after the disease had been ascertained, as well as its complications, taking into account roentgeno-morphological types of fibrosis and the stages of the disease [ru

  4. 75 FR 32142 - Combustible Dust

    Science.gov (United States)

    2010-06-07

    .... Contact Mat Chibbaro, P.E., Fire Protection Engineer, Office of Safety Systems, OSHA Directorate of..., and metals (such as aluminum and magnesium). Industries that may have combustible dust hazards include..., chemical manufacturing, textile manufacturing, furniture manufacturing, metal processing, fabricated metal...

  5. Trapping Dust to Form Planets

    Science.gov (United States)

    Kohler, Susanna

    2017-10-01

    Growing a planet from a dust grain is hard work! A new study explores how vortices in protoplanetary disks can assist this process.When Dust Growth FailsTop: ALMA image of the protoplanetary disk of V1247 Orionis, with different emission components labeled. Bottom: Synthetic image constructed from the best-fit model. [Kraus et al. 2017]Gradual accretion onto a seed particle seems like a reasonable way to grow a planet from a grain of dust; after all, planetary embryos orbit within dusty protoplanetary disks, which provides them with plenty of fuel to accrete so they can grow. Theres a challenge to this picture, though: the radial drift problem.The radial drift problem acknowledges that, as growing dust grains orbit within the disk, the drag force on them continues to grow as well. For large enough dust grains perhaps around 1 millimeter the drag force will cause the grains orbits to decay, and the particles drift into the star before they are able to grow into planetesimals and planets.A Close-Up Look with ALMASo how do we overcome the radial drift problem in order to form planets? A commonly proposed mechanism is dust trapping, in which long-lived vortices in the disk trap the dust particles, preventing them from falling inwards. This allows the particles to persist for millions of years long enough to grow beyond the radial drift barrier.Observationally, these dust-trapping vortices should have signatures: we would expect to see, at millimeter wavelengths, specific bright, asymmetric structures where the trapping occurs in protoplanetary disks. Such disk structures have been difficult to spot with past instrumentation, but the Atacama Large Millimeter/submillimeter Array (ALMA) has made some new observations of the disk V1247 Orionis that might be just what were looking for.Schematic of the authors model for the disk of V1247 Orionis. [Kraus et al. 2017]Trapped in a Vortex?ALMAs observations of V1247 Orionis are reported by a team of scientists led by Stefan

  6. Cosmological simulation with dust formation and destruction

    Science.gov (United States)

    Aoyama, Shohei; Hou, Kuan-Chou; Hirashita, Hiroyuki; Nagamine, Kentaro; Shimizu, Ikkoh

    2018-06-01

    To investigate the evolution of dust in a cosmological volume, we perform hydrodynamic simulations, in which the enrichment of metals and dust is treated self-consistently with star formation and stellar feedback. We consider dust evolution driven by dust production in stellar ejecta, dust destruction by sputtering, grain growth by accretion and coagulation, and grain disruption by shattering, and treat small and large grains separately to trace the grain size distribution. After confirming that our model nicely reproduces the observed relation between dust-to-gas ratio and metallicity for nearby galaxies, we concentrate on the dust abundance over the cosmological volume in this paper. The comoving dust mass density has a peak at redshift z ˜ 1-2, coincident with the observationally suggested dustiest epoch in the Universe. In the local Universe, roughly 10 per cent of the dust is contained in the intergalactic medium (IGM), where only 1/3-1/4 of the dust survives against dust destruction by sputtering. We also show that the dust mass function is roughly reproduced at ≲ 108 M⊙, while the massive end still has a discrepancy, which indicates the necessity of stronger feedback in massive galaxies. In addition, our model broadly reproduces the observed radial profile of dust surface density in the circum-galactic medium (CGM). While our model satisfies the observational constraints for the dust extinction on cosmological scales, it predicts that the dust in the CGM and IGM is dominated by large (>0.03 μm) grains, which is in tension with the steep reddening curves observed in the CGM.

  7. Respiratory Toxicity of Lunar Highland Dust

    Science.gov (United States)

    James, John T.; Lam, Chiu-wing; Wallace, William T.

    2009-01-01

    Lunar dust exposures occurred during the Apollo missions while the crew was on the lunar surface and especially when microgravity conditions were attained during rendezvous in lunar orbit. Crews reported that the dust was irritating to the eyes and in some cases respiratory symptoms were elicited. NASA s vision for lunar exploration includes stays of 6 months on the lunar surface hence the health effects of periodic exposure to lunar dust need to be assessed. NASA has performed this assessment with a series of in vitro and in vivo tests on authentic lunar dust. Our approach is to "calibrate" the intrinsic toxicity of lunar dust by comparison to a nontoxic dust (TiO2) and a highly toxic dust (quartz) using intratrachael instillation of the dusts in mice. A battery of indices of toxicity is assessed at various time points after the instillations. Cultures of selected cells are exposed to test dusts to assess the adverse effects on the cells. Finally, chemical systems are used to assess the nature of the reactivity of various dusts and to determine the persistence of reactivity under various environmental conditions that are relevant to a space habitat. Similar systems are used to assess the dissolution of the dust. From these studies we will be able to set a defensible inhalation exposure standard for aged dust and predict whether we need a separate standard for reactive dust. Presently-available data suggest that aged lunar highland dust is slightly toxic, that it can adversely affect cultured cells, and that the surface reactivity induced by grinding the dust persists for a few hours after activation.

  8. Design and development of a dust dispersion chamber to quantify the dispersibility of rock dust.

    Science.gov (United States)

    Perera, Inoka E; Sapko, Michael J; Harris, Marcia L; Zlochower, Isaac A; Weiss, Eric S

    2016-01-01

    Dispersible rock dust must be applied to the surfaces of entries in underground coal mines in order to inert the coal dust entrained or made airborne during an explosion and prevent propagating explosions. 30 CFR. 75.2 states that "… [rock dust particles] when wetted and dried will not cohere to form a cake which will not be dispersed into separate particles by a light blast of air …" However, a proper definition or quantification of "light blast of air" is not provided. The National Institute for Occupational Safety and Health (NIOSH) has, consequently, designed a dust dispersion chamber to conduct quantitative laboratory-scale dispersibility experiments as a screening tool for candidate rock dusts. A reproducible pulse of air is injected into the chamber and across a shallow tray of rock dust. The dust dispersed and carried downwind is monitored. The mass loss of the dust tray and the airborne dust measurements determine the relative dispersibility of the dust with respect to a Reference rock dust. This report describes the design and the methodology to evaluate the relative dispersibility of rock dusts with and without anti-caking agents. Further, the results of this study indicate that the dispersibility of rock dusts varies with particle size, type of anti-caking agent used, and with the untapped bulk density. Untreated rock dusts, when wetted and dried forming a cake that was much less dispersible than the reference rock dust used in supporting the 80% total incombustible content rule.

  9. Copper: From neurotransmission to neuroproteostasis

    Directory of Open Access Journals (Sweden)

    Carlos M Opazo

    2014-07-01

    Full Text Available Copper is critical for the Central Nervous System (CNS development and function. In particular, different studies have shown the effect of copper at brain synapses, where it inhibits Long Term Potentation (LTP and receptor pharmacology. Paradoxically, according to recent studies copper is required for a normal LTP response. Copper is released at the synaptic cleft, where it blocks glutamate receptors, which explain its blocking effects on excitatory neurotransmission. Our results indicate that copper also enhances neurotransmission through the accumulation of PSD95 protein, which increase the levels of AMPA receptors located at the plasma membrane of the post-synaptic density. Thus, our findings represent a novel mechanism for the action of copper, which may have implications for the neurophysiology and neuropathology of the CNS. These data indicate that synaptic configuration is sensitive to transient changes in transition metal homeostasis. Our results suggest that copper increases GluA1 subunit levels of the AMPA receptor through the anchorage of AMPA receptors to the plasma membrane as a result of PSD-95 accumulation. Here, we will review the role of copper on neurotransmission of CNS neurons. In addition, we will discuss the potential mechanisms by which copper could modulate neuronal proteostasis (neuroproteostasis in the CNS with focus in the Ubiquitin Proteasome System, which is particularly relevant to neurological disorders such Alzheimer’s disease (AD where copper and protein dyshomeostasis may contribute to neurodegeneration. An understanding of these mechanisms may ultimately lead to the development of novel therapeutic approaches to control metal and synaptic alterations observed in AD patients.

  10. Step by step in dust control

    Energy Technology Data Exchange (ETDEWEB)

    Archer, N. [Arch Environmental Equipment, Inc. (United States)

    2003-05-01

    The paper examines the different stages in identifying delegating and controlling dust before it becomes a serious problem for a facility. Material handling, processing, storage and traffic are the major dust producing sources. All industries that convey dry, light material need to install a dust control system. The confine-seal-suppress method of dust control has provided excellent results in numerous applications, only with the combination of all three will maximum dust control. When a system is properly engineered and correctly installed, meeting the EPA Government standards becomes very easy, and is necessary in to the operation of a quality facility. 5 photos.

  11. Dust bands in the asteroid belt

    International Nuclear Information System (INIS)

    Sykes, M.V.; Greenberg, R.; Dermott, S.F.; Nicholson, P.D.; Burns, J.A.

    1989-01-01

    This paper describes the original IRAS observations leading to the discovery of the three dust bands in the asteroid belt and the analysis of data. Special attention is given to an analytical model of the dust band torus and to theories concerning the origin of the dust bands, with special attention given to the collisional equilibrium (asteroid family), the nonequilibrium (random collision), and the comet hypotheses of dust-band origin. It is noted that neither the equilibrium nor nonequilibrium models, as currently formulated, present a complete picture of the IRAS dust-band observations. 32 refs

  12. Linear Alkylbenzenesulfonates in indoor Floor Dust

    DEFF Research Database (Denmark)

    Madsen, Jørgen Øgaard; Wolkoff, Peder; Madsen, Jørgen Øgaard

    1999-01-01

    The amount of Linear Alkylbenzenesulfonates (LAS) in the particle fraction of floor dust sampled from 7 selected public buildings varied between 34 and 1500 microgram per gram dust, while the contents of the fibre fractions generally were higher with up to 3500 microgram LAS/g dust. The use...... of a cleaning agent with LAS resulted in an increase of the amount of LAS in the floor dust after floor wash relative to just before floor wash. However, the most important source of LAS in the indoor floor dust appears to be residues of detergent in clothing. Thus, a newly washed shirt contained 2960 microgram...

  13. Time-Dependent Dust Formation in Novae

    Directory of Open Access Journals (Sweden)

    Kyung-Won Suh

    1991-06-01

    Full Text Available The dust formation processes in novae are investigated with close attention to recent infrared observations. Using mainly the classical nucleation theory, we have calculated the time scales of dust formation and growth in the environments of novae. Those time scales roughly resemble the typical observations. We have classified the dust-forming novae into three classes according to their explosion properties and the thermodynamic properties of dust grains. Oxygen grains from much later than carbon grains because of their thermodynamic properties. The effect of grain formation to the efficiency of stellar winds to drive the material outward is tested with newly obtained Planck mean values of dust grains.

  14. Numerical Prediction of Dust. Chapter 10

    Science.gov (United States)

    Benedetti, Angela; Baldasano, J. M.; Basart, S.; Benincasa, F.; Boucher, O.; Brooks, M.; Chen, J. P.; Colarco, P. R.; Gong, S.; Huneeus, N.; hide

    2013-01-01

    Covers the whole breadth of mineral dust research, from a scientific perspective Presents interdisciplinary work including results from field campaigns, satellite observations, laboratory studies, computer modelling and theoretical studies Explores the role of dust as a player and recorder of environmental change This volume presents state-of-the-art research about mineral dust, including results from field campaigns, satellite observations, laboratory studies, computer modelling and theoretical studies. Dust research is a new, dynamic and fast-growing area of science and due to its multiple roles in the Earth system, dust has become a fascinating topic for many scientific disciplines. Aspects of dust research covered in this book reach from timescales of minutes (as with dust devils, cloud processes, and radiation) to millennia (as with loess formation and oceanic sediments), making dust both a player and recorder of environmental change. The book is structured in four main parts that explore characteristics of dust, the global dust cycle, impacts of dust on the Earth system, and dust as a climate indicator. The chapters in these parts provide a comprehensive, detailed overview of this highly interdisciplinary subject. The contributions presented here cover dust from source to sink and describe all the processes dust particles undergo while travelling through the atmosphere. Chapters explore how dust is lifted and transported, how it affects radiation, clouds, regional circulations, precipitation and chemical processes in the atmosphere, and how it deteriorates air quality. The book explores how dust is removed from the atmosphere by gravitational settling, turbulence or precipitation, how iron contained in dust fertilizes terrestrial and marine ecosystems, and about the role that dust plays in human health. We learn how dust is observed, simulated using computer models and forecast. The book also details the role of dust deposits for climate reconstructions

  15. Dust removal system for fusion experimental reactors

    International Nuclear Information System (INIS)

    Onozuka, M.; Ueda, Y.; Takahashi, K.; Oda, Y.; Seki, Y.; Ueda, S.; Aoki, I.

    1995-01-01

    Development of a dust removal system using static electricity has been conducted. It is envisioned that the system can collect and transport dust under vacuum. In the system, the dust is charged by dielectric polarization and floated by an electrostatic attraction force that is generated by the DC electric field. The dust is then transported by the electric curtain formed by the three-phase AC electric field. Experimental investigation has been conducted to examine the characteristics of the system. Current research results indicate that the dust removal system using static electricity can be used for fusion experimental reactors

  16. Dust removal system for fusion experimental reactors

    Energy Technology Data Exchange (ETDEWEB)

    Onozuka, M.; Ueda, Y.; Takahashi, K.; Oda, Y. [Mitsubishi Heavy Industries, Ltd., Yokohama (Japan); Seki, Y.; Ueda, S.; Aoki, I. [Japan Atomic Energy Research Inst., Naka, Ibaraki (Japan)

    1995-12-31

    Development of a dust removal system using static electricity has been conducted. It is envisioned that the system can collect and transport dust under vacuum. In the system, the dust is charged by dielectric polarization and floated by an electrostatic attraction force that is generated by the DC electric field. The dust is then transported by the electric curtain formed by the three-phase AC electric field. Experimental investigation has been conducted to examine the characteristics of the system. Current research results indicate that the dust removal system using static electricity can be used for fusion experimental reactors.

  17. Advanced Copper Composites Against Copper-Tolerant Xanthomonas perforans and Tomato Bacterial Spot.

    Science.gov (United States)

    Strayer-Scherer, A; Liao, Y Y; Young, M; Ritchie, L; Vallad, G E; Santra, S; Freeman, J H; Clark, D; Jones, J B; Paret, M L

    2018-02-01

    Bacterial spot, caused by Xanthomonas spp., is a widespread and damaging bacterial disease of tomato (Solanum lycopersicum). For disease management, growers rely on copper bactericides, which are often ineffective due to the presence of copper-tolerant Xanthomonas strains. This study evaluated the antibacterial activity of the new copper composites core-shell copper (CS-Cu), multivalent copper (MV-Cu), and fixed quaternary ammonium copper (FQ-Cu) as potential alternatives to commercially available micron-sized copper bactericides for controlling copper-tolerant Xanthomonas perforans. In vitro, metallic copper from CS-Cu and FQ-Cu at 100 μg/ml killed the copper-tolerant X. perforans strain within 1 h of exposure. In contrast, none of the micron-sized copper rates (100 to 1,000 μg/ml) from Kocide 3000 significantly reduced copper-tolerant X. perforans populations after 48 h of exposure compared with the water control (P copper-based treatments killed the copper-sensitive X. perforans strain within 1 h. Greenhouse studies demonstrated that all copper composites significantly reduced bacterial spot disease severity when compared with copper-mancozeb and water controls (P copper composites significantly reduced disease severity when compared with water controls, using 80% less metallic copper in comparison with copper-mancozeb in field studies (P copper composites have the potential to manage copper-tolerant X. perforans and tomato bacterial spot.

