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Sample records for coordination sphere spektry

  1. Amidinate Ligands in Zinc coordination sphere

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Chemical Sciences; Volume 128; Issue 6. Amidinate Ligands in Zinc coordination sphere: Synthesis and structural diversity. SRINIVAS ANGA INDRANI BANERJEE TARUN K PANDA. Regular Article Volume 128 Issue 6 June 2016 pp ... Keywords. Zinc; carbodiimides; amidinate; alkyl migration.

  2. Amidinate Ligands in Zinc coordination sphere: Synthesis and ...

    Indian Academy of Sciences (India)

    ... Refresher Courses · Symposia · Live Streaming. Home; Journals; Journal of Chemical Sciences; Volume 128; Issue 6. Amidinate Ligands in Zinc coordination sphere: Synthesis and structural diversity. SRINIVAS ANGA INDRANI BANERJEE TARUN K PANDA. Regular Article Volume 128 Issue 6 June 2016 pp 867-873 ...

  3. Amidinate Ligands in Zinc coordination sphere: Synthesis and ...

    Indian Academy of Sciences (India)

    Amidinate Ligands in Zinc coordination sphere: Synthesis and structural diversity. SRINIVAS ANGA, INDRANI BANERJEE and TARUN K PANDA. ∗. Department of Chemistry, Indian Institute of Technology Hyderabad, Kandi 502 285,. Sangareddy, Telangana, India e-mail: tpanda@iith.ac.in. MS received 25 February 2016; ...

  4. Anisotropic Charged Fluid Sphere in Isotropic Coordinates

    Directory of Open Access Journals (Sweden)

    Neeraj Pant

    2014-01-01

    Full Text Available We have presented a class of charged superdense star models, starting with a static spherically symmetric metric in isotropic coordinates for anisotropic fluid by considering Hajj-Boutros-(1986 type metric potential and a specific choice of electrical intensity E and anisotropy factor Δ which involve charge parameter K and anisotropy parameter α. The solution is well behaved for all the values of Schwarzschild compactness parameter u lying in the range 0

  5. Transition Metal Complexes Coordinated by Water Soluble Phosphane Ligands: How Cyclodextrins Can Alter the Coordination Sphere?

    Directory of Open Access Journals (Sweden)

    Michel Ferreira

    2017-01-01

    Full Text Available The behaviour of platinum(II and palladium(0 complexes coordinated by various hydrosoluble monodentate phosphane ligands has been investigated by 31P{1H} NMR spectroscopy in the presence of randomly methylated β-cyclodextrin (RAME-β-CD. This molecular receptor can have no impact on the organometallic complexes, induce the formation of phosphane low-coordinated complexes or form coordination second sphere species. These three behaviours are under thermodynamic control and are governed not only by the affinity of RAME-β-CD for the phosphane but also by the phosphane stereoelectronic properties. When observed, the low-coordinated complexes may be formed either via a preliminary decoordination of the phosphane followed by a complexation of the free ligand by the CD or via the generation of organometallic species complexed by CD which then lead to expulsion of ligands to decrease their internal steric hindrance.

  6. Inner-Sphere versus Outer-Sphere Coordination of BF4– in a NHC-Gold(I) Complex

    KAUST Repository

    Veenboer, Richard M. P.

    2017-07-20

    The role of counterions in chemistry mediated by gold complexes stretches much further than merely providing charge balance to cationic gold species. Interplay between their basicities and coordination strengths influences interactions with both the gold center and substrates in catalysis. Actual monogold(I) active species are generally believed to be monocoordinated species, formed from the abstraction or the decoordination of a second ligand from precursor complexes, but only a small amount of experimental evidence exists to underpin the existence of these transient species. The formation of a bench-stable neutral IPrCl-gold(I) tetrafluoroborate complex is reported herein. Experimental studies by X-ray diffraction analysis and NMR spectroscopy and theoretical studies by DFT calculations were conducted to determine the composition, structure, and behavior of this complex. The absence of an auxiliary ligand resulted in inner-sphere coordination of the counterion in the solid state. In solution, an equilibrium between two conformations was found with the counterion occupying inner-sphere and outer-sphere positions, respectively. Stoichiometric and catalytic reactivity studies with the tetrafluoroborate complex have been conducted. These confirmed the lability of the inner-sphere coordinating counterion that gives the IPrCl-gold(I) fragment behavior similar to that of related systems.

  7. Coordination chemistry and antisolvent strategy to rare-earth solid solution colloidal spheres.

    Science.gov (United States)

    Li, Cheng Chao; Zeng, Hua Chun

    2012-11-21

    We have devised in this work a general synthetic strategy for preparation of single- and multicomponent rare-earth coordination polymer colloidal spheres (RE-CPCSs). This strategy is based on an integration of coordination chemistry and antisolvent effect for synchronized precipitation. Highly monodisperse RE-CPCSs with homogeneous mixing of RE elements, which are not readily attainable by any existing methods, have been successfully prepared for the first time. In addition, the type and molar ratio of these colloidal spheres can be adjusted easily in accordance to the variety and dosage of precursor salts. The molar ratio of RE elements in as-prepared colloidal spheres shows a linear relationship to that of starting reactants. Furthermore, the RE-based core/shell colloidal spheres can be facilely prepared by introducing other metal salts (beyond lanthanide elements) owing to their different coordination chemistry and precipitation behavior. By adjusting concentrations of the ionic activators, luminescent properties can be tuned accordingly. Moreover, the RE-CPCSs can be transformed to monodisperse lanthanide oxide spheres via simple heat treatment. We believe that the present synthetic strategy provides a viable route to prepare other lanthanide-containing colloidal spheres that have enormous potential for future applications as optoelectronic devices, catalysts, gas sensors, and solar cells.

  8. Ligand Control of the Metal Coordination Sphere: Structures, Reactivity and Catalysis

    Directory of Open Access Journals (Sweden)

    Danopoulos Andreas A.

    2016-03-01

    Full Text Available Two major aspects of coordination/organometallic chemistry are discussed in this article: (i the use of functional chelating ligands to stabilize metal complexes while allowing easy stereodifferentiation within the coordination sphere and (ii the choice of suitable ligands to stabilize challenging ‘underligated’ metal complexes with electronically highly unsaturated metal centres, thus potentially displaying unusual reactivity. In both cases, the relevance to homogeneous catalysis will be discussed.

  9. Catalytic effect in opening the coordination sphere of an organo-f-complex

    International Nuclear Information System (INIS)

    Andrea, T.; Wang, J.; Gourevich, I.; Eisen, M.S.

    2002-01-01

    Organo-f-complexes have been studied in the last decade showing unique stoichiometric and catalytic properties, which are deeply influenced by the nature of the x ancillary ligands. Opening of the metal center coordination sphere is obtained by replacing the pentamethylcyclopentadienyl ligation in Cp* 2 MR 2 (Cp* = C 5 Me 5 , M = f-element metal, R = a-bonded ligand) by the bridged ancillary ligation Anna-Me 2 SiCp 2MR 2 (Cp* = C 5 Me 4 ). For organolanthanides, this change allows an increase (10-100 fold) in rates for the olefin insertion into the M-R bond [1] and in organoactinides; this modification has been shown to cause an increase (103 fold) in their catalytic activity for the hydrogenation of 1-hexene [2]. Recently, we have shown that organoactinides of the type Cp* 2 MR 2 (Cp* = C 5 Me 5 ; M = Th, U; R = CH 3 ) are active catalysts for both the oligomerization and hydrosilylation of terminal alkynes [3J. Thus, a conceptual question arises regarding the use of an open organoactinide such as Me 2 SiCp* 2 U n Bu 2 as compared to Cp* 2 UR 2 . This opening in the coordination sphere at the metal center should be unique in such a way that it is reasonable expected the increase of the reactivity towards product formation in the hydrosilylation and metathesis catalytic processes of terminal alkynes. In this poster we report, and quantitatively compare, the effects of the ansa-organouranium complex (Me 2 SiCp'' 2 U n Bu) 2 O The synthesis of the complex was achieved as described in equations 1 and 2

  10. Coordinated HArd Sphere Model (CHASM): A Simplified Model for Silicate and Oxide Liquids at Mantle Conditions

    Science.gov (United States)

    Wolf, A. S.; Asimow, P. D.; Stevenson, D. J.

    2013-12-01

    Recent first-principles theoretical calculations (Stixrude 2009) and experimental shock-wave investigations (Mosenfelder 2009) indicate that melting perovskite requires significantly less energy than previously thought, supporting the idea of a deep-mantle magma ocean early in Earth's history. The modern-day solid Earth is thus likely the result of crystallization from an early predominantly molten state, a process that is primarily controlled by the poorly understood behavior of silicate melts at extreme pressures and temperatures. Probing liquid thermodynamics at mantle conditions is difficult for both theory and experiment, and further challenges are posed by the large relevant compositional space including at least MgO, SiO2, and FeO. First-principles molecular dynamics has been used with great success to determine the high P-T properties of a small set of fixed composition silicate-oxide liquids including MgO (Karki 2006), SiO2 (Karki 2007), Mg2SiO4 (de Koker 2008), MgSiO3 (Stixrude 2005), and Fe2SiO4 (Ramo 2012). While extremely powerful, this approach has limitations including high computational cost, lower bounds on temperature due to relaxation constraints, as well as restrictions to length scales and time scales that are many orders of magnitude smaller than those relevant to the Earth or experimental methods. As a compliment to accurate first-principles calculations, we have developed the Coordinated HArd Sphere Model (CHASM). We extend the standard hard sphere mixture model, recently applied to silicate liquids by Jing (2011), by accounting for the range of oxygen coordination states available to liquid cations. Utilizing approximate analytic expressions for the hard sphere model, the method can predict complex liquid structure and thermodynamics while remaining computationally efficient. Requiring only minutes on standard desktop computers rather than months on supercomputers, the CHASM approach is well-suited to providing an approximate thermodynamic

  11. Active Hydrogenation Catalyst with a Structured, Peptide-Based Outer-Coordination Sphere

    Energy Technology Data Exchange (ETDEWEB)

    Jain, Avijita; Buchko, Garry W.; Reback, Matthew L.; O' Hagan, Molly J.; Ginovska-Pangovska, Bojana; Linehan, John C.; Shaw, Wendy J.

    2012-10-05

    The synthesis, catalytic activity, and structural features of a rhodium-based hydrogenation catalyst containing a phosphine ligand coupled to a 14-residue peptide are reported. Both CD and NMR spectroscopy show that the peptide adopts a helical structure in 1:1:1 TFE/MeCN/H2O that is maintained when the peptide is attached to the ligand and when the ligand is attached to the metal complex. The metal complex hydrogenates aqueous solutions of 3-butenol to 1-butanol at 360 ± 50 turnovers/Rh/h at 294 K. This peptide- based catalyst represents a starting point for developing and characterizing a peptide-based outer-coordination sphere that can be used to introduce enzyme-like features into molecular catalysts. This work was funded by the US DOE Basic Energy Sciences, Chemical Sciences, Geoscience and Biosciences Division (AJ, JCL and WJS), the Office of Science Early Career Research Program through the Office of Basic Energy Sciences (GWB, MLR and WJS). Part of the research was conducted at the W.R. Wiley Environmental Molecular Sciences Laboratory, a national scientific user facility sponsored by U.S. Department of Energy’s Office of Biolog-ical and Environmental Research (BER) program located at Pacific Northwest National Laboratory (PNNL). PNNL is operated by Battelle for the U.S. Department of Energy.

  12. Hydrogen peroxide coordination to cobalt(II) facilitated by second-sphere hydrogen bonding

    Czech Academy of Sciences Publication Activity Database

    Wallen, C.M.; Palatinus, Lukáš; Bacsa, J.; Scarborough, C.C.

    2016-01-01

    Roč. 55, č. 39 (2016), s. 11902-11906 ISSN 0044-8249 Institutional support: RVO:68378271 Keywords : cobalt * hydrogen bonds * peroxides * peroxido ligands * second-sphere interactions Subject RIV: CC - Organic Chemistry

  13. Interplay between CN-Ligands and the Secondary Coordination Sphere of the H-Cluster in [FeFe]-Hydrogenases.

    Science.gov (United States)

    Lampret, Oliver; Adamska-Venkatesh, Agnieszka; Konegger, Hannes; Wittkamp, Florian; Apfel, Ulf-Peter; Reijerse, Edward J; Lubitz, Wolfgang; Rüdiger, Olaf; Happe, Thomas; Winkler, Martin

    2017-12-20

    The catalytic cofactor of [FeFe]-hydrogenses (H-cluster) is composed of a generic cubane [4Fe-4S]-cluster (4Fe H ) linked to a binuclear iron-sulfur cluster (2Fe H ) that has an open coordination site at which the reversible conversion of protons to molecular hydrogen occurs. The (2Fe H ) subsite features a diatomic coordination sphere composed of three CO and two CN - ligands affecting its redox properties and providing excellent probes for FTIR spectroscopy. The CO stretch vibrations are very sensitive to the redox changes within the H-cluster occurring during the catalytic cycle, whereas the CN - signals seem to be relatively inert to these effects. This could be due to the more structural role of the CN - ligands tightly anchoring the (2Fe H ) unit to the protein environment through hydrogen bonding. In this work we explore the effects of structural changes within the secondary ligand sphere affecting the CN - ligands on FTIR spectroscopy and catalysis. By comparing the FTIR spectra of wild-type enzyme and two mutagenesis variants, we are able to assign the IR signals of the individual CN - ligands of the (2Fe H ) site for different redox states of the H-cluster. Moreover, protein film electrochemistry reveals that targeted manipulation of the secondary coordination sphere of the proximal CN - ligand (i.e., closest to the (4Fe H ) site) can affect the catalytic bias. These findings highlight the importance of the protein environment for re-adjusting the catalytic features of the H-cluster in individual enzymes and provide valuable information for the design of artificial hydrogenase mimics.

  14. Coordinated Hard Sphere Mixture (CHaSM): A fast approximate model for oxide and silicate melts at extreme conditions

    Science.gov (United States)

    Wolf, A. S.; Asimow, P. D.; Stevenson, D. J.

    2015-12-01

    Recent first-principles calculations (e.g. Stixrude, 2009; de Koker, 2013), shock-wave experiments (Mosenfelder, 2009), and diamond-anvil cell investigations (Sanloup, 2013) indicate that silicate melts undergo complex structural evolution at high pressure. The observed increase in cation-coordination (e.g. Karki, 2006; 2007) induces higher compressibilities and lower adiabatic thermal gradients in melts as compared with their solid counterparts. These properties are crucial for understanding the evolution of impact-generated magma oceans, which are dominated by the poorly understood behavior of silicates at mantle pressures and temperatures (e.g. Stixrude et al. 2009). Probing these conditions is difficult for both theory and experiment, especially given the large compositional space (MgO-SiO2-FeO-Al2O3-etc). We develop a new model to understand and predict the behavior of oxide and silicate melts at extreme P-T conditions (Wolf et al., 2015). The Coordinated Hard Sphere Mixture (CHaSM) extends the Hard Sphere mixture model, accounting for the range of coordination states for each cation in the liquid. Using approximate analytic expressions for the hard sphere model, this fast statistical method compliments classical and first-principles methods, providing accurate thermodynamic and structural property predictions for melts. This framework is applied to the MgO system, where model parameters are trained on a collection of crystal polymorphs, producing realistic predictions of coordination evolution and the equation of state of MgO melt over a wide P-T range. Typical Mg-coordination numbers are predicted to evolve continuously from 5.25 (0 GPa) to 8.5 (250 GPa), comparing favorably with first-principles Molecular Dynamics (MD) simulations. We begin extending the model to a simplified mantle chemistry using empirical potentials (generally accurate over moderate pressure ranges, consuming classical MD calculations. This approach also sheds light on the universality

  15. Gosset helicoids: II. Second coordination sphere of eight-dimensional lattice E{sub 8} and ordered noncrystalline tetravalent structures

    Energy Technology Data Exchange (ETDEWEB)

    Samoylovich, M. I., E-mail: samoylovich@technomash.ru [Joint-Stock Company Central Research Technological Institute ' Technomash,' (Russian Federation); Talis, A. L. [Russian Academy of Sciences, Nesmeyanov Institute of Organoelement Compounds (Russian Federation)

    2009-12-15

    This paper completes a series of works in which the three-dimensional Euclidean realization of the system of constructions of algebraic geometry determines the three-level (cluster-helicoid-union of helicoids) scheme of the assembly of ordered tetravalent structures. The algebraic and topological properties of the second coordination sphere of the eight-dimensional lattice E{sub 8} have been used to derive an ordered noncrystalline diamond-like structure. An a priori constructed model represents a helicoidal assembly of finite tubes (from allowably distorted <110> diamond chains) with transverse pentacycles, hexacycles, and heptacycles and nonintegral screw axes. It has been assumed that similar structures can be formed in diamond-like thin films, gas hydrates, biological structures, nanostructures, and other ordered systems.

  16. Secondary coordination sphere accelerates hole transfer for enhanced hydrogen photogeneration from [FeFe]-hydrogenase mimic and CdSe QDs in water.

    Science.gov (United States)

    Wen, Min; Li, Xu-Bing; Jian, Jing-Xin; Wang, Xu-Zhe; Wu, Hao-Lin; Chen, Bin; Tung, Chen-Ho; Wu, Li-Zhu

    2016-07-15

    Achieving highly efficient hydrogen (H2) evolution via artificial photosynthesis is a great ambition pursued by scientists in recent decades because H2 has high specific enthalpy of combustion and benign combustion product. [FeFe]-Hydrogenase ([FeFe]-H2ase) mimics have been demonstrated to be promising catalysts for H2 photoproduction. However, the efficient photocatalytic H2 generation system, consisting of PAA-g-Fe2S2, CdSe QDs and H2A, suffered from low stability, probably due to the hole accumulation induced photooxidation of CdSe QDs and the subsequent crash of [FeFe]-H2ase mimics. In this work, we take advantage of supramolecular interaction for the first time to construct the secondary coordination sphere of electron donors (HA(-)) to CdSe QDs. The generated secondary coordination sphere helps realize much faster hole removal with a ~30-fold increase, thus leading to higher stability and activity for H2 evolution. The unique photocatalytic H2 evolution system features a great increase of turnover number to 83600, which is the highest one obtained so far for photocatalytic H2 production by using [FeFe]-H2ase mimics as catalysts.

  17. Experimental and DFT Investigations Reveal the Influence of the Outer Coordination Sphere on the Vibrational Spectra of Nickel-Substituted Rubredoxin, a Model Hydrogenase Enzyme.

    Science.gov (United States)

    Slater, Jeffrey W; Marguet, Sean C; Cirino, Sabrina L; Maugeri, Pearson T; Shafaat, Hannah S

    2017-04-03

    Nickel-substituted rubredoxin (NiRd) is a functional enzyme mimic of hydrogenase, highly active for electrocatalytic and solution-phase hydrogen generation. Spectroscopic methods can provide valuable insight into the catalytic mechanism, provided the appropriate technique is used. In this study, we have employed multiwavelength resonance Raman spectroscopy coupled with DFT calculations on an extended active-site model of NiRd to probe the electronic and geometric structures of the resting state of this system. Excellent agreement between experiment and theory is observed, allowing normal mode assignments to be made on the basis of frequency and intensity analyses. Both metal-ligand and ligand-centered vibrational modes are enhanced in the resonance Raman spectra. The latter provide information about the hydrogen bonding network and structural distortions due to perturbations in the secondary coordination sphere. To reproduce the resonance enhancement patterns seen for high-frequency vibrational modes, the secondary coordination sphere must be included in the computational model. The structure and reduction potential of the Ni III Rd state have also been investigated both experimentally and computationally. This work begins to establish a foundation for computational resonance Raman spectroscopy to serve in a predictive fashion for investigating catalytic intermediates of NiRd.

  18. Electronic and Structural Effects of Inner Sphere Coordination of Chloride to a Homoleptic Copper(II) Diimine Complex.

    Science.gov (United States)

    Leandri, Valentina; Daniel, Quentin; Chen, Hong; Sun, Licheng; Gardner, James M; Kloo, Lars

    2018-04-02

    The reaction of CuCl 2 with 2,9-dimethyl-1,10-phenanthroline (dmp) does not lead to the formation of [Cu(dmp) 2 ](Cl) 2 but instead to [Cu(dmp) 2 Cl]Cl, a 5-coordinated complex, in which one chloride is directly coordinated to the metal center. Attempts at removing the coordinated chloride by changing the counterion by metathesis were unsuccessful and resulted only in the exchange of the noncoordinated chloride, as confirmed from a crystal structure analysis. Complex [Cu(dmp) 2 Cl]PF 6 exhibits a reversible cyclic voltammogram characterized by a significant peak splitting between the reductive and oxidative waves (0.85 and 0.60 V vs NHE, respectively), with a half-wave potential E 1/2 = 0.73 V vs NHE. When reduced electrochemically, the complex does not convert into [Cu(dmp) 2 ] + , as one may expect. Instead, [Cu(dmp) 2 ] + is isolated as a product when the reduction of [Cu(dmp) 2 Cl]PF 6 is performed with l-ascorbic acid, as confirmed by electrochemistry, NMR spectroscopy, and diffractometry. [Cu(dmp) 2 ] 2+ complexes can be synthesized starting from Cu(II) salts with weakly and noncoordinating counterions, such as perchlorate. Growth of [Cu(dmp) 2 ](ClO 4 ) 2 crystals in acetonitrile results in a 5-coordinated complex, [Cu(dmp) 2 (CH 3 CN)](ClO 4 ) 2 , in which a solvent molecule is coordinated to the metal center. However, solvent coordination is associated with a dynamic decoordination-coordination behavior upon reduction and oxidation. Hence, the cyclic voltammogram of [Cu(dmp) 2 (CH 3 CN)] 2+ is identical to the one of [Cu(dmp) 2 ] + , if the measurements are performed in acetonitrile. The current results show that halide ions in precursors to Cu(II) metal-organic coordination compound synthesis, and most likely also other multivalent coordination centers, are not readily exchanged when exposed to presumed strongly binding and chelating ligand, and thus special care needs to be taken with respect to product characterization.

  19. Ambiguously Divided Responsibilities across Government Spheres: How they Impact the Policy Process and Result in Coordination Problems in the Case of Poland

    Directory of Open Access Journals (Sweden)

    Hans Dubois

    2014-07-01

    Full Text Available Empirical studies in decentralized settings associate ambiguities in the division of responsibilities between government spheres with coordination problems. This study explores the mechanisms behind this association, mainly drawing on in-depth interviews with local government officials in Poland. A typology emerges from the data. Ambiguities can refer to the policy content, but also to the rationale behind responsibilities. They may be real or perceived. The agent who perceives the ambiguities can be close to public administration (internal or further removed from it (external. External ambiguities mostly inhibit front-room stages of the policy cycle, while external ambiguities impede back-room stages. Through different paths, they contribute to tensions between government spheres, obstructing cooperation needed to address the ambiguities. Overall, the article contributes to a better understanding of the policy process in decentralized settings, unwraps the dynamic causal framework surrounding the ambiguities, and highlights the role of perceptions, not only by the electorate, but by public officials in particular.

  20. Molecular dynamics study of the coordination sphere of trivalent lanthanum in a highly concentrated LiCl aqueous solution: A combined classical and ab initio approach

    International Nuclear Information System (INIS)

    Vuilleumier, R.; Petit, L.; Maldivi, P.; Adamo, C.

    2008-01-01

    The first coordination sphere of trivalent lanthanum in a highly concentrated (14 M) lithium chloride solution is studied with a combination of classical molecular dynamics and density functional theory based first principle molecular dynamics. This method enables us to obtain a solvation shell of La 3+ containing 2 chloride ions and 6 water molecules. After refinement using first principle molecular dynamics, the resulting cation-water and cation-anion distances are in very good agreement with experiment. The 2 Cl - and the 6 water molecules arrange in a square anti-prism around La 3+ . Exchange of water molecules was also observed in the first-principle simulation, with an intermediate structure comprising 7 water molecules stable for 2.5 ps. Finally, evaluation of dipole moments using maximally localized Wannier functions shows a substantial polarization of the chloride anions and the water molecules in the first solvation shell of trivalent lanthanum. (authors)

  1. Second-sphere coordination complex via hydrogen bonding: Synthesis, characterization, X-ray crystal structure determination and packing of hexaamminecobalt(III) chloride di( para-nitrobenzoate)

    Science.gov (United States)

    Sharma, Raj Pal; Bala, Ritu; Sharma, Rajni; Perez, Julio; Miguel, Daniel

    2006-09-01

    A reddish orange coloured crystalline solid of hexaamminecobalt(III) chloride di( para-nitrobenzoate) was obtained when hexaamminecobalt(III) chloride was reacted with the sodium salt of para-nitrobenzoic acid (1:3 molar ratio) in hot aqueous medium. This cobalt(III) complex salt has been characterized by elemental analyses and spectroscopic techniques (e.g. UV/visible, IR and NMR). Single-crystal X-ray structure determination of the title complex salt revealed that it contains the cationic cobaltammine ([Co(NH 3) 6] 3+) and mixed anions (Cl -, NO 2C 6H 4COO -), which are held together by electrostatic forces attractions through second-sphere coordination, i.e. N-H⋯O (carboxylate and nitro) and N-H⋯Cl hydrogen bonds, resulting in a three-dimensional network.

  2. Packings of deformable spheres

    Science.gov (United States)

    Mukhopadhyay, Shomeek; Peixinho, Jorge

    2011-07-01

    We present an experimental study of disordered packings of deformable spheres. Fluorescent hydrogel spheres immersed in water together with a tomography technique enabled the imaging of the three-dimensional arrangement. The mechanical behavior of single spheres subjected to compression is first examined. Then the properties of packings of a randomized collection of deformable spheres in a box with a moving lid are tested. The transition to a state where the packing withstands finite stresses before yielding is observed. Starting from random packed states, the power law dependence of the normal force versus packing fraction or strain at different velocities is quantified. Furthermore, a compression-decompression sequence at low velocities resulted in rearrangements of the spheres. At larger packing fractions, a saturation of the mean coordination number took place, indicating the deformation and faceting of the spheres.

  3. Ligand-sensitive but not ligand-diagnostic: evaluating Cr valence-to-core X-ray emission spectroscopy as a probe of inner-sphere coordination.

    Science.gov (United States)

    MacMillan, Samantha N; Walroth, Richard C; Perry, Demetra M; Morsing, Thorbjørn J; Lancaster, Kyle M

    2015-01-05

    This paper explores the strengths and limitations of valence-to-core X-ray emission spectroscopy (V2C XES) as a probe of coordination environments. A library was assembled from spectra obtained for 12 diverse Cr complexes and used to calibrate density functional theory (DFT) calculations of V2C XES band energies. A functional dependence study was undertaken to benchmark predictive accuracy. All 7 functionals tested reproduce experimental V2C XES energies with an accuracy of 0.5 eV. Experimentally calibrated, DFT calculated V2C XES spectra of 90 Cr compounds were used to produce a quantitative spectrochemical series showing the V2C XES band energy ranges for ligands comprising 18 distinct classes. Substantial overlaps are detected in these ranges, which complicates the use of V2C XES to identify ligands in the coordination spheres of unknown Cr compounds. The ligand-dependent origins of V2C intensity are explored for a homologous series of [Cr(III)(NH3)5X](2+) (X = F, Cl, Br, and I) to rationalize the variable intensity contributions of these ligand classes.

  4. Hydrophosphorylation of 1,3-diphenyl-2-propen-1-one and 1-methyl-3-phenyl-2-propen-1-one in the coordination sphere of carbonyl complexes of group 6B metals

    International Nuclear Information System (INIS)

    Kuramshin, A.I.; Karpenko, E.A.; Cherkasov, R.A.

    2001-01-01

    Methods of synthesis of η 2 - and η 4 - complexes of chalcone and benzalacetone with hexacarbonyl mononuclear complexes of group 6B metals (M Cr, Mo, W) were developed and conditions of selective η 2 - or η 4 - coordination of π-heterodiene ligand were ascertained. By the method of IR and NMR spectroscopy it was shown that hydrophosphorylation of the complexes prepared occurs in the metal coordination sphere by the Abramov reaction scheme resulting in the relevant η 2 -coordinated α-hydroxyphosphonates. According to data of quantum-chemical calculations heterodienes lose planarity as a result of π-coordination with metal, which explains regioselectivity of phosphorylation by more electrophilic carbonyl group of coordinated enone [ru

  5. The Problems of Coordination of the International Duties of the Kazakhstan Republic in the Social-Labour Sphere and National Law

    Science.gov (United States)

    Buribayev, Yermek A.; Oryntayev, Zhambyl K.; Bekbossynov, Yermek; Mazhinbekov, Saken; Yessenbekova, Patima; Blasheva, Manshuk

    2016-01-01

    Background/Objectives: The research topicality is conditioned by the fact that the labour secure of the social and labour human rights is realized not only by the national law but also by the international law that is usually more progressive and establishes the generally accepted standards and norms of human rights in the social-labour sphere.…

  6. Public Sphere

    DEFF Research Database (Denmark)

    Trenz, Hans-Jörg

    2015-01-01

    of the collective will of the people in the act of democratic self-government. The concept of the public sphere is used across the fields of media and communication research, cultural studies and the humanities, the history of ideas, legal and constitutional studies as well as democracy studies. Historically......In modern societies, the public sphere represents the intermediary realm that supports the communication of opinions, the discovery of problems that need to be dealt with collectively, the channeling of these problems through the filter of the media and political institutions, and the realization......, public spheres have undergone structural transformations that were closely connected to the emergence of different mass media. More recently, they are subject to trends of transnationalization and digitalization in politics and society....

  7. Sphere based fluid systems

    Science.gov (United States)

    Elleman, Daniel D. (Inventor); Wang, Taylor G. (Inventor)

    1989-01-01

    Systems are described for using multiple closely-packed spheres. In one system for passing fluid, a multiplicity of spheres lie within a container, with all of the spheres having the same outside diameter and with the spheres being closely nested in one another to create multiple interstitial passages of a known size and configuration and smooth walls. The container has an inlet and outlet for passing fluid through the interstitial passages formed between the nested spheres. The small interstitial passages can be used to filter out material, especially biological material such as cells in a fluid, where the cells can be easily destroyed if passed across sharp edges. The outer surface of the spheres can contain a material that absorbs a constitutent in the flowing fluid, such as a particular contamination gas, or can contain a catalyst to chemically react the fluid passing therethrough, the use of multiple small spheres assuring a large area of contact of these surfaces of the spheres with the fluid. In a system for storing and releasing a fluid such as hydrogen as a fuel, the spheres can include a hollow shell containing the fluid to be stored, and located within a compressable container that can be compressed to break the shells and release the stored fluid.

  8. A Powerful Public Sphere?

    DEFF Research Database (Denmark)

    Fiig, Christina

    The paper holds a critical discussion of the Habermasian model of the public sphere and proposes a revised model of a general public......The paper holds a critical discussion of the Habermasian model of the public sphere and proposes a revised model of a general public...

  9. ORGANIZATION IN CONTEMPORARY PUBLIC SPHERE

    OpenAIRE

    Rosemarie HAINES

    2013-01-01

    The critical analysis of Habermas’ Public Sphere Theory and the comparative undertaking to the current day enables us to assert that in contemporary society, public sphere is no longer a political public sphere, this dimension being completed by a societal dimension, the public sphere has extended and now we can talk about partial public spheres in an ever more commercial environment. The new rebuilding and communication technologies create a new type of public character: the visible sphere –...

  10. Fuzzy spheres from inequivalent coherent states quantizations

    International Nuclear Information System (INIS)

    Gazeau, Jean Pierre; Huguet, Eric; Lachieze-Rey, Marc; Renaud, Jacques

    2007-01-01

    The existence of a family of coherent states (CS) solving the identity in a Hilbert space allows, under certain conditions, to quantize functions defined on the measure space of CS parameters. The application of this procedure to the 2-sphere provides a family of inequivalent CS quantizations based on the spin spherical harmonics (the CS quantization from usual spherical harmonics appears to give a trivial issue for the Cartesian coordinates). We compare these CS quantizations to the usual (Madore) construction of the fuzzy sphere. Due to these differences, our procedure yields new types of fuzzy spheres. Moreover, the general applicability of CS quantization suggests similar constructions of fuzzy versions of a large variety of sets

  11. Electromagnetically revolving sphere viscometer

    Science.gov (United States)

    Hosoda, Maiko; Sakai, Keiji

    2014-12-01

    In this paper, we propose a new method of low viscosity measurement, in which the rolling of a probe sphere on the flat solid bottom of a sample cell is driven remotely and the revolution speed of the probe in a sample liquid gives the viscosity measurements. The principle of this method is based on the electromagnetically spinning technique that we developed, and the method is effective especially for viscosity measurements at levels below 100 mPa·s with an accuracy higher than 1%. The probe motion is similar to that in the well-known rolling sphere (ball) method. However, our system enables a steady and continuous measurement of viscosity, which is problematic using the conventional method. We also discuss the limits of the measurable viscosity range common to rolling-sphere-type viscometers by considering the accelerating motion of a probe sphere due to gravity, and we demonstrate the performance of our methods.

  12. Gearing up the SPHERE

    Science.gov (United States)

    Kasper, M.; Beuzit, J.-L.; Feldt, M.; Dohlen, K.; Mouillet, D.; Puget, P.; Wildi, F.; Abe, L.; Baruffolo, A.; Baudoz, P.; Bazzon, A.; Boccaletti, A.; Brast, R.; Buey, T.; Chesneau, O.; Claudi, R.; Costille, A.; Delboulbé, A.; Desidera, S.; Dominik, C.; Dorn, R.; Downing, M.; Feautrier, P.; Fedrigo, E.; Fusco, T.; Girard, J.; Giro, E.; Gluck, L.; Gonte, F.; Gojak, D.; Gratton, R.; Henning, T.; Hubin, N.; Lagrange, A.-M.; Langlois, M.; Mignant, D. L.; Lizon, J.-L.; Lilley, P.; Madec, F.; Magnard, Y.; Martinez, P.; Mawet, D.; Mesa, D.; Müller-Nilsson, O.; Moulin, T.; Moutou, C.; O'Neal, J.; Pavlov, A.; Perret, D.; Petit, C.; Popovic, D.; Pragt, J.; Rabou, P.; Rochat, S.; Roelfsema, R.; Salasnich, B.; Sauvage, J.-F.; Schmid, H. M.; Schuhler, N.; Sevin, A.; Siebenmorgen, R.; Soenke, C.; Stadler, E.; Suarez, M.; Turatto, M.; Udry, S.; Vigan, A.; Zins, G.

    2012-09-01

    Direct imaging and spectral characterisation of exoplanets is one of the most exciting, but also one of the most challenging areas, in modern astronomy. The challenge is to overcome the very large contrast between the host star and its planet seen at very small angular separations. This article reports on the progress made in the construction of the second generation VLT instrument SPHERE, the Spectro-Polarimetric High-contrast Exoplanet REsearch instrument. SPHERE is expected to be commissioned on the VLT in 2013.

  13. Quantum quaternion spheres

    Indian Academy of Sciences (India)

    Indian Acad. Sci. (Math. Sci.) Vol. 127, No. 1, February 2017, pp. 133–164. DOI 10.1007/s12044-016-0318-z. Quantum quaternion spheres. BIPUL SAURABH. Indian Statistical .... sp(2n, C) to describe the type Cn groups at the Lie algebra level, while one switches to. SP(n) at the ...... By the same reasoning, E decomposes ...

  14. ORGANIZATION IN CONTEMPORARY PUBLIC SPHERE

    Directory of Open Access Journals (Sweden)

    Rosemarie HAINES

    2013-12-01

    Full Text Available The critical analysis of Habermas’ Public Sphere Theory and the comparative undertaking to the current day enables us to assert that in contemporary society, public sphere is no longer a political public sphere, this dimension being completed by a societal dimension, the public sphere has extended and now we can talk about partial public spheres in an ever more commercial environment. The new rebuilding and communication technologies create a new type of public character: the visible sphere – non-located, non-dialogical and open. Information and communication are more and more involved in the restructuring of capitalism on an international scale and the reorganization of leadership and management systems. The reevaluation of the public sphere, public opinion, communication allows us to define public sphere according to the profound mutations from today’s democratic societies.

  15. VMware vSphere Design

    CERN Document Server

    Guthrie, Forbes; Saidel-Keesing, Maish

    2011-01-01

    The only book focused on designing VMware vSphere implementations.VMware vSphere is the most widely deployed virtualization platform today. Considered the most robust and sophisticated hypervisor product, vSphere is the de facto standard for businesses, both large and small. This book is the only one of its kind to concisely explain how to execute a successful vSphere architecture, tailored to meet your company's needs. Expert authors share with you the factors that shape the design of a vSphere implementation. Learn how to make the right design decisions for your environment.Explores the late

  16. Full sphere hydrodynamic and dynamo benchmarks

    KAUST Repository

    Marti, P.

    2014-01-26

    Convection in planetary cores can generate fluid flow and magnetic fields, and a number of sophisticated codes exist to simulate the dynamic behaviour of such systems. We report on the first community activity to compare numerical results of computer codes designed to calculate fluid flow within a whole sphere. The flows are incompressible and rapidly rotating and the forcing of the flow is either due to thermal convection or due to moving boundaries. All problems defined have solutions that alloweasy comparison, since they are either steady, slowly drifting or perfectly periodic. The first two benchmarks are defined based on uniform internal heating within the sphere under the Boussinesq approximation with boundary conditions that are uniform in temperature and stress-free for the flow. Benchmark 1 is purely hydrodynamic, and has a drifting solution. Benchmark 2 is a magnetohydrodynamic benchmark that can generate oscillatory, purely periodic, flows and magnetic fields. In contrast, Benchmark 3 is a hydrodynamic rotating bubble benchmark using no slip boundary conditions that has a stationary solution. Results from a variety of types of code are reported, including codes that are fully spectral (based on spherical harmonic expansions in angular coordinates and polynomial expansions in radius), mixed spectral and finite difference, finite volume, finite element and also a mixed Fourier-finite element code. There is good agreement between codes. It is found that in Benchmarks 1 and 2, the approximation of a whole sphere problem by a domain that is a spherical shell (a sphere possessing an inner core) does not represent an adequate approximation to the system, since the results differ from whole sphere results. © The Authors 2014. Published by Oxford University Press on behalf of The Royal Astronomical Society.

  17. Solvation Sphere of I- and Br- in Water

    Energy Technology Data Exchange (ETDEWEB)

    2011-06-22

    The solvation sphere of halides in water has been investigated using a combination of extended x-ray absorption fine structure (EXAFS) and x-ray absorption near-edge structure (XANES) analysis techniques. The results have indicated that I- and Br- both have an asymmetric, 8 water molecule primary solvation spheres. These spheres are identical, with the Br{sup -} sphere about .3 {angstrom} smaller than the I{sup -} sphere. This study utilized near-edge analysis to supplement EXAFS analysis which suffers from signal dampening/broadening due to thermal noise. This paper has reported on the solvation first sphere of I{sup -} and Br{sup -} in water. Using EXAFS and XANES analysis, strong models which describe the geometric configuration of water molecules coordinated to a central anion have been developed. The combination of these techniques has provided us with a more substantiated argument than relying solely on one or the other. An important finding of this study is that the size of the anion plays a smaller role than previously assumed in determining the number of coordinating water molecules Further experimental and theoretical investigation is required to understand why the size of the anion plays a minor role in determining the number of water molecules bound.

  18. Fill tube fitted spheres

    International Nuclear Information System (INIS)

    Ives, B.H.

    1981-01-01

    The high temperature diffusion technique for fuel filling of some future direct drive cryogenic ICF targets may be unacceptable. The following describes a technique of fitting a 1 mm diameter x 6 μm thick glass microsphere with an approx. 50 μm O.D. glass fill tube. The process of laser drilling a 50 μm diameter hole in the microsphere wall, technique for making the epoxy joint between the sphere and fill tube, as well as the assembly procedure are also discussed

  19. Parallel sphere rendering

    Energy Technology Data Exchange (ETDEWEB)

    Krogh, M.; Hansen, C.; Painter, J. [Los Alamos National Lab., NM (United States); de Verdiere, G.C. [CEA Centre d`Etudes de Limeil, 94 - Villeneuve-Saint-Georges (France)

    1995-05-01

    Sphere rendering is an important method for visualizing molecular dynamics data. This paper presents a parallel divide-and-conquer algorithm that is almost 90 times faster than current graphics workstations. To render extremely large data sets and large images, the algorithm uses the MIMD features of the supercomputers to divide up the data, render independent partial images, and then finally composite the multiple partial images using an optimal method. The algorithm and performance results are presented for the CM-5 and the T3D.

  20. Synthesis of metalloporphyrin-based conjugated microporous polymer spheres directed by bipyridine-type ligands.

    Science.gov (United States)

    Ji, Guipeng; Yang, Zhenzhen; Zhao, Yanfei; Zhang, Hongye; Yu, Bo; Xu, Jilei; Xu, Huanjun; Liu, Zhimin

    2015-04-30

    Zinc porphyrin (TP-Zn)-based conjugated microporous polymer (Zn-CMP) spheres were obtained via Sonagashira-Hagihara cross coupling reactions between 5,10,15,20-tetrakis(4-ethynylphenyl)porphyrin-Zn(II) and brominated monomers directed by bidentate bipyridine (BP)-type ligands for the first time, and the sphere diameters could be adjusted from 320 to 740 nm. The coordination between BP and TP-Zn was proved to be the key to forming spheres.

  1. Falling-sphere radioactive viscometry

    International Nuclear Information System (INIS)

    Souza, R. de.

    1987-01-01

    In this work the falling sphere viscometric method was studies experimentally using a sphere tagged with 198 Au radiosotopo, the objective being the demosntration of the advantages of this technique in relation to the traditional method. The utilisation of the falling radioactive sphere permits the point-point monitoring of sphere position as a function of count rate. The fall tube wall and end effects were determined by this technique. Tests were performed with spheres of different diameters in four tubes. The application of this technique demosntrated the wall and end effects in sphere speed. The case of sphere fall in the steady slow regime allowed the determination of the terminal velocity, showing the increase of botton end effect as the sphere approaches the tube base. In the case the transient slow regime, the sphere was initially in a state of respose near the top surface. The data obtained show the influence of the free surface and wall on the sphere acceleration. These experimental data were applied to the Basset equation on order to verify the behaviour of the terms in this equation. (author) [pt

  2. On the simplified path integral on spheres

    Energy Technology Data Exchange (ETDEWEB)

    Bastianelli, Fiorenzo [Universita di Bologna, Dipartimento di Fisica ed Astronomia, Bologna (Italy); INFN, Sezione di Bologna, Bologna (Italy); Albert-Einstein-Institut, Max-Planck-Institut fuer Gravitationsphysik, Golm (Germany); Corradini, Olindo [Universita degli Studi di Modena e Reggio Emilia, Dipartimento di Scienze Fisiche, Informatiche e Matematiche, Modena (Italy); INFN, Sezione di Bologna, Bologna (Italy); Albert-Einstein-Institut, Max-Planck-Institut fuer Gravitationsphysik, Golm (Germany)

    2017-11-15

    We have recently studied a simplified version of the path integral for a particle on a sphere, and more generally on maximally symmetric spaces, and proved that Riemann normal coordinates allow the use of a quadratic kinetic term in the particle action. The emerging linear sigma model contains a scalar effective potential that reproduces the effects of the curvature. We present here further details of the construction, and extend its perturbative evaluation to orders high enough to read off the type-A trace anomalies of a conformal scalar in dimensions d = 14 and d = 16. (orig.)

  3. Freezing on a sphere

    Science.gov (United States)

    Guerra, Rodrigo E.; Kelleher, Colm P.; Hollingsworth, Andrew D.; Chaikin, Paul M.

    2018-02-01

    The best understood crystal ordering transition is that of two-dimensional freezing, which proceeds by the rapid eradication of lattice defects as the temperature is lowered below a critical threshold. But crystals that assemble on closed surfaces are required by topology to have a minimum number of lattice defects, called disclinations, that act as conserved topological charges—consider the 12 pentagons on a football or the 12 pentamers on a viral capsid. Moreover, crystals assembled on curved surfaces can spontaneously develop additional lattice defects to alleviate the stress imposed by the curvature. It is therefore unclear how crystallization can proceed on a sphere, the simplest curved surface on which it is impossible to eliminate such defects. Here we show that freezing on the surface of a sphere proceeds by the formation of a single, encompassing crystalline ‘continent’, which forces defects into 12 isolated ‘seas’ with the same icosahedral symmetry as footballs and viruses. We use this broken symmetry—aligning the vertices of an icosahedron with the defect seas and unfolding the faces onto a plane—to construct a new order parameter that reveals the underlying long-range orientational order of the lattice. The effects of geometry on crystallization could be taken into account in the design of nanometre- and micrometre-scale structures in which mobile defects are sequestered into self-ordered arrays. Our results may also be relevant in understanding the properties and occurrence of natural icosahedral structures such as viruses.

  4. Freezing on a sphere.

    Science.gov (United States)

    Guerra, Rodrigo E; Kelleher, Colm P; Hollingsworth, Andrew D; Chaikin, Paul M

    2018-02-14

    The best understood crystal ordering transition is that of two-dimensional freezing, which proceeds by the rapid eradication of lattice defects as the temperature is lowered below a critical threshold. But crystals that assemble on closed surfaces are required by topology to have a minimum number of lattice defects, called disclinations, that act as conserved topological charges-consider the 12 pentagons on a football or the 12 pentamers on a viral capsid. Moreover, crystals assembled on curved surfaces can spontaneously develop additional lattice defects to alleviate the stress imposed by the curvature. It is therefore unclear how crystallization can proceed on a sphere, the simplest curved surface on which it is impossible to eliminate such defects. Here we show that freezing on the surface of a sphere proceeds by the formation of a single, encompassing crystalline 'continent', which forces defects into 12 isolated 'seas' with the same icosahedral symmetry as footballs and viruses. We use this broken symmetry-aligning the vertices of an icosahedron with the defect seas and unfolding the faces onto a plane-to construct a new order parameter that reveals the underlying long-range orientational order of the lattice. The effects of geometry on crystallization could be taken into account in the design of nanometre- and micrometre-scale structures in which mobile defects are sequestered into self-ordered arrays. Our results may also be relevant in understanding the properties and occurrence of natural icosahedral structures such as viruses.

  5. Another face of Lorenz-Mie scattering: monodisperse distributions of spheres produce Lissajous-like patterns

    NARCIS (Netherlands)

    Doornbos, R.M.P.; Hoekstra, Alfons G.; Doornbos, Richard M.P.; Deurloo, K.E.I.; de Grooth, B.G.; Noordmans, Herke Jan; Sloot, Peter M.A.

    1994-01-01

    The complete scattering matrix S of spheres was measured with a flow cytometer. The experimental equipment allows simultaneous detection of two scattering-matrix elements for every sphere in the distribution. Two-parameter scatterplots withx andy coordinates determined by the Sll + Sij and S11 - Sij

  6. Microsphere Assemblies via Phosphonate Monoester Coordination Chemistry.

    Science.gov (United States)

    Bladek, Kamila J; Reid, Margaret E; Nishihara, Hirotomo; Akhtar, Farid; Gelfand, Benjamin S; Shimizu, George K H

    2018-02-01

    By complexing a bent phosphonate monoester ligand with cobalt(II), coupled with in situ ester hydrolysis, coordination microspheres (CALS=CALgary Sphere) are formed whereas the use of the phosphonic acid directly resulted in a sheet-like structure. Manipulation of the synthetic conditions gave spheres with different sizes, mechanical stabilities, and porosities. Time-dependent studies determined that the sphere formation likely occurred through the formation of a Co 2+ and ligand chain that propagates in three dimensions through different sets of interactions. The relative rates of these assembly processes versus annealing by ester hydrolysis and metal dehydration determine the growth of the microspheres. Hardness testing by nanoindentation is carried out on the spheres and sheets. Notably, no templates or capping agents are employed, the growth of the spheres is intrinsic to the ligand geometry and the coordination chemistry of cobalt(II) and the phosphonate monoester. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Second sphere coordination in anion binding: Synthesis, characterization, X-ray structure of tris(1,10-phenanthroline)cobalt(III)2,4-dinitrophenolate tetrahydrate, [Co(phen) 3](dnp) 3·4H 2O where dnp = 2,4-dinitrophenolate

    Science.gov (United States)

    Sharma, Raj Pal; Singh, Ajnesh; Ferretti, Valeria; Venugopalan, Paloth

    2009-01-01

    A new cobalt(III) complex salt, [Co(phen) 3](dnp) 3·4H 2O has been synthesized in an effort to utilize [Co(phen) 3] 3+ cation as a new host for di-substituted phenolate (2,4-dinitrophenolate) anion. This cobalt (III) complex salt has been characterized by elemental analyses and spectroscopic techniques (UV/visible, IR, NMR and conductance measurements). Single crystal X-ray structure determination confirmed the composition [Co(phen) 3](dnp) 3·4H 2O. A strong network of hydrogen bonding interactions C-H ...O (phenolate), C-H …O (nitro) involving second sphere coordination and O-H …O hydrogen bonding interactions stabilize the crystal lattice. The formation of a complex salt of definite composition along with solubility product data suggests that [Co(phen) 3] 3+ present in [Co(phen) 3]Cl 3 may be used as an anion receptor for 2,4-dinitrophenolate ion.

  8. Hard spheres out of equilibrium

    NARCIS (Netherlands)

    Hermes, M.

    2010-01-01

    In this thesis, experiments and simulations are combined to investigate the nonequilibrium behaviour of hard spheres. In the first chapters we use Molecular Dynamics simulations to investigate the dynamic glass transition of polydisperse hard spheres. We show that this dynamic transition is

  9. Amidinate Ligands in Zinc coordination sphere: Synthesis and ...

    Indian Academy of Sciences (India)

    Department of Chemistry, Indian Institute of Technology Hyderabad, Kandi 502 285,. Sangareddy, Telangana, India e-mail: tpanda@iith.ac. ..... All the new zinc complexes 1-3 were characterized using standard analytical and .... the adoption of a distorted tetrahedral geometry around the zinc ion. Supplementary Information ...

  10. Morse functions with sphere fibers

    OpenAIRE

    Saeki, Osamu

    2006-01-01

    A smooth closed manifold is said to be an almost sphere if it admits a Morse function with exactly two critical points. In this paper, we characterize those smooth closed manifolds which admit Morse functions such that each regular fiber is a finite disjoint union of almost spheres. We will see that such manifolds coincide with those which admit Morse functions with at most three critical values. As an application, we give a new proof of the characterization theorem of those closed manifolds ...

  11. The SPHERE View of Betelgeuse

    Science.gov (United States)

    Chesneau, O.; Schmid, H.-M.; Carbillet, M.; Chiavassa, A.; Abe, L.; Mouillet, D.

    2013-05-01

    SPHERE, the Spectro-Polarimetric High-contrast Exoplanet REsearch instrument for the VLT is optimized towards reaching the highest contrast in a limited field of view and at short distances from the central star, thanks to an extreme AO system. SPHERE is very well suited to study the close environment of Betelgeuse, and has a strong potential for detecting the ejection activity around this key red supergiant.

  12. Porous Ceramic Spheres From Cation Exchange Beads

    Science.gov (United States)

    Dynys, Fred

    2005-01-01

    This document is a slide presentation that examines the use of a simple templating process to produce hollow ceramic spheres with a pore size of 1 to 10 microns. Using ion exchange process it was determined that the method produces porous ceramic spheres with a unique structure: (i.e., inner sphere surrounded by an outer sphere.)

  13. ANIONS FUNCTIONS IN TRANSITION METALS COORDINATION COMPOUNDS

    Directory of Open Access Journals (Sweden)

    T. V. Koksharova

    2016-04-01

    Full Text Available The effect of anions on the structure and properties of coordination compounds of transition metals has been discussed. The examples of changes in the composition of the formed complexes by replacement of the anion are given: metal ratio to a neutral ligand, the composition of the inner sphere, the direction of template synthesis. Anions can determine the presence of isomers in complexes with different ligands. Examples of conformational, ionization isomerism, inner sphere bond isomerization are given. The nature of the coordination polyhedron is highly sensitive to the replacement of the anion too. Examples of coordination compounds where the anion change causes a change in coordination capacity of neutral ligands and the strength of their bonds with the metal, coordination number and geometry of the inner sphere, the organization of molecular structures (the structure of the hydrogen bond networks and the degree of polymerization, crystal packing. The anions significantly affect the binding of the solvent molecules, complexes magnetic and luminescent properties, they can change the compound color, the mechanisms of thermolysis. Anions make a very noticeable influence on possible redox processes following the complexation in some cases. Anions in the coordination sphere can change catalytic and biochemical processes as well as the ways of interaction of metal ions with drugs.

  14. Public Sphere as Digital Assemblage

    DEFF Research Database (Denmark)

    Salovaara-Moring, Inka

    the 1990s onwards digitalization brought concepts of network and complexity into the theoretical discourse. This relational turn changed the social ontology of the public sphere into a dynamic and complex system, erasing the division between the fields of reality (the world), representation (discourse...... theories. Drawing from Deleuze & Guattari (1987), Bennett (2010), and Latour (2004) in order to imagine post-human assemblages of public sphere, this paper argues for a relational ontology that emphasizes the complex interactions of political assemblages. Empirically, it draws from the author’s studies......Normative theories of public sphere have struggled with the topic of materiality. The historical narrative of the ‘public sphere’ situated the phenomenon in specific spaces, where practices (public deliberation) and language (discourse) constructed political agencies, and further publics. From...

