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Sample records for composite conical shells

  1. Time dependent response of low velocity impact induced composite conical shells under multiple delamination

    Science.gov (United States)

    Dey, Sudip; Karmakar, Amit

    2014-02-01

    This paper presents the time dependent response of multiple delaminated angle-ply composite pretwisted conical shells subjected to low velocity normal impact. The finite element formulation is based on Mindlin's theory incorporating rotary inertia and effects of transverse shear deformation. An eight-noded isoparametric plate bending element is employed to satisfy the compatibility of deformation and equilibrium of resultant forces and moments at the delamination crack front. A multipoint constraint algorithm is incorporated which leads to asymmetric stiffness matrices. The modified Hertzian contact law which accounts for permanent indentation is utilized to compute the contact force, and the time dependent equations are solved by Newmark's time integration algorithm. Parametric studies are conducted with respect to triggering parameters like laminate configuration, location of delamination, angle of twist, velocity of impactor, and impactor's displacement for centrally impacted shells.

  2. Thermoelectrically induced nonlinear free vibration analysis of piezo laminated composite conical shell panel with random fiber orientation

    Directory of Open Access Journals (Sweden)

    Lal Achchhe

    2017-09-01

    Full Text Available This paper presents the free vibration response of piezo laminated composite geometrically nonlinear conical shell panel subjected to a thermo-electrical loading. The temperature field is assumed to be a uniform distribution over the shell surface and through the shell thickness and the electric field is assumed to be the transverse component E2 only. The material properties are assumed to be independent of the temperature and the electric field. The basic formulation is based on higher order shear deformation plate theory (HSDT with von-Karman nonlinearity. A C0 nonlinear finite element method based on direct iterative approach is outlined and applied to solve nonlinear generalized eigenvalue problem. Parametric studies are carried out to examine the effect of amplitude ratios, stacking sequences, cone angles, piezoelectric layers, applied voltages, circumferential length to thickness ratios, change in temperatures and support boundary conditions on the nonlinear natural frequency of laminated conical shell panels. The present outlined approach has been validated with those available results in the literature.

  3. Non-linear buckling of an FGM truncated conical shell surrounded by an elastic medium

    International Nuclear Information System (INIS)

    Sofiyev, A.H.; Kuruoglu, N.

    2013-01-01

    In this paper, the non-linear buckling of the truncated conical shell made of functionally graded materials (FGMs) surrounded by an elastic medium has been studied using the large deformation theory with von Karman–Donnell-type of kinematic non-linearity. A two-parameter foundation model (Pasternak-type) is used to describe the shell–foundation interaction. The FGM properties are assumed to vary continuously through the thickness direction. The fundamental relations, the modified Donnell type non-linear stability and compatibility equations of the FGM truncated conical shell resting on the Pasternak-type elastic foundation are derived. By using the Superposition and Galerkin methods, the non-linear stability equations for the FGM truncated conical shell is solved. Finally, influences of variations of Winkler foundation stiffness and shear subgrade modulus of the foundation, compositional profiles and shell characteristics on the dimensionless critical non-linear axial load are investigated. The present results are compared with the available data for a special case. -- Highlights: • Nonlinear buckling of FGM conical shell surrounded by elastic medium is studied. • Pasternak foundation model is used to describe the shell–foundation interaction. • Nonlinear basic equations are derived. • Problem is solved by using Superposition and Galerkin methods. • Influences of various parameters on the nonlinear critical load are investigated

  4. Design and Manufacture of Conical Shell Structures Using Prepreg Laminates

    Science.gov (United States)

    Khakimova, Regina; Burau, Florian; Degenhardt, Richard; Siebert, Mark; Castro, Saullo G. P.

    2016-06-01

    The design and manufacture of unstiffened composite conical structures is very challenging, as the variation of the fiber orientations, lay-up and the geometry of the ply pieces have a significant influence on the thickness imperfections and ply angle deviations imprinted to the final part. This paper deals with the manufacture of laminated composite cones through the prepeg/autoclave process. The cones are designed to undergo repetitive buckling tests without accumulating permanent damage. The aim is to define a process that allows the control of fiber angle deviations and the removal of thickness imperfections generated from gaps and overlaps between ply pieces. Ultrasonic scan measurements are used to proof the effectiveness of the proposed method.

  5. Effect of Location of Delamination on Free Vibration of Cross-Ply Conical Shells

    Directory of Open Access Journals (Sweden)

    Sudip Dey

    2012-01-01

    Full Text Available Location of delamination is a triggering parameter for structural instability of laminated composites. In this paper, a finite element method is employed to determine the effects of location of delamination on free vibration characteristics of graphite-epoxy cross-ply composite pre-twisted shallow conical shells. The generalized dynamic equilibrium equation is derived from Lagrange's equation of motion neglecting Coriolis effect for moderate rotational speeds. The formulation is exercised by using an eight noded isoparametric plate bending element based on Mindlin's theory. Multi-point constraint algorithm is utilized to ensure the compatibility of deformation and equilibrium of resultant forces and moments at the delamination crack front. The standard eigen value problem is solved by applying the QR iteration algorithm. Finite element codes are developed to obtain the numerical results concerning the effects of location of delamination, twist angle and rotational speed on the natural frequencies of cross-ply composite shallow conical shells. The mode shapes are also depicted for a typical laminate configuration. Numerical results obtained from parametric studies of both symmetric and anti-symmetric cross-ply laminates are the first known non-dimensional natural frequencies for the type of analyses carried out here.

  6. Free vibration of symmetric angle ply truncated conical shells under different boundary conditions using spline method

    Energy Technology Data Exchange (ETDEWEB)

    Viswanathan, K. K.; Aziz, Z. A.; Javed, Saira; Yaacob, Y. [Universiti Teknologi Malaysia, Johor Bahru (Malaysia); Pullepu, Babuji [S R M University, Chennai (India)

    2015-05-15

    Free vibration of symmetric angle-ply laminated truncated conical shell is analyzed to determine the effects of frequency parameter and angular frequencies under different boundary condition, ply angles, different material properties and other parameters. The governing equations of motion for truncated conical shell are obtained in terms of displacement functions. The displacement functions are approximated by cubic and quintic splines resulting into a generalized eigenvalue problem. The parametric studies have been made and discussed.

  7. Free vibration of symmetric angle ply truncated conical shells under different boundary conditions using spline method

    International Nuclear Information System (INIS)

    Viswanathan, K. K.; Aziz, Z. A.; Javed, Saira; Yaacob, Y.; Pullepu, Babuji

    2015-01-01

    Free vibration of symmetric angle-ply laminated truncated conical shell is analyzed to determine the effects of frequency parameter and angular frequencies under different boundary condition, ply angles, different material properties and other parameters. The governing equations of motion for truncated conical shell are obtained in terms of displacement functions. The displacement functions are approximated by cubic and quintic splines resulting into a generalized eigenvalue problem. The parametric studies have been made and discussed.

  8. Three-dimensional free vibration of functionally graded truncated conical shells subjected to thermal environment

    Energy Technology Data Exchange (ETDEWEB)

    Malekzadeh, P., E-mail: p_malekz@yahoo.com [Department of Mechanical Engineering, Persian Gulf University, Bushehr 75168 (Iran, Islamic Republic of); Fiouz, A.R.; Sobhrouyan, M. [Department of Civil Engineering, Persian Gulf University, Bushehr 75168 (Iran, Islamic Republic of)

    2012-01-15

    A three-dimensional (3D) free vibration analysis of the functionally graded (FG) truncated conical shells subjected to thermal environment is presented. The material properties are assumed to be temperature-dependent and graded in the radius direction, which can vary according to a simple power law distribution. The initial thermal stresses are obtained accurately by solving the thermoelastic equilibrium equations and by considering the two-dimensional axisymmetric temperature distribution in the shell. The differential quadrature method (DQM) as an efficient and accurate numerical tool is adopted to solve the thermal and thermo-mechanical governing equations. For this purpose, a mapping technique is employed to transform the cross section of the shell into the computational domain of DQM. The convergence behavior of the method is numerically demonstrated and comparison studies with the available solutions in the literature are performed. The effects of temperature dependence of material properties, geometrical parameters, material graded index, thermal and mechanical boundary conditions on the frequency parameters of the FG truncated conical shells are carried out. - Highlights: Black-Right-Pointing-Pointer 3D free vibration analysis of the functionally graded truncated conical shells is presented. Black-Right-Pointing-Pointer Two-dimensional axisymmetric temperature distribution in the shell is assumed. Black-Right-Pointing-Pointer The material properties are assumed to be temperature-dependent. Black-Right-Pointing-Pointer Initial thermal stresses due to thermal environment are evaluated accurately and included. Black-Right-Pointing-Pointer Representing the effects of different parameters on the non-dimensional frequencies.

  9. The Expanding Bipolar Conic Shell of the Symbiotic Star AG Peg

    Science.gov (United States)

    Lee, Seong-Jae; Hyung, Siek

    2018-06-01

    Symbiotic stars are the most interesting since some systems are believed to host the most massive white dwarf, like SN Ia progenitors. Most recently, Lee and Hyung (2018, LH18) proposed a bipolar conic shell structure for the observed high expansion Hα and Hβ line profiles and other double peak lines observed in 1998 September (phase φ = 10.24): the physical conditions for the white dwarf luminosity and the ionized HII zone, responsible for double Gaussian optical lines including Balmer and Lyman line fluxes, were taken from the P-I model with gas density, nH = 109.85 cm-3 , while the column density for the scattering neutral zone was derived from the broader line components based on the result by Monte Carlo simulations. In this investigation, we examined whether the expanding shells of the bipolar conical geometry as proposed by LH18 would be able to form the other Hα and Hβ line profiles observed in other phases, φ = 11.56 and 11.98 (in 2001 August and 2002 August). We look into the kinematical property of the bipolar conic shell structure responsible for the HII and HI zones and then we discuss the secular variation of the broad line feature and the origin of the bipolar cone, i.e., part of a common envelope formed through the mass inflows from the giant star.

  10. Matrix analysis of the asymmetrical bending of conical shell-beams and their singular assemblies

    International Nuclear Information System (INIS)

    Kiedrzynski, A.; Coppens, L.

    1979-01-01

    As an alternative to refined finite element methodology a new method has been derived to investigate in much detail the linear static behaviour of singular assemblies of moderately thick conical shells of revolution submitted to non-axisymmetrical loads at their ends (an assembly of conical sections is said to be singular when the geometrical discontinuities are deformable, i.e. not stiffened by diaphragms). A detailed preliminary study has shown that the currently adopted simplifying assumptions in shell theories for moderate thickness lead to unconsistencies at any departure from axisymmetric loading. Therefore, FLUEGGE's general shell theory has been applied to a conical section, yielding a set of mixed first order differential equations in terms of displacements and conjuguated stress resultants well suited for a matrix formalism. The numerical integration is based on a fourth-order Runge-Kutta method and provides an 8 x 8 mixed matrix. This matrix contains complete information on the distribution of the displacements (exhibiting the warping and ovalization of the cross-section) and of the stress resultants along the meridian; also the stiffness coefficients proceed from it. (orig.)

  11. Parametric instability analysis of truncated conical shells using the Haar wavelet method

    Science.gov (United States)

    Dai, Qiyi; Cao, Qingjie

    2018-05-01

    In this paper, the Haar wavelet method is employed to analyze the parametric instability of truncated conical shells under static and time dependent periodic axial loads. The present work is based on the Love first-approximation theory for classical thin shells. The displacement field is expressed as the Haar wavelet series in the axial direction and trigonometric functions in the circumferential direction. Then the partial differential equations are reduced into a system of coupled Mathieu-type ordinary differential equations describing dynamic instability behavior of the shell. Using Bolotin's method, the first-order and second-order approximations of principal instability regions are determined. The correctness of present method is examined by comparing the results with those in the literature and very good agreement is observed. The difference between the first-order and second-order approximations of principal instability regions for tensile and compressive loads is also investigated. Finally, numerical results are presented to bring out the influences of various parameters like static load factors, boundary conditions and shell geometrical characteristics on the domains of parametric instability of conical shells.

  12. Calculation of plastic deformation of a conical shell with the transformation of inner surface into outer one

    Directory of Open Access Journals (Sweden)

    A. I. Uvarov

    2014-01-01

    Full Text Available An analytical model of plastic deformation of a conical shell with the transformation of internal surface into outer one was developed with a use of the kinematic method. The shell material was assumed to be perfectly plastic. The theory of thin shells and the kinematic theorem of limit equilibrium were utilized in this work. Both geometric and physical nonlinearities were taken into account. Dependences for calculating radius of curvature of the intensive deformation zones, value of chain ring deformation and values of the deforming force as a function of axial displacement were determined. Analysis showed the possibility of using a conical shell to absorb energy with high efficiency. Obtained results could be used for calculation and selection of optimal parameters of the energy-absorbing elements in shock absorbers.

  13. Combustion of peanut and tamarind shells in a conical fluidized-bed combustor: a comparative study.

    Science.gov (United States)

    Kuprianov, Vladimir I; Arromdee, Porametr

    2013-07-01

    Combustion of peanut and tamarind shells was studied in the conical fluidized-bed combustor using alumina sand as the bed material to prevent bed agglomeration. Morphological, thermogravimetric and kinetic characteristics were investigated to compare thermal and combustion reactivity between the biomass fuels. The thermogravimetric kinetics of the biomasses was fitted using the Coats-Redfern method. Experimental tests on the combustor were performed at 60 and 45 kg/h fuel feed rates, with excess air within 20-80%. Temperature and gas concentrations were measured along radial and axial directions in the reactor and at stack. The axial temperature and gas concentration profiles inside the combustor exhibited sensible effects of fuel properties and operating conditions on combustion and emission performance. High (≈ 99%) combustion efficiency and acceptable levels of CO, CxHy, and NO emissions are achievable when firing peanut shells at excess air of about 40%, whereas 60% is more preferable for burning tamarind shells. Copyright © 2013 Elsevier Ltd. All rights reserved.

  14. Non-linear general instability of ring-stiffened conical shells under external hydrostatic pressure

    International Nuclear Information System (INIS)

    Ross, C T F; Kubelt, C; McLaughlin, I; Etheridge, A; Turner, K; Paraskevaides, D; Little, A P F

    2011-01-01

    The paper presents the experimental results for 15 ring-stiffened circular steel conical shells, which failed by non-linear general instability. The results of these investigations were compared with various theoretical analyses, including an ANSYS eigen buckling analysis and another ANSYS analysis; which involved a step-by-step method until collapse; where both material and geometrical nonlinearity were considered. The investigation also involved an analysis using BS5500 (PD 5500), together with the method of Ross of the University of Portsmouth. The ANSYS eigen buckling analysis tended to overestimate the predicted buckling pressures; whereas the ANSYS nonlinear results compared favourably with the experimental results. The PD5500 analysis was very time consuming and tended to grossly underestimate the experimental buckling pressures and in some cases, overestimate them. In contrast to PD5500 and ANSYS, the design charts of Ross of the University of Portsmouth were the easiest of all these methods to use and generally only slightly underestimated the experimental collapse pressures. The ANSYS analyses gave some excellent graphical displays.

  15. Research on Free Vibration Frequency Characteristics of Rotating Functionally Graded Material Truncated Conical Shells with Eccentric Functionally Graded Material Stringer and Ring Stiffeners

    Directory of Open Access Journals (Sweden)

    Dao Van Dung

    Full Text Available Abstract In this research work, an exact analytical solution for frequency characteristics of the free vibration of rotating functionally graded material (FGM truncated conical shells reinforced by eccentric FGM stringers and rings has been investigated by the displacement function method. Material properties of shell and stiffeners are assumed to be graded in the thickness direction according to a simple power law distribution. The change of spacing between stringers is considered. Using the Donnell shell theory, Leckhnisky smeared stiffeners technique and taking into account the influences of centrifugal force and Coriolis acceleration the governing equations are derived. For stiffened FGM conical shells, it is difficult that free vibration equations are a couple set of three variable coefficient partial differential equations. By suitable transformations and applying Galerkin method, this difficulty is overcome in the paper. The sixth order polynomial equation for w is obtained and it is used to analyze the frequency characteristics of rotating ES-FGM conical shells. Effects of stiffener, geometrics parameters, cone angle, vibration modes and rotating speed on frequency characteristics of the shell forward and backward wave are discussed in detail. The present approach proves to be reliable and accurate by comparing with published results available in the literature.

  16. Design aids for stiffened composite shells with cutouts

    CERN Document Server

    Sahoo, Sarmila

    2017-01-01

    This book focuses on the free vibrations of graphite-epoxy laminated composite stiffened shells with cutout both in terms of the natural frequencies and mode shapes. The dynamic analysis of shell structures, which may have complex geometry and arbitrary loading and boundary conditions, is solved efficiently by the finite element method, even including cutouts in shells. The results may be readily used by practicing engineers dealing with stiffened composite shells with cutouts. Several shell forms viz. cylindrical shell, hypar shell, conoidal shell, spherical shell, saddle shell, hyperbolic paraboloidal shell and elliptic paraboloidal shell are considered in the book. The dynamic characteristics of stiffened composite shells with cutout are described in terms of the natural frequency and mode shapes. The size of the cutouts and their positions with respect to the shell centre are varied for different edge constraints of cross-ply and angle-ply laminated composite shells. The effects of these parametric variat...

  17. Conical light scattering in strontium barium niobate crystals related to an intrinsic composition inhomogeneity

    International Nuclear Information System (INIS)

    Bastwoeste, K; Sander, U; Imlau, M

    2007-01-01

    Conical light scattering is uncovered in poly- and mono-domain, nominally pure and Eu-doped strontium barium niobate (SBN) crystals over a wide temperature regime. The appearance of two scattering cones, a scattering line and a corona is observed and can be explained comprehensively within the Ewald sphere concept. Photorefraction, scattering from domain boundaries or from growth striations can be excluded from explaining the origin of the scattering. It is shown that the temperature-persistent scattering process is related to a growth-induced seeding rod, i.e. a composition inhomogeneity primarily localized at the centre of the SBN sample. The rod is directed parallel to the c axis and yields a refractive-index inhomogeneity with spatial frequencies on the micro-scale

  18. Core-shell particle composition by liquid phase infrared spectroscopy

    International Nuclear Information System (INIS)

    Ribeiro, Luiz F.B.; Machado, Ricardo A.F.; Goncalves, Odinei H.; Bona, Evandro

    2011-01-01

    Polymeric particles with core-shell morphology can offer advantages over conventional particles improving properties like mechanical and chemical resistance. However, particle composition must be known due to its influence on the final properties. In this work liquid phase infrared spectroscopy was used to determine the overall composition of core-shell particles composed by polystyrene (core) and poly(methyl methacrylate) (shell). Results were in agreement with those obtained with H 1 Nuclear Magnetic Resonance data (Goncalves et al, 2008). (author)

  19. Structural Acoustic Physics Based Modeling of Curved Composite Shells

    Science.gov (United States)

    2017-09-19

    NUWC-NPT Technical Report 12,236 19 September 2017 Structural Acoustic Physics -Based Modeling of Curved Composite Shells Rachel E. Hesse...SUBTITLE Structural Acoustic Physics -Based Modeling of Curved Composite Shells 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT...study was to use physics -based modeling (PBM) to investigate wave propagations through curved shells that are subjected to acoustic excitation. An

  20. Vibrations of composite circular shell structures due to transient loads

    International Nuclear Information System (INIS)

    Schrader, K.-H.; Krutzik, N.; Winkel, G.

    1975-01-01

    Referring to a container consisting of different shell structures - such as spherical, cylindrical and conical shells - the dynamic behavior of coupled spatial shell structures due to transient loads will be investigated. The spatial structure including the filling of water will be idealized as a three-dimensional model consisting of ring elements. The influence of the water filling on the vibrations will be considered by virtual masses added to the shell structures. In circular direction as well as in meridional direction a consistent mass model has been used. By variation of the virtual masses it will be clarified, how these additional masses influence the vibrational behavior of the composed system. Another aspect which will be investigated is the influence of different stiffnesses of substructures or parts of substructures on the natural frequencies, and on their affiliated eigensystems. Furthermore, the maximum and minimum stresses in the structures caused by transient loads acting on the inner surface of the shells will be explored. Here it seems to be possible to locate an area of maximum strain. Rotational loads as well as nonrotational loads will be considered

  1. A comparative study on free vibration analysis of delaminated torsion stiff and bending stiff composite shells

    International Nuclear Information System (INIS)

    Dey, Sudip; Karmakar, Amit

    2013-01-01

    This paper presents a finite element method to compare the effects of delamination on free vibration of graphite-epoxy bending stiff and torsion stiff composite pretwisted shallow conical shells. The generalized dynamic equilibrium equation is derived from Lagrange's equation of motion neglecting the Coriolis effect for moderate rotational speeds. An eight noded isoparametric plate bending element is employed incorporating rotary inertia and effects of transverse shear deformation based on Mindlin's theory. The multipoint constraint; algorithm is utilized to ensure the compatibility of deformation and equilibrium of resultant forces and moments at the delamination crack front. The standard eigen value problem is solved by applying the QR iteration algorithm. Mode shapes for typical configurations are also depicted. Numerical results obtained are the first known non-dimensional frequencies which could serve as reference solutions for the future investigators.

  2. Free vibration analysis of delaminated composite shells using different shell theories

    International Nuclear Information System (INIS)

    Nanda, Namita; Sahu, S.K.

    2012-01-01

    Free vibration response of laminated composite shells with delamination is presented using the finite element method based on first order shear deformation theory. The shell theory used is the extension of dynamic, shear deformable theory according to the Sanders' first approximation for doubly curved shells, which can be reduced to Love's and Donnell's theories by means of tracers. An eight-noded C 0 continuity, isoparametric quadrilateral element with five degrees of freedom per node is used in the formulation. For modeling the delamination, multipoint constraint algorithm is incorporated in the finite element code. The natural frequencies of the delaminated cylindrical (CYL), spherical (SPH) and hyperbolic paraboloid (HYP) shells are determined by using the above mentioned shell theories, namely Sanders', Love's, and Donnell's. The validity of the present approach is established by comparing the authors' results with those available in the literature. Additional studies on free vibration response of CYL, SPH and HYP shells are conducted to assess the effects of delamination size and number of layers considering all three shell theories. It is shown that shell theories according to Sanders and Love always predict practically identical frequencies. Donnell's theory gives reliable results only for shallow shells. Moreover, the natural frequency is found to be very sensitive to delamination size and number of layers in the shell.

  3. Optical Bistability in Graded Core-Shell Granular Composites

    International Nuclear Information System (INIS)

    Wu Ya-Min; Chen Guo-Qing; Xue Si-Zhong; Zhu Zhuo-Wei; Ma Chao-Qun

    2012-01-01

    The intrinsic optical bistability (OB) of graded core-shell granular composites is investigated. The coated particles are made of cores with gradient dielectric function in c (r) = A(r/a) k and nonlinear shells. In view of the exponential distribution of the core dielectric constant, the potential functions of each region are obtained by solving the Maxwell equations, and the mathematical expressions of electric field in the shells and cores are determined. Numerical study reveals that the optical bistable threshold and the threshold width of the composite medium are dependent on the shell thickness, core dielectric exponent, and power function coefficient. The optical bistable width increases with the decreasing shell thickness and the power exponent and with the increasing power function coefficient

  4. Modeling the carbon isotope composition of bivalve shells (Invited)

    Science.gov (United States)

    Romanek, C.

    2010-12-01

    The stable carbon isotope composition of bivalve shells is a valuable archive of paleobiological and paleoenvironmental information. Previous work has shown that the carbon isotope composition of the shell is related to the carbon isotope composition of dissolved inorganic carbon (DIC) in the ambient water in which a bivalve lives, as well as metabolic carbon derived from bivalve respiration. The contribution of metabolic carbon varies among organisms, but it is generally thought to be relatively low (e.g., 90%) in the shells from terrestrial organisms. Because metabolic carbon contains significantly more C-12 than DIC, negative excursions from the expected environmental (DIC) signal are interpreted to reflect an increased contribution of metabolic carbon in the shell. This observation contrasts sharply with modeled carbon isotope compositions for shell layers deposited from the inner extrapallial fluid (EPF). Previous studies have shown that growth lines within the inner shell layer of bivalves are produced during periods of anaerobiosis when acidic metabolic byproducts (e.g., succinic acid) are neutralized (or buffered) by shell dissolution. This requires the pH of EPF to decrease below ambient levels (~7.5) until a state of undersaturation is achieved that promotes shell dissolution. This condition may occur when aquatic bivalves are subjected to external stressors originating from ecological (predation) or environmental (exposure to atm; low dissolved oxygen; contaminant release) pressures; normal physiological processes will restore the pH of EPF when the pressure is removed. As a consequence of this process, a temporal window should also exist in EPF at relatively low pH where shell carbonate is deposited at a reduced saturation state and precipitation rate. For example, EPF chemistry should remain slightly supersaturated with respect to aragonite given a drop of one pH unit (6.5), but under closed conditions, equilibrium carbon isotope fractionation

  5. Structural experiments with ice (composite) shells

    NARCIS (Netherlands)

    Belis, J.; Martens, K.; Van Lancker, B.; Pronk, A.; Zingoni, Alphose

    2016-01-01

    ABSTRACT: Ice can be a very suitable building material for temporary structures in a freezing environment. When water, mixed with small fibre reinforcements, is sprayed onto an inflatable membrane structure in suitable cold outdoor conditions, a thin shell is formed which increases thickness layer

  6. Buckling Analysis of Grid-Stiffened Composite Shells

    NARCIS (Netherlands)

    Wang, D.; Abdalla, M.M.

    2014-01-01

    There is a renewed interest in grid-stiffened composite structures; they are not only competitive with conventional stiffened constructions and sandwich shells in terms of weight but also enjoy superior damage tolerance properties. In this paper, both global and local structural instabilities are

  7. Buckling Analysis of Grid-Stiffened Composite Shells

    OpenAIRE

    Wang, D.; Abdalla, M.M.

    2014-01-01

    There is a renewed interest in grid-stiffened composite structures; they are not only competitive with conventional stiffened constructions and sandwich shells in terms of weight but also enjoy superior damage tolerance properties. In this paper, both global and local structural instabilities are investigated for grid-stiffened composite panels using homogenization theory. Characteristic cell configurations with periodic boundary constraints are employed for orthogrid- and isogrid-stiffened s...

  8. Nonlinear Dynamic Buckling of Damaged Composite Cylindrical Shells

    Institute of Scientific and Technical Information of China (English)

    WANG Tian-lin; TANG Wen-yong; ZHANG Sheng-kun

    2007-01-01

    Based on the first order shear deformation theory(FSDT), the nonlinear dynamic equations involving transverse shear deformation and initial geometric imperfections were obtained by Hamilton's philosophy. Geometric deformation of the composite cylindrical shell was treated as the initial geometric imperfection in the dynamic equations, which were solved by the semi-analytical method in this paper. Stiffness reduction was employed for the damaged sub-layer, and the equivalent stiffness matrix was obtained for the delaminated area. By circumferential Fourier series expansions for shell displacements and loads and by using Galerkin technique, the nonlinear partial differential equations were transformed to ordinary differential equations which were finally solved by the finite difference method. The buckling was judged from shell responses by B-R criteria, and critical loads were then determined. The effect of the initial geometric deformation on the dynamic response and buckling of composite cylindrical shell was also discussed, as well as the effects of concomitant delamination and sub-layer matrix damages.

  9. Smart damping of laminated fuzzy fiber reinforced composite shells using 1–3 piezoelectric composites

    International Nuclear Information System (INIS)

    Kundalwal, S I; Suresh Kumar, R; Ray, M C

    2013-01-01

    This paper deals with the investigation of active constrained layer damping (ACLD) of smart laminated continuous fuzzy fiber reinforced composite (FFRC) shells. The distinct constructional feature of a novel FFRC is that the uniformly spaced short carbon nanotubes (CNTs) are radially grown on the circumferential surfaces of the continuous carbon fiber reinforcements. The constraining layer of the ACLD treatment is considered to be made of vertically/obliquely reinforced 1–3 piezoelectric composite materials. A finite element (FE) model is developed for the laminated FFRC shells integrated with the two patches of the ACLD treatment to investigate the damping characteristics of the laminated FFRC shells. The effect of variation of the orientation angle of the piezoelectric fibers on the damping characteristics of the laminated FFRC shells has been studied when the piezoelectric fibers are coplanar with either of the two mutually orthogonal vertical planes of the piezoelectric composite layer. It is revealed that radial growth of CNTs on the circumferential surfaces of the carbon fibers enhances the attenuation of the amplitude of vibrations and the natural frequencies of the laminated FFRC shells over those of laminated base composite shells without CNTs. (paper)

  10. Geometry of conics

    CERN Document Server

    Akopyan, A V

    2007-01-01

    The book is devoted to the properties of conics (plane curves of second degree) that can be formulated and proved using only elementary geometry. Starting with the well-known optical properties of conics, the authors move to less trivial results, both classical and contemporary. In particular, the chapter on projective properties of conics contains a detailed analysis of the polar correspondence, pencils of conics, and the Poncelet theorem. In the chapter on metric properties of conics the authors discuss, in particular, inscribed conics, normals to conics, and the Poncelet theorem for confoca

  11. Potential of using coconut shell particle fillers in eco-composite materials

    Energy Technology Data Exchange (ETDEWEB)

    Sarki, J., E-mail: sarksj@yahoo.com [Department of Fire and Safety, Kaduna International Airport, Kaduna-State (Nigeria); Department of Metallurgical and Materials Engineering, Ahmadu Bello University, Samaru, Zaria (Nigeria); Hassan, S.B., E-mail: hassbolaji@yahoo.com [Department of Fire and Safety, Kaduna International Airport, Kaduna-State (Nigeria); Department of Metallurgical and Materials Engineering, Ahmadu Bello University, Samaru, Zaria (Nigeria); Aigbodion, V.S., E-mail: aigbodionv@yahoo.com [Department of Fire and Safety, Kaduna International Airport, Kaduna-State (Nigeria); Department of Metallurgical and Materials Engineering, Ahmadu Bello University, Samaru, Zaria (Nigeria); Oghenevweta, J.E. [Department of Fire and Safety, Kaduna International Airport, Kaduna-State (Nigeria); Department of Metallurgical and Materials Engineering, Ahmadu Bello University, Samaru, Zaria (Nigeria)

    2011-02-03

    Research highlights: > The production and characterization of the composites has been done. - Abstract: Morphology and mechanical properties of coconut shell particles reinforced epoxy composites were evaluated to assess the possibility of using it as a new material in engineering applications. Coconut shell filled composites were prepared from epoxy polymer matrix containing up to 30 wt% coconut shell fillers. The effects of coconut shell particle content on the mechanical properties of the composites were investigated. Scanning electron microscopy (SEM) of the composite surfaces indicates that there are fairly good interfacial interaction between coconut shell particles and epoxy matrix. It was shown that the value of tensile modulus and tensile strength values increases with the increase of coconut shell particles content, while the impact strength slightly decreased, compared to pure epoxy resin. This work has shown that coconut shell particles can be used to improve properties of epoxy polymer composite to be used in eco-buildings.

  12. Potential of using coconut shell particle fillers in eco-composite materials

    International Nuclear Information System (INIS)

    Sarki, J.; Hassan, S.B.; Aigbodion, V.S.; Oghenevweta, J.E.

    2011-01-01

    Research highlights: → The production and characterization of the composites has been done. - Abstract: Morphology and mechanical properties of coconut shell particles reinforced epoxy composites were evaluated to assess the possibility of using it as a new material in engineering applications. Coconut shell filled composites were prepared from epoxy polymer matrix containing up to 30 wt% coconut shell fillers. The effects of coconut shell particle content on the mechanical properties of the composites were investigated. Scanning electron microscopy (SEM) of the composite surfaces indicates that there are fairly good interfacial interaction between coconut shell particles and epoxy matrix. It was shown that the value of tensile modulus and tensile strength values increases with the increase of coconut shell particles content, while the impact strength slightly decreased, compared to pure epoxy resin. This work has shown that coconut shell particles can be used to improve properties of epoxy polymer composite to be used in eco-buildings.

  13. Mechanical properties of epoxy/coconut shell filler particle composites

    International Nuclear Information System (INIS)

    Sapuan, S.M.; Harimi, M.; Maleque, M.A.

    2003-01-01

    This paper presents the tensile and flexural properties of composites made from coconut shell filler particles and epoxy resin. The tensile and flexural tests of composites based on coconut shell filler particles at three different filler contents viz., 5%, 0% and 15%were carried out using universal tensile testing machine according to ASTM D 3039/D M-95a and ASTM D790-90 tensile respectively and their results were presented. Experimental results showed that tensile and flexural properties of the composites increased with the increase of the filler particle content. The composite materials demonstrate somewhat linear behavior and sharp structure for tensile and slight nonlinear behavior and sharp fracture of flexural testing. The relation between stress and percentage of filler for tensile and flexural tests were found to b linear with correlation factors of 0.9929 and 0.9973 respectively. Concerning the relation between the modulus and percentage of filler for tensile and flexural tests, it was found to be a quadratic relation with the same correlation factor approximated to 1. The same behavior was observed for the strain versus percentage of filler tensile and flexural tests, with the same correlation factor. (author)

  14. First-Ply-Failure Performance of Composite Clamped Spherical Shells

    Science.gov (United States)

    Ghosh, A.; Chakravorty, D.

    2018-05-01

    The failure aspects of composites are available for plates, but studies of the literature on shells unveils that similar reports on them are very limited in number. The aim of this work was to investigate the first-ply-failure of industrially and aesthetically important spherical shells under uniform loadings. Apart from solving benchmark problems, numerical experiments were carried out with different variations of their parameters to obtain the first-ply-failure stresses by using the finite-element method. The load was increased in steps, and the lamina strains and stresses were put into well-established failure criteria to evaluate their first-ply-failure stress, the failed ply, the point of initiation of failure, and failure modes and tendencies. The results obtained are analyzed to extract the points of engineering significance.

  15. Material Distribution Optimization for the Shell Aircraft Composite Structure

    Science.gov (United States)

    Shevtsov, S.; Zhilyaev, I.; Oganesyan, P.; Axenov, V.

    2016-09-01

    One of the main goal in aircraft structures designing isweight decreasing and stiffness increasing. Composite structures recently became popular in aircraft because of their mechanical properties and wide range of optimization possibilities.Weight distribution and lay-up are keys to creating lightweight stiff strictures. In this paperwe discuss optimization of specific structure that undergoes the non-uniform air pressure at the different flight conditions and reduce a level of noise caused by the airflowinduced vibrations at the constrained weight of the part. Initial model was created with CAD tool Siemens NX, finite element analysis and post processing were performed with COMSOL Multiphysicsr and MATLABr. Numerical solutions of the Reynolds averaged Navier-Stokes (RANS) equations supplemented by k-w turbulence model provide the spatial distributions of air pressure applied to the shell surface. At the formulation of optimization problem the global strain energy calculated within the optimized shell was assumed as the objective. Wall thickness has been changed using parametric approach by an initiation of auxiliary sphere with varied radius and coordinates of the center, which were the design variables. To avoid a local stress concentration, wall thickness increment was defined as smooth function on the shell surface dependent of auxiliary sphere position and size. Our study consists of multiple steps: CAD/CAE transformation of the model, determining wind pressure for different flow angles, optimizing wall thickness distribution for specific flow angles, designing a lay-up for optimal material distribution. The studied structure was improved in terms of maximum and average strain energy at the constrained expense ofweight growth. Developed methods and tools can be applied to wide range of shell-like structures made of multilayered quasi-isotropic laminates.

  16. Filling a Conical Cavity

    Science.gov (United States)

    Nye, Kyle; Eslam-Panah, Azar

    2016-11-01

    Root canal treatment involves the removal of infected tissue inside the tooth's canal system and filling the space with a dense sealing agent to prevent further infection. A good root canal treatment happens when the canals are filled homogeneously and tightly down to the root apex. Such a tooth is able to provide valuable service for an entire lifetime. However, there are some examples of poorly performed root canals where the anterior and posterior routes are not filled completely. Small packets of air can be trapped in narrow access cavities when restoring with resin composites. Such teeth can cause trouble even after many years and lead the conditions like acute bone infection or abscesses. In this study, the filling of dead-end conical cavities with various liquids is reported. The first case studies included conical cavity models with different angles and lengths to visualize the filling process. In this investigation, the rate and completeness at which a variety of liquids fill the cavity were observed to find ideal conditions for the process. Then, a 3D printed model of the scaled representation of a molar with prepared post spaces was used to simulate the root canal treatment. The results of this study can be used to gain a better understanding of the restoration for endodontically treated teeth.

  17. Preparation and characterization of antibacterial Au/C core-shell composite

    Energy Technology Data Exchange (ETDEWEB)

    Gao Yanhong [Department of Chemistry and Institute of Nanochemistry, Jinan University, 601 Huangpudadaoxi Road, Guangzhou 510632, Guangdong (China); Centers for Disease Control and Prevention of Guangdong Province, Guangzhou 510300, Guangdong (China); Zhang Nianchun [Department of Chemistry and Institute of Nanochemistry, Jinan University, 601 Huangpudadaoxi Road, Guangzhou 510632, Guangdong (China); Zhong Yuwen [Centers for Disease Control and Prevention of Guangdong Province, Guangzhou 510300, Guangdong (China); Cai Huaihong [Department of Chemistry and Institute of Nanochemistry, Jinan University, 601 Huangpudadaoxi Road, Guangzhou 510632, Guangdong (China); Liu Yingliang, E-mail: tliuyl@jnu.edu.cn [Department of Chemistry and Institute of Nanochemistry, Jinan University, 601 Huangpudadaoxi Road, Guangzhou 510632, Guangdong (China)

    2010-09-01

    An environment-friendly oxidation-reduction method was used to prepare Au/C core-shell composite using carbon as core and gold as shell. The chemical structures and morphologies of Au/C core-shell composite and carbon sphere were characterized by X-ray diffraction, transmission electron microscope, energy dispersion X-ray spectrometry (EDS) and X-ray photoelectron spectroscopy (XPS). The antibacterial properties of the Au/C core-shell composite against Escherichia coli (E. coli), Staphylococcus aureus (S. aureus) and Candida albicans (C. albicans) were examined by the disk diffusion assay and minimal inhibition concentration (MIC) methods. In addition, antibacterial ability of Au/C core-shell composite was observed by atomic force microscope. Results demonstrated that gold homogeneously supported on the surface of carbon spheres without aggregation and showed efficient antibacterial abilities.

  18. Free vibration of laminated composite stiffened hyperbolic paraboloid shell panel with cutout

    Science.gov (United States)

    Sahoo, Sarmila

    2016-08-01

    Composite shell structures are extensively used in aerospace, civil, marine and other engineering applications. In practical civil engineering applications, the necessity of covering large column free open areas is often an issue and hyperbolic paraboloid shells are used as roofing units. Quite often, to save weight and also to provide a facility for inspection, cutouts are provided in shell panels. The paper considers free vibration characteristics of stiffened composite hyperbolic paraboloid shell panel with cutout in terms of natural frequency and mode shapes. A finite element code is developed for the purpose by combining an eight noded curved shell element with a three noded curved beam element. The size of the cutouts and their positions with respect to the shell centre are varied for different edge conditions to arrive at a set of inferences of practical engineering significances.

  19. Free vibration of laminated composite stiffened hyperbolic paraboloid shell panel with cutout

    International Nuclear Information System (INIS)

    Sahoo, Sarmila

    2016-01-01

    Composite shell structures are extensively used in aerospace, civil, marine and other engineering applications. In practical civil engineering applications, the necessity of covering large column free open areas is often an issue and hyperbolic paraboloid shells are used as roofing units. Quite often, to save weight and also to provide a facility for inspection, cutouts are provided in shell panels. The paper considers free vibration characteristics of stiffened composite hyperbolic paraboloid shell panel with cutout in terms of natural frequency and mode shapes. A finite element code is developed for the purpose by combining an eight noded curved shell element with a three noded curved beam element. The size of the cutouts and their positions with respect to the shell centre are varied for different edge conditions to arrive at a set of inferences of practical engineering significances. (paper)

  20. Design and Analysis of Tow-Steered Composite Shells Using Fiber Placement

    Science.gov (United States)

    Wu, K. Chauncey

    2008-01-01

    In this study, a sub-scale advanced composite shell design is evaluated to determine its potential for use on a future aircraft fuselage. Two composite shells with the same nominal 8-ply [+/-45/+/-Theta](sub s) layup are evaluated, where Theta indicates a tow-steered ply. To build this shell, a fiber placement machine would be used to steer unidirectional prepreg tows as they are placed around the circumference of a 17-inch diameter right circular cylinder. The fiber orientation angle varies continuously from 10 degrees (with respect to the shell axis of revolution) at the crown, to 45 degrees on the side, and back to 10 degrees on the keel. All 24 tows are placed at each point on every fiber path in one structure designated as the shell with overlaps. The resulting pattern of tow overlaps causes the laminate thickness to vary between 8 and 16 plies. The second shell without tow overlaps uses the capability of the fiber placement machine to cut and add tows at any point along the fiber paths to fabricate a shell with a nearly uniform 8-ply laminate thickness. Issues encountered during the design and analysis of these shells are presented and discussed. Static stiffness and buckling loads of shells with tow-steered layups are compared with the performance of a baseline quasi-isotropic shell using both finite element analyses and classical strength of materials theory.

  1. A novel Rapid Additive Manufacturing concept for architectural composite shell construction inspired by the shell formation in land snails.

    Science.gov (United States)

    Felbrich, Benjamin; Wulle, Frederik; Allgaier, Christoph; Menges, Achim; Verl, Alexander; Wurst, Karl-Heinz; Nebelsick, James

    2018-01-04

    State of the art rapid additive manufacturing (RAM), specifically Fused Filament Fabrication (FFF) has gained popularity among architects, engineers and designers for quick prototyping of technical devices, rapid production of small series and even construction scale fabrication of architectural elements. The spectrum of producible shapes and the resolution of detail, however, are determined and constrained by the layer-based nature of the fabrication process. These aspects significantly limit FFF-based approaches for the prefabrication and in-situ fabrication of freeform shells at the architectural scale. Snails exhibit a shell building process that suggests ways to overcome these limits. They produce a soft, pliable proteinaceous film - the periostracum - which later hardens and serves, among other functions, as a form-giving surface for an inner calcium carbonate layer. Snail shell formation behavior is interpreted from a technical point of view to extract potentially useful aspects for a biomimetic transfer. A RAM concept for continuous extrusion of thin free form composite shells inspired by the snail shell formation is presented. © 2018 IOP Publishing Ltd.

  2. The influence of stiffeners on axial crushing of glass-fabric-reinforced epoxy composite shells

    Directory of Open Access Journals (Sweden)

    A. Vasanthanathan

    2017-01-01

    Full Text Available A generic static and impact experimental procedure has been developed in this work aimed at improving the stability of glass fabric reinforced epoxy shell structures by bonding with axial stiffeners. Crashworthy structures fabricated from composite laminate with stiffeners would offer energy absorption superior to metallic structures under compressive loading situations. An experimental material characterisation of the glass fabric reinforced epoxy composite under uni-axial tension has been carried out in this study. This work provides a numerical simulation procedure to describe the static and dynamic response of unstiffened glass fabric reinforced epoxy composite shell (without stiffeners and stiffened glass fabric reinforced epoxy composite shell (with axial stiffeners under static and impact loading using the Finite Element Method. The finite element calculation for the present study was made with ANSYS®-LS-DYNA® software. Based upon the experimental and numerical investigations, it has been asserted that glass fabric reinforced epoxy shells stiffened with GFRP stiffeners are better than unstiffened glass fabric reinforced epoxy shell and glass fabric reinforced epoxy shell stiffened with aluminium stiffeners. The failure surfaces of the glass fabric reinforced epoxy composite shell structures tested under impact were examined by SEM.

  3. Analysis of thin composite structures using an efficient hex-shell finite element

    Energy Technology Data Exchange (ETDEWEB)

    Shiri, Seddik [Universite Bordeaux, Pessac (France); Naceur, Hakim [Universite de valenciennes, Valenciennes (France)

    2013-12-15

    In this paper a general methodology for the modeling of material composite multilayered shell structures is proposed using a Hex-shell finite element modeling. The first part of the paper is devoted to the general FE formulation of the present composite 8-node Hex-shell element called SCH8, based only on displacement degrees of freedom. A particular attention is given to alleviate shear, trapezoidal and thickness locking, without resorting to the classical plane-stress assumption. The anisotropic material behavior of layered shells is modeled using a fully three dimensional elastic orthotropic material law in each layer, including the thickness stress component. Applications to laminate thick shell structures are studied to validate the methodology, and good results have been obtained in comparison with ABAQUS commercial code.

  4. Core-Shell Composite Fibers for High-Performance Flexible Supercapacitor Electrodes.

    Science.gov (United States)

    Lu, Xiaoyan; Shen, Chen; Zhang, Zeyang; Barrios, Elizabeth; Zhai, Lei

    2018-01-31

    Core-shell nanofibers containing poly(acrylic acid) (PAA) and manganese oxide nanoparticles as the core and polypyrrole (PPy) as the shell were fabricated through electrospinning the solution of PAA and manganese ions (PAA/Mn 2+ ). The obtained nanofibers were stabilized by Fe 3+ through the interaction between Fe 3+ ions and carboxylate groups. Subsequent oxidation of Mn 2+ by KMnO 4 produced uniform manganese dioxide (MnO 2 ) nanoparticles in the fibers. A PPy shell was created on the fibers by immersing the fibers in a pyrrole solution where the Fe 3+ ions in the fiber polymerized the pyrrole on the fiber surfaces. In the MnO 2 @PAA/PPy core-shell composite fibers, MnO 2 nanoparticles function as high-capacity materials, while the PPy shell prevents the loss of MnO 2 during the charge/discharge process. Such a unique structure makes the composite fibers efficient electrode materials for supercapacitors. The gravimetric specific capacity of the MnO 2 @PAA/PPy core-shell composite fibers was 564 F/g based on cyclic voltammetry curves at 10 mV/s and 580 F/g based on galvanostatic charge/discharge studies at 5 A/g. The MnO 2 @PAA/PPy core-shell composite fibers also present stable cycling performance with 100% capacitance retention after 5000 cycles.

  5. Conical pitch angle distributions of very-low energy ion fluxes observed by ISEE 1

    International Nuclear Information System (INIS)

    Horowitz, J.L.; Baugher, C.R.; Chappell, C.R.; Shelley, E.G.; Young, D.T.

    1982-01-01

    Observations of low-energy ionospheric ions by the plasma composition experiment abroad ISEE 1 often show conical pitch angle distributions, that is, peak fluxes between 0 0 and 90 0 to the directions parallel or antiparallel to the magnetic field. Frequently, all three primary ionospheric ion species (H + , He + , and O + ) simultaneously exhibit conical distributions with peak fluxes at essentially the same pitch angle. A distinction is made here between unidirectional, or streaming, distributions, in which ions are traveling essentially from only one hemisphere, and symmetrical distributions, in which significant fluxes are observed traveling from both hemispheres. The orbital coverage for this survey was largely restricted to the night sector, approximately 2100--0600 LT, and moderate geomagnetic latitudes of 20 0 --40 0 . Also, lack of complete pitch angle coverage at all times may have reduced detection for conics with small cone angles. However, we may conclude that the unidirectional conical distributions observed in the northern hemisphere are always observed to be traveling from the northern hemisphere and that they exhibit the following characteristics relative to the symmetric distributions, in that they (1) are typically observed on higher L shells (that is, higher geomagnetic latitudes or larger geocentric distances or both), (2) tend to have significantly larger cone angles, and (3), are associated with higher magnetic activity levels

  6. Synthesis of hydrophobic zeolite X-SiO{sub 2} core-shell composites

    Energy Technology Data Exchange (ETDEWEB)

    Liu Liying [School of Material and Metallurgy, Northeastern University, Shenyang, Liaoning 110004 (China); Cooperative Research Centre for Greenhouse Gas Technologies (CO-2CRC) (Australia); Singh, Ranjeet; Li Gang; Xiao Gongkui [Cooperative Research Centre for Greenhouse Gas Technologies (CO-2CRC) (Australia); Department of Chemical Engineering, Monash University, Clayton, Victoria 3800 (Australia); Webley, Paul A., E-mail: paul.webley@eng.monash.edu.au [Cooperative Research Centre for Greenhouse Gas Technologies (CO-2CRC) (Australia); Department of Chemical and Biomolecular Engineering, University of Melbourne, Victoria 3010 (Australia); Zhai Yuchun [School of Material and Metallurgy, Northeastern University, Shenyang, Liaoning 110004 (China)

    2012-04-16

    Highlights: Black-Right-Pointing-Pointer Hydrophobic 13X zeolite composites with silicalite and mesoporous silica shells are designed. Black-Right-Pointing-Pointer These core-shell composites are silynated and their hydrophobicity is tested. Black-Right-Pointing-Pointer Addition of silica layer increases the density of surface hydroxyl groups which makes the improvement of the hydrophobicity possible by further silynation. - Abstract: Core-shell structures of zeolite X coated with silicalite as well as mesoporous (MCM-41) have been synthesized. Furthermore, the surfaces of the silicalite and mesoporous silica shells were silylated using organosilanes. The materials were characterized by X-ray diffraction, nitrogen adsorption/desorption, scanning and transmission electron microscopy. The results show that the properties of zeolite 13X-silicalite and zeolite 13X-mesoporous silica core-shells composite structures are well maintained even after the modification. As expected, the shell thickness increased with increase in synthesis time, however, the micropore volume decreased. Silylation with smaller organosilanes (trimethyl chlorosilane) resulted in decrease in surface area as they diffused through the pores; however, bulkier silane reacted with surface hydroxyl groups and maintained the pore structure. Contact angle measurements revealed that hydrophobicity of zeolite 13X was enhanced by the microporous and mesoporous shell coating and was further improved by silylation.

  7. Mechanical and thermal properties of polypropylene (PP) composites filled with modified shell waste

    Energy Technology Data Exchange (ETDEWEB)

    Yao, Z.T., E-mail: sxyzt@126.com [College of Materials Science and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018 (China); Chen, T. [Department of Ocean Science and Engineering, Zhejiang University, Hangzhou 310058 (China); Li, H.Y. [Zhoushan Ocean Research Institute, Zhejiang University, Zhoushan 316021 (China); Xia, M.S., E-mail: msxia@zju.edu.cn [Department of Ocean Science and Engineering, Zhejiang University, Hangzhou 310058 (China); Ye, Y.; Zheng, H. [Department of Ocean Science and Engineering, Zhejiang University, Hangzhou 310058 (China)

    2013-11-15

    Highlights: • Adding modified shell powder could significantly increase the properties of PP. • The modified shell powder could act as a nucleating agent in PP matrix. • The modified shell powder has a potential to be used as a bio-filler. -- Abstract: Shell waste, with its high content of calcium carbonate (CaCO{sub 3}) plus organic matrix, has a potential to be used as a bio-filler. In this work, shell waste was modified by furfural and then incorporated to reinforce polypropylene (PP). The shell waste and modified powder were characterized by means of X-ray diffraction (XRD), scanning electron microscopy equipped with an energy dispersive spectrometer (SEM-EDS), X-ray photoelectronic spectroscopy (XPS), and Fourier transformed infrared spectroscopy (FTIR). The mechanical and thermal properties of neat PP and PP composites were investigated as well. Thermal gravimetric (TG) analyses confirmed the reinforcing role of modified powder in PP composites. The mechanical properties studied showed that adding modified powder could significantly increase the impact strength, elongation at break point and flexural modulus of composites. The maximum incorporation content could reach 15 wt.% with a good balance between toughness and stiffness of PP composites. Differential scanning calorimetry (DSC) results showed that the modified powder could act as a nucleating agent and thus increase the crystallization temperature of PP. Polarized optical microscopy (POM) observation also indicated that the introduction of modified powder could promote the heterogeneous nucleation of PP matrix.

  8. Low-energy impact of adaptive cylindrical piezoelectric-composite shells

    Energy Technology Data Exchange (ETDEWEB)

    Saravanos, D.A. [University of Patras (United Kingdom). Dept. of Mechanical Engineering and Aeronautics; Christoforou, A.P. [Kuwait Univ. (Kuwait). Dept. of Mechanical Engineering

    2002-04-01

    A theoretical framework for analyzing low-energy impacts of laminated shells with active and sensory piezoelectric layers is presented, including impactor dynamics and contact law. The formulation encompasses a coupled piezoelectric shell theory mixing first order shear displacement assumptions and layerwise variation of electric potential. An exact in-plane Ritz solution for the impact of open cylindrical piezoelectric-composite shells is developed and solved numerically using an explicit time integration scheme. The active impact control problem of adaptive cylindrical shells with distributed curved piezoelectric actuators is addressed. The cases of optimized state feedback controllers and output feedback controllers using piezoelectric sensors are analyzed. Numerical results quantify the impact response of cylindrical shells of various curvatures including the signal of curved piezoelectric sensors. Additional numerical studies quantify the impact response of adaptive cylindrical panels and investigate the feasibility of actively reducing the impact force. (author)

  9. Stability analysis of whirling composite shells partially filled with two liquid phases

    Energy Technology Data Exchange (ETDEWEB)

    Sahebnasagh, Mohammad [Department of Mechanical Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Nikkhah-Bahrami, Mansour; Firouz-Abadi, Roohollah [Department of Aerospace Engineering, Sharif University, Tehran (Iran, Islamic Republic of)

    2017-05-15

    In this paper, the stability of whirling composite cylindrical shells partially filled with two liquid phases is studied. Using the first-order shear shell theory, the structural dynamics of the shell is modeled and based on the Navier-Stokes equations for ideal liquid, a 2D model is developed for liquid motion at each section of the cylinder. In steady state condition, liquids are supposed to locate according to mass density. In this study, the thick shells are investigated. Using boundary conditions between liquids, the model of coupled fluid-structure system is obtained. This coupled fluid-structure model is employed to determine the critical speed of the system. The effects of the main variables on the stability of the shell are studied and the results are investigated.

  10. Reduced Magnetism in Core–Shell Magnetite@MOF Composites

    Energy Technology Data Exchange (ETDEWEB)

    Elsaidi, Sameh K.; Sinnwell, Michael A.; Banerjee, Debasis; Devaraj, Arun; Kukkadapu, Ravi K.; Droubay, Timothy C.; Nie, Zimin; Kovarik, Libor; Murugesan, Vijayakumar; Manandhar, Sandeep; Nandasiri, Manjula I.; McGrail, Bernard P.; Thallapally, Praveen K.

    2017-10-17

    Rare-earth elements (REEs) have significant commercial and military uses.1-3 However, REE extraction through conventional mining processes is expensive and feasible at only a few locations worldwide. Alternative methods are needed to produce REEs from more geographically disperse resources and in a cost effective, environmental friendly manner.4,5 Among various sources, geothermal brine, used for generating geothermal energy can possess attractive concentrations (ppb to ppm level) of REEs along with other dissolved metal ions.6 A system that can selectively trap the REEs using an existing geothermal power plant infrastructure would be an attractive additional revenue stream for the plant operator that could accelerate the development and deployment of geothermal plants in the United States and rest of the world.7,8 Here, we demonstrate a magnetic core-shell approach that can effectively extract REEs in their ionic form from aqueous solution with up to 99.99% removal efficiency. The shell, composed of thermally and chemically stable functionalized metal-organic framework (MOF), is grown over a synthesized Fe3O4 magnetic core. Magnetic susceptibility of the particles was found to decline significantly after in situ growth of a MOF shell, which resulted from oxidation of Fe2+ species of the magnetite (Fe3O4) to Fe3+ species (maghemite). The core-shell particles can be completely removed from the mixture under an applied magnetic field, offering a practical, economic, and efficient REE-removal process.

  11. ECO-TECHNIQUE OF SEWER RENOVATION USING COMPOSITE SHELLS: STRUCTURAL ANALYSIS

    Directory of Open Access Journals (Sweden)

    B. Attaf

    2015-07-01

    Full Text Available An eco-technical renovation of the sewage system is developed in this paper; this technique involves incorporating into the existing sewer a series of jointed prefabricated sandwich or composite shells. The purpose of his study is to determine the structural shell deflection, the high displacement areas and to validate the non-failure criterion for each ply constituting the inner and outer laminate facings. The numerical results were obtained at low cost by using the finite element method. Studies have focused on structural analysis of a typical shell unit with an ovoid form (egg-shaped section when it is subjected, during annular space filling operation, to pressure forces generated by wet concrete. To ensure the safety of the composite shell structure, Tsai-Hill criterion function is applied and results are presented for the most stressed plies

  12. Parameterized Finite Element Modeling and Buckling Analysis of Six Typical Composite Grid Cylindrical Shells

    Science.gov (United States)

    Lai, Changliang; Wang, Junbiao; Liu, Chuang

    2014-10-01

    Six typical composite grid cylindrical shells are constructed by superimposing three basic types of ribs. Then buckling behavior and structural efficiency of these shells are analyzed under axial compression, pure bending, torsion and transverse bending by finite element (FE) models. The FE models are created by a parametrical FE modeling approach that defines FE models with original natural twisted geometry and orients cross-sections of beam elements exactly. And the approach is parameterized and coded by Patran Command Language (PCL). The demonstrations of FE modeling indicate the program enables efficient generation of FE models and facilitates parametric studies and design of grid shells. Using the program, the effects of helical angles on the buckling behavior of six typical grid cylindrical shells are determined. The results of these studies indicate that the triangle grid and rotated triangle grid cylindrical shell are more efficient than others under axial compression and pure bending, whereas under torsion and transverse bending, the hexagon grid cylindrical shell is most efficient. Additionally, buckling mode shapes are compared and provide an understanding of composite grid cylindrical shells that is useful in preliminary design of such structures.

  13. Minimum Compliance Topology Optimization of Shell-Infill Composites for Additive Manufacturing

    DEFF Research Database (Denmark)

    Wu, Jun; Clausen, Anders; Sigmund, Ole

    2017-01-01

    Additively manufactured parts are often composed of two sub-structures, a solid shell forming their exterior and a porous infill occupying the interior. To account for this feature this paper presents a novel method for generating simultaneously optimized shell and infill in the context of minimum...... interpolation model into a physical density field, upon which the compliance is minimized. Enhanced by an adapted robust formulation for controlling the minimum length scale of the base, our method generates optimized shell-infill composites suitable for additive manufacturing. We demonstrate the effectiveness...

  14. Synthesis and characterization of ZnO/TiO 2 composite core/shell ...

    Indian Academy of Sciences (India)

    Organic solar cells; ZnO/TiO2 core/shell; nanorod arrays; sol–gel. ... on indium tin oxide (ITO) substrate via a facile sol–gel dip-coating process. Effects of solution pH for ZnO, annealing temperature, growth time and temperature on the ... The optical and electrical properties of the bare TiO2 thin film and core/shell composite ...

  15. The Potential of Coconut Shell Powder (CSP) and Coconut Shell Activated Carbon (CSAC) Composites as Electromagnetic Interference (EMI) Absorbing Material

    International Nuclear Information System (INIS)

    Siti Nurbazilah Abdul Jabal; Seok, Y.B.; Hoon, W.F.

    2016-01-01

    Agriculture waste is potentially useful as an alternative material to absorb and attenuate electromagnetic interference (EMI). This research highlights the use of coconut shell powder (CSP) and coconut shell activated carbon (CSAC) as raw materials with epoxy resin and amine hardener composite to absorb microwave signals over frequency of 1 - 8 GHz. In order to investigate the suitability of these raw materials as EMI absorbing material, carbon composition of the raw materials is determined through CHNS Elemental Analysis. The surface morphology of the raw materials in term of porosity is investigated by using TM3000 Scanning Electron Microscope (SEM). The complex permittivity of the composites is determined by using high temperature dielectric probe in conjunction with Network Analyzer. From the result, the Carbon% of CSP and CSAC is 46.70 % and 84.28 % respectively. In term of surface morphology, the surface porosity of CSP and CSAC is in the range of 2 μm and 1 μm respectively. For the dielectric properties, the dielectric constant and the dielectric loss factor for CSP and CSAC is 4.5767 and 64.8307 and 1.2144 and 13.8296 respectively. The materials more potentially useful as substitute materials for electromagnetic interference (EMI) absorbing are discussed. (author)

  16. Polydopamine and MnO2 core-shell composites for high-performance supercapacitors

    Science.gov (United States)

    Hou, Ding; Tao, Haisheng; Zhu, Xuezhen; Li, Maoguo

    2017-10-01

    Polydopamine and MnO2 core-shell composites (PDA@MnO2) for high-performance supercapacitors had been successfully synthesized by a facile and fast method. The morphology, crystalline phase and chemical composition of PDA@MnO2 composites are characterized using SEM, TEM, XRD, EDS and XPS. The performance of PDA@MnO2 composites are further investigated by cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy in 1 M Na2SO4 electrolyte. The PDA@MnO2 core-shell nanostructure composites exhibit a high capacitance of 193 F g-1 at the current density of 1A g-1 and retained over 81.2% of its initial capacitance after 2500 cycles of charge-discharge at 2 A g-1. The results manifest that the PDA@MnO2 composites can be potentially applied in supercapacitors.

  17. Incorporation of coconut shell based nanoparticles in kenaf/coconut fibres reinforced vinyl ester composites

    Science.gov (United States)

    S, Abdul Khalil H. P.; Masri, M.; Saurabh, Chaturbhuj K.; Fazita, M. R. N.; Azniwati, A. A.; Sri Aprilia, N. A.; Rosamah, E.; Dungani, Rudi

    2017-03-01

    In the present study, a successful attempt has been made on enhancing the properties of hybrid kenaf/coconut fibers reinforced vinyl ester composites by incorporating nanofillers obtained from coconut shell. Coconut shells were grinded followed by 30 h of high energy ball milling for the production of nanoparticles. Particle size analyzer demonstrated that the size of 90% of obtained nanoparticles ranged between 15-140 nm. Furthermore, it was observed that the incorporation of coconut shell nanofillers into hybrid composite increased water absorption capacity. Moreover, tensile, flexural, and impact strength increased with the filler loading up to 3 wt.% and thereafter decrease was observed at higher filler concentration. However, elongation at break decreased and thermal stability increased in nanoparticles concentration dependent manner. Morphological analysis of composite with 3% of filler loading showed minimum voids and fiber pull outs and this indicated that the stress was successfully absorbed by the fiber.

  18. Harnessing the bistable composite shells to design a tunable phononic band gap structure

    Science.gov (United States)

    Li, Yi; Xu, Yanlong

    2018-02-01

    By proposing a system composed of an array of bistable composite shells immersed in air, we develop a new class of periodic structure to control the propagation of sound. Through numerical investigation, we find that the acoustic band gap of this system can be switched on and off by triggering the snap through deformation of the bistable composite shells. The shape of cross section and filling fraction of unit cell can be altered by different number of bistable composite shells, and they have strong impact on the position and width of the band gap. The proposed concept paves the way of using the bistable structures to design a new class of metamaterials that can be enable to manipulate sound.

  19. Design and analysis of reactor containment of steel-concrete composite laminated shell

    International Nuclear Information System (INIS)

    Ichikawa, K.; Isobata, O.; Kawamata, S.

    1977-01-01

    A new scheme of containment consisting of steel-concrete laminated shell is being developed. In the main part of a cylindrical vessel, the shell consists of two layers of thin steel plates located at the inner and outer surfaces, and a layer of concrete core into which both the steel plates are anchored. Because of the compressive and shearing resistance of the concrete core, the layers behave as a composite solid shell. Membrane forces are shared by steel plates and partly by concrete core. Bending moment is effectively resisted by the section with extreme layers of steel. Therefore, both surfaces can be designed as extremely thin plates: the inner plate, which is a load carrying members as well as a liner, can be welded without the laborious process of stress-relieving, and various jointing methods can be applied to the outer plate which is free from the need for leak tightness. The capability of the composite layers of behaving as a unified solid shell section depends largely on the shearing rigidity of the concrete core. However, as its resisting capacity to transverse shearing force is comparatively low, a device for reducing the shearing stress at the junction to the base mat is needed. In the new scheme, this part of the cylindrical shell is divided into multiple layers of the same kind of composite shell. This device makes the stiffness of the bottom of the cylindrical shell to lateral movement minimum while maintaining the proper resistance to membrane forces. The analysis shows that the transverse shearing stress can be reduced to less than 1√n of the ordinary case by dividing the thickness of the shell into n layers which are able to slip against each other at the contact surface. In order to validate the feasibility and safety of this new design, the results of analysis on the basis of up-to-date design loads are presented

  20. Supercooling suppression of microencapsulated phase change materials by optimizing shell composition and structure

    International Nuclear Information System (INIS)

    Cao, Fangyu; Yang, Bao

    2014-01-01

    Highlights: • A new method for supercooling suppression of microPCMs by optimizing the structure of the microcapsule shell. • Large effective latent heat (up to 213 J/g) of the microPCMs, much higher than those using additive as nucleating agents. • Change of shell composition and structure significantly affects the phase transition processes of the encapsulated PCMs. • The latent heat of the shell-induced phase transition is maximized, reaching 83.7% of the latent heat of bulk octadecane. • Hollow spheres with porous rather than solid resin shell are also formed when the SDS concentration is very high. - Abstract: A new method for supercooling suppression of microencapsulated phase change materials (PCMs) has been developed by optimizing the composition and structure of the microcapsule resin shell. The microcapsules comprising paraffin octadecane encapsulated in melamine–formaldehyde resin shell were synthesized with the use the oil-in-water emulsion technique. These PCM microcapsules are 5–15 μm in diameter. The supercooling of these octadecane microcapsules can be as large as 13.6 °C, when the homogeneous nucleation is dominant during the melt crystallization into the thermodynamically stable triclinic phase. It is discovered that the homogeneous nucleation can be mediated by shell-induced nucleation of the triclinic phase and the metastable rotator phase when the shell composition and structure are optimized, without need of any nucleating additives. The effects of synthesis parameters, such as ratio of melamine to formaldehyde, pH of pre-polymer, and pH of emulsion, on the phase transition properties of the octadecane microcapsules have been investigated systemically. The optimum synthesis conditions have been identified in terms of minimizing the supercooling while maintaining heat capacity. Potential applications of this type of phase changeable microcapsules include high heat capacity thermal fluids, thermal management in smart buildings

  1. Microstructural and thermal study of Al-Si-Mg/melon shell ash particulate composite

    Directory of Open Access Journals (Sweden)

    M. Abdulwahab

    Full Text Available The microstructural study via scanning electron microscope (SEM and thermal study via differential scanning calorimetric (DSC study of Al-7%Si-0.3Mg/melon shell ash particulate composite has been carried out. The melon shell ash was used in the production of MMC ranging from 5% to 20% at interval of 5% addition using stir casting method. The melon shell ash was characterized using X-ray fluorescent (XRF that reveal the presence of CaO, SiO2, Al2O3, MgO, and TiO2 as major compounds. The composite was machined and subjected to heat treatment. Microstructural analyses of the composite produced were done using scanning electron microscope (SEM. The microstructure obtained reveals a dark ceramic (reinforcer and white metallic phase. Equally, the 5 wt% DSC result gives better thermal conductivity than other proportions (10 wt%, 15 wt%, and 20 wt%. These results showed that an improved property of Al-Si-Mg alloy was achieved using melon shell ash particles as reinforcement up to a maximum of 20 wt% for microstructural and 5% wt DSC respectively. Keywords: Microstructural analysis, Melon shell ash, Stir casting, X-ray fluorescent, Reinforcement, Composite

  2. Bandgap Engineering of InP QDs Through Shell Thickness and Composition

    Energy Technology Data Exchange (ETDEWEB)

    Dennis, Allison M. [Los Alamos National Laboratory; Mangum, Benjamin D. [Los Alamos National Laboratory; Piryatinski, Andrei [Los Alamos National Laboratory; Park, Young-Shin [Los Alamos National Laboratory; Htoon, Han [Los Alamos National Laboratory; Hollingsworth, Jennifer A. [Los Alamos National Laboratory

    2012-06-21

    Fields as diverse as biological imaging and telecommunications utilize the unique photophysical and electronic properties of nanocrystal quantum dots (NQDs). The development of new NQD compositions promises material properties optimized for specific applications, while addressing material toxicity. Indium phosphide (InP) offers a 'green' alternative to the traditional cadmium-based NQDs, but suffers from extreme susceptibility to oxidation. Coating InP cores with more stable shell materials significantly improves nanocrystal resistance to oxidation and photostability. We have investigated several new InP-based core-shell compositions, correlating our results with theoretical predictions of their optical and electronic properties. Specifically, we can tailor the InP core-shell QDs to a type-I, quasi-type-II, or type-II bandgap structure with emission wavelengths ranging from 500-1300 nm depending on the shell material used (ZnS, ZnSe, CdS, or CdSe) and the thickness of the shell. Single molecule microscopy assessments of photobleaching and blinking are used to correlate NQD properties with shell thickness.

  3. INFLUENCE OF COCONUT SHELL ADDITION ON PHYSICO-MECHANICAL PROPERTIES OF WOOD PLASTIC COMPOSITES1

    Directory of Open Access Journals (Sweden)

    Éverton Hillig

    2018-04-01

    Full Text Available ABSTRACT In this study, composites with three types of thermoplastic matrix and cellulosic material in a proportion of 40% were produced. The three thermoplastic matrices were high density polyethylene (HDPE, polypropylene (PP and low density polyethylene (LDPE, and the cellulosic materials were pure wood flour (Pinus taeda L or a mixture of wood flour and coconut shell flour (Cocus nucifera L in equal ratios. The objective was to evaluate the influence of addition of coconut shell on the physico-mechanical properties (density, strength and rigidity and the distribution of the cellulosic material in the thermoplastic matrix of the manufactured composites. It was found that the composites had a satisfactory distribution of wood flour in thermoplastic matrices, but the addition of coconut shell promoted bubble formation in the resulting pieces and, thus, interfered with the material properties. The use of a coupling agent promoted interfacial adhesion (cellulose - thermoplastic matrix, which was better in high density polyethylene composites, followed by polypropylene and low density polyethylene. In general, the coconut shell addition caused a decrease of all properties compared to composites made with Loblolly Pine. In addition, the interactions between thermoplastic type and cellulosic matrix type have been statistically confirmed, which caused variations in the studied properties

  4. TiN/VN composites with core/shell structure for supercapacitors

    Energy Technology Data Exchange (ETDEWEB)

    Dong, Shanmu; Chen, Xiao [Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, No. 189 Songling Road, Qingdao 266101 (China); Gu, Lin [WPI Advanced Institute for Materials Research, Tohoku University, Sendai 9808577 (Japan); Zhou, Xinhong [Qingdao University of Science and Technology, Qingdao 266101 (China); Wang, Haibo; Liu, Zhihong; Han, Pengxian; Yao, Jianhua; Wang, Li [Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, No. 189 Songling Road, Qingdao 266101 (China); Cui, Guanglei, E-mail: cuigl@qibebt.ac.cn [Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, No. 189 Songling Road, Qingdao 266101 (China); Chen, Liquan [Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, No. 189 Songling Road, Qingdao 266101 (China); Institute of Physics, Chinese Academy of Sciences, Beijing 100080 (China)

    2011-06-15

    Research highlights: {yields} Vanadium and titanium nitride nanocomposite with core-shell structure was prepared. {yields} TiN/VN composites with different V:Ti molar ratios were obtained. {yields} TiN/VN composites can provide promising electronic conductivity and favorable capacity storage. -- Abstract: TiN/VN core-shell composites are prepared by a two-step strategy involving coating of commercial TiN nanoparticles with V{sub 2}O{sub 5}.nH{sub 2}O sols followed by ammonia reduction. The highest specific capacitance of 170 F g{sup -1} is obtained when scanned at 2 mV s{sup -1} and a promising rate capacity performance is maintained at higher voltage sweep rates. These results indicate that these composites with good electronic conductivity can deliver a favorable capacity performance.

  5. Wear behavior of Al-7%Si-0.3%Mg/melon shell ash particulate composites.

    Science.gov (United States)

    Abdulwahab, M; Dodo, R M; Suleiman, I Y; Gebi, A I; Umar, I

    2017-08-01

    The present study examined wear characteristics of A356/melon shell ash particulate composites. Dry-sliding the stainless steel ball against specimen disc revealed the abrasive wear behavior of the composites under loads of 2 and 5N. The composite showed lower wear rate of 2.182 × 10 -4 mm 3 /Nm at 20 wt% reinforced material under load of 5N. Results showed that wear rate decreased significantly with increasing weight percentage of melon shell ash particles. Microstructural analyses of worn surfaces of the composites reveal evidence of plastic deformation of matrix phase. The wear resistance of A356 increased considerably with percentage reinforcement. In other words, the abrasive mass loss decreased with increasing percentage of reinforcement addition at the both applied loads. The control sample suffered a highest mass loss at 5 N applied load.

