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Sample records for coordinated solution prior

  1. Peroxide coordination of tellurium in aqueous solutions

    Energy Technology Data Exchange (ETDEWEB)

    Mikhaylov, Alexey A.; Medvedev, Alexander G. [Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow (Russian Federation); The Casali Center of Applied Chemistry, The Institute of Chemistry, The Hebrew University of Jerusalem (Israel); Churakov, Andrei V.; Grishanov, Dmitry A.; Prikhodchenko, Petr V. [Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow (Russian Federation); Lev, Ovadia [The Casali Center of Applied Chemistry, The Institute of Chemistry, The Hebrew University of Jerusalem (Israel)

    2016-02-15

    Tellurium-peroxo complexes in aqueous solutions have never been reported. In this work, ammonium peroxotellurates (NH{sub 4}){sub 4}Te{sub 2}(μ-OO){sub 2}(μ-O)O{sub 4}(OH){sub 2} (1) and (NH{sub 4}){sub 5}Te{sub 2}(μ-OO){sub 2}(μ-O)O{sub 5}(OH).1.28 H{sub 2}O.0.72 H{sub 2}O{sub 2} (2) were isolated from 5 % hydrogen peroxide aqueous solutions of ammonium tellurate and characterized by single-crystal and powder X-ray diffraction analysis, by Raman spectroscopy and thermal analysis. The crystal structure of 1 comprises ammonium cations and a symmetric binuclear peroxotellurate anion [Te{sub 2}(μ-OO){sub 2}(μ-O)O{sub 4}(OH){sub 2}]{sup 4-}. The structure of 2 consists of an unsymmetrical [Te{sub 2}(μ-OO){sub 2}(μ-O)O{sub 5}(OH)]{sup 5-} anion, ammonium cations, hydrogen peroxide, and water. Peroxotellurate anions in both 1 and 2 contain a binuclear Te{sub 2}(μ-OO){sub 2}(μ-O) fragment with one μ-oxo- and two μ-peroxo bridging groups. {sup 125}Te NMR spectroscopic analysis shows that the peroxo bridged bitellurate anions are the dominant species in solution, with 3-40 %wt H{sub 2}O{sub 2} and for pH values above 9. DFT calculations of the peroxotellurate anion confirm its higher thermodynamic stability compared with those of the oxotellurate analogues. This is the first direct evidence for tellurium-peroxide coordination in any aqueous system and the first report of inorganic tellurium-peroxo complexes. General features common to all reported p-block element peroxides could be discerned by the characterization of aqueous and crystalline peroxotellurates. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  2. Coordination chemistry in fused-salt solutions

    Science.gov (United States)

    Gruen, D. M.

    1969-01-01

    Spectrophotometric work on structural determinations with fused-salt solutions is reviewed. Constraints placed on the method, as well as interpretation of the spectra, are discussed with parallels drawn to aqueous spectrophotometric curves of the same materials.

  3. Coordinate transformation and Polynomial Chaos for the Bayesian inference of a Gaussian process with parametrized prior covariance function

    KAUST Repository

    Sraj, Ihab

    2015-10-22

    This paper addresses model dimensionality reduction for Bayesian inference based on prior Gaussian fields with uncertainty in the covariance function hyper-parameters. The dimensionality reduction is traditionally achieved using the Karhunen-Loève expansion of a prior Gaussian process assuming covariance function with fixed hyper-parameters, despite the fact that these are uncertain in nature. The posterior distribution of the Karhunen-Loève coordinates is then inferred using available observations. The resulting inferred field is therefore dependent on the assumed hyper-parameters. Here, we seek to efficiently estimate both the field and covariance hyper-parameters using Bayesian inference. To this end, a generalized Karhunen-Loève expansion is derived using a coordinate transformation to account for the dependence with respect to the covariance hyper-parameters. Polynomial Chaos expansions are employed for the acceleration of the Bayesian inference using similar coordinate transformations, enabling us to avoid expanding explicitly the solution dependence on the uncertain hyper-parameters. We demonstrate the feasibility of the proposed method on a transient diffusion equation by inferring spatially-varying log-diffusivity fields from noisy data. The inferred profiles were found closer to the true profiles when including the hyper-parameters’ uncertainty in the inference formulation.

  4. Free energy landscapes of ion coordination in aqueous solution.

    Science.gov (United States)

    Brancato, Giuseppe; Barone, Vincenzo

    2011-11-10

    We show how the fruitful concept of free energy landscape, as invoked in the description of complex biological systems, can be rather easily extended to build up a simple and accurate picture about solvent coordination around ions. This may represent a revealing key element for the qualitative and quantitative physical-chemical interpretation of a large number of phenomena occurring in solution, such as water exchange mechanisms, ion mobility, solvation dynamics, ion channel selectivity, and so on. In particular, using a computational approach rooted into molecular dynamics simulations and enhanced sampling techniques, we show how the free energy landscapes of ion coordination in solution can be very easily and accurately obtained in a number of illustrative examples.

  5. Coordination chemistry and solution structure of Fe(II)-peplomycin. Two possible coordination geometries.

    Science.gov (United States)

    Li, Yang; Lehmann, Teresa

    2012-06-01

    The solution structure of Fe(II)-peplomycin was determined from NMR data collected for this molecule. As found previously for Fe(II)- and Co(II)-bound bleomycin; the coordination sphere of the metal is composed of the primary and secondary amines in β-aminoalanine, the pyrimidine and imidazole rings in the pyrimidinylpropionamide, and β-hydroxyhistidine moieties, respectively, the amine nitrogen in β-hydroxyhistidine, and either the carbamoyl group in mannose or a solvent molecule. The two most discussed coordination geometries for the aforementioned ligands in metallo-bleomycins have been tested against the NMR data generated for Fe(II)-peplomycin. The interpretation of the experimental evidence obtained through molecular dynamics indicates that both geometries are equally likely in solution for this compound in the absence of DNA, but arguments are offered to explain why one of these geometries is preferred in the presence of DNA.

  6. Determination of Coordination Configuration of Rare Earth Ionswith Aminoacids in Solutions with Cooperative Vibronic Spectroscopy

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The use of cooperative vibronic spectroscopy to measure coordination numbers of the ligands surrounding rare earth ions in solutions was proposed and demonstrated. It is shown that the time-resolved cooperative vibronic spectroscopy is a very useful technique for the determination of the ligand type and ligand number for different coordination groups. Coordination configuration of arginine with Tb3+ in solutions with different pH values was studied. It demonstrates that the carboxyl of arginine can replace H2O to coordinate with Tb3+ and the coordination number of carboxyl increases with the increase of pH value of the solutions.

  7. XAFS Study of Coordination Structure of Cu(L-His)2 in Solution

    Institute of Scientific and Technical Information of China (English)

    Yan Pana; Li-yun Zhang; Yang-zhong Liu

    2011-01-01

    Multiple coordination modes are present in the CuⅡ-histidine complex in solution and the copper coordination environment varies with pH.In this work,we have investigated the coordination geometry of Cu(His)2 complex using X-ray absorption fine structure (XAFS)analysis.Copper K-edge XAFS spectra were acquired on aqueous Cu2+ samples with histidine at different pH values.The coordination environments were further confirmed by chemically modified histidine.Results show that the caboxylate groups coordinate at acidic condition,while amino and imidazole nitrogens get coordinated at higher pH.For the coordination geometry of Cu(His)2 in solution at physiological pH,the sixfold coordination is preferentially formed,while the fivefold coordination can co-exist in equilibrium.

  8. Inverse problems with non-trivial priors: efficient solution through sequential Gibbs sampling

    DEFF Research Database (Denmark)

    Hansen, Thomas Mejer; Cordua, Knud Skou; Mosegaard, Klaus

    2012-01-01

    Markov chain Monte Carlo methods such as the Gibbs sampler and the Metropolis algorithm can be used to sample solutions to non-linear inverse problems. In principle, these methods allow incorporation of prior information of arbitrary complexity. If an analytical closed form description of the pri...... also reduce the computation time for the inversion dramatically. The method works for any statistical model for which sequential simulation can be used to generate realizations. This applies to most algorithms developed in the geostatistical community.......Markov chain Monte Carlo methods such as the Gibbs sampler and the Metropolis algorithm can be used to sample solutions to non-linear inverse problems. In principle, these methods allow incorporation of prior information of arbitrary complexity. If an analytical closed form description of the prior...... for applying the sequential Gibbs sampler and illustrate how it works. Through two case studies, we demonstrate the application of the method to a linear image restoration problem and to a non-linear cross-borehole inversion problem. We demonstrate how prior information can reduce the complexity of an inverse...

  9. Algebraically explicit analytical solutions of unsteady conduction with variable thermal properties in cylindrical coordinate

    Institute of Scientific and Technical Information of China (English)

    CAI Ruixian; ZHANG Na

    2004-01-01

    The analytical solutions of unsteady heat conduction with variable thermal properties(thermal conductivity,density and specific heat are functions of temperature or coordinates)are meaningful in theory.In addition,they are very useful to the computational heat conduction to check the numerical solutions and to develop numerical schemes,grid generation methods and so forth.Such solutions in rectangular coordinates have been derived by the authors.Some other solutions for 1-D and 2-D axisymmetrical heat conduction in cylin drical coordinates are given in this paper to promote the heat conduction theory and to develop the relative computational heat conduction.

  10. Approximate solutions of non-linear circular orbit relative motion in curvilinear coordinates

    Science.gov (United States)

    Bombardelli, Claudio; Gonzalo, Juan Luis; Roa, Javier

    2016-07-01

    A compact, time-explicit, approximate solution of the highly non-linear relative motion in curvilinear coordinates is provided under the assumption of circular orbit for the chief spacecraft. The rather compact, three-dimensional solution is obtained by algebraic manipulation of the individual Keplerian motions in curvilinear, rather than Cartesian coordinates, and provides analytical expressions for the secular, constant and periodic terms of each coordinate as a function of the initial relative motion conditions or relative orbital elements. Numerical test cases are conducted to show that the approximate solution can be effectively employed to extend the classical linear Clohessy-Wiltshire solution to include non-linear relative motion without significant loss of accuracy up to a limit of 0.4-0.45 in eccentricity and 40-45° in relative inclination for the follower. A very simple, quadratic extension of the classical Clohessy-Wiltshire solution in curvilinear coordinates is also presented.

  11. Approximate solutions of non-linear circular orbit relative motion in curvilinear coordinates

    Science.gov (United States)

    Bombardelli, Claudio; Gonzalo, Juan Luis; Roa, Javier

    2017-01-01

    A compact, time-explicit, approximate solution of the highly non-linear relative motion in curvilinear coordinates is provided under the assumption of circular orbit for the chief spacecraft. The rather compact, three-dimensional solution is obtained by algebraic manipulation of the individual Keplerian motions in curvilinear, rather than Cartesian coordinates, and provides analytical expressions for the secular, constant and periodic terms of each coordinate as a function of the initial relative motion conditions or relative orbital elements. Numerical test cases are conducted to show that the approximate solution can be effectively employed to extend the classical linear Clohessy-Wiltshire solution to include non-linear relative motion without significant loss of accuracy up to a limit of 0.4-0.45 in eccentricity and 40-45° in relative inclination for the follower. A very simple, quadratic extension of the classical Clohessy-Wiltshire solution in curvilinear coordinates is also presented.

  12. Darboux coordinates for periodic solutions of the sinh-Gordon equation

    Science.gov (United States)

    Knopf, Markus

    2016-12-01

    We study the space of periodic solutions of the elliptic sinh-Gordon equation by means of spectral data consisting of a Riemann surface Y and a divisor D and prove the existence of certain Darboux coordinates.

  13. The Two-Parameter Brane Sigma-Model: M*, M' solutions and M-theory solutions dependent on exotic coordinates

    CERN Document Server

    Cook, Paul P

    2016-01-01

    We investigate two-parameter solutions of sigma-models on two dimensional symmetric spaces contained in E11. Embedding such sigma-model solutions in space-time gives solutions of M* and M'-theory where the metric depends on general travelling wave functions, as opposed to harmonic functions typical in general relativity, supergravity and M-theory. Weyl reflection allows such solutions to be mapped to M-theory solutions where the wave functions depend explicitly on extra coordinates contained in the fundamental representation of E11.

  14. BENCHMARK SOLUTIONS FOR STOKES EQUATIONS WITH VARIABLE VISCOSITY IN CYLINDRICAL AND SPHERICAL COORDINATES

    Directory of Open Access Journals (Sweden)

    I. V. Makeev

    2016-01-01

    Full Text Available Stokes flows in cylindrical and spherical geometry are considered. Such flows are rather natural for geophysics. We derive some exact particular solutions of Stokes and continuity equations for particular dependence of viscosity and density on cylindrical coordinates. These solutions correspond to axisymmetric flows for the case when viscosity is a function of radius. We suggest exact particular solutions of Stokes and continuity equations with variable viscosity and density in spherical coordinates for the case of spherically symmetric viscosity and density distributions. We demonstrate how these solutions can be used for creation of test problems suitable for benchmarking numerical algorithms. Examples of such benchmarking are presented. The advantage of this benchmarking approach is the ability to test numerical algorithms for variable viscosity and density gradients. We suggest numerical scheme of multigrid algorithm for solving Stokes and continuity equations with variable viscosity in a spherical coordinate system. Calculations are performed on a sequence of orthogonal staggered grids. The quality of the numerical scheme was verified by comparing the numerical solution with the analytical solution of the test problem.

  15. Organometallic macromolecules with piano stool coordination repeating units: chain configuration and stimulated solution behaviour.

    Science.gov (United States)

    Cao, Kai; Ward, Jonathan; Amos, Ryan C; Jeong, Moon Gon; Kim, Kyoung Taek; Gauthier, Mario; Foucher, Daniel; Wang, Xiaosong

    2014-09-11

    Theoretical calculations illustrate that organometallic macromolecules with piano stool coordination repeating units (Fe-acyl complex) adopt linear chain configuration with a P-Fe-C backbone surrounded by aromatic groups. The macromolecules show molecular weight-dependent and temperature stimulated solution behaviour in DMSO.

  16. Metal ion coordination, conditional stability constants, and solution behavior of chelating surfactant metal complexes.

    Science.gov (United States)

    Svanedal, Ida; Boija, Susanne; Almesåker, Ann; Persson, Gerd; Andersson, Fredrik; Hedenström, Erik; Bylund, Dan; Norgren, Magnus; Edlund, Håkan

    2014-04-29

    Coordination complexes of some divalent metal ions with the DTPA (diethylenetriaminepentaacetic acid)-based chelating surfactant 2-dodecyldiethylenetriaminepentaacetic acid (4-C12-DTPA) have been examined in terms of chelation and solution behavior. The headgroup of 4-C12-DTPA contains eight donor atoms that can participate in the coordination of a metal ion. Conditional stability constants for five transition metal complexes with 4-C12-DTPA were determined by competition measurements between 4-C12-DTPA and DTPA, using electrospray ionization mass spectrometry (ESI-MS). Small differences in the relative strength between the coordination complexes of DTPA and 4-C12-DTPA indicated that the hydrocarbon tail only affected the chelating ability of the headgroup to a limited extent. The coordination of Cu(2+) ions was investigated in particular, using UV-visible spectroscopy. By constructing Job's plots, it was found that 4-C12-DTPA could coordinate up to two Cu(2+) ions. Surface tension measurements and NMR diffusometry showed that the coordination of metal ions affected the solution behavior of 4-C12-DTPA, but there were no specific trends between the studied divalent metal complexes. Generally, the effects of the metal ion coordination could be linked to the neutralization of the headgroup charge of 4-C12-DTPA, and the resulting reduced electrostatic repulsions between adjacent surfactants in micelles and monolayers. The pH vs concentration plots, on the other hand, showed a distinct difference between 4-C12-DTPA complexes of the alkaline earth metals and the transition metals. This was explained by the difference in coordination between the two groups of metal ions, as predicted by the hard and soft acid and base (HSAB) theory.

  17. Natural curvilinear coordinates for ideal magnetohydrodynamics equations. Solutions with constant total pressure

    CERN Document Server

    Golovin, Sergey V

    2010-01-01

    Equations of magneto-gasdynamics in the natural curvilinear system of coordinates where trajectories and magnetic lines play a role of coordinate curves are reduced to the nonlinear vector wave equation coupled with the incompressibility condition in the form of the generalized Cauchy integral. The symmetry group of obtained equation, equivalence transformation, and group classification with respect to the constitutive equation are calculated. New exact solutions with functional arbitrariness describing non-stationary incompressible flows with constant total pressure are given by explicit formulae. The corresponding magnetic surfaces have the shape of deformed nested cylinders, tori, or knotted tubes.

  18. Doping in solution as an order-inducing tool prior to film formation of regio-irregular polyalkylthiophenes

    DEFF Research Database (Denmark)

    Apperloo, J.J.; Janssen, R.A.J.; Nielsen, Martin Meedom;

    2000-01-01

    Favorable alignment of regio-irregular poly(3-alkylthiophene)s in a film can be attained, despite the fact that these polymers lack an intrinsic tendency to form well-ordered supramolecular aggregates. As reported here, alignment can be achieved simply by oxidizing the polymer in solution prior t...

  19. Coordinate Properties of Nitric Oxide in Hemoglobin Solution Containing a Minimal Amount of Nitric Oxide

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    Nitric oxide (NO) has a very important physiological function, and it is the unique small diffusible signaling molecule.When NO molecules bind to heme irons in α subunits in hemoglobin (Hb), they have two coordinate forms for Fe2+: one is 5-coordinate, and the other is 6-coordinate.However, there is only 6-coordinate for Fe2+ when NO molecules bind to heme irons in β subunits.When the amount of NO is at a minimal concentration, NO molecules mainly bind to α subunits.The results show that NO molecules do not transfer from heme irons of nitrosylhemoglobin (HbNO) to the thiol groups of Cysteine residues β93 (Cysβ93) to form s-nitrosohemoglobin (Hb-SNO) in the presence of minimal NO in hemoglobin solution.The presence of minimal NO in hemoglobin solution does not decrease the transportation of oxygen, but it does improve its transport ability.It is still under further research whether this mechanism is underlying in the therapy for the disease of cardiovascular system.

  20. The Anion Effect on Li+ Ion Coordination Structure in Ethylene Carbonate Solutions

    CERN Document Server

    Jiang, Bo; Shen, Yuneng; Yang, Xueming; Yuan, Kaijun; Vetere, Valentina; Mossa, Stefano; Skarmoutsos, Ioannis; Zhang, Yufan; Zheng, Junrong

    2016-01-01

    Rechargeable lithium ion batteries are an attractive alternative power source for a wide variety of applications. To optimize their performances, a complete description of the solvation properties of the ion in the electrolyte is crucial. A comprehensive understanding at the nanoscale of the solvation structure of lithium ions in nonaqueous carbonate electrolytes is, however, still unclear. We have measured by femtosecond vibrational spectroscopy the orientational correlation time of the CO stretching mode of Li+-bound and Li+-unbound ethylene carbonate molecules, in LiBF4, LiPF6, and LiClO4 ethylene carbonate solutions with different concentrations. Surprisingly, we have found that the coordination number of ethylene carbonate in the first solvation shell of Li+ is only two, in all solutions with concentrations higher than 0.5 M. Density functional theory calculations indicate that the presence of anions in the first coordination shell modifies the generally accepted tetrahedral structure of the complex, all...

  1. Coordination number of Li+ in nonaqueous electrolyte solutions determined by molecular rotational measurements.

    Science.gov (United States)

    Yuan, Kaijun; Bian, Hongtao; Shen, Yuneng; Jiang, Bo; Li, Jiebo; Zhang, Yufan; Chen, Hailong; Zheng, Junrong

    2014-04-03

    The coordination number of Li(+) in acetonitrile solutions was determined by directly measuring the rotational times of solvent molecules bound and unbound to it. The CN stretch of the Li(+) bound and unbound acetonitrile molecules in the same solution has distinct vibrational frequencies (2276 cm(-1) vs 2254 cm(-1)). The frequency difference allows the rotation of each type of acetonitrile molecule to be determined by monitoring the anisotropy decay of each CN stretch vibrational excitation signal. Regardless of the nature of anions and concentrations, the Li(+) coordination number was found to be 4-6 in the LiBF4 (0.2-2 M) and LiPF6 (1-2 M) acetonitrile solutions. However, the dissociation constants of the salt are dependent on the nature of anions. In 1 M LiBF4 solution, 53% of the salt was found to dissociate into Li(+), which is bound by 4-6 solvent molecules. In 1 M LiPF6 solution, 72% of the salt dissociates. 2D IR experiments show that the binding between Li(+) and acetonitrile is very strong. The lifetime of the complex is much longer than 19 ps.

  2. The Anion Effect on Li(+) Ion Coordination Structure in Ethylene Carbonate Solutions.

    Science.gov (United States)

    Jiang, Bo; Ponnuchamy, Veerapandian; Shen, Yuneng; Yang, Xueming; Yuan, Kaijun; Vetere, Valentina; Mossa, Stefano; Skarmoutsos, Ioannis; Zhang, Yufan; Zheng, Junrong

    2016-09-15

    Rechargeable lithium ion batteries are an attractive alternative power source for a wide variety of applications. To optimize their performances, a complete description of the solvation properties of the ion in the electrolyte is crucial. A comprehensive understanding at the nanoscale of the solvation structure of lithium ions in nonaqueous carbonate electrolytes is, however, still unclear. We have measured by femtosecond vibrational spectroscopy the orientational correlation time of the CO stretching mode of Li(+)-bound and Li(+)-unbound ethylene carbonate molecules, in LiBF4, LiPF6, and LiClO4 ethylene carbonate solutions with different concentrations. Surprisingly, we have found that the coordination number of ethylene carbonate in the first solvation shell of Li(+) is only two, in all solutions with concentrations higher than 0.5 M. Density functional theory calculations indicate that the presence of anions in the first coordination shell modifies the generally accepted tetrahedral structure of the complex, allowing only two EC molecules to coordinate to Li(+) directly. Our results demonstrate for the first time, to the best of our knowledge, the anion influence on the overall structure of the first solvation shell of the Li(+) ion. The formation of such a cation/solvent/anion complex provides a rational explanation for the ionic conductivity drop of lithium/carbonate electrolyte solutions at high concentrations.

  3. Effects of prior solution treatment on thermal aging behavior of duplex stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Li, Shilei; Wang, Yanli; Zhang, Hailong; Li, Shuxiao [State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083 (China); Wang, Genqi [Yantai Taihai Marnoir Nuclear Equipment Co. Ltd., Yantai 264003 (China); Wang, Xitao, E-mail: xtwang@ustb.edu.cn [State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083 (China)

    2013-10-15

    The influence of solution temperature on thermal aging behavior was studied in duplex stainless steels. With increasing solution temperature, the ferrite contents remarkably increase, Cr and Ni elements redistribute. During thermal aging, the impact properties of higher solution temperature treated materials suffer a serious degradation, which is not only related with ferrite content but also the alloy compositions in ferrite. Enrichment of Ni in ferrite can accelerate the spinodal decomposition kinetics. Thermal aging-inducing strain fields in ferrite cause the embrittlement of DSS.

  4. Analytical solutions for solute transport in groundwater and riverine flow using Green's Function Method and pertinent coordinate transformation method

    Science.gov (United States)

    Sanskrityayn, Abhishek; Suk, Heejun; Kumar, Naveen

    2017-04-01

    In this study, analytical solutions of one-dimensional pollutant transport originating from instantaneous and continuous point sources were developed in groundwater and riverine flow using both Green's Function Method (GFM) and pertinent coordinate transformation method. Dispersion coefficient and flow velocity are considered spatially and temporally dependent. The spatial dependence of the velocity is linear, non-homogeneous and that of dispersion coefficient is square of that of velocity, while the temporal dependence is considered linear, exponentially and asymptotically decelerating and accelerating. Our proposed analytical solutions are derived for three different situations depending on variations of dispersion coefficient and velocity, respectively which can represent real physical processes occurring in groundwater and riverine systems. First case refers to steady solute transport situation in steady flow in which dispersion coefficient and velocity are only spatially dependent. The second case represents transient solute transport in steady flow in which dispersion coefficient is spatially and temporally dependent while the velocity is spatially dependent. Finally, the third case indicates transient solute transport in unsteady flow in which both dispersion coefficient and velocity are spatially and temporally dependent. The present paper demonstrates the concentration distribution behavior from a point source in realistically occurring flow domains of hydrological systems including groundwater and riverine water in which the dispersivity of pollutant's mass is affected by heterogeneity of the medium as well as by other factors like velocity fluctuations, while velocity is influenced by water table slope and recharge rate. Such capabilities give the proposed method's superiority about application of various hydrological problems to be solved over other previously existing analytical solutions. Especially, to author's knowledge, any other solution doesn

  5. Accelerating potential of mean force calculations for lipid membrane permeation: System size, reaction coordinate, solute-solute distance, and cutoffs

    Science.gov (United States)

    Nitschke, Naomi; Atkovska, Kalina; Hub, Jochen S.

    2016-09-01

    Molecular dynamics simulations are capable of predicting the permeability of lipid membranes for drug-like solutes, but the calculations have remained prohibitively expensive for high-throughput studies. Here, we analyze simple measures for accelerating potential of mean force (PMF) calculations of membrane permeation, namely, (i) using smaller simulation systems, (ii) simulating multiple solutes per system, and (iii) using shorter cutoffs for the Lennard-Jones interactions. We find that PMFs for membrane permeation are remarkably robust against alterations of such parameters, suggesting that accurate PMF calculations are possible at strongly reduced computational cost. In addition, we evaluated the influence of the definition of the membrane center of mass (COM), used to define the transmembrane reaction coordinate. Membrane-COM definitions based on all lipid atoms lead to artifacts due to undulations and, consequently, to PMFs dependent on membrane size. In contrast, COM definitions based on a cylinder around the solute lead to size-independent PMFs, down to systems of only 16 lipids per monolayer. In summary, compared to popular setups that simulate a single solute in a membrane of 128 lipids with a Lennard-Jones cutoff of 1.2 nm, the measures applied here yield a speedup in sampling by factor of ˜40, without reducing the accuracy of the calculated PMF.

  6. Strengthening of the Coordination Shell by Counter Ions in Aqueous Th 4+ Solutions

    Energy Technology Data Exchange (ETDEWEB)

    Atta-Fynn, Raymond; Bylaska, Eric J.; de Jong, Wibe A.

    2016-12-29

    The presence of counter ions in solutions containing highly charged metal cations can trigger processes such as ion-pair formation, hydrogen bond breakages and subsequent reformation, and ligand exchanges. In this work, it is shown how halide (Cl-, Br-) and perchlorate (ClO4-) anions affect the strength of the primary solvent coordination shells around Th4+ using explicit solvent and finite temperature ab initio molecular dynamics modeling methods. The 9-fold solvent geometry was found to be the most stable hydration structure in each aqueous solution. Relative to the dilute aqueous solution, the presence of the counter ions did not significantly alter the geometry of the primary hydration shell. However, the free energy analyses indicated that the 10-fold hydrated states were thermodynamically accessible in dilute and bromide aqueous solutions within 1 kcal/mol. Analysis of the results showed that the hydrogen bond lifetimes were longer and solvent exchange energy barriers were larger in solutions with counter ions in comparison with the solution with no counter ions. This implies that the presence of the counter ions induces a strengthening of the Th4+ hydration shell.

  7. OPTIMAL SUBSTRUCTURE OF SET-VALUED SOLUTIONS OF NORMAL-FORM GAMES AND COORDINATION

    Institute of Scientific and Technical Information of China (English)

    Norimasa KOBAYASHI; Kyoichi KIJIMA

    2009-01-01

    A number of solution concepts of normal-form games have been proposed in the literature on subspaces of action profiles that have Nash type stability. While the literature mainly focuses on the minimal of such stable subspaces, this paper argues that non-minimal stable subspaces represent well the multi-agent situations to which neither Nash equilibrium nor rationalizability may be applied with satisfaction. As a theoretical support, the authors prove the optimal substructure of stable subspaces regarding the restriction of a game. It is further argued that the optimal substructure characterizes hierarchical diversity of coordination and interim phases in learning.

  8. Silver (I-coordinated bis(trimethoxysilylpropylamine Polycondensate for Adsorptive Removal of Iodide from Aqueous Solutions

    Directory of Open Access Journals (Sweden)

    Zhang Huifang

    2016-01-01

    Full Text Available Silver-coordinated bis(trimethoxysilylpropylamine polycondensate (TSPA-AgNO3 was prepared and used to adsorb iodide ions in aqueous solutions. Batch adsorption studies were performed to investigate the effects of pH, temperature and coexisting NaCl on adsorption behavior. The results show that TSPA-AgNO3 is easy to prepare and remarkably efficient in adsorbing iodide in water, especially in acidic solutions. Furthermore, increased temperature accelerated the adsorption, while coexisting NaCl inhibited the adsorption. TSPA-AgNO3 also proved to be chemically stable in simulated environmental situations, which reveals a promising potential for applying this method to the disposal of radioactive iodide in environment water.

  9. On analytic solutions of wave equations in regular coordinate systems on Schwarzschild background

    CERN Document Server

    Philipp, Dennis

    2015-01-01

    The propagation of (massless) scalar, electromagnetic and gravitational waves on fixed Schwarzschild background spacetime is described by the general time-dependent Regge-Wheeler equation. We transform this wave equation to usual Schwarzschild, Eddington-Finkelstein, Painleve-Gullstrand and Kruskal-Szekeres coordinates. In the first three cases, but not in the last one, it is possible to separate a harmonic time-dependence. Then the resulting radial equations belong to the class of confluent Heun equations, i.e., we can identify one irregular and two regular singularities. Using the generalized Riemann scheme we collect properties of all the singular points and construct analytic (local) solutions in terms of the standard confluent Heun function HeunC, Frobenius and asymptotic Thome series. We study the Eddington-Finkelstein case in detail and obtain a solution that is regular at the black hole horizon. This solution satisfies causal boundary conditions, i.e., it describes purely ingoing radiation at $r=2M$. ...

  10. Improvement of the basis for the solution of the Dirac equation in Cassini coordinates

    Science.gov (United States)

    Hahn, W.; Artemyev, A. N.; Surzhykov, A.

    2017-08-01

    We propose an improvement of the basis for the solution of the stationary two-centre Dirac equation in Cassini coordinates using the finite-basis-set method presented in our earlier article [J. Phys. B 43, 235207 (2010)]. For the calculations in the above article, we constructed the basis for approximating the energy eigenfunctions by using smooth piecewise defined polynomials, called B-splines. In the present article, we report that an analysis of the employed representation of the Dirac matrices shows that the above approximation is not efficient using B-splines only. Therefore, we include basis functions which are defined using functions with step-like behavior instead of B-splines. Thereby, we achieve a significant increase of accuracy of results.

  11. Improvement of the Basis for the Solution of the Dirac Equation in Cassini Coordinates

    CERN Document Server

    Hahn, Walter; Surzhykov, Andrey

    2016-01-01

    We propose an improvement of the basis for the solution of the stationary two-centre Dirac equation in Cassini coordinates using the finite-basis-set method presented in [1]. For the calculations in [1], we constructed the basis for approximating the energy eigenfunctions by using smooth piecewise defined polynomials, called B-splines. In the present article, we report that an analysis of the employed representation of the Dirac matrices shows that the above approximation is not efficient using B-spines only. Therefore, we include basis functions which are defined using functions with step-like behaviour instead of B-splines. Thereby, we achieve a significant increase of accuracy of results as compared to [1].

  12. Acid-base and coordination properties of Meso-substituted porphyrins in nonaqueous solutions

    Science.gov (United States)

    Pukhovskaya, S. G.; Nam, Dao Tkhe; Fien, Chan Ding; Domanina, E. N.; Ivanova, Yu. B.; Semeikin, A. S.

    2017-09-01

    Acid-base and coordination properties of alkyl and aryl meso-substituted porphyrins are studied spectrophotometrically in nonaqueous solutions. It is found that the nature of the substituent greatly affects the basicity of ligands for porphyrins characterized by a flat structure of macrocycle. The electronic effects of substituents have a much weaker influence on the kinetics of complexing. These effects could be due to the opposite orientation of some factors: an increase in the basicity and stability of the N-H bonds of porphyrin reaction centers. Dissociation constants p K b of the cationic forms of meso-substituted derivatives of porphyrin are measured. The values of p K b are in good agreement with classic concepts of the nature of substituents, particularly those indirectly included in the macrocycle through phenyl buffer rings.

  13. Exraction and separation of CERIUM(IV)/FLUORINE in fluoride-bearing cerium sulfate solution with fluoride coordination agent

    OpenAIRE

    Li, Y; J. G. He; X. X. Xue; Ru, H. Q.; X. W. Huang; Yang, H.

    2014-01-01

    In this paper the extraction and separation of cerium/fluorine in fluoride-bearing cerium sulfate solution with fluoride coordination agent has been studied. The UV-vis spectra suggest that Zr6+ and Al3+ can scrub the F- from [CeF2] 2+ complex. The separation and conductivity studies show that aluminum salt is the most suitable fluoride coordination agent, and an ion-exchange reaction is involved between Ce4+/ [CeF2] 2+ and hydrogen ion.

  14. HEMO2life as a protective additive to Celsior solution for static storage of donor hearts prior to transplantation.

    Science.gov (United States)

    Teh, Elaine S; Zal, Franck; Polard, Valérie; Menasché, Philippe; Chambers, David J

    2017-06-01

    Prior to heart transplantation, static storage of donor hearts is currently limited to 4-5 h, despite profound hypothermia (4-8 °C). Because heart transplantation is an emergency procedure, improved protection to extend safe storage duration would be advantageous. We investigated whether the naturally respiratory pigment HEMO2life(®), which is effective at hypothermia for the passive release of oxygen via oxygen gradient, could improve long-term preservation. Isolated Langendorff-perfused rat hearts (n = 12/group) were equilibrated (20 min) and function (left ventricular developed pressure: LVDP) measured by intraventricular balloon before arrest with cold (7.5 °C) Celsior(®) solution, either alone (control) or with the addition of HEMO2life(®) (Hemarina SA, Morlaix, France) at 1 g/L. Cold storage lasted 8 h prior to reperfusion (60 min) and recovery (as % of pre-ischemic function) was assessed. Hearts (minced and homogenized) were also assessed by TTC staining as a measure of viability and two hearts from each group were sliced and assessed by TTC staining for infarct size. Values are expressed as mean ± standard error of mean and analyzed by Student's t-test. Hearts recovered rapidly in both groups to a plateau by 20 min of reperfusion; control and HEMO2life(®) final recovery (60 min) was 45 ± 2% and 57 ± 1% (P natural oxygen releasing pigment HEMO2life(®) to Celsior(®) preservation solution significantly improved post-ischemic recovery of heart function. This additive may have major therapeutic potential for clinical heart transplantation.

  15. Supramolecular coordination chemistry in aqueous solution: lanthanide ion-induced triple helix formation.

    Science.gov (United States)

    Lessmann, J J; Horrocks, W D

    2000-07-24

    The self-assembly of dinuclear triple helical lanthanide ion complexes (helicates), in aqueous solution, is investigated utilizing laser-induced, lanthanide luminescence spectroscopy. A series of dinuclear lanthanide (III) helicates (Ln(III)) based on 2,6-pyridinedicarboxylic acid (dipicolinic acid, dpa) coordinating units was synthesized by linking two dpa moieties using the organic diamines (1R,2R)-diaminocyclohexane (chxn-R,R) and 4,4'-diaminodiphenylmethane (dpm). Luminescence excitation spectroscopy of the Eu3+ 7F0-->5D0 transition shows the apparent cooperative formation of neutral triple helical complexes in aqueous solution, with a [Eu2L3] stoichiometry. Eu3+ excitation peak wavelengths and excited-state lifetimes correspond to those of the [Eu(dpa)3]3- model complex. CD studies of the Nd(III) helicate Nd2(dpa-chxn-R,R)3 reveal optical activity of the f-f transitions, indicating that the chiral linking group induces a stable chirality at the metal ion center. Molecular mechanics calculations using CHARMm suggest that the delta delta configuration at the Nd3+ ion centers is induced by the chxn-R,R linker. Stability constants were determined for both ligands with Eu3+, yielding identical results: log K = 31.6 +/- 0.2 (K in units of M-4). Metal-metal distances calculated from Eu3+-->Nd3+ energy-transfer experiments show that the complexes have metal-metal distances close to those calculated by molecular modeling. The fine structure in the Tb3+ emission bands is consistent with the approximate D3 symmetry as anticipated for helicates.

  16. Characterization of HMPA-Coordinated Titanium(III) Species in Solutions of Zinc-Reduced Titanocene Dihalides

    DEFF Research Database (Denmark)

    Larsen, Jens; Juel Enemærke, Rasmus; Daasbjerg, Kim

    2006-01-01

    The effect of adding HMPA to THF solutions of metal-reduced titanocene dihalides (Cp2TiX2) has been investigated by means of cyclic voltammetry and kinetic measurements. It is shown that the high coordination affinity of HMPA toward the titanium nucleus results in the formation of a mixture...

  17. Identification of Copper(II) Complexes in Aqueous Solution by Electron Spin Resonance: An Undergraduate Coordination Chemistry Experiment.

    Science.gov (United States)

    Micera, G.; And Others

    1984-01-01

    Background, procedures, and results are provided for an experiment which examines, through electron spin resonance spectroscopy, complex species formed by cupric and 2,6-dihydroxybenzoate ions in aqueous solutions. The experiment is illustrative of several aspects of inorganic and coordination chemistry, including the identification of species…

  18. A dual coordinate system finite difference method for forward and inverse solutions of the volume conductor problem in neurology.

    Science.gov (United States)

    Ouyang, S; Maynard, D E

    1997-03-01

    Finite difference methods for the volume conductor problem have used a single coordinate system for the mesh and made approximations of Laplace's equation. This method is simple but has two major problems. Firstly, to deal with boundary conditions properly, the normal potential gradient at the boundary must be known. However it is complicated to compute at a curved surface point. Secondly, for an inverse solution the equation on a curved boundary is difficult to reverse since more than one inner mesh node appears in the approximation equation for each surface point. The new method developed in this paper is a dual coordinate system. One system serves as a frame mesh, the other is a sub-coordinate system in which surface points become mesh points (regular nodes). The equation at each surface point is then directly reversible since only one inner point appears in the equation. The forward solution is applied to both centric and eccentric bone models and uses the conventional successive over-relaxation (SOR) method. Noise is added to this solution for input to the inverse procedure which is a direct step-in non-iterative method. Low pass filtering was effective in reducing the effects of noise. In the examples given, only one coordinate subsystem is used but, for complex shape boundaries, multiple subsystems would be necessary.

  19. Solution-reaction Calorimetric Study of Coordination Compounds of Rare Earth Perchlorates with Alanine and Imidazole

    Institute of Scientific and Technical Information of China (English)

    ZHAO, Yan-Ru(赵艳茹); HOU, An-Xin(侯安新); DONG, Jia-Xin(董家新); ZHAO, Shun-Sheng(赵顺省); LIU, Yi(刘义); QU, Song-Sheng(屈松生)

    2004-01-01

    Two coordination compounds of rare earth perchlorates with alanine and imidazole, [RE(Ala)n(Im)(H2O)](ClO4)3(s) (RE=La, n=3; RE=Nd, n=2), have been prepared and characterized. The standard molar enthalpies of reaction for the following two reactions, LaCL·7H2O(s)+3Ala(s)+Im(s)+3NaClO4(s)=[La(Ala).(Im)(H2O)]-(ClO4)3(s)+3NaCl(s)+6H2O(I)(1)and NdCl3·6H2O(s)+2Ala(s)+2Ala(s)+Im(s)+3NaClO4(s)=[Nd(Ala)2(Im)(H2O)]-(ClO4)3(s)+3NaCl(s)+5H2O(l) (2), were determined by solution-reaction calorimetry, at T=298.15 K, as 36.168 ±0.642kJ·mol-1 and 48.590±0.934kJ·mol-1 respectively. From the results and other auxiliary quantities, the standard molar enthalpies of formation of [La(Ala)3(Im)(H2O)](ClO4)3(s) and [Nd(Ala)2(Im)(H2O)] (ClO4)3(s) were derived,△fH(-)m{[La(Ala).(Im)(H2O)](ClO4)3,s}=(-2984.8±1.0)kJ·mol-1 and △fH(-)m{[Nd(Ala).(Im)(H2O)]-(ClO4)3,s}=(-2387.8±0.8)kJ·mol-1, respectively.

  20. Exraction and separation of CERIUM(IV/FLUORINE in fluoride-bearing cerium sulfate solution with fluoride coordination agent

    Directory of Open Access Journals (Sweden)

    Y. Li

    2014-07-01

    Full Text Available In this paper the extraction and separation of cerium/fluorine in fluoride-bearing cerium sulfate solution with fluoride coordination agent has been studied. The UV-vis spectra suggest that Zr6+ and Al3+ can scrub the F- from [CeF2] 2+ complex. The separation and conductivity studies show that aluminum salt is the most suitable fluoride coordination agent, and an ion-exchange reaction is involved between Ce4+/ [CeF2] 2+ and hydrogen ion.

  1. An approximate analytical solution of free convection problem for vertical isothermal plate via transverse coordinate Taylor expansion

    CERN Document Server

    Leble, Sergey

    2013-01-01

    The model under consideration is based on approximate analytical solution of two dimensional stationary Navier-Stokes and Fourier-Kirchhoff equations. Approximations are based on the typical for natural convection assumptions: the fluid noncompressibility and Bousinesq approximation. We also assume that ortogonal to the plate component (x) of velocity is neglectible small. The solution of the boundary problem is represented as a Taylor Series in $x$ coordinate for velocity and temperature which introduces functions of vertical coordinate (y), as coefficients of the expansion. The correspondent boundary problem formulation depends on parameters specific for the problem: Grashoff number, the plate height (L) and gravity constant. The main result of the paper is the set of equations for the coefficient functions for example choice of expansion terms number. The nonzero velocity at the starting point of a flow appears in such approach as a development of convecntional boundary layer theory formulation.

  2. THE THREE-DIMENSIONAL FUNDAMENTAL SOLUTION TO STOKES FLOW IN THE OBLATE SPHEROIDAL COORDINATES WITH APPLICATIONS TO MULTIPLES SPHEROID PROBLEMS

    Institute of Scientific and Technical Information of China (English)

    庄宏; 严宗毅; 吴望一

    2002-01-01

    A new three-dimensional fundamental solution to the Stokes flow was proposedby transforming the solid harmonic functions in Lamb' s solution into expressions in terms ofthe oblate spheroidal coordinates. These fundamental solutions are advantageous in treatingflows past an arbitrary number of arbitrarily positioned and oriented oblate spheroids. Theleast squares technique was adopted herein so that the convergence difficulties oftenencountered in solving three-dimensional problems were completely avoided. The examplesdemonstrate that present approach is highly accurate, consistently stable andcomputationally efficient.The oblate spheroid may be used to model a variety of particle shapes between acircular disk and a sphere. For the first time, the effect of various geometric factors on theforces and torques exerted on two oblate spheroids were systematically studied by using theproposed fundamental solutions. The generality of this approach was illustrated by twoproblems of three spheroids.

  3. A review on the solution of Grad-Shafranov equation in the cylindrical coordinates based on the Chebyshev collocation technique

    Science.gov (United States)

    Amerian, Z.; Salem, M. K.; Salar Elahi, A.; Ghoranneviss, M.

    2017-03-01

    Equilibrium reconstruction consists of identifying, from experimental measurements, a distribution of the plasma current density that satisfies the pressure balance constraint. Numerous methods exist to solve the Grad-Shafranov equation, describing the equilibrium of plasma confined by an axisymmetric magnetic field. In this paper, we have proposed a new numerical solution to the Grad-Shafranov equation (an axisymmetric, magnetic field transformed in cylindrical coordinates solved with the Chebyshev collocation method) when the source term (current density function) on the right-hand side is linear. The Chebyshev collocation method is a method for computing highly accurate numerical solutions of differential equations. We describe a circular cross-section of the tokamak and present numerical result of magnetic surfaces on the IR-T1 tokamak and then compare the results with an analytical solution.

  4. A review on the solution of Grad–Shafranov equation in the cylindrical coordinates based on the Chebyshev collocation technique

    Indian Academy of Sciences (India)

    Z AMERIAN; M K SALEM; A SALAR ELAHI; M GHORANNEVISS

    2017-03-01

    Equilibrium reconstruction consists of identifying, from experimental measurements, a distribution of the plasma current density that satisfies the pressure balance constraint. Numerous methods exist to solve the Grad–Shafranov equation, describing the equilibrium of plasma confined by an axisymmetric magnetic field. In this paper, we have proposed a new numerical solution to the Grad–Shafranov equation (an axisymmetric,magnetic field transformed in cylindrical coordinates solved with the Chebyshev collocation method) when the source term (current density function) on the right-hand side is linear. The Chebyshev collocation method is a method for computing highly accurate numerical solutions of differential equations. We describe a circular crosssection of the tokamak and present numerical result of magnetic surfaces on the IR-T1 tokamak and then compare the results with an analytical solution.

  5. Characterization of HMPA-Coordinated Titanium(III) Species in Solutions of Zinc-Reduced Titanocene Dihalides

    DEFF Research Database (Denmark)

    Larsen, Jens; Juel Enemærke, Rasmus; Daasbjerg, Kim

    2006-01-01

    The effect of adding HMPA to THF solutions of metal-reduced titanocene dihalides (Cp2TiX2) has been investigated by means of cyclic voltammetry and kinetic measurements. It is shown that the high coordination affinity of HMPA toward the titanium nucleus results in the formation of a mixture...... of mainly Cp2Ti(hmpa)+, Cp2Ti(hmpa)2+, and Cp2TiX(hmpa) with an increase in the amount of ionic constituents as X is changed from Cl to Br and I. The oxidation potentials of all HMPA-coordinated TiIII species are more negative than those of the uncoordinated analogues, but nevertheless an inverse...

  6. Theoretical study of the Pb(II)-catechol system in dilute aqueous solution: Complex structure and metal coordination sphere determination

    Science.gov (United States)

    Lapouge, Christine; Cornard, Jean-Paul

    2010-04-01

    We investigated the unknown interaction of Pb(II) with catechol ligand in diluted aqueous solution by electronic spectroscopies combined with quantum chemical calculations. The aim of this work is the determination of the complete structure of the complex formed and particularly the metal coordination sphere. Three successive steps have been necessary to reach this goal: (i) the comparison of the experimental electronic absorption spectrum with theoretical spectra calculated from various hypothetical structures, (ii) complexation reaction pathways calculations in vacuum and with taking into account the solvent effects and finally (iii) the fluorescence emission wavelength calculations. All these investigations led to identify a monodentate complex with the monodeprotonated ligand, in which the Pb atom presents a coordination number of five. The formula of the complex is [Pb(Hcat)(HO)4]mono+.

  7. Effect of solution annealing on properties of used reformer centrifugally casted tubes prior to repair by welding

    Directory of Open Access Journals (Sweden)

    B. Mateša

    2014-01-01

    Full Text Available The specimens of damaged tubes, ASTM A297 HK 40, are repaired by welding. Before repairing, solution annealing is used as a procedure for properties restitution. This paper explores the influence of used solution annealing procedure (1 050 şC / 2h on mechanical and micro-structural properties. The emphasis is put on specific procedures at repair by welding.

  8. Origin and solution attributions of responsibility for wife abuse: effects of outcome severity, prior history, and sex of subject.

    Science.gov (United States)

    Sugarman, D B; Cohn, E S

    1986-01-01

    The purpose of the present study was to determine the effect of sex differences and seriousness of the abuse situation on observers' attributions of responsibility for origin and solution to both partners in a couple. Male and female undergraduate students (N = 354) read a vignette about a wife abuse incident. The results supported the victim activation hypothesis, with wives being held more responsible for the solution than for the origin of the problem. In contrast, husbands were held more responsible for the origin than for the solution to the problem. Overall, there were sex differences for attributions of responsibility to the husband but not for those to the wife. Women were more likely than men to attribute origin and solution responsibility to the husband. There was no clear support for the effects of the seriousness of the abuse situation. Husbands were attributed more control over the problem's solution than were wives.

  9. Exact Solution of the Curved Dirac Equation in Polar Coordinates: Master Function Approach

    Directory of Open Access Journals (Sweden)

    H. Panahi

    2015-01-01

    Full Text Available We show that the (2+1 curved Dirac equation in polar coordinates can be transformed into Schrodinger-like differential equation for upper spinor component. We compare this equation with the Schrodinger equation derived from shape invariance property of second order differential equations of mathematical physics. This formalism enables us to determine the electrostatic potential and relativistic energy in terms of master function and corresponding weight function. We also obtain the spinor wave function in terms of orthogonal polynomials.

  10. Efficacy, safety, and improved tolerability of travoprost BAK-free ophthalmic solution compared with prior prostaglandin therapy

    Directory of Open Access Journals (Sweden)

    J Charles Henry

    2008-10-01

    Full Text Available J Charles Henry1, James H Peace2, Jeanette A Stewart3,4, William C Stewart3,41Little Rock Eye Clinic, Little Rock, AR, USA; 2Diabetic Eye Medical Clinic, Inglewood, CA, USA; 3PRN Pharmaceutical Research Network, LLC, Dallas,TX, USA; 4Carolina Eye Institute, University of South Carolina, School of Medicine, Columbia, SC, USAPurpose: To evaluate the efficacy, safety and tolerability of changing to travoprost BAK-free from prior prostaglandin therapy in patients with primary open-angle glaucoma or ocular hypertension.Design: Prospective, multi-center, historical control study.Methods: Patients treated with latanoprost or bimatoprost who needed alternative therapy due to tolerability issues were enrolled. Patients were surveyed using the Ocular Surface Disease Index (OSDI to evaluate OSD symptoms prior to changing to travoprost BAK-free dosed once every evening. Patients were re-evaluated 3 months later.Results: In 691 patients, travoprost BAK-free demonstrated improved mean OSDI scores compared to either latanoprost or bimatoprost (p < 0.0001. Patients having any baseline OSD symptoms (n = 235 demonstrated significant improvement after switching to travoprost BAK-free (p < 0.0001. In 70.2% of these patients, symptoms were reduced in severity by at least 1 level. After changing medications to travoprost BAK-free, mean intraocular pressure (IOP was significantly decreased (p < 0.0001. Overall, 72.4% preferred travoprost BAK-free (p < 0.0001, travoprost BAK-free vs prior therapy. Travoprost BAK-free demonstrated less conjunctival hyperemia than either prior therapy (p < 0.0001.Conclusions: Patients previously treated with a BAK-preserved prostaglandin analog who are changed to travoprost BAK-free have clinically and statistically significant improvement in their OSD symptoms, decreased hyperemia, and equal or better IOP control.Keywords: glaucoma, prostaglandin analog, travoprost, latanoprost, bimatoprost, preservative, benzalkonium chloride

  11. Direct numerical solution of the Lippmann-Schwinger equation in coordinate space without partial-wave decomposition

    Science.gov (United States)

    Kuruoǧlu, Zeki C.

    2016-11-01

    Direct numerical solution of the coordinate-space integral-equation version of the two-particle Lippmann-Schwinger (LS) equation is considered without invoking the traditional partial-wave decomposition. The singular kernel of the three-dimensional LS equation in coordinate space is regularized by a subtraction technique. The resulting nonsingular integral equation is then solved via the Nystrom method employing a direct-product quadrature rule for three variables. To reduce the computational burden of discretizing three variables, advantage is taken of the fact that, for central potentials, the azimuthal angle can be integrated out, leaving a two-variable reduced integral equation. A regularization method for the kernel of the two-variable integral equation is derived from the treatment of the singularity in the three-dimensional equation. A quadrature rule constructed as the direct product of single-variable quadrature rules for radial distance and polar angle is used to discretize the two-variable integral equation. These two- and three-variable methods are tested on the Hartree potential. The results show that the Nystrom method for the coordinate-space LS equation compares favorably in terms of its ease of implementation and effectiveness with the Nystrom method for the momentum-space version of the LS equation.

  12. Uranyl-glycine-water complexes in solution: comprehensive computational modeling of coordination geometries, stabilization energies, and luminescence properties.

    Science.gov (United States)

    Su, Jing; Zhang, Kai; Schwarz, W H Eugen; Li, Jun

    2011-03-21

    Comprehensive computational modeling of coordination structures, thermodynamic stabilities, and luminescence spectra of uranyl-glycine-water complexes [UO(2)(Gly)(n)aq(m)](2+) (Gly = glycine, aq = H(2)O, n = 0-2, m = 0-5) in aqueous solution has been carried out using relativistic density functional approaches. The solvent is approximated by a dielectric continuum model and additional explicit water molecules. Detailed pictures are obtained by synergic combination of experimental and theoretical data. The optimal equatorial coordination numbers of uranyl are determined to be five. The energies of several complex conformations are competitively close to each other. In non-basic solution the most probable complex forms are those with two water ligands replaced by the bidentate carboxyl groups of zwitterionic glycine. The N,O-chelation in non-basic solution is neither entropically nor enthalpically favored. The symmetric and antisymmetric stretch vibrations of the nearly linear O-U-O unit determine the luminescence features. The shapes of the vibrationally resolved experimental solution spectra are reproduced theoretically with an empirically fitted overall line-width parameter. The calculated luminescence origins correspond to thermally populated, near-degenerate groups of the lowest electronically excited states of (3)Δ(g) and (3)Φ(g) character, originating from (U-O)σ(u) → (U-5f)δ(u),ϕ(u) configurations of the linear [OUO](2+) unit. The intensity distributions of the vibrational progressions are consistent with U-O bond-length changes around 5 1/2 pm. The unusually high intensity of the short wavelength foot is explained by near-degeneracy of vibrationally and electronically excited states, and by intensity enhancement through the asymmetric O-U-O stretch mode. The combination of contemporary computational chemistry and experimental techniques leads to a detailed understanding of structures, thermodynamics, and luminescence of actinide compounds, including

  13. Prioritizing urban sustainability solutions: coordinated approaches must incorporate scale-dependent built environment induced effects

    Science.gov (United States)

    Georgescu, M.; Chow, W. T. L.; Wang, Z. H.; Brazel, A.; Trapido-Lurie, B.; Roth, M.; Benson-Lira, V.

