WorldWideScience

Sample records for cooling crystallization process

  1. Investigation of lactose crystallization process during condensed milk cooling using native vacuum-crystallizer

    Directory of Open Access Journals (Sweden)

    E. I. Dobriyan

    2016-01-01

    Full Text Available One of the most general defects of condensed milk with sugar is its consistency heterogeneity – “candying”. The mentioned defect is conditioned by the presence of lactose big crystals in the product. Lactose crystals size up to 10 µm is not organoleptically felt. The bigger crystals impart heterogeneity to the consistency which can be evaluated as “floury”, “sandy”, “crunch on tooth”. Big crystals form crystalline deposit on the can or industrial package bottom in the form of thick layer. Industrial processing of the product with the defective process of crystallization results in the expensive equipment damage of the equipment at the confectionary plant accompanied with heavy losses. One of the factors influencing significantly lactose crystallization is the product cooling rate. Vacuum cooling is the necessary condition for provision of the product consistency homogeneity. For this purpose the vacuum crystallizers of “Vigand” company, Germany, are used. But their production in the last years has been stopped. All-Russian dairy research institute has developed “The references for development of the native vacuum crystallizer” according to which the industrial model has been manufactured. The produced vacuum – crystallizer test on the line for condensed milk with sugar production showed that the product cooling on the native vacuum-crystallizer guarantees production of the finished product with microstructure meeting the requirements of State standard 53436–2009 “Canned Milk. Milk and condensed cream with sugar”. The carried out investigations evidences that the average lactose crystals size in the condensed milk with sugar cooled at the native crystallizer makes up 6,78 µm. The granulometric composition of the product crystalline phase cooled at the newly developed vacuum-crystallizer is completely identical to granulometric composition of the product cooled at “Vigand” vacuum-crystallizer.

  2. Probing polymer crystallization at processing-relevant cooling rates with synchrotron radiation

    Energy Technology Data Exchange (ETDEWEB)

    Cavallo, Dario, E-mail: Dario.cavallo@unige.it [University of Genoa, Dept. of Chemistry and Industrial Chemistry, Via Dodecaneso 31, 16146 Genoa (Italy); Portale, Giuseppe [ESRF, Dubble CRG, Netherlands Organization of Scientific Research (NWO), 38043 Grenoble (France); Androsch, René [Martin-Luther-University Halle-Wittenberg, Center of Engineering Sciences, D-06099 Halle/S. (Germany)

    2015-12-17

    Processing of polymeric materials to produce any kind of goods, from films to complex objects, involves application of flow fields on the polymer melt, accompanied or followed by its rapid cooling. Typically, polymers solidify at cooling rates which span over a wide range, from a few to hundreds of °C/s. A novel method to probe polymer crystallization at processing-relevant cooling rates is proposed. Using a custom-built quenching device, thin polymer films are ballistically cooled from the melt at rates between approximately 10 and 200 °C/s. Thanks to highly brilliant synchrotron radiation and to state-of-the-art X-ray detectors, the crystallization process is followed in real-time, recording about 20 wide angle X-ray diffraction patterns per second while monitoring the instantaneous sample temperature. The method is applied to a series of industrially relevant polymers, such as isotactic polypropylene, its copolymers and virgin and nucleated polyamide-6. Their crystallization behaviour during rapid cooling is discussed, with particular attention to the occurrence of polymorphism, which deeply impact material’s properties.

  3. Nucleation control and separation of paracetamol polymorphs through swift cooling crystallization process

    Science.gov (United States)

    Sudha, C.; Srinivasan, K.

    2014-09-01

    Polymorphic nucleation behavior of pharmaceutical solid paracetamol has been investigated by performing swift cooling crystallization process. Saturated aqueous solution prepared at 318 K was swiftly cooled to 274 K in steps of every 1 K in the temperature range from 274 K to 313 K with uniform stirring of 100 rpm. The resultant supersaturation generated in the mother solution favours the nucleation of three different polymorphs of paracetamol. Lower supersaturation region σ=0.10-0.83 favours stable mono form I; the intermediate supersaturation region σ=0.92-1.28 favours metastable ortho form II and the higher supersaturation region σ=1.33-1.58 favours unstable form III polymorphic nucleation. Depending upon the level of supersaturation generated during swift cooling process and the corresponding solubility limit and metastable zone width (MSZW) of each polymorph, the nucleation of a particular polymorph occurs in the system. The type of polymorphs was identified by in-situ optical microscopy and the internal structure was confirmed by Powder X-ray diffraction (PXRD) study. By this novel approach, the preferred nucleation regions of all the three polymorphs of paracetamol are optimized in terms of different cooling ranges employed during the swift cooling process. Also solution mediated polymorphic transformations from unstable to mono and ortho to mono polymorphs have been studied by in-situ.

  4. Multi-scale simulation of single crystal hollow turbine blade manufactured by liquid metal cooling process

    Directory of Open Access Journals (Sweden)

    Xuewei Yan

    2018-02-01

    Full Text Available Liquid metal cooling (LMC process as a powerful directional solidification (DS technique is prospectively used to manufacture single crystal (SC turbine blades. An understanding of the temperature distribution and microstructure evolution in LMC process is required in order to improve the properties of the blades. For this reason, a multi-scale model coupling with the temperature field, grain growth and solute diffusion was established. The temperature distribution and mushy zone evolution of the hollow blade was simulated and discussed. According to the simulation results, the mushy zone might be convex and ahead of the ceramic beads at a lower withdrawal rate, while it will be concave and laggard at a higher withdrawal rate, and a uniform and horizontal mushy zone will be formed at a medium withdrawal rate. Grain growth of the blade at different withdrawal rates was also investigated. Single crystal structures were all selected out at three different withdrawal rates. Moreover, mis-orientation of the grains at 8 mm/min reached ~30°, while it was ~5° and ~15° at 10 mm/min and 12 mm/min, respectively. The model for predicting dendritic morphology was verified by corresponding experiment. Large scale for 2D dendritic distribution in the whole sections was investigated by experiment and simulation, and they presented a well agreement with each other. Keywords: Hollow blade, Single crystal, Multi-scale simulation, Liquid metal cooling

  5. Changes in copper sulfate crystal habit during cooling crystallization

    Science.gov (United States)

    Giulietti, M.; Seckler, M. M.; Derenzo, S.; Valarelli, J. V.

    1996-09-01

    The morphology of technical grade copper(II) sulfate pentahydrate crystals produced from batch cooling experiments in the temperature range of 70 to 30°C is described and correlated with the process conditions. A slow linear cooling rate (batch time of 90 min) predominantly caused the appearance of well-formed crystals. Exponential cooling (120 min) resulted in the additional formation of agglomerates and twins. The presence of seeds for both cooling modes led to round crystals, agglomerates and twins. Fast linear cooling (15 min) gave rise to a mixture of the former types. Broken crystals and adhering fragments were often found. Growth zoning was pronounced in seeded and linear cooling experiments. Fluid inclusions were always found and were more pronounced for larger particles. The occurrence of twinning, zoning and fluid inclusions was qualitatively explained in terms of fundamental principles.

  6. DKDP crystal growth controlled by cooling rate

    Science.gov (United States)

    Xie, Xiaoyi; Qi, Hongji; Shao, Jianda

    2017-08-01

    The performance of deuterated potassium dihydrogen phosphate (DKDP) crystal directly affects beam quality, energy and conversion efficiency in the Inertial Confinement Fusion(ICF)facility, which is related with the initial saturation temperature of solution and the real-time supersaturation during the crystal growth. However, traditional method to measure the saturation temperature is neither efficient nor accurate enough. Besides, the supersaturation is often controlled by experience, which yields the higher error and leads to the instability during the crystal growth. In this paper, DKDP solution with 78% deuteration concentration is crystallized in different temperatures. We study the relation between solubility and temperature of DKDP and fit a theoretical curve with a parabola model. With the model, the measurement of saturation temperature is simplified and the control precision of the cooling rate is improved during the crystal growth, which is beneficial for optimizing the crystal growth process.

  7. Process fluid cooling system

    International Nuclear Information System (INIS)

    Farquhar, N.G.; Schwab, J.A.

    1977-01-01

    A system of heat exchangers is disclosed for cooling process fluids. The system is particularly applicable to cooling steam generator blowdown fluid in a nuclear plant prior to chemical purification of the fluid in which it minimizes the potential of boiling of the plant cooling water which cools the blowdown fluid

  8. Second crystal cooling on cryogenically cooled undulator and wiggler double crystal monochromators

    International Nuclear Information System (INIS)

    Knapp, G. S.

    1998-01-01

    Simple methods for the cooling of the second crystals of cryogenically cooled undulator and wiggler double crystal monochromators are described. Copper braids between the first and second crystals are used to cool the second crystals of the double crystal monochromators. The method has proved successful for an undulator monochromator and we describe a design for a wiggler monochromator

  9. Time-resolved crystallization of deeply cooled liquid hydrogen isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Kuehnel, Matthias

    2014-02-15

    This thesis serves two main purposes: 1. The introduction of a novel experimental method to investigate phase change dynamics of supercooled liquids 2. First-time measurements for the crystallization behaviour for hydrogen isotopes under various conditions (1) The new method is established by the synergy of a liquid microjet of ∼ 5 μm diameter and a scattering technique with high spatial resolution, here linear Raman spectroscopy. Due to the high directional stability and the known velocity of the liquid filament, its traveling axis corresponds to a time axis static in space. Utilizing evaporative cooling in a vacuum environment, the propagating liquid cools down rapidly and eventually experiences a phase transition to the crystalline state. This temporal evolution is probed along the filament axis, ultimately resulting in a time resolution of 10 ns. The feasibility of this approach is proven successfully within the following experiments. (2) A main object of study are para-hydrogen liquid filaments. Raman spectra reveal a temperature gradient of the liquid across the filament. This behaviour can quantitatively be reconstructed by numerical simulations using a layered model and is rooted in the effectiveness of evaporative cooling on the surface and a finite thermal conductivity. The deepest supercoolings achieved are ∼ 30% below the melting point, at which the filament starts to solidify from the surface towards the core. With a crystal growth velocity extracted from the data the appropriate growth mechanism is identified. The crystal structure that initially forms is metastable and probably the result of Ostwald's rule of stages. Indications for a transition within the solid towards the stable equilibrium phase support this interpretation. The analog isotope ortho-deuterium is evidenced to behave qualitatively similar with quantitative differences being mass related. In further measurements, isotopic mixtures of para-hydrogen and ortho-deuterium are

  10. Time-resolved crystallization of deeply cooled liquid hydrogen isotopes

    International Nuclear Information System (INIS)

    Kuehnel, Matthias

    2014-02-01

    This thesis serves two main purposes: 1. The introduction of a novel experimental method to investigate phase change dynamics of supercooled liquids 2. First-time measurements for the crystallization behaviour for hydrogen isotopes under various conditions (1) The new method is established by the synergy of a liquid microjet of ∼ 5 μm diameter and a scattering technique with high spatial resolution, here linear Raman spectroscopy. Due to the high directional stability and the known velocity of the liquid filament, its traveling axis corresponds to a time axis static in space. Utilizing evaporative cooling in a vacuum environment, the propagating liquid cools down rapidly and eventually experiences a phase transition to the crystalline state. This temporal evolution is probed along the filament axis, ultimately resulting in a time resolution of 10 ns. The feasibility of this approach is proven successfully within the following experiments. (2) A main object of study are para-hydrogen liquid filaments. Raman spectra reveal a temperature gradient of the liquid across the filament. This behaviour can quantitatively be reconstructed by numerical simulations using a layered model and is rooted in the effectiveness of evaporative cooling on the surface and a finite thermal conductivity. The deepest supercoolings achieved are ∼ 30% below the melting point, at which the filament starts to solidify from the surface towards the core. With a crystal growth velocity extracted from the data the appropriate growth mechanism is identified. The crystal structure that initially forms is metastable and probably the result of Ostwald's rule of stages. Indications for a transition within the solid towards the stable equilibrium phase support this interpretation. The analog isotope ortho-deuterium is evidenced to behave qualitatively similar with quantitative differences being mass related. In further measurements, isotopic mixtures of para-hydrogen and ortho-deuterium are

  11. Time-resolved crystallization of deeply cooled liquid hydrogen isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Kuehnel, Matthias

    2014-02-15

    This thesis serves two main purposes: 1. The introduction of a novel experimental method to investigate phase change dynamics of supercooled liquids 2. First-time measurements for the crystallization behaviour for hydrogen isotopes under various conditions (1) The new method is established by the synergy of a liquid microjet of ∼ 5 μm diameter and a scattering technique with high spatial resolution, here linear Raman spectroscopy. Due to the high directional stability and the known velocity of the liquid filament, its traveling axis corresponds to a time axis static in space. Utilizing evaporative cooling in a vacuum environment, the propagating liquid cools down rapidly and eventually experiences a phase transition to the crystalline state. This temporal evolution is probed along the filament axis, ultimately resulting in a time resolution of 10 ns. The feasibility of this approach is proven successfully within the following experiments. (2) A main object of study are para-hydrogen liquid filaments. Raman spectra reveal a temperature gradient of the liquid across the filament. This behaviour can quantitatively be reconstructed by numerical simulations using a layered model and is rooted in the effectiveness of evaporative cooling on the surface and a finite thermal conductivity. The deepest supercoolings achieved are ∼ 30% below the melting point, at which the filament starts to solidify from the surface towards the core. With a crystal growth velocity extracted from the data the appropriate growth mechanism is identified. The crystal structure that initially forms is metastable and probably the result of Ostwald's rule of stages. Indications for a transition within the solid towards the stable equilibrium phase support this interpretation. The analog isotope ortho-deuterium is evidenced to behave qualitatively similar with quantitative differences being mass related. In further measurements, isotopic mixtures of para-hydrogen and ortho-deuterium are

  12. Effect of Cooling Rates on Shape and Crystal Size Distributions of Mefenamic Acid Polymorph in Ethyl Acetate

    Science.gov (United States)

    Mudalip, S. K. Abdul; Adam, F.; Parveen, J.; Abu Bakar, M. R.; Amran, N.; Sulaiman, S. Z.; Che Man, R.; Arshad, Z. I. Mohd; Shaarani, S. Md.

    2017-06-01

    This study investigate the effect of cooling rates on mefenamic acid crystallisation in ethyl acetate. The cooling rate was varied from 0.2 to 5 °C/min. The in-line conductivity system and turbidity system were employed to detect the onset of the crystallization process. The crystals produced were analysed using optical microscopy and Fourier transform infrared spectroscopy (FTIR). It was found that the crystals produced at different cooling rates were needle-like and exhibit polymorphic form type I. However, the aspect ratio and crystal size distributions were varied with the increased of cooling rate. A high crystals aspect ratio and narrower CSD (100-900 μm) was obtained at cooling rate of 0.5 °C/min. Thus, can be suggested as the most suitable cooling rate for crystallization of mefenamic acid in ethyl acetate.

  13. Preparation and cooling of magnesium ion crystals for sympathetic cooling of highly charged ions in a Penning trap

    Energy Technology Data Exchange (ETDEWEB)

    Murboeck, Tobias

    2017-07-01

    In this work, laser-cooled ion crystals containing 10{sup 3} to 10{sup 5} singly charged magnesium ions (Mg{sup +}) were prepared in a Penning trap. The properties of the ion crystals and their structure displaying long-range ordering were analyzed by various nondestructive techniques. After creation of the Mg{sup +} ions in the form of ion bunches in an external source, the ions were injected into the Penning trap where their temperature was reduced by eight orders of magnitude within seconds using a combination of buffer gas cooling and Doppler laser cooling. The achieved temperatures in the millikelvin-regime were close to the theoretical Doppler-cooling limit and sufficiently low to induce the transition to a crystal phase exhibiting long-range ordering. The structure of these mesoscopic ion crystals is in agreement with a model describing the crystal as a set of planar shells. This allows for a derivation of properties such as the charge density or the temperature of the observed crystals. For the process of combined buffer-gas and Doppler laser cooling an analytical model has been developed, which explains the time development of the temperature and the fluorescence signal in agreement with the experimental results. The external ion source for the production of singly charged magnesium ions was developed and characterized. A SIMION simulation of the ion creation and extraction process allows to describe the ion bunch structure and to increase the Mg{sup +} number by three orders of magnitude to 10{sup 6} Mg{sup +} ions per bunch. Other ion species with charge states between one (H{sup +}{sub 2}, C{sup +}, N{sup +}{sub 2}, CO{sup +}{sub 2}) and three (Ar{sup 3+}) were injected into the Mg{sup +} crystals. Ion crystals containing more than one ion species were observed with structures in agreement with the theory of centrifugal separation, which indicates sympathetic cooling of the non-fluorescing ion species. This preparation of mixed ion crystals is an

  14. Universal crystal cooling device for precession cameras, rotation cameras and diffractometers

    International Nuclear Information System (INIS)

    Hajdu, J.; McLaughlin, P.J.; Helliwell, J.R.; Sheldon, J.; Thompson, A.W.

    1985-01-01

    A versatile crystal cooling device is described for macromolecular crystallographic applications in the 290 to 80 K temperature range. It utilizes a fluctuation-free cold-nitrogen-gas supply, an insulated Mylar crystal cooling chamber and a universal ball joint, which connects the cooling chamber to the goniometer head and the crystal. The ball joint is a novel feature over all previous designs. As a result, the device can be used on various rotation cameras, precession cameras and diffractometers. The lubrication of the interconnecting parts with graphite allows the cooling chamber to remain stationary while the crystal and goniometer rotate. The construction allows for 360 0 rotation of the crystal around the goniometer axis and permits any settings on the arcs and slides of the goniometer head (even if working at 80 K). There are no blind regions associated with the frame holding the chamber. Alternatively, the interconnecting ball joint can be tightened and fixed. This results in a set up similar to the construction described by Bartunik and Schubert where the cooling chamber rotates with the crystal. The flexibility of the systems allows for the use of the device on most cameras or diffractometers. THis device has been installed at the protein crystallographic stations of the Synchrotron Radiation Source at Daresbury Laboratory and in the Laboratory of Molecular Biophysics, Oxford. Several data sets have been collected with processing statistics typical of data collected without a cooling chamber. Tests using the full white beam of the synchrotron also look promising. (orig./BHO)

  15. Process for cooling waste water

    Energy Technology Data Exchange (ETDEWEB)

    Rohner, P

    1976-12-16

    The process for avoiding thermal pollution of waters described rests on the principle of the heat conduction tube, by which heat is conducted from the liquid space into the atmosphere at a lower temperature above it. Such a tube, here called a cooling tube, consists in its simplest form of a heat conducting corrugated tube, made, for example, of copper or a copper alloy or of precious metals, which is sealed to be airtight at both ends, and after evacuation, is partially filled with a medium of low boiling point. The longer leg of the tube, which is bent at right angles, lies close below the surface of the water to be cooled and parallel to it; the shorter leg projects vertically into the atmosphere. The liquid inside the cooling tube fills the horizontal part of the tube to about halfway. A certain part of the liquid is always evaporated in this part. The vapor rising in the vertical part of the tube condenses on the internal wall cooled by the air outside, and gives off its heat to the atmosphere. The condensed medium flows back down the vertical internal wall into the initial position in a continuous cycle. A further development contains a smooth plastic inner tube in an outer corrugated tube, which is shorter than the outer tube; it ends at a distance from the caps sealing the outer tube at both ends. In this design the angle between the vertical and horizontal leg is less than 90/sup 0/. The shorter leg projects vertically from the water surface, below which the longer leg rises slightly from the knee of tube. The quantity of the liquid is gauged as a type of siphon, so that the space between the outer and inner tube at the knee of the tube remains closed by the liquid medium. The medium evaporated from the surface in the long leg of the tube therefore flows over the inner tube, which starts above the level of the medium. Thus evaporation and condensation paths are separated.

  16. Effect of cooling rate on crystallization in an aluminophosphosilicate melt

    DEFF Research Database (Denmark)

    Liu, S. J.; Zhang, Yanfei; Yue, Yuanzheng

    2011-01-01

    The effect of cooling rate on spontaneous crystallization behavior of an alumino-phospho-silicate melt is studied by means of differential scanning calorimetry, X-ray diffraction, scanning electron microscopy and viscometry. The cooling rates of 160, 2100 and 12000 K/s are attained by subjecting ......, the opalescence of the glass can be tuned by adjusting the cooling rate. This makes the production of opal glasses or transparent glass ceramics more efficient and energy saving, since the conventional isothermal treatment procedure can be left out....

  17. Investigation of the operating conditions to morphology evolution of β-L-glutamic acid during seeded cooling crystallization

    Science.gov (United States)

    Zhang, Fangkun; Liu, Tao; Huo, Yan; Guan, Runduo; Wang, Xue Z.

    2017-07-01

    In this paper the effects of operating conditions including cooling rate, initial supersaturation, and seeding temperature were investigated on the morphology evolution of β-L-glutamic acid (β-LGA) during seeded cooling crystallization. Based on the results of in-situ image acquisition of the crystal morphology evolution during the crystallization process, it was found that the crystal products tend to be plate-like or short rod-like under a slow cooling rate, low initial supersaturation, and low seeding temperature. In the opposite, the operating conditions of a faster cooling rate, higher initial supersaturation, and higher seeding temperature tend to produce long rod-like or needle-like crystals, and meanwhile, the length and width of crystal products will be increased together with a wider crystal size distribution (CSD). The aspect ratio of crystals, defined by the crystal length over width measured from in-situ or sample images, was taken as a shape index to analyze the crystal morphologies. Based on comparative analysis of the experimental results, guidelines on these operating conditions were given for obtaining the desired crystal shapes, along with the strategies for obtaining a narrower CSD for better product quality. Experimental verifications were performed to illustrate the proposed guidelines on the operating conditions for seeded cooling crystallization of LGA solution.

  18. Optimization of cooling strategy and seeding by FBRM analysis of batch crystallization

    Science.gov (United States)

    Zhang, Dejiang; Liu, Lande; Xu, Shijie; Du, Shichao; Dong, Weibing; Gong, Junbo

    2018-03-01

    A method is presented for optimizing the cooling strategy and seed loading simultaneously. Focused beam reflectance measurement (FBRM) was used to determine the approximating optimal cooling profile. Using these results in conjunction with constant growth rate assumption, modified Mullin-Nyvlt trajectory could be calculated. This trajectory could suppress secondary nucleation and has the potential to control product's polymorph distribution. Comparing with linear and two step cooling, modified Mullin-Nyvlt trajectory have a larger size distribution and a better morphology. Based on the calculating results, the optimized seed loading policy was also developed. This policy could be useful for guiding the batch crystallization process.

  19. Control of heat transfer in continuous-feeding Czochralski-silicon crystal growth with a water-cooled jacket

    Science.gov (United States)

    Zhao, Wenhan; Liu, Lijun

    2017-01-01

    The continuous-feeding Czochralski method is an effective method to reduce the cost of single crystal silicon. By promoting the crystal growth rate, the cost can be reduced further. However, more latent heat will be released at the melt-crystal interface under a high crystal growth rate. In this study, a water-cooled jacket was applied to enhance the heat transfer at the melt-crystal interface. Quasi-steady-state numerical calculation was employed to investigate the impact of the water-cooled jacket on the heat transfer at the melt-crystal interface. Latent heat released during the crystal growth process at the melt-crystal interface and absorbed during feedstock melting at the feeding zone was modeled in the simulations. The results show that, by using the water-cooled jacket, heat transfer in the growing crystal is enhanced significantly. Melt-crystal interface deflection and thermal stress increase simultaneously due to the increase of radial temperature at the melt-crystal interface. With a modified heat shield design, heat transfer at the melt-crystal interface is well controlled. The crystal growth rate can be increased by 20%.

  20. Cryogenic cooling of x-ray crystals using porous matrix

    International Nuclear Information System (INIS)

    Kuzay, T.M.

    1991-01-01

    It is well established that Si and SiC have very desirable thermophysical properties at cryogenic temperatures. This feature makes cryo-cooled optics potentially a good candidate for the first optical crystal of the presently built third generation synchrotron machines with very high heat flux levels. Currently, there is a great deal of interest in such cryo-cooled crystals pursued both experimentally and analytically. The analytical studies involve cut micro or capillary channel crystals. As opposed to the machined channels, porous matrices provide significant advantages. They operate very quietly. Such matrices are known to affect superior heat transfer enhancement. Data available in open literature suggest that surface heat flux levels up to ∼8 kW/cm 2 are possible. For cryogens for which the boiling heat transfer heat flux is rather a low value in conventional geometries, the enhancement available with such matrices is a very significant characteristic. Cryogens are poor thermal conductors themselves. The fact that at the cryogenic temperatures the Si and/or SiC matrix itself becomes highly conductive, the matrix distributes the surface heat flux into the full volume effectively offsetting the poor conductivity of the coolant. In addition the tortuous path of the coolant through the matrix increases the dwell time for better heat transfer, however, at the expense of increased pressure drop. In this study, thermal conductivity of such composite matrices and the effective heat transfer coefficient obtainable using them are investigated. A first optics crystal model of Si with Si and/or Sic porous matrix as its heat exchanger and subject to prototype synchrotron level heat flux is analyzed and limits of the cooling possible with liquid nitrogen in single phase and subcooled boiling heat transfer modes are delineated

  1. Deposit control in process cooling water systems

    International Nuclear Information System (INIS)

    Venkataramani, B.

    1981-01-01

    In order to achieve efficient heat transfer in cooling water systems, it is essential to control the fouling of heat exchanger surfaces. Solubilities of scale forming salts, their growth into crystals, and the nature of the surfaces play important roles in the deposition phenomenon. Condensed phosphates, organic polymers and compounds like phosphates are effective in controlling deposition of scale forming salts. The surface active agents inhibit crystal growth and modify the crystals of the scale forming salts, and thus prevent deposition of dense, uniformly structured crystalline mass on the heat transfer surface. Understanding the mechanism of biofouling is essential to control it by surface active agents. Certain measures taken in the plant, such as back flushing, to control scaling, sometimes may not be effective and can be detrimental to the system itself. (author)

  2. Transparent phosphosilicate glasses containing crystals formed during cooling of melts

    DEFF Research Database (Denmark)

    Liu, S. J.; Zhang, Yanfei; He, W.

    2011-01-01

    The effect of P2O5-SiO2 substitution on spontaneous crystallization of SiO2-Al2O3-P2O5- Na2O-MgO melts during cooling was studied by X-ray diffraction (XRD), differential scanning calorimetry (DSC), scanning electron microscopy (SEM) and rotation viscometry. Results show that addition of P2O5 leads...... to amorphous phase separation (APS), i.e., phosphate- and silicate-rich phases. It is due to the tendency of Mg2+ to form [MgO4] linking with [SiO4]. Molar substitution of P2O5 for SiO2 enhances the network polymerization of silicate-rich phase in the melts, and thereby the spontaneous crystallization of cubic...... Na2MgSiO4 is also enhanced during cooling of the melts. In addition, the sizes of the local crystalline and separated glassy domains are smaller than the wavelength of the visible light, and this leads to the transparency of the obtained glasses containing crystals....

  3. Heating and cooling processes in disks*

    Directory of Open Access Journals (Sweden)

    Woitke Peter

    2015-01-01

    Full Text Available This chapter summarises current theoretical concepts and methods to determine the gas temperature structure in protoplanetary disks by balancing all relevant heating and cooling rates. The processes considered are non-LTE line heating/cooling based on the escape probability method, photo-ionisation heating and recombination cooling, free-free heating/cooling, dust thermal accommodation and high-energy heating processes such as X-ray and cosmic ray heating, dust photoelectric and PAH heating, a number of particular follow-up heating processes starting with the UV excitation of H2, and the release of binding energy in exothermal reactions. The resulting thermal structure of protoplanetary disks is described and discussed.

  4. Systematic Procedure for Generating Operational Policies to Achieve Target Crystal Size Distribution (CSD) in Batch Cooling Crystallization

    DEFF Research Database (Denmark)

    Abdul Samad, Noor Asma Fazli; Singh, Ravendra; Sin, Gürkan

    2011-01-01

    Batch cooling crystallization is one of the important unit operations involving separation of solid-liquid phases. Usually the most common crystal product qualities are directly related to the crystal size distribution (CSD). However the main difficulty in batch crystallization is to obtain a uni...

  5. Resistive cooling circuits for charged particle traps using crystal resonators

    CERN Document Server

    Kaltenbacher, T; Doser, M; Kellerbauer, A; Pribyl, W

    2011-01-01

    The paper addresses a novel method to couple a signal from charged particles in a Penning trap to a high Q resonant circuit using a crystal resonator. Traditionally the trap capacity is converted into a resonator by means of an inductance. When normal conducting wires (e.g. copper) are applied to build up a coil, the unloaded Q value is limited to a value in the order of 1000. The tuned circuit’s Q factor is directly linked to the input impedance “seen” by the trapped particles at resonance frequency. This parallel resonance impedance is a measure of the efficiency of resistive cooling and thus it should be optimized. We propose here a commercially available crystal resonator since it exhibits a very high Q value and a parallel resonance impedance of several MOhm. The possibility to tune the parallel resonance frequency of the quartz results in filter behavior that allows covering a broad range of frequencies.

  6. Fabrication process of expanded cooling jackets

    International Nuclear Information System (INIS)

    Weber, C.M.

    1980-01-01

    The present invention concerns the fabrication process of heat exchangers and in particular, the fabrication and assembly process of cooling jackets of the system driving the control rods used in nuclear reactors. The cooling jackets are assembled for cooling the stator of a tubular motor displacing the control rods. The fabrication and assembling of the cooling jacket is made up by the following operations: - a sleeve has an inner fluid inlet and outlet ways, - an external socket is fitted to the sleeve, - on the external socket a continuous welding is realized, which join the socket to the sleeve, and define a serie of parallel welded turns, - a pressure is established between the sleeve and the socket by a fluid through the outlet or inlet ways of the sleeve. When the other way is sealed up, the socket expands between the welded turns, and the fluid can pass through the jacket [fr

  7. Magnonic crystals for data processing

    International Nuclear Information System (INIS)

    Chumak, A V; Serga, A A; Hillebrands, B

    2017-01-01

    Magnons (the quanta of spin waves) propagating in magnetic materials with wavelengths at the nanometer-scale and carrying information in the form of an angular momentum can be used as data carriers in next-generation, nano-sized low-loss information processing systems. In this respect, artificial magnetic materials with properties periodically varied in space, known as magnonic crystals, are especially promising for controlling and manipulating magnon currents. In this article, different approaches for the realization of static, reconfigurable, and dynamic magnonic crystals are presented along with a variety of novel wave phenomena discovered in these crystals. Special attention is devoted to the utilization of magnonic crystals for processing of analog and digital information. (paper)

  8. Device for isolation of seed crystals during processing of solution

    Science.gov (United States)

    Montgomery, K.E.; Zaitseva, N.P.; Deyoreo, J.J.; Vital, R.L.

    1999-05-18

    A device is described for isolation of seed crystals during processing of solutions. The device enables a seed crystal to be introduced into the solution without exposing the solution to contaminants or to sources of drying and cooling. The device constitutes a seed protector which allows the seed to be present in the growth solution during filtration and overheating operations while at the same time preventing the seed from being dissolved by the under saturated solution. When the solution processing has been completed and the solution cooled to near the saturation point, the seed protector is opened, exposing the seed to the solution and allowing growth to begin. 3 figs.

  9. Incorporation of cooling-induced crystallization into a 2-dimensional axisymmetric conduit heat flow model

    Science.gov (United States)

    Heptinstall, David; Bouvet de Maisonneuve, Caroline; Neuberg, Jurgen; Taisne, Benoit; Collinson, Amy

    2016-04-01

    Heat flow models can bring new insights into the thermal and rheological evolution of volcanic 3 systems. We shall investigate the thermal processes and timescales in a crystallizing, static 4 magma column, with a heat flow model of Soufriere Hills Volcano (SHV), Montserrat. The latent heat of crystallization is initially computed with MELTS, as a function of pressure and temperature for an andesitic melt (SHV groundmass starting composition). Three fractional crystallization simulations are performed; two with initial pressures of 34MPa (runs 1 & 2) and one of 25MPa (run 3). Decompression rate was varied between 0.1MPa/° C (runs 1 & 3) and 0.2MPa/° C (run 2). Natural and experimental matrix glass compositions are accurately reproduced by all MELTS runs. The cumulative latent heat released for runs 1, 2 and 3 differs by less than 9% (8.69E5 J/kg*K, 9.32E5 J/kg*K, and 9.49E5 J/kg*K respectively). The 2D axisymmetric conductive cooling simulations consider a 30m-diameter conduit that extends from the surface to a depth of 1500m (34MPa). The temporal evolution of temperature is closely tracked at depths of 10m, 750m and 1400m in the centre of the conduit, at the conduit walls, and 20m from the walls into the host rock. Following initial cooling by 7-15oC at 10m depth inside the conduit, the magma temperature rebounds through latent heat release by 32-35oC over 85-123 days to a maximum temperature of 1002-1005oC. At 10m depth, it takes 4.1-9.2 years for the magma column to cool by 108-131oC and crystallize to 75wt%, at which point it cannot be easily remobilized. It takes 11-31.5 years to reach the same crystallinity at 750-1400m depth. We find a wide range in cooling timescales, particularly at depths of 750m or greater, attributed to the initial run pressure and the dominant latent heat producing crystallizing phase, Albite-rich Plagioclase Feldspar. Run 1 is shown to cool fastest and run 3 cool the slowest, with surface emissivity having the strongest cooling

  10. Cooling water systems design using process integration

    CSIR Research Space (South Africa)

    Gololo, KV

    2010-09-01

    Full Text Available Cooling water systems are generally designed with a set of heat exchangers arranged in parallel. This arrangement results in higher cooling water flowrate and low cooling water return temperature thus reducing cooling tower efficiency. Previous...

  11. Processes influencing cooling of reactor effluents

    International Nuclear Information System (INIS)

    Magoulas, V.E.; Murphy, C.E. Jr.

    1982-01-01

    Discharge of heated reactor cooling water from SRP reactors to the Savannah River is through sections of stream channels into the Savannah River Swamp and from the swamp into the river. Significant cooling of the reactor effluents takes place in both the streams and swamp. The majority of the cooling is through processes taking place at the surface of the water. The major means of heat dissipation are convective transfer of heat to the air, latent heat transfer through evaporation and radiative transfer of infrared radiation. A model was developed which incorporates the effects of these processes on stream and swamp cooling of reactor effluents. The model was used to simulate the effect of modifications in the stream environment on the temperature of water flowing into the river. Environmental effects simulated were the effect of changing radiant heat load, the effect of changes in tree canopy density in the swamp, the effect of total removal of trees from the swamp, and the effect of diverting the heated water from L reactor from Steel Creek to Pen Branch. 6 references, 7 figures

  12. On-line monitoring of the crystallization process: relationship between crystal size and electrical impedance spectra

    International Nuclear Information System (INIS)

    Zhao, Yanlin; Yao, Jun; Wang, Mi

    2016-01-01

    On-line monitoring of crystal size in the crystallization process is crucial to many pharmaceutical and fine-chemical industrial applications. In this paper, a novel method is proposed for the on-line monitoring of the cooling crystallization process of L-glutamic acid (LGA) using electrical impedance spectroscopy (EIS). The EIS method can be used to monitor the growth of crystal particles relying on the presence of an electrical double layer on the charged particle surface and the polarization of double layer under the excitation of alternating electrical field. The electrical impedance spectra and crystal size were measured on-line simultaneously by an impedance analyzer and focused beam reflectance measurement (FBRM), respectively. The impedance spectra were analyzed using the equivalent circuit model and the equivalent circuit elements in the model can be obtained by fitting the experimental data. Two equivalent circuit elements, including capacitance ( C 2 ) and resistance ( R 2 ) from the dielectric polarization of the LGA solution and crystal particle/solution interface, are in relation with the crystal size. The mathematical relationship between the crystal size and the equivalent circuit elements can be obtained by a non-linear fitting method. The function can be used to predict the change of crystal size during the crystallization process. (paper)

  13. Sympathetic cooling and crystallization of ions in a linear Paul trap

    International Nuclear Information System (INIS)

    Drewsen, M.; Bowe, P.; Hornekaer, L.; Brodersen, C.; Schiffer, J.P.; Hangst, J.S.; Schiffer, J.P.

    1999-01-01

    Coulomb crystals, containing up to a few hundred ions of which more than 50% were cooled sympathetically by the Coulomb interaction with laser cooled Mg + ions, have been produced in a linear Paul trap. By controlling the balance of the radiation pressure from the two cooling lasers, the Coulomb crystals could be segregated according to ion species. Previous studies of ion crystals and molecular dynamics simulations suggest that the temperature may be around 10 mK or lower. The obtained results indicate that a wide range of atomic and molecular ions, which due to their internal structures are not amenable to direct laser cooling, can be effectively cooled and localized (crystallized) in linear Paul traps. For high resolution spectroscopy of such ions this may turn out to be very useful. copyright 1999 American Institute of Physics

  14. 40 CFR 63.1329 - Process contact cooling towers provisions.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 11 2010-07-01 2010-07-01 true Process contact cooling towers... Process contact cooling towers provisions. (a) The owner or operator of each new affected source that... end finisher process that utilizes a process contact cooling tower shall comply with paragraph (c) of...

  15. Heat pipe cooling of power processing magnetics

    Science.gov (United States)

    Hansen, I. G.; Chester, M.

    1979-01-01

    The constant demand for increased power and reduced mass has raised the internal temperature of conventionally cooled power magnetics toward the upper limit of acceptability. The conflicting demands of electrical isolation, mechanical integrity, and thermal conductivity preclude significant further advancements using conventional approaches. However, the size and mass of multikilowatt power processing systems may be further reduced by the incorporation of heat pipe cooling directly into the power magnetics. Additionally, by maintaining lower more constant temperatures, the life and reliability of the magnetic devices will be improved. A heat pipe cooled transformer and input filter have been developed for the 2.4 kW beam supply of a 30-cm ion thruster system. This development yielded a mass reduction of 40% (1.76 kg) and lower mean winding temperature (20 C lower). While these improvements are significant, preliminary designs predict even greater benefits to be realized at higher power. This paper presents the design details along with the results of thermal vacuum operation and the component performance in a 3 kW breadboard power processor.

  16. Choice of cooling regime of the superconducting magnetic system of the ''Crystal-2'' torsatron

    International Nuclear Information System (INIS)

    Glasov, B.V.; Druj, O.S.; Kurnosov, V.I.; Skibenko, E.I.; Yuferov, V.B.

    1981-01-01

    General requirements to a system of cryogenic cooling of superconducting magnetic systems (SMS) are formulated. Distributions of the value of thermal stresses about the temperature range are obtained for basic construction materials of SMS ''Crystal-2'' torsatron. Concrete circuits of SMS cryoprovision are considered. Values of specific and total heat capacity of the system, specific consumption of liquid are determined taking into consideration constructional peculiarities of SMS of''Crystal-2'' plant. Efficiency of different ways of SMS cooling are estimated, dynamical dependences of cooling and heating of SMS of the ''Crystal-2'' plant are obtained taking this into consideration [ru

  17. Liquid gallium cooling of silicon crystals in high intensity photon beams

    International Nuclear Information System (INIS)

    Smither, R.K.; Forster, G.A.; Bilderback, D.H.; Bedzyk, M.; Finkelstein, K.; Henderson, C.; White, J.; Berman, L.E.; Stefan, P.; Oversluizen, T.

    1989-01-01

    The high-brilliance, insertion-device-based photon beams of the next generation of synchrotron sources (Argonne's APS and Grenoble's ESRF) will deliver large thermal loads (1--10 kW) to the first optical elements. Considering the problems that present synchrotron users are experiencing with beams from recently installed insertion devices, new and improved methods of cooling these first optical elements, particularly when they are diffraction crystals, are clearly needed. A series of finite element calculations were performed to test the efficiency of new cooling geometries and various cooling fluids. The best results were obtained with liquid Ga metal flowing in channels just below the surface of the crystal. Ga was selected because of its good thermal conductivity and thermal capacity, low melting point, high boiling point, low kinetic viscosity, and very low vapor pressure. Its very low vapor pressure, even at elevated temperatures, makes it especially attractive in UHV conditions. A series of experiments were conducted at CHESS in February of 1988 that compared liquid gallium-cooled silicon diffraction crystals with water-cooled crystals. A six-pole wiggler beam was used to perform these tests on three different Si crystals, two with new cooling geometries and the one presently in use. A special high-pressure electromagnetic induction pump, recently developed at Argonne, was used to circulate the liquid gallium through the silicon crystals. In all experiments, the specially cooled crystal was used as the first crystal in a two crystal monochromator. An infrared camera was used to monitor the thermal profiles and correlated them with rocking curve measurements. A second set of cooling experiments were conducted in June of 1988 that used the intense, highly collimated beam from the newly installed ANL/CHESS undulator

  18. Rapid cooling and cold storage in a silicic magma reservoir recorded in individual crystals.

    Science.gov (United States)

    Rubin, Allison E; Cooper, Kari M; Till, Christy B; Kent, Adam J R; Costa, Fidel; Bose, Maitrayee; Gravley, Darren; Deering, Chad; Cole, Jim

    2017-06-16

    Silicic volcanic eruptions pose considerable hazards, yet the processes leading to these eruptions remain poorly known. A missing link is knowledge of the thermal history of magma feeding such eruptions, which largely controls crystallinity and therefore eruptability. We have determined the thermal history of individual zircon crystals from an eruption of the Taupo Volcanic Zone, New Zealand. Results show that although zircons resided in the magmatic system for 10 3 to 10 5 years, they experienced temperatures >650° to 750°C for only years to centuries. This implies near-solidus long-term crystal storage, punctuated by rapid heating and cooling. Reconciling these data with existing models of magma storage requires considering multiple small intrusions and multiple spatial scales, and our approach can help to quantify heat input to and output from magma reservoirs. Copyright © 2017, American Association for the Advancement of Science.

  19. The hardness of synthetic products obtained from cooled and crystallized basaltic melts (in Romanian)

    OpenAIRE

    Daniela Ogrean

    2001-01-01

    The Hardness of Synthetic Products Obtained from Cooled and Crystallized Basaltic Melts. Hardness is one of the main properties of the products obtained from cooled and crystallized basaltic melts under a controlled thermal regime. It influences the abrasion tear resistance of the resulted material. The microhardness measurements on the samples (bricks, boards, gutters, armour plates, tubes) indicated Vickers hardness value between 757–926 for the materials obtained from Şanovita basalts (Tim...

  20. Desalting a process cooling water using nanofiltration

    NARCIS (Netherlands)

    Radier, R.G.J.; van Oers, C.W.; Steenbergen, A.; Wessling, Matthias

    2001-01-01

    The cooling water system of a chemical plant of Akzo Nobel is a partly open system. The site is located at the North Sea. The air in contact with the cooling water contains seawater droplets dissolving and increasing the chloride concentration. The cooling water contains chromate to protect the

  1. Modelisation and numerical simulation for bulk crystal growth processes

    International Nuclear Information System (INIS)

    Duffar, F.; Dusserre, P.; Barat, C.; Nabot, J.P.

    1993-01-01

    The aim of this work is to study the relevance of numerical simulation for improving the process control in the field of crystal growth. This investigation focused on the growth of semiconductor and halide crystals by the Bridgman solidification technique, the principle of which is to cool a seeded feed material contained in a crucible, either by pulling the crucible or by decreasing the temperature in the furnace. Calculations are performed with the finite element method, and for comparison, experiments are carried out on Bridgman pulling machines operating either in a laboratory or in industrial plants. Calculations and experimental data have shown a good agreement and a satisfactory reliability

  2. Calculation of thermal deformations in water-cooled monochromator crystals

    International Nuclear Information System (INIS)

    Nakamura, Ario; Hashimoto, Shinya; Motohashi, Haruhiko

    1994-11-01

    Through calculation of temperature distribution and thermal deformation of monochromators, optical degradation by the heat loads in SPring-8 have been discussed. Cooling experiments were made on three models of copper structures with the JAERI Electron Beam Irradiation Stand (JEBIS) and the results were used to estimate heat transfer coefficients in the models. The heat transfer coefficients have been adopted to simulate heating processes on silicon models of the same structures as the copper models, for which radiations from the SPring-8 bending magnet and the JAERI prototype undulator (WPH-33J) were considered. It has been concluded that, in the case of bending magnet (with power density of 0.27[MW/m 2 ] on monochromator surface), the temperature at the surface center reaches about 30[degC] from the initial temperature of 27[degC] in all the models. In the case of WPH-33J (with power density of 8.2[MW/m 2 ]), the temperature reaches about 200 to 280[degC] depending on the models. The radiation from WPH-33J yields slope errors bigger than the Darwin's width(23[μrad]). (author)

  3. Structure evolution during the cooling and coalesced cooling processes of Cu-Co bimetallic clusters

    International Nuclear Information System (INIS)

    Li Guojian; Wang Qiang; Li Donggang; Lue Xiao; He Jicheng

    2008-01-01

    Constant-temperature molecular dynamics with general EAM was employed to study the structure evolutions during the cooling and coalesced cooling processes of Cu-Co bimetallic clusters. It shows that the desired particle morphologies and structures can be obtained by controlling the composition and distribution of hetero atoms during synthesis process

  4. Composition dependence of spontaneous crystallization of phosphosilicate glass melts during cooling

    DEFF Research Database (Denmark)

    Liu, S.J.; Zhu, C.F.; Zhang, Y.F.

    2012-01-01

    Crystallization behavior of alumino-phospho-silicate melts during cooling is studied by means of the differential scanning calorimetry, X-ray diffractometry and viscometry. The results show a pronounced impact of alkaline earth oxide, alkali oxide and fluoride on the crystal type and crystallizat......Crystallization behavior of alumino-phospho-silicate melts during cooling is studied by means of the differential scanning calorimetry, X-ray diffractometry and viscometry. The results show a pronounced impact of alkaline earth oxide, alkali oxide and fluoride on the crystal type...... and crystallization degree. It is found that adding NaF into the studied compositions slightly decreases melt fragility and improves both the glass-forming ability and melt workability. This effect is associated with the unique structural role of NaF compared to the other modifier oxides. It is also found...

  5. Nonlinear MIMO Control of a Continuous Cooling Crystallizer

    Directory of Open Access Journals (Sweden)

    Pedro Alberto Quintana-Hernández

    2012-01-01

    Full Text Available In this work, a feedback control algorithm was developed based on geometric control theory. A nonisothermal seeded continuous crystallizer model was used to test the algorithm. The control objectives were the stabilization of the third moment of the crystal size distribution (μ3 and the crystallizer temperature (T; the manipulated variables were the stirring rate and the coolant flow rate. The nonlinear control (NLC was tested at operating conditions established within the metastable zone. Step changes of magnitudes ±0.0015 and ±0.5°C were introduced into the set point values of the third moment and crystallizer temperature, respectively. In addition, a step change of ±1°C was introduced as a disturbance in the feeding temperature. Closed-loop stability was analyzed by calculating the eigenvalues of the internal dynamics. The system presented a stable dynamic behavior when the operation conditions maintain the crystallizer concentration within the metastable zone. Closed-loop simulations with the NLC were compared with simulations that used a classic PID controller. The PID controllers were tuned by minimizing the integral of the absolute value of the error (IAE criterion. The results showed that the NLC provided a suitable option for continuous crystallization control. For all analyzed cases, the IAEs obtained with NLC were smaller than those obtained with the PID controller.

  6. Cooling process in separation devices of krypton gas

    Energy Technology Data Exchange (ETDEWEB)

    Kimura, S; Sugimoto, K

    1975-06-11

    To prevent entry of impurities into purified gases and to detect leaks of heat exchanger in a separation and recovering device of krypton gas by means of liquefaction and distillation, an intermediate refrigerant having the same or slightly higher boiling point than that of gas to be cooled is used between the gas to be cooled (process gas) and refrigerant (nitrogen), and the pressure of the gas to be cooled is controlled to have a pressure higher than the intermediate refrigerant to cool the gas to be cooled.

  7. Liquid gallium cooling of silicon crystals in high intensity photon beam

    International Nuclear Information System (INIS)

    Smither, R.K.; Forster, G.A.; Bilderback, D.H.

    1988-11-01

    The high-brilliance, insertion-device-based, photon beams of the next generation of synchrotron sources will deliver large thermal loads (1 kW to 10 kW) to the first optical elements. Considering the problems that present synchrotron users are experiencing with beams from recently installed insertion devices, new and improved methods of cooling these first optical elements, particularly when they are diffraction crystals, are clearly needed. A series of finite element calculations were performed to test the efficiency of new cooling geometries and new cooling fluids. The best results were obtained with liquid Ga metal flowing in channels just below the surface of the crystal. Ga was selected because of its good thermal conductivity and thermal capacity, low melting point, high boiling point, low kinetic viscosity, and very low vapor pressure. Its very low vapor pressure, even at elevated temperatures, makes it especially attractive in uhv conditions. A series of experiments were conducted at CHESS in February of 1988 that compared liquid gallium cooled silicon diffraction crystals with water cooled crystals. 2 refs., 16 figs., 1 tab

  8. Design of a cryo-cooled artificial channel-cut crystal monochromator for the European XFEL

    Energy Technology Data Exchange (ETDEWEB)

    Dong, Xiaohao, E-mail: xiaohao.dong@xfel.eu; Sinn, Harald, E-mail: harald.sinn@xfel.eu [European XFEL GmbH, Hamburg, D-22761 (Germany); Shu, Deming, E-mail: shu@aps.anl.gov [Argonne National Laboratory, Argonne, IL 60439, U.S.A (United States)

    2016-07-27

    An artificial channel-cut crystal monochromator for the hard X-Ray beamlines of SASE 1&2, cryogenically cooled by the so-called pulse tube cooler (cryorefrigerator), is currently under development at the European XFEL ( http://www.xfel.eu/ ). The fabrication is on-going. We present here the crystal optical consideration and the novel cooling configuration, according to the X-Ray FEL pulses proprieties. The mechanical design improvements are pointed out as well to implement such kind of monochromator based on the previous similar design.

  9. Multi-dimensional population balance models of crystallization processes

    DEFF Research Database (Denmark)

    Meisler, Kresten Troelstrup; von Solms, Nicolas

    A generic and model-based framework for batch cooling crystallization operations has been extended to incorporate continuous and fed-batch processes. Modules for the framework have been developed, including a module for reactions, allowing the study of reactive crystallization within the framework....... A kinetic model library together with an ontology for knowledge representation has been developed, in which kinetic models and relations from the literature are stored along with the references and data. The model library connects to the generic modelling framework as well, as models can be retrieved......, analyzed, used for simulation and stored again. The model library facilitates comparison of expressions for kinetic phenomena and is tightly integrated with the model analysis tools of the framework.Through the framework, a model for a crystallization operation may be systematically generated...

  10. Strategies for Processing Semen from Subfertile Stallions for Cooled Transport.

    Science.gov (United States)

    Varner, Dickson D

    2016-12-01

    Subfertility can be a confusing term because some semen of good quality can have reduced fertility following cooled transport if the semen is processed in an improper manner. General procedures aimed at processing stallion semen for cooled transport are well described. An array of factors could exist in reduced fertility of cool-transported semen. This article focuses on centrifugation techniques that can be used to maximize sperm quality of stallions whose semen is intended for cooled transport. Clinical cases are also provided for practical application of techniques. Copyright © 2016 Elsevier Inc. All rights reserved.

  11. Design of an adaptive cooled first crystal for an X-ray monochromator

    International Nuclear Information System (INIS)

    Dezoret, D.; Marmoret, R.; Freund, A.K.; Kvick, AA.; Ravelet, R.

    1994-01-01

    We report here on the design of the first crystal in an x-ray monochromator for E.S.R.F. beam lines. This crystal is a thin silicon foil bonded to a cooled beryllium support. A system of piezoelectric actuators is used to counterbalance the deformations induced by synchrotron beams. This work was carried out by the C.E.A. in collaboration with the E.S.R.F. and the LASERDOT Company (Aerospatiale Group). (orig.)

  12. Detailed numerical simulations of laser cooling processes

    Science.gov (United States)

    Ramirez-Serrano, J.; Kohel, J.; Thompson, R.; Yu, N.

    2001-01-01

    We developed a detailed semiclassical numerical code of the forces applied on atoms in optical and magnetic fields to increase the understanding of the different roles that light, atomic collisions, background pressure, and number of particles play in experiments with laser cooled and trapped atoms.

  13. Cooling Crystallization of Indomethacin: Effect of Supersaturation, Temperature and Seeding on Polymorphism and Crystal Size Distribution

    DEFF Research Database (Denmark)

    Malwade, Chandrakant Ramkrishna; Qu, Haiyan

    2018-01-01

    In this work, effect of crystallization parameters i.e., supersaturation, seeding, and temperature on polymorphism and crystal size of a non-steroidal anti-inflammatory drug, indomethacin (IMC), was investigated. Firstly, several crystallization solvents (ethanol, methanol, ethyl acetate, acetone...... of IMC from ethanol confirmed that the supersaturation, operating temperature and seeding does affect the polymorphism as well as crystal size distribution of IMC. Fine needle shaped crystals of metastable α-IMC were obtained at 5 °C with high supersaturation even in presence of γ-IMC seeds, while...... rhombic plates like crystals of thermodynamically stable γ-IMC were obtained in remaining experiments. The amount of seed loading only marginally influenced the crystal growth rate and median particle diameter (d50). Particle size analysis of crystals obtained showed bimodal distribution in all...

  14. Flash crystallization kinetics of methane (sI) hydrate in a thermoelectrically-cooled microreactor.

    Science.gov (United States)

    Chen, Weiqi; Pinho, Bruno; Hartman, Ryan L

    2017-09-12

    The crystallization kinetics of methane (sI) hydrate were investigated in a thermoelectrically-cooled microreactor with in situ Raman spectroscopy. Step-wise and precise control of the temperature allowed acquisition of reproducible data within minutes, while the nucleation of methane hydrates can take up to 24 h in traditional batch reactors. The propagation rates of methane hydrate (from 3.1-196.3 μm s -1 ) at the gas-liquid interface were measured for different Reynolds' numbers (0.7-68.9), pressures (30.0-80.9 bar), and sub-cooling temperatures (1.0-4.0 K). The precise measurement of the propagation rates and their subsequent analyses revealed a transition from mixed heat-transfer-crystallization-rate-limited to mixed heat-transfer-mass-transfer-crystallization-rate-limited kinetics. A theoretical model, based on heat transfer, mass transfer, and intrinsic crystallization kinetics, was derived for the first time to understand the non-linear relationship between the propagation rate and sub-cooling temperature. The molecular diffusivity of methane within a stagnant film (ahead of the propagation front) was discovered to follow Stokes-Einstein, while calculated Hatta (0.50-0.68), Lewis (128-207), and beta (0.79-116) numbers also confirmed that the diffusive flux influences crystal growth. Understanding methane hydrate crystal growth is important to the atmospheric, oceanic, and planetary sciences and to energy production, storage, and transportation. Our discoveries could someday advance the science of other multiphase, high-pressure, and sub-cooled crystallizations.

  15. Cooling crystallization of Indomethacin from different organic solvents

    DEFF Research Database (Denmark)

    Malwade, Chandrakant Ramkrishna; Qu, Haiyan

    , 25, 35, and 45 °C. The solvents with varying polarities (ethanol, methanol, ethyl acetate, acetone, acetonitrile, and dichloromethane) were used for solubility measurement. Maximum solubility of IMC was observed in acetone, while acetonitrile showed the lowest solubility. Solid phase analysis...... of excess solute with XRPD and Raman spectroscopy confirmed formation of IMC solvate in acetone, methanol and dichloromethane at 15 °C. Based on solubility of IMC, the solvents ethanol, ethyl acetate, acetone, and dichloromethane were selected for crystallization experiments. Nucleation kinetics of IMC...... in selected solvents was investigated through the measurement of induction time at 5 °C and 15 °C. Longer induction times were observed for IMC in ethanol at both temperatures compared to the one in acetone. Metastable α form of IMC was obtained from ethanol, while solvate of IMC was produced from acetone....

  16. Process integration: Cooling water systems design

    CSIR Research Space (South Africa)

    Gololo, KV

    2010-10-01

    Full Text Available stream_source_info Gololo2_2010.pdf.txt stream_content_type text/plain stream_size 17891 Content-Encoding UTF-8 stream_name Gololo2_2010.pdf.txt Content-Type text/plain; charset=UTF-8 The 13th Asia Pacific Confederation... results in a nonlinear program (NLP) formulation and the second case yields mixed integer nonlinear program (MINLP). In both cases the cooling towers operating capacity were debottlenecked without compromising the heat duties. The 13th Asia...

  17. Integration of Generic Multi-dimensional Model and Operational Policies for Batch Cooling Crystallization

    DEFF Research Database (Denmark)

    Abdul Samad, Noor Asma Fazli; Singh, Ravendra; Sin, Gürkan

    2011-01-01

    Crystallization processes form an important class of separation methods that are frequently used in the chemical, the pharmaceutical and the food industry. The specifications of the crystal product are usually given in terms of crystal size, shape and purity. In order to predict the desired cryst...

  18. Final Rule for Industrial Process Cooling Towers: Fact Sheet

    Science.gov (United States)

    Fact sheet concerning a final rule to reduce air toxics emissions from industrial process cooling towers. Air toxics are those pollutants known or suspected of causing cancer or other serious health effects.

  19. Secondary process for securing emergency cooling in nuclear facilities

    International Nuclear Information System (INIS)

    Bachl, H.

    1975-01-01

    An auxiliary process for securing the emergency cooling of nuclear power plants is described which is characterized in that a two-material heat power auxiliary process is connected at the cold end of the cooling circuit to a main heat power process to obtain mechanical energy from thermal, which in normal operation works as a cold-absorption process, but with failure of the main process changes to a heat power process with full evaporation and subsequent superheating of the two-materials mixture. (RW/LH) [de

  20. Simulation and optimization of fractional crystallization processes

    DEFF Research Database (Denmark)

    Thomsen, Kaj; Rasmussen, Peter; Gani, Rafiqul

    1998-01-01

    A general method for the calculation of various types of phase diagrams for aqueous electrolyte mixtures is outlined. It is shown how the thermodynamic equilibrium precipitation process can be used to satisfy the operational needs of industrial crystallizer/centrifuge units. Examples of simulation...... and optimization of fractional crystallization processes are shown. In one of these examples, a process with multiple steady states is analyzed. The thermodynamic model applied for describing the highly non-ideal aqueous electrolyte systems is the Extended UNIQUAC model. (C) 1998 Published by Elsevier Science Ltd...

  1. Batch cooling crystallization and pressure filtration of sulphathiazole

    DEFF Research Database (Denmark)

    Häkkinen, Antti; Pöllänen, Kati; Karjalainen, Milja

    2005-01-01

    Currently there is a great interest in new process analytical approaches to increase the process understanding of pharmaceutical unit operations. In the present study, the influence of the solvent composition on the material properties and, further, on the filtration characteristics, of different...

  2. Cooling and heating of the ion flux on the transmission through crystals

    International Nuclear Information System (INIS)

    Karamyan, S.A.; Gruener, F.; Assmann, W.

    2003-01-01

    Transmission of charged particles through a monocrystalline medium is accompanied by many interesting phenomena, and a new one - redistribution of the isotropic flux - is now studied experimentally and described. The cooling or heating in the transverse momentum coordinate arises as a result of crystal-induced modification of the transmission trajectories. This indicates the violation of the reversibility rule, and cannot be explained within prevailing theory of channeling. The type of image (enhancement or reduction) and its intensity are dependent on the ion and crystal species, on the energy of ions and on the crystal thickness. Such dependencies have been studied experimentally and the mechanism involving the regular sequence of charge-exchange events with the transverse-energy non-conservation is attracted for understanding. The crystal response to ion flux transmission is also reviewed and characterized by the original results

  3. Solubility and crystallization of piroxicam from different solvents in evaporative and cooling crystallizations

    DEFF Research Database (Denmark)

    Qu, Haiyan; Ostergaard, Iben

    2018-01-01

    polarities; It has been found that the solubility of piroxicam in the solvents is in the following order: chloroform > dichloromethane > acetone > ethyl acetate > acetonitrile > acetic acid > methanol > hexane. Crystallization of piroxicam from different solvents has been performed with evaporative.......Results obtained in the present work showed the stochastic nature of nucleation of different polymorphs as well as the complexity of the crystallization of a polymorphic system....

  4. Processing of coke oven gas. Primary gas cooling

    Energy Technology Data Exchange (ETDEWEB)

    Ullrich, H [Otto (C.) und Co. G.m.b.H., Bochum (Germany, F.R.)

    1976-11-01

    The primary cooler is an indispensable part of all byproduct processing plants. Its purpose is to cool the raw gas from the coke oven battery and to remove the accompanying water vapor. The greater part of the cooling capacity is utilized for the condensation of water vapor and only a small capacity is needed for the gas cooling. Impurities in the gas, like naphthalene, tar and solid particles, necessitate a special design in view of the inclination to dirt accumulation. Standard types of direct and indirect primary gas coolers are described, with a discussion of their advantages and disadvantages.

  5. The hardness of synthetic products obtained from cooled and crystallized basaltic melts (in Romanian

    Directory of Open Access Journals (Sweden)

    Daniela Ogrean

    2001-04-01

    Full Text Available The Hardness of Synthetic Products Obtained from Cooled and Crystallized Basaltic Melts. Hardness is one of the main properties of the products obtained from cooled and crystallized basaltic melts under a controlled thermal regime. It influences the abrasion tear resistance of the resulted material. The microhardness measurements on the samples (bricks, boards, gutters, armour plates, tubes indicated Vickers hardness value between 757–926 for the materials obtained from Şanovita basalts (Timiş district and between 539–958 respectively, in case of the Racoş basalts (Braşov district. There is a certain variation of the hardness within the same sample, in various measurement points, within the theoretical limits of the hardnesses of the pyroxenes and that of the spinels.

  6. A white dwarf cooling age of 8 Gyr for NGC 6791 from physical separation processes.

    Science.gov (United States)

    García-Berro, Enrique; Torres, Santiago; Althaus, Leandro G; Renedo, Isabel; Lorén-Aguilar, Pablo; Córsico, Alejandro H; Rohrmann, René D; Salaris, Maurizio; Isern, Jordi

    2010-05-13

    NGC 6791 is a well studied open cluster that it is so close to us that can be imaged down to very faint luminosities. The main-sequence turn-off age ( approximately 8 Gyr) and the age derived from the termination of the white dwarf cooling sequence ( approximately 6 Gyr) are very different. One possible explanation is that as white dwarfs cool, one of the ashes of helium burning, (22)Ne, sinks in the deep interior of these stars. At lower temperatures, white dwarfs are expected to crystallize and phase separation of the main constituents of the core of a typical white dwarf ((12)C and (16)O) is expected to occur. This sequence of events is expected to introduce long delays in the cooling times, but has not hitherto been proven. Here we report that, as theoretically anticipated, physical separation processes occur in the cores of white dwarfs, resolving the age discrepancy for NGC 6791.

  7. Adiabatic cooling processes in frustrated magnetic systems with pyrochlore structure

    Science.gov (United States)

    Jurčišinová, E.; Jurčišin, M.

    2017-11-01

    We investigate in detail the process of adiabatic cooling in the framework of the exactly solvable antiferromagnetic spin-1/2 Ising model in the presence of the external magnetic field on an approximate lattice with pyrochlore structure. The behavior of the entropy of the model is studied and exact values of the residual entropies of all ground states are found. The temperature variation of the system under adiabatic (de)magnetization is investigated and the central role of the macroscopically degenerated ground states in cooling processes is explicitly demonstrated. It is shown that the model parameter space of the studied geometrically frustrated system is divided into five disjunct regions with qualitatively different processes of the adiabatic cooling. The effectiveness of the adiabatic (de)magnetization cooling in the studied model is compared to the corresponding processes in paramagnetic salts. It is shown that the processes of the adiabatic cooling in the antiferromagnetic frustrated systems are much more effective especially in nonzero external magnetic fields. It means that the frustrated magnetic materials with pyrochlore structure can be considered as very promising refrigerants mainly in the situations with nonzero final values of the magnetic field.

  8. Process Analytical Technology in Freeze-Drying: Detection of the Secondary Solute + Water Crystallization with Heat Flux Sensors.

    Science.gov (United States)

    Wang, Qiming; Shalaev, Evgenyi

    2018-04-01

    In situ and non-invasive detection of solute crystallization during freeze-drying would facilitate cycle optimization and scale-up from the laboratory to commercial manufacturing scale. The objective of the study is to evaluate heat flux sensor (HFS) as a tool for monitoring solute crystallization and other first-order phase transitions (e.g., onset of freezing). HFS is a thin-film differential thermopile, which acts as a transducer to generate an electrical signal proportional to the total heat applied to its surface. In this study, HFS is used to detect both primary (ice formation) and secondary (also known as eutectic) solute + water crystallization during cooling and heating of solutions in a freeze-dryer. Binary water-solute mixtures with typical excipients concentrations (e.g., 0.9% of NaCl and 5% mannitol) and fill volumes (1 to 3 ml/vial) are studied. Secondary crystallization is detected by the HFS during cooling in all experiments with NaCl solutions, whereas timing of mannitol crystallization depends on the cooling conditions. In particular, mannitol crystallization takes place during cooling, if the cooling rate is lower than the critical value. On the other hand, if the cooling rate exceeds the critical cooling rate, mannitol crystallization during cooling is prevented, and crystallization occurs during subsequent warming or annealing. It is also observed that, while controlled ice nucleation allows initiation of the primary freezing event in different vials simultaneously, there is a noticeable vial-to-vial difference in the timing of secondary crystallization. The HFS could be a valuable process monitoring tool for non-invasive detection of various crystallization events during freeze-drying manufacturing.

  9. Cooling a quantum oscillator: A useful analogy to understand laser cooling as a thermodynamical process

    Science.gov (United States)

    Freitas, Nahuel; Paz, Juan Pablo

    2018-03-01

    We analyze the lowest achievable temperature for a mechanical oscillator coupled with a quantum refrigerator composed of a parametrically driven system that is in contact with a bosonic reservoir where the energy is dumped. We show that the cooling of the oscillator (achieved by the resonant transport of its phonon excitations into the environment) is always stopped by a fundamental heating process that is dominant at sufficiently low temperatures. This process can be described as the nonresonant production of excitation pairs. This result is in close analogy with the recent study that showed that pair production is responsible for enforcing the validity of the dynamical version of the third law of thermodynamics [Phys. Rev. E 95, 012146 (2017), 10.1103/PhysRevE.95.012146]. Interestingly, we relate our model to the ones used to describe laser cooling of a single trapped ion reobtaining the correct limiting temperatures for the regimes of resolved and nonresolved sidebands. We show that the limiting temperature for laser cooling is achieved when the cooling transitions induced by the resonant transport of excitations from the motion into the electromagnetic environment is compensated by the heating transitions induced by the creation of phonon-photon pairs.