  6. Bio-composites based on polypropylene reinforced with Almond Shells particles: Mechanical and thermal properties

    International Nuclear Information System (INIS)

    Essabir, H.; Nekhlaoui, S.; Malha, M.; Bensalah, M.O.; Arrakhiz, F.Z.; Qaiss, A.; Bouhfid, R.

    2013-01-01

    Highlights: • Almond Shells (ASs) particles have been used as reinforcement in polypropylene matrix. • The SEBS-g-MA has been used to improve the adhesion between matrix and particles. • The mechanical and thermal properties of the composite have been improved by the AS. - Abstract: In this work, Almond Shells (ASs) particles are used as reinforcement in a thermoplastic matrix as polypropylene (PP). Composites containing Almond Shells (ASs) particles with and without compatibilizer (maleic anhydride grafted polypropylene; SEBS-g-MA) for various particle content (5, 10, 15, 20, 25, 30 wt.%) was investigated by means of studying their mechanical, thermal and rheological properties. The composites were prepared in a twin-screw extruder and assessed by means of X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), tensile testing and Dynamic Mechanical Analysis (DMA). Results show a clear improvement in mechanical and rheological properties from the use of Almond Shells particles in the matrix without and with maleic anhydride compatibilizer, corresponding to a gain in Young’s modulus of 56.2% and 35% respectively, at 30 wt.% particle loading. Thermal analysis revealed that incorporation of particle in the composites resulted in increase in the initial thermal decomposition temperatures

  7. Two-way actuation behavior of shape memory polymer/elastomer core/shell composites

    International Nuclear Information System (INIS)

    Kang, Tae-Hyung; Lee, Jeong-Min; Yu, Woong-Ryeol; Youk, Ji Ho; Ryu, Hee Wook

    2012-01-01

    Semi-crystalline shape memory polymers (SMPs) show net two-way shape memory (2W-SM) behavior under constant stresses by the recoverable creep strain upon heating and stress-induced crystallization under the application of creep stress upon cooling. The applied constant stress is the key factor in this 2W-SM behavior. A core/shell structure is manufactured for the purpose of imparting a constant stress upon SMPs. An SMP in film or fiber form is dipped into a solution of an elastomer, photoinitiator, and curing agent and then dried out. After this dip coating process is repeatedly carried out, the SMP/elastomer core/shell composite is deformed into a temporary shape after being heated up above the transition temperature of the SMP. Under constant strain conditions, the composite is cooled down, after which the shell elastomer is cured using ultraviolet light. Then, the SMP/elastomer core/shell composite extends and contracts upon cooling and heating, respectively, without any external load. This cyclic deformation behavior is characterized, demonstrating that the current method offers a simple macroscopic processing technique to manufacture 2W-SM polymer composites. (paper)

  8. Origin and diversity of testate amoebae shell composition: Example of Bullinularia indica living in Sphagnum capillifolium.

    Science.gov (United States)

    Delaine, Maxence; Bernard, Nadine; Gilbert, Daniel; Recourt, Philippe; Armynot du Châtelet, Eric

    2017-06-01

    Testate amoebae are free-living shelled protists that build a wide range of shells with various sizes, shapes, and compositions. Recent studies showed that xenosomic testate amoebae shells could be indicators of atmospheric particulate matter (PM) deposition. However, no study has yet been conducted to assess the intra-specific mineral, organic, and biologic grain diversity of a single xenosomic species in a natural undisturbed environment. This study aims at providing new information about grain selection to develop the potential use of xenosomic testate amoebae shells as bioindicators of the multiple-origin mineral/organic diversity of their proximal environment. To fulfil these objectives, we analysed the shell content of 38 Bullinularia indica individuals, a single xenosomic testate amoeba species living in Sphagnum capillifolium, by scanning electron microscope (SEM) coupled with X-ray spectroscopy. The shells exhibited high diversities of mineral, organic, and biomineral grains, which confirms their capability to recycle xenosomes. Mineral grain diversity and size of B. indica matched those of the atmospheric natural mineral PM deposited in the peatbog. Calculation of grain size sorting revealed a discrete selection of grains agglutinated by B. indica. These results are a first step towards understanding the mechanisms of particle selection by xenosomic testate amoebae in natural conditions. Copyright © 2017 Elsevier GmbH. All rights reserved.

  9. A filament wound carbon-carbon composite for impact shell application

    International Nuclear Information System (INIS)

    Zee, Ralph; Romanoski, Glenn

    2000-01-01

    The performance and safety of the radioisotope power source depend in part on the thermal and impact properties of the materials used in the general purpose heat source (GPHS) through the use of an impact shell, thermal insulation and an aeroshell. Within the aeroshell are two graphite impact shells, made of fine-weave pierced-fabric (FWPF) that encapsulate four iridium alloy clad isotopic fuel pellets and provides impact protection for the clad. Impact studies conducted at Los Alamos National Laboratory showed that impact shells typically fractured parallel to their longitudinal axis. The objective of this effort is to develop new impact shell concepts with improved performance. An effort to develop alternative carbon-carbon composites for the graphite impact shell was conducted. Eight braided architectures were examined in this study. The effects of the number of graphitization cycles on both the density and circumferential strength of these braided structures were determined. Results show that a filament wound carbon-carbon composite possesses the desired density and circumferential strength important to GPHS

  10. Study on the Ingredient Proportions and After-Treatment of Laser Sintering Walnut Shell Composites

    Directory of Open Access Journals (Sweden)

    Yueqiang Yu

    2017-12-01

    Full Text Available To alleviate resource shortage, reduce the cost of materials consumption and the pollution of agricultural and forestry waste, walnut shell composites (WSPC consisting of walnut shell as additive and copolyester hot melt adhesive (Co-PES as binder was developed as the feedstock of selective laser sintering (SLS. WSPC parts with different ingredient proportions were fabricated by SLS and processed through after-treatment technology. The density, mechanical properties and surface quality of WSPC parts before and after post processing were analyzed via formula method, mechanical test and scanning electron microscopy (SEM, respectively. Results show that, when the volume fraction of the walnut shell powder in the WSPC reaches the maximum (40%, sintered WSPC parts have the smallest warping deformation and the highest dimension precision, although the surface quality, density, and mechanical properties are low. However, performing permeating resin as the after-treatment technology could considerably increase the tensile, bending and impact strength by 496%, 464%, and 516%, respectively.

  11. Vibrations of laminated composite thick shells of revolution having meridionally varying curvature

    International Nuclear Information System (INIS)

    Suzuki, Katsuyoshi; Shikanai, Genji; Baba, Iwato

    1998-01-01

    An exact solution is presented for solving free vibrations of laminated composite thick shells of revolution having meridionally varying curvature. Based on the thick lamination theory considering the shear deformation and rotary inertia, equations of motion and boundary conditions are obtained from the stationary conditions of the Lagrangian. The equations of motion are solved exactly by using a power series expansion for symmetrically laminated cross-ply shells. Frequencies and mode shapes of shells of revolution having elliptical and parabolical meridians are presented for both ends clamped, and the effects of shear deformation and rotary inertia are discussed by comparing the results from the present theory with those from the thin lamination theory. (author)

  12. Controllable dielectric and electrical performance of polymer composites with novel core/shell-structured conductive particles through biomimetic method

    International Nuclear Information System (INIS)

    Yang, Dan; Tian, Ming; Wang, Wencai; Li, Dongdong; Li, Runyuan; Liu, Haoliang; Zhang, Liqun

    2013-01-01

    Highlights: ► Conductive core/shell-structured particles were synthesized by biomimetic method. ► These particles with silica/poly(dopamine)/silver core and poly(dopamine) shell. ► Dielectric composites were prepared with resulted particles and silicone elastomer. ► The dielectric properties of the composites can be controlled by shell thickness. ► This biomimetic method is simple, nontoxic, efficient and easy to control. - Abstract: Novel silica/poly(dopamine)/silver (from inner to outer) (denoted as SiO 2 /PDA/Ag) conductive micro-particles were first synthesized by biomimetic poly(dopamine) coating. These micro-particles were then coated with a poly(dopamine) layer to form core/shell-structured particles, with silica/poly(dopamine)/silver core and poly(dopamine) shell (denoted as SiO 2 /PDA/Ag/PDA). This multilayer core/shell micro-particles were confirmed by scanning electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, and transmission electron microscope. Polymer composites were then prepared by mechanical blending of poly(dimethyl siloxane) and the core/shell-structured particles. It was found that the silver layer and the poly(dopamine) shell had good adhesion with substrate and they kept intact even under violent shearing stress during mechanical mixing. The effect of the thickness of outermost poly(dopamine) shell as well as the loading amount of this filler on the dielectric and electrical properties of the composites was further studied. The results showed that the dielectric constant, dielectric loss, and conductivity of the composites decreased with increasing shell thickness (10–53 nm) at the same loading level. And the maximal dielectric constant of composites was achieved in the composites filled with SiO 2 /PDA/Ag/PDA (with 10–15 nm PDA shell) particles, which was much larger than that of the composite filled with SiO 2 /PDA/Ag particles without insulative PDA shell. At the same time, the composites can change

  13. Synthesis of fly ash based core-shell composites for use as functional pigment in paints

    Science.gov (United States)

    Sharma, Richa; Tiwari, Sangeeta

    2016-04-01

    Fly ash is a combustion residue, mainly composed of silica, alumina and iron oxides. It is produced by the power industries in very large amounts and usually disposed in landfills, which have represented an environmental problem in recent years1. The need to generate a market for fly ash consumption is the main reason why alternative applications have been studied. It has been applied as an additive in construction materials like cement and pavements2. The present work describes the synthesis of Flyash-Titania core-shell particles by precipitation technique using Titanium tetra isopropoxide (TTIP) which can be used for variety of applications such as NIR reflecting materials for cool coatings, Photocatalysis etc. In this work, Fly ash is used in core and Nano -TiO2 is coated as shell on it. Surfactants are used to improve the adhesion of Nano Titania shell on fly ash core. Effect on adhesion of TiO2 on Fly ash is studied by using different types of surfactant. The preparation of core shells was carried out in absence of surfactant as well as using anionic and non-ionic surfactants. The percentage of surfactant was varied to study the effect of amount of surfactant on the uniformity and size of particles in the shell using Kubelka-Munk transformed reflectance spectra. The morphology of core shell structures was studied using SEM technique. Use of anionic surfactant results in more uniform coating with reduced particle size of the shell material. The composite particles prepared by using anionic surfactant are having good pigment properties and also shows good reflectance in Near Infrared region and hence can be used as a pigment in cool coatings.

  14. Strength Calculation of Locally Loaded Orthotropic Shells

    Directory of Open Access Journals (Sweden)

    Yu. I. Vinogradov

    2015-01-01

    Full Text Available The article studies laminated orthotropic cylindrical, conic, spherical, and toroidal shells, which are often locally loaded in the aircraft designs over small areas of their surfaces.The aim of this work is to determine stress concentration in shells versus structure of orthotropic composite material, shell form and parameters, forms of loading areas, which borders do not coincide with lines of main curvatures of shells. For this purpose, an analytical computing algorithm to estimate strength of shells in terms of stress is developed. It enables us to have solution results of the boundary value problem with a controlled error. To solve differential equations an analytical method is used. An algorithm of the boundary value problem solution is multiplicative.The main results of researches are graphs of stress concentration in the orthotropic shells versus their parameters and areas of loading lineated by circles and ellipses.Among the other works aimed at determination of stress concentration in shells, the place of this one is defined by the analytical solution of applied problems for strength estimation in terms of shell stresses of classical forms.The developed effective analytical algorithm to solve the boundary value problem and received results are useful in research and development.

  15. Effects of electron-beam irradiation on HDPE/Brazil nut shell fiber composite

    International Nuclear Information System (INIS)

    Ferreira, Maiara S.; Sartori, Mariana N.; Oliveira, Rene R.; Moura, Esperidiana A.B.

    2013-01-01

    In recent years, research on the replacement of synthetic fibers by natural fibers as reinforcement in thermoplastic composites has increased dramatically due to the advantages of natural fibers, such as low density, low cost, environmental appeal and recyclability. In the present work, the influence of electron-beam irradiation on mechanical properties of HDPE and HDPE/Brazil Nut Shell (Bertholletia excelsa) fiber compositive was investigated. The HDPE composite reinforced with 5% or 10%, by weight of Brazil nut shell fiber powder with particle sizes equal or smaller than 250 μm were obtained by extrusion, using a twin screw extruder. The materials were irradiated at 200 kGy using a 1.5 MeV electron beam accelerator, at room temperature in presence of air. The irradiated and non-irradiated specimens tests samples were submitted to mechanical and thermo-mechanical tests, scanning electron microscopy (SEM), X-Ray diffraction (XRD) and sol-gel analysis and the correlation between their properties was discussed. The results showed significant changes in HDPE mechanical and thermo-mechanical properties due to Brazil nut shell fibers addition and electron-beam irradiation. The surface of the cryo fractured composite samples irradiated showed important visual changes which suggest a better fiber-matrix interfacial adhesion, due to irradiation treatment. These results showed that it is possible to get interesting property gains by using waste from renewable sources instead of the traditional ones and electron-beam radiation treatment. (author)

  16. Effects of electron-beam irradiation on HDPE/Brazil nut shell fiber composite

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Maiara S.; Sartori, Mariana N.; Oliveira, Rene R.; Moura, Esperidiana A.B., E-mail: maiara.sferreira@gmail.com [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2013-07-01

    In recent years, research on the replacement of synthetic fibers by natural fibers as reinforcement in thermoplastic composites has increased dramatically due to the advantages of natural fibers, such as low density, low cost, environmental appeal and recyclability. In the present work, the influence of electron-beam irradiation on mechanical properties of HDPE and HDPE/Brazil Nut Shell (Bertholletia excelsa) fiber compositive was investigated. The HDPE composite reinforced with 5% or 10%, by weight of Brazil nut shell fiber powder with particle sizes equal or smaller than 250 μm were obtained by extrusion, using a twin screw extruder. The materials were irradiated at 200 kGy using a 1.5 MeV electron beam accelerator, at room temperature in presence of air. The irradiated and non-irradiated specimens tests samples were submitted to mechanical and thermo-mechanical tests, scanning electron microscopy (SEM), X-Ray diffraction (XRD) and sol-gel analysis and the correlation between their properties was discussed. The results showed significant changes in HDPE mechanical and thermo-mechanical properties due to Brazil nut shell fibers addition and electron-beam irradiation. The surface of the cryo fractured composite samples irradiated showed important visual changes which suggest a better fiber-matrix interfacial adhesion, due to irradiation treatment. These results showed that it is possible to get interesting property gains by using waste from renewable sources instead of the traditional ones and electron-beam radiation treatment. (author)

  17. Suitability of Recycled Polyethylene/Palm Kernel Shell-Iron Filings Composite for Automobile Application

    Directory of Open Access Journals (Sweden)

    I.A. Samotu

    2015-06-01

    Full Text Available A recycling aimed research was carried out to produce a new composite material and proffer suggestion for the possible use of the newly developed composite material. The empty water sachet (commonly called pure water nylon in Nigeria, was used as a matrix, which was reinforced by carbonized palm kernel shell (CPKS particulate and iron fillings. The percentage composition of iron fillings was maintained at 5 wt%, while that of palm kernel shell ash was varied from 5 wt% - 20 wt% at an interval of 5 %. The composites were compounded and compressively moulded. Physical and mechanical properties of the composites were tested for alongside three conventional car bumper samples, and the results obtained shows that the composite material could be used to produce a car bumper among other parts of automobile like dashboard due to their impact strength and low density. Impact strength - density ratio for the materials gave prime information on the possible application of the developed material. Scanning Electron Microscope (SEM was used to examine the distribution of the reinforcement within the matrix. After results analysis, materials with 5 wt% of CPKS and that with 10 wt% of CPKS were recommended for the car bumper production following their high impact strength - density ratio of 0.26 and 0.19 respectively, which are higher as compared to that of a conventional bumper material measured alongside the composite materials.

  18. Thresholds of motion of shell debris under unidirectional flow: influence of faunal composition

    Science.gov (United States)

    Rieux, A.; Weill, P.; Mouazé, D.; Poirier, C.; Tessier, B.

    2017-12-01

    Quantifying bottom sediment erodibility is necessary to refine understanding of coastal processes and fossil records. Coastal sediments are partly composed of biogenic particles, which shape and density differ from rounded quartz grain and vary between species. Numerous studies have investigated the hydrodynamic behaviour of bioclastic sediments derived from reef-dwelling organisms, but research focusing on "cool-water carbonate" bioclastic particles (i.e. mollusc shell debris, calcareous algae, …) are rare. The present study aims in characterizing the influence of faunal composition on the entrainment threshold of mollusc shell debris from temperate regions. Shells have been sampled on shelly ridges in the southern coast of the Mont-Saint-Michel bay (NW France), before being ground and separated into individual sieve fractions. Eight species, representative of the local faunal composition, have been studied: four wild (cockle, furrow shell, saddle oyster, flat oyster), three reared (japanese oyster, mussel, manila clam) and one introduced (slipper limpet) species. Experiments for defining the threshold of motion of all samples were conducted in a small recirculating flume, under unidirectional current, and using an Acoustic Doppler Velocimeter Profiler. Critical bed shear stress values (τcr) were derived from velocity profiles in the boundary layer, by a logarithmic regression of the "law of the wall". Depending on the species, the evolution of τcr with increasing grain diameters follows either an asymptotic or a more linear trend. Differences between species can be discerned: saddle oyster, japanese oyster and flat oyster show the smallest τcr, slipper limpet, furrow shell and mussel have an intermediate τcr and cockle and manila clam the highest τcr. For the 2-3.15 mm fraction, τcr ranges from 0.38 N.m-2 (saddle oyster) to 2.13 N.m-2 (cockle). Oyster shells (japanese and flat oysters) are composed of foliated sheets of calcite, interbedded with soft

  19. Composite adhesive bonds reinforced with microparticle filler based on egg shell waste

    Science.gov (United States)

    Müller, Miroslav; Valášek, Petr

    2018-05-01

    A research on composite adhesive bonds reinforced with waste from hen eggs processing, i.e. egg shell waste (ESW) is based on an assumption of the utilization of agricultural/food production waste. The aim of the research is to gain new pieces of knowledge about the material utilization of ESW, i.e. to evaluate possibilities of the use of various concentrations of ESW microparticles smaller than 100 µm based on hen egg shells as the filler in a structural resin used for a creation of adhesive bonds from bearing metal elements. An adhesive bond strength, an elongation at break and a fracture surface were evaluated within the research on adhesive bonds. The experiment results proved the efficiency of ESW filler in the area of composite adhesive bonds. The adhesive bond strength was increased up of more than 17 % by adding 40 wt.% of ESW microparticles.

  20. Elemental compositions of crab and snail shells from the Kueishantao hydrothermal field in the southwestern Okinawa Trough

    Science.gov (United States)

    Zeng, Zhigang; Ma, Yao; Wang, Xiaoyuan; Chen, Chen-Tung Arthur; Yin, Xuebo; Zhang, Suping; Zhang, Junlong; Jiang, Wei

    2018-04-01

    To reveal differences in the behavior of benthic vent animals, and the sources and sinks of biogeochemical and fluid circulations, it is necessary to constrain the chemical characteristics of benthic animals from seafloor hydrothermal fields. We measured the abundances of 27 elements in shells of the crab Xenograpsus testudinatus and the snail Anachis sp., collected from the Kueishantao hydrothermal field (KHF) in the southwestern Okinawa Trough, with the aim of improving our understanding of the compositional variations between individual vent organisms, and the sources of the rare earth elements (REEs) in their shells. The Mn, Hg, and K concentrations in the male X. testudinatus shells are found to be higher than those in female crab shells, whereas the reverse is true for the accumulation of B, implying that the accumulation of K, Mn, Hg, and B in the crab shells is influenced by sex. This is inferred to be a result of the asynchronous molting of the male and female crab shells. Snail shells are found to have higher Ca, Al, Fe, Ni, and Co concentrations than crab shells. This may be attributed to different metal accumulation times. The majority of the light rare earth element (LREE) distribution patterns in the crab and snail shells are similar to those of Kueishantao vent fluids, with the crab and snail shells also exhibiting LREE enrichment, implying that the LREEs contained in crab and snail shells in the KHF are derived from vent fluids.

  1. Ni@Ru and NiCo@Ru Core-Shell Hexagonal Nanosandwiches with a Compositionally Tunable Core and a Regioselectively Grown Shell.

    Science.gov (United States)

    Hwang, Hyeyoun; Kwon, Taehyun; Kim, Ho Young; Park, Jongsik; Oh, Aram; Kim, Byeongyoon; Baik, Hionsuck; Joo, Sang Hoon; Lee, Kwangyeol

    2018-01-01

    The development of highly active electrocatalysts is crucial for the advancement of renewable energy conversion devices. The design of core-shell nanoparticle catalysts represents a promising approach to boost catalytic activity as well as save the use of expensive precious metals. Here, a simple, one-step synthetic route is reported to prepare hexagonal nanosandwich-shaped Ni@Ru core-shell nanoparticles (Ni@Ru HNS), in which Ru shell layers are overgrown in a regioselective manner on the top and bottom, and around the center section of a hexagonal Ni nanoplate core. Notably, the synthesis can be extended to NiCo@Ru core-shell nanoparticles with tunable core compositions (Ni 3 Co x @Ru HNS). Core-shell HNS structures show superior electrocatalytic activity for the oxygen evolution reaction (OER) to a commercial RuO 2 black catalyst, with their OER activity being dependent on their core compositions. The observed trend in OER activity is correlated to the population of Ru oxide (Ru 4+ ) species, which can be modulated by the core compositions. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Use of Almond Shells and Rice Husk as Fillers of Poly(Methyl Methacrylate) (PMMA) Composites.

    Science.gov (United States)

    Sabbatini, Alessandra; Lanari, Silvia; Santulli, Carlo; Pettinari, Claudio

    2017-07-28

    In recent years, wood fibres have often been applied as the reinforcement of thermoplastic materials, such as polypropylene, whereas their use in combination with thermosetting resin has been less widespread. This study concerns the production of PMMA-based composites by partly replacing alumina trihydrate (ATH) with wood waste fillers, namely rice husks and almond shells, which would otherwise be disposed by incineration. The amount of filler introduced was limited to 10% as regards rice husks and 10 or 15% almond shells, since indications provided by reactivity tests and viscosity measurements did not suggest the feasibility of total replacement of ATH. As a matter of fact, the introduction of these contents of wood waste filler in PMMA-based composite did not result in any significant deterioration of its mechanical properties (Charpy impact, Rockwell M hardness and flexural performance). Some reduction of these properties was only observed in the case of introduction of 15% almond shells. A further issue concerned the yellowing of the organic filler under exposure to UV light. On the other hand, a very limited amount of water was absorbed, never exceeding values around 0.6%, despite the significant porosity revealed by the filler's microscopic evaluation. These results are particularly interesting in view of the application envisaged for these composites, i.e., wood replacement boards.

  3. Traditional utilization and biochemical composition of six mollusc shells in Nigeria

    Directory of Open Access Journals (Sweden)

    Ademolu Kehinde O.

    2015-06-01

    Full Text Available The shells of molluscs protect them from physical damage, predators and dehydration. We studied various local uses of shells and their biochemical properties in Abeokuta, Nigeria. A standard structured questionnaire about use was applied to 100 snail and herb sellers and shells from 120 adult individuals of Archachatina marginata, Achatina achatina, Achatina fulica, Littorina littorea, Meretrix lusoria and Merceneria mercenaria were evaluated for their mineral components (Ca2+, Fe2+, Mg2+, Na+, Zn+, P+, K+ and proximate composition (crude protein, ash, fibre, crude fat and carbohydrate using standard methods. Properties against fungi and bacteria isolates were also tested. These shells are used for bleaching, brushing, abrasion and others. The weight of the shells varied from 0.5g (L. littorea to 25.00g (A. marginata and thickness from 0.46mm in M .lusoria to 5.35mm in M. mercenaria. We found no inhibitory effect against fungi and bacterial isolates. The molluscs are high in carbohydrates (83.54-92.76g/100g and low in protein (0.16-0.38g/100g. The fat content ranged between 0.42g/100g and 0.82g/100g, and ash between 2.14g/100g and 9.45g/100g. Ca2+ was the most abundant (10.25-96.35mg/g while K+ was the least abundant (0.3-0.7mg/g (p<0.05. Active ingredients of these shells can be used in the feed and construction industries.

  4. Evaluating the bio-energy potential of groundnut shell and sugarcane bagasse waste composite

    Directory of Open Access Journals (Sweden)

    Olatunde Ajani Oyelaran

    2015-12-01

    Full Text Available An assessment has been carried out on bio-coal briquettes from coal with sugarcane bagasse and coal with groundnut shell. Proximate analyses and elemental compositions of the coal and biomasses were determined. Different samples of briquettes were produced by blending varying composition of the coal with the biomasses in the ratio of 100:0; 90:10, 80:20, 70:30, 60:40, 50:50, 40:60 and 0: 100, using calcium carbonate as a desulfurizing agent and cassava starch as a binder. A manual hydraulically operated briquetting machine was used with the pressure kept at 5MPa. The results of the properties evaluated shows that biomass increases the burning efficiency of briquettes with increase in the biomass material, increasing combustion rate, faster ignition, producing lesser ash and fewer pollutants. Results obtained shows that the calorific value of briquettes produced from coal-groundnut shells and coal-sugarcane bagasse ranges from 16.94 - 20.81 and 17.31 – 21.03 MJ/kg respectively. The ignition time ranges from 6.9 – 12.5 minutes for coal-groundnut shells briquettes while that of coal-sugarcane bagasse ranges from 6.5 – 11.1 minutes. The bio-coal blends with sugarcane bagasse were better than that of groundnut shells. However, both sugarcane bagasse and groundnut shells produce bio-coal briquettes that are very efficient, providing sufficient heat as at the time necessary, generating less smoke and gases (e.g sulphur that are harmful to environment, and generating less ash, as these have adverse effect during cooking.

  5. Evaluating the bio-energy potential of groundnut shell and sugarcane bagasse waste composite

    OpenAIRE

    Olatunde Ajani Oyelaran

    2015-01-01

    An assessment has been carried out on bio-coal briquettes from coal with sugarcane bagasse and coal with groundnut shell. Proximate analyses and elemental compositions of the coal and biomasses were determined. Different samples of briquettes were produced by blending varying composition of the coal with the biomasses in the ratio of 100:0; 90:10, 80:20, 70:30, 60:40, 50:50, 40:60 and 0: 100, using calcium carbonate as a desulfurizing agent and cassava starch as a binder. A manual hydraulical...

  6. Investigation of Mechanical Behavior of Nettle Filled Hybrid Composites of Nettle Fiber-Hazelnut Shell

    OpenAIRE

    Kenan BÜYÜKKAYA

    2017-01-01

    Polymer beam specimens produced with reinforcement of nettle fiber and fixed nut hazelnut flour at different volume ratios were opened initial notches with a / W = 0.2, 0.3 ratios after thermal curing. The volume percentage of nettle fiber in the composite is 2.5, 5, 7.5 and 10 percent. The grain size of hazelnut shell flour is 0-50μ and the volume ratio in the composite is 15% in all samples. Mode I fracture behaviors of compacted specimens from single sides, compact tensile and mechanical ...

  7. Fano-like resonance and scattering in dielectric(core)–metal(shell) composites embedded in active host matrices

    CSIR Research Space (South Africa)

    Jule, L

    2015-07-01

    Full Text Available We investigate light scattering by core–shell consisting of metal/dielectric composites considering spherical and cylindrical nanoinclusions, within the framework of the conventional Rayleigh approximation. By writing the electric potential...

  8. Core–shell composite particles composed of biodegradable polymer particles and magnetic iron oxide nanoparticles for targeted drug delivery

    Energy Technology Data Exchange (ETDEWEB)

    Oka, Chiemi; Ushimaru, Kazunori [Department of Innovative and Engineered Materials, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8502 (Japan); Horiishi, Nanao [Bengala Techno Laboratory, 9-5-1006, 1-1 Kodai, Miyamae-ku, Kawasaki 216-0007 (Japan); Tsuge, Takeharu [Department of Innovative and Engineered Materials, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8502 (Japan); Kitamoto, Yoshitaka, E-mail: kitamoto.y.aa@m.titech.ac.jp [Department of Innovative and Engineered Materials, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8502 (Japan)

    2015-05-01

    Core–shell composite particles with biodegradability and superparamagnetic behavior were prepared using a Pickering emulsion for targeted drug delivery based on magnetic guidance. The composite particles were composed of a core of biodegradable polymer and a shell of assembled magnetic iron oxide nanoparticles. It was found that the dispersibility of the nanoparticles is crucial for controlling the core–shell structure. The addition of a small amount of dispersant into the nanoparticle's suspension could improve the dispersibility and led to the formation of composite particles with a thin magnetic shell covering a polymeric core. The composite particles were also fabricated with a model drug loaded into the core, which was released via hydrolysis of the core under strong alkaline conditions. Because the core can also be biodegraded by lipase, this result suggests that the slow release of the drug from the composite particles should occur inside the body. - Highlights: • Core−shell composites with biodegradability and magnetism are prepared. • O/W emulsion stabilized by iron oxide nanoparticles is utilized for the preparation. • The nanoparticle's dispersibility is crucial for controlling the composite structure. • Composites loading a model drug are also prepared. • The model drug is released with decomposition of the composites.

  9. Optimization of tribological behaviour on Al- coconut shell ash composite at elevated temperature

    Science.gov (United States)

    Siva Sankara Raju, R.; Panigrahi, M. K.; Ganguly, R. I.; Srinivasa Rao, G.

    2018-02-01

    In this study, determine the tribological behaviour of composite at elevated temperature i.e. 50 - 150 °C. The aluminium matrix composite (AMC) are prepared with compo casting route by volume of reinforcement of coconut shell ash (CSA) such as 5, 10 and 15%. Mechanical properties of composite has enhances with increasing volume of CSA. This study details to optimization of wear behaviour of composite at elevated temperatures. The influencing parameters such as temperature, sliding velocity and sliding distance are considered. The outcome response is wear rate (mm3/m) and coefficient of friction. The experiments are designed based on Taguchi [L9] array. All the experiments are considered as constant load of 10N. Analysis of variance (ANOVA) revealed that temperature is highest influencing factor followed by sliding velocity and sliding distance. Similarly, sliding velocity is most influencing factor followed by temperature and distance on coefficient of friction (COF). Finally, corroborates analytical and regression equation values by confirmation test.

  10. Facile synthesis of silver immobilized-poly(methyl methacrylate)/polyethyleneimine core-shell particle composites

    Energy Technology Data Exchange (ETDEWEB)

    Jenjob, Somkieath [Department of Chemistry, Faculty of Science, Mahidol University, 999 Phuttamonthon 4 Road, Salaya, Nakhon Pathom 73170 (Thailand); Center of Excellence for Innovation in Chemistry (PERCH-CIC), Department of Chemistry, Faculty of Science, Mahidol University, Rama 6 Road, Ratchathewi, Bangkok 10400 (Thailand); Tharawut, Teeralak [Department of Chemistry, Faculty of Science, Mahidol University, 999 Phuttamonthon 4 Road, Salaya, Nakhon Pathom 73170 (Thailand); Sunintaboon, Panya, E-mail: panya.sun@mahidol.ac.th [Department of Chemistry, Faculty of Science, Mahidol University, 999 Phuttamonthon 4 Road, Salaya, Nakhon Pathom 73170 (Thailand); Center of Excellence for Innovation in Chemistry (PERCH-CIC), Department of Chemistry, Faculty of Science, Mahidol University, Rama 6 Road, Ratchathewi, Bangkok 10400 (Thailand); Center for Alternative Energy, Faculty of Science, Mahidol University, 999 Phuttamonthon 4 Road, Salaya, Nakhon Pathom 73170 (Thailand)

    2012-10-01

    A facile route to synthesize silver-embedded-poly(methyl methacrylate)/polyethyleneimine (PMMA/PEI-Ag) core-shell particle composites was illustrated in this present work. PMMA/PEI core-shell particle templates were first prepared by a surfactant-free emulsion polymerization. PEI on the templates' surface was further used to complex and reduce Ag{sup +} ions (from silver nitrate solution) to silver nanoparticles (AgNPs) at ambient temperature, resulting in the PMMA/PEI-Ag particle composites. The formation of AgNPs was affected by the pHs of the reaction medium. The pH of reaction medium at 6.5 was optimal for the formation of PMMA/PEI-Ag with good colloidal stability, which was confirmed by size and size distribution, FTIR spectroscopy, UV-vis spectroscopy and X-ray diffraction. Moreover, the amount of AgNO{sub 3} solution (4.17-12.50 g) was found to affect the formation of AgNPs. Transmission electron microscopy (TEM) indicated that the AgNPs were incorporated in the PMMA/PEI core-shell matrix, and had 6-10 nm in diameter. AgNPs immobilized on PMMA/PEI core-shell particles were also investigated by energy dispersive X-ray spectroscopy analysis mode extended from scanning electron microscopy (SEM/EDS). Furthermore, the presence of AgNPs was found to influence the thermal degradation behavior of PMMA/PEI particle composites as observed through thermogravimetric analysis (TGA). Highlights: Black-Right-Pointing-Pointer A 2-step synthesis of Ag immobilized-PMMA/PEI particle composites was shown. Black-Right-Pointing-Pointer PMMA/PEI core-shell templates were first formed and PEI assisted AgNP formation. Black-Right-Pointing-Pointer Formation of PMMA/PEI-Ag was affected by pH of medium and amount of AgNO{sub 3}. Black-Right-Pointing-Pointer PMMA/PEI-Ag can be confirmed by color change, UV-vis, TEM, SEM with EDS, and X-ray. Black-Right-Pointing-Pointer Effect of AgNPs on thermal degradation of PMMA/PEI-Ag can be observed through TGA.

  11. Fast-dissolving core-shell composite microparticles of quercetin fabricated using a coaxial electrospray process.

    Directory of Open Access Journals (Sweden)

    Chen Li

    Full Text Available This study reports on novel fast-dissolving core-shell composite microparticles of quercetin fabricated using coaxial electrospraying. A PVC-coated concentric spinneret was developed to conduct the electrospray process. A series of analyses were undertaken to characterize the resultant particles in terms of their morphology, the physical form of their components, and their functional performance. Scanning and transmission electron microscopies revealed that the microparticles had spherical morphologies with clear core-shell structure visible. Differential scanning calorimetry and X-ray diffraction verified that the quercetin active ingredient in the core and sucralose and sodium dodecyl sulfate (SDS excipients in the shell existed in the amorphous state. This is believed to be a result of second-order interactions between the components; these could be observed by Fourier transform infrared spectroscopy. In vitro dissolution and permeation studies showed that the microparticles rapidly released the incorporated quercetin within one minute, and had permeation rates across the sublingual mucosa around 10 times faster than raw quercetin.

  12. Design and characterization of core-shell mPEG-PLGA composite microparticles for development of cell-scaffold constructs

    DEFF Research Database (Denmark)

    Wen, Yanhong; Gallego, Monica Ramos; Nielsen, Lene Feldskov

    2013-01-01

    /DS or Alg/CS/DS particles in the mPEG-PLGA microparticles were significantly dependent on the operating conditions, including the flow rate ratio (Qout/Qin) and the viscosity of the polymer solutions (Vout, Vin) between the outer and the inner feeding channels. The core-shell composite microparticles.......e. more sustainable cell growth was induced by the DS released from the core-shell composite microparticles comprising Alg/CS/DS particles. After seeding fibroblasts onto the composite microparticles, excellent cell adhesion was observed, and a successful assembly of the cell-scaffold constructs...... was induced within 7 days. Therefore, the present study demonstrates a novel strategy for fabrication of core-shell composite microparticles comprising additional particulate drug carriers in the core, which provides controlled delivery of DS and favorable cell biocompatibility; an approach to potentially...

  13. Yolk-shell structured composite for fast and selective lithium ion sieving.

    Science.gov (United States)

    Li, Na; Lu, Deli; Zhang, Jinlong; Wang, Lingzhi

    2018-06-15

    Yolk-shell structured C@Li 4 Ti 5 O 12 microspheres composed of carbon core (ca. 500 nm) and sea urchin-like Li 4 Ti 5 O 12 shell (ca. 400-500 nm) are formed by hydrothermally treating the core-shell structured C@TiO 2 in the EtOH/H 2 O solution of LiOH and calcining it in N 2 atmosphere. Yolk-shell structured TiO 2 -type lithium ion sieve is further transformed from C@Li 4 Ti 5 O 12 through the acid treatment, which have a high specific surface area of 201.74 m 2 /g. The composite shows adsorption capacity towards Li + proportional to the pH value in the range of 7-13. The adsorption reaches equilibrium within 2 h with a high equilibrium adsorption capacity of 28.46 mg/g under alkaline conditions, which is ca. 8 times the value of ordinary TiO 2 lithium ion sieve with comparable size and surface area, demonstrating the enhanced adsorption is attributed to the generation of more accessible surficial voids by replacing internal part with light carbon core. The adsorption follows Freundlich and pseudo-second-order kinetic models with a high rate constant of 0.015 g/(mg·min). The selective adsorption to Li + is verified in the presence of K + , Na + , Ca 2+ and Mg 2+ . Copyright © 2018 Elsevier Inc. All rights reserved.

  14. Giant magnetoimpedance in composite wires with insulator layer between non-magnetic core and soft magnetic shell

    International Nuclear Information System (INIS)

    Buznikov, N.A.; Antonov, A.S.; Granovsky, A.B.; Kim, C.G.; Kim, C.O.; Li, X.P.; Yoon, S.S.

    2006-01-01

    A method for calculation of the magnetoimpedance in composite wires having an insulator layer between non-magnetic core and soft magnetic shell is described. It is assumed that the magnetic shell has a helical anisotropy and the driving current flows through the core only. The distribution of eddy currents and expressions for the impedance are found by means of a solution of Maxwell equations taking into account the magnetization dynamics within the shell governed by the Landau-Lifshitz equation. The effect of the insulator layer on the magnetoimpedance is analyzed

  15. Giant magnetoimpedance in composite wires with insulator layer between non-magnetic core and soft magnetic shell

    Energy Technology Data Exchange (ETDEWEB)

    Buznikov, N.A. [Research Center for Advanced Magnetic Materials, Chungnam National University, Daejeon 305-764 (Korea, Republic of); Antonov, A.S. [Institute for Theoretical and Applied Electrodynamics, Russian Academy of Sciences, Moscow 125412 (Russian Federation); Granovsky, A.B. [Faculty of Physics, M.V. Lomonosov Moscow State University, Moscow 119992 (Russian Federation); Kim, C.G. [Research Center for Advanced Magnetic Materials, Chungnam National University, Daejeon 305-764 (Korea, Republic of)]. E-mail: cgkim@cnu.ac.kr; Kim, C.O. [Research Center for Advanced Magnetic Materials, Chungnam National University, Daejeon 305-764 (Korea, Republic of); Li, X.P. [Department of Mechanical Engineering and Division of Bioengineering, National University of Singapore, Singapore 119260 (Singapore); Yoon, S.S. [Department of Physics, Andong National University, Andong 760-749 (Korea, Republic of)

    2006-05-15

    A method for calculation of the magnetoimpedance in composite wires having an insulator layer between non-magnetic core and soft magnetic shell is described. It is assumed that the magnetic shell has a helical anisotropy and the driving current flows through the core only. The distribution of eddy currents and expressions for the impedance are found by means of a solution of Maxwell equations taking into account the magnetization dynamics within the shell governed by the Landau-Lifshitz equation. The effect of the insulator layer on the magnetoimpedance is analyzed.

  16. Transient Dynamic Response of Delaminated Composite Rotating Shallow Shells Subjected to Impact

    Directory of Open Access Journals (Sweden)

    Amit Karmakar

    2006-01-01

    Full Text Available In this paper a transient dynamic finite element analysis is presented to study the response of delaminated composite pretwisted rotating shallow shells subjected to low velocity normal impact. Lagrange's equation of motion is used to derive the dynamic equilibrium equation and moderate rotational speeds are considered wherein the Coriolis effect is negligible. An eight noded isoparametric plate bending element is employed in the finite element formulation incorporating rotary inertia and effects of transverse shear deformation based on Mindlin's theory. To satisfy the compatibility of deformation and equilibrium of resultant forces and moments at the delamination crack front a multipoint constraint algorithm is incorporated which leads to unsymmetric stiffness matrices. The modified Hertzian contact law which accounts for permanent indentation is utilized to compute the contact force, and the time dependent equations are solved by Newmark's time integration algorithm. Parametric studies are performed in respect of location of delamination, angle of twist and rotational speed for centrally impacted graphite-epoxy composite cylindrical shells.

  17. Resonant responses and chaotic dynamics of composite laminated circular cylindrical shell with membranes

    Science.gov (United States)

    Zhang, W.; Liu, T.; Xi, A.; Wang, Y. N.

    2018-06-01

    This paper is focused on the resonant responses and chaotic dynamics of a composite laminated circular cylindrical shell with radially pre-stretched membranes at both ends and clamped along a generatrix. Based on the two-degree-of-freedom non-autonomous nonlinear equations of this system, the method of multiple scales is employed to obtain the four-dimensional nonlinear averaged equation. The resonant case considered here is the primary parametric resonance-1/2 subharmonic resonance and 1:1 internal resonance. Corresponding to several selected parameters, the frequency-response curves are obtained. From the numerical results, we find that the hardening-spring-type behaviors and jump phenomena are exhibited. The jump phenomena also occur in the amplitude curves of the temperature parameter excitation. Moreover, it is found that the temperature parameter excitation, the coupling degree of two order modes and the detuning parameters can effect the nonlinear oscillations of this system. The periodic and chaotic motions of the composite laminated circular cylindrical shell clamped along a generatrix are demonstrated by the bifurcation diagrams, the maximum Lyapunov exponents, the phase portraits, the waveforms, the power spectrums and the Poincaré map. The temperature parameter excitation shows that the Pomeau-Manneville type intermittent chaos occur under the certain initial conditions. It is also found that there exist the twin phenomena between the Pomeau-Manneville type intermittent chaos and the period-doubling bifurcation.

  18. The Effects of Cocos Nucifera (Coconut Shell on the Mechanical and Tribological Properties of Recycled Waste Aluminium Can Composites

    Directory of Open Access Journals (Sweden)

    J.O. Agunsoye

    2014-06-01

    Full Text Available The dry sliding wear behaviour and mechanical properties of recycled aluminium metal matrix composite reinforced with 5 and 10 % coconut shell particles (CSp has been investigated. The particle size of Cocosnucifera (coconut shell that were used ranges from 50-300µm. The wear behaviors of developed samples were investigated under varied loads and speed using pin on disc equipment. The samples were also subjected to tensile, impact and hardness test. The result shows that the additions of coconut shell particles improved the wear resistance of the recycled aluminium can/CSp composites at low Speed (2.36 m/s. However, with increase in Speed (4.72 m/s, an increase in the specific wear rates were observed. Increasing the coconut shell particles additions to the recycled waste aluminium cans (RWAlC reduced the impact resistance, hence the toughness of the RWAlC/CSp composite samples. However, the impact resistance of the composites increased as the Cocosnucifera particle size increased. The result of the filler size variation shows that decrease in filler particles size improved the tensile strength and yield strength of the developed aluminium metal matrix /CSp composite. The hardness of the composite increased with increased additions of the filler within the matrix.

  19. Abrasive wear behaviour of Al-Cu-Mg/palm kernel shell ash particulate composite

    Directory of Open Access Journals (Sweden)

    Gambo Anthony VICTOR

    2017-12-01

    Full Text Available This paper presents a systematic approach to develop a wear model of Al-Cu-Mg/Palm kernel shell ash particulate composites (PKSAp produced by double stir-casting method. Four factors, five levels, central composite, rotatable design matrix was used to optimize the number of experiments. The factors considered were sliding velocity, sliding distance, normal load and mass fraction of PKSA reinforcement in the matrix. Response surface methodology (RSM was employed to develop the mathematical model. The developed regression model was validated by statistical software MINITAB and statistical tool such as analysis of variance (ANOVA. It was found that the developed regression model could be effectively used to predict the wear rate at 95% confidence level. The regression model indicated that the wear rate of cast Al-Cu-Mg/PKSAp composite decreased with an increase in the mass fraction of PKSA and increased with an increase of the sliding velocity, sliding distance and normal load acting on the composite specimen.

  20. Factors controlling carbon isotopic composition of land snail shells estimated from lab culturing experiment

    Science.gov (United States)

    Zhang, Naizhong; Yamada, Keita; Yoshida, Naohiro

    2014-05-01

    Carbon isotopic composition (δ13C) of land snail shell carbonate is widely applied in reconstructing the C3/C4 vegetation distribution of paleo-environment, which is considered to reflect variations of some environmental parameters [1][2][3]. Land snail shell carbon has three potential sources: diet, atmospheric CO2 and ingested carbonate (limestone) [4]. However, their relative contributions to shell carbonate have not been understood well yet [4][5][6][7][8]. More researches are necessary before we could apply this tool in paleo-environment reconstruction, especially inter-lab culturing experiment. A kind of land snail species, Acusta despecta sieboldiana, was collected at Yokohama, Japan and cultured under suitable environment to lay eggs. The second generations were growing up from eggs to adults around 6-12 months at the temperature of 20°, 25° and 30°, respectively. All of the snails at 25° and 30° and most of those at 20° were fed by cabbage (C3 plant) during their life span while others were fed by corn (C4 plant). To investigate the effect of ingested carbonate, some of them were fed by Ca3(PO4)2 powder while others were fed by CaCO3 powder. δ13C of shells were analyzed by an Isotope Ratio Mass Spectrometry (Thermo Finnigan MAT 253); δ13C of food and snail tissue were measured by a Cavity Ring-Down Spectroscopy (Picarro G1121-i). At the same time, δ13C of eggshell and new born snails were analyzed by a Continuous Flow Isotope Ratio Mass Spectrometry (GasBench II). We confirmed that diet, atmospheric CO2 and ingested limestone could be important sources controlling shell δ13C values. And the temperature could affect shell carbonate δ13C values, too. A simple but credible frame was raised to discuss the mechanism of how each possible source and environmental parameter could affect shell carbonate δ13C values based on previous works [4][6][8] and this study. According to this frame and some reasonable assumptions, we have estimated the

  1. I’m Discovering Conics and Designing Buildings with Conics

    Directory of Open Access Journals (Sweden)

    Serkan KULOGLU

    2015-01-01

    Full Text Available There are three stages in this activity. At the first stage, it is provided that gifted students learn the subject of conic through discovery learning method. By this way, the formation of misconceptions that students frequently encounter in mathematics has been prevented. At the second stage, gifted students have been asked to draw the conical objects which they encounter in their daily life. Thus, it has contributed to the development of gifted students’ creativity. At the third stage, gifted students have been asked to design a buildings consisting of conics. Moreover, gifted students have been informed that the buildings which they have been asked to design, would be evaluated according to the criteria which set before. And then, the building design model has been done by gifted students.

  2. Experimental Study of Multi-Walled Composite Shell Fragments under Thermal Force Effects

    Directory of Open Access Journals (Sweden)

    L. P. Tairova

    2015-01-01

    Full Text Available Multi-walled composite shells are a relatively new prospective type of load carrying structures for rocket and space engineering. These CFRP structures are produced by injection and infusion methods and have several advantages in comparison with common structures such as stringer-frame, grid and sandwich structures with a light core. In particular, those have more structural parameters, which enable one to control mechanical properties of the structure, and this is important in designing the load carrying structures of different purpose.Presently, there are few national and foreign publications on experimental investigations of mechanical properties of multi-walled shells. That is why the objective of the paper is to conduct the experimental study of deformation and failure processes of a multi-walled panel both under steady-state heating and under unsteady-state one.The paper presents the results of two tests: (1 the study of deformation and failure modes under compression and complete heating up to a specified temperature and (2 validation of working capability of multi-walled samples under single-side heating and compression simulating a start and flight version of the “ Proton” launch vehicle.Experimental results have shown that average elastic properties of multi-walled samples slightly depend on temperature for the studied range (from room temperature up to 195C while strength properties considerably decrease with increasing temperature, and this is typical for CFRP structures under compression. However, under unsteady-state short-term heating the structure has a strength that exceeds the minimal necessary strength of load carrying structures of the “Proton” launch vehicle (the samples satisfy simulated start conditions of the “Proton” launch vehicle. This is because of a low heat conductivity of the multi-walled core: an unheated sheet holds a low temperature and high load carrying capacity.Obtained results can be used in

  3. Spherical nano-SnSb/MCMB/carbon core–shell composite for high stability lithium ion battery anodes

    International Nuclear Information System (INIS)

    Li, Juan; Ru, Qiang; Hu, Shejun; Sun, Dawei; Zhang, Beibei; Hou, Xianhua

    2013-01-01

    A novel multi-step design of spherical nano-SnSb/MCMB/carbon core–shell composite for high stability and long life lithium battery electrodes has been introduced. The core–shell composite was successfully synthesized via co-precipitation and subsequent pyrolysis. The resultant composite sphere consisted of nanosized SnSb alloy and mesophase carbon microbeads (MCMB, 10 μm) embedded in a carbon matrix pyrolyzed from glucose and petroleum pitch, in which the MCMB was treated to be the inner core to offer mechanical support and efficient electron conducting pathway. The composite material exhibited a unique stability with a retention discharge capacity rate of 83.52% with reversible capacity of 422.5 mAh g −1 after 100 cycles and a high initial coulombic efficiency of 83.53%. The enhanced electrochemical performance is attributed to the structural stability of the composite sphere during the charging–discharging process

  4. Study of the carbon and oxygen isotopic compositions in marine shells of Salvador-Bahia, Brazil

    International Nuclear Information System (INIS)

    Freitas, J.C.B. de.

    1977-01-01

    The carbon and oxygen isotopic composition of 68 samples of marine shells from the region of Salvador was determined. These samples are from points on the open coast and in the interior of the Todos os Santos Bay and they are composed in part by recent specimens and in part by old specimens taken from Quaternary sediments. The results for δ 18 O are in the range of -2,83per mille to + 1,21per mille (PDB) and for δ 13 C in the range of -3,10per mille to +2,63per mille (PDB). The reults for the recent shells from the interior of the Todos os Santos Bay show variations in the δ 13 C values associated to the dominance of organic matter in some regions. For the old samoles, gathered in te variations in the δ 13 C values was associated to the existence in points of that region of deposits of fluvio-lagunar sediments, originated during the last marine transgression. It was identified, for a few species with the same age and location, the effect of biological fractionations. Nevertheless, the observed dominant factor on the isotopic differentiation was the environmental fractionation. (Author) [pt

  5. Chemical Composition of Apricot Pit Shells and Effect of Hot-Water Extraction

    Directory of Open Access Journals (Sweden)

    Derek B. Corbett

    2015-09-01

    Full Text Available Agricultural residues, such as corn stover, wheat straw, and nut shells show promise as feedstocks for lignocellulosic biorefinery due to their relatively high polysaccharide content and low or no nutritional value for human consumption. Apricot pit shells (APS were studied in this work to assess their potential for use in a biorefinery. Hot water extraction (HWE; 160 °C, 2 h, proposed to remove easily accessible hemicelluloses, was performed to evaluate the susceptibility of APS to this mild pretreatment process. The chemical composition of APS before and after HWE (EAPS was analyzed by standard methods and 1H-NMR. A low yield of the remaining HW-extracted APS (~59% indicated that APS are highly susceptible to this pretreatment method. 1H-NMR analysis of EAPS revealed that ~77% of xylan present in raw APS was removed along with ~24% of lignin. The energy of combustion of APS was measured before and after HWE showing a slight increase due to HWE (1.61% increase. Near infrared radiation spectroscopy (NIRS, proposed as a quick non-invasive method of biomass analysis, was performed. NIRS corroborated results of traditional analysis and 1H-NMR. Determination of antioxidizing activity (AOA of APS extracts was also undertaken. AOA of organic APS extracts were shown to be more than 20 times higher than that of a synthetic antioxidizing agent.

  6. Reaction rate of a composite core-shell nanoreactor with multiple nanocatalysts.

    Science.gov (United States)

    Galanti, Marta; Fanelli, Duccio; Angioletti-Uberti, Stefano; Ballauff, Matthias; Dzubiella, Joachim; Piazza, Francesco

    2016-07-27

    We present a detailed theory for the total reaction rate constant of a composite core-shell nanoreactor, consisting of a central solid core surrounded by a hydrogel layer of variable thickness, where a given number of small catalytic nanoparticles are embedded at prescribed positions and are endowed with a prescribed surface reaction rate constant. Besides the precise geometry of the assembly, our theory accounts explicitly for the diffusion coefficients of the reactants in the hydrogel and in the bulk as well as for their transfer free energy jump upon entering the hydrogel shell. Moreover, we work out an approximate analytical formula for the overall rate constant, which is valid in the physically relevant range of geometrical and chemical parameters. We discuss in depth how the diffusion-controlled part of the rate depends on the essential variables, including the size of the central core. In particular, we derive some simple rules for estimating the number of nanocatalysts per nanoreactor for an efficient catalytic performance in the case of small to intermediate core sizes. Our theoretical treatment promises to provide a very useful and flexible tool for the design of superior performing nanoreactor geometries with optimized nanoparticle load.

  7. High ink absorption performance of inkjet printing based on SiO2@Al13 core-shell composites

    Science.gov (United States)

    Chen, YiFan; Jiang, Bo; Liu, Li; Du, Yunzhe; Zhang, Tong; Zhao, LiWei; Huang, YuDong

    2018-04-01

    The increasing growth of the inkjet market makes the inkjet printing more necessary. A composite material based on core-shell structure has been developed and applied to prepare inkjet printing layer. In this contribution, the ink printing record layers based on SiO2@Al13 core-shell composite was elaborated. The prepared core-shell composite materials were characterized by X-ray photoelectron spectroscopy (XPS), zeta potential, X-ray diffraction (XRD), scanning electron microscopy (SEM). The results proved the presence of electrostatic adsorption between SiO2 molecules and Al13 molecules with the formation of the well-dispersed system. In addition, based on the adsorption and the liquid permeability analysis, SiO2@Al13 ink printing record layer achieved a relatively high ink uptake (2.5 gmm-1) and permeability (87%), respectively. The smoothness and glossiness of SiO2@Al13 record layers were higher than SiO2 record layers. The core-shell structure facilitated the dispersion of the silica, thereby improved its ink absorption performance and made the clear printed image. Thus, the proposed procedure based on SiO2@Al13 core-shell structure of dye particles could be applied as a promising strategy for inkjet printing.

  8. Characterizing conical refraction optical tweezers

    Science.gov (United States)

    McDonald, C.; McDougall, C.; Rafailov, E.; McGloin, D.

    2014-12-01

    Conical refraction occurs when a beam of light travels through an appropriately cut biaxial crystal. By focussing the conically refracted beam through a high numerical aperture microscope objective, conical refraction optical tweezers can be created, allowing for particle manipulation in both Raman spots and in the Lloyd/Poggendorff rings. We present a thorough quantification of the trapping properties of such a beam, focussing on the trap stiffness and how this varies with trap power and trapped particle location. We show that the lower Raman spot can be thought of as a single-beam optical gradient force trap, while radiation pressure dominates in the upper Raman spot, leading to optical levitation rather than trapping. Particles in the Lloyd/Poggendorff rings experience a lower trap stiffness than particles in the lower Raman spot but benefit from rotational control.

  9. Core/Shell Conjugated Polymer/Quantum Dot Composite Nanofibers through Orthogonal Non-Covalent Interactions

    Directory of Open Access Journals (Sweden)

    Brad W. Watson

    2016-11-01

    Full Text Available Nanostructuring organic polymers and organic/inorganic hybrid materials and controlling blend morphologies at the molecular level are the prerequisites for modern electronic devices including biological sensors, light emitting diodes, memory devices and solar cells. To achieve all-around high performance, multiple organic and inorganic entities, each designed for specific functions, are commonly incorporated into a single device. Accurate arrangement of these components is a crucial goal in order to achieve the overall synergistic effects. We describe here a facile methodology of nanostructuring conjugated polymers and inorganic quantum dots into well-ordered core/shell composite nanofibers through cooperation of several orthogonal non-covalent interactions including conjugated polymer crystallization, block copolymer self-assembly and coordination interactions. Our methods provide precise control on the spatial arrangements among the various building blocks that are otherwise incompatible with one another, and should find applications in modern organic electronic devices such as solar cells.

  10. Simplified welding distortion analysis for fillet welding using composite shell elements

    Directory of Open Access Journals (Sweden)

    Mingyu Kim

    2015-05-01

    Full Text Available This paper presents the simplified welding distortion analysis method to predict the welding deformation of both plate and stiffener in fillet welds. Currently, the methods based on equivalent thermal strain like Strain as Direct Boundary (SDB has been widely used due to effective prediction of welding deformation. Regarding the fillet welding, however, those methods cannot represent deformation of both members at once since the temperature degree of freedom is shared at the intersection nodes in both members. In this paper, we propose new approach to simulate deformation of both members. The method can simulate fillet weld deformations by employing composite shell element and using different thermal expansion coefficients according to thickness direction with fixed temperature at intersection nodes. For verification purpose, we compare of result from experiments, 3D thermo elastic plastic analysis, SDB method and proposed method. Compared of experiments results, the proposed method can effectively predict welding deformation for fillet welds.

  11. Core/shell fluorescent magnetic silica-coated composite nanoparticles for bioconjugation

    Science.gov (United States)

    He, Rong; You, Xiaogang; Shao, Jun; Gao, Feng; Pan, Bifeng; Cui, Daxiang

    2007-08-01

    A new class of highly fluorescent, photostable, and magnetic core/shell nanoparticles has been synthesized from a reverse microemulsion method. The obtained bifunctional nanocomposites were characterized by transmission electron microscopy (TEM), ultraviolet-visible (UV-vis) spectrometry, photoluminescence (PL) spectrometry, and fluorescence microscopy in a magnetic field. To further improve their biocompatibility, the silica-coated nanoparticles were functionalized with amino groups. The fluorescent magnetic composite nanoparticles (FMCNPs) had a typical diameter of 50 ± 5 nm and a saturation magnetization of 3.21 emu g-1 at room temperature, and exhibited strong excitonic photoluminescence. Through activation with glutaraldehyde, the FMCNPs were successfully conjugated with goat anti-mouse immunoglobin G (GM IgG), and the bioactivity and binding specificity of the as-prepared FMCNPs-GM IgG were confirmed via immunofluorescence assays, commonly used in bioanalysis. So they are potentially useful for many applications in biolabelling, imaging, drug targeting, bioseparation and bioassays.

  12. Core/shell fluorescent magnetic silica-coated composite nanoparticles for bioconjugation

    International Nuclear Information System (INIS)

    He Rong; You Xiaogang; Shao Jun; Gao Feng; Pan Bifeng; Cui Daxiang

    2007-01-01

    A new class of highly fluorescent, photostable, and magnetic core/shell nanoparticles has been synthesized from a reverse microemulsion method. The obtained bifunctional nanocomposites were characterized by transmission electron microscopy (TEM), ultraviolet-visible (UV-vis) spectrometry, photoluminescence (PL) spectrometry, and fluorescence microscopy in a magnetic field. To further improve their biocompatibility, the silica-coated nanoparticles were functionalized with amino groups. The fluorescent magnetic composite nanoparticles (FMCNPs) had a typical diameter of 50 ± 5 nm and a saturation magnetization of 3.21 emu g -1 at room temperature, and exhibited strong excitonic photoluminescence. Through activation with glutaraldehyde, the FMCNPs were successfully conjugated with goat anti-mouse immunoglobin G (GM IgG), and the bioactivity and binding specificity of the as-prepared FMCNPs-GM IgG were confirmed via immunofluorescence assays, commonly used in bioanalysis. So they are potentially useful for many applications in biolabelling, imaging, drug targeting, bioseparation and bioassays

  13. Facile Synthesis of Yolk/Core-Shell Structured TS-1@Mesosilica Composites for Enhanced Hydroxylation of Phenol

    KAUST Repository

    Zou, Houbing

    2015-12-14

    © 2015 by the authors. In the current work, we developed a facile synthesis of yolk/core-shell structured TS-1@mesosilica composites and studied their catalytic performances in the hydroxylation of phenol with H2O2 as the oxidant. The core-shell TS-1@mesosilica composites were prepared via a uniform coating process, while the yolk-shell TS-1@mesosilica composite was prepared using a resorcinol-formaldehyde resin (RF) middle-layer as the sacrificial template. The obtained materials were characterized by X-ray diffraction (XRD), N2 sorption, Fourier transform infrared spectoscopy (FT-IR) UV-Visible spectroscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The characterization results showed that these samples possessed highly uniform yolk/core-shell structures, high surface area (560–700 m2 g−1) and hierarchical pore structures from oriented mesochannels to zeolite micropores. Importantly, owing to their unique structural properties, these composites exhibited enhanced activity, and also selectivity in the phenol hydroxylation reaction.

  14. Advanced grid-stiffened composite shells for applications in heavy-lift helicopter rotor blade spars

    Science.gov (United States)

    Narayanan Nampy, Sreenivas

    Modern rotor blades are constructed using composite materials to exploit their superior structural performance compared to metals. Helicopter rotor blade spars are conventionally designed as monocoque structures. Blades of the proposed Heavy Lift Helicopter are envisioned to be as heavy as 800 lbs when designed using the monocoque spar design. A new and innovative design is proposed to replace the conventional spar designs with light weight grid-stiffened composite shell. Composite stiffened shells have been known to provide excellent strength to weight ratio and damage tolerance with an excellent potential to reduce weight. Conventional stringer--rib stiffened construction is not suitable for rotor blade spars since they are limited in generating high torsion stiffness that is required for aeroelastic stability of the rotor. As a result, off-axis (helical) stiffeners must be provided. This is a new design space where innovative modeling techniques are needed. The structural behavior of grid-stiffened structures under axial, bending, and torsion loads, typically experienced by rotor blades need to be accurately predicted. The overall objective of the present research is to develop and integrate the necessary design analysis tools to conduct a feasibility study in employing grid-stiffened shells for heavy-lift rotor blade spars. Upon evaluating the limitations in state-of-the-art analytical models in predicting the axial, bending, and torsion stiffness coefficients of grid and grid-stiffened structures, a new analytical model was developed. The new analytical model based on the smeared stiffness approach was developed employing the stiffness matrices of the constituent members of the grid structure such as an arch, helical, or straight beam representing circumferential, helical, and longitudinal stiffeners. This analysis has the capability to model various stiffening configurations such as angle-grid, ortho-grid, and general-grid. Analyses were performed using an

  15. Experiments on active precision isolation with a smart conical adapter

    Science.gov (United States)

    Li, H.; Li, H. Y.; Chen, Z. B.; Tzou, H. S.

    2016-07-01

    Based on a conical shell adaptor, an active vibration isolator for vibration control of precision payload is designed and tested in this study. Flexible piezoelectric sensors and actuators are bonded on the adaptor surface for active vibration monitoring and control. The mathematical model of a piezoelectric laminated conical shell is derived and then optimal design of the actuators is performed for the first axial vibration mode of the isolation system. A scaled conical adaptor is manufactured with four MFC actuators laminating on its outer surface. Active vibration isolation efficiency is then evaluated on a vibration shaker. The control model is built in Matlab/Simulink and programmed into the dSPACE control board. Experimental results show that, the proposed active isolator is effective in vibration suppression of payloads with the negative velocity feedback control. In contrast, the amplitude responses increase with positive feedback control. Furthermore, the amplitude responses increases when time delay is added into the control signals, and gets the maximum when the delay is close to one quarter of one cycle time.

  16. Understanding the Conics through Augmented Reality

    Science.gov (United States)

    Salinas, Patricia; Pulido, Ricardo

    2017-01-01

    This paper discusses the production of a digital environment to foster the learning of conics through augmented reality. The name conic refers to curves obtained by the intersection of a plane with a right circular conical surface. The environment gives students the opportunity to interact with the cone and the plane as virtual objects in real…

  17. Investigation of Mechanical Behavior of Nettle Filled Hybrid Composites of Nettle Fiber-Hazelnut Shell

    Directory of Open Access Journals (Sweden)

    Kenan BÜYÜKKAYA

    2017-12-01

    Full Text Available Polymer beam specimens produced with reinforcement of nettle fiber and fixed nut hazelnut flour at different volume ratios were opened initial notches with a / W = 0.2, 0.3 ratios after thermal curing. The volume percentage of nettle fiber in the composite is 2.5, 5, 7.5 and 10 percent. The grain size of hazelnut shell flour is 0-50μ and the volume ratio in the composite is 15% in all samples. Mode I fracture behaviors of compacted specimens from single sides, compact tensile and mechanical behavior were determined by three point bending test and impact test. The amount of crack opening was determined by the high-speed camera recorder. The bending test determined bending modulus and bending stresses. The morphological structure of the fractured surfaces obtained from the impulse test was revealed by sem views. It has been observed that the added hazelnut flour enhances the flexural modulus while reducing bending stress, fracture strength and impact resistance

  18. Assembly of core–shell structured porous carbon–graphene composites as anode materials for lithium-ion batteries

    International Nuclear Information System (INIS)

    Guo, Rong; Zhao, Li; Yue, Wenbo

    2015-01-01

    As potential anode materials for lithium-ion batteries, mesoporous carbons such as CMK-3 and CMK-8 usually show stable cycling performances but only slightly higher reversible capacities than commercial graphite. Graphene has much higher theoretical capacity than that of graphite in theory. However, its electrochemical behavior is not as good as expected due to the aggregation of graphene nanosheets. Herein we describe a novel strategy for the preparation of core–shell structured porous carbon–graphene composites. Compared to pure porous carbons or pure graphene nanosheets, these novel composites exhibit superior electrochemical performances including higher reversible capacities and better cycle/rate performances. This core–shell structure can avoid the aggregation of graphene nanosheets as well as may stabilize the mesostructure of porous carbon, which is beneficial to improving the electrochemical performances of the composites

  19. Electrochemical characterization of core@shell CoFe{sub 2}O{sub 4}/Au composite

    Energy Technology Data Exchange (ETDEWEB)

    Carla, Francesco [' Ugo Schiff' , Universita degli Studi di Firenze, Dipartimento di Chimica (Italy); Campo, Giulio; Sangregorio, Claudio; Caneschi, Andrea; Julian Fernandez, Cesar de; Cabrera, Lourdes I., E-mail: lourisa_cabrera@yahoo.com [Universita degli Studi di Firenze, Laboratorio di Magnetismo Molecolare, INSTM, Dipartimento di Chimica (Italy)

    2013-08-15

    In this paper, we address the synthesis and characterization of the core@shell composite magneto-plasmonic cobalt ferrite-gold (Co-ferrite/Au) nanosystem. The synthesis Co-ferrite/Au nanocomposite is not obvious, hence it was of interest to generate it in a simple straightforward method. Co-ferrite/Au nanocomposite was generated by synthesizing first by thermal decomposition Co-ferrite nanoparticles (NPs). On a second step, ionic gold (Au{sup 3+}) was reduced at the surface of Co-ferrite NPs by ultrasound, to obtain the metallic Au shell. The characterization of the nanomaterial was achieved by microscopy, spectroscopy, and performing magnetic measurements. However, what is attractive about our work is the use of electrochemical techniques as analytical tools. The key technique was cyclic voltammetry, which provided information about the nature and structure of the nanocomposite, allowing us to confirm the core@shell structure.

  20. Bimetal cup hydroforming of Al/St and Cu/St composites: Adaptive finite element analysis and experimental study

    Energy Technology Data Exchange (ETDEWEB)

    Hashemi, Abbas; Gollo, Mohammad Hoseinpour [Shahid Rajaee Teacher Training University, Tehran (Iran, Islamic Republic of); Seyedkashi, S. M. [University of Birjand, Birjand (Iran, Islamic Republic of)

    2016-05-15

    An adaptive Finite element analysis (FEA) was proposed in this paper for the industrial design of bimetal conical-cylindrical cup hydroforming. Forming circumstances for the perfect and imperfect parts were concluded through adaptive FEA using the ANSYS parametric design language. Effective parameters, including pressure loading path, layer placement order, and thickness ratio, were investigated for hydroforming of Al/St and Cu/St composite sheets. Experimental tests were implemented to validate adaptive finite element results. Rupture failure upon the pressure path occurred on the contact area between the blank and punch tip radius at low pressures and on the transition area of the conical-cylindrical portion at high pressures. The proposed method is applicable for any cylindrical, conical, or cylindrical/conical shapes with different materials and dimensions. Therefore, this method is beneficial as a practical design tool for engineers and researchers working in the process design of hydroformed shell products.

  1. Preparation, characterization and infrared emissivity study of helical polyurethane-SiO2 core-shell composite

    International Nuclear Information System (INIS)

    Wang Zhiqiang; Zhou Yuming; Yao Qingzhao; Sun Yanqing

    2009-01-01

    Helical polyurethane-SiO 2 (HPU-SiO 2 ) core-shell composite was prepared after surface modification of SiO 2 nanoparticles. HPU-SiO 2 was characterized by Fourier-transform infrared (FT-IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), ultraviolet (UV) spectroscopy, X-ray diffraction (XRD) and transmission electron microscopy (TEM). The results indicate that the helical polyurethane has been successfully grafted onto the surfaces of the modified SiO 2 . HPU-SiO 2 composite exhibits clearly core-shell structure. The ultraviolet absorption and crystallizability of HPU-SiO 2 are changed due to the shell of helical polyurethane, which possesses regular single-handed conformation and inter-chain hydrogen bonds. The infrared emissivity of HPU-SiO 2 was also investigated. The result indicates that the interfacial interactions between organic shell and inorganic core induce the infrared emissivity value being reduced from 0.781 for SiO 2 to 0.503 for HPU-SiO 2 .

  2. Composition-dependent photoluminescence properties of CuInS_2/ZnS core/shell quantum dots

    International Nuclear Information System (INIS)

    Hua, Jie; Du, Yuwei; Wei, Qi; Yuan, Xi; Wang, Jin; Zhao, Jialong; Li, Haibo

    2016-01-01

    CuInS_2/ZnS (CIS/ZnS) core/shell quantum dots (QDs) with various Cu/In ratios were synthesized using the hot-injection method, and their photoluminescence (PL) properties were investigated by measuring steady-state and time-resolved PL spectroscopy. The emission peak of the CIS/ZnS QDs were tuned from 680 to 580 nm by decreasing the Cu/In precursor ratio from 1/1 to 1/9. As the Cu/In ratio decreases, the PL lifetimes and PL quantum yields (QYs) of CIS/ZnS core/shell QDs increased firstly and then decreased. Two dominant radiative recombination processes were postulated to analyze composition-dependent PL properties, including the recombination from a quantized conduction band to deep defects state and donor-acceptor pair (DAP) recombination. The decrease of PL efficiency resulted from high density defects and traps, which formed at the interface between CIS core and ZnS shell due to the large off-stoichiometry composition. The PL intensity and peak energy for CIS/ZnS core/shell QDs as a function of temperature were also provided. The thermal quenching further confirmed that the PL emission of CIS/ZnS QDs did not come from the recombination of excitons but from the recombination of many kinds of intrinsic defects inside the QDs as emission centers.