  18. Air pollution assessment based on elemental concentration of leaves tissue and foliage dust along an urbanization gradient in Vienna

    International Nuclear Information System (INIS)

    Simon, Edina; Braun, Mihaly; Vidic, Andreas; Bogyo, David; Fabian, Istvan; Tothmeresz, Bela

    2011-01-01

    Foliage dust contains heavy metal that may have harmful effects on human health. The elemental contents of tree leaves and foliage dust are especially useful to assess air environmental pollution. We studied the elemental concentrations in foliage dust and leaves of Acer pseudoplatanus along an urbanization gradient in Vienna, Austria. Samples were collected from urban, suburban and rural areas. We analysed 19 elements in both kind of samples: aluminium, barium, calcium, copper, iron, potassium, magnesium, sodium, phosphor, sulphur, strontium and zinc. We found that the elemental concentrations of foliage dust were significantly higher in the urban area than in the rural area for aluminium, barium, iron, lead, phosphor and selenium. Elemental concentrations of leaves were significantly higher in urban than in rural area for manganese and strontium. Urbanization changed significantly the elemental concentrations of foliage dust and leaves and the applied method can be useful for monitoring the environmental load. - Highlights: → We studied the elements in dust and leaves along an urbanization gradient, Austria. → We analysed 19 elements: Al, Ba, Ca, Cd, Cu, Fe, K, Mg, Na, P, Pb, S, Sr and Zn. → Elemental concentrations were higher in urban area than in the rural area. → Studied areas were separated by CDA based on the elemental concentrations. → Dust and leaves can be useful for monitoring the environmental load. - Studying the elements (Al, Ba, Ca, Cu, Fe, K, Mg, Na, P, S, Sr, Zn) in dust and leaves along an urbanization gradient in Wien, Austria we found that the elemental concentrations of foliage dust were significantly higher in the urban area than in the rural area for Al, Ba, Fe, Pb, P and Se, and concentrations of leaves were significantly higher in urban than in rural area for Mn and Sr.

  19. Air pollution assessment based on elemental concentration of leaves tissue and foliage dust along an urbanization gradient in Vienna

    Energy Technology Data Exchange (ETDEWEB)

    Simon, Edina, E-mail: edina.simon@gmail.com [Department of Ecology, University of Debrecen, H-4010 Debrecen, P.O. Box 71 (Hungary); Braun, Mihaly [Department of Inorganic and Analytical Chemistry, University of Debrecen, H-4010 Debrecen, P.O. Box 21 (Hungary); Vidic, Andreas [Department fuer Naturschutzbiologie, Vegetations- und Landschaftsoekologie, Universitat Wien, Althanstrasse 14, 1090 Wien (Austria); Bogyo, David [Department of Ecology, University of Debrecen, H-4010 Debrecen, P.O. Box 71 (Hungary); Fabian, Istvan [Department of Inorganic and Analytical Chemistry, University of Debrecen, H-4010 Debrecen, P.O. Box 21 (Hungary); Tothmeresz, Bela [Department of Ecology, University of Debrecen, H-4010 Debrecen, P.O. Box 71 (Hungary)

    2011-05-15

    Foliage dust contains heavy metal that may have harmful effects on human health. The elemental contents of tree leaves and foliage dust are especially useful to assess air environmental pollution. We studied the elemental concentrations in foliage dust and leaves of Acer pseudoplatanus along an urbanization gradient in Vienna, Austria. Samples were collected from urban, suburban and rural areas. We analysed 19 elements in both kind of samples: aluminium, barium, calcium, copper, iron, potassium, magnesium, sodium, phosphor, sulphur, strontium and zinc. We found that the elemental concentrations of foliage dust were significantly higher in the urban area than in the rural area for aluminium, barium, iron, lead, phosphor and selenium. Elemental concentrations of leaves were significantly higher in urban than in rural area for manganese and strontium. Urbanization changed significantly the elemental concentrations of foliage dust and leaves and the applied method can be useful for monitoring the environmental load. - Highlights: > We studied the elements in dust and leaves along an urbanization gradient, Austria. > We analysed 19 elements: Al, Ba, Ca, Cd, Cu, Fe, K, Mg, Na, P, Pb, S, Sr and Zn. > Elemental concentrations were higher in urban area than in the rural area. > Studied areas were separated by CDA based on the elemental concentrations. > Dust and leaves can be useful for monitoring the environmental load. - Studying the elements (Al, Ba, Ca, Cu, Fe, K, Mg, Na, P, S, Sr, Zn) in dust and leaves along an urbanization gradient in Wien, Austria we found that the elemental concentrations of foliage dust were significantly higher in the urban area than in the rural area for Al, Ba, Fe, Pb, P and Se, and concentrations of leaves were significantly higher in urban than in rural area for Mn and Sr.

  20. ORIGIN OF DUST AROUND V1309 SCO

    International Nuclear Information System (INIS)

    Zhu, Chunhua; Lü, Guoliang; Wang, Zhaojun

    2013-01-01

    The origin of dust grains in the interstellar medium is still an unanswered problem. Nicholls et al. found the presence of a significant amount of dust around V1309 Sco, which may originate from the merger of a contact binary. We investigate the origin of dust around V1309 Sco and suggest that these dust grains are produced in the binary-merger ejecta. By means of the AGBDUST code, we estimate that ∼5.2 × 10 –4 M ☉ dust grains are produced with a radii of ∼10 –5 cm. These dust grains are mainly composed of silicate and iron grains. Because the mass of the binary merger ejecta is very small, the contribution of dust produced by binary merger ejecta to the overall dust production in the interstellar medium is negligible. However, it is important to note that the discovery of a significant amount of dust around V1309 Sco offers a direct support for the idea that common-envelope ejecta provides an ideal environment for dust formation and growth. Therefore, we confirm that common envelope ejecta can be important source of cosmic dust

  1. Engineering-scale dust control experiments

    International Nuclear Information System (INIS)

    Winberg, M.R.; Pawelko, R.J.; Jacobs, N.C.; Thompson, D.N.

    1990-12-01

    This report presents the results of engineering scale dust-control experiments relating to contamination control during handling of transuranic waste. These experiments focused on controlling dust during retrieval operations of buried waste where waste and soil are intimately mixed. Sources of dust generation during retrieval operations include digging, dumping, and vehicle traffic. Because contaminants are expected to attach to soil particles and move with the generated dust, control of the dust spread may be the key to contamination control. Dust control techniques examined in these experiments include the use of misting systems, soil fixatives, and dust suppression agents. The Dryfog Ultrasonic Misting Head, manufactured by Sonics, Incorporated, and ENTAC, an organic resin derived from tree sap manufactured by ENTAC Corporation, were tested. The results of the experiments include product performance and recommended application methods. 19 figs., 7 refs., 6 tabs

  2. COSMIC DUST AGGREGATION WITH STOCHASTIC CHARGING

    International Nuclear Information System (INIS)

    Matthews, Lorin S.; Hyde, Truell W.; Shotorban, Babak

    2013-01-01

    The coagulation of cosmic dust grains is a fundamental process which takes place in astrophysical environments, such as presolar nebulae and circumstellar and protoplanetary disks. Cosmic dust grains can become charged through interaction with their plasma environment or other processes, and the resultant electrostatic force between dust grains can strongly affect their coagulation rate. Since ions and electrons are collected on the surface of the dust grain at random time intervals, the electrical charge of a dust grain experiences stochastic fluctuations. In this study, a set of stochastic differential equations is developed to model these fluctuations over the surface of an irregularly shaped aggregate. Then, employing the data produced, the influence of the charge fluctuations on the coagulation process and the physical characteristics of the aggregates formed is examined. It is shown that dust with small charges (due to the small size of the dust grains or a tenuous plasma environment) is affected most strongly

  3. Mineralogical Study of a Biologically-Based Treatment System That Removes Arsenic, Zinc and Copper from Landfill Leachate

    Directory of Open Access Journals (Sweden)

    Maryam Khoshnoodi

    2013-12-01

    Full Text Available Mineralogical characterization by X-ray diffraction (XRD and a high throughput automated quantitative evaluation of minerals by scanning electron microscopy (QEMSCAN was conducted on samples from a sulphate-reducing biochemical reactor (BCR treating high concentrations of metals (As, Zn, Cu in smelter waste landfill seepage. The samples were also subjected to energy dispersive X-ray (EDX analysis of specific particles. The bulk analysis results revealed that the samples consisted mainly of silicate and carbonate minerals. More detailed phase analysis indicated four different classes: zinc-arsenic sulphosalts/sulphates, zinc-arsenic oxides, zinc phosphates and zinc-lead sulphosalts/sulphates. This suggests that sulphates and sulphides are the predominant types of Zn and As minerals formed in the BCR. Sphalerite (ZnS was a common mineral observed in many of the samples. In addition, X-ray point analysis showed evidence of As and Zn coating around feldspar and amphibole particles. The presence of arsenic-zinc-iron, with or without cadmium particles, indicated arsenopyrite minerals. Copper-iron-sulphide particles suggested chalcopyrite (CuFeS2 and tennantite (Cu,Fe12As4S13. Microbial communities found in each sample were correlated with metal content to describe taxonomic groups associated with high-metal samples. The research results highlight mineral grains that were present or formed at the site that might be the predominant forms of immobilized arsenic, zinc and copper.

  4. Iron mineralogy and bioaccessibility of dust generated from soils as determined by reflectance spectroscopy and magnetic and chemical properties--Nellis Dunes recreational area, Nevada

    Science.gov (United States)

    Goldstein, Harland L.; Reynolds, Richard L.; Morman, Suzette A.; Moskowitz, Bruce; Kokaly, Raymond F.; Goossens, Dirk; Buck, Brenda J.; Flagg, Cody; Till, Jessica; Yauk, Kimberly; Berquó, Thelma S.

    2013-01-01

    Atmospheric mineral dust exerts many important effects on the Earth system, such as atmospheric temperatures, marine productivity, and melting of snow and ice. Mineral dust also can have detrimental effects on human health through respiration of very small particles and the leaching of metals in various organs. These effects can be better understood through characterization of the physical and chemical properties of dust, including certain iron oxide minerals, for their extraordinary radiative properties and possible effects on lung inflammation. Studies of dust from the Nellis Dunes recreation area near Las Vegas, Nevada, focus on characteristics of radiative properties (capacity of dust to absorb solar radiation), iron oxide mineral type and size, chemistry, and bioaccessibility of metals in fluids that simulate human gastric, lung, and phagolysosomal fluids. In samples of dust from the Nellis Dunes recreation area with median grain sizes of 2.4, 3.1, and 4.3 micrometers, the ferric oxide minerals goethite and hematite, at least some of it nanosized, were identified. In one sample, in vitro bioaccessibility experiments revealed high bioaccessibility of arsenic in all three biofluids and higher leachate concentration and bioaccessibility for copper, uranium, and vanadium in the simulated lung fluid than in the phagolysosomal fluid. The combination of methods used here to characterize mineral dust at the Nellis Dunes recreation area can be applied to global dust and broad issues of public health.

  5. Coupling Mars' Dust and Water Cycles: Effects on Dust Lifting Vigor, Spatial Extent and Seasonality

    Science.gov (United States)

    Kahre, M. A.; Hollingsworth, J. L.; Haberle, R. M.; Montmessin, F.

    2012-01-01

    The dust cycle is an important component of Mars' current climate system. Airborne dust affects the radiative balance of the atmosphere, thus greatly influencing the thermal and dynamical state of the atmosphere. Dust raising events on Mars occur at spatial scales ranging from meters to planet-wide. Although the occurrence and season of large regional and global dust storms are highly variable from one year to the next, there are many features of the dust cycle that occur year after year. Generally, a low-level dust haze is maintained during northern spring and summer, while elevated levels of atmospheric dust occur during northern autumn and winter. During years without global-scale dust storms, two peaks in total dust loading were observed by MGS/TES: one peak occurred before northern winter solstice at Ls 200-240, and one peak occurred after northern winter solstice at L(sub s) 305-340. These maxima in dust loading are thought to be associated with transient eddy activity in the northern hemisphere, which has been observed to maximize pre- and post-solstice. Interactive dust cycle studies with Mars General Circulation Models (MGCMs) have included the lifting, transport, and sedimentation of radiatively active dust. Although the predicted global dust loadings from these simulations capture some aspects of the observed dust cycle, there are marked differences between the simulated and observed dust cycles. Most notably, the maximum dust loading is robustly predicted by models to occur near northern winter solstice and is due to dust lifting associated with down slope flows on the flanks of the Hellas basin. Thus far, models have had difficulty simulating the observed pre- and post- solstice peaks in dust loading. Interactive dust cycle studies typically have not included the formation of water ice clouds or their radiative effects. Water ice clouds can influence the dust cycle by scavenging dust from atmosphere and by interacting with solar and infrared radiation

  6. 21 CFR 73.1647 - Copper powder.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 1 2010-04-01 2010-04-01 false Copper powder. 73.1647 Section 73.1647 Food and... ADDITIVES EXEMPT FROM CERTIFICATION Drugs § 73.1647 Copper powder. (a) Identity. (1) The color additive copper powder is a very fine free-flowing metallic powder prepared from virgin electrolytic copper. It...

  7. Copper uptake and retention in liver parenchymal cells isolated from nutritionally copper-deficient rats

    NARCIS (Netherlands)

    Berg, van den G.J.; de Goeij, J.J.M.; Bock, I.; Gijbels, M.J.J.; Brouwer, A.; Lei, K.Y.; Hendriks, H.F.J.

    1991-01-01

    Copper uptake and retention were studied in primary cultures of liver parenchymal cells isolated from copper-deficient rats. Male Sprague-Dawley rats were fed a copper-deficient diet (<1 mg Cu/kg) for 10 wk. Copper-deficient rats were characterized by low copper concentrations in plasma and liver,

  8. Copper uptake and retention in liver parenchymal cells isolated from nutritionally copper-deficient rats

    NARCIS (Netherlands)

    Berg, G.J. van den; Goeij, J.J.M. de; Bock, I.; Gijbels, M.J.J.; Brouwer, A.; Lei, K.Y.; Hendruiks, H.F.J.

    1991-01-01

    Copper uptake and retention were studied in primary cultures of liver parenchymal cells isolated from copper-deficient rats. Male Sprague-Dawley rats were fed a copper-deficient diet (< 1 mg Cu/kg) for 10 wk. Copper-deficient rats were characterized by low copper concentrations in plasma and liver,

  9. Trail smelter question

    Energy Technology Data Exchange (ETDEWEB)

    Katz, M; McCallium, A W

    1937-01-01

    Under conditions existing at Summerland, B.C., trees growing under irrigation are definitely more susceptible to injury by sulfur dioxide than trees growing in natural habitat. In order of susceptibility to injury by sulfur dioxide the species used in these experiments rank as follows: larch, Douglas fir, Engelmann spruce, white pine, yellow pine, cedar, lodgepole pine, silver fir, and white fir. The conclusions drawn from the experiments carried out in 1931 on conifers in regard to seasonal variation in susceptibility were corroborated by the present work, it being shown that trees are very susceptible to injury during the early part of the growing season and very resistant during the fall and early winter. Lareh is extremely sensitive to injury, a fumigation of 0.30 ppM for six hours at an average humidity of 67 per cent causing injury at the end of May. Larch leaves growing on wood produced during the current year are much more susceptible to injury than are leaves produced on wood formed in previous years. Many larches which sustained severe injury to the foliage on wood of the current year made rapid growth subsequent to the fumigation, the injury seeming to have but slight effect upon growth. 10 figures, 17 tables.

  10. NID Copper Sample Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Kouzes, Richard T.; Zhu, Zihua

    2011-09-12

    The current focal point of the nuclear physics program at PNNL is the MAJORANA DEMONSTRATOR, and the follow-on Tonne-Scale experiment, a large array of ultra-low background high-purity germanium detectors, enriched in 76Ge, designed to search for zero-neutrino double-beta decay (0νββ). This experiment requires the use of germanium isotopically enriched in 76Ge. The MAJORANA DEMONSTRATOR is a DOE and NSF funded project with a major science impact. The DEMONSTRATOR will utilize 76Ge from Russia, but for the Tonne-Scale experiment it is hoped that an alternate technology, possibly one under development at Nonlinear Ion Dynamics (NID), will be a viable, US-based, lower-cost source of separated material. Samples of separated material from NID require analysis to determine the isotopic distribution and impurities. DOE is funding NID through an SBIR grant for development of their separation technology for application to the Tonne-Scale experiment. The Environmental Molecular Sciences facility (EMSL), a DOE user facility at PNNL, has the required mass spectroscopy instruments for making isotopic measurements that are essential to the quality assurance for the MAJORANA DEMONSTRATOR and for the development of the future separation technology required for the Tonne-Scale experiment. A sample of isotopically separated copper was provided by NID to PNNL in January 2011 for isotopic analysis as a test of the NID technology. The results of that analysis are reported here. A second sample of isotopically separated copper was provided by NID to PNNL in August 2011 for isotopic analysis as a test of the NID technology. The results of that analysis are also reported here.