  15. Sphere of Nursing Advocacy Model.

    Science.gov (United States)

    Hanks, Robert G

    2005-01-01

    The Sphere of Nursing Advocacy (SNA) model explains and depicts nursing advocacy on behalf of a client. The SNA model views the client as continually protected from the external environment by a semipermeable sphere of nursing advocacy that allows clients to self advocate if the client is emotionally and physically able or to be advocated for by the nurse if the patient is unable to advocate for him- or herself. The SNA model can be used to guide research or it can provide the basis for instruction on the subject of nursing advocacy.

  16. Troubleshooting vSphere storage

    CERN Document Server

    Preston, Mike

    2013-01-01

    This is a step-by-step example-oriented tutorial aimed at showing the reader how to troubleshoot a variety of vSphere storage problems, and providing the reader with solutions that can be completed with minimal effort and time in order to limit damage to work.If you are a vSphere administrator, this is the book for you. This book will provide you with 'need to know' information about the various storage transports that ESXi utilizes, the tools and techniques we can use to identify problems, and the fundamental knowledge and steps to take to troubleshoot storage-related issues. Prior knowledge

  17. Spheres of Justice within Schools

    DEFF Research Database (Denmark)

    Sabbagh, Clara; Resh, Nura; Mor, Michal

    2006-01-01

    This article argues that there are distinct spheres of justice within education and examines a range of justice norms and distribution rules that characterize the daily life of schools and classrooms. Moving from the macro to micro level, we identify the following five areas: the right to education......, and on the practices used in the actual allocation of these goods. In line with normative ‘spheres of justice’ arguments in social theory, we conclude that the ideals of social justice within schools vary strongly according to the particular resource to be distributed. Moreover, these ideals often do not correspond...

  18. Phase diagram of Hertzian spheres

    NARCIS (Netherlands)

    Pàmies, J.C.; Cacciuto, A.; Frenkel, D.

    2009-01-01

    We report the phase diagram of interpenetrating Hertzian spheres. The Hertz potential is purely repulsive, bounded at zero separation, and decreases monotonically as a power law with exponent 5/2, vanishing at the overlapping threshold. This simple functional describes the elastic interaction of

  19. Analytical Method and Semianalytical Method for Analysis of Scattering by Anisotropic Sphere: A Review

    Directory of Open Access Journals (Sweden)

    Chao Wan

    2012-01-01

    Full Text Available The history of methods for the electromagnetic scattering by an anisotropic sphere has been reviewed. Two main methods, angular expansion method and T-matrix method, which are widely used for the anisotropic sphere, are expressed in Cartesian coordinate firstly. The comparison of those and the further exploration on the scattering field are illustrated afterwards. Based on the most general form concluded by variable separation method, the coupled electric field and magnetic field of radial anisotropic sphere can be derived. By simplifying the condition, simpler case of uniaxial anisotropic media is expressed with confirmed coefficients for the internal and external field. Details of significant phenomenon are presented.

  20. Performance and Politics in the Public Sphere

    OpenAIRE

    Wiegmink, Pia

    2011-01-01

    Pia Wiegmink’s timely examination of the transforming transnational spaces of protest in a globalizing and technologically mediated public sphere in “Performance and Politics in the Public Sphere” offers a well-researched review of contemporary theory surrounding ideas of the political (Chantal Mouffe), the public sphere (Jürgen Habermas), the transnational public sphere (Nancy Fraser), and the reterritorialized transnational public sphere (Markus Schroer) as the basis for her analysis of how...

  1. The Lanthanide Contraction beyond Coordination Chemistry.

    Science.gov (United States)

    Ferru, Geoffroy; Reinhart, Benjamin; Bera, Mrinal K; Olvera de la Cruz, Monica; Qiao, Baofu; Ellis, Ross J

    2016-05-10

    The lanthanide contraction is conceptualized traditionally through coordination chemistry. Here we break this mold in a structural study of lanthanide ions dissolved in an amphiphilic liquid. The lanthanide contraction perturbs the weak interactions between molecular aggregates that drive mesoscale assembly and emergent behavior. The weak interactions correlate with lanthanide ion transport properties, suggesting new strategies for rare-earth separation that exploit forces outside of the coordination sphere. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Capillary holdup between vertical spheres

    Directory of Open Access Journals (Sweden)

    S. Zeinali Heris

    2009-12-01

    Full Text Available The maximum volume of liquid bridge left between two vertically mounted spherical particles has been theoretically determined and experimentally measured. As the gravitational effect has not been neglected in the theoretical model, the liquid interface profile is nonsymmetrical around the X-axis. Symmetry in the interface profile only occurs when either the particle size ratio or the gravitational force becomes zero. In this paper, some equations are derived as a function of the spheres' sizes, gap width, liquid density, surface tension and body force (gravity/centrifugal to estimate the maximum amount of liquid that can be held between the two solid spheres. Then a comparison is made between the result based on these equations and several experimental results.

  3. Mie scattering of magnetic spheres.

    Science.gov (United States)

    Tarento, R-J; Bennemann, K-H; Joyes, P; Van de Walle, J

    2004-02-01

    The Mie scattering intensity of a magnetic sphere has been derived by extending the classical Mie scattering approach to a media where the dielectric constant is no more a real number but a tensor with a gyrotropic form. Using a perturbation method the propagation equations of the electromagnetic field are derived. For an incident plane wave the magnetization effect could be detectable. The Mie scattering intensity is analyzed for special incident wave configurations, in particular, for the case where the magnetic field of the incident plane wave is polarized along the magnetization direction. This magnetization effect is most important for the finger pattern of the backscattering intensity. Magnetic Mie scattering is still significant for a magnetic sphere of radius larger than 10 nm.

  4. Charged-soft-sphere potentials for trivalent metal halides

    International Nuclear Information System (INIS)

    Erbolukbas, A.; Akdeniz, Z.; Tosi, M.P.

    1991-09-01

    Octahedral-type coordination by halogens in the liquid state has been reported for a number of trivalent metal ions from diffraction and Raman scattering experiments on their molten trihalides and from Raman scattering spectroscopy of liquid mixtures of trihalides with alkali halides. We analyze the available data on bond lengths and Raman frequencies by treating an isolated (MX 6 ) 3- species within a model which adopts charged-soft-sphere interionic potentials supplemented by an account of ionic polarization. The trivalent metal ions that we consider are M = La, Ce, Pr, Nd, Sm, Gd, Dy and Y for X = Cl and M = Al for X = F. The main result of the analysis is the prediction of trends in the soft-sphere repulsive parameters for the trivalent metal ions, leading to estimates of all the vibrational frequencies and the binding energy of such octahedral species. (author). 26 refs, 1 fig., 4 tabs

  5. Mastering VMware vSphere 5

    CERN Document Server

    Lowe, Scott

    2011-01-01

    A new and updated edition of bestselling Mastering VMware vSphere 4 Written by leading VMware expert, this book covers all the features and capabilities of VMware vSphere. You'll learn how to install, configure, operate, manage, and secure the latest release.Covers all the new features and capabilities of the much-anticipated new release of VMware vSphereDiscusses the planning, installation, operation, and management for the latest releaseReviews migration to the latest vSphere softwareOffers hands-on instruction and clear explanations with real-world examples Mastering VMware vSphere is the

  6. Generating perfect fluid spheres in general relativity

    International Nuclear Information System (INIS)

    Boonserm, Petarpa; Visser, Matt; Weinfurtner, Silke

    2005-01-01

    Ever since Karl Schwarzschild's 1916 discovery of the spacetime geometry describing the interior of a particular idealized general relativistic star--a static spherically symmetric blob of fluid with position-independent density--the general relativity community has continued to devote considerable time and energy to understanding the general-relativistic static perfect fluid sphere. Over the last 90 years a tangle of specific perfect fluid spheres has been discovered, with most of these specific examples seemingly independent from each other. To bring some order to this collection, in this article we develop several new transformation theorems that map perfect fluid spheres into perfect fluid spheres. These transformation theorems sometimes lead to unexpected connections between previously known perfect fluid spheres, sometimes lead to new previously unknown perfect fluid spheres, and in general can be used to develop a systematic way of classifying the set of all perfect fluid spheres

  7. Spheres of Justice within Schools

    DEFF Research Database (Denmark)

    Sabbagh, Clara; Resh, Nura; Mor, Michal

    2006-01-01

    , the allocation of (or selection into) learning places, teaching–learning practices, teachers’ treatment of students, and student evaluations of grade distribution. We discuss the literature on the beliefs by students and teachers about the just distribution of educational goods in these five domains......This article argues that there are distinct spheres of justice within education and examines a range of justice norms and distribution rules that characterize the daily life of schools and classrooms. Moving from the macro to micro level, we identify the following five areas: the right to education...

  8. VMware vSphere design

    CERN Document Server

    Guthrie, Forbes

    2013-01-01

    Achieve the performance, scalability, and ROI your business needs What can you do at the start of a virtualization deployment to make things run more smoothly? If you plan, deploy, maintain, and optimize vSphere solutions in your company, this unique book provides keen insight and solutions. From hardware selection, network layout, and security considerations to storage and hypervisors, this book explains the design decisions you'll face and how to make the right choices. Written by two virtualization experts and packed with real-world strategies and examples, VMware v

  9. Theory of amorphous packings of binary mixtures of hard spheres.

    Science.gov (United States)

    Biazzo, Indaco; Caltagirone, Francesco; Parisi, Giorgio; Zamponi, Francesco

    2009-05-15

    We extend our theory of amorphous packings of hard spheres to binary mixtures and more generally to multicomponent systems. The theory is based on the assumption that amorphous packings produced by typical experimental or numerical protocols can be identified with the infinite pressure limit of long-lived metastable glassy states. We test this assumption against numerical and experimental data and show that the theory correctly reproduces the variation with mixture composition of structural observables, such as the total packing fraction and the partial coordination numbers.

  10. Porous Ceramic Spheres from Ion Exchange Resin

    Science.gov (United States)

    Dynys, Fred

    2005-01-01

    A commercial cation ion exchange resin, cross-linked polystyrene, has been successfully used as a template to fabricate 20 to 50 micron porous ceramic spheres. Ion exchange resins have dual template capabilities. Pore architecture of the ceramic spheres can be altered by changing the template pattern. Templating can be achieved by utilizing the internal porous structure or the external surface of the resin beads. Synthesis methods and chemical/physical characteristics of the ceramic spheres will be reported.

  11. Method for producing small hollow spheres

    International Nuclear Information System (INIS)

    Hendricks, C.D.

    1979-01-01

    A method is described for producing small hollow spheres of glass, metal or plastic, wherein the sphere material is mixed with or contains as part of the composition a blowing agent which decomposes at high temperature (T >approx. 600 0 C). As the temperature is quickly raised, the blowing agent decomposes and the resulting gas expands from within, thus forming a hollow sphere of controllable thickness. The thus produced hollow spheres (20 to 10 3 μm) have a variety of application, and are particularly useful in the fabrication of targets for laser implosion such as neutron sources, laser fusion physics studies, and laser initiated fusion power plants

  12. Casimir interaction between spheres in (D+1)-dimensional Minkowski spacetime

    Energy Technology Data Exchange (ETDEWEB)

    Teo, L.P. [Department of Applied Mathematics, Faculty of Engineering, University of Nottingham Malaysia Campus, Jalan Broga, 43500, Semenyih, Selangor Darul Ehsan (Malaysia)

    2014-05-06

    We consider the Casimir interaction between two spheres in (D+1)-dimensional Minkowski spacetime due to the vacuum fluctuations of scalar fields. We consider combinations of Dirichlet and Neumann boundary conditions. The TGTG formula of the Casimir interaction energy is derived. The computations of the T matrices of the two spheres are straightforward. To compute the two G matrices, known as translation matrices, which relate the hyper-spherical waves in two spherical coordinate frames differ by a translation, we generalize the operator approach employed in R.C. Wittman, Spherical Wave Operators and the Translation Formulas, IEEE Trans. Antennas Propag. 36 (1988) 1078. . The result is expressed in terms of an integral over Gegenbauer polynomials. In contrast to the D=3 case, we do not re-express the integral in terms of 3j-symbols and hyper-spherical waves, which in principle, can be done but does not simplify the formula. Using our expression for the Casimir interaction energy, we derive the large separation and small separation asymptotic expansions of the Casimir interaction energy. In the large separation regime, we find that the Casimir interaction energy is of order L{sup −2D+3}, L{sup −2D+1} and L{sup −2D−1} respectively for Dirichlet-Dirichlet, Dirichlet-Neumann and Neumann-Neumann boundary conditions, where L is the center-to-center distance of the two spheres. In the small separation regime, we confirm that the leading term of the Casimir interaction agrees with the proximity force approximation, which is of order d{sup −((D+1)/2)}, where d is the distance between the two spheres. Another main result of this work is the analytic computations of the next-to-leading order term in the small separation asymptotic expansion. This term is computed using careful order analysis as well as perturbation method. In the case the radius of one of the sphere goes to infinity, we find that the results agree with the one we derive for sphere-plate configuration

  13. Coordination cycles

    Czech Academy of Sciences Publication Activity Database

    Steiner, Jakub

    2008-01-01

    Roč. 63, č. 1 (2008), s. 308-327 ISSN 0899-8256 Institutional research plan: CEZ:AV0Z70850503 Keywords : global games * coordination * crises * cycles and fluctuations Subject RIV: AH - Economics Impact factor: 1.333, year: 2008

  14. Coordination cycles

    Czech Academy of Sciences Publication Activity Database

    Steiner, Jakub

    -, č. 274 (2005), s. 1-26 ISSN 1211-3298 Institutional research plan: CEZ:AV0Z70850503 Keywords : coordination * crises * cycles and fluctuations Subject RIV: AH - Economics http://www.cerge-ei.cz/pdf/wp/Wp274.pdf

  15. Electric dipoles on the Bloch sphere

    OpenAIRE

    Vutha, Amar C.

    2014-01-01

    The time evolution of a two-level quantum mechanical system can be geometrically described using the Bloch sphere. By mapping the Bloch sphere evolution onto the dynamics of oscillating electric dipoles, we provide a physically intuitive link between classical electromagnetism and the electric dipole transitions of atomic & molecular physics.

  16. 1-Public sphere Ambadiang.pmd

    African Journals Online (AJOL)

    \\376\\377\\000s\\000e\\000r\\000i\\000a\\000n\\000e\\000.\\000c\\000a\\000m\\000a\\000r\\000a

    2011-03-09

    Mar 9, 2011 ... Discourse, as seen in Habermas's definition of the public sphere, is an essential aspect of the participation of .... Ambadiang: Public Sphere, Linguistic Sphericules and Discourse Communities in Africa argumentation and may ..... (c) 'Je ne connais que le nom des condiments pour faire mon marché'. (ibid).

  17. Bridging conflicting innovation spheres of tourism innovation

    DEFF Research Database (Denmark)

    Fuglsang, Lars; Sørensen, Flemming; Nordli, Anne Jørgensen

    2016-01-01

    that in tourist destinations actors belong to conflicting innovation spheres but can be brought together in innovation processes when a diplomat enable compromises and when innovation spheres change from personalized to more generalized forms of activity during interaction. The findings are relevant not only...

  18. Point defects in hard-sphere crystals

    NARCIS (Netherlands)

    Pronk, S.; Frenkel, D.

    2001-01-01

    We report numerical calculations of the concentration of interstitials in hard-sphere crystals. We find that in a three-dimensional fcc hard-sphere crystal at the melting point, the concentration of interstitials is 2.7(4) × 10-8. This is some 3 orders of magnitude lower than the concentration of

  19. NEW ECONOMY: APPROACHES, FEATURES, SOCIAL SPHERE DEVELOPMENT

    OpenAIRE

    Babicheva E.E.

    2015-01-01

    The article presents main features of the New economy. Special consideration was given to social sphere development and social institutions restructuring in the context of the New economy. A number of social problems arisen out of this processes had been covered. In the issue author concluded that social sphere development occurred under the conditions of the New economy is fundamental process

  20. Second sphere coordination in anion binding: Synthesis, characterization of [Co(phen) 2CO 3]X· nH 2O where X = o-nitrophenolate(onp), p-nitrophenolate(pnp), 2,4-dinitrophenolate(dnp), 2,4,6-trinitrophenolate(tnp) and single crystal X-ray structures of [Co(phen) 2CO 3](onp)·2H 2O and [Co(phen) 2CO 3](dnp)·4.5H 2O

    Science.gov (United States)

    Singh, Ajnesh; Sharma, Raj Pal; Brandão, Paula; Félix, Vitor; Venugopalan, Paloth

    2008-12-01

    In an effort to utilize [Co(phen) 2CO 3] + cation as a new host for mono-, di- and tri-substituted nitrophenolate anions, red coloured crystals of composition [Co(phen) 2CO 3](onp)·2H 2O, [Co(phen) 2CO 3](pnp), orange coloured precipitated product of [Co(phen) 2CO 3](dnp)·4.5H 2O (which gave red coloured crystals from acetone-water mixture) and orange-yellow coloured precipitated product of [Co(phen) 2CO 3](tnp) were obtained in good yields by reacting sodium salts of o-nitrophenol, p-nitrophenol 2,4-dinitrophenol and 2,4,6-trinitrophenol with [Co(phen) 2CO 3]Cl·5H 2O, respectively in 1:1 molar ratio in aqueous medium. These cobalt(III) complex salts have been characterized by elemental analyses, spectroscopic techniques (UV/Visible, IR and NMR) and conductance measurements. Single crystal X-ray structure determination of [Co(phen) 2CO 3](onp)·2H 2O and [Co(phen) 2CO 3](dnp)·4.5H 2O revealed the presence of discrete ions and lattice water molecules in the solid state. A strong network of hydrogen bond interactions through the weak second sphere coordination (C sbnd H…O (phenolate), C sbnd H…O (nitro), and strong interactions of type O sbnd H…O (water) besides the electrostatic interactions play a very important role in stabilizing the crystal lattice. The studies indicated that complex cation, [Co(phen) 2CO 3] + may preferentially bind nitrophenolate ions in the aqueous medium.

  1. TECHNICAL COORDINATION

    CERN Multimedia

    A. Ball

    Overview From a technical perspective, CMS has been in “beam operation” state since 6th November. The detector is fully closed with all components operational and the magnetic field is normally at the nominal 3.8T. The UXC cavern is normally closed with the radiation veto set. Access to UXC is now only possible during downtimes of LHC. Such accesses must be carefully planned, documented and carried out in agreement with CMS Technical Coordination, Experimental Area Management, LHC programme coordination and the CCC. Material flow in and out of UXC is now strictly controlled. Access to USC remains possible at any time, although, for safety reasons, it is necessary to register with the shift crew in the control room before going down.It is obligatory for all material leaving UXC to pass through the underground buffer zone for RP scanning, database entry and appropriate labeling for traceability. Technical coordination (notably Stephane Bally and Christoph Schaefer), the shift crew and run ...

  2. Theorising Public and Private Spheres

    Directory of Open Access Journals (Sweden)

    Sima Remina

    2016-12-01

    Full Text Available The 19th century saw an expression of women’s ardent desire for freedom, emancipation and assertion in the public space. Women hardly managed to assert themselves at all in the public sphere, as any deviation from their traditional role was seen as unnatural. The human soul knows no gender distinctions, so we can say that women face the same desire for fulfillment as men do. Today, women are more and more encouraged to develop their skills by undertaking activities within the public space that are different from those that form part of traditional domestic chores. The woman of the 19th century felt the need to be useful to society, to make her contribution visible in a variety of domains. A woman does not have to become masculine to get power. If she is successful in any important job, this does not mean that she thinks like a man, but that she thinks like a woman. Women have broken through the walls that cut them off from public life, activity and ambition. There are no hindrances that can prevent women from taking their place in society.

  3. Dense, layered, inclined flows of spheres

    Science.gov (United States)

    Jenkins, James T.; Larcher, Michele

    2017-12-01

    We consider dense, inclined flows of spheres in which the particles translate in layers, whose existence may be promoted by the presence of a rigid base and/or sidewalls. We imagine that in such flows a sphere of a layer is forced up the back of a sphere of the layer below, lifting a column of spheres above it, and then falls down the front of the lower sphere, until it bumps against the preceding sphere of the lower layer. We calculate the forces and rate of momentum transfer associated with this process of rub, lift, fall, and bump and determine a relation between the ratio of shear stress to normal stress and the rate of strain that may be integrated to obtain the velocity profile. The fall of a sphere and that of the column above it results in a linear increase in the magnitude of the velocity fluctuations with distance from the base of the flow. We compare the predictions of the model with measured profiles of velocity and granular temperature in several different dense, inclined flows.

  4. Unsteady flow over a decelerating rotating sphere

    Science.gov (United States)

    Turkyilmazoglu, M.

    2018-03-01

    Unsteady flow analysis induced by a decelerating rotating sphere is the main concern of this paper. A revolving sphere in a still fluid is supposed to slow down at an angular velocity rate that is inversely proportional to time. The governing partial differential equations of motion are scaled in accordance with the literature, reducing to the well-documented von Kármán equations in the special circumstance near the pole. Both numerical and perturbation approaches are pursued to identify the velocity fields, shear stresses, and suction velocity far above the sphere. It is detected that an induced flow surrounding the sphere acts accordingly to adapt to the motion of the sphere up to some critical unsteadiness parameters at certain latitudes. Afterward, the decay rate of rotation ceases such that the flow at the remaining azimuths starts revolving freely. At a critical unsteadiness parameter corresponding to s = -0.681, the decelerating sphere rotates freely and requires no more torque. At a value of s exactly matching the rotating disk flow at the pole identified in the literature, the entire flow field around the sphere starts revolving faster than the disk itself. Increasing values of -s almost diminish the radial outflow. This results in jet flows in both the latitudinal and meridional directions, concentrated near the wall region. The presented mean flow results will be useful for analyzing the instability features of the flow, whether of a convective or absolute nature.

  5. Finding a source inside a sphere

    International Nuclear Information System (INIS)

    Tsitsas, N L; Martin, P A

    2012-01-01

    A sphere excited by an interior point source or a point dipole gives a simplified yet realistic model for studying a variety of applications in medical imaging. We suppose that there is an exterior field (transmission problem) and that the total field on the sphere is known. We give analytical inversion algorithms for determining the interior physical characteristics of the sphere as well as the location, strength and orientation of the source/dipole. We start with static problems (Laplace’s equation) and then proceed to acoustic problems (Helmholtz equation). (paper)

  6. Coordinated unbundling

    DEFF Research Database (Denmark)

    Timmermans, Bram; Zabala-Iturriagagoitia, Jon Mikel

    2013-01-01

    Public procurement for innovation is a matter of using public demand to trigger innovation. Empirical studies have demonstrated that demand-based policy instruments can be considered to be a powerful tool in stimulating innovative processes among existing firms; however, the existing literature has...... not focused on the role this policy instrument can play in the promotion of (knowledge-intensive) entrepreneurship. This paper investigates this link in more detail and introduces the concept of coordinated unbundling as a strategy that can facilitate this purpose. We also present a framework on how...... to organise public procurement for innovation around this unbundling strategy and provide a set of challenges that need to be addressed....

  7. Einstein metrics on tangent bundles of spheres

    Energy Technology Data Exchange (ETDEWEB)

    Dancer, Andrew S [Jesus College, Oxford University, Oxford OX1 3DW (United Kingdom); Strachan, Ian A B [Department of Mathematics, University of Hull, Hull HU6 7RX (United Kingdom)

    2002-09-21

    We give an elementary treatment of the existence of complete Kaehler-Einstein metrics with nonpositive Einstein constant and underlying manifold diffeomorphic to the tangent bundle of the (n+1)-sphere.

  8. Elastic spheres can walk on water

    Science.gov (United States)

    Belden, Jesse; Hurd, Randy C.; Jandron, Michael A.; Bower, Allan F.; Truscott, Tadd T.

    2016-02-01

    Incited by public fascination and engineering application, water-skipping of rigid stones and spheres has received considerable study. While these objects can be coaxed to ricochet, elastic spheres demonstrate superior water-skipping ability, but little is known about the effect of large material compliance on water impact physics. Here we show that upon water impact, very compliant spheres naturally assume a disk-like geometry and dynamic orientation that are favourable for water-skipping. Experiments and numerical modelling reveal that the initial spherical shape evolves as elastic waves propagate through the material. We find that the skipping dynamics are governed by the wave propagation speed and by the ratio of material shear modulus to hydrodynamic pressure. With these insights, we explain why softer spheres skip more easily than stiffer ones. Our results advance understanding of fluid-elastic body interaction during water impact, which could benefit inflatable craft modelling and, more playfully, design of elastic aquatic toys.

  9. Acoustic levitation of a large solid sphere

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, Marco A. B., E-mail: marcobrizzotti@gmail.com [Institute of Physics, University of São Paulo, São Paulo 05508-090 (Brazil); Bernassau, Anne L. [School of Engineering and Physical Sciences, Heriot-Watt University, Edinburgh EH14 4AS (United Kingdom); Adamowski, Julio C. [Department of Mechatronics and Mechanical Systems Engineering, Escola Politécnica, University of São Paulo, São Paulo 05508-030 (Brazil)

    2016-07-25

    We demonstrate that acoustic levitation can levitate spherical objects much larger than the acoustic wavelength in air. The acoustic levitation of an expanded polystyrene sphere of 50 mm in diameter, corresponding to 3.6 times the wavelength, is achieved by using three 25 kHz ultrasonic transducers arranged in a tripod fashion. In this configuration, a standing wave is created between the transducers and the sphere. The axial acoustic radiation force generated by each transducer on the sphere was modeled numerically as a function of the distance between the sphere and the transducer. The theoretical acoustic radiation force was verified experimentally in a setup consisting of an electronic scale and an ultrasonic transducer mounted on a motorized linear stage. The comparison between the numerical and experimental acoustic radiation forces presents a good agreement.

  10. Spheres of Exemption, Figures of Exclusion

    DEFF Research Database (Denmark)

    , the history of ideas, social science, political science and literature studies, Spheres of Exemption, Figures of Exclusion offers thirteen investigations into the co-constitutive relationship between subjectivity and political and legal order, combining theoretical reflection with empirical and historical...

  11. Hydrodynamic interaction between bacteria and passive sphere

    Science.gov (United States)

    Zhang, Bokai; Ding, Yang; Xu, Xinliang

    2017-11-01

    Understanding hydrodynamic interaction between bacteria and passive sphere is important for identifying rheological properties of bacterial and colloidal suspension. Over the past few years, scientists mainly focused on bacterial influences on tracer particle diffusion or hydrodynamic capture of a bacteria around stationary boundary. Here, we use superposition of singularities and regularized method to study changes in bacterial swimming velocity and passive sphere diffusion, simultaneously. On this basis, we present a simple two-bead model that gives a unified interpretation of passive sphere diffusion and bacterial swimming. The model attributes both variation of passive sphere diffusion and changes of speed of bacteria to an effective mobility. Using the effective mobility of bacterial head and tail as an input function, the calculations are consistent with simulation results at a broad range of tracer diameters, incident angles and bacterial shapes.

  12. Gender, Diversity and the European Public Sphere

    DEFF Research Database (Denmark)

    Pristed Nielsen, Helene

    2009-01-01

    This paper argues that feminist criticism of Habermasian theory leads to new ways of approaching empirical analyses of public sphere deliberation, and gives some concrete indications of which methodological consequences such a critique may lead to....

  13. TECHNICAL COORDINATION

    CERN Multimedia

    A. Ball

    2010-01-01

    Operational Experience At the end of the first full-year running period of LHC, CMS is established as a reliable, robust and mature experiment. In particular common systems and infrastructure faults accounted for <0.6 % CMS downtime during LHC pp physics. Technical operation throughout the entire year was rather smooth, the main faults requiring UXC access being sub-detector power systems and rack-cooling turbines. All such problems were corrected during scheduled technical stops, in the shadow of tunnel access needed by the LHC, or in negotiated accesses or access extensions. Nevertheless, the number of necessary accesses to the UXC averaged more than one per week and the technical stops were inevitably packed with work packages, typically 30 being executed within a few days, placing a high load on the coordination and area management teams. It is an appropriate moment for CMS Technical Coordination to thank all those in many CERN departments and in the Collaboration, who were involved in CMS techni...

  14. vSphere high performance cookbook

    CERN Document Server

    Sarkar, Prasenjit

    2013-01-01

    vSphere High Performance Cookbook is written in a practical, helpful style with numerous recipes focusing on answering and providing solutions to common, and not-so common, performance issues and problems.The book is primarily written for technical professionals with system administration skills and some VMware experience who wish to learn about advanced optimization and the configuration features and functions for vSphere 5.1.

  15. Geometrical Dynamics in a Transitioning Superconducting Sphere

    Directory of Open Access Journals (Sweden)

    Claycomb J. R.

    2006-10-01

    Full Text Available Recent theoretical works have concentrated on calculating the Casimir effect in curved spacetime. In this paper we outline the forward problem of metrical variation due to the Casimir effect for spherical geometries. We consider a scalar quantum field inside a hollow superconducting sphere. Metric equations are developed describing the evolution of the scalar curvature after the sphere transitions to the normal state.

  16. Ethnography and the public sphere: summarizing questions

    OpenAIRE

    Cunha, Manuela Ivone; Lima, Antónia

    2013-01-01

    In line with the conference Ethnografeast III. Ethnography and the Public Sphere, from which it stems, this issue aims at equating uses and products of ethnography as they relate with each other within the context of the public sphere. Keeping the conference’s commitment to interdisciplinarity, pluralism in genres and theoretical suasions, it focuses on the way political and civic uses of ethnography enter into the conceptual elaboration of its products, and, conversely, on how the design and...

  17. Point Defects in Hard Sphere Crystals

    OpenAIRE

    Pronk, Sander; Frenkel, Daan

    2001-01-01

    We report numerical calculations of the concentration of interstitials in hard-sphere crystals. We find that, in a three-dimensional fcc hard-sphere crystal at the melting point, the concentration of interstitials is 2 * 10^-8. This is some three orders of magnitude lower than the concentration of vacancies. A simple, analytical estimate yields a value that is in fair agreement with the numerical results.

  18. vSphere virtual machine management

    CERN Document Server

    Fitzhugh, Rebecca

    2014-01-01

    This book follows a step-by-step tutorial approach with some real-world scenarios that vSphere businesses will be required to overcome every day. This book also discusses creating and configuring virtual machines and also covers monitoring virtual machine performance and resource allocation options. This book is for VMware administrators who want to build their knowledge of virtual machine administration and configuration. It's assumed that you have some experience with virtualization administration and vSphere.

  19. Inverse Magnus effect on a rotating sphere

    Science.gov (United States)

    Kim, Jooha; Park, Hyungmin; Choi, Haecheon; Yoo, Jung Yul

    2011-11-01

    In this study, we investigate the flow characteristics of rotating spheres in the subcritical Reynolds number (Re) regime by measuring the drag and lift forces on the sphere and the two-dimensional velocity in the wake. The experiment is conducted in a wind tunnel at Re = 0 . 6 ×105 - 2 . 6 ×105 and the spin ratio (ratio of surface velocity to the free-stream velocity) of 0 (no spin) - 0.5. The drag coefficient on a stationary sphere remains nearly constant at around 0.52. However, the magnitude of lift coefficient is nearly zero at Re Magnus effect, depending on the magnitudes of the Reynolds number and spin ratio. The velocity field measured from a particle image velocimetry (PIV) indicates that non-zero lift coefficient on a stationary sphere at Re > 2 . 0 ×105 results from the asymmetry of separation line, whereas the inverse Magnus effect for the rotating sphere results from the differences in the boundary-layer growth and separation along the upper and lower sphere surfaces. Supported by the WCU, Converging Research Center and Priority Research Centers Program, NRF, MEST, Korea.

  20. Genesis of public administration in sphere of civil protection in Ukraine during its independent years

    Directory of Open Access Journals (Sweden)

    O. A. Podskal’na

    2016-08-01

    On December 24, 2012 the Ministry of Emergencies of Ukraine and the State Inspectorate of technological security of Ukraine had been reorganized into the State Emergency Service of Ukraine (hereinafter - the SES of Ukraine, which was coordinated by the Cabinet of Ministers of Ukraine through the Minister of Defense of Ukraine (since April 25, 2014 it is coordinated by the Cabinet of Ministers of Ukraine through the Minister of Interior of Ukraine The responsibility of SES of Ukraine is to implement the state policy in the sphere of civil protection of population and territories from emergency situations, to prevent, to respond emergently, to rescue, to firefight, to maintain fire and technological safety, to provide search and rescue service and hydrometeorological activity. Positive experience of public administration in the sphere of civil protection, which has been gained in Ukraine, will be useful in the further reform of the civil protection according to the European standards.

  1. Ex vivo radiographic tooth length measurements with the reference sphere method (RSM).

    Science.gov (United States)

    Roeder, Felix; Brüllmann, Dan; d'Hoedt, Bernd; Schulze, Ralf

    2010-12-01

    A reference-based radiographic "reference sphere method" (RSM) for accurate length measurements in (dental) projection radiographs for the assessment of tooth length in dry human mandible sections is evaluated. RSM determines the depth coordinates of reference spheres placed in the object plane from the elliptical distortion of their shadows. Two segments (one canine and one molar) of dry human mandibles were exposed 95 times at different angulations (0-40°) on a dental charge-coupled device receptor. Three steel spheres (diameters d (1) = 2.00 mm, d (2) = 3.00 mm) were attached roughly coplanar with the tooth's main axis. Radiographs were assessed once by visual inspection plus manual landmark identification with a mouse-driven cursor. The results were compared to the true tooth length assessed after extraction and to a conventional method (C), i.e., the rule of proportion based on magnification of the sphere shadows. Mean relative length error was 2.28% (d (1)) and 0.46% (d (2)) for RSM and -13.58% (d (1)) and -9.90% (d (2)) for C. For both methods, length errors were significantly (p correction of objects coplanar with the reference spheres. Remaining errors are mainly due to incorrect landmark definition. In our setup, these were exaggerated by the visual/manual image-evaluation process. Automated image analysis has been shown for similar tasks to minimize these errors considerably.

  2. The Separate Spheres Model of Gendered Inequality.

    Directory of Open Access Journals (Sweden)

    Andrea L Miller

    Full Text Available Research on role congruity theory and descriptive and prescriptive stereotypes has established that when men and women violate gender stereotypes by crossing spheres, with women pursuing career success and men contributing to domestic labor, they face backlash and economic penalties. Less is known, however, about the types of individuals who are most likely to engage in these forms of discrimination and the types of situations in which this is most likely to occur. We propose that psychological research will benefit from supplementing existing research approaches with an individual differences model of support for separate spheres for men and women. This model allows psychologists to examine individual differences in support for separate spheres as they interact with situational and contextual forces. The separate spheres ideology (SSI has existed as a cultural idea for many years but has not been operationalized or modeled in social psychology. The Separate Spheres Model presents the SSI as a new psychological construct characterized by individual differences and a motivated system-justifying function, operationalizes the ideology with a new scale measure, and models the ideology as a predictor of some important gendered outcomes in society. As a first step toward developing the Separate Spheres Model, we develop a new measure of individuals' endorsement of the SSI and demonstrate its reliability, convergent validity, and incremental predictive validity. We provide support for the novel hypotheses that the SSI predicts attitudes regarding workplace flexibility accommodations, income distribution within families between male and female partners, distribution of labor between work and family spheres, and discriminatory workplace behaviors. Finally, we provide experimental support for the hypothesis that the SSI is a motivated, system-justifying ideology.

  3. The Separate Spheres Model of Gendered Inequality

    Science.gov (United States)

    Miller, Andrea L.; Borgida, Eugene

    2016-01-01

    Research on role congruity theory and descriptive and prescriptive stereotypes has established that when men and women violate gender stereotypes by crossing spheres, with women pursuing career success and men contributing to domestic labor, they face backlash and economic penalties. Less is known, however, about the types of individuals who are most likely to engage in these forms of discrimination and the types of situations in which this is most likely to occur. We propose that psychological research will benefit from supplementing existing research approaches with an individual differences model of support for separate spheres for men and women. This model allows psychologists to examine individual differences in support for separate spheres as they interact with situational and contextual forces. The separate spheres ideology (SSI) has existed as a cultural idea for many years but has not been operationalized or modeled in social psychology. The Separate Spheres Model presents the SSI as a new psychological construct characterized by individual differences and a motivated system-justifying function, operationalizes the ideology with a new scale measure, and models the ideology as a predictor of some important gendered outcomes in society. As a first step toward developing the Separate Spheres Model, we develop a new measure of individuals’ endorsement of the SSI and demonstrate its reliability, convergent validity, and incremental predictive validity. We provide support for the novel hypotheses that the SSI predicts attitudes regarding workplace flexibility accommodations, income distribution within families between male and female partners, distribution of labor between work and family spheres, and discriminatory workplace behaviors. Finally, we provide experimental support for the hypothesis that the SSI is a motivated, system-justifying ideology. PMID:26800454

  4. The Separate Spheres Model of Gendered Inequality.

    Science.gov (United States)

    Miller, Andrea L; Borgida, Eugene

    2016-01-01

    Research on role congruity theory and descriptive and prescriptive stereotypes has established that when men and women violate gender stereotypes by crossing spheres, with women pursuing career success and men contributing to domestic labor, they face backlash and economic penalties. Less is known, however, about the types of individuals who are most likely to engage in these forms of discrimination and the types of situations in which this is most likely to occur. We propose that psychological research will benefit from supplementing existing research approaches with an individual differences model of support for separate spheres for men and women. This model allows psychologists to examine individual differences in support for separate spheres as they interact with situational and contextual forces. The separate spheres ideology (SSI) has existed as a cultural idea for many years but has not been operationalized or modeled in social psychology. The Separate Spheres Model presents the SSI as a new psychological construct characterized by individual differences and a motivated system-justifying function, operationalizes the ideology with a new scale measure, and models the ideology as a predictor of some important gendered outcomes in society. As a first step toward developing the Separate Spheres Model, we develop a new measure of individuals' endorsement of the SSI and demonstrate its reliability, convergent validity, and incremental predictive validity. We provide support for the novel hypotheses that the SSI predicts attitudes regarding workplace flexibility accommodations, income distribution within families between male and female partners, distribution of labor between work and family spheres, and discriminatory workplace behaviors. Finally, we provide experimental support for the hypothesis that the SSI is a motivated, system-justifying ideology.

  5. RUN COORDINATION

    CERN Multimedia

    C. Delaere

    2013-01-01

    Since the LHC ceased operations in February, a lot has been going on at Point 5, and Run Coordination continues to monitor closely the advance of maintenance and upgrade activities. In the last months, the Pixel detector was extracted and is now stored in the pixel lab in SX5; the beam pipe has been removed and ME1/1 removal has started. We regained access to the vactank and some work on the RBX of HB has started. Since mid-June, electricity and cooling are back in S1 and S2, allowing us to turn equipment back on, at least during the day. 24/7 shifts are not foreseen in the next weeks, and safety tours are mandatory to keep equipment on overnight, but re-commissioning activities are slowly being resumed. Given the (slight) delays accumulated in LS1, it was decided to merge the two global runs initially foreseen into a single exercise during the week of 4 November 2013. The aim of the global run is to check that we can run (parts of) CMS after several months switched off, with the new VME PCs installed, th...

  6. RUN COORDINATION

    CERN Multimedia

    Christophe Delaere

    2013-01-01

    The focus of Run Coordination during LS1 is to monitor closely the advance of maintenance and upgrade activities, to smooth interactions between subsystems and to ensure that all are ready in time to resume operations in 2015 with a fully calibrated and understood detector. After electricity and cooling were restored to all equipment, at about the time of the last CMS week, recommissioning activities were resumed for all subsystems. On 7 October, DCS shifts began 24/7 to allow subsystems to remain on to facilitate operations. That culminated with the Global Run in November (GriN), which   took place as scheduled during the week of 4 November. The GriN has been the first centrally managed operation since the beginning of LS1, and involved all subdetectors but the Pixel Tracker presently in a lab upstairs. All nights were therefore dedicated to long stable runs with as many subdetectors as possible. Among the many achievements in that week, three items may be highlighted. First, the Strip...

  7. Thermodynamic properties of non-conformal soft-sphere fluids with effective hard-sphere diameters.

    Science.gov (United States)

    Rodríguez-López, Tonalli; del Río, Fernando

    2012-01-28

    In this work we study a set of soft-sphere systems characterised by a well-defined variation of their softness. These systems represent an extension of the repulsive Lennard-Jones potential widely used in statistical mechanics of fluids. This type of soft spheres is of interest because they represent quite accurately the effective intermolecular repulsion in fluid substances and also because they exhibit interesting properties. The thermodynamics of the soft-sphere fluids is obtained via an effective hard-sphere diameter approach that leads to a compact and accurate equation of state. The virial coefficients of soft spheres are shown to follow quite simple relationships that are incorporated into the equation of state. The approach followed exhibits the rescaling of the density that produces a unique equation for all systems and temperatures. The scaling is carried through to the level of the structure of the fluids.

  8. Scattering by two spheres: Theory and experiment

    DEFF Research Database (Denmark)

    Bjørnø, Irina; Jensen, Leif Bjørnø

    1998-01-01

    of suspended sediments. The scattering properties of single regular-shaped particles have been studied in depth by several authors in the past. However, single particle scattering cannot explain all features of scattering by suspended sediment. When the concentration of particles exceeds a certain limit......, multiple particle scattering becomes important. As a first step in the investigation of mutual interactions between several particles, the acoustical scattering by two spheres has been studied theoretically and experimentally and the results are reported in this paper. The study has mainly been focused...... on three issues: (1) to develop a simplified theory for scattering by two elastical spheres; (2) to measure the scattering by two spheres in a water tank, and (3) to compare the theoretical/numerical results with the measured data. A number of factors influencing multiple scattering, including...

  9. Silo outflow of soft frictionless spheres

    Science.gov (United States)

    Ashour, Ahmed; Trittel, Torsten; Börzsönyi, Tamás; Stannarius, Ralf

    2017-12-01

    Outflow of granular materials from silos is a remarkably complex physical phenomenon that has been extensively studied with simple objects like monodisperse hard disks in two dimensions (2D) and hard spheres in 2D and 3D. For those materials, empirical equations were found that describe the discharge characteristics. Softness adds qualitatively new features to the dynamics and to the character of the flow. We report a study of the outflow of soft, practically frictionless hydrogel spheres from a quasi-2D bin. Prominent features are intermittent clogs, peculiar flow fields in the container, and a pronounced dependence of the flow rate and clogging statistics on the container fill height. The latter is a consequence of the ineffectiveness of Janssen's law: the pressure at the bottom of a bin containing hydrogel spheres grows linearly with the fill height.

  10. Glass transition in soft-sphere dispersions

    International Nuclear Information System (INIS)

    RamIrez-Gonzalez, P E; Medina-Noyola, M

    2009-01-01

    The concept of dynamic equivalence among mono-disperse soft-sphere fluids is employed in the framework of the self-consistent generalized Langevin equation (SCGLE) theory of colloid dynamics to calculate the ideal glass transition phase diagram of model soft-sphere colloidal dispersions in the softness-concentration state space. The slow dynamics predicted by this theory near the glass transition is compared with available experimental data for the decay of the intermediate scattering function of colloidal dispersions of soft-microgel particles. Increasing deviations from this simple scheme occur for increasingly softer potentials, and this is studied here using the Rogers-Young static structure factor of the soft-sphere systems as the input of the SCGLE theory, without assuming a priori the validity of the equivalence principle above.

  11. The Positive Freedom of the Public Sphere

    DEFF Research Database (Denmark)

    Hansen, Ejvind

    2015-01-01

    calls for new reflections on the possible relationship between media, public sphere and democracy. This paper argues that we should change the questions that are raised when we try to assess the public sphere. It is argued that the traditional (Enlightenment) focus upon negative liberties and the truth......-value of utterances is not adequate. Negative freedom and truth are certainly important in the public sphere, because they are necessary conditions for taking a qualified stance towards the challenges that we face. It is, however, important also to reflect on what negative liberties are used for—which kinds of truths...... are articulated in public discussions. To answer this question it is argued that it is important to distinguish between affirmative truths and liberating truths (based on courage), the latter being what is required in democratic dialogues....

  12. Depletion zones and crystallography on pinched spheres

    Science.gov (United States)

    Chen, Jingyuan; Xing, Xiangjun; Yao, Zhenwei

    2018-03-01

    Understanding the interplay between ordered structures and substrate curvature is an interesting problem with versatile applications, including functionalization of charged supramolecular surfaces and modern microfluidic technologies. In this work, we investigate the two-dimensional packing structures of charged particles confined on a pinched sphere. By continuously pinching the sphere, we observe cleavage of elongated scars into pleats, proliferation of disclinations, and subsequently, emergence of a depletion zone at the negatively curved waist that is completely void of particles. We systematically study the geometrics and energetics of the depletion zone, and reveal its physical origin as a finite size effect, due to the interplay between Coulomb repulsion and concave geometry of the pinched sphere. These results further our understanding of crystallography on curved surfaces, and have implications in design and manipulation of charged, deformable interfaces in various applications.

  13. Does Negative Type Characterize the Round Sphere?

    DEFF Research Database (Denmark)

    Kokkendorff, Simon Lyngby

    2007-01-01

    We discuss the measure theoretic metric invariants extent, mean distance and symmetry ratio and their relation to the concept of negative type of a metric space. A conjecture stating that a compact Riemannian manifold with symmetry ratio 1 must be a round sphere, was put forward in a previous paper....... We resolve this conjecture in the class of Riemannian symmetric spaces by showing, that a Riemannian manifold with symmetry ratio 1 must be of negative type and that the only compact Riemannian symmetric spaces of negative type are the round spheres....

  14. vSphere design best practices

    CERN Document Server

    Bolander, Brian

    2014-01-01

    An easy-to-follow guide full of hands-on examples of real-world design best practices. Each topic is explained and placed in context, and for the more inquisitive, there are more details on the concepts used.If you wish to learn about vSphere best practices and how to apply them when designing virtual, high performance, reliable datacenters that support business critical applications to work more efficiently and to prepare for official certifications, this is the book for you. Readers should possess a good working knowledge of vSphere as well as servers, storage, and networking.

  15. Preliminary evaluation of glipizide spheres and compacts from spheres prepared by cross-linking technique.

    Science.gov (United States)

    Garcia, J G; Ghaly, E S

    2001-03-01

    The objective of this research was to use the natural polymer Carrageenan to obtain controlled release spheres loaded with glipizide using the cross-linking technique. The effect of polymer level and drug load were investigated. The drug was dispersed in Carrageenan solution and the dispersion was dropped by a device containing 3 disposable syringes into cross-linking solution containing 3% calcium chloride. After 15 minutes residence time, the spheres were collected by decantation and dried in hot air oven at 38 degrees C +/- 2 degrees C for 24 hours. The dried spheres were successfully compacted into tablets using rotary Manesty B-3B machine equipped with 12/32 inches round flat face punches, target tablet weight was 400 mg +/- 5%. As the polymer level was increased in the sphere formulation, the drug release rate was increased. However, as the drug level was increased in the sphere formulation, the release rate was decreased. This trend was also true for tablets compacted from spheres. The scanning electron microscope photographs supported the dissolution data. More cracks and rough surface were observed in tablets compacted from spheres containing high polymer level and low drug level.

  16. Wall effects on a rotating sphere

    NARCIS (Netherlands)

    Liu, Qianlong; Prosperetti, Andrea

    2010-01-01

    The flow induced by a spherical particle spinning in the presence of no-slip planar boundaries is studied by numerical means. In addition to the reference case of an infinite fluid, the situations considered include a sphere rotating near one or two infinite plane walls parallel or perpendicular to

  17. Log Gaussian Cox processes on the sphere

    DEFF Research Database (Denmark)

    Pacheco, Francisco Andrés Cuevas; Møller, Jesper

    We define and study the existence of log Gaussian Cox processes (LGCPs) for the description of inhomogeneous and aggregated/clustered point patterns on the d-dimensional sphere, with d = 2 of primary interest. Useful theoretical properties of LGCPs are studied and applied for the description of sky...

  18. Steel Spheres and Skydiver--Terminal Velocity

    Science.gov (United States)

    Costa Leme, J.; Moura, C.; Costa, Cintia

    2009-01-01

    This paper describes the use of open source video analysis software in the study of the relationship between the velocity of falling objects and time. We discuss an experiment in which a steel sphere falls in a container filled with two immiscible liquids. The motion is similar to that of a skydiver falling through air.

  19. Physics of the granite sphere fountain

    NARCIS (Netherlands)

    Snoeijer, Jacobus Hendrikus; van der Weele, J.P.

    2014-01-01

    A striking example of levitation is encountered in the “kugel fountain” where a granite sphere, sometimes weighing over a ton, is kept aloft by a thin film of flowing water. In this paper, we explain the working principle behind this levitation. We show that the fountain can be viewed as a giant

  20. Performance and Politics in the Public Sphere

    Directory of Open Access Journals (Sweden)

    Pia Wiegmink

    2011-12-01

    Full Text Available Pia Wiegmink’s timely examination of the transforming transnational spaces of protest in a globalizing and technologically mediated public sphere in “Performance and Politics in the Public Sphere” offers a well-researched review of contemporary theory surrounding ideas of the political (Chantal Mouffe, the public sphere (Jürgen Habermas, the transnational public sphere (Nancy Fraser, and the reterritorialized transnational public sphere (Markus Schroer as the basis for her analysis of how the performance of political action in public—virtual or physical—is transformed by the capacity of the local to be played on a global stage, thus turning the citizen-actor into a cosmopolitan, transnational force. Tracing examples from the Seattle protests against the World Trade Organization meetings in 1999 by the Global Justice Movement to the work of the Electronic Disturbance Theater, from the civil rights movement to the subject matter of her larger study, “The Church of Life After Shopping,” “Billionaires for Bush,” and “The Yes Men,” Wiegmink provides an important analysis of the “alternative aesthetics” of the counterpublics’ formation, dissent, and action in and against hegemony. This selection is taken from her monograph, Protest EnACTed: Activist Performance in the Contemporary United States, a strong, cultural studies–focused contribution to transnational American Studies.

  1. Performance and Politics in the Public Sphere

    Directory of Open Access Journals (Sweden)

    Pia Wiegmink

    2011-12-01

    Full Text Available Pia Wiegmink’s timely examination of the transforming transnational spaces of protest in a globalizing and technologically mediated public sphere in “Performance and Politics in the Public Sphere” offers a well-researched review of contemporary theory surrounding ideas of the political (Chantal Mouffe, the public sphere (Jürgen Habermas, the transnational public sphere (Nancy Fraser, and the reterritorialized transnational public sphere (Markus Schroer as the basis for her analysis of how the performance of political action in public—virtual or physical—is transformed by the capacity of the local to be played on a global stage, thus turning the citizen-actor into a cosmopolitan, transnational force. Tracing examples from the Seattle protests against the World Trade Organization meetings in 1999 by the Global Justice Movement to the work of the Electronic Disturbance Theater, from the civil rights movement to the subject matter of her larger study, “The Church of Life After Shopping,” “Billionaires for Bush,” and “The Yes Men,” Wiegmink provides an important analysis of the “alternative aesthetics” of the counterpublics’ formation, dissent, and action in and against hegemony. This selection is taken from her monograph, Protest EnACTed: Activist Performance in the Contemporary United States, a strong, cultural studies–focused contribution to transnational American Studies.

  2. On the torus cobordant cohomology spheres

    Indian Academy of Sciences (India)

    Is it true that for any smooth action of on a homotopy sphere with exactly two fixed points, the tangent -modules at these two points are isomorphic?" A result due to Atiyah and Bott proves that the answer is `yes' for Z Z p and it is also known ...

  3. New interior solution describing relativistic fluid sphere

    Indian Academy of Sciences (India)

    General relativity; exact solution; embedding class I; anisotropy; compact star. Abstract. Anewexact solution of embedding class I is presented for a relativistic anisotropicmassive fluid sphere. The new exact solution satisfies Karmarkar condition, is well-behaved in all respects, and therefore is suitable for the modelling of ...

  4. Art, politics and the public sphere

    NARCIS (Netherlands)

    Gielen, Pascal

    2014-01-01

    Contemporary art, with its foundation in the modern age, can merely exist by the grace of a political democracy; a democracy that in turn only exists by the grace of there being a public domain. Also, political democracy makes it possible for art to play a part in the public sphere and at the same

  5. Models of diffusive noise on the sphere

    International Nuclear Information System (INIS)

    Spina, M E; Saraceno, M

    2004-01-01

    We analyse Haake et al method for coarse graining quantum maps on the sphere from the point of view of realizable physical quantum operations achieved with completely positive superoperators. We conclude that sharp truncations in the style of Haake do not fall into this class. (letter to the editor)

  6. New interior solution describing relativistic fluid sphere

    Indian Academy of Sciences (India)

    Anewexact solution of embedding class I is presented for a relativistic anisotropicmassive fluid sphere. The new exact solution satisfies Karmarkar condition, is well-behaved in all respects, and therefore is suitable for the modelling of superdense stars. Consequently, using this solution, we have studied in detail two ...

  7. Stacked spheres and lower bound theorem

    Indian Academy of Sciences (India)

    BASUDEB DATTA

    2011-11-20

    Nov 20, 2011 ... Preliminaries. Lower bound theorem. On going work. Definitions. An n-simplex is a convex hull of n + 1 affinely independent points. (called vertices) in some Euclidean space R. N . Stacked spheres and lower bound theorem. Basudeb Datta. Indian Institute of Science. 2 / 27 ...

  8. Institutional change and spheres of authority

    DEFF Research Database (Denmark)

    Aagaard, Peter

    institutioner. Denne tilgang bidrager til at udvikle global governance begrebet "spheres of authority" Det forklarer hvordan transnational lederskab kan bevares, selv om magten spredes i en globaliseret verden. Gennem en illustrativ case om microcredit, viser artiklen hvordan en tilgang baseret på institutional...