  3. Fabrication and performances of microencapsulated paraffin composites with polymethylmethacrylate shell based on ultraviolet irradiation-initiated

    Energy Technology Data Exchange (ETDEWEB)

    Wang Yi, E-mail: wangyi@lut.cn [State Key Laboratory of Gansu Advanced Non-ferrous Metal Materials, Lanzhou University of Technology, Lanzhou 730050 (China); College of Petrochemical Technology, Lanzhou University of Technology, Lanzhou 730050 (China); Shi Huan [College of Petrochemical Technology, Lanzhou University of Technology, Lanzhou 730050 (China); Xia Tiandong [State Key Laboratory of Gansu Advanced Non-ferrous Metal Materials, Lanzhou University of Technology, Lanzhou 730050 (China); Zhang Ting; Feng Huixia [College of Petrochemical Technology, Lanzhou University of Technology, Lanzhou 730050 (China)

    2012-07-16

    In order to identify the validity of fabricating microencapsulated phase change material by ultraviolet irradiation-initiated method, the paraffin wax/polymethyl methacrylate microcapsules were prepared. The structural characteristics and thermal properties of the microcapsules were also determined by various techniques. The results of differential scanning calorimetry analyses indicate that the melting and freezing temperatures and latent heats of the microcapsules are 55.8 Degree-Sign C, 50.1 Degree-Sign C and 106.9 J g{sup -1}, 112.3 J g{sup -1}, respectively. Morphology and chemical characteristic analysis indicate that the spherical microcapsules were formed with average diameter of 0.21 {mu}m and maximum microencapsulation ratio of 66 wt.% without leakage of core materials. The results of accelerated thermal cyclic test show that the microcapsules have good thermal reliability and chemical stability although they were subjected 3000 melting/freezing cycles. Based on all these results, it can be concluded that the microencapsulated paraffin composites have good potential for thermal energy storage purposes and ultraviolet irradiation-initiated method is a prominent candidate for preparing microencapsulated PCMs. - Highlights: Black-Right-Pointing-Pointer Microencapsulated paraffin with PMMA shell was synthesized via self-assembly. Black-Right-Pointing-Pointer Microcapsules with excellent properties can be prepared by UV initiated method. Black-Right-Pointing-Pointer The microencapsulation ratio is as high as 66 wt.%. Black-Right-Pointing-Pointer Thermal properties are as high as comparable with microcapsules in the literature.

  4. Phase change Materials (PCM) microcapsules with different shell compositions: Preparation, characterization and thermal stability

    Energy Technology Data Exchange (ETDEWEB)

    Bayes-Garcia, L.; Ventola, L.; Cordobilla, R.; Benages, R.; Calvet, T.; Cuevas-Diarte, M.A. [Departament de Cristal.lografia, Mineralogia i Diposits Minerals, Facultat de Geologia, Universitat de Barcelona, Marti i Franques s/n, E-08028 Barcelona (Spain)

    2010-07-15

    In this study, phase change materials (Rubitherm registered RT 27) microcapsules were successfully obtained by two different methods. The main difference between them remains on the shell composition, as they are composed of different coacervates (Sterilized Gelatine/Arabic Gum for the SG/AG method and Agar-Agar/Arabic Gum for the AA/AG method). Microcapsules were thermally characterized by thermo-optical microscopy and differential scanning calorimetry. Using scanning electron microscopy, their spherical morphology (sphericity factor of 0.94-0.95) and their particle size distribution were determined, obtaining an average diameter of 12 {mu}m for the SG/AG method and lower values for the AA/AG method, where nanocapsules were also observed (average diameter of 4.3 {mu}m for the microcapsules and 104 nm for the nanocapsules). The thermal stability determination was carried out by Thermogravimetric analyses (TG) and the results show a high decomposition temperature, although the process takes places in four steps for the two mentioned methods. Moreover, the microcapsules obtained by the AA/AG method decompose in a more gradual way, as in the TG results a double step, instead of one, is appreciable. On the whole, the prepared microencapsulated PCM are totally capable of developing their role in thermal energy storage. (author)

  5. Fabrication and performances of microencapsulated paraffin composites with polymethylmethacrylate shell based on ultraviolet irradiation-initiated

    International Nuclear Information System (INIS)

    Wang Yi; Shi Huan; Xia Tiandong; Zhang Ting; Feng Huixia

    2012-01-01

    In order to identify the validity of fabricating microencapsulated phase change material by ultraviolet irradiation-initiated method, the paraffin wax/polymethyl methacrylate microcapsules were prepared. The structural characteristics and thermal properties of the microcapsules were also determined by various techniques. The results of differential scanning calorimetry analyses indicate that the melting and freezing temperatures and latent heats of the microcapsules are 55.8 °C, 50.1 °C and 106.9 J g −1 , 112.3 J g −1 , respectively. Morphology and chemical characteristic analysis indicate that the spherical microcapsules were formed with average diameter of 0.21 μm and maximum microencapsulation ratio of 66 wt.% without leakage of core materials. The results of accelerated thermal cyclic test show that the microcapsules have good thermal reliability and chemical stability although they were subjected 3000 melting/freezing cycles. Based on all these results, it can be concluded that the microencapsulated paraffin composites have good potential for thermal energy storage purposes and ultraviolet irradiation-initiated method is a prominent candidate for preparing microencapsulated PCMs. - Highlights: ► Microencapsulated paraffin with PMMA shell was synthesized via self-assembly. ► Microcapsules with excellent properties can be prepared by UV initiated method. ► The microencapsulation ratio is as high as 66 wt.%. ► Thermal properties are as high as comparable with microcapsules in the literature.

  6. Path integration in conical space

    International Nuclear Information System (INIS)

    Inomata, Akira; Junker, Georg

    2012-01-01

    Quantum mechanics in conical space is studied by the path integral method. It is shown that the curvature effect gives rise to an effective potential in the radial path integral. It is further shown that the radial path integral in conical space can be reduced to a form identical with that in flat space when the discrete angular momentum of each partial wave is replaced by a specific non-integral angular momentum. The effective potential is found proportional to the squared mean curvature of the conical surface embedded in Euclidean space. The path integral calculation is compatible with the Schrödinger equation modified with the Gaussian and the mean curvature. -- Highlights: ► We study quantum mechanics on a cone by the path integral approach. ► The path integral depends only on the metric and the curvature effect is built in. ► The approach is consistent with the Schrödinger equation modified by an effective potential. ► The effective potential is found to be of the “Jensen–Koppe” and “da Costa” type.

  7. Food Protein Based Core-Shell Nanocarriers for Oral Drug Delivery: Effect of Shell Composition on in Vitro and in Vivo Functional Performance of Zein Nanocarriers.

    Science.gov (United States)

    Alqahtani, Mohammed S; Islam, M Saiful; Podaralla, Satheesh; Kaushik, Radhey S; Reineke, Joshua; Woyengo, Tofuko; Perumal, Omathanu

    2017-03-06

    The study was aimed at systematically investigating the influence of shell composition on the particle size, stability, release, cell uptake, permeability, and in vivo gastrointestinal distribution of food protein based nanocarriers for oral delivery applications. Three different core-shell nanocarriers were prepared using food-grade biopolymers including zein-casein (ZC) nanoparticles, zein-lactoferrin (ZLF), nanoparticles and zein-PEG (ZPEG) micelles. Nile red was used as a model hydrophobic dye for in vitro studies. The nanocarriers had negative, positive, and neutral charge, respectively. All three nanocarriers had a particle size of less than 200 nm and a low polydispersity index. The nanoparticles were stable at gastrointestinal pH (2-9) and ionic strength (10-200 mM). The nanocarriers sustained the release of Nile red in simulated gastric and intestinal fluids. ZC nanoparticles showed the slowest release followed by ZLF nanoparticles and ZPEG micelles. The nanocarriers were taken up by endocytosis in Caco-2 cells. ZPEG micelles showed the highest cell uptake and transepithelial permeability followed by ZLF and ZC nanoparticles. ZPEG micelles also showed P-gp inhibitory activity. All three nanocarriers showed bioadhesive properties. Cy 5.5, a near IR dye, was used to study the in vivo biodistribution of the nanocarriers. The nanocarriers showed longer retention in the rat gastrointestinal tract compared to the free dye. Among the three formulations, ZC nanoparticles was retained the longest in the rat gastrointestinal tract (≥24 h). Overall, the outcomes from this study demonstrate the structure-function relationship of core-shell protein nanocarriers. The findings from this study can be used to develop food protein based oral drug delivery systems with specific functional attributes.

  8. Nitrite sensing composite systems based on a core-shell emissive-superamagnetic structure: Construction, characterization and sensing behavior

    Science.gov (United States)

    Yang, Yan; Liu, Liang; Zha, Jianhua; Yuan, Ningyi

    2017-04-01

    Two recyclable nitrite sensing composite samples were designed and constructed through a core-shell structure, with Fe3O4 nanoparticles as core, silica molecular sieve MCM-41 as shell and two rhodamine derivatives as chemosensors, respectively. These samples and their structure were identified with their electron microscopy images, N2 adsorption/desorption isotherms, magnetic response, IR spectra and thermogravimetric analysis. Their nitrite sensing behavior was discussed based on emission intensity quenching, their limit of detection was found as low as 1.2 μM. Further analysis suggested a static sensing mechanism between nitrite and chemosensors through an additive reaction between NO+ and chemosensors. After finishing their nitrite sensing, these composite samples and their emission could be recycled and recovered by sulphamic acid.

  9. Synthesis of eccentric titania-silica core-shell and composite particles

    NARCIS (Netherlands)

    Demirors, A.F.; van Blaaderen, A.; Imhof, A.

    2009-01-01

    We describe a novel method to synthesize colloidal particles with an eccentric core-shell structure. Titania-silica core-shell particles were synthesized by silica coating of porous titania particles under Sto¨ber (Sto¨ber et al. J. Colloid Interface Sci. 1968, 26, 62) conditions. We can control

  10. Ballistic Simulation Method for Lithium Ion Batteries (BASIMLIB) Using Thick Shell Composites (TSC) in LS-DYNA

    Science.gov (United States)

    2016-08-04

    BAllistic SImulation Method for Lithium Ion Batteries (BASIMLIB) using Thick Shell Composites (TSC) in LS-DYNA Venkatesh Babu, Dr. Matt Castanier, Dr...and behavior of the cells through experimental and modeling at their crash worthiness laboratory • Most of the simulation work on the batteries are...at a single cell level and gap exists to simulate the batteries at their full pack capacity - Firstly, requires an enormous amount of computational

  11. Composition, Shell Strength, and Metabolizable Energy of Mulinia lateralis and Ischadium recurvum as Food for Wintering Surf Scoters (Melanitta perspicillata.

    Directory of Open Access Journals (Sweden)

    Alicia M Wells-Berlin

    Full Text Available Decline in surf scoter (Melanitta perspicillata waterfowl populations wintering in the Chesapeake Bay has been associated with changes in the availability of benthic bivalves. The Bay has become more eutrophic, causing changes in the benthos available to surf scoters. The subsequent decline in oyster beds (Crassostrea virginica has reduced the hard substrate needed by the hooked mussel (Ischadium recurvum, one of the primary prey items for surf scoters, causing the surf scoter to switch to a more opportune species, the dwarf surfclam (Mulinia lateralis. The composition (macronutrients, minerals, and amino acids, shell strength (N, and metabolizable energy (kJ of these prey items were quantified to determine the relative foraging values for wintering scoters. Pooled samples of each prey item were analyzed to determine composition. Shell strength (N was measured using a shell crack compression test. Total collection digestibility trials were conducted on eight captive surf scoters. For the prey size range commonly consumed by surf scoters (6-12 mm for M. lateralis and 18-24 mm for I. recurvum, I. recurvum contained higher ash, protein, lipid, and energy per individual organism than M. lateralis. I. recurvum required significantly greater force to crack the shell relative to M. lateralis. No difference in metabolized energy was observed for these prey items in wintering surf scoters, despite I. recurvum's higher ash content and harder shell than M. lateralis. Therefore, wintering surf scoters were able to obtain the same amount of energy from each prey item, implying that they can sustain themselves if forced to switch prey.

  12. On the efficiency of conical targets for laser thermonuclear fusion

    International Nuclear Information System (INIS)

    Borovskij, A.V.; Korobkin, V.V.

    1981-01-01

    Advantages and drawbacks of conical targets (CT) for laser fusion (LF) are discussed. Possibility of the laser power reduction, laser pulse lengthening and neutron yield increase are analyzed for an ideal conical target with absolutely rigid and heat-proof walls as compared to a spherical target of the same mass. A simple theory is suggested which makes it possible to take into account an effect of walls on the fusion process in the conical target with gaseous fuel and heavy shell. Energy losses due to wall deformations and heat conduction are estimated. An influence of these effects on the neutron yield is estimated. CT used in the LF experiments are found to have serious drawbacks in comparison with spherical ones. These drawbacks are connected with the effect of walls on the processes taking place in CT. Analysis of CT, for which the effect of walls is not significant, points up some definite advantages of CT as compared with spherical one. These advantages are the possibility of laser pulse lengthening and laser power reduction in comparison with the irradiation of a sphere of an equal mass. These two positive qualities are connected with the fact that CT has large linear dimensions [ru

  13. Environmental controls on the boron and strontium isotopic composition of aragonite shell material of cultured Arctica islandica

    Directory of Open Access Journals (Sweden)

    Y.-W. Liu

    2015-06-01

    Full Text Available Ocean acidification, the decrease in ocean pH associated with increasing atmospheric CO2, is likely to impact marine organisms, particularly those that produce carbonate skeletons or shells. Therefore, it is important to investigate how environmental factors (seawater pH, temperature and salinity influence the chemical compositions in biogenic carbonates. In this study we report the first high-resolution strontium (87Sr / 86Sr and δ88 / 86Sr and boron (δ11B isotopic values in the aragonite shell of cultured Arctica islandica (A. islandica. The 87Sr / 86Sr ratios from both tank water and shell samples show ratios nearly identical to the open ocean, which suggests that the shell material reflects ambient ocean chemistry without terrestrial influence. The 84Sr–87Sr double-spike-resolved shell δ88 / 86Sr and Sr concentration data show no resolvable change throughout the culture period and reflect no theoretical kinetic mass fractionation throughout the experiment despite a temperature change of more than 15 °C. The δ11B records from the experiment show at least a 5‰ increase through the 29-week culture season (January 2010–August 2010, with low values from the beginning to week 19 and higher values thereafter. The larger range in δ11B in this experiment compared to predictions based on other carbonate organisms (2–3‰ suggests that a species-specific fractionation factor may be required. A significant correlation between the ΔpH (pHshell − pHsw and seawater pH (pHsw was observed (R2 = 0.35, where the pHshell is the calcification pH of the shell calculated from boron isotopic composition. This negative correlation suggests that A. islandica partly regulates the pH of the extrapallial fluid. However, this proposed mechanism only explains approximately 35% of the variance in the δ11B data. Instead, a rapid rise in δ11B of the shell material after week 19, during the summer, suggests that the boron uptake changes when a thermal

  14. CONICAL EQUIPOTENTIAL SUBSTRATE FOR LIQUID METAL SOURCES

    OpenAIRE

    Kubby , J.; Siegel , B.

    1986-01-01

    Morphological changes that occur at an ion bombarded surface as a result of erosion by sputtering can be utilized for the machining of cylindrically symmetric submicron structures. Such structuring has produced tungsten field emitters of conical configuration with variable cone half angle. A conical equipotential surface with an included half angle of 49.3° would be a useful emitter substrate for experiments designed to produce an equilibrium conical interface to a conducting fluid in an appl...

  15. Direct femtosecond observation of charge carrier recombination in ternary semiconductor nanocrystals: The effect of composition and shelling

    KAUST Repository

    Bose, Riya

    2015-02-12

    Heavy-metal free ternary semiconductor nanocrystals are emerging as key materials in photoactive applications. However, the relative abundance of intra-bandgap defect states and lack of understanding of their origins within this class of nanocrystals are major factors limiting their applicability. To remove these undesirable defect states which considerably shorten the lifetimes of photogenerated excited carriers, a detailed understanding about their origin and nature is required. In this report, we monitor the ultrafast charge carrier dynamics of CuInS2 (CIS), CuInSSe (CISSe), and CuInSe2 (CISe) nanocrystals, before and after ZnS shelling, using state-of-the-art time-resolved laser spectroscopy with broadband capabilities. The experimental results demonstrate the presence of both electron and hole trapping intra-bandgap states in the nanocrystals which can be removed significantly by ZnS shelling, and the carrier dynamics is slowed down. Another important observation remains the reduction of carrier lifetime in the presence of Se, and the shelling strategy is observed to be less effective at suppressing trap states. This study provides quantitative physical insights into the role of anion composition and shelling on the charge carrier dynamics in ternary CIS, CISSe, and CISe nanocrystals which are essential to improve their applicability for photovoltaics and optoelectronics.

  16. The lignin pyrolysis composition and pyrolysis products of palm kernel shell, wheat straw, and pine sawdust

    International Nuclear Information System (INIS)

    Chang, Guozhang; Huang, Yanqin; Xie, Jianjun; Yang, Huikai; Liu, Huacai; Yin, Xiuli; Wu, Chuangzhi

    2016-01-01

    Highlights: • The primarily pyrolysis composition of PKS lignin was p-hydroxyphenyl unit. • Higher phenol yield and lower gas energy yield were obtained from PKS pyrolysis. • PKS produced more bio-oil and biochar than WS and PS from pyrolysis at 650–850 °C. • PKS-char had poorer gasification reactivity due to higher ordering carbon degree. - Abstract: The lignin monomer composition of palm kernel shell (PKS) was characterized using pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS), and the characteristics and distributions of products obtained from PKS pyrolysis were investigated using Py-GC/MS, GC, and a specially designed pyrolysis apparatus. The gasification reactivity of PKS biochar was also characterized using thermogravimetry (TG) and Raman spectroscopy. All the results were compared with those obtained from wheat straw (WS) and pine sawdust (PS). The results showed that PKS lignin is primarily composed of p-hydroxyphenyl structural units, while WS and PS lignins are mainly made up of guaiacyl units. Both the mass and energy yields of non-condensable gases from PKS pyrolysis were lower than those obtained from WS and PS pyrolysis at 650–850 °C, owing to the lower volatile content (75.21%) and lack of methoxy groups in PKS. Compared with WS and PS, higher bio-oil productivity was observed during PKS pyrolysis. Phenols were the main component of PKS bio-oil from pyrolysis at 500 °C, and the phenol content of PKS bio-oil (13.49%) was higher than in WS bio-oil (1.62%) and PS bio-oil (0.55%). A higher yield of biochar (on an ash-free basis) was also obtained from PKS pyrolysis. Because of its greater relative degree of ordered carbon, PKS biochar exhibited lower in situ reactivity during CO_2 or H_2O gasification than WS and PS biochars. A longer residence time and addition of steam were found to be beneficial during PKS biochar gasification.

  17. Synthesis of Hβ (core)/SAPO-11 (shell) Composite Molecular Sieve and its Catalytic Performances in the Methylation of Naphthalene with Methanol

    International Nuclear Information System (INIS)

    Wang, Xiaoxiao; Zhao, Liangfu; Guo, Shaoqing

    2013-01-01

    Hβ (core)/SAPO-11 (shell) composite molecular sieve was synthesized by the hydrothermal method in order to combine the advantages of Hβ and SAPO-11 for the methylation of naphthalene with methanol. For comparison, the mechanical mixture was prepared through the blending of Hβ and SAPO-11. The physicochemical properties of Hβ, SAPO-11, the composite and the mechanical mixture were characterized by various characterization methods. The characterization results indicated that Hβ/SAPO-11 composite molecular sieve exhibited a core-shell structure, with the Hβ phase as the core and the SAPO-11 phase as the shell. The pore diameter of the composite was between that of Hβ and SAPO-11. The composite had fewer acid sites than Hβ and mechanical mixture while more acid sites than SAPO-11. The experimental results indicated that the composite exhibited high catalytic performances for the methylation of naphthalene with methanol

  18. Bistable near field and bistable transmittance in 2D composite slab consisting of nonlocal core-Kerr shell inclusions.

    Science.gov (United States)

    Huang, Yang; Wu, Ya Min; Gao, Lei

    2017-01-23

    We carry out a theoretical study on optical bistability of near field intensity and transmittance in two-dimensional nonlinear composite slab. This kind of 2D composite is composed of nonlocal metal/Kerr-type dielectric core-shell inclusions randomly embedded in the host medium, and we derivate the nonlinear relation between the field intensity in the shell of inclusions and the incident field intensity with self-consistent mean field approximation. Numerical demonstration has been performed to show the viable parameter space for the bistable near field. We show that nonlocality can provide broader region in geometric parameter space for bistable near field as well as bistable transmittance of the nonlocal composite slab compared to local case. Furthermore, we investigate the bistable transmittance in wavelength spectrum, and find that besides the input intensity, the wavelength operation could as well make the transmittance jump from a high value to a low one. This kind of self-tunable nano-composite slab might have potential application in optical switching devices.

  19. Leidenfrost phenomenon on conical surfaces

    Science.gov (United States)

    Hidalgo-Caballero, S.; Escobar-Ortega, Y.; Pacheco-Vázquez, F.

    2016-09-01

    The Leidenfrost state is typically studied by placing droplets on flat or slightly curved surfaces. Here this phenomenon is investigated by depositing water in hot conical bowls. We found that this phase exists even for large amounts of liquid in very narrow cones without considerable effect of the confinement on the Leidenfrost transition temperature TL. At a fixed temperature, T >TL , the total evaporation time τ has a nonmonotonic dependence on the angle of confinement θ : for large volumes (˜20 ml) on flat surfaces (θ ˜0∘ ), vapor chimneys appear and accelerate the evaporation rate, their frequency diminishes as θ augments and becomes zero at a certain angle θc, at which τ reaches its maximum value; then, τ decreases again at larger angles because the vapor layer holding up the water becomes thinner due to the increase of hydrostatic pressure and because the geometry facilitates the vapor expulsion along the conical wall. For small volumes (˜1 ml), surface tension mainly determines the drop curvature and the lifetime is practically independent of θ . Different chimney regimes and oscillation patterns were observed and summarized in a phase diagram. Finally, we developed a simple model to decipher the shape adopted by the liquid volume and its evolution as a function of time, and the predictions are in good agreement with the experimental results.

  20. Investigation of Tribological Behavior of a Novel Hybrid Composite Prepared with Al-Coconut Shell Ash Mixed with Graphite

    Science.gov (United States)

    Siva Sankara Raju, R.; Panigrahi, M. K.; Ganguly, R. I.; Srinivasa Rao, G.

    2017-08-01

    The present investigation develops a next-generation hybrid Al metal matrix composite using coconut shell ash (CSA) and graphite (Gr) reinforcement. Stir-casting is adapted to prepare an Al-1100-based composite. Three other composites of Al-Al2O3, Al-Al2O3-Gr, and Al-CSA are prepared that contain equivalent volume fractions of Al2O3, CSA, and Gr. These assist in comparisons among the three composites and the developed hybrid Al-CSA-Gr composite. The study reveals that the addition of 3 pct Gr improves the specific strength, toughness, and tribological properties. The Al-CSA composite shows better mechanical properties, such as tensile strength and hardness, than the other three composites. Gr addition helps the hybrid Al-CSA-Gr composite to attain better tribological properties with a slightly lower specific strength. Scanning electron microscopy studies of the worn material surfaces corroborate the findings of the abrasion testing. Elemental analyses by energy-dispersive X-ray spectroscopy of the debris from the counter-face of the tribo surface confirm the presence of Al, O, Si, Fe, Mn, and C.

  1. Factors controlling shell carbon isotopic composition of land snail Acusta despecta sieboldiana estimated from lab culturing experiment

    Science.gov (United States)

    Zhang, N.; Yamada, K.; Suzuki, N.; Yoshida, N.

    2014-05-01

    The carbon isotopic composition (δ13C) of land snail shell carbonate derives from three potential sources: diet, atmospheric CO2, and ingested carbonate (limestone). However, their relative contributions remain unclear. Under various environmental conditions, we cultured one land snail species, Acusta despecta sieboldiana collected from Yokohama, Japan, and confirmed that all of these sources affect shell carbonate δ13C values. Herein, we consider the influences of metabolic rates and temperature on the carbon isotopic composition of the shell carbonate. Based on previous works and on results obtained in this study, a simple but credible framework is presented for discussion of how each source and environmental parameter can affect shell carbonate δ13C values. According to this framework and some reasonable assumptions, we have estimated the contributions of different carbon sources for each snail individual: for cabbage (C3 plant) fed groups, the contributions of diet, atmospheric CO2 and ingested limestone respectively vary as 66-80%, 16-24%, and 0-13%. For corn (C4 plant) fed groups, because of the possible food stress (lower consumption ability of C4 plant), the values vary respectively as 56-64%, 18-20%, and 16-26%. Moreover, we present new evidence that snails have discrimination to choose C3 and C4 plants as food. Therefore, we suggest that food preferences must be considered adequately when applying δ13C in paleo-environment studies. Finally, we inferred that, during egg laying and hatching of our cultured snails, carbon isotope fractionation is controlled only by the isotopic exchange of the calcite-HCO3--aragonite equilibrium.

  2. Factors controlling shell carbon isotopic composition of land snail Acusta despecta sieboldiana estimated from laboratory culturing experiment

    Science.gov (United States)

    Zhang, N.; Yamada, K.; Suzuki, N.; Yoshida, N.

    2014-10-01

    The carbon isotopic composition (δ13C) of land snail shell carbonate derives from three potential sources: diet, atmospheric CO2, and ingested carbonate (limestone). However, their relative contributions remain unclear. Under various environmental conditions, we cultured one land snail subspecies, Acusta despecta sieboldiana, collected from Yokohama, Japan, and confirmed that all of these sources affect shell carbonate δ13C values. Herein, we consider the influences of metabolic rates and temperature on the carbon isotopic composition of the shell carbonate. Based on results obtained from previous works and this study, a simple but credible framework is presented to illustrate how each source and environmental parameter affects shell carbonate δ13C values. According to this framework and some reasonable assumptions, we estimated the contributions of different carbon sources for each snail individual: for cabbage-fed (C3 plant) groups, the contributions of diet, atmospheric CO2, and ingested limestone vary in the ranges of 66-80, 16-24, and 0-13%, respectively. For corn-fed (C4 plant) groups, because of the possible food stress (less ability to consume C4 plants), the values vary in the ranges of 56-64, 18-20, and 16-26%, respectively. Moreover, according to the literature and our observations, the subspecies we cultured in this study show preferences towards different plant species for food. Therefore, we suggest that the potential food preference should be considered adequately for some species in paleoenvironment studies. Finally, we inferred that only the isotopic exchange of the calcite-HCO3--aragonite equilibrium during egg laying and hatching of our cultured snails controls carbon isotope fractionation.

  3. Composite cement mortars based on marine sediments and oyster shell powder

    Directory of Open Access Journals (Sweden)

    Ez-zaki, H.

    2016-03-01

    Full Text Available Additions of dredged marine sediments and oyster shell powder (OS as cement substitute materials in mortars are examined by several techniques. The sediments have high water and chloride contents and calcite, quartz, illite and kaolinite as principal minerals. The OS powders are entirely composed of calcium carbonate and traces of other impurities. Four mixtures of treated sediments and OS powders at 650 °C and 850 °C are added to Portland cement at 8%, 16% and 33% by weight. The hydration of composite pastes is followed by calorimetric tests, the porosity accessible to water, the bulk density, the permeability to gas, the compressive strength and the accelerated carbonation resistance are measured. In general, the increase of addition amounts reduced the performance of mortars. However, a reduction of gas permeability was observed when the addition was up to 33%. Around 16% of addition, the compressive strength and carbonation resistance were improved.En este trabajo se ha valorado la sustitución de cemento en morteros por sedimentos marinos dragados y polvo de concha de ostra (OS. Los sedimentos tienen altos contenidos de agua, cloruros, calcita, cuarzo, illita y caolinita como minerales principales. Los polvos OS están compuestos de carbonato cálcico y trazas de otras impurezas. Se añadieron a un cemento Portland, cuatro mezclas de los sedimentos y polvos de OS tratados a 650 °C y 850 °C en proporciones del 8%, 16% y 33% en peso. La hidratación de pastas se estudió a través de calorimetría. Se estudió además la porosidad accesible al agua, densidad aparente, permeabilidad al gas, resistencia a compresión y carbonatación acelerada. En general, un aumento en la adición produjo una reducción del rendimiento de los morteros. Se observó, sin embargo, una reducción de la permeabilidad a los gases con porcentajes de adición de hasta el 33%. Con valores del 16% de sustitución, mejoraron las resistencias mecánicas y la

  4. The microwave properties of composites including lightweight core–shell ellipsoids

    International Nuclear Information System (INIS)

    Yuan, Liming; Xu, Yonggang; Dai, Fei; Liao, Yi; Zhang, Deyuan

    2016-01-01

    In order to study the microwave properties of suspensions including lightweight core–shell ellipsoids, the calculation formula was obtained by substituting an equivalent ellipsoid for the original core–shell ellipsoid. Simulations for Fe-coated diatomite/paraffin suspensions were performed. Results reveal that the calculated results fitted the measured results very well when the inclusion concentration was no more than 15 vol%, but there was an obvious deviation when the inclusion concentration reached 24 vol%. By comparisons, the formula for less diluted suspensions was more suitable for calculating the electromagnetic parameter of suspensions especially when the ratio was smaller between the electromagnetic parameter of the inclusion and that of the host medium. - Highlights: • The microwave properties of suspensions with core-shell inclusions were studied. • Less diluted suspensions were considered. • Flaky Fe-coated diatomite/paraffin suspensions were studied. • The microwave properties could be simulated successfully.

  5. The microwave properties of composites including lightweight core–shell ellipsoids

    Energy Technology Data Exchange (ETDEWEB)

    Yuan, Liming, E-mail: lming_y@163.com [Science and Technology on Electromagnetic Scattering Laboratory, Shanghai 200438 (China); Xu, Yonggang; Dai, Fei; Liao, Yi [Science and Technology on Electromagnetic Scattering Laboratory, Shanghai 200438 (China); Zhang, Deyuan [School of Mechanical Engineering and Automation, Beihang University, Beijing 100191 (China)

    2016-12-01

    In order to study the microwave properties of suspensions including lightweight core–shell ellipsoids, the calculation formula was obtained by substituting an equivalent ellipsoid for the original core–shell ellipsoid. Simulations for Fe-coated diatomite/paraffin suspensions were performed. Results reveal that the calculated results fitted the measured results very well when the inclusion concentration was no more than 15 vol%, but there was an obvious deviation when the inclusion concentration reached 24 vol%. By comparisons, the formula for less diluted suspensions was more suitable for calculating the electromagnetic parameter of suspensions especially when the ratio was smaller between the electromagnetic parameter of the inclusion and that of the host medium. - Highlights: • The microwave properties of suspensions with core-shell inclusions were studied. • Less diluted suspensions were considered. • Flaky Fe-coated diatomite/paraffin suspensions were studied. • The microwave properties could be simulated successfully.

  6. The partial replacement of palm kernel shell by carbon black and halloysite nanotubes as fillers in natural rubber composites

    Science.gov (United States)

    Daud, Shuhairiah; Ismail, Hanafi; Bakar, Azhar Abu

    2017-07-01

    The effect of partial replacement of palm kernel shell powder by carbon black (CB) and halloysite nanotube (HNT) on the tensile properties, rubber-filler interaction, thermal properties and morphological studies of natural rubber (NR) composites were investigated. Four different compositions of NR/PKS/CB and NR/PKS/HNT composites i.e 20/0, 15/5, 10/10,5/15 and 0/20 parts per hundred rubber (phr) were prepared on a two roll mill. The results showed that the tensile strength and modulus at 100% elongation (M100) and 300% elongation (M300) were higher for NR/PKS/CB compared to NR/PKS/HNT composites. NR/PKS/CB composites had the lowest elongation at break (Eb). The effect of commercial fillers in NR/PKS composites on tensile properties was confirmed by the rubber-filler interaction and scanning electron microscopy (SEM) study. The thermal stability of PKS filled NR composites with partially replaced by commercial fillers also determined by Thermo gravimetric Analysis (TGA).

  7. Core-shell Ni0.5TiOPO4/C composites as anode materials in Li ion batteries

    International Nuclear Information System (INIS)

    Zhang, X.J.; Zhang, Y.; Zhou, Z.; Wei, J.P.; Essehli, R.; Bali, B. El

    2011-01-01

    Pristine Ni 0.5 TiOPO 4 was prepared via a traditional solid-state reaction, and then Ni 0.5 TiOPO 4 /C composites with core-shell nanostructures were synthesized by hydrothermally treating Ni 0.5 TiOPO 4 in glucose solution. X-ray diffraction patterns indicate that Ni 0.5 TiOPO 4 /C crystallizes in monoclinic P2 1 /c space group. Scanning electron microscopy and transmission electron microscopy show that the small particles with different sizes are coated with uniform carbon film of ∼3 nm in thickness. Raman spectroscopy also confirms the presence of carbon in the composites. Ni 0.5 TiOPO 4 /C composites presented a capacity of 276 mAh g -1 after 30 cycles at the current density of 42.7 mA g -1 , much higher than that of pristine Ni 0.5 TiOPO 4 (155 mAh g -1 ). The improved electrochemical performances can be attributed to the existence of carbon shell.

  8. Synthesis, characterization and nitrite ion sensing performance of reclaimable composite samples through a core-shell structure

    Science.gov (United States)

    Cui, Xiao; Yuqing, Zhao; Cui, Jiantao; Zheng, Qian; Bo, Wang

    2018-02-01

    The following paper reported and discussed a nitrite ion optical sensing platform based on a core-shell structure, using superamagnetic nanoparticles as the core, a silica molecular sieve MCM-41 as the shell and two rhodamine derivatives as probe, respectively. This superamagnetic core made this sensing platform reclaimable after finishing nitrite ion sensing procedure. This sensing platform was carefully characterized by means of electron microscopy images, porous structure analysis, magnetic response, IR spectra and thermal stability analysis. Detailed analysis suggested that the emission of these composite samples was quenchable by nitrite ion, showing emission turn off effect. A static sensing mechanism based on an additive reaction between chemosensors and nitrite ion was proposed. These composite samples followed Demas quenching equation against different nitrite ion concentrations. Limit of detection value was obtained as low as 0.4 μM. It was found that, after being quenched by nitrite ion, these composite samples could be reclaimed and recovered by sulphamic acid, confirming their recyclability.

  9. An high order Mixed Interpolation Tensorial Components (MITC) shell element approach for modeling the buckling behavior of delaminated composites

    DEFF Research Database (Denmark)

    Gaiotti, Marco; Rizzo, Cesare M.; Branner, Kim

    2014-01-01

    This paper describes the experimental and numerical studies carried out on delaminated fiberglass epoxy resin laminates made-up by different fabrication methods, namely by vacuum infusion and prepreg. While the tested specimens were originally intended for the assessment of buckling behavior...... of composite laminates of wind turbine blades, results were found valuable for the marine industry as well, because similar laminates are used for the hull shell and stiffeners. Systematic calculations were carried out to assess the effects of an embedded delamination on the buckling load, varying the size...

  10. Hydrazine-Assisted Formation of Indium Phosphide (InP)-Based Nanowires and Core-Shell Composites.

    Science.gov (United States)

    Patzke, Greta R; Kontic, Roman; Shiolashvili, Zeinab; Makhatadze, Nino; Jishiashvili, David

    2012-12-27

    Indium phosphide nanowires (InP NWs) are accessible at 440 °C from a novel vapor phase deposition approach from crystalline InP sources in hydrazine atmospheres containing 3 mol % H₂O. Uniform zinc blende (ZB) InP NWs with diameters around 20 nm and lengths up to several tens of micrometers are preferably deposited on Si substrates. InP particle sizes further increase with the deposition temperature. The straightforward protocol was extended on the one-step formation of new core-shell InP-Ga NWs from mixed InP/Ga source materials. Composite nanocables with diameters below 20 nm and shells of amorphous gallium oxide are obtained at low deposition temperatures around 350 °C. Furthermore, InP/Zn sources afford InP NWs with amorphous Zn/P/O-coatings at slightly higher temperatures (400 °C) from analogous setups. At 450 °C, the smooth outer layer of InP-Zn NWs is transformed into bead-shaped coatings. The novel combinations of the key semiconductor InP with isotropic insulator shell materials open up interesting application perspectives in nanoelectronics.

  11. Fabrication of hierarchical core-shell polydopamine@MgAl-LDHs composites for the efficient enrichment of radionuclides

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Kairuo [Key Laboratory of Novel Thin Film Solar Cells, Institute of Plasma Physics, Chinese Academy Sciences, P.O. Box 1126, Hefei, 230031 (China); Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Soochow University, Suzhou, 215123 (China); Lu, Songhua; Gao, Yang; Zhang, Rui; Tan, Xiaoli [Key Laboratory of Novel Thin Film Solar Cells, Institute of Plasma Physics, Chinese Academy Sciences, P.O. Box 1126, Hefei, 230031 (China); Chen, Changlun, E-mail: clchen@ipp.ac.cn [Key Laboratory of Novel Thin Film Solar Cells, Institute of Plasma Physics, Chinese Academy Sciences, P.O. Box 1126, Hefei, 230031 (China); Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Soochow University, Suzhou, 215123 (China); AAM Research Group, Faculty of Science, King Abdulaziz University, Jeddah 21589 (Saudi Arabia)

    2017-02-28

    Highlights: • Novel hierarchical core/shell structured PDA@MgAl-LDHs were prepared. • PDA@MgAl-LDHs exhibited higher sorption ability for U(VI) and Eu(III). • PDA@MgAl-LDHs were promising materials for the enrichment of radionuclides. - Abstract: Novel hierarchical core/shell structured polydopamine@MgAl-layered double hydroxides (PDA@MgAl-LDHs) composites involving MgAl-layered double hydroxide shells and PDA cores were fabricated thought one-pot coprecipitation assembly and methodically characterized by X-ray diffraction, Fourier transformed infrared spectroscopy, scanning/transmission electron microscopy, selected area electron diffraction, elemental mapping, thermogravimetric analysis and X-ray photoelectron spectroscopy technologies. U(VI) and Eu(III) sorption experiments showed that the PDA@MgAl-LDHs exhibited higher sorption ability with a maximum sorption capacity of 142.86 and 76.02 mg/g at 298 K and pH 4.5, respectively. More importantly, according to XPS analyses, U(VI) and Eu(III) were sorbed on PDA@MgAl-LDHs via oxygen-containing functional groups, and the chemical affinity of U(VI) by oxygen-containing functional groups is higher than that of Eu(III). These observations show great expectations in the enrichment of radionuclides from aquatic environments by PDA@MgAl-LDHs.

  12. The effect of palm kernel shell ash on the mechanical properties of as-cast aluminium alloy matrix composites

    Directory of Open Access Journals (Sweden)

    Isiaka Oluwole OLADELE

    2016-06-01

    Full Text Available The present work describes the effect of palm kernel shell ash (PKSA as reinforcement on the mechanical properties of As-cast aluminium alloy. Recycled aluminium alloy from cylinder of an automotive engine block was degreased by using premium motor spirit (PMS also known as petrol, washed thoroughly with soap and water and sun dried for 5 days. The palm kernel shell was screened of dirt and other unwanted foreign materials before being roasted in furnace. The ash was further pulverized by laboratory ball mill machine followed by sieving to obtain particle sizes of 106 µm and divided into two parts. One portion was treated with NaOH solution while the other part was left as untreated before they are used to reinforced molten aluminium alloy in predetermined proportions. The newly developed composites were characterized with respect to their mechanical properties in response to the tests that were carried out on them. The results indicate that palm kernel shell ash can be used as potential reinforcing material for automobile applications.

  13. Mechanical and thermal properties of bio-composites based on polypropylene reinforced with Nut-shells of Argan particles

    International Nuclear Information System (INIS)

    Essabir, H.; Hilali, E.; Elgharad, A.; El Minor, H.; Imad, A.; Elamraoui, A.; Al Gaoudi, O.

    2013-01-01

    Highlights: ► Nuts-shells of Argan particles are used as reinforcement in thermoplastic matrix. ► Particles are homogeneously dispersed and distributed within PP matrix. ► Mechanical and thermal characterization of the composite are applied. ► Particles–matrix adhesion was assured by the use of a SBS compatibilizer. - Abstract: This study treats the combined effects of both particle sizes and particle loading on the mechanical and thermal properties of polypropylene (PP) composites reinforced with Nut-shells of Argan (NA) particles. Three range sizes of particles were used in the presence of a polypropylene matrix grafted with 8 wt.% of a linear block copolymer based on styrene and butadiene coupling agent, to improve adhesion between the particles and the matrix. The composites were prepared through melt-blending using an internal mixer and the tensile specimens were prepared using a hot press molding machine. Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FT-IR), Thermo Gravimetric Analysis (TGA), Differential Thermal Analysis (DTA) and tensile tests were employed to characterize the composites at 10, 15, 20 and 25 wt.% particle contents. Results show a clear improvement in Young’s modulus from the use of particles when compared to the neat PP, a gain of 42.65%, 26.7% and 2.9% at 20 wt.% particle loading, for particle range 1, 2 and 3, respectively. In addition a notable increase in the Young’s modulus was observed when decrease the particle size. The thermal stability of composites exhibits a slight decrease (256–230 °C) with particles loading from 10 to 25 wt.%, against neat PP (258 °C)

  14. Microwave electromagnetic and absorption properties of SiO2/C core/shell composites plated with metal cobalt

    Science.gov (United States)

    Shen, Guozhu; Fang, Xumin; Wu, Hongyan; Wei, Hongyu; Li, Jingfa; Li, Kaipeng; Mei, Buqing; Xu, Yewen

    2017-04-01

    A facile method has been developed to fabricate magnetic core/shell SiO2/C/Co sub-microspheres via the pyrolysis of SiO2/PANI (polyaniline) and electroless plating method. The electromagnetic parameters of these SiO2/C and SiO2/C/Co composites were measured and the microwave reflection loss properties were evaluated in the frequency range of 2-18 GHz. The results show that the dielectric loss of SiO2/C composite increases with the increase of carbonization temperature and the magnetic loss enhances due to the deposition of cobalt on the SiO2/C sub-microspheres. The reflection loss results exhibit that the microwave absorption properties of the SiO2/C/Co composites are more excellent than those of SiO2/C composites for each thickness. The maximum effective absorption bandwidth (reflection loss ≤ -10 dB) arrives at 5.0 GHz (13.0-18 GHz) for SiO2/C/Co composite with 1.5 mm of thickness and the minimum reflection loss value is -24.0 dB at 5.0 GHz with 4.0 mm of thickness. The microwave loss mechanism of the SiO2/C/Co composites was also discussed in this paper.

  15. Development of core-shell coaxially electrospun composite PCL/chitosan scaffolds.

    Science.gov (United States)

    Surucu, Seda; Turkoglu Sasmazel, Hilal

    2016-11-01

    This study was related to combining of synthetic Poly (ε-caprolactone) (PCL) and natural chitosan polymers to develop three dimensional (3D) PCL/chitosan core-shell scaffolds for tissue engineering applications. The scaffolds were fabricated with coaxial electrospinning technique and the characterizations of the samples were done by thickness and contact angle (CA) measurements, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-Ray Photoelectron Spectroscopy (XPS) analyses, mechanical and PBS absorption and shrinkage tests. The average inter-fiber diameter values were calculated for PCL (0.717±0.001μm), chitosan (0.660±0.007μm) and PCL/chitosan core-shell scaffolds (0.412±0.003μm), also the average inter-fiber pore size values exhibited decreases of 66.91% and 61.90% for the PCL and chitosan scaffolds respectively, compared to PCL/chitosan core-shell ones. XPS analysis of the PCL/chitosan core-shell structures exhibited the characteristic peaks of PCL and chitosan polymers. The cell culture studies (MTT assay, Confocal Laser Scanning Microscope (CLSM) and SEM analyses) carried out with L929 ATCC CCL-1 mouse fibroblast cell line proved that the biocompatibility performance of the scaffolds. The obtained results showed that the created micro/nano fibrous structure of the PCL/chitosan core-shell scaffolds in this study increased the cell viability and proliferation on/within scaffolds. Copyright © 2016 Elsevier B.V. All rights reserved.

  16. Nano-sized LiFePO4/C composite with core-shell structure as cathode material for lithium ion battery

    International Nuclear Information System (INIS)

    Liu, Yang; Zhang, Min; Li, Ying; Hu, Yemin; Zhu, Mingyuan; Jin, Hongming; Li, Wenxian

    2015-01-01

    Graphical abstract: Nano-sized LiFePO4/C composite with core-shell structure was fabricated via a well-designed approach as cathode material forlithium ion battery. The nano-sized LiFePO4/C composite with whole carbon shell coating layer showed an excellent electrical performance. - Abstract: Nano-sized composite with LiFePO 4 -core and carbon-shell was synthesized via a facile route followed by heat treatment at 650 °C. X-ray diffraction (XRD) shows that the core is well crystallized LiFePO 4 . The electron microscopy (SEM and TEM) observations show that the core-shell structured LiFePO 4 /C composite coating with whole carbon shell layer of ∼2.8 nm, possesses a specific surface area of 51 m 2 g −1 . As cathode material for lithium ion battery, the core-shell LiFePO 4 /C composite exhibits high initial capacity of 161 mAh g −1 at 0.1 C, excellent high-rate discharge capacity of 135 mAh g −1 at 5 C and perfect cycling retention of 99.6% at 100 th cycle. All these promising results should be contributed to the core-shell nanostructure which prevents collapse of the particle structure in the long-term charge and discharge cycles, as well as the large surface area of the nano-sized LiFePO 4 /C composite which enhances the electronic conductivity and shortens the distance of lithium ion diffusion

  17. Effect of Hybrid Talc-Basalt Fillers in the Shell Layer on Thermal and Mechanical Performance of Co-Extruded Wood Plastic Composites.

    Science.gov (United States)

    Huang, Runzhou; Mei, Changtong; Xu, Xinwu; Kärki, Timo; Lee, Sunyoung; Wu, Qinglin

    2015-12-08

    Hybrid basalt fiber (BF) and Talc filled high density polyethylene (HDPE) and co-extruded wood-plastic composites (WPCs) with different BF/Talc/HDPE composition levels in the shell were prepared and their mechanical, morphological and thermal properties were characterized. Incorporating BFs into the HDPE-Talc composite substantially enhanced the thermal expansion property, flexural, tensile and dynamic modulus without causing a significant decrease in the tensile and impact strength of the composites. Strain energy estimation suggested positive and better interfacial interactions of HDPE with BFs than that with talc. The co-extruded structure design improved the mechanical properties of WPC due to the protective shell layer. The composite flexural and impact strength properties increased, and the thermal expansion decreased as BF content increased in the hybrid BF/Talc filled shells. The cone calorimetry data demonstrated that flame resistance of co-extruded WPCs was improved with the use of combined fillers in the shell layer, especially with increased loading of BFs. The combined shell filler system with BFs and Talc could offer a balance between cost and performance for co-extruded WPCs.

  18. Effect of filler loading and silane modification on the biodegradability of SBR composites reinforced with peanut shell powder

    Science.gov (United States)

    Shaniba, V.; Balan, Aparna K.; Sreejith, M. P.; Jinitha, T. V.; Subair, N.; Purushothaman, E.

    2017-06-01

    The development of biocomposites and their applications are important in material science due to environmental and sustainability issues. The extent of degradation depends on the nature of reinforcing filler, particle size and their modification. In this article, we tried to focus on the biodegradation of composites of Styrene Butadiene Rubber (SBR) reinforced with Peanut Shell Powder (PSP) by soil burial test. The composites of SBR with untreated PSP (UPSP) and silane modified PSP (SPSP) of 10 parts per hundred rubber (phr) and 20 phr filler loading in two particle size were buried in the garden soil for six months. The microbial degradation were assessed through the measurement of weight loss, tensile strength and hardness at definite period. The study shows that degradation increases with increase in filler loading and particle size. The chemical treatment of filler has been found to resist the degradation. The analysis of morphological properties by the SEM also confirmed biodegradation process by the microorganism in the soil.

  19. The influence of some factors on the electrical conductivity and particle size of core/shell polystyrene/polyaniline composites

    Directory of Open Access Journals (Sweden)

    GORDANA D. NESTOROVIC

    2005-11-01

    Full Text Available The electrically conductive, micron-sized, core/shell polystyrene (PS/polyaniline (PANI composite particles were synthesized by chemical oxidative polymerization of aniline in the presence of micron-sized PS particles in 1 M HCl. The conditions of the dispersion polymerization of styrene were optimized. The influence of the initiator type employed for the chemical oxidative polymerization of aniline and the aniline (ANI concentration on the PS/PANI particle size and size distribution and their conductivity was investigated. The obtained results show that the conductivity of the samples increased with increasing ANI concentration. The conductivity of the PS/PANI composite particles obtained with the highest ANI concentration was of the same order of magnitude as that for PANI powder. The particle size did not depend on the concentration of ANI, while the particle size distribution was narrower at higher concentrations of ANI.

  20. Preparation of N-Doped Composite Shell Encapsulated Iron Nanoparticles and Their Magnetic, Adsorptive, and Photocatalytic Properties

    Directory of Open Access Journals (Sweden)

    Caijing Shi

    2017-01-01

    Full Text Available The N-doped composite shell encapsulated iron nanoparticles (CSEINPs were prepared by DC arc discharge under nitrogen at 800°C, using the anode with high Fe content and good homogeneity. The morphology, microstructure, composition, and some properties of the N-doped CSEINPs were characterized by various characterization techniques. The results revealed that the shells of the N-doped CSEINPs were composed of homogeneously amorphous structure containing C, Fe, O, and N elements; the saturation magnetization (Ms and coercivity (Hc of them at room temperature were 130 emu/g and 194 Oe, respectively. Due to the surface structure and the electrostatic interaction, the N-doped CSEINPs are employed to remove methylene blue (MB from the waste solution, and they exhibited high adsorption properties and photocatalytic activity under irradiation of visible light (IVL. The kinetics of adsorption of MB on the N-doped CSEINPs was investigated and the recycling test was carried out. The formation mechanism of the N-doped CSEINPs is discussed briefly.

  1. Soft tissue modelling with conical springs.

    Science.gov (United States)

    Omar, Nadzeri; Zhong, Yongmin; Jazar, Reza N; Subic, Aleksandar; Smith, Julian; Shirinzadeh, Bijan

    2015-01-01

    This paper presents a new method for real-time modelling soft tissue deformation. It improves the traditional mass-spring model with conical springs to deal with nonlinear mechanical behaviours of soft tissues. A conical spring model is developed to predict soft tissue deformation with reference to deformation patterns. The model parameters are formulated according to tissue deformation patterns and the nonlinear behaviours of soft tissues are modelled with the stiffness variation of conical spring. Experimental results show that the proposed method can describe different tissue deformation patterns using one single equation and also exhibit the typical mechanical behaviours of soft tissues.

  2. Copper Ferrocyanide Functionalized Core-Shell Magnetic Silica Composites for the Selective Removal of Cesium Ions from Radioactive Liquid Waste.

    Science.gov (United States)

    Lee, Hyun Kyu; Yang, Da Som; Oh, Wonzin; Choi, Sang-June

    2016-06-01

    The copper ferrocyanide functionalized core-shell magnetic silica composite (mag@silica-CuFC) was prepared and was found to be easily separated from aqueous solutions by using magnetic field. The synthesized mag@silica-CuFC composite has a high sorption ability of Cs owing to its strong affinity for Cs as well as the high surface area of the supports. Cs sorption on the mag@silica-CuFC composite quickly reached the sorption equilibrium after 2 h of contact time. The effect of the presence of salts with a high concentration of up to 3.5 wt% on the efficiency of Cs sorption onto the composites was also studied. The maximum sorption ability was found to be maintained in the presence of up to 3.5 wt% of NaCl in the solution. Considering these results, the mag@silica-CuFC composite has great potential for use as an effective sorbent for the selective removal of radioactive Cs ions.

  3. Effect of electron beam irradiation on mechanical properties of gelatin/Brazil nut shell fiber composites

    International Nuclear Information System (INIS)

    Inamura, Patricia Y.; Shimazaki, Kleber; Moura, Esperidiana Augusta Barretos de; Mastro, Nelida L. del; Colombo, Maria Aparecida; Rosa, Ricardo de

    2010-01-01

    The use of natural fiber as polymeric matrix reinforcement has attracted interest, as fibers are renewable, of low cost, biodegradable and possesses non-toxic properties. In the present paper, Brazil nuts (Bertholletia excelsa) shell fiber (10% w/w) were mixed with gelatin (25% w/w), glycerin as plasticizer and acrylamide as copolymer to investigate the resultant mechanical properties effects upon ionizing radiation. The samples were irradiated at 40 kGy using a Dynamitron electron beam accelerator, at room temperature in the presence of air. The results showed that samples of gelatin with 10% of Brazil nuts shell fiber and irradiated at 40 kGy presented promising results for mechanical performance. (author)

  4. Design and analysis of reactor containment of steel-concrete composite laminated shell

    International Nuclear Information System (INIS)

    Ichikawa, K.

    1977-01-01

    Reinforced and prestressed concrete containments for reactors have been developed in order to avoid the difficulties of welding of steel containments encountered as their capacities have become large: growing thickness of steel shells gave rise to the requirement of stress relief at the construction sites. However, these concrete vessels also seem to face another difficulty: the lack of shearing resistance capacity. In order to improve the shearing resistance capacity of the containment vessel, while avoiding the difficulty of welding, a new scheme of containment consisting of steel-concrete laminated shell is being developed. In the main part of a cylindrical vessel, the shell consists of two layers of thin steel plates located at the inner and outer surfaces, and a layer of concrete core into which both the steel plates are anchored. In order to validate the feasibility and safety of this new design, the results of analysis on the basis of up-to-date design loads are presented. The results of model tests in 1:30 scale are also reported. (Auth.)

  5. Handbook on semidefinite, conic and polynomial optimization

    CERN Document Server

    Anjos, Miguel F

    2012-01-01

    This book offers the reader a snapshot of the state-of-the-art in the growing and mutually enriching areas of semidefinite optimization, conic optimization and polynomial optimization. It covers theory, algorithms, software and applications.

  6. Controlling nanowire emission profile using conical taper

    DEFF Research Database (Denmark)

    Gregersen, Niels; Nielsen, Torben Roland; Mørk, Jesper

    2008-01-01

    The influence of a conical taper on nanowire light emission is studied. For nanowires with divergent output beams, the introduction of tapers improves the emission profile and increase the collection efficiency of the detection optics....

  7. Covered by lines and Conic connected varieties

    Directory of Open Access Journals (Sweden)

    Alex Massarenti

    2011-12-01

    Full Text Available We study some properties of an embedded variety covered by lines and give a numerical criterion ensuring the existence of a singular conic through two of its general points. We show that our criterion is sharp. Conic-connected, covered by lines, QEL, LQEL, prime Fano, defective, and dual defective varieties are closely related. We study some relations between the above mentioned classes of objects using basic results by Ein and Zak.

  8. Geometrically nonlinear transient vibrations of actively damped anti-symmetric angle ply laminated composite shallow shell using active fibre composite (AFC) actuators

    Science.gov (United States)

    Ashok, M. H.; Shivakumar, J.; Nandurkar, Santosh; Khadakbhavi, Vishwanath; Pujari, Sanjay

    2018-02-01

    In present work, the thin laminated composite shallow shell as smart structure with AFC material’s ACLD treatment is analyzed for geometrically nonlinear transient vibrations. The AFC material is used to make the constraining layer of the ACLD treatment. Golla-Hughes-McTavish (GHM) is used to model the constrained viscoelastic layer of the ACLD treatment in time domain. Along with a simple first-order shear deformation theory the Von Kármán type non-linear strain displacement relations are used for deriving this electromechanical coupled problem. A 3-dimensional finite element model of smart composite panels integrated with the ACLD treated patches has been modelled to reveal the performance of ACLD treated patches on improving the damping properties of slender anti-symmetric angle-ply laminated shallow shell, in controlling the transient vibrations which are geometrically nonlinear. The mathematical results explain that the ACLD treated patches considerably enhance the damping properties of anti-symmetric angle-ply panels undergoing geometrically nonlinear transient vibrations.

  9. Watching Electrons at Conical Intersections and Funnels

    Science.gov (United States)

    Jonas, David M.; Smith, Eric R.; Peters, William K.; Kitney, Katherine A.

    2009-06-01

    The electronic motion at conical intersections and funnels is probed after polarized excitation of aligned electronic wavepackets. The pulses have bandwidth sufficient to observe vibrations mainly through their effect on the electrons. Vibrational symmetry can be identified by the polarization anisotropy of vibrational quantum beats. The polarized transients show signatures of electronic wavepacket motion (due to the energy gaps) and of electron transfer between orbitals (due to the couplings) driven by the conical intersection. For a conical intersection in a four-fold symmetric symmetry silicon naphthalocyanine molecule, electronic motions on a 100 fs timescale are driven by couplings of 1 meV. In the lower symmetry free-base naphthalocyanine, the conical intersection may be missed or missing (conical funnel), and the motions are nearly as rapid, but electronic equilibration is incomplete for red-edge excitation. These experiments probe non-adiabatic electronic dynamics with near-zero nuclear momentum - the electronic motions are determined by the principal slopes of the conical intersection and the width of the vibrational wavepacket.

  10. A High-Order Theory for the Analysis of Circular Cylindrical Composite Sandwich Shells with Transversely Compliant Core Subjected to External Loads

    DEFF Research Database (Denmark)

    Rahmani, Omid; Khalili, S.M.R.; Thomsen, Ole Thybo

    2012-01-01

    A new model based on the high order sandwich panel theory is proposed to study the effect of external loads on the free vibration of circular cylindrical composite sandwich shells with transversely compliant core, including also the calculation of the buckling loads. In the present model......, which is based on a 3D elasticity solution for the core material, can be used as a benchmark in future studies of the free vibration and buckling of circular cylindrical composite sandwich shells with a transversely compliant core....

  11. Tunable thermodynamic stability of Au-CuPt core-shell trimetallic nanoparticles by controlling the alloy composition: insights from atomistic simulations.

    Science.gov (United States)

    Huang, Rao; Shao, Gui-Fang; Wen, Yu-Hua; Sun, Shi-Gang

    2014-11-07

    A microscopic understanding of the thermal stability of metallic core-shell nanoparticles is of importance for their synthesis and ultimately application in catalysis. In this article, molecular dynamics simulations have been employed to investigate the thermodynamic evolution of Au-CuPt core-shell trimetallic nanoparticles with various Cu/Pt ratios during heating processes. Our results show that the thermodynamic stability of these nanoparticles is remarkably enhanced upon rising Pt compositions in the CuPt shell. The melting of all the nanoparticles initiates at surface and gradually spreads into the core. Due to the lattice mismatch among Au, Cu and Pt, stacking faults have been observed in the shell and their numbers are associated with the Cu/Pt ratios. With the increasing temperature, they have reduced continuously for the Cu-dominated shell while more stacking faults have been produced for the Pt-dominated shell because of the significantly different thermal expansion coefficients of the three metals. Beyond the overall melting, all nanoparticles transform into a trimetallic mixing alloy coated by an Au-dominated surface. This work provides a fundamental perspective on the thermodynamic behaviors of trimetallic, even multimetallic, nanoparticles at the atomistic level, indicating that controlling the alloy composition is an effective strategy to realize tunable thermal stability of metallic nanocatalysts.

  12. Optimization of wall thickness and lay-up for the shell-like composite structure loaded by non-uniform pressure field

    Science.gov (United States)

    Shevtsov, S.; Zhilyaev, I.; Oganesyan, P.; Axenov, V.

    2017-01-01

    The glass/carbon fiber composites are widely used in the design of various aircraft and rotorcraft components such as fairings and cowlings, which have predominantly a shell-like geometry and are made of quasi-isotropic laminates. The main requirements to such the composite parts are the specified mechanical stiffness to withstand the non-uniform air pressure at the different flight conditions and reduce a level of noise caused by the airflow-induced vibrations at the constrained weight of the part. The main objective of present study is the optimization of wall thickness and lay-up of composite shell-like cowling. The present approach assumes conversion of the CAD model of the cowling surface to finite element (FE) representation, then its wind tunnel testing simulation at the different orientation of airflow to find the most stressed mode of flight. Numerical solutions of the Reynolds averaged Navier-Stokes (RANS) equations supplemented by k-w turbulence model provide the spatial distributions of air pressure applied to the shell surface. At the formulation of optimization problem the global strain energy calculated within the optimized shell was assumed as the objective. A wall thickness of the shell had to change over its surface to minimize the objective at the constrained weight. We used a parameterization of the problem that assumes an initiation of auxiliary sphere with varied radius and coordinates of the center, which were the design variables. Curve that formed by the intersection of the shell with sphere defined boundary of area, which should be reinforced by local thickening the shell wall. To eliminate a local stress concentration this increment was defined as the smooth function defined on the shell surface. As a result of structural optimization we obtained the thickness of shell's wall distribution, which then was used to design the draping and lay-up of composite prepreg layers. The global strain energy in the optimized cowling was reduced in2

  13. Reinforced PEI/PVdF Multicore-Shell Structure Composite Membranes by Phase Prediction on a Ternary Solution

    Directory of Open Access Journals (Sweden)

    Jihye Chae

    2018-04-01

    Full Text Available To construct a polyetherimide (PEI-reinforced polyvinylidene fluoride (PVdF composite membrane with multicore-shell structure, a ternary solution was prepared and electrospun by single-nozzle electrospinning. A theoretical prediction was made for the feasibility of complete distinction of two phases. The diameters of the membrane fibers and the PEI multi-core fibrils varied with the PEI ratio and the spinning time, respectively. The tensile strength and modulus were improved to 48 MPa and 1.5 GPa, respectively. The shrinkage of the membrane was only 6.6% at 180 °C, at which temperature the commercial PE separator melted down. The reinforcement in mechanical and thermal properties is associated with multiple PEI nanofibrils oriented along the fiber axis. Indeed, the unique morphology of self-assembled multicore-shell fibers plays an important role in their properties. All in all, PEI/PVdF membranes are appropriate for a lithium-ion battery application due to their high mechanical strength, excellent thermal stability, and controllable textural properties.

  14. Surface-biofunctionalized multicore/shell CdTe@SiO2 composite particles for immunofluorescence assay

    Science.gov (United States)

    Jing, Lihong; Li, Yilin; Ding, Ke; Qiao, Ruirui; Rogach, Andrey L.; Gao, Mingyuan

    2011-12-01

    Strongly fluorescent multicore/shell structured CdTe@SiO2 composite particles of ~ 50 nm were synthesized via the reverse microemulsion method by using CdTe quantum dots co-stabilized by thioglycolic acid and thioglycerol. The optical stability of the CdTe@SiO2 composite particles in a wide pH range, under prolonged UV irradiation in pure water, or in different types of physiological buffers was systematically investigated. Towards immunofluorescence assay, both poly(ethylene glycol) (PEG) and carboxyl residues were simultaneously grafted on the surface of the silanol-terminated CdTe@SiO2 composite particles upon further reactions with silane reagents bearing a PEG segment and carboxyl group, respectively, in order to suppress the nonspecific interactions of the silica particles with proteins and meanwhile introduce reactive moieties to the fluorescent particles. Agarose gel electrophoresis, dynamic light scattering and conventional optical spectroscopy were combined to investigate the effectiveness of the surface modifications. Via the surface carboxyl residue, various antibodies were covalently conjugated to the fluorescent particles and the resultant fluorescent probes were used in detecting cancer cells through both direct fluorescent antibody and indirect fluorescent antibody assays, respectively.

  15. Synthesis of composite nanoparticles using co-precipitation of a magnetic iron-oxide shell onto core nanoparticles

    International Nuclear Information System (INIS)

    Primc, Darinka; Belec, Blaž; Makovec, Darko

    2016-01-01

    Composite nanoparticles can be synthesized by coating a shell made of one material onto core nanoparticles made of another material. Here we report on a novel method for coating a magnetic iron oxide onto the surface of core nanoparticles in an aqueous suspension. The method is based on the heterogeneous nucleation of an initial product of Fe"3"+/Fe"2"+ co-precipitation on the core nanoparticles. The close control of the supersaturation of the precipitating species required for an exclusively heterogeneous nucleation and the growth of the shell were achieved by immobilizing the reactive Fe"3"+ ions in a nitrate complex with urea ([Fe((CO(NH_2)_2)_6](NO_3)_3) and by using solid Mg(OH)_2 as the precipitating reagent. The slow thermal decomposition of the complex at 60 °C homogeneously releases the reactive Fe"3"+ ions into the suspension of the core nanoparticles. The key stage of the process is the thermal hydrolysis of the released Fe"3"+ ions prior to the addition of Mg(OH)_2. The thermal hydrolysis results in the formation of γ-FeOOH, exclusively at the surfaces of the core nanoparticles. After the addition of the solid hydroxide Mg(OH)_2, the pH increases and at pH ~ 5.7 the Fe"2"+ precipitates and reacts with the γ-FeOOH to form magnetic iron oxide with a spinel structure (spinel ferrite) at the surfaces of the core nanoparticles. The proposed low-temperature method for the synthesis of composite nanoparticles is capable of forming well-defined interfaces between the two components, important for the coupling of the different properties. The procedure is environmentally friendly, inexpensive, and appropriate for scaling up to mass production.Graphical abstract

  16. Synthesis and magnetic properties of inverted core-shell polyaniline-ferrite composite

    Energy Technology Data Exchange (ETDEWEB)

    Donescu, Dan [National Institute for Research & Development in Chemistry and Petrochemistry - ICECHIM, 202 Spl. Independentei, 060021, Bucharest (Romania); Fierascu, Radu Claudiu, E-mail: radu_claudiu_fierascu@yahoo.com [National Institute for Research & Development in Chemistry and Petrochemistry - ICECHIM, 202 Spl. Independentei, 060021, Bucharest (Romania); Ghiurea, Marius [National Institute for Research & Development in Chemistry and Petrochemistry - ICECHIM, 202 Spl. Independentei, 060021, Bucharest (Romania); Manaila-Maximean, Doina [University Politehnica of Bucharest, Department of Physics, 313 Spl. Independentei, 060042, Bucharest (Romania); Nicolae, Cristian Andi; Somoghi, Raluca; Spataru, Catalin Ilie [National Institute for Research & Development in Chemistry and Petrochemistry - ICECHIM, 202 Spl. Independentei, 060021, Bucharest (Romania); Stanica, Nicolae [Institute of Physical Chemistry “Ilie Murgulescu”, 202 Spl. Independentei, 060021, Bucharest (Romania); Raditoiu, Valentin [National Institute for Research & Development in Chemistry and Petrochemistry - ICECHIM, 202 Spl. Independentei, 060021, Bucharest (Romania); Vasile, Eugeniu [SC METAV – CD SA, 31 C. A. Rosetti Str., 021051, Bucharest (Romania)

    2017-08-31

    The present paper studies the effect of polyaniline grafting on magnetite functionalized with aminopropyltrimethoxysilane. All the compounds were characterized by analytical techniques (X-ray fluorescence, X-ray diffraction, Fourier transform infrared spectroscopy, thermal analysis, Transmission electron microscopy), as well as by determining their magnetic properties. The electron microscopy analysis of the hybrids shows similar morphologies for all the samples. The presence of the iron atoms on the surface of the final product supports the idea of the existence of an inverted core-shell type structure, the more polar ferrite orienting itself towards water. The correlation between the maximum grafting probability and the maximum magnetization is evidenced, demonstrating the importance of the polymer grafting method on the magnetic properties.

  17. Laser Doppler Vibrometer Based Examination of the Efficiency of Introducing Artificial Delaminations into Composite Shells

    Directory of Open Access Journals (Sweden)

    Kustroń Kamila

    2015-09-01

    Full Text Available During its operation, the laminate shell of the watercraft hull can be exposed to local stability losses caused by the appearance and development of delaminations. The sources of these delaminations are discontinuities, created both in the production process and as a result of bumps of foreign bodies into the hull in operation. In the environment of fatigue loads acting on the hull, the delaminations propagate and lead to the loss of load capacity of the hull structure. There is a need to improve diagnostic systems used in Structural Health Monitoring (SHM of laminate hull elements to detect and monitor the development of the delaminations. Effective diagnostic systems used for delamination assessment base on expert systems. Along with other tools, the expert diagnostic advisory systems make use of the non-destructive examination method which consists in generating elastic waves in the hull shell structure and observing their changes by comparing the recorded signal with damage patterns collected in the expert system database. This system requires introducing certain patterns to its knowledge base, based on the results of experimental examinations performed on specimens with implemented artificial delaminations. The article presents the results of the examination oriented on assessing the delaminations artificially generated in the structure of glass- and carbon-epoxy laminates by introducing local non-adhesive layers with the aid of thin polyethylene film, teflon insert, or thin layer of polyvinyl alcohol. The efficiency of each method was assessed using laser vibrometry. The effect of the depth of delamination position in the laminate on the efficiency of the applied method is documented as well.

  18. Hierarchical shell/core CuO nanowire/carbon fiber composites as binder-free anodes for lithium-ion batteries

    International Nuclear Information System (INIS)

    Yuan, Wei; Luo, Jian; Pan, Baoyou; Qiu, Zhiqiang; Huang, Shimin; Tang, Yong

    2017-01-01

    Highlights: •The composite anode is composed of CuO nanowire shell and carbon fiber core. •The composite anode avoids completely the use of binders. •Synergistic effect of carbon fibers and CuO nanowires enhances performance. •Carbon fibers improve electrical conductivity and buffer volume change. •CuO nanowires shorten diffusion length and alleviate structural strain. -- Abstract: Developing high-performance electrode structures is of great importance for advanced lithium-ion batteries. This study reports an efficient method to fabricate hierarchical shell/core CuO nanowire/carbon fiber composites via electroless plating and thermal oxidation processes. With this method, a binder-free CuO nanowire/carbon fiber shell/core hierarchical network composite anode for lithium-ion batteries is successfully fabricated. The morphology and chemical composition of the anode are characterized, and the electrochemical performance of the anode is investigated by standard electrochemical tests. Owing to the superior properties of carbon fibers and the morphological advantages of CuO nanowires, this composite anode still retains an excellent reversible capacity of 598.2 mAh g −1 with a capacity retention rate above 86%, even after 50 cycles, which is much higher than the CuO anode without carbon fibers. Compared to the typical CuO/C electrode systems, the novel binder-free anode yields a performance close to that of the typical core/shell electrode systems and a much higher reversible capacity and capacity retention than the similar shell/core patterns as well as the anodes with binders. It is believed that this novel anode will pave the way to the development of binder-free anodes in response to the increasing demands for high-power energy storage.

  19. Ply-based Optimization of Laminated Composite Shell Structures under Manufacturing Constraints

    DEFF Research Database (Denmark)

    Sørensen, Rene; Lund, Erik

    2012-01-01

    This work concerns a new ply-based parameterization for performing simultaneous material selection and topology optimization of fiber reinforced laminated composite structures while ensuring that a series of different manufacturing constraints are fulfilled. The material selection can either...

  20. Recent developments in anisotropic heterogeneous shell theory

    CERN Document Server

    Grigorenko, Alexander Ya; Grigorenko, Yaroslav M; Vlaikov, Georgii G

    2016-01-01

    This volume focuses on the relevant general theory and presents some first applications, namely those based on classical shell theory. After a brief introduction, during which the history and state-of-the-art are discussed, the first chapter presents the mechanics of anisotropic heterogeneous shells, covering all relevant assumptions and the basic relations of 3D elasticity, classical and refined shell models. The second chapter examines the numerical techniques that are used, namely discrete orthogonalization, spline-collocation and Fourier series, while the third highlights applications based on classical theory, in particular, the stress-strain state of shallow shells, non-circular shells, shells of revolution, and free vibrations of conical shells. The book concludes with a summary and an outlook bridging the gap to the second volume.

  1. Shell Venster

    International Nuclear Information System (INIS)

    De Wit, P.; Looijesteijn, B.; Regeer, B.; Stip, B.

    1995-03-01

    In the bi-monthly issues of 'Shell Venster' (window on Shell) attention is paid to the activities of the multinational petroleum company Shell Nederland and the Koninklijke/Shell Groep by means of non-specialist articles

  2. Medium rare or well done - how would you like your snail? Influence of cooking practices on the isotopic composition of land snails' shells

    Science.gov (United States)

    Kwiecien, O.; Breitenbach, S. F. M.