  11. Gallium and copper radiopharmaceutical chemistry

    International Nuclear Information System (INIS)

    Green, M.A.

    1991-01-01

    Gallium and copper radionuclides have a long history of use in nuclear medicine. Table 1 presents the nuclear properties of several gallium and copper isotopes that either are used in the routine practice of clinical nuclear medicine or exhibit particular characteristics that might make them useful in diagnostic or therapeutic medicine. This paper will provide some historic perspective along with an overview of some current research directions in gallium and copper radiopharmaceutical chemistry. A more extensive review of gallium radiopharmaceutical chemistry has recently appeared and can be consulted for a more in-depth treatment of this topic

  12. Integrating science and business models of sustainability for environmentally-challenging industries such as secondary lead smelters: a systematic review and analysis of findings.

    Science.gov (United States)

    Genaidy, A M; Sequeira, R; Tolaymat, T; Kohler, J; Wallace, S; Rinder, M

    2010-09-01

    Secondary lead smelters (SLS) represent an environmentally-challenging industry as they deal with toxic substances posing potential threats to both human and environmental health, consequently, they operate under strict government regulations. Such challenges have resulted in the significant reduction of SLS plants in the last three decades. In addition, the domestic recycling of lead has been on a steep decline in the past 10 years as the amount of lead recovered has remained virtually unchanged while consumption has increased. Therefore, one may wonder whether sustainable development can be achieved among SLS. The primary objective of this study was to determine whether a roadmap for sustainable development can be established for SLS. The following aims were established in support of the study objective: (1) to conduct a systematic review and an analysis of models of sustainable systems with a particular emphasis on SLS; (2) to document the challenges for the U.S. secondary lead smelting industry; and (3) to explore practices and concepts which act as vehicles for SLS on the road to sustainable development. An evidence-based methodology was adopted to achieve the study objective. A comprehensive electronic search was conducted to implement the aforementioned specific aims. Inclusion criteria were established to filter out irrelevant scientific papers and reports. The relevant articles were closely scrutinized and appraised to extract the required information and data for the possible development of a sustainable roadmap. The search process yielded a number of research articles which were utilized in the systematic review. Two types of models emerged: management/business and science/mathematical models. Although the management/business models explored actions to achieve sustainable growth in the industrial enterprise, science/mathematical models attempted to explain the sustainable behaviors and properties aiming at predominantly ecosystem management. As such

  13. House Dust Mite Respiratory Allergy

    DEFF Research Database (Denmark)

    Calderón, Moisés A; Kleine-Tebbe, Jörg; Linneberg, Allan

    2015-01-01

    Although house dust mite (HDM) allergy is a major cause of respiratory allergic disease, specific diagnosis and effective treatment both present unresolved challenges. Guidelines for the treatment of allergic rhinitis and asthma are well supported in the literature, but specific evidence on the e......Although house dust mite (HDM) allergy is a major cause of respiratory allergic disease, specific diagnosis and effective treatment both present unresolved challenges. Guidelines for the treatment of allergic rhinitis and asthma are well supported in the literature, but specific evidence...... not extend beyond the end of treatment. Finally, allergen immunotherapy has a poor but improving evidence base (notably on sublingual tablets) and its benefits last after treatment ends. This review identifies needs for deeper physician knowledge on the extent and impact of HDM allergy in respiratory disease...... and therapy of HDM respiratory allergy in practice....

  14. Copper complexes as 'radiation recovery' agents

    International Nuclear Information System (INIS)

    Sorenson, J.R.J.

    1989-01-01

    Copper and its compounds have been used for their remedial effects since the beginning of recorded history. As early as 3000 BC the Egyptians used copper as an antiseptic for healing wounds and to sterilise drinking water; and later, ca 1550 BC, the Ebers Papyrus reports the use of copper acetate, copper sulphate and pulverised metallic copper for the treatment of eye infections. These historical uses of copper and its compounds are particularly interesting in the light of modern evidence concerning the use of certain copper complexes for the treatment of radiation sickness and more recently as an adjunct to radiotherapy for cancer patients. (author)

  15. Collisionless damping of nonlinear dust ion acoustic wave due to dust charge fluctuation

    International Nuclear Information System (INIS)

    Ghosh, Samiran; Chaudhuri, Tushar K.; Sarkar, Susmita; Khan, Manoranjan; Gupta, M.R.

    2002-01-01

    A dissipation mechanism for the damping of the nonlinear dust ion acoustic wave in a collisionless dusty plasma consisting of nonthermal electrons, ions, and variable charge dust grains has been investigated. It is shown that the collisionless damping due to dust charge fluctuation causes the nonlinear dust ion acoustic wave propagation to be described by the damped Korteweg-de Vries equation. Due to the presence of nonthermal electrons, the dust ion acoustic wave admits both positive and negative potential and it suffers less damping than the dust acoustic wave, which admits only negative potential

  16. 78 FR 33409 - Proposed Information Collection Request; Comment Request; See Item Specific ICR Titles Provided...

    Science.gov (United States)

    2013-06-04

    ... Production (40 CFR Part 60, Subpart M), Primary Copper Smelters (40 CFR Part 60, Subpart P), Primary Zinc... bronze production facilities, primary copper smelters, primary zinc smelters, primary lead smelters... ID Number: EPA-HQ-OECA-2013-0314; Title: NSPS for Phosphate Rock Plants (40 CFR Part 60, Subpart NN...

  17. Respiratory effects of borax dust.

    Science.gov (United States)

    Garabrant, D H; Bernstein, L; Peters, J M; Smith, T J; Wright, W E

    1985-12-01

    The relation of respiratory symptoms, pulmonary function, and abnormalities of chest radiographs to estimated exposures of borax dust has been investigated in a cross sectional study of 629 actively employed borax workers. Ninety three per cent of the eligible workers participated in the study and exposures ranged from 1.1 mg/m3 to 14.6 mg/m3. Symptoms of acute respiratory irritation such as dryness of the mouth, nose, or throat, dry cough, nose bleeds, sore throat, productive cough, shortness of breath, and chest tightness were related to exposures of 4.0 mg/m3 or more, and were infrequent at exposures of 1.1 mg/m3. Symptoms of persistent respiratory irritation meeting the definition of chronic simple bronchitis were related to exposure among non-smokers. Decrements in the FEV1 as a percentage of predicted were seen among smokers who had heavy cumulative borax exposures (greater than or equal to 80 mg/m3 years) but were not seen among less exposed smokers or among non-smokers. Radiographic abnormalities were uncommon and were not related to dust exposure. Borax dust appears to act as a simple respiratory irritant and perhaps causes small changes in the FEV1 among smokers who are heavily exposed.

  18. Dust-Tolerant Intelligent Electrical Connection System

    Science.gov (United States)

    Lewis, Mark; Dokos, Adam; Perotti, Jose; Calle, Carlos; Mueller, Robert; Bastin, Gary; Carlson, Jeffrey; Townsend, Ivan, III; Immer, Chirstopher; Medelius, Pedro

    2012-01-01

    Faults in wiring systems are a serious concern for the aerospace and aeronautic (commercial, military, and civilian) industries. Circuit failures and vehicle accidents have occurred and have been attributed to faulty wiring created by open and/or short circuits. Often, such circuit failures occur due to vibration during vehicle launch or operation. Therefore, developing non-intrusive fault-tolerant techniques is necessary to detect circuit faults and automatically route signals through alternate recovery paths while the vehicle or lunar surface systems equipment is in operation. Electrical connector concepts combining dust mitigation strategies and cable diagnostic technologies have significant application for lunar and Martian surface systems, as well as for dusty terrestrial applications. The dust-tolerant intelligent electrical connection system has several novel concepts and unique features. It combines intelligent cable diagnostics (health monitoring) and automatic circuit routing capabilities into a dust-tolerant electrical umbilical. It retrofits a clamshell protective dust cover to an existing connector for reduced gravity operation, and features a universal connector housing with three styles of dust protection: inverted cap, rotating cap, and clamshell. It uses a self-healing membrane as a dust barrier for electrical connectors where required, while also combining lotus leaf technology for applications where a dust-resistant coating providing low surface tension is needed to mitigate Van der Waals forces, thereby disallowing dust particle adhesion to connector surfaces. It also permits using a ruggedized iris mechanism with an embedded electrodynamic dust shield as a dust barrier for electrical connectors where required.

  19. Ocular toxicity of authentic lunar dust.

    Science.gov (United States)

    Meyers, Valerie E; Garcìa, Hector D; Monds, Kathryn; Cooper, Bonnie L; James, John T

    2012-07-20

    Dust exposure is a well-known occupational hazard for terrestrial workers and astronauts alike and will continue to be a concern as humankind pursues exploration and habitation of objects beyond Earth. Humankind's limited exploration experience with the Apollo Program indicates that exposure to dust will be unavoidable. Therefore, NASA must assess potential toxicity and recommend appropriate mitigation measures to ensure that explorers are adequately protected. Visual acuity is critical during exploration activities and operations aboard spacecraft. Therefore, the present research was performed to ascertain the ocular toxicity of authentic lunar dust. Small (mean particle diameter = 2.9 ± 1.0 μm), reactive lunar dust particles were produced by grinding bulk dust under ultrapure nitrogen conditions. Chemical reactivity and cytotoxicity testing were performed using the commercially available EpiOcularTM assay. Subsequent in vivo Draize testing utilized a larger size fraction of unground lunar dust that is more relevant to ocular exposures (particles lunar dust was minimally irritating. Minor irritation of the upper eyelids was noted at the 1-hour observation point, but these effects resolved within 24 hours. In addition, no corneal scratching was observed using fluorescein stain. Low-titanium mare lunar dust is minimally irritating to the eyes and is considered a nuisance dust for ocular exposure. No special precautions are recommended to protect against ocular exposures, but fully shielded goggles may be used if dust becomes a nuisance.

  20. Dust characterisation for hot gas filters

    Energy Technology Data Exchange (ETDEWEB)

    Dockter, B.; Erickson, T.; Henderson, A.; Hurley, J.; Kuehnel, V.; Katrinak, K.; Nowok, J.; O`Keefe, C.; O`Leary, E.; Swanson, M.; Watne, T. [University of North Dakota, Grand Forks, ND (United States). Energy and Environmental Research Center (UNDEERC)

    1998-03-01

    Hot gas filtration to remove particulates from the gas flow upstream of the gas turbine is critical to the development of many of the advanced coal-fired power generation technologies such as the Air Blown Gasification Cycle (ABGC), a hybrid gasification combined cycle being developed in the UK. Ceramic candle filters are considered the most promising technology for this purpose. Problems of mechanical failure and of `difficult-to-clean` dusts causing high pressure losses across the filter elements need to be solved. The project investigated the behaviour of high-temperature filter dusts, and the factors determining the ease with which they can be removed from filters. The high-temperature behaviour of dusts from both combustion and gasification systems was investigated. Dust samples were obtained from full-scale demonstration and pilot-scale plant operating around the world. Dust samples were also produced from a variety of coals, and under several different operating conditions, on UNDEERC`s pilot-scale reactor. Key factors affecting dust behaviour were examined, including: the rates of tensile strength developing in dust cakes; the thermochemical equilibria pertaining under filtration conditions; dust adhesivity on representative filter materials; and the build-up and cleaning behaviour of dusts on representative filter candles. The results obtained confirmed the importance of dust temperature, dust cake porosity, cake liquid content, and particle size distribution in determining the strength of a dust cake. An algorithm was developed to indicate the likely sticking propensity of dusts as a function of coal and sorbent composition and combustion conditions. This algorithm was incorporated into a computer package which can be used to judge the degree of difficulty in filter cleaning that can be expected to arise in a real plant based on operating parameters and coal analyzes. 6 figs.

  1. Copper tailings in stucco mortars

    Directory of Open Access Journals (Sweden)

    Osvaldo Pavez

    Full Text Available Abstract This investigation addressed the evaluation of the use of copper tailings in the construction industry in order to reduce the impact on the environment. The evaluation was performed by a technical comparison between stucco mortars prepared with crushed conventional sand and with copper tailings sand. The best results were achieved with the stucco mortars containing tailings. The tailings presented a fine particles size distribution curve different from that suggested by the standard. The values of compressive strength, retentivity, and adherence in the stucco mortars prepared with copper tailings were much higher than those obtained with crushed sand. According to the results from this study, it can be concluded that the preparation of stucco mortars using copper tailings replacing conventional sand is a technically feasible alternative for the construction industry, presenting the benefit of mitigating the impact of disposal to the environment.

  2. Health effects from exposure to atmospheric mineral dust near Las Vegas, NV, USA

    Directory of Open Access Journals (Sweden)

    Deborah E. Keil

    Full Text Available Desert areas are usually characterized by a continuous deposition of fine airborne particles. Over time, this process results in the accumulation of silt and clay on desert surfaces. We evaluated health effects associated with regional atmospheric dust, or geogenic dust, deposited on surfaces in the Nellis Dunes Recreation Area (NDRA in Clark County, Nevada, a popular off-road vehicle (ORV recreational site frequented daily by riders, families, and day campers. Because of atmospheric mixing and the mostly regional origin of the accumulated particles, the re-suspended airborne dust is composed of a complex mixture of minerals and metals including aluminum, vanadium, chromium, manganese, iron, cobalt, copper, zinc, arsenic, strontium, cesium, lead, uranium, and others. Geogenic dust with a median diameter of 4.1 μm was administered via oropharyngeal aspiration to female B6C3F1 mice at doses of 0.01 to 100 mg dust/kg body weight, four times, a week apart, for 28-days. Immuno- and neurotoxicological outcomes 24 h following the last exposure were evaluated. Antigen-specific IgM responses were dose-responsively suppressed at 0.1, 1.0, 10 and 100 mg/kg/day. Splenic and thymic lymphocytic subpopulations and natural killer cell activity also were significantly reduced. Antibodies against MBP, NF-68, and GFAP were not affected, while brain CD3+ T cells were decreased in number. A lowest observed adverse effect level (LOAEL of 0.1 mg/kg/day and a no observed adverse effect level (NOAEL of 0.01 mg/kg/day were derived based on the antigen-specific IgM responses. Keywords: Geogenic dust, Heavy metals, Minerals, Lung exposure, Immunotoxicity, Neurotoxicity

  3. The copper deposits of Michigan

    Science.gov (United States)

    Butler, B.S.; Burbank, W.S.

    1929-01-01

    The copper district of Keweenaw Point, in the northern peninsula of Michigan, is the second largest producer of copper in the world.  The output of the district since 1845 has been more than 7,500,000,000 pounds and showed a rather steady and consistent increase from the beginning of production to the end of the World War in 1918, since which there has been a marked decrease.

  4. Copper atomic-scale transistors.

    Science.gov (United States)

    Xie, Fangqing; Kavalenka, Maryna N; Röger, Moritz; Albrecht, Daniel; Hölscher, Hendrik; Leuthold, Jürgen; Schimmel, Thomas

    2017-01-01

    We investigated copper as a working material for metallic atomic-scale transistors and confirmed that copper atomic-scale transistors can be fabricated and operated electrochemically in a copper electrolyte (CuSO 4 + H 2 SO 4 ) in bi-distilled water under ambient conditions with three microelectrodes (source, drain and gate). The electrochemical switching-on potential of the atomic-scale transistor is below 350 mV, and the switching-off potential is between 0 and -170 mV. The switching-on current is above 1 μA, which is compatible with semiconductor transistor devices. Both sign and amplitude of the voltage applied across the source and drain electrodes ( U bias ) influence the switching rate of the transistor and the copper deposition on the electrodes, and correspondingly shift the electrochemical operation potential. The copper atomic-scale transistors can be switched using a function generator without a computer-controlled feedback switching mechanism. The copper atomic-scale transistors, with only one or two atoms at the narrowest constriction, were realized to switch between 0 and 1 G 0 ( G 0 = 2e 2 /h; with e being the electron charge, and h being Planck's constant) or 2 G 0 by the function generator. The switching rate can reach up to 10 Hz. The copper atomic-scale transistor demonstrates volatile/non-volatile dual functionalities. Such an optimal merging of the logic with memory may open a perspective for processor-in-memory and logic-in-memory architectures, using copper as an alternative working material besides silver for fully metallic atomic-scale transistors.