  9. Pious Entertainment: Hizbullah's Islamic Cultural Sphere

    NARCIS (Netherlands)

    Alagha, J.E.; Nieuwkerk, K. van

    2011-01-01

    Alagha’s chapter on Hezbollah’s Islamic cultural sphere is sure to generate some of the most interesting discussion. Lebanon and Hezbollah in particular are among the hottest topics in the studies of contemporary Islam, but few people actually have the appropriate levels of both access to and

  10. The Dirac operator on the Fuzzy sphere

    International Nuclear Information System (INIS)

    Grosse, H.

    1994-01-01

    We introduce the Fuzzy analog of spinor bundles over the sphere on which the non-commutative analog of the Dirac operator acts. We construct the complete set of eigenstates including zero modes. In the commutative limit we recover known results. (authors)

  11. Spheres: from Ground Development to ISS Operations

    Science.gov (United States)

    Katterhagen, A.

    2016-01-01

    SPHERES (Synchronized Position Hold Engage and Reorient Experimental Satellites) is an internal International Space Station (ISS) Facility that supports multiple investigations for the development of multi-spacecraft and robotic control algorithms. The SPHERES National Lab Facility aboard ISS is managed and operated by NASA Ames Research Center (ARC) at Moffett Field California. The SPHERES Facility on ISS consists of three self-contained eight-inch diameter free-floating satellites which perform the various flight algorithms and serve as a platform to support the integration of experimental hardware. SPHERES has served to mature the adaptability of control algorithms of future formation flight missions in microgravity (6 DOF (Degrees of Freedom) / long duration microgravity), demonstrate key close-proximity formation flight and rendezvous and docking maneuvers, understand fault diagnosis and recovery, improve the field of human telerobotic operation and control, and lessons learned on ISS have significant impact on ground robotics, mapping, localization, and sensing in three-dimensions - among several other areas of study.

  12. Micro sphere with nanoporosity by electrospinning

    International Nuclear Information System (INIS)

    He Jihuan; Liu Yong; Xu Lan; Yu Jianyong

    2007-01-01

    Nanoporous structures are potentially of great technological interest for the development of electronic, catalytic and hydrogen-storage systems, invisibility device (e.g. stealth plane) and others. Here we describe a general strategy for the synthesis of micro sphere with nanoporosity by electrospinning, the porous sizes having uniform but tunable diameters can be controlled by voltage applied in the electrospinning process

  13. Production of Liquid Metal Spheres by Molding

    Directory of Open Access Journals (Sweden)

    Mohammed G. Mohammed

    2014-10-01

    Full Text Available This paper demonstrates a molding technique for producing spheres composed of eutectic gallium-indium (EGaIn with diameters ranging from hundreds of microns to a couple millimeters. The technique starts by spreading EGaIn across an elastomeric sheet featuring cylindrical reservoirs defined by replica molding. The metal flows into these features during spreading. The spontaneous formation of a thin oxide layer on the liquid metal keeps the metal flush inside these reservoirs. Subsequent exposure to acid removes the oxide and causes the metal to bead up into a sphere with a size dictated by the volume of the reservoirs. This technique allows for the production and patterning of droplets with a wide range of volumes, from tens of nanoliters up to a few microliters. EGaIn spheres can be embedded or encased subsequently in polymer matrices using this technique. These spheres may be useful as solder bumps, electrodes, thermal contacts or components in microfluidic devices (valves, switches, pumps. The ease of parallel-processing and the ability to control the location of the droplets during their formation distinguishes this technique.

  14. Ligand sphere conversions in terminal carbide complexes

    DEFF Research Database (Denmark)

    Morsing, Thorbjørn Juul; Reinholdt, Anders; Sauer, Stephan P. A.

    2016-01-01

    Metathesis is introduced as a preparative route to terminal carbide complexes. The chloride ligands of the terminal carbide complex [RuC(Cl)2(PCy3)2] (RuC) can be exchanged, paving the way for a systematic variation of the ligand sphere. A series of substituted complexes, including the first exam...

  15. Piezoelectric hollow sphere transducers: The 'BBs'

    Science.gov (United States)

    Alkoy, Sedat

    This thesis describes the design, fabrication, modeling and device characteristics of ultrasound transducers developed from millimeter size piezoelectric ceramic hollow spheres. Green ceramic hollow spheres were produced using a coaxial nozzle slurry process and a sacrificial core coating process in the size range of 1-6 mm in diameter and 12-200 μm in wall thickness. Ceramic powders with the morphotropic phase boundary compositions of lead zirconate titanate solid solution known as PZT-4 and PZT-5A, and a modified lead titanate composition were used in these two processes. After sintering, the desired shapes were obtained by drilling, grinding, or polishing. Sphere surfaces were then coated with an electrode material in desired shapes and area of coverage. Two main poling configurations were studied: a radial poling configuration with inside and outside electrodes, and a tangential poling with top and bottom outside electrodes with several different electrode patterns. Dielectric, piezoelectric and ferroelectric properties of these transducers were measured. Vibration modes were determined using the ATILA™ finite element analysis (FEA) code, and associated resonance frequencies were measured and compared to the calculated values. The effect of sphere dimensions, materials and electrode configurations were analyzed using FEA. It was determined from the finite elements analysis of the structure that wall thickness variations do not have a pronounced affect on the vibrations of the structure at lower frequencies (from kHz to low MHz). Focused transducers were prepared for biomedical ultrasound imaging from dish-shape shell sections of the hollow spheres. Pulse-echo characteristics such as, insertion loss, waveform and bandwidth were measured. These transducers were also modeled using the FEA. Transducer operation frequencies of up to 50 MHz were achieved with f-numbers down to 1. Omnidirectional miniature hydrophones were prepared from radially poled hollow

  16. SPHERES: Synchronized, Position, Hold, Engage, Reorient, Experimental Satellites: SPHERES/Astrobee Working Group (SAWG)

    Science.gov (United States)

    Benavides, Jose

    2017-01-01

    SPHERES/Astrobee Working Group (SAWG) Quarterly meeting. Membership includes MIT, FIT, AFS, DARPA, CASIS, SJSU, and NASA (HQ, KSC, JSC, MSFC, and ARC)Face-to-Face, twice a year Purpose: Information sharing across the SPHERES community Program office shares National Lab Facility availability Status of resources (batteries, CO2 tanks, etc.), Overall Calendar (scheduled Test Sessions, up mass return), and Updates on new PD, Investigations, and ISS infrastructure. Provide the SPHERES community (PD, investigators, etc.) with up-to-date information to determine opportunities to use the NL Facility Discuss proposed changes updates to SPHERES Nat Lab which may be required to support a specific activity or research. Discuss specific support requests made to the ISS Office.

  17. Revitalization of the Public Sphere: A Comparison between Habermasian and the New Public Sphere

    Directory of Open Access Journals (Sweden)

    Muhammad Zubair Khan

    2014-06-01

    Full Text Available “Public sphere” is an important component of modern polity. Civil society brings the state in touch with the needs of the citizens through the medium of public sphere. However, Habermas argues that “public sphere” experienced refeudalization owing to various factors i.e. propaganda, cultural industry, market and state intervention. The “public” was condemned to be mere spectator again. This article argues that modern technologies enabled new public sphere (NPS can help restore public status as participant in the democratic process. By employing interpretivist approach the article compares the Habermasian ideal of public sphere with NPS and constructs a matrix, depicting the various related aspects between the two models for highlighting the revival of the public sphere.

  18. VMware vSphere PowerCLI Reference Automating vSphere Administration

    CERN Document Server

    Dekens, Luc; Sizemore, Glenn; van Lieshout, Arnim; Medd, Jonathan

    2011-01-01

    Your One-Stop Reference for VMware vSphere Automation If you manage vSphere in a Windows environment, automating routine tasks can save you time and increase efficiency. VMware vSphere PowerCLI is a set of pre-built commands based on Windows PowerShell that is designed to help you automate vSphere processes involving virtual machines, datacenters, storage, networks, and more. This detailed guide-using a practical, task-based approach and real-world examples-shows you how to get the most out of PowerCLI's handy cmdlets. Learn how to: Automate vCenter Server and ESX/ESX(i) Server deployment and

  19. Component-Customizable Porous Rare-Earth-Based Colloidal Spheres towards Highly Effective Catalysts and Bioimaging Applications.

    Science.gov (United States)

    Li, Cheng Chao; Rui, Xianhong; Wei, Weifeng; Chen, Libao; Yu, Yan

    2017-11-16

    Multicomponent porous colloidal spheres are of interest because they not only show a combination of the properties associated with all different components, but also usually present synergy effects. However, a combination of different components in a single porous sphere is still greatly challenged due to the different precipitation behaviors of each component. In this work, we have developed a general synthetic route to prepare several categories of porous monodisperse rare-earth (RE)-based colloidal spheres with customizable elemental compositions and a uniform element distribution. The two-step synthetic strategy is based on the integration of coordination chemistry precipitation of RE ions and a subsequent ion-exchange process, which steers clear of obstacles, such as differences in solubility product constant, that are to be found in traditional co-precipitation methods. Our approach provides a new mixing mechanism to realize homogeneous distribution of each element within the porous spheres. An array of binary, ternary, and even senary RE colloidal porous spheres with diameters of 500 nm to 700 nm has been successfully synthesized. Taking advantage of their good dispersibility, porosity, and customizable components, these porous RE oxide spheres show excellent catalytic activity for the reduction of 4-nitrophenol, and promising application in single-phase multifunctional bioprobes. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Modelling laminar transport phenomena in a Casson rheological fluid from an isothermal sphere with partial slip

    Directory of Open Access Journals (Sweden)

    Subbarao Annasagaram

    2015-01-01

    Full Text Available The laminar boundary layer flow and heat transfer of Casson non-Newtonian fluid from a permeable isothermal sphere in the presence of thermal and hydrodynamic slip conditions is analyzed. The surface of the sphere is maintained at a constant temperature. The boundary layer conservation equations, which are parabolic in nature, are normalized into non-similar form and then solved numerically with the well-tested, efficient, implicit, stable Keller-box finite-difference scheme. Increasing velocity slip induces acceleration in the flow near the surface of the sphere and the reverse effect further from the surface. Increasing velocity slip consistently enhances temperatures throughout the boundary layer regime. An increase in thermal slip parameter strongly decelerates the flow and also reduces temperatures in the boundary layer regime. An increase in Casson rheological parameter acts to elevate considerably the skin friction (non-dimensional wall shear stress and this effect is pronounced at higher values of tangential coordinate. Temperatures are however very slightly decreased with increasing values of Casson rheological parameter. Increasing mass flow injection (blowing at the sphere surface causes a strong acceleration, whereas increasing suction is found to induce the opposite effect. The study finds applications in rheological chocolate food processing.

  1. Innovation embedded in entrepreneurs' networks in private and public spheres

    DEFF Research Database (Denmark)

    Schøtt, Thomas; Cheraghi, Maryam; Rezaei, Shahamak

    2014-01-01

    Global studies have found tendencies: traditional culture promotes entrepreneurs' networking in the private sphere, impeding innovation, whereas secular-rational culture facilitates networking in the public sphere, benefiting innovation. This embeddedness is here scrutinised in contrasting...

  2. Cavity formation by the impact of Leidenfrost spheres

    KAUST Repository

    Marston, Jeremy

    2012-05-01

    We report observations of cavity formation and subsequent collapse when a heated sphere impacts onto a liquid pool. When the sphere temperature is much greater than the boiling point of the liquid, we observe an inverted Leidenfrost effect where the sphere is encompassed by a vapour layer that prevents physical contact with the liquid. This creates the ultimate non-wetting scenario during sphere penetration through a free surface, producing very smooth cavity walls. In some cases during initial entry, however, the liquid contacts the sphere at the equator, leading to the formation of a dual cavity structure. For cold sphere impacts, where a contact line is observed, we reveal details of the contact line pinning, which initially forms a sawtooth pattern. We also observe surface waves on the cavity interface for cold spheres. We compare our experimental results to previous studies of cavity dynamics and, in particular, the influence of hydrophobicity on the entry of the sphere. © 2012 Cambridge University Press.

  3. Random sequential addition of hard spheres in high Euclidean dimensions

    Science.gov (United States)

    Torquato, S.; Uche, O. U.; Stillinger, F. H.

    2006-12-01

    Sphere packings in high dimensions have been the subject of recent theoretical interest. Employing numerical and theoretical methods, we investigate the structural characteristics of random sequential addition (RSA) of congruent spheres in d -dimensional Euclidean space Rd in the infinite-time or saturation limit for the first six space dimensions (1≤d≤6) . Specifically, we determine the saturation density, pair correlation function, cumulative coordination number and the structure factor in each of these dimensions. We find that for 2≤d≤6 , the saturation density ϕs scales with dimension as ϕs=c1/2d+c2d/2d , where c1=0.202048 and c2=0.973872 . We also show analytically that the same density scaling is expected to persist in the high-dimensional limit, albeit with different coefficients. A byproduct of this high-dimensional analysis is a relatively sharp lower bound on the saturation density for any d given by ϕs≥(d+2)(1-S0)/2d+1 , where S0ɛ[0,1] is the structure factor at k=0 (i.e., infinite-wavelength number variance) in the high-dimensional limit. We demonstrate that a Palàsti-type conjecture (the saturation density in Rd is equal to that of the one-dimensional problem raised to the d th power) cannot be true for RSA hyperspheres. We show that the structure factor S(k) must be analytic at k=0 and that RSA packings for 1≤d≤6 are nearly “hyperuniform.” Consistent with the recent “decorrelation principle,” we find that pair correlations markedly diminish as the space dimension increases up to six. We also obtain kissing (contact) number statistics for saturated RSA configurations on the surface of a d -dimensional sphere for dimensions 2≤d≤5 and compare to the maximal kissing numbers in these dimensions. We determine the structure factor exactly for the related “ghost” RSA packing in Rd and demonstrate that its distance from “hyperuniformity” increases as the space dimension increases, approaching a constant asymptotic value

  4. Transformation procedures in 3D terrestrial coordinate systems

    Directory of Open Access Journals (Sweden)

    Sedlák Vladimír

    2001-12-01

    Full Text Available Transformation procedures belong to the main tasks of surveyor working in a field of geodesy, for example in satellite geodesy or astronomical geodesy. It is necessary to know transformation procedures in 3D terrestrial (Earth coordinate systems. Increasingly a dynamic advance growth of application of satellite navigation systems, for example GPS (Global Positioning System into engineering surveying, real estate register and others spheres of applied geodesy and geo-surveying (mine surveying exacts knowledge of these transformation procedures between coordinates in various coordinate systems. These tasks are common for daily work for various practical surveyors too, not only for theoretical scientific working surveyors.Conventional Terrestrial System is 3D coordinate system what is the most important coordinate system in global geodesy. Conventional Terrestrial System is an approximation of the nature coordinate system of the Earth. The origin of this coordinate system is placed in the earth substantial centre of gravity and in the centre of geoid. Conventional Terrestrial System is the Cartesian right-handed coordinate system, i.e. positive one. The Local Astronomical System is 3D coordinate system too and it belongs to an important coordinate system in geodesy from its practical point of view. Many geodetic measurements are realized in this coordinate system. Designation of this coordinate system as astronomical system expresses its sticking to a normal line to an equipotential plane, i.e. to a vertical. Local Astronomical system is the left-handed cartesian coordinate system.Transformation procedures in 3D terrestrial coordinate systems with theory of these systems are presented in the paper. Transformation in the local astronomical coordinate system presents common transformation in a frame of an adjustment of various local geodetic networks. In a case of satellite measurements (GPS, satellite altimetry, etc. transformation between local and

  5. Innovation embedded in entrepreneurs’ networks in private and public spheres

    DEFF Research Database (Denmark)

    Schøtt, Thomas; Cheraghi, Maryam; Rezaei, Shahamak

    2014-01-01

    societies, China and Denmark. Global Entrepreneurship Monitor has surveyed entrepreneurs in China, Denmark and elsewhere. Analyses reconfirm the global tendencies and show that, China in contrast to Denmark, public sphere networking is sparser, but private sphere networking is denser. Innovation......Global studies have found tendencies: traditional culture promotes entrepreneurs' networking in the private sphere, impeding innovation, whereas secular-rational culture facilitates networking in the public sphere, benefiting innovation. This embeddedness is here scrutinised in contrasting...

  6. 21 CFR 886.3320 - Eye sphere implant.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Eye sphere implant. 886.3320 Section 886.3320 Food... DEVICES OPHTHALMIC DEVICES Prosthetic Devices § 886.3320 Eye sphere implant. (a) Identification. An eye sphere implant is a device intended to be implanted in the eyeball to occupy space following the removal...

  7. Social movements and the Transnational Transformation of Public Spheres

    DEFF Research Database (Denmark)

    Bourne, Angela

    2017-01-01

    This article presents a theoretical framework for the empirical study of social movements as agents and arenas in the transnational transformation of public spheres. It draws on the existing literature on transnationalisation of public spheres, which predominantly focuses on the broadcast media a...... of public spheres and illustrate their applicability for the study of social movements using contemporary examples of movement practices and discourses....

  8. Criticality of a 237Np sphere

    International Nuclear Information System (INIS)

    Sanchez, Rene G.; Loaiza, David J.; Kimpland, Robert H.; Hayes, David K.; Cappiello, Charlene C.; Myers, William L.; Jaegers, Peter J.; Clement, Steven D.; Butterfield, Kenneth B.

    2003-01-01

    A critical mass experiment using a 6-kg 237 Np sphere has been performed. The purpose of the experiment is to get a better estimate of the critical mass of 237 Np. To attain criticality, the 237 Np sphere was surrounded with 93 wt% 235 U shells. A 1/M as a function of uranium mass was performed. An MCNP neutron transport code was used to model the experiment. The MCNP code yielded a k eff of 0.99089 ± 0.0003 compared with a k eff 1.0026 for the experiment. Based on these results, it is estimated that the critical mass of 237 Np ranges from kilogram weights in the high fifties to low sixties. (author)

  9. Fibonacci numerical integration on a sphere

    International Nuclear Information System (INIS)

    Hannay, J H; Nye, J F

    2004-01-01

    For elementary numerical integration on a sphere, there is a distinct advantage in using an oblique array of integration sampling points based on a chosen pair of successive Fibonacci numbers. The pattern has a familiar appearance of intersecting spirals, avoiding the local anisotropy of a conventional latitude-longitude array. Besides the oblique Fibonacci array, the prescription we give is also based on a non-uniform scaling used for one-dimensional numerical integration, and indeed achieves the same order of accuracy as for one dimension: error ∼N -6 for N points. This benefit of Fibonacci is not shared by domains of integration with boundaries (e.g., a square, for which it was originally proposed); with non-uniform scaling the error goes as N -3 , with or without Fibonacci. For experimental measurements over a sphere our prescription is realized by a non-uniform Fibonacci array of weighted sampling points

  10. Coated sphere scattering by geometric optics approximation.

    Science.gov (United States)

    Mengran, Zhai; Qieni, Lü; Hongxia, Zhang; Yinxin, Zhang

    2014-10-01

    A new geometric optics model has been developed for the calculation of light scattering by a coated sphere, and the analytic expression for scattering is presented according to whether rays hit the core or not. The ray of various geometric optics approximation (GOA) terms is parameterized by the number of reflections in the coating/core interface, the coating/medium interface, and the number of chords in the core, with the degeneracy path and repeated path terms considered for the rays striking the core, which simplifies the calculation. For the ray missing the core, the various GOA terms are dealt with by a homogeneous sphere. The scattering intensity of coated particles are calculated and then compared with those of Debye series and Aden-Kerker theory. The consistency of the results proves the validity of the method proposed in this work.

  11. Packing circles and spheres on surfaces

    KAUST Repository

    Schiftner, Alexander

    2009-12-01

    Inspired by freeform designs in architecture which involve circles and spheres, we introduce a new kind of triangle mesh whose faces\\' incircles form a packing. As it turns out, such meshes have a rich geometry and allow us to cover surfaces with circle patterns, sphere packings, approximate circle packings, hexagonal meshes which carry a torsion-free support structure, hybrid tri-hex meshes, and others. We show how triangle meshes can be optimized so as to have the incircle packing property. We explain their relation to conformal geometry and implications on solvability of optimization. The examples we give confirm that this kind of meshes is a rich source of geometric structures relevant to architectural geometry.

  12. Packing circles and spheres on surfaces

    KAUST Repository

    Schiftner, Alexander

    2009-01-01

    Inspired by freeform designs in architecture which involve circles and spheres, we introduce a new kind of triangle mesh whose faces\\' incircles form a packing. As it turns out, such meshes have a rich geometry and allow us to cover surfaces with circle patterns, sphere packings, approximate circle packings, hexagonal meshes which carry a torsion-free support structure, hybrid tri-hex meshes, and others. We show how triangle meshes can be optimized so as to have the incircle packing property. We explain their relation to conformal geometry and implications on solvability of optimization. The examples we give confirm that this kind of meshes is a rich source of geometric structures relevant to architectural geometry. © 2009 ACM.

  13. Locating a circle on a sphere

    DEFF Research Database (Denmark)

    Brimberg, Jack; Juel, Henrik; Schöbel, Anita

    2003-01-01

    We consider the problem of locating a spherical circle with respect to existing facilities on a sphere, such that the sum of weighted distances between the circle and the facilities is minimized, or such that the maximum weighted distance is minimized. The problem properties are analyzed, and we...... give solution procedures. When the circle to be located is restricted to be a great circle, some simplifications are possible....

  14. The sea - landfill or sphere of life

    International Nuclear Information System (INIS)

    Haury, H.J.; Koller, U.; Assmann, G.

    1990-01-01

    The Environmental Information Agency held its third seminar for journalists, entitled 'The sea - landfill or sphere of life' in Hamburg on July 18, 1989. Some 40 journalists - radio journalists and journalists from the staff of dailies and the technical press - took the opportunity to listen for a day to short lectures on selected subjects and submit their questions concerning sea pollution to scientists of diverse disciplines. (orig.) [de

  15. On the revolution of heavenly spheres

    CERN Document Server

    Copernicus, Nicolaus

    1995-01-01

    The Ptolemaic system of the universe, with the earth at the center, had held sway since antiquity as authoritative in philosophy, science, and church teaching. Following his observations of the heavenly bodies, Nicolaus Copernicus (1473-1543) abandoned the geocentric system for a heliocentric model, with the sun at the center. His remarkable work, On the Revolutions of Heavenly Spheres, stands as one of the greatest intellectual revolutions of all time, and profoundly influenced, among others, Galileo and Sir Isaac Newton.

  16. On the torus cobordant cohomology spheres

    Indian Academy of Sciences (India)

    Abstract. Let G be a compact Lie group. In 1960, P A Smith asked the following question: “Is it true that for any smooth action of G on a homotopy sphere with exactly two fixed points, the tangent G-modules at these two points are isomorphic?” A result due to Atiyah and Bott proves that the answer is 'yes' for Zp and it is also ...

  17. Connes distance function on fuzzy sphere and the connection between geometry and statistics

    Energy Technology Data Exchange (ETDEWEB)

    Devi, Yendrembam Chaoba, E-mail: chaoba@bose.res.in; Chakraborty, Biswajit, E-mail: biswajit@bose.res.in [S. N. Bose National Centre For Basic Sciences, Salt Lake, Kolkata 700098 (India); Prajapat, Shivraj, E-mail: shraprajapat@gmail.com [Technical Physics Division, Bhabha Atomic Research Centre (BARC), Mumbai 400085 (India); Mukhopadhyay, Aritra K., E-mail: aritra1910@gmail.com [Zentrum für Optische Quantentechnologien, Universität Hamburg, Luruper Chaussee 149, 22761 Hamburg (Germany); Scholtz, Frederik G., E-mail: fgs@sun.ac.za [National Institute for Theoretical Physics (NITheP), Stellenbosch 7602 (South Africa)

    2015-04-15

    An algorithm to compute Connes spectral distance, adaptable to the Hilbert-Schmidt operatorial formulation of non-commutative quantum mechanics, was developed earlier by introducing the appropriate spectral triple and used to compute infinitesimal distances in the Moyal plane, revealing a deep connection between geometry and statistics. In this paper, using the same algorithm, the Connes spectral distance has been calculated in the Hilbert-Schmidt operatorial formulation for the fuzzy sphere whose spatial coordinates satisfy the su(2) algebra. This has been computed for both the discrete and the Perelemov’s SU(2) coherent state. Here also, we get a connection between geometry and statistics which is shown by computing the infinitesimal distance between mixed states on the quantum Hilbert space of a particular fuzzy sphere, indexed by n ∈ ℤ/2.

  18. Surface modes of two spheres embedded into a third medium

    International Nuclear Information System (INIS)

    Nkoma, J.S.

    1990-07-01

    Surface modes of two spheres embedded into a third medium are studied. We obtain a result which relates the dependence of frequency on the distance between the two spheres. The derived expression reproduces previous results in the limit where the separation between the spheres is very large. Two surface mode branches are shown to exist for each order n. We apply the theory to three cases of practical interest: first, two similar metallic spheres in vacuum; secondly, two similar metallic spheres embedded into a different metal; thirdly, two spherical voids embedded into a metal. (author). 19 refs, 6 figs

  19. Agglomeration techniques for the production of spheres for packed beds

    International Nuclear Information System (INIS)

    Sullivan, J.D.

    1988-03-01

    One attractive fusion-breeder-blanket design features a lithium bearing ceramic in the form of spheres packed into a random array. The spheres have diameters of 3 mm and 0.3 mm. This report surveys techniques used to produce ceramic spheres on an industrial scale. The methods examined include tumbling and mixing granulation, extrusion, briquetting and pelletizing. It is concluded that the required quantities of 0.3 mm diameter spheres can be produced by the tumbling agglomeration of a feed powder. The 3 mm diameter spheres will be made using a process of extrusion, chopping and rolling

  20. Coordinated irradiation plan for the Fuel Refabrication and Development Program

    International Nuclear Information System (INIS)

    Barner, J.O.

    1979-04-01

    The Department of Energy's Fuel Refabrication and Development (FRAD) Program is developing a number of proliferation-resistant fuel systems and forms for alternative use in nuclear reactors. A major portion of the program is the development of irradiation behavioral information for the fuel system/forms with the ultimate objective of qualifying the design for licensing and commercial utilization. The nuclear fuel systems under development include denatured thoria--urania fuels and spiked urania--plutonia or thoria--plutonia fuels. The fuel forms being considered include pellet fuel produced from mechanically mixed or coprecipitated feed materials, pellet fuel fabricated from partially calcined gel-derived or freeze-dried spheres (hybrid fuel) and packed-particle fuel produced from sintered gel-derived spheres (sphere-pac). This document describes the coordinated development program that will be used to test and demonstrate the irradiation performance of alternative fuels

  1. Hopf Maps, Lowest Landau Level, and Fuzzy Spheres

    Directory of Open Access Journals (Sweden)

    Kazuki Hasebe

    2010-09-01

    Full Text Available This paper is a review of monopoles, lowest Landau level, fuzzy spheres, and their mutual relations. The Hopf maps of division algebras provide a prototype relation between monopoles and fuzzy spheres. Generalization of complex numbers to Clifford algebra is exactly analogous to generalization of fuzzy two-spheres to higher dimensional fuzzy spheres. Higher dimensional fuzzy spheres have an interesting hierarchical structure made of ''compounds'' of lower dimensional spheres. We give a physical interpretation for such particular structure of fuzzy spheres by utilizing Landau models in generic even dimensions. With Grassmann algebra, we also introduce a graded version of the Hopf map, and discuss its relation to fuzzy supersphere in context of supersymmetric Landau model.

  2. Recent developments in nonaqueous plutonium coordination chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Gaunt, A.J. [Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico (United States); Neu, M.P. [Associate Directorate for Chemistry, Life, and Earth Sciences, Los Alamos National Laboratory, Los Alamos, New Mexico (United States)

    2010-06-15

    This account highlights recent research from our laboratory on nonaqueous plutonium coordination chemistry. The preparation of organic-soluble synthons, the reactivity of plutonium with soft donor atom ligands, and initial characterization of resultant complexes are presented. Homoleptic soft donor complexes are targeted, to contrast with the much larger body of actinide chemistry that focuses covalency and reactivity within one to three sites in the coordination sphere. Structural parameters from X-ray structure determination and computation indicate small, yet significant, differences in covalency between isostructural plutonium and lanthanide complexes. Results are discussed in the context of our aim to expand the fundamental chemistry of plutonium, particularly to address challenges in the nuclear industry. (authors)

  3. Evolution of nickel sulfide hollow spheres through topotactic transformation

    Science.gov (United States)

    Wei, Chengzhen; Lu, Qingyi; Sun, Jing; Gao, Feng

    2013-11-01

    In this study, a topotactic transformation route was proposed to synthesize single-crystalline β-NiS hollow spheres with uniform phase and morphology evolving from polycrystalline α-NiS hollow spheres. Uniform polycrystalline α-NiS hollow spheres were firstly prepared with thiourea and glutathione as sulfur sources under hydrothermal conditions through the Kirkendall effect. By increasing the reaction temperature the polycrystalline α-NiS hollow spheres were transformed to uniform β-NiS hollow spheres. The β-NiS crystals obtained through the topotactic transformation route not only have unchanged morphology of hollow spheres but are also single-crystalline in nature. The as-prepared NiS hollow spheres display a good ability to remove the organic pollutant Congo red from water, which makes them have application potential in water treatment.In this study, a topotactic transformation route was proposed to synthesize single-crystalline β-NiS hollow spheres with uniform phase and morphology evolving from polycrystalline α-NiS hollow spheres. Uniform polycrystalline α-NiS hollow spheres were firstly prepared with thiourea and glutathione as sulfur sources under hydrothermal conditions through the Kirkendall effect. By increasing the reaction temperature the polycrystalline α-NiS hollow spheres were transformed to uniform β-NiS hollow spheres. The β-NiS crystals obtained through the topotactic transformation route not only have unchanged morphology of hollow spheres but are also single-crystalline in nature. The as-prepared NiS hollow spheres display a good ability to remove the organic pollutant Congo red from water, which makes them have application potential in water treatment. Electronic supplementary information (ESI) available: XRD patterns; SEM images and TEM images. See DOI: 10.1039/c3nr03371f

  4. Coordinators in Safaliba

    OpenAIRE

    Bodua-Mango, Kenneth

    2012-01-01

    This study examines the Safaliba coordinators „ní‟ / „aní‟, „á‟, „ka‟, „chɛ‟ and „bíí‟ in their naturally occurring environments. Safaliba is a Gur language spoken by some 5000 -7000 people in the north-western part of Ghana. The main areas of study include the syntactic categories that each coordinator can coordinate, the semantic properties of each of the coordinators and the pragmatic effect that the use of theses coordinators can have. Combinations of the individual coordinators calle...

  5. A purely Lagrangian method for simulating the shallow water equations on a sphere using smooth particle hydrodynamics

    Science.gov (United States)

    Capecelatro, Jesse

    2018-03-01

    It has long been suggested that a purely Lagrangian solution to global-scale atmospheric/oceanic flows can potentially outperform tradition Eulerian schemes. Meanwhile, a demonstration of a scalable and practical framework remains elusive. Motivated by recent progress in particle-based methods when applied to convection dominated flows, this work presents a fully Lagrangian method for solving the inviscid shallow water equations on a rotating sphere in a smooth particle hydrodynamics framework. To avoid singularities at the poles, the governing equations are solved in Cartesian coordinates, augmented with a Lagrange multiplier to ensure that fluid particles are constrained to the surface of the sphere. An underlying grid in spherical coordinates is used to facilitate efficient neighbor detection and parallelization. The method is applied to a suite of canonical test cases, and conservation, accuracy, and parallel performance are assessed.

  6. Locating a circle on a sphere

    DEFF Research Database (Denmark)

    Brimberg, Jack; Juel, Henrik; Schöbel, Anita

    2007-01-01

    We consider the problem of locating a spherical circle with respect to existing facilities on a sphere, such that the sum of distances between the circle and the facilities is minimized or such that the maximum distance is minimized. The problem properties are analyzed, and we give solution...... procedures. When the circle to be located is restricted to be a great circle, some simplifications are possible. The models may be used in preliminary studies on the location of large linear facilities on the earth's surface, such as superhighways, pipelines, and transmission lines, or in totally different...

  7. Determinantal point process models on the sphere

    DEFF Research Database (Denmark)

    Møller, Jesper; Nielsen, Morten; Porcu, Emilio

    We consider determinantal point processes on the d-dimensional unit sphere Sd . These are finite point processes exhibiting repulsiveness and with moment properties determined by a certain determinant whose entries are specified by a so-called kernel which we assume is a complex covariance function...... and eigenfunctions in a spectral representation for the kernel, and we figure out how repulsive isotropic DPPs can be. Moreover, we discuss the shortcomings of adapting existing models for isotropic covariance functions and consider strategies for developing new models, including a useful spectral approach....

  8. Sphere impact and penetration into wet sand

    KAUST Repository

    Marston, J. O.

    2012-08-07

    We present experimental results for the penetration of a solid sphere when released onto wet sand. We show, by measuring the final penetration depth, that the cohesion induced by the water can result in either a deeper or shallower penetration for a given release height compared to dry granular material. Thus the presence of water can either lubricate or stiffen the granular material. By assuming the shear rate is proportional to the impact velocity and using the depth-averaged stopping force in calculating the shear stress, we derive effective viscosities for the wet granular materials.

  9. The Finite Deformation Dynamic Sphere Test Problem

    Energy Technology Data Exchange (ETDEWEB)

    Versino, Daniele [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Brock, Jerry Steven [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-09-02

    In this manuscript we describe test cases for the dynamic sphere problem in presence of finite deformations. The spherical shell in exam is made of a homogeneous, isotropic or transverse isotropic material and elastic and elastic-plastic material behaviors are considered. Twenty cases, (a) to (t), are thus defined combining material types and boundary conditions. The inner surface radius, the outer surface radius and the material's density are kept constant for all the considered test cases and their values are ri = 10mm, ro = 20mm and p = 1000Kg/m3 respectively.

  10. Fermions, Skyrmions and the 3-sphere

    International Nuclear Information System (INIS)

    Goatham, Stephen W; Krusch, Steffen

    2010-01-01

    This paper investigates a background charge one Skyrme field chirally coupled to light fermions on the 3-sphere. The Dirac equation for the system commutes with a generalized angular momentum or grand spin. It can be solved explicitly for a Skyrme configuration given by the hedgehog form. The energy spectrum and degeneracies are derived for all values of the grand spin. Solutions for non-zero grand spin are each characterized by a set of four polynomials. The paper also discusses the energy of the Dirac sea using zeta-function regularization.

  11. Predictability limit for collapsing isothermal spheres

    International Nuclear Information System (INIS)

    Buff, J.; Gerola, H.; Stellingwerf, R.F.

    1979-01-01

    Using numerical hydrodynamic techniques, we have analyzed he radial instabilities of the nonhomologous collapse of isothermal spheres. The linear stability analysis shows that modes with shorter and shorter lengths become unstable as the collapse proceeds, as expected from a simple application of the Jeans criterion. The nonlinear analysis shows that the large-scale structure of the cloud is affected by initial perturbations in less than the free-fall time. We take these results to imply that, given the practical impossibility of knowing the initial spectrum of perturbations, no theoretical calculation can predict the complete evolution of a collapsing cloud

  12. Test Results of PBMR Fuel Spheres

    International Nuclear Information System (INIS)

    Koshcheev, Konstantin; Diakov, Alexander; Beltyukov, Igor; Barybin, Andrey; Chernetsov, Mikhail

    2014-01-01

    Results of pre-irradiation testing of fuel spheres (FS) and coated particles (CP) manufactured by PBMR SOC (Republic of South Africa) are described. The stable high quality level of major characteristics (dimensions, CP coating structure, uranium-235 contamination of the FS matrix graphite and the outer PyC layer of the CP coating) are shown. Results of a methodical irradiation test of two FS in helium and neon medium at temperatures of 800 to 1300 °C with simultaneous determination of release-to-birth ratios for major gaseous fission products (GFP) are described. (author)

  13. A new approach to: (a) grid generation for numerical optimization, and (b) interconnect networks for beowulf clusters, leveraging n-dimensional sphere-packings

    Science.gov (United States)

    Bewley, Thomas; Cessna, Joseph; Belitz, Paul

    2008-11-01

    The abstract field of n-dimensional sphere packing theory is well developed (for a comprehensive review, see Sphere Packings, Lattices and Groups by Conway and Sloane). This theory forms the theoretical underpinning of the error-correcting codes used in both deep space communications and in computer memory. The present work extends this elegant theory to two important and immensely practical problems in computational fluid dynamics: (a) the generation of efficient grids for the coordination of grid-based derivative-free optimization algorithms in n dimensions, and (b) the effective n-dimensional interconnection of massively-parallel clusters of computational nodes. As we will illustrate and quantify, the first problem benefits tremendously from dense sphere packings with large kissing numbers >> 2n, whereas the latter problem benefits tremendously from rare sphere packings with kissing number = n+1.

  14. Diagnosis of a Poorly Performing Liquid Hydrogen Bulk Storage Sphere

    Science.gov (United States)

    Krenn, Angela G.

    2011-01-01

    There are two 850,000 gallon Liquid Hydrogen (LH2) storage spheres used to support the Space Shuttle Program; one residing at Launch Pad A and the other at Launch Pad B. The LH2 Sphere at Pad B has had a high boiloff rate since being brought into service in the 1960's. The daily commodity loss was estimated to be approximately double that of the Pad A sphere, and well above the minimum required by the sphere's specification. Additionally, after being re-painted in the late 1990's a "cold spot" appeared on the outer sphere which resulted in a poor paint bond, and mold formation. Thermography was used to characterize the area, and the boiloff rate was continually evaluated. All evidence suggested that the high boiloff rate was caused by an excessive heat leak into the inner sphere due to an insulation void in the annulus. Pad B was recently taken out of Space Shuttle program service which provided a unique opportunity to diagnose the sphere's poor performance. The sphere was drained and inerted, and then opened from the annular relief device on the top where a series of boroscoping operations were accomplished. Boroscoping revealed a large Perlite insulation void in the region of the sphere where the cold spot was apparent. Perlite was then trucked in and off-loaded into the annular void region until the annulus was full. The sphere has not yet been brought back into service.

  15. The shallow water equations on the sphere and their Lagrange- Galerkin-solution

    CERN Document Server

    Heinze, T

    2002-01-01

    The shallow water equations are formulated on the sphere in a three- dimensional coordinate system with the aid of tangential velocity components and differential operators. We introduce a modified semi- Lagrangian scheme for the discretization in time. The discretization in space is solved by linear finite elements. The grids we use are regular refinements of a macro triangulation which itself is derived from a highly symmetric polyeder also known as a bucky or soccer ball. The good numerical results show that this combination is a promising approach. The numerical algorithm is stable and its strength is the conservation of mass and energy. (16 refs).

  16. The EU Security Continuum: the interaction between internal and external spheres in

    Directory of Open Access Journals (Sweden)

    Ana Postolache

    2012-08-01

    Full Text Available Exceeding the traditional dividing line between internal and external security, the article aims to analyze the coordination link between EU internal and external spheres in combating the "new security threats" and in achieving its security goals. First, I will analyze the rapprochement steps towards the EU security continuum, the instruments and the logic behind the process. Second, I will step beyond the discursive claims and I will analyze the EU operational aspects directed under this umbrella, with a particular focus on organised crime. Last but not least, I will discuss the reflection of EU security continuum on the wider global security arena.

  17. Röntgen spheres around active stars

    Science.gov (United States)

    Locci, Daniele; Cecchi-Pestellini, Cesare; Micela, Giuseppina; Ciaravella, Angela; Aresu, Giambattista

    2018-01-01

    X-rays are an important ingredient of the radiation environment of a variety of stars of different spectral types and age. We have modelled the X-ray transfer and energy deposition into a gas with solar composition, through an accurate description of the electron cascade following the history of the primary photoelectron energy deposition. We test and validate this description studying the possible formation of regions in which X-rays are the major ionization channel. Such regions, called Röntgen spheres may have considerable importance in the chemical and physical evolution of the gas embedding the emitting star. Around massive stars the concept of Röntgen sphere appears to be of limited use, as the formation of extended volumes with relevant levels of ionization is efficient just in a narrow range of gas volume densities. In clouds embedding low-mass pre-main-sequence stars significant volumes of gas are affected by ionization levels exceeding largely the cosmic-ray background ionization. In clusters arising in regions of vigorous star formation X-rays create an ionization network pervading densely the interstellar medium, and providing a natural feedback mechanism, which may affect planet and star formation processes.

  18. Clifford coherent state transforms on spheres

    Science.gov (United States)

    Dang, Pei; Mourão, José; Nunes, João P.; Qian, Tao

    2018-01-01

    We introduce a one-parameter family of transforms, U(m)t,t > 0, from the Hilbert space of Clifford algebra valued square integrable functions on the m-dimensional sphere, L2(Sm , dσm) ⊗Cm+1, to the Hilbert spaces, ML2(R m + 1 ∖ { 0 } , dμt) , of solutions of the Euclidean Dirac equation on R m + 1 ∖ { 0 } which are square integrable with respect to appropriate measures, dμt. We prove that these transforms are unitary isomorphisms of the Hilbert spaces and are extensions of the Segal-Bargman coherent state transform, U(1) :L2(S1 , dσ1) ⟶ HL2(C ∖ { 0 } , dμ) , to higher dimensional spheres in the context of Clifford analysis. In Clifford analysis it is natural to replace the analytic continuation from Sm to SCm as in (Hall, 1994; Stenzel, 1999; Hall and Mitchell, 2002) by the Cauchy-Kowalewski extension from Sm to R m + 1 ∖ { 0 } . One then obtains a unitary isomorphism from an L2-Hilbert space to a Hilbert space of solutions of the Dirac equation, that is to a Hilbert space of monogenic functions.

  19. Global warming in the public sphere.

    Science.gov (United States)

    Corfee-Morlot, Jan; Maslin, Mark; Burgess, Jacquelin

    2007-11-15

    Although the science of global warming has been in place for several decades if not more, only in the last decade and a half has the issue moved clearly into the public sphere as a public policy issue and a political priority. To understand how and why this has occurred, it is essential to consider the history of the scientific theory of the greenhouse effect, the evidence that supports it and the mechanisms through which science interacts with lay publics and other elite actors, such as politicians, policymakers and business decision makers. This article reviews why and how climate change has moved from the bottom to the top of the international political agenda. It traces the scientific discovery of global warming, political and institutional developments to manage it as well as other socially mediated pathways for understanding and promoting global warming as an issue in the public sphere. The article also places this historical overview of global warming as a public issue into a conceptual framework for understanding relationships between society and nature with emphasis on the co-construction of knowledge.

  20. Chaotic Fluid Mixing in Crystalline Sphere Arrays

    Science.gov (United States)

    Turuban, Regis; Lester, Daniel; Meheust, Yves; Le Borgne, Tanguy

    2017-11-01

    We study the Lagrangian dynamics of steady 3D Stokes flow over simple cubic (SC) and body-centered cubic (BCC) lattices of close-packed spheres, and uncover the mechanisms governing chaotic mixing. Due to the cusp-shaped sphere contacts, the topology of the skin friction field is fundamentally different to that of continuous (non-granular) media (e.g. open pore networks), with significant implications for fluid mixing. Weak symmetry breaking of the flow orientation with respect to the lattice symmetries imparts a transition from regular to strong chaotic mixing in the BCC lattice, whereas the SC lattice only exhibits weak mixing. Whilst the SC and BCC lattices share the same symmetry point group, these differences are explained in terms of their space groups, and we find that a glide symmetry of the BCC lattice generates chaotic mixing. These insights are used to develop accurate predictions of the Lyapunov exponent distribution over the parameter space of mean flow orientation, and point to a general theory of mixing and dispersion based upon the inherent symmetries of arbitrary crystalline structures. The authors acknowledge the support of ERC project ReactiveFronts (648377).

  1. Chaotic Fluid Mixing in Crystalline Sphere Arrays

    Science.gov (United States)

    Turuban, R.; Lester, D. R.; Le Borgne, T.; Méheust, Y.

    2017-12-01

    We study the Lagrangian dynamics of steady 3D Stokes flow over simple cubic (SC) and body-centered cubic (BCC) lattices of close-packed spheres, and uncover the mechanisms governing chaotic mixing. Due to the cusp-shaped sphere contacts, the topology of the skin friction field is fundamentally different to that of continuous (non-granular) media (e.g. open pore networks), with significant implications for fluid mixing. Weak symmetry breaking of the flow orientation with respect to the lattice symmetries imparts a transition from regular to strong chaotic mixing in the BCC lattice, whereas the SC lattice only exhibits weak mixing. Whilst the SC and BCC lattices share the same symmetry point group, these differences are explained in terms of their space groups, and we find that a glide symmetry of the BCC lattice generates chaotic mixing. These insight are used to develop accurate predictions of the Lyapunov exponent distribution over the parameter space of mean flow orientation, and point to a general theory of mixing and dispersion based upon the inherent symmetries of arbitrary crystalline structures.

  2. Measurement of dynamic and static radiation force on a sphere.

    Science.gov (United States)

    Chen, Shigao; Silva, Glauber T; Kinnick, Randall R; Greenleaf, James F; Fatemi, Mostafa

    2005-05-01

    Dynamic radiation force from ultrasound has found increasing applications in elasticity imaging methods such as vibro-acoustography. Radiation force that has both static and dynamic components can be produced by interfering two ultrasound beams of slightly different frequencies. This paper presents a method to measure both static and dynamic components of the radiation force on a sphere suspended by thin threads in water. Due to ultrasound radiation force, the sphere deflects to an equilibrant position and vibrates around it. The static radiation force is estimated from the deflection of the sphere. The dynamic radiation force is estimated from the calculated radiation impedance of the sphere and its vibration speed measured by a laser vibrometer. Experimental results on spheres of different size, vibrated at various frequencies, confirm the theoretical prediction that the dynamic and static radiation force on a sphere have approximately equal magnitudes [G. T. Silva, Phys. Rev. E 71, 056617 (2005)].

  3. A novel synthesis of micrometer silica hollow sphere

    International Nuclear Information System (INIS)

    Pan Wen; Ye Junwei; Ning Guiling; Lin Yuan; Wang Jing

    2009-01-01

    Silica microcapsules (hollow spheres) were synthesized successfully by a novel CTAB-stabilized water/oil emulsion system mediated hydrothermal method. The addition of urea to a solution of aqueous phase was an essential step of the simple synthetic procedure of silica hollow spheres, which leads to the formation of silica hollow spheres with smooth shell during hydrothermal process. The intact hollow spheres were obtained by washing the as-synthesized solid products with distilled water to remove the organic components. A large amount of silanol groups were retained in the hollow spheres by this facile route without calcination. The morphologies and optical properties of the product were characterized by transmission electron microscopy, scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy. Furthermore, on the basis of a series of SEM observations, phenomenological elucidation of a mechanism for the growth of the silica hollow spheres has been presented

  4. Co(II) Coordination in Prokaryotic Zinc Finger Domains as Revealed by UV-Vis Spectroscopy.

    Science.gov (United States)

    Sivo, Valeria; D'Abrosca, Gianluca; Russo, Luigi; Iacovino, Rosa; Pedone, Paolo Vincenzo; Fattorusso, Roberto; Isernia, Carla; Malgieri, Gaetano

    2017-01-01

    Co(II) electronic configuration allows its use as a spectroscopic probe in UV-Vis experiments to characterize the metal coordination sphere that is an essential component of the functional structure of zinc-binding proteins and to evaluate the metal ion affinities of these proteins. Here, exploiting the capability of the prokaryotic zinc finger to use different combinations of residues to properly coordinate the structural metal ion, we provide the UV-Vis characterization of Co(II) addition to Ros87 and its mutant Ros87_C27D which bears an unusual CysAspHis 2 coordination sphere. Zinc finger sites containing only one cysteine have been infrequently characterized. We show for the CysAspHis 2 coordination an intense d - d transition band, blue-shifted with respect to the Cys 2 His 2 sphere. These data complemented by NMR and CD data demonstrate that the tetrahedral geometry of the metal site is retained also in the case of a single-cysteine coordination sphere.

  5. Inner Coordination Sphere Control of Metal-Metal Superexchange in Ruthenium Dimers.

    Science.gov (United States)

    Rezvani, Ali R.; Bensimon, Corinne; Cromp, Benoit; Reber, Christian; Greedan, J. E.; Kondratiev, Veniamin V.; Crutchley, Robert J.

    1997-07-16

    The dinuclear Ru(III) complexes trans-[{(NH(3))(4)Ru(py)}(2)(&mgr;-L)][PF(6)](4), where py represents pyridine and L represents 1,4-dicyanamidobenzene dianion (dicyd(2)(-)) derivatives dicyd(2)(-) (1), Me(2)dicyd(2)(-) (2), Cl(2)dicyd(2)(-) (3), and Cl(4)dicyd(2)(-) (4), have been prepared and characterized by electronic absorption spectroscopy and cyclic voltammetry. A crystal structure of the complex trans-[{(NH(3))(4)Ru(py)}(2)(&mgr;-dicyd)][PF(6)](4).(1)/(2)H(2)O showed the dicyd(2)(-) ligand to be approximately planar with the cyanamido groups in a syn configuration. Crystal structure data are space group P2(1), with a, b, and c = 7.826(3), 20.455(7), and 14.428(5) Å, respectively, beta = 95.76 (3) degrees, V = 2296.7(14) Å(3), and Z = 2. The structure was refined by using 3292 reflections with I > 2.5sigma(I) to an R factor of 0.069. Solid state magnetic susceptibility measurements of the Ru(III)-Ru(III) dimers showed diamagnetic behavior at room temperature, and this is suggested to be due to strong antiferromagnetic superexchange via the HOMO of the dicyd(2)(-) ligand. The bridging ligand dependence of metal-metal coupling in the Ru(III)-Ru(II) complexes of 1, 2, 3, and 4 in acetonitrile solution was demonstrated by the trend in comproportionation constants, 1.5 x 10(6), 5.7 x 10(6), 1.4 x 10(4), and 1.1 x 10(3), respectively. In addition, comparison to the analogous pentaammineruthenium dimers showed that the magnitude of metal-metal superexchange could be controlled by the nature of the spectator ligand. Spectroelectrochemical methods were used to acquire the absorption spectra of the mixed-valence complexes, and the intervalence band properties were modeled with PKS theory. Metal-metal coupling in the Ru(III)-Ru(II) complexes of 1, 2, 3, and 4 was analyzed by using Hush and CNS theories.

  6. Elastic two-sphere swimmer in Stokes flow

    Science.gov (United States)

    Nasouri, Babak; Khot, Aditi; Elfring, Gwynn J.

    2017-04-01

    Swimming at low Reynolds number in Newtonian fluids is only possible through nonreciprocal body deformations due to the kinematic reversibility of the Stokes equations. We consider here a model swimmer consisting of two linked spheres, wherein one sphere is rigid and the other an incompressible neo-Hookean solid. The two spheres are connected by a rod that changes its length periodically. We show that the deformations of the body are nonreciprocal despite the reversible actuation and hence the elastic two-sphere swimmer propels forward. Our results indicate that even weak elastic deformations of a body can affect locomotion and may be exploited in designing artificial microswimmers.

  7. On $k$-stellated and $k$-stacked spheres

    OpenAIRE

    Bagchi, Bhaskar; Datta, Basudeb

    2012-01-01

    We introduce the class $\\Sigma_k(d)$ of $k$-stellated (combinatorial) spheres of dimension $d$ ($0 \\leq k \\leq d + 1$) and compare and contrast it with the class ${\\cal S}_k(d)$ ($0 \\leq k \\leq d$) of $k$-stacked homology $d$-spheres. We have $\\Sigma_1(d) = {\\cal S}_1(d)$, and $\\Sigma_k(d) \\subseteq {\\cal S}_k(d)$ for $d \\geq 2k - 1$. However, for each $k \\geq 2$ there are $k$-stacked spheres which are not $k$-stellated. The existence of $k$-stellated spheres which are not $k$-stacked remains...

  8. Steady state temperature profile in a sphere heated by microwaves

    Science.gov (United States)

    Barmatz, M.; Jackson, H. W.

    1992-01-01

    A new theory has been developed to calculate the microwave absorption and resultant temperature profile within a sphere positioned in a single mode rectangular cavity. This theory is an extension of a total absorption model based on Mie scattering results. Temperature profiles have been computed for alumina spheres at the center of a rectangular cavity excited in the TM354 mode. Parametric studies reveal significant structure in those profiles under special conditions that are associated with electromagnetic resonances inside the spheres. Anomalous behavior similar to thermal runaway occurs at moderate temperatures when there is enhanced absorption associated with resonant conditions in the sphere.

  9. Process development and fabrication for sphere-pac fuel rods

    International Nuclear Information System (INIS)

    Welty, R.K.; Campbell, M.H.

    1981-06-01

    Uranium fuel rods containing sphere-pac fuel have been fabricated for in-reactor tests and demonstrations. A process for the development, qualification, and fabrication of acceptable sphere-pac fuel rods is described. Special equipment to control fuel contamination with moisture or air and the equipment layout needed for rod fabrication is described and tests for assuring the uniformity of the fuel column are discussed. Fuel retainers required for sphere-pac fuel column stability and instrumentation to measure fuel column smear density are described. Results of sphere-pac fuel rod fabrication campaigns are reviewed and recommended improvements for high throughput production are noted

  10. Human postprandial gastric emptying of 1-3-millimeter spheres

    International Nuclear Information System (INIS)

    Meyer, J.H.; Elashoff, J.; Porter-Fink, V.; Dressman, J.; Amidon, G.L.