    2017-12-01

    Since the seminal work of Goodfriend (1992, EPSL 11), several studies confirmed a relation between the isotopic composition (δ18O, δ13C) of land snail shell carbonate, and environmental parameters like precipitation amount, moisture source, temperature and vegetation. This relation, however, is not straightforward and, importantly, site dependent. The choice of sampling strategy (discrete or bulk sampling), cleaning procedure, and/or pre-depositional history further complicate the shell analysis. The advantage of using snail shells as environmental archive lies in their limited mobility, and thus an intrinsic aptitude of recording local and site-specific conditions. However, snail shells found at archaeological sites, even if of local origin, often represent a dietary component and boiling/roasting could potentially alter the isotopic signature of aragonite material. While thermal processing affects the clumped isotope composition of carbonates, its influence on traditional isotopes is still debated (Ritter et al. 2017, Sedimentology; Müller et al. 2017, Scientific Reports). Consequently, a proper sampling strategy is of great importance and should be chosen according to scientific question. Horizontal high-resolution shell sampling (drill holes along growth axis, across growth lines) provides insights into the amplitude of seasonal variability, while vertical high-resolution sampling (multiple drill holes along the same growth line) produces reproducible results. We took advantage of this reproducibility and, on a yet unprecedented scale, experimentally and sequentially tested the influence of boiling on the δ18O and δ13C signature of shells of modern Helix pomatia. Our results challenge recent reports on alteration due to boiling (Müller et al., 2017, Scientific Reports) and support uncompromised application of snail shells from archeological sites for paleoenvironmental reconstructions.

  3. Ceramic core–shell composites with modified mechanical properties prepared by thermoplastic co-extrusion

    Czech Academy of Sciences Publication Activity Database

    Kaštyl, J.; Chlup, Zdeněk; Clemens, F.; Trunec, M.

    2015-01-01

    Roč. 35, č. 10 (2015), s. 2873-2881 ISSN 0955-2219 R&D Projects: GA MŠk(CZ) ED1.1.00/02.0068 Institutional support: RVO:68081723 Keywords : Alumina * Zirconia toughened alumina * Co-extrusion * Composite * Mechanical properties1 Subject RIV: JH - Ceramics, Fire-Resistant Materials and Glass Impact factor: 2.933, year: 2015

  4. Preparation of CdS@CeO{sub 2} core/shell composite for photocatalytic reduction of CO{sub 2} under visible-light irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Ijaz, Sana [CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190 (China); Institute of Chemical Sciences, Bahauddin Zakaryia University, Multan 60800 (Pakistan); Ehsan, Muhammad Fahad [CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190 (China); Ashiq, Muhammad Naeem, E-mail: naeemashiqqau@yahoo.com [Institute of Chemical Sciences, Bahauddin Zakaryia University, Multan 60800 (Pakistan); Karamat, Nazia [Institute of Chemical Sciences, Bahauddin Zakaryia University, Multan 60800 (Pakistan); He, Tao, E-mail: het@nanoctr.cn [CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190 (China); University of Chinese Academy of Sciences, Beijing 100049 (China)

    2016-12-30

    Highlights: • CdS@CeO{sub 2}core(*)/shell composite is fabricated using a two-step method. • CdS@CeO{sub 2} can photoreduce CO{sub 2} into CH{sub 4} and CH{sub 3}OH under visible-light irradiation. • CdS@CeO{sub 2} can enhance photocatalytic activity due to increased charge separation. • Core shell strategy for photocatalyst preparation can improve photostability. - Abstract: Present work demonstrates fabrication of CdS@CeO{sub 2} core/shell composite and its application in the photocatalytic reduction of CO{sub 2} under visible-light irradiation (λ ≥ 420 nm). CdS@CeO{sub 2} composite has been successfully prepared by two-step chemical method, while CeO{sub 2} and CdS have been synthesized by one-step hydrothermal method. X-ray diffraction analysis confirms the formation of fluorite cubic structure of CeO{sub 2} and cubic phase of CdS. High resolution transmission electron microscopy and scanning electron microscopy reveal the microsphere morphology of CdS, while CeO{sub 2} (shell) is in the form of spherical particles that surround the CdS (core) in case of the composite. X-ray photoelectron spectroscopy has been used to confirm the composition, oxidation state of the elements and valance band of the obtained materials. The CdS@CeO{sub 2} core/shell composite and CdS can convert CO{sub 2} into methane and methanol under visible-light irradiation. The CdS@CeO{sub 2} composite shows higher yield for both methane and methanol than CdS due to low recombination rate of photogenerated electron/hole pairs, as well as a larger BET specific surface area. Moreover, the CdS@CeO{sub 2} core/shell composite also shows improved stability upon photocatalysis.

  5. Conical wavefronts in optics and tomography

    International Nuclear Information System (INIS)

    Soroko, L.M.

    1990-01-01

    A wide range of techniques in which the information is transferred by conical (nonspherical and nonplanar) wave fronts is considered. This is the first summary of papers published in the field of mesooptics and optical tomography. After the introduction into the new branch of modern optics - mesooptics -the properties of conical wavefronts are treated in detail. Some possible applications of mesooptics in science and technology are considered. The long history of mesooptics treated in the last chapter of this review lecture goes from the early stage of our Universe, gravitational lens, first publications in the last century and up-to-date innovations in optics, mesooptics and optical tomography. 3 refs

  6. Hierarchical core-shell structure of ZnO nanorod@NiO/MoO₂ composite nanosheet arrays for high-performance supercapacitors.

    Science.gov (United States)

    Hou, Sucheng; Zhang, Guanhua; Zeng, Wei; Zhu, Jian; Gong, Feilong; Li, Feng; Duan, Huigao

    2014-08-27

    A hierarchical core-shell structure of ZnO nanorod@NiO/MoO2 composite nanosheet arrays on nickel foam substrate for high-performance supercapacitors was constructed by a two-step solution-based method involving two hydrothermal processes followed by a calcination treatment. Compared to one composed of pure NiO/MoO2 composite nanosheets, the hierarchical core-shell structure electrode displays better pseudocapacitive behaviors in 2 M KOH, including high areal specific capacitance values of 1.18 F cm(-2) at 5 mA cm(-2) and 0.6 F cm(-2) at 30 mA cm(-2) as well as relatively good rate capability at high current densities. Furthermore, it also shows remarkable cycle stability, remaining at 91.7% of the initial value even after 4000 cycles at a current density of 10 mA cm(-2). The enhanced pseudocapacitive behaviors are mainly due to the unique hierarchical core-shell structure and the synergistic effect of combining ZnO nanorod arrays and NiO/MoO2 composite nanosheets. This novel hierarchical core-shell structure shows promise for use in next-generation supercapacitors.

  7. Composites Based on Core-Shell Structured HBCuPc@CNTs-Fe3O4 and Polyarylene Ether Nitriles with Excellent Dielectric and Mechanical Properties

    Science.gov (United States)

    Pu, Zejun; Zhong, Jiachun; Liu, Xiaobo

    2017-10-01

    Core-shell structured magnetic carbon nanotubes (CNTs-Fe3O4) coated with hyperbranched copper phthalocyanine (HBCuPc) (HBCuPc@CNTs-Fe3O4) hybrids were prepared by the solvent-thermal method. The results indicated that the HBCuPc molecules were decorated on the surface of CNTs-Fe3O4 through coordination behavior of phthalocyanines, and the CNTs-Fe3O4 core was completely coaxial wrapped by a functional intermediate HBCuPc shell. Then, polymer-based composites with a relatively high dielectric constant and low dielectric loss were fabricated by using core-shell structured HBCuPc@CNTs-Fe3O4 hybrids as fillers and polyarylene ether nitriles (PEN) as the polymer matrix. The cross-sectional scanning electron microscopy (SEM) images of composites showed that there is almost no agglomeration and internal delamination. In addition, the rheological analysis reveals that the core-shell structured HBCuPc@CNTs-Fe3O4 hybrids present better dispersion and stronger interface adhesion with the PEN matrix than CNTs-Fe3O4, thus resulting in significant improvement of the mechanical, thermal and dielectric properties of polymer-based composites.

  8. Analysis of thin-walled cylindrical composite shell structures subject to axial and bending loads: Concept development, analytical modeling and experimental verification

    Science.gov (United States)

    Mahadev, Sthanu

    Continued research and development efforts devoted in recent years have generated novel avenues towards the advancement of efficient and effective, slender laminated fiber-reinforced composite members. Numerous studies have focused on the modeling and response characterization of composite structures with particular relevance to thin-walled cylindrical composite shells. This class of shell configurations is being actively explored to fully determine their mechanical efficacy as primary aerospace structural members. The proposed research is targeted towards formulating a composite shell theory based prognosis methodology that entails an elaborate analysis and investigation of thin-walled cylindrical shell type laminated composite configurations that are highly desirable in increasing number of mechanical and aerospace applications. The prime motivation to adopt this theory arises from its superior ability to generate simple yet viable closed-form analytical solution procedure to numerous geometrically intense, inherent curvature possessing composite structures. This analytical evaluative routine offers to acquire a first-hand insight on the primary mechanical characteristics that essentially govern the behavior of slender composite shells under typical static loading conditions. Current work exposes the robustness of this mathematical framework via demonstrating its potential towards the prediction of structural properties such as axial stiffness and bending stiffness respectively. Longitudinal ply-stress computations are investigated upon deriving the global stiffness matrix model for composite cylindrical tubes with circular cross-sections. Additionally, this work employs a finite element based numerical technique to substantiate the analytical results reported for cylindrically shaped circular composite tubes. Furthermore, this concept development is extended to the study of thin-walled, open cross-sectioned, curved laminated shells that are geometrically

  9. Core-shell composite metal catalysts incased into natural ceramic nanotubes

    International Nuclear Information System (INIS)

    Vinokurov, V; Berberov, A; Afonin, D; Borzaev, H; Ivanov, E; Gushchin, P; Lvov, Y

    2014-01-01

    The bimetallic halloysite nanotubes were prepared by the injection of halloysite- containing aerosols into the microwave plasma reactor. Nanotubes contain metal nanoparticles formed from the metal salt solution in the lumen of nanotubes and the iron oxide nanoparticles at the outer surface of nanotubes. Such halloysite composites may be sputtered onto the surface of the porous carrier forming the nanostructured catalyst, as was shown by the pure halloysite sputtering onto the model porous ceramic surface

  10. Decomposition in conic optimization with partially separable structure

    DEFF Research Database (Denmark)

    Sun, Yifan; Andersen, Martin Skovgaard; Vandenberghe, Lieven

    2014-01-01

    Decomposition techniques for linear programming are difficult to extend to conic optimization problems with general nonpolyhedral convex cones because the conic inequalities introduce an additional nonlinear coupling between the variables. However in many applications the convex cones have...

  11. Tablet-level origin of toughening in abalone shells and translation to synthetic composite materials.

    Science.gov (United States)

    Espinosa, Horacio D; Juster, Allison L; Latourte, Felix J; Loh, Owen Y; Gregoire, David; Zavattieri, Pablo D

    2011-02-01

    Nacre, the iridescent material in seashells, is one of many natural materials employing hierarchical structures to achieve high strength and toughness from relatively weak constituents. Incorporating these structures into composites is appealing as conventional engineering materials often sacrifice strength to improve toughness. Researchers hypothesize that nacre's toughness originates within its brick-and-mortar-like microstructure. Under loading, bricks slide relative to each other, propagating inelastic deformation over millimeter length scales. This leads to orders-of-magnitude increase in toughness. Here, we use in situ atomic force microscopy fracture experiments and digital image correlation to quantitatively prove that brick morphology (waviness) leads to transverse dilation and subsequent interfacial hardening during sliding, a previously hypothesized dominant toughening mechanism in nacre. By replicating this mechanism in a scaled-up model synthetic material, we find that it indeed leads to major improvements in energy dissipation. Ultimately, lessons from this investigation may be key to realizing the immense potential of widely pursued nanocomposites.

  12. Charge-doping and chemical composition-driven magnetocrystalline anisotropy in CoPt core-shell alloy clusters

    Science.gov (United States)

    Ruiz-Díaz, P.; Muñoz-Navia, M.; Dorantes-Dávila, J.

    2018-03-01

    Charge-doping together with 3 d-4 d alloying emerges as promising mechanisms for tailoring the magnetic properties of low-dimensional systems. Here, throughout ab initio calculations, we present a systematic overview regarding the impact of both electron(hole) charge-doping and chemical composition on the magnetocrystalline anisotropy (MA) of CoPt core-shell alloy clusters. By taking medium-sized Co n Pt m ( N = n + m = 85) octahedral-like alloy nanoparticles for some illustrative core-sizes as examples, we found enhanced MA energies and large induced spin(orbital) moments in Pt-rich clusters. Moreover, depending on the Pt-core-size, both in-plane and off-plane directions of magnetization are observed. In general, the MA of these binary compounds further stabilizes upon charge-doping. In addition, in the clusters with small MA, the doping promotes magnetization switching. Insights into the microscopical origins of the MA behavior are associated to changes in the electronic structure of the clusters. [Figure not available: see fulltext.

  13. Investigation on imperfection sensitivity of composite cylindrical shells using the nonlinearity reduction technique and the polynomial chaos method

    Science.gov (United States)

    Liang, Ke; Sun, Qin; Liu, Xiaoran

    2018-05-01

    The theoretical buckling load of a perfect cylinder must be reduced by a knock-down factor to account for structural imperfections. The EU project DESICOS proposed a new robust design for imperfection-sensitive composite cylindrical shells using the combination of deterministic and stochastic simulations, however the high computational complexity seriously affects its wider application in aerospace structures design. In this paper, the nonlinearity reduction technique and the polynomial chaos method are implemented into the robust design process, to significantly lower computational costs. The modified Newton-type Koiter-Newton approach which largely reduces the number of degrees of freedom in the nonlinear finite element model, serves as the nonlinear buckling solver to trace the equilibrium paths of geometrically nonlinear structures efficiently. The non-intrusive polynomial chaos method provides the buckling load with an approximate chaos response surface with respect to imperfections and uses buckling solver codes as black boxes. A fast large-sample study can be applied using the approximate chaos response surface to achieve probability characteristics of buckling loads. The performance of the method in terms of reliability, accuracy and computational effort is demonstrated with an unstiffened CFRP cylinder.

  14. Preparation of Vertically Aligned ZnO/TiO2 Core-Shell Composites for Dye-Sensitized Solar Cells

    Directory of Open Access Journals (Sweden)

    Lung-Chuan Chen

    2013-01-01

    Full Text Available Vertically aligned ZnO/TiO2 (VA-ZnO/TiO2 core-shell composites deposited on ZnO-seeded indium tin oxide (ITO glasses have been synthesized by a chemical bath deposition approach for growing one-dimensional ZnO structure followed by a spin procedure for coating TiO2 on the surface of ZnO structure. The influences of the cycles of spin coating of TiO2 (CSCT on the properties of VA-ZnO/TiO2 and performances of the assembled DSSCs were studied. The power conversion efficiency of the VA-ZnO/TiO2-based DSSC measured under illumination of 100 mW/cm2 and AM 1.5 can reach 0.81%, representing 93% improvement when compared with that of the pristine VA-ZnO electrode (0.42%. The intensity-modulated photocurrent spectroscopy (IMPS and electrochemical impedance spectroscopy (EIS were applied to study the kinetics and interfacial transfer of the photogenerated electrons. Both the photocurrent and power conversion efficiency correlate well with the steady state electron density. Enlargement in surface area and dye adsorption, suppression of dissolution of Zn2+, diminishment in electron recombination, and fast transfer of injected electrons from excited dyes to TiO2 conduction bands arising from coating TiO2 on VA-ZnO are regarded as the predominant causes for this improvement.

  15. Conical : An extended module for computing a numerically satisfactory pair of solutions of the differential equation for conical functions

    NARCIS (Netherlands)

    T.M. Dunster (Mark); A. Gil (Amparo); J. Segura (Javier); N.M. Temme (Nico)

    2017-01-01

    textabstractConical functions appear in a large number of applications in physics and engineering. In this paper we describe an extension of our module Conical (Gil et al., 2012) for the computation of conical functions. Specifically, the module includes now a routine for computing the function

  16. Dual-shell hollow polyaniline/sulfur-core/polyaniline composites improving the capacity and cycle performance of lithium–sulfur batteries

    Energy Technology Data Exchange (ETDEWEB)

    An, Yanling; Wei, Pan; Fan, Meiqiang, E-mail: fanmeiqiang@126.com; Chen, Da; Chen, Haichao; Ju, QiangJian; Tian, Guanglei; Shu, Kangying

    2016-07-01

    Highlights: • A dual core-shell hPANI/S/PANI composite was prepared in situ synthesis. • Cycle performance of the hPANI/S/PANI composite was enhanced. • The improvement was due to fine sulfur particles wrapped by two PANI films. • Some positive effects were elaborated. - Abstract: In this study, a dual-shell hollow polyaniline/sulfur-core/polyaniline (hPANI/S/PANI) composite was prepared by successively depositing PANI, S, and PANI on the surface of a template silicon sphere. The electrochemical properties of this composite were evaluated using a lithium plate as an anode in lithium/sulfur cells. The hPANI/S/PANI composite showed a discharge capacity of 572.2 mAh g{sup −1} after 214 cycles at 0.1 C, and the Coulombic efficiency was above 87% in the whole charge/discharge cycle. The improved cycle property of the hPANI/S/PANI composite can be ascribed to the fine sulfur particles homogeneously deposited on the PANI surface and sprawled inside the two PANI layers during the charge/discharge cycle. This behavior stabilized the nanostructure of sulfur and enhanced its conductivity.

  17. Combustion of peanut shells in a cone-shaped bubbling fluidized-bed combustor using alumina as the bed material

    International Nuclear Information System (INIS)

    Arromdee, Porametr; Kuprianov, Vladimir I.

    2012-01-01

    Highlights: ► We propose burning of peanut shells in a conical fluidized bed using alumina sand. ► We examine hydrodynamic, combustion and emission characteristics of the reactor. ► High, over 99%, combustion efficiency is achievable. ► Emissions of CO and NO from the combustor meet the national emission limits. ► Composition of the bed material undergoes significant changes during the combustion. -- Abstract: This paper reports experimental studies on burning peanut shells in the conical fluidized-bed combustor using alumina sand as the fluidizing agent. Prior to combustion tests, hydrodynamic regimes and characteristics of a conical alumina–biomass bed were investigated under cold-state conditions for variable percentage of peanut shells in the mixture and static bed height. With selected particle sizes (300–500 μm) and static bed height (30 cm), alumina ensured bubbling fluidization regime of the bed at operating conditions specified for firing biomass. Combustion tests were performed at 60 kg/h and 45 kg/h fuel feed rates, while ranging excess air from 20% to 80% at a fixed combustor load. Temperature and gas concentrations (O 2 , CO, C x H y as CH 4 , and NO) were measured along radial and axial directions inside the reactor as well as at stack in order to characterize combustion and emission performance of the combustor for the ranges of operating conditions. For firing 60 kg/h peanut shells, excess air of 40% can be selected as an appropriate value ensuring high, about 99%, combustion efficiency and rather low emissions of CO and NO: 520 ppm and 125 ppm, respectively (both on a dry basis and at 6% O 2 ). With reducing combustor load, the combustion efficiency and emission characteristics were improved to a little extent. No evidence of bed agglomeration was found during 30-h combustion tests on this conical fluidized-bed combustor using alumina sand as the bed material. However, the timescale effect on the composition of the bed material was

  18. The sustained-release behavior and in vitro and in vivo transfection of pEGFP-loaded core-shell-structured chitosan-based composite particles

    Science.gov (United States)

    Wang, Yun; Lin, Fu-xing; Zhao, Yu; Wang, Mo-zhen; Ge, Xue-wu; Gong, Zheng-xing; Bao, Dan-dan; Gu, Yu-fang

    2014-01-01

    Novel submicron core-shell-structured chitosan-based composite particles encapsulated with enhanced green fluorescent protein plasmids (pEGFP) were prepared by complex coacervation method. The core was pEGFP-loaded thiolated N-alkylated chitosan (TACS) and the shell was pH- and temperature-responsive hydroxybutyl chitosan (HBC). pEGFP-loaded TACS-HBC composite particles were spherical, and had a mean diameter of approximately 120 nm, as measured by transmission electron microscopy and particle size analyzer. pEGFP showed sustained release in vitro for >15 days. Furthermore, in vitro transfection in human embryonic kidney 293T and human cervix epithelial cells, and in vivo transfection in mice skeletal muscle of loaded pEGFP, were investigated. Results showed that the expression of loaded pEGFP, both in vitro and in vivo, was slow but could be sustained over a long period. pEGFP expression in mice skeletal muscle was sustained for >60 days. This work indicates that these submicron core-shell-structured chitosan-based composite particles could potentially be used as a gene vector for in vivo controlled gene transfection. PMID:25364253

  19. Folic acid-functionalized magnetic ZnFe2O4 hollow microsphere core/mesoporous silica shell composite particles: synthesis and application in drug release.

    Science.gov (United States)

    Yang, Dandan; Wei, Kaiwei; Liu, Qi; Yang, Yong; Guo, Xue; Rong, Hongren; Cheng, Mei-Ling; Wang, Guoxiu

    2013-07-01

    A drug delivery system was designed by deliberately combining the useful functions into one entity, which was composed of magnetic ZnFe2O4 hollow microsphere as the core, and mesoporous silica with folic acid molecules as the outer shell. Amine groups coated magnetic ZnFe2O4 hollow microsphere core/mesoporous silica shell (MZHM-MSS-NH2) composite particles were first synthesized by a one-pot direct co-condensation method. Subsequently a novel kind of folic acid-functionalized magnetic ZnFe2O4 hollow microsphere core/mesoporous silica shell (MZHM-MSS-NHFA) composite particles were synthesized by conjugating folic acid as targeted molecule to MZHM-MSS-NH2. Ibuprofen, a well-known antiphlogistic drug, was used as a model drug to assess the loading and releasing behavior of the composite microspheres. The results show that the MZHM-MSS-NHFA system has the higher capacity of drug storage and good sustained drug-release property. Copyright © 2013 Elsevier B.V. All rights reserved.

  20. Polyaniline/multi-walled carbon nanotubes composite with core-shell structures as a cathode material for rechargeable lithium-polymer cells

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Pan [School of Marine Science and Technology, Harbin Institute of Technology, Weihai 264209 (China); Han, Jia-Jun, E-mail: hanjiajunhitweihai@163.com [School of Marine Science and Technology, Harbin Institute of Technology, Weihai 264209 (China); Jiang, Li-Feng [Dalian Chemical Institute of Chinese Academy of Sciences, Dalian 116011 (China); Li, Zhao-Yu; Cheng, Jin-Ning [School of Marine Science and Technology, Harbin Institute of Technology, Weihai 264209 (China)

    2017-04-01

    Highlights: • The polyaniline multi-walled carbon nanotubes composite with core-shell structures was synthetized via in situ chemical oxidative polymerization, and the materials were characterized by physical and chemical methods. • The PANI/WMCNTs was synthetized via in situ chemical oxidative polymerization with core-shell structures. • The WMCNTs highly enhanced the conductivity of composites. • The comopsites were more conducive to the intercalation and deintercalation of anions and cations. • The much better performance as the cathode for lithium-ion cells was acquired for the composites. • The composites are low cost and eco-friendly which have a good prospect in future. - Abstract: The aniline was polymerized onto functionalized multi-walled carbon nanotubes in order to obtain a cathode material with core-shell structures for lithium batteries. The structure and morphology of the samples were investigated by Fourier transform infrared spectroscopy analysis, scanning electron microscope, transmission electron microscope and X-ray diffraction. The electrochemical properties of the composite were characterized by the cyclic voltammetry, the charge/discharge property, coulombic efficiency, and ac impedance spectroscopy in detail. At a constant current density of 0.2 C, the first specific discharge capacity of the reduced and oxidized PANI/WMCNTs were 181.8 mAh/g and 135.1 mAh/g separately, and the capacity retention rates were corresponding to 76.75% and 86.04% for 100 cycles with 99% coulombic efficiency. It was confirmed that the CNTs obviously enhanced the conductivity and electrochemical performance of polyaniline, and compared with the pure PANI, the reduced composite possessed a quite good performance for the cathode of lithium batteries.

  1. Black hole thermodynamics with conical defects

    Energy Technology Data Exchange (ETDEWEB)

    Appels, Michael [Centre for Particle Theory, Durham University,South Road, Durham, DH1 3LE (United Kingdom); Gregory, Ruth [Centre for Particle Theory, Durham University,South Road, Durham, DH1 3LE (United Kingdom); Perimeter Institute,31 Caroline Street North, Waterloo, ON, N2L 2Y5 (Canada); Kubiznák, David [Perimeter Institute,31 Caroline Street North, Waterloo, ON, N2L 2Y5 (Canada)

    2017-05-22

    Recently we have shown https://www.doi.org/10.1103/PhysRevLett.117.131303 how to formulate a thermodynamic first law for a single (charged) accelerated black hole in AdS space by fixing the conical deficit angles present in the spacetime. Here we show how to generalise this result, formulating thermodynamics for black holes with varying conical deficits. We derive a new potential for the varying tension defects: the thermodynamic length, both for accelerating and static black holes. We discuss possible physical processes in which the tension of a string ending on a black hole might vary, and also map out the thermodynamic phase space of accelerating black holes and explore their critical phenomena.

  2. Study of magnetization and magnetoelectricity in CoFe2O4/BiFeO3 core-shell composites

    Science.gov (United States)

    Kuila, S.; Tiwary, Sweta; Sahoo, M. R.; Barik, A.; Babu, P. D.; Siruguri, V.; Birajdar, B.; Vishwakarma, P. N.

    2018-02-01

    CoFe2O4 (core)/BiFeO3 (shell) nanoparticles are prepared by varying the relative molar concentration of core and shell materials (40%CoFe2O4-60%BiFeO3, 50%CoFe2O4-50%BiFeO3, and 60%CoFe2O4-40%BiFeO3). The core-shell nature is confirmed from transmission electron microscopy on these samples. A plot of ΔM (=MFC-MZFC) vs temperature suggests the presence of two types of spin dynamics: (a) particle size dependent spin blocking and (b) spin-disorder. These two spin dynamic processes are found to contribute independently to the generation of magnetoelectric voltage. Very clear first order and second order magnetoelectric voltages are recorded. The resemblance of the first order magnetoelectric coefficient vs temperature plot to that of building up of order parameters in the mean field theory suggests that spin disorder can act like one of the essential ingredients in building the magnetoelectric coupling. The best result is obtained for the 50-50 composition sample, which may be due to better coupling of magnetostrictive CoFe2O4, and piezoelectric BiFeO3, because of the optimum thickness of shell and core.

  3. Noise suppression in curved glass shells using macro-fiber-composite actuators studied by the means of digital holography and acoustic measurements

    Directory of Open Access Journals (Sweden)

    P. Mokrý

    2015-02-01

    Full Text Available The paper presents methods and experimental results of the semi-active control of noise transmission in a curved glass shell with attached piezoelectric macro fiber composite (MFC actuators. The semi-active noise control is achieved via active elasticity control of piezoelectric actuators by connecting them to an active electric shunt circuit that has a negative effective capacitance. Using this approach, it is possible to suppress the vibration of the glass shell in the normal direction with respect to its surface and to increase the acoustic transmission loss of the piezoelectric MFC-glass composite structure. The effect of the MFC actuators connected to the negative capacitance shunt circuit on the surface distribution of the normal vibration amplitude is studied using frequency-shifted digital holography (FSDH. The principle of the used FSDH method is described in the paper. The frequency dependence of the acoustic transmission loss through the piezoelectric MFC-glass composite structure is estimated using measurements of the specific acoustic impedance of the curved glass shell. The specific acoustic impedance is measured using two microphones and a laser Doppler vibrometer (LDV. The results from the LDV measurements are compared with the FSDH data. The results of the experiments show that using this approach, the acoustic transmission loss in a glass shell can be increased by 36 dB in the frequency range around 247 Hz and by 25 dB in the frequency range around 258 Hz. The experiments indicate that FSDH measurements provide an efficient tool that can be used for fast and accurate measurements of the acoustic transmission loss in large planar structures.

  4. Structural shell analysis understanding and application

    CERN Document Server

    Blaauwendraad, Johan

    2014-01-01

    The mathematical description of the properties of a shell is much more elaborate than those of beam and plate structures. Therefore many engineers and architects are unacquainted with aspects of shell behaviour and design, and are not familiar with sufficiently reliable shell theories for the different shell types as derived in the middle of the 20th century. Rather than contributing to theory development, this university textbook focuses on architectural and civil engineering schools. Of course, practising professionals will profit from it as well. The book deals with thin elastic shells, in particular with cylindrical, conical and spherical types, and with elliptic and hyperbolic paraboloids. The focus is on roofs, chimneys, pressure vessels and storage tanks. Special attention is paid to edge bending disturbance zones, which is indispensable knowledge in FE meshing. A substantial part of the book results from research efforts in the mid 20th century at Delft University of Technology. As such, it is a valua...

  5. Synergistic Removal of Humic Acid in Water by Coupling Adsorption and Photocatalytic Degradation Using TiO2/Coconut Shell Powder Composite

    Directory of Open Access Journals (Sweden)

    Jong Kyu Kim

    2016-01-01

    Full Text Available The feasibility of applying nanoscale TiO2/coconut shell powder (TCNSP composite to remove HA in aqueous solution was evaluated, and the optimization of the photocatalytic systems using newly developed TCNSP composite was performed. The developed TCNSP composite has high specific surface area (i.e., 454 m2/g and great porosity (i.e., 66.9% with pore size of less than 5 μm. High removal efficiencies (≥95% of HA were observed due to the significant synergistic effects by coupling adsorption and photocatalytic reaction of TCNSP composite. As the initial concentration of HA increased, the degradation rate (Kapp decreased due to HA sorption saturation to the surface of TCNSP composite and the photon interception by HA molecules in aqueous solution. Since the increased loading amount of TCNSP composite enhanced the number of active sites, Kapp values increased until the optimum loading amount of TCNSP composite. As pH values increased, HA removal efficiency decreased due to increasing electrostatic repulsion between HA and TCNSP composite. Based on the response surface methodology, higher HA removal efficiencies were obtained with acidic condition, longer reaction time, and appropriated loading amount of TCNSP. Further pilot-scale study is in progress using TCNSP composite combined with UVC to remove HA from large amounts of surface water (i.e., 200 m3/d.

  6. Synthesis and supercapacitor electrode of VO{sub 2}(B)/C core–shell composites with a pseudocapacitance in aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Yifu, E-mail: yfzhang@dlut.edu.cn; Zheng, Jiqi; Hu, Tao; Tian, Fuping; Meng, Changgong

    2016-05-15

    Highlights: • A facile one-pot hydrothermal method was used to synthesize VO{sub 2}(B)/C core–shell composites. • VO{sub 2}(B)/C composites consisted of the crystal VO{sub 2}(B) phase and the amorphous carbon phase. • The supercapacitor property of VO{sub 2}(B)/C composites was improved by this novel structure. - Abstract: VO{sub 2}(B)/C core–shell composites were successfully prepared using commercial V{sub 2}O{sub 5}, glucose and water as the starting materials by a facile one-pot hydrothermal method. The composition of the products was characterized by the techniques including X-ray powder diffraction, infrared spectroscopy, Raman, energy-dispersive X-ray spectrometer and elemental analysis. The morphology of the products was observed by scanning electron microscopy and transmission electron microscopy tests. The results showed the products consisted of the crystal VO{sub 2}(B) phase and the amorphous carbon phase. The amorphous carbon contained lots of organic groups, such as −OH, C−H, C=O and C=C, etc., which suggested that the carbon here was organic carbon. The morphology of the as-obtained VO{sub 2}(B)/C composites was well-defined nanobelts, and each VO{sub 2}(B) core was encapsulated into carbon. Furthermore, the electrochemical properties of VO{sub 2}(B)/C core–shell composites were investigated by cyclic voltammetry and galvanostatic charge–discharge. The results showed the measured capacitance of VO{sub 2}(B)/C composites was mainly based on the pseudocapacitance. VO{sub 2}(B)/C composites displayed the specific capacitance of 203, 190, 182, 173, 164, and 147 F g{sup −1} at the current density of 0.2, 0.5, 1, 5, 10 and 20 A g{sup −1}, respectively. They also showed an excellent energy density of 198.9 W h kg{sup −1} at a power density of 504.5 W kg{sup −1} and a rapidly reversible redox Faraday response.

  7. The effect of smelting time and composition of palm kernel shell charcoal reductant toward extractive Pomalaa nickel laterite ore in mini electric arc furnace

    Science.gov (United States)

    Sihotang, Iqbal Huda; Supriyatna, Yayat Iman; Ismail, Ika; Sulistijono

    2018-04-01

    Indonesia is a country that is rich in natural resources. Being a third country which has a nickel laterite ore in the world after New Caledonia and Philippines. However, the processing of nickel laterite ore to increase its levels in Indonesia is still lacking. In the processing of nickel laterite ore into metal, it can be processed by pyrometallurgy method that typically use coal as a reductant. However, coal is a non-renewable energy and have high enough levels of pollution. One potentially replace is the biomass, that is a renewable energy. Palm kernel shell are biomass that can be used as a reductant because it has a fairly high fix carbon content. This research aims to make nickel laterite ores become metal using palm kernel shell charcoal as reductant in mini electric arc furnace. The result show that the best smelting time of this research is 60 minutes with the best composition of the reductant is 2,000 gram.

  8. Magnetization-induced enhancement of photoluminescence in core-shell CoFe{sub 2}O{sub 4}@YVO{sub 4}:Eu{sup 3+} composite

    Energy Technology Data Exchange (ETDEWEB)

    Jia, Yanmin, E-mail: ymjia@zjnu.edu.cn, E-mail: wuzheng@zjnu.cn; Zhou, Zhihua; Wei, Yongbin [Department of Physics, Zhejiang Normal University, Jinhua 321004 (China); Wu, Zheng, E-mail: ymjia@zjnu.edu.cn, E-mail: wuzheng@zjnu.cn; Chen, Jianrong [College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua 321004 (China); Zhang, Yihe [School of Materials Science and Technology, China University of Geosciences, Beijing 100083 (China); Liu, Yongsheng [Department of Physics, Shanghai University of Electric Power, Shanghai 200090 (China)

    2013-12-07

    After the core-shell CoFe{sub 2}O{sub 4}@YVO{sub 4}:Eu{sup 3+} composite synthesized through a facile sol-gel method was magnetized under an external magnetic field of 0.25 T for 4 h, an enhancement of ∼56% in photoluminescence intensity was observed. The remanent magnetization of the CoFe{sub 2}O{sub 4} core increases the intensity of the excited charge transfer transition of VO{sub 4}{sup 3−} group in YVO{sub 4}:Eu{sup 3+} shell, which may enhance the probability related to the Eu{sup 3+} radiative transition {sup 5}D{sub 0}-{sup 7}F{sub 2}, yielding to a high photoluminescence. The obvious remanent-magnetization-induced enhancement in photoluminescence is helpful in developing excellent magnetic/luminescent material for the practical display devices.

  9. [Effect of the harvest season on the composition of raw and fermented cotyledons of 2 varieties of cacao and shell fractions].

    Science.gov (United States)

    de Dios Alvarado, J; Villacís, F E; Zamora, G F

    1983-06-01

    A study was carried out wherein during the period August 1979 to January 1980, samples of raw and fermented cacao were analyzed monthly. These included two varieties: Arriba, taken from a farm in "Quevedo", and the EET-19, grown in "Pichilingüe" by the Instituto Nacional de Investigaciones Agropecuarias (INIAP). Taking the ear of cacao as a basis, the weight of its main parts was determined. The proximal composition was established in the cotyledons, with significant statistical differences in regard to moisture, protein, and ether extract content according to the month of harvest. As to the fermentation process, differences in moisture, ether extract and ash content were detected; differences in the ether extract and ash content were found between the two varieties. The fat extracted from the cotyledons presented different iodine, saponification and acidity index values between the raw and fermented samples, but none were determined between the varieties; as far as the month of harvest is concerned, differences in the acidity index were observed. The percentage composition of the main fatty acids is reported (palmitic, stearic, oleic, and linoleic acids). In order to suggest possible industrial ways of utilizing the cacao shell by-product which is discarded by the shelling machine, the chemical characteristics of five fractions were determined based on the functioning of the shelling machine. The moisture, protein, ether extract, ash, crude fiber, theobromine, and caffeine contents varied among the fractions, and it was dependent on the broken "nibs" content. Differences in the protein, ether extract, and ash content, according to the months of production, were found. Obviously, the high fat content in fractions A (fine dust) and B (fine ground), which varied from 30 to 11 g/100 g, merits its extraction; the remainder meal has a valuable protein and alkaloid content. The chemical characteristics of the fat extracted from the shell of two fractions were similar to

  10. Time resolution measurements with an improved discriminator and conical scintillators

    International Nuclear Information System (INIS)

    McGervey, J.D.; Vogel, J.; Sen, P.; Knox, C.

    1977-01-01

    A new constant fraction discriminator with improved stability and walk characteristics is described. The discriminator was used with RCA C31024 photomultiplier tubes to test scintillators of conical and cylindrical shapes. Conical scintillators of 2.54 cm base diameter, 1.0 cm top diameter, and 2.54 cm height gave a fwhm of 155 ps for 60 Co gamma rays; larger conical scintillators gave an improvement of 10-15% in fwhm over cylindrical scintillators of equal volume. (Auth.)

  11. Conical Double Frequency Emission by Femtosecond Laser Pulses from DKDP

    International Nuclear Information System (INIS)

    Xi-Peng, Zhang; Hong-Bing, Jiang; Shan-Chun, Tang; Qi-Huang, Gong

    2009-01-01

    Conical double frequency emission is investigated by femtosecond laser pulses at a wavelength of 800 nm in a DKDP crystal. It is demonstrated that the sum frequency of incident wave and its scattering wave accounts for the conical double frequency emission. The gaps on the conical rings are observed and they are very sensitive to the propagation direction, and thus could be used to detect the small angle deviation of surface direction. (fundamental areas of phenomenology (including applications))

  12. Fabrication of carbon nanospheres by the pyrolysis of polyacrylonitrile–poly(methyl methacrylate core–shell composite nanoparticles

    Directory of Open Access Journals (Sweden)

    Dafu Wei

    2017-09-01

    Full Text Available Carbon nanospheres with a high Brunauer–Emmett–Teller (BET specific surface area were fabricated via the pyrolysis of polyacrylonitrile–poly(methyl methacrylate (PAN–PMMA core–shell nanoparticles. Firstly, PAN–PMMA nanoparticles at high concentration and low surfactant content were controllably synthesized by a two-stage azobisisobutyronitrile (AIBN-initiated semicontinuous emulsion polymerization. The carbon nanospheres were obtained after the PAN core domain was converted into carbon and the PMMA shell was sacrificed via the subsequent heat treatment steps. The thickness of the PMMA shell can be easily adjusted by changing the feeding volume ratio (FVR of methyl methacrylate (MMA to acrylonitrile (AN. At an FVR of 1.6, the coarse PAN cores were completely buried in the PMMA shells, and the surface of the obtained PAN–PMMA nanoparticles became smooth. The thick PMMA shell can inhibit the adhesion between carbon nanospheres caused by cyclization reactions during heat treatment. The carbon nanospheres with a diameter of 35–65 nm and a high BET specific surface area of 612.8 m2/g were obtained from the PAN–PMMA nanoparticles synthesized at an FVR of 1.6. The carbon nanospheres exhibited a large adsorption capacity of 190.0 mg/g for methylene blue, thus making them excellent adsorbents for the removal of organic pollutants from water.

  13. Conical Refraction: new observations and a dual cone model.

    Science.gov (United States)

    Sokolovskii, G S; Carnegie, D J; Kalkandjiev, T K; Rafailov, E U

    2013-05-06

    We propose a paraxial dual-cone model of conical refraction involving the interference of two cones of light behind the exit face of the crystal. The supporting experiment is based on beam selecting elements breaking down the conically refracted beam into two separate hollow cones which are symmetrical with one another. The shape of these cones of light is a product of a 'competition' between the divergence caused by the conical refraction and the convergence due to the focusing by the lens. The developed mathematical description of the conical refraction demonstrates an excellent agreement with experiment.

  14. Switching Exciton Pulses Through Conical Intersections

    Science.gov (United States)

    Leonhardt, K.; Wüster, S.; Rost, J. M.

    2014-11-01

    Exciton pulses transport excitation and entanglement adiabatically through Rydberg aggregates, assemblies of highly excited light atoms, which are set into directed motion by resonant dipole-dipole interaction. Here, we demonstrate the coherent splitting of such pulses as well as the spatial segregation of electronic excitation and atomic motion. Both mechanisms exploit local nonadiabatic effects at a conical intersection, turning them from a decoherence source into an asset. The intersection provides a sensitive knob controlling the propagation direction and coherence properties of exciton pulses. The fundamental ideas discussed here have general implications for excitons on a dynamic network.

  15. Conical differentiability for evolution variational inequalities

    Science.gov (United States)

    Jarušek, Jiří; Krbec, Miroslav; Rao, Murali; Sokołowski, Jan

    The conical differentiability of solutions to the parabolic variational inequality with respect to the right-hand side is proved in the paper. From one side the result is based on the Lipschitz continuity in H {1}/{2},1 (Q) of solutions to the variational inequality with respect to the right-hand side. On the other side, in view of the polyhedricity of the convex cone K={v∈ H;v |Σ c⩾0,v |Σ d=0}, we prove new results on sensitivity analysis of parabolic variational inequalities. Therefore, we have a positive answer to the question raised by Fulbert Mignot (J. Funct. Anal. 22 (1976) 25-32).

  16. Conic coconuts : the pricing of contingent capital notes using conic finance

    NARCIS (Netherlands)

    Madan, D.B.; Schoutens, W.

    2010-01-01

    In this paper we introduce a fundamental model under which we will price contingent capital notes using conic finance techniques. The model is based on more realistic balance-sheet models recognizing the fact that asset and liabilities are both risky and have been treated differently taking into

  17. The sustained-release behavior and in vitro and in vivo transfection of pEGFP-loaded core-shell-structured chitosan-based composite particles

    Directory of Open Access Journals (Sweden)

    Wang Y

    2014-10-01

    Full Text Available Yun Wang,1 Fu-xing Lin,2 Yu Zhao,1 Mo-zhen Wang,2 Xue-wu Ge,2 Zheng-xing Gong,1 Dan-dan Bao,1 Yu-fang Gu1 1Department of Plastic Surgery, First Affiliated Hospital of Anhui Medical University, 2CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui, People’s Republic of China Abstract: Novel submicron core-shell-structured chitosan-based composite particles ­encapsulated with enhanced green fluorescent protein plasmids (pEGFP were prepared by complex coacervation method. The core was pEGFP-loaded thiolated N-alkylated chitosan (TACS and the shell was pH- and temperature-responsive hydroxybutyl chitosan (HBC. pEGFP-loaded TACS-HBC composite particles were spherical, and had a mean diameter of approximately 120 nm, as measured by transmission electron microscopy and particle size analyzer. pEGFP showed sustained release in vitro for >15 days. Furthermore, in vitro transfection in human embryonic kidney 293T and human cervix epithelial cells, and in vivo transfection in mice skeletal muscle of loaded pEGFP, were investigated. Results showed that the expression of loaded pEGFP, both in vitro and in vivo, was slow but could be sustained over a long period. pEGFP expression in mice skeletal muscle was sustained for >60 days. This work indicates that these submicron core-shell-structured chitosan-based composite particles could potentially be used as a gene vector for in vivo controlled gene transfection. Keywords: gene therapy, gene transfection, hydroxybutyl chitosan, thiolated N-alkylated chitosan, pEGFP, complex coacervation

  18. Highly efficient enrichment of low-abundance intact proteins by core-shell structured Fe3O4-chitosan@graphene composites.

    Science.gov (United States)

    Zhang, Peng; Fang, Xiaoni; Yan, Guoquan; Gao, Mingxia; Zhang, Xiangmin

    2017-11-01

    In proteomics research, the screening and monitoring of disease biomarkers is still a major challenge, mainly due to their low concentration in biological samples. However, the universal enrichment of intact proteins has not been further studied. In this work, we developed a Fe 3 O 4 -chitosan@graphene (Fe 3 O 4 -CS@G) core-shell composite to enrich low-abundance proteins from biological samples. Fe 3 O 4 -CS@G composite holds chitosan layer decorated Fe 3 O 4 core, which improves the hydrophilicity of materials greatly. Meanwhile, the graphene nanosheets shell formed via electrostatic assembly endows the composite with huge surface area (178m 2 /g). The good water dispersibility ensures the sufficient contact opportunities between graphene composites and proteins, and the large surface area provides enough adsorption sites for the enrichment of proteins. Using Fe 3 O 4 -CS@G, four standard proteins Cyt-c, BSA, Myo and OVA were enriched with better adsorption capacity and recovery rate, compared with previously reported magnetic graphene composites. Additionally, the mechanism of compared to" is corrected into "compared with". proteins adsorption on Fe 3 O 4 -CS@G was further studied, which indicates that hydrophobic and electrostatic interaction work together to facilitate the universal and efficient enrichment of proteins. Human plasma sample was employed to further evaluate the enrichment performance of Fe 3 O 4 -CS@G. Eventually, 123 proteins were identified from one of SAX fractions of human plasma, which is much better than commercial Sep-pak C18 enrichment column (39 proteins). All these outstanding performances suggest that Fe 3 O 4 -CS@G is an ideal platform for the enrichment of low-abundance intact proteins and thus holds great potential to facilitate the identification of biomarkers from biological samples in proteomics research. Copyright © 2017 Elsevier B.V. All rights reserved.

  19. Chemical Composition of Vermicompost Made from Organic Wastes through the Vermicomposting and Composting with the Addition of Fish Meal and Egg Shells Flour

    Directory of Open Access Journals (Sweden)

    Nurhidayati

    2017-05-01

    Full Text Available Chemical composition of compost is an important indicator that determines the quality of compost. This study compared the chemical composition of vermicompost resulting from the process of vermicomposting alone with combined vermicomposting and composting with addition of egg shells flour and fish meal. Organic wastes used were the mixture of spent mushrooms waste, coconut husks, cow dung, vegetables residue, and leaf litter. Lumbricus rubellus was the species of earthworm used in the vermicomposting process. In the composting process, egg shells flour and fish meal are added into the vermicompost as additives materials. The results indicate that the combined vermicomposting and composting process with addition the additives materials improves the chemical composition of vermicompost compared to using vermicomposting process alone. The change of chemical composition was indicated by a decrease in C-organic content and C/N ratio by 29% and 99%, respectively, while the content of N, P, K and S increased by 52%, 67.5%, 29% and 25%, respectively due to the addition of additives material in the composting process. The largest increase of vermicompost nutrient content occurred in the Ca content by an average of up to 7-fold. While polyphenols, lignin and cellulose content of vermicompost decreased slightly. The treatment of two mixture (a spent mushrooms waste, cow dung and vegetables residue, and (b spent mushroom waste, cow dung, vegetables residue, and leaf litter gave the best chemical composition. However, to determine the quality, we need to test the product in a plant growth bioassay as a follow-up study.

  20. Fabrication of magnetic carbon composites from peanut shells and its application as a heterogeneous Fenton catalyst in removal of methylene blue

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, Lincheng, E-mail: zhoulc@lzu.edu.cn; Ma, Junjun; Zhang, He; Shao, Yanming; Li, Yanfeng

    2015-01-01

    Graphical abstract: Peanut shell magnetic carbon (PMC) were fabricated by carbonized the mixture of peanut shells and (NH{sub 4}){sub 3}Fe(C{sub 2}O{sub 4}){sub 3}. The obtained PMC exhibit high efficiency in catalysis oxidation methylene blue with the help of K{sub 2}S{sub 2}O{sub 8} and it can be easily separated from aqueous by external magnetic field. Meanwhile, the catalyst can be reused for seven times almost without decreased of activity. - Highlights: • Novel peanut shell magnetic carbon (PMC) catalysts were successfully synthesized. • PMC exhibited superior activity as a heterogeneous Fenton-like catalyst. • A high efficient Fenton-like system was set up for removal MB. • PMC posed excellent catalysis oxidation quality, stability and good reusability. - Abstract: Magnetic carbons were prepared from agricultural waste peanut shells and Ferric ammonium oxalate via a simple impregnation and carbonization process. The obtained composites were characterized by element analysis, MÖssbauer spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, X-ray diffraction, vibrating sample magnetometry and the Brunauer-Emmett-Teller surface area method, respectively. The magnetic carbon material was used as catalyst of heterogeneous Fenton reaction to remove methylene blue with the help of persulfate in waste water. The results indicated that both the removal rate and removal efficiency of this catalytic system are very excellent. The degradation efficiency was best (90% within 30 min) using initial concentrations of 0.5 g L{sup −1} persulfate and 40 mg L{sup −1} methylene blue. The removal mechanism was investigated by LC-MS. The catalyst retained its activity after seven reuses, indicating its good stability and reusability. It is inexpensive because it consists mainly of agricultural waste. Its porosity contributed to its high activity, which was achieved without any additional activation process. These indicating that the catalyst is

  1. A facile method for preparing porous, optically active, magnetic Fe3 O4 @poly(N-acryloyl-leucine) inverse core/shell composite microspheres.

    Science.gov (United States)

    Liu, Dong; Deng, Jianping; Yang, Wantai

    2014-01-01

    The first synthesis of porous, optically active, magnetic Fe3 O4 @poly(N-acryloyl-leucine) inverse core/shell composite microspheres is reported, in which the core is constructed of chiral polymer and the shell is constructed of Fe3 O4 NPs. The microspheres integrate three significant concepts, "porosity", "chirality", and "magneticity", in one single microspheric entity. The microspheres consist of Fe3 O4 nanoparticles and porous optically active microspheres, and thus combine the advantages of both magnetic nanoparticles and porous optically active microspheres. The pore size and specific surface area of the microspheres are characterized by N2 adsorption, from which it is found that the composite microspheres possess a desirable porous structure. Circular dichroism and UV-vis absorption spectroscopy measurements demonstrate that the microspheres exhibit the expected optical activity. The microspheres also have high saturation magnetization of 14.7 emu g(-1) and rapid magnetic responsivity. After further optimization, these novel microspheres may potentially find applications in areas such as asymmetric catalysis, chiral adsorption, etc. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Influence of Glycidyl Methacrylate Grafting on the Mechanical, Water Absorption, and Thermal Properties of Recycled High-Density Polyethylene/Rubber Seed Shell Particle Composites

    Directory of Open Access Journals (Sweden)

    Kaimeng Xu

    2016-01-01

    Full Text Available Rubber seed shell (RSS was modified by grafting treatment using glycidyl methacrylate (GMA at various concentrations. The RSS was then used to reinforce high-density polyethylene (HDPE. The effects of modification on the mechanical, water absorption, and thermal properties of the RSS/HDPE composites were studied using a mechanical testing instrument, weighing method, Vicat softening temperature (VST testing, thermogravimetry, and dynamic mechanical analysis. The results showed that the GMA grafting produced an improvement in the flexural and tensile properties of the composites. The water absorption rate of the composites also had an obvious decrease. While a slight increase in VST was found, the various concentrations of GMA showed no improvement in VST. GMA modification also could elevate the thermal stability of the composites at the initial decomposition stage. The optimum grafting concentration of GMA (2.5% led to the lowest thermal weight loss (37.07% and 26.56% during the first and second decomposition stages. The E’ values of the composites had a significant increase with the addition of GMA. There were two peaks of tan δ for the untreated samples, but the modified samples exhibited a shift in the transition peak at higher temperatures; moreover, the second peak disappeared.

  3. Methane explosion suppression characteristics based on the NaHCO3/red-mud composite powders with core-shell structure.

    Science.gov (United States)

    Wang, Yan; Cheng, Yi-Shen; Yu, Ming-Gao; Li, Yao; Cao, Jian-Liang; Zheng, Li-Gang; Yi, Hong-Wei

    2017-08-05

    The NaHCO 3 /red-mud (RM) composite powders were successfully prepared by the solvent-anti-solvent method for methane explosion suppression. The RM was used as a carrier, and the NaHCO 3 was used as a loaded inhibitor. The NaHCO 3 /RM composite powders showed a special core-shell structure and excellent endothermic performance. The suppression properties of NaHCO 3 /RM composite for 9.5% CH 4 explosion were tested in a 20L spherical explosion vessel and a 5L Perspex duct. The results showed that the NaHCO 3 /RM composite powders displayed a much better suppression property than the pure RM or NaHCO 3 powders. The loading amount of NaHCO 3 has an intensive influence on the inhibition property of NaHCO 3 /RM composite powders. The best loaded content of NaHCO 3 is 35%. It exhibited significant inhibitory effect that the explosion max-pressure declined 44.9%, the max-pressure rise rate declined 96.3% and the pressure peak time delayed 366.7%, respectively. Copyright © 2017 Elsevier B.V. All rights reserved.

  4. Hydrogen storage and hydrolysis properties of core-shell structured Mg-MFx (M=V, Ni, La and Ce) nano-composites prepared by arc plasma method

    Science.gov (United States)

    Mao, Jianfeng; Zou, Jianxin; Lu, Chong; Zeng, Xiaoqin; Ding, Wenjiang

    2017-10-01

    In this work, core-shell structured Mg-MFx (M = V, Ni, La and Ce) nano-composites are prepared by using arc plasma method. The particle size distribution, phase components, microstructures, hydrogen sorption properties of these composites and hydrolysis properties of their corresponding hydrogenated powders are carefully investigated. It is shown that the addition of MFx through arc plasma method can improve both the hydrogen absorption kinetics of Mg and the hydrolysis properties of corresponding hydrogenated powders. Among them, the Mg-NiF2 composite shows the best hydrogen absorption properties at relatively low temperatures, which can absorb 3.26 wt% of H2 at 373 K in 2 h. Such rapid hydrogen absorption rate is mainly due to the formation of Mg2Ni and MgF2 on Mg particles during arc evaporation and condensation. In contrast, measurements also show that the hydrogenated Mg-VF3 composite has the lowest peak desorption temperature and the fastest hydrolysis rate among all the hydrogenated Mg-MFx composites. The less agglomeration tendency of Mg particles and VO2 covered on MgH2 particles account for the reduced hydrogen desorption temperature and enhanced hydrolysis rate.

  5. Quasi-conical centrifugal ion trap

    International Nuclear Information System (INIS)

    Golikov, Yu.K.; Solov'ev, K.V.; Grigor'ev, D.V.; Flegontova, E.Yu.

    1999-01-01

    This paper describes a new excellent ion trap that principally differs from the classic hyperbolic one by its action. The action is based on the axisymmetric electrostatic quasi-conical field with the following potential type: F=F 0 [ln r - r 2 /2+z 2 ], where r, z are cylindrical dimensionless coordinates. The radial potential run (f=ln r-r 2 /2), in this case, is exactly presented by the approximation function f a =ar 2 +b/r 2 +c. In addition, there are some ranges of r (for example, 0.6< r<0.35), in which the concurrence accuracy value is above 0.5%. The paper presents the theory of particles dynamics in the centrifugal trap. Basic correlation for resolution ratios and sensitivity values are developed. Recommendations on the centrifugal trap design implementation, including the recording system, are given

  6. Dirac operator on spaces with conical singularities

    International Nuclear Information System (INIS)

    Chou, A.W.

    1982-01-01

    The Dirac operator on compact spaces with conical singularities is studied via the separation of variables formula and the functional calculus of the Dirac Laplacian on the cone. A Bochner type vanishing theorem which gives topological obstructions to the existence of non-negative scalar curvature k greater than or equal to 0 in the singular case is proved. An index formula relating the index of the Dirac operator to the A-genus and Eta-invariant similar to that of Atiyah-Patodi-Singer is obtained. In an appendix, manifolds with boundary with non-negative scalar curvature k greater than or equal to 0 are studied, and several new results on constructing complete metrics with k greater than or equal to on them are obtained

  7. Hypervelocity jets from conical hollow-charges

    International Nuclear Information System (INIS)

    Velarde, P. M.; Martinez-Val, J. M.; Eliezer, S.; Piera, M.; Guillen, J.; Cobo, M. D.; Ogando, F.; Crisol, A.; Gonzalez, L.; Prieto, J.; Velarde, G.

    1997-01-01

    In this article the formation of jets by means of the implosion of conical targets is analyzed. This implosion might be induced by high intensity lasers or X rays. It is known of experiments with explosive and numeric simulations that the formation of jets depends critically on the aperture of the cone. It is found in these simulations that for a given collapsing speed an angle of the cone exists below which jet doesn't take place. This critical angle grows with the collapsing speed. The numerical simulations seem to indicate that the production of jets is related to the separation of the shock wave that takes place in the collapsing region. We will also analyze the mass and kinetic energy of the jets taken place as a function of the initial opening of the cone

  8. Conically scanning lidar error in complex terrain

    Directory of Open Access Journals (Sweden)

    Ferhat Bingöl

    2009-05-01

    Full Text Available Conically scanning lidars assume the flow to be homogeneous in order to deduce the horizontal wind speed. However, in mountainous or complex terrain this assumption is not valid implying a risk that the lidar will derive an erroneous wind speed. The magnitude of this error is measured by collocating a meteorological mast and a lidar at two Greek sites, one hilly and one mountainous. The maximum error for the sites investigated is of the order of 10 %. In order to predict the error for various wind directions the flows at both sites are simulated with the linearized flow model, WAsP Engineering 2.0. The measurement data are compared with the model predictions with good results for the hilly site, but with less success at the mountainous site. This is a deficiency of the flow model, but the methods presented in this paper can be used with any flow model.

  9. Triple layered core–shell structure with surface fluorinated ZnO-carbon nanotube composites and its electron emission properties

    International Nuclear Information System (INIS)

    Wang, H.Y.; Chua, Daniel H.C.

    2013-01-01

    Highlights: ► The effects of CF 4 plasma on ZnO-CNT core–shell structures were studied. ► ZnO was effective in protecting the aligned CNTs core for as long as 30 min of plasma etching. ► SEM showed the surface morphology was nearly similar between pristine, 2 min and 30 min plasma etched specimens. ► F was observed to displace O in ZnO. ► This is the first report of an ultra long plasma etch of fluorine onto ZnO surface. - Abstract: Core-shelled structures such as zinc oxide (ZnO) on carbon nanotubes (CNTs) give rise to interesting material properties. In this work, a triple-layered core–shell–shell structure is presented where the effects of fluorine (F) incorporation on the outmost shell of the ZnO-CNT structure are studied. The samples prepared ranged from a short 2 min to a 30 min immersion in carbon tetraflouride (CF 4 ) plasma. In addition, its effects on the electron emission properties also studied and it is shown that the plasma immersions create thinner field emitters with sharp tiny wrinkles giving rise to more electron emission sites and higher enhancement factor. In addition, X-ray photoelectron spectroscopy measurements showed that F ions replace O in ZnO coatings during immersion process, thus increasing the electrical conductivity and shifts the Fermi level of ZnO upwards. Both physical and electronic effects further contribute to a lower threshold field.

  10. A highly conspicuous mineralized composite photonic architecture in the translucent shell of the blue-rayed limpet

    OpenAIRE

    Li, Ling; Kolle, Stefan; Weaver, James C.; Ortiz, Christine; Aizenberg, Joanna; Kolle, Mathias

    2015-01-01

    Many species rely on diverse selections of entirely organic photonic structures for the manipulation of light and the display of striking colours. Here we report the discovery of a mineralized hierarchical photonic architecture embedded within the translucent shell of the blue-rayed limpet Patella pellucida. The bright colour of the limpet’s stripes originates from light interference in a periodically layered zig-zag architecture of crystallographically co-oriented calcite lamellae. Beneath t...

  11. Arrays of ZnO/CuIn{sub x}Ga{sub 1−x}Se{sub 2} nanocables with tunable shell composition for efficient photovoltaics

    Energy Technology Data Exchange (ETDEWEB)

    Akram, Muhammad Aftab; Javed, Sofia [Center of Super-Diamond and Advanced Films (COSDAF), Department of Physics and Materials Science, City University of Hong Kong, Hong Kong (Hong Kong); City University of Hong Kong, Shenzhen Research Institute, Shenzhen 518057 (Hong Kong); School of Chemical and Materials Engineering, National University of Sciences and Technology, Sector H-12, Islamabad 44000 (Pakistan); Xu, Jun, E-mail: apjunxu@hfut.edu.cn [School of Electronic Science and Applied Physics, Hefei University of Technology, Hefei 230009 (China); Mujahid, Mohammad, E-mail: principal@scme.nust.edu.pk [School of Chemical and Materials Engineering, National University of Sciences and Technology, Sector H-12, Islamabad 44000 (Pakistan); Lee, Chun-Sing, E-mail: c.s.lee@cityu.edu.hk [Center of Super-Diamond and Advanced Films (COSDAF), Department of Physics and Materials Science, City University of Hong Kong, Hong Kong (Hong Kong); City University of Hong Kong Shenzhen Research Institute, Shenzhen 518057 (Hong Kong)

    2015-05-28

    Arrays of one-dimensional (1D) nanostructure are receiving much attention for their optoelectronic and photovoltaic applications due to their advantages in light absorption, charge separation, and transportation. In this work, arrays of ZnO/CuIn{sub x}Ga{sub 1−x}Se{sub 2} core/shell nanocables with tunable shell compositions over the full range of 0 ≤ x ≤ 1 have been controllably synthesized. Chemical conversions of ZnO nanorods to a series of ZnO-based nanocables, including ZnO/ZnSe, ZnO/CuSe, ZnO/CuSe/In{sub x}Ga{sub 1−x}, ZnO/CuSe/(In{sub x}Ga{sub 1−x}){sub 2}Se{sub 3}, and ZnO/CuIn{sub x}Ga{sub 1−x}Se{sub 2}, are well designed and successfully achieved. Composition-dependent influences of the CuIn{sub x}Ga{sub 1−x}Se{sub 2} shells on photovoltaic performance are investigated. It is found that the increase in indium content (x) leads to an increase in short-circuit current density (J{sub SC}) but a decrease in open-circuit voltage (V{sub OC}) for the ZnO/CuIn{sub x}Ga{sub 1−x}Se{sub 2} nanocable solar cells. An array of ZnO/CuIn{sub 0.67}Ga{sub 0.33}Se{sub 2} nanocables with a length of ∼1 μm and a shell thickness of ∼10 nm exhibits a bandgap of 1.20 eV, and yields a maximum power conversion efficiency of 1.74% under AM 1.5 G illumination at an intensity of 100 mW/cm{sup 2}. It dramatically surpasses that (0.22%) of the ZnO/CuIn{sub 0.67}Ga{sub 0.33}Se{sub 2} planar thin-film device. Our work reveals that 1D nanoarray allows efficient photovoltaics without using toxic CdS buffer layer.

  12. Arrays of ZnO/CuInxGa1−xSe2 nanocables with tunable shell composition for efficient photovoltaics

    International Nuclear Information System (INIS)

    Akram, Muhammad Aftab; Javed, Sofia; Xu, Jun; Mujahid, Mohammad; Lee, Chun-Sing

    2015-01-01

    Arrays of one-dimensional (1D) nanostructure are receiving much attention for their optoelectronic and photovoltaic applications due to their advantages in light absorption, charge separation, and transportation. In this work, arrays of ZnO/CuIn x Ga 1−x Se 2 core/shell nanocables with tunable shell compositions over the full range of 0 ≤ x ≤ 1 have been controllably synthesized. Chemical conversions of ZnO nanorods to a series of ZnO-based nanocables, including ZnO/ZnSe, ZnO/CuSe, ZnO/CuSe/In x Ga 1−x , ZnO/CuSe/(In x Ga 1−x ) 2 Se 3 , and ZnO/CuIn x Ga 1−x Se 2 , are well designed and successfully achieved. Composition-dependent influences of the CuIn x Ga 1−x Se 2 shells on photovoltaic performance are investigated. It is found that the increase in indium content (x) leads to an increase in short-circuit current density (J SC ) but a decrease in open-circuit voltage (V OC ) for the ZnO/CuIn x Ga 1−x Se 2 nanocable solar cells. An array of ZnO/CuIn 0.67 Ga 0.33 Se 2 nanocables with a length of ∼1 μm and a shell thickness of ∼10 nm exhibits a bandgap of 1.20 eV, and yields a maximum power conversion efficiency of 1.74% under AM 1.5 G illumination at an intensity of 100 mW/cm 2 . It dramatically surpasses that (0.22%) of the ZnO/CuIn 0.67 Ga 0.33 Se 2 planar thin-film device. Our work reveals that 1D nanoarray allows efficient photovoltaics without using toxic CdS buffer layer

  13. Chemical synthesis of Fe/Fe{sub 3}O{sub 4} core-shell composites with enhanced soft magnetic performances

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Bai, E-mail: byang@buaa.edu.cn [Key Laboratory of Aerospace Advanced Materials and Performance, Ministry of Education, School of Materials Science and Engineering, Beihang University, Beijing 100191 (China); Li, Xiaopan [Key Laboratory of Aerospace Advanced Materials and Performance, Ministry of Education, School of Materials Science and Engineering, Beihang University, Beijing 100191 (China); Yang, Xueying [Hi-tech Industry Standardization Institute, Hubei Standardization and Quality Institution, Wuhan 430061 (China); Yu, Ronghai [Key Laboratory of Aerospace Advanced Materials and Performance, Ministry of Education, School of Materials Science and Engineering, Beihang University, Beijing 100191 (China)

    2017-04-15

    The large-grain Fe/Fe{sub 3}O{sub 4} composite particles with average size of about 1.2 µm have been fabricated by a facile one-step solvothermal method. The formation of high-purity Fe{sub 3}O{sub 4} as the shells (90.14 wt%) and α-Fe as the cores (9.86 wt%) in the Fe/Fe{sub 3}O{sub 4} composites leads to their high saturation magnetization of 119.6 A m{sup 2} Kg{sup -1}. Very low coercivity of 30 Oe is obtained in the composites due to their uniform cubic-shaped morphologies. Compared with Fe-based nanosized particles, these micron-sized magnetic Fe/Fe{sub 3}O{sub 4} composites exhibit high air stability and good compactibility with high compressed density of 5.9 g cm{sup -3}. The fully compacted sample shows good soft magnetic properties including high magnetic induction B{sub 1.2k} {sub (H=1200} {sub A/m)} of 540 mT and good frequency-dependent magnetic properties with operating frequency up to 50 MHz superior to those of the most traditional soft magnetic ferrites, which promotes their potential applications in high-frequency and high-power magnetic devices. - Highlights: • Micron-sized Fe/Fe{sub 3}O{sub 4} composites are prepared by a one-step solvothermal method. • High saturation magnetization and low coercivity are obtained in the composites. • Good air stability and high bulk density occurs in the composites. • High magnetic induction and good frequency-dependent properties are achieved.

  14. Rational Construction of Uniform CoNi-Based Core-Shell Microspheres with Tunable Electromagnetic Wave Absorption Properties.

    Science.gov (United States)

    Chen, Na; Jiang, Jian-Tang; Xu, Cheng-Yan; Yan, Shao-Jiu; Zhen, Liang

    2018-02-16

    Core-shell particles with integration of ferromagnetic core and dielectric shell are attracting extensive attention for promising microwave absorption applications. In this work, CoNi microspheres with conical bulges were synthesized by a simple and scalable liquid-phase reduction method. Subsequent coating of dielectric materials was conducted to acquire core-shell structured CoNi@TiO 2 composite particles, in which the thickness of TiO 2 is about 40 nm. The coating of TiO 2 enables the absorption band of CoNi to effectively shift from K u to S band, and endows CoNi@TiO 2 microspheres with outstanding electromagnetic wave absorption performance along with a maximum reflection loss of 76.6 dB at 3.3 GHz, much better than that of bare CoNi microspheres (54.4 dB at 17.8 GHz). The enhanced EMA performance is attributed to the unique core-shell structures, which can induce dipole polarization and interfacial polarization, and tune the dielectric properties to achieve good impedance matching. Impressively, TiO 2 coating endows the composites with better microwave absorption capability than CoNi@SiO 2 microspheres. Compared with SiO 2 , TiO 2 dielectric shells could protect CoNi microspheres from merger and agglomeration during annealed. These results indicate that CoNi@TiO 2 core-shell microspheres can serve as high-performance absorbers for electromagnetic wave absorbing application.

  15. Chitosan mediated synthesis of core/double shell ternary polyaniline/Chitosan/cobalt oxide nano composite-as high energy storage electrode material in supercapacitors

    International Nuclear Information System (INIS)

    Vellakkat, Mini; Hundekkal, Devendrappa

    2016-01-01

    Nanostructured ternary composite of polyaniline (PANI), Co 3 O 4 nanoparticles, and Chitosan (CS) has been prepared by an in situ chemical oxidation method, and the nanocomposites (CPAESCO) were used as supercapacitor electrodes. The Co 3 O 4 nanoparticles are uniformly coated with CS and PANI layers in it. Different techniques (Fourier transform infrared spectrophotometry, x-ray diffraction, thermal gravimetric analysis, UV−visible spectroscopy, scanning electron microscopy, transmission electron microscopy and electro chemical analysis-cyclic voltammetry, galvanostatic charge/discharge (GCD), and electrochemical impedance spectroscopy) were used to analyse the optical, structural, thermal, chemical and supercapacitive aspects of the nanocomposites. Core/double shell ternary composite electrode exhibits significantly increased specific capacitance than PANI/Co 3 O 4 or PANI/CS binary composites in supercapacitors. The ternary nanocomposite with 40% nanoparticle exhibits a highest specific capacitance reaching 687 F g −1 , Energy density of (95.42 Wh kg −1 at 1 A g −1 ) and power density of (1549 W kg −1 at 3 A g −1 ) and outstanding cycling performance, with, 91% capacitance retained over 5000 cycles. It is found that this unique bio compatible nano composite with synergy is a new multifunctional material which will be useful in the design of supercapacitor electrodes and other energy conversion devices too. (paper)

  16. Adsorption of Pb(II) using silica gel composite from rice husk ash modified 3-aminopropyltriethoxysilane (APTES)-activated carbon from coconut shell

    Science.gov (United States)

    Yusmaniar, Purwanto, Agung; Putri, Elfriyana Awalita; Rosyidah, Dzakiyyatur

    2017-03-01

    Silica gel modified by 3-aminopropyltriethoxysilane (APTES) was synthesized from rice husk ash combined with activated carbon from coconut shell yielded the composite adsorbent. The composite was characterized by Fourier Transform Infra Red spectroscopy (FT-IR), Electron Dispersive X-Ray (EDX), Surface Area Analyzer (SAA) and adsorption test by Atomic Absorption Spectrometry (AAS). This composite adsorbent has been used moderately for the removal of lead ions from metal solutions and compared with silica gel modified APTES and activated carbon. The adsorption experiments of Pb -ions by adsorbents were performed at different pH and contact time with the same metal solutions concentration, volume solution, and adsorbent dosage. The optimum pH for the adsorption was found to be 5.0 and the equilibrium was achieved for Pb with 20 min of contact time. Pb ions adsorption by composite silica gel modified APTES-activated carbon followed by Langmuir isotherm model with qmax value of 46.9483 mg/g that proved an adsorbent mechanism consistent to the mechanism of monolayer formation.

  17. Interfacial effect on physical properties of composite media: Interfacial volume fraction with non-spherical hard-core-soft-shell-structured particles.

    Science.gov (United States)

    Xu, Wenxiang; Duan, Qinglin; Ma, Huaifa; Chen, Wen; Chen, Huisu

    2015-11-02

    Interfaces are known to be crucial in a variety of fields and the interfacial volume fraction dramatically affects physical properties of composite media. However, it is an open problem with great significance how to determine the interfacial property in composite media with inclusions of complex geometry. By the stereological theory and the nearest-surface distribution functions, we first propose a theoretical framework to symmetrically present the interfacial volume fraction. In order to verify the interesting generalization, we simulate three-phase composite media by employing hard-core-soft-shell structures composed of hard mono-/polydisperse non-spherical particles, soft interfaces, and matrix. We numerically derive the interfacial volume fraction by a Monte Carlo integration scheme. With the theoretical and numerical results, we find that the interfacial volume fraction is strongly dependent on the so-called geometric size factor and sphericity characterizing the geometric shape in spite of anisotropic particle types. As a significant interfacial property, the present theoretical contribution can be further drawn into predicting the effective transport properties of composite materials.

  18. A generic double-curvature piezoelectric shell energy harvester: Linear/nonlinear theory and applications

    Science.gov (United States)

    Zhang, X. F.; Hu, S. D.; Tzou, H. S.