  5. Atmospheric corrosion effects on copper

    International Nuclear Information System (INIS)

    Franey, J.P.

    1985-01-01

    Studies have been performed on the naturally formed patina on various copper samples. Samples have been obtained from structures at AT and T Bell Laboratories, Murray Hill, NJ (40,2,1 and <1 yr) and the Statue of Liberty (100 yr). The samples show a distinct layering effect, that is, the copper base material shows separate oxide and basic sulfate layers on all samples, indicating that patina is not a homogeneous mixture of oxides and basic sulfates

  6. Chronic copper poisoning in lambs

    Energy Technology Data Exchange (ETDEWEB)

    Ross, D B

    1964-08-08

    This communication presented evidence of the elevation of plasma GOT (glutamic oxaloacetic transaminase or aspartate transaminase) concentration during the development of copper toxicity in some experimental lambs, and also demonstrated that plasma GOT concentration can be used to assess the course of the disease during treatment. A group of Kerry Hill lambs were fed 1 1/2 lb per day of a proprietary concentrate containing 40 parts of copper per million on a dry-matter basis in addition to hay and water ad lib. Data was included for the plasma GOT concentrations of the lambs, bled weekly after weaning from pasture to this diet. There was some variation between the individual lambs, and in one there was no increase in plasma GOT by the 20th week when all the surviving lambs were slaughtered. The concentrations of copper found in the caudate lobe of the liver and in the kidney cortex post mortem were given. The overall findings showed that the liver gave a reliable indication of the copper status of an animal whereas the kidney cortex copper concentration was a better criterion for the diagnosis of copper poisoning and was in agreement with the results of Eden, Todd, and Grocey and Thompson. Observations demonstrated the benefits resulting from the early diagnosis of chronic copper poisoning in lambs, when treatment of affected animals may be commenced before the haemolytic crisis develops. Treatment included reducing the copper intake and dosing with ammonium molybdate and sodium sulfate, and the plasma GOT concentration may be used to assess the rate of recovery. 4 references, 3 tables.

  7. House dust in seven Danish offices

    Science.gov (United States)

    Mølhave, L.; Schneider, T.; Kjærgaard, S. K.; Larsen, L.; Norn, S.; Jørgensen, O.

    Floor dust from Danish offices was collected and analyzed. The dust was to be used in an exposure experiment. The dust was analyzed to show the composition of the dust which can be a source of airborne dust indoors. About 11 kg of dust from vacuum cleaner bags from seven Danish office buildings with about 1047 occupants (12 751 m 2) was processed according to a standardized procedure yielding 5.5 kg of processed bulk dust. The bulk dust contained 130.000-160.000 CFU g -1 microorganisms and 71.000-90.000 CFU g -1 microfungi. The content of culturable microfungi was 65-123 CFU 30 g -1 dust. The content of endotoxins ranged from 5.06-7.24 EU g -1 (1.45 ng g -1 to 1.01 ng g -1). Allergens (ng g -1) were from 147-159 (Mite), 395-746 (dog) and 103-330 (cat). The macro molecular organic compounds (the MOD-content) varied from 7.8-9.8 mg g -1. The threshold of release of histamine from basophil leukocytes provoked by the bulk dust was between 0.3 and 1.0 mg ml -1. The water content was 2% (WGT) and the organic fraction 33%. 6.5-5.9% (dry) was water soluble. The fiber content was less than 0.2-1.5% (WGT) and the desorbable VOCs was 176-319 μg g -1. Most of the VOC were aldehydes. However, softeners for plastic (DBP and DEHP) were present. The chemical composition includes human and animal skin fragments, paper fibers, glass wool, wood and textilefibers and inorganic and metal particles. The sizes ranged from 0.001-1 mm and the average specific density was 1.0 g m -3. The bulk dust was resuspended and injected into an exposure chamber. The airborne dust was sampled and analyzed to illustrate the exposures that can result from sedimented dirt and dust. The airborne dust resulting from the bulk dust reached concentrations ranging from 0.26-0.75 mg m -3 in average contained 300-170 CFU m -3. The organic fraction was from 55-70% and the water content about 2.5% (WGT). The content of the dust was compared to the similar results reported in the literature and its toxic potency is

  8. Incubation of air-pollution-control residues from secondary Pb smelter in deciduous and coniferous organic soil horizons: Leachability of lead, cadmium and zinc

    Energy Technology Data Exchange (ETDEWEB)

    Chrastny, Vladislav, E-mail: vladislavchrastny@seznam.cz [University of South Bohemia, Faculty of Science, Studentska 13, 370 05 Ceske Budejovice (Czech Republic); Czech University of Life Sciences Prague, Faculty of Environmental Sciences, Kamycka 129, 165 21 Prague 6 (Czech Republic); Vanek, Ales [Czech University of Life Sciences Prague, Faculty of Agrobiology, Food and Natural Resources, Kamycka 129, 165 21 Praha 6 (Czech Republic); Komarek, Michael [Czech University of Life Sciences Prague, Faculty of Environmental Sciences, Kamycka 129, 165 21 Prague 6 (Czech Republic); Farkas, Juraj [Czech Geological Survey, Geologicka 6, 152 00 Praha 5 (Czech Republic); Drabek, Ondrej; Vokurkova, Petra [Czech University of Life Sciences Prague, Faculty of Agrobiology, Food and Natural Resources, Kamycka 129, 165 21 Praha 6 (Czech Republic); Nemcova, Jana [University of South Bohemia, Faculty of Agriculture, Studentska 13, 370 05 Ceske Budejovice (Czech Republic)

    2012-03-30

    Highlights: Black-Right-Pointing-Pointer Pb smelter fly ash was incubated in forest soil horizons to assess metal mobility. Black-Right-Pointing-Pointer The metal mobilization depends on pH and the ratio of humic/fulvic acids to SOM. Black-Right-Pointing-Pointer The lowest mobilization of Pb, Zn and Cd took place in horizon H (coniferous forest). Black-Right-Pointing-Pointer A huge amount of Cd was found to have leached in the horizon F (deciduous forest). Black-Right-Pointing-Pointer More vulnerable to metal leaching from APC residues is soil from deciduous forest. - Abstract: The leachability of air-pollution-control (APC) residues from a secondary lead smelter in organic soil horizons (F and H) from a deciduous and a coniferous forest during incubation periods of 0, 3 and 6 months were compared in this work. While the concentration of Pb, Zn and Cd associated with the exchangeable/acid extractable fraction in the horizon F from the coniferous forest was higher compared to the deciduous, significantly lower concentrations in the humified horizon H was found. It is suggested that lower pH and a higher share of fulvic acids fraction (FAs) of solid phase soil organic matter (SOM) in the humified soil horizon H from the coniferous compared to the deciduous forest is responsible for a higher metal association with solid phase SOM and therefore a lower metal leaching in a soil system. From this point of view, the humified soil horizon H from the deciduous forest represents a soil system more vulnerable to Pb, Zn and Cd leaching from APC residues.

  9. A test of the stability of Cd, Cu, Hg, Pb and Zn profiles over two decades in lake sediments near the Flin Flon Smelter, Manitoba, Canada

    Energy Technology Data Exchange (ETDEWEB)

    Percival, J.B.; Outridge, P.M., E-mail: outridge@nrcan.gc.ca

    2013-06-01

    Lake sediments are valuable archives of atmospheric metal deposition, but the stability of some element profiles may possibly be affected by diagenetic changes over time. In this extensive case study, the stability of sedimentary Cd, Cu, Hg, Pb and Zn profiles was assessed in dated sediment cores that were collected in 2004 from four smelter-affected lakes near Flin Flon, Manitoba, which had previously been cored in 1985. Metal profiles determined in 1985 were in most cases clearly reproduced in the corresponding sediment layers in 2004, although small-scale spatial heterogeneity in metal distribution complicated the temporal comparisons. Pre-smelter (i.e. pre-1930) increases in metal profiles were likely the result of long-range atmospheric metal pollution, coupled with particle mixing at the 1930s sediment surface. However, the close agreement between key inflection points in the metal profiles sampled two decades apart suggests that metals in most of the lakes, and Hg and Zn in the most contaminated lake (Meridian), were stable once the sediments were buried below the surface mixed layer. Cadmium, Cu and Pb profiles in Meridian Lake did not agree as well between studies, showing evidence of upward remobilization over time. Profiles of redox-indicator elements (Fe, Mn, Mo and U) suggested that the rate of Mn oxyhydroxide recycling within sediment was more rapid in Meridian Lake, which may have caused the Cd, Cu and Pb redistribution. - Highlights: • Sedimentary Cd, Cu, Hg, Pb and Zn profiles in four lakes were mostly unchanged over 19 years. • In one lake, Cd, Cu and Pb profiles were offset relative to the originals. • The offset could indicate diagenetic upcore dispersal of these metals.

  10. Copper sulphate poisoning in horses

    Energy Technology Data Exchange (ETDEWEB)

    Bauer, M

    1975-01-01

    In the archives of the Clinic for Internal Diseases of Domestic Animals at the Veterinary Faculty of Zagreb University some thirty cases of horse disease diagnosed as copper sulphate poisoning were noted. The data correspond in many respects to the clinical findings of copper sulphate poisoning in other domestic animals. A series of experimental horse poisonings were undertaken in order to determine the toxicity of copper sulphate. The research results are as follows: Horses are sensitive to copper sulphate. Even a single application of 0.125 g/kg body weight in 1% concentration by means of incubation into the stomach causes stomach and gut disturbances and other poisoning symptoms. Poisoning occurs in two types: acute and chronic. The former appears after one to three applications of copper sulphate solution and is characterized by gastroenteritis, haemolysis, jaundice and haemoglobinuria with signs of consecutive damage of kidney, liver and other organs. The disease, from the first application to death lasts for two weeks. Chronic poisoning is caused by ingestion of dry copper sulphate in food (1% solution dried on hay or clover) for two or more months. There are chronic disturbances of stomach and gut and loss of weight, and consecutive (three to four) haemolytic crises similar to those of acute poisoning. From the beginning of poisoning to death six or more months can elapse.

  11. Characterization of high concentration dust generator

    International Nuclear Information System (INIS)

    Shimura, Toichiro; Yokochi, Akira

    1999-01-01

    This paper describes the development of fluidized bed type high concentration dust generator that keeps for long period dust concentration range of about 10 mg/m 3 for the study of working place monitoring system and evaluation of respirator. The generator is keeping constant powder in fluidized bed for keeping the dust concentration. It is necessary to keep constant feeding rate of powder in order to keep the quantity of dust in the fluidized bed. Our generator enables to obtain constant feeding rate by a screw feeder and by using mixed powder with fluidising particles (glass beads) before feeding. The generator produces high concentration dust of 11.3 mg/m 3 ± 1.0 mg/m 3 for about 5 hours and keeps the dust size 4.2-4.6 μm in mass median aerodynamic diameter with reasonable reproducibility. (author)

  12. Molecules and dust in Cassiopeia A

    DEFF Research Database (Denmark)

    Biscaro, Chiara; Cherchneff, Isabelle

    2016-01-01

    We study the dust evolution in the supernova remnant Cassiopeia A. We follow the processing of dust grains that formed in the Type II-b supernova ejecta by modelling the sputtering of grains. The dust is located in dense ejecta clumps that are crossed by the reverse shock. We also investigate......-rich clumps that correspond to the outermost carbon-rich ejecta zone. We consider the various dust components that form in the supernova, several reverse shock velocities and inter-clump gas temperatures, and derive grain-size distributions and masses for the dust as a function of time. Both non...... and size, and the shock velocity in the clump. A Type II-b SN forms small grains that are sputtered within the clumps and in the inter-clump medium. For Cas A, silicate grains do not survive thermal sputtering in the inter-clump medium, while alumina, silicon carbide, and carbon dust may survive...

  13. Active Dust Experiment in the Mesosphere

    International Nuclear Information System (INIS)

    Norberg, Carol; Pellinen-Wannberg, Asta

    2008-01-01

    The mesosphere stretches from an altitude of about 50 to 90 km above the Earth's surface. Meteors entering the Earth's atmosphere are believed to ablate and hence give rise to a thin layer of dust particles in the upper part of the Earth's mesosphere. It seems that the dust is most dense in a layer that lies between 80 and 90 km. The dust particles are thought to have sizes of a few to tens of nanometers. Efforts have been made to measure these particles using rockets and radar techniques with limited success. We propose to release dust into the mesosphere over northern Sweden at a height of about 90 km and observe the released dust using the EISCAT radar system. The dust will be launched from the Swedish Space Corporation Esrange Space Centre on a single-stage Improved-Orion rocket that will be launched so that its flight path will be in the radar field of view.

  14. Dust observations by PFS on Mars Express

    Science.gov (United States)

    Zasova, L. V.; Formisano, V.; Moroz, V. I.; Grassi, D.; Ignatiev, N. I.; Blecka, M. I.; Maturilli, A.; Palomba, E.; Piccioni, G.; Pfs Team

    Dust is always present in the Martian atmosphere with opacity, which changes from values below 0.1 (at 9 μ m) up to several units during the dust storms. From the thermal IR (LW channel of PFS) the dust opacity is retrieved in a self consistent way together with the temperature profile from the same spectrum A preliminary investigation along the orbit, which comes through Hellas, shows that the value of dust opacity anticorrelates with surface altitude. From -70 to +25 of latitude the vertical dust distribution follows the exponential low with the scale of 12 km, which corresponds to the gaseous scale height near noon and indicates for well mixed condition. The dust opacity, corresponding to the zero surface altitude, is found of 0.25+-0.05. More detailed investigations of all available data will be presented, including analysis of both short- and long- wavelength spectra of PFS.

  15. Formation and dissociation of dust molecules in dusty plasma

    International Nuclear Information System (INIS)

    Yan Jia; Feng Fan; Liu Fucheng; Dong Lifang; He Yafeng

    2016-01-01

    Dust molecules are observed in a dusty plasma experiment. By using measurements with high spatial resolution, the formation and dissociation of the dust molecules are studied. The ion cloud in the wake of an upper dust grain attracts the lower dust grain nearby. When the interparticle distance between the upper dust grain and the lower one is less than a critical value, the two dust grains would form a dust molecule. The upper dust grain always leads the lower one as they travel. When the interparticle distance between them is larger than the critical value, the dust molecule would dissociate. (paper)

  16. Genome Sequences of Two Copper-Resistant Escherichia coli Strains Isolated from Copper-Fed Pigs

    DEFF Research Database (Denmark)

    Lüthje, Freja L.; Hasman, Henrik; Aarestrup, Frank Møller

    2014-01-01

    The draft genome sequences of two copper-resistant Escherichia coli strains were determined. These had been isolated from copper-fed pigs and contained additional putative operons conferring copper and other metal and metalloid resistances.......The draft genome sequences of two copper-resistant Escherichia coli strains were determined. These had been isolated from copper-fed pigs and contained additional putative operons conferring copper and other metal and metalloid resistances....

  17. Thermodynamic analysis of the selective chlorination of electric arc furnace dust

    International Nuclear Information System (INIS)

    Pickles, C.A.

    2009-01-01

    The remelting of automobile scrap in an electric arc furnace (EAF) results in the production of a dust, which contains high concentrations of the oxides of zinc, iron, calcium and other metals. Typically, the lead and zinc are of commercial value, while the other metals are not worth recovering. At the present time, EAF dusts are treated in high temperature Waelz rotary kiln-type processes, where the lead and zinc oxides are selectively reduced and simultaneously reoxidized and a crude zinc oxide is produced. Another alternative processing route is selective chlorination, in which the non-ferrous metals are preferentially chlorinated to their gaseous chlorides and in this manner separated from the iron. In the present research, a detailed thermodynamic analysis of this chlorination process has been performed and the following factors were investigated; temperature, amount of chlorine, lime content, silica content, presence of an inert gas and the oxygen potential. High lead and zinc recoveries as gaseous chlorides could be achieved but some of the iron oxide was also chlorinated. Additionally, the calcium oxide in the dust consumes chlorine, but this can be minimized by adding silica, which results in the formation of stable calcium silicates. The optimum conditions were determined for a typical dust composition. The selectivities achieved with chlorination were lower than those for reduction, as reported in the literature, but there are other advantages such as the potential recovery of copper.