    2015-06-01

    Because of a projected surge of several billion urban inhabitants by mid-century, a rising urgency exists to advance local and strategically deployed measures intended to ameliorate negative consequences on urban climate (e.g., heat stress, poor air quality, energy/water availability). Here we highlight the importance of incorporating scale-dependent built environment induced solutions within the broader umbrella of urban sustainability outcomes, thereby accounting for fundamental physical principles. Contemporary and future design of settlements demands cooperative participation between planners, architects, and relevant stakeholders, with the urban and global climate community, which recognizes the complexity of the physical systems involved and is ideally fit to quantitatively examine the viability of proposed solutions. Such participatory efforts can aid the development of locally sensible approaches by integrating across the socioeconomic and climatic continuum, therefore providing opportunities facilitating comprehensive solutions that maximize benefits and limit unintended consequences.

  14. Determining the solution space for a coordinated whole body movement in a noisy environment: application to the upstart in gymnastics.

    Science.gov (United States)

    Hiley, Michael J; Yeadon, Maurice R

    2014-08-01

    The upstart is a fundamental skill in gymnastics, requiring whole body coordination to transfer the gymnast from a swing beneath the bar to a support position above the bar. The aim of this study was to determine the solution space within which a gymnast could successfully perform an upstart. A previous study had shown that the underlying control strategy for the upstart could be accounted for by maximizing the likelihood of success while operating in a noisy environment. In the current study, data were collected on a senior gymnast and a computer simulation model of a gymnast and bar was used to determine the solution space for maximizing success while operating in a noisy environment. The effects of timing important actions, gymnast strength, and movement execution noise on the success of the upstart were then systematically determined. The solution space for the senior gymnast was relatively large. Decreasing strength and increasing movement execution noise reduced the size of the solution space. A weaker gymnast would have to use a different technique than that used by the senior gymnast to produce an acceptable success rate.

  15. Solid-state and solution-state coordination chemistry of lanthanide(III) complexes with α-hydroxyisobutyric acid.

    Science.gov (United States)

    Chen, Xiao-Yan; Goff, George S; Ewing, William C; Scott, Brian L; Runde, Wolfgang

    2012-12-17

    Despite the wide range of applications of α-hydroxyisobutyric acid (HIBA) in biochemical processes, pharmaceutical formulations, and group and elemental separations of lanthanides and actinides, the structures and geometries of lanthanide-HIBA complexes are still not well understood. We reacted HIBA with lanthanides in aqueous solution at pH = 5 and synthesized 14 lanthanide-HIBA complexes of the formula [Ln(HIBA)(2)(H(2)O)(2)](NO(3))·H(2)O (Ln = La (1), Ce (2), Pr (3), Nd (4), Sm (5), Eu (6), Gd (7), Tb (8), Dy (9), Ho (10), Er (11), Tm (12), Yb (13), Lu (14)), isolating single crystals (1-7, 10, and 11) and powders (8, 9, and 12-14). Both single-crystal and powder X-ray diffraction studies reveal a two-dimensional extended structure across the entire lanthanide series. The environment around the eight-coordinated Ln(III) atom is best described as a distorted dodecahedron, where HIBA acts as a monoanionic tridentate ligand with one carboxylato oxygen atom and one hydroxyl oxygen atom chelating to one Ln(III) center. The carboxylato oxygen atom from a second HIBA ligand bridges to a neighboring Ln(III) atom to form a two-dimensional extended structure. While the coordination mode for HIBA is identical across the lanthanide series, three different structure types are found for La, Ce-Ho, and Er-Lu. Solution characterization using (13)C NMR further confirmed a single solution complex under the crystallization conditions. Raman and UV-vis-NIR absorbance and diffuse reflectance spectra of HIBA-Ln(III) complexes were also measured.

  16. New insights into the coordination chemistry and molecular structure of copper(II) histidine complexes in aqueous solutions.

    Science.gov (United States)

    Mesu, J Gerbrand; Visser, Tom; Soulimani, Fouad; van Faassen, Ernst E; de Peinder, Peter; Beale, Andrew M; Weckhuysen, Bert M

    2006-03-06

    Aqueous solutions of Cu2+/histidine (his) (1:2) have been analyzed in parallel with infrared, Raman, ultraviolet/visible/near-infrared, electron spin resonance, and X-ray absorption spectroscopy in the pH range from 0 to 10. Comprehensive interpretation of the data has been used to extract complementary structural information in order to determine the relative abundance of the different complexes. The formation of six different, partly coexisting species is proposed. Structural proposals from literature have been unambiguously confirmed, refined, or, in several cases, corrected. At highly acidic conditions, Cu2+ and his are present as free ions, but around pH = 2, coordination starts via the deprotonated carboxylic acid group. This results in the intermediate species Cu2+[H3his+(Oc)] and Cu2+[H3his+(Oc)]2. The coordination via Oc is attended with a drop in the pKa value of the other receptor groups resulting in a concomitant conversion to the bidentates Cu2+[H2his0(Oc,Nam)] and Cu2+[H2his0(Oc,Nam)]2, with the latter being dominant at pH = 3.5. Coordination of the imidazole ring begins around pH = 3 and leads to the formation of the mixed ligand complexes Cu2+[H2his0(Oc,Nam)][Hhis-(Oc,Nam,Nim)] and Cu2+[Hhis-(Nam,Nim)][Hhis-(Oc,Nam,Nim)] around pH = 5. It is demonstrated that coordination of the imidazole ring occurs predominantly via the N(pi) atom. At pH > 7, the double-tridentate ligand complex Cu2+[Hhis-(Oc,Nam,Nim)]2 is the major species with the N atoms in the equatorial plane and the O atoms in the axial position. This complex decomposes at pH > 10 into a copper oxide/hydroxide precipitate. The overall results provide a consistent picture of the mechanism that drives the coordination and complex formation of the Cu2+/his system.

  17. SOLUTION OF GENERALIZED COORDINATE FOR WARPING FOR NATURALLY CURVED AND TWISTED BEAMS

    Institute of Scientific and Technical Information of China (English)

    虞爱民; 易明

    2004-01-01

    A theoretical method for static analysis of naturally curved and twisted beams under complicated loads was presented, with special attention devoted to the solving process of governing equations which take into account the effects of torsion-related warping as well as transverse shear deformations. These governing equations, in special cases, can be readily solved and yield the solutions to the problem. The solutions can be used for the analysis of the beams, including the calculation of various internal forces, stresses, strains and displacements. The present theory will be used to investigate the stresses and displacements of a plane curved beam subjected to the action of horizontal and vertical distributed loads. The numerical results obtained by the present theory are found to be in very good agreement with the results of the FEM results. Besides, the present theory is not limited to the beams with a double symmetric cross-section, it can also be extended to those with arbitrary cross-sectional shape.

  18. Electromagnetic Field in de Sitter Expanding Universe: Majorana--Oppenheimer Formalism, Exact Solutions in non-Static Coordinates

    CERN Document Server

    Veko, O V; Sitenko, Yu A; Ovsiyuk, E M; Red'kov, V M

    2014-01-01

    Tetrad-based generalized complex formalism by Majorana--Oppenheimer is applied to treat electromagnetic field in extending de Sitter Universe in on-static spherically-symmetric coordinates. With the help of Wigner D-functions, we separate angular dependence in the complex vector field E_{j}(t,r)+i B_{j}(t,r) from (t,r)-dependence. The separation parameter arising here instead of frequency \\omega in Minkowski space-time is quantized, non-static geometry of the de Sitter model leads to definite dependence of electromagnetic modes on the time variable. Relation of 3-vector complex approach to 10-dimensional Duffin-Kemmer-Petiau formalism is considered. On this base, the electromagnetic waves of magnetic and electric type have been constructed in both approaches. In Duffin-Kemmer-Petiau approach, there are constructed gradient-type solutions in Lorentz gauge.

  19. Photoprocesses of coordination compounds and dyes in solution and nanoporous materials: Evolution from milliseconds to femtoseconds

    Indian Academy of Sciences (India)

    P Natarajan; K Duraimurugan; K Senthil Kumar

    2011-09-01

    The photoredox reactions of cobalt(III), nickel(II) complexes and organic dyes are reviewed with particular emphasis on using flash photolysis methods to identify the transients in the time scale from milliseconds to subpicoseconds. The excitation flash radiation initially was limited to flash lamps with a time resolution to study the decay of the excited states and the fast reactions of photo produced transients in milliseconds and microseconds. Some of the photolysis reactions investigated provide details in real time including the thermal reactions of molecular oxygen with cobalt(II) amine systems and the cobalt (III) alkyl complex formation on photolysis of cobalt(III) aminoacid complexes. Photoredox reactions of thiazine and safranine dyes are investigated using time resolved absorption and emission techniques in solution and on encapsulation in micro and mesoporous host materials. Picosecond and femtosecond diffuse reflectance fluorescence investigations in the porous solid host materials show intramolecular proton transfer reactions of the dyes and deprotonation of the dyes in the excited states. Photosensitization of nanoparticles of semiconductors, anatase TiO2 and ZnO by the excited states of dyes in meso and microporous silicate hosts is investigated using pico and femtosecond fluorescence and transient absorptions techniques and the results are reviewed.

  20. X-ray absorption spectroscopy of strontium(II) coordination. I. Static and thermal disorder in crystalline, hydrated, and precipitated solids and in aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    O' Day, P.A.; Newville, M.; Neuhoff, P.S.; Sahai, N.; Carroll, S.A.

    2000-02-15

    Detailed analyses of crystalline, hydrated, and precipitated strontium compounds and an aqueous strontium solution by synchrotron extended X-ray adsorption fine structure (EXAFS) were used to quantify local thermal and static disorder and the characterize strontium coordination in a variety of oxygen-ligated bonding environments. Comparison of strontium structural coordination determined in this and previous studies suggest that previous EXAFS determinations of hydrated strontium may have underestimated first-shell interatomic distances and coordination numbers because minor contributions to the EXAFS phase-shift and amplitude functions were not accounted for, either theoretically or empirically.

  1. Solid-state and solution-state coordination chemistry of lanthanide(III) complexes with (pyrazol-1-yl)acetic acid.

    Science.gov (United States)

    Chen, Xiao-Yan; Goff, George S; Scott, Brian L; Janicke, Michael T; Runde, Wolfgang

    2013-03-18

    As a precursor of carboxyl-functionalized task-specific ionic liquids (TSILs) for f-element separations, (pyrazol-1-yl)acetic acid (L) can be deprotonated as a functionalized pyrazolate anion to coordinate with hard metal cations. However, the coordination chemistry of L with f-elements remains unexplored. We reacted L with lanthanides in aqueous solution at pH = 5 and synthesized four lanthanide complexes of general formula [Ln(L)3(H2O)2]·nH2O (1, Ln = La, n = 2; 2, Ln = Ce, n = 2; 3, Ln = Pr, n = 2; 4, Ln = Nd, n = 1). All complexes were characterized by single crystal X-ray diffraction analysis revealing one-dimensional chain formations. Two distinct crystallographic structures are governed by the different coordination modes of carboxylate groups in L: terminal bidentate and bridging tridentate (1-3); terminal bidentate, bridging bidentate, and tridentate coordination in 4. Comparison of the solid state UV-vis-NIR diffuse reflectance spectra with solution state UV-vis-NIR spectra suggests a different species in solution and solid state. The different coordination in solid state and solution was verified by distinctive (13)C NMR signals of the carboxylate groups in the solid state NMR.

  2. Global Positioning System (GPS) survey of Augustine Volcano, Alaska, August 3-8, 2000: data processing, geodetic coordinates and comparison with prior geodetic surveys

    Science.gov (United States)

    Pauk, Benjamin A.; Power, John A.; Lisowski, Mike; Dzurisin, Daniel; Iwatsubo, Eugene Y.; Melbourne, Tim

    2001-01-01

    Between August 3 and 8,2000,the Alaska Volcano Observatory completed a Global Positioning System (GPS) survey at Augustine Volcano, Alaska. Augustine is a frequently active calcalkaline volcano located in the lower portion of Cook Inlet (fig. 1), with reported eruptions in 1812, 1882, 1909?, 1935, 1964, 1976, and 1986 (Miller et al., 1998). Geodetic measurements using electronic and optical surveying techniques (EDM and theodolite) were begun at Augustine Volcano in 1986. In 1988 and 1989, an island-wide trilateration network comprising 19 benchmarks was completed and measured in its entirety (Power and Iwatsubo, 1998). Partial GPS surveys of the Augustine Island geodetic network were completed in 1992 and 1995; however, neither of these surveys included all marks on the island.Additional GPS measurements of benchmarks A5 and A15 (fig. 2) were made during the summers of 1992, 1993, 1994, and 1996. The goals of the 2000 GPS survey were to:1) re-measure all existing benchmarks on Augustine Island using a homogeneous set of GPS equipment operated in a consistent manner, 2) add measurements at benchmarks on the western shore of Cook Inlet at distances of 15 to 25 km, 3) add measurements at an existing benchmark (BURR) on Augustine Island that was not previously surveyed, and 4) add additional marks in areas of the island thought to be actively deforming. The entire survey resulted in collection of GPS data at a total of 24 sites (fig. 1 and 2). In this report we describe the methods of GPS data collection and processing used at Augustine during the 2000 survey. We use this data to calculate coordinates and elevations for all 24 sites surveyed. Data from the 2000 survey is then compared toelectronic and optical measurements made in 1988 and 1989. This report also contains a general description of all marks surveyed in 2000 and photographs of all new marks established during the 2000 survey (Appendix A).

  3. Alkoxide coordination of iron(III) protoporphyrin IX by antimalarial quinoline methanols: a key interaction observed in the solid-state and solution.

    Science.gov (United States)

    Gildenhuys, Johandie; Sammy, Chandre J; Müller, Ronel; Streltsov, Victor A; le Roex, Tanya; Kuter, David; de Villiers, Katherine A

    2015-10-14

    The quinoline methanol antimalarial drug mefloquine is a structural analogue of the Cinchona alkaloids, quinine and quinidine. We have elucidated the single crystal X-ray diffraction structure of the complexes formed between racemic erythro mefloquine and ferriprotoporphyrin IX (Fe(iii)PPIX) and show that alkoxide coordination is a key interaction in the solid-state. Mass spectrometry confirms the existence of coordination complexes of quinine, quinidine and mefloquine to Fe(iii)PPIX in acetonitrile. The length of the iron(iii)-O bond in the quinine and quinidine complexes as determined by Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy unequivocally confirms that coordination of the quinoline methanol compounds to Fe(iii)PPIX occurs in non-aqueous aprotic solution via their benzylic alkoxide functional group. UV-visible spectrophotometric titrations of the low-spin bis-pyridyl-Fe(iii)PPIX complex with each of the quinoline methanol compounds results in the displacement of a single pyridine molecule and subsequent formation of a six-coordinate pyridine-Fe(iii)PPIX-drug complex. We propose that formation of the drug-Fe(iii)PPIX coordination complexes is favoured in a non-aqueous environment, such as that found in lipid bodies or membranes in the malaria parasite, and that their existence may contribute to the mechanism of haemozoin inhibition or other toxicity effects that lead ultimately to parasite death. In either case, coordination is a key interaction to be considered in the design of novel antimalarial drug candidates.

  4. Seven-coordinate anion complex with a tren-based urea: binding discrepancy of hydrogen sulfate in solid and solution states.

    Science.gov (United States)

    Pramanik, Avijit; Thompson, Bethtrice; Hayes, Trina; Tucker, Kimberly; Powell, Douglas R; Bonnesen, Peter V; Ellis, Erick D; Lee, Ken S; Yu, Hongtao; Hossain, Md Alamgir

    2011-06-21

    Structural characterization of a hydrogen sulfate complex with a tren-based urea suggests that the anion is coordinated with six NH···O bonds (d(N···O) = 2.857 (3) to 3.092 (3) Å) and one OH···O bond (d(O···O) = 2.57 (2) Å) from three receptors; however, in solution the anion is bound within the pseudo-cavity of one receptor.

  5. Seven-coordinate anion complex with a tren-based urea: Binding discrepancy of hydrogen sulfate in solid and solution states

    Energy Technology Data Exchange (ETDEWEB)

    Pramanik, Avijit [Jackson State University; Thompson, Bethtrice [Jackson State University; Hayes, Trina [Jackson State University; Tucker, Kimberly [Jackson State University; Powell, Douglas R. [University of Oklahoma, Norman; Bonnesen, Peter V [ORNL; Ellis, Erick D [Jackson State University; Lee, Ken S. [Jackson State University; Yu, Hongtau [Jackson State University; Hossain, Md. Alamgir [Jackson State University

    2011-01-01

    Structural characterization of a hydrogen sulfate complex with a tren-based urea suggests that the anion is coordinated with sixNH Obonds (dN O = 2.857 (3) to 3.092 (3)A ) and one OH O bond (dO O = 2.57 (2) A ) from three receptors; however, in solution the anion is bound within the pseudocavity of one receptor.

  6. A spectroscopic study on the coordination and solution structures of the interaction systems between biperoxidovanadate complexes and the pyrazolylpyridine-like ligands.

    Science.gov (United States)

    Yu, Xian-Yong; Deng, Lin; Zheng, Baishu; Zeng, Bi-Rong; Yi, Pinggui; Xu, Xin

    2014-01-28

    In order to understand the substitution effects of pyrazolylpyridine (pzpy) on the coordination reaction equilibria, the interactions between a series of pzpy-like ligands and biperoxidovanadate ([OV(O2)2(D2O)](-)/[OV(O2)2(HOD)](-), abbrv. bpV) have been explored using a combination of multinuclear ((1)H, (13)C, and (51)V) magnetic resonance, heteronuclear single quantum coherence (HSQC), and variable temperature NMR in a 0.15 mol L(-1) NaCl D2O solution that mimics the physiological conditions. Both the direct NMR data and the equilibrium constants are reported for the first time. A series of new hepta-coordinated peroxidovanadate species [OV(O2)2L](-) (L = pzpy-like chelating ligands) are formed due to several competitive coordination interactions. According to the equilibrium constants for products between bpV and the pzpy-like ligands, the relative affinity of the ligands is found to be pzpy > 2-Ester-pzpy ≈ 2-Me-pzpy ≈ 2-Amide-pzpy > 2-Et-pzpy. In the interaction system between bpV and pzpy, a pair of isomers (Isomers A and B) are observed in aqueous solution, which are attributed to different types of coordination modes between the metal center and the ligands, while the crystal structure of NH4[OV(O2)2(pzpy)]·6H2O (CCDC 898554) has the same coordination structure as Isomer A (the main product for pzpy). For the N-substituted ligands, however, Isomer A or B type complexes can also be observed in solution but the molar ratios of the isomer are reversed (i.e., Isomer B type is the main product). These results demonstrate that when the N atom in the pyrazole ring has a substitution group, hydrogen bonding (from the H atom in the pyrazole ring), the steric effect (from alkyl) and the solvation effect (from the ester or amide group) can jointly affect the coordination reaction equilibrium.

  7. Solution chemistry of a water-soluble eta2-H2 ruthenium complex: evidence for coordinated H2 acting as a hydrogen bond donor.

    Science.gov (United States)

    Szymczak, Nathaniel K; Zakharov, Lev N; Tyler, David R

    2006-12-13

    The ability of an eta2-H2 ligand to participate in intermolecular hydrogen bonding in solution has long been an unresolved issue. Such species are proposed to be key intermediates in numerous important reactions such as the proton-transfer pathway of H2 production by hydrogenase enzymes. We present the synthesis of several new water-soluble ruthenium coordination complexes including an eta2-H2 complex that is surprisingly inert to substitution by water. The existence of dihydrogen hydrogen bonding (DHHB) was experimentally probed by monitoring the chemical shift of H-bonded Ru-(H2) complexes using NMR spectroscopy, by UV-visible spectroscopy, and by monitoring the rotational dynamics of a hydrogen-bonding probe molecule. The results provide strong evidence that coordinated H2 can indeed participate in intermolecular hydrogen bonding to bulk solvent and other H-bond acceptors.

  8. Solution Dynamics of Redox Noninnocent Nitrosoarene Ligands: Mapping the Electronic Criteria for the Formation of Persistent Metal-Coordinated Nitroxide Radicals.

    Science.gov (United States)

    Barnett, Brandon R; Labios, Liezel A; Moore, Curtis E; England, Jason; Rheingold, Arnold L; Wieghardt, Karl; Figueroa, Joshua S

    2015-07-20

    The redox-noninnocence of metal-coordinated C-organo nitrosoarenes has been established on the basis of solid-state characterization techniques, but the solution-phase properties of this class of metal-coordinated radicals have been relatively underexplored. In this report, the solution-phase properties and dynamics of the bis-nitrosobenzene diradical complex trans-Pd(κ(1)-N-PhNO)2(CNAr(Dipp2))2 are presented. This complex, which is best described as containing singly reduced phenylnitroxide radical ligands, is shown to undergo facile nitrosobenzene dissociation in solution to form the metalloxaziridine Pd(η(2)-N,O-PhNO)(CNAr(Dipp2))2 and thus is not a persistent species in solution. An equilibrium between trans-Pd(κ(1)-N-PhNO)2(CNAr(Dipp2))2, Pd(η(2)-N,O-PhNO)(CNAr(Dipp2))2, and free nitrosobenzene is established in solution, with the metalloxaziridine being predominantly favored. Efforts to perturb this equilibrium by the addition of excess nitrosobenzene reveal that the formation of trans-Pd(κ(1)-N-PhNO)2(CNAr(Dipp2))2 is in competition with insertion-type chemistry of Pd(η(2)-N,O-PhNO)(CNAr(Dipp2))2 and is therefore not a viable strategy for the production of a kinetically persistent bis-nitroxide radical complex. Electronic modification of the nitrosoarene framework was explored as a means to generate a persistent trans-Pd(κ(1)-N-ArNO)2(CNAr(Dipp2))2 complex. While most substitution schemes failed to significantly perturb the kinetic lability of the nitrosoarene ligands in the corresponding trans-Pd(κ(1)-N-ArNO)2(CNAr(Dipp2))2 complexes, utilization of para-formyl or para-cyano nitrosobenzene produced bis-nitroxide diradical complexes that display kinetic persistence in solution. The origin of this persistence is rationalized by the ability of para-formyl- and para-cyano-aryl groups to both attenuate the trans effect of the corresponding nitrosoarene and, more importantly, delocalize spin density away from the aryl-nitroxide NO unit. The results

  9. A coordination chemistry study of hydrated and solvated cationic vanadium ions in oxidation states +III, +IV, and +V in solution and solid state

    OpenAIRE

    Krakowiak, Joanna; Lundberg, Daniel; Persson, Ingmar

    2012-01-01

    The coordination chemistry of hydrated and solvated vanadium(III), oxovanadium(IV), and dioxovanadium(V) ions in the oxygen donor solvents water, dimethylsulfoxide (dmso) and N,N′-dimethylpropyleneurea (dmpu) has been studied in solution by EXAFS and large angle X-ray scattering (LAXS) and in solid state by single crystal X-ray diffraction and EXAFS. The hydrated vanadium(III) ion has a regular octahedral configuration with a mean V-O bond distance of 1.99 Å. In the hydrated and dimethylsulfo...

  10. Cosmological solutions from induced matter model applied to 5D f(R,T) gravity and the shrinking of the extra coordinate

    Energy Technology Data Exchange (ETDEWEB)

    Moraes, P.H.R.S. [Divisao de Astrofisica, INPE-Instituto Nacional de Pesquisas Espaciais, Sao Jose dos Campos, SP (Brazil)

    2015-04-01

    In this work, I present exact cosmological solutions from Wesson's induced matter model applied to a general 5D metric in f(R,T) theory of gravity. The non-conservation of the energy-momentum tensor, predicted by f(R,T) theory, allows the derivation of a relation that describes the time evolution of the extra coordinate, revealing its compactification. It is shown that such a compactification could induce the effects of an accelerated expansion in the observable universe. (orig.)

  11. Coordinate Transformation and Exact Solutions of Schr(o)dinger Equation with Position-Dependent Effective Mass

    Institute of Scientific and Technical Information of China (English)

    JU Guo-Xing; CAI Chang-Ying; XIANG Yang; REN Zhong-Zhou

    2007-01-01

    Using the coordinate transformation method, we solve the one-dimensional Schr(o)dinger equation with position-dependent mass. The explicit expressions for the potentials, energy eigenvalues, and eigcnfunctions of the systems are given. The eigenfunctions can be expressed in terms of the Jacobi, Hermite, and generalized Laguerre polynomials. All potentials for these solvable systems have an extra term Vm, which is produced from the dependence of mass on the position, compared with those for the systems of constant mass. The properties of Vm for several mass functions are discussed.

  12. Fac-mer equilibria of coordinated iminodiacetate (ida2-) in ternary CuII(ida)(H-1B)- complex formation (B = imidazole, benzimidazole) in aqueous solution

    Indian Academy of Sciences (India)

    Susmita Bandyopadhyay; G N Mukherjee

    2003-08-01

    pH potentiometric and spectrophotometric investigations on the complex formation equilibria of CuII with iminodiacetate (ida2-) and heterocyclic N-bases, viz. imidazole and benzimidazole (B), in aqueous solution in binary and ternary systems using different molar ratios of the reactants indicated the formation of complexes of the types, Cu(ida), Cu(ida)(OH)-, (ida)Cu(OH)Cu(ida)-, Cu(B)2+, Cu(H-1B)+, Cu(ida)(H-1B)-, (ida)Cu(B)Cu(ida) and (ida)Cu(H-1B)Cu(ida)-. Formation constants of the complexes at 25 ± 1° at a fixed ionic strength, = 0.1 mol dm-3 (NaNO3) in aqueous solution were evaluated and the complex formation equilibria were elucidated with the aid of speciation curves. Departure of the experimental values of the reproportionation constants (log Cu) of ternary Cu(ida)(H-1B)- complexes from the statistically expected values, despite their formation in appreciable amounts at equilibrium, were assigned to fac(f)-mer(m) equilibria of the ida2- ligand coordinated to CuII, as the N-heterocyclic donors, (H-1B)-, coordinate trans- to the N-(ida2-) atom in the binary Cu(ida) complex to form the ternary Cu(ida) (H-1B)- complexes.

  13. Coordination of the uranyl ion in solution and ionic liquids : a combined UV-Vis absorption and EXAFS study

    OpenAIRE

    Servaes, Kelly

    2007-01-01

    The uranyl ion (UO22+) has been extensively studied for decades and nowadays it is still a hot topic in a number of contemporary issues like nuclear waste treatment and the Balkan syndrome. Therefore, besides our fundamental interest in this complex system, the aim of this study was to provide a convenient and straightforward approach to identify the structure of various uranyl complexes formed in solution. To achieve this goal, spectroscopic techniques like UV-Vis absorption spectroscopy, ...

  14. A Novel Tris(2-aminoethylamine Based Tripodal Ligand: Synthesis and Solution Coordination Studies with Trivalent Iron and Chromium

    Directory of Open Access Journals (Sweden)

    Minati Baral

    2016-01-01

    Full Text Available A novel tris(2-aminoethylamine (TREN based tripodal ligand TRENOL (L has been synthesized and characterized by elemental analysis and UV-VIS, IR, 1H, and 13C NMR spectroscopic methods. The coordination behaviour of the ligand with H+ and trivalent metal ions, Fe(III and Cr(III, was investigated in aqueous medium at 0.1 M KCl at 25±1°C by potentiometric and spectrophotometric studies. Tripodal ligand showed seven protonation constants in the adopted pH range 2–11 and its electronic spectra exhibited three bands at 216, 323, and 423 nm. Ligand formed various metal complex species of the type MLH5, MLH4, MLH3, MLH, and ML with trivalent metal ions. The determined values of the formation constants (for ML species of the ligand with Fe(III and Cr(III were 24.19 and 18.64, respectively. Molecular modeling studies revealed that the metal complexes formed distorted octahedral geometry. Besides, ligand showed fluorescence at 496 nm when excited at 289 nm. The fluorescence behaviour of the ligand in the presence of Fe(III ions showed noticeable quenching in comparison to the other metal ions at physiological pH (7.4. So, as per the outcomes of the present study, TRENOL has the potential to be used as the iron detector in environmental, agricultural, and medical fields.

  15. Fundamental solution of Laplace's equation in oblate spheroidal coordinates and Galerkin's matrix for Neumann's problem in Earth's gravity field studies

    Science.gov (United States)

    Holota, Petr; Nesvadba, Otakar

    2015-04-01

    In this paper the reciprocal distance is used for generating Galerkin's approximations in the weak solution of Neumann's problem that has an important role in Earth's gravity field studies. The reciprocal distance has a natural tie to the fundamental solution of Laplace's partial differential equation and in the paper it is represented by means of an expansion into a series of oblate spheroidal harmonics. Subsequently, the gradient vector of the reciprocal distance is constructed. In the computation of its components the expansion mentioned above is employed. The paper then focuses on the scalar product of reciprocal distance gradients in two different points and in particular on a series representation of a volume integral of the scalar product spread over an unbounded domain given by the exterior of an oblate spheroid (oblate ellipsoid of revolution). The integral yields the entries of Galerkin's matrix. The numerical interpretation of all the expansions used as well as the respective software implementation within the OpenCL framework is treated, which concerns also a numerical evaluation of Legendre functions of a real and an imaginary argument. In parallel an approximate closed formula expressing the entries of Galerkin's matrix (with an accuracy up to terms multiplied by the square of numerical eccentricity) is derived for convenience and comparison. The paper is added extensive numerical examples that illustrate the approach applied and demonstrate the accuracy of the derived formulas. Aspects related to practical applications are discussed.

  16. A coordination chemistry study of hydrated and solvated cationic vanadium ions in oxidation states +III, +IV, and +V in solution and solid state.

    Science.gov (United States)

    Krakowiak, Joanna; Lundberg, Daniel; Persson, Ingmar

    2012-09-17

    The coordination chemistry of hydrated and solvated vanadium(III), oxovanadium(IV), and dioxovanadium(V) ions in the oxygen-donor solvents water, dimethyl sulfoxide (DMSO), and N,N'-dimethylpropyleneurea (DMPU) has been studied in solution by extended X-ray absorption fine structure (EXAFS) and large-angle X-ray scattering (LAXS) and in the solid state by single-crystal X-ray diffraction and EXAFS. The hydrated vanadium(III) ion has a regular octahedral configuration with a mean V-O bond distance of 1.99 Å. In the hydrated and DMSO-solvated oxovanadium(IV) ions, vanadium binds strongly to an oxo group at ca. 1.6 Å. The solvent molecule trans to the oxo group is very weakly bound, at ca. 2.2 Å, while the remaining four solvent molecules, with a mean V-O bond distance of 2.0 Å, form a plane slightly below the vanadium atom; the mean O═V-O(perp) bond angle is ca. 98°. In the DMPU-solvated oxovanadium(IV) ion, the space-demanding properties of the DMPU molecule leave no solvent molecule in the trans position to the oxo group, which reduces the coordination number to 5. The O═V-O bond angle is consequently much larger, 107°, and the mean V═O and V-O bond distances decrease to 1.58 and 1.97 Å, respectively. The hydrated and DMSO-solvated dioxovanadium(V) ions display a very distorted octahedral configuration with the oxo groups in the cis position with a mean V═O bond distance of 1.6 Å and a O═V═O bond angle of ca. 105°. The solvent molecules trans to the oxo groups are weakly bound, at ca. 2.2 Å, while the remaining two have bond distances of 2.02 Å. The experimental studies of the coordination chemistry of hydrated and solvated vanadium(III,IV,V) ions are complemented by summarizing previously reported crystal structures to yield a comprehensive description of the coordination chemistry of vanadium with oxygen-donor ligands.

  17. The role of local strains from prior cold work on stress corrosion cracking of α-brass in Mattsson's solution

    Energy Technology Data Exchange (ETDEWEB)

    Ulaganathan, Jaganathan, E-mail: jagan.ulaganathan@mail.utoronto.ca; Newman, Roger C., E-mail: roger.newman@utoronto.ca

    2014-06-01

    The dynamic strain rate ahead of a crack tip formed during stress corrosion cracking (SCC) under a static load is assumed to arise from the crack propagation. The strain surrounding the crack tip would be redistributed as the crack grows, thereby having the effect of dynamic strain. Recently, several studies have shown cold work to cause accelerated crack growth rates during SCC, and the slip-dissolution mechanism has been widely applied to account for this via a supposedly increased crack-tip strain rate in cold worked material. While these interpretations consider cold work as a homogeneous effect, dislocations are generated inhomogeneously within the microstructure during cold work. The presence of grain boundaries results in dislocation pile-ups that cause local strain concentrations. The local strains generated from cold working α-brass by tensile elongation were characterized using electron backscatter diffraction (EBSD). The role of these local strains in SCC was studied by measuring the strain distributions from the same regions of the sample before cold work, after cold work, and after SCC. Though, the cracks did not always initiate or propagate along boundaries with pre-existing local strains from the applied cold work, the local strains surrounding the cracked boundaries had contributions from both the crack propagation and the prior cold work. - Highlights: • Plastic strain localization has a complex relationship with SCC susceptibility. • Surface relief created by cold work creates its own granular strain localization. • Cold work promotes crack growth but several other factors are involved.

  18. Low-Temperature Nitriding of Deformed Austenitic Stainless Steels with Various Nitrogen Contents Obtained by Prior High-Temperature Solution Nitriding

    Science.gov (United States)

    Bottoli, Federico; Winther, Grethe; Christiansen, Thomas L.; Dahl, Kristian Vinter; Somers, Marcel A. J.

    2016-08-01

    In the past decades, high nitrogen steels (HNS) have been regarded as substitutes for conventional austenitic stainless steels because of their superior mechanical and corrosion properties. However, the main limitation to their wider application is their expensive production process. As an alternative, high-temperature solution nitriding has been applied to produce HNS from three commercially available stainless steel grades (AISI 304L, AISI 316, and EN 1.4369). The nitrogen content in each steel alloy is varied and its influence on the mechanical properties and the stability of the austenite investigated. Both hardness and yield stress increase and the alloys remain ductile. In addition, strain-induced transformation of austenite to martensite is suppressed, which is beneficial for subsequent low-temperature nitriding of the surface of deformed alloys. The combination of high- and low-temperature nitriding results in improved properties of both bulk and surface.

  19. Room-Temperature Energy-Sampling Kβ X-ray Emission Spectroscopy of the Mn4Ca Complex of Photosynthesis Reveals Three Manganese-Centered Oxidation Steps and Suggests a Coordination Change Prior to O2 Formation.

    Science.gov (United States)

    Zaharieva, Ivelina; Chernev, Petko; Berggren, Gustav; Anderlund, Magnus; Styring, Stenbjörn; Dau, Holger; Haumann, Michael

    2016-08-01

    In oxygenic photosynthesis, water is oxidized and dioxygen is produced at a Mn4Ca complex bound to the proteins of photosystem II (PSII). Valence and coordination changes in its catalytic S-state cycle are of great interest. In room-temperature (in situ) experiments, time-resolved energy-sampling X-ray emission spectroscopy of the Mn Kβ1,3 line after laser-flash excitation of PSII membrane particles was applied to characterize the redox transitions in the S-state cycle. The Kβ1,3 line energies suggest a high-valence configuration of the Mn4Ca complex with Mn(III)3Mn(IV) in S0, Mn(III)2Mn(IV)2 in S1, Mn(III)Mn(IV)3 in S2, and Mn(IV)4 in S3 and, thus, manganese oxidation in each of the three accessible oxidizing transitions of the water-oxidizing complex. There are no indications of formation of a ligand radical, thus rendering partial water oxidation before reaching the S4 state unlikely. The difference spectra of both manganese Kβ1,3 emission and K-edge X-ray absorption display different shapes for Mn(III) oxidation in the S2 → S3 transition when compared to Mn(III) oxidation in the S1 → S2 transition. Comparison to spectra of manganese compounds with known structures and oxidation states and varying metal coordination environments suggests a change in the manganese ligand environment in the S2 → S3 transition, which could be oxidation of five-coordinated Mn(III) to six-coordinated Mn(IV). Conceivable options for the rearrangement of (substrate) water species and metal-ligand bonding patterns at the Mn4Ca complex in the S2 → S3 transition are discussed.

  20. Coordination Capacity

    CERN Document Server

    Cuff, Paul; Cover, Thomas

    2009-01-01

    We develop elements of a theory of cooperation and coordination in networks. Rather than considering a communication network as a means of distributing information, or of reconstructing random processes at remote nodes, we ask what dependence can be established among the nodes given the communication constraints. Specifically, in a network with communication rates between the nodes, we ask what is the set of all achievable joint distributions p(x1, ..., xm) of actions at the nodes on the network. Several networks are solved, including arbitrarily large cascade networks. Distributed cooperation can be the solution to many problems such as distributed games, distributed control, and establishing mutual information bounds on the influence of one part of a physical system on another.

  1. Binuclear Pt-Tl bonded complex with square pyramidal coordination around Pt: a combined multinuclear NMR, EXAFS, UV-Vis, and DFT/TDDFT study in dimethylsulfoxide solution.

    Science.gov (United States)

    Purgel, Mihály; Maliarik, Mikhail; Glaser, Julius; Platas-Iglesias, Carlos; Persson, Ingmar; Tóth, Imre

    2011-07-04

    The structure and bonding of a new Pt-Tl bonded complex formed in dimethylsulfoxide (dmso), (CN)(4)Pt-Tl(dmso)(5)(+), have been studied by multinuclear NMR and UV-vis spectroscopies, and EXAFS measurements in combination with density functional theory (DFT) and time dependent density functional theory (TDDFT) calculations. This complex is formed following the equilibrium reaction Pt(CN)(4)(2-) + Tl(dmso)(6)(3+) ⇆ (CN)(4)Pt-Tl(dmso)(5)(+) + dmso. The stability constant of the Pt-Tl bonded species, as determined using (13)C NMR spectroscopy, amounts to log K = 2.9 ± 0.2. The (NC)(4)Pt-Tl(dmso)(5)(+) species constitutes the first example of a Pt-Tl bonded cyanide complex in which the sixth coordination position around Pt (in trans with respect to the Tl atom) is not occupied. The spectral parameters confirm the formation of the metal-metal bond, but differ substantially from those measured earlier in aqueous solution for complexes (CN)(5)Pt-Tl(CN)(n)(H(2)O)(x)(n-) (n = 0-3). The (205) Tl NMR chemical shift, δ = 75 ppm, is at extraordinary high field, while spin-spin coupling constant, (1)J(Pt-Tl) = 93 kHz, is the largest measured to date for a Pt-Tl bond in the absence of supporting bridging ligands. The absorption spectrum is dominated by two strong absorption bands in the UV region that are assigned to MMCT (Pt → Tl) and LMCT (dmso → Tl) bands, respectively, on the basis of MO and TDDFT calculations. The solution of the complex has a bright yellow color as a result of a shoulder present on the low energy side of the band at 355 nm. The geometry of the (CN)(4)Pt-Tl core can be elucidated from NMR data, but the particular stoichiometry and structure involving the dmso ligands are established by using Tl and Pt L(III)-edge EXAFS measurements. The Pt-Tl bond distance is 2.67(1) Å, the Tl-O bond distance is 2.282(6) Å, and the Pt-C-N entity is linear with Pt-C and Pt···N distances amounting to 1.969(6) and 3.096(6) Å, respectively. Geometry optimizations on

  2. Direct numerical solution of the two-particle Lippmann-Schwinger equation in coordinate space using the multi-variable Nystrom method

    CERN Document Server

    Kuruoglu, Zeki C

    2016-01-01

    Direct numerical solution of the coordinate-space integral-equation version of the two-particle Lippmann Schwinger (LS) equation is considered as a means of avoiding the shortcomings of partial-wave expansion at high energies and in the context of few-body problems. Upon the regularization of the singular kernel of the three-dimensional LS equation by a subtraction technique, a three-variate quadrature rule is used to solve the resulting nonsingular integral equation. To avoid the computational burden of discretizing three variables, advantage is taken of the fact that, for central potentials, azimuthal angle can be integrated out leaving a two-variable reduced integral equation. Although the singularity in the the kernel of the two-variable integral equation is weaker than that of the three-dimensional equation, it nevertheless requires careful handling for quadrature discretization to be applicable. A regularization method for the kernel of the two-variable integral equation is derived from the treatment of...

  3. Fighting Prior Review.

    Science.gov (United States)

    Bowen, John

    1990-01-01

    Reviews arguments for and against prior administrative review and censorship of student expression. Suggests that prior review strips any pretense of democracy from many American educational institutions. Argues that prior review is journalistically inappropriate, educationally unsound, and practically illogical. (KEH)

  4. SOLUTIONING

    Directory of Open Access Journals (Sweden)

    Maria de Hoyos Guajardo, Ph.D. Candidate, M.Sc., B.Eng.

    2004-11-01

    Full Text Available The theory that is presented below aims to conceptualise how a group of undergraduate students tackle non-routine mathematical problems during a problem-solving course. The aim of the course is to allow students to experience mathematics as a creative process and to reflect on their own experience. During the course, students are required to produce a written ‘rubric’ of their work, i.e., to document their thoughts as they occur as well as their emotionsduring the process. These ‘rubrics’ were used as the main source of data.Students’ problem-solving processes can be explained as a three-stage process that has been called ‘solutioning’. This process is presented in the six sections below. The first three refer to a common area of concern that can be called‘generating knowledge’. In this way, generating knowledge also includes issues related to ‘key ideas’ and ‘gaining understanding’. The third and the fourth sections refer to ‘generating’ and ‘validating a solution’, respectively. Finally, once solutions are generated and validated, students usually try to improve them further before presenting them as final results. Thus, the last section deals with‘improving a solution’. Although not all students go through all of the stages, it may be said that ‘solutioning’ considers students’ main concerns as they tackle non-routine mathematical problems.

  5. Uranyl ion coordination

    Science.gov (United States)

    Evans, H.T.

    1963-01-01

    A review of the known crystal structures containing the uranyl ion shows that plane-pentagon coordination is equally as prevalent as plane-square or plane-hexagon. It is suggested that puckered-hexagon configurations of OH - or H2O about the uranyl group will tend to revert to plane-pentagon coordination. The concept of pentagonal coordination is invoked for possible explanations of the complex crystallography of the natural uranyl hydroxides and the unusual behavior of polynuclear ions in hydrolyzed uranyl solutions.

  6. Team coordination dynamics.

    Science.gov (United States)

    Gorman, Jamie C; Amazeen, Polemnia G; Cooke, Nancy J

    2010-07-01

    Team coordination consists of both the dynamics of team member interaction and the environmental dynamics to which a team is subjected. Focusing on dynamics, an approach is developed that contrasts with traditional aggregate-static concepts of team coordination as characterized by the shared mental model approach. A team coordination order parameter was developed to capture momentary fluctuations in coordination. Team coordination was observed in three-person uninhabited air vehicle teams across two experimental sessions. The dynamics of the order parameter were observed under changes of a team familiarity control parameter. Team members returned for the second session to either the same (Intact) or different (Mixed) team. 'Roadblock' perturbations, or novel changes in the task environment, were introduced in order to probe the stability of team coordination. Nonlinear dynamic methods revealed differences that a traditional approach did not: Intact and Mixed team coordination dynamics looked very different; Mixed teams were more stable than Intact teams and explored the space of solutions without the need for correction. Stability was positively correlated with the number of roadblock perturbations that were overcome successfully. The novel and non-intuitive contribution of a dynamical analysis was that Mixed teams, who did not have a long history working together, were more adaptive. Team coordination dynamics carries new implications for traditional problems such as training adaptive teams.

  7. 47 CFR 87.305 - Frequency coordination.

    Science.gov (United States)

    2010-10-01

    ... 47 Telecommunication 5 2010-10-01 2010-10-01 false Frequency coordination. 87.305 Section 87.305... Flight Test Stations § 87.305 Frequency coordination. (a)(1) Each application for a new station license... prior coordinations and assignments on the proposed frequency(ies). The committee must also...

  8. Poisson Coordinates.

    Science.gov (United States)

    Li, Xian-Ying; Hu, Shi-Min

    2013-02-01

    Harmonic functions are the critical points of a Dirichlet energy functional, the linear projections of conformal maps. They play an important role in computer graphics, particularly for gradient-domain image processing and shape-preserving geometric computation. We propose Poisson coordinates, a novel transfinite interpolation scheme based on the Poisson integral formula, as a rapid way to estimate a harmonic function on a certain domain with desired boundary values. Poisson coordinates are an extension of the Mean Value coordinates (MVCs) which inherit their linear precision, smoothness, and kernel positivity. We give explicit formulas for Poisson coordinates in both continuous and 2D discrete forms. Superior to MVCs, Poisson coordinates are proved to be pseudoharmonic (i.e., they reproduce harmonic functions on n-dimensional balls). Our experimental results show that Poisson coordinates have lower Dirichlet energies than MVCs on a number of typical 2D domains (particularly convex domains). As well as presenting a formula, our approach provides useful insights for further studies on coordinates-based interpolation and fast estimation of harmonic functions.

  9. Overcoming priors anxiety

    CERN Document Server

    D'Agostini, Giulio

    1999-01-01

    The choice of priors may become an insoluble problem if priors and Bayes' rule are not seen and accepted in the framework of subjectivism. Therefore, the meaning and the role of subjectivity in science is considered and defended from the pragmatic point of view of an ``experienced scientist''. The case for the use of subjective priors is then supported and some recommendations for routine and frontier measurement applications are given. The issue of reference priors is also considered from the practical point of view and in the general context of ``Bayesian dogmatism''.

  10. The Dilemma and Solution of the Coordinated Development of Beijing-Tianjin-Hebei Region%京津冀协同发展:困境与出路

    Institute of Scientific and Technical Information of China (English)

    柳天恩

    2015-01-01

    京津冀协同发展有利于增强区域发展动力、缩小地区差距、落实国家区域战略和培育具有国际竞争力的城市群。但回顾京津冀近四十年的合作历程,可以发现京津冀协同发展并未取得预期效果,区域一体化还处于从市场一体化向产业一体化迈进的阶段,区域空间结构呈现典型的“中心—外围”特征。区域发展不平衡、生态环境问题突出、行政区经济和缺乏区际协调机制是制约京津冀协同发展的关键原因,应从明确区域功能定位、优化区域空间结构、推进功能区联动、构建区际协调机制四个方面推进京津冀协同发展。%The coordinated development of Beijing-Tianjin-Hebei region is conductive to enhancing regional development, narrowing regional gap,implementing regional strategies and nurturing internationally competitive urban agglomeration. But the results suggest that the coordinated development has not been achieved the expected results yet by reviewing nearly forty-year cooperation process among Beijing,Tianjin and Hebei. The regional integration is still in the stage between market integration and industrial integration. And regional spatial structure shows typical center-periphery features. The key reasons for restricting the coordinated development of Beijing-Tianjin-Hebei region are imbalanced regional development,environmental issues, administrative region economy and the lack of inter-regional coordination mechanism. Therefore,the author suggests that clarifying the region-functional positioning,optimizing regional spatial structure,advancing harmonious development of function areas and constructing inter-regional coordination mechanism can promote the coordinated development of Beijing-Tianjin-Hebei region.

  11. Cognitive Temporal Document Priors

    NARCIS (Netherlands)

    Peetz, M.H.; de Rijke, M.

    2013-01-01

    Temporal information retrieval exploits temporal features of document collections and queries. Temporal document priors are used to adjust the score of a document based on its publication time. We consider a class of temporal document priors that is inspired by retention functions considered in cogn

  12. Constructing priors in synesthesia.

    Science.gov (United States)

    van Leeuwen, Tessa M

    2014-01-01

    A new theoretical framework (PPSMC) applicable to synesthesia has been proposed, in which the discrepancy between the perceptual reality of (some) synesthetic concurrents and their subjective non-veridicality is being explained. The PPSMC framework stresses the relevance of the phenomenology of synesthesia for synesthesia research-and beyond. When describing the emergence and persistence of synesthetic concurrents under PPSMC, it is proposed that precise, high-confidence priors are crucial in synesthesia. I discuss the construction of priors in synesthesia.

  13. An integral transform of Green's function, off-shell Jost solution and T-matrix for Coulomb–Yamaguchi potential in coordinate representation

    Indian Academy of Sciences (India)

    U Laha

    2009-03-01

    By exploiting the theory of ordinary differential equations together with certain properties of higher transcendental functions, a useful analytical expression for the integral transform of the Green's function for motion in Coulomb–Yamaguchi potential is derived via the r-space approach. This integral transform is applied to construct an analytical expression for off-shell Jost solution in its ‘maximal reduced form’ involving confluent and Gaussian hypergeometric functions. Corresponding Jost functions auto-matically follow from this solution. Finally, as another application of the off-shell Jost solution, the off-shell T-matrix is calculated by using a modified relation between offshell physical wave function and T-matrix which does not involve the potential explicitly, thereby avoiding certain difficult integrals, and expressed it in terms of rational functions and simple hypergeometric functions which is in exact agreement with the results given previously by other authors.

  14. Prior Knowledge Assessment Guide

    Science.gov (United States)

    2014-12-01

    determine the students’ extent of prior knowledge, not their reading speed or comprehension. Therefore, be sure to consider the reading and English ...backgrounds and skills to make training more effective, meaningful and efficient. Initial research in this tailored training program was on...history of developing measures of mental ability or cognitive skills for personnel selection; beginning with World War I (Zeidner & Drucker, 1988

  15. Arthur Prior and 'Now'

    DEFF Research Database (Denmark)

    Blackburn, Patrick Rowan; Jørgensen, Klaus Frovin

    2015-01-01

    ’s search led him through the work of Castaneda, and back to his own work on hybrid logic: the first made temporal reference philosophically respectable, the second made it technically feasible in a modal framework. With the aid of hybrid logic, Prior built a bridge from a two-dimensional UT calculus...

  16. TECHNICAL COORDINATION

    CERN Multimedia

    A. Ball

    Overview From a technical perspective, CMS has been in “beam operation” state since 6th November. The detector is fully closed with all components operational and the magnetic field is normally at the nominal 3.8T. The UXC cavern is normally closed with the radiation veto set. Access to UXC is now only possible during downtimes of LHC. Such accesses must be carefully planned, documented and carried out in agreement with CMS Technical Coordination, Experimental Area Management, LHC programme coordination and the CCC. Material flow in and out of UXC is now strictly controlled. Access to USC remains possible at any time, although, for safety reasons, it is necessary to register with the shift crew in the control room before going down.It is obligatory for all material leaving UXC to pass through the underground buffer zone for RP scanning, database entry and appropriate labeling for traceability. Technical coordination (notably Stephane Bally and Christoph Schaefer), the shift crew and run ...

  17. A series of Zn/Cd coordination polymers constructed from 1,4-naphthalenedicarboxylate and N-donor ligands: Syntheses, structures and luminescence sensing of Cr{sup 3+} in aqueous solutions

    Energy Technology Data Exchange (ETDEWEB)

    Hu, Dong-Cheng [College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070 (China); Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou 515063 (China); Fan, Yan; Si, Chang-Dai; Wu, Ya-Jun; Dong, Xiu-Yan; Yang, Yun-Xia; Yao, Xiao-Qiang [College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070 (China); Liu, Jia-Cheng, E-mail: jcliu8@nwnu.edu.cn [College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070 (China)

    2016-09-15

    A novel series of Zn/Cd coordination polymers based on H{sub 3}L, namely, [Zn{sub 2}(HL){sub 2}(bipy){sub 2}(H{sub 2}O){sub 6}]{sub n} (1), [Zn(HL)(phen)]{sub n} (2), [Cd{sub 3}L{sub 2}(bbi){sub 3}]{sub n} (3), [Zn{sub 3}L{sub 2}(bbi){sub 3}]{sub n} (4) [(H{sub 3}L =4-[(1-carboxynaphthalen-2-yl)oxy]phthalic acid, bipy =4,4′-bipyridine, phen =1,10-phenanthroline, bbi =1,1′-(1,4-butanediyl)bis(imidazole] have been successfully synthesized by solvothermal reaction. Compound 1 possesses two diverse 1D chains constructed by different bipy coligands, which were further connected to form a 3D supramolecular architecture by hydrogen bonding interactions. Compound 2 possesses a complicated 1D chain based on secondary building unit (SBU) with binuclear Zn cluster. Compounds 3 and 4 exhibit similar 2D→3D framework, which can be rationalized as (3,4,4)-connected 3D net with a Schläfli symbol of (6{sup 3}.8.10{sup 2}){sub 2}(6{sup 3}){sub 2}(6{sup 4}.8.10). In particular, compound 3 exhibited a high sensitivity for Cr{sup 3+} in aqueous solutions, which suggest that compound 3 is a promising luminescent probe for selectively sensing Cr{sup 3+}. - Graphical abstract: A series of novel Zn/Cd coordination polymers have been successfully synthesized by solvothermal reaction. The unique 3D Cd{sup 2+} polymer containing bbi as second ligand demonstrates high sensitivity for detection of toxic Cr{sup 3+} in aqueous solutions. Display Omitted - Highlights: • π-conjugated semirigid tricarboxylate ligands with naphthalene rings(H{sub 3}L) were rationally designed. • Four Zn/Cd coordination polymers based on H{sub 3}L have been successfully synthesized by solvothermal reaction. • Compound 3 is a promising luminescent probe for selectively sensing Cr{sup 3+} with high sensitivity in aqueous solutions.

  18. Noncommuting Coordinates in the Landau Problem

    OpenAIRE

    Magro, Gabrielle

    2003-01-01

    Basic ideas about noncommuting coordinates are summarized, and then coordinate noncommutativity, as it arises in the Landau problem, is investigated. I review a quantum solution to the Landau problem, and evaluate the coordinate commutator in a truncated state space of Landau levels. Restriction to the lowest Landau level reproduces the well known commutator of planar coordinates. Inclusion of a finite number of Landau levels yields a matrix generalization.