    2014-12-01

    Converting vibration energy to useful electric energy has attracted much attention in recent years. Based on the electromechanical coupling of piezoelectricity, distributed piezoelectric zero-curvature type (e.g., beams and plates) energy harvesters have been proposed and evaluated. The objective of this study is to develop a generic linear and nonlinear piezoelectric shell energy harvesting theory based on a double-curvature shell. The generic piezoelectric shell energy harvester consists of an elastic double-curvature shell and piezoelectric patches laminated on its surface(s). With a current model in the closed-circuit condition, output voltages and energies across a resistive load are evaluated when the shell is subjected to harmonic excitations. Steady-state voltage and power outputs across the resistive load are calculated at resonance for each shell mode. The piezoelectric shell energy harvesting mechanism can be simplified to shell (e.g., cylindrical, conical, spherical, paraboloidal, etc.) and non-shell (beam, plate, ring, arch, etc.) distributed harvesters using two Lamé parameters and two curvature radii of the selected harvester geometry. To demonstrate the utility and simplification procedures, the generic linear/nonlinear shell energy harvester mechanism is simplified to three specific structures, i.e., a cantilever beam case, a circular ring case and a conical shell case. Results show the versatility of the generic linear/nonlinear shell energy harvesting mechanism and the validity of the simplification procedures.

  19. Reliability of shell carbon isotope composition of different land snail species as a climate proxy: A case study in the monsoon region of China

    Science.gov (United States)

    Bao, Rui; Sheng, Xuefen; Teng, Henry H.; Ji, Junfeng

    2018-05-01

    Carbon isotope compositions of land snail shells (δ13Cshell) are shown to be indicative of local climate conditions. However, it is largely unknown how the responses of δ13Cshell to climatic factors changes amongst different species. In this study, we collected 3 species of land snail shells across the East Asian monsoon region of China to explore the overall relationship between δ13Cshell as well as the response of individual species to the regional climate. Results show that, whereas all species collectively can provide a consensus relation between δ13Cshell and local climatic factors such as temperature and precipitation; the response of individual species to the fluctuations of these factors is not uniform. Specifically, while the southerly species Bradybaena similaris exhibits robust δ13Cshell - mean precipitation correlation in both linearity and sensitivity, a common northerly species, Cathaica fasciola, only finds limited utility as a climate indicator, particularly for precipitation. Meanwhile, the south-central species Acusta ravida appears to be able to faithfully record past climate conditions despite showing a wider distribution and a broader habitat. Such species-dependent nature in the relations between δ13Cshell and local climatic factors can be attributed to the effect of ingested carbonate and variations in eco-physiological factors of different species, and is expected to be widespread, suggesting the need to be taken into consideration for future studies.

  20. MoS2/Ni3S4 composite nanosheets on interconnected carbon shells as an excellent supercapacitor electrode architecture for long term cycling at high current densities

    Science.gov (United States)

    Qin, Shengchun; Yao, Tinghui; Guo, Xin; Chen, Qiang; Liu, Dequan; Liu, Qiming; Li, Yali; Li, Junshuai; He, Deyan

    2018-05-01

    In this paper, we report an electrode architecture of molybdenum disulfide (MoS2)/nickel sulfide (Ni3S4) composite nanosheets anchored on interconnected carbon (C) shells (C@MoS2/Ni3S4). Electrochemical measurements indicate that the C@MoS2/Ni3S4 structure possesses excellent supercapacitive properties especially for long term cycling at high current densities. A specific capacitance as high as ∼640.7 F g-1 can still be delivered even after 10,000 cycles at a high current density of 20 A g-1. From comparison of microstructures and electrochemical properties of the related materials/structures, the improved performance of C@MoS2/Ni3S4 can be attributed to the relatively dispersedly distributed nanosheet-shaped MoS2/Ni3S4 that provides efficient contact with electrolyte and effectively buffers the volume change during charge/discharge processes, enhanced cycling stability by MoS2, and reduced equivalent series resistance by the interconnected C shells.

  1. Investigation of dosimetric characteristics of a core-shell quantum dots nano composite (CdTe/CdS/PMMA): fabrication of a new gamma sensor

    Science.gov (United States)

    Feizi, Shahzad; Zare, Hakimeh; Hoseinpour, Masoumeh

    2018-06-01

    CdTe/CdS-PMMA nanocomposite was prepared using dispersion of CdTe/CdS core-shell quantum dots (QDs) in poly methyl methacrylate (PMMA) polymer matrix. High-quality CdTe/CdS core/shell quantum dots were synthesized in aqueous solution and were transferred from water to chloroform using ligand-exchange process in the presence of 1-dodecanethiol (1-DDT). Transmission electron microscopy analysis reveals that the obtained nano-particles are highly crystalline nature with mean diameter of 3.6 nm. To prepare an ohmic contact detector, a conductive cell with two silver coated walls was designed and fabricated for exploring gamma detecting properties of the nano composite. New detector was assessed for the linearity of doserate response, angular dependence, sensitivity and repeatability. The results show that the dose rate response of the prepared sensor is linear in the dose rate range of 50-145 mGy/min. So this nanocomposite can be utilized as a potential gamma sensor in the medical radiation device design.

  2. Al2O3 - TiO2-A simple sol-gel strategy to the synthesis of low temperature sintered alumina-aluminium titanate composites through a core-shell approach

    International Nuclear Information System (INIS)

    Jayasankar, M.; Ananthakumar, S.; Mukundan, P.; Wunderlich, W.; Warrier, K.G.K.

    2008-01-01

    A simple sol-gel based core-shell approach for the synthesis of alumina-aluminium titanate composite is reported. Alumina is the core and titania is the shell. The coating of titania has been performed in aqueous medium on alumina particle by means of heterocoagulation of titanyl chloride. Further heat treatment results in low temperature formation of aluminium titanate as well as low temperature sintering of alumina-aluminium titanate composites. The lowering of the reaction temperature can be attributed to the maximisation of the contact surface between the reactants due to the core-shell approach involving nanoparticles. The mechanism of formation of aluminium titanate and the observations on densification features in the present process are compared with that of mixture of oxides under identical conditions. The sintered alumina-aluminium titanate composite has an average grain size of 2 μm. - Graphical abstract: The article presents a simple sol-gel process through core-shell approach to the synthesis of low temperature sintered alumina-aluminium titanate. The lowering of the reaction temperature can be attributed to the maximisation of the contact surface between the reactant due to the core-shell approach. This material showed the better microstructure control compared to the standard solid-state mixing route

  3. Fabrication of hydrogel-coated single conical nanochannels exhibiting controllable ion rectification characteristics.

    Science.gov (United States)

    Wang, Linlin; Zhang, Huacheng; Yang, Zhe; Zhou, Jianjun; Wen, Liping; Li, Lin; Jiang, Lei

    2015-03-07

    Heterogeneous nanochannel materials that endow new functionalities different to the intrinsic properties of two original nanoporous materials have wide potential applications in nanofluidics, energy conversion, and biosensors. Herein, we report novel, interesting hydrogel-composited nanochannel devices with regulatable ion rectification characteristics. The heterogeneous nanochannel devices were constructed by selectively coating the tip side, base side, or both sides of a single conical nanochannel membrane with thin agar hydrogel layers. The tunable ion current rectification of the nanochannels in the three different coating states was systematically demonstrated by current-voltage (I-V) curves. The asymmetric ionic transport property of the conical nanochannel was further strengthened in the tip-coating state and weakened in the base-coating state, whereas the conical nanochannel showed nearly symmetric ionic transport in the dual-coating state. Repeated experiments presented insight into the good stability and reversibility of the three coating states of the hydrogel-nanochannel-integrated systems. This work, as an example, may provide a new strategy to further design and develop multifunctional gel-nanochannel heterogeneous smart porous nanomaterials.

  4. Use of LS-DYNA(Registered TradeMark) to Assess the Energy Absorption Performance of a Shell-Based Kevlar(TradeMark)/Epoxy Composite Honeycomb

    Science.gov (United States)

    Polanco, Michael

    2010-01-01

    The forward and vertical impact stability of a composite honeycomb Deployable Energy Absorber (DEA) was evaluated during a full-scale crash test of an MD-500 helicopter at NASA Langley?s Landing and Impact Research Facility. The lower skin of the helicopter was retrofitted with DEA components to protect the airframe subfloor upon impact and to mitigate loads transmitted to Anthropomorphic Test Device (ATD) occupants. To facilitate the design of the DEA for this test, an analytical study was conducted using LS-DYNA(Registered TradeMark) to evaluate the performance of a shell-based DEA incorporating different angular cell orientations as well as simultaneous vertical and forward impact conditions. By conducting this study, guidance was provided in obtaining an optimum design for the DEA that would dissipate the kinetic energy of the airframe while maintaining forward and vertical impact stability.

  5. Early structure of LPG partially premixed conically stabilized flames

    KAUST Repository

    Elbaz, Ayman M.

    2013-01-01

    This paper presents experimental investigation of LPG partially premixed turbulent flames stabilized within a conical nozzle burner under constant degree of partial premixing. The stability limits and mean flame structure are presented based

  6. Vortex breakdown in a truncated conical bioreactor

    Energy Technology Data Exchange (ETDEWEB)

    Balci, Adnan; Brøns, Morten [DTU Compute, Technical University of Denmark, DK-2800 Kgs. Lyngby (Denmark); Herrada, Miguel A [E.S.I, Universidad de Sevilla, Camino de los Descubrimientos s/n, E-41092 (Spain); Shtern, Vladimir N, E-mail: mobr@dtu.dk [Shtern Research and Consulting, Houston, TX 77096 (United States)

    2015-12-15

    This numerical study explains the eddy formation and disappearance in a slow steady axisymmetric air–water flow in a vertical truncated conical container, driven by the rotating top disk. Numerous topological metamorphoses occur as the water height, H{sub w}, and the bottom-sidewall angle, α, vary. It is found that the sidewall convergence (divergence) from the top to the bottom stimulates (suppresses) the development of vortex breakdown (VB) in both water and air. At α = 60°, the flow topology changes eighteen times as H{sub w} varies. The changes are due to (a) competing effects of AMF (the air meridional flow) and swirl, which drive meridional motions of opposite directions in water, and (b) feedback of water flow on AMF. For small H{sub w}, the AMF effect dominates. As H{sub w} increases, the swirl effect dominates and causes VB. The water flow feedback produces and modifies air eddies. The results are of fundamental interest and can be relevant for aerial bioreactors. (paper)

  7. Vortex breakdown in a truncated conical bioreactor

    International Nuclear Information System (INIS)

    Balci, Adnan; Brøns, Morten; Herrada, Miguel A; Shtern, Vladimir N

    2015-01-01

    This numerical study explains the eddy formation and disappearance in a slow steady axisymmetric air–water flow in a vertical truncated conical container, driven by the rotating top disk. Numerous topological metamorphoses occur as the water height, H w , and the bottom-sidewall angle, α, vary. It is found that the sidewall convergence (divergence) from the top to the bottom stimulates (suppresses) the development of vortex breakdown (VB) in both water and air. At α = 60°, the flow topology changes eighteen times as H w varies. The changes are due to (a) competing effects of AMF (the air meridional flow) and swirl, which drive meridional motions of opposite directions in water, and (b) feedback of water flow on AMF. For small H w , the AMF effect dominates. As H w increases, the swirl effect dominates and causes VB. The water flow feedback produces and modifies air eddies. The results are of fundamental interest and can be relevant for aerial bioreactors. (paper)

  8. DE 1 and Viking observations associated with electron conical distributions

    Science.gov (United States)

    Menietti, J. D.; Weimer, D. R.; Andre, M.; Eliasson, L.

    1994-01-01

    Data from the electron detectors on board the Swedish Viking satellite launched during a period of low solar activity and from the Dynamic Explorer (DE) 1 satellite launched during active solar coditions have been examined for the occurrence and location of electron conical distributions and several conclusions can be drawn. First, we note that most of the best examples of electron conics observed by the V-3 experiment onboard Viking occurred in the afternoon sector in the range of magneitc local time 14 hours less than Magnetic Local Time (MLT) less than 18 hours, at midaltitudes in the range 10,000 km less than h less than 13,500 km, with few occurring in the nightside auroral region, a region poorly sampled at altitudes greater than 5000 km. For the Viking data there is an association of electron conics with upper hybrid waves. DE 1 observations made by the high-altitude plasma instrument (HAPI) indicate that electron conics were observed in the midmorning sector and the late evening sector, and as has been reported earlier, the correlation with upper hybird waves was good. The HAPI did not sample the afternoon sector. The electon conics observed on both satellites occurred in the presence of at least a modest (several kilovolts) potential difference beneath the satellite with a maximum energy that was usually, but not always, equal to or greater than the maximum energy of the electron conics. Two independent sets of observations by DE 1 suggest two distinct production mechanisms for electron conics. Examiniation of DE 1 electric field measurements from the plasma wave instrument during the observation of electron conics show simultaneous parallel oscillations in the frequency range of 0.2 Hz less than f less than 0.5 Hz during one and perhaps two of four events examined, and upper hybrid waves were observed on all four events. In addition, recent observations of '90-deg' electron conics associated with auroral kilometric radiation source regions suggest a

  9. Preferential solvation and solvation shell composition of free base and protonated 5, 10, 15, 20-tetrakis(4-sulfonatophenyl)porphyrin in aqueous organic mixed solvents

    Science.gov (United States)

    Farajtabar, Ali; Jaberi, Fatemeh; Gharib, Farrokh

    2011-12-01

    The solvatochromic properties of the free base and the protonated 5, 10, 15, 20-tetrakis(4-sulfonatophenyl)porphyrin (TPPS) were studied in pure water, methanol, ethanol (protic solvents), dimethylsulfoxide, DMSO, (non-protic solvent), and their corresponding aqueous-organic binary mixed solvents. The correlation of the empirical solvent polarity scale ( ET) values of TPPS with composition of the solvents was analyzed by the solvent exchange model of Bosch and Roses to clarify the preferential solvation of the probe dyes in the binary mixed solvents. The solvation shell composition and the synergistic effects in preferential solvation of the solute dyes were investigated in terms of both solvent-solvent and solute-solvent interactions and also, the local mole fraction of each solvent composition was calculated in cybotactic region of the probe. The effective mole fraction variation may provide significant physico-chemical insights in the microscopic and molecular level of interactions between TPPS species and the solvent components and therefore, can be used to interpret the solvent effect on kinetics and thermodynamics of TPPS. The obtained results from the preferential solvation and solvent-solvent interactions have been successfully applied to explain the variation of equilibrium behavior of protonation of TPPS occurring in aqueous organic mixed solvents of methanol, ethanol and DMSO.

  10. Heat transfer behaviors in round tube with conical ring inserts

    International Nuclear Information System (INIS)

    Promvonge, P.

    2008-01-01

    To increase convection heat transfer in a uniform heat flux tube by a passive method, several conical rings used as turbulators are mounted over the test tube. The effects of the conical ring turbulator inserts on the heat transfer rate and friction factor are experimentally investigated in the present work. Conical rings with three different diameter ratios of the ring to tube diameter (d/D = 0.5, 0.6, 0.7) are introduced in the tests, and for each ratio, the rings are placed with three different arrangements (converging conical ring, referred to as CR array, diverging conical ring, DR array and converging-diverging conical ring, CDR array). In the experiment, cold air at ambient condition for Reynolds numbers in a range of 6000-26,000 is passed through the uniform heat flux circular tube. It is found that the ring to tube diameter ratio and the ring arrays provide a significant effect on the thermal performance of the test tube. The experimental results demonstrate that the use of conical ring inserts leads to a higher heat transfer rate than that of the plain surface tube, and the DR array yields a better heat transfer than the others. The results are also correlated in the form of Nusselt number as a function of Reynolds number, Prandtl number and diameter ratio. An augmentation of up to 197%, 333%, and 237% in Nusselt number is obtained in the turbulent flow for the CR, DR and CDR arrays, respectively, although the effect of using the conical ring causes a substantial increase in friction factor

  11. Manufacture of conical springs with elastic medium technology improvement

    Science.gov (United States)

    Kurguzov, S. A.; Mikhailova, U. V.; Kalugina, O. B.

    2018-01-01

    This article considers the manufacturing technology improvement by using an elastic medium in the stamping tool forming space to improve the conical springs performance characteristics and reduce the costs of their production. Estimation technique of disk spring operational properties is developed by mathematical modeling of the compression process during the operation of a spring. A technique for optimizing the design parameters of a conical spring is developed, which ensures a minimum voltage value when operated in the edge of the spring opening.

  12. Improving dielectric properties of BaTiO_3/poly(vinylidene fluoride) composites by employing core-shell structured BaTiO_3@Poly(methylmethacrylate) and BaTiO_3@Poly(trifluoroethyl methacrylate) nanoparticles

    International Nuclear Information System (INIS)

    Zhang, Xianhong; Zhao, Sidi; Wang, Fang; Ma, Yuhong; Wang, Li; Chen, Dong; Zhao, Changwen; Yang, Wantai

    2017-01-01

    Highlights: • Core-shell structured BT@PMMA and BT@PTFEMA nanoparticles were synthesized. • The dispersity of BT nanoparticles in PVDF matrix was improved significantly. • Dielectric properties both of BT@PMMA/PVDF and BT@PTFEMA/PVDF composites were improved. • The frequency dependence of dielectric constant attenuation of BT@PTFEMA/PVDF composites was smaller than that of BT@PMMA/PVDF composites. - Abstract: Polymer based dielectric composites were fabricated through incorporation of core-shell structured BaTiO_3 (BT) nanoparticles into PVDF matrix by means of solution blending. Core-shell structured BT nanoparticles with different shell composition and shell thickness were prepared by grafting methacrylate monomer (MMA or TFEMA) onto the surface of BT nanoparticles via surface initiated atom transfer radical polymerization (SI-ATRP). The content of the grafted polymer and the micro-morphology of the core-shell structured BT nanoparticles were investigated by thermo gravimetric analyses (TGA) and transmission electron microscopy (TEM), respectively. The dielectric properties were measured by broadband dielectric spectroscopy. The results showed that high dielectric constant and low dielectric loss are successfully realized in the polymer based composites. Moreover, the type of the grafted polymer and its content had different effect on the dielectric constant. In detail, the attenuation of dielectric constant was 16.6% for BT@PMMA1/PVDF and 10.7% for BT@PMMA2/PVDF composite in the range of 10 Hz to 100 kHz, in which the grafted content of PMMA was 5.5% and 8.0%, respectively. However, the attenuation of dielectric constant was 5.5% for BT@PTFEMA1/PVDF and 4.0% for BT@PTFEMA2/PVDF composite, in which the grafted content of PTFEMA was 1.5% and 2.0%, respectively. These attractive features of BT@PTFEMA/PVDF composites suggested that dielectric ceramic fillers modified with fluorinated polymer can be used to prepare high performance composites, especially

  13. Initiation of Gaseous Detonation by Conical Projectiles

    Science.gov (United States)

    Verreault, Jimmy

    Initiation and stabilization of detonation by hypersonic conical projectiles launched into combustible gas mixtures is investigated. This phenomenon must be understood for the design and optimization of specific hypersonic propulsion devices, such as the oblique detonation wave engine and the ram accelerator. The criteria for detonation initiation by a projectile is also related to fundamental aspects of detonation research, such as the requirement for direct initiation of a detonation by a blast wave. Experimental results of this problem also offer useful references for validation of numerical and theoretical modeling. Projectiles with cone half angles varying from 15° to 60° were launched into stoichiometric mixtures of hydrogen/oxygen with 70% argon dilution at initial pressures between 10 and 200 kPa. The projectiles were launched from a combustion-driven gas gun at velocities up to 2.2 km/s (corresponding to 133% of the Chapman Jouguet velocity). Pictures of the flowfields generated by the projectiles were taken via Schlieren photography. Five combustion regimes were observed about the projectile ranging from prompt and delayed oblique detonation wave formation, combustion instabilities, a wave splitting, and an inert shock wave. Two types of transition from the prompt oblique detonation wave regime to the inert shock regime were observed. The first (the delayed oblique detonation wave regime) showed an inert shock attached to the tip of the projectile followed by a sharp kink at the onset of an oblique detonation wave; this regime occurred by decreasing the cone angle at high mixture pressures. The second (the combustion instabilities regime) exhibited large density gradients due to combustion ignition and quenching phenomena; this regime occurred by decreasing the mixture pressure at large cone angles. A number of theoretical models were considered to predict critical conditions for the initiation of oblique detonations. The Lee-Vasiljev model agreed

  14. Preparation of Cotton-Wool-Like Poly(lactic acid-Based Composites Consisting of Core-Shell-Type Fibers

    Directory of Open Access Journals (Sweden)

    Jian Wang

    2015-11-01

    Full Text Available In previous works, we reported the fabrication of cotton-wool-like composites consisting of siloxane-doped vaterite and poly(l-lactic acid (SiVPCs. Various irregularly shaped bone voids can be filled with the composite, which effectively supplies calcium and silicate ions, enhancing the bone formation by stimulating the cells. The composites, however, were brittle and showed an initial burst release of ions. In the present work, to improve the mechanical flexibility and ion release, the composite fiber was coated with a soft, thin layer consisting of poly(d,l-lactic-co-glycolic acid (PLGA. A coaxial electrospinning technique was used to prepare a cotton-wool-like material comprising “core-shell”-type fibers with a diameter of ~12 µm. The fibers, which consisted of SiVPC coated with a ~2-µm-thick PLGA layer, were mechanically flexible; even under a uniaxial compressive load of 1.5 kPa, the cotton-wool-like material did not exhibit fracture of the fibers and, after removing the load, showed a ~60% recovery. In Tris buffer solution, the initial burst release of calcium and silicate ions from the “core-shell”-type fibers was effectively controlled, and the ions were slowly released after one day. Thus, the mechanical flexibility and ion-release behavior of the composites were drastically improved by the thin PLGA coating.

  15. Amperometric hydrogen peroxide biosensor based on the immobilization of horseradish peroxidase on core-shell organosilica-chitosan nanospheres and multiwall carbon nanotubes composite

    International Nuclear Information System (INIS)

    Chen Shihong; Yuan Ruo; Chai Yaqin; Yin Bin; Li Wenjun; Min Ligen

    2009-01-01

    The application of the composites of multiwall carbon nanotubes (MWNTs) and core-shell organosilica-chitosan crosslinked nanospheres as an immobilization matrix for the construction of an amperometric hydrogen peroxide (H 2 O 2 ) biosensor was described. MWNTs and positively charged organosilica-chitosan nanospheres were dispersed in acetic acid solution (0.6 wt%) to achieve organosilica-chitosan/MWNTs composites, which were cast onto a glass carbon electrode (GCE) surface directly. And then, horseradish peroxidase (HRP), as a model enzyme, was immobilized onto it through electrostatic interaction between oppositely charged organosilica-chitosan nanospheres and HRP. The direct electron transfer of HRP was achieved at HRP/organosilica-chitosan/MWNTs/GCE, which exhibited excellent electrocatalytic activity for the reduction of H 2 O 2 . The catalysis currents increased linearly to H 2 O 2 concentration in a wide range of 7.0 x 10 -7 to 2.8 x 10 -3 M, with a sensitivity of 49.8 μA mM -1 cm -2 and with a detection limit of 2.5 x 10 -7 M at 3σ. A Michaelies-Menten constant K M app value was estimated to be 0.32 mM, indicating a high-catalytic activity of HRP. Moreover, the proposed biosensor displayed a rapid response to H 2 O 2 and possessed good stability and reproducibility. When used to detect H 2 O 2 concentration in disinfector samples and sterilized milks, respectively, it showed satisfactory results

  16. Multilayer core-shell structured composite paper electrode consisting of copper, cuprous oxide and graphite assembled on cellulose fibers for asymmetric supercapacitors

    Science.gov (United States)

    Wan, Caichao; Jiao, Yue; Li, Jian

    2017-09-01

    An easily-operated and inexpensive strategy (pencil-drawing-electrodeposition-electro-oxidation) is proposed to synthesize a novel class of multilayer core-shell structured composite paper electrode, which consists of copper, cuprous oxide and graphite assembled on cellulose fibers. This interesting electrode structure plays a pivotal role in providing more active sites for electrochemical reactions, facilitating ion and electron transport and shorting their diffusion pathways. This electrode demonstrates excellent electrochemical properties with a high specific capacitance of 601 F g-1 at 2 A g-1 and retains 83% of this capacitance when operated at an ultrahigh current density of 100 A g-1. In addition, a high energy density of 13.4 W h kg-1 at the power density of 0.40 kW kg-1 and a favorable cycling stability (95.3%, 8000 cycles) were achieved for this electrode. When this electrode was assembled into an asymmetric supercapacitor with carbon paper as negative electrode, the device displays remarkable electrochemical performances with a large areal capacitances (122 mF cm-2 at 1 mA cm-2), high areal energy density (10.8 μW h cm-2 at 402.5 μW cm-2) and outstanding cycling stability (91.5%, 5000 cycles). These results unveil the potential of this composite electrode as a high-performance electrode material for supercapacitors.

  17. Core/Shell Structure of TiO2-Coated MWCNTs for Thermal Protection for High-Temperature Processing of Metal Matrix Composites

    Directory of Open Access Journals (Sweden)

    Laura Angélica Ardila Rodriguez

    2018-01-01

    Full Text Available The production of metal matrix composites with elevated mechanical properties depends largely on the reinforcing phase properties. Due to the poor oxidation resistance of multiwalled carbon nanotubes (MWCNTs as well as their high reactivity with molten metal, the processing conditions for the production of MWCNT-reinforced metal matrix composites may be an obstacle to their successful use as reinforcement. Coating MWCNTs with a ceramic material that acts as a thermal protection would be an alternative to improve oxidation stability. In this work, MWCNTs previously functionalized were coated with titanium dioxide (TiO2 layers of different thicknesses, producing a core-shell structure. Heat treatments at three different temperatures (500°C, 750°C, and 1000°C were performed on coated nanotubes in order to form a stable metal oxide structure. The MWCNT/TiO2 hybrids produced were evaluated in terms of thermal stability. Thermogravimetric analysis (TGA, X-ray diffraction (XRD, scanning electron microscopy (SEM, Fourier transform infrared spectroscopy (FTIR, Raman spectroscopy (RS, and X-ray photoelectron spectroscopy (XPS were performed in order to investigate TiO2-coated MWCNT structure and thermal stability under oxidative atmosphere. It was found that the thermal stability of the TiO2-coated MWCNTs was dependent of the TiO2 layer morphology that in turn depends on the heat treatment temperature.

  18. Core-shell composite of hierarchical MoS2 nanosheets supported on graphitized hollow carbon microspheres for high performance lithium-ion batteries

    International Nuclear Information System (INIS)

    Xia, Yuan; Wang, Beibei; Zhao, Xiaojun; Wang, Gang; Wang, Hui

    2016-01-01

    In this work, a core-shell composite composed of MoS 2 nanosheets grown on hollow carbon microspheres is synthesized by a hydrothermal and a subsequent annealing route. The result shows that well-graphitized hollow-carbon@highlycrystallineMoS 2 (HC@MoS 2 ) was obtained after the four-step reaction. And it is found that the synthesized MoS 2 is consist of 2H and 1T phases. The lithium storage property of the composite is investigated as an anode material for lithium-ion batteries. Benefited from the special morphology and structure, a stable capacity of 970 mAh g −1 for over 100 cycles at a current density of 0.25 A g −1 is realized on the material. Even at a high current density of 4 A g −1 , a reversible capacity as high as 560 mAh g −1 is delivered. Moreover, the reasons for the excellent electrochemical performance of the material are explored and discussed in detail.

  19. Shell supports

    DEFF Research Database (Denmark)

    Almegaard, Henrik

    2004-01-01

    A new statical and conceptual model for membrane shell structures - the stringer system - has been found. The principle was first published at the IASS conference in Copenhagen (OHL91), and later the theory has been further developed (ALMO3)(ALMO4). From the analysis of the stringer model it can...... be concluded that all membrane shells can be described by a limited number of basic configurations of which quite a few have free edges....

  20. The Volatile Composition of newly-discovered C/2017 E4 (Lovejoy) before its dissolutionas revealed by iSHELL at NASA/IRTF

    Science.gov (United States)

    Faggi, Sara; Villanueva, Geronimo Luis; Mumma, Michael J.; Paganini, Lucas

    2017-10-01

    In April 2017, we acquired comprehensive high-resolution spectra of newly-discovered comet C/2017 E4 (Lovejoy) as it approached perihelion, and before its disintegration. We detected many cometary emission lines across 4 customized instrument settings (L1-b, L3, Lp1-b and M1) in the (1 - 5) μm range, using iSHELL - the new near-IR high resolution immersion echelle spectrograph on NASA/IRTF (Mauna Kea, Hawaii).In M1, near 5μm, we detected multiple ro-vibrational lines of H2O, CO and the (X-X) system of CN; the latter data constitute a complete survey of CN at these wavelengths. We derived quantitative abundances for CN and addressed its origin by comparing with quantitative production rates for HCN. The ability to quantify both primary and product species eliminates systematic error that may be introduced when measurements are acquired with different astronomical techniques and instruments.In L1, around 3 μm, we detected fluorescence emission from HCN, C2H2, and water, prompt emission from OH, and many other features. Methane, ethane and methanol were detected both in L3 and Lp1 settings. These species are relevant to astrobiology, owing to questions regarding the origin of pre-biotic organics and water on terrestrial planets.The many water emission lines detected in L1-b (and M1) provided an opportunity to retrieve independent measures of rotational temperature for ortho- and para-H2O, thereby reducing systematic uncertainty in the derived ortho-para ratio and nuclear spin temperature. Deuterated species were also sought and results will be presented.The bright Oort cloud comet E4 Lovejoy combined with the new capabilities of iSHELL provided unique results. The individual iSHELL settings cover very wide spectral range with very high accuracy, eliminating many sources of systematic errors when retrieving molecular abundances; future comparisons amongst comets will clarify the nature and meaning of cosmogonic indicators based on composition.Acknowledgments NASA

  1. Asymmetric supercapacitors based on carbon nanotubes@NiO ultrathin nanosheets core-shell composites and MOF-derived porous carbon polyhedrons with super-long cycle life

    Science.gov (United States)

    Yi, Huan; Wang, Huanwen; Jing, Yuting; Peng, Tianquan; Wang, Xuefeng

    2015-07-01

    Aqueous electrolyte based asymmetric supercapacitors (ASCs) has recently attracted increasing interest by virtue of their operation voltage and high ionic conductivity. Herein, we developed a novel ASC based on carbon nanotubes@nickel oxide nanosheets (CNT@NiO) core-shell composites as positive electrode and porous carbon polyhedrons (PCPs) as negative electrode in aqueous KOH solution as electrolyte. The CNT@NiO core-shell hybrids were prepared through a facile chemical bath deposition method followed by thermal annealing, while PCPs were obtained by direct carbonization of Zn-based metal-organic frameworks (MOFs). Owing to their unique microstructures, outstanding electrochemical properties have been achieved in three-electrode configuration, e.g., 996 F g-1 at 1 A g-1, 500 at 20 A g-1 for the CNT@NiO electrode within 0-0.5 V window, and 245 F g-1 at 1 A g-1 for the PCPs electrode within -1-0 V window. Resulting from these merits, the as-fabricated CNT@NiO//PCPs ASC exhibits maximum energy density of 25.4 Wh kg-1 at a power density of 400 W kg-1 and even remains 9.8 Wh kg-1 at 16,000 W kg-1 (a full charge-discharge within 4.4 s) in the wide voltage region of 0-1.6 V. More importantly, the CNT@NiO//PCPs asymmetric supercapacitor shows ultralong cycling stability, with 93% capacitance retention after 10,000 cycles.

  2. Biophysical basis for the geometry of conical stromatolites.

    Science.gov (United States)

    Petroff, Alexander P; Sim, Min Sub; Maslov, Andrey; Krupenin, Mikhail; Rothman, Daniel H; Bosak, Tanja

    2010-06-01

    Stromatolites may be Earth's oldest macroscopic fossils; however, it remains controversial what, if any, biological processes are recorded in their morphology. Although the biological interpretation of many stromatolite morphologies is confounded by the influence of sedimentation, conical stromatolites form in the absence of sedimentation and are, therefore, considered to be the most robust records of biophysical processes. A qualitative similarity between conical stromatolites and some modern microbial mats suggests a photosynthetic origin for ancient stromatolites. To better understand and interpret ancient fossils, we seek a quantitative relationship between the geometry of conical stromatolites and the biophysical processes that control their growth. We note that all modern conical stromatolites and many that formed in the last 2.8 billion years display a characteristic centimeter-scale spacing between neighboring structures. To understand this prominent-but hitherto uninterpreted-organization, we consider the role of diffusion in mediating competition between stromatolites. Having confirmed this model through laboratory experiments and field observation, we find that organization of a field of stromatolites is set by a diffusive time scale over which individual structures compete for nutrients, thus linking form to physiology. The centimeter-scale spacing between modern and ancient stromatolites corresponds to a rhythmically fluctuating metabolism with a period of approximately 20 hr. The correspondence between the observed spacing and the day length provides quantitative support for the photosynthetic origin of conical stromatolites throughout geologic time.

  3. Conical twist fields and null polygonal Wilson loops

    Science.gov (United States)

    Castro-Alvaredo, Olalla A.; Doyon, Benjamin; Fioravanti, Davide

    2018-06-01

    Using an extension of the concept of twist field in QFT to space-time (external) symmetries, we study conical twist fields in two-dimensional integrable QFT. These create conical singularities of arbitrary excess angle. We show that, upon appropriate identification between the excess angle and the number of sheets, they have the same conformal dimension as branch-point twist fields commonly used to represent partition functions on Riemann surfaces, and that both fields have closely related form factors. However, we show that conical twist fields are truly different from branch-point twist fields. They generate different operator product expansions (short distance expansions) and form factor expansions (large distance expansions). In fact, we verify in free field theories, by re-summing form factors, that the conical twist fields operator product expansions are correctly reproduced. We propose that conical twist fields are the correct fields in order to understand null polygonal Wilson loops/gluon scattering amplitudes of planar maximally supersymmetric Yang-Mills theory.

  4. Pressure Shell Approach to Integrated Environmental Protection

    Science.gov (United States)

    Kennedy, Kriss J.

    2011-01-01

    The next generation of exploration mission human systems will require environmental protection such as radiation protection that is effective and efficient. In order to continue human exploration, habitat systems will require special shells to protect astronauts from hostile environments. The Pressure Shell Approach to integrated environmental (radiation) protection is a multi-layer shell that can be used for multifunctional environmental protection. Self-healing, self-repairing nano technologies and sensors are incorporated into the shell. This shell consists of multiple layers that can be tailored for specific environmental protection needs. Mainly, this innovation focuses on protecting crew from exposure to micrometeorites, thermal, solar flares, and galactic cosmic ray (GCR) radiation. The Pressure Shell Approach consists of a micrometeoroid and secondary ejecta protection layer; a thin, composite shell placed in between two layers that is non-structural; an open cavity layer that can be filled with water, regolith, or polyethylene foam; a thicker composite shell that is a structural load bearing that is placed between two layers; and a bladder coating on the interior composite shell. This multi-layer shell creates an effective radiation protection system. Most of its layers can be designed with the materials necessary for specific environments. In situ materials such as water or regolith can be added to the shell design for supplemental radiation protection.

  5. Facile morphology-controlled synthesis of nickel-coated graphite core-shell particles for excellent conducting performance of polymer-matrix composites and enhanced catalytic reduction of 4-nitrophenol

    Science.gov (United States)

    Bian, Juan; Lan, Fang; Wang, Yilong; Ren, Ke; Zhao, Suling; Li, Wei; Chen, Zhihong; Li, Jiangyu; Guan, Jianguo

    2018-04-01

    We have developed a novel seed-mediated growth method to fabricate nickel-coated graphite composite particles (GP@Ni-CPs) with controllable shell morphology by simply adjusting the concentration of sodium hydroxide ([NaOH]). The fabrication of two kinds of typical GP@Ni-CPs includes adsorption of Ni2+ via electrostatic attraction, sufficient heterogeneous nucleation of Ni atoms by an in situ reduction, and shell-controlled growth by regulating the kinetics of electroless Ni plating in turn. High [NaOH] results in fast kinetics of electroless plating, which causes heterogeneous nuclei to grow isotropically. After fast and uniform growth of Ni nuclei, GP@Ni-CPs with dense shells can be achieved. The first typical GP@Ni-CPs exhibit denser shells, smaller diameters and higher conductivities than the available commercial ones, indicating their important applications in the conducting of polymer-matrix composites. On the other hand, low [NaOH] favors slow kinetics. Thus, the reduction rate of Ni2+ slows down to a relatively low level so that electroless plating is dominated thermodynamically instead of kinetically, leading to an anisotropic crystalline growth of nuclei and finally to the formation of GP@Ni-CPs with nanoneedle-like shells. The second typical samples can effectively catalyze the reduction of p-nitrophenol into p-aminophenol with NaBH4 in comparison with commercial GP@Ni-CPs and RANEY® Ni, owing to the strong charge accumulation effect of needle-like Ni shells. This work proposes a model system for fundamental investigations and has important applications in the fields of electronic interconnection and catalysis.

  6. Generation of fast multiply charged ions in conical targets

    International Nuclear Information System (INIS)

    Demchenko, V.V.; Chukbar, K.V.

    1990-01-01

    So-called conical targets, when the thermonuclear fuel is compressed and heated in a conical cavity in a heavy material (lead, gold, etc.) with the help of a spherical segment that is accelerated by a laser pulse or a beam of charged particles, are often employed in experimental studies of inertial-confinement fusion. In spite of the obvious advantages of such a scheme, one of which is a significant reduction of the required energy input compared with the complete spherical target, it also introduces additional effects into the process of cumulation of energy. In this paper the authors call attention to an effect observed in numerical calculations: the hydrodynamic heating of a small group of multiply charged heavy ions of the walls of the conical cavity up to high energies (T i approx-gt 100 keV). This effect ultimately occurs as a result of the high radiation losses of a multiply charged plasma

  7. Hole Feature on Conical Face Recognition for Turning Part Model

    Science.gov (United States)

    Zubair, A. F.; Abu Mansor, M. S.

    2018-03-01

    Computer Aided Process Planning (CAPP) is the bridge between CAD and CAM and pre-processing of the CAD data in the CAPP system is essential. For CNC turning part, conical faces of part model is inevitable to be recognised beside cylindrical and planar faces. As the sinus cosines of the cone radius structure differ according to different models, face identification in automatic feature recognition of the part model need special intention. This paper intends to focus hole on feature on conical faces that can be detected by CAD solid modeller ACIS via. SAT file. Detection algorithm of face topology were generated and compared. The study shows different faces setup for similar conical part models with different hole type features. Three types of holes were compared and different between merge faces and unmerge faces were studied.

  8. Dispersive O+ conics observed in the plasma-sheet boundary layer with CRRES/LOMICS during a magnetic storm

    Directory of Open Access Journals (Sweden)

    M. Wüest

    1996-06-01

    Full Text Available We present initial results from the Low-energy magnetospheric ion composition sensor (LOMICS on the Combined release and radiation effects satellite (CRRES together with electron, magnetic field, and electric field wave data. LOMICS measures all important magnetospheric ion species (H+, He++, He+, O++, O+ simultaneously in the energy range 60 eV to 45 keV, as well as their pitch-angle distributions, within the time resolution afforded by the spacecraft spin period of 30 s. During the geomagnetic storm of 9 July 1991, over a period of 42 min (0734 UT to 0816 UT the LOMICS ion mass spectrometer observed an apparent O+ conic flowing away from the southern hemisphere with a bulk velocity that decreased exponentially with time from 300 km/s to 50 km/s, while its temperature also decreased exponentially from 700 to 5 eV. At the onset of the O+ conic, intense low-frequency electromagnetic wave activity and strong pitch-angle scattering were also observed. At the time of the observations the CRRES spacecraft was inbound at L~7.5 near dusk, magnetic local time (MLT, and at a magnetic latitude of –23°. Our analysis using several CRRES instruments suggests that the spacecraft was skimming along the plasma sheet boundary layer (PSBL when the upward-flowing ion conic arrived. The conic appears to have evolved in time, both slowing and cooling, due to wave-particle interactions. We are unable to conclude whether the conic was causally associated with spatial structures of the PSBL or the central plasma sheet.

  9. Analytical Investigation of Elastic Thin-Walled Cylinder and Truncated Cone Shell Intersection Under Internal Pressure

    OpenAIRE

    Zamani, J.; Soltani, B.; Aghaei, M.

    2014-01-01

    An elastic solution of cylinder-truncated cone shell intersection under internal pressure is presented. The edge solution theory that has been used in this study takes bending moments and shearing forces into account in the thin-walled shell of revolution element. The general solution of the cone equations is based on power series method. The effect of cone apex angle on the stress distribution in conical and cylindrical parts of structure is investigated. In addition, the effect of the inter...

  10. Probabilistic structural assessment of conical grouted joint using numerical modelling

    DEFF Research Database (Denmark)

    Njomo-Wandji, Wilfried; Natarajan, Anand; Dimitrov, Nikolay

    2018-01-01

    Conical grouted joints have been proposed as a solution for the relative settlement observed between the sleeve and the pile on monopiles for wind turbines. In this paper, the influence of the design parameters such as steel wall thicknesses and conical angle on the failure modes associated...... to continual loadings are assessed based on finite element analysis. It is found that both the sleeve's and pile's wall thicknesses have a significant impact on the grouted joint health. Namely, the larger are the wall thicknesses, the more vulnerable the grout is with respect to fatigue and material...

  11. Wave-vector and polarization dependence of conical refraction.

    Science.gov (United States)

    Turpin, A; Loiko, Yu V; Kalkandjiev, T K; Tomizawa, H; Mompart, J

    2013-02-25

    We experimentally address the wave-vector and polarization dependence of the internal conical refraction phenomenon by demonstrating that an input light beam of elliptical transverse profile refracts into two beams after passing along one of the optic axes of a biaxial crystal, i.e. it exhibits double refraction instead of refracting conically. Such double refraction is investigated by the independent rotation of a linear polarizer and a cylindrical lens. Expressions to describe the position and the intensity pattern of the refracted beams are presented and applied to predict the intensity pattern for an axicon beam propagating along the optic axis of a biaxial crystal.

  12. In vitro toxicity of FemOn, FemOn-SiO2 composite, and SiO2-FemOn core-shell magnetic nanoparticles

    Directory of Open Access Journals (Sweden)

    Toropova YG

    2017-01-01

    of uncoated, FemOn-SiO2 composite flake-like, and SiO2-FemOn core-shell IONPs on cell viability, function, and morphology were tested 48 h postincubation in human umbilical vein endothelial cell culture. Cell viability and apoptosis/necrosis rate were determined using 3-(4,5-dimethylthiazol-2-yl-2,5-diphenyltetrazolium bromide assay and annexin V-phycoerythrin kit, respectively. Cell morphology was evaluated using bright-field microscopy and forward and lateral light scattering profiles obtained with flow cytometry analysis. All tested IONP types were used at three different doses, that is, 0.7, 7.0, and 70.0 µg. Dose-dependent changes in cell morphology, viability, and apoptosis rate were shown. At higher doses, all types of IONPs caused formation of binucleated cells suggesting impaired cytokinesis. FemOn-SiO2 composite flake-like and SiO2-FemOn core-shell IONPs were characterized by similar profile of cytotoxicity, whereas bare IONPs were shown to be less toxic. The presence of either silica core or silica nanoflakes in composite IONPs can promote cytotoxic effects. Keywords: iron oxide nanoparticles, composite nanoparticles, silica coating, silica nanoflakes, cytotoxicity

  13. Core-shell N-doped active carbon fiber@graphene composites for aqueous symmetric supercapacitors with high-energy and high-power density

    Science.gov (United States)

    Xie, Qinxing; Bao, Rongrong; Xie, Chao; Zheng, Anran; Wu, Shihua; Zhang, Yufeng; Zhang, Renwei; Zhao, Peng

    2016-06-01

    Graphene wrapped nitrogen-doped active carbon fibers (ACF@GR) of a core-shell structure were successfully prepared by a simple dip-coating method using natural silk as template. Compared to pure silk active carbon, the as-prepared ACF@GR composites exhibit high specific surface area in a range of 1628-2035 m2 g-1, as well as superior energy storage capability, an extremely high single-electrode capacitance of 552.8 F g-1 was achieved at a current density of 0.1 A g-1 in 6 M KOH aqueous electrolyte. The assembled aqueous symmetric supercapacitors are capable of deliver both high energy density and high power density, for instance, 17.1 Wh kg-1 at a power density of 50.0 W kg-1, and 12.2 Wh kg-1 at 4.7 kW kg-1 with a retention rate of 71.3% for ACF@GR1-based supercapacitor.

  14. Multigene phylogenetic reconstruction of the Tubulinea (Amoebozoa) corroborates four of the six major lineages, while additionally revealing that shell composition does not predict phylogeny in the Arcellinida.

    Science.gov (United States)

    Lahr, Daniel J G; Grant, Jessica R; Katz, Laura A

    2013-05-01

    Tubulinea is a phylogenetically stable higher-level taxon within Amoebozoa, morphologically characterized by monoaxially streaming and cylindrical pseudopods. Contemporary phylogenetic reconstructions have largely relied on SSU rDNA, and to a lesser extent, on actin genes to reveal the relationships among these organisms. Additionally, the test (shell) forming Arcellinida, one of the most species-rich amoebozoan groups, is nested within Tubulinea and suffers from substantial under-sampling of taxa. Here, we increase taxonomic and gene sampling within the Tubulinea, characterizing molecular data for 22 taxa and six genes (SSU rDNA, actin, α- and β-tubulin, elongation factor 2 and the 14-3-3 regulatory protein). We perform concatenated phylogenetic analyses using these genes as well as approximately unbiased tests to assess evolutionary relationships within the Tubulinea. We confirm the monophyly of Tubulinea and four of the six included lineages (Echinamoeboidea, Leptomyxida, Amoebida and Poseidonida). Arcellinida and Hartmanellidae, the remaining lineages, are not monophyletic in our reconstructions, although statistical testing does not allow rejection of either group. We further investigate more fine-grained morphological evolution of previously defined groups, concluding that relationships within Arcellinida are more consistent with general test and aperture shape than with test composition. We also discuss the implications of this phylogeny for interpretations of the Precambrian fossil record of testate amoebae. Copyright © 2013 Elsevier GmbH. All rights reserved.

  15. GPM GROUND VALIDATION CONICAL SCANNING MILLIMETER-WAVE IMAGING RADIOMETER (COSMIR) MC3E V1

    Data.gov (United States)

    National Aeronautics and Space Administration — The GPM Ground Validation Conical Scanning Millimeter-wave Imaging Radiometer (COSMIR) MC3E dataset used the Conical Scanning Millimeter-wave Imaging Radiometer...

  16. GPM GROUND VALIDATION CONICAL SCANNING MILLIMETER-WAVE IMAGING RADIOMETER (COSMIR) GCPEX V1

    Data.gov (United States)

    National Aeronautics and Space Administration — The GPM Ground Validation Conical Scanning Millimeter-wave Imaging Radiometer (COSMIR) GCPEx dataset used the Conical Scanning Millimeter-wave Imaging Radiometer...

  17. New Approach to Simulation of Heat State of Compartments from Lattice Composite Shells for Space Engineering Products

    Directory of Open Access Journals (Sweden)

    Razin Alexander F.

    2017-01-01

    Full Text Available A new approach to the simulation of the heat state of the compartment of lattice polymer composite materials (PCM, not providing for the use of known commercial software packages, has been proposed. The simulation has been performed using the PCM interstage of the Proton rocket as an example with due account of aerodynamic heating, solar radiation and acting of jets of auxiliary propulsion units. At the first stage of numerical analysis, a problem of unsteady heat conduction in the system “skin-air gap-heat insulation” has been solved. An effect of changing a pressure inside a compartment on thermal conductivity of heat insulation was taken into account. The effective thermal conductivity in gaps was used. An effect of a temperature of equipment on a value of radiant heat flux was also taken into account. At the second stage, the heat state of the system “skin-rib” was analyzed. A mathematical model in the form of a system of nonlinear equations for heat balance of control elements on which a rib and a skin section were partitioned, including an information about a temperature of heat insulation received at the first stage of the simulation, was used.

  18. Broadband dielectric spectroscopy of standard and core-shell BaTiO.sub.3./sub.-NiO ceramic composites compared to the BaTiO.sub.3./sub. ceramics

    Czech Academy of Sciences Publication Activity Database

    Nuzhnyy, Dmitry; Petzelt, Jan; Bovtun, Viktor; Ostapchuk, Tetyana; Savinov, Maxim; Kempa, Martin; Bednyakov, Petr; Fernández-Garciá, L.; Rodriguez-Suarez, T.; Menendéz, J.L.

    2016-01-01

    Roč. 500, č. 1 (2016), s. 1-19 ISSN 0015-0193 R&D Projects: GA ČR GA15-08389S Institutional support: RVO:68378271 Keywords : core-shell composite * effective dielectric function * effective infrared response * effective medium approximation * percolation * barium titanate * nickel oxide Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 0.551, year: 2016

  19. Wear Assessment of Conical Pick used in Coal Cutting Operation

    Czech Academy of Sciences Publication Activity Database

    Dewangan, S.; Chattopadhyaya, S.; Hloch, Sergej

    -, 11/2014 (2014), s. 1-6 ISSN 0723-2632 Institutional support: RVO:68145535 Keywords : conical pick * wear * SEM * EDX Subject RIV: JQ - Machines ; Tools Impact factor: 2.420, year: 2014 http://link.springer.com/article/10.1007/s00603-014-0680-z

  20. Conical Dispersion and Effective Zero Refractive Index in Photonic Quasicrystals

    NARCIS (Netherlands)

    J. Dong; M Chang; X. Huang; Z. Hang; Z. Zhong; W. Chen; Z. Huang; C. Chan; X. Huang; Z. Huang

    2015-01-01

    htmlabstractIt is recognized that for a certain class of periodic photonic crystals, conical dispersion can be related to a zero-refractive index. It is not obvious whether such a notion can be extended to a noncrystalline system. We show that certain photonic quasicrystalline approximants have

  1. Thermokinetics of heterogeneous droplet nucleation on conically textured substrates.

    Science.gov (United States)

    Singha, Sanat K; Das, Prasanta K; Maiti, Biswajit

    2015-11-28

    Within the framework of the classical theory of heterogeneous nucleation, a thermokinetic model is developed for line-tension-associated droplet nucleation on conical textures considering growth or shrinkage of the formed cluster due to both interfacial and peripheral monomer exchange and by considering different geometric configurations. Along with the principle of free energy extremization, Katz kinetic approach has been employed to study the effect of substrate conicity and wettability on the thermokinetics of heterogeneous water droplet nucleation. Not only the peripheral tension is found to have a considerable effect on the free energy barrier but also the substrate hydrophobicity and hydrophilicity are observed to switch over their roles between conical crest and trough for different growth rates of the droplet. Besides, the rate of nucleation increases and further promotes nucleation for negative peripheral tension as it diminishes the free energy barrier appreciably. Moreover, nucleation inhibition can be achievable for positive peripheral tension due to the enhancement of the free energy barrier. Analyzing all possible geometric configurations, the hydrophilic narrower conical cavity is found to be the most preferred nucleation site. These findings suggest a physical insight into the context of surface engineering for the promotion or the suppression of nucleation on real or engineered substrates.

  2. Polynomial modal analysis of lamellar diffraction gratings in conical mounting.

    Science.gov (United States)

    Randriamihaja, Manjakavola Honore; Granet, Gérard; Edee, Kofi; Raniriharinosy, Karyl

    2016-09-01

    An efficient numerical modal method for modeling a lamellar grating in conical mounting is presented. Within each region of the grating, the electromagnetic field is expanded onto Legendre polynomials, which allows us to enforce in an exact manner the boundary conditions that determine the eigensolutions. Our code is successfully validated by comparison with results obtained with the analytical modal method.

  3. Variable volume combustor with a conical liner support

    Science.gov (United States)

    Johnson, Thomas Edward; McConnaughhay, Johnie Franklin; Keener, Chrisophter Paul; Ostebee, Heath Michael

    2017-06-27

    The present application provides a variable volume combustor for use with a gas turbine engine. The variable volume combustor may include a liner, a number of micro-mixer fuel nozzles positioned within the liner, and a conical liner support supporting the liner.

  4. RECIPES FOR BUILDING THE DUAL OF CONIC OPTIMIZATION PROBLEM

    Directory of Open Access Journals (Sweden)

    Diah Chaerani

    2010-08-01

    Full Text Available Building the dual of the primal problem of Conic Optimization (CO isa very important step to make the ¯nding optimal solution. In many cases a givenproblem does not have the simple structure of CO problem (i.e., minimizing a linearfunction over an intersection between a±ne space and convex cones but there areseveral conic constraints and sometimes also equality constraints. In this paper wedeal with the question how to form the dual problem in such cases. We discuss theanswer by considering several conic constraints with or without equality constraints.The recipes for building the dual of such cases is formed in standard matrix forms,such that it can be used easily on the numerical experiment. Special attention isgiven to dual development of special classes of CO problems, i.e., conic quadraticand semide¯nite problems. In this paper, we also brie°y present some preliminariestheory on CO as an introduction to the main topic

  5. Parameter dependence of conic angle of nanofibres during electrospinning

    International Nuclear Information System (INIS)

    Zhou Zhengping; Wu Xiangfa; Jiang Long; Gao Xueqin; Zhao Yong; Fong Hao

    2011-01-01

    This paper reports the dependence of conic angle of nanofibres on the processing and material parameters during electrospinning. Solutions of polyacrylonitrile (PAN) in dimethylformamide (DMF) with varied PAN concentrations were studied as the model systems, and they were electrospun into nanofibres at different high direct current (dc) voltages, flow rates and needle diameters. The dynamic and transient shear viscosities of the PAN/DMF solutions were characterized by a parallel-plate rheometer at varied shear rates. Rheological measurements showed that the PAN/DMF solutions behaved as Newtonian fluids at relatively low to medium shear rates, while the solutions with high PAN concentrations of 18 and 20 wt% exhibited a significant shear-thinning behaviour at high shear rates, especially in the case of transient shear mode. Experimental results indicated that at the electrostatic field of ∼80 kV m -1 and needle inner diameter of 0.48 mm (22 gauge), the conic angle of the nanofibre envelope decreased from ∼160° to ∼75° with an increase in PAN concentration from 12 to 20 wt%; at the PAN concentration of 16 wt%, the conic angle increased nonlinearly from ∼40° to ∼160° with an increase in electric field from 50 to 140 kV m -1 . In addition, experimental results showed that the needle inner diameter also noticeably influenced the conic angle. This study provided the experimental evidence useful for understanding the scaling properties of electrohydrodynamic jet motion for controllable electrospinning and process modelling.

  6. Smooth structures on pseudomanifolds with isolated conical singularities

    Czech Academy of Sciences Publication Activity Database

    Le, Hong-Van; Somberg, P.; Vanžura, Jiří

    2013-01-01

    Roč. 38, č. 1 (2013), s. 33-54 ISSN 0251-4184 Institutional support: RVO:67985840 Keywords : conical pseudomanifold * symplectic form * Poisson structure Subject RIV: BA - General Mathematics http://link.springer.com/article/10.1007%2Fs40306-013-0009-0#

  7. Analysis of the conical piezoelectric acoustic emission transducer

    Czech Academy of Sciences Publication Activity Database

    Červená, Olga; Hora, Petr

    2008-01-01

    Roč. 2, č. 1 (2008), s. 13-24 ISSN 1802-680X R&D Projects: GA ČR GA101/06/1689 Institutional research plan: CEZ:AV0Z20760514 Keywords : acoustic emission * conical transducer * FEM Subject RIV: BI - Acoustics

  8. Performance Optimization of a Conical Dielectric Elastomer Actuator

    Directory of Open Access Journals (Sweden)

    Chongjing Cao

    2018-06-01

    Full Text Available Dielectric elastomer actuators (DEAs are known as ‘artificial muscles’ due to their large actuation strain, high energy density and self-sensing capability. The conical configuration has been widely adopted in DEA applications such as bio-inspired locomotion and micropumps for its good compactness, ease for fabrication and large actuation stroke. However, the conical protrusion of the DEA membrane is characterized by inhomogeneous stresses, which complicate their design. In this work, we present an analytical model-based optimization for conical DEAs with the three biasing elements: (I linear compression spring; (II biasing mass; and (III antagonistic double-cone DEA. The optimization is to find the maximum stroke and work output of a conical DEA by tuning its geometry (inner disk to outer frame radius ratio a/b and pre-stretch ratio. The results show that (a for all three cases, stroke and work output are maximum for a pre-stretch ratio of 1 × 1 for the Parker silicone elastomer, which suggests the stretch caused by out-of-plane deformation is sufficient for this specific elastomer. (b Stroke maximization is obtained for a lower a/b ratio while a larger a/b ratio is required to maximize work output, but the optimal a/b ratio is less than 0.3 in all three cases. (c The double-cone configuration has the largest stroke while single cone with a biasing mass has the highest work output.

  9. Generalized synthesis of mesoporous shells on zeolite crystals

    KAUST Repository

    Han, Yu; Pitukmanorom, Pemakorn; Zhao, L. J.; Ying, Jackie

    2010-01-01

    A simple and generalized synthetic approach is developed for creating mesoporous shells on zeolite crystals. This method allows for the tailoring of thickness, pore size, and composition of the mesoporous shell, and can be applied to zeolites

  10. Acridine orange adsorption by zinc oxide/almond shell activated carbon composite: Operational factors, mechanism and performance optimization using central composite design and surface modeling.

    Science.gov (United States)

    Zbair, M; Anfar, Z; Ait Ahsaine, H; El Alem, N; Ezahri, M

    2018-01-15

    Zinc Oxide/Activated Carbon Powder was used for the adsorptive removal of Acridine Orange dye (AO) from aqueous solution. The prepared composite material was characterized using XRD, XPS, SEM, EDS, FTIR, XRF, Raman, BET surface area and TGA/DTA. The adsorption isotherms, kinetics and thermodynamic studies of AO onto the ZnO-AC were thoroughly analyzed. The kinetic modeling data revealed that the adsorption of AO has a good adjustment to the pseudo-second-order model. Langmuir isotherm model is better fitted for adsorption data and the maximum adsorption capacity was found to be 909.1 mg/g at 313 K. The negative values of ΔG showed the spontaneous nature of the AO adsorption onto ZnO-AC. The results indicated the adsorption was pH dependent which is mainly governed by electrostatic attraction, hydrogen bonding and π-π interaction. Reusability test showed a low decrease in the removal performance of ZnO-AC due to the mesopore filling mechanism confirmed by BET analysis after adsorption. Also, thermal regeneration could deposit AO dye on the surface of the composite leading to the efficiency decrease. Finally, the effect of various parameters such as pH, temperature, contact time and initial dye concentration was studied using response surface methodology (RSM). The model predicted a maximum AO removal (99.42 ± 0.57%) under the optimum conditions, which was very close to the experimental value (99.32 ± 0.18%). Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. Optimization of the composition of bimetallic core/shell Fe{sub 2}O{sub 3}/Au nanoparticles for MRI/CT dual-mode imaging

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Song; Qi, Yueyong; Yang, Hua; Gong, Mingfu; Zhang, Dong; Zou, Liguang, E-mail: zlgxqyy@163.com [Third Military Medical University, Department of Radiology, Xinqiao Hospital (China)

    2013-11-15

    Bimetallic core/shell Fe{sub 2}O{sub 3}/Au nanoparticles are promising candidate dual-mode contrast agents for magnetic resonance imaging (MRI) and computed tomography (CT) imaging. However, the gold coating on the hybrid nanoparticles (hybrids) affects the MRI and CT imaging quality. A thick gold nanoshell increases the X-ray attenuation effect but decreases the magnetic saturation of the hybrids. Therefore, we studied the effect of the Fe{sub 2}O{sub 3} and Au composition on these properties to find a suitable hybrid for MRI and CT imaging. Water-soluble, Au-coated magnetic nanoparticles were synthesized by iteratively reducing Au{sup 3+} onto the Fe{sub 2}O{sub 3} surface via hydroxylamine seeding. The properties of the hybrids obtained after different numbers of Au seeding cycles were studied using transmission electron microscopy, UV–Vis spectrophotometry, a vibrating swatch gaussmeter, MRI, CT, and an MTT assay. The hybrids obtained after three Au seeding cycles had an Fe{sub 2}O{sub 3}:Au molar ratio of 7.2:26.8, a mean diameter of 48.3 nm, a UV–Vis absorbance peak of 550 nm, a saturation magnetization of 49.0 emu/g, and no cytotoxicity at a concentration of 500 μg/mL after incubation with RAW 264.7 cells for up to 72 h. The hybrids obtained after three Au seeding cycles are the preferred candidates for MRI and CT applications because of their relatively high R2 relaxivity (95 mM{sup −1 }s{sup −1}) and X-ray attenuation (1.87 times that of iodine) compared to those of the other hybrids investigated in this study.

  12. Co-reduction self-assembly of reduced graphene oxide nanosheets coated Cu2O sub-microspheres core-shell composites as lithium ion battery anode materials

    International Nuclear Information System (INIS)

    Xu, Yi-Tao; Guo, Ying; Song, Le-Xin; Zhang, Kai; Yuen, Matthew M.F.; Xu, Jian-Bin; Fu, Xian-Zhu; Sun, Rong; Wong, Ching-Ping

    2015-01-01

    Cuprous oxide (Cu 2 O) sub-microspheres @ reduced graphene oxide (rGO) nanosheets core-shell composites with 3D architecture are successfully fabricated by a one-step method through co-reduction of irregular cupric citrate and graphene oxide nanosheets at room temperature. Comparing to the bare Cu 2 O sub-microspheres and the simple physical mixture of Cu 2 O and rGO (Cu 2 O-rGO-M), the Cu 2 O@rGO electrodes demonstrate dramatically improved capacity, cyclic stability and rate capability as anode materials for lithium ion batteries. At a low current density of 100 mA∙g −1 , Cu 2 O@rGO electrodes deliver a discharge capacity of 534 mAh∙g −1 after 50 cycles, retaining 94% of the initial capacity. Under a higher current density of 1000 mA∙g −1 , Cu 2 O@rGO electrodes exhibit a discharge capacity of 181 mAh∙g −1 after 200 cycles, approximately 4 times larger than that of bare Cu 2 O sub-microsphere electrodes. The rate capacity retention of Cu 2 O@rGO electrode is 74% at 200 mA∙g −1 and 38% at 1000 mA∙g −1 relative to 100 mA∙g −1 , much better than that for Cu 2 O-rGO-M (52% and 34%) and bare Cu 2 O electrodes (13% and 3%,). The enhanced electrochemical performance for Cu 2 O@rGO might be ascribed to the rGO coating and 3D architecture. The outer coated rGO nanosheets could provide additional 3D conductive networks as well as serve as the buffer layers for accommodating the large volume change of the inner Cu 2 O sub-microspheres during the charge-discharge cycling

  13. Optimization of the composition of bimetallic core/shell Fe2O3/Au nanoparticles for MRI/CT dual-mode imaging

    International Nuclear Information System (INIS)

    Zhang, Song; Qi, Yueyong; Yang, Hua; Gong, Mingfu; Zhang, Dong; Zou, Liguang

    2013-01-01

    Bimetallic core/shell Fe 2 O 3 /Au nanoparticles are promising candidate dual-mode contrast agents for magnetic resonance imaging (MRI) and computed tomography (CT) imaging. However, the gold coating on the hybrid nanoparticles (hybrids) affects the MRI and CT imaging quality. A thick gold nanoshell increases the X-ray attenuation effect but decreases the magnetic saturation of the hybrids. Therefore, we studied the effect of the Fe 2 O 3 and Au composition on these properties to find a suitable hybrid for MRI and CT imaging. Water-soluble, Au-coated magnetic nanoparticles were synthesized by iteratively reducing Au 3+ onto the Fe 2 O 3 surface via hydroxylamine seeding. The properties of the hybrids obtained after different numbers of Au seeding cycles were studied using transmission electron microscopy, UV–Vis spectrophotometry, a vibrating swatch gaussmeter, MRI, CT, and an MTT assay. The hybrids obtained after three Au seeding cycles had an Fe 2 O 3 :Au molar ratio of 7.2:26.8, a mean diameter of 48.3 nm, a UV–Vis absorbance peak of 550 nm, a saturation magnetization of 49.0 emu/g, and no cytotoxicity at a concentration of 500 μg/mL after incubation with RAW 264.7 cells for up to 72 h. The hybrids obtained after three Au seeding cycles are the preferred candidates for MRI and CT applications because of their relatively high R2 relaxivity (95 mM −1  s −1 ) and X-ray attenuation (1.87 times that of iodine) compared to those of the other hybrids investigated in this study

  14. The use of a conical lens to find the refractive index of liquids

    International Nuclear Information System (INIS)

    Anguiano-Morales, Marcelino; Salas Peimbert, Didia P; Trujillo-Schiaffino, Gerardo

    2011-01-01

    In this work, the basic idea is to determine the refractive index of liquids unknown using a conical lens. The measurement of the refractive index of liquids is an important work in engineering and science since is one of the most important optical parameter. The adulteration problem is increasing day by day; therefore it is necessary to implement new and simple devices for measure the refractive index of several materials. There is a great variety of interferometric methods that may be used for determining the refractive index. However, these methods either need sophisticated equipment or have low accuracy. Our system consists of a conical lens coupled to a cylindrical container with a liquid whose composition can be changed easily or adulterated. The diameter of the emergent beam of the container is associated to the specific index of refraction of each substance. Any adulteration of the liquid will be reflected in the diameter of the beam, which will be detected by a charge-coupled device (CCD). Our hypothesis is supported by developed mathematical calculations and numerical simulations.

  15. Formation of tin-tin oxide core–shell nanoparticles in the composite SnO{sub 2−x}/nitrogen-doped carbon nanotubes by pulsed ion beam irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Korusenko, P.M., E-mail: korusenko@obisp.oscsbras.ru [Omsk Scientific Center, Siberian Branch of the Russian Academy of Sciences, Karl Marx avenue 15, 644040 Omsk (Russian Federation); Nesov, S.N.; Bolotov, V.V.; Povoroznyuk, S.N. [Omsk Scientific Center, Siberian Branch of the Russian Academy of Sciences, Karl Marx avenue 15, 644040 Omsk (Russian Federation); Pushkarev, A.I. [National Research Tomsk Polytechnic University, Lenin Ave. 2a, 634028 Tomsk (Russian Federation); Ivlev, K.E. [Omsk Scientific Center, Siberian Branch of the Russian Academy of Sciences, Karl Marx avenue 15, 644040 Omsk (Russian Federation); Smirnov, D.A. [St. Petersburg State University, Lieutenant Shmidt Emb. 11, 198504 St. Petersburg (Russian Federation); Institute of Solid State Physics, Dresden University of Technology, D-01069 Dresden (Germany)

    2017-03-01

    Highlights: • Original method the formation of core–shell structures by pulsed ion beam is proposed. • The composite SnO{sub 2−x}/N-MWCNTs was irradiated by pulsed ion beam. • Morphology and electronic structure of the irradiated composite were characterized. • The formation of Sn−SnO{sub x} core–shell nanoparticles after irradiation was observed. - Abstract: The complex methods of transmission electron microscopy, energy dispersive X-ray analysis, and X-ray photoelectron spectroscopy were used to investigate the changes in the morphology, phase composition, and electronic structure of the composite SnO{sub 2−x}/nitrogen-doped multiwalled carbon nanotubes (SnO{sub 2−x}/N-MWCNTs) irradiated with the pulsed ion beam of nanosecond duration. The irradiation of the composite SnO{sub 2−x}/N-MWCNTs leads to the formation of nanoparticles with the core–shell structure on the surface of CNTs with a sharp interfacial boundary. It has been established that the “core” is a metal tin (Sn{sup 0}) with a typical size of 5–35 nm, and the “shell” is a thin amorphous layer (2–6 nm) consisting of nonstoichiometric tin oxide with a low oxygen content. The “core–shell” structure Sn−SnO{sub x} is formed due to the process of heating and evaporation of SnO{sub 2−x} under the effect of the ion beam, followed by vapor deposition on the surface of carbon nanotubes.

  16. Significantly Enhanced Dielectric Performances and High Thermal Conductivity in Poly(vinylidene fluoride)-Based Composites Enabled by SiC@SiO2 Core-Shell Whiskers Alignment.

    Science.gov (United States)

    He, Dalong; Wang, Yao; Song, Silong; Liu, Song; Deng, Yuan

    2017-12-27

    Design of composites with ordered fillers arrangement results in anisotropic performances with greatly enhanced properties along a specific direction, which is a powerful tool to optimize physical properties of composites. Well-aligned core-shell SiC@SiO 2 whiskers in poly(vinylidene fluoride) (PVDF) matrix has been achieved via a modified spinning approach. Because of the high aspect ratio of SiC whiskers, strong anisotropy and significant enhancement in dielectric constant were observed with permittivity 854 along the parallel direction versus 71 along the perpendicular direction at 20 vol % SiC@SiO 2 loading, while little increase in dielectric loss was found due to the highly insulating SiO 2 shell. The anisotropic dielectric behavior of the composite is perfectly understood macroscopically to have originated from anisotropic intensity of interfacial polarization based on an equivalent circuit model of two parallel RC circuits connected in series. Furthermore, finite element simulations on the three-dimensional distribution of local electric field, polarization, and leakage current density in oriented SiC@SiO 2 /PVDF composites under different applied electrical field directions unambiguously revealed that aligned core-shell SiC@SiO 2 whiskers with a high aspect ratio significantly improved dielectric performances. Importantly, the thermal conductivity of the composite was synchronously enhanced over 7 times as compared to that of PVDF matrix along the parallel direction at 20 vol % SiC@SiO 2 whiskers loading. This study highlights an effective strategy to achieve excellent comprehensive properties for high-k dielectrics.

  17. Preparation, characterization, and luminescence properties of dysprosium perchlorate with MABA-Si and phen or dipy complexes as well as SiO{sub 2}@Dy(MABA-Si)L core-shell structure nanometermeter luminescent composites

    Energy Technology Data Exchange (ETDEWEB)

    Li, Wen-Xian, E-mail: nmglwx@163.com [College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021 (China); Zheng, Yu-Shan [Inner Mongolia Autonomous Region Product Quality Inspection Institute, Hohhot 010010 (China); Cao, Xiao-fang; Bai, Juan; Fu, Zhi-Fang; Bao, Jin-Rong; Li, Yi-Lian [College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021 (China)

    2016-10-15

    Two novel ternary rare earth complexes Dy(MABA-Si)·L{sub 2}(ClO{sub 4}){sub 3}·2H{sub 2}O (L= Phen or Dipy) were prepared using HOOCC{sub 6}H{sub 4}N(CONH(CH{sub 2}){sub 3}Si-(OCH{sub 2}CH{sub 3}){sub 3}){sub 2} which was abbreviated or denoted as MABA-Si. MABA-Si was the first ligand, L was the second ligand. The corresponding two SiO{sub 2}@Dy(MABA-Si)L nanometermeter luminescent composites were synthesized as well, and the silica spheres is the core, and the ternary rare earth complex Dy(MABA-Si)·L{sub 2}(ClO{sub 4}){sub 3}·2H{sub 2}O was the shell layer, who was abbreviated or denoted as Dy((MABA-Si)L). The ternary complexes have been characterized by element analysis, molar conductivity, IR spectra and {sup 1}HNMR spectra. The results showed that the chemical formula of the complex was Dy(MABA-Si)·L{sub 2}(ClO{sub 4}){sub 3}·2H{sub 2}O. The fluorescent spectra illustrated that the complexes displayed its characteristic luminescence in solid state, and the luminescence was superior than Dy{sup 3+}. The core-shell structure of SiO{sub 2}@Dy(MABA-Si)L nanometermeter luminescent composite was characterized by SEM, TEM and IR spectra. Based on the SEM photographs, the core-shell structure particles showed its regular microstructure including smooth surface, and good dispersity. The ternary complex coated on the mono-dispersed SiO{sub 2} spheres by self-assembly. The fluorescent spectra illustrated that the core-shell structure of SiO{sub 2}@Dy(MABA-Si)L nanometermeter luminescent composites exhibited stronger fluorescent than the ternary complexes. The fluorescence lifetime of the complexes and core-shell structure composites was measured as well.