  10. Process and device for cooling liquid or vaporised fluids

    International Nuclear Information System (INIS)

    1975-01-01

    The invention relates to a process for the ambient air cooling of liquid fluids or those vaporised under low pressure. An exchanger composing a first circuit for the fluid to be cooled is set up and is separated by a partition from a second circuit swept by the atmospheric air. Each one of these two circuits is made up of pipes of not more than 4 mm hydraulic diameter and on the side of the second circuit swept by the air a quantity of water is brought to the extent of 0 to 50 g/kg of dry air crossing it. The water is sprayed into the second circuit. The tubes of the second circuit are set up so that the water sprayed on, runs down the partition separating the two circuits. The water is sprayed counter-current with respect to the direction of the cooling air. A quantity of water is projected into the second circuit depending on the thermal flow to be exchanged and the desired cooling temperature, the amount of water being limited so that the outgoing air, returned to the atmosphere, contains an amount of water per kilogram of dry air corresponding to the absolute moisture of the saturated air for the dry ambient temperature at the time. The process affords all the advantages of a wet cooling tower, great efficiency and low temperature [fr

  11. The temperature gradient on section of casting in process of primary crystallization of chromium cast iron

    Directory of Open Access Journals (Sweden)

    A. Studnicki

    2008-08-01

    Full Text Available The methodology of defining in article was introduced the temperature gradient in process of primary crystallization during cooling the casting from chromium cast iron on basis of measurements of thermal field in test DTA-K3. Insert also the preliminary results of investigations of influence temperature gradient on structure of studied wear resistance chromium cast iron.

  12. Three-body crystallization diagrams and the cooling of white dwarfs.

    Science.gov (United States)

    Segretain, L.

    1996-06-01

    The 3-body crystallization diagrams of C/O/Ne ionic mixtures characteristic of white dwarf interiors are examined within the framework of the density-functional theory of freezing. The crystallization process is described more accurately than in former calculations where the three-component system was treated as an effective two-component mixture (Segretain et al. 1994). The distillation process due to neon-crystallization is found to occur only for the late stages of crystallization. At the beginning, the presence of neon plays only a minor role and the phase diagram resembles a pure carbon-oxygen diagram. The final phase diagram is found to exhibit an azeotropic point with a neon concentration x_Ne_=0.22, a carbon concentration x_C_=0.78 and an oxygen concentration x_O_=0, so that during the distillation process, the fluid crystallizes into a pure neon-carbon solid. The critical temperature is T_A_=0.85T_C_, where T_C_ is the pure carbon crystallization temperature. We use this accurate phase diagram to calculate the total gravitational energy released during white dwarf crystallization and the related time delay. The final result yields {DELTA}τ=~2.6Gyr, among which about 20% are due to the neon-distillation process.

  13. High-temperature gas-cooled reactors and process heat

    International Nuclear Information System (INIS)

    Kasten, P.R.

    1980-01-01

    High-Temperature Gas-Cooled Reactors (HTGRs) are fueled with ceramic-coated microspheres of uranium and thorium oxides/carbides embedded in graphite blocks which are cooled with helium. Promising areas of HTGR application are in cogeneration, energy transport using Heat Transfer Salt, recovery of oils from oil shale, steam reforming of methane for chemical production, coal gasification, and in energy transfer using chemical heat jpipes in the long term. Further, HTGRs could be used as the energy source for hydrogen production through thermochemical water splitting in the long term. The potential market for Process Heat HTGRs is 100-200 large units by about the year 2020

  14. Axions from cooling compact stars: pair-breaking processes

    Energy Technology Data Exchange (ETDEWEB)

    Keller, Jochen; Sedrakian, Armen [Frankfurt Univ. (Germany). Inst. fuer Theoretische Physik

    2013-07-01

    Once formed in a supernova explosion, a neutron star cools rapidly via neutrino emission during the first 10{sup 4}-10{sup 5} years of its life-time. Here we compute the axion emission rate from baryonic components of a star at temperatures below their respective critical temperatures T{sub c} for normal-superfluid phase transition. The axion production is driven by a charge neutral weak process, associated with Cooper pair breaking and recombination. The requirement that the axion cooling does not overshadow the neutrino cooling yields a lower bound on the axion decay constant f{sub a} > 6 x 10{sup 9} T{sup -1}{sub c9} GeV, with T{sub c9} = T{sub c}/10{sup 9} K. This translates into an upper bound on the axion mass m{sub a} < 10{sup -3} T{sub c9} eV.

  15. Axions from cooling compact stars: Pair-breaking processes

    Energy Technology Data Exchange (ETDEWEB)

    Keller, Jochen [Institute for Theoretical Physics, J.W. Goethe-University, D-60438 Frankfurt am Main (Germany); Sedrakian, Armen, E-mail: sedrakian@th.physik.uni-frankfurt.de [Institute for Theoretical Physics, J.W. Goethe-University, D-60438 Frankfurt am Main (Germany)

    2013-01-02

    Once formed in a supernova explosion, a neutron star cools rapidly via neutrino emission during the first 10{sup 4}-10{sup 5} yr of its life-time. Here we compute the axion emission rate from baryonic components of a star at temperatures below their respective critical temperatures T{sub c} for normal-superfluid phase transition. The axion production is driven by a charge neutral weak process, associated with Cooper pair breaking and recombination. The requirement that the axion cooling does not overshadow the neutrino cooling puts a lower bound on the axion decay constant f{sub a}>6 Multiplication-Sign 10{sup 9}T{sub c9}{sup -1} GeV, with T{sub c9}=T{sub c}/10{sup 9} K. This translates into an upper bound on the axion mass m{sub a}<10{sup -3}T{sub c9} eV.

  16. Radiative cooling of solar absorbers using a visibly transparent photonic crystal thermal blackbody

    Science.gov (United States)

    Zhu, Linxiao; Raman, Aaswath P.; Fan, Shanhui

    2015-01-01

    A solar absorber, under the sun, is heated up by sunlight. In many applications, including solar cells and outdoor structures, the absorption of sunlight is intrinsic for either operational or aesthetic considerations, but the resulting heating is undesirable. Because a solar absorber by necessity faces the sky, it also naturally has radiative access to the coldness of the universe. Therefore, in these applications it would be very attractive to directly use the sky as a heat sink while preserving solar absorption properties. Here we experimentally demonstrate a visibly transparent thermal blackbody, based on a silica photonic crystal. When placed on a silicon absorber under sunlight, such a blackbody preserves or even slightly enhances sunlight absorption, but reduces the temperature of the underlying silicon absorber by as much as 13 °C due to radiative cooling. Our work shows that the concept of radiative cooling can be used in combination with the utilization of sunlight, enabling new technological capabilities. PMID:26392542

  17. Laser-cooled atoms inside a hollow-core photonic-crystal fiber

    DEFF Research Database (Denmark)

    Bajcsy, Michal; Hofferberth, S.; Peyronel, Thibault

    2011-01-01

    We describe the loading of laser-cooled rubidium atoms into a single-mode hollow-core photonic-crystal fiber. Inside the fiber, the atoms are confined by a far-detuned optical trap and probed by a weak resonant beam. We describe different loading methods and compare their trade-offs in terms...... of implementation complexity and atom-loading efficiency. The most efficient procedure results in loading of ∼30,000 rubidium atoms, which creates a medium with an optical depth of ∼180 inside the fiber. Compared to our earlier study this represents a sixfold increase in the maximum achieved optical depth...

  18. Designing Robust Process Analytical Technology (PAT) Systems for Crystallization Processes: A Potassium Dichromate Crystallization Case Study

    DEFF Research Database (Denmark)

    Abdul Samad, Noor Asma Fazli Bin; Sin, Gürkan

    2013-01-01

    The objective of this study is to test and validate a Process Analytical Technology (PAT) system design on a potassium dichromate crystallization process in the presence of input uncertainties using uncertainty and sensitivity analysis. To this end a systematic framework for managing uncertaintie...

  19. Study of the cooling process of an extruded aluminium profile

    International Nuclear Information System (INIS)

    Bouffioux, C.; Habraken, A.M.; Carton, M.; Lecomte-Beckers, J.

    2004-01-01

    The prediction of the final axial stresses and the residual strains of complex extruded aluminium profiles requires a good knowledge of the material behavior and of the industrial process. This paper is focused on the methods required to provide the whole set of data: material ones and process ones. Scanning differential calorimetry, dilatometry and diffusivity tests identify thermophysic material properties and hot tensile tests identify parameters of the elasto-visco-plastic Norton-Hoff law. The description of the industrial process and its simulations are described. Then a sensitivity analyzis provides the cooling key parameters causing the undesired final curvature during the industrial process

  20. Cooling of low-mass carbon-oxygen dwarfs from the planetary nucleus stage through the crystallization stage

    International Nuclear Information System (INIS)

    Iben, I. Jr.; Tutukov, A.V.

    1984-01-01

    The evolution of a carbon-oxygen dwarf of mass Mroughly-equal0.6 Msun has been carried all the way from an initial nuclear burning stage, when it is the central star of a planetary nebula, to the stage of complete internal crystallization, after 10 10 yr of cooling. Shell hydrogen and helium burning, neutrino losses, and the effects of liquification and crystallization have been taken into account. We show how the luminosity-time relationship may be understood in terms of balances between competing physical processes and demonstrate that, after complete crystallization, the time scale for cooling to terrestrial-like temperatures, in our approximation, is simply the optical depth of the outer, nonisothermal layer multiplied by a dimensional constant which, in years, is of the order of unity. A luminosity function based on the results covers the range -5< or approx. =log(L/Lsun)< or approx. =4 and agrees reasonably well with the observed luminosity function extending from the brighest planetary nebula nuclei to the dimmest observed white dwarfs, except perhaps for log(L/L/sub sun/)< or approx. =-4.5. Possible reasons for the apparent discrepancy at low luminosity, apart from the extreme obstacles against discovery, are discussed, one of the simplest is that the oldest dwarfs in the solar vicinity are distributed over a distance from the galactic plane that is approx.5 times larger than is the case for the youngest dwarfs; another possibility is that the opacity in the outer layers of the oldest dwarf models has been overestimated (or underestimatedexclamation) by a factor of 5 or more

  1. Liquid-metal-cooled, curved-crystal monochromator for Advanced Photon Source bending-magnet beamline 1-BM

    International Nuclear Information System (INIS)

    Brauer, S.; Rodricks, B.; Assoufid, L.; Beno, M.A.; Knapp, G.S.

    1996-06-01

    The authors describe a horizontally focusing curved-crystal monochromator that invokes a 4-point bending scheme and a liquid-metal cooling bath. The device has been designed for dispersive diffraction and spectroscopy in the 5--20 keV range, with a predicted focal spot size of ≤ 100 microm. To minimize thermal distortions and thermal equilibration time, the 355 x 32 x 0.8 mm crystal will be nearly half submerged in a bath of Ga-In-Sn-Zn alloy. The liquid metal thermally couples the crystal to the water-cooled Cu frame, while permitting the required crystal bending. Calculated thermal profiles and anticipated focusing properties are discussed

  2. Cryogenic cooling of x-ray crystals using a porous matrix

    International Nuclear Information System (INIS)

    Kuzay, T.M.

    1992-01-01

    It is well established that Si and SiC have very desirable thermophysical properties (principally, high thermal conductivity, and low thermal expansion) at cryogenic temperatures. Thus, cryocooled optics are a potentially good candidate for the first optical crystal of the third generation synchrotron machines, which will have very high heat flux levels. Currently, there is a great deal of interest, both experimental and analytical in such cryocooled crystals. The analytical studies involve cut micro- or capillary channel crystals. As opposed to machined channels, porous matrices provide significant advantages. Such matrices are known to effect superior heat transfer. They operate very quietly. Data available in the open literature suggest that surface heat flux levels up to ∼8 kW/cm 2 are possible. For cryogens for which the boiling heat transfer heat flux is a rather low value in conventional geometries, the enhancement available with such matrices is very significant. Cryogens are poor thermal conductors themselves. At cryogenic temperatures, the Si and/or SiC matrix itself becomes highly conductive: Thus, the matrix distributes the surface heat flux into the full volume effectively offsetting the poor conductivity of the coolant. In addition, the tortuous path of the coolant through the matrix increases the dwell time resulting in better heat transfer, however, at the expense of an increased pressure drop. In this study, a first optics crystal model of Si with a Si and/or SiC porous matrix as its heat exchanger and subject to prototypic synchrotron loads is analyzed, and the feasibility limits of the cooling possible with liquid nitrogen in single phase are delineated

  3. Afterheat usage from cooling facilities in ORC processes

    International Nuclear Information System (INIS)

    Theede, Florian; Luke, Andrea

    2016-01-01

    In the course of the reduction of climate warming an energy-efficient lay-out of processes is necessary. A possibility for the efficiency increasement is the usage of afterheat currents for instance in ORC processes. Connected with the limitation of refrigerants with high greenhouse potential it comes to the increased application of transcritical cooling facilities with carbon dioxide (CO_2) as refrigerant. By the high pressures after the compression arise here new afterheat sources on a temperature level of about 100 C. An alternative for the simple back-cooling or the heating support and drinking-water heating represents the current production in an ORC process. Great challenges for the lay-out of such an ORC process are the selection of the working fluid as well as the lay-out of the heat exchangers. Established refrigerants in the low-temperature like R245fa for ORC facilities will be in forseeable future no more available. For the study of the possible replacement by alternative refrigerants a simulation model has been developed. By means of this model different refrigerants are analyzed regarding their performance and simultaneously the effects on process and other components studied. The results show that in the temperature range two hydrofluoroolefines R1233zd[E] and R1234ze[Z] as well as the hadron carbon butane can thermodynamically form an alternative.

  4. Systematic Modelling and Crystal Size Distribution Control for Batch Crystallization Processes

    DEFF Research Database (Denmark)

    Abdul Samad, Noor Asma Fazli; Singh, Ravendra; Sin, Gürkan

    Crystallization processes form an important class of separation methods that are frequently used in the chemical, the pharmaceutical and the food industry. The specifications of the crystal product are usually given in terms of crystal size, shape and purity. In order to predict the desired cryst...

  5. LASER PROCESSING ON SINGLE CRYSTALS BY UV PULSE LASER

    OpenAIRE

    龍見, 雅美; 佐々木, 徹; 高山, 恭宜

    2009-01-01

    Laser processing by using UV pulsed laser was carried out on single crystal such as sapphire and diamond in order to understand the fundamental laser processing on single crystal. The absorption edges of diamond and sapphire are longer and shorter than the wave length of UV laser, respectively. The processed regions by laser with near threshold power of processing show quite different state in each crystal.

  6. Cooling and crystallization of rhyolite-obsidian lava: Insights from micron-scale projections on plagioclase microlites

    Science.gov (United States)

    Sano, Kyohei; Toramaru, Atsushi

    2017-07-01

    To reveal the cooling process of a rhyolite-obsidian flow, we studied the morphology of plagioclase microlites in the Tokachi-Ishizawa lava of Shirataki, northern Hokkaido, Japan, where the structure of the lava can be observed from obsidian at the base of the flow to the innermost rhyolite. Needle-like micron-scale textures, known as "projections", occur on the short side surfaces of the plagioclase microlites. Using FE-SEM we discovered a positive correlation between the lengths and spacings of these projections. On the basis of the instability theory of an interface between melt and crystal, and to understand the length and spacing data, we developed a model that explains the positive correlation and allows us to simultaneously estimate growth rates and growth times. Applying the model to our morphological data and the estimated growth rates and growth times, we suggest that the characteristics of the projections reflect the degree of undercooling, which in turn correlates with lava structure (the obsidian at the margin of the flow experienced a higher degree of undercooling than the interior rhyolite). The newly developed method provides insights into the degree of undercooling during the final stages of crystallization of a rhyolitic lava flow.

  7. Integrated Intelligent Modeling, Design and Control of Crystal Growth Processes

    National Research Council Canada - National Science Library

    Prasad, V

    2000-01-01

    .... This MURI program took an integrated approach towards modeling, design and control of crystal growth processes and in conjunction with growth and characterization experiments developed much better...

  8. EIS study on corrosion and scale processes and their inhibition in cooling system media

    Energy Technology Data Exchange (ETDEWEB)

    Marin-Cruz, J. [Universidad Autonoma Metropolitana, Departamento de Quimica, Apdo. Postal 55-534, 09340 Mexico, DF (Mexico) and Instituto Mexicano del Petroleo, Coordinacion de Ingenieria Molecular, Competencia de Quimica Aplicada, Eje Central Lazaro Cardenas No. 152, CP 07730, DF (Mexico)]. E-mail: jmarin@imp.mx; Cabrera-Sierra, R. [Universidad Autonoma Metropolitana, Departamento de Quimica, Apdo. Postal 55-534, 09340 Mexico, DF (Mexico); Escuela Superior de Ingenieria Quimica e Industrias Extractivas (ESIQIE-IPN), Departamento de Metalurgia, UPALM Zacatenco AP 75-874, CP 07338, DF (Mexico); Pech-Canul, M.A. [Departamento de Fisica Aplicada, Centro de Investigacion y de Estudios, Avanzados del IPN, AP 73 Cordemex, CP 97310, Merida, Yucatan (Mexico); Gonzalez, I. [Universidad Autonoma Metropolitana, Departamento de Quimica, Apdo. Postal 55-534, 09340 Mexico, DF (Mexico)]. E-mail: igm@xanum.uam.mx

    2006-01-20

    A study of the carbon steel/cooling water interface was carried out using electrochemical impedance spectroscopy (EIS). EIS spectra reveal that a layer of corrosion and scale products forms naturally and evolves with the immersion time modifying the carbon steel/cooling water interface and giving rise to corrosion and scale processes. In addition, the nature of the layer formed on the metal was found to depend on the inhibitor used. It was established that the corrosion inhibitor (hydroxyphosphonoacetic acid (HPA)) chelates with Ca(II) ion generating a layer with resistive properties that provides good protection against corrosion. In contrast, the scale inhibitor (1-hydroxy-ethane-1,1-diphosphonic acid (HEDP)) is incorporated into the calcium carbonate crystals at the surface, modifying the structure and diminishing scale formation in the surface; this additive additionally inhibited corrosion. These observations were supported by scanning electronic microscopy (SEM) and corroborate previous studies performed by other techniques on HPA and HEDP. Finally, a synergistic effect was observed between these inhibitors that provides good protection to steel against corrosion and scaling in cooling media.

  9. EIS study on corrosion and scale processes and their inhibition in cooling system media

    International Nuclear Information System (INIS)

    Marin-Cruz, J.; Cabrera-Sierra, R.; Pech-Canul, M.A.; Gonzalez, I.

    2006-01-01

    A study of the carbon steel/cooling water interface was carried out using electrochemical impedance spectroscopy (EIS). EIS spectra reveal that a layer of corrosion and scale products forms naturally and evolves with the immersion time modifying the carbon steel/cooling water interface and giving rise to corrosion and scale processes. In addition, the nature of the layer formed on the metal was found to depend on the inhibitor used. It was established that the corrosion inhibitor (hydroxyphosphonoacetic acid (HPA)) chelates with Ca(II) ion generating a layer with resistive properties that provides good protection against corrosion. In contrast, the scale inhibitor (1-hydroxy-ethane-1,1-diphosphonic acid (HEDP)) is incorporated into the calcium carbonate crystals at the surface, modifying the structure and diminishing scale formation in the surface; this additive additionally inhibited corrosion. These observations were supported by scanning electronic microscopy (SEM) and corroborate previous studies performed by other techniques on HPA and HEDP. Finally, a synergistic effect was observed between these inhibitors that provides good protection to steel against corrosion and scaling in cooling media

  10. Crystallization processes derived from the interaction of urine and dolostone

    Science.gov (United States)

    Cámara, Beatriz; Alvarez de Buergo, Monica; Fort, Rafael

    2015-04-01

    The increase in the number of pets (mostly dogs), homeless people and the more recent open-air drinking sessions organized by young people in historical centers of European cities, derive on the augmentation of urinations on stone façades of the built cultural heritage. Up to now this process has been considered only under an undesirable aesthetical point of view and the insalubrious conditions it creates, together with the cleaning costs that the local governments have to assume. This study aims to confirm urine as a real source of soluble salts that can trigger the decay of building materials, especially of those of built cultural heritage of the historical centers of the cities, which are suffering the new social scenario described above. For this purpose, an experimental setup was designed and performed in the laboratory to simulate this process. 5 cm side cubic specimens of dolostone were subjected to 100 testing cycles of urine absorption by capillarity. The necessary amount of urine was collected by donors and stored following clinical protocol conditions. Each cycle consisted of imbibitions of the specimens in 3 mm high urine sheet for 3 hours, drying at 40°C in an oven for 20 hours and 1 hour cooling in a dessicator. At the end of the 100 cycles, small pieces of the specimens were cut, observed and analyzed with the aid of an environmental scanning electron microscope, which presents the advantage of no sample preparation. The sampled pieces were selected considering there were different sections in height in the specimens: a) a bottom section that corresponds to the section that has been immersed in the urine solution (3 mm); b) an interface section, immediately above the immersed area, which is the area most affected by the urine capillarity process, characterized by a strong yellowish color; c) the section that we have named as section of influence, which is subjected to the capillary absorption, although not so strongly than the interface section

  11. CRYSTALLIZATION IN MULTICOMPONENT GLASSES

    Energy Technology Data Exchange (ETDEWEB)

    KRUGER AA; HRMA PR

    2009-10-08

    In glass processing situations involving glass crystallization, various crystalline forms nucleate, grow, and dissolve, typically in a nonuniform temperature field of molten glass subjected to convection. Nuclear waste glasses are remarkable examples of multicomponent vitrified mixtures involving partial crystallization. In the glass melter, crystals form and dissolve during batch-to-glass conversion, melter processing, and product cooling. Crystals often agglomerate and sink, and they may settle at the melter bottom. Within the body of cooling glass, multiple phases crystallize in a non-uniform time-dependent temperature field. Self-organizing periodic distribution (the Liesegnang effect) is common. Various crystallization phenomena that occur in glass making are reviewed.

  12. Crystallization In Multicomponent Glasses

    International Nuclear Information System (INIS)

    Kruger, A.A.; Hrma, P.R.

    2009-01-01

    In glass processing situations involving glass crystallization, various crystalline forms nucleate, grow, and dissolve, typically in a nonuniform temperature field of molten glass subjected to convection. Nuclear waste glasses are remarkable examples of multicomponent vitrified mixtures involving partial crystallization. In the glass melter, crystals form and dissolve during batch-to-glass conversion, melter processing, and product cooling. Crystals often agglomerate and sink, and they may settle at the melter bottom. Within the body of cooling glass, multiple phases crystallize in a non-uniform time-dependent temperature field. Self-organizing periodic distribution (the Liesegnang effect) is common. Various crystallization phenomena that occur in glass making are reviewed.

  13. 40 CFR 61.134 - Standard: Naphthalene processing, final coolers, and final-cooler cooling towers.

    Science.gov (United States)

    2010-07-01

    ... coolers, and final-cooler cooling towers. 61.134 Section 61.134 Protection of Environment ENVIRONMENTAL... Standard: Naphthalene processing, final coolers, and final-cooler cooling towers. (a) No (“zero”) emissions are allowed from naphthalene processing, final coolers and final-cooler cooling towers at coke by...

  14. Processing-structure-mechanical property relationship in Ti-Nb microalloyed steel: Continuous cooling versus interrupted cooling

    Energy Technology Data Exchange (ETDEWEB)

    Natarajan, V.V. [Laboratory for Excellence in Advanced Steel Research, Materials Science and Engineering Program, Department of Metallurgical, Materials and Biomedical Engineering, University of Texas at El Paso, 500 W. University Avenue, El Paso, TX 79968 (United States); Liu, S. [Laboratory for Excellence in Advanced Steel Research, Materials Science and Engineering Program, Department of Metallurgical, Materials and Biomedical Engineering, University of Texas at El Paso, 500 W. University Avenue, El Paso, TX 79968 (United States); School of Materials Science and Engineering, University of Science and Technology, Beijing (China); Challa, V.S.A. [Laboratory for Excellence in Advanced Steel Research, Materials Science and Engineering Program, Department of Metallurgical, Materials and Biomedical Engineering, University of Texas at El Paso, 500 W. University Avenue, El Paso, TX 79968 (United States); Misra, R.D.K., E-mail: dmisra2@utep.edu [Laboratory for Excellence in Advanced Steel Research, Materials Science and Engineering Program, Department of Metallurgical, Materials and Biomedical Engineering, University of Texas at El Paso, 500 W. University Avenue, El Paso, TX 79968 (United States); Sidorenko, D.M.; Mulholland, M.D.; Manohar, M.; Hartmann, J.E. [ArcelorMittal Global R& D Center, 3001 East Columbus Drive, East Chicago, IN 46312 (United States)

    2016-08-01

    The process parameters associated with thermo-mechanical controlled processing (TMCP) of steels play an important role in influencing the ultimate mechanical properties. The study of TMCP parameters have not received the required attention. In this regard, we elucidate here the impact of finish cooling temperature on interrupted cooling and compare with continuous cooling on microstructural evolution and precipitation behavior and associated mechanical properties in Ti-Nb microalloyed steels. The microstructural evolution was studied via transmission electron microscopy and electron back scattered diffraction (EBSD). The microstructure of continuously cooled and interrupted cooled steels with different finish exit temperatures consisted of polygonal ferrite, bainite and martensite/austenite constituent. However, the fraction of different microstructural constituents was different in each of the experimental steels. Similarly, there were differences in the distribution and average size of (Nb, Ti)C precipitates. The aforementioned differences in the microstructure and precipitation introduced differences in tensile properties. Furthermore, electron back scattered diffraction studies indicated distinct variation in average grain area and high angle boundaries between continuously cooled and interrupted cooled steels.

  15. The crystallization processes in the aluminum particles production technology

    Directory of Open Access Journals (Sweden)

    Arkhipov Vladimir

    2015-01-01

    Full Text Available The physical and mathematical model of the crystallization process of liquid aluminum particles in the spray-jet of the ejection-type atomizer was proposed. The results of mathematical modeling of two-phase flow in the spray-jet and the crystallization process of fluid particles are given. The influence of the particle size, of the flow rate and the stagnation temperature gas in the ranges of industrial technology implemented for the production of powders aluminum of brands ASD, on the crystallization characteristics were investigated. The approximations of the characteristics of the crystallization process depending on the size of the aluminum particles on the basis of two approaches to the mathematical description of the process of crystallization of aluminum particles were obtained. The results allow to optimize the process parameters of ejection-type atomizer to produce aluminum particles with given morphology.

  16. Inhibition of calcium carbonate crystal growth by organic additives using the constant composition method in conditions of recirculating cooling circuits

    Science.gov (United States)

    Chhim, Norinda; Kharbachi, Chams; Neveux, Thibaut; Bouteleux, Céline; Teychené, Sébastien; Biscans, Béatrice

    2017-08-01

    The cooling circuits used in power plants are subject to mineral crystallization which can cause scaling on the surfaces of equipment and construction materials reducing their heat exchange efficiency. Precipitated calcium carbonate is the predominant mineral scale commonly observed in cooling systems. Supersaturation is the key parameter controlling the nucleation and growth of calcite in these systems. The present work focuses on the precipitation of calcite using the constant composition method at constant supersaturation, through controlled addition of reactants to a semi-batch crystallizer, in order to maintain constant solution pH. The determination of the thermodynamic driving force (supersaturation) was based on the relevant chemical equilibria, total alkalinity and calculation of the activity coefficients. Calcite crystallization rates were derived from the experiments performed at supersaturation levels similar to those found in industrial station cooling circuits. Several types of seeds particles were added into the aqueous solution to mimic natural river water conditions in terms of suspended particulate matters content, typically: calcite, silica or illite particles. The effect of citric and copolycarboxylic additive inhibitors added to the aqueous solution was studied. The calcium carbonate growth rate was reduced by 38.6% in the presence of the citric additive and a reduction of 92.7% was observed when the copolycarboxylic additive was used under identical experimental conditions. These results are explained by the location of the adsorbed inhibitor at the crystal surface and by the degree of chemical bonding to the surface.

  17. Modelling and analysis of a desiccant cooling system using the regenerative indirect evaporative cooling process

    DEFF Research Database (Denmark)

    Bellemo, Lorenzo; Elmegaard, Brian; Reinholdt, Lars O.

    2013-01-01

    This paper focuses on the numerical modeling and analysis of a Desiccant Cooling (DEC) system with regenerative indirect evaporative cooling, termed Desiccant Dewpoint Cooling (DDC) system. The DDC system includes a Desiccant Wheel (DW), Dew Point Coolers (DPCs), a heat recovery unit and a heat...... in different climates: temperate in Copenhagen and Mediterranean in Venice. Cheap and clean heat sources (e.g. solar energy) strongly increase the attractiveness of the DDC system. For the Mediterranean climate the DDC system represents a convenient alternative to chiller-based systems in terms of energy costs...... and CO2 emissions. The electricity consumption for auxiliaries in the DDC system is higher than in the chiller-based systems. The number of commercial-size DPC units required to cover the cooling load during the whole period is high: 8 in Copenhagen and 12 in Venice....

  18. Melt extraction during heating and cooling of felsic crystal mushes in shallow volcanic systems: An experimental study

    Science.gov (United States)

    Pistone, M.; Baumgartner, L. P.; Sisson, T. W.; Bloch, E. M.

    2017-12-01

    The dynamics and kinetics of melt extraction in near-solidus, rheologically stalled, felsic crystal mushes (> 50 vol.% crystals) are essential to feeding many volcanic eruptions. At shallow depths (volatile-saturated and may be thermally stable for long time periods (104-107 years). In absence of deformation, residual melt can segregate from the mush's crystalline framework stimulated by: 1) gas injecting from hot mafic magmas into felsic mushes (heating / partial melting scenario), and 2) gas exsolving from the crystallizing mush (cooling / crystallizing scenario). The conditions and efficiency of melt extraction from a mush in the two scenarios are not well understood. Thus, we conducted high-temperature (700 to 850 °C) and -pressure (1.1 kbar) cold seal experiments (8-day duration) on synthetic felsic mushes, composed of water-saturated (4.2 wt.%) rhyodacite melt bearing different proportions of added quartz crystals (60, 70, and 80 vol%; 68 mm average particle size). High-spatial resolution X-ray tomography of run products show: 1) in the heating scenario (> 750 °C) melt has not segregated due to coalescence of vesicles (≤ 23 vol%) and large melt connectivity (> 7 vol% glass) / low pressure gradient for melt movement up to 80 vol% crystals; 2) in the cooling scenario (≤ 750 °C) vesicle (< 11 vol%) coalescence is limited or absent and limited amount of melt (3 to 11 vol%) segregated from sample center to its outer periphery (30 to 100 mm melt-rich lenses), testifying to the efficiency of melt extraction dictated by increasing crystallinity. These results suggest that silicic melt hosted within a crystal-rich mush can accumulate rapidly due to the buildup of modest gas pressures during crystallization at temperatures near the solidus.

  19. Time evolution of absorption process in nonlinear metallic photonic crystals

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Mahi R.; Hatef, Ali [Department of Physics and Astronomy, University of Western Ontario, London (Canada)

    2009-05-15

    The time evolution of the absorption coefficient in metallic photonic crystals has been studied numerically. These crystals are made from metallic spheres which are arranged periodically in air. The refractive index of the metallic spheres depends on the plasma frequency. Probe and pump fields are applied to monitor the absorption process. Ensembles of three-level particles are embedded in the crystal. Nanoparticles are interacting with the metallic crystals via the electron-photon interaction. It is found that when the resonance states lie away from the band edges system goes to transparent state. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  20. Emergency cooling process and device for nuclear reactor containment

    International Nuclear Information System (INIS)

    Costes, D.

    1985-01-01

    The emergency cooling system of a PWR containment, according to the principal patent, comprises a turbine fed by the humid air of the containment, a condenser in which the air flowing out of the turbine is dryed and cooled by an external coolant and a compressor actuated by the turbine and returning the dryed air in the containment [fr

  1. Experimental study of air evaporative cooling process using microporous membranes

    Directory of Open Access Journals (Sweden)

    Englart Sebastian

    2017-01-01

    Full Text Available This article describes the potential use of microporous membranes in evaporative cooling applications for air conditioning. The structure of membrane contractor and the measuring device are described. On the basis of the results of the measurements air cooling effectiveness coefficient has been determined.

  2. Highly oriented Bi-system bulk sample prepared by a decomposition-crystallization process

    International Nuclear Information System (INIS)

    Xi Zhengping; Zhou Lian; Ji Chunlin

    1992-01-01

    A decomposition-crystallization method, preparing highly oriented Bi-system bulk sample is reported. The effects of processing parameter, decomposition temperature, cooling rate and post-treatment condition on texture and superconductivity are investigated. The method has successfully prepared highly textured Bi-system bulk samples. High temperature annealing does not destroy the growing texture, but the cooling rate has some effect on texture and superconductivity. Annealing in N 2 /O 2 atmosphere can improve superconductivity of the textured sample. The study on the superconductivity of the Bi(Pb)-Sr-Ca-Cu-O bulk material has been reported in numerous papers. The research on J c concentrates on the tape containing the 2223 phase, with very few studies on the J c of bulk sample. The reason for the lack of studies is that the change of superconducting phases at high temperatures has not been known. The authors have reported that the 2212 phase incongruently melted at about 875 degrees C and proceeded to orient the c-axis perpendicular to the surface in the process of crystallization of the 2212 phase. Based on that result, a decomposition-crystallization method was proposed to prepare highly oriented Bi-system bulk sample. In this paper, the process is described in detail and the effects of processing parameters on texture and superconductivity are reported

  3. A systematic framework for design of process monitoring and control (PAT) systems for crystallization processes

    DEFF Research Database (Denmark)

    Abdul Samad, Noor Asma Fazli Bin; Sin, Gürkan; Gernaey, Krist

    2013-01-01

    A generic computer-aided framework for systematic design of a process monitoring and control system for crystallization processes has been developed to study various aspects of crystallization operations.The systematic design framework contains a generic crystallizer modelling toolbox, a tool for...

  4. Research and Development of Crystal Purification for Product of Uranium Crystallization Process

    Energy Technology Data Exchange (ETDEWEB)

    Yano, K. [Japan Atomic Energy Agency - JAEA (Japan)

    2009-06-15

    Uranium crystallization has been developed as a part of advanced aqueous reprocessing for FBR spent fuel. Although the purity of uranyl nitrate hexahydrate (UNH) crystal from the crystallization process is supposed to meet a specification of FBR blanket fuel, an improvement of its purity is able to reduce the cost of fuel fabrication and storage (in case interim storage of recovered uranium is required). In this work, UNH crystal purification was developed as additional process after crystallization. Contamination of the crystal is caused by mother solution and solid state impurities. They are inseparable by washing and filtration. Mother solution on the surface of UNH crystals is removable by washing, but it is difficult to remove that in an obstructed part of crystalline aggregate by washing. Major elements of solid state impurities are cesium and barium. Cesium precipitates with tetravalent plutonium as a double nitrate, Cs{sub 2}Pu(NO{sub 3}){sub 6}. Barium crystallizes as Ba(NO{sub 3}){sub 2} because of its low solubility in nitric acid solution. It is difficult to separate their particle from UNH crystal by solid-liquid separation such as simple filtration. As a kind of crystal purification, there are some methods using sweating. Sweating is a phenomenon that a crystal melts partly below its melting point and it is caused by depression of freezing point due to impurity. It is considerably applicable for removal of mother solution. Concerning the solid state impurities, which has higher melting point than that of UNH crystal, it is supposed that they are separable by melting UNH crystal and filtration. The behaviors of impurities and applicability of sweating and melting-filtration operations to the purification for UNH crystal were investigated experimentally on a beaker and an engineering scale. With regard to behaviors of impurities, the conditions of cesium and barium precipitation were surveyed and it was clarified that there were most impurities on the

  5. Industrial Process Cooling Towers: National Emission Standards for Hazardous Air Pollutants

    Science.gov (United States)

    Standards limiting discharge of chromium compound air emissions from industrial process cooling towers (IPCT's). Includes rule history, Federal Registry citations, implementation information and additional resources.

  6. Control of cooling processes with forced-air aimed at efficiency energetic and the cooling time of horticultural products

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Joao Carlos Teles Ribeiro da; Mederos, Barbara Janet Teruel [Universidade Estadual de Campinas (FEAGRI/UNICAMP), SP (Brazil). Fac. de Engenharia Agricola

    2008-07-01

    The application of cooling technologies for the conservation of horticultural products is one of the stages the Cold Chain. In Brazil particularly, as a country with tropical climate with average high temperature almost all year, the application of these technologies is very important because the shelf-life of fresh horticultural products, with quality that the market demands, is directly related to temperature. In particular, the systems of forced air cooling operate according to the flow of air predetermined in the project according to the quantity of product to cool. When actual conditions differ from considerations of the project, as to the quantity of product, a situation very common in agricultural properties and packing houses, the fan will continue providing the nominal flow rate, causing alteration of the cost-benefit relation of process. This project aims at the development of a micro-processing equipment (output current of 4 to 20 mA) to control the rotational speed of the motor of the fan systems, air forced through an inverter of frequency. The objective is development of a Man-Machine Interface, based on an algorithm, which, through the introduction of mass product data and the automatic acquisition of data from temperature of the product and the camera, is calculated the cooling time. The rotation of the engine fan will be amended automatically, to maintain air flow with a proper cost-benefit, in connection with the reduction of cooling time, energy consumption, for the increasing the shelf life of products. (author)

  7. Effects of Undercooling and Cooling Rate on Peritectic Phase Crystallization Within Ni-Zr Alloy Melt

    Science.gov (United States)

    Lü, P.; Wang, H. P.

    2018-04-01

    The liquid Ni-16.75 at. pct Zr peritectic alloy was substantially undercooled and containerlessly solidified by an electromagnetic levitator and a drop tube. The dependence of the peritectic solidification mode on undercooling was established based on the results of the solidified microstructures, crystal growth velocity, as well as X-ray diffraction patterns. Below a critical undercooling of 124 K, the primary Ni7Zr2 phase preferentially nucleates and grows from the undercooled liquid, which is followed by a peritectic reaction of Ni7Zr2+L → Ni5Zr. The corresponding microstructure is composed of the Ni7Zr2 dendrites, peritectic Ni5Zr phase, and inter-dendritic eutectic. Nevertheless, once the liquid undercooling exceeds the critical undercooling, the peritectic Ni5Zr phase directly precipitates from this undercooled liquid. However, a negligible amount of residual Ni7Zr2 phase still appears in the microstructure, indicating that nucleation and growth of the Ni7Zr2 phase are not completely suppressed. The micromechanical property of the peritectic Ni5Zr phase in terms of the Vickers microhardness is enhanced, which is ascribed to the transition of the peritectic solidification mode. To suppress the formation of the primary phase completely, this alloy was also containerlessly solidified in free fall experiments. Typical peritectic solidified microstructure forms in large droplets, while only the peritectic Ni5Zr phase appears in smaller droplets, which gives an indication that the peritectic Ni5Zr phase directly precipitates from the undercooled liquid by completely suppressing the growth of the primary Ni7Zr2 phase and the peritectic reaction due to the combined effects of the large undercooling and high cooling rate.

  8. Initial crystallization and growth in melt processing of large-domain YBa2Cu3Ox for magnetic levitation

    International Nuclear Information System (INIS)

    Shi, D.

    1994-10-01

    Crystallization temperature in YBa 2 Cu 3 O x (123) during peritectic reaction has been studied by differential thermal analysis (DTA) and optical microscopy. It has been found that YBa 2 Cu 3 O x experiences partial melting near 1,010 C during heating while crystallization takes place at a much lower temperature range upon cooling indicating a delayed nucleation process. A series of experiments have been conducted to search for the initial crystallization temperature in the Y 2 BaCuO x + liquid phase field. The authors have found that the slow-cool period (1 C/h) for the 123 grain texturing can start at as low as 960 C. This novel processing has resulted in high-quality, large-domain, strongly pinned 123 magnetic levitators

  9. Dissolution enhancement of Deflazacort using hollow crystals prepared by antisolvent crystallization process.

    Science.gov (United States)

    Paulino, A S; Rauber, G; Campos, C E M; Maurício, M H P; de Avillez, R R; Capobianco, G; Cardoso, S G; Cuffini, S L

    2013-05-13

    Deflazacort (DFZ), a derivate of prednisolone, is a poorly soluble drug which has been proposed to have major advantages over other corticosteroids. Poorly soluble drugs present limited bioavailability due to their low solubility and dissolution rate and several strategies have been developed in order to find ways to improve them. In general, pharmaceutical laboratories use a micronized process to reduce the particle size in order to increase the dissolution of the drugs. However, this process causes changes such as polymorphic transitions, particle agglomeration and a reduction in fluidity and wettability. These solid-state properties affect the dissolution behavior and stability performance of drugs. Crystallization techniques are widely used in the pharmaceutical industry and antisolvent crystallization has been used to obtain ultrafine particles. In this study, DFZ was investigated in terms of its antisolvent crystallization in different solvents and under various preparation conditions (methanol/water ratio, stirring and evaporation rate, etc.), in order to compare the physicochemical properties between crystallized samples and raw materials available on the Brazilian market with and without micronization. Crystalline structure, morphology, and particle size, and their correlation with the Intrinsic Dissolution Rate (IDR) and dissolution profile as relevant biopharmaceutical properties were studied. Crystallization conditions were achieved which provided crystalline samples of hollow-shaped crystals with internal channels, which increased the dissolution rate of DFZ. The antisolvent crystallization process allowed the formation of hollow crystals, which demonstrated a better dissolution profile than the raw material (crystalline and micronized), making this a promising technique as a crystallization strategy for improving the dissolution and thus the bioavailability of poorly soluble drugs. Copyright © 2013 Elsevier B.V. All rights reserved.

  10. Enhancement of Cognitive Processing by Multiple Sclerosis Patients Using Liquid Cooling Technology: A Case Study

    Science.gov (United States)

    Montgomery, Leslie D.; Montgomery, Richard W.; Ku, Yu-Tsuan; Luna, Bernadette (Technical Monitor)

    1997-01-01

    Cognitive dysfunction is a common symptom in patients with multiple sclerosis (MS). This can have a significant impact on the quality of life of both the patient and of their primary care giver. This case study explores the possibility that liquid cooling therapy may be used to enhance the cognitive processing of MS patients in the same way that it provides temporary relief of some physical impairment. Two MS patients were presented a series of pattern discrimination tasks before and after being cooled with a liquid cooling garment for a one hour period. The subject whose ear temperature was reduced during cooling showed greater electroencephalographic (EEG) activity and scored much better on the task after cooling. The patient whose ear temperature was unaffected by cooling showed less EEG activity and degraded performance after the one hour cooling period.

  11. Stimulated Brillouin processes in crystals and glasses

    International Nuclear Information System (INIS)

    Faris, G.W.; Hickman, A.P.

    1992-02-01

    The basic physics and material properties needed to describe and predict the Brillouin gain for a variety of materials have been investigated. Lawrence Livermore National Laboratory (LLNL) has identified transverse stimulated Brillouin scattering (SBS) as an important limiting mechanism in high power laser fusion systems. At sufficiently high laser intensities, SBS drives acoustic vibrations that can damage optical components. SRI has performed measurements and developed the corresponding theory for stimulated Brillouin gain spectroscopy in anisotropic crystals. Absolute Brillouin steady-state gain coefficients, linewidths, and frequency shifts have been determined at 532 nm for a number of optical materials of interest to LLNL. This knowledge can be used to select optical materials and devise suppression schemes that will allow much higher laser fluences to be used in laser fusion

  12. History Dependence of the Microstructure on Time-Dependent Deformation During In-Situ Cooling of a Nickel-Based Single-Crystal Superalloy

    Science.gov (United States)

    Panwisawas, Chinnapat; D'Souza, Neil; Collins, David M.; Bhowmik, Ayan; Roebuck, Bryan

    2018-05-01

    Time-dependent plastic deformation through stress relaxation and creep deformation during in-situ cooling of the as-cast single-crystal superalloy CMSX-4® has been studied via neutron diffraction, transmission electron microscopy, electro-thermal miniature testing, and analytical modeling across two temperature regimes. Between 1000 °C and 900 °C, stress relaxation prevails and gives rise to softening as evidenced by a decreased dislocation density and the presence of long segment stacking faults in γ phase. Lattice strains decrease in both the γ matrix and γ' precipitate phases. A constitutive viscoplastic law derived from in-situ isothermal relaxation test under-estimates the equivalent plastic strain in the prediction of the stress and strain evolution during cooling in this case. It is thereby shown that the history dependence of the microstructure needs to be taken into account while deriving a constitutive law and which becomes even more relevant at high temperatures approaching the solvus. Higher temperature cooling experiments have also been carried out between 1300 °C and 1150 °C to measure the evolution of stress and plastic strain close to the γ' solvus temperature. In-situ cooling of samples using ETMT shows that creep dominates during high-temperature deformation between 1300 °C and 1220 °C, but below a threshold temperature, typically 1220 °C work hardening begins to prevail from increasing γ' fraction and resulting in a rapid increase in stress. The history dependence of prior accumulated deformation is also confirmed in the flow stress measurements using a single sample while cooling. The saturation stresses in the flow stress experiments show very good agreement with the stresses measured in the cooling experiments when viscoplastic deformation is dominant. This study demonstrates that experimentation during high-temperature deformation as well as the history dependence of the microstructure during cooling plays a key role in deriving

  13. Vacuum evaporator-crystallizer process development for Hanford defense waste

    International Nuclear Information System (INIS)

    Tanaka, K.H.

    1978-04-01

    One of the major programs in the Department of Energy (DOE) waste management operations at Hanford is the volume reduction and solidification of Hanford Defense Residual Liquor (HDRL) wastes. These wastes are neutralized radioactive wastes that have been concentrated and stored in single-shell underground tanks. Two production vacuum evaporator-crystallizers were built and are operating to reduce the liquid volume and solidify these wastes. The process involves evaporating water under vacuum and thus concentrating and crystallizing the salt waste. The high caustic residual liquor is composed primarily of nitrate, nitrite, aluminate, and carbonate salts. Past evaporator-crystallizer operation was limited to crystallizing nitrate, nitrite, and carbonate salts. These salts formed a drainable salt cake that was acceptable for storage in the original single-shell tanks. The need for additional volume reduction and further concentration necessitated this process development work. Further concentration forms aluminate salts which pose unique processing problems. The aluminate salts are very fine crystals, non-drainable, and suitable only for storage in new double-shell tanks where the fluid waste can be continuously monitored. A pilot scale vacuum evaporator-crystallizer system was built and operated by Rockwell Hanford Operations to support flowsheet development for the production evaporator-crystallizers. The process developed was the concentration of residual liquor to form aluminate salts. The pilot plant tests demonstrated that residual liquors with high aluminum concentrations could be concentrated and handled in a vacuum evaporator-crystallizer system. The dense slurry with high solids content and concentrated liquor was successfully pumped in the insulated heated piping system. The most frequent problem encountered in the pilot plant was the failure of mechanical pump seals due to the abrasive slurry

  14. Process cooling for Africa's food industry

    Energy Technology Data Exchange (ETDEWEB)

    Klempert, Oliver

    2011-07-01

    Temperatures exceeding 40 C are the order of the day, the sun burns brightly in the sky. In Tunisia and Morocco, an international team of scientists now uses solar energy to keep perishable foodstuffs such as milk, wine, fruit and vegetables fresh by means of solar cooling. (orig.)

  15. All-optical image processing with nonlinear liquid crystals

    Science.gov (United States)

    Hong, Kuan-Lun

    Liquid crystals are fascinating materials because of several advantages such as large optical birefringence, dielectric anisotropic, and easily compatible to most kinds of materials. Compared to the electro-optical properties of liquid crystals widely applied in displays and switching application, transparency through most parts of wavelengths also makes liquid crystals a better candidate for all-optical processing. The fast response time of liquid crystals resulting from multiple nonlinear effects, such as thermal and density effect can even make real-time processing realized. In addition, blue phase liquid crystals with spontaneously self-assembled three dimensional cubic structures attracted academic attention. In my dissertation, I will divide the whole contents into six parts. In Chapter 1, a brief introduction of liquid crystals is presented, including the current progress and the classification of liquid crystals. Anisotropy and laser induced director axis reorientation is presented in Chapter 2. In Chapter 3, I will solve the electrostrictive coupled equation and analyze the laser induced thermal and density effect in both static and dynamic ways. Furthermore, a dynamic simulation of laser induced density fluctuation is proposed by applying finite element method. In Chapter 4, two image processing setups are presented. One is the intensity inversion experiment in which intensity dependent phase modulation is the mechanism. The other is the wavelength conversion experiment in which I can read the invisible image with a visible probe beam. Both experiments are accompanied with simulations to realize the matching between the theories and practical experiment results. In Chapter 5, optical properties of blue phase liquid crystals will be introduced and discussed. The results of grating diffractions and thermal refractive index gradient are presented in this chapter. In addition, fiber arrays imaging and switching with BPLCs will be included in this chapter

  16. Cycle time improvement for plastic injection moulding process by sub groove modification in conformal cooling channel

    Science.gov (United States)

    Kamarudin, K.; Wahab, M. S.; Batcha, M. F. M.; Shayfull, Z.; Raus, A. A.; Ahmed, Aqeel

    2017-09-01

    Mould designers have been struggling for the improvement of the cooling system performance, despite the fact that the cooling system complexity is physically limited by the fabrication capability of the conventional tooling methods. However, the growth of Solid Free Form Technology (SFF) allow the mould designer to develop more than just a regular conformal cooling channel. Numerous researchers demonstrate that conformal cooling channel was tremendously given significant result in the improvement of productivity and quality in the plastic injection moulding process. This paper presents the research work that applies the passive enhancement method in square shape cooling channel to enhance the efficiency of cooling performance by adding the sub groove to the cooling channel itself. Previous design that uses square shape cooling channel was improved by adding various numbers of sub groove to meet the best sub groove design that able reduced the cooling time. The effect of sub groove design on cooling time was investigated by Autodesk Modlflow Insight software. The simulation results showed that the various sub groove designs give different values to ejection time. The Design 7 showed the lowest value of ejection time with 24.3% increment. The addition of sub groove significantly increased a coolant velocity and a rate of heat transfer from molten plastic to coolant.

  17. Dynamic crystallization of a eucrite basalt. [achondrite textural features produced by superheating and differing cooling rates

    Science.gov (United States)

    Walker, D.; Powell, M. A.; Hays, J. F.; Lofgren, G. E.

    1978-01-01

    The textural features produced in Stannern, a non-porpyritic representative of the eucrite basaltic achondrite class of meteorite, at differing cooling rates and various degrees of initial superheating were studied. Textures produced from mildly superheated melts were found to be fasciculate rather than porphyritic as the result of the cosaturated bulk chemistry of Stannern. The qualitative type of texture apparently depends mainly on the degree of initial superheating, whereas cooling rate exerts a strong influence on the coarseness of texture. Increasing the degree of superheating produces textures from intergranular/subophitic to fasciculate/porphyritic. With initial superheating to 1200 deg C the transition to quasi-porphyritic is controlled by cooling rate, but the development of phenocrysts is merely an overprint on the fasciculate background texture of the groundmass. The suppression of fasciculate texture is completed by a decrease of the degree of initial superheating below the plagioclast entry and suppression of quasi-porphyritic texture is completed by decrease of the degree of initial superheating below pyroxene entry; these qualitative changes do not seem to be produced by changes of cooling rate. A grain size/cooling rate dependence has been used to deduce the cooling rate of fasciculate-textured Stannern clasts (10.1 to 100 deg C/hr).

  18. Photodynamic Processes in Fluoride Crystals Doped with Ce3+

    Directory of Open Access Journals (Sweden)

    Pavlov V.V.

    2015-01-01

    Full Text Available Integrated studies of photoelectric phenomena and their associated photodynamic processes in LiCaAlF6, LiLuF4, LiYF4, LiY0,5Lu0,5F4, SrAlF5 crystals doped with Ce3+ ions have been carried out using the combination of the methods of optical and dielectric spectroscopy. The numerical values of the basic parameters of photodynamic processes and their spectral dependence in 240 – 310 nm spectral range are evaluated. It has been shown that the most probable process, which leads to the photoionization of Ce3+ ions in LiYxLu1-xF4:Ce3+ (x=0; 0,5; 1 and LiCaAlF6:Ce3+ crystals, is excited-state absorption to the states of mixed configurations of Ce3+ ions localized near/in the conduction band of crystal.

  19. The effect of primary copper slag cooling rate on the copper valorization in the flotation process

    Directory of Open Access Journals (Sweden)

    Aleksandar Mihajlović

    2015-06-01

    Full Text Available Technological procedure of slow cooling slag from primary copper production is applied in the purpose of copper recovery in the level of 98.5% to blister. This technological procedure is divided into two phases, first slow cooling of slag on the air for 24 hours, and then accelerated cooling with water for 48 hours. Within the research following methods were used: calculation of nonstationary slag cooling, verification of the calculation using computer simulation of slag cooling in the software package COMSOL Multiphysics and experimental verification of simulation results. After testing of the experimentally gained samples of slowly cooled slag it was found that this technological procedure gives the best results in promoting growth or coagulation of dispersed particles of copper sulfide and copper in the slag, thereby increasing the utilization of the flotation process with a decrease of copper losses through very fine particles.

  20. Geothermal energy used in a cooling generation process

    International Nuclear Information System (INIS)

    Benzaoui, A.; El Gharbi, N.; Merabti, L.

    2006-01-01

    This paper deals with the geothermal energy recovery and use. It is available in an important water reservoir at 1800 m deep. Some drilled wells deliver each one about 200 1/s at 75-95 degree centigrade for agricultural use. It is necessarily cooled to be in irrigation conditions at 20-25 degree centigrade. Our purpose is to install the adequate sized heat exchangers to recover this important energy and to use it in different needs. Furthermore, a systematic survey is made, on the basis od Lindal Diagram, about different possibilities to use this geothermal reservoir available in arid area. Several applications are experimented and presented to farmers: air conditioning, domestic space heating, bathing, fruits and products drying, aqua fishing, etc.. In this report we present the study including scientific and technical questions (heat and mass transfer, absorption cooling generating, energy and mass balances, etc..). The available heat must be upgraded.The solar energy is used for this need. The total experimental cooled space is: 4 rooms X 210 m 3 . The coefficient of performance of the set up is 44% and could be enhanced. Inhabitants could use this fresh atmosphere to stock their products and to pay some home comfort. All calculations and theoretical simulations will be presented and commented.(Author)

  1. Downstream Processability of Crystal Habit-Modified Active Pharmaceutical Ingredient

    DEFF Research Database (Denmark)

    Pudasaini, Nawin; Upadhyay, Pratik Pankaj; Parker, Christian Richard

    2017-01-01

    Efficient downstream processing of active pharmaceutical ingredients (APIs) can depend strongly on their particulate properties, such as size and shape distributions. Especially in drug products with high API content, needle-like crystal habit of an API may show compromised flowability and tablet......Efficient downstream processing of active pharmaceutical ingredients (APIs) can depend strongly on their particulate properties, such as size and shape distributions. Especially in drug products with high API content, needle-like crystal habit of an API may show compromised flowability...

  2. A Robust Process Analytical Technology (PAT) System Design for Crystallization Processes

    DEFF Research Database (Denmark)

    Abdul Samad, Noor Asma Fazli Bin; Sin, Gürkan; Gernaey, Krist

    2013-01-01

    A generic computer-aided framework for systematic design of a process monitoring and control system for crystallization processes has been developed to study various aspects of crystallization operations. The design framework contains a generic multidimensional modelling framework, a tool for gen...

  3. Introducing uncertainty analysis of nucleation and crystal growth models in Process Analytical Technology (PAT) system design of crystallization processes

    DEFF Research Database (Denmark)

    Abdul Samad, Noor Asma Fazli Bin; Sin, Gürkan; Gernaey, Krist

    2013-01-01

    This paper presents the application of uncertainty and sensitivity analysis as part of a systematic modelbased process monitoring and control (PAT) system design framework for crystallization processes. For the uncertainty analysis, the Monte Carlo procedure is used to propagate input uncertainty...

  4. Equilibrium positions due to different cooling processes in superconducting levitation systems

    International Nuclear Information System (INIS)

    Navau, C; Sanchez, A; Pardo, E; Chen, D-X

    2004-01-01

    The equilibrium position of a superconducting levitation device is determined not only by the geometry and electromagnetic properties of its components, but also by the cooling process of the superconductor. In this work we study the dependence of the equilibrium positions upon the cooling process by introducing diagrams of a new kind which display the different possibilities for a given levitation system. Using the critical state model and the principle of magnetic energy, we calculate different diagrams of this type for the case of a cylindrically symmetric permanent magnet-superconductor system. The results allow us to find out, for a given levitation system, which cooling process improves the capabilities of the system

  5. Effect of process parameters on crystal size and morphology of lactose in ultrasound-assisted crystallization

    Energy Technology Data Exchange (ETDEWEB)

    Patel, S.R.; Murthy, Z.V.P. [Chemical Engineering Department, S.V. National Institute of Technology, Surat - 395 007, Gujarat (India)

    2011-03-15

    {alpha}-lactose monohydrate is widely used as a pharmaceutical excipient. Drug delivery system requires the excipient to be of narrow particle size distribution with regular particle shape. Application of ultrasound is known to increase or decrease the growth rate of certain crystal faces and controls the crystal size distribution. In the present paper, effect of process parameters such as sonication time, anti-solvent concentration, initial lactose concentration and initial pH of sample on lactose crystal size, shape and thermal transition temperature was studied. The parameters were set according to the L{sub 9}-orthogonal array method at three levels and recovered lactose from whey by sonocrystallization. The recovered lactose was analyzed by particle size analyzer, scanning electron microscopy and differential scanning calorimeter. It was found that the morphology of lactose crystal was rod/needle like shape. Crystal size distribution of lactose was observed to be influenced by different process parameters. From the results of analysis of variance, the sonication time interval was found to be the most significant parameter affecting the volume median diameter of lactose with the highest percentage contribution (74.28%) among other parameters. (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  6. Photonic Crystal Nanocavity Devices for Nonlinear Signal Processing

    DEFF Research Database (Denmark)

    Yu, Yi

    , membranization of InP/InGaAs structure and wet etching. Experimental investigation of the switching dynamics of InP photonic crystal nanocavity structures are carried out using short-pulse homodyne pump-probe techniques, both in the linear and nonlinear region where the cavity is perturbed by a relatively small......This thesis deals with the investigation of InP material based photonic crystal cavity membrane structures, both experimentally and theoretically. The work emphasizes on the understanding of the physics underlying the structures’ nonlinear properties and their applications for all-optical signal...... processing. Based on the previous fabrication recipe developed in our III-V platform, several processing techniques are developed and optimized for the fabrication of InP photonic crystal membrane structures. Several key issues are identified to ensure a good device quality such as air hole size control...

  7. Cooling tower make-up water processing for nuclear power plants: a comparison

    Energy Technology Data Exchange (ETDEWEB)

    Andres, O; Flunkert, F; Hampel, G; Schiffers, A [Rheinisch-Westfaelisches Elektrizitaetswerk A.G., Essen (Germany, F.R.)

    1977-01-01

    In water-cooled nuclear power plants, 1 to 2% of the total investment costs go to cooling tower make-up water processing. The crude water taken from rivers or stationary waters for cooling must be sufficiently purified regarding its content of solids, carbonate hardness and corrosive components so as to guarantee an operation free of disturbances. At the same time, the processing methods must be selected for operational-economic reasons in such a manner that waste water and waste problems are kept small regarding environmental protection. The various parameters described have a decisive influence on the processing methods of the crude water, individual processes (filtration, sedimentation, decarbonization) are described, circuit possibilities for cooling water systems are compared and the various processes are analyzed and compared with regard to profitableness and environmental compatability.

  8. Introducing uncertainty analysis of nucleation and crystal growth models in Process Analytical Technology (PAT) system design of crystallization processes.

    Science.gov (United States)

    Samad, Noor Asma Fazli Abdul; Sin, Gürkan; Gernaey, Krist V; Gani, Rafiqul

    2013-11-01

    This paper presents the application of uncertainty and sensitivity analysis as part of a systematic model-based process monitoring and control (PAT) system design framework for crystallization processes. For the uncertainty analysis, the Monte Carlo procedure is used to propagate input uncertainty, while for sensitivity analysis, global methods including the standardized regression coefficients (SRC) and Morris screening are used to identify the most significant parameters. The potassium dihydrogen phosphate (KDP) crystallization process is used as a case study, both in open-loop and closed-loop operation. In the uncertainty analysis, the impact on the predicted output of uncertain parameters related to the nucleation and the crystal growth model has been investigated for both a one- and two-dimensional crystal size distribution (CSD). The open-loop results show that the input uncertainties lead to significant uncertainties on the CSD, with appearance of a secondary peak due to secondary nucleation for both cases. The sensitivity analysis indicated that the most important parameters affecting the CSDs are nucleation order and growth order constants. In the proposed PAT system design (closed-loop), the target CSD variability was successfully reduced compared to the open-loop case, also when considering uncertainty in nucleation and crystal growth model parameters. The latter forms a strong indication of the robustness of the proposed PAT system design in achieving the target CSD and encourages its transfer to full-scale implementation. Copyright © 2013 Elsevier B.V. All rights reserved.

  9. Stability and servo-control of the crystal pulling process

    International Nuclear Information System (INIS)

    Johansen, T.H.

    1990-11-01

    The paper analyzes why the crystal pulling process needs servo-control, and how it can be implemented. Special emphasis is put on the fundamental question of inherent stability, and how to interpret the signal from a balance when the weighing method is used for cystal diameter detection. 15 refs., 13 figs

  10. Control of a nonlinear ice cream crystallization process

    OpenAIRE

    Casenave, Céline; Dochain, Denis; Alvarez, Graciela; Arellano, Marcela; Benkhelifa, Hayat; Leducq, Denis

    2013-01-01

    International audience; In the ice cream industry, the type of final desired product (large cartons (sqrounds) or ice creams on a stick) determine the viscosity at which the ice cream has to be produced. One of the objectives of the ice cream crystallization processes is therefore to produce an ice cream of specified viscosity. In this paper, a nonlinear control strategy is proposed for the control of the viscosity of the ice cream in a continuous crystallizer. It has been designed on the bas...

  11. Iron crystallization in a fluidized-bed Fenton process.

    Science.gov (United States)

    Boonrattanakij, Nonglak; Lu, Ming-Chun; Anotai, Jin

    2011-05-01

    The mechanisms of iron precipitation and crystallization in a fluidized-bed reactor were investigated. Within the typical Fenton's reagent dosage and pH range, ferric ions as a product from ferrous ion oxidation would be supersaturated and would subsequently precipitate out in the form of ferric hydroxide after the initiation of the Fenton reaction. These precipitates would simultaneously crystallize onto solid particles in a fluidized-bed Fenton reactor if the precipitation proceeded toward heterogeneous nucleation. The heterogeneous crystallization rate was controlled by the fluidized material type and the aging/ripening period of the crystallites. Iron crystallization onto the construction sand was faster than onto SiO(2), although the iron removal efficiencies at 180 min, which was principally controlled by iron hydroxide solubility, were comparable. To achieve a high iron removal rate, fluidized materials have to be present at the beginning of the Fenton reaction. Organic intermediates that can form ferro-complexes, particularly volatile fatty acids, can significantly increase ferric ion solubility, hence reducing the crystallization performance. Therefore, the fluidized-bed Fenton process will achieve exceptional performance with respect to both organic pollutant removal and iron removal if it is operated with the goal of complete mineralization. Crystallized iron on the fluidized media could slightly retard the successive crystallization rate; thus, it is necessary to continuously replace a portion of the iron-coated bed with fresh media to maintain iron removal performance. The iron-coated construction sand also had a catalytic property, though was less than those of commercial goethite. Copyright © 2011 Elsevier Ltd. All rights reserved.

  12. A Generic Framework for Systematic Design of Process Monitoring and Control System for Crystallization Processes

    DEFF Research Database (Denmark)

    Abdul Samad, Noor Asma Fazli Bin; Meisler, Kresten Troelstrup; Sin, Gürkan

    2012-01-01

    Crystallization processes have a wide range of application as a solid-liquid separation technique in the chemical, the pharmaceutical and the food industries, due to the fact that high quality crystalline products can be produced. The main specifications of the crystal product are usually given i...

  13. Manufacturability of Wood Plastic Composite Sheets on the Basis of the Post-Processing Cooling Curve

    Directory of Open Access Journals (Sweden)

    Sami Matthews

    2015-10-01

    Full Text Available Extruded wood-plastic composites (WPCs are increasingly regarded as promising materials for future manufacturing industries. It is necessary to select and tune the post-processing methods to be able to utilize these materials fully. In this development, temperature-related material properties and the cooling rate are important indicators. This paper presents the results of natural cooling in a factory environment fit into a cooling curve function with temperature zones for forming, cutting, and packaging overlaid using a WPC material. This information is then used in the evaluation of manufacturability and productivity in terms of cost effectiveness and technical quality by comparing the curve to actual production time data derived from a prototype post-process forming line. Based on this information, speed limits for extrusion are presented. This paper also briefly analyzes techniques for controlling material cooling to counter the heat loss before post-processing.

  14. Improvement of crystal identification performance for a four-layer DOI detector composed of crystals segmented by laser processing

    Science.gov (United States)

    Mohammadi, Akram; Inadama, Naoko; Yoshida, Eiji; Nishikido, Fumihiko; Shimizu, Keiji; Yamaya, Taiga

    2017-09-01

    We have developed a four-layer depth of interaction (DOI) detector with single-side photon readout, in which segmented crystals with the patterned reflector insertion are separately identified by the Anger-type calculation. Optical conditions between segmented crystals, where there is no reflector, affect crystal identification ability. Our objective of this work was to improve crystal identification performance of the four-layer DOI detector that uses crystals segmented with a recently developed laser processing technique to include laser processed boundaries (LPBs). The detector consisted of 2 × 2 × 4mm3 LYSO crystals and a 4 × 4 array multianode photomultiplier tube (PMT) with 4.5 mm anode pitch. The 2D position map of the detector was calculated by the Anger calculation method. At first, influence of optical condition on crystal identification was evaluated for a one-layer detector consisting of a 2 × 2 crystal array with three different optical conditions between the crystals: crystals stuck together using room temperature vulcanized (RTV) rubber, crystals with air coupling and segmented crystals with LPBs. The crystal array with LPBs gave the shortest distance between crystal responses in the 2D position map compared with the crystal array coupled with RTV rubber or air due to the great amount of cross-talk between segmented crystals with LPBs. These results were used to find optical conditions offering the optimum distance between crystal responses in the 2D position map for the four-layer DOI detector. Crystal identification performance for the four-layer DOI detector consisting of an 8 × 8 array of crystals segmented with LPBs was examined and it was not acceptable for the crystals in the first layer. The crystal identification was improved for the first layer by changing the optical conditions between all 2 × 2 crystal arrays of the first layer to RTV coupling. More improvement was observed by combining different optical conditions between all

  15. Liquid desiccant dehumidification and regeneration process to meet cooling and freshwater needs of desert greenhouses

    KAUST Repository

    Lefers, Ryan

    2016-04-19

    Agriculture accounts for ~70% of freshwater usage worldwide. Seawater desalination alone cannot meet the growing needs for irrigation and food production, particularly in hot, desert environments. Greenhouse cultivation of high-value crops uses just a fraction of freshwater per unit of food produced when compared with open field cultivation. However, desert greenhouse producers face three main challenges: freshwater supply, plant nutrient supply, and cooling of the greenhouse. The common practice of evaporative cooling for greenhouses consumes large amounts of fresh water. In Saudi Arabia, the most common greenhouse cooling schemes are fresh water-based evaporative cooling, often using fossil groundwater or energy-intensive desalinated water, and traditional refrigeration-based direct expansion cooling, largely powered by the burning of fossil fuels. The coastal deserts have ambient conditions that are seasonally too humid to support adequate evaporative cooling, necessitating additional energy consumption in the dehumidification process of refrigeration-based cooling. This project evaluates the use of a combined-system liquid desiccant dehumidifier and membrane distillation unit that can meet the dual needs of cooling and freshwater supply for a greenhouse in a hot and humid environment. © 2016 Balaban Desalination Publications. All rights reserved.