  19. A study of the effects of grid non-orthogonality on the solution of shallow water equations in boundary-fitted coordinate systems

    CERN Document Server

    Sankaranarayanan, S

    2003-01-01

    In the present study, an existing two-dimensional boundary-fitted model [J. Hydraul. Eng.-ASCE 122 (9) (1996) 512] is used to study the effect of grid non-orthogonality on the solution of shallow water equations using boundary-fitted grids. The linearized two-dimensional shallow water equations are expressed in terms of the grid angle and aspect ratio. The truncation errors of the finite difference approximations used in the solution of the governing equations are shown to be dependent on the grid angle and the aspect ratio. The coefficient of the truncation error was shown to increase, with the decrease in the grid angle. The RMS errors in model predicted surface elevations and velocities for the case of seiching in a rectangular basin are found to increase gradually, as the grid resolution decreases from 174 to 80 gridpoints per wavelength or as the grid angle decreases from 90 deg. to 50 deg. and increases rather sharply for a grid angle of 30 deg. at grid resolutions less than 80 gridpoints per wavelength...

  20. A generalization of the analytical least-squares solution to the 3D symmetric Helmert coordinate transformation problem with an approximate error analysis

    Science.gov (United States)

    Chang, Guobin; Xu, Tianhe; Wang, Qianxin; Zhang, Shubi; Chen, Guoliang

    2017-05-01

    The symmetric Helmert transformation model is widely used in geospatial science and engineering. Using an analytical least-squares solution to the problem, a simple and approximate error analysis is developed. This error analysis follows the Pope procedure solving nonlinear problems, but no iteration is needed here. It is simple because it is not based on the direct and cumbersome error analysis of every single process involved in the analytical solution. It is approximate because it is valid only in the first-order approximation sense, or in other words, the error analysis is performed approximately on the tangent hyperplane at the estimates instead of the original nonlinear manifold of the observables. Though simple and approximate, this error analysis's consistency is not sacrificed as can be validated by Monte Carlo experiments. So the practically important variance-covariance matrix, as a consistent accuracy measure of the parameter estimate, is provided by the developed error analysis. Further, the developed theory can be easily generalized to other cases with more general assumptions about the measurement errors.

  1. Study on the numerical solutions of the eikonal equationin curvilinear coordinate system%曲线坐标系程函方程的求解方法研究

    Institute of Scientific and Technical Information of China (English)

    刘一峰; 兰海强

    2012-01-01

    The classical eikonal equation is commonly used in Cartesian coordinate system for problems that involve static correction, prestack migration, earthquake location and seismic tomography, but is less effective for calculating travel times in an earth model that has an irregular surface. We transform the eikonal equation to a curvilinear coordinate system that conforms with the boundaries of the domain. The eikonal equation in the curvilinear coordinate system displays the mathematical form of an anisotropic eikonal equations (even though the medium is isotropic in the Cartesian coordinate system). Then, we try to solve the anisotropic eikonal equations with two numerical methods, a simple modification of the fast marching method and Lax-Friedrichs fast sweeping method, respectively. Through a number of different numerical experiments we find- one may compute wrong solutions by extending fast marching methods designed for isotropic eikonal equations to anisotropic eikonal equations without taking into account the differences between them; the Lax-Friedrichs fast sweeping method is stable and valid for the eikonal equation in the curvilinear coordinate system, which has a significant meaning in the direction of solution of the eikonal equation in the curvilinear coordinate system.%笛卡尔坐标系中经典的程函方程在静校正、叠前偏移、走时反演、地震定位、层析成像等许多地球物理工作都有应用,然而用其计算起伏地表的地震波走时时却比较困难.我们通过把曲线坐标系中的矩形网格映射到笛卡尔坐标系的贴体网格推导出了曲线坐标中的程函方程,此时,曲线坐标系的程函方程呈现为各向异性的程函方程(尽管在笛卡尔坐标系中介质是各向同同性的).然后尝试用求解各向同性程函方程的快速推进法和Lax-Friedrichs快速扫描算法来分别求解该方程.数值试验表明未加考虑各向异性程函方程与各向同性程函方程的差

  2. Long-time solution of the time-dependent Schroedinger equation for an atom in an electromagnetic field using complex coordinate contours

    Energy Technology Data Exchange (ETDEWEB)

    Tao, Liang; Vanroose, Wim; Reps, Brian; Rescigno, Thomas N.; McCurdy, C. William

    2009-09-08

    We demonstrate that exterior complex scaling (ECS) can be used to impose outgoing wave boundary conditions exactly on solutions of the time-dependent Schrodinger equation for atoms in intense electromagnetic pulses using finite grid methods. The procedure is formally exact when applied in the appropriate gauge and is demonstrated in a calculation of high harmonic generation in which multiphoton resonances are seen for long pulse durations. However, we also demonstrate that while the application of ECS in this way is formally exact, numerical error can appear for long time propagations that can only be controlled by extending the finite grid. A mathematical analysis of the origins of that numerical error, illustrated with an analytically solvable model, is also given.

  3. TECHNICAL COORDINATION

    CERN Multimedia

    A. Ball

    2010-01-01

    Operational Experience At the end of the first full-year running period of LHC, CMS is established as a reliable, robust and mature experiment. In particular common systems and infrastructure faults accounted for <0.6 % CMS downtime during LHC pp physics. Technical operation throughout the entire year was rather smooth, the main faults requiring UXC access being sub-detector power systems and rack-cooling turbines. All such problems were corrected during scheduled technical stops, in the shadow of tunnel access needed by the LHC, or in negotiated accesses or access extensions. Nevertheless, the number of necessary accesses to the UXC averaged more than one per week and the technical stops were inevitably packed with work packages, typically 30 being executed within a few days, placing a high load on the coordination and area management teams. It is an appropriate moment for CMS Technical Coordination to thank all those in many CERN departments and in the Collaboration, who were involved in CMS techni...

  4. Enterprise Coordination on the Internet

    Directory of Open Access Journals (Sweden)

    Charles Petrie

    2011-02-01

    Full Text Available Enterprises are now connected internally and externally to other Enterprises via the Internet in ways that are increasingly difficult to manage, especially as these interconnections become more dynamic. Current methods of coordinating the effects of change as they propagate through these networks of connections are not likely to scale. What is needed is a new paradigm for how the Internet supports such coordination. Indeed, the Internet should and could provide fundamental coordination functions that are missing today. In this paper, we describe how such a “Coordinated Internet” would work (this paper is an expanded version of [1]. The key functionality of a Coordinated Internet would be that the Internet actively watches what people do (analogous to search completion on desktops today, correlates these activities, and actively notifies people when and how their current tasks affect and are affected by the activities of other people. This would be accomplished by standard coordination functions implemented as a common Internet layer that can be used as a utility by more specialized applications. Such a Coordinated Internet would revolutionize enterprise management, for all enterprises, large and small, corporate and personal. For example, static workflows would become obsolete for all but the the most routine processes. Some solutions provide existence proofs of such a coordination substrate, such as the Redux solution in concurrent engineering, which we describe herein. However, foundational research remains to be done in the new field of Coordination Engineering in order to reach the goal of a future Internet in which coordination functions are fundamental.

  5. Fluoro- and perfluoralkylsulfonylpentafluoroanilides: synthesis and characterization of NH acids for weakly coordinating anions and their gas-phase and solution acidities.

    Science.gov (United States)

    Kögel, Julius F; Linder, Thomas; Schröder, Fabian G; Sundermeyer, Jörg; Goll, Sascha K; Himmel, Daniel; Krossing, Ingo; Kütt, Karl; Saame, Jaan; Leito, Ivo

    2015-04-01

    Fluoro- and perfluoralkylsulfonyl pentafluoroanilides [HN(C6F5)(SO2X); X = F, CF3, C4F9, C8F17] are a class of imides with two different strongly electron-withdrawing substituents attached to a nitrogen atom. They are NH acids, the unsymmetrical hybrids of the well-known symmetrical bissulfonylimides and bispentafluorophenylamine. The syntheses, the structures of these perfluoroanilides, their solvates, and some selected lithium salts give rise to a structural variety beyond the symmetrical parent compounds. The acidities of representative subsets of these novel NH acids have been investigated experimentally and quantum-chemically and their gas-phase acidities (GAs) are reported, as well as the pKa values of these compounds in acetonitrile (MeCN) and DMSO solution. In quantum chemical investigations with the vertical and relaxed COSMO cluster-continuum models (vCCC/rCCC), the unusual situation is encountered that the DMSO-solvated acid Me2SO-H-N(SO2CF3)2, optimized in the gas phase (vCCC model), dissociates to Me2SO-H(+)-N(SO2CF3)2(-) during structural relaxation and full optimization with the solvation model turned on (rCCC model). This proton transfer underlines the extremely high acidity of HN(SO2CF3)2. The importance of this effect is studied computationally in DMSO and MeCN solution. Usually this effect is less pronounced in MeCN and is of higher importance in the more basic solvent DMSO. Nevertheless, the neglect of the structural relaxation upon solvation causes typical changes in the computational pKa values of 1 to 4 orders of magnitude (4-20 kJ mol(-1)). The results provide evidence that the published experimental DMSO pKa value of HN(SO2CF3)2 should rather be interpreted as the pKa of a Me2SO-H(+)-N(SO2CF3)2(-) contact ion pair.

  6. A ladder coordination polymer based on Ca(2+) and (4,5-dicyano-1,2-phenylene)bis(phosphonic acid): crystal structure and solution-state NMR study.

    Science.gov (United States)

    Venkatramaiah, Nutalapati; Mendes, Ricardo F; Silva, Artur M S; Tomé, João P C; Almeida Paz, Filipe A

    2016-09-01

    The preparation of coordination polymers (CPs) based on either transition metal centres or rare-earth cations has grown considerably in recent decades. The different coordination chemistry of these metals allied to the use of a large variety of organic linkers has led to an amazing structural diversity. Most of these compounds are based on carboxylic acids or nitrogen-containing ligands. More recently, a wide range of molecules containing phosphonic acid groups have been reported. For the particular case of Ca(2+)-based CPs, some interesting functional materials have been reported. A novel one-dimensional Ca(2+)-based coordination polymer with a new organic linker, namely poly[[diaqua[μ4-(4,5-dicyano-1,2-phenylene)bis(phosphonato)][μ3-(4,5-dicyano-1,2-phenylene)bis(phosphonato)]dicalcium(II)] tetrahydrate], {[Ca2(C8H4N2O6P2)2(H2O)2]·4H2O}n, has been prepared at ambient temperature. The crystal structure features one-dimensional ladder-like ∞(1)[Ca2(H2cpp)2(H2O)2] polymers [H2cpp is (4,5-dicyano-1,2-phenylene)bis(phosphonate)], which are created by two distinct coordination modes of the anionic H2cpp(2-) cyanophosphonate organic linkers: while one molecule is only bound to Ca(2+) cations via the phosphonate groups, the other establishes an extra single connection via a cyano group. Ladders close pack with water molecules through an extensive network of strong and highly directional O-H...O and O-H...N hydrogen bonds; the observed donor-acceptor distances range from 2.499 (5) to 3.004 (6) Å and the interaction angles were found in the range 135-178°. One water molecule was found to be disordered over three distinct crystallographic positions. A detailed solution-state NMR study of the organic linker is also provided.

  7. Reaction Mechanism for Direct Proton Transfer from Carbonic Acid to a Strong Base in Aqueous Solution II: Solvent Coordinate-Dependent Reaction Path.

    Science.gov (United States)

    Daschakraborty, Snehasis; Kiefer, Philip M; Miller, Yifat; Motro, Yair; Pines, Dina; Pines, Ehud; Hynes, James T

    2016-03-10

    The protonation of methylamine base CH3NH2 by carbonic acid H2CO3 within a hydrogen (H)-bonded complex in aqueous solution was studied via Car-Parrinello dynamics in the preceding paper (Daschakraborty, S.; Kiefer, P. M.; Miller, Y.; Motro, Y.; Pines, D.; Pines, E.; Hynes, J. T. J. Phys. Chem. B 2016, DOI: 10.1021/acs.jpcb.5b12742). Here some important further details of the reaction path are presented, with specific emphasis on the water solvent's role. The overall reaction is barrierless and very rapid, on an ∼100 fs time scale, with the proton transfer (PT) event itself being very sudden (water solvent changes little until the actual PT occurrence; this results from the very strong driving force for the reaction, as indicated by the very favorable acid-protonated base ΔpKa difference. Further solvent rearrangement follows immediately the sudden PT's production of an incipient contact ion pair, stabilizing it by establishment of equilibrium solvation. The solvent water's short time scale ∼120 fs response to the incipient ion pair formation is primarily associated with librational modes and H-bond compression of water molecules around the carboxylate anion and the protonated base. This is consistent with this stabilization involving significant increase in H-bonding of hydration shell waters to the negatively charged carboxylate group oxygens' (especially the former H2CO3 donor oxygen) and the nitrogen of the positively charged protonated base's NH3(+).

  8. RUN COORDINATION

    CERN Multimedia

    C. Delaere

    2013-01-01

    Since the LHC ceased operations in February, a lot has been going on at Point 5, and Run Coordination continues to monitor closely the advance of maintenance and upgrade activities. In the last months, the Pixel detector was extracted and is now stored in the pixel lab in SX5; the beam pipe has been removed and ME1/1 removal has started. We regained access to the vactank and some work on the RBX of HB has started. Since mid-June, electricity and cooling are back in S1 and S2, allowing us to turn equipment back on, at least during the day. 24/7 shifts are not foreseen in the next weeks, and safety tours are mandatory to keep equipment on overnight, but re-commissioning activities are slowly being resumed. Given the (slight) delays accumulated in LS1, it was decided to merge the two global runs initially foreseen into a single exercise during the week of 4 November 2013. The aim of the global run is to check that we can run (parts of) CMS after several months switched off, with the new VME PCs installed, th...

  9. RUN COORDINATION

    CERN Multimedia

    Christophe Delaere

    2013-01-01

    The focus of Run Coordination during LS1 is to monitor closely the advance of maintenance and upgrade activities, to smooth interactions between subsystems and to ensure that all are ready in time to resume operations in 2015 with a fully calibrated and understood detector. After electricity and cooling were restored to all equipment, at about the time of the last CMS week, recommissioning activities were resumed for all subsystems. On 7 October, DCS shifts began 24/7 to allow subsystems to remain on to facilitate operations. That culminated with the Global Run in November (GriN), which   took place as scheduled during the week of 4 November. The GriN has been the first centrally managed operation since the beginning of LS1, and involved all subdetectors but the Pixel Tracker presently in a lab upstairs. All nights were therefore dedicated to long stable runs with as many subdetectors as possible. Among the many achievements in that week, three items may be highlighted. First, the Strip...

  10. Preparation, spectrochemical, and computational analysis of L-carnosine (2-[(3-aminopropanoyl)amino]-3-(1H-imidazol-5-yl)propanoic acid) and its ruthenium (II) coordination complexes in aqueous solution.

    Science.gov (United States)

    Branham, Michael Lee; Singh, Parvesh; Bisetty, Krishna; Sabela, Myalo; Govender, Thirumala

    2011-12-09

    This study reports the synthesis and characterization of novel ruthenium (II) complexes with the polydentate dipeptide, L-carnosine (2-[(3-aminopropanoyl)amino]-3-(1H-imidazol-5-yl)propanoic acid). Mixed-ligand complexes with the general composition [ML(p)(Cl)(q)(H₂O)(r)]·xH₂O (M = Ru(II); L = L-carnosine; p = 3 - q; r = 0-1; and x = 1-3) were prepared by refluxing aqueous solutions of the ligand with equimolar amounts of ruthenium chloride (black-alpha form) at 60 °C for 36 h. Physical properties of the complexes were characterized by elemental analysis, DSC/TGA, and cyclic voltammetry. The molecular structures of the complexes were elucidated using UV-Vis, ATR-IR, and heteronuclear NMR spectroscopy, then confirmed by density function theory (DFT) calculations at the B3LYP/LANL2DZ level. Two-dimensional NMR experiments (¹H COSY, ¹³C gHMBC, and ¹⁵N gHMBC) were also conducted for the assignment of chemical shifts and calculation of relative coordination-induced shifts (RCIS) by the complex formed. According to our results, the most probable coordination geometries of ruthenium in these compounds involve nitrogen (N1) from the imidazole ring and an oxygen atom from the carboxylic acid group of the ligand as donor atoms. Additional thermogravimetric and electrochemical data suggest that while the tetrahedral-monomer or octahedral-dimer are both possible structures of the formed complexes, the metal in either structure occurs in the ²⁺ oxidation state. Resulting RCIS values indicate that the amide-carbonyl, and the amino-terminus of the dipeptide are not involved in chelation and these observations correlate well with theoretical shift predictions by DFT.

  11. Preparation, Spectrochemical, and Computational Analysis of L-Carnosine (2-[(3-Aminopropanoylamino]-3-(1H-imidazol-5-ylpropanoic Acid and Its Ruthenium (II Coordination Complexes in Aqueous Solution

    Directory of Open Access Journals (Sweden)

    Myalo Sabela

    2011-12-01

    Full Text Available This study reports the synthesis and characterization of novel ruthenium (II complexes with the polydentate dipeptide, L-carnosine (2-[(3-aminopropanoylamino]-3-(1H-imidazol-5-ylpropanoic acid. Mixed-ligand complexes with the general composition [MLp(Clq(H2Or]·xH2O (M = Ru(II; L = L-carnosine; p = 3 − q; r = 0–1; and x = 1–3 were prepared by refluxing aqueous solutions of the ligand with equimolar amounts of ruthenium chloride (black-alpha form at 60 °C for 36 h. Physical properties of the complexes were characterized by elemental analysis, DSC/TGA, and cyclic voltammetry. The molecular structures of the complexes were elucidated using UV-Vis, ATR-IR, and heteronuclear NMR spectroscopy, then confirmed by density function theory (DFT calculations at the B3LYP/LANL2DZ level. Two-dimensional NMR experiments (1H COSY, 13C gHMBC, and 15N gHMBC were also conducted for the assignment of chemical shifts and calculation of relative coordination-induced shifts (RCIS by the complex formed. According to our results, the most probable coordination geometries of ruthenium in these compounds involve nitrogen (N1 from the imidazole ring and an oxygen atom from the carboxylic acid group of the ligand as donor atoms. Additional thermogravimetric and electrochemical data suggest that while the tetrahedral-monomer or octahedral-dimer are both possible structures of the formed complexes, the metal in either structure occurs in the (2+ oxidation state. Resulting RCIS values indicate that the amide-carbonyl, and the amino-terminus of the dipeptide are not involved in chelation and these observations correlate well with theoretical shift predictions by DFT.

  12. RUN COORDINATION

    CERN Multimedia

    G. Rakness.

    2013-01-01

    After three years of running, in February 2013 the era of sub-10-TeV LHC collisions drew to an end. Recall, the 2012 run had been extended by about three months to achieve the full complement of high-energy and heavy-ion physics goals prior to the start of Long Shutdown 1 (LS1), which is now underway. The LHC performance during these exciting years was excellent, delivering a total of 23.3 fb–1 of proton-proton collisions at a centre-of-mass energy of 8 TeV, 6.2 fb–1 at 7 TeV, and 5.5 pb–1 at 2.76 TeV. They also delivered 170 μb–1 lead-lead collisions at 2.76 TeV/nucleon and 32 nb–1 proton-lead collisions at 5 TeV/nucleon. During these years the CMS operations teams and shift crews made tremendous strides to commission the detector, repeatedly stepping up to meet the challenges at every increase of instantaneous luminosity and energy. Although it does not fully cover the achievements of the teams, a way to quantify their success is the fact that that...

  13. Varying prior information in Bayesian inversion

    Science.gov (United States)

    Walker, Matthew; Curtis, Andrew

    2014-06-01

    Bayes' rule is used to combine likelihood and prior probability distributions. The former represents knowledge derived from new data, the latter represents pre-existing knowledge; the Bayesian combination is the so-called posterior distribution, representing the resultant new state of knowledge. While varying the likelihood due to differing data observations is common, there are also situations where the prior distribution must be changed or replaced repeatedly. For example, in mixture density neural network (MDN) inversion, using current methods the neural network employed for inversion needs to be retrained every time prior information changes. We develop a method of prior replacement to vary the prior without re-training the network. Thus the efficiency of MDN inversions can be increased, typically by orders of magnitude when applied to geophysical problems. We demonstrate this for the inversion of seismic attributes in a synthetic subsurface geological reservoir model. We also present results which suggest that prior replacement can be used to control the statistical properties (such as variance) of the final estimate of the posterior in more general (e.g., Monte Carlo based) inverse problem solutions.

  14. Separation of variables in an asymmetric cyclidic coordinate system

    Science.gov (United States)

    Cohl, H. S.; Volkmer, H.

    2013-06-01

    A global analysis is presented of solutions for Laplace's equation on three-dimensional Euclidean space in one of the most general orthogonal asymmetric confocal cyclidic coordinate systems which admit solutions through separation of variables. We refer to this coordinate system as five-cyclide coordinates since the coordinate surfaces are given by two cyclides of genus zero which represent inversions of each other with respect to the unit sphere, a cyclide of genus one, and two disconnected cyclides of genus zero. This coordinate system is obtained by stereographic projection of sphero-conal coordinates on four-dimensional Euclidean space. The harmonics in this coordinate system are given by products of solutions of second-order Fuchsian ordinary differential equations with five elementary singularities. The Dirichlet problem for the global harmonics in this coordinate system is solved using multiparameter spectral theory in the regions bounded by the asymmetric confocal cyclidic coordinate surfaces.

  15. Motor coordination: a local hub for coordination.

    Science.gov (United States)

    Calabrese, Ronald L

    2014-03-31

    A local interneuron of a crayfish central pattern generator serves as a hub that integrates ascending and descending coordinating information and passes it on to a local oscillatory microcircuit to coordinate a series of segmental appendages known as swimmerets.

  16. A series of Zn/Cd coordination polymers constructed from 1,4-naphthalenedicarboxylate and N-donor ligands: Syntheses, structures and luminescence sensing of Cr3+ in aqueous solutions

    Science.gov (United States)

    Hu, Dong-Cheng; Fan, Yan; Si, Chang-Dai; Wu, Ya-Jun; Dong, Xiu-Yan; Yang, Yun-Xia; Yao, Xiao-Qiang; Liu, Jia-Cheng

    2016-09-01

    A novel series of Zn/Cd coordination polymers based on H3L, namely, [Zn2(HL)2(bipy)2(H2O)6]n (1), [Zn(HL)(phen)]n (2), [Cd3L2(bbi)3]n (3), [Zn3L2(bbi)3]n (4) [(H3L =4-[(1-carboxynaphthalen-2-yl)oxy]phthalic acid, bipy =4,4‧-bipyridine, phen =1,10-phenanthroline, bbi =1,1‧-(1,4-butanediyl)bis(imidazole] have been successfully synthesized by solvothermal reaction. Compound 1 possesses two diverse 1D chains constructed by different bipy coligands, which were further connected to form a 3D supramolecular architecture by hydrogen bonding interactions. Compound 2 possesses a complicated 1D chain based on secondary building unit (SBU) with binuclear Zn cluster. Compounds 3 and 4 exhibit similar 2D→3D framework, which can be rationalized as (3,4,4)-connected 3D net with a Schläfli symbol of (63.8.102)2(63)2(64.8.10). In particular, compound 3 exhibited a high sensitivity for Cr3+ in aqueous solutions, which suggest that compound 3 is a promising luminescent probe for selectively sensing Cr3+.

  17. Accommodating Uncertainty in Prior Distributions

    Energy Technology Data Exchange (ETDEWEB)

    Picard, Richard Roy [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Vander Wiel, Scott Alan [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-01-19

    A fundamental premise of Bayesian methodology is that a priori information is accurately summarized by a single, precisely de ned prior distribution. In many cases, especially involving informative priors, this premise is false, and the (mis)application of Bayes methods produces posterior quantities whose apparent precisions are highly misleading. We examine the implications of uncertainty in prior distributions, and present graphical methods for dealing with them.

  18. Coordinated induction of bile acid detoxification and alternative elimination in mice: role of FXR-regulated organic solute transporter-alpha/beta in the adaptive response to bile acids.

    Science.gov (United States)

    Zollner, Gernot; Wagner, Martin; Moustafa, Tarek; Fickert, Peter; Silbert, Dagmar; Gumhold, Judith; Fuchsbichler, Andrea; Halilbasic, Emina; Denk, Helmut; Marschall, Hanns-Ulrich; Trauner, Michael

    2006-05-01

    The bile acid receptor farnesoid X receptor (FXR) is a key regulator of hepatic defense mechanisms against bile acids. A comprehensive study addressing the role of FXR in the coordinated regulation of adaptive mechanisms including biosynthesis, metabolism, and alternative export together with their functional significance is lacking. We therefore fed FXR knockout (FXR(-/-)) mice with cholic acid (CA) and ursodeoxycholic acid (UDCA). Bile acid synthesis and hydroxylation were assessed by real-time RT-PCR for cytochrome P-450 (Cyp)7a1, Cyp3a11, and Cyp2b10 and mass spectrometry-gas chromatography for determination of bile acid composition. Expression of the export systems multidrug resistance proteins (Mrp)4-6 in the liver and kidney and the recently identified basoalteral bile acid transporter, organic solute transporter (Ost-alpha/Ost-beta), in the liver, kidney, and intestine was also investigated. CA and UDCA repressed Cyp7a1 in FXR(+/+) mice and to lesser extents in FXR(-/-) mice and induced Cyp3a11 and Cyp2b10 independent of FXR. CA and UDCA were hydroxylated in both genotypes. CA induced Ost-alpha/Ost-beta in the liver, kidney, and ileum in FXR(+/+) but not FXR(-/-) mice, whereas UDCA had only minor effects. Mrp4 induction in the liver and kidney correlated with bile acid levels and was observed in UDCA-fed and CA-fed FXR(-/-) animals but not in CA-fed FXR(+/+) animals. Mrp5/6 remained unaffected by bile acid treatment. In conclusion, we identified Ost-alpha/Ost-beta as a novel FXR target. Absent Ost-alpha/Ost-beta induction in CA-fed FXR(-/-) animals may contribute to increased liver injury in these animals. The induction of bile acid hydroxylation and Mrp4 was independent of FXR but could not counteract liver toxicity sufficiently. Limited effects of UDCA on Ost-alpha/Ost-beta may jeopardize its therapeutic efficacy.

  19. Limitations of Radar Coordinates

    OpenAIRE

    Bini, Donato; Lusanna, Luca; Mashhoon, Bahram

    2004-01-01

    The construction of a radar coordinate system about the world line of an observer is discussed. Radar coordinates for a hyperbolic observer as well as a uniformly rotating observer are described in detail. The utility of the notion of radar distance and the admissibility of radar coordinates are investigated. Our results provide a critical assessment of the physical significance of radar coordinates.

  20. Conforming to coordinate: children use majority information for peer coordination.

    Science.gov (United States)

    Grueneisen, Sebastian; Wyman, Emily; Tomasello, Michael

    2015-03-01

    Humans are constantly required to coordinate their behaviour with others. As this often relies on everyone's convergence on the same strategy (e.g., driving on the left side of the road), a common solution is to conform to majority behaviour. In this study, we presented 5-year-old children with a coordination problem: To retrieve some rewards, they had to choose the same of four options as a peer partner--in reality a stooge--whose decision they were unable to see. Before making a choice, they watched a video showing how other children from their partner's peer group had behaved; a majority chose the same option and a minority chose a different one. In a control condition, children watched the same video but could then retrieve the reward irrespective of their partner's choice (i.e., no coordination was necessary). Children followed the majority more often when coordination was required. Moreover, conformers mostly justified their choices by referring to the majority from the video demonstration. This study is the first to show that young children are able to strategically coordinate decisions with peers by conforming to the majority.

  1. Menarche: Prior Knowledge and Experience.

    Science.gov (United States)

    Skandhan, K. P.; And Others

    1988-01-01

    Recorded menstruation information among 305 young women in India, assessing the differences between those who did and did not have knowledge of menstruation prior to menarche. Those with prior knowledge considered menarche to be a normal physiological function and had a higher rate of regularity, lower rate of dysmenorrhea, and earlier onset of…

  2. The Importance of Prior Knowledge.

    Science.gov (United States)

    Cleary, Linda Miller

    1989-01-01

    Recounts a college English teacher's experience of reading and rereading Noam Chomsky, building up a greater store of prior knowledge. Argues that Frank Smith provides a theory for the importance of prior knowledge and Chomsky's work provided a personal example with which to interpret and integrate that theory. (RS)

  3. The Importance of Prior Knowledge.

    Science.gov (United States)

    Cleary, Linda Miller

    1989-01-01

    Recounts a college English teacher's experience of reading and rereading Noam Chomsky, building up a greater store of prior knowledge. Argues that Frank Smith provides a theory for the importance of prior knowledge and Chomsky's work provided a personal example with which to interpret and integrate that theory. (RS)

  4. Offset detection in GPS coordinate time series

    Science.gov (United States)

    Gazeaux, J.; King, M. A.; Williams, S. D.

    2013-12-01

    Global Positioning System (GPS) time series are commonly affected by offsets of unknown magnitude and the large volume of data globally warrants investigation of automated detection approaches. The Detection of Offsets in GPS Experiment (DOGEx) showed that accuracy of Global Positioning System (GPS) time series can be significantly improved by applying statistical offset detection methods (see Gazeaux et al. (2013)). However, the best of these approaches did not perform as well as manual detection by expert analysts. Many of the features of GPS coordinates time series have not yet been fully taken into account in existing methods. Here, we apply Bayesian theory in order to make use of prior knowledge of the site noise characteristics and metadata in an attempt to make the offset detection more accurate. In the past decades, Bayesian theory has shown relevant results for a widespread range of applications, but has not yet been applied to GPS coordinates time series. Such methods incorporate different inputs such as a dynamic model (linear trend, periodic signal..) and a-priori information in a process that provides the best estimate of parameters (velocity, phase and amplitude of periodic signals...) based on all the available information. We test the new method on the DOGEx simulated dataset and compare it to previous solutions, and to Monte-Carlo method to test the accuracy of the procedure. We make a preliminary extension of the DOGEx dataset to introduce metadata information, allowing us to test the value of this data type in detecting offsets. The flexibility, robustness and limitations of the new approach are discussed. Gazeaux, J. Williams, S., King, M., Bos, M., Dach, R., Deo, M.,Moore, A.W., Ostini, L., Petrie, E., Roggero, M., Teferle, F.N., Olivares, G.,Webb, F.H. 2013. Detecting offsets in GPS time series: First results from the detection of offsets in GPS experiment. Journal of Geophysical Research: Solid Earth 118. 5. pp:2169-9356. Keywords : GPS

  5. Solution preparation

    Energy Technology Data Exchange (ETDEWEB)

    Seitz, M.G.

    1982-01-01

    Reviewed in this statement are methods of preparing solutions to be used in laboratory experiments to examine technical issues related to the safe disposal of nuclear waste from power generation. Each approach currently used to prepare solutions has advantages and any one approach may be preferred over the others in particular situations, depending upon the goals of the experimental program. These advantages are highlighted herein for three approaches to solution preparation that are currently used most in studies of nuclear waste disposal. Discussion of the disadvantages of each approach is presented to help a user select a preparation method for his particular studies. Also presented in this statement are general observations regarding solution preparation. These observations are used as examples of the types of concerns that need to be addressed regarding solution preparation. As shown by these examples, prior to experimentation or chemical analyses, laboratory techniques based on scientific knowledge of solutions can be applied to solutions, often resulting in great improvement in the usefulness of results.

  6. Universal Prior Prediction for Communication

    CERN Document Server

    Lomnitz, Yuval

    2011-01-01

    We consider the problem of communicating over an unknown and arbitrarily varying channel, using feedback. This paper focuses on the problem of determining the input behavior, or more specifically, a prior which is used to randomly generate a codebook. We pose the problem of setting the prior as a universal sequential prediction problem using information theoretic abstractions of the communication channel. For the case where the channel is block-wise constant, we show it is possible to asymptotically approach the best rate that can be attained by any system using a fixed prior. For the case where the channel may change on each symbol, we combine a rateless coding scheme with a prior predictor and asymptotically approach the capacity of the average channel universally for every sequence of channels.

  7. Recruiting for Prior Service Market

    Science.gov (United States)

    2008-06-01

    perceptions, expectations and issues for re-enlistment • Develop potential marketing and advertising tactics and strategies targeted to the defined...01 JUN 2008 2. REPORT TYPE N/A 3. DATES COVERED - 4. TITLE AND SUBTITLE Recruiting for Prior Service Market 5a. CONTRACT NUMBER 5b. GRANT...Command First Handshake to First Unit of Assignment An Army of One Proud to Be e e to Serve Recruiting for Prior Service Market MAJ Eric Givens / MAJ Brian

  8. Movement and Coordination

    Science.gov (United States)

    ... Español Text Size Email Print Share Movement and Coordination Page Content Article Body At this age, your ... level will strengthen his body and develop his coordination. In the months ahead, your child’s running will ...

  9. Developmental coordination disorder

    Science.gov (United States)

    ... page: //medlineplus.gov/ency/article/001533.htm Developmental coordination disorder To use the sharing features on this page, please enable JavaScript. Developmental coordination disorder is a childhood disorder. It leads to ...

  10. Existence of frozen-in coordinate systems

    Science.gov (United States)

    Chertkov, A. D.

    1995-01-01

    The 'frozen-in' coordinate systems were first introduced in the works on 'reconnection' and 'magnetic barrier' theories (see review by M.l.Pudovkin and V.S.Semenov, Space Sci. Rev. 41,1 1985). The idea was to utilize the mathematical apparatus developed for 'general relativity' theory to simplify obtaining solutions to the ideal MHD equations set. Magnetic field (B), plasma velocity (v), and their vector product were used as coordinate vectors. But there exist no stationary solutions of ideal MHD set that satisfies the required boundary conditions at infinity (A.D.Chertkov, Solar Wind Seven Conf.,Pergamon Press,1992,165) having non-zero vector product of v and B where v and B originate from the same sphere. The existence of a solution is the hidden mine of the mentioned theories. The solution is constructed in the coordinate system, which is unknown and indeterminate before obtaining this solution. A substitution of the final solution must be done directly into the initial MHD set in order to check the method. One can demonstrate that 'solutions' of Petschek's problem, obtained by 'frozen-in' coordinate systems, does not satisfy just the 'frozen-in' equation, i.e. induction equation. It stems from the fact that Petschek's 're-connection' model, treated as a boundary problem, is over determined. This problem was incorrectly formulated.

  11. Coordination and Cooperation

    OpenAIRE

    Janssen, Maarten

    2003-01-01

    textabstractThis comment makes four related points. First, explaining coordination is different from explaining cooperation. Second, solving the coordination problem is more important for the theory of games than solving the cooperation problem. Third, a version of the Principle of Coordination can be rationalized on individualistic grounds. Finally, psychological game theory should consider how players perceive their gaming situation. ---------------------------------------------------------...

  12. Processing Coordination Ambiguity

    Science.gov (United States)

    Engelhardt, Paul E.; Ferreira, Fernanda

    2010-01-01

    We examined temporarily ambiguous coordination structures such as "put the butter in the bowl and the pan on the towel." Minimal Attachment predicts that the ambiguous noun phrase "the pan" will be interpreted as a noun-phrase coordination structure because it is syntactically simpler than clausal coordination. Constraint-based theories assume…

  13. Processing Coordination Ambiguity

    Science.gov (United States)

    Engelhardt, Paul E.; Ferreira, Fernanda

    2010-01-01

    We examined temporarily ambiguous coordination structures such as "put the butter in the bowl and the pan on the towel." Minimal Attachment predicts that the ambiguous noun phrase "the pan" will be interpreted as a noun-phrase coordination structure because it is syntactically simpler than clausal coordination. Constraint-based…

  14. Coordination and Cooperation

    NARCIS (Netherlands)

    M.C.W. Janssen (Maarten)

    2003-01-01

    textabstractThis comment makes four related points. First, explaining coordination is different from explaining cooperation. Second, solving the coordination problem is more important for the theory of games than solving the cooperation problem. Third, a version of the Principle of Coordination can

  15. Coordination and Cooperation

    NARCIS (Netherlands)

    M.C.W. Janssen (Maarten)

    2003-01-01

    textabstractThis comment makes four related points. First, explaining coordination is different from explaining cooperation. Second, solving the coordination problem is more important for the theory of games than solving the cooperation problem. Third, a version of the Principle of Coordination can

  16. Objective prior distribution of climate sensitivity

    Science.gov (United States)

    Pueyo, S.

    2012-04-01

    of the climate feedback parameter, which has also been used as a prior in some studies. The log-uniform behaves better than the uniform in the upper tail. These results do not necessarily imply that the log-uniform should be used directly when treating data. The log-uniform represents absence of information, but we do have information preceding the use of any given dataset, for example about the physical processes involved. Ignoring this information could lead to severe biases. The construction of an optimum prior should start from the non-informative prior (of S or of other parameters of which S is a function), and pieces of information should be introduced in the form of partial, explicit and well-justified modifications of this distribution. It would be interesting to initiate a collective process to construct this prior, and, thereafter, to use it by combining several heterogeneous, representative datasets. Reference Pueyo, S. 2011. "Solution to the paradox of climate sensitivity". Clim. Change, doi: 10.1007/s10584-011-0328-x

  17. Variational segmentation problems using prior knowledge in imaging and vision

    DEFF Research Database (Denmark)

    Fundana, Ketut

    This dissertation addresses variational formulation of segmentation problems using prior knowledge. Variational models are among the most successful approaches for solving many Computer Vision and Image Processing problems. The models aim at finding the solution to a given energy functional defined......, prior knowledge is needed to obtain the desired solution. The introduction of shape priors in particular, has proven to be an effective way to segment objects of interests. Firstly, we propose a prior-based variational segmentation model to segment objects of interest in image sequences, that can deal...... pose invariant parameters complicate the optimization of the model. To overcome the common numerical problems associated with the step size of the pose parameters in the discretization of the pose model, we propose a novel gradient procedure for the pose estimation based on the construction...

  18. PFP solution stabilization

    Energy Technology Data Exchange (ETDEWEB)

    Aftanas, B.L.

    1996-04-30

    This Functional Design Criteria (FDC) addresses remediation of the plutonium-bearing solutions currently in inventory at the Plutonium Finishing Plant (PFP). The recommendation from the Environmental Impact Statement (EIS) is that the solutions be treated thermally and stabilized as a solid for long term storage. For solutions which are not discardable, the baseline plan is to utilize a denitration process to stabilize the solutions prior to packaging for storage.

  19. Bayesian priors for transiting planets

    CERN Document Server

    Kipping, David M

    2016-01-01

    As astronomers push towards discovering ever-smaller transiting planets, it is increasingly common to deal with low signal-to-noise ratio (SNR) events, where the choice of priors plays an influential role in Bayesian inference. In the analysis of exoplanet data, the selection of priors is often treated as a nuisance, with observers typically defaulting to uninformative distributions. Such treatments miss a key strength of the Bayesian framework, especially in the low SNR regime, where even weak a priori information is valuable. When estimating the parameters of a low-SNR transit, two key pieces of information are known: (i) the planet has the correct geometric alignment to transit and (ii) the transit event exhibits sufficient signal-to-noise to have been detected. These represent two forms of observational bias. Accordingly, when fitting transits, the model parameter priors should not follow the intrinsic distributions of said terms, but rather those of both the intrinsic distributions and the observational ...

  20. Arthur Prior and medieval logic

    OpenAIRE

    2012-01-01

    Though Arthur Prior is now best known for his founding of modern temporal logic and hybrid logic, much of his early philosophical career was devoted to history of logic and historical logic. This interest laid the foundations for both of his ground-breaking innovations in the 1950s and 1960s. Because of the important rôle played by Prior’s research in ancient and medieval logic in his development of temporal and hybrid logic, any student of Prior, temporal logic, or hybrid logic should be fam...

  1. On the existence of MSA coordinates

    CERN Document Server

    Hernández-Pastora, J L

    2009-01-01

    The static solutions of the axially symmetric vacuum Einstein equations with a finite number of Relativistic Multipole Moments are described by means of a function that can be written in the same analytic form as the Newtonian gravitational multipole potential. A family of so-called MSA (Multipole-Symmetry Adapted) coordinates are introduced and calculated at any multipole order to perform the transformation of the Weyl solutions. In analogy with a previous result obtained in Newtonian gravity, the existence of a symmetry of a certain system of differential equations leading to the determination of that kind of multipole solutions in General Relativity is explored. The relationship between the existence of this kind of coordinate and the symmetries mentioned is proved for some cases, and the characterization of the MSA system of coordinates by means of this relationship is discussed.

  2. Asymptotic admissibility of priors and elliptic differential equations

    CERN Document Server

    Hartigan, J A

    2010-01-01

    We evaluate priors by the second order asymptotic behavior of the corresponding estimators.Under certain regularity conditions, the risk differences between efficient estimators of parameters taking values in a domain D, an open connected subset of R^d, are asymptotically expressed as elliptic differential forms depending on the asymptotic covariance matrix V. Each efficient estimator has the same asymptotic risk as a 'local Bayes' estimate corresponding to a prior density p. The asymptotic decision theory of the estimators identifies the smooth prior densities as admissible or inadmissible, according to the existence of solutions to certain elliptic differential equations. The prior p is admissible if the quantity pV is sufficiently small near the boundary of D. We exhibit the unique admissible invariant prior for V=I,D=R^d-{0). A detailed example is given for a normal mixture model.

  3. TURNAROUND COORDINATOR. YES OR NOT?

    Directory of Open Access Journals (Sweden)

    Martin HROMÁDKA

    2013-12-01

    Full Text Available Both low cost carriers ‘fresh wind’ and liberalisation of ground handling market makes airlines to be cost-wise in every single field. Thus, ground handling contract are cutting down in terms of their costs. Handling companies struggle with pressure being put from the market environment, they rush 25 minutes turnaround with couple of people. This can be potentially dangerous from the safety point of view. One of possible solutions seems to be introducing turnaround coordinator, person who would supervise the ramp handling procedures. This paper discusses the role of turnaround coordinator within the aircraft turnaround process. Duties and responsibilities of this person are described. However, not every airport is staffing this position. The survey shows that smaller airports pay much more attention to this issue than the big ones.

  4. Components of Visual Prior Entry

    Science.gov (United States)

    Schneider, Keith A.; Bavelier, Daphne

    2003-01-01

    The prior entry hypothesis contends that attention accelerates sensory processing, shortening the time to perception. Typical observations supporting the hypothesis may be explained equally well by response biases, changes in decision criteria, or sensory facilitation. In a series of experiments conducted to discriminate among the potential…

  5. Arthur Prior and medieval logic

    NARCIS (Netherlands)

    Uckelman, S.L.

    2012-01-01

    Though Arthur Prior is now best known for his founding of modern temporal logic and hybrid logic, much of his early philosophical career was devoted to history of logic and historical logic. This interest laid the foundations for both of his ground-breaking innovations in the 1950s and 1960s. Becaus

  6. Investigation on Tidal Components in GPS Coordinates

    Science.gov (United States)

    Araszkiewicz, Andrzej; Bogusz, Janusz; Figurski, Mariusz

    2009-01-01

    This paper presents analyses on the GPS coordinates from sub-diurnal solutions of EPN data provided by Warsaw Military University of Technology. The aim of this research is to investigate the way the tidal models used in Bernese software (solid Earth and ocean tides as well) fit to the individual conditions of EPN stations. The 1-hour solution technique of GPS data processing was utilized to obtain coordinates of above 70 EPN stations. Additionally several Polish permanent sites with clearly seen oscillations were examined. This processing technique allowed us to recognize diurnal and sub-diurnal residual oscillations which could be next utilized for validation of the tidal models.

  7. Enhanced time overcurrent coordination

    Energy Technology Data Exchange (ETDEWEB)

    Enriquez, Arturo Conde; Martinez, Ernesto Vazquez [Universidad Autonoma de Nuevo Leon, Facultad de Ingenieria Mecanica y Electrica, Apdo. Postal 114-F, Ciudad Universitaria, CP 66450 San Nicolas de los Garza, Nuevo Leon (Mexico)

    2006-04-15

    In this paper, we recommend a new coordination system for time overcurrent relays. The purpose of the coordination process is to find a time element function that allows it to operate using a constant back-up time delay, for any fault current. In this article, we describe the implementation and coordination results of time overcurrent relays, fuses and reclosers. Experiments were carried out in a laboratory test situation using signals of a power electrical system physics simulator. (author)

  8. Quantum steganography using prior entanglement

    Energy Technology Data Exchange (ETDEWEB)

    Mihara, Takashi, E-mail: mihara@toyo.jp

    2015-06-05

    Steganography is the hiding of secret information within innocent-looking information (e.g., text, audio, image, video, etc.). A quantum version of steganography is a method based on quantum physics. In this paper, we propose quantum steganography by combining quantum error-correcting codes with prior entanglement. In many steganographic techniques, embedding secret messages in error-correcting codes may cause damage to them if the embedded part is corrupted. However, our proposed steganography can separately create secret messages and the content of cover messages. The intrinsic form of the cover message does not have to be modified for embedding secret messages. - Highlights: • Our steganography combines quantum error-correcting codes with prior entanglement. • Our steganography can separately create secret messages and the content of cover messages. • Errors in cover messages do not have affect the recovery of secret messages. • We embed a secret message in the Steane code as an example of our steganography.

  9. Design of non-molecular coordination solids from aqueous solution: [CuIILnX(H2O)], where X=SO4, Cl or H2O and L=pyrazole, imidazole or glutamic acid and = 1 or 4

    Indian Academy of Sciences (India)

    Vineet Kumar; Aritra Kundu; Monika Singh; Kandalam V Ramanujachary; Arunachalam Rramanan

    2014-09-01

    We have successfully crystallized four new non-molecular coordination solids utilizing the synthons-Cu-OSO3- and -Cu-Cl- in the presence of four organic ligands:[{Cu()4SO4}{Cu()4SO4 (H2O)}]. H2O2, [Cu(imi)4SO4]3, [Cu(imi)4(NO3)2]4 and [Cu(glu)Cl(H2O)]5. Use of glutamic acid resulted in two chiral coordination polymers 5 and [Cu(glu)(H2O)]. H2O 6 depending on the copper source. The paper provides chemical insights to the supramolecular aggregation of a crystal driven by the various competing intermolecular forces.

  10. Shared knowledge or shared affordances? Insights from an ecological dynamics approach to team coordination in sports.

    Science.gov (United States)

    Silva, Pedro; Garganta, Júlio; Araújo, Duarte; Davids, Keith; Aguiar, Paulo

    2013-09-01

    Previous research has proposed that team coordination is based on shared knowledge of the performance context, responsible for linking teammates' mental representations for collective, internalized action solutions. However, this representational approach raises many questions including: how do individual schemata of team members become reformulated together? How much time does it take for this collective cognitive process to occur? How do different cues perceived by different individuals sustain a general shared mental representation? This representational approach is challenged by an ecological dynamics perspective of shared knowledge in team coordination. We argue that the traditional shared knowledge assumption is predicated on 'knowledge about' the environment, which can be used to share knowledge and influence intentions of others prior to competition. Rather, during competitive performance, the control of action by perceiving surrounding informational constraints is expressed in 'knowledge of' the environment. This crucial distinction emphasizes perception of shared affordances (for others and of others) as the main communication channel between team members during team coordination tasks. From this perspective, the emergence of coordinated behaviours in sports teams is based on the formation of interpersonal synergies between players resulting from collective actions predicated on shared affordances.

  11. Characterizing traits of coordination

    NARCIS (Netherlands)

    Poss, R.

    2013-01-01

    How can one recognize coordination languages and technologies? As this report shows, the common approach that contrasts coordination with computation is intellectually unsound: depending on the selected understanding of the word "computation", it either captures too many or too few programming

  12. Coordination models and languages

    NARCIS (Netherlands)

    Papadopoulos, G.A.; Arbab, F.

    1998-01-01

    A new class of models, formalisms and mechanisms has recently evolved for describing concurrent and distributed computations based on the concept of ``coordination''. The purpose of a coordination model and associated language is to provide a means of integrating a number of possibly heterogeneous c

  13. Coordinate measuring machines

    DEFF Research Database (Denmark)

    De Chiffre, Leonardo

    This document is used in connection with three exercises of 2 hours duration as a part of the course GEOMETRICAL METROLOGY AND MACHINE TESTING. The exercises concern three aspects of coordinate measuring: 1) Measuring and verification of tolerances on coordinate measuring machines, 2) Traceability...

  14. Social Postural Coordination

    Science.gov (United States)

    Varlet, Manuel; Marin, Ludovic; Lagarde, Julien; Bardy, Benoit G.

    2011-01-01

    The goal of the current study was to investigate whether a visual coupling between two people can produce spontaneous interpersonal postural coordination and change their intrapersonal postural coordination involved in the control of stance. We examined the front-to-back head displacements of participants and the angular motion of their hip and…

  15. Social Postural Coordination

    Science.gov (United States)

    Varlet, Manuel; Marin, Ludovic; Lagarde, Julien; Bardy, Benoit G.

    2011-01-01

    The goal of the current study was to investigate whether a visual coupling between two people can produce spontaneous interpersonal postural coordination and change their intrapersonal postural coordination involved in the control of stance. We examined the front-to-back head displacements of participants and the angular motion of their hip and…

  16. 3D electrical resistivity inversion using prior spatial shape constraints

    Institute of Scientific and Technical Information of China (English)

    Li Shu-Cai; Nie Li-Chao; Liu Bin; Song Jie; Liu Zheng-Yu; Su Mao-Xin; Xu Lei

    2013-01-01

    To minimize the number of solutions in 3D resistivity inversion, an inherent problem in inversion, the amount of data considered have to be large and prior constraints need to be applied. Geological and geophysical data regarding the extent of a geological anomaly are important prior information. We propose the use of shape constraints in 3D electrical resistivity inversion. Three weighted orthogonal vectors (a normal and two tangent vectors) were used to control the resistivity differences at the boundaries of the anomaly. The spatial shape of the anomaly and the constraints on the boundaries of the anomaly are thus established. We incorporated the spatial shape constraints in the objective function of the 3D resistivity inversion and constructed the 3D resistivity inversion equation with spatial shape constraints. Subsequently, we used numerical modeling based on prior spatial shape data to constrain the direction vectors and weights of the 3D resistivity inversion. We established a reasonable range between the direction vectors and weights, and verified the feasibility and effectiveness of using spatial shape prior constraints in reducing excessive structures and the number of solutions. We applied the prior spatially shape-constrained inversion method to locate the aquifer at the Guangzhou subway. The spatial shape constraints were taken from ground penetrating radar data. The inversion results for the location and shape of the aquifer agree well with drilling data, and the number of inversion solutions is significantly reduced.

  17. Modeling, Control and Coordination of Helicopter Systems

    CERN Document Server

    Ren, Beibei; Chen, Chang; Fua, Cheng-Heng; Lee, Tong Heng

    2012-01-01

    Modeling, Control and Coordination of Helicopter Systems provides a comprehensive treatment of helicopter systems, ranging from related nonlinear flight dynamic modeling and stability analysis to advanced control design for single helicopter systems, and also covers issues related to the coordination and formation control of multiple helicopter systems to achieve high performance tasks. Ensuring stability in helicopter flight is a challenging problem for nonlinear control design and development. This book is a valuable reference on modeling, control and coordination of helicopter systems,providing readers with practical solutions for the problems that still plague helicopter system design and implementation. Readers will gain a complete picture of helicopters at the systems level, as well as a better understanding of the technical intricacies involved. This book also: Presents a complete picture of modeling, control and coordination for helicopter systems Provides a modeling platform for a general class of ro...

  18. Coordination of mastication, swallowing and breathing

    Directory of Open Access Journals (Sweden)

    Koichiro Matsuo

    2009-05-01

    Full Text Available The pathways for air and food cross in the pharynx. In breathing, air may flow through either the nose or the mouth; it always flows through the pharynx. During swallowing, the pharynx changes from an airway to a food channel. The pharynx is isolated from the nasal cavity and lower airway by velopharyngeal and laryngeal closure during the pharyngeal swallow. During mastication, the food bolus accumulates in the pharynx prior to swallow initiation. The structures in the oral cavity, pharynx and larynx serve multiple functions in breathing, speaking, mastication and swallowing. Thus, the fine temporal coordination of feeding among breathing, mastication and swallowing is essential to provide proper food nutrition and to prevent pulmonary aspiration. This review paper will review the temporo-spatial coordination of the movements of oral, pharyngeal, and laryngeal structures during mastication and swallowing, and temporal coordination between breathing, mastication, and swallowing.

  19. Coordination of Mastication, Swallowing and Breathing.

    Science.gov (United States)

    Matsuo, Koichiro; Palmer, Jeffrey B

    2009-05-01

    The pathways for air and food cross in the pharynx. In breathing, air may flow through either the nose or the mouth, it always flows through the pharynx. During swallowing, the pharynx changes from an airway to a food channel. The pharynx is isolated from the nasal cavity and lower airway by velopharyngeal and laryngeal closure during the pharyngeal swallow. During mastication, the food bolus accumulates in the pharynx prior to swallow initiation. The structures in the oral cavity, pharynx and larynx serve multiple functions in breathing, speaking, mastication and swallowing. Thus, the fine temporal coordination of feeding among breathing, mastication and swallowing is essential to provide proper food nutrition and to prevent pulmonary aspiration. This review paper will review the temporo-spatial coordination of the movements of oral, pharyngeal, and laryngeal structures during mastication and swallowing, and temporal coordination between breathing, mastication, and swallowing.

  20. Optimal coordinated voltage control of power systems

    Institute of Scientific and Technical Information of China (English)

    LI Yan-jun; HILL David J.; WU Tie-jun

    2006-01-01

    An immune algorithm solution is proposed in this paper to deal with the problem of optimal coordination of local physically based controllers in order to preserve or retain mid and long term voltage stability. This problem is in fact a global coordination control problem which involves not only sequencing and timing different control devices but also tuning the parameters of controllers. A multi-stage coordinated control scheme is presented, aiming at retaining good voltage levels with minimal control efforts and costs after severe disturbances in power systems. A self-pattern-recognized vaccination procedure is developed to transfer effective heuristic information into the new generation of solution candidates to speed up the convergence of the search procedure to global optima. An example of four bus power system case study is investigated to show the effectiveness and efficiency of the proposed algorithm, compared with several existing approaches such as differential dynamic programming and tree-search.