  18. Fabrication of the novel core-shell MCM-41@mTiO{sub 2} composite microspheres with large specific surface area for enhanced photocatalytic degradation of dinitro butyl phenol (DNBP)

    Energy Technology Data Exchange (ETDEWEB)

    Wei, Xiao-Na; Wang, Hui-Long, E-mail: hlwang@dlut.edu.cn; Li, Zhen-Duo; Huang, Zhi-Qiang; Qi, Hui-Ping; Jiang, Wen-Feng

    2016-05-30

    Graphical abstract: The mesoporous MCM-41@mTiO{sub 2} composite microspheres with core/shell structure, well-crystallized mesoporous TiO{sub 2} layer, high specific surface, large pore volume and excellent photocatalytic activity were synthesized by combining sol-gel and simple hydrothermal treatment. - Highlights: • The mesoporous MCM-41@mTiO{sub 2} composite was synthesized successfully. • The composite was facilely prepared by combining sol-gel and hydrothermal method. • The composite exhibited high photocatalytic degradation activity for DNBP. • The composite photocatalyst has excellent reproducibility. - Abstract: The mesoporous MCM-41@mTiO{sub 2} core-shell composite microspheres were synthesized successfully by combining sol-gel and simple hydrothermal treatment. The morphology and microstructure characteristics of the synthesized materials were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), N{sub 2} adsorption-desorption measurements, X-ray powder diffraction (XRD), UV–vis diffuse reflectance spectra (UV–vis/DRS) and Fourier transform infrared spectroscopy (FT-IR). The results indicate that the composite material possesses obvious core/shell structure, a pure mesoporous and well-crystallized TiO{sub 2} layer (mTiO{sub 2}), high specific surface area (316.8 m{sup 2}/g), large pore volume (0.42 cm{sup 3}/g) and two different pore sizes (2.6 nm and 11.0 nm). The photocatalytic activity of the novel MCM-41@mTiO{sub 2} composite was evaluated by degrading 2-sec-butyl-4,6-dinitrophenol (DNBP) in aqueous suspension under UV and visible light irradiation. The results were compared with commercial anatase TiO{sub 2} and Degussa P25 and the enhanced degradation were obtained with the synthesized MCM-41@mTiO{sub 2} composite under the same conditions, which meant that this material can serve as an efficient photocatalyst for the degradation of hazardous organic pollutants in wastewaters.

  19. Optimization of the Conical Angle Design in Conical Implant-Abutment Connections: A Pilot Study Based on the Finite Element Method.

    Science.gov (United States)

    Yao, Kuang-Ta; Chen, Chen-Sheng; Cheng, Cheng-Kung; Fang, Hsu-Wei; Huang, Chang-Hung; Kao, Hung-Chan; Hsu, Ming-Lun

    2018-02-01

    Conical implant-abutment connections are popular for their excellent connection stability, which is attributable to frictional resistance in the connection. However, conical angles, the inherent design parameter of conical connections, exert opposing effects on 2 influencing factors of the connection stability: frictional resistance and abutment rigidity. This pilot study employed an optimization approach through the finite element method to obtain an optimal conical angle for the highest connection stability in an Ankylos-based conical connection system. A nonlinear 3-dimensional finite element parametric model was developed according to the geometry of the Ankylos system (conical half angle = 5.7°) by using the ANSYS 11.0 software. Optimization algorithms were conducted to obtain the optimal conical half angle and achieve the minimal value of maximum von Mises stress in the abutment, which represents the highest connection stability. The optimal conical half angle obtained was 10.1°. Compared with the original design (5.7°), the optimal design demonstrated an increased rigidity of abutment (36.4%) and implant (25.5%), a decreased microgap at the implant-abutment interface (62.3%), a decreased contact pressure (37.9%) with a more uniform stress distribution in the connection, and a decreased stress in the cortical bone (4.5%). In conclusion, the methodology of design optimization to determine the optimal conical angle of the Ankylos-based system is feasible. Because of the heterogeneity of different systems, more studies should be conducted to define the optimal conical angle in various conical connection designs.

  20. Production of ion beam by conical pinched electron beam diode

    International Nuclear Information System (INIS)

    Matsukawa, Y.; Nakagawa, Y.

    1982-01-01

    Some properties of the ion beam produced by pinched electron beam diode having conical shape electrodes and organic insulator anode was studied. Ion energy is about 200keV and the peak diode current is about 30 kA. At 11cm from the diode apex, not the geometrical focus point, concentrated ion beam was obtained. Its density is more than 500A/cm 2 . The mean ion current density within the radius of 1.6cm around the axis from conical diode is two or three times that from an usual pinched electron beam diode with flat parallel electrodes of same dimension and impedance under the same conditions. (author)

  1. Self-Propulsion Of Catalytic Conical Micro-Swimmer

    Science.gov (United States)

    Gallino, Giacomo; Gallaire, Francois; Lauga, Eric; Michelin, Sebastien

    2017-11-01

    Self-propelled artificial micro-motors have attracted much attention both as fundamental examples of active matter and for their potential biomedical applications (e.g. drug delivery, cell sorting). A popular design exploits the catalytic decomposition of a fuel (e.g. hydrogen peroxide) on the active surface of the motor to produce oxygen bubbles that propel the swimmer, effectively converting chemical energy into swimming motion. We focus here on a conical shape swimmer with chemically-active inner surfaces. Using numerical simulations of the chemical problem and viscous hydrodynamics, we analyze the formation, growth and motion of the bubbles inside the micro-motor and the resulting swimming motion. Our results shed light on the fundamental hydrodynamics of the propulsion of conical swimmers and may help to improve the efficiency of these machines. G.G. aknowledges support from the Swiss National Science Fundation.

  2. Anisotropic Exchange Interaction in the Conical Magnetic Phase of Erbium

    DEFF Research Database (Denmark)

    Jensen, J.

    1974-01-01

    From a general two ion spin Hamiltonian, an expression is deduced for the energies of spin waves propagating in a hexagonal solid in which the magnetic moments are ordered in a conical or helical structure. The spin wave dispersion relation in the c direction of Er in its conical magnetic phase...... at 4.5K, which has been studied by Nicklow et al (1971) is reanalysed. In this analysis an alternative kind of anisotropic coupling between the total angular moments (Ji and Jj) on the sites i and j is introduced which is proportional to the following combination of Racah operators: O2, -2(Ji), O2, -2......(Jj), expressed with respect to a coordinate system with the z axis along the c direction. The resulting anisotropy (both the constant and the q dependent part) is reduced by an order of magnitude in comparison with that deduced by Nicklow et al (1971). The constant anisotropy is found to be equal...

  3. Helico-conical beams for generating optical twisters

    DEFF Research Database (Denmark)

    Glückstad, Jesper; Palima, Darwin; Daria, Vincent Ricardo Mancao

    2010-01-01

    charge is increased, the area where destructive interference at the centre increases thereby enlarging the light ring. The propagation along the optical axis follows a conical ray of light where the concentration of high intensities is maintained at the outskirts of the conical beam where constructive...... with an apodized helical phase front at the outskirts and linearly scaled towards no phase singularity at the centre of the beam. At the focal volume, we show that our beam fonms an intensity distribution that can be accurately described as an "optical twister" as it propagates along the optical axis. Unlike LG...... beams, an optical twister can have minimal changes in radius but with a scalable DAM. Furthenmore, we characterize the DAM in tenms of its capacity to introduce spiral motion on particles trapped along its orbit. We also show that our "optical twister" maintains a high concentration of photons...

  4. Preparation and characterization of WO{sub 3} nanoparticles, WO{sub 3}/TiO{sub 2} core/shell nanocomposites and PEDOT:PSS/WO{sub 3} composite thin films for photocatalytic and electrochromic applications

    Energy Technology Data Exchange (ETDEWEB)

    Boyadjiev, Stefan I., E-mail: boiajiev@gmail.com [MTA-BME Technical Analytical Chemistry Research Group, Szent Gellért tér 4, Budapest, H-1111 (Hungary); Santos, Gustavo dos Lopes; Szűcs, Júlia [Budapest University of Technology and Economics, Department of Inorganic and Analytical Chemistry, Szent Gellért tér 4, Budapest, H-1111 (Hungary); Szilágyi, Imre M., E-mail: imre.szilagyi@mail.bme.hu [MTA-BME Technical Analytical Chemistry Research Group, Szent Gellért tér 4, Budapest, H-1111 (Hungary); Budapest University of Technology and Economics, Department of Inorganic and Analytical Chemistry, Szent Gellért tér 4, Budapest, H-1111 (Hungary)

    2016-03-25

    In this study, monoclinic WO{sub 3} nanoparticles were obtained by thermal decomposition of (NH{sub 4}){sub x}WO{sub 3} in air at 600 °C. On them by atomic layer deposition (ALD) TiO{sub 2} films were deposited, and thus core/shell WO{sub 3}/TiO{sub 2} nanocomposites were prepared. We prepared composites of WO{sub 3} nanoparticles with conductive polymer as PEDOT:PSS, and deposited thin films of them on glass and ITO substrates by spin coating. The formation, morphology, composition and structure of the as-prepared pure and composite nanoparticles, as well thin films, were studied by TEM, SEM-EDX and XRD. The photocatalytic activity of both the WO{sub 3} and core/shell WO{sub 3}/TiO{sub 2} nanoparticles was studied by decomposing methyl orange in aqueous solution under UV light irradiation. Cyclic voltammetry measurements were performed on the composite PEDOT:PSS/WO{sub 3} thin films, and the coloring and bleaching states were studied.

  5. Folding and unfolding of large-size shell construction for application in Earth orbit

    Science.gov (United States)

    Kondyurin, Alexey; Pestrenina, Irena; Pestrenin, Valery; Rusakov, Sergey

    2016-07-01

    A future exploration of space requires a technology of large module for biological, technological, logistic and other applications in Earth orbits [1-3]. This report describes the possibility of using large-sized shell structures deployable in space. Structure is delivered to the orbit in the spaceship container. The shell is folded for the transportation. The shell material is either rigid plastic or multilayer prepreg comprising rigid reinforcements (such as reinforcing fibers). The unfolding process (bringing a construction to the unfolded state by loading the internal pressure) needs be considered at the presence of both stretching and bending deformations. An analysis of the deployment conditions (the minimum internal pressure bringing a construction from the folded state to the unfolded state) of large laminated CFRP shell structures is formulated in this report. Solution of this mechanics of deformable solids (MDS) problem of the shell structure is based on the following assumptions: the shell is made of components whose median surface has a reamer; in the separate structural element relaxed state (not stressed and not deformed) its median surface coincides with its reamer (this assumption allows choose the relaxed state of the structure correctly); structural elements are joined (sewn together) by a seam that does not resist rotation around the tangent to the seam line. The ways of large shell structures folding, whose median surface has a reamer, are suggested. Unfolding of cylindrical, conical (full and truncated cones), and large-size composite shells (cylinder-cones, cones-cones) is considered. These results show that the unfolding pressure of such large-size structures (0.01-0.2 atm.) is comparable to the deploying pressure of pneumatic parts (0.001-0.1 atm.) [3]. It would be possible to extend this approach to investigate the unfolding process of large-sized shells with ruled median surface or for non-developable surfaces. This research was

  6. Direct determination of the resonance properties of metallic conical nanoantennas

    KAUST Repository

    Tuccio, Salvatore; Razzari, Luca; Alabastri, Alessandro; Toma, Andrea; Liberale, Carlo; De Angelis, Francesco De; Candeloro, Patrizio; Das, Gobind; Giugni, Andrea; Di Fabrizio, Enzo M.; Proietti Zaccaria, Remo

    2014-01-01

    We present a simple method that is able to predict the resonant frequencies of a metallic conical nanoantenna. The alculation is based on an integral relation that takes into account the dependence of the effective refractive index of the plasmonic mode on the cone radius. Numerical simulations retrieving the near field properties of nanocones with different lengths are also performed for comparison. The fine agreement between the two approaches demonstrates the validity of our method. © 2014 Optical Society of America.

  7. High efficiency conical scanner for earth resources applications

    Science.gov (United States)

    Bates, J. C.; Dumas, H. J., Jr.

    1975-01-01

    A description is given of a six-arm conical scanner which was selected to provide a continuous line-of-sight scan. Two versions of the instrument are considered. The two versions differ in their weight. The weight of the heavy version is 600 lbs. A light weight design which employs beryllium and aluminum optical components weighs only 350 lbs. A multiplexer and analog-to-digital converter are to be incorporated into the design. Questions of instrument performance are also discussed.

  8. Mixed-Integer Conic Linear Programming: Challenges and Perspectives

    Science.gov (United States)

    2013-10-01

    The novel DCCs for MISOCO may be used in branch- and-cut algorithms when solving MISOCO problems. The experimental software CICLO was developed to...perform limited, but rigorous computational experiments. The CICLO solver utilizes continuous SOCO solvers, MOSEK, CPLES or SeDuMi, builds on the open...submitted Fall 2013. Software: 1. CICLO : Integer conic linear optimization package. Authors: J.C. Góez, T.K. Ralphs, Y. Fu, and T. Terlaky

  9. Radially Polarized Conical Beam from an Embedded Etched Fiber

    OpenAIRE

    Kalaidji , D.; Spajer , M.; Marthouret , N.; Grosjean , T.

    2009-01-01

    International audience; We propose a method for producing a conical beam based on the lateral refraction of the TM01 mode from a two-mode fiber after chemical etching of the cladding, and for controlling its radial polarization. The whole power of the guided mode is transferred to the refracted beam with low diffraction. Polarization control by a series of azimuthal detectors and a stress controller affords the transmission of a stabilized radial polarization through an optical fiber. A solid...

  10. Composition and strain effects in Type I and Type II heterostructure ZnSe/Cd(Zn)S and ZnSe/Cd1-xZnxS core/shell quantum dots

    Science.gov (United States)

    Gheshlaghi, Negar; Pisheh, Hadi Sedaghat; Ünlü, Hilmi

    2017-11-01

    We investigated the effect of ternary shell alloy composition on the bandgap and diameter of core of ZnSe / Cd1 - x Znx S heterostructure core/shell quantum dots, which were synthesized by using a simple colloidal technique. Characterization by using the x-ray diffraction (XRD), transmission electron microscopy (TEM), UV-Vis absorption and fluorescence emission spectroscopic techniques indicate that (i) there is a transition of ZnSe / Cd0.6 Zn0.4 S Type-I heterostructure (electrons and holes tend to localize in core) to ZnSe / Cd0.75 Zn0.25 S quasi-Type-II heterostructures (holes tend to localized in the core and electrons are delocalized) and (ii) then after large red shift and Stock-shift in PL emission spectra but not a distinct absorption peak in UV spectra become noticeable in ZnSe/Cd0.75Zn0.25 S quasi-Type II and ZnSe/CdS Type II heterostructures (electrons are localized in core and holes are localized in shell). Furthermore, the increase of Cd:S ratio in shell alloy composition shifts the XRD peaks to lower 2θ degrees which corresponds to tensile strain in the ZnSe core. Finally, the hydrostatic interfacial strain has effect on the squeezing or stretching the capped core: A decrease of compressive force on core from ZnSe/ZnS to tensile force in ZnSe/CdS with increase in Cd:S ratio indicates that transition of compressive strain to tensile strain takes place with the transition from Type-I to II heterostructure.

  11. The Poisson equation in axisymmetric domains with conical points

    International Nuclear Information System (INIS)

    Nkemzi, B.

    2003-01-01

    This paper analyzes the application of the Fourier-finite-element method (FFEM) for the resolution of the Derichlet problem for the Poisson equation -Δu-circumflex = f-circumflex in axisymmetric domains Ω-circumflex subset of R 3 with conical points on the rotation axis. The FFEM combines the approximate Fourier method with respect to one space direction with the finite element method for the approximate calculation of the Fourier coefficients of the solution. Here, the influence of the conical points on the regularity of the Fourier coefficients of the solution is analyzed and the asymptotic behaviour of the coefficients near the conical points is described by some singularity functions and treated numerically by mesh grading in the two-dimensional meridian of Ω-circumflex. It is proved that for f-circumflex in L 2 (Ω-circumflex), the rate of convergence of the combined approximations in the Sobolev space W 2 1 (Ω-circumflex) is of the order O(h + N -1 ), where h and N represent, respectively, the parameters of the finite-element- and the Fourier-approximation, with h → 0 and n → ∞. (author)

  12. Conical refraction in a degenerated two-crystal cascade

    International Nuclear Information System (INIS)

    Peet, V

    2016-01-01

    When a collimated light beam is passed consequently along the optic axes of two identical biaxial crystals, the conical refraction produces in the focal image plane a specific light pattern consisting of a ring and a central spot. The ring is formed due to the additive action of two crystals, while the spot results from the reversed conical refraction in such a degenerated cascade arrangement. The relative intensity of these two components depends on the azimuth angle between the orientations of the crystals about the beam axis. It is shown that this dependence arises due to the interference of pairs of waves produced by conical refraction in two crystals. If a part of these waves is blocked by polarization selection of beam components, the dependence of the light pattern on the azimuth angle vanishes. In this case, the outgoing light profile consists of a ring and a central spot with fixed intensities so that the total beam power is divided equally between these two components. Depending on the applied polarization, the central spot appears either as a restored input beam or a charge-two optical vortex. The results of numerical simulations of the effect are in a very good agreement with the experimental observations. (paper)

  13. Ultrafast X-Ray Spectroscopy of Conical Intersections

    Science.gov (United States)

    Neville, Simon P.; Chergui, Majed; Stolow, Albert; Schuurman, Michael S.

    2018-06-01

    Ongoing developments in ultrafast x-ray sources offer powerful new means of probing the complex nonadiabatically coupled structural and electronic dynamics of photoexcited molecules. These non-Born-Oppenheimer effects are governed by general electronic degeneracies termed conical intersections, which play a key role, analogous to that of a transition state, in the electronic-nuclear dynamics of excited molecules. Using high-level ab initio quantum dynamics simulations, we studied time-resolved x-ray absorption (TRXAS) and photoelectron spectroscopy (TRXPS) of the prototypical unsaturated organic chromophore, ethylene, following excitation to its S2(π π*) state. The TRXAS, in particular, is highly sensitive to all aspects of the ensuing dynamics. These x-ray spectroscopies provide a clear signature of the wave packet dynamics near conical intersections, related to charge localization effects driven by the nuclear dynamics. Given the ubiquity of charge localization in excited state dynamics, we believe that ultrafast x-ray spectroscopies offer a unique and powerful route to the direct observation of dynamics around conical intersections.

  14. Determination on the chemical composition of Ammonia beccarii shell using SEM and EDX: Preliminary study of benthic foraminifera capacity in response to anthropogenic metal contamination in coastal areas

    Science.gov (United States)

    Rositasari, R.; Suratno; Yogaswara, D.

    2018-02-01

    The use of single-celled and shelled biota, such as foraminifera that lives as benthic, in coastal environmental monitoring activity is very efficient. Several species of the Ammonia have been used as a proxy of various aquatic environmental monitoring activities. Chemical constituents screening in foraminiferal shell is a step ahead to identify the capacity of benthic foraminifera in responding to anthropogenic metal contamination in coastal water areas. The initial hypothesis of this study is the calcite test of Ammonia beccarii binds the anthropogenic metal in its shell structure and triggers the deformation test. The normal and abnormal shells of Ammonia specimens from Jakarta Bay and Batam waters are used in this study. The Ponar grab was used to sample surface sediment in Jakarta Bay and Batam waters in 2015, and the short core was used to acquire substratum sediment in Jakarta Bay in 2011.The Ammonia beccarii shell was analyzed using SEM and EDX detectors (Scanning Electron Microscope and Energy Dispersive X-ray). The shooting was performed three times in each test, i.e. in the first chamber (proloculus), the last chamber and the chamber between the two. The main building blocks of the foraminifera test are oxygen with an average weight range of 42.86 - 58.79% and carbon with an average weight range of 17.69 - 26.32%. There is a tendency for low levels of C and O elements in the abnormal tests.

  15. Fast ignition upon the implosion of a thin shell onto a precompressed deuterium-tritium ball

    Science.gov (United States)

    Gus'kov, S. Yu.; Zmitrenko, N. V.

    2012-11-01

    Fast ignition of a precompressed inertial confinement fusion (ICF) target by a hydrodynamic material flux is investigated. A model system of hydrodynamic objects consisting of a central deuterium-tritium (DT) ball and a concentric two-layer shell separated by a vacuum gap is analyzed. The outer layer of the shell is an ablator, while the inner layer consists of DT ice. The igniting hydrodynamic flux forms as a result of laser-driven acceleration and compression of the shell toward the system center. A series of one-dimensional numerical simulations of the shell implosion, the collision of the shell with the DT ball, and the generation and propagation of thermonuclear burn waves in both parts of the system are performed. Analytic models are developed that describe the implosion of a thin shell onto a central homogeneous ball of arbitrary radius and density and the initiation and propagation of a thermonuclear burn wave induced by such an implosion. Application of the solution of a model problem to analyzing the implosion of a segment of a spherical shell in a conical channel indicates the possibility of fast ignition of a spherical ICF target from a conical target driven by a laser pulse with an energy of 500-700 kJ.

  16. The status of experimental buckling investigations of shells

    International Nuclear Information System (INIS)

    Singer, J.

    1982-01-01

    The recent developments in shell buckling experiments are surveyed and related to a review of the progress in the seventies. Model fabrication, imperfection measurements, boundary conditions, nondestructive testing, combined loading, postbuckling behavior, composite shells and other aspects of shell buckling tests are discussed. The motivation for experiments and the conclusions drawn in the previous review are reassessed. (orig.)

  17. Nonlinear problems of the theory of heterogeneous slightly curved shells

    Science.gov (United States)

    Kantor, B. Y.

    1973-01-01

    An account if given of the variational method of the solution of physically and geometrically nonlinear problems of the theory of heterogeneous slightly curved shells. Examined are the bending and supercritical behavior of plates and conical and spherical cupolas of variable thickness in a temperature field, taking into account the dependence of the elastic parameters on temperature. The bending, stability in general and load-bearing capacity of flexible isotropic elastic-plastic shells with different criteria of plasticity, taking into account compressibility and hardening. The effect of the plastic heterogeneity caused by heat treatment, surface work hardening and irradiation by fast neutron flux is investigated. Some problems of the dynamic behavior of flexible shells are solved. Calculations are performed in high approximations. Considerable attention is given to the construction of a machine algorithm and to the checking of the convergence of iterative processes.

  18. Optical properties of core-shell and multi-shell nanorods

    Science.gov (United States)

    Mokkath, Junais Habeeb; Shehata, Nader

    2018-05-01

    We report a first-principles time dependent density functional theory study of the optical response modulations in bimetallic core-shell (Na@Al and Al@Na) and multi-shell (Al@Na@Al@Na and Na@Al@Na@Al: concentric shells of Al and Na alternate) nanorods. All of the core-shell and multi-shell configurations display highly enhanced absorption intensity with respect to the pure Al and Na nanorods, showing sensitivity to both composition and chemical ordering. Remarkably large spectral intensity enhancements were found in a couple of core-shell configurations, indicative that optical response averaging based on the individual components can not be considered as true as always in the case of bimetallic core-shell nanorods. We believe that our theoretical results would be useful in promising applications depending on Aluminum-based plasmonic materials such as solar cells and sensors.

  19. Obtainment of calcium carbonate from mussels shell

    International Nuclear Information System (INIS)

    Hamester, M.R.R.; Becker, D.

    2010-01-01

    The mussels and oyster shell are discarded at environment, and this accumulation is causing negative consequences to ecosystem. Calcium carbonate is main constituent of the shell chemical composition. Aiming to reduce environmental aggression and generate income to shellfish producer, there was the possibility of using these shells as an alternative to commercial calcium carbonate. For this physics, chemicals and thermal properties were evaluated, using X-ray fluorescence, thermogravimetric analysis, size distribution, abrasiveness and scanning electronic microscopy. The results indicate that mussels shells have an initial degradation temperature higher than commercial calcium carbonate e same lost weight behavior and 95% of shell chemical composition is calcium carbonate. The sample size distribution was influenced by grinding condition and time as well as its abrasiveness. (author)

  20. Generation of attosecond electron packets via conical surface plasmon electron acceleration

    Science.gov (United States)

    Greig, S. R.; Elezzabi, A. Y.

    2016-01-01

    We present a method for the generation of high kinetic energy attosecond electron packets via magnetostatic and aperture filtering of conical surface plasmon (SP) accelerated electrons. The conical SP waves are excited by coupling an ultrafast radially polarized laser beam to a conical silica lens coated with an Ag film. Electromagnetic and particle tracking models are employed to characterize the ultrafast electron packets. PMID:26764129

  1. Generalized probabilistic theories and conic extensions of polytopes

    Science.gov (United States)

    Fiorini, Samuel; Massar, Serge; Patra, Manas K.; Tiwary, Hans Raj

    2015-01-01

    Generalized probabilistic theories (GPT) provide a general framework that includes classical and quantum theories. It is described by a cone C and its dual C*. We show that whether some one-way communication complexity problems can be solved within a GPT is equivalent to the recently introduced cone factorization of the corresponding communication matrix M. We also prove an analogue of Holevo's theorem: when the cone C is contained in {{{R}}n}, the classical capacity of the channel realized by sending GPT states and measuring them is bounded by log n. Polytopes and optimising functions over polytopes arise in many areas of discrete mathematics. A conic extension of a polytope is the intersection of a cone C with an affine subspace whose projection onto the original space yields the desired polytope. Extensions of polytopes can sometimes be much simpler geometric objects than the polytope itself. The existence of a conic extension of a polytope is equivalent to that of a cone factorization of the slack matrix of the polytope, on the same cone. We show that all 0/1 polytopes whose vertices can be recognized by a polynomial size circuit, which includes as a special case the travelling salesman polytope and many other polytopes from combinatorial optimization, have small conic extension complexity when the cone is the completely positive cone. Using recent exponential lower bounds on the linear extension complexity of polytopes, this provides an exponential gap between the communication complexity of GPT based on the completely positive cone and classical communication complexity, and a conjectured exponential gap with quantum communication complexity. Our work thus relates the communication complexity of generalizations of quantum theory to questions of mainstream interest in the area of combinatorial optimization.

  2. Generalized probabilistic theories and conic extensions of polytopes

    International Nuclear Information System (INIS)

    Fiorini, Samuel; Massar, Serge; Patra, Manas K; Tiwary, Hans Raj

    2015-01-01

    Generalized probabilistic theories (GPT) provide a general framework that includes classical and quantum theories. It is described by a cone C and its dual C*. We show that whether some one-way communication complexity problems can be solved within a GPT is equivalent to the recently introduced cone factorization of the corresponding communication matrix M. We also prove an analogue of Holevo's theorem: when the cone C is contained in R n , the classical capacity of the channel realized by sending GPT states and measuring them is bounded by logn. Polytopes and optimising functions over polytopes arise in many areas of discrete mathematics. A conic extension of a polytope is the intersection of a cone C with an affine subspace whose projection onto the original space yields the desired polytope. Extensions of polytopes can sometimes be much simpler geometric objects than the polytope itself. The existence of a conic extension of a polytope is equivalent to that of a cone factorization of the slack matrix of the polytope, on the same cone. We show that all 0/1 polytopes whose vertices can be recognized by a polynomial size circuit, which includes as a special case the travelling salesman polytope and many other polytopes from combinatorial optimization, have small conic extension complexity when the cone is the completely positive cone. Using recent exponential lower bounds on the linear extension complexity of polytopes, this provides an exponential gap between the communication complexity of GPT based on the completely positive cone and classical communication complexity, and a conjectured exponential gap with quantum communication complexity. Our work thus relates the communication complexity of generalizations of quantum theory to questions of mainstream interest in the area of combinatorial optimization. (paper)

  3. Design of spheromak injector using conical accelerator for large helical device

    Energy Technology Data Exchange (ETDEWEB)

    Miyazawa, J.; Yamada, H.; Yasui, K.; Kato, S. [National Inst. for Fusion Science, Toki, Gifu (Japan); Fukumoto, N.; Nagata, M.; Uyama, T. [Himeji Inst. of Tech., Hyogo (Japan)

    1999-11-01

    Optimization of CT injector for LHD has been carried out and conical electrode for adiabatic CT compression is adopted in the design. Point-model of CT acceleration in a co-axial electrode is solved to optimize the electrode geometry and the power supplies. Large acceleration efficiency of 34% is to be obtained with 3.2 m long conical accelerator and 40 kV - 42 kJ power supply. The operation scenario of a CT injector named SPICA mk. I (SPheromak Injector using Conical Accelerator) consisting of 0.8 m conical accelerator is discussed based on this design. (author)

  4. Elaboration of the technology of forming a conical product of sheet metal

    Directory of Open Access Journals (Sweden)

    W. Matysiak

    2010-01-01

    Full Text Available The work presents a general knowledge about spinning draw pieces of sheets, one of multi-operational processes of spinning a sheet metal conical product without machining. The objective of the work was to elaborate both the technology of forming conical products of sheet metal and execution of technological tests as well as to determine the technological parameters for the process of spinning a conical insert. As a result of the investigations, the products with improved mechanical properties, stricter execution tolerance and low roughness have been obtained. The series of 200 prototype conical inserts for the shipbuilding industry have been made.

  5. Corrosion behaviour of groundnut shell ash and silicon carbide hybrid reinforced Al-Mg-Si alloy matrix composites in 3.5% NaCl and 0.3M H2SO4 solutions

    Directory of Open Access Journals (Sweden)

    Kenneth Kanayo ALANEME

    2015-05-01

    Full Text Available The corrosion behaviour of Al-Mg-Si alloy based composites reinforced with groundnut shell ash (GSA and silicon carbide (SiC was investigated. The aim is to assess the corrosion properties of Al-Mg-Si alloy based hybrid reinforced composites developed using different mix ratios of GSA (a cheaply processed agro waste derivative which served as partial replacement for SiC and SiC as reinforcing materials. GSA and SiC mixed in weight ratios 0:1, 1:3, 1:1, 3:1, and 1:0 were utilized to prepare 6 and 10 wt% of the reinforcing phase with Al‐Mg‐Si alloy as matrix using two‐step stir casting method. Mass loss and corrosion rate measurement was used to study the corrosion behaviour of the produced composites in 3.5% NaCl and 0.3M H2SO4 solutions. The results show that the Al-Mg-Si alloy based composites containing 6 and 10 wt% GSA and SiC in varied weight ratios were resistant to corrosion in 3.5% NaCl solution. The composites were however more susceptible to corrosion in 0.3M H2SO4 solution (in comparison with the 3.5% NaCl solution. It was noted that the Al-Mg-Si/6 wt% GSA-SiC hybrid composite grades containing GSA and SiC in weight ratio 1:3 and 3:1 respectively exhibited superior corrosion resistance in the 0.3M H2SO4 solution compared to other composites produced for this series. In the case of the Al-Mg-Si/10 wt% GSA-SiC hybrid composite grades, the corrosion resistance was relatively superior for the composites containing a greater weight ratio of GSA (75% and 100% in 0.3M H2SO4 solution.

  6. Conical pinched electron beam diode for intense ion beam source

    International Nuclear Information System (INIS)

    Matsukawa, Yoshinobu; Nakagawa, Yoshiro

    1982-01-01

    For the purpose of improvement of the pinched electron beam diode, the production of an ion beam by a diode with electrodes in a conical shape was studied at low voltage operation (--200 kV). The ion beam is emitted from a small region of the diode apex. The mean ion beam current density near the axis at 12 cm from the diode apex is two or three times that from an usual flat parallel diode with the same dimension and impedance. The brightness and the power brightness at the otigin are 450 MA/cm 2 sr and 0.12 TW/cm 2 sr respectively. (author)

  7. Conical flow near singular rays. [shock generation in ideal gas

    Science.gov (United States)

    Zahalak, G. I.; Myers, M. K.

    1974-01-01

    The steady flow of an ideal gas past a conical body is investigated by the method of matched asymptotic expansions, with particular emphasis on the flow near the singular ray occurring in linearized theory. The first-order problem governing the flow in this region is formulated, leading to the equation of Kuo, and an approximate solution is obtained in the case of compressive flow behind the main front. This solution is compared with the results of previous investigations with a view to assessing the applicability of the Lighthill-Whitham theories.

  8. Radially polarized conical beam from an embedded etched fiber.

    Science.gov (United States)

    Kalaidji, Djamel; Spajer, Michel; Marthouret, Nadège; Grosjean, Thierry

    2009-06-15

    We propose a method for producing a conical beam based on the lateral refraction of the TM(01) mode from a two-mode fiber after chemical etching of the cladding, and for controlling its radial polarization. The whole power of the guided mode is transferred to the refracted beam with low diffraction. Polarization control by a series of azimuthal detectors and a stress controller affords the transmission of a stabilized radial polarization through an optical fiber. A solid component usable for many applications has been obtained.

  9. Interference of conically scattered light in surface plasmon resonance.

    Science.gov (United States)

    Webster, Aaron; Vollmer, Frank

    2013-02-01

    Surface plasmon polaritons on thin metal films are a well studied phenomena when excited using prism coupled geometries such as the Kretschmann attenuated total reflection configuration. Here we describe a novel interference pattern in the conically scattered light emanating from such a configuration when illuminated by a focused beam. We observe conditions indicating only self-interference of scattered surface plasmon polaritions without any contributions from specular reflection. The spatial evolution of this field is described in the context of Fourier optics and has applications in highly sensitive surface plasmon based biosensing.

  10. Simple atom trap in a conical hollow mirror: Numerical analysis

    International Nuclear Information System (INIS)

    Kim, J. A.; Lee, K. I.; Nha, H.; Noh, H. R.; Yoo, S. H.; Jhe, W

    1996-01-01

    We analyze the trap dynamic in a conical hollow (axicon) mirror system. Atom's trajectory is ring shaped if we move the coil (magnetic field) axis off the mirror axis and if we overlap these two axes trap cloud is ball shaped and it is consistent with experiment. We also make a simple comparison between 6-beam MOT and axicon MOT in the ball shaped case, and it shows that at low velocity limit the axicon MOT and typical 6-beam MOT have nearly same trap properties. The axicon trap may be useful as precooled atom source for many other atomic physics experiments such as cold atomic beam, atom funnel, and atom waveguide.

  11. Spatiotemporal dynamics of underwater conical shock wave focusing

    Czech Academy of Sciences Publication Activity Database

    Hoffer, Petr; Lukeš, Petr; Akiyama, H.; Hosseini, H.

    2017-01-01

    Roč. 27, č. 4 (2017), s. 685-690 ISSN 0938-1287 Grant - others:Rada Programu interní podpory projektů mezinárodní spolupráce AV ČR(CZ) M100431203 Program:M Institutional support: RVO:61389021 Keywords : Underwater shock wave focusing * multichannel * electrohydraulic discharge * conical shock wave reflection * medical application Subject RIV: BI - Acoustics OBOR OECD: Applied mechanics Impact factor: 1.107, year: 2016 https://link.springer.com/article/10.1007/s00193-016-0703-7

  12. Preparation of ZnS@In2S3 Core@shell Composite for Enhanced Photocatalytic Degradation of Gaseous o-Dichlorobenzene under Visible Light.

    Science.gov (United States)

    Liu, Baojun; Hu, Xia; Li, Xinyong; Li, Ying; Chen, Chang; Lam, Kwok-Ho

    2017-11-27

    In this study, novel ZnS@In 2 S 3 core@shell hollow nanospheres were fabricated by a facile refluxing method for the first time, and the formation mechanism of hollow structure with interior architecture was discussed based on ion-exchange Ostwald ripening. As the photocatalytic material for degradation of gaseous o-Dichlorobenzene (o-DCB), the as-synthesized core@shell hollow nanospheres were found to show significantly enhanced catalytic performance for effective separation of photo-generated charges. Moreover, the mechanisms of enhanced activity were elucidated by band alignment and unique configuration. Such photocatalyst would meet the demands for the control of persistent organic pollutant (POPs) in the atmospheric environment.

  13. Photonic bandgap narrowing in conical hollow core Bragg fibers

    Energy Technology Data Exchange (ETDEWEB)

    Ozturk, Fahri Emre; Yildirim, Adem; Kanik, Mehmet [UNAM-National Nanotechnology Research Center, Bilkent University, 06800 Ankara (Turkey); Institute of Materials Science and Nanotechnology, Bilkent University, 06800 Ankara (Turkey); Bayindir, Mehmet, E-mail: bayindir@nano.org.tr [UNAM-National Nanotechnology Research Center, Bilkent University, 06800 Ankara (Turkey); Institute of Materials Science and Nanotechnology, Bilkent University, 06800 Ankara (Turkey); Department of Physics, Bilkent University, 06800 Ankara (Turkey)

    2014-08-18

    We report the photonic bandgap engineering of Bragg fibers by controlling the thickness profile of the fiber during the thermal drawing. Conical hollow core Bragg fibers were produced by thermal drawing under a rapidly alternating load, which was applied by introducing steep changes to the fiber drawing speed. In conventional cylindrical Bragg fibers, light is guided by omnidirectional reflections from interior dielectric mirrors with a single quarter wave stack period. In conical fibers, the diameter reduction introduced a gradient of the quarter wave stack period along the length of the fiber. Therefore, the light guided within the fiber encountered slightly smaller dielectric layer thicknesses at each reflection, resulting in a progressive blueshift of the reflectance spectrum. As the reflectance spectrum shifts, longer wavelengths of the initial bandgap cease to be omnidirectionally reflected and exit through the cladding, which narrows the photonic bandgap. A narrow transmission bandwidth is particularly desirable in hollow waveguide mid-infrared sensing schemes, where broadband light is coupled to the fiber and the analyte vapor is introduced into the hollow core to measure infrared absorption. We carried out sensing simulations using the absorption spectrum of isopropyl alcohol vapor to demonstrate the importance of narrow bandgap fibers in chemical sensing applications.

  14. Numerical Study of Motion of Falling Conical Graupel

    Science.gov (United States)

    Chueh, Chih-Che; Wang, Pao K.; Hashino, Tempei

    2018-01-01

    In the present study, the attitudes of freely-falling conical graupel with a realistic range of densities are investigated numerically by solving the transient Navier-Stokes equations and the body dynamics equations representing the 6-degrees-of-freedom motion. This framework allows us to determine the position and orientation of the graupel in response to the hydrodynamic force of the flow fields. The results show more significant horizontal movements than those cases with a fixed bulk density of ice assumed in our previous study. This is because the real graupel particles possess the density less than the bulk density of ice, which, in turn, leads to a relatively small mass and a relatively small set of moments of inertia. We demonstrate that, with the six degrees of freedom considered together, when Reynolds number is small, a typical damped oscillation occurs, whereas when Reynolds number is high, amplifying oscillation may occur which leads to more complicated and unpredictable flying attitudes such as tumbling. The drag coefficients obtained in the present study agree with the previous studies and can be approximated by that of spheres of the same Reynolds numbers. We also show that conical graupel can perform significant horizontal translations which can be on the order of 1 km in 1 h.

  15. Fatigue induced changes in conical implant-abutment connections.

    Science.gov (United States)

    Blum, Kai; Wiest, Wolfram; Fella, Christian; Balles, Andreas; Dittmann, Jonas; Rack, Alexander; Maier, Dominik; Thomann, Ralf; Spies, Benedikt Christopher; Kohal, Ralf Joachim; Zabler, Simon; Nelson, Katja

    2015-11-01

    Based on the current lack of data and understanding of the wear behavior of dental two-piece implants, this study aims for evaluating the microgap formation and wear pattern of different implants in the course of cyclic loading. Several implant systems with different conical implant-abutment interfaces were purchased. The implants were first evaluated using synchrotron X-ray high-resolution radiography (SRX) and scanning electron microscopy (SEM). The implant-abutment assemblies were then subjected to cyclic loading at 98N and their microgap was evaluated after 100,000, 200,000 and 1 million cycles using SRX, synchrotron micro-tomography (μCT). Wear mechanisms of the implant-abutment connection (IAC) after 200,000 cycles and 1 million cycles were further characterized using SEM. All implants exhibit a microgap between the implant and abutment prior to loading. The gap size increased with cyclic loading with its changes being significantly higher within the first 200,000 cycles. Wear was seen in all implants regardless of their interface design. The wear pattern comprised adhesive wear and fretting. Wear behavior changed when a different mounting medium was used (brass vs. polymer). A micromotion of the abutment during cyclic loading can induce wear and wear particles in conical dental implant systems. This feature accompanied with the formation of a microgap at the IAC is highly relevant for the longevity of the implants. Copyright © 2015 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

  16. Generalized synthesis of mesoporous shells on zeolite crystals

    KAUST Repository

    Han, Yu

    2010-12-30

    A simple and generalized synthetic approach is developed for creating mesoporous shells on zeolite crystals. This method allows for the tailoring of thickness, pore size, and composition of the mesoporous shell, and can be applied to zeolites of various structures, compositions, and crystal sizes. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. Core–shell structured FeSiAl/SiO{sub 2} particles and Fe{sub 3}Si/Al{sub 2}O{sub 3} soft magnetic composite cores with tunable insulating layer thicknesses

    Energy Technology Data Exchange (ETDEWEB)

    Fan, Xi’an, E-mail: groupfxa@163.com [The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, Hubei 430081 (China); Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan, Hubei 430081 (China); Wang, Jian, E-mail: snove418562@163.com [The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, Hubei 430081 (China); Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan, Hubei 430081 (China); Wu, Zhaoyang, E-mail: wustwuzhaoyang@163.com [The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, Hubei 430081 (China); Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan, Hubei 430081 (China); Li, Guangqiang, E-mail: ligq-wust@mail.wust.edu.cn [The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan, Hubei 430081 (China); Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan, Hubei 430081 (China)

    2015-11-15

    Graphical abstract: - Highlights: • FeSiAl/SiO{sub 2} core–shell particles and Fe{sub 3}Si/Al{sub 2}O{sub 3} composite cores were prepared. • SiO{sub 2} surrounding FeSiAl were replaced by Al{sub 2}O{sub 3} during sintering process. • Fe{sub 3}Si particles were separated by Al{sub 2}O{sub 3} with tunable thickness in composite cores. • Fe{sub 3}Si/Al{sub 2}O{sub 3} had lower core loss and better frequency stability than FeSiAl core. • The insulating layer between ferromagnetic particles can reduce core loss. - Abstract: FeSiAl/SiO{sub 2} core–shell particles and Fe{sub 3}Si/Al{sub 2}O{sub 3} composite cores with tunable insulating layer thicknesses have been synthesized via a modified Stöber method combined with following high temperature sintering process. Most of the conductive FeSiAl particles could be coated by insulating SiO{sub 2} using the modified Stöber method. During the sintering process, the reaction 4Al + 3SiO{sub 2} ≣ 2α-Al{sub 2}O{sub 3} + 3Si took place and the new Fe{sub 3}Si/Al{sub 2}O{sub 3} composite was formed. The Fe{sub 3}Si/Al{sub 2}O{sub 3} composite cores displayed more excellent soft magnetic properties, better frequency stability at high frequencies, much higher resistivity and lower core loss than the raw FeSiAl core. Based on this, several types of FeSiAl/SiO{sub 2} particles and Fe{sub 3}Si/Al{sub 2}O{sub 3} composite cores with tunable insulating layer thicknesses were selectively prepared by simply varying TEOS contents. The thickness of Al{sub 2}O{sub 3} insulating layer and resistivity of Fe{sub 3}Si/Al{sub 2}O{sub 3} composite cores increased with increasing the TEOS contents, while the permeability and core loss changed in the opposite direction.

  18. ''Electron Conic'' Signatures observed in the nightside auroral zone and over the polar cap

    International Nuclear Information System (INIS)

    Menietti, J.D.; Burch, J.L.

    1985-01-01

    A preliminary search of the Dynamics Explorer 1 high-altitude plasma instrument data base has yielded examples of ''electron conic'' signatures. The three example passes show an association with regions of downward electron acceleration and upward ion beams, but this is not true of all the electron conic events. The electron conic signatures are clearly discernible on energy-flux-versus-time color spectrograms as pairs of discrete vertical bands which are symmetric about a pitch angle of approximately 180 0 . One of the examples is a polar cap pass with electron conic signatures observed at invariant latitudes from 84 0 to 75 0 . The other two cases are nightside auroral zone passes in which the regions of detectable electron conics are spatially more confined, covering only about 1 0 in invariant latitude. The conic signatures have been found at energies that range from 50 eV 0 is larger than expected for a loss cone feature. If the electrons conserve the first adiabatic invariant in a dipole magnetic field, and in some cases a parallel electric field, the mirroring altitude varies between about 500 km and 8000 km, which is above the atmospheric loss region. For this reason, and in analogy with the formation of ion conics, we suggest that the conic signatures are produced by heating of the electrons perpendicular to the magnetic field

  19. Supersymmetric Conical Defects: Towards a string theoretic description of black hole formation

    NARCIS (Netherlands)

    Balasubramanian, V.; de Boer, J.; Keski-Vakkuri, E.; Ross, S.F.

    2001-01-01

    Conical defects, or point particles, in $AdS_3$ are one of the simplest non-trivial gravitating systems, and are particularly interesting because black holes can form from their collision. We embed the BPS conical defects of three dimensions into the N=4b supergravity in six dimensions, which arises

  20. A new design equation for drained stability of conical slopes in cohesive-frictional soils

    Directory of Open Access Journals (Sweden)

    Boonchai Ukritchon

    2018-04-01

    Full Text Available New plasticity solutions to the drained stability of conical slopes in homogeneous cohesive-frictional soils were investigated by axisymmetric finite element limit analysis. Three parameters were studied, i.e. excavated height ratios, slope inclination angles, and soil friction angles. The influences of these parameters on the stability factor and predicted failure mechanism of conical slopes were discussed. A new design equation developed from a nonlinear regression of the lower bound solution was proposed for drained stability analyses of a conical slope in practice. Numerical examples were given to demonstrate a practical application of the proposed equation to stability evaluations of conical slopes with both associated and non-associated flow rules. Keywords: Limit analysis, Slope stability, Conical slope, Unsupported excavation, Cohesive-frictional soils

  1. Influence of surface morphology and UFG on damping and mechanical properties of composite reinforced with spinel MgAl{sub 2}O{sub 4}-SiC core-shell microcomposites

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Subhash; Pal, Kaushik, E-mail: pl_kshk@yahoo.co.in

    2017-01-15

    Interface between ceramic particulate and matrix is known to control the response of the materials and functionality of the composite. Among numerous physical properties, grain structure of the materials has also played a significant role in defining the behaviour of metal matrix composites. Usually, silicon carbide (SiC) particles show poor interfacial wettability in aluminium melt. Herein, we were successfully synthesized magnesium oxide (MgO) and nanocrystalline magnesium aluminate (MgAl{sub 2}O{sub 4}) spinel coated silicon carbide (SiC) core-shell micro-composites through sol-gel technique to improve the wettability of dispersoids. Core-shell structures of submicron size were thoroughly investigated by various characterization techniques. Further, aluminium matrix composites incorporated with pristine SiC, MgO grafted SiC and MgAl{sub 2}O{sub 4} grafted SiC particles were fabricated by stir casting technique, respectively. Additionally, as-cast composites were processed via friction stir processing (FSP) technique to observe the influence of grain refinement on mechanical and damping properties. Electron back scattered diffraction (EBSD), Field emission scanning electron microscopy (FE-SEM) and X-ray energy dispersion spectroscopy (EDX) analysis were conducted for investigating grain size refinement, adequate dispersion, stability and de-agglomeration of encapsulated SiC particles in aluminium matrix. The mechanical as well as thermal cyclic (from − 100 to 400 °C) damping performance of the as-cast and friction stir processed composites were studied, respectively. Finally, the enhanced properties were attributable to reduced agglomeration, stabilization and proper dispersion of the tailored SiC particles Al matrix. - Highlights: •Synthesizing a novel coating layer of MgO and MgAl{sub 2}O{sub 4} spinel onto SiC particles •Significant improvement in UTS and hardness by reinforcing tailored SiC in Al •Significant grain refinements were obtained through

  2. Composites

    International Nuclear Information System (INIS)

    Kasen, M.B.

    1983-01-01

    This chapter discusses the roles of composite laminates and aggregates in cryogenic technology. Filamentary-reinforced composites are emphasized because they are the most widely used composite materials. Topics considered include composite systems and terminology, design and fabrication, composite failure, high-pressure reinforced plastic laminates, low-pressure reinforced plastics, reinforced metals, selectively reinforced structures, the effect of cryogenic temperatures, woven-fabric and random-mat composites, uniaxial fiber-reinforced composites, composite joints in cryogenic structures, joining techniques at room temperature, radiation effects, testing laminates at cryogenic temperatures, static and cyclic tensile testing, static and cyclic compression testing, interlaminar shear testing, secondary property tests, and concrete aggregates. It is suggested that cryogenic composite technology would benefit from the development of a fracture mechanics model for predicting the fitness-for-purpose of polymer-matrix composite structures

  3. Plasmonic effect of Ag@TiO{sub 2} core–shell nanocubes on dye-sensitized solar cell performance based on reduced graphene oxide–TiO{sub 2} nanotube composite

    Energy Technology Data Exchange (ETDEWEB)

    Chandrasekhar, P.S., E-mail: pschandrasekhar9@gmail.com [Centre for Energy Studies, Indian Institute of Technology Delhi, New Delhi 110016 (India); Chander, Nikhil [Centre for Energy Studies, Indian Institute of Technology Delhi, New Delhi 110016 (India); Anjaneyulu, Oruganti [Department of Chemistry, Indian Institute of Technology Delhi, New Delhi 110016 (India); Komarala, Vamsi K., E-mail: vamsi@ces.iitd.ac.in [Centre for Energy Studies, Indian Institute of Technology Delhi, New Delhi 110016 (India)

    2015-11-02

    The role of reduced graphene oxide (RGO) and plasmonic Ag@TiO{sub 2} core–shell nanocubes has been investigated on dye-sensitized solar cell (DSSC) performance based on 1-D TiO{sub 2} nanotubes (TNTs) as photoanodes. A series of cells are fabricated with different amounts of RGO (0.2 to 1.0 wt.%) in TNTs. The incorporation of RGO in TNTs is confirmed by photoluminescence, Raman, and X-ray photoelectron spectroscopy studies. The best performance is achieved with 0.8 wt.% RGO–TNT composite, which exhibited a power conversion efficiency (PCE) of 4.26%, while with bare TNTs, it showed a PCE of 2.85%. The ~ 49% enhancement in PCE with RGO is attributed to the improved dye loading, reduced charge carrier recombination, and high electron transfer efficiency. The enhancement in open circuit voltage (maximum of 50 mV) is also observed with RGO, which is due to the increased electron density in the conduction band of TiO{sub 2} leading to the change in position of quasi Fermi level to higher levels, resulting in shifts towards negative potential side. To further enhance the PCE of DSSCs based on RGO–TNT composites, surface plasmon resonances (SPRs) of silver (Ag) @TiO{sub 2} core–shell nanocubes are also exploited by integrating differing concentrations from 0.1 to 0.3 wt.%. The PCE of plasmonic DSSC is further enhanced to 5.19% with 0.2 wt.% Ag nanocubes. The strong near-fields around the nanocubes (SPR peak spread from 600 to 1000 nm) stimulated the N719 dye for generating more photoelectrons with enhanced light absorption process in broad wavelength region. - Highlights: • Systematic investigation is carried out based on reduced graphene oxide (RGO)–TiO{sub 2} nanotube (TNT) composites as photoanodes. • Surface Plasmon Resonance of Ag@TiO{sub 2} core–shell nanocubes are incorporated in RGO–TNTs to improve the light absorption in near IR regions. • RGO improved the electron transportation by suppressing charge recombination, and also increases the dye

  4. Investigation of fusion gain in fast ignition with conical targets

    Directory of Open Access Journals (Sweden)

    MJ Tabatabaei

    2011-03-01

    Full Text Available Fast ignition is a new scheme for inertial confinement fusion (ICF. In this scheme, at first the interaction of ultraintense laser beam with the hohlraum wall surrounding a capsule containing deuterium-tritium (D-T fuel causes implosion and compression of fuel to high density and then laser produced protons penetrate in the compressed fuel and deposit their energy in it as the ignition hot spot is created. In this paper, following the energy gain of spherical target and considering relationship of the burn fraction to burn duration, we have obtained the energy gain of conical targets characterized by the angle β, and found a hemispherical capsule (β=π/2 has a gain as high as 96% of that of the whole spherical capsule. The results obtained in this study are qualitatively consistent with Atzeni et al.'s studies of simulations.

  5. Analysis of turbulent conical diffuser flow using second moment closures

    International Nuclear Information System (INIS)

    Adane, K.K.; Tachie, M.F.; Ormiston, S.J.

    2004-01-01

    A commercial CFD code, CFX-TASCflow, is used to predict a turbulent conical diffuser flow. The computation was performed using a low-Reynolds number k-ω model, a low-Reynolds number k-ω based non-linear algebraic Reynolds stress model, and a second moment closure with a wall-function. The experimental data of Kassab are used to validate the numerical results. The results show that all the turbulence models reproduce the static pressure coefficient distribution reasonably well. The low Reynolds number k-ω models give better prediction of the friction velocity than the second moment closure. The models also predict the Reynolds shear stress reasonably well but fail to reproduce the correct level of the turbulent kinetic energy. (author)

  6. The mechanical response of tetragonal zirconia polycrystal to conical indentation

    International Nuclear Information System (INIS)

    Asif, S.A.S.; Biswas, S.K.

    1994-01-01

    Blocks of 3Y-TZP were indented with conical diamond indenters. Indentation caused tetragonal to monoclinic phase transformation in a subsurface. Of the cracks generated in the subsurface, radial and lateral cracks can be accounted for by a continuum model of the indented subsurface, built using a combination of the Boussinesq and blister stress fields. Additional ring, median and cone cracks were also observed. It is hypothesized that the latter are motivated by the reduction in blister strength or residual energy brought about by the material damage caused by the phase transformation. This damage reduces the load bearing capacity of the material progressively with increasing normal load. (author). 13 refs., 5 figs., 2 tabs

  7. Thermal design of AOTV heatshields for a conical drag brake

    Science.gov (United States)

    Pitts, W. C.; Murbach, M. S.

    1985-01-01

    Results are presented from an on-going study of the thermal performance of thermal protection systems for a conical drag brake type AOTV. Three types of heatshield are considered: rigid ceramic insulation, flexible ceramic blankets, and ceramic cloths. The results for the rigid insulation apply to other types of AOTV as well. Charts are presented in parametric form so that they may be applied to a variety of missions and vehicle configurations. The parameters considered include: braking maneuver heat flux and total heat load, heatshield material and thickness, heatshield thermal mass and conductivity, absorptivity and emissivity of surfaces, thermal mass of support structure, and radiation transmission through thin heatshields. Results of temperature calculations presented show trends with and sensitivities to these parameters. The emphasis is on providing information that will be useful in estimating the minimum required mass of these heatshield materials.

  8. Straight, conic and circular fringes in single interferogram

    International Nuclear Information System (INIS)

    Rajkumar

    2015-01-01

    Interferometry is an important part of optics courses taught at the undergraduate level in universities throughout the world. It is used to explain to students the wave nature of light and is also used to measure parameters like length, refractive index, thickness of test samples and wavelength of light source, etc. The shape of interference fringes (linear, conic or circular) gives vital information about the interfering wavefronts and is used for firsthand visual inspection in optical shop testing and other applications of scientific and engineering importance. The present work describes a simple laboratory technique to generate fringes with different shapes in a single interferogram. This is achieved by using our diffraction-Lloyd mirror interferometer where two portions of the diffracted field are superimposed to generate the interference fringes. The technique is quite helpful in explaining the role of source orientation on the shape of interference fringes to students. (paper)

  9. Conical Refraction Bottle Beams for Entrapment of Absorbing Droplets.

    Science.gov (United States)

    Esseling, Michael; Alpmann, Christina; Schnelle, Jens; Meissner, Robert; Denz, Cornelia

    2018-03-22

    Conical refraction (CR) optical bottle beams for photophoretic trapping of airborne absorbing droplets are introduced and experimentally demonstrated. CR describes the circular split-up of unpolarised light propagating along an optical axis in a biaxial crystal. The diverging and converging cones lend themselves to the construction of optical bottle beams with flexible entry points. The interaction of single inkjet droplets with an open or partly open bottle beam is shown implementing high-speed video microscopy in a dual-view configuration. Perpendicular image planes are visualized on a single camera chip to characterize the integral three-dimensional movement dynamics of droplets. We demonstrate how a partly opened optical bottle transversely confines liquid objects. Furthermore we observe and analyse transverse oscillations of absorbing droplets as they hit the inner walls and simultaneously measure both transverse and axial velocity components.

  10. Performance of cylindrical-conical cyclones with different geometrical configurations

    Directory of Open Access Journals (Sweden)

    J.D.A.M. Santana

    2001-09-01

    Full Text Available The present work is a continuation of a study of the influence of geometric characteristics on the performance of reverse-flow cylindrical-conical cyclones. After studying the behavior of the pressure drop in previous work (Arnosti et al., 1998, here performance in terms of collection efficiency in the removal of particulate material is addressed. The independent variables considered in this study were inlet gas velocity (three velocities and the following dimensions of the cyclone: the cylindrical section (three heights and internal height of the gas exit duct (three heights. The tests were performed using an 3³ experimental design. Analysis of the results for overall efficiency was carried out using response surfaces and the statistical parameters were estimated from linear regression.

  11. Thermodynamical description of stationary, asymptotically flat solutions with conical singularities

    International Nuclear Information System (INIS)

    Herdeiro, Carlos; Rebelo, Carmen; Radu, Eugen

    2010-01-01

    We examine the thermodynamical properties of a number of asymptotically flat, stationary (but not static) solutions having conical singularities, with both connected and nonconnected event horizons, using the thermodynamical description recently proposed in [C. Herdeiro, B. Kleihaus, J. Kunz, and E. Radu, Phys. Rev. D 81, 064013 (2010).]. The examples considered are the double-Kerr solution, the black ring rotating in either S 2 or S 1 , and the black Saturn, where the balance condition is not imposed for the latter two solutions. We show that not only the Bekenstein-Hawking area law is recovered from the thermodynamical description, but also the thermodynamical angular momentum is the Arnowitt-Deser-Misner angular momentum. We also analyze the thermodynamical stability and show that, for all these solutions, either the isothermal moment of inertia or the specific heat at constant angular momentum is negative, at any point in parameter space. Therefore, all these solutions are thermodynamically unstable in the grand canonical ensemble.

  12. Analytical Investigation of Elastic Thin-Walled Cylinder and Truncated Cone Shell Intersection Under Internal Pressure.

    Science.gov (United States)

    Zamani, J; Soltani, B; Aghaei, M

    2014-10-01

    An elastic solution of cylinder-truncated cone shell intersection under internal pressure is presented. The edge solution theory that has been used in this study takes bending moments and shearing forces into account in the thin-walled shell of revolution element. The general solution of the cone equations is based on power series method. The effect of cone apex angle on the stress distribution in conical and cylindrical parts of structure is investigated. In addition, the effect of the intersection and boundary locations on the circumferential and longitudinal stresses is evaluated and it is shown that how quantitatively they are essential.

  13. Conical refraction of elastic waves in absorbing crystals

    International Nuclear Information System (INIS)

    Alshits, V. I.; Lyubimov, V. N.

    2011-01-01

    The absorption-induced acoustic-axis splitting in a viscoelastic crystal with an arbitrary anisotropy is considered. It is shown that after “switching on” absorption, the linear vector polarization field in the vicinity of the initial degeneracy point having an orientation singularity with the Poincaré index n = ±1/2, transforms to a planar distribution of ellipses with two singularities n = ±1/4 corresponding to new axes. The local geometry of the slowness surface of elastic waves is studied in the vicinity of new degeneracy points and a self-intersection line connecting them. The absorption-induced transformation of the classical picture of conical refraction is studied. The ellipticity of waves at the edge of the self-intersection wedge in a narrow interval of propagation directions drastically changes from circular at the wedge ends to linear in the middle of the wedge. For the wave normal directed to an arbitrary point of this wedge, during movement of the displacement vector over the corresponding polarization ellipse, the wave ray velocity s runs over the same cone describing refraction in a crystal without absorption. In this case, the end of the vector moves along a universal ellipse whose plane is orthogonal to the acoustic axis for zero absorption. The areal velocity of this movement differs from the angular velocity of the displacement vector on the polarization ellipse only by a constant factor, being delayed by π/2 in phase. When the wave normal is localized at the edge of the wedge in its central region, the movement of vector s along the universal ellipse becomes drastically nonuniform and the refraction transforms from conical to wedge-like.

  14. Early structure of LPG partially premixed conically stabilized flames

    KAUST Repository

    Elbaz, Ayman M.

    2013-01-01

    This paper presents experimental investigation of LPG partially premixed turbulent flames stabilized within a conical nozzle burner under constant degree of partial premixing. The stability limits and mean flame structure are presented based on the mean gas temperature and the concentration of CO, O 2, NO, and HC at the flame early region of reaction. The investigation covered the influence of the nozzle cone angle, the jet exit velocity and the jet equivalence ratio. The stability results show that the flames with cone are more stable than those without cone. For conical stabilized flames, the stability results exhibit three different sensitivity regions between the jet velocity and equivalence ratio. The inflame measurements prove that the flame stability could be attributed to the triple flame structure at the flame leading edge. The data show that the triple flame structure is influenced by cone angle, the jet velocity and the equivalence ratio. The flame is believed to be controlled by the recirculation flow inside the cone. Increasing the cone angle induced higher air entrainment to the reaction zone as depicted by a higher O 2 concentration within the flame leading edge. Increasing the jet velocity to a certain limit enhances the intensity of combustion at the flame leading edge, while excessive increase in jet velocity reduces this intensity. At a fixed jet velocity the higher the equivalence ratio, the higher the amount of fuel diffused and engulfed to the reaction zone, the more delay of the combustion completion and the higher the emission concentrations of the flame. © 2012 Elsevier Inc.

  15. High-latitude Conic Current Sheets in the Solar Wind

    Energy Technology Data Exchange (ETDEWEB)

    Khabarova, Olga V.; Obridko, Vladimir N.; Kharshiladze, Alexander F. [Pushkov Institute of Terrestrial Magnetism, Ionosphere and Radio Wave Propagation of the Russian Academy of Sciences (IZMIRAN), Moscow (Russian Federation); Malova, Helmi V. [Scobeltsyn Nuclear Physics Institute of Lomonosov Moscow State University, Moscow (Russian Federation); Kislov, Roman A.; Zelenyi, Lev M. [Space Research Centre of the Polish Academy of Sciences (CBK PAN), Warsaw (Poland); Tokumaru, Munetoshi; Fujiki, Ken’ichi [Institute for Space-Earth Environmental Research, Nagoya University (Japan); Sokół, Justyna M.; Grzedzielski, Stan [Space Research Centre of the Polish Academy of Sciences (CBK), Warsaw (Poland)

    2017-02-10

    We provide observational evidence for the existence of large-scale cylindrical (or conic-like) current sheets (CCSs) at high heliolatitudes. Long-lived CCSs were detected by Ulysses during its passages over the South Solar Pole in 1994 and 2007. The characteristic scale of these tornado-like structures is several times less than a typical width of coronal holes within which the CCSs are observed. CCS crossings are characterized by a dramatic decrease in the solar wind speed and plasma beta typical for predicted profiles of CCSs. Ulysses crossed the same CCS at different heliolatitudes at 2–3 au several times in 1994, as the CCS was declined from the rotation axis and corotated with the Sun. In 2007, a CCS was detected directly over the South Pole, and its structure was strongly highlighted by the interaction with comet McNaught. Restorations of solar coronal magnetic field lines reveal the occurrence of conic-like magnetic separators over the solar poles in both 1994 and 2007. Such separators exist only during solar minima. Interplanetary scintillation data analysis confirms the presence of long-lived low-speed regions surrounded by the typical polar high-speed solar wind in solar minima. Energetic particle flux enhancements up to several MeV/ nuc are observed at edges of the CCSs. We built simple MHD models of a CCS to illustrate its key features. The CCSs may be formed as a result of nonaxiality of the solar rotation axis and magnetic axis, as predicted by the Fisk–Parker hybrid heliospheric magnetic field model in the modification of Burger and coworkers.

  16. Gold-coated silicon nanowire-graphene core-shell composite film as a polymer binder-free anode for rechargeable lithium-ion batteries

    Science.gov (United States)

    Kim, Han-Jung; Lee, Sang Eon; Lee, Jihye; Jung, Joo-Yun; Lee, Eung-Sug; Choi, Jun-Hyuk; Jung, Jun-Ho; Oh, Minsub; Hyun, Seungmin; Choi, Dae-Geun

    2014-07-01

    We designed and fabricated a gold (Au)-coated silicon nanowires/graphene (Au-SiNWs/G) hybrid composite as a polymer binder-free anode for rechargeable lithium-ion batteries (LIBs). A large amount of SiNWs for LIB anode materials can be prepared by metal-assisted chemical etching (MaCE) process. The Au-SiNWs/G composite film on current collector was obtained by vacuum filtration using an anodic aluminum oxide (AAO) membrane and hot pressing method. Our experimental results show that the Au-SiNWs/G composite has a stable reversible capacity of about 1520 mA h/g which was maintained for 20 cycles. The Au-SiNWs/G composite anode showed much better cycling performance than SiNWs/polyvinylidene fluoride (PVDF)/Super-P, SiNWs/G composite, and pure SiNWs anodes. The improved electrochemical properties of the Au-SiNWs/G composite anode material is mainly ascribed to the composite's porous network structure.

  17. Pseudodirect to Direct Compositional Crossover in Wurtzite GaP/InxGa1–xP Core–Shell Nanowires

    KAUST Repository

    Gagliano, L.

    2016-11-29

    Thanks to their uniqueness, nanowires allow the realization of novel semiconductor crystal structures with yet unexplored properties, which can be key to overcome current technological limits. Here we develop the growth of wurtzite GaP/InGaP core-shell nanowires with tunable indium concentration and optical emission in the visible region from 590 nm (2.1 eV) to 760 nm (1.6 eV). We demonstrate a pseudodirect (δ-δ) to direct (δ-δ) transition crossover through experimental and theoretical approach. Time resolved and temperature dependent photoluminescence measurements were used, which led to the observation of a steep change in carrier lifetime and temperature dependence by respectively one and 3 orders of magnitude in the range 0.28 ± 0.04 ≤ x ≤ 0.41 ± 0.04. Our work reveals the electronic properties of wurtzite InGaP.

  18. Composition

    DEFF Research Database (Denmark)

    Bergstrøm-Nielsen, Carl

    2011-01-01

    Strategies are open compositions to be realised by improvising musicians. See more about my composition practise in the entry "Composition - General Introduction". Caution: streaming the sound files will in some cases only provide a few minutes' sample. Please DOWNLOAD them to hear them in full...

  19. Composition

    DEFF Research Database (Denmark)

    2014-01-01

    Memory Pieces are open compositions to be realised solo by an improvising musicians. See more about my composition practise in the entry "Composition - General Introduction". Caution: streaming the sound files will in some cases only provide a few minutes' sample. Please DOWNLOAD them to hear them...

  20. Test Report for Cesium and Solids Removal from an 11.5L Composite of Archived Hanford Double Shell Tank Supernate for Off-Site Disposal.

    Energy Technology Data Exchange (ETDEWEB)

    Doll, S. R.; Cooke, G. A.

    2017-08-31

    The 222-S Laboratory blended supernate waste from Hanford Tanks 241-AN-101, 241-AN- 106, 241-AP-105, 241-AP-106, 241-AP-107, and 241-AY-101 from the hot cell archive to create a bulk composite. The composite was blended with 600 mL 19.4 M NaOH, which brought the total volume to approximately 11.5 L (3 gal). The composite was filtered to remove solids and passed through spherical resorcinol-formaldehyde ion-exchange resin columns to remove cesium. The composite masses were tracked as a treatability study. Samples collected before, during, and after the ion exchange process were characterized for a full suite of analytes (inorganic, organic, and radionuclides) to aid in the classification of the waste for shipping, receiving, treatment, and disposal determinations.

  1. Test Report for Cesium and Solids Removal from an 11.5L Composite of Archived Hanford Double Shell Tank Supernate for Off-Site Disposal

    Energy Technology Data Exchange (ETDEWEB)

    Doll, Stephanie R. [Hanford Site (HNF), Richland, WA (United States); Cooke, Gary A. [Hanford Site (HNF), Richland, WA (United States)

    2017-08-31

    The 222-S Laboratory blended supernate waste from Hanford Tanks 241-AN-101, 241-AN- 106, 241-AP-105, 241-AP-106, 241-AP-107, and 241-AY-101 from the hot cell archive to create a bulk composite. The composite was blended with 600 mL 19.4 M NaOH, which brought the total volume to approximately 11.5 L (3 gal). The composite was filtered to remove solids and passed through spherical resorcinol-formaldehyde ion-exchange resin columns to remove cesium. The composite masses were tracked as a treatability study. Samples collected before, during, and after the ion-exchange process were characterized for a full suite of analytes (inorganic, organic, and radionuclides) to aid in the classification of the waste for shipping, receiving, treatment, and disposal determinations.

  2. Improving dielectric properties of BaTiO{sub 3}/poly(vinylidene fluoride) composites by employing core-shell structured BaTiO{sub 3}@Poly(methylmethacrylate) and BaTiO{sub 3}@Poly(trifluoroethyl methacrylate) nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Xianhong; Zhao, Sidi; Wang, Fang [Key Laboratory of Carbon Fiber and Functional Polymers, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029 (China); Ma, Yuhong, E-mail: mayh@mail.buct.edu.cn [Key Laboratory of Carbon Fiber and Functional Polymers, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029 (China); Beijing Engineering Research Center of Syntheses and Applications of Waterborne Polymers, Beijing University of Chemical Technology, 100029 (China); Wang, Li; Chen, Dong; Zhao, Changwen [Key Laboratory of Carbon Fiber and Functional Polymers, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029 (China); Beijing Engineering Research Center of Syntheses and Applications of Waterborne Polymers, Beijing University of Chemical Technology, 100029 (China); Yang, Wantai, E-mail: yangwt@mail.buct.edu.cn [Key Laboratory of Carbon Fiber and Functional Polymers, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029 (China); Beijing Engineering Research Center of Syntheses and Applications of Waterborne Polymers, Beijing University of Chemical Technology, 100029 (China)

    2017-05-01

    Highlights: • Core-shell structured BT@PMMA and BT@PTFEMA nanoparticles were synthesized. • The dispersity of BT nanoparticles in PVDF matrix was improved significantly. • Dielectric properties both of BT@PMMA/PVDF and BT@PTFEMA/PVDF composites were improved. • The frequency dependence of dielectric constant attenuation of BT@PTFEMA/PVDF composites was smaller than that of BT@PMMA/PVDF composites. - Abstract: Polymer based dielectric composites were fabricated through incorporation of core-shell structured BaTiO{sub 3} (BT) nanoparticles into PVDF matrix by means of solution blending. Core-shell structured BT nanoparticles with different shell composition and shell thickness were prepared by grafting methacrylate monomer (MMA or TFEMA) onto the surface of BT nanoparticles via surface initiated atom transfer radical polymerization (SI-ATRP). The content of the grafted polymer and the micro-morphology of the core-shell structured BT nanoparticles were investigated by thermo gravimetric analyses (TGA) and transmission electron microscopy (TEM), respectively. The dielectric properties were measured by broadband dielectric spectroscopy. The results showed that high dielectric constant and low dielectric loss are successfully realized in the polymer based composites. Moreover, the type of the grafted polymer and its content had different effect on the dielectric constant. In detail, the attenuation of dielectric constant was 16.6% for BT@PMMA1/PVDF and 10.7% for BT@PMMA2/PVDF composite in the range of 10 Hz to 100 kHz, in which the grafted content of PMMA was 5.5% and 8.0%, respectively. However, the attenuation of dielectric constant was 5.5% for BT@PTFEMA1/PVDF and 4.0% for BT@PTFEMA2/PVDF composite, in which the grafted content of PTFEMA was 1.5% and 2.0%, respectively. These attractive features of BT@PTFEMA/PVDF composites suggested that dielectric ceramic fillers modified with fluorinated polymer can be used to prepare high performance composites, especially

  3. Investigation of turbulence measurements with a continuous wave, conically scanning LiDAR

    DEFF Research Database (Denmark)

    Wagner, Rozenn; Mikkelsen, Torben; Courtney, Michael

    averaging is done in two steps: 1) the weighted averaging of the wind speed in the probe volume of the laser beam; 2) the averaging of the wind speeds occurring on the circular path described by the conically scanning lidar. Therefore the standard deviation measured by a lidar resolves only the turbulence...... of a continuous wave, conically scanning Zephir lidar. First, the wind speed standard deviation measured by such a lidar gives on average 80% of the standard deviation measured by a cup anemometer. This difference is due to the spatial averaging inherently made by a cw conically scanning lidar. The spatial...