  16. Crystallization process of a three-dimensional complex plasma

    Science.gov (United States)

    Steinmüller, Benjamin; Dietz, Christopher; Kretschmer, Michael; Thoma, Markus H.

    2018-05-01

    Characteristic timescales and length scales for phase transitions of real materials are in ranges where a direct visualization is unfeasible. Therefore, model systems can be useful. Here, the crystallization process of a three-dimensional complex plasma under gravity conditions is considered where the system ranges up to a large extent into the bulk plasma. Time-resolved measurements exhibit the process down to a single-particle level. Primary clusters, consisting of particles in the solid state, grow vertically and, secondarily, horizontally. The box-counting method shows a fractal dimension of df≈2.72 for the clusters. This value gives a hint that the formation process is a combination of local epitaxial and diffusion-limited growth. The particle density and the interparticle distance to the nearest neighbor remain constant within the clusters during crystallization. All results are in good agreement with former observations of a single-particle layer.

  17. Inverse opal photonic crystal of chalcogenide glass by solution processing.

    Science.gov (United States)

    Kohoutek, Tomas; Orava, Jiri; Sawada, Tsutomu; Fudouzi, Hiroshi

    2011-01-15

    Chalcogenide opal and inverse opal photonic crystals were successfully fabricated by low-cost and low-temperature solution-based process, which is well developed in polymer films processing. Highly ordered silica colloidal crystal films were successfully infilled with nano-colloidal solution of the high refractive index As(30)S(70) chalcogenide glass by using spin-coating method. The silica/As-S opal film was etched in HF acid to dissolve the silica opal template and fabricate the inverse opal As-S photonic crystal. Both, the infilled silica/As-S opal film (Δn ~ 0.84 near λ=770 nm) and the inverse opal As-S photonic structure (Δn ~ 1.26 near λ=660 nm) had significantly enhanced reflectivity values and wider photonic bandgaps in comparison with the silica opal film template (Δn ~ 0.434 near λ=600 nm). The key aspects of opal film preparation by spin-coating of nano-colloidal chalcogenide glass solution are discussed. The solution fabricated "inorganic polymer" opal and the inverse opal structures exceed photonic properties of silica or any organic polymer opal film. The fabricated photonic structures are proposed for designing novel flexible colloidal crystal laser devices, photonic waveguides and chemical sensors. Copyright © 2010 Elsevier Inc. All rights reserved.

  18. System design package for the solar heating and cooling central data processing system

    Science.gov (United States)

    1978-01-01

    The central data processing system provides the resources required to assess the performance of solar heating and cooling systems installed at remote sites. These sites consist of residential, commercial, government, and educational types of buildings, and the solar heating and cooling systems can be hot-water, space heating, cooling, and combinations of these. The instrumentation data associated with these systems will vary according to the application and must be collected, processed, and presented in a form which supports continuity of performance evaluation across all applications. Overall software system requirements were established for use in the central integration facility which transforms raw data collected at remote sites into performance evaluation information for assessing the performance of solar heating and cooling systems.

  19. Thermal expansion and cooling rate dependence of transition temperature in ZrTiO4 single crystal

    International Nuclear Information System (INIS)

    Park, Y.

    1998-01-01

    Thermal expansion in ZrTiO 4 single crystal was investigated in the temperature range covering the normal, incommensurate, and commensurate phases. Remarkable change was found at the normal-incommensurate phase transition (T I ) in all thermal expansion coefficients a, b, and c. The spontaneous strains χ as and χ bs along the a and b axes show linear temperature dependence, while the spontaneous strain χ cs along the c axis shows a nonlinear temperature dependence. Small discontinuity along the c direction was observed at the incommensurate-commensurate transition temperature, T c = 845 C. dT I /dP and dT c /dP depend on the cooling rate

  20. Closed-cycle process of coke-cooling water in delayed coking unit

    International Nuclear Information System (INIS)

    Zhou, P.; Bai, Z.S.; Yang, Q.; Ma, J.; Wang, H.L.

    2008-01-01

    Synthesized processes are commonly used to treat coke-cooling wastewater. These include cold coke-cut water, diluting coke-cooling water, adding chemical deodorization into oily water, high-speed centrifugal separation, de-oiling and deodorization by coke adsorption, and open nature cooling. However, because of water and volatile evaporation loss, it is not suitable to process high-sulphur heavy oil using open treatments. This paper proposed a closed-cycling process in order to solve the wastewater treatment problem. The process is based on the characteristics of coke-cooling water, such as rapid parametric variation, oil-water-coke emulsification and steam-water mixing. The paper discussed the material characteristics and general idea of the study. The process of closed-cycle separation and utilization process of coke-cooling water was presented along with a process flow diagram. Several applications were presented, including a picture of hydrocyclones for pollution separation and a picture of equipments of pollution separation and components regeneration. The results showed good effect had been achieved since the coke-cooling water system was put into production in 2004. The recycling ratios for the components of the coke-cooling water were 100 per cent, and air quality in the operating area reached the requirements of the national operating site circumstance and the health standards. Calibration results of the demonstration unit were presented. It was concluded that since the devices went into operation, the function of production has been normal and stable. The operation was simple, flexible, adjustable and reliable, with significant economic efficiency and environmental benefits. 10 refs., 2 tabs., 3 figs

  1. Startup of Pumping Units in Process Water Supplies with Cooling Towers at Thermal and Nuclear Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Berlin, V. V., E-mail: vberlin@rinet.ru; Murav’ev, O. A., E-mail: muraviov1954@mail.ru; Golubev, A. V., E-mail: electronik@inbox.ru [National Research University “Moscow State University of Civil Engineering,” (Russian Federation)

    2017-03-15

    Aspects of the startup of pumping units in the cooling and process water supply systems for thermal and nuclear power plants with cooling towers, the startup stages, and the limits imposed on the extreme parameters during transients are discussed.

  2. Processes setting the characteristics of sea surface cooling induced by tropical cyclones

    OpenAIRE

    Vincent, E.M.; Lengaigne, Matthieu; Madec, G.; Vialard, Jérôme; Samson, G.; Jourdain, N.C.; Menkès, Christophe; Jullien, S.

    2012-01-01

    A 1/2 degrees resolution global ocean general circulation model is used to investigate the processes controlling sea surface cooling in the wake of tropical cyclones (TCs). Wind forcing related to more than 3000 TCs occurring during the 1978-2007 period is blended with the CORE II interannual forcing, using an idealized TC wind pattern with observed magnitude and track. The amplitude and spatial characteristics of the TC-induced cooling are consistent with satellite observations, with an aver...

  3. Comment on "Rapid cooling and cold storage in a silicic magma reservoir recorded in individual crystals".

    Science.gov (United States)

    Wilson, Colin J N; Morgan, Daniel J; Charlier, Bruce L A; Barker, Simon J

    2017-12-22

    Rubin et al (Reports, 16 June 2017, p. 1154) proposed that gradients in lithium abundance in zircons from a rhyolitic eruption in New Zealand reflected short-lived residence at magmatic temperatures interleaved with long-term "cold" (<650°C) storage. Important issues arise with the interpretation of these lithium gradients and consequent crystal thermal histories that raise concerns about the validity of this conclusion. Copyright © 2017, American Association for the Advancement of Science.

  4. Electron spin resonance of Gd in the nuclear cooling agent: PrNi5 single crystals

    International Nuclear Information System (INIS)

    Levin, R.; Davidov, D.; Grayevsky, A.; Shaltiel, D.; Zevin, V.

    1980-01-01

    The ESR of Gd in single crystals of PrNi 5 is observed to exhibit significant angular dependence of the resonance position and linewidth at low temperatures. This is interpreted in terms of the axial spin Hamiltonian which takes the anisotropic susceptibility and the Gd-Pr exchange into consideration. From lineshape analysis the axial crystal field parameter and isotropic Gd-Pr exchange are derived. The Gd ESR linewidth increases with temperature; the thermal broadening is angularly dependent. This is similar to that observed for the Pr NMR in PrNi 5 single crystals. Both the NMR and ESR thermal broadenings are attributed to low-frequency fluctuations of the Pr ions induced by the Pr-Pr exchange coupling. A model for hexagonal Van-Vleck compounds is given and with the linewidth enables the Pr-Pr exchange coupling, under the assumption of a Gaussian or a Lorenzian distribution of the low-frequency fluctuation spectra, to be extracted. It is suggested that the angular dependence of the ESR thermal broadening is due to the Gd-Pr exchange coupling. (UK)

  5. Energy transfer processes in Er-doped crystals

    International Nuclear Information System (INIS)

    Georgescu, Serban; Toma, Octavian

    2005-01-01

    In this paper, the microparameters characteristic to various energy-transfer processes in erbium doped crystals are estimated using the Dexter theory. For all the investigated processes, electric dipole-dipole interaction between donor and acceptor ions is assumed. The spectra appearing in Dexter's expression of the microparameter are simulated as a superposition of Lorentzian lines, knowing the positions of both initial and final Stark levels, and calibrated using the Judd-Ofelt model. This approach can give an estimation of the importance of the energy-transfer processes. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  6. Effect of titanium dioxide (TiO{sub 2}) on largely improving solar reflectance and cooling property of high density polyethylene (HDPE) by influencing its crystallization behavior

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Shichao; Zhang, Jun, E-mail: zhangjun@njtech.edu.cn

    2014-12-25

    Highlights: • HDPE/TiO{sub 2} composites have more perfect crystal structure. • Refractive index is the key factor affecting the final solar reflectance. • HDPE/TiO{sub 2} composites can achieve high solar reflectance. • The real cooling property is in accordance with solar reflectance. - Abstract: In this study, the different crystal forms of titanium dioxide (TiO{sub 2}) were added into high density polyethylene (HDPE) to fabricate cool material. Crystal structure, crystallization behavior, crystal morphology were investigated by wide angle X-ray diffraction (WAXD), differential scanning calorimetry (DSC) and polarized optical microscope (POM). Scanning electron microscope (SEM) was applied to observe dispersion of TiO{sub 2} particles in the HDPE matrix and the cross section morphology. The solar reflectance and actual cooling property were evaluated by UV–Vis–NIR spectrometer and a self-designed device. By adding TiO{sub 2} particles into HDPE matrix, the polymer chain could crystallize into more perfect and thermal stable lamella. The presence of TiO{sub 2} particles dramatically increased the number of nucleation site therefore decreased the crystal size. The subsequent solar reflectance was related to the degree of crystallinity, the spherulite size of HDPE, refractive index, and distribution of TiO{sub 2} particles in HDPE matrix. It was found the rutile TiO{sub 2} could largely improve the total solar reflectance from 28.2% to 51.1%. Finally, the temperature test showed that the composites had excellent cooling property, which was in accordance with solar reflectance result.

  7. Effect of titanium dioxide (TiO2) on largely improving solar reflectance and cooling property of high density polyethylene (HDPE) by influencing its crystallization behavior

    International Nuclear Information System (INIS)

    Wang, Shichao; Zhang, Jun

    2014-01-01

    Highlights: • HDPE/TiO 2 composites have more perfect crystal structure. • Refractive index is the key factor affecting the final solar reflectance. • HDPE/TiO 2 composites can achieve high solar reflectance. • The real cooling property is in accordance with solar reflectance. - Abstract: In this study, the different crystal forms of titanium dioxide (TiO 2 ) were added into high density polyethylene (HDPE) to fabricate cool material. Crystal structure, crystallization behavior, crystal morphology were investigated by wide angle X-ray diffraction (WAXD), differential scanning calorimetry (DSC) and polarized optical microscope (POM). Scanning electron microscope (SEM) was applied to observe dispersion of TiO 2 particles in the HDPE matrix and the cross section morphology. The solar reflectance and actual cooling property were evaluated by UV–Vis–NIR spectrometer and a self-designed device. By adding TiO 2 particles into HDPE matrix, the polymer chain could crystallize into more perfect and thermal stable lamella. The presence of TiO 2 particles dramatically increased the number of nucleation site therefore decreased the crystal size. The subsequent solar reflectance was related to the degree of crystallinity, the spherulite size of HDPE, refractive index, and distribution of TiO 2 particles in HDPE matrix. It was found the rutile TiO 2 could largely improve the total solar reflectance from 28.2% to 51.1%. Finally, the temperature test showed that the composites had excellent cooling property, which was in accordance with solar reflectance result

  8. Novel casting processes for single-crystal turbine blades of superalloys

    Science.gov (United States)

    Ma, Dexin

    2018-03-01

    This paper presents a brief review of the current casting techniques for single-crystal (SC) blades, as well as an analysis of the solidification process in complex turbine blades. A series of novel casting methods based on the Bridgman process were presented to illustrate the development in the production of SC blades from superalloys. The grain continuator and the heat conductor techniques were developed to remove geometry-related grain defects. In these techniques, the heat barrier that hinders lateral SC growth from the blade airfoil into the extremities of the platform is minimized. The parallel heating and cooling system was developed to achieve symmetric thermal conditions for SC solidification in blade clusters, thus considerably decreasing the negative shadow effect and its related defects in the current Bridgman process. The dipping and heaving technique, in which thinshell molds are utilized, was developed to enable the establishment of a high temperature gradient for SC growth and the freckle-free solidification of superalloy castings. Moreover, by applying the targeted cooling and heating technique, a novel concept for the three-dimensional and precise control of SC growth, a proper thermal arrangement may be dynamically established for the microscopic control of SC growth in the critical areas of large industrial gas turbine blades.

  9. Crystal Sinking Modeling for Designing Iodine Crystallizer in Thermochemical Sulfur-Iodine Hydrogen Production Process

    Energy Technology Data Exchange (ETDEWEB)

    Park, Byung Heung [Korea National University of Transportation, Chungju (Korea, Republic of); Jeong, Seong-Uk [Korea Institute of Energy Research, Daejeon (Korea, Republic of); Kang, Jeong Won [Korea University, Seoul (Korea, Republic of)

    2014-12-15

    SI process is a thermochemical process producing hydrogen by decomposing water while recycling sulfur and iodine. Various technologies have been developed to improve the efficiency on Section III of SI process, where iodine is separated and recycled. EED(electro-electrodialysis) could increase the efficiency of Section III without additional chemical compounds but a substantial amount of I{sub 2} from a process stream is loaded on EED. In order to reduce the load, a crystallization technology prior to EED is considered as an I{sub 2} removal process. In this work, I{sub 2} particle sinking behavior was modeled to secure basic data for designing an I{sub 2} crystallizer applied to I{sub 2}-saturated HI{sub x} solutions. The composition of HI{sub x} solution was determined by thermodynamic UVa model and correlation equations and pure properties were used to evaluate the solution properties. A multiphysics computational tool was utilized to calculate particle sinking velocity changes with respect to I{sub 2} particle radius and temperature. The terminal velocity of an I{sub 2} particle was estimated around 0.5 m/s under considered radius (1.0 to 2.5 mm) and temperature (10 to 50 .deg. C) ranges and it was analyzed that the velocity is more dependent on the solution density than the solution viscosity.

  10. Mass production and photoelectric performances of P and Al Co-doped ZnO nanocrystals under different cooling post-processes

    International Nuclear Information System (INIS)

    Deng, Ya-Juan; Lu, Yi; Liu, Jin-Ku; Yang, Xiao-Hong

    2015-01-01

    The phosphorus and aluminum co-doped in zinc oxide (ZnO) called PAZO nano-crystals (NCs) have been mass synthesized by a combustion method, which shows a preferable photocatalytic capability and conductive ability. This article focuses on the properties of PAZO NCs experienced by three cooling-down aftertreatments, which were the normalizing, quenching and annealing process, respectively. The influences of different cooling processes on the photocatalytic and conductive performances are discussed in details. From the research, we found the quenched-PAZO NCs showed the most unappealing photocatalysis and conductivity, because excessive defects as the recombination center of electron–hole pairs were generated in the quenching process. - Graphical abstract: This research focuses on the PAZO NCs experienced by different cooling-down aftertreatments, which were the normalizing, quenching and annealing process, respectively. The quenched-PAZO NCs had the most unappealing photocatalysis and conductivity, because of generating excessive defects as the recombination center of electron–hole pairs in the quenching process. - Highlights: • We presented a method to mass synthesize co-doped P and Al in ZnO nanocrystals. • The PAZO NCs have novel photoelectric performances. • The cooling post-process influence on the photoelectric properties was studied. • The excessive defects decline the photocatalytic and conductive activities

  11. Dimensional accuracy of internal cooling channel made by selective laser melting (SLM And direct metal laser sintering (DMLS processes in fabrication of internally cooled cutting tools

    Directory of Open Access Journals (Sweden)

    Ghani S. A. C.

    2017-01-01

    Full Text Available Selective laser melting(SLM and direct metal laser sintering(DMLS are preferred additive manufacturing processes in producing complex physical products directly from CAD computer data, nowadays. The advancement of additive manufacturing promotes the design of internally cooled cutting tool for effectively used in removing generated heat in metal machining. Despite the utilisation of SLM and DMLS in a fabrication of internally cooled cutting tool, the level of accuracy of the parts produced remains uncertain. This paper aims at comparing the dimensional accuracy of SLM and DMLS in machining internally cooled cutting tool with a special focus on geometrical dimensions such as hole diameter. The surface roughness produced by the two processes are measured with contact perthometer. To achieve the objectives, geometrical dimensions of identical tool holders for internally cooled cutting tools fabricated by SLM and DMLS have been determined by using digital vernier calliper and various magnification of a portable microscope. In the current study, comparing internally cooled cutting tools made of SLM and DMLS showed that generally the higher degree of accuracy could be obtained with DMLS process. However, the observed differences in surface roughness between SLM and DMLS in this study were not significant. The most obvious finding to emerge from this study is that the additive manufacturing processes selected for fabricating the tool holders for internally cooled cutting tool in this research are capable of producing the desired internal channel shape of internally cooled cutting tool.

  12. Stochastic behavior of cooling processes in hot nuclei

    International Nuclear Information System (INIS)

    de Oliveira, P.M.; Sa Martins, J.S.; Szanto de Toledo, A.

    1997-01-01

    The collapse of structure effects observed in hot nuclei is interpreted in terms of a dynamic lattice model which describes the process of nucleon (clusters) evaporation from a hot nucleus, predicting the final mass distribution. Results are compared with experimental data for the 10 B+ 9 Be and 10 B+ 10 B reactions, and indicate that the structures observed in the low-energy mass distributions in both simulation and experiment are a consequence of the competition between the residual interactions and the thermalization dissipative process. As a characteristic feature of complex evolving systems, this competition leads to long term memory during the dissipative path, the observables becoming thus insensitive to the actual microscopic interactions. copyright 1997 The American Physical Society

  13. The design of integrated cooling processes in district heating systems; Kylprocessers design i fjaerrvaermesystem

    Energy Technology Data Exchange (ETDEWEB)

    Martin, Viktoria [Royal Inst. of Technology, Stockholm (SE). Dept. of Chemical Engineering and Technology; Setterwall, Fredrik [Fredrik Setterwall Konsult AB, Sollentuna (Sweden); Andersson, Mikael [AB Berglunds Rostfria, Boden (Sweden)

    2005-07-01

    This report presents the results from an investigation regarding the design of integrated cooling processes in district heating systems. Increasing investment levels in district heating networks combined with expanding comfort cooling demand makes heat-driven cooling processes extremely interesting. This solution has a great potential tbe cost effective. At the same time, the problem with the environmentally harmful refrigerants used in conventional vapor compression chillers is avoided. In many cases it is beneficial for the district heating provider to lower the supply and/or return temperatures in the network, at least for part of the year. In combined heat and power generation (CHP) a lower supply temperature means that the electricity yield increases. In this context, it is important to consider that conventional absorption chillers are designed to run on 120 deg C heat. However,they can work on heat with temperature as low as 80 deg C if a chiller with a large enough generator area is used, although this has a negative impact on the dimensions of other components and leads ta lower coefficient of performance. For these reasons low temperature driven absorption chillers have been developed in recent years. Two concepts (from different manufacturers) are now available on the market. Factors that affect the choice of district heat-integrated cooling processes have been investigated in this study. Key system aspects that embody a holistic view on the production of heating, cooling and power are especially highlighted. Important tasks have been: To quantify the following effects on the design of an integrated cooling process: the temperatures in the district heating net, available cooling water temperature (to cool the absorber and condenser), electricity price, and the composition of the energy system (e.g. fuel and CHP or power-only mode of operation). To analyze the potential of the low temperature driven chiller concept with regards to energy and cost

  14. The analysis of the process in the cooling tower with the low efficiency

    Science.gov (United States)

    Badriev, A. I.; Sharifullin, V. N.

    2017-11-01

    We put quite a difficult task maintaining a temperature drop to 11-12 degrees at thermal power plants to ensure the required depth of cooling of vacuum in the condenser, cooling towers. This requirement is achieved with the reducing of the hydraulic load with the low efficiency of the apparatus. The task analysis process in this unit and identify the causes of his poor performance was put in the work. One of the possible reasons may be the heterogeneity of the process in the volume of the apparatus. Therefore, it was decided to investigate experimentally the distribution of the irrigation water and the air flow in the cross section of industrial cooling towers. As a result, we found a significant uneven distribution of flows of water and air in the volume of the apparatus. We have shown theoretically that the uneven distribution of irrigation leads to a significant decrease in the efficiency of evaporation in the cooling tower. The velocity distribution of the air as the tower sections, and inside sections are interesting. The obtained experimental data allowed to establish the internal communication: the effects of the distributions of the density of irrigation in sections of the apparatus for the distribution of changes of the temperature and the air velocity. The obtained results allowed to formulate a methodology for determining process problems and to develop actions on increase of the efficiency of the cooling tower.

  15. Pressure Effects on Solid State Phase Transformation of Aluminium Bronze in Cooling Process

    International Nuclear Information System (INIS)

    Hai-Yan, Wang; Jian-Hua, Liu; Gui-Rong, Peng; Yan, Chen; Yu-Wen, Liu; Fei, Li; Wen-Kui, Wang

    2009-01-01

    Effects of high pressure (6 GPa) on the solid state phase transformation kinetic parameters of aluminum bronze during the cooling process are investigated, based on the measurement and calculation of its solid state phase transformation temperature, duration and activation energy and the observation of its microstructures. The results show that high pressure treatment can reduce the solid phase transformation temperature and activation energy in the cooling process and can shorten the phase transformation duration, which is favorable when forming fine-grained aluminum bronze

  16. Crystallization process and magnetic properties of amorphous iron oxide nanoparticles

    International Nuclear Information System (INIS)

    Phu, N D; Luong, N H; Chau, N; Hai, N H; Ngo, D T; Hoang, L H

    2011-01-01

    This paper studied the crystallization process, phase transition and magnetic properties of amorphous iron oxide nanoparticles prepared by the microwave heating technique. Thermal analysis and magnetodynamics studies revealed many interesting aspects of the amorphous iron oxide nanoparticles. The as-prepared sample was amorphous. Crystallization of the maghemite γ-Fe 2 O 3 (with an activation energy of 0.71 eV) and the hematite α-Fe 2 O 3 (with an activation energy of 0.97 eV) phase occurred at around 300 deg. C and 350 deg. C, respectively. A transition from the maghemite to the hematite occurred at 500 deg. C with an activation energy of 1.32 eV. A study of the temperature dependence of magnetization supported the crystallization and the phase transformation. Raman shift at 660 cm -1 and absorption band in the infrared spectra at 690 cm -1 showed the presence of disorder in the hematite phase on the nanoscale which is supposed to be the origin of the ferromagnetic behaviour of that antiferromagnetic phase.

  17. Tube failures due to cooling process problem and foreign materials in power plants

    Energy Technology Data Exchange (ETDEWEB)

    Ahmad, J. [Kapar Energy Ventures Sdn Bhd, Jalan Tok Muda, Kapar 42200 (Malaysia); Purbolaksono, J., E-mail: judha@uniten.edu.m [Department of Mechanical Engineering, Universiti Tenaga Nasional, Km 7 Jalan Kajang-Puchong, Kajang 43009, Selangor (Malaysia); Beng, L.C. [Kapar Energy Ventures Sdn Bhd, Jalan Tok Muda, Kapar 42200 (Malaysia)

    2010-07-15

    Cooling process which uses water for heat transfer is an essential factor in coal-fired and nuclear plants. Loss of cooling upset can force the plants to shut down. In particular, this paper reports visual inspections and metallurgical examinations on the failed SA210-A1 right-hand side (RHS) water wall tube of a coal-fired plant. The water wall tube showed the abnormal outer surface colour and has failed with wide-open ductile rupture and thin edges indicating typical signs of short-term overheating. Metallurgical examinations confirmed the failed tube experiencing higher temperature operation. Water flow starvation due to restriction inside the upstream tube is identified as the main root cause of failure. The findings are important to take failure mitigation actions in the future operation. Discussion on the typical problems related to the cooling process in nuclear power plants is also presented.

  18. Medios de enfriamiento para el temple // Means for Cooling During the Hardening Process

    Directory of Open Access Journals (Sweden)

    N. Caballero Stevens

    1999-07-01

    Full Text Available Los factores que rigen el proceso de temple son la temperatura, el tiempo de calentamiento y la velocidad de enfriamiento.Tradicionalmente, la variación de la velocidad de enfriamiento se ha logrado mediante la utilización de diferentes medios como elagua, aceites minerales, aceites orgánicos, metales fundidos y otros.En este trabajo, se presentan las características fundamentales de los medios convencionales y actuales empleados para elenfriamiento durante el temple.Palabras claves: Endurecimiento superficial, temple superficial, medios de enfriamiento._____________________________________________________________________AbstractFactors governing of the hardening process are temperature, heating time and cooling speed. Traditionally, the variation of thecooling time has been achieved by using different means such as water, mineral oils, molten metals, etc.In this work, the fundamental characteristics of the conventional and modern means developed for cooling during the hardeningprocess are presented.Key words: Hardening process, cooling means.

  19. The Merkel coefficient and its dependence on the temperature position of the cooling tower process

    International Nuclear Information System (INIS)

    Klenke, W.

    1977-01-01

    The Merkel coefficient, or evaporation coefficient, is still being used as a characteristic factor for the cooling tower process. Its dependence on the cooling range or on the warm water temperature of the process is often considered a disadvantage of the theory of evaporation cooling. This is also the reason for the suggestion to change the theory in such a way that the Merkel coefficient becomes independent of the temperature. The present investigation, however, leads to the result that the dependence of the Merkel coefficient on the temperature must be considered as a remarkable confirmation for the evidence of the theory of heat and mass transfer, as the experimental statements agree fully with the results of the theoretical considerations. (orig.) [de

  20. Tube failures due to cooling process problem and foreign materials in power plants

    International Nuclear Information System (INIS)

    Ahmad, J.; Purbolaksono, J.; Beng, L.C.

    2010-01-01

    Cooling process which uses water for heat transfer is an essential factor in coal-fired and nuclear plants. Loss of cooling upset can force the plants to shut down. In particular, this paper reports visual inspections and metallurgical examinations on the failed SA210-A1 right-hand side (RHS) water wall tube of a coal-fired plant. The water wall tube showed the abnormal outer surface colour and has failed with wide-open ductile rupture and thin edges indicating typical signs of short-term overheating. Metallurgical examinations confirmed the failed tube experiencing higher temperature operation. Water flow starvation due to restriction inside the upstream tube is identified as the main root cause of failure. The findings are important to take failure mitigation actions in the future operation. Discussion on the typical problems related to the cooling process in nuclear power plants is also presented.

  1. Control of Process Operations and Monitoring of Product Qualities through Generic Model-based Framework in Crystallization Processes

    DEFF Research Database (Denmark)

    Abdul Samad, Noor Asma Fazli Bin

    A generic and systematic model-based framework for the design of a process monitoring and control system to achieve the desired crystal size distribution (CSD) and crystal shape for a wide range of crystallization processes has been developed. This framework combines a generic multi-dimensional m...

  2. Diffraction and signal processing experiments with a liquid crystal microdisplay

    International Nuclear Information System (INIS)

    MartInez, Jose Luis; Moreno, Ignacio; Ahouzi, Esmail

    2006-01-01

    In this work, we show some diffraction experiments performed with a liquid crystal display (LCD) that shows how useful this device can be to teach and experience diffraction optics and signal processing experiments. The LCD acts as a programmable pixelated diffractive mask. The Fourier spectrum of the image displayed in the LCD is visualized through a simple free propagation diffraction experiment. This optical system allows easy testing of different diffractive elements. As a demonstration we include experimental results with well-known diffractive elements like diffraction gratings or Fresnel lenses, and with more complicated elements like computer-generated holograms

  3. Diffraction and signal processing experiments with a liquid crystal microdisplay

    Energy Technology Data Exchange (ETDEWEB)

    MartInez, Jose Luis [Departamento de Ciencia y TecnologIa de Materiales, Universidad Miguel Hernandez de Elche, Alicante (Spain); Moreno, Ignacio [Departamento de Ciencia y TecnologIa de Materiales, Universidad Miguel Hernandez de Elche, Alicante (Spain); Ahouzi, Esmail [Institut National des Postes et Telecomunications (INTP), Madinat Al Irfane, Rabat (Morocco)

    2006-09-01

    In this work, we show some diffraction experiments performed with a liquid crystal display (LCD) that shows how useful this device can be to teach and experience diffraction optics and signal processing experiments. The LCD acts as a programmable pixelated diffractive mask. The Fourier spectrum of the image displayed in the LCD is visualized through a simple free propagation diffraction experiment. This optical system allows easy testing of different diffractive elements. As a demonstration we include experimental results with well-known diffractive elements like diffraction gratings or Fresnel lenses, and with more complicated elements like computer-generated holograms.

  4. Dynamics of liquid nitrogen cooling process of solid surface at wetting contact coefficient

    International Nuclear Information System (INIS)

    Smakulski, P; Pietrowicz, S

    2015-01-01

    Liquid cryogens cooling by direct contact is very often used as a method for decreasing the temperature of electronic devices or equipment i.e. HTS cables. Somehow, cooldown process conducted in that way could not be optimized, because of cryogen pool boiling characteristic and low value of the heat transfer coefficient. One of the possibilities to increase the efficiency of heat transfer, as well as the efficiency of cooling itself, it is to use a spray cooling method. The paper shows dynamics analysis of liquid nitrogen cooling solid surface process. The model of heat transfer for the single droplet of liquid nitrogen, which hits on a flat and smooth surface with respect to the different Weber numbers, is shown. Temperature profiles in calculation domains are presented, as well as the required cooling time. The numerical calculations are performed for different initial and boundary conditions, to study how the wetting contact coefficient is changing, and how it contributed to heat transfer between solid and liquid cryogen. (paper)

  5. Effect of Airflow Velocity on Pre-cooling Process of Pomegranate by Forced Cooling Air under Unsteady State Heat Transfer Condition

    Directory of Open Access Journals (Sweden)

    M. A Behaeen

    2018-03-01

    Full Text Available Introduction Pomegranate (Punica grantum L. is classified into the family of Punicaceae. One of the most influential factors in postharvest life and quality of horticultural products is temperature. In precooling, heat is reduced in fruit and vegetable after harvesting to prepare it quickly for transport and storage. Fikiin (1983, Dennis (1984 and Hass (1976 reported that cold air velocity is one of the effective factors in cooling vegetables and fruits. Determining the time-temperature profiles is an important step in cooling process of agricultural products. The objective of this study was the analysis of cooling rate in the center (arils and outer layer (peel of pomegranate and comparison of the two sections at different cold air velocities. These results are useful for designing and optimizing the precooling systems. Materials and Methods The pomegranate variety was Rabab (thick peel and the experiments were performed on arils (center and peel (outer layer of a pomegranate. The velocities of 0.5, 1 and 1.3 m s-1 were selected for testing. To perform the research, the cooling instrument was designed and built at Department of Biosystems Engineering of Tabriz University, Tabriz, Iran. In each experiment six pt100 temperature sensors was used in a single pomegranate. The cooling of pomegranate was continued until the central temperature reached to 10°C and then the instrument turned off. The average of air and product temperatures was 7.2 and 22.2°C, respectively. The following parameters were measured to analyze the process of precooling: a Dimensionless temperature (θ, b Cooling coefficient (C, c Lag factor (J, d Half-cooling time (H, e Seven-eighths cooling time (S, f Cooling heterogeneity, g Fruit mass loss, h Instantaneous cooling rate, and i convective heat transfer coefficient. Results and Discussion At any air velocity, with increasing the radius from center to outer layer, the lag factor decreased and cooling coefficient increased

  6. Account of External Cooling Medium Temperature while Modeling Thermal Processes in Power Oil-Immersed Transformers

    OpenAIRE

    Yu. A. Rounov; O. G. Shirokov; D. I. Zalizny; D. M. Los

    2004-01-01

    The paper proposes a thermal model of a power oil-immersed transformer as a system of four homogeneous bodies: winding, oil, core and cooling medium. On the basis of experimental data it is shown that such model describes more precisely actual thermal processes taking place in a transformer than the thermal model accepted in GOST 14209-85.

  7. Account of External Cooling Medium Temperature while Modeling Thermal Processes in Power Oil-Immersed Transformers

    Directory of Open Access Journals (Sweden)

    Yu. A. Rounov

    2004-01-01

    Full Text Available The paper proposes a thermal model of a power oil-immersed transformer as a system of four homogeneous bodies: winding, oil, core and cooling medium. On the basis of experimental data it is shown that such model describes more precisely actual thermal processes taking place in a transformer than the thermal model accepted in GOST 14209-85.

  8. Enhancement of Cognitive Processing by Multiple Sclerosis Patients Using Liquid Cooling Technology: A Case Study

    Science.gov (United States)

    Montgomery, Leslie D.; Ku, Yu-Tsuan E.; Montgomery, Richard W.; Kliss, Mark (Technical Monitor)

    1997-01-01

    strongly in reduced energy in the occipital region during the initial processing of the precooling period visual stimulus which may indicate impaired early visual processing; and (3) increased postcooling activation in the le ft angular gyrus may result in enhanced higher-level reasoning related to processing visual task information. By this hypothesis the superior performance of Subject Two following body cooling may be a result of increased neural activation in his early visual recognition and processing centers.

  9. Recombining processes in a cooling plasma by mixing of initially heated gas

    International Nuclear Information System (INIS)

    Furukane, Utaro; Sato, Kuninori; Takiyama, Ken; Oda, Toshiatsu.

    1992-03-01

    A numerical investigation of recombining process in a high temperature plasma in a quasi-steady state is made in a gas contact cooling, in which the initial temperature effect of contact gas heated up by the hot plasma is considered as well as the gas cooling due to the surrounding neutral particles freely coming into the plasma. The calculation has shown that the electron temperature relaxes in accord with experimental results and that the occurrence of recombining region and the inverted populations almost agree with the experimental ones. (author)

  10. A task based design procedure and modelling approached for industrial crystallization processes

    NARCIS (Netherlands)

    Menon, A.R.

    2006-01-01

    A synthesis-based approach to the design of crystallizers and industrial crystallization processes is introduced in this thesis. An ontology for a task-based design procedure has been developed which breaks the crystallization process into a subset of basic functions (physical tasks) which transform

  11. The Worlds First Ever Cooling Tower Acceptance Test Using Process Data Reconciliation

    International Nuclear Information System (INIS)

    Magnus Langenstein; Jan Hansen-Schmidt

    2006-01-01

    The cooling capacity of cooling towers is influenced by multiple constructive and atmospheric parameters in a very complex way. This leads to strong variations of the measured cold-water temperature and causes unacceptable unreliability of conventional acceptance tests, which are based on single point measurements. In order to overcome this lack of accuracy a new approach to acceptance test based on process data reconciliation has been developed by BTB Jansky and applied at a nuclear power plant. This approach uses process data reconciliation according to VDI 2048 to evaluate datasets over a long period covering different operating conditions of the cooling tower. Data reconciliation is a statistical method to determine the true process parameters with a statistical probability of 95% by considering closed material-, mass-and energy balances. Datasets which are not suitable for the evaluation due to strong transient gradients are excluded beforehand, according to well-defined criteria. The reconciled cold-water temperature is then compared, within a wet bulb temperature range of 5 deg. C to 20 deg. C to the manufacturer's guaranteed temperature. Finally, if the average deviation between reconciled and guaranteed value over the evaluated period is below zero, the cooling tower guarantee is fulfilled. (authors)

  12. Analysis of mercerization process based on the intensity change of deconvoluted resonances of 13C CP/MAS NMR: Cellulose mercerized under cooling and non-cooling conditions

    International Nuclear Information System (INIS)

    Miura, Kento; Nakano, Takato

    2015-01-01

    The area intensity change of C1, C4, and C6 in spectrum obtained by 13 C CP/MAS NMR and the mutual relationship between their changes were examined for cellulose samples treated with various concentrations of aqueous NaOH solutions under non-cooling and cooling conditions. The area intensity of C1-up and C6-down changed cooperatively with that of C4-down which corresponds to the crystallinity of samples: “-up” and “-down” are the up- and down- field component in a splitting peak of NMR spectrum, respectively. The intensity change of C1-up starts to decrease with decreasing in that of C4-down after that of C6-down is almost complete. These changes were more clearly observed for samples treated under cooling condition. It can be suggested that their characteristic change relates closely to the change in conformation of cellulose chains by induced decrystallization and the subsequent crystallization of cellulose II, and presumed that their changes at microscopic level relate to the macroscopic morphological changes such as contraction along the length of cellulose chains and recovery along the length. - Highlight: • Samples were mercerized at various NaOH concentrations under non-cooling and cooling. • The intensity change of C1 starts immediately after that of C6 is complete. • The creation of cell-II starts when decrystallization proceeds to a certain state. • This change relates closely to the change in conformation of cellulose chains. • The above change is more clearly found for samples treated under cooling

  13. Selected Parameters of Micro-Jet Cooling Gases in Hybrid Spraying Process

    Directory of Open Access Journals (Sweden)

    Szczucka-Lasota B.

    2016-06-01

    Full Text Available The innovative technology, like thermal spraying with a micro-jet cooling is one of the important modification of classical ultrasonic spraying methods. Using of micro-stream with gases like argon or nitrogen allows to cool the coating immediately after spraying, and thereby reduce the time of transition during the injection of each layer. As a result of the process, the fine dispersive structure of coatings is obtained during the shorter time in comparable to the classical high velocity oxygen fuel process (HVOF. The parameter of process and the type of stream equipment determine the quality of the obtained structure and thermal stress in the coating. The article presents the relationship between selected parameters of hybrid process and properties of the coatings. The presented technology should be adapted to the actual production of protective coating for machines and construction working in wear conditions.

  14. Optimization of cryogenic cooled EDM process parameters using grey relational analysis

    International Nuclear Information System (INIS)

    Kumar, S Vinoth; Kumar, M Pradeep

    2014-01-01

    This paper presents an experimental investigation on cryogenic cooling of liquid nitrogen (LN 2 ) copper electrode in the electrical discharge machining (EDM) process. The optimization of the EDM process parameters, such as the electrode environment (conventional electrode and cryogenically cooled electrode in EDM), discharge current, pulse on time, gap voltage on material removal rate, electrode wear, and surface roughness on machining of AlSiCp metal matrix composite using multiple performance characteristics on grey relational analysis was investigated. The L 18 orthogonal array was utilized to examine the process parameters, and the optimal levels of the process parameters were identified through grey relational analysis. Experimental data were analyzed through analysis of variance. Scanning electron microscopy analysis was conducted to study the characteristics of the machined surface.

  15. Influence of the Mould Cooling Process on the Quality and Properties of Aluminium Alloy

    Directory of Open Access Journals (Sweden)

    Viktorie Weiss

    2014-12-01

    Full Text Available The article deals with the effect on the quality of casting moulds (metal, bentonite mixture on the structure of the alloy AlZn5,5MgCu and selected mechanical properties of the alloy. The effect of foundry moulds can significantly affect formation and range of crystal segregation and the subsequent thermal process of homogenization which has an influence on the final quality of the alloy. The research focuses on the formation and range of crystal segregation and its removal with homogenization annealing, in which the observed influence of individual factors influencing the diffusion process and quality of the aluminium alloy.

  16. An intelligent approach for cooling radiator fault diagnosis based on infrared thermal image processing technique

    International Nuclear Information System (INIS)

    Taheri-Garavand, Amin; Ahmadi, Hojjat; Omid, Mahmoud; Mohtasebi, Seyed Saeid; Mollazade, Kaveh; Russell Smith, Alan John; Carlomagno, Giovanni Maria

    2015-01-01

    This research presents a new intelligent fault diagnosis and condition monitoring system for classification of different conditions of cooling radiator using infrared thermal images. The system was adopted to classify six types of cooling radiator faults; radiator tubes blockage, radiator fins blockage, loose connection between fins and tubes, radiator door failure, coolant leakage, and normal conditions. The proposed system consists of several distinct procedures including thermal image acquisition, image pre-processing, image processing, two-dimensional discrete wavelet transform (2D-DWT), feature extraction, feature selection using a genetic algorithm (GA), and finally classification by artificial neural networks (ANNs). The 2D-DWT is implemented to decompose the thermal images. Subsequently, statistical texture features are extracted from the original images and are decomposed into thermal images. The significant selected features are used to enhance the performance of the designed ANN classifier for the 6 types of cooling radiator conditions (output layer) in the next stage. For the tested system, the input layer consisted of 16 neurons based on the feature selection operation. The best performance of ANN was obtained with a 16-6-6 topology. The classification results demonstrated that this system can be employed satisfactorily as an intelligent condition monitoring and fault diagnosis for a class of cooling radiator. - Highlights: • Intelligent fault diagnosis of cooling radiator using thermal image processing. • Thermal image processing in a multiscale representation structure by 2D-DWT. • Selection features based on a hybrid system that uses both GA and ANN. • Application of ANN as classifier. • Classification accuracy of fault detection up to 93.83%

  17. Molecular dynamics study of dynamic and structural properties of supercooled liquid and glassy iron in the rapid-cooling processes

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Qi-Long; Huang, Duo-Hui; Yang, Jun-Sheng; Wan, Min-Jie; Wang, Fan-Hou, E-mail: eatonch@gmail.com

    2014-10-01

    Molecular dynamics simulations were applied to study the dynamic and structural properties of supercooled liquid and glassy iron in the rapid-cooling processes. The mean-square displacement and the non-Gaussian parameter were used to describe the dynamic properties. The evolution of structural properties was investigated using the pair distribution functions and bond-angle distribution functions. Results for dynamic and structural relaxations indicate that the dynamic features are consistently correlated with the structure evolution, and there are three temperature regions as the temperature decreases: (1) at higher temperatures (1500 K, 1300 K, and 1100 K), the system remains in the liquid characteristics during the overall relaxation process. (2) At medial temperatures (1050 K, 900 K, and 700 K), a fast β-relaxation is followed by a much slower α-relaxation. There is a little change in the structural properties in the β-relaxation region, while major configuration rearrangements occurred in the α-relaxation range and the crystallization process was completed at the end of α-relaxation region. (3) At lower temperature (500 K), the system shows glassy characteristics during the overall relaxation process. In addition, the melting temperature, glass transition temperature and diffusion coefficients of supercooled liquid iron are also computed.

  18. Time-resolved photoemission spectroscopy of electronic cooling and localization in CH3NH3PbI3 crystals

    Science.gov (United States)

    Chen, Zhesheng; Lee, Min-i.; Zhang, Zailan; Diab, Hiba; Garrot, Damien; Lédée, Ferdinand; Fertey, Pierre; Papalazarou, Evangelos; Marsi, Marino; Ponseca, Carlito; Deleporte, Emmanuelle; Tejeda, Antonio; Perfetti, Luca

    2017-09-01

    We measure the surface of CH3NH3PbI3 single crystals by making use of two-photon photoemission spectroscopy. Our method monitors the electronic distribution of photoexcited electrons, explicitly discriminating the initial thermalization from slower dynamical processes. The reported results disclose the fast-dissipation channels of hot carriers (0.25 ps), set an upper bound to the surface-induced recombination velocity (PbI3 samples is consistent with the progressive reduction of photoconversion efficiency in operating devices. Minimizing the density of shallow traps and solving the aging problem may boost the macroscopic efficiency of solar cells to the theoretical limit.

  19. Calorimetric analysis of heating and cooling process of nodular cast iron

    Directory of Open Access Journals (Sweden)

    Bińczyk F.

    2007-01-01

    Full Text Available The study presents the results of investigations of the thermal effects which take place during heating and cooling of samples of the nodular graphite cast iron taken from the stepped test casting of the wall thicknesses amounting to 5, 10, 15 and 20 mm. For investigations, a differential scanning calorimeter, type Multi HTC S60, was used. During heating, three endothermic effects related with pearlite decomposition, phase transformation α → γ, and carbon dissolution in austenite were observed on a DSC diagram. During cooling, two exothermic effects related with phase transformation γ→ α and pearlite formation were observed to consecutively take place on a DSC diagram. The values of the enthalpy of these processes differ and depend on the initial microstructure of the examined samples. The metallic matrix in 5 mm sample after the process of heating and cooling changes totally in favour of ferrite. The same effect, though less advanced in intensity, takes place in 10 mm sample, while in 15 and 20 mm samples the matrix constitution remains unchanged. The higher is the content of ferrite in samples, the stronger is the endothermic effect of the α → γ transformation and the weaker is the endothermic effect related with carbon dissolution in austenite. The total of the endothermic effects (heating is reduced, while that of the exothermic effects (cooling increases along with the increasing thickness of walls in a stepped test casting, from which samples for the investigations were taken.

  20. The influence of slow cooling on Y211 size and content in single-grain YBCO bulk superconductor through the infiltration-growth process

    Energy Technology Data Exchange (ETDEWEB)

    Ouerghi, A [Systems and Applied Mechanics Laboratory LASMAP, Polytechnic School of Tunisia, Rue El Kawarezmi La Marsa 743, Université de Carthage Tunis (Tunisia); Moutalbi, N., E-mail: nahed.moutalbi@yahoo.fr [Systems and Applied Mechanics Laboratory LASMAP, Polytechnic School of Tunisia, Rue El Kawarezmi La Marsa 743, Université de Carthage Tunis (Tunisia); Noudem, J.G. [CRISMAT-ENSICAEN (UMR-CNRS 6508), Université de Caen-Basse-Normandie, F-14050 Caen (France); LUSAC, Université de Caen-Basse-Normandie F-50130 Cherbourg-Octeville (France); M' chirgui, A. [Systems and Applied Mechanics Laboratory LASMAP, Polytechnic School of Tunisia, Rue El Kawarezmi La Marsa 743, Université de Carthage Tunis (Tunisia)

    2017-03-15

    Highlights: • YBCO bulk superconductors are produced by optimized Seeded Infiltration and Growth process. • The slow cooling time, in a fixed slow cooling temperature window, affects considerably the surface morphology and the bulk’s microstructure. • The Y211 particle’s size and content depend on the slow cooling time and its distribution behavior changes from one position to another. • There is an optimum slow cooling time, estimated to 88h, over which the shrinkage for both the liquid phase and the Y211 pellet is maximal, without any improvement of the crystal grain growth. • The magnetic trapped flux distribution for a given sample brings out the single grain characteristic. - Abstract: Highly textured YBa{sub 2}Cu{sub 3}O{sub 7-δ} (Y123) superconductors were produced using modified Textured Top Seeded Infiltration Growth (TSIG) process. The liquid source is made of only Y123 powder whereas the solid source is composed of Y{sub 2}BaCuO{sub 5} (Y211) powder. We aim to control the amount of liquid that infiltrates the solid pellet, which in turn controls the final amount of Y{sub 2}BaCuO{sub 5} particles in Y123 matrix. The effect of the slow cooling kinetics on sample morphology, on grain growth and on final microstructure was too investigated. It is shown that appropriate slow cooling time may also contribute to the control of the amount of Y211 inclusions in the final structure of Y123 bulk. We report herein the Y211 particle size and density distribution in the whole Y123 matrix. The present work proves that finest Y211 particles locate under the seed and that their size and density increase with distance from the seed.

  1. Direct transmission electron microscopy observations of martensitic transformations in Ni-rich NiTi single crystals during in situ cooling and straining

    International Nuclear Information System (INIS)

    Kroeger, A.; Dziaszyk, S.; Frenzel, J.; Somsen, Ch.; Dlouhy, A.; Eggeler, G.

    2008-01-01

    We investigate martensitic transformations using transmission electron microscopy (TEM) in compression aged Ni-rich NiTi single crystals with one family of Ni 4 Ti 3 precipitates. Small cylinders from a Ni-rich NiTi single crystal with a Ni content of 51.0 at.% were compression aged at 550 deg. C in the [1 1 1] B2 direction for different aging times. Differential scanning calorimetry (DSC) investigations show that a three-step martensitic transformation (three DSC peaks on cooling from the high temperature regime) can be observed for aging times of 4 ks. In situ cooling TEM investigations reveal that the first peak on cooling is associated with a transformation from B2 to R-phase, starting from all precipitate/matrix interfaces. On further cooling, the B19'-phase appears and grows along precipitate/matrix interfaces (second step). With further decreasing temperature, the remaining R-phase between the precipitates transforms to B19' (third peak). In situ TEM straining experiments of B2 above the martensitic start temperature reveal that first some microstructural regions directly transform in microscopic burst like events from B2 to B19'. On further straining, the B19'-phase grows along precipitate/matrix interfaces. However, no formation of R-phase precedes the formation of stress-induced B19'

  2. Influence of Crucible Thermal Conductivity on Crystal Growth in an Industrial Directional Solidification Process for Silicon Ingots

    Directory of Open Access Journals (Sweden)

    Zaoyang Li

    2016-01-01

    Full Text Available We carried out transient global simulations of heating, melting, growing, annealing, and cooling stages for an industrial directional solidification (DS process for silicon ingots. The crucible thermal conductivity is varied in a reasonable range to investigate its influence on the global heat transfer and silicon crystal growth. It is found that the crucible plays an important role in heat transfer, and therefore its thermal conductivity can influence the crystal growth significantly in the entire DS process. Increasing the crucible thermal conductivity can shorten the time for melting of silicon feedstock and growing of silicon crystal significantly, and therefore large thermal conductivity is helpful in saving both production time and power energy. However, the high temperature gradient in the silicon ingots and the locally concave melt-crystal interface shape for large crucible thermal conductivity indicate that high thermal stress and dislocation propagation are likely to occur during both growing and annealing stages. Based on the numerical simulations, some discussions on designing and choosing the crucible thermal conductivity are presented.

  3. Ethnography of Cool Roof Retrofits: The Role of Rebates in the Materials Selection Process

    Energy Technology Data Exchange (ETDEWEB)

    Mazur-Stommen, Susan [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2011-02-01

    In the summer of 2010, ethnographic research was conducted with nine households in the Bay Area and Sacramento region. The purpose of this task was to collect methodologically grounded insights into how and why consumers chose the cool roofing material they selected. These nine households comprised fifteen respondents, and their dependents. They were selected from among a pool of respondents to a mail solicitation of all Sacramento Municipal Utility District and Pacific Gas and Electric customers who had received a rebate for their cool roof retrofit. Consumers are uniformly happy with their cool roof retrofits. Consumers typically stayed very close to the aesthetic of the original roof style. Price was not a primary concern, while longevity was paramount. Consumers did not use roofing price, nor energy savings (with one exception), in tracking return on investment through energy savings. The utility rebate had little role to play in terms of incentivizing customers to choose cool materials. Contractors were critical partners in the decision-­making process.

  4. The use of quasi-isothermal modulated temperature differential scanning calorimetry for the characterization of slow crystallization processes in lipid-based solid self-emulsifying systems.

    Science.gov (United States)

    Otun, Sarah O; Meehan, Elizabeth; Qi, Sheng; Craig, Duncan Q M

    2015-04-01

    Slow or incomplete crystallization may be a significant manufacturing issue for solid lipid-based dosage forms, yet little information is available on this phenomenon. In this investigation we suggest a novel means by which slow solidification may be monitored in Gelucire 44/14 using quasi-isothermal modulated temperature DSC (QiMTDSC). Conventional linear heating and cooling DSC methods were employed, along with hot stage microscopy (HSM), for basic thermal profiling of Gelucire 44/14. QiMTDSC experiments were performed on cooling from the melt, using a range of incremental decreases in temperature and isothermal measurement periods. DSC and HSM highlighted the main (primary) crystallization transition; solid fat content analysis and kinetic analysis were used to profile the solidification process. The heat capacity profile from QiMTDSC indicated that after an initial energetic primary crystallisation, the lipid underwent a slower period of crystallization which continued to manifest at much lower temperatures than indicated by standard DSC. We present evidence that Gelucire 44/14 undergoes an initial crystallization followed by a secondary, slower process. QIMTDSC appears to be a promising tool in the investigation of this secondary crystallization process.

  5. Modification of the crystal habit of celecoxib for improved processability.

    Science.gov (United States)

    Banga, Sheere; Chawla, Garima; Varandani, Deepak; Mehta, B R; Bansal, Arvind K

    2007-01-01

    Crystallization is often used in the pharmaceutical industry for purification and isolation of drugs, and also as a means of generating polymorphs or isomorphs. The aim of this study was to investigate the role of extrinsic crystallization parameters on the crystallized product, with special emphasis on improving the mechanical properties of acicular celecoxib. Celecoxib isomorphs were prepared using different techniques (solvent crystallization and vapour diffusion) and crystallization conditions (solvents, stirring, degree of supersaturation, crystallization temperature and seeding). Powder X-ray diffractometry, spectroscopic and thermal methods were used to investigate physical characteristics of crystals. Growth kinetics and aggregation dynamics of crystallization in polar and non-polar solvents were simulated using a dynamic light scattering method. The quick appearance of broad peaks over the range of 10-8000 nm in chloroform during crystallization simulation studies indicated faster aggregation in non-polar solvents. Aspect ratio, flow, compressibility and surface area of recrystallized products were also determined. Surface topography was determined by atomic force microscopy and the lath-shaped crystals (aspect ratio of 2-4) exhibited a roughness index of 1.79 in comparison with 2.92 for needles. Overall, the lath-shaped isomorphs exhibited improved flow and better compressibility.

  6. Investigation of thermal and hydrodynamic processes in the oil transformer radiator cooling system

    OpenAIRE

    Ільїн, Сергій Віталійович

    2013-01-01

    Despite the large number of publications in the field of transformer, heat transfer and hydrodynamic processes that take place in the radiator cooling systems, lack of attention. However, for a comprehensive analysis of the entire oil circuit in the transformer, it is necessary to take into account the work of the radiator, as it was on the efficiency of removal of heat in it will depend on the oil temperature at the inlet of the transformer. To achieve these objectives, this paper describes ...

  7. The spatial variation of initial 87Sr/86Sr ratios in the Toki granite, Central Japan. Implications for the intrusion and cooling processes of a granitic pluton

    International Nuclear Information System (INIS)

    Yuguchi, Takashi; Tsuruta, Tadahiko; Hama, Katsuhiro; Nishiyama, Tadao

    2013-01-01

    The spatial variation in initial 87 Sr/ 86 Sr ratios (SrI) in the Toki granite, Central Japan, shows heterogeneity ranging from 0.708942 to 0.710069, which provides information on the intrusion and cooling processes of plutons. The Toki granite has three mineralogy-based rock facies: muscovite-biotite granite (MBG), hornblende-biotite granite (HBG) and biotite granite (BG). Large SrI values were found to be distributed at the western margin (west MBG) and the lithologically central region (central BG), while small SrI values were found at the northeast margin (northeast MBG). Regions with high and low Sr concentrations were also found in the Toki granite. In the Sr-rich samples, SrI (0.708942-0.709789) increases with 100/Sr (0.7-1.5). This geochemical trend extends towards the country sedimentary rocks of the Mino Terrane, which can be interpreted to result from assimilation and fractional crystallization (AFC) between the original granitic magma and the Mino sedimentary rocks. The SrI values in the Sr-rich regions show a correlation with the Alumina Saturation Index (ASI). In particular, the west MBG, with large SrI values, is classified as a peraluminous granitoid with large ASI, suggesting that the western margin of the pluton was strongly affected by assimilation during the intrusion process. The Sr-poor samples are present both in the central BG, with large SrI values, and in the northeast MBG, with small SrI values. The Sr-poor samples have small ASI and large differentiation indices, indicating that the central BG and the northeast MBG were generated either by different AFC process with different amounts of contaminants or by the intrusion and fractionation of different source magma with different SrI values. Overall, the geochemical spatial variations found in the Toki granite can be explained by various degrees of assimilation and fractional crystallization in the magma chamber and/or multi-stage intrusions with different degrees of crystallization of

  8. The contrasting roles of creep and stress relaxation in the time-dependent deformation during in-situ cooling of a nickel-base single crystal superalloy.

    Science.gov (United States)

    Panwisawas, Chinnapat; D'Souza, Neil; Collins, David M; Bhowmik, Ayan

    2017-09-11

    Time dependent plastic deformation in a single crystal nickel-base superalloy during cooling from casting relevant temperatures has been studied using a combination of in-situ neutron diffraction, transmission electron microscopy and modelling. Visco-plastic deformation during cooling was found to be dependent on the stress and constraints imposed to component contraction during cooling, which mechanistically comprises creep and stress relaxation. Creep results in progressive work hardening with dislocations shearing the γ' precipitates, a high dislocation density in the γ channels and near the γ/γ' interface and precipitate shearing. When macroscopic contraction is restricted, relaxation dominates. This leads to work softening from a decreased dislocation density and the presence of long segment stacking faults in γ phase. Changes in lattice strains occur to a similar magnitude in both the γ and γ' phases during stress relaxation, while in creep there is no clear monotonic trend in lattice strain in the γ phase, but only a marginal increase in the γ' precipitates. Using a visco-plastic law derived from in-situ experiments, the experimentally measured and calculated stresses during cooling show a good agreement when creep predominates. However, when stress relaxation dominates accounting for the decrease in dislocation density during cooling is essential.

  9. Thermally driven interaction of the littoral and limnetic zones by autumnal cooling processes

    Directory of Open Access Journals (Sweden)

    Kolumban HUTTER

    2005-02-01

    Full Text Available In autumn, during the transition period, shores influence the interior dynamics of large temperate lakes by the formation of horizontal water-temperature gradients between the shallow and deep areas, whilst vertical temperature gradients are smoothed by convection due to surface cooling. A simple heat budget model, based on the heat balance of the water column without horizontal advection and turbulent mixing, allows deduction of the time-dependent difference between the mean temperature within the littoral area and the temperature in the upper mixed layer. The model corroborates that littoral areas cool faster than regions distant from shores, and provides a basis for an estimation of structure of flows from the beginning of cooling process till the formation of the thermal bar. It predicts the moment in the cooling process, when the corresponding density difference between the littoral and limnetic parts reaches a maximum. For a linear initial vertical temperature profile, the time-dependent "target depth" is explicitly calculated; this is the depth in the pelagic area with a temperature, characteristic of the littoral zone. This depth is estimated as 4/3 of the (concurrent thickness of the upper mixed layer. It is shown that, for a linear initial vertical temperature profile, the horizontal temperature profile between the shore and the lake has a self-similar behavior, and the temperature difference between the littoral waters and the upper mixed off-shore layer, divided by the depth of the upper mixed layer, is an invariant of the studied process. The results are in conformity with field data.

  10. Liquid desiccant dehumidification and regeneration process to meet cooling and freshwater needs of desert greenhouses

    KAUST Repository

    Lefers, Ryan; Bettahalli Narasimha, Murthy Srivatsa; Nunes, Suzana Pereira; Fedoroff, Nina; Davies, Philip A.; Leiknes, TorOve

    2016-01-01

    practice of evaporative cooling for greenhouses consumes large amounts of fresh water. In Saudi Arabia, the most common greenhouse cooling schemes are fresh water-based evaporative cooling, often using fossil groundwater or energy-intensive desalinated

  11. Site-specific investigations of aquifer thermal energy storage for space and process cooling

    International Nuclear Information System (INIS)

    Brown, D.R.

    1991-01-01

    This paper reports on the Pacific Northwest Laboratory (PNL) that has completed three preliminary site-specific feasibility studies that investigated aquifer thermal energy storage (ATES) for reducing space and process cooling costs. Chilled water stored in an ATES system could be used to meet all or part of the process and/or space cooling loads at the three facilities investigated. Seasonal or diurnal chill ATES systems could be significantly less expensive than a conventional electrically-driven, load-following chiller system at one of the three sites, depending on the cooling water loop return temperature and presumed future electricity escalation rate. For the other two sites investigated, a chill ATES system would be economically competitive with conventional chillers if onsite aquifer characteristics were improved. Well flow rates at one of the sites were adequate, but the expected thermal recovery efficiency was too low. The reverse of this situation was found at the other site, where the thermal recovery efficiency was expected to be adequate, but well flow rates were too low

  12. Analysis of counter current flow limitation during the cooling process at the rectangular narrow boundary

    International Nuclear Information System (INIS)

    Nur Rahmad Yusuf

    2013-01-01

    Experimental studies to study the mechanism of boiling heat transfer in narrow rectangular channel under severe accident scenarios of TMI-2 nuclear power plant necessary for the understanding of management-related accidents. The research aims to obtain heat flux values and the critical heat flux (CHF) during the process of boiling heat transfer in narrow rectangular channel. Research methods experimentally using the HEATING-02 test section with cooling fluid is water temperature 98 °C. Experiments performed by varying the hot plate initial temperature of 100 °C, 200 °C and 300 °C with channel size 1 mm. Boiling during the cooling process was recorded by a transient temperature on the hot plate. Temperature data used to calculate the heat flux and wall temperature, the results are represented through the boiling curve. The results show that the higher plate temperature, the narrower width of the curve will be narrower and its mean that the plate surface cooling time will be slower. Results visualization is seen that the CCF occurred at the hot plate initial temperature of 100 °C, 200 °C and 300 °C with channel size 1 mm. (author)

  13. Cooling process of liquid propellant rocket by means of kerosene-alumina nanofluid

    Directory of Open Access Journals (Sweden)

    Mostafa Mahmoodi

    2016-12-01

    Full Text Available Heat transfer augmentation of kerosene-alumina nanofluid is studied for the possible use in the regenerative cooling channel of semi cryogenic engine. The basic partial differential equations are reduced to ordinary differential equations which are solved using differential transformation method. Velocity and temperature profiles as well as the skin friction coefficient and Nusselt number are determined. The influence of pertinent parameters such as nanofluid volume fraction, viscosity parameter and Eckert number on the flow and heat transfer characteristics is discussed. The results indicate that adding alumina into the fuel of liquid rocket engine (kerosene can be considered as the way of enhancing cooling process of chamber and nozzle walls. Nusselt number is an increasing function of viscosity parameter and nanoparticle volume fraction while it is a decreasing function of Eckert number.

  14. Effect of Fe2O3 on the crystallization behavior of glass-ceramics produced from naturally cooled yellow phosphorus furnace slag

    Science.gov (United States)

    Liu, Hong-pan; Huang, Xiao-feng; Ma, Li-ping; Chen, Dan-li; Shang, Zhi-biao; Jiang, Ming

    2017-03-01

    CaO-Al2O3-SiO2 (CAS) glass-ceramics were prepared via a melting method using naturally cooled yellow phosphorus furnace slag as the main raw material. The effects of the addition of Fe2O3 on the crystallization behavior and properties of the prepared glass-ceramics were studied by differential thermal analysis, X-ray diffraction, and scanning electron microscopy. The crystallization activation energy was calculated using the modified Johnson-Mehl-Avrami equation. The results show that the intrinsic nucleating agent in the yellow phosphorus furnace slag could effectively promote the crystallization of CAS. The crystallization activation energy first increased and then decreased with increasing amount of added Fe2O3. At 4wt% of added Fe2O3, the crystallization activation energy reached a maximum of 676.374 kJ·mol-1. The type of the main crystalline phase did not change with the amount of added Fe2O3. The primary and secondary crystalline phases were identified as wollastonite (CaSiO3) and hedenbergite (CaFe(Si2O6)), respectively.

  15. The Relationship between Emotional Intelligence and Cool and Hot Cognitive Processes: A Systematic Review

    Science.gov (United States)

    Gutiérrez-Cobo, María José; Cabello, Rosario; Fernández-Berrocal, Pablo

    2016-01-01

    Although emotion and cognition were considered to be separate aspects of the psyche in the past, researchers today have demonstrated the existence of an interplay between the two processes. Emotional intelligence (EI), or the ability to perceive, use, understand, and regulate emotions, is a relatively young concept that attempts to connect both emotion and cognition. While EI has been demonstrated to be positively related to well-being, mental and physical health, and non-aggressive behaviors, little is known about its underlying cognitive processes. The aim of the present study was to systematically review available evidence about the relationship between EI and cognitive processes as measured through “cool” (i.e., not emotionally laden) and “hot” (i.e., emotionally laden) laboratory tasks. We searched Scopus and Medline to find relevant articles in Spanish and English, and divided the studies following two variables: cognitive processes (hot vs. cool) and EI instruments used (performance-based ability test, self-report ability test, and self-report mixed test). We identified 26 eligible studies. The results provide a fair amount of evidence that performance-based ability EI (but not self-report EI tests) is positively related with efficiency in hot cognitive tasks. EI, however, does not appear to be related with cool cognitive tasks: neither through self-reporting nor through performance-based ability instruments. These findings suggest that performance-based ability EI could improve individuals’ emotional information processing abilities. PMID:27303277

  16. Afterheat usage from cooling facilities in ORC processes; Abwaermenutzung aus Kaelteanlagen in ORC-Prozessen

    Energy Technology Data Exchange (ETDEWEB)

    Theede, Florian; Luke, Andrea [Kassel Univ. (Germany). Technische Themodynamik

    2016-07-01

    In the course of the reduction of climate warming an energy-efficient lay-out of processes is necessary. A possibility for the efficiency increasement is the usage of afterheat currents for instance in ORC processes. Connected with the limitation of refrigerants with high greenhouse potential it comes to the increased application of transcritical cooling facilities with carbon dioxide (CO{sub 2}) as refrigerant. By the high pressures after the compression arise here new afterheat sources on a temperature level of about 100 C. An alternative for the simple back-cooling or the heating support and drinking-water heating represents the current production in an ORC process. Great challenges for the lay-out of such an ORC process are the selection of the working fluid as well as the lay-out of the heat exchangers. Established refrigerants in the low-temperature like R245fa for ORC facilities will be in forseeable future no more available. For the study of the possible replacement by alternative refrigerants a simulation model has been developed. By means of this model different refrigerants are analyzed regarding their performance and simultaneously the effects on process and other components studied. The results show that in the temperature range two hydrofluoroolefines R1233zd[E] and R1234ze[Z] as well as the hadron carbon butane can thermodynamically form an alternative.