    1988-01-01

    Microspheres of pancreatin should empty from the stomachs of patients with pancreatic insufficiency as fast as food. The present study was undertaken in 26 healthy subjects to identify the size of spheres that would empty from the stomach with food and to determine whether different meals alter this size. Spheres of predefined sizes were labeled with /sup 113m/In or /sup 99m/Tc. Using a gamma-camera, we studied the concurrent gastric emptying of spheres labeled with /sup 113m/In and of chicken liver labeled with /sup 99m/Tc in 100-g, 154-kcal or 420-g, 919-kcal meals, or the concurrent emptying of 1-mm vs. larger spheres. One-millimeter spheres emptied consistently (p less than 0.01, paired t-test) faster than 2.4- or 3.2-mm spheres when ingested together with either the 420- or 100-g meals. Thus, in the 1-3-mm range of diameters, sphere size was a more important determinant of sphere emptying than meal size. Statistical analyses indicated that spheres 1.4 +/- 0.3 mm in diameter with a density of 1 empty at the same rate as /sup 99m/Tc-liver. Our data indicate some commercially marketed microspheres of pancreatin will empty too slowly to be effective in digestion of food

  11. Carbonaceous spheres—an unusual template for solid metal oxide mesoscale spheres: Application to ZnO spheres

    International Nuclear Information System (INIS)

    Patrinoiu, Greta; Calderón-Moreno, Jose Maria; Culita, Daniela C.; Birjega, Ruxandra; Ene, Ramona; Carp, Oana

    2013-01-01

    A green template route for the synthesis of mesoscale solid ZnO spheres was ascertained. The protocol involves a double coating of the carbonaceous spheres with successive layers of zinc-containing species by alternating a non-ultrasound and ultrasound-assisted deposition, followed by calcination treatments. The composites were characterized by FTIR spectroscopy, thermal analysis, scanning electron microscopy while the obtained ZnO spheres by X-ray diffraction, Raman spectroscopy, scanning and transmission electron microscopy, N 2 adsorption–desorption isotherms and photoluminescence investigations. A growth mechanism of the solid spheres is advanced based on these results. While the spheres' diameters and the mean size values of ZnO are independent on deposition order, the surface area and the external porosity are fairly dependent. The photoluminescence measurements showed interesting emission features, with emission bands in the violet to orange region. The spheres present high photocatalytical activity towards the degradation of phenol under UV irradiation, the main reaction being its mineralization. - Graphical abstract: A novel and eco-friendly methodology for the synthesis of mesoscale solid ZnO spheres was developed. The protocol involves a double coating of the starch-derived carbonaceous spheres with successive layers of zinc-containing species by alternating a non-ultrasound and ultrasound-assisted deposition, followed by calcination treatments. - Highlights: • ZnO solid spheres are obtained via a template route using carbonaceous spheres. • Two-step coatings of interchangeable order are used as deposition procedure. • The coating procedure influences the porosity and surface area. • ZnO spheres exhibited interesting visible photoluminescence properties. • Solid spheres showed photocatalytical activity in degradation of phenol

  12. Self-Assembled Hollow Spheres of β-Ni(OH) 2 and Their Derived Nanomaterials

    KAUST Repository

    Zhang, Shengmao

    2009-03-10

    This paper describes a novel solution-based chemical process to architect hollow spheres of β-Ni(OH) 2 with controllable sizes in submicrometer and micrometer regimes. In the synthesis, starting nickel salt (nitrate) is first converted to 6-coordinated nickel ion complex [Ni(EDA) 3] 2+ (bidentate ligand EDA = C 2H 4(NH 2) 2) to avoid rapid solid formation. Hollow and core - shell β-Ni(OH) 2 spheres can be obtained with this template-free approach under one-pot conditions. The β-Ni(OH) 2 spheres are constructed from petal-like nanobuilding units which in turn are formed from even smaller nanocrystallites. The obtained porous β-Ni(OH) 2 spheres have a large specific surface area and show a unimodal pore-size distribution. Several preparative parameters have been examined and optimized. In particular, the concentration of divalent nickel in the starting solutions plays an important role in controlling thickness of the petal-like β-Ni(OH) 2 flakes and diameter of spheres. The β-Ni(OH) 2 flakes self-assemble into final spherical products through a donut-like structural intermediate. Furthermore, the β-Ni(OH) 2 hollow spheres can be used as solid precursors to synthesize other nanostructured derivatives. In this work, phase pure inorganic nanostructures, carbon nanotube (CNT) - inorganic nanocomposites, and inorganic - inorganic nanocom-posites (e.g., NiO, Ni, NiO/Ni, Ni/β-Ni(OH) 2, CNTs/NiO, CNTs/Ni, Ni@CNTs, Fe(OH) 3/β-Ni(OH) 2, Co(OH) 2/β-Ni(OH) 2, and Mg(OH) 2/β-Ni(OH) 2) have been prepared via solid-state thermal decomposition, gas-phase reduction, solution-based reduction, surface oxidation, chemical vapor deposition, and liquid-phase deposition. A greater picture for general synthesis of Ni-containing nanomaterials is thus obtained. © 2009 American Chemical Society.

  13. Modelling Priorities of Financial Provision of the Social Sphere

    Directory of Open Access Journals (Sweden)

    Mamonova Hanna V.

    2014-01-01

    Full Text Available The article studies the modern state of the social sphere and conducts modelling of priorities of financial provision of the social sphere at the state level. Social sphere should be considered as the basis of development of the national economy. The goal of this article is the study of the modern state and modelling priorities of financial provision of the social sphere at the state level. The subject of the study is modelling priority directions of financial provision of components of the social sphere. Taking into account fast changes in the social sphere of the country and regular increase of social standards, the article identifies a necessity of changing priorities of the social policy, first of all, problems of financing the social sphere and formation of priority directions on improvement of this system. The article shows that the main problems of financial provision of the social sphere are: insufficient volumes of budget funds for financing the social sphere, financing practically all items of social expenditures in a smaller volume than it is required for the existing social support of the population and absence of mechanisms of ensuring quality of social services. The article offers to use the hierarchy analysis method for identifying immediate and priority directions of financing components of the social sphere. On the basis of the built directed communication graph the article presents a binary matrix of dependence of components of the social sphere and builds a hierarchy model of these components. As a result it is seen that the highest level of hierarchy is taken by science, then healthcare and social sphere are at the same level, then education, sports and at the lowest level are culture and art. The obtained results could be used when improving financing of the social sphere. In order to ensure efficiency of functioning of the social sphere it is necessary to improve the system of financing of its components on the basis of use

  14. Determination of the Avogadro constant by the XRCD method using a 28Si-enriched sphere

    Science.gov (United States)

    Kuramoto, Naoki; Mizushima, Shigeki; Zhang, Lulu; Fujita, Kazuaki; Azuma, Yasushi; Kurokawa, Akira; Okubo, Sho; Inaba, Hajime; Fujii, Kenichi

    2017-10-01

    To determine the Avogadro constant N A by the x-ray crystal density method, the density of a 28Si-enriched crystal was determined by absolute measurements of the mass and volume of a 1 kg sphere manufactured from the crystal. The mass and volume were determined by an optical interferometer and a vacuum mass comparator, respectively. The sphere surface was characterized by x-ray photoelectron spectroscopy and spectroscopic ellipsometry to derive the mass and volume of the Si core of the sphere excluding the surface layers. From the mass and volume, the density of the Si core was determined with a relative standard uncertainty of 2.3  ×  10-8. By combining the Si core density with the lattice constant and the molar mass of the sphere reported by the International Avogadro Coordination (IAC) project in 2015, a new value of 6.022 140 84(15)  ×  1023 mol-1 was obtained for N A with a relative standard uncertainty of 2.4  ×  10-8. To make the N A value determined in this work usable for a future adjustment of the fundamental constants by the CODATA Task Group on Fundamental Constants, the correlation of the new N A value with the N A values determined in our previous works was examined. The correlation coefficients with the values of N A determined by IAC in 2011 and 2015 were estimated to be 0.07 and 0.28, respectively. The correlation of the new N A value with the N A value determined by IAC in 2017 using a different 28Si-enriched crystal was also examined, and the correlation coefficient was estimated to be 0.21.

  15. Coordination chemistry and solution structure of Fe(II)-peplomycin. Two possible coordination geometries.

    Science.gov (United States)

    Li, Yang; Lehmann, Teresa

    2012-06-01

    The solution structure of Fe(II)-peplomycin was determined from NMR data collected for this molecule. As found previously for Fe(II)- and Co(II)-bound bleomycin; the coordination sphere of the metal is composed of the primary and secondary amines in β-aminoalanine, the pyrimidine and imidazole rings in the pyrimidinylpropionamide, and β-hydroxyhistidine moieties, respectively, the amine nitrogen in β-hydroxyhistidine, and either the carbamoyl group in mannose or a solvent molecule. The two most discussed coordination geometries for the aforementioned ligands in metallo-bleomycins have been tested against the NMR data generated for Fe(II)-peplomycin. The interpretation of the experimental evidence obtained through molecular dynamics indicates that both geometries are equally likely in solution for this compound in the absence of DNA, but arguments are offered to explain why one of these geometries is preferred in the presence of DNA. Published by Elsevier Inc.

  16. Polymeric coordination compounds

    Indian Academy of Sciences (India)

    Administrator

    Ce(dipic)3Sr(dipicH2)(OH2)3·5H2O (4) (dipicH2 – dipicolinic acid) exhibits 1-D polymeric chain structure, built up of alternating nine coordinate Ce and eight coordinate. Sr polyhedra. The analogous Ce–Ba compound (5) exhibits a polymeric chain built up of nine coordinate Ba units only, arranged in a hexagonal lattice.

  17. Creeping Viscous Flow around a Heat-Generating Solid Sphere

    DEFF Research Database (Denmark)

    Krenk, Steen

    1981-01-01

    The velocity field for creeping viscous flow around a solid sphere due to a spherically symmetric thermal field is determined and a simple thermal generalization of Stokes' formula is obtained. The velocity field due to an instantaneous heat source at the center of the sphere is obtained in close...... form and an application to the storage of heat-generating nuclear waste is discussed....

  18. Sphere sovereignty in late-modern society and social theory

    NARCIS (Netherlands)

    van Putten, R.J.

    2016-01-01

    This paper analyses to which extent the concept of sphere sovereignty, as developed by Kuyper and Dooyeweerd, is relevant for the understanding of late modern society. The central topic therefore is sphere sovereignty as view on social order. Firstly, I argue the urgency of studying the

  19. Applications of Bonner sphere detectors in neutron field dosimetry

    International Nuclear Information System (INIS)

    Awschalom, M.; Sanna, R.S.

    1983-09-01

    The theory of neutron moderation and spectroscopy are briefly reviewed, and moderators that are useful for Bonner sphere spectrometers are discussed. The choice of the neutron detector for a Bonner sphere spectrometer is examined. Spectral deconvolution methods are briefly reviewed, including derivative, parametric, quadrature, and Monte Carlo methods. Calibration is then discussed

  20. Radioactive spheres without inactive wall for lesion simulation in PET

    International Nuclear Information System (INIS)

    Bazanez-Borgert, M.; Bundschuh, R.A.; Herz, M.; Martinez, M.J.; Schwaiger, M.; Ziegler, S.I.

    2008-01-01

    With the growing importance of PET and PET/CT in diagnosis, staging, therapy monitoring and radiotherapy planning, appropriate tools to simulate lesions in phantoms are important. Normally hollow spheres, made of plastic or glass, which can be filled with radioactive solutions, are used. As these spheres have an inactive wall they do not reflect the real situation in the patient and lead to quantification errors in the presence of background activity. We propose spheres made of radioactive wax, which are easy to produce, give a high flexibility to the user and a more accurate quantification. These wax spheres were evaluated for their applicability in PET phantoms and it was found that the activity is not diffusing into the surrounding water in relevant quantities, that they show a sufficient homogeneity, and that their attenuation properties are equivalent to water for photons of PET energies. Recovery coefficients for the wax spheres were measured and compared with those obtained for fillable plastic spheres for diameters of 28, 16, 10, and 6 mm in the presence of background activity. Recovery coefficients of the wax spheres were found to be up to 21% higher than for the fillable spheres. (orig.)

  1. Thermodynamics and vibrational modes of hard sphere colloidal systems

    NARCIS (Netherlands)

    Zargar, R.

    2014-01-01

    The central question that we address in this thesis is the thermodynamics of colloidal glasses. The thermodynamics of colloidal hard sphere glasses are directly related to the entropy of the system, since the phase behavior of hard sphere systems is dictated only by entropic contributions, and also

  2. Covariant differential calculus on quantum spheres of odd dimension

    International Nuclear Information System (INIS)

    Welk, M.

    1998-01-01

    Covariant differential calculus on the quantum spheres S q 2N-1 is studied. Two classification results for covariant first order differential calculi are proved. As an important step towards a description of the noncommutative geometry of the quantum spheres, a framework of covariant differential calculus is established, including first and higher order calculi and a symmetry concept. (author)

  3. The sintering behavior of close-packed spheres

    DEFF Research Database (Denmark)

    Bjørk, Rasmus; Tikare, V.; Frandsen, Henrik Lund

    2012-01-01

    The sintering behavior of close-packed spheres is investigated using a numerical model. The investigated systems are the body-centered cubic (bcc), face-centered cubic (fcc) and hexagonal close-packed spheres (hcp). The sintering behavior is found to be ideal, with no grain growth until full dens...

  4. Women, Power and Performance in the Yoruba Public Sphere

    African Journals Online (AJOL)

    chifaou.amzat

    2010-04-14

    Apr 14, 2010 ... Songs of the King's Wives: Women, Power and Performance in the Yoruba Public Sphere. Bode Omojola*. Abstract. Indigenous festivals, which rely significantly on music and dance, of- ten constitute the village public sphere and the social arena within which the structures of power are performed and ...

  5. Convexity of spheres in a manifold without conjugate points

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    Abstract. For a non-compact, complete and simply connected manifold M without conjugate points, we prove that if the determinant of the second fundamental form of the geodesic spheres in M is a radial function, then the geodesic spheres are convex. We also show that if M is two or three dimensional and without ...

  6. VMware vSphere 5.5 cookbook

    CERN Document Server

    G B, Abhilash

    2015-01-01

    This is an excellent handbook for system administrators, support professionals, or for anyone intending to give themselves a headstart in learning how to install, configure, and manage a vSphere environment. It is also a good task-oriented reference guide for consultants or infrastructure architects who design and deploy vSphere environments.

  7. Rigid sphere transport through a colloidal gas–liquid interface

    NARCIS (Netherlands)

    de Folter, J.W.J.; de Villeneuve, V.W.A.; Aarts, D.G.A.L.; Lekkerkerker, H.N.W.

    2010-01-01

    In this paper we report on the gravity-driven transport of rigid spheres of various sizes through the fluid–fluid interface of a demixed colloid–polymer mixture. Three consecutive stages can be distinguished: (i) the sphere approaches the interface by sedimenting through the polymer-rich phase, (ii)

  8. Axioms of spheres in lightlike geometry of submanifolds

    Indian Academy of Sciences (India)

    Introduction. The notion of axioms of planes for Riemannian manifolds was originally introduced by. Cartan [2]. In [8], Leung and Nomizu generalized the notion of axioms of planes to the axioms of spheres on Riemannian manifolds. In [7], Kumar et al. studied the axioms of spheres and planes for indefinite Riemannian ...

  9. Orbital Motion of Electrically Charged Spheres in Microgravity

    Science.gov (United States)

    Banerjee, Shubho; Andring, Kevin; Campbell, Desmond; Janeski, John; Keedy, Daniel; Quinn, Sean; Hoffmeister, Brent

    2008-01-01

    The similar mathematical forms of Coulomb's law and Newton's law of gravitation suggest that two uniformly charged spheres should be able to orbit each other just as two uniform spheres of mass are known to do. In this paper we describe an experiment that we performed to demonstrate such an orbit. This is the first published account of a…

  10. Six-coordinate manganese(3+) in catalysis by yeast manganese superoxide dismutase

    Energy Technology Data Exchange (ETDEWEB)

    Sheng, Yuewei; Gralla, Edith Butler; Schumacher, Mikhail; Cascio, Duilio; Cabelli, Diane E.; Valentine, Joan Selverstone (EWHA); (UCLA); (BNL)

    2012-10-10

    Reduction of superoxide (O{sub 2}{sup -}) by manganese-containing superoxide dismutase occurs through either a 'prompt protonation' pathway, or an 'inner-sphere' pathway, with the latter leading to formation of an observable Mn-peroxo complex. We recently reported that wild-type (WT) manganese superoxide dismutases (MnSODs) from Saccharomyces cerevisiae and Candida albicans are more gated toward the 'prompt protonation' pathway than human and bacterial MnSODs and suggested that this could result from small structural changes in the second coordination sphere of manganese. We report here that substitution of a second-sphere residue, Tyr34, by phenylalanine (Y34F) causes the MnSOD from S. cerevisiae to react exclusively through the 'inner-sphere' pathway. At neutral pH, we have a surprising observation that protonation of the Mn-peroxo complex in the mutant yeast enzyme occurs through a fast pathway, leading to a putative six-coordinate Mn3+ species, which actively oxidizes O{sub 2}{sup -} in the catalytic cycle. Upon increasing pH, the fast pathway is gradually replaced by a slow proton-transfer pathway, leading to the well-characterized five-coordinate Mn{sup 3+}. We here propose and compare two hypothetical mechanisms for the mutant yeast enzyme, diffeeing in the structure of the Mn-peroxo complex yet both involving formation of the active six-coordinate Mn{sup 3+} and proton transfer from a second-sphere water molecule, which has substituted for the -OH of Tyr34, to the Mn-peroxo complex. Because WT and the mutant yeast MnSOD both rest in the 2+ state and become six-coordinate when oxidized up from Mn{sup 2+}, six-coordinate Mn{sup 3+} species could also actively function in the mechanism of WT yeast MnSODs.

  11. Segregation in inclined flows of binary mixtures of spheres

    Directory of Open Access Journals (Sweden)

    Larcher Michele

    2017-01-01

    Full Text Available We outline the equations that govern the evolution of segregation of a binary mixture of spheres in flows down inclines. These equations result from the mass and momentum balances of a kinetic theory for dense flows of inelastic spheres that interact through collisions. The theory employed for segregation is appropriate for particles with relatively small differences in size and mass. The flow of the mixture is assumed to reach a fully developed state much more rapidly than does the concentrations of the two species. We illustrate the predictions of the theory for a mixture of spheres of the same diameter but different masses and for spheres of different diameters but nearly the same mass. We show the evolution of the profiles of the concentration fractions of the two types of spheres and the profiles in the final, steady state. The latter compare favourably with those obtained in discrete-element numerical simulations.

  12. Fe2O3 hollow sphere nanocomposites for supercapacitor applications

    Science.gov (United States)

    Zhao, Yu; Wen, Yang; Xu, Bing; Lu, Lu; Ren, Reiming

    2018-02-01

    Nanomaterials have attracted increasing interest in electrochemical energy storage and conversion. Hollow sphere Fe2O3 nanocomposites were successfully prepared through facile low temperature water-bath method with carbon sphere as hard template. The morphology and microstructure of samples were characterized by X-ray diffraction (XRD) and Scanning electron microscope (SEM), respectively. Through hydrolysis mechanism, using ferric chloride direct hydrolysis, iron hydroxide coated on the surface of carbon sphere, after high temperature calcination can form the hollow spherical iron oxide materials. Electrochemical performances of the hollow sphere Fe2O3 nanocomposites electrodes were investigated by cyclic voltammery (CV) and galvanostatic charge/discharge. The Pure hollow sphere Fe2O3 nanocomposites achieves a specific capacitance of 125 F g-1 at the current density of 85 mA g-1. The results indicate that the uniform dispersion of hollow ball structure can effectively reduce the particle reunion in the process of charging and discharging.

  13. From ring-in-ring to sphere-in-sphere: self-assembly of discrete 2D and 3D architectures with increasing stability.

    Science.gov (United States)

    Sun, Bin; Wang, Ming; Lou, Zhichao; Huang, Mingjun; Xu, Chenglong; Li, Xiaohong; Chen, Li-Jun; Yu, Yihua; Davis, Grant L; Xu, Bingqian; Yang, Hai-Bo; Li, Xiaopeng

    2015-02-04

    Directed by increasing the density of coordination sites (DOCS) to increase the stability of assemblies, discrete 2D ring-in-rings and 3D sphere-in-sphere were designed and self-assembled by one tetratopic pyridyl-based ligand with 180° diplatinum(II) acceptors and naked Pd(II), respectively. The high DOCS resulted by multitopic ligand provided more geometric constraints to form discrete structures with high stability. Compared to reported supramolecular hexagons and polyhedra by ditotpic ligands, the self-assembly of such giant architectures using multitopic ligands with all rigid backbone emphasized the structural integrity with precise preorganization of entire architecture, and required elaborate synthetic operations for ligand preparation. In-depth structural characterization was conducted to support desired structures, including multinuclear NMR ((1)H, (31)P, and (13)C) analysis, 2D NMR spectroscopy (COSY and NOESY), diffusion-ordered NMR spectroscopy (DOSY), multidimensional mass spectrometry, TEM and AFM. Furthermore, a quantitative definition of DOCS was proposed to compare 2D and 3D structures and correlate the DOCS and stability of assemblies in a quantitative manner. Finally, ring-in-rings in DMSO or DMF could undergo hierarchical self-assembly into the ordered nanostructures and generated translucent supramolecular metallogels.

  14. Neutron spectrometry and dosimetry with neural networks and Bonner spheres: a study to reduce the spheres number

    International Nuclear Information System (INIS)

    Espinoza G, J. G.; Martinez B, M. R.; Leon P, A. A.; Hernandez P, C. F.; Castaneda M, V. H.; Solis S, L. O.; Castaneda M, R.; Ortiz R, J. M.; Vega C, H. R.; Mendez, R.; Gallego, E.; De Sousa L, M. A.

    2016-10-01

    For neutron spectrometry and neutron dosimetry, the Bonner spheres spectrometric system has been the most widely used system, however, the number, size and weight of the spheres composing the system, as well as the need to use a reconstruction code and the long periods of time used to carry out the measurements are some of the disadvantages of this system. For the reconstruction of the spectra, different techniques such as artificial neural networks of reverse propagation have been used. The objective of this work was to reduce the number of Bonner spheres and to use counting speeds in a reverse propagation neural network, optimized by means of the robust design methodology, to reconstruct the neutron spectra. For the design of the neural network we used the neutron spectra of the IAEA and the response matrix of the Bonner spheres with 6 LiI(Eu) detector. The performance of the network was compared; using 7 Bonner spheres against other cases where only 2 and one sphere are used. The network topologies were trained 36 times for each case keeping constant the objective error (1E(-3)), the training algorithm was trains cg and the robust design methodology to determine the best network architectures. With these, the best and worst results were compared. The results obtained using 7 spheres were similar to those with the 5-in sphere, however is still in an information analysis stage. (Author)

  15. Plutonium(IV) complexation by diglycolamide ligands - coordination chemistry insight into TODGA-based actinide separations

    NARCIS (Netherlands)

    Reilly, S.D.; Gaunt, A.J.; Scott, B.L.; Modolo, G.; Iqbal, M.; Verboom, Willem; Sarsfield, M.J.

    2012-01-01

    Complexation of Pu(IV) with TMDGA, TEDGA, and TODGA diglycolamide ligands was followed by vis-NIR spectroscopy. A crystal structure determination reveals that TMDGA forms a 1:3 homoleptic Pu(IV) complex with the nitrate anions forced into the outer coordination sphere

  16. Recovering functions defined on the unit sphere by integration on a special family of sub-spheres

    Science.gov (United States)

    Salman, Yehonatan

    2017-06-01

    The aim of this article is to derive a reconstruction formula for the recovery of C1 functions, defined on the unit sphere S^{n - 1}, given their integrals on a special family of n - 2 dimensional sub-spheres. For a fixed point \\overline{a} strictly inside S^{n - 1}, each sub-sphere in this special family is obtained by intersection of S^{n - 1} with a hyperplane passing through \\overline{a}. The case \\overline{a} = 0 results in an inversion formula for the special case of integration on great spheres (i.e., Funk transform). The limiting case where p\\in S^{n - 1} and \\overline{a}→ p results in an inversion formula for the special case of integration on spheres passing through a common point in S^{n - 1}.

  17. Coordination failure caused by sunspots

    DEFF Research Database (Denmark)

    Beugnot, Julie; Gürgüç, Zeynep; Øvlisen, Frederik Roose

    2012-01-01

    In a coordination game with Pareto-ranked equilibria, we study whether a sunspot can lead to either coordination on an inferior equilibrium (mis-coordination) or to out-of equilibrium behavior (dis-coordination). While much of the literature searches for mechanisms to attain coordination on the e......In a coordination game with Pareto-ranked equilibria, we study whether a sunspot can lead to either coordination on an inferior equilibrium (mis-coordination) or to out-of equilibrium behavior (dis-coordination). While much of the literature searches for mechanisms to attain coordination...

  18. Coordinate measuring machines

    DEFF Research Database (Denmark)

    De Chiffre, Leonardo

    This document is used in connection with three exercises of 2 hours duration as a part of the course GEOMETRICAL METROLOGY AND MACHINE TESTING. The exercises concern three aspects of coordinate measuring: 1) Measuring and verification of tolerances on coordinate measuring machines, 2) Traceability...

  19. Experimental study on combustion of a methane hydrate sphere

    Science.gov (United States)

    Yoshioka, Tomoki; Yamamoto, Yuji; Yokomori, Takeshi; Ohmura, Ryo; Ueda, Toshihisa

    2015-10-01

    The combustion behavior of a methane hydrate sphere under normal gravity is experimentally investigated. The initial diameter of the sphere is 20 mm. Variation in temperature at the center of the sphere ( T c) is measured with a K-type thermocouple at ignition temperatures ( T c,i) from 193 to 253 K at 20 K intervals. Variation in the near-surface temperature of the sphere ( T s) is measured at ignition temperatures ( T s,i) from 233 to 263 K at 10 K intervals. Two combustion phases are observed. When the hydrate is ignited, a stable flame envelope is formed around the sphere (phase 1). In phase 1, the surface of the sphere is dry. After a few seconds, water formed by dissociation of the methane hydrate appears on the surface and methane bubbles are formed by methane ejected from inside the sphere (phase 2), thus destabilizing the flame and causing local extinction. Methane bubbles move down along the surface and merge into a large methane bubble at the bottom of the sphere. This bubble bursts, releasing methane to form a temporary flame, and the water drops from the hydrate sphere. Water on the surface is cooled by the hydrate inside, and an ice shell confines the methane gas that dissociated inside the sphere. Because the dissociation occurs continuously inside the hydrate, the inner pressure gradually increases and at some instant, the ice cracks and methane gas is ejected from the cracks, which results in a micro-explosion with a flame. In phase 1, the surface temperature is below the freezing point of water, and so the surface remains dry and a stable flame envelope is formed; in phase 2, the surface temperature is above the freezing point, and so water appears on the surface. When the temperature at the center of the sphere is lower (193, 213, or 233 K), some methane hydrate remains even after flame extinction because heat transfer from the flame decreases in phase 2 as a result of local extinction. The diameter of the sphere decreases during combustion in

  20. Stress relaxation in viscous soft spheres.

    Science.gov (United States)

    Boschan, Julia; Vasudevan, Siddarth A; Boukany, Pouyan E; Somfai, Ellák; Tighe, Brian P

    2017-10-04

    We report the results of molecular dynamics simulations of stress relaxation tests in athermal viscous soft sphere packings close to their unjamming transition. By systematically and simultaneously varying both the amplitude of the applied strain step and the pressure of the initial condition, we access both linear and nonlinear response regimes and control the distance to jamming. Stress relaxation in viscoelastic solids is characterized by a relaxation time τ* that separates short time scales, where viscous loss is substantial, from long time scales, where elastic storage dominates and the response is essentially quasistatic. We identify two distinct plateaus in the strain dependence of the relaxation time, one each in the linear and nonlinear regimes. The height of both plateaus scales as an inverse power law with the distance to jamming. By probing the time evolution of particle velocities during relaxation, we further identify a correlation between mechanical relaxation in the bulk and the degree of non-affinity in the particle velocities on the micro scale.

  1. Second-order impartiality and public sphere

    Directory of Open Access Journals (Sweden)

    Sládeček Michal

    2016-01-01

    Full Text Available In the first part of the text the distinction between first- and second-order impartiality, along with Brian Barry’s thorough elaboration of their characteristics and the differences between them, is examined. While the former impartiality is related to non-favoring fellow-persons in everyday occasions, the latter is manifested in the institutional structure of society and its political and public morality. In the second part of the article, the concept of public impartiality is introduced through analysis of two examples. In the first example, a Caledonian Club with its exclusive membership is considered as a form of association which is partial, but nevertheless morally acceptable. In the second example, the so-called Heinz dilemma has been reconsidered and the author points to some flaws in Barry’s interpretation, arguing that Heinz’s right of giving advantage to his wife’s life over property rights can be recognized through mitigating circum-stances, and this partiality can be appreciated in the public sphere. Thus, public impartiality imposes limits to the restrictiveness and rigidity of political impartiality implied in second-order morality. [Projekat Ministarstva nauke Republike Srbije, br. 179049

  2. Bubble entrapment during sphere impact onto quiescent liquid surfaces

    KAUST Repository

    Marston, Jeremy

    2011-06-20

    We report observations of air bubble entrapment when a solid sphere impacts a quiescent liquid surface. Using high-speed imaging, we show that a small amount of air is entrapped at the bottom tip of the impacting sphere. This phenomenon is examined across a broad range of impact Reynolds numbers, 0.2 a Re = (DU0/Il) a 1.2\\' 105. Initially, a thin air pocket is formed due to the lubrication pressure in the air layer between the sphere and the liquid surface. As the liquid surface deforms, the liquid contacts the sphere at a finite radius, producing a thin sheet of air which usually contracts to a nearly hemispherical bubble at the bottom tip of the sphere depending on the impact parameters and liquid properties. When a bubble is formed, the final bubble size increases slightly with the sphere diameter, decreases with impact speed but appears independent of liquid viscosity. In contrast, for the largest viscosities tested herein, the entrapped air remains in the form of a sheet, which subsequently deforms upon close approach to the base of the tank. The initial contact diameter is found to conform to scalings based on the gas Reynolds number whilst the initial thickness of the air pocket or adimplea scales with a Stokes\\' number incorporating the influence of the air viscosity, sphere diameter and impact speed and liquid density. © 2011 Cambridge University Press.

  3. Forming MOFs into spheres by use of molecular gastronomy methods.

    Science.gov (United States)

    Spjelkavik, Aud I; Aarti; Divekar, Swapnil; Didriksen, Terje; Blom, Richard

    2014-07-14

    A novel method utilizing hydrocolloids to prepare nicely shaped spheres of metal-organic frameworks (MOFs) has been developed. Microcrystalline CPO-27-Ni particles are dispersed in either alginate or chitosan solutions, which are added dropwise to solutions containing, respectively, either divalent group 2 cations or base that act as gelling agents. Well-shaped spheres are immediately formed, which can be dried into spheres containing mainly MOF (>95 wt %). The spheronizing procedures have been optimized with respect to maximum specific surface area, shape, and particle density of the final sphere. At optimal conditions, well-shaped 2.5-3.5 mm diameter CPO-27-Ni spheres with weight-specific surface areas <10 % lower than the nonformulated CPO-27-Ni precursor, and having sphere densities in the range 0.8 to 0.9 g cm(-3) and particle crushing strengths above 20 N, can be obtained. The spheres are well suited for use in fixed-bed catalytic or adsorption processes. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Review of reaction spheres for spacecraft attitude control

    Science.gov (United States)

    Zhu, Linyu; Guo, Jian; Gill, Eberhard

    2017-05-01

    With respect to spacecraft attitude control, reaction spheres are promising alternatives to conventional momentum exchange devices for the benefits brought by their 4π rotation. Many design concepts of reaction spheres have been proposed in the past decades, however, developments of the driving unit and the bearing, as well as their combination remain great challenges. To facilitate research and push developments in this field, this paper provides a comprehensive review of reaction spheres. To some extent, an in-depth survey of multi-DOF (degree of freedom) spherical motors and possible bearings is provided, along with their advantages and weaknesses addressed. Some multi-DOF actuators for different applications, such as robotic joints, are investigated since they share many similar challenges and techniques with reaction spheres. The experimental performances of realized reaction spheres are listed and compared. Limits of current designs are identified and their causes are analyzed and discussed. Compared with existing summaries on multi-DOF actuators and some surveys done for specific reaction spheres' design, this paper provides the first thorough review on reaction spheres, considering approaches to excite and support the free 4π rotation.

  5. Public sphere as assemblage: the cultural politics of roadside memorialization.

    Science.gov (United States)

    Campbell, Elaine

    2013-09-01

    This paper investigates contemporary academic accounts of the public sphere. In particular, it takes stock of post-Habermasian public sphere scholarship, and acknowledges a lively and variegated debate concerning the multiple ways in which individuals engage in contemporary political affairs. A critical eye is cast over a range of key insights which have come to establish the parameters of what 'counts' as a/the public sphere, who can be involved, and where and how communicative networks are established. This opens up the conceptual space for re-imagining a/the public sphere as an assemblage. Making use of recent developments in Deleuzian-inspired assemblage theory - most especially drawn from DeLanda's (2006) 'new philosophy of society' - the paper sets out an alternative perspective on the notion of the public sphere, and regards it as a space of connectivity brought into being through a contingent and heterogeneous assemblage of discursive, visual and performative practices. This is mapped out with reference to the cultural politics of roadside memorialization. However, a/the public sphere as an assemblage is not simply a 'social construction' brought into being through a logic of connectivity, but is an emergent and ephemeral space which reflexively nurtures and assembles the cultural politics (and political cultures) of which it is an integral part. The discussion concludes, then, with a consideration of the contribution of assemblage theory to public sphere studies. (Also see Campbell 2009a). © London School of Economics and Political Science 2013.

  6. Radar Imaging of Spheres in 3D using MUSIC

    Energy Technology Data Exchange (ETDEWEB)

    Chambers, D H; Berryman, J G

    2003-01-21

    We have shown that multiple spheres can be imaged by linear and planar EM arrays using only one component of polarization. The imaging approach involves calculating the SVD of the scattering response matrix, selecting a subset of singular values that represents noise, and evaluating the MUSIC functional. The noise threshold applied to the spectrum of singular values for optimal performance is typically around 1%. The resulting signal subspace includes more than one singular value per sphere. The presence of reflections from the ground improves height localization, even for a linear array parallel to the ground. However, the interference between direct and reflected energy modulates the field, creating periodic nulls that can obscure targets in typical images. These nulls are largely eliminated by normalizing the MUSIC functional with the broadside beam pattern of the array. The resulting images show excellent localization for 1 and 2 spheres. The performance for the 3 sphere configurations are complicated by shadowing effects and the greater range of the 3rd sphere in case 2. Two of the three spheres are easily located by MUSIC but the third is difficult to distinguish from other local maxima of the complex imaging functional. Improvement is seen when the linear array is replace with a planar array, which increases the effective aperture height. Further analysis of the singular values and their relationship to modes of scattering from the spheres, as well as better ways to exploit polarization, should improve performance. Work along these lines is currently being pursued by the authors.

  7. Making three-dimensional Monson's sphere using virtual dental models.

    Science.gov (United States)

    Nam, Shin-Eun; Park, Young-Seok; Lee, WooCheol; Ahn, Sug-Joon; Lee, Seung-Pyo

    2013-04-01

    The Monson's sphere and curve of Wilson can be used as reference for prosthetic reconstructions or orthodontic treatments. This study aimed to generate and measure the three-dimensional (3-D) Monson's sphere and curve of Wilson using virtual dental models and custom software. Mandibular dental casts from 79 young adults of Korean descent were scanned and rendered as virtual dental models using a 3-D digitizing scanner. 26 landmarks were digitized on the virtual dental models using a custom made software program. The Monson's sphere was estimated by fitting a sphere to the cusp tips using a least-squares method. Two curves of Wilson were generated by finding the intersecting circle between the Monson's sphere and two vertical planes orthogonal to a virtual occlusal plane. Non-parametric Mann-Whitney and Kruskal-Wallis tests were performed to test for difference between sex and in cusp number within tooth position. The mean radius of Monson's sphere was 110.89 ± 25.75 mm. There were significant differences between males and females in all measurements taken (pocclusal curvature (p>0.05). This study describes a best-fit algorithm for generating 3-D Monson's sphere using occlusal curves quantified from virtual dental models. The radius of Monson's sphere in Korean subjects was greater than the original four-inch value suggested by Monson. The Monson's sphere and curve of Wilson can be used as a reference for prosthetic reconstruction and orthodontic treatment. The data found in this study may be applied to improve dental treatment results. Copyright © 2013 Elsevier Ltd. All rights reserved.

  8. Coordinating Interactions: The Event Coordination Notation

    DEFF Research Database (Denmark)

    Kindler, Ekkart

    on a much more technical level. The Event Coordination Notation (ECNO) allows modelling the behaviour of an application on a high level of abstraction that is closer to the application’s domain than to the software realizing it. Still, these models contain all necessary details for actually executing...... the models and for generating code from them. In order to be able to model the behaviour of a domain, the ECNO makes the events in which the different elements of the domain could engage explicit. The local behaviour of an element defines at which time an element can engage or participate in an event....... The global behaviour of the application results from different elements jointly engaging in such events, which is called an interaction. Which events are supposed to be jointly executed and which elements need to join in is defined by so-called coordination diagrams of the ECNO. Together, the models...

  9. Formation of Public Spheres and Islamist Movements in Malay Muslim Society of Malaysia

    OpenAIRE

    Shiozaki, Yuki

    2007-01-01

    Muslim society originally had spheres for discussion based on Islamic logic, which are similar to a "public sphere." Such spheres were organized by ulama (Islamic clerics) and tariqa (Islamic order of mystics). Buildings established through waqf (religious endowment) including mosques and religious schools also provided such spheres for discussion. On the premise of the existence of plural public spheres rather than the single civil sphere advocated by Habermas, the contemporary Islamist move...

  10. Gender and Diversity in the European Public Spheres

    DEFF Research Database (Denmark)

    Siim, Birte

    The increasing institutionalization of rights in EU has inspired a debate about the gap between the EU polity and citizens' abilities to influence multilevel governance and politics. The objective of the paper is to discuss diversity in the European public spheres from a gender perspective...... state and to link feminist proposals for gender justice with frames for a multilayered trans-national citizenship. The paper aims to contribute to debates about theoretical approaches and models to study gender and diversity in the public sphere in general and in particular The European Public Sphere...

  11. POSTGRADUATE EDUCATION FUNCTIONING PATTERNS OF TOURISM SPHERE SPECIALISTS IN SWITZERLAND

    Directory of Open Access Journals (Sweden)

    Наталія Закордонець

    2014-04-01

    Full Text Available Functioning patterns of postgraduate education of tourism sphere specialists in Switzerland have been established. The competences of tourism sphere specialist, the formation of which programs of postgraduate education are focused on have been considered. The benefits of educational qualification of Masters in Business Administration with a major specialization in tourism have been outlined. The characteristics of the core curriculum of the Doctor of Management of leading universities in the field of tourism education have been determined. The performance criteria of postgraduate education system functioning of tourism sphere specialists in Switzerland have been revealed.

  12. Mastering VMware vSphere 5.5

    CERN Document Server

    Lowe, Scott; Guthrie, Forbes; Liebowitz, Matt; Atwell, Josh

    2013-01-01

    The 2013 edition of the bestselling vSphere book on the market Virtualization remains the hottest trend in the IT world, and VMware vSphere is the industry's most widely deployed virtualization solution. The demand for IT professionals skilled in virtualization and cloud-related technologies is great and expected to keep growing. This comprehensive Sybex guide covers all the features and capabilities of VMware vSphere, showing administrators step by step how to install, configure, operate, manage, and secure it. This perfect blend of hands-on instruction, conceptual explanation, and practic

  13. High pressure gas spheres for neutron and photon experiments

    Science.gov (United States)

    Rupp, G.; Petrich, D.; Käppeler, F.; Kaltenbaek, J.; Leugers, B.; Reifarth, R.

    2009-09-01

    High pressure gas spheres have been designed and successfully used in several nuclear physics experiments on noble gases. The pros and cons of this solution are the simple design and the high reliability versus the fact that the density is limited to 40-60% of liquid or solid gas samples. Originally produced for neutron capture studies at keV energies, the comparably small mass of the gas spheres were an important advantage, which turned out to be of relevance for other applications as well. The construction, performance, and operation of the spheres are described and examples for their use are presented.

  14. Twistor Interpretation of Harmonic Spheres and Yang–Mills Fields

    Directory of Open Access Journals (Sweden)

    Armen Sergeev

    2015-03-01

    Full Text Available We consider the twistor descriptions of harmonic maps of the Riemann sphere into Kähler manifolds and Yang–Mills fields on four-dimensional Euclidean space. The motivation to study twistor interpretations of these objects comes from the harmonic spheres conjecture stating the existence of the bijective correspondence between based harmonic spheres in the loop space \\(\\Omega G\\ of a compact Lie group \\(G\\ and the moduli space of Yang–Mills \\(G\\-fields on \\(\\mathbb R^4\\.

  15. Ensuring Economic Security in Lending Sphere

    Directory of Open Access Journals (Sweden)

    Ivan Vadimovich Kochikin

    2016-06-01

    Full Text Available Relevance of the topic is determined by the need for sustainable development of the country’s banking system, capable of ensuring the process of raising funds to producers and the public for their projects. One of the implementation of this objective is to discourage unfair behavior in financial markets. Trust is a key factor in the development of financial markets, therefore it is necessary to suppress the appearance of unfair practices and participants – black creditors, falsification of financial statements, trading on insider information and market manipulation. It requires a whole range of activities, and above all ensuring the inevitability and proportionality of punishment for unscrupulous players, the introduction of requirements for the business reputation of the management of financial institutions.The article is devoted to structuring legal violations in the lending sphere. The analysis of indicators of credit organizations in Russia was conducted to fulfill this aim. This analysis revealed the causes of sustainable growth of overdue accounts payable – job cuts in enterprises, violations in the financial sector, various errors in the credit granting / raising. The authors carry out the systematization and classification of offenses in the area of lending, provide examples, as well as factual material illustrating the violations in the lending process having the characteristics of a fraud. The article substantiates the obligations of employees of the credit institution, in the result of which risks of granting credit to fraudsters can be reduced. The methods of fraud prevention should include the identified methods of protection against fraud in the area under consideration – exchange of information by banks associated with the criminal intentions of customers; technology development and technical support, training, and personnel responsibilities.

  16. TIDALLY DRIVEN DYNAMOS IN A ROTATING SPHERE

    International Nuclear Information System (INIS)

    Cébron, D.; Hollerbach, R.

    2014-01-01

    Large-scale planetary or stellar magnetic fields generated by a dynamo effect are mostly attributed to flows forced by buoyancy forces in electrically conducting fluid layers. However, these large-scale fields may also be controlled by tides, as previously suggested for the star τ-boo, Mars, or the early Moon. By simulating a small local patch of a rotating fluid, Barker and Lithwick have recently shown that tides can drive small-scale dynamos by exciting a hydrodynamic instability, the so-called elliptical (or tidal) instability. By performing global magnetohydrodynamic simulations of a rotating spherical fluid body, we investigate if this instability can also drive the observed large-scale magnetic fields. We are thus interested in the dynamo threshold and the generated magnetic field in order to test if such a mechanism is relevant for planets and stars. Rather than solving the problem in a geometry deformed by tides, we consider a spherical fluid body and add a body force to mimic the tidal deformation in the bulk of the fluid. This allows us to use an efficient spectral code to solve the magnetohydrodynamic problem. We first compare the hydrodynamic results with theoretical asymptotic results and numerical results obtained in a truly deformed ellipsoid, which confirms the presence of elliptical instability. We then perform magnetohydrodynamic simulations and investigate the dynamo capability of the flow. Kinematic and self-consistent dynamos are finally simulated, showing that the elliptical instability is capable of generating a dipole-dominated large-scale magnetic field in global simulations of a fluid rotating sphere

  17. Developmental coordination disorder

    Science.gov (United States)

    Developmental coordination disorder can lead to: Learning problems Low self-esteem resulting from poor ability at sports and teasing by other children Repeated injuries Weight gain as a result of not wanting to participate ...

  18. Supercritical Airfoil Coordinates

    Data.gov (United States)

    National Aeronautics and Space Administration — Rectangular Supercritical Wing (Ricketts) - design and measured locations are provided in an Excel file RSW_airfoil_coordinates_ricketts.xls . One sheet is with Non...

  19. Regional transit coordination guidebook.

    Science.gov (United States)

    2009-01-01

    Constant growth in rural areas and extensive suburban development have contributed to increasingly more people needing seamless and adequate public transportation into and from nearby cities. Coordinating existing services or determining the need for...

  20. Environmental Compliance Issue Coordination

    Science.gov (United States)

    An order to establish the Department of Energy (DOE) requirements for coordination of significant environmental compliance issues to ensure timely development and consistent application of Departmental environmental policy and guidance

  1. Haskell_#: Coordinating Functional Processes

    OpenAIRE

    Junior, Francisco Heron de Carvalho; Lins, Rafael Dueire

    2012-01-01

    This paper presents Haskell#, a coordination language targeted at the efficient implementation of parallel scientific applications on loosely coupled parallel architectures, using the functional language Haskell. Examples of applications, their implementation details and performance figures are presented.

  2. Understanding social motor coordination.

    Science.gov (United States)

    Schmidt, R C; Fitzpatrick, Paula; Caron, Robert; Mergeche, Joanna

    2011-10-01

    Recently there has been much interest in social coordination of motor movements, or as it is referred to by some researchers, joint action. This paper reviews the cognitive perspective's common coding/mirror neuron theory of joint action, describes some of its limitations and then presents the behavioral dynamics perspective as an alternative way of understanding social motor coordination. In particular, behavioral dynamics' ability to explain the temporal coordination of interacting individuals is detailed. Two experiments are then described that demonstrate how dynamical processes of synchronization are apparent in the coordination underlying everyday joint actions such as martial art exercises, hand-clapping games, and conversations. The import of this evidence is that emergent dynamic patterns such as synchronization are the behavioral order that any neural substrate supporting joint action (e.g., mirror systems) would have to sustain. Copyright © 2010 Elsevier B.V. All rights reserved.

  3. On the motion of linked spheres in a Stokes flow

    Science.gov (United States)

    Box, F.; Han, E.; Tipton, C. R.; Mullin, T.

    2017-04-01

    The results of an experimental investigation into the motion of linked spheres at low Reynolds number are presented. Small permanent magnets were embedded in the spheres and torques were generated by application of an external magnetic field. Pairs of neutrally buoyant spheres, connected by either glass rods or thin elastic struts, move in a reciprocal orbit when driven by an oscillatory field. An array of three spheres linked by elastic struts buckles in a periodic, non-reciprocal manner. The induced magneto-elastic buckling propels the elemental swimmer and we find that the geometrical asymmetry of the device, introduced by the struts of different lengths, determines the swimming direction. We propose that this novel method of creating movement remotely is suitable for miniaturization.

  4. Equivariant harmonic maps into the sphere via isoparametric maps

    International Nuclear Information System (INIS)

    Xin, Y.L.

    1992-08-01

    By using concrete isoparametric maps we obtain some new equivariant harmonic maps between spheres and solve equivariant boundary value problems for harmonic maps from unit open ball B m+1 into S n . (author). 22 refs

  5. Friction and drag forces on spheres propagating down inclined planes

    Science.gov (United States)

    Tee, Yi Hui; Longmire, Ellen

    2017-11-01

    When a submerged sphere propagates along an inclined wall at terminal velocity, it experiences gravity, drag, lift, and friction forces. In the related equations of motion, the drag, lift and friction coefficients are unknown. Experiments are conducted to determine the friction and drag coefficients of the sphere over a range of Reynolds numbers. Through high speed imaging, translational and rotational velocities of spheres propagating along a glass plate are determined in liquids with several viscosities. The onset of sliding motion is identified by computing the dimensionless rotation rate of the sphere. Using drag and lift coefficients for Re friction coefficients are calculated for several materials. The friction coefficients are then employed to estimate the drag coefficient for 350 frictional force over this Re range. Supported by NSF (CBET-1510154).

  6. [The power of religion in the public sphere] / Alar Kilp

    Index Scriptorium Estoniae

    Kilp, Alar, 1969-

    2012-01-01

    Arvustus: Buthler, Judith, Habermas, Jürgen, Taylor, Charles, West, Cornel. The power of religion in the public sphere. (Eduardo Mendieta, Jonathan VanAntwerpen (eds.) Afterword by Craig Calhoun.) New York ; Chichester : Columbia University Press, 2011

  7. Method for producing dustless graphite spheres from waste graphite fines

    Science.gov (United States)

    Pappano, Peter J [Oak Ridge, TN; Rogers, Michael R [Clinton, TN

    2012-05-08

    A method for producing graphite spheres from graphite fines by charging a quantity of spherical media into a rotatable cylindrical overcoater, charging a quantity of graphite fines into the overcoater thereby forming a first mixture of spherical media and graphite fines, rotating the overcoater at a speed such that the first mixture climbs the wall of the overcoater before rolling back down to the bottom thereby forming a second mixture of spherical media, graphite fines, and graphite spheres, removing the second mixture from the overcoater, sieving the second mixture to separate graphite spheres, charging the first mixture back into the overcoater, charging an additional quantity of graphite fines into the overcoater, adjusting processing parameters like overcoater dimensions, graphite fines charge, overcoater rotation speed, overcoater angle of rotation, and overcoater time of rotation, before repeating the steps until graphite fines are converted to graphite spheres.

  8. (Dis)guises: Spheres of Government, Functional Areas and Authority

    African Journals Online (AJOL)

    regional planning and development', 'urban and rural development', 'provincial planning' and 'municipal planning' are divided among the three spheres of government. Yet the boundaries between these items listed in Schedules 4 and 5 of ...

  9. A Reaction Sphere for High Performance Attitude Control, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Our innovative reaction sphere (Doty pending patent application serial number 61/164,868) has the potential to provide much higher performance than a conventional...

  10. Method and apparatus for producing small hollow spheres

    International Nuclear Information System (INIS)

    Hendricks, C.D.

    1979-01-01

    A method and apparatus are described for producing small hollow spheres of glass, metal or plastic, wherein the sphere material is mixed with or contains as part of the composition a blowing agent which decomposes at high temperature (T greater than or equal to 600 0 C). As the temperature is quickly raised, the blowing agent decomposes and the resulting gas expands from within, thus forming a hollow sphere of controllable thickness. The thus produced hollow spheres (20 to 10 3 μm) have a variety of application, and are particularly useful in the fabrication of targets for laser implosion such as neutron sources, laser fusion physics studies, and laser initiated fusion power plants

  11. SPHERES: From Ground Development to Operations on ISS

    Science.gov (United States)

    Katterhagen, A.

    2015-01-01

    SPHERES (Synchronized Position Hold Engage and Reorient Experimental Satellites) is an internal International Space Station (ISS) Facility that supports multiple investigations for the development of multi-spacecraft and robotic control algorithms. The SPHERES Facility on ISS is managed and operated by the SPHERES National Lab Facility at NASA Ames Research Center (ARC) at Moffett Field California. The SPHERES Facility on ISS consists of three self-contained eight-inch diameter free-floating satellites which perform the various flight algorithms and serve as a platform to support the integration of experimental hardware. To help make science a reality on the ISS, the SPHERES ARC team supports a Guest Scientist Program (GSP). This program allows anyone with new science the possibility to interface with the SPHERES team and hardware. In addition to highlighting the available SPHERES hardware on ISS and on the ground, this presentation will also highlight ground support, facilities, and resources available to guest researchers. Investigations on the ISS evolve through four main phases: Strategic, Tactical, Operations, and Post Operations. The Strategic Phase encompasses early planning beginning with initial contact by the Principle Investigator (PI) and the SPHERES program who may work with the PI to assess what assistance the PI may need. Once the basic parameters are understood, the investigation moves to the Tactical Phase which involves more detailed planning, development, and testing. Depending on the nature of the investigation, the tactical phase may be split into the Lab Tactical Phase or the ISS Tactical Phase due to the difference in requirements for the two destinations. The Operations Phase is when the actual science is performed; this can be either in the lab, or on the ISS. The Post Operations Phase encompasses data analysis and distribution, and generation of summary status and reports. The SPHERES Operations and Engineering teams at ARC is composed of

  12. Relaxation of Thick-Walled Cylinders and Spheres

    DEFF Research Database (Denmark)

    Saabye Ottosen, N.

    1982-01-01

    Using the nonlinear creep law proposed by Soderberg, (1936) closed-form solutions are derived for the relaxation of incompressible thick-walled spheres and cylinders in plane strain. These solutions involve series expressions which, however, converge very quickly. By simply ignoring these series...... expressions, extremely simple approximate solutions are obtained. Despite their simplicity these approximations possess an accuracy that is superior to approximations currently in use. Finally, several physical aspects related to the relaxation of cylinders and spheres are discussed...

  13. Integral measurements using the 'sphere method'. The case of carbon

    International Nuclear Information System (INIS)

    Haouat, G.; Lachkar, J.; Patin, Y.; Cocu, F.; Sigaud, J.; Cotten, D.