  18. Thermodynamic analysis of the selective chlorination of electric arc furnace dust

    Energy Technology Data Exchange (ETDEWEB)

    Pickles, C.A., E-mail: pickles-c@mine.queensu.ca [Department of Mining Engineering, Queen' s University, Kingston, Ontario, K7L 3N6 (Canada)

    2009-07-30

    The remelting of automobile scrap in an electric arc furnace (EAF) results in the production of a dust, which contains high concentrations of the oxides of zinc, iron, calcium and other metals. Typically, the lead and zinc are of commercial value, while the other metals are not worth recovering. At the present time, EAF dusts are treated in high temperature Waelz rotary kiln-type processes, where the lead and zinc oxides are selectively reduced and simultaneously reoxidized and a crude zinc oxide is produced. Another alternative processing route is selective chlorination, in which the non-ferrous metals are preferentially chlorinated to their gaseous chlorides and in this manner separated from the iron. In the present research, a detailed thermodynamic analysis of this chlorination process has been performed and the following factors were investigated; temperature, amount of chlorine, lime content, silica content, presence of an inert gas and the oxygen potential. High lead and zinc recoveries as gaseous chlorides could be achieved but some of the iron oxide was also chlorinated. Additionally, the calcium oxide in the dust consumes chlorine, but this can be minimized by adding silica, which results in the formation of stable calcium silicates. The optimum conditions were determined for a typical dust composition. The selectivities achieved with chlorination were lower than those for reduction, as reported in the literature, but there are other advantages such as the potential recovery of copper.

  19. Thermodynamic analysis of the selective chlorination of electric arc furnace dust.

    Science.gov (United States)

    Pickles, C A

    2009-07-30

    The remelting of automobile scrap in an electric arc furnace (EAF) results in the production of a dust, which contains high concentrations of the oxides of zinc, iron, calcium and other metals. Typically, the lead and zinc are of commercial value, while the other metals are not worth recovering. At the present time, EAF dusts are treated in high temperature Waelz rotary kiln-type processes, where the lead and zinc oxides are selectively reduced and simultaneously reoxidized and a crude zinc oxide is produced. Another alternative processing route is selective chlorination, in which the non-ferrous metals are preferentially chlorinated to their gaseous chlorides and in this manner separated from the iron. In the present research, a detailed thermodynamic analysis of this chlorination process has been performed and the following factors were investigated; temperature, amount of chlorine, lime content, silica content, presence of an inert gas and the oxygen potential. High lead and zinc recoveries as gaseous chlorides could be achieved but some of the iron oxide was also chlorinated. Additionally, the calcium oxide in the dust consumes chlorine, but this can be minimized by adding silica, which results in the formation of stable calcium silicates. The optimum conditions were determined for a typical dust composition. The selectivities achieved with chlorination were lower than those for reduction, as reported in the literature, but there are other advantages such as the potential recovery of copper.

  20. Lixiviación amoniacal de polvos de fundición de cobre y precipitación como sulfuro de cobre

    Directory of Open Access Journals (Sweden)

    Morales, A.

    2009-12-01

    Full Text Available The effect of ammonia on the leaching of copper smelter dust and copper precipitation from these solutions as sulphide using sulfur and sulfur dioxide was studied. The precipitation was done in ammoniacal media because this solution produced more satisfactory results at room temperature that a sulphuric media. A solid was precipitated containing 60 % of copper of the dust smelter. The other waste generated contained around 80 % of the arsenic of the original copper smelter dust. Based on the preliminary results obtained in this work it will propose a procedure for the recovery of copper as sulphide from copper smelter dust with parallel confinement of arsenic.

    Se estudió el efecto del amoniaco en la lixiviación de polvos de fundición de cobre y en la precipitación de sulfuro de cobre, usando azufre y dióxido de azufre desde estas disoluciones. La precipitación se realizó en un medio amoniacal para tener rendimientos satisfactorios a temperatura ambiente. Se precipitó un sólido que recupera alrededor del 60 % del cobre contenido en los polvos de fundición. El otro residuo generado contenía del orden del 80 % del arsénico de los polvos originales. Sobre la base de estos resultados preliminares, se planteó un procedimiento para la recuperación de cobre desde los polvos de fundición y para el confinamiento del arsénico.

  1. The risk of pulmonary tuberculosis in underground copper miners in Zambia exposed to respirable silica: a cross-sectional study

    Directory of Open Access Journals (Sweden)

    Kingsley Ngosa

    2016-08-01

    Full Text Available Abstract Background Pulmonary tuberculosis (PTB among underground miners exposed to silica remains a global problem. Although well described in gold and coal mining, risk in other mining entities are not as well documented. This study aims to determine dust-related dose response risk for PTB among underground miners exposed to silica dust in Zambia's copper mines. Methods A cross sectional study of in-service miners (n = 357 was conducted at Occupational Health and Safety Institute (OHSI, Zambia. A systematic review of medical data over a 5-year period from assessments conducted by doctors at OHSI and statutory silica exposure data (n = 16678 from the Mine Safety Department (MSD were analysed. Lifetime cumulative exposure metrics were calculated. Multivariate logistic regression analysis was used to determine the association between PTB and lifetime exposure to silica, while adjusting for various confounders. Results The median respirable silica dust level was 0.3 mg/m3 (range 0.1–1.3. The overall prevalence of PTB was 9.5 % (n = 34. High cumulative respirable silica dust category showed a statistically significant association with PTB (OR = 6.4 (95 % CI 1. 8–23 and a significant trend of increasing disease prevalence with increasing cumulative respirable silica dust categories was observed (ptrend < 0.01. Smoking showed a statistically significant association with PTB with OR = 4.3 (95 % CI 1.9–9.9. Conclusions Our results demonstrate the association of increased risk for certified active TB with cumulative respirable dust in a dose related manner among this sample of copper miners. There is need to intensify dust control measures and incorporate anti-smoking interventions into TB prevention and control programmes in the mines.

  2. Formation of copper-indium-selenide and/or copper-indium-gallium-selenide films from indium selenide and copper selenide precursors

    Science.gov (United States)

    Curtis, Calvin J [Lakewood, CO; Miedaner, Alexander [Boulder, CO; Van Hest, Maikel [Lakewood, CO; Ginley, David S [Evergreen, CO; Nekuda, Jennifer A [Lakewood, CO

    2011-11-15

    Liquid-based indium selenide and copper selenide precursors, including copper-organoselenides, particulate copper selenide suspensions, copper selenide ethylene diamine in liquid solvent, nanoparticulate indium selenide suspensions, and indium selenide ethylene diamine coordination compounds in solvent, are used to form crystalline copper-indium-selenide, and/or copper indium gallium selenide films (66) on substrates (52).

  3. Use of copper radioisotopes in investigating disorders of copper metabolism

    International Nuclear Information System (INIS)

    Camakaris, J.; Voskoboinik, I.; Brooks, H.; Greenough, M.; Smith, S.; Mercer, J.

    1998-01-01

    Full text: Copper is an essential trace element for life as a number of vital enzymes require it. Copper deficiency can lead to neurological disorders, osteoporosis and weakening of arteries. However Cu is also highly toxic and homeostatic mechanisms have evolved to maintain Cu at levels which satisfy requirements but do not cause toxicity. Toxicity is mediated by the oxidative capacity of Cu and its ability to generate toxic free radicals. There are several acquired and inherited diseases due to either Cu toxicity or Cu deficiency. The study of these diseases facilitates identification of genes and proteins involved in copper homeostasis, and this in turn will provide rational therapeutic approaches. Our studies have focused on Menkes disease in humans which is an inherited and usually lethal copper deficiency. Using copper radioisotopes 64 Cu (t 1/2 = 12.8 hr) and 67 Cu (t 1/2 = 61 hr) we have studied the protein which is mutated in Menkes disease. This is a transmembrane copper pump which is responsible for absorption of copper into the body and also functions to pump out excess Cu from cells when Cu is elevated. It is therefore a vital component of normal Cu homeostasis. We have provided the first biochemical evidence that the Menkes protein functions as a P-type ATPase Cu pump (Voskoboinik et al., FEBS Letters, in press) and these data will be discussed. The assay involved pumping of radiocopper into purified membrane vesicles. Furthermore we have transfected normal and mutant Menkes genes into cells and are carrying out structure-function studies. We are also studying the role of amyloid precursor protein (APP) as a Cu transport protein in order to determine how Cu regulates this protein and its cleavage products. These studies will provide vital information on the relationship between Cu and APP and processes which lead to Alzheimers disease

  4. Trace metals in urban road dust

    International Nuclear Information System (INIS)

    Randazzo, Loredana Antonella; Dongarra, Gaetano; Manno, Emanuela; Varrica, Daniela

    2006-01-01

    Heavy metals associated with urban road dust is a matter for concern as they may have serious effects on biological systems. The bioavailability and potential toxicity of metals bound to urban dust is related to the specific chemical form of the element. In the present article are reported the determinations and chemical speciation of As, Ba, Cr, Cu, Mo, Ni, Pb and Zn in six samples of road dust collected within the urban centre and the outskirts of Palermo [it

  5. Cylindrical dust acoustic waves with transverse perturbation

    International Nuclear Information System (INIS)

    Xue Jukui

    2003-01-01

    The nonlinear dust acoustic waves in dusty plasmas with the combined effects of bounded cylindrical geometry and the transverse perturbation are studied. Using the perturbation method, a cylindrical Kadomtsev-Petviashvili (CKP) equation that describes the dust acoustic waves is deduced for the first time. A particular solution of this CKP equation is also obtained. It is shown that the dust acoustic solitary waves can exist in the CKP equation

  6. The control and prevention of dust explosions

    Energy Technology Data Exchange (ETDEWEB)

    1982-01-01

    Papers presented discussed: explosion characteristics and hybrid mixtures explosion characteristics and influencing factors, propagation of dust explosions in ducts, prevention of dust explosions, desensitization, explosion-proof type of construction, explosion pressure relief, optical flame barriers, slide-valves for explosion protection, Ventex explosion barrier valves, grinding and mixing plants, spray driers, dust explosions in silos, and explosion-proof bucket elevators. One paper has been abstracted separately.

  7. Sulphation reactions of oxidic dust particles in waste heat boiler environment. Literature review

    Energy Technology Data Exchange (ETDEWEB)

    Ranki, T.

    1999-09-01

    Sulphation of metal oxides has an important role in many industrial processes. In different applications sulphation reactions have different aims and characteristics. In the flash smelting process sulphation of oxidic flue dust is a spontaneous and inevitable phenomena, which takes place in the waste heat boiler (WHB) when cooling down hot dust laden off-gases from sulphide smelters. Oxidic dust particles (size 0 - 50 {mu}m) react with O{sub 2} and SO{sub 2} or SO{sub 3} in a certain temperature range (500 - 800 deg C). Sulphation reactions are highly exothermic releasing large amount of heat, which affects the gas cooling and thermal performance of the boiler. Thermodynamics and kinetics of the system have to be known to improve the process and WHB operation. The rate of sulphation is affected by the prevailing conditions (temperature, gas composition) and particle size and microstructure (porosity, surface area). Some metal oxides (CuO) can react readily with SO{sub 2} and O{sub 2} and act as self-catalysts, but others (NiO) require the presence of an external catalyst to enhance the SO{sub 3} formation and sulphation to proceed. Some oxides (NiO) sulphate directly, some (CuO) may form first intermediate phases (basic sulphates) depending on the reaction conditions. Thus, the reaction mechanisms are very complex. The aim of this report was to search information about the factors affecting the dust sulphation reactions and suggested reaction mechanisms and kinetics. Many investigators have studied sulphation thermodynamics and reaction kinetics and mechanisms of macroscopical metal oxide pieces, but only few articles have been published about sulphation of microscopical particles, like dust. All the found microscale studies dealt with sulphation reactions of calcium oxide, which is not present in the flash smelting process, but used as an SO{sub 2} absorbent in the combustion processes. However, also these investigations may give some hints about the sulphation

  8. Dust control at Yucca Mountain project

    International Nuclear Information System (INIS)

    Kissell, F.; Jurani, R.; Dresel, R.; Reaux, C.

    1999-01-01

    This report describes actions taken to control silica dust at the Yucca Mountain Exploratory Studies Facility, a tunnel located in Southern Nevada that is part of a scientific program to determine site suitability for a potential nuclear waste repository. The rock is a volcanic tuff containing significant percentages of both quartz and cristobalite. Water use for dust control was limited because of scientific test requirements, and this limitation made dust control a difficult task. Results are reported for two drifts, called the Main Loop Drift and the Cross Drift. In the Main Loop Drift, dust surveys and tracer gas tests indicated that air leakage from the TBM head, the primary ventilation duct, and movement of the conveyor belt were all significant sources of dust. Conventional dust control approaches yielded no significant reductions in dust levels. A novel alternative was to install an air cleaning station on a rear deck of the TBM trailing gear. It filtered dust from the contaminated intake air and discharged clean air towards the front of the TBM. The practical effect was to produce dust levels below the exposure limit for all TBM locations except close to the head. In the Cross Drift, better ventilation and an extra set of dust seals on the TBM served to cut down the leakage of dust from the TBM cutter head. However, the conveyor belt was much dustier than the belt in the main loop drift. The problem originated with dirt on the bottom of the belt return side and much spillage from the belt top side. Achieving lower dust levels in hard rock tunneling operations will require new approaches as well as a more meticulous application of existing technology. Planning for dust control will require specific means to deal with dust that leaks from the TBM head, dust that originates with leaky ventilation systems, and dust that comes from conveyor belts. Also, the application of water could be more efficient if automatic controls were used to adjust the water flow

  9. Beryllium dust generation resulting from plasma bombardment

    International Nuclear Information System (INIS)

    Doerner, R.; Mays, C.

    1997-01-01

    The beryllium dust resulting from erosion of beryllium samples subjected to plasma bombardment has been measured in PISCES-B. Loose surface dust was found to be uniformly distributed throughout the device and accounts for 3% of the eroded material. A size distribution measurement of the loose surface dust shows an increasing number of particles with decreasing diameter. Beryllium coatings on surfaces with a line of sight view of the target interaction region account for an additional 33% of the eroded beryllium material. Flaking of these surface layers is observed and is thought to play a significant role in dust generation inside the vacuum vessel. (orig.)

  10. Control of dust production in ITER

    International Nuclear Information System (INIS)

    Rodriguez-Rodrigo, L.; Ciattaglia, S.; Elbez-Uzan, J.

    2006-01-01

    In the last years dust has been observed in a number of fusion devices and is being studied more in detail for understanding in particular the physical phenomena related to its formation, its composition, physical and chemical characteristics, and the amount of produced dust. The extrapolation of dust formation to ITER predicts (with large error bars), a large mass of dust production with a scattered size distribution. To evaluate the impact of dust on safety, assumptions have also been made on radionuclide inventory, and mobility in off-normal events, as well as any postulated contributions the dust may make to effluents or accidental releases. Solid activation products in structures are generally not readily mobilisable in incidental and accidental situations, so that activated dust, tritium and activated corrosions products are the important in-vessel source terms in postulated scenarios that assume a mobilisation and release of some fraction of this inventory. Such a release would require the simultaneous leak or bypass of several robust confinement barriers. Further concerns for dust may be the potential for chemical reactions between dust and coolant in the event of an in-vessel leak, and the theoretical possibility of a dust explosion, either of which could in principle cause a pressure rise that challenges one or more of the confinement barriers. Although these hazards can - and will - be controlled by other measures in the ITER design, application of the principle of Defence in Depth dictates that the dust inventory should also be minimised and controlled to prevent the potential hazard. A well-coordinated R-and-D programme is required to support this dust production control. This document provides from the safety point of view, an overview of existing data given in '' Dossier d'Options de Surete '', the first safety report presented in 2001 to the French Safety Authorities, and ITER documents; it also gathers information on status of studies on activated

  11. NID Copper Sample Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Kouzes, Richard T.; Zhu, Zihua

    2011-02-01

    The current focal point of the nuclear physics program at PNNL is the MAJORANA DEMONSTRATOR, and the follow-on Tonne-Scale experiment, a large array of ultra-low background high-purity germanium detectors, enriched in 76Ge, designed to search for zero-neutrino double-beta decay (0νββ). This experiment requires the use of germanium isotopically enriched in 76Ge. The DEMONSTRATOR will utilize 76Ge from Russia, but for the Tonne-Scale experiment it is hoped that an alternate technology under development at Nonlinear Ion Dynamics (NID) will be a viable, US-based, lower-cost source of separated material. Samples of separated material from NID require analysis to determine the isotopic distribution and impurities. The MAJORANA DEMONSTRATOR is a DOE and NSF funded project with a major science impact. DOE is funding NID through an SBIR grant for development of their separation technology for application to the Tonne-Scale experiment. The Environmental Molecular Sciences facility (EMSL), a DOE user facility at PNNL, has the required mass spectroscopy instruments for making these isotopic measurements that are essential to the quality assurance for the MAJORANA DEMONSTRATOR and for the development of the future separation technology required for the Tonne-Scale experiment. A sample of isotopically separated copper was provided by NID to PNNL for isotopic analysis as a test of the NID technology. The results of that analysis are reported here.