  17. SIMULATION TOOL OF VELOCITY AND TEMPERATURE PROFILES IN THE ACCELERATED COOLING PROCESS OF HEAVY PLATES

    Directory of Open Access Journals (Sweden)

    Antônio Adel dos Santos

    2014-10-01

    Full Text Available The aim of this paper was to develop and apply mathematical models for determining the velocity and temperature profiles of heavy plates processed by accelerated cooling at Usiminas’ Plate Mill in Ipatinga. The development was based on the mathematical/numerical representation of physical phenomena occurring in the processing line. Production data from 3334 plates processed in the Plate Mill were used for validating the models. A user-friendly simulation tool was developed within the Visual Basic framework, taking into account all steel grades produced, the configuration parameters of the production line and these models. With the aid of this tool the thermal profile through the plate thickness for any steel grade and dimensions can be generated, which allows the tuning of online process control models. The simulation tool has been very useful for the development of new steel grades, since the process variables can be related to the thermal profile, which affects the mechanical properties of the steels.

  18. Self-reporting inhibitors: single crystallization process to get two optically pure enantiomers.

    Science.gov (United States)

    Wan, Xinhua; Ye, Xichong; Cui, Jiaxi; Li, Bowen; Li, Na; Zhang, Jie

    2018-05-22

    Collection of two optically pure enantiomers in a single crystallization process can significantly increase the chiral separation efficiency but it's hard to realize nowadays. Herein we describe, for the first time, a self-reporting strategy for visualizing the crystallization process by a kind of dyed self-assembled inhibitors made from the copolymers with tri(ethylene glycol)-grafting polymethylsiloxane as main chains and poly(N6-methacryloyl-L-lysine) as side chains. When applied with seeds together for the fractional crystallization of conglomerates, the inhibitors can label the formation of the secondary crystals and guide us to completely separate the crystallization process of two enantiomers with colorless crystals as the first product and red crystals as the secondary product. This method leads to high optical purity of D/L-Asn·H2O (99.9 ee% for D-crystals and 99.5 ee% for L-crystals) in a single crystallization process. Moreover, it requires low feeding amount of additives and shows excellent recyclability. We foresee its great potential in developing novel chiral separation methods that can be used in different scales. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Effect of irreversible processes on the thermodynamic performance of open-cycle desiccant cooling cycles

    International Nuclear Information System (INIS)

    La, Dong; Li, Yong; Dai, Yanjun; Ge, Tianshu; Wang, Ruzhu

    2013-01-01

    Highlights: ► Effects of irreversible processes on the performance of desiccant cooling cycle are identified. ► The exergy destructions involved are classified by the properties of the individual processes. ► Appropriate indexes for thermodynamic evaluation are proposed based on thermodynamic analyses. - Abstract: Thermodynamic analyses of desiccant cooling cycle usually focus on the overall cycle performance in previous study. In this paper, the effects of the individual irreversible processes in each component on thermodynamic performance are analyzed in detail. The objective of this paper is to reveal the elemental features of the individual components, and to show their effects on the thermodynamic performance of the whole cycle in a fundamental way. Appropriate indexes for thermodynamic evaluation are derived based on the first and second law analyses. A generalized model independent of the connection of components is developed. The results indicate that as the effectiveness of the desiccant wheel increases, the cycle performance is increased principally due to the significant reduction in exergy carried out by exhaust air. The corresponding exergy destruction coefficient of the cycle with moderate performance desiccant wheel is decreased greatly to 3.9%, which is more than 50% lower than that of the cycle with low performance desiccant wheel. The effect of the heat source is similar. As the temperature of the heat source increases from 60 °C to 90 °C, the percentage of exergy destruction raised by exhaust air increases sharply from 5.3% to 21.8%. High heat exchanger effectiveness improves the cycle performance mainly by lowering the irreversibility of the heat exchanger, using less regeneration heat and pre-cooling the process air effectively

  20. Direct Urca Processes Involving Proton 1 S 0 Superfluidity in Neutron Star Cooling

    Science.gov (United States)

    Xu, Yan; Yu, Zi; Zhang, Xiao-Jun; Fan, Cun-Bo; Liu, Guang-Zhou; Zhao, En-Guang; Huang, Xiu-Lin; Liu, Cheng-Zhi

    2018-04-01

    A detailed description of the baryon direct Urca processes A: n\\to p+e+{\\bar{ν }}e, B: Λ \\to p+e+{\\bar{ν }}e and C: {\\Xi }-\\to Λ +e+{\\bar{ν }}e related to the neutron star cooling is given in the relativistic mean field approximation. The contributions of the reactions B and C on the neutrino luminosity are calculated by means of the relativistic expressions of the neutrino energy losses. Our results show that the total neutrino luminosities of the reactions A, B and C within the mass range (1.603–2.067) M⊙ ((1.515–1.840) M⊙ for TM1 model) for GM1 model are larger than the corresponding values for neutron star without hyperons. Furthermore, although the neutrino emissivity of the reaction A is suppressed with the appearance of the proton 1 S 0 superfluid, the contribution of the reactions B and C can still quicken a massive neutron star cooling. In particular, the reaction C in PSR J1614-2230 and J0348+0432 is not suppressed by the proton 1 S 0 superfluid due to the higher threshold density of the reaction C, which will further speed up the two pulsars cooling. Supported by the National Natural Science Foundation of China under Grant Nos. 11447165, 11373047, 11404336 and U1731240, Youth Innovation Promotion Association, CAS under Grant No. 2016056, and the Development Project of Science and Technology of Jilin Province under Grant No. 20180520077JH

  1. Fabrication of gas turbine water-cooled composite nozzle and bucket hardware employing plasma spray process

    Science.gov (United States)

    Schilke, Peter W.; Muth, Myron C.; Schilling, William F.; Rairden, III, John R.

    1983-01-01

    In the method for fabrication of water-cooled composite nozzle and bucket hardware for high temperature gas turbines, a high thermal conductivity copper alloy is applied, employing a high velocity/low pressure (HV/LP) plasma arc spraying process, to an assembly comprising a structural framework of copper alloy or a nickel-based super alloy, or combination of the two, and overlying cooling tubes. The copper alloy is plamsa sprayed to a coating thickness sufficient to completely cover the cooling tubes, and to allow for machining back of the copper alloy to create a smooth surface having a thickness of from 0.010 inch (0.254 mm) to 0.150 inch (3.18 mm) or more. The layer of copper applied by the plasma spraying has no continuous porosity, and advantageously may readily be employed to sustain a pressure differential during hot isostatic pressing (HIP) bonding of the overall structure to enhance bonding by solid state diffusion between the component parts of the structure.

  2. Comparison between two rheocasting processes of damper cooling tube method and low superheat casting

    Directory of Open Access Journals (Sweden)

    Zhang Xiaoli

    2014-09-01

    Full Text Available To produce a high quality semisolid slurry that consists of fine primary particles uniformly suspended in the liquid matrix for rheoforming, chemical refining and electromagnetic or mechanical stirring are the two methods commonly used. But these two methods either contaminate the melt or incur high cost. In this study, the damper cooling tube (DCT method was designed to prepare semisolid slurry of A356 aluminum alloy, and was compared with the low superheat casting (LSC method - a conventional process used to produce casting slab with equiaxed dendrite microstructure for thixoforming route. A series of comparative experiments were performed at the pouring temperatures of 650 °C, 638 °C and 622 °C. Metallographic observations of the casting samples were carried out using an optical electron microscope with image analysis software. Results show that the microstructure of semisolid slurry produced by the DCT process consists of spherical primary α-Al grains, while equiaxed grains microstructure is found in the LSC process. The lower the pouring temperature, the smaller the grain size and the rounder the grain morphology in both methods. The copious nucleation, which could be generated in the DCT, owing to the cooling and stirring effect, is the key to producing high quality semisolid slurry. DCT method could produce rounder and smaller α-Al grains, which are suitable for semisolid processing; and the equivalent grain size is no more than 60 μm when the pouring temperature is 622 °C.

  3. Metal Halide Perovskite Single Crystals: From Growth Process to Application

    Directory of Open Access Journals (Sweden)

    Shuigen Li

    2018-05-01

    Full Text Available As a strong competitor in the field of optoelectronic applications, organic-inorganic metal hybrid perovskites have been paid much attention because of their superior characteristics, which include broad absorption from visible to near-infrared region, tunable optical and electronic properties, high charge mobility, long exciton diffusion length and carrier recombination lifetime, etc. It is noted that perovskite single crystals show remarkably low trap-state densities and long carrier diffusion lengths, which are even comparable with the best photovoltaic-quality silicon, and thus are expected to provide better optoelectronic performance. This paper reviews the recent development of crystal growth in single-, mixed-organic-cation and fully inorganic halide perovskite single crystals, in particular the solution approach. Furthermore, the application of metal hybrid perovskite single crystals and future perspectives are also highlighted.

  4. Process for obtaining oxygen doped zinc telluride monocrystals and scintillator crystals obtained by this process

    International Nuclear Information System (INIS)

    Schneider, Maurice; Moreau, Roland; D'Haenen, J.-P.; Merenda, Pierre.

    1976-01-01

    A process is described for obtaining oxygen doped zinc telluride monocrystals, for use as scintillator crystals for ionising radiation detectors. The following operations are carried out in succession: one or several zinc telluride crystals are introduced into a silica ampoule together with a ternary mixture of zinc tellurium and oxygen, as an oxide or hydroxide of these elements; the ampoule is pumped down to a high vacuum and sealed; the sealed ampoule containing the mixture and monocrystals is placed in a kiln and brought to a uniform temperature sufficient to make the mixture three-phased, depending on its composition; the zinc telluride crystalline compound remains solid; the ampoule is then tempered to bring it quickly back to ambient temperature [fr

  5. crystal

    Science.gov (United States)

    Yu, Yi; Huang, Yisheng; Zhang, Lizhen; Lin, Zhoubin; Sun, Shijia; Wang, Guofu

    2014-07-01

    A Nd3+:Na2La4(WO4)7 crystal with dimensions of ϕ 17 × 30 mm3 was grown by the Czochralski method. The thermal expansion coefficients of Nd3+:Na2La4(WO4)7 crystal are 1.32 × 10-5 K-1 along c-axis and 1.23 × 10-5 K-1 along a-axis, respectively. The spectroscopic characteristics of Nd3+:Na2La4(WO4)7 crystal were investigated. The Judd-Ofelt theory was applied to calculate the spectral parameters. The absorption cross sections at 805 nm are 2.17 × 10-20 cm2 with a full width at half maximum (FWHM) of 15 nm for π-polarization, and 2.29 × 10-20 cm2 with a FWHM of 14 nm for σ-polarization. The emission cross sections are 3.19 × 10-20 cm2 for σ-polarization and 2.67 × 10-20 cm2 for π-polarization at 1,064 nm. The fluorescence quantum efficiency is 67 %. The quasi-cw laser of Nd3+:Na2La4(WO4)7 crystal was performed. The maximum output power is 80 mW. The slope efficiency is 7.12 %. The results suggest Nd3+:Na2La4(WO4)7 crystal as a promising laser crystal fit for laser diode pumping.

  6. Influence of additive L-phenylalanine on stabilization of metastable α-form of L-glutamic acid in cooling crystallization

    Science.gov (United States)

    Quang, Khuu Chau; Nhan, Le Thi Hong; Huyen, Trinh Thi Thanh; Tuan, Nguyen Anh

    2017-09-01

    The influence of additive amino acid L-phenylalanine on stabilization of metastable α-form of L-glutamic acid was investigated in cooling crystallization. The present study found that the additive L-phenylalanine could be used to stabilize the pure metastable α-form in L-glutamic acid crystallization, where the additive concentration of 0.05-0.1 (g/L) was sufficient to stabilize the 100% wt metastable α-form in solid product at L-glutamic acid concentration of 30-45 (g/L). Additionally, the present results indicated that the adsorption of additive L-phenylalanine on the (001) surface of α-form was more favorable than that of the β-form molecular, so the nucleation sites of stable β-form was occupied by additive molecular, which resulted in inhibition of nucleation and growth of β-form, allowing stabilization of metastable α-form.

  7. Assessment of the dry process fuel sodium-cooled fast reactors

    Energy Technology Data Exchange (ETDEWEB)

    Roh, Gyu Hong; Choi, Hang Bok

    2004-04-01

    The feasibility of using dry-processed oxide fuel in a Sodium-cooled Fast Reactor (SFR) was analyzed for the equilibrium fuel cycle of two reference cores: Hybrid BN-600 benchmark core with a enlarged lattice pitch and modified BN-600 core. The dry process technology assumed in this study based on the molten-salt process, which was developed by Russian scientists for recycling oxide fuels. The core calculation was performed by the REBUS-3 code and the reactor characteristics such as the transuranic enrichment, breeding ratio, peak linear power, burnup reactivity swing, etc. were calculated for the equilibrium core under a fixed fuel management scheme. The results showed that a self-sustainable breakeven core was achievable without blanket fuels when the fuel volume fraction was {approx}50% and most of the fission products were removed.

  8. Assessment of the dry process fuel sodium-cooled fast reactors

    International Nuclear Information System (INIS)

    Roh, Gyu Hong; Choi, Hang Bok

    2004-04-01

    The feasibility of using dry-processed oxide fuel in a Sodium-cooled Fast Reactor (SFR) was analyzed for the equilibrium fuel cycle of two reference cores: Hybrid BN-600 benchmark core with a enlarged lattice pitch and modified BN-600 core. The dry process technology assumed in this study based on the molten-salt process, which was developed by Russian scientists for recycling oxide fuels. The core calculation was performed by the REBUS-3 code and the reactor characteristics such as the transuranic enrichment, breeding ratio, peak linear power, burnup reactivity swing, etc. were calculated for the equilibrium core under a fixed fuel management scheme. The results showed that a self-sustainable breakeven core was achievable without blanket fuels when the fuel volume fraction was ∼50% and most of the fission products were removed

  9. Twinning processes in Cu-Al-Ni martensite single crystals investigated by neutron single crystal diffraction method

    International Nuclear Information System (INIS)

    Molnar, P.; Sittner, P.; Novak, V.; Lukas, P.

    2008-01-01

    A neutron single crystal diffraction method for inspecting the quality of martensite single crystals is introduced. True interface-free martensite single crystals are indispensable for, e.g. measurement of elastic constants of phases by ultrasonic techniques. The neutron diffraction method was used to detect and distinguish the presence of individual lattice correspondence variants of the 2H orthorhombic martensite phase in Cu-Al-Ni as well as to follow the activity of twinning processes during the deformation test on the martensite variant single crystals. When preparing the martensite single variant prism-shaped crystals by compression deformation method, typically a small fraction of second unwanted martensitic variant (compound twin) remains in the prism samples. Due to the very low stress (∼1 MPa) for the compound twinning in many shape memory alloys, it is quite difficult not only to deplete the martensite prisms of all internal interfaces but mainly to keep them in the martensite single variant state for a long time needed for further investigations

  10. Reliability analysis of nuclear component cooling water system using semi-Markov process model

    International Nuclear Information System (INIS)

    Veeramany, Arun; Pandey, Mahesh D.

    2011-01-01

    Research highlights: → Semi-Markov process (SMP) model is used to evaluate system failure probability of the nuclear component cooling water (NCCW) system. → SMP is used because it can solve reliability block diagram with a mixture of redundant repairable and non-repairable components. → The primary objective is to demonstrate that SMP can consider Weibull failure time distribution for components while a Markov model cannot → Result: the variability in component failure time is directly proportional to the NCCW system failure probability. → The result can be utilized as an initiating event probability in probabilistic safety assessment projects. - Abstract: A reliability analysis of nuclear component cooling water (NCCW) system is carried out. Semi-Markov process model is used in the analysis because it has potential to solve a reliability block diagram with a mixture of repairable and non-repairable components. With Markov models it is only possible to assume an exponential profile for component failure times. An advantage of the proposed model is the ability to assume Weibull distribution for the failure time of components. In an attempt to reduce the number of states in the model, it is shown that usage of poly-Weibull distribution arises. The objective of the paper is to determine system failure probability under these assumptions. Monte Carlo simulation is used to validate the model result. This result can be utilized as an initiating event probability in probabilistic safety assessment projects.

  11. Heat Transfer Modeling of an Annular On-Line Spray Water Cooling Process for Electric-Resistance-Welded Steel Pipe.

    Science.gov (United States)

    Chen, Zejun; Han, Huiquan; Ren, Wei; Huang, Guangjie

    2015-01-01

    On-line spray water cooling (OSWC) of electric-resistance-welded (ERW) steel pipes can replace the conventional off-line heat treatment process and become an important and critical procedure. The OSWC process improves production efficiency, decreases costs, and enhances the mechanical properties of ERW steel pipe, especially the impact properties of the weld joint. In this paper, an annular OSWC process is investigated based on an experimental simulation platform that can obtain precise real-time measurements of the temperature of the pipe, the water pressure and flux, etc. The effects of the modes of annular spray water cooling and related cooling parameters on the mechanical properties of the pipe are investigated. The temperature evolutions of the inner and outer walls of the pipe are measured during the spray water cooling process, and the uniformity of mechanical properties along the circumferential and longitudinal directions is investigated. A heat transfer coefficient model of spray water cooling is developed based on measured temperature data in conjunction with simulation using the finite element method. Industrial tests prove the validity of the heat transfer model of a steel pipe undergoing spray water cooling. The research results can provide a basis for the industrial application of the OSWC process in the production of ERW steel pipes.

  12. Heat Transfer Modeling of an Annular On-Line Spray Water Cooling Process for Electric-Resistance-Welded Steel Pipe

    Science.gov (United States)

    Chen, Zejun; Han, Huiquan; Ren, Wei; Huang, Guangjie

    2015-01-01

    On-line spray water cooling (OSWC) of electric-resistance-welded (ERW) steel pipes can replace the conventional off-line heat treatment process and become an important and critical procedure. The OSWC process improves production efficiency, decreases costs, and enhances the mechanical properties of ERW steel pipe, especially the impact properties of the weld joint. In this paper, an annular OSWC process is investigated based on an experimental simulation platform that can obtain precise real-time measurements of the temperature of the pipe, the water pressure and flux, etc. The effects of the modes of annular spray water cooling and related cooling parameters on the mechanical properties of the pipe are investigated. The temperature evolutions of the inner and outer walls of the pipe are measured during the spray water cooling process, and the uniformity of mechanical properties along the circumferential and longitudinal directions is investigated. A heat transfer coefficient model of spray water cooling is developed based on measured temperature data in conjunction with simulation using the finite element method. Industrial tests prove the validity of the heat transfer model of a steel pipe undergoing spray water cooling. The research results can provide a basis for the industrial application of the OSWC process in the production of ERW steel pipes. PMID:26201073

  13. Continuous vacuum processing system for quartz crystal resonators

    International Nuclear Information System (INIS)

    Ney, R.J.; Hafner, E.

    1979-01-01

    An ultrahigh vacuum continuous cycle quartz crystal fabrication facility has been developed that assures an essentially contamination-free environment throughout the final manufacturing steps of the crystal unit. The system consists of five essentially tubular vacuum chambers that are interconnected through gate valves. The unplated crystal resonators, mounted in ceramic flatback frames and loaded on carrier trays, enter the vacuum system through an entrance air lock, are UV/ozone cleaned, baked at 300 0 C, plated to frequency, thermocompression sealed, and exit as completed crystal units through an exit air lock, while the bake, plate and seal chambers remain under continuous vacuum permanently. In-line conveyor belts are used, in conjunction with balanced vacuum manipulators, to move the resonator components to the various work stations. Unique high density, highly directional nozzle beam evaporation sources, capable of long term operation without reloading, are used for electroding the resonators simultaneously on both sides. The design goal for the system is a production rate of 200 units per 8 hour day; it is adaptable to automatic operation

  14. Potential applications of helium-cooled high-temperature reactors to process heat use

    International Nuclear Information System (INIS)

    Gambill, W.R.; Kasten, P.R.

    1981-01-01

    High-Temperature Gas-Cooled Reactors (HTRs) permit nuclear energy to be applied to a number of processes presently utilizing fossil fuels. Promising applications of HTRs involve cogeneration, thermal energy transport using molten salt systems, steam reforming of methane for production of chemicals, coal and oil shale liquefaction or gasification, and - in the longer term - energy transport using a chemical heat pipe. Further, HTRs might be used in the more distant future as the energy source for thermochemical hydrogen production from water. Preliminary results of ongoing studies indicate that the potential market for Process Heat HTRs by the year 2020 is about 150 to 250 GW(t) for process heat/cogeneration application, plus approximately 150 to 300 GW(t) for application to fossil conversion processes. HTR cogeneration plants appear attractive in the near term for new industrial plants using large amounts of process heat, possibly for present industrial plants in conjunction with molten-salt energy distribution systems, and also for some fossil conversion processes. HTR reformer systems will take longer to develop, but are applicable to chemicals production, a larger number of fossil conversion processes, and to chemical heat pipes

  15. Quantum simulation and quantum information processing with molecular dipolar crystals

    International Nuclear Information System (INIS)

    Ortner, M.

    2011-01-01

    In this thesis interactions between dipolar crystals and neutral atoms or separated molecules have been investigated. They were motivated to realize new kinds of lattice models in mixtures of atoms and polar molecules where an MDC functions as an underlying periodic lattice structure for the second species. Such models bring out the peculiar features of MDC's, that include a controllable, potentially sub-optical wavelength periodicity and strong particle phonon interactions. Only stable collisional configurations have been investigated, excluding chemical reactions between the substituents, and crystal distortions beyond the scope of perturbation theory. The system was treated in the polaron picture where particles of the second species are dressed by surrounding crystal phonons. To describe the competition between coherent and incoherent dynamics of the polarons, a master equation in the Brownian motion limit was used with phonons treated as a thermal heat bath. It was shown analytically that in a wide range of realistic parameters the corrections to the coherent time evolution are small, and that the dynamics of the dressed particles can be described by an effective extended Hubbard model with controllable system parameters. The last chapter of this thesis contains a proposal for QIP with cold polar molecules that, in contrast to previous works, uses an MDC as a quantum register. It was motivated by the unique features of dipolar molecules and to exploit the peculiar physical conditions in dipolar crystals. In this proposal the molecular dipole moments were tailored by non-local fields to include a small, switchable, state-dependent dipole moment in addition to the large internal state independent moment that stabilizes the crystal. It was shown analytically that a controllable, non-trivial phonon-mediated interaction can be generated that exceeds non-trivial, direct dipole-dipole couplings. The addressability problem due to high crystal densities was overcome by

  16. Crystallization processes in an amorphous Co-Fe-Cr-Si-B alloy under isothermal annealing

    Science.gov (United States)

    Fedorets, A. N.; Pustovalov, E. V.; Plotnikov, V. S.; Modin, E. B.; Kraynova, G. S.; Frolov, A. M.; Tkachev, V. V.; Tsesarskaya, A. K.

    2017-09-01

    Research present the crystallization processes investigation of the amorphous Co67Fe3Cr3Si15B12 alloy. In-situ experiments on heating in a transmission electron microscope (TEM) column were carried out. Critical temperatures influencing material structure are determined. The onset temperature of material crystallization was determined.

  17. An evaluation of reactor cooling and coupled hydrogen production processes using the modular helium reactor

    International Nuclear Information System (INIS)

    Harvego, E.A.; Reza, S.M.M.; Richards, M.; Shenoy, A.

    2006-01-01

    The high-temperature characteristics of the modular helium reactor (MHR) make it a strong candidate for producing hydrogen using either thermochemical or high-temperature electrolysis (HTE) processes. Using heat from the MHR to drive a sulfur-iodine (SI) thermochemical hydrogen production process has been the subject of a U.S. Department of Energy sponsored Nuclear Engineering Research Initiative (NERI) project led by General Atomics, with participation from the Idaho National Laboratory (INL) and Texas A and M University. While the focus of much of the initial work was on the SI thermochemical production of hydrogen, recent activities included development of a preconceptual design for an integral HTE hydrogen production plant driven by the process heat and electricity produced by a 600 MW MHR. This paper describes ATHENA analyses performed to evaluate alternative primary system cooling configurations for the MHR to minimize peak reactor vessel and core temperatures while achieving core helium outlet temperatures in the range of 900-1000 deg. C that are needed for the efficient production of hydrogen using either the SI or HTE process. The cooling schemes investigated are intended to ensure peak fuel temperatures do not exceed specified limits under normal or transient upset conditions, and that reactor vessel temperatures do not exceed American Society of Mechanical Engineers (ASME) code limits for steady-state or transient conditions using standard light water reactor vessel materials. Preconceptual designs for SI and HTE hydrogen production plants driven by one or more 600 MW MHRs at helium outlet temperatures in the range of 900-1000 deg. C are described and compared. An initial SAPHIRE model to evaluate the reliability, maintainability, and availability of the SI hydrogen production plant is also described. Finally, a preliminary flowsheet for a conceptual design of an HTE hydrogen production plant coupled to a 600 MW modular helium reactor is presented and

  18. Crystallization processes in Ni-Ti-B glassy alloys of near-ternary-eutectic composition

    International Nuclear Information System (INIS)

    Merk, N.; Morris, D.G.; Stadelmann, P.

    1987-01-01

    The crystallization kinetics and mechanisms of three Ni-Ti-B glasses have been examined with a view to elucidating the roles of chemical composition and quenched structure on behaviour. Alloys of composition near a ternary-eutectic point have been chosen because they represent a real and complex situation where several crystalline phases may form simultaneously. Crystallization processes are analysed in terms of nucleation and growth stages. Different nucleation mechanisms seem to be best explained in terms of the short range ordered structure of the quenched glass. Analysis of crystal glass interface energies indicates that it is not this energy term which controls the nucleation of crystals on annealing. Crystal growth may involve a eutectic mechanism or a single-phase mechanism controlled by interface or matrix-diffusion kinetics. Crystallization is fastest when eutectic nucleation and growth occurs. Formation of the eutectic colony requires the initial formation of the phase of complex structure followed by the phase of simpler structure

  19. Crystal-Tolerant Glass Approach For Mitigation Of Crystal Accumulation In Continuous Melters Processing Radioactive Waste

    International Nuclear Information System (INIS)

    Kruger, Albert A.; Rodriguez, Carmen P.; Lang, Jesse B.; Huckleberry, Adam R.; Matyas, Josef; Owen, Antoinette T.

    2012-01-01

    High-level radioactive waste melters are projected to operate in an inefficient manner as they are subjected to artificial constraints, such as minimum liquidus temperature (T L ) or maximum equilibrium fraction of crystallinity at a given temperature. These constraints substantially limit waste loading, but were imposed to prevent clogging of the melter with spinel crystals [(Fe, Ni, Mn, Zn)(Fe, Cr) 2 O 4 ]. In the melter, the glass discharge riser is the most likely location for crystal accumulation during idling because of low glass temperatures, stagnant melts, and small diameter. To address this problem, a series of lab-scale crucible tests were performed with specially formulated glasses to simulate accumulation of spinel in the riser. Thicknesses of accumulated layers were incorporated into empirical model of spinel settling. In addition, T L of glasses was measured and impact of particle agglomeration on accumulation rate was evaluated. Empirical model predicted well the accumulation of single crystals and/or smallscale agglomerates, but, excessive agglomeration observed in high-Ni-Fe glass resulted in an under-prediction of accumulated layers, which gradually worsen over time as an increased number of agglomerates formed. Accumulation rate of ∼14.9 +- 1 nm/s determined for this glass will result in ∼26 mm thick layer in 20 days of melter idling

  20. Renewable Heating And Cooling

    Science.gov (United States)

    Renewable heating and cooling is a set of alternative resources and technologies that can be used in place of conventional heating and cooling technologies for common applications such as water heating, space heating, space cooling and process heat.

  1. Electrochemical filtration for turbidity removal in industrial cooling/process water systems

    International Nuclear Information System (INIS)

    Kumbhar, A.G.; Venkateswaran, G.

    2008-01-01

    Water samples of large cooling water reservoirs may look visibly clear and transparent, but still may contain sub-micron size particles at sub-parts-per-million levels. Deposition of these particles on heat exchanger surfaces, reduces the heat transfer efficiency in power industry. In nuclear power plants, additionally it creates radiation exposure problems due to activation of fine metallic turbidity in the reactor core and its subsequent transfer to out-of-core surfaces. Sub-micron filtration creates back high-pressure problem. Zeta filters available commercially are prescribed for separating either positively or negatively charged particles. They are of once-use and throw-type. Precipitation surface modified ion exchangers impart chemical impurities to the system. Thus, sub-micron size and dilute turbidity removal from large volumes of waters such as heat exchanger cooling water in nuclear and power industry poses a problem. Electro deposition of the turbidity causing particles, on porous carbon/graphite felt electrodes, is one of the best suited methods for turbidity removal from large volumes of water due to the filter's high permeability, inertness to the system and regenerability resulting in low waste generation. Initially, active indium turbidity removal from RAPS-1 heavy water moderator system, and microbes removal from heat exchanger cooling lake water of RAPS 1 and 2 were demonstrated with in-house designed and fabricated prototype electrochemical filter (ECF). Subsequently, a larger size, high flow filter was fabricated and deployed for iron turbidity removal from active process waters system of Kaiga Generation Station unit 1 and silica and iron turbidity removal from cooling water pond used for heat exchanger of a high temperature high pressure (HTHP) loop at WSCD, Kalpakkam. The ECF proved its exclusive utility for sub-micron size turbidity removal and microbes removal. ECF maneuverability with potential and current for both positively and

  2. Processing of radioactive waste solutions in a vacuum evaporator-crystallizer

    International Nuclear Information System (INIS)

    Petrie, J.C.; Donovan, R.I.; Van der Cook, R.E.; Christensen, W.R.

    1975-01-01

    Results of the first 18 months' operation of Hanford's vacuum evaporator-crystallizer are reported. This process reduces the volume of radioactive waste solutions and simultaneously converts the waste to a less mobile salt cake. The evaporator-crystallizer is operating at better than design production rates and has reduced the volume of radioactive wastes by more than 15 million gallons. A process description, plant performance data, mechanical difficulties, and future operating plans are discussed. Also discussed is a computer model of the evaporator-crystallizer process

  3. Characteristics of bulk liquid undercooling and crystallization ...

    Indian Academy of Sciences (India)

    Characteristics of bulk liquid undercooling and crystallization behaviors ... cooling rate is fixed, the change of undercooling depends on the melt processing tem- ... solidification and a deep knowledge of undercooling of ... evolution, to obtain the information for the nucleation and ..... When cooling rate is fixed, the change.

  4. Thermohydraulic modeling of the dry air passive containment cooling system process in the Westinghouse AP-600 ALWR

    Energy Technology Data Exchange (ETDEWEB)

    Harari, R; Weis, Y; Barnea, Y [Israel Atomic Energy Commission, Beersheba (Israel). Nuclear Research Center-Negev

    1996-12-01

    Following postulated events of a LOCA, the passive Containment Cooling System (PCCS) uses dry air to transfer the residual heat by natural circulation. The air flow path, designed between the steel reactor containment hot shell and the concrete shield building, creates an open thermosyphon. The purpose of this inherently safe process is to assure the long term steady-state cooling of the nuclear core after an emergency shutdown (authors).

  5. About the influence of lubricating-cooling agents on the cutting process

    Directory of Open Access Journals (Sweden)

    O.I. Sochko

    2017-12-01

    Full Text Available Set forth problem of necessity of increase of workability of metal. On the basis of generalization of researches at the area of physics – chemical mechanics of materials the offered hypothesis on the permanent activating of lubricating cooling technological facilities in the zone of cutting to hydrogen plasma, mechanism of her influence on the processes of deformation and destruction, and also reasonable new ways of formation of form of wares. It is in-process shown that lubricating – cooling technological facilities in it in the zone of destruction to the new phase state – hydrogen plasma. It is therefore consisted majority mainly of two elements – hydrogen and carbon, the basic changes of mechanical properties of solid are activated in the conditions of co-operating of body with an environment, it follows to link, with influence of nascent radically-active environment, but not from initial superficially – active. An ambiguousness in the estimation of reasons, at that arises up facilitation of processes of deformation and destructions of solids, that become deformed in different environments caused raising of system researches that is sanctified to this problem. As a result of chemical transformations of initial environment to the level of origin electric of active parts of hydrogen, possibility of their co-operating appears with ions and lone electrons of metal, that increases the electric field, to existing in the system «machine-tool – instrument – purveyance». Exactly co-operation electric of active structure of metal that arises up as a result of mechanical action, with the electric charged mixture of parts of hydrogen, id est an electron-electron, electron-ion and ion-ion, is able co-operation radically to change physical and mechanical properties of metal.

  6. Image processing of small protein-crystals in electron microscopy

    International Nuclear Information System (INIS)

    Feinberg, D.A.

    1978-11-01

    This electron microscope study was undertaken to determine whether high resolution reconstructed images could be obtained from statistically noisy micrographs by the super-position of several small areas of images of well-ordered crystals of biological macromolecules. Methods of rotational and translational alignment which use Fourier space data were demonstrated to be superior to methods which use Real space image data. After alignment, the addition of the diffraction patterns of four small areas did not produce higher resolution because of unexpected image distortion effects. A method was developed to determine the location of the distortion origin and the coefficients of spiral distortion and pincushion/barrel distortion in order to make future correction of distortions in electron microscope images of large area crystals

  7. Figuring process of potassium dihydrogen phosphate crystal using ion beam figuring technology.

    Science.gov (United States)

    Li, Furen; Xie, Xuhui; Tie, Guipeng; Hu, Hao; Zhou, Lin

    2017-09-01

    Currently, ion beam figuring (IBF) technology has presented many excellent performances in figuring potassium dihydrogen phosphate (KDP) crystals, such as it is a noncontact figuring process and it does not require polishing fluid. So, it is a very clean figuring process and does not introduce any impurities. However, the ion beam energy deposited on KDP crystal will heat the KDP crystal and may generate cracks on it. So, it is difficult directly using IBF technology to figure KDP crystal, as oblique incident IBF (OI-IBF) has lower heat deposition, higher removal rate, and smoother surface roughness compared to normal incident IBF. This paper studied the process of using OI-IBF to figure KDP crystal. Removal rates and removal functions at different incident angles were first investigated. Then heat depositions on a test work piece were obtained through experiments. To validate the figuring process, a KDP crystal with a size of 200  mm×200  mm×12  mm was figured by OI-IBF. After three iterations using the OI-IBF process, the surface error decreases from the initial values with PV 1.986λ RMS 0.438λ to PV 0.215λ RMS 0.035λ. Experimental results indicate that OI-IBF is feasible and effective to figure KDP crystals.

  8. More accurate determination of the quantity of ice crystallized at low cooling rates in the glycerol and 1,2-propanediol aqueous solutions: comparison with equilibrium.

    Science.gov (United States)

    Boutron, P

    1984-04-01

    It is generally assumed that when cells are cooled at rates close to those corresponding to the maximum of survival, once supercooling has ceased, above the eutectic melting temperature the extracellular ice is in equilibrium with the residual solution. This did not seem evident to us due to the difficulty of ice crystallization in cryoprotective solutions. The maximum quantities of ice crystallized in glycerol and 1,2-propanediol solutions have been calculated from the area of the solidification and fusion peaks obtained with a Perkin-Elmer DSC-2 differential scanning calorimeter. The accuracy has been improved by several corrections: better defined baseline, thermal variation of the heat of fusion of the ice, heat of solution of the water from its melting with the residual solution. More ice crystallizes in the glycerol than in the 1,2-propanediol solutions, of which the amorphous residue contains about 40 to 55% 1,2-propanediol. The equilibrium values are unknown in the presence of 1,2-propanediol. With glycerol, in our experiments, the maximum is first lower than the equilibrium but approaches it as the concentration increases. It is not completely determined by the colligative properties of the solutes.

  9. Cooling treatment of olive paste during the oil processing: Impact on the yield and extra virgin olive oil quality.

    Science.gov (United States)

    Veneziani, G; Esposto, S; Taticchi, A; Urbani, S; Selvaggini, R; Di Maio, I; Sordini, B; Servili, M

    2017-04-15

    In recent years, the temperature of processed olives in many olive-growing areas was often close to 30°C, due to the global warming and an early harvesting period. Consequently, the new trends in the extraction process have to include the opportunity to cool the olives or olive paste before processing to obtain high quality EVOO. A tubular thermal exchanger was used for a rapid cooling treatment (CT) of olive paste after crushing. The results did not show a significant difference in the oil yield or any modifications in the legal parameters. The cooling process determined a significant improvement of phenolic compounds in all the three Italian cultivar EVOOs analyzed, whereas the volatile compounds showed a variability largely affected by the genetic origin of the olives with C 6 aldehydes that seem to be more stable than C 6 alcohols and esters. Copyright © 2016 Elsevier Ltd. All rights reserved.

  10. Development of an innovative polygeneration process in hybrid solar-biomass system for combined power, cooling and desalination

    International Nuclear Information System (INIS)

    Sahoo, U.; Kumar, R.; Pant, P.C.; Chaudhary, R.

    2017-01-01

    Highlights: • Heat utilization from solar and biomass resources are considered for hybridization. • Modeling of polygeneration process in hybrid solar-biomass power plant is considered. • Thermodynamic evaluation are performed to identify the effect of various parameters. • Primary Energy Saving of polygeneration process is determined. - Abstract: In the polygeneration process simultaneous production of power, vapor absorption refrigeration (VAR) cooling and multi-effect humidification and dehumidification (MEHD) desalination system from different heat sources in hybrid solar-biomass (HSB) system with higher energy efficiency take place. It is one of the solutions to fulfill energy requirements from renewable sources and also helps in the reduction of carbon dioxide emissions. The VAR cooling system operates using the extracted heat taken from turbine and condenser heat of the VAR cooling system is used in desalination system for production of drinking water as per demand requirement. Though the production of electricity decreases due to extraction of heat from turbine for VAR cooling and desalination, the complete system meets the energy requirements & increases the primary energy savings (PES). The thermodynamic evaluation and optimization of HSB system in polygeneration process for combined power, cooling and desalination is investigated to identify the effects of various operating parameters. Primary energy savings (PES) of polygeneration process in HSB system is achieved to 50.5%. The energy output is increased to 78.12% from this system as compared to simple power plant.

  11. A generic multi-dimensional model-based system for batch cooling crystallization processes

    DEFF Research Database (Denmark)

    Abdul Samad, Noor Asma Fazli; Singh, Ravendra; Sin, Gürkan

    2011-01-01

    Highly porous deposits of flame-made aerosol nanoparticles were formed by filtration through a porous substrate (α-alumina, average pore diameter 3.7 μm). The aerosol was characterized by transmission electron microscopy (TEM) and scanning mobility particle sizer (SMPS) showing average primary an...

  12. The Use of Atomic-Force Microscopy for Studying the Crystallization Process of Amorphous Alloys

    Science.gov (United States)

    Elmanov, G. N.; Ivanitskaya, E. A.; Dzhumaev, P. S.; Skrytniy, V. I.

    The crystallization process of amorphous alloys is accompanied by the volume changes as a result of structural phase transitions. This leads to changes in the surface topography, which was studied by atomic force microscopy (AFM). The changes of the surface topography, structure and phase composition during multistage crystallization process of the metallic glasses with composition Ni71,5Cr6,8Fe2,7B11,9Si7,1 and Ni63,4Cr7,4Fe4,3Mn0,8B15,6Si8,5 (AWS BNi2) has been investigated. The obtained results on changing of the surface topography in crystallization process are in good agreement with the data of X-ray diffraction analysis (XRD). The nature of redistribution of some alloy components in the crystallization process has been suggested.

  13. Embedded RF Photonic Crystals as Routing and Processing Devices in Naval Aperstructures

    National Research Council Canada - National Science Library

    Prather, Dennis W

    2008-01-01

    .... To address these issues, we utilize advanced artificial materials - photonic crystals (PhCs) and meta-material - to construct a sensing head with minaturized antennas as RF receivers and embedded signal channelization for pre-processing...

  14. Effect of processing parameters of rotary ultrasonic machining on surface integrity of potassium dihydrogen phosphate crystals

    Directory of Open Access Journals (Sweden)

    Jianfu Zhang

    2015-09-01

    Full Text Available Potassium dihydrogen phosphate is an important optical crystal. However, high-precision processing of large potassium dihydrogen phosphate crystal workpieces is difficult. In this article, surface roughness and subsurface damage characteristics of a (001 potassium dihydrogen phosphate crystal surface produced by traditional and rotary ultrasonic machining are studied. The influence of process parameters, including spindle speed, feed speed, type and size of sintered diamond wheel, ultrasonic power, and selection of cutting fluid on potassium dihydrogen phosphate crystal surface integrity, was analyzed. The surface integrity, especially the subsurface damage depth, was affected significantly by the ultrasonic power. Metal-sintered diamond tools with high granularity were most suitable for machining potassium dihydrogen phosphate crystal. Cutting fluid played a key role in potassium dihydrogen phosphate crystal machining. A more precise surface can be obtained in machining with a higher spindle speed, lower feed speed, and using kerosene as cutting fluid. Based on the provided optimized process parameters for machining potassium dihydrogen phosphate crystal, a processed surface quality with Ra value of 33 nm and subsurface damage depth value of 6.38 μm was achieved.

  15. Thermal-capillary analysis of Czochralski and liquid encapsulated Czochralski crystal growth. II - Processing strategies

    Science.gov (United States)

    Derby, J. J.; Brown, R. A.

    1986-01-01

    The pseudosteady-state heat transfer model developed in a previous paper is augmented with constraints for constant crystal radius and melt/solid interface deflection. Combinations of growth rate, and crucible and bottom-heater temperatures are tested as processing parameters for satisfying the constrained thermal-capillary problem over a range of melt volumes corresponding to the sequence occuring during the batchwise Czochralski growth of a small-diameter silicon crystal. The applicability of each processing strategy is judged by the range of existence of the solution, in terms of melt volume and the values of the axial and radial temperature gradients in the crystal.

  16. Modeling the high-temperature gas-cooled reactor process heat plant: a nuclear to chemical conversion process

    International Nuclear Information System (INIS)

    Pfremmer, R.D.; Openshaw, F.L.

    1982-05-01

    The high-temperature heat available from the High-Temperature Gas-Cooled Reactor (HTGR) makes it suitable for many process applications. One of these applications is a large-scale energy production plant where nuclear energy is converted into chemical energy and stored for industrial or utility applications. This concept combines presently available nuclear HTGR technology and energy conversion chemical technology. The design of this complex plant involves questions of interacting plant dynamics and overall plant control. This paper discusses how these questions were answered with the aid of a hybrid computer model that was developed within the time-frame of the conceptual design studies. A brief discussion is given of the generally good operability shown for the plant and of the specific potential problems and their anticipated solution. The paper stresses the advantages of providing this information in the earliest conceptual phases of the design

  17. High heat load performance of an inclined crystal monochromator with liquid gallium cooling on the CHESS-ANL undulator

    International Nuclear Information System (INIS)

    Macrander, A.T.; Lee, W.K.; Smither, R.K.; Mills, D.M.

    1992-01-01

    Recent results for the performance of a novel double crystal monochromator subjected to high heat loads on an APS prototype undulator at the Cornell High Energy Synchrotron Source (CHESS) are presented. The monochromator was designed to achieve symmetric diffraction from asymmetric planes to spread out the beam footprint thereby lowering the incident power density. Both crystals had (111) oriented surfaces and were arranged such that the beam was diffracted from the (11 bar 1) planes at 5 KeV. Rocking curves with minimal distortion were obtained at a ring electron current of 100 mA. This corresponded to 380 Watts total power and an average power density of 40 Watts/mm 2 normal to the incident beam. These results are compared to data obtained from the same crystals in the standard geometry (diffracting planes parallel to surface). The footprint area in the inclined case was three times that of the standard case. We also obtained rocking curve data for the (333) reflection at 15 KeV for both standard and inclined cases, and these data also showed a minimal distortion only for the inclined case. In addition, thermal data were obtained via infrared pyrometry. Liquid gallium flow rates of up to 2 gallons per minute were investigated. The diffraction data revealed a dramatically improved performance for the inclined crystal case

  18. Numerical simulation of distorted crystal Darwin width

    International Nuclear Information System (INIS)

    Wang Li; Xu Zhongmin; Wang Naxiu

    2012-01-01

    A new numerical simulation method according to distorted crystal optical theory was used to predict the direct-cooling crystal monochromator optical properties(crystal Darwin width) in this study. The finite element analysis software was used to calculate the deformed displacements of DCM crystal and to get the local reciprocal lattice vector of distorted crystal. The broadening of direct-cooling crystal Darwin width in meridional direction was estimated at 4.12 μrad. The result agrees well with the experimental data of 5 μrad, while it was 3.89 μrad by traditional calculation method of root mean square (RMS) of the slope error in the center line of footprint. The new method provides important theoretical support for designing and processing of monochromator crystal for synchrotron radiation beamline. (authors)

  19. Modeling of Rocket Fuel Heating and Cooling Processes in the Interior Receptacle Space of Ground-Based Systems

    Directory of Open Access Journals (Sweden)

    K. I. Denisova

    2016-01-01

    Full Text Available The propellant to fill the fuel tanks of the spacecraft, upper stages, and space rockets on technical and ground-based launch sites before fueling should be prepared to ensure many of its parameters, including temperature, in appropriate condition. Preparation of fuel temperature is arranged through heating and cooling the rocket propellants (RP in the tanks of fueling equipment. Processes of RP temperature preparation are the most energy-intensive and timeconsuming ones, which require that a choice of sustainable technologies and modes of cooling (heating RP provided by the ground-based equipment has been made through modeling of the RP [1] temperature preparation processes at the stage of design and operation of the groundbased fueling equipment.The RP temperature preparation in the tanks of the ground-based systems can be provided through the heat-exchangers built-in the internal space and being external with respect to the tank in which antifreeze, air or liquid nitrogen may be used as the heat transfer media. The papers [1-12], which note a promising use of the liquid nitrogen to cool PR, present schematic diagrams and modeling systems for the RP temperature preparation in the fueling equipment of the ground-based systems.We consider the RP temperature preparation using heat exchangers to be placed directly in RP tanks. Feeding the liquid nitrogen into heat exchanger with the antifreeze provides the cooling mode of PR while a heated air fed there does that of heating. The paper gives the systems of equations and results of modeling the processes of RP temperature preparation, and its estimated efficiency.The systems of equations of cooling and heating RP are derived on the assumption that the heat exchange between the fuel and the antifreeze, as well as between the storage tank and the environment is quasi-stationary.The paper presents calculation results of the fuel temperature in the tank, and coolant temperature in the heat exchanger, as

  20. Solid radioactive waste processing system for light water cooled reactor plants

    International Nuclear Information System (INIS)

    Anon.

    1979-01-01

    Design, construction and performance requirements are given for the operation of the solid radioactive waste processing system for light water-cooled reactor plants. All radioactive or contaminated materials, including spent air and liquid filter elements, spent bead resins, filter sludge, spent powdered resins, evaporator and reverse osmosis concentrates, and dry radioactive wastes are to be processed in appropriate portions of the system. Sections of the standard cover: overall system requirements; equipment requirement; controls and instrumentation; physical arrangement; system capacity and redundancy; operation and maintenance; and system construction and testing. Provisions contained in this standard are to take precedence over ANS-51.1-1973(N18.2-1973) and its revision, ANS-51.8-1975(N18.2a-1975), Sections 2.2 and 2.3. The product resulting from the solid radioactive waste processing system must meet criteria imposed by standards and regulations for transportation and burial (Title 10, Code of Federal Regulations, Part 71, Title 49, Code of Federal Regulations, Parts 100 to 199). As a special feature, all statements in this standard which are related to nuclear safety are set off in boxes

  1. Restaurant food cooling practices.

    Science.gov (United States)

    Brown, Laura Green; Ripley, Danny; Blade, Henry; Reimann, Dave; Everstine, Karen; Nicholas, Dave; Egan, Jessica; Koktavy, Nicole; Quilliam, Daniela N

    2012-12-01

    Improper food cooling practices are a significant cause of foodborne illness, yet little is known about restaurant food cooling practices. This study was conducted to examine food cooling practices in restaurants. Specifically, the study assesses the frequency with which restaurants meet U.S. Food and Drug Administration (FDA) recommendations aimed at reducing pathogen proliferation during food cooling. Members of the Centers for Disease Control and Prevention's Environmental Health Specialists Network collected data on food cooling practices in 420 restaurants. The data collected indicate that many restaurants are not meeting FDA recommendations concerning cooling. Although most restaurant kitchen managers report that they have formal cooling processes (86%) and provide training to food workers on proper cooling (91%), many managers said that they do not have tested and verified cooling processes (39%), do not monitor time or temperature during cooling processes (41%), or do not calibrate thermometers used for monitoring temperatures (15%). Indeed, 86% of managers reported cooling processes that did not incorporate all FDA-recommended components. Additionally, restaurants do not always follow recommendations concerning specific cooling methods, such as refrigerating cooling food at shallow depths, ventilating cooling food, providing open-air space around the tops and sides of cooling food containers, and refraining from stacking cooling food containers on top of each other. Data from this study could be used by food safety programs and the restaurant industry to target training and intervention efforts concerning cooling practices. These efforts should focus on the most frequent poor cooling practices, as identified by this study.

  2. A Low-Cost System Based on Image Analysis for Monitoring the Crystal Growth Process.

    Science.gov (United States)

    Venâncio, Fabrício; Rosário, Francisca F do; Cajaiba, João

    2017-05-31

    Many techniques are used to monitor one or more of the phenomena involved in the crystallization process. One of the challenges in crystal growth monitoring is finding techniques that allow direct interpretation of the data. The present study used a low-cost system, composed of a commercial webcam and a simple white LED (Light Emitting Diode) illuminator, to follow the calcium carbonate crystal growth process. The experiments were followed with focused beam reflectance measurement (FBRM), a common technique for obtaining information about the formation and growth of crystals. The images obtained in real time were treated with the red, blue, and green (RGB) system. The results showed a qualitative response of the system to crystal formation and growth processes, as there was an observed decrease in the signal as the growth process occurred. Control of the crystal growth was managed by increasing the viscosity of the test solution with the addition of monoethylene glycol (MEG) at 30% and 70% in a mass to mass relationship, providing different profiles of the RGB average curves. The decrease in the average RGB value became slower as the concentration of MEG was increased; this reflected a lag in the growth process that was proven by the FBRM.

  3. Waste Heat Recovery and Recycling in Thermal Separation Processes: Distillation, Multi-Effect Evaporation (MEE) and Crystallization Processes

    Energy Technology Data Exchange (ETDEWEB)

    Emmanuel A. Dada; Chandrakant B. Panchal; Luke K. Achenie; Aaron Reichl; Chris C. Thomas

    2012-12-03

    Evaporation and crystallization are key thermal separation processes for concentrating and purifying inorganic and organic products with energy consumption over 1,000 trillion Btu/yr. This project focused on a challenging task of recovering low-temperature latent heat that can have a paradigm shift in the way thermal process units will be designed and operated to achieve high-energy efficiency and significantly reduce the carbon footprint as well as water footprint. Moreover, this project has evaluated the technical merits of waste-heat powered thermal heat pumps for recovery of latent heat from distillation, multi-effect evaporation (MEE), and crystallization processes and recycling into the process. The Project Team has estimated the potential energy, economics and environmental benefits with the focus on reduction in CO2 emissions that can be realized by 2020, assuming successful development and commercialization of the technology being developed. Specifically, with aggressive industry-wide applications of heat recovery and recycling with absorption heat pumps, energy savings of about 26.7 trillion Btu/yr have been estimated for distillation process. The direct environmental benefits of this project are the reduced emissions of combustible products. The estimated major reduction in environmental pollutants in the distillation processes is in CO2 emission equivalent to 3.5 billion lbs/year. Energy consumption associated with water supply and treatments can vary between 1,900 kWh and 23,700 kWh per million-gallon water depending on sources of natural waters [US DOE, 2006]. Successful implementation of this technology would significantly reduce the demand for cooling-tower waters, and thereby the use and discharge of water treatment chemicals. The Project Team has also identified and characterized working fluid pairs for the moderate-temperature heat pump. For an MEE process, the two promising fluids are LiNO3+KNO3+NANO3 (53:28:19 ) and LiNO3+KNO3+NANO2

  4. Data Processing and Measuring System for Studying the Cooling Capacity of Quenchants

    Science.gov (United States)

    Tsaplin, S. V.; Bolychev, S. A.; Shemanaev, D. V.; Mishagin, B. S.

    2014-09-01

    A domestically produced device for determining the cooling capacity of quenchants is developed on the basis of the ISO 9001, ISO 9950, ASTM D6200-01, and ASTM D6482-01 standards. Acomparison of the results of a determination of the parameters of cooling environments obtained by means of the present device and a foreign counterpart is carried out.

  5. Validation of mathematical model for CZ process using small-scale laboratory crystal growth furnace

    Science.gov (United States)

    Bergfelds, Kristaps; Sabanskis, Andrejs; Virbulis, Janis

    2018-05-01

    The present material is focused on the modelling of small-scale laboratory NaCl-RbCl crystal growth furnace. First steps towards fully transient simulations are taken in the form of stationary simulations that deal with the optimization of material properties to match the model to experimental conditions. For this purpose, simulation software primarily used for the modelling of industrial-scale silicon crystal growth process was successfully applied. Finally, transient simulations of the crystal growth are presented, giving a sufficient agreement to experimental results.

  6. Elementary martensitic transformation processes in Ni-rich NiTi single crystals with Ni4Ti3 precipitates

    International Nuclear Information System (INIS)

    Michutta, J.; Somsen, Ch.; Yawny, A.; Dlouhy, A.; Eggeler, G.

    2006-01-01

    The present study shows that multiple-step martensitic transformations can be observed in aged Ni-rich NiTi single crystals. Ageing of solution-annealed and water-quenched Ni-rich NiTi single crystals results in a homogeneous precipitation of coherent Ni 4 Ti 3 particles. When the interparticle spacing reaches a critical value (order of magnitude: 200 nm), three distinct transformation processes are observed on cooling from the high-temperature phase using differential scanning calorimetry and in situ transmission electron microscopy. The transformation sequence begins with the formation of R-phase starting from all precipitate/matrix interfaces (first step). The transformation continues with the formation of B19' and its subsequent growth along all precipitate/matrix interfaces (second step). Finally, the matrix in between the precipitates transforms to B19' (third step). Elementary transformation mechanisms which account for two- and three-step transformations in a system with small-scale microstructural heterogeneities were identified

  7. Crystallization characteristics of cast aluminum alloys during a unidirectional solidification process

    Energy Technology Data Exchange (ETDEWEB)

    Okayasu, Mitsuhiro, E-mail: mitsuhiro.okayasu@utoronto.ca; Takeuchi, Shuhei

    2015-05-01

    The crystal orientation characteristics of cast Al–Si, Al–Cu and Al–Mg alloys produced by a unidirectional solidification process are examined. Two distinct crystal orientation patterns are observed: uniform and random formation. A uniform crystal orientation is created by columnar growth of α-Al dendrites in the alloys with low proportions of alloying element, e.g., the Al–Si alloy (with Si <12.6%) and the Al–Cu and Al–Mg alloys (with Cu and Mg <2%). A uniformly organized crystal orientation with [100] direction is created by columnar growth of α-Al dendrites. With increasing proportion of alloying element (>2% Cu or Mg), the uniform crystal orientations collapse in the Al–Cu and Al–Mg alloys, owing to interruption of the columnar α-Al dendrite growth as a result of different dynamics of the alloying atoms and the creation of a core for the eutectic phases. For the hypo-eutectic Al–Si alloys, a uniform crystal orientation is obtained. In contrast, a random orientation can be detected in the hyper-eutectic Al–Si alloy (15% Si), which results from interruption of the growth of the α-Al dendrites due to precipitation of primary Si particles. There is no clear effect of crystal formation on ultimate tensile strength (UTS), whereas crystal orientation does influence the material ductility, with the alloys with a uniform crystal orientation being elongated beyond their UTS points and with necking occurring in the test specimens. In contrast, the alloys with a nonuniform crystal orientation are not elongated beyond their UTS points.

  8. Crystallization characteristics of cast aluminum alloys during a unidirectional solidification process

    International Nuclear Information System (INIS)

    Okayasu, Mitsuhiro; Takeuchi, Shuhei

    2015-01-01

    The crystal orientation characteristics of cast Al–Si, Al–Cu and Al–Mg alloys produced by a unidirectional solidification process are examined. Two distinct crystal orientation patterns are observed: uniform and random formation. A uniform crystal orientation is created by columnar growth of α-Al dendrites in the alloys with low proportions of alloying element, e.g., the Al–Si alloy (with Si <12.6%) and the Al–Cu and Al–Mg alloys (with Cu and Mg <2%). A uniformly organized crystal orientation with [100] direction is created by columnar growth of α-Al dendrites. With increasing proportion of alloying element (>2% Cu or Mg), the uniform crystal orientations collapse in the Al–Cu and Al–Mg alloys, owing to interruption of the columnar α-Al dendrite growth as a result of different dynamics of the alloying atoms and the creation of a core for the eutectic phases. For the hypo-eutectic Al–Si alloys, a uniform crystal orientation is obtained. In contrast, a random orientation can be detected in the hyper-eutectic Al–Si alloy (15% Si), which results from interruption of the growth of the α-Al dendrites due to precipitation of primary Si particles. There is no clear effect of crystal formation on ultimate tensile strength (UTS), whereas crystal orientation does influence the material ductility, with the alloys with a uniform crystal orientation being elongated beyond their UTS points and with necking occurring in the test specimens. In contrast, the alloys with a nonuniform crystal orientation are not elongated beyond their UTS points

  9. Phosphates (V) recovery from phosphorus mineral fertilizers industry wastewater by continuous struvite reaction crystallization process.

    Science.gov (United States)

    Hutnik, Nina; Kozik, Anna; Mazienczuk, Agata; Piotrowski, Krzysztof; Wierzbowska, Boguslawa; Matynia, Andrzej

    2013-07-01

    Continuous DT MSMPR (Draft Tube Mixed Suspension Mixed Product Removal) crystallizer was provided with typical wastewater from phosphorus mineral fertilizers industry (pH < 4, 0.445 mass % of PO4(3-), inorganic impurities presence), dissolved substrates (magnesium and ammonium chlorides) and solution alkalising the environment of struvite MgNH4PO4·6H2O reaction crystallization process. Research ran in constant temperature 298 K assuming stoichiometric proportions of substrates or 20% excess of magnesium ions. Influence of pH (8.5-10) and mean residence time (900-3600 s) on product size distribution, its chemical composition, crystals shape, size-homogeneity and process kinetics was identified. Crystals of mean size ca. 25-37 μm and homogeneity CV 70-83% were produced. The largest crystals, of acceptable homogeneity, were produced using 20% excess of magnesium ions, pH 9 and mean residence time 3600 s. Under these conditions nucleation rate did not exceed 9 × 10(7) 1/(s m(3)) according to SIG (Size Independent Growth) MSMPR kinetic model. Linear crystal growth rate was 4.27 × 10(-9) m/s. Excess of magnesium ions influenced struvite reaction crystallization process yield advantageously. Concentration of phosphate(V) ions decreased from 0.445 to 9.2 × 10(-4) mass %. This can be regarded as a very good process result. In product crystals, besides main component - struvite, all impurities from wastewater were detected analytically. Copyright © 2013 Elsevier Ltd. All rights reserved.

  10. Creep of crystals: High-temperature deformation processes in metals, ceramics and minerals

    Science.gov (United States)

    Poirier, J. P.

    An introductory text describing high-temperature deformation processes in metals, ceramics, and minerals is presented. Among the specific topics discussed are: the mechanical aspects of crystal deformation; lattice defects; and phenomenological and thermodynamical analysis of quasi-steady-state creep. Consideration is also given to: dislocation creep models; the effect of hydrostatic pressure on deformation; creep polygonization; and dynamic recrystallization. The status of experimental techniques for the study of transformation plasticity in crystals is also discussed.

  11. Response to Comment on "Rapid cooling and cold storage in a silicic magma reservoir recorded in individual crystals".

    Science.gov (United States)

    Cooper, Kari M; Till, Christy B; Kent, Adam J R; Costa, Fidel; Rubin, Allison E; Gravley, Darren; Deering, Chad; Cole, Jim; Bose, Maitrayee

    2017-12-22

    In a recent paper, we used Li concentration profiles and U-Th ages to constrain the thermal conditions of magma storage. Wilson and co-authors argue that the data instead reflect control of Li behavior by charge balance during partitioning and not by experimentally determined diffusion rates. Their arguments are based on (i) a coupled diffusion mechanism for Li, which has been postulated but has not been documented to occur, and (ii) poorly constrained zircon growth rates combined with the assumption of continuous zircon crystallization. Copyright © 2017, American Association for the Advancement of Science.

  12. Development of Auto-Seeding System Using Image Processing Technology in the Sapphire Crystal Growth Process via the Kyropoulos Method

    Directory of Open Access Journals (Sweden)

    Churl Min Kim

    2017-04-01

    Full Text Available The Kyropoulos (Ky and Czochralski (Cz methods of crystal growth are used for large-diameter single crystals. The seeding process in these methods must induce initial crystallization by initiating contact between the seed crystals and the surface of the melted material. In the Ky and Cz methods, the seeding process lays the foundation for ingot growth during the entire growth process. When any defect occurs in this process, it is likely to spread to the entire ingot. In this paper, a vision system was constructed for auto seeding and for observing the surface of the melt in the Ky method. An algorithm was developed to detect the time when the internal convection of the melt is stabilized by observing the shape of the spoke pattern on the melt material surface. Then, the vision system and algorithm were applied to the growth furnace, and the possibility of process automation was examined for sapphire growth. To confirm that the convection of the melt was stabilized, the position of the island (i.e., the center of a spoke pattern was detected using the vision system and image processing. When the observed coordinates for the center of the island were compared with the coordinates detected from the image processing algorithm, there was an average error of 1.87 mm (based on an image with 1024 × 768 pixels.

  13. Material development for gas-cooled high temperature reactors for the production of nuclear process heat

    International Nuclear Information System (INIS)

    Nickel, H.

    1977-04-01

    In the framework of the material development for gas-cooled high temperature reactors, considerable investigations of the materials for the reactor core and the primary cicuit are being conducted. Concerning the core components, the current state-of-the-art and the objectives of the development work on the spherical fuel elements, coated particles and structural graphite are discussed. As an example of the structural graphite, the non-replaceable reflector of the process heat reactor is discussed. The primary circuit will be constructed mainly from metallic materials, although some ceramics are also being considered. Components of interest are hot gas ducts, liners, methane reformer tubes and helium-helium intermediate heat exchangers. The gaseous impurities present in the helium coolant may cause oxidation and carburization of the nickel-base and iron-base alloys envisaged for use in these components, with a possible associated adverse effect on the mechanical properties such as creep and fatigue. Test capacity has therefore been installed to investigate materials behaviour in simulated reactor helium under both constant and alternating stress conditions. The first results on the creep behaviour of several alloys in impure helium are presented and discussed. (orig./GSC) [de

  14. Manufacturing Process Developments for Regeneratively-Cooled Channel Wall Rocket Nozzles

    Science.gov (United States)

    Gradl, Paul; Brandsmeier, Will

    2016-01-01

    Regeneratively cooled channel wall nozzles incorporate a series of integral coolant channels to contain the coolant to maintain adequate wall temperatures and expand hot gas providing engine thrust and specific impulse. NASA has been evaluating manufacturing techniques targeting large scale channel wall nozzles to support affordability of current and future liquid rocket engine nozzles and thrust chamber assemblies. The development of these large scale manufacturing techniques focus on the liner formation, channel slotting with advanced abrasive water-jet milling techniques and closeout of the coolant channels to replace or augment other cost reduction techniques being evaluated for nozzles. NASA is developing a series of channel closeout techniques including large scale additive manufacturing laser deposition and explosively bonded closeouts. A series of subscale nozzles were completed evaluating these processes. Fabrication of mechanical test and metallography samples, in addition to subscale hardware has focused on Inconel 625, 300 series stainless, aluminum alloys as well as other candidate materials. Evaluations of these techniques are demonstrating potential for significant cost reductions for large scale nozzles and chambers. Hot fire testing is planned using these techniques in the future.

  15. Development of a neutron irradiation device with a cooled crystal filter: Radiation physical properties and applications in in vivo irradiations

    International Nuclear Information System (INIS)

    Braetter, P.; Galinke, E.; Gatschke, W.; Gawlik, D.; Roesick, U.

    1979-01-01

    The radiation-physical and geometrical properties of a neutron-beam, collimated with a Bi-crystal filter were investigated at the reactor BER II. The influence of the crystal temperature as well as the actions of a reflector and a collimator on neutron flux-density and neutron field of the thermal neutrons were investigated. The dose contributions of the thermal, epithermal and fast neutrons as well as γ-radiation was determined by activation of the sample respective with TLD-measurements. The influence of irradiation and measurement geometry on the sensitivity and detection probability was investigated by means of phantom irradiations. The method prooved to be suitable, to detect changes of the Ca-content in a rat hind leg by about 10%. In investigations on animal groups of about 10 animals a threshold of detectability for changes of the ca-content is to be expected by about 4%. In a further group experiment it was found, that even in the case of multiple radiation the procedure of irradiation and measurement was not followed by a significant change in the Ca-content of the hind legs of the testing animals. (orig.) [de

  16. Monoclinic MB phase and phase instability in [110] field cooled Pb(Zn1/3Nb2/3)O3-4.5%PbTiO3 single crystals

    Science.gov (United States)

    Yao, Jianjun; Cao, Hu; Ge, Wenwei; Li, Jiefang; Viehland, D.

    2009-08-01

    We report the finding of a monoclinic MB phase in Pb(Zn1/3Nb2/3)O3-4.5%PbTiO3 single crystals. High precision x-ray diffraction investigations of [110] field cooled crystals have shown a transformation sequence of cubic(C)→tetragonal(T)→orthorhombic(O)→monoclinic(MB), which is different from that previously reported [A.-E. Renault et al., J. Appl. Phys. 97, 044105 (2005)]. Beginning in the zero-field-cooled condition at 383 K, a rhombohedral (R)→MB→O sequence was observed with increasing field. Coexisting MB and O phases were then found upon removal of field, which fully transformed to MB on cooling to room temperature.

  17. Experimental study and process parameters analysis on the vacuum cooling of iceberg lettuce

    International Nuclear Information System (INIS)

    He Suyan; Li Yunfei

    2008-01-01

    The vacuum cooling of iceberg lettuce was described in this paper. Based on the energy and mass balance, a mathematical model was developed to analyze the performance of the vacuum cooler and the evaporation-boiling phenomena during vacuum cooling of iceberg lettuce. The temporal trends of total system pressure, produce temperature such as surface temperature, center temperature, mass-average temperature, the weight loss of iceberg lettuce during vacuum cooling were predicted. Validation experimentation is achieved in the designed vacuum cooler. The experimental data were compared with the simulation results. It was found that the differences of the temperature between the simulation and the experiments were within 1 deg. C. The amount of water evaporated from the iceberg lettuce by simulation was 3.32% during the whole vacuum cooling, while the tested water loss rate was 2.97%, the maximal deviation of weight loss was within 0.59%. The simulation results agreed well with the experimental data

  18. Experimental study and process parameters analysis on the vacuum cooling of iceberg lettuce

    Energy Technology Data Exchange (ETDEWEB)

    He Suyan [School of Mechanical and Electrical Engineering, Qingdao University, Qingdao 266071 (China)], E-mail: hesuyan67829@sina.com; Li Yunfei [Department of Food Science and Engineering, School of Agriculture and Biology, Shanghai Jiao Tong University (China)

    2008-10-15

    The vacuum cooling of iceberg lettuce was described in this paper. Based on the energy and mass balance, a mathematical model was developed to analyze the performance of the vacuum cooler and the evaporation-boiling phenomena during vacuum cooling of iceberg lettuce. The temporal trends of total system pressure, produce temperature such as surface temperature, center temperature, mass-average temperature, the weight loss of iceberg lettuce during vacuum cooling were predicted. Validation experimentation is achieved in the designed vacuum cooler. The experimental data were compared with the simulation results. It was found that the differences of the temperature between the simulation and the experiments were within 1 deg. C. The amount of water evaporated from the iceberg lettuce by simulation was 3.32% during the whole vacuum cooling, while the tested water loss rate was 2.97%, the maximal deviation of weight loss was within 0.59%. The simulation results agreed well with the experimental data.