    1977-01-01

    The time-of-flight spectrum of direct and scattered neutrons with a 10cm diameter carbon sphere. (The direct neutron energy is 14.81MeV, the basic time-of-flight being 6m). The time-of-flight spectrum of the neutrons from T(d,n) 4 He is given in the same experimental conditions (without the carbon sphere) [fr

  14. Silica hollow spheres with nano-macroholes like diatomaceous earth.

    Science.gov (United States)

    Fujiwara, Masahiro; Shiokawa, Kumi; Sakakura, Ikuko; Nakahara, Yoshiko

    2006-12-01

    Artificial synthesis of hollow cell walls of diatoms is an ultimate target of nanomaterial science. The addition of some water-soluble polymers such as sodium polymethacrylate to a solution of water/oil/water emulsion system, which is an essential step of the simple synthetic procedure of silica hollow spheres (microcapsules), led to the formation of silica hollow spheres with nano-macroholes (>100 nm) in their shell walls, the morphologies of which are analogous to those of diatom earth.

  15. A note on automorphisms of the sphere complex

    Indian Academy of Sciences (India)

    Introduction. In [1], Aramayona and Souto have shown that the group Aut(S(M)) of simplicial auto- morphisms of the sphere complex S(M) associated to the manifold M = ♯nS2 × S1 is isomorphic to the group Out(Fn) of outer automorphisms of the free group Fn of rank n ≥ 3. The idea of the proof is as follows: the sphere ...

  16. Coordination polyhedra LnOn (Ln = Er, Tm, Yb, Lu) in crystal structures

    International Nuclear Information System (INIS)

    Vologzhanina, A.V.; Pushkin, D.V.; Serezhkin, V.N.

    2006-01-01

    Using Voronoi-Dirichlet polyhedra and the method of intercrossing spheres crystal chemical analysis of 728 compounds containing 976 crystallographically nonequivalent types of polyhedra LnO n (Ln = Er, Tm, Yb, Lu) are done. It is detected that coordination number of Ln atoms take on a value from 3 to 10 and 14 types of coordination polyhedra are realized in the structure of compounds considered. It is shown that in spite of wide variety of coordination numbers the volumes of Voronoi-Dirichlet polyhedra depend on Ln atom nature and valent state only [ru

  17. Coordination Environment of Copper Sites in Cu-CHA Zeolite Investigated by Electron Paramagnetic Resonance

    DEFF Research Database (Denmark)

    Godiksen, Anita; Stappen, Frederick N.; Vennestrøm, Peter N. R.

    2014-01-01

    Cu-CHA combines high activity for the selective catalytic reduction (SCR) reaction with better hydrothermal stability and selectivity compared to other copper-substituted zeolites. At the same time Cu-CHA offers an opportunity for unraveling the coordination environment of the copper centers since...... of the EPR silent monomeric Cu2+ in copper-substituted zeolites is suggested to be copper species with an approximate trigonal coordination sphere appearing during the dehydration. After complete dehydration at 250 °C the majority of the EPR silent Cu2+ is suggested to exist as Cu2+–OH– coordinated to two...

  18. Electric potential on solid spheres in a plasma

    Science.gov (United States)

    De, B. R.

    1974-01-01

    Derivation of the general expression for the potential on a solid sphere immersed in a plasma, showing the dependence of the potential on the radius (a) of the sphere and the radius (s) of the plasma sheath that develops around the sphere. In the limit where the radius a is much larger than the sheath thickness s-a, the well-known result for the potential on an infinite wall in contact with a plasma is recovered from this expression. At the other extreme, where s is much larger than a, the result derived by Spitzer (1941) for the potential on spherical grains in the interstellar plasma is obtained. Since the surface of the sphere forms a sink for the charged particles, there is a net drift of the plasma towards the surface. The effect of this drift on the potential is examined. Finally, for very small metallic spheres, an effect leading to a revision of the potential is discussed. This effect consists in a lowering of the potential barrier for the electrons due to the image force. The various effects limiting the potential on spheres are discussed.

  19. Squeeze flow of a Carreau fluid during sphere impact

    KAUST Repository

    Uddin, J.

    2012-07-19

    We present results from a combined numerical and experimental investigation into the squeeze flow induced when a solid sphere impacts onto a thin, ultra-viscous film of non-Newtonian fluid. We examine both the sphere motion through the liquid as well as the fluid flow field in the region directly beneath the sphere during approach to a solid plate. In the experiments we use silicone oil as the model fluid, which is well-described by the Carreau model. We use high-speed imaging and particle tracking to achieve flow visualisation within the film itself and derive the corresponding velocity fields. We show that the radial velocity either diverges as the gap between the sphere and the wall diminishes (Z tip → 0) or that it reaches a maximum value and then decays rapidly to zero as the sphere comes to rest at a non-zero distance (Z tip = Z min ) away from the wall. The horizontal shear rate is calculated and is responsible for significant viscosity reduction during the approach of the sphere. Our model of this flow, based on lubrication theory, is solved numerically and compared to experimental trials. We show that our model is able to correctly describe the physical features of the flow observed in the experiments.

  20. Sound Scattering and Its Reduction by a Janus Sphere Type

    Directory of Open Access Journals (Sweden)

    Deliya Kim

    2014-01-01

    Full Text Available Sound scattering by a Janus sphere type is considered. The sphere has two surface zones: a soft surface of zero acoustic impedance and a hard surface of infinite acoustic impedance. The zones are arranged such that axisymmetry of the sound field is preserved. The equivalent source method is used to compute the sound field. It is shown that, by varying the sizes of the soft and hard zones on the sphere, a significant reduction can be achieved in the scattered acoustic power and upstream directivity when the sphere is near a free surface and its soft zone faces the incoming wave and vice versa for a hard ground. In both cases the size of the sphere’s hard zone is much larger than that of its soft zone. The boundary location between the two zones coincides with the location of a zero pressure line of the incoming standing sound wave, thus masking the sphere within the sound field reflected by the free surface or the hard ground. The reduction in the scattered acoustic power diminishes when the sphere is placed in free space. Variations of the scattered acoustic power and directivity with the sound frequency are also given and discussed.

  1. Scattering characteristics of relativistically moving concentrically layered spheres

    Science.gov (United States)

    Garner, Timothy J.; Lakhtakia, Akhlesh; Breakall, James K.; Bohren, Craig F.

    2018-02-01

    The energy extinction cross section of a concentrically layered sphere varies with velocity as the Doppler shift moves the spectral content of the incident signal in the sphere's co-moving inertial reference frame toward or away from resonances of the sphere. Computations for hollow gold nanospheres show that the energy extinction cross section is high when the Doppler shift moves the incident signal's spectral content in the co-moving frame near the wavelength of the sphere's localized surface plasmon resonance. The energy extinction cross section of a three-layer sphere consisting of an olivine-silicate core surrounded by a porous and a magnetite layer, which is used to explain extinction caused by interstellar dust, also depends strongly on velocity. For this sphere, computations show that the energy extinction cross section is high when the Doppler shift moves the spectral content of the incident signal near either of olivine-silicate's two localized surface phonon resonances at 9.7 μm and 18 μm.

  2. Global Calibration of Multiple Cameras Based on Sphere Targets

    Directory of Open Access Journals (Sweden)

    Junhua Sun

    2016-01-01

    Full Text Available Global calibration methods for multi-camera system are critical to the accuracy of vision measurement. Proposed in this paper is such a method based on several groups of sphere targets and a precision auxiliary camera. Each camera to be calibrated observes a group of spheres (at least three, while the auxiliary camera observes all the spheres. The global calibration can be achieved after each camera reconstructs the sphere centers in its field of view. In the process of reconstructing a sphere center, a parameter equation is used to describe the sphere projection model. Theoretical analysis and computer simulation are carried out to analyze the factors that affect the calibration accuracy. Simulation results show that the parameter equation can largely improve the reconstruction accuracy. In the experiments, a two-camera system calibrated by our method is used to measure a distance about 578 mm, and the root mean squared error is within 0.14 mm. Furthermore, the experiments indicate that the method has simple operation and good flexibility, especially for the onsite multiple cameras without common field of view.

  3. Pressure solution creep of random packs of spheres

    Science.gov (United States)

    Bernabé, Y.; Evans, B.

    2014-05-01

    We performed numerical calculations of compaction in aggregates of spherical grains, using Lehner and Leroy's (2004, hereinafter LL) constitutive model of pressure solution at grain contacts. That model is founded on a local definition of the thermodynamic driving force and leads to a fully coupled formulation of elastic deformation, dissolution, and diffusive transport along the grain boundaries. The initial geometry of the aggregate was generated by random packing of spheres with a small standard deviation of the diameters. During the simulations, isostatic loading was applied. The elastic displacements at the contacts were calculated according to Digby's (1981) nonlinear contact force model, and deformation by dissolution was evaluated using the LL formulation. The aggregate strain and porosity were tracked as a function of time for fixed temperature, applied effective pressure, and grain size. We also monitored values of the average and standard deviation of total load at each contact, the coordination number for packing, and the statistics of the contact dimensions. Because the simulations explicitly exclude processes such as fracturing, plastic flow, and transport owing to surface curvature, they can be used to test the influence of relative changes in the kinetics of dissolution and diffusion processes caused by contact growth and packing rearrangements. We found that the simulated strain data could be empirically fitted by two successive power laws of the form, ɛx ∝ tξ, where ξ was equal to 1 at very early times, but dropped to as low as 0.3 at longer times. The apparent sensitivity of strain rate to stress found in the simulations was much lower than predicted from constitutive laws that assume a single dominant process driven by average macroscopic loads. Likewise, the apparent activation enthalpy obtained from the simulated data was intermediate between that assumed for dissolution and diffusion, and, further, tended to decrease with time. These

  4. Plane shear flows of frictionless spheres: Kinetic theory and 3D soft-sphere discrete element method simulations

    OpenAIRE

    Vescovi, Dalila; Berzi, Diego; Richard, Patrick; Brodu, Nicolas

    2014-01-01

    International audience; We use existing 3D Discrete Element simulations of simple shear flows of spheres to evaluate the radial distribution function at contact that enables kinetic theory to correctly predict the pressure and the shear stress, for different values of the collisional coefficient of restitution. Then, we perform 3D Discrete Element simulations of plane flows of frictionless, inelastic spheres, sheared between walls made bumpy by gluing particles in a regular array, at fixed av...

  5. Collective modes in simple melts: Transition from soft spheres to the hard sphere limit.

    Science.gov (United States)

    Khrapak, Sergey; Klumov, Boris; Couëdel, Lénaïc

    2017-08-11

    We study collective modes in a classical system of particles with repulsive inverse-power-law (IPL) interactions in the fluid phase, near the fluid-solid coexistence (IPL melts). The IPL exponent is varied from n = 10 to n = 100 to mimic the transition from moderately soft to hard-sphere-like interactions. We compare the longitudinal dispersion relations obtained using molecular dynamic (MD) simulations with those calculated using the quasi-crystalline approximation (QCA) and find that this simple theoretical approach becomes grossly inaccurate for [Formula: see text]. Similarly, conventional expressions for high-frequency (instantaneous) elastic moduli, predicting their divergence as n increases, are meaningless in this regime. Relations of the longitudinal and transverse elastic velocities of the QCA model to the adiabatic sound velocity, measured in MD simulations, are discussed for the regime where QCA is applicable. Two potentially useful freezing indicators for classical particle systems with steep repulsive interactions are discussed.

  6. Two-spheres method for evaluating the metrological structural resolution in dimensional computed tomography

    Science.gov (United States)

    Zanini, F.; Carmignato, S.

    2017-11-01

    In recent years, x-ray computed tomography has been successfully applied as an innovative coordinate measurement technology for dimensional metrology. An important characteristic to be evaluated when testing the metrological performances of computed tomography systems is the metrological structural resolution for dimensional measurements, which describes the size of the smallest structure that can still be measured within error limits to be specified. The ‘two-spheres’ concept allows for the investigation of the metrological structural resolution by using a simple reference standard consisting of two touching spheres with the same nominal diameter. This work is aimed at defining and validating an enhanced method based on the ‘two-spheres’ concept and on a new measurement strategy. Advantages in using this method are discussed and a selection of the factors influencing the results are evaluated through experimental and simulation analyses.

  7. Outer-Sphere Reactivity Shift of Secondary Phosphine Oxide-Based Nickel Complexes: From Ethylene Hydrophosphinylation to Oligomerization.

    Science.gov (United States)

    Lhermet, Rudy; Moser, Emile; Jeanneau, Erwann; Olivier-Bourbigou, Hélène; Breuil, Pierre-Alain R

    2017-06-01

    A new dimension for secondary phosphine oxide (SPOs) ligands is described in this article. Demonstrated on original π-allylic nickel structures, these self-assembled complexes trigger catalytic hydrophosphinylation reactions. Addition of a Lewis acid B(C 6 F 5 ) 3 switches the reactivity towards migratory insertion and thus ethylene oligomerization through an unprecedented outer-sphere interaction with the coordinated SPO ligand. NMR experiments and X-ray analyses allowed for the observation of the formation of zwitterionic active species as well as their degradation pathway. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Tin-wall hollow ceramic spheres from slurries. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Chapman, A.T.; Cochran, J.K.

    1992-12-31

    The overall objective of this effort was to develop a process for economically fabricating thin-wall hollow ceramic spheres from conventional ceramic powders using dispersions. This process resulted in successful production of monosized spheres in the mm size range which were point contact bonded into foams. Thin-wall hollow ceramic spheres of small (one to five millimeter) diameter have novel applications as high-temperature insulation and light structural materials when bonded into monolithic foams. During Phase 1 of this program the objective as to develop a process for fabricating thin-wall hollow spheres from powder slurries using the coaxial nozzle fabrication method. Based on the success during Phase 1, Phase 2 was revised to emphasize the assessment of the potential structural and insulation applications for the spheres and modeling of the sphere formation process was initiated. As more understanding developed, it was clear that to achieve successful structural application, the spheres had to be bonded into monolithic foams and the effort was further expanded to include both bonding into structures and finite element mechanical modeling which became the basis of Phase 3. Successful bonding techniques and mechanical modeling resulted but thermal conductivities were higher than desired for insulating activities. In addition, considerable interest had been express by industry for the technology. Thus the final Phase 4 concentrated on methods to reduce thermal conductivity by a variety of techniques and technology transfer through individualized visits. This program resulted in three Ph.D. theses and 10 M.S. theses and they are listed in the appropriate technical sections.

  9. [Binocular coordination during reading].

    Science.gov (United States)

    Bassou, L; Granié, M; Pugh, A K; Morucci, J P

    1992-01-01

    Is there an effect on binocular coordination during reading of oculomotor imbalance (heterophoria, strabismus and inadequate convergence) and of functional lateral characteristics (eye preference and perceptually privileged visual laterality)? Recordings of the binocular eye-movements of ten-year-old children show that oculomotor imbalances occur most often among children whose left visual perceptual channel is privileged, and that these subjects can present optomotor dissociation and manifest lack of motor coordination. Close binocular motor coordination is far from being the norm in reading. The faster reader displays saccades of differing spatial amplitude and the slower reader an oculomotor hyperactivity, especially during fixations. The recording of binocular movements in reading appears to be an excellent means of diagnosing difficulties related to visual laterality and to problems associated with oculomotor imbalance.

  10. Introduction to Coordination Chemistry

    CERN Document Server

    Lawrance, Geoffrey Alan

    2010-01-01

    Introduction to Coordination Chemistry examines and explains how metals and molecules that bind as ligands interact, and the consequences of this assembly process. This book describes the chemical and physical properties and behavior of the complex assemblies that form, and applications that may arise as a result of these properties. Coordination complexes are an important but often hidden part of our world?even part of us?and what they do is probed in this book. This book distills the essence of this topic for undergraduate students and for research scientists.

  11. Quantifying linguistic coordination

    DEFF Research Database (Denmark)

    Fusaroli, Riccardo; Tylén, Kristian

    task (Bahrami et al 2010, Fusaroli et al. 2012) we extend to linguistic coordination dynamical measures of recurrence employed in the analysis of sensorimotor coordination (such as heart-rate (Konvalinka et al 2011), postural sway (Shockley 2005) and eye-movements (Dale, Richardson and Kirkham 2012......). We employ nominal recurrence analysis (Orsucci et al 2005, Dale et al 2011) on the decision-making conversations between the participants. We report strong correlations between various indexes of recurrence and collective performance. We argue this method allows us to quantify the qualities...

  12. Coordinate Standard Measurement Development

    Energy Technology Data Exchange (ETDEWEB)

    Hanshaw, R.A.

    2000-02-18

    A Shelton Precision Interferometer Base, which is used for calibration of coordinate standards, was improved through hardware replacement, software geometry error correction, and reduction of vibration effects. Substantial increases in resolution and reliability, as well as reduction in sampling time, were achieved through hardware replacement; vibration effects were reduced substantially through modification of the machine component dampening and software routines; and the majority of the machine's geometry error was corrected through software geometry error correction. Because of these modifications, the uncertainty of coordinate standards calibrated on this device has been reduced dramatically.

  13. Recursive Advice for Coordination

    DEFF Research Database (Denmark)

    Terepeta, Michal Tomasz; Nielson, Hanne Riis; Nielson, Flemming

    2012-01-01

    Aspect-oriented programming is a programming paradigm that is often praised for the ability to create modular software and separate cross-cutting concerns. Recently aspects have been also considered in the context of coordination languages, offering similar advantages. However, introducing aspect...... systems. Even though primarily used for analysis of recursive programs, we are able to adapt them to fit this new context.......Aspect-oriented programming is a programming paradigm that is often praised for the ability to create modular software and separate cross-cutting concerns. Recently aspects have been also considered in the context of coordination languages, offering similar advantages. However, introducing aspects...

  14. Review on the Celestial Sphere Positioning of FITS Format Image Based on WCS and Research on General Visualization

    Science.gov (United States)

    Song, W. M.; Fan, D. W.; Su, L. Y.; Cui, C. Z.

    2017-11-01

    Calculating the coordinate parameters recorded in the form of key/value pairs in FITS (Flexible Image Transport System) header is the key to determine FITS images' position in the celestial system. As a result, it has great significance in researching the general process of calculating the coordinate parameters. By combining CCD related parameters of astronomical telescope (such as field, focal length, and celestial coordinates in optical axis, etc.), astronomical images recognition algorithm, and WCS (World Coordinate System) theory, the parameters can be calculated effectively. CCD parameters determine the scope of star catalogue, so that they can be used to build a reference star catalogue by the corresponding celestial region of astronomical images; Star pattern recognition completes the matching between the astronomical image and reference star catalogue, and obtains a table with a certain number of stars between CCD plane coordinates and their celestial coordinates for comparison; According to different projection of the sphere to the plane, WCS can build different transfer functions between these two coordinates, and the astronomical position of image pixels can be determined by the table's data we have worked before. FITS images are used to carry out scientific data transmission and analyze as a kind of mainstream data format, but only to be viewed, edited, and analyzed in the professional astronomy software. It decides the limitation of popular science education in astronomy. The realization of a general image visualization method is significant. FITS is converted to PNG or JPEG images firstly. The coordinate parameters in the FITS header are converted to metadata in the form of AVM (Astronomy Visualization Metadata), and then the metadata is added to the PNG or JPEG header. This method can meet amateur astronomers' general needs of viewing and analyzing astronomical images in the non-astronomical software platform. The overall design flow is realized

  15. Formation of Innovative Infrastructure of the Industrial Sphere

    Directory of Open Access Journals (Sweden)

    M. Ya. Veselovsky

    2017-01-01

    Full Text Available Purpose: in article problems of formation of innovative infrastructure of the industrial sphere in the Russian Federation are investigated, her merits and demerits are considered. In the context of foreign experience the analysis of statistics of development of innovative infrastructure on the basis of which is carried out the main shortcomings constraining efficiency of her work are allocated. Among them lack of cooperation between the organizations of infrastructure, a gap between scientific sector and business community, lack of effective communications between participants of innovative process, information opacity, extremely insufficient financing, and also low demand for innovations from the industrial enterprises, lack of motivation at business to carry out financing of innovative projects. Authors offer mechanisms of formation and management of innovative infrastructure. The purpose of article is increase in efficiency of innovative infrastructure of the industrial sphere. Article tasks: to analyse a condition of innovative infrastructure of the industrial sphere in Russia; to study foreign experience of formation of innovative infrastructure; to reveal shortcomings of functioning of innovative infrastructure; to offer mechanisms of formation and management of innovative infrastructure of the industrial sphere. Methods: hen carrying out a research data of Rosstat, legislative and normative legal acts, state programs of development of innovative activities and the industrial sphere, fundamental and application-oriented works of authoritative scientists in the field of innovative development were the main sources of basic data. The research is based on theoretical methods of scientific knowledge, in particular use of methods of synthesis and deduction, and also methods of empirical knowledge for which allowed to open a range of a set of problems which hinder with innovative development of the industrial sphere. Results: the analysis of the

  16. Glass transition of dense fluids of hard and compressible spheres

    Science.gov (United States)

    Berthier, Ludovic; Witten, Thomas A.

    2009-08-01

    We use computer simulations to study the glass transition of dense fluids made of polydisperse repulsive spheres. For hard particles, we vary the volume fraction, φ , and use compressible particles to explore finite temperatures, T>0 . In the hard sphere limit, our dynamic data show evidence of an avoided mode-coupling singularity near φMCT≈0.592 ; they are consistent with a divergence of equilibrium relaxation times occurring at φ0≈0.635 , but they leave open the existence of a finite temperature singularity for compressible spheres at volume fraction φ>φ0 . Using direct measurements and a scaling procedure, we estimate the equilibrium equation of state for the hard sphere metastable fluid up to φ0 , where pressure remains finite, suggesting that φ0 corresponds to an ideal glass transition. We use nonequilibrium protocols to explore glassy states above φ0 and establish the existence of multiple equations of state for the unequilibrated glass of hard spheres, all diverging at different densities in the range φɛ[0.642,0.664] . Glassiness thus results in the existence of a continuum of densities where jamming transitions can occur.

  17. Crown sealing and buckling instability during water entry of spheres

    KAUST Repository

    Marston, J. O.

    2016-04-05

    We present new observations from an experimental investigation of the classical problem of the crown splash and sealing phenomena observed during the impact of spheres onto quiescent liquid pools. In the experiments, a 6 m tall vacuum chamber was used to provide the required ambient conditions from atmospheric pressure down to of an atmosphere, whilst high-speed videography was exploited to focus primarily on the above-surface crown formation and ensuing dynamics, paying particular attention to the moments just prior to the surface seal. In doing so, we have observed a buckling-type azimuthal instability of the crown. This instability is characterised by vertical striations along the crown, between which thin films form that are more susceptible to the air flow and thus are drawn into the closing cavity, where they atomize to form a fine spray within the cavity. To elucidate to the primary mechanisms and forces at play, we varied the sphere diameter, liquid properties and ambient pressure. Furthermore, a comparison between the entry of room-temperature spheres, where the contact line pins around the equator, and Leidenfrost spheres (i.e. an immersed superheated sphere encompassed by a vapour layer), where there is no contact line, indicates that the buckling instability appears in all crown sealing events, but is intensified by the presence of a pinned contact line. © 2016 Cambridge University Press.

  18. Corrected Four-Sphere Head Model for EEG Signals

    Directory of Open Access Journals (Sweden)

    Solveig Næss

    2017-10-01

    Full Text Available The EEG signal is generated by electrical brain cell activity, often described in terms of current dipoles. By applying EEG forward models we can compute the contribution from such dipoles to the electrical potential recorded by EEG electrodes. Forward models are key both for generating understanding and intuition about the neural origin of EEG signals as well as inverse modeling, i.e., the estimation of the underlying dipole sources from recorded EEG signals. Different models of varying complexity and biological detail are used in the field. One such analytical model is the four-sphere model which assumes a four-layered spherical head where the layers represent brain tissue, cerebrospinal fluid (CSF, skull, and scalp, respectively. While conceptually clear, the mathematical expression for the electric potentials in the four-sphere model is cumbersome, and we observed that the formulas presented in the literature contain errors. Here, we derive and present the correct analytical formulas with a detailed derivation. A useful application of the analytical four-sphere model is that it can serve as ground truth to test the accuracy of numerical schemes such as the Finite Element Method (FEM. We performed FEM simulations of the four-sphere head model and showed that they were consistent with the corrected analytical formulas. For future reference we provide scripts for computing EEG potentials with the four-sphere model, both by means of the correct analytical formulas and numerical FEM simulations.

  19. Hydrothermal Syntheses of Colloidal Carbon Spheres from Cyclodextrins

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Yongsoon; Wang, Li Q.; Bae, In-Tae; Arey, Bruce W.; Exarhos, Gregory J.

    2008-09-18

    Colloidal carbon spheres have been prepared from aqueous alpha-, beta-, and gamma-cyclodextrin (CD) solutions in closed systems under hydrothermal conditions at 160 oC. Both liquid and solid-state 13C NMR spectra taken for samples at different reaction times have been used to monitor the dehydration and carbonization pathways. CD slowly hydrolyzes to glucose and forms 5-hydroxymethyl furfural (HMF) followed by carbonization into colloidal carbon spheres. The isolated carbon spheres are 70-150 nm in diameter, exhibit a core-shell structure, and are comprised of a condensed core (C=C) peppered with resident chemical functionalities including carboxylate and hydroxyl groups. Evidence from 13C solid-state NMR and FT-IR spectra reveal that the evolving carbon spheres show a gradual increase in the amount of aromatic carbon as a function of reaction time and that the carbon spheres generated from gamma-CD contain significantly higher aromatic carbon than those derived from alpha- and beta-CD.

  20. ORSPHERE: CRITICAL, BARE, HEU(93.2)-METAL SPHERE

    Energy Technology Data Exchange (ETDEWEB)

    Margaret A. Marshall

    2013-09-01

    In the early 1970’s Dr. John T. Mihalczo (team leader), J.J. Lynn, and J.R. Taylor performed experiments at the Oak Ridge Critical Experiments Facility (ORCEF) with highly enriched uranium (HEU) metal (called Oak Ridge Alloy or ORALLOY) in an attempt to recreate GODIVA I results with greater accuracy than those performed at Los Alamos National Laboratory in the 1950’s (HEU-MET-FAST-001). The purpose of the Oak Ridge ORALLOY Sphere (ORSphere) experiments was to estimate the unreflected and unmoderated critical mass of an idealized sphere of uranium metal corrected to a density, purity, and enrichment such that it could be compared with the GODIVA I experiments. “The very accurate description of this sphere, as assembled, establishes it as an ideal benchmark for calculational methods and cross-section data files.” (Reference 1) While performing the ORSphere experiments care was taken to accurately document component dimensions (±0. 0001 in. for non-spherical parts), masses (±0.01 g), and material data The experiment was also set up to minimize the amount of structural material in the sphere proximity. A three part sphere was initially assembled with an average radius of 3.4665 in. and was then machined down to an average radius of 3.4420 in. (3.4425 in. nominal). These two spherical configurations were evaluated and judged to be acceptable benchmark experiments; however, the two experiments are highly correlated.

  1. Experimental performance evaluation of sintered Gd spheres packed beds

    DEFF Research Database (Denmark)

    Tura, A.; Nielsen, Klaus K.; Van Nong, Ngo

    2016-01-01

    Research in magnetic refrigeration heavily relies on the use of packed spheres in regenerators, however little investigation to verify that such non-monolithic arrangements guarantee a sufficiently constrained structure has yet been performed. This work presents a preliminary comparison of the pe......Research in magnetic refrigeration heavily relies on the use of packed spheres in regenerators, however little investigation to verify that such non-monolithic arrangements guarantee a sufficiently constrained structure has yet been performed. This work presents a preliminary comparison...... of the performance of AMRs consisting of Gd spheres with diameters ranging from 450-550 microns partially sintered by Spark Plasma Sintering (SPS) to similar spheres, sorted in the same size range and from the same batch, but merely packed. Pressure drop is compared at uniform temperature and at a range of heat...... rejection temperatures and temperature spans. Performance is compared in terms of temperature span at a range of heat rejection temperatures (295-308 K) and 0 and 10 W cooling loads. Results show a moderate increase of pressure drop with the sintered spheres, while temperature spans were consistently 2...

  2. Non-uniformly sampled grids in double pole coordinate system for freeform reflector construction

    Science.gov (United States)

    Ma, Donglin; Pacheco, Shaun; Feng, Zexin; Liang, Rongguang

    2015-08-01

    We propose a new method to design freeform reflectors by nonuniformly sampling the source intensity distribution in double pole coordinate system. In double pole coordinate system, there is no pole for the whole hemisphere because both poles of the spherical coordinate system are moved to southernmost point of the sphere and overlapped together. With symmetric definition of both angular coordinates in the modified double pole coordinate system, a better match between the source intensity distribution and target irradiance distribution can be achieved for reflectors with large acceptance solid angle, leading to higher light efficiency and better uniformity on the target surface. With non-uniform sampling of the source intensity, we can design circular freeform reflector to obtain uniform rectangular illumination pattern. Aided by the feedback optimization, the freeform reflector can achieve the collection efficiency for ideal point source over 0.7 and relative standard deviation (RSD) less than 0.1.

  3. Coordination failure caused by sunspots

    DEFF Research Database (Denmark)

    Beugnot, Julie; Gürgüç, Zeynep; Øvlisen, Frederik Roose

    2012-01-01

    on the efficient equilibrium, we consider sunspots as a potential reason for coordination failure. We conduct an experiment with a three player 2x2x2 game in which coordination on the efficient equilibrium is easy and should normally occur. In the control session, we find almost perfect coordination on the payoff......-dominant equilibrium, but in the sunspot treatment, dis-coordination is frequent. Sunspots lead to significant inefficiency, and we conclude that sunspots can indeed cause coordination failure....

  4. Coordination Compounds in Biology

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 4; Issue 6. Coordination Compounds in Biology - The Chemistry of Vitamin B12 and Model Compounds. K Hussian Reddy. General Article Volume 4 Issue 6 June 1999 pp 67-77 ...

  5. Coordination Compounds in Biology

    Indian Academy of Sciences (India)

    Coordination Compounds in Biology equatorial ligand, there are two axial ligands in most B. 12 derivatives. Derivatives of B12. The various derivatives of B. 12 result most commonly from changes in the axial ligands bound to cobalt. Often it is convenient to draw a greatly abbreviated structure for a B. 12 molecule using a ...

  6. Polymeric coordination compounds

    Indian Academy of Sciences (India)

    Administrator

    Metal coordination polymers with one- and two-dimensional structures are of current interest due to their possible relevance to material science 1. In continuation of our previous studies 2,3, several new polymeric compounds are reported here. Among the complexes of silver with aminomethyl pyridine (amp) ...

  7. Coordination of mobile labor

    Czech Academy of Sciences Publication Activity Database

    Steiner, Jakub

    2008-01-01

    Roč. 139, č. 1 (2008), s. 25-46 ISSN 0022-0531 R&D Projects: GA MŠk LC542 Institutional research plan: CEZ:AV0Z70850503 Keywords : coordination * general equilibrium * global games Subject RIV: AH - Economics Impact factor: 1.224, year: 2008

  8. Block coordination copolymers

    Energy Technology Data Exchange (ETDEWEB)

    Koh, Kyoung Moo; Wong-Foy, Antek G.; Matzger, Adam J.; Benin, Annabelle I.; Willis, Richard R.

    2012-12-04

    The present invention provides compositions of crystalline coordination copolymers wherein multiple organic molecules are assembled to produce porous framework materials with layered or core-shell structures. These materials are synthesized by sequential growth techniques such as the seed growth technique. In addition, the invention provides a simple procedure for controlling functionality.

  9. Block coordination copolymers

    Energy Technology Data Exchange (ETDEWEB)

    Koh, Kyoung Moo; Wong-Foy, Antek G; Matzger, Adam J; Benin, Annabelle I; Willis, Richard R

    2014-11-11

    The present invention provides compositions of crystalline coordination copolymers wherein multiple organic molecules are assembled to produce porous framework materials with layered or core-shell structures. These materials are synthesized by sequential growth techniques such as the seed growth technique. In addition, the invention provides a simple procedure for controlling functionality.

  10. Block coordination copolymers

    Energy Technology Data Exchange (ETDEWEB)

    Koh, Kyoung Moo; Wong-Foy, Antek G; Matzger, Adam J; Benin, Annabelle I; Willis, Richard R

    2012-11-13

    The present invention provides compositions of crystalline coordination copolymers wherein multiple organic molecules are assembled to produce porous framework materials with layered or core-shell structures. These materials are synthesized by sequential growth techniques such as the seed growth technique. In addition, the invention provides a simple procedure for controlling functionality.

  11. Reusability of coordination programs

    NARCIS (Netherlands)

    F. Arbab (Farhad); C.L. Blom (Kees); F.J. Burger (Freek); C.T.H. Everaars (Kees)

    1996-01-01

    textabstractIsolating computation and communication concerns into separate pure computation and pure coordination modules enhances modularity, understandability, and reusability of parallel and/or distributed software. This can be achieved by moving communication primitives (such as SendMessage and

  12. [Civilian-military coordination].

    Science.gov (United States)

    de Montravel, G

    2002-01-01

    Current humanitarian emergencies create complex, mutidimensional situations that stimulate simultaneous responses from a wide variety of sources including governments, non-governmental organizations (NGO), United Nations agencies, and private individuals. As a result, it has become essential to establish a coherent framework in which each actor can contribute promptly and effectively to the overall effort. This is the role of the United Nations Office for the Coordination of Humanitarian Affairs. Regardless of the circumstances and level of coordination, cooperation and collaboration between humanitarian and military personnel, it is necessary to bear in mind their objectives. The purpose of humanitarian action is to reduce human suffering. The purpose of military intervention is to stop warfare. The author of this article will discuss the three major obstacles to civilian-military coordination (strategic, tactical, and operational). Operations cannot be conducted smoothly and differences cannot be ironed out without mutual respect between the two parties, an explicit definition of their respective duties and responsibilities, a clear understanding of their cultural differences, and the presence of an organization and facilities for coordination and arbitrage by a neutral referee.

  13. Impact of a Hydrophobic Sphere onto a Bath

    Science.gov (United States)

    Harris, Daniel M.; Edmonds, John; Galeano-Rios, Carlos A.; Milewski, Paul A.

    2017-11-01

    Small hydrophobic particles impacting a water surface can rebound completely from the interface (Lee & Kim, Langmuir, 2008). In the present work, we focus on the bouncing dynamics of millimetric hydrophobic spheres impacting the surface of a quiescent water bath. Particular attention is given to the dependence of the normal coefficient of restitution and contact time on the impact velocity and the radius and density of the sphere. Our experimental observations are compared to the predictions of a fluid model derived from linearized Navier-Stokes under the assumption of a high Reynolds number regime (Galeano-Rios et al., JFM, in press). In the model, the motions of the sphere and the fluid interface are found by imposing the natural geometric and kinematic compatibility conditions. Future directions will be discussed. C.A.G.-R. and P.A.M. gratefully acknowledge support through the EPSRC project EP/N018176/1.

  14. Fast breeder reactor primary pump discharge sphere support device

    International Nuclear Information System (INIS)

    Terny, P.; Blaix, J.C.

    1987-01-01

    In their lower part, the fast breeder reactor primary pump are connected to a sphere-shaped discharge capacity from which the diagrid feedpipes emerge. This discharge capacity is rigidly set on the strongback by means of a device that bears the forces resulting from the bottom effect. This last being generated by the pressure of the sodium discharged from primary pump. When the reactor operating conditions undergo some rapid changes combined to temperature changes, the structures differential expansions result in high stresses in the sphere support as well as in the feedpipes. This paper aims at describing a sphere support which is provided with flexibility under horizontal forces and a higher stiffness under vertical forces for a better adaptation to the various loading conditions. (orig.)

  15. Burning molten metallic spheres: One class of ball lightning?

    Science.gov (United States)

    Stephan, Karl D.; Massey, Nathan

    2008-08-01

    Abrahamson and Dinniss [2000. Ball lightning caused by oxidation of nanoparticle networks from normal lightning strikes on soil. Nature 403, 519-521] proposed a theory of ball lighting in which silicon nanoparticles undergo slow oxidation and emit light. Paiva et al. [2007. Production of ball-lightning-like luminous balls by electrical discharges in silicon. Physical Review Letters 98, 048501] reported that an electric arc to silicon produced long-lasting luminous white spheres showing many characteristics of ball lightning. We show experimentally that these consist of burning molten silicon spheres with diameters in the 0.1-1 mm range. The evidence of our experiments leads us to propose that a subset of ball lightning events may consist of macro-scale molten spheres of burning metallic materials likely to be ejected from a conventional lightning strike to earth.

  16. Electrodepositing of Au on hollow PS micro-spheres

    International Nuclear Information System (INIS)

    Sun Jingyuan; Zhang Yunwang; Du Kai; Wan Xiaobo; Xiao Jiang; Zhang Wei; Zhang Lin; Chen Jing

    2010-01-01

    Using the self-regulating new micro-sphere electrodepositing device, the techniques of electrodepositing gold on hollow PS micro-spheres were established. The experiment was carried out under the following conditions: voltage was about 0.7 ∼ 0.8 V, current density was 2.0 mA · cm -2 , the temperature was 45 degree C, cathode rotating rate was 250 r · min -1 , flow rate of the solution was 7 mL · min -1 · cm -2 . Hollow gold-plated micro-spheres were prepared with well spherical symmetry, uniform thickness and surface smoothness under 500 nm. The speed of the gold depositing was 6 μm · h -1 . (authors)

  17. Topologically Directed Assemblies of Semiconducting Sphere-Rod Conjugates.

    Science.gov (United States)

    Lin, Zhiwei; Yang, Xing; Xu, Hui; Sakurai, Tsuneaki; Matsuda, Wakana; Seki, Shu; Zhou, Yangbin; Sun, Jian; Wu, Kuan-Yi; Yan, Xiao-Yun; Zhang, Ruimeng; Huang, Mingjun; Mao, Jialin; Wesdemiotis, Chrys; Aida, Takuzo; Zhang, Wei; Cheng, Stephen Z D

    2017-12-27

    Spontaneous organizations of designed elements with explicit shape and symmetry are essential for developing useful structures and materials. We report the topologically directed assemblies of four categories (a total of 24) of sphere-rod conjugates, composed of a sphere-like fullerene (C 60 ) derivative and a rod-like oligofluorene(s) (OF), both of which are promising organic semiconductor materials. Although the packing of either spheres or rods has been well-studied, conjugates having both shapes substantially enrich resultant assembled structures. Mandated by their shapes and topologies, directed assemblies of these conjugates result not only in diverse unconventional semiconducting supramolecular lattices with controlled domain sizes but also in tunable charge transport properties of the resulting structures. These results demonstrate the importance of persistent molecular topology on hierarchically assembled structures and their final properties.

  18. SPHERES: a platform for formation-flight research

    Science.gov (United States)

    Saenz-Otero, Alvar; Miller, David W.

    2005-08-01

    New space missions, such as the Terrestrial Planet Finder (TPF) and Darwin programs, call for the use of spacecraft which maintain precise formation to achieve the effective aperture of a much larger spacecraft. Achieving this requires the development of several new space technologies. The SPHERES program was specifically designed to develop a wide range of algorithms in support of formation flight systems. Specifically, SPHERES allows the incremental development of metrology, control, autonomy, artificial intelligence, and communications algorithms. To achieve this, SPHERES exhibits a wide array of features to 1) facilitate the iterative research process, 2) support experiments, 3) support multiple scientists, and 4) enable reconfiguration and modularity. The effectiveness of these aspects of the facility have been demonstrated by several programs including development of system identification routines, coarse formation flight control algorithms, and demonstration of tethered systems.

  19. Spontaneous orbiting of two spheres levitated in a vibrated liquid.

    Science.gov (United States)

    Pacheco-Martinez, H A; Liao, L; Hill, R J A; Swift, Michael R; Bowley, R M

    2013-04-12

    In the absence of gravity, particles can form a suspension in a liquid irrespective of the difference in density between the solid and the liquid. If such a suspension is subjected to vibration, there is relative motion between the particles and the fluid which can lead to self-organization and pattern formation. Here, we describe experiments carried out to investigate the behavior of two identical spheres suspended magnetically in a fluid, mimicking weightless conditions. Under vibration, the spheres mutually attract and, for sufficiently large vibration amplitudes, the spheres are observed to spontaneously orbit each other. The collapse of the experimental data onto a single curve indicates that the instability occurs at a critical value of the streaming Reynolds number. Simulations reproduce the observed behavior qualitatively and quantitatively, and are used to identify the features of the flow that are responsible for this instability.

  20. 5D SYM on 3D deformed spheres

    Directory of Open Access Journals (Sweden)

    Teruhiko Kawano

    2015-09-01

    Full Text Available We reconsider the relation of superconformal indices of superconformal field theories of class S with five-dimensional N=2 supersymmetric Yang–Mills theory compactified on the product space of a round three-sphere and a Riemann surface. We formulate the five-dimensional theory in supersymmetric backgrounds preserving N=2 and N=1 supersymmetries and discuss a subtle point in the previous paper concerned with the partial twisting on the Riemann surface. We further compute the partition function by localization of the five-dimensional theory on a squashed three-sphere in N=2 and N=1 supersymmetric backgrounds and on an ellipsoid three-sphere in an N=1 supersymmetric background.

  1. Hyperuniformity of self-assembled soft colloidal spheres

    Science.gov (United States)

    Bretz, Coline

    2015-03-01

    Hyperuniformity characterizes a state of matter for which density fluctuations vanish on large scales. Hyperuniform materials are of technological importance as they exhibit interesting photonic properties. We have shown that such materials can be obtained by assembling spheres into a disordered jammed 2D- packing. To this end, we use a binary mixture of large and small Poly(NIPAM) particles confined between two cover slips. These soft spheres have been chosen for their temperature-sensitive properties. We can locally increase or decrease the volume fraction occupied by the spheres by finely tuning the temperature. By applying various temperature patterns, we are studying the spatial arrangements of the microgels and characterizing their hyperuniform properties through reconstruction and detection algorithms. CNRS-Rhodia-UPenn UMI 3254, Bristol, PA 19007-3624, USA

  2. VMware vSphere 5 Administration Instant Reference

    CERN Document Server

    Kusek, Christopher; Daniel, Andy

    2011-01-01

    Compact and portable reference guide for quick answers to VMware vSphere If you're looking to migrate to the newest version of VMware vSphere, this concise guide will get you up to speed and down to business in no time. If you're new to VMware vSphere, this book is for you too! The compact size of this quick reference makes it easy for you to have by your side—whether you're in the field, server room, or at your desk. Helpful elements for finding information such as thumb tabs, tables of contents with page numbers at the beginning of each chapter, and special headers puts what you need a

  3. Extraction of neutron spectral information from Bonner-Sphere data

    CERN Document Server

    Haney, J H; Zaidins, C S

    1999-01-01

    We have extended a least-squares method of extracting neutron spectral information from Bonner-Sphere data which was previously developed by Zaidins et al. (Med. Phys. 5 (1978) 42). A pulse-height analysis with background stripping is employed which provided a more accurate count rate for each sphere. Newer response curves by Mares and Schraube (Nucl. Instr. and Meth. A 366 (1994) 461) were included for the moderating spheres and the bare detector which comprise the Bonner spectrometer system. Finally, the neutron energy spectrum of interest was divided using the philosophy of fuzzy logic into three trapezoidal regimes corresponding to slow, moderate, and fast neutrons. Spectral data was taken using a PuBe source in two different environments and the analyzed data is presented for these cases as slow, moderate, and fast neutron fluences. (author)

  4. Steady flow in a rotating sphere with strong precession

    Science.gov (United States)

    Kida, Shigeo

    2018-04-01

    The steady flow in a rotating sphere is investigated by asymptotic analysis in the limit of strong precession. The whole spherical body is divided into three regions in terms of the flow characteristics: the critical band, which is the close vicinity surrounding the great circle perpendicular to the precession axis, the boundary layer, which is attached to the whole sphere surface and the inviscid region that occupies the majority of the sphere. The analytic expressions, in the leading order of the asymptotic expansion, of the velocity field are obtained in the former two, whereas partial differential equations for the velocity field are derived in the latter, which are solved numerically. This steady flow structure is confirmed by the corresponding direct numerical simulation.

  5. Synthesis, Coordination Chemistry, and Cooperative Activation of H2 with Ruthenium Complexes of ProtonResponsive METAMORPhos Ligands

    NARCIS (Netherlands)

    Terrade, F.G.; Lutz, M.; van der Vlugt, J.I.; Reek, J.N.H.

    2014-01-01

    The synthetic scope of proton-responsive sulfonamidophosphorus (METAMORPhos) ligands is expanded and design principles for the selective formation of particular tautomers, ion pairs, or double condensation products are elucidated. These systems have been introduced in the coordination sphere of Ru

  6. Symmetry in Sphere-Based Assembly Configuration Spaces

    Directory of Open Access Journals (Sweden)

    Meera Sitharam

    2016-01-01

    Full Text Available Many remarkably robust, rapid and spontaneous self-assembly phenomena occurring in nature can be modeled geometrically, starting from a collection of rigid bunches of spheres. This paper highlights the role of symmetry in sphere-based assembly processes. Since spheres within bunches could be identical and bunches could be identical, as well, the underlying symmetry groups could be of large order that grows with the number of participating spheres and bunches. Thus, understanding symmetries and associated isomorphism classes of microstates that correspond to various types of macrostates can significantly increase efficiency and accuracy, i.e., reduce the notorious complexity of computing entropy and free energy, as well as paths and kinetics, in high dimensional configuration spaces. In addition, a precise understanding of symmetries is crucial for giving provable guarantees of algorithmic accuracy and efficiency, as well as accuracy vs. efficiency trade-offs in such computations. In particular, this may aid in predicting crucial assembly-driving interactions. This is a primarily expository paper that develops a novel, original framework for dealing with symmetries in configuration spaces of assembling spheres, with the following goals. (1 We give new, formal definitions of various concepts relevant to the sphere-based assembly setting that occur in previous work and, in turn, formal definitions of their relevant symmetry groups leading to the main theorem concerning their symmetries. These previously-developed concepts include, for example: (i assembly configuration spaces; (ii stratification of assembly configuration space into configurational regions defined by active constraint graphs; (iii paths through the configurational regions; and (iv coarse assembly pathways. (2 We then demonstrate the new symmetry concepts to compute the sizes and numbers of orbits in two example settings appearing in previous work. (3 Finally, we give formal

  7. Complex cobordism and stable homotopy groups of spheres

    CERN Document Server

    Ravenel, Douglas C

    2003-01-01

    Since the publication of its first edition, this book has served as one of the few available on the classical Adams spectral sequence, and is the best account on the Adams-Novikov spectral sequence. This new edition has been updated in many places, especially the final chapter, which has been completely rewritten with an eye toward future research in the field. It remains the definitive reference on the stable homotopy groups of spheres. The first three chapters introduce the homotopy groups of spheres and take the reader from the classical results in the field though the computational aspects

  8. Temperature-dependent and optimized thermal emission by spheres

    Science.gov (United States)

    Nguyen, K. L.; Merchiers, O.; Chapuis, P.-O.

    2018-03-01

    We investigate the temperature and size dependencies of thermal emission by homogeneous spheres as a function of their dielectric properties. Different power laws obtained in this work show that the emitted power can depart strongly from the usual fourth power of temperature given by Planck's law and from the square or the cube of the radius. We also show how to optimize the thermal emission by selecting permittivities leading to resonances, which allow for the so-called super-Planckian regime. These results will be useful as spheres, i.e. the simplest finite objects, are often considered as building blocks of more complex objects.

  9. Thermal and mechanical stresses in a functionally graded thick sphere

    International Nuclear Information System (INIS)

    Eslami, M.R.; Babaei, M.H.; Poultangari, R.

    2005-01-01

    In this paper, a general solution for the one-dimensional steady-state thermal and mechanical stresses in a hollow thick sphere made of functionally graded material is presented. The temperature distribution is assumed to be a function of radius, with general thermal and mechanical boundary conditions on the inside and outside surfaces of the sphere. The material properties, except Poisson's ratio, are assumed to vary along the radius r according to a power law function. The analytical solution of the heat conduction equation and the Navier equation lead to the temperature profile, radial displacement, radial stress, and hoop stress as a function of radial direction

  10. Animating Impacting Spheres with the Elastic Leidenfrost Effect

    Science.gov (United States)

    Waitukaitis, Scott; Souslov, Anton; van Hecke, Martin

    2016-11-01

    Liquid droplets impacting on hot surfaces above the Leidenfrost temperature can squeeze out the vapor layer and enter the contact boiling regime. What happens to soft but vaporizable solids, such as hydrogel spheres, under such conditions? I will show how this combination leads to sustained bouncing dynamics. The key physics is the coupling between the sphere's elastic deformations and vaporization. Beyond being a new facet of the Leidenfrost effect, this phenomenon promises to be useful in fields such as fluid dynamics, microfluidics, and active matter. NWO Veni and Vici Programs.

  11. Quantum black holes: the event horizon as a fuzzy sphere

    International Nuclear Information System (INIS)

    Dolan, Brian P.

    2005-01-01

    Modeling the event horizon of a black hole by a fuzzy sphere leads us to modify some suggestions in the literature concerning black hole mass spectra. We derive a formula for the mass spectrum of quantum black holes in terms of four integers which define the area, angular momentum, electric and magnetic charge of the black hole. Although the event horizon becomes a commutative sphere in the classical limit a vestige of the quantum theory still persists in that the event horizon stereographically projects onto the non-commutative plane. We also suggest how the classical bounds on extremal black holes might be modified in the quantum theory. (author)

  12. Diversity and the European Public Sphere. The Case of Denmark

    DEFF Research Database (Denmark)

    Pristed Nielsen, Helene; Siim, Birte; Agustin, Lise Rolandsen

    2010-01-01

    This report contains empirical findings from the Danish case within the Eurosphere project. It is based on 55 interviews with Danish opinion makers on the topics of diversity, EU polity and the European public sphere The empirical research programme of EUROSPHERE aims to explore whether it is pos......This report contains empirical findings from the Danish case within the Eurosphere project. It is based on 55 interviews with Danish opinion makers on the topics of diversity, EU polity and the European public sphere The empirical research programme of EUROSPHERE aims to explore whether......, and is primarily based on expert interviews with 55 opinion makers within Denmark....

  13. Photonic Bandgaps in Mie Scattering by Concentrically Stratified Spheres

    Science.gov (United States)

    Smith, David D.; Fuller, Kirk A.; Curreri, Peter A.

    2002-01-01

    The Mie formulation for homogeneous spheres is generalized to handle core/shell systems and multiple concentric layers in a manner that exploits an analogy with stratified planar systems, thereby allowing concentric multi-layered structures to be treated as photonic bandgap materials. Representative results from a Mie code employing this analogy demonstrate that photonic bands are present for periodic concentric spheres, though not readily apparent in extinction spectra. Rather, the periodicity simply alters the scattering profile, enhancing the ratio of backscattering to forward scattering inside the bandgap, whereas modification of the interference structure is evident in extinction spectra in accordance with the optical theorem

  14. Smith-Purcell radiation from a chain of spheres

    International Nuclear Information System (INIS)

    Lekomtsev, K V; Strikhanov, M N; Tishchenko, A A

    2010-01-01

    Smith-Purcell and diffraction radiation were investigated. These types of radiation appear when a charged particle moves close to a conducting target. Spectral and angular distribution of diffraction radiation from the non-periodic chain of spheres is obtained analytically; local field effects are discussed. Analytical expression for the distribution of Smith-Purcell radiation from the periodic chain of spheres is obtained as well. For the first time it has been shown, that Smith-Purcell radiation for such a system is distributed over the cone. The results are investigated for the particles of different sizes, dielectric and metal, and for both ultrarelativistic and nonrelativistic cases.

  15. Pulsed sphere measurements for weapons and fusion reactor design

    International Nuclear Information System (INIS)

    Anon.

    1978-01-01

    Pulsed sphere measurements provide a way of validating the Monte Carlo transport codes and the input cross sections used in the design of thermonuclear weapons and fusion reactors. In these measurements pulsed 14-MeV neutrons are generated at the center of spheres of materials to be investigated, and the emitted neutron spectrum is measured by time-of-flight techniques. The measurements described in this article cannot reproduce the complex conditions found in weapons and fusion reactors. However, agreement between measurement and calculations for a simple geometry and one material (or simple composites) is a necessary prerequisite to reliable fusion reactor calculations

  16. Political Intersectionality and Democratic Politics in the European Public Sphere

    DEFF Research Database (Denmark)

    Siim, Birte

    2015-01-01

    Public Sphere (EPS). It is inspired by results and reflections from the European Gender Project (EGP) , where intersectionality was used as an approach for analysing negotiations between gender and ethno-national diversity in selected European countries and in relation to the European Public Sphere...... intersections of gender and ethnic diversity in political life at the national and transnational levels across Europe. In this context, political intersectionality refers to the framing of gender and ethnic diversity by major political actors as well as by activities of women’s and anti-racist organisations...

  17. On the sedimentation velocity of spheres in a polymeric liquid

    DEFF Research Database (Denmark)

    Rasmussen, Henrik Koblitz; Hassager, Ole

    1996-01-01

    A Lagrangian finite element method is used to simulate the transient sedimentation of spheres in polymeric liquids. The liquid is described by an integral constitutive equation of the Rivlin-Sawyers type. The simulations show a marked increase in the drag, which is apparently related to the elong......A Lagrangian finite element method is used to simulate the transient sedimentation of spheres in polymeric liquids. The liquid is described by an integral constitutive equation of the Rivlin-Sawyers type. The simulations show a marked increase in the drag, which is apparently related...