  1. Mirror averaging with sparsity priors

    CERN Document Server

    Dalalyan, Arnak

    2010-01-01

    We consider the problem of aggregating the elements of a (possibly infinite) dictionary for building a decision procedure, that aims at minimizing a given criterion. Along with the dictionary, an independent identically distributed training sample is available, on which the performance of a given procedure can be tested. In a fairly general set-up, we establish an oracle inequality for the Mirror Averaging aggregate based on any prior distribution. This oracle inequality is applied in the context of sparse coding for different problems of statistics and machine learning such as regression, density estimation and binary classification.

  2. Alkali-metal ion coordination in uranyl(VI) poly-peroxide complexes in solution. Part 1: the Li⁺, Na⁺ and K⁺--peroxide-hydroxide systems.

    Science.gov (United States)

    Zanonato, Pier Luigi; Di Bernardo, Plinio; Vallet, Valerie; Szabó, Zoltán; Grenthe, Ingmar

    2015-01-28

    The alkali metal ions Li(+), Na(+) and K(+) have a profound influence on the stoichiometry of the complexes formed in uranyl(VI)-peroxide-hydroxide systems, presumably as a result of a templating effect, resulting in the formation of two complexes, M[(UO2)(O2)(OH)]2(-) where the uranyl units are linked by one peroxide bridge, μ-η(2)-η(2), with the second peroxide coordinated "end-on", η(2), to one of the uranyl groups, and M[(UO2)(O2)(OH)]4(3-), with a four-membered ring of uranyl ions linked by μ-η(2)-η(2) peroxide bridges. The stoichiometry and equilibrium constants for the reactions: M(+) + 2UO2(2+) + 2HO2(-) + 2H2O → M[(UO2)(O2)(OH)]2(-) + 4H(+) (1) and M(+) + 4UO2(2+) + 4HO2(-) + 4H2O → M[(UO2)(O2)(OH)]4(3-) + 8H(+) (2) have been measured at 25 °C in 0.10 M (tetramethyl ammonium/M(+))NO3 ionic media using reaction calorimetry. Both reactions are strongly enthalpy driven with large negative entropies of reaction; the observation that ΔH(2) ≈ 2ΔH(1) suggests that the enthalpy of reaction is approximately the same when peroxide is added in bridging and "end-on" positions. The thermodynamic driving force in the reactions is the formation of strong peroxide bridges and the role of M(+) cations is to provide a pathway with a low activation barrier between the reactants and in this way "guide" them to form peroxide bridged complexes; they play a similar role as in the synthesis of crown-ethers. Quantum chemical (QC) methods were used to determine the structure of the complexes, and to demonstrate how the size of the M(+)-ions affects their coordination geometry. There are several isomers of Na[(UO2)(O2)(OH)]2(-) and QC energy calculations show that the ones with a peroxide bridge are substantially more stable than the ones with hydroxide bridges. There are isomers with different coordination sites for Na(+) and the one with coordination to the peroxide bridge and two uranyl oxygen atoms is the most stable one.

  3. Mirror black and white holes from generalized Kruskal coordinates

    OpenAIRE

    Nieto, Juan Antonio; Aguilar, José Edgar Madriz

    2016-01-01

    By introducing generalized Kruskal coordinates in the typical Schwazschild black hole metric solution we obtain a new kind of metric solutions that can be interpreted as mirror black and white holes. We found that this new type of mirror black and white holes solutions in $(3+1)$-dimensions suggest that the original space-time can be extended to $(4+4)$-signature.

  4. Integrating prior knowledge and structure from motion

    DEFF Research Database (Denmark)

    Guilbert, Nicolas; Aanæs, Henrik; Larsen, Rasmus

    2001-01-01

    A new approach for formulating prior knowledge in structure form motion is presented, where the structure is viewed as a 3D stochastic variable, hereby priors are more naturally expressed. It is demonstrated that this formulation is efficient for regularizing structure reconstruction via prior...... knowledge. Specifically algorithms for imposing priors in the proposed formulation are presented....

  5. Motion prediction in geodetic coordinate systems: A solution based on Gaussian distribution%大地坐标系下目标运动预测:一种基于高斯分布的求解方法

    Institute of Scientific and Technical Information of China (English)

    慈元卓; 谭跃进; 徐一帆; 贺仁杰

    2011-01-01

    The unknown parameters of moving target bring uncertainty to moving target search which constrains the optimal search plan making and impairs surveillance assets efficiency. Motion prediction in geodetic coordinate systems, as a way to depress the effect of uncertainty and to optimize the search plan, is well discussed: firstly, moving target motion in plane Cartesian coordinate systems is analyzed and a Gaussian distribution of target transition probability density function (PDF) is deduced; secondly,the PDF is extended to denote .target transition probability in 3-D Cartesian coordinate; thirdly, the method for computing the target transition probability in geodetic coordinate systems based on Gaussian distribution is deduced by coordinate systems transformation and curved surface integral method; finally, a simulation scenario with high fidelity satellite orbit data is utilized to verify the motion prediction algorithm in the problem of moving target search by satellite. The simulation performance statistics show that the prediction algorithm is effective which can decrease the uncertainty and reduce the eyeless search during making search plan.%目标运动参数未知给移动目标优化搜索问题带来不确定性,制约了优化搜索计划的制定、降低了侦察监视资源的使用效益.为了降低目标运动引入的不确定性影响和辅助目标优化搜索计划的制定,针对大地坐标系下目标运动预测问题,首先在平面笛卡尔坐标系下对目标的运动进行分析,推导出一种基于高斯分布的目标转移概率密度函数;然后在三维笛卡尔坐标系内进行扩展,得到地球表面上目标运动转移概率的数学描述;接下来借助坐标转换原理和曲面积分方法,提出了大地坐标系下基于高斯分布的目标转移概率计算方法;最后针对卫星对地移动目标搜索中的目标运动预测问题,采用高可信的卫星轨道数据建立T仿真场景进行验证.仿真统

  6. Magnetic Coordinate Systems

    CERN Document Server

    Laundal, K M

    2016-01-01

    Geospace phenomena such as the aurora, plasma motion, ionospheric currents and associated magnetic field disturbances are highly organized by Earth's main magnetic field. This is due to the fact that the charged particles that comprise space plasma can move almost freely along magnetic field lines, but not across them. For this reason it is sensible to present such phenomena relative to Earth's magnetic field. A large variety of magnetic coordinate systems exist, designed for different purposes and regions, ranging from the magnetopause to the ionosphere. In this paper we review the most common magnetic coordinate systems and describe how they are defined, where they are used, and how to convert between them. The definitions are presented based on the spherical harmonic expansion coefficients of the International Geomagnetic Reference Field (IGRF) and, in some of the coordinate systems, the position of the Sun which we show how to calculate from the time and date. The most detailed coordinate systems take the...

  7. Supercritical Airfoil Coordinates

    Data.gov (United States)

    National Aeronautics and Space Administration — Rectangular Supercritical Wing (Ricketts) - design and measured locations are provided in an Excel file RSW_airfoil_coordinates_ricketts.xls . One sheet is with Non...

  8. Understanding social motor coordination.

    Science.gov (United States)

    Schmidt, R C; Fitzpatrick, Paula; Caron, Robert; Mergeche, Joanna

    2011-10-01

    Recently there has been much interest in social coordination of motor movements, or as it is referred to by some researchers, joint action. This paper reviews the cognitive perspective's common coding/mirror neuron theory of joint action, describes some of its limitations and then presents the behavioral dynamics perspective as an alternative way of understanding social motor coordination. In particular, behavioral dynamics' ability to explain the temporal coordination of interacting individuals is detailed. Two experiments are then described that demonstrate how dynamical processes of synchronization are apparent in the coordination underlying everyday joint actions such as martial art exercises, hand-clapping games, and conversations. The import of this evidence is that emergent dynamic patterns such as synchronization are the behavioral order that any neural substrate supporting joint action (e.g., mirror systems) would have to sustain.

  9. Environmental Compliance Issue Coordination

    Science.gov (United States)

    An order to establish the Department of Energy (DOE) requirements for coordination of significant environmental compliance issues to ensure timely development and consistent application of Departmental environmental policy and guidance

  10. Alkali-metal ion coordination in uranyl(VI) poly-peroxo complexes in solution, inorganic analogues to crown-ethers. Part 2. Complex formation in the tetramethyl ammonium-, Li(+)-, Na(+)- and K(+)-uranyl(VI)-peroxide-carbonate systems.

    Science.gov (United States)

    Zanonato, Pier Luigi; Szabó, Zoltán; Vallet, Valerie; Di Bernardo, Plinio; Grenthe, Ingmar

    2015-10-01

    The constitution and equilibrium constants of ternary uranyl(vi) peroxide carbonate complexes [(UO2)p(O2)q(CO3)r](2(p-q-r)) have been determined at 0 °C in 0.50 M MNO3, M = Li, K, and TMA (tetramethyl ammonium), ionic media using potentiometric and spectrophotometric data; (17)O NMR data were used to determine the number of complexes present. The formation of cyclic oligomers, "[(UO2)(O2)(CO3)]n", n = 4, 5, 6, with different stoichiometries depending on the ionic medium used, suggests that Li(+), Na(+), K(+) and TMA ions act as templates for the formation of uranyl peroxide rings where the uranyl-units are linked by μ-η(2)-η(2) bridged peroxide-ions. The templating effect is due to the coordination of the M(+)-ions to the uranyl oxygen atoms, where the coordination of Li(+) results in the formation of Li[(UO2)(O2)(CO3)]4(7-), Na(+) and K(+) in the formation of Na/K[(UO2)(O2)(CO3)]5(9-) complexes, while the large tetramethyl ammonium ion promotes the formation of two oligomers, TMA[(UO2)(O2)(CO3)]5(9-) and TMA[(UO2)(O2)(CO3)]6(11-). The NMR spectra demonstrate that the coordination of Na(+) in the five- and six-membered oligomers is significantly stronger than that of TMA(+); these observations suggest that the templating effect is similar to the one observed in the synthesis of crown-ethers. The NMR experiments also demonstrate that the exchange between TMA[(UO2)(O2)(CO3)]5(9-) and TMA[(UO2)(O2)(CO3)]6(11-) is slow on the (17)O chemical shift time-scale, while the exchange between TMA[(UO2)(O2)(CO3)]6(11-) and Na[(UO2)(O2)(CO3)]6(11-) is fast. There was no indication of the presence of large clusters of the type identified by Burns and Nyman (M. Nyman and P. C. Burns, Chem. Soc. Rev., 2012, 41, 7314-7367) and possible reasons for this and the implications for the synthesis of large clusters are briefly discussed.

  11. A Relativistic Algorithm with Isotropic Coordinates

    Directory of Open Access Journals (Sweden)

    S. A. Ngubelanga

    2013-01-01

    Full Text Available We study spherically symmetric spacetimes for matter distributions with isotropic pressures. We generate new exact solutions to the Einstein field equations which also contain isotropic pressures. We develop an algorithm that produces a new solution if a particular solution is known. The algorithm leads to a nonlinear Bernoulli equation which can be integrated in terms of arbitrary functions. We use a conformally flat metric to show that the integrals may be expressed in terms of elementary functions. It is important to note that we utilise isotropic coordinates unlike other treatments.

  12. [Coordination and donation].

    Science.gov (United States)

    Elizalde, J; Lorente, M

    2006-01-01

    The progressive incorporation of organ transplants as a therapeutic resource resulted in organisational adaptation and overall transplant management, leading to the emergence of the figure of the transplant coordinator in the mid-1980s. In Spain, the National Organisation of Transplants (Organización Nacional de Transplantes - ONT) was created, establishing a system - called the "Spanish model" - based on a network of coordinators at three levels: national, the autonomous community and the hospital. This organisational structure is a point of reference at the world level. The prevalence of the Intensive Medicine specialisation amongst hospital transplant coordinators is remarkable. The majority of organs proceed from brain-dead patients with beating hearts and this requires the infrastructure offered by intensive care units. The functions of the coordinator can be summarised in guaranteeing a synchrony of all the elements and teams that come together in an organisational chain that has come to be called the "process of donation". Schematically, the crucial points that the hospital coordinator develops are the following: - Detection of the potential donor. - Maintenance of the donor. - Diagnosis of brain death. - Family consent. - Preparation of the hospital logistics. - Helping the relatives. - Direct involvement in the Program of Guarantee of Quality. - Person of reference in any activity related to the transplant. It would be desirable to achieve the creation of transplant coordination teams, with univocal messages, professionalism and a permanent input of the so-called "human factor", which is so necessary and also so close to the transplant world.

  13. Continuous parallel coordinates.

    Science.gov (United States)

    Heinrich, Julian; Weiskopf, Daniel

    2009-01-01

    Typical scientific data is represented on a grid with appropriate interpolation or approximation schemes,defined on a continuous domain. The visualization of such data in parallel coordinates may reveal patterns latently contained in the data and thus can improve the understanding of multidimensional relations. In this paper, we adopt the concept of continuous scatterplots for the visualization of spatially continuous input data to derive a density model for parallel coordinates. Based on the point-line duality between scatterplots and parallel coordinates, we propose a mathematical model that maps density from a continuous scatterplot to parallel coordinates and present different algorithms for both numerical and analytical computation of the resulting density field. In addition, we show how the 2-D model can be used to successively construct continuous parallel coordinates with an arbitrary number of dimensions. Since continuous parallel coordinates interpolate data values within grid cells, a scalable and dense visualization is achieved, which will be demonstrated for typical multi-variate scientific data.

  14. Magnetic Coordinate Systems

    Science.gov (United States)

    Laundal, K. M.; Richmond, A. D.

    2017-03-01

    Geospace phenomena such as the aurora, plasma motion, ionospheric currents and associated magnetic field disturbances are highly organized by Earth's main magnetic field. This is due to the fact that the charged particles that comprise space plasma can move almost freely along magnetic field lines, but not across them. For this reason it is sensible to present such phenomena relative to Earth's magnetic field. A large variety of magnetic coordinate systems exist, designed for different purposes and regions, ranging from the magnetopause to the ionosphere. In this paper we review the most common magnetic coordinate systems and describe how they are defined, where they are used, and how to convert between them. The definitions are presented based on the spherical harmonic expansion coefficients of the International Geomagnetic Reference Field (IGRF) and, in some of the coordinate systems, the position of the Sun which we show how to calculate from the time and date. The most detailed coordinate systems take the full IGRF into account and define magnetic latitude and longitude such that they are constant along field lines. These coordinate systems, which are useful at ionospheric altitudes, are non-orthogonal. We show how to handle vectors and vector calculus in such coordinates, and discuss how systematic errors may appear if this is not done correctly.

  15. Numerical study of bipolar coordinate Jeffery-Hamel flow

    Science.gov (United States)

    Matyas, Alpar; Nagy, Botond

    2017-07-01

    In this paper we report the bipolar coordinate formulation of Jeffery-Hamel (JH) flow and study vorticity-stream function, bipolar coordinate JH and conventional JH solutions. It is shown that our derived equation can intrinsically describe the flow behavior in curved geometries and it gives improved results as compared to conventional JH theory.

  16. Coordinated Platoon Routing in a Metropolitan Network

    Energy Technology Data Exchange (ETDEWEB)

    Larson, Jeffrey; Munson, Todd; Sokolov, Vadim

    2016-10-10

    Platooning vehicles—connected and automated vehicles traveling with small intervehicle distances—use less fuel because of reduced aerodynamic drag. Given a network de- fined by vertex and edge sets and a set of vehicles with origin/destination nodes/times, we model and solve the combinatorial optimization problem of coordinated routing of vehicles in a manner that routes them to their destination on time while using the least amount of fuel. Common approaches decompose the platoon coordination and vehicle routing into separate problems. Our model addresses both problems simultaneously to obtain the best solution. We use modern modeling techniques and constraints implied from analyzing the platoon routing problem to address larger numbers of vehicles and larger networks than previously considered. While the numerical method used is unable to certify optimality for candidate solutions to all networks and parameters considered, we obtain excellent solutions in approximately one minute for much larger networks and vehicle sets than previously considered in the literature.

  17. Identifiability of linear systems in physical coordinates

    Science.gov (United States)

    Su, Tzu-Jeng; Juang, Jer-Nan

    1992-01-01

    Identifiability of linear, time-invariant systems in physical coordinates is discussed. It is shown that identification of the system matrix in physical coordinates can be accomplished by determining a transformation matrix that relates the physical locations of actuators and sensors to the test-data-derived input and output matrices. For systems with symmetric matrices, the solution of a constrained optimization problem is used to characterize all the possible solutions of the transformation matrix. Conditions for the existence of a unique transformation matrix are established easily from the explicit form of the solutions. For systems with limited inputs and outputs, the question about which part of the system can be uniquely identified is also answered. A simple mass-spring system is used to verify the conclusions of this study.

  18. 24 hours prior to curtain.

    Science.gov (United States)

    Mishra, S; Rosen, C A; Murry, T

    2000-03-01

    A retrospective review was conducted of 40 singers presenting with acute voice problems prior to performance. The purpose of this study was to determine the reasons for seeking emergent voice treatment, the types of acute voice disorders, and the performance outcome. The patients were assessed by age, singing style, years of experience, chief complaint, laryngovideostroboscopic findings, and treatment regimens. The outcomes were classified as full, restricted, or no performance. The majority of patients were classical singers. Laryngovideostroboscopy frequently revealed a pattern of early glottic contact at the mid-portion of the membranous vocal fold in patients with acute laryngitis. Experienced singers uniformly sought treatment many days before their performance compared with inexperienced singers who presented closer in time to performance. Six patients initially withheld information, which had a bearing on their acute management. The results of this study suggest that there is a need to accurately diagnose and treat the singer's emergent problem and educate singers regarding early evaluation of medical problems. With modern evaluation techniques and multi-modality treatment, 85% of the singers proceeded to full performance without negative sequelae.

  19. A Frequency Matching Method: Solving Inverse Problems by Use of Geologically Realistic Prior Information

    DEFF Research Database (Denmark)

    Lange, Katrine; Frydendall, Jan; Cordua, Knud Skou

    2012-01-01

    The frequency matching method defines a closed form expression for a complex prior that quantifies the higher order statistics of a proposed solution model to an inverse problem. While existing solution methods to inverse problems are capable of sampling the solution space while taking into accou...

  20. Coordination of the New Schiff Base with Copper(Ⅱ) or Iron(Ⅲ) in Solution%新席夫碱与铜(Ⅱ)、铁(Ⅲ)在溶液中的配位反应研究

    Institute of Scientific and Technical Information of China (English)

    郑璇; 赵毅; 朱必学

    2011-01-01

    A new Schiff base C33H31N4O5(L) was synthesized from l-(3-pyridyl)-l, 3-butanedione and 1, 3-bis(2-aminophenoxyl)-2-propanol. The structure of the Schiff base was determined by X-ray diffraction analysis. Furthermore, the coordination reaction of the Schiff base with Cu(II) or Fe(DD was investigated via UV-Vis spectroscopy, the stability constants of the two complexes were determined respectively. CCDC: 797351.%以1-(3-吡啶基)-1,3-丁二酮和1.3-二(2-胺基苯氧基)-2-丙醇进行缩合得到席夫碱1,3-二(2-胺基苯氧基)-2-丙醇缩双1-(3-吡啶基)丁烷-1,3-丁二酮(L),并通过单晶X射线衍射解析了Schiff碱配体(L)的结构.进一步将Schiff碱配体L与金属铜(Ⅱ)、铁(Ⅲ)进行配位反应.采用UV-Vis光谱技术,分别测定了铜(Ⅱ)、铁(Ⅲ)配合物的稳定常数.

  1. Coordinating Interactions: The Event Coordination Notation

    DEFF Research Database (Denmark)

    Kindler, Ekkart

    on a much more technical level. The Event Coordination Notation (ECNO) allows modelling the behaviour of an application on a high level of abstraction that is closer to the application’s domain than to the software realizing it. Still, these models contain all necessary details for actually executing...... implementation of ECNO, which consists of a modelling environment based on Eclipse and the Eclipse Modeling Framework (EMF) and an execution engine, which fully supports all the concepts and features of ECNO discussed in this technical report. All the examples are based on EMF, but the ECNO Engine can be used......The purpose of a domain model is to concisely capture the concepts of an application’s domain, and their relation among each other. Even though the main purpose of domain models is not on implementing the application, major parts of an application can be generated from the application’s domain...

  2. Quantifying linguistic coordination

    DEFF Research Database (Denmark)

    Fusaroli, Riccardo; Tylén, Kristian

    ). We employ nominal recurrence analysis (Orsucci et al 2005, Dale et al 2011) on the decision-making conversations between the participants. We report strong correlations between various indexes of recurrence and collective performance. We argue this method allows us to quantify the qualities......Language has been defined as a social coordination device (Clark 1996) enabling innovative modalities of joint action. However, the exact coordinative dynamics over time and their effects are still insufficiently investigated and quantified. Relying on the data produced in a collective decision...

  3. Introduction to Coordination Chemistry

    CERN Document Server

    Lawrance, Geoffrey Alan

    2010-01-01

    Introduction to Coordination Chemistry examines and explains how metals and molecules that bind as ligands interact, and the consequences of this assembly process. This book describes the chemical and physical properties and behavior of the complex assemblies that form, and applications that may arise as a result of these properties. Coordination complexes are an important but often hidden part of our world?even part of us?and what they do is probed in this book. This book distills the essence of this topic for undergraduate students and for research scientists.

  4. Coordinate Standard Measurement Development

    Energy Technology Data Exchange (ETDEWEB)

    Hanshaw, R.A.

    2000-02-18

    A Shelton Precision Interferometer Base, which is used for calibration of coordinate standards, was improved through hardware replacement, software geometry error correction, and reduction of vibration effects. Substantial increases in resolution and reliability, as well as reduction in sampling time, were achieved through hardware replacement; vibration effects were reduced substantially through modification of the machine component dampening and software routines; and the majority of the machine's geometry error was corrected through software geometry error correction. Because of these modifications, the uncertainty of coordinate standards calibrated on this device has been reduced dramatically.

  5. 34 CFR 642.32 - Prior experience.

    Science.gov (United States)

    2010-07-01

    ... 34 Education 3 2010-07-01 2010-07-01 false Prior experience. 642.32 Section 642.32 Education....32 Prior experience. (a)(1) The Secretary gives priority to each applicant that has conducted a... points to be awarded each eligible applicant, the Secretary considers the applicant's prior experience of...

  6. Iterated random walks with shape prior

    DEFF Research Database (Denmark)

    Pujadas, Esmeralda Ruiz; Kjer, Hans Martin; Piella, Gemma;

    2016-01-01

    We propose a new framework for image segmentation using random walks where a distance shape prior is combined with a region term. The shape prior is weighted by a confidence map to reduce the influence of the prior in high gradient areas and the region term is computed with k-means to estimate th...

  7. Non-commutativity in polar coordinates

    CERN Document Server

    Edwards, James P

    2016-01-01

    We reconsider the fundamental commutation relations for non-commutative $\\mathbb{R}^{2}$ described in polar coordinates with non-commutativity parameter $\\theta$. Previous analysis found that the natural transition from Cartesian coordinates to polars led to a representation of $\\left[\\hat{r}, \\hat{\\varphi}\\right]$ as an everywhere diverging series. We compute the Borel resummation of this series, showing that it can subsequently be extended throughout parameter space and hence provide an interpretation of this commutator. Our analysis provides a complete solution for arbitrary $r$ and $\\theta$ that reproduces the earlier calculations at lowest order. We compare our results to previous literature in the (pseudo-)commuting limit, finding a surprising spatial dependence for the coordinate commutator when $\\theta \\gg r^{2}$. We raise some questions for future study in light of this progress.

  8. Non-commutativity in polar coordinates

    Energy Technology Data Exchange (ETDEWEB)

    Edwards, James P. [Universidad Michoacana de San Nicolas de Hidalgo, Ciudad Universitaria, Instituto de Fisica y Matematicas, Morelia, Michoacan (Mexico)

    2017-05-15

    We reconsider the fundamental commutation relations for non-commutative R{sup 2} described in polar coordinates with non-commutativity parameter θ. Previous analysis found that the natural transition from Cartesian coordinates to the traditional polar system led to a representation of [r, φ] as an everywhere diverging series. In this article we compute the Borel resummation of this series, showing that it can subsequently be extended throughout parameter space and hence provide an interpretation of this commutator. Our analysis provides a complete solution for arbitrary r and θ that reproduces the earlier calculations at lowest order and benefits from being generally applicable to problems in a two-dimensional non-commutative space. We compare our results to previous literature in the (pseudo-)commuting limit, finding a surprising spatial dependence for the coordinate commutator when θ >> r{sup 2}. Finally, we raise some questions for future study in light of this progress. (orig.)

  9. 应用多波前法快速求解最优协调电压控制问题%Fast Solution for Optimal Coordinated Voltage Control Using Multifrontal Method

    Institute of Scientific and Technical Information of China (English)

    郑文杰; 刘明波

    2011-01-01

    将长期电压稳定场景下的协调电压控制问题用带有微分-代数方程约束的最优控制模型来描述,借助Radau排列技术将这个动态优化问题转化为大型非线性规划模型,并采用非线性原-对偶内点法求解.重点探讨如何应用多波前方法结合近似最小度排序提高求解稀疏线性修正方程的效率.以IEEE 17机162节点系统和新英格兰10机39节点系统作为算例,通过与近似最小度法和反向Cuthill-McKee法排序下三角分解结果进行对比,证实了所述方法在计算速度上的优越性.%A differential algebraic equation optimization model is used to describe the optimal coordinated voltage control problem in the long-term voltage stability scenario. This dynamic optimization problem can be converted into a large-scale nonlinear programming model using Radau collocation method. The nonlinear primal-dual interior-point method is then applied to solve this problem. This paper focuses on application of the multifrontal method to enhance the efficiency of solving sparse linear correction equations by referring to approximate minimum degree permutation. The IEEE 17-generator 162-bus test system and New England 10-generator 39-bus system are used to verify the effectiveness of the method proposed for comparison with the triangular decomposition using other permutation methods such as approximate minimum degree and reversed Cuthill-McKee.

  10. Coordination failure caused by sunspots

    DEFF Research Database (Denmark)

    Beugnot, Julie; Gürgüç, Zeynep; Øvlisen, Frederik Roose

    2012-01-01

    In a coordination game with Pareto-ranked equilibria, we study whether a sunspot can lead to either coordination on an inferior equilibrium (mis-coordination) or to out-of equilibrium behavior (dis-coordination). While much of the literature searches for mechanisms to attain coordination...... on the efficient equilibrium, we consider sunspots as a potential reason for coordination failure. We conduct an experiment with a three player 2x2x2 game in which coordination on the efficient equilibrium is easy and should normally occur. In the control session, we find almost perfect coordination on the payoff......-dominant equilibrium, but in the sunspot treatment, dis-coordination is frequent. Sunspots lead to significant inefficiency, and we conclude that sunspots can indeed cause coordination failure....

  11. Coordinating Work with Groupware

    DEFF Research Database (Denmark)

    Pors, Jens Kaaber; Simonsen, Jesper

    2003-01-01

    One important goal of employing groupware is to make possible complex collaboration between geographically distributed groups. This requires a dual transformation of both technology and work practice. The challenge is to re­duce the complexity of the coordination work by successfully inte­grating...

  12. Rockin' Readers Coordinator Handbook.

    Science.gov (United States)

    Alachua County Schools, Gainesville, FL.

    This coordinator's handbook describes the "Rockin' Readers" program, in which senior-citizen volunteers are matched with specifically targeted at-risk children (usually of kindergarten age or slightly older) in Alachua County, Florida, who tested below their peer group in language development and reading readiness skills. The handbook…

  13. Explicit Spin Coordinates

    CERN Document Server

    Hunter, G; Hunter, Geoffrey; Schlifer, Ian

    2005-01-01

    The recently established existence of spherical harmonic functions, $Y_\\ell^{m}(\\theta,\\phi)$ for half-odd-integer values of $\\ell$ and $m$, allows for the introduction into quantum chemistry of explicit electron spin-coordinates; i.e. spherical polar angles $\\theta_s, \\phi_s$, that specify the orientation of the spin angular momentum vector in space. In this coordinate representation the spin angular momentum operators, $S^2, S_z$, are represented by the usual differential operators in spherical polar coordinates (commonly used for $L^2, L_z$), and their electron-spin eigenfunctions are $\\sqrt{\\sin\\theta_s} \\exp(\\pm\\phi_s/2)$. This eigenfunction representation has the pedagogical advantage over the abstract spin eigenfunctions, $\\alpha, \\beta,$ that ``integration over spin coordinates'' is a true integration (over the angles $\\theta_s, \\phi_s$). In addition they facilitate construction of many electron wavefunctions in which the electron spins are neither parallel nor antiparallel, but inclined at an interme...

  14. Equilibria with Coordination Failures

    NARCIS (Netherlands)

    Herings, P.J.J.; van der Laan, G.; Talman, A.J.J.

    2004-01-01

    This paper extends the recent literature on equilibria with coordination failures to arbitrary convex sets of admissible prices.We introduce a new equilibrium concept, called quantity constrained equilibrium (QCE), giving a uni.ed treatment to all cases considered in the literature so far.At a QCE

  15. Block coordination copolymers

    Science.gov (United States)

    Koh, Kyoung Moo; Wong-Foy, Antek G; Matzger, Adam J; Benin, Annabelle I; Willis, Richard R

    2012-11-13

    The present invention provides compositions of crystalline coordination copolymers wherein multiple organic molecules are assembled to produce porous framework materials with layered or core-shell structures. These materials are synthesized by sequential growth techniques such as the seed growth technique. In addition, the invention provides a simple procedure for controlling functionality.

  16. High dosage of monosodium glutamate causes deficits of the motor coordination and the number of cerebellar Purkinje cells of rats.

    Science.gov (United States)

    Prastiwi, D; Djunaidi, A; Partadiredja, G

    2015-11-01

    Monosodium glutamate (MSG) has been widely used throughout the world as a flavoring agent of food. However, MSG at certain dosages is also thought to cause damage to many organs, including cerebellum. This study aimed at investigating the effects of different doses of MSG on the motor coordination and the number of Purkinje cells of the cerebellum of Wistar rats. A total of 24 male rats aged 4 to 5 weeks were divided into four groups, namely, control (C), T2.5, T3, and T3.5 groups, which received intraperitoneal injection of 0.9% sodium chloride solution, 2.5 mg/g body weight (bw) of MSG, 3.0 mg/g bw of MSG, and 3.5 mg/g bw of MSG, respectively, for 10 consecutive days. The motor coordination of the rats was examined prior and subsequent to the treatment. The number of cerebellar Purkinje cells was estimated using physical fractionator method. It has been found that the administration of MSG at a dosage of 3.5 mg/g bw, but not at lower dosages, caused a significant decrease of motor coordination and the estimated total number of Purkinje cells of rats. There was also a significant correlation between motor coordination and the total number of Purkinje cells.

  17. The power prior: theory and applications.

    Science.gov (United States)

    Ibrahim, Joseph G; Chen, Ming-Hui; Gwon, Yeongjin; Chen, Fang

    2015-12-10

    The power prior has been widely used in many applications covering a large number of disciplines. The power prior is intended to be an informative prior constructed from historical data. It has been used in clinical trials, genetics, health care, psychology, environmental health, engineering, economics, and business. It has also been applied for a wide variety of models and settings, both in the experimental design and analysis contexts. In this review article, we give an A-to-Z exposition of the power prior and its applications to date. We review its theoretical properties, variations in its formulation, statistical contexts for which it has been used, applications, and its advantages over other informative priors. We review models for which it has been used, including generalized linear models, survival models, and random effects models. Statistical areas where the power prior has been used include model selection, experimental design, hierarchical modeling, and conjugate priors. Frequentist properties of power priors in posterior inference are established, and a simulation study is conducted to further examine the empirical performance of the posterior estimates with power priors. Real data analyses are given illustrating the power prior as well as the use of the power prior in the Bayesian design of clinical trials.

  18. Training a system-literate care coordination workforce

    DEFF Research Database (Denmark)

    Naccarella, Lucio; Osborne, Richard H.; Brooks, Peter M.

    2016-01-01

    People with chronic complex conditions continue to experience increasing health system fragmentation and poor coordination. To reverse these trends, one solution has been an investment in effective models of care coordination that use a care coordinator workforce. Care coordinators...... standards for the care coordinator workforce. With the growing complexity and fragmentation of the health care system, health system literacy - shared understanding of the roles and contributions of the different workforce professions, organisations and systems, among patients and indeed the health...... workforce is required. Efforts to improve health system literacy among the health workforce are increasing at a policy, practice and research level. However, insufficient evidence exists about what are the health system literacy needs of care coordinators, and what is required for them to be most effective...

  19. The role of simulation prior to manufacturing in space

    Science.gov (United States)

    Shaw, M. C.

    1983-01-01

    Prior to manufacturing in space, it is useful to conduct analog experiments where possible so that problems that are apt to be encountered may be identified and planning toward their solution considered. An example is presented involving containerless casting in a near zero gravitational field using paraffin wax as the material cast surrounded by a heated fluid immiscible with the wax that renders it neutrally buoyant.

  20. Topochemical control in desolvation of coordination polymers

    OpenAIRE

    Matteo Lusi

    2015-01-01

    Reactions in the solid state are at the core of crystal engineering as they can result in new crystalline phases that are not always accessible by traditional solution methods. The work of Brammer and co-workers [Wright et al. (2015), IUCrJ, 2, 188–197] represents a clear example of this potential as applied to the synthesis of a silver–phenazine coordination polymer.

  1. Training a system-literate care coordination workforce.

    Science.gov (United States)

    Naccarella, Lucio; Osborne, Richard H; Brooks, Peter M

    2016-04-01

    People with chronic complex conditions continue to experience increasing health system fragmentation and poor coordination. To reverse these trends, one solution has been an investment in effective models of care coordination that use a care coordinator workforce. Care coordinators are not a homogenous workforce - but an applied professional role, providing direct and indirect care, and is often undertaken by nurses, allied health professionals, social workers or general practitioners. In Australia, there is no training curriculum nor courses, nor nationally recognised professional quality standards for the care coordinator workforce. With the growing complexity and fragmentation of the health care system, health system literacy - shared understanding of the roles and contributions of the different workforce professions, organisations and systems, among patients and indeed the health workforce is required. Efforts to improve health system literacy among the health workforce are increasing at a policy, practice and research level. However, insufficient evidence exists about what are the health system literacy needs of care coordinators, and what is required for them to be most effective. Key areas to build a health system literate care coordination workforce are presented. Care coordination is more than an optional extra, but one of the only ways we are going to be able to provide equitable health services for people with chronic complex conditions. People with low health literacy require more support with the coordination of their care, therefore we need to build a high performing care coordinator workforce that upholds professional quality standards, and is health literacy responsive.

  2. A framework of manufacturer-retailer coordination process

    DEFF Research Database (Denmark)

    Wong, Chee Yew; Johansen, John

    2008-01-01

    Purpose - Triggered by perceived inefficiency and inequality, buyers and suppliers coordinate with each other. The purpose of this paper is to develop a framework of coordination process based on theoretical review and verifications from three case studies. Design/methodology/approach - The appro......Purpose - Triggered by perceived inefficiency and inequality, buyers and suppliers coordinate with each other. The purpose of this paper is to develop a framework of coordination process based on theoretical review and verifications from three case studies. Design....../methodology/approach - The approach takes the form of three longitudinal and in-depth case studies, which involved coordination processes between a toy manufacturer with three European retailers in one calendar year. Findings - The three case studies provided three main observations. First, the coordination process followed some...... there was disagreement. Third, closer mode of coordination, which involved joint evaluation and derivation of coordination solutions, reduced the numbers of iterative coordination cycles. These empirical findings verified the presupposed framework of coordination process. Research limitations/implications - Three...

  3. Coordination Between the Sexes Constrains the Optimization of Reproductive Timing in Honey Bee Colonies.

    Science.gov (United States)

    Lemanski, Natalie J; Fefferman, Nina H

    2017-06-01

    Honeybees are an excellent model system for examining how trade-offs shape reproductive timing in organisms with seasonal environments. Honeybee colonies reproduce two ways: producing swarms comprising a queen and thousands of workers or producing males (drones). There is an energetic trade-off between producing workers, which contribute to colony growth, and drones, which contribute only to reproduction. The timing of drone production therefore determines both the drones' likelihood of mating and when colonies reach sufficient size to swarm. Using a linear programming model, we ask when a colony should produce drones and swarms to maximize reproductive success. We find the optimal behavior for each colony is to produce all drones prior to swarming, an impossible solution on a population scale because queens and drones would never co-occur. Reproductive timing is therefore not solely determined by energetic trade-offs but by the game theoretic problem of coordinating the production of reproductives among colonies.

  4. Synthesis, spectroscopic characterization, and determination of the solution association energy of the dimer [Co{N(SiMe3)2}2]2: magnetic studies of low-coordinate Co(II) silylamides [Co{N(SiMe3)2}2L] (L = PMe3, pyridine, and THF) and related species that reveal evidence of very large zero-field splittings.

    Science.gov (United States)

    Bryan, Aimee M; Long, Gary J; Grandjean, Fernande; Power, Philip P

    2013-10-21

    The synthesis, magnetic, and spectroscopic characteristics of the synthetically useful dimeric cobalt(II) silylamide complex [Co{N(SiMe3)2}2]2 (1) and several of its Lewis base complexes have been investigated. Variable-temperature nuclear magnetic resonance (NMR) spectroscopy of 1 showed that it exists in a monomer-dimer equilibrium in benzene solution and has an association energy (ΔGreacn) of -0.30(20) kcal mol(-1) at 300 K. Magnetic data for the polycrystalline, red-brown [Co{N(SiMe3)2}2]2 (1) showed that it displays strong antiferromagnetic exchange coupling, expressed as -2JexS1S2, between the two S = (3)/2 cobalt(II) centers with a Jex value of -215(5) cm(-1), which is consistent with its bridged dimeric structure in the solid state. The electronic spectrum of 1 in solution is reported for the first time, and it is shown that earlier reports of the melting point, synthesis, electronic spectrum, and magnetic studies of the monomer "Co{N(SiMe3)2}2" are consistent with those of the bright green-colored tetrahydrofuran (THF) complex [Co{N(SiMe3)2}2(THF)] (4). Treatment of 1 with various Lewis bases yielded monomeric three-coordinated species-[Co{N(SiMe3)2}2(PMe3)] (2), and [Co{N(SiMe3)2}2(THF)] (4), as well as the previously reported [Co{N(SiMe3)2}2(py)] (3)-and the four-coordinated species [Co{N(SiMe3)2}2(py)2] (5) in good yields. The paramagnetic complexes 2-4 were characterized by electronic and (1)H NMR spectroscopy, and by X-ray crystallography in the case of 2 and 4. Magnetic studies of 2-5 and of the known three-coordinated cobalt(II) species [Na(12-crown-4)2][Co{N(SiMe3)2}3] (6) showed that they have considerably larger χMT products and, hence, magnetic moments, than the spin-only values of 1.875 emu K mol(-1) and 3.87 μB, which is indicative of a significant zero-field splitting and g-tensor anisotropy resulting from the pseudo-trigonal crystal field. A fit of χMT for 2-6 yields a large g-tensor anisotropy, large negative D-values (between -62 cm(-1

  5. A Frequency Matching Method: Solving Inverse Problems by Use of Geologically Realistic Prior Information

    DEFF Research Database (Denmark)

    Lange, Katrine; Frydendall, Jan; Cordua, Knud Skou;

    2012-01-01

    The frequency matching method defines a closed form expression for a complex prior that quantifies the higher order statistics of a proposed solution model to an inverse problem. While existing solution methods to inverse problems are capable of sampling the solution space while taking into account...... solution model to an inverse problem by using a priori information based on multiple point statistics learned from training images. We demonstrate the applicability of the suggested method on a synthetic tomographic crosshole inverse problem....

  6. Coordinate mapping of hyolaryngeal mechanics in swallowing.

    Science.gov (United States)

    Thompson, Thomas Z; Obeidin, Farres; Davidoff, Alisa A; Hightower, Cody L; Johnson, Christohper Z; Rice, Sonya L; Sokolove, Rebecca-Lyn; Taylor, Brandon K; Tuck, John M; Pearson, William G

    2014-05-06

    Characterizing hyolaryngeal movement is important to dysphagia research. Prior methods require multiple measurements to obtain one kinematic measurement whereas coordinate mapping of hyolaryngeal mechanics using Modified Barium Swallow (MBS) uses one set of coordinates to calculate multiple variables of interest. For demonstration purposes, ten kinematic measurements were generated from one set of coordinates to determine differences in swallowing two different bolus types. Calculations of hyoid excursion against the vertebrae and mandible are correlated to determine the importance of axes of reference. To demonstrate coordinate mapping methodology, 40 MBS studies were randomly selected from a dataset of healthy normal subjects with no known swallowing impairment. A 5 ml thin-liquid bolus and a 5 ml pudding swallows were measured from each subject. Nine coordinates, mapping the cranial base, mandible, vertebrae and elements of the hyolaryngeal complex, were recorded at the frames of minimum and maximum hyolaryngeal excursion. Coordinates were mathematically converted into ten variables of hyolaryngeal mechanics. Inter-rater reliability was evaluated by Intraclass correlation coefficients (ICC). Two-tailed t-tests were used to evaluate differences in kinematics by bolus viscosity. Hyoid excursion measurements against different axes of reference were correlated. Inter-rater reliability among six raters for the 18 coordinates ranged from ICC = 0.90 - 0.97. A slate of ten kinematic measurements was compared by subject between the six raters. One outlier was rejected, and the mean of the remaining reliability scores was ICC = 0.91, 0.84 - 0.96, 95% CI. Two-tailed t-tests with Bonferroni corrections comparing ten kinematic variables (5 ml thin-liquid vs. 5 ml pudding swallows) showed statistically significant differences in hyoid excursion, superior laryngeal movement, and pharyngeal shortening (p Pearson correlations of hyoid excursion measurements from two different

  7. Global Coordinate System

    Science.gov (United States)

    1985-02-01

    Time in hours at Oh UT is GAST (hours) = GMST + E (41) GAST in radians is GASTo (radians) = GAST (hours) L (42) The angle e required for transforming...inertial coordinates to ECEF is- 6(radians) GASTo + 6.3003880.99 (ti - th) (43) o ~ooUT Mod ( E 27) where St.i - tohLjT = (JD -2.4 106). (JDOE -2.4 x

  8. International Monetary Policy Coordination

    OpenAIRE

    Carlberg, Michael

    2005-01-01

    This paper studies the international coordination of monetary policies in the world economy. It carefully discusses the process of policy competition and the structure of policy cooperation. As to policy competition, the focus is on monetary competition between Europe and America. Similarly, as to policy cooperation, the focus is on monetary cooperation between Europe and America. The spillover effects of monetary policy are negative. The policy targets are price stability and full employment.

  9. Functional uniform priors for nonlinear modeling.

    Science.gov (United States)

    Bornkamp, Björn

    2012-09-01

    This article considers the topic of finding prior distributions when a major component of the statistical model depends on a nonlinear function. Using results on how to construct uniform distributions in general metric spaces, we propose a prior distribution that is uniform in the space of functional shapes of the underlying nonlinear function and then back-transform to obtain a prior distribution for the original model parameters. The primary application considered in this article is nonlinear regression, but the idea might be of interest beyond this case. For nonlinear regression the so constructed priors have the advantage that they are parametrization invariant and do not violate the likelihood principle, as opposed to uniform distributions on the parameters or the Jeffrey's prior, respectively. The utility of the proposed priors is demonstrated in the context of design and analysis of nonlinear regression modeling in clinical dose-finding trials, through a real data example and simulation.

  10. Global coordination: weighted voting

    Directory of Open Access Journals (Sweden)

    Jan-Erik Lane

    2014-03-01

    Full Text Available In order to halt the depletion of global ecological capital, a number of different kinds of meetings between Governments of countries in the world has been scheduled. The need for global coordination of environmental policies has become ever more obvious, supported by more and more evidence of the running down of ecological capital. But there are no formal or binding arrangements in sight, as global environmental coordination suffers from high transaction costs (qualitative voting. The CO2 equivalent emissions, resulting in global warming, are driven by the unstoppable economic expansion in the global market economy, employing mainly fossil fuel generated energy, although at the same time lifting sharply the GDP per capita of several emerging countries. Only global environmental coordination on the successful model of the World Band and the IMF (quantitative voting can stem the rising emissions numbers and stop further environmental degradation. However, the system of weighted voting in the WB and the IMF must be reformed by reducing the excessive voting power disparities, for instance by reducing all member country votes by the cube root expression.

  11. Universal mechatronics coordinator

    Science.gov (United States)

    Muir, Patrick F.

    1999-11-01

    Mechatronic systems incorporate multiple actuators and sensor which must be properly coordinated to achieve the desired system functionality. Many mechatronic systems are designed as one-of-a-kind custom projects without consideration for facilitating future system or alterations and extensions to the current syste. Thus, subsequent changes to the system are slow, different, and costly. It has become apparent that manufacturing processes, and thus the mechatronics which embody them, need to be agile in order to more quickly and easily respond to changing customer demands or market pressures. To achieve agility, both the hardware and software of the system need to be designed such that the creation of new system and the alteration and extension of current system is fast and easy. This paper describes the design of a Universal Mechatronics Coordinator (UMC) which facilitates agile setup and changeover of coordination software for mechatronic systems. The UMC is capable of sequencing continuous and discrete actions that are programmed as stimulus-response pairs, as state machines, or a combination of the two. It facilitates the modular, reusable programing of continuous actions such as servo control algorithms, data collection code, and safety checking routines; and discrete actions such as reporting achieved states, and turning on/off binary devices. The UMC has been applied to the control of a z- theta assembly robot for the Minifactory project and is applicable to a spectrum of widely differing mechatronic systems.

  12. Improving Project Manufacturing Coordination

    Directory of Open Access Journals (Sweden)

    Korpivaara Ville

    2014-09-01

    Full Text Available The objective of this research is to develop firms’ project manufacturing coordination. The development will be made by centralizing the manufacturing information flows in one system. To be able to centralize information, a deep user need assessment is required. After user needs have been identified, the existing system will be developed to match these needs. The theoretical background is achieved through exploring the literature of project manufacturing, development project success factors and different frameworks and tools for development project execution. The focus of this research is rather in customer need assessment than in system’s technical expertise. To ensure the deep understanding of customer needs this study is executed by action research method. As a result of this research the information system for project manufacturing coordination was developed to respond revealed needs of the stakeholders. The new system improves the quality of the manufacturing information, eliminates waste in manufacturing coordination processes and offers a better visibility to the project manufacturing. Hence it provides a solid base for the further development of project manufacturing.

  13. Bayesian variable selection with spherically symmetric priors

    OpenAIRE

    De Kock, M. B.; Eggers, H. C.

    2014-01-01

    We propose that Bayesian variable selection for linear parametrisations with Gaussian iid likelihoods be based on the spherical symmetry of the diagonalised parameter space. Our r-prior results in closed forms for the evidence for four examples, including the hyper-g prior and the Zellner-Siow prior, which are shown to be special cases. Scenarios of a single variable dispersion parameter and of fixed dispersion are studied, and asymptotic forms comparable to the traditional information criter...

  14. Penalised Complexity Priors for Stationary Autoregressive Processes

    KAUST Repository

    Sørbye, Sigrunn Holbek

    2017-05-25

    The autoregressive (AR) process of order p(AR(p)) is a central model in time series analysis. A Bayesian approach requires the user to define a prior distribution for the coefficients of the AR(p) model. Although it is easy to write down some prior, it is not at all obvious how to understand and interpret the prior distribution, to ensure that it behaves according to the users\\' prior knowledge. In this article, we approach this problem using the recently developed ideas of penalised complexity (PC) priors. These prior have important properties like robustness and invariance to reparameterisations, as well as a clear interpretation. A PC prior is computed based on specific principles, where model component complexity is penalised in terms of deviation from simple base model formulations. In the AR(1) case, we discuss two natural base model choices, corresponding to either independence in time or no change in time. The latter case is illustrated in a survival model with possible time-dependent frailty. For higher-order processes, we propose a sequential approach, where the base model for AR(p) is the corresponding AR(p-1) model expressed using the partial autocorrelations. The properties of the new prior distribution are compared with the reference prior in a simulation study.

  15. Optimizing Vibrational Coordinates To Modulate Intermode Coupling.

    Science.gov (United States)

    Zimmerman, Paul M; Smereka, Peter

    2016-04-12

    The choice of coordinate system strongly affects the convergence properties of vibrational structure computations. Two methods for efficient generation of improved vibrational coordinates are presented and justified by analysis of a model anharmonic two-mode Hessian and numerical computations on polyatomic molecules. To produce optimal coordinates, metrics which quantify off-diagonal couplings over a grid of Hessian matrices are minimized through unitary rotations of the vibrational basis. The first proposed metric minimizes the total squared off-diagonal coupling, and the second minimizes the total squared change in off-diagonal coupling. In this procedure certain anharmonic modes tend to localize, for example X-H stretches. The proposed methods do not rely on prior fitting of the potential energy, vibrational structure computations, or localization metrics, so they are unique from previous vibrational coordinate generation algorithms and are generally applicable to polyatomic molecules. Fitting the potential to the approximate n-mode representation in the optimized bases for all-trans polyenes shows that off-diagonal anharmonic couplings are substantially reduced by the new choices of coordinate system. Convergence of vibrational energies is examined in detail for ethylene, and it is shown that coupling-optimized modes converge in vibrational configuration interaction computations to within 1 cm(-1) using only 3-mode couplings, where normal modes require 4-mode couplings for convergence. Comparison of the vibrational configuration interaction convergence with respect to excitation level for the two proposed metrics shows that minimization of the total off-diagonal coupling is most effective for low-cost vibrational structure computations.

  16. Symmetric two-coordinate photodiode

    Directory of Open Access Journals (Sweden)

    Dobrovolskiy Yu. G.

    2008-12-01

    Full Text Available The two-coordinate photodiode is developed and explored on the longitudinal photoeffect, which allows to get the coordinate descriptions symmetric on the steepness and longitudinal resistance great exactness. It was shown, that the best type of the coordinate description is observed in the case of scanning by the optical probe on the central part of the photosensitive element. The ways of improvement of steepness and linear of its coordinate description were analyzed.

  17. Invariant Manifolds and Collective Coordinates

    CERN Document Server

    Papenbrock, T

    2001-01-01

    We introduce suitable coordinate systems for interacting many-body systems with invariant manifolds. These are Cartesian in coordinate and momentum space and chosen such that several components are identically zero for motion on the invariant manifold. In this sense these coordinates are collective. We make a connection to Zickendraht's collective coordinates and present certain configurations of few-body systems where rotations and vibrations decouple from single-particle motion. These configurations do not depend on details of the interaction.

  18. Analytical solutions in terms of the quadrilateral area coordinates for pure bending state and the finite element model overcoming the limitation of MacNeal’s theorem%基于第二类四边形面积坐标的弹性力学纯弯解及MacNeal局限定理的破解

    Institute of Scientific and Technical Information of China (English)

    岑松; 周培蕾

    2016-01-01

    为了提高有限元的性能,弹性力学的解析解(齐次方程的通解)常常可用作有限元的试探函数。然而单元自由度数与完备的直角坐标解析解个数并不匹配,不完备的试函数会导致单元有方向依赖性。利用新型局部自然坐标———第二类四边形面积坐标 QACM-II (S,T),给出了平面问题对应任意方向纯弯曲状态的应力函数解析解,即S 3和T3的线性组合,并推导出了这两组应力函数对应的应力、应变和位移解析解。之后,利用QACM-II表示的解析解构造了非对称的平面4节点8自由度单元 USQ4,该单元可以同时通过常应力/应变分片检验和纯弯测试,从而破解了 MacNeal局限定理对平面低阶单元的限制。%In order to improve the performance of finite element models,analytical solutions of problems in theory of elasticity (the general solutions of the homogeneous equations )were often used as the element trial functions.However,the number of the element DOFs usually does not match the number of the complete analytical solutions,and such incomplete trial functions may lead to direction dependence of the finite elements.In this paper,a new local natural coordinate method,i.e.,the second form of the quadrilateral area coordinate method QACM-II (S,T),was employed to formulate the analytical solutions (the linear combination of S3 and T3 )of the Airy stress function for pure bending state along arbitrary directions.And corresponding analytical solutions for stresses,strains or displacements were also derived out.Then,by utilizing above solutions,a new unsymmetric 4-node,8-DOF plane quadrilate-ral element,denoted by USQ4,was successfully created.The new element can pass both the constant strain/stress patch test and the pure bending test,which means that the limitation defined by the MacNeal’s theorem is overcome.

  19. Coordination Processes in International Organisations

    DEFF Research Database (Denmark)

    Nedergaard, Peter

    2008-01-01

    to coordinate relatively elaborate agreements due to the strength of its coordination as far as professional or technical and political activities (excepting the ILO budget) are concerned. In other more clear-cut or 'simple' policy areas such as the ILO budget, the EU coordination is weak: this contrast...

  20. Relationship between Prior Knowledge and Reading Comprehension

    Science.gov (United States)

    Abdelaal, Noureldin Mohamed; Sase, Amal Saleh

    2014-01-01

    This study investigates the relationship between prior knowledge and reading comprehension in second language among postgraduate students in UPM. Participants in the study were 20 students who have the same level in English as a second language from several faculties. On the basis of a prior-knowledge questionnaire and test, students were…

  1. Quantitative Evidence Synthesis with Power Priors

    NARCIS (Netherlands)

    Rietbergen, C.|info:eu-repo/dai/nl/322847796

    2016-01-01

    The aim of this thesis is to provide the applied researcher with a practical approach for quantitative evidence synthesis using the conditional power prior that allows for subjective input and thereby provides an alternative tgbgo deal with the difficulties as- sociated with the joint power prior

  2. Quantitative Evidence Synthesis with Power Priors

    NARCIS (Netherlands)

    Rietbergen, C.