  19. Uranium and thorium concentration process during partial fusion and crystallization of granitic magma

    International Nuclear Information System (INIS)

    Cuney, M.

    1982-01-01

    Two major processes, frequently difficult to distinguish, lead to uranium and thorium enrichment in igneous rocks and more particularly in granitoids; these are partial melting and fractional crystallization. Mont-Laurier uranothoriferous pegmatoids, Bancroft and Roessing deposits are examples of radioelement concentrations resulting mostly of low grade of melting on essentially metasedimentary formations deposited on a continental margin or intracratonic. Fractional crystallization follows generally partial melting even in migmatitic areas. Conditions prevailing during magma crystallization and in particular oxygen fugacity led either to the formation of uranium preconcentrations in granitoids, or to its partition in the fluid phase expelled from the magma. No important economic uranium deposit appears to be mostly related to fractional crystallization of large plutonic bodies

  20. Patterning solution-processed organic single-crystal transistors with high device performance

    Directory of Open Access Journals (Sweden)

    Yun Li

    2011-06-01

    Full Text Available We report on the patterning of organic single-crystal transistors with high device performance fabricated via a solution process under ambient conditions. The semiconductor was patterned on substrates via surface selective deposition. Subsequently, solvent-vapor annealing was performed to reorganize the semiconductor into single crystals. The transistors exhibited field-effect mobility (μFET of up to 3.5 cm2/V s. Good reliability under bias-stress conditions indicates low density of intrinsic defects in crystals and low density of traps at the active interfaces. Furthermore, the Y function method clearly suggests that the variation of μFET of organic crystal transistors was caused by contact resistance. Further improvement of the device with higher μFET with smaller variation can be expected when lower and more uniform contact resistance is achieved.

  1. Properties of the Sodium Naproxen-Lactose-Tetrahydrate Co-Crystal upon Processing and Storage

    DEFF Research Database (Denmark)

    Sovago, Ioana; Wang, Wenbo; Qiu, Danwen

    2016-01-01

    naproxen-lactose-tetrahydrate co-crystal and the co-amorphous mixture of sodium, naproxen, and lactose was investigated. The structure of the co-crystal is described using single-crystal X-ray diffraction. The structural analysis revealed a monoclinic lattice, space group P21, with the asymmetric unit...... containing one molecule of lactose, one of naproxen, sodium, and four water molecules. Upon heating, it was observed that the co-crystal transforms into a co-amorphous system due to the loss of its crystalline bound water. Dehydration and co-amorphization were studied using synchrotron X-ray radiation...... and thermogravimetric analysis (TGA). Subsequently, different processing techniques (ball milling, spray drying, and dehydration) were used to prepare the co-amorphous mixture of sodium, naproxen, and lactose. X-ray powder diffraction (XRPD) revealed the amorphous nature of the mixtures after preparation. Differential...

  2. Seed crystals with improved properties for melt processing superconductors for practical applications

    Science.gov (United States)

    Veal, Boyd W.; Paulikas, Arvydas; Balachandran, Uthamalingam; Zhong, Wei

    1997-01-01

    A method of fabricating bulk superconducting material including RBa.sub.2 Cu.sub.3 O.sub.7-.delta. comprising heating compressed powder oxides and/or carbonates of R and Ba and Cu present in mole ratios to form RBa.sub.2 Cu.sub.3 O.sub.7-.delta. in physical contact with an oxide single crystal seed to a temperature sufficient to form a liquid phase in the RBa.sub.2 Cu.sub.3 O.sub.7-.delta. while maintaining the single crystal seed solid to grow the superconducting material and thereafter cooling to provide a material including RBa.sub.2 Cu.sub.3 O.sub.7-.delta.. R is a rare earth or Y or La and the single crystal seed has a lattice mismatch with RBa.sub.2 Cu.sub.3 O.sub.7-.delta. of less than about 2% at the growth temperature. The starting material may be such that the final product contains a minor amount of R.sub.2 BaCuO.sub.5.

  3. Low Temperature Synthesis of Metal Oxides by a Supercritical Seed Enhanced Crystallization (SSEC) Process

    DEFF Research Database (Denmark)

    Jensen, Henrik; Brummerstedt Iversen, Steen; Joensen, Karsten Dan

    2006-01-01

    A novel method for producing crystalline nanosized metal oxides by a Supercritical Seed Enhanced Crystallization (SSEC) Process has been developed. The process is a modified sol-gel process taking place at temperatures as low as 95 ºC with supercritical CO2 as solvent and polypropylene as seeding...... material. The nanocrystalline product is obtained without having to resort to costly post-reaction processing and the product is obtained directly after the SSEC process. TiO2 powders produced by the SSEC process were shown to have a crystallinity of 60 % and a crystal size of 7.3 ± 2.6 nm....... The crystallinity can be controlled by changing the heating rate of the initial formation of the nanoparticles and the morphology can be altered by changing the process time....

  4. Dynamic Processes in Nanostructured Crystals Under Ion Irradiation

    Science.gov (United States)

    Uglov, V. V.; Kvasov, N. T.; Shimanski, V. I.; Safronov, I. V.; Komarov, N. D.

    2018-02-01

    The paper presents detailed investigations of dynamic processes occurring in nanostructured Si(Fe) material under the radiation exposure, namely: heating, thermoelastic stress generation, elastic disturbances of the surrounding medium similar to weak shock waves, and dislocation generation. The performance calculations are proposed for elastic properties of the nanostructured material with a glance to size effects in nanoparticles.

  5. Borassus flabellifer L. Brown Crystal Sugar Processing (The Study of Sap pH and Fine Crystal Sucrose (FCS Concentration

    Directory of Open Access Journals (Sweden)

    Azmi Alvian Gabriel

    2017-04-01

    Full Text Available Nira as one of the Borassus flabellirer L. products has a similar characteristics with other agricultural commodities that are easily damaged. This research aims to know the influence of nira’s pH and concentration addition of FCS against characteristics of the brown crystal sugar. Research compiled by using Randomized Block Design (RBD which comprises two factors consisting of 3 levels with 3 times replication. The first factor is pH or degree of nira acidity which consists of 3 level (6.50 (± 0.10; 7.00 (± 0.10; 7.50 (± 0.10 and the second factor is addition of FCS concentration consisting of 3 level (5%; 10%; 15% (b/v. The analyzes used include analysis of organoleptic (color, aroma, taste as well as physical and chemical analyzes (sucrose content, moisture content, ash content, reducing sugar content, insoluble solid content. The analysis results of raw material showed that the pH of palm sap affect the amount of total sugar because the fermentation process. The addition of 10% FCS provides organoleptic results with the best reception at the brown crystal sugar. Physical and chemical test results of products with the best treatment showed that the levels of sucrose in brown crystal sugar was 81.483% in accordance with the minimum requirements specified Indonesian Industrial Standard (IIS, water content of 6.32% dry basis , ash content of 1.78%, reducing sugar amounted to 5.18%, and insoluble solid content of 0.089%.

  6. Laboratory Investigation of Contact Freezing and the Aerosol to Ice Crystal Transformation Process

    Energy Technology Data Exchange (ETDEWEB)

    Shaw, Raymond A. [Michigan Technological Univ., Houghton, MI (United States)

    2014-10-28

    This project has been focused on the following objectives: 1. Investigations of the physical processes governing immersion versus contact nucleation, specifically surface-induced crystallization; 2. Development of a quadrupole particle trap with full thermodynamic control over the temperature range 0 to –40 °C and precisely controlled water vapor saturation ratios for continuous, single-particle measurement of the aerosol to ice crystal transformation process for realistic ice nuclei; 3. Understanding the role of ice nucleation in determining the microphysical properties of mixed-phase clouds, within a framework that allows bridging between laboratory and field measurements.

  7. Glow discharge processing in the liquid crystal display industry

    International Nuclear Information System (INIS)

    Schmitt, Jacques; Elyaakoubi, Mustapha; Sansonnens, Laurent

    2002-01-01

    The active matrix display industry is rapidly presented. The most challenging aspect for plasma source design lies in the substrate size which is now entering the 1-2 m range. This paper focuses on the conventional planar RF capacitor at 13.56 MHz. A detailed analysis of the local perturbation due to a hole in the metal susceptor illustrates the process effects of various plasma microscopic parameters. It appears that not only the process rate must be kept uniform, but also the ion bombardment. It is also shown that very wide capacitive reactors no longer follow some classical rules: (1) plasma RF conductivity is limited, its propagation is shown to be described by a telegraph equation, in agreement with numerical modelling and electrostatic measurements, (2) the RF wavelength is no longer infinite compared to the dimensions, this leads to standing waves. The presence of the plasma is shown to worsen the effect by shortening the RF propagation wavelength

  8. Effects of face/head and whole body cooling during passive heat stress on human somatosensory processing.

    Science.gov (United States)

    Nakata, Hiroki; Namba, Mari; Kakigi, Ryusuke; Shibasaki, Manabu

    2017-06-01

    We herein investigated the effects of face/head and whole body cooling during passive heat stress on human somatosensory processing recorded by somatosensory-evoked potentials (SEPs) at C4' and Fz electrodes. Fourteen healthy subjects received a median nerve stimulation at the left wrist. SEPs were recorded at normothermic baseline (Rest), when esophageal temperature had increased by ~1.2°C (heat stress: HS) during passive heating, face/head cooling during passive heating (face/head cooling: FHC), and after HS (whole body cooling: WBC). The latencies and amplitudes of P14, N20, P25, N35, P45, and N60 at C4' and P14, N18, P22, and N30 at Fz were evaluated. Latency indicated speed of the subcortical and cortical somatosensory processing, while amplitude reflected the strength of neural activity. Blood flow in the internal and common carotid arteries (ICA and CCA, respectively) and psychological comfort were recorded in each session. Increases in esophageal temperature due to HS significantly decreased the amplitude of N60, psychological comfort, and ICA blood flow in the HS session, and also shortened the latencies of SEPs (all, P body temperature. Copyright © 2017 the American Physiological Society.

  9. Spatial Control of Crystal Texture by Laser DMD Process

    Science.gov (United States)

    2009-02-01

    Parallel to rolling direction 1120 827 31 205 24 Matweb In718 filler material 1140 414 Charpy Impact Energy (J) Hardness (HRC) Tensile strength (Mpa...J. Choi, K. Nagarathnam, J. Koch, and D. Hetzner, “The direct metal deposition of H13 tool steel for 3-D components,” JOM, 49(5), 1997, 55-60. 4. M...Transactions A, 36A, 2005, 3397-3406. 6. Y. Hua and J. Choi, “Feedback control effects on dimensions and defects of H13 tool steel by DMD process,” J. of Laser Applications, 17(2), 2005, 117-125. 412

  10. Process Analytical Technology for Crystallization of Active Pharmaceutical Ingredients

    DEFF Research Database (Denmark)

    Malwade, Chandrakant Ramkrishna; Qu, Haiyan

    2018-01-01

    Background: Pharmaceutical industry is witnessing increased pressure to introduce innovative and efficient processes for manufacturing of Active Pharmaceutical Ingredients (APIs) in order to be competitive as well as to meet the stringent product quality requirements set by regulatory authorities...... parameters and their impact on quality of APIs and subsequently the drug products assume great significance for pharmaceutical industry. Methods: This review paper focuses on application of PAT tools, an integral part of Quality by Design (QbD) approach, for better understanding, control, and design...

  11. Mineralization Process of Biocemented Sand and Impact of Bacteria and Calcium Ions Concentrations on Crystal Morphology

    Directory of Open Access Journals (Sweden)

    Guobin Xu

    2017-01-01

    Full Text Available Microbial-induced calcite precipitation (MICP is a sustainable technique used to improve sandy soil. Analysis of the mineralization process, as well as different bacterial suspensions and calcium concentrations on the crystal morphology, revealed that the mineralization process included four stages: self-organised hydrolysis of microorganisms, molecular recognition and interface interaction, growth modulation, and epitaxial growth. By increasing bacterial suspensions and calcium concentrations, the crystal morphology changed from hexahedron to oblique polyhedron to ellipsoid; the best crystal structure occurs at OD600 = 1.0 and [Ca2+] = 0.75 mol/l. It should be noted that interfacial hydrogen bonding is the main force that binds the loose sand particles. These results will help in understanding the mechanism of MICP.

  12. Self-organization processes and nanocluster formation in crystal lattices by low-energy ion irradiation

    International Nuclear Information System (INIS)

    Tereshko, I.; Abidzina, V.; Tereshko, A.; Glushchenko, V.; Elkin, I.

    2007-01-01

    The goal of this paper is to study self-organization processes that cause nanostructural evolution in nonlinear crystal media. The subjects of the investigation were nonlinear homogeneous and heterogeneous atom chains. The method of computer simulation was used to investigate the interaction between low-energy ions and crystal lattices. It was based on the conception of three-dimensional lattice as a nonlinear atom chain system. We showed that that in homogeneous atom chains critical energy needed for self-organization processes development is less than for nonlinear atom chain with already embedded clusters. The possibility of nanostructure formation was studied by a molecular dynamics method of nonlinear oscillations in atomic oscillator systems of crystal lattices after their low-energy ion irradiation. (authors)

  13. Normal processes of phonon-phonon scattering and thermal conductivity of germanium crystals with isotopic disorder

    CERN Document Server

    Kuleev, I G

    2001-01-01

    The effect of normal processes of the phonon-phonon scattering on the thermal conductivity of the germanium crystals with various isotopic disorder degrees is considered. The phonon pulse redistribution in the normal scattering processes both inside each oscillatory branch (the Simons mechanism) and between various phonon oscillatory branches (the Herring mechanism) is accounted for. The contributions of the longitudinal and cross-sectional phonons drift motion into the thermal conductivity are analyzed. It is shown that the pulse redistribution in the Herring relaxation mechanism leads to essential suppression of the longitudinal phonons drift motion in the isotopically pure germanium crystals. The calculations results of thermal conductivity for the Herring relaxation mechanism agree well with experimental data on the germanium crystals with various isotopic disorder degrees

  14. Implementation of thermoelectric module for cooling process of microscale experimental room

    Science.gov (United States)

    Gołebiowska, Justyna; Żelazna, Agnieszka; Zioło, Paweł

    2017-08-01

    Thermoelectric modules, also known as Peltier modules, are used for cooling small devices and also, according to literature, in refrigeration. They can be an alternative to conventional refrigeration systems based on the use of compressors chillers powered by AC power. Peltier modules are powered by direct current (DC), which allows to power them directly supply by photovoltaic modules. In this paper operation of thermoelectric module used for cooling experimental room of cubature 0.125 m3 is presented. The study involves investigation of temperatures achieved on the cold and hot sides of module and inside the experimental room depending on the values of module supplying current. These studies provide an introduction to the assessment of the influence of different methods of heat removal on the hot side of thermoelectric module on cooling efficiency of whole system.

  15. Process and device for cooling of nuclear reactor fuel elements enclosed in a transport container

    International Nuclear Information System (INIS)

    Stiefel, M.

    1986-01-01

    In order to remove the post-decay heat of the fuel elements contained in them, transport containers for burnt-up fuel elements can be connected to a water cooling circuit. In order to avoid thermal shocks, a tenside forming foam and air are introduced into the cooling circuit before its entry into the transport container in the direction of flow. The tenside and air continue to be supplied until the temperature inside the transport container has fallen below the temperature at which the foam is destroyed. By adding tenside and air, a two phase mixture is produced, which foams greatly when it enters the transport container and which cools the fuel elements so as to protect them.(orig./HP) [de

  16. Design of an integrated fermentation-crystallization process applied to the production of DOIP

    NARCIS (Netherlands)

    Blokker, S.; Dabkowski, M.; Groendijk, W.; Renckens, D.; De Rond, J.

    2004-01-01

    The design problem of CPD3312 was the comparison of the conventional batch (Base case) and the new integrated fermentation-crystallization process (In Situ Product Removal or ISPR case) in particular for the production of 2 tonnes 6R-dihydrooxoisophorone (DOIP) from 4-oxo-isophorone (OIP) per year.

  17. Use of process steam in vapor absorption refrigeration system for cooling and heating applications: An exergy analysis

    Directory of Open Access Journals (Sweden)

    S. Anand

    2016-12-01

    Full Text Available The exponential increase in cost of conventional fuels shifts the interest toward the use of alternative as well waste energy sources for the operation of refrigeration and air-conditioning units. The present study therefore analyzes the performance of a process steam-operated vapor absorption system for cooling and heating applications using ammonia and water as working fluids based on first and second laws of thermodynamics. A mathematical model has been developed based on exergy analysis to investigate the performance of the system. The different performance parameters such as coefficient of performance (COP and exergetic efficiency of absorption system for cooling and heating applications are also calculated under different operating conditions. The results obtained show that cooling and heating COP along with second law efficiency (exergy efficiency increases with the heat source temperature at constant evaporator, condenser, and absorber temperature. Also, COP as well as exergy efficiency increases with an increase in the evaporator temperature at constant generator, condenser, and absorber temperature. The effect of ambient temperature on the exergetic efficiency for cooling and heating applications is also studied. The results obtained from the simulation studies can be used to optimize different components of the system so that the performance can be improved significantly.

  18. Experimental study and process parameters analysis on the vacuum cooling of iceberg lettuce

    Energy Technology Data Exchange (ETDEWEB)

    He, Su-Yan [School of Mechanical and Electrical Engineering, Qingdao University, Qingdao 266071 (China); Li, Yun-Fei [Department of Food Science and Engineering, School of Agriculture and Biology, Shanghai Jiao Tong University (China)

    2008-10-15

    The vacuum cooling of iceberg lettuce was described in this paper. Based on the energy and mass balance, a mathematical model was developed to analyze the performance of the vacuum cooler and the evaporation-boiling phenomena during vacuum cooling of iceberg lettuce. The temporal trends of total system pressure, produce temperature such as surface temperature, center temperature, mass-average temperature, the weight loss of iceberg lettuce during vacuum cooling were predicted. Validation experimentation is achieved in the designed vacuum cooler. The experimental data were compared with the simulation results. It was found that the differences of the temperature between the simulation and the experiments were within 1{sup o}C. The amount of water evaporated from the iceberg lettuce by simulation was 3.32% during the whole vacuum cooling, while the tested water loss rate was 2.97%, the maximal deviation of weight loss was within 0.59%. The simulation results agreed well with the experimental data. (author)

  19. Exchange bias in (La,Ca)MnO3 bilayers: influence of cooling process

    International Nuclear Information System (INIS)

    Restrepo-Parra, E; Agudelo, J D; Restrepo, J

    2012-01-01

    The exchange bias (EB) phenomenon in La 2/3 Ca 1/3 MnO 3 /La 1/3 Ca 2/3 MnO 3 bilayers was studied using Monte Carlo simulations combined with the Heisenberg model and the Metropolis algorithm. These simulations were carried out using the model proposed by Kiwi for an uncompensated interface. The Hamiltonian considered several terms corresponding to the nearest neighbor interaction, magnetocrystalline anisotropy and Zeeman effect. Several interactions in the ferromagnetic (FM), antiferromagnetic (AFM) and FM/AFM interface were considered, depending on the type of interacting ion (Mn 3+eg , Mn 3+eg′ or Mn 4+d3 ). The influence of field cooling and cooling temperature on the EB was analyzed and discussed. Regarding the field cooling, it caused an increase in the EB until a certain critical value was reached. After that, its effect was almost negligible. On the other hand, at low values of cooling temperature, not only the EB but also the coercive field were enhanced. (paper)

  20. Engineering structure design and fabrication process of small sized China helium-cooled solid breeder test blanket module

    International Nuclear Information System (INIS)

    Wang Zeming; Chen Lu; Hu Gang

    2014-01-01

    Preliminary design and analysis for china helium-cooled solid breeder (CHHC-SB) test blanket module (TBM) have been carried out recently. As partial verification that the original size module was reasonable and the development process was feasible, fabrication work of a small sized module was to be carried out targetedly. In this paper, detailed design and structure analysis of small sized TBM was carried out based on preliminary design work, fabrication process and integrated assembly process was proposed, so a fabrication for the trial engineering of TBM was layed successfully. (authors)

  1. Determination of energy to be supplied by photovoltaic systems for fan-pad systems in cooling process of greenhouses

    International Nuclear Information System (INIS)

    Romantchik, Eugenio; Ríos, Eduardo; Sánchez, Elisa; López, Irineo; Sánchez, José Reyes

    2017-01-01

    Intending to increase the reliability of photovoltaic systems in agriculture sector, this work was developed to calculate the energy required by fan-pad systems for the cooling process in greenhouses. This calculation aims to ensure that the cooling process is completely sustainable. Today, there are no scientific tools to determine the electrical energy consumed by air exhaust fans. In order to address this problem, a mathematical model that predicts the greenhouse temperatures and ventilation rates, was calibrated with experimental data. The results correspond to a typical summer day with high solar radiation and showed that mathematical model can enhance the management of the energy for the cooling process. These results are: power of exhaust fans and their operating hours. It was used a methodology for selection of photovoltaic systems in order to design grid-connected configurations systems capable of producing, at least, the whole of the required energy by three greenhouses with different areas. It is concluded that the accuracy of the model is acceptable and with the methodology of selection of photovoltaic systems represent a reliable tool for calculus of electric power [W] and electric energy [kWh] consumed by the fans, which represent the main and initial design parameter of any type of photovoltaic system.

  2. Non-classical crystallization of thin films and nanostructures in CVD and PVD processes

    CERN Document Server

    Hwang, Nong Moon

    2016-01-01

    This book provides a comprehensive introduction to a recently-developed approach to the growth mechanism of thin films and nanostructures via chemical vapour deposition (CVD). Starting from the underlying principles of the low pressure synthesis of diamond films, it is shown that diamond growth occurs not by individual atoms but by charged nanoparticles. This newly-discovered growth mechanism turns out to be general to many CVD and some physical vapor deposition (PVD) processes. This non-classical crystallization is a new paradigm of crystal growth, with active research taking place on growth in solution, especially in biomineralization processes. Established understanding of the growth of thin films and nanostructures is based around processes involving individual atoms or molecules. According to the author’s research over the last two decades, however, the generation of charged gas phase nuclei is shown to be the rule rather than the exception in the CVD process, and charged gas phase nuclei are actively ...

  3. Kinetic studies on the degradation of crystal violet by the Fenton oxidation process.

    Science.gov (United States)

    Wu, H; Fan, M M; Li, C F; Peng, M; Sheng, L J; Pan, Q; Song, G W

    2010-01-01

    The degradation of dye crystal violet (CV) by Fenton oxidation process was investigated. The UV-Vis spectrogram has shown that CV can be degraded effectively by Fenton oxidation process. Different system variables namely initial H(2)O(2) concentration, initial Fe(2 + ) concentration and reaction temperature, which have effect on the degradation of CV by Fenton oxidation process, have been studied systematically. The degradation kinetics of CV was also elucidated based on the experimental data. The degradation of CV obeys the first-order reaction kinetics. The kinetic model can be described as k=1.5 exp(-(7.5)/(RT))[H(2)O(2)](0)(0.8718)[Fe(2+)](0)(0.5062). According to the IR spectrogram, it is concluded that the benzene ring of crystal violet has been destroyed by Fenton oxidation. The result will be useful in treating dyeing wastewater containing CV by Fenton oxidation process.

  4. Restaurant Food Cooling Practices†

    Science.gov (United States)

    BROWN, LAURA GREEN; RIPLEY, DANNY; BLADE, HENRY; REIMANN, DAVE; EVERSTINE, KAREN; NICHOLAS, DAVE; EGAN, JESSICA; KOKTAVY, NICOLE; QUILLIAM, DANIELA N.

    2017-01-01

    Improper food cooling practices are a significant cause of foodborne illness, yet little is known about restaurant food cooling practices. This study was conducted to examine food cooling practices in restaurants. Specifically, the study assesses the frequency with which restaurants meet U.S. Food and Drug Administration (FDA) recommendations aimed at reducing pathogen proliferation during food cooling. Members of the Centers for Disease Control and Prevention’s Environmental Health Specialists Network collected data on food cooling practices in 420 restaurants. The data collected indicate that many restaurants are not meeting FDA recommendations concerning cooling. Although most restaurant kitchen managers report that they have formal cooling processes (86%) and provide training to food workers on proper cooling (91%), many managers said that they do not have tested and verified cooling processes (39%), do not monitor time or temperature during cooling processes (41%), or do not calibrate thermometers used for monitoring temperatures (15%). Indeed, 86% of managers reported cooling processes that did not incorporate all FDA-recommended components. Additionally, restaurants do not always follow recommendations concerning specific cooling methods, such as refrigerating cooling food at shallow depths, ventilating cooling food, providing open-air space around the tops and sides of cooling food containers, and refraining from stacking cooling food containers on top of each other. Data from this study could be used by food safety programs and the restaurant industry to target training and intervention efforts concerning cooling practices. These efforts should focus on the most frequent poor cooling practices, as identified by this study. PMID:23212014

  5. Simulation of thermal processes in superconducting pancake coils cooled by GM cryocooler

    International Nuclear Information System (INIS)

    Lebioda, M; Rymaszewski, J; Korzeniewska, E

    2014-01-01

    This article presents the thermal model of a small scale superconducting magnetic energy storage system with the closed cycle helium cryocooler. The authors propose the use of contact-cooled coils with maintaining the possibility of the system reconfiguring. The model assumes the use of the second generation superconducting tapes to make the windings in the form of flat discs (pancakes). The paper presents results for a field model of the single pancake coil and the winding system consisting of several coils.

  6. Preventing Crystal Agglomeration of Pharmaceutical Crystals Using Temperature Cycling and a Novel Membrane Crystallization Procedure for Seed Crystal Generation

    Directory of Open Access Journals (Sweden)

    Elena Simone

    2018-01-01

    Full Text Available In this work, a novel membrane crystallization system was used to crystallize micro-sized seeds of piroxicam monohydrate by reverse antisolvent addition. Membrane crystallization seeds were compared with seeds produced by conventional antisolvent addition and polymorphic transformation of a fine powdered sample of piroxicam form I in water. The membrane crystallization process allowed for a consistent production of pure monohydrate crystals with narrow size distribution and without significant agglomeration. The seeds were grown in 350 g of 20:80 w/w acetone-water mixture. Different seeding loads were tested and temperature cycling was applied in order to avoid agglomeration of the growing crystals during the process. Focused beam reflectance measurement (FBRM; and particle vision and measurement (PVM were used to monitor crystal growth; nucleation and agglomeration during the seeded experiments. Furthermore; Raman spectroscopy was used to monitor solute concentration and estimate the overall yield of the process. Membrane crystallization was proved to be the most convenient and consistent method to produce seeds of highly agglomerating compounds; which can be grown via cooling crystallization and temperature cycling.

  7. Analysis of mercerization process based on the intensity change of deconvoluted resonances of {sup 13}C CP/MAS NMR: Cellulose mercerized under cooling and non-cooling conditions

    Energy Technology Data Exchange (ETDEWEB)

    Miura, Kento [Mitsubishi Rayon Co., Ltd. Otake Research Laboratories (Japan); Nakano, Takato, E-mail: tnakano@kais.kyoto-u.ac.jp [Laboratory of Biomaterials Design, Division of Forest and Biomaterials Science, Graduate School of Agriculture, Kyoto University (Japan)

    2015-08-01

    The area intensity change of C1, C4, and C6 in spectrum obtained by {sup 13}C CP/MAS NMR and the mutual relationship between their changes were examined for cellulose samples treated with various concentrations of aqueous NaOH solutions under non-cooling and cooling conditions. The area intensity of C1-up and C6-down changed cooperatively with that of C4-down which corresponds to the crystallinity of samples: “-up” and “-down” are the up- and down- field component in a splitting peak of NMR spectrum, respectively. The intensity change of C1-up starts to decrease with decreasing in that of C4-down after that of C6-down is almost complete. These changes were more clearly observed for samples treated under cooling condition. It can be suggested that their characteristic change relates closely to the change in conformation of cellulose chains by induced decrystallization and the subsequent crystallization of cellulose II, and presumed that their changes at microscopic level relate to the macroscopic morphological changes such as contraction along the length of cellulose chains and recovery along the length. - Highlight: • Samples were mercerized at various NaOH concentrations under non-cooling and cooling. • The intensity change of C1 starts immediately after that of C6 is complete. • The creation of cell-II starts when decrystallization proceeds to a certain state. • This change relates closely to the change in conformation of cellulose chains. • The above change is more clearly found for samples treated under cooling.

  8. A novel methodology to model the cooling processes of packed horticultural produce using 3D shape models

    Science.gov (United States)

    Gruyters, Willem; Verboven, Pieter; Rogge, Seppe; Vanmaercke, Simon; Ramon, Herman; Nicolai, Bart

    2017-10-01

    Freshly harvested horticultural produce require a proper temperature management to maintain their high economic value. Towards this end, low temperature storage is of crucial importance to maintain a high product quality. Optimizing both the package design of packed produce and the different steps in the postharvest cold chain can be achieved by numerical modelling of the relevant transport phenomena. This work presents a novel methodology to accurately model both the random filling of produce in a package and the subsequent cooling process. First, a cultivar-specific database of more than 100 realistic CAD models of apple and pear fruit is built with a validated geometrical 3D shape model generator. To have an accurate representation of a realistic picking season, the model generator also takes into account the biological variability of the produce shape. Next, a discrete element model (DEM) randomly chooses surface meshed bodies from the database to simulate the gravitational filling process of produce in a box or bin, using actual mechanical properties of the fruit. A computational fluid dynamics (CFD) model is then developed with the final stacking arrangement of the produce to study the cooling efficiency of packages under several conditions and configurations. Here, a typical precooling operation is simulated to demonstrate the large differences between using actual 3D shapes of the fruit and an equivalent spheres approach that simplifies the problem drastically. From this study, it is concluded that using a simplified representation of the actual fruit shape may lead to a severe overestimation of the cooling behaviour.

  9. Microstructure and Mechanical Properties of J55ERW Steel Pipe Processed by On-Line Spray Water Cooling

    Directory of Open Access Journals (Sweden)

    Zejun Chen

    2017-04-01

    Full Text Available An on-line spray water cooling (OSWC process for manufacturing electric resistance welded (ERW steel pipes is presented to enhance their mechanical properties and performances. This technique reduces the processing needed for the ERW pipe and overcomes the weakness of the conventional manufacturing technique. Industrial tests for J55 ERW steel pipe were carried out to validate the effectiveness of the OSWC process. The microstructure and mechanical properties of the J55 ERW steel pipe processed by the OSWC technology were investigated. The optimized OSWC technical parameters are presented based on the mechanical properties and impact the performance of steel pipes. The industrial tests show that the OSWC process can be used to efficiently control the microstructure, enhance mechanical properties, and improve production flexibility of steel pipes. The comprehensive mechanical properties of steel pipes processed by the OSWC are superior to those of other published J55 grade steels.

  10. Economic analysis of wind-powered refrigeration cooling/water-heating systems in food processing. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Garling, W.S.; Harper, M.R.; Merchant-Geuder, L.; Welch, M.

    1980-03-01

    Potential applications of wind energy include not only large central turbines that can be utilized by utilities, but also dispersed systems for farms and other applications. The US Departments of Energy (DOE) and Agriculture (USDA) currently are establishing the feasibility of wind energy use in applications where the energy can be used as available, or stored in a simple form. These applications include production of hot water for rural sanitation, heating and cooling of rural structures and products, drying agricultural products, and irrigation. This study, funded by USDA, analyzed the economic feasibility of wind power in refrigeration cooling and water heating systems in food processing plants. Types of plants included were meat and poultry, dairy, fruit and vegetable, and aquaculture.

  11. Modeling of the Cutting Forces in Turning Process Using Various Methods of Cooling and Lubricating: An Artificial Intelligence Approach

    Directory of Open Access Journals (Sweden)

    Djordje Cica

    2013-01-01

    Full Text Available Cutting forces are one of the inherent phenomena and a very significant indicator of the metal cutting process. The work presented in this paper is an investigation of the prediction of these parameters in turning using soft computing techniques. During the experimental research focus is placed on the application of various methods of cooling and lubricating of the cutting zone. On this occasion were used the conventional method of cooling and lubricating, high pressure jet assisted machining, and minimal quantity lubrication technique. The data obtained by experiment are used to create two different models, namely, artificial neural network and adaptive networks based fuzzy inference systems for prediction of cutting forces. Furthermore, both models are compared with the experimental data and results are indicated.

  12. Cooling techniques

    International Nuclear Information System (INIS)

    Moeller, S.P.

    1994-01-01

    After an introduction to the general concepts of cooling of charged particle beams, some specific cooling methods are discussed, namely stochastic, electron and laser cooling. The treatment concentrates on the physical ideas of the cooling methods and only very crude derivations of cooling times are given. At the end three other proposed cooling schemes are briefly discussed. (orig.)

  13. Applying the sequential neural-network approximation and orthogonal array algorithm to optimize the axial-flow cooling system for rapid thermal processes

    International Nuclear Information System (INIS)

    Hung, Shih-Yu; Shen, Ming-Ho; Chang, Ying-Pin

    2009-01-01

    The sequential neural-network approximation and orthogonal array (SNAOA) were used to shorten the cooling time for the rapid cooling process such that the normalized maximum resolved stress in silicon wafer was always below one in this study. An orthogonal array was first conducted to obtain the initial solution set. The initial solution set was treated as the initial training sample. Next, a back-propagation sequential neural network was trained to simulate the feasible domain to obtain the optimal parameter setting. The size of the training sample was greatly reduced due to the use of the orthogonal array. In addition, a restart strategy was also incorporated into the SNAOA so that the searching process may have a better opportunity to reach a near global optimum. In this work, we considered three different cooling control schemes during the rapid thermal process: (1) downward axial gas flow cooling scheme; (2) upward axial gas flow cooling scheme; (3) dual axial gas flow cooling scheme. Based on the maximum shear stress failure criterion, the other control factors such as flow rate, inlet diameter, outlet width, chamber height and chamber diameter were also examined with respect to cooling time. The results showed that the cooling time could be significantly reduced using the SNAOA approach

  14. Effect of power history on the shape and the thermal stress of a large sapphire crystal during the Kyropoulos process

    Science.gov (United States)

    Nguyen, Tran Phu; Chuang, Hsiao-Tsun; Chen, Jyh-Chen; Hu, Chieh

    2018-02-01

    In this study, the effect of the power history on the shape of a sapphire crystal and the thermal stress during the Kyropoulos process are numerically investigated. The simulation results show that the thermal stress is strongly dependent on the power history. The thermal stress distributions in the crystal for all growth stages produced with different power histories are also studied. The results show that high von Mises stress regions are found close to the seed of the crystal, the highly curved crystal surface and the crystal-melt interface. The maximum thermal stress, which occurs at the crystal-melt interface, increases significantly in value as the crystal expands at the crown. After this, there is reduction in the maximum thermal stress as the crystal lengthens. There is a remarkable enhancement in the maximum von Mises stress when the crystal-melt interface is close to the bottom of the crucible. There are two obvious peaks in the maximum Von Mises stress, at the end of the crown stage and in the final stage, when cracking defects can form. To alleviate this problem, different power histories are considered in order to optimize the process to produce the lowest thermal stress in the crystal. The optimal power history is found to produce a significant reduction in the thermal stress in the crown stage.

  15. Investigation of the crystallization process of titanium alloy ingots produced by vacuum arc melting method

    International Nuclear Information System (INIS)

    Tetyukhin, V.V.; Kurapov, V.N.; Trubin, A.N.; Demchenko, M.V.; Lazarev, V.G.; Ponedilko, S.V.; Dubrovina, N.T.; Kurapova, L.A.

    1978-01-01

    The process of crystallization and hardening of the VT3-1 and VT9 titanium alloys ingots during the vacuum-arc remelting (VAR) has been studied. In order to investigate the kinetics of the hole shape changing and the peculiarities of the ingot formation during the VAR, the radiography method has been used. It is established that the VAR of the titanium alloy ingots is basically a continuous process. An intense heating of the liquid bath mirror and the availability of high temperature gradients in the hole are the typical features of the VAR process

  16. Relap5 Analysis of Processes in Reactor Cooling Circuit and Reactor Cavity in Case of Station Blackout in RBMK-1500

    International Nuclear Information System (INIS)

    Kaliatka, A.

    2007-01-01

    Ignalina NPP is equipped with channel-type boiling-water graphite-moderated reactor RBMK-1500. Results of the level-1 probabilistic safety assessment of the Ignalina NPP have shown that in topography of the risk, the transients with failure of long-term core cooling other than LOCA are the main contributors to the core damage frequency. The total loss of off-site power with a failure to start any diesel generator, that is station blackout, is the event which could lead to the loss of long-term core cooling. Such accident could lead to multiple ruptures of fuel channels with severe consequences and should be analyzed in order to estimate the timing of the key events and the possibilities for accident management. This paper presents the results of the analysis of station blackout at Ignalina NPP. Analysis was performed using thermal-hydraulic state-of-the-art RELAP5/MOD3.2 code. The response of reactor cooling system and the processes in the reactor cavity and its venting system in case of a few fuel-channel ruptures due to overheating were demonstrated. The possible measures for prevention of the development of this beyond design basis accident (BDBA) to a severe accident are discussed

  17. Visualization of nanosecond laser-induced dewetting, ablation and crystallization processes in thin silicon films

    Science.gov (United States)

    Qi, Dongfeng; Zhang, Zifeng; Yu, Xiaohan; Zhang, Yawen

    2018-06-01

    In the present work, nanosecond pulsed laser crystallization, dewetting and ablation of thin amorphous silicon films are investigated by time-resolved imaging. Laser pulses of 532 nm wavelength and 7 ns temporal width are irradiated on silicon film. Below the dewetting threshold, crystallization process happens after 400 ns laser irradiation in the spot central region. With the increasing of laser fluence, it is observed that the dewetting process does not conclude until 300 ns after the laser irradiation, forming droplet-like particles in the spot central region. At higher laser intensities, ablative material removal occurs in the spot center. Cylindrical rims are formed in the peripheral dewetting zone due to solidification of transported matter at about 500 ns following the laser pulse exposure.

  18. The microstructural changes of Ge2Sb2Te5 thin film during crystallization process

    Science.gov (United States)

    Xu, Jingbo; Qi, Chao; Chen, Limin; Zheng, Long; Xie, Qiyun

    2018-05-01

    Phase change memory is known as the most promising candidate for the next generation nonvolatile memory technology. In this paper, the microstructural changes of Ge2Sb2Te5 film, which is the most common choice of phase change memory material, has been carefully studied by the combination of several characterization techniques. The combination of resistance measurements, X-ray diffraction, Raman spectroscopy and X-ray reflectivity allows us to simultaneously extract the characteristics of microstructural changes during crystallization process. The existence of surface/interface Ge2Sb2Te5 layer has been proposed here based on X-ray reflectivity measurements. Although the total film thickness decreases, as a result of the phase transition from amorphous to metastable crystalline cubic and then to the stable hexagonal phase, the surface/interface thickness increases after crystallization. Moreover, the increase of average grain size, density and surface roughness has been confirmed during thermal annealing process.

  19. Characteristics of indomethacin-saccharin (IMC-SAC) co-crystals prepared by an anti-solvent crystallization process.

    Science.gov (United States)

    Chun, Nan-Hee; Wang, In-Chun; Lee, Min-Jeong; Jung, Yun-Taek; Lee, Sangkil; Kim, Woo-Sik; Choi, Guang J

    2013-11-01

    The creation of co-crystals of various insoluble drug substances has been extensively investigated as a promising approach to improve their pharmaceutical performance. In this study, co-crystal powders of indomethacin and saccharin (IMC-SAC) were prepared by an anti-solvent (water) addition and compared with co-crystals by evaporation method. No successful synthesis of a pharmaceutical co-crystal powder via an anti-solvent approach has been reported. Among solvents examined, methanol was practically the only one that resulted in the formation of highly pure IMC-SAC co-crystal powders by anti-solvent approach. The mechanism of a preferential formation of IMC-SAC co-crystal to IMC was explained with two aspects: phase solubility diagram and solution complexation concept. Accordingly, the anti-solvent approach can be considered as a competitive route for producing pharmaceutical co-crystal powders with acceptable properties. Copyright © 2013 Elsevier B.V. All rights reserved.

  20. Crystallization Process of Protein Rv0731c from Mycobacterium Tuberculosis for a Successful Atomic Resolution Crystal Structure at 1.2 Angstrom

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Liang Cong

    2009-06-08

    Proteins are bio-macromolecules consisting of basic 20 amino acids and have distinct three-dimensional folds. They are essential parts of organisms and participate in every process within cells. Proteins are crucial for human life, and each protein within the body has a specific function, such as antibodies, contractile proteins, enzymes, hormonal proteins, structural proteins, storage proteins and transport proteins. Determining three-dimensional structure of a protein can help researchers discover the remarkable protein folding, binding site, conformation and etc, in order to understand well of protein interaction and aid for possible drug design. The research on protein structure by X-ray protein crystallography carried by Li-Wei Hung's research group in the Physical Bioscience Division at Lawrence Berkeley National Laboratory (LBNL) is focusing on protein crystallography. The research in this lab is in the process of from crystallizing the proteins to determining the three dimensional crystal structures of proteins. Most protein targets are selected from Mycobacterium Tuberculosis. TB (Tuberculosis) is a possible fatal infectious disease. By studying TB target protein can help discover antituberculer drugs, and find treatment for TB. The high-throughput mode of crystallization, crystal harvesting, crystal screening and data collection are applied to the research pipeline (Figure 1). The X-ray diffraction data by protein crystals can be processed and analyzed to result in a three dimensional representation of electron density, producing a detailed model of protein structure. Rv0731c is a conserved hypothetical protein with unknown function from Mycobacterium Tuberculosis. This paper is going to report the crystallization process and brief structure information of Rv0731c.

  1. Lecithin hydrophobicity modulates the process of cholesterol crystal nucleation and growth in supersaturated model bile systems.

    OpenAIRE

    Ochi, H; Tazuma, S; Kajiyama, G

    1996-01-01

    The present study was performed to determine whether the degree of lecithin hydrophobicity regulates bile metastability and, therefore, affects the process of cholesterol crystallization. Supersaturated model bile (MB) solutions were prepared with an identical composition on a molar basis (taurocholate/lecithin/cholesterol, 73:19.5:7.5; total lipid concentration 9 g/dl) except for the lecithin species; egg yolk phosphatidylcholine, soybean phosphatidylcholine, 1-palmitoyl-2-linoleoyl-sn-phosp...

  2. Cooling off with physics

    Energy Technology Data Exchange (ETDEWEB)

    Clarke, Chris [Unilever R and D (United Kingdom)

    2003-08-01

    You might think of ice cream as a delicious treat to be enjoyed on a sunny summer's day. However, to the ice-cream scientists who recently gathered in Thessaloniki in Greece for the 2nd International Ice Cream Symposium, it is a complex composite material. Ice cream consists of three dispersed phases: ice crystals, which have a mean size of 50 microns, air bubbles with a diameter of about 70 microns, and fat droplets with a size of 1 micron. These phases are held together by what is called the matrix - not a sci-fi film, but a viscous solution of sugars, milk proteins and polysaccharides. The microstructure, and hence the texture that you experience when you eat ice cream, is created in a freezing process that has remained fundamentally unchanged since the first ice-cream maker was patented in the 1840s. The ingredients - water, milk protein, fat, sugar, emulsifiers, stabilizers, flavours and a lot of air - are mixed together before being pasteurized and homogenized. They are then pumped into a cylinder that is cooled from the outside with a refrigerant. As the mixture touches the cylinder wall it freezes and forms ice crystals, which are quickly scraped off by a rotating blade. The blade is attached to a beater that disperses the ice crystals into the mixture. At the same time, air is injected and broken down into small bubbles by the shear that the beater generates. As the mixture passes along the cylinder, the number of ice crystals increases and its temperature drops. As a result, the viscosity of the mixture increases, so that more energy input is needed to rotate the beater. This energy is dissipated as heat, and when the ice cream reaches about -6 deg. C the energy input through the beater equals the energy removed as heat by the refrigerant. The process therefore becomes self-limiting and it is not possible to cool the ice cream any further. However, at -6 deg. C the microstructure is unstable. The ice cream therefore has to be removed from the freezer

  3. Quality improvement of CdZnTe single crystal by ultrasound processing

    Science.gov (United States)

    Lisiansky, M.; Berner, A.; Korchnoy, V.

    2017-06-01

    Intrinsic defects and contaminations removal from the undoped p-type Cd0.96Zn0.04Te single crystals has been achieved by the ultrasound vibration processing at the room temperature. Surface analysis based on Auger Electron Spectroscopy, Energy Dispersive Spectroscopy, and Scanning Electron Spectroscopy shows a significant reconstruction of the crystal surface after processing, namely, the appearance of numerous "volcano craters" and triangle-shaped defects with a typical size of 0.2-5.0 μm. Elemental analysis of these defects shows that they are Te inclusions emerged on the surface. The regular crystal surface outside the defects also displays a considerable enrichment by Te. Distinct presence of copper is found in both the thin surface layer and in the defects emerged on the surface. The surface reconstruction is associated with a remarkable change in the bulk material properties, electrical (an increase in the resistivity by a factor of ∼6) and optical (an IR transmittance increase). A post-polishing following the ultrasound processing makes the CdZnTe material more stable and reliable for a wide range of device applications.

  4. Effect of hydrothermal process for inorganic alumina sol on crystal structure of alumina gel

    Directory of Open Access Journals (Sweden)

    K. Yamamura

    2016-09-01

    Full Text Available This paper reports the effect of a hydrothermal process for alumina sol on the crystal structure of alumina gel derived from hydrothermally treated alumina sol to help push forward the development of low temperature synthesis of α-Al2O3. White precipitate of aluminum hydroxide was prepared with a homogeneous precipitation method using aluminum nitrate and urea in aqueous solution. The obtained aluminum hydroxide precipitate was peptized by using acetic acid at room temperature, which resulted in the production of a transparent alumina sol. The alumina sol was treated with a hydrothermal process and transformed into an alumina gel film by drying at room temperature. Crystallization of the alumina gel to α-Al2O3 with 900 °C annealing was dominant for a hydrothermal temperature of 100 °C and a hydrothermal time of 60 min, as production of diaspore-like species was promoted with the hydrothermal temperature and time. Excess treatments with hydrothermal processes at higher hydrothermal temperature for longer hydrothermal time prevented the alumina gel from being crystallized to α-Al2O3 because the excess hydrothermal treatments promoted production of boehmite.

  5. Effects of deep cryogenic treatment on the solid-state phase transformation of Cu-Al alloy in cooling process

    Science.gov (United States)

    Wang, Yuhui; Liao, Bo; Liu, Jianhua; Chen, Shuqing; Feng, Yu; Zhang, Yanyan; Zhang, Ruijun

    2012-07-01

    The solid-state phase transformation temperature and duration of deep cryogenic treated and untreated Cu-Al alloys in cooling process were measured by differential scanning calorimetry measurement. The solid-state phase transformation activation energy and Avrami exponent were calculated according to these measurements. The effects of deep cryogenic treatment on the solid-state phase transformation were investigated based on the measurement and calculation as well as the observation of alloy's microstructure. The results show that deep cryogenic treatment can increase the solid-phase transformation activation energy and shorten the phase transformation duration, which is helpful to the formation of fine grains in Cu-Al alloy.

  6. Scaling analysis of the coupled heat transfer process in the high-temperature gas-cooled reactor core

    International Nuclear Information System (INIS)

    Conklin, J.C.

    1986-08-01

    The differential equations representing the coupled heat transfer from the solid nuclear core components to the helium in the coolant channels are scaled in terms of representative quantities. This scaling process identifies the relative importance of the various terms of the coupled differential equations. The relative importance of these terms is then used to simplify the numerical solution of the coupled heat transfer for two bounding cases of full-power operation and depressurization from full-system operating pressure for the Fort St. Vrain High-Temperature Gas-Cooled Reactor. This analysis rigorously justifies the simplified system of equations used in the nuclear safety analysis effort at Oak Ridge National Laboratory

  7. Effect of the electronic structure of the etched CdTe single crystals on the exciton radiation processes

    International Nuclear Information System (INIS)

    Tkachuk, P.M.; Tkachuk, V.Yi.; Mel'nichuk, S.V.; Kurik, M.V.

    2005-01-01

    Under optical excitation the structure of the radiation beyond fundamental absorption of the orientated CdTe single crystals caused by LO-phonon scattering processes of the electron-hole states is observed. Crystals have been doped with impurity of Cl as a result of the surface preparing by etching in Br-methanol. Electronic structure of the single crystals surface layer is identified on the basis of two-phonon radiation absorption investigation. Taking into account the modes selection rules the one and two phonon scattering mechanisms for two crystals surface orientations are determined

  8. Fluoride-Salt-Cooled High-Temperature Reactor (FHR) for Power and Process Heat

    Energy Technology Data Exchange (ETDEWEB)

    Forsberg, Charles [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Hu, Lin-wen [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Peterson, Per [Univ. of California, Berkeley, CA (United States); Sridharan, Kumar [Univ. of Wisconsin, Madison, WI (United States)

    2015-01-21

    In 2011 the U.S. Department of Energy through its Nuclear Energy University Program (NEUP) awarded a 3- year integrated research project (IRP) to the Massachusetts Institute of Technology (MIT) and its partners at the University of California at Berkeley (UCB) and the University of Wisconsin at Madison (UW). The IRP included Westinghouse Electric Company and an advisory panel chaired by Regis Matzie that provided advice as the project progressed. The first sentence of the proposal stated the goals: The objective of this Integrated Research Project (IRP) is to develop a path forward to a commercially viable salt-cooled solid-fuel high-temperature reactor with superior economic, safety, waste, nonproliferation, and physical security characteristics compared to light-water reactors. This report summarizes major results of this research.

  9. Fluoride-Salt-Cooled High-Temperature Reactor (FHR) for Power and Process Heat

    International Nuclear Information System (INIS)

    Forsberg, Charles; Hu, Lin-wen; Peterson, Per; Sridharan, Kumar

    2015-01-01

    In 2011 the U.S. Department of Energy through its Nuclear Energy University Program (NEUP) awarded a 3- year integrated research project (IRP) to the Massachusetts Institute of Technology (MIT) and its partners at the University of California at Berkeley (UCB) and the University of Wisconsin at Madison (UW). The IRP included Westinghouse Electric Company and an advisory panel chaired by Regis Matzie that provided advice as the project progressed. The first sentence of the proposal stated the goals: The objective of this Integrated Research Project (IRP) is to develop a path forward to a commercially viable salt-cooled solid-fuel high-temperature reactor with superior economic, safety, waste, nonproliferation, and physical security characteristics compared to light-water reactors. This report summarizes major results of this research.

  10. Development of intergranular thermal residual stresses in beryllium during cooling from processing temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Brown, D.W. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)], E-mail: dbrown@lanl.gov; Sisneros, T.A.; Clausen, B.; Abeln, S.; Bourke, M.A.M.; Smith, B.G.; Steinzig, M.L.; Tome, C.N.; Vogel, S.C. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    2009-02-15

    The intergranular thermal residual stresses in texture-free solid polycrystalline beryllium were determined by comparison of crystallographic lattice parameters in solid and powder samples measured by neutron diffraction during cooling from 800 deg. C. The internal stresses are not significantly different from zero >575 deg. C and increase nearly linearly <525 deg. C. At room temperature, the c axis of an average grain is under {approx}200 MPa of compressive internal stress, and the a axis is under 100 MPa of tensile stress. For comparison, the stresses have also been calculated using an Eshelby-type polycrystalline model. The measurements and calculations agree very well when temperature dependence of elastic constants is accounted for, and no plastic relaxation is allowed in the model.

  11. Data processing for elliptical crystal spectrometer used in Z-pinch diagnostic

    International Nuclear Information System (INIS)

    Li Jing; Xie Weiping; Huang Xianbin; Yang Libing; Cai Hongchun; Xiao Shali

    2010-01-01

    Elliptical crystal spectrometers are key instruments to detect the line spectra of soft X-rays in Z-pinch diagnostics. This paper deals with the data processing for an elliptical crystal spectrometer. Taking the diagnostic results obtained in a neon gas-puff Z-pinch experiment as an example, the detailed processes, such as changing the optical density to X-ray intensity according a calibrated film response curve, determining the X-ray energy of the measured spectrum using the energy and the order number of scanned point of identified spectral lines, and correcting the intensity of spectrum using the formula given by Henke are discussed. In the Henke's formula, the effect of nonuniform dispersion, integrated reflectivity of crystals and transmission of X-ray filters are considered. The final unfolding results are presented, including the relative intensities of several neon K-shell lines (H α , He α and He β , etc.) given by Lorentz fitting. The relative errors of the spectral intensities are also briefly discussed. (authors)

  12. Reconfigurable Photonic Crystals Enabled by Multistimuli-Responsive Shape Memory Polymers Possessing Room Temperature Shape Processability.

    Science.gov (United States)

    Fang, Yin; Leo, Sin-Yen; Ni, Yongliang; Wang, Junyu; Wang, Bingchen; Yu, Long; Dong, Zhe; Dai, Yuqiong; Basile, Vito; Taylor, Curtis; Jiang, Peng

    2017-02-15

    Traditional shape memory polymers (SMPs) are mostly thermoresponsive, and their applications in nano-optics are hindered by heat-demanding programming and recovery processes. By integrating a polyurethane-based shape memory copolymer with templating nanofabrication, reconfigurable/rewritable macroporous photonic crystals have been demonstrated. This SMP coupled with the unique macroporous structure enables unusual all-room-temperature shape memory cycles. "Cold" programming involving microscopic order-disorder transitions of the templated macropores is achieved by mechanically deforming the macroporous SMP membranes. The rapid recovery of the permanent, highly ordered photonic crystal structure from the temporary, disordered configuration can be triggered by multiple stimuli including a large variety of vapors and solvents, heat, and microwave radiation. Importantly, the striking chromogenic effects associated with these athermal and thermal processes render a sensitive and noninvasive optical methodology for quantitatively characterizing the intriguing nanoscopic shape memory effects. Some critical parameters/mechanisms that could significantly affect the final performance of SMP-based reconfigurable photonic crystals including strain recovery ratio, dynamics and reversibility of shape recovery, as well as capillary condensation of vapors in macropores, which play a crucial role in vapor-triggered recovery, can be evaluated using this new optical technology.

  13. Magnetization Reversal Process of Single Crystal α-Fe Containing a Nonmagnetic Particle

    International Nuclear Information System (INIS)

    Li Yi; Xu Ben; Li Qiu-Lin; Liu Wei; Hu Shen-Yang; Li Yu-Lan

    2015-01-01

    The magnetization reversal process and hysteresis loops in a single crystal α-iron with nonmagnetic particles are simulated in this work based on the Landau—Lifshitz—Gilbert equation. The evolutions of the magnetic domain morphology are studied, and our analyses show that the magnetization reversal process is affected by the interaction between the moving domain wall and the existing nonmagnetic particles. This interaction strongly depends on the size of the particles, and it is found that particles with a particular size contribute the most to magnetic hardening. (paper)

  14. The effects on the microbiological condition of product of carcass dressing, cooling, and portioning processes at a poultry packing plant.

    Science.gov (United States)

    Gill, C O; Moza, L F; Badoni, M; Barbut, S

    2006-07-15

    The log mean numbers of aerobes, coliforms, Escherichia coli and presumptive staphylococci plus listerias on chicken carcasses and carcass portions at various stages of processing at a poultry packing plant were estimated from the numbers of those bacteria recovered from groups of 25 randomly selected product units. The fractions of listerias in the presumptive staphylococci plus listerias groups of organisms were also estimated. Samples were obtained from carcasses by excising a strip of skin measuring approximately 5 x 2 cm(2) from a randomly selected site on each selected carcass, or by rinsing each selected carcass portion. The log mean numbers of aerobes, coliforms, E. coli and presumptive staphylococci plus listerias on carcasses after scalding at 58 degrees C and plucking were about 4.4, 2.5, 2.2 and 1.4 log cfu/cm(2), respectively. The numbers of bacteria on eviscerated carcasses were similar. After the series of operations for removing the crop, lungs, kidneys and neck, the numbers of aerobes were about 1 log unit less than on eviscerated carcasses, but the numbers of the other bacteria were not substantially reduced. After cooling in water, the numbers of coliforms and E. coli were about 1 log unit less and the numbers of presumptive staphylococci plus listerias were about 0.5 log unit less than the numbers on dressed carcasses, but the numbers of aerobes were not reduced. The numbers of aerobes were 1 log unit more on boneless breasts, and 0.5 log units more on skin-on thighs and breasts that had been tumbled with brine than on cooled carcasses; and presumptive staphylococci plus listerias were 0.5 log unit more on thighs than on cooled carcasses. Otherwise the numbers of bacteria on the product were not substantially affected by processing. Listerias were 40% of the organisms were listerias.

  15. Investigations on the photographic elementary process in AgCl single crystal foils

    International Nuclear Information System (INIS)

    Schmidt, H.; Haase, G.; Zoergiebel, F.

    1977-01-01

    The behaviour of the latent image produced by actinic radiation (lambda = 365 nm and lambda = 407 nm) in AgCl monocrystal foils highly doped with Cd and grown and annealed under various conditions was studied by extinction measurements in the near infrared. The photographic elementary process in these highly doped crystals cannot be described satisfactorily by the classical Gurney Mott model. Therefore another model was used based on the creation of anion vacancies and molecular chlorine complexes. The radiation-induced electrons occupy these anion vacancies, and quasimetallic centres are formed. By this model the behaviour of the light-induced latent image can also be described as the nuclear particle track formation in the Cd doped AgCl crystals. (author)

  16. Investigations on the photographic elementary process in AgCl single crystal foils

    International Nuclear Information System (INIS)

    Schmidt, H.; Haase, G.; Zoergiebel, F.

    1976-01-01

    The behaviour of the latent image produced by actinic radiation (lambda = 365 mn and lambda = 407 nm) in AgCl-monocrystal foils highly doped with Cd and grown and annealed under various conditions was studied by extinction measurements in the near infrared. The photographic elementary process in these highly doped crystals cannot be described satisfactorily by the classical Gurney Mott model. Therefore another model was used based on the creation of anion vacancies and molecular chlorine complexes. The radiation induced electrons occupy these anion vacancies, and quasimetallic centers are formed. By this model the behaviour of the light induced latent image can as well be described as the nuclear particle track formation in the Cd doped AgCl-crystals. (orig.) [de

  17. Heat and mass transfer in semiconductor melts during single-crystal growth processes

    Science.gov (United States)

    Kakimoto, Koichi

    1995-03-01

    The quality of large semiconductor crystals grown from melts is significantly affected by the heat and mass transfer in the melts. The current understanding of the phenomena, especially melt convection, is reviewed starting from the results of visualization using model fluids or silicon melt, and continuing to the detailed numerical calculations needed for quantitative modeling of processing with solidification. The characteristics of silicon flows are also reviewed by focusing on the Coriolis force in the rotating melt. Descriptions of flow instabilities are included that show the level of understanding of melt convection with a low Prandtl number. Based on hydrodynamics, the origin of the silicon flow structure is reviewed, and it is discussed whether silicon flow is completely turbulent or has an ordered structure. The phase transition from axisymmetric to nonaxisymmetric flow is discussed using different geometries. Additionally, surface-tension-driven flow is reviewed for Czochralski crystal growth systems.

  18. ZnO crystals obtained by electrodeposition: Statistical analysis of most important process variables

    International Nuclear Information System (INIS)

    Cembrero, Jesus; Busquets-Mataix, David

    2009-01-01

    In this paper a comparative study by means of a statistical analysis of the main process variables affecting ZnO crystal electrodeposition is presented. ZnO crystals were deposited on two different substrates, silicon wafer and indium tin oxide. The control variables were substrate types, electrolyte concentration, temperature, exposition time and current density. The morphologies of the different substrates were observed using scanning electron microscopy. The percentage of substrate area covered by ZnO deposit was calculated by computational image analysis. The design of the applied experiments was based on a two-level factorial analysis involving a series of 32 experiments and an analysis of variance. Statistical results reveal that variables exerting a significant influence on the area covered by ZnO deposit are electrolyte concentration, substrate type and time of deposition, together with a combined two-factor interaction between temperature and current density. However, morphology is also influenced by surface roughness of the substrates

  19. Synthesis and crystal kinetics of cerium oxide nanocrystallites prepared by co-precipitation process

    International Nuclear Information System (INIS)

    Shih, C.J.; Chen, Y.J.; Hon, M.H.

    2010-01-01

    Cerium oxide nanocrystallites were synthesized at a relatively low temperature using cerium nitrate as starting materials in a water solution by a co-precipitation process. Effect of calcination temperature on the crystallite growth of cerium oxide nano-powders was investigated by X-ray diffraction, transmission electron microscopy and electron diffraction. The crystallization temperature of the cerium oxide powders was estimated to be about 273 K by XRD analysis. When calcined from 473 to 1273 K, the crystallization of the face-centered cubic phase was observed by XRD. The crystallite size of the cerium oxide increased from 10.0 to 43.8 nm with calcining temperature increasing from 673 to 1273 K. The activation energy for growth of cerium oxide nanoparticles was found to be 16.0 kJ mol -1 .

  20. Synthesis and crystal kinetics of cerium oxide nanocrystallites prepared by co-precipitation process

    Energy Technology Data Exchange (ETDEWEB)

    Shih, C.J., E-mail: cjshih@kmu.edu.tw [Department of Fragrance and Cosmetics Science, Kaohsiung Medical University, 100 Shi-Chuan 1st Road, Kaohsiung 807, Taiwan (China); Chen, Y.J. [Institute of Biomedical Sciences, National Sun Yat-Sen University, Kaohsiung 804, Taiwan (China); Hon, M.H. [Department of Materials Science and Engineering, National Cheng Kung University, Tainan 701, Taiwan (China)

    2010-05-15

    Cerium oxide nanocrystallites were synthesized at a relatively low temperature using cerium nitrate as starting materials in a water solution by a co-precipitation process. Effect of calcination temperature on the crystallite growth of cerium oxide nano-powders was investigated by X-ray diffraction, transmission electron microscopy and electron diffraction. The crystallization temperature of the cerium oxide powders was estimated to be about 273 K by XRD analysis. When calcined from 473 to 1273 K, the crystallization of the face-centered cubic phase was observed by XRD. The crystallite size of the cerium oxide increased from 10.0 to 43.8 nm with calcining temperature increasing from 673 to 1273 K. The activation energy for growth of cerium oxide nanoparticles was found to be 16.0 kJ mol{sup -1}.

  1. Vitrification and Crystallization of Phase-Separated Metallic Liquid

    Directory of Open Access Journals (Sweden)

    Yun Cheng

    2017-02-01

    Full Text Available The liquid–liquid phase separation (LLPS behavior of Fe50Cu50 melt from 3500 K to 300 K with different rapid quenching is investigated by molecular dynamics (MD simulation based on the embedded atom method (EAM. The liquid undergoes metastable phase separation by spinodal decomposition in the undercooled regime and subsequently solidifies into three different Fe-rich microstructures: the interconnected-type structure is kept in the glass and crystal at a higher cooling rate, while the Fe-rich droplets are found to crystalize at a lower cooling rate. During the crystallization process, only Fe-rich clusters can act as the solid nuclei. The twinning planes can be observed in the crystal and only the homogeneous atomic stacking shows mirror symmetry along the twinning boundary. Our present work provides atomic-scale understanding of LLPS melt during the cooling process.

  2. Zircon growth in a granitic pluton with specific mechanisms, crystallization temperatures and U-Pb ages. Implication to the 'spatiotemporal' formation process of the Toki granite, central Japan

    International Nuclear Information System (INIS)

    Yuguchi, Takashi; Ishibashi, Masayuki; Sasao, Eiji; Iwano, Hideki; Danhara, Tohru; Kato, Takenori; Sakata, Shuhei; Hattori, Kentaro; Hirata, Takafumi; Sueoka, Shigeru; Nishiyama, Tadao

    2016-01-01

    Zircons collected from a granitic pluton provide evidence of serial growth events with specific mechanisms, crystallization temperatures and U-Pb ages, revealing details of the sequential formation process from intrusion through emplacement to crystallization/solidification. The events have been identified by: 1) the study of the internal structure of zircon using cathodoluminescence, 2) deriving crystallization temperatures using Ti-in-zircon thermometry of the internal structure and 3) U-Pb age dating of the internal structure. The magmatic zircons from the Toki granite, central Japan, show two kinds in their internal structure: a low luminescence core (LLC) and oscillatory zonation (OZ). The LLC was produced by interfacial reaction-controlled growth in the granitic magma with cooling from about 910 to 760°C. The formation of OZ occurred by diffusion-controlled growth in a cooling magma chamber from about 850 to 690°C. The U-Pb ages derived from the LLC ranges from 74.7 ± 4.2 to 70.5 ± 1.3 Ma, indicating the incipient intrusion timing of the magma into the shallow crust. The OZ ages distribute from 72.7 ± 0.6 to 70.4 ± 1.7 Ma, which mean the timing from emplacement to crystallization/solidification of the granite pluton. Thus, the serial processes from intrusion through emplacement to crystallization/solidification occurred within a few million years. The old LLC and OZ ages are recognized in the western margins of the Toki granite, implying that the magma forming the western margins was the first to intrude, emplace and crystallize/solidify. The western margins with initial intrusion may accompany the crustal assimilation in order to create sufficient magma reservoir space, which is consistent with larger SrI and ASI values found in the western margins of the granite. (author)

  3. Experimental study of the use of refrigeration systems as cooling and heating systems in the production process of the VCO

    Science.gov (United States)

    Mulawarman, AANB; Arsana, M. E.; Temaja, I. W.; Sukadana, IBP

    2018-01-01

    Coconut oil extracted from the coconut milk obtained from fresh coconuts s often called virgin coconut oil (VCO). VCO is beneficial to health as an anti-oxidant and can lower HDL cholesterol in the blood while increasing blood LDL levels. In Indonesia most of VCO being produced on a small scale of home industries. Its production capacity still needs to be increased by improving production processes and implementing an appropriate technology accordingly. This research aims to conduct a study on making small-scale production machinery needed to produce VCO with reduced production time and improved quality of VCO in accordance with ISO 7381 quality criteria. The experimental results of the VCO machine has been develop and tested show good Coefficient of Performance of the system in amount of 3.93 and 2.8 for heating and cooling system respectively. Temperature of the VCO cooling chamber can be maintained in the range of 8°C to 10°C, as well as for heating, the reactor temperature can be maintained from 39°C to 42°C. The expected goal of this research developing a prototype of VCO production machine was done with ability to provide more efficient production process able to increase volume of VCO result by 23%.