  18. VMware vSphere 5.1 cookbook

    CERN Document Server

    GB, Abhilash

    2013-01-01

    A fast-paced, task-oriented Cookbook covering recipes on the installation and configuration of vSphere 5.1 components. The recipes are accompanied with relevant screenshots with an intention to provide a visual guidance as well. The book concentrates more on the actual task rather than the theory around it, making it easier to understand what is really needed to achieve the task.This book is a guide for anyone who wants to learn how to install and configure VMware vSphere components. This is an excellent handbook for support professionals or for anyone intending to give themselves a head start

  19. Coordination chemistry of technetium

    International Nuclear Information System (INIS)

    Together with development of chemistry of radiopharmaceuticals, coordination chemistry of technetium has recently progressed. The synthetic procedures of technetium complexes have also been established in a various oxidation states. Especially, technetium(V) complexes which possess a Tc=0 or 0=Tc = 0 core are interested from a view point kinetic stability. In the present paper, substitution reaction mechanisms of Tc(V), Tc(IV) and Tc(III) complexes coordinated with a β-diketone as ligand are discussed in connection with the structural chemistry of technetium complexes. The base hydrolysis of halobis(β-diketonato)oxotechnetium(V) and dihalobis (β-diketonato)technetium(IV) complexes liberate halide ion by the attack of hydroxide ion, followed by the liberation of β-diketones. Technetium is found to be pertechnetate as a final product

  20. Coordinating Work with Groupware

    DEFF Research Database (Denmark)

    Pors, Jens Kaaber; Simonsen, Jesper

    2003-01-01

    One important goal of employing groupware is to make possible complex collaboration between geographically distributed groups. This requires a dual transformation of both technology and work practice. The challenge is to re­duce the complexity of the coordination work by successfully inte......­grating the protocol stipulating the collaboration and the ar­te­fact, in form of the groupware application, mediating the col­laboration. This paper analyses a generic groupware application that was deployed in a large financial organisation in order to support working groups distributed throughout four countries....... Using the CSCW frame­work of coordination mechanisms, we have elicited six general factors influencing the integration of the groupware application in two situations....

  1. On the impossibility of defining adhesive hard spheres as sticky limit of a hard-sphere-Yukawa potential.

    Science.gov (United States)

    Gazzillo, Domenico

    2011-03-28

    For fluids of molecules with short-ranged hard-sphere-Yukawa (HSY) interactions, it is proven that the Noro-Frenkel "extended law of corresponding states" cannot be applied down to the vanishing attraction range, since the exact HSY second virial coefficient diverges in such a limit. It is also shown that, besides Baxter's original approach, a fully correct alternative definition of "adhesive hard spheres" can be obtained by taking the vanishing-range-limit (sticky limit) not of a Yukawa tail, as is commonly done, but of a slightly different potential with a logarithmic-Yukawa attraction.

  2. Improving Project Manufacturing Coordination

    Directory of Open Access Journals (Sweden)

    Korpivaara Ville

    2014-09-01

    Full Text Available The objective of this research is to develop firms’ project manufacturing coordination. The development will be made by centralizing the manufacturing information flows in one system. To be able to centralize information, a deep user need assessment is required. After user needs have been identified, the existing system will be developed to match these needs. The theoretical background is achieved through exploring the literature of project manufacturing, development project success factors and different frameworks and tools for development project execution. The focus of this research is rather in customer need assessment than in system’s technical expertise. To ensure the deep understanding of customer needs this study is executed by action research method. As a result of this research the information system for project manufacturing coordination was developed to respond revealed needs of the stakeholders. The new system improves the quality of the manufacturing information, eliminates waste in manufacturing coordination processes and offers a better visibility to the project manufacturing. Hence it provides a solid base for the further development of project manufacturing.

  3. Universal mechatronics coordinator

    Science.gov (United States)

    Muir, Patrick F.

    1999-11-01

    Mechatronic systems incorporate multiple actuators and sensor which must be properly coordinated to achieve the desired system functionality. Many mechatronic systems are designed as one-of-a-kind custom projects without consideration for facilitating future system or alterations and extensions to the current syste. Thus, subsequent changes to the system are slow, different, and costly. It has become apparent that manufacturing processes, and thus the mechatronics which embody them, need to be agile in order to more quickly and easily respond to changing customer demands or market pressures. To achieve agility, both the hardware and software of the system need to be designed such that the creation of new system and the alteration and extension of current system is fast and easy. This paper describes the design of a Universal Mechatronics Coordinator (UMC) which facilitates agile setup and changeover of coordination software for mechatronic systems. The UMC is capable of sequencing continuous and discrete actions that are programmed as stimulus-response pairs, as state machines, or a combination of the two. It facilitates the modular, reusable programing of continuous actions such as servo control algorithms, data collection code, and safety checking routines; and discrete actions such as reporting achieved states, and turning on/off binary devices. The UMC has been applied to the control of a z- theta assembly robot for the Minifactory project and is applicable to a spectrum of widely differing mechatronic systems.

  4. Coordinating Shared Activities

    Science.gov (United States)

    Clement, Bradley

    2004-01-01

    Shared Activity Coordination (ShAC) is a computer program for planning and scheduling the activities of an autonomous team of interacting spacecraft and exploratory robots. ShAC could also be adapted to such terrestrial uses as helping multiple factory managers work toward competing goals while sharing such common resources as floor space, raw materials, and transports. ShAC iteratively invokes the Continuous Activity Scheduling Planning Execution and Replanning (CASPER) program to replan and propagate changes to other planning programs in an effort to resolve conflicts. A domain-expert specifies which activities and parameters thereof are shared and reports the expected conditions and effects of these activities on the environment. By specifying these conditions and effects differently for each planning program, the domain-expert subprogram defines roles that each spacecraft plays in a coordinated activity. The domain-expert subprogram also specifies which planning program has scheduling control over each shared activity. ShAC enables sharing of information, consensus over the scheduling of collaborative activities, and distributed conflict resolution. As the other planning programs incorporate new goals and alter their schedules in the changing environment, ShAC continually coordinates to respond to unexpected events.

  5. Global coordination: weighted voting

    Directory of Open Access Journals (Sweden)

    Jan-Erik Lane

    2014-03-01

    Full Text Available In order to halt the depletion of global ecological capital, a number of different kinds of meetings between Governments of countries in the world has been scheduled. The need for global coordination of environmental policies has become ever more obvious, supported by more and more evidence of the running down of ecological capital. But there are no formal or binding arrangements in sight, as global environmental coordination suffers from high transaction costs (qualitative voting. The CO2 equivalent emissions, resulting in global warming, are driven by the unstoppable economic expansion in the global market economy, employing mainly fossil fuel generated energy, although at the same time lifting sharply the GDP per capita of several emerging countries. Only global environmental coordination on the successful model of the World Band and the IMF (quantitative voting can stem the rising emissions numbers and stop further environmental degradation. However, the system of weighted voting in the WB and the IMF must be reformed by reducing the excessive voting power disparities, for instance by reducing all member country votes by the cube root expression.

  6. Radio making waves in the italian diaspora: Public sphere ...

    African Journals Online (AJOL)

    The deterritorialised publics of diaspora are conceptually quite different from the homogenous nationally bound public originally conceived to participate in Habermas' public sphere. However, with globalisation and parallel advances in media technologies the qualities of diasporic communication increasingly come to ...

  7. Determination of corrosion potential of coated hollow spheres

    International Nuclear Information System (INIS)

    Fedorkova, Andrea; Orinakova, Renata; Orinak, Andrej; Dudrova, Eva; Kupkova, Miriam; Kalavsky, Frantisek

    2008-01-01

    Copper hollow spheres were created on porous iron particles by electro-less deposition. The consequent Ni plating was applied to improve the mechanical properties of copper hollow micro-particles. Corrosion properties of coated hollow spheres were investigated using potentiodynamic polarisation method in 1 mol dm -3 NaCl solution. Surface morphology and composition were studied by scanning electron microscopy (SEM), light microscopy (LM) and energy-dispersive X-ray spectroscopy (EDX). Original iron particles, uncoated copper spheres and iron particles coated with nickel were studied as the reference materials. The effect of particle composition, particularly Ni content on the corrosion potential value was investigated. The results indicated that an increase in the amount of Ni coating layer deteriorated corrosion resistivity of coated copper spheres. Amount of Ni coating layer depended on conditions of Ni electrolysis, mainly on electrolysis time and current intensity. Corrosion behaviour of sintered particles was also explored by potentiodynamic polarisation experiments for the sake of comparison. Formation of iron rich micro-volumes on the particle surface during sintering caused the corrosion potential shift towards more negative values. A detailed study of the morphological changes between non-sintered and sintered micro-particles provided explanation of differences in corrosion potential (E corr )

  8. Characterization of silane coated hollow sphere alumina-reinforced

    Indian Academy of Sciences (India)

    Silane coated hollow sphere alumina ceramic particles were moulded with ultra high molecular weight polyethylene (UHMWPE) to form a series of composites with alumina weight percent in the range from 15 to 50. The composites were prepared in a cylindrical mould using powder-processing technique. The composites ...

  9. Superconducting Sphere in an External Magnetic Field Revisited

    Science.gov (United States)

    Sazonov, Sergey N.

    2013-01-01

    The purpose of this article is to give the intelligible procedure for undergraduate students to grasp proof of the fact that the magnetic field outside the hollow superconducting sphere (superconducting shell) coincides with the field of a point magnetic dipole both when an uniform external magnetic field is applied as when a ferromagnetic sphere…

  10. Passive control of a sphere by complex-shaped appendages

    Science.gov (United States)

    Bagheri, Shervin; Lacis, Ugis; Olivieri, Stefano; Mazzino, Andrea

    2015-11-01

    Appendages of various shapes and sizes (e.g. plumes, barbs, tails, feathers, hairs, fins) play an important role in dispersion and locomotion. In our previous work (Lacis, U. et al. Passive appendages generate drift through symmetry breaking. Nat. Commun. 5:5310, doi: 10.1038/ncomms6310, 2014), we showed that a free-falling cylinder with a splitter plate turns and drifts due to a symmetry-breaking instability (called inverted-pendulum instability or IPL). In other words, in a separated flow, the straight position of a short splitter plate is unstable and as a consequence a side force and a torque are induced on the cylinder. In this work, we seek the three-dimensional (3D) appendage shape (on a sphere at Re =200) that induces the largest drift of the sphere. We find that highly non-trivial shapes of appendages on a sphere increase the side force significantly compared to trivial shapes (such as an elliptic sheet). We also find that appendages may be designed to generate drift in either direction, that is, a free-falling sphere can drift either in the direction in which appendage is tilted or in the opposite direction depending on the particular geometry of the appendage. We discuss the physical mechanisms behind these optimal appendage shapes in the context of the IPL instability.

  11. Holomorphic two-spheres in complex Grassmann manifold

    Indian Academy of Sciences (India)

    Home; Journals; Proceedings – Mathematical Sciences; Volume 118; Issue 3. Holomorphic Two-Spheres in Complex Grassmann Manifold (2, 4). Xiaowei Xu ... Author Affiliations. Xiaowei Xu1 Xiaoxiang Jiao1. School of Mathematical Sciences, Graduate University of Chinese Academy of Sciences, Beijing 100049, China ...

  12. Two-body quantum mechanical problem on spheres

    OpenAIRE

    Shchepetilov, Alexey V.

    2005-01-01

    The quantum mechanical two-body problem with a central interaction on the sphere ${\\bf S}^{n}$ is considered. Using recent results in representation theory an ordinary differential equation for some energy levels is found. For several interactive potentials these energy levels are calculated in explicit form.

  13. Geometrical frustration: A study of four-dimensional hard spheres

    NARCIS (Netherlands)

    van Meel, J.A.; Frenkel, D.; Charbonneau, P.

    2009-01-01

    The smallest maximum-kissing-number Voronoi polyhedron of three-dimensional (3D) Euclidean spheres is the icosahedron, and the tetrahedron is the smallest volume that can show up in Delaunay tessellation. No periodic lattice is consistent with either, and hence these dense packings are geometrically

  14. Error analysis of the track fit on the Riemann sphere

    CERN Document Server

    Strandlie, A

    2002-01-01

    We present in this paper a derivation of the covariance matrix of the estimated track parameters given by the Riemann sphere track fitting method. Results of a simulation experiment from the ATLAS Transition Radiation Tracker show that the covariance matrix presented herein very well reflects the actual spread of the track parameters. (6 refs).

  15. Characterization of silane coated hollow sphere alumina-reinforced ...

    Indian Academy of Sciences (India)

    Silane coated hollow sphere alumina ceramic particles were moulded with ultra high molecular weight polyethylene (UHMWPE) to form a series of composites with alumina weight percent in the range from 15 to 50. The composites were prepared in a cylindrical mould using powder-processing technique. The composites ...

  16. Violence against Brazilian Women in Public and Mediatic Spheres

    Science.gov (United States)

    Souza-Leal, Bruno; de-Carvalho, Carlos-Alberto; Antunes, Elton

    2018-01-01

    This paper explores the capacity of the media to incorporate controversies in circulation in the public sphere. For that, it is based on the analysis of a set of 607 news stories about violence against women in context of gender relations and proximity, collected in nine Brazilian media during the years of 2013 and 2014. Recognized as one of the…

  17. Do European elections create a European public sphere?

    NARCIS (Netherlands)

    Boomgaarden, H.G.; de Vreese, C.H.; van der Brug, W.; de Vreese, C.H.

    2016-01-01

    This chapter answers the question whether the news coverage of European Parliament (EP) elections across time has helped create a European public sphere. The focus is on the salience of European Union affairs in the mass media during EP election campaigns and on the Europeanness of such coverage,

  18. Rigidity theorem for Willmore surfaces in a sphere

    Indian Academy of Sciences (India)

    (Math. Sci.) Vol. 126, No. 2, May 2016, pp. 253–260. c Indian Academy of Sciences. Rigidity theorem for Willmore surfaces in a sphere. HONGWEI XU1 and DENGYUN YANG2,∗. 1Center of Mathematical Sciences, Zhejiang University, Hangzhou 310027,. People's Republic of China. 2College of Mathematics and ...

  19. The Polyakov relation for the sphere and higher genus surfaces

    International Nuclear Information System (INIS)

    Menotti, Pietro

    2016-01-01

    The Polyakov relation, which in the sphere topology gives the changes of the Liouville action under the variation of the position of the sources, is also related in the case of higher genus to the dependence of the action on the moduli of the surface. We write and prove such a relation for genus 1 and for all hyperelliptic surfaces. (paper)

  20. User Modeling and Personalization in the Microblogging Sphere

    NARCIS (Netherlands)

    Gao, Q.

    2013-01-01

    Microblogging has become a popular mechanism for people to publish, share, and propagate information on the Web. The massive amount of digital traces that people have left in the microblogging sphere, creates new possibilities and poses challenges for user modeling and personalization. How can

  1. The unsteady motion of a sphere in a viscoelastic fluid

    DEFF Research Database (Denmark)

    Becker, L.E.; McKinley, G. H.; Rasmussen, Henrik K.

    1994-01-01

    The motion of a sphere accelerating from rest along the center line of a cylindrical tube filled with a polyisobutylene (PIB) Boger fluid is examined both experimentally, using a digital imaging system, and numerically via a Lagrangian finite element method for single and multimode Oldroyd models...

  2. Simple liquids’ quasiuniversality and the hard-sphere paradigm

    DEFF Research Database (Denmark)

    Dyre, Jeppe C.

    2016-01-01

    This topical review discusses the quasiuniversality of simple liquids' structure and dynamics and two possible justifications of it. The traditional one is based on the van der Waals picture of liquids in which the hard-sphere system reflects the basic physics. An alternative explanation argues t...

  3. Simple liquids' quasiuniversality and the hard-sphere paradigm

    DEFF Research Database (Denmark)

    Dyre, Jeppe C.

    This presentation reflects on the well-known quasiuniversality of simple liquids’ structure and dynamics [1, 2, 3, 4, 5]. We discuss two possible justifications of it [6, 7]. The traditional one is based on the van der Waals picture of liquids in which the hard-sphere system reflects the basic ph...

  4. Mesoscale organization of CuO nanoslices: Formation of sphere

    Indian Academy of Sciences (India)

    WINTEC

    Mesoscale organization of CuO nanoslices. 195. Figure 4. Illustration of formation mechanism of the sphere. 3. Results and discussion. The structure and chemical composition of CuO sample synthesized in this work was confirmed by XRD method. As reported in figure 1, typical XRD pattern for the sam- ple is displayed.

  5. Simulating colloids with Baxter's adhesive hard sphere model

    NARCIS (Netherlands)

    Miller, M.A.; Frenkel, D.

    2004-01-01

    The structure of the Baxter adhesive hard sphere fluid is examined using computer simulation. The radial distribution function (which exhibits unusual discontinuities due to the particle adhesion) and static structure factor are calculated with high accuracy over a range of conditions and compared

  6. Everyday political talk in the internet-based public sphere

    NARCIS (Netherlands)

    Graham, Todd; Coleman, Stephen; Freelon, Deen

    Ever since the advent of the Internet, political communication scholars have debated its potential to facilitate and support public deliberation as a means of revitalizing and extending the public sphere. Much of the debate has focused on the medium’s potential in offering communicative spaces that

  7. Three-sphere swimmer in a nonlinear viscoelastic medium

    KAUST Repository

    Curtis, Mark P.

    2013-04-10

    A simple model for a swimmer consisting of three colinearly linked spheres attached by rods and oscillating out of phase to break reciprocal motion is analyzed. With a prescribed forcing of the rods acting on the three spheres, the swimming dynamics are determined analytically in both a Newtonian Stokes fluid and a zero Reynolds number, nonlinear, Oldroyd-B viscoelastic fluid with Deborah numbers of order one (or less), highlighting the effects of viscoelasticity on the net displacement of swimmer. For instance, the model predicts that the three-sphere swimmer with a sinusoidal, but nonreciprocal, forcing cycle within an Oldroyd-B representation of a polymeric Boger fluid moves a greater distance with enhanced efficiency in comparison with its motility in a Newtonian fluid of the same viscosity. Furthermore, the nonlinear contributions to the viscoelastic constitutive relation, while dynamically nontrivial, are predicted a posteriori to have no effect on swimmer motility at leading order, given a prescribed forcing between spheres. © 2013 American Physical Society.

  8. Phase diagram of the adhesive hard sphere fluid

    NARCIS (Netherlands)

    Miller, M.A.; Frenkel, D.

    2004-01-01

    The phase behavior of the Baxter adhesive hard sphere fluid has been determined using specialized Monte Carlo simulations. We give a detailed account of the techniques used and present data for the fluid–fluid coexistence curve as well as parametrized fits for the supercritical equation of state and

  9. Magnetohydraulic flow through a packed bed of electrically conducting spheres

    International Nuclear Information System (INIS)

    Sanders, T.L.

    1985-01-01

    The flow of an electrically conducting fluid through a packed bed of electrically conducting spheres in the presence of a strong magnetic field constitutes a very complex flow situation due to the constant turning of the fluid in and out of magnetic field lines. The interaction of the orthogonal components of the velocity and magnetic field will induce electric fields that are orthogonal to both and the electric fields in turn can cause currents that interact with the magnetic field to generate forces against the direction of flow. The strengths of these generated forces depend primarily upon the closure paths taken by the induced currents which, in turn, depend upon the relative ratio of the electrical resistance of the solid spheres to that of the fluid. Both experimental and analytical analyses of the slow flow of a eutectic mixture of sodium and potassium (NaK) through packed cylinders containing stainless steel spheres in the presence of a strong transverse magnetic field were completed. A theory of magnetohydraulic flow is developed by analogy with the development of hydraulic radius theories of flow through porous media. An exact regional analysis is successfully applied to an infinite bed of electrically conducting spheres with a conducting or non-conducting constraining wall on one side. The equations derived are solved for many different combinations of flowrate, magnetic field strength, porosity, and electrical resistance ratio

  10. Scattering of linearly polarized Bessel beams by dielectric spheres

    Science.gov (United States)

    Shoorian, Hamed

    2017-09-01

    The scattering of a Linearly Polarized Bessel Beam (LPBB) by an isotropic and homogenous dielectric sphere is investigated. Using analytical relation between the cylindrical and the spherical vector wave functions, all the closed- form analytical expressions, in terms of spherical wave-functions expansions, are derived for the scattered field. It is shown that in the case of conical angle of incident Bessel beam is equal to zero, the Linearly Polarized Bessel Beam becomes a plane wave and its scattering coefficients become the same as the expansion coefficients of plane wave in Mie theory. The transverse Cartesian and spherical components of the electric field, scattered by a sphere are shown in the z-plane for different cases, moreover the intensity of the incident Bessel beam and the effects of its conical angle on the scattered field and the field inside the sphere are investigated. To quantitatively study the scattering phenomenon and the variations of the fields inside and outside of the sphere, the scattering and absorption efficiencies are obtained for the scattering of the linearly-polarized Bessel beam, and are compared with those of the plane wave scattering.

  11. Consolidation of metallic hollow spheres by electric sintering

    Science.gov (United States)

    Mironov, V.; Tatarinov, A.; Lapkovsky, V.

    2017-07-01

    This paper considers peculiarities of the technology of production of structures from metallic hollow spheres (MHS) using magnetic fields and electric sintering. In these studies, the raw material was MHS obtained by burning of polystyrene balls coated by carbon steel. MHS had an outer diameter of 3-5 mm and a steel wall thickness of 70-120 microns. Pulsed current generators were used for electric sintering of MHS to obtain different spatial structures. Since MHS have small strength, the compressive pressure during sintering should be minimal. To improve the adhesion strength and reduce the required energy for sintering, hollow spheres were coated with copper by ion-plasma sputtering in vacuum. The coating thickness was 10-15 microns. The ferromagnetic properties of MHS allowed using of magnet fields for orientation of the spheres in the structures, as well as using of perforated tapes acting as orienting magnetic cores. Ultrasonic testing of MHS structures has been tried using through propagation of ultrasound in low kilohertz frequency range. Sensitivity of the propagation parameters to water filling of inter-spheres space and sintering temperature was demonstrated.

  12. Axioms of spheres in lightlike geometry of submanifolds

    Indian Academy of Sciences (India)

    In [7], Kumar et al. studied the axioms of spheres and planes for indefinite Riemannian manifolds having lightlike submanifolds. Yano and Mogi [10] generalized the concept of axioms of planes for Riemannian mani- folds to the axioms of holomorphic planes for Kaehler manifolds. The same conclusion prevails for a Kaehler ...

  13. Exact anisotropic sphere with polytropic equation of state

    Indian Academy of Sciences (India)

    self-gravitating, static, isotropic fluid spheres when pressure explicitly depends on matter density, which invariably leads to non-integrable equations [32]. However, our treatment of anisotropic fluids with polytropic equation of state gets some flexibility in solving the. Einstein field equations with uncharged matter in static ...

  14. Absorption of continuum radiation in a resonant expanding gaseous sphere

    International Nuclear Information System (INIS)

    Shaparev, N Y

    2014-01-01

    The paper deals with absorption of external continuum radiation in a self-similarly expanding gaseous sphere. Frequency probability and integral probability of radiation absorption in the resonance frequency range are determined depending on the expansion velocity gradient and thickness of the optical medium. It is shown that expansion results in a reduced optical thickness of the medium and enhanced integral absorption. (paper)

  15. Hard sphere colloidal dispersions: Mechanical relaxation pertaining to thermodynamic forces

    NARCIS (Netherlands)

    Mellema, J.; de Kruif, C.G.; Blom, C.; Vrij, A.

    1987-01-01

    The complex viscosity of sterically stabilized (hard) silica spheres in cyclohexane has been measured between 80 Hz and 170 kHz with torsion pendulums and a nickel tube resonator. The observed relaxation behaviour can be attributed to the interplay of hydrodynamic and thermodynamic forces. The

  16. The Perception of Community Radio as Public Sphere and its ...

    African Journals Online (AJOL)

    Levi Manda

    engage in public issue debates in a rational-critical fashion, then guide state actions. Thus, the public sphere ... local sports; not crime in general but crime in the community” (p. 33). The democratic decision-making ... production of content to distribution and consumption of programming, each of which accounts for its social ...

  17. Interrogating Public Sphere and Popular Culture as Theoretical ...

    African Journals Online (AJOL)

    Because of its theoretical roots in Western liberal thinking, scholars in African studies such as Comaroffs, Mamdani and Ekeh have vigorously debated the extent to which the concept of civil society is useful in explaining and interrogating developments in Africa. However, the concept of the public sphere has been subjected ...

  18. Chemical flowsheet conditions for preparing urania spheres by internal gelation

    International Nuclear Information System (INIS)

    Haas, P.A.; Begovich, J.M.; Ryon, A.D.; Vavruska, J.S.

    1979-01-01

    Small, ceramic urania spheres can be prepared for use as nuclear fuel by internal chemical gelation of uranyl nitrate solution droplets. Decomposition of hexamethylenetetramine (HMTA) dissolved in the uranyl nitrate solution releases ammonia to precipitate hydrated UO 3 . Previously established flowsheet conditions have been improved and modified at ORNL and have been applied to prepare dense UO 2 spheres with average diameters of 1200, 300, and 30 μm. Acid-deficient uranyl nitrate (ADUN) solutions up to 3.4 M in uranium with NO 3 - /U mole ratios of 1.5 to 1.7 are prepared by dissolution of U 3 O 8 or UO 3 . Continuous mixing of metered, cooled ADUN containing urea and HMTA solutions provides a smooth, regulated flow of the temperature-sensitive feed solution. The gelation times for solution drops in organic liquids at 45 to 95 0 C depend on both the chemical reaction rates and the rates of heat transfer. The gel properties vary with temperature and other gelation variables. Gelation conditions were determined which allow easy washing, drying, firing, and sintering to produce dense UO 2 spheres of all three sizes. The 1200- and 300-μm UO 2 spheres were pepared by gelation in trichloroethylene at 50 to 65 0 C; 2-ethyl-l-hexanol was used as the gelation medium to prepare 30-μm UO 2 spheres. Washing and drying requirements were determined. The gel dried to 225 0 C contains about 95% UO 3 ; the remaining components are H 2 O, NH 3 - , which are volatilized during firing to UO 2

  19. Symmetric two-coordinate photodiode

    Directory of Open Access Journals (Sweden)

    Dobrovolskiy Yu. G.

    2008-12-01

    Full Text Available The two-coordinate photodiode is developed and explored on the longitudinal photoeffect, which allows to get the coordinate descriptions symmetric on the steepness and longitudinal resistance great exactness. It was shown, that the best type of the coordinate description is observed in the case of scanning by the optical probe on the central part of the photosensitive element. The ways of improvement of steepness and linear of its coordinate description were analyzed.

  20. Reconstruction of Colloidal Spheres by Targeted Etching: A Generalized Self-Template Route to Porous Amphoteric Metal Oxide Hollow Spheres.

    Science.gov (United States)

    Pan, Jia Hong; Bai, Yuqing; Wang, Qing

    2015-04-21

    Despite the significant progress in developing various synthetic strategies for metal oxide hollow spheres (h-MO), the so-far explored materials are mostly chemically inert metal oxides. Very few attempts have been made for amphoteric metal oxides such as Al2O3 and ZnO due to the difficulties in the control of the dissolution and recrystallization process. Herein, a facile self-template route to the synthesis of amphoteric h-MO with tunable size and shell thickness is developed by targeted etching via an acid-base reaction. With the protection of polyvinylpyrrolidone (PVP) on the surface, the interior of metal oxide solid colloidal spheres (c-MOs) that possess radially divergent structures could be selectively etched with acid/alkali as an etchant, forming h-MO of Al2O3 and ZnO. Our results also show that a wide variety of metal oxide colloidal spheres can be potential self-templates for targeted etching, which paves the way for developing a generalized strategy for the synthesis of various metal oxide hollow spheres.

  1. Metal-coordinating substrate analogs as inhibitors of metalloenzymes.

    Science.gov (United States)

    Holmquist, B; Vallee, B L

    1979-01-01

    A group of active-site metal coordinating inhibitors of zinc proteases (carboxypeptidase A, thermolysin, Bacillus cereus neutral protease, and angiotensin-converting enzyme) have been synthesized and their properties investigated. Their general structures are R-SH and R-NH-PO2(O phi)H, where-S- or -O- serve as metal ligands and R refers to an amino acid or peptide group designed to interact with substrate recognition sites. These inhibitors can be extremely potent; thus, N-(2-mercaptoacetyl)-D-phenylalanine, e.g., inhibits carboxypeptidase A with a Kiapp of 2.2 x 10(-7) M. The spectral response of cobalt(II)-substituted thermolysin or carboxypeptidase A to the sulfur-containing inhibitors signals the direct interaction of the mercaptan with the metal. An S leads to Co(II) charge transfer band is generated near 340 nm and is detected by absorption, circular dichroism, and magnetic circular dichroism. The cobalt(II) spectra indicate both inner sphere coordination with sulfur and 4-coordination in the enzyme-inhibitor complex. Thus, the metal undergoes a simple substitution reaction, the inhibitor most likely displacing water at the fourth coordination site. PMID:230502

  2. Work Coordination Engine

    Science.gov (United States)

    Zendejas, Silvino; Bui, Tung; Bui, Bach; Malhotra, Shantanu; Chen, Fannie; Kim, Rachel; Allen, Christopher; Luong, Ivy; Chang, George; Sadaqathulla, Syed

    2009-01-01

    The Work Coordination Engine (WCE) is a Java application integrated into the Service Management Database (SMDB), which coordinates the dispatching and monitoring of a work order system. WCE de-queues work orders from SMDB and orchestrates the dispatching of work to a registered set of software worker applications distributed over a set of local, or remote, heterogeneous computing systems. WCE monitors the execution of work orders once dispatched, and accepts the results of the work order by storing to the SMDB persistent store. The software leverages the use of a relational database, Java Messaging System (JMS), and Web Services using Simple Object Access Protocol (SOAP) technologies to implement an efficient work-order dispatching mechanism capable of coordinating the work of multiple computer servers on various platforms working concurrently on different, or similar, types of data or algorithmic processing. Existing (legacy) applications can be wrapped with a proxy object so that no changes to the application are needed to make them available for integration into the work order system as "workers." WCE automatically reschedules work orders that fail to be executed by one server to a different server if available. From initiation to completion, the system manages the execution state of work orders and workers via a well-defined set of events, states, and actions. It allows for configurable work-order execution timeouts by work-order type. This innovation eliminates a current processing bottleneck by providing a highly scalable, distributed work-order system used to quickly generate products needed by the Deep Space Network (DSN) to support space flight operations. WCE is driven by asynchronous messages delivered via JMS indicating the availability of new work or workers. It runs completely unattended in support of the lights-out operations concept in the DSN.

  3. Spin state switching in iron coordination compounds

    Directory of Open Access Journals (Sweden)

    Philipp Gütlich

    2013-02-01

    Full Text Available The article deals with coordination compounds of iron(II that may exhibit thermally induced spin transition, known as spin crossover, depending on the nature of the coordinating ligand sphere. Spin transition in such compounds also occurs under pressure and irradiation with light. The spin states involved have different magnetic and optical properties suitable for their detection and characterization. Spin crossover compounds, though known for more than eight decades, have become most attractive in recent years and are extensively studied by chemists and physicists. The switching properties make such materials potential candidates for practical applications in thermal and pressure sensors as well as optical devices.The article begins with a brief description of the principle of molecular spin state switching using simple concepts of ligand field theory. Conditions to be fulfilled in order to observe spin crossover will be explained and general remarks regarding the chemical nature that is important for the occurrence of spin crossover will be made. A subsequent section describes the molecular consequences of spin crossover and the variety of physical techniques usually applied for their characterization. The effects of light irradiation (LIESST and application of pressure are subjects of two separate sections. The major part of this account concentrates on selected spin crossover compounds of iron(II, with particular emphasis on the chemical and physical influences on the spin crossover behavior. The vast variety of compounds exhibiting this fascinating switching phenomenon encompasses mono-, oligo- and polynuclear iron(II complexes and cages, polymeric 1D, 2D and 3D systems, nanomaterials, and polyfunctional materials that combine spin crossover with another physical or chemical property.

  4. One-pot synthesis of uniform hollow cuprous oxide spheres fabricated by single-crystalline particles via a simple solvothermal route

    International Nuclear Information System (INIS)

    Li Shikuo; Li Chuanhao; Huang Fangzhi; Wang Yang; Shen Yuhua; Xie Anjian; Wu Qiong

    2011-01-01

    Uniform Cu 2 O hollow spheres fabricated by single-crystalline particles (smaller than 20 nm) are facile synthesized in ethylene glycol (EG) solution by a simple solvothermal route without using pre-fabricated templates and reductive agents. EG in this protocol is not only used as a solvent, complexing agent, and reducing agent, but also served as a structure-directing agent for the formation of hollow structure. By control of reaction conditions, such as reaction time, temperature, and the anions, the morphology and structure of the hollow spheres can be tuned. A coordination adsorption and oriented attachment and Ostwald ripening mechanism is proposed for explaining the formation process of hollow Cu 2 O spheres in EG solution; and importantly, the hollow Cu 2 O spheres exhibit an excellent property for the electro-catalytic oxidization of ascorbic acid in acetic acid buffer solution. Moreover, the hollow spherical Cu 2 O particles could be potentially applied in catalysis, sensor, and as model for fundamental research.

  5. Bending nanofibers into nanospirals: coordination chemistry as a tool for shaping hydrophobic assemblies.

    Science.gov (United States)

    Kossoy, Elizaveta; Weissman, Haim; Rybtchinski, Boris

    2015-01-02

    In the current work, we demonstrate how coordination chemistry can be employed to direct self-assembly based on strong hydrophobic interactions. To investigate the influence of coordination sphere geometry on aqueous self-assembly, we synthesized complexes of the amphiphilic perylene diimide terpyridine ligand with the first-row transition-metal centers (zinc, cobalt, and nickel). In aqueous medium, aggregation of these complexes is induced by hydrophobic interactions between the ligands. However, the final shapes of the resulting assemblies depend on the preferred geometry of the coordination spheres typical for the particular metal center. The self-assembly process was characterized by UV/Vis spectroscopy, zeta potential measurements, and cryogenic transmission electron microscopy (cryo-TEM). Coordination of zinc(II) and cobalt(II) leads to the formation of unique nanospiral assemblies, whereas complexation of nickel(II) leads to the formation of straight nanofibers. Notably, coordination bonds are utilized not as connectors between elementary building blocks, but as directing interactions, enabling control over supramolecular geometry. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Analytical solution of the problem of a shock wave in the collapsing gas in Lagrangian coordinates

    Science.gov (United States)

    Kuropatenko, V. F.; Shestakovskaya, E. S.

    2016-10-01

    It is proposed the exact solution of the problem of a convergent shock wave and gas dynamic compression in a spherical vessel with an impermeable wall in Lagrangian coordinates. At the initial time the speed of cold ideal gas is equal to zero, and a negative velocity is set on boundary of the sphere. When t > t0 the shock wave spreads from this point into the gas. The boundary of the sphere will move under the certain law correlated with the motion of the shock wave. The trajectories of the gas particles in Lagrangian coordinates are straight lines. The equations determining the structure of the gas flow between the shock front and gas border have been found as a function of time and Lagrangian coordinate. The dependence of the entropy on the velocity of the shock wave has been found too. For Lagrangian coordinates the problem is first solved. It is fundamentally different from previously known formulations of the problem of the self-convergence of the self-similar shock wave to the center of symmetry and its reflection from the center, which was built up for the infinite area in Euler coordinates.

  7. Dual Smarandache Curves of a Timelike Curve lying on Unit dual Lorentzian Sphere

    OpenAIRE

    Kahraman, Tanju; Hüseyin Ugurlu, Hasan

    2016-01-01

    In this paper, we give Darboux approximation for dual Smarandache curves of time like curve on unit dual Lorentzian sphere. Firstly, we define the four types of dual Smarandache curves of a timelike curve lying on dual Lorentzian sphere.

  8. THE TRANSFORM BETWEEN GEOGRAPHIC COORDINATES AND LOCATION CODES OF APERTURE 4 HEXAGONAL GRID SYSTEM

    Directory of Open Access Journals (Sweden)

    R. Wang

    2017-09-01

    Full Text Available Discrete global grid system is a new data model which supports the fusion processing of multi-source geospatial data. In discrete global grid systems, all cell operations can be completed by codes theoretically, but most of current spatial data are in the forms of geographic coordinates and projected coordinates. It is necessary to study the transform between geographic coordinates and grid codes, which will support data entering and getting out of the systems. This paper chooses the icosahedral hexagonal discrete global system as a base, and builds the mapping relationships between the sphere and the icosahedron. Then an encoding scheme of planar aperture 4 hexagonal grid system is designed and applied to the icosahedron. Basing on this, a new algorithm of transforms between geographic coordinates and grid codes is designed. Finally, experiments test the accuracy and efficiency of this algorithm. The efficiency of code addition of HLQT is about 5 times the efficiency of code addition of HQBS.

  9. The Transform Between Geographic Coordinates and Location Codes of Aperture 4 Hexagonal Grid System

    Science.gov (United States)

    Wang, R.; Ben, J.; Li, Y.; Du, L.

    2017-09-01

    Discrete global grid system is a new data model which supports the fusion processing of multi-source geospatial data. In discrete global grid systems, all cell operations can be completed by codes theoretically, but most of current spatial data are in the forms of geographic coordinates and projected coordinates. It is necessary to study the transform between geographic coordinates and grid codes, which will support data entering and getting out of the systems. This paper chooses the icosahedral hexagonal discrete global system as a base, and builds the mapping relationships between the sphere and the icosahedron. Then an encoding scheme of planar aperture 4 hexagonal grid system is designed and applied to the icosahedron. Basing on this, a new algorithm of transforms between geographic coordinates and grid codes is designed. Finally, experiments test the accuracy and efficiency of this algorithm. The efficiency of code addition of HLQT is about 5 times the efficiency of code addition of HQBS.

  10. Finite Element in Angle Unit Sphere Meshing for Charged Particle Transport.

    Energy Technology Data Exchange (ETDEWEB)

    Ortega, Mario Ivan [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Drumm, Clifton R. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-10-01

    Finite element in angle formulations of the charged particle transport equation require the discretization of the unit sphere. In Sceptre, a three-dimensional surface mesh of a sphere is transformed into a two-dimensional mesh. Projection of a sphere onto a two-dimensional surface is well studied with map makers spending the last few centuries attempting to create maps that preserve proportion and area. Using these techniques, various meshing schemes for the unit sphere were investigated.

  11. Coordinating the Provision of Health Services in Humanitarian Crises: a Systematic Review of Suggested Models.

    Science.gov (United States)

    Lotfi, Tamara; Bou-Karroum, Lama; Darzi, Andrea; Hajjar, Rayan; El Rahyel, Ahmed; El Eid, Jamale; Itani, Mira; Brax, Hneine; Akik, Chaza; Osman, Mona; Hassan, Ghayda; El-Jardali, Fadi; Akl, Elie

    2016-08-03

    Our objective was to identify published models of coordination between entities funding or delivering health services in humanitarian crises, whether the coordination took place during or after the crises. We included reports describing models of coordination in sufficient detail to allow reproducibility. We also included reports describing implementation of identified models, as case studies. We searched Medline, PubMed, EMBASE, Cochrane Central Register of Controlled Trials, CINAHL, PsycINFO, and the WHO Global Health Library. We also searched websites of relevant organizations. We followed standard systematic review methodology. Our search captured 14,309 citations. The screening process identified 34 eligible papers describing five models of coordination of delivering health services: the "Cluster Approach" (with 16 case studies), the 4Ws "Who is Where, When, doing What" mapping tool (with four case studies), the "Sphere Project" (with two case studies), the "5x5" model (with one case study), and the "model of information coordination" (with one case study). The 4Ws and the 5x5 focus on coordination of services for mental health, the remaining models do not focus on a specific health topic. The Cluster approach appears to be the most widely used. One case study was a mixed implementation of the Cluster approach and the Sphere model. We identified no model of coordination for funding of health service. This systematic review identified five proposed coordination models that have been implemented by entities funding or delivering health service in humanitarian crises. There is a need to compare the effect of these different models on outcomes such as availability of and access to health services.

  12. Motion of a sphere in an oscillatory boundary layer: an optical ...

    Indian Academy of Sciences (India)

    Shankar Ghosh

    2006-11-12

    Nov 12, 2006 ... Introduction. WATER. Strong distortion of motion of the sphere at high frequencies. GLYCEROL. Motion of the sphere is sinusoidal and monochromatic. Shankar Ghosh. Motion of a sphere in an oscillatory boundary layer: an optical tweezer based study ...

  13. Electric field of not completely symmetric systems earthed sphere-uniformly charged dielectric plan

    International Nuclear Information System (INIS)

    Vila, F.

    1994-07-01

    In this paper we study theoretically the electric field in the not completely symmetric system, earthed metallic sphere-uniformly charged dielectric plan, for sphere surface points situated in the plan that contains sphere's center and vertical symmetry axe of dielectric plan. (author). 11 refs, 1 fig

  14. STS-36 onboard view of the 'Bonner Sphere', a neutron flux experiment

    Science.gov (United States)

    1990-01-01

    STS-36 experiment called the 'Bonner Sphere', a polyethylene object containing neutron activation foils in its core, is mounted on the middeck starboard wall of Atlantis, Orbiter Vehicle (OV) 104. Different sphere sizes - this one represents the larger ones - sample different portions of high energy neutron flux. The sphere is enclosed in a fire retardant nomex bag.

  15. From “Threads” to Threats: Religion, the Public Sphere, and Why ...

    African Journals Online (AJOL)

    The first part of this article is a theoretical exploration of the use and understanding of the term religion; the notion of the public sphere according to Jürgen Habermas; the media as public sphere; and finally, religion in the media as public sphere. By way of using, but also contesting, Habermas's and other theories of media ...

  16. Account of volume heat capacity on interface in numerical solution of the Stephen problem using the strained coordinates method

    International Nuclear Information System (INIS)

    Latynin, V.A.; Reshetov, V.A.; Karaseva, L.N.

    1988-01-01

    Numerical solution of the Stephen problem by the strained coordinate method is presented for an one-dimensional sphere. Differential formulae of heat fluxes from moving interfaces do not take into account volume heat capacities of the front nodes. Calculations, carried out according to these balanced formulae, as well as according to those usually used, have shown that the balanced formulae permit to reduce approximately by an order the number of nodes on the sphere radius, if similar accuracy of heat balance of the whole process of melting or crystallization is observed. 2 refs.; 1 fig

  17. Random close packing of hard spheres and disks

    International Nuclear Information System (INIS)

    Berryman, J.G.

    1983-01-01

    A simple definition of random close packing of hard spheres is presented, and the consequences of this definition are explored. According to this definition, random close packing occurs at the minimum packing fraction eta for which the median nearest-neighbor radius equals the diameter of the spheres. Using the radial distribution function at more dilute concentrations to estimate median nearest-neighbor radii, lower bounds on the critical packing fraction eta/sub RCP/ are obtained and the value of eta/sub RCP/ is estimated by extrapolation. Random close packing is predicted to occur for eta/sub RCP/ = 0.64 +- 0.02 in three dimensions and eta/sub RCP/ = 0.82 +- 0.02 in two dimensions. Both of these predictions are shown to be consistent with the available experimental data

  18. Signal Analysis by Generalized Hilbert Transforms on the Unit Sphere

    International Nuclear Information System (INIS)

    Wietzke, Lennart; Fleischmann, Oliver; Sommer, Gerald

    2008-01-01

    In 1D signal processing local energy and phase can be determined by the analytic signal. Local energy, phase and orientation of 2D signals can be analyzed by the monogenic signal for all i(ntrinsic)1D signals in an rotational invariant way by the generalized Hilbert transform. In order to analyze both i1D and i2D signals in one framework the main idea of this contribution is to lift up 2D signals to the higher dimensional conformal space in which the original signal can be analyzed with more degrees of freedom by the generalized Hilbert transform on the unit sphere. An appropriate embedding of 2D signals on the unit sphere results in an extended feature space spanned by local energy, phase, orientation/direction and curvature. In contrast to classical differential geometry, local curvature can now be determined by the generalized Hilbert transform in monogenic scale space without any derivatives.

  19. Optimum radars and filters for the passive sphere system

    Science.gov (United States)

    Luers, J. K.; Soltes, A.

    1971-01-01

    Studies have been conducted to determine the influence of the tracking radar and data reduction technique on the accuracy of the meteorological measurements made in the 30 to 100 kilometer altitude region by the ROBIN passive falling sphere. A survey of accuracy requirements was made of agencies interested in data from this region of the atmosphere. In light of these requirements, various types of radars were evaluated to determine the tracking system most applicable to the ROBIN, and methods were developed to compute the errors in wind and density that arise from noise errors in the radar supplied data. The effects of launch conditions on the measurements were also examined. Conclusions and recommendations have been made concerning the optimum tracking and data reduction techniques for the ROBIN falling sphere system.

  20. CFD simulation of dimpled sphere and its wind tunnel verification

    Directory of Open Access Journals (Sweden)

    Spálenský Vojtěch

    2017-01-01

    Full Text Available Paper deals with problems of CFD simulating airflow over a dimpled spherical surface and its verification by the wind tunnel measurement. The low-cost simulation approach was applied to be run on a common PC using the commercial software ANSYS CFX. The wind tunnel testing has been performed in the laboratory of aerodynamics at the Department of Air Force and Aircraft Technology of the University of Defence. Measured results of the drag coefficient versus the Reynolds number for smooth and dimpled spheres were compared and discussed. Presented simulation corresponds adequately to the experimental results. It can be stated that the CFD simulation is suitable for simulating the flow over the dimpled surfaces similar to sphere.

  1. Breeder fuel pellet fabrication from gel-sphere conversion

    International Nuclear Information System (INIS)

    McLemore, D.R.; Bennett, D.W.; Hart, P.E.; Norman, R.E.

    1980-01-01

    The development of automated nuclear fuel fabrication methods is the goal of the United States breeder reactor program and will form the technological basis for the future breeder reactor fuel supply. A major factor in achieving this goal is the development of remotely operated fuel fabrication equipment. The program schedule is to demonstrate the feasibility of automated pellet fuel fabrication and remote maintenance techniques by the mid-1980's. Development of major ceramic unit operations and the required computer control system is currently in the engineering testing stage. This report describes the planned program activities for evaluating the gel-sphere conversion process and demonstrating the fabrication of breeder fuel pellets from these gel-derived spheres

  2. Analytic study of a rolling sphere on a rough surface

    Directory of Open Access Journals (Sweden)

    Olivia A. Florea

    2016-11-01

    Full Text Available In this paper it is realized an analytic study of the rolling’s sphere on a rough horizontal plane under the action of its own gravity. The necessities of integration of the system of dynamical equations of motion lead us to find a reference system where the motion equations should be transformed into simpler expressions and which, in the presence of some significant hypothesis to permit the application of some original methods of analytical integration. In technical applications, the bodies may have a free rolling motion or a motion constrained by geometrical relations in assemblies of parts and machine parts. This study involves a lot of investigations in the field of tribology and of applied dynamics accompanied by experiments. Multiple recordings of several trajectories of the sphere, as well as their treatment of images, also followed by statistical processing experimental data allowed highlighting a very good agreement between the theoretical findings and experimental results.

  3. Hard sphere dynamics for normal and granular fluids.

    Science.gov (United States)

    Dufty, James W; Baskaran, Aparna

    2005-06-01

    A fluid of N smooth, hard spheres is considered as a model for normal (elastic collision) and granular (inelastic collision) fluids. The potential energy is discontinuous for hard spheres so that the pairwise forces are singular and the usual forms of Newtonian and Hamiltonian mechanics do not apply. Nevertheless, particle trajectories in the N particle phase space are well defined and the generators for these trajectories can be identified. The first part of this presentation is a review of the generators for the dynamics of observables and probability densities. The new results presented in the second part refer to applications of these generators to the Liouville dynamics for granular fluids. A set of eigenvalues and eigenfunctions of the generator for this Liouville dynamics system is identified in a special stationary representation. This provides a class of exact solutions to the Liouville equation that are closely related to hydrodynamics for granular fluids.

  4. Radioembolization for hepatocellular carcinoma using TheraSphere®.

    Science.gov (United States)

    Ali, Safiyya Mohamed

    2011-01-01

    Hepatocellular carcinoma (HCC) is the most common primary malignancy of the liver. Radioembolization with yttrium-90 (Y90) microspheres is a new concept in radiation therapy for HCC. This review focuses on the indications, efficacy, side effects, and future direction of Y90 therapy, using TheraSphere® , in HCC patients. Comprehensive literature reviews have described the clinical and scientific evidence of Y90 therapy. The Radioembolization Brachytherapy Oncology Consortium has concluded that there is sufficient evidence to support the safe and effective use of this locoregional therapy in HCC patients, including those with portal vein thrombosis. There are currently no randomized clinical trials done on TheraSphere® and none of the studies so far have shown a survival benefit. Thus, although it represents a very promising therapy with excellent initial results, it cannot be fully recommended yet, till well-designed, large, randomized clinical studies are conducted showing survival benefits.

  5. Application for coordinate transformation between Gaus - Kruger projection: Bessel ellipsoid and UTM projection: WGS84 ellipsoid

    Directory of Open Access Journals (Sweden)

    Zoran Gojković

    2017-01-01

    Full Text Available The physical surface of the earth has irregular shape which is not mathematically defined, therefore the shape of the Earth is approximated with mathematically defined surfaces such as ellipsoid and sphere. The developing of a global positioning systems, thus and modern navigation systems, as effect produce large amounts of data which contain the problem of homogeneity. This problem could be exceed if all the data are store in the same coordinate system. Hence the need for data transformation from local coordinate systems to the global coordinate systems. Global level implies WGS84 ellipsoid and UTM projection while national coordinate system of Republic Serbia is Gauss-Kruger with Bessel ellipsoid. This coordinate system of Republic Serbia on a global level has a local character. Applying appropriate mathematical models and functions it is possible to transform coordinates from one system to another and vice versa. The paper describes coordinate transformations from Gauss-Kruger coordinate system ellipsoid Bessel to UTM projection WGS84 ellipsoid and vice versa, and also an application which provides transformation of its kind that is made using open source environment. Name of the application is TRANS7_GK_UTM_GK and it can be found and used on the web page of the faculty for Mining and Geology under the link http://gk2utm.rgf.bg.ac.rs with a user guide.

  6. Creating learning opportunities for students with Science on a Sphere

    OpenAIRE

    Bates, Kara

    2014-01-01

    In many classrooms, teachers are looking for ways to increase student engagement. Disengaged students are not reaching their full potential and experience relatively high levels of anxiety and frustration, which negatively impacts learning. Providing multiple hands-on and problem-solving learning opportunities can increase student engagement. The new curriculum developed for use on the Science on a Sphere provides educators with a resource to create problem-solving learning opportunities in t...

  7. Elastodynamic cloaking and field enhancement for soft spheres

    Science.gov (United States)

    Diatta, Andre; Guenneau, Sebastien

    2016-11-01

    We propose a spherical cloak described by a non-singular asymmetric elasticity tensor {C} depending upon a small parameter η, that defines the softness of a region one would like to conceal from elastodynamic waves. By varying η, we generate a class of soft spheres dressed by elastodynamic cloaks, which are shown to considerably reduce the scattering of the soft spheres. Importantly, such cloaks also provide some wave protection except for a countable set of frequencies, for which some large elastic field enhancement can be observed within the soft spheres. Through an investigation of trapped modes in elasticity, we supply a good approximation of such Mie-type resonances by some transcendental equation. Our results, unlike previous studies that focused merely on the invisibility aspects, shed light on potential pitfalls of elastodynamic cloaks for earthquake protection designed via geometric transforms: a seismic cloak needs to be designed in such a way that its inner resonances differ from eigenfrequencies of the building one wishes to protect. In order to circumvent this downfall of field enhancement inside the cloaked area, we introduce a novel generation of cloaks, named here, mixed cloaks. Such mixed cloaks consist of a shell that detours incoming waves, hence creating an invisibility region, and of a perfectly matched layer (PML, located at the inner boundary of the cloaks) that absorbs residual wave energy in such a way that aforementioned resonances in the soft sphere are strongly attenuated. The designs of mixed cloaks with a non-singular elasticity tensor combined with an inner PML and non-vanishing density bring seismic cloaks one step closer to a practical implementation. Note in passing that the concept of mixed cloaks also applies in the case of singular cloaks and can be translated in other wave areas for a similar purpose (i.e. to smear down inner resonances within the invisibility region).

  8. Role of moving planes and moving spheres following Dupin cyclides

    KAUST Repository

    Jia, Xiaohong

    2014-03-01

    We provide explicit representations of three moving planes that form a μ-basis for a standard Dupin cyclide. We also show how to compute μ-bases for Dupin cyclides in general position and orientation from their implicit equations. In addition, we describe the role of moving planes and moving spheres in bridging between the implicit and rational parametric representations of these cyclides. © 2014 Elsevier B.V.

  9. Upgrading the Investment Capacity of the Scientific Sphere in Ukraine

    Directory of Open Access Journals (Sweden)

    Burdonos Ludmila

    2016-11-01

    Full Text Available The article analyzes the effective system of distribution of public funds for investing into the sphere of science. Alternative factors of promoting cooperation with foreign subjects of scientific activity are determined. It is established that an important factor, determining the activity of research and development in the country, is the system of redistribution of financial risks from investing into research and development.