  12. NID Copper Sample Analysis

    International Nuclear Information System (INIS)

    Kouzes, Richard T.; Zhu, Zihua

    2011-01-01

    The current focal point of the nuclear physics program at PNNL is the MAJORANA DEMONSTRATOR, and the follow-on Tonne-Scale experiment, a large array of ultra-low background high-purity germanium detectors, enriched in 76 Ge, designed to search for zero-neutrino double-beta decay (0νββ). This experiment requires the use of germanium isotopically enriched in 76 Ge. The DEMONSTRATOR will utilize 76 Ge from Russia, but for the Tonne-Scale experiment it is hoped that an alternate technology under development at Nonlinear Ion Dynamics (NID) will be a viable, US-based, lower-cost source of separated material. Samples of separated material from NID require analysis to determine the isotopic distribution and impurities. The MAJORANA DEMONSTRATOR is a DOE and NSF funded project with a major science impact. DOE is funding NID through an SBIR grant for development of their separation technology for application to the Tonne-Scale experiment. The Environmental Molecular Sciences facility (EMSL), a DOE user facility at PNNL, has the required mass spectroscopy instruments for making these isotopic measurements that are essential to the quality assurance for the MAJORANA DEMONSTRATOR and for the development of the future separation technology required for the Tonne-Scale experiment. A sample of isotopically separated copper was provided by NID to PNNL for isotopic analysis as a test of the NID technology. The results of that analysis are reported here.

  13. Improving Beneficiation of Copper and Iron from Copper Slag by Modifying the Molten Copper Slag

    Directory of Open Access Journals (Sweden)

    Zhengqi Guo

    2016-04-01

    Full Text Available In the paper, a new technology was developed to improve the beneficiation of copper and iron components from copper slag, by modifying the molten slag to promote the mineralization of valuable minerals and to induce the growth of mineral grains. Various parameters, including binary basicity, dosage of compound additive, modification temperature, cooling rate and the end point temperature of slow cooling were investigated. Meanwhile, optical microscope, scanning electron microscope and energy dispersive spectrometer (SEM-EDS was employed to determine the mineralogy of the modified and unmodified slag, as well as to reveal the mechanisms of enhancing beneficiation. The results show that under the proper conditions, the copper grade of rougher copper concentrate was increased from 6.43% to 11.04%, iron recovery of magnetic separation was increased significantly from 32.40% to 63.26%, and other evaluation indexes were changed slightly, in comparison with unmodified copper slag. Moreover, matte and magnetite grains in the modified slag aggregated together and grew obviously to the mean size of over 50 μm, resulting in an improvement of beneficiation of copper and iron.

  14. Integrative Analysis of Desert Dust Size and Abundance Suggests Less Dust Climate Cooling

    Science.gov (United States)

    Kok, Jasper F.; Ridley, David A.; Zhou, Qing; Miller, Ron L.; Zhao, Chun; Heald, Colette L.; Ward, Daniel S.; Albani, Samuel; Haustein, Karsten

    2017-01-01

    Desert dust aerosols affect Earths global energy balance through interactions with radiation, clouds, and ecosystems. But the magnitudes of these effects are so uncertain that it remains unclear whether atmospheric dust has a net warming or cooling effect on global climate. Consequently, it is still uncertain whether large changes in atmospheric dust loading over the past century have slowed or accelerated anthropogenic climate change, and the climate impact of possible future alterations in dust loading is similarly disputed. Here we use an integrative analysis of dust aerosol sizes and abundance to constrain the climatic impact of dust through direct interactions with radiation. Using a combination of observational, experimental, and model data, we find that atmospheric dust is substantially coarser than represented in current climate models. Since coarse dust warms global climate, the dust direct radiative effect (DRE) is likely less cooling than the 0.4 W m superscript 2 estimated by models in a current ensemble. We constrain the dust DRE to -0.20 (-0.48 to +0.20) W m superscript 2, which suggests that the dust DRE produces only about half the cooling that current models estimate, and raises the possibility that dust DRE is actually net warming the planet.

  15. Carbohydrate and protein contents of grain dusts in relation to dust morphology.

    Science.gov (United States)

    Dashek, W V; Olenchock, S A; Mayfield, J E; Wirtz, G H; Wolz, D E; Young, C A

    1986-01-01

    Grain dusts contain a variety of materials which are potentially hazardous to the health of workers in the grain industry. Because the characterization of grain dusts is incomplete, we are defining the botanical, chemical, and microbial contents of several grain dusts collected from grain elevators in the Duluth-Superior regions of the U.S. Here, we report certain of the carbohydrate and protein contents of dusts in relation to dust morphology. Examination of the gross morphologies of the dusts revealed that, except for corn, each dust contained either husk or pericarp (seed coat in the case of flax) fragments in addition to respirable particles. When viewed with the light microscope, the fragments appeared as elongated, pointed structures. The possibility that certain of the fragments within corn, settled, and spring wheat were derived from cell walls was suggested by the detection of pentoses following colorimetric assay of neutralized 2 N trifluoroacetic acid hydrolyzates of these dusts. The presence of pentoses together with the occurrence of proteins within water washings of grain dusts suggests that glycoproteins may be present within the dusts. With scanning electron microscopy, each dust was found to consist of a distinct assortment of particles in addition to respirable particles. Small husk fragments and "trichome-like" objects were common to all but corn dust. Images FIGURE 4. FIGURE 5. PMID:3709476

  16. Renal cortex copper concentration in acute copper poisoning in calves

    Directory of Open Access Journals (Sweden)

    Luis E. Fazzio

    2012-01-01

    Full Text Available The aim of this study was to estimate the diagnostic value of renal cortex copper (Cu concentration in clinical cases of acute copper poisoning (ACP. A total of 97 calves that died due to subcutaneous copper administration were compiled in eleven farms. At least, one necropsy was conducted on each farm and samples for complementary analysis were taken. The degree of autolysis in each necropsy was evaluated. The cases appeared on extensive grazing calf breeding and intensive feedlot farms, in calves of 60 to 200 kg body weight. Mortality varied from 0.86 to 6.96 %, on the farms studied. The first succumbed calf was found on the farms between 6 and 72 hours after the susbcutaneous Cu administration. As discrepancies regarding the reference value arose, the local value (19.9 parts per million was used, confirming the diagnosis of acute copper poisoning in 93% of the analyzed kidney samples. These results confirm the value of analysis of the cortical kidney Cu concentration for the diagnosis of acute copper poisoning.

  17. The Electric Environment of Martian Dust Devils

    Science.gov (United States)

    Barth, E. L.; Farrell, W. M.; Rafkin, S. C.

    2017-12-01

    While Martian dust devils have been monitored through decades of observations, we have yet to study their possible electrical effects from in situ instrumentation. However, evidence for the existence of active electrodynamic processes on Mars is provided by laboratory studies of analog material and field campaigns of dust devils on Earth. We have enabled our Mars regional scale atmospheric model (MRAMS) to estimate an upper limit on electric fields generated through dust devil circulations by including charged particles as defined from the Macroscopic Triboelectric Simulation (MTS) code. MRAMS is used to investigate the complex physics of regional, mesoscale, and microscale atmospheric phenomena on Mars; it is a 3-D, nonhydrostatic model, which permits the simulation of atmospheric flows with large vertical accelerations, such as dust devils. MTS is a 3-D particle code which quantifies charging associated with swirling, mixing dust grains; grains of pre-defined sizes and compositions are placed in a simulation box and allowed to move under the influence of winds and gravity. Our MRAMS grid cell size makes our results most applicable to dust devils of a few hundred meters in diameter. We have run a number of simulations to understand the sensitivity of the electric field strength to the particle size and abundance and the amount of charge on each dust grain. We find that Efields can indeed develop in Martian dust convective features via dust grain filtration effects. The overall value of these E-fields is strongly dependent upon dust grain size, dust load, and lifting efficiency, and field strengths can range from 100s of mV/m to 10s of kV/m.

  18. Investigation of copper nuclei

    International Nuclear Information System (INIS)

    Delfini, M.G.

    1983-01-01

    An extensive study has been performed on copper isotopes in the mass region A=63-66. The results of a precise measurement are presented on the properties of levels of 64 Cu and 66 Cu. They were obtained by bombarding the 63 Cu and 65 Cu nuclei with neutrons. The gamma spectra collected after capture of thermal, 2-keV, 24-keV neutrons have been analysed and combined to give a rather extensive set of precise level energies and gamma transition strengths. From the angular distribution of the gamma rays it is possible to obtain information concerning the angular momentum J of several low-lying states. The level schemes derived from such measurements have been used as a test for calculations in the framework of the shell model. The spectral distributions of eigenstates in 64 Cu for different configuration spaces are presented and discussed. In this study the relative importance of configurations with n holes in the 1f7/2 shell with n up to 16, are investigated. It is found that the results strongly depend on the values of the single-particle energies. The results of the spectral-distribution method were utilized for shell-model calculations. From the information obtained from the spectral analysis it was decided to adopt a configuration space which includes up to one hole in the 1f7/2 shell and up to two particles in the 1g9/2 shell. Further, restrictions on seniority and on the coupling of the two particles in the 1g9/2 orbit have been applied and their effects have been studied. It is found that the calculated excitation energies reproduce the measured values in a satisfactory way, but that some of the electromagnetic properties are less well in agreement with experimental data. (Auth.)

  19. LIGNOCELLULOSE NANOCOMPOSITE CONTAINING COPPER SULFIDE

    Directory of Open Access Journals (Sweden)

    Sanchi Nenkova

    2011-04-01

    Full Text Available Copper sulfide-containing lignocellulose nanocomposites with improved electroconductivity were obtained. Two methods for preparing the copper sulfide lignocellulose nanocomposites were developed. An optimization of the parameters for obtaining of the nanocomposites with respect to obtaining improved electroconductivity, economy, and lower quantities and concentration of copper and sulfur ions in waste waters was conducted. The mechanisms and schemes of delaying and subsequent connection of copper sulfides in the lignocellulosic matrix were investigated. The modification with a system of 2 components: cupric sulfate pentahydrate (CuSO4. 5H2O and sodium thiosulfate pentahydrate (Na2S2O3.5H2O for wood fibers is preferred. Optimal parameters were established for the process: 40 % of the reduction system; hydromodule M=1:6; and ratio of cupric sulfate pentahydrate:sodium thiosulfate pentahydrate = 1:2. The coordinative connection of copper ions with oxygen atoms of cellulose OH groups and aromatic nucleus in lignin macromolecule was observed.

  20. The dust acoustic wave in a bounded dusty plasma with strong electrostatic interactions between dust grains

    International Nuclear Information System (INIS)

    Shukla, Nitin; Shukla, P.K.

    2011-01-01

    The dispersion relation for the dust acoustic wave (DAW) in an unmagnetized dusty plasma cylindrical waveguide is derived, accounting for strong electrostatic interactions between charged dust grains. It is found that the boundary effect limits the radial extent of the DAW. The present result should be helpful for understanding the frequency spectrum of the DAW in a dusty plasma waveguide with strongly coupled charged dust grains. - Highlights: → We study the dust acoustic wave (DAW) in a bounded plasma. → We account for interactions between dust grains. → The boundary effect limits the radial extent of the DAW.

  1. Radioactive dust in the air

    Energy Technology Data Exchange (ETDEWEB)

    Yano, N

    1956-01-01

    An electric precipitator is used to collect dust in the air because its collection efficiency for radioactive substances is up to 10 times that of the impactor of filter-paper types. About 10 cu m of air is filtered during 5 hours, and the trapped dust is measured more than 24 hours after collection to avoid the influence of naturally active substances. The average radioactivity of the air is approximately 10/sup -16/ c/cc. During the period of observation 4 peaks occurred. The dates and maximum levels of artificial activity, respectively, are November 4 to 10, 1954, 1.2 x 10/sup -7/ uc/l; April 11 to 13, 1955, 4.3 x 10/sup -8/ uc/l; November 25 to 28, 1955, maximum unknown; and March 22 to 25, 1956, 1.- x 10/sup -7/ uc/l. The presumed dates and places of detonation corresponding to the peaks are October 31, 1954 northwest of Japan; March 29, 1955, Nevada, US; November 22, 1955, near L. Baikal, USSR; and March 13 to 15, 1956 unknown.

  2. Current trends in copper theft prevention

    Energy Technology Data Exchange (ETDEWEB)

    Mastrofrancesco, A. [Electrical Safety Authority, ON (Canada)

    2009-07-01

    Copper is used in electrical wiring, water and gas piping, currency, and in household items. An increase in the price and demand for copper has made copper theft a profitable venture for some thieves. Copper consumed in North America is typically supplied by recycling. Scrap dealers may pay near-market prices for pure copper wires. However, copper theft poses a serious threat to the safety of utility workers and the public. Power outages caused by copper theft are now affecting grid reliability. This paper examined technologies and techniques used to prevent copper theft as part of a security strategy for utilities. Attempts to steal copper can leave utility substations unsecured and accessible to children. The theft of neutral grounds will cause the local distribution company (LDC) to malfunction and may cause power surges in homes as well as appliance fires. Utilities are now looking at using a hybrid steel and copper alternative to prevent copper theft. Asset identification techniques are also being used to identify the original owners of the copper and more easily prosecute thieves. Automated monitoring techniques are also being used to increase substation security. Utilities are also partnering with law enforcement agencies and pressuring governments to require scrap dealers to record who they buy from. It was concluded that strategies to prevent copper theft should be considered as part of an overall security strategy for utilities. tabs., figs.

  3. Comet Dust After Deep Impact

    Science.gov (United States)

    Wooden, Diane H.; Harker, David E.; Woodward, Charles E.

    2006-01-01

    When the Deep Impact Mission hit Jupiter Family comet 9P/Tempel 1, an ejecta crater was formed and an pocket of volatile gases and ices from 10-30 m below the surface was exposed (A Hearn et aI. 2005). This resulted in a gas geyser that persisted for a few hours (Sugita et al, 2005). The gas geyser pushed dust grains into the coma (Sugita et a1. 2005), as well as ice grains (Schulz et al. 2006). The smaller of the dust grains were submicron in radii (0-25.3 micron), and were primarily composed of highly refractory minerals including amorphous (non-graphitic) carbon, and silicate minerals including amorphous (disordered) olivine (Fe,Mg)2SiO4 and pyroxene (Fe,Mg)SiO3 and crystalline Mg-rich olivine. The smaller grains moved faster, as expected from the size-dependent velocity law produced by gas-drag on grains. The mineralogy evolved with time: progressively larger grains persisted in the near nuclear region, having been imparted with slower velocities, and the mineralogies of these larger grains appeared simpler and without crystals. The smaller 0.2-0.3 micron grains reached the coma in about 1.5 hours (1 arc sec = 740 km), were more diverse in mineralogy than the larger grains and contained crystals, and appeared to travel through the coma together. No smaller grains appeared at larger coma distances later (with slower velocities), implying that if grain fragmentation occurred, it happened within the gas acceleration zone. These results of the high spatial resolution spectroscopy (GEMINI+Michelle: Harker et 4. 2005, 2006; Subaru+COMICS: Sugita et al. 2005) revealed that the grains released from the interior were different from the nominally active areas of this comet by their: (a) crystalline content, (b) smaller size, (c) more diverse mineralogy. The temporal changes in the spectra, recorded by GEMIM+Michelle every 7 minutes, indicated that the dust mineralogy is inhomogeneous and, unexpectedly, the portion of the size distribution dominated by smaller grains has

  4. The management of house dust mite allergies

    NARCIS (Netherlands)

    Bronswijk, van J.E.M.H.; Schober, G.; Kniest, F.M.