  4. Kinetic Study of Crystallization Process in Fe32Ni36Cr14P12B6 Metallic Glass

    International Nuclear Information System (INIS)

    Lad, Kirit; Pratap, Arun; Rao, T. L. Shanker

    2010-01-01

    Kinetics of crystallization process in a Fe-based metallic glass 2826A (Fe 32 Ni 36 Cr 14 P 12 B 6 ) has been studied with the help of differential scanning calorimetry(DSC). It is found that the 2826A metallic glass exhibits two overlapping crystallization peaks. The activation energy for crystallization (E) and the Avrami exponent (n) for the two crystallization peaks have been obtained using the Kolmogorov-Jhonson-Mehl-Avrami (KJMA) equation. The so-obtained values of E and n have been utilized to derive normalized heat flow curves. It has been observed that the theoretical heat flow curves obtained using KJMA equation show large deviations from the experimental curves for the first peak whereas the curves are in very close agreement for the second peak. This suggests that kinetics of crystallization process during the first peak cannot be described correctly in KJMA formalism.

  5. Kinetic Study of Crystallization Process in Fe32Ni36Cr14P12B6 Metallic Glass

    Science.gov (United States)

    Lad, Kirit; Rao, T. L. Shanker; Pratap, Arun

    2010-06-01

    Kinetics of crystallization process in a Fe-based metallic glass 2826A (Fe32Ni36Cr14P12B6) has been studied with the help of differential scanning calorimetry(DSC). It is found that the 2826A metallic glass exhibits two overlapping crystallization peaks. The activation energy for crystallization (E) and the Avrami exponent (n) for the two crystallization peaks have been obtained using the Kolmogorov-Jhonson-Mehl-Avrami (KJMA) equation. The so-obtained values of E and n have been utilized to derive normalized heat flow curves. It has been observed that the theoretical heat flow curves obtained using KJMA equation show large deviations from the experimental curves for the first peak whereas the curves are in very close agreement for the second peak. This suggests that kinetics of crystallization process during the first peak cannot be described correctly in KJMA formalism.

  6. Numerical simulation of heat transfer process in solar enhanced natural draft dry cooling tower with radiation model

    International Nuclear Information System (INIS)

    Wang, Qiuhuan; Zhu, Jialing; Lu, Xinli

    2017-01-01

    Graphical abstract: A 3-D numerical model integrated with a discrete ordinate (DO) solar radiation model (considering solar radiation effect in the room of solar collector) was developed to investigate the influence of solar radiation intensity and ambient pressure on the efficiency and thermal characteristics of the SENDDCT. Our study shows that introducing such a radiation model can more accurately simulate the heat transfer process in the SENDDCT. Calculation results indicate that previous simulations overestimated solar energy obtained by the solar collector and underestimated the heat loss. The cooling performance is improved when the solar radiation intensity or ambient pressure is high. Air temperature and velocity increase with the increase of solar radiation intensity. But ambient pressure has inverse effects on the changes of air temperature and velocity. Under a condition that the solar load increases but the ambient pressure decreases, the increased rate of heat transferred in the heat exchanger is not obvious. Thus the performance of the SENDDCT not only depends on the solar radiation intensity but also depends on the ambient pressure. - Highlights: • A radiation model has been introduced to accurately simulate heat transfer process. • Heat transfer rate would be overestimated if the radiation model was not introduced. • The heat transfer rate is approximately proportional to solar radiation intensity. • The higher the solar radiation or ambient pressure, the better SENDDCT performance. - Abstract: Solar enhanced natural draft dry cooling tower (SENDDCT) is more efficient than natural draft dry cooling tower by utilizing solar radiation in arid region. A three-dimensional numerical model considering solar radiation effect was developed to investigate the influence of solar radiation intensity and ambient pressure on the efficiency and thermal characteristics of SENDDCT. The numerical simulation outcomes reveal that a model with consideration of

  7. Draining and drying process development of the Tokamak Cooling Water System of ITER

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Seokho, E-mail: kims@ornl.gov [US ITER, Oak Ridge National Laboratory, Oak Ridge, TN (United States); Van Hove, Walter; Ferrada, Juan [US ITER, Oak Ridge National Laboratory, Oak Ridge, TN (United States); Di Maio, Pietro Alessandro [University of Palermo, Viale delle Scienze, Palermo 90128 (Italy); Felde, David [Reactor and Nuclear Systems Division, ORNL, Oak Ridge, TN (United States); Raphael, Mitteau; Dell’Orco, Giovanni [ITER Organization, 13067 St Paul Lez Durance (France); Berry, Jan [US ITER, Oak Ridge National Laboratory, Oak Ridge, TN (United States)

    2016-11-01

    Highlights: • A thermal-hydraulic model using RELAP was developed for the ITER FW/BLK modules to determine design parameters for the nitrogen blowout flow rate and pressure. • The analysis indicates that as low as 2 MPa of pressure difference over the blanket modules will sufficiently evacuate the water in blankets. • A limited validation study indicates that the analysis yields less conservative results to compare against data collected from experiments. Therefore, the designed blow out flow of the drying system was selected with a large margin above the measured values to ensure the blow out operation. - Abstract: The ITER Organization (IO) developed a thermal-hydraulic (TH) model of the complex first wall and blanket (FW/BLK) cooling channels to determine gas flow rate and pressure required to effectively blow out the water in the FW/BLK. In addition, US ITER conducted experiments for selected geometries of FW/BLK flow channels to predict the blowout parameters. The analysis indicates that as low as 2 MPa of pressure difference over the blanket modules will ensure substantial evacuation of the water in blankets with just a few percent remaining in the blanket flow channels. A limited validation study indicates that the analysis yields less conservative results to compare against data collected from experiments. Therefore, the designed blow out flow of the drying system was selected with a large margin above the measured values to ensure the blow out operation.

  8. An innovative scintillation process for correcting, cooling, and reducing the randomness of waveforms

    International Nuclear Information System (INIS)

    Shen, J.

    1991-01-01

    Research activities were concentrated on an innovative scintillation technique for high-energy collider detection. Heretofore, scintillation waveform data of high- energy physics events have been problematically random. This paper represents a bottleneck of data flow for the next generation of detectors for proton colliders like SSC or LHC. Prevailing problems to resolve were: additional time walk and jitter resulting from the random hitting positions of particles, increased walk and jitter caused by scintillation photon propagation dispersions, and quantum fluctuations of luminescence. However, these were manageable when the different aspects of randomness had been clarified in increased detail. For this purpose, these three were defined as pseudorandomness, quasi-randomness, and real randomness, respectively. A unique scintillation counter incorporating long scintillators with light guides, a drift chamber, and fast discriminators plus integrators was employed to resolve problems of correcting time walk and reducing the additional jitter by establishing an analytical waveform description of V(t,z) for a measured (z). Resolving problem was accomplished by reducing jitter by compressing V(t,z) with a nonlinear medium, called cooling scintillation. Resolving problem was proposed by orienting molecular and polarizing scintillation through the use of intense magnetic technology, called stabilizing the waveform

  9. First results of a coated heat exchanger for the use in dehumidification and cooling processes

    International Nuclear Information System (INIS)

    Munz, Gunther M.; Bongs, C.; Morgenstern, A.; Lehmann, S.; Kummer, H.; Henning, H.-M.; Henninger, Stefan K.

    2013-01-01

    In this work a novel solar driven dehumidification and cooling system is presented. The core components of this combined system are a sorptive dehumidification device based on high performance sorptive coatings and a novel evacuated tube solar air collector providing the driving heat. The essential part of the system is the coated heat exchanger. The chosen adsorbent is attached to the heat exchanger surface by a newly developed coating technique. Besides a brief description of the novel components and the experimental setup, the development of the aluminum heat exchanger, the coating procedure and scale up for geometries comparable to the heat exchanger in the dehumidification setup, as well as a first characterization of a small-sized coated heat exchanger regarding water uptake and dehumidification performance are presented. For estimating an overall system performance, a 2-dimensional thermodynamic model was applied, using the parameters in focus for the development of heat exchanger, coating and demonstration system. Highlights: • A novel developed technology is applied for sorptive coating of heat exchangers. • Upscaling to dimensions of 100 × 100 × 400 mm 3 was successful. • A small scale heat exchanger was coated and characterized showing good results. • Evaluation of adsorbents and simulation of system performance were carried out. • SAPO-34 gives best performance for driving temperatures of 100 °C and above

  10. Charge exchange processes of high energy heavy ions channeled in crystals

    International Nuclear Information System (INIS)

    Andriamonje, S.; Dural, J.; Toulemonde, M.; Groeneveld, K.O.; Maier, R.; Quere, Y.

    1990-01-01

    The interaction of moving ions with single crystals is very sensitive to the orientation of the incident beam with respect to the crystalline directions of the target. The experiments show that high energy heavy ion channeling deeply modifies the slowing down and charge exchange processes. In this review, we describe the opportunity offered by channeling conditions to study the charge exchange processes. Some aspects of the charge exchange processes with high energy channeled heavy ions are selected from the extensive literature published over the past few years on this subject. Special attention is given to the work performed at the GANIL facility on the study of Radiative Electron Capture (REG), Electron Impact Ionisation (EII), and convoy electron emission. Finally we emphasize the interest of studying resonant charge exchange processes such as Resonant Coherent Excitation (RCE), Resonant Transfer and Excitation (RTE) or Dielectronic Recombination (DR) and the recently proposed Nuclear Excitation by Electron Capture (NEEC)

  11. Optical Constants of Crystallized TiO2 Coatings Prepared by Sol-Gel Process

    Directory of Open Access Journals (Sweden)

    Jun Shen

    2013-07-01

    Full Text Available Titanium oxide coatings have been deposited by the sol-gel dip-coating method. Crystallization of titanium oxide coatings was then achieved through thermal annealing at temperatures above 400 °C. The structural properties and surface morphology of the crystallized coatings were studied by micro-Raman spectroscopy and atomic force microscopy, respectively. Characterization technique, based on least-square fitting to the measured reflectance and transmittance spectra, is used to determine the refractive indices of the crystallized TiO2 coatings. The stability of the synthesized sol was also investigated by dynamic light scattering particle size analyzer. The influence of the thermal annealing on the optical properties was then discussed. The increase in refractive index with high temperature thermal annealing process was observed, obtaining refractive index values from 1.98 to 2.57 at He-Ne laser wavelength of 633 nm. The Raman spectroscopy and atomic force microscopy studies indicate that the index variation is due to the changes in crystalline phase, density, and morphology during thermal annealing.

  12. Transient phases during crystallization of solution-processed organic thin films

    Science.gov (United States)

    Wan, Jing; Li, Yang; Ulbrandt, Jeffery; Smilgies, Detlef-M.; Hollin, Jonathan; Whalley, Adam; Headrick, Randall

    We report an in-situ study of 2,7-dioctyl[1]benzothieno[3,2-b][1]benzothiophene (C8-BTBT) organic semiconductor thin film deposition from solution via hollow pen writing, which exhibits multiple transient phases during crystallization. Under high writing speed (25 mm/s) the films have an isotropic morphology, although the mobilities range up to 3.0 cm2/V.s. To understand the crystallization in this highly non-equilibrium regime, we employ in-situ microbeam grazing incidence wide-angle X-ray scattering combined with optical video microscopy at different deposition temperatures. A sequence of crystallization was observed in which a layered liquid-crystalline (LC) phase of C8-BTBT precedes inter-layer ordering. For films deposited above 80ºC, a transition from LC phase to a transient crystalline state that we denote as Cr1 occurs after a temperature-dependent incubation time, which is consistent with classical nucleation theory. After an additional ~ 0.5s, Cr1 transforms to the final stable structure Cr2. Based on these results, we demonstrate a method to produce large crystalline grain size and high carrier mobility during high-speed processing by controlling the nucleation rate during the transformation from the LC phase. Nsf DMR-1307017, NSF DMR-1332208.

  13. Twinning processes in Cu-Al-Ni martensite single crystals investigated by neutron single crystal diffraction method

    Czech Academy of Sciences Publication Activity Database

    Molnar, P.; Šittner, P.; Novák, V.; Lukáš, Petr

    2008-01-01

    Roč. 481, Sp.Iss.SI (2008), s. 513-517 ISSN 0921-5093 R&D Projects: GA AV ČR IAA100480704 Institutional research plan: CEZ:AV0Z10480505 Keywords : Cu-Al-Ni * single crystals * neutron diffraction Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 1.806, year: 2008

  14. Tips pentacene crystal alignment for improving performance of solution processed organic thin film transistors

    Science.gov (United States)

    He, Zhengran

    A newly-developed p-type organic semiconductor 6,13-bis (triisopropylsilylethynyl) pentacene (TIPS pentacene) demonstrates various advantages such as high mobility, air stability and solution processibility, but at the same time its application is restricted by major issues, such as crystal misorientation and performance variation of organic thin-film transistors (OTFTs). This dissertation demonstrates several different approaches to address these issues. As a result, both crystal orientation and areal coverage can be effectively improved, leading to an enhancement of average mobility and performance consistency of OTFTs. Chapter 1 presents an introduction and background of this dissertation. Chapter 2 explores the usage of inorganic silica nanoparticles to manipulate the morphology of TIPS pentacene thin films and the performance of solution-processed organic OTFTs. The resultant drop-cast films yield improved morphological uniformity at ~10% SiO2 loading, which also leads to a 3-fold increase in average mobility and nearly 4-times reduction in the ratio of standard deviation of mobility (μStdev) to average mobility (μAvg). The experimental results suggest that the SiO2 nanoparticles mostly aggregate at TIPS pentacene grain boundaries, and that 10% nanoparticle concentration effectively reduces the undesirable crystal misorientation without considerably compromising TIPS pentacene crystallinity. Chapter 3 discusses the utilization of air flow to effectively reduce the TIPS pentacene crystal anisotropy and enhance performance consistency in OTFTs. Under air-flow navigation (AFN), TIPS pentacene forms thin films with improved crystal orientation and increased areal coverage, which subsequently lead to a four-fold increase of average hole mobility and one order of magnitude enhancement in performance consistency. Chapter 4 investigates the critical roles of lateral and vertical phase separation in the performance of the next-generation organic and hybrid electronic

  15. A thermal analysis for the use of cooled rotating drums in electron processing

    International Nuclear Information System (INIS)

    Fletcher, P.M.; Williams, K.E.

    1988-01-01

    The thermal response of rotating drums under an electron beam has been analyzed using a finite difference thermal analysis computer code. Rotating drums are used to convey thin webs or films under the electron beams while controlling their temperature and, in some cases, in dissipating the exotherm involved in curing coatings applied to them. Each portion of the drum surface receives one heat pulse per rotation as it passes under the beam. The drum's thermal behavior shows both an immediate response to each heat pulse and a more gradual response to the average heat acquired over many pulses. After many rotations a steady state is reached where there is only an immediate response to each heat pulse but the gradual heating has tapered off. Nevertheless the steady state temperatures are strongly dependent on the gradual heating that led to them. Slow and fast speeds of rotation are compared showing the effects of both gradual and immediate heating components. The thermal analysis is extended to include the coolant fluid inside the drum shell and the web on the drum surface. The coolant's incoming temperature, volumetric flow rate, flow speed through the coolant channels and film coefficient between the outer shell and fluid are all included in the analysis. The small air gap between the web and drum, the convective cooling of the web to the ambient air, and the exothermic reaction of any chemical reactions on the web are included. The stresses produced in the drum shell (i.e. between the outer surface and the temperature-controlling fluid within the drum) are analyzed in order to define safe e-beam powers and rotating speeds. The analysis provides the basis for many design decisions and can give an end-user a full temperature history for his product for any set of conditions. (author)

  16. Thermal-hydraulic process for cooling, heating and power production with low-grade heat sources in residential sector

    International Nuclear Information System (INIS)

    Borgogno, R.; Mauran, S.; Stitou, D.; Marck, G.

    2017-01-01

    Highlights: • Assessment of solar thermal-hydraulic process for tri-generation application. • Choice of the most suitable working fluid pair (R1234yf/R1233zd). • Evaluation of the global annual performance in Mediterranean climate. • Global annual COP and heat amplification achieving 0.24 and 1.2 respectively. • Global annual performance achieving an electric efficiency of 3.7%. - Abstract: A new process based on thermal-hydraulic conversion actuated by low-grade thermal energy is investigated. Input thermal energy can be provided by the means of solar collectors, as well as other low temperature energy sources. In the following article, “thermo-hydraulic” term refers to a process involving an incompressible fluid used as an intermediate medium to transfer work hydraulically between different thermal operated components or sub-systems. The system aims at providing trigeneration energy features for the residential sector, that is providing heating, cooling and electrical power for meeting the energy needs of domestic houses. This innovative system is made of two dithermal processes (working at two different levels of temperatures) and featuring two different working fluids. The first process is able to directly supply either electrical energy generated by an hydraulic turbine or drives the second process thanks to the incompressible fluid, which is similar to a heat pump effect for heating or cooling purposes. The innovative aspect of this process relies on the use of an hydraulic transfer fluid to transfer the work between each sub-system and therefore simplifying the conversion chain. A model, assuming steady-state operation, is developed to assess the energy performances of different variants of this thermo-hydraulic process with various heat source temperatures (80–110 °C) or heat sinks (0–30 °C), as well as various pairs of working fluids. For instance, in the frame of a single-family home, located in the Mediterranean region, the working

  17. Crystallization process of zircon and fergusonite during hydrothermal alteration in Nechalacho REE deposit, Thor Lake, Canada

    Science.gov (United States)

    Hoshino, M.; Watanabe, Y.; Murakami, H.; Kon, Y.; Tsunematsu, M.

    2012-04-01

    The core samples of two drill holes, which penetrate sub-horizontal mineralized horizons at Nechalacho REE deposit in the Proterozoic Thor Lake syenite, Canada, were studied in order to clarify magmatic and hydrothermal processes that enriched HFSE (e.g. Zr, Nb, Y and REE). Zircon is the most common REE minerals in Nechalacho REE deposit. The zircon is divided into five types as follows: Type-1 zircon occurs as single grain in phlogopite and the chondrite-normalized REE pattern is characterized by a steeply-rising slope from the LREE to the HREE with a positive Ce-anomaly and negative Eu-anomaly. This chemical characteristic is similar to that of igneous zircon. Type-2 zircon consists of HREE-rich magmatic porous core and LREE-Nb-F-rich hydrothermal rim. This type zircon is mostly included in phlogopite and fluorite, and occasionally in microcline. Type-3 zircon is characterized by euhedral to anhedral crystal, occurring in a complex intergrowth with REE fluorocarbonates. Type-3 zircons have high contents of REE, Nb and fluorine. Type-4 zircon consists of porous-core and -rim zones, but their chemical compositions are similar to each other. This type zircon is a subhedral crystal rimmed by fergusonite. Type-5 zircon is characterized by smaller, porous and subhedral to anhedral crystals. The interstices between small zircons are filled by fergusonite. Type-4 and -5 zircons show low REE and Nb contents. Occurrences of these five types of zircon are different according to the depth and degree of the alteration by hydrothermal solutions rich in F- and CO3 of the two drill holes, which permit a model for evolution of the zircon crystallization in Nechalacho REE deposit as follows: (1) type-1 (single magmatic zircon) is formed in miaskitic syenite. (2) LREE-Nb-F-rich hydrothermal zircon formed around HREE-rich magmatic zircon (type-2 zircon); (3) type-3 zircon crystallized thorough F and CO3-rich hydrothermal alteration of type-2 zircon which formed the complex

  18. "Hot" Facilitation of "Cool" Processing: Emotional Distraction Can Enhance Priming of Visual Search

    Science.gov (United States)

    Kristjansson, Arni; Oladottir, Berglind; Most, Steven B.

    2013-01-01

    Emotional stimuli often capture attention and disrupt effortful cognitive processing. However, cognitive processes vary in the degree to which they require effort. We investigated the impact of emotional pictures on visual search and on automatic priming of search. Observers performed visual search after task-irrelevant neutral or emotionally…

  19. Preliminary calculations on the cooling rate of the Renca batholit, Sierra de San Luis, Argentina

    International Nuclear Information System (INIS)

    Lopez de Luchi, M.G.; Ostera, H.A.; Linares, E; Rosello, E.A

    2001-01-01

    Cooling rates can be used to constrain the unroofing history of plutonic-metamorphic system. Geocronological cooling rates (Spear and Parrish, 1996) can be unravelled using age calculations on minerals that were open systems and subsequently passed through their closure temperatures (Dodson, 1973) during cooling. Several age determinations on different minerals are needed in order to accurately constrain the cooling path of a pluton (Hodges 1991, Spear and Parrish, 1996 and references therein). Isotopic open-system behaviour in minerals can be modelled as volume diffusion process (Hodges, 1991 and references therein), which depends on the cooling rate of the whole system. We present the first results on the calculation of the cooling rate of the Renca batholith on the basis of the combination of both thermometric calculations and available crystallization and cooling ages (au)

  20. Redox process catalysed by growing crystal-strengite, FePO4,2H2O, crystallizing from solution with iron(II) and hydroxylamine

    Science.gov (United States)

    Lundager Madsen, Hans Erik

    2014-09-01

    In an attempt to grow pure crystals of the iron(II) phosphate vivianite, Fe3(PO4)2,8H2O, from a solution of Mohr's salt, Fe(NH4)2(SO4)2,6H2O, added to a solution of ammonium phosphate, hydroxylammonium chloride, NH3OHCl, was added to the iron(II) stock solution to eliminate oxidation of iron(II) by oxygen from the air. However, the effect turned out to be the opposite of the expected: whereas hydroxylamine reduces iron(III) in bulk solution, it acted as a strong oxidant in the presence of growing iron phosphate crystals, causing the crystallization of the iron(III) phosphate strengite, FePO4,2H2O, as the only solid phase. Evidently the crystal surface catalyses oxidation of iron(II) by hydroxylamine. The usual composite kinetics of spiral growth and surface nucleation was found. The surface-nucleation part yielded edge free energy λ in the range 12-45 pJ/m, virtually independent of temperature and in the range typical for phosphates of divalent metals. The scatter of values for λ presumably arises from contributions from different crystal forms to the overall growth rate. The low mean value points to strong adsorption of iron(II), which is subsequently oxidized at the crystal surface, forming strengite. The state of the system did not tend to thermodynamic equilibrium, but to a metastable state, presumably controlled by the iron(II) rich surface layer of the crystal. In addition to crystal growth, it was possible to measure nucleation kinetics by light scattering (turbidimetry). A point of transition from heterogeneous to homogeneous nucleation was found, and from the results for the homogeneous domain a rather precise value of crystal surface free energy γ=55 mJ/m2 was found. This is a relatively low value as well, indicating that the redox process plays a role already at the nucleation stage.

  1. Virtual Crystallizer

    Energy Technology Data Exchange (ETDEWEB)

    Land, T A; Dylla-Spears, R; Thorsness, C B

    2006-08-29

    Large dihydrogen phosphate (KDP) crystals are grown in large crystallizers to provide raw material for the manufacture of optical components for large laser systems. It is a challenge to grow crystal with sufficient mass and geometric properties to allow large optical plates to be cut from them. In addition, KDP has long been the canonical solution crystal for study of growth processes. To assist in the production of the crystals and the understanding of crystal growth phenomena, analysis of growth habits of large KDP crystals has been studied, small scale kinetic experiments have been performed, mass transfer rates in model systems have been measured, and computational-fluid-mechanics tools have been used to develop an engineering model of the crystal growth process. The model has been tested by looking at its ability to simulate the growth of nine KDP boules that all weighed more than 200 kg.

  2. Uncovering molecular processes in crystal nucleation and growth by using molecular simulation.

    Science.gov (United States)

    Anwar, Jamshed; Zahn, Dirk

    2011-02-25

    Exploring nucleation processes by molecular simulation provides a mechanistic understanding at the atomic level and also enables kinetic and thermodynamic quantities to be estimated. However, whilst the potential for modeling crystal nucleation and growth processes is immense, there are specific technical challenges to modeling. In general, rare events, such as nucleation cannot be simulated using a direct "brute force" molecular dynamics approach. The limited time and length scales that are accessible by conventional molecular dynamics simulations have inspired a number of advances to tackle problems that were considered outside the scope of molecular simulation. While general insights and features could be explored from efficient generic models, new methods paved the way to realistic crystal nucleation scenarios. The association of single ions in solvent environments, the mechanisms of motif formation, ripening reactions, and the self-organization of nanocrystals can now be investigated at the molecular level. The analysis of interactions with growth-controlling additives gives a new understanding of functionalized nanocrystals and the precipitation of composite materials. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. Rapid, cool sintering of wet processed yttria-stabilized zirconia ceramic electrolyte thin films.

    Science.gov (United States)

    Park, Jun-Sik; Kim, Dug-Joong; Chung, Wan-Ho; Lim, Yonghyun; Kim, Hak-Sung; Kim, Young-Beom

    2017-09-29

    Here we report a photonic annealing process for yttria-stabilized zirconia films, which are one of the most well-known solid-state electrolytes for solid oxide fuel cells (SOFCs). Precursor films were coated using a wet-chemical method with a simple metal-organic precursor solution and directly annealed at standard pressure and temperature by two cycles of xenon flash lamp irradiation. The residual organics were almost completely decomposed in the first pre-annealing step, and the fluorite crystalline phases and good ionic conductivity were developed during the second annealing step. These films showed properties comparable to those of thermally annealed films. This process is much faster than conventional annealing processes (e.g. halogen furnaces); a few seconds compared to tens of hours, respectively. The significance of this work includes the treatment of solid-state electrolyte oxides for SOFCs and the demonstration of the feasibility of other oxide components for solid-state energy devices.

  4. In situ study of the growth and degradation processes in tetragonal lysozyme crystals on a silicon substrate by high-resolution X-ray diffractometry

    Science.gov (United States)

    Kovalchuk, M. V.; Prosekov, P. A.; Marchenkova, M. A.; Blagov, A. E.; D'yakova, Yu. A.; Tereshchenko, E. Yu.; Pisarevskii, Yu. V.; Kondratev, O. A.

    2014-09-01

    The results of an in situ study of the growth of tetragonal lysozyme crystals by high-resolution X-ray diffractometry are considered. The crystals are grown by the sitting-drop method on crystalline silicon substrates of different types: both on smooth substrates and substrates with artificial surface-relief structures using graphoepitaxy. The crystals are grown in a special hermetically closed crystallization cell, which enables one to obtain images with an optical microscope and perform in situ X-ray diffraction studies in the course of crystal growth. Measurements for lysozyme crystals were carried out in different stages of the crystallization process, including crystal nucleation and growth, developed crystals, the degradation of the crystal structure, and complete destruction.

  5. Electrical, thermal and magnetic behaviour of the metallic glass Fe80B20 in the crystallization process

    International Nuclear Information System (INIS)

    Isalgue, A.; Cusido, J.A.

    1986-01-01

    The thermal, electrical DC conductivity and magnetic properties have been studied in the crystallization process of the metallic glass Fe 80 B 20 (Metglass 2605) induced by heat treatment. The electrical and thermal conductivity, the coercive force and the remanence are strongly affected with the crystallization of the glass. Two steps can be dicerned from the magnetic measurements; the differences between the two steps are interpreted in the basis of the ''spherulite-type'', grown of Fe 3 B in the first crystallization step and the aparition of Fe 2 B in the second step. (author)

  6. In situ diagnostics of the crystal-growth process through neutron imaging

    DEFF Research Database (Denmark)

    Tremsin, Anton S.; Makowska, Malgorzata Grazyna; Perrodin, Didier

    2016-01-01

    Neutrons are known to be unique probes in situations where other types of radiation fail to penetrate samples and their surrounding structures. In this paper it is demonstrated how thermal and cold neutron radiography can provide time-resolved imaging of materials while they are being processed (e......, as limited by the resolution of the present experiments). It is also demonstrated that the dopant concentration can be quantified even for very low concentration levels (∼ 0.1%) in 10 mm thick samples. The interface between the solid and liquid phases can also be imaged, provided there is a sufficient change.......g. while growing single crystals). The processing equipment, in this case furnaces, and the scintillator materials are opaque to conventional X-ray interrogation techniques. The distribution of the europium activator within a BaBrCl:Eu scintillator (0.1 and 0.5% nominal doping concentrations per mole...

  7. The ergonomics approach for thin film transistor-liquid crystal display manufacturing process.

    Science.gov (United States)

    Lu, Chih-Wei; Yao, Chia-Chun; Kuo, Chein-Wen

    2012-01-01

    The thin film transistor-liquid crystal display (TFT-LCD) has been used all over the world. Although the manufacture process of TFT-LCD was highly automated, employees are hired to do manual job in module assembly process. The operators may have high risk of musculoskeletal disorders because of the long work hours and the repetitive activities in an unfitted work station. The tools of this study were questionnaire, checklist and to evaluate the work place design. The result shows that the participants reported high musculoskeletal disorder symptoms in shoulder (59.8%), neck (49.5%), wrist (39.5%), and upper back (30.6%). And, to reduce the ergonomic risk factors, revising the height of the work benches, chairs and redesigning the truck to decrease the chance of unsuitable positions were recommended and to reduce other ergonomics hazards and seta good human machine interface and appropriate job design.

  8. Effects of different cooling rates during two casting processes on the microstructures and mechanical properties of extruded Mg–Al–Ca–Mn alloy

    International Nuclear Information System (INIS)

    Xu, S.W.; Oh-ishi, K.; Kamado, S.; Takahashi, H.; Homma, T.

    2012-01-01

    Highlights: ► Ordered monolayer GP zone was formed by increasing cooling rate. ► Finer extruded microstructure was obtained by increasing cooling rate. ► Higher number density precipitates was obtained by increasing cooling rate. ► Tensile 0.2% proof stress was increased by 105 MPa by increasing cooling rate. ► Extruded DC-cast alloy shows higher tensile 0.2% proof stress of 409 MPa. - Abstract: In this study, Mg–3.6Al–3.4Ca–0.3Mn (wt.%) (which is denoted AXM4303) alloy ingots were prepared by two casting processes with different cooling rates: permanent mold (PM) casting, which has a lower cooling rate of 10–20 °C/s and direct chill (DC) casting, which has a higher cooling rate of 100–110 °C/s. Then, these two types of AXM4303 alloy ingots were hot extruded at 400 °C under the same conditions. The microstructures of the as-cast and extruded alloy samples were systematically investigated by field-emission scanning electron microscope (FE-SEM), transmission electron microscope (TEM) and electron backscattered diffraction (EBSD) systems. The effects of the different cooling rates during the casting process on the microstructures and mechanical properties of the extruded AXM4303 alloy samples were evaluated. The results show that the strength of the extruded Mg–Al–Ca–Mn alloy can be substantially increased by microstructural control during the casting process. Because the cooling rate of the DC casting process is much faster than the cooling rate of PM casting, the DC-cast AXM4303 has the following properties: (i) the lamellar eutectic structure and dendrite cell size are significantly refined, (ii) the ordered monolayer GP zones enriched with Al and Ca nucleate with no growth, and (iii) most of the Mn remains in solution in the matrix. Thus, after hot extrusion, the DC-cast AXM4303 has finer dynamically recrystallized (DRXed) grain size, finer and more uniformly distributed fragmented eutectic particles, finer planar Al 2 Ca precipitates

  9. Integration of High-Temperature Gas-Cooled Reactors into Industrial Process Applications

    International Nuclear Information System (INIS)

    Nelson, Lee

    2009-01-01

    This report is a preliminary comparison of conventional and potential HTGR-integrated processes in several common industrial areas: (1) Producing electricity via a traditional power cycle; (2) Producing hydrogen; (3) Producing ammonia and ammonia-derived products, such as fertilizer; (4) Producing gasoline and diesel from natural gas or coal; (5) Producing substitute natural gas from coal; and (6) Steam-assisted gravity drainage (extracting oil from tar sands).

  10. Optimisation and process control of steam and cooling cycles by use of online TOC analysis

    Energy Technology Data Exchange (ETDEWEB)

    Schroeter, Jens-Uwe [LAR Process Analysers AG, Berlin (Germany). Domestic Sales

    2013-06-01

    Online monitoring of organic pollution is of great importance in processes with steam, condensate and boiler feed water due to the influence of impurities on corrosion as well as the formation of biofilms, and deposits. Today, the recommended TOC limit value is set between 0.1 to 0.2 mg/l C. Plants can be optimised when monitoring the TOC values. Only some online-OC analysers that are available on the market meet the measurement requirements. (orig.)

  11. Comparative analysis of different process simulation settings of a micro injection molded part featuring conformal cooling

    DEFF Research Database (Denmark)

    Marhöfer, David Maximilian; Tosello, Guido; Islam, Aminul

    2015-01-01

    . In the reported work, process simulations using Autodesk Moldflow Insight 2015® are applied to a micro mechanical part to be fabricated by micro injection molding and with over-all dimensions of 12.0 × 3.0 × 0.8 mm³ and micro features (micro hole, diameter of 580 μm, and sharp radii down to 100 μm). Three...

  12. Kinetics of non-equilibrium processes in non-linear crystals of lithium borates excited with synchrotron radiation

    CERN Document Server

    Ogorodnikov, I N; Isaenko, L I; Zinin, E I; Kruzhalov, A V

    2000-01-01

    The paper presents the results of a study of the LiB sub 3 O sub 5 and Li sub 2 B sub 4 O sub 7 crystals by the use of the luminescent spectroscopy with the sub-nanosecond time resolution under excitation of the high-power synchrotron radiation. The commonness in the origin of the non-equilibrium processes in these crystals as well as the observed differences in the luminescence manifestations is discussed.

  13. Kinetics of non-equilibrium processes in non-linear crystals of lithium borates excited with synchrotron radiation

    Energy Technology Data Exchange (ETDEWEB)

    Ogorodnikov, I.N. E-mail: ogo@dpt.ustu.ru; Pustovarov, V.A.; Isaenko, L.I.; Zinin, E.I.; Kruzhalov, A.V

    2000-06-21

    The paper presents the results of a study of the LiB{sub 3}O{sub 5} and Li{sub 2}B{sub 4}O{sub 7} crystals by the use of the luminescent spectroscopy with the sub-nanosecond time resolution under excitation of the high-power synchrotron radiation. The commonness in the origin of the non-equilibrium processes in these crystals as well as the observed differences in the luminescence manifestations is discussed.

  14. Laser cooling of solids

    CERN Document Server

    Petrushkin, S V

    2009-01-01

    Laser cooling is an important emerging technology in such areas as the cooling of semiconductors. The book examines and suggests solutions for a range of problems in the development of miniature solid-state laser refrigerators, self-cooling solid-state lasers and optical echo-processors. It begins by looking at the basic theory of laser cooling before considering such topics as self-cooling of active elements of solid-state lasers, laser cooling of solid-state information media of optical echo-processors, and problems of cooling solid-state quantum processors. Laser Cooling of Solids is an important contribution to the development of compact laser-powered cryogenic refrigerators, both for the academic community and those in the microelectronics and other industries. Provides a timely review of this promising field of research and discusses the fundamentals and theory of laser cooling Particular attention is given to the physics of cooling processes and the mathematical description of these processes Reviews p...

  15. Process for first charge of gas cooled nuclear reactors with fuel elements

    International Nuclear Information System (INIS)

    Bromkamp, K.H.; Daoud, H.; Engelhardt, K.; Hantke, H.J.

    1979-01-01

    The charging of the THTR-300 takes place continuously via three positions in the inner zone and 12 positions in the outer zone. The inner and outer zone are charged alternately. The size of the charging step is chosen so that the mixing zone formed between the two zones does not exceed a given width. The reflector rods are driven out during the whole fuelling process and the core rods are driven into the core. The charging always takes place in the sub-critical condition, where the degree of sub-criticality is checked by measurement of the inverse multiplication factor after each fuelling step. (DG) [de

  16. Rapid, cool sintering of wet processed yttria-stabilized zirconia ceramic electrolyte thin films

    OpenAIRE

    Park, Jun-Sik; Kim, Dug-Joong; Chung, Wan-Ho; Lim, Yonghyun; Kim, Hak-Sung; Kim, Young-Beom

    2017-01-01

    Here we report a photonic annealing process for yttria-stabilized zirconia films, which are one of the most well-known solid-state electrolytes for solid oxide fuel cells (SOFCs). Precursor films were coated using a wet-chemical method with a simple metal-organic precursor solution and directly annealed at standard pressure and temperature by two cycles of xenon flash lamp irradiation. The residual organics were almost completely decomposed in the first pre-annealing step, and the fluorite cr...

  17. Numerical simulation on vacuum solution heat treatment and gas quenching process of a low rhenium-containing Ni-based single crystal turbine blade

    Directory of Open Access Journals (Sweden)

    Zhe-xin Xu

    2016-11-01

    Full Text Available Numerical heat-transfer and turbulent flow model for an industrial high-pressure gas quenching vacuum furnace was established to simulate the heating, holding and gas fan quenching of a low rhenium-bearing Ni-based single crystal turbine blade. The mesh of simplified furnace model was built using finite volume method and the boundary conditions were set up according to the practical process. Simulation results show that the turbine blade geometry and the mutual shielding among blades have significant influence on the uniformity of the temperature distribution. The temperature distribution at sharp corner, thin wall and corner part is higher than that at thick wall part of blade during heating, and the isotherms show a toroidal line to the center of thick wall. The temperature of sheltered units is lower than that of the remaining part of blade. When there is no shelteration among multiple blades, the temperature distribution for all blades is almost identical. The fluid velocity field, temperature field and cooling curves of the single and multiple turbine blades during gas fan quenching were also simulated. Modeling results indicate that the loading tray, free outlet and the location of turbine blades have important influences on the flow field. The high-speed gas flows out from the nozzle is divided by loading tray, and the free outlet enhanced the two vortex flow at the end of the furnace door. The closer the blade is to the exhaust outlet and the nozzle, the greater the flow velocity is and the more adequate the flow is. The blade geometry has an effect on the cooling for single blade and multiple blades during gas fan quenching, and the effects in double layers differs from that in single layer. For single blade, the cooing rate at thin-walled part is lower than that at thick-walled part, the cooling rate at sharp corner is greater than that at tenon and blade platform, and the temperature at regions close to the internal position is

  18. Influence of nanomechanical crystal properties on the comminution process of particulate solids in spiral jet mills.

    Science.gov (United States)

    Zügner, Sascha; Marquardt, Karin; Zimmermann, Ingfried

    2006-02-01

    Elastic-plastic properties of single crystals are supposed to influence the size reduction process of bulk materials during jet milling. According to Pahl [M.H. Pahl, Zerkleinerungstechnik 2. Auflage. Fachbuchverlag, Leipzig (1993)] and H. Rumpf: [Prinzipien der Prallzerkleinerung und ihre Anwendung bei der Strahlmahlung. Chem. Ing. Tech., 3(1960) 129-135.] fracture toughness, maximum strain or work of fracture for example are strongly dependent on mechanical parameters like hardness (H) and young's modulus of elasticity (E). In addition the dwell time of particles in a spiral jet mill proved to correlate with the hardness of the feed material [F. Rief: Ph. D. Thesis, University of Würzburg (2001)]. Therefore 'near-surface' properties have a direct influence on the effectiveness of the comminution process. The mean particle diameter as well as the size distribution of the ground product may vary significantly with the nanomechanical response of the material. Thus accurate measurement of crystals' hardness and modulus is essential to determine the ideal operational micronisation conditions of the spiral jet mill. The recently developed nanoindentation technique is applied to examine subsurface properties of pharmaceutical bulk materials, namely calcite, sodium ascorbate, lactose and sodium chloride. Pressing a small sized tip into the material while continuously recording load and displacement, characteristic diagrams are derived. The mathematical evaluation of the force-displacement-data allows for calculation of the hardness and the elastic modulus of the investigated material at penetration depths between 50-300 nm. Grinding experiments performed with a modified spiral jet mill (Type Fryma JMRS 80) indicate the strong impact of the elastic-plastic properties of a given substance on its breaking behaviour. The fineness of milled products produced at constant grinding conditions but with different crystalline powders varies significantly as it is dependent on the

  19. Dissolution of powdered spent fuel and U crystallization from actual dissolver solution for 'NEXT' process development

    International Nuclear Information System (INIS)

    Nomura, Kazunori; Hinai, Hiroshi; Nakahara, Masaumi; Kaji, Naoya; Kamiya, Masayoshi; Ohyama, Koichi; Sano, Yuichi; Washiya, Tadahiro; Komaki, Jun

    2008-01-01

    The beaker-scale experiments on the effective powdered fuel dissolution and the U crystallization from dissolver solution with the irradiated MOX fuel from the experimental fast reactor 'JOYO' were carried out. The powdered fuel was effectively dissolved into the nitric acid solution. In the U crystallization experiments, U crystal was obtained from the actual dissolver solution without any addition of reagent. (authors)

  20. Using high temperature gas-cooled reactors for energy neutral mineral development processes – A proposed IAEA Coordinated Research Project

    International Nuclear Information System (INIS)

    Haneklaus, N.; Reitsma, F.; Tulsidas, H.; Dyck, G.; Koshy, T.; Tyobeka, B.; Schnug, E.; Allelein, H-J.; Birky, B.

    2014-01-01

    Today, uranium mined from various regions is the predominant reactor fuel of the present generation of nuclear power plants. The anticipated growth in nuclear energy may require introducing uranium/thorium from unconventional resources (e.g. phosphates, coal ash or sea water) as a future nuclear reactor fuel. The demand for mineral commodities is growing exponentially and high-grade, easily-extractable resources are being depleted rapidly. This shifts the global production to low-grade, or in certain cases unconventional mineral resources, the production of which is constrained by the availability of large amounts of energy. Numerous mining processes can benefit from the use of so-called “thermal processing”. This is in particular beneficial for (1) low grade deposits that cannot be treated using the presently dominant chemical processing techniques; (2) the extraction of high purity end products; and (3) the separation of high value or unwanted impurities (e.g. uranium, thorium, rare earths, etc.) that could be used/sold, when extracted, which will result in cleaner final products. The considerably lower waste products also make it attractive compared to chemical processing. In the future, we may need to extract nuclear fuel and minerals from the same unconventional resources to make nuclear fuel- and low grade ore processing feasible and cost-effective. These processes could be sustainable only if low-cost, carbon free, reliable energy is available for comprehensive extraction of all valuable commodities, for the entire life of the project. Nuclear power plants and specifically High Temperature Gas-cooled Reactors (HTGRs) can produce this energy and heat in a sustainable way, especially if enough uranium/thorium can be extracted to fuel these reactors.

  1. Integrated membrane distillation-crystallization: process design and cost estimations for seawater treatment and fluxes of single salt solutions

    NARCIS (Netherlands)

    Creusen, R.J.M.; Medevoort, J. van; Roelands, C.P.M.; Renesse van Duivenbode, J.A.D. van; Hanemaaijer, J.H.; Leerdam, R.C. van

    2013-01-01

    The goal of this research is to design an integrated membrane distillation-crystallization (MDC) process for desalination of seawater with pure water and dry salts as the only products. The process is based on a combination of membrane distillation (MD) and osmotic distillation (OD) steps with

  2. Mathematical modeling of static layer crystallization for propellant grade hydrogen peroxide

    Science.gov (United States)

    Hao, Lin; Chen, Xinghua; Sun, Yaozhou; Liu, Yangyang; Li, Shuai; Zhang, Mengqian

    2017-07-01

    Hydrogen peroxide (H2O2) is an important raw material widely used in many fields. In this work a mathematical model of heat conduction with a moving boundary was proposed to study the melt crystallization process of hydrogen peroxide which was carried out outside a cylindrical crystallizer. Considering the effects of the temperature of the cooling fluid on the thermal conductivity of crude crystal, the model is an improvement of Guardani's research and can be solved by analytic iteration method. An experiment was designed to measure the thickness of crystal layer with time under different conditions. A series of analysis, including the effects of different refrigerant temperature on crystal growth rate, the effects of different cooling rates on crystal layer growth rate, the effects of crystallization temperature on heat transfer and the model's application scope were conducted based on the comparison between experimental results and simulation results of the model.

  3. Energy loss and charge exchange processes of high energy heavy ions channeled in crystals

    International Nuclear Information System (INIS)

    Poizat, J.C.; Andriamonje, S.; Anne, R.; Faria, N.V.d.C.; Chevallier, M.; Cohen, C.; Dural, J.; Farizon-Mazuy, B.; Gaillard, M.J.; Genre, R.; Hage-Ali, M.; Kirsch, R.; L'hoir, A.; Mory, J.; Moulin, J.; Quere, Y.; Remillieux, J.; Schmaus, D.; Toulemonde, M.

    1990-01-01

    The interaction of moving ions with single crystals is very sensitive to the orientation of the incident beam with respect to the crystalline directions of the target. Our experiments show that high energy heavy ion channeling deeply modifies their slowing down and charge exchange processes. This is due to the fact that channeled ions interact only with outershell target electrons, which means that the electron density they experience is very low and that the binding energy, and then the momentum distribution of these electrons, are quite different from the corresponding average values associated to random incidence. The two experimental studies presented here show the reduction of the energy loss rate for fast channeled heavy ions and illustrate the two aspects of channeling effects on charge exchange, the reduction of electron loss on one hand, and of electron capture on the other hand

  4. Superconducting properties of single-crystal Nb sphere formed by large-undercooling solidification process

    Energy Technology Data Exchange (ETDEWEB)

    Takeya, H.; Sung, Y.S.; Hirata, K.; Togano, K

    2003-10-15

    An electrostatic levitation (ESL) system has been used for investigating undercooling effects on superconducting materials. In this report, preliminary experiments on Nb (melting temperature: T{sub m}=2477 deg. C) have been performed by melting Nb in levitation using 150 and 250 W Nd-YAG lasers. Since molten Nb is solidified without any contact in a high vacuum condition, a significantly undercooled state up to 400 deg. C is maintained before recalescence followed by solidification. Spherical single crystals of Nb are formed by the ESL process due to the suppression of heterogeneous nucleation. The field dependence of magnetization of Nb shows a reversible behavior as an ideal type II superconductor, implying that it contains almost no flux-pinning centers.

  5. Development of photonic crystals using sol-gel process for high power laser applications

    International Nuclear Information System (INIS)

    Benoit, Florence

    2015-01-01

    Three-dimensional photonic crystals (PCs) are periodic materials with a modulated refractive index on a length scale close to the light wavelength. This optical property allows the preparation of specific optical components like highly reflective mirrors. Moreover, these structured materials might have a high laser-induced damage threshold (LIDT) in the sub-nanosecond range compared to multilayered dielectric mirrors. This property is obtained because only one high LIDT material (silica) is used. In this work, we present the development of 3D PCs with narrow-sized colloidal silica particles, prepared by sol-gel process and deposited with Langmuir-Blodgett technique. Different syntheses routes have been investigated and compared regarding the optical properties of the PCs. A numerical model based on an ideal opal network including defect influence is used to explain these experimental results. (author) [fr

  6. Theoretical investigations of the meltoff and resolidification process of fuel claddings during accidents in liquid metal cooled fast breeder reactors

    International Nuclear Information System (INIS)

    Angerer, G.

    1978-08-01

    During loss-of-coolant-flow accidents in liquid metal cooled fast breeder reactors with failure to scram the fuel claddings will melt after boiling and evaporation of the coolant. The CMOT model presented here describes the subsequent process of relocation and resolidification of the molten claddings. The basic thermohydrodynamics equations of the two-phase flow of cladding material and sodium vapor are solved numerically by differential approximations in a Eulerian reference net. The results calculated by the model improved the insight into the dynamics of the cladding relocation process. Here are the main results: - Shortly after the onset of cladding relocation large waves of molten cladding material are generated. The motion of these waves contributes considerably to the material transport. - The dynamics of cladding relocation exhibits strong local incoherences. - The formation of cladding blockages observed at the ends of the fuel region is confirmed by the calculations. - In case of incoherent cladding meltoff less cladding material is transported upwards. - Cladding relocation strongly depends on the axial pressure drop and the underlying friction factor correlations. Recalculation of the R5 loss-of-coolant-flow experiment performed in the U.S. TREAT test reactor is in good agreement with the experimental data. (orig./HP) 891 HP [de

  7. Crystallization of nuclear glass under a thermal gradient: application to the self-crucible produced in the skull melting process

    International Nuclear Information System (INIS)

    Delattre, O.

    2013-01-01

    In the context of the vitrification of high level nuclear waste, a new industrial process has been launched in 2010 at the La Hague factory: The skull melting process. This setup applies thermal gradients to the melt, which leads to the formation of a solid layer of glass: the 'self-crucible'. The question would be to know whether these thermal gradients have an impact or not on the crystallization behaviour of the considered glasses in the self crucible. In order to answer that question, the crystallization of two glass compositions of nuclear interest has been investigated with an image analysis based method in isothermal and thermal gradient heat treatments conditions. The isothermal experiments allow for the quantification (growth speed, nucleation, crystallized fraction) of the crystallization of apatites (660 C-900 C) and powellites (630 C-900 C). The comparison of the results obtained through these two types of experimentations allows us to conclude that there is no impact of the thermal gradient on the crystallization of the studied glass compositions. In order to complete the image analysis study (based on surfaces), in and ex situ microtomography experiments have been performed at ESRF (Grenoble) on the ID19 beamline. This study allowed us to follow the crystallization of apatites in a simplified glass and to confirm the reliability of the image analysis method based on the analysis of surfaces. (author) [fr

  8. Investigation of the process of co-crystallization of barium and strontium nitrates from the system acetic acid-water

    International Nuclear Information System (INIS)

    Hubicki, W.; Piskorek, M.

    1976-01-01

    Co-crystallization of barium nitrate and strontium nitrate from the system CH 3 COOH-H 2 O was investigated by using radioactive tracer Ba 133 . The authors have found that during the crystallization of strontium nitrate from acetic acid solution at 25 0 C, one can obtain a 67-fold lowering of the content of barium in strontium nitrate, a 40-fold lowering of the content of barium in strontium nitrate is at 35 0 C. Strontium nitrate went to the solid phase with 70% efficiency. Acetic acid solutions of 24.5-24.3 per cent weight were used. Attention was paid to the franctionation of barium admixtures during crystallization of strontium nitrate from acetic acid solutions (so called ''isothermic salting out crystallization process'') is in agreement with the logarithmic law of Doerner-Hoskins. Process is characterized by a constant coefficient of surface co-crystallization lambda = 18. The results of investigations show that it is possible to obtain spectrally pure non-barium strontium nitrate as the result of its crystallization from the system CH 3 COOH-H 2 O at a temperature of 25 0 and 35 0 C. (author)

  9. Theory of tapered laser cooling

    International Nuclear Information System (INIS)

    Okamoto, Hiromi; Wei, J.

    1998-01-01

    A theory of tapered laser cooling for fast circulating ion beams in a storage ring is constructed. The authors describe the fundamentals of this new cooling scheme, emphasizing that it might be the most promising way to beam crystallization. The cooling rates are analytically evaluated to study the ideal operating condition. They discuss the physical implication of the tapering factor of cooling laser, and show how to determine its optimum value. Molecular dynamics method is employed to demonstrate the validity of the present theory

  10. Investigate earing of TWIP steel sheet during deep-drawing process by using crystal plasticity constitutive model

    Directory of Open Access Journals (Sweden)

    Yang J.

    2015-01-01

    Full Text Available By combining the nonlinear finite element analysis techniques and crystal plasticity theory, the macroscopic mechanical behaviour of crystalline material, the texture evolution and earing-type characteristics are simulated accurately. In this work, a crystal plasticity model exhibiting deformation twinning is introduced based on crystal plasticity theory and saturation-type hardening laws for FCC metal Fe-22Mn-0.6C TWIP steel. Based on the CPFE model and parameters which have been determined for TWIP steel, a simplified finite element model for deep drawing is promoted by using crystal plasticity constitutive model. The earing characteristics in typical deep-drawing process are simulated well. Further, the drawing forces are calculated and compared to the experimental results from reference. Meanwhile, the impacts of drawing coefficient and initial texture on the earing characteristics are investigated for controlling the earing.

  11. Planar nucleation and crystallization in the annealing process of ion implanted silicon

    International Nuclear Information System (INIS)

    Luo Yimin; Chen Zhenhua; Chen Ding

    2010-01-01

    According to thermodynamic and kinetic theory, considering the variation of bulk free energy and superficial energy after nucleation as well as the migration of atoms, we study systematically the planar nucleation and crystallization that relate to two possible transition mechanisms in the annealing process of ion implanted Si: (1) liquid/solid transition: the critical nucleation work is equal to half the increased superficial energy and inversely proportional to the supercooling ΔT. Compared with bulk nucleation, the radius of the critical nucleus decreases by half, and the nucleation rate attains its maximum at T = T m /2. (2) amorphous/crystalline transition: the atoms contained in the critical nucleus and situated on its surface, as well as critical nucleation work, are all directly proportional to the height of the nucleus, and the nucleation barrier is equal to half the superficial energy too. In addition, we take SiGe semiconductor as a specific example for calculation; a value of 0.03 eV/atom is obtained for the elastic strain energy, and a more reasonable result can be gotten after taking into account its effect on transition Finally, we reach the following conclusion as a result of the calculation: for the annealing of ion implanted Si, no matter what the transition method is-liquid or solid planar nucleation-the recrystallization process is actually carried out layer by layer on the crystal substrate, and the probability of forming a 'rod-like' nucleus is much larger than that of a 'plate-like' nucleus. (semiconductor materials)

  12. In-line monitoring and interpretation of an indomethacin anti-solvent crystallization process by near-infrared spectroscopy (NIRS).

    Science.gov (United States)

    Lee, Hea-Eun; Lee, Min-Jeong; Kim, Woo-Sik; Jeong, Myung-Yung; Cho, Young-Sang; Choi, Guang Jin

    2011-11-28

    PAT (process analytical technology) has been emphasized as one of key elements for the full implementation of QbD (quality-by-design) in the pharmaceutical area. NIRS (near-infrared spectroscopy) has been studied intensively as an in-line/on-line monitoring tool in chemical and biomedical industries. A precise and reliable monitoring of the particle characteristics during crystallization along with a suitable control strategy should be highly encouraged for the conformance to new quality system of pharmaceutical products. In this study, the anti-solvent crystallization process of indomethacin (IMC) was monitored using an in-line NIRS. IMC powders were produced via anti-solvent crystallization using two schemes; 'S-to-A' (solvent-to-antisolvent) and 'A-to-S' (antisolvent-to-solvent). In-line NIR spectra were analyzed by a PCA (principal component analysis) method. Although pure α-form IMC powder was resulted under A-to-S scheme, a mixture of the α-form and γ-form was produced for S-to-A case. By integrating the PCA results with off-line characterization (SEM, XRD, DSC) data, the crystallization process under each scheme was elucidated by three distinct consecutive steps. It was demonstrated that in-line NIRS, combined with PCA, can be very useful to monitor in real time and interpret the anti-solvent crystallization process with respect to the polymorphism and particle size. Copyright © 2011 Elsevier B.V. All rights reserved.

  13. Cooling towers

    International Nuclear Information System (INIS)

    Boernke, F.

    1975-01-01

    The need for the use of cooling systems in power plant engineering is dealt with from the point of view of a non-polluting form of energy production. The various cooling system concepts up to the modern natural-draught cooling towers are illustrated by examples. (TK/AK) [de

  14. Process design and simulation for optimizing the oxygen concentration in Czochralski-grown single-crystal silicon

    International Nuclear Information System (INIS)

    Jung, Y. J.; Kim, W. K.; Jung, J. H.

    2014-01-01

    The highest-concentration impurity in a single-crystal silicon ingot is oxygen, which infiltrates the ingot during growth stage. This oxygen adversely affects the wafer is quality. This study was aimed at finding an optimal design for the Czochralski (Cz) process to enable high-quality and low cost (by reducing power consumption) wafer production by controlling the oxygen concentration in the silicon ingots. In the Cz process, the characteristics of silicon ingots during crystallization are greatly influenced by the design and the configuration of the hot zone, and by crystallization rate. In order to identify process conditions for obtaining an optimal oxygen concentration of 11 - 13 ppma (required for industrial-grade ingots), designed two shield shapes for the hot zone. Furthermore, oxygen concentrations corresponding to these two shapes were compared by evaluating each shape at five different production speeds. In addition, simulations were performed to identify the optimal shield design for industrial applications.

  15. Process design and simulation for optimizing the oxygen concentration in Czochralski-grown single-crystal silicon

    Energy Technology Data Exchange (ETDEWEB)

    Jung, Y. J.; Kim, W. K.; Jung, J. H. [Yeungnam University, Gyeongsan (Korea, Republic of)

    2014-08-15

    The highest-concentration impurity in a single-crystal silicon ingot is oxygen, which infiltrates the ingot during growth stage. This oxygen adversely affects the wafer is quality. This study was aimed at finding an optimal design for the Czochralski (Cz) process to enable high-quality and low cost (by reducing power consumption) wafer production by controlling the oxygen concentration in the silicon ingots. In the Cz process, the characteristics of silicon ingots during crystallization are greatly influenced by the design and the configuration of the hot zone, and by crystallization rate. In order to identify process conditions for obtaining an optimal oxygen concentration of 11 - 13 ppma (required for industrial-grade ingots), designed two shield shapes for the hot zone. Furthermore, oxygen concentrations corresponding to these two shapes were compared by evaluating each shape at five different production speeds. In addition, simulations were performed to identify the optimal shield design for industrial applications.

  16. Large-scale membrane transfer process: its application to single-crystal-silicon continuous membrane deformable mirror

    International Nuclear Information System (INIS)

    Wu, Tong; Sasaki, Takashi; Hane, Kazuhiro; Akiyama, Masayuki

    2013-01-01

    This paper describes a large-scale membrane transfer process developed for the construction of large-scale membrane devices via the transfer of continuous single-crystal-silicon membranes from one substrate to another. This technique is applied for fabricating a large stroke deformable mirror. A bimorph spring array is used to generate a large air gap between the mirror membrane and the electrode. A 1.9 mm × 1.9 mm × 2 µm single-crystal-silicon membrane is successfully transferred to the electrode substrate by Au–Si eutectic bonding and the subsequent all-dry release process. This process provides an effective approach for transferring a free-standing large continuous single-crystal-silicon to a flexible suspension spring array with a large air gap. (paper)

  17. Anodic processes in the chemical and electrochemical etching of Si crystals in acid-fluoride solutions: Pore formation mechanism

    Energy Technology Data Exchange (ETDEWEB)

    Ulin, V. P.; Ulin, N. V.; Soldatenkov, F. Yu., E-mail: f.soldatenkov@mail.ioffe.ru [Ioffe Physical–Technical Institute (Russian Federation)

    2017-04-15

    The interaction of heavily doped p- and n-type Si crystals with hydrofluoric acid in the dark with and without contact with metals having greatly differing work functions (Ag and Pd) is studied. The dependences of the dissolution rates of Si crystals in HF solutions that contain oxidizing agents with different redox potentials (FeCl{sub 3}, V{sub 2}O{sub 5} and CrO{sub 3}) on the type and level of silicon doping are determined. Analysis of the experimental data suggests that valence-band holes in silicon are not directly involved in the anodic reactions of silicon oxidation and dissolution and their generation in crystals does not limit the rate of these processes. It is also shown that the character and rate of the chemical process leading to silicon dissolution in HF-containing electrolytes are determined by the interfacial potential attained at the semiconductor–electrolyte interface. The mechanism of electrochemical pore formation in silicon crystals is discussed in terms of selfconsistent cooperative reactions of nucleophilic substitution between chemisorbed fluorine anions and coordination- saturated silicon atoms in the crystal subsurface layer. A specific feature of these reactions for silicon crystals is that vacant nonbonding d{sup 2}sp{sup 3} orbitals of Si atoms, associated with sixfold degenerate states corresponding to the Δ valley of the conduction band, are involved in the formation of intermediate complexes. According to the suggested model, the pore-formation process spontaneously develops in local regions of the interface under the action of the interfacial potential in the adsorption layer and occurs as a result of the detachment of (SiF{sub 2}){sub n} polymer chains from the crystal. Just this process leads to the preferential propagation of pores along the <100> crystallographic directions. The thermodynamic aspects of pore nucleation and the effect of the potential drop across the interface, conduction type, and free-carrier concentration

  18. Monolithic I-Beam Crystal Monochromator

    Energy Technology Data Exchange (ETDEWEB)

    Bagnasco, John

    2001-10-16

    Curved crystal, focusing monochromators featuring cubed-root thickness profiles typically employ side-clamped cooling to reduce thermally induced overall bend deformation of the crystal. While performance is improved, residual bend deformation is often an important limiting factor in the monochromator performance. A slightly asymmetric ``I-beam'' crystal cross section with cubed-root flange profiles has been developed to further reduce this effect. Physical motivation, finite-element modeling evaluation and performance characteristics of this design are discussed. Reduction of high mounting stress at the fixed end of the crystal required the soldering of an Invar support fixture to the crystal. Detailed descriptions of this process along with its performance characteristics are also presented.

  19. Semantic modeling of the structural and process entities during plastic deformation of crystals and rocks

    Science.gov (United States)

    Babaie, Hassan; Davarpanah, Armita

    2016-04-01

    We are semantically modeling the structural and dynamic process components of the plastic deformation of minerals and rocks in the Plastic Deformation Ontology (PDO). Applying the Ontology of Physics in Biology, the PDO classifies the spatial entities that participate in the diverse processes of plastic deformation into the Physical_Plastic_Deformation_Entity and Nonphysical_Plastic_Deformation_Entity classes. The Material_Physical_Plastic_Deformation_Entity class includes things such as microstructures, lattice defects, atoms, liquid, and grain boundaries, and the Immaterial_Physical_Plastic_Deformation_Entity class includes vacancies in crystals and voids along mineral grain boundaries. The objects under the many subclasses of these classes (e.g., crystal, lattice defect, layering) have spatial parts that are related to each other through taxonomic (e.g., Line_Defect isA Lattice_Defect), structural (mereological, e.g., Twin_Plane partOf Twin), spatial-topological (e.g., Vacancy adjacentTo Atom, Fluid locatedAlong Grain_Boundary), and domain specific (e.g., displaces, Fluid crystallizes Dissolved_Ion, Void existsAlong Grain_Boundary) relationships. The dynamic aspect of the plastic deformation is modeled under the dynamical Process_Entity class that subsumes classes such as Recrystallization and Pressure_Solution that define the flow of energy amongst the physical entities. The values of the dynamical state properties of the physical entities (e.g., Chemical_Potential, Temperature, Particle_Velocity) change while they take part in the deformational processes such as Diffusion and Dislocation_Glide. The process entities have temporal parts (phases) that are related to each other through temporal relations such as precedes, isSubprocessOf, and overlaps. The properties of the physical entities, defined under the Physical_Property class, change as they participate in the plastic deformational processes. The properties are categorized into dynamical, constitutive

  20. A computer-aided molecular design framework for crystallization solvent design

    DEFF Research Database (Denmark)

    Karunanithi, Arunprakash T.; Achenie, Luke E.K.; Gani, Rafiqul

    2006-01-01

    One of the key decisions in designing solution crystallization processes is the selection of solvents. In this paper, we present a computer-aided molecular design (CAMD) framework for the design and selection of solvents and/or anti-solvents for solution crystallization. The CAMD problem is formu......One of the key decisions in designing solution crystallization processes is the selection of solvents. In this paper, we present a computer-aided molecular design (CAMD) framework for the design and selection of solvents and/or anti-solvents for solution crystallization. The CAMD problem...... solvent molecules. Solvent design and selection for two types of solution crystallization processes namely cooling crystallization and drowning out crystallization are presented. In the first case study, the design of single compound solvent for crystallization of ibuprofen, which is an important...

  1. Magma oceanography. II - Chemical evolution and crustal formation. [lunar crustal rock fractional crystallization model

    Science.gov (United States)

    Longhi, J.

    1977-01-01

    A description is presented of an empirical model of fractional crystallization which predicts that slightly modified versions of certain of the proposed whole moon compositions can reproduce the major-element chemistry and mineralogy of most of the primitive highland rocks through equilibrium and fractional crystallization processes combined with accumulation of crystals and trapping of residual liquids. These compositions contain sufficient Al to form a plagioclase-rich crust 60 km thick on top of a magma ocean that was initially no deeper than about 300 km. Implicit in the model are the assumptions that all cooling and crystallization take place at low pressure and that there are no compositional or thermal gradients in the liquid. Discussions of the cooling and crystallization of the proposed magma ocean show these assumptions to be disturbingly naive when applied to the ocean as a whole. However, the model need not be applied to the whole ocean, but only to layers of cooling liquid near the surface.

  2. Effect of γ-radiation on crystallization of polycaprolactone

    International Nuclear Information System (INIS)

    Zhu Guangming; Xu, Qianyong; Qin Ruifeng; Yan Hongxia; Liang Guozheng

    2005-01-01

    The crystallization behavior of radiation cross-linked poly(ε-caprolactone) (PCL) was studied by DSC at different cooling rates. The crystallization process was analyzed by the Ozawa equation and the Mo-Zhishen method that is developed from combining the Avrami equation and the Ozawa equation. It was concluded that the crystallization of radiation crosslinked PCL is governed by heterogeneous nucleation and single-dimension growth; the crystal fraction and rates of crystallization are related to the radiation dose and degree of cross-linking; the relationship between relative crystallinity and time follows the Ozawa equation: The higher the degree of crosslinking, the less the crystal velocity constant. The activation energy of crystallization for irradiated PCL is between 65 and 54kJ/mol

  3. Experimental evaluation of desuperheating and oil cooling process through liquid injection in two-staged ammonia refrigeration systems with screw compressors

    International Nuclear Information System (INIS)

    Zlatanović, Ivan; Rudonja, Nedžad

    2012-01-01

    This paper examines the problem of achieving desuperheating through liquid injection in two-staged refrigeration systems based on screw compressors. The oil cooling process by refrigerant injection is also included. The basic thermodynamic principles of desuperheating and compressor cooling as well as short comparison with traditional method with a thermosyphon system have also been presented. Finally, the collected data referring to a big refrigeration plant are analyzed in the paper. Specific ammonia system concept applied in this refrigeration plant has demonstrated its advantages and disadvantages. - Highlights: ► An experiment was setup during a frozen food factory refrigeration system reconstruction and adaptation. ► Desuperheating and low-stage compressors oil cooling process were investigated. ► Efficiency of compression process and high-stage compressors functioning were examined. ► Evaporation temperature reduction has great influence on the need for injected liquid refrigerant. ► Several cases in which desuperheating and oil cooling process application are justified were determined.

  4. Gas-cooled reactor commercialization study: introduction scenario and commercialization analyses for process heat applications. Final report, July 8, 1977--November 30, 1977

    International Nuclear Information System (INIS)

    1977-12-01

    This report identifies and presents an introduction scenario which can lead to the operation of High Temperature Gas Cooled Reactor demonstration plants for combined process heat and electric power generation applications, and presents a commercialization analysis relevant to the organizational and management plans which could implement a development program

  5. Gas-cooled reactor commercialization study: introduction scenario and commercialization analyses for process heat applications. Final report, July 8, 1977--November 30, 1977

    Energy Technology Data Exchange (ETDEWEB)

    1977-12-01

    This report identifies and presents an introduction scenario which can lead to the operation of High Temperature Gas Cooled Reactor demonstration plants for combined process heat and electric power generation applications, and presents a commercialization analysis relevant to the organizational and management plans which could implement a development program.

  6. Effect of surfactants or a water soluble polymer on the crystal transition of clarithromycin during a wet granulation process.