    2016-01-01

    The aim of this thesis is to provide the applied researcher with a practical approach for quantitative evidence synthesis using the conditional power prior that allows for subjective input and thereby provides an alternative tgbgo deal with the difficulties as- sociated with the joint power prior di

  3. Signaling Without Common Prior : An Experiment

    NARCIS (Netherlands)

    Drouvelis, M.; Müller, W.; Possajennikov, A.

    2009-01-01

    The common prior assumption is pervasive in game-theoretic models with incomplete information. This paper investigates experimentally the importance of inducing a common prior in a two-person signaling game. For a specific probability distribution of the sender’s type, the long-run behavior without

  4. Signaling Without Common Prior : An Experiment

    NARCIS (Netherlands)

    Drouvelis, M.; Müller, W.; Possajennikov, A.

    2009-01-01

    The common prior assumption is pervasive in game-theoretic models with incomplete information. This paper investigates experimentally the importance of inducing a common prior in a two-person signaling game. For a specific probability distribution of the sender’s type, the long-run behavior without

  5. Improving Open Access through Prior Learning Assessment

    Science.gov (United States)

    Yin, Shuangxu; Kawachi, Paul

    2013-01-01

    This paper explores and presents new data on how to improve open access in distance education through using prior learning assessments. Broadly there are three types of prior learning assessment (PLAR): Type-1 for prospective students to be allowed to register for a course; Type-2 for current students to avoid duplicating work-load to gain…

  6. Work Coordination Engine

    Science.gov (United States)

    Zendejas, Silvino; Bui, Tung; Bui, Bach; Malhotra, Shantanu; Chen, Fannie; Kim, Rachel; Allen, Christopher; Luong, Ivy; Chang, George; Sadaqathulla, Syed

    2009-01-01

    The Work Coordination Engine (WCE) is a Java application integrated into the Service Management Database (SMDB), which coordinates the dispatching and monitoring of a work order system. WCE de-queues work orders from SMDB and orchestrates the dispatching of work to a registered set of software worker applications distributed over a set of local, or remote, heterogeneous computing systems. WCE monitors the execution of work orders once dispatched, and accepts the results of the work order by storing to the SMDB persistent store. The software leverages the use of a relational database, Java Messaging System (JMS), and Web Services using Simple Object Access Protocol (SOAP) technologies to implement an efficient work-order dispatching mechanism capable of coordinating the work of multiple computer servers on various platforms working concurrently on different, or similar, types of data or algorithmic processing. Existing (legacy) applications can be wrapped with a proxy object so that no changes to the application are needed to make them available for integration into the work order system as "workers." WCE automatically reschedules work orders that fail to be executed by one server to a different server if available. From initiation to completion, the system manages the execution state of work orders and workers via a well-defined set of events, states, and actions. It allows for configurable work-order execution timeouts by work-order type. This innovation eliminates a current processing bottleneck by providing a highly scalable, distributed work-order system used to quickly generate products needed by the Deep Space Network (DSN) to support space flight operations. WCE is driven by asynchronous messages delivered via JMS indicating the availability of new work or workers. It runs completely unattended in support of the lights-out operations concept in the DSN.

  7. Observable Priors: Limiting Biases in Estimated Parameters for Incomplete Orbits

    Science.gov (United States)

    Kosmo, Kelly; Martinez, Gregory; Hees, Aurelien; Witzel, Gunther; Ghez, Andrea M.; Do, Tuan; Sitarski, Breann; Chu, Devin; Dehghanfar, Arezu

    2017-01-01

    Over twenty years of monitoring stellar orbits at the Galactic center has provided an unprecedented opportunity to study the physics and astrophysics of the supermassive black hole (SMBH) at the center of the Milky Way Galaxy. In order to constrain the mass of and distance to the black hole, and to evaluate its gravitational influence on orbiting bodies, we use Bayesian statistics to infer black hole and stellar orbital parameters from astrometric and radial velocity measurements of stars orbiting the central SMBH. Unfortunately, most of the short period stars in the Galactic center have periods much longer than our twenty year time baseline of observations, resulting in incomplete orbital phase coverage--potentially biasing fitted parameters. Using the Bayesian statistical framework, we evaluate biases in the black hole and orbital parameters of stars with varying phase coverage, using various prior models to fit the data. We present evidence that incomplete phase coverage of an orbit causes prior assumptions to bias statistical quantities, and propose a solution to reduce these biases for orbits with low phase coverage. The explored solution assumes uniformity in the observables rather than in the inferred model parameters, as is the current standard method of orbit fitting. Of the cases tested, priors that assume uniform astrometric and radial velocity observables reduce the biases in the estimated parameters. The proposed method will not only improve orbital estimates of stars orbiting the central SMBH, but can also be extended to other orbiting bodies with low phase coverage such as visual binaries and exoplanets.

  8. Advice for Coordination

    DEFF Research Database (Denmark)

    Hankin, Chris; Nielson, Flemming; Nielson, Hanne Riis

    2008-01-01

    demanding than the closed joinpoints in more traditional aspect oriented languages like AspectJ. The usefulness of our approach is demonstrated by mechanisms for discretionary and mandatory access control policies, as usually expressed by reference monitors, as well as mechanisms for logging actions.......We show how to extend a coordination language with support for aspect oriented programming. The main challenge is how to properly deal with the trapping of actions before the actual data have been bound to the formal parameters. This necessitates dealing with open joinpoints – which is more...

  9. Markov stochasticity coordinates

    Science.gov (United States)

    Eliazar, Iddo

    2017-01-01

    Markov dynamics constitute one of the most fundamental models of random motion between the states of a system of interest. Markov dynamics have diverse applications in many fields of science and engineering, and are particularly applicable in the context of random motion in networks. In this paper we present a two-dimensional gauging method of the randomness of Markov dynamics. The method-termed Markov Stochasticity Coordinates-is established, discussed, and exemplified. Also, the method is tweaked to quantify the stochasticity of the first-passage-times of Markov dynamics, and the socioeconomic equality and mobility in human societies.

  10. Video Contents Prior Storing Server For Lte Networks

    Directory of Open Access Journals (Sweden)

    Tony Tsang

    2015-10-01

    Full Text Available One of the most important multimedia applications is Internet protocol TV (IPTV for next-generation networks. IPTV provides triple-play services that require high-speed access networks with the functions of multicasting and quality of service (QoS guarantees. Among 4G mobile ac-cess networks, LTE networks are regarded as among the best solutions to meet higher bandwidth demands. In this paper, we propose a new architecture for multicasting live IPTV traffic in 4G LTE networks. The proposed mechanism involves assigning a unique logical link identifier to each IPTV channel. To manage multicasting, a prior storing server in the Base Station and in each mobile network unit, mobile phone, is constructed. In this work, we propose a partial prior storing strategy that considers the changes in the popularity of the video content segments over time and the access patterns of the users to compute the utility of the objects in the prior storage. We also propose to partition the prior storage to avoid the eviction of the popular objects (those not accessed frequently by the unpopular ones which are accessed with higher frequency. The popularity distribution and ageing of popularity are measured from two online datasets and use the parameters in simulations. Simulation results show that our proposed architecture can improve the system performance and QoS parameters in terms of packet delay, jitter and packet loss.

  11. VIDEO CONTENTS PRIOR STORING SERVER FOR OPTICAL ACCESS NETWORK

    Directory of Open Access Journals (Sweden)

    Tony Tsang

    2015-03-01

    Full Text Available One of the most important multimedia applications is Internet protocol TV (IPTV for next-generation networks. IPTV provides triple-play services that require high-speed access networks with the functions of multicasting and quality of service (QoS guarantees. Among optical access networks, Ethernet passive optical networks (EPONs are regarded as among the best solutions to meet higher bandwidth demands. In this paper, we propose a new architecture for multicasting live IPTV traffic in optical access network. The proposed mechanism involves assigning a unique logical link identifier to each IPTV channel. To manage multicasting, a prior storing server in the optical line terminal (OLT and in each optical network unit (ONU is constructed. In this work, we propose a partial prior storing strategy that considers the changes in the popularity of the video content segments over time and the access patterns of the users to compute the utility of the objects in the prior storage. We also propose to partition the prior storage to avoid the eviction of the popular objects (those not accessed frequently by the unpopular ones which are accessed with higher frequency. The popularity distribution and ageing of popularity are measured from two online datasets and use the parameters in simulations. Simulation results show that our proposed architecture can improve the system performance and QoS parameters in terms of packet delay, jitter and packet loss

  12. Collective Coordinates in One-Dimensional Soliton Models Revisited

    CERN Document Server

    Takyi, I

    2016-01-01

    We compare numerical solutions to the full field equations to simplified approaches based on implementing three collective coordinates for kink-antikink interactions within the $\\varphi^4$ and $\\phi^6$ models in one time and one space dimensions. We particularly pursue the question whether the collective coordinate approximation substantiates the conjecture that vibrational modes are important for resonance structures to occur in kink-antikink scattering.

  13. Coordination Processes in International Organisations

    DEFF Research Database (Denmark)

    Nedergaard, Peter

    2008-01-01

    The EU is not a member of the International Labour Organisation (ILO), but relatively elaborate EU coordination takes place anyway. This paper addresses two research questions: 1) How is it possible to evaluate the coordination of the EU in its specific observable configuration in the ILO?, and 2......) To what outcome does this coordination lead and why? Based on an analysis of EU coordination before and during the International Labour Conference in 2005, and on a comparison with coordination processes of the IMEC group, it is found that the Commission and the Presidency act as twin-agents vis...... by the principals. On the other hand, both before and during the Conference, the Member States accept the so-called discursive coordination of the Commission, which seems to be of great (but often neglected) importance. Owing to the organisational set-up in which coordination takes place, the EU is able...

  14. Incident Management Systems are essential for Effective Coordination of Large Disease Outbreaks: Perspectives from the Coordination of the Ebola Outbreak Response in Sierra Leone

    Directory of Open Access Journals (Sweden)

    Olushayo Oluseun Olu

    2016-11-01

    Full Text Available Background: Response to the 2014–2015 Ebola Virus Disease (EVD outbreak in Sierra Leone overwhelmed the national capacity to contain it and necessitated a massive international response and strong coordination platform. Consequently, the Sierra Leone Government, with support of the international humanitarian community, established and implemented various models for national coordination of the outbreak. In this article we review the strengths and limitations of the EVD outbreak response coordination systems in Sierra Leone and propose recommendations for improving coordination of similar outbreaks in the future. Conclusions: There were two main frameworks used for the coordination of the outbreak; the Emergency Operation Center (EOC and the National Ebola Response Center (NERC. We observed an improvement in outbreak coordination as the management mechanism evolved from the EOC to the NERC. Both coordination systems had their advantages and disadvantages; however the NERC coordination mechanism appeared to be more robust. We identified challenges, such as competition and duplication of efforts between the numerous coordination groups, slow resource mobilization, inadequate capacity of NERC/EOC staff for health coordination and an overtly centralized coordination and decision making system as the main coordination challenges during the outbreak. Recommendations: We recommend the establishment of emergency operation centers with simple incident management system-based coordination prior to outbreaks, strong government leadership, decentralization of coordination systems and functions to the epicenter of outbreaks, with clear demarcation of roles and responsibilities between different levels, regular training of key coordination leaders and better community participation as methods to improve coordination of future disease outbreaks.

  15. Colorization by classifying the prior knowledge

    Institute of Scientific and Technical Information of China (English)

    DU Weiwei

    2011-01-01

    When a one-dimensional luminance scalar is replaced by a vector of a colorful multi-dimension for every pixel of a monochrome image,the process is called colorization.However,colorization is under-constrained.Therefore,the prior knowledge is considered and given to the monochrome image.Colorization using optimization algorithm is an effective algorithm for the above problem.However,it cannot effectively do with some images well without repeating experiments for confirming the place of scribbles.In this paper,a colorization algorithm is proposed,which can automatically generate the prior knowledge.The idea is that firstly,the prior knowledge crystallizes into some points of the prior knowledge which is automatically extracted by downsampling and upsampling method.And then some points of the prior knowledge are classified and given with corresponding colors.Lastly,the color image can be obtained by the color points of the prior knowledge.It is demonstrated that the proposal can not only effectively generate the prior knowledge but also colorize the monochrome image according to requirements of user with some experiments.

  16. Variational segmentation problems using prior knowledge in imaging and vision

    DEFF Research Database (Denmark)

    Fundana, Ketut

    -manifold of pose-invariant planar contours into both the Chan-Vese model and its convex formulation to segment an object of interest in a sequence of images. We apply the models to track the viewpoint onto 3D rigid object. The prior-based object segmentation models encounter the problem of shape alignment, where......This dissertation addresses variational formulation of segmentation problems using prior knowledge. Variational models are among the most successful approaches for solving many Computer Vision and Image Processing problems. The models aim at finding the solution to a given energy functional defined...... to describe a Computer Vision task through energy minimization. Image segmentation, as an ill-posed problem, is still a major challenge in Computer Vision. Due to the presence of noise, clutter and occlusion, the use of image information alone often gives poor segmentation results. To overcome this problem...

  17. PARAMETER COORDINATION AND ROBUST OPTIMIZATION FOR MULTIDISCIPLINARY DESIGN

    Institute of Scientific and Technical Information of China (English)

    HU Jie; PENG Yinghong; XIONG Guangleng

    2006-01-01

    A new parameter coordination and robust optimization approach for multidisciplinary design is presented. Firstly, the constraints network model is established to support engineering change, coordination and optimization. In this model, interval boxes are adopted to describe the uncertainty of design parameters quantitatively to enhance the design robustness. Secondly, the parameter coordination method is presented to solve the constraints network model, monitor the potential conflicts due to engineering changes, and obtain the consistency solution space corresponding to the given product specifications. Finally, the robust parameter optimization model is established, and genetic arithmetic is used to obtain the robust optimization parameter. An example of bogie design is analyzed to show the scheme to be effective.

  18. Methods for Coordinated Inventory Control in Supply Chain Management

    DEFF Research Database (Denmark)

    Larsen, Christian; Thorstenson, Anders

    2010-01-01

    and heuristic control methods for coordination. The numerical results obtained by simulation are compared with the solutions found when inventories in the supply chain are controlled independently of each other. Findings Coordinated inventory control can offer a significant potential for cost reduction...... in a supply chain. However, the resulting inventory allocations are not always obvious without thorough analyses of the coordination effects. Research limitations/implications Some of the conclusions are formed on the basis of numerical examples and future research could involve investigation of a wider set...

  19. Uranyl-oxo coordination directed by non-covalent interactions.

    Science.gov (United States)

    Lewis, Andrew J; Yin, Haolin; Carroll, Patrick J; Schelter, Eric J

    2014-07-28

    Directed coordination of weakly Lewis acidic K(+) ions to weakly Lewis basic uranyl oxo ligands is accomplished through non-covalent cation-π and cation-F interactions for the first time. Comparison of a family of structurally related diarylamide ligands highlights the role that the cation-π and cation-F interactions play in guiding coordination. Cation binding to uranyl is demonstrated in the solid state and in solution, providing the shortest reported crystallographic uranyl-oxo to potassium distance. UV-Vis, TD-DFT calculations, and electrochemical measurements show that cation coordination directly impacts the electronics at the uranium(vi) cation.

  20. Terminology for pregnancy loss prior to viability

    DEFF Research Database (Denmark)

    Kolte, A M; Bernardi, L A; Christiansen, O B

    2015-01-01

    Pregnancy loss prior to viability is common and research in the field is extensive. Unfortunately, terminology in the literature is inconsistent. The lack of consensus regarding nomenclature and classification of pregnancy loss prior to viability makes it difficult to compare study results from...... different centres. In our opinion, terminology and definitions should be based on clinical findings, and when possible, transvaginal ultrasound. With this Early Pregnancy Consensus Statement, it is our goal to provide clear and consistent terminology for pregnancy loss prior to viability....

  1. Robust Parameter Coordination for Multidisciplinary Design

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    This paper introduced a robust parameter coordination method to analyze parameter uncertainties so as to predict conflicts and coordinate parameters in multidisciplinary design. The proposed method is based on constraints network, which gives a formulated model to analyze the coupling effects between design variables and product specifications. In this model, interval boxes are adopted to describe the uncertainty of design parameters quantitatively to enhance the design robustness. To solve this constraint network model, a general consistent algorithm framework is designed and implemented with interval arithmetic and the genetic algorithm, which can deal with both algebraic and ordinary differential equations. With the help of this method, designers could infer the consistent solution space from the given specifications. A case study involving the design of a bogie dumping system demonstrates the usefulness of this approach.

  2. Update of technical coordinating committee activities

    Energy Technology Data Exchange (ETDEWEB)

    Alvarado, R.A.

    1995-12-31

    The Technical Coordinating Committee has its origins in the earliest days of implementing the Low-Level Radioactive Waste Policy Act. Between 1982 and 1985, individuals in several of the states felt that coordination among the states would be beneficial to all by affording states a cost-effective method for sharing ideas, discussing alternatives, and presenting solutions to common problems. At the current time, the committee comprises members from each of the sited states. Various compacts, federal agencies, and industry groups participate in committee activities. The Low-Level Management Program provides support for the committee through the provision of logistical support and limited manpower allocation. Activities of the committee have recently focused on waste treatment and minimization technologies. The committee also has worked diligently to see the review of the 3RSTAT computer code completed. The committee has taken a position on various regulatory proposals the past year. The committee expects to continue its work until new sites are brought online.

  3. A Simulation of Pell Grant Awards and Costs Using Prior-Prior Year Financial Data

    Science.gov (United States)

    Kelchen, Robert; Jones, Gigi

    2015-01-01

    We examine the likely implications of switching from a prior year (PY) financial aid system, the current practice in which students file the Free Application for Federal Student Aid (FAFSA) using income data from the previous tax year, to prior-prior year (PPY), in which data from two years before enrollment is used. While PPY allows students to…

  4. Coordination using Implicit Communication

    CERN Document Server

    Cuff, Paul

    2011-01-01

    We explore a basic noise-free signaling scenario where coordination and communication are naturally merged. A random signal X_1,...,X_n is processed to produce a control signal or action sequence A_1,...,A_n, which is observed and further processed (without access to X_1,...,X_n) to produce a third sequence B_1,...,B_n. The object of interest is the set of empirical joint distributions p(x,a,b) that can be achieved in this setting. We show that H(A) >= I(X;A,B) is the necessary and sufficient condition for achieving p(x,a,b) when no causality constraints are enforced on the encoders. We also give results for various causality constraints. This setting sheds light on the embedding of digital information in analog signals, a concept that is exploited in digital watermarking, steganography, cooperative communication, and strategic play in team games such as bridge.

  5. On Coordinating Collaborative Objects

    CERN Document Server

    Imine, Abdessamad

    2010-01-01

    A collaborative object represents a data type (such as a text document) designed to be shared by a group of dispersed users. The Operational Transformation (OT) is a coordination approach used for supporting optimistic replication for these objects. It allows the users to concurrently update the shared data and exchange their updates in any order since the convergence of all replicas, i.e. the fact that all users view the same data, is ensured in all cases. However, designing algorithms for achieving convergence with the OT approach is a critical and challenging issue. In this paper, we propose a formal compositional method for specifying complex collaborative objects. The most important feature of our method is that designing an OT algorithm for the composed collaborative object can be done by reusing the OT algorithms of component collaborative objects. By using our method, we can start from correct small collaborative objects which are relatively easy to handle and incrementally combine them to build more ...

  6. Distributed sensor coordination for advanced energy systems

    Energy Technology Data Exchange (ETDEWEB)

    Tumer, Kagan [Oregon State Univ., Corvallis, OR (United States). School of Mechanical, Industrial and Manufacturing Engineering

    2015-03-12

    coordination, and sensor network control in advanced power systems. Each application has specific needs, but they all share the one crucial underlying problem: how to ensure that the interactions of a large number of heterogenous agents lead to coordinated system behavior. This proposal describes a new paradigm that addresses that very issue in a systematic way. Key Results and Findings: All milestones have been completed. Our results demonstrate that by properly shaping agent objective functions, we can develop large (up to 10,000 devices) heterogeneous sensor networks with key desirable properties. The first milestone shows that properly choosing agent-specific objective functions increases system performance by up to 99.9% compared to global evaluations. The second milestone shows evolutionary algorithms learn excellent sensor network coordination policies prior to network deployment, and these policies can be refined online once the network is deployed. The third milestone shows the resulting sensor networks networks are extremely robust to sensor noise, where networks with up to 25% sensor noise are capable of providing measurements with errors on the order of 10⁻³. The fourth milestone shows the resulting sensor networks are extremely robust to sensor failure, with 25% of the sensors in the system failing resulting in no significant performance losses after system reconfiguration.

  7. Prior Authorization of PMDs Demonstration - Status Update

    Data.gov (United States)

    U.S. Department of Health & Human Services — CMS implemented a Prior Authorization process for scooters and power wheelchairs for people with Fee-For-Service Medicare who reside in seven states with high...

  8. Coordinating Group report

    Energy Technology Data Exchange (ETDEWEB)

    1994-01-01

    In December 1992, western governors and four federal agencies established a Federal Advisory Committee to Develop On-site Innovative Technologies for Environmental Restoration and Waste Management (the DOIT Committee). The purpose of the Committee is to advise the federal government on ways to improve waste cleanup technology development and the cleanup of federal sites in the West. The Committee directed in January 1993 that information be collected from a wide range of potential stakeholders and that innovative technology candidate projects be identified, organized, set in motion, and evaluated to test new partnerships, regulatory approaches, and technologies which will lead to improve site cleanup. Five working groups were organized, one to develop broad project selection and evaluation criteria and four to focus on specific contaminant problems. A Coordinating Group comprised of working group spokesmen and federal and state representatives, was set up to plan and organize the routine functioning of these working groups. The working groups were charged with defining particular contaminant problems; identifying shortcomings in technology development, stakeholder involvement, regulatory review, and commercialization which impede the resolution of these problems; and identifying candidate sites or technologies which could serve as regional innovative demonstration projects to test new approaches to overcome the shortcomings. This report from the Coordinating Group to the DOIT Committee highlights the key findings and opportunities uncovered by these fact-finding working groups. It provides a basis from which recommendations from the DOIT Committee to the federal government can be made. It also includes observations from two public roundtables, one on commercialization and another on regulatory and institutional barriers impeding technology development and cleanup.

  9. Application of Bayesian Hierarchical Prior Modeling to Sparse Channel Estimation

    DEFF Research Database (Denmark)

    Pedersen, Niels Lovmand; Manchón, Carles Navarro; Shutin, Dmitriy

    2012-01-01

    . The estimators result as an application of the variational message-passing algorithm on the factor graph representing the signal model extended with the hierarchical prior models. Numerical results demonstrate the superior performance of our channel estimators as compared to traditional and state......Existing methods for sparse channel estimation typically provide an estimate computed as the solution maximizing an objective function defined as the sum of the log-likelihood function and a penalization term proportional to the l1-norm of the parameter of interest. However, other penalization......-of-the-art sparse methods....

  10. Inference with the Median of a Prior

    Directory of Open Access Journals (Sweden)

    Ali Mohammad-Djafari

    2006-06-01

    Full Text Available We consider the problem of inference on one of the two parameters of a probability distribution when we have some prior information on a nuisance parameter. When a prior probability distribution on this nuisance parameter is given, the marginal distribution is the classical tool to account for it. If the prior distribution is not given, but we have partial knowledge such as a fixed number of moments, we can use the maximum entropy principle to assign a prior law and thus go back to the previous case. In this work, we consider the case where we only know the median of the prior and propose a new tool for this case. This new inference tool looks like a marginal distribution. It is obtained by first remarking that the marginal distribution can be considered as the mean value of the original distribution with respect to the prior probability law of the nuisance parameter, and then, by using the median in place of the mean.

  11. Transferring visual prior for online object tracking.

    Science.gov (United States)

    Wang, Qing; Chen, Feng; Yang, Jimei; Xu, Wenli; Yang, Ming-Hsuan

    2012-07-01

    Visual prior from generic real-world images can be learned and transferred for representing objects in a scene. Motivated by this, we propose an algorithm that transfers visual prior learned offline for online object tracking. From a collection of real-world images, we learn an overcomplete dictionary to represent visual prior. The prior knowledge of objects is generic, and the training image set does not necessarily contain any observation of the target object. During the tracking process, the learned visual prior is transferred to construct an object representation by sparse coding and multiscale max pooling. With this representation, a linear classifier is learned online to distinguish the target from the background and to account for the target and background appearance variations over time. Tracking is then carried out within a Bayesian inference framework, in which the learned classifier is used to construct the observation model and a particle filter is used to estimate the tracking result sequentially. Experiments on a variety of challenging sequences with comparisons to several state-of-the-art methods demonstrate that more robust object tracking can be achieved by transferring visual prior.

  12. An anatomically oriented breast coordinate system for mammogram analysis

    DEFF Research Database (Denmark)

    Brandt, Sami; Karemore, Gopal; Karssemeijer, Nico

    2011-01-01

    and orientations are registered and extracted without non-linearly deforming the images. We use the proposed breast coordinate transform in a cross-sectional breast cancer risk assessment study of 490 women, in which we attempt to learn breast cancer risk factors from mammograms that were taken prior to when...... between the mammograms of each woman and among the mammograms of all of the women in the study. The results of the cross-sectional study show that the classification into cancer and control groups can be improved by using the new coordinate system, compared to other systems evaluated. Comparisons were...

  13. PET image reconstruction using multi-parametric anato-functional priors

    Science.gov (United States)

    Mehranian, Abolfazl; Belzunce, Martin A.; Niccolini, Flavia; Politis, Marios; Prieto, Claudia; Turkheimer, Federico; Hammers, Alexander; Reader, Andrew J.

    2017-08-01

    also showed that the Gaussian prior with voxel-based feature vectors, the Bowsher and the joint Burg entropy priors were the best performing priors. However, for the FDG dataset with simulated tumours, the TV and proposed priors were capable of preserving the PET-unique tumours. Finally, an important outcome was the demonstration that the MAP reconstruction of a low-count FDG PET dataset using the proposed joint entropy prior can lead to comparable image quality to a conventional ML reconstruction with up to 5 times more counts. In conclusion, multi-parametric anato-functional priors provide a solution to address the pitfalls of the conventional priors and are therefore likely to increase the diagnostic confidence in MR-guided PET image reconstructions.

  14. Identification of coordination factors affecting building projects performance

    Directory of Open Access Journals (Sweden)

    Wesam Salah Alaloul

    2016-09-01

    Full Text Available Construction projects performance requires improvement to fulfil the complexity of the stakeholders’ needs and expectations. Coordination process is proposed as an efficient solution for weak performance of construction projects. Therefore, coordination factors are vital in ensuring a successful implementation of all project phases. This study aimed to identify and prioritise coordination factors that influence the performance of building projects in Malaysian context. A vast body of literature on coordination process was reviewed and resulted in 53 coordination factor. Three rounds of Delphi technique were conducted. The most effective coordination factors were ranked based on the Relative Importance Index (RII such as Scheduling (RII = 0.97, Quality assurance plan (RII = 0.93, and all parties’ participation in plans (RII = 0.89. These coordination factors have fulfilled the research gap and provided better management and higher performance for project parties. The results offer insightful perspectives to define the most effective coordination factors, for addressing the dependency between project tasks and the parties to enhance project performance.

  15. Positive Solutions of Advanced Differential Systems

    Directory of Open Access Journals (Sweden)

    Josef Diblík

    2013-01-01

    graph coordinates of two (lower and upper auxiliary vector functions. This result is applied to scalar advanced linear differential equations. Criteria of existence of positive solutions are given and their asymptotic behavior is discussed.

  16. Overactuated systems coordination

    OpenAIRE

    Michellod, Yvan

    2009-01-01

    The economic growth inherent to our nowadays society pushes the industries toward better performances. In the mechatronic context, the increasing competition results in more and more stringent specifications. Thus, the multiple objectives to track become hard to achieve without compromises. A potential interesting solution to this problematic is overactuation, in the sense that, the considered system has more actuated degrees of freedom than the minimal number required to realize a task. Inde...

  17. Invariant manifolds and collective coordinates

    Energy Technology Data Exchange (ETDEWEB)

    Papenbrock, T. [Centro Internacional de Ciencias, Cuernavaca, Morelos (Mexico); Institute for Nuclear Theory, University of Washington, Seattle, WA (United States); Seligman, T.H. [Centro Internacional de Ciencias, Cuernavaca, Morelos (Mexico); Centro de Ciencias Fisicas, University of Mexico (UNAM), Cuernavaca (Mexico)

    2001-09-14

    We introduce suitable coordinate systems for interacting many-body systems with invariant manifolds. These are Cartesian in coordinate and momentum space and chosen such that several components are identically zero for motion on the invariant manifold. In this sense these coordinates are collective. We make a connection to Zickendraht's collective coordinates and present certain configurations of few-body systems where rotations and vibrations decouple from single-particle motion. These configurations do not depend on details of the interaction. (author)

  18. Station Coordinates Combination Status and Contribution to ITRF2005

    Science.gov (United States)

    Ferland, R.

    2007-12-01

    Under the auspices of the International GNSS Service (IGS), the Reference Frame Working Group combines at Natural Resources Canada (NRCan) an accurate and consistent set of station coordinates, velocities and Earth Rotation Parameters (ERP) that are updated weekly. The consistency of these parameters is ensured by simultaneously combining them using their full variance-covariance information. The IGS Analysis Centers (ACs) (cod, emr, esa, gfz, jpl, mit, ngs, sio) provide the solutions used in the IGS weekly combination. The Global Network Associates Analysis Centers (GNAAC) (mit, ncl) also generate weekly combined solutions that include consistent station coordinates and ERPs. Those GNAAC solutions are used for comparisons and quality control of the IGS weekly solution. In recent weeks each AC has been contributing between about 50 and 250 station coordinates estimates. The combined product currently approaches 300 stations. Of those, between 40 and 110 are used for the current IGS reference frame realization of the ITRF2005 in each AC solution. The quality of the AC station coordinates solutions has improved significantly since they have started contributing in early 1996. This is due to the densification of the network of stations along with gradual improvements in station hardware and processing software. For recent solutions, the estimated noise (std. dev.) level between the AC weekly solutions and the different combined solutions varies between 1-3mm horizontally and 2-10mm vertically. More details about the statistics, their evolution and differences between the ACs will be presented. IGS weekly station coordinates and ERP combined products have also been contributed to the ITRF2005. Those weekly solutions were all recombined from the original AC contributions, going back to the beginning of 1996. The recombined solutions were edited for known problems (e.g. incorrect antenna heights and outliers). Several stations with short time span were also removed. A

  19. Coordinated Water Under Confinement Eases Sliding Friction

    Science.gov (United States)

    Defante, Adrian; Dhopotkar, Nishad; Dhinojwala, Ali

    Water is essential to a number of interfacial phenomena such as the lubrication of knee joints, protein folding, mass transport, and adsorption processes. We have used a biaxial friction cell to quantify underwater friction between a hydrophobic elastomeric lens and a hydrophobic self-assembled monolayer in the presence of surfactant solutions. To gain an understanding of the role of water in these processes we have coupled this measurement with surface sensitive sum frequency generation to directly probe the molecular constitution of the confined contact interface. We observe that role of confined coordinated water between two hydrophobic substrates covered with surfactants is the key to obtaining a low coefficient of friction.

  20. Tuning your priors to the world.

    Science.gov (United States)

    Feldman, Jacob

    2013-01-01

    The idea that perceptual and cognitive systems must incorporate knowledge about the structure of the environment has become a central dogma of cognitive theory. In a Bayesian context, this idea is often realized in terms of "tuning the prior"-widely assumed to mean adjusting prior probabilities so that they match the frequencies of events in the world. This kind of "ecological" tuning has often been held up as an ideal of inference, in fact defining an "ideal observer." But widespread as this viewpoint is, it directly contradicts Bayesian philosophy of probability, which views probabilities as degrees of belief rather than relative frequencies, and explicitly denies that they are objective characteristics of the world. Moreover, tuning the prior to observed environmental frequencies is subject to overfitting, meaning in this context overtuning to the environment, which leads (ironically) to poor performance in future encounters with the same environment. Whenever there is uncertainty about the environment-which there almost always is-an agent's prior should be biased away from ecological relative frequencies and toward simpler and more entropic priors.

  1. Generative supervised classification using Dirichlet process priors.

    Science.gov (United States)

    Davy, Manuel; Tourneret, Jean-Yves

    2010-10-01

    Choosing the appropriate parameter prior distributions associated to a given bayesian model is a challenging problem. Conjugate priors can be selected for simplicity motivations. However, conjugate priors can be too restrictive to accurately model the available prior information. This paper studies a new generative supervised classifier which assumes that the parameter prior distributions conditioned on each class are mixtures of Dirichlet processes. The motivations for using mixtures of Dirichlet processes is their known ability to model accurately a large class of probability distributions. A Monte Carlo method allowing one to sample according to the resulting class-conditional posterior distributions is then studied. The parameters appearing in the class-conditional densities can then be estimated using these generated samples (following bayesian learning). The proposed supervised classifier is applied to the classification of altimetric waveforms backscattered from different surfaces (oceans, ices, forests, and deserts). This classification is a first step before developing tools allowing for the extraction of useful geophysical information from altimetric waveforms backscattered from nonoceanic surfaces.

  2. A sensorimotor approach to the training of manual actions in children with developmental coordination disorder.

    Science.gov (United States)

    Snapp-Childs, Winona; Mon-Williams, Mark; Bingham, Geoffrey P

    2013-02-01

    Developmental coordination disorder affects a relatively large proportion (5%-6%) of the childhood population. Severity of the disorder varies but there is a great need for therapeutic intervention. We propose a method for the training of manual actions in children with developmental coordination disorder. Our solution is achieved by applying haptic virtual reality technology to attack the difficulties that children with developmental coordination disorder evidence. Our results show that children with developmental coordination disorder are able to learn complex motor skills if proper training methods are employed. These findings conflict with reports of impaired motor learning in developmental coordination disorder because of underactivation of cerebellar and parietal networks.

  3. GENERAL ASPECTS REGARDING THE PRIOR DISCIPLINARY RESEARCH

    Directory of Open Access Journals (Sweden)

    ANDRA PURAN (DASCĂLU

    2012-05-01

    Full Text Available Disciplinary research is the first phase of the disciplinary action. According to art. 251 paragraph 1 of the Labour Code no disciplinary sanction may be ordered before performing the prior disciplinary research.These regulations provide an exception: the sanction of written warning. The current regulations in question, kept from the old regulation, provides a protection for employees against abuses made by employers, since sanctions are affecting the salary or the position held, or even the development of individual employment contract. Thus, prior research of the fact that is a misconduct, before a disciplinary sanction is applied, is an essential condition for the validity of the measure ordered. Through this study we try to highlight some general issues concerning the characteristics, processes and effects of prior disciplinary research.

  4. Structured sparse priors for image classification.

    Science.gov (United States)

    Srinivas, Umamahesh; Suo, Yuanming; Dao, Minh; Monga, Vishal; Tran, Trac D

    2015-06-01

    Model-based compressive sensing (CS) exploits the structure inherent in sparse signals for the design of better signal recovery algorithms. This information about structure is often captured in the form of a prior on the sparse coefficients, with the Laplacian being the most common such choice (leading to l1 -norm minimization). Recent work has exploited the discriminative capability of sparse representations for image classification by employing class-specific dictionaries in the CS framework. Our contribution is a logical extension of these ideas into structured sparsity for classification. We introduce the notion of discriminative class-specific priors in conjunction with class specific dictionaries, specifically the spike-and-slab prior widely applied in Bayesian sparse regression. Significantly, the proposed framework takes the burden off the demand for abundant training image samples necessary for the success of sparsity-based classification schemes. We demonstrate this practical benefit of our approach in important applications, such as face recognition and object categorization.

  5. Commissioning of the PRIOR proton microscope

    CERN Document Server

    Varentsov, D; Bakhmutova, A; Barnes, C W; Bogdanov, A; Danly, C R; Efimov, S; Endres, M; Fertman, A; Golubev, A A; Hoffmann, D H H; Ionita, B; Kantsyrev, A; Krasik, Ya E; Lang, P M; Lomonosov, I; Mariam, F G; Markov, N; Merrill, F E; Mintsev, V B; Nikolaev, D; Panyushkin, V; Rodionova, M; Schanz, M; Schoenberg, K; Semennikov, A; Shestov, L; Skachkov, V S; Turtikov, V; Udrea, S; Vasylyev, O; Weyrich, K; Wilde, C; Zubareva, A

    2015-01-01

    Recently a new high energy proton microscopy facility PRIOR (Proton Microscope for FAIR) has been designed, constructed and successfully commissioned at GSI Helmholtzzentrum f\\"ur Schwerionenforschung (Darmstadt, Germany). As a result of the experiments with 3.5-4.5 GeV proton beams delivered by the heavy ion synchrotron SIS-18 of GSI, 30 um spatial and 10 ns temporal resolutions of the proton microscope have been demostrated. A new pulsed power setup for studying properties of matter under extremes has been developed for the dynamic commissioning of the PRIOR facility. This paper describes the PRIOR setup as well as the results of the first static and dynamic proton radiography experiments performed at GSI.

  6. Entropic Priors and Bayesian Model Selection

    CERN Document Server

    Brewer, Brendon J

    2009-01-01

    We demonstrate that the principle of maximum relative entropy (ME), used judiciously, can ease the specification of priors in model selection problems. The resulting effect is that models that make sharp predictions are disfavoured, weakening the usual Bayesian "Occam's Razor". This is illustrated with a simple example involving what Jaynes called a "sure thing" hypothesis. Jaynes' resolution of the situation involved introducing a large number of alternative "sure thing" hypotheses that were possible before we observed the data. However, in more complex situations, it may not be possible to explicitly enumerate large numbers of alternatives. The entropic priors formalism produces the desired result without modifying the hypothesis space or requiring explicit enumeration of alternatives; all that is required is a good model for the prior predictive distribution for the data. This idea is illustrated with a simple rigged-lottery example, and we outline how this idea may help to resolve a recent debate amongst ...

  7. Generative Prior Knowledge for Discriminative Classification

    CERN Document Server

    DeJong, G; 10.1613/jair.1934

    2011-01-01

    We present a novel framework for integrating prior knowledge into discriminative classifiers. Our framework allows discriminative classifiers such as Support Vector Machines (SVMs) to utilize prior knowledge specified in the generative setting. The dual objective of fitting the data and respecting prior knowledge is formulated as a bilevel program, which is solved (approximately) via iterative application of second-order cone programming. To test our approach, we consider the problem of using WordNet (a semantic database of English language) to improve low-sample classification accuracy of newsgroup categorization. WordNet is viewed as an approximate, but readily available source of background knowledge, and our framework is capable of utilizing it in a flexible way.

  8. Coordination Control Of Complex Machines

    NARCIS (Netherlands)

    J.C.M. Baeten; B. van Beek; J. Markovski; L.J.A.M. Somers

    2015-01-01

    Control and coordination are important aspects of the development of complex machines due to an ever-increasing demand for better functionality, quality, and performance. In WP6 of the C4C project, we developed a synthesis-centric systems engineering framework suitable for supervisory coordination o

  9. Coordinate-Free Rotation Operator.

    Science.gov (United States)

    Leubner, C.

    1979-01-01

    Suggests the use of a coordinate-free rotation operator for the teaching of rotations in Euclidean three space because of its twofold didactic advantage. Illustrates the potentialities of the coordinate-free rotation operator approach by a number of examples. (Author/GA)

  10. Coordination of Conditional Poisson Samples

    Directory of Open Access Journals (Sweden)

    Grafström Anton

    2015-12-01

    Full Text Available Sample coordination seeks to maximize or to minimize the overlap of two or more samples. The former is known as positive coordination, and the latter as negative coordination. Positive coordination is mainly used for estimation purposes and to reduce data collection costs. Negative coordination is mainly performed to diminish the response burden of the sampled units. Poisson sampling design with permanent random numbers provides an optimum coordination degree of two or more samples. The size of a Poisson sample is, however, random. Conditional Poisson (CP sampling is a modification of the classical Poisson sampling that produces a fixed-size πps sample. We introduce two methods to coordinate Conditional Poisson samples over time or simultaneously. The first one uses permanent random numbers and the list-sequential implementation of CP sampling. The second method uses a CP sample in the first selection and provides an approximate one in the second selection because the prescribed inclusion probabilities are not respected exactly. The methods are evaluated using the size of the expected sample overlap, and are compared with their competitors using Monte Carlo simulation. The new methods provide a good coordination degree of two samples, close to the performance of Poisson sampling with permanent random numbers.

  11. Adaptive group coordination and role differentiation.

    Directory of Open Access Journals (Sweden)

    Michael E Roberts

    Full Text Available Many real world situations (potluck dinners, academic departments, sports teams, corporate divisions, committees, seminar classes, etc. involve actors adjusting their contributions in order to achieve a mutually satisfactory group goal, a win-win result. However, the majority of human group research has involved situations where groups perform poorly because task constraints promote either individual maximization behavior or diffusion of responsibility, and even successful tasks generally involve the propagation of one correct solution through a group. Here we introduce a group task that requires complementary actions among participants in order to reach a shared goal. Without communication, group members submit numbers in an attempt to collectively sum to a randomly selected target number. After receiving group feedback, members adjust their submitted numbers until the target number is reached. For all groups, performance improves with task experience, and group reactivity decreases over rounds. Our empirical results provide evidence for adaptive coordination in human groups, and as the coordination costs increase with group size, large groups adapt through spontaneous role differentiation and self-consistency among members. We suggest several agent-based models with different rules for agent reactions, and we show that the empirical results are best fit by a flexible, adaptive agent strategy in which agents decrease their reactions when the group feedback changes. The task offers a simple experimental platform for studying the general problem of group coordination while maximizing group returns, and we distinguish the task from several games in behavioral game theory.

  12. Nanometrization of Lanthanide-Based Coordination Polymers.

    Science.gov (United States)

    Neaime, Chrystelle; Daiguebonne, Carole; Calvez, Guillaume; Freslon, Stéphane; Bernot, Kevin; Grasset, Fabien; Cordier, Stéphane; Guillou, Olivier

    2015-11-23

    Heteronuclear lanthanide-based coordination polymers are microcrystalline powders, the luminescence properties of which can be precisely tuned by judicious choice of the rare-earth ions. In this study, we demonstrate that such materials can also be obtained as stable solutions of nanoparticles in non-toxic polyols. Bulk powders of the formula [Ln2-2x Ln'2x (bdc)3 ⋅4 H2 O]∞ (where H2 bdc denotes 1,4-benzene-dicarboxylic acid, 0≤x≤1, and Ln and Ln' denote lanthanide ions of the series La to Tm plus Y) afford nanoparticles that have been characterized by dynamic light-scattering (DLS) and transmission electron microscopy (TEM) measurements. Their luminescence properties are similar to those of the bulk materials. Stabilities versus time and versus dilution with another solvent have been studied. This study has revealed that it is possible to tune the size of the nanoparticles. This process offers a reliable means of synthesizing suspensions of nanoparticles with tunable luminescence properties and tunable size distributions in a green solvent (glycerol). The process is also extendable to other coordination polymers and other solvents (ethylene glycol, for example). It constitutes a new route for the facile solubilization of lanthanide-based coordination polymers.

  13. Genome position specific priors for genomic prediction

    DEFF Research Database (Denmark)

    Brøndum, Rasmus Froberg; Su, Guosheng; Lund, Mogens Sandø

    2012-01-01

    population when using a prior derived from the Nordic Holstein population compared to using no prior information. These improvements were significant (PHotelling Williams t-test for protein- and fat yield Conclusion For some traits the method might be advantageous compared to pooling...... to estimate SNP effects, except in the case of fat yield. The small size of the Jersey validation set meant that these improvements in accuracy were not significant using a Hotelling-Williams t-test at the 5% level. An increase in accuracy of 1-2% for all traits was observed in the Australian Holstein...

  14. Numbers and prior knowledge in sentence comprehension

    Directory of Open Access Journals (Sweden)

    Pedro Macizo

    2013-01-01

    Full Text Available We evaluated whether the comprehension of sentences that contained numerical information could benefit from presenting numbers in Arabic format and from using prior knowledge. Participants read sentences including numbers (Arabic digits or number words while the comprehension accuracy was evaluated. In addition, the sentences were biased or unbiased by people's prior knowledge about quantities. The results showed better comprehension for sentences that contained Arabic digits as compared to number words. Moreover, biased sentences were understood more accurately than unbiased sentences. These results indicate that information about magnitude in sentence context is comprehended better when quantities are presented in Arabic format and when they are associated with participants' world knowledge.

  15. Reasoning about coordination in the problem of conceptualization

    DEFF Research Database (Denmark)

    Hansen, Pelle Guldborg

    2010-01-01

    Within the last decade or so theories of inductive learning in games have increasingly become the primary approach in the construction of models for explaining how agents may resolve repeated coordination problems as well as the emergence social conventions at the more general level. However...... rest on convention and thus that the models only work by begging the question they were thought to answer. Finally, the paper points to the possibility that a non-circular solution to the problem of conceptualization may be found in an understanding of the way agents reason about coordination, when...... the idea of repeated coordination itself acts as a frame for conceptualizing their mutual decision problem as a coordination problem....

  16. Validity in assessment of prior learning

    DEFF Research Database (Denmark)

    Wahlgren, Bjarne; Aarkrog, Vibe

    2015-01-01

    The article deals with the results of a study of school-based assessment of adults who have enrolled as students at a vocational college in order to qualify for occupations as skilled workers. Based on examples of methods for assessing the students’ prior learning in a programme for hairdressers...

  17. Action priors for learning domain invariances

    CSIR Research Space (South Africa)

    Rosman, Benjamin S

    2015-04-01

    Full Text Available , defined as distributions over the action space, conditioned on environment state, and show how these can be learnt from a set of value functions. We apply action priors in the setting of reinforcement learning, to bias action selection during exploration...

  18. Recognition of Prior Learning: The Participants' Perspective

    Science.gov (United States)

    Miguel, Marta C.; Ornelas, José H.; Maroco, João P.

    2016-01-01

    The current narrative on lifelong learning goes beyond formal education and training, including learning at work, in the family and in the community. Recognition of prior learning is a process of evaluation of those skills and knowledge acquired through life experience, allowing them to be formally recognized by the qualification systems. It is a…

  19. Validity in assessment of prior learning

    DEFF Research Database (Denmark)

    Wahlgren, Bjarne; Aarkrog, Vibe

    2015-01-01

    The article deals with the results of a study of school-based assessment of adults who have enrolled as students at a vocational college in order to qualify for occupations as skilled workers. Based on examples of methods for assessing the students’ prior learning in a programme for hairdressers...

  20. The prior statistics of object colors

    NARCIS (Netherlands)

    Koenderink, J.J.

    2010-01-01

    The prior statistics of object colors is of much interest because extensive statistical investigations of reflectance spectra reveal highly non-uniform structure in color space common to several very different databases. This common structure is due to the visual system rather than to the statistics

  1. Models for Validation of Prior Learning (VPL)

    DEFF Research Database (Denmark)

    Ehlers, Søren

    would have been categorized as utopian can become realpolitik. Validation of Prior Learning (VPL) was in Europe mainly regarded as utopian while universities in the United States of America (USA) were developing ways to obtain credits to those students which was coming with experiences from working life....

  2. Offending prior to first psychiatric contact

    DEFF Research Database (Denmark)

    Stevens, H; Agerbo, E; Dean, K

    2012-01-01

    There is a well-established association between psychotic disorders and subsequent offending but the extent to which those who develop psychosis might have a prior history of offending is less clear. Little is known about whether the association between illness and offending exists in non-psychot...

  3. The Coordinated Control Solution for the Reactive Compensation of Large-Scale Onshore Wind Power Projects---Taking South Huashan Wind Farm as an Example%大型陆上风电项目无功补偿协调控制方案--以南华山风电场为例

    Institute of Scientific and Technical Information of China (English)

    王建华; 张婷; 王淼

    2015-01-01

    在近几年的风电项目设计中,大型风力发电升压站35 kV母线段存在采用不同厂家无功补偿设备的现象,不同厂家控制系统独立引起无功的发出和吸收同时存在相互抵消的问题。针对上述问题,结合山西南华山风电工程经验,提出了较为全面的协调解决方案,经实测波形验证该方案有效地提高了电压合格率,为同类工程设计提供了良好的参考。%In recent years’ design of wind power projects, there is the phenomenon that could be clearly find from recently designed onshore wind farms that the single 35 kV busbar equipped in the large-scale wind-power booster station adopts the reactive compensation equipment produced by different manufactures, and a new problem emerged due to the different control systems, that is, the reactive power issued could be offset by the power absorbed. In the light of above-mentioned problem, and connecting with the experiences of Shanxi South Huashan Wind Power Project, this paper puts forward a new relatively comprehensive coordinated control solution, which can effectively improves the voltage qualification rate through actual waveform measurement and provide a good reference for similar engineering design.

  4. Keep Meaning in Conversational Coordination

    Directory of Open Access Journals (Sweden)

    Elena Clare Cuffari

    2014-12-01

    Full Text Available Coordination is a widely employed term across recent quantitative and qualitative approaches to intersubjectivity, particularly approaches that give embodiment and enaction central explanatory roles. With a focus on linguistic and bodily coordination in conversational contexts, I review the operational meaning of coordination in recent empirical research and related theorizing of embodied intersubjectivity. This discussion articulates what must be involved in treating linguistic meaning as dynamic processes of coordination. The coordination approach presents languaging as a set of dynamic self-organizing processes and actions on multiple timescales and across multiple modalities that come about and work in certain domains (those jointly constructed in social, interactive, high-order sense-making. These processes go beyond meaning at the level that is available to first-person experience. I take one crucial consequence of this to be the ubiquitously moral nature of languaging with others. Languaging coordinates experience, among other levels of behavior and event. Ethical effort is called for by the automatic autonomy-influencing forces of languaging as coordination.

  5. Chinese geodetic coordinate system 2000

    Institute of Scientific and Technical Information of China (English)

    YANG YuanXi

    2009-01-01

    The basic strategies In establishing the Chinese geodetic coordinate system 2000 have been summarized,including the definition of the coordinate system,the structure of the terrestrial reference frame,the functional and stochastic models involved in the realization of the reference frame as well as the Improvements of the adjustment procedures.First,the fundamental frame of the coordinate system is composed of the permanent GPS tracking network in China which is integrated into the international GPS service stations by combined adjustment,in order to guarantee the consistence between the international terrestrial reference system and the Chinese geodetic coordinate system.Second,the extended frame of the coordinate system is composed of the unified 2000' national GPS network which is Integrated by 6 nationwide GPS networks with more than 2500 stations under the controlling of the fundamental frame.Third,the densified frame is composed of national astronomical geodetic network with nearly 50 thousand stations which was updated by the combined adjustment with the 2000' national GPS network,thus the datum of the national astronomical geodetic network has been unified and the precision greatly improved.By the optimal data fusion method the influences of the datum errors,systematic errors and the outliers in the separated geodetic networks are weakened in the unified Chinese geodetic coordinate frame.The significance in application of the new geodetic coordinate system and the existing problems In the reference frame are described and analyzed.

  6. Toward a theory of coordinating: Creating coordinating mechanisms in practice

    OpenAIRE

    Jarzabkowski, P; Le, J. K.; Feldman, M. S.

    2012-01-01

    This paper uses a practice perspective to study coordinating as dynamic activities that are continuously created and modified in order to enact organizational relationships and activities. It is based on the case of Servico, an organization undergoing a major restructuring of its value chain in response to a change in government regulation. In our case, the actors iterate between the abstract concept of a coordinating mechanism referred to as end-to-end management and its performance in pract...

  7. Evaluating the Relational Coordination instrument

    DEFF Research Database (Denmark)

    Edwards, Kasper; Lundstrøm, Sanne Lykke

    2014-01-01

    and surgical performance. This has prompted the attention of both practitioners and politicians some of who perceive relational coordination as a means to attain better performance. The relational coordination instrument has been validated as a measure of teamwork from the following perspectives: internal...... consistency, interrater agreement and reliability, structural validity, content validity. However as relational coordination is being used as a diagnostics tool it is important to examine further if the instrument can measure changes. Indeed we need to know how precise and sensitive the instrument is when...

  8. Total Logistic Plant Solutions

    Directory of Open Access Journals (Sweden)

    Dusan Dorcak

    2016-02-01

    Full Text Available The Total Logistics Plant Solutions, plant logistics system - TLPS, based on the philosophy of advanced control processes enables complex coordination of business processes and flows and the management and scheduling of production in the appropriate production plans and planning periods. Main attributes of TLPS is to create a comprehensive, multi-level, enterprise logistics information system, with a certain degree of intelligence, which accepts the latest science and research results in the field of production technology and logistics. Logistic model of company understands as a system of mutually transforming flows of materials, energy, information, finance, which is realized by chain activities and operations

  9. Multifractal analysis and instability index of prior-to-crash market situations

    CERN Document Server

    Piacquadio, M

    2009-01-01

    We take prior-to-crash market prices (NASDAQ, Dow Jones Industrial Average) as a signal, a function of time, we project these discrete values onto a vertical axis, thus obtaining a Cantordust. We study said cantordust with the tools of multifractal analysis, obtaining spectra by definition and by lagrangian coordinates. These spectra have properties that typify the prior-to-crash market situation. Any of these spectra entail elaborate processing of the raw signal data. With the unprocessed raw data we obtain an instability index, also with properties that typify the prior-to-crisis market situation. Both spectra and the instability index agree in characterizing such crashes, and in giving an early warning of them.

  10. Some properties of emission coordinates

    CERN Document Server

    Pozo, J M

    2006-01-01

    4 emitters broadcasting an increasing electromagnetic signal generate a system of relativistic coordinates for the space-time, called emission coordinates. Their physical realization requires an apparatus similar to the one of the Global Navigation Satellite Systems (GNSS). Several relativistic corrections are utilized for the current precisions, but the GNSS are conceived as classical (Newtonian) systems, which has deep implications in the way of operating them. The study of emission coordinates is an essential step in order to develop a fully relativistic theory of positioning systems. This talk presents some properties of emission coordinates. In particular, we characterize how any observer sees a configuration of satellites giving a degenerated system and show that the trajectories of the satellites select a unique privileged observer at each point and, for any observer, a set of 3 orthogonal spatial axes.