    1990-01-01

    A safe and practical home sanitation procedure for the removal of house dust mites (Dermatophagoides pteronyssinus) and their allergens is described. The severity of mite infestation was assessed with the use of the Acarex test, which measures the concentration of guanine in house dust, and all

  5. A rotating dust cloud in general relativity

    International Nuclear Information System (INIS)

    Bonnor, W.B.

    1977-01-01

    An axially symmetric, stationary exact solution of Einstein's equations for dust is studied. It is asymptotically flat, and represents a rotating dust cloud extending tenuously to infinity, containing a singularity at the centre. An explanation is given as to why there exists no corresponding solution in Newtonian theory. (author)

  6. Dust coagulation in protoplanetary disks : porosity matters

    NARCIS (Netherlands)

    Ormel, C. W.; Spaans, M.; Tielens, A. G. G. M.

    Context. Sticking of colliding dust particles through van der Waals forces is the first stage in the grain growth process in protoplanetary disks, eventually leading to the formation of comets, asteroids and planets. A key aspect of the collisional evolution is the coupling between dust and gas

  7. Correlation between Yellow Dust and Radioactivity

    Energy Technology Data Exchange (ETDEWEB)

    AIZaabia, Mouza A [Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of); Kim, Byoung-Jik [Korea Institute of Nuclear Safety, Daejeon (Korea, Republic of)

    2015-10-15

    In East Asia, yellow dust or Asian Dust (AD) outbreaks are among the largest contributors of wind-blown dust that carry natural and anthropogenic radionuclides and subsequently alter their concentration and distribution throughout the environment. Although the Korean Peninsula has been experiencing AD events since ancient times, the research has tended to focus on the transport routes and characteristics of AD, rather than on its impact on radionuclide activity levels. This paper examines the relationship between radionuclide concentration in the air and the frequency of dusty days in South Korea during AD intrusion events. It also investigates whether increased radionuclide concentration is a function of either more mass or more dust contamination. In this study, significant linear correlations of gamma-emitting radionuclides were found with mass of dust and occurrence frequency of AD. Regardless of the source origin of the dust, {sup 137}Cs and {sup 7}Be concentration primarily depended on dust mass in the filter. Nonetheless, the correlations were greatly distorted in 2011 and in the spring season, particularly the correlations with AD days that were far below that of the correlations obtained for the whole study period. A possible explanation of these conflicting results is that a change in the dust source could appreciably alter the concentration, deposition, and distribution of airborne radionuclides.

  8. Correlation between Yellow Dust and Radioactivity

    International Nuclear Information System (INIS)

    AIZaabia, Mouza A; Kim, Byoung-Jik

    2015-01-01

    In East Asia, yellow dust or Asian Dust (AD) outbreaks are among the largest contributors of wind-blown dust that carry natural and anthropogenic radionuclides and subsequently alter their concentration and distribution throughout the environment. Although the Korean Peninsula has been experiencing AD events since ancient times, the research has tended to focus on the transport routes and characteristics of AD, rather than on its impact on radionuclide activity levels. This paper examines the relationship between radionuclide concentration in the air and the frequency of dusty days in South Korea during AD intrusion events. It also investigates whether increased radionuclide concentration is a function of either more mass or more dust contamination. In this study, significant linear correlations of gamma-emitting radionuclides were found with mass of dust and occurrence frequency of AD. Regardless of the source origin of the dust, 137 Cs and 7 Be concentration primarily depended on dust mass in the filter. Nonetheless, the correlations were greatly distorted in 2011 and in the spring season, particularly the correlations with AD days that were far below that of the correlations obtained for the whole study period. A possible explanation of these conflicting results is that a change in the dust source could appreciably alter the concentration, deposition, and distribution of airborne radionuclides

  9. Measurement of nicotine in household dust

    International Nuclear Information System (INIS)

    Kim, Sungroul; Aung, Ther; Berkeley, Emily; Diette, Gregory B.; Breysse, Patrick N.

    2008-01-01

    An analytical method of measuring nicotine in house dust was optimized and associations among three secondhand smoking exposure markers were evaluated, i.e., nicotine concentrations of both house dust and indoor air, and the self-reported number of cigarettes smoked daily in a household. We obtained seven house dust samples from self-reported nonsmoking homes and 30 samples from smoking homes along with the information on indoor air nicotine concentrations and the number of cigarettes smoked daily from an asthma cohort study conducted by the Johns Hopkins Center for Childhood Asthma in the Urban Environment. House dust nicotine was analyzed by isotope dilution gas chromatography-mass spectrometry (GC/MS). Using our optimized method, the median concentration of nicotine in the dust of self-reported nonsmoking homes was 11.7 ng/mg while that of smoking homes was 43.4 ng/mg. We found a substantially positive association (r=0.67, P<0.0001) between house dust nicotine concentrations and the numbers of cigarettes smoked daily. Optimized analytical methods showed a feasibility to detect nicotine in house dust. Our results indicated that the measurement of nicotine in house dust can be used potentially as a marker of longer term SHS exposure

  10. 30 CFR 56.9315 - Dust control.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Dust control. 56.9315 Section 56.9315 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND... control. Dust shall be controlled at muck piles, material transfer points, crushers, and on haulage roads...

  11. Role of dust in H II regions

    International Nuclear Information System (INIS)

    Sarazin, C.L.

    1975-01-01

    The purpose of this dissertation is to determine quantitatively the effects of U.V. absorbing dust on H II regions, and compare these effects with observations. Many observations indicate that dust grains are present within H II regions. An analytic theory is presented which describes all three of the effects of dust in H II regions. Although this model is relatively crude, it is useful in determining the approximate size of the modifications due to dust. In order to explore this problem more carefully, detailed numerical models of H II regions with dust were constructed. The ionization and thermal structure of these model H II regions is discussed. The observational consequences of the presence of dust are explored; the optical line intensities, radio continuum and line fluxes, and infrared emission of model H II regions with dust are given. These numerical models are compared with observations of diffuse nebulae. The optical line ratios are compared to several nearby bright H II regions, and it is found that the dust models may explain several anomalies in their spectrum

  12. The Continuous Monitoring of Desert Dust using an Infrared-based Dust Detection and Retrieval Method

    Science.gov (United States)

    Duda, David P.; Minnis, Patrick; Trepte, Qing; Sun-Mack, Sunny

    2006-01-01

    Airborne dust and sand are significant aerosol sources that can impact the atmospheric and surface radiation budgets. Because airborne dust affects visibility and air quality, it is desirable to monitor the location and concentrations of this aerosol for transportation and public health. Although aerosol retrievals have been derived for many years using visible and near-infrared reflectance measurements from satellites, the detection and quantification of dust from these channels is problematic over bright surfaces, or when dust concentrations are large. In addition, aerosol retrievals from polar orbiting satellites lack the ability to monitor the progression and sources of dust storms. As a complement to current aerosol dust retrieval algorithms, multi-spectral thermal infrared (8-12 micron) data from the Moderate Resolution Imaging Spectroradiometer (MODIS) and the Meteosat-8 Spinning Enhanced Visible and Infrared Imager (SEVIRI) are used in the development of a prototype dust detection method and dust property retrieval that can monitor the progress of Saharan dust fields continuously, both night and day. The dust detection method is incorporated into the processing of CERES (Clouds and the Earth s Radiant Energy System) aerosol retrievals to produce dust property retrievals. Both MODIS (from Terra and Aqua) and SEVERI data are used to develop the method.

  13. Dust plume formation in the free troposphere and aerosol size distribution during the Saharan Mineral Dust Experiment in North Africa

    KAUST Repository

    Khan, Basit Ali; Stenchikov, Georgiy L.; Weinzierl, Bernadett; Kalenderski, Stoitchko; Osipov, Sergey

    2015-01-01

    , this study combines model simulations and dust observations collected during the first stage of the Saharan Mineral Dust Experiment (SAMUM-I), which sampled dust events that extended from Morocco to Portugal, and investigated the spatial distribution

  14. Extracting lunar dust parameters from image charge signals produced by the Lunar Dust Experiment

    Science.gov (United States)

    Stanley, J.; Kempf, S.; Horanyi, M.; Szalay, J.

    2015-12-01

    The Lunar Dust Experiment (LDEX) onboard the Lunar Atmosphere and Dust Environment Explorer (LADEE) is an impact ionization dust detector used to characterize the lunar dust exosphere generated by the impacts of large interplanetary particles and meteor streams (Horanyi et al., 2015). In addition to the mass and speed of these lofted particles, LDEX is sensitive to their charge. The resulting signatures of impact events therefore provide valuable information about not only the ambient plasma environment, but also the speed vectors of these dust grains. Here, impact events produced from LDEX's calibration at the Dust Accelerator Laboratory are analyzed using an image charge model derived from the electrostatic simulation program, Coulomb. We show that parameters such as dust grain speed, size, charge, and position of entry into LDEX can be recovered and applied to data collected during LADEE's seven-month mission.

  15. Heating of Porous Icy Dust Aggregates

    Energy Technology Data Exchange (ETDEWEB)

    Sirono, Sin-iti [Earth and Environmental Sciences, Nagoya University, Tikusa-ku, Furo-cho, Nagoya 464-8601 (Japan)

    2017-06-10

    At the beginning of planetary formation, highly porous dust aggregates are formed through coagulation of dust grains. Outside the snowline, the main component of an aggregate is H{sub 2}O ice. Because H{sub 2}O ice is formed in amorphous form, its thermal conductivity is extremely small. Therefore, the thermal conductivity of an icy dust aggregate is low. There is a possibility of heating inside an aggregate owing to the decay of radionuclides. It is shown that the temperature increases substantially inside an aggregate, leading to crystallization of amorphous ice. During the crystallization, the temperature further increases sufficiently to continue sintering. The mechanical properties of icy dust aggregates change, and the collisional evolution of dust aggregates is affected by the sintering.

  16. The relaxation of plasmas with dust particles

    International Nuclear Information System (INIS)

    Chutov, Yu.I.; Kravchenko, A.Yu.; Schram, P.P.J.M.

    1997-01-01

    Various parameters of relaxing plasmas with dust particles including the electron and ion energy distributions function are numerically simulated at various parameters of the dust particles using the PIC method and taking into account the dynamics of the dust particle charge without the assumption about the equilibrium of electrons and ions. Coulomb collisions are taken into account in the framework of the method of stochastic differential equations. The relaxation of bounded plasma clouds expanding into a vacuum as well as the relaxation of a uniform plasma, in which dust particles appear at some initial time, are investigated. The obtained results show that the relaxation of plasmas can be accompanied by a deviation of the ion distribution function from equilibrium as well as a change of the mean energy of electrons and ions because of the dependence of the collection of electrons and ions by dust particles on their energy. (author)

  17. Recycling of steelmaking dusts: The Radust concept

    Directory of Open Access Journals (Sweden)

    Jalkanen H.

    2005-01-01

    Full Text Available Recycling of dusts and other wastes of steelmaking is becoming to a necessity of two reasons: due to high contents of iron oxides dusts are valuable raw material for steelmaking and tightening environmental legislation makes the landfill disposal of wastes more expensive. Fine dust fractions from various stages of steelmaking route contain besides iron and carbon heavy metals especially zinc and lead and heavy hydrocarbons that are acceptable neither for landfill disposal nor for recycling back to processes without any spe4cial treatments. Some theoretical and practical aspects concerning high temperature treatments of steelmaking dusts for removal of hazardous components and production of clean high iron raw material for recycling is discussed in this paper. The Radust technology developed at Koverhar steelwork in Finland for treatment of the most problematic fine fractions of blast furnace and oxygen converter dusts is shortly presented and discussed.

  18. Mechanochemical reduction of copper sulfide

    DEFF Research Database (Denmark)

    Balaz, P.; Takacs, L.; Jiang, Jianzhong

    2002-01-01

    The mechanochemical reduction of copper sulfide with iron was induced in a Fritsch P-6 planetary mill, using WC vial filled with argon and WC balls. Samples milled for specific intervals were analyzed by XRD and Mossbauer spectroscopy. Most of the reaction takes place during the first 10 min...... of milling and only FeS and Cu are found after 60 min. The main chemical process is accompanied by phase transformations of the sulfide phases as a result of milling. Djurleite partially transformed to chalcocite and a tetragonal copper sulfide phase before reduction. The cubic modification of FeS was formed...... first, transforming to hexagonal during the later stages of the process. The formation of off-stoichiometric phases and the release of some elemental sulfur by copper sulfide are also probable....

  19. Laser sintering of copper nanoparticles

    International Nuclear Information System (INIS)

    Zenou, Michael; Saar, Amir; Ermak, Oleg; Kotler, Zvi

    2014-01-01

    Copper nanoparticle (NP) inks serve as an attractive potential replacement to silver NP inks in functional printing applications. However their tendency to rapidly oxidize has so far limited their wider use. In this work we have studied the conditions for laser sintering of Cu-NP inks in ambient conditions while avoiding oxidation. We have determined the regime for stable, low-resistivity copper (< ×3 bulk resistivity value) generation in terms of laser irradiance and exposure duration and have indicated the limits on fast processing. The role of pre-drying conditions on sintering outcome has also been studied. A method, based on spectral reflectivity measurements, was used for non-contact monitoring of the sintering process evolution. It also indicates preferred spectral regions for sintering. Finally, we illustrated how selective laser sintering can generate high-quality, fine line (<5 µm wide) and dense copper circuits. (paper)

  20. Copper tolerance of Trichoderma species

    Directory of Open Access Journals (Sweden)

    Jovičić-Petrović Jelena

    2014-01-01

    Full Text Available Some Trichoderma strains can persist in ecosystems with high concentrations of heavy metals. The aim of this research was to examine the variability of Trichoderma strains isolated from different ecosystems, based on their morphological properties and restriction analysis of ITS fragments. The fungal growth was tested on potato dextrose agar, amended with Cu(II concentrations ranging from 0.25 to 10 mmol/l, in order to identify copper-resistant strains. The results indicate that some isolated strains of Trichoderma sp. show tolerance to higher copper concentrations. Further research to examine the ability of copper bioaccumulation by tolerant Trichoderma strains is needed. [Projekat Ministarstva nauke Republike Srbije, br. TR 31080 i br. III 43010

  1. Biliary copper excretion by hepatocyte lysosomes in the rat. Major excretory pathway in experimental copper overload

    International Nuclear Information System (INIS)

    Gross, J.B. Jr.; Myers, B.M.; Kost, L.J.; Kuntz, S.M.; LaRusso, N.F.

    1989-01-01

    We investigated the hypothesis that lysosomes are the main source of biliary copper in conditions of hepatic copper overload. We used a rat model of oral copper loading and studied the relationship between the biliary output of copper and lysosomal hydrolases. Male Sprague-Dawley rats were given tap water with or without 0.125% copper acetate for up to 36 wk. Copper loading produced a 23-fold increase in the hepatic copper concentration and a 30-65% increase in hepatic lysosomal enzyme activity. Acid phosphatase histochemistry showed that copper-loaded livers contained an increased number of hepatocyte lysosomes; increased copper concentration of these organelles was confirmed directly by both x ray microanalysis and tissue fractionation. The copper-loaded rats showed a 16-fold increase in biliary copper output and a 50-300% increase in biliary lysosomal enzyme output. In the basal state, excretory profiles over time were similar for biliary outputs of lysosomal enzymes and copper in the copper-loaded animals but not in controls. After pharmacologic stimulation of lysosomal exocytosis, biliary outputs of copper and lysosomal hydrolases in the copper-loaded animals remained coupled: injection of colchicine or vinblastine produced an acute rise in the biliary output of both lysosomal enzymes and copper to 150-250% of baseline rates. After these same drugs, control animals showed only the expected increase in lysosomal enzyme output without a corresponding increase in copper output. We conclude that the hepatocyte responds to an increased copper load by sequestering excess copper in an increased number of lysosomes that then empty their contents directly into bile. The results provide direct evidence that exocytosis of lysosomal contents into biliary canaliculi is the major mechanism for biliary copper excretion in hepatic copper overload

  2. Figurines in Pietrele: Copper Age ideology

    Directory of Open Access Journals (Sweden)

    Svend Hansen

    2011-12-01

    Full Text Available Major trends in figurine production of the copper age settlement of Pietrele (Romania are discussed. The bone figurines are seen as an ideological innovation of the Early Copper Age system in the Eastern Balkans.