    Science.gov (United States)

    Nozawa, Kenji; Iwao, Yasunori; Noguchi, Shuji; Itai, Shigeru

    2015-11-10

    To generate products containing a stable form of clarithromycin (CAM) (form II) regardless of the initial crystal form of CAM or type of granulation solvent, the effects of five surfactants, or a water-soluble polymer (macrogol 400) were determined on the crystal transition of CAM. The metastable form (form I) was kneaded with water, after adding surfactants, or a water-soluble polymer. Form II was also kneaded with ethanol, after adding the same additives. The resulting samples were analyzed by powder X-ray diffraction. Form I was completely converted to form II by a wet granulation using water with additives bearing polyoxyethylene chains such as polysorbate 80 (PS80), polyoxyl 40 stearate or macrogol 400. The granulation of the form II using ethanol with these additives did not result in a crystal transition to form I. Furthermore, CAM tablets were manufactured using granules with PS80, and these crystal forms and dissolution behaviors were investigated. As a result, the wet granulation of CAM with PS80 gave CAM tablets containing only form II and PS80 did not have any adverse effects on tablet characteristics. Therefore, these data suggests that the crystal form of CAM can be controlled to be form II using a wet granulation process with additives bearing polyoxyethylene chains regardless of the initial crystal form of CAM or type of granulation solvent. Copyright © 2015 Elsevier B.V. All rights reserved.

  7. Crystal Structure of the HEAT Domain from the Pre-mRNA Processing Factor Symplekin

    Energy Technology Data Exchange (ETDEWEB)

    Kennedy, Sarah A.; Frazier, Monica L.; Steiniger, Mindy; Mast, Ann M.; Marzluff, William F.; Redinbo, Matthew R.; (UNC)

    2010-09-30

    The majority of eukaryotic pre-mRNAs are processed by 3'-end cleavage and polyadenylation, although in metazoa the replication-dependent histone mRNAs are processed by 3'-end cleavage but not polyadenylation. The macromolecular complex responsible for processing both canonical and histone pre-mRNAs contains the {approx} 1160-residue protein Symplekin. Secondary-structural prediction algorithms identified putative HEAT domains in the 300 N-terminal residues of all Symplekins of known sequence. The structure and dynamics of this domain were investigated to begin elucidating the role Symplekin plays in mRNA maturation. The crystal structure of the Drosophila melanogaster Symplekin HEAT domain was determined to 2.4 {angstrom} resolution with single-wavelength anomalous dispersion phasing methods. The structure exhibits five canonical HEAT repeats along with an extended 31-amino-acid loop (loop 8) between the fourth and fifth repeat that is conserved within closely related Symplekin sequences. Molecular dynamics simulations of this domain show that the presence of loop 8 dampens correlated and anticorrelated motion in the HEAT domain, therefore providing a neutral surface for potential protein-protein interactions. HEAT domains are often employed for such macromolecular contacts. The Symplekin HEAT region not only structurally aligns with several established scaffolding proteins, but also has been reported to contact proteins essential for regulating 3'-end processing. Together, these data support the conclusion that the Symplekin HEAT domain serves as a scaffold for protein-protein interactions essential to the mRNA maturation process.

  8. Three-dimensional Random Voronoi Tessellations: From Cubic Crystal Lattices to Poisson Point Processes

    OpenAIRE

    Lucarini, Valerio

    2008-01-01

    We perturb the SC, BCC, and FCC crystal structures with a spatial Gaussian noise whose adimensional strength is controlled by the parameter a, and analyze the topological and metrical properties of the resulting Voronoi Tessellations (VT). The topological properties of the VT of the SC and FCC crystals are unstable with respect to the introduction of noise, because the corresponding polyhedra are geometrically degenerate, whereas the tessellation of the BCC crystal is topologically stable eve...

  9. Direct transmission electron microscopy observations of martensitic transformations in Ni-rich NiTi single crystals during in situ cooling and straining

    Czech Academy of Sciences Publication Activity Database

    Kröger, A.; Dziaszyk, S.; Frenzel, J.; Somsen, Ch.; Dlouhý, Antonín; Eggeler, G.

    2008-01-01

    Roč. 481, Sp. Iss. (2008), s. 452-456 ISSN 0921-5093. [ESOMAT 2006. Bochum, 10.09.2006-15.09.2006] Institutional research plan: CEZ:AV0Z20410507 Keywords : In situ TEM * NiTi single crystal * Martensitic transformations Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.806, year: 2008

  10. Orientation selection process during the early stage of cubic dendrite growth: A phase-field crystal study

    International Nuclear Information System (INIS)

    Tang Sai; Wang Zhijun; Guo Yaolin; Wang Jincheng; Yu Yanmei; Zhou Yaohe

    2012-01-01

    Using the phase-field crystal model, we investigate the orientation selection of the cubic dendrite growth at the atomic scale. Our simulation results reproduce how a face-centered cubic (fcc) octahedral nucleus and a body-centered cubic (bcc) truncated-rhombic dodecahedral nucleus choose the preferred growth direction and then evolve into the dendrite pattern. The interface energy anisotropy inherent in the fcc crystal structure leads to the fastest growth velocity in the 〈1 0 0〉 directions. New { 1 1 1} atomic layers prefer to nucleate at positions near the tips of the fcc octahedron, which leads to the directed growth of the fcc dendrite tips in the 〈1 0 0〉 directions. A similar orientation selection process is also found during the early stage of bcc dendrite growth. The orientation selection regime obtained by phase-field crystal simulation is helpful for understanding the orientation selection processes of real dendrite growth.

  11. Re-Engineering Control Systems using Automatic Generation Tools and Process Simulation: the LHC Water Cooling Case

    CERN Document Server

    Booth, W; Bradu, B; Gomez Palacin, L; Quilichini, M; Willeman, D

    2014-01-01

    This paper presents the approach used at CERN (European Organization for Nuclear Research) to perform the re-engineering of the control systems dedicated to the LHC (Large Hadron Collider) water cooling systems.

  12. Adsorption of crystal violet with diatomite earth&carbon by a modification of hydrothermal carbonization process.

    Science.gov (United States)

    Zhang, Yanzhuo; Li, Jun; Chen, Guanghui; Bian, Wei; Lu, Yun; Li, Wenjing; Zheng, Zhaoming; Cheng, Xiaojie

    2016-01-01

    The high colority and difficulty of decolorization are the most important tasks on printing and dyeing wastewater. This study investigates the ability of diatomite earth&carbon (DE&C) as an adsorbent to removal crystal violet (CV) from aqueous solutions. Fourier transform infrared spectroscopy results indicate the importance of functional groups during the adsorption of CV. The obtained N2 adsorption-desorption isotherm values accord with well IUPAC type II. Our calculations determined a surface area of 73.15 m(2) g(-1) for DE&C and an average pore diameter of 10.56 nm. Equilibrium data of the adsorption process fitted very well to the Langmuir model (R(2) > 0.99). The results of kinetics study showed that the pseudo-second-order model fitted to the experimental data well. The thermodynamic parameters were also evaluated. ΔH° 0 and ΔG° < 0 demonstrated that the adsorption process was spontaneous and exothermic for dye. Furthermore the positive value of ΔS° reflected good affinity of the CV dye.

  13. High-performance and flexible thermoelectric films by screen printing solution-processed nanoplate crystals.

    Science.gov (United States)

    Varghese, Tony; Hollar, Courtney; Richardson, Joseph; Kempf, Nicholas; Han, Chao; Gamarachchi, Pasindu; Estrada, David; Mehta, Rutvik J; Zhang, Yanliang

    2016-09-12

    Screen printing allows for direct conversion of thermoelectric nanocrystals into flexible energy harvesters and coolers. However, obtaining flexible thermoelectric materials with high figure of merit ZT through printing is an exacting challenge due to the difficulties to synthesize high-performance thermoelectric inks and the poor density and electrical conductivity of the printed films. Here, we demonstrate high-performance flexible films and devices by screen printing bismuth telluride based nanocrystal inks synthesized using a microwave-stimulated wet-chemical method. Thermoelectric films of several tens of microns thickness were screen printed onto a flexible polyimide substrate followed by cold compaction and sintering. The n-type films demonstrate a peak ZT of 0.43 along with superior flexibility, which is among the highest reported ZT values in flexible thermoelectric materials. A flexible thermoelectric device fabricated using the printed films produces a high power density of 4.1 mW/cm(2) with 60 °C temperature difference between the hot side and cold side. The highly scalable and low cost process to fabricate flexible thermoelectric materials and devices demonstrated here opens up many opportunities to transform thermoelectric energy harvesting and cooling applications.

  14. Subsurface damage mechanism of high speed grinding process in single crystal silicon revealed by atomistic simulations

    International Nuclear Information System (INIS)

    Li, Jia; Fang, Qihong; Zhang, Liangchi; Liu, Youwen

    2015-01-01

    Highlights: • Molecular dynamic model of nanoscale high speed grinding of silicon workpiece has been established. • The effect of grinding speed on subsurface damage and grinding surface integrity by analyzing the chip, dislocation movement, and phase transformation during high speed grinding process are thoroughly investigated. • Subsurface damage is studied by the evolution of surface area at first time for more obvious observation on transition from ductile to brittle. • The hydrostatic stress and von Mises stress by the established analytical model are studied subsurface damage mechanism during nanoscale grinding. - Abstract: Three-dimensional molecular dynamics (MD) simulations are performed to investigate the nanoscale grinding process of single crystal silicon using diamond tool. The effect of grinding speed on subsurface damage and grinding surface integrity by analyzing the chip, dislocation movement, and phase transformation are studied. We also establish an analytical model to calculate several important stress fields including hydrostatic stress and von Mises stress for studying subsurface damage mechanism, and obtain the dislocation density on the grinding subsurface. The results show that a higher grinding velocity in machining brittle material silicon causes a larger chip and a higher temperature, and reduces subsurface damage. However, when grinding velocity is above 180 m s −1 , subsurface damage thickness slightly increases because a higher grinding speed leads to the increase in grinding force and temperature, which accelerate dislocation nucleation and motion. Subsurface damage is studied by the evolution of surface area at first time for more obvious observation on transition from ductile to brittle, that provides valuable reference for machining nanometer devices. The von Mises stress and the hydrostatic stress play an important role in the grinding process, and explain the subsurface damage though dislocation mechanism under high

  15. Optimization of induced crystallization reaction in a novel process of nutrients removal coupled with phosphorus recovery from domestic wastewater

    Directory of Open Access Journals (Sweden)

    Zou Haiming

    2017-12-01

    Full Text Available Phosphorus removal and recovery from domestic wastewater is urgent nowadays. A novel process of nutrients removal coupled with phosphorus recovery from domestic sewage was proposed and optimization of induced crystallization reaction was performed in this study. The results showed that 92.3% of phosphorus recovery via induced Hydroxyapatite crystallization was achieved at the optimum process parameters: reaction time of 80 min, seed crystal loads of 60 g/L, pH of 8.5, Ca/P mole ratio of 2.0 and 4.0 L/min aeration rate when the PO43--P concentration was 10 mg/L in the influent, displaying an excellent phosphorus recovery performance. Importantly, it was found that the effect of reaction temperature on induced Hydroxyapatite crystallization was slight, thus favoring practical application of phosphorus recovery method described in this study. From these results, the proposed method of induced HAP crystallization to recover phosphorus combined with nutrients removal can be an economical and effective technology, probably favoring the water pollution control and phosphate rock recycle.

  16. Process development and characterization of centrosymmetric semiorganic nonlinear optical crystal: 4-dimethylaminopyridine potassium chloride

    Science.gov (United States)

    Johnson, J.; Srineevasan, R.; Sivavishnu, D.

    2018-06-01

    Centrosymmetric semiorganic crystal 4-dimethylaminopyridine potassium chloride (4-DMAPKC) has been grown successfully by using slow evaporation solution growth technique. Powder x-ray diffraction shows the 4-DMAPKC crystal has good crystalline nature. Single crystal XRD shows that the grown 4-DMAPKC is cubic crystal system with cell parameters a = 3.09 Å, b = 3.09 Å, c = 3.09 Å. Investigation has been carried out to assign the Vibrational frequencies of the grown crystal by FTIR spectral studies. UVsbnd Visible NIR optical absorption spectral studies in the range of 200-1100 nm shows low absorption in UVsbnd Visible region with lower cutoff wave length at 261 nm and optical band gap energy was found as Eg = 5.52 eV. Optically transmittance spectral shows 4-DMAPKC crystal is very good transparency in UV-Visible NIR region. Thermogravimetry and differential thermal (TG-DTA) analysis were carried out. Dielectric studies of as grown crystal sample exhibit low dielectric constant and loss at higher frequencies and attests the nonlinear optical activity. Micro hardness studies of as grown crystal were discussed. Second harmonic generation (SHG) efficiency of the 4-DMAPKC is 0.69 times as that of KDP.

  17. Development of a task-based design approach for solution crystallization processes

    NARCIS (Netherlands)

    Lakerveld, R.

    2010-01-01

    Crystallization is historically one of the most important separation and product formation technologies in chemical industry. The future impact of crystallization is expected to increase as new high-added value products are often in crystalline form and need to comply with increasingly stringent

  18. The X'tal cube PET detector with a monolithic crystal processed by the 3D sub-surface laser engraving technique: Performance comparison with glued crystal elements

    Energy Technology Data Exchange (ETDEWEB)

    Yoshida, Eiji, E-mail: rush@nirs.go.jp [Molecular Imaging Center, National Institute of Radiological Sciences, 4-9-1 Anagawa, Inage-ku, Chiba 263-8555 (Japan); Hirano, Yoshiyuki; Tashima, Hideaki; Inadama, Naoko; Nishikido, Fumihiko [Molecular Imaging Center, National Institute of Radiological Sciences, 4-9-1 Anagawa, Inage-ku, Chiba 263-8555 (Japan); Moriya, Takahiro; Omura, Tomohide; Watanabe, Mitsuo [Hamamatsu Photonics K.K., 5000 Hirakuchi, Hamakita-ku, Hamamatsu, Shizuoka 434-8601 (Japan); Murayama, Hideo; Yamaya, Taiga [Molecular Imaging Center, National Institute of Radiological Sciences, 4-9-1 Anagawa, Inage-ku, Chiba 263-8555 (Japan)

    2013-09-21

    The X'tal cube is a depth-of-interaction (DOI)-PET detector which is aimed at obtaining isotropic resolution by effective readout of scintillation photons from six sides of the crystal block. The X'tal cube is composed of a 3D crystal block with isotropic segments. Each face of the 3D crystal block is covered with a 4×4 array of multi-pixel photon counters (MPPCs). Previously, in order to fabricate the 3D crystal block efficiently and precisely, we applied a sub-surface laser engraving technique to a monolithic crystal block instead of gluing segmented small crystals. A dense arrangement of multiple micro-cracks carved by the laser beam works efficiently as a scattering wall for the scintillation photons. The X'tal cube with the laser-processed block showed excellent performance with respect to crystal identification and energy resolution. In this work, for characteristics comparison between the laser-processed block and the conventional segmented array block, we made the laser-processed block and two types of segmented array blocks, one with air gaps and the other with glued segmented small crystals. All crystal blocks had 3D grids of 2 mm pitch. The 4×4 MPPC arrays were optically coupled to each surface of the crystal block. When performance was evaluated using a uniform irradiation of 511 keV, we found that the X'tal cubes with the laser-processed block could easily achieve 2 mm{sup 3} uniform crystal identification. Also, the average energy resolution of each 3D grid was 11.1±0.7%. On the other hand, the glued segmented array block had a pinched distribution and crystals could not be separated clearly. The segmented array block with air gaps had satisfactory crystal identification performance; however, the laser-processed block had higher crystal identification performance. Also, the energy resolution of the laser-processed block was better than for the segmented array blocks. In summary, we found the laser-processed X'tal cube had

  19. Spray cooling

    International Nuclear Information System (INIS)

    Rollin, Philippe.

    1975-01-01

    Spray cooling - using water spraying in air - is surveyed as a possible system for make-up (peak clipping in open circuit) or major cooling (in closed circuit) of the cooling water of the condensers in thermal power plants. Indications are given on the experiments made in France and the systems recently developed in USA, questions relating to performance, cost and environmental effects of spray devices are then dealt with [fr

  20. Spherical Nb single crystals containerlessly grown by electrostatic levitation

    International Nuclear Information System (INIS)

    Sung, Y.S.; Takeya, H.; Hirata, K.; Togano, K.

    2003-01-01

    Spherical Nb (T m =2750 K) single crystals were grown via containerless electrostatic levitation (ESL). Samples became spherical at melting in levitation and undercooled typically 300-450 K prior to nucleation. As-processed samples were still spherical without any macroscopic shape change by solidification showing a uniform dendritic surface morphology. Crystallographic {111} planes exposed in equilateral triangular shapes on the surface by preferential macroetching and spotty back-reflection Laue patterns confirm the single crystal nature of the ESL-processed Nb samples. No hysteresis in magnetization between zero field and field cooling also implies a clean defect-free condition of the spherical Nb single crystals

  1. Optimization of anisotropic photonic density of states for Raman cooling of solids

    Science.gov (United States)

    Chen, Yin-Chung; Ghosh, Indronil; Schleife, André; Carney, P. Scott; Bahl, Gaurav

    2018-04-01

    Optical refrigeration of solids holds tremendous promise for applications in thermal management. It can be achieved through multiple mechanisms including inelastic anti-Stokes Brillouin and Raman scattering. However, engineering of these mechanisms remains relatively unexplored. The major challenge lies in the natural unfavorable imbalance in transition rates for Stokes and anti-Stokes scattering. We consider the influence of anisotropic photonic density of states on Raman scattering and derive expressions for cooling in such photonically anisotropic systems. We demonstrate optimization of the Raman cooling figure of merit considering all possible orientations for the material crystal and two example photonic crystals. We find that the anisotropic description of the photonic density of states and the optimization process is necessary to obtain the best Raman cooling efficiency for systems having lower symmetry. This general result applies to a wide array of other laser cooling methods in the presence of anisotropy.

  2. Processing of FRG high-temperature gas-cooled reactor fuel elements at General Atomic under the US/FRG cooperative agreement for spent fuel elements

    International Nuclear Information System (INIS)

    Holder, N.D.; Strand, J.B.; Schwarz, F.A.; Drake, R.N.

    1981-11-01

    The Federal Republic of Germany (FRG) and the United States (US) are cooperating on certain aspects of gas-cooled reactor technology under an umbrella agreement. Under the spent fuel treatment development section of the agreement, both FRG mixed uranium/ thorium and low-enriched uranium fuel spheres have been processed in the Department of Energy-sponsored cold pilot plant for high-temperature gas-cooled reactor (HTGR) fuel processing at General Atomic Company in San Diego, California. The FRG fuel spheres were crushed and burned to recover coated fuel particles suitable for further treatment for uranium recovery. Successful completion of the tests described in this paper demonstrated certain modifications to the US HTGR fuel burining process necessary for FRG fuel treatment. Results of the tests will be used in the design of a US/FRG joint prototype headend facility for HTGR fuel

  3. Multi-response optimization of process parameters using Taguchi method and grey relational analysis during turning AA 7075/SiC composite in dry and spray cooling environments

    Directory of Open Access Journals (Sweden)

    P. C. Mishra

    2015-09-01

    Full Text Available Turning experiments were carried out on AA 7075/SiC composite workpiece in dry and spray cooling environments based on L16 Taguchi design of experiments. Multiple performance optimization of process parameters was performed using grey relational analysis. The performance characteristics considered were average surface roughness, cutting tool temperature and material removal rate. Uncoated carbide inserts were used for machining the workpiece in a high speed precision lathe. A grey relational grade obtained from grey relational analysis was used to optimize the process parameters. Optimal combination of process parameters was then determined by the Taguchi method using the grey relational grade as the performance index. Experimental results indicated that the turning in spray cooling environment was beneficial compared to that in dry environment for the quality response characteristics under consideration. Analysis of variance showed that feed was the most significant parameter for the multiple performance characteristics during turning in both the environments.

  4. Long wavelength approximation of transport processes in a single-band crystal

    International Nuclear Information System (INIS)

    Ferrari, Loris

    2014-01-01

    The single band, long wavelength approximation (SBA–LWA) is currently used in textbooks as a quasi-free-particle picture of the motion in a quantum crystal. The resulting transport process might thereby look a trivial issue. In contrast, we shall show that the SBA–LWA hides some controversial aspects that should be clarified at the level of an advanced course of condensed matter physics, and refer to the incompleteness of the SBA representation. In particular, it will be shown that the single-band velocity v 1B , expressed in terms of the projectors on the Bloch states, cannot be a transport velocity in a full sense, since the resulting current violates the continuity equation. The drawback manifests itself as a ‘lost’ current J lost , which provides a non conventional estimate of the limits of accuracy of SBA–LWA. The vanishing of J lost corresponds to the effective mass approximation in which the dispersion relation can be reduced to a quadratic form in the (pseudo) momentum components. In practice, the quantity transported by v 1B is not the bare mass, but the effective mass, until this notion does make sense. Recalling that the non-quadratic expression of the relativistic kinetic energy leads to a difference between the rest and moving mass, the notion of the lost current is finally used as a non-conventional approach to relativistic quantum mechanics, with special reference to Dirac’s theory. (paper)

  5. Crystallization kinetics of magnetic glass-ceramics prepared by the processing of waste materials

    International Nuclear Information System (INIS)

    Francis, A.A.

    2006-01-01

    The objective of the present investigation was to study the feasibility of conversion of an intimate mixture of blast furnace slag and blast furnace flue dust generated by a single industrial company into magnetic glass-ceramic product. Blast furnace slag (BFS) and blast furnace flue dust (BFD) are generated at a rate of 300,000 and 30,000 tons/year, respectively, from iron and steel factory. The crystallization mechanisms of a composition containing BFS and BFD in a 50/50 proportion were investigated by differential thermal analysis (DTA), X-ray diffraction (XRD) and scanning electron microscopy (SEM). The crystallization temperature was found to vary from 900 to 1100 deg. C and two phases appeared in the crystallized samples: pyroxene Ca(Mg, Fe, Al)(Si, Al) 2 O 6 and magnetite/maghemite. Heating rate and particle sizes effects on crystal growth of powdered samples were studied by DTA. The apparent activation energy of crystal growth using the particle size 180-315 μm was determined to be 355 and 329 kJ/mol for the first and second peak, respectively. The presence of sharp and broad crystallization peaks indicate simultaneous surface and internal crystallization mechanism. Good wear resistance and chemical durability particularly in alkaline environment, combine with good hardness and magnetic properties make this glass-ceramic material potentially useful for various industrial applications

  6. Formation of Piroxicam Polymorphism in Solution Crystallization

    DEFF Research Database (Denmark)

    Bruun Hansen, Thomas; Qu, Haiyan

    2015-01-01

    also explored, and new insights into polymorphic control are documented and discussed. The crystal landscape was mapped for cooling crystallization of piroxicam from acetone/water mixtures (0.5 K/min) and for antisolvent crystallization from acetone with water as the antisolvent. Varying cooling rates...

  7. Photophysical processes of ionic crystals exitation at photosorption and photocatalysis. Fotofizicheskie protsessy vozbuzhdeniya ionnykh kristallov pri fotovozbuzhdenii i fotokatalize

    Energy Technology Data Exchange (ETDEWEB)

    Ryabchuk, V K; Burukina, G V [Leningradskij Gosudarstvennyj Univ., Leningrad (Russian Federation). Nauchno-Issledovatel' skij Fizicheskij Inst.

    1991-06-01

    Processes of photoexcitation of wide-band oxides and alkali-halide crystals (AHC) within intrinsic absorption range, of impurity absorption and surface states and photoinduced colour centers resulting in development of centers of photosorption and photocatalysis are considered. Mechanisms of effect of photosorption of O[sub 2], H[sub 2], CH[sub 4] and other molecules on photostimulated defect formation in oxides and AHC as well as atomic and ionic processes in photosorption and photocatalysis are dicussed.

  8. Reactor core cooling device

    International Nuclear Information System (INIS)

    Kobayashi, Masahiro.

    1986-01-01

    Purpose: To safely and effectively cool down the reactor core after it has been shut down but is still hot due to after-heat. Constitution: Since the coolant extraction nozzle is situated at a location higher than the coolant injection nozzle, the coolant sprayed from the nozzle, is free from sucking immediately from the extraction nozzle and is therefore used effectively to cool the reactor core. As all the portions from the top to the bottom of the reactor are cooled simultaneously, the efficiency of the reactor cooling process is increased. Since the coolant extraction nozzle can be installed at a point considerably higher than the coolant injection nozzle, the distance from the coolant surface to the point of the coolant extraction nozzle can be made large, preventing cavitation near the coolant extraction nozzle. Therefore, without increasing the capacity of the heat exchanger, the reactor can be cooled down after a shutdown safely and efficiently. (Kawakami, Y.)

  9. Theoretical modelling and experimental study of air thermal conditioning process of a heat pump assisted solid desiccant cooling system

    DEFF Research Database (Denmark)

    Nie, Jinzhe; Li, Zan; Hu, Wenju

    2017-01-01

    purification aimed at improving indoor air quality and reducing building energy consumption. The heat and moisture transfer in adsorption desiccant rotor was theoretical modelled with one-dimensional partial differential equations. The theoretical model was validated with experimental measurements...... system, the energy performance of HP-SDC was more efficient mainly due to high efficient air purification capacity, reduction of cooling load and raised evaporation temperature. The energy performance of HP-SDC was sensitive to outdoor humidity ratio. Further improvements of HP-SDC energy efficiency......Taking the integrated gaseous contaminants and moisture adsorption potential of desiccant material, a new heat pump assisted solid desiccant cooling system (HP-SDC) was proposed based on the combination of desiccant rotor with heat pump. The HP-SDC was designed for dehumidification, cooling and air...

  10. Utilization of process energy from supermarket refrigeration systems. Coupling of cooling and heating; Prozessenergienutzung von Supermarktkaelteanlagen. Kaelte-Waerme-Kopplung

    Energy Technology Data Exchange (ETDEWEB)

    Wirsching, Alexander [TEKO Gesellschaft fuer Kaeltetechnik mbH, Altenstadt (Germany). Technologie und Kommunikation

    2010-03-15

    The efficiency is defined as the relation between utility and expenditure. Thus, it is obvious for the specialist of refrigeration to tackle with the expenditure (energy consumption) since the utilization conventionally is defined as the produced/need cooling performance of a refrigeration plant. If refrigeration plants are regarded according to their function (withdrawal of heat from a refrigeration chamber and delivery to the environment), the heating system is the producer of the requirement for cooling in 'the winter' (heating season). Thus, the refrigeration plant perhaps already has a marvellous efficiency, and the separate heating system too - however in interaction. The broad view moves into the focus. The possible approaches and effects are described in the contribution under consideration using the example of a Discount supermarket with a sales area of 800 square meters and a requirement of cooling of more than 30 kW.

  11. Solution processed deposition of electron transport layers on perovskite crystal surface—A modeling based study

    Energy Technology Data Exchange (ETDEWEB)

    Mortuza, S.M.; Taufique, M.F.N.; Banerjee, Soumik, E-mail: soumik.banerjee@wsu.edu

    2017-02-01

    Highlights: • The model determined the surface coverage of solution-processed film on perovskite. • Calculated surface density map provides insight into morphology of the monolayer. • Carbonyl oxygen atom of PCBM strongly attaches to the (110) surface of perovskite. • Uniform distribution of clusters on perovskite surface at lower PCBM concentration. • Deposition rate of PCBM on the surface is very high at initial stage of film growth. - Abstract: The power conversion efficiency (PCE) of planar perovskite solar cells (PSCs) has reached up to ∼20%. However, structural and chemicals defects that lead to hysteresis in the perovskite based thin film pose challenges. Recent work has shown that thin films of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) deposited on the photo absorption layer, using solution processing techniques, minimize surface pin holes and defects thereby increasing the PCE. We developed and employed a multiscale model based on molecular dynamics (MD) and kinetic Monte Carlo (kMC) to establish a relationship between deposition rate and surface coverage on perovskite surface. The MD simulations of PCBMs dispersed in chlorobenzene, sandwiched between (110) perovskite substrates, indicate that PCBMs are deposited through anchoring of the oxygen atom of carbonyl group to the exposed lead (Pb) atom of (110) perovskite surface. Based on rates of distinct deposition events calculated from MD, kMC simulations were run to determine surface coverage at much larger time and length scales than accessible by MD alone. Based on the model, a generic relationship is established between deposition rate of PCBMs and surface coverage on perovskite crystal. The study also provides detailed insights into the morphology of the deposited film.

  12. Solution processed deposition of electron transport layers on perovskite crystal surface—A modeling based study

    International Nuclear Information System (INIS)

    Mortuza, S.M.; Taufique, M.F.N.; Banerjee, Soumik

    2017-01-01

    Highlights: • The model determined the surface coverage of solution-processed film on perovskite. • Calculated surface density map provides insight into morphology of the monolayer. • Carbonyl oxygen atom of PCBM strongly attaches to the (110) surface of perovskite. • Uniform distribution of clusters on perovskite surface at lower PCBM concentration. • Deposition rate of PCBM on the surface is very high at initial stage of film growth. - Abstract: The power conversion efficiency (PCE) of planar perovskite solar cells (PSCs) has reached up to ∼20%. However, structural and chemicals defects that lead to hysteresis in the perovskite based thin film pose challenges. Recent work has shown that thin films of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) deposited on the photo absorption layer, using solution processing techniques, minimize surface pin holes and defects thereby increasing the PCE. We developed and employed a multiscale model based on molecular dynamics (MD) and kinetic Monte Carlo (kMC) to establish a relationship between deposition rate and surface coverage on perovskite surface. The MD simulations of PCBMs dispersed in chlorobenzene, sandwiched between (110) perovskite substrates, indicate that PCBMs are deposited through anchoring of the oxygen atom of carbonyl group to the exposed lead (Pb) atom of (110) perovskite surface. Based on rates of distinct deposition events calculated from MD, kMC simulations were run to determine surface coverage at much larger time and length scales than accessible by MD alone. Based on the model, a generic relationship is established between deposition rate of PCBMs and surface coverage on perovskite crystal. The study also provides detailed insights into the morphology of the deposited film.

  13. Coherent electron cooling

    Energy Technology Data Exchange (ETDEWEB)

    Litvinenko,V.

    2009-05-04

    Cooling intense high-energy hadron beams remains a major challenge in modern accelerator physics. Synchrotron radiation is still too feeble, while the efficiency of two other cooling methods, stochastic and electron, falls rapidly either at high bunch intensities (i.e. stochastic of protons) or at high energies (e-cooling). In this talk a specific scheme of a unique cooling technique, Coherent Electron Cooling, will be discussed. The idea of coherent electron cooling using electron beam instabilities was suggested by Derbenev in the early 1980s, but the scheme presented in this talk, with cooling times under an hour for 7 TeV protons in the LHC, would be possible only with present-day accelerator technology. This talk will discuss the principles and the main limitations of the Coherent Electron Cooling process. The talk will describe the main system components, based on a high-gain free electron laser driven by an energy recovery linac, and will present some numerical examples for ions and protons in RHIC and the LHC and for electron-hadron options for these colliders. BNL plans a demonstration of the idea in the near future.

  14. Investigation of melt structure and crystallization processes by high-temperature Raman spectroscopy method

    International Nuclear Information System (INIS)

    Voron'ko, Yu.K.; Kudryavtsev, A.B.; Osiko, V.V.; Sobol', A.A.

    1988-01-01

    A review of studies dealing with the melts of alkali, rare earth and other element phosphates, gallates, germanates, niobates and tungstates, which are carried out by the method of high-temperature Raman spectroscopy, is given. The effect of the melt structure on the mechanism of the substance cystallization is considered. It is shown that vitrification and supercooling of the melt, as well as its crystallization in the from of metastable structures, are related to the effect of nonconformity between the melt and crystal strucure. The effect of nonconformity between anion motives in the melt and crystal creates obstacles for equilibrium structure nucleation, which results in the formation mainly of metastable forms with lattice structure for from the structure of the melt, though cases of equilibrium phase crystallization are also possible. 37 refs.; 13 figs.; 2 tabs

  15. IR spectroscopy together with multivariate data analysis as a process analytical tool for in-line monitoring of crystallization process and solid-state analysis of crystalline product

    DEFF Research Database (Denmark)

    Pöllänen, Kati; Häkkinen, Antti; Reinikainen, Satu-Pia

    2005-01-01

    -ray powder diffraction (XRPD) as a reference technique. In order to fully utilize DRIFT, the application of multivariate techniques are needed, e.g., multivariate statistical process control (MSPC), principal component analysis (PCA) and partial least squares (PLS). The results demonstrate that multivariate...... Fourier transform infra red (ATR-FTIR) spectroscopy provides valuable information on process, which can be utilized for more controlled crystallization processes. Diffuse reflectance Fourier transform infra red (DRIFT-IR) is applied for polymorphic characterization of crystalline product using X......Crystalline product should exist in optimal polymorphic form. Robust and reliable method for polymorph characterization is of great importance. In this work, infra red (IR) spectroscopy is applied for monitoring of crystallization process in situ. The results show that attenuated total reflection...

  16. Impact toughness and microstructure relationship in niobium- and vanadium-microalloyed steels processed with varied cooling rates to similar yield strength

    Energy Technology Data Exchange (ETDEWEB)

    Shanmugam, S. [Center for Structural and Functional Materials and Department of Chemical Engineering, University of Louisiana at Lafayette, LA 70504-4130 (United States); Misra, R.D.K. [Center for Structural and Functional Materials and Department of Chemical Engineering, University of Louisiana at Lafayette, LA 70504-4130 (United States)]. E-mail: dmisra@louisiana.edu; Mannering, T. [Nucor-Yamato Steel, P.O. Box 1228, 5929 East State Highway 18, Blytheville, AR 72316 (United States); Panda, D. [Nucor-Yamato Steel, P.O. Box 1228, 5929 East State Highway 18, Blytheville, AR 72316 (United States); Jansto, S.G. [Reference Metals, 1000 Old Pond Road, Bridgeville, PA 15017 (United States)

    2006-11-15

    We describe here the relationship between microstructure and impact toughness behavior as a function of cooling rate for industrially processed Nb- and V-microalloyed steels of almost similar yield strength ({approx}60 ksi). Both Nb- and V-microalloyed steels exhibited increase in toughness with increase in cooling rates during processing. However, Nb-microalloyed steels were characterized by relatively higher toughness than the V-microalloyed steels under identical processing conditions. The microstructure of Nb- and V-microalloyed steels processed at conventional cooling rate, primarily consisted of polygonal ferrite-pearlite microconstituents, while Nb-microalloyed steels besides polygonal ferrite and pearlite contained significant fraction of degenerated pearlite. The microstructure of Nb- and V-microalloyed steels processed at relatively higher cooling rate contained degenerated pearlite and lath-type (acicular) ferrite in addition to the primary ferrite-pearlite constituents. The fraction of degenerated pearlite was higher in Nb-microalloyed steels than in the V-microalloyed steels. In both Nb- and V-microalloyed steels the precipitation characteristics were similar with precipitation occurring at grain boundaries, dislocations, and in the ferrite matrix. Fine-scale ({approx}5-10 nm) precipitation was observed in the ferrite matrix of both the steels. The selected area diffraction (SAD) pattern analysis revealed that these fine precipitates were MC type of niobium and vanadium carbides in the respective steels and followed Baker-Nutting orientation relationship with the ferrite matrix. The microstructural studies suggest that the increase in toughness of Nb-microalloyed steels is attributed to higher fraction of degenerated pearlite in the steel.

  17. Impact toughness and microstructure relationship in niobium- and vanadium-microalloyed steels processed with varied cooling rates to similar yield strength

    International Nuclear Information System (INIS)

    Shanmugam, S.; Misra, R.D.K.; Mannering, T.; Panda, D.; Jansto, S.G.

    2006-01-01

    We describe here the relationship between microstructure and impact toughness behavior as a function of cooling rate for industrially processed Nb- and V-microalloyed steels of almost similar yield strength (∼60 ksi). Both Nb- and V-microalloyed steels exhibited increase in toughness with increase in cooling rates during processing. However, Nb-microalloyed steels were characterized by relatively higher toughness than the V-microalloyed steels under identical processing conditions. The microstructure of Nb- and V-microalloyed steels processed at conventional cooling rate, primarily consisted of polygonal ferrite-pearlite microconstituents, while Nb-microalloyed steels besides polygonal ferrite and pearlite contained significant fraction of degenerated pearlite. The microstructure of Nb- and V-microalloyed steels processed at relatively higher cooling rate contained degenerated pearlite and lath-type (acicular) ferrite in addition to the primary ferrite-pearlite constituents. The fraction of degenerated pearlite was higher in Nb-microalloyed steels than in the V-microalloyed steels. In both Nb- and V-microalloyed steels the precipitation characteristics were similar with precipitation occurring at grain boundaries, dislocations, and in the ferrite matrix. Fine-scale (∼5-10 nm) precipitation was observed in the ferrite matrix of both the steels. The selected area diffraction (SAD) pattern analysis revealed that these fine precipitates were MC type of niobium and vanadium carbides in the respective steels and followed Baker-Nutting orientation relationship with the ferrite matrix. The microstructural studies suggest that the increase in toughness of Nb-microalloyed steels is attributed to higher fraction of degenerated pearlite in the steel

  18. Numerical and experimental study of a solid pellet feed continuous Czochralski growth process for silicon single crystals

    Science.gov (United States)

    Anselmo, A.; Prasad, V.; Koziol, J.; Gupta, K. P.

    1993-07-01

    A polysilicon pellets (≅1 mm diameter) feed continuous Czochralski (CCZ) growth process for silicon single crystals is proposed and investigated. Experiments in an industrial puller (14-18 inch diameter crucible) successfully demonstrate the feasibility of this process. The advantages of the proposed scheme are: a steady state growth process, a low aspect ratio melt, uniformity of heat addition and a growth apparatus with single crucible and no baffle(s). The addition of dopant with the solid charge will allow a better control of oxygen concentration leading to crystals of uniform properties and better quality. This paper presents theoretical results on melting of fully and partially immersed silicon spheres and numerical solutions on temperature and flow fields in low aspect ration melts with and without the addition of solid pellets. The theoretical and experimental results obtained thus far show a great promise for the proposed scheme.

  19. The Use of Quasi-Isothermal Modulated Temperature Differential Scanning Calorimetry for the Characterization of Slow Crystallization Processes in Lipid-Based Solid Self-Emulsifying Systems

    OpenAIRE

    Otun, Sarah O.; Meehan, Elizabeth; Qi, Sheng; Craig, Duncan Q. M.

    2014-01-01

    Purpose Slow or incomplete crystallization may be a significant manufacturing issue for solid lipid-based dosage forms, yet little information is available on this phenomenon. In this investigation we suggest a novel means by which slow solidification may be monitored in Gelucire 44/14 using quasi-isothermal modulated temperature DSC (QiMTDSC). Methods Conventional linear heating and cooling DSC methods were employed, along with hot stage microscopy (HSM), for basic thermal profiling of Geluc...

  20. Dynamic Thermal Loads and Cooling Requirements Calculations for V ACs System in Nuclear Fuel Processing Facilities Using Computer Aided Energy Conservation Models

    International Nuclear Information System (INIS)

    EL Fawal, M.M.; Gadalla, A.A.; Taher, B.M.

    2010-01-01

    In terms of nuclear safety, the most important function of ventilation air conditioning (VAC) systems is to maintain safe ambient conditions for components and structures important to safety inside the nuclear facility and to maintain appropriate working conditions for the plant's operating and maintenance staff. As a part of a study aimed to evaluate the performance of VAC system of the nuclear fuel cycle facility (NFCF) a computer model was developed and verified to evaluate the thermal loads and cooling requirements for different zones of fuel processing facility. The program is based on transfer function method (TFM) and it is used to calculate the dynamic heat gain by various multilayer walls constructions and windows hour by hour at any orientation of the building. The developed model was verified by comparing the obtained calculated results of the solar heat gain by a given building with the corresponding calculated values using finite difference method (FDM) and total equivalent temperature different method (TETD). As an example the developed program is used to calculate the cooling loads of the different zones of a typical nuclear fuel facility the results showed that the cooling capacities of the different cooling units of each zone of the facility meet the design requirements according to safety regulations in nuclear facilities.

  1. Review of state-of-the-art of solar collector corrosion processes. Task 1 of solar collector studies for solar heating and cooling applications. Final technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    Clifford, J E; Diegle, R B

    1980-04-11

    The state-of-the-art of solar collector corrosion processes is reviewed, and Task 1 of a current research program on use of aqueous heat transfer fluids for solar heating and cooling is summarized. The review of available published literature has indicated that lack of quantitative information exists relative to collector corrosion at the present time, particularly for the higher temperature applications of solar heating and cooling compared to domestic water heating. Solar collector systems are reviewed from the corrosion/service life viewpoint, with emphasis on various applications, collector design, heat transfer fluids, and freeze protection methods. Available information (mostly qualitative) on collector corrosion technology is reviewed to indicate potential corrosion problem areas and corrosion prevention practices. Sources of limited quantitative data that are reviewed are current solar applications, research programs on collector corrosion, and pertinent experience in related applications of automotive cooling and non-solar heating and cooling. A data bank was developed to catalog corrosion information. Appendix A of this report is a bibliography of the data bank, with abstracts reproduced from presently available literature accessions (about 220). This report is presented as a descriptive summary of information that is contained in the data bank.

  2. Pure & crystallized 2D Boron Nitride sheets synthesized via a novel process coupling both PDCs and SPS methods

    Science.gov (United States)

    Yuan, Sheng; Linas, Sébastien; Journet, Catherine; Steyer, Philippe; Garnier, Vincent; Bonnefont, Guillaume; Brioude, Arnaud; Toury, Bérangère

    2016-02-01

    Within the context of emergent researches linked to graphene, it is well known that h-BN nanosheets (BNNSs), also referred as 2D BN, are considered as the best candidate for replacing SiO2 as dielectric support or capping layers for graphene. As a consequence, the development of a novel alternative source for highly crystallized h-BN crystals, suitable for a further exfoliation, is a prime scientific issue. This paper proposes a promising approach to synthesize pure and well-crystallized h-BN flakes, which can be easily exfoliated into BNNSs. This new accessible production process represents a relevant alternative source of supply in response to the increasing need of high quality BNNSs. The synthesis strategy to prepare pure h-BN is based on a unique combination of the Polymer Derived Ceramics (PDCs) route with the Spark Plasma Sintering (SPS) process. Through a multi-scale chemical and structural investigation, it is clearly shown that obtained flakes are large (up to 30 μm), defect-free and well crystallized, which are key-characteristics for a subsequent exfoliation into relevant BNNSs.

  3. Analysis of the residual strain change of Bi2212, Ag alloy and Ag during the heating and cooling process in Bi2212/Ag/Ag alloy composite wire

    International Nuclear Information System (INIS)

    Shin, J K; Ochiai, S; Okuda, H; Mukai, Y; Sugano, M; Sato, M; Oh, S S; Ha, D W; Kim, S C

    2008-01-01

    The residual strain change of Bi2212 and Ag during the cooling and heating process in the Bi2212/Ag/Ag alloy composite superconductor was studied. First, the residual strain of Bi2212 filaments at room temperature was measured by the x-ray diffraction method. Then, the Young's moduli of the constituents (Bi2212 filaments, Ag and Ag alloy) and yield strains of Ag and Ag alloy were estimated from the analysis of the measured stress-strain curve, based on the rule of mixtures. Also, the coefficient of thermal expansion of the Bi2212 filaments was estimated from the analysis of the measured thermal expansion curve of the composite wire. From the modeling analysis using the estimated property values and the residual strain of Bi2212 filaments, the changes of residual strain of Bi2212, Ag alloy and Ag with temperature during the cooling and heating process were revealed

  4. Summer cooling in the east central Arabian Sea - a process of dynamic response to the southwest monsoon

    Digital Repository Service at National Institute of Oceanography (India)

    RameshBabu, V.; Sastry, J.S.

    The cooling of the east central Arabian Sea during summer monsoon season is examined using data sets of MONEX '79 and MONSOON '77 programmes. These studies have revealed that downward transfer of heat due to the mixing of warm surface and cold sub...

  5. Luminescence and photothermally stimulated defects creation processes in PbWO4:La3+, Y3+ (PWO II) crystals

    International Nuclear Information System (INIS)

    Auffray, E.; Korjik, M.; Zazubovich, S.

    2015-01-01

    Photoluminescence and thermally stimulated luminescence (TSL) are studied for a PbWO 4 crystal grown by the Czochralski method at Bogoroditsk Technical Chemical Plant, Russia from the melt with a precise tuning of the stoichiometry and co-doped with La 3+ and Y 3+ ions (the PWO II crystal). Photothermally stimulated processes of electron and hole centers creation under selective UV irradiation of this crystal in the 3.5–5.0 eV energy range and the 85–205 K temperature range are clarified and the optically created electron and hole centers are identified. The electrons in PWO II are mainly trapped at the (WO 4 ) 2− groups located close to single La 3+ and Y 3+ ions, producing the electron {(WO 4 ) 3− –La 3+ } and {(WO 4 ) 3− –Y 3+ } centers. The holes are mainly trapped at the regular oxygen ions O 2− located close to La 3+ and Y 3+ ions associated with lead vacancies, producing the hole O − (I)-type centers. No evidence of single-vacancy-related centers has been observed in PWO II. The data obtained indicate that excellent scintillation characteristics of the PWO II crystal can be explained by a negligible concentration of single (non-compensated) oxygen and lead vacancies as the traps for electrons and holes, respectively. - Highlights: • Photoluminescence of the PbWO 4 :La 3+ , Y 3+ (PWO II) crystal is investigated. • Creation of defects under UV irradiation of PWO II is studied by TSL. • Origin of dominating electron and hole centers is ascertained. • Concentration of single-vacancy-related centers is found to be negligible. • Excellent scintillation characteristics of the PWO II crystal are explained.

  6. Identification of new fluorescence processes in the UV spectra of cool stars from new energy levels of Fe II and Cr II

    Science.gov (United States)

    Johansson, Sveneric; Carpenter, Kenneth G.

    1988-01-01

    Two fluorescence processes operating in atmospheres of cool stars, symbiotic stars, and the Sun are presented. Two emission lines, at 1347.03 and 1360.17 A, are identified as fluorescence lines of Cr II and Fe II. The lines are due to transitions from highly excited levels, which are populated radiatively by the hydrogen Lyman alpha line due to accidental wavelength coincidences. Three energy levels, one in Cr II and two in Fe II, are reported.

  7. P2O5-doping in waste glasses: evolution of viscosity and crystallization processes

    Science.gov (United States)

    Tarrago, Mariona; Espuñes, Alex; Garcia-Valles, Maite; Martinez, Salvador

    2015-04-01

    Current concern for environmental preservation is the main motive for the study of new, more sustainable materials. Increasing amounts of sewage sludge are produced in wastewater treatment plants over the world every day. This fact represents a major problem for the municipalities and industries due to the volume of waste and also to the contaminant elements it may bear, which require expensive conditions for disposal in landfills. Vitrification is an established technique in the inertization of different types of toxic wastes (such as nuclear wastes and contaminated soils) that has been used successfully for sewage sludge. Glasses of basaltic composition (43.48SiO2-14.00Al2O3-12.86Fe2O3-10.00CaO-9.94MgO-3.27Na2O-1.96K2O-0.17MnO-0.55P2O5-2.48TiO2) are used as a laboratory analogous of wastes such as sewage sludge and galvanic sludge to study the properties of the inertization matrix. This basaltic matrix is doped by adding 1%, 2%, 3%, 4% and 20% of P5O5 in order to cover the compositional range of phosphate in sewage sludge encountered in the literature. In this study, the focus has been placed in the effect of the concentration of phosphate (P2O5) in glass stability, thermal properties and evolution of viscosity with temperature. The dependence of viscosity on temperature and the thermal behaviour of these glasses are critical parameters in the design of their production process. Regarding the compositional limits of the mixture, it has been observed that melt reactivity is much increased when P2O5 content is over 4%, hindering the glass conformation process. Moreover, stanfieldite (calcium and magnesium phosphate) crystallized during glass making when phosphate concentration approached 20%, hence establishing the upper limit for glass stability. Viscosity is also dramatically increased in this range, hence requiring production amends. Differential thermal analysis has provided nucleation and crystallization temperatures of the glasses around 915°C and 1050

  8. The Effects of Doping and Processing on the Thermoelectric Properties of Platinum Diantimonide Based Materials for Cryogenic Peltier Cooling Applications

    Science.gov (United States)

    Waldrop, Spencer Laine

    The study of thermoelectrics is nearly two centuries old. In that time a large number of applications have been discovered for these materials which are capable of transforming thermal energy into electricity or using electrical work to create a thermal gradient. Current use of thermoelectric materials is in very niche applications with contemporary focus being upon their capability to recover waste heat. A relatively undeveloped region for thermoelectric application is focused upon Peltier cooling at low temperatures. Materials based on bismuth telluride semiconductors have been the gold standard for close to room temperature applications for over sixty years. For applications below room temperature, semiconductors based on bismuth antimony reign supreme with few other possible materials. The cause of this diculty in developing new, higher performing materials is due to the interplay of the thermoelectric properties of these materials. The Seebeck coecient, which characterizes the phenomenon of the conversion of heat to electricity, the electrical conductivity, and the thermal conductivity are all interconnected properties of a material which must be optimized to generate a high performance thermoelectric material. While for above room temperature applications many advancements have been made in the creation of highly ecient thermoelectric materials, the below room temperature regime has been stymied by ill-suited properties, low operating temperatures, and a lack of research. The focus of this work has been to investigate and optimize the thermoelectric properties of platinum diantimonide, PtSb2, a nearly zero gap semiconductor. The electronic properties of PtSb2 are very favorable for cryogenic Peltier applications, as it exhibits good conductivity and large Seebeck coecient below 200 K. It is shown that both n- and p-type doping may be applied to this compound to further improve its electronic properties. Through both solid solution formation and processing

  9. Crystallization mechanisms of acicular crystals

    Science.gov (United States)

    Puel, François; Verdurand, Elodie; Taulelle, Pascal; Bebon, Christine; Colson, Didier; Klein, Jean-Paul; Veesler, Stéphane

    2008-01-01

    In this contribution, we present an experimental investigation of the growth of four different organic molecules produced at industrial scale with a view to understand the crystallization mechanism of acicular or needle-like crystals. For all organic crystals studied in this article, layer-by-layer growth of the lateral faces is very slow and clear, as soon as the supersaturation is high enough, there is competition between growth and surface-activated secondary nucleation. This gives rise to pseudo-twinned crystals composed of several needle individuals aligned along a crystallographic axis; this is explained by regular over- and inter-growths as in the case of twinning. And when supersaturation is even higher, nucleation is fast and random. In an industrial continuous crystallization, the rapid growth of needle-like crystals is to be avoided as it leads to fragile crystals or needles, which can be partly broken or totally detached from the parent crystals especially along structural anisotropic axis corresponding to weaker chemical bonds, thus leading to slower growing faces. When an activated mechanism is involved such as a secondary surface nucleation, it is no longer possible to obtain a steady state. Therefore, the crystal number, size and habit vary significantly with time, leading to troubles in the downstream processing operations and to modifications of the final solid-specific properties. These results provide valuable information on the unique crystallization mechanisms of acicular crystals, and show that it is important to know these threshold and critical values when running a crystallizer in order to obtain easy-to-handle crystals.

  10. Crystallization, data collection and processing of the chymotrypsin–BTCI–trypsin ternary complex

    Energy Technology Data Exchange (ETDEWEB)

    Esteves, Gisele Ferreira; Teles, Rozeni Chagas Lima; Cavalcante, Nayara Silva; Neves, David; Ventura, Manuel Mateus [Laboratório de Biofísica, Instituto de Ciências Biológicas, Universidade de Brasília, 70910-900 Brasília-DF (Brazil); Barbosa, João Alexandre Ribeiro Gonçalves, E-mail: joao@lnls.br [Center for Structural Molecular Biology (CeBiME), Brazilian Synchrotron Light Laboratory (LNLS), CP 6192, 13083-970 Campinas-SP (Brazil); Freitas, Sonia Maria de, E-mail: joao@lnls.br [Laboratório de Biofísica, Instituto de Ciências Biológicas, Universidade de Brasília, 70910-900 Brasília-DF (Brazil)

    2007-12-01

    A ternary complex of the proteinase inhibitor (BTCI) with trypsin and chymotrypsin was crystallized and its crystal structure was solved by molecular replacement. A ternary complex of the black-eyed pea trypsin and chymotrypsin inhibitor (BTCI) with trypsin and chymotrypsin was crystallized by the sitting-drop vapour-diffusion method with 0.1 M HEPES pH 7.5, 10%(w/v) polyethylene glycol 6000 and 5%(v/v) 2-methyl-2,4-pentanediol as precipitant. BTCI is a small protein with 83 amino-acid residues isolated from Vigna unguiculata seeds and is able to inhibit trypsin and chymotrypsin simultaneously by forming a stable ternary complex. X-ray data were collected from a single crystal of the trypsin–BTCI–chymotrypsin ternary complex to 2.7 Å resolution under cryogenic conditions. The structure of the ternary complex was solved by molecular replacement using the crystal structures of the BTCI–trypsin binary complex (PDB code) and chymotrypsin (PDB code) as search models.

  11. Crystallization, data collection and processing of the chymotrypsin–BTCI–trypsin ternary complex

    International Nuclear Information System (INIS)

    Esteves, Gisele Ferreira; Teles, Rozeni Chagas Lima; Cavalcante, Nayara Silva; Neves, David; Ventura, Manuel Mateus; Barbosa, João Alexandre Ribeiro Gonçalves; Freitas, Sonia Maria de

    2007-01-01

    A ternary complex of the proteinase inhibitor (BTCI) with trypsin and chymotrypsin was crystallized and its crystal structure was solved by molecular replacement. A ternary complex of the black-eyed pea trypsin and chymotrypsin inhibitor (BTCI) with trypsin and chymotrypsin was crystallized by the sitting-drop vapour-diffusion method with 0.1 M HEPES pH 7.5, 10%(w/v) polyethylene glycol 6000 and 5%(v/v) 2-methyl-2,4-pentanediol as precipitant. BTCI is a small protein with 83 amino-acid residues isolated from Vigna unguiculata seeds and is able to inhibit trypsin and chymotrypsin simultaneously by forming a stable ternary complex. X-ray data were collected from a single crystal of the trypsin–BTCI–chymotrypsin ternary complex to 2.7 Å resolution under cryogenic conditions. The structure of the ternary complex was solved by molecular replacement using the crystal structures of the BTCI–trypsin binary complex (PDB code) and chymotrypsin (PDB code) as search models

  12. Cooling with Superfluid Helium

    Energy Technology Data Exchange (ETDEWEB)

    Lebrun, P; Tavian, L [European Organization for Nuclear Research, Geneva (Switzerland)

    2014-07-01

    The technical properties of helium II (‘superfluid’ helium) are presented in view of its applications to the cooling of superconducting devices, particularly in particle accelerators. Cooling schemes are discussed in terms of heat transfer performance and limitations. Large-capacity refrigeration techniques below 2 K are reviewed, with regard to thermodynamic cycles as well as process machinery. Examples drawn from existing or planned projects illustrate the presentation. Keywords: superfluid helium, cryogenics.

  13. Ventilative Cooling

    DEFF Research Database (Denmark)

    Heiselberg, Per Kvols; Kolokotroni, Maria

    This report, by venticool, summarises the outcome of the work of the initial working phase of IEA ECB Annex 62 Ventilative Cooling and is based on the findings in the participating countries. It presents a summary of the first official Annex 62 report that describes the state-of-the-art of ventil......This report, by venticool, summarises the outcome of the work of the initial working phase of IEA ECB Annex 62 Ventilative Cooling and is based on the findings in the participating countries. It presents a summary of the first official Annex 62 report that describes the state......-of-the-art of ventilative cooling potentials and limitations, its consideration in current energy performance regulations, available building components and control strategies and analysis methods and tools. In addition, the report provides twenty six examples of operational buildings using ventilative cooling ranging from...

  14. Predictive modeling of crystal accumulation in high-level waste glass melters processing radioactive waste

    Energy Technology Data Exchange (ETDEWEB)

    Matyáš, Josef; Gervasio, Vivianaluxa; Sannoh, Sulaiman E.; Kruger, Albert A.

    2017-11-01

    The effectiveness of HLW vitrification is limited by precipitation/accumulation of spinel crystals [(Fe, Ni, Mn, Zn)(Fe, Cr)2O4] in the glass discharge riser of Joule-heated ceramic melters during idling. These crystals do not affect glass durability; however, if accumulated in thick layer, they can clog the melter and prevent discharge of molten glass into canisters. To address this problem, an empirical model was developed that can predict thicknesses of accumulated layers as a function of glass composition. This model predicts well the accumulation of single crystals and/or small-scale agglomerates, but, excessive agglomeration observed in high-Ni-Fe glass resulted in an under-prediction of accumulated layers, which gradually worsen over time as an increased number of agglomerates formed. Accumulation rate of ~53.8 ± 3.7 µm/h determined for this glass will result in ~26 mm thick layer in 20 days of melter idling.

  15. Investigation of structural relaxation, crystallization process and magnetic properties of the Fe-Ni-Si-B-C amorphous alloy

    Energy Technology Data Exchange (ETDEWEB)

    Kalezic-Glisovic, A. [Joint Laboratory for Advanced Materials of SASA, Section for Amorphous Systems, Technical Faculty Cacak, Svetog Save 65, 32000 Cacak (Serbia and Montenegro)]. E-mail: aleksandrakalezic@eunet.yu; Novakovic, L. [Faculty of Physics, Studentski trg 16, 11000 Belgrade (Serbia and Montenegro); Maricic, A. [Joint Laboratory for Advanced Materials of SASA, Section for Amorphous Systems, Technical Faculty Cacak, Svetog Save 65, 32000 Cacak (Serbia and Montenegro); Minic, D. [Faculty of Physical Chemistry, Studentski trg 16, 11000 Belgrade (Serbia and Montenegro); Mitrovic, N. [Joint Laboratory for Advanced Materials of SASA, Section for Amorphous Systems, Technical Faculty Cacak, Svetog Save 65, 32000 Cacak (Serbia and Montenegro)]. E-mail: nmitrov@tfc.kg.ac.yu

    2006-07-15

    The differential scanning calorimetry method was used for investigating the crystallization process of the Fe{sub 89.8}Ni{sub 1.5}Si{sub 5.2}B{sub 3}C{sub 0.5} amorphous alloy. It was shown that the examined alloy crystallizes in three stages. The first crystallization stage occurs at 799 K, the second at 820 K and the third at 888 K. Temperature dependence of the magnetic susceptibility relative change was investigated by the modified Faraday method in the temperature region from room temperature up to 900 K. It has been established that the Curie temperature is about 700 K for amorphous state. The magnetic susceptibility increases by 30% after the first heating up to 710 K. During the second heating up to 840 K the alloy loses its ferromagnetic features in the temperature region from 710 to 750 K, upon which it again regains the same. After the second heating magnetic susceptibility decreases by 23% as compared to the amorphous starting value and by 53% as compared to the value before the second heating. The crystallized alloy maintains ferromagnetic features in the whole temperature region during the heating up to 900 K.

  16. Investigation of structural relaxation, crystallization process and magnetic properties of the Fe-Ni-Si-B-C amorphous alloy

    International Nuclear Information System (INIS)

    Kalezic-Glisovic, A.; Novakovic, L.; Maricic, A.; Minic, D.; Mitrovic, N.

    2006-01-01

    The differential scanning calorimetry method was used for investigating the crystallization process of the Fe 89.8 Ni 1.5 Si 5.2 B 3 C 0.5 amorphous alloy. It was shown that the examined alloy crystallizes in three stages. The first crystallization stage occurs at 799 K, the second at 820 K and the third at 888 K. Temperature dependence of the magnetic susceptibility relative change was investigated by the modified Faraday method in the temperature region from room temperature up to 900 K. It has been established that the Curie temperature is about 700 K for amorphous state. The magnetic susceptibility increases by 30% after the first heating up to 710 K. During the second heating up to 840 K the alloy loses its ferromagnetic features in the temperature region from 710 to 750 K, upon which it again regains the same. After the second heating magnetic susceptibility decreases by 23% as compared to the amorphous starting value and by 53% as compared to the value before the second heating. The crystallized alloy maintains ferromagnetic features in the whole temperature region during the heating up to 900 K

  17. Thermoactivation processes in PbI2:Zr and PbI2 crystals

    International Nuclear Information System (INIS)

    Panasyuk, M.R.; Kapustyanik, V.B.; Tsibul's'kij, V.S.; Dubov, Yu.G.; Pasternak, R.M.

    2007-01-01

    The X-ray luminescence, thermal emission and thermally stimulated depolarisation spectra as well as the influence of IR-illumination on the thermal emission and thermally stimulated depolarisation spectra of the PbI 2 :Zr and PbI 2 crystals have been studied. There were found the hole traps in the PbI 2 :Zr crystals that are absent in PbI 2 . For the observed traps the activation energy has been calculated. The mechanisms describing the traps' nature and that of thermally stimulated depolarisation currents have been proposed

  18. Residual stress improvement in multi-layer welded plates using water-shower cooling during welding process

    International Nuclear Information System (INIS)

    Yanagida, Nobuyoshi; Koide, Hiroo

    2006-01-01

    To reduce tensile residual stress in a welded region, we developed a new welding method that applies a water-shower behind the welding torch. When this method is applied to welding of austenitic stainless steel plates, cooling conditions mainly determine how much the residual stress can be reduced. To determine the conditions, we first used FEM to evaluate the effects of interpass temperature on the residual stress. And we found effective conditions for reducing tensile residual stress. To verify the validity of the conditions, specimens welded with or without water shower cooling were manufactured. Residual stresses of the specimens were experimentally measured. It was found that tensile residual stresses were generated on the surface of the welds and those were reduced in the case that the water-shower was applied. These measurement results agree well with the FEM analyses. It can therefore be concluded that the water-shower cooling during welding is appropriate for reducing tensile residual stress in austenitic stainless steel welding. (author)

  19. Specific features of the crystal packing that enable styryl dyes of the pyridine series to undergo the solid-phase [2 + 2] photocycloaddition including the process with single crystal retention

    International Nuclear Information System (INIS)

    Kuz'mina, L. G.; Vedernikov, A. I.; Sazonov, S. K.; Lobova, N. A.; Loginov, P. S.; Howard, J. A. K.; Alfimov, M. V.; Gromov, S. P.

    2008-01-01

    The crystal packing of a number of styryl dyes of the pyridine series is analyzed. The structures of three dyes and three [2 + 2] photocycloaddition (PCA) products, 1,2,3,4-tetrasubstituted cyclobutanes, obtained in single crystals are determined by X-ray diffraction. Stacks of planar organic cations are characteristic of styryl dye packings. The proceeding of the PCA reaction as a single crystal-to-single crystal transformation in the syn head-to-head stacks is in principle impossible. The syn head-to-tail stacking packings are favorable for the PCA reactions resulting in the centrosymmetric rctt isomers of cyclobutane. The stacking packings, in which molecules are related by the twofold axes (the anti arrangement of molecules), are also favorable for PCA in single crystals. In this case, the products are the rtct isomers of cyclobutane. The presence of the I - counterions in a packing is a factor impeding the PCA reaction, because the secondary I-H-C bonds increase the rigidity of the crystal lattice. The conditions necessary for proceeding the PCA reactions in styryl dyes as single crystal-to-single crystal processes are as follows: (1) the stacks split into pairs of organic cations (dimers) with the d distances within 4.2 A in a dimer and d exceeding 4.2 A between the dimers; and (2) the dimers are surrounded by flexible shells consisting of anions, solvate molecules, or flexible moieties of the organic cations themselves.

  20. Numerical analysis of the influence of ultrasonic vibration on crystallization processes

    Energy Technology Data Exchange (ETDEWEB)

    Ubbenjans, B.; Nacke, B. [Institute of Electrotechnology, Hannover (Germany); Frank-Rotsch, C.; Rudolph, P. [Institute for Crystal Growth, Berlin (Germany); Virbulis, J. [University of Latvia, Laboratory for Mathematical Modelling of Environmental and Technological Processes, Riga (Latvia)

    2012-03-15

    The challenge in the future fabrication of semiconductor bulk crystals is the improvement of the crystal quality with a simultaneous increase of the yield. For that, a proper control of mass transfer within the fluid phase is required. Besides the damping of violent convective fluctuations, the thickness of the diffusion boundary layer, causing morphological instability, has to be decreased. The influence of ultrasound in molten Germanium was analyzed by numerical simulations. The simulations were provided by applying commercial software packages ANSYS {sup registered} and FLUENT {sup registered}. ANSYS {sup registered} was used to model the ultrasonic wave propagation in the whole growth system consisting of melt and crystal, crucible and surrounding media. As a result the sound pressure distribution in every point of the melt and the displacement in every point of the solid have been obtained. The melt flow and the temperature distribution were simulated with the help of FLUENT {sup registered}. The main focus was the analysis of Schlichting streams that occur at the crystallization front which affect the diffusion boundary layer. It was shown that ultrasonic treatment can help to reduce the harmful diffusion boundary layer very effectively. (copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  1. Crystallization processes in Ge2Sb2Se4Te glass

    Czech Academy of Sciences Publication Activity Database

    Svoboda, R.; Bezdička, Petr; Gutwirth, J.; Malek, J.