  10. The public sphere, women and the casamance peace process

    Directory of Open Access Journals (Sweden)

    Irene N. Osemeka

    2011-06-01

    Full Text Available Las mujeres en la Casamance tradicionalmente se limita a la esfera privada como madres, esposas y los agricultores, mientras que algunos sacerdotes son mujeres. La naturaleza prolongada del conflicto de Casamance ha tenido efectos devastadores sobre la población civil, incluidas las mujeres. Pero también ha ofrecido oportunidades para que las mujeres contribuyan al proceso de paz lo que les empuja a la esfera pública, que de otro modo, es el dominio de los hombres. El documento se centra en los esfuerzos de reconciliación en la región de Casamance que muestra la relación entre la esfera pública, las mujeres y la resolución de conflictos. Asimismo, ofrecer soluciones que pueden conducir a un proceso más integrador, teniendo en cuenta el enfoque de exclusión de los esfuerzos de paz de Casamance, que ha contribuido significativamente a la imposibilidad de lograr una solución duradera al conflicto.Palabras claves: espacio público. Proceso de Paz.___________________________Abstract:Women in the Casamance are traditionally confined to the private sphere as mothers, wives and farmers while a few are female priests. The protracted nature of the Casamance conflict has had devastating effects on the civilian population including women. But it has also provided opportunities for women to contribute to the peace process thereby thrusting them into the public sphere, which otherwise, is the domain of men. The paper focuses on the reconciliatory efforts in the Casamance showing the link between the public sphere, women and the resolution of conflicts. It will also proffer solutions that can lead to a more inclusive process, taking into consideration the exclusionary approach of the Casamance peace efforts which has contributed significantly to the failure to achieve durable solution to the conflict.Keywords: Public Sphere. Peace Process.

  11. Solvothermal synthesis of cobalt ferrite hollow spheres with chitosan.

    Science.gov (United States)

    Briceño, Sarah; Suarez, Jorge; Gonzalez, Gema

    2017-09-01

    Cobalt ferrite hollow spheres with chitosan (CoFe 2 O 4 /CS) were synthesized by two different approaches using the solvothermal method. The first approach involves in-situ incorporation of FeCl 3 :6H 2 O and CoNO 3 :6H 2 O in the solvothermal reaction (M1) and in second approach already prepared CoFe 2 O 4 nanoparticles (NPs) using the thermal decomposition method was placed in the solvothermal reaction to form the hollow spheres (M2). Structural identification of the samples were characterized by Fourier transform infrared spectra (FTIR), powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analyses (DSC-TGA) and energy dispersive X-ray spectroscopy (EDX). The magnetic properties were evaluated using a vibrating sample magnetometer (VSM). The presence of chitosan on the hollow sphere was confirmed by FTIR. The XRD analyses proved that the synthesized samples were cobalt ferrite with spinel structure. The structure of the surface and the average particle size of the spheres were observed by SEM and TEM showing the nano scale of the CoFe 2 O 4 component. Structural characterization demonstrating that chitosan does not affect the crystallinity, chemical composition, and magnetic properties of the CoFe 2 O 4 /CS. This work demonstrates that the CoFe 2 O 4 /CS prepared using the as synthesized CoFe 2 O 4 NPs have better structural and magnetic properties. Copyright © 2017 Elsevier B.V. All rights reserved.

  12. Spectrophotometer-Integrating-Sphere System for Computing Solar Absorptance

    Science.gov (United States)

    Witte, William G., Jr.; Slemp, Wayne S.; Perry, John E., Jr.

    1991-01-01

    A commercially available ultraviolet, visible, near-infrared spectrophotometer was modified to utilize an 8-inch-diameter modified Edwards-type integrated sphere. Software was written so that the reflectance spectra could be used to obtain solar absorptance values of 1-inch-diameter specimens. A descriptions of the system, spectral reflectance, and software for calculation of solar absorptance from reflectance data are presented.

  13. Regularity of optimal transport maps on multiple products of spheres

    OpenAIRE

    Figalli, Alessio; Kim, Young-Heon; McCann, Robert J.

    2010-01-01

    This article addresses regularity of optimal transport maps for cost="squared distance" on Riemannian manifolds that are products of arbitrarily many round spheres with arbitrary sizes and dimensions. Such manifolds are known to be non-negatively cross-curved [KM2]. Under boundedness and non-vanishing assumptions on the transfered source and target densities we show that optimal maps stay away from the cut-locus (where the cost exhibits singularity), and obtain injectivity and continuity of o...

  14. Solar sphere viewed through the Skylab solar physics experiment

    Science.gov (United States)

    1973-01-01

    The solar sphere viewed through the Skylab solar physics experiment (S082) Extreme Ultraviolet Spectroheliographis seen in this photographic reproduction taken from a color television transmission made by a TV camera aboard the Skylab space station in Earth orbit. The solar chromosphere and lower corona are much hotter than the surface of the Sun characterized by the white light emissions. This image was recorded during the huge solar prominence which occurred on August 21, 1973.

  15. Satellite Relative Motion Control for MIT’s SPHERES Program

    Science.gov (United States)

    2012-03-01

    verv iew 128 Desire(! Position...fi1CortrllAI[1Jrittrnto be lmplemerteCI on SPHERES Oli:puts F igu re B .2: E rror D eterm in ation O verv iew 129 Desired Translational States (Global Frame...lltl G) I • I Desired Pointing Vector Mag1 1 Eigenaxis of Rotation F igu re B .9: S p eed & P ath C on troller O verv iew 137 3-0

  16. The Strategic Partnership between Russia and China in Educational Sphere

    Directory of Open Access Journals (Sweden)

    Lyu Tseya

    2013-01-01

    Full Text Available The paper is devoted to the scientific and educational cooperation of Russia and China. Over the last two decades it has developed dramatically due to the constant support of the countries’ leaders and resultedin a large number of agreements in scientific, technical, educational and cultural spheres. The partnership involves the joint research programs, training programs, scientific and educational activities, mutual support of academic mobility of teachers and students, international conferences, workshops, contests of innovative projects and students’ festivals. The research methodology combines general scientific methods of logicalcognition, analysis and synthesis, and statistic methods of selection, combination, comparison and generalization. The paper demonstrates the dynamics of Chinese students graduated in Russia from 1950 to 2013 and Russian students graduated in China in the last thirteen years, as well as therelated prognoses for 2020.The partnership between Russia and China in educational sphere has a strategic importance for economic stability and steady development of both countries in the nearest and distant future, given the globalization processes, complicated international situation, etc. However, there still remains a considerable potential for the reciprocal friendly cooperation in educational and cultural spheres. The author emphasizes a need for further exploration and development of the intellectual exchange mechanisms and effectiveness of the process.

  17. Anisotropic fluid spheres of embedding class one using Karmarkar condition

    Energy Technology Data Exchange (ETDEWEB)

    Maurya, S.K. [University of Nizwa, Department of Mathematical and Physical Sciences, College of Arts and Science, Nizwa (Oman); Maharaj, S.D. [School of Mathematics, Statistics and Computer Science, University of KwaZulu-Natal, Astrophysics and Cosmology Research Unit, Private Bag X54001, Durban (South Africa)

    2017-05-15

    We obtain a new anisotropic solution for spherically symmetric spacetimes by analyzing the Karmarkar embedding condition. For this purpose we construct a suitable form of one of the gravitational potentials to obtain a closed form solution. This form of the remaining gravitational potential allows us to solve the embedding equation and integrate the field equations. The resulting new anisotropic solution is well behaved, which can be utilized to construct realistic static fluid spheres. Also we estimated the masses and radii of fluid spheres for LMC X-4, EXO 1785-248, PSR J1903+327 and 4U 1820-30 by using observational data set values. The masses and radii obtained show that our anisotropic solution can represent fluid spheres to a very good degree of accuracy. The physical validity of the solution depends on the parameter values of a, b and c. The solution is well behaved for the wide range of parameters values 0.00393 ≤ a ≤ 0.0055, 0.0002 ≤ b ≤ 0.0025 and 0.0107 ≤ c ≤ 0.0155. The range of corresponding physical parameters for the different compact stars are 0.3266 ≤ v{sub r0} ≤ 0.3708, 0.1583 ≤ v{sub t0} ≤ 0.2558, 0.3256 ≤ z{sub s} ≤ 0.4450 and 4.3587 ≤ Γ{sub 0} ≤ 5.6462. (orig.)

  18. Inelastic accretion of inertial particles by a towed sphere

    Science.gov (United States)

    Vallée, Robin; Henry, Christophe; Hachem, Elie; Bec, Jérémie

    2018-02-01

    The problem of accretion of small particles by a sphere embedded in a mean flow is studied in the case where the particles undergo inelastic collisions with the solid object. The collision efficiency, which gives the flux of particles experiencing at least one bounce on the sphere, is found to depend upon the sphere Reynolds number only through the value of the critical Stokes number below which no collision occurs. In the absence of molecular diffusion, it is demonstrated that multiple bounces do not provide enough energy dissipation for the particles to stick to the surface within a finite time. This excludes the possibility of any kind of inelastic collapse, so that determining an accretion efficiency requires modeling more precisely particle-surface microphysical interactions. A straightforward choice is to assume that the particles stick when their kinetic energy at impact is below a threshold. In this view, numerical simulations are performed to describe the statistics of impact velocities at various values of the Reynolds number. Successive bounces are shown to enhance accretion. These results are put together to provide a general qualitative picture on how the accretion efficiency depends upon the nondimensional parameters of the problem.

  19. Composite micro-sphere optical resonators for electric field measurement

    Science.gov (United States)

    Stubblefield, J.; Womack, D.; Ioppolo, T.; Ayaz, U.; Otugen, M. V.

    2012-02-01

    Polymer-based, multi-layered dielectric microspheres are investigated for high-resolution electric field sensing. The external electric field induces changes in the morphology of the spheres, leading to shifts in the whispering gallery modes (WGMs). Light from a distributed feedback (DFB) laser is sidecoupled into the microspheres using a tapered section of a single mode optical fiber to interrogate the optical modes. The base material of these multi-layered spheres is polydimethylsiloxane (PDMS). Three microsphere geometries are investigated: (1) cores comprised of a 60:1 volumetric ratio of PDMS-to-curing agent mixture that are mixed with varying amounts of barium titanate (BaTiO3) nano particles, (2) cores comprised of 60:1 PDMS that are coated with a thin layer of 60:1 PDMS that is mixed with varying amounts of barium titanate and (3) a composite Carbon Black-BaTiO3 prototype. The outermost layer for all sphere geometries is a thin coat of 60:1 PDMS which serves as the shell waveguide. Light from the tapered laser is coupled into this outermost shell that provides high optical quality factor WGM (Q ~ 106). The microspheres are poled for several hours at electric fields of ~ 1 MV/m to increase their sensitivity to electric field. Preliminary results show that electric fields of the order of 100 V/m can be detected using these composite micro-resonators.

  20. The sphere-in-contact model of carbon materials.

    Science.gov (United States)

    Zeinalipour-Yazdi, Constantinos D; Pullman, David P; Catlow, C Richard A

    2016-01-01

    A sphere-in-contact model is presented that is used to build physical models of carbon materials such as graphite, graphene, carbon nanotubes and fullerene. Unlike other molecular models, these models have correct scale and proportions because the carbon atoms are represented by their atomic radius, in contrast to the more commonly used space-fill models, where carbon atoms are represented by their van der Waals radii. Based on a survey taken among 65 undergraduate chemistry students and 28 PhD/postdoctoral students with a background in molecular modeling, we found misconceptions arising from incorrect visualization of the size and location of the electron density located in carbon materials. Based on analysis of the survey and on a conceptual basis we show that the sphere-in-contact model provides an improved molecular representation of the electron density of carbon materials compared to other molecular models commonly used in science textbooks (i.e., wire-frame, ball-and-stick, space-fill). We therefore suggest that its use in chemistry textbooks along with the ball-and-stick model would significantly enhance the visualization of molecular structures according to their electron density. Graphical Abstract A sphere-in-contact model of C60-fullerene.

  1. Platonic polyhedra tune the 3-sphere: harmonic analysis on simplices

    International Nuclear Information System (INIS)

    Kramer, Peter

    2009-01-01

    A spherical topological manifold of dimension n- 1 forms a prototile on its cover, the (n- 1)-sphere. The tiling is generated by the fixpoint-free action of the group of deck transformations. By a general theorem, this group is isomorphic to the first homotopy group. A basis for the harmonic analysis on the (n- 1)-sphere is given by the spherical harmonics that transform according to irreducible representations of the orthogonal group. Multiplicity and selection rules appear in the form of reduction of group representations. The deck transformations form a subgroup and so the representations of the orthogonal group can be reduced to those of this subgroup. Upon reducing to the identity representation of the subgroup, the reduced subset of spherical harmonics becomes periodic on the tiling and tunes the harmonic analysis on the (n-1)-sphere to the manifold. A particular class of spherical 3-manifolds arises from the Platonic polyhedra. The harmonic analysis on the Poincare dodecahedral 3-manifold was analyzed along these lines. For comparison we construct here the harmonic analysis on simplicial spherical manifolds of dimension n=1, 2, 3. Harmonic analysis can be applied to the cosmic microwave background observed in astrophysics. Selection rules found in this analysis can detect the multiple connectivity of spherical 3-manifolds on the space part of cosmic space-time.

  2. AGEISM IN THE SPHERE OF HEALTH SUPPORT OF SENIOR CITIZENS

    Directory of Open Access Journals (Sweden)

    Lola Vladimirovna Kolpina

    2013-10-01

    Full Text Available The paper based on the results of the focus group which includes a medical and social workers; the ageism’s problems of the elderly people in the spheres of medical care, social protection and security are discussed. It is proved that the display of ageism is more typical for the medical sphere; practice of ageism has moral, organizational and socio-economic aspects, in the sphere of social protect and ensuring the greatest risks of ageism are associated with high psychological stress on social workers, which is conditioned with the complexity of communication with the elderly people.Purpose. Sociological diagnostics displays ageism elderly people in health and social work in the Belgorod region.Methodology. To achieve this goal, in May 2013 we carried out a focus group composed of doctors, nurses and employees of social service agencies and security in the amount of 16 people.Results. Theoretical and empirical models of ageismPractical implications. Institutions of medical and social services, and educational institutions that train specialists of relevant specialties.DOI: http://dx.doi.org/10.12731/2218-7405-2013-7-24

  3. Transnational Chinese Sphere in Singapore: Dynamics, Transformations and Characteristics

    Directory of Open Access Journals (Sweden)

    Hong Liu

    2012-01-01

    Full Text Available Based upon an empirical analysis of Singaporean Chinese’s intriguing and changing linkages with China over the past half century, this paper suggests that multi-layered interactions between the Chinese diaspora and the homeland have led to the formulation of an emerging transnational Chinese social sphere, which has three main characteristics: First, it is a space for communication by ethnic Chinese abroad with their hometown/ homeland through steady and extensive flows of people, ideas, goods and capital that transcend the nation-state borders, although states also play an important role in shaping the nature and characteristics of these flows. Second, this transnational social sphere constitutes a dynamic interface between economy, politics and culture, which has contributed to creating a collective diasporic identity as well as social and business networks. Third, the key institutional mechanism of the transnational social sphere is various types of Chinese organizations – ranging from hometown associations to professional organizations – which serve as integral components of Chinese social and business networks.

  4. Coordinating Group report

    International Nuclear Information System (INIS)

    1994-01-01

    In December 1992, western governors and four federal agencies established a Federal Advisory Committee to Develop On-site Innovative Technologies for Environmental Restoration and Waste Management (the DOIT Committee). The purpose of the Committee is to advise the federal government on ways to improve waste cleanup technology development and the cleanup of federal sites in the West. The Committee directed in January 1993 that information be collected from a wide range of potential stakeholders and that innovative technology candidate projects be identified, organized, set in motion, and evaluated to test new partnerships, regulatory approaches, and technologies which will lead to improve site cleanup. Five working groups were organized, one to develop broad project selection and evaluation criteria and four to focus on specific contaminant problems. A Coordinating Group comprised of working group spokesmen and federal and state representatives, was set up to plan and organize the routine functioning of these working groups. The working groups were charged with defining particular contaminant problems; identifying shortcomings in technology development, stakeholder involvement, regulatory review, and commercialization which impede the resolution of these problems; and identifying candidate sites or technologies which could serve as regional innovative demonstration projects to test new approaches to overcome the shortcomings. This report from the Coordinating Group to the DOIT Committee highlights the key findings and opportunities uncovered by these fact-finding working groups. It provides a basis from which recommendations from the DOIT Committee to the federal government can be made. It also includes observations from two public roundtables, one on commercialization and another on regulatory and institutional barriers impeding technology development and cleanup

  5. Effect of radiation and magnetohydrodynamic free convection boundary layer flow on a solid sphere with Newtonian heating in a micropolar fluid

    Energy Technology Data Exchange (ETDEWEB)

    Alkasasbeh, Hamzeh Taha, E-mail: zukikuj@yahoo.com; Sarif, Norhafizah Md, E-mail: zukikuj@yahoo.com; Salleh, Mohd Zuki, E-mail: zukikuj@yahoo.com [Futures and Trends Research Group, Faculty of Industrial Science and Technology, Universiti Malaysia Pahang, 26300 UMP Kuantan, Pahang (Malaysia); Tahar, Razman Mat [Faculty of Technology, Universiti Malaysia Pahang, 26300 UMP Kuantan, Pahang (Malaysia); Nazar, Roslinda [School of Mathematical Sciences, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia); Pop, Ioan [Department of Mathematics, Babeş-Bolyai University, R-400084 Cluj-Napoca (Romania)

    2015-02-03

    In this paper, the effect of radiation on magnetohydrodynamic free convection boundary layer flow on a solid sphere with Newtonian heating in a micropolar fluid, in which the heat transfer from the surface is proportional to the local surface temperature, is considered. The transformed boundary layer equations in the form of nonlinear partial differential equations are solved numerically using an implicit finite difference scheme known as the Keller-box method. Numerical solutions are obtained for the local wall temperature and the local skin friction coefficient, as well as the velocity, angular velocity and temperature profiles. The features of the flow and heat transfer characteristics for various values of the Prandtl number Pr, micropolar parameter K, magnetic parameter M, radiation parameter N{sub R}, the conjugate parameter γ and the coordinate running along the surface of the sphere, x are analyzed and discussed.

  6. Development of Well-Balanced Regulation in the Sphere of Innovative Financial Technologies for Digitalization of the Common Measure of Value

    Directory of Open Access Journals (Sweden)

    Kotlyarevskyy Yaroslav V.

    2017-11-01

    Full Text Available The article focuses on the modern financial technologies in the sphere of monetary and credit circulation, in particular, the ontology of so-called virtual currencies is investigated, theoretical, methodological and practical aspects of their implementation are defined both in the retrospective and in modern contexts. Along with the analysis of theoretical developments of domestic and foreign scholars, a comparative analysis of the international financial and economic issues of establishing effective regulation was conducted, the main provisions for further improving the coordination of the monetary, financial and economic policies in the mentioned sphere with regard to aspects of sustainable development, institutional economy, tax policy and counteracting the money laundering have been expounded.

  7. Smart SPHERES: A Telerobotic Free-Flyer for Intravehicular Activities in Space

    Science.gov (United States)

    Fong, Terrence; Micire, Mark J.; Morse, Ted; Park, Eric; Provencher, Chris; To, Vinh; Wheeler, D. W.; Mittman, David; Torres, R. Jay; Smith, Ernest

    2013-01-01

    Smart SPHERES is a prototype free-flying space robot based on the SPHERES platform. Smart SPHERES can be remotely operated by astronauts inside a spacecraft, or by mission controllers on the ground. We developed Smart SPHERES to perform a variety of intravehicular activities (IVA), such as operations inside the International Space Station (ISS). These IVA tasks include environmental monitoring surveys (radiation, sound levels, etc.), inventory, and mobile camera work. In this paper, we first discuss the motivation for free-flying space robots. We then describe the development of the Smart SPHERES prototype, including avionics, software, and data communications. Finally, we present results of initial flight tests on-board the ISS.

  8. Model of the absorbed dose on a small sphere into a gamma irradiation field

    International Nuclear Information System (INIS)

    Mangussi, J.

    2009-01-01

    Several models of the absorbed dose calculated as the energy deposited by the secondary electrons on a small volume sphere are presented. The calculations use the Compton scattering of a uniform photon beam in water, the photon attenuation and the electron stopping power are included. The sphere total absorbed dose is due to the stopping of the electrons generated in three regions: into the sphere volume, ahead and behind the sphere volume. Calculations are performed for spheres of different radius and placed at various depth of the vacuum - water interface. (author)

  9. Developmental coordination disorder - literature review

    OpenAIRE

    Kosová, Blanka

    2015-01-01

    Title: Developmental coordination disorder - literature review Objectives: The theoretical part talks about developmental coordination disorder, its diagnosis, investigations, etiology and division during the different ages of the child. The practical part compares the studies relating to atypical development of motor skills in children with developmental coordination disorder. In diploma thesis was often used shortcut CKP and DCD, depending on the source from which it was drawn. DCD is the E...

  10. Synchronization matters for motor coordination.

    Science.gov (United States)

    Pesce Ibarra, Luigi S

    2018-03-01

    Using electroencephalography and electromyography recordings from healthy participants during a visual-depended bimanual coordination task, de Vries and colleagues showed that functional synchronization is important in motor coordination. The authors reported that higher coordination correlated positively with intermuscular synchrony, but correlated negatively with corticomuscular synchrony. They proposed that these two diverse motor systems operate differently depending on task demands. Similar experimental paradigms could identify motor mechanisms in patients with neurological disorders to design novel rehabilitation strategies.

  11. Pull Promotions and Channel Coordination

    OpenAIRE

    Eitan Gerstner; James D. Hess

    1995-01-01

    This paper recommends that manufacturers consider a pull price promotion as a coordination device in an independent channel of distribution. Uncoordinated decisions of both manufacturer and retailer to charge high prices can break down the effort to expand the market, resulting in losses to the channel as a whole. We show that manufacturers can enhance channel price coordination by designing pull price discounts that target price-conscious consumers. The increased price coordination improves ...

  12. Initial Examination of Low Velocity Sphere Impact of Glass Ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Morrissey, Timothy G [ORNL; Fox, Ethan E [ORNL; Wereszczak, Andrew A [ORNL; Ferber, Mattison K [ORNL

    2012-06-01

    This report summarizes US Army TARDEC sponsored work at Oak Ridge National Laboratory (ORNL) involving low velocity (< 30 m/s or < 65 mph) sphere impact testing of two materials from the lithium aluminosilicate family reinforced with different amounts of ceramic particulate, i.e., glass-ceramic materials, SCHOTT Resistan{trademark}-G1 and SCHOTT Resistan{trademark}-L. Both materials are provided by SCHOTT Glass (Duryea, PA). This work is a follow-up to similar sphere impact studies completed by the authors on PPG's Starphire{reg_sign} soda-lime silicate glass and SCHOTT BOROFLOAT{reg_sign} borosilicate glass. A gas gun or a sphere-drop test setup was used to produce controlled velocity delivery of silicon nitride (Si{sub 3}N{sub 4}) spheres against the glass ceramic tile targets. Minimum impact velocities to initiate fracture in the glass-ceramics were measured and interpreted in context to the kinetic energy of impact and the elastic property mismatch between sphere and target material. Quasistatic spherical indentation was also performed on both glass ceramics and their contact damage responses were compared to those of soda-lime silicate and borosilicate glasses. Lastly, variability of contact damage response was assessed by performing spherical indentation testing across the area of an entire glass ceramic tile. The primary observations from this low velocity (< 30 m/s or < 65 mph) testing were: (1) Resistan{trademark}-L glass ceramic required the highest velocity of sphere impact for damage to initiate. Starphire{reg_sign} soda-lime silicate glass was second best, then Resistan{trademark}-G1 glass ceramic, and then BOROFLOAT{reg_sign} borosilicate glass. (2) Glass-ceramic Resistan{trademark}-L also required the largest force to initiate ring crack from quasi-static indentation. That ranking was followed, in descending order, by Starphire{reg_sign} soda-lime silicate glass, Resistan{trademark}-G1 glass ceramic, and BOROFLOAT{reg_sign} borosilicate glass

  13. Plane shear flows of frictionless spheres: Kinetic theory and 3D soft-sphere discrete element method simulations

    Science.gov (United States)

    Vescovi, D.; Berzi, D.; Richard, P.; Brodu, N.

    2014-05-01

    We use existing 3D Discrete Element simulations of simple shear flows of spheres to evaluate the radial distribution function at contact that enables kinetic theory to correctly predict the pressure and the shear stress, for different values of the collisional coefficient of restitution. Then, we perform 3D Discrete Element simulations of plane flows of frictionless, inelastic spheres, sheared between walls made bumpy by gluing particles in a regular array, at fixed average volume fraction and distance between the walls. The results of the numerical simulations are used to derive boundary conditions appropriated in the cases of large and small bumpiness. Those boundary conditions are, then, employed to numerically integrate the differential equations of Extended Kinetic Theory, where the breaking of the molecular chaos assumption at volume fraction larger than 0.49 is taken into account in the expression of the dissipation rate. We show that the Extended Kinetic Theory is in very good agreement with the numerical simulations, even for coefficients of restitution as low as 0.50. When the bumpiness is increased, we observe that some of the flowing particles are stuck in the gaps between the wall spheres. As a consequence, the walls are more dissipative than expected, and the flows resemble simple shear flows, i.e., flows of rather constant volume fraction and granular temperature.

  14. Plane shear flows of frictionless spheres: Kinetic theory and 3D soft-sphere discrete element method simulations

    International Nuclear Information System (INIS)

    Vescovi, D.; Berzi, D.; Richard, P.; Brodu, N.

    2014-01-01

    We use existing 3D Discrete Element simulations of simple shear flows of spheres to evaluate the radial distribution function at contact that enables kinetic theory to correctly predict the pressure and the shear stress, for different values of the collisional coefficient of restitution. Then, we perform 3D Discrete Element simulations of plane flows of frictionless, inelastic spheres, sheared between walls made bumpy by gluing particles in a regular array, at fixed average volume fraction and distance between the walls. The results of the numerical simulations are used to derive boundary conditions appropriated in the cases of large and small bumpiness. Those boundary conditions are, then, employed to numerically integrate the differential equations of Extended Kinetic Theory, where the breaking of the molecular chaos assumption at volume fraction larger than 0.49 is taken into account in the expression of the dissipation rate. We show that the Extended Kinetic Theory is in very good agreement with the numerical simulations, even for coefficients of restitution as low as 0.50. When the bumpiness is increased, we observe that some of the flowing particles are stuck in the gaps between the wall spheres. As a consequence, the walls are more dissipative than expected, and the flows resemble simple shear flows, i.e., flows of rather constant volume fraction and granular temperature

  15. Triassico: A Sphere Positioning System for Surface Studies with IBA Techniques

    Science.gov (United States)

    Fontana, Cristiano L.; Doyle, Barney L.

    We propose here a novel device, called the Triassico, to microscopically study the entire surface of millimeter-sized spheres. The sphere dimensions can be as small as 1 mm, and the upper limit defined only by the power and by the mechanical characteristics of the motors used. Three motorized driving rods are arranged so an equilateral triangle is formed by the rod's axes, on such a triangle the sphere sits. Movement is achieved by rotating the rods with precise relative speeds and by exploiting the friction between the sphere and the rods surfaces. The sphere can be held in place by gravity or by an opposing trio of rods. By rotating the rods with specific relative angular velocities, a net torque can be exerted on the sphere which then rotates. No repositioning of the sphere or of the motors is needed to cover the full surface with the investigating tools. An algorithm was developed to position the sphere at any arbitrary polar and azimuthal angle. The algorithm minimizes the number of rotations needed by the rods, in order to efficiently select a particular position on the sphere surface. A prototype Triassico was developed for the National Ignition Facility, of the Lawrence Livermore National Laboratory (Livermore, California, USA), as a sphere manipulation apparatus for ion microbeam analysis at Sandia National Laboratories (Albuquerque, NM, USA) of Xe-doped DT inertial confinement fusion fuel spheres. Other applications span from samples orientation, ball bearing manufacturing, or jewelry.

  16. The onset of cavitation during the collision of a sphere with a wetted surface

    KAUST Repository

    Mansoor, Mohammad M.

    2014-01-01

    We investigate the onset of cavitation during the collision of a sphere with a solid surface covered with a layer of Newtonian liquid. The conventional theory dictates cavitation to initiate during depressurization, i.e. when the sphere rebounds from the solid surface. Using synchronized dual-view high-speed imaging, we provide conclusive experimental evidence that confirms this scenario- namely-that cavitation occurs only after the sphere makes initial contact with the solid surface. Similar to previous experimental observations for spheres released above the liquid surface, bubbles are formed on the sphere surface during entry into the liquid layer. These were found to squeeze radially outwards with the liquid flow as the sphere approached the solid surface, producing an annular bubble structure unrelated to cavitation. In contrast, spheres released below the liquid surface did not exhibit these patterns. © Springer-Verlag Berlin Heidelberg 2014.

  17. Study on 14C content in post-irradiation graphite spheres of HTR-10

    International Nuclear Information System (INIS)

    Wang Shouang; Pi Yue; Xie Feng; Li Hong; Cao Jianzhu

    2014-01-01

    Since the production mechanism of the 14 C in spherical fuel elements was similar to that of fuel-free graphite spheres, in order to obtain the amount of 14 C in fuel elements and graphite spheres of HTR-10, the production mechanism of the 14 C in graphite spheres was studied. The production sources of the 14 C in graphite spheres and fuel elements were summarized, the amount of 14 C in the post-irradiation graphite spheres was calculated, the decomposition techniques of graphite spheres were compared, and experimental methods for decomposing the graphite spheres and preparing the 14 C sample were proposed. The results can lay the foundation for further experimental research and provide theoretical calculations for comparison. (authors)

  18. Lanthanide co-ordination frameworks: Opportunities and diversity

    International Nuclear Information System (INIS)

    Hill, Robert J.; Long, De-Liang; Hubberstey, Peter; Schroeder, Martin; Champness, Neil R.

    2005-01-01

    Significant successes have been made over recent years in preparing co-ordination framework polymers that show macroscopic material properties, but in the vast majority of cases this has been achieved with d-block metal-based systems. Lanthanide co-ordination frameworks also offer attractive properties in terms of their potential applications as luminescent, non-linear optical and porous materials. However, lanthanide-based systems have been far less studied to date than their d-block counterparts. One possible reason for this is that the co-ordination spheres of lanthanide cations are more difficult to control and, in the absence of design strategies for lanthanide co-ordination frameworks, it is significantly more difficult to target materials with specific properties. However, this article highlights some of the exciting possibilities that have emerged from the earliest investigations in this field with new topological families of compounds being discovered from relatively simple framework components, including unusual eight, seven and five-connected framework systems. Our own research, as well as others, is leading to a much greater appreciation of the factors that control framework formation and the resultant observed topologies of these polymers. As this understanding develops targeting particular framework types will become more straightforward and the development of designed polyfunctional materials more accessible. Thus, it can be seen that lanthanide co-ordination frameworks have the potential to open up previously unexplored directions for materials chemistry. This article focuses on the underlying concepts for the construction of these enticing and potentially highly important materials

  19. Wake structures of two side by side spheres in a tripped boundary layer flow

    Directory of Open Access Journals (Sweden)

    Canli Eyüb

    2014-03-01

    Full Text Available Two independent spheres were placed in a side by side arrangement and flow structure in the wake region of the spheres was investigated with a Particle Image Velocimetry (PIV system when the spheres were in a boundary layer over a flat plate as a special case. Reynolds number was 5000 based on the sphere diameter which was 42.5 mm. Boundary layer was tripped 8mm away from the leading edge of the flat plate with a 5 mm trip wire. The thickness of the hydrodynamically developed boundary layer was determined as 63mm which was larger than the sphere diameter of D=42.5mm. Wake region of the spheres was examined from point of flow physics for the different sphere locations in the ranges of 0≤G/D ≤1.5 and 0≤S/D ≤1.5 where G and S were the distance between the spheres and the distance between the bottom point of the spheres and the flat plate surface, respectively. Depending on the different sphere locations, instantaneous and time averaged vorticity data, scalar values of time-averaged velocity components and their root mean square (rms values and time averaged vorticity data are presented in the study for the evaluation of wake region of the spheres. It is demonstrated that the gap between the two spheres and the interaction between the gap and the boundary layer greatly affects flow pattern, especially when spheres are located near to the flat plate surface, i.e. S/D=0.1 for 0≤G/D ≤1.5. Different distances between the spheres resulted in various flow patterns as the spheres were approached to the flat plate. The distance S/D=0.1 for all gap values has the strongest effect on the wake structures. Beyond G/D=1.0, the sphere wakes tend to be similar to single sphere case. The instantaneous vorticity fields of the side by side arrangements comprised wavy structures in higher level comparing to an individual sphere case. The gap flow intensifies the occurrence of small scale eddies in the wake region. The submersion rate of the spheres

  20. Flexoelectricity via coordinate transformations

    Science.gov (United States)

    Stengel, Massimiliano

    2014-03-01

    Flexoelectricity describes the electric polarization that is linearly induced by a strain gradient, and is being intensely investigated as a tantalizing new route to converting mechanical stimulation into electrical signals and vice versa. While several breakthough experiments have been reported in the past few years, progress on the theoretical front has been comparatively slow, especially in the context of first-principles electronic-structure theory. The main difficulty with calculating the flexoelectric response of a material is the inherent breakdown of translational periodicity that a strain gradient entails, which at first sight questions the very applicability of traditional plane-wave pseudopotential methods. In this talk I will show how these obstacles can be overcome by combining density-functional perturbation theory with generalized coordinate transformations, gaining access to the full microscopic response (in terms of electronic charge density, polarization and atomic displacements) of a crystal or nanostructure to an arbitrary deformation field. As a practical demonstration, I will present results on the full flexoelectric response of a SrTiO3 film, including atomic relaxations and surface effects.

  1. Characterization studies and cyclic voltammetry on nickel(II amino acid dithiocarbamates with triphenylphosphine in the coordination sphere

    Directory of Open Access Journals (Sweden)

    SUBBIAH THIRUMARAN

    2008-02-01

    Full Text Available Nickel(II amino acid dithiocarbamate complexes of the composition [Ni(AAdtc(PPh3(NCS], [Ni(AAdtc(PPh3(CN] and [Ni(AAdtc(PPh32]ClO4 [(AAdtc = dithiocarbamate derivatives of amino acids, i.e., glycine (glydtc, L-iso-leucine (i-leudtc and L-proline (prodtc] were synthesized. The compounds were characterized by IR and electronic spectroscopy, thermal analysis, cyclic voltammetry and conductivity measurements. In the case of the mixed ligand complexes, the thioureide n(C−N values were shifted to higher wave numbers compared to [Ni(AAdtc2]. This observation shows the increased strength of the thioureide bond due to the presence of the p-accepting phosphine. Electronic spectral studies suggest square planar geometry for the complexes. Thermal analyses of the complexes are in keeping with the proposed formulae. Almost all the complexes showed signs of decay above 170 °C. At around 390 °C, the final mass corresponded to NiS. Cyclic voltammetry showed a decrease of the electron density on the nickel in the mixed ligand complexes compared to [Ni(AAdtc2].

  2. Drug policy coordination: identifying and assessing dimensions of coordination.

    Science.gov (United States)

    Hughes, Caitlin Elizabeth; Ritter, Alison; Mabbitt, Nicholas

    2013-05-01

    Coordination has been recognised as a critical ingredient for successful drug policy governance. Yet what coordination means and how we assess the processes, outputs and outcomes of drug policy coordination is seldom defined. In this article we explore the utility of internationally recognised principles of good governance for examining aspects of drug policy coordination. We describe the development of an assessment tool, and pilot it in one context that has been both praised and criticised for its approach to drug policy coordination: Australia. Eight good governance principles of the United Nations Economic and Social Commission for Asia and the Pacific (which specify the need for policy processes to be participatory, responsive, equitable etc.), were adapted to drug policy coordination. A pilot survey was created to enable assessment of their perceived importance and perceived application and administered to 36 stakeholders from peak Australian advisory bodies. The instrument was shown to have high internal reliability and high face validity. Application to the Australian context suggested that the eight principles differed in importance, and that the most important principles were 'accountability' and 'participation'. Application also revealed perceived strengths and weaknesses in coordination, most notably, an apparent need to increase 'accountability' for stakeholder actions. The instrument requires further assessment of reliability and validity. Yet, at least within the Australian context, it starts to unpack normative statements about coordination to show perceptions of what coordination is, areas where improvement may be warranted and the degree of contestation amongst different players. Further application of the good governance lens within this and other contexts will progress the assessment of a fundamental yet neglected policy process and foster a more nuanced consideration of the possibilities for coordination in the drug policy "soup". Copyright

  3. Freezing lines of colloidal Yukawa spheres. II. Local structure and characteristic lengths

    Energy Technology Data Exchange (ETDEWEB)

    Gapinski, Jacek, E-mail: gapinski@amu.edu.pl; Patkowski, Adam [Molecular Biophysics Division, Faculty of Physics, A. Mickiewicz University, Umultowska 85, 61-614 Poznań (Poland); NanoBioMedical Center, A. Mickiewicz University, Umultowska 85, 61-614 Poznań (Poland); Nägele, Gerhard [Institute of Complex Systems (ICS-3), Forschungszentrum Jülich, D-52425 Jülich (Germany)

    2014-09-28

    Using the Rogers-Young (RY) integral equation scheme for the static pair correlation functions combined with the liquid-phase Hansen-Verlet freezing rule, we study the generic behavior of the radial distribution function and static structure factor of monodisperse charge-stabilized suspensions with Yukawa-type repulsive particle interactions at freezing. In a related article, labeled Paper I [J. Gapinski, G. Nägele, and A. Patkowski, J. Chem. Phys. 136, 024507 (2012)], this hybrid method was used to determine two-parameter freezing lines for experimentally controllable parameters, characteristic of suspensions of charged silica spheres in dimethylformamide. A universal scaling of the RY radial distribution function maximum is shown to apply to the liquid-bcc and liquid-fcc segments of the universal freezing line. A thorough analysis is made of the behavior of characteristic distances and wavenumbers, next-neighbor particle coordination numbers, osmotic compressibility factor, and the Ravaché-Mountain-Streett minimum-maximum radial distribution function ratio.

  4. Vertical discretization with finite elements for a global hydrostatic model on the cubed sphere

    Science.gov (United States)

    Yi, Tae-Hyeong; Park, Ja-Rin

    2017-06-01

    A formulation of Galerkin finite element with basis-spline functions on a hybrid sigma-pressure coordinate is presented to discretize the vertical terms of global Eulerian hydrostatic equations employed in a numerical weather prediction system, which is horizontally discretized with high-order spectral elements on a cubed sphere grid. This replaces the vertical discretization of conventional central finite difference that is first-order accurate in non-uniform grids and causes numerical instability in advection-dominant flows. Therefore, a model remains in the framework of Galerkin finite elements for both the horizontal and vertical spatial terms. The basis-spline functions, obtained from the de-Boor algorithm, are employed to derive both the vertical derivative and integral operators, since Eulerian advection terms are involved. These operators are used to discretize the vertical terms of the prognostic and diagnostic equations. To verify the vertical discretization schemes and compare their performance, various two- and three-dimensional idealized cases and a hindcast case with full physics are performed in terms of accuracy and stability. It was shown that the vertical finite element with the cubic basis-spline function is more accurate and stable than that of the vertical finite difference, as indicated by faster residual convergence, fewer statistical errors, and reduction in computational mode. This leads to the general conclusion that the overall performance of a global hydrostatic model might be significantly improved with the vertical finite element.

  5. Coordination of Conditional Poisson Samples

    Directory of Open Access Journals (Sweden)

    Grafström Anton

    2015-12-01

    Full Text Available Sample coordination seeks to maximize or to minimize the overlap of two or more samples. The former is known as positive coordination, and the latter as negative coordination. Positive coordination is mainly used for estimation purposes and to reduce data collection costs. Negative coordination is mainly performed to diminish the response burden of the sampled units. Poisson sampling design with permanent random numbers provides an optimum coordination degree of two or more samples. The size of a Poisson sample is, however, random. Conditional Poisson (CP sampling is a modification of the classical Poisson sampling that produces a fixed-size πps sample. We introduce two methods to coordinate Conditional Poisson samples over time or simultaneously. The first one uses permanent random numbers and the list-sequential implementation of CP sampling. The second method uses a CP sample in the first selection and provides an approximate one in the second selection because the prescribed inclusion probabilities are not respected exactly. The methods are evaluated using the size of the expected sample overlap, and are compared with their competitors using Monte Carlo simulation. The new methods provide a good coordination degree of two samples, close to the performance of Poisson sampling with permanent random numbers.

  6. Coordinate-Free Rotation Operator.

    Science.gov (United States)

    Leubner, C.

    1979-01-01

    Suggests the use of a coordinate-free rotation operator for the teaching of rotations in Euclidean three space because of its twofold didactic advantage. Illustrates the potentialities of the coordinate-free rotation operator approach by a number of examples. (Author/GA)

  7. Coordinated Transportation: Problems and Promise?

    Science.gov (United States)

    Fickes, Michael

    1998-01-01

    Examines the legal, administrative, and logistical barriers that have prevented the wide acceptance of coordinating community and school transportation services and why these barriers may be breaking down. Two examples of successful implementation of coordinated transportation are examined: employing a single system to serve all transportation…

  8. Introduction to coordinated linear systems

    NARCIS (Netherlands)

    Kempker, P.L.

    2014-01-01

    This chapter serves as an introduction to the concepts of coordinated linear systems, in formal as well as intuitive terms. The concept of a coordinated linear system is introduced and formulated, and some basic properties are derived, providing both a motivaton and a formal basis for the following

  9. Transformation optics in orthogonal coordinates

    OpenAIRE

    Chen, Huanyang

    2008-01-01

    The author proposes the methodology of transformation optics in orthogonal coordinates to obtain the material parameters of the transformation media from the mapping in orthogonal coordinates. Several examples are given to show the applications of such a methodology by using the full-wave simulations.

  10. Bare coordination: the semantic shift

    NARCIS (Netherlands)

    de Swart, Henriette|info:eu-repo/dai/nl/074764187; Le Bruyn, Bert|info:eu-repo/dai/nl/30484912X

    2014-01-01

    This paper develops an analysis of the syntax-semantics interface of two types of split coordination structures. In the first type, two bare singular count nouns appear as arguments in a coordinated structure, as in bride and groom were happy. We call this the N&N construction. In the second type,

  11. Low Velocity Sphere Impact of a Borosilicate Glass

    Energy Technology Data Exchange (ETDEWEB)

    Morrissey, Timothy G [ORNL; Ferber, Mattison K [ORNL; Wereszczak, Andrew A [ORNL; Fox, Ethan E [ORNL

    2012-05-01

    This report summarizes US Army TARDEC sponsored work at Oak Ridge National Laboratory (ORNL) involving low velocity (< 30 m/s or < 65 mph) ball impact testing of Borofloat borosilicate glass, and is a follow-up to a similar study completed by the authors on Starphire soda-lime silicate glass last year. The response of the borosilicate glass to impact testing at different angles was also studied. The Borofloat glass was supplied by the US Army Research Laboratory and its tin-side was impacted or indented. The intent was to better understand low velocity impact response in the Borofloat. Seven sphere materials were used whose densities bracket that of rock: borosilicate glass, soda-lime silicate glass, silicon nitride, aluminum oxide, zirconium oxide, carbon steel, and a chrome steel. A gas gun or a ball-drop test setup was used to produce controlled velocity delivery of the spheres against the glass tile targets. Minimum impact velocities to initiate fracture in the Borofloat were measured and interpreted in context to the kinetic energy of impact and the elastic property mismatch between the seven sphere-Borofloat-target combinations. The primary observations from this low velocity (< 30 m/s or < 65 mph) testing were: (1) BS glass responded similarly to soda-lime silicate glass when spherically indented but quite differently under sphere impact conditions; (2) Frictional effects contributed to fracture initiation in BS glass when it spherically indented. This effect was also observed with soda-lime silicate glass; (3) The force necessary to initiate fracture in BS glass under spherical impact decreases with increasing elastic modulus of the sphere material. This trend is opposite to what was observed with soda-lime silicate glass. Friction cannot explain this trend and the authors do not have a legitimate explanation for it yet; (4) The force necessary to initiate contact-induced fracture is higher under dynamic conditions than under quasi-static conditions. That

  12. Formal Variability of Terms in the Sphere of Network Technologies

    Directory of Open Access Journals (Sweden)

    Roman Viktorovich Deniko

    2015-09-01

    Full Text Available The article addresses the problem of formal variability of terms in the sphere of network terminology in the Russian language. The research is based on data from the Internet communication in the sphere of network technologies. Such formal variability types as graphical, phonemic, word building and complex (graphic and phonetic, morphologic and accentual are discussed in this article. The authors reveal the reasons for graphic variability of foreign origin terms making up the international terminological fund. These reasons cover such aspects as the use of graphics of source language and recipient language; the presence or absence of hyphenation, etc. It is determined that the phonemic variants of terms appear as a result of oral or written borrowings. The existence of such variants is also connected with the stage of their adaptation in the Russian language after borrowing. In this case the variants are related with soft or hard pronunciation of consonants. There are also some cases of phonemic variability on the graphic level. The complex variability is regarded as a part of active processes taking place in the modern Russian language, and these processes involve both native and foreign origin terms. The particular attention is paid to the word-building variants – word-building affixes the variability of which is peculiar of network technologies. The results of the research show that the variability of professional units belonging to the network technologies sublanguage is caused by the active process of borrowing of specialpurpose vocabulary into the Russian language. The process is due to the intensification of intercultural communication in the professional spheres.

  13. Phylogeography by diffusion on a sphere: whole world phylogeography

    Directory of Open Access Journals (Sweden)

    Remco Bouckaert

    2016-09-01

    Full Text Available Background Techniques for reconstructing geographical history along a phylogeny can answer many questions of interest about the geographical origins of species. Bayesian models based on the assumption that taxa move through a diffusion process have found many applications. However, these methods rely on diffusion processes on a plane, and do not take the spherical nature of our planet in account. Performing an analysis that covers the whole world thus does not take in account the distortions caused by projections like the Mercator projection. Results In this paper, we introduce a Bayesian phylogeographical method based on diffusion on a sphere. When the area where taxa are sampled from is small, a sphere can be approximated by a plane and the model results in the same inferences as with models using diffusion on a plane. For taxa sampled from the whole world, we obtain substantial differences. We present an efficient algorithm for performing inference in a Markov Chain Monte Carlo (MCMC algorithm, and show applications to small and large samples areas. We compare results between planar and spherical diffusion in a simulation study and apply the method by inferring the origin of Hepatitis B based on sequences sampled from Eurasia and Africa. Conclusions We describe a framework for performing phylogeographical inference, which is suitable when the distortion introduced by map projections is large, but works well on a smaller scale as well. The framework allows sampling tips from regions, which is useful when the exact sample location is unknown, and placing prior information on locations of clades in the tree. The method is implemented in the GEO_SPHERE package in BEAST 2, which is open source licensed under LGPL and allows joint tree and geography inference under a wide range of models.

  14. Lazy orbits: An optimization problem on the sphere

    Science.gov (United States)

    Vincze, Csaba

    2018-01-01

    Non-transitive subgroups of the orthogonal group play an important role in the non-Euclidean geometry. If G is a closed subgroup in the orthogonal group such that the orbit of a single Euclidean unit vector does not cover the (Euclidean) unit sphere centered at the origin then there always exists a non-Euclidean Minkowski functional such that the elements of G preserve the Minkowskian length of vectors. In other words the Minkowski geometry is an alternative of the Euclidean geometry for the subgroup G. It is rich of isometries if G is "close enough" to the orthogonal group or at least to one of its transitive subgroups. The measure of non-transitivity is related to the Hausdorff distances of the orbits under the elements of G to the Euclidean sphere. Its maximum/minimum belongs to the so-called lazy/busy orbits, i.e. they are the solutions of an optimization problem on the Euclidean sphere. The extremal distances allow us to characterize the reducible/irreducible subgroups. We also formulate an upper and a lower bound for the ratio of the extremal distances. As another application of the analytic tools we introduce the rank of a closed non-transitive group G. We shall see that if G is of maximal rank then it is finite or reducible. Since the reducible and the finite subgroups form two natural prototypes of non-transitive subgroups, the rank seems to be a fundamental notion in their characterization. Closed, non-transitive groups of rank n - 1 will be also characterized. Using the general results we classify all their possible types in lower dimensional cases n = 2 , 3 and 4. Finally we present some applications of the results to the holonomy group of a metric linear connection on a connected Riemannian manifold.

  15. Equilibrium and nonequilibrium dynamics of soft sphere fluids.

    Science.gov (United States)

    Ding, Yajun; Mittal, Jeetain

    2015-07-14

    We use computer simulations to test the freezing-point scaling relationship between equilibrium transport coefficients (self-diffusivity, viscosity) and thermodynamic parameters for soft sphere fluids. The fluid particles interact via the inverse-power potential (IPP), and the particle softness is changed by modifying the exponent of the distance-dependent potential term. In the case of IPP fluids, density and temperature are not independent variables and can be combined to obtain a coupling parameter to define the thermodynamic state of the system. We find that the rescaled coupling parameter, based on its value at the freezing point, can approximately collapse the diffusivity and viscosity data for IPP fluids over a wide range of particle softness. Even though the collapse is far from perfect, the freezing-point scaling relationship provides a convenient and effective way to compare the structure and dynamics of fluid systems with different particle softness. We further show that an alternate scaling relationship based on two-body excess entropy can provide an almost perfect collapse of the diffusivity and viscosity data below the freezing transition. Next, we perform nonequilibrium molecular dynamics simulations to calculate the shear-dependent viscosity and to identify the distinct role of particle softness in underlying structural changes associated with rheological properties. Qualitatively, we find a similar shear-thinning behavior for IPP fluids with different particle softness, though softer particles exhibit stronger shear-thinning tendency. By investigating the distance and angle-dependent pair correlation functions in these systems, we find different structural features in the case of IPP fluids with hard-sphere like and softer particle interactions. Interestingly, shear-thinning in hard-sphere like fluids is accompanied by enhanced translational order, whereas softer fluids exhibit loss of order with shear. Our results provide a systematic evaluation

  16. Increased coordination in public transport – which mechanisms are available?

    DEFF Research Database (Denmark)

    Sørensen, Claus Hedegaard; Longva, Frode

    2011-01-01

    and suggested to increase coordination between core stakeholders within passenger railway services and bus services. Four distinctive mechanisms of coordination are suggested, namely organisational coordination, contractual coordination, partnership coordination and discursive coordination. Each coordination...

  17. Archimedes' principle in general coordinates

    International Nuclear Information System (INIS)

    Ridgely, Charles T

    2010-01-01

    Archimedes' principle is well known to state that a body submerged in a fluid is buoyed up by a force equal to the weight of the fluid displaced by the body. Herein, Archimedes' principle is derived from first principles by using conservation of the stress-energy-momentum tensor in general coordinates. The resulting expression for the force is applied in Schwarzschild coordinates and in rotating coordinates. Using Schwarzschild coordinates for the case of a spherical mass suspended within a perfect fluid leads to the familiar expression of Archimedes' principle. Using rotating coordinates produces an expression for a centrifugal buoyancy force that agrees with accepted theory. It is then argued that Archimedes' principle ought to be applicable to non-gravitational phenomena, as well. Conservation of the energy-momentum tensor is then applied to electromagnetic phenomena. It is shown that a charged body submerged in a charged medium experiences a buoyancy force in accordance with an electromagnetic analogue of Archimedes' principle.

  18. Archimedes' principle in general coordinates

    Science.gov (United States)

    Ridgely, Charles T.

    2010-05-01

    Archimedes' principle is well known to state that a body submerged in a fluid is buoyed up by a force equal to the weight of the fluid displaced by the body. Herein, Archimedes' principle is derived from first principles by using conservation of the stress-energy-momentum tensor in general coordinates. The resulting expression for the force is applied in Schwarzschild coordinates and in rotating coordinates. Using Schwarzschild coordinates for the case of a spherical mass suspended within a perfect fluid leads to the familiar expression of Archimedes' principle. Using rotating coordinates produces an expression for a centrifugal buoyancy force that agrees with accepted theory. It is then argued that Archimedes' principle ought to be applicable to non-gravitational phenomena, as well. Conservation of the energy-momentum tensor is then applied to electromagnetic phenomena. It is shown that a charged body submerged in a charged medium experiences a buoyancy force in accordance with an electromagnetic analogue of Archimedes' principle.

  19. Extinction in finite perfect crystals: Case of a sphere

    International Nuclear Information System (INIS)

    Al Haddad, M.; Becker, P.

    1990-01-01

    The extinction factor in finite perfect crystals is calculated from pure dynamical theory. In particular, a detailed solution is proposed for a sphere, in which case the extinction factor depends on the Bragg angle θ and the parameter (R/Λ), where R is the radius of the crystal and Λ the extinction length. An approximate solution based on the Laue geometry is proposed and corrections to take care of the complex boundary conditions are presented. An expression easily usable in refinement programs is proposed that fits the exact value to better than 1%. (orig.)

  20. Dynamical study of a polydisperse hard-sphere system

    KAUST Repository

    Nogawa, Tomoaki

    2010-08-10

    We study the interplay between the fluid-crystal transition and the glass transition of elastic sphere system with polydispersity using nonequilibrium molecular dynamics simulations. It is found that the end point of the crystal-fluid transition line, which corresponds to the critical polydispersity above which the crystal state is unstable, is on the glass transition line. This means that crystal and fluid states at the melting point becomes less distinguishable as polydispersity increases and finally they become identical state, i.e., marginal glass state, at critical polydispersity. © 2010 The American Physical Society.