  11. Coordination Games on Dynamical Networks

    Directory of Open Access Journals (Sweden)

    Enea Pestelacci

    2010-07-01

    Full Text Available We propose a model in which agents of a population interacting according to a network of contacts play games of coordination with each other and can also dynamically break and redirect links to neighbors if they are unsatisfied. As a result, there is co-evolution of strategies in the population and of the graph that represents the network of contacts. We apply the model to the class of pure and general coordination games. For pure coordination games, the networks co-evolve towards the polarization of different strategies. In the case of general coordination games our results show that the possibility of refusing neighbors and choosing different partners increases the success rate of the Pareto-dominant equilibrium.

  12. Fedosov supermanifolds: II. Normal coordinates

    CERN Document Server

    Geyer, B; Geyer, Bodo; Lavrov, Peter

    2004-01-01

    The study of recently introduced Fedosov supermanifolds is continued. Using normal coordinates, properties of even and odd symplectic supermanifolds endowed with a symmetric connection respecting given sympletic structure are studied.

  13. Surface normals and barycentric coordinates

    Directory of Open Access Journals (Sweden)

    Mullineux Glen

    1996-01-01

    Full Text Available The normal to a triangular parametric surface is investigated where the parameters used are barycentric coordinates. Formulae for the normal are obtained for non-rational and rational surfaces.

  14. Ellipsoidal analysis of coordination polyhedra

    Science.gov (United States)

    Cumby, James; Attfield, J. Paul

    2017-02-01

    The idea of the coordination polyhedron is essential to understanding chemical structure. Simple polyhedra in crystalline compounds are often deformed due to structural complexity or electronic instabilities so distortion analysis methods are useful. Here we demonstrate that analysis of the minimum bounding ellipsoid of a coordination polyhedron provides a general method for studying distortion, yielding parameters that are sensitive to various orders in metal oxide examples. Ellipsoidal analysis leads to discovery of a general switching of polyhedral distortions at symmetry-disallowed transitions in perovskites that may evidence underlying coordination bistability, and reveals a weak off-centre `d5 effect' for Fe3+ ions that could be exploited in multiferroics. Separating electronic distortions from intrinsic deformations within the low temperature superstructure of magnetite provides new insights into the charge and trimeron orders. Ellipsoidal analysis can be useful for exploring local structure in many materials such as coordination complexes and frameworks, organometallics and organic molecules.

  15. Prior Information in Inverse Boundary Problems

    DEFF Research Database (Denmark)

    Garde, Henrik

    This thesis gives a threefold perspective on the inverse problem of inclusion detection in electrical impedance tomography: depth dependence, monotonicitybased reconstruction, and sparsity-based reconstruction. The depth dependence is given in terms of explicit bounds on the datum norm, which shows...... into how much noise that can be allowed in the datum before an inclusion cannot be detected. The monotonicity method is a direct reconstruction method that utilizes a monotonicity property of the forward problem in order to characterize the inclusions. Here we rigorously prove that the method can...... of the method. Sparsity-based reconstruction is an iterative method, that through an optimization problem with a sparsity prior, approximates the inhomogeneities. Here we make use of prior information, that can cheaply be obtained from the monotonicity method, to improve both the contrast and resolution...

  16. Image Segmentation Using Weak Shape Priors

    CERN Document Server

    Xu, Robert Sheng; Salama, Magdy

    2010-01-01

    The problem of image segmentation is known to become particularly challenging in the case of partial occlusion of the object(s) of interest, background clutter, and the presence of strong noise. To overcome this problem, the present paper introduces a novel approach segmentation through the use of "weak" shape priors. Specifically, in the proposed method, an segmenting active contour is constrained to converge to a configuration at which its geometric parameters attain their empirical probability densities closely matching the corresponding model densities that are learned based on training samples. It is shown through numerical experiments that the proposed shape modeling can be regarded as "weak" in the sense that it minimally influences the segmentation, which is allowed to be dominated by data-related forces. On the other hand, the priors provide sufficient constraints to regularize the convergence of segmentation, while requiring substantially smaller training sets to yield less biased results as compare...

  17. Kaluza's theory in generalized coordinates

    CERN Document Server

    García-Perciante, A L; García-Colin, L S; Garcia-Perciante, Ana Laura; Sandoval-Villalbazo, Alfredo

    2001-01-01

    Maxwell's equations can be obtained in generalized coordinates by considering the electromagnetic field as an external agent. The work here presented shows how to obtain the electrodynamics for a charged particle in generalized coordinates eliminating the concept of external force. Based on Kaluza's formalism, the one here presented extends the 5x5 metric into a 6x6 space-time giving enough room to include magnetic monopoles in a very natural way.

  18. Coordination theory and collaboration technology

    CERN Document Server

    Olson, Gary M; Smith, John B

    2001-01-01

    The National Science Foundation funded the first Coordination Theory and Collaboration Technology initiative to look at systems that support collaborations in business and elsewhere. This book explores the global revolution in human interconnectedness. It will discuss the various collaborative workgroups and their use in technology. The initiative focuses on processes of coordination and cooperation among autonomous units in human systems, in computer and communication systems, and in hybrid organizations of both systems. This initiative is motivated by three scientific issues which have been

  19. CPN Models in General Coordinates

    CERN Document Server

    Barnes, K J

    2002-01-01

    An analysis of CPN models is given in terms of general coordinates or arbitrary interpolating fields.Only closed expressions made from simple functions are involved.Special attention is given to CP2 and CP4. In the first of these the retrieval of stereographic coordinates reveals the hermitian form of the metric. A similar analysis for the latter case allows comparison with the Fubini-Study metric.

  20. Inflation, Growth and Policy Coordination

    OpenAIRE

    Renato E. Reside Jr.; Parantap Basu

    1996-01-01

    The effect of monetary policy on output growth and inflation is examined in a monetary endogenous growth model with an explicit banking sector that intermediates capital. Monetary policy is coordinated with fiscal policy in the sense that all the seigniorage revenue gleaned through the inflation tax is spent to make efficient provision of public services. With the reserve requirement and money growth as instruments, policy coordination implies that one instrument may be solved endogenously wh...

  1. Engineering report (conceptual design) PFP solution stabilization

    Energy Technology Data Exchange (ETDEWEB)

    Witt, J.B.

    1997-07-17

    This Engineering Report (Conceptual Design) addresses remediation of the plutonium-bearing solutions currently in inventory at the Plutonium Finishing Plant (PFP). The recommendation from the Environmental Impact Statement (EIS) is that the solutions be treated thermally and stabilized as a solid for long term storage. For solutions which are not discardable, the baseline plan is to utilize a denitration process to stabilize the solutions prior to packaging for storage.

  2. Plasticity of intermediate mechanics students’ coordinate system choice

    Directory of Open Access Journals (Sweden)

    Eleanor C. Sayre

    2008-11-01

    Full Text Available We investigate the interplay between mathematics and physics resources in intermediate mechanics students. In the mechanics course, the selection and application of coordinate systems is a consistent thread. At the University of Maine, students often start the course with a strong preference to use Cartesian coordinates, in accordance with their prior physics and mathematics classes. In small-group interviews and in homework help sessions, we ask students to define a coordinate system and set up the equations of motion for a simple pendulum for which polar coordinates are more appropriate. We analyze video data from several encounters using a combination of Process/Object theory and Resource Theory. We find that students sometimes persist in using an inappropriate Cartesian system. Furthermore, students often derive (rather than recall the details of the polar coordinate system, indicating that their knowledge is far from solid. To describe our work more precisely, we define a scale of plasticity and several heuristics for defining resources and their plasticity.

  3. Spanning boundaries and creating strong patient relationships to coordinate care are strategies used by experienced chronic condition care coordinators.

    Science.gov (United States)

    Ehrlich, Carolyn; Kendall, Elizabeth; Muenchberger, Heidi

    2012-08-01

    People with complex chronic conditions frequently need to navigate their own way through and around a fragmented and siloed health care system. Care coordination is a defining principle of primary care and is frequently proposed as a solution to this problem. However, care coordination requires more time and effort than primary care physicians alone have the capacity to deliver. Although registered nurses (RNs) are skilled team members who can be included in the delivery of coordinated patient care, any model of care coordination that involves RNs needs to fit within the existing health care delivery system. In this study, which used qualitative techniques based on grounded theory and included face-to-face interviews and open coding and theoretical sampling until data saturation was achieved, and which was one component of a larger action research study, we aimed to gain an understanding of the difference between usual chronic condition care and the work of chronic condition care coordination. The researchers interviewed general practitioners and RNs from various general practice sites who were actively coordinating care. Four unique processes were found to define care coordination implementation, namely: (1) moving beyond usual practice by spanning boundaries; (2) relationship-based care; (3) agreed roles and routines among relevant parties; and (4) committing to chronic condition care coordination. The findings suggested that existing professional and organisational cultures required negotiation before care coordination could be integrated into existing contexts. The challenge, however, seems to be in acknowledging and overcoming professional practice boundaries that define existing care through reflective practice and shared resourcing.

  4. Design and construction coordination problems and planning for design-build project new users

    National Research Council Canada - National Science Library

    Shen, Fang-Ying; Chang, Andrew S; Ibbs, William

    2010-01-01

    ... to be encountered in execution by new users. This paper investigates coordination problems arising from design and construction concurrence and solutions by studying five ongoing DB projects and interviewing nine major contract parties...

  5. Managing interteam coordination within and between organizations

    NARCIS (Netherlands)

    de Vries, Thomas Arend

    2015-01-01

    To accomplish complex tasks and effectively respond to environmental contingencies, teams must coordinate task-related issues with other teams (i.e., interteam coordination). Regrettably, interteam coordination is often complicated by misunderstandings that can arise from differences in teams’

  6. R3GMRES: including prior information in GMRES-type methods for discrete inverse problems

    DEFF Research Database (Denmark)

    Dong, Yiqiu; Garde, Henrik; Hansen, Per Christian

    2014-01-01

    Lothar Reichel and his collaborators proposed several iterative algorithms that augment the underlying Krylov subspace with an additional low-dimensional subspace in order to produce improved regularized solutions. We take a closer look at this approach and investigate a particular Regularized Ra...... Range-Restricted GMRES method, R3GMRES, with a subspace that represents prior information about the solution. We discuss the implementation of this approach and demonstrate its advantage by means of several test problems....

  7. Metallogels from Coordination Complexes, Organometallic, and Coordination Polymers.

    Science.gov (United States)

    Dastidar, Parthasarathi; Ganguly, Sumi; Sarkar, Koushik

    2016-09-20

    A supramolecular gel results from the immobilization of solvent molecules on a 3D network of gelator molecules stabilized by various supramolecular interactions that include hydrogen bonding, π-π stacking, van der Waals interactions, and halogen bonding. In a metallogel, a metal is a part of the gel network as a coordinated metal ion (in a discrete coordination complex), as a cross-linking metal node with a multitopic ligand (in coordination polymer), and as metal nanoparticles adhered to the gel network. Although the field is relatively new, research into metallogels has experienced a considerable upsurge owing to its fundamental importance in supramolecular chemistry and various potential applications. This focus review aims to provide an insight into the development of designing metallogelators. Because of the limited scope, discussions are confined to examples pertaining to metallogelators derived from discrete coordination complexes, organometallic gelators, and coordination polymers. This review is expected to enlighten readers on the current development of designing metallogelators of the abovementioned class of molecules. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Multipolar Solutions

    CERN Document Server

    Quevedo, Hernando

    2012-01-01

    A class of exact solutions of the Einstein-Maxwell equations is presented which contains infinite sets of gravitoelectric, gravitomagnetic and electromagnetic multipole moments. The multipolar structure of the solutions indicates that they can be used to describe the exterior gravitational field of an arbitrarily rotating mass distribution endowed with an electromagnetic field. The presence of gravitational multipoles completely changes the structure of the spacetime because of the appearance of naked singularities in a confined spatial region. The possibility of covering this region with interior solutions is analyzed in the case of a particular solution with quadrupole moment.

  9. Probing the coordination environment of Ti(3+) ions coordinated to nitrogen-containing Lewis bases.

    Science.gov (United States)

    Morra, E; Maurelli, S; Chiesa, M; Van Doorslaer, S

    2015-08-28

    Multi-frequency continuous-wave and pulsed EPR techniques are employed to investigate the coordination of nitrogen-containing ligands to Ti(3+)-chloro complexes. Frozen solutions of TiCl3 and TiCl3(Py)3 dissolved in nitrogen-containing solvents have been investigated together with the TiCl3(Py)3 solid-state complex. For these different systems, the hyperfine and nuclear quadrupole data of Ti(3+)-bound (14)N nuclei are reported and discussed in the light of DFT computations, allowing for a detailed description of the microscopic structure of these systems.

  10. Graph cuts with invariant object-interaction priors: application to intervertebral disc segmentation.

    Science.gov (United States)

    Ben Ayed, Ismail; Punithakumar, Kumaradevan; Garvin, Gregory; Romano, Walter; Li, Shuo

    2011-01-01

    This study investigates novel object-interaction priors for graph cut image segmentation with application to intervertebral disc delineation in magnetic resonance (MR) lumbar spine images. The algorithm optimizes an original cost function which constrains the solution with learned prior knowledge about the geometric interactions between different objects in the image. Based on a global measure of similarity between distributions, the proposed priors are intrinsically invariant with respect to translation and rotation. We further introduce a scale variable from which we derive an original fixed-point equation (FPE), thereby achieving scale-invariance with only few fast computations. The proposed priors relax the need of costly pose estimation (or registration) procedures and large training sets (we used a single subject for training), and can tolerate shape deformations, unlike template-based priors. Our formulation leads to an NP-hard problem which does not afford a form directly amenable to graph cut optimization. We proceeded to a relaxation of the problem via an auxiliary function, thereby obtaining a nearly real-time solution with few graph cuts. Quantitative evaluations over 60 intervertebral discs acquired from 10 subjects demonstrated that the proposed algorithm yields a high correlation with independent manual segmentations by an expert. We further demonstrate experimentally the invariance of the proposed geometric attributes. This supports the fact that a single subject is sufficient for training our algorithm, and confirms the relevance of the proposed priors to disc segmentation.

  11. Dynamics of coupled field solitons: A collective coordinate approach

    Indian Academy of Sciences (India)

    Danial Saadatmand; Aliakbar Moradi Marjaneh; Mahdi Heidari

    2014-10-01

    In this paper we consider a class of systems of two coupled real scalar fields in bidimensional space-time, with the main motivation of studying classical stability of soliton solutions using collective coordinate approach. First, we present the class of systems of the collective coordinate equations which are derived using the presented method. After that, we follow the dynamics of the coupled fields with local inhomogeneity like a delta function potential wall as well as a delta function potential well. The results of the investigation of the two coupled fields are compared to each other and the differences are discussed. The method can predict most of the characters of the interaction.

  12. [Registration of prehabilitation prior to surgery].

    Science.gov (United States)

    Tønnesen, Hanne; Duus, Benn R

    2008-04-21

    Four to eight week prehabilitation programs for smokers and harmful drinkers were included in the national guidelines in 2001. In October 2007 a guarantee for surgery within one month of waiting time came into effect in Denmark. The present Danish patient administration system already contains room for registration of prehabilitation prior to surgery. Using one specific code for prehabilitation at the surgical department and another for prehabilitation at other departments will enable correct registration. Thereby, it is possible to differentiate between ordinary waiting time before surgery and time for prehabilitation.

  13. Copy Me or Copy You? The Effect of Prior Experience on Social Learning

    Science.gov (United States)

    Wood, Lara A.; Kendal, Rachel L.; Flynn, Emma G.

    2013-01-01

    The current study investigated children's solution choice and imitation of causally-irrelevant actions by using a controlled design to mirror naturalistic learning contexts in which children receive social information for tasks about which they have some degree of prior knowledge. Five-year-old children (N = 167) were presented with a reward…

  14. Werner coordination chemistry and neurodegeneration.

    Science.gov (United States)

    Telpoukhovskaia, Maria A; Orvig, Chris

    2013-02-21

    Neurodegenerative diseases are capturing the world's attention as being the next set of diseases we must tackle collectively. Not only are the patients experiencing gradual cognitive and physical decline in most cases, but these diseases are fatal with no prevention currently available. As these diseases are progressive, providing care and symptom treatment for the ageing population is becoming both a medical and a financial challenge. This review discusses how Werner coordination chemistry plays a role in three diseases - those of Alzheimer's, Parkinson's, and prions. Metal ions are considered to be involved in these diseases in part via their propensity to cause toxic aggregation of proteins. First, the coordination of metal ions, with emphasis on copper(II), to metalloproteins that are hallmarks of these diseases - amyloid β, α-synuclein, and prion, respectively - will be discussed. We will present the current understanding of the metal coordination environments created by the amino acids of these proteins, as well as metal binding affinity. Second, a diverse set of examples of rationally designed metal chelators to outcompete this deleterious binding will be examined based on coordination mode and affinity toward bio-relevant metal ions. Overall, this review will give a general overview of protein and metal chelator coordination environments in neurodegenerative diseases.

  15. Tensors, BICEP2, prior dependence, and dust

    CERN Document Server

    Cortês, Marina; Parkinson, David

    2014-01-01

    We investigate the prior dependence on the inferred spectrum of primordial tensor perturbations, in light of recent results from BICEP2 and taking into account a possible dust contribution to polarized anisotropies. We highlight an optimized parameterization of the tensor power spectrum, and adoption of a logarithmic prior on its amplitude $A_T$, leading to results that transform more evenly under change of pivot scale. In the absence of foregrounds the tension between the results of BICEP2 and Planck drives the tensor spectral index $n_T$ to be blue-tilted in a joint analysis, which would be in contradiction to the standard inflation prediction ($n_T<0$). When foregrounds are accounted for, the BICEP2 results no longer require non-standard inflationary parameter regions. We present limits on primordial $A_T$ and $n_T$, adopting foreground scenarios put forward by Mortonson & Seljak and motivated by Planck 353 GHz observations, and assess what dust contribution leaves a detectable cosmological signal. ...

  16. How prior expectations shape multisensory perception.

    Science.gov (United States)

    Gau, Remi; Noppeney, Uta

    2016-01-01

    The brain generates a representation of our environment by integrating signals from a common source, but segregating signals from different sources. This fMRI study investigated how the brain arbitrates between perceptual integration and segregation based on top-down congruency expectations and bottom-up stimulus-bound congruency cues. Participants were presented audiovisual movies of phonologically congruent, incongruent or McGurk syllables that can be integrated into an illusory percept (e.g. "ti" percept for visual «ki» with auditory /pi/). They reported the syllable they perceived. Critically, we manipulated participants' top-down congruency expectations by presenting McGurk stimuli embedded in blocks of congruent or incongruent syllables. Behaviorally, participants were more likely to fuse audiovisual signals into an illusory McGurk percept in congruent than incongruent contexts. At the neural level, the left inferior frontal sulcus (lIFS) showed increased activations for bottom-up incongruent relative to congruent inputs. Moreover, lIFS activations were increased for physically identical McGurk stimuli, when participants segregated the audiovisual signals and reported their auditory percept. Critically, this activation increase for perceptual segregation was amplified when participants expected audiovisually incongruent signals based on prior sensory experience. Collectively, our results demonstrate that the lIFS combines top-down prior (in)congruency expectations with bottom-up (in)congruency cues to arbitrate between multisensory integration and segregation.

  17. Depth image enhancement using perceptual texture priors

    Science.gov (United States)

    Bang, Duhyeon; Shim, Hyunjung

    2015-03-01

    A depth camera is widely used in various applications because it provides a depth image of the scene in real time. However, due to the limited power consumption, the depth camera presents severe noises, incapable of providing the high quality 3D data. Although the smoothness prior is often employed to subside the depth noise, it discards the geometric details so to degrade the distance resolution and hinder achieving the realism in 3D contents. In this paper, we propose a perceptual-based depth image enhancement technique that automatically recovers the depth details of various textures, using a statistical framework inspired by human mechanism of perceiving surface details by texture priors. We construct the database composed of the high quality normals. Based on the recent studies in human visual perception (HVP), we select the pattern density as a primary feature to classify textures. Upon the classification results, we match and substitute the noisy input normals with high quality normals in the database. As a result, our method provides the high quality depth image preserving the surface details. We expect that our work is effective to enhance the details of depth image from 3D sensors and to provide a high-fidelity virtual reality experience.

  18. Flexibility and Stability of Metal Coordination Macromolecules.

    Science.gov (United States)

    Jiang, Heyan; Geng, Diya; Liu, Dapeng; Lanigan, Nicholas; Wang, Xiaosong

    2017-06-16

    The effect of chain structure on flexibility and stability of macromolecules containing weak P-Fe metal coordination bonds is studied. Migration insertion polymerization (MIP) of FpCX Fp (1) and PR2 CY PR2 (2) (Fp: CpFe(CO)2 ; CX and CY : alkyl spacers; P: phosphine; R: phenyl or isopropyl) generates P(1/2), in which the P-Fe and Fe-P bonds with opposite bonding direction are alternatively arranged in the backbone. On the other hand, P(FpCX P) synthesized from AB-type monomers (FpCX P) has P-Fe bonds arranged in the same direction. P(1/2) is more rigid and stable than P(FpCX P), which is attributed to the chain conformation resulting from the P-Fe bonding direction. In addition, the longer spacers render P(1/2) relatively flexible; the phenyl substituents, as compared with the isopropyl groups, improves the rigidity, thermal, and solution stability of P(1/2). It is therefore possible to incorporate weak metal coordination bonds into macromolecules with improved stability and adjustable flexibility for material processing. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Coordinates of features on the Galilean satellites

    Science.gov (United States)

    Davies, M. E.; Katayama, F. Y.

    1981-09-01

    Control nets of the four Galilean satellites have been established photogrammetrically from pictures taken by the two Voyager spacecraft during their flybys of Jupiter in 1979. Coordinates of 504 points on Io, 112 points on Europa, 1547 points on Ganymede, and 439 points on Callisto are listed. Selected points are identified on U.S. Geological Survey maps of the satellites. Measurements of these points were made on 234 pictures of Io, 115 pictures of Europa, 282 pictures of Ganymede, and 200 pictures of Callisto. The systems of longitude were defined by craters on Europa, Ganymede, and Callisto. Preliminary solutions have been found for the directions of the axes of rotation of the Galilean satellites. New mean radii have been determined as 1815 + or - 5 km for Io, 1569 + or - 10 km for Europa, 2631 + or - 10 km for Ganymede, and 2400 + or - 10 km for Callisto.

  20. Reference analysis of the signal + background model in counting experiments II. Approximate reference prior

    CERN Document Server

    Casadei, Diego

    2014-01-01

    The objective Bayesian treatment of a model representing two independent Poisson processes, labelled as "signal" and "background" and both contributing additively to the total number of counted events, is considered. It is shown that the reference prior for the parameter of interest (the signal intensity) is well approximated by the widely (ab)used flat prior only when the expected background is very high. For a large portion of the background parameters space, a very simple approximation (the asymptotic form of the reference prior for the limit of perfect prior background knowledge) can be safely used. In all cases, this approximation outperforms the uniform prior. When the asymptotic prior is not good enough, a simple 1-parameter fitting function is often sufficient to obtain an objective Bayesian solution. Otherwise, it is shown that a 2-parameters fitting function is able to reproduce the reference prior in all other cases. The latter is also useful to speed-up the computing time, which can be useful in a...

  1. Top-down (Prior Knowledge) and Bottom-up (Perceptual Modality) Influences on Spontaneous Interpersonal Synchronization.

    Science.gov (United States)

    Gipson, Christina L; Gorman, Jamie C; Hessler, Eric E

    2016-04-01

    Coordination with others is such a fundamental part of human activity that it can happen unintentionally. This unintentional coordination can manifest as synchronization and is observed in physical and human systems alike. We investigated the role of top-down influences (prior knowledge of the perceptual modality their partner is using) and bottom-up factors (perceptual modality combination) on spontaneous interpersonal synchronization. We examine this phenomena with respect to two different theoretical perspectives that differently emphasize top-down and bottom-up factors in interpersonal synchronization: joint-action/shared cognition theories and ecological-interactive theories. In an empirical study twelve dyads performed a finger oscillation task while attending to each other's movements through either visual, auditory, or visual and auditory perceptual modalities. Half of the participants were given prior knowledge of their partner's perceptual capabilities for coordinating across these different perceptual modality combinations. We found that the effect of top-down influence depends on the perceptual modality combination between two individuals. When people used the same perceptual modalities, top-down influence resulted in less synchronization and when people used different perceptual modalities, top-down influence resulted in more synchronization. Furthermore, persistence in the change in behavior as a result of having perceptual information about each other ('social memory') was stronger when this top-down influence was present.

  2. COCO: Conversion of Celestial Coordinates

    Science.gov (United States)

    Wallace, Patrick

    2014-06-01

    The COCO program converts star coordinates from one system to another. Both the improved IAU system, post-1976, and the old pre-1976 system are supported. COCO can perform accurate transformations between multiple coordinate systems. COCO's user-interface is spartan but efficient and the program offers control over report resolution. All input is free-format, and defaults are provided where this is meaningful. COCO uses SLALIB (ascl:1403.025) and is distributed as part of the Starlink software collection (ascl:1110.012).

  3. A coordination language for databases

    DEFF Research Database (Denmark)

    Li, Ximeng; Wu, Xi; Lluch Lafuente, Alberto

    2017-01-01

    We present a coordination language for the modeling of distributed database applications. The language, baptized Klaim-DB, borrows the concepts of localities and nets of the coordination language Klaim but re-incarnates the tuple spaces of Klaim as databases. It provides high-level abstractions...... in the semantics. The use of the language is illustrated in a scenario where the sales from different branches of a chain of department stores are aggregated from their local databases. Raising the abstraction level and encapsulating integrity checks in the language primitives have benefited the modeling task...

  4. 7 CFR 22.201 - Coordination.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 1 2010-01-01 2010-01-01 false Coordination. 22.201 Section 22.201 Agriculture Office of the Secretary of Agriculture RURAL DEVELOPMENT COORDINATION Roles and Responsibilities of Federal Government § 22.201 Coordination. The following identifies types and levels of coordination: (a) Washington...

  5. 15 CFR 923.56 - Plan coordination.

    Science.gov (United States)

    2010-01-01

    ... 15 Commerce and Foreign Trade 3 2010-01-01 2010-01-01 false Plan coordination. 923.56 Section 923... COASTAL ZONE MANAGEMENT PROGRAM REGULATIONS Coordination, Public Involvement and National Interest § 923.56 Plan coordination. (a) The management program must be coordinated with local, areawide,...

  6. 40 CFR 109.6 - Coordination.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 21 2010-07-01 2010-07-01 false Coordination. 109.6 Section 109.6..., LOCAL AND REGIONAL OIL REMOVAL CONTINGENCY PLANS § 109.6 Coordination. For the purposes of coordination... coordination of these contingency plans with the National Oil and Hazardous Materials Pollution...

  7. 29 CFR 42.8 - Coordination plan.

    Science.gov (United States)

    2010-07-01

    ... 29 Labor 1 2010-07-01 2010-07-01 true Coordination plan. 42.8 Section 42.8 Labor Office of the Secretary of Labor COORDINATED ENFORCEMENT § 42.8 Coordination plan. (a) Based upon, among other things, the... coordination plan concerning farm labor-related responsibilities of the Department, including migrant housing...

  8. 33 CFR 165.8 - Geographic coordinates.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Geographic coordinates. 165.8... Geographic coordinates. Geographic coordinates expressed in terms of latitude or longitude, or both, are not... 1983 (NAD 83), unless such geographic coordinates are expressly labeled NAD 83. Geographic...

  9. The Convex Coordinates of the Symmedian Point

    Science.gov (United States)

    Boyd, J. N.; Raychowdhury, P. N.

    2006-01-01

    In this note, we recall the convex (or barycentric) coordinates of the points of a closed triangular region. We relate the convex and trilinear coordinates of the interior points of the triangular region. We use the relationship between convex and trilinear coordinates to calculate the convex coordinates of the symmedian point of the triangular…

  10. 78 FR 73819 - Forest Resource Coordinating Committee

    Science.gov (United States)

    2013-12-09

    ... Forest Service Forest Resource Coordinating Committee AGENCY: Forest Service, USDA. ACTION: Notice of...-18, 2013 meeting of the Forest Resource Coordinating Committee due to the Government partial shutdown... INFORMATION CONTACT: Maya Solomon, Forest Resource Coordinating Committee Program Coordinator; by phone at...

  11. State borders in ETRS89 coordinates – reality or fiction ?

    Directory of Open Access Journals (Sweden)

    Jiří Poláček

    2015-12-01

    Full Text Available Common unique ETRS89 coordinates of the state boundaries are crucial for cross-border data harmonization for international projects. In the frame of European Location Framework (ELF project Czech Office for Surveying, Mapping and Cadastre (ČÚZK cooperates with Poland on egde-matching on the state border. During the preliminary phase of the project was some difficulty identified. If the state boundary is measured and administered in the national coordinate system, the accuracy of the transformation into the ETRS89 is influenced by discrepancies of the local trigonometric network, which results in two slightly different state boundaries. Final solution for Europe – international treaties on the state borders based on the ETRS89 coordinates – is necessary, but it will take years.

  12. Can balance trampoline training promote motor coordination and balance performance in children with developmental coordination disorder?

    Science.gov (United States)

    Giagazoglou, Paraskevi; Sidiropoulou, Maria; Mitsiou, Maria; Arabatzi, Fotini; Kellis, Eleftherios

    2015-01-01

    The present study aimed to examine movement difficulties among typically developing 8- to 9-year-old elementary students in Greece and to investigate the possible effects of a balance training program to those children assessed with Developmental Coordination Disorder (DCD). The Body Coordination Test for Children (BCTC; Körperkoordinationstest fur Kinder, KTK, Kiphard & Schilling, 1974) was chosen for the purposes of this study and 20 children out of the total number of 200, exhibited motor difficulties indicating a probable DCD disorder. The 20 students diagnosed with DCD were equally separated into two groups where each individual of the experimental group was paired with an individual of the control group. The intervention group attended a 12-week balance training program while students of the second - control group followed the regular school schedule. All participants were tested prior to the start and after the end of the 12-week period by performing static balance control tasks while standing on an EPS pressure platform and structured observation of trampoline exercises while videotaping. The results indicated that after a 12-week balance training circuit including a trampoline station program, the intervention group improved both factors that were examined. In conclusion, balance training with the use of attractive equipment such as trampoline can be an effective intervention for improving functional outcomes and can be recommended as an alternative mode of physical activity.

  13. Effects of prior stimulus and prior perception on neural correlates of auditory stream segregation.

    Science.gov (United States)

    Snyder, Joel S; Holder, W Trent; Weintraub, David M; Carter, Olivia L; Alain, Claude

    2009-11-01

    We examined whether effects of prior experience are mediated by distinct brain processes from those processing current stimulus features. We recorded event-related potentials (ERPs) during an auditory stream segregation task that presented an adaptation sequence with a small, intermediate, or large frequency separation between low and high tones (Deltaf), followed by a test sequence with intermediate Deltaf. Perception of two streams during the test was facilitated by small prior Deltaf and by prior perception of two streams and was accompanied by more positive ERPs. The scalp topography of these perception-related changes in ERPs was different from that observed for ERP modulations due to increasing the current Deltaf. These results reveal complex interactions between stimulus-driven activity and temporal-context-based processes and suggest a complex set of brain areas involved in modulating perception based on current and previous experience.

  14. Improving semantic scene understanding using prior information

    Science.gov (United States)

    Laddha, Ankit; Hebert, Martial

    2016-05-01

    Perception for ground robot mobility requires automatic generation of descriptions of the robot's surroundings from sensor input (cameras, LADARs, etc.). Effective techniques for scene understanding have been developed, but they are generally purely bottom-up in that they rely entirely on classifying features from the input data based on learned models. In fact, perception systems for ground robots have a lot of information at their disposal from knowledge about the domain and the task. For example, a robot in urban environments might have access to approximate maps that can guide the scene interpretation process. In this paper, we explore practical ways to combine such prior information with state of the art scene understanding approaches.

  15. Theoretical Priors On Modified Growth Parametrisations

    CERN Document Server

    Song, Yong-Seon; Caldera-Cabral, Gabriela; Koyama, Kazuya

    2010-01-01

    Next generation surveys will observe the large-scale structure of the Universe with unprecedented accuracy. This will enable us to test the relationships between matter over-densities, the curvature perturbation and the Newtonian potential. Any large-distance modification of gravity or exotic nature of dark energy modifies these relationships as compared to those predicted in the standard smooth dark energy model based on General Relativity. In linear theory of structure growth such modifications are often parameterised by virtue of two functions of space and time that enter the relation of the curvature perturbation to, first, the matter over-density, and second, the Newtonian potential. We investigate the predictions for these functions in Brans-Dicke theory, clustering dark energy models and interacting dark energy models. We find that each theory has a distinct path in the parameter space of modified growth. Understanding these theoretical priors on the parameterisations of modified growth is essential to...

  16. Care for women with prior preterm birth

    Science.gov (United States)

    Iams, Jay D.; Berghella, Vincenzo

    2013-01-01

    Women who have delivered an infant between 16 and 36 weeks’ gestation have an increased risk of preterm birth in subsequent pregnancies. The risk increases with more than 1 preterm birth and is inversely proportional to the gestational age of the previous preterm birth. African American women have rates of recurrent preterm birth that are nearly twice that of women of other backgrounds. An approximate risk of recurrent preterm birth can be estimated by a comprehensive reproductive history, with emphasis on maternal race, the number and gestational age of prior births, and the sequence of events preceding the index preterm birth. Interventions including smoking cessation, eradication of asymptomatic bacteriuria, progestational agents, and cervical cerclage can reduce the risk of recurrent preterm birth when employed appropriately. PMID:20417491

  17. Sparse Multivariate Modeling: Priors and Applications

    DEFF Research Database (Denmark)

    Henao, Ricardo

    modeling, a model for peptide-protein/protein-protein interactions called latent protein tree, a framework for sparse Gaussian process classification based on active set selection and a linear multi-category sparse classifier specially targeted to gene expression data. The thesis is organized to provide......This thesis presents a collection of statistical models that attempt to take advantage of every piece of prior knowledge available to provide the models with as much structure as possible. The main motivation for introducing these models is interpretability since in practice we want to be able...... to use them as hypothesis generating tools. All of our models start from a family of structures, for instance factor models, directed acyclic graphs, classifiers, etc. Then we let them be selectively sparse as a way to provide them with structural fl exibility and interpretability. Finally, we complement...

  18. Care for women with prior preterm birth.

    Science.gov (United States)

    Iams, Jay D; Berghella, Vincenzo

    2010-08-01

    Women who have delivered an infant between 16 and 36 weeks' gestation have an increased risk of preterm birth in subsequent pregnancies. The risk increases with more than 1 preterm birth and is inversely proportional to the gestational age of the previous preterm birth. African American women have rates of recurrent preterm birth that are nearly twice that of women of other backgrounds. An approximate risk of recurrent preterm birth can be estimated by a comprehensive reproductive history, with emphasis on maternal race, the number and gestational age of prior births, and the sequence of events preceding the index preterm birth. Interventions including smoking cessation, eradication of asymptomatic bacteriuria, progestational agents, and cervical cerclage can reduce the risk of recurrent preterm birth when employed appropriately. Copyright (c) 2010 Mosby, Inc. All rights reserved.

  19. Early medical abortion without prior ultrasound.

    Science.gov (United States)

    Raymond, Elizabeth G; Bracken, Hillary

    2015-09-01

    To explore the potential for using last menstrual period (LMP) rather than ultrasound to establish gestational age (GA) eligibility for medical abortion. We used the results of a recently published systematic review to identify studies with data on the number of abortion patients with GA more than 63 or 70 days by ultrasound but less than those or other specific limits by LMP. We analyzed data from these studies to estimate the proportion of women with GAs greater than 63 or 70 days by ultrasound in various subgroups of women defined by LMP. We found three studies with relevant data. One enrolled 4257 medical abortion patients of whom 4% had GAs of >70 days by ultrasound. Of the 2681 who were certain that their LMPs began no more than 56 days prior, only 16 (0.6%) were >70 days by ultrasound. In a second much smaller study of surgical abortion patients, of whom 19% were >70 days by ultrasound, 90 women were certain that their LMPs started more than 56 days prior, and of those, 7 (7.8%) had GAs of >70 days by ultrasound. In the third study, which included surgical abortion patients with a mean GA of 61 days, at least 12% of the 138 patients with LMPs 70 days by ultrasound. The possibility that access to medical abortion can be enhanced for selected women by omitting the requirement for a screening ultrasound is promising and should be further investigated. Gestational dating using LMP rather than ultrasound may be reasonable for selected patients before medical abortion. Copyright © 2015 Elsevier Inc. All rights reserved.

  20. Solitonic generation of five-dimensional black ring solution

    CERN Document Server

    Iguchi, H; Iguchi, Hideo; Mishima, Takashi

    2006-01-01

    Using the solitonic solution-generating technique we rederived the one-rotational five-dimensional black ring solution found by Emparan and Reall. The seed solution is not the Minkowski metric, which is the seed of $S^2$-rotating black ring. The obtained solution has more parameters than the Emparan and Reall's $S^1$-rotating black ring. We found the conditions of parameters to reduce the solution to the $S^1$-rotating black ring. In addition we examined the relation between the expressions of the metric in the prolate-spheroidal coordinates and in the canonical coordinates.

  1. A static axisymmetric exact solution of f(R)-gravity

    Energy Technology Data Exchange (ETDEWEB)

    Gutierrez-Pineres, Antonio C., E-mail: acgutierrez@correo.nucleares.unam.mx [Facultad de Ciencias Basicas, Universidad Tecnologica de Bolivar, CO 131001 Cartagena de Indias (Colombia); Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico, A.P. 70-543, 04510 Mexico D.F. (Mexico); Lopez-Monsalvo, Cesar S., E-mail: cesar.slm@correo.nucleares.unam.mx [Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico, A.P. 70-543, 04510 Mexico D.F. (Mexico)

    2013-01-29

    We present an exact, axially symmetric, static, vacuum solution for f(R)-gravity in Weyl's canonical coordinates. We obtain a general explicit expression for the dependence of df(R)/dR upon the r and z coordinates and then the corresponding explicit form of f(R), which must be consistent with the field equations. We analyze in detail the modified Schwarzschild solution in prolate spheroidal coordinates. Finally, we study the curvature invariants and show that, in the case of f(R){ne}R, this solution corresponds to a naked singularity.

  2. Coordination Frictions and Job Heterogeneity

    DEFF Research Database (Denmark)

    Kennes, John; le Maire, Christian Daniel

    This paper develops and extends a dynamic, discrete time, job to worker matching model in which jobs are heterogeneous in equilibrium. The key assumptions of this economic environment are (i) matching is directed and (ii) coordination frictions lead to heterogeneous local labor markets. We de- rive...

  3. Terrestrial Coordinate Systems and Frames

    Science.gov (United States)

    Boucher, C.; Murdin, P.

    2000-11-01

    A terrestrial reference system (TRS) is a spatial reference system corotating with the Earth in its DIURNAL MOTION in space. In such a system, the positions of points anchored on the Earth's solid surface have coordinates which have only small variations with time, as a result of geophysical effects (tectonic or tidal deformations; see TECTONICS, EARTH'S INTERIOR, TIDES). A terrestrial reference ...

  4. Archimedes' Principle in General Coordinates

    Science.gov (United States)

    Ridgely, Charles T.

    2010-01-01

    Archimedes' principle is well known to state that a body submerged in a fluid is buoyed up by a force equal to the weight of the fluid displaced by the body. Herein, Archimedes' principle is derived from first principles by using conservation of the stress-energy-momentum tensor in general coordinates. The resulting expression for the force is…

  5. Coordinated Exploration for Grand Challenges

    DEFF Research Database (Denmark)

    Ørding Olsen, Anders; Sofka, Wolfgang; Grimpe, Christoph

    2016-01-01

    on the acceptance and support of important stakeholders. In this study, we suggest that search consortia are more likely to receive funding when they include representatives of stakeholder concerns, so-called advocacy groups. We extend theory on coordinated exploration in joint search by integrating mechanisms from...

  6. Coordinating talk and practical action

    DEFF Research Database (Denmark)

    Oshima, Sae; Streeck, Jürgen

    2015-01-01

    This paper investigates how talk and practical action are coordinated during one type of activity involving professional communication: the service-assessment sequence in hair salons. During this activity, a practical inspection of the haircut must be coupled with sequentially produced verbal act...

  7. Archimedes' Principle in General Coordinates

    Science.gov (United States)

    Ridgely, Charles T.

    2010-01-01

    Archimedes' principle is well known to state that a body submerged in a fluid is buoyed up by a force equal to the weight of the fluid displaced by the body. Herein, Archimedes' principle is derived from first principles by using conservation of the stress-energy-momentum tensor in general coordinates. The resulting expression for the force is…

  8. Coordinating talk and practical action

    DEFF Research Database (Denmark)

    Oshima, Sae; Streeck, Jürgen

    2015-01-01

    . Our analysis of four examples reveals that there is no fixed relationship between the organization of talk and practical action. Instead, people manipulate this relationship on a moment-by-moment basis, often coordinating the two into a single, integral package, or relying on one stream of action...

  9. Early insulin therapy Coordination Council

    Directory of Open Access Journals (Sweden)

    Marina Vladimirovna Shestakova

    2012-12-01

    Full Text Available Coordination Council has denoted the importance of adherence to Russian and international guidelines and prominent role of insulin therapy in management of type 2 diabetes mellitus (T2DM. Insulin therapy in T2DM preserves endogenous insulin secretion, prevents or decelerates development of microvascular complications and is known to be the most effective glucose-lowering treatment.

  10. Submerged Landau jet: exact solutions, their meaning and application

    Energy Technology Data Exchange (ETDEWEB)

    Broman, Goran I [Blekinge Institute of Technology, Karlskrona (Sweden); Rudenko, Oleg V [M. V. Lomonosov Moscow State University, Faculty of Physics, Moscow (Russian Federation)

    2010-01-31

    Exact hydrodynamic solutions generalizing the Landau submerged jet solution are reviewed. It is shown how exact inviscid solutions can be obtained and how boundary layer viscosity can be included by introducing parabolic coordinates. The use of exact solutions in applied hydrodynamics and acoustics is discussed. A historical perspective on the discovery of a class of exact solutions and on the analysis of their physical meaning is presented. (methodological notes)

  11. Equivalence of Network-Solution and PPP-Solution

    Institute of Scientific and Technical Information of China (English)

    PENG Lin; LIU Yanxiong; ZHOU Xinghua; WU Yongting

    2006-01-01

    The technique of precise point positioning (PPP) is gradually becoming a popular method in GPS data-processing. In GPS observation equation, the unknown parameters can be separated into two parts: global parameters and local parameters. The global parameters include orbit, satellite clock and geodynamic parameters. The local parameters are site-occupation-specific, such as position, tropospheric delay, etc. The formulas of local parameters are firstly derived under the network-solution and the PPP-solution conditions respectively. If the weight matrix of global parameters in PPP-solution is small enough, the cofactor matrices of local parameters are the same as that in network-solution. Then, 16 daily solutions are obtained in both PPP mode and network mode. Three sites are selected to compare the solutions. The experimental results demonstrated that the difference between two solutions in coordinates and tropospheric delays are only few millimeters. This level of difference can be neglected so that the solutions from both PPP mode and network mode can be taken as the same in the actual application.

  12. Distributed Sensor Coordination for Advanced Energy Systems

    Energy Technology Data Exchange (ETDEWEB)

    Tumer, Kagan

    2013-07-31

    The ability to collect key system level information is critical to the safe, efficient and reli- able operation of advanced energy systems. With recent advances in sensor development, it is now possible to push some level of decision making directly to computationally sophisticated sensors, rather than wait for data to arrive to a massive centralized location before a decision is made. This type of approach relies on networked sensors (called “agents” from here on) to actively collect and process data, and provide key control deci- sions to significantly improve both the quality/relevance of the collected data and the as- sociating decision making. The technological bottlenecks for such sensor networks stem from a lack of mathematics and algorithms to manage the systems, rather than difficulties associated with building and deploying them. Indeed, traditional sensor coordination strategies do not provide adequate solutions for this problem. Passive data collection methods (e.g., large sensor webs) can scale to large systems, but are generally not suited to highly dynamic environments, such as ad- vanced energy systems, where crucial decisions may need to be reached quickly and lo- cally. Approaches based on local decisions on the other hand cannot guarantee that each agent performing its task (maximize an agent objective) will lead to good network wide solution (maximize a network objective) without invoking cumbersome coordination rou- tines. There is currently a lack of algorithms that will enable self-organization and blend the efficiency of local decision making with the system level guarantees of global decision making, particularly when the systems operate in dynamic and stochastic environments. In this work we addressed this critical gap and provided a comprehensive solution to the problem of sensor coordination to ensure the safe, reliable, and robust operation of advanced energy systems. The differentiating aspect of the proposed work is in shift- ing

  13. Spectra of sodium aluminate solutions

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The UV spectra of sodium aluminate solutions were obtained in the sodium oxide concentration range from 59 to 409 g/L and the caustic ratio range from 1.5 to 4.0 to reveal the structure characteristics of them. It is found that a new peak appears at about 370 nm besides peaks at about 220 and 266 nm in all solutions. The new peak is strongly favored by high hydroxide concentration and high caustic ratio. And it only appears when the solutions are prepared by dissolving sodium hydroxide and aluminum hydroxide.In addition, the IR and Raman spectra of sodium aluminate solutions with high alkali concentration and high caustic ratio were measured, and the UV spectra of aqueous solutions of Al(H2O)63+ and AlF63- were measured as well. According to the crystal field theory in coordination chemistry as well as the above spectra characteristics, this new peak at about 370 nm is determined as the evidence of a new species of aluminate ion with a coordination number of 6.

  14. Collaboration and Coordination in Secondary Networks for Opportunistic Spectrum Access

    CERN Document Server

    Jouini, Wassim; Bononi, Luciano; Moy, Christophe

    2012-01-01

    In this paper, we address the general case of a coordinated secondary network willing to exploit communication opportunities left vacant by a licensed primary network. Since secondary users (SU) usually have no prior knowledge on the environment, they need to learn the availability of each channel through sensing techniques, which however can be prone to detection errors. We argue that cooperation among secondary users can enable efficient learning and coordination mechanisms in order to maximize the spectrum exploitation by SUs, while minimizing the impact on the primary network. To this goal, we provide three novel contributions in this paper. First, we formulate the spectrum selection in secondary networks as an instance of the Multi-Armed Bandit (MAB) problem, and we extend the analysis to the collaboration learning case, in which each SU learns the spectrum occupation, and shares this information with other SUs. We show that collaboration among SUs can mitigate the impact of sensing errors on system perf...

  15. Coordinated standoff tracking of moving targets using differential geometry

    Institute of Scientific and Technical Information of China (English)

    Zhi-qiang SONG; Hua-xiong LI; Chun-lin CHEN; Xian-zhong ZHOU; Feng XU

    2014-01-01

    This research is concerned with coordinated standoff tracking, and a guidance law against a moving target is proposed by using differential geometry. We first present the geometry between the unmanned aircraft (UA) and the target to obtain the convergent solution of standoff tracking when the speed ratio of the UA to the target is larger than one. Then, the convergent solution is used to guide the UA onto the standoff tracking geometry. We propose an improved guidance law by adding a derivative term to the relevant algorithm. To keep the phase angle difference of multiple UAs, we add a second derivative term to the relevant control law. Simulations are done to demonstrate the feasibility and performance of the proposed approach. The proposed algo-rithm can achieve coordinated control of multiple UAs with its simplicity and stability in terms of the standoff distance and phase angle difference.

  16. Studies on the Coordination Polymer of Copper Electropolyurushiol

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The coordination polymer of copper electropolyurushiol(EPU-Cu2+) was obtained by the reaction of copper chloride with electropolyurushiol (EPU) in an isopropyl alcohol solution. The properties of EPU-Cu2+ were studied by means of ESR, FTIR, XPS, DMTA and TG-DTA.The results of AES show that the content of Cu2+ was 8.63%. The electric resistances of EPUCu2+ and EPU were determined to be 9.37×1010Ω and 7.90×1010Ω respectively. It was also ascertained that in EPU-Cu2+ each Cu2+ is coordinated with two units hydroxyl in EPU, making the EPU-Cu2+ cross-link further. As a result, the title polymer exhibits an insolubility in most of organic solutions, a higher glass transition temperature and thermal resistance.

  17. Axially symmetric solutions in f(R)-gravity

    Energy Technology Data Exchange (ETDEWEB)

    Capozziello, Salvatore; De Laurentis, Mariafelicia [Dipartimento di Scienze Fisiche, Universita di Napoli ' Federico II' (Italy); Stabile, Arturo, E-mail: capozziello@na.infn.i [Dipartimento di Ingegneria, Universita del Sannio, Benevento, C.so Garibaldi 107, I-80125 Benevento (Italy)

    2010-08-21

    Axially symmetric solutions for f(R)-gravity can be derived starting from exact spherically symmetric solutions achieved by Noether symmetries. The method takes advantage of a complex coordinate transformation previously developed by Newman and Janis in general relativity. An example is worked out to show the general validity of the approach. The physical properties of the solution are also considered.

  18. Static Solutions of Einstein's Equations with Cylindrical Symmetry

    Science.gov (United States)

    Trendafilova, C. S.; Fulling, S. A.

    2011-01-01

    In analogy with the standard derivation of the Schwarzschild solution, we find all static, cylindrically symmetric solutions of the Einstein field equations for vacuum. These include not only the well-known cone solution, which is locally flat, but others in which the metric coefficients are powers of the radial coordinate and the spacetime is…

  19. Silicon Photodetectors Matrix Coordinate Bipolar Functionally Integrated Structures

    Directory of Open Access Journals (Sweden)

    V.N. Murashev

    2015-03-01

    Full Text Available In this paper a new approach for solving the detection and coordinate the detection of radiation in the optical range of 0.3-1.1 microns, based on the use of so-called bipolar functionally integrated structures (BI-FIS in pixels photodetector arrays is discussed. Variants of new technical solutions based on photo-detectors matrix pixel BI-FIS structures are shown. Their effectiveness and scope are evaluated.

  20. Schwarzschild-de Sitter Metric and Inertial Beltrami Coordinates

    CERN Document Server

    Sun, Li-Feng; Deng, Ya; Huang, Wei; Hu, Sen

    2013-01-01

    Under consideration of coordinate conditions, we get the Schwarzschild-Beltrami-de Sitter (S-BdS) metric solution of the Einstein field equations with a cosmological constant $\\Lambda$. A brief review to the de Sitter invariant special relativity (dS-SR), and de Sitter general relativity (dS-GR, or GR with a $\\Lambda$) is presented. The Beltrami metric $B_{\\mu\

  1. CAMERA: Coordination and Management Environments for Responsive Agents

    Science.gov (United States)

    2005-02-01

    simple solution, the outcome was much better than the pre- existing way of doing business , which involved coordinating the schedules by talking on...a probabilistic model based on statistical mechanics. In our implementation of SA we start by randomly assigning resources to tasks until all...Program: http://www.isi.edu/~szekely/antsebook/ ebook / The e-book was edited by Alejandro Bugacov, Stephen Fitzpatrick, Gabor Karsai, Victor Lesser

  2. Three-dimensional nonparaxial beams in parabolic rotational coordinates.

    Science.gov (United States)

    Deng, Dongmei; Gao, Yuanmei; Zhao, Juanying; Zhang, Peng; Chen, Zhigang

    2013-10-01

    We introduce a class of three-dimensional nonparaxial optical beams found in a parabolic rotational coordinate system. These beams, representing exact solutions of the nonparaxial Helmholtz equation, have inherent parabolic symmetries. Assisted with a computer-generated holography, we experimentally demonstrate the generation of different modes of these beams. The observed transverse beam patterns along the propagation direction agree well with those from our theoretical predication.

  3. Mechanisms that underlie coordination in children with developmental coordination disorder.

    Science.gov (United States)

    O'Brien, Jane Clifford; Williams, Harriet G; Bundy, Anita; Lyons, Jim; Mittal, Amita

    2008-01-01

    The authors examined potential mechanisms underlying motor coordination in children with developmental coordination disorder (DCD). Because children with DCD experience difficulty processing visual, auditory, and vibrotactile information, the authors explored patterns of choice reaction time (RT) in young (6-7 years) and older (9-10 years) children with and without DCD by using a compatibility-incompatibility paradigm and different sensory modalities. Young children responded more slowly than older children to visual, auditory, and vibrotactile stimuli. Children with DCD took longer than typical children to process visual and vibrotactile stimuli under more complex stimulus-response mappings. Young children with DCD responded more slowly than typical children to visual and vibrotactile information under incompatible conditions. Children with DCD responded faster than unaffected children to auditory stimuli. The results suggest that there is a developmental nature in the processing of visual and auditory input and imply that the vibrotactile sensory modality may be key to the motor coordination difficulties of children with DCD.

  4. Automated selection of LEDs by luminance and chromaticity coordinate

    CERN Document Server

    Fischer, Ulrich H P; Reinboth, Christian

    2010-01-01

    The increased use of LEDs for lighting purposes has led to the development of numerous applications requiring a pre-selection of LEDs by their luminance and / or their chromaticity coordinate. This paper demonstrates how a manual pre-selection process can be realized using a relatively simple configuration. Since a manual selection service can only be commercially viable as long as only small quantities of LEDs need to be sorted, an automated solution suggests itself. This paper introduces such a solution, which has been developed by Harzoptics in close cooperation with Rundfunk Gernrode. The paper also discusses current challenges in measurement technology as well as market trends.

  5. Units Coordination and the Construction of Improper Fractions: A Revision of the Splitting Hypothesis

    Science.gov (United States)

    Hackenberg, Amy J.