    2015-01-01

    Roč. 61, JAN (2015), s. 207-214 ISSN 0025-5408 Institutional support: RVO:61388980 Keywords : Chalcogenides * Glass es * Differential scanning calorimetry (DSC) * X-ray diffraction * Crystal structure Subject RIV: CA - Inorganic Chemistry Impact factor: 2.435, year: 2015

  2. Digital signal processing applied to crystal identification in Positron Emission Tomography dedicated to small animals

    International Nuclear Information System (INIS)

    Fontaine, Rejean; Viscogliosi, Nicolas; Semmaoui, Hicham; Belanger, Francois; Lemieux, Francois; Tetrault, Marc-Andre; Michaud, Jean-Baptiste; Berard, Philippe; Cadorette, Jules; Pepin, Catherine M.; Lecomte, Roger

    2007-01-01

    The recent introduction of all-digital electronic architecture in Positron Emission Tomography (PET) scanners, enables new paradigms to be explored for extracting relevant information from the detector signals, such as energy, time and crystal identification. The LabPET TM small animal scanner, which implements free-running 45-MHz sampling directly at the output of the charge sensitive preamplifiers, provides an excellent platform to test such advanced digital algorithms. A real-time identification method, based on an Auto-Regressive Moving-Average (ARMA) scheme, was tested for discriminating between LYSO (t r ∼40 ns) and LGSO (t r ∼65 ns) scintillators in phoswich detectors, coupled to a single Avalanche Photodiode (APD). Even with a low energy threshold of 250 keV applied individually, error rates 10%, typically with conventional analog pulse shape discrimination techniques. Such digital crystal identification techniques can be readily implemented with phoswich detectors for improving spatial resolution in PET, either by increasing crystal pixellization or by mitigating parallax errors through depth-of-interaction determination. It also allows to reduce the event rate presented to the real-time coincidence engine by applying a low energy limit at the crystal granularity and rejecting more Compton photons

  3. Digital signal processing applied to crystal identification in Positron Emission Tomography dedicated to small animals

    Energy Technology Data Exchange (ETDEWEB)

    Fontaine, Rejean [Department of Electrical and Computer Engineering, Universite de Sherbrooke, 2500 Boul. Universite, Sherbrooke, Que., J1 K 2R1 (Canada)]. E-mail: Rejean.Fontaine@Usherbrooke.ca; Viscogliosi, Nicolas [Department of Electrical and Computer Engineering, Universite de Sherbrooke, 2500 Boul. Universite, Sherbrooke, Que., J1 K 2R1 (Canada); Semmaoui, Hicham [Department of Electrical and Computer Engineering, Universite de Sherbrooke, 2500 Boul. Universite, Sherbrooke, Que., J1 K 2R1 (Canada); Belanger, Francois [Department of Electrical and Computer Engineering, Universite de Sherbrooke, 2500 Boul. Universite, Sherbrooke, Que., J1 K 2R1 (Canada); Lemieux, Francois [Department of Electrical and Computer Engineering, Universite de Sherbrooke, 2500 Boul. Universite, Sherbrooke, Que., J1 K 2R1 (Canada); Tetrault, Marc-Andre [Department of Electrical and Computer Engineering, Universite de Sherbrooke, 2500 Boul. Universite, Sherbrooke, Que., J1 K 2R1 (Canada); Michaud, Jean-Baptiste [Department of Electrical and Computer Engineering, Universite de Sherbrooke, 2500 Boul. Universite, Sherbrooke, Que., J1 K 2R1 (Canada); Berard, Philippe [Department of Nuclear Medicine and Radiobiology, Universite de Sherbrooke, 2500 Boul. Universite, Sherbrooke, Que., J1 K 2R1 (Canada); Cadorette, Jules [Department of Nuclear Medicine and Radiobiology, Universite de Sherbrooke, 2500 Boul. Universite, Sherbrooke, Que., J1 K 2R1 (Canada); Pepin, Catherine M. [Department of Nuclear Medicine and Radiobiology, Universite de Sherbrooke, 2500 Boul. Universite, Sherbrooke, Que., J1 K 2R1 (Canada); Lecomte, Roger [Department of Nuclear Medicine and Radiobiology, Universite de Sherbrooke, 2500 Boul. Universite, Sherbrooke, Que., J1 K 2R1 (Canada)

    2007-02-01

    The recent introduction of all-digital electronic architecture in Positron Emission Tomography (PET) scanners, enables new paradigms to be explored for extracting relevant information from the detector signals, such as energy, time and crystal identification. The LabPET{sup TM} small animal scanner, which implements free-running 45-MHz sampling directly at the output of the charge sensitive preamplifiers, provides an excellent platform to test such advanced digital algorithms. A real-time identification method, based on an Auto-Regressive Moving-Average (ARMA) scheme, was tested for discriminating between LYSO (t{sub r}{approx}40 ns) and LGSO (t{sub r}{approx}65 ns) scintillators in phoswich detectors, coupled to a single Avalanche Photodiode (APD). Even with a low energy threshold of 250 keV applied individually, error rates<4% can be achieved, as compared to >10%, typically with conventional analog pulse shape discrimination techniques. Such digital crystal identification techniques can be readily implemented with phoswich detectors for improving spatial resolution in PET, either by increasing crystal pixellization or by mitigating parallax errors through depth-of-interaction determination. It also allows to reduce the event rate presented to the real-time coincidence engine by applying a low energy limit at the crystal granularity and rejecting more Compton photons.

  4. All-optical signal processing at 10 GHz using a photonic crystal molecule

    Energy Technology Data Exchange (ETDEWEB)

    Combrié, Sylvain; Lehoucq, Gaëlle; Junay, Alexandra; De Rossi, Alfredo, E-mail: alfredo.derossi@thalesgroup.com [Thales Research and Technology, 1 Avenue A. Fresnel, 91767 Palaiseau (France); Malaguti, Stefania; Bellanca, Gaetano; Trillo, Stefano [Department of Engineering, Università di Ferrara, v. Saragat 1, 44122 Ferrara (Italy); Ménager, Loic [Thales Systèmes Aeroportés, 2 Av. Gay Lussac, 78851 Elancourt (France); Peter Reithmaier, Johann [Institute of Nanostructure Technologies and Analytics, CINSaT, University of Kassel, Heinrich-Plett-Str. 40, 34132 Kassel (Germany)

    2013-11-04

    We report on 10 GHz operation of an all-optical gate based on an Indium Phosphide Photonic Crystal Molecule. Wavelength conversion and all-optical mixing of microwave signals are demonstrated using the 2 mW output of a mode locked diode laser. The spectral separation of the optical pump and signal is crucial in suppressing optical cross-talk.

  5. Photonic crystal fiber as lab-in-fiber optofluidic platform for sensing and process monitoring

    Science.gov (United States)

    Tian, Fei

    The ability to design and fabricate photonic crystal fiber (PCF) of vastly different microstructural and optical characteristics is arguably one of the most significant recent advances in the field of fiber optics. This dissertation aims to advance the PCF research frontier by exploring long-period fiber gratings (LPG) inscribed in PCF for sensing and process monitoring via combined numerical and experimental investigation. Specifically, a mode solver based on the Finite Element Method (FEM) has been employed to calculate the mode field distribution, the phase matching condition, and the dispersive characteristics associated with LPG-induced coupling of the fundamental core mode (LP01) to various cladding modes (LPmn, m=0,1; n=2,3, ...) in an endlessly single mode PCF. The numerical results have been used to guide the design and fabrication of LPG in PCF by CO2 laser inscription to maximize index sensitivity in gas or liquid medium. Cascaded PCF-LPG has been fabricated and shown to exhibit record sensitivity in excess of 1700 nm/RIU with high resolution for index measurements of gas phase. The inherent interference fringes in the transmission spectrum of cascaded PCF-LPG have been utilized to analyze mode coupling behaviour. In addition, we have developed and implemented a reflective mirror-aided method to allow symmetrical CO2 laser irradiation of PCF during LPG inscription. Both numerical analysis and experimental measurements have shown significantly improved mode coupling behaviour, mode field distribution, as well as reproducibility in LPG fabrication, critical for practical exploitation of the PCF-LPG platform. We have further exploited the high index sensitivity of PCF-LPG to monitor layer-by-layer (LbL) self-assembly of poly(vinyl pyrrolidone) (PVPON) and poly(methacrylic acid) (PMAA) polyelectrolyte layers as well as the pH responsiveness of the cross-linked PMAA hydrogel films. A shift of ˜1.625 nm in the resonance wavelength per polyelectrolyte layer

  6. Process Parameters on the Crystallization and Morphology of Hydroxyapatite Powders Prepared by a Hydrolysis Method

    Science.gov (United States)

    Wang, Moo-Chin; Hon, Min-Hsiung; Chen, Hui-Ting; Yen, Feng-Lin; Hung, I.-Ming; Ko, Horng-Huey; Shih, Wei-Jen

    2013-07-01

    The effects of process parameters on the crystallization and morphology of hydroxyapatite (Ca10(PO4)6(OH)2, HA) powders synthesized from dicalcium phosphate dihydrate (CaHPO4·2H2O, DCPD) using a hydrolysis method have been investigated. X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectra, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and selected area electron diffraction (SAED) were used to characterize the synthesized powders. When DCPD underwent hydrolysis in 2.5 NaOH solution (Na(aq)) at 303 K to 348 K (30 °C to 75 °C) for 1 hour, the XRD results revealed that HA was obtained for all the as-dried samples. The SEM morphology of the HA powders for DCPD hydrolysis produced at 348 K (75 °C) shows regular alignment and a short rod shape with a size of 200 nm in length and 50 nm in width. With DCPD hydrolysis in 2.5 M NaOH(aq) holding at 348 K (75 °C) for 1 to 24 hours, XRD results demonstrated that all samples were HA and no other phases could be detected. Moreover, the XRD results also show that all the as-dried powders still maintained the HA structure when DCPD underwent hydrolysis in 0.1 to 5 M NaOH(aq) at 348 K (75 °C) for 1 hour. Otherwise, the full transformation from HA to octa-calcium phosphate (OCP, Ca8H2(PO4)6·5H2O) occurred when hydrolysis happened in 10 M NaOH(aq). FT-IR spectra analysis revealed that some carbonated HA (Ca10(PO4)6(CO3), CHA) had formed. The SEM morphology results show that the 60 to 65 nm width of the uniformly long rods with regular alignment formed in the HA powder aggregates when DCPD underwent hydrolysis in 2.5 M NaOH(aq) at 348 K (75 °C) for 1 hour.

  7. Separation of glucose and fructose by freezing crystallization

    Energy Technology Data Exchange (ETDEWEB)

    Silva, A.T.C.R.; Martinez, K.C.L. [Federal University of Sao Carlos, Chemical Engineering Department, Industrial Crystallization Laboratory - Rod. Washington Luis km 235, P.O. Box 676, CEP:13565-905, Sao Carlos-SP (Brazil); Brito, A.B.N. [Federal University of Espirito Santo, Engineering and Computing Dept. - Rodovia BR 101 Norte, Km. 60, Bairro Litoraneo, CEP 29932-540, Sao Mateus-ES (Brazil); Giulietti, M. [Laboratory of Chemical Process and Particle Technology of Institute for Technological Research, Av. Prof. Almeida Prado 532 -Universitary City, CEP:05508-901, Sao Paulo-SP (Brazil)

    2010-10-15

    This work comprises the implementation of a methodology for the study of an industrial crystallization process by freezing and cooling to be applied in the separation of sugars with industrial relevance (glucose and fructose). The main interest is the production of fructose. This sugar is obtained by sucrose hydrolysis in acidic solutions, which yields an equimolar mixture of glucose and fructose. The developed separation process is based on the solubility difference between the sugars. Experiments were carried out in a jacketed glass crystallizer where the solution coming from the sucrose acid inversion was submitted to a slow cooling. Since glucose has lower solubility than fructose, it crystallizes in the bulk as the temperature is lowered, thus it can be removed from the solution by filtration or centrifugation. Best fructose-glucose separation was achieved for a total sugar concentration of 50 wt%. (copyright 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  8. Zeolite-zeolite composite composed of Y zeolite and single-crystal-like ZSM-5 zeolite: Fabricated by a process like “big fish swallowing little one”

    Energy Technology Data Exchange (ETDEWEB)

    Pan, Meng; Li, Peng [Research Centre of Energy Chemical & Catalytic Technology, Taiyuan University of Technology, Taiyuan 030024 (China); Zheng, Jiajun, E-mail: zhengjiajun@tyut.edu.cn [Research Centre of Energy Chemical & Catalytic Technology, Taiyuan University of Technology, Taiyuan 030024 (China); Liu, Yujian [SINOPEC Research Institute of Petroleum Processing, Beijing, 100083 (China); Kong, Qinglan [Research Centre of Energy Chemical & Catalytic Technology, Taiyuan University of Technology, Taiyuan 030024 (China); Tian, Huiping [SINOPEC Research Institute of Petroleum Processing, Beijing, 100083 (China); Li, Ruifeng, E-mail: rfli@tyut.edu.cn [Research Centre of Energy Chemical & Catalytic Technology, Taiyuan University of Technology, Taiyuan 030024 (China)

    2017-06-15

    Zeolite-zeolite composite composed of Y and ZSM-5 zeolite was prepared using depolymerized Y as partial nutrients for the growth of ZSM-5. The as-synthesized samples were characterized by X-ray powder diffraction (XRD), FT-IR, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM), N{sub 2} adsorption-desorption measurement and Thermogravimetric analysis (TG). Chemical equilibrium at the solution-crystal interface was changed because of the partially depolymerized Y zeolite, the conditions necessary for the growth of ZSM-5 were therefore obtained. ZSM-5 zeolite crystals nucleated and grew on the interface, and Y zeolite crystals were then gradually swallowed by the growing single-crystal-like ZSM-5. - Graphical abstract: Y zeolite crystals in the hydrothermal system were partially depolymerized and an ambience in favor of the formation of ZSM-5 was formed, and ZSM-5 zeolite crystals nucleated and grew up on the external surfaces of Y zeolite crystals. As a consequence, Y zeolite crystals were swallowed by single-crystal-like ZSM-5. - Highlights: • Zeolite composite is composed by Y zeolite and single-crystal-like ZSM-5. • A composite material formed by a process like “big fish swallowing little one”. • Ratio of two zeolites in the as-synthesized sample can be adjusted.

  9. Study of phonon-induced energy transfer processes in crystals using heat pulses

    International Nuclear Information System (INIS)

    Burns, A.R.

    1978-03-01

    The artificial generation of acoustic lattice vibrations by a heat pulse technique is developed in order to probe phonon interactions in molecular crystals. Specifically, the phonon-assisted delocalization of ''trapped'' excited triplet state energy in the aromatic crystal 1,2,4,5-tetrachlorobenzene (TCB) is studied in a quantitative manner by monitoring the time-resolved decrease in trap phosphorescence intensity due to the propagation of a well-defined heat pulse. The excitation distribution in a single trap system, such as the X-trap in neat h 2 -TCB, is discussed in terms of the energy partition function relating the temperature dependence of the trap phosphorescence intensity to the trap depth, exciton bandwidth, and the number of exciton band states. In a multiple trap system, such as the hd and h 2 isotopic traps in d 2 -TCB, the excitation distribution is distinctly non-Boltzmann; yet it may be discussed in terms of a preferential energy transfer between the two trap states via the exciton band. For both trap systems, a previously developed kinetic model is presented which relates the efficiency of trap-band energy exchange to the density of band states and the trap-phonon coupling matrix elements. A bolometric technique for determining the thermal response time of the heater/crystal system is presented. The phonon mean free path in the crystal is size-limited, and the heater/crystal boundary conductance is reasonably close to previously reported values. The theory of heat pulse phonon spectroscopy is presented and discussed in terms of black-body phonon radiation

  10. Specific cooling capacity of liquid nitrogen

    Science.gov (United States)

    Kilgore, R. A.; Adcock, J. B.

    1977-01-01

    The assumed cooling process and the method used to calculate the specific cooling capacity of liquid nitrogen are described, and the simple equation fitted to the calculated specific cooling capacity data, together with the graphical form calculated values of the specific cooling capacity of nitrogen for stagnation temperatures from saturation to 350 K and stagnation pressures from 1 to 10 atmospheres, are given.

  11. Cooling towers

    International Nuclear Information System (INIS)

    Korik, L.; Burger, R.

    1992-01-01

    What is the effect of 0.6C (1F) temperature rise across turbines, compressors, or evaporators? Enthalpy charts indicate for every 0.6C (1F) hotter water off the cooling tower will require an additional 2 1/2% more energy cost. Therefore, running 2.2C (4F) warmer due to substandard cooling towers could result in a 10% penalty for overcoming high heads and temperatures. If it costs $1,250,000.00 a year to operate the system, $125,000.00 is the energy penalty for hotter water. This paper investigates extra fuel costs involved in maintaining design electric production with cooling water 0.6C (1F) to 3C (5.5F) hotter than design. If design KWH cannot be maintained, paper will calculate dollar loss of saleable electricity. The presentation will conclude with examining the main causes of deficient cold water production. State-of-the-art upgrading and methodology available to retrofit existing cooling towers to optimize lower cooling water temperatures will be discussed

  12. Flux free growth of large FeSe1/2Te1/2 superconducting single crystals by an easy high temperature melt and slow cooling method

    Directory of Open Access Journals (Sweden)

    P. K. Maheshwari

    2015-09-01

    Full Text Available We report successful growth of flux free large single crystals of superconducting FeSe1/2Te1/2 with typical dimensions of up to few cm. The AC and DC magnetic measurements revealed the superconducting transition temperature (Tc value of around 11.5K and the isothermal MH showed typical type-II superconducting behavior. The lower critical field (Hc1 being estimated by measuring the low field isothermal magnetization in superconducting regime is found to be above 200Oe at 0K. The temperature dependent electrical resistivity ρ(T  showed the Tc (onset to be 14K and the Tc(ρ = 0 at 11.5K. The electrical resistivity under various magnetic fields i.e., ρ(TH for H//ab and H//c demonstrated the difference in the width of Tc with applied field of 14Tesla to be nearly 2K, confirming the anisotropic nature of superconductivity. The upper critical and irreversibility fields at absolute zero temperature i.e., Hc2(0 and Hirr(0 being determined by the conventional one-band Werthamer–Helfand–Hohenberg (WHH equation for the criteria of normal state resistivity (ρn falling to 90% (onset, and 10% (offset is 76.9Tesla, and 37.45Tesla respectively, for H//c and 135.4Tesla, and 71.41Tesla respectively, for H//ab. The coherence length at the zero temperature is estimated to be above 20Å ´ by using the Ginsburg-Landau theory. The activation energy for the FeSe1/2Te1/2 in both directions H//c and H//ab is determined by using Thermally Activation Flux Flow (TAFF model.

  13. Effects of short immersion time and cooling rates of copperizing process to the evolution of microstructures and copper behavior in the dead mild steel

    Science.gov (United States)

    Jatimurti, Wikan; Sutarsis, Cunika, Aprida Ulya

    2017-01-01

    In a dead mild steel with maximum carbon content of 0.15%, carbon does not contribute much to its strength. By adding copper as an alloying element, a balance between strength and ductility could be obtained through grain refining, solid solution, or Cu precipitation. This research aimed to analyse the changes in microstructures and copper behaviour on AISI 1006, including the phases formed, composition, and Cu dispersion. The addition of cooper was done by immersing steel into molten copper or so we called, copperizing using the principles of diffusion. Specimens were cut with 6 × 3 × 0.3 cm measurement then preheated to 900°C and melting the copper at 1100°C. Subsequently, the immersion of the specimens into molten copper varied to 5 and 7 minutes, and also varying the cooling rate to annealing, normalizing, and quenching. A series of test being conduct were optical microscope test, scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX), optical emission spectroscopy (OES), and X-ray diffraction (XRD). The results showed that the longer the immersion time and slower cooling rate, the more Cu diffused causing smaller grain size with the highest Cu diffused recorded was 0.277% in the copperized AISI 1006 steel with 7 minutes of immersion and was annealed. The grain size reduced to 23041.5404 µm2. The annealed specimens show ferrite phase, the normalized ones show polygonal ferrite phase, while the quenched ones show granular bainite phase. The phase formed is single phase Cu. In addition, the normalized and quenched specimens show that Cu dissolved in Fe crystal forming solid solution.

  14. Effect of meat ingredients (sodium nitrite and erythorbate) and processing (vacuum storage and packaging atmosphere) on germination and outgrowth of Clostridium perfringens spores in ham during abusive cooling.

    Science.gov (United States)

    Redondo-Solano, Mauricio; Valenzuela-Martinez, Carol; Cassada, David A; Snow, Daniel D; Juneja, Vijay K; Burson, Dennis E; Thippareddi, Harshavardhan

    2013-09-01

    The effect of nitrite and erythorbate on Clostridium perfringens spore germination and outgrowth in ham during abusive cooling (15 h) was evaluated. Ham was formulated with ground pork, NaNO2 (0, 50, 100, 150 or 200 ppm) and sodium erythorbate (0 or 547 ppm). Ten grams of meat (stored at 5 °C for 3 or 24 h after preparation) were transferred to a vacuum bag and inoculated with a three-strain C. perfringens spore cocktail to obtain an inoculum of ca. 2.5 log spores/g. The bags were vacuum-sealed, and the meat was heat treated (75 °C, 20 min) and cooled within 15 h from 54.4 to 7.2 °C. Residual nitrite was determined before and after heat treatment using ion chromatography with colorimetric detection. Cooling of ham (control) stored for 3 and 24 h, resulted in C. perfringens population increases of 1.46 and 4.20 log CFU/g, respectively. For samples that contained low NaNO2 concentrations and were stored for 3 h, C. perfringens populations of 5.22 and 2.83 log CFU/g were observed with or without sodium erythorbate, respectively. Residual nitrite was stable (p > 0.05) for both storage times. Meat processing ingredients (sodium nitrite and sodium erythorbate) and their concentrations, and storage time subsequent to preparation of meat (oxygen content) affect C. perfringens spore germination and outgrowth during abusive cooling of ham. Copyright © 2013 Elsevier Ltd. All rights reserved.

  15. Abstracts, Third Space Processing Symposium, Skylab results

    Science.gov (United States)

    1974-01-01

    Skylab experiments results are reported in abstracts of papers presented at the Third Space Processing Symposium. Specific areas of interest include: exothermic brazing, metals melting, crystals, reinforced composites, glasses, eutectics; physics of the low-g processes; electrophoresis, heat flow, and convection demonstrations flown on Apollo missions; and apparatus for containerless processing, heating, cooling, and containing materials.

  16. Disentangling nonradiative recombination processes in Ge micro-crystals on Si substrates

    International Nuclear Information System (INIS)

    Pezzoli, Fabio; Giorgioni, Anna; Gatti, Eleonora; Grilli, Emanuele; Bonera, Emiliano; Miglio, Leo; Gallacher, Kevin; Millar, Ross W.; Paul, Douglas J.; Isa, Fabio; Biagioni, Paolo; Isella, Giovanni

    2016-01-01

    We address nonradiative recombination pathways by leveraging surface passivation and dislocation management in μm-scale arrays of Ge crystals grown on deeply patterned Si substrates. The time decay photoluminescence (PL) at cryogenic temperatures discloses carrier lifetimes approaching 45 ns in band-gap engineered Ge micro-crystals. This investigation provides compelling information about the competitive interplay between the radiative band-edge transitions and the trapping of carriers by dislocations and free surfaces. Furthermore, an in-depth analysis of the temperature dependence of the PL, combined with capacitance data and finite difference time domain modeling, demonstrates the effectiveness of GeO_2 in passivating the surface of Ge and thus in enhancing the room temperature PL emission.

  17. Disentangling nonradiative recombination processes in Ge micro-crystals on Si substrates

    Science.gov (United States)

    Pezzoli, Fabio; Giorgioni, Anna; Gallacher, Kevin; Isa, Fabio; Biagioni, Paolo; Millar, Ross W.; Gatti, Eleonora; Grilli, Emanuele; Bonera, Emiliano; Isella, Giovanni; Paul, Douglas J.; Miglio, Leo

    2016-06-01

    We address nonradiative recombination pathways by leveraging surface passivation and dislocation management in μm-scale arrays of Ge crystals grown on deeply patterned Si substrates. The time decay photoluminescence (PL) at cryogenic temperatures discloses carrier lifetimes approaching 45 ns in band-gap engineered Ge micro-crystals. This investigation provides compelling information about the competitive interplay between the radiative band-edge transitions and the trapping of carriers by dislocations and free surfaces. Furthermore, an in-depth analysis of the temperature dependence of the PL, combined with capacitance data and finite difference time domain modeling, demonstrates the effectiveness of GeO2 in passivating the surface of Ge and thus in enhancing the room temperature PL emission.

  18. Disentangling nonradiative recombination processes in Ge micro-crystals on Si substrates

    Energy Technology Data Exchange (ETDEWEB)

    Pezzoli, Fabio, E-mail: fabio.pezzoli@unimib.it; Giorgioni, Anna; Gatti, Eleonora; Grilli, Emanuele; Bonera, Emiliano; Miglio, Leo [LNESS and Dipartimento di Scienza dei Materiali, Università degli Studi di Milano-Bicocca, via Cozzi 55, I-20125 Milano (Italy); Gallacher, Kevin; Millar, Ross W.; Paul, Douglas J. [School of Engineering, University of Glasgow, Rankine Building, Oakfield Avenue, Glasgow G12 8LT (United Kingdom); Isa, Fabio [LNESS, Dipartimento di Fisica del Politecnico di Milano and IFN-CNR, Polo Territoriale di Como, Via Anzani 42, I-22100 Como (Italy); Laboratory for Solid State Physics, ETH Zurich, Otto-Stern-Weg 1, CH-8093 Zürich (Switzerland); Biagioni, Paolo [LNESS, Dipartimento di Fisica del Politecnico di Milano and IFN-CNR, Piazza Leonardo da Vinci 32, I-20133 Milano (Italy); Isella, Giovanni [LNESS, Dipartimento di Fisica del Politecnico di Milano and IFN-CNR, Polo Territoriale di Como, Via Anzani 42, I-22100 Como (Italy)

    2016-06-27

    We address nonradiative recombination pathways by leveraging surface passivation and dislocation management in μm-scale arrays of Ge crystals grown on deeply patterned Si substrates. The time decay photoluminescence (PL) at cryogenic temperatures discloses carrier lifetimes approaching 45 ns in band-gap engineered Ge micro-crystals. This investigation provides compelling information about the competitive interplay between the radiative band-edge transitions and the trapping of carriers by dislocations and free surfaces. Furthermore, an in-depth analysis of the temperature dependence of the PL, combined with capacitance data and finite difference time domain modeling, demonstrates the effectiveness of GeO{sub 2} in passivating the surface of Ge and thus in enhancing the room temperature PL emission.

  19. Cooling tower

    Energy Technology Data Exchange (ETDEWEB)

    Norbaeck, P; Heneby, H

    1976-01-22

    Cooling towers to be transported on road vehicles as a unit are not allowed to exceed certain dimensions. In order to improve the efficiency of such a cooling tower (of cross-flow design and box-type body) with given dimensions, it is proposed to arrange at least one of the scrubbing bodies displaceable within a module or box. Then it can be moved out of the casing into working position, thereby increasing the front surface available for the inlet of air (and with it the efficiency) by nearly a factor of two.

  20. Spectroscopic properties and quenching processes of Yb3+ in Fluoride single crystals for laser applications

    International Nuclear Information System (INIS)

    Bensalah, A.; Ito, M.; Guyot, Y.; Goutaudier, C.; Jouini, A.; Brenier, A.; Sato, H.; Fukuda, T.; Boulon, G.

    2007-01-01

    Spectroscopic characterization is carried out to identify Stark's levels of Yb 3+ transitions in several fluoride crystals grown either by the Czochralski technique or by the laser-heated pedestal growth method. Yb 3+ concentration dependence of the decay time is analyzed in order to understand involved concentration quenching mechanisms. Laser tests under saphire:Ti pumping are presented for all our materials as well as under diode pumping for Yb:CaF 2

  1. Predictive modeling of crystal accumulation in high-level waste glass melters processing radioactive waste

    Science.gov (United States)

    Matyáš, Josef; Gervasio, Vivianaluxa; Sannoh, Sulaiman E.; Kruger, Albert A.

    2017-11-01

    The effectiveness of high-level waste vitrification at Hanford's Waste Treatment and Immobilization Plant may be limited by precipitation/accumulation of spinel crystals [(Fe, Ni, Mn, Zn)(Fe, Cr)2O4] in the glass discharge riser of Joule-heated ceramic melters during idling. These crystals do not affect glass durability; however, if accumulated in thick layers, they can clog the melter and prevent discharge of molten glass into canisters. To address this problem, an empirical model was developed that can predict thicknesses of accumulated layers as a function of glass composition. This model predicts well the accumulation of single crystals and/or small-scale agglomerates, but excessive agglomeration observed in high-Ni-Fe glass resulted in an underprediction of accumulated layers, which gradually worsened over time as an increased number of agglomerates formed. The accumulation rate of ∼53.8 ± 3.7 μm/h determined for this glass will result in a ∼26 mm-thick layer after 20 days of melter idling.

  2. Modeling Textural Processes during Self-Assembly of Plant-Based Chiral-Nematic Liquid Crystals

    Directory of Open Access Journals (Sweden)

    Yogesh K. Murugesan

    2010-12-01

    Full Text Available Biological liquid crystalline polymers are found in cellulosic, chitin, and DNA based natural materials. Chiral nematic liquid crystalline orientational order is observed frozen-in in the solid state in plant cell walls and is known as a liquid crystal analogue characterized by a helicoidal plywood architecture. The emergence of the plywood architecture by directed chiral nematic liquid crystalline self assembly has been postulated as the mechanism that leads to optimal cellulose fibril organization. In natural systems, tissue growth and development takes place in the presence of inclusions and secondary phases leaving behind characteristic defects and textures, which provide a unique testing ground for the validity of the liquid crystal self-assembly postulate. In this work, a mathematical model, based on the Landau-de Gennes theory of liquid crystals, is used to simulate defect textures arising in the domain of self assembly, due to presence of secondary phases representing plant cells, lumens and pit canals. It is shown that the obtained defect patterns observed in some plant cell walls are those expected from a truly liquid crystalline phase. The analysis reveals the nature and magnitude of the viscoelastic material parameters that lead to observed patterns in plant-based helicoids through directed self-assembly. In addition, the results provide new guidance to develop biomimetic plywoods for structural and functional applications.

  3. Conductivity equations of protons transporting through 2D crystals obtained with the rate process theory and free volume concept

    Science.gov (United States)

    Hao, Tian; Xu, Yuanze; Hao, Ting

    2018-04-01

    The Eyring's rate process theory and free volume concept are employed to treat protons (or other particles) transporting through a 2D (two dimensional) crystal like graphene and hexagonal boron nitride. The protons are assumed to be activated first in order to participate conduction and the conduction rate is dependent on how much free volume available in the system. The obtained proton conductivity equations show that only the number of conduction protons, proton size and packing structure, and the energy barrier associated with 2D crystals are critical; the quantization conductance is unexpectedly predicted with a simple Arrhenius type temperature dependence. The predictions agree well with experimental observations and clear out many puzzles like much smaller energy barrier determined from experiments than from the density function calculations and isotope separation rate independent of the energy barrier of 2D crystals, etc. Our work may deepen our understandings on how protons transport through a membrane and has direct implications on hydrogen related technology and proton involved bioprocesses.

  4. The effect factors of potassium dihydrogen phosphate crystallization in aqueous solution

    Science.gov (United States)

    Zhou, Cun; Sun, Fei; Liu, Xuzhao

    2017-01-01

    The effects of cooling rate and pH on the potassium dihydrogen phosphate crystallization process were studied by means of batch crystallization process. The experiment shows that with the increase of cooling rate, the metastable zone width increase and the induction period decrease. When the pH is 3.0, the metastable zone width and induction period are both the minimum, while the crystallization rate is the highest. The crystallization products were characterized by scanning election microscope. Potassium Dihydrogen Phosphate (KDP) is a kind of excellent nonlinear optical materials, and belongs to tetragonal system, and ideal shape is aggregate of tetragonal prism and tetragonal dipyramid, the (100) cone is alternating accumulation by double positive ions and double negative ions [1-4]. The crystals of aqueous solution method to grow have large electro-optical nonlinear coefficient and high loser-damaged threshold, and it is the only nonlinear optical crystal could be used in inertial confinement fusion (ICF), KDP crystals are the ideal system to study the native defects of complex oxide insulating material [5-7]. With the development of photovoltaic technology, KDP crystals growth and performance have become a research focus worldwide [8, 9]. The merits of the crystallization process directly affect the quality of KDP products, so the study of the effect of crystallization conditions has an important significance on industrial production. This paper studied the change rule of metastable zone width, induction period, crystallization rate and particle size distribution in crystal process, and discussed the technical condition of KDP crystallization.

  5. Stochastic cooling

    International Nuclear Information System (INIS)

    Bisognano, J.; Leemann, C.

    1982-03-01

    Stochastic cooling is the damping of betatron oscillations and momentum spread of a particle beam by a feedback system. In its simplest form, a pickup electrode detects the transverse positions or momenta of particles in a storage ring, and the signal produced is amplified and applied downstream to a kicker. The time delay of the cable and electronics is designed to match the transit time of particles along the arc of the storage ring between the pickup and kicker so that an individual particle receives the amplified version of the signal it produced at the pick-up. If there were only a single particle in the ring, it is obvious that betatron oscillations and momentum offset could be damped. However, in addition to its own signal, a particle receives signals from other beam particles. In the limit of an infinite number of particles, no damping could be achieved; we have Liouville's theorem with constant density of the phase space fluid. For a finite, albeit large number of particles, there remains a residue of the single particle damping which is of practical use in accumulating low phase space density beams of particles such as antiprotons. It was the realization of this fact that led to the invention of stochastic cooling by S. van der Meer in 1968. Since its conception, stochastic cooling has been the subject of much theoretical and experimental work. The earliest experiments were performed at the ISR in 1974, with the subsequent ICE studies firmly establishing the stochastic cooling technique. This work directly led to the design and construction of the Antiproton Accumulator at CERN and the beginnings of p anti p colliding beam physics at the SPS. Experiments in stochastic cooling have been performed at Fermilab in collaboration with LBL, and a design is currently under development for a anti p accumulator for the Tevatron

  6. Workshop on beam cooling and related topics

    International Nuclear Information System (INIS)

    Bosser, J.

    1994-01-01

    The sessions of the Workshop on Beam Cooling and Related Topics, held in Montreux from 4-8 October 1993, are reported in these Proceedings. This meeting brought together international experts in the field of accelerator beam cooling. Its purpose was to discuss the status of the different cooling techniques currently in use (stochastic, electron, ionization, heavy-ion, and laser) and their actual performances, technological implications, and future prospects. Certain theoretical principles (muon cooling, cyclotron maser cooling) were discussed and are reported on in these Proceedings. Also of interest in this Workshop was the possibility of beam crystallization in accelerators using ultimate cooling. In the first part of these Proceedings, overview talks on the various cooling techniques, their implications, present performance, and future prospects are presented. More detailed reports on all the topics are then given in the form of oral presentations or poster sessions. Finally, the chairmen and/or convenors then present summary talks. (orig.)

  7. Investigation of cool down processes in a NPP turbine of the K-1000-60/1500 type

    International Nuclear Information System (INIS)

    Pereverzev, D.A.; Lebedev, A.G.; Palej, V.A.

    1985-01-01

    Methods of mathematical simulation were used to investigate cooling-off dynamics of separate NPP turbine parts of the K-1000-60/1500 type during shutdowns of different duration. Investigations indicated that a flange section of horizontal external casing joint in the steam inlet zone of the intermediate pressure casing is a main place limiting duration of turbine starting regime. When strengthening thermal protection of branch pipes, turbine start-up time (after shutdown during 72-168 h) can be reduced by 0.25-0.3 h; if also pick-ups are isolated than reduction of start-up duration will constitute 0.5-0.7 h. During shutdowns of shorter duration all critical assemblies will not limit in practice time of starting regime

  8. Modeling of the Radial Heat Flow and Cooling Processes in a Deep Ultraviolet Cu+ Ne-CuBr Laser

    Directory of Open Access Journals (Sweden)

    Iliycho Petkov Iliev

    2009-01-01

    Full Text Available An improved theoretical model of the gas temperature profile in the cross-section of an ultraviolet copper ion excited copper bromide laser is developed. The model is based on the solution of the one-dimensional heat conduction equation subject to special nonlinear boundary conditions, describing the heat interaction between the laser tube and its surroundings. It takes into account the nonuniform distribution of the volume power density along with the radius of the laser tube. The problem is reduced to the boundary value problem of the first kind. An explicit solution of this model is obtained. The model is applied for the evaluation of the gas temperature profiles of the laser in the conditions of free and forced air-cooling. Comparison with other simple models assumed constant volume power density is made. In particular, a simple expression for calculating the average gas temperature is found.

  9. Modern cooling systems in thermal power plants relieve environmental pollution. Pt. 2

    International Nuclear Information System (INIS)

    Brosche, D.

    1983-01-01

    Direct and indirect dry recirculation cooling, wet cooling tower, natural-draught wet cooling tower, combined cooling processes, hybrid cooling systems, cell cooling systems, auxiliary water preparation, cooling process design, afterheat removal in nuclear power plants, environmental effects, visible plumes as a function of weather conditions, environmental protection and energy supply assurance. (orig.) [de

  10. In-situ Spectroscopic Studies and Modelling of Crystallization Processes of Sulphuric Acid Catalysts

    DEFF Research Database (Denmark)

    Oehlers, C.; Fehrmann, Rasmus; Masters, Stephen Grenville

    1996-01-01

    Deactivation of commercial and prototype sulphuric acid catalysts has been investigated in-situ by ESR spectroscopy. The influence of support pore structure,and the chemical composition of the catalyst and the gas phase was dicussed.A statistical lattice model was applied to describe the crystall......Deactivation of commercial and prototype sulphuric acid catalysts has been investigated in-situ by ESR spectroscopy. The influence of support pore structure,and the chemical composition of the catalyst and the gas phase was dicussed.A statistical lattice model was applied to describe...

  11. All-optical signal processing using InP photonic-crystal nanocavity switches

    DEFF Research Database (Denmark)

    Yu, Yi; Vukovic, Dragana; Heuck, Mikkel

    2014-01-01

    In this paper, we present recent progress in experimental characterization of InP photonic-crystal nanocavity switches. Pump-probe measurements on an InP PhC H0 cavity show large-contrast ultrafast switching at low pulse energy. At large pulse energies, a large resonance shift passing across...... for the joint effects of fast carrier diffusion, slow surface and bulk recombination. Utilizin g the simple InP PhC nanocavity structure, we successfully dem onstrate 10-Gb/s RZ- OOK all-optical modulation with low energy consumption....

  12. Design of a Eutectic Freeze Crystallization process for multicomponent waste water stream

    DEFF Research Database (Denmark)

    Lewis, Alison E.; Nathoo, J.; Thomsen, Kaj

    2010-01-01

    Complex, hypersaline brines originating from the mining and extractive metallurgical industries have the potential to be treated using Eutectic Freeze Crystallization (EFC). Although EFC has been shown to be effective in separating a single salt and water, it has yet to be applied to the complex...... hypersaline brines that are typical of reverse osmosis retentates in South Africa. This paper focuses on the application of EFC for the purification of a typical brine containing high levels of sodium, chlorine, sulphate and ammonia that cannot be achieved with other separation techniques. The presence...

  13. Crystal structure of aspartame anhydrate from powder diffraction data. Structural aspects of the dehydration process of aspartame

    NARCIS (Netherlands)

    Guguta, C.; Meekes, H.L.M.; Gelder, R. de

    2006-01-01

    Aspartame has three pseudo-polymorphic forms, two hydrates and a hemi-hydrate, for which crystal structures were determined from single-crystal diffraction data. This paper presents the crystal structure of the anhydrate, which was obtained by dehydrating the hemi-hydrate. The crystal structure of

  14. Processes for the elimination of fogging on KDP crystals prior to and during use in laser systems

    International Nuclear Information System (INIS)

    Thomas, I.M.; Kozlowski, M.R.; Edwards, G.; Stanion, K.; Fuchs, B.

    1992-01-01

    The rate of surface fogging on KDP crystals has been associated with several parameters in the diamond turning and subsequent cleaning process. Fogging can also occur during use because of environmental degradation. We have determined that reaction of the KDP surfaces with additives in the diamond turning oil has been a major factor in fogging and have found a replacement oil that eliminates this effect. We have also developed an antireflective silicone-sol coating that also reduces surface environmental deterioration during use by a factor of four

  15. Mode-selective mapping and control of vectorial nonlinear-optical processes in multimode photonic-crystal fibers.

    Science.gov (United States)

    Hu, Ming-Lie; Wang, Ching-Yue; Song, You-Jian; Li, Yan-Feng; Chai, Lu; Serebryannikov, Evgenii; Zheltikov, Aleksei

    2006-02-06

    We demonstrate an experimental technique that allows a mapping of vectorial nonlinear-optical processes in multimode photonic-crystal fibers (PCFs). Spatial and polarization modes of PCFs are selectively excited in this technique by varying the tilt angle of the input beam and rotating the polarization of the input field. Intensity spectra of the PCF output plotted as a function of the input field power and polarization then yield mode-resolved maps of nonlinear-optical interactions in multimode PCFs, facilitating the analysis and control of nonlinear-optical transformations of ultrashort laser pulses in such fibers.

  16. Registration of melting and crystallization process of MCMgLi8Ca5 alloy with use of ATND method

    Directory of Open Access Journals (Sweden)

    J. Pezda

    2009-04-01

    Full Text Available Among lightweight metal alloys, magnesium is the lightest structural material with density of 1.74 g/cm3, having many attractive physical and mechanical properties combined with processing advantages. Therefore, it represents very attractive material for large amountof applications starting from automotive industry as the main user, up to other industry fields like sports, robotic electronics, armaments, and textile ones, or production of audio-video equipment. Furthermore, addition of lithium, that has density of 0,53 g/cm3, reduces density of the resulting Mg-Li alloys to the same level as polymeric materials. On metallic matrix of magnesium alloys with lithium are also manufactured composites reinforced with e.g. ceramic fiber, which are used as a lightweight and resistant structure materials. Therefore, Mg-Li alloys become an alternative material assuring low density, improved ductility and corrosion resistance.The paper presents an attempt of implementation of the ATND method to monitoring of crystallization process of MCMgLi8Ca5 alloys.Investigated magnesium alloys were produced in the Foundry Research Institute. Registration of melting and crystallization processes wasmade with use of the ATND method. Results of the preliminary tests are shown in a graphical form.

  17. A very cool cooling system

    CERN Multimedia

    Antonella Del Rosso

    2015-01-01

    The NA62 Gigatracker is a jewel of technology: its sensor, which delivers the time of the crossing particles with a precision of less than 200 picoseconds (better than similar LHC detectors), has a cooling system that might become the precursor to a completely new detector technique.   The 115 metre long vacuum tank of the NA62 experiment. The NA62 Gigatracker (GTK) is composed of a set of three innovative silicon pixel detectors, whose job is to measure the arrival time and the position of the incoming beam particles. Installed in the heart of the NA62 detector, the silicon sensors are cooled down (to about -20 degrees Celsius) by a microfluidic silicon device. “The cooling system is needed to remove the heat produced by the readout chips the silicon sensor is bonded to,” explains Alessandro Mapelli, microsystems engineer working in the Physics department. “For the NA62 Gigatracker we have designed a cooling plate on top of which both the silicon sensor and the...

  18. Design and analysis of a small-scale natural gas liquefaction process adopting single nitrogen expansion with carbon dioxide pre-cooling

    International Nuclear Information System (INIS)

    Yuan, Zongming; Cui, Mengmeng; Xie, Ying; Li, Chunlin

    2014-01-01

    With the growth of energy consumption and environmental protection concerns, it is of enormous economic and environmental values for the development of stranded gas. As a means for exploitation and transportation of stranded gas to market, a novel small-scale liquefaction process adopting single nitrogen expansion with carbon dioxide pre-cooling is put up with in this paper. Taking unit energy consumption as the target function, Aspen HYSYS is employed to simulate and optimize the process to achieve the liquefaction rate of 0.77 with unit energy consumption of 9.90 kW/kmol/h. Furthermore, the adaptability of this process under different pressure, temperature and compositions of feed gas is studied. Based on the optimization results, the exergy losses of main equipment in the process are evaluated and analyzed in details. With compact device, safety operation, simple capability, this liquefaction process proves to be suitable for the development of small gas reserves, satellite distribution fields of gas or coalbed methane fields. - Highlights: •A novel small-scale liquefaction process used in stranded gas is designed. •The adaptability of this process under different pressure, temperature and compositions of feed gas is studied. •The exergy analysis of main equipment in the process is analyzed

  19. Design and analysis of a small-scale natural gas liquefaction process adopting single nitrogen expansion with carbon dioxide pre-cooling

    Energy Technology Data Exchange (ETDEWEB)

    Yuan, Zongming; Cui, Mengmeng; Xie, Ying; Li, Chunlin

    2014-03-01

    With the growth of energy consumption and environmental protection concerns, it is of enormous economic and environmental values for the development of stranded gas. As a means for exploitation and transportation of stranded gas to market, a novel small-scale liquefaction process adopting single nitrogen expansion with carbon dioxide pre-cooling is put up with in this paper. Taking unit energy consumption as the target function, Aspen HYSYS is employed to simulate and optimize the process to achieve the liquefaction rate of 0.77 with unit energy consumption of 9.90 kW/kmol/h. Furthermore, the adaptability of this process under different pressure, temperature and compositions of feed gas is studied. Based on the optimization results, the exergy losses of main equipment in the process are evaluated and analyzed in details. With compact device, safety operation, simple capability, this liquefaction process proves to be suitable for the development of small gas reserves, satellite distribution fields of gas or coalbed methane fields. - Highlights: •A novel small-scale liquefaction process used in stranded gas is designed. •The adaptability of this process under different pressure, temperature and compositions of feed gas is studied. •The exergy analysis of main equipment in the process is analyzed.

  20. Cooling pancakes

    International Nuclear Information System (INIS)

    Bond, J.R.; Wilson, J.R.

    1984-01-01

    In theories of galaxy formation with a damping cut-off in the density fluctuation spectrum, the first non-linear structures to form are Zeldovich pancakes in which dissipation separates gas from any collisionless dark matter then present. One-dimensional numerical simulations of the collapse, shock heating, and subsequent thermal evolution of pancakes are described. Neutrinos (or any other cool collisionless particles) are followed by direct N-body methods and the gas by Eulerian hydrodynamics with conduction as well as cooling included. It is found that the pressure is relatively uniform within the shocked region and approximately equals the instantaneous ram pressure acting at the shock front. An analytic theory based upon this result accurately describes the numerical calculations. (author)

  1. Cool Sportswear

    Science.gov (United States)

    1982-01-01

    New athletic wear design based on the circulating liquid cooling system used in the astronaut's space suits, allows athletes to perform more strenuous activity without becoming overheated. Techni-Clothes gear incorporates packets containing a heat-absorbing gel that slips into an insulated pocket of the athletic garment and is positioned near parts of the body where heat transfer is most efficient. A gel packet is good for about one hour. Easily replaced from a supply of spares in an insulated container worn on the belt. The products, targeted primarily for runners and joggers and any other athlete whose performance may be affected by hot weather, include cooling headbands, wrist bands and running shorts with gel-pack pockets.

  2. Cooling systems

    International Nuclear Information System (INIS)

    Coutant, C.C.

    1978-01-01

    Progress on the thermal effects project is reported with regard to physiology and distribution of Corbicula; power plant effects studies on burrowing mayfly populations; comparative thermal responses of largemouth bass from northern and southern populations; temperature selection by striped bass in Cherokee Reservoir; fish population studies; and predictive thermoregulation by fishes. Progress is also reported on the following; cause and ecological ramifications of threadfin shad impingement; entrainment project; aquaculture project; pathogenic amoeba project; and cooling tower drift project

  3. Review of cavity optomechanical cooling

    International Nuclear Information System (INIS)

    Liu Yong-Chun; Hu Yu-Wen; Xiao Yun-Feng; Wong Chee Wei

    2013-01-01

    Quantum manipulation of macroscopic mechanical systems is of great interest in both fundamental physics and applications ranging from high-precision metrology to quantum information processing. For these purposes, a crucial step is to cool the mechanical system to its quantum ground state. In this review, we focus on the cavity optomechanical cooling, which exploits the cavity enhanced interaction between optical field and mechanical motion to reduce the thermal noise. Recent remarkable theoretical and experimental efforts in this field have taken a major step forward in preparing the motional quantum ground state of mesoscopic mechanical systems. This review first describes the quantum theory of cavity optomechanical cooling, including quantum noise approach and covariance approach; then, the up-to-date experimental progresses are introduced. Finally, new cooling approaches are discussed along the directions of cooling in the strong coupling regime and cooling beyond the resolved sideband limit. (topical review - quantum information)

  4. Reduction of radiation fields in the cooling water circuits of PWRs: a one-step or a multistep process

    International Nuclear Information System (INIS)

    Lassau, R.T.; Cherepakhov, G.; Smee, J.L.; Berger, J.

    1988-01-01

    A basic problem for nuclear power plants is the formation or radioactive corrosion products in crud particles and oxide films found mainly in the primary side of the reactor cooling water circuits. The activated corrosion products produce radiation fields, which are the major source of exposure for personnel during maintenance and operation of the system. As a health safeguard for personnel, and for the considerable economic benefit to a plant that can be realized by the reduction of radiation fields, the nuclear industry implements physical and chemical decontamination methods to dissolve oxide films and to assist in the removal of crud during plant shutdowns. These procedures impact on the scheduling of activities that must be accomplished before the reactor can be returned to full operation and are therefore carefully planned to minimize the time for decontamination while maximizing the radioactive field reductions. Of considerable importance to the industry, therefore, are procedures that might be implemented during normal reactor operation and as a reactor approaches shutdown that would assist in the removal of radioactive material while controlling the recontamination during reactor operation. A study program was therefore undertaken to compare radioactive field reductions and corrosion rates obtained from a dilute multistep chemical decontamination with data obtained from a single-step parametric cycling experiment on PWR materials

  5. Experiments of cooling photovoltaic panel by desorption process; Dacchaku hanno wo riyoshita taiyoko hatsuden panel no ondo josho yokusei jikken

    Energy Technology Data Exchange (ETDEWEB)

    Akisawa, A; Inoue, S; Kashiwagi, T [Tokyo University of Agriculture and Technology, Tokyo (Japan)

    1997-11-25

    It is important to cool a photovoltaic (PV) panel, because increased panel temperature is accompanied by decreased power generation efficiency. The authors have proposed a PV power generation system combined with an adsorption chiller driven by low-temperature heat, and simulated temperature changes during the desorption cycle, where the chiller utilizes endothermic reactions of an adsorbent during the desorption cycle. Described herein are results of the tests carried out to validate possibility of controlling panel temperature increase. The system consists of the PV panel with which a bed packed with an adsorbent is monolithically combined, condenser and evaporator. It generates power during the daytime by sunbeams, and provides low-temperature heat during the nighttime by the evaporator. In particular, ice can be produced when methanol and activated coal are used as the adsorbate and adsorbent. It has an advantage of effective utilization of energy as the heat source, which has been merely dissipated by the conventional system in the air. Such a system is expected to be useful for promoting effective utilization of solar energy and for peak power shaving in summer. The initial targets are achieved by the tests. 4 refs., 10 figs.

  6. Combining nanocalorimetry and dynamic transmission electron microscopy for in situ characterization of materials processes under rapid heating and cooling

    Energy Technology Data Exchange (ETDEWEB)

    Grapes, Michael D., E-mail: mgrapes1@jhu.edu [Department of Materials Science and Engineering, Johns Hopkins University, Baltimore, Maryland 21218 (United States); Materials Measurement Science Division, Material Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); LaGrange, Thomas; Reed, Bryan W.; Campbell, Geoffrey H. [Condensed Matter and Materials Division, Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Friedman, Lawrence H.; LaVan, David A., E-mail: david.lavan@nist.gov [Materials Measurement Science Division, Material Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Weihs, Timothy P., E-mail: weihs@jhu.edu [Department of Materials Science and Engineering, Johns Hopkins University, Baltimore, Maryland 21218 (United States)

    2014-08-15

    Nanocalorimetry is a chip-based thermal analysis technique capable of analyzing endothermic and exothermic reactions at very high heating and cooling rates. Here, we couple a nanocalorimeter with an extremely fast in situ microstructural characterization tool to identify the physical origin of rapid enthalpic signals. More specifically, we describe the development of a system to enable in situ nanocalorimetry experiments in the dynamic transmission electron microscope (DTEM), a time-resolved TEM capable of generating images and electron diffraction patterns with exposure times of 30 ns–500 ns. The full experimental system consists of a modified nanocalorimeter sensor, a custom-built in situ nanocalorimetry holder, a data acquisition system, and the DTEM itself, and is capable of thermodynamic and microstructural characterization of reactions over a range of heating rates (10{sup 2} K/s–10{sup 5} K/s) accessible by conventional (DC) nanocalorimetry. To establish its ability to capture synchronized calorimetric and microstructural data during rapid transformations, this work describes measurements on the melting of an aluminum thin film. We were able to identify the phase transformation in both the nanocalorimetry traces and in electron diffraction patterns taken by the DTEM. Potential applications for the newly developed system are described and future system improvements are discussed.

  7. PROCESS OF OBTAINING OF SUGAR FROM SUGAR BEET AND INFLUENCE ON ITS QUALITY

    Directory of Open Access Journals (Sweden)

    Marián Tokár

    2011-02-01

    Full Text Available Cooking of massecuites has been study in the connection with different particle size distribution of white sugar. During the crystallization is possible to operate with parameters which have influence on particle size of white sugar. Dry matter of juice in crystallizer, volume of the standard syrup in crystallizer and heating curve of crystallization process are constant parameters in this process. Quantity of slurry (seed magma crystallizate and volume of slurry massecuite are parameters which can be changed for control the particle size distribution of white sugar. Five variants of viable parameters have been trying for obtain ideal particle size distribution of white sugar. As a best has been evaluated variant with 1100 cm3 of slurry and 20 % of volume of slurry massecuite in crystallizer. This variant has had the crystals proportions captured by the sieves between 1.00 and 0.40 mm with minimal differences in weight. More results have been related to reduction of losses of sugar in molasses with the right setting for the line of cooling crystallization process. The looses of sugar can be reduced by adding two coolers in the end of cooling crystalization process what will decrease a temperature to 40 ° C. This temperature will lead to more efficient crystallization in the cooling crystallization process.doi:10.5219/122

  8. Techniques and processes for the measurement of the resonances of small single crystals

    International Nuclear Information System (INIS)

    Migliori, A.; Stekel, A.; Sarrao, J.L.; Visscher, W.M.; Bell, T.; Lei, M.

    1991-01-01

    The mechanical resonances of small oriented single crystals of materials of interest to basic science and engineering can be used to determine all the elastic moduli and the ultrasonic attenuation of these materials. To measure the resonances of the samples without introducing the resonances of the measuring system requires that the transducers be non-resonant at the frequencies of interest, and that they be well isolated from their mounts. However, for samples near 1 mm in the largest dimension, the transducer design problem becomes sever, and the signals become weak. In addition, no resonances can be missed, and, often, the symmetry class of the resonances must be known. We outline here appropriate transducer, electronics, and system designs to circumvent these problems. 10 refs., 4 figs

  9. USING OF THE FOLK SOURCE IN THE PROCESS OF CRYSTALLIZATION OF ROMANIAN CHORAL MUSIC

    Directory of Open Access Journals (Sweden)

    MORARU EMILIA

    2015-12-01

    Full Text Available The Romanian choral music from the second half of the nineteenth century and the beginning of the twentieth century was built on the foundation of folk art, expressed through the monodic popular song, peasant dance and church music. Jn the pages of this article, the author highlights the most representative works of folk inspiration, signed by predecessor composers of Romanian choral music, who, through their creative effort, contributed essentially to the crystallization of the genre of the choral music of this period. Thus, in the author’s objective were the creations of composers Alexandru Flechtenmacher, Eduard Wachmann, Eduard Caudella, Gavriil Musicescu, Gheorghe Dima, Jacob Mureşianu, Ciprian Porumbescu, Jon Vidu and others.

  10. Registration of Crystallization Process of Ultra-Lightweight Mg-Li Alloys with Use of ATND Method

    Directory of Open Access Journals (Sweden)

    A. Białobrzeski

    2007-07-01

    Full Text Available Magnesium alloys are characterized by advantageous ratio of strength and/or elastic modulus to density, that is, can sustain static and dynamic loads similar to iron and aluminium, and additionally feature good vibration damping. Castings from magnesium alloys are lighter with about 20 – 30% than aluminium alloys and with 50 – 75% than iron alloys, that is why they are used in aviation and rocket industry and everywhere the weight of a product is of important significance for conditions of its operation. Also automotive industry introduces to vehicle’s structure an elements (castings manufactured from such alloys. On metallic matrix of magnesium alloys with lithium are also manufactured a composites reinforced with e.g. ceramic fiber, which are used as lightweight and resistant structure materials. The paper presents an attempt of implementation of ATND method (Thermal-Voltage-Derivative Analysis to monitoring of crystallization process of ultra-lightweight Mg-Li alloys. Investigated magnesium alloys with contents of about 2,3% Li, 10% Li and 11 % Li were produced in the Foundry Research Institute. Registration of melting and crystallization processes was made with use of the ATND method. Results of preliminary tests are shown in graphical form.

  11. Supersaturation Control using Analytical Crystal Size Distribution Estimator for Temperature Dependent in Nucleation and Crystal Growth Phenomena

    Science.gov (United States)

    Zahari, Zakirah Mohd; Zubaidah Adnan, Siti; Kanthasamy, Ramesh; Saleh, Suriyati; Samad, Noor Asma Fazli Abdul

    2018-03-01

    The specification of the crystal product is usually given in terms of crystal size distribution (CSD). To this end, optimal cooling strategy is necessary to achieve the CSD. The direct design control involving analytical CSD estimator is one of the approaches that can be used to generate the set-point. However, the effects of temperature on the crystal growth rate are neglected in the estimator. Thus, the temperature dependence on the crystal growth rate needs to be considered in order to provide an accurate set-point. The objective of this work is to extend the analytical CSD estimator where Arrhenius expression is employed to cover the effects of temperature on the growth rate. The application of this work is demonstrated through a potassium sulphate crystallisation process. Based on specified target CSD, the extended estimator is capable of generating the required set-point where a proposed controller successfully maintained the operation at the set-point to achieve the target CSD. Comparison with other cooling strategies shows a reduction up to 18.2% of the total number of undesirable crystals generated from secondary nucleation using linear cooling strategy is achieved.

  12. Simulation of warpage induced by non-isothermal crystallization of co-polypropylene during the SLS process

    Science.gov (United States)

    Amado, Antonio; Schmid, Manfred; Wegener, Konrad

    2015-05-01

    Polymer processing using Additive Manufacturing Technologies (AM) has experienced a remarkable growth during the last years. The application range has been expanding rapidly, particularly driven by the so-called consumer 3D printing sector. However, for applications demanding higher requirements in terms of thermo-mechanical properties and dimensional accuracy the long established AM technologies such as Selective Laser Sintering (SLS) do not depict a comparable development. The higher process complexity hinders the number of materials that can be currently processed and the interactions between the different physics involved have not been fully investigated. In case of thermoplastic materials the crystallization kinetics coupled to the shrinkage strain development strongly influences the stability of the process. Thus, the current investigation presents a transient Finite Element simulation of the warpage effect during the SLS process of a new developed polyolefin (co-polypropylene) coupling the thermal, mechanical and phase change equations that control the process. A thermal characterization of the material was performed by means of DSC, integrating the Nakamura model with the classical Hoffmann-Lauritzen theory. The viscoelastic behavior was measured using a plate-plate rheometer at different degrees of undercooling and a phase change-temperature superposition principle was implemented. Additionally, for validation porpoises the warpage development of the first sintered layers was captured employing an optical device. The simulation results depict a good agreement with experimental measurements of deformation, describing the high sensitivity of the geometrical accuracy of the sintered parts related to the processing conditions.

  13. Energy-constrained open-system magmatic processes IV: Geochemical, thermal and mass consequences of energy-constrained recharge, assimilation and fractional crystallization (EC-RAFC)

    International Nuclear Information System (INIS)

    Wendy A. Bohrson Department of Geological Sciences, Central Washington University, Ellensburg, Washington, 98926, USA; Frank J. Spera Institute for Crustal Studies and Department of Geological Sciences, University of California, Santa Barbara, California, 93106, USA

    2003-01-01

    A wealth of geochemical and petrological data provide evidence that the processes of fractional crystallization, assimilation, and magma recharge (replenishment) dominate the chemical signatures of many terrestrial igneous rocks. Previous work [Spera and Bohrson, 2001 ; Bohrson and Spera, 2001] has established the importance of integrating energy, species and mass conservation into simulations of complex magma chamber processes. An extended version of the energy-constrained formulation, Energy-Constrained Recharge, Assimilation, Fractional Crystallization (EC-RAFC), tracks mass and compositional variations of melt, cumulates, and enclaves in a magma body undergoing simultaneous recharge, assimilation, and fractional crystallization [Spera and Bohrson, 2002]. Because many EC-RAFC results are distinct from those predicted by extant RAFC formulations, the primary goal of this paper is to present a range of geochemical and mass relationships for selected cases that highlight issues relevant to modern petrology. Among the plethora of petrologic problems that have important, well-documented analogues in nature are the geochemical distinctions that arise when a magma body undergoes continuous versus episodic recharge, the connection between erupted magmas and associated cumulate bodies, the behavior of recharge-fractionation dominated systems (RFC), thermodynamic conditions that promote the formation of enclaves versus cumulates, and the conditions under which magma bodies may be described as chemically homogeneous. Investigation of the effects of continuous versus episodic recharge for mafic magma undergoing RAFC in the lower crust indicates that the resulting geochemical trends for melt and solids are sensitive to the intensity and composition of recharge, suggesting that EC-RAFC may be used as a tool to distinguish the nature of the recharge events. Compared to the record preserved in melts, the geochemical and mass characteristics of solids associated with particular

  14. The effect of freestream turbulence on film cooling adiabatic effectiveness

    International Nuclear Information System (INIS)

    Mayhew, James E.; Baughn, James W.; Byerley, Aaron R.

    2003-01-01

    The film-cooling performance of a flat plate in the presence of low and high freestream turbulence is investigated using liquid crystal thermography. This paper contributes high-resolution color images that clearly show how the freestream turbulence spreads the cooling air around a larger area of the film-cooled surface. Distributions of the adiabatic effectiveness are determined over the film-cooled surface of the flat plate using the hue method and image processing. Three blowing rates are investigated for a model with three straight holes spaced three diameters apart, with density ratio near unity. High freestream turbulence is shown to increase the area-averaged effectiveness at high blowing rates, but decrease it at low blowing rates. At low blowing ratio, freestream turbulence clearly reduces the coverage area of the cooling air due to increased mixing with the main flow. However, at high blowing ratio, when much of the jet has lifted off in the low turbulence case, high freestream turbulence turns its increased mixing into an asset, entraining some of the coolant that penetrates into the main flow and mixing it with the air near the surface

  15. System for fast and accurate filling of a two-phase cooling device, notably a heat pipe, adapted for use in an automated process

    NARCIS (Netherlands)

    Wits, Wessel Willems; Ten Hoeve, Harm Jan; Te Riele Gert, Jan; Van Es, Johannes

    2013-01-01

    The current invention relates to a system for fast and accurate filling of a two-phase cooling device, comprising a binding device (30) intended to be hermetically mounted onto the cooling device, the binding device (30) comprising a through-hole (32) able to be in fluid contact with the cooling

  16. SYSTEM FOR FAST AND ACCURATE FILLING OF A TWO-PHASE COOLING DEVICE, NOTABLY A HEAT PIPE, ADAPTED FOR USE IN AN AUTOMATED PROCESS

    NARCIS (Netherlands)

    Wits, Wessel Willems; Ten Hoeve, Harm Jan; Te Riele Gert, Jan; Van Es, Johannes

    2013-01-01

    The current invention relates to a system for fast and accurate filling of a two- phase cooling device, comprising a binding device (30) intended to be hermetically mounted onto the cooling device, the binding device (30) comprising a through-hole (32) able to be in fluid contact with the cooling

  17. SYSTEM FOR FAST AND ACCURATE FILLING OF A TWO-PHASE COOLING DEVICE, NOTABLY A HEAT PIPE, ADAPTED FOR USE IN AN AUTOMATED PROCESS

    NARCIS (Netherlands)

    Wits, Wessel Willems; Ten Hoeve, Harm Jan; Te Riele Gert, Jan; Van Es, Johannes; Wits, Wessel Willems; Ten Hoeve, Harm Jan; Te Riele, Gerhardus Wilhelmus; Van Es, Johannes

    2014-01-01

    The current invention relates to a system for fast and accurate filling of a two-phase cooling device, comprising a binding device (30) intended to be hermetically mounted onto the cooling device, the binding device (30) comprising a through-hole (32) able to be in fluid contact with the cooling

  18. A Process for Evaluating Adverse Environmental Impacts by Cooling-Water System Entrainment at a California Power Plant

    Directory of Open Access Journals (Sweden)

    C.P. Ehrler

    2002-01-01

    Full Text Available A study to determine the effects of entrainment by the Diablo Canyon Power Plant (DCPP was conducted between 1996 and 1999 as required under Section 316(b of the Clean Water Act. The goal of this study was to present the U.S. Environmental Protection Agency (EPA and Central Coast Regional Water Quality Control Board (CCRWQCB with results that could be used to determine if any adverse environmental impacts (AEIs were caused by the operation of the plant’s cooling-water intake structure (CWIS. To this end we chose, under guidance of the CCRWQCB and their entrainment technical working group, a unique approach combining three different models for estimating power plant effects: fecundity hindcasting (FH, adult equivalent loss (AEL, and the empirical transport model (ETM. Comparisons of the results from these three approaches provided us a relative measure of confidence in our estimates of effects. A total of 14 target larval fish taxa were assessed as part of the DCPP 316(b. Example results are presented here for the kelp, gopher, and black-and-yellow (KGB rockfish complex and clinid kelpfish. Estimates of larval entrainment losses for KGB rockfish were in close agreement (FH is approximately equals to 550 adult females per year, AEL is approximately equals to 1,000 adults [male and female] per year, and ETM = larval mortality as high as 5% which could be interpreted as ca. 2,600 1 kg adult fish. The similar results from the three models provided confidence in the estimated effects for this group. Due to lack of life history information needed to parameterize the FH and AEL models, effects on clinid kelpfish could only be assessed using the ETM model. Results from this model plus ancillary information about local populations of adult kelpfish suggest that the CWIS might be causing an AEI in the vicinity of DCPP.

  19. Identification of important phenomena under sodium fire accidents based on PIRT process with factor analysis in sodium-cooled fast reactor

    International Nuclear Information System (INIS)

    Aoyagi, Mitsuhiro; Uchibori, Akihiro; Kikuchi, Shin; Takata, Takashi; Ohno, Shuji; Ohshima, Hiroyuki

    2016-01-01

    The PIRT (Phenomena Identification and Ranking Table) process is an effective method to identify key phenomena involved in safety issues in nuclear power plants. The present PIRT process is aimed to validate sodium fire analysis codes. Because a sodium fire accident in sodium-cooled fast reactor (SFR) involves complex phenomena, various figures of merit (FOMs) could exist in this PIRT process. In addition, importance evaluation of phenomena for each FOM should be implemented in an objective manner under the PIRT process. This paper describes the methodology for specification of FOMs, identification of associated phenomena and importance evaluation of each associated phenomenon in order to complete a ranking table of important phenomena involved in a sodium fire accident in an SFR. The FOMs were specified through factor analysis in this PIRT process. Physical parameters to be quantified by a sodium fire analysis code were identified by considering concerns resulting from sodium fire in the factor analysis. Associated phenomena were identified through the element- and sequence-based phenomena analyses as is often conducted in PIRT processes. Importance of each associated phenomenon was evaluated by considering the sequence-based analysis of associated phenomena correlated with the FOMs. Then, we complete the ranking table through the factor and phenomenon analyses. (author)

  20. Numerical analysis of the heat and mass transfer processes in selected M-Cycle heat exchangers for the dew point evaporative cooling

    International Nuclear Information System (INIS)

    Pandelidis, Demis; Anisimov, Sergey

    2015-01-01

    Highlights: • The comparative numerical study of the eight M-Cycle heat exchangers was presented. • The mathematical model is compared against the experimental data. • The results show, that the original M-Cycle heat and mass exchanger can be improved. • The effectiveness of the heat and mass exchangers depends strongly on the inlet air parameters. - Abstract: This paper investigates a mathematical simulation of heat and mass transfer in eight different types of the Maisotsenko Cycle (M-Cycle) heat and mass exchangers (HMXs) used for indirect evaporative air cooling. A two-dimensional heat and mass transfer model is developed to perform the thermal calculations of the indirect evaporative cooling process and quantifying the overall performance. The mathematical model was validated against experimental data. A numerical simulation reveals many unique features of the considered HMXs, enabling an accurate prediction of their performance. Results of the model allow for comparison of the analyzed devices in order to improve the performance of the original HMX