  3. Copper tolerance and virulence in bacteria

    Science.gov (United States)

    Ladomersky, Erik; Petris, Michael J.

    2015-01-01

    Copper (Cu) is an essential trace element for all aerobic organisms. It functions as a cofactor in enzymes that catalyze a wide variety of redox reactions due to its ability to cycle between two oxidation states, Cu(I) and Cu(II). This same redox property of copper has the potential to cause toxicity if copper homeostasis is not maintained. Studies suggest that the toxic properties of copper are harnessed by the innate immune system of the host to kill bacteria. To counter such defenses, bacteria rely on copper tolerance genes for virulence within the host. These discoveries suggest bacterial copper intoxication is a component of host nutritional immunity, thus expanding our knowledge of the roles of copper in biology. This review summarizes our current understanding of copper tolerance in bacteria, and the extent to which these pathways contribute to bacterial virulence within the host. PMID:25652326

  4. Dust storm events over Delhi: verification of dust AOD forecasts with satellite and surface observations

    Science.gov (United States)

    Singh, Aditi; Iyengar, Gopal R.; George, John P.

    2016-05-01

    Thar desert located in northwest part of India is considered as one of the major dust source. Dust storms originate in Thar desert during pre-monsoon season, affects large part of Indo-Gangetic plains. High dust loading causes the deterioration of the ambient air quality and degradation in visibility. Present study focuses on the identification of dust events and verification of the forecast of dust events over Delhi and western part of IG Plains, during the pre-monsoon season of 2015. Three dust events have been identified over Delhi during the study period. For all the selected days, Terra-MODIS AOD at 550 nm are found close to 1.0, while AURA-OMI AI shows high values. Dust AOD forecasts from NCMRWF Unified Model (NCUM) for the three selected dust events are verified against satellite (MODIS) and ground based observations (AERONET). Comparison of observed AODs at 550 nm from MODIS with NCUM predicted AODs reveals that NCUM is able to predict the spatial and temporal distribution of dust AOD, in these cases. Good correlation (~0.67) is obtained between the NCUM predicted dust AODs and location specific observations available from AERONET. Model under-predicted the AODs as compared to the AERONET observations. This may be mainly because the model account for only dust and no anthropogenic activities are considered. The results of the present study emphasize the requirement of more realistic representation of local dust emission in the model both of natural and anthropogenic origin, to improve the forecast of dust from NCUM during the dust events.

  5. Human copper transporter 2 is localized in late endosomes and lysosomes and facilitates cellular copper uptake

    NARCIS (Netherlands)

    Berghe, van den P.V.E; Folmer, D.E.; Malingré, H.E.M.; Beurden, van E.; Klomp, A.E.M.; Sluis, van de B.; Merkx, M.; Berger, R.J.; Klomp, L.W.J.

    2007-01-01

    High-affinity cellular copper uptake is mediated by the CTR (copper transporter) 1 family of proteins. The highly homologous hCTR (human CTR) 2 protein has been identified, but its function in copper uptake is currently unknown. To characterize the role of hCTR2 in copper homoeostasis,

  6. Copper nitrate redispersion to arrive at highly active silica-supported copper catalysts

    NARCIS (Netherlands)

    Munnik, P.|info:eu-repo/dai/nl/328228524; Wolters, M.|info:eu-repo/dai/nl/304829560; Gabrielsson, A.; Pollington, S.D.; Headdock, G.; Bitter, J.H.|info:eu-repo/dai/nl/160581435; de Jongh, P.E.|info:eu-repo/dai/nl/186125372; de Jong, K.P.|info:eu-repo/dai/nl/06885580X

    2011-01-01

    In order to obtain copper catalysts with high dispersions at high copper loadings, the gas flow rate and gas composition was varied during calcination of silica gel impregnated with copper nitrate to a loading of 18 wt % of copper. Analysis by X-ray diffraction (XRD), N2O chemisorption, and

  7. Copper and Anesthesia: Clinical Relevance and Management of Copper Related Disorders

    OpenAIRE

    Langley, Adrian; Dameron, Charles T.

    2013-01-01

    Recent research has implicated abnormal copper homeostasis in the underlying pathophysiology of several clinically important disorders, some of which may be encountered by the anesthetist in daily clinical practice. The purpose of this narrative review is to summarize the physiology and pharmacology of copper, the clinical implications of abnormal copper metabolism, and the subsequent influence of altered copper homeostasis on anesthetic management.

  8. 21 CFR 73.1125 - Potassium sodium copper chloropyhllin (chlorophyllin-copper complex).

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 1 2010-04-01 2010-04-01 false Potassium sodium copper chloropyhllin (chlorophyllin-copper complex). 73.1125 Section 73.1125 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT....1125 Potassium sodium copper chloropyhllin (chlorophyllin-copper complex). (a) Identity. (1) The color...

  9. 21 CFR 73.2125 - Potassium sodium copper chlorophyllin (chlorophyllin-copper complex).

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 1 2010-04-01 2010-04-01 false Potassium sodium copper chlorophyllin (chlorophyllin-copper complex). 73.2125 Section 73.2125 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT... § 73.2125 Potassium sodium copper chlorophyllin (chlorophyllin-copper complex). (a) Identity and...

  10. Dust Evolution in Galaxy Cluster Simulations

    Science.gov (United States)

    Gjergo, Eda; Granato, Gian Luigi; Murante, Giuseppe; Ragone-Figueroa, Cinthia; Tornatore, Luca; Borgani, Stefano

    2018-06-01

    We implement a state-of-the-art treatment of the processes affecting the production and Interstellar Medium (ISM) evolution of carbonaceous and silicate dust grains within SPH simulations. We trace the dust grain size distribution by means of a two-size approximation. We test our method on zoom-in simulations of four massive (M200 ≥ 3 × 1014M⊙) galaxy clusters. We predict that during the early stages of assembly of the cluster at z ≳ 3, where the star formation activity is at its maximum in our simulations, the proto-cluster regions are rich in dusty gas. Compared to the case in which only dust production in stellar ejecta is active, if we include processes occurring in the cold ISM,the dust content is enhanced by a factor 2 - 3. However, the dust properties in this stage turn out to be significantly different from those observationally derived for the average Milky Way dust, and commonly adopted in calculations of dust reprocessing. We show that these differences may have a strong impact on the predicted spectral energy distributions. At low redshift in star forming regions our model reproduces reasonably well the trend of dust abundances over metallicity as observed in local galaxies. However we under-produce by a factor of 2 to 3 the total dust content of clusters estimated observationally at low redshift, z ≲ 0.5 using IRAS, Planck and Herschel satellites data. This discrepancy does not subsist by assuming a lower sputtering efficiency, which erodes dust grains in the hot Intracluster Medium (ICM).

  11. Dust in the Quasar Wind (Artist Concept)

    Science.gov (United States)

    2007-01-01

    Dusty grains -- including tiny specks of the minerals found in the gemstones peridot, sapphires and rubies -- can be seen blowing in the winds of a quasar, or active black hole, in this artist's concept. The quasar is at the center of a distant galaxy. Astronomers using NASA's Spitzer Space Telescope found evidence that such quasar winds might have forged these dusty particles in the very early universe. The findings are another clue in an ongoing cosmic mystery: where did all the dust in our young universe come from? Dust is crucial for efficient star formation as it allows the giant clouds where stars are born to cool quickly and collapse into new stars. Once a star has formed, dust is also needed to make planets and living creatures. Dust has been seen as far back as when the universe was less than a tenth of its current age, but how did it get there? Most dust in our current epoch forms in the winds of evolved stars that did not exist when the universe was young. Theorists had predicted that winds from quasars growing in the centers of distant galaxies might be a source of this dust. While the environment close to a quasar is too hot for large molecules like dust grains to survive, dust has been found in the cooler, outer regions. Astronomers now have evidence that dust is created in these outer winds. Using Spitzer's infrared spectrograph instrument, scientists found a wealth of dust grains in a quasar called PG2112+059 located at the center of a galaxy 8 billion light-years away. The grains - including corundum (sapphires and rubies); forsterite (peridot); and periclase (naturally occurring in marble) - are not typically found in galaxies without quasars, suggesting they might have been freshly formed in the quasar's winds.

  12. High Latitude Dust in the Earth System

    Science.gov (United States)

    Bullard, Joanna E.; Baddock, Matthew; Bradwell, Tom; Crusius, John; Darlington, Eleanor; Gaiero, Diego; Gasso, Santiago; Gisladottir, Gudrun; Hodgkins, Richard; McCulloch, Robert; hide

    2016-01-01

    Natural dust is often associated with hot, subtropical deserts, but significant dust events have been reported from cold, high latitudes. This review synthesizes current understanding of high-latitude (> or = 50degN and > or = 40degS) dust source geography and dynamics and provides a prospectus for future research on the topic. Although the fundamental processes controlling aeolian dust emissions in high latitudes are essentially the same as in temperate regions, there are additional processes specific to or enhanced in cold regions. These include low temperatures, humidity, strong winds, permafrost and niveo-aeolian processes all of which can affect the efficiency of dust emission and distribution of sediments. Dust deposition at high latitudes can provide nutrients to the marine system, specifically by contributing iron to high-nutrient, low-chlorophyll oceans; it also affects ice albedo and melt rates. There have been no attempts to quantify systematically the expanse, characteristics, or dynamics of high-latitude dust sources. To address this, we identify and compare the main sources and drivers of dust emissions in the Northern (Alaska, Canada, Greenland, and Iceland) and Southern (Antarctica, New Zealand, and Patagonia) Hemispheres. The scarcity of year-round observations and limitations of satellite remote sensing data at high latitudes are discussed. It is estimated that under contemporary conditions high-latitude sources cover >500,000 sq km and contribute at least 80-100 Tg/yr1 of dust to the Earth system (approx. 5% of the global dust budget); both are projected to increase under future climate change scenarios.

  13. Refining processes in the copper casting technology

    OpenAIRE

    Rzadkosz, S.; Kranc, M.; Garbacz-Klempka, A.; Kozana, J.; Piękoś, M.

    2015-01-01

    The paper presents the analysis of technology of copper and alloyed copper destined for power engineering casts. The casts quality was assessed based on microstructure, chemical content analysis and strength properties tests. Characteristic deoxidising (Logas, Cup) and modifying (ODM2, Kupmod2) formulas were used for the copper where high electrical conductivity was required. Chosen examples of alloyed copper with varied Cr and Zr content were studied, and the optimal heat treatment parameter...

  14. 21 CFR 184.1261 - Copper sulfate.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Copper sulfate. 184.1261 Section 184.1261 Food and... Substances Affirmed as GRAS § 184.1261 Copper sulfate. (a) Copper sulfate (cupric sulfate, CuSO4·5H2O, CAS... the reaction of sulfuric acid with cupric oxide or with copper metal. (b) The ingredient must be of a...

  15. The Bauschinger Effect in Copper

    DEFF Research Database (Denmark)

    Pedersen, Ole Bøcker; Brown, L .M.; Stobbs, W. M.

    1981-01-01

    A study of the Bauschinger effect in pure copper shows that by comparison with dispersion hardened copper the effect is very small and independent of temperature. This suggests that the obstacles to flow are deformable. A simple composite model based on this principle accounts for the data semi......-quantitatively and also accounts for the stored energy of cold-work. An interesting feature of the model is that it shows very clearly that, although dislocation pile-ups may exist, the flow stress of the composite is entirely due to the resistance to dislocation motion in the tangles of forest dislocations....

  16. Cupriferous peat: embryonic copper ore

    Energy Technology Data Exchange (ETDEWEB)

    Fraser, D C

    1961-07-01

    A Canadian peat was found to contain up to 10% (dry weight) Cu, and a mechanism for Cu accumulation in peat was discussed. Wet chemical techniques and x-ray diffraction were utilized to identify Cu compounds. Copper was organically bound in peat as a chelate complex and did not occur as an oxide, sulfide, or as elemental Cu. Because of the low S content of peat the Cu was assumed to be bound to nitrogen or oxygen-containing components. Copper, having a greater affinity for N, tended to form the more stable Cu-N chelate. The element was concentrated as circulating cupriferous ground waters filtered through the peat.

  17. Tunable synthesis of copper nanotubes

    International Nuclear Information System (INIS)

    Kaniukov, E; Yakimchuk, D; Kozlovsky, A; Shlimas, D; Zdorovets, M; Kadyrzhanov, K

    2016-01-01

    Simple method of tunable synthesis of copper nanotubes based on template synthesis was developed. A comprehensive study of the structural, morphological and electrical characteristics of the obtained nanostructures was carried out. Characterization of structural features was made by methods of scanning electron microscopy, energy dispersive spectroscopy and X-ray diffractometry analysis. Evaluation of wall thickness is made by methods of gas permeability. Electrical conductivity of nanotubes was define in the study of their current-voltage characteristics. The possibility to control of copper nanotubes physical properties by variation of the deposition parameters was shown. (paper)

  18. Electrical conduction in composites containing copper core–copper ...

    Indian Academy of Sciences (India)

    Unknown

    of Mott's small polaron hopping conduction model. ... sample exhibited a metallic conduction confirming the formation of a percolative chain of ..... value of εp. Also the oxide layer formation on the initially unoxidized copper particles will increase the resistivity level of the nanocomposite. This is borne out by results shown in ...

  19. 21 CFR 73.2647 - Copper powder.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 1 2010-04-01 2010-04-01 false Copper powder. 73.2647 Section 73.2647 Food and... ADDITIVES EXEMPT FROM CERTIFICATION Cosmetics § 73.2647 Copper powder. (a) Identity and specifications. The color additive copper powder shall conform in identity and specifications to the requirements of § 73...

  20. Sequential heavy metal extraction from dust precipitates and road sediments. Part 2. Sequential heavy metal extraction from urban dust; Sequentielle Schwermetallextraktion aus Staubniederschlaegen und Strassensedimenten. T. 2. Sequentielle Schwermetallextraktion von staedtischen Staeuben

    Energy Technology Data Exchange (ETDEWEB)

    Heiser, U.; Norra, S.; Stueben, D.; Wagner, M. von [Karlsruhe Univ. (T.H.) (Germany). Inst. fuer Petrographie und Geochemie

    1999-03-01

    For the application of our method for the sequential extraction of heavy metals from microsamples presented in part 1 (`Sequentielle Schwermetallextraktion von Mikroproben` - `Sequential Extraction of Heavy Metals from Micro Samples`) an investigation was carried out to evaluate airborne dust fallout and street sediments at two urban sites where different heavy metal immission rates occur due to traffic influence. In the street sediments the total concentrations of zinc, copper and lead was three to fivefold higher in the silt and clay fraction (<63 {mu}m) than in the particle size fraction (<1,12 mm), but showed nearly the same mobilisation behaviour. The dust samples showed equal mobilisation behaviour as the street sediments for copper and lead, while zinc was considerably more mobile in the dust samples: In extraction steps I-IV (I: mobile fraction; II: easily deliverable fraction; III: fraction bound to manganese oxides; IV: fraction bound organic to matter) zinc, copper and lead in street sediments, as well as copper and lead in dust samples, were dissolved to 40-70%, whereas about 80% of zinc in the dust samples was already dissolved in extraction step I. (orig.) [Deutsch] Mit Hilfe des in Teil 1 (`Sequentielle Schwermetallextraktion von Mikroproben`) vorgestellten Verfahrens zur sequentiellen Schwermetallextraktion von Mikroproben wurden die Mobilisierbarkeiten von Zink, Kupfer und Blei aus Staubniederschlaegen und aus der Schluff- und Tonfraktion von Strassensedimenten an zwei urbanen Standorten mit unterschiedlicher, verkehrsbedingter Schwermetallbelastung untersucht und miteinander verglichen. In Strassensedimenten wiesen Zink, Kupfer und Blei in der Schluff- und Tonfraktion drei- bis fuenffach hoehere Gesamtgehalte auf als die Korngroessenfraktion <1,12 mm, zeigten aber aehnliches Verhalten in der Mobilisierbarkeit. Bei den Staubproben war die Mobilisierbarkeit von Kupfer und Blei aehnlich wie in den Strassensedimenten, waehrend sich Zink als erheblich