  1. WebSphere Application Server Step by Step

    CERN Document Server

    Cline, Owen; Van Sickel, Peter

    2012-01-01

    WebSphere Application Server (WAS) is complex and multifaceted middleware used by huge enterprises as well as small businesses. In this book, the authors do an excellent job of covering the many aspects of the software. While other books merely cover installation and configuration, this book goes beyond that to cover the critical verification and management process to ensure a successful installation and implementation. It also addresses all of the different packages-from Express to Network-so that no matter what size your company is, you will be able to successfully implement WAS V6. To de

  2. Charging changes contact composition in binary sphere packings.

    Science.gov (United States)

    Schella, André; Weis, Simon; Schröter, Matthias

    2017-06-01

    Equal volume mixtures of small and large polytetrafluorethylene spheres are shaken in an atmosphere of controlled humidity which allows one to also control their tribocharging. We find that the contact numbers are charge dependent: As the charge density of the beads increases, the number of same-type contacts decreases and the number of opposite-type contacts increases. This change is not caused by a global segregation of the sample. Hence, tribocharging can be a way to tune the local composition of a granular material.

  3. Magnetic and Optical Properties of Submicron-Size Hollow Spheres

    Directory of Open Access Journals (Sweden)

    Hirofumi Yoshikawa

    2010-02-01

    Full Text Available Magnetic hollow spheres with a controlled diameter and shell thickness have emerged as an important class of magnetic nanomaterials. The confined hollow geometry and pronouncedly curved surfaces induce unique physical properties different from those of flat thin films and solid counterparts. In this paper, we focus on recent progress on submicron-size spherical hollow magnets (e.g., cobalt- and iron-based materials, and discuss the effects of the hollow shape and the submicron size on magnetic and optical properties.

  4. Photoneutron spectrum measured with Bonner Spheres in Planetary method mode

    Energy Technology Data Exchange (ETDEWEB)

    Benites R, J. [Centro Estatal de Cancerologia de Nayarit, Servicio de Seguridad Radiologica, Calz. de la Cruz 118 Sur, 63000 Tepic, Nayarit (Mexico); Vega C, H. R. [Universidad Autonoma de Zacatecas, Unidad Academica de Estudios Nucleares, Apdo. Postal 336, 98000 Zacatecas (Mexico); Velazquez F, J., E-mail: jlbenitesr@prodigy.net.mx [Universidad Autonoma de Nayarit, Posgrado en Ciencias Biologico Agropecuarias, Carretera Tepic-Compostela Km 9, 63780 Jalisco-Nayarit (Mexico)

    2012-10-15

    We measured the spectrum of photoneutrons at 100 cm isocenter linear accelerator (Linac) Varian ix operating at 15 MV Bremsstrahlung mode. In this process was used a radiation field of 20 x 20 cm{sup 2} at a depth of 5 cm in a solid water phantom with dimensions of 30 x 30 x 15 cm{sup 3}. The measurement was performed with a system using it Bonner Spheres spectrometric method Planetary mode. As neutron detector of the spectrometer is used thermoluminescent dosimeters pairs of type 600 and 700. (Author)

  5. Templated Sphere Phase Liquid Crystals for Tunable Random Lasing

    Directory of Open Access Journals (Sweden)

    Ziping Chen

    2017-11-01

    Full Text Available A sphere phase liquid crystal (SPLC composed of three-dimensional twist structures with disclinations among them exists between isotropic phase and blue phase in a very narrow temperature range, about several degrees centigrade. A low concentration polymer template is applied to improve the thermal stability of SPLCs and broadens the temperature range to more than 448 K. By template processing, a wavelength tunable random lasing is demonstrated with dye doped SPLC. With different polymer concentrations, the reconstructed SPLC random lasing may achieve more than 40 nm wavelength continuous shifting by electric field modulation.

  6. Lie theory and control systems defined on spheres

    Science.gov (United States)

    Brockett, R. W.

    1972-01-01

    It is shown that in constructing a theory for the most elementary class of control problems defined on spheres, some results from the Lie theory play a natural role. To understand controllability, optimal control, and certain properties of stochastic equations, Lie theoretic ideas are needed. The framework considered here is the most natural departure from the usual linear system/vector space problems which have dominated control systems literature. For this reason results are compared with those previously available for the finite dimensional vector space case.

  7. Enterprise Coordination on the Internet

    Directory of Open Access Journals (Sweden)

    Charles Petrie

    2011-02-01

    Full Text Available Enterprises are now connected internally and externally to other Enterprises via the Internet in ways that are increasingly difficult to manage, especially as these interconnections become more dynamic. Current methods of coordinating the effects of change as they propagate through these networks of connections are not likely to scale. What is needed is a new paradigm for how the Internet supports such coordination. Indeed, the Internet should and could provide fundamental coordination functions that are missing today. In this paper, we describe how such a “Coordinated Internet” would work (this paper is an expanded version of [1]. The key functionality of a Coordinated Internet would be that the Internet actively watches what people do (analogous to search completion on desktops today, correlates these activities, and actively notifies people when and how their current tasks affect and are affected by the activities of other people. This would be accomplished by standard coordination functions implemented as a common Internet layer that can be used as a utility by more specialized applications. Such a Coordinated Internet would revolutionize enterprise management, for all enterprises, large and small, corporate and personal. For example, static workflows would become obsolete for all but the the most routine processes. Some solutions provide existence proofs of such a coordination substrate, such as the Redux solution in concurrent engineering, which we describe herein. However, foundational research remains to be done in the new field of Coordination Engineering in order to reach the goal of a future Internet in which coordination functions are fundamental.

  8. Association of coordination compounds of cobalt and molybdenum in solution

    Energy Technology Data Exchange (ETDEWEB)

    Kudryavtsev, A.B.; Sapunov, V.N. (Moskovskij Lesotekhnicheskij Inst. (USSR))

    1981-01-01

    Association of acetylacetonates Co(2) and MoO/sub 2/(6) in CHCl/sub 3/ is studied using the PMR method. In the absence of hydroxyl-containing substances the compounds form labile complex with the bond through molybdenyl oxygen. Equilibrium constant at 23 deg is equal to 2.2+-0.6 l/mol. Alcohol introduction results in partial dischelating of MoO/sub 2/(Acac)/sub 2/ and formation of mixed acetylacetonate-alcoholate complex of molybdenyl. Equilibrium constant of the reaction at 23 deg constitutes 0.14+-0.02 l/mol. Under the conditions Co(2) acetylacetonate is introduced into the first coordination sphere of MoO/sub 2/, the splitting off of the second acetylacetonate ligand and formation of strong associate which might condition the decrease of catalytic activity of mixed cobaltmolybdenum catalysts of epoxidation.

  9. Surface coordination polymerization of ethylene by hydrozirconation-immobilized metallocene.

    Science.gov (United States)

    Zheng, Jun; Wang, Yanhui; Ye, Lin; Lin, Yichao; Tang, Tao; Zhang, Jidong

    2014-07-01

    Hydrozirconation on vinyl-terminated substrates (silicon wafer and nanosilica sphere) is employed as an efficient way for immobilization of zirconocene catalyst through Zr-C bonds, which is applied in surface coordination ethylene polymerization producing surface-tethered polyethylene (PE). The formation of Zr-C σ bond induced by hydrozirconation provides an initiator precursor for growing a layer of PE covalently linked onto substrates. The results from SEM, AFM, and TEM show that the surface polymerization is controlled by hydrozirconation. Surface pattern or core-shell structure with crystalline PE coating can be formed, when silicon wafer is selectively functionalized with vinyl-groups or vinyl-modified nanosilica is applied. It is believed that hydrozirconation for the synthesis of zirconocene initiator can be a versatile route to prepare polyolefin hybrid materials. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Experimental study and DEM simulation of granular flow through a new sphere discharge valve

    International Nuclear Information System (INIS)

    Zhang He; Li Tianjin; Huang Zhiyong; Gao Zhi; Qi Weiwei; Bo Hanliang

    2015-01-01

    Experiments and DEM simulation have been conducted to investigate the granular flow through a new type of sphere discharge valve. The new sphere discharge valve was based on the principle of angle of repose. The glass sphere was used in the granular discharge experiments. Experimental results showed that the relation between the averaging sphere discharge mass flow rate and the stroke of the sphere discharge valve were consisted of three zones, i.e. the idle stroke zone, linearly zone and orifice restriction zone. The Beverloo's law was suitable for the granular flow through multi-orifices in the orifice restriction zone. The variation of averaging sphere discharge mass flow rate with the stroke of the sphere discharge valve was described by Beverloo's law with the modification based on the stroke of the sphere discharge valve. DEM simulation results showed that the drained angle of repose during granular flow in the sphere storage vessel remained 23 degrees with different stroke of the sphere discharge valve. (authors)

  11. Comparison of Flow Characteristics of Different Sphere Geometries Under the Free Surface Effect

    Directory of Open Access Journals (Sweden)

    Sahin B.

    2013-04-01

    Full Text Available Comparison of the experimental results of turbulent flow structures between a smooth sphere and a sphere with a vent hole, roughened, and o-ring is presented in the presence of a free-surface. Dye visualization and particle image velocimetry (PIV techniques were performed to examine effects of passive control methods on the sphere wake for Reynolds number Re = 5000 based on the sphere diameter with a 42.5mm in an open water channel. Instantaneous and time-averaged flow patterns in the wake region of the sphere were examined from point of flow physics for the different sphere locations in the range of 0≤h/D≤2.0 where h was the space between the top point of the sphere and the free surface. The ratio of ventilation hole to sphere diameter was 0.15, o-ring was located at 55° with a 2 mm from front stagnation point of the sphere and roughened surface was formed by means of totally 410 circular holes with a 3 mm diameter and around 2 mm depth in an equilateral triangle arrangement. The flow characteristics of instantaneous velocity vectors, vorticity contours, time-averaged streamline patterns, Reynolds stress correlations and streamwise and cross-stream velocity fluctuations for both the smooth and passively controlled sphere were interpreted.

  12. Passive control of flow structure interaction between a sphere and free-surface

    Directory of Open Access Journals (Sweden)

    Akilli Huseyin

    2012-04-01

    Full Text Available Flow characteristics for both a smooth and a vented sphere such as velocity vectors, patterns of streamlines, vorticity contours, stream-wise fluctuations, cross-stream velocity fluctuations and Reynolds stress correlations between a sphere and free-surface for various submerged ratio at Re =5,000 are studied by using dye visualization and the particle image velocimetry technique. Passive control of flow structure interaction between sphere and free surface was examined by using a modified geometry which has a 15% sphere diameter hole passing through the sphere equator. Both of the spheres were separately placed beneath the free surface with different positions from touching to the free surface to two sphere diameters below the free surface. It is demonstrated that reattachment point of the separated flow to the free surface varies for both of the sphere cases as the sphere position alters vertically through the water flow while the flow structure for the vented sphere occurs considerably symmetrical due to forming of a pair of counter-rotating ring vortices.

  13. Heating-induced inner-sphere substitution and reduction-oxidation reactions of the solid phenanthroline containing cobalt (2) and cobalt (3) complexes

    International Nuclear Information System (INIS)

    Palade, D.M.

    1996-01-01

    The results of the differential thermal and thermogravimetric analyses of solid phenanthroline-containing complexes of cobalt (2) and cobalt (3) in the atmosphere of the air have been analyzed. Mechanism of redox reactions occurring when cobalt (3) complexes are heated has been discussed. It is shown that some of gaseous products of the redox processes appear as a result of secondary reactions and not the processes of the ligands oxidation by Co 3+ . The influence of certain inner-sphere and coordinated anions (of I, inclusively) on cobalt (3) complexes behaviour during heating has been considered

  14. Coordination chemistry of homoleptic actinide(IV)-thiocyanate complexes

    Energy Technology Data Exchange (ETDEWEB)

    Carter, Tyler J.; Wilson, Richard E. [Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, IL (United States)

    2015-10-26

    The synthesis, X-ray crystal structure, vibrational and optical spectroscopy for the eight-coordinate thiocyanate compounds, [Et{sub 4}N]{sub 4}[Pu{sup IV}(NCS){sub 8}], [Et{sub 4}N]{sub 4}[Th{sup IV}(NCS){sub 8}], and [Et{sub 4}N]{sub 4}[Ce{sup III}(NCS){sub 7}(H{sub 2}O)] are reported. Thiocyanate was found to rapidly reduce plutonium to Pu{sup III} in acidic solutions (pH<1) in the presence of NCS{sup -}. The optical spectrum of [Et{sub 4}N][SCN] containing Pu{sup III} solution was indistinguishable from that of aquated Pu{sup III} suggesting that inner-sphere complexation with [Et{sub 4}N][SCN] does not occur in water. However, upon concentration, the homoleptic thiocyanate complex [Et{sub 4}N]{sub 4}[Pu{sup IV}(NCS){sub 8}] was crystallized when a large excess of [Et{sub 4}N][NCS] was present. This compound, along with its U{sup IV} analogue, maintains inner-sphere thiocyanate coordination in acetonitrile based on the observation of intense ligand-to-metal charge-transfer bands. Spectroscopic and crystallographic data do not support the interaction of the metal orbitals with the ligand π system, but support an enhanced An{sup IV}-NCS interaction, as the Lewis acidity of the metal ion increases from Th to Pu. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  15. Keep Meaning in Conversational Coordination

    Directory of Open Access Journals (Sweden)

    Elena Clare Cuffari

    2014-12-01

    Full Text Available Coordination is a widely employed term across recent quantitative and qualitative approaches to intersubjectivity, particularly approaches that give embodiment and enaction central explanatory roles. With a focus on linguistic and bodily coordination in conversational contexts, I review the operational meaning of coordination in recent empirical research and related theorizing of embodied intersubjectivity. This discussion articulates what must be involved in treating linguistic meaning as dynamic processes of coordination. The coordination approach presents languaging as a set of dynamic self-organizing processes and actions on multiple timescales and across multiple modalities that come about and work in certain domains (those jointly constructed in social, interactive, high-order sense-making. These processes go beyond meaning at the level that is available to first-person experience. I take one crucial consequence of this to be the ubiquitously moral nature of languaging with others. Languaging coordinates experience, among other levels of behavior and event. Ethical effort is called for by the automatic autonomy-influencing forces of languaging as coordination.

  16. Axial acoustic radiation force on a sphere in Gaussian field

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Rongrong; Liu, Xiaozhou, E-mail: xzliu@nju.edu.cn; Gong, Xiufen [Key Laboratory of Modern Acoustics, Institute of Acoustics and School of Physics, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093 (China)

    2015-10-28

    Based on the finite series method, the acoustical radiation force resulting from a Gaussian beam incident on a spherical object is investigated analytically. When the position of the particles deviating from the center of the beam, the Gaussian beam is expanded as a spherical function at the center of the particles and the expanded coefficients of the Gaussian beam is calculated. The analytical expression of the acoustic radiation force on spherical particles deviating from the Gaussian beam center is deduced. The acoustic radiation force affected by the acoustic frequency and the offset distance from the Gaussian beam center is investigated. Results have been presented for Gaussian beams with different wavelengths and it has been shown that the interaction of a Gaussian beam with a sphere can result in attractive axial force under specific operational conditions. Results indicate the capability of manipulating and separating spherical spheres based on their mechanical and acoustical properties, the results provided here may provide a theoretical basis for development of single-beam acoustical tweezers.

  17. Artificial black opal fabricated from nanoporous carbon spheres.

    Science.gov (United States)

    Yamada, Yuri; Ishii, Masahiko; Nakamura, Tadashi; Yano, Kazuhisa

    2010-06-15

    A nanocasting method via chemical vapor deposition of acetonitrile was successfully employed to fabricate porous carbon colloidal crystal using colloidal crystal from monodispersed mesoporous silica spheres (MMSS) as a sacrificial scaffold. The mesostructure as well as periodic arrays within (111) plane of MMSS were replicated for the carbon colloidal crystal (black opal) with the length scale in the centimeter range. Brilliant iridescent colors were clearly observed for the first time on the black carbon colloidal crystal fabricated from porous carbon spheres, and they changed dramatically in accordance with the observation angle, like natural black opals. Reflection spectra measurements based on 2D surface diffraction and Bragg diffraction in the mirror mode were conducted for the fabricated carbon periodic arrays. The periodicity in the (111) plane as well as in the direction perpendicular to the (111) plane of the colloidal crystal was evaluated by comparing the results obtained from these two measurements. It was found that the periodicity in the direction perpendicular to the (111) surface is not high for the obtained black carbon opal. On the other hand, the relationship between the incident angles and the peak wavelengths of the reflection spectra, collected in the condition where the incident light and the reflected light pass through in the same direction, is governed by an approximation based on 2D surface diffraction. The results imply that the origin of the iridescent colors on the fabricated black carbon opal is derived from the periodicity not in the direction perpendicular to the (111) plane but within the (111) plane.

  18. Emotional Sphere in Elderly People: Age and Regional Differences

    Directory of Open Access Journals (Sweden)

    Shagidaeva A.B.

    2014-08-01

    Full Text Available We present a study of the negative aspects of the emotional sphere in elderly man: depression and loneliness. Empirical research was carried out in Moscow and Grozny involving elderly people living in families and in geriatric centers (201 subjects, as well as with middle-aged people (132 subjects. We used the following methods: Zung differential diagnosis of depressive states inventory in adaptation by T.I. Balachova and D. Russell and M. Ferguson Loneliness scale (UKL in adaptation by N.E. Vodopyanova. It is shown that at the present stage of development of society, middle-aged people already have quite high level of depression and pronounced sense of loneliness. We confirmed the hypothesis that the preservation of the negative aspects of the emotional sphere in elderly people is less dependent on the conditions of life at the micro level (family or gerontology center and more dependent from the living conditions at the macro level (socio-economic situation in the region. In Grozny, a city of more complex socio-economic situation, negative emotional states are more pronounced than in Moscow.

  19. The Cognitive Modeling of Development of Tourism Sphere

    Directory of Open Access Journals (Sweden)

    Los Vita O.

    2017-10-01

    Full Text Available The article explores the inter-sectoral interaction in the tourism sphere, which is based on the application of cognitive modeling. The authors consider the interaction of powers (political environment, tourism (tourism business, business (socio-economic environment and ecology (ecological environment. The ecology is identified as the exceptional decisive factor in creating an enabling environment for the development of the market for tourism services. A static analysis of the cognitive model was carried out, which revealed 624 contours, of which 473 were stabilizing and 151 were destabilizing. Based on results of the systemic characterizations of the cognitive model, it was found that the interaction between the two sectors, tourism (tourist business and business (socio-economic environment needs special attention. A dynamic analysis of the built cognitive model was carried out using the method of impulse processes that helped to generate alternative scenarios for the development of tourism services. As a result, it has been found that increased investment in restaurant and hotel activities facilitates the increase in the level of development of market for tourism services for one period earlier than the increase in financing tourism sphere from the budget.

  20. Ligand-mediated adhesive mechanics of two static, deformed spheres.

    Science.gov (United States)

    Sircar, Sarthok; Nguyen, Giang; Kotousov, Andrei; Roberts, Anthony J

    2016-10-01

    A self-consistent model is developed to investigate attachment/detachment kinetics of two static, deformable microspheres with irregular surface and coated with flexible binding ligands. The model highlights how the microscale binding kinetics of these ligands as well as the attractive/repulsive potential of the charged surface affects the macroscale static deformed configuration of the spheres. It is shown that in the limit of smooth, neutrally charged surface (i.e., the dimensionless inverse Debye length, [Formula: see text]), interacting via elastic binders (i.e., the dimensionless stiffness coefficient, [Formula: see text]) the adhesion mechanics approaches the regime of application of the JKR theory, and in this particular limit, the contact radius, R c , scales with the particle radius, R, according to the scaling law, [Formula: see text]. We show that static, deformed, highly charged, ligand-coated surface of micro-spheres exhibit strong adhesion. Normal stress distribution within the contact area adjusts with the binder stiffness coefficient, from a maximum at the center to a maximum at the periphery of the region. Although reported in some in vitro experiments involving particle adhesion, until now a physical interpretation for this variation of the stress distribution for deformable, charged, ligand-coated microspheres is missing. Surface roughness results in a diminished adhesion with a distinct reduction in the pull-off force, larger separation gap, weaker normal stress and limited area of adhesion. These results are in agreement with the published experimental findings.

  1. Stability of barotropic vortex strip on a rotating sphere.

    Science.gov (United States)

    Sohn, Sung-Ik; Sakajo, Takashi; Kim, Sun-Chul

    2018-02-01

    We study the stability of a barotropic vortex strip on a rotating sphere, as a simple model of jet streams. The flow is approximated by a piecewise-continuous vorticity distribution by zonal bands of uniform vorticity. The linear stability analysis shows that the vortex strip becomes stable as the strip widens or the rotation speed increases. When the vorticity constants in the upper and the lower regions of the vortex strip have the same positive value, the inner flow region of the vortex strip becomes the most unstable. However, when the upper and the lower vorticity constants in the polar regions have different signs, a complex pattern of instability is found, depending on the wavenumber of perturbations, and interestingly, a boundary far away from the vortex strip can be unstable. We also compute the nonlinear evolution of the vortex strip on the rotating sphere and compare with the linear stability analysis. When the width of the vortex strip is small, we observe a good agreement in the growth rate of perturbation at an early time, and the eigenvector corresponding to the unstable eigenvalue coincides with the most unstable part of the flow. We demonstrate that a large structure of rolling-up vortex cores appears in the vortex strip after a long-time evolution. Furthermore, the geophysical relevance of the model to jet streams of Jupiter, Saturn and Earth is examined.

  2. Pair Interaction of Catalytical Sphere Dimers in Chemically Active Media

    Directory of Open Access Journals (Sweden)

    Jing-Min Shi

    2018-01-01

    Full Text Available We study the pair dynamics of two self-propelled sphere dimers in the chemically active medium in which a cubic autocatalytic chemical reaction takes place. Concentration gradient around the dimer, created by reactions occurring on the catalytic sphere surface and responsible for the self-propulsion, is greatly influenced by the chemical activities of the environment. Consequently, the pair dynamics of two dimers mediated by the concentration field are affected. In the particle-based mesoscopic simulation, we combine molecular dynamics (MD for potential interactions and reactive multiparticle collision dynamics (RMPC for solvent flow and bulk reactions. Our results indicate three different configurations between a pair of dimers after the collision, i.e., two possible scenarios of bound dimer pairs and one unbound dimer pair. A phase diagram is sketched as a function of the rate coefficients of the environment reactions. Since the pair interactions are the basic elements of larger scale systems, we believe the results may shed light on the understanding of the collective dynamics.

  3. Two-Loop Scattering Amplitudes from the Riemann Sphere

    CERN Document Server

    Geyer, Yvonne; Monteiro, Ricardo; Tourkine, Piotr

    2016-01-01

    The scattering equations give striking formulae for massless scattering amplitudes at tree level and, as shown recently, at one loop. The progress at loop level was based on ambitwistor string theory, which naturally yields the scattering equations. We proposed that, for ambitwistor strings, the standard loop expansion in terms of the genus of the worldsheet is equivalent to an expansion in terms of nodes of a Riemann sphere, with the nodes carrying the loop momenta. In this paper, we show how to obtain two-loop scattering equations with the correct factorization properties. We adapt genus-two integrands from the ambitwistor string to the nodal Riemann sphere and show that these yield correct answers, by matching standard results for the four-point two-loop amplitudes of maximal supergravity and super-Yang-Mills theory. In the Yang-Mills case, this requires the loop analogue of the Parke-Taylor factor carrying the colour dependence, which includes non-planar contributions.

  4. Crystallization and dynamical arrest of attractive hard spheres.

    Science.gov (United States)

    Babu, Sujin; Gimel, Jean-Christophe; Nicolai, Taco

    2009-02-14

    Crystallization of hard spheres interacting with a square well potential was investigated by numerical simulations using so-called Brownian cluster dynamics. The phase diagram was determined over a broad range of volume fractions. The crystallization rate was studied as a function of the interaction strength expressed in terms of the second virial coefficient. For volume fractions below about 0.3 the rate was found to increase abruptly with increasing attraction at the binodal of the metastable liquid-liquid phase separation. The rate increased until a maximum was reached after which it decreased with a power law dependence on the second virial coefficient. Above a critical percolation concentration, a transient system spanning network of connected particles was formed. Crystals were formed initially as part of the network, but eventually crystallization led to the breakup of the network. The lifetime of the transient gels increased very rapidly over a small range of interaction energies. Weak attraction destabilized the so-called repulsive crystals formed in pure hard sphere systems and shifted the coexistence line to higher volume fractions. Stronger attraction led to the formation of a denser, so-called attractive, crystalline phase. Nucleation of attractive crystals in the repulsive crystalline phase was observed close to the transition.

  5. Diverse assembly behavior in colloidal Platonic polyhedral sphere clusters

    Science.gov (United States)

    Marson, Ryan; Teich, Erin; Dshemuchadse, Julia; Glotzer, Sharon; Larson, Ronald

    We simulate the self-assembly of colloidal ``polyhedral sphere clusters (PSCs)'', which consist of equal-sized spheres placed at the vertices of a polyhedron such that they just touch along each edge. These colloidal building blocks have recently been experimentally fabricated; here we predict crystal structures that would appear in the phase diagram of resulting particle assemblies. We use Brownian dynamics (BD) simulations of rigid body clusters performed in the open-source GPU-based HOOMD-Blue particle simulation package to show the assembly behavior of the 5 Platonic PSCs. The simulations contain as many as 4096 individual polyhedra, across over 30 different densities per cluster geometry, with some ordered phases possessing unit cells with 20 or more particles. We observe the formation of not only traditional cubic structures such as BCC and FCC, but also more complex phases having structure symmetries with Pearson symbols - hP7, cP20, cI2, mP6, and hR3. The observations reported here will serve as a guide for future colloidal assembly experiments using an expanded library of PSCs, consisting of other regular and irregular polyhedra, allowing researchers to target specific arrangements of ``halo'' and ``core'' particles for technologically relevant applications including photonics and structural color.

  6. Supercooled liquid dynamics for the charged hard-sphere model

    International Nuclear Information System (INIS)

    Lai, S.K.; Chang, S.Y.

    1994-08-01

    We study the dynamics of supercooled liquid and the liquid-glass transition by applying the mode coupling theory to the charged hard-sphere model. By exploiting the two independent parameters inherent in the charged hard-sphere system we examine structurally the subtle and competitive role played by the short-range hard-core correlation and the long-range Coulomb tail. It is found in this work that the long-range Coulombic charge factor effect is generally a less effective contribution to structure when the plasma parameter is less than 500 and becomes dominant when it is greater thereof. To extend our understanding of the supercooled liquid and the liquid-glass transition, an attempt is made to calculate and to give physical relevance to the mode-coupling parameters which are frequently used as mere fitting parameters in analysis of experiments on supercooled liquid systems. This latter information enables us to discuss the possible application of the model to a realistic system. (author). 22 refs, 4 figs

  7. One-loop amplitudes on the Riemann sphere

    CERN Document Server

    Geyer, Yvonne; Monteiro, Ricardo; Tourkine, Piotr

    2016-01-01

    The scattering equations provide a powerful framework for the study of scattering amplitudes in a variety of theories. Their derivation from ambitwistor string theory led to proposals for formulae at one loop on a torus for 10 dimensional supergravity, and we recently showed how these can be reduced to the Riemann sphere and checked in simple cases. We also proposed analogous formulae for other theories including maximal super-Yang-Mills theory and supergravity in other dimensions at one loop. We give further details of these results and extend them in two directions. Firstly, we propose new formulae for the one-loop integrands of Yang-Mills theory and gravity in the absence of supersymmetry. These follow from the identification of the states running in the loop as expressed in the ambitwistor-string correlator. Secondly, we give a systematic proof of the non-supersymmetric formulae using the worldsheet factorisation properties of the nodal Riemann sphere underlying the scattering equations at one loop. Our f...

  8. Stability of barotropic vortex strip on a rotating sphere

    Science.gov (United States)

    Sohn, Sung-Ik; Sakajo, Takashi; Kim, Sun-Chul

    2018-02-01

    We study the stability of a barotropic vortex strip on a rotating sphere, as a simple model of jet streams. The flow is approximated by a piecewise-continuous vorticity distribution by zonal bands of uniform vorticity. The linear stability analysis shows that the vortex strip becomes stable as the strip widens or the rotation speed increases. When the vorticity constants in the upper and the lower regions of the vortex strip have the same positive value, the inner flow region of the vortex strip becomes the most unstable. However, when the upper and the lower vorticity constants in the polar regions have different signs, a complex pattern of instability is found, depending on the wavenumber of perturbations, and interestingly, a boundary far away from the vortex strip can be unstable. We also compute the nonlinear evolution of the vortex strip on the rotating sphere and compare with the linear stability analysis. When the width of the vortex strip is small, we observe a good agreement in the growth rate of perturbation at an early time, and the eigenvector corresponding to the unstable eigenvalue coincides with the most unstable part of the flow. We demonstrate that a large structure of rolling-up vortex cores appears in the vortex strip after a long-time evolution. Furthermore, the geophysical relevance of the model to jet streams of Jupiter, Saturn and Earth is examined.

  9. Energy dissipation in head-on collisions of spheres

    International Nuclear Information System (INIS)

    Krijt, S; Tielens, A G G M; Güttler, C; Heißelmann, D; Dominik, C

    2013-01-01

    Collisions between spheres are a common ingredient in a variety of scientific problems, and the coefficient of restitution (COR) is a key parameter to describe their outcome. We present a new collision model that treats adhesion and viscoelasticity self-consistently, while energy losses arising from plastic deformation are assumed to be additive. Results show that viscoelasticity can significantly increase the energy that is dissipated in a collision, enhancing the sticking velocity. Furthermore, collisions well above the sticking velocity remain dissipative. We systemically compare the model to a large and unbiased set of published laboratory experiments to show its general applicability. The model is well capable of reproducing the important relation between impact velocity and COR as measured in the experiments, covering a wide range of materials, particle sizes, and collision velocities. Furthermore, the fitting parameters from those curves provide physical parameters such as the surface energy, yield strength, and characteristic viscous relaxation time. Our results show that all three aspects—adhesion, viscoelastic dissipation and plastic deformation—are required for a proper description of the kinetic energy losses in sphere collisions. (paper)

  10. Evaluation framework for K-best sphere decoders

    KAUST Repository

    Shen, Chungan

    2010-08-01

    While Maximum-Likelihood (ML) is the optimum decoding scheme for most communication scenarios, practical implementation difficulties limit its use, especially for Multiple Input Multiple Output (MIMO) systems with a large number of transmit or receive antennas. Tree-searching type decoder structures such as Sphere decoder and K-best decoder present an interesting trade-off between complexity and performance. Many algorithmic developments and VLSI implementations have been reported in literature with widely varying performance to area and power metrics. In this semi-tutorial paper we present a holistic view of different Sphere decoding techniques and K-best decoding techniques, identifying the key algorithmic and implementation trade-offs. We establish a consistent benchmark framework to investigate and compare the delay cost, power cost, and power-delay-product cost incurred by each method. Finally, using the framework, we propose and analyze a novel architecture and compare that to other published approaches. Our goal is to explicitly elucidate the overall advantages and disadvantages of each proposed algorithms in one coherent framework. © 2010 World Scientific Publishing Company.

  11. Protection of qubit-coherence on a Bloch sphere

    Science.gov (United States)

    Zong, Xiao-Lan; Chu, Wen-Jing; Yang, Ming; Yang, Qing; Cao, Zhuo-Liang

    2017-07-01

    Single qubit pure state is a fundamental resource in quantum information and quantum computation. Therefore, it is of great importance to protect the coherence of single qubits against decoherence. In this letter, we demonstrate that decoherence caused by spontaneous emission can be effectively suppressed by adding a universal static external field. In order to have an intuitive view to the protection effects and its physical mechanisms, we study the coherence evolution of a single qubit on a Bloch sphere. We can clearly see that different external resonant drivings can rotate the Bloch vector around different axes, and the steady-state solution of the master equation (under protection) are visualized on the Bloch sphere. Furthermore, the frequency detuning between the qubit system and the driving is taken into account, and the results show that our protection scheme still works fine in the detuned cases and the smaller the detuning is, the better the protection effect is. In addition, this protocol can protect the coherence of single qubit states with a wide range of driving parameters, and help people to design simple coherence protection schemes for qubit states. The simplicity and the abundance of the current scheme may warrant its experimental realization.

  12. Workshop for Coordinators/Assistants/Alternate Coordinators of IAEA Projects

    International Nuclear Information System (INIS)

    2009-01-01

    The objectives of the workshop was to discuss the roles and responsibilities of IAEA projects co-coordinators and the challenges they encounter in the implementation of such projects. Solutions were suggested.(Lead Record)

  13. Coordinating distributed work : Exploring situated coordination with gaming-simulation

    NARCIS (Netherlands)

    van Laere, J.

    2003-01-01

    Organizational work has become more and more distributed nowadays. Information and communication technologies (ICT) provide opportunities to improve coordination of distributed work, but in practice many organizations struggle with integrating new organizational structures, new work practices and

  14. Coordinate Mastering Using Optical Coupling

    Science.gov (United States)

    Bieman, Leonard H.

    1989-01-01

    For a multi-sensor machine vision system, relating each sensor's measurement to a master gage coordinate system has been a difficult task. This is especially true for sheet metal gaging in the automotive industry where sensors may be separated by four or five meters. The current approach used to establish this master coordinate system, which is difficult at best, has been the following. First, the part is placed in the gage. The exact location, that is being measured by each sensor, is marked on the part. Then the marked part is transported to a coordinate measuring machine (CMM), where the location of each of the marked points is measured. These CMM measurements establish a master coordinate system. The procedure just described has major drawbacks including: the accuracy of marking the exact location being measured; the sensors orientation must be known with respect to the master coordinate system; and deformation of the sheet metal part when it is transported to the CMM. The mastering process can be significantly improved by optical coupling a theodolite pair with each machine vision sensor. This optical coupling is established by locating a target in a position that can be accurately measured by both a sensor and the theodolite system. First, the theodolite system is calibrated in gage coordinates by sighting on reference points placed on the machine vision gage. Then, for each sensor, the target location is measured by both the sensor and theodolite pair at three or more positions (or alternately one target may have three or more points that can be measured). From this data, the transforms from sensor coordinates to gage coordinates can be calculated. This report will present the configuration and calculations for coordinate mastering using optical coupling.

  15. Evaluating the Relational Coordination instrument

    DEFF Research Database (Denmark)

    Edwards, Kasper; Lundstrøm, Sanne Lykke

    2014-01-01

    and surgical performance. This has prompted the attention of both practitioners and politicians some of who perceive relational coordination as a means to attain better performance. The relational coordination instrument has been validated as a measure of teamwork from the following perspectives: internal...... consistency, interrater agreement and reliability, structural validity, content validity. However as relational coordination is being used as a diagnostics tool it is important to examine further if the instrument can measure changes. Indeed we need to know how precise and sensitive the instrument is when...

  16. A Convenient and Templated Method for the Fabrication of Monodisperse Micrometer Hollow Titania Spheres

    Directory of Open Access Journals (Sweden)

    Haibo Yao

    2013-01-01

    Full Text Available A simple and widely applicable methodology was presented to synthesize monodisperse micrometer hollow titania spheres (HTS based on the templating method. It was performed by using the preformed poly(styrene-acrylic acid (PSA as template spheres which was mixed with tetrabutyltitanate (TBOT in an ethanol solvent under steam treatment. The HTS which were obtained by the calcination of PSA/TiO2 composite core-shell spheres had a narrow particle size distribution and commendable surface topography characterized by SEM. The calcined HTS at 500°C displayed crystalline reflection peaks that were characteristic to the anatase phase by XRD. Moreover, some key influencing factors including TBOT concentration and reaction time were analyzed. As expected, the diameter of HTS could be readily controlled by altering the size of PSA template spheres. In addition, the approach was also applied to fabricate hollow zirconia spheres and other inorganic spheres.

  17. A General Synthesis Strategy for Hierarchical Porous Metal Oxide Hollow Spheres

    Directory of Open Access Journals (Sweden)

    Huadong Fu

    2015-01-01

    Full Text Available The hierarchical porous TiO2 hollow spheres were successfully prepared by using the hydrothermally synthesized colloidal carbon spheres as templates and tetrabutyl titanate as inorganic precursors. The diameter and wall thickness of hollow TiO2 spheres were determined by the hard templates and concentration of tetrabutyl titanate. The particle size, dispersity, homogeneity, and surface state of the carbon spheres can be easily controlled by adjusting the hydrothermal conditions and adding certain amount of the surfactants. The prepared hollow spheres possessed the perfect spherical shape, monodispersity, and hierarchically pore structures, and the further experiment verified that the present approach can be used to prepare other metal oxide hollow spheres, which could be used as catalysis, fuel cells, lithium-air battery, gas sensor, and so on.

  18. Cavitation and radicals drive the sonochemical synthesis of functional polymer spheres

    Energy Technology Data Exchange (ETDEWEB)

    Narayanan, Badri, E-mail: bnarayanan@anl.gov; Deshmukh, Sanket A.; Sankaranarayanan, Subramanian K. R. S., E-mail: ssankaranarayanan@anl.gov [Center for Nanoscale Materials, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Shrestha, Lok Kumar; Ariga, Katsuhiko [World Premier International Center for Materials Nanoarchitechtonics (WPI-MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba 305-0044 (Japan); Pol, Vilas G. [School of Chemical Engineering, Purdue University, West Lafayette, Indiana 47907 (United States)

    2016-07-25

    Sonochemical synthesis can lead to a dramatic increase in the kinetics of formation of polymer spheres (templates for carbon spheres) compared to the modified Stöber silica method applied to produce analogous polymer spheres. Reactive molecular dynamics simulations of the sonochemical process indicate a significantly enhanced rate of polymer sphere formation starting from resorcinol and formaldehyde precursors. The associated chemical reaction kinetics enhancement due to sonication is postulated to arise from the localized lowering of atomic densities, localized heating, and generation of radicals due to cavitation collapse in aqueous systems. This dramatic increase in reaction rates translates into enhanced nucleation and growth of the polymer spheres. The results are of broad significance to understanding mechanisms of sonication induced synthesis as well as technologies utilizing polymers spheres.

  19. Type-I superconductivity in carbon-coated Sn nano-spheres

    Science.gov (United States)

    Shani, L.; Kumar, V. B.; Gedanken, A.; Shapiro, I.; Shapiro, B. Ya.; Shaulov, A.; Yeshurun, Y.

    2018-03-01

    Tin spheres of diameter ∼120 nm and ∼1400 nm coated with sub-nanometer carbon layers were fabricated, using a sonochemical technique. Samples of both spheres reveal a type-I superconducting behavior characterized by super-critical fields and an intermediate state manifested by a gradual increase of the magnetization to zero. However, the small and large tin spheres exhibit a similar critical field, Hc, contrary to the expected increase in Hc in spheres with size smaller than the coherence length (∼230 nm). Analysis of the data shows that a relative high degree of carbon doping in the small tin spheres, eliminates the expected size-effect on Hc. Simulations, based on the time dependent Ginzburg-Landau equations, imply that the intermediate state in both measured samples consists of only one superconducting domain surrounded by a normal domain, whereas a rich multi-domain structure is predicted for larger Sn spheres.

  20. A reliable parameter to standardize the scoring of stem cell spheres.

    Directory of Open Access Journals (Sweden)

    Xiaochen Zhou

    Full Text Available Sphere formation assay is widely used in selection and enrichment of normal stem cells or cancer stem cells (CSCs, also known as tumor initiating cells (TICs, based on their ability to grow in serum-free suspension culture for clonal proliferation. However, there is no standardized parameter to accurately score the spheres, which should be reflected by both the number and size of the spheres. Here we define a novel parameter, designated as Standardized Sphere Score (SSS, which is expressed by the total volume of selected spheres divided by the number of cells initially plated. SSS was validated in quantification of both tumor spheres from cancer cell lines and embryonic bodies (EB from mouse embryonic stem cells with high sensitivity and reproducibility.

  1. Preparation of SnO 2 /Carbon Composite Hollow Spheres and Their Lithium Storage Properties

    KAUST Repository

    Lou, Xiong Wen

    2008-10-28

    In this work, we present a novel concept of structural design for preparing functional composite hollow spheres and derived double-shelled hollow spheres. The approach involves two main steps: preparation of porous hollow spheres of one component and deposition of the other component onto both the interior and exterior surfaces of the shell as well as in the pores. We demonstrate the concept by preparing SnO2/carbon composite hollow spheres and evaluate them as potential anode materials for lithium-ion batteries. These SnO2/carbon hollow spheres are able to deliver a reversible Li storage capacity of 473 mA h g-1 after 50 cycles. Unusual double-shelled carbon hollow spheres are obtained by selective removal of the sandwiched porous SnO2 shells. © 2008 American Chemical Society.

  2. Facile Synthesis and High Photocatalytic Degradation Performance of ZnO-SnO2 Hollow Spheres

    OpenAIRE

    Jin, Changqing; Ge, Chenghai; Jian, Zengyun; Wei, Yongxing

    2016-01-01

    ZnO-SnO2 hollow spheres were successfully synthesized through a hydrothermal method-combined carbon sphere template. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and Fourier transform infrared spectroscopy (FT-IR). The average diameter of hollow spheres is about 150?nm. The photocatalytic activity of the as-prepared samples was investigated by photodegrading Rhodamine B. The results indicated that the ph...

  3. Determination of minimum impact parameter by modified touching spheres schemes for intermediate energy Coulomb excitation experiments

    International Nuclear Information System (INIS)

    Kumar, Rajiv; Sharma, Shagun; Singh, Pradeep; Kharab, Rajesh

    2016-01-01

    The energy-independent touching spheres schemes commonly used for the determination of the safe minimum value of the impact parameter for Coulomb excitation experiments are modified through the inclusion of an energy-dependent term. The touching spheres+3fm scheme after modification emerges out to be the best one while touching spheres+4fm scheme is found to be better in its unmodified form. (orig.)

  4. Gel-sphere-pac fuel for thermal reactors: assessment of fabrication technology and irradiation performance

    Energy Technology Data Exchange (ETDEWEB)

    Beatty, R.L. Norman, R.E.; Notz, K.J. (comps.)

    1979-11-01

    Recent interest in proliferation-resistant fuel cycles for light-water reactors has focused attention on spiked plutonium and /sup 233/U-Th fuels, requiring remote refabrication. The gel-sphere-pac process for fabricating metal-clad fuel elements has drawn special attention because it involves fewer steps. Gel-sphere-pac fabrication technology involves two major areas: the preparation of fuel spheres of high density and loading these spheres into rods in an efficiently packed geometry. Gel sphere preparation involves three major steps: preparation of a sol or of a special solution (broth), gelation of droplets of sol or broth to give semirigid spheres of controlled size, and drying and sintering these spheres to a high density. Gelation may be accomplished by water extraction (suitable only for sols) or ammonia gelation (suitable for both sols and broths but used almost exclusively with broths). Ammonia gelation can be accomplished either externally, via ammonia gas and ammonium hydroxide, or internally via an added ammonia generator such as hexamethylenetetramine. Sphere-pac fuel rod fabrication involves controlled blending and metering of three sizes of spheres into the rod and packing by low- to medium-energy vibration to achieve about 88% smear density; these sizes have diametral ratios of about 40:10:1 and are blended in size fraction amounts of about 60% coarse, 18% medium, and 22% fine. Irradiation test results indicate that sphere-pac fuel performs at least as well as pellet fuel, and may in fact offer an advantage in significantly reducing mechanical and chemical interaction between the fuel and cladding. The normal feed for gel sphere preparation, heavy metal nitrate solution, is the usual product of fuel reprocessing, so that fabrication of gel spheres performs all the functions performed by both conversion and pellet fabrication in the case of pellet technology.

  5. SPHERE DAQ and off-line systems: implementation based on the qdpb system

    International Nuclear Information System (INIS)

    Isupov, A.Yu.

    2003-01-01

    Design of the on-line data acquisition (DAQ) system for the SPHERE setup (LHE, JINR) is described. SPHERE DAQ is based on the qdpb (Data Processing with Branchpoints) system and configurable experimental data and CAMAC hardware representations. Implementation of the DAQ and off-line program code, depending on the SPHERE setup's hardware layout and experimental data contents, is explained as well as software modules specific for such implementation

  6. Array of the two arc monopoles on a sphere with surface impedance

    OpenAIRE

    Dakhov, Viktor M.; Berdnik, Sergey L.; Blinova, Natalya K.; Penkin, Yu. M.

    2017-01-01

    The antenna array of two arc monopoles which are located parallel to the surface of a perfectly conducting or impedance sphere is considered. The influences of the phase of excitation of a monopole, the distance to the sphere surface, and sphere radius and its surface impedance on the directivity of the radiator are considered. It is shown that the radiation pattern of the antenna for antiphase excitation is highly directional and has a single maximum in the plane of arrangement of the emitters.

  7. Facile preparation method for rare earth phosphate hollow spheres and their photoluminescence properties.

    Science.gov (United States)

    Guan, Mingyun; Tao, Feifei; Sun, Jianhua; Xu, Zheng

    2008-08-05

    We have developed a template-free hydrothermal method of constructing rare earth phosphate hollow spheres using H(6)P(4)O(13) as the PO(4) (3-) source. The mechanism of hollow spheres formation was proposed on the basis of Ostwald ripening. The resulting hollow spheres, especially with the aid of doping of other lanthanide cations, exhibit emission spanning the whole UV-visible wavelength range.

  8. An internet-mediated political public sphere in China and South Korea

    OpenAIRE

    Chase, Thomas

    2017-01-01

    This thesis investigates the growing volume of online political commentary being produced by Internet users in Mainland China and South Korea, analysing the qualities and characteristics of these discourses through adaptation of the argument provided by German sociologist Jürgen Habermas about the workings of the public sphere. In evaluating the gap between the idealised qualities of the public sphere and real-life communication, the study uses the concept of the public sphere as a heuristic...

  9. Coordinating a successful discharge plan.

    Science.gov (United States)

    Hester, L E

    1996-06-01

    Whether you're working with a team or serving as liaison to a specially designated home care coordinator, your role is crucial in paving the way home for your patient. Here are the essential steps to take.

  10. Who matters in coordination problems?

    Czech Academy of Sciences Publication Activity Database

    Sákovics, J.; Steiner, Jakub

    2012-01-01

    Roč. 102, č. 7 (2012), s. 3439-3461 ISSN 0002-8282 Institutional support: RVO:67985998 Keywords : coordination problem s * heterogeneous agents Subject RIV: AH - Economics Impact factor: 2.792, year: 2012

  11. Spectroscopic and DFT Studies of Second Sphere Variants of the Type 1 Copper Site in Azurin: Covalent and Non-Local Electrostatic Contributions to Reduction Potentials

    Science.gov (United States)

    Hadt, Ryan G.; Sun, Ning; Marshall, Nicholas M.; Hodgson, Keith O.; Hedman, Britt; Lu, Yi; Solomon, Edward I.

    2012-01-01

    The reduction potentials (E0) of type 1 (T1) or blue copper (BC) sites in proteins and enzymes with identical first coordination spheres around the redox active copper ion can vary by ~400 mV. Here, we use a combination of low temperature electronic absorption and magnetic circular dichroism, electron paramagnetic resonance, resonance Raman, and S K-edge X-ray absorption spectroscopies to investigate a series of second sphere variants—F114P, N47S, and F114N in Pseudomonas aeruginosa azurin (Az)—which modulate hydrogen bonding to and protein derived dipoles nearby the Cu-S(Cys) bond. Density functional theory (DFT) calculations correlated to the experimental data allow for the fractionation of the contributions to tuning E0 into covalent and non-local electrostatic components. These are found to be significant, comparable in magnitude, and additive for active H-bonds, while passive H-bonds are mostly non-local electrostatic in nature. For dipoles, these terms can be additive to or oppose one another. This study provides a methodology for uncoupling covalency from non-local electrostatics, which, when coupled to X-ray crystallographic data, distinguishes specific local interactions from more long range protein/active interactions, while affording further insight into the second sphere mechanisms available to the protein to tune the E0 of electron transfer sites in biology. PMID:22985400

  12. A precise determination of the void percolation threshold for two distributions of overlapping spheres

    Energy Technology Data Exchange (ETDEWEB)

    RINTOUL,MARK DANIEL

    2000-01-25

    The void percolation threshold is calculated for a distribution of overlapping spheres with equal radii, and for a binary sized distribution of overlapping spheres, where half of the spheres have radii twice as large as the other half. Using systems much larger than previous work, the authors determine a much more precise value for the percolation thresholds and correlation length exponent. The values for the percolation thresholds are shown to be significantly different, in contrast with previous, less precise works that speculated that the threshold might be universal with respect to sphere size distribution.

  13. A novel approach for fabricating NiO hollow spheres for gas sensors

    Science.gov (United States)

    Kuang, Chengwei; Zeng, Wen; Ye, Hong; Li, Yanqiong

    2018-03-01

    Hollow spheres are usually fabricated by hard template methods or soft template methods with soft surfactants, which is quiet tedious and time-consuming. In this paper, NiO hollow spheres with fluffy surface were successfully synthesized by a facile hydrothermal method and subsequent calcination, where bubbles acted as the template. NiO hollow spheres exhibited excellent gas sensing performances, which results from its hollow structure and high specific surface area. In addition, a possible evolution mechanism of NiO hollow spheres was proposed based on experimental results.

  14. Controllable Fabrication and Optical Properties of Uniform Gadolinium Oxysulfate Hollow Spheres

    OpenAIRE

    Chen, Fashen; Chen, Gen; Liu, Tao; Zhang, Ning; Liu, Xiaohe; Luo, Hongmei; Li, Junhui; Chen, Limiao; Ma, Renzhi; Qiu, Guanzhou

    2015-01-01

    Uniform gadolinium oxysulfate (Gd2O2SO4) hollow spheres were successfully fabricated by calcination of corresponding Gd-organic precursor obtained via a facile hydrothermal process. The Gd2O2SO4 hollow spheres have a mean diameter of approximately 550?nm and shell thickness in the range of 30?70?nm. The sizes and morphologies of as-prepared Gd2O2SO4 hollow spheres could be deliberately controlled by adjusting the experimental parameters. Eu-doped Gd2O2SO4 hollow spheres have also been prepare...

  15. VMware vSphere performance designing CPU, memory, storage, and networking for performance-intensive workloads

    CERN Document Server

    Liebowitz, Matt; Spies, Rynardt

    2014-01-01

    Covering the latest VMware vSphere software, an essential book aimed at solving vSphere performance problems before they happen VMware vSphere is the industry's most widely deployed virtualization solution. However, if you improperly deploy vSphere, performance problems occur. Aimed at VMware administrators and engineers and written by a team of VMware experts, this resource provides guidance on common CPU, memory, storage, and network-related problems. Plus, step-by-step instructions walk you through techniques for solving problems and shed light on possible causes behind the problems. Divu

  16. The electromagnetic radiation from simple sources in the presence of a homogeneous dielectric sphere

    Science.gov (United States)

    Mason, V. B.

    1973-01-01

    In this research, the effect of a homogeneous dielectric sphere on the electromagnetic radiation from simple sources is treated as a boundary value problem, and the solution is obtained by the technique of dyadic Green's functions. Exact representations of the electric fields in the various regions due to a source located inside, outside, or on the surface of a dielectric sphere are formulated. Particular attention is given to the effect of sphere size, source location, dielectric constant, and dielectric loss on the radiation patterns and directivity of small spheres (less than 5 wavelengths in diameter) using the Huygens' source excitation. The computed results are found to closely agree with those measured for waveguide-excited plexiglas spheres. Radiation patterns for an extended Huygens' source and for curved electric dipoles located on the sphere's surface are also presented. The resonance phenomenon associated with the dielectric sphere is studied in terms of the modal representation of the radiated fields. It is found that when the sphere is excited at certain frequencies, much of the energy is radiated into the sidelobes. The addition of a moderate amount of dielectric loss, however, quickly attenuates this resonance effect. A computer program which may be used to calculate the directivity and radiation pattern of a Huygens' source located inside or on the surface of a lossy dielectric sphere is listed.

  17. Coordination theory and collaboration technology

    CERN Document Server

    Olson, Gary M; Smith, John B

    2001-01-01

    The National Science Foundation funded the first Coordination Theory and Collaboration Technology initiative to look at systems that support collaborations in business and elsewhere. This book explores the global revolution in human interconnectedness. It will discuss the various collaborative workgroups and their use in technology. The initiative focuses on processes of coordination and cooperation among autonomous units in human systems, in computer and communication systems, and in hybrid organizations of both systems. This initiative is motivated by three scientific issues which have been

  18. Muscle Activation and Movement Coordination.

    OpenAIRE

    Ljung, Carl

    2014-01-01

    The purpose of this project was to empirically develop a method of using electromyography to identify how humans coordinate their muscles during certain sequences of movement and the effect of an injured anterior cruciate ligament to muscle coordination. In this study, more simple movements of the lower extremities are examined and relatively accurate hypothesizes can be made solely based on anatomical theory. However, a general method for electromyographic studies would open up the possibili...

  19. DEVELOPMENTAL COORDINATION DISORDER IN CHILDREN

    OpenAIRE

    Saeideh MIRAFKHAMI; Seyyed Hossein FAKHRAEE; Sina MIRAFKHAMI; Mojtaba YOUSEFI; Mona VARZANDEH FAR

    2010-01-01

    ObjectiveIn this article, a motor skill disorder called developmental coordination disorder (DCD), that is usually first diagnosed during childhood, is explained and discussed. In the year 1987, DCD was formally recognized as a distinct disorder in children by the American Psychiatric Association  (APA). DCD is a generalized term for the children who have some degrees of impairment in the development of motor coordination and therefore have difficulties with physical skills which significantl...

  20. Path integrals in curvilinear coordinates

    International Nuclear Information System (INIS)

    Prokhorov, L.V.

    1984-01-01

    Integration limits are studied for presenting the path integral curvilinear coordinates. For spherical (and topoloqically equivalent) coordinates it is shown that in formulas involving classical action in the exponent integration over all variables should be carried out within infinite limits. Another peculiarity is associated with appearance of the operator q which provides a complete definition of the wave functions out of the physical region. arguments are given upporting the validity of the cited statament in the general case