    2007-01-01

    This article communicates findings from a year-long constructivist teaching experiment about the relationship between four sixth-grade students' multiplicative structures and their construction of improper fractions. Students' multiplicative structures are the units coordinations that they can take as given prior to activity--i.e., the units…

  6. Glutathione-coordinated [2Fe-2S] cluster is stabilized by intramolecular salt bridges.

    Science.gov (United States)

    Li, Jingwei; Pearson, Stephen A; Fenk, Kevin D; Cowan, J A

    2015-12-01

    Halide salts of alkali and alkaline earth metals were used to probe the contributions of intramolecular salt bridge formation on the stability of glutathione-coordinated [2Fe-2S] cluster toward hydrolysis. The effect of ionic strength on cluster stability was quantitatively investigated by application of Debye-Hückel theory to the rates of hydrolysis. Results from this study demonstrate that ionic strength influences the stability of the cluster, with the rate of cluster degradation depending on the charge density, hydrated ionic radius, and hydration energy. The identity of the salt ions was also observed to be correlated with the binding affinity toward the cluster. Based on the modified Debye-Hückel equation and counterion screening effect, these results suggest that interactions between glutathione molecules in the [2Fe-2S](GS)4 cluster is via salt bridges, in agreement with our previous results where modifications of glutathione carboxylates and amines prevented solution aggregation and cluster formation. These results not only provide a rationale for the stability of such clusters under physiological conditions, but also suggest that the formation of glutathione-complexed [2Fe-2S] cluster from a glutathione tetramer may be facilitated by salt bridge interactions between glutathione molecules prior to cluster assembly, in a manner consistent with Nature's equivalent of dynamic combinatorial chemistry.

  7. Digitisation of prior screening mammograms. Norwegian Breast Cancer Screening Program Troms and Finnmark

    Energy Technology Data Exchange (ETDEWEB)

    Pedersen, K.; Johansen, S.; Roenning, F.; Stormo, S.; Bjurstam, N.

    2004-07-01

    In the coming years a transition from analogue to digital imaging technology will take place in the Norwegian Breast Cancer Screening Program (NBCSP).This will make softcopy reading of images possible. However, one will also wish to compare new (digital) images with prior images on film. This can be solved in different ways. This report contains a brief description of different alternatives. The solution chosen in Troms and Finnmark, digitisation of prior images, is then described in detail. Both technical and economical aspects are covered. (Author)

  8. Solving Einstein's Equations With Dual Coordinate Frames

    CERN Document Server

    Scheel, M A; Lindblom, L; Pfeiffer, H P; Rinne, O; Teukolsky, S A; Kidder, Lawrence E.; Lindblom, Lee; Pfeiffer, Harald P.; Rinne, Oliver; Scheel, Mark A.; Teukolsky, Saul A.

    2006-01-01

    A method is introduced for solving Einstein's equations using two distinct coordinate systems. The coordinate basis vectors associated with one system are used to project out components of the metric and other fields, in analogy with the way fields are projected onto an orthonormal tetrad basis. These field components are then determined as functions of a second independent coordinate system. The transformation to the second coordinate system can be thought of as a mapping from the original ``inertial'' coordinate system to the computational domain. This dual-coordinate method is used to perform stable numerical evolutions of a black-hole spacetime using the generalized harmonic form of Einstein's equations in coordinates that rotate with respect to the inertial frame at infinity; such evolutions are found to be generically unstable using a single rotating coordinate frame. The dual-coordinate method is also used here to evolve binary black-hole spacetimes for several orbits. The great flexibility of this met...

  9. Wave Solutions

    CERN Document Server

    Christov, Ivan C

    2012-01-01

    In classical continuum physics, a wave is a mechanical disturbance. Whether the disturbance is stationary or traveling and whether it is caused by the motion of atoms and molecules or the vibration of a lattice structure, a wave can be understood as a specific type of solution of an appropriate mathematical equation modeling the underlying physics. Typical models consist of partial differential equations that exhibit certain general properties, e.g., hyperbolicity. This, in turn, leads to the possibility of wave solutions. Various analytical techniques (integral transforms, complex variables, reduction to ordinary differential equations, etc.) are available to find wave solutions of linear partial differential equations. Furthermore, linear hyperbolic equations with higher-order derivatives provide the mathematical underpinning of the phenomenon of dispersion, i.e., the dependence of a wave's phase speed on its wavenumber. For systems of nonlinear first-order hyperbolic equations, there also exists a general ...

  10. Managing Coordinator, Educational or Entrepreneurial Coordinator: Course Coordinator Profile Analysis at Private HEIS

    Directory of Open Access Journals (Sweden)

    Mariana Augusta de Araújo Silva

    2014-12-01

    Full Text Available Higher Education dynamics is impacted by political, economic and financial interference. In parallel, the Ministry of Education and Culture (MEC is strict in its reviews to ensure Brazilian higher education is appreciated and promoted. The purpose of this study is to identify the profile of Course Coordinators and factors that might improve, at the surveyed HEIs, this professional´s relationship with students, teaching staff and Directors. Literature was searched and reviewed so as to collect subject matter pertaining issues. A quantitative research approach was employed and objectives were of exploratory descriptive nature since this technique ensures extended comprehension of the investigated phenomenon, whilst data was gathered via personal interviews. The object of investigation comprised all Course Coordinators of the Estácio/Natal Group in Brazil´s four units. The survey´s tool comprises: 13 closed questions to identify the Coordinator´s profile; 17 questions with a 5 point Likert score scale to identify the entrepreneurial profile; 42 also resorting to a 5 point Likert score scale to measure the dimensions of the Coordinator´s activities and 4 open, optional questions to measure difficulties and possibilities that impact the development of an entrepreneurial course management approach. The study employed both a statistical method (data analysis and descriptive statistics. Findings lead to the conclusion that information and knowledge gathered support researched HEIs in their overcoming of challenges, amongst which encouraging strategic course management and innovation, focused on implementing a new vision of the Course Coordinator, as professionals that master how to balance management and pedagogical skills, whilst innovating by resorting to entrepreneurial competencies.

  11. Prior muscular exercise affects cycling pattern.

    Science.gov (United States)

    Bieuzen, F; Hausswirth, C; Couturier, A; Brisswalter, J

    2008-05-01

    The aim of this study was to investigate the effect of concentric or eccentric fatiguing exercise on cycling pattern. Eleven well trained cyclists completed three sessions of cycling (control cycling test [CTRL], cycling following concentric [CC] or eccentric [ECC] knee contractions) at a mean power of 276.8 +/- 26.6 Watts. Concentric and eccentric knee contractions were performed at a load corresponding to 80 % of one repetition maximum with both legs. Before and after CTRL, CC or ECC knee contractions and after cycling, a maximal voluntary contraction (MVC) test was performed. Cardiorespiratory, mechanical and electromyographic activity (EMG) of the rectus femoris, vastus lateralis and biceps femoris muscles were recorded during cycling. A significant decrease in MVC values was observed after CC and ECC exercises and after the cycling. ECC exercise induced a significant decrease in EMG root mean square during MVC and a decrease in pedal rate during cycling. EMG values of the three muscles were significantly higher during cycling exercise following CC exercise when compared to CTRL. The main finding of this study was that a prior ECC exercise induces a greater neuromuscular fatigue than a CC exercise, and changes in cycling pattern.

  12. Prior expectations facilitate metacognition for perceptual decision.

    Science.gov (United States)

    Sherman, M T; Seth, A K; Barrett, A B; Kanai, R

    2015-09-01

    The influential framework of 'predictive processing' suggests that prior probabilistic expectations influence, or even constitute, perceptual contents. This notion is evidenced by the facilitation of low-level perceptual processing by expectations. However, whether expectations can facilitate high-level components of perception remains unclear. We addressed this question by considering the influence of expectations on perceptual metacognition. To isolate the effects of expectation from those of attention we used a novel factorial design: expectation was manipulated by changing the probability that a Gabor target would be presented; attention was manipulated by instructing participants to perform or ignore a concurrent visual search task. We found that, independently of attention, metacognition improved when yes/no responses were congruent with expectations of target presence/absence. Results were modeled under a novel Bayesian signal detection theoretic framework which integrates bottom-up signal propagation with top-down influences, to provide a unified description of the mechanisms underlying perceptual decision and metacognition. Copyright © 2015 Elsevier Inc. All rights reserved.

  13. Seismicity prior to the 2016 Kumamoto earthquakes

    CERN Document Server

    Nanjo, K Z; Orihara, Y; Furuse, N; Togo, S; Nitta, H; Okada, T; Tanaka, R; Kamogawa, M; Nagao, T

    2016-01-01

    The 2016 Kumamoto earthquakes occurred under circumstance that seismicity remains high in all parts of Japan since the 2011 Tohoku-Oki earthquake. Identifying what happened before this incident is one starting point for promote earthquake forecast research to prepare for subsequent large earthquakes in the near future in Japan. Here we report precursory seismic patterns prior to the Kumamoto earthquakes, measured by four different methods based on seismicity changes that can be used for earthquake forecasting: b-value method, two kinds of seismic quiescence evaluation methods, and a method of detailed foreshock evaluation. The spatial extent of precursory patterns differs from one method to the other and ranges from local scales (typically asperity size), to regional scales (e.g., 2{\\deg} x 3{\\deg} around the source zone). The earthquakes are preceded by periods of pronounced anomalies, which lasted decade scales (e.g., 20 years or longer) to yearly scales (e.g., 1~2 years). We demonstrate that combination of...

  14. Cathodic ARC surface cleaning prior to brazing

    Energy Technology Data Exchange (ETDEWEB)

    Dave, V. R. (Vivek R.); Hollis, K. J. (Kendall J.); Castro, R. G. (Richard G.); Smith, F. M. (Frank M.); Javernick, D. A. (Daniel A.)

    2002-01-01

    Surface cleanliness is one the critical process variables in vacuum furnace brazing operations. For a large number of metallic components, cleaning is usually accomplished either by water-based alkali cleaning, but may also involve acid etching or solvent cleaning / rinsing. Nickel plating may also be necessary to ensure proper wetting. All of these cleaning or plating technologies have associated waste disposal issues, and this article explores an alternative cleaning process that generates minimal waste. Cathodic arc, or reserve polarity, is well known for welding of materials with tenacious oxide layers such as aluminum alloys. In this work the reverse polarity effect is used to clean austenitic stainless steel substrates prior to brazing with Ag-28%Cu. This cleaning process is compared to acid pickling and is shown to produce similar wetting behavior as measured by dynamic contact angle experiments. Additionally, dynamic contact angle measurements with water drops are conducted to show that cathodic arc cleaning can remove organic contaminants as well. The process does have its limitations however, and alloys with high titanium and aluminum content such as nickel-based superalloys may still require plating to ensure adequate wetting.

  15. Human papilloma virus infection prior to coitarche.

    Science.gov (United States)

    Doerfler, Daniela; Bernhaus, Astrid; Kottmel, Andrea; Sam, Christine; Koelle, Dieter; Joura, Elmar A

    2009-05-01

    The aim of our study was to determine the prevalence and the natural course of anogenital human papilloma virus (HPV) infections in girls prior to coitarche attending an outpatient gynecological unit. Specimens were taken from the anogenital region of 114 unselected 4-15 year old girls who were referred consecutively for various gynecological problems. Four girls were excluded because of sexual abuse. Low-risk HPV-deoxyribonucleic acid (DNA) was detected in 4 girls (3.6%) and high-risk HPV DNA in 15 children (13.6%). Two girls testing positive for HPV DNA had clinical apparent warts. After 1 year, 2 children had persistent high-risk HPV DNA, and in 1 case we found a switch from high-risk to low-risk HPV DNA. Subclinical genital low- and high-risk HPV infections are common in girls without any history of sexual abuse or sexual activity. We found persistence of genital HPV infection in children, which could be a reservoir for HPV-associated diseases later in life.

  16. Investigations on organozinc compounds XII. Coordination chemistry of organozinc compounds RZnX: Organozinc compounds of the type EtZnNPhCSZ

    NARCIS (Netherlands)

    Boersma, J.; Noltes, J.G.

    1969-01-01

    The coordination chemistry of the organozinc-nitrogen compounds EtZnNPhCSZ (Z = H, Me, OMe, SMe and NPh2) has been studied. Whereas the benzeneinsoluble EtZnNPhCSH appears to be a coordination polymer, all the other compounds occur as dimers in benzene solution. A structure with four-coordinate zinc

  17. Investigations on organozinc compounds XII. Coordination chemistry of organozinc compounds RZnX: Organozinc compounds of the type EtZnNPhCSZ

    NARCIS (Netherlands)

    Boersma, J.; Noltes, J.G.

    The coordination chemistry of the organozinc-nitrogen compounds EtZnNPhCSZ (Z = H, Me, OMe, SMe and NPh2) has been studied. Whereas the benzeneinsoluble EtZnNPhCSH appears to be a coordination polymer, all the other compounds occur as dimers in benzene solution. A structure with four-coordinate zinc

  18. Solution Prototype

    DEFF Research Database (Denmark)

    Efeoglu, Arkin; Møller, Charles; Serie, Michel

    2013-01-01

    This paper outlines an artifact building and evaluation proposal. Design Science Research (DSR) studies usually consider encapsulated artifact that have relationships with other artifacts. The solution prototype as a composed artifact demands for a more comprehensive consideration in its systematic...... environment. The solution prototype that is composed from blending product and service prototype has particular impacts on the dualism of DSR’s “Build” and “Evaluate”. Since the mix between product and service prototyping can be varied, there is a demand for a more agile and iterative framework. Van de Ven...

  19. Supply chain coordination : A case study of supply chain coordination in practice among one TPL provider and two customers

    OpenAIRE

    Yang, Tuo; Chen, Bo

    2013-01-01

    Introduction: The last decade of the twentieth century witnessed radical changes for a variety of organizations especially in the business field. SCM has become the focus of attention from the business world. As the global competition intensifies, many compa-nies pursue solutions to increase their competitive advantages via SCM approaches. However, studies often overlook the customer perspective in supply chain coordination context. As an attempt to bridge the gap, the research is primarily f...

  20. Supply Chain Reorganization and Coordination

    Institute of Scientific and Technical Information of China (English)

    WANG Feng-bin

    2001-01-01

    Three generic forms of governance--hierarchy, hybrid and market are proposed in the newinstitutional economics, giving an abstract description of alternative coordination and control mechanisms forgeneral use. While this theory is known as far away from being operational and specified, a few researchersin the management and organization area are trying to extend Galbraith and/or Mintzberg's organizationaldesign theories into the application of logistical coordination for obtaining a smooth flow of products along thesupply chain within and without the focal organization. In this paper, we present an explorative case study onthe design of various organizational architectures of logistics activities and their relevant coordinationmechanisms, especially internal and external contracts as one new kind of hybrid mechanisms forcoordinating effective supply chains.

  1. [Transplant coordinator: organ donation process].

    Science.gov (United States)

    Gironés-Guillem, Purificación; Camaño-Puig, Ramón; Lillo-Crespo, Manuel

    2014-01-01

    Spain is a leader in organ donations although it seems that this number does not increase in the same proportion that the waiting list and it is necessary to decrease the refusal situations, which are ~16%. Analytic study. We review the reports prepared by the coordinators of transplants archived at the hospital La Fe during the period between May 1, 2004 and December 31, 2007, resulting in conceptualization and categorization. Sixty-nine topics were obtained from the point of view of the family and 11 from the point of view of the interviewer. After its conceptualization, codification and classification, we proceeded to create an appropriate text. Certain guidelines may be offered that allow us to standardize the action of transplant coordinators during the interview and to be more effective.

  2. Porphyrin coordination polymer nanospheres and nanorods

    Science.gov (United States)

    Wang, Zhongchun; Shelnutt, John A.; Medforth, Craig J.

    2012-12-04

    A porphyrin coordination polymer nanostructure comprising a network of pyridyl porphyrin molecules and coordinating metal ions coordinatively bound through the pyridyl groups. In some embodiments, the porphyrins are metalloporphyrins. A variety of nanostructures are formed by the network polymer, including nanospheres, polygonal nanostructures, nanorods, and nanofibers, depending on a variety of factors including coordination metal ion, porphyrin type, metal of the metalloporphyrin, and degree of agitation during nanostructure formation. Reduction of coordinating metal ions may be used to form metal nanoparticles on the coordination polymer nanostructure.

  3. Porphyrin coordination polymer nanospheres and nanorods

    Science.gov (United States)

    Wang, Zhongchun; Shelnutt, John A.; Medforth, Craig J.

    2013-09-10

    A porphyrin coordination polymer nanostructure comprising a network of pyridyl porphyrin molecules and coordinating metal ions coordinatively bound through the pyridyl groups. In some embodiments, the porphyrins are metalloporphyrins. A variety of nanostructures are formed by the network polymer, including nanospheres, polygonal nanostructures, nanorods, and nanofibers, depending on a variety of factors including coordination metal ion, porphyrin type, metal of the metalloporphyrin, and degree of agitation during nanostructure formation. Reduction of coordinating metal ions may be used to form metal nanoparticles on the coordination polymer nanostructure.

  4. Resolution enhancement in tilted coordinates

    Science.gov (United States)

    Hariri Naghadeh, Diako; Keith Morley, Christopher

    2016-11-01

    Deconvolution is applied to remove source wavelet effects from seismograms. The results are resolution enhancement that enables detection of thin layers. Following enhancement of resolution, low frequency and high angle reflectors, particularly at great depth, appear as low amplitude and semi-invisible reflectors that are difficult to track and pick. A new approach to enhance resolution is introduced that estimates a derivative using continuous wavelet transform in tilted coordinates. The results are compared with sparse spike deconvolution, curvelet deconvolution and inverse quality filtering in wavelet domain. The positive consequence of the new method is to increase sampling of high dip features by changing the coordinate system from Cartesian to tilted. To compare those methods a complex data set was chosen that includes high angle faults and chaotic mass transport complex. Image enhancement using curvelet deconvolution shows a chaotic system as a non-chaotic one. The results show that sparse spike deconvolution and inverse quality filtering in wavelet domain are able to enhance resolution more than curvelet deconvolution especially at great depth but it is impossible to follow steep dip reflectors after resolution enhancement using these methods, especially when their apparent dips are more than 45°. By estimating derivatives in a continuous wavelet transform from tilted data sets similar resolution enhancement as the other deconvolution methods is achieved but additionally steep dipping reflectors are imaged much better than others. Subtracted results of the enhanced resolution data set using new method and the other introduced methods show that steeply dipping reflectors are highlighted as a particular ability of the new method. The results show that high frequency recovery in Cartesian co-ordinate is accompanied by inability to image steeply dipping reflectors especially at great depths. Conversely recovery of high frequency data and imaging of the data

  5. DEVELOPMENTAL COORDINATION DISORDER IN CHILDREN

    Directory of Open Access Journals (Sweden)

    Saeideh MIRAFKHAMI

    2010-04-01

    Full Text Available ObjectiveIn this article, a motor skill disorder called developmental coordination disorder (DCD, that is usually first diagnosed during childhood, is explained and discussed. In the year 1987, DCD was formally recognized as a distinct disorder in children by the American Psychiatric Association  (APA. DCD is a generalized term for the children who have some degrees of impairment in the development of motor coordination and therefore have difficulties with physical skills which significantly interfere with their academic achievements and /or performing everyday activities. As they develop, other age-related tasks are also below average. Because these impairment & conditions are often associated with emotional distress, they can seriously interfere with the person's everyday life and social relationships. Reviews indicate that most of the training rocedures have only a limited effect on the development of general coordination, and that they have no effect at all on academic progress.This includes approaches based on assumed underlying deficiencies such as sensory integration deficits and kinesthetic functioning deficits, as well as the more traditional perceptual - motor training. One new approach is Cognitive Orientation to daily Occupational Performance (CO-OP, based on problem - solving strategies and guided discovery of the child and task specific strategies. The aim of this article was to inform, promote and disseminate more information about some difficulties in applying the diagnostic criteria for DCD. Also, a brief review of the researches on the intervention methods is presented.Keywords: Developmental coordination disorder, Motor skills disorder, Childhood disorder, Intervention methods

  6. Coordination strategies of crew management

    Science.gov (United States)

    Conley, Sharon; Cano, Yvonne; Bryant, Don

    1991-01-01

    An exploratory study that describes and contrasts two three-person flight crews performing in a B-727 simulator is presented. This study specifically attempts to delineate crew communication patterns accounting for measured differences in performance across routine and nonroutine flight patterns. The communication patterns in the two crews evaluated indicated different modes of coordination, i.e., standardization in the less effective crew and planning/mutual adjustment in the more effective crew.

  7. Coordination strategies of crew management

    Science.gov (United States)

    Conley, Sharon; Cano, Yvonne; Bryant, Don

    1991-01-01

    An exploratory study that describes and contrasts two three-person flight crews performing in a B-727 simulator is presented. This study specifically attempts to delineate crew communication patterns accounting for measured differences in performance across routine and nonroutine flight patterns. The communication patterns in the two crews evaluated indicated different modes of coordination, i.e., standardization in the less effective crew and planning/mutual adjustment in the more effective crew.

  8. Coordinate unsaturation with fluorinated ligands

    Energy Technology Data Exchange (ETDEWEB)

    Rack, J.L.; Hurlburt, P.K.; Anderson, O.P.; Strauss, S.H. [Colorado State Univ., Ft. Collins, CO (United States)

    1993-12-31

    The preparation and characterization of Zn(OTeF{sub 5}){sub 2} has resulted in a model compound with which to explore the concept of coordinative unsaturation. The coordination of solvents of varying donicity and dielectric constant to the Zn(II) ions in Zn(OTeF{sub 5}){sub 2} was studied by vapor phase monometry, NMR and IR spectroscopy, conductimetry, and X-Ray crystallography. The structures of [Zn(C{sub 6}H{sub 5}NO{sub 2}){sub 2}(OTeF{sub 5})2]2 and Zn(C{sub 6}H{sub 5}NO{sub 2}){sub 3}(OTEF{sub 5}){sub 2} demonstrate the electronic flexibility of some weakly coordinating solvents in that nitrobenzene can function as either an {eta}{sup 1}O or {eta}{sup 2}O,O`-ligand. The dependence of the number of bound solvent molecules and the degree of OTeF{sub 5}{minus} dissociation on solvent donor number and dielectric constant will be presented.

  9. DEVELOPMENTAL COORDINATION DISORDER IN CHILDREN

    Directory of Open Access Journals (Sweden)

    Saeideh MIRAFKHAMI

    2010-03-01

    Full Text Available ObjectiveIn this article, a motor skill disorder called developmental coordination disorder (DCD, that is usually first diagnosed during childhood, is explained and discussed. In the year 1987, DCD was formally recognized as a distinct disorder in children by the American Psychiatric Association (APA. DCD is a generalized term for the children who have some degrees of impairment in the development of motor coordination and therefore have difficulties with physical skills which significantly interfere with their academic achievements and /or performing everyday activities. As they develop, other age-related tasks are also below average. Because these impairment & conditions are often associated with emotional distress, they can seriously interfere with the person's everyday life and social relationships. Reviews indicate that most of the training rocedures have only a limited effect on the development of general coordination, and that they have no effect at all on academic progress.This includes approaches based on assumed underlying deficiencies such as sensory integration deficits and kinesthetic functioning deficits, as well as the more traditional perceptual - motor training. One new approach is Cognitive Orientation to daily Occupational Performance (CO-OP, based on problem - solving strategies and guided discovery of the child and task specific strategies. The aim of this article was to inform, promote and disseminate more information about some difficulties in applying the diagnostic criteria for DCD. Also, a brief review of the researches on the intervention methods is presented.

  10. Podcast solutions

    CERN Document Server

    Geoghegan, Michael W

    2005-01-01

    Podcasting is the art of recording radio show style audio tracks, then distributing them to listeners on the Web via podcasting software such as iPodder. From downloading podcasts to producing a track for fun or profit, ""Podcast Solutions"" covers the entire world of podcasting with insight, humor, and the unmatched wisdom of experience.

  11. Soil Solution

    NARCIS (Netherlands)

    Sonneveld, C.; Voogt, W.

    2009-01-01

    The characteristics of the soil solution in the root environment in the greenhouse industry differ much from those for field grown crops. This is caused firstly by the growing conditions in the greenhouse, which strongly differ from those in the field and secondly the function attributed to the soil

  12. PACSPLUS Solutions

    Directory of Open Access Journals (Sweden)

    Reza A Zoroofi

    2007-08-01

    Full Text Available Medal Electronic (ME Engineering Company provides high quality systems, software and services in medical image management, processing and visualization. We assist health care professionals to improve and extend the efficiency of their practices with cost effective solutions. ME is the developer of several medical software including MEDAL-PACS, 3D-Sonosoft, Analytical-Electrophoresis, CBONE and Rhino-Plus. ME is also the exclusive distributor of PACSPLUS in Iran. PACSPLUS is an international, standard, scalable and enterprise PACS solution. PACSPLUS is of ISO, CE and FDA-510 approvals. It is now operational in more than 1000 clinical environment throughout the globe. We discuss about the key features of PACSPLUS system for dealing with real world challenge in PACS as well as the PACS solu-tions needed to fulfill the demands of the clinicians in Iran. Our experience in developing high-end medical software confirms our capability in providing the PACSPLUS as an ultimate PACS solution in Iran.

  13. Plugging solution

    Energy Technology Data Exchange (ETDEWEB)

    Tomashevskiy, L.P.; Boldin, V.M.; Borovikov, P.A.; Fedorova, G.G.; Koshelova, I.F.; Krivoshchekova, N.P.; Prokhorevich, L.D.; Prudnikova, N.N.; Vin, L.R.

    1982-01-01

    This solution is designed to quickly harden in a cool environment. Phenoformaldyhyde tar is used as a hardening agent along with a modified diethyleneglycol in the amounts of (part by weight): phenoformaldyhyde tar and diethyleneglycol=1oo; acidic hardener=8-16; water=2-4.

  14. Green Solutions

    Institute of Scientific and Technical Information of China (English)

    LU LING

    2010-01-01

    @@ World Expo's China Pavilion is a large crimson building,but it's green at heart.The pavilion,a magnificent symbol of Chinese culture,is also a "green landmark" on the world stage,thanks to German company Siemens' energy-saving solutions.

  15. Interdisciplinarity and the Prior Knowledge Profile Examination

    Directory of Open Access Journals (Sweden)

    Carmen Oñate Gómez

    2009-05-01

    Full Text Available This article presents an activity that has been for years a common assignment for professors and students at the beginning of the school year at the Technical University of Madrid (UPM, for its acronym in Spanish Universidad Politécnica de Madrid: the Knowledge Profile Examination. Among the many variables this examination has, interdisciplinarity is one of the most significant ones. This remarkable meta-cognitive variable, which urgently needs to be studied, researched, solved and qualified, undoubtedly provides the best contributions to the quantity-quality intricacy of knowledge. The solution of the most important pedagogical issues in the coming years depends on it, when the development of a more humane, useful and responsible knowledge at universities is aimed.

  16. Scaling relations for galaxies prior to reionization

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Pengfei; Norman, Michael L.; Xu, Hao [CASS, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093 (United States); Wise, John H. [Center for Relativistic Astrophysics, School of Physics, Georgia Institute of Technology, 837 State Street, Atlanta, GA 30332 (United States); O' Shea, Brian W., E-mail: pec008@ucsd.edu, E-mail: mlnorman@ucsd.edu, E-mail: hxu@ucsd.edu, E-mail: jwise@gatech.edu, E-mail: oshea@msu.edu [Lyman Briggs College and Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States)

    2014-11-10

    The first galaxies in the universe are the building blocks of all observed galaxies. We present scaling relations for galaxies forming at redshifts z ≥ 15 when reionization is just beginning. We utilize the 'Rarepeak' cosmological radiation hydrodynamics simulation that captures the complete star formation history in over 3300 galaxies, starting with massive Population III stars that form in dark matter halos as small as ∼10{sup 6} M {sub ☉}. We make various correlations between the bulk halo quantities, such as virial, gas, and stellar masses and metallicities and their respective accretion rates, quantifying a variety of properties of the first galaxies up to halo masses of 10{sup 9} M {sub ☉}. Galaxy formation is not solely relegated to atomic cooling halos with virial temperatures greater than 10{sup 4} K, where we find a dichotomy in galaxy properties between halos above and below this critical mass scale. Halos below the atomic cooling limit have a stellar mass-halo mass relationship log M {sub *} ≅ 3.5 + 1.3log (M {sub vir}/10{sup 7} M {sub ☉}). We find a non-monotonic relationship between metallicity and halo mass for the smallest galaxies. Their initial star formation events enrich the interstellar medium and subsequent star formation to a median of 10{sup –2} Z {sub ☉} and 10{sup –1.5} Z {sub ☉}, respectively, in halos of total mass 10{sup 7} M {sub ☉}, which is then diluted by metal-poor inflows well beyond Population III pre-enrichment levels of 10{sup –3.5} Z {sub ☉}. The scaling relations presented here can be employed in models of reionization, galaxy formation, and chemical evolution in order to consider these galaxies forming prior to reionization.

  17. Directional interactions between current and prior saccades

    Directory of Open Access Journals (Sweden)

    Stephanie Anne Holland Jones

    2014-10-01

    Full Text Available One way to explore how prior sensory and motor events impact eye movements is to ask someone to look to targets located about a central point, returning gaze to the central point after each eye movement. Concerned about the contribution of this return to centre movement, Anderson et al. (2008 used a sequential saccade paradigm in which participants made a continuous series of saccades to peripheral targets that appeared to the left or right of the currently fixated location in a random sequence (the next eye movement began from the last target location. Examining the effects of previous saccades (n-x on current saccade latency (n, they found that saccadic reaction times (RT were reduced when the direction of the current saccade matched that of a preceding saccade (e.g. two left saccades, even when the two saccades in question were separated by multiple saccades in any direction. We examined if this pattern extends to conditions in which targets appear inside continuously marked locations that provide stable visual features (i.e. target ‘placeholders’ and when saccades are prompted by central arrows. Participants completed 3 conditions: peripheral targets (PT; continuous, sequential saccades to peripherally presented targets without placeholders; PT with placeholders; and centrally presented arrows (CA; left or right pointing arrows at the currently fixated location instructing participants to saccade to the left or right. We found reduced saccadic RT when the immediately preceding saccade (n-1 was in the same (vs. opposite direction in the PT without placeholders and CA conditions. This effect varied when considering the effect of the previous 2-5 (n-x saccades on current saccade latency (n. The effects of previous eye movements on current saccade latency may be determined by multiple, time-varying mechanisms related to sensory (i.e., retinotopic location, motor (i.e., saccade direction, and environmental (i.e., persistent visual objects

  18. SIPPI: A Matlab toolbox for sampling the solution to inverse problems with complex prior information

    DEFF Research Database (Denmark)

    Hansen, Thomas Mejer; Cordua, Knud Skou; Looms, Majken Caroline

    2013-01-01

    We present an application of the SIPPI Matlab toolbox, to obtain a sample from the a posteriori probability density function for the classical tomographic inversion problem. We consider a number of different forward models, linear and non-linear, such as ray based forward models that rely...... on the high frequency approximation of the wave-equation and ‘fat’ ray based forward models relying on finite frequency theory. In order to sample the a posteriori probability density function we make use of both least squares based inversion, for linear Gaussian inverse problems, and the extended Metropolis...... sampler, for non-linear non-Gaussian inverse problems. To illustrate the applicability of the SIPPI toolbox to a tomographic field data set we use a cross-borehole traveltime data set from Arrenæs, Denmark. Both the computer code and the data are released in the public domain using open source and open...

  19. SIPPI: A Matlab toolbox for sampling the solution to inverse problems with complex prior information

    DEFF Research Database (Denmark)

    Hansen, Thomas Mejer; Cordua, Knud Skou; Caroline Looms, Majken

    2013-01-01

    for solving such probabilistically formulated inverse problems by sampling the a posteriori probability density function. In order to describe the a priori probability density function, we consider both simple Gaussian models and more complex (and realistic) a priori models based on higher order statistics....... These a priori models can be used with both linear and non-linear inverse problems. For linear inverse Gaussian problems we make use of least-squares and kriging-based methods to describe the a posteriori probability density function directly. For general non-linear (i.e. non-Gaussian) inverse problems, we make...... use of the extended Metropolis algorithm to sample the a posteriori probability density function. Together with the extended Metropolis algorithm, we use sequential Gibbs sampling that allow computationally efficient sampling of complex a priori models. The toolbox can be applied to any inverse...

  20. Coordination Nature of 4-Mercaptoaniline to Sn(II Ion: Formation of a One Dimensional Coordination Polymer and Its Decomposition to a Mono Nuclear Sn(IV Complex

    Directory of Open Access Journals (Sweden)

    Eon S. Burkett

    2014-12-01

    Full Text Available The coordination of the bifunctional ligand 4-mercaptoaniline with aqueo us tin(II metal ion was studied. A coordination polymer was synthesized when an aqueous solution of SnCl2 was treated with 4-MA. The crystalline material is stable under atmospheric conditions retaining its oxidation state. However, when submerged in a solution saturated with oxygen, the compound oxidizes to a mononuclear tin(IV complex. Both the compounds were characterized by single crystal X-ray diffraction studies. Although the structure of the tin(IV complex was previously reported, crystal structure of this compound was redetermined.

  1. Electronic palliative care coordination systems: Devising and testing a methodology for evaluating documentation.

    Science.gov (United States)

    Allsop, Matthew J; Kite, Suzanne; McDermott, Sarah; Penn, Naomi; Millares-Martin, Pablo; Bennett, Michael I

    2017-05-01

    The need to improve coordination of care at end of life has driven electronic palliative care coordination systems implementation across the United Kingdom and internationally. No approaches for evaluating electronic palliative care coordination systems use in practice have been developed. This study outlines and applies an evaluation framework for examining how and when electronic documentation of advance care planning is occurring in end of life care services. A pragmatic, formative process evaluation approach was adopted. The evaluation drew on the Project Review and Objective Evaluation methodology to guide the evaluation framework design, focusing on clinical processes. Data were extracted from electronic palliative care coordination systems for 82 of 108 general practices across a large UK city. All deaths ( n = 1229) recorded on electronic palliative care coordination systems between April 2014 and March 2015 were included to determine the proportion of all deaths recorded, median number of days prior to death that key information was recorded and observations about routine data use. The evaluation identified 26.8% of all deaths recorded on electronic palliative care coordination systems. The median number of days to death was calculated for initiation of an electronic palliative care coordination systems record (31 days), recording a patient's preferred place of death (8 days) and entry of Do Not Attempt Cardiopulmonary Resuscitation decisions (34 days). Where preferred and actual place of death was documented, these were matching for 75% of patients. Anomalies were identified in coding used during data entry on electronic palliative care coordination systems. This study reports the first methodology for evaluating how and when electronic palliative care coordination systems documentation is occurring. It raises questions about what can be drawn from routine data collected through electronic palliative care coordination systems and outlines

  2. Reducing complexity of inverse problems using geostatistical priors

    DEFF Research Database (Denmark)

    Hansen, Thomas Mejer; Mosegaard, Klaus; Cordua, Knud Skou

    a posterior sample, can be reduced significantly using informed priors based on geostatistical models. We discuss two approaches to include such geostatistically based prior information. One is based on a parametric description of the prior likelihood that applies to 2-point based statistical models...

  3. Coordination of Passive Systems under Quantized Measurements

    NARCIS (Netherlands)

    De Persis, Claudio; Jayawardhana, Bayu

    2012-01-01

    In this paper we investigate a passivity approach to collective coordination and synchronization problems in the presence of quantized measurements and show that coordination tasks can be achieved in a practical sense for a large class of passive systems.

  4. Energy shaping for coordinating internally actuated vehicles

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    This paper considers the stable coordination problem of two vehicles equipping with internal moving mass actuators.The coordinating and stabilizing control are derived by energy shaping. The proposed method is physically motivated and avoids cancelation or domination of nonlinearities.

  5. Periodic behavior of lanthanide coordination within reverse micelles.

    Science.gov (United States)

    Ellis, Ross J; Meridiano, Yannick; Chiarizia, Renato; Berthon, Laurence; Muller, Julie; Couston, Laurent; Antonio, Mark R

    2013-02-18

    equivalent to the solid nor bulk solution behaviors. Herein we address atomic- and mesoscale phenomena in the under-explored field of lanthanide coordination and periodic behavior within RMs, providing a consilience of fundamental insights into the chemistry of growing importance in technologies as diverse as nanosynthesis and separations science.

  6. Dressed coordinates: The path-integral approach

    Science.gov (United States)

    Casana, R.; Flores-Hidalgo, G.; Pimentel, B. M.

    2007-02-01

    The recently introduced dressed coordinates are studied in the path-integral approach. These coordinates are defined in the context of a harmonic oscillator linearly coupled to massless scalar field and it is shown that in this model the dressed coordinates appear as a coordinate transformation preserving the path-integral functional measure. The analysis also generalizes the sum rules established in a previous work.

  7. Digital communication constraints in prior space missions

    Science.gov (United States)

    Yassine, Nathan K.

    2004-01-01

    Digital communication is crucial for space endeavors. Jt transmits scientific and command data between earth stations and the spacecraft crew. It facilitates communications between astronauts, and provides live coverage during all phases of the mission. Digital communications provide ground stations and spacecraft crew precise data on the spacecraft position throughout the entire mission. Lessons learned from prior space missions are valuable for our new lunar and Mars missions set by our president s speech. These data will save our agency time and money, and set course our current developing technologies. Limitations on digital communications equipment pertaining mass, volume, data rate, frequency, antenna type and size, modulation, format, and power in the passed space missions are of particular interest. This activity is in support of ongoing communication architectural studies pertaining to robotic and human lunar exploration. The design capabilities and functionalities will depend on the space and power allocated for digital communication equipment. My contribution will be gathering these data, write a report, and present it to Communications Technology Division Staff. Antenna design is very carefully studied for each mission scenario. Currently, Phased array antennas are being developed for the lunar mission. Phased array antennas use little power, and electronically steer a beam instead of DC motors. There are 615 patches in the phased array antenna. These patches have to be modified to have high yield. 50 patches were created for testing. My part is to assist in the characterization of these patch antennas, and determine whether or not certain modifications to quartz micro-strip patch radiators result in a significant yield to warrant proceeding with repairs to the prototype 19 GHz ferroelectric reflect-array antenna. This work requires learning how to calibrate an automatic network, and mounting and testing antennas in coaxial fixtures. The purpose of this

  8. An Ensemble Approach to Building Mercer Kernels with Prior Information

    Science.gov (United States)

    Srivastava, Ashok N.; Schumann, Johann; Fischer, Bernd

    2005-01-01

    This paper presents a new methodology for automatic knowledge driven data mining based on the theory of Mercer Kernels, which are highly nonlinear symmetric positive definite mappings from the original image space to a very high, possibly dimensional feature space. we describe a new method called Mixture Density Mercer Kernels to learn kernel function directly from data, rather than using pre-defined kernels. These data adaptive kernels can encode prior knowledge in the kernel using a Bayesian formulation, thus allowing for physical information to be encoded in the model. Specifically, we demonstrate the use of the algorithm in situations with extremely small samples of data. We compare the results with existing algorithms on data from the Sloan Digital Sky Survey (SDSS) and demonstrate the method's superior performance against standard methods. The code for these experiments has been generated with the AUTOBAYES tool, which automatically generates efficient and documented C/C++ code from abstract statistical model specifications. The core of the system is a schema library which contains templates for learning and knowledge discovery algorithms like different versions of EM, or numeric optimization methods like conjugate gradient methods. The template instantiation is supported by symbolic-algebraic computations, which allows AUTOBAYES to find closed-form solutions and, where possible, to integrate them into the code.

  9. 7 CFR 23.3 - Coordination.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 1 2010-01-01 2010-01-01 false Coordination. 23.3 Section 23.3 Agriculture Office of the Secretary of Agriculture STATE AND REGIONAL ANNUAL PLANS OF WORK State Program § 23.3 Coordination... designate an official who will be responsible for the overall coordination of the authorized programs...

  10. 47 CFR 74.638 - Frequency coordination.

    Science.gov (United States)

    2010-10-01

    ... frequency coordinated under this paragraph, the interference protection criteria in 47 CFR 101.105(a), (b), and (c) and the frequency usage coordination procedures in 47 CFR 101.103(d) will apply. (c) For each... 47 Telecommunication 4 2010-10-01 2010-10-01 false Frequency coordination. 74.638 Section...

  11. 47 CFR 27.57 - International coordination.

    Science.gov (United States)

    2010-10-01

    ... 47 Telecommunication 2 2010-10-01 2010-10-01 false International coordination. 27.57 Section 27.57... COMMUNICATIONS SERVICES Technical Standards § 27.57 International coordination. (a) WCS operations in the border areas shall be subject to coordination with those countries and provide protection to non-U.S...

  12. 42 CFR 38.1 - Purpose; coordination.

    Science.gov (United States)

    2010-10-01

    ... 42 Public Health 1 2010-10-01 2010-10-01 false Purpose; coordination. 38.1 Section 38.1 Public... DISASTER ASSISTANCE FOR CRISIS COUNSELING AND TRAINING § 38.1 Purpose; coordination. (a) Purpose. This part... providing those professional counseling services. (b) Coordination. The Secretary, acting through the...

  13. 45 CFR 98.82 - Coordination.

    Science.gov (United States)

    2010-10-01

    ... 45 Public Welfare 1 2010-10-01 2010-10-01 false Coordination. 98.82 Section 98.82 Public Welfare DEPARTMENT OF HEALTH AND HUMAN SERVICES GENERAL ADMINISTRATION CHILD CARE AND DEVELOPMENT FUND Indian Tribes § 98.82 Coordination. Tribal applicants shall coordinate as required by §§ 98.12 and 98.14 and: (a) To...

  14. Construction and minimality of coordinated linear systems

    NARCIS (Netherlands)

    Kempker, P.L.; Ran, A.C.M.; Schuppen, J.H. van

    2014-01-01

    Coordinated linear systems are a particular class of hierarchical systems with a top-to-bottom information structure, consisting of a coordinator system and two or more subsystems. This paper deals with the construction and minimality of coordinated linear systems. Construction procedures are given

  15. 45 CFR 1310.23 - Coordinated transportation.

    Science.gov (United States)

    2010-10-01

    ... 45 Public Welfare 4 2010-10-01 2010-10-01 false Coordinated transportation. 1310.23 Section 1310... START PROGRAM HEAD START TRANSPORTATION Special Requirements § 1310.23 Coordinated transportation. (a) Each agency providing transportation services must make reasonable efforts to coordinate...

  16. 36 CFR 13.1104 - Coordinates.

    Science.gov (United States)

    2010-07-01

    ... 36 Parks, Forests, and Public Property 1 2010-07-01 2010-07-01 false Coordinates. 13.1104 Section 13.1104 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR... Administrative Provisions § 13.1104 Coordinates. All coordinates referenced in this subpart use horizontal...

  17. 33 CFR 166.103 - Geographic coordinates.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Geographic coordinates. 166.103...) PORTS AND WATERWAYS SAFETY SHIPPING SAFETY FAIRWAYS General § 166.103 Geographic coordinates. Geographic coordinates expressed in terms of latitude or longitude, or both, are not intended for plotting on maps...

  18. 33 CFR 167.3 - Geographic coordinates.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Geographic coordinates. 167.3...) PORTS AND WATERWAYS SAFETY OFFSHORE TRAFFIC SEPARATION SCHEMES General § 167.3 Geographic coordinates. Geographic coordinates are defined using North American 1927 Datum (NAD 27) unless indicated otherwise....

  19. Managing interteam coordination within and between organizations

    NARCIS (Netherlands)

    de Vries, Thomas Arend

    2015-01-01

    To accomplish complex tasks and effectively respond to environmental contingencies, teams must coordinate task-related issues with other teams (i.e., interteam coordination). Regrettably, interteam coordination is often complicated by misunderstandings that can arise from differences in teams’ langu

  20. 78 FR 34035 - Forest Resource Coordinating Committee

    Science.gov (United States)

    2013-06-06

    ... Forest Service Forest Resource Coordinating Committee AGENCY: Forest Service, USDA. ACTION: Notice of meeting. SUMMARY: The Forest Resource Coordinating Committee will meet via teleconference every month on... conference call will be posted to the Forest Resource Coordinating Committee Web site, http://www.fs.fed.us...

  1. 78 FR 57128 - Forest Resource Coordinating Committee

    Science.gov (United States)

    2013-09-17

    ... Forest Service Forest Resource Coordinating Committee AGENCY: Forest Service, USDA. ACTION: Notice of meeting. SUMMARY: The Forest Resource Coordinating Committee Meeting will meet in Rosslyn, Virginia. The... inspect comments received on the Forest Resource Coordinating Committee Web site at http://www.fs.fed.us...

  2. 78 FR 44519 - Forest Resource Coordinating Committee

    Science.gov (United States)

    2013-07-24

    ... Office of the Secretary Forest Resource Coordinating Committee AGENCY: Forest Service, USDA. ACTION: Notice; Re-establishment of the Forest Resource Coordinating Committee and call for nominations. SUMMARY: The Department of Agriculture re-established the Forest Resource Coordinating Committee (Committee...

  3. Is fiscal policy coordination in EMU desirable?

    NARCIS (Netherlands)

    R.M.W.J. Beetsma; X. Debrun; F.J.G.M. Klaassen

    2001-01-01

    'It is widely argued that Europe's unified monetary policy calls for international coordination of fiscal policy. This paper surveys the issues involved with the coordination of fiscal policies as a demand management tool. We discuss ex-ante and ex-post coordination. The former operates through bind

  4. 49 CFR 214.325 - Train coordination.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Train coordination. 214.325 Section 214.325..., DEPARTMENT OF TRANSPORTATION RAILROAD WORKPLACE SAFETY Roadway Worker Protection § 214.325 Train coordination. Working limits established by a roadway worker through the use of train coordination shall comply with the...

  5. Coordination in serial-parallel image processing

    Science.gov (United States)

    Wójcik, Waldemar; Dubovoi, Vladymyr M.; Duda, Marina E.; Romaniuk, Ryszard S.; Yesmakhanova, Laura; Kozbakova, Ainur

    2015-12-01

    Serial-parallel systems used to convert the image. The control of their work results with the need to solve coordination problem. The paper summarizes the model of coordination of resource allocation in relation to the task of synchronizing parallel processes; the genetic algorithm of coordination developed, its adequacy verified in relation to the process of parallel image processing.

  6. 77 FR 778 - Council Coordination Committee Meeting

    Science.gov (United States)

    2012-01-06

    ... National Oceanic and Atmospheric Administration RIN 0648-XA918 Council Coordination Committee Meeting...), Commerce. ACTION: Notice of a public meeting. SUMMARY: NMFS will host a meeting of the Council Coordination... Reauthorization Act (MSRA) of 2006 established the Council Coordination Committee by amending Section 302 (16...

  7. Schwarzschild solution from Weyl transverse gravity

    Science.gov (United States)

    Oda, Ichiro

    2017-01-01

    We study classical solutions in the Weyl-transverse (WTDiff) gravity. The WTDiff gravity is invariant under both the local Weyl (conformal) transformation and the volume preserving diffeomorphisms (Diff) (transverse diffeomorphisms (TDiff)) and is known to be equivalent to general relativity at least at the classical level. In particular, we find that in a general spacetime dimension, the Schwarzschild metric is a classical solution in the WTDiff gravity when it is expressed in the Cartesian coordinate system.

  8. Post-prior discrepancies in the continuum distorted wave-eikonal initial state approximation for ion-helium ionization

    Energy Technology Data Exchange (ETDEWEB)

    Ciappina, M F [CONICET and Departamento de Fisica, Universidad Nacional del Sur, 8000 Bahia Blanca (Argentina); Cravero, W R [CONICET and Departamento de Fisica, Universidad Nacional del Sur, 8000 Bahia Blanca (Argentina); Garibotti, C R [CONICET and Division Colisiones Atomicas, Centro Atomico Bariloche, 8400 Bariloche (Argentina)

    2003-09-28

    We have explored post-prior discrepancies within continuum distorted wave-eikonal initial state theory for ion-atom ionization. Although there are no post-prior discrepancies when electron-target initial and final states are exact solutions of the respective Hamiltonians, discrepancies do arise for multielectronic targets, when a hydrogenic continuum with effective charge is used for the final electron-residual target wavefunction. We have found that the prior version calculations give better results than the post version, particularly for highly charged projectiles. We have explored the reasons for this behaviour and found that the prior version shows less sensitivity to the choice of the final state. The fact that the perturbation potentials operate upon the initial state suggests that the selection of the initial bound state is relatively more important than the final continuum state for the prior version.

  9. Normal BGG solutions and polynomials

    CERN Document Server

    Cap, A; Hammerl, M

    2012-01-01

    First BGG operators are a large class of overdetermined linear differential operators intrinsically associated to a parabolic geometry on a manifold. The corresponding equations include those controlling infinitesimal automorphisms, higher symmetries, and many other widely studied PDE of geometric origin. The machinery of BGG sequences also singles out a subclass of solutions called normal solutions. These correspond to parallel tractor fields and hence to (certain) holonomy reductions of the canonical normal Cartan connection. Using the normal Cartan connection, we define a special class of local frames for any natural vector bundle associated to a parabolic geometry. We then prove that the coefficient functions of any normal solution of a first BGG operator with respect to such a frame are polynomials in the normal coordinates of the parabolic geometry. A bound on the degree of these polynomials in terms of representation theory data is derived. For geometries locally isomorphic to the homogeneous model of ...

  10. Coordinated hybrid automatic repeat request

    KAUST Repository

    Makki, Behrooz

    2014-11-01

    We develop a coordinated hybrid automatic repeat request (HARQ) approach. With the proposed scheme, if a user message is correctly decoded in the first HARQ rounds, its spectrum is allocated to other users, to improve the network outage probability and the users\\' fairness. The results, which are obtained for single- and multiple-antenna setups, demonstrate the efficiency of the proposed approach in different conditions. For instance, with a maximum of M retransmissions and single transmit/receive antennas, the diversity gain of a user increases from M to (J+1)(M-1)+1 where J is the number of users helping that user.

  11. Application coordination in pervasive systems

    CERN Document Server

    Majuntke, Verena Elisabeth

    2013-01-01

    Pervasive applications are designed to support users in their daily life. For this purpose, applications interact with their environment, i.e. their context. They are able to adapt themselves to context changes or to explicitly change the context via actuators. If multiple applications are executed in the same context, interferences are likely to occur. To manage interferences, a coordination framework is presented in this thesis. Interferences are detected using a context model and information about applications' interaction with the context. The resolution of interference is achieved through

  12. Geometrical product specifications. Datums and coordinate systems

    Science.gov (United States)

    Glukhov, V. I.; Ivleva, I. A.; Zlatkina, O. Y.

    2017-06-01

    The work is devoted to the relevant topic such as the technical products quality improvement due to the geometrical specifications accuracy. The research purpose is to ensure the quality indicators on the basis of the systematic approach to the values normalization and geometrical specifications accuracy in the workpiece coordinate systems in the process of design. To achieve the goal two tasks are completed such as the datum features classification according to the number of linear and angular freedom degrees constraints, called the datums informativeness, and the rectangular coordinate systems identification, materialized by workpiece datums sets. The datum features informativeness characterizes the datums functional purpose to limit product workpiece linear and angular degrees of freedom. The datum features informativeness numerically coincides with the kinematic pairs classes and couplings in mechanics. The datum features informativeness identifies the coordinate system without the location redundancy. Each coordinate plane of a rectangular coordinate system has different informativeness 3 + 2 + 1. Each coordinate axis also has different informativeness 4+2+Θ (zero). It is possible to establish the associated workpiece position with three linear and three angular coordinates relative to two axes with the informativeness 4 and 2. is higher, the more informativeness of the coordinate axis or a coordinate plane is, the higher is the linear and angular coordinates accuracy, the coordinate being plotted along the coordinate axis or plane. The systematic approach to the geometrical products specifications positioning in coordinate systems is the scientific basis for a natural transition to the functional dimensions of features position - coordinating dimensions and the size of the features form - feature dimensions of two measures: linear and angular ones. The products technical quality improving is possible due to the coordinate systems introduction materialized by

  13. Harmonic Vibrational Analysis in Delocalized Internal Coordinates.

    Science.gov (United States)

    Jensen, Frank; Palmer, David S

    2011-01-11

    It is shown that a principal component analysis of a large set of internal coordinates can be used to define a nonredundant set of delocalized internal coordinates suitable for the calculation of harmonic vibrational normal modes. The selection of internal coordinates and the principal component analysis provide large degrees of freedom in extracting a nonredundant set of coordinates, and thus influence how the vibrational normal modes are described. It is shown that long-range coordinates may be especially suitable for describing low-frequency global deformation modes in proteins.

  14. Unpacking Coordination Benefits in Supply Networks

    DEFF Research Database (Denmark)

    Petrick, Irene J.; Maitland, Carleen; Pogrebnyakov, Nicolai

    2016-01-01

    This paper examines how coordination among firms in supply networks generates benefits in the short and long terms for firms. It focuses on information technology (IT) and process improvement coordination. Analysis was performed on quantitative and qualitative data from a sample of SMEs in plastics...... manufacturing in Pennsylvania. Results indicate that coordination on both IT and process improvement leads to short- and long-term benefits. These relationships were mediated by the adoption of innovations (when coordinating on IT) and access to new capabilities (in process improvement coordination......). These results extend the understanding of how participation in supply networks benefits individual firms....

  15. Improved Appliance Coordination Scheme with Waiting Time in Smart Grids

    Directory of Open Access Journals (Sweden)

    Firas A. Al Balas

    2016-04-01

    Full Text Available Smart grids aim to merge the advances in communications and information technologies with traditional power grids. In smart grids, users can generate energy and sell it to the local utility supplier. The users can reduce energy consumption by shifting appliances’ start time to off-peak hours. Many researchers have proposed techniques to reduce the previous issue for home appliances, such as the Appliances Coordination (ACORD scheme and Appliances Coordination with Feed In (ACORD-FI scheme. The goal of this work is to introduce an efficient scheme to reduce the total cost of energy bills by utilizing the ACORD-FI scheme to obtain an effective solution. In this work three scheduling schemes are proposed: the Appliances Coordination by Giving Waiting Time (ACORD-WT, the Appliances Coordination by Giving Priority (ACORD-P, and using photovoltaic (PV with priority and waiting time scheduling algorithms. A simulator written in C++ is used to test the performance of the proposed schemes using. The performance metric used is the total savings in the cost of the energy bill in dollars. The first comparison for the proposed schemes with the ACORD-FI, and the results show that the efficiency of the proposed ACORD-WT is better than the ACORD-FI, regardless of the number of appliances. Moreover, the proposed ACORD-P, is also better than the standard ACORD-FI.