  4. Experimental study of CF4 conical theta pinch plasma expanding into vacuum

    International Nuclear Information System (INIS)

    Pedrow, P.D.; Nasiruddin, A.M.

    1989-01-01

    Langmuir probe, photodiode, and optical multichannel analyzer (OMA) measurements have been made on a pulsed CF 4 conical theta pinch plasma. A cloud of CF 4 gas was puffed into a conical theta pinch coil, converted to plasma, and propelled into the vacuum region ahead of the expanding gas cloud. At a position 67 cm away from the conical theta pinch coil, the plasma arrived in separate packets that were about 20 μs in duration. The average drift velocity of these packets corresponded to an energy of about 3 eV. The OMA measurements showed that the second packet contained neutral atomic fluorine as well as charged particles

  5. Analysis of spatial dispersion characteristics of improved conical sprays; Kairyo kasajo funmu no kukan bunsansei no kento

    Energy Technology Data Exchange (ETDEWEB)

    Long, W; Murakami, A; Hama, J [Mechanical Engineering Lab., Tokyo (Japan); Obokata, T [Gunma University, Gunma (Japan)

    1997-10-01

    The macro-characteristics of conical and improved conical sprays were analyzed using laser sheet and high speed camera. The injection pressure was 14.7, 24.5 or 34.3 MPa and the chamber pressure was 0.098, 0.98 or 1.96 MPa, where the amount of injected fuel was 28.5 mg per cycle, and the injection frequency was 8.3 Hz. As a result, at atmospheric pressure, both of the conical spray and improved conical spray have a conical pattern, but at high chamber pressure, the sprays become three dimensional. The penetration of the improved conical spray was about 25% stronger than that of the conical spray. 10 refs., 11 figs.

  6. Synthesis of parallel and antiparallel core-shell triangular nanoparticles

    Science.gov (United States)

    Bhattacharjee, Gourab; Satpati, Biswarup

    2018-04-01

    Core-shell triangular nanoparticles were synthesized by seed mediated growth. Using triangular gold (Au) nanoparticle as template, we have grown silver (Ag) shellto get core-shell nanoparticle. Here by changing the chemistry we have grown two types of core-shell structures where core and shell is having same symmetry and also having opposite symmetry. Both core and core-shell nanoparticles were characterized using transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDX) to know the crystal structure and composition of these synthesized core-shell nanoparticles. From diffraction pattern analysis and energy filtered TEM (EFTEM) we have confirmed the crystal facet in core is responsible for such two dimensional growth of core-shell nanostructures.

  7. Soft template synthesis of yolk/silica shell particles.

    Science.gov (United States)

    Wu, Xue-Jun; Xu, Dongsheng

    2010-04-06

    Yolk/shell particles possess a unique structure that is composed of hollow shells that encapsulate other particles but with an interstitial space between them. These structures are different from core/shell particles in that the core particles are freely movable in the shell. Yolk/shell particles combine the properties of each component, and can find potential applications in catalysis, lithium ion batteries, and biosensors. In this Research News article, a soft-template-assisted method for the preparation of yolk/silica shell particles is presented. The demonstrated method is simple and general, and can produce hollow silica spheres incorporated with different particles independent of their diameters, geometry, and composition. Furthermore, yolk/mesoporous silica shell particles and multishelled particles are also prepared through optimization of the experimental conditions. Finally, potential applications of these particles are discussed.

  8. Slow pyrolysis of pistachio shell

    Energy Technology Data Exchange (ETDEWEB)

    Apaydin-Varol, Esin; Putun, Ersan; Putun, Ayse E [Anadolu University, Eskisehir (Turkey). Department of Chemical Engineering

    2007-08-15

    In this study, pistachio shell is taken as the biomass sample to investigate the effects of pyrolysis temperature on the product yields and composition when slow pyrolysis is applied in a fixed-bed reactor at atmospheric pressure to the temperatures of 300, 400, 500, 550, 700{sup o}C. The maximum liquid yield was attained at about 500-550{sup o}C with a yield of 20.5%. The liquid product obtained under this optimum temperature and solid products obtained at all temperatures were characterized. As well as proximate and elemental analysis for the products were the basic steps for characterization, column chromatography, FT-IR, GC/MS and SEM were used for further characterization. The results showed that liquid and solid products from pistachio shells show similarities with high value conventional fuels. 31 refs., 9 figs., 1 tab.

  9. AT Cnc: A SECOND DWARF NOVA WITH A CLASSICAL NOVA SHELL

    International Nuclear Information System (INIS)

    Shara, Michael M.; Mizusawa, Trisha; Zurek, David; Wehinger, Peter; Martin, Christopher D.; Neill, James D.; Forster, Karl; Seibert, Mark

    2012-01-01

    We are systematically surveying all known and suspected Z Cam-type dwarf novae for classical nova shells. This survey is motivated by the discovery of the largest known classical nova shell, which surrounds the archetypal dwarf nova Z Camelopardalis. The Z Cam shell demonstrates that at least some dwarf novae must have undergone classical nova eruptions in the past, and that at least some classical novae become dwarf novae long after their nova thermonuclear outbursts, in accord with the hibernation scenario of cataclysmic binaries. Here we report the detection of a fragmented 'shell', 3 arcmin in diameter, surrounding the dwarf nova AT Cancri. This second discovery demonstrates that nova shells surrounding Z Cam-type dwarf novae cannot be very rare. The shell geometry is suggestive of bipolar, conical ejection seen nearly pole-on. A spectrum of the brightest AT Cnc shell knot is similar to that of the ejecta of the classical nova GK Per, and of Z Cam, dominated by [N II] emission. Galaxy Evolution Explorer FUV imagery reveals a similar-sized, FUV-emitting shell. We determine a distance of 460 pc to AT Cnc, and an upper limit to its ejecta mass of ∼5 × 10 –5 M ☉ , typical of classical novae.

  10. AT Cnc: A SECOND DWARF NOVA WITH A CLASSICAL NOVA SHELL

    Energy Technology Data Exchange (ETDEWEB)

    Shara, Michael M.; Mizusawa, Trisha; Zurek, David [Department of Astrophysics, American Museum of Natural History, Central Park West at 79th Street, New York, NY 10024-5192 (United States); Wehinger, Peter [Steward Observatory, the University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721 (United States); Martin, Christopher D.; Neill, James D.; Forster, Karl [Department of Physics, Math and Astronomy, California Institute of Technology, 1200 East California Boulevard, Mail Code 405-47, Pasadena, CA 91125 (United States); Seibert, Mark [Observatories of the Carnegie Institution of Washington, 813 Santa Barbara Street, Pasadena, CA 91101 (United States)

    2012-10-20

    We are systematically surveying all known and suspected Z Cam-type dwarf novae for classical nova shells. This survey is motivated by the discovery of the largest known classical nova shell, which surrounds the archetypal dwarf nova Z Camelopardalis. The Z Cam shell demonstrates that at least some dwarf novae must have undergone classical nova eruptions in the past, and that at least some classical novae become dwarf novae long after their nova thermonuclear outbursts, in accord with the hibernation scenario of cataclysmic binaries. Here we report the detection of a fragmented 'shell', 3 arcmin in diameter, surrounding the dwarf nova AT Cancri. This second discovery demonstrates that nova shells surrounding Z Cam-type dwarf novae cannot be very rare. The shell geometry is suggestive of bipolar, conical ejection seen nearly pole-on. A spectrum of the brightest AT Cnc shell knot is similar to that of the ejecta of the classical nova GK Per, and of Z Cam, dominated by [N II] emission. Galaxy Evolution Explorer FUV imagery reveals a similar-sized, FUV-emitting shell. We determine a distance of 460 pc to AT Cnc, and an upper limit to its ejecta mass of {approx}5 Multiplication-Sign 10{sup -5} M {sub Sun }, typical of classical novae.

  11. Change of Pressing Chamber Conicalness at Briquetting Process in Briquetting Machine Pressing Chamber

    Directory of Open Access Journals (Sweden)

    Peter Križan

    2012-01-01

    Full Text Available In this paper, we will present the impact of the conical shape of a pressing chamber, an important structural parameter. Besides the known impact of the technological parameters of pressing chambers, it is also very important to pay attention to their structural parameters. In the introduction, we present a theoretical analysis of pressing chamber conicalness. An experiment aimed at detecting this impact was performed at our institute, and it showed that increasing the conicalness of a pressing chamber improves the quality of the final briquettes. The conicalness of the pressing chamber has a significanteffect on the final briquette quality and on the construction of briquetting machines. The experimental findings presented here show the importance of this parameter in the briquetting process.

  12. Convergence of shock waves between conical and parabolic boundaries

    Energy Technology Data Exchange (ETDEWEB)

    Yanuka, D.; Zinowits, H. E.; Antonov, O.; Efimov, S.; Virozub, A.; Krasik, Ya. E. [Physics Department, Technion, Haifa 32000 (Israel)

    2016-07-15

    Convergence of shock waves, generated by underwater electrical explosions of cylindrical wire arrays, between either parabolic or conical bounding walls is investigated. A high-current pulse with a peak of ∼550 kA and rise time of ∼300 ns was applied for the wire array explosion. Strong self-emission from an optical fiber placed at the origin of the implosion was used for estimating the time of flight of the shock wave. 2D hydrodynamic simulations coupled with the equations of state of water and copper showed that the pressure obtained in the vicinity of the implosion is ∼7 times higher in the case of parabolic walls. However, comparison with a spherical wire array explosion showed that the pressure in the implosion vicinity in that case is higher than the pressure in the current experiment with parabolic bounding walls because of strong shock wave reflections from the walls. It is shown that this drawback of the bounding walls can be significantly minimized by optimization of the wire array geometry.

  13. The fastest drop climbing on a wet conical fibre

    KAUST Repository

    Li, Erqiang; Thoroddsen, Sigurdur T

    2013-01-01

    We use high-speed video imaging to study the capillary-driven motion of a micro-droplet along the outside of a pre-wetted conical fiber. The cones are fabricated on a glass-puller with tip diameters as small as 1 μm, an order of magnitude smaller than in previous studies. The liquid is fed through the hollow fiber accumulating at the fiber tip to form droplets. The droplets are initially attached to the opening as they grow in size before detaching and traveling up the cone. This detachment can produce a transient oscillation of high frequency. The spatial variation of the capillary pressure drives the droplets towards the wider side of the cone. Various liquids were used to change the surface tension by a factor of 3.5 and viscosity by a factor of 1500. Within each droplet size and viscous-dissipation regime, the data for climbing speeds collapse on a single curve. Droplets traveling with and against gravity allow us to pinpoint the absolute strength of the driving capillary pressure and viscous stresses and thereby determine the prefactors in the dimensionless relationships. The motions are consistent with earlier results obtained from much larger cones. Translation velocities up to 270 mm/s were observed and overall the velocities follow capillary-viscous scaling, whereas the speed of the fastest droplets is limited by inertia following their emergence at the cone tip.

  14. Conical singularities in AdS space time

    International Nuclear Information System (INIS)

    Ferreira, Cristine Nunes

    2011-01-01

    Full text: In recent years, the study of conformal gauge theories from 10-D has been motivated by the AdS d+1 /CFT d correspondence, first conjectured by J. Maldacena. The aim of this work is to consider the d = 4 case by analysing the configuration of the N coincident D3 branes. In this context, the work shows that there is a duality between type IIB string theory in AdS 5 x S 5 and N = 4 SU(N) Super Yang-Mills Theory in the IR. The AdS 5 /CFT 4 correspondence brought also new approaches to the strong coupling problem in QCD. Nowadays, there is a whole line of works that focus on the low dimensional correspondence AdS 4 /CFT 3 , like the application to graphene and topological insulators, and the AdS 3 /CFT 2 correspondence, related with the entanglement entropy. In this work, we consider the vortex configuration solution to the AdS 4 and AdS 3 space-time. The most important motivation is to discuss the boundary theory resulting from these solutions. We have examined a straightforward approach to a holographic computation of the graphene and entanglement entropy in the presence of the conical singularity. After this analysis, we consider the scalar field in the bulk in the presence of this metrics and work out the compactification modes. Taking the holographic point of view, we study and discuss the resulting Green function. (author)

  15. Weakly nonlinear sloshing in a truncated circular conical tank

    International Nuclear Information System (INIS)

    Gavrilyuk, I P; Hermann, M; Lukovsky, I A; Solodun, O V; Timokha, A N

    2013-01-01

    Sloshing of an ideal incompressible liquid in a rigid truncated (tapered) conical tank is considered when the tank performs small-magnitude oscillatory motions with the forcing frequency close to the lowest natural sloshing frequency. The multimodal method, the non-conformal mapping technique and the Moiseev type asymptotics are employed to derive a finite-dimensional system of weakly nonlinear ordinary differential (modal) equations. This modal system is a generalization of that by Gavrilyuk et al 2005 Fluid Dyn. Res. 37 399–429. Using the derived modal equations, we classify the resonant steady-state wave regimes occurring due to horizontal harmonic tank excitations. The frequency ranges are detected where the ‘planar’ and/or ‘swirling’ steady-state sloshing are stable as well as a range in which all steady-state wave regimes are not stable and irregular (chaotic) liquid motions occur is established. The results on the frequency ranges are qualitatively supported by experiments by Matta E 2002 PhD Thesis Politecnico di Torino, Torino. (paper)

  16. The fastest drop climbing on a wet conical fibre

    KAUST Repository

    Li, Erqiang

    2013-05-21

    We use high-speed video imaging to study the capillary-driven motion of a micro-droplet along the outside of a pre-wetted conical fiber. The cones are fabricated on a glass-puller with tip diameters as small as 1 μm, an order of magnitude smaller than in previous studies. The liquid is fed through the hollow fiber accumulating at the fiber tip to form droplets. The droplets are initially attached to the opening as they grow in size before detaching and traveling up the cone. This detachment can produce a transient oscillation of high frequency. The spatial variation of the capillary pressure drives the droplets towards the wider side of the cone. Various liquids were used to change the surface tension by a factor of 3.5 and viscosity by a factor of 1500. Within each droplet size and viscous-dissipation regime, the data for climbing speeds collapse on a single curve. Droplets traveling with and against gravity allow us to pinpoint the absolute strength of the driving capillary pressure and viscous stresses and thereby determine the prefactors in the dimensionless relationships. The motions are consistent with earlier results obtained from much larger cones. Translation velocities up to 270 mm/s were observed and overall the velocities follow capillary-viscous scaling, whereas the speed of the fastest droplets is limited by inertia following their emergence at the cone tip.

  17. Separability of diagonal symmetric states: a quadratic conic optimization problem

    Directory of Open Access Journals (Sweden)

    Jordi Tura

    2018-01-01

    Full Text Available We study the separability problem in mixtures of Dicke states i.e., the separability of the so-called Diagonal Symmetric (DS states. First, we show that separability in the case of DS in $C^d\\otimes C^d$ (symmetric qudits can be reformulated as a quadratic conic optimization problem. This connection allows us to exchange concepts and ideas between quantum information and this field of mathematics. For instance, copositive matrices can be understood as indecomposable entanglement witnesses for DS states. As a consequence, we show that positivity of the partial transposition (PPT is sufficient and necessary for separability of DS states for $d \\leq 4$. Furthermore, for $d \\geq 5$, we provide analytic examples of PPT-entangled states. Second, we develop new sufficient separability conditions beyond the PPT criterion for bipartite DS states. Finally, we focus on $N$-partite DS qubits, where PPT is known to be necessary and sufficient for separability. In this case, we present a family of almost DS states that are PPT with respect to each partition but nevertheless entangled.

  18. Numerical optimization of conical flow waveriders including detailed viscous effects

    Science.gov (United States)

    Bowcutt, Kevin G.; Anderson, John D., Jr.; Capriotti, Diego

    1987-01-01

    A family of optimized hypersonic waveriders is generated and studied wherein detailed viscous effects are included within the optimization process itself. This is in contrast to previous optimized waverider work, wherein purely inviscid flow is used to obtain the waverider shapes. For the present waveriders, the undersurface is a streamsurface of an inviscid conical flowfield, the upper surface is a streamsurface of the inviscid flow over a tapered cylinder (calculated by the axisymmetric method of characteristics), and the viscous effects are treated by integral solutions of the boundary layer equations. Transition from laminar to turbulent flow is included within the viscous calculations. The optimization is carried out using a nonlinear simplex method. The resulting family of viscous hypersonic waveriders yields predicted high values of lift/drag, high enough to break the L/D barrier based on experience with other hypersonic configurations. Moreover, the numerical optimization process for the viscous waveriders results in distinctly different shapes compared to previous work with inviscid-designed waveriders. Also, the fine details of the viscous solution, such as how the shear stress is distributed over the surface, and the location of transition, are crucial to the details of the resulting waverider geometry. Finally, the moment coefficient variations and heat transfer distributions associated with the viscous optimized waveriders are studied.

  19. Optical trapping using cascade conical refraction of light.

    Science.gov (United States)

    O'Dwyer, D P; Ballantine, K E; Phelan, C F; Lunney, J G; Donegan, J F

    2012-09-10

    Cascade conical refraction occurs when a beam of light travels through two or more biaxial crystals arranged in series. The output beam can be altered by varying the relative azimuthal orientation of the two biaxial crystals. For two identical crystals, in general the output beam comprises a ring beam with a spot at its centre. The relative intensities of the spot and ring can be controlled by varying the azimuthal angle between the refracted cones formed in each crystal. We have used this beam arrangement to trap one microsphere within the central spot and a second microsphere on the ring. Using linearly polarized light, we can rotate the microsphere on the ring with respect to the central sphere. Finally, using a half wave-plate between the two crystals, we can create a unique beam profile that has two intensity peaks on the ring, and thereby trap two microspheres on diametrically opposite points on the ring and rotate them around the central sphere. Such a versatile optical trap should find application in optical trapping setups.

  20. Reactive microencapsulation of carbon allotropes in polyamide shell-core structures and their transformation in hybrid composites with tailored electrical properties

    Directory of Open Access Journals (Sweden)

    F. Oliveira

    2016-02-01

    Full Text Available Polyamide 6 microcapsules (PAMC loaded with 2–10 wt% of different carbon allotropes: carbon black, multiwalled carbon nanotubes, carbon nanofibers and graphite were synthesized via activated anionic polymerization (AAROP of ε-caprolactam in solution performed in the presence of the respective micro- or nanosized loads. The forming high-molecular weight microporous PAMC showed typical diameters of 15–35 µm, the filler particles being entrapped in the core as proven by microscopy methods. The melt processing of the loaded microcapsules produced PA6/C-filler hybrid thermoplastic composites with homogeneous distribution of one or two C-fillers even at loads of up to 10% without any functionalization. The crystalline structure of all PAMC and molded composites was studied by thermal and X-ray diffraction methods focusing on possible structure modification during the transition from PAMC to molded plates. Mechanical tests in tension and electrical conductivity measurements showed that transforming loaded PAMC into composites by melt processing could be a facile and rapid method to fabricate polyamide composites with improved mechanical performance and tailored electrical and dielectric properties.

  1. Bioinspired conical copper wire with gradient wettability for continuous and efficient fog collection.

    Science.gov (United States)

    Ju, Jie; Xiao, Kai; Yao, Xi; Bai, Hao; Jiang, Lei

    2013-11-06

    Inspired by the efficient fog collection on cactus spines, conical copper wires with gradient wettability are fabricated through gradient electrochemical corrosion and subsequent gradient chemical modification. These dual-gradient copper wires' fog-collection ability is demonstrated to be higher than that of conical copper wires with pure hydrophobic surfaces or pure hydrophilic surfaces, and the underlying mechanism is also analyzed. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Automatic fitting of conical envelopes to free-form surfaces for flank CNC machining

    OpenAIRE

    Bo P.; Bartoň M.; Pottmann H.

    2017-01-01

    We propose a new algorithm to detect patches of free-form surfaces that can be well approximated by envelopes of a rotational cone under a rigid body motion. These conical envelopes are a preferable choice from the manufacturing point of view as they are, by-definition, manufacturable by computer numerically controlled (CNC) machining using the efficient flank (peripheral) method with standard conical tools. Our geometric approach exploits multi-valued vector fields that consist of vectors in...

  3. Derivation of Conditions for the Normal Gain Behavior of Conical Horns

    Directory of Open Access Journals (Sweden)

    Chin Yeng Tan

    2007-01-01

    Full Text Available Monotonically increasing gain-versus-frequency pattern is in general expected to be a characteristic of aperture antennas that include the smooth-wall conical horn. While optimum gain conical horns do naturally exhibit this behavior, nonoptimum horns need to meet certain criterion: a minimum axial length for given aperture diameter, or, alternatively, a maximum aperture diameter for the given axial length. In this paper, approximate expressions are derived to determine these parameters.

  4. Performance of conical abutment (Morse Taper) connection implants: a systematic review.

    Science.gov (United States)

    Schmitt, Christian M; Nogueira-Filho, Getulio; Tenenbaum, Howard C; Lai, Jim Yuan; Brito, Carlos; Döring, Hendrik; Nonhoff, Jörg

    2014-02-01

    In this systematic review, we aimed to compare conical versus nonconical implant-abutment connection systems in terms of their in vitro and in vivo performances. An electronic search was performed using PubMed, Embase, and Medline databases with the logical operators: "dental implant" AND "dental abutment" AND ("conical" OR "taper" OR "cone"). Names of the most common conical implant-abutment connection systems were used as additional key words to detect further data. The search was limited to articles published up to November 2012. Recent publications were also searched manually in order to find any relevant studies that might have been missed using the search criteria noted above. Fifty-two studies met the inclusion criteria and were included in this systematic review. As the data and methods, as well as types of implants used was so heterogeneous, this mitigated against the performance of meta-analysis. In vitro studies indicated that conical and nonconical abutments showed sufficient resistance to maximal bending forces and fatigue loading. However, conical abutments showed superiority in terms of seal performance, microgap formation, torque maintenance, and abutment stability. In vivo studies (human and animal) indicated that conical and nonconical systems are comparable in terms of implant success and survival rates with less marginal bone loss around conical connection implants in most cases. This review indicates that implant systems using a conical implant-abutment connection, provides better results in terms of abutment fit, stability, and seal performance. These design features could lead to improvements over time versus nonconical connection systems. © 2013 Wiley Periodicals, Inc.

  5. Surface-enhanced Raman spectroscopy based on conical holed enhancing substrates

    International Nuclear Information System (INIS)

    Chen, Yao; Chen, Zeng-Ping; Zuo, Qi; Shi, Cai-Xia; Yu, Ru-Qin

    2015-01-01

    In this contribution, surface-enhanced Raman spectroscopy (SERS) based on conical holed glass substrates deposited with silver colloids was reported for the first time. It combines the advantages of both dry SERS assays based on plane films deposited with silver colloids and wet SERS assays utilizing cuvettes or capillary tubes. Compared with plane glass substrates deposited with silver colloids, the conical holed glass substrates deposited with silver colloids exhibited five-to ten-folds of increase in the rate of signal enhancement, due to the internal multiple reflections of both the excitation laser beam and the Raman scattering photons within conical holes. The application of conical holed glass substrates could also yield significantly stronger and more reproducible SERS signals than SERS assays utilizing capillary tubes to sample the mixture of silver colloids and the solution of the analyte of interest. The conical holed glass substrates in combination with the multiplicative effects model for surface-enhanced Raman spectroscopy (MEM SERS ) achieved quite sensitive and precise quantification of 6-mercaptopurine in complex plasma samples with an average relative prediction error of about 4% and a limit of detection of about 0.02 μM using a portable i-Raman 785H spectrometer. It is reasonable to expect that SERS technique based on conical holed enhancing substrates in combination with MEM SERS model can be developed and extended to other application areas such as drug detection, environmental monitoring, and clinic analysis, etc. - Highlights: • A novel conical holed SERS enhancing substrate was designed and manufactured. • The optimal conical holed glass substrates can produce stronger SERS signal. • The novel substrates can overcome the shortcomings of both dry and wet methods. • The novel substrates coupled with MEM SERS can realize quantitative SERS assays

  6. The influence of initial pressure on the characteristics of conical bubble sonoluminescence

    Energy Technology Data Exchange (ETDEWEB)

    He, Shoujie, E-mail: heshouj@hbu.edu.cn [Hebei Key Laboratory of Optic-electronic Information and Materials, College of Physics Science and Technology, Hebei University, Baoding 071002 (China); Ha, Jing [Institute of Science, Hebei Agriculture University, Baoding 071001 (China); Duan, Pingguang [Hebei Key Laboratory of Optic-electronic Information and Materials, College of Physics Science and Technology, Hebei University, Baoding 071002 (China)

    2015-12-18

    Based on a conical bubble U-tube, conical bubble sonoluminescence was investigated by using pure water as the working medium. Intense cavitation luminescence can be obtained. With the decrease in initial pressure inside the bubble, the intensity and duration of light emission increased. The spectrum is mainly composed of the spectral bands of H{sub 2}O at the initial pressure of 1000 Pa. With the decrease in initial pressure, a broad continuum background spectrum that is well fitted by blackbody radiation can be detected, on which several spectral bands emitted by water molecules are superimposed. A higher temperature inside the bubble can be obtained with the decrease in initial pressure. Moreover, the intensity of the continuum background spectrum becomes more dominant compared with that of H{sub 2}O emission bands. Finally, we conclude that blackbody radiation and molecular emission contribute to luminescence of conical bubble cavitation. Moreover, the initial pressure inside the conical bubble significantly affects the emission mechanism of conical bubble sonoluminescence. - Highlights: • The spectra and light pulses of CBL are investigated in pure water. • The continuum background spectrum becomes more dominant with decrease of initial pressure. • The mechanism of CBL depends on the initial pressure of bubble. • Blackbody radiation and molecular emission contribute to luminescence of conical bubble cavitation.

  7. Coal option. [Shell Co

    Energy Technology Data Exchange (ETDEWEB)

    1978-01-01

    This paper notes the necessity of developing an international coal trade on a very large scale. The role of Shell in the coal industry is examined; the regions in which Shell companies are most active are Australia, Southern Africa, Indonesia; Europe and North America. Research is being carried out on marketing and transportation, especially via slurry pipelines; coal-oil emulsions; briquets; fluidized-bed combustion; recovery of coal from potential waste material; upgrading of low-rank coals; unconventional forms of mining; coal conversion (the Shell/Koppers high-pressure coal gasification process). Techniques for cleaning flue gas (the Shell Flue Gas Desulfurization process) are being examined.

  8. Shell-like structures

    CERN Document Server

    Altenbach, Holm

    2011-01-01

    In this volume, scientists and researchers from industry discuss the new trends in simulation and computing shell-like structures. The focus is put on the following problems: new theories (based on two-dimensional field equations but describing non-classical effects), new constitutive equations (for materials like sandwiches, foams, etc. and which can be combined with the two-dimensional shell equations), complex structures (folded, branching and/or self intersecting shell structures, etc.) and shell-like structures on different scales (for example: nano-tubes) or very thin structures (similar

  9. Composition

    DEFF Research Database (Denmark)

    Bergstrøm-Nielsen, Carl

    2014-01-01

    Cue Rondo is an open composition to be realised by improvising musicians. See more about my composition practise in the entry "Composition - General Introduction". Caution: streaming the sound/video files will in some cases only provide a few minutes' sample, or the visuals will not appear at all....... Please DOWNLOAD them to see/hear them in full length! This work is licensed under a Creative Commons "by-nc" License. You may for non-commercial purposes use and distribute it, performance instructions as well as specially designated recordings, as long as the author is mentioned. Please see http...

  10. Modification of polyimide wetting properties by laser ablated conical microstructures

    International Nuclear Information System (INIS)

    Least, Brandon T.; Willis, David A.

    2013-01-01

    Laser texturing of Kapton ® HN polyimide was performed by low-fluence ablation using a pulsed, frequency tripled (349 nm) Nd:YLF laser. The laser was scanned in two dimensions in order to generate texture over a large area. The laser overlap percentage and fluence were varied and the resulting texture was studied. The texture features were inspected by electron microscopy and energy dispersive X-Ray spectroscopy (EDS), while the static contact angle of de-ionized water was measured by a contact angle goniometer. Rounded bump features were formed at all fluences, which decreased in areal density with fluence and number of laser pulses. Conical microstructures or “cones” were also formed at most fluences. Cones were larger than the bumps and thus had lower areal density, which increased as a function of the number of laser pulses. The polyimide was hydrophilic before texturing, with a contact angle of approximately 76°. For most of the experimental conditions the contact angle increased as a result of texturing, with the contact angle exceeding 90° for some textured surfaces, and reaching values as high as 118°. In general, the surfaces with significant increases in contact angle had high density of texture features, either bumps or cones. The surfaces that experienced a decrease in contact angle generally had low density of texture features. The increase in contact angle from a wetting (θ 90°) cannot be explained by texturing alone. EDS measurements indicate that textured regions had higher carbon content than the untextured regions due to depletion of oxygen species. The increase in carbon content relative to the oxygen content increased the native contact angle of the surface, causing the transition from hydrophilic to hydrophobic behavior. The contact angle of a textured surface increased as the relative spacing of features (diameter to spacing) decreased.

  11. Capillary micromechanics for core-shell particles

    NARCIS (Netherlands)

    Kong, T.; Wang, Liqiu; Wyss, H.M.; Shum, H.C.

    2014-01-01

    In this work, we have developed a facile, economical microfluidic approach as well as a simple model description to measure and predict the mechanical properties of composite core–shell microparticles made from materials with dramatically different elastic properties. By forcing the particles

  12. Ti2Al(C, N) Solid Solution Reinforcing TiAl-Based Composites: Evolution of a Core-Shell Structure, Interfaces, and Mechanical Properties.

    Science.gov (United States)

    Song, Xiaojie; Cui, Hongzhi; Han, Ye; Ding, Lei; Song, Qiang

    2018-05-16

    In this work, Ti 2 Al(C, N) solid solution with lamellar structure-enhanced TiAl matrix composites was synthesized by vacuum arc melting, using bulk g-C 3 N 4 , Ti, and Al powders as raw materials. The phases, microstructures, interfaces, and mechanical properties were investigated. MAX phase of Ti 2 Al(C, N) solid solution with lamellar structure was formed. During the melting process, first, C 3 N 4 reacted with Ti to form Ti(C, N) by Ti + C 3 N 4 → Ti(C, N). Then Ti 2 Al(C, N) was formed by a peritectic reaction of TiAl(l) + Ti(C, N)(s) → Ti 2 Al(C, N). C 3 N 4 is the single reactant that provides C and N simultaneously to final product of Ti 2 Al(C, N). The interfaces of TiAl//Ti 2 Al(C, N) and Ti 2 Al(C, N)//Ti(C, N) display perfect orientation relationships with low misfit values. The microhardness, compressive strength, and strain of best-performing TiAl-10 mol % Ti 2 Al(C, N) composite were improved by 45%, 55.7%, and 50% compared with the TiAl alloy, respectively. Uniformly distributed Ti 2 Al(C, N) and unreacted Ti(C, N) particles contributed to the grain refinement and reinforcement of the TiAl matrix. Laminated tearing, particle pull-out, and the crack-arresting of Ti 2 Al(C, N) are crucial for the improvement in compressive strength and plasticity of the composites.

  13. Conical diffraction as a versatile building block to implement new imaging modalities for superresolution in fluorescence microscopy

    Science.gov (United States)

    Fallet, Clément; Caron, Julien; Oddos, Stephane; Tinevez, Jean-Yves; Moisan, Lionel; Sirat, Gabriel Y.; Braitbart, Philippe O.; Shorte, Spencer L.

    2014-08-01

    We present a new technology for super-resolution fluorescence imaging, based on conical diffraction. Conical diffraction is a linear, singular phenomenon taking place when a polarized beam is diffracted through a biaxial crystal. The illumination patterns generated by conical diffraction are more compact than the classical Gaussian beam; we use them to generate a super-resolution imaging modality. Conical Diffraction Microscopy (CODIM) resolution enhancement can be achieved with any type of objective on any kind of sample preparation and standard fluorophores. Conical diffraction can be used in multiple fashion to create new and disruptive technologies for super-resolution microscopy. This paper will focus on the first one that has been implemented and give a glimpse at what the future of microscopy using conical diffraction could be.

  14. Randomized intubation with polyurethane or conical cuffs to prevent pneumonia in ventilated patients.

    Science.gov (United States)

    Philippart, François; Gaudry, Stéphane; Quinquis, Laurent; Lau, Nicolas; Ouanes, Islem; Touati, Samia; Nguyen, Jean Claude; Branger, Catherine; Faibis, Frédéric; Mastouri, Maha; Forceville, Xavier; Abroug, Fekri; Ricard, Jean Damien; Grabar, Sophie; Misset, Benoît

    2015-03-15

    The occurrence of ventilator-associated pneumonia (VAP) is linked to the aspiration of contaminated pharyngeal secretions around the endotracheal tube. Tubes with cuffs made of polyurethane rather than polyvinyl chloride or with a conical rather than a cylindrical shape increase tracheal sealing. To test whether using polyurethane and/or conical cuffs reduces tracheal colonization and VAP in patients with acute respiratory failure. We conducted a multicenter, prospective, open-label, randomized study in four parallel groups in four intensive care units between 2010 and 2012. A cohort of 621 patients with expected ventilation longer than 2 days was included at intubation with a cuff composed of cylindrical polyvinyl chloride (n = 148), cylindrical polyurethane (n = 143), conical polyvinyl chloride (n = 150), or conical polyurethane (n = 162). We used Kaplan-Meier estimates and log-rank tests to compare times to events. After excluding 17 patients who secondarily refused participation or had met an exclusion criterion, 604 were included in the intention-to-treat analysis. Cumulative tracheal colonization greater than 10(3) cfu/ml at Day 2 was as follows (median [interquartile range]): cylindrical polyvinyl chloride, 0.66 (0.58-0.74); cylindrical polyurethane, 0.61 (0.53-0.70); conical polyvinyl chloride, 0.67 (0.60-0.76); and conical polyurethane, 0.62 (0.55-0.70) (P = 0.55). VAP developed in 77 patients (14.4%), and postextubational stridor developed in 28 patients (6.4%) (P = 0.20 and 0.28 between groups, respectively). Among patients requiring mechanical ventilation, polyurethane and/or conically shaped cuffs were not superior to conventional cuffs in preventing tracheal colonization and VAP. Clinical trial registered with clinicaltrials.gov (NCT01114022).

  15. Shell coal gasification process

    Energy Technology Data Exchange (ETDEWEB)

    Hennekes, B. [Shell Global Solutions (US) Inc. (United States). Technology Marketing

    2002-07-01

    The presentation, on which 17 slides/overheads are included in the papers, explained the principles of the Shell coal gasification process and the methods incorporated for control of sulfur dioxide, nitrogen oxides, particulates and mercury. The economics of the process were discussed. The differences between gasification and burning, and the differences between the Shell process and other processes were discussed.

  16. Wrinkling of Pressurized Elastic Shells

    KAUST Repository

    Vella, Dominic; Ajdari, Amin; Vaziri, Ashkan; Boudaoud, Arezki

    2011-01-01

    We study the formation of localized structures formed by the point loading of an internally pressurized elastic shell. While unpressurized shells (such as a ping-pong ball) buckle into polygonal structures, we show that pressurized shells

  17. "Conical Hut": A Basic Form of House Types in Timor Island

    Science.gov (United States)

    Chen, Y. R.; Lim, Y. L.; Wang, M. H.; Chen, C. Y.

    2015-08-01

    Timor Island situates in the southeast end of Southeast Asia. The island accommodates many ethnic groups, which produce many diverse house types. As visiting East Timor in 2012 and Timor Island in 2014, we found the "Pair- House Type" widely spread over Timor Island. Uma Lulik (holy house), accommodating the ancestry soul, fireplace and elder's bed, and Uma Tidor (house for sleep), containing living, sleeping and working space, compose the pair-house. The research team visited 14 ethnic groups and their houses, some of which were measured and drawn into 3D models as back to Taiwan. Uma Tidors of each ethnic group are quite similar with rectangular volume and hip roof, however, one of the fourteen ethnic groups can build cylinder houses for Uma Tidor. Uma Luliks of different ethnic groups are diversified and special. One group of the Uma Luliks shows a rectangular or square volume sheltered by a hip roof. The other group of Uma Luliks presents a non-specific volume under a conical roof, that we called the "conical hut". Seven ethnic groups, Atoni, Weimua, Makassae, Mambai, Bunaq, Kemak and Bekais, have built "conical huts" for the use of Uma Lulik. People of the seven ethnic groups can construct a reasonable structural system to support the conical roof, and take good advantage of the space under the conical roof to meet their sacred needs and everyday life. "Conical Hut" may be regarded as the basic form of the house types adopted by the seven ethnic groups. It contains the basic spatial limits and the formal properties that the construction systems have to follow. Based on the concise rules of the basic form, people of each ethnic group use their talents, skills and building materials to generate variations of "conical hut", which are different in house scale, spatial layout, construction system and form. The "conical huts" contain the consistency that all the huts come from the basic form, meanwhile, they also present the diversification that each conical hut has

  18. "Conical Hut": A Basic Form of House Types in Timor Island

    Directory of Open Access Journals (Sweden)

    Y. R. Chen

    2015-08-01

    Full Text Available Timor Island situates in the southeast end of Southeast Asia. The island accommodates many ethnic groups, which produce many diverse house types. As visiting East Timor in 2012 and Timor Island in 2014, we found the “Pair- House Type” widely spread over Timor Island. Uma Lulik (holy house, accommodating the ancestry soul, fireplace and elder’s bed, and Uma Tidor (house for sleep, containing living, sleeping and working space, compose the pair-house. The research team visited 14 ethnic groups and their houses, some of which were measured and drawn into 3D models as back to Taiwan. Uma Tidors of each ethnic group are quite similar with rectangular volume and hip roof, however, one of the fourteen ethnic groups can build cylinder houses for Uma Tidor. Uma Luliks of different ethnic groups are diversified and special. One group of the Uma Luliks shows a rectangular or square volume sheltered by a hip roof. The other group of Uma Luliks presents a non-specific volume under a conical roof, that we called the “conical hut”. Seven ethnic groups, Atoni, Weimua, Makassae, Mambai, Bunaq, Kemak and Bekais, have built “conical huts” for the use of Uma Lulik. People of the seven ethnic groups can construct a reasonable structural system to support the conical roof, and take good advantage of the space under the conical roof to meet their sacred needs and everyday life. “Conical Hut” may be regarded as the basic form of the house types adopted by the seven ethnic groups. It contains the basic spatial limits and the formal properties that the construction systems have to follow. Based on the concise rules of the basic form, people of each ethnic group use their talents, skills and building materials to generate variations of “conical hut”, which are different in house scale, spatial layout, construction system and form. The “conical huts” contain the consistency that all the huts come from the basic form, meanwhile, they also present

  19. Conical Perspective Image of an Architectural Object Close to Human Perception

    Science.gov (United States)

    Dzwierzynska, Jolanta

    2017-10-01

    The aim of the study is to develop a method of computer aided constructing conical perspective of an architectural object, which is close to human perception. The conical perspective considered in the paper is a central projection onto a projection surface being a conical rotary surface or a fragment of it. Whereas, the centre of projection is a stationary point or a point moving on a circular path. The graphical mapping results of the perspective representation is realized directly on an unrolled flat projection surface. The projective relation between a range of points on a line and the perspective image of the same range of points received on a cylindrical projection surface permitted to derive formulas for drawing perspective. Next, the analytical algorithms for drawing perspective image of a straight line passing through any two points were formulated. It enabled drawing a perspective wireframe image of a given 3D object. The use of the moving view point as well as the application of the changeable base elements of perspective as the variables in the algorithms enable drawing conical perspective from different viewing positions. Due to this fact, the perspective drawing method is universal. The algorithms are formulated and tested in Mathcad Professional software, but can be implemented in AutoCAD and majority of computer graphical packages, which makes drawing a perspective image more efficient and easier. The presented conical perspective representation, and the convenient method of its mapping directly on the flat unrolled surface can find application for numerous advertisement and art presentations.

  20. The plastic instability of clamped-clamped conical thin-walled pipe reducers

    International Nuclear Information System (INIS)

    Awad, Ibrahim; Saleh, Ch.A.R.; Ragab, A.R.

    2016-01-01

    The analytical study for plastic deformation of clamped–clamped conical reducer pipe under internal pressure does not deduce a closed form expression for the pressure at plastic instability. The presented study employs finite element analysis (FEA) to estimate the internal pressure at instability for conical reducers made of different materials and having different dimensional configurations. Forty dimensional configurations, classified as medium type, and five types of materials have been included in the analysis using ABAQUS package. A correlation expression is derived by nonlinear regression to predict the instability pressure. The proposed expression is verified for other dimensional configurations out of the above used forty models and for other materials. Experiments have been conducted by pressurizing conical clamped-clamped reducers until bursting in order to verify the finite element models. Comparison of instability pressures, strains and deflections at specific points along the conical surface shows satisfactory agreement between analysis and experiments. - Highlights: • This study offers a parametric study of the plastic instability pressure of clamped-clamped conical reducers. • A closed form analytical expression for the instability pressure is derived by using nonlinear regression. • The finite element analysis is validated by conducting bursting tests.

  1. Waste truck-tyre processing by flash pyrolysis in a conical spouted bed reactor

    International Nuclear Information System (INIS)

    Lopez, G.; Alvarez, J.; Amutio, M.; Mkhize, N.M.; Danon, B.; Gryp, P.; Görgens, J.F. van der; Bilbao, J.; Olazar, M.

    2017-01-01

    Highlights: • Flash pyrolysis improves TPO and limonene yields vs. slow pyrolysis. • The most suitable temperature for TPO and limonene maximization was 475 °C. • Operating at 575 °C gas yields and char quality was enhanced. • Temperature showed a limited effect on sulphur distribution among products. - Abstract: The flash pyrolysis of waste truck-tyres was studied in a conical spouted bed reactor (CSBR) operating in continuous regime. The influence of temperature on product distribution was analysed in the 425–575 °C range. A detailed characterization of the pyrolysis products was carried out in order to assess their most feasible application. Moreover, special attention was paid to the sulphur distribution among the products. The analysis of gaseous products was carried out using a micro-GC and the tyre pyrolysis oil (TPO) by means of GC-FID using peak areas for quantification, with GC/MS for identification and elemental analysis. Finally, the char was subjected to elemental analysis and surface characterization. According to the results, 475 °C is an appropriate temperature for the pyrolysis of waste tyres, given that it ensures total devolatilisation of tyre rubber and a high TPO yield, 58.2 wt.%. Moreover, the quality of the oil is optimum at this temperature, especially in terms of high concentrations of valuable chemicals, such as limonene. An increase in temperature to 575 °C reduced the TPO yield to 53.9 wt.% and substantially changed its chemical composition by increasing the aromatic content. However, the quality of the recovered char was improved at high temperatures.

  2. Optimised photocatalytic hydrogen production using core–shell AuPd promoters with controlled shell thickness

    DEFF Research Database (Denmark)

    Jones, Wilm; Su, Ren; Wells, Peter

    2014-01-01

    of these materials towards the reforming of alcohols for hydrogen production. The core–shell structured Au–Pd bimetallic nanoparticle supported on TiO2 has being of interest as it exhibited extremely high quantum efficiencies for hydrogen production. However, the effect of shell composition and thickness...... of the nanoparticles by a combination of X-ray absorption fine structure and X-ray photoelectron spectroscopy. Photocatalytic ethanol reforming showed that the core–shell structured Au–Pd promoters supported on TiO2 exhibit enhanced activity compared to that of monometallic Au and Pd as promoters, whilst the core......–shell Au–Pd promoters containing one ML equivalent Pd provide the optimum reactivity....

  3. Design and synthesis of core-shell Fe3O4@PTMT composite magnetic microspheres for adsorption of heavy metals from high salinity wastewater.

    Science.gov (United States)

    Huang, Xin; Yang, Jinyue; Wang, Jingkang; Bi, Jingtao; Xie, Chuang; Hao, Hongxun

    2018-05-10

    In this study, a novel magnetic nanoparticles (MNP) modified by an organodisulfide polymer (PTMT) was designed for adsorption of heavy metals (Hg(II), Pb(II) and Cd(II)) from simulated coal chemical high salinity wastewater. The MNP-PTMT nano-composite was synthesize and characterized by SEM, TEM, FTIR, BET, VSM, TGA and XRD. The results indicate that the wanted MNP-PTMT magnetic nanoparticles were successfully obtained by modification. Adsorption experiments were systematically carried out to evaluate the performance of the obtained nanoparticles and to build up the adsorption models. The results demonstrate that the adsorption kinetic and isotherms thermodynamic followed the pseudo-second-order model and the Freundlich equation, respectively. In the presence of the inorganic salt in high salinity wastewater, the adsorption efficiency of MNP-PTMT for heavy metals was still excellent. The magnetic adsorbent could be recovered from aqueous solution by an external magnetic field in 20s and the subsequent regeneration of Hg(II)/Pb(II) loaded MNP-PTMT can be efficiently achieved by using EDTA-2Na solution as desorbent. The novel MNP-PTMT nanoparticles could be used reproductively for five times without apparent decrease in sorption capacity. Copyright © 2018 Elsevier Ltd. All rights reserved.

  4. Molluscan shell colour.

    Science.gov (United States)

    Williams, Suzanne T

    2017-05-01

    The phylum Mollusca is highly speciose, and is the largest phylum in the marine realm. The great majority of molluscs are shelled, including nearly all bivalves, most gastropods and some cephalopods. The fabulous and diverse colours and patterns of molluscan shells are widely recognised and have been appreciated for hundreds of years by collectors and scientists alike. They serve taxonomists as characters that can be used to recognise and distinguish species, however their function for the animal is sometimes less clear and has been the focus of many ecological and evolutionary studies. Despite these studies, almost nothing is known about the evolution of colour in molluscan shells. This review summarises for the first time major findings of disparate studies relevant to the evolution of shell colour in Mollusca and discusses the importance of colour, including the effects of visual and non-visual selection, diet and abiotic factors. I also summarise the evidence for the heritability of shell colour in some taxa and recent efforts to understand the molecular mechanisms underpinning synthesis of shell colours. I describe some of the main shell pigments found in Mollusca (carotenoids, melanin and tetrapyrroles, including porphyrins and bile pigments), and their durability in the fossil record. Finally I suggest that pigments appear to be distributed in a phylogenetically relevant manner and that the synthesis of colour is likely to be energetically costly. © 2016 Cambridge Philosophical Society.

  5. Nuclear shell theory

    CERN Document Server

    de-Shalit, Amos; Massey, H S W

    1963-01-01

    Nuclear Shell Theory is a comprehensive textbook dealing with modern methods of the nuclear shell model. This book deals with the mathematical theory of a system of Fermions in a central field. It is divided into three parts. Part I discusses the single particle shell model. The second part focuses on the tensor algebra, two-particle systems. The last part covers three or more particle systems. Chapters on wave functions in a central field, tensor fields, and the m-Scheme are also presented. Physicists, graduate students, and teachers of nuclear physics will find the book invaluable.

  6. CALCULATION OF ROCKET NOSE FAIRING SHELLS AERODYNAMIC CHARACTERISTICS

    Directory of Open Access Journals (Sweden)

    Vladimir T. Kalugin

    2018-01-01

    Full Text Available The aerodynamic characteristics of the detachable elements of transport systems are introduced, they allow to calculate the trajectories of these elements after their separation and determine the size of elements impact areas. Special consideration is given to head fairing shells, containing cylindrical, conical and spherical sections. Head fairing shells have high lift-to-drag ratio and the widest impact areas. Aerodynamics of bodies of such configurations has been insufficiently studied. The paper presents the numerical results of modeling the flow around a typical head fairing shell in free flight. Open source OpenFOAM package is used for numerical simulation. The aerodynamic characteristics at trans- and supersonic velocities are obtained, flow pattern transformation with the change of the angle of attack and Mach number is analyzed. The possibility of OpenFOAM package for aerodynamic calculations of thin shells is shown. The analysis of the obtained results demonstrate that there are many complex shock waves interacting with each other at flow supersonic speeds, at subsonic speeds vast regions of flow separations are observed. The authors identify intervals of angles of attack, where different types of flow structures are realized, both for trans- and supersonic flow speeds. The flow pattern change affects the aerodynamic characteristics, the aerodynamic coefficients significantly change with increase of the angle of attack. There are two trim angles of attack at all examined flow velocities. The results obtained can be used to develop a passive stabilization system for fairing shell that will balance the body at the angle of attack with minimum lift-to-drag ratio and will reduce random deviations.

  7. Modeling of microencapsulated polymer shell solidification

    International Nuclear Information System (INIS)

    Boone, T.; Cheung, L.; Nelson, D.; Soane, D.; Wilemski, G.; Cook, R.

    1995-01-01

    A finite element transport model has been developed and implemented to complement experimental efforts to improve the quality of ICF target shells produced via controlled-mass microencapsulation. The model provides an efficient means to explore the effect of processing variables on the dynamics of shell dimensions, concentricity, and phase behavior. Comparisons with experiments showed that the model successfully predicts the evolution of wall thinning and core/wall density differences. The model was used to efficiently explore and identify initial wall compositions and processing temperatures which resulted in concentricity improvements from 65 to 99%. The evolution of trace amounts of water entering into the shell wall was also tracked in the simulations. Comparisons with phase envelope estimations from modified UNIFAP calculations suggest that the water content trajectory approaches the two-phase region where vacuole formation via microphase separation may occur

  8. Shell Buckling Knockdown Factors

    Data.gov (United States)

    National Aeronautics and Space Administration — The Shell Buckling Knockdown Factor (SBKF) Project, NASA Engineering and Safety Center (NESC) Assessment #: 07-010-E, was established in March of 2007 by the NESC in...

  9. Separation and extension of cover inequalities for second-order conic knapsack constraints with GUBs

    DEFF Research Database (Denmark)

    Atamtürk, Alper; Muller, Laurent Flindt; Pisinger, David

    We consider the second-order conic equivalent of the classic knapsack polytope where the variables are subject to generalized upper bound constraints. We describe and compare a number of separation and extension algorithms which make use of the extra structure implied by the generalized upper bound...... constraints in order to strengthen the second-order conic equivalent of the classic cover cuts. We show that determining whether a cover can be extended with a variable is NP-hard. Computational experiments are performed comparing the proposed separation and extension algorithms. These experiments show...

  10. Numerical Calculation for Whirling Motion of a Centrifugal Blood Pump with Conical Spiral Groove Bearings

    Science.gov (United States)

    Shigemaru, Daichi; Tsukamoto, Hiroshi

    2010-06-01

    Whirling motion of a pump impeller was calculated for the centrifugal blood pump with Conical Spiral Groove Bearings to get a criterion for the instability of impeller whirling motion. The motion of the centrifugal blood pump impeller was calculated based on a spring damping model, and unsteady flow in the pump was computed using the commercial CFD package ANSYS CFX. Also the whirling motion of rotating impeller was measured using two displacement sensors fixed to the blood pump casing. The numerical calculations were done for the blood pump impeller with conical spiral groove bearings, and impeller whirling motion was evaluated.

  11. Spectral and spatial characteristics of third-harmonic generation in conical light beams

    International Nuclear Information System (INIS)

    Peet, V.E.; Shchemeljov, S.V.

    2003-01-01

    Generation of resonance-enhanced third harmonic in Bessel and other conical beams is analyzed from a simple picture, where the fundamental light field is decomposed into elementary configurations of crossed plain-wave sub-beams. We show that the overall harmonic output can be derived as a superposition of all partial harmonic components driven by elementary configurations of the fundamental field. Good agreement with experimental observations has been obtained in simulation of spectral and spatial characteristics of the generated third harmonic. Some peculiarities of harmonic generation in conical light fields are discussed

  12. Influence of Test Section Geometry on the Blast Environment in an Explosively Driven Conical Shock Tube

    Science.gov (United States)

    2018-03-30

    ARL-TR-8335•MAR 2018 US Army Research Laboratory Influence of Test Section Geometry on theBlast Environment in an Explosively DrivenConical Shock...ARL-TR-8335•MAR 2018 US Army Research Laboratory Influence of Test Section Geometry on theBlast Environment in an Explosively DrivenConical Shock...TITLE AND SUBTITLE    5a. CONTRACT NUMBER  5b. GRANT NUMBER  5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S)    5d.  PROJECT  NUMBER  5e. TASK NUMBER  5f

  13. Practical conic sections the geometric properties of ellipses, parabolas and hyperbolas

    CERN Document Server

    Downs, J W

    2010-01-01

    Illustrated with interesting examples from everyday life, this text shows how to create ellipses, parabolas, and hyperbolas and presents fascinating historical background on their ancient origins. The text starts with a discussion of techniques for generating the conic curves, showing how to create accurate depictions of large or small conic curves and describing their reflective properties, from light in telescopes to sound in microphones and amplifiers. It further defines the role of curves in the construction of auditoriums, antennas, lamps, and numerous other design applications. Only a ba

  14. Power of the Poincaré group: elucidating the hidden symmetries in focal conic domains.

    Science.gov (United States)

    Alexander, Gareth P; Chen, Bryan Gin-Ge; Matsumoto, Elisabetta A; Kamien, Randall D

    2010-06-25

    Focal conic domains are typically the "smoking gun" by which smectic liquid crystalline phases are identified. The geometry of the equally spaced smectic layers is highly generic but, at the same time, difficult to work with. In this Letter we develop an approach to the study of focal sets in smectics which exploits a hidden Poincaré symmetry revealed only by viewing the smectic layers as projections from one-higher dimension. We use this perspective to shed light upon several classic focal conic textures, including the concentric cyclides of Dupin, polygonal textures, and tilt-grain boundaries.

  15. Power of the Poincare Group: Elucidating the Hidden Symmetries in Focal Conic Domains

    International Nuclear Information System (INIS)

    Alexander, Gareth P.; Chen, Bryan Gin-ge; Matsumoto, Elisabetta A.; Kamien, Randall D.

    2010-01-01

    Focal conic domains are typically the 'smoking gun' by which smectic liquid crystalline phases are identified. The geometry of the equally spaced smectic layers is highly generic but, at the same time, difficult to work with. In this Letter we develop an approach to the study of focal sets in smectics which exploits a hidden Poincare symmetry revealed only by viewing the smectic layers as projections from one-higher dimension. We use this perspective to shed light upon several classic focal conic textures, including the concentric cyclides of Dupin, polygonal textures, and tilt-grain boundaries.

  16. A new approach to evaluate the response functions for conical and cylindrical collimators

    International Nuclear Information System (INIS)

    Gigante, G.E.

    1989-01-01

    A new approach to the evaluation of the conical collimator response function is shown. The basic collimator formulae are reviewed. The collimator response function has been found in a very easy way. An approximate solution has been introduced. Studying the response of a measuring system, the use of this approximation strongly reduces the complexity of the relations to be used; therefore it would provide a useful starting point for a Monte Carlo calculation. The errors introduced are less than 10%. Approximate relations that allow the evaluation of the response of conical and cylindrical collimators to plane and line sources are also given. (orig.)

  17. Shells and Patterns

    Science.gov (United States)

    Sutley, Jane

    2009-01-01

    "Shells and Patterns" was a project the author felt would easily put smiles on the faces of her fifth-graders, and teach them about unity and the use of watercolor pencils as well. It was thrilling to see the excitement in her students as they made their line drawings of shells come to life. For the most part, they quickly got the hang of…

  18. Off-shell CHY amplitudes

    Energy Technology Data Exchange (ETDEWEB)

    Lam, C.S., E-mail: Lam@physics.mcgill.ca [Department of Physics, McGill University, Montreal, Q.C., H3A 2T8 (Canada); Department of Physics and Astronomy, University of British Columbia, Vancouver, BC, V6T 1Z1 (Canada); Yao, York-Peng, E-mail: yyao@umich.edu [Department of Physics, The University of Michigan Ann Arbor, MI 48109 (United States)

    2016-06-15

    The Cachazo–He–Yuan (CHY) formula for on-shell scattering amplitudes is extended off-shell. The off-shell amplitudes (amputated Green's functions) are Möbius invariant, and have the same momentum poles as the on-shell amplitudes. The working principles which drive the modifications to the scattering equations are mainly Möbius covariance and energy momentum conservation in off-shell kinematics. The same technique is also used to obtain off-shell massive scalars. A simple off-shell extension of the CHY gauge formula which is Möbius invariant is proposed, but its true nature awaits further study.

  19. Analysis of thermal-plastic response of shells of revolution by numerical integration

    International Nuclear Information System (INIS)

    Leonard, J.W.

    1975-01-01

    An economic technique for the numerical analysis of the elasto-plastic behaviour of shells of revolution would be of considerable value in the nuclear reactor industry. A numerical method based on the numerical integration of the governing shell equations has been shown, for elastic cases, to be more efficient than the finite element method when applied to shells of revolution. In the numerical integration method, the governing differential equations of motion are converted into a set of initial-value problems. Each initial-value problem is integrated numerically between meridional boundary points and recombined so as to satisfy boundary conditions. For large-deflection elasto-plastic behaviour, the equations are nonlinear and, hence, are recombined in an iterative manner using the Newton-Raphson procedure. Suppression techniques are incorporated in order to eliminate extraneous solutions within the numerical integration procedure. The Reissner-Meissner shell theory for shells of revolution is adopted to account for large deflection and higher-order rotation effects. The computer modelling of the equations is quite general in that specific shell segment geometries, e.g. cylindrical, spherical, toroidal, conical segments, and any combinations thereof can be handled easily. (Auth.)

  20. Effective spectral densities for system-environment dynamics at conical intersections: S{sub 2}-S{sub 1} conical intersection in pyrazine

    Energy Technology Data Exchange (ETDEWEB)

    Martinazzo, Rocco [Department of Physical Chemistry and Electrochemistry, University of Milan, Via Golgi 19, 20122 Milan (Italy); Hughes, Keith H. [School of Chemistry, Bangor University, Bangor, Gwynedd LL57 2UW (United Kingdom); Martelli, Fausto [Department of Physical Chemistry and Electrochemistry, University of Milan, Via Golgi 19, 20122 Milan (Italy); Departement de Chimie, Ecole Normale Superieure, 24 rue Lhomond, F-75231 Paris cedex 05 (France); Burghardt, Irene, E-mail: irene.burghardt@ens.fr [Departement de Chimie, Ecole Normale Superieure, 24 rue Lhomond, F-75231 Paris cedex 05 (France)

    2010-11-25

    Graphical abstract: The effect of high-dimensional environments on conical intersections can be described by hierarchies of approximate spectral densities, which translate to truncated effective-mode chains in the time domain. Abstract: A recently developed effective-mode representation is employed to characterize the influence of a multi-dimensional environment on the S{sub 2}-S{sub 1} conical intersection in pyrazine, taken as a paradigm case of high-dimensional dynamics at a conical intersection. We consider a simplified model by which four modes are strongly coupled to the electronic subsystem while a number of weakly coupled tuning modes, inducing energy gap fluctuations, are sampled from a spectral density. The latter is approximated by a series of simplified spectral densities which can be cast into a continued-fraction form, as previously demonstrated in Hughes et al. (K.H. Hughes, C.D. Christ, I. Burghardt, J. Chem. Phys. 131 (2009) 124108). In the time domain, the hierarchy of spectral densities translates to truncated effective-mode chains with a Markovian or quasi-Markovian (Rubin type) closure. A sequential deconvolution procedure is employed to generate this chain representation. The implications for the ultrafast dynamics and its representation in terms of reduced-dimensional models are discussed.

  1. Ni3Si(Al)/a-SiOx core shell nanoparticles: characterization, shell formation, and stability

    Science.gov (United States)

    Pigozzi, G.; Mukherji, D.; Gilles, R.; Barbier, B.; Kostorz, G.

    2006-08-01

    We have used an electrochemical selective phase dissolution method to extract nanoprecipitates of the Ni3Si-type intermetallic phase from two-phase Ni-Si and Ni-Si-Al alloys by dissolving the matrix phase. The extracted nanoparticles are characterized by transmission electron microscopy, energy-dispersive x-ray spectrometry, x-ray powder diffraction, and electron powder diffraction. It is found that the Ni3Si-type nanoparticles have a core-shell structure. The core maintains the size, the shape, and the crystal structure of the precipitates that existed in the bulk alloys, while the shell is an amorphous phase, containing only Si and O (SiOx). The shell forms around the precipitates during the extraction process. After annealing the nanoparticles in nitrogen at 700 °C, the tridymite phase recrystallizes within the shell, which remains partially amorphous. In contrast, on annealing in air at 1000 °C, no changes in the composition or the structure of the nanoparticles occur. It is suggested that the shell forms after dealloying of the matrix phase, where Si atoms, the main constituents of the shell, migrate to the surface of the precipitates.

  2. WebQuest on Conic Sections as a Learning Tool for Prospective Teachers

    Science.gov (United States)

    Kurtulus, Aytac; Ada, Tuba

    2012-01-01

    WebQuests incorporate technology with educational concepts through integrating online resources with student-centred and activity-based learning. In this study, we describe and evaluate a WebQuest based on conic sections, which we have used with a group of prospective mathematics teachers. The WebQuest entitled: "Creating a Carpet Design Using…

  3. Bio-inspired multistructured conical copper wires for highly efficient liquid manipulation.

    Science.gov (United States)

    Wang, Qianbin; Meng, Qingan; Chen, Ming; Liu, Huan; Jiang, Lei

    2014-09-23

    Animal hairs are typical structured conical fibers ubiquitous in natural system that enable the manipulation of low viscosity liquid in a well-controlled manner, which serves as the fundamental structure in Chinese brush for ink delivery in a controllable manner. Here, drawing inspiration from these structure, we developed a dynamic electrochemical method that enables fabricating the anisotropic multiscale structured conical copper wire (SCCW) with controllable conicity and surface morphology. The as-prepared SCCW exhibits a unique ability for manipulating liquid with significantly high efficiency, and over 428 times greater than its own volume of liquid could be therefore operated. We propose that the boundary condition of the dynamic liquid balance behavior on conical fibers, namely, steady holding of liquid droplet at the tip region of the SCCW, makes it an excellent fibrous medium to manipulate liquid. Moreover, we demonstrate that the titling angle of the SCCW can also affect its efficiency of liquid manipulation by virtue of its mechanical rigidity, which is hardly realized by flexible natural hairs. We envision that the bio-inspired SCCW could give inspiration in designing materials and devices to manipulate liquid in a more controllable way and with high efficiency.

  4. Soft Computing Technique and Conventional Controller for Conical Tank Level Control

    Directory of Open Access Journals (Sweden)

    Sudharsana Vijayan

    2016-03-01

    Full Text Available In many process industries the control of liquid level is mandatory. But the control of nonlinear process is difficult. Many process industries use conical tanks because of its non linear shape contributes better drainage for solid mixtures, slurries and viscous liquids. So, control of conical tank level is a challenging task due to its non-linearity and continually varying cross-section. This is due to relationship between controlled variable level and manipulated variable flow rate, which has a square root relationship. The main objective is to execute the suitable controller for conical tank system to maintain the desired level. System identification of the non-linear process is done using black box modelling and found to be first order plus dead time (FOPDT model. In this paper it is proposed to obtain the mathematical modelling of a conical tank system and to study the system using block diagram after that soft computing technique like fuzzy and conventional controller is also used for the comparison.

  5. Conical square function estimates in UMD Banach spaces and applications to H?-functional calculi

    NARCIS (Netherlands)

    Hytönen, T.; Van Neerven, J.; Portal, P.

    2008-01-01

    We study conical square function estimates for Banach-valued functions and introduce a vector-valued analogue of the Coifman-Meyer-Stein tent spaces. Following recent work of Auscher-M(c)Intosh-Russ, the tent spaces in turn are used to construct a scale of vector-valued Hardy spaces associated with

  6. The index of Fourier integral operators on manifolds with conical singularities

    International Nuclear Information System (INIS)

    Nazaikinskii, Vladimir E; Sternin, B Yu; Schulze, B-W

    2001-01-01

    We describe homogeneous canonical transformations of the cotangent bundle of a manifold with conical singular points and compute the index of an elliptic Fourier integral operator obtained by the quantization of such a transformation. The answer involves the index of an elliptic Fourier integral operator on a smooth manifold and the residues of the conormal symbol

  7. On the bound states of Schrodinger operators with -interactions on conical surfaces

    Czech Academy of Sciences Publication Activity Database

    Lotoreichik, Vladimir; Ourmieres-Bonafos, T.

    2016-01-01

    Roč. 41, č. 6 (2016), s. 999-1028 ISSN 0360-5302 Institutional support: RVO:61389005 Keywords : conical and hyperconical surfaces * delta-interaction * existence of bound states * Schrodinger operator * spectral asymptotics Subject RIV: BE - Theoretical Physics Impact factor: 1.608, year: 2016

  8. CBLIB 2014: a benchmark library for conic mixed-integer and continuous optimization

    DEFF Research Database (Denmark)

    Friberg, Henrik Alsing

    2016-01-01

    The Conic Benchmark Library is an ongoing community-driven project aiming to challenge commercial and open source solvers on mainstream cone support. In this paper, 121 mixed-integer and continuous second-order cone problem instances have been selected from 11 categories as representative...

  9. Conic Sections and the Discovery of a Novel Curve Using Differential Equations

    Science.gov (United States)

    de Alwis, Amal

    2013-01-01

    We began by observing a variety of properties related to the tangent and normal lines of three conic sections: a parabola, an ellipse, and a hyperbola. Some of these properties include specific relationships between the x- and y-intercepts of the tangent and normal lines. Using these properties, we were able to form several differential equations.…

  10. Dispersion of near-infrared laser energy through radicular dentine when using plain or conical tips.

    Science.gov (United States)

    Teo, Christine Yi Jia; George, Roy; Walsh, Laurence J

    2018-02-01

    The aim of this study was to investigate the influence of tip design on patterns of laser energy dispersion through the dentine of tooth roots when using near-infrared diode lasers. Diode laser emissions of 810 or 940 nm were used in combination with optical fiber tips with either conventional plain ends or conical ends, to irradiate tooth roots of oval or round cross-sectional shapes. The lasers were operated in continuous wave mode at 0.5 W for 5 s with the distal end of the fiber tip placed in the apical or coronal third of the root canal at preset positions. Laser light exiting through the roots and apical foramen was imaged, and the extent of lateral spread calculated. There was a significant difference in infrared light exiting the root canal apex between plain and conical fiber tips for both laser wavelengths, with more forward transmission of laser energy through the apex for plain tips. For both laser wavelengths, there were no significant differences in emission patterns when the variable of canal shape was used and all other variables were kept the same (plain vs conical tip, tip position). To ensure optimal treatment effect and to prevent the risks of inadvertent laser effects on the adjacent periapical tissues, it is important to have a good understanding of laser transmission characteristics of the root canal and root dentine. Importantly, it is also essential to understand transmission characteristics of plain and conical fibers tips.

  11. Optical vault: a reconfigurable bottle beam based on conical refraction of light.

    Science.gov (United States)

    Turpin, A; Shvedov, V; Hnatovsky, C; Loiko, Yu V; Mompart, J; Krolikowski, W

    2013-11-04

    We employ conical refraction of light in a biaxial crystal to create an optical bottle for photophoretic trapping and manipulation of particles in gaseous media. We show that by only varying the polarization state of the input light beam the optical bottle can be opened and closed in order to load and unload particles in a highly controllable manner.

  12. Wave function continuity and the diagonal Born-Oppenheimer correction at conical intersections.

    Science.gov (United States)

    Meek, Garrett A; Levine, Benjamin G

    2016-05-14

    We demonstrate that though exact in principle, the expansion of the total molecular wave function as a sum over adiabatic Born-Oppenheimer (BO) vibronic states makes inclusion of the second-derivative nonadiabatic energy term near conical intersections practically problematic. In order to construct a well-behaved molecular wave function that has density at a conical intersection, the individual BO vibronic states in the summation must be discontinuous. When the second-derivative nonadiabatic terms are added to the Hamiltonian, singularities in the diagonal BO corrections (DBOCs) of the individual BO states arise from these discontinuities. In contrast to the well-known singularities in the first-derivative couplings at conical intersections, these singularities are non-integrable, resulting in undefined DBOC matrix elements. Though these singularities suggest that the exact molecular wave function may not have density at the conical intersection point, there is no physical basis for this constraint. Instead, the singularities are artifacts of the chosen basis of discontinuous functions. We also demonstrate that continuity of the total molecular wave function does not require continuity of the individual adiabatic nuclear wave functions. We classify nonadiabatic molecular dynamics methods according to the constraints placed on wave function continuity and analyze their formal properties. Based on our analysis, it is recommended that the DBOC be neglected when employing mixed quantum-classical methods and certain approximate quantum dynamical methods in the adiabatic representation.

  13. Discharge Coefficient Measurements for Flow Through Compound-Angle Conical Holes with Cross-Flow

    Directory of Open Access Journals (Sweden)

    M. E. Taslim

    2004-01-01

    Full Text Available Diffusion-shaped film holes with compound angles are currently being investigated for high temperature gas turbine airfoil film cooling. An accurate prediction of the coolant blowing rate through these film holes is essential in determining the film effectiveness. Therefore, the discharge coefficients associated with these film holes for a range of hole pressure ratios is essential in designing airfoil cooling circuits. Most of the available discharge coefficient data in open literature has been for cylindrical holes. The main objective of this experimental investigation was to measure the discharge coefficients for subsonic as well as supersonic pressure ratios through a single conical-diffusion hole. The conical hole has an exit-to-inlet area ratio of 4, a nominal flow length-to-inlet diameter ratio of 4, and an angle with respect to the exit plane (inclination angle of 0°, 30°, 45°, and 60°. Measurements were performed with and without a cross-flow. For the cases with a cross-flow, discharge coefficients were measured for each of the hole geometries and 5 angles between the projected conical hole axis and the cross-flow direction of 0°, 45°, 90°, 135°, and 180°. Results are compared with available data in open literature for cylindrical film holes as well as limited data for conical film holes.

  14. Flow structures in large-angle conical diffusers measured by PIV

    DEFF Research Database (Denmark)

    Meyer, Knud Erik; Nielsen, L.; Nielsen, N.F.

    2004-01-01

    Flow in two different conical diffusers with large opening angles (30° and 18°) have been measured with stereoscopic Particle Image Velocimetry (PIV). The measurements were done in a cross section just after the exit of the diffuser. The Reynolds number was 100000 based on upstream diameter...

  15. Isotopic characteristics of shells Mytilus galloprovincialis from eastern coastal area of Adriatic Sea

    Directory of Open Access Journals (Sweden)

    Tjaša Kanduč

    2006-06-01

    Full Text Available Samples of Mytilus galloprovincialis were collected from entire Eastern Adriatic coast to determine δ18O and δ13C performed on calcite and aragonite shell layers. The aim of this work was to check whether shells of M. galloprovincialis are good environmental indicators (water temperature, salinity. Based on measured isotopic composition of oxygen in shell layers and assumed isotopic composition in water temperatures of calcite and aragonite of shell layers were calculated. The calculated temperatures for M. galloprovincialis shell growth of calcite and aragonite shell layer are in good agreement with measured temperatures of sea water. According to our results of δ18O and δ13C in shell layers we canseparate the locations of the investigated area into three groups: those with more influence of fresh water, those with less influence of fresh water and those of marine environments.

  16. Process to make core-shell structured nanoparticles

    Science.gov (United States)

    Luhrs, Claudia; Phillips, Jonathan; Richard, Monique N

    2014-01-07

    Disclosed is a process for making a composite material that contains core-shell structured nanoparticles. The process includes providing a precursor in the form of a powder a liquid and/or a vapor of a liquid that contains a core material and a shell material, and suspending the precursor in an aerosol gas to produce an aerosol containing the precursor. In addition, the process includes providing a plasma that has a hot zone and passing the aerosol through the hot zone of the plasma. As the aerosol passes through the hot zone of the plasma, at least part of the core material and at least part of the shell material in the aerosol is vaporized. Vapor that contains the core material and the shell material that has been vaporized is removed from the hot zone of the plasma and allowed to condense into core-shell structured nanoparticles.

  17. Dyson shells: a retrospective

    Science.gov (United States)

    Bradbury, Robert J.