  16. Coordinated Control of Wave Energy Converters Subject to Motion Constraints

    Directory of Open Access Journals (Sweden)

    Liguo Wang

    2016-06-01

    Full Text Available In this paper, a generic coordinated control method for wave energy converters is proposed, and the constraints on motion amplitudes and the hydrodynamic interaction between converters are considered. The objective of the control problem is to maximize the energy converted from ocean waves, and this is achieved by coordinating the power take-off (PTO damping of each wave energy converter in the frequency domain in each sea state. In a case study, a wave energy farm consisting of four converters based on the concept developed by Uppsala University is studied. In the solution, motion constraints, including constraints on the amplitudes of displacement and velocity, are included. Twelve months of sea states, based on measured wave data at the Lysekil test site on the Swedish west coast, are used in the simulation to evaluate the performance of the wave energy farm using the new method. Results from the new coordinated control method and traditional control method are compared, indicating that the coordinated control of wave energy converters is an effective way to improve the energy production of wave energy farm in harmonic waves.

  17. Ytterbium Coordination Polymer with Four Different Coordination Numbers: The First Structural Characterization of Lanthanide Phthalate Complex

    Institute of Scientific and Technical Information of China (English)

    WAN,Yong-Hong(万永红); JIN,Lin-Pei(金林培); WANG,Ke-Zhi(王科志)

    2002-01-01

    The novel ytterbium coordination polymer is a two-dimensional framework in which the central metal ions have four different coordination numhers and form four kinds of coordination polyhedra. The four kinds of coordination polyhedra connect into infinite chains by sharing oxygen atoms

  18. SUPPLY CHAIN DECISION-MAKING AND COORDINATION UNDER PRICE-DEPENDENT DEMAND

    Institute of Scientific and Technical Information of China (English)

    Guangming HUANG; Lu LIU

    2006-01-01

    This paper studies the decision-making and coordination of supply chain (SC) considering the effect of price-dependent demand. By assuming demand decreases as the price increases, we analyse the impacts of the dependence on the SC in three different models: decentralized without coordination,centralized coordination and decentralized with coordination by revenue sharing contract. The existence of the best solution in the different models is proved, and the performance of revenue sharing coordination SC is similar to the centralized one. We find that the more evidently the price affects the demand, the more revenue sharing contract improves the performance of SC. The dependence affects the decision-making and the parameter setting of revenue sharing contract is also found.

  19. Visuo-manual coordination in preterm infants without neurological impairments.

    Science.gov (United States)

    Petkovic, Maja; Chokron, Sylvie; Fagard, Jacqueline

    2016-01-01

    The extent of and reasons for visuo-manual coordination deficits in moderate and late preterm born infants without neurological impairments are not well known. This paper presents a longitudinal study on the visuo-manual development of twelve preterm infants, born after 33-36 weeks of gestation without neurological complications, between the ages of 6 and 12 months. Visuo-manual integration and grasping were assessed using the Peabody Developmental Motor Scales, along with bimanual coordination and handedness tests. Visual function was examined once prior to the beginning of the study. Gross motor development was also evaluated every month. Preterm infants were compared to a control group of ten full-term infants according to corrected age. Compared to full-terms, the visual perception of preterm infants was close to normal, with only a measure of visual fixation lower than in full-terms. In contrast, preterm infants had delayed development of visuo-manual integration, grasping, bimanual coordination, and handedness even when compared using corrected age. Tonicity and gestational age at birth were the main variables associated to the delays. These results are discussed in terms of the possible factors underlying such delays. They need to be confirmed on a larger sample of preterm born children, and to be correlated with later development. This would allow developing markers of future neuropsychological impairments during childhood.

  20. Coordination of intrinsic and extrinsic foot muscles during walking.

    Science.gov (United States)

    Zelik, Karl E; La Scaleia, Valentina; Ivanenko, Yuri P; Lacquaniti, Francesco

    2015-04-01

    The human foot undergoes complex deformations during walking due to passive tissues and active muscles. However, based on prior recordings it is unclear if muscles that contribute to flexion/extension of the metatarsophalangeal (MTP) joints are activated synchronously to modulate joint impedance, or sequentially to perform distinct biomechanical functions. We investigated the coordination of MTP flexors and extensors with respect to each other, and to other ankle-foot muscles. We analyzed surface electromyographic (EMG) recordings of intrinsic and extrinsic foot muscles for healthy individuals during level treadmill walking, and also during sideways and tiptoe gaits. We computed stride-averaged EMG envelopes and used the timing of peak muscle activity to assess synchronous vs. sequential coordination. We found that peak MTP flexor activity occurred significantly before peak MTP extensor activity during walking (P walking tended to dissociate during other locomotor tasks. For instance, extensor hallucis brevis and extensor digitorum brevis muscle activation peaks decoupled during sideways gait. The sequential peak activity of MTP flexors followed by MTP extensors suggests that their biomechanical contributions may be largely separable from each other and from other extrinsic foot muscles during walking. Meanwhile, the task-specific coordination of the foot muscles during other modes of locomotion indicates a high-level of specificity in their function and control.

  1. Implicit Coordination Strategies for Effective Team Communication.

    Science.gov (United States)

    Butchibabu, Abhizna; Sparano-Huiban, Christopher; Sonenberg, Liz; Shah, Julie

    2016-06-01

    We investigated implicit communication strategies for anticipatory information sharing during team performance of tasks with varying degrees of complexity. We compared the strategies used by teams with the highest level of performance to those used by the lowest-performing teams to evaluate the frequency and methods of communications used as a function of task structure. High-performing teams share information by anticipating the needs of their teammates rather than explicitly requesting the exchange of information. As the complexity of a task increases to involve more interdependence among teammates, the impact of coordination on team performance also increases. This observation motivated us to conduct a study of anticipatory information sharing as a function of task complexity. We conducted an experiment in which 13 teams of four people performed collaborative search-and-deliver tasks with varying degrees of complexity in a simulation environment. We elaborated upon prior characterizations of communication as implicit versus explicit by dividing implicit communication into two subtypes: (a) deliberative/goal information and (b) reactive status updates. We then characterized relationships between task structure, implicit communication, and team performance. We found that the five teams with the fastest task completion times and lowest idle times exhibited higher rates of deliberative communication versus reactive communication during high-complexity tasks compared with the five teams with the slowest completion times and longest idle times (p = .039). Teams in which members proactively communicated information about their next goal to teammates exhibited improved team performance. The findings from our work can inform the design of communication strategies for team training to improve performance of complex tasks. © 2016, Human Factors and Ergonomics Society.

  2. D Coordinate Transformation Using Artificial Neural Networks

    Science.gov (United States)

    Konakoglu, B.; Cakır, L.; Gökalp, E.

    2016-10-01

    Two coordinate systems used in Turkey, namely the ED50 (European Datum 1950) and ITRF96 (International Terrestrial Reference Frame 1996) coordinate systems. In most cases, it is necessary to conduct transformation from one coordinate system to another. The artificial neural network (ANN) is a new method for coordinate transformation. One of the biggest advantages of the ANN is that it can determine the relationship between two coordinate systems without a mathematical model. The aim of this study was to investigate the performances of three different ANN models (Feed Forward Back Propagation (FFBP), Cascade Forward Back Propagation (CFBP) and Radial Basis Function Neural Network (RBFNN)) with regard to 2D coordinate transformation. To do this, three data sets were used for the same study area, the city of Trabzon. The coordinates of data sets were measured in the ED50 and ITRF96 coordinate systems by using RTK-GPS technique. Performance of each transformation method was investigated by using the coordinate differences between the known and estimated coordinates. The results showed that the ANN algorithms can be used for 2D coordinate transformation in cases where optimum model parameters are selected.

  3. Collaborative Supply Chain Planning and Coordination

    DEFF Research Database (Denmark)

    Wong, Chee Yew

    between the toy manufacturer and three European retailers. These three case studies provide evidences that the toy manufacturer and the retailers followed some particular patterns of planning coordination processes; they also practised some patterns of coordination behaviour during the coordination...... processes, particularly the behaviour of risk-taking/avoidance, conflict resolutions, and self-interest. All these lead to conclusion of five propositions or principles of supply chain coordination, and the theory of coordination process and behaviour. Combining the propositions of responsiveness......This thesis contains main results from an industrial PhD research in the areas of supply chain strategy, planning, and coordination. It applies the concepts of responsiveness and coordination to reduce mismatch of supply and demand, especially for a volatile and seasonal supply chain. It involves...

  4. Solution to Projectile Motion with Quadratic Drag and Graphing the Trajectory in Spreadsheets

    Science.gov (United States)

    Benacka, Jan

    2010-01-01

    This note gives the analytical solution to projectile motion with quadratic drag by decomposing the velocity vector to "x," "y" coordinate directions. The solution is given by definite integrals. First, the impact angle is estimated from above, then the projectile coordinates are computed, and the trajectory is graphed at various launch angles and…

  5. Comparison of no-prior and soft-prior regularization in biomedical microwave imaging

    Directory of Open Access Journals (Sweden)

    Amir H Golnabi

    2011-01-01

    Full Text Available Microwave imaging for medical applications is attractive because the range of dielectric properties of different soft tissues can be substantial. Breast cancer detection and monitoring of treatment response are areas where this technology could be important because of the contrast between normal and malignant tissue. Unfortunately, the technique is unable to achieve the high spatial resolution at depth in tissue which is available from other conventional modalities such as x-ray computed tomography (CT or magnetic resonance imaging (MRI. We have incorporated a soft-prior regularization strategy within our microwave reconstruction algorithm and compared it with the images obtained with traditional no-prior (Levenberg-Marquardt regularization. Initial simulation and phantom results show a significant improvement of the recovered electrical properties. Specifically, errors in the microwave property estimates were improved by as much as 95%. The effects of a false-inclusion region were also evaluated and the results show that a small residual property bias of 6% in permittivity and 15% in conductivity can occur that does not otherwise degrade the property recovery accuracy of inclusions that actually exist. The work sets the stage for integrating microwave imaging with MR for improved resolution and functional imaging of the breast in the future.

  6. Application of Advanced Particle Swarm Optimization Techniques to Wind-thermal Coordination

    DEFF Research Database (Denmark)

    Singh, Sri Niwas; Østergaard, Jacob; Yadagiri, J.

    2009-01-01

    wind-thermal coordination algorithm is necessary to determine the optimal proportion of wind and thermal generator capacity that can be integrated into the system. In this paper, four versions of Particle Swarm Optimization (PSO) techniques are proposed for solving wind-thermal coordination problem....... A pseudo code based algorithm is suggested to deal with the equality constraints of the problem for accelerating the optimization process. The simulation results show that the proposed PSO methods are capable of obtaining higher quality solutions efficiently in wind-thermal coordination problems....

  7. Relativistic gravitational collapse in comoving coordinates: The post-quasistatic approximation

    CERN Document Server

    Herrera, L

    2010-01-01

    A general iterative method proposed some years ago for the description of relativistic collapse, is presented here in comoving coordinates. For doing that we redefine the basic concepts required for the implementation of the method for comoving coordinates. In particular the definition of the post-quasistatic approximation in comoving coordinates is given. We write the field equations, the boundary conditions and a set of ordinary differential equations (the surface equations) which play a fundamental role in the algorithm. As an illustration of the method, we show how to build up a model inspired in the well known Schwarzschild interior solution. Both, the adiabatic and non adiabatic, cases are considered.

  8. The Weierstrass–Enneper Representation using Hodographic Coordinates on a Minimal Surface

    Indian Academy of Sciences (India)

    Rukmini Dey

    2003-05-01

    In this paper we obtain the general solution to the minimal surface equation, namely its local Weierstrass–Enneper representation, using a system of hodographic coordinates. This is done by using the method of solving the Born–Infeld equations by Whitham. We directly compute conformal coordinates on the minimal surface which give the Weierstrass–Enneper representation. From this we derive the hodographic coordinate $ρ \\in D \\subset \\mathbb{C}$ and its complex conjugate which enables us to write the Weierstrass–Enneper representation in a new way.

  9. Sensorimotor Oscillations Prior to Speech Onset Reflect Altered Motor Networks in Adults Who Stutter

    Science.gov (United States)

    Mersov, Anna-Maria; Jobst, Cecilia; Cheyne, Douglas O.; De Nil, Luc

    2016-01-01

    Adults who stutter (AWS) have demonstrated atypical coordination of motor and sensory regions during speech production. Yet little is known of the speech-motor network in AWS in the brief time window preceding audible speech onset. The purpose of the current study was to characterize neural oscillations in the speech-motor network during preparation for and execution of overt speech production in AWS using magnetoencephalography (MEG). Twelve AWS and 12 age-matched controls were presented with 220 words, each word embedded in a carrier phrase. Controls were presented with the same word list as their matched AWS participant. Neural oscillatory activity was localized using minimum-variance beamforming during two time periods of interest: speech preparation (prior to speech onset) and speech execution (following speech onset). Compared to controls, AWS showed stronger beta (15–25 Hz) suppression in the speech preparation stage, followed by stronger beta synchronization in the bilateral mouth motor cortex. AWS also recruited the right mouth motor cortex significantly earlier in the speech preparation stage compared to controls. Exaggerated motor preparation is discussed in the context of reduced coordination in the speech-motor network of AWS. It is further proposed that exaggerated beta synchronization may reflect a more strongly inhibited motor system that requires a stronger beta suppression to disengage prior to speech initiation. These novel findings highlight critical differences in the speech-motor network of AWS that occur prior to speech onset and emphasize the need to investigate further the speech-motor assembly in the stuttering population. PMID:27642279

  10. Sensorimotor oscillations prior to speech onset reflect altered motor networks in adults who stutter

    Directory of Open Access Journals (Sweden)

    Anna-Maria Mersov

    2016-09-01

    Full Text Available Adults who stutter (AWS have demonstrated atypical coordination of motor and sensory regions during speech production. Yet little is known of the speech-motor network in AWS in the brief time window preceding audible speech onset. The purpose of the current study was to characterize neural oscillations in the speech-motor network during preparation for and execution of overt speech production in AWS using magnetoencephalography (MEG. Twelve AWS and twelve age-matched controls were presented with 220 words, each word embedded in a carrier phrase. Controls were presented with the same word list as their matched AWS participant. Neural oscillatory activity was localized using minimum-variance beamforming during two time periods of interest: speech preparation (prior to speech onset and speech execution (following speech onset. Compared to controls, AWS showed stronger beta (15-25Hz suppression in the speech preparation stage, followed by stronger beta synchronization in the bilateral mouth motor cortex. AWS also recruited the right mouth motor cortex significantly earlier in the speech preparation stage compared to controls. Exaggerated motor preparation is discussed in the context of reduced coordination in the speech-motor network of AWS. It is further proposed that exaggerated beta synchronization may reflect a more strongly inhibited motor system that requires a stronger beta suppression to disengage prior to speech initiation. These novel findings highlight critical differences in the speech-motor network of AWS that occur prior to speech onset and emphasize the need to investigate further the speech-motor assembly in the stuttering population.

  11. Stateless and Delivery Guaranteed Geometric Routing on Virtual Coordinate System

    CERN Document Server

    Liu, Ke

    2008-01-01

    Stateless geographic routing provides relatively good performance at a fixed overhead, which is typically much lower than conventional routing protocols such as AODV. However, the performance of geographic routing is impacted by physical voids, and localization errors. Accordingly, virtual coordinate systems (VCS) were proposed as an alternative approach that is resilient to localization errors and that naturally routes around physical voids. However, VCS also faces virtual anomalies, causing their performance to trail geographic routing. In existing VCS routing protocols, there is a lack of an effective stateless and delivery guaranteed complementary routing algorithm that can be used to traverse voids. Most proposed solutions use variants of flooding or blind searching when a void is encountered. In this paper, we propose a spanning-path virtual coordinate system which can be used as a complete routing algorithm or as the complementary algorithm to greedy forwarding that is invoked when voids are encountere...

  12. The Unifying Principle of Coordinated Measurements in Geospace Science

    Science.gov (United States)

    Lotko, William

    2017-04-01

    Space scientists recognize geospace as a coupled dynamical system extending from the Earth's upper atmosphere, ionosphere, and magnetosphere, through interplanetary space to the Sun. The weather in geospace describes variability in the electromagnetic fields, particle radiation, plasmas, and gases permeating it, usually in response to solar disturbances. Severe space weather poses a significant threat to human activities in space and to modern technological systems deployed both in space and at Earth. The challenge of characterizing and predicting space weather requires widely distributed, coordinated observations. Partnerships among government agencies, international consortia, and the private sector are developing creative solutions to address this challenge. This brief commentary highlights some of the coordinated measurements and data systems that are unifying knowledge of the geospace environment.

  13. Modeling the effects of prior infection on vaccine efficacy

    Energy Technology Data Exchange (ETDEWEB)

    Smith, D.J.; Forrest, S.; Ackley, D.H. [Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Computer Science; Perelson, A.S. [Los Alamos National Lab., NM (United States)

    1997-11-01

    We performed computer simulations to study the effects of prior infection on vaccine efficacy. We injected three antigens sequentially. The first antigen, designated the prior, represented a prior infection or vaccination. The second antigen, the vaccine, represented a single component of the trivalent influenza vaccine. The third antigen, the epidemic, represented challenge by an epidemic strain. For a fixed vaccine to epidemic strain cross-reactivities to the vaccine and to the epidemic strains. We found that, for many cross-reactivities, vaccination, when it had been preceded by a prior infection, provided more protection than vaccination alone. However, at some cross-reactivities, the prior infection reduced protection by clearing the vaccine before it had the chance to produce protective memory. The cross-reactivities between the prior, vaccine and epidemic strains played a major role in determining vaccine efficacy. This work has applications to understanding vaccination against viruses such as influenza that are continually mutating.

  14. Frameworks Coordinate Scientific Data Management

    Science.gov (United States)

    2012-01-01

    Jet Propulsion Laboratory computer scientists developed a unique software framework to help NASA manage its massive amounts of science data. Through a partnership with the Apache Software Foundation of Forest Hill, Maryland, the technology is now available as an open-source solution and is in use by cancer researchers and pediatric hospitals.

  15. Impairments of social motor coordination in schizophrenia.

    Directory of Open Access Journals (Sweden)

    Manuel Varlet

    Full Text Available It has been demonstrated that motor coordination of interacting people plays a crucial role in the success of social exchanges. Abnormal movements have been reported during interpersonal interactions of patients suffering from schizophrenia and a motor coordination breakdown could explain this social interaction deficit, which is one of the main and earliest features of the illness. Using the dynamical systems framework, the goal of the current study was (i to investigate whether social motor coordination is impaired in schizophrenia and (ii to determine the underlying perceptual or cognitive processes that may be affected. We examined intentional and unintentional social motor coordination in participants oscillating hand-held pendulums from the wrist. The control group consisted of twenty healthy participant pairs while the experimental group consisted of twenty participant pairs that included one participant suffering from schizophrenia. The results showed that unintentional social motor coordination was preserved while intentional social motor coordination was impaired. In intentional coordination, the schizophrenia group displayed coordination patterns that had lower stability and in which the patient never led the coordination. A coupled oscillator model suggests that the schizophrenia group coordination pattern was due to a decrease in the amount of available information together with a delay in information transmission. Our study thus identified relational motor signatures of schizophrenia and opens new perspectives for detecting the illness and improving social interactions of patients.

  16. Medicaid Managed Care Structures and Care Coordination.

    Science.gov (United States)

    Gilchrist-Scott, Douglas H; Feinstein, James A; Agrawal, Rishi

    2017-09-01

    Child enrollment in Medicaid managed care (MMC) has expanded dramatically, primarily through state mandates. Care coordination is a key metric in MMC evaluation because it drives much of the proposed cost savings and may be associated with improved health outcomes and utilization. We evaluated the relationships between enrollment in 2 MMC structures, primary care case management (PCCM) and health maintenance organization (HMO) and access to and receipt of care coordination by children. Using data from the 2011/2012 National Survey of Children's Health and the Medicaid Statistical Information System state data mart, we conducted a retrospective, cross-sectional analysis of the relationships between fee-for-service, PCCM or HMO enrollment, and access to and receipt of care coordination. State-level univariate analyses and individual and state multilevel multivariable analyses evaluated correlations between MMC enrollment and care coordination, controlling for demographic characteristics and state financing levels. In univariate and multilevel multivariable analyses, the PCCM penetration rate was significantly associated with increased access to care coordination (adjusted odds ratio: 1.23, P = .034) and receipt of care coordination (adjusted odds ratio: 1.37, P = .02). The HMO penetration rate was significantly associated with lower access to care coordination (adjusted odds ratio: 0.85, P = .05) and receipt of care coordination (adjusted odds ratio: 0.71, P coordination may be more effective in PCCM than HMO structures. States should consider care coordination outcomes when structuring their Medicaid programs. Copyright © 2017 by the American Academy of Pediatrics.

  17. Coordination control of distributed systems

    CERN Document Server

    Villa, Tiziano

    2015-01-01

    This book describes how control of distributed systems can be advanced by an integration of control, communication, and computation. The global control objectives are met by judicious combinations of local and nonlocal observations taking advantage of various forms of communication exchanges between distributed controllers. Control architectures are considered according to  increasing degrees of cooperation of local controllers:  fully distributed or decentralized control,  control with communication between controllers,  coordination control, and multilevel control.  The book covers also topics bridging computer science, communication, and control, like communication for control of networks, average consensus for distributed systems, and modeling and verification of discrete and of hybrid systems. Examples and case studies are introduced in the first part of the text and developed throughout the book. They include: control of underwater vehicles, automated-guided vehicles on a container terminal, contro...

  18. Tree Formation Using Coordinate Method

    Directory of Open Access Journals (Sweden)

    Monika Choudhary

    2015-06-01

    Full Text Available In this paper we are introducing a new method of tree formation, we propose a coordinate based method by which we can store and access tree structures. As we know in NLP, parsing is the most important module. The output of this module is generally parsed trees. Currently, TAG (Tree Adjoining Grammar is widely used grammar due to its linguistic and formal nature. It is simply tree generating system. The unit structure used in TAG is structured trees. So we used our new method to store trees where we worked on English to Hindi language. We worked on different sentences from English to Hindi, our method is the easiest way to manipulate tree. We have implemented within small corpus and for finite number of structures and further can be extended in future.

  19. PTPRR, cerebellum, and motor coordination.

    Science.gov (United States)

    Schmitt, Ina; Bitoun, Emmanuelle; Manto, Mario

    2009-06-01

    Tyrosine phosphorylation is a powerful mechanism of modulation for proliferation, differentiation, and functioning of neurons. The protein products of the neuronal mouse gene PTPRR are physiological regulators of mitogen-activated protein kinase (MAPK) activities. PTPRR(-/-) mice display deficits of motor coordination and balance skills. PTPRR gene orthologues are found in many vertebrates. Recent observations suggest that the human episodic ataxia 2 (EA2) and spinocerebellar ataxia types 6 (SCA6), 12 (SCA12), and 14 (SCA14) might be associated with impaired phosphorylation levels of cerebellum calcium channels and receptors. The concept that MAPK signaling is a key process in tuning synaptic plasticity in cerebellar circuits is now emerging, with numerous implications for understanding cerebellar functions and cerebellar disorders.

  20. Non-negative matrix factorization with Gaussian process priors

    DEFF Research Database (Denmark)

    Schmidt, Mikkel Nørgaard; Laurberg, Hans

    2008-01-01

    We present a general method for including prior knowledge in a nonnegative matrix factorization (NMF), based on Gaussian process priors. We assume that the nonnegative factors in the NMF are linked by a strictly increasing function to an underlying Gaussian process specified by its covariance...... function. This allows us to find NMF decompositions that agree with our prior knowledge of the distribution of the factors, such as sparseness, smoothness, and symmetries. The method is demonstrated with an example from chemical shift brain imaging....

  1. Spectrally Consistent Satellite Image Fusion with Improved Image Priors

    DEFF Research Database (Denmark)

    Nielsen, Allan Aasbjerg; Aanæs, Henrik; Jensen, Thomas B.S.;

    2006-01-01

    Here an improvement to our previous framework for satellite image fusion is presented. A framework purely based on the sensor physics and on prior assumptions on the fused image. The contributions of this paper are two fold. Firstly, a method for ensuring 100% spectrally consistency is proposed......, even when more sophisticated image priors are applied. Secondly, a better image prior is introduced, via data-dependent image smoothing....

  2. Acquisition of multiple prior distributions in tactile temporal order judgment

    Directory of Open Access Journals (Sweden)

    Yasuhito eNagai

    2012-08-01

    Full Text Available The Bayesian estimation theory proposes that the brain acquires the prior distribution of a task and integrates it with sensory signals to minimize the effect of sensory noise. Psychophysical studies have demonstrated that our brain actually implements Bayesian estimation in a variety of sensory-motor tasks. However, these studies only imposed one prior distribution on participants within a task period. In this study, we investigated the conditions that enable the acquisition of multiple prior distributions in temporal order judgment (TOJ of two tactile stimuli across the hands. In Experiment 1, stimulation intervals were randomly selected from one of two prior distributions (biased to right hand earlier and biased to left hand earlier in association with color cues (green and red, respectively. Although the acquisition of the two priors was not enabled by the color cues alone, it was significant when participants shifted their gaze (above or below in response to the color cues. However, the acquisition of multiple priors was not significant when participants moved their mouths (opened or closed. In Experiment 2, the spatial cues (above and below were used to identify which eye position or retinal cue position was crucial for the eye-movement-dependent acquisition of multiple priors in Experiment 1. The acquisition of the two priors was significant when participants moved their gaze to the cues (i.e., the cue positions on the retina were constant across the priors, as well as when participants did not shift their gazes (i.e., the cue positions on the retina changed according to the priors. Thus, both eye and retinal cue positions were effective in acquiring multiple priors. Based on previous neurophysiological reports, we discuss possible neural correlates that contribute to the acquisition of multiple priors.

  3. Non-negative matrix factorization with Gaussian process priors

    DEFF Research Database (Denmark)

    Schmidt, Mikkel Nørgaard; Laurberg, Hans

    2008-01-01

    We present a general method for including prior knowledge in a nonnegative matrix factorization (NMF), based on Gaussian process priors. We assume that the nonnegative factors in the NMF are linked by a strictly increasing function to an underlying Gaussian process specified by its covariance...... function. This allows us to find NMF decompositions that agree with our prior knowledge of the distribution of the factors, such as sparseness, smoothness, and symmetries. The method is demonstrated with an example from chemical shift brain imaging....

  4. Bayesian estimation of generalized exponential distribution under noninformative priors

    Science.gov (United States)

    Moala, Fernando Antonio; Achcar, Jorge Alberto; Tomazella, Vera Lúcia Damasceno

    2012-10-01

    The generalized exponential distribution, proposed by Gupta and Kundu (1999), is a good alternative to standard lifetime distributions as exponential, Weibull or gamma. Several authors have considered the problem of Bayesian estimation of the parameters of generalized exponential distribution, assuming independent gamma priors and other informative priors. In this paper, we consider a Bayesian analysis of the generalized exponential distribution by assuming the conventional noninformative prior distributions, as Jeffreys and reference prior, to estimate the parameters. These priors are compared with independent gamma priors for both parameters. The comparison is carried out by examining the frequentist coverage probabilities of Bayesian credible intervals. We shown that maximal data information prior implies in an improper posterior distribution for the parameters of a generalized exponential distribution. It is also shown that the choice of a parameter of interest is very important for the reference prior. The different choices lead to different reference priors in this case. Numerical inference is illustrated for the parameters by considering data set of different sizes and using MCMC (Markov Chain Monte Carlo) methods.

  5. Prior knowledge in recalling arguments in bioethical dilemmas

    Directory of Open Access Journals (Sweden)

    Hiemke Katharina Schmidt

    2015-09-01

    Full Text Available Prior knowledge is known to facilitate learning new information. Normally in studies confirming this outcome the relationship between prior knowledge and the topic to be learned is obvious: the information to be acquired is part of the domain or topic to which the prior knowledge belongs. This raises the question as to whether prior knowledge of various domains facilitates recalling information. In this study 79 eleventh-grade students completed a questionnaire on their prior knowledge of seven different domains related to the bioethical dilemma of prenatal diagnostics. The students read a text containing arguments for and arguments against prenatal diagnostics. After one week and again 12 weeks later they were asked to write down all the arguments they remembered. Prior knowledge helped them recall the arguments one week (r = .350 and 12 weeks (r = .316 later. Prior knowledge of three of the seven domains significantly helped them recall the arguments one week later (correlations between r = .194 to r = .394. Partial correlations with interest as a control item revealed that interest did not explain the relationship between prior knowledge and recall. Prior knowledge of different domains jointly supports the recall of arguments related to bioethical topics.

  6. Solutions of the coupled Higgs field equations.

    Science.gov (United States)

    Talukdar, Benoy; Ghosh, Swapan K; Saha, Aparna; Pal, Debabrata

    2013-07-01

    By an appropriate choice for the phase of the complex nucleonic field and going over to the traveling coordinate, we reduce the coupled Higgs equations to the Hamiltonian form and treat the resulting equation using the dynamical system theory. We present a phase-space analysis of its stable points. The results of our study demonstrate that the equation can support both traveling- and standing-wave solutions. The traveling-wave solution appears in the form of a soliton and resides in the midst of doubly periodic standing-wave solutions.

  7. Knowledge-guided gene ranking by coordinative component analysis.

    Science.gov (United States)

    Wang, Chen; Xuan, Jianhua; Li, Huai; Wang, Yue; Zhan, Ming; Hoffman, Eric P; Clarke, Robert

    2010-03-30

    In cancer, gene networks and pathways often exhibit dynamic behavior, particularly during the process of carcinogenesis. Thus, it is important to prioritize those genes that are strongly associated with the functionality of a network. Traditional statistical methods are often inept to identify biologically relevant member genes, motivating researchers to incorporate biological knowledge into gene ranking methods. However, current integration strategies are often heuristic and fail to incorporate fully the true interplay between biological knowledge and gene expression data. To improve knowledge-guided gene ranking, we propose a novel method called coordinative component analysis (COCA) in this paper. COCA explicitly captures those genes within a specific biological context that are likely to be expressed in a coordinative manner. Formulated as an optimization problem to maximize the coordinative effort, COCA is designed to first extract the coordinative components based on a partial guidance from knowledge genes and then rank the genes according to their participation strengths. An embedded bootstrapping procedure is implemented to improve statistical robustness of the solutions. COCA was initially tested on simulation data and then on published gene expression microarray data to demonstrate its improved performance as compared to traditional statistical methods. Finally, the COCA approach has been applied to stem cell data to identify biologically relevant genes in signaling pathways. As a result, the COCA approach uncovers novel pathway members that may shed light into the pathway deregulation in cancers. We have developed a new integrative strategy to combine biological knowledge and microarray data for gene ranking. The method utilizes knowledge genes for a guidance to first extract coordinative components, and then rank the genes according to their contribution related to a network or pathway. The experimental results show that such a knowledge-guided strategy

  8. ENTROPY CHARACTERISTICS IN MODELS FOR COORDINATION OF NEIGHBORING ROAD SECTIONS

    Directory of Open Access Journals (Sweden)

    N. I. Kulbashnaya

    2016-01-01

    Full Text Available The paper considers an application of entropy characteristics as criteria to coordinate traffic conditions at neighboring road sections. It has been proved that the entropy characteristics are widely used in the methods that take into account information influence of the environment on drivers and in the mechanisms that create such traffic conditions which ensure preservation of the optimal level of driver’s emotional tension during the drive. Solution of such problem is considered in the aspect of coordination of traffic conditions at neighboring road sections that, in its turn, is directed on exclusion of any driver’s transitional processes. Methodology for coordination of traffic conditions at neighboring road sections is based on the E. V. Gavrilov’s concept on coordination of some parameters of road sections which can be expressed in the entropy characteristics. The paper proposes to execute selection of coordination criteria according to accident rates because while moving along neighboring road sections traffic conditions change drastically that can result in creation of an accident situation. Relative organization of a driver’s perception field and driver’s interaction with the traffic environment has been selected as entropy characteristics. Therefore, the given characteristics are made conditional to the road accidents rate. The investigation results have revealed a strong correlation between the relative organization of the driver’s perception field and the relative organization of the driver’s interaction with the traffic environment and the accident rate. Results of the executed experiment have proved an influence of the accident rate on the investigated entropy characteristics.

  9. Local coordinates alignment with global preservation for dimensionality reduction.

    Science.gov (United States)

    Chen, Jing; Ma, Zhengming; Liu, Yang

    2013-01-01

    Dimensionality reduction is vital in many fields, and alignment-based methods for nonlinear dimensionality reduction have become popular recently because they can map the high-dimensional data into a low-dimensional subspace with the property of local isometry. However, the relationships between patches in original high-dimensional space cannot be ensured to be fully preserved during the alignment process. In this paper, we propose a novel method for nonlinear dimensionality reduction called local coordinates alignment with global preservation. We first introduce a reasonable definition of topology-preserving landmarks (TPLs), which not only contribute to preserving the global structure of datasets and constructing a collection of overlapping linear patches, but they also ensure that the right landmark is allocated to the new test point. Then, an existing method for dimensionality reduction that has good performance in preserving the global structure is used to derive the low-dimensional coordinates of TPLs. Local coordinates of each patch are derived using tangent space of the manifold at the corresponding landmark, and then these local coordinates are aligned into a global coordinate space with the set of landmarks in low-dimensional space as reference points. The proposed alignment method, called landmarks-based alignment, can produce a closed-form solution without any constraints, while most previous alignment-based methods impose the unit covariance constraint, which will result in the deficiency of global metrics and undesired rescaling of the manifold. Experiments on both synthetic and real-world datasets demonstrate the effectiveness of the proposed algorithm.

  10. Chromosomal differences between acute nonlymphocytic leukemia in patients with prior solid tumors and prior hematologic malignancies. A study of 14 cases with prior breast cancer

    Energy Technology Data Exchange (ETDEWEB)

    Mamuris, Z.; Dumont, J.; Dutrillaux, B.; Aurias, A. (Institut Curie, Paris (France))

    1989-10-01

    A cytogenetic study of 14 patients with secondary acute nonlymphocytic leukemia (S-ANLL) with prior treatment for breast cancer is reported. The chromosomes recurrently involved in numerical or structural anomalies are chromosomes 7, 5, 17, and 11, in decreasing order of frequency. The distribution of the anomalies detected in this sample of patients is similar to that observed in published cases with prior breast or other solid tumors, though anomalies of chromosome 11 were not pointed out, but it significantly differs from that of the S-ANLL with prior hematologic malignancies. This difference is principally due to a higher involvement of chromosome 7 in patients with prior hematologic malignancies and of chromosomes 11 and 17 in patients with prior solid tumors. A genetic determinism involving abnormal recessive alleles located on chromosomes 5, 7, 11, and 17 uncovered by deletions of the normal homologs may be a cause of S-ANLL. The difference between patients with prior hematologic malignancies or solid tumors may be explained by different constitutional mutations of recessive genes in the two groups of patients.

  11. Improving Coordination of Addiction Health Services Organizations with Mental Health and Public Health Services.

    Science.gov (United States)

    Guerrero, Erick G; Andrews, Christina; Harris, Lesley; Padwa, Howard; Kong, Yinfei; M S W, Karissa Fenwick

    2016-01-01

    In this mixed-method study, we examined coordination of mental health and public health services in addiction health services (AHS) in low-income racial and ethnic minority communities in 2011 and 2013. Data from surveys and semistructured interviews were used to evaluate the extent to which environmental and organizational characteristics influenced the likelihood of high coordination with mental health and public health providers among outpatient AHS programs. Coordination was defined and measured as the frequency of interorganizational contact among AHS programs and mental health and public health providers. The analytic sample consisted of 112 programs at time 1 (T1) and 122 programs at time 2 (T2), with 61 programs included in both periods of data collection. Forty-three percent of AHS programs reported high frequency of coordination with mental health providers at T1 compared to 66% at T2. Thirty-one percent of programs reported high frequency of coordination with public health services at T1 compared with 54% at T2. Programs with culturally responsive resources and community linkages were more likely to report high coordination with both services. Qualitative analysis highlighted the role of leadership in leveraging funding and developing creative solutions to deliver coordinated care. Overall, our findings suggest that AHS program funding, leadership, and cultural competence may be important drivers of program capacity to improve coordination with health service providers to serve minorities in an era of health care reform.

  12. Observing joint action: Coordination creates commitment.

    Science.gov (United States)

    Michael, John; Sebanz, Natalie; Knoblich, Günther

    2016-12-01

    Previous research has shown that interpersonal coordination enhances pro-social attitudes and behavior. Here, we extend this research by investigating whether the degree of coordination observed in a joint action enhances the perception of individuals' commitment to the joint action. In four experiments, participants viewed videos of joint actions. In the low coordination condition, two agents made independent individual contributions to a joint action. In the high coordination condition, the individual contributions were tightly linked. Participants judged whether and for how long the observed agents would resist a tempting outside option and remain engaged in the joint action. The results showed that participants were more likely to expect agents to resist outside options when observing joint actions with a high degree of coordination. This indicates that observing interpersonal coordination is sufficient to enhance the perception of commitment to joint action. Copyright © 2016 Elsevier B.V. All rights reserved.

  13. Control coordination abilities in shock combat sports

    Directory of Open Access Journals (Sweden)

    Natalya Boychenko

    2014-12-01

    Full Text Available Purpose: optimize the process control level of coordination abilities in martial arts. Material and Methods: analysis and compilation of scientific and methodological literature, interviews with coaches of drum martial arts, video analysis techniques, teacher observations. Results: identified specific types of coordination abilities in shock combat sports. Pod branny and offered specific and nonspecific tests to monitor the level of species athletes coordination abilities. Conclusion: it is determined that in order to achieve victory in the fight martial artists to navigate the space to be able to assess and manage dynamic and spatio-temporal parameters of movements, maintain balance, have a high coordination of movements. The proposed tests to monitor species coordination abilities athletes allow an objective assessment of not only the overall level of coordination, and the level of specific types of manifestations of this ability.

  14. Reaction Coordinates and Mechanistic Hypothesis Tests.

    Science.gov (United States)

    Peters, Baron

    2016-05-27

    Reaction coordinates are integral to several classic rate theories that can (a) predict kinetic trends across conditions and homologous reactions, (b) extract activation parameters with a clear physical interpretation from experimental rates, and (c) enable efficient calculations of free energy barriers and rates. New trajectory-based rare events methods can provide rates directly from dynamical trajectories without a reaction coordinate. Trajectory-based frameworks can also generate ideal (but abstract) reaction coordinates such as committors and eigenfunctions of the master equation. However, rates and mechanistic insights obtained from trajectory-based methods and abstract coordinates are not readily generalized across simulation conditions or reaction families. We discuss methods for identifying physically meaningful reaction coordinates, including committor analysis, variational transition state theory, Kramers-Langer-Berezhkovskii-Szabo theory, and statistical inference methods that can use path sampling data to screen, mix, and optimize thousands of trial coordinates. Special focus is given to likelihood maximization and inertial likelihood maximization approaches.

  15. Reaction Coordinates and Mechanistic Hypothesis Tests

    Science.gov (United States)

    Peters, Baron

    2016-05-01

    Reaction coordinates are integral to several classic rate theories that can (a) predict kinetic trends across conditions and homologous reactions, (b) extract activation parameters with a clear physical interpretation from experimental rates, and (c) enable efficient calculations of free energy barriers and rates. New trajectory-based rare events methods can provide rates directly from dynamical trajectories without a reaction coordinate. Trajectory-based frameworks can also generate ideal (but abstract) reaction coordinates such as committors and eigenfunctions of the master equation. However, rates and mechanistic insights obtained from trajectory-based methods and abstract coordinates are not readily generalized across simulation conditions or reaction families. We discuss methods for identifying physically meaningful reaction coordinates, including committor analysis, variational transition state theory, Kramers-Langer-Berezhkovskii-Szabo theory, and statistical inference methods that can use path sampling data to screen, mix, and optimize thousands of trial coordinates. Special focus is given to likelihood maximization and inertial likelihood maximization approaches.

  16. Characteristics of Trivalent Lanthanides in Coordination Chemistry

    Institute of Scientific and Technical Information of China (English)

    Xue Dongfeng(薛冬峰); Zuo Sen(左森); Henryk Ratajczak

    2004-01-01

    Some basic characteristics of lanthanide-oxygen bonds in various trivalent lanthanide metal-organic complexes are quantitatively studied by the bond valence model. Some important relationships among the electronegativity, bond valence parameter, bond length and lanthanide coordination number in these complexes are generally found , which show that for each trivalent lanthanide cation all calculated parameters may well be correlated with its coordination number in their coordination complexes. Specifically,32 new data for the bond valence parameter are first calculated in this work.An approximate linear relationship between the Ln-O bond valence parameter and the coordination number of Ln3+ is obtained.The Ln-O bond length increases with the increase in the lanthanide coordination number.The difference of electronegative values decreases with the increase in the lanthanide coordination number.

  17. Testability evaluation using prior information of multiple sources

    Institute of Scientific and Technical Information of China (English)

    Wang Chao; Qiu Jing; Liu Guanjun; Zhang Yong

    2014-01-01

    Testability plays an important role in improving the readiness and decreasing the life-cycle cost of equipment. Testability demonstration and evaluation is of significance in measuring such testability indexes as fault detection rate (FDR) and fault isolation rate (FIR), which is useful to the producer in mastering the testability level and improving the testability design, and helpful to the consumer in making purchase decisions. Aiming at the problems with a small sample of testabil-ity demonstration test data (TDTD) such as low evaluation confidence and inaccurate result, a test-ability evaluation method is proposed based on the prior information of multiple sources and Bayes theory. Firstly, the types of prior information are analyzed. The maximum entropy method is applied to the prior information with the mean and interval estimate forms on the testability index to obtain the parameters of prior probability density function (PDF), and the empirical Bayesian method is used to get the parameters for the prior information with a success-fail form. Then, a parametrical data consistency check method is used to check the compatibility between all the sources of prior information and TDTD. For the prior information to pass the check, the prior credibility is calculated. A mixed prior distribution is formed based on the prior PDFs and the corresponding credibility. The Bayesian posterior distribution model is acquired with the mixed prior distribution and TDTD, based on which the point and interval estimates are calculated. Finally, examples of a flying control system are used to verify the proposed method. The results show that the proposed method is feasible and effective.

  18. Testability evaluation using prior information of multiple sources

    Directory of Open Access Journals (Sweden)

    Wang Chao

    2014-08-01

    Full Text Available Testability plays an important role in improving the readiness and decreasing the life-cycle cost of equipment. Testability demonstration and evaluation is of significance in measuring such testability indexes as fault detection rate (FDR and fault isolation rate (FIR, which is useful to the producer in mastering the testability level and improving the testability design, and helpful to the consumer in making purchase decisions. Aiming at the problems with a small sample of testability demonstration test data (TDTD such as low evaluation confidence and inaccurate result, a testability evaluation method is proposed based on the prior information of multiple sources and Bayes theory. Firstly, the types of prior information are analyzed. The maximum entropy method is applied to the prior information with the mean and interval estimate forms on the testability index to obtain the parameters of prior probability density function (PDF, and the empirical Bayesian method is used to get the parameters for the prior information with a success-fail form. Then, a parametrical data consistency check method is used to check the compatibility between all the sources of prior information and TDTD. For the prior information to pass the check, the prior credibility is calculated. A mixed prior distribution is formed based on the prior PDFs and the corresponding credibility. The Bayesian posterior distribution model is acquired with the mixed prior distribution and TDTD, based on which the point and interval estimates are calculated. Finally, examples of a flying control system are used to verify the proposed method. The results show that the proposed method is feasible and effective.

  19. Increased coordination in public transport – which mechanisms are available?

    DEFF Research Database (Denmark)

    Sørensen, Claus Hedegaard; Longva, Frode

    2011-01-01

    After several years of New Public Management reforms within public transport, coordination seems to receive increased attention. With examples of actual as well as suggested changes taken from Denmark, Sweden and the UK the aim of the article is to analyse and classify the mechanisms utilized...... and suggested to increase coordination between core stakeholders within passenger railway services and bus services. Four distinctive mechanisms of coordination are suggested, namely organisational coordination, contractual coordination, partnership coordination and discursive coordination. Each coordination...

  20. Managing interteam coordination within and between organizations

    OpenAIRE

    de Vries, Thomas Arend

    2015-01-01

    To accomplish complex tasks and effectively respond to environmental contingencies, teams must coordinate task-related issues with other teams (i.e., interteam coordination). Regrettably, interteam coordination is often complicated by misunderstandings that can arise from differences in teams’ languages, routines, and goals. In this dissertation I examine organizational structures, team composition strategies, and individual team member characteristics that can help to overcome such difficult...

  1. Novel Coordination Chemistry of Aluminum Borohydride

    Science.gov (United States)

    2014-08-01

    four different crystal shapes were identified under a microscope.  Super thin plates are not a preferred crystal shape for X-ray analysis. Anion ...coordination of various ligands. Previously we investigated an IL based upon the [Al(BH4)4]- anion . This material showed a much improved air and...moisture stability compared to ABH. Here we present research on the coordination of the cyanoborohydride anion (NCBH3-) with ABH. The coordination

  2. Convergence of barycentric coordinates to barycentric kernels

    KAUST Repository

    Kosinka, Jiří

    2016-02-12

    We investigate the close correspondence between barycentric coordinates and barycentric kernels from the point of view of the limit process when finer and finer polygons converge to a smooth convex domain. We show that any barycentric kernel is the limit of a set of barycentric coordinates and prove that the convergence rate is quadratic. Our convergence analysis extends naturally to barycentric interpolants and mappings induced by barycentric coordinates and kernels. We verify our theoretical convergence results numerically on several examples.

  3. Axially symmetric solutions in f(R)-gravity

    CERN Document Server

    Capozziello, Salvatore; Stabile, Arturo

    2009-01-01

    Axially symmetric solutions for f(R)-gravity can be derived starting from exact spherically symmetric solutions. The method takes advantage of a complex coordinate transformation previously developed by Newman and Janis in General Relativity. An example is worked out to show the general validity of the approach.

  4. Stabilization of coordinated motion for underwater vehicles

    Institute of Scientific and Technical Information of China (English)

    Fan Wu; Zhi-Yong Geng

    2011-01-01

    This paper presents a coordinating and stabilizing control law for a group of underwater vehicles with unstable dynamics. The coordinating law is derived from a potential that only depends on the relative configuration of the underwater vehicles. Being coordinated, the group behaves like one mechanical system with symmetry, and we focus on stabilizing a family of coordinated motions, called relative equilibria. The stabilizing law is derived using energy shaping to stabilize the relative equilibria which involve each vehicle translating along its longest (unstable) axis without spinning,while maintaining a relative configuration within the group.The proposed control law is physically motivated and avoids the linearization or cancellation of nonlinearities.

  5. INVERSE DDA OF A SYSTEM OF BLOCKS IN SPHERE COORDINATES

    Institute of Scientific and Technical Information of China (English)

    WuYun; WangHui; ZhouShuoyu; ShiShunying

    2003-01-01

    In accordance with the geometric equations of elastic-mechanics in the sphere-coordinates, the displacement equation of blocks on asphere consisting of 6 deforming parameters is developed. The formula for distance between blocks is derived under the supposition that all block boundaries are prime arcs. The kinematic constraint and the penalty function for reasonable contact between blocks are developed. The normal equations and their coefficient matrix, based on the Least Squares Principle, are derived. The problem of adjudging penetration between blocks is discussed, and a solution is proposed.

  6. High School Students' Publication Rights and Prior Restraint.

    Science.gov (United States)

    Huffman, John L.; Trauth, Denise M.

    1981-01-01

    Federal court decisions on high school students' publication rights in the Second, Fourth, Fifth, and Seventh Circuits reveal substantial disagreement about school officials' power of prior restraint over student publications. The courts' opinions range from approval of broad powers of prior restraint to denial of any power. (Author/RW)

  7. 25 CFR 13.13 - Technical assistance prior to petitioning.

    Science.gov (United States)

    2010-04-01

    ... 25 Indians 1 2010-04-01 2010-04-01 false Technical assistance prior to petitioning. 13.13 Section... OF JURISDICTION OVER CHILD CUSTODY PROCEEDINGS Reassumption § 13.13 Technical assistance prior to... matters, Bureau agency and Area Offices shall provide technical assistance and make available any...

  8. Prior Abdominal Surgery Jeopardizes Quality of Resection in Colorectal Cancer

    NARCIS (Netherlands)

    Stommel, M.W.J.; Wilt, J.H.W. de; Broek, R.P.G ten; Strik, C.; Rovers, M.M.; Goor, H. van

    2016-01-01

    BACKGROUND: Prior abdominal surgery increases complexity of abdominal operations. Effort to prevent injury during adhesiolysis might result in less extensive bowel resection in colorectal cancer surgery. The aim of this study was to evaluate the effect of prior abdominal surgery on the outcome of

  9. Effects of Prior Knowledge on Memory: Implications for Education

    Science.gov (United States)

    Shing, Yee Lee; Brod, Garvin

    2016-01-01

    The encoding, consolidation, and retrieval of events and facts form the basis for acquiring new skills and knowledge. Prior knowledge can enhance those memory processes considerably and thus foster knowledge acquisition. But prior knowledge can also hinder knowledge acquisition, in particular when the to-be-learned information is inconsistent with…

  10. Source-specific Informative Prior for i-Vector Extraction

    DEFF Research Database (Denmark)

    Shepstone, Sven Ewan; Lee, Kong Aik; Li, Haizhou

    2015-01-01

    -informative, since for homogeneous datasets there is no gain in generality in using an informative prior. This work shows that extracting i-vectors for a heterogeneous dataset, containing speech samples recorded from multiple sources, using informative priors instead is applicable, and leads to favorable results...

  11. Designing conjoint choice experiments using managers' prior beliefs

    NARCIS (Netherlands)

    Sandor, Z; Wedel, M

    2001-01-01

    The authors provide more efficient designs for conjoint choice experiments based on prior information elicited from managers about the parameters and their associated uncertainty. The authors use a Bayesian design procedure that assumes a prior distribution of likely parameter values and optimizes

  12. 18 CFR 415.51 - Prior non-conforming structures.

    Science.gov (United States)

    2010-04-01

    ... 18 Conservation of Power and Water Resources 2 2010-04-01 2010-04-01 false Prior non-conforming... ADMINISTRATIVE MANUAL BASIN REGULATIONS-FLOOD PLAIN REGULATIONS Enforcement § 415.51 Prior non-conforming... this part): (a) A non-conforming structure in the floodway may not be expanded, except that it may...

  13. EEG Sequence Imaging: A Markov Prior for the Variational Garrote

    DEFF Research Database (Denmark)

    Hansen, Sofie Therese; Hansen, Lars Kai

    2013-01-01

    We propose the following generalization of the Variational Garrote for sequential EEG imaging: A Markov prior to promote sparse, but temporally smooth source dynamics. We derive a set of modied Variational Garrote updates and analyze the role of the prior's hyperparameters. An experimental evalua...

  14. Self-Assessment in University Assessment of Prior Learning Procedures

    Science.gov (United States)

    Brinke, D. Joosten-Ten; Sluijsmans, D. M. A.; Jochems, W. M. G.

    2009-01-01

    Competency-based university education, in which lifelong learning and flexible learning are key elements, demands a renewed vision on assessment. Within this vision, Assessment of Prior Learning (APL), in which learners have to show their prior learning in order for their goals to be recognised, becomes an important element. This article focuses…

  15. 7 CFR 1412.74 - Prior enrollment in DCP.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 10 2010-01-01 2010-01-01 false Prior enrollment in DCP. 1412.74 Section 1412.74... (ACRE) Program § 1412.74 Prior enrollment in DCP. (a) If a farm was enrolled in a DCP contract according... request to have the DCP contract withdrawn for that crop year. To participate in an annual ACRE...

  16. Portfolios for Prior Learning Assessment: Caught between Diversity and Standardization

    Science.gov (United States)

    Sweygers, Annelies; Soetewey, Kim; Meeus, Wil; Struyf, Elke; Pieters, Bert

    2009-01-01

    In recent years, procedures have been established in Flanders for "Prior Learning Assessment" (PLA) outside the formal learning circuit, of which the portfolio is a regular component. In order to maximize the possibilities of acknowledgement of prior learning assessment, the Flemish government is looking for a set of common criteria and…

  17. Academic Credit for Prior Learning: 2016 Progress Report

    Science.gov (United States)

    Washington Student Achievement Council, 2017

    2017-01-01

    Students come to college with skills and knowledge acquired through work, military, and other experiences. Academic credit for prior learning is awarded when a student's prior learning is assessed and found to be the equivalent of specific college course outcomes, and when the award of credit is consistent with the policies of the institution.…

  18. On the use of a pruning prior for neural networks

    DEFF Research Database (Denmark)

    Goutte, Cyril

    1996-01-01

    We address the problem of using a regularization prior that prunes unnecessary weights in a neural network architecture. This prior provides a convenient alternative to traditional weight-decay. Two examples are studied to support this method and illustrate its use. First we use the sunspots...

  19. Drunkorexia: Calorie Restriction Prior to Alcohol Consumption among College Freshman

    Science.gov (United States)

    Burke, Sloane C.; Cremeens, Jennifer; Vail-Smith, Karen; Woolsey, Conrad

    2010-01-01

    Using a sample of 692 freshmen at a southeastern university, this study examined caloric restriction among students prior to planned alcohol consumption. Participants were surveyed for self-reported alcohol consumption, binge drinking, and caloric intake habits prior to drinking episodes. Results indicated that 99 of 695 (14%) of first year…

  20. 28 CFR 2.9 - Study prior to sentencing.

    Science.gov (United States)

    2010-07-01

    ... 28 Judicial Administration 1 2010-07-01 2010-07-01 false Study prior to sentencing. 2.9 Section 2... PRISONERS, YOUTH OFFENDERS, AND JUVENILE DELINQUENTS United States Code Prisoners and Parolees § 2.9 Study prior to sentencing. When an adult Federal offender has been committed to an institution by...