    2001-08-01

    More than 40 years have passed since Freeman Dyson suggested that advanced technological civilizations are likely to dismantle planets in their solar systems to harvest all of the energy their stars wastefully radiate into space. Clearly this was an idea that was ahead of its time. Since that time, dozens of SETI searches have been conducted and almost all of them have focused their attention on stars which by definition cannot be the advanced civilizations that Dyson envisioned. I will review the data that created the confusion between Dyson spheres and Dyson shells. The sources that disprove Dyson spheres while still allowing Dyson shells will be discussed. The use of outmoded ideas that have biased the few searches for Dyson Shells that have occurred will be pointed out. An update of the concept of Dyson shells to include our current knowledge of biotechnology, nanotechnology and computer science will be explored. Finally, an approach to setting limits on the abundance of Dyson shells in our galaxy using existing optical astronomical data and future optical satellites will be proposed.

  18. NIF Double Shell outer/inner shell collision experiments

    Science.gov (United States)

    Merritt, E. C.; Loomis, E. N.; Wilson, D. C.; Cardenas, T.; Montgomery, D. S.; Daughton, W. S.; Dodd, E. S.; Desjardins, T.; Renner, D. B.; Palaniyappan, S.; Batha, S. H.; Khan, S. F.; Smalyuk, V.; Ping, Y.; Amendt, P.; Schoff, M.; Hoppe, M.

    2017-10-01

    Double shell capsules are a potential low convergence path to substantial alpha-heating and ignition on NIF, since they are predicted to ignite and burn at relatively low temperatures via volume ignition. Current LANL NIF double shell designs consist of a low-Z ablator, low-density foam cushion, and high-Z inner shell with liquid DT fill. Central to the Double Shell concept is kinetic energy transfer from the outer to inner shell via collision. The collision determines maximum energy available for compression and implosion shape of the fuel. We present results of a NIF shape-transfer study: two experiments comparing shape and trajectory of the outer and inner shells at post-collision times. An outer-shell-only target shot measured the no-impact shell conditions, while an `imaging' double shell shot measured shell conditions with impact. The `imaging' target uses a low-Z inner shell and is designed to perform in similar collision physics space to a high-Z double shell but can be radiographed at 16keV, near the viable 2DConA BL energy limit. Work conducted under the auspices of the U.S. DOE by LANL under contract DE-AC52-06NA25396.

  19. Analysis of thermal-plastic response of shells of revolution by numerical integration

    International Nuclear Information System (INIS)

    Leonard, J.W.

    1975-01-01

    A numerical method based instead on the numerical integration of the governing shell equations has been shown, for elastic cases, to be more efficient than the finite element method when applied to shells of revolution. In the numerical integration method, the governing differential equations of motions are converted into a set of initial-value problems. Each initial-value problem is integrated numerically between meridional boundary points and recombined so as to satisfy boundary conditions. For large-deflection elasto-plastic behavior, the equations are nonlinear and, hence, are recombined in an iterative manner using the Newton-Raphson procedure. Suppression techniques are incorporated in order to eliminate extraneous solutions within the numerical integration procedure. The Reissner-Meissner shell theory for shells of revolution is adopted to account for large deflection and higher-order rotation effects. The computer modelling of the equations is quite general in that specific shell segment geometries, e.g. cylindrical, spherical, toroidal, conical segments, and any combinations thereof can be handled easily. The elasto-plastic constitutive relations adopted are in accordance with currently recommended constitutive equations for inelastic design analysis of FFTF Components. The Von Mises yield criteria and associated flow rule is used and the kinematic hardening law is followed. Examples are considered in which stainless steels common to LMFBR application are used

  20. Nonadiabatic Eigenfunctions Can Have Amplitude, Signed Conical Nodes, or Signed Higher Order Nodes at a Conical Intersection with Circular Symmetry (Open Access Publisher’s Version)

    Science.gov (United States)

    2017-09-26

    marked by black rings on the potential energy surfaces. In some sense, only about half of the zero point energy is available to each of the two...wheel at the bottom. The conical intersection at q1 = q2 = 0 and E = 0 is submerged below the zero-point energy of Ezp = 181 cm −1 ( black curve). The...J. Chem. Phys. 123, 044102 (2005)]. J. Chem. Phys. 2008, 128, 109902. (49) Clinton, W. L.; Rice , B. Reformulation of the Jahn-Teller Theorem. J

  1. Nanostructued core–shell Sn nanowires @ CNTs with controllable thickness of CNT shells for lithium ion battery

    Energy Technology Data Exchange (ETDEWEB)

    Zhong, Yu; Li, Xifei; Zhang, Yong; Li, Ruying [Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9 (Canada); Cai, Mei [General Motors Research and Development Center, Warren, MI 48090-9055 (United States); Sun, Xueliang, E-mail: xsun@eng.uwo.ca [Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9 (Canada)

    2015-03-30

    Graphical abstract: - Highlights: • Sn nanowires encapsulated in CNTs directly grew on current collectors. • The thickness of CNTs were controlled via growth time, gas flow rate and synthesis temperature. • Thick CNTs contributed to a better capacity retention while thin CNTs led to a higher capacity. • The core–shell structures formed in one-step CVD process. - Abstract: Core–shell structure of Sn nanowires encapsulated in amorphous carbon nanotubes (Sn@CNTs) with controlled thickness of CNT shells was in situ prepared via chemical vapor deposition (CVD) method. The thickness of CNT shells was accurately controlled from 4 to 99 nm by using different growth time, flow rate of hydrocarbon gas (C{sub 2}H{sub 4}) and synthesis temperature. The microstructure and composition of the coaxial Sn@CNTs were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and high resolution transmission electron microscopy (HRTEM) techniques. Moreover, the Sn@CNTs were studied as anode materials for Li-ion batteries and showed excellent cycle performance. The capacity was affected by the thickness of outer CNT shells: thick CNT shells contributed to a better retention while thin CNT shells led to a higher capacity. The thin CNT shell of 6 nm presented the highest capacity around 630 mAh g{sup −1}.

  2. Nanostructued core–shell Sn nanowires @ CNTs with controllable thickness of CNT shells for lithium ion battery

    International Nuclear Information System (INIS)

    Zhong, Yu; Li, Xifei; Zhang, Yong; Li, Ruying; Cai, Mei; Sun, Xueliang

    2015-01-01

    Graphical abstract: - Highlights: • Sn nanowires encapsulated in CNTs directly grew on current collectors. • The thickness of CNTs were controlled via growth time, gas flow rate and synthesis temperature. • Thick CNTs contributed to a better capacity retention while thin CNTs led to a higher capacity. • The core–shell structures formed in one-step CVD process. - Abstract: Core–shell structure of Sn nanowires encapsulated in amorphous carbon nanotubes (Sn@CNTs) with controlled thickness of CNT shells was in situ prepared via chemical vapor deposition (CVD) method. The thickness of CNT shells was accurately controlled from 4 to 99 nm by using different growth time, flow rate of hydrocarbon gas (C 2 H 4 ) and synthesis temperature. The microstructure and composition of the coaxial Sn@CNTs were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and high resolution transmission electron microscopy (HRTEM) techniques. Moreover, the Sn@CNTs were studied as anode materials for Li-ion batteries and showed excellent cycle performance. The capacity was affected by the thickness of outer CNT shells: thick CNT shells contributed to a better retention while thin CNT shells led to a higher capacity. The thin CNT shell of 6 nm presented the highest capacity around 630 mAh g −1

  3. Sidewall coring shell

    Energy Technology Data Exchange (ETDEWEB)

    Edelman, Ya A; Konstantinov, L P; Martyshin, A N

    1966-12-12

    A sidewall coring shell consists of a housing and a detachable core catcher. The core lifter is provided with projections, the ends of which are situated in another plane, along the longitudinal axis of the lifter. The chamber has corresponding projections.

  4. Stability of charged thin shells

    International Nuclear Information System (INIS)

    Eiroa, Ernesto F.; Simeone, Claudio

    2011-01-01

    In this article we study the mechanical stability of spherically symmetric thin shells with charge, in Einstein-Maxwell and Einstein-Born-Infeld theories. We analyze linearized perturbations preserving the symmetry, for shells around vacuum and shells surrounding noncharged black holes.

  5. Temporal structures in shell models

    DEFF Research Database (Denmark)

    Okkels, F.

    2001-01-01

    The intermittent dynamics of the turbulent Gledzer, Ohkitani, and Yamada shell-model is completely characterized by a single type of burstlike structure, which moves through the shells like a front. This temporal structure is described by the dynamics of the instantaneous configuration of the shell...

  6. FINITE ELEMENT DISPLACEMENT PERTURBATION METHOD FOR GEOMETRIC NONLINEAR BEHAVIORS OF SHELLS OF REVOLUTION OVERALL BENDING IN A MERIDIONAL PLANE AND APPLICATION TO BELLOWS (Ⅰ)

    Institute of Scientific and Technical Information of China (English)

    朱卫平; 黄黔

    2002-01-01

    In order to analyze bellows effectively and practically, the finite-element-displacement-perturbation method (FEDPM) is proposed for the geometric nonlinearbehaviors of shells of revolution subjected to pure bending moments or lateral forces in one of their meridional planes. The formulations are mainly based upon the idea of perturba-tion that the nodal displacement vector and the nodal force vector of each finite elementare expanded by taking root-mean-square value of circumferential strains of the shells as aperturbation parameter. The load steps and the iteration times are not cs arbitrary andunpredictable as in usual nonlinear analysis. Instead, there are certain relations betweenthe load steps and the displacement increments, and no need of iteration for each loadstep. Besides, in the formulations, the shell is idealized into a series of conical frusta for the convenience of practice, Sander' s nonlinear geometric equations of moderate smallrotation are used, and the shell made of more than one material ply is also considered.

  7. Single-step generation of metal-plasma polymer multicore@shell nanoparticles from the gas phase.

    Science.gov (United States)

    Solař, Pavel; Polonskyi, Oleksandr; Olbricht, Ansgar; Hinz, Alexander; Shelemin, Artem; Kylián, Ondřej; Choukourov, Andrei; Faupel, Franz; Biederman, Hynek

    2017-08-17

    Nanoparticles composed of multiple silver cores and a plasma polymer shell (multicore@shell) were prepared in a single step with a gas aggregation cluster source operating with Ar/hexamethyldisiloxane mixtures and optionally oxygen. The size distribution of the metal inclusions as well as the chemical composition and the thickness of the shells were found to be controlled by the composition of the working gas mixture. Shell matrices ranging from organosilicon plasma polymer to nearly stoichiometric SiO 2 were obtained. The method allows facile fabrication of multicore@shell nanoparticles with tailored functional properties, as demonstrated here with the optical response.

  8. Vertical microbial community variability of carbonate-based cones may provide insight into ancient conical stromatolite formation

    Science.gov (United States)

    Bradley, James; Daille, Leslie; Trivedi, Christopher; Bojanowski, Caitlin; Nunn, Heather; Stamps, Blake; Johnson, Hope; Stevenson, Bradley; Berelson, Will; Corsetti, Frank; Spear, John

    2016-04-01

    Stromatolite morphogenesis is poorly understood, and the process by which microbial mats become mineralized is a primary question in microbialite formation. Ancient conical stromatolites are primarily carbonate-based whereas the few modern analogues in hot springs are either non-mineralized or mineralized by silica. A team from the 2015 International GeoBiology Course investigated carbonate-rich microbial cones from near Little Hot Creek (LHC), Long Valley Caldera, California, to investigate how conical stromatolites might form in a hot spring carbonate system. The cones rise up from a layered microbial mat on the east side of a 45° C pool with very low flow that is super-saturated with respect to CaCO3. Cone structures are 8-30 mm in height, are rigid and do not deform when removed from the pool. Morphological characterization through environmental scanning electronic microscopy revealed that the cone structure is maintained by a matrix of intertwining microbial filaments around carbonate grains. This matrix gives rise to cone-filaments that are arranged vertically or horizontally, and provides further stability to the cone. Preliminary 16S rRNA gene analysis indicated variability of community composition between different vertical levels of the cone. The cone tip had comparatively greater abundance of filamentous cyanobacteria including Leptolingbya, Phormidium and Isosphaera and fewer heterotrophs (e.g. Chloroflexi) compared to the cone bottom. This supports the hypothesis that cone formation may depend on the differential abundance of the microbial community and their potential functional roles. Metagenomic analyses of the cones revealed potential genes related to chemotaxis and motility. Specifically, a genomic bin identified as a member of the genus Isosphaera contained an hmp chemotaxis operon implicated in gliding motility in the cyanobacterium Nostoc punctiforme. Isosphaera is a Planctomycete shown to have phototactic capabilities, and may play a role in

  9. Numerical method of applying shadow theory to all regions of multilayered dielectric gratings in conical mounting.

    Science.gov (United States)

    Wakabayashi, Hideaki; Asai, Masamitsu; Matsumoto, Keiji; Yamakita, Jiro

    2016-11-01

    Nakayama's shadow theory first discussed the diffraction by a perfectly conducting grating in a planar mounting. In the theory, a new formulation by use of a scattering factor was proposed. This paper focuses on the middle regions of a multilayered dielectric grating placed in conical mounting. Applying the shadow theory to the matrix eigenvalues method, we compose new transformation and improved propagation matrices of the shadow theory for conical mounting. Using these matrices and scattering factors, being the basic quantity of diffraction amplitudes, we formulate a new description of three-dimensional scattering fields which is available even for cases where the eigenvalues are degenerate in any region. Some numerical examples are given for cases where the eigenvalues are degenerate in the middle regions.

  10. Born-Infeld determinantal gravity and the taming of the conical singularity in 3-dimensional spacetime

    Energy Technology Data Exchange (ETDEWEB)

    Ferraro, Rafael, E-mail: ferraro@iafe.uba.a [Instituto de Astronomia y Fisica del Espacio, Casilla de Correo 67, Sucursal 28, 1428 Buenos Aires (Argentina); Departamento de Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellon I, 1428 Buenos Aires (Argentina); Fiorini, Franco, E-mail: franco@iafe.uba.a [Instituto de Astronomia y Fisica del Espacio, Casilla de Correo 67, Sucursal 28, 1428 Buenos Aires (Argentina)

    2010-08-30

    In the context of Born-Infeld determinantal gravity formulated in an n-dimensional spacetime with absolute parallelism, we found an exact 3-dimensional vacuum circular symmetric solution without cosmological constant consisting in a rotating spacetime with non-singular behavior. The space behaves at infinity as the conical geometry typical of 3-dimensional General Relativity without cosmological constant. However, the solution has no conical singularity because the space ends at a minimal circle that no freely falling particle can ever reach in a finite proper time. The space is curved, but no divergences happen since the curvature invariants vanish at both asymptotic limits. Remarkably, this very mechanism also forbids the existence of closed timelike curves in such a spacetime.

  11. Born-Infeld determinantal gravity and the taming of the conical singularity in 3-dimensional spacetime

    International Nuclear Information System (INIS)

    Ferraro, Rafael; Fiorini, Franco

    2010-01-01

    In the context of Born-Infeld determinantal gravity formulated in an n-dimensional spacetime with absolute parallelism, we found an exact 3-dimensional vacuum circular symmetric solution without cosmological constant consisting in a rotating spacetime with non-singular behavior. The space behaves at infinity as the conical geometry typical of 3-dimensional General Relativity without cosmological constant. However, the solution has no conical singularity because the space ends at a minimal circle that no freely falling particle can ever reach in a finite proper time. The space is curved, but no divergences happen since the curvature invariants vanish at both asymptotic limits. Remarkably, this very mechanism also forbids the existence of closed timelike curves in such a spacetime.

  12. The spectra of conical bubble sonoluminescence in 1,2-propanediol and glycol

    International Nuclear Information System (INIS)

    He Shoujie; Jing Ha; Li Xuechen; Li Qing; Dong Lifang; Wang, Long

    2007-01-01

    A conical bubble straight tube apparatus was set up to study sonoluminescence. The spectra of conical bubble sonoluminescence for 1,2-propanediol and glycol were detected. The results show that the luminescence is intense, and the spectra consist of a broad background on which five clear sequences of Swan bands and three sequences of the B 2 Σ + → X 2 Σ + transition of CN are superimposed. A band assigned to the A 2 Δ → X 2 Π transition of CH was also measured and the vibrational and rotational structures of Swan bands could be resolved. The origin of the C* 2 and C 2 H* is discussed. Finally, the achieved molecular vibrational temperature is estimated to be about 5400 ± 350 K

  13. ANALYSIS OF RIBBONING ON CONICAL YARN PACKAGE WOUND BY OPENEND SPINNING MACHINES

    Directory of Open Access Journals (Sweden)

    Resul FETTAHOV

    2001-03-01

    Full Text Available In this paper, Ribboning , one of the common faults in yarn packages, is mathematically analysed. If yarn is repeatly laid on top of or along the same path as the previously wound yarn, this duplication of yarn path on the package creates a defect known as ribboning. The number of turns of package (n per double traverse of yarn guide is calculated in two different way One is calculated the length of a coil on the package and total length of yarn in a double traverse; the other is considered transmission rate between drum and conical yarn package The result of two different approach is similar and the probable diameter of conical yarn package which ribboning is occurred is calculated and used on Schalafhorst-Autocore OE spinning machines.

  14. Numerical analysis for the flow field past a two-staged conical orifice

    International Nuclear Information System (INIS)

    Kim, Yeon Soo; Kim, You Gon

    2001-01-01

    The objective of the paper was to measure the pressure drop and to investigate the recirculation region of the conical orifices used in Kwang-yang Iron and Steel Company. The flow field with water used as a working fluid was the turbulent flow for Reynolds number of 2x10 4 . The effective parameters for the pressure drop and the recirculation region were the conical orifice's inclined angle (θ) against the wall, the interval(L) between orifices, the relative angle of rotation(α) of the orifices, the shape of the orifice's hole(circle, rectangle, triangle) having the same area. It was found that the shape of the orifice's hold affected the pressure drop and the flow field a lot. But the other parameters did not make much differences to the pressure drop. The PISO algorithm with FLUENT code was employed

  15. Emission performance and combustion efficiency of a conical fluidized-bed combustor firing various biomass fuels

    International Nuclear Information System (INIS)

    Permchart, W.; Kouprianov, V.I.

    2004-01-01

    This paper summarizes the results of an experimental study on combustion of three distinct biomass fuels (sawdust, rice husk and pre-dried sugar cane bagasse) in a single fluidized-bed combustor (FBC) with a conical bed using silica sand as the inert bed material. Temperature, CO, NO and O 2 concentrations along the combustor height as well as in flue (stack) gas were measured in the experimental tests. The effects of fuel properties and operating conditions (load and excess air) on these variables were investigated. Both CO and NO axial profiles were found to have a maximum whose location divides conventionally the combustor volume into formation (lower) and reduction (upper) regions for these pollutants. Based on CO emission and unburned carbon content in fly ash, the combustion efficiency of the conical FBC was quantified for the selected biomass fuels fired under different operating conditions. (Author)

  16. Thermal response of an aeroassisted orbital-transfer vehicle with a conical drag brake

    Science.gov (United States)

    Pitts, W. C.; Murbach, M. S.

    1984-01-01

    As an aeroassisted orbital-transfer vehicle (AOTV) goes through an aerobraking maneuver, a significant amount of heat is generated. In this paper, the thermal response of a specific AOTV to this aerobrake heating is examined. The vehicle has a 70 deg, conical drag-brake heat shield attached to a cylindrical body which contains the payload. The heat shield is made of silica fabric. The heat-shield thickness is varied from that of a thin cloth to a 1.5-cm blanket. The fabric thickness, the radiation absorptivity of the vehicle surface materials, and radiation from the wake are all significant parameters in the thermal response to the heating produced by the braking maneuver. The maximum temperatures occur in the vicinity of the interface between the body and the conical heat shield.

  17. Thermal Response of an Aeroassisted Orbital Transfer Vehicle with a Conical Drag Brake

    Science.gov (United States)

    Pitts, W. C.; Murbach, M. S.

    1985-01-01

    As an aeroassisted orbital transfer vehicle (AOTV) goes through an aerobraking maneuver a significant amount of heat is generated. In this paper, the thermal response of a specific AOTV to this aerobrake heating is examined. The vehicle has a 70-deg, Conical drag-brake heat shield attached to a cylindrical body which contains the payload. The heat shield is made of ceramic fabric its thickness is varied from that of a thin cloth to a 1.5-cm blanket. The fabric thickness, the radiation absorptivity of the vehicle surface materials, and radiation from the wake are all significant parameters in the thermal response to the heating produced by the braking maneuver. The maximum temperatures occur In the vicinity of the interface between the body and the conical heat shield.

  18. High-Efficiency Fog Collector: Water Unidirectional Transport on Heterogeneous Rough Conical Wires.

    Science.gov (United States)

    Xu, Ting; Lin, Yucai; Zhang, Miaoxin; Shi, Weiwei; Zheng, Yongmei

    2016-12-27

    An artificial periodic roughness-gradient conical copper wire (PCCW) can be fabricated by inspiration from cactus spines and wet spider silks. PCCW can harvest fog on periodic points of the conical surface from air and transports the drops for a long distance without external force, which is attributed to dynamic as-released energy generated from drop deformation in drop coalescence, in addition to both gradients of geometric curve (inducing Laplace pressure) and periodic roughness (inducing surface energy difference). It is found that the ability of fog collection can be related to various tilt-angle wires, thus a fog collector with an array system of PCCWs is further designed to achieve a continuous process of efficient water collection. As a result, the effect of water collection on PCCWs is better than previous results. These findings are significant to develop and design materials with water collection and water transport for promising application in fogwater systems to ease the water crisis.

  19. Conical Refraction of Elastic Waves by Anisotropic Metamaterials and Application for Parallel Translation of Elastic Waves.

    Science.gov (United States)

    Ahn, Young Kwan; Lee, Hyung Jin; Kim, Yoon Young

    2017-08-30

    Conical refraction, which is quite well-known in electromagnetic waves, has not been explored well in elastic waves due to the lack of proper natural elastic media. Here, we propose and design a unique anisotropic elastic metamaterial slab that realizes conical refraction for horizontally incident longitudinal or transverse waves; the single-mode wave is split into two oblique coupled longitudinal-shear waves. As an interesting application, we carried out an experiment of parallel translation of an incident elastic wave system through the anisotropic metamaterial slab. The parallel translation can be useful for ultrasonic non-destructive testing of a system hidden by obstacles. While the parallel translation resembles light refraction through a parallel plate without angle deviation between entry and exit beams, this wave behavior cannot be achieved without the engineered metamaterial because an elastic wave incident upon a dissimilar medium is always split at different refraction angles into two different modes, longitudinal and shear.

  20. Theoretical interpretation of upstreaming electrons and elevated conics on auroral field lines

    International Nuclear Information System (INIS)

    Ashour-Abdalla, M.; Schriver, D.

    1989-01-01

    Recent VIKING satellite observations in the auroral zone have shown the association of elevated ion conics (conics with a low energy cutoff above zero) with upward streaming electrons in the presence of low frequency electric field fluctuations. A self-consistent particle simulation was developed which assumed the presence of a steady state electric field on auroral zone field lines capable of accelerating ions up the magnetic field lines. Results from this study show that a low frequency ion-ion two stream instability can be excited. This low frequency instability creates a fluctuating electric field which heats the ions oblique to the magnetic field forming distributions similar to the elevated ion comics. The ion-ion waves also interact resonantly with electrons and accelerates them in the direction of the ion beam

  1. The universe of conics from the ancient Greeks to 21st century developments

    CERN Document Server

    Glaeser, Georg; Odehnal, Boris

    2016-01-01

    This text presents the classical theory of conics in a modern form. It includes many novel results that are not easily accessible elsewhere. The approach combines synthetic and analytic methods to derive projective, affine and metrical properties, covering both Euclidean and non-Euclidean geometries. With more than two thousand years of history, conic sections play a fundamental role in numerous fields of mathematics and physics, with applications to mechanical engineering, architecture, astronomy, design and computer graphics. This text will be invaluable to undergraduate mathematics students, those in adjacent fields of study, and anyone with an interest in classical geometry. Augmented with more than three hundred fifty figures and photographs, this innovative text will enhance your understanding of projective geometry, linear algebra, mechanics, and differential geometry, with careful exposition and many illustrative exercises. Authors Hellmuth Stachel, born 1942, got his PhD and habilitation in geometry ...

  2. BALL KINEMATICS IN FINE POLISHING BETWEEN MISALIGNED DISKS IN CONIC OPENINGS

    Directory of Open Access Journals (Sweden)

    K. G. Shchetnikovich

    2009-01-01

    Full Text Available The paper considers ball kinematics in polishing between misaligned disks rotating with equal angular velocity; one of these disks has conic openings. Analytical dependences have been obtained for calculation of an angular velocity and ball sliding speed in the conic opening. It has been revealed that at a constant contact of a ball with elastic coating of a flat disk and absence of vibrations in the technological system an instantaneous axis of ball rotation does not change its position in the moving ball. It has been ascertained that when a ball is in contact with a flat disk having elastic coating with grooves changes in the position of ball rotation instantaneous axis have a regular character and do not depend on vibrations in the technological system.

  3. Interaction of a conical shock wave with a turbulent boundary layer

    Science.gov (United States)

    Teh, S. L.; Gai, S. L.

    The paper reports an investigation on the interaction of an incident conical shock wave with a turbulent boundary layer. Although a conical shock theoretically creates a hyperbolic shock trace on the flat plate, the line joining all the experimental interaction origins takes a different form due to varying upstream influence. The existence of strong pressure gradients in the spanwise direction after the shock leads to the boundary-layer twist. A model based on the upstream influence of the shock when combined with McCabe's secondary-flow theory showed separation to occur at an external flow deflection of 11.8 deg. The oil flow measurements however show this to occur at 9.2 deg. This discrepancy is of the same order as that found by McCabe. Detailed data involving Schlieren and shadowgraph photography, surface-flow visualization, and surface-pressure measurements are presented.

  4. Geometrical pinning of magnetic vortices induced by a deficit angle on a surface: Anisotropic spins on a conic space background

    International Nuclear Information System (INIS)

    Moura-Melo, W.A.; Pereira, A.R.; Mol, L.A.S.; Pires, A.S.T.

    2007-01-01

    We study magnetic vortex-like excitations lying on a conic space background. Two types of them are obtained. Their energies appear to be linearly dependent on the conical aperture parameter, besides of being logarithmically divergent with the sample size. In addition, we realize a geometrical-like pinning of the vortex, say, it is energetically favorable for it to nucleate around the conical apex. We also study the problem of two vortices on the cone and obtain an interesting effect on such a geometry: excitations of the same charge, then repealing each other, may nucleate around the apex for suitable cone apertures. We also pay attention to the problem of the vortex pair and how its dissociation temperature depends upon conical geometry

  5. The flow field structure of highly stabilized partially premixed flames in a concentric flow conical nozzle burner with coflow

    KAUST Repository

    Elbaz, Ayman M.; Zayed, M.F.; Samy, M.; Roberts, William L.; Mansour, Mohy S.

    2015-01-01

    The stability limits, the stabilization mechanism, and the flow field structure of highly stabilized partially premixed methane flames in a concentric flow conical nozzle burner with air co-flow have been investigated and presented in this work

  6. Graphical Derivatives and Stability Analysis for Parameterized Equilibria with Conic Constraints

    Czech Academy of Sciences Publication Activity Database

    Mordukhovich, B. S.; Outrata, Jiří; Ramírez, H. C.

    2015-01-01

    Roč. 23, č. 4 (2015), s. 687-704 ISSN 1877-0533 R&D Projects: GA ČR(CZ) GAP201/12/0671 Institutional support: RVO:67985556 Keywords : Variational analysis and optimization * Parameterized equilibria * Conic constraints * Sensitivity and stability analysis * Solution maps * Graphical derivatives * Normal and tangent cones Subject RIV: BA - General Mathematics Impact factor: 0.973, year: 2015 http://library.utia.cas.cz/separaty/2015/MTR/outrata-0449259.pdf

  7. Inverse truss design as a conic mathematical program with equilibrium constraints

    Czech Academy of Sciences Publication Activity Database

    Kočvara, Michal; Outrata, Jiří

    2017-01-01

    Roč. 10, č. 6 (2017), s. 1329-1350 ISSN 1937-1632 R&D Projects: GA ČR GA15-00735S Institutional support: RVO:67985556 Keywords : conic optimization * truss topology optimization * mathematical programs with equilibrium constraints Subject RIV: BA - General Mathematics OBOR OECD: Applied mathematics Impact factor: 0.781, year: 2016 http://library.utia.cas.cz/separaty/2017/MTR/kocvara-0477818.pdf

  8. Loads experiments study on two-story RC box and truncated conical walls

    International Nuclear Information System (INIS)

    Asega, H.; Iizuka, S.; Kurihara, I.; Kubo, T.

    1987-01-01

    The failure modes of the two specimens were the sliding shear failure. The two specimens showed almost equal deformation at the maximum shear strength. The ratio of the flexural deformation in the deformation of the truncated conical was larger than that of the box wall. The ratio of the shear deformation in the deformation of the two-story RC box wall was larger than that of the flexural deformation. (orig./HP)

  9. Conical refraction and formation of multiring focal image with Laguerre-Gauss light beams.

    Science.gov (United States)

    Peet, Viktor

    2011-08-01

    For a light beam focused through a biaxial crystal along one of its optical axes, the effect of internal conical refraction in the crystal leads to the formation in the focal image plane of two bright rings separated by a dark ring. It is shown that, with circularly polarized Laguerre-Gauss LG(0)(ℓ) beams entering the crystal, this classical double-ring pattern is transformed into a multiring one consisting of ℓ+2 bright rings. © 2011 Optical Society of America

  10. Indications of Conical Emission of Charged Hadrons at the BNL Relativistic Heavy Ion Collider

    Czech Academy of Sciences Publication Activity Database

    Abelev, B. I.; Aggarwal, M. M.; Ahammed, Z.; Anderson, B. D.; Arkhipkin, D.; Averichev, G. S.; Balewski, J.; Barannikova, O.; Barnby, L. S.; Baudot, J.; Baumgart, S.; Beavis, D.R.; Bellwied, R.; Benedosso, F.; Betancourt, M.J.; Betts, R. R.; Bhasin, A.; Bhati, A.K.; Bichsel, H.; Bielčík, Jaroslav; Bielčíková, Jana; Biritz, B.; Bland, L.C.; Bombara, M.; Bonner, B. E.; Botje, M.; Bouchet, J.; Braidot, E.; Brandin, A. V.; Bruna, E.; Bueltmann, S.; Burton, T. P.; Bysterský, Michal; Cai, X.Z.; Caines, H.; Sanchez, M.C.D.; Catu, O.; Cebra, D.; Cendejas, R.; Cervantes, M.C.; Chajecki, Z.; Chaloupka, Petr; Chattopadhyay, S.; Chen, H.F.; Chen, J.H.; Cheng, J.; Cherney, M.; Chikanian, A.; Choi, K.E.; Christie, W.; Clarke, R.F.; Codrington, M.J.M.; Corliss, R.; Cormier, T.M.; Coserea, R. M.; Cramer, J. G.; Crawford, H. J.; Das, D.; Dash, S.; Daugherity, M.; De Silva, L.C.; Dedovich, T. G.; DePhillips, M.; Derevschikov, A.A.; de Souza, R.D.; Didenko, L.; Djawotho, P.; Dunlop, J.C.; Mazumdar, M.R.D.; Edwards, W.R.; Efimov, L.G.; Elhalhuli, E.; Elnimr, M.; Emelianov, V.; Engelage, J.; Eppley, G.; Erazmus, B.; Estienne, M.; Eun, L.; Fachini, P.; Fatemi, R.; Fedorisin, J.; Feng, A.; Filip, P.; Finch, E.; Fine, V.; Fisyak, Y.; Gagliardi, C. A.; Gaillard, L.; Ganti, M. S.; Gangaharan, D.R.; Garcia-Solis, E.J.; Geromitsos, A.; Geurts, F.; Ghazikhanian, V.; Ghosh, P.; Gorbunov, Y.N.; Gordon, A.; Grebenyuk, O.; Grosnick, D.; Grube, B.; Guertin, S.M.; Guimaraes, K.S.F.F.; Gupta, A.; Gupta, N.; Guryn, W.; Haag, B.; Hallman, T.J.; Hamed, A.; Harris, J.W.; He, W.; Heinz, M.; Heppelmann, S.; Hippolyte, B.; Hirsch, A.; Hjort, E.; Hoffman, A.M.; Hoffmann, G.W.; Hofman, D.J.; Hollis, R.S.; Huang, H.Z.; Humanic, T.J.; Igo, G.; Iordanova, A.; Jacobs, P.; Jacobs, W.W.; Jakl, Pavel; Jena, C.; Jin, F.; Jones, C.L.; Jones, P.G.; Joseph, J.; Judd, E.G.; Kabana, S.; Kajimoto, K.; Kang, K.; Kapitán, Jan; Keane, D.; Kechechyan, A.; Kettler, D.; Khodyrev, V.Yu.; Kikola, D.P.; Kiryluk, J.; Kisiel, A.; Klein, S.R.; Knospe, A.G.; Kocoloski, A.; Koetke, D.D.; Kopytine, M.; Korsch, W.; Kotchenda, L.; Kushpil, Vasilij; Kravtsov, P.; Kravtsov, V.I.; Krueger, K.; Krus, M.; Kuhn, C.; Kumar, L.; Kurnadi, P.; Lamont, M.A.C.; Landgraf, J.M.; LaPointe, S.; Lauret, J.; Lebedev, A.; Lednický, Richard; Lee, Ch.; Lee, J.H.; Leight, W.; LeVine, M.J.; Li, N.; Li, C.; Li, Y.; Lin, G.; Lindenbaum, S.J.; Lisa, M.A.; Liu, F.; Liu, J.; Liu, L.; Ljubicic, T.; Llope, W.J.; Longacre, R.S.; Love, W.A.; Lu, Y.; Ludlam, T.; Ma, G.L.; Ma, Y.G.; Mahapatra, D.P.; Majka, R.; Mall, O.I.; Mangotra, L.K.; Manweiler, R.; Margetis, S.; Markert, C.; Matis, H.S.; Matulenko, Yu.A.; McShane, T.S.; Meschanin, A.; Milner, R.; Minaev, N.G.; Mioduszewski, S.; Mischke, A.; Mitchell, J.; Mohanty, B.; Morozov, D.A.; Munhoz, M. G.; Nandi, B.K.; Nattrass, C.; Nayak, T. K.; Nelson, J.M.; Netrakanti, P.K.; Ng, M.J.; Nogach, L.V.; Nurushev, S.B.; Odyniec, G.; Ogawa, A.; Okada, H.; Okorokov, V.; Olson, D.; Pachr, M.; Page, B.S.; Pal, S.K.; Pandit, Y.; Panebratsev, Y.; Panitkin, S.Y.; Pawlak, T.; Peitzmann, T.; Perevoztchikov, V.; Perkins, C.; Peryt, W.; Phatak, S.C.; Poljak, N.; Poskanzer, A.M.; Potukuchi, B.V.K.S.; Prindle, D.; Pruneau, C.; Pruthi, N.K.; Putschke, J.; Raniwala, R.; Raniwala, S.; Ray, R.L.; Redwine, R.; Reed, R.; Ridiger, A.; Ritter, H.G.; Roberts, J.B.; Rogachevskiy, O.V.; Romero, J.L.; Rose, A.; Roy, C.; Ruan, L.; Russcher, M.J.; Sahoo, R.; Sakrejda, I.; Sakuma, T.; Salur, S.; Sandweiss, J.; Sarsour, M.; Schambach, J.; Scharenberg, R.P.; Schmitz, N.; Seger, J.; Selyuzhenkov, I.; Seyboth, P.; Shabetai, A.; Shahaliev, E.; Shao, M.; Sharma, M.; Shi, S.S.; Shi, X.H.; Sichtermann, E.P.; Simon, F.; Singaraju, R.N.; Skoby, M.J.; Smirnov, N.; Snellings, R.; Sorensen, P.; Sowinski, J.; Spinka, H.M.; Srivastava, B.; Stadnik, A.; Stanislaus, T.D.S.; Staszak, D.; Strikhanov, M.; Stringfellow, B.; Suaide, A.A.P.; Suarez, M.C.; Subba, N.L.; Šumbera, Michal; Sun, X.M.; Sun, Y.; Sun, Z.; Surrow, B.; Symons, T.J.M.; de Toledo, A. S.; Takahashi, J.; Tang, A.H.; Tang, Z.; Tarnowsky, T.; Thein, D.; Thomas, J.H.; Tian, J.; Timmins, A.R.; Timoshenko, S.; Tokarev, M. V.; Trainor, T.A.; Tram, V.N.; Trattner, A.L.; Trentalange, S.; Tribble, R. E.; Tsai, O.D.; Ulery, J.; Ullrich, T.; Underwood, D.G.; Van Buren, G.; van Leeuwen, M.; Vander Molen, A.M.; Vanfossen, J.A.; Varma, R.; Vasconcelos, G.S.M.; Vasilevski, I.M.; Vasiliev, A. N.; Videbaek, F.; Vigdor, S.E.; Viyogi, Y. P.; Vokal, S.; Voloshin, S.A.; Wada, M.; Walker, M.; Wang, F.; Wang, G.; Wang, J.S.; Wang, Q.; Wang, X.; Wang, X.L.; Wang, Y.; Webb, G.; Webb, J.C.; Westfall, G.D.; Whitten, C.; Wieman, H.; Wissink, S.W.; Witt, R.; Wu, Y.; Tlustý, David; Xie, W.; Xu, N.; Xu, Q.H.; Xu, Y.; Xu, Z.; Yang, P.; Yepes, P.; Yip, K.; Yoo, I.K.; Yue, Q.; Zawisza, M.; Zbroszczyk, H.; Zhan, W.; Zhang, S.; Zhang, W.M.; Zhang, X.P.; Zhang, Y.; Zhang, Z.; Zhao, Y.; Zhong, C.; Zhou, J.; Zoulkarneev, R.; Zoulkarneeva, Y.; Zuo, J.X.

    2009-01-01

    Roč. 102, č. 5 (2009), 052302/1-052302/7 ISSN 0031-9007 R&D Projects: GA ČR GA202/07/0079 Institutional research plan: CEZ:AV0Z10480505; CEZ:AV0Z10100502 Keywords : PARTICLE CORRELATIONS * QCD MATTER * CONICAL EMISSION Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 7.328, year: 2009

  11. Electro-optical study of nanoscale Al-Si-truncated conical photodetector with subwavelength aperture

    Science.gov (United States)

    Karelits, Matityahu; Mandelbaum, Yaakov; Chelly, Avraham; Karsenty, Avi

    2017-10-01

    A type of silicon photodiode has been designed and simulated to probe the optical near field and detect evanescent waves. These waves convey subwavelength resolution. This photodiode consists of a truncated conical shaped, silicon Schottky diode having a subwavelength aperture of 150 nm. Electrical and electro-optical simulations have been conducted. These results are promising toward the fabrication of a new generation of photodetector devices.

  12. Radial-firing optical fiber tip containing conical-shaped air-pocket for biomedical applications.

    Science.gov (United States)

    Lee, Seung Ho; Ryu, Yong-Tak; Son, Dong Hoon; Jeong, Seongmook; Kim, Youngwoong; Ju, Seongmin; Kim, Bok Hyeon; Han, Won-Taek

    2015-08-10

    We report a novel radial-firing optical fiber tip containing a conical-shaped air-pocket fabricated by deforming a hollow optical fiber using electric arc-discharge process. The hollow optical fiber was fusion spliced with a conventional optical fiber, simultaneously deforming into the intagliated conical-shaped region along the longitudinal fiber-axis of the fiber due to the gradual collapse of the cavity of the hollow optical fiber. Then the distal-end of the hollow optical fiber was sealed by the additional arc-discharge in order to obstruct the inflow of an external bio-substance or liquid to the inner air surface during the surgical operations, resulting in the formation of encased air-pocket in the silica glass fiber. Due to the total internal reflection of the laser beam at the conical-shaped air surface, the laser beam (λ = 632.8 nm) was deflected to the circumferential direction up to 87 degree with respect to the fiber-axis.

  13. Torsional Vibrations of a Conic Shaft with Opposite Tapers Carrying Arbitrary Concentrated Elements

    Directory of Open Access Journals (Sweden)

    Jia-Jang Wu

    2013-01-01

    Full Text Available The purpose of this paper is to present the exact solution for free torsional vibrations of a linearly tapered circular shaft carrying a number of concentrated elements. First of all, the equation of motion for free torsional vibration of a conic shaft is transformed into a Bessel equation, and, based on which, the exact displacement function in terms of Bessel functions is obtained. Next, the equations for compatibility of deformations and equilibrium of torsional moments at each attaching point (including the shaft ends between the concentrated elements and the conic shaft with positive and negative tapers are derived. From the last equations, a characteristic equation of the form is obtained. Then, the natural frequencies of the torsional shaft are determined from the determinant equation , and, corresponding to each natural frequency, the column vector for the integration constants, , is obtained from the equation . Substitution of the last integration constants into the associated displacement functions gives the corresponding mode shape of the entire conic shaft. To confirm the reliability of the presented theory, all numerical results obtained from the exact method are compared with those obtained from the conventional finite element method (FEM and good agreement is achieved.

  14. Conical evaporator and liquid-return wick model for vapor anode, multi-tube AMTEC cells

    Science.gov (United States)

    Tournier, Jean-Michel; El-Genk, Mohamed S.

    2000-01-01

    A detailed, 2-D thermal-hydraulic model for conical and flat evaporators and the liquid sodium return artery in PX-type AMTEC cells was developed, which predicts incipient dryout at the evaporator wick surface. Results obtained at fixed hot and cold side temperatures showed that the flat evaporator provided a slightly lower vapor pressure, but reached the capillary limit at higher temperature. The loss of performance due to partial recondensation over up to 20% of the wick surface of the deep conical evaporators was offset by the larger surface area available for evaporation, providing a slightly higher vapor pressure. Model results matched the PX-3A cell's experimental data of electrical power output, but the predicted temperature of the cell's conical evaporator was consistently ~50 K above measurements. A preliminary analysis indicated that sodium vapor leakage in the cell (through microcracks in the BASE tubes' walls or brazes) may explain the difference between predicted and measured evaporator temperatures in PX-3A. .

  15. Energy-flux characterization of conical and space-time coupled wave packets

    International Nuclear Information System (INIS)

    Lotti, A.; Couairon, A.; Faccio, D.; Trapani, P. Di

    2010-01-01

    We introduce the concept of energy density flux as a characterization tool for the propagation of ultrashort laser pulses with spatiotemporal coupling. In contrast with calculations for the Poynting vector, those for energy density flux are derived in the local frame moving at the velocity of the envelope of the wave packet under examination and do not need knowledge of the magnetic field. We show that the energy flux defined from a paraxial propagation equation follows specific geometrical connections with the phase front of the optical wave packet, which demonstrates that the knowledge of the phase fronts amounts to the measurement of the energy flux. We perform a detailed numerical study of the energy density flux in the particular case of conical waves, with special attention paid to stationary-envelope conical waves (X or O waves). A full characterization of linear conical waves is given in terms of their energy flux. We extend the definition of this concept to the case of nonlinear propagation in Kerr media with nonlinear losses.

  16. A truncated conical beam model for analysis of the vibration of rat whiskers.

    Science.gov (United States)

    Yan, Wenyi; Kan, Qianhua; Kergrene, Kenan; Kang, Guozheng; Feng, Xi-Qiao; Rajan, Ramesh

    2013-08-09

    A truncated conical beam model is developed to study the vibration behaviour of a rat whisker. Translational and rotational springs are introduced to better represent the constraint conditions at the base of the whiskers in a living rat. Dimensional analysis shows that the natural frequency of a truncated conical beam with generic spring constraints at its ends is inversely proportional to the square root of the mass density. Under all the combinations of the classical free, pinned, sliding or fixed boundary conditions of a truncated conical beam, it is proved that the natural frequency can be expressed as f = α(rb/L(2))E/ρ and the frequency coefficient α only depends on the ratio of the radii at the two ends of the beam. The natural frequencies of a representative rat whisker are predicted for two typical situations: freely whisking in air and the tip touching an object. Our numerical results show that there exists a window where the natural frequencies of a rat whisker are very sensitive to the change of the rotational constraint at the base. This finding is also confirmed by the numerical results of 18 whiskers with their data available from literature. It can be concluded that the natural frequencies of a rat whisker can be adjusted within a wide range through manipulating the constraints of the follicle on the rat base by a behaving animal. Copyright © 2013 Elsevier Ltd. All rights reserved.

  17. An assessment of a conical horn waveguide to represent the human eardrum

    Science.gov (United States)

    Fields, Taylor N.; Schnetzer, Lucia; Brister, Eileen; Yates, Charles W.; Withnell, Robert H.

    2018-05-01

    This study examined a model of the acoustic input impedance of the ear that includes a waveguide model of the eardrum. The eardrum was modeled as a lossless conical-horn with rigid walls. The ear canal was modeled as a one-dimensional lossy transmission line. The output impedance of the eardrum, the middle ear, and the cochlea, was modeled as a circuit analog. The model was fit to acoustic input impedance data from human ears using a nonlinear least-squares fit. The impact of a conical-horn shape for the eardrum was quantified by comparison with the eardrum modeled as a near-flat surface. The model provided a good match to the data over the frequency range examined. A conical-horn model of the human eardrum provided gain at high frequencies, most notably above 1–2 kHz, with a broader middle-ear frequency response. This finding may suggest that eardrum shape plays an important role in sound transmission to the cochlea.

  18. Analysis of solar water heater with parabolic dish concentrator and conical absorber

    Science.gov (United States)

    Rajamohan, G.; Kumar, P.; Anwar, M.; Mohanraj, T.

    2017-06-01

    This research focuses on developing novel technique for a solar water heating system. The novel solar system comprises a parabolic dish concentrator, conical absorber and water heater. In this system, the conical absorber tube directly absorbs solar radiation from the sun and the parabolic dish concentrator reflects the solar radiations towards the conical absorber tube from all directions, therefore both radiations would significantly improve the thermal collector efficiency. The working fluid water is stored at the bottom of the absorber tubes. The absorber tubes get heated and increases the temperature of the working fluid inside of the absorber tube and causes the working fluid to partially evaporate. The partially vaporized working fluid moves in the upward direction due to buoyancy effect and enters the heat exchanger. When fresh water passes through the heat exchanger, temperature of the vapour decreases through heat exchange. This leads to condensation of the vapour and forms liquid phase. The working fluid returns to the bottom of the collector absorber tube by gravity. Hence, this will continue as a cyclic process inside the system. The proposed investigation shows an improvement of collector efficiency, enhanced heat transfer and a quality water heating system.

  19. Super-Cavitating Flow Around Two-Dimensional Conical, Spherical, Disc and Stepped Disc Cavitators

    Science.gov (United States)

    Sooraj, S.; Chandrasekharan, Vaishakh; Robson, Rony S.; Bhanu Prakash, S.

    2017-08-01

    A super-cavitating object is a high speed submerged object that is designed to initiate a cavitation bubble at the nose which extends past the aft end of the object, substantially reducing the skin friction drag that would be present if the sides of the object were in contact with the liquid in which the object is submerged. By reducing the drag force the thermal energy consumption to move faster can also be minimised. The super-cavitation behavioural changes with respect to Cavitators of various geometries have been studied by varying the inlet velocity. Two-dimensional computational fluid dynamics analysis has been carried out by applying k-ε turbulence model. The variation of drag coefficient, cavity length with respect to cavitation number and inlet velocity are analyzed. Results showed conical Cavitator with wedge angle of 30° has lesser drag coefficient and cavity length when compared to conical Cavitators with wedge angles 45° and 60°, spherical, disc and stepped disc Cavitators. Conical cavitator 60° and disc cavitator have the maximum cavity length but with higher drag coefficient. Also there is significant variation of supercavitation effect observed between inlet velocities of 32 m/s to 40 m/s.

  20. Influence of abutment materials on the implant-abutment joint stability in internal conical connection type implant systems

    OpenAIRE

    Jo, Jae-Young; Yang, Dong-Seok; Huh, Jung-Bo; Heo, Jae-Chan; Yun, Mi-Jung; Jeong, Chang-Mo

    2014-01-01

    PURPOSE This study evaluated the influence of abutment materials on the stability of the implant-abutment joint in internal conical connection type implant systems. MATERIALS AND METHODS Internal conical connection type implants, cement-retained abutments, and tungsten carbide-coated abutment screws were used. The abutments were fabricated with commercially pure grade 3 titanium (group T3), commercially pure grade 4 titanium (group T4), or Ti-6Al-4V (group TA) (n=5, each). In order to assess ...

  1. Analytical and experimental position stability of the abutment in different dental implant systems with a conical implant?abutment connection

    OpenAIRE

    Semper-Hogg, Wiebke; Kraft, Silvan; Stiller, Sebastian; Mehrhof, Juergen; Nelson, Katja

    2012-01-01

    Objectives Position stability of the abutment should be investigated in four implant systems with a conical implant?abutment connection. Materials and methods Previously developed formulas and an established experimental setup were used to determine the position stability of the abutment in the four implant systems with a conical implant?abutment connection and different positional index designs: The theoretical rotational freedom was calculated by using the dimensions of one randomly selecte...

  2. Shells on elastic foundations

    International Nuclear Information System (INIS)

    Das, Y.C.; Kedia, K.K.

    1977-01-01

    No realistic analytical work in the area of Shells on Elastic Foundations has been reported in the literature. Various foundation models have been proposed by several authors. These models involve one or more than one parameters to characterise the foundation medium. Some of these models cannot be used to derive the basic equations governing the behaviour of shells on elastic foundations. In the present work, starting from an elastic continuum hypothesis, a mathematical model for foundation has been derived in curvilinear orthogonal coordinates by the help of principle of virtual displacements, treating one of the virtual displacements as known to satisfy certain given conditions at its edge surfaces. In this model, several foundation parameters can be considered and it can also be used for layered medium of both finite and infinite thickness. (Auth.)

  3. Design and development by direct polishing of the WFXT thin polynomial mirror shells

    Science.gov (United States)

    Proserpio, L.; Campana, S.; Citterio, O.; Civitani, M.; Combrinck, H.; Conconi, P.; Cotroneo, V.; Freeman, R.; Mattini, E.; Langstrof, P.; Morton, R.; Motta, G.; Oberle, O.; Pareschi, G.; Parodi, G.; Pels, C.; Schenk, C.; Stock, R.; Tagliaferri, G.

    2017-11-01

    The Wide Field X-ray Telescope (WFXT) is a medium class mission proposed to address key questions about cosmic origins and physics of the cosmos through an unprecedented survey of the sky in the soft X-ray band (0.2-6 keV) [1], [2]. In order to get the desired angular resolution of 10 arcsec (5 arcsec goal) on the entire 1 degrees Field Of View (FOV), the design of the optical system is based on nested grazing-incidence polynomial profiles mirrors, and assumes a focal plane curvature and plate scale corrections among the shells. This design guarantees an increased angular resolution also at large off-axis positions with respect to the usually adopted Wolter I configuration. In order to meet the requirements in terms of mass and effective area (less than 1200 kg, 6000 cm2 @ 1 keV), the nested shells are thin and made of quartz glass. The telescope assembly is composed by three identical modules of 78 nested shells each, with diameter up to 1.1 m, length in the range of 200-440 mm and thickness of less than 2.2 mm. At this regard, a deterministic direct polishing method is under investigation to manufacture the WFXT thin grazing-incidence mirrors made of quartz. The direct polishing method has already been used for past missions (as Einstein, Rosat, Chandra) but based on much thicker shells (10 mm ore more). The technological challenge for WFXT is to apply the same approach but for 510 times thinner shells. The proposed approach is based on two main steps: first, quartz glass tubes available on the market are ground to conical profiles; second the pre-shaped shells are polished to the required polynomial profiles using a CNC polishing machine. In this paper, preliminary results on the direct grinding and polishing of prototypes shells made by quartz glass with low thickness, representative of the WFXT optical design, are presented.

  4. An investigation of the Performance of a Conical Solar Water Heater in the Kingdom of Bahrain

    Science.gov (United States)

    Gaaliche, Nessreen; Ayhan, Teoman; Fathallah, Raouf

    2017-11-01

    Domestic water heater corresponds to 25% of the house energy consumption and can play an important role to reduce energy house expenses. Solar energy offers a preferred renewable energy resource because of its economic and environmental advantages. It is considered the best alternative to reduce domestic water heater energy consumption cost. Converting solar energy into heat can be considered among the simplest used systems. Solar thermal conversion is more efficient than solar electrical direct conversion method. Solar water heater systems are particularly easy to use and to repair. The integrated conical solar collector water heater (ICSCWH) is so far the easiest among water heating systems. The ICSCWH converts directly and efficiently the solar flux into heat. In order to expand the utilization of ICSCWH systems, many design modifications have been examined and analyzed. This study provides an experimental investigation and mathematical simulation of an ICSCWH system equipped with a glass cover resulting in the increase of the maximum absorption. Integrating the cone-shaped heat collector with an aluminum spiral pipe flow system may enhance the efficiency of the proposed system. In order to maximize the solar radiation of the system, the solar water heater has been designed in a conical shape, which removes the need to change its orientation toward the sun to receive the maximum sun radiation during the day. In this system, the heating of water has been obtained using the spiral pipe flow without the use of the solar cells and mirrors in order to reduce the total cost. The storage water tank of this system is coupled with a conical solar collector. Based on the above design, the solar water heater has been fabricated and tested. In addition, an analytical modeling approach aiming to predict the flow rate within the conical integrated collector storage solar water heater (ICSSWH) and its efficiency, was developed. Modeling through a numerical simulation approach

  5. Conical Magnetic Bearings Developed for Active Stall Control in Gas Turbine Engines

    Science.gov (United States)

    Trudell, Jeffrey J.; Kascak, Albert F.; Provenza, Andrew J.; Buccieri, Carl J.

    2004-01-01

    Active stall control is a current research area at the NASA Glenn Research Center that offers a great benefit in specific fuel consumption by allowing the gas turbine to operate beyond the onset of stall. Magnetic bearings are being investigated as a new method to perform active stall control. This enabling global aviation safety technology would result in improved fuel efficiency and decreased carbon dioxide emissions, as well as improve safety and reliability by eliminating oil-related delays and failures of engine components, which account for 40 percent of the commercial aircraft departure delays. Active stall control works by perturbing the flow in front of the compressor stage such that it cancels the pressure wave, which causes the compressor to go into stall. Radial magnetic bearings are able to whirl the shaft so that variations in blade tip leakage would flow upstream causing a perturbation wave that could cancel the rotating stall cell. Axial or thrust magnetic bearings cannot be used to cancel the surge mode in the compressor because they have a very low bandwidth and thus cannot modulate at a high enough frequency. Frequency response is limited because the thrust runner cannot be laminated. To improve the bandwidth of magnetic thrust bearings, researchers must use laminations to suppress the eddy currents. A conical magnetic bearing can be laminated, resulting in increased bandwidth in the axial direction. In addition, this design can produce both radial and thrust force in a single bearing, simplifying the installation. The proposed solution combines the radial and thrust bearing into one design that can be laminated--a conical magnetic bearing. The new conical magnetic bearing test rig, funded by a Glenn fiscal year 2002 Director's Discretionary Fund, was needed because none of the existing rigs has an axial degree of freedom. The rotor bearing configuration will simulate that of the main shaft on a gas turbine engine. One conical magnetic bearing

  6. An investigation of the Performance of a Conical Solar Water Heater in the Kingdom of Bahrain

    Directory of Open Access Journals (Sweden)

    Gaaliche Nessreen

    2017-01-01

    Full Text Available Domestic water heater corresponds to 25% of the house energy consumption and can play an important role to reduce energy house expenses. Solar energy offers a preferred renewable energy resource because of its economic and environmental advantages. It is considered the best alternative to reduce domestic water heater energy consumption cost. Converting solar energy into heat can be considered among the simplest used systems. Solar thermal conversion is more efficient than solar electrical direct conversion method. Solar water heater systems are particularly easy to use and to repair. The integrated conical solar collector water heater (ICSCWH is so far the easiest among water heating systems. The ICSCWH converts directly and efficiently the solar flux into heat. In order to expand the utilization of ICSCWH systems, many design modifications have been examined and analyzed. This study provides an experimental investigation and mathematical simulation of an ICSCWH system equipped with a glass cover resulting in the increase of the maximum absorption. Integrating the cone-shaped heat collector with an aluminum spiral pipe flow system may enhance the efficiency of the proposed system. In order to maximize the solar radiation of the system, the solar water heater has been designed in a conical shape, which removes the need to change its orientation toward the sun to receive the maximum sun radiation during the day. In this system, the heating of water has been obtained using the spiral pipe flow without the use of the solar cells and mirrors in order to reduce the total cost. The storage water tank of this system is coupled with a conical solar collector. Based on the above design, the solar water heater has been fabricated and tested. In addition, an analytical modeling approach aiming to predict the flow rate within the conical integrated collector storage solar water heater (ICSSWH and its efficiency, was developed. Modeling through a numerical

  7. STABLE CONIC-HELICAL ORBITS OF PLANETS AROUND BINARY STARS: ANALYTICAL RESULTS

    Energy Technology Data Exchange (ETDEWEB)

    Oks, E. [Physics Department, 206 Allison Lab., Auburn University, Auburn, AL 36849 (United States)

    2015-05-10

    Studies of planets in binary star systems are especially important because it was estimated that about half of binary stars are capable of supporting habitable terrestrial planets within stable orbital ranges. One-planet binary star systems (OBSS) have a limited analogy to objects studied in atomic/molecular physics: one-electron Rydberg quasimolecules (ORQ). Specifically, ORQ, consisting of two fully stripped ions of the nuclear charges Z and Z′ plus one highly excited electron, are encountered in various plasmas containing more than one kind of ion. Classical analytical studies of ORQ resulted in the discovery of classical stable electronic orbits with the shape of a helix on the surface of a cone. In the present paper we show that despite several important distinctions between OBSS and ORQ, it is possible for OBSS to have stable planetary orbits in the shape of a helix on a conical surface, whose axis of symmetry coincides with the interstellar axis; the stability is not affected by the rotation of the stars. Further, we demonstrate that the eccentricity of the stars’ orbits does not affect the stability of the helical planetary motion if the center of symmetry of the helix is relatively close to the star of the larger mass. We also show that if the center of symmetry of the conic-helical planetary orbit is relatively close to the star of the smaller mass, a sufficiently large eccentricity of stars’ orbits can switch the planetary motion to the unstable mode and the planet would escape the system. We demonstrate that such planets are transitable for the overwhelming majority of inclinations of plane of the stars’ orbits (i.e., the projections of the planet and the adjacent start on the plane of the sky coincide once in a while). This means that conic-helical planetary orbits at binary stars can be detected photometrically. We consider, as an example, Kepler-16 binary stars to provide illustrative numerical data on the possible parameters and the

  8. Electrochemical synthesis of CORE-shell magnetic nanowires

    KAUST Repository

    Ovejero, Jesús G.

    2015-04-16

    (Fe, Ni, CoFe) @ Au core-shell magnetic nanowires have been synthesized by optimized two-step potentiostatic electrodeposition inside self-assembled nanopores of anodic aluminium templates. The optimal electrochemical parameters (e.g., potential) have been firstly determined for the growth of continuous Au nanotubes at the inner wall of pores. Then, a magnetic core was synthesized inside the Au shells under suitable electrochemical conditions for a wide spectrum of single elements and alloy compositions (e.g., Fe, Ni and CoFe alloys). Novel opportunities offered by such nanowires are discussed particularly the magnetic behavior of (Fe, Ni, CoFe) @ Au core-shell nanowires was tested and compared with that of bare TM nanowires. These core-shell nanowires can be released from the template so, opening novel opportunities for biofunctionalization of individual nanowires.

  9. Combustion of palm kernel shell in a fluidized bed: Optimization of biomass particle size and operating conditions

    International Nuclear Information System (INIS)

    Ninduangdee, Pichet; Kuprianov, Vladimir I.

    2014-01-01

    Highlights: • Safe burning of palm kernel shell is achievable in a FBC using alumina as the bed material. • Thermogravimetric analysis of the shell with different particle sizes is performed. • Optimal values of the shell particle size and excess air lead to the minimum emission costs. • Combustion efficiency of 99.4–99.7% is achievable when operated under optimal conditions. • CO and NO emissions of the FBC are at levels substantially below national emission limits. - Abstract: This work presents a study on the combustion of palm kernel shell (PKS) in a conical fluidized-bed combustor (FBC) using alumina sand as the bed material to prevent bed agglomeration. Prior to combustion experiments, a thermogravimetric analysis was performed in nitrogen and dry air to investigate the effects of biomass particle size on thermal and combustion reactivity of PKS. During the combustion tests, the biomass with different mean particle sizes (1.5 mm, 4.5 mm, 7.5 mm, and 10.5 mm) was burned at a 45 kg/h feed rate, while excess air was varied from 20% to 80%. Temperature and gas concentrations (O 2 , CO, C x H y as CH 4 , and NO) were recorded along the axial direction in the reactor as well as at stack. The experimental results indicated that the biomass particle size and excess air had substantial effects on the behavior of gaseous pollutants (CO, C x H y , and NO) in different regions inside the reactor, as well as on combustion efficiency and emissions of the conical FBC. The CO and C x H y emissions can be effectively controlled by decreasing the feedstock particle size and/or increasing excess air, whereas the NO emission can be mitigated using coarser biomass particles and/or lower excess air. A cost-based approach was applied to determine the optimal values of biomass particle size and excess air, ensuring minimum emission costs of burning the biomass in the proposed combustor. From the optimization analysis, the best combustion and emission performance of the

  10. Study Added of Waste Chicken Egg Shell in Soils

    Directory of Open Access Journals (Sweden)

    Keng Wong Irwan Lie

    2016-01-01

    Full Text Available Soil is the foundation of structure or construction that will receive the load transfer through to foundation. If the soil has a carrying capacity of small and cannot withstand the load transfer can result in the failure of construction. If the soil has a carrying capacity of small ground it is necessary to stabilize or improve the soil so that an increase in the carrying capacity of the land so that it can be used for construction. One material is commonly used for soil stabilization with the addition of lime. Waste chicken egg shell is waste that is still rarely used, the results of research [1], states that composition egg shell broadly consists of water (1,6% and dry material (98,4%. The total dry ingredients are there, in shell eggs contained mineral elements (95,1% and protein (3,3%. Based on the existing mineral composition, then the egg shells are composed of crystalline CaCO3 (98,43%, MgCO3 (0,84% and Ca3(PO42 (0,75%. This research was done by adding powdered chicken egg shell waste in clay with a composition of 5%, 7,5%, 10% and 14% with physical properties test and soil compaction test.

  11. Collisions of massive particles, timelike thin shells and formation of black holes in three dimensions

    International Nuclear Information System (INIS)

    Lindgren, Jonathan

    2016-01-01

    We study collisions of massive pointlike particles in three dimensional anti-de Sitter space, generalizing the work on massless particles in http://dx.doi.org/10.1088/0264-9381/33/14/145009. We show how to construct exact solutions corresponding to the formation of either a black hole or a conical singularity from the collision of an arbitrary number of massive particles that fall in radially and collide at the origin of AdS. No restrictions on the masses or the angular and radial positions from where the particles are released, are imposed. We also consider the limit of an infinite number of particles, obtaining novel timelike thin shell spacetimes. These thin shells have an arbitrary mass distribution as well as a non-trivial embedding where the radial location of the shell depends on the angular coordinate, and we analyze these shells using the junction formalism of general relativity. We also consider the massless limit and find consistency with earlier results, as well as comment on the stress-energy tensor modes of the dual CFT.

  12. Collisions of massive particles, timelike thin shells and formation of black holes in three dimensions

    Energy Technology Data Exchange (ETDEWEB)

    Lindgren, Jonathan [Theoretische Natuurkunde, Vrije Universiteit Brussel, and the International Solvay Institutes,Pleinlaan 2, B-1050 Brussels (Belgium); Physique Théorique et Mathématique, Université Libre de Bruxelles,Campus Plaine C.P. 231, B-1050 Bruxelles (Belgium)

    2016-12-13

    We study collisions of massive pointlike particles in three dimensional anti-de Sitter space, generalizing the work on massless particles in http://dx.doi.org/10.1088/0264-9381/33/14/145009. We show how to construct exact solutions corresponding to the formation of either a black hole or a conical singularity from the collision of an arbitrary number of massive particles that fall in radially and collide at the origin of AdS. No restrictions on the masses or the angular and radial positions from where the particles are released, are imposed. We also consider the limit of an infinite number of particles, obtaining novel timelike thin shell spacetimes. These thin shells have an arbitrary mass distribution as well as a non-trivial embedding where the radial location of the shell depends on the angular coordinate, and we analyze these shells using the junction formalism of general relativity. We also consider the massless limit and find consistency with earlier results, as well as comment on the stress-energy tensor modes of the dual CFT.

  13. Self-force on an arbitrarily coupled scalar charge in cylindrical thin-shell spacetimes

    Energy Technology Data Exchange (ETDEWEB)

    Tomasini, C.; Rubin de Celis, E.; Simeone, C. [Universidad de Buenos Aires y IFIBA, CONICET, Ciudad Universitaria, Departamento de Fisica, Facultad de Ciencias Exactas y Naturales, Buenos Aires (Argentina)

    2018-02-15

    We consider the arbitrarily coupled field and self-force of a static massless scalar charge in cylindrical spacetimes with one or two asymptotic regions, with the only matter content concentrated in a thin-shell characterized by the trace of the extrinsic curvature jump κ. The self-force is studied numerically and analytically in terms of the curvature coupling ξ. We found the critical values ξ{sub c}{sup (n)} = n/(ρ(r{sub s})κ), with n element of N and ρ(r{sub s}) the metric's profile function at the position of the shell, for which the scalar field is divergent in the background configuration. The pathological behavior is removed by restricting the coupling to a domain of stability. The coupling has a significant influence over the self-force at the vicinities of the shell, and we identified ξ = 1/4 as the value for which the scalar force changes sign at a neighborhood of r{sub s}; if κ(1-4ξ) > 0 the shell acts repulsively as an effective potential barrier, while if κ(1-4ξ) < 0 it attracts the charge as a potential well. The sign of the asymptotic self-force only depends on whether there is an angle deficit or not on the external region where the charge is placed; conical asymptotics produce a leading attractive force, while Minkowski regions produce a repulsive asymptotic self-force. (orig.)

  14. Wrinkling of Pressurized Elastic Shells

    KAUST Repository

    Vella, Dominic

    2011-10-01

    We study the formation of localized structures formed by the point loading of an internally pressurized elastic shell. While unpressurized shells (such as a ping-pong ball) buckle into polygonal structures, we show that pressurized shells are subject to a wrinkling instability. We study wrinkling in depth, presenting scaling laws for the critical indentation at which wrinkling occurs and the number of wrinkles formed in terms of the internal pressurization and material properties of the shell. These results are validated by numerical simulations. We show that the evolution of the wrinkle length with increasing indentation can be understood for highly pressurized shells from membrane theory. These results suggest that the position and number of wrinkles may be used in combination to give simple methods for the estimation of the mechanical properties of highly pressurized shells. © 2011 American Physical Society.

  15. Assembly of Robust Bacterial Microcompartment Shells Using Building Blocks from an Organelle of Unknown Function

    Energy Technology Data Exchange (ETDEWEB)

    Lassila, JK; Bernstein, SL; Kinney, JN; Axen, SD; Kerfeld, CA

    2014-05-29

    Bacterial microconnpartnnents (BMCs) sequester enzymes from the cytoplasmic environment by encapsulation inside a selectively permeable protein shell. Bioinformatic analyses indicate that many bacteria encode BMC clusters of unknown function and with diverse combinations of shell proteins. The genome of the halophilic myxobacterium Haliangium ochraceum encodes one of the most atypical sets of shell proteins in terms of composition and primary structure. We found that microconnpartnnent shells could be purified in high yield when all seven H. ochraceum BMC shell genes were expressed from a synthetic operon in Escherichia coll. These shells differ substantially from previously isolated shell systems in that they are considerably smaller and more homogeneous, with measured diameters of 39 2 nm. The size and nearly uniform geometry allowed the development of a structural model for the shells composed of 260 hexagonal units and 13 hexagons per icosahedral face. We found that new proteins could be recruited to the shells by fusion to a predicted targeting peptide sequence, setting the stage for the use of these remarkably homogeneous shells for applications such as three-dimensional scaffolding and the construction of synthetic BMCs. Our results demonstrate the value of selecting from the diversity of BMC shell building blocks found in genomic sequence data for the construction of novel compartments. (C) 2014 Elsevier Ltd. All rights reserved.

  16. Fabrication, characterization and evaluation of bacterial cellulose-based capsule shells for oral drug delivery

    DEFF Research Database (Denmark)

    Ullah, Hanif; Badshah, Munair; Mäkilä, Ermei

    2017-01-01

    Bacterial cellulose (BC) was investigated for the first time for the preparation of capsule shells for immediate and sustained release of drugs. The prepared capsule shells were characterized using X-ray diffraction, scanning electron microscopy and Fourier transform infrared spectroscopy. The BC...... to gelatin capsules with both immediate and sustained drug release properties depending upon the compositions of the encapsulated materials....

  17. Fast synthesis, formation mechanism, and control of shell thickness of CuS–polystyrene core–shell microspheres

    International Nuclear Information System (INIS)

    Zhao, Li-min; Shao, Xin; Yin, Yi-bin; Li, Wen-zhi

    2012-01-01

    Graphical abstract: Core–shell structure PSt/CuS were prepared using polystyrene which were modified by 3-methacryloxypropyltrimethoxysilane as template. The coating thickness of CuS can be controlled by the amount of 3-methacryloxypropyltrimethoxysilane and the UV–vis absorption intensity of PSt/CuS composite also changed with the coating thickness of CuS. Highlights: ► Core–shell structure PSt/CuS were prepared using silanol-modified polystyrene microspheres as template. ► The coating thickness of core–shell structure PSt/CuS can be controlled by a simple method. ► The UV–vis absorption intensity of PSt/CuS composite also changed with the coating thickness of CuS. -- Abstract: The silanol-modified polystyrene microspheres were prepared through dispersion polymerization. Then copper sulfide particles were grown on silanol-modified polystyrene through sonochemical deposition in an aqueous bath containing copper acetate and sulfide, released through the hydrolysis of thioacetamide. The resulting particles were continuous and uniform as characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Fourier transform infrared, thermogravimetric analysis and UV–vis absorption spectroscopy were used to characterize the structure and properties of core–shell particles. The results showed the coating thickness of CuS shell can be controlled by the amount of silanol and the UV–vis absorption intensity of PSt/CuS composite also changed with the coating thickness of CuS.

  18. Seismic analysis of axisymmetric shells

    International Nuclear Information System (INIS)

    Jospin, R.J.; Toledo, E.M.; Feijoo, R.A.

    1984-01-01

    Axisymmetric shells subjected to multiple support excitation are studied. The shells are spatialy discretized by the finite element method and in order to obtain estimates for the maximum values of displacements and stresses the response spectrum tecnique is used. Finally, some numerical results are presented and discussed in the case of a shell of revolution with vertical symmetry axis, subjected to seismic ground motions in the horizontal, vertical and rocking directions. (Author) [pt

  19. Creep analysis of orthotropic shells

    International Nuclear Information System (INIS)

    Mehra, V.K.; Ghosh, A.

    1975-01-01

    A method of creep analysis of orthotropic cylindrical shells subjected to axisymmetric loads has been developed. A general study of creep behaviour of cylindrical shells subjected to a uniform internal pressure has been conducted for a wide range of values of anisotropy coefficients and creep law exponent. Analysis includes determination of stress re-distribution, strain rates, stationary state stresses. Application of reference stress technique has been extended to analysis of shells. (author)

  20. The direct manipulation shell

    International Nuclear Information System (INIS)

    Allen, M.E.; Christiansen, M.

    1992-01-01

    Accelerator controls systems provide parameter display pages which allow the operator to monitor and manipulate selected control points in the system. Display pages are generally implemented as either hand-crafted, purpose-built programs; or by using a specialized display page layout tool. These two methods of display page development exhibit the classic trade-off between functionality vs. ease of implementation. In the Direct Manipulation Shell we approach the process of developing a display page in a manifestly object-oriented manner. This is done by providing a general framework for interactively instantiating and manipulating display objects. (author)